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Sample records for rotational barrier energy

  1. Partitioning of methyl internal rotational barrier energy of ...

    Indian Academy of Sciences (India)

    The nature of methyl internal rotational barrier in thioacetaldehyde has been investigated by relaxation effect, natural bond orbital (NBO) analysis and Pauling exchange interactions. The true experimental barrier can be obtained by considering fully relaxed rotation. Nuclear-electron attraction term is a barrier forming term in ...

  2. Hindered rotational energy barriers of BH4- tetrahedra in β-Mg(BH4)2 from quasielastic neutron scattering and DFT calculations

    DEFF Research Database (Denmark)

    Blanchard, Didier; Maronsson, Jon Bergmann; Riktor, M.D.

    2012-01-01

    , around the 2-fold (C2) and 3-fold (C3) axes were observed at temperatures from 120 to 440 K. The experimentally obtained activation energies (EaC2 = 39 and 76 meV and EaC3 = 214 meV) and mean residence times between reorientational jumps are comparable with the energy barriers obtained from DFT......In this work, hindered rotations of the BH4- tetrahedra in Mg(BH4)2 were studied by quasielastic neutron scattering, using two instruments with different energy resolution, in combination with density functional theory (DFT) calculations. Two thermally activated reorientations of the BH4- units...... calculations. A linear dependency of the energy barriers for rotations around the C2 axis parallel to the Mg-Mg axis with the distance between these two axes was revealed by the DFT calculations. At the lowest temperature (120 K) only 15% of the BH4- units undergo rotational motion and from comparison with DFT...

  3. The rotational barrier in ethane: a molecular orbital study.

    Science.gov (United States)

    Quijano-Quiñones, Ramiro F; Quesadas-Rojas, Mariana; Cuevas, Gabriel; Mena-Rejón, Gonzalo J

    2012-04-20

    The energy change on each Occupied Molecular Orbital as a function of rotation about the C-C bond in ethane was studied using the B3LYP, mPWB95 functional and MP2 methods with different basis sets. Also, the effect of the ZPE on rotational barrier was analyzed. We have found that σ and π energies contribution stabilize a staggered conformation. The σ(s) molecular orbital stabilizes the staggered conformation while the stabilizes the eclipsed conformation and destabilize the staggered conformation. The π(z) and molecular orbitals stabilize both the eclipsed and staggered conformations, which are destabilized by the π(v) and molecular orbitals. The results show that the method of calculation has the effect of changing the behavior of the energy change in each Occupied Molecular Orbital energy as a function of the angle of rotation about the C-C bond in ethane. Finally, we found that if the molecular orbital energy contribution is deleted from the rotational energy, an inversion in conformational preference occurs.

  4. The Rotational Barrier in Ethane: A Molecular Orbital Study

    Directory of Open Access Journals (Sweden)

    Gonzalo J. Mena-Rejón

    2012-04-01

    Full Text Available The energy change on each Occupied Molecular Orbital as a function of rotation about the C-C bond in ethane was studied using the B3LYP, mPWB95 functional and MP2 methods with different basis sets. Also, the effect of the ZPE on rotational barrier was analyzed. We have found that σ and π energies contribution stabilize a staggered conformation. The σs molecular orbital stabilizes the staggered conformation while the  stabilizes the eclipsed conformation and destabilize the staggered conformation. The πz and  molecular orbitals stabilize both the eclipsed and staggered conformations, which are destabilized by the πv and  molecular orbitals. The results show that the method of calculation has the effect of changing the behavior of the energy change in each Occupied Molecular Orbital energy as a function of the angle of rotation about the C–C bond in ethane. Finally, we found that if the molecular orbital energy contribution is deleted from the rotational energy, an inversion in conformational preference occurs.

  5. Determination of the Rotational Barrier in Ethane by Vibrational Spectroscopy and Statistical Thermodynamics

    Science.gov (United States)

    Ercolani, Gianfranco

    2005-01-01

    The finite-difference boundary-value method is a numerical method suited for the solution of the one-dimensional Schrodinger equation encountered in problems of hindered rotation. Further, the application of the method, in combination with experimental results for the evaluation of the rotational energy barrier in ethane is presented.

  6. Theoretical analysis of the rotational barrier of ethane.

    Science.gov (United States)

    Mo, Yirong; Gao, Jiali

    2007-02-01

    The understanding of the ethane rotation barrier is fundamental for structural theory and the conformational analysis of organic molecules and requires a consistent theoretical model to differentiate the steric and hyperconjugation effects. Due to recently renewed controversies over the barrier's origin, we developed a computational approach to probe the rotation barriers of ethane and its congeners in terms of steric repulsion, hyperconjugative interaction, and electronic and geometric relaxations. Our study reinstated that the conventional steric repulsion overwhelmingly dominates the barriers.

  7. Low Barrier Methyl Rotation in 3-PENTYN-1-OL as Observed by Microwave Spectroscopy

    Science.gov (United States)

    Eibl, Konrad; Kannengießer, Raphaela; Stahl, Wolfgang; Nguyen, Ha Vinh Lam; Kleiner, Isabelle

    2016-06-01

    It is known that the barrier to internal rotation of the methyl groups in ethane (1) is about 1000 wn. If a C-C-triple bond is inserted between the methyl groups as a spacer (2), the torsional barrier is assumed to be dramatically lower, which is a common feature of ethinyl groups in general. To study this effect of almost free internal rotation, we measured the rotational spectrum of 3-pentyn-1-ol (3) by pulsed jet Fourier transform microwave spectroscopy in the frequency range from 2 to 26.5 GHz. Quantum chemical calculations at the MP2/6-311++G(d,p) level of theory yielded five stable conformers on the potential energy surface. The most stable conformer, which possesses C1 symmetry, was assigned and fitted using two theoretical approaches treating internal rotations, the rho axis method (BELGI-C1) and the combined axis method (XIAM). The molecular parameters as well as the internal rotation parameters were determined. A very low barrier to internal rotation of the methyl group of only 9.4545(95) wn was observed. R. M. Pitzer, Acc. Chem. Res., 1983, 16, 207-210

  8. Stabilising high energy orbit oscillations by the utilisation of centrifugal effects for rotating-tyre-induced energy harvesting

    Science.gov (United States)

    Zhang, Yunshun; Zheng, Rencheng; Nakano, Kimihiko; Cartmell, Matthew P.

    2018-04-01

    Nonlinear energy harvesters are frequently considered in preference to linear devices because they can potentially overcome the narrow frequency bandwidth limitations inherent to linear variants; however, the possibility of variable harvesting efficiency is raised for the nonlinear case. This paper proposes a rotational energy harvester which may be fitted into an automobile tyre, with the advantage that it may broaden the rotating frequency bandwidth and simultaneously stabilise high-energy orbit oscillations. By consideration of the centrifugal effects due to rotation, the overall restoring force will potentially be increased for a cantilever implemented within the harvester, and this manifests as an increase in its equivalent elastic stiffness. In addition, this study reveals that the initial potential well barriers become as shallow as those for a bistable system. When the rotational frequency increases beyond an identifiable boundary frequency, the system transforms into one with a potential barrier of a typical monostable system. On this basis, the inter-well motion of the bistable system can provide sufficient kinetic energy so that the cantilever maintains its high-energy orbit oscillation for monostable hardening behaviour. Furthermore, in a vehicle drive experiment, it has been shown that the effective rotating frequency bandwidth can be widened from 15 km/h-25 km/h to 10 km/h-40 km/h. In addition, it is confirmed that the centrifugal effects can improve the harvester performance, producing a mean power of 61 μW at a driving speed of 40 km/h, and this is achieved by stabilising the high-energy orbit oscillations of the rotational harvester.

  9. The low internal rotation barriers of halogenated toluenes: Rotational spectrum of 2,4-difluorotoluene

    Science.gov (United States)

    Nair, K. P. Rajappan; Herbers, Sven; Obenchain, Daniel A.; Grabow, Jens-Uwe; Lesarri, Alberto

    2018-02-01

    The rotational spectrum of 2,4-difluorotoluene in the region 5-25 GHz has been studied by pulsed supersonic jet using Fourier transform microwave spectroscopy. The tunneling splitting due to the methyl internal rotation in the ground torsional state could be unambiguously identified and the threefold (V3) potential barrier hindering the internal rotation of the methyl top was determined as 2.80144 (82) kJ/mol. The ground-state rotational parameters for the parent and seven 13C isotopic species in natural abundance were determined with high accuracy, including all quartic centrifugal distortion constants. The electric dipole moment μ = 1.805(42) D was obtained from Stark effect measurements. The molecular structure was derived using the substitution (rs) method. Supporting ab initio (MP2) calculations provided comparative values for the potential barrier and molecular parameters.

  10. Rotational spectrum of 1,1-difluoroethane-argon: influence of the interaction with the Ar atom on the V 3 barrier to internal rotation of the methyl group

    Science.gov (United States)

    Velino, Biagio; Melandri, Sonia; Favero, Paolo G.; Dell'Erba, Adele; Caminati, Walther

    2000-01-01

    The free-jet millimeter-wave absorption spectrum of 1,1-difluoroethane-Ar is reported. Most of the measured lines are split due to internal rotation of the methyl group and the tunnelling motion of Ar connecting two equivalent potential energy minima. The Ar atom, close to the CHF 2 group, eclipses one of the methylic hydrogens in the symmetryless geometry of the complex, reducing in this way the barrier to the internal rotation of the methyl group with respect to isolated 1,1-difluoroethane. For high J levels the distance of Ar from the molecule increases, however, due to the centrifugal distortion, and the barrier increases towards the value for 1,1-difluoroethane.

  11. Unraveling the interplay between hydrogen bonding and rotational energy barrier to fine-tune the properties of triazine molecular glasses.

    Science.gov (United States)

    Laventure, Audrey; De Grandpré, Guillaume; Soldera, Armand; Lebel, Olivier; Pellerin, Christian

    2016-01-21

    Mexylaminotriazine derivatives form molecular glasses with outstanding glass-forming ability (GFA), high resistance to crystallization (glass kinetic stability, GS), and a glass transition temperature (Tg) above room temperature that can be conveniently modulated by selection of the headgroup and ancillary groups. A common feature of all these compounds is their secondary amino linkers, suggesting that they play a critical role in their GFA and GS for reasons that remain unclear because they can simultaneously form hydrogen (H) bonds and lead to a high interconversion energy barrier between different rotamers. To investigate independently and better control the influence of H bonding capability and rotational energy barrier on Tg, GFA and GS, a library of twelve analogous molecules was synthesized with different combinations of NH, NMe and O linkers. Differential scanning calorimetry (DSC) revealed that these compounds form, with a single exception, kinetically stable glasses with Tg values spanning a very broad range from -25 to 94 °C. While variable temperature infrared spectroscopy combined to chemometrics reveals that, on average, around 60% of the NH groups are still H-bonded as high as 40 °C above Tg, critical cooling rates obtained by DSC clearly show that molecules without H-bond donating linkers also present an outstanding GFA, meaning that H bonding plays a dominant role in controlling Tg but is not required to prevent crystallization. It is a high interconversion energy barrier, provoking a distribution of rotamers, that most efficiently promotes both GFA and resistance to crystallization. These new insights pave the way to more efficient glass engineering by extending the possible range of accessible Tg, allowing in particular the preparation of homologous glass-formers with high GS at ambient temperature in either the viscous or vitreous state.

  12. Rotational Spectrum and Internal Rotation Barrier of 1-Chloro-1,1-difluoroethane

    Science.gov (United States)

    Alonso, José L.; López, Juan C.; Blanco, Susana; Guarnieri, Antonio

    1997-03-01

    The rotational spectra of 1-chloro-1,1-difluoroethane (HCFC-142b) has been investigated in the frequency region 8-115 GHz with Stark, waveguide Fourier transform (FTMW), and millimeter-wave spectrometers. Assignments in large frequency regions with the corresponding frequency measurements have been made for the ground andv18= 1 (CH3torsion) vibrational states of the35Cl isotopomer and for the ground state of the37Cl species. Accurate rotational, quartic centrifugal distortion, and quadrupole coupling constants have been determined from global fits considering all these states. SmallA-Einternal rotation splittings have been observed for thev18= 1 vibrational state using FTMW spectroscopy. The barrier height for the internal rotation of the methyl group has been determined to be 3751 (4) cal mol-1, in disagreement with the previous microwave value of 4400 (100) cal mol-1reported by G. Graner and C. Thomas [J. Chem. Phys.49,4160-4167 (1968)].

  13. Macroscopic-microscopic energy of rotating nuclei in the fusion-like deformation valley

    International Nuclear Information System (INIS)

    Gherghescu, R.A.; Royer, Guy

    2000-01-01

    The energy of rotating nuclei in the fusion-like deformation valley has been determined within a liquid drop model including the proximity energy, the two-center shell model and the Strutinsky method. The potential barriers of the 84 Zr, 132 Ce, 152 Dy and 192 Hg nuclei have been determined. A first minimum having a microscopic origin and lodging the normally deformed states disappears with increasing angular momenta. The microscopic and macroscopic energies contribute to generate a second minimum where superdeformed states may survive. It becomes progressively the lowest one at intermediate spins. At higher angular momenta, the minimum moves towards the foot of the external fission barrier leading to hyperdeformed quasi-molecular states. (author)

  14. A high rotational barrier for physisorbed hydrogen in an fcu-metal-organic framework

    KAUST Repository

    Pham, Tony T.; Forrest, Katherine A.; Georgiev, Peter A L; Lohstroh, Wiebke; Xue, Dongxu; Hogan, Adam; Eddaoudi, Mohamed; Space, Brian; Eckert, Juergen

    2014-01-01

    A combined inelastic neutron scattering (INS) and theoretical study of H2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H2. This rotational barrier for H2 is the highest yet of reported MOF materials based on physisorption. This journal is

  15. Theoretical study of formic acid: A new look at the origin of the planar Z conformation and C-O rotational barrier

    International Nuclear Information System (INIS)

    Hirao, Hajime

    2008-01-01

    The E and Z rotamers of formic acid (HCOOH) and its barrier to internal rotation about the C-O bond were computationally explored at the HF/6-311 + G**, B3LYP/cc-pVTZ, and CCSD(T)/cc-pVTZ levels of theory. All calculations yielded similar results consistent with experimental observations. Subsequent analysis of the interaction between formate ion (HCOO - ) and proton (H + ) within formic acid demonstrated a direct correlation between the changes in fragment interaction energy and the total energy of formic acid upon rotation. To obtain further insights into the interaction, energy decomposition analysis based on the reactive bond orbital (RBO) method was carried out using the 6-311 + G** basis set. The analysis showed the electrostatic effect constitutes a major component that gives rise to the interaction energy variation along the rotation path. Thus, the electrostatic environment of HCOO - can be viewed as the key factor determining the Z ground state and C-O rotational barrier of formic acid. The anisotropic electrostatic environment of formate that favors planar conformations of formic acid may be due to the in-plane distribution of carbonyl lone pairs, and the larger electrostatic attraction in the Z form appears to come from a secondary electrostatic interaction between the proton and the distal oxygen. At the rotational transition state, the O-H bond was not exactly perpendicular to the molecular plane, but slightly tilted toward the E side, which can also be explained by the electrostatic hypothesis. Charge-transfer stabilization was smallest in the Z conformation, but it gradually increased upon rotation to a maximum at the E conformation. Therefore, charge - transfer does not explain the geometry of formic acid. The important role of the electrostatic effect was also observed in in-plane rotation of the O-H bond

  16. Rotating bubble and toroidal nuclei and fragmentation

    International Nuclear Information System (INIS)

    Royer, G.; Haddad, F.; Jouault, B.

    1995-01-01

    The energy of rotating bubble and toroidal nuclei predicted to be formed in central heavy-ion collisions at intermediate energies is calculated within the generalized rotating liquid drop model. The potential barriers standing in these exotic deformation paths are compared with the three dimensional and plane fragmentation barriers. In the toroidal deformation path of the heaviest systems exists a large potential pocket localised below the plane fragmentation barriers. This might allow the temporary survival of heavy nuclear toroids before the final clusterization induced by the surface and proximity tension. (author)

  17. Magnetization reversal processes of single nanomagnets and their energy barrier

    International Nuclear Information System (INIS)

    Krone, P.; Makarov, D.; Albrecht, M.; Schrefl, T.; Suess, D.

    2010-01-01

    Micromagnetic simulations were performed to investigate the influence of geometry and magnetic anisotropy constant on energy barrier and magnetization reversal mechanism of individual bits important for the bit patterned media concept in magnetic data storage. It is shown that dependency of the energy barrier on magnetic and geometric properties of bits can be described by an analytical approach in the case of quasi-coherent magnetization rotation process. However, when the bit size exceeds a critical size, for which an incoherent magnetization reversal is preferred, the analytical approach becomes invalid and no self-consistent theory is available. By systematically investigating the influence of bit size on the magnetization reversal mode, it was found that the transition from quasi-coherent to incoherent magnetization reversal mode can still be described analytically if an activation volume is considered instead of the bit volume. In this case, the nucleation volume is an important parameter determining thermal stability of the bit. If the volume of the bit is larger than twice the activation volume, the energy barrier stays nearly constant; with further increase in bit size, no gain in thermal stability can be achieved.

  18. Energy crops in rotation. A review

    Energy Technology Data Exchange (ETDEWEB)

    Zegada-Lizarazu, Walter; Monti, Andrea [Department of Agroenvironmental Science and Technology, University of Bologna, Viale G. Fanin, 44 - 40127, Bologna (Italy)

    2011-01-15

    The area under energy crops has increased tenfold over the last 10 years, and there is large consensus that the demand for energy crops will further increase rapidly to cover several millions of hectares in the near future. Information about rotational systems and effects of energy crops should be therefore given top priority. Literature is poor and fragmentary on this topic, especially about rotations in which all crops are exclusively dedicated to energy end uses. Well-planned crop rotations, as compared to continuous monoculture systems, can be expected to reduce the dependence on external inputs through promoting nutrient cycling efficiency, effective use of natural resources, especially water, maintenance of the long-term productivity of the land, control of diseases and pests, and consequently increasing crop yields and sustainability of production systems. The result of all these advantages is widely known as crop sequencing effect, which is due to the additional and positive consequences on soil physical-chemical and biological properties arising from specific crops grown in the same field year after year. In this context, the present review discusses the potential of several rotations with energy crops and their possibilities of being included alongside traditional agriculture systems across different agro-climatic zones within the European Union. Possible rotations dedicated exclusively to the production of biomass for bioenergy are also discussed, as rotations including only energy crops could become common around bio-refineries or power plants. Such rotations, however, show some limitations related to the control of diseases and to the narrow range of available species with high production potential that could be included in a rotation of such characteristics. The information on best-known energy crops such as rapeseed (Brassica napus) and sunflower (Helianthus annuus) suggests that conventional crops can benefit from the introduction of energy crops in

  19. Theoretical and Spectroscopic investigations of conformations, rotational barriers and scaled vibrations of 2,3-dimethyl hexane

    Directory of Open Access Journals (Sweden)

    Aziz Aboulmouhajir

    2017-01-01

    Full Text Available The 2,3-dimethyl hexane conformational isomerism has been investigated in detail, based on HF, Post-HF and DFT calculations at different basis set. The effect of size of basis, ZPE, thermal contributions, electronic correlation and optimization methods on the conformational stability was discussed. The rotational barriers from the most stable conformer to the lowest energy secondary conformers and their correspondent inversion barriers at both HF and MP2 methods using 6-31G* basis set have also been approached. A normal mode calculation of the most and less-stable conformers using a scaled ab initio force field in terms of non-redundant local symmetry coordinates have been made to elucidate the conformational dependence of the vibrational spectra.

  20. Energy correlations for mixed rotational bands

    International Nuclear Information System (INIS)

    Doessing, T.

    1985-01-01

    A schematic model for the mixing of rotational bands above the yrast line in well deformed nuclei is considered. Many-particle configurations of a rotating mean field form basis bands, and these are subsequently mixed due to a two body residual interaction. The energy interval over which a basis band is spread out increases with increasing excitation energy above the yrast line. Conversely, the B(E2) matrix element for rotational decay out of one of the mixed band states is spread over an interval which is predicted to become more narrow with increasing excitation energy. Finally, the implication of band mixing for γ-ray energy correlations is briefly discussed. (orig.)

  1. Deformation energy of a toroidal nucleus and plane fragmentation barriers

    International Nuclear Information System (INIS)

    Fauchard, C.; Royer, G.

    1996-01-01

    The path leading to pumpkin-like configurations and toroidal shapes is investigated using a one-parameter shape sequence. The deformation energy is determined within the analytical expressions obtained for the various shape-dependent functions and the generalized rotating liquid drop model taking into account the proximity energy and the temperature. With increasing mass and angular momentum, a potential well appears in the toroidal shape path. For the heaviest systems, the pocket is large and locally favourable with respect to the plane fragmentation barriers which might allow the formation of evanescent toroidal systems which would rapidly decay in several fragments to minimize the surface tension. (orig.)

  2. Barriers to improvements in energy efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, A.K.N.

    1991-10-01

    To promote energy-efficiency improvements, actions may be required at one or more levels -- from the lowest level of the consumer (residential, commercial, industrial, etc.) through the highest level of the global agencies. But barriers to the implementation of energy-efficiency improvements exist or can arise at all these levels. Taking up each one of these barriers in turn, the paper discusses specific measures that can contribute to overcoming the barriers. However, a one-barrier-one-measure approach must be avoided. Single barriers may in fact involve several sub-barriers. Also, combinations of measures are much more effective in overcoming barriers. In particular, combinations of measures that simultaneously overcome several barriers are most successful. The paper discusses the typology of barriers, explores their origin and suggests measures that by themselves or in combination with other measures, will overcome these barriers. Since most of the barriers dealt with can be found in the barriers'' literature, any originality in the paper lies in its systematic organization, synoptic view and holistic treatment of this issue. This paper is intended to initiate a comprehensive treatment of barriers, their origins and the measures that contribute to overcoming them. Hopefully, such a treatment will facilitate the implementation of energy-efficiency improvements involving a wide diversity of ever-changing energy end uses and consumer preferences.

  3. Barriers to improvements in energy efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, A.K.N.

    1991-10-01

    To promote energy-efficiency improvements, actions may be required at one or more levels -- from the lowest level of the consumer (residential, commercial, industrial, etc.) through the highest level of the global agencies. But barriers to the implementation of energy-efficiency improvements exist or can arise at all these levels. Taking up each one of these barriers in turn, the paper discusses specific measures that can contribute to overcoming the barriers. However, a one-barrier-one-measure approach must be avoided. Single barriers may in fact involve several sub-barriers. Also, combinations of measures are much more effective in overcoming barriers. In particular, combinations of measures that simultaneously overcome several barriers are most successful. The paper discusses the typology of barriers, explores their origin and suggests measures that by themselves or in combination with other measures, will overcome these barriers. Since most of the barriers dealt with can be found in the ``barriers`` literature, any originality in the paper lies in its systematic organization, synoptic view and holistic treatment of this issue. This paper is intended to initiate a comprehensive treatment of barriers, their origins and the measures that contribute to overcoming them. Hopefully, such a treatment will facilitate the implementation of energy-efficiency improvements involving a wide diversity of ever-changing energy end uses and consumer preferences.

  4. Enershield : energy saving air barriers

    Energy Technology Data Exchange (ETDEWEB)

    Hallihan, D. [Enershield Industries Ltd., Edmonton, AB (Canada)

    2008-07-01

    Enershield Industries is a leader in air barrier technology and provides solution for the Canadian climate. This presentation described the advantages of air barriers and the impact of rising energy costs. An air barrier is used to separate areas of differing environments and makes existing building systems more efficient. This presentation discussed how an air barrier works. It also identified how Enershield Industries calculates energy savings. It described air barrier applications and those who use barrier technology. These include the commercial and industrial sector as well as the personnel and retail sector. Barrier technology can be used for cold storage; vehicle and equipment washes; food processing; and environmental separation. Features and benefits such as the ability to create seal, acoustic insulation, and long term durability were also discussed. Last, the presentation addressed model selection and design criteria issues. Design criteria that were presented included a discussion of acoustic installation, articulating nozzles, scroll cased fans, and structural frame. Other design criteria presented were galvanized frames, telescopic sliders, and off the shelf parts. It was concluded that the ability to reduce energy consumption and enhance employee/client comfort is beneficial to the employer as well as to the employee. figs.

  5. A study of the deep structure of the energy landscape of glassy polystyrene: the exponential distribution of the energy barriers revealed by high-field electron spin resonance spectroscopy

    International Nuclear Information System (INIS)

    Bercu, V; Martinelli, M; Massa, C A; Pardi, L A; Leporini, D

    2004-01-01

    The reorientation of one small paramagnetic molecule (spin probe) in glassy polystyrene (PS) is studied by high-field electron spin resonance spectroscopy at two different Larmor frequencies (190 and 285 GHz). The exponential distribution of the energy barriers for the rotational motion of the spin probe is unambiguously evidenced at both 240 and 270 K. The same shape for the distribution of the energy barriers of PS was evidenced by the master curves provided by previous mechanical and light scattering studies. The breadth of the energy barrier distribution of the spin probe is in the range of the estimates of the breadth of the PS energy barrier distribution. The evidence that the deep structure of the energy landscape of PS exhibits the exponential shape of the energy barrier distribution agrees with the results from extreme-value statistics (Bouchaud and Mezard 1997 J. Phys. A: Math. Gen. 30 7997) and the trap model by Bouchaud and co-workers (1996 J. Phys. A: Math. Gen. 29 3847, 2001 Phys. Rev. B 64 104417). (letter to the editor)

  6. Barriers in the energy of deformed nuclei

    Directory of Open Access Journals (Sweden)

    V. Yu. Denisov

    2014-06-01

    Full Text Available Interaction energy between two nuclei considering to their deformations is studied. Coulomb and nuclear in-teraction energies, as well as the deformation energies of both nuclei, are taken into account at evaluation of the interaction energy. It is shown that the barrier related to the interaction energy of two nuclei depends on the de-formations and the height of the minimal barrier is evaluated. It is obtained that the heavier nucleus-nucleus sys-tems have large deformation values at the lowest barrier. The difference between the barrier between spherical nuclei and the lowest barrier between deformed nuclei increases with the mass and the charge of the interacting nuclei.

  7. Energy barriers in patterned media

    NARCIS (Netherlands)

    de Vries, Jeroen

    2013-01-01

    Due to the fact that thermal activation aids in overcoming the energy barrier, the required field for reversal varies from instance to instance for the same island. This thermally induced switching field distribution can be used to determine the difference in energy barrier of magneticallyweak and

  8. Structure of molecules and internal rotation

    CERN Document Server

    Mizushima, San-Ichiro

    1954-01-01

    Structure of Molecules and Internal Rotation reviews early studies on dihalogenoethanes. This book is organized into two parts encompassing 8 chapters that evaluate the Raman effect in ethane derivatives, the energy difference between rotational isomers, and the infrared absorption of ethane derivatives. Some of the topics covered in the book are the potential barrier to internal rotation; nature of the hindering potential; entropy difference between the rotational isomers; internal rotation in butane, pentane, and hexane; and internal rotation in long chain n-paraffins. Other chapters deal wi

  9. The torsional barriers of two equivalent methyl internal rotations in 2,5-dimethylfuran investigated by microwave spectroscopy

    Science.gov (United States)

    Van, Vinh; Bruckhuisen, Jonas; Stahl, Wolfgang; Ilyushin, Vadim; Nguyen, Ha Vinh Lam

    2018-01-01

    The microwave spectrum of 2,5-dimethylfuran was recorded using two pulsed molecular jet Fourier transform microwave spectrometers which cover the frequency range from 2 to 40 GHz. The internal rotations of two equivalent methyl tops with a barrier height of approximately 439.15 cm-1 introduce torsional splittings of all rotational transitions in the spectrum. For the spectral analysis, two different computer programs were applied and compared, the PAM-C2v-2tops code based on the principal axis method which treats several torsional states simultaneously, and the XIAM code based on the combined axis method, yielding accurate molecular parameters. The experimental work was supplemented by quantum chemical calculations. Two-dimensional potential energy surfaces depending on the torsional angles of both methyl groups were calculated and parametrized.

  10. Role of rotational energy and deformations in the dynamics of {sup 6}Li+{sup 90}Zr reaction

    Energy Technology Data Exchange (ETDEWEB)

    Kaur, Gurvinder; Grover, Neha; Sandhu, Kirandeep; Sharma, Manoj K., E-mail: msharma@thapar.edu

    2014-07-15

    In reference to recent experimental data, the dynamical cluster-decay model (DCM) has been applied to study the neutron evaporation residue (ER) cross sections of intermediate mass nucleus {sup 96}Tc{sup ⁎} spread over a wide range of incident energy across the Coulomb barrier. In order to analyze the effect of rotational energy in the dynamics of {sup 6}Li+{sup 90}Zr reaction, the cross sections have been calculated using the sticking (I{sub S}) and the non-sticking (I{sub NS}) limits of moment of inertia with inclusion of quadrupole (β{sub 2}) deformation within optimum orientation approach. The effect of either of the two approaches on the angular momentum, and hence the rotational energy associated with it, is assessed through the fragment mass distribution, preformation factor and the barrier penetrability. Also, the role of deformations is studied through a comparative analysis of decay path for spherical and β{sub 2} deformed fragmentation. The calculated evaporation residue cross sections show excellent agreement with the reported data at all incident energies for both spherical and β{sub 2}-deformed approach. Finally, the incomplete fusion (ICF) process observed due to loosely bound projectile {sup 6}Li is addressed within the framework of DCM.

  11. Vibrational and Rotational Energy Relaxation in Liquids

    DEFF Research Database (Denmark)

    Petersen, Jakob

    Vibrational and rotational energy relaxation in liquids are studied by means of computer simulations. As a precursor for studying vibrational energy relaxation of a solute molecule subsequent to the formation of a chemical bond, the validity of the classical Bersohn-Zewail model for describing......, the vibrational energy relaxation of I2 subsequent to photodissociation and recombination in CCl4 is studied using classical Molecular Dynamics simulations. The vibrational relaxation times and the time-dependent I-I pair distribution function are compared to new experimental results, and a qualitative agreement...... is found in both cases. Furthermore, the rotational energy relaxation of H2O in liquid water is studied via simulations and a power-and-work analysis. The mechanism of the energy transfer from the rotationally excited H2O molecule to its water neighbors is elucidated, i.e. the energy-accepting degrees...

  12. Shakeoff Ionization near the Coulomb Barrier Energy

    Science.gov (United States)

    Sharma, Prashant; Nandi, T.

    2017-11-01

    We measure the projectile K x-ray spectra as a function of the beam energies around the Coulomb barrier in different collision systems. The energy is scanned in small steps around the barrier aiming to explore the nuclear effects on the elastically scattered projectile ions. The variation of the projectile x-ray energy with the ion-beam energies exhibits an unusual increase in between the interaction barrier and fusion barrier energies. This additional contribution to the projectile ionization can be attributed to the shakeoff of outer-shell electrons of the projectile ions due to the sudden nuclear recoil (˜10-21 sec ) caused by the attractive nuclear potential, which gets switched on near the interaction barrier energy. In the sudden approximation limit, the theoretical shakeoff probability calculation due to the nuclear recoil explains the observed data well. In addition to its fundamental interest, such processes can play a significant role in dark matter detection through the possible mechanism of x-ray emissions, where the weakly interacting massive particle-nucleus elastic scattering can lead to the nuclear-recoil-induced inner-shell vacancy creations. Furthermore, the present work may provide new prospects for atomic physics research at barrier energies as well as provide a novel technique to perform barrier distribution studies for two-body systems.

  13. Experimental and ab initio study on structures and internal barriers to rotation in α-stannyl, germanium, and silicon carbamates

    Science.gov (United States)

    Jadidi, Khosrow; Khaligh, Nader Ghaffari; Islami, Parisa; Aryan, Reza; Arvin-Nezhad, Hamid

    2009-02-01

    A detailed study of structural parameters and internal rotational barriers in α-stannyl, germanium and silicon carbamates 1 [H 3 CX-CH 2-N(Me)CO 2Me X dbnd C, Si, Ge, Sn] were calculated at HF/6-311G, HF/3-21G and B3LYP/3-21G//HF/3-21G levels and compared with DNMR data of synthesized molecules and a literature X-ray data. Two minimum-energy conformers, namely A and B, with almost similar energies were found for these molecules. Effect of heteroatom on structure and relative energies ( Erel) between the participants in the conformational equilibrium (A ↔ B) of these carbamates has been investigated.

  14. Barriers to fusion

    International Nuclear Information System (INIS)

    Berriman, A.C.; Butt, R.D.; Dasgupta, M.; Hinde, D.J.; Morton, C.R.; Newton, J.O.

    1999-01-01

    The fusion barrier is formed by the combination of the repulsive Coulomb and attractive nuclear forces. Recent research at the Australian National University has shown that when heavy nuclei collide, instead of a single fusion barrier, there is a set of fusion barriers. These arise due to intrinsic properties of the interacting nuclei such deformation, rotations and vibrations. Thus the range of barrier energies depends on the properties of both nuclei. The transfer of matter between nuclei, forming a neck, can also affect the fusion process. High precision data have been used to determine fusion barrier distributions for many nuclear reactions, leading to new insights into the fusion process

  15. Toroidal and rotating bubble nuclei and the nuclear fragmentation

    International Nuclear Information System (INIS)

    Royer, G.; Fauchard, C.; Haddad, F.; Jouault, B.

    1997-01-01

    The energy of rotating bubble and toroidal nuclei predicted to be formed in central heavy ion collisions at intermediate energies is calculated within the generalized rotating liquid drop model. Previously, a one-parameter shape sequence has been defined to describe the path leading to pumpkin-like configurations and toroidal shapes. New analytical expressions for the shape dependent functions have been obtained. The potential barriers standing in these exotic deformation paths are compared with the three-dimensional and plane-fragmentation barriers. Metastable bubble-like minima only appear at very high angular momentum and above the three dimensional fragmentation barriers. In the toroidal deformation path of the heaviest systems exists a large potential pocket localized below the plane-fragmentation barriers. This might allow the temporary survival of heavy nuclear toroids before the final clusterization induced by the surface and proximity tension

  16. 9Be+120Sn scattering at near-barrier energies within a four-body model

    Science.gov (United States)

    Arazi, A.; Casal, J.; Rodríguez-Gallardo, M.; Arias, J. M.; Lichtenthäler Filho, R.; Abriola, D.; Capurro, O. A.; Cardona, M. A.; Carnelli, P. F. F.; de Barbará, E.; Fernández Niello, J.; Figueira, J. M.; Fimiani, L.; Hojman, D.; Martí, G. V.; Martínez Heimman, D.; Pacheco, A. J.

    2018-04-01

    Cross sections for elastic and inelastic scattering of the weakly bound 9Be nucleus on a 120Sn target have been measured at seven bombarding energies around and above the Coulomb barrier. The elastic angular distributions are analyzed with a four-body continuum-discretized coupled-channels (CDCC) calculation, which considers 9Be as a three-body projectile (α +α +n ). An optical model analysis using the São Paulo potential is also shown for comparison. The CDCC analysis shows that the coupling to the continuum part of the spectrum is important for the agreement with experimental data even at energies around the Coulomb barrier, suggesting that breakup is an important process at low energies. At the highest incident energies, two inelastic peaks are observed at 1.19(5) and 2.41(5) MeV. Coupled-channels (CC) calculations using a rotational model confirm that the first inelastic peak corresponds to the excitation of the 21+ state in 120Sn, while the second one likely corresponds to the excitation of the 31- state.

  17. Barriers for realisation of energy savings in buildings; Barrierer for realisering af energibesparelser i bygninger

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, O.M.

    2004-07-01

    Many years' efforts within the energy labelling area have shown large saving potentials in heating and use of electricity in buildings. At the same time it has been proved that these saving potentials, even when economically advantageous, only are cashed to a limited extent. The reason to this is ascribed to barriers that meet the individual building owner who wants to start saving energy. Most barriers are known and a lot of these have been sought overcome for some time. The questions are how many barriers still exist, have new barriers arisen and the character of these barriers. On this background the objective of this survey has been to concretize and study the barriers, which are blocking reasonable energy savings. Focus has especially been on barriers for realisation of heating savings, but through a general evaluation of energy savings of barriers other forms of energy saving methods have been taken into consideration. Special interest has been directed towards houses, typically one family houses, which are affected by the Energy Labelling Scheme. The concept barriers include all kinds of barriers, also barriers that not are acknowledged as barriers by the individual house owner, or that on closer inspection turn out to be something else than actual barriers. This note suggests an alternative inertia model, in order to create an idea of the inertness characteristic of the many house owners who understand the message but fail to act on it. (BA)

  18. Rotation and impurity studies in the presence of MHD activity and internal transport barriers on TCV

    Energy Technology Data Exchange (ETDEWEB)

    Federspiel, L. I.

    2014-07-01

    This thesis focuses on measurements of toroidal rotation and impurity profiles in improved plasma scenarios and in the presence of magneto-hydrodynamic (MHD) activity. Experiments were performed on TCV, the Tokamak a Configuration Variable in Lausanne. In TCV, plasma rotation is measured by the charge exchange recombination spectroscopy diagnostic (CXRS). The CXRS is associated with a low power diagnostic neutral beam injector (DNBI) that provides CX emission from the hot plasma core, without perturbing the plasma with additional torque. The beam is observed transversally by the CXRS diagnostic so that local ion temperature, density and intrinsic velocity measurements are obtained. The three systems composing the present day CXRS2013 diagnostic cover the entire TCV radial midplane with up to 80 measurement locations separated by around 7 mm with a time resolution ranging from 2-30 ms. The main upgrades concerned the installation of new sensitive cameras, the overhaul of the toroidal system, the extended-chord configuration and the automation of the acquisition and analysis processes. These new Cars capabilities permitted the investigation of more complex scenarios featuring low intensity and/or fast events, like the low density electron internal transport barriers (eITBs) and the sawtooth (ST) instability. A comparison between rotation profiles measured over several sawtooth events and across a 'canonical' sawtooth cycle has been undertaken in limited L-mode plasmas. The averaged rotation profiles obtained with the upgraded CXRS diagnostic show that ST restrict the maximum attainable and that the rotation profiles are flattened and almost always display a small co-current contribution. It is this effect that results in the 1/I{sub p} scaling observed in TCV limited L-mode plasmas. The co-current core contribution is related to the ST crash, whilst, during the quiescent ramp of the sawtooth period, a plasma recoil outside the mixing radius is observed. A

  19. Rotation and impurity studies in the presence of MHD activity and internal transport barriers on TCV

    International Nuclear Information System (INIS)

    Federspiel, L. I.

    2014-01-01

    This thesis focuses on measurements of toroidal rotation and impurity profiles in improved plasma scenarios and in the presence of magneto-hydrodynamic (MHD) activity. Experiments were performed on TCV, the Tokamak a Configuration Variable in Lausanne. In TCV, plasma rotation is measured by the charge exchange recombination spectroscopy diagnostic (CXRS). The CXRS is associated with a low power diagnostic neutral beam injector (DNBI) that provides CX emission from the hot plasma core, without perturbing the plasma with additional torque. The beam is observed transversally by the CXRS diagnostic so that local ion temperature, density and intrinsic velocity measurements are obtained. The three systems composing the present day CXRS2013 diagnostic cover the entire TCV radial midplane with up to 80 measurement locations separated by around 7 mm with a time resolution ranging from 2-30 ms. The main upgrades concerned the installation of new sensitive cameras, the overhaul of the toroidal system, the extended-chord configuration and the automation of the acquisition and analysis processes. These new Cars capabilities permitted the investigation of more complex scenarios featuring low intensity and/or fast events, like the low density electron internal transport barriers (eITBs) and the sawtooth (ST) instability. A comparison between rotation profiles measured over several sawtooth events and across a 'canonical' sawtooth cycle has been undertaken in limited L-mode plasmas. The averaged rotation profiles obtained with the upgraded CXRS diagnostic show that ST restrict the maximum attainable and that the rotation profiles are flattened and almost always display a small co-current contribution. It is this effect that results in the 1/I p scaling observed in TCV limited L-mode plasmas. The co-current core contribution is related to the ST crash, whilst, during the quiescent ramp of the sawtooth period, a plasma recoil outside the mixing radius is observed. A high

  20. Market and Policy Barriers to Energy Storage Deployment

    Energy Technology Data Exchange (ETDEWEB)

    Bhatnagar, Dhruv [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Currier, Aileen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Hernandez, Jacquelynne [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Ma, Ookie [Dept. of Energy (DOE), Washington DC (United States) Office of Energy Efficiency and Renewable Energy; Kirby, Brendan [Consultant

    2013-09-01

    Electric energy storage technologies can provide numerous grid services; there are a number of factors that restrict their current deployment. The most significant barrier to deployment is high capital costs, though several recent deployments indicate that capital costs are decreasing and energy storage may be the preferred economic alternative in certain situations. However, a number of other market and regulatory barriers persist, limiting further deployment. These barriers can be categorized into regulatory barriers, market (economic) barriers, utility and developer business model barriers, cross-cutting barriers and technology barriers.

  1. Micro-fabricated Liquid Encapsulated Energy Harvester with Polymer Barrier Layer as Liquid Electret Interface

    International Nuclear Information System (INIS)

    Bu, L; Xu, H Y; Xu, B J; Song, L

    2014-01-01

    This paper addresses the electret discharge issue for liquid based electret energy harvesters. An interface structure of PDMS/PTFE polymer barrier layer between liquid and electrets is introduced, achieving 75% charge retain rate over 100h, compared with 0% without the proposed layer over 100h. Further, the PDMS/PTFE layer is introduced into liquid encapsulated energy harvester (LEEH) and is compatible with micro-fabrication process. The retain rate of device voltage is about 47%∼65% over 100h. At 100h after corona charging, the device generates maximally 3.7V, 0.55μW @1Hz rotation

  2. Rotating gravity currents. Part 1. Energy loss theory

    Science.gov (United States)

    Martin, J. R.; Lane-Serff, G. F.

    2005-01-01

    A comprehensive energy loss theory for gravity currents in rotating rectangular channels is presented. The model is an extension of the non-rotating energy loss theory of Benjamin (J. Fluid Mech. vol. 31, 1968, p. 209) and the steady-state dissipationless theory of rotating gravity currents of Hacker (PhD thesis, 1996). The theory assumes the fluid is inviscid, there is no shear within the current, and the Boussinesq approximation is made. Dissipation is introduced using a simple method. A head loss term is introduced into the Bernoulli equation and it is assumed that the energy loss is uniform across the stream. Conservation of momentum, volume flux and potential vorticity between upstream and downstream locations is then considered. By allowing for energy dissipation, results are obtained for channels of arbitrary depth and width (relative to the current). The results match those from earlier workers in the two limits of (i) zero rotation (but including dissipation) and (ii) zero dissipation (but including rotation). Three types of flow are identified as the effect of rotation increases, characterized in terms of the location of the outcropping interface between the gravity current and the ambient fluid on the channel boundaries. The parameters for transitions between these cases are quantified, as is the detailed behaviour of the flow in all cases. In particular, the speed of the current can be predicted for any given channel depth and width. As the channel depth increases, the predicted Froude number tends to surd 2, as for non-rotating flows.

  3. Empirical investigation of energy efficiency barriers in Italian manufacturing SMEs

    International Nuclear Information System (INIS)

    Trianni, Andrea; Cagno, Enrico; Worrell, Ernst; Pugliese, Giacomo

    2013-01-01

    The paper identifies and evaluates barriers to industrial energy efficiency through the investigation of 48 manufacturing Small and Medium-sized Enterprises (SMEs) in Northern Italy. The research provides interesting suggestions both for enterprises and energy policy-makers. Firstly, economic and information barriers are perceived as the major obstacles to the adoption of energy-efficient technologies, whilst behavioural barriers do not seem to affect enterprises very much. Nonetheless, despite what declared, the most relevant barriers are the lack of interest in energy efficiency and the existence of other priorities, thus showing that decision-makers tend to downgrade energy efficiency to a marginal issue. Furthermore, perceived barriers do not take place exclusively in implementing energy-efficient technologies, but, with comparable importance, also in generating the interest and knowledge of the opportunities. Moreover, the study highlights that relevant differences can be appreciated for both perceived and real barriers even among SMEs, that thus should not be bundled together. In addition to that, other factors affect barriers, stimulating future research: indeed, lower real barriers can be observed with higher complexity of the production, high variability of the demand and strong competitors. -- Highlights: ► Evidence of existing misalignments between perceived and real barriers to the adoption of energy-efficient technologies. ► Relevance of barriers to the generation of interest towards energy efficiency. ► Evidence of firm's size (within SMEs) and energy expenditures on barriers to energy efficiency. ► Importance, for energy efficiency barriers, of avoid bundling SMEs as a whole. ► Preliminary evidence of factors related to supply chain complexity affecting barriers to energy efficiency.

  4. Market and policy barriers to energy storage deployment :

    Energy Technology Data Exchange (ETDEWEB)

    Bhatnagar, Dhruv; Currier, Aileen B.; Hernandez, Jacquelynne; Ma, Ookie; Kirby, Brendan

    2013-09-01

    Electric energy storage technologies have recently been in the spotlight, discussed as essential grid assets that can provide services to increase the reliability and resiliency of the grid, including furthering the integration of variable renewable energy resources. Though they can provide numerous grid services, there are a number of factors that restrict their current deployment. The most significant barrier to deployment is high capital costs, though several recent deployments indicate that capital costs are decreasing and energy storage may be the preferred economic alternative in certain situations. However, a number of other market and regulatory barriers persist, limiting further deployment. These barriers can be categorized into regulatory barriers, market (economic) barriers, utility and developer business model barriers, crosscutting barriers and technology barriers. This report, through interviews with stakeholders and review of regulatory filings in four regions roughly representative of the United States, identifies the key barriers restricting further energy storage development in the country. The report also includes a discussion of possible solutions to address these barriers and a review of initiatives around the country at the federal, regional and state levels that are addressing some of these issues. Energy storage could have a key role to play in the future grid, but market and regulatory issues have to be addressed to allow storage resources open market access and compensation for the services they are capable of providing. Progress has been made in this effort, but much remains to be done and will require continued engagement from regulators, policy makers, market operators, utilities, developers and manufacturers.

  5. Fission excitation function for 19F + 194,196,198Pt at near and above barrier energies

    Directory of Open Access Journals (Sweden)

    Singh Varinderjit

    2015-01-01

    Full Text Available Fission excitation functions for 19F + 194,196,198Pt reactions populating 213,215,217Fr compound nuclei are reported. Out of these three compound nuclei, 213Fr is a shell closed (N=126 compound nucleus and the other two are away from the shell closure. From a comparison of the experimental fission cross-sections with the statistical model predictions, it is observed that the fission cross-sections are underestimated by the statistical model predictions using shell corrected finite range rotating liquid drop model (FRLDM fission barriers. Further the FRLDM fission barriers are reduced to fit the fission cross-sections over the entire measured energy range.

  6. Highway renewable energy : photovoltaic noise barriers

    Science.gov (United States)

    2017-07-01

    Highway photovoltaic noise barriers (PVNBs) represent the combination of noise barrier systems and photovoltaic systems in order to mitigate traffic noise while simultaneously producing renewable energy. First deployed in Switzerland in 1989, PVNBs a...

  7. Intrinsic Rotation and Momentum Transport in Reversed Shear Plasmas with Internal Transport Barriers

    Science.gov (United States)

    Jhang, Hogun; Kim, S. S.; Diamond, P. H.

    2010-11-01

    The intrinsic rotation in fusion plasmas is believed to be generated via the residual stress without external momentum input. The physical mechanism responsible for the generation and transport of intrinsic rotation in L- and H-mode tokamak plasmas has been studied extensively. However, it is noted that the physics of intrinsic rotation generation and its relationship to the formation of internal transport barriers (ITBs) in reversed shear (RS) tokamak plasmas have not been explored in detail, which is the main subject in the present work. A global gyrofluid code TRB is used for this study. It is found that the large intrinsic rotation (˜10-30% of the ion sound speed depending on ITB characteristics) is generated near the ITB region and propagates into the core. The intrinsic rotation increases linearly as the temperature gradient at ITB position increases, albeit not indefinitely. Key parameters related to the symmetry breaking, such as turbulent intensity and its gradient, the flux surface averaged parallel wavenumber are evaluated dynamically during the ITB formation. The role of reversed shear and the q-profile curvature is presented in relation to the symmetry breaking mechanism in RS plasmas.

  8. A theoretical study of rotatable renewable energy system for stratospheric airship

    International Nuclear Information System (INIS)

    Lv, Mingyun; Li, Jun; Zhu, Weiyu; Du, Huafei; Meng, Junhui; Sun, Kangwen

    2017-01-01

    Highlights: • A new rotatable renewable energy system is designed for stratospheric airship. • A theoretical model of optimal rotation angle and required area are studied. • The effects of latitude and date on output energy per day are investigated. • The advantages of the rotatable renewable energy system are studied. - Abstract: Renewable energy system is very critical for solving the energy problem of a long endurance stratospheric airship. Output performance of the traditional solar array fixed on the upper surface of the airship remains to be improved to reduce the area and weight of renewable energy system. Inspired by the solar tracking system and kirigami, a rotatable renewable energy system (mainly including solar array) is designed to improve the current status of the energy system. The advantages of the rotatable solar array are studied using a MATLAB computer program based on the theoretical model established in this paper. The improvements in output energy and required area of the solar array were compared between the traditional airship and improved one. Studies had shown that the rotatable renewable energy system made the total weight of energy system decreased by 1000 kg when the maximum design speed of the airship was greater than 22 m/s. The results demonstrate that the rotatable renewable energy system for the airship can be a good way to improve the output performance of solar array, and the conceptual design and theoretical model suggest a pathway towards solving the energy problem of a stratospheric airship.

  9. Barriers to renewable energy development: A case study of large-scale wind energy in Saskatchewan, Canada

    International Nuclear Information System (INIS)

    Richards, Garrett; Noble, Bram; Belcher, Ken

    2012-01-01

    Renewable energy is receiving increased attention as a viable alternative to non-renewable electrical generation, however, meeting global energy demands will require a more ambitious renewable energy program than is currently the case. There have been several reviews of potential technological, economic, social, or public barriers and solutions to renewable energy investment. Although important, there is also need for multi-dimensional analyses of these barriers and identification of the most significant underlying barriers if viable solutions are to be developed. In this paper we apply a theoretical framework to examine stakeholder's perceptions and understanding of the barriers to wind energy development in Saskatchewan, Canada. We identify and examine the most significant underlying barriers to investment in renewable energy and the interactions between those barriers. Results show a number of perceived barriers to wind energy investment, however, these barriers can be explained in large part by knowledge barriers, if not disagreement over whether the current level of investment in wind energy is sufficient. We show that barriers to renewable energy cannot be explained solely by technological, social, political, or economic factors in isolation, and that a multi-dimensional approach, identifying and explaining the underlying sources of these barriers, is necessary to develop viable solutions. - Highlights: ► Meeting future wind energy objectives requires an ambitious investment program. ► A framework is applied to identify and explain perceived barriers to wind energy. ► Stakeholders perceived technological and political barriers as the most significant. ► These could be explained by knowledge barriers and complacency with the status quo. ► Even with additional investment these underlying barriers will constrain progress.

  10. Massive star formation by accretion. II. Rotation: how to circumvent the angular momentum barrier?

    Science.gov (United States)

    Haemmerlé, L.; Eggenberger, P.; Meynet, G.; Maeder, A.; Charbonnel, C.; Klessen, R. S.

    2017-06-01

    Context. Rotation plays a key role in the star-formation process, from pre-stellar cores to pre-main-sequence (PMS) objects. Understanding the formation of massive stars requires taking into account the accretion of angular momentum during their PMS phase. Aims: We study the PMS evolution of objects destined to become massive stars by accretion, focusing on the links between the physical conditions of the environment and the rotational properties of young stars. In particular, we look at the physical conditions that allow the production of massive stars by accretion. Methods: We present PMS models computed with a new version of the Geneva Stellar Evolution code self-consistently including accretion and rotation according to various accretion scenarios for mass and angular momentum. We describe the internal distribution of angular momentum in PMS stars accreting at high rates and we show how the various physical conditions impact their internal structures, evolutionary tracks, and rotation velocities during the PMS and the early main sequence. Results: We find that the smooth angular momentum accretion considered in previous studies leads to an angular momentum barrier and does not allow the formation of massive stars by accretion. A braking mechanism is needed in order to circumvent this angular momentum barrier. This mechanism has to be efficient enough to remove more than two thirds of the angular momentum from the inner accretion disc. Due to the weak efficiency of angular momentum transport by shear instability and meridional circulation during the accretion phase, the internal rotation profiles of accreting stars reflect essentially the angular momentum accretion history. As a consequence, careful choice of the angular momentum accretion history allows circumvention of any limitation in mass and velocity, and production of stars of any mass and velocity compatible with structure equations.

  11. Energy transfer in turbulence under rotation

    Science.gov (United States)

    Buzzicotti, Michele; Aluie, Hussein; Biferale, Luca; Linkmann, Moritz

    2018-03-01

    It is known that rapidly rotating turbulent flows are characterized by the emergence of simultaneous upscale and downscale energy transfer. Indeed, both numerics and experiments show the formation of large-scale anisotropic vortices together with the development of small-scale dissipative structures. However the organization of interactions leading to this complex dynamics remains unclear. Two different mechanisms are known to be able to transfer energy upscale in a turbulent flow. The first is characterized by two-dimensional interactions among triads lying on the two-dimensional, three-component (2D3C)/slow manifold, namely on the Fourier plane perpendicular to the rotation axis. The second mechanism is three-dimensional and consists of interactions between triads with the same sign of helicity (homochiral). Here, we present a detailed numerical study of rotating flows using a suite of high-Reynolds-number direct numerical simulations (DNS) within different parameter regimes to analyze both upscale and downscale cascade ranges. We find that the upscale cascade at wave numbers close to the forcing scale is generated by increasingly dominant homochiral interactions which couple the three-dimensional bulk and the 2D3C plane. This coupling produces an accumulation of energy in the 2D3C plane, which then transfers energy to smaller wave numbers thanks to the two-dimensional mechanism. In the forward cascade range, we find that the energy transfer is dominated by heterochiral triads and is dominated primarily by interaction within the fast manifold where kz≠0 . We further analyze the energy transfer in different regions in the real-space domain. In particular, we distinguish high-strain from high-vorticity regions and we uncover that while the mean transfer is produced inside regions of strain, the rare but extreme events of energy transfer occur primarily inside the large-scale column vortices.

  12. Overcoming energy efficiency barriers through systems approach—A conceptual framework

    International Nuclear Information System (INIS)

    Chai, Kah-Hin; Yeo, Catrina

    2012-01-01

    In this paper we propose a framework which categorizes energy efficiency barriers based on the stage at which the barriers exist. Barriers to energy efficiency have been widely studied but to our knowledge, except for a few studies, we found inadequate consideration for barrier–barrier interactions when proposing policy measures for improving energy efficiency. Leveraging systems thinking's power as a problem solver which identifies underlying structure that explains (similar) patterns of behavior in a variety of different situations, we attempted to identify patterns of barriers to adoption of energy efficiency measures in industrial companies. Inspired by systems thinking, the proposed framework has four stages, namely, Motivation, Capability, Implementation and Results, as well as a feedback loop. Using a case study, we show that following the four stages will lead to positive feedback for future energy efficiency implementations. The framework highlights the interconnected nature of the barriers and a need for policymakers to address these barriers in a holistic manner. We argue that the overall effectiveness of energy efficiency policies is only as strong as the weakest link in the four-stage framework. This differs from most prior research that addressed barriers in isolation, where a solution is proposed for each of the barriers without considering the relationship between the barriers. Our framework also offers a way to understand the roles and responsibilities of major stakeholders such as governments and energy service companies (ESCOs) in driving energy efficiency. This allows the assessment and identification of weak links in energy efficiency policies. - Highlights: ► We propose a systems approach to overcome energy efficiency barriers. ► Barriers are grouped into Motivation, Capability, Implementation and Results. ► Case study shows that there is a feedback loop from Results to Motivation. ► Current Results will affect future Motivation.

  13. Ultra high energy electrons powered by pulsar rotation.

    Science.gov (United States)

    Mahajan, Swadesh; Machabeli, George; Osmanov, Zaza; Chkheidze, Nino

    2013-01-01

    A new mechanism of particle acceleration, driven by the rotational slow down of the Crab pulsar, is explored. The rotation, through the time dependent centrifugal force, can efficiently excite unstable Langmuir waves in the electron-positron (hereafter e(±)) plasma of the star magnetosphere. These waves, then, Landau damp on electrons accelerating them in the process. The net transfer of energy is optimal when the wave growth and the Landau damping times are comparable and are both very short compared to the star rotation time. We show, by detailed calculations, that these are precisely the conditions for the parameters of the Crab pulsar. This highly efficient route for energy transfer allows the electrons in the primary beam to be catapulted to multiple TeV (~ 100 TeV) and even PeV energy domain. It is expected that the proposed mechanism may, unravel the puzzle of the origin of ultra high energy cosmic ray electrons.

  14. Parametric modeling of energy filtering by energy barriers in thermoelectric nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Zianni, Xanthippi, E-mail: xzianni@teiste.gr, E-mail: xzianni@gmail.com [Department of Aircraft Technology, Technological Educational Institution of Sterea Ellada, 34400 Psachna (Greece); Department of Microelectronics, INN, NCSR “Demokritos,” 15310 Athens (Greece); Narducci, Dario [Department of Materials Science, University of Milano Bicocca, 20125 Milano (Italy)

    2015-01-21

    We present a parametric modeling of the thermoelectric transport coefficients based on a model previously used to interpret experimental measurements on the conductivity, σ, and Seebeck coefficient, S, in highly Boron-doped polycrystalline Si, where a very significant thermoelectric power factor (TPF) enhancement was observed. We have derived analytical formalism for the transport coefficients in the presence of an energy barrier assuming thermionic emission over the barrier for (i) non-degenerate and (ii) degenerate one-band semiconductor. Simple generic parametric equations are found that are in agreement with the exact Boltzmann transport formalism in a wide range of parameters. Moreover, we explore the effect of energy barriers in 1-d composite semiconductors in the presence of two phases: (a) the bulk-like phase and (b) the barrier phase. It is pointed out that significant TPF enhancement can be achieved in the composite structure of two phases with different thermal conductivities. The TPF enhancement is estimated as a function of temperature, the Fermi energy position, the type of scattering, and the barrier height. The derived modeling provides guidance for experiments and device design.

  15. Rotating flux compressor for energy conversion

    International Nuclear Information System (INIS)

    Chowdhuri, P.; Linton, T.W.; Phillips, J.A.

    1983-01-01

    The rotating flux compressor (RFC) converts rotational kinetic energy into an electrical output pulse which would have higher energy than the electrical energy initially stored in the compressor. An RFC has been designed in which wedge-shaped rotor blades pass through the air gaps between successive turns of a solenoid, the stator. Magnetic flux is generated by pulsing the stator solenoids when the inductance is a maximum, i.e., when the flux fills the stator-solenoid volume. Connecting the solenoid across a load conserves the flux which is compressed within the small volume surrounding the stator periphery when the rotor blades cut into the free space between the stator plates, creating a minimum-inductance condition. The unique features of this design are: (1) no electrical connections (brushes) to the rotor; (2) no conventional windings; and (3) no maintenance. The device has been tested up to 5000 rpm of rotor speed

  16. Energy analysis of vehicle-to-cable barrier impacts.

    Science.gov (United States)

    2013-06-01

    An accident reconstruction technique was developed for estimating the energy absorbed during an impact with a cable barrier system as well as the initial impact velocity. The kinetic energy absorbed during a cable barrier system impact is comprised o...

  17. The influence of molecular rotation on vibration--translation energy transfer

    International Nuclear Information System (INIS)

    McKenzie, R.L.

    1977-01-01

    The role of molecular rotations in the exchange of vibrational and translational energy is investigated for collisions between anharmonic diatomic molecules and structureless atoms. A three-dimensional, semiclassical, impact parameter description is applied with emphasis directed towards the influence of rotational coupling on the net rate of vibrational energy transfer summed over all final rotational states. These results are then related to the predictions of an equivalent collinear collision model, and their comparison allows an evaluation of the collinear approximation. The mechanisms of vibrational energy transfer including rotational transitions are shown to be separable into three classes, with the molecules belonging to each class identified first and foremost by their ratio of fundamental vibrational and rotational frequencies, ω/sub e//B/sub e/, and second by the proximity of their initial state to a near-resonant vibration--rotation transition with a small change in angular momentum. While the dynamics of molecules with ω/sub e//B/sub e/ ratios that are comparable to the range of angular momentum transitions having strong coupling are found to require a complete three-dimensional description, the rates of vibrational energy transfer in molecules with large ω/sub e//B/sub e/ ratios appear to be well approximated by a collinear collision model

  18. Nontechnical Barriers to Solar Energy Use: Review of Recent Literature

    Energy Technology Data Exchange (ETDEWEB)

    Margolis, R.; Zuboy, J.

    2006-09-01

    This paper reviews the nontechnical barriers to solar energy use, drawing on recent literature to help identify key barriers that must be addressed as part of the Technology Acceptance efforts under the U.S. Department of Energy (DOE) Solar America Initiative. A broad literature search yielded more than 400 references, which were narrowed to 19 recent documents on nontechnical barriers to the use of solar energy and other energy efficiency and renewable energy (EE/RE) technologies. Some of the most frequently identified barriers included lack of government policy supporting EE/RE, lack of information dissemination and consumer awareness about energy and EE/RE, high cost of solar and other EE/RE technologies compared with conventional energy, and inadequate financing options for EE/RE projects.

  19. Vacuum energy of the electromagnetic field in a rotating system

    International Nuclear Information System (INIS)

    Hacyan, S.; Sarmiento, A.

    1986-01-01

    The vacuum energy of the electromagnetic field is calculated for a uniformly rotating observer. The spectrum of vacuum fluctuations is composed of the zero-point energy with a modified density of states and a contribution due to the rotation which is not thermal. (orig.)

  20. Investing in Energy Efficiency. Removing the Barriers

    International Nuclear Information System (INIS)

    2004-01-01

    Investing in improving energy efficiency has the clear advantages of reducing energy costs, improving security of supply and mitigating the environmental impacts of energy use. And still, many viable opportunities for higher energy efficiency are not tapped because of the existence of numerous barriers to such investments. These lost opportunities imply costs to the individual energy consumers and to the society as a whole and they are particularly important in economies in transition. This report identifies various types of barriers for making energy efficiency investments (be they of legal, administrative, institutional or financial nature), mainly in buildings, district heating and efficient lighting. The role of various bodies and organisations for the facilitation of energy efficiency investments is analysed, from public authorities and regulators to banks and international financing institutions

  1. A piezoelectric energy harvester for broadband rotational excitation using buckled beam

    Science.gov (United States)

    Xie, Zhengqiu; Kitio Kwuimy, C. A.; Wang, Zhiguo; Huang, Wenbin

    2018-01-01

    This paper proposes a rotational energy harvester using a piezoelectric bistable buckled beam to harvest low-speed rotational energy. The proposed harvester consists of a piezoelectric buckled beam with a center magnet, and a rotary magnet pair with opposite magnetic poles mounted on a revolving host. The magnetic plucking is used to harvest the angular kinetic energy of the host. The nonlinear snap-through mechanism is utilized to improve the vibration displacement and output voltage of the piezoelectric layer over a wide rotation frequency range. Theoretical simulation and experimental results show that the proposed energy harvester can yield a stable average output power ranging between 6.91-48.01 μW over a rotation frequency range of 1-14 Hz across a resistance load of 110 kΩ. Furthermore, dual attraction magnets were employed to overcome the suppression phenomenon at higher frequencies, which yields a broadband and flat frequency response over 6-14 Hz with the output power reaching 42.19-65.44 μW, demonstrating the great potential of the bistable buckled beam for wideband rotation motion energy harvesting.

  2. A piezoelectric energy harvester for broadband rotational excitation using buckled beam

    Directory of Open Access Journals (Sweden)

    Zhengqiu Xie

    2018-01-01

    Full Text Available This paper proposes a rotational energy harvester using a piezoelectric bistable buckled beam to harvest low-speed rotational energy. The proposed harvester consists of a piezoelectric buckled beam with a center magnet, and a rotary magnet pair with opposite magnetic poles mounted on a revolving host. The magnetic plucking is used to harvest the angular kinetic energy of the host. The nonlinear snap-through mechanism is utilized to improve the vibration displacement and output voltage of the piezoelectric layer over a wide rotation frequency range. Theoretical simulation and experimental results show that the proposed energy harvester can yield a stable average output power ranging between 6.91-48.01 μW over a rotation frequency range of 1-14 Hz across a resistance load of 110 kΩ. Furthermore, dual attraction magnets were employed to overcome the suppression phenomenon at higher frequencies, which yields a broadband and flat frequency response over 6-14 Hz with the output power reaching 42.19-65.44 μW, demonstrating the great potential of the bistable buckled beam for wideband rotation motion energy harvesting.

  3. Role of rotational energy component in the dynamics of 16O+198Pt reaction

    Directory of Open Access Journals (Sweden)

    Sharma Manoj K.

    2017-01-01

    Full Text Available The role of rotational energy is investigated in reference to the dynamics of 16O+198Pt →214Rn∗ reaction using the sticking (IS and the non-sticking (INS limits of moment of inertia within the framework of dynamical cluster decay model. The decay barrier height and barrier position get significantly modified for the use of sticking or non-sticking choice, which in turn reproduce the evaporation residue and the fusion-fission cross-sections nicely by the IS approach, while the INS approach provides feasible addressal of data only for evaporation residue channel. Moreover, the fragmentation path of decaying fragments of 214Rn∗ compound nucleus gets influenced for different choices of moment of inertia. Beside this, the role of nuclear deformations i.e. static, dynamic quadurpole (β2 and higher order static deformation up to β4 are duly investigated for both choices of the moment of inertia.

  4. Reducing barriers to energy efficiency in the German energy service companies sector. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Koewener, D.; Schleich, J.

    2000-12-01

    This report describes the empirical research conducted in the German energy service sector to assess to what extent energy service companies (ESCOs) can help overcome the barriers to energy in the higher education, brewing and mechanical engineering sectors. This report complements the sector for Germany within the BARRIERS project (Sorrell et al., 2000; Schleich/Boede 2000a; Schleich/Boede 2000b; Schleich et al., 2000). The report characterises the German energy service sector, contains a description and analysis of four case studies in the energy service sector, identifies the main barriers and chances for ESCOs in the higher education, brewery and mechanical engineering sectors, and concludes with brief recommendations on how these barriers may be overcome. The results of the study are summarised here under the following headings: Characterising the energy service sector in Germany; - Case studies of energy service companies in Germany; - The role of ESCOs in the case-study sectors; - Policy implications. (orig.)

