WorldWideScience

Sample records for resonance hydrogen plasmas

  1. Dry cleaning of fluorocarbon residues by low-power electron cyclotron resonance hydrogen plasma

    CERN Document Server

    Lim, S H; Yuh, H K; Yoon Eui Joon; Lee, S I

    1988-01-01

    A low-power ( 50 W) electron cyclotron resonance hydrogen plasma cleaning process was demonstrated for the removal of fluorocarbon residue layers formed by reactive ion etching of silicon dioxide. The absence of residue layers was confirmed by in-situ reflection high energy electron diffraction and cross-sectional high resolution transmission electron microscopy. The ECR hydrogen plasma cleaning was applied to contact cleaning of a contact string structure, resulting in comparable contact resistance arising during by a conventional contact cleaning procedure. Ion-assisted chemical reaction involving reactive atomic hydrogen species generated in the plasma is attributed for the removal of fluorocarbon residue layers.

  2. Temperature and density evolution during decay in a 2.45 GHz hydrogen electron cyclotron resonance plasma: Off-resonant and resonant cases

    Energy Technology Data Exchange (ETDEWEB)

    Cortázar, O. D. [ESS Bilbao, Edificio Cosimet, Landabarri 2, 48940-Leioa, Vizcaya (Spain); Universidad de Castilla-La Mancha, ETSII, C.J. Cela s/n, 13170 Ciudad Real (Spain); Megía-Macías, A.; Vizcaíno-de-Julián, A. [ESS Bilbao, Edificio Cosimet, Landabarri 2, 48940-Leioa, Vizcaya (Spain)

    2013-09-15

    Time resolved electron temperature and density measurements during the decay stage in a hydrogen electron cyclotron resonance (ECR) plasma are presented for a resonance and off-resonance magnetic field configurations. The measurements are conducted on a ECR plasma generator excited at 2.45 GHz denominated test-bench for ion-sources plasma studies at ESS Bilbao. The plasma parameters evolution is studied by Langmuir probe diagnostic with synchronized sample technique developed for repetitive pulsed plasmas with a temporal resolution of 200 ns in typical decay processes of about 40 μs. An afterglow transient is clearly observed in the reflected microwave power signal from the plasma. Simultaneously, the electron temperature evolution shows rebounding peaks that may be related to the interplay between density drop and microwave coupling with deep impact on the Electron Energy Distribution Function. The correlation of such structures with the plasma absorbed power and the coupling quality is also reported.

  3. Resonant-Cavity Driven Alfvén Waves in a Helium-Hydrogen Plasma

    Science.gov (United States)

    Clark, Mary; Dorfman, Seth; Vincena, Steve; Zhu, Ziyan; Carter, Troy

    2016-10-01

    Alfvén waves exist in many regimes. In fusion experiments, they can disrupt fusion processes by scattering particles, and in space, they are proposed to heat the solar corona. In these environments, multiple ion species usually occur. It is therefore relevant to study Alfvén waves carried by multiple ion species in a laboratory device. Here a resonant cavity launches them in UCLA's Large Plasma Device (LaPD) in a helium/hydrogen plasma. In a two-ion species plasma, Alfvén waves propagate in two bands: below the heavy ion cyclotron frequency and between a hybrid frequency and the light ion cyclotron frequency. We observe two Alfvén waves at different frequencies (in different bands) emerge when the resonant cavity is excited at one frequency: one at the driving frequency and one at a lower frequency. The two frequencies and wavelengths agree with the dispersion relation. The resonant cavity theory predicts that the wavelengths should be 4 times the cavity's length; only the high frequency lies close to this prediction. This work was funded by UCLA's Norton Rodman Award, and was performed at the Basic Plasma Science Facility, funded by DoE and NSF.

  4. Temperature peaking at beginning of breakdown in 2.45 GHz pulsed off-resonance electron cyclotron resonance ion source hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Cortazar, O. D. [Universidad de Castilla-La Mancha. E.T.S.I.I., Camilo J. Cela s/n, 13071-C. Real (Spain); Megia-Macias, A.; Vizcaino-de-Julian, A. [E.S.S. Bilbao, Edificio Cosimet, Landabarri 2, 48940-Leioa, Vizcaya (Spain)

    2012-10-15

    An experimental study of temperature and density evolution during breakdown in off-resonance ECR hydrogen plasma is presented. Under square 2.45 GHz microwave excitation pulses with a frequency of 50 Hz and relative high microwave power, unexpected transient temperature peaks that reach 18 eV during 20 {mu}s are reported at very beginning of plasma breakdown. Decays of such peaks reach final stable temperatures of 5 eV at flat top microwave excitation pulse. Evidence of interplay between incoming power and duty cycle giving different kind of plasma parameters evolutions engaged to microwave coupling times is observed. Under relative high power conditions where short microwave coupling times are recorded, high temperature peaks are measured. However, for lower incoming powers and longer coupling times, temperature evolves gradually to a higher final temperature without peaking. On the other hand, the early instant where temperature peaks are observed also suggest a possible connection with preglow processes during breakdown in ECRIS plasmas.

  5. Hydrogen Recovery by ECR Plasma Pyrolysis of Methane Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Development of a microgravity and hypogravity compatible Electron Cyclotron Resonance (ECR) Plasma Methane Pyrolysis Reactor is proposed to recover hydrogen which is...

  6. Sound-resonance hydrogen sensor

    OpenAIRE

    Dong, Shuxiang; Bai, Feiming; Li, Jiefang; Viehland, Dwight D.

    2003-01-01

    A hydrogen sensor is reported in which a small piezoelectric-sound-resonance-cavity (PSRC) is used as the sensing element. Detection utilizes sound resonance and acoustic property differences between H-2 and air as a sensing mechanism. Changes in H-2 concentration result in a shift of the sound-resonance state of the PSRC. Preliminary experiments have demonstrated a sensitivity limit of 8 ppm, a fast response time similar to1.5 second, and detection capabilities over a broad concentration ran...

  7. Hydrogen manufacturing using plasma reformers

    Energy Technology Data Exchange (ETDEWEB)

    Bromberg, L.; Cohn, D.R.; Rabinovich, A.; Hochgreb, S.; O`Brien, C. [Massachusetts Institute of Technology, Cambridge, MA (United States)

    1996-10-01

    Manufacturing of hydrogen from hydrocarbon fuels is needed for a variety of applications. These applications include fuel cells used in stationary electric power production and in vehicular propulsion. Hydrogen can also be used for various combustion engine systems. There is a wide range of requirements on the capacity of the hydrogen manufacturing system, the purity of the hydrogen fuel, and capability for rapid response. The overall objectives of a hydrogen manufacturing facility are to operate with high availability at the lowest possible cost and to have minimal adverse environmental impact. Plasma technology has potential to significantly alleviate shortcomings of conventional means of manufacturing hydrogen. These shortcomings include cost and deterioration of catalysts; limitations on hydrogen production from heavy hydrocarbons; limitations on rapid response; and size and weight requirements. In addition, use of plasma technology could provide for a greater variety of operating modes; in particular the possibility of virtual elimination of CO{sub 2} production by pyrolytic operation. This mode of hydrogen production may be of increasing importance due to recent additional evidence of global warming.

  8. Neutral Resonant Ionization in Hydrogen Anion Production

    Science.gov (United States)

    Vogel, John

    2013-09-01

    Dissociative ionization of molecules causes gas phase H- but fails to explain anion intensity. Atomic collisions on surfaces with reduced work function give anions, but also fail to explain intensity, lowered electron density, and diagnostics. Neutral resonant ionization of H(2s) atoms to ion pairs is here predicted with a very high cross section. H(2s,p) atoms are resonant with numerous short-lived excited states (``resonances'') of H- as well as the putative doubly-excited stable state of H- which resists production by other means. This state decays through 1Σu+ (2s σu2) to a singly excited ion pair, leaving both proton and anion with 3.8 eV energy. H(2s,p) atoms arise from dissociative recombination of trihydrogen ion (H3+)which dominates ion content of hydrogen plasmas. Initial H(2s,p) are resonantly produced by ground state Cs atoms or excited Ar, Kr, and Xe atoms, but these initiators are not needed to sustain anion production. This theory may explain the intense ion source at Cal Tech that produced 1.5 mA/cm2 H3 in the mid-1980's (1). A full CRM calculation is not complete, but equilibrium calculations suggest that >1 mA/cm2 H- may be predicted.

  9. Insight into hydrogenation of graphene: Effect of hydrogen plasma chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Felten, A.; Nittler, L.; Pireaux, J.-J. [Research Center in Physics of Matter and Radiation (PMR), University of Namur, Namur (Belgium); McManus, D. [School of Physics and Astronomy, University of Manchester, Manchester (United Kingdom); Rice, C.; Casiraghi, C. [School of Chemistry and Photon Science Institute, University of Manchester, Manchester (United Kingdom)

    2014-11-03

    Plasma hydrogenation of graphene has been proposed as a tool to modify the properties of graphene. However, hydrogen plasma is a complex system and controlled hydrogenation of graphene suffers from a lack of understanding of the plasma chemistry. Here, we correlate the modifications induced on monolayer graphene studied by Raman spectroscopy with the hydrogen ions energy distributions obtained by mass spectrometry. We measure the energy distribution of H{sup +}, H{sub 2}{sup +}, and H{sub 3}{sup +} ions for different plasma conditions showing that their energy strongly depends on the sample position, pressure, and plasma power and can reach values as high as 45 eV. Based on these measurements, we speculate that under specific plasma parameters, protons should possess enough energy to penetrate the graphene sheet. Therefore, a graphene membrane could become, under certain conditions, transparent to both protons and electrons.

  10. Electron waves and resonances in bounded plasmas

    CERN Document Server

    Vandenplas, Paul E

    1968-01-01

    General theoretical methods and experimental techniques ; the uniform plasma slab-condenser system ; the hollow cylindrical plasma ; scattering of a plane electromagnetic wave by a plasma column in steady magnetic fields (cold plasma approximation) ; hot non-uniform plasma column ; metallic and dielectric resonance probes, plasma-dielectric coated antenna, general considerations.

  11. Potential applications of an electron cyclotron resonance multicusp plasma source

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, C.C.; Berry, L.A.; Gorbatkin, S.M.; Haselton, H.H.; Roberto, J.B.; Stirling, W.L. (Oak Ridge National Laboratory, Oak Ridge, TN (USA))

    1990-05-01

    An electron cyclotron resonance (ECR) multicusp plasmatron has been developed by feeding a multicusp bucket arc chamber with a compact ECR plasma source. This novel source produces large (about 25 cm diam), uniform (to within {plus minus}10%), dense ({gt}10{sup 11} cm{sup {minus}3}) plasmas of argon, helium, hydrogen, and oxygen. It has been operated to produce an oxygen plasma for etching 12.7 cm (5 in.) positive photoresist-coated silicon wafers with uniformity within {plus minus}8%. Results and potential applications of this new ECR plasma source for plasma processing of thin films are discussed.

  12. Microwave Plasma Hydrogen Recovery System

    Science.gov (United States)

    Atwater, James; Wheeler, Richard, Jr.; Dahl, Roger; Hadley, Neal

    2010-01-01

    A microwave plasma reactor was developed for the recovery of hydrogen contained within waste methane produced by Carbon Dioxide Reduction Assembly (CRA), which reclaims oxygen from CO2. Since half of the H2 reductant used by the CRA is lost as CH4, the ability to reclaim this valuable resource will simplify supply logistics for longterm manned missions. Microwave plasmas provide an extreme thermal environment within a very small and precisely controlled region of space, resulting in very high energy densities at low overall power, and thus can drive high-temperature reactions using equipment that is smaller, lighter, and less power-consuming than traditional fixed-bed and fluidized-bed catalytic reactors. The high energy density provides an economical means to conduct endothermic reactions that become thermodynamically favorable only at very high temperatures. Microwave plasma methods were developed for the effective recovery of H2 using two primary reaction schemes: (1) methane pyrolysis to H2 and solid-phase carbon, and (2) methane oligomerization to H2 and acetylene. While the carbon problem is substantially reduced using plasma methods, it is not completely eliminated. For this reason, advanced methods were developed to promote CH4 oligomerization, which recovers a maximum of 75 percent of the H2 content of methane in a single reactor pass, and virtually eliminates the carbon problem. These methods were embodied in a prototype H2 recovery system capable of sustained high-efficiency operation. NASA can incorporate the innovation into flight hardware systems for deployment in support of future long-duration exploration objectives such as a Space Station retrofit, Lunar outpost, Mars transit, or Mars base. The primary application will be for the recovery of hydrogen lost in the Sabatier process for CO2 reduction to produce water in Exploration Life Support systems. Secondarily, this process may also be used in conjunction with a Sabatier reactor employed to

  13. Plasma production for electron acceleration by resonant plasma wave

    Science.gov (United States)

    Anania, M. P.; Biagioni, A.; Chiadroni, E.; Cianchi, A.; Croia, M.; Curcio, A.; Di Giovenale, D.; Di Pirro, G. P.; Filippi, F.; Ghigo, A.; Lollo, V.; Pella, S.; Pompili, R.; Romeo, S.; Ferrario, M.

    2016-09-01

    Plasma wakefield acceleration is the most promising acceleration technique known nowadays, able to provide very high accelerating fields (10-100 GV/m), enabling acceleration of electrons to GeV energy in few centimeter. However, the quality of the electron bunches accelerated with this technique is still not comparable with that of conventional accelerators (large energy spread, low repetition rate, and large emittance); radiofrequency-based accelerators, in fact, are limited in accelerating field (10-100 MV/m) requiring therefore hundred of meters of distances to reach the GeV energies, but can provide very bright electron bunches. To combine high brightness electron bunches from conventional accelerators and high accelerating fields reachable with plasmas could be a good compromise allowing to further accelerate high brightness electron bunches coming from LINAC while preserving electron beam quality. Following the idea of plasma wave resonant excitation driven by a train of short bunches, we have started to study the requirements in terms of plasma for SPARC_LAB (Ferrario et al., 2013 [1]). In particular here we focus on hydrogen plasma discharge, and in particular on the theoretical and numerical estimates of the ionization process which are very useful to design the discharge circuit and to evaluate the current needed to be supplied to the gas in order to have full ionization. Eventually, the current supplied to the gas simulated will be compared to that measured experimentally.

  14. Plasma production for electron acceleration by resonant plasma wave

    Energy Technology Data Exchange (ETDEWEB)

    Anania, M.P., E-mail: maria.pia.anania@lnf.infn.it [INFN - LNF, via Enrico Fermi, 40, 00044 Frascati (Italy); Biagioni, A.; Chiadroni, E. [INFN - LNF, via Enrico Fermi, 40, 00044 Frascati (Italy); Cianchi, A. [University of Rome Tor Vergata - INFN, via della Ricerca Scientifica, 1, 00133 Roma (Italy); INFN, Via della Ricerca Scientifica, 1, 00133 Roma (Italy); Croia, M.; Curcio, A. [INFN - LNF, via Enrico Fermi, 40, 00044 Frascati (Italy); University of Rome La Sapienza, Piazzale Aldo Moro, 2, 00185 Roma (Italy); Di Giovenale, D.; Di Pirro, G.P. [INFN - LNF, via Enrico Fermi, 40, 00044 Frascati (Italy); Filippi, F. [University of Rome La Sapienza, Piazzale Aldo Moro, 2, 00185 Roma (Italy); Ghigo, A.; Lollo, V.; Pella, S.; Pompili, R. [INFN - LNF, via Enrico Fermi, 40, 00044 Frascati (Italy); Romeo, S. [INFN - LNF, via Enrico Fermi, 40, 00044 Frascati (Italy); University of Rome La Sapienza, Piazzale Aldo Moro, 2, 00185 Roma (Italy); Ferrario, M. [INFN - LNF, via Enrico Fermi, 40, 00044 Frascati (Italy)

    2016-09-01

    Plasma wakefield acceleration is the most promising acceleration technique known nowadays, able to provide very high accelerating fields (10–100 GV/m), enabling acceleration of electrons to GeV energy in few centimeter. However, the quality of the electron bunches accelerated with this technique is still not comparable with that of conventional accelerators (large energy spread, low repetition rate, and large emittance); radiofrequency-based accelerators, in fact, are limited in accelerating field (10–100 MV/m) requiring therefore hundred of meters of distances to reach the GeV energies, but can provide very bright electron bunches. To combine high brightness electron bunches from conventional accelerators and high accelerating fields reachable with plasmas could be a good compromise allowing to further accelerate high brightness electron bunches coming from LINAC while preserving electron beam quality. Following the idea of plasma wave resonant excitation driven by a train of short bunches, we have started to study the requirements in terms of plasma for SPARC-LAB (Ferrario et al., 2013 [1]). In particular here we focus on hydrogen plasma discharge, and in particular on the theoretical and numerical estimates of the ionization process which are very useful to design the discharge circuit and to evaluate the current needed to be supplied to the gas in order to have full ionization. Eventually, the current supplied to the gas simulated will be compared to that measured experimentally.

  15. Hydrogen Plasma Processing of Iron Ore

    Science.gov (United States)

    Sabat, Kali Charan; Murphy, Anthony B.

    2017-06-01

    Iron is currently produced by carbothermic reduction of oxide ores. This is a multiple-stage process that requires large-scale equipment and high capital investment, and produces large amounts of CO2. An alternative to carbothermic reduction is reduction using a hydrogen plasma, which comprises vibrationally excited molecular, atomic, and ionic states of hydrogen, all of which can reduce iron oxides, even at low temperatures. Besides the thermodynamic and kinetic advantages of a hydrogen plasma, the byproduct of the reaction is water, which does not pose any environmental problems. A review of the theory and practice of iron ore reduction using a hydrogen plasma is presented. The thermodynamic and kinetic aspects are considered, with molecular, atomic and ionic hydrogen considered separately. The importance of vibrationally excited hydrogen molecules in overcoming the activation energy barriers, and in transferring energy to the iron oxide, is emphasized. Both thermal and nonthermal plasmas are considered. The thermophysical properties of hydrogen and argon-hydrogen plasmas are discussed, and their influence on the constriction and flow in the of arc plasmas is considered. The published R&D on hydrogen plasma reduction of iron oxide is reviewed, with both the reduction of molten iron ore and in-flight reduction of iron ore particles being considered. Finally, the technical and economic feasibility of the process are discussed. It is shown that hydrogen plasma processing requires less energy than carbothermic reduction, mainly because pelletization, sintering, and cokemaking are not required. Moreover, the formation of the greenhouse gas CO2 as a byproduct is avoided. In-flight reduction has the potential for a throughput at least equivalent to the blast furnace process. It is concluded that hydrogen plasma reduction of iron ore is a potentially attractive alternative to standard methods.

  16. Hydrogen Plasma Processing of Iron Ore

    Science.gov (United States)

    Sabat, Kali Charan; Murphy, Anthony B.

    2017-03-01

    Iron is currently produced by carbothermic reduction of oxide ores. This is a multiple-stage process that requires large-scale equipment and high capital investment, and produces large amounts of CO2. An alternative to carbothermic reduction is reduction using a hydrogen plasma, which comprises vibrationally excited molecular, atomic, and ionic states of hydrogen, all of which can reduce iron oxides, even at low temperatures. Besides the thermodynamic and kinetic advantages of a hydrogen plasma, the byproduct of the reaction is water, which does not pose any environmental problems. A review of the theory and practice of iron ore reduction using a hydrogen plasma is presented. The thermodynamic and kinetic aspects are considered, with molecular, atomic and ionic hydrogen considered separately. The importance of vibrationally excited hydrogen molecules in overcoming the activation energy barriers, and in transferring energy to the iron oxide, is emphasized. Both thermal and nonthermal plasmas are considered. The thermophysical properties of hydrogen and argon-hydrogen plasmas are discussed, and their influence on the constriction and flow in the of arc plasmas is considered. The published R&D on hydrogen plasma reduction of iron oxide is reviewed, with both the reduction of molten iron ore and in-flight reduction of iron ore particles being considered. Finally, the technical and economic feasibility of the process are discussed. It is shown that hydrogen plasma processing requires less energy than carbothermic reduction, mainly because pelletization, sintering, and cokemaking are not required. Moreover, the formation of the greenhouse gas CO2 as a byproduct is avoided. In-flight reduction has the potential for a throughput at least equivalent to the blast furnace process. It is concluded that hydrogen plasma reduction of iron ore is a potentially attractive alternative to standard methods.

  17. Electron cyclotron resonance breakdown studies in a linear plasma system

    Indian Academy of Sciences (India)

    Vipin K Yadav; K Sathyanarayana; D Bora

    2008-03-01

    Electron cyclotron resonance (ECR) plasma breakdown is studied in a small linear cylindrical system with four different gases - hydrogen, helium, argon and nitrogen. Microwave power in the experimental system is delivered by a magnetron at 2.45 ± 0.02 GHz in TE10 mode and launched radially to have extra-ordinary (X) wave in plasma. The axial magnetic field required for ECR in the system is such that the fundamental ECR surface ( = 875.0 G) resides at the geometrical centre of the plasma system. ECR breakdown parameters such as plasma delay time and plasma decay time from plasma density measurements are carried out at the centre using a Langmuir probe. The operating parameters such as working gas pressure (1 × 10-5 -1 × 10-2 mbar) and input microwave power (160{800 W) are varied and the corresponding effect on the breakdown parameters is studied. The experimental results obtained are presented in this paper.