  5. Renewable energy costs, potentials, barriers: Conceptual issues

    International Nuclear Information System (INIS)

    Verbruggen, Aviel; Fischedick, Manfred; Moomaw, William; Weir, Tony; Nadai, Alain; Nilsson, Lars J.; Nyboer, John; Sathaye, Jayant

    2010-01-01

    Renewable energy can become the major energy supply option in low-carbon energy economies. Disruptive transformations in all energy systems are necessary for tapping widely available renewable energy resources. Organizing the energy transition from non-sustainable to renewable energy is often described as the major challenge of the first half of the 21st century. Technological innovation, the economy (costs and prices) and policies have to be aligned to achieve full renewable energy potentials, and barriers impeding that growth need to be removed. These issues are also covered by IPCC's special report on renewable energy and climate change to be completed in 2010. This article focuses on the interrelations among the drivers. It clarifies definitions of costs and prices, and of barriers. After reviewing how the third and fourth assessment reports of IPCC cover mitigation potentials and commenting on definitions of renewable energy potentials in the literature, we propose a consistent set of potentials of renewable energy supplies.

  6. Gyrofluid Simulations of Intrinsic Rotation Generation in Reversed Shear Plasmas with Internal Transport Barriers

    Science.gov (United States)

    Jhang, Hogun; Kim, S. S.; Kwon, J. M.; Terzolo, L.; Kim, J. Y.; Diamond, P. H.

    2010-11-01

    It is accepted that the intrinsic rotation is generated via the residual stress, which is non-diffusive components of the turbulent Reynolds stress, without external momentum input. The physics leading to the onset of intrinsic rotation in L- and H- mode plasmas have been elucidated elsewhere. However, the physics responsible for the generation and transport of the intrinsic rotation and its relationship to the formation of internal transport barriers (ITBs) in reversed shear (RS) plasmas have not been explored in detail, which is the main subject in the present work. The revised version of the global gyrofluid code TRB is used for this study. It is found that the large intrinsic rotation (˜10-30% of the ion sound speed depending on ITB characteristics) is generated near the ITB region and propagates into the core. The intrinsic rotation increases linearly as the temperature gradient at ITB position increases, albeit not indefinitely. Key parameters related to the symmetry breaking, such as turbulent intensity and its gradient, the flux surface averaged parallel wavenumber are evaluated dynamically during the ITB formation. In particular, the role of reversed shear and the q-profile curvature is presented in relation to the symmetry breaking in RS plasmas.

  7. Barriers' and policies' analysis of China's building energy efficiency

    International Nuclear Information System (INIS)

    Zhang, Yurong; Wang, Yuanfeng

    2013-01-01

    With the rapid economic growth and the improvement of people's living standards, China's building energy consumption has kept rising during the past 15 years. Under the effort of the Chinese government and the society, China's building energy efficiency has made certain achievements. However, the implementation of building energy efficiency in China is still far from its potential. Based on the analysis of the existing policies implemented in China, the article concluded that the most essential and the most effective ways to promote building energy efficiency is the government's involvement as well as economic and financial incentives. In addition, the main barriers in the process of promoting building energy efficiency in China are identified in six aspects. It has been found that the legal system and administrative issues constitute major barriers, and the lack of financial incentives and the mismatching of market mechanism also hamper the promotion of building energy efficiency. Finally, in view of the existing policies and barriers analysis, three corresponding policy proposals are presented. -- Highlights: •The existing policies implemented in China from three aspects are presented and analysed. •The Government's involvement is the most essential effective way to promote building-energy efficiency. •Six aspects of barriers in promoting building energy efficiency in China are identified. •The legal system and administrative issues constitute the major barriers. •Three policy proposals to further promote building energy efficiency in China are proposed

  8. The free energy barrier for arginine gating charge translation is altered by mutations in the voltage sensor domain.

    Directory of Open Access Journals (Sweden)

    Christine S Schwaiger

    Full Text Available The gating of voltage-gated ion channels is controlled by the arginine-rich S4 helix of the voltage-sensor domain moving in response to an external potential. Recent studies have suggested that S4 moves in three to four steps to open the conducting pore, thus visiting several intermediate conformations during gating. However, the exact conformational changes are not known in detail. For instance, it has been suggested that there is a local rotation in the helix corresponding to short segments of a 3(10-helix moving along S4 during opening and closing. Here, we have explored the energetics of the transition between the fully open state (based on the X-ray structure and the first intermediate state towards channel closing (C1, modeled from experimental constraints. We show that conformations within 3 Å of the X-ray structure are obtained in simulations starting from the C1 model, and directly observe the previously suggested sliding 3(10-helix region in S4. Through systematic free energy calculations, we show that the C1 state is a stable intermediate conformation and determine free energy profiles for moving between the states without constraints. Mutations indicate several residues in a narrow hydrophobic band in the voltage sensor contribute to the barrier between the open and C1 states, with F233 in the S2 helix having the largest influence. Substitution for smaller amino acids reduces the transition cost, while introduction of a larger ring increases it, largely confirming experimental activation shift results. There is a systematic correlation between the local aromatic ring rotation, the arginine barrier crossing, and the corresponding relative free energy. In particular, it appears to be more advantageous for the F233 side chain to rotate towards the extracellular side when arginines cross the hydrophobic region.

  9. Energy management action plan: Developing a strategy for overcoming institutional barriers to municipal energy conservation

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    Energy offices working to improve efficiency of local government facilities face not only technical tasks, but institutional barriers, such as budget structures that do not reward efficiency, a low awareness of energy issues, and purchasing procedures based only on minimizing initial cost. The bureau, in working to remove such barriers in San Francisco, has identified 37 institutional barriers in areas such as operations & maintenance, purchasing, and facility design; these barriers were then reorganized into three groupings-- policy & attitudes, budget & incentives, and awareness & information-- and mapped. This map shows that the barriers mutually reinforce each other, and that a holistic approach is required for permanent change. The city`s recreation & parks department was used as a model department, and information about facility energy use was compiled into a departmental energy review. Staff interviews showed how barriers affect conservation. The bureau then generated ideas for projects to remove specific barriers and rated them according to potential impact and the resources required to implement them. Four of the six projects selected focused on maintenance staff: a cost- sharing lighting retrofit program, a boiler efficiency program, a departmental energy tracking system, and a budgetary incentive program for conservation. The other two projects are city-wide: promotion of a new term contract supplying energy-efficient light materials, and publication/distribution of ENERGY NEWS newsletter. A general methodology, the EMAP Strategy Guide, has been created to assist other energy offices in developing EMAPs.

  10. Analysis of interactions among the barriers to energy saving in China

    International Nuclear Information System (INIS)

    Wang Guohong; Wang Yunxia; Zhao Tao

    2008-01-01

    Since China became the second largest energy consumer and carbon dioxide emitter, the problem of energy consumption and environmental pollution has drawn the world's attention. Meanwhile, Chinese government has put high emphasis on the problem. One project of energy saving initiated by Chinese government has been put into practice. However, many difficulties need to be dealt with to meet the expected aim of social development. The objective of this article is to investigate the interactions among the major barriers which prevent the practice of energy saving in China. Obviously, a clear definition of relationships among the barriers to energy saving helps top leaders make relevant decisions to solve the problem of economic sustainability, energy security and environment pollution in the future. To date, studies specifying energy-saving barriers have often focused on analyzing these barriers separately. As a result, a holistic view in understanding the barriers to energy-saving project is lacking. Interpretive structural modeling (ISM) is utilized to summarize the critical barriers hindering the project of energy saving in China and to explain the interrelationships among them. Suggestions for energy-saving practice and future research are provided

  11. Non-resonant energy harvester with elastic constraints for low rotating frequencies

    Science.gov (United States)

    Machado, Sebastián P.; Febbo, Mariano; Gatti, Claudio D.; Ramirez, José M.

    2017-11-01

    This paper presents a non-resonant piezoelectric energy harvester (PEH) which is designed to capture energy from low frequency rotational vibration. The proposed device works out of the plane of rotation where the motion of a mass-spring system is transferred to a piezoelectric layer with the intention to generate energy to power wireless structural monitoring systems or sensors. The mechanical structure is formed by two beams with rigid and elastic boundary conditions at the clamped end. On the free boundaries, heavy masses connected by a spring are placed in order to increase voltage generation and diminish the natural frequency. A mathematical framework and the equations governing the energy-harvesting system are presented. Numerical simulations and experimental verifications are performed for different rotation speeds ranging from 0.7 to 2.5 Hz. An output power of 125 μW is obtained for maximum rotating frequency demonstrating that the proposed design can collect enough energy for the suggested application.

  12. Measurement and Analysis of Rotational Energy of Nitrogen Molecular Beam by REMPI

    International Nuclear Information System (INIS)

    Mori, H.; Yamaguchi, H.; Kataoka, K.; Sugiyama, N.; Ide, K.; Niimi, T.

    2008-01-01

    Molecular beams are powerful tools for diagnoses of solid surfaces and gas-surface interaction tests. Unfortunately, there are very few reports about experimental analysis of internal energy distribution (e.g. rotational energy) of molecular beams of diatomic or polyatomic molecules, because measurement of internal energy distribution is very difficult. Spectroscopic measurement techniques based on resonantly enhanced multiphoton ionization (REMPI) is very powerful for measurement in highly rarefied gas flows. In this study, the REMPI method is applied to measurement of rotational energy distribution of nitrogen molecular beams. The REMPI spectrum of the molecular beam indicates the rotational temperature higher than the translational temperature of 7.2 K estimated by assuming isentropic flows. The O and P branches of the REMPI spectrum correspond to the rotational temperature of 30 K, but the S branch of the spectrum deviates from that at 30 K. It seems to be because the non-equilibrium rotational energy distribution of the molecular beam deviates from the Boltzmann distribution.

  13. Fusion of 6Li with 159Tb at near-barrier energies

    International Nuclear Information System (INIS)

    Pradhan, M. K.; Mukherjee, A.; Basu, P.; Goswami, A.; Kshetri, R.; Roy, Subinit; Chowdhury, P. Roy; Sarkar, M. Saha; Palit, R.; Parkar, V. V.; Santra, S.; Ray, M.

    2011-01-01

    Complete and incomplete fusion cross sections for 6 Li + 159 Tb have been measured at energies around the Coulomb barrier by the γ-ray method. The measurements show that the complete fusion cross sections at above-barrier energies are suppressed by ∼34% compared to coupled-channel calculations. A comparison of the complete fusion cross sections at above-barrier energies with the existing data for 11,10 B + 159 Tb and 7 Li + 159 Tb shows that the extent of suppression is correlated with the α separation energies of the projectiles. It has been argued that the Dy isotopes produced in the reaction 6 Li + 159 Tb at below-barrier energies are primarily due to the d transfer to unbound states of 159 Tb, while both transfer and incomplete fusion processes contribute at above-barrier energies.

  14. Barriers to renewable energy penetration. A framework for analysis

    DEFF Research Database (Denmark)

    Painuly, Jyoti P.

    2001-01-01

    Renewable energy has the potential to play an important role in providing energy with sustainability to the vast populations in developing countries who as yet have no access to clean energy. Although economically viable fur several applications, renewable energy has not been able to realise its...... potential due to several barriers to its penetration. A framework has been developed in this paper to identify the barriers to renewable energy penetration acid to suggest measures to overcome them. (C) 2001 Elsevier Science Ltd. All rights reserved....

  15. 7Li breakup polarization potential at near barrier energies

    International Nuclear Information System (INIS)

    Lubian, J. . E-mail lubian@if.uff.br; Correa, T.; Paes, B.; Figueira, J.M.; Abriola, D.; Fernandez Niello, J.O.; Arazi, A.; Capurro, O.A.; de Barbara, E.; Marti, G.V.; Martinez Heinmann, D.; Negri, A.E.; Pacheco, A.J.; Padron, I.; Gomes, P.R.S.

    2007-01-01

    Inelastic and one neutron transfer cross sections at energies around the Coulomb barrier were used to derive dynamic polarization potential (DPP) for the 7 Li + 27 Al system. The DPP due to breakup, obtained in a simple way, indicates that its real part is repulsive at near barrier energies

  16. Barriers to and drivers for energy efficiency in the Swedish foundry industry

    International Nuclear Information System (INIS)

    Rohdin, Patrik; Thollander, Patrik; Solding, Petter

    2007-01-01

    Despite the need for increased industrial energy efficiency, studies indicate that cost-efficient energy conservation measures are not always implemented, explained by the existence of barriers to energy efficiency. This paper investigates the existence of different barriers to and driving forces for the implementation of energy efficiency measures in the energy intensive Swedish foundry industry. The overall results from a questionnaire show that limited access to capital constitutes by far the largest barrier to energy efficiency according to the respondents. A comparison between group-owned and privately owned foundries shows that, except for limited access to capital, they face different high-ranked barriers. While barriers within group owned companies are more related to organizational problems, barriers within private foundries are more related to information problems. This study also found that energy consultants or other actors working with energy issues in foundries are of major importance in overcoming the largest barriers, as the foundries consider them trustworthy. They may thus help the foundries overcome organizational problems such as lack of sub-metering and lack of budget funds by quantifying potential energy efficiency investments. The two, by far, most important drivers were found to be people with real ambition and long-term energy strategies

  17. Energy barrier to decoherence

    International Nuclear Information System (INIS)

    Mizel, Ari; Mitchell, M. W.; Cohen, Marvin L.

    2001-01-01

    We propose a ground-state approach to realizing quantum computers. This scheme is time-independent and inherently defends against decoherence by possessing an energy barrier to excitation. We prove that our time-independent qubits can perform the same algorithms as their time-dependent counterparts. Advantages and disadvantages of the time-independent approach are described. A model involving quantum dots is provided for illustration

  18. Linear and non-linear energy barriers in systems of interacting single-domain ferromagnetic particles

    International Nuclear Information System (INIS)

    Petrila, Iulian; Bodale, Ilie; Rotarescu, Cristian; Stancu, Alexandru

    2011-01-01

    A comparative analysis between linear and non-linear energy barriers used for modeling statistical thermally-excited ferromagnetic systems is presented. The linear energy barrier is obtained by new symmetry considerations about the anisotropy energy and the link with the non-linear energy barrier is also presented. For a relevant analysis we compare the effects of linear and non-linear energy barriers implemented in two different models: Preisach-Neel and Ising-Metropolis. The differences between energy barriers which are reflected in different coercive field dependence of the temperature are also presented. -- Highlights: → The linear energy barrier is obtained from symmetry considerations. → The linear and non-linear energy barriers are calibrated and implemented in Preisach-Neel and Ising-Metropolis models. → The temperature and time effects of the linear and non-linear energy barriers are analyzed.

  19. Energy transfer in scattering by rotating potentials

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Quantum mechanical scattering theory is studied for time-dependent. Schrödinger ... the energy transferred to a particle by collision with a rotating blade. Keywords. ..... terms of the unitary group for some time-independent generator. This will ...

  20. Urban sound energy reduction by means of sound barriers

    Science.gov (United States)

    Iordache, Vlad; Ionita, Mihai Vlad

    2018-02-01

    In urban environment, various heating ventilation and air conditioning appliances designed to maintain indoor comfort become urban acoustic pollution vectors due to the sound energy produced by these equipment. The acoustic barriers are the recommended method for the sound energy reduction in urban environment. The current sizing method of these acoustic barriers is too difficult and it is not practical for any 3D location of the noisy equipment and reception point. In this study we will develop based on the same method a new simplified tool for acoustic barriers sizing, maintaining the same precision characteristic to the classical method. Abacuses for acoustic barriers sizing are built that can be used for different 3D locations of the source and the reception points, for several frequencies and several acoustic barrier heights. The study case presented in the article represents a confirmation for the rapidity and ease of use of these abacuses in the design of the acoustic barriers.

  1. Urban sound energy reduction by means of sound barriers

    Directory of Open Access Journals (Sweden)

    Iordache Vlad

    2018-01-01

    Full Text Available In urban environment, various heating ventilation and air conditioning appliances designed to maintain indoor comfort become urban acoustic pollution vectors due to the sound energy produced by these equipment. The acoustic barriers are the recommended method for the sound energy reduction in urban environment. The current sizing method of these acoustic barriers is too difficult and it is not practical for any 3D location of the noisy equipment and reception point. In this study we will develop based on the same method a new simplified tool for acoustic barriers sizing, maintaining the same precision characteristic to the classical method. Abacuses for acoustic barriers sizing are built that can be used for different 3D locations of the source and the reception points, for several frequencies and several acoustic barrier heights. The study case presented in the article represents a confirmation for the rapidity and ease of use of these abacuses in the design of the acoustic barriers.

  2. Sensorless Estimation and Nonlinear Control of a Rotational Energy Harvester

    Science.gov (United States)

    Nunna, Kameswarie; Toh, Tzern T.; Mitcheson, Paul D.; Astolfi, Alessandro

    2013-12-01

    It is important to perform sensorless monitoring of parameters in energy harvesting devices in order to determine the operating states of the system. However, physical measurements of these parameters is often a challenging task due to the unavailability of access points. This paper presents, as an example application, the design of a nonlinear observer and a nonlinear feedback controller for a rotational energy harvester. A dynamic model of a rotational energy harvester with its power electronic interface is derived and validated. This model is then used to design a nonlinear observer and a nonlinear feedback controller which yield a sensorless closed-loop system. The observer estimates the mechancial quantities from the measured electrical quantities while the control law sustains power generation across a range of source rotation speeds. The proposed scheme is assessed through simulations and experiments.

  3. Reducing barriers to energy efficiency in the German brewing sector. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, J; Boede, U; Ostertag, K; Radgen, P

    2000-12-01

    This report describes the empirical research into barriers to energy efficiency in the German brewing sector. It is one of nine such reports in the BARRIERS project. The report contains description and analysis of five case studies of energy management in German breweries. The results are analysed using the theoretical framework developed for the BARRIERS project. The report also provides brief recommendations on how these barriers to the rational use of energy (RUE) may be overcome and how energy efficiency within the brewing sector may be improved. The results of the study for the brewing sector in Germany are summarised in this executive summary under the following headings: - Characterising the brewing sector - Case studies of energy management in the German brewing sector; - Evidence of barriers in the German brewing sector; - The role of energy service companies in the brewing sector; - Policy implications. (orig.)

  4. Reducing barriers to energy efficiency in the German brewing sector. Executive Summary

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, J.; Boede, U.; Ostertag, K.; Radgen, P.

    2000-12-01

    This report describes the empirical research into barriers to energy efficiency in the German brewing sector. It is one of nine such reports in the BARRIERS project. The report contains description and analysis of five case studies of energy management in German breweries. The results are analysed using the theoretical framework developed for the BARRIERS project. The report also provides brief recommendations on how these barriers to the rational use of energy (RUE) may be overcome and how energy efficiency within the brewing sector may be improved. The results of the study for the brewing sector in Germany are summarised in this executive summary under the following headings: - Characterising the brewing sector; - Case studies of energy management in the German brewing sector; - Evidence of barriers in the German brewing sector; - The role of energy service companies in the brewing sector; - Policy implications. (orig.)

  5. Compact passively self-tuning energy harvesting for rotating applications

    International Nuclear Information System (INIS)

    Gu, Lei; Livermore, Carol

    2012-01-01

    This paper presents a compact, passive, self-tuning energy harvester for rotating applications. The harvester rotates in the vertical plane and is comprised of two beams: a relatively rigid piezoelectric generating beam and a narrow, flexible driving beam with a tip mass mounted at the end. The mass impacts the generating beam repeatedly under the influence of gravity to drive generation. Centrifugal force from the rotation modifies the resonant frequency of the flexible driving beam and the frequency response of the harvester. An analytical model that captures the harvester system's resonant frequency as a function of rotational speed is used to guide the detailed design. With an optimized design, the resonant frequency of the harvester substantially matches the frequency of the rotation over a wide frequency range from 4 to 16.2 Hz. A prototype of the passive self-tuning energy harvester using a lead zirconate titanate generating beam achieved a power density of 30.8 µW cm −3 and a more than 11 Hz bandwidth, which is much larger than the 0.8 Hz bandwidth calculated semi-empirically for a similar but untuned harvester. Passive tuning was also demonstrated using the more robust and reliable but less efficient polymer polyvinylidene fluoride for the generating beam

  6. A low frequency rotational energy harvesting system

    International Nuclear Information System (INIS)

    Febbo, M; Machado, S P; Ramirez, J M; Gatti, C D

    2016-01-01

    This paper presents a rotary power scavenging unit comprised of two systems of flexible beams connected by two masses which are joined by means of a spring, considering a PZT (QP16N, Midé Corporation) piezoelectric sheet mounted on one of the beams. The energy harvesting (EH) system is mounted rigidly on a rotating hub. The gravitational force on the masses causes sustained oscillatory motion in the flexible beams as long as there is rotary motion. The intention is to use the EH system in the wireless autonomous monitoring of wind turbines under different wind conditions. Specifically, the development is oriented to monitor the dynamic state of the blades of a wind generator of 30 KW which rotates between 50 and 150 rpm. The paper shows a complete set of experimental results on three devices, modifying the amount of beams in the frame supporting the system. The results show an acceptable sustained voltage generation for the expected range, in the three proposed cases. Therefore, it is possible to use this system for generating energy in a low-frequency rotating environment. As an alternative, the system can be easily adapted to include an array of piezoelectric sheets to each of the beams, to provide more power generation. (paper)

  7. Barriers to Industrial Energy Efficiency - Study (Appendix A), June 2015

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-06-01

    This study examines barriers that impede the adoption of energy efficient technologies and practices in the industrial sector, and identifies successful examples and opportunities to overcome these barriers. Three groups of energy efficiency technologies and measures were examined: industrial end-use energy efficiency, industrial demand response, and industrial combined heat and power. This study also includes the estimated economic benefits from hypothetical Federal energy efficiency matching grants, as directed by the Act.

  8. Barriers to Industrial Energy Efficiency - Report to Congress, June 2015

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-06-01

    This report examines barriers that impede the adoption of energy efficient technologies and practices in the industrial sector, and identifies successful examples and opportunities to overcome these barriers. Three groups of energy efficiency technologies and measures were examined: industrial end-use energy efficiency, industrial demand response, and industrial combined heat and power. This report also includes the estimated economic benefits from hypothetical Federal energy efficiency matching grants, as directed by the Act.

  9. l-dependent potential barriers and superdeformed states

    International Nuclear Information System (INIS)

    Gherghescu, R.A.; Royer, G.

    1999-01-01

    The macroscopic-microscopic energy of rotating nuclei moving in the fusion-like deformation valley has been determined within a generalized liquid drop model including the nuclear proximity energy, the two-center shell model and the Strutinsky method. The l-dependent potential barriers of the 84 Zr, 132 Ce, 152 Dy and 192 Hg nuclei have been determined. A first minimum having a pure microscopic origin and lodging the normally deformed states, progressively disappears with increasing angular momenta. The microscopic and macroscopic energies contribute to generate a second minimum where superdeformed states may survive. It becomes progressively the lowest one at intermediate spins. At still higher angular momenta, the minimum moves towards the foot of the external fission barrier leading to macroscopic hyper-deformed quasi-molecular states. (authors)

  10. Three-dimensional analytic probabilities of coupled vibrational-rotational-translational energy transfer for DSMC modeling of nonequilibrium flows

    International Nuclear Information System (INIS)

    Adamovich, Igor V.

    2014-01-01

    A three-dimensional, nonperturbative, semiclassical analytic model of vibrational energy transfer in collisions between a rotating diatomic molecule and an atom, and between two rotating diatomic molecules (Forced Harmonic Oscillator–Free Rotation model) has been extended to incorporate rotational relaxation and coupling between vibrational, translational, and rotational energy transfer. The model is based on analysis of semiclassical trajectories of rotating molecules interacting by a repulsive exponential atom-to-atom potential. The model predictions are compared with the results of three-dimensional close-coupled semiclassical trajectory calculations using the same potential energy surface. The comparison demonstrates good agreement between analytic and numerical probabilities of rotational and vibrational energy transfer processes, over a wide range of total collision energies, rotational energies, and impact parameter. The model predicts probabilities of single-quantum and multi-quantum vibrational-rotational transitions and is applicable up to very high collision energies and quantum numbers. Closed-form analytic expressions for these transition probabilities lend themselves to straightforward incorporation into DSMC nonequilibrium flow codes

  11. Developing effective rockfall protection barriers for low energy impacts

    Science.gov (United States)

    Mentani, Alessio; Giacomini, Anna; Buzzi, Olivier; Govoni, Laura; Gottardi, Guido; Fityus, Stephen

    2016-04-01

    Recently, important progresses have been made towards the development of high capacity rockfall barriers (100 kJ - 8000 kJ). The interest of researchers and practitioners is now turning to the development of fences of minor capacity, whose use becomes essential in areas where rockfall events generally have low intensity and the use of high capacity barriers would be accompanied by excessive costs and high environmental impact. Low energy barriers can also provide a cost-effective solution even in areas where high energies events are expected. Results of full-scale tests are vital to any investigation on the behaviour of these structures. An experimental set-up has been developed at The University of Newcastle (AUS), to investigate the response of low energy rockfall barrier prototypes to low energy impacts. The Australian territory, and in particular New South Wales, is in fact characterised by rockfall events of low-to-medium intensity (50 kJ - 500 kJ) and the need of protection structures working within such energy range, is particularly felt [1]. The experiments involved the impact of a test block onto three spans, low energy barrier prototypes, made of steel structural posts, fully fixed at the base, side cables and a steel meshwork constituted by a double twist hexagonal wire net [2]. Test data enabled the development, calibration and assessment of FE models [3], on which non-linear and dynamic analyses have been performed addressing the effect of the block size. Results have shown that the response of the structure is strongly governed by the net. Data from tests conducted on the sole net and on the entire barrier showed in fact a similar trend, different to what typically observed for high capacity barriers, whose behaviour is also led by the presence of uphill cables and brakes. In particular, the numerical analyses have demonstrated a dependence of the net performance on the block size. In particular, a loss of capacity in the order of 50% occurred as the

  12. Dealing with barriers to energy efficiency and SMEs: Some empirical evidences

    International Nuclear Information System (INIS)

    Trianni, A.; Cagno, E.

    2012-01-01

    This paper aims at providing an identification and an analysis of the most relevant barriers to energy efficiency that limit a widespread implementation of the Best Available Technologies and Practices (BAT/Ps) through the investigation of 128 non-energy intensive manufacturing Small and Medium-sized Enterprises (SMEs) in Northern Italy. The study, starting from the existing literature, performs an investigation of the operational difficulties occurring when it has been decided to undertake the process of investing resources in energy efficiency interventions. The most perceived barriers have been analyzed with respect to several important characteristics (among others, sector and firm’s size). This examination shows also that very much attention should be paid to avoid bundling together SMEs of different sizes and sectors, since different behaviors with respect to the perception of the barriers can be observed. The analysis of the sample presents some interesting trends considering the perception of the barriers with respect to previous experience of the enterprises on energy efficiency. The paper also explores, through a preliminary analysis, the correlations among questions in order to understand the dynamics and the possible effects of a given barrier with respect to others. Several suggestions for future research in this important area have been provided. -- Highlights: ► Evidences of different behaviors with respect to energy efficiency among sectors and firm’s size (within SMEs). ► Importance, for energy efficiency barriers, of avoid bundling SMEs as a whole. ► Preliminary investigation of relationships between barriers in order to understand the dynamics.

  13. High-Energy Emission from Rotation-Powered Pulsars

    Science.gov (United States)

    Harding, Alice K.

    2007-01-01

    Thirty-five years after the discovery of rotation-powered pulsars, we still do not understand their pulsed emission at any wavelength. In the last few years there have been some fundamental developments in acceleration and emission models. I will review both the basic physics of the models as well as the latest developments in understanding the high-energy emission of rotation-powered pulsars. Special and general relativistic effects play important roles in pulsar emission, from inertial frame-dragging near the stellar surface to aberration, time-of-flight and retardation of the magnetic field near the light cylinder. Understanding how these effects determine what we observe at different wavelengths is critical to unraveling the emission physics. Fortunately two new gamma-ray telescopes, AGILE and GLAST, with launches expected this year will detect many new gamma-ray pulsars and test the predictions of these models with unprecedented sensitivity and energy resolution for gamma-rays in the range of 30 MeV to 300 GeV.

  14. Energy Transfer in Scattering by Rotating Potentials

    Indian Academy of Sciences (India)

    Quantum mechanical scattering theory is studied for time-dependent Schrödinger operators, in particular for particles in a rotating potential. Under various assumptions about the decay rate at infinity we show uniform boundedness in time for the kinetic energy of scattering states, existence and completeness of wave ...

  15. Wave-driven Rotation in Supersonically Rotating Mirrors

    Energy Technology Data Exchange (ETDEWEB)

    A. Fetterman and N.J. Fisch

    2010-02-15

    Supersonic rotation in mirrors may be produced by radio frequency waves. The waves produce coupled diffusion in ion kinetic and potential energy. A population inversion along the diffusion path then produces rotation. Waves may be designed to exploit a natural kinetic energy source or may provide the rotation energy on their own. Centrifugal traps for fusion and isotope separation may benefit from this wave-driven rotation.

  16. Wave-driven Rotation in Supersonically Rotating Mirrors

    International Nuclear Information System (INIS)

    Fetterman, A.; Fisch, N.J.

    2010-01-01

    Supersonic rotation in mirrors may be produced by radio frequency waves. The waves produce coupled diffusion in ion kinetic and potential energy. A population inversion along the diffusion path then produces rotation. Waves may be designed to exploit a natural kinetic energy source or may provide the rotation energy on their own. Centrifugal traps for fusion and isotope separation may benefit from this wave-driven rotation.

  17. Energy efficiency barriers in commercial and industrial firms in Ukraine: An empirical analysis

    International Nuclear Information System (INIS)

    Hochman, Gal; Timilsina, Govinda R.

    2017-01-01

    Improvement in energy efficiency is one of the main options to reduce energy demand and greenhouse gas emissions. However, large-scale deployment of energy-efficient technologies is constrained by several factors. Employing a survey of 509 industrial and commercial firms throughout Ukraine and a generalized ordered logit model, we quantified the economic, behavioral, and institutional barriers that may impede the deployment of energy-efficient technologies. Our analysis shows that behavioral barriers resulted from lack of information, knowledge, and awareness are major impediments to the adoption of energy-efficient technologies in Ukraine, and that financial barriers may further impede investments in these technologies especially for small firms. This suggests that carefully targeted information provisions and energy audits will enhance Ukrainian firms' investments in energy-efficient technologies to save energy consumption, improve productivity, and reduce carbon emissions from the productive sectors. - Highlights: • Employing a survey of 509 industrial and commercial firms throughout Ukraine • A generalized ordered logit model is used in the analysis. • The paper quantifies the economic, behavioral, and institutional barriers to energy-efficient technologies. • Behavioral barriers are major impediments to the adoption of energy-efficient technologies. • Financial barriers may further impede investments in these technologies especially for small firms.

  18. A path method for finding energy barriers and minimum energy paths in complex micromagnetic systems

    International Nuclear Information System (INIS)

    Dittrich, R.; Schrefl, T.; Suess, D.; Scholz, W.; Forster, H.; Fidler, J.

    2002-01-01

    Minimum energy paths and energy barriers are calculated for complex micromagnetic systems. The method is based on the nudged elastic band method and uses finite-element techniques to represent granular structures. The method was found to be robust and fast for both simple test problems as well as for large systems such as patterned granular media. The method is used to estimate the energy barriers in CoCr-based perpendicular recording media

  19. Implementation of renewable energy technologies - Opportunities and barriers. Ghana country study

    Energy Technology Data Exchange (ETDEWEB)

    Edjekumhene, I.; Atakora, S.B.; Atta-Konadu, R.; Brew-Hammond, A. [Kumasi Inst. og Technology and Environment (Ghana)

    2001-07-01

    This report presents the experience of Ghana in the development, utilisation and promotion of Renewable Energy Technologies (RETs). The report gives a general overview of the state of RETs, describes past/existing institutional, regulatory and policy framework, identifies key barriers to and opportunities for RETs, and recommends directional changes needed to remove barriers and promote wide-scale adoption of RETs in Ghana. A total of eight RETs - biomass-fired dryers, sawdust stoves, sawdust briquette, biogas, solar crop dryer, solar water heater, solar water pump and small hydro power - are covered in the report. Analyses of barriers to the eight RETs are carried out using a framework approach that categorises barriers into socio-technical, economic and crosscutting barriers. Financial analyses, as opposed to economic analyses, have been carried out for all the selected RETs. The report also incorporates stake holders' perspectives and views on barriers and how they can be removed. Ghana is endowed with several renewable energy resources like solar radiation, small hydro, biomass, and wind. Exploitation of Ghana's renewable energy resources has been carried out under two main policy regimes - PND Law 62 (1983) and the Energy Sector Development Programme (ESDP). Several measures and instruments have been employed in the implementation of renewable energy policies. The main measures used are research and development, information and eduction, and some normative measures (like the passing of PNDC Law 62 and the Energy Commission Law). Some economic instruments, such as subsidies, taxes, pricing, financing and duty waiver/reduction, have been used as well but only to a limited extent. The effective development, implementation and dissemination of all the RETs studied are hampered by several barriers, which can be grouped into three main categories - Socio-technical barriers, economic barriers and crosscutting barriers. Socio-technical barriers refer to

  20. Implementation of renewable energy technologies - Opportunities and barriers. Ghana country study

    Energy Technology Data Exchange (ETDEWEB)

    Edjekumhene, I; Atakora, S B; Atta-Konadu, R; Brew-Hammond, A [Kumasi Inst. og Technology and Environment (Ghana)

    2001-07-01

    This report presents the experience of Ghana in the development, utilisation and promotion of Renewable Energy Technologies (RETs). The report gives a general overview of the state of RETs, describes past/existing institutional, regulatory and policy framework, identifies key barriers to and opportunities for RETs, and recommends directional changes needed to remove barriers and promote wide-scale adoption of RETs in Ghana. A total of eight RETs - biomass-fired dryers, sawdust stoves, sawdust briquette, biogas, solar crop dryer, solar water heater, solar water pump and small hydro power - are covered in the report. Analyses of barriers to the eight RETs are carried out using a framework approach that categorises barriers into socio-technical, economic and crosscutting barriers. Financial analyses, as opposed to economic analyses, have been carried out for all the selected RETs. The report also incorporates stake holders' perspectives and views on barriers and how they can be removed. Ghana is endowed with several renewable energy resources like solar radiation, small hydro, biomass, and wind. Exploitation of Ghana's renewable energy resources has been carried out under two main policy regimes - PND Law 62 (1983) and the Energy Sector Development Programme (ESDP). Several measures and instruments have been employed in the implementation of renewable energy policies. The main measures used are research and development, information and eduction, and some normative measures (like the passing of PNDC Law 62 and the Energy Commission Law). Some economic instruments, such as subsidies, taxes, pricing, financing and duty waiver/reduction, have been used as well but only to a limited extent. The effective development, implementation and dissemination of all the RETs studied are hampered by several barriers, which can be grouped into three main categories - Socio-technical barriers, economic barriers and crosscutting barriers. Socio-technical barriers refer to resource

  1. Barriers to the sustainable development of electrical energy in the industrialized nations

    International Nuclear Information System (INIS)

    Ringel, M.; Leonardi, J.

    2003-01-01

    The liberalization of the electricity market in the industrialized nations may considered as an opportunity to bring about a diversification of the energy sector which could help overcome the economic barriers to a more sustainable development By allowing new companies to boost their market share, in many countries increases have been obtained in the supply of electricity based on renewable energy or energy services offering greater efficiency. It is now possible to reduce the cost of the measures which encourage the sustainable development of the sector, taking account of those barriers which prevent the expansion of ENR, hold back further gains in energy efficiency and block a reduction in demand An active energy policy will make it possible to overcome the difficulties encountered in various countries. This study highlights the main barriers to the sustainable development of electrical energy and outlines which solutions may be envisaged to overcome these barriers. (authors)

  2. Causal extraction of black hole rotational energy by various kinds of electromagnetic fields

    International Nuclear Information System (INIS)

    Koide, Shinji; Baba, Tamon

    2014-01-01

    Recent general relativistic magnetohydrodynamics (MHD) simulations have suggested that relativistic jets from active galactic nuclei (AGNs) have been powered by the rotational energy of central black holes. Some mechanisms for extraction of black hole rotational energy have been proposed, like the Penrose process, Blandford-Znajek mechanism, MHD Penrose process, and superradiance. The Blandford-Znajek mechanism is the most promising mechanism for the engines of the relativistic jets from AGNs. However, an intuitive interpretation of this mechanism with causality is not yet clarified, while the Penrose process has a clear interpretation for causal energy extraction from a black hole with negative energy. In this paper, we present a formula to build physical intuition so that in the Blandford-Znajek mechanism, as well as in other electromagnetic processes, negative electromagnetic energy plays an important role in causal extraction of the rotational energy of black holes.

  3. Financing energy SMEs in Ghana and Senegal: Outcomes, barriers and prospects

    DEFF Research Database (Denmark)

    Haselip, James Arthur; Desgain, Denis DR; Mackenzie, Gordon A.

    2014-01-01

    enterprises (energy SMEs). These assumptions were (1) that the lack of affordable local financing presented the most significant barrier to setting up and expanding energy SMEs, and (2) that these barriers would be overcome by a ‘demonstration effect’ whereby successful businesses, supported by donor...

  4. Energy extraction from a Konoplya–Zhidenko rotating non-Kerr black hole

    Directory of Open Access Journals (Sweden)

    Fen Long

    2018-01-01

    Full Text Available We have investigated the properties of the ergosphere and the energy extraction by Penrose process in a Konoplya–Zhidenko rotating non-Kerr black hole spacetime. We find that the ergosphere becomes thin and the maximum efficiency of energy extraction decreases as the deformation parameter increases. For the case with aM, we find that the maximum efficiency can reach so high that it is almost unlimited as the positive deformation parameter is close to zero, which is a new feature of energy extraction in such kind of rotating non-Kerr black hole spacetime.

  5. Power law scaling for rotational energy transfer

    International Nuclear Information System (INIS)

    Pritchard, D.E.; Smith, N.; Driver, R.D.; Brunner, T.A.

    1979-01-01

    We have applied a new scaling law to several sets of rotational energy transfer cross sections. The new law asserts that the square of the T-matrix depends on the amount of energy transferred as a power law. Two different kinds of angular momentum statistics are assumed, one corresponding to m/sub j/ being conserved and the other corresponding to m/sub j/ being completely randomized. Numerical fits are presented which demonstrate that the data follow the power law better than the widely used exponential gap law

  6. Reducing barriers to energy efficiency in the German mechanical engineering sector. Executive summary

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, J.; Boede, U.

    2000-12-01

    This report describes the empirical research into barriers to energy efficiency in the German mechanical engineering (ME) sector. It is one of nine such reports in the BARRIERS project. The report contains description and analysis of four case studies of energy management in German companies in the ME sector. The results are analysed using the theoretical framework developed for the BARRIERS project. The report also provides brief recommendations on how these barriers to the rational use of energy (RUE) may be overcome and how energy efficiency within the ME sector may be improved. The results of the study for the ME sector in Germany are summarised in this executive summary under the following headings: - Characterising the mechanical engineering sector; - Case studies of energy management in the German mechanical engineering sector; - Evidence of barriers in the German mechanical engineering sector; - The role of energy service companies in the mechanical engineering sector; - Policy implications. (orig.)

  7. Reducing barriers to energy efficiency in the German higher education sector. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, J.; Boede, U.

    2000-12-01

    This report describes the empirical research into barriers to energy efficiency in the German higher education (HE) sector. It is one of nine such reports in the BARRIERS project. The report contains description and analysis of six case studies of energy management in German universities. The results are analysed using the theoretical framework developed for the BARRIERS project (Sorrell et al., 2000). The report also provides brief recommendations on how these barriers to the rational use of energy (RUE) may be overcome and how energy efficiency within the sector may be improved. The results of the study for the higher education sector in Germany are summarised in this executive summary under the following headings: - Characterising the higher education sector; - Case studies of energy management in the German higher education sector; - Evidence of barriers in the German higher education sector; - The role of energy service companies in the higher education sector; - Policy implications. (orig.)

  8. Reducing barriers to energy efficiency in the German higher education sector. Executive summary

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, J.; Boede, U.

    2000-12-01

    This report describes the empirical research into barriers to energy efficiency in the German higher education (HE) sector. It is one of nine such reports in the BARRIERS project. The report contains description and analysis of six case studies of energy management in German universities. The results are analysed using the theoretical framework developed for the BARRIERS project (Sorrell et al., 2000). The report also provides brief recommendations on how these barriers to the rational use of energy (RUE) may be overcome and how energy efficiency within the sector may be improved. The results of the study for the higher education sector in Germany are summarised in this executive summary under the following headings: - Characterising the higher education sector; - Case studies of energy management in the German higher education sector; - Evidence of barriers in the German higher education sector; - The role of energy service companies in the higher education sector; - Policy implications. (orig.)

  9. Reducing barriers to energy efficiency in the German mechanical engineering sector. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, J.; Boede, U.

    2000-12-01

    This report describes the empirical research into barriers to energy efficiency in the German mechanical engineering (ME) sector. It is one of nine such reports in the BARRIERS project. The report contains description and analysis of four case studies of energy management in German companies in the ME sector. The results are analysed using the theoretical framework developed for the BARRIERS project. The report also provides brief recommendations on how these barriers to the rational use of energy (RUE) may be overcome and how energy efficiency within the ME sector may be improved. The results of the study for the ME sector in Germany are summarised in this executive summary under the following headings: - Characterising the mechanical engineering sector; - Case studies of energy management in the German mechanical engineering sector; - Evidence of barriers in the German mechanical engineering sector; - The role of energy service companies in the mechanical engineering sector; - Policy implications. (orig.)

  10. Barriers and opportunities: A review of selected successful energy-efficiency programs

    International Nuclear Information System (INIS)

    Worrell, Ernst; Price, Lynn

    2001-01-01

    In industry, barriers may exist at various points in the decision making process, and in the implementation and management of measures to improve energy efficiency. Barriers may take many forms, and are determined by the business environment and include decision-making processes, energy prices, lack of information, a lack of confidence in the information, or high transaction costs for obtaining reliable information, as well as limited capital availability. Other barriers are the ''invisibility'' of energy efficiency measures and the difficulty of quantifying the impacts, and slow diffusion of innovative technology into markets while firms typically under-invest in R and D, despite the high pay-backs. Various programs try to reduce the barriers to improve the uptake of innovative technologies. A wide array of policies has been used and tested in the industrial sector in industrialized countries, with varying success rates. We review some new approaches to industrial energy efficiency improvement in industrialized countries, focusing on voluntary agreements

  11. Nuclear energy technology transfer: the security barriers

    International Nuclear Information System (INIS)

    Rinne, R.L.

    1975-08-01

    The problems presented by security considerations to the transfer of nuclear energy technology are examined. In the case of fusion, the national security barrier associated with the laser and E-beam approaches is discussed; for fission, the international security requirements, due to the possibility of the theft or diversion of special nuclear materials or sabotage of nuclear facilities, are highlighted. The paper outlines the nuclear fuel cycle and terrorist threat, examples of security barriers, and the current approaches to transferring technology. (auth)

  12. Rotational and divergent kinetic energy in the mesoscale model ALADIN

    Directory of Open Access Journals (Sweden)

    V. Blažica

    2013-03-01

    Full Text Available Kinetic energy spectra from the mesoscale numerical weather prediction (NWP model ALADIN with horizontal resolution 4.4 km are split into divergent and rotational components which are then compared at horizontal scales below 300 km and various vertical levels. It is shown that about 50% of kinetic energy in the free troposphere in ALADIN is divergent energy. The percentage increases towards 70% near the surface and in the upper troposphere towards 100 hPa. The maximal percentage of divergent energy is found at stratospheric levels around 100 hPa and at scales below 100 km which are not represented by the global models. At all levels, the divergent energy spectra are characterised by shallower slopes than the rotational energy spectra, and the difference increases as horizontal scales become larger. A very similar vertical distribution of divergent energy is obtained by using the standard ALADIN approach for the computation of spectra based on the extension zone and by applying detrending approach commonly used in mesoscale NWP community.

  13. Understanding energy efficiency barriers in Ukraine: Insights from a survey of commercial and industrial firms

    International Nuclear Information System (INIS)

    Timilsina, Govinda R.; Hochman, Gal; Fedets, Iryna

    2016-01-01

    Improvement of energy efficiency is an important element of energy policy for a sustainable supply of energy in Ukraine. However, the country is facing several challenges to the large-scale deployment of energy efficient technologies. We conducted a two-stage quota sample survey of 509 commercial and industrial firms of all regions of Ukraine to understand the barriers to energy efficiency improvements. Our study finds that more than two-thirds of the commercial and industrial firms in the country view improvement of energy efficiency very important to their business. However, due to several barriers they are unable to realize the improvements of energy efficiency. Among the 19 potential barriers investigated in the study, the survey results show that high upfront investment requirement, lack of government policies to support energy efficiency improvements, higher cost of capital, and lack of information and awareness are the most critical barriers to the improvement of energy efficiency in the industrial and commercial sectors in Ukraine. - Highlights: • Despite attractiveness, large scale deployment of energy efficiency is lacking. • Several barriers are responsible for slow implementation of energy efficiency. • Understanding the barriers from the field is crucial to design effective policies. • A survey of commercial and industrial firms reveals the key barriers. • Financial barriers are the main hurdles to adopt energy efficient technologies.

  14. Applications of Skyrme energy-density functional to fusion reactions spanning the fusion barriers

    International Nuclear Information System (INIS)

    Liu Min; Wang, Ning; Li Zhuxia; Wu Xizhen; Zhao Enguang

    2006-01-01

    The Skyrme energy density functional has been applied to the study of heavy-ion fusion reactions. The barriers for fusion reactions are calculated by the Skyrme energy density functional with proton and neutron density distributions determined by using restricted density variational (RDV) method within the same energy density functional together with semi-classical approach known as the extended semi-classical Thomas-Fermi method. Based on the fusion barrier obtained, we propose a parametrization of the empirical barrier distribution to take into account the multi-dimensional character of real barrier and then apply it to calculate the fusion excitation functions in terms of barrier penetration concept. A large number of measured fusion excitation functions spanning the fusion barriers can be reproduced well. The competition between suppression and enhancement effects on sub-barrier fusion caused by neutron-shell-closure and excess neutron effects is studied

  15. Addressing and overcoming barriers for energy savings in business

    DEFF Research Database (Denmark)

    Dirckinck-Holmfeld, Kasper

    Energy savings are generally viewed as an effective way to cut GHG emissions, as there are huge potentials for improvements because of several barriers and constraining factors for implementing otherwise profitable solutions. Several different polity tools have been applied to overcome these barr......Energy savings are generally viewed as an effective way to cut GHG emissions, as there are huge potentials for improvements because of several barriers and constraining factors for implementing otherwise profitable solutions. Several different polity tools have been applied to overcome...

  16. Poloidal rotation dynamics, radial electric field, and neoclassical theory in the jet internal-transport-barrier region.

    Science.gov (United States)

    Crombé, K; Andrew, Y; Brix, M; Giroud, C; Hacquin, S; Hawkes, N C; Murari, A; Nave, M F F; Ongena, J; Parail, V; Van Oost, G; Voitsekhovitch, I; Zastrow, K-D

    2005-10-07

    Results from the first measurements of a core plasma poloidal rotation velocity (upsilontheta) across internal transport barriers (ITB) on JET are presented. The spatial and temporal evolution of the ITB can be followed along with the upsilontheta radial profiles, providing a very clear link between the location of the steepest region of the ion temperature gradient and localized spin-up of upsilontheta. The upsilontheta measurements are an order of magnitude higher than the neoclassical predictions for thermal particles in the ITB region, contrary to the close agreement found between the determined and predicted particle and heat transport coefficients [K.-D. Zastrow, Plasma Phys. Controlled Fusion 46, B255 (2004)]. These results have significant implications for the understanding of transport barrier dynamics due to their large impact on the measured radial electric field profile.

  17. A novel energy-efficient rotational variable stiffness actuator

    NARCIS (Netherlands)

    Rao, S.; Carloni, Raffaella; Stramigioli, Stefano

    This paper presents the working principle, the design and realization of a novel rotational variable stiffness actuator, whose stiffness can be varied independently of its output angular position. This actuator is energy-efficient, meaning that the stiffness of the actuator can be varied by keeping

  18. Key Barriers to the Implementation of Solar Energy in Nigeria: A Critical Analysis

    Science.gov (United States)

    Abdullahi, D.; Suresh, S.; Renukappa, S.; Oloke, D.

    2017-08-01

    Nigeria, potentially, has abundant sunshine throughout the year, making it full thirst for solar energy generation. Even though, the country’s solar energy projects have not realised a fair result over the years, due to many barriers associated with initiatives implementation. Therefore, the entire power sector remains incapacitated to generate, transmit and distribute a clean, affordable and sustainable energy to assist economic growth. The research integrated five African counterpart’s solar energy initiatives, barriers, policies and strategies adopted as a lesson learned to Nigeria. Inadequate solar initiative’s research, lack of technological know-how, short-term policies, lack of awareness and political instability are the major barriers that made the implementation of solar initiatives almost impossible in Nigeria. The shock of the barriers therefore, constitutes a major negative contribution to the crippling of the power sector in the state. Future research will concentrate on initiatives for mitigating solar and other renewable energy barriers.

  19. Li breakup polarization potential at near barrier energies

    International Nuclear Information System (INIS)

    Lubian, F. J.; Correa, T.; Gomes, P.R.S.; Paes, B; Figueira, J. M.; Abriola, D.; Fernandez, J. O.; Capurro, O. A.; Marti, G.V.; Martinez, D.; Heimann; Negri, A.; Pacheco, A. J.; Padron, I.

    2007-01-01

    Inelastic and one neutron transfer cross sections at energies around the Coulomb barrier were used to derive dynamic polarization potential (DPP) for the 7 Li + 27 Al system. The DPP due to breakup, obtained in a simple way, indicates that its real part is repulsive at nearbarrier energies. (Author)

  20. Plasma rotation evolution near the peripheral transport barrier in the presence of low-frequency MHD bursts in TUMAN-3M tokamak

    International Nuclear Information System (INIS)

    Bulanin, V V; Askinazi, L G; Lebedev, S V; Gorohov, M V; Kornev, V A; Petrov, A V; Tukachinsky, A S; Vildjunas, M I

    2006-01-01

    The experiments described in the paper are aimed at investigating the possible influence of the low frequency magnetohydrodynamic (MHD) activity burst on the Ohmic H-mode in the TUMAN-3M tokamak. During the MHD burst a transient deterioration of improved confinement was observed. The study has been focused on the measurements of plasma fluctuation poloidal velocity performed by microwave Doppler reflectometry. The plasma fluctuation rotation observed before the MHD burst in the vicinity of the edge transport barrier was in the direction of plasma drift in the negative radial electric field. During the MHD activity the measured poloidal velocity was drastically decreased and even changed its sign. Radial profiles of the poloidal velocity measured in a set of reproducible tokamak shots exhibited the plasma fluctuation rotation in the ion diamagnetic drift direction at the location of the peripheral transport barrier. The possible reasons for this phenomenon are discussed

  1. Study of Quasielastic scattering for 7Li+159Tb at around- barrier energies

    Directory of Open Access Journals (Sweden)

    Mukherjee A.

    2017-01-01

    Full Text Available Quasielastic scattering cross sections for the reaction 7Li+159Tb have been measured at large backangles, at energies around the Coulomb barrier. The quasielastic barrier distribution has been extracted from the measured quasielastic scattering excitation function, including and excluding α particle contribution. The peak of the quasielastic barrier distribution including α particle contribution shows a shift towards higher energy compared to the peak of the distribution without α particles. The quasielastic barrier distribution when compared to the calculated fusion barrier distribution, appears to show reasonable agreement for the system.

  2. Rotation, Stability and Transport

    Energy Technology Data Exchange (ETDEWEB)

    Connor, J. W.

    2007-07-01

    Tokamak plasmas can frequently exhibit high levels of rotation and rotation shear. This can usually be attributed to various sources: injection of momentum, e.g. through neutral beams, flows driven by plasma gradients or torques resulting from non-ambipolar particle loss; however, the source sometimes remains a mystery, such as the spontaneous rotation observed in Ohmic plasmas. The equilibrium rotation profile is given by the balance of these sources with transport and other losses; the edge boundary conditions can play an important role in determining this profile . Such plasma rotation, particularly sheared rotation, is predicted theoretically to have a significant influence on plasma behaviour. In the first place, sonic flows can significantly affect tokamak equilibria and neoclassical transport losses. However, the influence of rotation on plasma stability and turbulence is more profound. At the macroscopic level it affects the behaviour of the gross MHD modes that influence plasma operational limits. This includes sawteeth, the seeding of neoclassical tearing modes, resistive wall modes and the onset of disruptions through error fields, mode locking and reconnection. At the microscopic level it has a major effect on the stability of ballooning modes, both ideal MHD and drift wave instabilities such as ion temperature gradient (ITG) modes. In the non-linear state, as unstable drift waves evolve into turbulent structures, sheared rotation also tears apart eddies, thereby reducing the resulting transport. There is considerable experimental evidence for these effects on both MHD stability and plasma confinement. In particular, the appearance of improved confinement modes with transport barriers, such as edge H-mode barriers and internal transport barriers (ITBs) appears to correlate well with the presence of sheared plasma rotation. This talk will describe the theory underlying some of these phenomena involving plasma rotation, on both macroscopic and microscopic

  3. An out-of-plane rotational energy harvesting system for low frequency environments

    International Nuclear Information System (INIS)

    Febbo, M.; Machado, S.P.; Gatti, C.D.; Ramirez, J.M.

    2017-01-01

    Highlights: • An alternative to cantilever beam-type systems for energy harvesting is proposed. • The device generates energy in a low frequency rotational environment. • It comprises two beams, a spring and two heavy masses joined by the spring. • By varying the flexibility of one beam, the device increments output DC power. • The generated DC power suffices to feed low power wireless transmitters. - Abstract: We present a novel design of a rotational power scavenging system as an alternative to cantilever beams attached to a hub. The device is meant to provide energy to wireless autonomous monitoring systems in low frequency environments such as wind turbines of 30 kW with rotational speeds of between 50 and 150 rpm. These characteristics define the bandwidth of the rotational energy harvesting system (REH) and its physical dimensions. A versatile geometric configuration with two elastic beams and two heavy masses joined by a spring is proposed. A piezoelectric sheet is mounted on the primary beam while the REH is placed on a rotating hub with the gravitational force acting as a periodic source. This kind of double-beam system offers the possibility to modify the vibration characteristics of the harvester for achieving high power density. An analytical framework using the Lagrangian formulation is derived to describe the motion of the system and the voltage output as a function of rotation speed. Several sets of experiments were performed to characterize the system and to validate the assumed hypothesis. In the experimental setup, a wireless data acquisition system based on Arduino technology was implemented to avoid slip-ring mechanisms. The results show very good agreement between the theoretical and experimental tests. Moreover, the output power of a simple harvesting circuit, which serves as an energy storage device, yields values ranging 26–105 μW over the whole frequency range. This allows us to use the proposed device for the designed purpose

  4. Methyl internal rotation in the microwave spectrum of vinyl acetate.

    Science.gov (United States)

    Nguyen, Ha Vinh Lam; Jabri, Atef; Van, Vinh; Stahl, Wolfgang

    2014-12-26

    The rotational spectrum of vinyl acetate, CH3(CO)OCH═CH2, was measured using two molecular beam Fourier transform microwave spectrometers operating in the frequency range from 2 to 40 GHz. Large splittings up to 2 GHz occurred due to the internal rotation of the acetyl methyl group CH3CO with a V3 potential of 151.492(34) cm(-1), much larger than the barrier of approximately 100 cm(-1) often found in acetates. The torsional transitions were fitted using three different programs XIAM, ERHAM, and BELGI-Cs, whereby the rotational constants, centrifugal distortion constants, and the internal rotation parameters could be determined with very high accuracy. The experimental results were supported by quantum chemical calculations. For a conformational analysis, potential energy surfaces were calculated.

  5. Observation of rotating nuclear molecules and determination of their lifetimes

    Energy Technology Data Exchange (ETDEWEB)

    Comas, V.; Heinz, S.; Ackermann, D.; Heredia, J.; Hessberger, F.P.; Khuyagbaatar, J.; Kindler, B.; Lommel, B.; Mann, R. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Darmstadt (Germany); Hofmann, S. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Darmstadt (Germany); Goethe-Universitaet Frankfurt, Institut fuer Physik, Frankfurt (Germany)

    2012-12-15

    Long-living rotating nuclear molecules (or ''dinuclear systems'') have been observed at the velocity filter SHIP at GSI in reactions of {sup 64}Ni + {sup 207}Pb at Coulomb barrier energies. The rotation was directly revealed by the velocity spectra of deep inelastic target-like transfer products which are formed during the lifetime of the nuclear molecule and emitted after its breakup. The corresponding rotation angles were about 180 degree pointing to long nuclear interaction times or lifetimes of the system, respectively. We deduced the lifetimes from the lines in the velocity spectra originating from two different rotation angles. Further, the unambiguous correlation of a certain transfer product with its individual velocity spectrum allowed us to study the lifetimes as a function of the number of transferred protons. (orig.)

  6. Effect of crop rotations and fertilization on energy balance in typical production systems on the Canadian Prairies

    Energy Technology Data Exchange (ETDEWEB)

    Zentner, R.P.; Stumborg, M.A.; Campbell, C.A.

    1989-03-01

    Non-renewable energy inputs (both direct and indirect), metabolizable energy output and energy efficiency of 10 spring wheat (Triticum aestivum L.) rotations were examined over 18 years on a loam soil in the Brown soil zone of the Canadian Prairies. The rotations, which were managed using conventional tillage, included a range of crops, cropping intensities, crop sequences and fertilizer practices. Results showed that the total energy input per unit of land was lowest for the traditional fallow-wheat (F-W) rotation (3482 MJ ha/sup -1/), intermediate (4470 MJ ha/sup -1/) for N- and P-fertilized fallow-wheat-wheat (F-W-W) and highest for N- and P-fertilized continuous wheat (7100 MJ ha/sup -1/). Substituting flax (Linum usitatissimum L.) or rye (Secale cereale L.) for wheat in the rotations reduced total energy input by 3 to 8%, while withholding the application of either N or P fertilizer reduced total energy input by 16-37%. Liquid fuel for field operations and local product transport, and fertilizer (primarily N) were the major energy inputs; both increased with cropping intensity. Fuel accounted for 30-50% of the total energy input of the rotations. Fertilizer represented 15-49% of the total energy input and was more important than fuel for the continuous crop rotations. Despite the high energy content in pesticides, they accounted for only 4-11% of the total energy input of the rotations. Metabolizable energy output displayed similar response patterns as total energy input reflecting the higher total annual grain yields as cropping intensity increased. The average energy output to input ratio for F-W was 3.6, or 262 kg of wheat GJ/sup -1/ of energy input, while those for F-W-W and continuous wheat were 3.3 and 2.6, or 240 and 191 kg of wheat GJ/sup -1/ of energy input, respectively. Rotations that included flax or cereal forage crops had the lowest energy efficiencies. 2 figs., 31 refs., 4 tabs.

  7. A methodology for low-speed broadband rotational energy harvesting using piezoelectric transduction and frequency up-conversion

    International Nuclear Information System (INIS)

    Fu, Hailing; Yeatman, Eric M.

    2017-01-01

    Energy harvesting from vibration for low-power electronics has been investigated intensively in recent years, but rotational energy harvesting is less investigated and still has some challenges. In this paper, a methodology for low-speed rotational energy harvesting using piezoelectric transduction and frequency up-conversion is analysed. The system consists of a piezoelectric cantilever beam with a tip magnet and a rotating magnet on a revolving host. The angular kinetic energy of the host is transferred to the vibration energy of the piezoelectric beam via magnetic coupling between the magnets. Frequency up-conversion is achieved by magnetic plucking, converting low frequency rotation into high frequency vibration of the piezoelectric beam. A distributed-parameter theoretical model is presented to analyse the electromechanical behaviour of the rotational energy harvester. Different configurations and design parameters were investigated to improve the output power of the device. Experimental studies were conducted to validate the theoretical estimation. The results illustrate that the proposed method is a feasible solution to collecting low-speed rotational energy from ambient hosts, such as vehicle tires, micro-turbines and wristwatches. - Highlights: • A topology to harvest low-frequency broad-band rotational energy is studied. • Different configurations were considered; arrangement (a)-repulsive was the best. • Theoretical analysis shows the harvester has a wide bandwidth at low frequency. • The ripples of output power are related to the beam's natural frequency. • Experimental results show a good performance (over 20 μW) from 15 Hz to 35 Hz.

  8. Stereodynamic tetrahydrobiisoindole “NU-BIPHEP(O”s: functionalization, rotational barriers and non-covalent interactions

    Directory of Open Access Journals (Sweden)

    Golo Storch

    2016-07-01

    Full Text Available Stereodynamic ligands offer intriguing possibilities in enantioselective catalysis. “NU-BIPHEPs” are a class of stereodynamic diphosphine ligands which are easily accessible via rhodium-catalyzed double [2 + 2 + 2] cycloadditions. This study explores the preparation of differently functionalized “NU-BIPHEP(O” compounds, the characterization of non-covalent adduct formation and the quantification of enantiomerization barriers. In order to explore the possibilities of functionalization, we studied modifications of the ligand backbone, e.g., with 3,5-dichlorobenzoyl chloride. Diastereomeric adducts with Okamoto-type cellulose derivatives and on-column deracemization were realized on the basis of non-covalent interactions. Enantioselective dynamic HPLC (DHPLC allowed for the determination of rotational barriers of ΔG‡298K = 92.2 ± 0.3 kJ mol−1 and 99.5 ± 0.1 kJ mol−1 underlining the stereodynamic properties of “NU-BIPHEPs” and “NU-BIPHEP(Os”, respectively. These results make the preparation of tailor-made functionalized stereodynamic ligands possible and give an outline for possible applications in enantioselective catalysis.

  9. The diffusion of solar energy use in HK: What are the barriers?

    International Nuclear Information System (INIS)

    Zhang Xiaoling; Shen Liyin; Chan, Sum Yee

    2012-01-01

    The world is facing the severe challenges of energy depletion and carbon dioxide (CO 2 ) emissions, and solar energy is considered to be a promising source of renewable energy and effective solution. However, the application of solar energy is limited in practice due to various barriers. Based on data collected from a survey of practice, this paper identifies the key barriers to the deployment of solar photovoltaic (PV) energy systems in Hong Kong. These include “high initial and repair cost”, “long payback period”, “inadequate installation space and service infrastructure”, “lack of participation of stakeholders/community in energy policy” and “lack of incentives by legislation and regulation”. Recommendations for addressing these barriers are proposed. For example, the high cost of solar PV energy systems can be reduced by the development and mass production of low-cost fabrication technologies and high performance PV technologies. Solar thermal applications should be encouraged as they are much more economical than solar PVs. It is also recommended that the Hong Kong Government adopt strategies to encourage a greater use of solar energy systems. The results from this study not only provide useful information for the Government, the private sector and consumers in Hong Kong but are also likely to apply equally to other similar regions around the world. - Highlights: ► The Hong Kong Government needs to adopt various strategies to encourage the solar energy system application. ► This paper identifies the key barriers to the diffusion of solar energy systems from a questionnaire survey and case study in Hong Kong. ► The barriers highlighted from the questionnaire survey include “high initial and repair cost”, “long payback period”, “inadequate installation space and service infrastructure”, “lack of stakeholder/community participation in energy choices” and “legal and regulation constraints”.

  10. Experimental investigation of rotation resistance moment energy spectra in multicylindrical circular Couette system with independently rotating cylinders

    Directory of Open Access Journals (Sweden)

    Serov Anatoly

    2017-01-01

    Full Text Available The torque of the rotational resistance in the Ku-Etta multi-cylinder system rotating in the direction towards each other is measured. The experiments were carried out for three values of the kinematic viscosity of the working fluid that fills the multicylinder system: water at a temperature of 24 °C (viscosity 0.9 cSt, an aqueous solution of glycerol at 20 °C and 41 °C (2.5 cSt and 5.2 cSt. An attempt is made to investigate the features of a viscous flow in the multicolor Couette flow system from the analysis of the energy spectra of the moment of resistance to rotation of cylinders.

  11. 6,7Li + 28Si total reaction cross sections at near barrier energies

    International Nuclear Information System (INIS)

    Pakou, A.; Musumarra, A.; Pierroutsakou, D.; Alamanos, N.; Assimakopoulos, P.A.; Divis, N.; Doukelis, G.; Gillibert, A.; Harissopulos, S.; Kalyva, G.; Kokkoris, M.; Lagoyannis, A.; Mertzimekis, T.J.; Nicolis, N.G.; Papachristodoulou, C.; Perdikakis, G.; Roubos, D.; Rusek, K.; Spyrou, S.; Zarkadas, Ch.

    2007-01-01

    Total reaction cross section measurements for the 6,7 Li + 28 Si systems have been performed at near-barrier energies. The results indicate that, with respect to the potential anomaly at barrier, 6 Li and 7 Li on light targets exhibit similar energy dependence on the imaginary potential. Comparisons are made with 6,7 Li cross sections on light and heavy targets, extracted via previous elastic scattering measurements and also with CDCC calculations. Energy dependent parametrisations are also obtained for total reaction cross sections of 6,7 Li on Si, as well as on any target, at near barrier energies

  12. Effects of rotation on the stability of nuclei under fission and the possibility of fusion in heavy-ion reactions

    International Nuclear Information System (INIS)

    Mustafa, M.G.; Kumar, K.

    1975-06-01

    The two-center shell model for fission is extended to include the effects of nuclear rotation or angular momentum J. The principle of minimization of total nuclear energy with respect to a constraint on J leads to an effective potential energy which depends on J as well as moment of inertia. This effective potential energy is minimized with respect to nuclear shape variables, neutron pairing energy gap, and proton pairing energy gap for each J value. The resulting potential minima, fission barriers, and moments of inertia are quite sensitive to J. Results are given for 208 82 Pb, 240 94 Pu, and for a super-heavy nucleus, 298 114 X. Microscopic calculations of the critical angular momentum (at which the fission barrier vanishes) are compared with the rotating liquid drop calculations of Cohen, Plasil, and Swiatecki. The influence of these results on the possibility of fusion in heavy-ion reactions is discussed. (5 figures, 6 tables) (U.S.)

  13. Possible Measurable Effects of Dark Energy in Rotating Superconductors

    Directory of Open Access Journals (Sweden)

    Clovis Jacinto de Matos

    2009-01-01

    Full Text Available We discuss recent laboratory experiments with rotating superconductors and show that three so far unexplained experimentally observed effects (anomalous acceleration signals, anomalous gyroscope signals, Cooper pair mass excess can be physically explained in terms of a possible interaction of dark energy with Cooper pairs. Our approach is based on a Ginzburg-Landau-like model of electromagnetic dark energy, where gravitationally active photons obtain mass in the superconductor. We show that this model can account simultaneously for the anomalous acceleration and anomalous gravitomagnetic fields around rotating superconductors measured by Tajmar et al. and for the anomalous Cooper pair mass in superconductive Niobium, measured by Cabrera and Tate. It is argued that these three different physical effects are ultimately different experimental manifestations of the simultaneous spontaneous breaking of gauge invariance and of the principle of general covariance in superconductive materials.

  14. Sustainability and energy self-sufficiency; overcoming the barriers

    Directory of Open Access Journals (Sweden)

    Rania Abdel Galil

    2015-12-01

    Full Text Available Engendering more positive attitudes to renewable energy is by no means a simple feat. Renewable energy technologies are viewed as radical innovations which necessitate substantial changes in production and consumption patterns, hence often met with resistance from both institutions and individuals. Yet action is needed; global energy consumption is expected to rise by 41% and global carbon dioxide emissions by 29%, with most of the demand and rise coming from emerging economies (BP energy outlook 2035. Further, countries need to meet objectives of reduction of GHG under the United Nations Framework Convention on Climate Change. Renewable energy share in the global energy mix needs to significantly increase in order to reach supply sufficiency, energy security, energy equity and environmental sustainability.Meeting demands of energy is critical for the economic and social development of any country; energy must be secure, accessible and affordable at all levels of society, and any negative impact of energy production and energy use on the environment must be minimized. Middle East energy consumption is expected to grow by 69% whilst production to grow by 32%, with 97% of demand still met by fossil fuels by the end of the 2035. Energy investment of $316 billion will be required in the Middle East and North Africa (MENA between 2015 and 2019 to meet its growing demand for power (Apicorp, 2014. Diversifying energy sources is indeed of interest in the MENA region, spurred by growing demand for power and desalinated water, fluctuating fuel price, GHG emission reduction targets, depleting fossil fuel reserves and advances in renewable energy technology. However, there are many barriers that hinder the adoption of renewable energy technologies worldwide, but more so in the MENA region. These barriers are political, economic, social and technological. With a focus on Europe and MENA, it can be said that these barriers have much in common albeit framing

  15. Improving energy efficiency in industrial energy systems an interdisciplinary perspective on barriers, energy audits, energy management, policies, and programs

    CERN Document Server

    Thollander, Patrik

    2012-01-01

    Industrial energy efficiency is one of the most important means of reducing the threat of increased global warming. Research however states that despite the existence of numerous technical energy efficiency measures, its deployment is hindered by the existence of various barriers to energy efficiency. The complexity of increasing energy efficiency in manufacturing industry calls for an interdisciplinary approach to the issue. Improving energy efficiency in industrial energy systems applies an interdisciplinary perspective in examining energy efficiency in industrial energy systems, and discuss

  16. Migration energy barriers of symmetric tilt grain boundaries in body-centered cubic metal Fe

    International Nuclear Information System (INIS)

    Wu, Minghui; Gu, Jianfeng; Jin, Zhaohui

    2015-01-01

    Graphical abstract: DFT calculated migration energy barrier (left) for symmetric grain boundary in metals is an essential physical property to measure the trend of grain boundary migration, in particular, in terms of the classical homogeneous nucleation model of GB dislocation/disconnection loops (right). - Migration energy barriers of two symmetric tilt grain boundaries in body-centered cubic metal Fe are obtained via first-principles calculations in combination with the nudged elastic band methods. Although the two grain boundaries show similar grain boundary energies, the migration energy barriers are different. Based on a homogeneous nucleation theory of grain-boundary dislocation loops, the calculated energy barrier provides a measure of intrinsic grain-boundary mobility and helps to evaluate effects due to vacancy and interstitial atoms such as carbon

  17. Market failures and barriers as a basis for clean energy policies

    International Nuclear Information System (INIS)

    Brown, M.A.

    2001-01-01

    This paper provides compelling evidence that large-scale market failures and barriers prevent consumers in the United States from obtaining energy services at least cost. Assessments of numerous energy policies and programs suggest that public interventions can overcome many of these market obstacles. By articulating these barriers and reviewing the literature on ways of addressing them, this paper provides a strong justification for the policy portfolios that define the ''Scenarios for a Clean Energy Future'', a study conducted by five National Laboratories. These scenarios are described in other papers published in this special issue of Energy Policy. (author)

  18. Surprisal analysis and probability matrices for rotational energy transfer

    International Nuclear Information System (INIS)

    Levine, R.D.; Bernstein, R.B.; Kahana, P.; Procaccia, I.; Upchurch, E.T.

    1976-01-01

    The information-theoretic approach is applied to the analysis of state-to-state rotational energy transfer cross sections. The rotational surprisal is evaluated in the usual way, in terms of the deviance of the cross sections from their reference (''prior'') values. The surprisal is found to be an essentially linear function of the energy transferred. This behavior accounts for the experimentally observed exponential gap law for the hydrogen halide systems. The data base here analyzed (taken from the literature) is largely computational in origin: quantal calculations for the hydrogenic systems H 2 +H, He, Li + ; HD+He; D 2 +H and for the N 2 +Ar system; and classical trajectory results for H 2 +Li + ; D 2 +Li + and N 2 +Ar. The surprisal analysis not only serves to compact a large body of data but also aids in the interpretation of the results. A single surprisal parameter theta/subR/ suffices to account for the (relative) magnitude of all state-to-state inelastic cross sections at a given energy

  19. Balance of the stored energies sustained by the internal and edge transport barriers and effects of ELMs and L-H transitions in JT-60U

    International Nuclear Information System (INIS)

    Kamada, Y.; Yoshida, M.; Sakamoto, Y.; Koide, Y.; Oyama, N.; Urano, H.; Kamiya, K.; Suzuki, T.; Isayama, A.

    2009-01-01

    To understand key physics processes determining radial profiles of the kinetic plasma parameters in the advanced tokamak operation scenarios, correlations between the edge transport barrier (ETB) and the internal transport barrier (ITB) have been studied in the JT-60U tokamak device. It has been found that the edge pedestal poloidal beta, β p -ped, increases almost linearly with the total poloidal beta, β p -tot, over a wide range of the plasma current for type I ELMing H-mode plasmas, and this dependence becomes stronger with increasing triangularity. This dependence is not due to the profile stiffness, since the dependence is the same regardless of the existence of ITB. As the stored energy inside the ITB-foot radius (W ITB ) increases, the total thermal stored energy (W th ) increases and then the pedestal stored energy (W ped ) increases. On the other hand, as W ped increases, the ELM penetration expands more inwards and finally reaches the ITB-foot radius. At this situation, the ITB-foot radius cannot move outwards because of the erosion by ELMs. Then the fractions of W ITB /W th and W ped /W th become almost constant. It has also been found that the type I ELM expels/decreases the edge toroidal momentum larger than the edge ion thermal energy. The ELM penetration for the toroidal rotation tends to be deeper than that for the ion temperature and can exceed the ITB-foot radius. The ELM penetration is deeper for CO-rotating plasmas than CTR rotating plasmas. In both cases, the ELM penetration is deeper in the order of the toroidal rotation (V t ), the ion temperature (T i ) and then the electron temperature (T e ). The L-H transition also changes the V t profile more significantly than the T i profile. At the L-H transition, the pedestal V t shifts into the CTR-direction deeply and suddenly without a change in T i , and then the pedestal V t grows further together with a growth of the pedestal T i in a slower timescale. Such changes in V t by ELMs and L

  20. Barriers to Energy Efficiency in Swedish Non-Energy-Intensive Micro- and Small-Sized Enterprises—A Case Study of a Local Energy Program

    Directory of Open Access Journals (Sweden)

    Fredrik Backman

    2017-01-01

    Full Text Available Improved energy efficiency has become a strategic issue and represents a priority for European competitiveness. Countries adopt various energy policies on local and national levels where energy audit programs are the most common energy end-use efficiency policy for industrial small- and medium-sized enterprises (SMEs. However, studies indicate that cost-efficient energy conservation measures are not always implemented, which can be explained by the existence of barriers to energy efficiency. This paper investigates how Swedish municipalities can support local micro- and small-sized enterprises with improved energy efficiency and the existence of different barriers to the implementation of energy efficiency. Relating this empirical case study to the theoretical barriers outlined in the text, this study found that the major explanatory factors related to non-implementation of cost-effective energy efficiency measures among micro- and small-sized industrial enterprises were bounded rationality (lack of time and/or other priorities, split incentives (having other priorities for capital investments, and imperfect information (slim organization and lack of technical skill. This study also found that information in the form of a report was the main thing that companies gained from working on the project “Energy-Driven Business”. Notably, the study involved companies that had participated in a local energy program and, still, companies face major barriers inhibiting implementation, indicating a need to further study other alternative policy models and how knowledge transfer can be improved.

  1. Rotational barriers in ammonium hexachlorometallates as studied by NMR, tunneling spectroscopy and ab initio calculations

    DEFF Research Database (Denmark)

    Birczynski, A.; Lalowicz, Z.T.; Lodziana, Zbigniew

    2004-01-01

    Ammonium hexachlorometallates, (NH4)(2)MCl6 With M = Pd, Pt, Ir, Os, Re, Se, Sn, Te and Pb, comprise a set of compounds with systematically changing properties. The compounds may be ordered according to decreasing tunnelling frequency (TF) of ammonium ions, which is related to the increasing...... structure explain observed variation of the tunnelling frequencies for NH4+. The theory provides also M-Cl distances and barriers for C-2 and C-3 rotations of ammonium ions in respective compounds, which show good agreement with experimental values. (C) 2004 Elsevier B.V. All rights reserved....

  2. Short-rotation forestry for energy production in Hawaii

    Energy Technology Data Exchange (ETDEWEB)

    Phillips, V.C.; Liu, W. [Univ. of Hawaii, Honolulu, HI (United States); Merriam, R.A.

    1993-12-31

    In Hawaii, imports of fossil fuels continue to accelerate and now provide over 90% of the total energy supply at a cost exceeding $1 {times} 10{sup 9} annually exported from the local economy. Concurrently, sugarcane and pineapple crops, the traditional mainstays of the state`s economy, have declined such that as much as 80,000 hectares of agricultural land are now available for alternative land uses. The feasibility of short-rotation forestry for sustainable energy production on these former sugarcane and pineapple plantation lands is being evaluated using species- and site-specific empirical models to predict yields of Eucalyptus grandis, E. saligna, and Leucaena leucocephala, a system model to estimate delivered costs, and a geographic information system to extend the analysis to areas where no field trials exist and to present results in map form. The island of Hawaii is showcased as an application of the methodology. Modeling results of methanol, ethanol, and electricity production from tropical hardwoods are presented. Short-rotation forestry appears to hold promise for the greening of Hawaii`s energy system and agricultural lands for the benefit of the state`s citizens and visitors. The methodology is readily transferable to other regions of the United States and rest of the world.

  3. Ultrafast rotation in an amphidynamic crystalline metal organic framework.

    Science.gov (United States)

    Vogelsberg, Cortnie S; Uribe-Romo, Fernando J; Lipton, Andrew S; Yang, Song; Houk, K N; Brown, Stuart; Garcia-Garibay, Miguel A

    2017-12-26

    Amphidynamic crystals are an emergent class of condensed phase matter designed with a combination of lattice-forming elements linked to components that display engineered dynamics in the solid state. Here, we address the design of a crystalline array of molecular rotors with inertial diffusional rotation at the nanoscale, characterized by the absence of steric or electronic barriers. We solved this challenge with 1,4-bicyclo[2.2.2]octane dicarboxylic acid (BODCA)-MOF, a metal-organic framework (MOF) built with a high-symmetry bicyclo[2.2.2]octane dicarboxylate linker in a Zn 4 O cubic lattice. Using spin-lattice relaxation 1 H solid-state NMR at 29.49 and 13.87 MHz in the temperature range of 2.3-80 K, we showed that internal rotation occurs in a potential with energy barriers of 0.185 kcal mol -1 These results were confirmed with 2 H solid-state NMR line-shape analysis and spin-lattice relaxation at 76.78 MHz obtained between 6 and 298 K, which, combined with molecular dynamics simulations, indicate that inertial diffusional rotation is characterized by a broad range of angular displacements with no residence time at any given site. The ambient temperature rotation of the bicyclo[2.2.2]octane (BCO) group in BODCA-MOF constitutes an example where engineered rotational dynamics in the solid state are as fast as they would be in a high-density gas or in a low-density liquid phase.

  4. Rotation and diffusion of naphthalene on Pt(111)

    Science.gov (United States)

    Kolsbjerg, E. L.; Goubert, G.; McBreen, P. H.; Hammer, B.

    2018-03-01

    The behavior of naphthalene on Pt(111) surfaces is studied by combining insight from scanning tunneling microscopy (STM) and van der Waals enabled density functional theory. Adsorption, diffusion, and rotation are investigated by a series of variable temperature STM experiments revealing naphthalene ability to rotate on-site with ease with a rotational barrier of 0.69 eV. Diffusion to neighbouring sites is found to be more difficult. The experimental results are in good agreement with the theoretical investigations which confirm that the barrier for diffusion is slightly higher than the one for rotation. The theoretical barriers for rotation and translation are found to be 0.75 and 0.78 eV, respectively. An automatic mapping of the possible diffusion pathways reveals very detailed diffusion paths with many small local minima that would have been practically impossible to find manually. This automated procedure provides detailed insight into the preferred diffusion pathways that are important for our understanding of molecule-substrate interactions.

  5. The Taylor-Proudman column in a rapidly-rotating compressible fluid I. energy transports

    International Nuclear Information System (INIS)

    Park, Jun Sang

    2014-01-01

    A theoretical study is made of the steady flow of a compressible fluid in a rapidly rotating finite cylinder. Flow is generated by imposing mechanical and/or thermal disturbances at the rotating endwall disks. Both the Ekman and Rossby numbers are small. An examination is made of the energy budget for a control volume in the Ekman boundary layer. A combination of physical variables, which is termed the energy flux content, consisting of temperature and modified angular momentum, emerges to be relevant. The distinguishing features of a compressible fluid, in contrast to those of an incompressible fluid, are noted. A plausible argument is given to explain the difficulty in achieving the Taylor-Proudman column in a compressible rotating fluid. For the Taylor-Proudman column to be sustained, in the interior, it is shown that the net energy transport between the solid disk wall and the interior fluid should vanish. Physical rationalizations are facilitated by resorting to the concept of the afore-stated energy flux content.

  6. Institutional distributed energy interconnection barriers

    International Nuclear Information System (INIS)

    Castelaz, S.A.

    2002-01-01

    This PowerPoint presentation provided an introduction to Encorp Inc., a leading provider of network technology and infrastructure management solutions for the distributed energy market. Encorp develops and markets software and hardware technology solutions for communications, control and networking of distributed energy. It is developing and implementing real-time, distributed energy-focused solutions for a wide variety of applications through new products and services which are technology neutral, and easily networked. Encorp controls more than 500 MW of distributed power with a total of 127 customers. This paper reviewed 3 barriers (regulatory, contractual/tariffs, and business practices) based on US experience. The challenge remaining is to determine if microgrids can be used effectively, and to determine the limitations of bi-directional power flows. The key issues regarding how end-users can share the costs and maximize on the benefits of distributed energy resources include: standby service charges, departing load charges, regulatory uncertainty, rate class degradation, lack of incentives for utility cost reduction, and lack of ability to create experimental tariffs. tabs., figs

  7. Free energy barriers to evaporation of water in hydrophobic confinement.

    Science.gov (United States)

    Sharma, Sumit; Debenedetti, Pablo G

    2012-11-08

    We use umbrella sampling Monte Carlo and forward and reverse forward flux sampling (FFS) simulation techniques to compute the free energy barriers to evaporation of water confined between two hydrophobic surfaces separated by nanoscopic gaps, as a function of the gap width, at 1 bar and 298 K. The evaporation mechanism for small (1 × 1 nm(2)) surfaces is found to be fundamentally different from that for large (3 × 3 nm(2)) surfaces. In the latter case, the evaporation proceeds via the formation of a gap-spanning tubular cavity. The 1 × 1 nm(2) surfaces, in contrast, are too small to accommodate a stable vapor cavity. Accordingly, the associated free energy barriers correspond to the formation of a critical-sized cavity for sufficiently large confining surfaces, and to complete emptying of the gap region for small confining surfaces. The free energy barriers to evaporation were found to be of O(20kT) for 14 Å gaps, and to increase by approximately ~5kT with every 1 Å increase in the gap width. The entropy contribution to the free energy of evaporation was found to be independent of the gap width.

  8. Rotation and transport in Alcator C-Mod ITB plasmas

    Science.gov (United States)

    Fiore, C. L.; Rice, J. E.; Podpaly, Y.; Bespamyatnov, I. O.; Rowan, W. L.; Hughes, J. W.; Reinke, M.

    2010-06-01

    Internal transport barriers (ITBs) are seen under a number of conditions in Alcator C-Mod plasmas. Most typically, radio frequency power in the ion cyclotron range of frequencies (ICRFs) is injected with the second harmonic of the resonant frequency for minority hydrogen ions positioned off-axis at r/a > 0.5 to initiate the ITBs. They can also arise spontaneously in ohmic H-mode plasmas. These ITBs typically persist tens of energy confinement times until the plasma terminates in radiative collapse or a disruption occurs. All C-Mod core barriers exhibit strongly peaked density and pressure profiles, static or peaking temperature profiles, peaking impurity density profiles and thermal transport coefficients that approach neoclassical values in the core. The strongly co-current intrinsic central plasma rotation that is observed following the H-mode transition has a profile that is peaked in the centre of the plasma and decreases towards the edge if the ICRF power deposition is in the plasma centre. When the ICRF resonance is placed off-axis, the rotation develops a well in the core region. The central rotation continues to decrease as long as the central density peaks when an ITB develops. This rotation profile is flat in the centre (0 ITB density profile is observed (0.5 ITB foot that is sufficiently large to stabilize ion temperature gradient instabilities that dominate transport in C-Mod high density plasmas.

  9. Energy education: breaking up the rational energy use barriers

    International Nuclear Information System (INIS)

    Dias, R.A.; Mattos, C.R.; Balestieri, J.A.P.

    2004-01-01

    Human development is associated directly or indirectly with the energy use, and because of this the energetic sources were dealt with in the recent past, as fully available to human necessities. The reality shows that the energy availability, considering the non-renewable sources, is limited, and beyond that, the exploration, the processing and the use of energy impose considerable impacts on the environment. There is not a system which operates with no losses and without imposing changes to the environment. Therefore, the energy conservation incorporates the concepts and the actions applied to the research of sustainable balance between nature and the energy availability and use. Such actions can be presented both in the short term, in which the energy system is close to a collapse, or in the medium/long term, in which those responsible for the energy policies are concerned with the structure of the socio-economic development. Such a situation requires more responsibility in the treatment of energy questions, mainly through education, which represents long-term investments. This paper discusses barriers that are present in the projects applied to energy conservation, by making clear that education is one of the best ways to transform the human behavior in for the rational use of energy

  10. Sustained turbulence and magnetic energy in non-rotating shear flows

    DEFF Research Database (Denmark)

    Nauman, Farrukh; Blackman, Eric G.

    2017-01-01

    From numerical simulations, we show that non-rotating magnetohydrodynamic shear flows are unstable to finite amplitude velocity perturbations and become turbulent, leading to the growth and sustenance of magnetic energy, including large scale fields. This supports the concept that sustained...... magnetic energy from turbulence is independent of the driving mechanism for large enough magnetic Reynolds numbers....

  11. Fission barriers in the quasi-molecular shape path

    International Nuclear Information System (INIS)

    Royer, G.; Bonilla, C.; Zbiri, K.; Gherghescu, R.A.

    2003-01-01

    New observed phenomena like asymmetric fission of intermediate mass nuclei, nuclear molecules in light nuclei, super and hyperdeformations, cluster radioactivity, fast-fission of heavy systems and fragmentation have renewed interest in investigating the fusion-like fission valley which leads rapidly to two touching spherical fragments and quasi-molecular shapes. Furthermore, rotating super and hyperdeformed nuclear states and superheavy nuclei can be formed only in heavy-ion collisions for which the initial configuration is two close quasi-spherical nuclei. For these shapes the balance between the Coulomb forces and surface tension forces does not allow to link the sheets of the potential energy surface corresponding to one-body shapes and to two separated fragments, respectively. It is necessary to add another term called proximity energy reproducing the finite-range effects of the nuclear force in the neck or the gap between the nascent fission fragments. A generalized liquid drop model has been developed to take into account this nuclear proximity energy, the mass and charge asymmetry, an accurate nuclear radius and the temperature effects. The initial value of the surface energy coefficient has been kept. Microscopic corrections have been determined within the asymmetric two center shell model or simpler algebraic approximations. With this model and deformation valley first studies had led to the following results: (i) good agreement between the potential barrier heights and the experimental fission barrier heights in the whole mass range; (ii) saddle-point corresponding to two separated fragments maintained in unstable equilibrium by the balance between the repulsive Coulomb forces and the attractive proximity forces; (iii) strong enhancement of the maximal angular momentum against fission; (iv) reasonable agreement with experimental data on the double-humped barriers of actinides. Within this same approach we have recently shown that the calculated potential

  12. Energy valorization of the species used in short-rotation plantations

    International Nuclear Information System (INIS)

    Moya Roque, Roger; Tenorio Monge, Carolina; Salazar Zeledon, Estephania

    2016-01-01

    The energy potential of some non-traditional plantations for production of energy is exposed. Forest and forage species are utilized in Costa Rica for energy plantations. The characteristics of these species have been short rotation (1-3 years) and a production between 20 and 25 tonnes of dry matter per hectare. Agro-energy plantations are described. Gmelina arborea y Pennisetum purpureum species have been viable options for biomass production. However, the high cost of seedlings and land to cultivate have been one of the problems of this energy source [es

  13. Barriers and Solutions to Fieldwork Education in Hand Therapy.

    Science.gov (United States)

    Short, Nathan; Sample, Shelby; Murphy, Malachi; Austin, Brittany; Glass, Jillian

    2017-08-09

    Survey. Fieldwork education is a vital component of training the next generation of CHTs. Barriers and solutions to fieldwork rotations in hand therapy are examined, as well as proposed solutions, including recommendations for student preparation. This descriptive study examined barriers for certified hand therapist clinicians to accept students for clinical rotations and clinicians' preferences for student preparation before a rotation in a hand setting. A survey was developed, peer reviewed, and distributed using the electronic mailing list of the Hand Therapy Certification Commission via SurveyMonkey. Aggregate responses were analyzed to identify trends including barriers to student clinical rotations and recommendations for students to prepare for hand rotations. A total of 2080 participants responded to the survey, representing a 37% response rate. Common logistical barriers were identified for accepting students such as limited clinical time and space. Many clinicians (32% agree and 8% strongly agree) also felt that the students lack the clinical knowledge to be successful. Areas of knowledge, skill set, and experience were surveyed for development before a clinical rotation in a hand setting. Most respondents (74%) reported increased likelihood of accepting a student with the recommended preparation. Novel qualitative responses to improve clinical experiences are presented as well. Student preparation before a clinical rotation in a hand setting appears to be a significant barrier based on the survey results. Areas of recommended knowledge, skill set, and experience may serve to guide both formal and informal methods of student preparation before a hand-specific clinical rotation to facilitate knowledge translation from experienced certified hand therapists to the next generation. Although logistical barriers may be difficult to overcome, hand-specific preparation based on clinician' recommendations may facilitate student acceptance and success in hand

  14. Efficient free energy calculations for compounds with multiple stable conformations separated by high energy barriers

    NARCIS (Netherlands)

    Hritz, J.; Oostenbrink, C.

    2009-01-01

    Compounds with high intramolecular energy barriers represent challenging targets for free energy calculations because of the difficulty to obtain sufficient conformational sampling. Existing approaches are therefore computationally very demanding, thus preventing practical applications for such

  15. Heavy ion collisions at energies near the Coulomb barrier 1990

    International Nuclear Information System (INIS)

    Nagarajan, M.A.

    1991-01-01

    During recent years, detailed experimental and theoretical investigations have been carried out on heavy ion collisions at energies close to the Coulomb barrier. These studies have provided direct evidence of strong couplings between the various reaction channels available at energies near the top of the Coulomb barrier. This field of research has remained the focus of interest and with improved experimental techniques, new detailed high resolution data have been obtained. The workshop on ''Heavy Ion Collisions at Energies Close to the Coulomb Barrier'' was organized with the aim of reviewing the current understanding of the collision dynamics and to discuss future directions in this area of research. The topics discussed at the workshop were broadly classified under the titles: quasielastic reactions; fusion of heavy ions; and shape and spin dependence in heavy ion collisions. The last of these topics was included to review new data obtained with polarized heavy ions and their theoretical interpretations. This volume contains the invited and contributed talks as well as a few short presentations during panel discussions. (author)

  16. Vib--rotational energy distributions and relaxation processes in pulsed HF chemical lasers

    International Nuclear Information System (INIS)

    Ben-Shaul, A.; Kompa, K.L.; Schmailzl, U.

    1976-01-01

    The rate equations governing the temporal evolution of photon densities and level populations in pulsed F+H 2 →HF+H chemical lasers are solved for different initial conditions. The rate equations are solved simultaneously for all relevant vibrational--rotational levels and vibrational--rotational P-branch transitions. Rotational equilibrium is not assumed. Approximate expressions for the detailed state-to-state rate constants corresponding to the various energy transfer processes (V--V, V--R,T, R--R,T) coupling the vib--rotational levels are formulated on the basis of experimental data, approximate theories, and qualitative considerations. The main findings are as follows: At low pressures, R--T transfer cannot compete with the stimulated emission, and the laser output largely reflects the nonequilibrium energy distribution in the pumping reaction. The various transitions reach threshold and decay almost independently and simultaneous lasing on several lines takes place. When a buffer gas is added in excess to the reacting mixture, the enhanced rotational relaxation leads to nearly single-line operation and to the J shift in lasing. Laser efficiency is higher at high inert gas pressures owing to a better extraction of the internal energy from partially inverted populations. V--V exchange enhances lasing from upper vibrational levels but reduces the total pulse intensity. V--R,T processes reduce the efficiency but do not substantially modify the spectral output distribution. The photon yield ranges between 0.4 and 1.4 photons/HF molecule depending on the initial conditions. Comparison with experimental data, when available, is fair

  17. Deep inelastic collisions at near-barrier energies and search for cold donor-fragment production

    International Nuclear Information System (INIS)

    Chatterjee, M.B.

    1992-01-01

    Deep inelastic collisions in the near barrier energies of the mass asymmetric systems are of importance since controversial results on energy partition are being reported. Energy dissipation and the partition of dissipated energy among the reaction partners are of interest. Search for cold donor-fragment production at near barrier energies were carried out on a mass asymmetric system like Ni+Pb. (author). 13 refs., 8 figs

  18. Barriers to the adoption of energy-conserving technologies in the textile industry

    Energy Technology Data Exchange (ETDEWEB)

    Evans, A.R.; Zussman, S.K.

    1979-09-01

    An overview of the textile industry and a discussion of energy-conserving technologies currently available at the pilot-demonstration stage are presented. Existing and potential barriers to the adoption of these technologies in the textile industry identified are: economic; technical acceptance; conflict between commitments of capital for compliance with environmental and health regulations and for investment in energy conservation measures; and a lack of information and technical expertise. Possible measures to eliminate barriers to the implementation of energy-conserving technologies are discussed. (MCW)

  19. Transition to distributed energy generation in Finland: Prospects and barriers

    International Nuclear Information System (INIS)

    Ruggiero, Salvatore; Varho, Vilja; Rikkonen, Pasi

    2015-01-01

    Small-scale distributed energy generation is expected to play an important role in helping Finland increase its energy self-sufficiency. However, the overall strategy to date for promoting distributed energy remains unclear. It is not yet well understood which factors promote the growth of the distributed energy sector and what barriers need to be removed. In this article we present the results of a questionnaire directed at a panel of 26 experts from the distributed energy value chain and 15 semi-structured interviews with industry and non-industry representatives. We investigated, from a sociotechnical transition perspective, the possibilities and challenges of the transition to distributed energy in Finland through 2025. The results show that a shift to a prosperous future for distributed energy is possible if permit procedures, ease of grid connection, and taxation laws are improved in the electricity sector and new business concepts are introduced in the heat sector. In contrast to other European countries, the transition in Finland is expected to take place through a market-based approach favoring investment-focused measures. We conclude that incentive-based schemes alone, whatever they may be, will be insufficient to create significant growth in Finland without institutional change, removal of barriers, and the engagement of key actors. - Highlights: • We examine the possibilities and challenges of the transition to DE in Finland. • Technological niches are emerging both in the heat and electricity sector. • Business model innovation is evident only in the electricity sector. • Removing barriers and developing new business models will accelerate the transition.

  20. Technical Barriers, Gaps, and Opportunities Related to Home Energy Upgrade Market Delivery

    Energy Technology Data Exchange (ETDEWEB)

    Bianchi, M. V. A.

    2011-11-01

    This report outlines the technical barriers, gaps, and opportunities that arise in executing home energy upgrade market delivery approaches, as identified through research conducted by the U.S. Department of Energy's Building America program. The objective of this report is to outline the technical1 barriers, gaps, and opportunities that arise in executing home energy upgrade market delivery approaches, as identified through research conducted by the U.S. Department of Energy's (DOE) Building America program. This information will be used to provide guidance for new research necessary to enable the success of the approaches. Investigation for this report was conducted via publications related to home energy upgrade market delivery approaches, and a series of interviews with subject matter experts (contractors, consultants, program managers, manufacturers, trade organization representatives, and real estate agents). These experts specified technical barriers and gaps, and offered suggestions for how the technical community might address them. The potential benefits of home energy upgrades are many and varied: reduced energy use and costs; improved comfort, durability, and safety; increased property value; and job creation. Nevertheless, home energy upgrades do not comprise a large part of the overall home improvement market. Residential energy efficiency is the most complex climate intervention option to deliver because the market failures are many and transaction costs are high (Climate Change Capital 2009). The key reasons that energy efficiency investment is not being delivered are: (1) The opportunity is highly fragmented; and (2) The energy efficiency assets are nonstatus, low-visibility investments that are not properly valued. There are significant barriers to mobilizing the investment in home energy upgrades, including the 'hassle factor' (the time and effort required to identify and secure improvement works), access to financing, and the

  1. Determination of the Rotational Barrier for Kinetically Stable Conformational Isomers via NMR and 2D TLC: An Introductory Organic Chemistry Experiment

    Science.gov (United States)

    Rushton, Gregory T.; Burns, William G.; Lavin, Judi M.; Chong, Yong S.; Pellechia, Perry; Shimizu, Ken D.

    2007-01-01

    An experiment to determine the rotational barrier about a C[subscript aryl]-N[subscript imide] single bond that is suitable for first-semester organic chemistry students is presented. The investigation begins with the one-step synthesis of a N,N'-diaryl naphthalene diimide, which exists as two room temperature-stable atropisomers (syn and anti).…

  2. Critical energy barrier for capillary condensation in mesopores: Hysteresis and reversibility

    International Nuclear Information System (INIS)

    Hiratsuka, Tatsumasa; Tanaka, Hideki; Miyahara, Minoru T.

    2016-01-01

    Capillary condensation in the regime of developing hysteresis occurs at a vapor pressure, P cond , that is less than that of the vapor-like spinodal. This is because the energy barrier for the vapor-liquid transition from a metastable state at P cond becomes equal to the energy fluctuation of the system; however, a detailed mechanism of the spontaneous transition has not been acquired even through extensive experimental and simulation studies. We therefore construct accurate atomistic silica mesopore models for MCM-41 and perform molecular simulations (gauge cell Monte Carlo and grand canonical Monte Carlo) for argon adsorption on the models at subcritical temperatures. A careful comparison between the simulation and experiment reveals that the energy barrier for the capillary condensation has a critical dimensionless value, W c * = 0.175, which corresponds to the thermal fluctuation of the system and depends neither on the mesopore size nor on the temperature. We show that the critical energy barrier W c * controls the capillary condensation pressure P cond and also determines a boundary between the reversible condensation/evaporation regime and the developing hysteresis regime.

  3. Critical energy barrier for capillary condensation in mesopores: Hysteresis and reversibility

    Science.gov (United States)

    Hiratsuka, Tatsumasa; Tanaka, Hideki; Miyahara, Minoru T.

    2016-04-01

    Capillary condensation in the regime of developing hysteresis occurs at a vapor pressure, Pcond, that is less than that of the vapor-like spinodal. This is because the energy barrier for the vapor-liquid transition from a metastable state at Pcond becomes equal to the energy fluctuation of the system; however, a detailed mechanism of the spontaneous transition has not been acquired even through extensive experimental and simulation studies. We therefore construct accurate atomistic silica mesopore models for MCM-41 and perform molecular simulations (gauge cell Monte Carlo and grand canonical Monte Carlo) for argon adsorption on the models at subcritical temperatures. A careful comparison between the simulation and experiment reveals that the energy barrier for the capillary condensation has a critical dimensionless value, Wc* = 0.175, which corresponds to the thermal fluctuation of the system and depends neither on the mesopore size nor on the temperature. We show that the critical energy barrier Wc* controls the capillary condensation pressure Pcond and also determines a boundary between the reversible condensation/evaporation regime and the developing hysteresis regime.

  4. Quantitative rotating frame relaxometry methods in MRI.

    Science.gov (United States)

    Gilani, Irtiza Ali; Sepponen, Raimo

    2016-06-01

    Macromolecular degeneration and biochemical changes in tissue can be quantified using rotating frame relaxometry in MRI. It has been shown in several studies that the rotating frame longitudinal relaxation rate constant (R1ρ ) and the rotating frame transverse relaxation rate constant (R2ρ ) are sensitive biomarkers of phenomena at the cellular level. In this comprehensive review, existing MRI methods for probing the biophysical mechanisms that affect the rotating frame relaxation rates of the tissue (i.e. R1ρ and R2ρ ) are presented. Long acquisition times and high radiofrequency (RF) energy deposition into tissue during the process of spin-locking in rotating frame relaxometry are the major barriers to the establishment of these relaxation contrasts at high magnetic fields. Therefore, clinical applications of R1ρ and R2ρ MRI using on- or off-resonance RF excitation methods remain challenging. Accordingly, this review describes the theoretical and experimental approaches to the design of hard RF pulse cluster- and adiabatic RF pulse-based excitation schemes for accurate and precise measurements of R1ρ and R2ρ . The merits and drawbacks of different MRI acquisition strategies for quantitative relaxation rate measurement in the rotating frame regime are reviewed. In addition, this review summarizes current clinical applications of rotating frame MRI sequences. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  5. Closed Loop Short Rotation Woody Biomass Energy Crops

    Energy Technology Data Exchange (ETDEWEB)

    Brower, Michael [CRC Development, LLC, Oakland, CA (United States)

    2012-09-30

    CRC Development LLC is pursuing commercialization of shrub willow crops to evaluate and confirm estimates of yield, harvesting, transportation and renewable energy conversion costs and to provide a diverse resource in its supply portfolio.The goal of Closed Loop Short Rotation Woody Biomass Energy Crops is supply expansion in Central New York to facilitate the commercialization of willow biomass crops as part of the mix of woody biomass feedstocks for bioenergy and bioproducts. CRC Development LLC established the first commercial willow biomass plantation acreage in North America was established on the Tug Hill in the spring of 2006 and expanded in 2007. This was the first 230- acres toward the goal of 10,000 regional acres. This project replaces some 2007-drought damaged acreage and installs a total of 630-acre new planting acres in order to demonstrate to regional agricultural producers and rural land-owners the economic vitality of closed loop short rotation woody biomass energy crops when deployed commercially in order to motivate new grower entry into the market-place. The willow biomass will directly help stabilize the fuel supply for the Lyonsdale Biomass facility, which produces 19 MWe of power and exports 15,000 pph of process steam to Burrows Paper. This project will also provide feedstock to The Biorefinery in New York for the manufacture of renewable, CO2-neutral liquid transportation fuels, chemicals and polymers. This project helps end dependency on imported fossil fuels, adds to region economic and environmental vitality and contributes to national security through improved energy independence.

  6. Barriers to energy efficiency in shipping: A triangulated approach to investigate the principal agent problem

    International Nuclear Information System (INIS)

    Rehmatulla, Nishatabbas; Smith, Tristan

    2015-01-01

    Energy efficiency is a key policy strategy to meet some of the challenges being faced today and to plan for a sustainable future. Numerous empirical studies in various sectors suggest that there are cost-effective measures that are available but not always implemented due to existence of barriers to energy efficiency. Several cost-effective energy efficient options (technologies for new and existing ships and operations) have also been identified for improving energy efficiency of ships. This paper is one of the first to empirically investigate barriers to energy efficiency in the shipping industry using a novel framework and multidisciplinary methods to gauge implementation of cost-effective measures, perception on barriers and observations of barriers. It draws on findings of a survey conducted of shipping companies, content analysis of shipping contracts and analysis of energy efficiency data. Initial results from these methods suggest the existence of the principal agent problem and other market failures and barriers that have also been suggested in other sectors and industries. Given this finding, policies to improve implementation of energy efficiency in shipping need to be carefully considered to improve their efficacy and avoid unintended consequences. -- Highlights: •We provide the first analysis of the principal agent problem in shipping. •We develop a framework that incorporates methodological triangulation. •Our results show the extent to which this barrier is observed and perceived. •The presence of the barrier has implications on the policy most suited to shipping

  7. Wave energy fluxes and multi-decadal shoreline changes

    DEFF Research Database (Denmark)

    Kabuth, Alina Kristin; Kroon, Aart

    2014-01-01

    Spatial patterns of multidecadal shoreline changes in two microtidal, low-energetic embayments of southern Zealand, Denmark, were investigated by using the directional distribution of wave energy fluxes. The sites include a barrier island system attached to moraine bluffs, and a recurved spit...... variability of directional distributions of wave energy fluxes furthermore outlined potential sediment sources and sinks for the evolution of the barrier island system and for the evolution of the recurved spit....... adjacent to a cliff coast. The barrier island system is characterized by cross-shore translation and by an alignment of the barrier alongshore alternating directions of barrier-spit progradation in a bidirectional wave field. The recurved spit adjacent to the cliff coast experienced shoreline rotation...

  8. Should we quit our jobs? Challenges, barriers and recommendations for interdisciplinary energy research

    International Nuclear Information System (INIS)

    Schuitema, Geertje; Sintov, Nicole D.

    2017-01-01

    Many plea for a better integration of social sciences in energy research, which would imply more comprehensive interdisciplinary energy research. We argue that in order to achieve this, institutional barriers and research challenges need to be recognised and addressed. We identify six challenges and barriers, and provide recommendations for working towards solutions. We conclude that to engage in interdisciplinary research implies extra costs and fewer rewards for all researchers, particularly early and mid-career academics. We propose a new conceptualisation of practices and incentive structures among academic institutions, funding agencies, and publication outlets, and urge all energy researchers to join this debate. - Highlights: • Interdisciplinary energy research currently does not reach its full potential. • Social sciences are underutilised in energy research. • Barriers and challenges need to be addressed to stimulate interdisciplinary energy research. • High costs and small rewards for interdisciplinary (early and mid-career) researchers.

  9. Ultrafast rotation in an amphidynamic crystalline metal organic framework

    Energy Technology Data Exchange (ETDEWEB)

    Vogelsberg, Cortnie S.; Uribe-Romo, Fernando J.; Lipton, Andrew S.; Yang, Song; Houk, K. N.; Brown, Stuart; Garcia-Garibay, Miguel A.

    2017-12-11

    Amphidynamic crystals are an emergent class of condensed phase matter designed with a combination of lattice-forming elements linked to components that display engineered dynamics in the solid state. Here, we address the design of a crystalline array of molecular rotors with inertial diffusional rotation at the nanoscale, characterized by the absence of steric or electronic barriers. We solved this challenge with 1,4-bicyclo[2.2.2]octane dicarboxylic acid (BODCA)-MOF, a metal-organic framework (MOF) built with a high-symmetry bicyclo[2.2.2]octane dicarboxylate linker in a Zn4O cubic lattice. Using spin-lattice relaxation 1H solid-state NMR at 29.49 and 13.87 MHz in the temperature range of 2.3–80 K, we showed that internal rotation occurs in a potential with energy barriers of 0.185 kcal mol-1. These results were confirmed with 2H solid-state NMR line-shape analysis and spin-lattice relaxation at 76.78 MHz obtained between 6 and 298 K, which, combined with molecular dynamics simulations, indicate that inertial diffusional rotation is characterized by a broad range of angular displacements with no residence time at any given site. The ambient temperature rotation of the bicyclo[2.2.2]octane (BCO) group in BODCA-MOF constitutes an example where engineered rotational dynamics in the solid state are as fast as they would be in a high-density gas or in a low-density liquid phase.

  10. Potential and barrier study. Energy efficiency in Norwegian vocational buildings; Potensial- og barrierestudie. Energieffektivisering i norske yrkesbygg

    Energy Technology Data Exchange (ETDEWEB)

    Boehn, Trond Ivar; Palm, Linn Therese; Bakken, Line; Nossum, Aase; Jordell, Hanne

    2012-07-01

    On behalf of Enova SF, Multiconsult AS and Analyse og Strategi AS conducted an analysis to identify potential and barriers related to commercial buildings energy performance. The aim of this study was to determine what is the potential for energy efficiency for Norwegian vocational buildings that distinguishes between theoretical, technical, financial and real potential. Technical potential is the percentage of the theoretical potential that is technically feasible. Economic potential is the proportion of technical potential that is economically profitable to implement. Economic potential varies with the energy price. Build a small part of the total potential in 2020. In the calculation of the real potential is taken into account induced potential in terms of that, each year, a percentage actually implementing energy conservation measures (energy efficiency ratio 2%), a percentage rehabilitating / upgrading existing buildings (rehab rate 1.5%), and that a proportion of new buildings built better than regulatory requirements (rate 10%). In real potential for energy efficiency is the proportion of the economic potential that is not natural triggered but which is limited by various barriers. In real potential also varies with energy price. Respondents in our study is particularly concerned with the economic barriers, and least concerned the technical barriers. Attitudes and knowledge barriers are also very important. Lack of knowledge the effects and benefits of energy efficiency means that negative attitudes persist and that myths about the lack of profitability continues to exist. Many believe this is due to lack the knowledge and can be the cause of other types of barriers such as economic barriers. It has been analyzed which part of the real potential bounded by the barriers, and which type of institutions in society that can reduce these barriers with various categories of instrument. Main barriers for existing buildings practical barriers, economic barriers and

  11. Identifying barriers to aboriginal renewable energy deployment in Canada

    International Nuclear Information System (INIS)

    Krupa, Joel

    2012-01-01

    As one of the largest and wealthiest countries in the world, Canada stands well-positioned to take advantage of ongoing growth in North American demand for primary energy supply by expanding domestic delivery of renewable energy generation to internationally interconnected electric grids across the country. There are myriad benefits of adopting the renewable energy approach to development—as the province of Ontario has acknowledged through the implementation of their 2009 Green Energy Act—including drastic reductions in carbon emissions, the decommissioning of existing fossil fuel power generation that cause serious public health problems, and opportunities for sustainable development at the community level. One group in particular stands poised to shape these debates. In Canada, historically marginalized Aboriginal peoples remain one of the groups with the greatest potential for meeting these enormous renewable energy deployment needs. Aboriginal involvement in renewable energy generation in Canada has been as diverse as Canada's Aboriginal peoples and groups have already adopted a range of different solutions to meet energy supply needs. However, many significant barriers exist that prevent this diverse cultural group from reaching its full potential. The article identifies some of these shortcomings and analyzes their roots. - Highlights: ► Renewable energy is one of the most important sustainable development opportunities today. ► Aboriginal-led renewable development could dramatically increase Canadian supply. ► Surmountable barriers are identified.

  12. Simultaneous Feedback Control of Plasma Rotation and Stored Energy on the DIII-D Tokamak

    International Nuclear Information System (INIS)

    Scoville, J.T.; Ferron, J.R.; Humphreys, D.A.; Walker, M.L.

    2006-01-01

    One of the major modifications made to the DIII-D tokamak during the 2005 Long Torus Opening was the rotation of one of the four two-source neutral beam injection systems. Prior to this modification, all beams injected power with a component in the same direction as the usual plasma current ('' co-injection ''). Starting in early 2006, two of the seven beams inject with a component in the opposite direction ('' counter-injection ''). This new capability allows, for the first time, a partial decoupling of the injected energy and momentum during neutral beam heating experiments. An immediate advantage of mixed co- and counter-injection beams is the capability to control the plasma rotation velocity. High beta plasmas can now be studied over a wide range of the plasma rotation velocity. The stabilizing effect of rotation on the resistive wall mode (RWM), for example, can be directly compared to the stabilization achieved by external feedback coils. This is an advantage over previous techniques to control plasma rotation, such as magnetic braking, which have had only limited success. We describe development and implementation of a model-based control algorithm for simultaneous regulation of plasma rotation and beta. The model includes the two relevant plasma states (plasma rotation and stored energy), and describes the dynamic effects of the relevant actuators on those states. The actuators include the applied beam torque and beam power, which depend on the amount of co and counter-injected beams. Implementation of the model-based control within the plasma control system (PCS) [B.G. Penaflor, et al, '' Current Status of DIII-D Plasma Control System Computer Upgrades,'' Fusion Eng. and Design 71 (2004) 47] requires real-time measurements of the plasma rotation, obtained from the charge exchange recombination (CER) diagnostic, and stored energy calculated by the real-time EFIT equilibrium reconstruction. Details of this model and its development, and a comparison with

  13. Identifying barriers in the diffusion of renewable energy sources

    International Nuclear Information System (INIS)

    Eleftheriadis, Iordanis M.; Anagnostopoulou, Evgenia G.

    2015-01-01

    Rapid diffusion of renewable energy sources (RES) in the electricity power sector is crucial if the EU wants to fulfill its 2050 CO 2 reduction commitments. For this reason, identifying and alleviating all barriers that hinder the development of RES is necessary to the successful deployment of these technologies. This paper discusses the main barriers in the diffusion of wind and photovoltaic (PV) solar power in the Greek electricity sector by drawing on the literature of technological innovation systems and system functions. Furthermore, we provide an explanation of the different diffusion rates between the two technologies. Inadequate financial resources, low grid capacity, delays in the issuance of building permits, opposition from local communities to the construction of wind farms and the lack of a stable institutional framework are among the most important barriers that inhibit the diffusion of the wind and PV solar power. The nature of the barriers identified in this study calls for policy intervention. - Highlights: • Firms in the Greek wind and solar power sectors assess RES barriers. • Lack of financial resources is the most important RES barrier. • Lack of a stable institutional framework negatively affects RES deployment. • The support of the public sector is crucial to the diffusion of RES. •Wind power faces strong legitimization barriers

  14. Controlling Schottky energy barriers in organic electronic devices using self-assembled monolayers

    Science.gov (United States)

    Campbell, I. H.; Rubin, S.; Zawodzinski, T. A.; Kress, J. D.; Martin, R. L.; Smith, D. L.; Barashkov, N. N.; Ferraris, J. P.

    1996-11-01

    We demonstrate tuning of Schottky energy barriers in organic electronic devices by utilizing chemically tailored electrodes. The Schottky energy barrier of Ag on poly[2-methoxy, 5-(2'-ethyl-hexyloxy)- 1,4-phenylene was tuned over a range of more than 1 eV by using self-assembled monolayers (SAM's) to attach oriented dipole layers to the Ag prior to device fabrication. Kelvin probe measurements were used to determine the effect of the SAM's on the Ag surface potential. Ab initio Hartree-Fock calculations of the molecular dipole moments successfully describe the surface potential changes. The chemically tailored electrodes were then incorporated in organic diode structures and changes in the metal/organic Schottky energy barriers were measured using an electroabsorption technique. These results demonstrate the use of self-assembled monolayers to control metal/organic interfacial electronic properties. They establish a physical principle for manipulating the relative energy levels between two materials and demonstrate an approach to improve metal/organic contacts in organic electronic devices.

  15. E4 - Energy efficient elevators and escalators. Barriers to and strategies for promoting energy-efficient lift and escalator technologies

    Energy Technology Data Exchange (ETDEWEB)

    Duetschke, Elisabeth; Hirzel, Simon

    2010-02-25

    According to prior findings of the E4 project, considerable savings potential exists both for lifts and escalators that could be realized if appropriate technology is implemented. However, energy-efficient technology is slowly diffusing the market - a phenomenon that could be explained by barriers present in the market. A barrier is defined as a mechanism that inhibits a decision or behavior that appears to be both energy-efficient and economically efficient and thereby prevents investment in energy-efficient technologies. This document has two aims. First, it will identify influential barriers in the European lift and escalator market. This analysis is based on the literature as well as a study including interviews as well as group discussions with relevant stakeholders. Second, strategies and measures to overcome the barriers identified in the first step are outlined. Major barriers to the penetration of energy-efficient technologies identified in this paper include a lack of monitoring energy consumption of installations and a lack of awareness of as well as knowledge about energy-efficient technology. Thus, installations and components are usually chosen without a (comprehensive) assessment of their energy consumption and without considering life-cycle approaches. On top of this, split incentives are a regularly occurring barrier. Various stakeholders are influential in the decisionmaking process about an installation or its components. However, those who will later pay for the energy consumption often are not involved in this process. Moreover, it is important to keep in mind that the number of new lifts and escalators installed each year is relatively low compared to the existing stock. Thus, it is very important to discuss enhancement of energy efficiency also for the existing stock. Based on our analyses, several recommendations are developed in this paper that could contribute to a market transformation in the lift and escalator market. First of all, a

  16. Direct measurement of free-energy barrier to nucleation of crystallites in amorphous silicon thin films

    Science.gov (United States)

    Shi, Frank G.

    1994-01-01

    A method is introduced to measure the free-energy barrier W(sup *), the activation energy, and activation entropy to nucleation of crystallites in amorphous solids, independent of the energy barrier to growth. The method allows one to determine the temperature dependence of W(sup *), and the effect of the preparation conditions of the initial amorphous phase, the dopants, and the crystallization methds on W(sup *). The method is applied to determine the free-energy barrier to nucleation of crystallites in amorphous silicon (a-Si) thin films. For thermally induced nucleation in a-Si thin films with annealing temperatures in the range of from 824 to 983 K, the free-energy barrier W(sup *) to nucleation of silicon crystals is about 2.0 - 2.1 eV regardless of the preparation conditions of the films. The observation supports the idea that a-Si transforms into an intermediate amorphous state through the structural relaxation prior to the onset of nucleation of crystallites in a-Si. The observation also indicates that the activation entropy may be an insignificant part of the free-energy barrier for the nucleation of crystallites in a-Si. Compared with the free-energy barrier to nucleation of crystallites in undoped a-Si films, a significant reduction is observed in the free-energy barrier to nucleation in Cu-doped a-Si films. For a-Si under irradiation of Xe(2+) at 10(exp 5) eV, the free-energy barrier to ion-induced nucleation of crystallites is shown to be about half of the value associated with thermal-induced nucleation of crystallites in a-Si under the otherwise same conditions, which is much more significant than previously expected. The present method has a general kinetic basis; it thus should be equally applicable to nucleation of crystallites in any amorphous elemental semiconductors and semiconductor alloys, metallic and polymeric glasses, and to nucleation of crystallites in melts and solutions.

  17. Barriers to investments in energy saving technologies. Case study for the industry

    NARCIS (Netherlands)

    Masselink, Dirk Jan

    2007-01-01

    To realise future energy saving targets, the government needs to increase energy reduction rates. One option to increase energy savings is found in removing barriers to investments in cost-effective energy saving technologies. Many technologies save energ

  18. Renewable Energy Permitting Barriers in Hawaii: Experience from the Field

    Energy Technology Data Exchange (ETDEWEB)

    Busche, S.; Donnelly, C.; Atkins, D.; Fields, R.; Black, C.

    2013-03-01

    This white paper presents a summary of the solicited input from permitting agencies and renewable energy developers on the permitting process in Hawaii to provide stakeholders in Hawaii, particularly those involved in permitting, with information on current permitting barriers that renewable energy developers are experiencing.

  19. Identifying and prioritizing barriers to implementation of smart energy city projects in Europe: An empirical approach

    International Nuclear Information System (INIS)

    Mosannenzadeh, Farnaz; Di Nucci, Maria Rosaria; Vettorato, Daniele

    2017-01-01

    Successful implementation of smart energy city projects in Europe is crucial for a sustainable transition of urban energy systems and the improvement of quality of life for citizens. We aim to develop a systematic classification and analysis of the barriers hindering successful implementation of smart energy city projects. Through an empirical approach, we investigated 43 communities implementing smart and sustainable energy city projects under the Sixth and Seventh Framework Programmes of the European Union. Validated through literature review, we identified 35 barriers categorized in policy, administrative, legal, financial, market, environmental, technical, social, and information-and-awareness dimensions. We prioritized these barriers, using a novel multi-dimensional methodology that simultaneously analyses barriers based on frequency, level of impact, causal relationship among barriers, origin, and scale. The results indicate that the key barriers are lacking or fragmented political support on the long term at the policy level, and lack of good cooperation and acceptance among project partners, insufficient external financial support, lack of skilled and trained personnel, and fragmented ownership at the project level. The outcome of the research should aid policy-makers to better understand and prioritize implementation barriers to develop effective action and policy interventions towards more successful implementation of smart energy city projects. - Highlights: • A solid empirical study on the implementation of European smart energy city projects. • We found 35 barriers in nine dimensions; e.g. policy, legal, financial, and social. • We suggested a new multi-dimensional methodology to prioritize barriers. • Lacking or fragmented political support on the long term is a key barrier. • We provided insights for action for project coordinators and policy makers.

  20. Woody biomass from short rotation energy crops. Chapter 2

    Science.gov (United States)

    R.S., Jr. Zalesny Jr.; M.W. Cunningham; R.B. Hall; J. Mirck; D.L. Rockwood; J.A. Stanturf; T.A. Volk

    2011-01-01

    Short rotation woody crops (SRWCs) are ideal for woody biomass production and management systems because they are renewable energy feedstocks for biofuels, bioenergy, and bioproducts that can be strategically placed in the landscape to conserve soil and water, recycle nutrients, and sequester carbon. This chapter is a synthesis of the regional implications of producing...

  1. Energy Barriers and Hysteresis in Martensitic Phase Transformations

    Science.gov (United States)

    2008-08-01

    glacial acetic acid (CH3COOH) and 10-15% perchloric acid (HCLO4) by volume, the cathode was stainless steel , the anode was stainless steel or Ti, the...Submitted to Acta Materialia Energy barriers and hysteresis in martensitic phase transformations Zhiyong Zhang, Richard D. James and Stefan Müller...hysteresis based on the growth from a small scale of fully developed austenite martensite needles. In this theory the energy of the transition layer plays a

  2. A low noise discrete velocity method for the Boltzmann equation with quantized rotational and vibrational energy

    Science.gov (United States)

    Clarke, Peter; Varghese, Philip; Goldstein, David

    2018-01-01

    A discrete velocity method is developed for gas mixtures of diatomic molecules with both rotational and vibrational energy states. A full quantized model is described, and rotation-translation and vibration-translation energy exchanges are simulated using a Larsen-Borgnakke exchange model. Elastic and inelastic molecular interactions are modeled during every simulated collision to help produce smooth internal energy distributions. The method is verified by comparing simulations of homogeneous relaxation by our discrete velocity method to numerical solutions of the Jeans and Landau-Teller equations, and to direct simulation Monte Carlo. We compute the structure of a 1D shock using this method, and determine how the rotational energy distribution varies with spatial location in the shock and with position in velocity space.

  3. A novel method for calculating the energy barriers for carbon diffusion in ferrite under heterogeneous stress

    Science.gov (United States)

    Tchitchekova, Deyana S.; Morthomas, Julien; Ribeiro, Fabienne; Ducher, Roland; Perez, Michel

    2014-07-01

    A novel method for accurate and efficient evaluation of the change in energy barriers for carbon diffusion in ferrite under heterogeneous stress is introduced. This method, called Linear Combination of Stress States, is based on the knowledge of the effects of simple stresses (uniaxial or shear) on these diffusion barriers. Then, it is assumed that the change in energy barriers under a complex stress can be expressed as a linear combination of these already known simple stress effects. The modifications of energy barriers by either uniaxial traction/compression and shear stress are determined by means of atomistic simulations with the Climbing Image-Nudge Elastic Band method and are stored as a set of functions. The results of this method are compared to the predictions of anisotropic elasticity theory. It is shown that, linear anisotropic elasticity fails to predict the correct energy barrier variation with stress (especially with shear stress) whereas the proposed method provides correct energy barrier variation for stresses up to ˜3 GPa. This study provides a basis for the development of multiscale models of diffusion under non-uniform stress.

  4. A novel method for calculating the energy barriers for carbon diffusion in ferrite under heterogeneous stress

    International Nuclear Information System (INIS)

    Tchitchekova, Deyana S.; Morthomas, Julien; Perez, Michel; Ribeiro, Fabienne; Ducher, Roland

    2014-01-01

    A novel method for accurate and efficient evaluation of the change in energy barriers for carbon diffusion in ferrite under heterogeneous stress is introduced. This method, called Linear Combination of Stress States, is based on the knowledge of the effects of simple stresses (uniaxial or shear) on these diffusion barriers. Then, it is assumed that the change in energy barriers under a complex stress can be expressed as a linear combination of these already known simple stress effects. The modifications of energy barriers by either uniaxial traction/compression and shear stress are determined by means of atomistic simulations with the Climbing Image-Nudge Elastic Band method and are stored as a set of functions. The results of this method are compared to the predictions of anisotropic elasticity theory. It is shown that, linear anisotropic elasticity fails to predict the correct energy barrier variation with stress (especially with shear stress) whereas the proposed method provides correct energy barrier variation for stresses up to ∼3 GPa. This study provides a basis for the development of multiscale models of diffusion under non-uniform stress

  5. A novel method for calculating the energy barriers for carbon diffusion in ferrite under heterogeneous stress

    Energy Technology Data Exchange (ETDEWEB)

    Tchitchekova, Deyana S. [IRSN, PSN, SEMIA, LPTM, Saint-Paul-Lez-Durance (France); Univ. Lyon, INSA Lyon, MATEIS, UMR CNRS 5510, Villeurbanne (France); Morthomas, Julien; Perez, Michel [Univ. Lyon, INSA Lyon, MATEIS, UMR CNRS 5510, Villeurbanne (France); Ribeiro, Fabienne [IRSN, PSN, SEMIA, LPTM, Saint-Paul-Lez-Durance (France); Ducher, Roland [IRSN, PSN, SAG, LETR, Saint-Paul-Lez-Durance (France)

    2014-07-21

    A novel method for accurate and efficient evaluation of the change in energy barriers for carbon diffusion in ferrite under heterogeneous stress is introduced. This method, called Linear Combination of Stress States, is based on the knowledge of the effects of simple stresses (uniaxial or shear) on these diffusion barriers. Then, it is assumed that the change in energy barriers under a complex stress can be expressed as a linear combination of these already known simple stress effects. The modifications of energy barriers by either uniaxial traction/compression and shear stress are determined by means of atomistic simulations with the Climbing Image-Nudge Elastic Band method and are stored as a set of functions. The results of this method are compared to the predictions of anisotropic elasticity theory. It is shown that, linear anisotropic elasticity fails to predict the correct energy barrier variation with stress (especially with shear stress) whereas the proposed method provides correct energy barrier variation for stresses up to ∼3 GPa. This study provides a basis for the development of multiscale models of diffusion under non-uniform stress.

  6. 11Li Breakup on 208 at energies around the Coulomb barrier.

    Science.gov (United States)

    Fernández-García, J P; Cubero, M; Rodríguez-Gallardo, M; Acosta, L; Alcorta, M; Alvarez, M A G; Borge, M J G; Buchmann, L; Diget, C A; Falou, H A; Fulton, B R; Fynbo, H O U; Galaviz, D; Gómez-Camacho, J; Kanungo, R; Lay, J A; Madurga, M; Martel, I; Moro, A M; Mukha, I; Nilsson, T; Sánchez-Benítez, A M; Shotter, A; Tengblad, O; Walden, P

    2013-04-05

    The inclusive breakup for the (11)Li + (208)Pb reaction at energies around the Coulomb barrier has been measured for the first time. A sizable yield of (9)Li following the (11)Li dissociation has been observed, even at energies well below the Coulomb barrier. Using the first-order semiclassical perturbation theory of Coulomb excitation it is shown that the breakup probability data measured at small angles can be used to extract effective breakup energy as well as the slope of B(E1) distribution close to the threshold. Four-body continuum-discretized coupled-channels calculations, including both nuclear and Coulomb couplings between the target and projectile to all orders, reproduce the measured inclusive breakup cross sections and support the presence of a dipole resonance in the (11)Li continuum at low excitation energy.

  7. Rotating Algal Biofilm Reactors: Mathematical Modeling and Lipid Production

    OpenAIRE

    Woolsey, Paul A.

    2011-01-01

    Harvesting of algal biomass presents a large barrier to the success of biofuels made from algae feedstock. Small cell sizes coupled with dilute concentrations of biomass in lagoon systems make separation an expensive and energy intense-process. The rotating algal biofilm reactor (RABR) has been developed at USU to provide a sustainable technology solution to this issue. Algae cells grown as a biofilm are concentrated in one location for ease of harvesting of high density biomass. A mathematic...

  8. Building energy efficiency for public hospitals and healthcare facilities in China: Barriers and drivers

    International Nuclear Information System (INIS)

    Wang, Tao; Li, Xiaodong; Liao, Pin-Chao; Fang, Dongping

    2016-01-01

    Maximizing energy efficiency within HHFs (hospitals and healthcare facilities) is a major challenge in the field of energy conservation. This paper studies the key barriers to the implementation of energy-efficient technologies in China's public HHFs. For this purpose, a preliminary survey was conducted at the Beijing Municipal Health Bureau in order to assess the energy conservation efforts being made at 20 public HHFs. In the survey, a list of specific barriers to energy efficiency was created and HHF staffs were asked to rank these barriers in the order of importance. The results show that the economic incentives, appropriate technology, as well as enforceable laws and regulations are insufficiently supported by the government, have become the most significant obstacles to the improvement of energy efficiency. To remedy this, policymakers should take a multipronged approach which addresses the hospitals, projects, and technical and operating procedures in order to encourage the full participation and support of all stakeholders involved. Specifically, the government should offer multilevel economic incentives and reward policies; establish practical mandatory targets for building energy efficiency; provide demonstrable best practices in terms of the project, techniques, and operating procedures; and promote awareness of the importance of property risk management. - Highlights: • We developed a checklist of building energy efficiency barriers of HHFs in China. • We took a survey to prioritize the barriers by the staff from 20 public HHFs. • Policy makers should provide multiple-level solutions to all the stakeholders. • Economic incentives, mandatory target, technique supports are critical drivers.

  9. On the study of rotational effects in mass asymmetric colliding nuclei at intermediate energies

    Science.gov (United States)

    Kaur, Kamaldeep; Kumar, Suneel

    2018-05-01

    The rotational dynamics has been studied for different mass asymmetric systems 49122In + 50126Sn, 48114Cs + 54134In, 40100Mo + 64148Gd, 3686Kr + 67162Ho, 3171Ga + 71177Lu, 2860Ni + 76188Os and 2450Cr + 78198 Pt for incident energies between 40 MeV/nucleon and 400 MeV/nucleon for impact parameter range 0.25 free protons have been compared successfully with IQMD model calculations. The rotational flow of free protons with increasing incident energies and elliptic flow (calculated from the fits of azimuthal distributions of free protons) dependence with energy has also been investigated.

  10. Display of rotational levels near the fission threshold in 232Th(n,f) reaction

    International Nuclear Information System (INIS)

    Blons, J.; Mazur, C.; Paya, D.

    1975-01-01

    The 232 Th(n,f) cross section has been measured relative to that of 235 U up to 5MeV, with a neutron energy resolution of 3keV at 1.6MeV. The angular anisotropy of fission fragments has also been measured in the same energy range with an energy resolution of 6keV at 1,6MeV. The broad vibrational levels located above 1MeV are resolved into sharp structures which are interpreted as rotational states. The rotational constants h 2 /2J of highly deformed 233 Th are found to be 2.45 and 2.65keV at 1.5 and 1.6MeV respectively. These results are interpreted by the possibility of a third minimum in the fission barrier [fr

  11. Molecular Viscosity Sensors with Two Rotators for Optimizing the Fluorescence Intensity-Contrast Trade-Off.

    Science.gov (United States)

    Lee, Seung-Chul; Lee, Chang-Lyoul; Heo, Jeongyun; Jeong, Chan-Uk; Lee, Gyeong-Hui; Kim, Sehoon; Yoon, Woojin; Yun, Hoseop; Park, Sung O; Kwak, Sang Kyu; Park, Sung-Ha; Kwon, O-Pil

    2018-02-26

    A series of fluorescent molecular rotors obtained by introducing two rotational groups ("rotators"), which exhibit different rotational and electron-donating abilities, are discussed. Whereas the control molecular rotor, PH, includes a single rotator (the widely used phenyl group), the PO molecular rotors consist of two rotators (a phenyl group and an alkoxy group), which exhibit simultaneous strongly electron-donating and easy rotational abilities. Compared with the control rotor PH, PO molecular rotors exhibited one order of magnitude higher quantum yield (fluorescence intensity) and simultaneously exhibited significantly higher fluorescence contrast. These properties are directly related to the strong electron-donating ability and low energy barrier of rotation of the alkoxy group, as confirmed by dynamic fluorescence experiments and quantum chemical calculations. The PO molecular rotors exhibited two fluorescence relaxation pathways, whereas the PH molecular rotor exhibited a single fluorescence relaxation pathway. Cellular fluorescence imaging with PO molecular rotors for mapping cellular viscosity was successfully demonstrated. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. The role of cooperatives in overcoming the barriers to adoption of renewable energy

    International Nuclear Information System (INIS)

    Viardot, Eric

    2013-01-01

    Recently, cooperatives have been created to promote the use of renewable energy (RE) most notably in Canada, the US, UK, Denmark or Germany. In order to develop the adoption of RE, the cooperatives have to seek to influence the behaviour of their members so that they switch from the use of traditional fossil energy to RE. This paper examines the various barriers to adoption of RE and the way cooperatives are circumventing those obstacles in order to develop the use of RE. This study surveyed a sample of 9 cooperatives from countries where governments are subsidizing the use of RE. The paper identifies a set of specific barriers to the adoption of RE by consumers. It also reveals that cooperatives effectively contribute to the uptake of RE with community-based social marketing initiatives that are lowering those barriers successfully. Those initiatives are related to educational communication, low prices, local offers with complementary services, and cooperative distribution. The paper put forwards a framework for the assessment of how each of those initiatives contributes to the diminishing of each of the barriers to adoption of RE. - Highlights: • We examine the barriers to adoption of renewable energy by RE cooperatives. • We have identified the main significant barriers to adoption of RE by consumers. • Cooperatives apply community-based marketing initiatives to ease the uptake of RE. • We evaluate how each marketing initiatives diminish the barriers to adoption of RE

  13. Addressing barriers to low carbon energy

    International Nuclear Information System (INIS)

    Berry, Fiona; Dunstan, Chris

    2012-01-01

    Full text: Two energy solutions gaining attention are cogeneration and trigeneration, mostly fuelled by natural gas, although other renewable sources can be used, such as sewage, agricultural waste and municipal waste. Trigeneration has become increasingly popular in Australia's urban centres as a relatively cost-effective means to cut the carbon-intensity of energy supply by more than half compared to traditional coal- fired electricity. Some examples of trigeneration projects include the City of Sydney's planned 360 megawatt trigeneration networks by 2030, the University of Technology Sydney's campus master plan and the six star Green Star Commonwealth Bank Place building in Sydney. Trigeneration and cogeneration can present opportunities such as addressing the issue of rising peak demand, which is a major driver for the current $9 billion per annum of network infrastructure spending. They can also face barriers. For example, depending on the current state of the network, additional network costs can be required to accommodate trigeneration. Furthermore, under the current National Electricity Market regulations and conventions, challenges do exist to timely and financially viable connection to the grid. Here we present two examples of barriers to trigeneration and cogeneration and solutions being considered and implemented. The University of Technology Sydney campus master plan is underway, with approximately 100,000sq.m of floor area being built by 2019 and includes plans for trigeneration. During the master planning phase of development, the university considered small trigeneration units in individual buildings in order to reduce the carbon intensity of electricity supply and deliver high ratings under Green Star ratings. When considering connecting trigeneration with the grid at multiple buildings on an individual basis, a number of barriers were encountered by UTS. The largest barrier was appropriate charging for connecting to and using the grid. However

  14. Financing Solar Energy Systems with Energy Savings Performance Contracts in the Federal Sector: Results of a Survey on Barriers

    Energy Technology Data Exchange (ETDEWEB)

    Gee, R. C.; LaPorta, C.