  18. Potential applications of an electron cyclotron resonance multicusp plasma source

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, C.C.; Berry, L.A.; Gorbatkin, S.M.; Haselton, H.H.; Roberto, J.B.; Schechter, D.E.; Stirling, W.L.

    1990-03-01

    An electric cyclotron resonance (ECR) multicusp plasmatron has been developed by feeding a multicusp bucket arc chamber with a compact ECR plasma source. This novel source produces large (about 25-cm- diam), uniform (to within {plus minus}10%), dense (>10{sup 11}--cm{sup {minus}3}) plasmas of argon, helium, hydrogen, and oxygen. It has been operated to produce an oxygen plasma for etching 12.7-cm (5-in.) positive photoresist-coated silicon wafers with uniformity within {plus minus}8%. Following a brief review of the large plasma source developed at Oak Ridge National Laboratory, the configuration and operation of the source are described and a discharge model is presented. Results from this new ECR plasma source and potential applications for plasma processing of thin films are discussed. 21 refs., 10 figs.

  19. Ablation of Hydrogen Pellets in Hydrogen and Helium Plasmas

    DEFF Research Database (Denmark)

    Jørgensen, L W; Sillesen, Alfred Hegaard; Øster, Flemming

    1975-01-01

    Measurements on the interaction between solid hydrogen pellets and rotating plasmas are reported. The investigations were carried out because of the possibility of refuelling fusion reactors by the injection of pellets. The ablation rate found is higher than expected on the basis of a theory...

  20. Hydrogen Production from Ammonia Using a Plasma Membrane Reactor

    Directory of Open Access Journals (Sweden)

    Shinji Kambara

    2016-06-01

    Full Text Available In this study, an efficient method for using pulsed plasma to produce hydrogen from ammonia was developed. An original pulsed plasma reactor with a hydrogen separation membrane was developed for efficient hydrogen production, and its hydrogen production performance was investigated. Hydrogen production in the plasma was affected by the applied voltage and flow rate of ammonia gas. The maximum hydrogen production flow rate of a typical plasma reactor was 8.7 L/h, whereas that of the plasma membrane reactor was 21.0 L/h. We found that ammonia recombination reactions in the plasma controlled hydrogen production in the plasma reactor. In the plasma membrane reactor, a significant increase in hydrogen production was obtained because ammonia recombination reactions were inhibited by the permeation of hydrogen radicals generated in the plasma through a palladium alloy membrane. The energy efficiency was 4.42 mol-H2/kWh depending on the discharge power.

  1. Cyclotron resonance absorption in ionospheric plasma

    Science.gov (United States)

    Villalon, Elena

    1991-04-01

    The mode conversion of ordinary polarized electromagnetic waves into electrostatic cyclotron waves in the inhomogeneous ionospheric plasma is investigated. Near resonance the warm plasma dispersion relation is a function of the angle theta between the geomagnetic field and the density gradient and of the wave frequency omega, which lies between the electron cyclotron frequency and its doubling. The differential equations describing the electric field amplitudes near the plasma resonance are studied, including damping at the second gyroharmonic. The energy transmission coefficients and power absorbed by the cyclotron waves are calculated. The vertical penetration of the plasma wave amplitudes is estimated using a WKB analysis of the wave equation.

  2. Electron cyclotron resonance heating in a short cylindrical plasma system

    Indian Academy of Sciences (India)

    Vipin K Yadav; D Bora

    2004-09-01

    Electron cyclotron resonance (ECR) plasma is produced and studied in a small cylindrical system. Microwave power is delivered by a CW magnetron at 2.45 GHz in TE10 mode and launched radially to have extraordinary (X) wave in plasma. The axial magnetic field required for ECR in the system is such that the first two ECR surfaces ( = 875.0 G and = 437.5 G) reside in the system. ECR plasma is produced with hydrogen with typical plasma density e as 3.2 × 1010 cm-3 and plasma temperature e between 9 and 15 eV. Various cut-off and resonance positions are identified in the plasma system. ECR heating (ECRH) of the plasma is observed experimentally. This heating is because of the mode conversion of X-wave to electron Bernstein wave (EBW) at the upper hybrid resonance (UHR) layer. The power mode conversion efficiency is estimated to be 0.85 for this system. The experimental results are presented in this paper.

  3. Hydrogen Pellet-Rotating Plasma Interaction

    DEFF Research Database (Denmark)

    Jørgensen, L. W.; Sillesen, Alfred Hegaard; Øster, Flemming

    1977-01-01

    Spectroscopic measurements on the interaction between solid hydrogen pellets and rotating plasmas are reported. It was found that the light emitted is specific to the pellet material, and that the velocity of the ablated H-atoms is of the order of l0^4 m/s. The investigation was carried out...

  4. Upgradation of bauxite by molecular hydrogen and hydrogen plasma

    Science.gov (United States)

    Parhi, B. R.; Sahoo, S. K.; Mishra, S. C.; Bhoi, B.; Paramguru, R. K.; Satapathy, B. K.

    2016-10-01

    An approach was developed to upgrade the bauxite ore by molecular hydrogen and hydrogen plasma. A gibbsite-type bauxite sample was obtained from National Aluminium Company (NALCO), Odisha, India. The obtained sample was crushed and sieved (to 100 μm) prior to the chemical analysis and grain-size distribution study. The bauxite sample was calcined in the temperature range from 500 to 700°C for different time intervals to optimize the conditions for maximum moisture removal. This process was followed by the reduction of the calcined ore by molecular hydrogen and hydrogen plasma. Extraction of alumina from the reduced ore was carried out via acid leaching in chloride media for 2 h at 60°C. X-ray diffraction, scanning electron microscopy, thermogravimetry in conjunction with differential scanning calorimetry, and Fourier transform infrared spectroscopy were used to determine the physicochemical characteristics of the material before and after extraction. Alumina extracted from the reduced ore at the optimum calcination temperature of 700°C and the optimum calcination time of 4 h is found to be 90% pure.

  5. Stark-induced resonances in the photoionization of hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Glab, W.L.; Nayfeh, M.H.

    1985-01-01

    We report the first observation of electric-field-induced resonances in the multistep photoionization of hydrogen. Asymmetric profiles having blue wings are observed near the photoionization limit resulting from tunneling across the Stark-Coulomb combined potential (shape resonance). We measured the dependence of the spacing of the resonances on the electric field strength.

  6. Hydrogen atom in a Laser-Plasma

    CERN Document Server

    Falaye, Babatunde James; Liman, Muhammed S; Oyewumi, K J; Dong, Shi-Hai

    2016-01-01

    We scrutinize the behaviour of hydrogen atom's eigenvalues in a quantum plasma as it interacts with electric field directed along $\\theta=\\pi$ and exposed to linearly polarized intense laser field radiation. Using the Kramers-Henneberger (KH) unitary transformation, which is semiclassical counterpart of the Block-Nordsieck transformation in the quantized field formalism, the squared vector potential that appears in the equation of motion is eliminated and the resultant equation is expressed in KH frame. Within this frame, the resulting potential and the corresponding wavefunction have been expanded in Fourier series and using Ehlotzky's approximation, we obtain a laser-dressed potential to simulate intense laser field. By fitting the exponential-cosine-screened Coulomb potential into the laser-dressed potential, and then expanding it in Taylor series up to $\\mathcal{O}(r^4,\\alpha_0^9)$, we obtain the eigensolution (eigenvalues and wavefunction) of hydrogen atom in laser-plasma encircled by electric field, wit...

  7. Cyclotron resonance absorption in ionospheric plasma

    Energy Technology Data Exchange (ETDEWEB)

    Villalon, E. (Northeastern Univ., Boston, MA (USA) Geophysics Lab., Hanscom AFB, MA (USA))

    1991-04-01

    The mode conversion of ordinary polarized electromagnetic waves into electrostatic cyclotron waves in the inhomogeneous ionospheric plasma is investigated. Near resonance the warm plasma dispersion relation is a function of the angle {theta} between the geomagnetic field and the density gradient and of the wave frequency {omega}, where {Omega} {le} {omega} {le} 2{Omega} and {Omega} is the electron cyclotron frequency. The differential equations describing the electric field amplitudes near the plasma resonance are studied, including damping at the second gyroharmonic. For certain values of {omega} and {theta} (e.g., {theta} < 45{degree}, {omega} {approximately} 2{Omega}) the wave equations reduce to the parabolic cylinder equation. The energy transmission coefficients and power absorbed by the cyclotron waves are calculated. The vertical penetration of the plasma wave amplitudes is iestimated using a WKB analysis of the wave equation.

  8. Producing Hydrogen by Plasma Pyrolysis of Methane

    Science.gov (United States)

    Atwater, James; Akse, James; Wheeler, Richard

    2010-01-01

    Plasma pyrolysis of methane has been investigated for utility as a process for producing hydrogen. This process was conceived as a means of recovering hydrogen from methane produced as a byproduct of operation of a life-support system aboard a spacecraft. On Earth, this process, when fully developed, could be a means of producing hydrogen (for use as a fuel) from methane in natural gas. The most closely related prior competing process - catalytic pyrolysis of methane - has several disadvantages: a) The reactor used in the process is highly susceptible to fouling and deactivation of the catalyst by carbon deposits, necessitating frequent regeneration or replacement of the catalyst. b) The reactor is highly susceptible to plugging by deposition of carbon within fixed beds, with consequent channeling of flow, high pressure drops, and severe limitations on mass transfer, all contributing to reductions in reactor efficiency. c) Reaction rates are intrinsically low. d) The energy demand of the process is high.

  9. Transport properties of partially ionized hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Ramazanov, T S [IETP, Al Farabi Kazakh National University, Tole bi, 96a, 480012, Almaty (Kazakhstan); Galiyev, K Zh [IETP, Al Farabi Kazakh National University, Tole bi, 96a, 480012, Almaty (Kazakhstan); Dzhumagulova, K N [IETP, Al Farabi Kazakh National University, Tole bi, 96a, 480012, Almaty (Kazakhstan); Roepke, G [Fachbereich Physik, Universitaet Rostock, D-18051 Rostock (Germany); Redmer, R [Fachbereich Physik, Universitaet Rostock, D-18051 Rostock (Germany)

    2003-06-06

    We have considered partially ionized hydrogen plasma for the density region n{sub e} = (10{sup 18}-10{sup 22}) cm{sup -3}. Charged particles in the system (electrons, protons) interact via an effective potential taking into account three-particle correlations. We use the Buckingham polarization potential to describe electron-atom and proton-atom interactions. The electrical and thermal conductivity is determined using the Chapman-Enskog method. We compare the obtained results with other available data.

  10. Plasma probe characteristics in low density hydrogen pulsed plasmas

    CERN Document Server

    Astakhov, D I; Lee, C J; Ivanov, V V; Krivtsun, V M; Zotovich, A I; Zyryanov, S M; Lopaev, D V; Bijkerk, F

    2014-01-01

    Probe theories are only applicable in the regime where the probe's perturbation of the plasma can be neglected. However, it is not always possible to know, a priori, that a particular probe theory can be successfully applied, especially in low density plasmas. This is especially difficult in the case of transient, low density plasmas. Here, we applied probe diagnostics in combination with a 2D particle-in-cell model, to an experiment with a pulsed low density hydrogen plasma. The calculations took into account the full chamber geometry, including the plasma probe as an electrode in the chamber. It was found that the simulations reproduce the time evolution of the probe IV characteristics with good accuracy. The disagreement between the simulated and probe measured plasma density is attributed to the limited applicability of probe theory to measurements of low density pulsed plasmas. Indeed, in the case studied here, probe measurements would lead to a large overestimate of the plasma density. In contrast, the ...

  11. Josephson plasma resonance in superconducting multilayers

    DEFF Research Database (Denmark)

    Pedersen, Niels Falsig; Sakai, S

    1998-01-01

    We derive an analytical solution for the Josephson plasma resonance of superconducting multilayers. This analytical solution is derived mainly for low-T-c systems with magnetic coupling between the superconducting layers. but many features of our results are more general, and thus an application...

  12. Josephson plasma resonance in superconducting multilayers

    DEFF Research Database (Denmark)

    Pedersen, Niels Falsig

    1999-01-01

    We derive an analytical solution for the josephson plasma resonance of superconducting multilayers. This analytical solution is derived mainly for low T-c systems with magnetic coupling between the superconducting layers, but many features of our results are more general, and thus an application...

  13. Magnetosonic resonances in the magnetospheric plasma

    Science.gov (United States)

    Leonovich, A. S.; Kozlov, D. A.

    2013-05-01

    A problem of coupling between fast and slow magnetosonic waves in Earth's magnetosphere (magnetosonic resonance) is examined. Propagation both slow magnetosonic wave and Alfven wave can easily be canalized along the magnetic field line direction. The main difference between the two is that slow magnetosonic waves dissipate strongly due to their interaction with the background plasma ions, whose temperature is above the electron temperature. In Earth's magnetosphere, however, there is a region where the dissipation of slow magnetosonic waves can be weak—the inner plasmasphere. The slow magnetosonic waves generated there can be registered directly. In other regions, with strong dissipation of slow magnetosonic waves, their signature may be detected through their impact on the Alfven resonance at frequencies for which the resonant Alfven and slow magnetosonic waves exist simultaneously in the magnetosphere. Owing to their strong coupling with the background plasma ions, resonant slow magnetosonic waves can transfer the energy and impulse from the solar wind to the magnetospheric plasma ions via fast magnetosonic waves penetrating into the tail lobes. A problem of resonant conversion of fast magnetosonic waves into slow magnetosonic oscillations in a magnetosphere with dipole-like magnetic field is also examined.

  14. Characteristics of Wave-Particle Interaction in a Hydrogen Plasma

    Institute of Scientific and Technical Information of China (English)

    HE Hui-Yong; CHEN Liang-Xu; LI Jiang-Fan

    2008-01-01

    We study the characteristics of cyclotron wave-particle interaction in a typical hydrogen plasma. The numerical calculations of minimum resonant energy Emin, resonant wave frequency w, and pitch angle diffusion coefficient Dαα for interactions between R-mode/L-mode and electrons/protons are presented. It is found that Emin decreases with ω for R-mode/electron, L-mode/proton and L-mode/electron interactions, but increase with w for R-mode/proton interaction. It is shown that both R-mode and L-mode waves can efficiently scatter energetic (10 keV~100 keV) electrons and protons and cause precipitation loss at L=4, indicating that perhaps waveparticle interaction is a serious candidate for the ring current decay.

  15. The strength of side chain hydrogen bonds in the plasma membrane

    Science.gov (United States)

    Hristova, Kalina; Sarabipour, Sarvenaz

    2013-03-01

    There are no direct quantitative measurements of hydrogen bond strengths in membrane proteins residing in their native cellular environment. To address this knowledge gap, here we use fluorescence resonance energy transfer (FRET) to measure the impact of hydrogen bonds on the stability of a membrane protein dimer in vesicles derived from eukaryotic plasma membranes, and we compare these results to previous measurements of hydrogen bond strengths in model lipid bilayers. We demonstrate that FRET measurements of membrane protein interactions in plasma membrane vesicles have the requisite sensitivity to quantify the strength of hydrogen bonds. We find that the hydrogen bond-mediated stabilization in the plasma membrane is small, only -0.7 kcal/mole. It is the same as in model lipid bilayers, despite the different nature and dielectric properties of the two environments.

  16. Selective trapping of hydrogen plasma in mirror machine

    Science.gov (United States)

    Be'Ery, Ilan; Seemann, Omri; Fruchtman, Amnon; Fisher, Amnon; Ron, Amiram

    2013-10-01

    When ablation plasma, consisting mostly of hydrogen and carbon ions and neutral, is injected through the throat of a mirror machine, pure hydrogen plasma is observed to accumulate inside the mirror trap. In this work we study the formation of magnetized plasma beam, the scattering out of the loss cone, and the plasma decay in the mirror trap. The selective accumulation of hydrogen ions is shown to be a result of the difference in the magnetic channeling through a limiter and of difference in scattering probabilities into the trapped regions of phase space. The accumulation of plasma in the trap is limited by centrifugal drift instability, convecting plasma to the walls.

  17. Microwave Absorption in Electron Cyclotron Resonance Plasma

    Institute of Scientific and Technical Information of China (English)

    LIU Ming-Hai; HU Xi-Wei; WU Qin-Chong; YU Guo-Yang

    2000-01-01

    The microwave power absorption in electron cyclotron resonance plasma reactor was investigated with a twodimensional hybrid-code. Simulation results indicated that there are two typical power deposition profiles over the entire parameter region: (1) microwave power deposition peaks on the axis and decreases in radial direction,(2) microwave power deposition has its maximum at some radial position, i.e., a hollow distribution. The spatial distribution of electron temperature resembles always to the microwave power absorption profile. The dependence of plasma parameter on the gas pressure is discussed also.

  18. Modification of Plasma Solitons by Resonant Particles

    DEFF Research Database (Denmark)

    Karpman, Vladimir; Lynov, Jens-Peter; Michelsen, Poul;

    1980-01-01

    A consistent theory of plasma soliton interaction with resonant particles is developed. A simple derivation of a perturbed Korteweg–de Vries equation with the interaction term is presented. It is shown how the known limit cases (such as Ott–Sudan’s, etc.) can be derived from the general equations...... Korteweg–de Vries equation. Laboratory measurements carried out in a strongly magnetized, plasma‐filled waveguide and results from particle simulation are interpreted in terms of the analytical results....

  19. Particle growth in hydrogen-methane plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, T. [Centre for Interdisciplinary Plasma Science, Max-Planck Institute for extraterrestrial Physics, Giessenbachstr. 1, D-85741 Garching (Germany); Jacob, W. [Centre for Interdisciplinary Plasma Science, Max-Planck Institute for Plasma Physics, Boltzmanstr. 2, D-85748 Garching (Germany); Thomas, H. [Centre for Interdisciplinary Plasma Science, Max-Planck Institute for extraterrestrial Physics, Giessenbachstr. 1, D-85741 Garching (Germany); Morfill, G. [Centre for Interdisciplinary Plasma Science, Max-Planck Institute for extraterrestrial Physics, Giessenbachstr. 1, D-85741 Garching (Germany); Abe, T. [Department of Electronic Device and Materials, Tohoku Institute of Technology, 35-1, Kasumi-cho, Yagiyama, Taihaku-ku, Sendai 982-8577 (Japan); Watanabe, Y. [Graduate School of Information Science and Electrical Engineering, Kyushu University, 6-10-1, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan); Sato, N. [Centre for Interdisciplinary Plasma Science, Max-Planck Institute for extraterrestrial Physics, Giessenbachstr. 1, D-85741 Garching (Germany); Professor Emeritus, Tohoku University, 05, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8579 (Japan)

    2006-05-26

    Particle growth and the behavior of particle clouds in hydrogen-methane capacitively coupled rf plasmas are investigated. At room temperature, most for different wall temperatures and gas compositions of these particles are due to flakes of layers delaminated from the electrode surfaces. Heating of the electrodes up to 800 K and dilution by hydrogen (up to H{sub 2}:CH{sub 4} = 20:1) suppresses the production of the particles from the electrode surfaces. The electron temperature in the particle levitation region is controlled by introducing an additional electrode made from a grid (= gridded electrode) in between the levitation electrode and the driven electrode. If we introduce diamond seed particles ({approx} 2.8 {mu}m in diameter) into the plasma with the gridded electrode in place, we observe nucleation of new grains ({approx} 100 nm) on the surfaces of the diamond particles. On the other hand, without the gridded electrode, we do not observe nucleation but growth of amorphous carbon films on them.

  20. Plasma Density Measurements on Refuelling by Solid Hydrogen Pellets in a Rotating Plasma

    DEFF Research Database (Denmark)

    Jørgensen, L. W.; Sillesen, A. H.

    1978-01-01

    The authors used laser interferometry to directly measure the increase in plasma density caused by the ablation of a solid hydrogen pellet situated in a rotating plasma.......The authors used laser interferometry to directly measure the increase in plasma density caused by the ablation of a solid hydrogen pellet situated in a rotating plasma....

  1. Plasma processing methods for hydrogen production

    Science.gov (United States)

    Mizeraczyk, Jerzy; Jasiński, Mariusz

    2016-08-01

    In the future a transfer from the fossil fuel-based economy to hydrogen-based economy is expected. Therefore the development of systems for efficient H2 production becomes important. The several conventional methods of mass-scale (or central) H2 production (methane, natural gas and higher hydrocarbons reforming, coal gasification reforming) are well developed and their costs of H2 production are acceptable. However, due to the H2 transport and storage problems the small-scale (distributed) technologies for H2 production are demanded. However, these new technologies have to meet the requirement of producing H2 at a production cost of (1-2)/kg(H2) (or 60 g(H2)/kWh) by 2020 (the U.S. Department of Energy's target). Recently several plasma methods have been proposed for the small-scale H2 production. The most promising plasmas for this purpose seems to be those generated by gliding, plasmatron and nozzle arcs, and microwave discharges. In this paper plasma methods proposed for H2 production are briefly described and critically evaluated from the view point of H2 production efficiency. The paper is aiming at answering a question if any plasma method for the small-scale H2 production approaches such challenges as the production energy yield of 60 g(H2)/kWh, high production rate, high reliability and low investment cost. Contribution to the topical issue "6th Central European Symposium on Plasma Chemistry (CESPC-6)", edited by Nicolas Gherardi, Ester Marotta and Cristina Paradisi

  2. Low Hydrogen Content Silicon Nitride Films Deposited at Room Temperature with an ECR Plasma Source

    NARCIS (Netherlands)

    Isai, Gratiela I.; Holleman, Jisk; Wallinga, Hans; Woerlee, Pierre H.

    2004-01-01

    Silicon nitride layers with very low hydrogen content (less than 1 atomic percent) were deposited at near room temperature, from N2 and SiH4, with a multipolar electron cyclotron resonance plasma. The influences of pressure and nitrogen flow rate on physical and electrical properties were studied in

  3. Elementary Processes and Kinetic Modeling for Hydrogen and Helium Plasmas

    Directory of Open Access Journals (Sweden)

    Roberto Celiberto

    2017-05-01

    Full Text Available We report cross-sections and rate coefficients for excited states colliding with electrons, heavy particles and walls useful for the description of H 2 /He plasma kinetics under different conditions. In particular, the role of the rotational states in resonant vibrational excitations of the H 2 molecule by electron impact and the calculation of the related cross-sections are illustrated. The theoretical determination of the cross-section for the rovibrational energy exchange and dissociation of H 2 molecule, induced by He atom impact, by using the quasi-classical trajectory method is discussed. Recombination probabilities of H atoms on tungsten and graphite, relevant for the determination of the nascent vibrational distribution, are also presented. An example of a state-to-state plasma kinetic model for the description of shock waves operating in H 2 and He-H 2 mixtures is presented, emphasizing also the role of electronically-excited states in affecting the electron energy distribution function of free electrons. Finally, the thermodynamic properties and the electrical conductivity of non-ideal, high-density hydrogen plasma are finally discussed, in particular focusing on the pressure ionization phenomenon in high-pressure high-temperature plasmas.

  4. Unnatural parity resonance states in positron-excited hydrogen scattering

    Institute of Scientific and Technical Information of China (English)

    Ma Jia; Zhou Ya-Jun; Wang Yuan-Cheng

    2012-01-01

    The coupled-channels optical method for positron scattering has been applied to investigate resonance states with unnatural parities in a positron-excited hydrogen system.The positronium formation channels and continuum channel are included via a complex equivalent local potential.Resonance states with angular momenta L =1 to L =2 and parities (-1)L+1 are calculated.Resonance energies and widths are reported and compared with other theoretical calculations.We found that the opening positronium formation channels play an important role in forming nondipole Feshbach resonances.

  5. Plasma Outages in Pulsed, High-Power RF Hydrogen Ion Sources

    Science.gov (United States)

    Stockli, Martin; Han, Baoxi; Murray, Syd; Pennisi, Terry; Piller, Chip; Santana, Manuel; Welton, Robert

    2011-04-01

    Pulsed, high-power RF ion sources are needed to produce copious amounts of negative H-ions for high-power accelerators with charge-changing injection schemes. When increasing the RF power, the plasma inductance changes the RF resonance, which drifts away from the low-power resonance. When the RF circuit is tuned to maximize the (pulsed) plasma power, the (off-resonance) power at the beginning of the pulse is reduced. If the induced electric fields fall below the breakdown strength of the hydrogen gas, the plasma fails to develop. This can be avoided with a compromise tune and/or by increasing the inductance of the resonant circuit. However, the breakdown strength of the hydrogen gas increases with time due to the gradual decrease of the electron-rich plasma impurities, which causes plasma outages after weeks of reliable operation. In this paper we discuss the success of different mitigations that were tested and implemented to overcome this fundamental problem of pulsed, high-power RF hydrogen ion sources.

  6. Excitation and ionization of hydrogen Rydberg states in a plasma

    Energy Technology Data Exchange (ETDEWEB)

    Glab, W.; Nayfeh, M.H.

    1982-08-01

    Hydrogen Rydberg states in a hydrogen plasma are optically excited from the plasma-excited n = 2 state. Photoionization and optogalvanic, which are due to electron-impact ionization and other collisional processes, are used to monitor the Rydberg states. This process may be used to study collisional ionization of the Rydberg states.

  7. Excitation and ionization of hydrogen Rydberg states in a plasma.

    Science.gov (United States)

    Glab, W; Nayfeh, M H

    1982-08-01

    Hydrogen Rydberg states in a hydrogen plasma are optically excited from the plasma-excited n = 2 state. Photoionization and optogalvanic ionization, which is due to electron-impact ionization and other collisional processes, are used to monitor the Rydberg states. This process may be used to study collisional ionization of the Rydberg states.

  8. Hydrogen isotope fractionation in methane plasma

    Science.gov (United States)

    Robert, François; Derenne, Sylvie; Lombardi, Guillaume; Hassouni, Khaled; Michau, Armelle; Reinhardt, Peter; Duhamel, Rémi; Gonzalez, Adriana; Biron, Kasia

    2017-01-01

    The hydrogen isotope ratio (D/H) is commonly used to reconstruct the chemical processes at the origin of water and organic compounds in the early solar system. On the one hand, the large enrichments in deuterium of the insoluble organic matter (IOM) isolated from the carbonaceous meteorites are interpreted as a heritage of the interstellar medium or resulting from ion‑molecule reactions taking place in the diffuse part of the protosolar nebula. On the other hand, the molecular structure of this IOM suggests that organic radicals have played a central role in a gas-phase organosynthesis. So as to reproduce this type of chemistry between organic radicals, experiments based on a microwave plasma of CH4 have been performed. They yielded a black organic residue in which ion microprobe analyses revealed hydrogen isotopic anomalies at a submicrometric spatial resolution. They likely reflect differences in the D/H ratios between the various CHx radicals whose polymerization is at the origin of the IOM. These isotopic heterogeneities, usually referred to as hot and cold spots, are commensurable with those observed in meteorite IOM. As a consequence, the appearance of organic radicals in the ionized regions of the disk surrounding the Sun during its formation may have triggered the formation of organic compounds.

  9. Active plasma resonance spectroscopy: A functional analytic description

    OpenAIRE

    Lapke, Martin; Oberrath, Jens; Mussenbrock, Thomas; Brinkmann, Ralf Peter

    2012-01-01

    The term "Active Plasma Resonance Spectroscopy" refers to a class of diagnostic methods which employ the ability of plasmas to resonate on or near the plasma frequency. The basic idea dates back to the early days of discharge physics: An signal in the GHz range is coupled to the plasma via an electrical probe; the spectral response is recorded, and then evaluated with a mathematical model to obtain information on the electron density and other plasma parameters. In recent years, the concept h...

  10. Hydrogenation Properties of Zr Films Under Various Conditions of Hydrogen Plasma

    Institute of Scientific and Technical Information of China (English)

    晏国强; 施立群; 周筑颖; 赵国庆; 胡佩钢; 罗顺忠; 彭述明; 丁伟; 龙兴贵

    2002-01-01

    The hydrogenation properties of Zr samples with and without an Ni overlayer under various plasma conditionswere investigated by means of non-Rutherford backscattering and elastic recoil detection analysis. The theoretical maximum hydrogen capacity, 66.7at%, could be achieved at a hydrogen absolute pressure of2 Pa and a substrate temperature of ~393 K for a plasma irradiation of only 10 min; this was significantly greater than that for gas hydrogenation under the same hydrogen pressure and substrate temperature. It was also found that the C and O contamination on the sample surface strongly influences the hydrogenation, and that the maximum equilibrium hydrogen content drops dramatically with the increasing total contamination. In addition, the influence of the Ni overlayer on the plasma hydrogenation is discussed.

  11. Hydrogen atom kinetics in capacitively coupled plasmas

    Science.gov (United States)

    Nunomura, Shota; Katayama, Hirotaka; Yoshida, Isao

    2017-05-01

    Hydrogen (H) atom kinetics has been investigated in capacitively coupled very high frequency (VHF) discharges at powers of 16-780 mW cm-2 and H2 gas pressures of 0.1-2 Torr. The H atom density has been measured using vacuum ultra violet absorption spectroscopy (VUVAS) with a micro-discharge hollow cathode lamp as a VUV light source. The measurements have been performed in two different electrode configurations of discharges: conventional parallel-plate diode and triode with an intermediate mesh electrode. We find that in the triode configuration, the H atom density is strongly reduced across the mesh electrode. The H atom density varies from ˜1012 cm-3 to ˜1010 cm-3 by crossing the mesh with 0.2 mm in thickness and 36% in aperture ratio. The fluid model simulations for VHF discharge plasmas have been performed to study the H atom generation, diffusion and recombination kinetics. The simulations suggest that H atoms are generated in the bulk plasma, by the electron impact dissociation (e + H2 \\to e + 2H) and the ion-molecule reaction (H2 + + H2 \\to {{{H}}}3+ + H). The diffusion of H atoms is strongly limited by a mesh electrode, and thus the mesh geometry influences the spatial distribution of the H atoms. The loss of H atoms is dominated by the surface recombination.

  12. Influence of microwave driver coupling design on plasma density at Testbench for Ion sources Plasma Studies, a 2.45 GHz Electron Cyclotron Resonance Plasma Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Megía-Macías, A.; Vizcaíno-de-Julián, A. [E.S.S. Bilbao, Edificio Cosimet, Landabarri 2, 48940-Leioa, Vizcaya (Spain); Cortázar, O. D., E-mail: dcortazar@essbilbao.org [E.S.S. Bilbao, Edificio Cosimet, Landabarri 2, 48940-Leioa, Vizcaya (Spain); Universidad de Castilla-La Mancha, ETSII, C.J. Cela s/n, 13170 Ciudad Real (Spain)

    2014-03-15

    A comparative study of two microwave driver systems (preliminary and optimized) for a 2.45 GHz hydrogen Electron Cyclotron Resonance plasma generator has been conducted. The influence on plasma behavior and parameters of stationary electric field distribution in vacuum, i.e., just before breakdown, along all the microwave excitation system is analyzed. 3D simulations of resonant stationary electric field distributions, 2D simulations of external magnetic field mapping, experimental measurements of incoming and reflected power, and electron temperature and density along the plasma chamber axis have been carried out. By using these tools, an optimized set of plasma chamber and microwave coupler has been designed paying special attention to the optimization of stationary electric field value in the center of the plasma chamber. This system shows a strong stability on plasma behavior allowing a wider range of operational parameters and even sustaining low density plasma formation without external magnetic field. In addition, the optimized system shows the capability to produce values of plasma density four times higher than the preliminary as a consequence of a deeper penetration of the magnetic resonance surface in relative high electric field zone by keeping plasma stability. The increment of the amount of resonance surface embedded in the plasma under high electric field is suggested as a key factor.

  13. Optimization of Pd Surface Plasmon Resonance sensors for hydrogen detection

    NARCIS (Netherlands)

    Perrotton, C.; Javahiraly, N.; Slaman, M.; Schreuders, H.; Dam, B.; Meyrueis, P.

    2011-01-01

    A design to optimize a fiber optic Surface Plasmon Resonance (SPR) sensor using Palladium as a sensitive layer for hydrogen detection is presented. In this approach, the sensitive layer is deposited on the core of a multimode fiber, after removing the optical cladding. The light is injected in the f

  14. Optimization of Pd Surface Plasmon Resonance sensors for hydrogen detection

    NARCIS (Netherlands)

    Perrotton, C.; Javahiraly, N.; Slaman, M.; Schreuders, H.; Dam, B.; Meyrueis, P.

    2011-01-01

    A design to optimize a fiber optic Surface Plasmon Resonance (SPR) sensor using Palladium as a sensitive layer for hydrogen detection is presented. In this approach, the sensitive layer is deposited on the core of a multimode fiber, after removing the optical cladding. The light is injected in the f

  15. Initial damage processes for diamond film exposure to hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Deslandes, A., E-mail: acd@ansto.gov.au [Institute for Environmental Research, Australian Nuclear Science and Technology Organisation, Sydney (Australia); Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Sydney (Australia); Guenette, M.C. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Sydney (Australia); Samuell, C.M. [Plasma Research Laboratory, Research School of Physics and Engineering, The Australian National University, Canberra 0200 (Australia); Karatchevtseva, I. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Sydney (Australia); Ionescu, M.; Cohen, D.D. [Institute for Environmental Research, Australian Nuclear Science and Technology Organisation, Sydney (Australia); Blackwell, B. [Plasma Research Laboratory, Research School of Physics and Engineering, The Australian National University, Canberra 0200 (Australia); Corr, C., E-mail: cormac.corr@anu.edu.au [Plasma Research Laboratory, Research School of Physics and Engineering, The Australian National University, Canberra 0200 (Australia); Riley, D.P., E-mail: dry@ansto.gov.au [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Sydney (Australia)

    2013-12-15

    Graphical abstract: -- Highlights: • Exposing chemical vapour deposited (CVD) diamond films in a recently constructed device, MAGPIE, specially commissioned to simulate fusion plasma conditions. • Non-diamond material is etched from the diamond. • There is no hydrogen retention observed, which suggests diamond is an excellent candidate for plasma facing materials. • Final structure of the surface is dependent on synergistic effects of etching and ion-induced structural change. -- Abstract: Diamond is considered to be a possible alternative to other carbon based materials as a plasma facing material in nuclear fusion devices due to its high thermal conductivity and resistance to chemical erosion. In this work CVD diamond films were exposed to hydrogen plasma in the MAGnetized Plasma Interaction Experiment (MAGPIE): a linear plasma device at the Australian National University which simulates plasma conditions relevant to nuclear fusion. Various negative sample stage biases of magnitude less than 500 V were applied to control the energies of impinging ions. Characterisation results from SEM, Raman spectroscopy and ERDA are presented. No measureable quantity of hydrogen retention was observed, this is either due to no incorporation of hydrogen into the diamond structure or due to initial incorporation as a hydrocarbon followed by subsequent etching back into the plasma. A model is presented for the initial stages of diamond erosion in fusion relevant hydrogen plasma that involves chemical erosion of non-diamond material from the surface by hydrogen radicals and damage to the subsurface region from energetic hydrogen ions. These results show that the initial damage processes in this plasma regime are comparable to previous studies of the fundamental processes as reported for less extreme plasma such as in the development of diamond films.

  16. Hydrogen Recovery by ECR Plasma Pyrolysis of Methane Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Development of a microgravity and hypogravity compatible microwave plasma methane pyrolysis reactor is proposed to recover hydrogen which is lost as methane in the...

  17. Hydrogen sulfide waste treatment by microwave plasma-chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Harkness, J.B.L.; Doctor, R.D.

    1994-03-01

    A waste-treatment process that recovers both hydrogen and sulfur from industrial acid-gas waste streams is being developed to replace the Claus technology, which recovers only sulfur. The proposed process is derived from research reported in the Soviet technical literature and uses microwave (or radio-frequency) energy to initiate plasma-chemical reactions that dissociate hydrogen sulfide into elemental hydrogen and sulfur. This process has several advantages over the current Claus-plus-tail-gas-cleanup technology, which burns the hydrogen to water. The primary advantage of the proposal process is its potential for recovering and recycling hydrogen more cheaply than the direct production of hydrogen. Since unconverted hydrogen sulfide is recycled to the plasma reactor, the plasma-chemical process has the potential for sulfur recoveries in excess of 99% without the additional complexity of the tail-gas-cleanup processes associated with the Claus technology. There may also be some environmental advantages to the plasma-chemical process, because the process purge stream would primarily be the carbon dioxide and water contained in the acid-gas waste stream. Laboratory experiments with pure hydrogen sulfide have demonstrated the ability of the process to operate at or above atmospheric pressure with an acceptable hydrogen sulfide dissociation energy. Experiments with a wide range of acid-gas compositions have demonstrated that carbon dioxide and water are compatible with the plasma-chemical dissociation process and that they do not appear to create new waste-treatment problems. However, carbon dioxide does have negative impacts on the overall process. First, it decreases the hydrogen production, and second, it increases the hydrogen sulfide dissociation energy.

  18. Measurement of plasma hydrogen sulfide in vivo and in vitro

    OpenAIRE

    Shen, Xinggui; Pattillo, Christopher B.; Pardue, Sibile; Bir, Shyamal C.; Wang, Rui; Kevil, Christopher G.

    2011-01-01

    The gasotransmitter hydrogen sulfide is known to regulate multiple cellular functions during normal and pathophysiological states. However, a paucity of concise information exists regarding quantitative amounts of hydrogen sulfide involved in physiological and pathological responses. This is primarily due to disagreement among various methods employed to measure free hydrogen sulfide. In this article, we describe a very sensitive method of measuring the presence of H2S in plasma down to nanom...

  19. Hydrogen desorption from hydrogen fluoride and remote hydrogen plasma cleaned silicon carbide (0001) surfaces

    Energy Technology Data Exchange (ETDEWEB)

    King, Sean W., E-mail: sean.king@intel.com; Tanaka, Satoru; Davis, Robert F. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Nemanich, Robert J. [Department of Physics, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2015-09-15

    Due to the extreme chemical inertness of silicon carbide (SiC), in-situ thermal desorption is commonly utilized as a means to remove surface contamination prior to initiating critical semiconductor processing steps such as epitaxy, gate dielectric formation, and contact metallization. In-situ thermal desorption and silicon sublimation has also recently become a popular method for epitaxial growth of mono and few layer graphene. Accordingly, numerous thermal desorption experiments of various processed silicon carbide surfaces have been performed, but have ignored the presence of hydrogen, which is ubiquitous throughout semiconductor processing. In this regard, the authors have performed a combined temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy (XPS) investigation of the desorption of molecular hydrogen (H{sub 2}) and various other oxygen, carbon, and fluorine related species from ex-situ aqueous hydrogen fluoride (HF) and in-situ remote hydrogen plasma cleaned 6H-SiC (0001) surfaces. Using XPS, the authors observed that temperatures on the order of 700–1000 °C are needed to fully desorb C-H, C-O and Si-O species from these surfaces. However, using TPD, the authors observed H{sub 2} desorption at both lower temperatures (200–550 °C) as well as higher temperatures (>700 °C). The low temperature H{sub 2} desorption was deconvoluted into multiple desorption states that, based on similarities to H{sub 2} desorption from Si (111), were attributed to silicon mono, di, and trihydride surface species as well as hydrogen trapped by subsurface defects, steps, or dopants. The higher temperature H{sub 2} desorption was similarly attributed to H{sub 2} evolved from surface O-H groups at ∼750 °C as well as the liberation of H{sub 2} during Si-O desorption at temperatures >800 °C. These results indicate that while ex-situ aqueous HF processed 6H-SiC (0001) surfaces annealed at <700 °C remain terminated by some surface C–O and

  20. Study on low temperature plasma driven permeation of hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Takizawa, Masayuki [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1998-03-01

    It is one of the most important problem in PWI of fusion devices from the point of view of tritium leakage that hydrogen diffuses in the wall of the device and permeates through it, which results in hydrogen being released to the coolant side. In this study, plasma driven permeation experiments were carried out with several kinds of metal membranes in the low temperature plasma where ionic and atomic hydrogen as well as electron existed in order to survey PDP mechanism from the many view points. In addition, incident flux rate from the plasma to the membrane surface was evaluated by calculation analysis. As a result the mechanism of low temperature PDP was found out and described as PDP models. The simulation of the membrane pump system was executed and the system performance was estimated with the models. (author). 135 refs.

  1. Hydrogen Evolution by Plasma Electrolysis in Aqueous Solution

    Science.gov (United States)

    Mizuno, Tadahiko; Akimoto, Tadashi; Azumi, Kazuhisa; Ohmori, Tadayoshi; Aoki, Yoshiaki; Takahashi, Akito

    2005-01-01

    Hydrogen has recently attracted attention as a possible solution to environmental and energy problems. If hydrogen should be considered an energy storage medium rather than a natural resource. However, free hydrogen does not exist on earth. Many techniques for obtaining hydrogen have been proposed. It can be reformulated from conventional hydrocarbon fuels, or obtained directly from water by electrolysis or high-temperature pyrolysis with a heat source such as a nuclear reactor. However, the efficiencies of these methods are low. The direct heating of water to sufficiently high temperatures for sustaining pyrolysis is very difficult. Pyrolysis occurs when the temperature exceeds 4000°C. Thus plasma electrolysis may be a better alternative, it is not only easier to achieve than direct heating, but also appears to produce more hydrogen than ordinary electrolysis, as predicted by Faraday’s laws, which is indirect evidence that it produces very high temperatures. We also observed large amounts of free oxygen generated at the cathode, which is further evidence of direct decomposition, rather than electrolytic decomposition. To achieve the continuous generation of hydrogen with efficiencies exceeding Faraday efficiency, it is necessary to control the surface conditions of the electrode, plasma electrolysis temperature, current density and input voltage. The minimum input voltage required induce the plasma state depends on the density and temperature of the solution, it was estimated as 120 V in this study. The lowest electrolyte temperature at which plasma forms is ˜75°C. We have observed as much as 80 times more hydrogen generated by plasma electrolysis than by conventional electrolysis at 300 V.

  2. Isotope Effects of Solid Hydrogenic Pellet Ablation in Fusion Plasma

    Institute of Scientific and Technical Information of China (English)

    PENGLilin; DENGBaiquan; YANJiancheng; WANGXiaoyu

    2003-01-01

    The isotope effects of ablation processes in fusion plasma for five combinations of solid isotopic hydrogenic pellets H2, HD, D2,DT, T2 have been first time studied. The resuits show that the modifications caused by isotope effects for pellet erosion speeds range from 1 for hydrogen pellet down to 0. 487 for tritium pellet and are not negligible in ablation rate calculations. These effects lead to deeper mass deposition and improved core fueling efficiency.