    1999-08-17

    This report summarizes the findings of an investigation into financing solar energy systems for the Federal sector. The objectives of the investigation were (1) to identify the barriers that impede companies from using Energy Savings Performance Contracts (ESPCs) to develop solar energy projects for Federal facilities, and (2) to clarify the impacts of Federal contracting requirements on energy service companies' use of ESPCs. Twenty-four representatives of energy service companies agreed to be interviewed. Their responses indicate that these are the primary barriers to greater use of ESPCs: the relatively long payback periods for investments in solar technologies; the length of the ESPC process; the cost of certain contractual requirements regarding wages and financing; and a lack of knowledge about the actual cost and reliability of solar systems. The report proposes a number of actions the government could take to remove these barriers, including (1) streamlining and shortening the ESPC process and (2) doing more to inform both government agencies and energy service companies about the costs and benefits of solar systems.

  15. Controlling Schottky energy barriers in organic electronic devices using self-assembled monolayers

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, I.H.; Rubin, S.; Zawodzinski, T.A.; Kress, J.D.; Martin, R.L.; Smith, D.L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Barashkov, N.N.; Ferraris, J.P. [The University of Texas at Dallas, Richardson, Texas 75083 (United States)

    1996-11-01

    We demonstrate tuning of Schottky energy barriers in organic electronic devices by utilizing chemically tailored electrodes. The Schottky energy barrier of Ag on poly[2-methoxy], 5-(2{prime}-ethyl-hexyloxy)- 1,4-phenylene was tuned over a range of more than 1 eV by using self-assembled monolayers (SAM{close_quote}s) to attach oriented dipole layers to the Ag prior to device fabrication. Kelvin probe measurements were used to determine the effect of the SAM{close_quote}s on the Ag surface potential. {ital Ab} {ital initio} Hartree-Fock calculations of the molecular dipole moments successfully describe the surface potential changes. The chemically tailored electrodes were then incorporated in organic diode structures and changes in the metal/organic Schottky energy barriers were measured using an electroabsorption technique. These results demonstrate the use of self-assembled monolayers to control metal/organic interfacial electronic properties. They establish a physical principle for manipulating the relative energy levels between two materials and demonstrate an approach to improve metal/organic contacts in organic electronic devices. {copyright} {ital 1996 The American Physical Society.}

  16. Controlling Schottky energy barriers in organic electronic devices using self-assembled monolayers

    International Nuclear Information System (INIS)

    Campbell, I.H.; Rubin, S.; Zawodzinski, T.A.; Kress, J.D.; Martin, R.L.; Smith, D.L.; Barashkov, N.N.; Ferraris, J.P.

    1996-01-01

    We demonstrate tuning of Schottky energy barriers in organic electronic devices by utilizing chemically tailored electrodes. The Schottky energy barrier of Ag on poly[2-methoxy], 5-(2'-ethyl-hexyloxy)- 1,4-phenylene was tuned over a range of more than 1 eV by using self-assembled monolayers (SAM close-quote s) to attach oriented dipole layers to the Ag prior to device fabrication. Kelvin probe measurements were used to determine the effect of the SAM close-quote s on the Ag surface potential. Ab initio Hartree-Fock calculations of the molecular dipole moments successfully describe the surface potential changes. The chemically tailored electrodes were then incorporated in organic diode structures and changes in the metal/organic Schottky energy barriers were measured using an electroabsorption technique. These results demonstrate the use of self-assembled monolayers to control metal/organic interfacial electronic properties. They establish a physical principle for manipulating the relative energy levels between two materials and demonstrate an approach to improve metal/organic contacts in organic electronic devices. copyright 1996 The American Physical Society

  17. Barriers and drivers for energy efficiency: Different perspectives from an exploratory study in the Netherlands

    International Nuclear Information System (INIS)

    Cagno, Enrico; Trianni, Andrea; Abeelen, Christiaan; Worrell, Ernst; Miggiano, Federica

    2015-01-01

    Highlights: • We investigated the perception of barriers and drivers and mechanisms regulating them. • Firms agree on the most important barriers and drivers. • Firms agree on the most critical decision-making steps and actors promoting drivers. • Major external actors perceive barriers, drivers and mechanisms differently. • Success of voluntary agreements depends on the link to other policy instruments. - Abstract: Increased energy efficiency represents a crucial opportunity for European industrial sustainability, but several barriers still need to be tackled. Thus, it is crucial to understand the existing mismatches between the perception of enterprises and what the major actors promoting energy efficiency believe enterprises suffer from and need within the decision-making process. To do so, we have performed an exploratory investigation analysing a set of manufacturing enterprises participating in the Dutch voluntary agreements. The study involved the major external actors, i.e. the national energy agency, governmental and industrial organisations, to map their views on the decision-making process. Results show that enterprises agree not only on the most important barriers and drivers, but also on the mechanisms underlying them. However, even a general common understanding of the barriers is disputed when major external actors are considered, as they only agree on the primary role of economic barriers. Mismatches appear when considering how single barriers affect the decision-making process and which drivers – and actors promoting them – need to be addressed. Although voluntary agreements represent the most popular instrument on energy efficiency in the Netherlands, they do not seem to be considered by small and medium-sized enterprises as a stimulus for improving energy efficiency. Crucial for future success are the link with other policy instruments, and the degree to which the instruments trigger the right drivers and barriers at the right

  18. Closing the Energy Efficiency Gap: A study linking demographics with barriers to adopting energy efficiency measures in the home

    International Nuclear Information System (INIS)

    Pelenur, Marcos J.; Cruickshank, Heather J.

    2012-01-01

    This paper presents a study which linked demographic variables with barriers affecting the adoption of domestic energy efficiency measures in large UK cities. The aim was to better understand the ‘Energy Efficiency Gap’ and improve the effectiveness of future energy efficiency initiatives. The data for this study was collected from 198 general population interviews (1.5–10 min) carried out across multiple locations in Manchester and Cardiff. The demographic variables were statistically linked to the identified barriers using a modified chi-square test of association (first order Rao–Scott corrected to compensate for multiple response data), and the effect size was estimated with an odds-ratio test. The results revealed that strong associations exist between demographics and barriers, specifically for the following variables: sex; marital status; education level; type of dwelling; number of occupants in household; residence (rent/own); and location (Manchester/Cardiff). The results and recommendations were aimed at city policy makers, local councils, and members of the construction/retrofit industry who are all working to improve the energy efficiency of the domestic built environment. -- Highlights: ► 7 demographic variables linked to 8 barriers to adopting energy efficiency measures. ► A modified chi-square test for association was used (first order Rao–Scott corrected). ► Results revealed strong associations between most of the demographics and barriers. ► Data was collected from 198 interviews in the UK cities of Manchester and Cardiff. ► Specific recommendations are presented for regional policy makers and industry.

  19. Examining barrier distributions and, in extension, energy derivative of probabilities for surrogate experiments

    International Nuclear Information System (INIS)

    Romain, P.; Duarte, H.; Morillon, B.

    2012-01-01

    The energy derivatives of probabilities are functions suited to a best understanding of certain mechanisms. Applied to compound nuclear reactions, they can bring information on fusion barrier distributions as originally introduced, and also, as presented here, on fission barrier distributions and heights. Extendedly, they permit to access the compound nucleus spin-parity states preferentially populated according to an entrance channel, at a given energy. (authors)

  20. Energy shift and conduction-to-valence band transition mediated by a time-dependent potential barrier in graphene

    Science.gov (United States)

    Chaves, Andrey; da Costa, D. R.; de Sousa, G. O.; Pereira, J. M.; Farias, G. A.

    2015-09-01

    We investigate the scattering of a wave packet describing low-energy electrons in graphene by a time-dependent finite-step potential barrier. Our results demonstrate that, after Klein tunneling through the barrier, the electron acquires an extra energy which depends on the rate of change of the barrier height with time. If this rate is negative, the electron loses energy and ends up as a valence band state after leaving the barrier, which effectively behaves as a positively charged quasiparticle.

  1. The role of confined collagen geometry in decreasing nucleation energy barriers to intrafibrillar mineralization.

    Science.gov (United States)

    Kim, Doyoon; Lee, Byeongdu; Thomopoulos, Stavros; Jun, Young-Shin

    2018-03-06

    Mineralization of collagen is critical for the mechanical functions of bones and teeth. Calcium phosphate nucleation in collagenous structures follows distinctly different patterns in highly confined gap regions (nanoscale confinement) than in less confined extrafibrillar spaces (microscale confinement). Although the mechanism(s) driving these differences are still largely unknown, differences in the free energy for nucleation may explain these two mineralization behaviors. Here, we report on experimentally obtained nucleation energy barriers to intra- and extrafibrillar mineralization, using in situ X-ray scattering observations and classical nucleation theory. Polyaspartic acid, an extrafibrillar nucleation inhibitor, increases interfacial energies between nuclei and mineralization fluids. In contrast, the confined gap spaces inside collagen fibrils lower the energy barrier by reducing the reactive surface area of nuclei, decreasing the surface energy penalty. The confined gap geometry, therefore, guides the two-dimensional morphology and structure of bioapatite and changes the nucleation pathway by reducing the total energy barrier.

  2. Barriers to energy efficiency in small industry clusters: Multi-criteria-based prioritization using the analytic hierarchy process

    International Nuclear Information System (INIS)

    Nagesha, N.; Balachandra, P.

    2006-01-01

    The small scale industry (SSI) is an important component of Indian economy and a majority of SSI units tend to exist in geographical clusters. Energy efficiency is crucial for the survival and growth of energy intensive SSI clusters, not only to improve their competitiveness through cost reduction but also to minimize adverse environmental impacts. However, this is easier said than done due to the presence of a variety of barriers. The identification of relevant barriers and their appropriate prioritization in such clusters is a prerequisite to effectively tackle them. This paper identifies relevant barriers to energy efficiency and their dimensions in SSI clusters. Further, the barriers are prioritized based on the perceptions and experiences of entrepreneurs, the main stakeholders of SSIs, using the analytic hierarchy process (AHP). The field data from two energy intensive clusters of foundry and brick and tile in Karnataka (a state in India) reveal that the prioritization remained the same despite differences in the relative weights of barrier groups. The financial and economic barrier (FEB) and behavioural and personal barrier (BPB) have emerged as the top two impediments to energy efficiency improvements

  3. On the economic analysis of problems in energy efficiency: Market barriers, market failures, and policy implications

    International Nuclear Information System (INIS)

    Sanstad, A.H.; Koomey, J.G.; Levine, M.D.

    1993-01-01

    In his recent paper in The Energy Journal, Ronald Sutherland argues that several so-called ''market barriers'' to energy efficiency frequently cited in the literature are not market failures in the conventional sense and are thus irrelevant for energy policy. We argue that Sutherland has inadequately analyzed the idea of market barrier and misrepresented the policy implications of microeconomics. We find that economic theory, correctly interpreted, does not provide for the categorical dismissal of market barriers. We explore important methodological issues underlying the debate over market barriers, and discuss the importance of reconciling the findings of non-economic social sciences with the economic analysis of energy demand and consumer decision-making. We also scrutinize Sutherland's attempt to apply finance theory to rationalize high implicit discount rates observed in energy-related choices, and find this use of finance theory to be inappropriate

  4. On the economic analysis of problems in energy efficiency: Market barriers, market failures, and policy implications

    Energy Technology Data Exchange (ETDEWEB)

    Sanstad, A.H.; Koomey, J.G.; Levine, M.D.

    1993-01-01

    In his recent paper in The Energy Journal, Ronald Sutherland argues that several so-called ``market barriers`` to energy efficiency frequently cited in the literature are not market failures in the conventional sense and are thus irrelevant for energy policy. We argue that Sutherland has inadequately analyzed the idea of market barrier and misrepresented the policy implications of microeconomics. We find that economic theory, correctly interpreted, does not provide for the categorical dismissal of market barriers. We explore important methodological issues underlying the debate over market barriers, and discuss the importance of reconciling the findings of non-economic social sciences with the economic analysis of energy demand and consumer decision-making. We also scrutinize Sutherland`s attempt to apply finance theory to rationalize high implicit discount rates observed in energy-related choices, and find this use of finance theory to be inappropriate.

  5. The methyl rotational potentials of Ga(CH sub 3) sub 3 derived by neutron spectroscopy

    CERN Document Server

    Prager, M; Parker, S F; Desmedt, A; Lechner, R E

    2002-01-01

    High resolution neutron spectra of Ga(CH sub 3) sub 3 show tunnelling transitions between 4.5 and 19 mu eV. The spectrum can be explained within the single-particle model on the basis of the monoclinic C2/c (Z = 16) low temperature crystal structure of Ga(CH sub 3) sub 3 with six inequivalent methyl groups in the unit cell. The overlapping tunnelling lines prevent the extraction of temperature dependent linewidths which would allow us to assign the librational energies measured in the phonon density of states. Classical rotational motion is studied by quasielastic neutron scattering. Three activation energies could be extracted. Methyl librations, tunnelling energies and barrier heights are combined with consistent intensities into rotational potentials. Only the concerted application of all spectroscopic techniques yields a conclusive description.

  6. Market barriers to energy efficiency: A critical reappraisal of the rationale for public policies to promote energy efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Golove, W.H.; Eto, J.H. [Lawrence Berkeley National Lab., CA (United States). Energy and Environment Div.

    1996-03-01

    This report reviews current perspectives on market barriers to energy efficiency. Ratepayer-funded utility energy-efficiency programs are likely to change in scope, size, and nature as the deregulation process proceeds; the authors research focuses on understanding to what extent some form of future intervention may be warranted and how they might judge the success of particular interventions, especially those funded by ratepayers. They find that challenges to the existence of market barriers have, for the most part, failed to provide a testable alternative explanation for evidence suggesting that there is a substantial ``efficiency gap`` between a consumer`s actual investments in energy efficiency and those that appear to be in the consumer`s own interest. They then suggest that differences of opinion about the appropriateness of public policies stem not from disputes about whether market barriers exist, but from different perceptions of the magnitude of the barriers, and the efficacy and (possibly unintended) consequences of policies designed to overcome them. They conclude that there are compelling justifications for future energy-efficiency policies. Nevertheless, in order to succeed, they must be based on a sound understanding of the market problems they seek to correct and a realistic assessment of their likely efficacy. This understanding can only emerge from detailed investigations of the current operation of individual markets.

  7. Financing energy SMEs in Ghana and Senegal: Outcomes, barriers and prospects

    International Nuclear Information System (INIS)

    Haselip, James; Desgain, Denis; Mackenzie, Gordon

    2014-01-01

    The article presents the findings of primary research carried out in Ghana and Senegal, which revisited the main assumptions behind the African Rural Energy Enterprise Development (AREED) initiative (2002–2012), and other donor-backed programmes, designed to promote small and medium-sized energy enterprises (energy SMEs). These assumptions were (1) that the lack of affordable local financing presented the most significant barrier to setting up and expanding energy SMEs, and (2) that these barriers would be overcome by a ‘demonstration effect’ whereby successful businesses, supported by donor-backed programmes, could in turn influence the commercial financial sector to invest in energy SMEs, thus triggering a virtuous circle of growth and profitability. - Highlights: • Analysis of the AREED ‘demonstration effect’ in Senegal and Ghana. • Commercial financial backing for SMEs remains a serious challenge for entrepreneurs. • Structural issues that increase the financial risk of investing in energy SMEs. • High transaction costs of investing in SMEs. • Longer supply chains and slower pay-back periods for capital-intensive technologies

  8. Study of internal rotation in molecules using molecular orbital method in the CNDO/BW approximation

    International Nuclear Information System (INIS)

    Pedrosa, M.S.

    1987-10-01

    It is presented a LCAO-MO-SCF study of Internal Rotation for the molecules C 2 H 6 , CH 3 NH 2 , H 2 O 2 , and N 2 H 4 by ysing the CNDO/BW approximation and an M-center energy partition. Our results are compared with those obtained with the CNDO/2 approximation. It is shown that there are differences in the analysis of the process involved in the internal rotation barriers mechanism. Thus the interpretation of the results is strongly dependent on the parametrization used. (author) [pt

  9. Contra-rotating homopolar motor-generator for energy storage and return

    International Nuclear Information System (INIS)

    Kustom, R.L.; Wehrle, R.B.

    1978-01-01

    An apparatus for receiving electrical energy in amounts of the order of hundreds of megajoules, converting the electrical energy to mechanical energy for storage, and delivering the stored energy as electrical energy in times of the order of a second. It consists of a sequence of stacked electrically conducting cylindrical shells having a common axis. The conducting shells are free to rotate and are separated by stationary insulating cylindrical shells. Adjacent conducting shells are connected electrically by brushes at the edges and a radial magnetic field is caused to pass through the conductors. The apparatus permits the reversal in a plasma heating coil of electric currents of amplitudes up to 100,000 amperes in a time of the order of a second

  10. Nuclear dynamics around the barrier: from fusion to evaporation

    International Nuclear Information System (INIS)

    Simenel, Cedric

    2003-01-01

    This work is devoted to aspects of nuclear dynamics around the barrier. It is shown that for fusion reactions, the Coulomb field couples relative motion of nuclei to rotation of a deformed projectile independently of the energy and the charge of the nuclei. An experimental study of the reaction 6 He + 190 Os via gamma spectroscopy of product nuclei has shown that the break up of the 6 He is coupled to the relative motion too, a strong hindrance resulting in the fusion around and above the fusion barrier. The path to fusion after overcoming the barrier, especially the charge equilibration, have been studied in the framework of the TDHF theory via the preequilibrium GDR excited in N/Z asymmetric reactions. An application to formation of the super-heavy elements has been proposed. Finally, couplings between protons and neutrons have been shown up in mean field calculations. Their main expected effect is an emission of protons under the Coulomb barrier. (author)

  11. Rotating-Sleeve Triboelectric-Electromagnetic Hybrid Nanogenerator for High Efficiency of Harvesting Mechanical Energy.

    Science.gov (United States)

    Cao, Ran; Zhou, Tao; Wang, Bin; Yin, Yingying; Yuan, Zuqing; Li, Congju; Wang, Zhong Lin

    2017-08-22

    Currently, a triboelectric nanogenerator (TENG) and an electromagnetic generator (EMG) have been hybridized to effectively scavenge mechanical energy. However, one critical issue of the hybrid device is the limited output power due to the mismatched output impedance between the two generators. In this work, impedance matching between the TENG and EMG is achieved facilely through commercial transformers, and we put forward a highly integrated hybrid device. The rotating-sleeve triboelectric-electromagnetic hybrid nanogenerator (RSHG) is designed by simulating the structure of a common EMG, which ensures a high efficiency in transferring ambient mechanical energy into electric power. The RSHG presents an excellent performance with a short-circuit current of 1 mA and open-circuit voltage of 48 V at a rotation speed of 250 rpm. Systematic measurements demonstrate that the hybrid nanogenerator can deliver the largest output power of 13 mW at a loading resistance of 8 kΩ. Moreover, it is demonstrated that a wind-driven RSHG can light dozens of light-emitting diodes and power an electric watch. The distinctive structure and high output performance promise the practical application of this rotating-sleeve structured hybrid nanogenerator for large-scale energy conversion.

  12. 8B + 208Pb Elastic Scattering at Coulomb Barrier Energies

    Science.gov (United States)

    La Commara, M.; Mazzocco, M.; Boiano, A.; Boiano, C.; Manea, C.; Parascandolo, C.; Pierroutsakou, D.; Signorini, C.; Strano, E.; Torresi, D.; Yamaguchi, H.; Kahl, D.; Di Meo, P.; Grebosz, J.; Imai, N.; Hirayama, Y.; Ishiyama, H.; Iwasa, N.; Jeong, S. C.; Jia, H. M.; Kim, Y. H.; Kimura, S.; Kubono, S.; Lin, C. J.; Miyatake, H.; Mukai, M.; Nakao, T.; Nicoletto, M.; Sakaguchi, Y.; Sánchez-Benítez, A. M.; Soramel, F.; Teranishi, T.; Wakabayashi, Y.; Watanabe, Y. X.; Yang, L.; Yang, Y. Y.

    2018-02-01

    The scattering process of weakly-bound nuclei at Coulomb barrier energies provides deep insights on the reaction dynamics induced by exotic nuclei. Within this framework, we measured for the first time the scattering process of the short-lived Radioactive Ion Beam (RIB) 8B (Sp = 0.1375 MeV) from a 208Pb target at 50 MeV beam energy. The 8B RIB was produced by means of the in-flight facility CRIB (RIKEN, Japan) with an average intensity on target of 10 kHz and a purity about 25%. Elastically scattering ions were detected in the angular range θc.m. = 10°-160° by means of the detector array EXPADES. A preliminary optical model analysis indicates a total reaction cross section of about 1 b, a value, once reduced, 2-3 times larger than those obtained for the reactions induced by the stable weakly-bound projectiles 6,7Li on a 208Pb target in the energy range around the Coulomb barrier.

  13. Design and Experimental Characterization of a Vibration Energy Harvesting Device for Rotational Systems

    Directory of Open Access Journals (Sweden)

    Lutao Yan

    2013-01-01

    Full Text Available This paper presents a new vibration based electromagnetic power generator to transfer energy from stationary to rotating equipment, which can be a new attempt to substitute slip ring in rotational systems. The natural frequencies and modes are simulated in order to have a maximum and steady power output from the device. Parameters such as piezoelectric disk location and relative motion direction of the magnet are theoretically and experimentally analyzed. The results show that the position that is close to the fixed end of the cantilever and the relative motion along the long side gives higher power output. Moreover, the capability of the energy harvester to extract power from lower energy environment is experimentally validated. The voltage and power output are measured at different excitation frequencies.

  14. On the economic analysis of problems in energy efficiency: Market barriers, market failures, and policy implications

    Energy Technology Data Exchange (ETDEWEB)

    Sanstad, A.H.; Koomey, J.G.; Levine, M.D.

    1993-01-01

    In his recent paper in The Energy Journal, Ronald Sutherland argues that several so-called market barriers'' to energy efficiency frequently cited in the literature are not market failures in the conventional sense and are thus irrelevant for energy policy. We argue that Sutherland has inadequately analyzed the idea of market barrier and misrepresented the policy implications of microeconomics. We find that economic theory, correctly interpreted, does not provide for the categorical dismissal of market barriers. We explore important methodological issues underlying the debate over market barriers, and discuss the importance of reconciling the findings of non-economic social sciences with the economic analysis of energy demand and consumer decision-making. We also scrutinize Sutherland's attempt to apply finance theory to rationalize high implicit discount rates observed in energy-related choices, and find this use of finance theory to be inappropriate.

  15. 11Li Breakup on 208Pb at Energies Around the Coulomb Barrier

    DEFF Research Database (Denmark)

    Fernández-García, J.P.; Cubero, M.; Rodríguez-Gallardo, M.

    2013-01-01

    The inclusive breakup for the 11Li+208Pb reaction at energies around the Coulomb barrier has been measured for the first time. A sizable yield of 9Li following the 11Li dissociation has been observed, even at energies well below the Coulomb barrier. Using the first-order semiclassical perturbation...... theory of Coulomb excitation it is shown that the breakup probability data measured at small angles can be used to extract effective breakup energy as well as the slope of B(E1) distribution close to the threshold. Four-body continuum-discretized coupled-channels calculations, including both nuclear...... and Coulomb couplings between the target and projectile to all orders, reproduce the measured inclusive breakup cross sections and support the presence of a dipole resonance in the 11Li continuum at low excitation energy....

  16. Implementation of renewable energy technologies - Opportunities and barriers. Egypt country study

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    The project used case studies of renewable energy implementation projects to analyse the reasons for success or failure of specific projects or technologies. In particular the study aimed to identify possibilities for 'removing' the main barriers and thus 'promoting' increased implementation of (RETs), and to 'generalise' the experiences from the case studies and produce results that can be disseminated and utilized further in a planned second phase. The specific objectives for Egypt Country Study were: 1) To determine, on the basis of analysis of the past experience, the barriers against implementation of RETs in Egypt, and to identify the favourable conditions and actions required for such implementation. 2) To apply the knowledge gained and results of the analysis of past projects for a detailed analysis of barriers to a chosen set of potential RETs implementation projects with view to success. 3) To identify specific RET projects for implementation including necessary actions to overcome identified barriers. The case study revealed that; for Domestic Solar Water Heating (DSWH) the main barriers are; the economic barriers followed by the awareness / information barriers, then the Technical and Institution barriers. For the PV rural electrification, the most important barriers are; the economic and financial barriers, the awareness and information barriers then the technical barriers. For the large-scale biogas systems, the main barriers are the institution and capacity, economic, policy and awareness / information respectively. According to the project results the main actions that could be taken to overcome the barriers and make use of the available opportunities are: Economic / Financial: 1) Creation of new financial schemes for the RETs applications components and systems. 2) Reducing the taxes and duties for the components and / or materials needed for Renewable Energy (RE) systems. 3) More government-supported market incentives to encourage further

  17. Implementation of renewable energy technologies - Opportunities and barriers. Egypt country study

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    The project used case studies of renewable energy implementation projects to analyse the reasons for success or failure of specific projects or technologies. In particular the study aimed to identify possibilities for 'removing' the main barriers and thus 'promoting' increased implementation of (RETs), and to 'generalise' the experiences from the case studies and produce results that can be disseminated and utilized further in a planned second phase. The specific objectives for Egypt Country Study were: 1) To determine, on the basis of analysis of the past experience, the barriers against implementation of RETs in Egypt, and to identify the favourable conditions and actions required for such implementation. 2) To apply the knowledge gained and results of the analysis of past projects for a detailed analysis of barriers to a chosen set of potential RETs implementation projects with view to success. 3) To identify specific RET projects for implementation including necessary actions to overcome identified barriers. The case study revealed that; for Domestic Solar Water Heating (DSWH) the main barriers are; the economic barriers followed by the awareness / information barriers, then the Technical and Institution barriers. For the PV rural electrification, the most important barriers are; the economic and financial barriers, the awareness and information barriers then the technical barriers. For the large-scale biogas systems, the main barriers are the institution and capacity, economic, policy and awareness / information respectively. According to the project results the main actions that could be taken to overcome the barriers and make use of the available opportunities are: Economic / Financial: 1) Creation of new financial schemes for the RETs applications components and systems. 2) Reducing the taxes and duties for the components and / or materials needed for Renewable Energy (RE) systems. 3) More government-supported market incentives

  18. Overcoming financial barriers to wider use of renewable energy technology in Africa

    International Nuclear Information System (INIS)

    Davidson, O.R.; Turkson, J.

    2001-01-01

    Future energy demand in Africa will rise dramatically due to development desires and increased industrial needs. Coping with this demand will pose a serious challenge because of the economic and environmental constraints of the continent. Exploiting its vast renewable energy sources for this purpose will assist greatly, but financial and other barriers to the rapid growth of associated technologies are significant. This paper explores measures that can be implemented to reduce these financial barriers. The analyses, which are based on lessons from experiences in and out of the region, show that replicating and enhancing current initiatives along with the implementation of suggested policy options could substantially increase the use of renewable energy technologies in Africa. (author)

  19. Carbon storage and recycling in short-rotation energy crops

    International Nuclear Information System (INIS)

    Ranney, J.W.; Wright, L.L.; Mitchell, C.P.

    1991-01-01

    Short-rotation energy crops can play a significant role in storing carbon compared to the agricultural land uses they would displace. However, the benefits from these plantations in avoiding further use of fossil fuel and in taking pressure off of native forests for energy uses provides longer term carbon benetfits than the plantation carbon sequestration itself. The fast growth and harvest frequency of plantations tends to limit the amount of above and below-ground carbon storage in them. The primary components of plantation carbon sequestering compared to sustained agricultural practices involve above-ground wood, possible increased soil carbon, litter layer formation, and increased root biomass. On the average, short-rotation plantations in total may increase carbon inventories by about 30 to 40 tonnes per hectare over about a 20- to 56-year period when displacing cropland. This is about doubling in storage over cropland and about one-half the storage in human-impacted forests. The sequestration benefit of wood energy crops over cropland would be negated in about 75 to 100 years by the use of fossil fuels to tend the plantations and handle biomass. Plantation interactions with other land uses and total landscape carbon inventory is important in assessing the relative role plantations play in terrestrial and atmospheric carbon dynamics. It is speculated that plantations, when viewed in this context. could trencrate a global leveling of net carbon emissions for approximately 10 to 20 years

  20. Review of Renewable Energy Technologies in Zambian Households: Capacities and Barriers Affecting Successful Deployment

    Directory of Open Access Journals (Sweden)

    Priscilla Kachapulula-Mudenda

    2018-05-01

    Full Text Available Modern renewable energy has been hailed as one of the prerequisites for fostering green growth and the achievement of sustainable development. Despite efforts to promote the use of renewable energy in households, its adoption has remained fairly low, hence the need for an inquiry into household capabilities needed for the acquisition and adoption of renewable energy technologies. This paper reviews the requisite capacities of households for the adoption of renewable energy services and expounds on some of the barriers hampering renewable energy among households. It takes a desk research approach to analyse the capacities which should be possessed by Zambian households and possible barriers constraining the widespread deployment of renewable energy technologies. The findings reveal that there is a need for a broader, multidimensional understanding of access to renewable energy in order for deployment to be effective. Barriers to the successful adoption of clean energy technologies include underserved populations, policy inadequacies; an underexploited renewable energy sector and heavy reliance on a service-challenged hydro-power utility. Since most of the aforementioned challenges are institutional in nature, the paper concludes with a recommendation of a baseline assessment to understand knowledge, perceptions, attitudes and drivers for renewable energy technology adoption among households.

  1. Technical Barriers, Gaps,and Opportunities Related to Home Energy Upgrade Market Delivery

    Energy Technology Data Exchange (ETDEWEB)

    Bianchi, Marcus V.A. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2011-11-01

    This report outlines the technical barriers, gaps, and opportunities that arise in executing home energy upgrade market delivery approaches, as identified through research conducted by the U.S. Department of Energy's Building America program.

  2. Imprint reduction in rotating heavy ions beam energy deposition

    Energy Technology Data Exchange (ETDEWEB)

    Bret, A., E-mail: antoineclaude.bret@uclm.es [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS-51, Cambridge, MA 02138 (United States); ETSI Industriales, Universidad Castilla-La Mancha, 13071 Ciudad Real (Spain); Instituto de Investigaciones Energéticas y Aplicaciones Industriales, Campus Universitario de Ciudad Real, 13071 Ciudad Real (Spain); Piriz, A.R., E-mail: Roberto.Piriz@uclm.es [ETSI Industriales, Universidad Castilla-La Mancha, 13071 Ciudad Real (Spain); Instituto de Investigaciones Energéticas y Aplicaciones Industriales, Campus Universitario de Ciudad Real, 13071 Ciudad Real (Spain); Tahir, N.A., E-mail: n.tahir@gsi.de [GSI Darmstadt, Plankstrasse 1, 64291 Darmstadt (Germany)

    2014-01-01

    The compression of a cylindrical target by a rotating heavy ions beam is contemplated in certain inertial fusion schemes or in heavy density matter experiments. Because the beam has its proper temporal profile, the energy deposition is asymmetric and leaves an imprint which can have important consequences for the rest of the process. In this paper, the Fourier components of the deposited ion density are computed exactly in terms of the beam temporal profile and its rotation frequency Ω. We show that for any beam profile of duration T, there exist an infinite number of values of ΩT canceling exactly any given harmonic. For the particular case of a parabolic profile, we find possible to cancel exactly the first harmonic and nearly cancel every other odd harmonics. In such case, the imprint amplitude is divided by 4 without any increase of Ω.

  3. Imprint reduction in rotating heavy ions beam energy deposition

    International Nuclear Information System (INIS)

    Bret, A.; Piriz, A.R.; Tahir, N.A.

    2014-01-01

    The compression of a cylindrical target by a rotating heavy ions beam is contemplated in certain inertial fusion schemes or in heavy density matter experiments. Because the beam has its proper temporal profile, the energy deposition is asymmetric and leaves an imprint which can have important consequences for the rest of the process. In this paper, the Fourier components of the deposited ion density are computed exactly in terms of the beam temporal profile and its rotation frequency Ω. We show that for any beam profile of duration T, there exist an infinite number of values of ΩT canceling exactly any given harmonic. For the particular case of a parabolic profile, we find possible to cancel exactly the first harmonic and nearly cancel every other odd harmonics. In such case, the imprint amplitude is divided by 4 without any increase of Ω

  4. Summary of Gaps and Barriers for Implementing Residential Building Energy Efficiency Strategies

    Energy Technology Data Exchange (ETDEWEB)

    2010-08-01

    This report presents the key gaps and barriers to implementing residential energy efficiency strategies in the U.S. market, as identified in sessions at the U.S. Department of Energy's Building America 2010 Residential Energy Efficiency Meeting held in Denver, Colorado, on July 20-22, 2010.

  5. Internationalization as a strategy to overcome industry barriers-An assessment of the marine energy industry

    International Nuclear Information System (INIS)

    Lovdal, Nicolai; Neumann, Frank

    2011-01-01

    Research on conditions to develop new innovations within emerging renewable energy industries is often done with a national focus. However, recent research on international entrepreneurship has revealed that firms operate on international levels very early in their life time. Thus, based on former research on international entrepreneurship and case examples, we build the propositions that firms in the marine energy industry use internationalization as a strategy to overcome industry barriers. Our primary source of data is a unique dataset from a global survey of all the companies in the marine energy industry who are aiming to commercialize a wave or tidal energy device. This paper is organized in two steps: first we identified the most challenging industry barriers perceived by companies. Second we use these to form propositions which we assess through empirical data. The two most challenging barriers perceived by the companies are need for capital and need for supportive political schemes. Our findings reveal that internationalization certainly is a common strategy to access capital and attractive support schemes in foreign countries. The early internationalization has implications for researchers, managers and policy makers. - Research highlights: → Industry barriers identified as access to capital and supportive political schemes. → International entrepreneurship is used to overcome industry barriers. → Start-ups in emerging energy industries 'shop' national support schemes. → Future research to provide policy advice should adapt to the international reality. → Research based on a worldwide survey of wave and tidal energy device developers.

  6. Internationalization as a strategy to overcome industry barriers-An assessment of the marine energy industry

    Energy Technology Data Exchange (ETDEWEB)

    Lovdal, Nicolai, E-mail: nicolai.lovdal@iot.ntnu.n [Industrial Economics and Technology Management, Norwegian University of Science and Technology, 7491 Trondheim (Norway); Neumann, Frank, E-mail: frank@wave-energy-centre.or [Wave Energy Centre, Av. Manuel Maia, 36, r/c Dto., 1000-201 Lisboa (Portugal)

    2011-03-15

    Research on conditions to develop new innovations within emerging renewable energy industries is often done with a national focus. However, recent research on international entrepreneurship has revealed that firms operate on international levels very early in their life time. Thus, based on former research on international entrepreneurship and case examples, we build the propositions that firms in the marine energy industry use internationalization as a strategy to overcome industry barriers. Our primary source of data is a unique dataset from a global survey of all the companies in the marine energy industry who are aiming to commercialize a wave or tidal energy device. This paper is organized in two steps: first we identified the most challenging industry barriers perceived by companies. Second we use these to form propositions which we assess through empirical data. The two most challenging barriers perceived by the companies are need for capital and need for supportive political schemes. Our findings reveal that internationalization certainly is a common strategy to access capital and attractive support schemes in foreign countries. The early internationalization has implications for researchers, managers and policy makers. - Research highlights: {yields} Industry barriers identified as access to capital and supportive political schemes. {yields} International entrepreneurship is used to overcome industry barriers. {yields} Start-ups in emerging energy industries 'shop' national support schemes. {yields} Future research to provide policy advice should adapt to the international reality. {yields} Research based on a worldwide survey of wave and tidal energy device developers.

  7. Hindered Csbnd N bond rotation in triazinyl dithiocarbamates

    Science.gov (United States)

    Jung, Taesub; Do, Hee-Jin; Son, Jongwoo; Song, Jae Hee; Cha, Wansik; Kim, Yeong-Joon; Lee, Kyung-Koo; Kwak, Kyungwon

    2018-01-01

    The substituent and solvent effects on the rotation around a Csbnd N amide bond were studied for a series of triazine dibenzylcarbamodithioates. The Gibbs free energies (ΔG‡) were measured to be 16-18 kcal/mol in DMSO-d6 and toluene-d8 using variable-temperature nuclear magnetic resonance (VT-1H NMR) spectroscopy. Density functional theory (DFT) calculations reproduced the experimental observations with various substituents, as well as solvents. From the detailed analysis of the DFT results, we found that the electron donating dibenzyl amine group increased the electron population on the triazinyl ring, which decreased the rotational barrier of the Csbnd N bond in the dithiocarbamate group attached to the triazinyl ring. The higher electron population on the triazine moiety stabilizes the partial double bond character of the Ssbnd C bond, which competitively excludes the double bond character of the Csbnd N bond. Therefore, the rotational dynamics of the Csbnd N bond in dithiocarbamates can be a sensitive probe to small differences in the electron population of substituents on sulfur.

  8. Control of Rotational Energy and Angular Momentum Orientation with an Optical Centrifuge

    Science.gov (United States)

    Ogden, Hannah M.; Murray, Matthew J.; Mullin, Amy S.

    2017-04-01

    We use an optical centrifuge to trap and spin molecules to an angular frequency of 30 THz with oriented angular momenta and extremely high rotational energy and then investigate their subsequent collision dynamics with transient high resolution IR spectroscopy. The optical centrifuge is formed by combining oppositely-chirped pulses of 800 nm light, and overlapping them spatially and temporally. Polarization-sensitive Doppler-broadened line profiles characterize the anisotropic kinetic energy release of the super rotor molecules, showing that they behave like molecular gyroscopes. Studies are reported for collisions of CO2 super rotors with CO2, He and Ar. These studies reveal how mass, velocity and rotational adiabaticity impact the angular momentum relaxation and reorientation. Quantum scattering calculations provide insight into the J-specific collision cross sections that control the relaxation. NSF-CHE 105 8721.

  9. Simple analytical approximation for rotationally inelastic rate constants based on the energy corrected sudden scaling law

    International Nuclear Information System (INIS)

    Smith, N.; Pritchard, D.E.

    1981-01-01

    We have recently demonstrated that the energy corrected sudden (ECS) scaling law of De Pristo et al. when conbined with the power law assumption for the basis rates k/sub l/→0proportional[l(l+1)]/sup -g/ can accurately fit a wide body of rotational energy transfer data. We develop a simple and accurate approximation to this fitting law, and in addition mathematically show the connection between it and our earlier proposed energy based law which also has been successful in describing both theoretical and experimental data on rotationally inelastic collisions

  10. Near-Barrier Fusion of Heavy Nuclei. Coupling of the Channels

    CERN Document Server

    Zagrebaev, V I

    2003-01-01

    The problem of quantum description of near-barrier fusion of heavy nuclei taking place under strong coupling of relative motion with rotation of deformed nuclei and with dynamic deformations of their surfaces is studied in the paper. A new effective method is proposed for numerical solution of a set of coupled Schrodinger equations with boundary conditions corresponding to a full absorption of the flux penetrated through the multi-dimensional Coulomb barrier. The method has no limitation on the number of coupled channels and allows one to calculate fusion cross-sections of very heavy nuclei used for synthesis of super-heavy elements. A combined analysis of the multi-dimensional potential energy surface relief and the multi-channel wave function in the vicinity of the Coulomb barrier gives a clear interpretation of near-barrier fusion dynamics. Comparison with experimental data and with semi-empirical model calculations is performed. The computing codes are allocated at the web-server http://nrv.jinr.ru/nrv/ w...

  11. Spectroscopic and electrooptical manifestations of internal rotation of the outer-sphere cation in Li(PO3) molecule

    International Nuclear Information System (INIS)

    Romanets, A.V.; Sukhanov, L.P.

    1997-01-01

    Spectroscopic and electrooptical manifestations of internal molecular rotations in LiPO 3 have been studied on the basis of ab initio calculated surface of potential energy and dipole momentum function using the finite element method. It has been ascertained that tunnel splitting of energy levels with number n, available for vibrational spectroscopy of high resolution, apper in the molecule studied only at n≥13. It is shown that internal rotations in the molecule are able to decrease sharply its polarity on vibration-excited levels, sufficiently far from the vertex of potential barrier of intramolecular regroupings. Difficulties of experimental confirmation of predicted electrooptical effect of structural non-rigidity in the molecule studied are discussed

  12. Removing barriers to women entrepreneurs’ engagement in decentralized sustainable energy solutions for the poor

    Directory of Open Access Journals (Sweden)

    Yannick Glemarec

    2016-01-01

    Full Text Available  Rapidly falling renewable technology costs and new business models mean that decentralized energy solutions hold great promise to accelerate universal sustainable energy access. Across developing countries, women are typically the primary household energy managers. Close to their customers, women entrepreneurs have the potential to lower customer acquisition and servicing costs and drive these new decentralized solutions. However, they remain under-represented in the industry. This paper attempts to understand the root causes of this gender gap. It formulates the research hypothesis that market transformation policies intended to reduce investment risks to accelerate energy access may not benefit men and women entrepreneurs equally because of the existing structural barriers that women face. To test this hypothesis, the paper conducts a gender sensitive investment barrier and risk analysis, overlaid onto an existing gender neutral taxonomy of investment barriers and risks for decentralized sustainable energy solutions. A key finding is that for women entrepreneurs, existing structural impediments to gender equality translate into additional investment barriers as well as increased likelihood of occurrence and severity of the financial impact of generic investment risks. The paper offers an illustrative theory of change to facilitate a dialogue on the specific interventions needed to address these gender differentiated risks locally. It concludes that market transformation efforts for universal sustainable energy access must include targeted policy measures to ensure equal benefits to men and women entrepreneurs, and optimize the use of public resources to catalyze private investment and reduce poverty.

  13. Fission barriers of light nuclei

    International Nuclear Information System (INIS)

    Grotowski, K.; Planeta, R.; Blann, M.; Komoto, T.

    1989-01-01

    Experimental fission excitation functions for compound nuclei /sup 52/Fe, /sup 49/Cr, /sup 46/V, and /sup 44/Ti formed in heavy-ion reactions are analyzed in the Hauser-Feshbach/Bohr-Wheeler formalism using fission barriers based on the rotating liquid drop model of Cohen et al. and on the rotating finite range model of Sierk. We conclude that the rotating finite range approach gives better reproduction of experimental fission yields, consistent with results found for heavier systems

  14. Numerical evaluation of energy barriers and magnetic relaxation in interacting nanostructured magnetic systems

    International Nuclear Information System (INIS)

    Chubykalo-Fesenko, Oksana A.; Chantrell, Roy W.

    2004-01-01

    We discuss a model to quantify long-time thermally induced magnetization reversal in magnetic systems with distributed properties. Two algorithms, based on kinetic and Metropolis Monte Carlo are introduced. While the former requires the constant recalculation of all energy barriers and is useful when the interactions are weak, the latter uses the Metropolis Monte Carlo to estimate the magnetization trajectory and, consequently, only the most probable transition rates are evaluated. The ridge optimization method is used to evaluate the energy barriers in a multidimensional energy landscape. The algorithms are applied to a granular system modeled by means of Voronoi polyhedra and having random in-plane anisotropy

  15. Potential and barrier study. Energy efficiency of Norwegian homes; Potensial- og barrierestudie. Energieffektivisering av norske boliger

    Energy Technology Data Exchange (ETDEWEB)

    Mjoenes, Christian; Pettersen, Folke Vogn Haug; Kristoffersen, Bjoerge Sandberg; Birkeland, Bjoern Mangor; Essen, Jan von; Haarberg; Karl Johan

    2012-01-15

    On behalf of Enova SF, Prognosesenteret AS and Entelligens AS carried out a potential and barrier study of energy efficiency of the Norwegian housing stock. The study made use of newer and known studies of the Norwegian housing stock, known and documented barriers to energy efficiency, and new and extensive studies of several topics which have only been partially or never explored before. Through unique analysis and a case-based approach, it revealed a real energy efficiency potential in Norwegian homes with known technology and revealed representativeness, relevance, strength and extent of the barriers that prevent that one can realize most of the technical energy efficiency potential in the Norwegian housing stock. (eb)

  16. Driving forces and barriers to improved energy performance of buildings: an analysis of energy performance of Swedish buildings, 2000-2006

    Energy Technology Data Exchange (ETDEWEB)

    Fuglseth, Bente Beckstroem

    2008-06-15

    The building sector is responsible for a substantial part of energy use and green house gas emissions in Europe. This report explores driving forces and barriers to improved energy performance of buildings, using the Swedish building sector as a case. The development of energy performance of buildings in Sweden from 2000 until 2006 is explored by applying a threefold understanding of energy performance of buildings: substitution from fossil fuels to renewable energy, conversion from electrical heating to thermal energy and reduction in energy demand. Three explanatory approaches are used to analyse driving forces and barriers to improved energy performance: the techno-economic approach stresses the physical aspects of infrastructure and technologies, the institutional approach emphasizes the role of institutional factors, while the regulative approach focuses on formal rules and laws. The study concludes that all factors have promoted substitution of fossil fuels with renewable energy, while they have prevented conversion from electrical heating to thermal energy and reduction in energy demand. (author). 95 refs

  17. Modeling and Characteristic Analysis of Wireless Ultrasonic Vibration Energy Transmission Channels through Planar and Curved Metal Barriers

    Directory of Open Access Journals (Sweden)

    DingXin Yang

    2018-01-01

    Full Text Available Wireless ultrasonic vibration energy transmission systems through metal barriers based on piezoelectric transducers have drawn a lot of focus due to the advantage of nonpenetration of the barriers, thus maintaining the integrity of sealed structures. It is meaningful to investigate appropriate modeling methods and to characterize such wireless ultrasonic energy transmission channels with different geometric shapes. In this paper, equivalent circuit modeling and finite element modeling methods are applied to the planar metal barrier channel, and a 3-dimensional finite element modeling method is applied to the cylindrical metallic barrier channel. Meanwhile, the experimental setup is established and measurements are carried out to validate the effectiveness of the corresponding modeling methods. The results show that Leach’s equivalent circuit modeling method and finite element modeling method are nearly similarly effective in characterizing the planar metal barrier channel. But for a cylindrical metal barrier, only the three-dimensional finite element modeling method is effective. Furthermore, we found that, for the planar barrier, the effect of standing waves on the efficiency of wireless energy transmission is dominated. But for the curved barrier, only the resonant phenomenon of the piezoelectric transducer exists.

  18. Renewable energy in South Africa: Potentials, barriers and options for support

    International Nuclear Information System (INIS)

    Pegels, Anna

    2010-01-01

    The challenge of transforming entire economies is enormous; even more so if a country is as fossil fuel based and emission intensive as South Africa. However, in an increasingly carbon constrained world and already now facing climate change impacts South Africa has to reduce greenhouse gas emissions intensity soon and decidedly. The South African electricity sector is a vital part of the economy and at the same time contributes most to the emissions problem. First steps have been taken by the South African government to enhance energy efficiency and promote renewable energy, however, they fail to show large-scale effects. This paper seeks to identify the relevant barriers to renewable energy investments and, based on experience from other countries, provide policy recommendations. The major barrier identified in the paper is based on the economics of renewable energy technologies, i.e. their cost and risk structures, two main factors in investment planning. As a solution, the South African government introduced several renewable energy support measures, such as a feed-in tariff. The paper discusses the potential and possible shortcomings of this and other existing support schemes and identifies complementing measures on a national scale.

  19. Modeling barriers of solid waste to energy practices: An Indian perspective

    International Nuclear Information System (INIS)

    Bag, S.; Mondal, N.; Dubey, R.

    2016-01-01

    In recent years managing solid wastes has been one of the burning problems in front of state and local municipal authorities. This is mainly due to scarcity of lands for landfill sites. In this context experts suggest that conversion of solid waste to energy and useful component is the best approach to reduce space and public health related problems. The entire process has to be managed by technologies that prevent pollution and protect the environment and at the same time minimize the cost through recovery of energy. Energy recovery in the form of electricity, heat and fuel from the waste using different technologies is possible through a variety of processes, including incineration, gasification, pyrolysis and anaerobic digestion. These processes are often grouped under “Waste to Energy technologies”. The objective of the study is twofold. First authors assessed the current status of solid waste management practices in India. Secondly the leading barriers are identified and Interpretive structural modeling technique and MICMAC analysis is performed to identify the contextual interrelationships between leading barriers influencing the solid waste to energy programs in the country. Finally the conclusions are drawn which will assist policy makers in designing sustainable waste management programs.

  20. Renewable energy in South Africa. Potentials, barriers and options for support

    Energy Technology Data Exchange (ETDEWEB)

    Pegels, Anna [German Development Institute/Deutsches Institut fuer Entwicklungspolitik, Tulpenfeld 6, 53113 Bonn (Germany)

    2010-09-15

    The challenge of transforming entire economies is enormous; even more so if a country is as fossil fuel based and emission intensive as South Africa. However, in an increasingly carbon constrained world and already now facing climate change impacts South Africa has to reduce greenhouse gas emissions intensity soon and decidedly. The South African electricity sector is a vital part of the economy and at the same time contributes most to the emissions problem. First steps have been taken by the South African government to enhance energy efficiency and promote renewable energy, however, they fail to show large-scale effects. This paper seeks to identify the relevant barriers to renewable energy investments and, based on experience from other countries, provide policy recommendations. The major barrier identified in the paper is based on the economics of renewable energy technologies, i.e. their cost and risk structures, two main factors in investment planning. As a solution, the South African government introduced several renewable energy support measures, such as a feed-in tariff. The paper discusses the potential and possible shortcomings of this and other existing support schemes and identifies complementing measures on a national scale. (author)

  1. Renewable energy in South Africa: Potentials, barriers and options for support

    Energy Technology Data Exchange (ETDEWEB)

    Pegels, Anna, E-mail: anna.pegels@die-gdi.d [German Development Institute/Deutsches Institut fuer Entwicklungspolitik, Tulpenfeld 6, 53113 Bonn (Germany)

    2010-09-15

    The challenge of transforming entire economies is enormous; even more so if a country is as fossil fuel based and emission intensive as South Africa. However, in an increasingly carbon constrained world and already now facing climate change impacts South Africa has to reduce greenhouse gas emissions intensity soon and decidedly. The South African electricity sector is a vital part of the economy and at the same time contributes most to the emissions problem. First steps have been taken by the South African government to enhance energy efficiency and promote renewable energy, however, they fail to show large-scale effects. This paper seeks to identify the relevant barriers to renewable energy investments and, based on experience from other countries, provide policy recommendations. The major barrier identified in the paper is based on the economics of renewable energy technologies, i.e. their cost and risk structures, two main factors in investment planning. As a solution, the South African government introduced several renewable energy support measures, such as a feed-in tariff. The paper discusses the potential and possible shortcomings of this and other existing support schemes and identifies complementing measures on a national scale.

  2. Barriers and Potential Solutions for Energy Renovation of Buildings in Denmark

    DEFF Research Database (Denmark)

    Meyer, Niels I; Mathiesen, Brian vad; Hvelplund, Frede

    2014-01-01

    the supply and demand side for heat, electricity and transport. Implementing such Smart Energy Systems requires integrated strategic energy planning on the national and local level. With the fundamental changes in the energy supply technologies expected during the coming years, it is important to synchronize...... investments in energy conservation measures with investments in the supply side, in order to avoid overinvestment in supply systems and thus to minimize the total costs of the transformation to Smart Energy Systems. This paper highlights some of the most important barriers for renovation of existing buildings...

  3. Geometrical changes during the internal rotation in ethane

    NARCIS (Netherlands)

    Monkhorst, H. J.

    Theoretical and experimental indications are presented that the predominant geometrical change during the internal rotation in ethane is a stretching of the CC bond by about 1%. going from the staggered to the eclipsed conformation. This suggests that the rotation barrier is primarily caused by the

  4. Origin of methyl torsional potential barrier – An overview

    Indian Academy of Sciences (India)

    Unknown

    The effect of skeletal flexing on the picture of barrier .... views to explain the origin of the barrier to this rotation have been proposed, but none of .... molecule, a model is always advantageous to predict the barrier and its cause in a given.

  5. Pair transfer processes probed at deep sub barrier energies

    International Nuclear Information System (INIS)

    Corradi, L.; Mason, P.; Fioretto, E.; Michelagnoli, C.; Stefanini, A.M.; Valiente-Dobon, J.J.; Szinler, S.; Jelavic-Malenica, D.; Soic, N.; Pollarolo, G.; Farnea, E.; Montagnoli, G.; Montanari, D.; Scarlassara, F.; Ur, C.A.; Gadea, A.; Haas, F.; Marginean, N.

    2011-01-01

    Multinucleon transfer cross sections in the system 40 Ca+ 96 Zr have been measured at bombarding energies ranging from the Coulomb barrier to ∼ 25% below. Target-like (lighter) recoils in inverse kinematics have been completely identified in A,Z and Q-value with the large solid angle magnetic spectrometer PRISMA. The experimental slopes of the neutron transfer probabilities at large internuclear separation are consistent with the values derived from the binding energies. A phenomenological interpretation of the transfer probabilities indicates the presence of enhanced values for the even number of neutron transfers. (authors)

  6. Response of wave-dominated and mixed-energy barriers to storms

    NARCIS (Netherlands)

    Masselink, G.; Heteren, S. van

    2014-01-01

    Wave-dominated and mixed-energy barriers are extremely dynamic landforms, responding to processes operating over a spectrum of time scales, ranging from daily-to-monthly fluctuations related to storm and post-storm conditions, to century-to-millennium-scale evolution driven by relative sea-level

  7. Design and experimental investigation of a magnetically coupled vibration energy harvester using two inverted piezoelectric cantilever beams for rotational motion

    International Nuclear Information System (INIS)

    Zou, Hong-Xiang; Zhang, Wen-ming; Li, Wen-Bo; Wei, Ke-Xiang; Gao, Qiu-Hua; Peng, Zhi-Ke; Meng, Guang

    2017-01-01

    Highlights: • A magnetically coupled two-degree-of-freedom harvester for rotation is proposed. • The electromechanical coupling model is developed and validated experimentally. • The harvester can generate high voltage at low rotating speeds. • The harvester can harvest vibration energy in multiple frequency bands. - Abstract: Energy can be harvested from rotational motion for powering wireless autonomous electronic devices. The paper presents a magnetically coupled two-degree-of-freedom vibration energy harvester for rotary motion applications. The design consists of two inverted piezoelectric cantilever beams whose free ends point to the rotating shaft. The centrifugal force of the inverted cantilever beam is beneficial to producing large amplitude in a low speed range. The electromechanical coupling dynamical model is developed by the energy method from Hamilton’s principle and validated experimentally. The experimental results indicate that the presented harvester is suitable for low speed rotation and can harvest vibration energy in multiple frequency bands. The first and second resonant behaviors of voltage can be obtained at 420 r/min and 550 r/min, and the average output powers are 564 μW and 535.3 μW, respectively.

  8. Quantum complex rotation and uniform semiclassical calculations of complex energy eigenvalues

    International Nuclear Information System (INIS)

    Connor, J.N.L.; Smith, A.D.

    1983-01-01

    Quantum and semiclassical calculations of complex energy eigenvalues have been carried out for an exponential potential of the form V 0 r 2 exp(-r) and Lennard-Jones (12,6) potential. A straightforward method, based on the complex coordinate rotation technique, is described for the quantum calculation of complex eigenenergies. For singular potentials, the method involves an inward and outward integration of the radial Schroedinger equation, followed by matching of the logarithmic derivatives of the wave functions at an intermediate point. For regular potentials, the method is simpler, as only an inward integration is required. Attention is drawn to the World War II researches of Hartree and co-workers who anticipated later quantum mechanical work on the complex rotation method. Complex eigenenergies are also calculated from a uniform semiclassical three turning point quantization formula, which allows for the proximity of the outer pair of complex turning points. Limiting cases of this formula, which are valid for very narrow or very broad widths, are also used in the calculations. We obtain good agreement between the semiclassical and quantum results. For the Lennard-Jones (12,6) potential, we compare resonance energies and widths from the complex energy definition of a resonance with those obtained from the time delay definition

  9. Socio-cultural barriers to the development of a sustainable energy system - the case of hydrogen

    DEFF Research Database (Denmark)

    Petersen, Lars Kjerulf; Andersen, Anne Holst

    Any transition to a more sustainable energy system, radically reducing greenhouse gas emissions, is bound to run in to a host of different barriers - technological and economic, but also socio-cultural. This will also be the case for any large-scale application of hydrogen as energy carrier......, especially if the system is going to be based on renewable energy sources. The aim of these research notes is to review and discuss major socio-cultural barriers to new forms of energy supply in general and to hydrogen specifically. Reaching sufficient reductions in greenhouse gas emissions may require more...

  10. Anisotropic Lithium Insertion Behavior in Silicon Nanowires: Binding Energy, Diffusion Barrier, and Strain Effect

    KAUST Repository

    Zhang, Qianfan; Cui, Yi; Wang, Enge

    2011-01-01

    Silicon nanowires (SiNWs) have recently been shown to be promising as high capacity lithium battery anodes. SiNWs can be grown with their long axis along several different crystallographic directions. Due to distinct atomic configuration and electronic structure of SiNWs with different axial orientations, their lithium insertion behavior could be different. This paper focuses on the characteristics of single Li defects, including binding energy, diffusion barriers, and dependence on uniaxial strain in [110], [100], [111], and [112] SiNWs. Our systematic ab initio study suggests that the Si-Li interaction is weaker when the Si-Li bond direction is aligned close to the SiNW long axis. This results in the [110] and [111] SiNWs having the highest and lowest Li binding energy, respectively, and it makes the diffusion barrier along the SiNW axis lower than other pathways. Under external strain, it was found that [110] and [001] SiNWs are the most and least sensitive, respectively. For diffusion along the axial direction, the barrier increases (decreases) under tension (compression). This feature results in a considerable difference in the magnitude of the energy barrier along different diffusion pathways. © 2011 American Chemical Society.

  11. Anisotropic Lithium Insertion Behavior in Silicon Nanowires: Binding Energy, Diffusion Barrier, and Strain Effect

    KAUST Repository

    Zhang, Qianfan

    2011-05-19

    Silicon nanowires (SiNWs) have recently been shown to be promising as high capacity lithium battery anodes. SiNWs can be grown with their long axis along several different crystallographic directions. Due to distinct atomic configuration and electronic structure of SiNWs with different axial orientations, their lithium insertion behavior could be different. This paper focuses on the characteristics of single Li defects, including binding energy, diffusion barriers, and dependence on uniaxial strain in [110], [100], [111], and [112] SiNWs. Our systematic ab initio study suggests that the Si-Li interaction is weaker when the Si-Li bond direction is aligned close to the SiNW long axis. This results in the [110] and [111] SiNWs having the highest and lowest Li binding energy, respectively, and it makes the diffusion barrier along the SiNW axis lower than other pathways. Under external strain, it was found that [110] and [001] SiNWs are the most and least sensitive, respectively. For diffusion along the axial direction, the barrier increases (decreases) under tension (compression). This feature results in a considerable difference in the magnitude of the energy barrier along different diffusion pathways. © 2011 American Chemical Society.

  12. Organizational human factors as barriers to energy efficiency in electrical motors systems in industry

    International Nuclear Information System (INIS)

    Sola, Antonio Vanderley Herrero; Augusto de Paula, Xavier Antonio

    2007-01-01

    This paper presents a study accomplished in the State of Parana in Southern Brazil, aiming at verifying the correlation between organizational human factors (OHF) and the level of energy losses in organizations. The purpose is to subsidize the formularization of institutional policies in organizations to improve the energy efficiency in the productive sector. The research was carried out in ten industries of the following sectors: pulp and paper; food; wood and chemical products. The losses of electric energy were determined in motor systems with the aid of a mathematical model and the evaluation of 27 OHF identified in the literature review was made with the supervisors in the industries by means of a structurized questionnaire. Seven OHF had presented significant correlation with energy losses and six of them are inversely proportional to the losses, in accordance with linear regression analysis. The inversely proportional factors to the losses also with significant correlation are considered determinative OHF and constitute barriers for energy efficiency in organizations. These barriers are linked with the following organizational areas: management system; education of employees; strategical vision. The study recommends the implementation of the determinative OHF in organizations as a way to transpose the human barriers for energy efficiency

  13. The congruence energy: a contribution to nuclear masses, deformation energies and fission barriers

    International Nuclear Information System (INIS)

    Myers, W.D.; Swiatecki, W.J.

    1997-01-01

    The difference between measured binding energies and those calculated using a shell- and pairing-corrected Thomas-Fermi model can be described approximately by C(I)=-10 exp(-4.2 vertical stroke I vertical stroke) MeV, where I=(N-Z)/A. Our interpretation of this extra binding is in terms of the granularity of quantal nucleonic density distributions, which leads to a stronger interaction for a neutron and proton with congruent nodal structures of their wave functions. The predicted doubling of this congruence energy in fission is supported by an analysis of measured fission barriers and by a study of wave functions in a dividing Hill-Wheeler box potential. A semi-empirical formula for the shape-dependent congruence energy is described. (orig.)

  14. Organizational, interface, and financial barriers to the commercial development of community energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Schladale, R.; Ritschard, R.

    1979-12-01

    The scope of this analysis was limited to systems producing electricity - the output of a community energy system typically falling in the range 10 kW to 150 MW. The purpose of this study was to identify the barriers that groups and individuals will face when attempting to commercialize community energy systems. Three particular classes of barriers were investigated: those within the organization attempting the commercialization, those that arise from attempts to link the community system with an electric utility, and those that impede the flow of investment capital into community energy systems. In summary, three general observations regarding community energy systems may be distilled from this study. First, although many barriers exist to the commercialization of the systems, few if any appear unresolvable. Perhaps most challenginng will be the problem of expanding the use of cogeneration and municipal sold waste while at the same time maintaining or improving ambient air quality. Second, the financial subsidies required to make community systems competitive are not extraordinary. Indeed, with the exception of photovoltaics they should not amount to more than about 10% of capital cost of the new systems, and mass production may eliminate the need for subsidies altogether at some point in the future. Third, the administrative and regulatory procedures required to make community energy systems viable appear to be taking shape in a positive and timely fashion.

  15. Negotiating EU CO2/energy taxation. Political economic driving forces and barriers

    International Nuclear Information System (INIS)

    Klok, Jacob

    2001-11-01

    The primary objective of this project is to identify the main political economic driving forces behind and barriers against the creation of an EU agreement on CO 2 /energy taxation. The analysis is based on a theoretical framework for understanding European integration and on detailed historical investigations into a process of EU negotiations concerning CO 2 /energy taxation that took place from the 1980s to 1994. Following the historical analysis of political economic driving forces and barriers, some overall perspectives on possible future developments within the field of EU CO 2 /energy taxation are finally advanced. The secondary objective of the project is to consider the possible effects on the EU negotiation process of Danish efforts to push the CO 2 /energy tax proposal from the late 1980s to 994. This analysis is based on the preceding historical analysis of the EU negotiation process, as well as further investigations into the national Danish development within the field of CO 2 /energy taxation, including accounts of Denmark's particular relations with the EU during the period in question. Finally, based on the likely future developments in the field EU CO 2 /energy taxation. Denmark's strategic opportunities are outlined. (BA)

  16. Determination of the activation energy of rotational microviscosity in the DPPC multilayer dispersions and the effects of high electrolyte concentration on rotational microviscosity

    Energy Technology Data Exchange (ETDEWEB)

    Aydas, C. [Ankara Nuclear Research and Training Center, Ankara (Turkmenistan); Korkmaz, M. [Hacettepe University, Beytepe, Ankara (Turkmenistan)

    2004-10-15

    In the present work, electron spin resonance (ESR) spectroscopy was used to study, through the rotational microviscosity approach, the effects of high electrolyte concentrations on the phase behaviors of DPPC (dipalmitoylphosphatidylcholine) multilayer aqueous dispersions of lipid concentrations of 25 mg/ml and 50 mg/ml containing a 5-SASL spin label. The correlation time involved in the definition of rotational microviscosity was calculated using two different equations given in the literature. The activation energies of the rotational viscosity in the gel and the liquid crystal phases and the main transition temperatures were calculated from constructed Andrade plots. The results obtained are discussed in light of the literature data, and the validity of the approach was emphasized.

  17. Energy barriers between metastable states in first-order quantum phase transitions

    Science.gov (United States)

    Wald, Sascha; Timpanaro, André M.; Cormick, Cecilia; Landi, Gabriel T.

    2018-02-01

    A system of neutral atoms trapped in an optical lattice and dispersively coupled to the field of an optical cavity can realize a variation of the Bose-Hubbard model with infinite-range interactions. This model exhibits a first-order quantum phase transition between a Mott insulator and a charge density wave, with spontaneous symmetry breaking between even and odd sites, as was recently observed experimentally [Landig et al., Nature (London) 532, 476 (2016), 10.1038/nature17409]. In the present paper, we approach the analysis of this transition using a variational model which allows us to establish the notion of an energy barrier separating the two phases. Using a discrete WKB method, we then show that the local tunneling of atoms between adjacent sites lowers this energy barrier and hence facilitates the transition. Within our simplified description, we are thus able to augment the phase diagram of the model with information concerning the height of the barrier separating the metastable minima from the global minimum in each phase, which is an essential aspect for the understanding of the reconfiguration dynamics induced by a quench across a quantum critical point.

  18. Current-induced changes of migration energy barriers in graphene and carbon nanotubes

    Science.gov (United States)

    Obodo, J. T.; Rungger, I.; Sanvito, S.; Schwingenschlögl, U.