  3. Plasma promoted manufacturing of hydrogen and vehicular applications

    Science.gov (United States)

    Bromberg, Leslie

    2003-10-01

    Plasmas can be used for promoting reformation of fuels. Plasma-based reformers developed at MIT use a low temperature, low power, low current electrical discharge to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The very fuel rich mixture is hard to ignite, and the plasmatron provides a volume-ignition. To minimize erosion and to simplify the power supply, a low current high voltage discharge is used, with wide area electrodes. The plasmatron fuel reformer operates at or slightly above atmospheric pressure. The plasma-based reformer technology provides the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels. These advantages enable use of hydrogen-manufacturing reformation technology in cars using available fuels, such as gasoline and diesel. This plasma-based reformer technology can provide substantial throughputs even without the use of a catalyst. The electrical power consumption of the device is minimized by design and operational characteristics (less than 500 W peak and 200 W average). The product from these plasma reactors is a hydrogen rich mixture that can be used for combustion enhancement and emissions aftertreatment in vehicular applications. By converting a small fraction of the fuel to hydrogen rich gas, in-cylinder combustion can be improved. With minor modification of the engine, use of hydrogen rich gas results in increased fuel efficiency and decreased emissions of smog producing gases. The status of plasma based reformer technology and its application to vehicles will be described.

  4. Investigation of Non-Equilibrium Argon and Hydrogen Plasmas.

    Science.gov (United States)

    Braun, Christopher Gifford

    1987-09-01

    Theoretical and experimental investigations are made into non-equilibrium argon and hydrogen partially -ionized plasmas characteristic of glow discharge devices such as thyratrons and discharge tubes. For an argon plasma, the development and use of a collisional-radiative, steady -state, three-energy-level model is presented and experimental measurements on pulsed argon plasmas are briefly mentioned. Two different theoretical argon plasma models are discussed; the first is numerically solved using a non-Maxwellian electron distribution function, while the second is solved analytically, including atom-atom inelastic collisions, assuming Maxwellian electron and atom distribution functions. For a hydrogen plasma, experimental measurements using fluorescence and laser-induced fluorescence have been made in a modified hydrogen thyratron over a wide current density range (from 100 to 8,000 A/cm('2)) for the atomic hydrogen population densities n = 2,3,4. A pronounced rise in the atomic hydrogen excited state populations is observed after the end of the current pulse. A new method to measure the time-resolved electron density has been developed and results are presented. A time-dependent model for atomic hydrogen plasmas typical of a thyratron has been constructed, and preliminary results are shown. This model includes ten atomic energy levels (n = 1 to n = 9 and the continuum), takes into account energy balance with an externally supplied current density and assumes a Maxwellian electron distribution function. Implications of these measurements and theoretical analysis upon the operation of thyratrons are discussed. (Copies available exclusively from Micrographics Department, Doheny Library, University of Southern California, Los Angeles, CA 90089 -0182.).

  5. Exploring the electron density in plasma induced by EUV radiation: II. Numerical studies in argon and hydrogen

    NARCIS (Netherlands)

    Astakhov, D. I.; Goedheer, W. J.; Lee, C. J.; Ivanov, V. V.; Krivtsun, V. M.; Koshelev, K. N.; Lopaev, D. V.; van der Horst, R. M.; Beckers, J.; Osorio, E. A.; Bijkerk, F.

    2016-01-01

    We used numerical modeling to study the evolution of EUV-induced plasmas in argon and hydrogen. The results of simulations were compared to the electron densities measured by microwave cavity resonance spectroscopy. It was found that the measured electron densities can be used to derive the integral

  6. Selective etching of graphene edges by hydrogen plasma.

    Science.gov (United States)

    Xie, Liming; Jiao, Liying; Dai, Hongjie

    2010-10-27

    We devised a controlled hydrogen plasma reaction at 300 °C to etch graphene and graphene nanoribbons (GNRs) selectively at the edges over the basal plane. Atomic force microscope imaging showed that the etching rates for single-layer and few-layer (≥2 layers) graphene are 0.27 ± 0.05 nm/min and 0.10 ± 0.03 nm/min, respectively. Meanwhile, Raman spectroscopic mapping revealed no D band in the planes of single-layer or few-layer graphene after the plasma reaction, suggesting selective etching at the graphene edges without introducing defects in the basal plane. We found that hydrogen plasma at lower temperature (room temperature) or a higher temperature (500 °C) could hydrogenate the basal plane or introduce defects in the basal plane. Using the hydrogen plasma reaction at the intermediate temperature (300 °C), we obtained narrow, presumably hydrogen terminated GNRs (sub-5 nm) by etching of wide GNRs derived from unzipping of multiwalled carbon nanotubes. Such GNRs exhibited semiconducting characteristics with high on/off ratios (∼1000) in GNR field effect transistor devices at room temperature.

  7. Ablation of Solid Hydrogen in a Plasma

    DEFF Research Database (Denmark)

    Jørgensen, L. W.; Sillesen, Alfred Hegaard

    1979-01-01

    Several hydrogen pellet ablation models based on the formation of a shielding neutral cloud have been reported by different authors. The predicted ablation rates are shown to follow almost the same scaling law and this is used to explain the authors' ablation experiment....

  8. Non-thermal plasma treatment of hydrogen sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Frost, L.J.; Hartvigsen, J.; Elangovan, S. [Ceramatec Inc., Salt Lake City, UT (United States)

    2009-07-01

    This paper described a non-thermal plasma reforming process to treat hydrogen sulfide (H{sub 2}S) in heavy hydrocarbons. H{sub 2}S is present in natural gas, petroleum, and various process gases. It is an unwanted compound that is generally removed using an amine extraction process followed by a Claus process. Ceramatec Inc. has developed a GlidArc plasma reformer to recover some of the hydrogen from the H{sub 2}S. Non-thermal plasma reforming breaks hydrogen sulfide into hydrogen and elemental sulphur. Ceramatec has established the catalytic nature of the non-thermal plasma generated by its GlidArc plasma reformer. This treatment process is still in the laboratory stage, but it offers the possibility of a new method to treat acid gas that will provide an opportunity to recover hydrogen that is currently burned to water during the Claus sulphur removal process. Ceramatec, in conjunction with Albin Czernichowski of ECP in France, has demonstrated the ability to reform a variety of hydrocarbons using the non-thermal plasma catalyzed reaction. The plasma reaction can be initiated in either a partial oxidation or steam reforming mode. Multiple hydrocarbons can be processed by the same unit with only control parameters changing to meet the requirements of the individual hydrocarbons being processed. Although a tested unit did not accomplish complete conversion, some additional options will be tested that are expected to increase the conversion under an existing program operated by the United States Department of Energy. 4 refs., 9 figs.

  9. Spectrum analysis of hydrogen plasma in spherically convergent beam fusion

    Energy Technology Data Exchange (ETDEWEB)

    Ogasawara, Kazuki; Yamauchi, Kunihito; Watanabe, Masato; Sunaga, Yoshitaka; Hotta, Eiki [Tokyo Institute of Technology, Dept. of Energy Sciences, Yokohama, Kanagawa (Japan); Okino, Akitoshi [Tokyo Institute of Technology, Dept. of Electrical and Electronic Engineering, Tokyo (Japan)

    2001-09-01

    Spectroscopic analysis of spherical glow discharge fusion device was carried out using hydrogen gas. Effects of the discharge current and cathode voltage on spectrum profiles of hydrogen Balmar lines were measured. The profiles of all hydrogen lines were broadened with the cathode voltage. From the relationship between the maximum broadening width and the cathode voltage, it was indicated that the broadening was caused by the Doppler effect. From the spatial distribution of emission intensity, it was found that plasma core size became larger with discharge current and smaller with cathode voltage. (author)

  10. Experimental evidence of E × B plasma rotation in a 2.45 GHz hydrogen discharge

    Energy Technology Data Exchange (ETDEWEB)

    Cortázar, O. D., E-mail: daniel.cortazar@uclm.es [Institute for Energy Research-INEI, University of Castilla-La Mancha, C.J. Cela s/n, 13170 Ciudad Real (Spain); Megía-Macías, A. [CERN, BE-ABP-HSL Department, CH1211 Geneva (Switzerland); E.S.S. Bilbao, Polígono Ugaldeguren III, A-7B, 48170 Zamudio (Spain); Tarvainen, O.; Koivisto, H. [Department of Physics, Accelerator Laboratory, University of Jyväskylä, PO Box 35 (YFL), 40500 Jyväskylä (Finland)

    2015-12-15

    An experimental observation of a rotating plasma structure in a 2.45 GHz microwave-driven hydrogen discharge is reported. The rotation is presumably produced by E × B drift. The formation of the rotating plasma structure is sensitive to the strength of the off-resonance static magnetic field. The rotation frequency is on the order of 10 kHz and is affected by the neutral gas pressure and applied microwave power.

  11. Plasma resonance in anisotropic layered high-Tc superconductors

    DEFF Research Database (Denmark)

    Sakai, Shigeki; Pedersen, Niels Falsig

    1999-01-01

    The plasma resonance is described theoretically by the inductive coupling model for a large stacked Josephson-junction system such as the intrinsic Josephson-junction array in anisotropic high- T-c superconductors. Eigenmodes of the plasma oscillation are analytically described and a numerical...

  12. Electron Cyclotron Resonance Heating of a High-Density Plasma

    DEFF Research Database (Denmark)

    Hansen, F. Ramskov

    1986-01-01

    Various schemes for electron cyclotron resonance heating of tokamak plasmas with the ratio of electron plasma frequency to electron cyclotron frequency, "»pe/^ce* larger than 1 on axis, are investigated. In particular, a mode conversion scheme is investigated using ordinary waves at the fundamental...

  13. Magnetic Field Dependence and Q of the Josephson Plasma Resonance

    DEFF Research Database (Denmark)

    Pedersen, Niels Falsig; Finnegan, T. F.; Langenberg, D. N.

    1972-01-01

    The results of an experimental study of the magnetic field dependence of the Josephson-plasma-resonance frequency and linewidth in Pb-Pb oxide-Pb tunnel junctions are reported. In the presence of an external magnetic field, the plasma mode is found to be sensitive to an antisymmetric component...... of supercurrent density which is not observed in conventional measurements of the field-dependent critical current. The frequency and field dependence of the plasma-resonance linewidth are interpreted as evidence that the previously unobserved quasiparticle-pair-interference tunnel current predicted by Josephson...

  14. Laser induced phase locking of hydrogen plasma striations

    Energy Technology Data Exchange (ETDEWEB)

    Glab, W.; Nayfeh, M.H.

    1982-04-01

    Laser induced transient striations of a hydrogen discharge plasma are studied as a function of the ''detuning'' of the discharge parameters from the steady-state oscillatory response conditions. We observed laser induced phase locking of the steady-state striations.

  15. Hydrogen plasma treatment of silicon dioxide for improved silane deposition.

    Science.gov (United States)

    Gupta, Vipul; Madaan, Nitesh; Jensen, David S; Kunzler, Shawn C; Linford, Matthew R

    2013-03-19

    We describe a method for plasma cleaning silicon surfaces in a commercial tool that removes adventitious organic contamination and enhances silane deposition. As shown by wetting, ellipsometry, and XPS, hydrogen, oxygen, and argon plasmas effectively clean Si/SiO2 surfaces. However, only hydrogen plasmas appear to enhance subsequent low-pressure chemical vapor deposition of silanes. Chemical differences between the surfaces were confirmed via (i) deposition of two different silanes: octyldimethylmethoxysilane and butyldimethylmethoxysilane, as evidenced by spectroscopic ellipsometry and wetting, and (ii) a principal components analysis (PCA) of TOF-SIMS data taken from the different plasma-treated surfaces. AFM shows no increase in surface roughness after H2 or O2 plasma treatment of Si/SiO2. The effects of surface treatment with H2/O2 plasmas in different gas ratios, which should allow greater control of surface chemistry, and the duration of the H2 plasma (complete surface treatment appeared to take place quickly) are also presented. We believe that this work is significant because of the importance of silanes as surface functionalization reagents, and in particular because of the increasing importance of gas phase silane deposition.

  16. Modification of Plasma Solitons by Resonant Particles

    DEFF Research Database (Denmark)

    Karpman, Vladimir; Lynov, Jens-Peter; Michelsen, Poul;

    1979-01-01

    Experimental and numerical results are compared with new theoretical results describing soliton propagation and deformation in a strongly magnetized, plasma-loaded waveguide.......Experimental and numerical results are compared with new theoretical results describing soliton propagation and deformation in a strongly magnetized, plasma-loaded waveguide....

  17. Investigation of plasma hydrogenation and trapping mechanism for layer transfer

    Science.gov (United States)

    Chen, Peng; Chu, Paul K.; Höchbauer, T.; Lee, J.-K.; Nastasi, M.; Buca, D.; Mantl, S.; Loo, R.; Caymax, M.; Alford, T.; Mayer, J. W.; Theodore, N. David; Cai, M.; Schmidt, B.; Lau, S. S.

    2005-01-01

    Hydrogen ion implantation is conventionally used to initiate the transfer of Si thin layers onto Si wafers coated with thermal oxide. In this work, we studied the feasibility of using plasma hydrogenation to replace high dose H implantation for layer transfer. Boron ion implantation was used to introduce H-trapping centers into Si wafers to illustrate the idea. Instead of the widely recognized interactions between boron and hydrogen atoms, this study showed that lattice damage, i.e., dangling bonds, traps H atoms and can lead to surface blistering during hydrogenation or upon postannealing at higher temperature. The B implantation and subsequent processes control the uniformity of H trapping and the trap depths. While the trap centers were introduced by B implantation in this study, there are many other means to do the same without implantation. Our results suggest an innovative way to achieve high quality transfer of Si layers without H implantation at high energies and high doses.

  18. Interaction of plasma vortices with resonant particles

    DEFF Research Database (Denmark)

    Jovanovic, D.; Pécseli, Hans; Juul Rasmussen, J.

    1990-01-01

    Kinetic effects associated with the electron motion along magnetic field lines in low‐beta plasmas are studied. Using the gyrokinetic description of electrons, a kinetic analog of the reduced magnetohydrodynamic equations is derived, and it is shown that in the strongly nonlinear regime they poss......Kinetic effects associated with the electron motion along magnetic field lines in low‐beta plasmas are studied. Using the gyrokinetic description of electrons, a kinetic analog of the reduced magnetohydrodynamic equations is derived, and it is shown that in the strongly nonlinear regime...... particles. The evolution equations indicate the possibility of excitation of plasma vortices by electron beams....

  19. Hydrogen production from dimethyl ether using corona discharge plasma

    Science.gov (United States)

    Zou, Ji-Jun; Zhang, Yue-Ping; Liu, Chang-Jun

    Dimethyl ether (DME), with its non-toxic character, high H/C ratio and high-energy volumetric density, is an ideal resource for hydrogen production. In this work, hydrogen production from the decomposition of DME using corona discharge has been studied. The corona discharge plasma decomposition was conducted at ambient conditions. The effects of dilution gas (argon), flow rate, frequency and waveforms on the DME decomposition were investigated. The addition of dilution gas can significantly increase the hydrogen production rate. The highest hydrogen production rate with the lowest energy consumption presents at the flow rate of 27.5 Nml min -1. AC voltage is more favored than DC voltage for the production of hydrogen with less energy input. The optimal frequency is 2.0 kHz. The hydrogen production rate is also affected by the input waveform and decreases as following: sinusoid triangular > sinusoid > ramp > square, whereas the sinusoid waveform shows the highest energy efficiency. The corona discharge decomposition of DME is leading to a simple, easy and convenient hydrogen production with no needs of catalyst and external heating.

  20. Electron Plasmas Cooled by Cyclotron-Cavity Resonance

    CERN Document Server

    Povilus, A P; Evans, L T; Evetts, N; Fajans, J; Hardy, W N; Hunter, E D; Martens, I; Robicheaux, F; Shanman, S; So, C; Wang, X; Wurtele, J S

    2016-01-01

    We observe that high-Q electromagnetic cavity resonances increase the cyclotron cooling rate of pure electron plasmas held in a Penning-Malmberg trap when the electron cyclotron frequency, controlled by tuning the magnetic field, matches the frequency of standing wave modes in the cavity. For certain modes and trapping configurations, this can increase the cooling rate by factors of ten or more. In this paper, we investigate the variation of the cooling rate and equilibrium plasma temperatures over a wide range of parameters, including the plasma density, plasma position, electron number, and magnetic field.

  1. Optical emission spectroscopy of argon and hydrogen-containing plasmas

    Science.gov (United States)

    Siepa, Sarah; Danko, Stephan; Tsankov, Tsanko V.; Mussenbrock, Thomas; Czarnetzki, Uwe

    2015-09-01

    Optical emission spectroscopy (OES) on neutral argon is applied to investigate argon, hydrogen and hydrogen-silane plasmas. The spectra are analyzed using an extensive collisional-radiative model (CRM), from which the electron density and the electron temperature (or mean energy) can be calculated. The CRM also yields insight into the importance of different excited species and kinetic processes. The OES measurements are performed on pure argon plasmas at intermediate pressure. Besides, hydrogen and hydrogen-silane plasmas are investigated using argon as a trace gas. Especially for the gas mixture discharges, CRMs for low and high pressure differ substantially. The commonly used line-ratio technique is found to lose its sensitivity for gas mixture discharges at higher pressure. A solution using absolutely calibrated line intensities is proposed. The effect of radiation trapping and the shape of the electron energy distribution function on the results are discussed in detail, as they have been found to significantly influence the results. This work was supported by the Ruhr University Research School PLUS, funded by Germany's Excellence Initiative [DFG GSC 98/3].

  2. Observation of superconductivity in hydrogen sulfide from nuclear resonant scattering.

    Science.gov (United States)

    Troyan, Ivan; Gavriliuk, Alexander; Rüffer, Rudolf; Chumakov, Alexander; Mironovich, Anna; Lyubutin, Igor; Perekalin, Dmitry; Drozdov, Alexander P; Eremets, Mikhail I

    2016-03-18

    High-temperature superconductivity remains a focus of experimental and theoretical research. Hydrogen sulfide (H2S) has been reported to be superconducting at high pressures and with a high transition temperature. We report on the direct observation of the expulsion of the magnetic field in H2S compressed to 153 gigapascals. A thin (119)Sn film placed inside the H2S sample was used as a sensor of the magnetic field. The magnetic field on the (119)Sn sensor was monitored by nuclear resonance scattering of synchrotron radiation. Our results demonstrate that an external static magnetic field of about 0.7 tesla is expelled from the volume of (119)Sn foil as a result of the shielding by the H2S sample at temperatures between 4.7 K and approximately 140 K, revealing a superconducting state of H2S.

  3. Active plasma resonance spectroscopy: a functional analytic description

    Science.gov (United States)

    Lapke, M.; Oberrath, J.; Mussenbrock, T.; Brinkmann, R. P.

    2013-04-01

    The term ‘active plasma resonance spectroscopy’ denotes a class of diagnostic methods which employ the ability of plasmas to resonate on or near the plasma frequency. The basic idea dates back to the early days of discharge physics: a signal in the GHz range is coupled to the plasma via an electrical probe; the spectral response is recorded, and then evaluated with a mathematical model to obtain information on the electron density and other plasma parameters. In recent years, the concept has found renewed interest as a basis of industry compatible plasma diagnostics. This paper analyzes the diagnostic technique in terms of a general description based on functional analytic (or Hilbert Space) methods which hold for arbitrary probe geometries. It is shown that the response function of the plasma-probe system can be expressed as a matrix element of the resolvent of an appropriately defined dynamical operator. A specialization of the formalism to a symmetric probe design is given, as well as an interpretation in terms of a lumped circuit model consisting of series resonance circuits. We present ideas for an optimized probe design based on geometric and electrical symmetry.

  4. Gas breakdown and plasma impedance in split-ring resonators

    Science.gov (United States)

    Hoskinson, Alan R.; Parsons, Stephen; Hopwood, Jeffrey

    2016-02-01

    The appearance of resonant structures in metamaterials coupled to plasmas motivates the systematic investigation of gas breakdown and plasma impedance in split-ring resonators over a frequency range of 0.5-9 GHz. In co-planar electrode gaps of 100 μm, the breakdown voltage amplitude decreases from 280 V to 225 V over this frequency range in atmospheric argon. At the highest frequency, a microplasma can be sustained using only 2 mW of power. At 20 mW, we measure a central electron density of 2 × 1020 m-3. The plasma-electrode overlap plays a key role in the microplasma impedance and causes the sheath impedance to dominate the plasma resistance at very low power levels. Contribution to the Topical Issue "Recent Breakthroughs in Microplasma Science and Technology", edited by Kurt Becker, Jose Lopez, David Staack, Klaus-Dieter Weltmann and Wei Dong Zhu.

  5. Direct synthesis of hydrogen peroxide from plasma-water interactions

    OpenAIRE

    Jiandi Liu; Bangbang He; Qiang Chen; Junshuai Li; Qing Xiong; Guanghui Yue; Xianhui Zhang; Size Yang; Hai Liu; Qing Huo Liu

    2016-01-01

    Hydrogen peroxide (H2O2) is usually considered to be an important reagent in green chemistry since water is the only by-product in H2O2 involved oxidation reactions. Early studies show that direct synthesis of H2O2 by plasma-water interactions is possible, while the factors affecting the H2O2 production in this method remain unclear. Herein, we present a study on the H2O2 synthesis by atmospheric pressure plasma-water interactions. The results indicate that the most important factors for the ...

  6. Cleaning of SiC surfaces by low temperature ECR microwave hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Huang Lingqin; Zhu Qiaozhi; Gao Mingchao [School of Electronic Science and Technology, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, 116024 (China); Qin Fuwen [State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), Dalian University of Technology, 116024 (China); Wang Dejun, E-mail: dwang121@dlut.edu.cn [School of Electronic Science and Technology, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, 116024 (China)

    2011-09-15

    N-type 4H-SiC (0 0 0 1) surfaces were cleaned by low temperature hydrogen plasma in electronic cyclotron resonance (ECR) microware plasma system. The effects of the hydrogen plasma treatment (HPT) on the structure, chemical and electronic properties of surfaces were characterized by in situ reflection high energy electron diffraction (RHEED) and X-ray photoelectron spectroscopy (XPS). The RHEED results indicate that the structures of the films are strongly dependent on the treatment temperature and time. Significant improvements in quality of 4H-SiC films can be obtained with the temperature ranging from 200 deg. C to 700 deg. C for an appropriate treatment period. The XPS results show that the surface oxygen is greatly reduced and the carbon contamination is completely removed from the 4H-SiC surfaces. The hydrogenated SiC surfaces exhibit an unprecedented stability against oxidation in the air. The surface Fermi level moves toward the conduction band in 4H-SiC after the treatment indicating an unpinning Fermi level with the density of surfaces states as low as 8.09 x 10{sup 10} cm{sup -2} eV{sup -1}.

  7. Effect of Hydrogen Plasma on Model Corrosion Layers of Bronze

    Science.gov (United States)

    Fojtíková, P.; Sázavská, V.; Mika, F.; Krčma, F.

    2016-05-01

    Our work is about plasmachemical reduction of model corrosion layers. The model corrosion layers were produced on bronze samples with size of 10 × 10 × 5 mm3, containing Cu and Sn. Concentrated hydrochloric acid was used as a corrosive environment. The application of reduction process in low-pressure low-temperature hydrogen plasma followed. A quartz cylindrical reactor with two outer copper electrodes was used. Plasma discharge was generated in pure hydrogen by a RF generator. Each corroded sample was treated in different conditions (supplied power and a continual or pulsed regime with a variable duty cycle mode). Process monitoring was ensured by optical emission spectroscopy. After treatment, samples were analyzed by SEM and EDX.

  8. Exploring the electron density in plasma induced by EUV radiation: II. Numerical studies in argon and hydrogen

    CERN Document Server

    Astakhov, D I; Lee, C J; Ivanov, V V; Krivtsun, V M; Koshelev, K N; Lopaev, D V; van der Horst, R M; Beckers, J; Osorio, E A; Bijkerk, F

    2016-01-01

    We used numerical modeling to study the evolution of EUV-induced plasmas in argon and hydrogen. The results of simulations were compared to the electron densities measured by microwave cavity resonance spectroscopy. It was found that the measured electron densities can be used to derive the integral amount of plasma in the cavity. However, in some regimes, the impact of the setup geometry, EUV spectrum, and EUV induced secondary emission should be taken into account. The influence of these parameters on the generated plasma and the measured electron density is discussed.

  9. Hydrogen in tungsten as plasma-facing material

    Science.gov (United States)

    Roth, Joachim; Schmid, Klaus

    2011-12-01

    Materials facing plasmas in fusion experiments and future reactors are loaded with high fluxes (1020-1024 m-2 s-1) of H, D and T fuel particles at energies ranging from a few eV to keV. In this respect, the evolution of the radioactive T inventory in the first wall, the permeation of T through the armour into the coolant and the thermo-mechanical stability after long-term exposure are key parameters determining the applicability of a first wall material. Tungsten exhibits fast hydrogen diffusion, but an extremely low solubility limit. Due to the fast diffusion of hydrogen and the short ion range, most of the incident ions will quickly reach the surface and recycle into the plasma chamber. For steady-state operation the solute hydrogen for the typical fusion reactor geometry and wall conditions can reach an inventory of about 1 kg. However, in short-pulse operation typical of ITER, solute hydrogen will diffuse out after each pulse and the remaining inventory will consist of hydrogen trapped in lattice defects, such as dislocations, grain boundaries and irradiation-induced traps. In high-flux areas the hydrogen energies are too low to create displacement damage. However, under these conditions the solubility limit will be exceeded within the ion range and the formation of gas bubbles and stress-induced damage occurs. In addition, simultaneous neutron fluxes from the nuclear fusion reaction D(T,n)α will lead to damage in the materials and produce trapping sites for diffusing hydrogen atoms throughout the bulk. The formation and diffusive filling of these different traps will determine the evolution of the retained T inventory. This paper will concentrate on experimental evidence for the influence different trapping sites have on the hydrogen inventory in W as studied in ion beam experiments and low-temperature plasmas. Based on the extensive experimental data, models are validated and applied to estimate the contribution of different traps to the tritium inventory in

  10. Measurement of plasma hydrogen sulfide in vivo and in vitro.

    Science.gov (United States)

    Shen, Xinggui; Pattillo, Christopher B; Pardue, Sibile; Bir, Shyamal C; Wang, Rui; Kevil, Christopher G

    2011-05-01

    The gasotransmitter hydrogen sulfide is known to regulate multiple cellular functions during normal and pathophysiological states. However, a paucity of concise information exists regarding quantitative amounts of hydrogen sulfide involved in physiological and pathological responses. This is primarily due to disagreement among various methods employed to measure free hydrogen sulfide. In this article, we describe a very sensitive method of measuring the presence of H₂S in plasma down to nanomolar levels, using monobromobimane (MBB). The current standard assay using methylene blue provides erroneous results that do not actually measure H₂S. The method presented herein involves derivatization of sulfide with excess MBB in 100 mM Tris-HCl buffer (pH 9.5, 0.1 mM DTPA) for 30 min in 1% oxygen at room temperature. The fluorescent product sulfide-dibimane (SDB) is analyzed by RP-HPLC using an eclipse XDB-C18 (4.6 × 250 mm) column with gradient elution by 0.1% (v/v) trifluoroacetic acid in acetonitrile. The limit of detection for sulfide-dibimane is 2 nM and the SDB product is very stable over time, allowing batch storage and analysis. In summary, our MBB method is suitable for sensitive quantitative measurement of free hydrogen sulfide in multiple biological samples such as plasma, tissue and cell culture lysates, or media.

  11. Natural and Unnatural Parity Resonance States in the Positron-Hydrogen System with Screened Coulomb Interactions

    Directory of Open Access Journals (Sweden)

    Ye Ning

    2015-12-01

    Full Text Available In the present work, we report calculations of resonances in the positron-hydrogen system interacting with screened Coulomb potentials using the method of complex scaling together with employing correlated Hylleraas wave functions. Resonances with natural and unnatural parities are investigated. For the natural parity case, resonance parameters (energy and width for D-wave resonance states with even parity lying below various positronium and hydrogen thresholds up to the H(N = 4 level are determined. For the unnatural parity case, results for P-even and D-odd resonance states with various screened Coulomb interaction strengths are located below different lower-lying Ps and H thresholds.

  12. Active plasma resonance spectroscopy: A functional analytic description

    CERN Document Server

    Lapke, Martin; Mussenbrock, Thomas; Brinkmann, Ralf Peter

    2012-01-01

    The term "Active Plasma Resonance Spectroscopy" refers to a class of diagnostic methods which employ the ability of plasmas to resonate on or near the plasma frequency. The basic idea dates back to the early days of discharge physics: An signal in the GHz range is coupled to the plasma via an electrical probe; the spectral response is recorded, and then evaluated with a mathematical model to obtain information on the electron density and other plasma parameters. In recent years, the concept has found renewed interest as a basis of industry compatible plasma diagnostics. This paper analyzes the diagnostics technique in terms of a general description based on functional analytic (or Hilbert Space) methods which hold for arbitrary probe geometries. It is shown that the response function of the plasma-probe system can be expressed as a matrix element of the resolvent of an appropriately defined dynamical operator. A specialization of the formalism for a symmetric probe desing is given, as well as an interpreation...

  13. Plasma screening effects on the energies of hydrogen atom

    Energy Technology Data Exchange (ETDEWEB)

    Soylu, A. [Department of Physics, Nigde University, 51240 Nigde (Turkey)

    2012-07-15

    A more general exponential cosine screened Coulomb potential is used for the first time to investigate the screening effects on the hydrogen atom in plasmas. This potential is examined for four different cases that correspond to four different type potentials when the different parameters are used in the potential within the framework of the well-known asymptotic iteration method. By solving the corresponding the radial Schroedinger equation with the screened and exponential cosine screened Coulomb potentials and comparing the obtained energy eigenvalues with the results of other studies, the applicability of the method to this kind of plasma physics problem is shown. The energy values of more general exponential cosine screened Coulomb potential are presented for various parameters in the potential. One of the advantages of the present potential is that it exhibits stronger screening effect than that of the exponential cosine screened Coulomb potential and it is also reduced to screened Coulomb and exponential cosine screened Coulomb as well as Coulomb potentials for special values of parameters. The parameters in the potential would be useful to model screening effects which cause an increase or decrease in the energy values of hydrogen atom in both Debye and quantum plasmas and in this manner this potential would be useful for the investigations of the atomic structure and collisions in plasmas.

  14. Direct synthesis of hydrogen peroxide from plasma-water interactions

    Science.gov (United States)

    Liu, Jiandi; He, Bangbang; Chen, Qiang; Li, Junshuai; Xiong, Qing; Yue, Guanghui; Zhang, Xianhui; Yang, Size; Liu, Hai; Liu, Qing Huo

    2016-12-01

    Hydrogen peroxide (H2O2) is usually considered to be an important reagent in green chemistry since water is the only by-product in H2O2 involved oxidation reactions. Early studies show that direct synthesis of H2O2 by plasma-water interactions is possible, while the factors affecting the H2O2 production in this method remain unclear. Herein, we present a study on the H2O2 synthesis by atmospheric pressure plasma-water interactions. The results indicate that the most important factors for the H2O2 production are the processes taking place at the plasma-water interface, including sputtering, electric field induced hydrated ion emission, and evaporation. The H2O2 production rate reaches ~1200 μmol/h when the liquid cathode is purified water or an aqueous solution of NaCl with an initial conductivity of 10500 μS cm‑1.

  15. Reduction of TiO2 with hydrogen cold plasma in DC pulsed glow discharge

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yu-wen; DING Wei-zhong; LU Xiong-gang; GUO Shu-qiang; XU Kuang-di

    2005-01-01

    The reduction of TiO2 to Ti2O3 with hydrogen cold plasma generated by a DC pulsed glow discharge was realized under 2 500 Pa at 1 233 K. Only a little of Ti10O19 and Ti9O17 was detected for using molecular hydrogen.Enhancement effects of hydrogen cold plasma on the reduction were discussed in terms of thermodynamic coupling,kinetics and plasma sheath. The exited hydrogen species are considered more effective reducing agents. It is instructive to reduce refractory oxides with plasma hydrogen at the reduced temperature.

  16. Novel Composite Hydrogen-Permeable Membranes for Nonthermal Plasma Reactors for the Decomposition of Hydrogen Sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Morris Argyle; John Ackerman; Suresh Muknahallipatna; Jerry Hamann; Stanislaw Legowski; Gui-Bing Zhao; Sanil John; Ji-Jun Zhang; Linna Wang

    2007-09-30

    The goal of this experimental project was to design and fabricate a reactor and membrane test cell to dissociate hydrogen sulfide (H{sub 2}S) in a nonthermal plasma and to recover hydrogen (H{sub 2}) through a superpermeable multi-layer membrane. Superpermeability of hydrogen atoms (H) has been reported by some researchers using membranes made of Group V transition metals (niobium, tantalum, vanadium, and their alloys), but it was not achieved at the moderate pressure conditions used in this study. However, H{sub 2}S was successfully decomposed at energy efficiencies higher than any other reports for the high H{sub 2}S concentration and moderate pressures (corresponding to high reactor throughputs) used in this study.

  17. Simulation of plasma filled hemispherical cavity as dielectric resonator antenna

    Science.gov (United States)

    Trenchev, G.; Kissóvski, Zh

    2016-10-01

    Plasma antennas are becoming an increasingly interesting research topic because of their uncommon characteristics. They are highly configurable, can be turned on and off rapidly, and exhibit lower thermal noise compared to metal antennas. In recent years, research has been conducted on cylindrical plasma columns sustained by DC, RF or microwave field, and their application as leaky wave antennas or as regular monopole antennas. Dielectric resonator antennas (DRA) with high dielectric permittivity are known for their small size and excellent operating characteristics for modern mobile communications (WiMAX, LTE). Hemispherical dielectric resonator antennas are characterized by simple shape, high radiation efficiency and wide bandwidth. Hemispherical DRA with a low density weakly ionized plasma as dielectric material will combine the positive features of plasma and dielectric antennas, and is particularly interesting, as antennas of this type have not been studied yet. The hemispherical plasma antenna is simulated with Ansoft HFSS in the microwave S-band. Obtained radiation pattern and bandwidth show the advantages of hemispherical plasma antennas for future communication technology.

  18. Electric disruption in a hydrogen toroidal plasma; Ruptura eletrica em um plasma toroidal em hidrogenio

    Energy Technology Data Exchange (ETDEWEB)

    Roberto, M. [UNESP, Guaratingueta, SP (Brazil). Faculdade de Engenharia. Dept. de Fisica; Silva, C.A.B. [Centro Tecnico Aeroespacial (CTA-IEAv), Sao Jose dos Campos, SP (Brazil). Inst. de Estudos Avancados; Goes, L.C.S.; Sudano, J.P. [Centro Tecnico Aeroespacial, Sao Jose dos Campos, SP (Brazil). Inst. Tecnologico de Aeronautica

    1990-12-31

    By using a zero-dimensional model the ionizing initial phase of a toroidal plasma produced in hydrogen was investigated. The model consists on describing the plasma time evolution through the density and particle temperature space averaged on the plasma volume. The involved equations are energy and particles balance equations (electrons and ions). The electron loss is due to ambipolar diffusion in the presence of magnetic field. The electron energy loss is due to ionizing, processes of Coulomb interaction and diffusion. The ohmic heating transformer gives a initial voltage necessary to the breaking 11 refs., 2 figs.

  19. Hydrogen production by coal plasma gasification for fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Galvita, V. [Max-Planck-Institute, Dynamics of Complex Technical Systems, Sandtorstrasse 1, 39106, Magdeburg (Germany); Messerle, V.E.; Ustimenko, A.B. [Research Department of Plasmotechnics, 22 Zvereva str., 050100 Almaty (Kazakhstan)

    2007-11-15

    Coal gasification in steam and air atmosphere under arc plasma conditions has been investigated with Podmoskovnyi brown coal, Kuuchekinski bituminous coal and Canadian petrocoke. It was found that for those coals the gasification degree to synthesis gas were 92.3%, 95.8 and 78.6% correspondingly. The amount of produced syngas was 30-40% higher in steam than in air gasification of the coal. The reduction of the carbon monoxide content in the hydrogen-rich reformate gas for low-temperature fuel cell applications normally involves high- and low-temperature water gas shift reactors followed by selective oxidation of residual carbon monoxide. It is shown that the carbon monoxide content can be reduced in one single reactor, which is based on an iron redox cycle. During the reduction phase of the cycle, the raw gas mixture of H{sub 2} and CO reduces a Fe{sub 3}O{sub 4}-CeO{sub 2}-ZrO{sub 2} sample, while during the oxidation phase steam re-oxidizes the iron and simultaneously hydrogen is being produced. The integration of the redox iron process with a coal plasma gasification technology in future allows the production of CO{sub x}-free hydrogen. (author)

  20. Collector optic cleaning by in-situ hydrogen plasma

    Science.gov (United States)

    Elg, Daniel T.; Panici, Gianluca A.; Srivastava, Shailendra N.; Ruzic, D. N.

    2015-03-01

    Extreme ultraviolet (EUV) lithography sources produce EUV photons by means of a hot, dense, highly-ionized Sn plasma. This plasma expels high-energy Sn ions and neutrals, which deposit on the collector optic used to focus the EUV light. This Sn deposition lowers the reflectivity of the collector optic, necessitating downtime for collector cleaning and replacement. A method is being developed to clean the collector with an in-situ hydrogen plasma, which provides hydrogen radicals that etch the Sn by forming gaseous SnH4. This method has the potential to significantly reduce collector-related source downtime. EUV reflectivity restoration and Sn cleaning have been demonstrated on multilayer mirror samples attached to a Sn-coated 300mm-diameter steel dummy collector driven at 300W RF power with 500sccm H2 and a pressure of 260mTorr. Use of the in-situ cleaning method is also being studied at industriallyapplicable high pressure (1.3 Torr). Plasma creation across the dummy collector surface has been demonstrated at 1.3 Torr with 1000sccm H2 flow, and etch rates have been measured. Additionally, etching has been demonstrated at higher flow rates up to 3200sccm. A catalytic probe has been used to measure radical density at various pressures and flows. The results lend further credence to the hypothesis that Sn removal is limited not by radical creation but by the removal of SnH4 from the plasma. Additionally, further progress has been made in an attempt to model the physical processes behind Sn removal.

  1. Residual gas entering high density hydrogen plasma: rarefaction due to rapid heating

    NARCIS (Netherlands)

    N. den Harder,; D.C. Schram,; W. J. Goedheer,; de Blank, H. J.; M. C. M. van de Sanden,; van Rooij, G. J.

    2015-01-01

    The interaction of background molecular hydrogen with magnetized (0.4 T) high density (1–5 × 10 20  m −3 ) low temperature (∼3 eV) hydrogen plasma was inferred from the Fulcher band emission in the linear plasma generator Pilot-PSI. In the plasma center,

  2. Effect of oxygen plasma on nanomechanical silicon nitride resonators

    Science.gov (United States)

    Luhmann, Niklas; Jachimowicz, Artur; Schalko, Johannes; Sadeghi, Pedram; Sauer, Markus; Foelske-Schmitz, Annette; Schmid, Silvan

    2017-08-01

    Precise control of tensile stress and intrinsic damping is crucial for the optimal design of nanomechanical systems for sensor applications and quantum optomechanics in particular. In this letter, we study the influence of oxygen plasma on the tensile stress and intrinsic damping of nanomechanical silicon nitride resonators. Oxygen plasma treatments are common steps in micro and nanofabrication. We show that oxygen plasma for only a few minutes oxidizes the silicon nitride surface, creating several nanometer thick silicon dioxide layers with a compressive stress of 1.30(16) GPa. Such oxide layers can cause a reduction in the effective tensile stress of a 50 nm thick stoichiometric silicon nitride membrane by almost 50%. Additionally, intrinsic damping linearly increases with the silicon dioxide film thickness. An oxide layer of 1.5 nm grown in just 10 s in a 50 W oxygen plasma almost doubled the intrinsic damping. The oxide surface layer can be efficiently removed in buffered hydrofluoric acid.

  3. A laser-induced fluorescence measurement technique for obtaining neutral hydrogen densities in plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Yao, X.Z.; Yang, T.F.; Chang-Diaz, F.R. [Plasma Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    1995-09-01

    The resonance fluorescence of neutral hydrogen illuminated by {ital H}{sub {alpha}} radiation has been used as a technique for the spatially and temporally resolved density measurements of neutral hydrogen in high temperature plasmas, such as in the tokamak and magnetic mirror plasma fusion devices. The fluorescence signal, usually very weak and buried in the background of stray laser light and {ital H}{sub {alpha}} emission, is very difficult to extract and its measurements are inaccurate. This paper discusses the improvement of the signal extraction using two optical path laser-induced fluorescence (LIF) methods. One optical path carries the fluorescence signal and the background (the stray laser light and {ital H}{sub {alpha}} emission), whereas the other path carries only the background signal. By combining these two signals, a clean fluorescence signal can be isolated by subtracting out the background using a differential amplifier. The measurement is obtained instantaneously from these two signals which are taken simultaneously in one pulse rather than being extracted from two separate spectra taken in two sequential pulses (double pulses). This method, therefore, makes a significant improvement on the double pulse technique in terms of the accuracy of the measurement and the time resolution. Using this LIF technique the measurement of the neutral density profile in the exhaust of a tandem mirror plasma propulsion device is obtained and presented. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  4. Numerical Study on the Acetylene Concentration in the Hydrogen-Carbon System in a Hydrogen Plasma Torch

    Institute of Scientific and Technical Information of China (English)

    CHEN Longwei; SHEN Jie; SHU Xingsheng; FANG Shidong; ZHANG Lipeng; MENG Yuedong

    2009-01-01

    Effects of the hydrogen/carbon mole ratio and pyrolysis gas pressure on the acetylene concentration in the hydrogen-carbon system in a plasma torch were numerically calculated by using the chemical thermodynamic equilibrium method of Gibbs free energy. The calculated results indicate that the hydrogen concentration and the pyrolysis gas pressure play crucial roles in acetylene formation. Appropriately abundant hydrogen, with a mole ratio of hydrogen to carbon about 1 or 2, and a relatively high pyrolysis gas pressure can enhance the acetylene concentration. In the experiment, a compromised project consisting of an appropriate hydrogen flow rate and a feasible high pyrolysis gas pressure needs to be carried out to increase the acetylene concentration from coal pyrolysis in the hydrogen plasma torch.