    2016-05-01

    An electron current can move atoms in a nanoscale device with important consequences for the device operation and breakdown. We perform first principles calculations aimed at evaluating the possibility of changing the energy barriers for atom migration in carbon-based systems. In particular, we consider the migration of adatoms and defects in graphene and carbon nanotubes. Although the current-induced forces are large for both the systems, in graphene the force component along the migration path is small and therefore the barrier height is little affected by the current flow. In contrast, the same barrier is significantly reduced in carbon nanotubes as the current increases. Our work also provides a real-system numerical demonstration that current-induced forces within density functional theory are non-conservative.An electron current can move atoms in a nanoscale device with important consequences for the device operation and breakdown. We perform first principles calculations aimed at evaluating the possibility of changing the energy barriers for atom migration in carbon-based systems. In particular, we consider the migration of adatoms and defects in graphene and carbon nanotubes. Although the current-induced forces are large for both the systems, in graphene the force component along the migration path is small and therefore the barrier height is little affected by the current flow. In contrast, the same barrier is significantly reduced in carbon nanotubes as the current increases. Our work also provides a real-system numerical demonstration that current-induced forces within density functional theory are non-conservative. Electronic supplementary information (ESI) available. See DOI: 10.1039/C6NR00534A

  19. Barriers to Energy Efficiency and the Uptake of Green Revolving Funds in Canadian Universities

    Science.gov (United States)

    Maiorano, John; Savan, Beth

    2015-01-01

    Purpose: The purpose of this paper is to investigate the barriers to the implementation of energy efficiency projects in Canadian universities, including access to capital, bounded rationality, hidden costs, imperfect information, risk and split incentives. Methods to address these barriers are investigated, including evaluating the efficacy of…

  20. Analysis of Relationships among Organizational Barriers to Energy Efficiency Improvement: A Case Study in Indonesia’s Steel Industry

    Directory of Open Access Journals (Sweden)

    Apriani Soepardi

    2018-01-01

    Full Text Available The aim of this paper is to analyze and rank the managerial-organizational barriers to energy efficiency improvement from an industry perspective. To that end, this study utilizes the Interpretive Structural Modeling (ISM methodology to identify the contextual relationships among the barriers. In a focus group discussion forum, five practitioners from the steel industry were consulted to identify these mutual linkages. The results indicated that five of the eight barriers proposed are in the linkage category. These barriers include that the energy manager or people in charge of energy management lack influence, there are higher priorities to production activity, there is management resistance to change, there is inadequate management capacity, and there are conflicts of interest within the organization. The management should focus more attention on these barriers, because they have both high driving power and dependency. The findings are intended to help managers from manufacturing sectors identify key barriers and thus develop strategic plans to address these issues.

  1. Magnetostrictive energy generator for harvesting the rotation of human knee joint

    Directory of Open Access Journals (Sweden)

    Baiping Yan

    2018-05-01

    Full Text Available This paper presents the design and fabrication of a rotary-impact magnetostrictive energy generator, used to harvest the rotation of human knee joint. The harvester consists of twelve movable Terfenol-D rods, surrounded by the picked up coils respectively, and alternate permanent magnet (PM array sandwiched in each part of the shell. Rotational electromagnetic power generating effect and impacted magnetostrictive power generating effect are designed in the harvester. Modeling and simulation are used to validate the concept. Then, magnetic field and leakage of the harvester are analyzed, electromagnetic force in the harvester is simulated. A prototype of harvester is fabricated, and subjected to the experimental characterization. It can be concluded that huge induced voltage generated in the short-time impact situation and that induced voltage in the harvester can reach up to 60-80 volts at 0.91Hz low frequency rotation. Also, the presented harvester has good harvesting effects at low frequency human walking and periodic swing crus situation, which are suitable to be used for future researches of wearable knee joint applications.

  2. Magnetostrictive energy generator for harvesting the rotation of human knee joint

    Science.gov (United States)

    Yan, Baiping; Zhang, Chengming; Li, Liyi

    2018-05-01

    This paper presents the design and fabrication of a rotary-impact magnetostrictive energy generator, used to harvest the rotation of human knee joint. The harvester consists of twelve movable Terfenol-D rods, surrounded by the picked up coils respectively, and alternate permanent magnet (PM) array sandwiched in each part of the shell. Rotational electromagnetic power generating effect and impacted magnetostrictive power generating effect are designed in the harvester. Modeling and simulation are used to validate the concept. Then, magnetic field and leakage of the harvester are analyzed, electromagnetic force in the harvester is simulated. A prototype of harvester is fabricated, and subjected to the experimental characterization. It can be concluded that huge induced voltage generated in the short-time impact situation and that induced voltage in the harvester can reach up to 60-80 volts at 0.91Hz low frequency rotation. Also, the presented harvester has good harvesting effects at low frequency human walking and periodic swing crus situation, which are suitable to be used for future researches of wearable knee joint applications.

  3. Energy harvester for rotating environments using offset pendulum and nonlinear dynamics

    International Nuclear Information System (INIS)

    Roundy, Shad; Tola, Jeffry

    2014-01-01

    We present an energy harvester for environments that rotate through the Earth’s gravitational field. Example applications include shafts connected to motors, axles, propellers, fans, and wheels or tires. Our approach uses the unique dynamics of an offset pendulum along with a nonlinear bistable restoring spring to improve the operational bandwidth of the system. Depending on the speed of the rotating environment, the system can act as a bistable oscillator, monostable stiffening oscillator, or linear oscillator. We apply our approach to a tire pressure monitoring system mounted on a car rim. Simulation and experimental test results show that the prototype generator is capable of directly powering an RF transmission every 60 s or less over a speed range of 10 to 155 kph. (paper)

  4. Energy harvester for rotating environments using offset pendulum and nonlinear dynamics

    Science.gov (United States)

    Roundy, Shad; Tola, Jeffry

    2014-10-01

    We present an energy harvester for environments that rotate through the Earth’s gravitational field. Example applications include shafts connected to motors, axles, propellers, fans, and wheels or tires. Our approach uses the unique dynamics of an offset pendulum along with a nonlinear bistable restoring spring to improve the operational bandwidth of the system. Depending on the speed of the rotating environment, the system can act as a bistable oscillator, monostable stiffening oscillator, or linear oscillator. We apply our approach to a tire pressure monitoring system mounted on a car rim. Simulation and experimental test results show that the prototype generator is capable of directly powering an RF transmission every 60 s or less over a speed range of 10 to 155 kph.

  5. Renewable energy market conditions and barriers in Turkey

    International Nuclear Information System (INIS)

    Nalan, Cicek Bezir; Murat, Oeztuerk; Nuri, Oezek

    2009-01-01

    Decentralized wind, hydropower, biogas and biomass, geothermal, solar thermal and solar electricity energy systems are the most commonly found renewable energy technologies promoted for rural energy supply within sustainable developments programs. They are, therefore, seen to have a central place in the practice of sustainable development and in allowing less development countries to bypass the environmentally damaging fossil fuel intensive paths made by industrialized countries. On the political front, many less development countries are critical of pressure on them to adopt environmental energy technologies. Turkey is situated the meeting point of three continents (Asia, Europe and Africa) and stands as a bridge between Asia and Europe. The country is located in southeastern Europe and southwestern Asia. As Turkey's economy has expanded in recent years, the consumption of primary energy has increased. Presently in order to increase the energy production from domestic energy resources, decrease the use of fossil fuels as well as reduce of green house gas emissions different renewable energy sources are used for energy production in Turkey. The share of energy production from renewable energy sources has increased during the last 10 years. Turkey must import most of the energy to meet her needs. Turkey also has a large potential for renewable energies. The lack of knowledge about renewable energy technologies by most policy-makers, potential consumers, and energy firm managers has played against renewable energy developments. The paper presents renewable energy used in Turkey and Europe Union and evaluation of the market conditions and barriers of renewable energy use in Turkey. (author)

  6. On the experimental determination of the efficiency of piezoelectric impact-type energy harvesters using a rotational flywheel

    International Nuclear Information System (INIS)

    Janphuang, P; Lockhart, R; Briand, D; De Rooij, N F; Henein, S

    2013-01-01

    This paper demonstrates a novel methodology using a rotational flywheel to determine the energy conversion efficiency of the impact based piezoelectric energy harvesters. The influence of the impact speed and additional proof mass on the efficiency is presented here. In order to convert low frequency mechanical oscillations into usable electrical energy, a piezoelectric harvester is coupled to a rotating gear wheel driven by flywheel. The efficiency is determined from the ratio of the electrical energy generated by the harvester to the mechanical energy dissipated by the flywheel. The experimental results reveal that free vibrations of the harvester after plucking contribute significantly to the efficiency. The efficiency and output energy can be greatly improved by adding a proof mass to the harvester. Under certain conditions, the piezoelectric harvesters have an impact energy conversion efficiency of 1.2%

  7. Reactions with weakly bound nuclei at near barrier energies

    International Nuclear Information System (INIS)

    Nanal, Vandana

    2014-01-01

    In reactions with weakly bound nuclei, the effect of breakup on fusion process has attracted much attention in recent years. The experimental study shows that breakup channel leads to suppression of complete fusion at above barrier energies due to loss of flux. The fusion barrier distribution can provide a further insight into understanding the influence of coupling to the breakup channels. Similar information could be obtained from the elastic and quasielastic (QEL) scattering because of the conservation of the reaction flux (i.e. R+T= 1), where R is the reflection probability and T is the transmission probability. Thus, quasi-elastic scattering at backward angles is the counterpart of the fusion process and it is expected that the barrier distributions extracted from two processes, namely, QEL and fusion should be similar. While this is true for tightly bound reaction systems, in reactions involving weakly bound projectiles significant differences have been observed for QEL barrier distributions with and without inclusion of breakup processes. This talk will present the recent results for fusion and quasi-elastic scattering in "6","7Li + "1"9"7Au system. Developmental efforts towards a momentum achromatic separator, MARIE, to extract projectile-like secondary ion beams following the reactions of heavy-ion beams from superconducting LINAC booster at Mumbai will also be presented. (author)

  8. Probing the Electronic Environment of Methylindoles using Internal Rotation and (14)N Nuclear Quadrupole Coupling.

    Science.gov (United States)

    Gurusinghe, Ranil M; Tubergen, Michael J

    2016-05-26

    High-resolution rotational spectra were recorded in the 10.5-21.0 GHz frequency range for seven singly methylated indoles. (14)N nuclear quadrupole hyperfine structure and spectral splittings arising from tunneling along the internal rotation of the methyl group were resolved for all indole species. The nuclear quadrupole coupling constants were used to characterize the electronic environment of the nitrogen atom, and the program XIAM was used to fit the barrier to internal rotation to the measured transition frequencies. The best fit barriers were found to be 277.1(2), 374.32(4), 414.(5), 331.6(2), 126.8675(15), 121.413(4), and 426(3) cm(-1) for 1-methylindole through 7-methylindole, respectively. The fitted barriers were found to be in good agreement with barriers calculated at the ωB97XD/6-311++G(d,p) level. The complete set of experimental barriers is compared to theoretical investigations of the origins of methyl torsional barriers and confirms that the magnitude of these barriers is an overall effect of individual hyperconjugative and structural interactions of many bonding/antibonding orbitals.

  9. Barriers and Potential Solutions for Energy Renovation of Buildings in Denmark

    Directory of Open Access Journals (Sweden)

    Niels I. Meyer

    2014-02-01

    Full Text Available Buildings account for a substantial part of the total energy consumption. In Denmark this number is about 40 % and this is approximately the same in most industrial countries. On this background there is an urgent need to develop strategies for reducing the energy demand in the building sector. Renovation of existing buildings must have high priority as houses often last for 50 to 100 years, while the time perspective for the desired transformation to low-energy houses is less than 30 years in order to mitigate global warming and avoid irreversible tipping-points. The only sustainable energy supply in the perspective of centuries is renewable energy provided by the sun and exploited in the form of solar heat, solar electricity (PVs, wind power, hydropower, wave power, and some types of biomass etc. A future dominating role of intermittent renewable sources requires new integrated systems thinking on both the supply and demand side for heat, electricity and transport. Implementing such Smart Energy Systems requires integrated strategic energy planning on the national and local level. With the fundamental changes in the energy supply technologies expected during the coming years, it is important to synchronize investments in energy conservation measures with investments in the supply side, in order to avoid overinvestment in supply systems and thus to minimize the total costs of the transformation to Smart Energy Systems. This paper highlights some of the most important barriers for renovation of existing buildings in Denmark and points to policies for overcoming these barriers. Some of the policies have been presented in the reports of a recent Danish research project (CEESA

  10. Barriers to the adoption of energy-saving technologies in the building sector: A survey study of Jing-jin-tang, China

    International Nuclear Information System (INIS)

    Du, Ping; Zheng, Li-Qun; Xie, Bai-Chen; Mahalingam, Arjun

    2014-01-01

    The building sector of China currently consumes 20% of the total energy consumption. Studies on barriers to the adoption of building energy-saving technologies are of great significance on implementing policies related to achieving energy-saving goals. This paper studied 15 barriers with the aid of information collected through questionnaires and semi-structured interviews. The respondents were 135 employees working in the Jing-jin-tang area. Based on the results of the factor analysis, the barriers were categorized into five groups: attitudes of stakeholders, policies and regulations, auxiliary resources, profitability, and adaptability of the technologies. Analysis of the entire sample showed that the stakeholders’ reluctance to use was the largest barrier, followed by high initial investment and low profitability. Further analysis showed that the occupation and designation of the respondents and the size of the enterprises that they served influenced their perspectives on the barriers. It was found that architects attributed more importance to the adoption of energy-saving technologies than contractors; barriers confronted by employees of large enterprises and small enterprises were different; managers perceived weaker barriers than frontline employees and were more optimistic about the prospect of building energy-saving technologies. Finally, policy recommendations were proposed based on these in-depth and targeted analyses. - Highlights: • Fifteen barriers to the adoption of energy-saving technologies are discussed. • Surveys are conducted in one of China's most technologically developed area. • The barriers are divided into 5 groups according to the results of factor analysis. • Barriers related to profitability greatly hamper the adoption of the technologies. • Comparative analyses show the background of respondents influence their viewpoints

  11. Assessment of non-cost barriers to renewable energy growth in EU Member States - AEON

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-05-15

    The accelerated deployment of renewable energy technologies has become a major priority for public policy makers across the globe. In the last two decades, most of the debate concerning the promotion of renewables was focused on the financial support schemes and on improving grid access conditions for renewable electricity. Of course, these are crucial issues which will continue to deserve serious attention in the future. However, during the last few years, the importance of tackling non-financial and non-technical barriers to renewable electricity, heat and transport has gained the attention of many policy analysts. In June 2009, Directive 2009/28/EC on the promotion of the use of energy from renewable sources, entered into force. The articles 13, 14 and 16 of the Directive contain a number of requirements for Member States to address or remove non-cost barriers to the increased deployment of renewable energy sources. This study presents among others an overview of these barriers in all EU Member States; their history, their impact on renewable energy deployment and suggestions for policy solutions, where feasible. Separate studies were carried out for 27 EU-countries and made available in a zip-file.

  12. Fisher information and steric effect: study of the internal rotation barrier of ethane.

    Science.gov (United States)

    Esquivel, Rodolfo O; Liu, Shubin; Angulo, Juan Carlos; Dehesa, Jesús S; Antolín, Juan; Molina-Espíritu, Moyocoyani

    2011-05-05

    On the basis of a density-based quantification of the steric effect [Liu, S. B. J. Chem. Phys.2007, 126, 244103], the origin of the internal rotation barrier between the eclipsed and staggered conformers of ethane is systematically investigated in this work from an information-theoretical point of view by using the Fisher information measure in conjugated spaces. Two kinds of computational approaches are considered in this work: adiabatic (with optimal structure) and vertical (with fixed geometry). The analyses are performed systematically by following, in each case, the conformeric path by changing the dihedral angle from 0 to 180° . This is calculated at the HF, MP2, B3LYP, and CCSD(T) levels of theory and with several basis sets. Selected descriptors of the densities are utilized to support the observations. Our results show that in the adiabatic case the eclipsed conformer possesses a larger steric repulsion than the staggered conformer, but in the vertical cases the staggered conformer retains a larger steric repulsion. Our results verify the plausibility for defining and computing the steric effect in the post-Hartree-Fock level of theory according to the scheme proposed by Liu.

  13. Free-Energy Barrier of Filling a Spherical Cavity in the Presence of Line Tension: Implication to the Energy Barrier between the Cassie and Wenzel States on a Superhydrophobic Surface with Spherical Cavities.

    Science.gov (United States)

    Iwamatsu, Masao

    2016-09-20

    The free-energy barrier of filling a spherical cavity having an inner wall of various wettabilities is studied. The morphology and free energy of a lens-shaped droplet are determined from the minimum of the free energy. The effect of line tension on the free energy is also studied. Then, the equilibrium contact angle of the droplet is determined from the generalized Young's equation. By increasing the droplet volume within the spherical cavity, the droplet morphology changes from spherical with an equilibrium contact angle of 180° to a lens with a convex meniscus, where the morphological complete drying transition occurs. By further increasing the droplet volume, the meniscus changes from convex to concave. Then, the lens-shaped droplet with concave meniscus spreads over the whole inner wall, resulting in an equilibrium contact angle of 0° to leave a spherical bubble, where the morphological complete wetting transition occurs. Finally, the whole cavity is filled with liquid. The free energy shows a barrier from complete drying to complete wetting as a function of droplet volume, which corresponds to the energy barrier between the Cassie and Wenzel states of the superhydrophobic surface with spherical cavities. The free-energy maximum occurs when the meniscus of the droplet becomes flat, and it is given by an analytic formula. The effect of line tension is expressed by the scaled line tension, and this effect is largest at the free-energy maximum. The positive line tension increases the free-energy maximum, which thus increases the stability of the Cassie superhydrophobic state, whereas the negative line tension destabilizes the superhydrophobic state.

  14. Nucleus-size pinning for determination of nucleation free-energy barriers and nucleus geometry

    Science.gov (United States)

    Sharma, Abhishek K.; Escobedo, Fernando A.

    2018-05-01

    Classical Nucleation Theory (CNT) has recently been used in conjunction with a seeding approach to simulate nucleation phenomena at small-to-moderate supersaturation conditions when large free-energy barriers ensue. In this study, the conventional seeding approach [J. R. Espinosa et al., J. Chem. Phys. 144, 034501 (2016)] is improved by a novel, more robust method to estimate nucleation barriers. Inspired by the interfacial pinning approach [U. R. Pedersen, J. Chem. Phys. 139, 104102 (2013)] used before to determine conditions where two phases coexist, the seed of the incipient phase is pinned to a preselected size to iteratively drive the system toward the conditions where the seed becomes a critical nucleus. The proposed technique is first validated by estimating the critical nucleation conditions for the disorder-to-order transition in hard spheres and then applied to simulate and characterize the highly non-trivial (prolate) morphology of the critical crystal nucleus in hard gyrobifastigia. A generalization of CNT is used to account for nucleus asphericity and predict nucleation free-energy barriers for gyrobifastigia. These predictions of nuclei shape and barriers are validated by independent umbrella sampling calculations.

  15. Transformation of heat into mechanical energy by means of rotating systems

    Directory of Open Access Journals (Sweden)

    Mešina Marian

    2018-01-01

    Full Text Available All heat engines need two different temperatures for their work, T1rotation around a given axis. The heat introduced and removed can not only lead to a change in the parameters of temperature, pressure, and volume, which are considered in conventional thermodynamics, but also to a change in the state of rotation. The rotational speed must also be taken into account in all phases of the cycle for all efficiency calculations. In many cases, this leads to a surprisingly different result from the results of conventional thermodynamics, that the efficiency of the cycle can exceed the Carnot limit. The efficiency values depend not only on temperatures and rotational speeds, but also on the material data. The proposed new type of heat engine makes it possible to better utilise very small temperature differences and under certain conditions, in combination with an ideal heat pump, to extract ambient heat and convert it into mechanical energy. The calculated results were presented for simple geometry and can easily be verified experimentally. In combination with an ideal heat pump, the proposed heat engine facilitates the surroundings to withdraw heat and convert it into mechanical work.

  16. Breakup mechanisms for 7Li + 197Au, 204Pb systems at sub-barrier energies

    Directory of Open Access Journals (Sweden)

    Luong D.H.

    2013-12-01

    Full Text Available Coincidence measurements of breakup fragments were carried out for the 7Li + 197Au and 204Pb systems at sub-barrier energies. The mechanisms triggering breakup, and time-scales of each process, were identified through the reaction Q-values and the relative energy of the breakup fragments. Binary breakup of 7Li were found to be predominantly triggered by nucleon transfer, with p-pickup leading to 8Be → α + α decay being the preferred breakup mode. From the time-scales of each process, the coincidence yields were separated into prompt and delayed components, allowing the identification of breakup process important in the suppression of complete fusion of 7Li at above-barrier energies.

  17. The rotational predissociation of HeH+ energy and lifetime measurements, ch. 3

    International Nuclear Information System (INIS)

    Locht, R.; Maas, J.G.; Asselt, N.P.F.B. van; Los, J.

    1976-01-01

    Relative lifetimes and energies above the dissociation limit have been determined for the rotational predissociation of several quasi-bound levels of the X'Σ + state of 4 HeH + . In particular, the lifetimes are very sensitive to the shape of the potential energy curve. These measurements are used to discriminate between two ab initio potential curves which differ by only 0.00004 a.u. (approximately 1 meV). Using the lifetime data, relative population factors were determined for the observed levels

  18. Rotational energy transfer of the A{sup 2}{Sigma}`({nu}`=1) state of OH

    Energy Technology Data Exchange (ETDEWEB)

    Beaud, P; Radi, P; Frey, H B; Mischler, B; Tzannis, A P; Gerber, T [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Spectrally and temporally resolved laser excited fluorescence of OH is investigated in the picosecond time domain. The total rotational energy transfer (RET) rate from the excited state is determined from the experimental data. Simulated spectra obtained by modelling RET with the energy corrected sudden approximation agree well with the measured spectra. (author) 1 fig., 1 tab., 5 refs.

  19. Nuclear rotational population patterns in heavy-ion scattering and transfer reactions

    Energy Technology Data Exchange (ETDEWEB)

    Rasmussen, J O; Stoyer, M A [Lawrence Berkeley Lab., CA (USA); Canto, L F; Donangelo, R [Universidade Federal do Rio de Janeiro, RJ (Brazil); Ring, P [Technische Univ. Muenchen, Garching (Germany, F.R.). Fakultaet fuer Physik

    1991-05-01

    A model of {sup 239}Pu with decoupled neutron is used for theoretical calculations of rotational population patterns in heavy ion inelastic scattering and one-neutron transfer reactions. The system treated in {sup 90}Zr on {sup 239}Pu at the near-barrier energy of 500 MeV and backscattering angles of 180deg and 140deg. The influence of the complex nuclear optical potential is seen to be very strong, and the Nilsson wave function of the odd neutron produces a distinctive pattern in the transfer reaction. (orig.).

  20. Environmental effects of energy forest (short rotation willow)

    International Nuclear Information System (INIS)

    Frank, K.

    1994-01-01

    This paper deals with environmental effects of producing and combusting energy forest fuel. Energy forest means short rotation willow (Salix). Supposed effects of sewage sludge application are discussed as well. Energy forestry on agricultural land implies both advantages and disadvantages for the environment. Leaf litter (humified leaves) increases the humus content in the top soil. The soil fauna is also positively affected. Until now performed studies about nitrogen leakage from fields cultivated with energy forest (Salix), have not given any distinct results. A retarded drainage within energy forest fields is on the other hand noticed. While the root system of Salix is active during a long period of the year, the nitrogen leakage become less compared to traditional cultivation. The content of plant nutrients and organic matter in sewage sludge make a resource that can be useful for agricultural purposes, especially for energy forest cultivation. The content of heavy metals and organic emissions contradicts sludge application to agricultural land. Sewage sludge with todays quality increases somewhat the content of heavy metals in the soil. This condition can be counteracted to a certain extent by growing energy forest. It has been established that Salix has high ability to heavy metal uptake, especially cadmium. Growing energy forest on drained farm land is connected with a risk for root penetration into the drainage system. With enough water and plant nutrients in the top soil the risk is reduced. Shallow depth of the pipes increases the risk. Combustion of wood chip from energy forests (and other types of biomass) gives especially two advantages. It does not give any net contribution of carbon dioxide to the atmosphere. The sulphur discharge will be minimal since the sulphur content in wood fuels is low. Discharge of nitrogen oxide and hydrocarbons may give some problems. These can be reduced by technological measures when combusting. 27 refs, 4 tabs

  1. Energy barriers for diffusion on heterogeneous stepped metal surfaces: Ag/Cu(110)

    International Nuclear Information System (INIS)

    Sbiaai, K.; Boughaleb, Y.; Mazroui, M.; Hajjaji, A.; Kara, A.

    2013-01-01

    In this paper we investigated the diffusion of Ag adatom by computing the energy barriers for many elementary diffusive processes which are likely to happen near to the step edge on Cu (110). The barriers are calculated by means of molecular dynamics simulation by using embedded atom potentials. The proximity to steps alters these barriers considerably, and very different results may be expected. In fact, our numerical calculations show that the diffusion via jump process along step edge is predominant for Ag/Cu(110) and the diffusion over the step occurs sometimes, but only via exchange mechanisms. The adatom diffusion across channels is difficult due to the high value of activation energy required (around 1 eV). Furthermore, we found the Ehrlich–Schwoebel barrier for diffusion around 120 meV in order to descend via exchange process and of the order of 170 meV via hopping mode. This aspect may have a strong influence on the growth character. In general our results suggest that, for our metal system, diffusion mechanism may be important for mass transport across the steps. Implications of these findings are discussed. - Highlights: • Study of adatom diffusion near the step edge • The diffusion along channel is enhanced through jump process. • Arrhenius law is satisfied for a wide range of temperature (310–600 K)

  2. Pump--probe measurements of state-to-state rotational energy transfer rates in N2 (v=1)

    International Nuclear Information System (INIS)

    Sitz, G.O.; Farrow, R.L.

    1990-01-01

    We report direct measurements of the state-to-state rotational energy transfer rates for N 2 (υ=1) at 298 K. Stimulated Raman pumping of Q-branch (υ=1 left-arrow 0) transitions is used to prepare a selected rotational state of N 2 in the υ=1 state. After allowing an appropriate time interval for collisions to occur, 2+2 resonance-enhanced multiphoton ionization is used (through the a 1 Π g left-arrow X 1 Σ + g transition) to detect the relative population of the pumped level and other levels to which rotational energy transfer has occurred. We have performed a series of measurements in which a single even rotational level (J i =0--14) is excited and the time-dependent level populations are recorded at three or more delay times. This data set is then globally fit to determine the best set of state-to-state rate constants. The fitting procedure does not place any constraints (such as an exponential gap law) on the J or energy dependence of the rates. We compare our measurements and best-fit rates with results predicted from phenomenological rate models and from a semiclassical scattering calculation of Koszykowski et al. [J. Phys. Chem. 91, 41 (1987)]. Excellent agreement is obtained with two of the models and with the scattering calculation. We also test the validity of the energy-corrected sudden (ECS) scaling theory for N 2 by using our experimental transfer rates as basis rates (J=L→0), finding that the ECS scaling expressions accurately predict the remaining rates

  3. Socio-cultural barriers to the development of a sustainable energy system - the case of hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Kjerulf Petersen, L.; Holst Andersen, A.

    2009-02-15

    Any transition to a more sustainable energy system, radically reducing greenhouse gas emissions, is bound to run in to a host of different barriers - technological and economic, but also socio-cultural. This will also be the case for any large-scale application of hydrogen as energy carrier, especially if the system is going to be based on renewable energy sources. The aim of these research notes is to review and discuss major socio-cultural barriers to new forms of energy supply in general and to hydrogen specifically. Reaching sufficient reductions in greenhouse gas emissions may require more than large-scale dissemination of renewable energy sources. Also reductions or moderations in energy demand may be necessary. Hence, a central point in the research note is to consider not only socio-cultural obstacles for changing technologies in energy production, distribution and consumption but also obstacles for changing the scale of energy consumption, i.e. moderating the growth in how much energy is consumed or even reducing consumption volumes. (au)

  4. Barriers to installing innovative energy systems in existing housing stock identified

    NARCIS (Netherlands)

    Hoppe, Thomas

    2013-01-01

    Several barriers to upgrading existing social housing with innovative energy systems (IES) have been identified by a study of eight large-scale renovation projects in the Netherlands. These include a lack of trust between stakeholders, opposition from tenants on grounds of increased costs or delays,

  5. Barriers and possibilities for low-carbon-energy consuming technologies

    DEFF Research Database (Denmark)

    Bjarklev, Araceli

    consensus that one of the solutions to the current environmental challenge will be based on low-carbon-technologies, there are many issues that set a barrier for its adequate development and still many actors in these sectors are sceptical about the possibilities. Illumination is a very interesting sector...... to target, since it uses 19% of the total electricity produced in the world. Consequently, this paper takes the Danish office lighting sector as a study object and discusses the question: What are the main barriers and possibilities for the energy saving illumination technologies to efficiently reduce...... their ecological footprint. The discussion is supported by using relevant elements of the cradle-to-grave, eco-design and environmental-innovation theories. It is based on active participation in interdisciplinary projects and face-to-face in-depth interviews with relevant actors along the entire Danish...

  6. Triaxial energy relation to describe rotational band in 98-112Ru nuclei

    International Nuclear Information System (INIS)

    Singh, Yuvraj; Gupta, K.K.; Bihari, Chhail; Varshney, A.K.; Varshney, Mani; Singh, M.; Gupta, D.K.

    2010-01-01

    In a broader perspective rotation vibration coupling parameter (b) is considered changing with the change in excitation energy (ε 1 ) and is evaluated on fitting experimental energy for 98-112 Ru isotopes in the frame work of general asymmetric rotor model. The moment of inertia parameter (a), common to yrast and quasi-γ band, is calculated from deformation parameter (β) using general empirical relation. The present work is undertaken to suggest some suitable equation for the trajectories which are similar in shape in 98-112 Ru nuclei

  7. Analyzing Barriers to Energy Conservation in Residences and Offices: The Rewire Program at the University of Toronto

    Science.gov (United States)

    Stokes, Leah C.; Mildenberger, Matto; Savan, Beth; Kolenda, Brian

    2012-01-01

    Conducting a barriers analysis is an important first step when designing proenvironmental behavior change interventions. Yet, detailed information on common barriers to energy conservation campaigns remains unavailable. Using a pair of original surveys, we leverage the theory of planned behavior to report on the most important barriers for…

  8. Barriers to the use of renewable energy in Western Australia

    International Nuclear Information System (INIS)

    Harman, F.; Stocker, L.; Walker, I.; Stirling, M.

    1991-08-01

    Public attitudes towards renewable energy sources, in particular solar energy is examined through a survey of water heating in the metropolitan area, energy supply and use on pastoral leases in Western Australia. The private costs of water heating systems was assessed in a way which may give guidance to manufacturers on improving the economics of solar water heating systems, and to policy makers for facilitating the use of solar water heating systems. The policies currently in place in Western Australia which act as barriers to the greater use of renewable energy were also outlined. The cost data, together with the attitudes of consumers as revealed in the surveys, indicate that manufacturers and suppliers of renewable energy equipment need to reduce costs and improve the actual and perceived capability, performance and reliability of their equipment. 96 refs., 30 tabs., 38 figs

  9. Current-induced changes of migration energy barriers in graphene and carbon nanotubes.

    Science.gov (United States)

    Obodo, J T; Rungger, I; Sanvito, S; Schwingenschlögl, U

    2016-05-21

    An electron current can move atoms in a nanoscale device with important consequences for the device operation and breakdown. We perform first principles calculations aimed at evaluating the possibility of changing the energy barriers for atom migration in carbon-based systems. In particular, we consider the migration of adatoms and defects in graphene and carbon nanotubes. Although the current-induced forces are large for both the systems, in graphene the force component along the migration path is small and therefore the barrier height is little affected by the current flow. In contrast, the same barrier is significantly reduced in carbon nanotubes as the current increases. Our work also provides a real-system numerical demonstration that current-induced forces within density functional theory are non-conservative.

  10. Barriers to Building Energy Efficiency (BEE) promotion: A transaction costs perspective

    Science.gov (United States)

    Qian Kun, Queena

    Worldwide, buildings account for a surprisingly high 40% of global energy consumption, and the resulting carbon footprint significantly exceeds that of all forms of transportation combined. Large and attractive opportunities exist to reduce buildings' energy use at lower costs and higher returns than in other sectors. This thesis analyzes the concerns of the market stakeholders, mainly real estate developers and end-users, in terms of transaction costs as they make decisions about investing in Building Energy Efficiency (BEE). It provides a detailed analysis of the current situation and future prospects for BEE adoption by the market's stakeholders. It delineates the market and lays out the economic and institutional barriers to the large-scale deployment of energy-efficient building techniques. The aim of this research is to investigate the barriers raised by transaction costs that hinder market stakeholders from investing in BEES. It explains interactions among stakeholders in general and in the specific case of Hong Kong as they consider transaction costs. It focuses on the influence of transaction costs on the decision-making of the stakeholders during the entire process of real estate development. The objectives are: 1) To establish an analytical framework for understanding the barriers to BEE investment with consideration of transaction costs; 2) To build a theoretical game model of decision making among the BEE market stakeholders; 3) To study the empirical data from questionnaire surveys of building designers and from focused interviews with real estate developers in Hong Kong; 4) To triangulate the study's empirical findings with those of the theoretical model and analytical framework. The study shows that a coherent institutional framework needs to be established to ensure that the design and implementation of BEE policies acknowledge the concerns of market stakeholders by taking transaction costs into consideration. Regulatory and incentive options

  11. GaN Schottky diodes with single-crystal aluminum barriers grown by plasma-assisted molecular beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Tseng, H. Y.; Yang, W. C.; Lee, P. Y.; Lin, C. W.; Cheng, Kai-Yuan; Hsieh, K. C.; Cheng, K. Y., E-mail: kycheng@ee.nthu.edu.tw [Department of Electrical Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Hsu, C.-H. [Division of Scientific Research, National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China)

    2016-08-22

    GaN-based Schottky barrier diodes (SBDs) with single-crystal Al barriers grown by plasma-assisted molecular beam epitaxy are fabricated. Examined using in-situ reflection high-energy electron diffractions, ex-situ high-resolution x-ray diffractions, and high-resolution transmission electron microscopy, it is determined that epitaxial Al grows with its [111] axis coincident with the [0001] axis of the GaN substrate without rotation. In fabricated SBDs, a 0.2 V barrier height enhancement and 2 orders of magnitude reduction in leakage current are observed in single crystal Al/GaN SBDs compared to conventional thermal deposited Al/GaN SBDs. The strain induced piezoelectric field is determined to be the major source of the observed device performance enhancements.

  12. Low energy pion detection by a silicon surface barrier telescope

    International Nuclear Information System (INIS)

    Sealock, R.M.; Caplan, H.S.; Leung, M.K.

    1978-01-01

    Four telescopes of three (2-ΔE, 1-E) silicon surface barrier detectors each, mounted in the focal plane of a magnetic spectrometer, have been used to detect positive pions in the energy range from 4.7-17.9 MeV and negative pions from 14.1-17.9 MeV. Positive pions from 4.7-12.7 MeV were stopped in the third detector while positive and negative pions from 14.1-17.9 MeV were detected in transmission. For energies greater than 7.4 MeV aluminum moderators were placed in front of the first detector to degrade the pion energy. Energy spectra show well resolved pion peaks with extremely low background. Double differential cross sections for the 12 C(e,π + ) 12 B,e' reaction have been measured. (Auth.)

  13. The consequences of translational and rotational entropy lost by small molecules on binding to proteins

    Science.gov (United States)

    Murray, Christopher W.; Verdonk, Marcel L.

    2002-10-01

    When a small molecule binds to a protein, it loses a significant amount of rigid body translational and rotational entropy. Estimates of the associated energy barrier vary widely in the literature yet accurate estimates are important in the interpretation of results from fragment-based drug discovery techniques. This paper describes an analysis that allows the estimation of the rigid body entropy barrier from the increase in binding affinities that results when two fragments of known affinity and known binding mode are joined together. The paper reviews the relatively rare number of examples where good quality data is available. From the analysis of this data, we estimate that the barrier to binding, due to the loss of rigid-body entropy, is 15-20 kJ/mol, i.e. around 3 orders of magnitude in affinity at 298 K. This large barrier explains why it is comparatively rare to observe multiple fragments binding to non-overlapping adjacent sites in enzymes. The barrier is also consistent with medicinal chemistry experience where small changes in the critical binding regions of ligands are often poorly tolerated by enzymes.

  14. Financing renewable energy in developing countries. Drivers and barriers for private finance in sub-Saharan Africa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-02-15

    The focus of this report is to identify and portray current barriers to the scaling up of private investment and finance for electricity generation from renewable energy sources in the sub-Saharan region. Best practice in tackling these barriers is identified, partly from a literature review but especially from the results of a survey conducted among 36 financial institutions that are UNEP Finance Initiative members and two non-member banks (all survey respondents have experience in the field of energy infrastructure finance). Promising avenues in the areas of local policy reform, incentive mechanisms and international de-risking instruments are highlighted. In particular, this report addresses the following questions: (a) Why are sub-Saharan Africa and developing countries elsewhere failing to expand electricity generation from renewable sources? What are the barriers to such expansion? What is keeping the risk-return profile of renewable energy investments in sub-Saharan Africa unattractive and projects commercially unviable?; (b) What have been the experiences of private sector lenders and investors in the area of renewable energy projects in developing countries? What barriers and drivers have they encountered, and how can these experiences be of use in sub-Saharan Africa?; (c) What can be learned from the modest but encouraging successes of a few sub-Saharan African countries? Can these results be replicated? What was done in these countries to improve the risk-return profile of renewable energy and unlock private finance?.

  15. Continuously rotating cat scanning apparatus and method

    International Nuclear Information System (INIS)

    Bax, R.F.

    1980-01-01

    A tomographic scanner with a continuously rotating source of radiation is energized by converting inertial mechanical energy to electrical energy. The mechanical-to-electrical conversion apparatus is mounted with the x-ray source to be energized on a rotating flywheel. The inertial mechanical energy stored in the rotating conversion apparatus, flywheel and x-ray source is utilized for generating electrical energy used, in turn, to energize the x-ray source

  16. BARRIERS TO ENERGY ACCESS IN THE URBAN POOR AREAS OF DHAKA, BANGLADESH: ANALYSIS OF PRESENT SITUATION AND RECOMMENDATIONS

    Directory of Open Access Journals (Sweden)

    Molla Shahadat Hossain Lipu

    2013-10-01

    Full Text Available Energy is a crucial input to promote socioeconomic development. In Bangladesh, about 96 million people (59% do not have access to electricity and 143 million people (88% still depend on biomass for cooking. The urban poor living in slum areas with lack of access to clean and modern sources of energy have not been addressed comprehensively. The main objective of this study is to identify the barriers faced by the urban poor in the slum areas of Dhaka in accessing different fuels and provide specific recommendations to overcome the barriers to enable energy access. The study is mainly based on field survey covering 185 households of the four major slum areas of Dhaka, literature review, and stakeholder interviews. Many barriers have been identified through this research where urban poor face problems in accessing legal energy services due to illegal settlement, lack of explicit policy on energy and housing, lack of dedicated institution, the pervasive role of Mastaans, poor infrastructure and lack of monitoring and evaluating system. Barriers specific recommendations are also suggested based on the experiences from the field visit and the best practices outside Bangladesh are also identified.

  17. Socio-technical barriers to the use of energy-efficient timber drying technology in New Zealand

    International Nuclear Information System (INIS)

    Bell, Martha; Carrington, Gerry; Lawson, Rob; Stephenson, Janet

    2014-01-01

    This study of industrial energy behaviours identifies barriers to the use of energy-efficient drying technology in the New Zealand timber industry, and explores these barriers through the “energy cultures” lens. Vented kiln dryers were preferred by larger firms and heat pump kiln dryers were used by smaller firms. Although few firms could specify all their costs, we found no significant differences in the average operating costs, drying costs or commercial success of the larger and smaller firms. We found that socio-technical barriers create “energy cultures” at the level of both the firm and the sector, supporting the dominance of vented kiln dryers. The prevailing technologies, practices and norms at the sector level strongly support vented kilns, the status quo being embedded in the socio-technical context, hindering technological learning, improved energy efficiency and innovation. Influential stakeholders in the industry were thus part of, and locked into, the industry-wide energy culture, and were not in a position to effect change. We conclude that actors external to the prevailing industry energy culture need to leverage change in the industry norms, practices and/or technologies in order to reap the advantages of energy-efficient drying technology, assist its continued evolution and avoid the risks of path-dependency. - Highlights: • Firms processing timber in New Zealand use two main drying technologies. • Relatively inefficient vented dryers dominate over energy-efficient heat pumps. • Operating costs are similar but the socio-technical regime supports vented dryers. • Stasis is created by fixed energy cultures both within firms and across the sector. • Stasis hampers technical development in heat pump drying and business innovation

  18. Fusion barrier distributions in 28,30Si + 124Sn reactions

    International Nuclear Information System (INIS)

    Danu, L.S.; Nayak, B.K.; Biswas, D.C.; Saxena, A.; Thomas, R.G.; Mirgule, E.T.; Choudhury, R.K.

    2009-01-01

    The coupling of various degrees of freedom such as static deformation, inelastic excitation and nucleon transfer with the relative motion gives rise to a distribution of barrier in heavy ion induced fusion reactions. The barrier distribution is a fingerprint of the reaction characterizing the important channel couplings. The relative importance of various couplings in fusion reaction is of topical interest. In an earlier study with deformed projectiles 28,30 Si on 115 In target, it was observed that the barrier distributions get affected due to coulomb reorientation of the deformed projectile nuclei in the field of target nucleus thus giving rise to fusion hindrance at sub-barrier energies. In that study, we considered deformed projectile rotational and positive Q-value transfer channel couplings to relative motion in fusion for investigation of Coulomb reorientation and no inelastic coupling of the 115 In target was considered. In the present work, we have extended the measurements with 124 Sn target and inelastic coupling of target has been considered in the coupled channel calculations. The fusion barrier distributions for 28,30 Si + 124 Sn systems have been obtained by quasi-elastic scattering measurements at backward angles and the results compared with the predictions of coupled channel calculations

  19. Observation of the one- to six-neutron transfer reactions at sub-barrier energies

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, C.L.; Rehm, K.E.; Gehring, J. [and others

    1995-08-01

    It was suggested many years ago that when two heavy nuclei are in contact during a grazing collision, the transfer of several correlated neutron-pairs could occur. Despite considerable experimental effort, however, so far only cross sections for up to four-neutron transfers have been uniquely identified. The main difficulties in the study of multi-neutron transfer reactions are the small cross sections encountered at incident energies close to the barrier, and various experimental uncertainties which can complicate the analysis of these reactions. We have for the first time found evidence for multi-neutron transfer reactions covering the full sequence from one- to six-neutron transfer reactions at sub-barrier energies in the system {sup 58}Ni + {sup 100}Mo.

  20. Current-induced changes of migration energy barriers in graphene and carbon nanotubes

    KAUST Repository

    Obodo, Tobechukwu Joshua

    2016-04-29

    An electron current can move atoms in a nanoscale device with important consequences for the device operation and breakdown. We perform first principles calculations aimed at evaluating the possibility of changing the energy barriers for atom migration in carbon-based systems. In particular, we consider the migration of adatoms and defects in graphene and carbon nanotubes. Although the current-induced forces are large for both the systems, in graphene the force component along the migration path is small and therefore the barrier height is little affected by the current flow. In contrast, the same barrier is significantly reduced in carbon nanotubes as the current increases. Our work also provides a real-system numerical demonstration that current-induced forces within density functional theory are non-conservative. © 2016 The Royal Society of Chemistry.

  1. Understanding the free energy barrier and multiple timescale dynamics of charge separation in organic photovoltaic cells.

    Science.gov (United States)

    Yan, Yaming; Song, Linze; Shi, Qiang

    2018-02-28

    By employing several lattice model systems, we investigate the free energy barrier and real-time dynamics of charge separation in organic photovoltaic (OPV) cells. It is found that the combined effects of the external electric field, entropy, and charge delocalization reduce the free energy barrier significantly. The dynamic disorder reduces charge carrier delocalization and results in the increased charge separation barrier, while the effect of static disorder is more complicated. Simulation of the real-time dynamics indicates that the free charge generation process involves multiple time scales, including an ultrafast component within hundreds of femtoseconds, an intermediate component related to the relaxation of the hot charge transfer (CT) state, and a slow component on the time scale of tens of picoseconds from the thermally equilibrated CT state. Effects of hot exciton dissociation as well as its dependence on the energy offset between the Frenkel exciton and the CT state are also analyzed. The current results indicate that only a small energy offset between the band gap and the lowest energy CT state is needed to achieve efficient free charge generation in OPV devices, which agrees with recent experimental findings.

  2. Understanding the free energy barrier and multiple timescale dynamics of charge separation in organic photovoltaic cells

    Science.gov (United States)

    Yan, Yaming; Song, Linze; Shi, Qiang

    2018-02-01

    By employing several lattice model systems, we investigate the free energy barrier and real-time dynamics of charge separation in organic photovoltaic (OPV) cells. It is found that the combined effects of the external electric field, entropy, and charge delocalization reduce the free energy barrier significantly. The dynamic disorder reduces charge carrier delocalization and results in the increased charge separation barrier, while the effect of static disorder is more complicated. Simulation of the real-time dynamics indicates that the free charge generation process involves multiple time scales, including an ultrafast component within hundreds of femtoseconds, an intermediate component related to the relaxation of the hot charge transfer (CT) state, and a slow component on the time scale of tens of picoseconds from the thermally equilibrated CT state. Effects of hot exciton dissociation as well as its dependence on the energy offset between the Frenkel exciton and the CT state are also analyzed. The current results indicate that only a small energy offset between the band gap and the lowest energy CT state is needed to achieve efficient free charge generation in OPV devices, which agrees with recent experimental findings.

  3. Wave-Driven Rotation In Centrifugal Mirrors

    International Nuclear Information System (INIS)

    Fetterman, Abraham J.; Fisch, Nathaniel J.

    2011-01-01

    Centrifugal mirrors use supersonic rotation to provide axial confinement and enhanced stability. Usually the rotation is produced using electrodes, but these electrodes have limited the rotation to the Alfven critical ionization velocity, which is too slow to be useful for fusion. Instead, the rotation could be produced using radio frequency waves. A fixed azimuthal ripple is a simple and efficient wave that could produce rotation by harnessing alpha particle energy. This is an extension of the alpha channeling effect. The alpha particle power and efficiency in a simulated devices is sufficient to produce rotation without external energy input. By eliminating the need for electrodes, this opens new opportunities for centrifugal traps.

  4. Wave-particle interactions in rotating mirrorsa)

    Science.gov (United States)

    Fetterman, Abraham J.; Fisch, Nathaniel J.

    2011-05-01

    Wave-particle interactions in E ×B rotating plasmas feature an unusual effect: particles are diffused by waves in both potential energy and kinetic energy. This wave-particle interaction generalizes the alpha channeling effect, in which radio frequency waves are used to remove alpha particles collisionlessly at low energy. In rotating plasmas, the alpha particles may be removed at low energy through the loss cone, and the energy lost may be transferred to the radial electric field. This eliminates the need for electrodes in the mirror throat, which have presented serious technical issues in past rotating plasma devices. A particularly simple way to achieve this effect is to use a high azimuthal mode number perturbation on the magnetic field. Rotation can also be sustained by waves in plasmas without a kinetic energy source. This type of wave has been considered for plasma centrifuges used for isotope separation. Energy may also be transferred from the electric field to particles or waves, which may be useful for ion heating and energy generation.

  5. Wave-particle Interactions In Rotating Mirrors

    Energy Technology Data Exchange (ETDEWEB)

    Abraham J. Fetterman and Nathaniel J. Fisch

    2011-01-11

    Wave-particle interactions in E×B rotating plasmas feature an unusual effect: particles are diffused by waves in both potential energy and kinetic energy. This wave-particle interaction generalizes the alpha channeling effect, in which radio frequency waves are used to remove alpha particles collisionlessly at low energy. In rotating plasmas, the alpha particles may be removed at low energy through the loss cone, and the energy lost may be transferred to the radial electric field. This eliminates the need for electrodes in the mirror throat, which have presented serious technical issues in past rotating plasma devices. A particularly simple way to achieve this effect is to use a high azimuthal mode number perturbation on the magnetic field. Rotation can also be sustained by waves in plasmas without a kinetic energy source. This type of wave has been considered for plasma centrifuges used for isotope separation. Energy may also be transferred from the electric field to particles or waves, which may be useful for ion heating and energy generation.

  6. Wave-particle interactions in rotating mirrors

    International Nuclear Information System (INIS)

    Fetterman, Abraham J.; Fisch, Nathaniel J.

    2011-01-01

    Wave-particle interactions in ExB rotating plasmas feature an unusual effect: particles are diffused by waves in both potential energy and kinetic energy. This wave-particle interaction generalizes the alpha channeling effect, in which radio frequency waves are used to remove alpha particles collisionlessly at low energy. In rotating plasmas, the alpha particles may be removed at low energy through the loss cone, and the energy lost may be transferred to the radial electric field. This eliminates the need for electrodes in the mirror throat, which have presented serious technical issues in past rotating plasma devices. A particularly simple way to achieve this effect is to use a high azimuthal mode number perturbation on the magnetic field. Rotation can also be sustained by waves in plasmas without a kinetic energy source. This type of wave has been considered for plasma centrifuges used for isotope separation. Energy may also be transferred from the electric field to particles or waves, which may be useful for ion heating and energy generation.

  7. Wave-particle Interactions In Rotating Mirrors

    International Nuclear Information System (INIS)

    Fetterman, Abraham J.; Fisch, Nathaniel J.

    2011-01-01

    Wave-particle interactions in E-B rotating plasmas feature an unusual effect: particles are diffused by waves in both potential energy and kinetic energy. This wave-particle interaction generalizes the alpha channeling effect, in which radio frequency waves are used to remove alpha particles collisionlessly at low energy. In rotating plasmas, the alpha particles may be removed at low energy through the loss cone, and the energy lost may be transferred to the radial electric field. This eliminates the need for electrodes in the mirror throat, which have presented serious technical issues in past rotating plasma devices. A particularly simple way to achieve this effect is to use a high azimuthal mode number perturbation on the magnetic field. Rotation can also be sustained by waves in plasmas without a kinetic energy source. This type of wave has been considered for plasma centrifuges used for isotope separation. Energy may also be transferred from the electric field to particles or waves, which may be useful for ion heating and energy generation.

  8. Multiscale gyrokinetics for rotating tokamak plasmas: fluctuations, transport and energy flows.

    Science.gov (United States)

    Abel, I G; Plunk, G G; Wang, E; Barnes, M; Cowley, S C; Dorland, W; Schekochihin, A A

    2013-11-01

    This paper presents a complete theoretical framework for studying turbulence and transport in rapidly rotating tokamak plasmas. The fundamental scale separations present in plasma turbulence are codified as an asymptotic expansion in the ratio ε = ρi/α of the gyroradius to the equilibrium scale length. Proceeding order by order in this expansion, a set of coupled multiscale equations is developed. They describe an instantaneous equilibrium, the fluctuations driven by gradients in the equilibrium quantities, and the transport-timescale evolution of mean profiles of these quantities driven by the interplay between the equilibrium and the fluctuations. The equilibrium distribution functions are local Maxwellians with each flux surface rotating toroidally as a rigid body. The magnetic equilibrium is obtained from the generalized Grad-Shafranov equation for a rotating plasma, determining the magnetic flux function from the mean pressure and velocity profiles of the plasma. The slow (resistive-timescale) evolution of the magnetic field is given by an evolution equation for the safety factor q. Large-scale deviations of the distribution function from a Maxwellian are given by neoclassical theory. The fluctuations are determined by the 'high-flow' gyrokinetic equation, from which we derive the governing principle for gyrokinetic turbulence in tokamaks: the conservation and local (in space) cascade of the free energy of the fluctuations (i.e. there is no turbulence spreading). Transport equations for the evolution of the mean density, temperature and flow velocity profiles are derived. These transport equations show how the neoclassical and fluctuating corrections to the equilibrium Maxwellian act back upon the mean profiles through fluxes and heating. The energy and entropy conservation laws for the mean profiles are derived from the transport equations. Total energy, thermal, kinetic and magnetic, is conserved and there is no net turbulent heating. Entropy is produced

  9. Disentangling complete and incomplete fusion for 9Be+187Re system at near barrier energies

    International Nuclear Information System (INIS)

    Kharab, Rajesh; Chahal, Rajiv; Rajiv Kumar

    2015-01-01

    The breakup of projectile before fusion leads to some unusual fusion mechanisms like incomplete fusion (ICF) and sequential complete fusion (SCF). Experimentally, it is not possible to separate SCF events from direct complete fusion (DCF). However, the complete fusion and incomplete fusion can be measured separately. Theoretically it is very difficult to calculate the complete and incomplete fusion cross section separately using different models. Very recently A. Diaz-Torres has developed a computer code platypus based on classical dynamical model wherein the complete and incomplete fusion cross sections are calculated separately. But this model is found to work very well at energies above the barrier energy. Here we have attempted to extrapolate the results of the code platypus by using simple Wong's formula in conjunction with the energy dependent Woods-Saxon potential (EDWSP) in the below barrier energy region

  10. Optimization of voltage output of energy harvesters with continuous mechanical rotation extracted from human motion (Conference Presentation)

    Science.gov (United States)

    Rashid, Evan; Hamidi, Armita; Tadesse, Yonas

    2017-04-01

    With increasing popularity of portable devices for outdoor activities, portable energy harvesting devices are coming into spot light. The next generation energy harvester which is called hybrid energy harvester can employ more than one mechanism in a single device to optimize portion of the energy that can be harvested from any source of waste energy namely motion, vibration, heat and etc. In spite of few recent attempts for creating hybrid portable devices, the level of output energy still needs to be improved with the intention of employing them in commercial electronic systems or further applications. Moreover, implementing a practical hybrid energy harvester in different application for further investigation is still challenging. This proposal is projected to incorporate a novel approach to maximize and optimize the voltage output of hybrid energy harvesters to achieve a greater conversion efficiency normalized by the total mass of the hybrid device than the simple arithmetic sum of the individual harvesting mechanisms. The energy harvester model previously proposed by Larkin and Tadesse [1] is used as a baseline and a continuous unidirectional rotation is incorporated to maximize and optimize the output. The device harvest mechanical energy from oscillatory motion and convert it to electrical energy through electromagnetic and piezoelectric systems. The new designed mechanism upgrades the device in a way that can harvest energy from both rotational and linear motions by using magnets. Likewise, the piezoelectric section optimized to harvest at least 10% more energy. To the end, the device scaled down for tested with different sources of vibrations in the immediate environment, including machinery operation, bicycle, door motion while opening and closing and finally, human motions. Comparing the results from literature proved that current device has capability to be employed in commercial small electronic devices for enhancement of battery usage or as a backup

  11. New light on an old problem: Reflections on barriers and enablers of distributed energy

    International Nuclear Information System (INIS)

    Szatow, Anthony; Quezada, George; Lilley, Bill

    2012-01-01

    This viewpoint article, New light on an Old Problem, aims to stimulate thought and discussion on pathways to rapid emission reduction trajectories. It considers briefly the history of the Australian energy system and recent attempts to support emerging, distributed energy supply systems, before exploring the importance of new energy supply models and how they may emerge organically, ahead of further policy and regulatory shifts in Australia. The article is shaped by extensive primary research, literature review and engagement with policy makers, industry and community organisations, energy market institutions, colleagues and others over a period of four years. It outlines how new business models may reduce emissions ahead of policy and regulation, and the importance of keeping an open mind when considering ‘barriers’ to distributed energy. We hope this article will spark interest and dialogue with colleagues who may be experiencing and grappling with similar challenges. - Research highlights: ► We discuss documented barriers to distributed energy. ► We draw on socio-technical system literature and our research experience to outline a possible solution to distributed energy barriers. ► We describe a hypothetical energy service business model, led by the property sector, as a catalyst for energy market change. ► We outline reasons for our confidence in this property sector led energy services model.

  12. Potential and barrier study. Passive house and near-zero energy buildings; Potensial- og barrierestudie. Passivhus og naer nullenergibygninger

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    The main conclusion from the analysis is that the barriers to realize both passive and near zero-energy buildings are significant. In addition to being a mere economic assessment indicates that 30-70% of the technical potential is not profitable depending on energy price levels, the barriers is reducing the economic potential with approximately another half as a realistic market potential.(eb)

  13. Short rotation coppice for energy production: hydrological guidelines

    Energy Technology Data Exchange (ETDEWEB)

    Hall, R.L.

    2003-07-01

    This report provides hydrological guidelines for growers, land and water resource managers, environmental groups and other parties interested in utilising short rotation coppice (SRC) for energy production. The aim of the report is to help interested parties decide if a location is suitable for SRC planting by considering whether potential hydrological impacts will have an adverse effect on crop productivity and yield. The guidelines consider: the water use of SRC compared with other crops; the factors governing water use; the water requirements for a productive crop; and the likely impacts on the availability and quantity of water. The report points out that there are still gaps in our knowledge of the processes controlling the water use and growth of SRC and notes that, in some situations, there will be considerable uncertainty in predictions.

  14. Complex energy eigenvalues of a linear potential with a parabolical barrier

    International Nuclear Information System (INIS)

    Malherbe, J.B.

    1978-01-01

    The physical meaning and restrictions of complex energy eigenvalues are briefly discussed. It is indicated that a quasi-stationary phase describes an idealised disintegration system. Approximate resonance-eigenvalues of the one dimensional Schrodinger equation with a linear potential and parabolic barrier are calculated by means of Connor's semiclassical method. This method is based on the generalized WKB-method of Miller and Good. The results obtained confirm the correctness of a model representation which explains the unusual distribution of eigenvalues by certain other linear potentials in a complex energy level [af

  15. Wave induced supersonic rotation in mirrors

    Science.gov (United States)

    Fetterman, Abraham

    2010-11-01

    Wave-particle interactions in ExB supersonically rotating plasmas feature an unusual effect: particles are diffused by waves in both potential energy and kinetic energy [1]. This wave-particle interaction generalizes the alpha channeling effect, in which radio frequency waves are used to remove alpha particles collisionlessly at low energy. In rotating plasmas, the alpha particles may be removed at low energy through the loss cone, and the energy lost may be transferred to the radial electric field. This eliminates the need for electrodes in the mirror throat, which have presented serious technical issues in past rotating plasma devices. A particularly simple way to achieve this effect is to use a high azimuthal mode number perturbation on the magnetic field [2]. In the rotating frame, this perturbation is seen as a wave near the alpha particle cyclotron harmonic, and can break the azimuthal symmetry and magnetic moment conservation without changing the particle's total energy. The particle may exit if it reduces its kinetic energy and becomes more trapped if it gains kinetic energy, leading to a steady state current that maintains the field. Simulations of single particles in rotating mirrors show that a stationary wave can extract enough energy from alpha particles for a reactor to be self-sustaining. Rotation can also be sustained by waves in plasmas without a kinetic energy source. This type of wave has been considered for plasma centrifuges used for isotope separation [3]. [4pt] [1] A. J. Fetterman and N. J. Fisch, Phys Rev Lett 101, 205003 (2008). [0pt] [2] A. J. Fetterman and N. J. Fisch, Phys. Plasmas 17, 042112 (2010). [0pt] [3] A. J. Fetterman and N. J. Fisch, Plasma Sources Sci. Tech. 18, 045003 (2009).

  16. Hydrogen rotational and translational diffusion in calcium borohydride from quasielastic neutron scattering and DFT

    DEFF Research Database (Denmark)

    Blanchard, Didier; Riktor, M.D.; Maronsson, Jon Bergmann

    2010-01-01

    Hydrogen dynamics in crystalline calcium borohydride can be initiated by long-range diffusion or localized motion such as rotations, librations, and vibrations. Herein, the rotational and translational diffusion were studied by quasielastic neutron scattering (QENS) by using two instruments...... with different time scales in combination with density functional theory (DFT) calculations. Two thermally activated reorientational motions were observed, around the 2-fold (C2) and 3-fold (C3) axes of the BH4− units, at temperature from 95 to 280K. The experimental energy barriers (EaC2 = 0.14 eV and EaC3 = 0...... of the interstitial H2 might come from the synthesis of the compound or a side reaction with trapped synthesis residue leading to the partial oxidation of the compound and hydrogen release....

  17. The Schottky energy barrier dependence of charge injection in organic light-emitting diodes

    Science.gov (United States)

    Campbell, I. H.; Davids, P. S.; Smith, D. L.; Barashkov, N. N.; Ferraris, J. P.

    1998-04-01

    We present device model calculations of the current-voltage (I-V) characteristics of organic diodes and compare them with measurements of structures fabricated using MEH-PPV. The structures are designed so that all of the current is injected from one contact. The I-V characteristics are considered as a function of the Schottky energy barrier to charge injection from the contact. Experimentally, the Schottky barrier is varied from essentially zero to more than 1 eV by using different metal contacts. A consistent description of the device I-V characteristics is obtained as the Schottky barrier is varied from small values, less than about 0.4 eV, where the current flow is space-charge limited to larger values where it is contact limited.

  18. Barriers and opportunities for labels for highly energy-efficient houses

    International Nuclear Information System (INIS)

    Mlecnik, Erwin; Visscher, Henk; Van Hal, Anke

    2010-01-01

    Promoting energy efficiency in the building sector is essential if the agreements of the Kyoto Protocol are to be honoured. Different initiatives for energy labelling of highly energy-efficient residential buildings have emerged throughout Europe as an essential method to stimulate market demand, to control grants or to ensure the quality of demonstration projects with excellent energy performance. The paper identifies the barriers and opportunities for the further diffusion of labels for highly energy-efficient houses. A model based on the theory of the diffusion of innovation is developed to analyse perceived attributes of existing European labels. The paper investigates the innovation characteristics of existing labels in Europe, with a focus on advanced countries. The question of compatibility with the development of the European Energy Performance of Buildings Directive (EPBD) is examined in detail. We found that the diffusion of emerging and already existing voluntary European labels for highly energy-efficient houses is needed. Their complexity can be lowered and relative advantage, trialability, observability, and compatibility can be increased. EPBD calculation procedures should be able to receive highly energy-efficient houses. In the framework of the recast of the EPBD, official recognition of existing voluntary labels is recommended. (author)

  19. Energy SMEs in sub-Saharan Africa: Outcomes, barriers and prospects in Ghana, Senegal, Tanzania and Zambia

    DEFF Research Database (Denmark)

    Haselip, James Arthur; Desgain, Denis DR; Mackenzie, Gordon A.

    a commercially viable energy SME sector, emphasising the lack of strong policy support from governments, poor business skills capacity and the high cost of many RETs as related cause-and-effect barriers. While these issues continue to characterise, to a greater or lesser extent, the energy SMEs sectors......; lack of clearly defined markets; demand-side barriers to purchase relatively high capital-intense energy products. Where numerous energy SMEs are in operation and thus where a valid demonstration effect can be identified, there is a perceived paradox that serves to undermine commercial interest...... in investing in energy SMEs. The paradox is that the donor-supported businesses that were issued with concessional and/or flexible loans serve to demonstrate that these businesses depend upon such concessional terms, i.e., that they could not survive in ‘the real world’. While this assumption is widely...

  20. Implementation of renewable energy technology - Opportunities and barriers. Summary of country studies

    Energy Technology Data Exchange (ETDEWEB)

    Painuly, J.P.; Fenhann, J.V.

    2002-07-01

    The project was launched to identify barriers to the implementation of renewable energy technologies (RETs) and explore measures to overcome the identified barriers. National institutions in Egypt, Ghana and Zimbabwe carried out the country studies based on the basic methodological framework provided by the UNEP Centre. The objectives of the project included strengthening institutional capacity for analysis and implementation of RET projects in the participating countries and bring out experiences on RETs barriers and removal measures for dissemination so that others can benefit from the knowledge so gained. An important highlight of the studies was involvement of stake holders in the process of identification of barriers and measures to remove them. A preliminary identification of relevant RETs for their countries was done by the country teams in the initial stage of the project. After that, national workshops involving various stake holders were held between July and September 1999 to discuss the RETs and barriers to their implementation. Based on the discussions, a few important RETs were identified for more detailed study. PV systems for rural electrification, solar water heating systems and large-scale biogas system were identified and analysed for barriers in the Egypt country study. Economic, information and policy barriers were identified as major barriers for these technologies. Solar water pumps, biogas and small hydro were the focus of study in Ghana. In this case also, economic, information and policy barriers were found to be the important barriers for the selected technologies. In the case of Zimbabwe, focus was on identification of primary and secondary barriers to RETs dissemination. The primary barriers included lack of capacity to develop proposals, lack of information for policy making and framework for information dissemination. The study concluded that the secondary barriers as seen and experienced by the stake holders are due to primary

  1. Transportation Energy Futures Series. Non-Cost Barriers to Consumer Adoption of New Light-Duty Vehicle Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Stephens, Thomas [Argonne National Lab. (ANL), Argonne, IL (United States)

    2013-03-01

    Consumer preferences are key to the adoption of new vehicle technologies. Barriers to consumer adoption include price and other obstacles, such as limited driving range and charging infrastructure; unfamiliarity with the technology and uncertainty about direct benefits; limited makes and models with the technology; reputation or perception of the technology; standardization issues; and regulations. For each of these non-cost barriers, this report estimates an effective cost and summarizes underlying influences on consumer preferences, approximate magnitude and relative severity, and assesses potential actions, based on a comprehensive literature review. While the report concludes that non-cost barriers are significant, effective cost and potential market share are very uncertain. Policies and programs including opportunities for drivers to test drive advanced vehicles, general public outreach and information programs, incentives for providing charging and fueling infrastructure, and development of technology standards were examined for their ability to address barriers, but little quantitative data exists on the effectiveness of these measures. This is one in a series of reports produced as a result of the Transportation Energy Futures project, a Department of Energy-sponsored multi-agency effort to pinpoint underexplored strategies for reducing GHGs and petroleum dependence related to transportation. View all reports on the TEF Web page, http://www.eere.energy.gov/analysis/transportationenergyfutures/index.html.

  2. Implementation of a Non-Metallic Barrier in an Electric Motor

    Science.gov (United States)

    M'Sadoques, George A. (Inventor); Carra, Michael R. (Inventor); Beringer, Durwood M. (Inventor)

    2013-01-01

    A motor for use in a volatile environment includes a rotor exposed to the volatile environment, electronics for rotating the rotor, an impervious ceramic barrier separating the electronics and the rotor, and a flexible seal for preventing the volatile environment from contacting the electronics and for minimizing vibratory and twisting loads upon the barrier to minimize damage to the barrier.