  5. Scattering processes and electrical conductivity of partially ionized hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Ramazanov, T. [Fachbereich Physik, Universitaet Rostock, D-18051 Rostock (Germany); SRIETP, Al Farabi Kazakh National University, Tole bi, 96a, 480012, Almaty (Kazakhstan); Galiyev, K.; Dzhumagulova, K.N. [SRIETP, Al Farabi Kazakh National University, Tole bi, 96a, 480012, Almaty (Kazakhstan); Roepke, G.; Redmer, R. [Fachbereich Physik, Universitaet Rostock, D-18051 Rostock (Germany)

    2003-07-01

    We consider partially ionized hydrogen plasma for the density region n{sub e} = (10{sup 18} / 10{sup 22}) cm{sup -} {sup 3}. The cross sections for scattering processes between the particles are calculated within the partial wave method. Charged particles in the system (electrons, protons) interact via an effective potential that takes into account three-particle correlations. The Buckingham polarization potential is used to describe electron-atom and proton-atom interactions. The electrical conductivity is determined using the Chapman-Enskog method. The results are compared with other available data. (Abstract Copyright [2003], Wiley Periodicals, Inc.)

  6. Modeling of Stark–Zeeman Lines in Magnetized Hydrogen Plasmas

    Indian Academy of Sciences (India)

    J. Rosato; H. Bufferand; H. Capes; M. Koubiti; L. Godbert-Mouret; Y. Marandet; R. Stamm

    2015-12-01

    The action of electric and magnetic fields on atomic species results in a perturbation of the energy level structure, which alters the shape of spectral lines. In this work, we present the Zeeman–Stark line shape simulation method and perform new calculations of hydrogen Lyman and Balmer lines, in the framework of magnetic fusion research. The role of the Zeeman effect, fine structure and the plasma's non-homogeneity along the line-of-sight are investigated. Under specific conditions, our results are applicable to DA white dwarf atmospheres.

  7. The LC resonance probe for determining local plasma density

    Energy Technology Data Exchange (ETDEWEB)

    Boris, D R; Fernsler, R F; Walton, S G, E-mail: david.boris.ctr@nrl.navy.mi [Naval Research Laboratory, Charge Particle Physics Branch-Code 6752, Plasma Physics Division, 4555 Overlook Ave. SW, Washington, DC 20375 (United States)

    2011-04-15

    We present a novel plasma diagnostic for measuring local plasma density in reactive-gas plasmas, and depositing plasmas. The diagnostic uses a network analyzer to measure the LC resonance (LCR) frequency of a parallel plate capacitor with inductive leads. The location of the LCR ({omega}{sub R}) in frequency space is then used as a measure of the plasma dielectric constant bold varepsilon{sub p} between the plates. By properly constructing the LCR probe, {omega}{sub R} can be tuned such that {omega}{sub R} >> {omega}{sub ce}, where {omega}{sub ce} is the electron-cyclotron frequency. Thus, the probe can be used in plasmas with varying degrees of magnetization while avoiding complications introduced to bold varepsilon{sub p} when {omega} is comparable to {omega}{sub ce}. Density measurements from the LCR probe are compared with Langmuir probe measurements in an electron-beam generated plasma in which density varied from 10{sup 9} to 10{sup 11} cm{sup -3}. An axial magnetic field, typically used to confine the electron beam, was varied between 0 to 300 G. The LCR probe showed good agreement with a Langmuir probe across the entire range of magnetic fields.

  8. Dislocation in heteroepitaxial diamond visualized by hydrogen plasma etching

    Energy Technology Data Exchange (ETDEWEB)

    Ichikawa, K.; Kodama, H. [Department of Electrical Engineering and Electronics, Aoyama Gakuin University, Sagamihara 229-0206 (Japan); Suzuki, K. [TOPLAS ENGINEERING Co., Ltd., Chofu, Tokyo 182-0006 (Japan); Sawabe, A. [Department of Electrical Engineering and Electronics, Aoyama Gakuin University, Sagamihara 229-0206 (Japan)

    2016-02-01

    The classification of etch pits formed by hydrogen plasma etching on heteroepitaxial diamond has been done by cross-sectional transmission electron microscope (TEM). We demonstrated that the origin of etch pit was mainly [001] threading dislocation. From invisibility criterion of dislocation contrast in TEM observation, this dislocation was identified as edge and 45° mixed dislocation. The correlation between dislocation types and etch pit shape was discussed. - Highlights: • The etch pits formed by plasma etching on heteroepitaxial diamond have been clarified by TEM. • The origin of etch pit was mainly [001] threading dislocation. • These dislocations were identified as edge and 45° mixed type. • The correlation between dislocation types and etch pit shape.

  9. Wakefield Resonant Excitation by Intense Laser Pulse in Capillary Plasma%Wakefield Resonant Excitation by Intense Laser Pulse in Capillary Plasma

    Institute of Scientific and Technical Information of China (English)

    周素云; 袁孝; 刘明萍

    2012-01-01

    The laser-induced plasma wakefield in a capillary is investigated on the basis of a simple two-dimensional analytical model. It is shown that as an intense laser pulse reshaped by the capillary wall propagates in capillary plasma, it resonantly excites a strong wakefield if a suitable laser pulse width and capillary radius are chosen for a certain plasma density. The dependence of the laser width and capillary radius on the plasma density for resonance conditions is considered. The wakefield amplitude and longitudinal scale of bubbles in capillary plasma are much larger than those in unbounded plasma, so the capillary guided plasma wakefield is more favorable to electron acceleration.

  10. Further observations on resonance cones in non-Maxwellian plasmas

    Science.gov (United States)

    Thiemann, H.; Singh, N.

    1983-01-01

    Results on the angular distribution of the electrostatic potential of a pulsating point charge in a warm magnetized plasma permeated by an electron beam are presented. The theoretical formulation for a finite magnetic field is given, and the solution of the resonance cone dispersion relation is presented. Numerical results on the angular distribution of the potential are shown, and the propagation of waves outside the resonance cones is described. It is demonstrated that with the inclusions of a finite magnetic field, the field patterns of a point charge are qualitatively similar to those obtained for a uniaxial plasma. The Cerenkov radiation occurs at angles much smaller than the cold-cone angle, even with the finite magnetic field. When the beam velocity is well above the thermal velocity of the background electrons, a characteristic wave propagation occurs between the cold-cone angles.

  11. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source

    Energy Technology Data Exchange (ETDEWEB)

    Kim, June Young, E-mail: beacoolguy@snu.ac.kr; Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae, E-mail: jkjlsh1@snu.ac.kr; Hwang, Y. S. [Department of Nuclear Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of)

    2016-02-15

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H{sup −} ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ∼4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H{sup −} ion generation in volume-produced negative hydrogen ion sources.

  12. Resonance broadening modification of weak plasma turbulence theory

    Energy Technology Data Exchange (ETDEWEB)

    Hanssen, A. (Max-Planck-Inst. fuer Aeronomie, Katlenburg-Lindau (West Germany))

    1991-02-01

    The author examines the effects on energy spectra of weak Langmuir turbulence when he includes a nonlinear damping due to the perturbation of electron orbits. The physical mechanism under consideration is usually known as a resonance broadening effect. The calculations show that the inclusion of this additional damping reduces the number of cascades predicted from weak turbulence theory for waves detectable with the EISCAT UHF (933 MHz) radar in Tromso, Norway, during RF modification of the ionospheric plasma.

  13. Semiclassical Szego limit of resonance clusters for the hydrogen atom Stark Hamiltonian

    CERN Document Server

    Hislop, Peter D

    2011-01-01

    We study the weighted averages of resonance clusters for the hydrogen atom with a Stark electric field in the weak field limit. We prove a semiclassical Szego-type theorem for resonance clusters showing that the limiting distribution of the resonance shifts concentrates on the classical energy surface corresponding to a rescaled eigenvalue of the hydrogen atom Hamiltonian. This result extends Szego-type results on eigenvalue clusters to resonance clusters. There are two new features in this work: first, the study of resonance clusters requires the use of non self-adjoint operators, and second, the Stark perturbation is unbounded so control of the perturbation is achieved using localization properties of coherent states corresponding to hydrogen atom eigenvalues.

  14. Negative hydrogen ions in a linear helicon plasma device

    Science.gov (United States)

    Corr, Cormac; Santoso, Jesse; Samuell, Cameron; Willett, Hannah; Manoharan, Rounak; O'Byrne, Sean

    2015-09-01

    Low-pressure negative ion sources are of crucial importance to the development of high-energy (>1 MeV) neutral beam injection systems for the ITER experimental tokamak device. Due to their high power coupling efficiency and high plasma densities, helicon devices may be able to reduce power requirements and potentially remove the need for caesium. In helicon sources, the RF power can be coupled efficiently into the plasma and it has been previously observed that the application of a small magnetic field can lead to a significant increase in the plasma density. In this work, we investigate negative ion dynamics in a high-power (20 kW) helicon plasma source. The negative ion fraction is measured by probe-based laser photodetachment, electron density and temperature are determined by a Langmuir probe and tuneable diode laser absorption spectroscopy is used to determine the density of the H(n = 2) excited atomic state and the gas temperature. The negative ion density and excited atomic hydrogen density display a maximum at a low applied magnetic field of 3 mT, while the electron temperature displays a minimum. The negative ion density can be increased by a factor of 8 with the application of the magnetic field. Spatial and temporal measurements will also be presented. The Australian Research Grants Council is acknowledged for funding.

  15. Simulation of the Partially Ionized Negative Hydrogen Plasma

    Science.gov (United States)

    Averkin, Sergey; Gatsonis, Nikolaos; Olson, Lynn

    2012-10-01

    A High Pressure Discharge Negative Ion Source (HPDNIS) operating on hydrogen is been under investigation. The Negative Ion Production (NIP) section of the HPDNIS attaches to the 10-100 Torr RF-discharge chamber with a micronozzle and ends with a grid that extracts the negative ion beam. The partially ionized and reacting plasma flow in the NIP section is simulated using an unstructured three-dimensional Direct Simulation Monte Carlo (U3DSMC) code. The NIP section contains a low-pressure plasma that includes H2, vibrationally-rotationally excited H2^*, negative hydrogen atoms H^-, and electrons. Primary reactions in the NIP section are dissociate attachment, H2^*+e->H^0+H^-and electron collisional detachment, e+H^-->H+2e. The U3DSMC computational domain includes the entrance to the NIP nozzle and the extraction grid at the exit. The flow parameters at the entrance are based on conditions in the RF-discharge chamber and are implemented in U3DSMC using a Kinetic-Moment subsonic boundary conditions method. Neutral--neutral, ion-neutral, Coulomb collisions and charge-neutralizing collisions are implemented in U3DSMC using the no time counter method, electron-molecule collisions are treated by the constant timestep method. Simulations cover the regime of operation of the HPDNIS and examine the flow characteristics inside the NIP section.

  16. DIRECT REDUCTION OF HEMATITE POWDERS VIA COLD HYDROGEN PLASMA

    Directory of Open Access Journals (Sweden)

    Iraldo de Sá Silveira

    2014-12-01

    Full Text Available The goal of this work was to study the reduction kinetics of hematite powders (Fe2O3 using cold hydrogen plasma as reducing agent. Reduction experiments were carried out in a DC pulsed plasma reactor, under hydrogen flow-rates of 300 cm3/min, at pressure of 400 Pa, times from 30 to 120 minutes and temperatures of 320, 340, 360 and 380°C. Fe2O3 powders after reduction experiments were characterized by X-ray diffraction, weight loss of oxygen (gravimetric analyses and light microscopy. The results show that using a reduction temperature of 380°C after 120 min allows obtaining α-iron with a reduction fraction of about 0.93. The powder particles are transformed into two steps: Fe2O3→Fe3O4→Fe-α. The apparent activation energy experimentally established for the reduction of Fe2O3 is about 98.4 kJ/mol.

  17. Coupled-channels optical calculation of positron-hydrogen resonances

    Institute of Scientific and Technical Information of China (English)

    Yu Rong-Mei; Zhou Ya-Jun; Jiao Li-Guang; Cheng Yong-Jun

    2012-01-01

    An application of the coupled-channels optical method is given for the energy-dependent phenomena of positronhydrogen resonances below the n =2 excitation threshold.The equivalent local optical potential is used to account for the target polarization and positronium formation.The calculation includes 9 explicitly physical coupled channels.The lowest S-wave resonance energy position and new resonances are found.Angular dependence of the cross section in the resonance region are investigated.

  18. Characteristics of surface sterilization using electron cyclotron resonance plasma

    Science.gov (United States)

    Yonesu, Akira; Hara, Kazufumi; Nishikawa, Tatsuya; Hayashi, Nobuya

    2016-07-01

    The characteristics of surface sterilization using electron cyclotron resonance (ECR) plasma were investigated. High-energy electrons and oxygen radicals were observed in the ECR zone using electric probe and optical emission spectroscopic methods. A biological indicator (BI), Geobacillus stearothermophilus, containing 1 × 106 spores was sterilized in 120 s by exposure to oxygen discharges while maintaining a temperature of approximately 55 °C at the BI installation position. Oxygen radicals and high-energy electrons were found to be the sterilizing species in the ECR region. It was demonstrated that the ECR plasma could be produced in narrow tubes with an inner diameter of 5 mm. Moreover, sterilization tests confirmed that the spores present inside the narrow tube were successfully inactivated by ECR plasma irradiation.

  19. Low-pressure hydrogen plasmas explored using a global model

    Science.gov (United States)

    Samuell, Cameron M.; Corr, Cormac S.

    2016-02-01

    Low-pressure hydrogen plasmas have found applications in a variety of technology areas including fusion, neutral beam injection and material processing applications. To better understand these discharges, a global model is developed to predict the behaviour of electrons, ground-state atomic and molecular hydrogen, three positive ion species (H+, \\text{H}2+ , and \\text{H}3+ ), a single negative ion species (H-), and fourteen vibrationally excited states of molecular hydrogen ({{\\text{H}}2}≤ft(\\upsilon =1\\right. -14)). The model is validated by comparison with experimental results from a planar inductively coupled GEC reference cell and subsequently applied to the MAGPIE linear helicon reactor. The MAGPIE reactor is investigated for a range of pressures from 1 to 100 mTorr and powers up to 5 kW. With increasing power between 50 W and 5 kW at 10 mTorr the density of all charged species increases as well as the dissociative fraction while the electron temperature remains almost constant at around 3 eV. For gas pressures from 1-100 mTorr at an input power of 1 kW, the electron density remains almost constant, the electron temperature and dissociative fraction decreases, while \\text{H}3+ density increases in density and also dominates amongst ion species. Across these power and pressure scans, electronegativity remains approximately constant at around 2.5%. The power and pressure determines the dominant ion species in the plasma with \\text{H}3+ observed to dominate at high pressures and low powers whereas H+ tends to be dominant at low pressures and high powers. A sensitivity analysis is used to demonstrate how experimental parameters (power, pressure, reactor wall material, geometry etc) influence individual species’ density as well as the electron temperature. Physical reactor changes including the length, radius and wall recombination coefficient are found to have the largest influence on outputs obtained from the model.

  20. Hydrogen production by plasma electrolysis reactor of KOH-ethanol solution

    Science.gov (United States)

    Saksono, N.; Batubara, T.; Bismo, S.

    2016-11-01

    Plasma electrolysis has great potential in industrial hydrogen production, chlor-alkali production, and waste water treatment. Plasma electrolysis produces more hydrogen with less energy consumption than hydrocarbon or Faraday electrolysis. This paper investigated the hydrogen production by plasma electrolysis of KOH-ethanol solution at 80 °C and 1 atm. The effects of voltage, KOH solution, ethanol addition, and cathode deep on plasma electrolysis performance were studied. The hydrogen production was analyzed using bubble flow meter and hydrogen analyzer. The electrical energy consumption was measured by a digital multimeter. The effectiveness of plasma electrolysis in terms of hydrogen production was evaluated by comparing it with Faraday Electrolysis. The results showed that hydrogen produced by plasma electrolysis is 149 times higher than the hydrogen produced by Faraday electrolysis. The optimum hydrogen production was 50.71 mmol/min, obtained at 700 V with 0.03 M KOH, 10% vol ethanol and 6.6 cm cathode deep, with energy consumption 1.49 kJ/mmol. The result demonstrates a promising path for hydrogen production by utilizing plasma electrolysis reactor.

  1. Development of a Hydrogen Gas Sensor Using a Double Saw Resonator System at Room Temperature

    Directory of Open Access Journals (Sweden)

    Zainab Yunusa

    2015-02-01

    Full Text Available A double SAW resonator system was developed as a novel method for gas sensing applications. The proposed system was investigated for hydrogen sensing. Commercial Surface Acoustic Wave (SAW resonators with resonance frequencies of 433.92 MHz and 433.42 MHz were employed in the double SAW resonator system configuration. The advantages of using this configuration include its ability for remote measurements, and insensitivity to vibrations and other external disturbances. The sensitive layer is composed of functionalized multiwalled carbon nanotubes and polyaniline nanofibers which were deposited on pre-patterned platinum metal electrodes fabricated on a piezoelectric substrate. This was mounted into the DSAWR circuit and connected in parallel. The sensor response was measured as the difference between the resonance frequencies of the SAW resonators, which is a measure of the gas concentration. The sensor showed good response towards hydrogen with a minimum detection limit of 1%.

  2. Development of a hydrogen gas sensor using a double SAW resonator system at room temperature.

    Science.gov (United States)

    Yunusa, Zainab; Hamidon, Mohd Nizar; Ismail, Alyani; Mohd Isa, Maryam; Yaacob, Mohd Hanif; Rahmanian, Saeed; Ibrahim, Siti Azlida; Shabaneh, Arafat A A

    2015-02-26

    A double SAW resonator system was developed as a novel method for gas sensing applications. The proposed system was investigated for hydrogen sensing. Commercial Surface Acoustic Wave (SAW) resonators with resonance frequencies of 433.92 MHz and 433.42 MHz were employed in the double SAW resonator system configuration. The advantages of using this configuration include its ability for remote measurements, and insensitivity to vibrations and other external disturbances. The sensitive layer is composed of functionalized multiwalled carbon nanotubes and polyaniline nanofibers which were deposited on pre-patterned platinum metal electrodes fabricated on a piezoelectric substrate. This was mounted into the DSAWR circuit and connected in parallel. The sensor response was measured as the difference between the resonance frequencies of the SAW resonators, which is a measure of the gas concentration. The sensor showed good response towards hydrogen with a minimum detection limit of 1%.

  3. Resonant excitation of waves by a spiraling ion beam on the large plasma device

    Science.gov (United States)

    Tripathi, Shreekrishna

    2015-11-01

    The resonant interaction between energetic-ions and plasma waves is a fundamental topic of importance in the space, controlled magnetic-fusion, and laboratory plasma physics. We report new results on the spontaneous generation of traveling shear Alfvén waves and high-harmonic beam-modes in the lower-hybrid range of frequencies by an intense ion beam. In particular, the role of Landau and Doppler-shifted ion-cyclotron resonances (DICR) in extracting the free-energy from the ion-beam and destabilizing Alfvén waves was explored on the Large Plasma Device (LAPD). In these experiments, single and dual-species magnetized plasmas (n ~1010 -1012 cm-3, Te ~ 5.0-10.0 eV, B = 0.6-1.8 kG, He+ and H+ ions, 19.0 m long, 0.6 m diameter) were produced and a spiraling hydrogen ion beam (5-15 keV, 2-10 A, beam-speed/Alfvén-speed = 0.2-1.5, J ~ 50-150 mA/cm2, pitch-angle ~53°) was injected into the plasma. The interaction of the beam with the plasma was diagnosed using a retarding-field energy analyzer, three-axis magnetic-loop, and Langmuir probes. The resonance conditions for the growth of shear Alfvén waves were examined by varying the parameters of the ion-beam and ambient plasma. The experimental results demonstrate that the DICR process is particularly effective in exciting left-handed polarized shear Alfvén waves that propagate in the direction opposite to the ion beam. The high-harmonic beam modes were detected in the vicinity of the spiraling ion beam and contained more than 80 harmonics of Doppler-shifted gyro-frequency of the beam. Work jointly supported by US DOE and NSF and performed at the Basic Plasma Science Facility, UCLA.

  4. Photoluminescence of amorphous carbon films fabricated by layer-by-layer hydrogen plasma chemical annealing method

    Institute of Scientific and Technical Information of China (English)

    徐骏; 黄晓辉; 李伟; 王立; 陈坤基

    2002-01-01

    A method in which nanometre-thick film deposition was alternated with hydrogen plasma annealing (layer-by-layermethod) was applied to fabricate hydrogenated amorphous carbon films in a conventional plasma-enhanced chemicalvapour deposition system. It was found that the hydrogen plasma treatment could decrease the hydrogen concentrationin the films and change the sp2/sp3 ratio to some extent by chemical etching. Blue photoluminescence was observed atroom temperature, as a result of the reduction of sp2 clusters in the films.

  5. Modeling the Spectra of Dense Hydrogen Plasmas: Beyond Occupation Probability

    CERN Document Server

    Gomez, T A; Nagayama, T; Kilcrease, D P; Winget, D E

    2016-01-01

    Accurately measuring the masses of white dwarf stars is crucial in many astrophysical contexts (e.g., asteroseismology and cosmochronology). These masses are most commonly determined by fitting a model atmosphere to an observed spectrum; this is known as the spectroscopic method. However, for cases in which more than one method may be employed, there are well known discrepancies between masses determined by the spectroscopic method and those determined by astrometric, dynamical, and/or gravitational-redshift methods. In an effort to resolve these discrepancies, we are developing a new model of hydrogen in a dense plasma that is a significant departure from previous models. Experiments at Sandia National Laboratories are currently underway to validate these new models, and we have begun modifications to incorporate these models into stellar-atmosphere codes.

  6. Dynamical Properties of Hydrogen in ZnO:H Treated by H2/Ar Plasma under Atmospheric Pressure

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jun Kue; Kwon, Hyeok-Jung; Kim, Han-Sung; Kim, Dae-Il; Cho, Yong Sub [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    ZnO is a wide-band-gap semiconductor with many technological applications, including catalysis, gas sensing, and the fabrication of microelectronic devices. The geometric, electronic, and defect surface structures play a role in many applications of ZnO. Electron spin resonance (ESR) measurement on temperature was made to identify occupied energy states of H in ZnO:H, the g-value of H being revealed to be 1.96. The dynamical properties of ZnO:H are discussed in view of conversion to hydrogen molecule by analyzing the spin-lattice relaxation time of 1H nuclear magnetic resonance (NMR) spectroscopy. We have investigated the diffusional properties of hydrogen adsorbed on ZnO surface (ZnO:H) by a H{sub 2}/Ar mixed plasma treatment installed at KOMAC. Electron spin resonance measurement identified occupied energy states of H in ZnO:H, the g-value of H being revealed to be 1.96. In further work, the proton dynamics of ZnO:H would be discussed in view of conversion to hydrogen molecule by analyzing the spin-lattice relaxation time of 1H nuclear magnetic resonance spectroscopy.

  7. Characterization of doped hydrogenated nanocrystalline silicon films prepared by plasma enhanced chemical vapour deposition

    Institute of Scientific and Technical Information of China (English)

    Wang Jin-Liang; Wu Er-Xing

    2007-01-01

    The B-and P-doped hydrogenated nanocrystalline silicon films (nc-Si:H) are prepared by plasma-enhanced chemical vapour deposition (PECVD) .The microstructures of doped nc-Si:H films are carefully and systematically char acterized by using high resolution electron microscopy (HREM) ,Raman scattering,x-ray diffraction (XRD) ,Auger electron spectroscopy (AES) ,and resonant nucleus reaction (RNR) .The results show that as the doping concentration of PH3 increases,the average grain size (d) tends to decrease and the crystalline volume percentage (Xc) increases simultaneously.For the B-doped samples,as the doping concentration of B2H6 increases,no obvious change in the value of d is observed,but the value of Xc is found to decrease.This is especially apparent in the case of heavy B2H6 doped samples,where the films change from nanocrystalline to amorphous.

  8. Dynamics of resonant magnetic field penetration and plasma rotation

    Science.gov (United States)

    Ivanov, N. V.; Kakurin, A. M.

    2017-01-01

    Results of calculations and analysis of the penetration of resonant magnetic perturbations (RMP) into tokamak plasma are presented. The TEAR code used for the calculations is based on a two-fluid magnetohydrodynamics approximation that gives coupled diffusion-type equations for the magnetic flux perturbation and for plasma rotation velocities in toroidal and poloidal directions. The radial distribution of the magnetic flux perturbation is calculated taking account of an externally applied RMP and magnetic perturbation generated by an eddy current in the resistive-vacuum vessel. The decoupling of magnetic-island velocity from the velocity of plasma rotation is employed in the calculations according to available experimental evidence and corresponding theoretical understanding. The account of this decoupling, as well as of plasma rotation in the poloidal direction in addition to the toroidal one, reduces the RMP penetration threshold and accelerates the penetration process. The main attention is paid to the dependences of the RMP penetration dynamics on the simulation conditions. The simulation findings are compared with available experimental data. Some predictions of the penetration threshold values for ITER conditions are presented.

  9. Impact of hydrogen isotope species on microinstabilities in helical plasmas

    Science.gov (United States)

    Nakata, Motoki; Nunami, Masanori; Sugama, Hideo; Watanabe, Tomo-Hiko

    2016-07-01

    The impact of isotope ion mass on ion-scale and electron-scale microinstabilities such as ion temperature gradient (ITG) mode, trapped electron mode (TEM), and electron temperature gradient (ETG) mode in helical plasmas are investigated by using gyrokinetic Vlasov simulations with a hydrogen isotope and real-mass kinetic electrons. Comprehensive scans for the equilibrium parameters and magnetic configurations clarify the transition from ITG mode to TEM instability, where a significant TEM enhancement is revealed in the case of inward-shifted plasma compared to that in the standard configuration. It is elucidated that the ion-mass dependence on the ratio of the electron-ion collision frequency to the ion transit one, i.e. {ν\\text{ei}}/{ω\\text{ti}}\\propto {{≤ft({{m}\\text{i}}/{{m}\\text{e}}\\right)}1/2} , leads to a stabilization of the TEM for heavier isotope ions. The ITG growth rate indicates a gyro-Bohm-like ion-mass dependence, where the mixing-length estimate of diffusivity yields γ /k\\bot2\\propto m\\text{i}1/2 . On the other hand, a weak isotope dependence of the ETG growth rate is identified. A collisionality scan also reveals that the TEM stabilization by the isotope ions becomes more significant for relatively higher collisionality in a banana regime.

  10. Effects of permanent magnet arrangements and antenna locations on the generation of multicusp electron cyclotron resonance plasma

    Energy Technology Data Exchange (ETDEWEB)

    Namura, T. (Kyoto Research Laboratory, Matsushita Electronics Corporation, Kyoto 601 (Japan)); Arikata, I. (Himeji Institute of Technology, Syosha, Himeji 671-22 (Japan)); Fukumasa, O. (Department of Electrical Engineering, Yamaguchi University, Ube 755 (Japan)); Kubo, M.; Itatani, R. (Department of Electronics, Kyoto University, Kyoto 606 (Japan))

    1992-01-01

    A comparative study on the generation of 2.45-GHz multicusp electron cyclotron resonance (ECR) plasma is performed. Looped cusp structures such as the ring-cusp give a low-power and low-pressure ignition, and vice versa, indicating an importance to keep the electron trajetory of gradient-{ital B} drift motion inside the chamber even in the case of ECR plasmas. The importance of the antenna location in such multicusp fields is elucidated by comparison in two cases of the axial antenna located in the weak magnetic field region, generating a hydrogen plasma of limited density ({ital n}{sub {ital e}}{lt}7.4{times}10{sup 10} cm{sup {minus}3}), and a radial antenna located in the strong magnetic field region, generating an overdense plasma ({ital n}{sub {ital e}}{similar to}2{times}10{sup 11} cm{sup {minus}3}).

  11. Correlation of H/sup -/ production and the work function of a surface in a hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Wada, M.

    1983-03-01

    Surface-plasma negative hydrogen ion sources are being developed as possible parts for future neutral beam systems. In these ion sources, negative hydrogen ions (H/sup -/) are produced at low work function metal surfaces immersed in hydrogen plasmas. To investigate the correlation between the work function and the H/sup -/ production at the surface with a condition similar to the one in the actual plasma ion source, these two parameters were simultaneously measured in the hydrogen plasma environment.

  12. Effects of Hydrogen on the Methane Coupling under Non-equilibrium Plasma

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, hydrogen is first utilized in the study on methane coupling under nonequilibrium plasma. Results indicate that the addition of hydrogen is beneficial to the methanecoupling so as to increase the conversion rate of methane and the yield of C2 hydrocarbon with agradual increase in the addition of hydrogen in a certain range of proportionality. This conclusionexplores a new route of hydrogenated methane coupling.PACS: 52.75

  13. Multicusp type Electron Cyclotron Resonance ion source for plasma processing

    Energy Technology Data Exchange (ETDEWEB)

    Amemiya, Hiroshi; Shigueoka, Yoshyuki (Institute of Physical and Chemical Research, Wako, Saitama (Japan)); Ishii, Shigeyuki

    1991-02-01

    A multi-cusp type ECR (electron cyclotron resonance) ion source is built with use of SmCo magnets and 2.45 GHz-TE{sub 11} circular mode microwave. The ion source is operated at pressures from 10{sup -4} to 10{sup -3} Torr with the input microwave power from 100 to 400 W. In hydrogen, the current density of H{sup +} is higher than those of H{sub 2}{sup +} and H{sub 3}{sup +}. The dependence of the fraction of each ion species on the power and pressure is measured and explained by rate equations. The source is operated also in other gases. Mass spectra in He, N{sub 2}, O{sub 2}, Ar and CH{sub 4} are shown together with the pressure and power dependences. Multicharged state of up to 3 has been obtained. (author).

  14. FORMATION OF CARBON NANOSTRUCTURES USING ACETYLENE, ARGON-ACETYLENE AND ARGON-HYDROGEN-ACETYLENE PLASMAS

    OpenAIRE

    Marcinauskas, Liutauras; Grigonis, Alfonsas; Valincius, Vitas

    2013-01-01

    The amorphous carbon films were deposited on silicon-metal substrates by plasma jet chemical vapor deposition (PJCVD) and plasma enchanted CVD (PECVD). PJCVD carbon films have been prepared at atmospheric pressure in argon-acetylene and argon-hydrogen-acetylene plasma mixtures. The films deposited in Ar-C2H2 plasma are attributed to graphite-like carbon films. The formation of the nanocrystalline graphite was obtained in Ar-H2-C2H2 plasma. Addition of the hydrogen gas lead to the ...

  15. Nuclear magnetic resonance J coupling constant polarizabilities of hydrogen peroxide

    DEFF Research Database (Denmark)

    Kjær, Hanna; Nielsen, Monia R.; Pagola, Gabriel I.

    2012-01-01

    approximation for the small molecule hydrogen peroxide, which allowed us to carry out calculations with the largest available basis sets optimized for the calculation of NMR coupling constants. We ¿nd a systematic but rather slow convergence with the one-electron basis set and that augmentation functions...

  16. Reduction of a thin chromium oxide film on Inconel surface upon treatment with hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Vesel, Alenka, E-mail: alenka.vesel@guest.arnes.si [Jozef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Mozetic, Miran [Jozef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Balat-Pichelin, Marianne [PROMES-CNRS Laboratory, 7 Rue du four solaire, 66120 Font Romeu Odeillo (France)

    2016-11-30

    Highlights: • Oxidized Inconel alloy was exposed to hydrogen at temperatures up to 1500 K. • Oxide reduction in hydrogen plasma started at approximately 1300 K. • AES depth profiling revealed complete reduction of oxides in plasma. • Oxides were not reduced, if the sample was heated just in hydrogen atmosphere. • Surface of reduced Inconel preserved the same composition as the bulk material. - Abstract: Inconel samples with a surface oxide film composed of solely chromium oxide with a thickness of approximately 700 nm were exposed to low-pressure hydrogen plasma at elevated temperatures to determine the suitable parameters for reduction of the oxide film. The hydrogen pressure during treatment was set to 60 Pa. Plasma was created by a surfaguide microwave discharge in a quartz glass tube to allow for a high dissociation fraction of hydrogen molecules. Auger electron depth profiling (AES) was used to determine the decay of the oxygen in the surface film and X-ray diffraction (XRD) to measure structural modifications. During hydrogen plasma treatment, the oxidized Inconel samples were heated to elevated temperatures. The reduction of the oxide film started at temperatures of approximately 1300 K (considering the emissivity of 0.85) and the oxide was reduced in about 10 s of treatment as revealed by AES. The XRD showed sharper substrate peaks after the reduction. Samples treated in hydrogen atmosphere under the same conditions have not been reduced up to approximately 1500 K indicating usefulness of plasma treatment.

  17. Resonance Effects in Mixed Hydrogen-Deuterium Crystals

    DEFF Research Database (Denmark)

    Powell, B. M.; Nielsen, Mourits

    1975-01-01

    Neutron scattering measurements of the impurity induced resonance mode caused by orthodeuterium as a substitutional impurity in solid h.c.p. parahydrogen are found to be in qualitative agreement with simple mass defect theory predictions. The samples studied contained 11-, 10-, and 6 at.% deuteri...

  18. Temperature of hydrogen radio frequency plasma under dechlorination process of polychlorinated biphenyls

    Science.gov (United States)

    Inada, Y.; Abe, K.; Kumada, A.; Hidaka, K.; Amano, K.; Itoh, K.; Oono, T.

    2014-10-01

    It has been reported that RF (radio frequency) hydrogen plasmas promote the dechlorination process of PCBs (polychlorinated biphenyls) under irradiation of MW (microwave). A relative emission intensity spectroscope system was used for single-shot imaging of two-dimensional temperature distributions of RF hydrogen plasmas generated in chemical solutions with several mixing ratios of isopropyl alcohol (IPA) and insulation oil under MW irradiation. Our experimental results showed that the plasma generation frequencies for the oil-contaminating solutions were higher than that for the pure IPA solution. In addition, the plasma temperature in the compound liquids including both oil and IPA was higher than that in the pure IPA and oil solutions. A combination of the plasma temperature measurements and plasma composition analysis indicated that the hydrogen radicals generated in a chemical solution containing the equal volumes of IPA and oil were almost the same amounts of H and H+, while those produced in the other solutions were mainly H.

  19. Hydrogen Plasma Generation with 200 MHz RF Ion Source

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jeongtae; Park, Kwangmook; Seo, Dong Hyuk; Kim, Han-Sung; Kwon, Hyeok-Jung; Cho, Yong-Sub [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2014-10-15

    The ion source for the system is required to be rugged with 2000 hours maintenance free operation time because it is installed in the vessel filled with SF6 gas at the pressure of 10 bar. A 200 MHz RF ion source is considered as an ion source. It is a simple construction and provides long life operation. The specifications of the ion source are 5 kV extraction voltage and 1 mA beam current referenced to the proton. RF ion source has been developed and undergone a performance test. Results of the test are presented. 200 MHz RF ion source is designated and manufactured. First of all test stand test of ion source are set up for a performance test of ion source. It includes a RF ion source, a 200-MHz RF system, beam extraction system, vacuum system, beam extraction system, and beam diagnostic system. At pressure of 1.2E-5 torr, hydrogen plasma is generated with net RF power 70 W. Pyrex tube surrounded by an inductive coil takes the role of vessel and discharge is enhanced with field of permanent magnets.

  20. Collisional Thermalization of Hydrogen and Helium in Solar Wind Plasma

    CERN Document Server

    Maruca, Bennett A; Sorriso-Valvo, Luca; Kasper, Justin C; Stevens, Michael L

    2013-01-01

    In situ observations of the solar wind frequently show the temperature of $\\alpha$-particles (fully ionized helium), $T_\\alpha$, to significantly differ from that of protons (ionized hydrogen), $T_p$. Many heating processes in the plasma act preferentially on $\\alpha$-particles, even as collisions among ions act to gradually establish thermal equilibrium. Measurements from the $\\textit{Wind}$ spacecraft's Faraday cups reveal that, at $r=1.0\\ \\textrm{AU}$ from the Sun, the observed values of the $\\alpha$-proton temperature ratio, $\\theta_{\\alpha p} \\equiv T_\\alpha\\,/\\,T_p$ has a complex, bimodal distribution. This study applied a simple model for the radial evolution of $\\theta_{\\alpha p}$ to these data to compute expected values of $\\theta_{\\alpha p}$ at $r=0.1\\ \\textrm{AU}$. These inferred $\\theta_{\\alpha p}$-values have no trace of the bimodality seen in the $\\theta_{\\alpha p}$-values measured at $r=1.0\\ \\textrm{AU}$ but are instead consistent with the actions of the known mechanisms for $\\alpha$-particle p...

  1. Multiphoton resonant ionization of hydrogen atom exposed to two-colour laser pulses

    Institute of Scientific and Technical Information of China (English)

    Wang Pei-Jie; Fang Yan

    2008-01-01

    This paper studies the multiphoton resonant ionization by two-colour laser pulses in the hydrogen atom by solving the time-dependent Schr(o)dinger equation.By fixing the parameters of fundamental laser field and scanning the frequency of second laser field,it finds that the ionization probability shows several resonance peaks and is also much larger than the linear superposition of probabilities by applying two lasers separately.The enhancement of the ionization happens when the system is resonantly pumped to the excited states by absorbing two or more colour photons non-sequentially.

  2. Adaptive optical design in surface plasma resonance sensor

    Institute of Scientific and Technical Information of China (English)

    ZHANG Feng; ZHONG Jin-gang

    2006-01-01

    A double-prism adaptive optical design in surface plasma resonance (SPR) sensor is proposed,which consists of two identical isosceles right-triangular prisms. One prism is used as a component of Kretschmann configuration,and the other is for regulation of the optical path. When double-prism structure is angle-scanned by an immovable incident ray,the output ray will be always parallel with the incident ray and just has a small displacement with the shift of output point.The output ray can be focused on a fixed photodetector by a convex lens.Thus it can be avoided that a prism and a photodetector rotate by θ and 2θ respectively in conventional angular scanning SPR sensor.This new design reduces the number of the movable components,makes the structure simple and compact,and makes the manipulation convenient.

  3. Characteristics of electron cyclotron resonance plasma formed by lower hybrid current drive grill antenna

    Indian Academy of Sciences (India)

    P K Sharma; S L Rao; K Mishra; R G Trivedi; D Bora

    2008-03-01

    A 3.7 GHz system, which is meant for LHCD experiments on ADITYA tokamak, is used for producing ECR discharge. The ECR discharge is produced by setting the appropriate resonance magnetic field of 0.13 T, with hydrogen at a fill pressure of about 5 × 10-5 Torr. The RF powe r, up to 10 kW (of which ∼ 50% is reflected back), with a typical pulse length of 50 ms, is injected into the vacuum chamber of the ADITYA tokamak by a LHCD grill antenna and is used for plasma formation. The average coupled RF power density (the RF power/a typical volume of the plasma) is estimated to be ∼ 5 kW/m3. When the ECR appears inside the tokamak chamber for the given pumping frequency ( = 3.7 GHz) a plasma with a density () ∼ 4 × 1016 m-3 and electron temperature ∼ 8 eV is produced. The density and temperature during the RF pulse are measured by sets of Langmuir probes, located toroidally, on either side of the antenna. signals are also monitored to detect ionization. An estimate of density and temperature based on simple theoretical calculation agrees well with our experimental measurements. The plasma produced by the above mechanism is further used to characterize the ECR-assisted low voltage Ohmic start-up discharges. During this part of the experiments, Ohmic plasma is formed using capacitor banks. The plasma loop voltage is gradually decreased, till the discharge ceases to form. The same is repeated in the presence of ECR-formed plasma (RF pre-ionization), formed 10 ms prior to the loop voltage. We have observed that (with LHCD-induced) ECR-assisted Ohmic start-up discharges is reliably and repeatedly obtained with reduced loop voltage requirement and breakdown time decreases substantially. The current ramp-up rates also decrease with reduced loop voltage operation. These studies established that ECR plasma formed with LHCD system exhibits similar characteristics as reported earlier by dedicated ECR systems. This experiment also addresses the issue of whether ECR plasma

  4. Resonant Scattering of Muonic Hydrogen Atoms and Dynamics of Muonic Molecular Complex

    CERN Document Server

    Fujiwara, M C; Bailey, J M; Beer, G A; Beveridge, J L; Faifman, M P; Huber, T M; Kammel, P; Kim, S K; Knowles, P E; Kunselman, A R; Maier, M; Markushin, V E; Marshall, G M; Martoff, C J; Mason, G R; Mulhauser, F; Olin, A; Petitjean, C; Porcelli, T A; Wozniak, J; Zmeskal, J

    2001-01-01

    Resonant scattering of muonic hydrogen atoms via back decay of molecular complex, a key process in the understanding of epithermal muonic molecular formation, is analyzed. The limitations of the effective rate approximation are discussed and the importance of the explicit treatment of the back decay is stressed. An expression of the energy distribution for the back-decayed atoms is given.

  5. Most Typical 12 Resonant Perturbation of the Hydrogen Atom by Weak Electric and Magnetic Fields

    NARCIS (Netherlands)

    Efstathiou, K.; Lukina, O. V.; Sadovskii, D. A.

    2008-01-01

    We study a perturbation of the hydrogen atom by small homogeneous static electric and magnetic fields in a specific mutual alignment with angle approximately pi/3 which results in the 12 resonance of the linearized Keplerian n-shell approximation. The bifurcation diagram of the classical integrable

  6. Sound waves and resonances in electron-hole plasma

    Science.gov (United States)

    Lucas, Andrew

    2016-06-01

    Inspired by the recent experimental signatures of relativistic hydrodynamics in graphene, we investigate theoretically the behavior of hydrodynamic sound modes in such quasirelativistic fluids near charge neutrality, within linear response. Locally driving an electron fluid at a resonant frequency to such a sound mode can lead to large increases in the electrical response at the edges of the sample, a signature, which cannot be explained using diffusive models of transport. We discuss the robustness of this signal to various effects, including electron-acoustic phonon coupling, disorder, and long-range Coulomb interactions. These long-range interactions convert the sound mode into a collective plasmonic mode at low frequencies unless the fluid is charge neutral. At the smallest frequencies, the response in a disordered fluid is quantitatively what is predicted by a "momentum relaxation time" approximation. However, this approximation fails at higher frequencies (which can be parametrically small), where the classical localization of sound waves cannot be neglected. Experimental observation of such resonances is a clear signature of relativistic hydrodynamics, and provides an upper bound on the viscosity of the electron-hole plasma.