  3. Deuteron interaction with 124Sn nuclei at sub-barrier energies

    Directory of Open Access Journals (Sweden)

    Yu.N. Pavlenko

    2015-04-01

    Full Text Available The measurements of cross sections for deuteron elastic scattering and (d,p reaction on 124Sn nuclei have been performed with aim to study the features of sub-barrier deuteron interaction with heavy nuclei. Experimental data were obtained on the electrostatic Tandem accelerator EGP-10K of the Institute for Nuclear Research (Kyiv at the deuteron beam energies Ed = 4.0; 5.0 and 5.5 MeV. Cross sections of deuteron elastic scattering were calculated in approach where the deuteron interaction potential with heavy nuclei at sub-barrier energies has been constructed in the framework of single folding model using the complex dynamic polarization potential. It is shown that the account of finite deuteron size leads to the increasing the nuclear potential in outer region of interaction and significantly improves the description of the experimental data. The calculations of elastic scattering cross sections were performed without any variations of the nuclear potential parameters. The analysis of measured integral cross sections of the 124Sn(d,p reaction and calculated cross sections of deuteron breakup reaction 124Sn(d,pn124Sn shows the dominant contribution of the neutron transfer reaction in the processes of the formation of protons and elastic scattering cross sections.

  4. Energy Transition and Barriers on the Path to its Introduction

    Directory of Open Access Journals (Sweden)

    Tomislav Tkalec

    2015-12-01

    Full Text Available Energy transition is a concept originating from the necessity of solving environmental problems and conflicts in the energy sector. It originates from environmental tradition and advocates transition from environmentally and socially controversial sources of energy to renewables. That also means a shift from large centralized production units (mainly based on fossil and nuclear energy to smaller, dispersed ones. This decentralization process inherently leads to a democratization of the electricity sector, as large energy companies are losing their power and position in the energy policy arena, as more and more smaller actors emerge. However, when trying to change the electricity system, many obstacles arise – from the economics, old energy paradigm, path dependence, inertia of electricity system, power relations between actors, institutional lock-in, to perceptions and values of the dominant players. All barriers are reflected in the energy policy arena, dominated mainly by large energy companies, reluctant to accept changes. Demands for a change come from non-dominant actors, mainly from civil society actors and others, who are pushed to the margins of the political arena. Therefore, decision-makers should recognize their role, change institutional structure of the energy policy arena, and open it to various actors that can add new qualities to decision-making processes and outputs.

  5. Alpha Channeling in Rotating Plasma with Stationary Waves

    International Nuclear Information System (INIS)

    Fetterman, A.; Fisch, N.J.

    2010-01-01

    An extension of the alpha channeling effect to supersonically rotating mirrors shows that the rotation itself can be driven using alpha particle energy. Alpha channeling uses radiofrequency waves to remove alpha particles collisionlessly at low energy. We show that stationary magnetic fields with high n θ can be used for this purpose, and simulations show that a large fraction of the alpha energy can be converted to rotation energy.

  6. Rotationally invariant correlation filtering

    International Nuclear Information System (INIS)

    Schils, G.F.; Sweeney, D.W.

    1985-01-01

    A method is presented for analyzing and designing optical correlation filters that have tailored rotational invariance properties. The concept of a correlation of an image with a rotation of itself is introduced. A unified theory of rotation-invariant filtering is then formulated. The unified approach describes matched filters (with no rotation invariance) and circular-harmonic filters (with full rotation invariance) as special cases. The continuum of intermediate cases is described in terms of a cyclic convolution operation over angle. The angular filtering approach allows an exact choice for the continuous trade-off between loss of the correlation energy (or specificity regarding the image) and the amount of rotational invariance desired

  7. High-energy extracorporeal shock-wave therapy for calcifying tendinitis of the rotator cuff: a randomised trial.

    Science.gov (United States)

    Albert, J-D; Meadeb, J; Guggenbuhl, P; Marin, F; Benkalfate, T; Thomazeau, H; Chalès, G

    2007-03-01

    In a prospective randomised trial of calcifying tendinitis of the rotator cuff, we compared the efficacy of dual treatment sessions delivering 2500 extracorporeal shock waves at either high- or low-energy, via an electromagnetic generator under fluoroscopic guidance. Patients were eligible for the study if they had more than a three-month history of calcifying tendinitis of the rotator cuff, with calcification measuring 10 mm or more in maximum dimension. The primary outcome measure was the change in the Constant and Murley Score. A total of 80 patients were enrolled (40 in each group), and were re-evaluated at a mean of 110 (41 to 255) days after treatment when the increase in Constant and Murley score was significantly greater (t-test, p = 0.026) in the high-energy treatment group than in the low-energy group. The improvement from the baseline level was significant in the high-energy group, with a mean gain of 12.5 (-20.7 to 47.5) points (p energy group. Total or subtotal resorption of the calcification occurred in six patients (15%) in the high-energy group and in two patients (5%) in the low-energy group. High-energy shock-wave therapy significantly improves symptoms in refractory calcifying tendinitis of the shoulder after three months of follow-up, but the calcific deposit remains unchanged in size in the majority of patients.

  8. Energy consumption and CO2 emissions of industrial process technologies. Saving potentials, barriers and instruments

    International Nuclear Information System (INIS)

    Fleiter, Tobias; Schlomann, Barbara; Eichhammer, Wolfgang

    2013-01-01

    Which contribution can the increase of energy efficiency achieve in the industry energy for the energy transition in Germany? To answer this question a model-based analysis of existing energy efficiency potentials of the energy-intensive industries is performed, which account for about 70% of the total energy demand of the industry. Based on this industry for each sector are instruments proposed for the implementation of the calculated potential and to overcome the existing barriers. [de

  9. Fusion barriers in heavy ion collisions

    International Nuclear Information System (INIS)

    Zhu Long; Su Jun; Xie Wenjie; Guo Chenchen; Zhang Donghong; Zhang Fengshou

    2014-01-01

    Study of fusion barrier is very important for people to better understand fusion reactions. In this paper the Improved Isospin-dependent Quantum Molecular Dynamics (ImIQMD) model is introduced firstly. Then the shell correction effects, energy dependence, isospin effects and orientation effects of fusion barrier are studied. The fusion barriers for the fusion reactions "4"0Ca + "4"0Ca, "4"8Ca + "2"0"8Pb, "4"8Ca + "2"0"4Pb and "1"6O + "1"5"4Sm are extracted. The negative shell correction energies lower potential barriers of a certain reaction. A complex phenomenon of energy dependence is observed. It is also found that incident energy dependence of the barrier radius and barrier height shows opposite behaviors. The Coulomb potential shows weak energy dependence when distance of two colliding nuclei is lower than the touching distance. The isospin effects of the potential barrier are investigated. The orientation effects of the potential barrier are also discussed for the system "1"6O + "1"5"4Sm. (authors)

  10. Solid state {sup 1}H spin-lattice relaxation and isolated-molecule and cluster electronic structure calculations in organic molecular solids: The relationship between structure and methyl group and t-butyl group rotation

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xianlong, E-mail: WangXianlong@uestc.edu.cn, E-mail: pbeckman@brynmawr.edu [Key Laboratory for NeuroInformation of Ministry of Education, School of Life Science and Technology, University of Electronic Science and Technology of China, 4 North Jianshe Rd., 2nd Section, Chengdu 610054 (China); Mallory, Frank B. [Department of Chemistry, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, Pennsylvania 19010-2899 (United States); Mallory, Clelia W. [Department of Chemistry, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, Pennsylvania 19010-2899 (United States); Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323 (United States); Odhner, Hosanna R.; Beckmann, Peter A., E-mail: WangXianlong@uestc.edu.cn, E-mail: pbeckman@brynmawr.edu [Department of Physics, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, Pennsylvania 19010-2899 (United States)

    2014-05-21

    We report ab initio density functional theory electronic structure calculations of rotational barriers for t-butyl groups and their constituent methyl groups both in the isolated molecules and in central molecules in clusters built from the X-ray structure in four t-butyl aromatic compounds. The X-ray structures have been reported previously. We also report and interpret the temperature dependence of the solid state {sup 1}H nuclear magnetic resonance spin-lattice relaxation rate at 8.50, 22.5, and 53.0 MHz in one of the four compounds. Such experiments for the other three have been reported previously. We compare the computed barriers for methyl group and t-butyl group rotation in a central target molecule in the cluster with the activation energies determined from fitting the {sup 1}H NMR spin-lattice relaxation data. We formulate a dynamical model for the superposition of t-butyl group rotation and the rotation of the t-butyl group's constituent methyl groups. The four compounds are 2,7-di-t-butylpyrene, 1,4-di-t-butylbenzene, 2,6-di-t-butylnaphthalene, and 3-t-butylchrysene. We comment on the unusual ground state orientation of the t-butyl groups in the crystal of the pyrene and we comment on the unusually high rotational barrier of these t-butyl groups.

  11. Driven diffusion against electrostatic or effective energy barrier across α-hemolysin

    Energy Technology Data Exchange (ETDEWEB)

    Ansalone, Patrizio [Istituto Nazionale di Ricerca Metrologica, Strada delle Cacce 91, Torino, IT-10135 (Italy); Chinappi, Mauro [Center for Life Nano Science@Sapienza, Istituto Italiano di Tecnologia, Via Regina Elena 291, 00161 Roma (Italy); Rondoni, Lamberto [Scienze Matematiche, Politecnico di Torino Corso Duca degli Abruzzi 24, Torino, IT-10129, Italy and INFN, Sez. di Torino, Via P. Giuria 1, Torino IT-10125 (Italy); Cecconi, Fabio, E-mail: fabio.cecconi@roma1.infn.it [CNR-Istituto dei Sistemi Complessi UoS “Sapienza,” Via dei Taurini 19, 00185 Roma (Italy)

    2015-10-21

    We analyze the translocation of a charged particle across an α-Hemolysin (αHL) pore in the framework of a driven diffusion over an extended energy barrier generated by the electrical charges of the αHL. A one-dimensional electrostatic potential is extracted from the full 3D solution of the Poisson’s equation. We characterize the particle transport under the action of a constant forcing by studying the statistics of the translocation time. We derive an analytical expression of translocation time average that compares well with the results from Brownian dynamic simulations of driven particles over the electrostatic potential. Moreover, we show that the translocation time distributions can be perfectly described by a simple theory which replaces the true barrier by an equivalent structureless square barrier. Remarkably, our approach maintains its accuracy also for low-applied voltage regimes where the usual inverse-Gaussian approximation fails. Finally, we discuss how the comparison between the simulated time distributions and their theoretical prediction results to be greatly simplified when using the notion of the empirical Laplace transform technique.

  12. Energy barrier of bcc-fcc phase transition via the Bain path in Yukawa system

    Science.gov (United States)

    Kiyokawa, Shuji

    2018-05-01

    In the Yukawa system with the dimensionless screening parameter κ>1.5 , when bcc-fcc transition occurs via Bain path, we show that spontaneous transitions do not occur even if the system temperature reaches the transition point of bcc-fcc because it is necessary to increase once the free energy in the process of transition from bcc to fcc through Bain deformation. Here, we refer the temporary increment of the free energy during Bain deformation as Bain barrier. Since there are the Bain barriers at the transitions between bcc and fcc phases, these phases may coexist as metastable state in the wide region (not a coexistence line) of κ and the coupling constant Γ. We study the excess energy of the system and the free energy difference between bcc and fcc phases by the Monte Carlo method, where the simulation box is divided into a large number of elements with small volume and a particle in the box is restricted be placed in one of these elements. By this method, we can tabulate the values of the interparticle potential and can calculate the internal energy fast and precisely.

  13. Reaction channels of 6,7Li+28Si at near-barrier energies

    International Nuclear Information System (INIS)

    Pakou, A; Rusek, K; Nicolis, N G; Alamanos, N; Doukelis, G; Gillibert, A; Kalyva, G; Kokkoris, M; Lagoyannis, A; Musumarra, A; Papachristodoulou, C; Perdikakis, G; Pierroutsakou, D; Pollacco, E C; Spyrou, A; Zarkadas, Ch

    2005-01-01

    The production of α-particles in the reactions 6,7 Li+ 28 Si was studied as a means to disentangle the various reaction channels at near-barrier energies. The competition between compound and direct reactions was determined by using the shape of angular distributions and statistical model calculations. DWBA calculations were also performed to probe the various direct channels. It was found that, approaching barrier, transfer channels are the most dominant for both reactions. For 7 Li+ 28 Si d-transfer is one of the contributing channels without excluding t-transfer, while for 6 Li+ 28 Si, n-transfer and p-transfer have substantial contribution but without excluding d-transfer

  14. Energy transfer of excitons between quantum wells separated by a wide barrier

    International Nuclear Information System (INIS)

    Lyo, S. K.

    2000-01-01

    We present a microscopic theory of the excitonic Stokes and anti-Stokes energy-transfer mechanisms between two widely separated unequal quantum wells with a large energy mismatch (Δ) at low temperatures (T). Several important intrinsic energy-transfer mechanisms have been examined, including dipolar coupling, real and virtual photon-exchange coupling, and over-barrier ionization of the excitons via exciton-exciton Auger processes. The transfer rate is calculated as a function of T and the center-to-center distance d between the wells. The rates depend sensitively on T for plane-wave excitons. For localized excitons, the rates depend on T only through the T dependence of the exciton localization radius. For Stokes energy transfer, the dominant energy transfer occurs through a photon-exchange interaction, which enables the excitons from the higher-energy wells to decay into free electrons and holes in the lower-energy wells. The rate has a slow dependence on d, yielding reasonable agreement with recent data from GaAs/Al x Ga 1-x As quantum wells. The dipolar rate is about an order of magnitude smaller for large d (e.g., d=175Aa) with a stronger range dependence proportional to d -4 . However, the latter can be comparable to the radiative rate for small d (e.g., d≤80Aa). For anti-Stokes transfer through exchange-type (e.g., dipolar and photon-exchange) interactions, we show that thermal activation proportional to exp(-Δ/k B T) is essential for the transfer, contradicting a recent nonactivated result based on the Fo''rster-Dexter's spectral-overlap theory. Phonon-assisted transfer yields a negligibly small rate. On the other hand, energy transfer through over-barrier ionization of excitons via Auger processes yields a significantly larger nonactivated rate which is independent of d. The result is compared with recent data

  15. Barriers to energy efficiency improvement. Empirical evidence from small-and-medium-sized enterprises in China

    Energy Technology Data Exchange (ETDEWEB)

    Kostka, Genia; Moslener, Ulf; Andreas, Jan G.

    2012-07-01

    This paper analyzes barriers for energy efficiency investments for small-and medium-sized enterprises (SMEs) in China. Based on a survey of 480 SMEs in Zhejiang Province, this study assesses financial, informational, and organizational barriers for energy efficiency investments in the SME sector. The conventional view has been that the lack of appropriate financing mechanisms particularly hinders SMEs to adopt cost-effective energy efficiency measures. As such, closing the financing gap for SMEs is seen as a prerequisite in order to promote energy efficiency in the sector. The econometric estimates of this study, however, suggest that access to information is an important determinant of investment outcomes, while this is less clear with respect to financial and organizational factors. More than 40 percent of enterprises in the sample declared that that they are not aware of energy saving equipments or practices in their respective business area, indicating that there are high transaction costs for SMEs to gather, assess, and apply information about energy saving potentials and relevant technologies. One implication is that the Chinese government may assume an active role in fostering the dissemination of energy-efficiency related information in the SME sector. (orig.)

  16. Design and Numerical Analysis of a Novel Counter-Rotating Self-Adaptable Wave Energy Converter Based on CFD Technology

    Directory of Open Access Journals (Sweden)

    Chongfei Sun

    2018-03-01

    Full Text Available The lack of an efficient and reliable power supply is currently one of the bottlenecks restricting the practical application of unmanned ocean detectors. Wave energy is the most widely distributed ocean energy, with the obvious advantages of high energy density and predictability. In this paper, a novel wave energy converter (WEC for power supply of low-power unmanned ocean detectors is proposed, which is a small-scale counter-rotating self-adaptive point absorber-type WEC. The double-layer counter-rotating absorbers can achieve the torque balance of the whole device. Besides, the self-adaptation of the blade to the water flow can maintain a unidirectional continuous rotation of the single-layer absorber. The WEC has several advantages, including small occupied space, simple exchange process and convenient modular integration. It is expected to meet the power demand of low-power ocean detectors. Through modeling and CFD analysis, it was found that the power and efficiency characteristics of WEC are greatly influenced by the relative flow velocity, the blade angle of the absorber and the interaction between the upper and lower absorbers. A physical prototype of the WEC was made and some related experiments were conducted to verify the feasibility of WEC working principle and the reliability of CFD analysis.

  17. Relaxation processes in rotational motion

    International Nuclear Information System (INIS)

    Broglia, R.A.

    1986-01-01

    At few MeV above the yrast line the normally strong correlations among γ-ray energies in a rotational sequence become weaker. This observation can be interpreted as evidence for the damping of rotational motion in hot nuclei. It seems possible to relate the spreading width of the E2-rotational decay strength to the spread in frequency Δω 0 of rotational bands. The origin of these fluctuations is found in: (1) fluctuations in the occupation of special single-particle orbits which contribute a significant part of the total angular momentum; and (2) fluctuations in the moment of inertia induced by vibrations of the nuclear shape. Estimates of Δω 0 done making use of the hundred-odd known discrete rotational bands in the rare-earth region lead, for moderate spin and excitation energies (I ≅ 30 and U ≅ 3 to 4 MeV), to rotational spreading widths of the order of 60 to 160 keV in overall agreement with the data. 24 refs

  18. The Schottky energy barrier dependence of charge injection in organic light-emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, I.H.; Davids, P.S.; Smith, D.L. [Los Alamos National Laboratory, Los Alamos, New Mexico87545 (United States); Barashkov, N.N.; Ferraris, J.P. [The University of Texas at Dallas, Richardson, Texas75083 (United States)

    1998-04-01

    We present device model calculations of the current{endash}voltage (I{endash}V) characteristics of organic diodes and compare them with measurements of structures fabricated using MEH-PPV. The structures are designed so that all of the current is injected from one contact. The I{endash}V characteristics are considered as a function of the Schottky energy barrier to charge injection from the contact. Experimentally, the Schottky barrier is varied from essentially zero to more than 1 eV by using different metal contacts. A consistent description of the device I{endash}V characteristics is obtained as the Schottky barrier is varied from small values, less than about 0.4 eV, where the current flow is space-charge limited to larger values where it is contact limited. {copyright} {ital 1998 American Institute of Physics.}

  19. Effects of high- and low-energy radial shock waves therapy combined with physiotherapy in the treatment of rotator cuff tendinopathy: a retrospective study.

    Science.gov (United States)

    Su, Xiangzheng; Li, Zhongli; Liu, Zhengsheng; Shi, Teng; Xue, Chao

    2017-06-09

    The aim of this study was to investigate the efficacy of high- and low-energy radial shock waves combined with physiotherapy for rotator cuff tendinopathy patients. Data from rotator cuff tendinopathy patients received high- or low-energy radial shock waves combined with physiotherapy or physiotherapy alone were collected. The Constant and Murley score and visual analog scale score were collected to assess the effectiveness of treatment in three groups at 4, 8, 12, and 24 weeks. In total, 94 patients were involved for our retrospective study. All groups showed remarkable improvement in the visual analog scale and Constant and Murley score compared to baseline at 24 weeks. The high-energy radial shock waves group had more marked improvement in the Constant and Murley score compared to the physiotherapy group at 4 and 8 weeks and at 4 weeks when compared with low-energy group. Furthermore, high-energy radial shock waves group had superior results on the visual analog scale at 4, 8, and 12 weeks compared to low-energy and physiotherapy groups. This retrospective study supported the usage of high-energy radial shock waves as a supplementary therapy over physiotherapy alone for rotator cuff tendinopathy by relieving the symptoms rapidly and maintaining symptoms at a satisfactory level for 24 weeks. Implications for Rehabilitation High-energy radial shock waves can be a supplemental therapy to physiotherapy for rotator cuff tendinopathy. We recommend the usage of high-energy radial shock waves during the first 5 weeks, at an interval of 7 days, of physiotherapy treatment. High-energy radial shock waves treatment combined with physiotherapy can benefit rotator cuff tendinopathy by relieving symptoms rapidly and maintain these improvements at a satisfactory level for quite a long time.

  20. Stability and control of resistive wall modes in high beta, low rotation DIII-D plasmas

    International Nuclear Information System (INIS)

    Garofalo, A.M.; Jackson, G.L.; Haye, R.J. La; Okabayashi, M.; Reimerdes, H.; Strait, E.J.; Ferron, J.R.; Groebner, R.J.; In, Y.; Lanctot, M.J.; Matsunaga, G.; Navratil, G.A.; Solomon, W.M.; Takahashi, H.; Takechi, M.; Turnbull, A.D.

    2007-01-01

    Recent high-β DIII-D (Luxon J.L. 2002 Nucl. Fusion 42 64) experiments with the new capability of balanced neutral beam injection show that the resistive wall mode (RWM) remains stable when the plasma rotation is lowered to a fraction of a per cent of the Alfven frequency by reducing the injection of angular momentum in discharges with minimized magnetic field errors. Previous DIII-D experiments yielded a high plasma rotation threshold (of order a few per cent of the Alfven frequency) for RWM stabilization when resonant magnetic braking was applied to lower the plasma rotation. We propose that the previously observed rotation threshold can be explained as the entrance into a forbidden band of rotation that results from torque balance including the resonant field amplification by the stable RWM. Resonant braking can also occur naturally in a plasma subject to magnetic instabilities with a zero frequency component, such as edge localized modes. In DIII-D, robust RWM stabilization can be achieved using simultaneous feedback control of the two sets of non-axisymmetric coils. Slow feedback control of the external coils is used for dynamic error field correction; fast feedback control of the internal non-axisymmetric coils provides RWM stabilization during transient periods of low rotation. This method of active control of the n = 1 RWM has opened access to new regimes of high performance in DIII-D. Very high plasma pressure combined with elevated q min for high bootstrap current fraction, and internal transport barriers for high energy confinement, are sustained for almost 2 s, or 10 energy confinement times, suggesting a possible path to high fusion performance, steady-state tokamak scenarios

  1. Energy wood production in short rotation. Opportunities and problems in their implementation. An analysis involving expert interviews; Energieholzproduktion im Kurzumtrieb. Chancen und Probleme bei ihrer Umsetzung. Eine Analyse unter Einbeziehung von Experteninterviews

    Energy Technology Data Exchange (ETDEWEB)

    Wirkner, Ronny

    2010-12-01

    The thesis has to the content the latest stand and the possibilities of further development of wood energy production by short rotation coppice (SRC). After analyzing the development of this relatively new option of the management of fast growing tree species and their possibilities, the associated legal bases are being analyzed. In addition to related agricultural land, other options will be considered to establish land (forest, fallow land). Weaknesses in delimitation and promotion, especially at country level are discussed. There follows a detailed consideration of the economical and ecological contemplation of wood agricultural cultivation, as well as the basics of the management including the raw material supply. The analyzed results serve as a basis for running interviews with experts of the subject fast growing tree species. The results of the interviews show that SRC mainly as an opportunity for long-term wood energy supply and establishment of regional circuits is seen with emphasis on the agricultural sector, but in this context there are lots of deficits on side of the management technology, basic conditions and other establishment barriers that we are confront with. After overcoming the remaining start-up difficulties however the chances are good to expand the energy wood production in short rotation forestry in an economically viable, ecologically profitable and socially acceptable way and therewith contribute to the diversification of agricultural production and relief of multifunctional forest management. (orig.)

  2. A novel method of calculating the energy deposition curve of nanosecond pulsed surface dielectric barrier discharge

    International Nuclear Information System (INIS)

    He, Kun; Wang, Xinying; Lu, Jiayu; Cui, Quansheng; Pang, Lei; Di, Dongxu; Zhang, Qiaogen

    2015-01-01

    To obtain the energy deposition curve is very important in the fields to which nanosecond pulse dielectric barrier discharges (NPDBDs) are applied. It helps the understanding of the discharge physics and fast gas heating. In this paper, an equivalent circuit model, composed of three capacitances, is introduced and a method of calculating the energy deposition curve is proposed for a nanosecond pulse surface dielectric barrier discharge (NPSDBD) plasma actuator. The capacitance C d and the energy deposition curve E R are determined by mathematically proving that the mapping from C d to E R is bijective and numerically searching one C d that satisfies the requirement for E R to be a monotonically non-decreasing function. It is found that the value of capacitance C d varies with the amplitude of applied pulse voltage due to the change of discharge area and is dependent on the polarity of applied voltage. The bijectiveness of the mapping from C d to E R in nanosecond pulse volumetric dielectric barrier discharge (NPVDBD) is demonstrated and the feasibility of the application of the new method to NPVDBD is validated. This preliminarily shows a high possibility of developing a unified approach to calculate the energy deposition curve in NPDBD. (paper)

  3. Barriers to and drivers of the adpotion of energy crops by Swedish farmers: An empirical approach

    Energy Technology Data Exchange (ETDEWEB)

    Jonsson, Anna C.; Ostwald, Madelene; Asplund, Therese; Wibeck, Victoria (Linkoeping Univ., Linkoeping (Sweden). The Tema Inst., Centre for Climate Science and Policy Research)

    2011-06-15

    Since the Swedish government and the EU intend to encourage farmers to expand energy crop production, knowledge of the factors motivating adoption decisions is vital to policy success. Earlier studies have demonstrated that important barriers to farmer adoption of energy crops include converting from annual to perennial crops and from traditional crops or production systems to new ones. Economic motivations for changing production systems are strong, but factors such as values (e.g., aesthetics), knowledge (e.g., habits and knowledge of production methods), and legal conditions (e.g., cultivation licenses) are crucial for the change to energy crops. This paper helps fill gaps in the literature regarding why farmers decide to keep or change a production system. Based on a series of focus group interviews with Swedish farmers, the paper explores how farmers frame crop change decisions and what factors they consider most important. The main drivers of and barriers to growing energy crops, according to interviewees, are grouped and discussed in relation to four broad groups of motivational factors identified in the literature, i.e., values, legal conditions, knowledge, and economic factors. The paper ends by discussing whether some barriers could be overcome by policy changes at the national and European levels

  4. Innovative isothermal oil-free co-rotating scroll compressor–expander for energy storage with first expander tests

    International Nuclear Information System (INIS)

    Iglesias, A.; Favrat, D.

    2014-01-01

    Highlights: • Doing a new concept of small scale compressed air energy storage. • Presenting a new working process of scroll machinery. • Updating a thermodynamic model of scroll compressor that take into account water injection. • Updating a mathematical model of volumetric loses that take into account sealing effect of liquid water. • Encouraging results to investigate more deeply this new concept. - Abstract: The development of an efficient isothermal turbine and compressor is essential for the realization of a small-scale compressed air energy storage (CAES). This article presents the theoretical development of an oil-free co-rotating scroll air compressor and turbine working with water injection to make the operations of expansion and compression as isothermal as possible. First experimental results in expander mode are shown. The theoretical performance is predicted with the help of a mathematical model using the equations of energy and mass conservation and the equation of state. This model takes into account the effects of water injection and volumetric losses. The experimental prototype is an oil-free scroll air compressor with the distinctive feature of having two mobile involutes working in synchronized co-rotation one relative to another. The prime-mover is an electric motor driving the two scrolls with two synchronizing belts. Water injection in the housing intends to provide a quasi-isothermal compression. The same device is used as an isothermal expander by supplying high-pressure air with water when it rotates backwards in expander mode, the electric motor acting then as a generator. Expected improvements to a standard scroll compressor and expander are a better volumetric efficiency and a greater power density due to a higher rotational speed of the scrolls, thanks to their symmetrical masses. The isothermal processes increase also the overall performance

  5. Polymer in a pore: Effect of confinement on the free energy barrier

    Science.gov (United States)

    Kumar, Sanjiv; Kumar, Sanjay

    2018-06-01

    We investigate the transfer of a polymer chain from cis- side to trans- side through two types of pores: cone-shaped channel and flat-channel. Using the exact enumeration technique, we obtain the free energy landscapes of a polymer chain for such systems. We have also calculated the free-energy barrier of a polymer chain attached to the edge of the pore. The model system allows us to calculate the force required to pull polymer from the pore and stall-force to confine polymer within the pore.

  6. How does incomplete fusion show up at slightly above barrier energies?

    Directory of Open Access Journals (Sweden)

    Prasad R.

    2012-02-01

    Full Text Available Experimental results on the onset of incomplete fusion at slightly above barrier energies are discussed in this paper. Spin-distributions of evaporation residues populated via complete and/or incomplete fusion of 12C,16O (Elab ≈ 4–7 MeV with 169Tm have been measured to probe associated ℓ–values. Particle (Z=1,2 – γ – coincidence technique has been used for channel selection. Entirely different entry state spin populations have been observed during the de-excitation of complete and incomplete composites. The complete fusion residues are found to be strongly fed over a broad spin range. While, a narrow range feeding for only high spin states has been observed in case of incomplete fusion residues. In the present work, incomplete fusion is shown to be a promising tool to populate high spin states in final reaction products. For better insight into the onset and strength of incomplete fusion, the relative contributions of complete and incomplete fusion have been deduced from the analysis of excitation functions and forward recoil ranges. A significant fraction of ICF has been observed even at energy as low as ≈ 7% above the barrier. The relative strengths of complete and incomplete fusion deduced from the analysis of forward-recoil-ranges and excitation functions complement each other. All the available results are discussed in light of the Morgenstern’s mass-asymmetry systematics. Incomplete fusion fraction is found to be large for more mass-asymmetric systems for individual projectiles, which points towards the projectile structure effect on incomplete fusion fraction. Experimentally measured forward ranges of recoils complement the existence of incomplete fusion at slightly above barrier energies, where more than one linear-momentum-transfer components associated with full- and/or partial-fusion of projectile(s have been observed. Present results conclusively demonstrate the possibility to selectively populate high spin states

  7. Political rotations and cross-province acquisitions in China

    DEFF Research Database (Denmark)

    Muratova, Yulia; Arnoldi, Jakob; Chen, Xin

    2018-01-01

    The underdeveloped institutional framework and trade barriers between China’s provinces make cross-province acquisitions challenging. We explore how Chinese firms can mitigate this problem. Drawing on social network theory we propose that cross-province rotation of political leaders—a key element...... of the promotion system of political cadres in China—is a mechanism enabling growth through cross-province acquisitions. We conceptualize rotated leaders as brokers between two geographically dispersed networks. We contribute to the literature on the characteristics of Chinese social networks, the effect...... of political connections on firm strategy, and the impact of political rotations on firm growth in China’s provinces....

  8. Rotating shaft model updating from modal data by a direct energy approach : a feasibility study

    International Nuclear Information System (INIS)

    Audebert, S.

    1996-01-01

    Investigations to improve the rotating machinery monitoring tend more and more to use numerical models. The aim is to obtain multi-fluid bearing rotor models which are able to correctly represent their dynamic behaviour, either modal or forced response type. The possibility of extending the direct energy method, initially developed for undamped structures, to rotating machinery is studied. It is based on the minimization of the kinetic and strain energy gap between experimental and analytic modal data. The preliminary determination of a multi-linear bearing rotor system Eigen modes shows the problem complexity in comparison with undamped non rotating structures: taking into account gyroscopic effects and bearing damping, as factors of rotor velocities, leads to complex component Eigen modes; moreover, non symmetric matrices, related to stiffness and damping bearing contributions, induce distinct left and right-hand side Eigen modes (left hand side Eigenmodes corresponds to the adjoint structure). Theoretically, the extension of the energy method is studied, considering first the intermediate case of an undamped non gyroscopic structure, second the general case of a rotating shaft: dta used for updating procedure are Eigen frequencies and left- and right- hand side mode shapes. Since left hand side mode shapes cannot be directly measured, they are replaced by analytic ones. The method is tested on a two-bearing rotor system, with a mass added; simulated data are used, relative to a non compatible structure, i.e. which is not a part of the set of modified analytic possible structures. Parameters to be corrected are the mass density, the Young's modulus, and the stiffness and damping linearized characteristics of bearings. If parameters are influent in regard with modes to be updates, the updating method permits a significant improvement of the gap between analytic and experimental modes, even for modes not involves in the procedure. Modal damping appears to be more

  9. Capabilities of silicon Shottki barriers and planar detectors in low-energy proton spectometry

    Energy Technology Data Exchange (ETDEWEB)

    Verbitskaya, E M; Eremin, V K; Malyarenko, A M; Sakharov, V I; Serenkov, I T; Strokan, N B; Sukhanov, V L

    1987-05-12

    Dependence of the resolution of surface barrier and planar diffusion silicon detectors on proton energy is investigated. The experiment was conducted at the device, representing the double mass spectrometer with the maximal energy of single-charged ions up to 200 keV. Two advantages of using planar diffusion detectors for light low-energy ion spectrometry is established: high energy resolution and independence of signal amplitude of bias voltage. Background noise represents the main factor dictaiting resolution, but fluctuations of losses in input window are sufficient as well. It was concluded that planar detector application for spectrometry of protons with energy of less than 200 keV would improve the resolution up to 2.2 keV without detector cooling.

  10. Input-output analysis of energy requirements for short rotation, intensive culture, woody biomass

    International Nuclear Information System (INIS)

    Strauss, C.H.; Grado, S.C.

    1992-01-01

    A production model for short rotation, intensive culture (SRIC) plantations was developed to determine the energy and financial cost of woody biomass. The model was based on hybrid poplars planted on good quality agricultural sites at a density of 2100 cuttings ha -1 , with average annual growth forecast at 16 metric tonne, oven dry (mg(OD)). Energy and financial analyses showed preharvest cost 4381 megajoules (MJ) Mg -1 (OD) and $16 (US) Mg -1 (OD). Harvesting and transportation requirements increased the total costs 6130 MJ Mg -1 (OD) and $39 Mg -1 (OD) for the delivered material. On an energy cost basis, the principal input was land, whereas on a financial basis, costs were more uniformly distributed among equipment, land, labor, and materials and fuel

  11. From static to rotating to conformal static solutions: rotating imperfect fluid wormholes with(out) electric or magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Azreg-Ainou, Mustapha [Baskent University, Department of Mathematics, Ankara (Turkey)

    2014-05-15

    We derive a shortcut stationary metric formula for generating imperfect fluid rotating solutions, in Boyer-Lindquist coordinates, from spherically symmetric static ones. We explore the properties of the curvature scalar and stress-energy tensor for all types of rotating regular solutions we can generate without restricting ourselves to specific examples of regular solutions (regular black holes or wormholes). We show through examples how it is generally possible to generate an imperfect fluid regular rotating solution via radial coordinate transformations. We derive rotating wormholes that are modeled as imperfect fluids and discuss their physical properties. These are independent on the way the stress-energy tensor is interpreted. A solution modeling an imperfect fluid rotating loop black hole is briefly discussed. We then specialize to the recently discussed stable exotic dust Ellis wormhole as emerged in a source-free radial electric or magnetic field, and we generate its, conjecturally stable, rotating counterpart. This turns out to be an exotic imperfect fluid wormhole, and we determine the stress-energy tensor of both the imperfect fluid and the electric or magnetic field. (orig.)

  12. From static to rotating to conformal static solutions: rotating imperfect fluid wormholes with(out) electric or magnetic field

    International Nuclear Information System (INIS)

    Azreg-Ainou, Mustapha

    2014-01-01

    We derive a shortcut stationary metric formula for generating imperfect fluid rotating solutions, in Boyer-Lindquist coordinates, from spherically symmetric static ones. We explore the properties of the curvature scalar and stress-energy tensor for all types of rotating regular solutions we can generate without restricting ourselves to specific examples of regular solutions (regular black holes or wormholes). We show through examples how it is generally possible to generate an imperfect fluid regular rotating solution via radial coordinate transformations. We derive rotating wormholes that are modeled as imperfect fluids and discuss their physical properties. These are independent on the way the stress-energy tensor is interpreted. A solution modeling an imperfect fluid rotating loop black hole is briefly discussed. We then specialize to the recently discussed stable exotic dust Ellis wormhole as emerged in a source-free radial electric or magnetic field, and we generate its, conjecturally stable, rotating counterpart. This turns out to be an exotic imperfect fluid wormhole, and we determine the stress-energy tensor of both the imperfect fluid and the electric or magnetic field. (orig.)

  13. Targeted energy transfer in laminar vortex-induced vibration of a sprung cylinder with a nonlinear dissipative rotator

    Science.gov (United States)

    Blanchard, Antoine; Bergman, Lawrence A.; Vakakis, Alexander F.

    2017-07-01

    We computationally investigate the dynamics of a linearly-sprung circular cylinder immersed in an incompressible flow and undergoing transverse vortex-induced vibration (VIV), to which is attached a rotational nonlinear energy sink (NES) consisting of a mass that freely rotates at constant radius about the cylinder axis, and whose motion is restrained by a rotational linear viscous damper. The inertial coupling between the rotational motion of the attached mass and the rectilinear motion of the cylinder is ;essentially nonlinear;, which, in conjunction with dissipation, allows for one-way, nearly irreversible targeted energy transfer (TET) from the oscillating cylinder to the nonlinear dissipative attachment. At the intermediate Reynolds number Re = 100, the NES-equipped sprung cylinder undergoes repetitive cycles of slowly decaying oscillations punctuated by intervals of chaotic instabilities. During the slowly decaying portion of each cycle, the dynamics of the cylinder is regular and, for large enough values of the ratio ε of the NES mass to the total mass (i.e., NES mass plus cylinder mass), can lead to significant vortex street elongation with partial stabilization of the wake. As ε approaches zero, no such vortex elongation is observed and the wake patterns appear similar to that for a sprung cylinder with no NES. We apply proper orthogonal decomposition (POD) to the velocity flow field during a slowly decaying portion of the solution and show that, in situations where vortex elongation occurs, the NES, though not in direct contact with the surrounding fluid, has a drastic effect on the underlying flow structures, imparting significant and continuous passive redistribution of energy among POD modes. We construct a POD-based reduced-order model for the lift coefficient to characterize energy transactions between the fluid and the cylinder throughout the slowly decaying cycle. We introduce a quantitative signed measure of the work done by the fluid on the

  14. Bursting and large-scale intermittency in turbulent convection with differential rotation

    International Nuclear Information System (INIS)

    Garcia, O.E.; Bian, N.H.

    2003-01-01

    The tilting mechanism, which generates differential rotation in two-dimensional turbulent convection, is shown to produce relaxation oscillations in the mean flow energy integral and bursts in the global fluctuation level, akin to Lotka-Volterra oscillations. The basic reason for such behavior is the unidirectional and conservative transfer of kinetic energy from the fluctuating motions to the mean component of the flows, and its dissipation at large scales. Results from numerical simulations further demonstrate the intimate relation between these low-frequency modulations and the large-scale intermittency of convective turbulence, as manifested by exponential tails in single-point probability distribution functions. Moreover, the spatio-temporal evolution of convective structures illustrates the mechanism triggering avalanche events in the transport process. The latter involves the overlap of delocalized mixing regions when the barrier to transport, produced by the mean component of the flow, transiently disappears

  15. Reduction of the energy of secondary beams down to the Coulomb barrier

    International Nuclear Information System (INIS)

    Yang Yong Feng; Mittig, W.; Roussel-Chomaz, P.; Lewitowicz, M.; Sida, J.L.; Alamanos, N.; Auger, F.; Gillibert, A.; Volant, C.; Cabot, C.; Borcea, C.

    1993-01-01

    With the doubly achromatic spectrometer LISE at GANIL, the energy of a secondary 11 Be beam produced by the reaction of 63 MeV/nucleon 18 O with a 9 Be target has been reduced to Coulomb barrier energies using various thick targets and a thinner target plus a thick degrader. The experimental results were compared with calculations performed with the program INTENSITY and with simple analytical expressions. It was found that in the present device, the thick target method is more convenient and efficient than the achromatic degrader

  16. Determination of the barrier height for acetyl radical dissociation from acetyl chloride photodissociation at 235 nm using velocity map imaging.

    Science.gov (United States)

    Tang, Xiaonan; Ratliff, Britni J; FitzPatrick, Benjamin L; Butler, Laurie J

    2008-12-18

    This work uses velocity map imaging to determine the barrier height for acetyl radical, CH3CO, dissociation to CH3 + CO. Photodissociation of acetyl chloride at 235 nm generates acetyl radicals with an internal energy distribution spanning this barrier. We determine the velocity and internal energy distribution of all nascent acetyl radicals, stable and unstable, by measuring the velocities of the Cl(2P3/2) and Cl(2P1/2) cofragments. These Cl cofragments are detected with 2 + 1 resonance-enhanced multiphoton ionization (REMPI) in a spin-orbit branching ratio Cl(2P3/2):Cl(2P1/2) of 3.3 +/- 0.2. Using 157 nm photoionization, we then detect the recoil velocities of the energetically stable acetyl radicals. The radicals and momentum matched Cl atoms evidence parallel angular distributions. Comparison of the total recoil translational energy distribution P(E(T)) for all radicals to that obtained from the detection of stable radicals yields an onset for dissociation at a translational energy of 25.0 +/- 0.4 kcal/mol. From this onset we can calculate the barrier height for CH3CO --> CH3 + CO, but this relies on prior determinations of the C-Cl bond energy of acetyl chloride. Using an experimental bond dissociation energy of 83.4 +/- 0.2 kcal/mol yields a dissociation barrier of 14.2 +/- 0.5 kcal/mol. Our data evidence that a portion of the acetyl radicals formed with total internal energy above the barrier are stable due to the partitioning of energy into rotation during the C-Cl bond fission of the precursor. Thus, the internal energy onset for dissociation is not as sharp as was assumed in prior determinations of the barrier. The experimentally determined onset is compared with that predicted from electronic structure calculations at the G3//B3LYP and CCSD(T) levels of theory.

  17. Testing Convergence of Different Free-Energy Methods in a Simple Analytical System with Hidden Barriers

    Directory of Open Access Journals (Sweden)

    S. Alexis Paz

    2018-03-01

    Full Text Available In this work, we study the influence of hidden barriers on the convergence behavior of three free-energy calculation methods: well-tempered metadynamics (WTMD, adaptive-biasing forces (ABF, and on-the-fly parameterization (OTFP. We construct a simple two-dimensional potential-energy surfaces (PES that allows for an exact analytical result for the free-energy in any one-dimensional order parameter. Then we chose different CV definitions and PES parameters to create three different systems with increasing sampling challenges. We find that all three methods are not greatly affected by the hidden-barriers in the simplest case considered. The adaptive sampling methods show faster sampling while the auxiliary high-friction requirement of OTFP makes it slower for this case. However, a slight change in the CV definition has a strong impact in the ABF and WTMD performance, illustrating the importance of choosing suitable collective variables.

  18. Transportation Energy Futures Series: Non-Cost Barriers to Consumer Adoption of New Light-Duty Vehicle Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Stephens, T.

    2013-03-01

    Consumer preferences are key to the adoption of new vehicle technologies. Barriers to consumer adoption include price and other obstacles, such as limited driving range and charging infrastructure; unfamiliarity with the technology and uncertainty about direct benefits; limited makes and models with the technology; reputation or perception of the technology; standardization issues; and regulations. For each of these non-cost barriers, this report estimates an effective cost and summarizes underlying influences on consumer preferences, approximate magnitude and relative severity, and assesses potential actions, based on a comprehensive literature review. While the report concludes that non-cost barriers are significant, effective cost and potential market share are very uncertain. Policies and programs including opportunities for drivers to test drive advanced vehicles, general public outreach and information programs, incentives for providing charging and fueling infrastructure, and development of technology standards were examined for their ability to address barriers, but little quantitative data exists on the effectiveness of these measures. This is one in a series of reports produced as a result of the Transportation Energy Futures project, a Department of Energy-sponsored multi-agency effort to pinpoint underexplored strategies for reducing GHGs and petroleum dependence related to transportation.

  19. Fusion enhancement at near and sub-barrier energies in {sup 19}O + {sup 12}C

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Varinderjit; Vadas, J.; Steinbach, T.K.; Wiggins, B.B.; Hudan, S. [Department of Chemistry and Center for Exploration of Energy and Matter, Indiana University, 2401 Milo B. Sampson Lane, Bloomington, IN 47408 (United States); Souza, R.T. de, E-mail: deSouza@indiana.edu [Department of Chemistry and Center for Exploration of Energy and Matter, Indiana University, 2401 Milo B. Sampson Lane, Bloomington, IN 47408 (United States); Lin, Zidu; Horowitz, C.J. [Department of Physics and Center for Exploration of Energy and Matter, Indiana University, 2401 Milo B. Sampson Lane, Bloomington, IN 47408 (United States); Baby, L.T.; Kuvin, S.A.; Tripathi, Vandana; Wiedenhöver, I. [Department of Physics, Florida State University, Tallahassee, FL 32306 (United States); Umar, A.S. [Department of Physics and Astronomy, Vanderbilt University, Nashville, TN 37235 (United States)

    2017-02-10

    Measuring the fusion excitation function for an isotopic chain of projectile nuclei provides a stringent test of a microscopic description of fusion. We report the first measurement of the fusion excitation function at near-barrier energies for the {sup 19}O + {sup 12}C system. The measured excitation function is compared with the fusion excitation function of {sup 18}O + {sup 12}C. A significant enhancement in the fusion probability of {sup 19}O ions with a {sup 12}C target as compared to {sup 18}O ions is observed. The experimental cross-sections observed at near-barrier energies are compared with a state-of-the-art microscopic model.

  20. Effects of zonal flows on correlation between energy balance and energy conservation associated with nonlinear nonviscous atmospheric dynamics in a thin rotating spherical shell

    Science.gov (United States)

    Ibragimov, Ranis N.

    2018-03-01

    The nonlinear Euler equations are used to model two-dimensional atmosphere dynamics in a thin rotating spherical shell. The energy balance is deduced on the basis of two classes of functorially independent invariant solutions associated with the model. It it shown that the energy balance is exactly the conservation law for one class of the solutions whereas the second class of invariant solutions provides and asymptotic convergence of the energy balance to the conservation law.

  1. Energy SMEs in sub-Saharan Africa: Outcomes, barriers and prospects in Ghana, Senegal, Tanzania and Zambia

    Energy Technology Data Exchange (ETDEWEB)

    Haselip, J. A.; Desgain, D.; Mackenzie, G. A.

    2013-05-15

    This report presents the findings of research into the main outcomes of government and donor-backed efforts to promote small and medium-sized energy businesses (energy SMEs) in sub-Saharan Africa. The research follows an outcome analysis methodology. The focus is on four countries: Ghana, Senegal, Tanzania and Zambia and primarily on UNEP's AREED programme (2002-2012). This research focuses on the 'contributing factors' - a deliberately broader term that incorporates the internal 'success factors' - for energy SMEs, about which much has already been written. Indeed, the research findings presented in this report reaffirm most of what has been concluded in previous studies. These studies identified the lack of access to affordable finance as being the predominant, persistent, barrier to establishing and scaling up a commercially viable energy SME sector, emphasising the lack of strong policy support from governments, poor business skills capacity and the high cost of many RETs as related cause-and-effect barriers. While these issues continue to characterise, to a greater or lesser extent, the energy SMEs sectors in the countries studied for this research, it is more relevant to revisit the main assumption behind AREED and other donor-backed programmes designed to promote energy SMEs. The assumption is that the solution to the aforementioned barriers would be overcome by a 'demonstration effect' whereby successful energy SMEs, supported by donor-backed programmes, influence the commercial financial sector to invest in energy SMEs, thus triggering a virtuous circle of growth and profitability. Experiences drawn from a decade of AREED support across four of the project countries reveal both the presence (Ghana, Senegal) and absence, or weak presence, of this demonstration effect (Tanzania, Zambia). This is a central question, and one which was not the focus of previous research, presumably because the answer was not fully apparent prior to 2006 when the last

  2. Advanced transport modeling of toroidal plasmas with transport barriers

    International Nuclear Information System (INIS)

    Fukuyama, A.; Murakami, S.; Honda, M.; Izumi, Y.; Yagi, M.; Nakajima, N.; Nakamura, Y.; Ozeki, T.

    2005-01-01

    Transport modeling of toroidal plasmas is one of the most important issue to predict time evolution of burning plasmas and to develop control schemes in reactor plasmas. In order to describe the plasma rotation and rapid transition self-consistently, we have developed an advanced scheme of transport modeling based on dynamical transport equation and applied it to the analysis of transport barrier formation. First we propose a new transport model and examine its behavior by the use of conventional diffusive transport equation. This model includes the electrostatic toroidal ITG mode and the electromagnetic ballooning mode and successfully describes the formation of internal transport barriers. Then the dynamical transport equation is introduced to describe the plasma rotation and the radial electric field self-consistently. The formation of edge transport barriers is systematically studied and compared with experimental observations. The possibility of kinetic transport modeling in velocity space is also examined. Finally the modular structure of integrated modeling code for tokamaks and helical systems is discussed. (author)

  3. INFALLING–ROTATING MOTION AND ASSOCIATED CHEMICAL CHANGE IN THE ENVELOPE OF IRAS 16293–2422 SOURCE A STUDIED WITH ALMA

    Energy Technology Data Exchange (ETDEWEB)

    Oya, Yoko; López-Sepulcre, Ana; Watanabe, Yoshimasa; Yamamoto, Satoshi [Department of Physics, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Sakai, Nami [The Institute of Physical and Chemical Research (RIKEN), Wako, Saitama 351-0198 (Japan); Ceccarelli, Cecilia; Lefloch, Bertrand; Favre, Cécile, E-mail: oya@taurus.phys.s.u-tokyo.ac.jp [Université Grenoble Alpes, IPAG, F-38000 Grenoble (France)

    2016-06-20

    We have analyzed rotational spectral line emission of OCS, CH{sub 3}OH, HCOOCH{sub 3}, and H{sub 2}CS observed toward the low-mass Class 0 protostellar source IRAS 16293–2422 Source A at a sub-arcsecond resolution (∼0.″6 × 0.″5) with ALMA. Significant chemical differentiation is found on a scale of 50 au. The OCS line is found to trace well the infalling–rotating envelope in this source. On the other hand, the distributions of CH{sub 3}OH and HCOOCH{sub 3} are found to be concentrated around the inner part of the infalling–rotating envelope. With a simple ballistic model of the infalling–rotating envelope, the radius of the centrifugal barrier (a half of the centrifugal radius) and the protostellar mass are evaluated from the OCS data to be from 40 to 60 au and from 0.5 to 1.0 M {sub ⊙}, respectively, assuming the inclination angle of the envelope/disk structure to be 60° (90° for the edge-on configuration). Although the protostellar mass is correlated with the inclination angle, the radius of the centrifugal barrier is not. This is the first indication of the centrifugal barrier of the infalling–rotating envelope in a hot corino source. CH{sub 3}OH and HCOOCH{sub 3} may be liberated from ice mantles by weak accretion shocks around the centrifugal barrier and/or by protostellar heating. The H{sub 2}CS emission seems to come from the disk component inside the centrifugal barrier in addition to the envelope component. The centrifugal barrier plays a central role not only in the formation of a rotationally supported disk but also in the chemical evolution from the envelope to the protoplanetary disk.

  4. Probing Vitamine C, Aspirin and Paracetamol in the Gas Phase: High Resolution Rotational Studies

    Science.gov (United States)

    Mata, S.; Cabezas, C.; Varela, M.; Pena, I.; Nino, A.; López, J. C.; Alonso, J. L.; Grabow, J.-U.

    2011-06-01

    A solid sample of Vitamin C (m.p. 190°C) vaporized by laser ablation has been investigated in gas phase and characterized through their rotational spectra. Two spectroscopy techniques has been used to obtain the spectra: a new design of broadband chirped pulse Fourier transform microwave spectroscopy with in-phase/quadrature-phase-modulation passage-acquired-coherence technique (IMPACT) and conventional laser ablation molecular beam Fourier transform microwave spectroscopy (LA-MB-FTMW). Up to now, two low-energy conformer have been observed and their rotational constants determined. Ab initio calculations at the MP2/6-311++G (d,p) level of theory predicted rotational constants which helped us to identify these conformers unequivocally. Among the molecules to benefit from the LA-MB-FTMW technique there are common important drugs never observed in the gas phase through rotational spectroscopy. We present here the results on acetyl salicylic acid and acetaminophen (m.p. 136°C), commonly known as aspirin and paracetamol respectively. We have observed two stable conformers of aspirin and two for paracetamol. The internal rotation barrier of the methyl group in aspirin has been determined for both conformers from the analysis of the A-E splittings due to the coupling of internal and overall rotation. J. L. Alonso, C. Pérez, M. E. Sanz, J. C. López, S. Blanco, Phys. Chem. Chem. Phys. 11,617-627 (2009)and references therein

  5. Free and binary rotation of polyatomic molecules

    International Nuclear Information System (INIS)

    Konyukhov, V K

    2003-01-01

    A modification of the quantum-mechanical theory of rotation of polyatomic molecules (binary rotation) is proposed, which is based on the algebra and representations of the SO(4) group and allows the introduction of the concept of parity, as in atomic spectroscopy. It is shown that, if an asymmetric top molecule performing binary rotation finds itself in a spatially inhomogeneous electric field, its rotational levels acquire the additional energy due to the quadrupole moment. The existence of the rotational states of polyatomic molecules that cannot transfer to the free rotation state is predicted. In particular, the spin isomers of a water molecule, which corresponds to such states, can have different absolute values of the adsorption energy due to the quadrupole interaction of the molecule with a surface. The difference in the adsorption energies allows one to explain qualitatively the behaviour of the ortho- and para-molecules of water upon their adsorption on the surface of solids in accordance with experimental data. (laser applications and other topics in quantum electronics)

  6. Peak creation in the energy spectrum of laser-produced protons by phase rotation

    International Nuclear Information System (INIS)

    Noda, Akira; Nakamura, Shu; Iwashita, Yoshihisa; Shirai, Toshiyuki; Tongu, Hiromu; Ito, Hiroyuki; Souda, Hikaru; Yamazaki, Atsushi; Tanabe, Mikio; Daido, Hiroyuki; Mori, Michiaki; Kado, Masataka; Sagisaka, Akito; Ogura, Koichi; Nishiuchi, Mamiko; Orimo, Satoshi; Hayashi, Yukio; Yogo, Akifumi; Bulanov, Sergei; Esirkepov, Timur; Nagashima, Akira; Kimura, Toyoaki; Tajima, Toshiki; Fukumi, Atsushi; Li, Zhong

    2007-01-01

    In collaboration between JAEA, Kansai Photon Science Institute and Institute for Chemical Research, Kyoto University, proton generation from a thin foil target (Ti 3 or 5 μm in thickness) with use of 10 TW laser (JLITEX) has been performed. Proton production is optimized by real time proton energy measurement with use of TOF method. Phase rotation with use of an RF electric field phase-synchronized to the pulse laser enabled the creation of peaks with the spread of ∼7% in the energy spectrum of the produced protons, which resulted in the increase of the intensity ∼4 times at peak position. (author)

  7. Low Li+ Insertion Barrier Carbon for High Energy Efficient Lithium-Ion Capacitor.

    Science.gov (United States)

    Lee, Wee Siang Vincent; Huang, Xiaolei; Tan, Teck Leong; Xue, Jun Min

    2018-01-17

    Lithium-ion capacitor (LIC) is an attractive energy-storage device (ESD) that promises high energy density at moderate power density. However, the key challenge in its design is the low energy efficient negative electrode, which barred the realization of such research system in fulfilling the current ESD technological inadequacy due to its poor overall energy efficiency. Large voltage hysteresis is the main issue behind high energy density alloying/conversion-type materials, which reduces the electrode energy efficiency. Insertion-type material though averted in most research due to the low capacity remains to be highly favorable in commercial application due to its lower voltage hysteresis. To further reduce voltage hysteresis and increase capacity, amorphous carbon with wider interlayer spacing has been demonstrated in the simulation result to significantly reduce Li + insertion barrier. Hence, by employing such amorphous carbon, together with disordered carbon positive electrode, a high energy efficient LIC with round-trip energy efficiency of 84.3% with a maximum energy density of 133 Wh kg -1 at low power density of 210 W kg -1 can be achieved.

  8. SOLPLAN Report: An Assessment of Barriers and Incentives to Conservation and Alternative-Energy Use in the Residential Sector in Wisconsin

    Energy Technology Data Exchange (ETDEWEB)

    Fulenwider, Claire K.; Weiss, Lonnie S.; Pfefferkorn, Carol; Wiener, Don E.; Feldman, Stephen L.

    1981-03-01

    The Alternative Energy Policy Project of the Wisconsin Center for Public Policy focused upon two principle objectives: (1) gathering and analyzing new and previously unavailable data on barriers and incentives to greater energy conservation and alternative energy commercialization in the state of Wisconsin; and (2) building consensus around alternative energy policy to develop guidelines for alternative energy policy for the state. Particular attention was paid to public involvement in the policy process and to assessing barriers and incentives from as many key sectors of the energy field as possible. Thus, data were gathered from the general public, alternative energy users, the heating industry generally, the alternative-energy industry specifically, and key decision makers. The report is divided into four principal sections. The first looks at findings and analyses dealing with barriers to greater conservation and alternative energy use. Incentives for accelerating the extent of residential conservation and alternative energy use are discussed in the second section. The decision-making process itself in energy policy has been little analyzed and seldom documented. The role of consensus-building in the alternative-energy field and analysis of the decision-making process are discussed in Section III. Appendices in Section IV provide survey instruments and descriptions, a compendium of energy-related legislation developed within the project, and various reports. The total report reflects the interactive decision-making model as it was applied in SOLPLAN. (MCW)

  9. Further Study of Λ-Related Quantum Interference of Π-State Diatomic on Collision-Induced Rotational Energy Transfer

    International Nuclear Information System (INIS)

    Li Yongqing; Song Peng; Chen Yuehui; Wang Weili; Ma Fengcai

    2005-01-01

    In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys. Lett. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (A 1 Π, v = 3) with inert gases, which originates from the difference between the two Λ-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.

  10. Rotational dynamics of C60 in Na2RbC60

    International Nuclear Information System (INIS)

    Christides, C.; Prassides, K.; Neumann, D.A.; Copley, J.R.D.; Mizuki, J.; Tanigaki, K.; Hirosawa, I.; Ebbesen, T.W.

    1993-01-01

    We have measured the low-energy neutron inelastic-scattering (NIS) spectra of superconducting Na 2 RbC 60 in the temperature range 50-350 K. Well-defined librational peaks are observed at 50 K at 2.83(17) meV (FWHM = 1.7(5) meV). They soften and broaden with increasing temperature. Their behaviour mimics that found in solid C 60 and differs markedly from K 3 C 60 . The rotational barrier for C 60 reorientations in Na 2 RbC 60 is somewhat higher than in pristine C 60 and approximately half as large as in K 3 C 60 . An order-disorder transition is anticipated at a temperature higher than that found in C 60 . (orig.)

  11. Alpha Channeling in a Rotating Plasma

    International Nuclear Information System (INIS)

    Abraham J. Fetterman; Nathaniel J. Fisch

    2008-01-01

    The wave-particle α-channeling effect is generalized to include rotating plasma. Specifically, radio frequency waves can resonate with α particles in a mirror machine with E x B rotation to diffuse the α particles along constrained paths in phase space. Of major interest is that the α-particle energy, in addition to amplifying the RF waves, can directly enhance the rotation energy which in turn provides additional plasma confinement in centrifugal fusion reactors. An ancillary benefit is the rapid removal of alpha particles, which increases the fusion reactivity

  12. α Channeling in a Rotating Plasma

    International Nuclear Information System (INIS)

    Fetterman, Abraham J.; Fisch, Nathaniel J.

    2008-01-01

    The wave-particle α-channeling effect is generalized to include rotating plasma. Specifically, radio frequency waves can resonate with α particles in a mirror machine with ExB rotation to diffuse the α particles along constrained paths in phase space. Of major interest is that the α-particle energy, in addition to amplifying the rf waves, can directly enhance the rotation energy which in turn provides additional plasma confinement in centrifugal fusion reactors. An ancillary benefit is the rapid removal of alpha particles, which increases the fusion reactivity

  13. Performance enhancement of a rotational energy harvester utilizing wind-induced vibration of an inclined stay cable

    International Nuclear Information System (INIS)

    Kim, In-Ho; Jung, Hyung-Jo; Jang, Seon-Jun

    2013-01-01

    In this paper, an innovative strategy for improving the performance of a recently developed rotational energy harvester is proposed. Its performance can be considerably enhanced by replacing the electromagnetic induction part, consisting of moving permanent magnets and a fixed solenoid coil, with a moving mass and a rotational generator (i.e., an electric motor). The proposed system is easily tuned to the natural frequency of a target structure using the position change of a proof mass. Owing to the high efficiency of the rotational generator, the device can more effectively harness electrical energy from the wind-induced vibration of a stay cable. Also, this new configuration makes the device more compact and geometrically tunable. In order to validate the effectiveness of the new configuration, a series of laboratory and field tests are carried out with the prototype of the proposed device, which is designed and fabricated based on the dynamic characteristics of the vibration of a stay cable installed in an in-service cable-stayed bridge. From the field test, it is observed that the normalized output power of the proposed system is 35.67 mW (m s −2 ) −2 , while that of the original device is just 5.47 mW (m s −2 ) −2 . These results show that the proposed device generates much more electrical energy than the original device. Moreover, it is verified that the proposed device can generate sufficient electricity to power a wireless sensor node placed on a cable under gentle–moderate wind conditions. (paper)

  14. Liquid-drop model description of heavy ion fusion at sub-barrier energies

    Energy Technology Data Exchange (ETDEWEB)

    Aguiar, C E; Barbosa, V C; Canto, L F; Donangelo, R

    1987-10-05

    The enhancement of the heavy ion fusion cross section at sub-barrier energies is studied in the liquid-drop model approach. The shape of the system is described by two spheres smoothly connected by a neck, and the kinetic and potential energies are calculated within this parametrization. Underbarrier fusion cross sections for symmetric projectile-target combinations are calculated in the WKB approximation and a comparison with the available data is made. The agreement is quite satisfactory, except for those systems in which the reaction is strongly affected by the details of the nuclear structure of the collision partners.

  15. Analysis of Upper Bound Power Output for a Wrist-Worn Rotational Energy Harvester from Real-World Measured Inputs

    International Nuclear Information System (INIS)

    Xue, T; Roundy, S; Ma, X; Rahn, C

    2014-01-01

    Energy harvesting from human motion addresses the growing need for battery-free health and wellness sensors in wearable applications. The major obstacles to harvesting energy in such applications are low and random frequencies due to the nature of human motion. This paper presents a generalized rotational harvester model in 3 dimensions to determine the upper bound of power output from real world measured data. Simulation results indicate much space for improvement on power generation comparing to existing devices. We have developed a rotational energy harvester for human motion that attempts to close the gap between theoretical possibility and demonstrated devices. Like previous work, it makes use of magnetically plucked piezoelectric beams. However, it more fully utilizes the space available and has many degrees of freedom available for optimization. Finally we present a prototype harvester based on the coupled harvester model with preliminary experimental validation

  16. Rotational distributions of molecular photoions following resonant excitation

    International Nuclear Information System (INIS)

    Poliakoff, E.D.; Chan, J.C.K.; White, M.G.

    1986-01-01

    We demonstrate that the photoelectron energy mediates the rotational energy distribution of N + 2 ions created by photoionization, and conversely, that rotational energy determinations probe resonant excitation in molecular photoionization. Experimentally, this is accomplished by monitoring the dispersed fluorescence from N + 2 (B 2 Σ + /sub u/) photoions to determine their rotational energy distribution. These results demonstrate that while dipole selection rules constrain the total angular momentum of the electron--ion complex, the partitioning of angular momentum between the photoelectron and photoion depends on the photoejection dynamics. Implications for photoionization and electron impact ionizatin studies are discussed

  17. Potential and barrier study. Energy efficiency of Norwegian homes; Potensial- og barrierestudie. Energieffektivisering av norske boliger

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    Enova has identified potentials and barriers for energy efficiency in Norwegian buildings. This report summarizes the results of this work. Efficient energy in buildings is important to ensure that future economic activity and growth can occur in a way that reduces the possibilities for an environmentally and economically sound development. (eb)

  18. Maximum dose angle for oblique incidence on primary beam protective barriers in the design of medical radiation therapy facilities

    International Nuclear Information System (INIS)

    Fondevila, Damian; Arbiser, Silvio; Sansogne, Rosana; Brunetto, Monica; Dosoretz, Bernardo

    2008-01-01

    Primary barrier determinations for the shielding of medical radiation therapy facilities are generally made assuming normal beam incidence on the barrier, since this is geometrically the most unfavorable condition for that shielding barrier whenever the occupation line is allowed to run along the barrier. However, when the occupation line (for example, the wall of an adjacent building) runs perpendicular to the barrier (especially roof barrier), then two opposing factors come in to play: increasing obliquity angle with respect to the barrier increases the attenuation, while the distance to the calculation point decreases, hence, increasing the dose. As a result, there exists an angle (α max ) for which the equivalent dose results in a maximum, constituting the most unfavorable geometric condition for that shielding barrier. Based on the usual NCRP Report No. 151 model, this article presents a simple formula for obtaining α max , which is a function of the thickness of the barrier (t E ) and the equilibrium tenth-value layer (TVL e ) of the shielding material for the nominal energy of the beam. It can be seen that α max increases for increasing TVL e (hence, beam energy) and decreases for increasing t E , with a range of variation that goes from 13 to 40 deg for concrete barriers thicknesses in the range of 50-300 cm and most commercially available teletherapy machines. This parameter has not been calculated in the existing literature for radiotherapy facilities design and has practical applications, as in calculating the required unoccupied roof shielding for the protection of a nearby building located in the plane of the primary beam rotation

  19. Maximum dose angle for oblique incidence on primary beam protective barriers in the design of medical radiation therapy facilities.

    Science.gov (United States)

    Fondevila, Damián; Arbiser, Silvio; Sansogne, Rosana; Brunetto, Mónica; Dosoretz, Bernardo

    2008-05-01

    Primary barrier determinations for the shielding of medical radiation therapy facilities are generally made assuming normal beam incidence on the barrier, since this is geometrically the most unfavorable condition for that shielding barrier whenever the occupation line is allowed to run along the barrier. However, when the occupation line (for example, the wall of an adjacent building) runs perpendicular to the barrier (especially roof barrier), then two opposing factors come in to play: increasing obliquity angle with respect to the barrier increases the attenuation, while the distance to the calculation point decreases, hence, increasing the dose. As a result, there exists an angle (alpha(max)) for which the equivalent dose results in a maximum, constituting the most unfavorable geometric condition for that shielding barrier. Based on the usual NCRP Report No. 151 model, this article presents a simple formula for obtaining alpha(max), which is a function of the thickness of the barrier (t(E)) and the equilibrium tenth-value layer (TVL(e)) of the shielding material for the nominal energy of the beam. It can be seen that alpha(max) increases for increasing TVL(e) (hence, beam energy) and decreases for increasing t(E), with a range of variation that goes from 13 to 40 deg for concrete barriers thicknesses in the range of 50-300 cm and most commercially available teletherapy machines. This parameter has not been calculated in the existing literature for radiotherapy facilities design and has practical applications, as in calculating the required unoccupied roof shielding for the protection of a nearby building located in the plane of the primary beam rotation.

  20. Apparatus for sealing a rotatable shield plug in a liquid metal nuclear reactor

    International Nuclear Information System (INIS)

    Winkleblack, R.K.

    1980-01-01

    An apparatus for sealing a rotatable shield plug in a nuclear reactor having liquid metal coolant is described. The apparatus includes a dip -ring seal adapted to provide a fluid barrier between the liquid metal and the atmosphere and to permit rotation of the shield plug. The apparatus also includes a static seal for the rotatable shield plug located between the dip-ring seal and the liquid metal. The static seal isolates the dip-ring seal from the liquid metal vapor during operation at power and can be disengaged for rotation of the shield plug

  1. Measurement of Fission Fragment Angular Distributions for 14 N+ 232 Th and 11 B+ 235 U at Near-Barrier Energies

    International Nuclear Information System (INIS)

    Behera, B.R.; Jena, S.; Satapathy, M.; Ison, V.V.; Kailas, S.; Chatterjee, A.; Shrivastava, A.; Mahata, K.; Satpathy, L.; Basu, P.; Roy, S.; Sharan, M.; Chatterjee, M.L; Datta, S.K.

    2000-01-01

    Fission fragment angular distributions of heavy-ion induced fission in actinide nuclei at near-barrier energies show anomalous fragment anisotropies. At above barrier energies entrance channel dependence is a probable cause and explanation in terms of pre-equilibrium fission and the critical mass asymmetry parameter (Businaro-Gallone) has been tried. Target deformation and ground state spin also seem to influence the measured anisotropy. To understand the extent of importance of some or all of these features, we performed a set of experiments where (i) entrance channel dependence (ii) mass asymmetry on the two sides of Businaro-Gallone and (iii) different ground state spins are present. The channels chosen are 14 N+ 232 Th and 11 B+ 235 U. Experiments were done using the Pelletron accelerators at NSC, New Delhi and BARC-TIFR, Bombay. Compound nucleus populated in both cases is 246 Bk. 232 Th has ground state spin zero and 235 U has spin 7/2. Fragment anisotropies have been measured from 10-15 % above barrier to 10 % below barrier at similar excitation energy (around 40 MeV to 58 MeV). The mean square angular momentum is matched at least at one energy. Results indicate that when both excitation energy and angular momentum are matched, there are differences in the measured values of fission anisotropies. This implies entrance channel dependence consistent with the expectation of pre-equilibrium fission model. (authors)

  2. Validity of single term energy expression for ground state rotational band of even-even nuclei

    International Nuclear Information System (INIS)

    Sharma, S.; Kumar, R.; Gupta, J.B.

    2005-01-01

    Full text: There are large numbers of empirical studies of gs band of even-even nuclei in various mass regions. The Bohr-Mottelson's energy expression is E(I) = AX + BX 2 +CX 3 +... where X = I(I+1). The anharmonic vibrator energy expression is: E(I) = al + bl 2 + cl 3 SF model with energy expression: E(I)= pX + qI + rXI... where the terms represents the rotational, vibrational and R-V interaction energy, respectively. The validity f the various energy expressions with two terms had been tested by Sharma for light, medium and heavy mass regions using R I s. R 4 plots (where, spin I=6, 8, 10, 12), which are parameter independent. It was also noted, that of the goodness of energy expression can be judged with the minimum input of energies (i.e. only 2 parameters) and predictability's of the model p to high spins. Recently, Gupta et. al proposed a single term energy expression (SSTE) which was applied for rare earth region. This proposed power law reflected the unity of rotation - vibration in a different way and was successful in explaining the structure of gs-band. It will be useful for test the single term energy expression for light and heavy mass region. The single term expression for energy of ground state band can be written as: E I =axI b , where the index b and the coefficient a are the constant for the band. The values of b+1 and a 1 are as follows: b 1 =log(R 1 )/log(I/2) and a 1 =E I /I b ... The following results were gained: 1) The sharp variation in the value of index b at given spin will be an indication of the change in the shape of the nucleus; 2) The value of E I /I b is fairly constant with spin below back-bending, which reflects the stability of shape with spin; 3) This proposed power law is successful in explaining the structure of gs-band of nuclei

  3. Factors Affecting Energy Barriers for Pyramidal Inversion in Amines and Phosphines: A Computational Chemistry Lab Exercise

    Science.gov (United States)

    Montgomery, Craig D.

    2013-01-01

    An undergraduate exercise in computational chemistry that investigates the energy barrier for pyramidal inversion of amines and phosphines is presented. Semiempirical calculations (PM3) of the ground-state and transition-state energies for NR[superscript 1]R[superscript 2]R[superscript 3] and PR[superscript 1]R[superscript 2]R[superscript 3] allow…

  4. Poster - 11: Radiation barrier thickness calculations for the GammaPod

    International Nuclear Information System (INIS)

    La Russa, Daniel; Vandervoort, Eric; Wilkins, David

    2016-01-01

    A consortium of radiotherapy centers in North America is in the process of evaluating a novel new 60 Co teletherapy device, called the GammaPod™ (Xcision Medical Systems, Columbia Maryland), designed specifically for breast SBRT. The GammaPod consists of 36 collimated 60 Co sources with a total activity of 4320 Ci. The sources are housed in a hemispherical source carrier that rotates during treatment to produce a cylindrically symmetric cone of primary beam spanning 16° – 54° degrees from the horizontal. This unique beam geometry presents challenges when designing or evaluating room shielding for the purposes of meeting regulatory requirements, and for ensuring the safety of staff and the public in surrounding areas. Conventional methods for calculating radiation barrier thicknesses have been adapted so that barrier transmission factors for the GammaPod can be determined from a few relevant distances and characteristics of the primary beam. Simple formalisms have been determined for estimating shielding requirements for primary radiation (with a rotating and non-rotating source carrier), patient-scattered radiation, and leakage radiation. When making worst case assumptions, it was found that conventional barrier thicknesses associated with linac treatment suites are sufficient for shielding all sources of radiation from the GammaPod.

  5. Poster - 11: Radiation barrier thickness calculations for the GammaPod

    Energy Technology Data Exchange (ETDEWEB)

    La Russa, Daniel; Vandervoort, Eric; Wilkins, David [Radiation Medicine Program, The Ottawa Hospital (Canada)

    2016-08-15

    A consortium of radiotherapy centers in North America is in the process of evaluating a novel new {sup 60}Co teletherapy device, called the GammaPod™ (Xcision Medical Systems, Columbia Maryland), designed specifically for breast SBRT. The GammaPod consists of 36 collimated {sup 60}Co sources with a total activity of 4320 Ci. The sources are housed in a hemispherical source carrier that rotates during treatment to produce a cylindrically symmetric cone of primary beam spanning 16° – 54° degrees from the horizontal. This unique beam geometry presents challenges when designing or evaluating room shielding for the purposes of meeting regulatory requirements, and for ensuring the safety of staff and the public in surrounding areas. Conventional methods for calculating radiation barrier thicknesses have been adapted so that barrier transmission factors for the GammaPod can be determined from a few relevant distances and characteristics of the primary beam. Simple formalisms have been determined for estimating shielding requirements for primary radiation (with a rotating and non-rotating source carrier), patient-scattered radiation, and leakage radiation. When making worst case assumptions, it was found that conventional barrier thicknesses associated with linac treatment suites are sufficient for shielding all sources of radiation from the GammaPod.

  6. Thermodynamic properties of rotating trapped ideal Bose gases

    International Nuclear Information System (INIS)

    Li, Yushan; Gu, Qiang

    2014-01-01

    Ultracold atomic gases can be spined up either by confining them in rotating frame, or by introducing “synthetic” magnetic field. In this paper, thermodynamics of rotating ideal Bose gases are investigated within truncated-summation approach which keeps to take into account the discrete nature of energy levels, rather than to approximate the summation over single-particle energy levels by an integral as it does in semi-classical approximation. Our results show that Bose gases in rotating frame exhibit much stronger dependence on rotation frequency than those in “synthetic” magnetic field. Consequently, BEC can be more easily suppressed in rotating frame than in “synthetic” magnetic field.

  7. Origins and implications of temperature-dependent activation energy barriers for dislocation nucleation in face-centered cubic metals

    International Nuclear Information System (INIS)

    Warner, D.H.; Curtin, W.A.

    2009-01-01

    The linking of atomistic simulations of stress-driven processes to experimentally observed mechanical behavior via the computation of activation energy barriers is a topic of intense current research. Using dislocation nucleation from a crack tip as the reaction process, long-time multiscale molecular dynamics simulations show that the activation barrier can exhibit significant temperature dependence. Using an analytic model for the nucleation process and computing the relevant material properties (elastic constants and stacking fault energies), the temperature dependence is shown to arise primarily from the temperature dependence of the material parameters for both Al and Ni. After thermally activated emission of the first partial dislocation, there is then a competition between two other thermally activated processes: twinning and full dislocation emission. Because the activation barriers depend on temperature, this transition is more complex than usually envisioned. Simulations in Al reveal that a transition from twinning to full dislocation emission back to twinning occurs with increasing temperature, which is counter to traditional metallurgical wisdom. Temperature-dependent activation energies are thus essential to accurate understanding and prediction of those phenomena that control fracture and deformation in metals at realistic loading rates.

  8. Active control of internal transport barrier and confinement database in JT-60U reversed shear plasma

    Energy Technology Data Exchange (ETDEWEB)

    Sakamoto, Yoshiteru; Takizuka, Tomonori; Shirai, Hiroshi; Fujita, Takaaki; Kamada, Yutaka; Ide, Shunsuke; Fukuda, Takeshi; Koide, Yoshihiko [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment

    2001-07-01

    Active control of internal transport barrier (ITB) and confinement properties of plasma with ITB have been studied in reversed shear plasmas. Modifications of the radial electric field (E{sub r}) profile by changing the combination of tangential neutral beams can control the ITB strength, where the contribution to E{sub r} from the toroidal rotation plays an important role. The ITB confinement database of reversed shear plasmas has been constructed. Stored energy is strongly correlated with poloidal magnetic field at the ITB foot. (author)

  9. Production of internal transport barriers via self-generated mean flows in Alcator C-Mod

    Energy Technology Data Exchange (ETDEWEB)

    Fiore, C. L.; Ernst, D. R.; Podpaly, Y. A.; Howard, N. T.; Lee, Jungpyo; Reinke, M. L.; Rice, J. E.; Hughes, J. W.; Ma, Y. [MIT-PSFC, 77 Mass. Ave., Cambridge, Massachusetts 02139 (United States); Mikkelsen, D. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, New Jersey 08543-0451 (United States); Rowan, W. L.; Bespamyatnov, I. [FRC, U of Texas at Austin, Austin, Texas 78712 (United States)

    2012-05-15

    New results suggest that changes observed in the intrinsic toroidal rotation influence the internal transport barrier (ITB) formation in the Alcator C-Mod tokamak [E. S. Marmar and Alcator C-Mod group, Fusion Sci. Technol. 51, 261 (2007)]. These arise when the resonance for ion cyclotron range of frequencies (ICRF) minority heating is positioned off-axis at or outside of the plasma half-radius. These ITBs form in a reactor relevant regime, without particle or momentum injection, with Ti Almost-Equal-To Te, and with monotonic q profiles (q{sub min} < 1). C-Mod H-mode plasmas exhibit strong intrinsic co-current rotation that increases with increasing stored energy without external drive. When the resonance position is moved off-axis, the rotation decreases in the center of the plasma resulting in a radial toroidal rotation profile with a central well which deepens and moves farther off-axis when the ICRF resonance location reaches the plasma half-radius. This profile results in strong E Multiplication-Sign B shear (>1.5 Multiplication-Sign 10{sup 5} rad/s) in the region where the ITB foot is observed. Gyrokinetic analyses indicate that this spontaneous shearing rate is comparable to the linear ion temperature gradient (ITG) growth rate at the ITB location and is sufficient to reduce the turbulent particle and energy transport. New and detailed measurement of the ion temperature demonstrates that the radial profile flattens as the ICRF resonance position moves off axis, decreasing the drive for the ITG the instability as well. These results are the first evidence that intrinsic rotation can affect confinement in ITB plasmas.

  10. Tilting mode in rigidly rotating field-reversed configurations

    International Nuclear Information System (INIS)

    Clemente, R.A.; Milovich, J.L.

    1983-01-01

    The tilting-mode stability of field-reversed configurations is analyzed taking into account plasma rotational effects that had not been included in previous theoretical treatments. It is shown that for a rigidly rotating plasma in stationary equilibrium, stability can be attained if the plasma rotational energy is of the same order as the thermal energy. Since presently available values of the rotational velocities are quite lower than required by the stabilization mechanism considered here, the contribution of this effect to the overall stability of the mode does not appear to be significant

  11. Holographic stress-energy tensor near the Cauchy horizon inside a rotating black hole

    Science.gov (United States)

    Ishibashi, Akihiro; Maeda, Kengo; Mefford, Eric

    2017-07-01

    We investigate a stress-energy tensor for a conformal field theory (CFT) at strong coupling inside a small five-dimensional rotating Myers-Perry black hole with equal angular momenta by using the holographic method. As a gravitational dual, we perturbatively construct a black droplet solution by applying the "derivative expansion" method, generalizing the work of Haddad [Classical Quantum Gravity 29, 245001 (2012), 10.1088/0264-9381/29/24/245001] and analytically compute the holographic stress-energy tensor for our solution. We find that the stress-energy tensor is finite at both the future and past outer (event) horizons and that the energy density is negative just outside the event horizons due to the Hawking effect. Furthermore, we apply the holographic method to the question of quantum instability of the Cauchy horizon since, by construction, our black droplet solution also admits a Cauchy horizon inside. We analytically show that the null-null component of the holographic stress-energy tensor negatively diverges at the Cauchy horizon, suggesting that a singularity appears there, in favor of strong cosmic censorship.

  12. Tunnel superpenetrability of potential barriers

    International Nuclear Information System (INIS)

    Zakhariev, B N.

    1982-01-01

    The transmission of two particles through the same barrier is considered. The limiting cases are compared when the particles are joined together in a single particle with double mass-energy and potential and when they pass the barrier independently. As an intermediate case a pair of particles bound in a quasideuteron of a finite size is considered. It is shown that long-range collective correlations of particles (of the superfluidity type and others) simplify very much for them passing through high potential barriers. This happens due to the transfer of the additional energy from the particles outside the barriers to those inside it

  13. Molecular equilibrium structures from experimental rotational constants and calculated vibration-rotation interaction constants

    DEFF Research Database (Denmark)

    Pawlowski, F; Jorgensen, P; Olsen, Jeppe

    2002-01-01

    A detailed study is carried out of the accuracy of molecular equilibrium geometries obtained from least-squares fits involving experimental rotational constants B(0) and sums of ab initio vibration-rotation interaction constants alpha(r)(B). The vibration-rotation interaction constants have been...... calculated for 18 single-configuration dominated molecules containing hydrogen and first-row atoms at various standard levels of ab initio theory. Comparisons with the experimental data and tests for the internal consistency of the calculations show that the equilibrium structures generated using Hartree......-Fock vibration-rotation interaction constants have an accuracy similar to that obtained by a direct minimization of the CCSD(T) energy. The most accurate vibration-rotation interaction constants are those calculated at the CCSD(T)/cc-pVQZ level. The equilibrium bond distances determined from these interaction...

  14. Temperature dependence of the distribution of the thermally activated energy barriers in Tl2Ba2CaCu2O8 film

    International Nuclear Information System (INIS)

    Ren, C.; Lin, F.Y.; Ding, S.Y.; Li, Z.M.; Aruna, S.A.; Qiu, L.; Yao, X.X.; Yan, S.L.; Si, M.S.

    1999-01-01

    The effects of frequency and ac amplitude on ac susceptibility have been measured for a thin Tl 2 Ba 2 CaCu 2 O 8 film in the range 100 Hz-100 kHz in magnetic field 0.52 T. A phenomenological equation with an asymmetrical distribution of thermally activated energy barriers has been used to analyse these frequency and amplitude dependences of the ac susceptibility χ(ω,h ac ) in the vicinity of the peak temperature of χ''. We obtain the effective energy barrier U against amplitude h ac (current density j): U h ac -0.38 . This U(j) relationship shows that the flux lines are in the 3D collective creep regime. Therefore, we conclude that the effective energy barrier is in fact an average of the barrier's distribution, and the distribution function is a distinguished asymmetrical one in this 3D collective creep regime. (author)

  15. US-China Clean Energy Research Center on Building Energy Efficiency: Materials that Improve the Cost-Effectiveness of Air Barrier Systems

    Energy Technology Data Exchange (ETDEWEB)

    Hun, Diana E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-12-01

    The US–China Clean Energy Research Center (CERC) was launched in 2009 by US Energy Secretary Steven Chu, Chinese Minister of Science and Technology Wan Gang, and Chinese National Energy Agency Administrator Zhang Guobao. This 5-year collaboration emerged from the fact that the United States and China are the world’s largest energy producers, energy consumers, and greenhouse gas emitters, and that their joint effort could have significant positive repercussions worldwide. CERC’s main goal is to develop and deploy clean energy technologies that will help both countries meet energy and climate challenges. Three consortia were established to address the most pressing energy-related research areas: Advanced Coal Technology, Clean Vehicles, and Building Energy Efficiency (BEE). The project discussed in this report was part of the CERC-BEE consortia; its objective was to lower energy use in buildings by developing and evaluating technologies that improve the cost-effectiveness of air barrier systems for building envelopes.

  16. Biomass energy in organic farming - the potential role of short rotation coppice

    Energy Technology Data Exchange (ETDEWEB)

    Joergensen, Uffe; Dalgaard, Tommy [Danish Inst. of Agricultural Sciences (DIAS), Dept. of Agroecology, Research Centre Foulum, Tjele (Denmark); Kristensen, Erik Steen [Danish Research Centre for Organic Farming (DARCOF), Research Centre Foulum, Tjele (Denmark)

    2005-02-01

    One of the aims of organic farming is to 'reduce the use of non-renewable resources (e.g. fossil fuels) to a minimum'. So far, however, only very little progress has been made to introduce renewable energy in organic farming. This paper presents energy balances of Danish organic farming compared with energy balances of conventional farming. In general, the conversion to organic farming leads to a lower energy use (approximately 10% per unit of product). But the production of energy in organic farming is very low compared with the extensive utilisation of straw from conventional farming in Denmark (energy content of straw used for energy production was equivalent to 18% of total energy input in Danish agriculture in 1996). Biomass is a key energy carrier with a good potential for on-farm development. Apart from utilising farm manure and crop residues for biogas production, the production of nutrient efficient short rotation coppice (SRC) is an option in organic farming. Alder (Alnus spp.) is an interesting crop due to its symbiosis with the actinomycete Frankia, which has the ability to fix up to 185 kg/ha nitrogen (N{sub 2}) from the air. Yields obtained at different European sites are presented and the R and D needed to implement energy cropping in organic farming is discussed. Possible win-win solutions for SRC production in organic farming that may facilitate its implementation are; the protection of ground water quality in intensively farmed areas, utilisation of wastewater for irrigation, or combination with outdoor animal husbandry such as pigs or poultry. (Author)

  17. Barriers and drivers for energy efficiency : Different perspectives from an exploratory study in the Netherlands

    NARCIS (Netherlands)

    Cagno, Enrico; Trianni, Andrea; Worrell, Ernst; Miggiano, Federica

    2014-01-01

    Increased energy efficiency represents a crucial opportunity for European industrial sustainability, but several barriers still need to be tackled, as recent policies have not often succeeded as expected. Thus, it is crucial to understand the existing mismatches between the perception of

  18. Market and behavioral barriers to energy efficiency: A preliminary evaluation of the case for tariff financing in California

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, K. Sydny

    2011-06-23

    Consumers regularly forgo purchases of high efficiency appliances that appear to be cost effective at a reasonable rate of return. While some argue that this is a true revelation of preferences for appliance features, this 'efficiency gap' can be largely explained by a combination of market and behavioral failures that reduce consumers ability to evaluate the relative value of appliances and skew preferences toward initial cost savings, undervaluing future reductions in operating costs. These failures and barriers include externalities of energy use, imperfect competition between manufacturers, asymmetric information, bounded rationality, split incentives, and transaction costs (Golove 1996). Recognizing the social benefit of energy conservation, several major methods are used by policymakers to ensure that efficient appliances are purchased: minimum efficiency standards, Energy Star labeling, and rebates and tax credits. There is no single market for energy services; there are hundreds of uses, thousands of intermediaries, and millions of users, and likewise, no single appropriate government intervention (Golove 1996). Complementary approaches must be implemented, considering policy and institutional limitations. In this paper, I first lay out the rationale for government intervention by addressing the market and behavioral failures and barriers that arise in the context of residential energy efficiency. I then consider the ways in which some of these failures and barriers are addressed through major federal programs and state and utility level programs that leverage them, as well as identifying barriers that are not addressed by currently implemented programs. Heterogeneity of consumers, lack of financing options, and split incentives of landlords and tenants contribute significantly to the under-adoption of efficient appliances. To quantify the size of the market most affected by these barriers, I estimate the number of appliances, and in particular

  19. Barriers on the propagation of renewable energy sources and sustainable solid waste management practices in Greece.

    Science.gov (United States)

    Boemi, Sn; Papadopoulos, Am; Karagiannidis, A; Kontogianni, S

    2010-11-01

    Renewable energy sources (RES), excluding large hydroelectric plants, currently produce 4.21% of total electricity production in Greece. Even when considering the additional production from large hydroelectric plants, which accounts for some 7.8%, the distance to be covered towards the objective of 20% electricity produced from RES by 2010 and respectively towards 20% of total energy production by 2020 is discouraging. The potential, however, does exist; unfortunately so do serious barriers. On the other hand, solid waste management (SWM) is an issue that generates continuously increasing interest due to the extra amounts of solid waste generated; the lack of existing disposal facilities with adequate infrastructure and integrated management plans, also often accompanied by legislative and institutional gaps. However, socio-economic and public awareness problems are still met in the planning and implementation of RES and SWM projects, together with the lack of a complete national cadastre and a spatial development master plan, specifying areas eligible for RES and SWM development. Specific barriers occur for individual RES and the on-going inclusion of waste-derived renewable energy in the examined palette further increases the complexity of the entire issue. The consolidated study of this broad set of barriers was a main task of the present study which was carried out within the frame of a Hellenic-Canadian research project; the main results will be discussed herein.

  20. Simulations of skin barrier function: free energies of hydrophobic and hydrophilic transmembrane pores in ceramide bilayers.

    Science.gov (United States)

    Notman, Rebecca; Anwar, Jamshed; Briels, W J; Noro, Massimo G; den Otter, Wouter K

    2008-11-15

    Transmembrane pore formation is central to many biological processes such as ion transport, cell fusion, and viral infection. Furthermore, pore formation in the ceramide bilayers of the stratum corneum may be an important mechanism by which penetration enhancers such as dimethylsulfoxide (DMSO) weaken the barrier function of the skin. We have used the potential of mean constraint force (PMCF) method to calculate the free energy of pore formation in ceramide bilayers in both the innate gel phase and in the DMSO-induced fluidized state. Our simulations show that the fluid phase bilayers form archetypal water-filled hydrophilic pores similar to those observed in phospholipid bilayers. In contrast, the rigid gel-phase bilayers develop hydrophobic pores. At the relatively small pore diameters studied here, the hydrophobic pores are empty rather than filled with bulk water, suggesting that they do not compromise the barrier function of ceramide membranes. A phenomenological analysis suggests that these vapor pores are stable, below a critical radius, because the penalty of creating water-vapor and tail-vapor interfaces is lower than that of directly exposing the strongly hydrophobic tails to water. The PMCF free energy profile of the vapor pore supports this analysis. The simulations indicate that high DMSO concentrations drastically impair the barrier function of the skin by strongly reducing the free energy required for pore opening.

  1. Barriers to electric energy efficiency in Ghana

    Science.gov (United States)

    Berko, Joseph Kofi, Jr.

    Development advocates argue that sustainable development strategies are the best means to permanently improve living standards in developing countries. Advocates' arguments are based on the technical, financial, and environmental advantages of sustainable development. However, they have not addressed the organizational and administrative decision-making issues which are key to successful implementation of sustainable development in developing countries. Using the Ghanaian electricity industry as a case study, this dissertation identifies and analyzes organizational structures, administrative mechanisms, and decision-maker viewpoints that critically affect the success of adoption and implementation of energy efficiency within a sustainable development framework. Utilizing semi-structured interviews in field research, decision-makers' perceptions of the pattern of the industry's development, causes of the electricity supply shortfall, and barriers to electricity-use efficiency were identified. Based on the initial findings, the study formulated a set of policy initiatives to establish support for energy use efficiency. In a second set of interviews, these policy suggestions were presented to some of the top decision-makers to elicit their reactions. According to the decision-makers, the electricity supply shortfall is due to rapid urbanization and increased industrial consumption as a result of the structural adjustment program, rural electrification, and the sudden release of suppressed loads. The study found a lack of initiative and collaboration among industry decision-makers, and a related divergence in decision-makers' concerns and viewpoints. Also, lacking are institutional support systems and knowledge of proven energy efficiency strategies and technologies. As a result, planning, and even the range of perceived solutions to choose from are supply-side oriented. The final chapter of the study presents implications of its findings and proposes that any

  2. Thermodynamics in rotating systems—analysis of selected examples

    International Nuclear Information System (INIS)

    Güémez, J; Fiolhais, M

    2014-01-01

    We solve a set of selected exercises on rotational motion requiring a mechanical and thermodynamical analysis. When non-conservative forces or thermal effects are present, a complete study must use the first law of thermodynamics together with Newton’s second law. The latter is here better expressed in terms of an ‘angular’ impulse–momentum equation (Poinsot–Euler equation), or, equivalently, in terms of a ‘rotational’ pseudo-work–energy equation. Thermodynamical aspects in rotational systems, when e.g. frictional forces are present or when there is a variation of the rotational kinetic energy due to internal sources of energy, are discussed. (paper)

  3. Barriers, drivers and decision-making process for industrial energy efficiency: A broad study among manufacturing small and medium-sized enterprises

    International Nuclear Information System (INIS)

    Trianni, Andrea; Cagno, Enrico; Farné, Stefano

    2016-01-01

    Highlights: • Barriers and drivers vary along the decision-making process of EEM adoption. • Economic barriers, awareness and behavioural are most critical. • Beside economic drivers, major relevance of regulatory and vocational training. • Importance of stakeholders providing technical support. • Barriers and drivers are different according to several firm characteristics. - Abstract: Energy efficiency has been recognized as a primary means to increase the competitiveness of the industrial sector, and in particular for small and medium-sized enterprises (SMEs), in which energy efficiency measures (EEMs) are scarcely implemented. For this reason, future policies should carefully address such issue. Hence, it is really crucial to have a precise and punctual knowledge of the barriers to be tackled in the decision-making process of adopting an EEM and the drivers to be promoted. This study discussed the findings from a broad investigation within 222 manufacturing SMEs located in a Northern Italy region. Beside economic issues particularly affecting SMEs, awareness and behavioural issues emerge as critical, affecting the very first steps of the decision-making process, related to the punctual identification and evaluation of plausible EEMs. The support from manufacturers, technology suppliers, installers and ESCOs supporting SMEs through vocational training drivers (e.g. technical support) is really important to tackle such issues. More generally, beside financial institutions, the supply chain of technologies is recognized as particularly useful for supporting enterprises in the adoption of EEMs. Additionally, having previously conducted energy audit and implemented EEMs are critical factors able to highlight non-economic barriers and drivers. Therefore, the promotion of EEMs will necessarily imply a further effort in pointing out the so-called non-energy benefits (NEBs) from the implementation of EEMs. Finally, our study reveals that smaller and non-energy

  4. Normalized lift: an energy interpretation of the lift coefficient simplifies comparisons of the lifting ability of rotating and flapping surfaces.

    Science.gov (United States)

    Burgers, Phillip; Alexander, David E

    2012-01-01

    For a century, researchers have used the standard lift coefficient C(L) to evaluate the lift, L, generated by fixed wings over an area S against dynamic pressure, ½ρv(2), where v is the effective velocity of the wing. Because the lift coefficient was developed initially for fixed wings in steady flow, its application to other lifting systems requires either simplifying assumptions or complex adjustments as is the case for flapping wings and rotating cylinders.This paper interprets the standard lift coefficient of a fixed wing slightly differently, as the work exerted by the wing on the surrounding flow field (L/ρ·S), compared against the total kinetic energy required for generating said lift, ½v(2). This reinterpreted coefficient, the normalized lift, is derived from the work-energy theorem and compares the lifting capabilities of dissimilar lift systems on a similar energy footing. The normalized lift is the same as the standard lift coefficient for fixed wings, but differs for wings with more complex motions; it also accounts for such complex motions explicitly and without complex modifications or adjustments. We compare the normalized lift with the previously-reported values of lift coefficient for a rotating cylinder in Magnus effect, a bat during hovering and forward flight, and a hovering dipteran.The maximum standard lift coefficient for a fixed wing without flaps in steady flow is around 1.5, yet for a rotating cylinder it may exceed 9.0, a value that implies that a rotating cylinder generates nearly 6 times the maximum lift of a wing. The maximum normalized lift for a rotating cylinder is 1.5. We suggest that the normalized lift can be used to evaluate propellers, rotors, flapping wings of animals and micro air vehicles, and underwater thrust-generating fins in the same way the lift coefficient is currently used to evaluate fixed wings.

  5. Alpha-production channels in 6Li+159Tb at energies around the Coulomb barrier

    International Nuclear Information System (INIS)

    Pradhan, M.K.; Mukherjee, A.; Roy, S.; Basu, P.; Goswami, A.; Saha Sarkar, M.; Kshetri, R.; Roy Chowdhury, R.; Ray, M.; Santra, S.; Kailas, S.; Parkar, V.V.; Palit, R.

    2010-01-01

    In order to investigate what are the dominant processes that might contribute to the inclusive α-particle channels, very recently measurements have been performed by the characteristic γ-ray method for the system 6 Li+ 159 Tb at energies below and above the Coulomb barrier (V B = 26.9 MeV)

  6. Quantum mechanics of electronic-rotational energy transfer in F(2P) + H2 collisions

    International Nuclear Information System (INIS)

    Wyatt, R.E.; Walker, R.B.

    1977-01-01

    A theoretical study is made of electronic-rotational energy transfer in F( 2 P) + H 2 three-dimensional collisions, with electronic matrix elements from DIM theory. The quantum close-coupled equations are integrated via the R-matrix propagation method. Inelastic quenching probabilities are emphasized, with and without simulated open reaction channels. Interweaving patterns in the transition probability for even and odd nuclear parity vs. J (total angular momentum quantum number) are analyzed in terms of avoided crossing structure in the electrotational energy correlation diagrams. Localized regions where electronic quenching is dominant are identified in the correlation diagrams, and are confirmed in separate calculations which neglect interchannel mixing in local regions of the atom-molecule separation. Open reaction channels are found to have little influence on the quenching probabilities in these low energy calculations

  7. Calculation of multidimensional potential energy surfaces for even-even transuranium nuclei: systematic investigation of the triaxiality effect on the fission barrier

    Science.gov (United States)

    Chai, Qing-Zhen; Zhao, Wei-Juan; Liu, Min-Liang; Wang, Hua-Lei

    2018-05-01

    Static fission barriers for 95 even-even transuranium nuclei with charge number Z = 94–118 have been systematically investigated by means of pairing self-consistent Woods-Saxon-Strutinsky calculations using the potential energy surface approach in multidimensional (β 2, γ, β 4) deformation space. Taking the heavier 252Cf nucleus (with the available fission barrier from experiment) as an example, the formation of the fission barrier and the influence of macroscopic, shell and pairing correction energies on it are analyzed. The results of the present calculated β 2 values and barrier heights are compared with previous calculations and available experiments. The role of triaxiality in the region of the first saddle is discussed. It is found that the second fission barrier is also considerably affected by the triaxial deformation degree of freedom in some nuclei (e.g., the Z=112–118 isotopes). Based on the potential energy curves, general trends of the evolution of the fission barrier heights and widths as a function of the nucleon numbers are investigated. In addition, the effects of Woods-Saxon potential parameter modifications (e.g., the strength of the spin-orbit coupling and the nuclear surface diffuseness) on the fission barrier are briefly discussed. Supported by National Natural Science Foundation of China (11675148, 11505157), the Project of Youth Backbone Teachers of Colleges and Universities of Henan Province (2017GGJS008), the Foundation and Advanced Technology Research Program of Henan Province (162300410222), the Outstanding Young Talent Research Fund of Zhengzhou University (1521317002) and the Physics Research and Development Program of Zhengzhou University (32410017)

  8. Rotational Spectrum and Conformational Analysis of N-methyl-2-aminoethanol: Insights into the Shape of Adrenergic Neurotransmitters

    Science.gov (United States)

    Calabrese, Camilla; Maris, Assimo; Evangelisti, Luca; Piras, Anna; Parravicini, Valentina; Melandri, Sonia

    2018-02-01

    Abstract We describe an experimental and quantum chemical study for the accurate determination of the conformational space of small molecular systems governed by intramolecular non-covalent interactions. The model systems investigated belong to the biological relevant aminoalcohol’s family, and include 2-aminophenylethanol, 2-methylaminophenylethanol, noradrenaline, adrenaline 2-aminoethanol and N-methyl-2-aminoethanol. For the latter molecule, the rotational spectrum in the 6-18 and 59.6-74.4 GHz ranges was recorded in the isolated conditions of a free jet expansion. Based on the analysis of the rotational spectra, two different conformational species and 11 isotopologues were observed and their spectroscopic constants, including 14N-nuclear hyperfine coupling constants and methyl internal rotation barriers, were determined. From the experimental data a structural determination was obtained, which was also used to benchmark accurate quantum chemical calculations on the whole conformational space. Atom in molecules and non-covalent interactions theories allowed the characterization of the position of the intramolecular non-covalent interactions and the energies involved, highlighting the subtle balance responsible of the stabilization of all the molecular systems.

  9. Stability analysis of a power system made up of an intermittent renewable energy source directly tied to a conventional rotating power generator

    International Nuclear Information System (INIS)

    Coiante, D.

    1997-02-01

    A simple power system made up of a conventional rotating power generator in direct connection to an intermittent renewable energy source (with energy or photovoltaic) is modelled on the base of respective functional schemes. The relative variations of the voltage frequency are calculated as an output to an abrupt variation of intermittent tied power and in function of electro-mechanical parameters of the rotating generator (dumping coefficient and inertial rotor coefficient). The stability conditions and the tolerance allowed on the frequency variations are considered in relation to toad service requires. As a consequence, the maximum intermittent power amount, which can be accepted in direct connection, is obtained. For usual conventional rotating machines, the resulting limit is placed in the range of (12-19)% of nominal capacity of power generator

  10. The Swedish energy forestry research programme at the Department of Short Rotation Forestry, SUAS, Uppsala. Summary report prepared for the evaluation of the short-rotation forestry research 1993-1996

    Energy Technology Data Exchange (ETDEWEB)

    Ledin, S.; Christersson, L. [eds.

    1996-12-31

    The overall aim of the Department of Short Rotation Forestry is to carry out research for development of basic, theoretical and practical knowledge in the related disciplines of biology, ecology and cultivation techniques in order to reach a high and sustainable production of woody biomass for energy purposes using environmentally acceptable methods. This report gives summaries of nine research programs within the Department, and the reports were prepared for the evaluation of the research during the period 1993-1996. The projects are: 1. Competition in short rotation forests (Theo Verwijst); 2. Carbon allocation as a function of nutrient and water availability (Lars Rytter, Tom Ericsson); 3. States and fluxes of water and carbon dioxide in the soil-plant-atmosphere system (Anders Lindroth); 4. Root dynamics of fast growing deciduous trees (Rose-Marie Rytter); 5. Accumulation and mobilization of root reserves in coppice growth (Lisa Sennerby-Forsse, Lars Bollmark, Yuehua von Fircks); 6. Effects of nutrient supply on frost resistance in fast growing Salix clones (Heinrich von Fircks); 7. Optimizing water and nutrients in poplar and willow plantations for maximum growth (Sune Elowson); 8. Soil biology in relation to energy forestry (Ulf Granhall); and 9. Plant protection in short rotation forestry against fungi and bacteria (Mauritz Ramstedt)

  11. Collective rotation from ab initio theory

    International Nuclear Information System (INIS)

    Caprio, M.A.; Maris, P.; Vary, J.P.; Smith, R.

    2015-01-01

    Through ab initio approaches in nuclear theory, we may now seek to quantitatively understand the wealth of nuclear collective phenomena starting from the underlying internucleon interactions. No-core configuration interaction (NCCI) calculations for p-shell nuclei give rise to rotational bands, as evidenced by rotational patterns for excitation energies, electromagnetic moments and electromagnetic transitions. In this review, NCCI calculations of 7–9 Be are used to illustrate and explore ab initio rotational structure, and the resulting predictions for rotational band properties are compared with experiment. We highlight the robustness of ab initio rotational predictions across different choices for the internucleon interaction. (author)

  12. Future energy efficiency improvements within the US department of defense: Incentives and barriers

    International Nuclear Information System (INIS)

    Umstattd, Ryan J.

    2009-01-01

    The present work describes the military impact of improved efficiency and then highlights existing technological, political, and financial barriers for improving overall energy efficiency. As the largest user of energy within the US government, the Department of Defense (DOD) is rightly concerned that any disruption to the nation's energy supply may have an extremely adverse impact on its military capabilities. The total solution to providing energy security will be multi-faceted with progress required on many fronts. Increasing the use of renewable energy sources and improving energy storage capabilities are gradually creating a positive impact, but investing in improving the overall efficiency of the military effort provides both immediate and long-lasting payback. One might suppose that a decrease in the energy used by the DOD should lead to a decrease in military capability, but historical data proves otherwise. It is shown that the military has additional impetus, compared to civilian consumers, to pursue energy-efficiency improvements. Many tools are available to help the DOD along this path, yet there remain obstacles which must first be identified and analyzed as discussed herein.

  13. Mechanised harvesting of short-rotation coppices

    OpenAIRE

    Vanbeveren, Stefan P.P.; Spinelli, Raffaele; Eisenbies, Mark; Schweier, Janine; Mola-Yudego, Blas; Magagnotti, Natascia; Acuna, Mauricio; Dimitriou, Ioannis; Ceulemans, Reinhart

    2017-01-01

    Abstract: Short-rotation coppice (SRC) is an important source of woody biomass for bioenergy. Despite the research carried out on several aspects of SRC production, many uncertainties create barriers to farmers establishing SRC plantations. One of the key economic sources of uncertainty is harvesting methods and costs; more specifically, the performance of contemporary machine methods is reviewed. We collected data from 25 literature references, describing 166 field trials. Three harvesting s...

  14. Initiatives for the energy renovation of single-family houses inDenmark evaluated on the basis of barriers and motivators

    DEFF Research Database (Denmark)

    Grøn Bjørneboe, Matilde; Svendsen, Svend; Heller, Alfred

    2018-01-01

    The renovation of single-family houses in Denmark is progressing only slowly. Changes in current pol-icy are needed if the political goal of a fossil-free building sector as part of a fossil-free society is to beachieved. Known barriers and motivators for energy renovation are identified, and arr......The renovation of single-family houses in Denmark is progressing only slowly. Changes in current pol-icy are needed if the political goal of a fossil-free building sector as part of a fossil-free society is to beachieved. Known barriers and motivators for energy renovation are identified......, suggestions are madefor improvement in four areas: (1) focus on non-energy benefits rather than investment, (2) enhance-ment of subsidy system, (3) including relevant renovation plans in the energy performance certificate(EPC), and (4) long-term regulation on the maximum allowed energy consumption of houses....

  15. Identifying Barriers and Pathways to Success for Renewable Energy Development on American Indian Lands

    Energy Technology Data Exchange (ETDEWEB)

    Necefer, Len Edward [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Univ. of Arizona, Tucson, AZ (United States); Jones, Thomas Elisha [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2016-11-01

    American Indian tribes possess lands rich with renewable energy (RE) resources. Tribes have great potential and need to develop these resources, yet face a host of barriers that continue to impede development. Understanding these challenges as well as the pathways that can be taken to overcome them may facilitate more economic development to meet community needs and better position tribes to play a role in securing a low-carbon energy future for the United States. This paper presents the results of an expert elicitation of 24 tribal energy experts from federal, tribal, academic, and private industry backgrounds to identify barriers and opportunities for federally recognized tribes in the lower 48 states. Experts identified a number of unique challenges facing tribes including financing and funding, infrastructure, tribal leadership and staff, state-level influence, and partnerships. Cultural factors were seen only to be of concern with large-scale development. Tribal sovereignty is a significant motivation for RE development and has yet to be fully realized. Cultural considerations are critical to the success of future projects; smaller residential and community-scale projects may be a better fit. Improving partnerships between tribes and the private sector can increase RE deployment and overcome historical distrust. States can have a double-ended influence on projects within tribal lands through taxation.

  16. Helical spin rotators and snakes for RHIC

    International Nuclear Information System (INIS)

    Ptitsin, V.I.; Shatunov, Yu.M.; Peggs, S.

    1995-01-01

    The RHIC collider, now under construction at BNL, will have the possibility of polarized proton-proton collisions up to a beam energy of 250 Gev. Polarized proton beams of such high energy can be only obtained with the use of siberian snakes, a special kind of spin rotator that rotates the particle spin by 180 degree around an axis lying in the horizontal plane. Siberian snakes help to preserve the beam polarization while numerous spin depolarizing resonances are crossed, during acceleration. In order to collide longitudinally polarized beams, it is also planned to install spin rotators around two interaction regions. This paper discusses snake and spin rotator designs based on sequences of four helical magnets. The schemes that were chosen to be applied at RHIC are presented

  17. Design of a non-linear power take-off simulator for model testing of rotating wave energy devices

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, M.F.P.; Henriques, J.C.C.; Lopes, Miguel C.; Gato, L.M.C. [IDMEC - Instituto de Engenharia Mecanica, Instituto Superior Tecnico, Universidade Tecnica de Lisboa, Lisboa (Portugal); Dente Antonio [CIE3 - Center for Innovation in Electrical and Energy Engineering, Lisboa (Portugal)

    2009-07-01

    Eddy current brakes provide a versatile way of simulating the power take-off system (PTO) in the model testing of wave energy converters at small scale. These are based on the principle that a conductive material moving perpendicularly to a magnetic field generates a braking force proportional to its velocity. This was applied in the design of the PTO simulator of a bottom-hinged flap wave energy converter model, at 1/16 scale. The efforts put into the accurate dynamic simulation of the device led to the development of a controllable PTO simulator, which can be applied to other small scale rotating wave energy device models. A special power source was built to provide the required controllable current intensity to feed the magnetic field generating coils. Different non-linear damping PTO characteristic curves can be simulated by basing the current control on real-time velocity measurement. The calibration of the system was done by connecting the device to a constant rotating speed motor and measuring the resistent torque produced by the PTO with a torquemeter for different values of current intensity through the coils.

  18. Survey of the Relationship Between Activity Energy Expenditure Metabolic Equivalents and Barrier Factors of Physical Activity in the Elderly in Kashan

    OpenAIRE

    Sadrollahi, Ali; Khalili, Zahra; Pour Nazari, Robab; Mohammadi, Majid; Ahmadi Khatir, Maryam; Mossadegh, Najima

    2016-01-01

    Background Physical activity in the elderly is influenced by aspects of aging that cause personal, mental, environmental, and social changes. Increases in factors that are barriers to activity cause physical energy expenditure to decrease. Objectives The aim of the present study was to survey the relationship between energy expenditure in metabolic equivalent units (MET) and factors that are barriers to physical activity in elderly people in Kashan, Iran Methods This is a descriptive analysis...

  19. Barriers to clean development mechanism renewable energy projects in Mexico

    International Nuclear Information System (INIS)

    Lokey, Elizabeth

    2009-01-01

    Mexico is not reaching its full potential to capture benefits from clean development mechanism (CDM) projects because of its limited market for independent power producers (IPPs) and the barriers imposed on these entities by the state-run electric utility that controls most of the country's generation and transmission. This state-run entity has pursued CDM revenues only in isolated cases where international financial assistance was given because it is bound by law to pursue the least-cost generation option for its customers. Recent changes in Mexican legislation that provide incentives for renewable energy development could open the marketplace for these types of projects. (author)

  20. Origin of methyl torsional potential barrier – An overview

    Indian Academy of Sciences (India)

    Unknown

    This paper presents the evolution of views on methyl internal rotation ... recognized in the early years of quantum theory.1 Since then, detailed experimental and ..... C−C bond in the methyl conjugated molecules is an important factor for barrier.

  1. The energy highways. The three safety barriers at nuclear power plants. Where does coal fit into the energy mix?. Sustainable urban development in Hanover. Energy in sub-Saharan Africa

    International Nuclear Information System (INIS)

    Anon.

    2005-01-01

    This issue of Alternatives newsletter contains a main press-kit about the economics of interconnected power distribution systems and 4 articles dealing with reactors safety, the advantages and drawbacks of coal in the energy mix, the environmental policy of Hanover city, and the energy situation in sub-Saharan Africa: 1 - 'The energy highways': Spotlight on the electrical power grids. From the much needed modernization of existing installations to the extension of networks in developing countries, Alternatives takes a look at these infrastructures that shape our environment, which can be considered as veritable 'energy highways' ensuring the coverage of our planet. 2 - 'The three safety barriers at nuclear power plants': Review of the three protective barriers deployed in the nuclear industry to ensure reactor safety. 3 - 'Where does coal fit into the energy mix?': Two experts put into perspective the challenges related to the use of coal, its efficiency and its environmental impact, on the basis of the Chinese and Polish examples. 4 - 'Sustainable urban development in Hanover': Bringing together quality of living and energy savings, this is the challenge taken up by Hanover in the Kronsberg area. Alternatives has examined this original model, which could serve as an example for other European cities. 5 - 'Energy in sub-Saharan Africa': Relatively abundant resources but which are poorly utilized and distributed characterize the energy situation in sub-Saharan Africa. Analysis of the situation and explanation of this paradox

  2. Design and Simulation of a Spin Rotator for Longitudinal Field Measurements in the Low Energy Muons Spectrometer

    Science.gov (United States)

    Salman, Z.; Prokscha, T.; Keller, P.; Morenzoni, E.; Saadaoui, H.; Sedlak, K.; Shiroka, T.; Sidorov, S.; Suter, A.; Vrankovic, V.; Weber, H.-P.

    We usedGeant4 to accurately model the low energy muons (LEM) beam line, including scattering due to the 10-nm thin carbon foil in the trigger detector. Simulations of the beam line transmission give excellent agreement with experimental results for beam energies higher than ∼ 12keV.We use these simulations to design and model the operation of a spin rotator for the LEM spectrometer, which will enable longitudinal field measurements in the near future.

  3. Prediction of point-defect migration energy barriers in alloys using artificial intelligence for atomistic kinetic Monte Carlo applications

    Energy Technology Data Exchange (ETDEWEB)

    Castin, N. [Structural Materials Group, Nuclear Materials Science Institute, Studiecentrum voor Kerneenergie Centre d' etude de l' energie nucleaire (SCK CEN), Boeretang 200, B-2400 Mol (Belgium); Universite Libre de Bruxelles (ULB), Physique des Solides Irradies et Nanostructures (PSIN), CP234 Boulevard du triomphe, Brussels (Belgium); Malerba, L. [Structural Materials Group, Nuclear Materials Science Institute, Studiecentrum voor Kerneenergie Centre d' etude de l' energie nucleaire (SCK CEN), Boeretang 200, B-2400 Mol (Belgium)], E-mail: lmalerba@sckcen.be

    2009-09-15

    We significantly improved a previously proposed method to take into account chemical and also relaxation effects on point-defect migration energy barriers, as predicted by an interatomic potential, in a rigid lattice atomistic kinetic Monte Carlo simulation. Examples of energy barriers are rigorously calculated, including chemical and relaxation effects, as functions of the local atomic configuration, using a nudged elastic bands technique. These examples are then used to train an artificial neural network that provides the barriers on-demand during the simulation for each configuration encountered by the migrating defect. Thanks to a newly developed training method, the configuration can include a large number of neighbour shells, thereby properly including also strain effects. Satisfactory results have been obtained when the configuration includes different chemical species only. The problems encountered in the extension of the method to configurations including any number of point-defects are stated and solutions to tackle them are sketched.

  4. Order parameters and energies of analytic and singular vortex lines in rotating 3He-A

    International Nuclear Information System (INIS)

    Passvogel, T.; Schopohl, N.; Warnke, M.; Tewordt, L.

    1982-01-01

    We present the expressions of the generalized Ginzburg-Landau (GL) theory for the free energy and the supercurrent in terms of the d vector, the magnetic field H, and operators containing the spatial gradient and the rotation Ω. These expressions are then specialized to the Anderson--Brinkman--Morel (ABM) state. We consider eight single-vortex lines of cylindrical symmetry and radius R = [2mΩ/h]/sup -1/2/: the Mermin--Ho vortex, a second analytic vortex, and six singular vortices, i.e., the orbital and radial disgyrations, the orbital and radial phase vortices, and two axial phase vortices. These eight vortex states are determined by solving the Euler--Lagrange equations whose solutions minimize the GL free energy functional. For increasing field, the core radius of the I texture of the Mermin--Ho vortex tends to a limiting value, while the core radius of the d texture goes to zero. The gap of the singular vortices behaves like r/sup α/ for r→0, where α ranges between √1/2 and √9/2. The energy of the radial disgyration becomes lower than that of the Mermin--Ho vortex for fields H> or =6.5 H* = 6.5 x 25 G (at T = 0.99 T/sub c/ and for R = 10 L* = 60 μm, or Ω = 2.9 rad/sec). For R→2xi/sub T/ (xi/sub T/ is the GL coherence length) or Ω→Ω/sub c2/ (upper critical rotation speed), the energies of the singular vortices become lower than the energies of the analytic vortices. This is in agreement with the exact result of Schopohl for a vortex lattice at Ω/sub c/2 . Finally, we calculate the correction of order (1-T/T/sub c/) to the GL gap for the axial phase vortex

  5. Enhancing the effective energy barrier of a Dy(III) SMM using a bridged diamagnetic Zn(II) ion.

    Science.gov (United States)

    Upadhyay, Apoorva; Singh, Saurabh Kumar; Das, Chinmoy; Mondol, Ranajit; Langley, Stuart K; Murray, Keith S; Rajaraman, Gopalan; Shanmugam, Maheswaran

    2014-08-18

    Field induced single-molecule-magnet behaviour is observed for both a heterodinuclear [ZnDy(L(-))2](3+) complex (1) and a mononuclear [Dy(HL)2](3+) complex (2), with effective energy barriers of 83 cm(-1) and 16 cm(-1), respectively. Insights into the relaxation mechanism(s) and barrier heights are provided via ab initio and DFT calculations. Our findings reveal an interesting observation that the U(eff) of SMMs can be enhanced by incorporating diamagnetic metal ions.

  6. Tunneling of an energy eigenstate through a parabolic barrier viewed from Wigner phase space

    DEFF Research Database (Denmark)

    Heim, D.M.; Schleich, W.P.; Alsing, P.M.

    2013-01-01

    We analyze the tunneling of a particle through a repulsive potential resulting from an inverted harmonic oscillator in the quantum mechanical phase space described by the Wigner function. In particular, we solve the partial differential equations in phase space determining the Wigner function...... of an energy eigenstate of the inverted oscillator. The reflection or transmission coefficients R or T are then given by the total weight of all classical phase-space trajectories corresponding to energies below, or above the top of the barrier given by the Wigner function....

  7. A barrier analysis for the development of distributed energy in China: A case study in Fujian province

    International Nuclear Information System (INIS)

    Liu, Jian; Wang, Run; Sun, Yanwei; Lin, Yanjie; Xiao, Lishan

    2013-01-01

    Distributed energy (DE) is receiving lots of attention from the Chinese government. A number of DE projects have been constructed in China. However, there are still numerous problems with DE projects. What hinders the development of DE in China? The Huadian Jimei distributed energy project (HJDE) is a typical DE building project that was not completed successfully. This paper focuses on this DE project to explore the barriers to DE development. The research group conducted 13 semi-structured interviews with representatives of institutions and corporations involved in the HJDE project to collect information. Based on the information, three types of problems were determined, and the results indicate that these conflicts between the core stakeholders make DE projects unsuccessful. These problems result from institutional barriers to DE, rooting in the development policy and the current energy market. Moreover, several key stakeholders are not able to play an active role in the design or management of DE projects. The Chinese government will put a much greater effort into the development of future DE projects. Many national support policies and rules will be announced, which are easy to practical use. Under these conditions, 1000 DE projects will be successfully completed until 2015. - Highlights: • Using stakeholder analysis, this paper focuses on one typical building DE project. • Conflicts between core stakeholders make the DE project cannot be completed. • The barriers are related to the role of electricity consumers in DE projects. • The barriers are also related to current Chinese natural gas and LNG market. • Drivers such as regulation, incentives and so on should be built and modified

  8. Do we need to overcome barriers to learning in the workplace for foundation trainees rotating in neurosurgery in order to improve training satisfaction?

    Science.gov (United States)

    Phan, Pho Nh; Patel, Keyur; Bhavsar, Amar; Acharya, Vikas

    2016-01-01

    Junior doctors go through a challenging transition upon qualification; this repeats every time they start a rotation in a new department. Foundation level doctors (first 2 years postqualification) in neurosurgery are often new to the specialty and face various challenges that may result in significant workplace dissatisfaction. The neurosurgical environment is a clinically demanding area with a high volume of unwell patients and frequent emergencies - this poses various barriers to learning in the workplace for junior doctors. We identify a number of key barriers and review ideas that can be trialed in the department to overcome them. Through an evaluation of current suggestions in the literature, we propose that learning opportunities need to be made explicit to junior doctors in order to encourage them to participate as a member of the team. We consider ideas for adjustments to the induction program and the postgraduate medical curriculum to shift the focus from medical knowledge to improving confidence and clinical skills in newly qualified doctors. Despite being a powerful window for opportunistic learning, the daily ward round is unfortunately not maximized and needs to be more learner focused while maintaining efficiency and time consumption. Finally, we put forward the idea of an open forum where trainees can talk about their learning experiences, identify subjective barriers, and suggest solutions to senior doctors. This would be achieved through departmental faculty development. These interventions are presented within the context of the neurosurgical ward; however, they are transferable and can be adapted in other specialties and departments.

  9. Analysis of Rotation and Transport Data in C-Mod ITB Plasmas

    Science.gov (United States)

    Fiore, C. L.; Rice, J. E.; Reinke, M. L.; Podpaly, Y.; Bespamyatnov, I. O.; Rowan, W. L.

    2009-11-01

    Internal transport barriers (ITBs) spontaneously form near the half radius of Alcator C-Mod plasmas when the EDA H-mode is sustained for several energy confinement times in either off-axis ICRF heated discharges or in purely ohmic heated plasmas. These plasmas exhibit strongly peaked density and pressure profiles, static or peaking temperature profiles, peaking impurity density profiles, and thermal transport coefficients that approach neoclassical values in the core. It has long been observed that the intrinsic central plasma rotation that is strongly co-current following the H-mode transition slows and often reverses as the density peaks as the ITB forms. Recent spatial measurements demonstrate that the rotation profile develops a well in the core region that decreases continuously as central density rises while the value outside of the core remains strongly co-current. This results in the formation of a steep potential gradient/strong electric field at the location of the foot of the ITB density profile. The resulting E X B shearing rate is also quite significant at the foot. These analyses and the implications for plasma transport and stability will be presented.

  10. NOVEL TSUNAMI BARRIERS AND THEIR APPLICATIONS FOR HYDROELECTRIC ENERGY STORAGE, FISH FARMING, AND FOR LAND RECLAMATION

    Directory of Open Access Journals (Sweden)

    Hans J. Scheel

    2014-10-01

    Full Text Available The tsunami hazard can be mitigated if the destructive waves generated from earthquakes and landslides can be reflected by a stable submerged vertical barrier before striking coastal communities or important structures. Building such deep walls by conventional submarine technology is difficult. The present study describes the principle and the erection of such submarine defensive walls by a relatively simple efficient and economic technology. This technology is based on lowering high- strength steel fences with horizontal anchors, or two parallel steel fences with distance holders, into the sea and fixing them with rocks deposited from top. Dredged material like gravel or sand can be used for additional filling. This Tsunami-Flooding Barrier (TFB extends a few meters above sea level and carries on top a concrete supply and service road protected on both sides against storm waves by concrete walls. Replaceable surge stoppers (parapets, wave return walls prevent overtopping and erosion of the seaward barrier face. The TFBs protect the coastline against tsunami and the highest storm waves from hurricanes, but also can provide protection from oil spills or other contaminations from the ocean and thus protect flora, fauna, coral reefs and beaches. Channels and gates allow navigation and can be closed quickly upon a tsunami or storm warning. The construction costs can be eventually compensated by using the reservoirs between coast and barriers for hydroelectric energy storage (using pump-turbines in the barriers or for fish-farming, or alternatively the reservoir can be filled with rocks, rubble, gravel, sand and covered with soil in order to reclaim new land. Tidal energy can be generated by installing turbines within these barriers. Also, this submarine architecture may be applied to protect pillars of bridges and offshore platforms, and for erecting “roads” into the sea to connect near-shore platforms and wind-parks with the coast and

  11. What we have learned so far on reactions and scattering with weakly bound nuclei at near barrier energies

    International Nuclear Information System (INIS)

    Gomes, P.R.S.

    2011-01-01

    Reactions involving weakly bound nuclei, especially halo nuclei, at near barrier energies, are an important subject not yet fully understood. Due to the low threshold energy for breakup, this process is particularly important and may affect significantly the fusion process and elastic scattering. In this talk I will show the systematic of results so far available in this field, concerning static and dynamical effects of halo and breakup on fusion and total reaction cross sections, the energy dependence of the optical potential on the elastic scattering and coupling effects on quasi-elastic scattering barrier distributions involving weakly bound nuclei, both stable and radioactive. The data to be discussed are new data from our group and from the literature, together with some older data. I will also present some experimental challenges for the development of this field. (author)

  12. Mind the gap! Barriers and implementation deficiencies of energy policies at the local scale in urban China

    International Nuclear Information System (INIS)

    Wu, Jing; Zuidema, Christian; Gugerell, Katharina; Roo, Gert de

    2017-01-01

    Environmental concerns and potential social-economic impacts associated with fossil fuels have turned cities into indispensable entities for supporting energy transitions in China. Pursuing a transition towards a sustainable energy system has become a major policy concern for the Chinese central government. In response, and on the basis of a top-down and conformance-oriented system of policy implementation and evaluation, the Chinese central government has launched various policies and targets on energy efficiency and production that lower levels of government have to follow. However, the translation of top-down targets and the measurement of conformance-based targets have both proved to be problematic. This paper investigates Chinese state policy on energy efficiency through four empirical case studies. It identifies how policy design of target setting and evaluation is both impacting and driving the implementation of energy efficiency at the local urban scale. We demonstrate how local authorities are faced with constraining barriers that can inhibit the implementation of centrally issued targets and policies. These barriers may even undermine local performance in the pursuit of ambitious energy efficiency goals, resulting in potentially harmful consequences. - Highlights: • Energy efficiency policies are ill-adapted to the diversity of local circumstances. • Predominant focus on conformance in energy policies overlooks local performance. • Pursuing ambitions runs the risk of being undermined by strict measuring systems. • Chinese energy transition needs more flexibility in target setting and evaluation.

  13. Barriers for Energy Renovation of Danish Single-Family Houses and Suggested Solutions to Overcome These

    DEFF Research Database (Denmark)

    Mortensen, Andrea; Heiselberg, Per; Knudstrup, Mary-Ann

    2011-01-01

    As much as 40% of the total energy consumption in Denmark is utilized by the building sector and most of this energy is used for heating. Political initiatives have been taken to reduce this amount considerably but for this to happen, the energy consumption of the existing residential housing stock...... must be reduced dramatically. The greatest saving potential is found among the approximately 440.000 standardised single-family houses which were constructed in the 1960’s and 1970’s. It is found that barriers preventing the implementation of this great potential are present in various forms among all...

  14. Fusion of light ion systems at energies near and below the Coulomb barrier

    International Nuclear Information System (INIS)

    Arnould, M.; Howard, W.M.; Cusson, R.Y.

    1978-01-01

    Experimental fusion cross sections for light ion systems at energies below the Coulomb barrier become available in greater and greater number, and provide a stringent test of the macroscopic and microscopic physics involved in models of heavy-ion reactions. Measurements and predictions of the fusion cross sections for 12 C + 12 C, 12 C + 16 O and 16 O + 16 O are also of major importance in astrophysics. (orig.) [de

  15. Non-monotonic probability of thermal reversal in thin-film biaxial nanomagnets with small energy barriers

    Directory of Open Access Journals (Sweden)

    N. Kani

    2017-05-01

    Full Text Available The goal of this paper is to investigate the short time-scale, thermally-induced probability of magnetization reversal for an biaxial nanomagnet that is characterized with a biaxial magnetic anisotropy. For the first time, we clearly show that for a given energy barrier of the nanomagnet, the magnetization reversal probability of an biaxial nanomagnet exhibits a non-monotonic dependence on its saturation magnetization. Specifically, there are two reasons for this non-monotonic behavior in rectangular thin-film nanomagnets that have a large perpendicular magnetic anisotropy. First, a large perpendicular anisotropy lowers the precessional period of the magnetization making it more likely to precess across the x^=0 plane if the magnetization energy exceeds the energy barrier. Second, the thermal-field torque at a particular energy increases as the magnitude of the perpendicular anisotropy increases during the magnetization precession. This non-monotonic behavior is most noticeable when analyzing the magnetization reversals on time-scales up to several tens of ns. In light of the several proposals of spintronic devices that require data retention on time-scales up to 10’s of ns, understanding the probability of magnetization reversal on the short time-scales is important. As such, the results presented in this paper will be helpful in quantifying the reliability and noise sensitivity of spintronic devices in which thermal noise is inevitably present.

  16. Sub-barrier capture with quantum diffusion approach

    Directory of Open Access Journals (Sweden)

    Scheid W.

    2011-10-01

    Full Text Available With the quantum diffusion approach the behavior of capture cross sections and mean-square angular momenta of captured systems are revealed in the reactions with deformed and spherical nuclei at sub-barrier energies. With decreasing bombarding energy under the barrier the external turning point of the nucleus-nucleus potential leaves the region of short-range nuclear interaction and action of friction. Because of this change of the regime of interaction, an unexpected enhancement of the capture cross section is found at bombarding energies far below the Coulomb barrier. This effect is shown its worth in the dependence of mean-square angular momentum on the bombarding energy. From the comparison of calculated capture cross sections and experimental capture or fusion cross sections the importance of quasifission near the entrance channel is demonstrated for the actinidebased reactions and reactions with medium-heavy nuclei at extreme sub-barrier energies.

  17. Rotating quantum states

    International Nuclear Information System (INIS)

    Ambruş, Victor E.; Winstanley, Elizabeth

    2014-01-01

    We revisit the definition of rotating thermal states for scalar and fermion fields in unbounded Minkowski space–time. For scalar fields such states are ill-defined everywhere, but for fermion fields an appropriate definition of the vacuum gives thermal states regular inside the speed-of-light surface. For a massless fermion field, we derive analytic expressions for the thermal expectation values of the fermion current and stress–energy tensor. These expressions may provide qualitative insights into the behaviour of thermal rotating states on more complex space–time geometries

  18. Nonlinear dynamics and anisotropic structure of rotating sheared turbulence.

    Science.gov (United States)

    Salhi, A; Jacobitz, F G; Schneider, K; Cambon, C

    2014-01-01

    Homogeneous turbulence in rotating shear flows is studied by means of pseudospectral direct numerical simulation and analytical spectral linear theory (SLT). The ratio of the Coriolis parameter to shear rate is varied over a wide range by changing the rotation strength, while a constant moderate shear rate is used to enable significant contributions to the nonlinear interscale energy transfer and to the nonlinear intercomponental redistribution terms. In the destabilized and neutral cases, in the sense of kinetic energy evolution, nonlinearity cannot saturate the growth of the largest scales. It permits the smallest scale to stabilize by a scale-by-scale quasibalance between the nonlinear energy transfer and the dissipation spectrum. In the stabilized cases, the role of rotation is mainly nonlinear, and interacting inertial waves can affect almost all scales as in purely rotating flows. In order to isolate the nonlinear effect of rotation, the two-dimensional manifold with vanishing spanwise wave number is revisited and both two-component spectra and single-point two-dimensional energy components exhibit an important effect of rotation, whereas the SLT as well as the purely two-dimensional nonlinear analysis are unaffected by rotation as stated by the Proudman theorem. The other two-dimensional manifold with vanishing streamwise wave number is analyzed with similar tools because it is essential for any shear flow. Finally, the spectral approach is used to disentangle, in an analytical way, the linear and nonlinear terms in the dynamical equations.

  19. The rotating converter GKN II starts operation

    International Nuclear Information System (INIS)

    Jergas, E.

    1989-01-01

    At the beginning of 1989 the energy supply and consumption of the 110-kV-railway mains has changed considerably with starting the rotating converter of the German Federal Railways (DB) in the joint nuclear power station Neckar GmbH (GKN) block II. A description is given of the planned utilization of the rotating converters at baseload operation and possibilities for optimal energy use are shown. (orig.) [de

  20. Glenohumeral interposition of rotator cuff stumps: a rare complication of traumatic rotator cuff tear

    Directory of Open Access Journals (Sweden)

    Paulo Moraes Agnollitto

    2016-02-01

    Full Text Available Abstract The present report describes a case where typical findings of traumatic glenohumeral interposition of rotator cuff stumps were surgically confirmed. This condition is a rare complication of shoulder trauma. Generally, it occurs in high-energy trauma, frequently in association with glenohumeral joint dislocation. Radiography demonstrated increased joint space, internal rotation of the humerus and coracoid process fracture. In addition to the mentioned findings, magnetic resonance imaging showed massive rotator cuff tear with interposition of the supraspinatus, infraspinatus and subscapularis stumps within the glenohumeral joint. Surgical treatment was performed confirming the injury and the rotator cuff stumps interposition. It is important that radiologists and orthopedic surgeons become familiar with this entity which, because of its rarity, might be neglected in cases of shoulder trauma.

  1. Rotational Energy as Mass in H3 + and Lower Limits on the Atomic Masses of D and 3He

    Science.gov (United States)

    Smith, J. A.; Hamzeloui, S.; Fink, D. J.; Myers, E. G.

    2018-04-01

    We have made precise measurements of the cyclotron frequency ratios H3 +/HD+ and H3 +/ 3He+ and observe that different H3+ ions result in different cyclotron frequency ratios. We interpret these differences as due to the molecular rotational energy of H3 + changing its inertial mass. We also confirm that certain high J , K rotational levels of H3+ have mean lifetimes exceeding several weeks. From measurements with the lightest H3+ ion we obtain lower limits on the atomic masses of deuterium and helium-3 with respect to the proton.

  2. Rotational Energy as Mass in H_{3}^{+} and Lower Limits on the Atomic Masses of D and ^{3}He.

    Science.gov (United States)

    Smith, J A; Hamzeloui, S; Fink, D J; Myers, E G

    2018-04-06

    We have made precise measurements of the cyclotron frequency ratios H_{3}^{+}/HD^{+} and H_{3}^{+}/^{3}He^{+} and observe that different H_{3}^{+} ions result in different cyclotron frequency ratios. We interpret these differences as due to the molecular rotational energy of H_{3}^{+} changing its inertial mass. We also confirm that certain high J, K rotational levels of H_{3}^{+} have mean lifetimes exceeding several weeks. From measurements with the lightest H_{3}^{+} ion we obtain lower limits on the atomic masses of deuterium and helium-3 with respect to the proton.

  3. Normalized Lift: An Energy Interpretation of the Lift Coefficient Simplifies Comparisons of the Lifting Ability of Rotating and Flapping Surfaces

    Science.gov (United States)

    Burgers, Phillip; Alexander, David E.

    2012-01-01

    For a century, researchers have used the standard lift coefficient CL to evaluate the lift, L, generated by fixed wings over an area S against dynamic pressure, ½ρv 2, where v is the effective velocity of the wing. Because the lift coefficient was developed initially for fixed wings in steady flow, its application to other lifting systems requires either simplifying assumptions or complex adjustments as is the case for flapping wings and rotating cylinders. This paper interprets the standard lift coefficient of a fixed wing slightly differently, as the work exerted by the wing on the surrounding flow field (L/ρ·S), compared against the total kinetic energy required for generating said lift, ½v2. This reinterpreted coefficient, the normalized lift, is derived from the work-energy theorem and compares the lifting capabilities of dissimilar lift systems on a similar energy footing. The normalized lift is the same as the standard lift coefficient for fixed wings, but differs for wings with more complex motions; it also accounts for such complex motions explicitly and without complex modifications or adjustments. We compare the normalized lift with the previously-reported values of lift coefficient for a rotating cylinder in Magnus effect, a bat during hovering and forward flight, and a hovering dipteran. The maximum standard lift coefficient for a fixed wing without flaps in steady flow is around 1.5, yet for a rotating cylinder it may exceed 9.0, a value that implies that a rotating cylinder generates nearly 6 times the maximum lift of a wing. The maximum normalized lift for a rotating cylinder is 1.5. We suggest that the normalized lift can be used to evaluate propellers, rotors, flapping wings of animals and micro air vehicles, and underwater thrust-generating fins in the same way the lift coefficient is currently used to evaluate fixed wings. PMID:22629326

  4. Normalized lift: an energy interpretation of the lift coefficient simplifies comparisons of the lifting ability of rotating and flapping surfaces.

    Directory of Open Access Journals (Sweden)

    Phillip Burgers

    Full Text Available For a century, researchers have used the standard lift coefficient C(L to evaluate the lift, L, generated by fixed wings over an area S against dynamic pressure, ½ρv(2, where v is the effective velocity of the wing. Because the lift coefficient was developed initially for fixed wings in steady flow, its application to other lifting systems requires either simplifying assumptions or complex adjustments as is the case for flapping wings and rotating cylinders.This paper interprets the standard lift coefficient of a fixed wing slightly differently, as the work exerted by the wing on the surrounding flow field (L/ρ·S, compared against the total kinetic energy required for generating said lift, ½v(2. This reinterpreted coefficient, the normalized lift, is derived from the work-energy theorem and compares the lifting capabilities of dissimilar lift systems on a similar energy footing. The normalized lift is the same as the standard lift coefficient for fixed wings, but differs for wings with more complex motions; it also accounts for such complex motions explicitly and without complex modifications or adjustments. We compare the normalized lift with the previously-reported values of lift coefficient for a rotating cylinder in Magnus effect, a bat during hovering and forward flight, and a hovering dipteran.The maximum standard lift coefficient for a fixed wing without flaps in steady flow is around 1.5, yet for a rotating cylinder it may exceed 9.0, a value that implies that a rotating cylinder generates nearly 6 times the maximum lift of a wing. The maximum normalized lift for a rotating cylinder is 1.5. We suggest that the normalized lift can be used to evaluate propellers, rotors, flapping wings of animals and micro air vehicles, and underwater thrust-generating fins in the same way the lift coefficient is currently used to evaluate fixed wings.

  5. Study of the dynamical potential barriers in heavy ion collisions

    International Nuclear Information System (INIS)

    Zhu, Long; Su, Jun; Xie, Wen-Jie; Zhang, Feng-Shou

    2013-01-01

    The nucleus–nucleus interaction potentials for the fusion reactions 16 O + 208 Pb, 64 Ni + 64 Ni, 58 Ni + 58 Ni and 16 O + 154 Sm are extracted from the improved isospin-dependent quantum molecular dynamics model. The shell correction effects are discussed. The negative shell correction energies lower potential barriers of a certain reaction. The incident energy dependence of the potential barrier is investigated for each system. A complex phenomenon of energy dependence is observed. It is also found that incident energy dependence of the barrier radius and barrier height shows opposite behaviors. The Coulomb potential shows weak energy dependence when distance of two colliding nuclei is lower than the touching distance. The isospin effects of the potential barrier are investigated. The orientation effects of the potential barrier is also discussed for the system 16 O + 154 Sm. The fusion cross sections that correspond to the equatorial orientation of 154 Sm are very low in sub-barrier region because of the high fusion barriers and the shallow potential pockets

  6. Advances in Rotational Seismic Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Pierson, Robert [Applied Technology Associates, Albuquerque, NM (United States); Laughlin, Darren [Applied Technology Associates, Albuquerque, NM (United States); Brune, Robert [Applied Technology Associates, Albuquerque, NM (United States)

    2016-10-19

    Rotational motion is increasingly understood to be a significant part of seismic wave motion. Rotations can be important in earthquake strong motion and in Induced Seismicity Monitoring. Rotational seismic data can also enable shear selectivity and improve wavefield sampling for vertical geophones in 3D surveys, among other applications. However, sensor technology has been a limiting factor to date. The US Department of Energy (DOE) and Applied Technology Associates (ATA) are funding a multi-year project that is now entering Phase 2 to develop and deploy a new generation of rotational sensors for validation of rotational seismic applications. Initial focus is on induced seismicity monitoring, particularly for Enhanced Geothermal Systems (EGS) with fracturing. The sensors employ Magnetohydrodynamic (MHD) principles with broadband response, improved noise floors, robustness, and repeatability. This paper presents a summary of Phase 1 results and Phase 2 status.

  7. Fluctuations and correlations in rotating Bose-Einstein condensates

    International Nuclear Information System (INIS)

    Baharian, Soheil; Baym, Gordon

    2010-01-01

    We investigate the effects of correlations on the properties of the ground state of the rotating harmonically trapped Bose gas by adding Bogoliubov fluctuations to the mean-field ground state of an N-particle single-vortex system. We demonstrate that the fluctuation-induced correlations lower the energy compared to that of the mean-field ground state, that the vortex core is pushed slightly away from the center of the trap, and that an unstable mode with negative energy (for rotations slower than a critical frequency) emerges in the energy spectrum, thus pointing to a better state for slow rotation. We construct mean-field ground states of zero-, one-, and two-vortex states as a function of rotation rate and determine the critical frequencies for transitions between these states, as well as the critical frequency for appearance of a metastable state with an off-center vortex and its image vortex in the evanescent tail of the cloud.

  8. Measurement of leakage and design for the protective barrier of the high energy radiation therapy room

    International Nuclear Information System (INIS)

    Chu, S.S.; Park, C.Y.

    1981-01-01

    The logical development of an optimum structural shielding design and the computation of protective barriers for high energy radiation therapy room, Toshiba 13 MeV are presented. We obtained following results by comparison in between the precalculating values and actual survey after complete installation of radiogenerating units. 1) The calculating formula for the protective barrier written in NCRP report no. 34(1970) was the most ideal and economic calculating methods for the construction of barrier and to determine thickness for the meeting requirements of the number of patients of 80-100 in daily treatment. 2) The precalculating values of protective barrier are 5 times more protective than that of actual measurement. It is depending on radiation workload and utilization the data most securely. 3) The dose rate during exposure are 2-10 mR/hr at out of the door and the control room. 4) The foul smelling and ozone gas production from long exposure of cancer patients cannot be estimated when the room is ill ventilated. (author)

  9. The effect of rotational and translational energy exchange on tracer diffusion in rough hard sphere fluids.

    Science.gov (United States)

    Kravchenko, Olga; Thachuk, Mark

    2011-03-21

    A study is presented of tracer diffusion in a rough hard sphere fluid. Unlike smooth hard spheres, collisions between rough hard spheres can exchange rotational and translational energy and momentum. It is expected that as tracer particles become larger, their diffusion constants will tend toward the Stokes-Einstein hydrodynamic result. It has already been shown that in this limit, smooth hard spheres adopt "slip" boundary conditions. The current results show that rough hard spheres adopt boundary conditions proportional to the degree of translational-rotational energy exchange. Spheres for which this exchange is the largest adopt "stick" boundary conditions while those with more intermediate exchange adopt values between the "slip" and "stick" limits. This dependence is found to be almost linear. As well, changes in the diffusion constants as a function of this exchange are examined and it is found that the dependence is stronger than that suggested by the low-density, Boltzmann result. Compared with smooth hard spheres, real molecules undergo inelastic collisions and have attractive wells. Rough hard spheres model the effect of inelasticity and show that even without the presence of attractive forces, the boundary conditions for large particles can deviate from "slip" and approach "stick."

  10. Rotating UPS installations and dynamic energy storage. Comparison of static and rotating UPS and comparison of dynamic energy storage using batteries - Final Report; Rotierende USV-Anlagen und dynamische Energiespeicherung. Vergleich der statischen mit rotierenden USV-Anlagen und Vergleich der dynamischen Energiespeicherung mit Batterieanlagen - Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Mauchle, P.; Schnyder, G.

    2010-01-15

    As an alternative to the static UPS-Systems (uninterruptible power supply systems), rotating UPS-Systems can be applied. The application and the realisation of rotating UPS-Systems are different to the one of static UPS-Systems. Furthermore at the rotating UPS-Systems is to distinguish, if the UPS-System is realised as a diesel dynamic UPS-System, with an activity up from 400 kVA, or if the dynamic part is limited to the energy storage, with an activity up from 60 kVA. The diesel dynamic UPS-Systems are composed of a synchronous machine, an asynchronous machine with a flywheel, respectively a kinetic module and the diesel engine. The connection to the critical user at the low voltage network occurs using an inductor and the accordant switchgears. The application of a diesel dynamic UPS-System is optimal when it can be connected with an emergency power supply. With the realisation of dynamic energy storages, battery systems can be avoided respectively can be reduced or the lifetime of batteries can be extended. It is only possible to avoid the batteries if the requested autonomous time of the UPS-System is shorter than two minutes. Is an autonomous time longer than 2 minutes necessary, battery systems have to be realised for the energy storage. Thereby dynamic energy storage in parallel to the battery system is useful, because the dynamic energy storage will compensate temporary voltage drops or short power failures. In this way the number of charge and discharge cycles of the battery system will be reduced and therefore the lifetime of the battery will be extended. The use of a dynamic or static UPS system is dependent on the requirements of the powered load. Taking into account various criteria it can be found for each specific application the optimal type of UPS system. (authors)

  11. Barriers for the introduction of bioenergy in the Netherlands

    International Nuclear Information System (INIS)

    Gerlagh, T.; Groenendaal, B.; Van Ree, R.; Dinkelbach, L.; Van Doorn, J.; Hemmes, K.

    2000-01-01

    The use of biomass for energy in the Netherlands is still limited despite the political incentives to make bio-energy a major source of renewable energy. The hesitation of many stake-holders is due to the limited insight into the potential of biomass in the Netherlands and the presence of numerous other barriers. Availability of biomass, emission regulation and waste treatment regulations are considered important barriers. Analyses of their current state show that these barriers are broadly recognised and possibilities to decrease their impact are present. Some barriers with a minor influence so far will be of increasing importance and could be a threat to the development of bio-energy in future. These are the fast liberalising of the energy market and sustainable energy market, the competition with other renewables and the unclear status of the current technology available. Future research should focus on the possibilities to overcome these new barriers. 5 refs

  12. How to perform Energy Trace & BarrierAnalysis (ETBA in industries? Acase study in Isomax Unit of Tehran refinery

    Directory of Open Access Journals (Sweden)

    J Adl

    2006-04-01

    Full Text Available Background and Aims: People, equipments and properties are continuously exposed tonumerous hazards while technology develops. The global increasing rate of accidents and workrelatedinjuries, especially in Iran, is an evidence for these hazards. There are numerous methodsfor hazard analysis such as the Energy Trace & Barrier Analysis (ETBA, which is a process ofanalysis based on system safety for detecting and definition of hazards and also risks that maycause system damage.Method: This is a case study in the Isomax unit of Tehran refinery and allied section. Datecollection and completion of the ETBAsheets were conducted through observation and interviewmethod with experts, walking - talking through method, investigation of technical and operativedocuments.Results: Twelve different kinds of energy and 28 subgroups were investigated. The types ofenergies, existence barriers, vulnerable targets, risk assessment code, and adequacy of barriers aswell as recommendations for decreasing risk level through tolerable risk were identified.Conclusion: The results of this study show potential application of ETBA in different industries,especially chemical industry, which is a method for identification hazards and prevention ofwork-related injuries.

  13. Bound state potential energy surface construction: ab initio zero-point energies and vibrationally averaged rotational constants.

    Science.gov (United States)

    Bettens, Ryan P A

    2003-01-15

    Collins' method of interpolating a potential energy surface (PES) from quantum chemical calculations for reactive systems (Jordan, M. J. T.; Thompson, K. C.; Collins, M. A. J. Chem. Phys. 1995, 102, 5647. Thompson, K. C.; Jordan, M. J. T.; Collins, M. A. J. Chem. Phys. 1998, 108, 8302. Bettens, R. P. A.; Collins, M. A. J. Chem. Phys. 1999, 111, 816) has been applied to a bound state problem. The interpolation method has been combined for the first time with quantum diffusion Monte Carlo calculations to obtain an accurate ground state zero-point energy, the vibrationally average rotational constants, and the vibrationally averaged internal coordinates. In particular, the system studied was fluoromethane using a composite method approximating the QCISD(T)/6-311++G(2df,2p) level of theory. The approach adopted in this work (a) is fully automated, (b) is fully ab initio, (c) includes all nine nuclear degrees of freedom, (d) requires no assumption of the functional form of the PES, (e) possesses the full symmetry of the system, (f) does not involve fitting any parameters of any kind, and (g) is generally applicable to any system amenable to quantum chemical calculations and Collins' interpolation method. The calculated zero-point energy agrees to within 0.2% of its current best estimate. A0 and B0 are within 0.9 and 0.3%, respectively, of experiment.

  14. The Energy Effectiveness Of Crops In Crop Rotation Under Different Soil Tillage Systems

    Directory of Open Access Journals (Sweden)

    Strašil Zdeněk

    2015-09-01

    Full Text Available The paper identifies and compares the energy balance of winter wheat, spring barley and white mustard – all grown in crop rotation under different tillage conditions. The field trial included the conventional tillage (CT method, minimum tillage (MT and a system with no tillage (NT. The energy inputs included both the direct and indirect energy component. Energy outputs are evaluated as gross calorific value (gross heating value of phytomass dry matter of the primary product and the total harvested production. The energy effectiveness (energy output: energy input was selected for evaluation. The greatest energy effectiveness for the primary product was established as 6.35 for barley, 6.04 for wheat and 3.68 for mustard; in the case of total production, it was 9.82 for barley, 10.08 for wheat and 9.72 for mustard. When comparing the different tillage conditions, the greatest energy effectiveness was calculated for the evaluated crops under the MT operation and represented the primary product of wheat at 6.49, barley at 6.69 and mustard at 3.92. The smallest energy effectiveness for the primary product was found in wheat 5.77 and barley 6.10 under the CT option; it was 3.55 for mustard under the option of NT. Throughout the entire cropping pattern, the greatest energy effectiveness was established under the minimum tillage option – 5.70 for the primary product and 10.47 for the total production. On the other hand, the smallest values were calculated under CT – 5.22 for the primary product and 9.71 for total production.

  15. Condensation on superhydrophobic surfaces: the role of local energy barriers and structure length scale.

    Science.gov (United States)

    Enright, Ryan; Miljkovic, Nenad; Al-Obeidi, Ahmed; Thompson, Carl V; Wang, Evelyn N

    2012-10-09

    Water condensation on surfaces is a ubiquitous phase-change process that plays a crucial role in nature and across a range of industrial applications, including energy production, desalination, and environmental control. Nanotechnology has created opportunities to manipulate this process through the precise control of surface structure and chemistry, thus enabling the biomimicry of natural surfaces, such as the leaves of certain plant species, to realize superhydrophobic condensation. However, this "bottom-up" wetting process is inadequately described using typical global thermodynamic analyses and remains poorly understood. In this work, we elucidate, through imaging experiments on surfaces with structure length scales ranging from 100 nm to 10 μm and wetting physics, how local energy barriers are essential to understand non-equilibrium condensed droplet morphologies and demonstrate that overcoming these barriers via nucleation-mediated droplet-droplet interactions leads to the emergence of wetting states not predicted by scale-invariant global thermodynamic analysis. This mechanistic understanding offers insight into the role of surface-structure length scale, provides a quantitative basis for designing surfaces optimized for condensation in engineered systems, and promises insight into ice formation on surfaces that initiates with the condensation of subcooled water.

  16. Encapsulation of Protonated Diamines in a Water-Soluble Chiral, Supramolecular Assembly Allows for Measurement of Hydrogen-Bond Breaking Followed by Nitrogen Inversion/Rotation (NIR)

    Energy Technology Data Exchange (ETDEWEB)

    Meux, Susan C.; Pluth, Michael D.; Bergman, Robert G.; Raymond, Kenneth N.

    2007-09-19

    Amine nitrogen inversion, difficult to observe in aqueous solution, is followed in a chiral, supramolecular host molecule with purely-rotational T-symmetry that reduces the local symmetry of encapsulated monoprotonated diamines and enables the observation and quantification of {Delta}G{double_dagger} for the combined hydrogen-bond breaking and nitrogen inversion rotation (NIR) process. Free energies of activation for the combined hydrogen-bond breaking and NIR process inside of the chiral assembly were determined by the NMR coalescence method. Activation parameters for ejection of the protonated amines from the assembly confirm that the NIR process responsible for the coalescence behavior occurs inside of the assembly rather than by a guest ejection/NIR/re-encapsulation mechanism. For one of the diamines, N,N,N{prime},N{prime}-tetramethylethylenediamine (TMEDA), the relative energy barriers for the hydrogen-bond breaking and NIR process were calculated at the G3(MP2)//B3LYP/6-31++G(d,p) level of theory, and these agreed well with the experimental data.

  17. Decontamination of a rotating cutting tool during operation by means of atmospheric pressure plasmas

    DEFF Research Database (Denmark)

    Leipold, Frank; Kusano, Yukihiro; Hansen, F.

    2010-01-01

    , is used for the experiments. A rotating knife was inoculated with L. innocua. The surface of the rotating knife was partly exposed to an atmospheric pressure dielectric barrier discharge operated in air, where the knife itself served as a ground electrode. The rotation of the knife ensures a treatment...... of the whole cutting tool. A log 5 reduction of L. innocua is obtained after 340 s of plasma operation. The temperature of the knife after treatment was found to be below 30 °C. The design of the setup allows a decontamination during slicing operation....

  18. Earth Rotation

    Science.gov (United States)

    Dickey, Jean O.

    1995-01-01

    The study of the Earth's rotation in space (encompassing Universal Time (UT1), length of day, polar motion, and the phenomena of precession and nutation) addresses the complex nature of Earth orientation changes, the mechanisms of excitation of these changes and their geophysical implications in a broad variety of areas. In the absence of internal sources of energy or interactions with astronomical objects, the Earth would move as a rigid body with its various parts (the crust, mantle, inner and outer cores, atmosphere and oceans) rotating together at a constant fixed rate. In reality, the world is considerably more complicated, as is schematically illustrated. The rotation rate of the Earth's crust is not constant, but exhibits complicated fluctuations in speed amounting to several parts in 10(exp 8) [corresponding to a variation of several milliseconds (ms) in the Length Of the Day (LOD) and about one part in 10(exp 6) in the orientation of the rotation axis relative to the solid Earth's axis of figure (polar motion). These changes occur over a broad spectrum of time scales, ranging from hours to centuries and longer, reflecting the fact that they are produced by a wide variety of geophysical and astronomical processes. Geodetic observations of Earth rotation changes thus provide insights into the geophysical processes illustrated, which are often difficult to obtain by other means. In addition, these measurements are required for engineering purposes. Theoretical studies of Earth rotation variations are based on the application of Euler's dynamical equations to the problem of finding the response of slightly deformable solid Earth to variety of surface and internal stresses.

  19. Some peculiarities of interactions of weakly bound lithium nuclei at near-barrier energies

    Science.gov (United States)

    Kabyshev, A. M.; Kuterbekov, K. A.; Sobolev, Yu G.; Penionzhkevich, Yu E.; Kubenova, M. M.; Azhibekov, A. K.; Mukhambetzhan, A. M.; Lukyanov, S. M.; Maslov, V. A.; Kabdrakhimova, G. D.

    2018-02-01

    This paper presents new experimental data on the total cross sections of 9Li + 28Si reactions at low energies as well as the analysis of previously obtained data for 6,7Li. Based on a large collection of data (authors’ and literature data) we carried out a comparative analysis of the two main experimental interaction cross sections (angular distributions of the differential cross sections and total reaction cross sections) for weakly bound lithium (6-9Li, 11Li) nuclei in the framework of Kox parameterization and the macroscopic optical model. We identified specific features of these interactions and predicted the experimental trend in the total reaction cross sections for Li isotopes at energies close to the Coulomb barrier.

  20. Hindrance of O16+Pb208 fusion at extreme sub-barrier energies

    Science.gov (United States)

    Esbensen, Henning; Mişicu, Şerban

    2007-11-01

    We analyze the fusion data for O16+Pb208 using coupled-channels calculations. We include couplings to the low-lying surface excitations of the projectile and target and study the effect of the (O16,O17) one-neutron pickup. The hindrance of the fusion data that is observed at energies far below the Coulomb barrier cannot be explained by a conventional ion-ion potential and defining the fusion in terms of ingoing-wave boundary conditions (IWBC). We show that the hindrance can be explained fairly well by applying the M3Y double-folding potential which has been corrected with a calibrated, repulsive term that simulates the effect of nuclear incompressibility. We show that the coupling to one-neutron transfer channels plays a crucial role in improving the fit to the data. The best fit is achieved by increasing the transfer strength by 25% relative to the strength that is required to reproduce the one-neutron transfer data. The larger strength is not unrealistic because the calculated inelastic plus transfer cross section is in good agreement with the measured quasielastic cross section. We finally discuss the problem of reproducing the fusion data at energies far above the Coulomb barrier. Here we do not account for the data when we apply the IWBC but the discrepancy is essentially eliminated by applying the M3Y+repulsion potential and a weak, short-ranged imaginary potential.

  1. Rotational Spectrum and Conformational Analysis of N-Methyl-2-Aminoethanol: Insights into the Shape of Adrenergic Neurotransmitters

    Directory of Open Access Journals (Sweden)

    Camilla Calabrese

    2018-02-01

    Full Text Available We describe an experimental and quantum chemical study for the accurate determination of the conformational space of small molecular systems governed by intramolecular non-covalent interactions. The model systems investigated belong to the biological relevant aminoalcohol's family, and include 2-amino-1-phenylethanol, 2-methylamino-1-phenylethanol, noradrenaline, adrenaline 2-aminoethanol, and N-methyl-2-aminoethanol. For the latter molecule, the rotational spectrum in the 6–18 and 59.6–74.4 GHz ranges was recorded in the isolated conditions of a free jet expansion. Based on the analysis of the rotational spectra, two different conformational species and 11 isotopologues were observed and their spectroscopic constants, including 14N-nuclear hyperfine coupling constants and methyl internal rotation barriers, were determined. From the experimental data a structural determination was performed, which was also used to benchmark accurate quantum chemical calculations on the whole conformational space. Atom in molecules and non-covalent interactions theories allowed the characterization of the position of the intramolecular non-covalent interactions and the energies involved, highlighting the subtle balance responsible of the stabilization of all the molecular systems.

  2. A proton polarimeter for beam energies below 300 keV

    International Nuclear Information System (INIS)

    Buchmann, L.

    1990-10-01

    A nuclear polarimeter based on the low energy analyzing power of the 6 Li(p, 3 He)α reaction has been developed and tested for proton energies below E p =300 keV. The polarimeter uses a 6 LiF target evaporated on a water cooled tantalum backing. The target is observed at backwards angles by four silicon surface barrier detectors. The energy dependence of the analyzing power under 130 o for the 6 Li(p, 3 He)α reaction has been determined down to 200 keV. Spin rotation has been observed via a magnetic field incorporated in a Wien filter demonstrating that the polarimeter is operational. (Author) (7 refs., 7 figs.)

  3. Economic impacts of short-rotation woody crops for energy or oriented strand board: a Minnesota case study

    Science.gov (United States)

    William F. Lazarus; Douglas G. Tiffany; Ronald S. Zalesny Jr.; Don E. Riemenschneider

    2011-01-01

    Short-rotation woody crops (SRWC) such as hybrid poplars are becoming increasingly competitive with agriculture on marginal land. The trees can be grown for energy and for traditional uses such as oriented strandboard. Using IMPLAN (Impact Analysis for Planning) software, we modeled the impacts of shifting land use from hay and pasture for cow-calf beef operations to...

  4. Chemistry at molecular junctions: Rotation and dissociation of O2 on the Ag(110) surface induced by a scanning tunneling microscope.

    Science.gov (United States)

    Roy, Sharani; Mujica, Vladimiro; Ratner, Mark A

    2013-08-21

    The scanning tunneling microscope (STM) is a fascinating tool used to perform chemical processes at the single-molecule level, including bond formation, bond breaking, and even chemical reactions. Hahn and Ho [J. Chem. Phys. 123, 214702 (2005)] performed controlled rotations and dissociations of single O2 molecules chemisorbed on the Ag(110) surface at precise bias voltages using STM. These threshold voltages were dependent on the direction of the bias voltage and the initial orientation of the chemisorbed molecule. They also observed an interesting voltage-direction-dependent and orientation-dependent pathway selectivity suggestive of mode-selective chemistry at molecular junctions, such that in one case the molecule underwent direct dissociation, whereas in the other case it underwent rotation-mediated dissociation. We present a detailed, first-principles-based theoretical study to investigate the mechanism of the tunneling-induced O2 dynamics, including the origin of the observed threshold voltages, the pathway dependence, and the rate of O2 dissociation. Results show a direct correspondence between the observed threshold voltage for a process and the activation energy for that process. The pathway selectivity arises from a competition between the voltage-modified barrier heights for rotation and dissociation, and the coupling strength of the tunneling electrons to the rotational and vibrational modes of the adsorbed molecule. Finally, we explore the "dipole" and "resonance" mechanisms of inelastic electron tunneling to elucidate the energy transfer between the tunneling electrons and chemisorbed O2.

  5. Balancing the daylighting and energy performance of solar screens in residential desert buildings: Examination of screen axial rotation and opening aspect ratio

    KAUST Repository

    Sabry, Hanan

    2014-05-01

    Solar screens are typically used to control solar access into building spaces. They proved their usefulness in improving the daylighting and energy performance of buildings in the hot arid desert environments which are endowed with abundance of clear skies.The daylighting and energy performance of solar screens is affected by many parameters. These include screen perforation, depth, reflectivity and color, aspect ratio of openings, shape, tilt angle and rotation. Changing some of these parameters can improve the daylighting performance drastically. However, this can result in increased energy consumption. A balanced solution must be sought, where acceptable daylighting performance would be achieved at minimum energy consumption.This paper aims at defining solar screen designs that achieve visual comfort and at the same time minimum energy consumption in residential desert settings. The study focused on the effect of changing the solar screen axial rotation and the aspect ratio of its openings under the desert clear-sky. The individual and combined effects of changing these parameters were studied.Results of this study demonstrated that a non-rotated solar screen that has wide horizontal openings (aspect ratio of 18:1) proved to be successful in the north and south orientations. Its performance in the east/west orientations was also superior. In contrast, the screen that was rotated along its vertical axis while having small size openings (aspect ratio of 1:1) proved to be more successful in the east/west orientations. Its performance in the north orientation was also good. These solutions enhanced daylighting performance, while maintaining the energy consumption at a minimum.Moreover, it was observed that combining two screen parameters which proved useful in previous studies on daylighting or thermal performance does not add up to better solutions. The combined solutions that were tested in this study did not prove successful in satisfying daylighting and thermal

  6. Effect of toroidal field ripple on the formation of internal transport barriers

    Energy Technology Data Exchange (ETDEWEB)

    Vries, P C de; Hawkes, N C; Challis, C D; Andrew, Y; Beurskens, M; Brix, M; Giroud, C; Zastrow, K-D [EURATOM/UKAEA Fusion Association, Culham Science Centre, Abingdon, OX14 3DB (United Kingdom); Joffrin, E [EFDA-JET CSU, Culham Science Centre, Abingdon, Oxfordshire, OX14 3DB (United Kingdom); Litaudon, X [Association EURATOM-CEA, DSM/DFRC, CEA Cadarache, 13108, St Paul lez Durance (France); Brzozowski, J; Johnson, T [Association EURATOM-VR, Fusion Plasma Physics, EES, KTH, Stockholm (Sweden); Crombe, K [Department of Applied Physics, Ghent University, Ghent (Belgium); Hobirk, J [Max-Planck-Institut fuer Plasmaphysik, Euratom Association, 85748 Garching (Germany); Loennroth, J; Salmi, A [Association Euratom-Tekes, Helsinki University of Technology, PO Box 4100, 02015 TKK (Finland); Tala, T [Association Euratom-Tekes, VTT, PO Box 1000, 02044 VTT (Finland); Yavorskij, V [Institute for Theoretical Physics, Association EURATOM-OEAW, University of Innsbruck (Austria)], E-mail: Peter.de.Vries@jet.uk

    2008-06-15

    The effect of a toroidal field (TF) ripple on the formation and performance of internal transport barriers (ITBs) has been studied in JET. It was found that the TF ripple had a profound effect on the toroidal plasma rotation. An increased TF ripple up to {delta} = 1% led to a lower rotation and reduced the rotational shear in the region where the ITBs were formed. ITB triggering events were observed in all cases and it is thought that the rotational shear may be less important for this process than, for example, the q-profile. However, the increase in the pressure gradient following the ITB trigger was reduced in discharges with a larger TF ripple and consequently a lower rotational shear. This suggests that toroidal rotation and its shear play a role in the growth of the ITB once it has been triggered.

  7. SUBARCSECOND ANALYSIS OF THE INFALLING–ROTATING ENVELOPE AROUND THE CLASS I PROTOSTAR IRAS 04365+2535

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, Nami [The Institute of Physical and Chemical Research (RIKEN), 2-1, Hirosawa, Wako-shi, Saitama 351-0198 (Japan); Oya, Yoko; López-Sepulcre, Ana; Watanabe, Yoshimasa; Yamamoto, Satoshi [Department of Physics, The University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan); Sakai, Takeshi [Department of Communication Engineering and Informatics, Graduate School of Informatics and Engineering, The University of Electro-Communications, Chofugaoka, Chofu, Tokyo 182-8585 (Japan); Hirota, Tomoya [National Astronomical Observatory of Japan, Osawa, Mitaka, Tokyo 181-8588 (Japan); Aikawa, Yuri [Center for Computational Science, University of Tsukuba, Tsukuba, Ibaraki 305-8577 (Japan); Ceccarelli, Cecilia; Lefloch, Bertrand; Kahane, Claudine [Universite de Grenoble Alpes, IPAG, F-38000 Grenoble (France); Caux, Emmanuel; Vastel, Charlotte [Universite de Toulouse, UPS-OMP, IRAP, Toulouse (France)

    2016-04-01

    Subarcsecond images of the rotational line emission of CS and SO have been obtained toward the Class I protostar IRAS 04365+2535 in TMC-1A with ALMA. A compact component around the protostar is clearly detected in the CS and SO emission. The velocity structure of the compact component of CS reveals infalling–rotating motion conserving the angular momentum. It is well explained by a ballistic model of an infalling–rotating envelope with the radius of the centrifugal barrier (one-half of the centrifugal radius) of 50 au, although the distribution of the infalling gas is asymmetric around the protostar. The distribution of SO is mostly concentrated around the radius of the centrifugal barrier of the simple model. Thus, a drastic change in chemical composition of the gas infalling onto the protostar is found to occur at a 50 au scale probably due to accretion shocks, demonstrating that the infalling material is significantly processed before being delivered into the disk.

  8. Renewable energy clusters recurring barriers to cluster development in eleven countries

    CERN Document Server

    Jaegersberg, Gudrun

    2017-01-01

    Taking eleven countries in Europe, Canada, South Africa, America, Latin America and Australia, this book discusses recurring barriers to cluster development in the renewable energy sector. The authors look at the real-world dynamics and tensions between stakeholders on the ground, with a particular focus on the relationships between SMEs and other actors. This trans-regional study is unique in its scale and scope, drawing on a decade of field research to show how by learning from the successes and failures of other clusters, costs and risk can be reduced. The book fills a significant gap in the literature for policymakers, managers and economic developers in a key market.

  9. Symbolic derivation of high-order Rayleigh-Schroedinger perturbation energies using computer algebra: Application to vibrational-rotational analysis of diatomic molecules

    Energy Technology Data Exchange (ETDEWEB)

    Herbert, John M. [Kansas State Univ., Manhattan, KS (United States). Dept. of Chemistry

    1997-01-01

    Rayleigh-Schroedinger perturbation theory is an effective and popular tool for describing low-lying vibrational and rotational states of molecules. This method, in conjunction with ab initio techniques for computation of electronic potential energy surfaces, can be used to calculate first-principles molecular vibrational-rotational energies to successive orders of approximation. Because of mathematical complexities, however, such perturbation calculations are rarely extended beyond the second order of approximation, although recent work by Herbert has provided a formula for the nth-order energy correction. This report extends that work and furnishes the remaining theoretical details (including a general formula for the Rayleigh-Schroedinger expansion coefficients) necessary for calculation of energy corrections to arbitrary order. The commercial computer algebra software Mathematica is employed to perform the prohibitively tedious symbolic manipulations necessary for derivation of generalized energy formulae in terms of universal constants, molecular constants, and quantum numbers. As a pedagogical example, a Hamiltonian operator tailored specifically to diatomic molecules is derived, and the perturbation formulae obtained from this Hamiltonian are evaluated for a number of such molecules. This work provides a foundation for future analyses of polyatomic molecules, since it demonstrates that arbitrary-order perturbation theory can successfully be applied with the aid of commercially available computer algebra software.

  10. Rotational excitation of N2 by electron impact: 1-4 eV

    International Nuclear Information System (INIS)

    Wong, S.F.; Dube, L.

    1978-01-01

    Rotational and rotational-vibrational (v = 0 → 1) excitation in N 2 have been studied with a crossed-beam electron-impact apparatus. In the energy range 1-4 eV, the elastic and vibrational energy-loss peaks show large rotational broadening compared with the apparatus profile (full width at half-maximum, 18 meV). The branching ratios for rotational transitions with Δj = 0, +- 2, +- 4 are obtained with a line-shape analysis applied to the energy-loss profiles. The results for rotational-vibrational excitation at 2.27 eV and scattering angles 30-90 0 are in good agreement with the calculations using the resonant dπ waves and the rotational impulse approximation. The corresponding results for pure rotational excitation show that the branches with Δj = +- 2 and +- 4 are predominantly excited via resonances, while the branch with Δj = 0 contains a large contribution from direct scattering. The absolute rotational cross sections for Δj = +- 4 are measured; they exhibit a large magnitude (10 -16 cm 2 ) and peak and valley structures in the 1-4 eV range, reminiscent of well-known resonant vibrational excitation. The energy dependence and the absolute magnitude of the rotational cross sections for Δj = +- 4 can be understood in terms of a ''boomerang'' calculation. A comparison of the experiment with the relevant theoretical calculations is made

  11. Development of simplified rotating plug seal structure

    International Nuclear Information System (INIS)

    Ueta, M.; Ichimiya, M.; Kanaoka, T.; Sekiya, H.; Ueda, S.; Ishibashi, S.

    1991-01-01

    We studied a compact and simplified rotating plug seal structure and conducted experiments for key elements of the concept such us the mechanical seal structure and sodium deposit prevention system. Good characteristics were confirmed for the mechanical seal structure, which utilizes an elastomer seal and thin lathe bearing. Applicability of the density barrier concept was also confirmed as the sodium deposit prevention system. This concept can be applied to actual plants. (author)

  12. Energy efficiency in social housing: Opportunities and barriers from a case study in Brazil

    International Nuclear Information System (INIS)

    Bodach, Susanne; Hamhaber, J.

    2010-01-01

    This paper investigates the energy efficiency in a segment of the building sector in emerging countries by analyzing and evaluating the energy efficiency of a social housing project in Brazil. Energy efficiency measures and bioclimatic design strategies are developed in order to improve thermal comfort in this social housing project and to reduce the energy consumption and expenses of their residents. The institutional barriers and constraints toward higher efficiency are described. The results of this study show that there is a high potential to increase energy efficiency in social housing in emerging countries like Brazil. The implementation and consideration of the energy efficiency measures and policy recommendations would contribute substantially to the goal to dampen the fast growth of energy demand in these countries. Moreover the improvement of energy efficiency in the social housing sector could be a driver for market transformation towards more sustainability in the whole building sector. - Research highlights: →There is a high potential to increase energy efficiency in social housing in Brazil. →Energy-efficient social housing would contribute substantially to dampen the fast growth of energy consumption in emerging countries like Brazil. →Implementation of energy efficiency would improve the income situation of the poorest strata of the population.

  13. CdS films deposited by chemical bath under rotation

    International Nuclear Information System (INIS)

    Oliva-Aviles, A.I.; Patino, R.; Oliva, A.I.

    2010-01-01

    Cadmium sulfide (CdS) films were deposited on rotating substrates by the chemical bath technique. The effects of the rotation speed on the morphological, optical, and structural properties of the films were discussed. A rotating substrate-holder was fabricated such that substrates can be taken out from the bath during the deposition. CdS films were deposited at different deposition times (10, 20, 30, 40 and 50 min) onto Corning glass substrates at different rotation velocities (150, 300, 450, and 600 rpm) during chemical deposition. The chemical bath was composed by CdCl 2 , KOH, NH 4 NO 3 and CS(NH 2 ) 2 as chemical reagents and heated at 75 deg. C. The results show no critical effects on the band gap energy and the surface roughness of the CdS films when the rotation speed changes. However, a linear increase on the deposition rate with the rotation energy was observed, meanwhile the stoichiometry was strongly affected by the rotation speed, resulting a better 1:1 Cd/S ratio as speed increases. Rotation effects may be of interest in industrial production of CdTe/CdS solar cells.

  14. CdS films deposited by chemical bath under rotation

    Energy Technology Data Exchange (ETDEWEB)

    Oliva-Aviles, A.I., E-mail: aoliva@mda.cinvestav.mx [Centro de Investigacion y de Estudios Avanzados Unidad Merida, Departamento de Fisica Aplicada. A.P. 73-Cordemex, 97310 Merida, Yucatan (Mexico); Patino, R.; Oliva, A.I. [Centro de Investigacion y de Estudios Avanzados Unidad Merida, Departamento de Fisica Aplicada. A.P. 73-Cordemex, 97310 Merida, Yucatan (Mexico)

    2010-08-01

    Cadmium sulfide (CdS) films were deposited on rotating substrates by the chemical bath technique. The effects of the rotation speed on the morphological, optical, and structural properties of the films were discussed. A rotating substrate-holder was fabricated such that substrates can be taken out from the bath during the deposition. CdS films were deposited at different deposition times (10, 20, 30, 40 and 50 min) onto Corning glass substrates at different rotation velocities (150, 300, 450, and 600 rpm) during chemical deposition. The chemical bath was composed by CdCl{sub 2}, KOH, NH{sub 4}NO{sub 3} and CS(NH{sub 2}){sub 2} as chemical reagents and heated at 75 deg. C. The results show no critical effects on the band gap energy and the surface roughness of the CdS films when the rotation speed changes. However, a linear increase on the deposition rate with the rotation energy was observed, meanwhile the stoichiometry was strongly affected by the rotation speed, resulting a better 1:1 Cd/S ratio as speed increases. Rotation effects may be of interest in industrial production of CdTe/CdS solar cells.

  15. Deep inelastic scattering near the Coulomb barrier

    International Nuclear Information System (INIS)

    Gehring, J.; Back, B.; Chan, K.

    1995-01-01

    Deep inelastic scattering was recently observed in heavy ion reactions at incident energies near and below the Coulomb barrier. Traditional models of this process are based on frictional forces and are designed to predict the features of deep inelastic processes at energies above the barrier. They cannot be applied at energies below the barrier where the nuclear overlap is small and friction is negligible. The presence of deep inelastic scattering at these energies requires a different explanation. The first observation of deep inelastic scattering near the barrier was in the systems 124,112 Sn + 58,64 Ni by Wolfs et al. We previously extended these measurements to the system 136 Xe + 64 Ni and currently measured the system 124 Xe + 58 Ni. We obtained better statistics, better mass and energy resolution, and more complete angular coverage in the Xe + Ni measurements. The cross sections and angular distributions are similar in all of the Sn + Ni and Xe + Ni systems. The data are currently being analyzed and compared with new theoretical calculations. They will be part of the thesis of J. Gehring

  16. Lattice vibrations and barrier to hindered rotation in lithium tetradeuteroaluminate by 2H, 7Li and 27Al NMR

    International Nuclear Information System (INIS)

    Tarasov, V.P.; Kirakosyan, G.A.

    1996-01-01

    Temperature dependences of 2 H, 7 Li, 27 Al NMR line shape in LiAlD 4 lithium polycrystal tetradeuteroaluminate in the range of 103-420 K have been studied. The quadrupole bond constants and asymmetry parameters of electric field gradient tensor have been measured. The frequencies of lattice vibrations have been evaluated in the framework of the Buyer model. From temperature dependences of spin-lattice relaxation time and 2 H NMR line shape the activation energies of AlD 4 anion decelerated rotation, amounting to 74 and 62 k J/mol respectively, have been determined. 15 refs.; 5 figs.; 2 tabs

  17. Short Rotation Crops in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Wright, L L

    1998-06-04

    The report is based primarily on the results of survey questions sent to approximately 60 woody and 20 herbaceous crop researchers in the United States and on information from the U.S. Department of Energy's Bioenergy Feedstock Development Program. Responses were received from 13 individuals involved in woody crops research or industrial commercialization (with 5 of the responses coming from industry). Responses were received from 11 individuals involved in herbaceous crop research. Opinions on market incentives, technical and non-technical barriers, and highest priority research and development areas are summarized in the text. Details on research activities of the survey responders are provided as appendices to the paper. Woody crops grown as single-stem systems (primarily Populus and Eucalyptus species) are perceived to have strong pulp fiber and oriented strand board markets, and the survey responders anticipated that energy will comprise 25% or less of the utilization of single-stem short-rotation woody crops between now and 2010. The only exception was a response from California where a substantial biomass energy market does currently exist. Willows (Salix species) are only being developed for energy and only in one part of the United States at present. Responses from herbaceous crop researchers suggested frustration that markets (including biomass energy markets) do not currently exist for the crop, and it was the perception of many that federal incentives will be needed to create such markets. In all crops, responses indicate that a wide variety of research and development activities are needed to enhance the yields and profitability of the crops. Ongoing research activities funded by the U.S. Department of Energy's Bioenergy Feedstock Development Program are described in an appendix to the paper.

  18. A novel approach for barriers to industrial energy efficiency

    NARCIS (Netherlands)

    Cagno, E.; Worrell, E.; Trianni, A.; Pugliese, G.

    2013-01-01

    A critical review of the literature highlighted the need for a new taxonomy encompassing the most relevant barriers stemmed from previous studies, and accounting for interactions and independences of the barriers to avoid overlaps and implicit interactions. Based on an extensive literature review

  19. Internal rotation in trifluoromethylsulfur pentafluoride: CF3SF5 by Fourier transform microwave spectroscopy

    Science.gov (United States)

    Hirota, Eizi; Kawasima, Yoshiyuki; Ajiki, Ken

    2017-12-01

    Trifluoromethylsulfur pentafluoride CF3SF5, which has been attracting much attention because of its unusually large global warming potential, was investigated by Fourier transform microwave spectroscopy in order to determine the twelve-fold potential barrier to internal rotation in this molecule. We have found the V12 value to be close to zero. Relaxation among internal-rotation and overall-rotation levels was found inhomogeneous, resulting in distributions quite different from thermal in low-temperature molecular beam, which might affect significantly thermodynamic properties of the molecule. Rotational spectra of the 13C species and the 34S species were also observed in natural abundance, leading to the rs Csbnd S bond length of 1.8808 (7) Å.

  20. Thermochemical and physical evaluation of poplar genotypes as short rotation forestry crops for energy use

    International Nuclear Information System (INIS)

    Monedero, Esperanza; Hernández, Juan José; Cañellas, Isabel; Otero, Jose María; Sixto, Hortensia

    2016-01-01

    Highlights: • The combustion properties of poplar genotypes harvested from three different sites were analyzed. • Both the genotype and the locations affect the expected combustion behavior. • Among the poplar genotypes, ‘Monviso’ and ‘Viriato’ are expected to have better combustion behavior. • No operating problems derived from fouling/corrosion are expected for any of the genotypes. - Abstract: Short rotation plantations of fast-growing species provide a promising way to produce heat and electricity from renewable sources. The thermo-chemical and physical properties of different genotypes of poplar in short rotation forestry crops grown at three locations with different climatic and edaphic characteristics as well as planting density, have been determined in order to characterize the most appropriate biomass in terms of energy potential. The planting density was 6666 or 13,333 trees/ha (depending on the location) in a rotation of three-four years and the analysis was carried out at the end of the first rotation. For all the genotypes, experimental tests to quantify the moisture content, particle size distribution, bulk density, heating value, ash content and composition as well as the volatile matter were performed. In addition, natural air drying of biomass (stem and branches) was studied in two locations with the aim of determining the humidity loss during raw storage. A significant effect of the genotype and the planting density on the biomass properties was observed. The results obtained indicate that ‘Monviso’ and ‘Viriato’ are the most suitable genotypes. No operational problems related to ash fouling and deposition in combustion devices are expected for any of the genotypes studied.

  1. Fusion hindrance at deep sub-barrier energies for the 11B+197Au system

    Science.gov (United States)

    Shrivastava, A.; Mahata, K.; Nanal, V.; Pandit, S. K.; Parkar, V. V.; Rout, P. C.; Dokania, N.; Ramachandran, K.; Kumar, A.; Chatterjee, A.; Kailas, S.

    2017-09-01

    Fusion cross sections for the 11B+197Au system have been measured at energies around and deep below the Coulomb barrier, to probe the occurrence of fusion hindrance in case of asymmetric systems. A deviation with respect to the standard coupled channels calculations has been observed at the lowest energy. The results have been compared with an adiabatic model calculation that considers a damping of the coupling strength for a gradual transition from sudden to adiabatic regime at very low energies. The data could be explained without inclusion of the damping factor. This implies that the influence of fusion hindrance is not significant within the measured energy range for this system. The present result is consistent with the observed trend between the degree of fusion hindrance and the charge product that reveals a weaker influence of hindrance on fusion involving lighter projectiles on heavy targets.

  2. Rotational dynamics with Tracker

    International Nuclear Information System (INIS)

    Eadkhong, T; Danworaphong, S; Rajsadorn, R; Jannual, P

    2012-01-01

    We propose the use of Tracker, freeware for video analysis, to analyse the moment of inertia (I) of a cylindrical plate. Three experiments are performed to validate the proposed method. The first experiment is dedicated to find the linear coefficient of rotational friction (b) for our system. By omitting the effect of such friction, we derive I for a cylindrical plate rotated around its central axis from the other two experiments based on the relation between torque and angular acceleration of rotational motion and conservation of energy. Movies of the rotating plate and hung masses are recorded. As a result, we have the deviation of I from its theoretical value of 0.4% and 3.3%, respectively. Our setup is completely constructed from locally available inexpensive materials and the experimental results indicate that the system is highly reliable. This work should pave the way for those who prefer to build a similar setup from scratch at relatively low cost compared to commercial units. (paper)

  3. Spin Chirality of Cu3 and V3 Nanomagnets. 1. Rotation Behavior of Vector Chirality, Scalar Chirality, and Magnetization in the Rotating Magnetic Field, Magnetochiral Correlations.

    Science.gov (United States)

    Belinsky, Moisey I

    2016-05-02

    The rotation behavior of the vector chirality κ, scalar chirality χ, and magnetization M in the rotating magnetic field H1 is considered for the V3 and Cu3 nanomagnets, in which the Dzialoshinsky-Moriya coupling is active. The polar rotation of the field H1 of the given strength H1 results in the energy spectrum characterized by different vector and scalar chiralities in the ground and excited states. The magnetochiral correlations between the vector and scalar chiralities, energy, and magnetization in the rotating field were considered. Under the uniform polar rotation of the field H1, the ground-state chirality vector κI performs sawtooth oscillations and the magnetization vector MI performs the sawtooth oscillating rotation that is accompanied by the correlated transformation of the scalar chirality χI. This demonstrates the magnetochiral effect of the joint rotation behavior and simultaneous frustrations of the spin chiralities and magnetization in the rotating field, which are governed by the correlation between the chiralities and magnetization.

  4. Internal barrier discharges in JET and their sensitivity to edge conditions

    International Nuclear Information System (INIS)

    Sips, A.C.C.

    2001-01-01

    Experiments in JET have concentrated on steady state discharges with internal transport barriers. The internal transport barriers are formed during the current rise phase of the discharge with low magnetic shear in the centre and with high additional heating power. In order to achieve stability against disruptions at high pressure peaking, typical for ITB discharges, the pressure profile can be broadened with a H-mode transport barrier at the edge of the plasma. However, the strong increase in edge pressure during an ELM free H-mode weakens the internal transport barrier due to a reduction of the rotational shear and pressure gradient at the ITB location. In addition, type I ELM activity, associated with a high edge pedestal pressure, leads to a collapse of the ITB with the input powers available in JET. The best ITB discharges are obtained with input power control to reduce to core pressure, and with the edge of the plasma controlled by argon gas dosing. These discharges achieve steady conditions for several energy confinement times with H97 confinement enhancement factors of 1.2-1.6 at line average densities around 30%-40% of the Greenwald density. This is at much lower density (typically factor 2 to 3) compared to standard H-mode discharges in JET. Increasing the density, using additional deuterium gas dosing or shallow pellet fueling has not been successful so far. A possible route to higher densities should maintain the type III ELM's towards high edge density, giving scope for future experiments in JET. (author)

  5. Nuclear reorganization barriers to electron transfer

    International Nuclear Information System (INIS)

    Sutin, N.; Brunschwig, B.S.; Creutz, C.; Winkler, J.R.

    1988-01-01

    The nuclear barrier to electron transfer arises from the need for reorganization of intramolecular and solvent internuclear distances prior to electron transfer. For reactions with relatively small driving force (''normal'' free-energy region) the nuclear factors and rates increase as intrinsic inner-shell and outer-shell barriers decrease; this is illustrated by data for transition metal complexes in their ground electronic states. By contrast, in the inverted free-energy region, rates and nuclear factors decrease with decreasing ''intrinsic'' barriers; this is illustrated by data for the decay of charge-transfer excited states. Several approaches to the evaluation of the outer-shell barrier are explored in an investigation of the distance dependence of the nuclear factor in intramolecular electron-transfer processes. 39 refs., 14 figs., 3 tabs

  6. Spin dependence of rotational damping by the rotational plane mapping method

    Energy Technology Data Exchange (ETDEWEB)

    Leoni, S; Bracco, A; Million, B [Milan Univ. (Italy). Ist. di Fisica; Herskind, B; Dossing, T; Rasmussen, P [Niels Bohr Inst., Copenhagen (Denmark); Bergstrom, M; Brockstedt, A; Carlsson, H; Ekstrom, P; Nordlund, A; Ryde, H [Lund Univ. (Sweden). Dept. of Physics; Ingebretsen, F; Tjom, P O [Oslo Univ. (Norway); Lonnroth, T [Aabo Akademi, Turku (Finland). Dept. of Physics

    1992-08-01

    In the study of deformed nuclei by gamma spectroscopy, the large quadrupole transition strength known from rotational bands at high excitation energy may be distributed over all final states of a given parity within an interval defined as the rotational damping width {Gamma}{sub rot} The method of rotational plane mapping extracts a value of {Gamma}{sub rot} from the width of valleys in certain planes in the grid plots of triple gamma coincidence data sets. The method was applied to a high spin triple data set on {sup 162,163}Tm taken with NORDBALL at the tandem accelerator of the Niels Bohr Institute, and formed in the reaction {sup 37}Cl + {sup 130}Te. The value {Gamma}{sub rot} = 85 keV was obtained. Generally, experimental values seem to be lower than theoretical predictions, although the only calculation made was for {sup 168}Yb. 6 refs., 3 figs.

  7. Forced vibrations of rotating circular cylindrical shells

    International Nuclear Information System (INIS)

    Igawa, Hirotaka; Maruyama, Yoshiyuki; Endo, Mitsuru

    1995-01-01

    Forced vibrations of rotating circular cylindrical shells are investigated. Basic equations, including the effect of initial stress due to rotation, are formulated by the finite-element method. The characteristic relations for finite elements are derived from the energy principle by considering the finite strain. The equations of motion can be separated into quasi-static and dynamic ones, i.e., the equations in the steady rotating state and those in the vibration state. Radial concentrated impulses are considered as the external dynamic force. The transient responses of circular cylindrical shells are numerically calculated under various boundary conditions and rotating speeds. (author)

  8. Climate impact and energy efficiency from electricity generation through anaerobic digestion or direct combustion of short rotation coppice willow

    International Nuclear Information System (INIS)

    Ericsson, Niclas; Nordberg, Åke; Sundberg, Cecilia; Ahlgren, Serina; Hansson, Per-Anders

    2014-01-01

    Highlights: • Using LCA, CHP from willow use in biogas was compared with direct combustion. • Direct combustion was ninefold more energy-efficient. • Biogas had a much greater cooling effect on global mean surface temperature. • The effects of soil carbon changes on temperature over time differed. • Biogas had long-term temperature effects, direct combustion short-term effects. - Abstract: Short rotation coppice willow is an energy crop used in Sweden to produce electricity and heat in combined heat and power plants. Recent laboratory-scale experiments have shown that SRC willow can also be used for biogas production in anaerobic digestion processes. Here, life cycle assessment is used to compare the climate impact and energy efficiency of electricity and heat generated by these measures. All energy inputs and greenhouse gas emissions, including soil organic carbon fluxes were included in the life cycle assessment. The climate impact was determined using time-dependent life cycle assessment methodology. Both systems showed a positive net energy balance, but the direct combustion system delivered ninefold more energy than the biogas system. Both systems had a cooling effect on the global mean surface temperature change. The cooling impact per hectare from the biogas system was ninefold higher due to the carbon returned to soil with the digestate. Compensating the lower energy production of the biogas system with external energy sources had a large impact on the result, effectively determining whether the biogas scenario had a net warming or cooling contribution to the global mean temperature change per kWh of electricity. In all cases, the contribution to global warming was lowered by the inclusion of willow in the energy system. The use of time-dependent climate impact methodology shows that extended use of short rotation coppice willow can contribute to counteract global warming

  9. Mode cross coupling observations with a rotation sensor

    Science.gov (United States)

    Nader-Nieto, M. F.; Igel, H.; Ferreira, A. M.; Al-Attar, D.

    2013-12-01

    The Earth's free oscillations induced by large earthquakes have been one of the most important ways to measure the Earth's internal structure and processes. They provide important large scale constraints on a variety of elastic parameters, attenuation and density of the Earth's deep interior. The potential of rotational seismic records for long period seismology was proven useful as a complement to traditional measurements in the study of the Earth's free oscillations. Thanks to the high resolution of the G-ring laser located at Geodetic Observatory Wettzell, Germany, we are now able to study the spectral energy generated by rotations in the low frequency range. On a SNREI Earth, a vertical component rotational sensor is primarily excited by horizontally polarised shear motions (SH waves, Love waves) with theoretically no sensitivity to compressional waves and conversions (P-SV) and Rayleigh waves. Consequently, in the context of the Earth's normal modes, this instrument detects mostly toroidal modes. Here, we present observations of spectral energy of both toroidal and spheroidal normal modes in the G-ring Laser records of one of the largest magnitude events recently recorded: Tohoku-Oki, Japan, 2011. In an attempt to determine the mechanisms responsible for spheroidal energy in the vertical axes rotational spectra, we first rule out instrumental effects as well as the effect of local heterogeneity. Second, we carry out a simulation of an ideal rotational sensor taking into account the effects of the Earth's daily rotation, its hydrostatic ellipticity and structural heterogeneity, finding a good fit to the data. Simulations considering each effect separately are performed in order to evaluate the sensitivity of rotational motions to global effects with respect to traditional translation measurements.

  10. Electron scattering by CO2: Elastic scattering, rotational excitation, and excitation of the asymmetric stretch at 10 eV impact energy

    International Nuclear Information System (INIS)

    Thirumalai, D.; Onda, K.; Truhlar, D.G.

    1981-01-01

    Coupled-channels calculations based on an effective potential are presented for electron scattering by CO 2 at 10 eV impact energy. The processes studied are pure elastic scattering, rotational excitation, and vibrational excitation of the asymmetric stretch; the vibrational excitation is always accompanied by rotational excitation. The quantities calculated are differential, partial, integral, and momentum transfer cross sections, both state to state and summed over final rotational states for a given final vibrational level. The effective potential is based on the INDOX2/1s method for the static and polarization potentials and the semiclassical exchange approximation for the exchange potential. There are no empirical parameters. The present calculations are compared to experiment and to previous calculations where available, and we also perform calculations with an altered polarization potential to further elucidate the reasons for the differences from one of the previous calculations. The agreement of the present results with the experimental rotationally summed, vibrationally inelastic differential cross section is excellent

  11. Pulse-height response of silicon surface-barrier detectors to high-energy heavy ions

    International Nuclear Information System (INIS)

    Smith, G.D.

    1973-01-01

    The pulse-height defect (PHD) of high-energy heavy ions in silicon surface-barrier detectors can be divided into three components: (1) energy loss in the gold-surface layer, (2) a nuclear-stopping defect, and (3) a defect due to recombination of electron-hole pairs in the plasma created by the heavy ion. The plasma recombination portion of the PHD was the subject of this study using the variation of the PHD with (1) the angle of incidence of incoming heavy ions, and (2) changes in the detector bias. The Tandem Van de Graaff accelerator at Argonne National Laboratory was used to produce scattered beam ions ( 32 S, 35 Cl) and heavy target recoils (Ni, Cu, 98 Mo, Ag, Au) at sufficient energies to produce a significant recombination defect. The results confirm the existence of a recombination zone at the front surface of these detectors and the significance of plasma recombination as a portion of the pulse-height defect. (Diss. Abstr. Int., B)

  12. Stochastic Hydrodynamic Synchronization in Rotating Energy Landscapes

    OpenAIRE

    Koumakis, N.; Di Leonardo, R.

    2013-01-01

    Hydrodynamic synchronization provides a general mechanism for the spontaneous emergence of coherent beating states in independently driven mesoscopic oscillators. A complete physical picture of those phenomena is of definite importance to the understanding of biological cooperative motions of cilia and flagella. Moreover, it can potentially suggest novel routes to exploit synchronization in technological applications of soft matter. We demonstrate that driving colloidal particles in rotating ...

  13. Quantum instability in the kicked rotator with rank-one perturbation

    International Nuclear Information System (INIS)

    Milek, B.; Seba, P.

    1990-03-01

    We show that the quasi-energy spectrum of the kicked quantum rotator with rank-one perturbation is singularly continous under certain conditions. The exotic quasi-energy eigenstates, given analytically within this model, are calculated in a basis of 2x10 6 rotator states and their self-similarity property is demonstrated. (orig.)

  14. Efficient sampling over rough energy landscapes with high barriers: A combination of metadynamics with integrated tempering sampling

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Y. Isaac [Institute of Theoretical and Computational Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Zhang, Jun; Che, Xing; Yang, Lijiang; Gao, Yi Qin, E-mail: gaoyq@pku.edu.cn [Institute of Theoretical and Computational Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Biodynamic Optical Imaging Center, Peking University, Beijing 100871 (China)

    2016-03-07

    In order to efficiently overcome high free energy barriers embedded in a complex energy landscape and calculate overall thermodynamics properties using molecular dynamics simulations, we developed and implemented a sampling strategy by combining the metadynamics with (selective) integrated tempering sampling (ITS/SITS) method. The dominant local minima on the potential energy surface (PES) are partially exalted by accumulating history-dependent potentials as in metadynamics, and the sampling over the entire PES is further enhanced by ITS/SITS. With this hybrid method, the simulated system can be rapidly driven across the dominant barrier along selected collective coordinates. Then, ITS/SITS ensures a fast convergence of the sampling over the entire PES and an efficient calculation of the overall thermodynamic properties of the simulation system. To test the accuracy and efficiency of this method, we first benchmarked this method in the calculation of ϕ − ψ distribution of alanine dipeptide in explicit solvent. We further applied it to examine the design of template molecules for aromatic meta-C—H activation in solutions and investigate solution conformations of the nonapeptide Bradykinin involving slow cis-trans isomerizations of three proline residues.

  15. Deep inelastic scattering near the Coulomb barrier

    Energy Technology Data Exchange (ETDEWEB)

    Gehring, J.; Back, B.; Chan, K. [and others

    1995-08-01

    Deep inelastic scattering was recently observed in heavy ion reactions at incident energies near and below the Coulomb barrier. Traditional models of this process are based on frictional forces and are designed to predict the features of deep inelastic processes at energies above the barrier. They cannot be applied at energies below the barrier where the nuclear overlap is small and friction is negligible. The presence of deep inelastic scattering at these energies requires a different explanation. The first observation of deep inelastic scattering near the barrier was in the systems {sup 124,112}Sn + {sup 58,64}Ni by Wolfs et al. We previously extended these measurements to the system {sup 136}Xe + {sup 64}Ni and currently measured the system {sup 124}Xe + {sup 58}Ni. We obtained better statistics, better mass and energy resolution, and more complete angular coverage in the Xe + Ni measurements. The cross sections and angular distributions are similar in all of the Sn + Ni and Xe + Ni systems. The data are currently being analyzed and compared with new theoretical calculations. They will be part of the thesis of J. Gehring.

  16. Collisions between heavy nuclei near the barrier

    International Nuclear Information System (INIS)

    Henning, W.

    1988-05-01

    Detailed information has recently become available on the reaction behavior in very heavy nuclear systems close to the Coulomb barrier. Starting from an experimental study of the distribution of the reaction strength above and below the barrier, the dominant reaction channels of quasi-elastic and strongly-damped processes are examined. With decreasing incident energy, the sub-barrier collisions are increasingly dominated by quasi-elastic processes. From the division of internal excitation energy, new information is obtained on the nature of the dissipative processes. (orig.)

  17. Production of internal transport barriers via self-generated mean flows in Alcator C-Moda)

    Science.gov (United States)

    Fiore, C. L.; Ernst, D. R.; Podpaly, Y. A.; Mikkelsen, D.; Howard, N. T.; Lee, Jungpyo; Reinke, M. L.; Rice, J. E.; Hughes, J. W.; Ma, Y.; Rowan, W. L.; Bespamyatnov, I.

    2012-05-01

    New results suggest that changes observed in the intrinsic toroidal rotation influence the internal transport barrier (ITB) formation in the Alcator C-Mod tokamak [E. S. Marmar and Alcator C-Mod group, Fusion Sci. Technol. 51, 261 (2007)]. These arise when the resonance for ion cyclotron range of frequencies (ICRF) minority heating is positioned off-axis at or outside of the plasma half-radius. These ITBs form in a reactor relevant regime, without particle or momentum injection, with Ti ≈ Te, and with monotonic q profiles (qmin 1.5 × 105 rad/s) in the region where the ITB foot is observed. Gyrokinetic analyses indicate that this spontaneous shearing rate is comparable to the linear ion temperature gradient (ITG) growth rate at the ITB location and is sufficient to reduce the turbulent particle and energy transport. New and detailed measurement of the ion temperature demonstrates that the radial profile flattens as the ICRF resonance position moves off axis, decreasing the drive for the ITG the instability as well. These results are the first evidence that intrinsic rotation can affect confinement in ITB plasmas.

  18. Influence of average ion energy and atomic oxygen flux per Si atom on the formation of silicon oxide permeation barrier coatings on PET

    Science.gov (United States)

    Mitschker, F.; Wißing, J.; Hoppe, Ch; de los Arcos, T.; Grundmeier, G.; Awakowicz, P.

    2018-04-01

    The respective effect of average incorporated ion energy and impinging atomic oxygen flux on the deposition of silicon oxide (SiO x ) barrier coatings for polymers is studied in a microwave driven low pressure discharge with additional variable RF bias. Under consideration of plasma parameters, bias voltage, film density, chemical composition and particle fluxes, both are determined relative to the effective flux of Si atoms contributing to film growth. Subsequently, a correlation with barrier performance and chemical structure is achieved by measuring the oxygen transmission rate (OTR) and by performing x-ray photoelectron spectroscopy. It is observed that an increase in incorporated energy to 160 eV per deposited Si atom result in an enhanced cross-linking of the SiO x network and, therefore, an improved barrier performance by almost two orders of magnitude. Furthermore, independently increasing the number of oxygen atoms to 10 500 per deposited Si atom also lead to a comparable barrier improvement by an enhanced cross-linking.

  19. Symmetry breaking in small rotating clouds of trapped ultracold Bose atoms

    International Nuclear Information System (INIS)

    Dagnino, D.; Barberan, N.; Riera, A.; Osterloh, K.; Lewenstein, M.

    2007-01-01

    We study the signatures of rotational and phase symmetry breaking in small rotating clouds of trapped ultracold Bose atoms by looking at rigorously defined condensate wave function. Rotational symmetry breaking occurs in narrow frequency windows, where energy degeneracy between the lowest energy states of different total angular momentum takes place. This leads to a complex condensate wave function that exhibits vortices clearly seen as holes in the density, as well as characteristic local phase patterns, reflecting the appearance of vorticities. Phase symmetry (or gauge symmetry) breaking, on the other hand, is clearly manifested in the interference of two independent rotating clouds

  20. Rotational-vibrational states of nonaxial deformable even-even nuclei

    International Nuclear Information System (INIS)

    Porodzinskii, Yu.V.; Sukhovitskii, E.Sh.

    1991-01-01

    The rotational-vibrational excitations of nonaxial even-even nuclei are studied on the basis of a Hamiltonian operator with five dynamical variables. Explicit forms of the wave functions and energies of the rotational-vibrational excitations of such nuclei are obtained. The experimental energies of excited positive-parity states of the 238 U nucleus and those calculated in terms of the model discussed in the article are compared