  7. Fano resonances in photoconductivity spectra of hydrogen donors in ZnO and rutile

    Science.gov (United States)

    Lavrov, E. V.; Herklotz, F.; Weber, J.

    2015-02-01

    The results of photoconductivity studies of hydrogen donors in ZnO and rutile TiO2 are presented. It is shown that local vibrational modes of O-H bonds comprising donors in both semiconductors can be detected in photoconductivity spectra as Fano resonances at 3611 and 3290 cm-1 in the case of ZnO and TiO2, respectively. The frequencies of these features red-shift in energy down to 2668 (ZnO) and 2445 cm-1 (TiO2) if hydrogen is substituted by deuterium. Based on the frequency of the deuterium resonance it is concluded that the ionization energy of the hydrogen donor in TiO2 is less than 300 meV, which is in variance with predictions of theory. The reasons for such a discrepancy are discussed.

  8. Spectro-Polarimetric Observations of Interplanetary Hydrogen as a Diagnostic of the Heliopause Plasma Boundary

    Science.gov (United States)

    Harris, W.; Ben-Jaffel, L.; Roesler, F.; Corliss, J.; Dawson, O.; Giersch, L.

    2006-12-01

    Neutral interplanetary hydrogen (IPH) does not originate in the solar system, but is dominated by material in the interstellar medium (ISM) that has penetrated into the solar system. This material is not pristine or thermal in its properties, but contains a record of both the ISM and its passage across the broad mixing- plasma boundary formed by the interaction of the Solar wind and the ionized component of the ISM. This record is provided by charge exchange interactions between hydrogen atoms and protons in the boundary region that effectively translate the characteristics of the plasma interaction and boundary region to the non- interacting neutral population. The primary observational technique used to observe IPH is resonance scattering of solar Ly-alpha emission in the optically thick medium. These data show evidence of line of sight dependent line-broadening and deceleration associated with the boundary crossing. Here we describe a new class of instrument, a spatial-heterodyne spectro-polarimeter (SHSPOL) that offers improved diagnostic capabilities for the study of the IPH. SHSPOL combines the high sensitivity and spectral resolving power of SHS with a novel far ultraviolet polarimeter design. Combined, these technologies permit rapid accumulation of IPH line-shape measurements with the added measurement of the offers a new way to explore the radial properties of the IPH along a given line of sight from the scattering angle dependent polarization of the incoming light. We will discuss the principle of SHSPOL and our development of prototype instrument for observing the IPH from a sounding rocket platform.

  9. Emission of fast non-Maxwellian hydrogen atoms in low-density laboratory plasma

    Science.gov (United States)

    Brandt, Christian; Marchuk, Oleksandr; Pospieszczyk, Albrecht; Dickheuer, Sven

    2017-03-01

    The source of strong and broad emission of the Balmer-α line in mixed plasmas of hydrogen (or deuterium) and noble gases in front of metallic surfaces is a subject of controversial discussion of many plasma types. In this work the excitation source of the Balmer lines is investigated by means of optical emission spectroscopy in the plasma device PSI-2. Neutral fast non-Maxwellian hydrogen atoms are produced by acceleration of hydrogen ions towards an electrode immersed into the plasma. By variation of the electrode potential the energy of ions and in turn of reflected fast atoms can be varied in the range of 40-300 eV. The fast atoms in front of the electrode are observed simultaneously by an Echelle spectrometer (0.001 nm/channel) and by an imaging spectrometer (0.01 nm/channel) up to few cm in the plasma. Intense excitation channels of the Balmer lines are observed when hydrogen is mixed with argon or with krypton. Especially in Ar-H and Ar-D mixed plasmas the emission of fast hydrogen atoms is very strong. Intermixing hydrogen with other noble gases (He, Ne or Xe) one observes the same effect however the emission is one order of magnitude less compared to Kr-H or Kr-D plasmas. It is shown, that the key process, impacting this emission, is the binary collision between the fast neutral hydrogen atom and the noble gas atom. Two possible sources of excitation are discussed in details: one is the excitation of hydrogen atoms by argon atoms in the ground state and the second one is the process of the so-called excitation transfer between the metastable states of noble gases and hydrogen. In the latter case the atomic data for excitation of Balmer lines are still not available in literature. Further experimental investigations are required to conclude on the source process of fast atom emission.

  10. In situ study of hydrogen diffusion in a-Si:H based junctions exposed to hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Larbi, Fadila; Hadjadj, Aomar [Groupe de Recherche en Sciences pour l' Ingenieur (GRESPI), Universite de Reims (France); Fellah, Samira; Roca i Cabarrocas, Pere [Laboratoire de Physique des Interfaces et Couches Minces (LPICM), Ecole Polytechnique, Palaiseau (France); Dine Sib, Jamal [Laboratoire de Physique des Couches Minces et Materiaux pour l' Electronique (LPCM2E), Universite d' Oran (Algeria)

    2012-06-15

    Just after their deposition by plasma enhanced chemical vapor deposition (PECVD) process, we have exposed Cr/I/N, Cr/I/P, Cr/N/I and Cr/P/I a-Si:H based junctions to H{sub 2} plasma and followed in situ, by ellipsometry, the modifications induced by hydrogen diffusion. In the case of Cr/N/I and Cr/P/I junctions, no significant effects of the junction on the hydrogen diffusion were observed since the time-evolution of the thickness of the H-modified layer is similar to that of a single intrinsic layer. However, Cr/I/N, Cr/I/P structures present an attenuated thickness of the H-modified layer in the first few minutes of hydrogen plasma exposure. This effect should be attributed to the charges in the field regions of I/N or I/P junctions which increase the hydrogen trap concentration and restrain the hydrogen diffusion. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  11. Thermodynamical study on production of acetylene from coal pyrolysis in hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Wang, F.; Guo, W.K.; Yuan, X.Q.; Zhao, T.Z. [Fudan University, Shanghai (China). Inst. for Modern Physics

    2006-05-15

    The chemical thermodynamic equilibrium of acetylene production by coal pyrolysis in hydrogen plasma was studied. The thermodynamic equilibrium is obtained by using the method of free energy. Calculated results show that the hydrogen concentration in the equilibrium system is very important for the acetylene production by coal conversion and the energy consumption for the production of acetylene per-kilogram strongly depends on the hydrogen concentration and the temperature.

  12. Thermodynamical Study on Production of Acetylene from Coal Pyrolysis in Hydrogen Plasma

    Science.gov (United States)

    Wang, Fei; Guo, Wenkang; Yuan, Xingqiu; Zhao, Taize

    2006-05-01

    The chemical thermodynamic equilibrium of acetylene production by coal pyrolysis in hydrogen plasma was studied. The thermodynamic equilibrium is obtained by using the method of free energy. Calculated results show that the hydrogen concentration in the equilibrium system is very important for the acetylene production by coal conversion and the energy consumption for the production of acetylene per-kilogram strongly depends on the hydrogen concentration and the temperature.

  13. A road to hydrogenating graphene by a reactive ion etching plasma

    NARCIS (Netherlands)

    Wojtaszek, M.; Tombros, N.; Caretta, A.; van Loosdrecht, P. H. M.; van Wees, B. J.

    2011-01-01

    We report the hydrogenation of single and bilayer graphene by an argon-hydrogen plasma produced in a reactive ion etching (RIE) system. Electronic transport measurements in combination with Raman spectroscopy are used to link the electric mean free path to the optically extracted defect

  14. Particle-in-cell investigation on the resonant absorption of a plasma surface wave

    Institute of Scientific and Technical Information of China (English)

    Lan Chao-Hui; Hu Xi-Wei

    2011-01-01

    The resonant absorption of a plasma surface wave is supposed to be an important and efficient mechanism of power deposition for a surface wave plasma source.In this paper,by using the particle-in-cell method and Monte Carlo simulation,the resonance absorption mechanism is investigated.Simulation results demonstrate the existence of surface wave resonance and show the high efficiency of heating electrons.The positions of resonant points,the resonance width and the spatio-temporal evolution of the resonant electric field are presented,which accord well with the theoretical results.The paper also discusses the effect of pressure on the resonance electric field and the plasma density.

  15. Uniform Atomic Layer Deposition of Al2O3 on Graphene by Reversible Hydrogen Plasma Functionalization

    Science.gov (United States)

    2017-01-01

    A novel method to form ultrathin, uniform Al2O3 layers on graphene using reversible hydrogen plasma functionalization followed by atomic layer deposition (ALD) is presented. ALD on pristine graphene is known to be a challenge due to the absence of dangling bonds, leading to nonuniform film coverage. We show that hydrogen plasma functionalization of graphene leads to uniform ALD of closed Al2O3 films down to 8 nm in thickness. Hall measurements and Raman spectroscopy reveal that the hydrogen plasma functionalization is reversible upon Al2O3 ALD and subsequent annealing at 400 °C and in this way does not deteriorate the graphene’s charge carrier mobility. This is in contrast with oxygen plasma functionalization, which can lead to a uniform 5 nm thick closed film, but which is not reversible and leads to a reduction of the charge carrier mobility. Density functional theory (DFT) calculations attribute the uniform growth on both H2 and O2 plasma functionalized graphene to the enhanced adsorption of trimethylaluminum (TMA) on these surfaces. A DFT analysis of the possible reaction pathways for TMA precursor adsorption on hydrogenated graphene predicts a binding mechanism that cleans off the hydrogen functionalities from the surface, which explains the observed reversibility of the hydrogen plasma functionalization upon Al2O3 ALD.

  16. VUV diagnostic of electron impact processes in low temperature molecular hydrogen plasma

    CERN Document Server

    Komppula, J

    2015-01-01

    Novel methods for diagnostics of molecular hydrogen plasma processes, such as ionization, production of high vibrational levels, dissociation of molecules via excitation to singlet and triplet states and production of metastable states, are presented for molecular hydrogen plasmas in corona equilibrium. The methods are based on comparison of rate coefficients of plasma processes and optical emission spectroscopy of lowest singlet and triplet transitions, i.e. Lyman-band ($B^1\\Sigma^+_u \\rightarrow X^1\\Sigma^+_g$) and molecular continuum ($a^3\\Sigma^+_g \\rightarrow b^3\\Sigma^+_u$), of the hydrogen molecule in VUV wavelength range. Comparison of rate coefficients of spin-allowed and/or spin-forbidden excitations reduces the uncertainty caused by the non-equilibrium distributions of electron energy and molecular vibrational level, which are typically known poorly in plasma sources. The described methods are applied to estimate the rates of various plasma processes in a filament arc discharge.

  17. Optimum plasma grid bias for a negative hydrogen ion source operation with Cs

    Energy Technology Data Exchange (ETDEWEB)

    Bacal, Marthe, E-mail: marthe.bacal@lpp.polytechnique.fr [UPMC, LPP, Ecole Polytechnique, UMR CNRS 7648, Palaiseau (France); Sasao, Mamiko [R& D Promotion Organization, Doshisha University, Kamigyoku, Kyoto 602-8580 (Japan); Wada, Motoi [School of Science and Engineering, Doshisha University, Kyotonabe, Kyoto 610-0321 (Japan); McAdams, Roy [CCFE, Culham Science Center, Abingdon, Oxfordshire 0X14 3DB (United Kingdom)

    2016-02-15

    The functions of a biased plasma grid of a negative hydrogen (H{sup −}) ion source for both pure volume and Cs seeded operations are reexamined. Proper control of the plasma grid bias in pure volume sources yields: enhancement of the extracted negative ion current, reduction of the co-extracted electron current, flattening of the spatial distribution of plasma potential across the filter magnetic field, change in recycling from hydrogen atomic/molecular ions to atomic/molecular neutrals, and enhanced concentration of H{sup −} ions near the plasma grid. These functions are maintained in the sources seeded with Cs with additional direct emission of negative ions under positive ion and neutral hydrogen bombardment onto the plasma electrode.

  18. Measurement of Ar resonance and metastable level number densities in argon containing plasmas

    Science.gov (United States)

    Fiebrandt, Marcel; Hillebrand, Bastian; Spiekermeier, Stefan; Bibinov, Nikita; Böke, Marc; Awakowicz, Peter

    2017-09-01

    The resonance 1s_4~({\\hspace{0pt}}^3P_1), ~1s_2~({\\hspace{0pt}}^1P_1) and metastable 1s_5~({\\hspace{0pt}}^3P_2), ~1s_3~({\\hspace{0pt}}^3P_0) level number densities of argon are determined by means of the branching fraction method in an inductively coupled plasma at 5 Pa and 10 Pa in argon with admixture of hydrogen, nitrogen and oxygen. The 1s_5~({\\hspace{0pt}}^3P_2) densities are compared to laser absorption spectroscopy measurements to evaluate the reliability of the branching fraction method and its limitations. The results are in good agreement and the use of a compact, low cost, low resolution spectrometer (Δλ = 1.3 nm) is sufficient to reliably determine the first four excited states of argon in argon-hydrogen and argon-oxygen mixtures. The addition of nitrogen results in unreliable densities, as the observed argon lines overlap with emission of the N_2(B^3\\Pi_g-A^3Σ_u^+) transition.

  19. Features of electromagnetic waves in a complex plasma due to surface plasmon resonances on macroparticles

    CERN Document Server

    Vladimirov, S V

    2015-01-01

    The dielectric properties of complex plasma containing either metal or dielectric spherical inclusions (macroparticles, dust) are investigated. We focus on surface plasmon resonances on the macroparticle surfaces and their effect on electromagnetic wave propagation. It is demonstrated that the presence of surface plasmon oscillations significantly modifies plasma electromagnetic properties by resonances and cutoffs in the effective permittivity. This leads to related branches of electromagnetic waves and to the wave band gaps. The results are discussed in the context of dusty plasma experiments.

  20. Plasma test on industrial diamond powder in hydrogen and air for fracture strength study

    Science.gov (United States)

    Chary, Rohit Asuri Sudharshana

    Diamonds are the most precious material all over the world. Ever since their discovery, the desire for natural diamonds has been great; recently, the demand has steeply increased, leading to scarcity. For example, in 2010, diamonds worth $50 billion were marketed. This increased demand has led to discovering alternative sources to replace diamonds. The diamond, being the hardest material on earth, could be replaced with no other material except another diamond. Thus, the industrial or synthetic diamond was invented. Because of extreme hardness is one of diamond's properties, diamonds are used in cutting operations. The fracture strength of diamond is one of the crucial factors that determine its life time as a cutting tool. Glow discharge is one of the techniques used for plasma formation. The glow discharge process is conducted in a vacuum chamber by ionizing gas atoms. Ions penetrate into the atomic structure, ejecting a secondary electron. The objective of this study is to determine the change in fracture strength of industrial diamond powder before and after plasma treatment. This study focuses mainly on the change in crystal defects and crushing strength (CS) of industrial diamond powder after the penetration of hydrogen gas, air and hydrogen-air mixture ions into the sample powder. For this study, an industrial diamond powder sample of 100 carats weight, along with its average fracture strength value was received from Engis Corporation, Illinois. The sample was divided into parts, each weighing 10-12 carats. At the University of Nevada, Las Vegas (UNLV), a plasma test was conducted on six sample parts for a total of 16 hours on each part. The three gas types mentioned above were used during plasma tests, with the pressure in vacuum chamber between 200 mTorr and 2 Torr. The plasma test on four sample parts was in the presence of hydrogen-air mixture. The first sample had chamber pressures between 200 mTorr and 400 mTorr. The remaining three samples had chamber

  1. Evidences for Cooperative Resonance-Assisted Hydrogen Bonds in Protein Secondary Structure Analogs

    Science.gov (United States)

    Zhou, Yu; Deng, Geng; Zheng, Yan-Zhen; Xu, Jing; Ashraf, Hamad; Yu, Zhi-Wu

    2016-11-01

    Cooperative behaviors of the hydrogen bonding networks in proteins have been discovered for a long time. The structural origin of this cooperativity, however, is still under debate. Here we report a new investigation combining excess infrared spectroscopy and density functional theory calculation on peptide analogs, represented by N-methylformamide (NMF) and N-methylacetamide (NMA). Interestingly, addition of the strong hydrogen bond acceptor, dimethyl sulfoxide, to the pure analogs caused opposite effects, namely red- and blue-shift of the N-H stretching infrared absorption in NMF and NMA, respectively. The contradiction can be reconciled by the marked lowering of the energy levels of the self-associates between NMA molecules due to a cooperative effect of the hydrogen bonds. On the contrary, NMF molecules cannot form long-chain cooperative hydrogen bonds because they tend to form dimers. Even more interestingly, we found excellent linear relationships between changes on bond orders of N-H/N-C/C = O and the hydrogen bond energy gains upon the formation of hydrogen bonding multimers in NMA, suggesting strongly that the cooperativity originates from resonance-assisted hydrogen bonds. Our findings provide insights on the structures of proteins and may also shed lights on the rational design of novel molecular recognition systems.

  2. Hard graphitelike hydrogenated amorphous carbon grown at high rates by a remote plasma

    DEFF Research Database (Denmark)

    Singh, Shailendra Vikram; Zaharia, T.; Creatore, M.

    2010-01-01

    Hydrogenated amorphous carbon (a-C:H) deposited from an Ar-C 2H2 expanding thermal plasma chemical vapor deposition (ETP-CVD) is reported. The downstream plasma region of an ETP is characterized by a low electron temperature (∼0.3 eV), which leads to an ion driven chemistry and negligible physical...

  3. Reorganization of graphite surfaces into carbon micro- and nanoparticles under high flux hydrogen plasma bombardment

    NARCIS (Netherlands)

    Bystrov, K.; van der Vegt, L.; De Temmerman, G.; Arnas, C.; Marot, L.

    2013-01-01

    Fine-grain graphite samples were exposed to high density low temperature (n(e) similar to 10(20)m(-3), T-e similar to 1 eV) hydrogen plasmas in the Pilot-PSI linear plasma generator. Redeposition of eroded carbon is so strong that no external precursor gas injection is necessary for deposits to form

  4. Ultrafast optical control using the Kerr nonlinearity in hydrogenated amorphous silicon microcylindrical resonators

    Science.gov (United States)

    Vukovic, N.; Healy, N.; Suhailin, F. H.; Mehta, P.; Day, T. D.; Badding, J. V.; Peacock, A. C.

    2013-10-01

    Microresonators are ideal systems for probing nonlinear phenomena at low thresholds due to their small mode volumes and high quality (Q) factors. As such, they have found use both for fundamental studies of light-matter interactions as well as for applications in areas ranging from telecommunications to medicine. In particular, semiconductor-based resonators with large Kerr nonlinearities have great potential for high speed, low power all-optical processing. Here we present experiments to characterize the size of the Kerr induced resonance wavelength shifting in a hydrogenated amorphous silicon resonator and demonstrate its potential for ultrafast all-optical modulation and switching. Large wavelength shifts are observed for low pump powers due to the high nonlinearity of the amorphous silicon material and the strong mode confinement in the microcylindrical resonator. The threshold energy for switching is less than a picojoule, representing a significant step towards advantageous low power silicon-based photonic technologies.

  5. Resonance states in the hydrogen-antihydrogen system from a nonadiabatic treatment

    Science.gov (United States)

    Stegeby, Henrik; Piszczatowski, Konrad

    2016-01-01

    The quantum-mechanical four-body problem for the hydrogen-antihydrogen system has been solved by means of the variational implementation of the coupled-arrangement channel method. Wave functions have been formed using the Gaussian expansion method (GEM) in Jacobi coordinates; they explicitly include components corresponding to the rearrangement from hydrogen and antihydrogen (H + \\bar{{{H}}}) into protonium and positronium (Pn + Ps). We analyze the solutions belonging to the discretized spectrum of the four-body eigenvalue problem, searching for resonance states at energies just below the H-\\bar{{{H}}} dissociation energy threshold by means of the stabilization method and complex scaling.

  6. Resonant Alfven waves in partially ionized plasmas of the solar atmosphere

    CERN Document Server

    Soler, R; Goossens, M

    2011-01-01

    Context. Magnetohydrodynamic (MHD) waves are ubiquitous in the solar atmosphere. In magnetic waveguides resonant absorption due to plasma inhomogeneity naturally transfers wave energy from large-scale motions to small-scale motions. In the cooler parts of the solar atmosphere as, e.g., the chromosphere, effects due to partial ionization may be relevant for wave dynamics and heating. Aims. We study resonant Alfven waves in partially ionized plasmas. Methods. We use the multifluid equations in the cold plasma approximation. We investigate propagating resonant MHD waves in partially ionized flux tubes. We use approximate analytical theory based on normal modes in the thin tube and thin boundary approximations along with numerical eigenvalue computations. Results. We find that the jumps of the wave perturbations across the resonant layer are the same as in fully ionized plasmas. The damping length due to resonant absorption is inversely proportional to the frequency, while that due to ion-neutral collisions is in...

  7. Improvement of silicon direct bonding using surfaces activated by hydrogen plasma treatment

    CERN Document Server

    Choi, W B; Lee Jae Sik; Sung, M Y

    2000-01-01

    The plasma surface treatment, using hydrogen gas, of silicon wafers was studied as a pretreatment for silicon direct bonding. Chemical reactions of the hydrogen plasma with the surfaces were used for both surface activation and removal of surface contaminants. Exposure of the silicon wafers to the plasma formed an active oxide layer on the surface. This layer was hydrophilic. The surface roughness and morphology were examined as functions of the plasma exposure time and power. The surface became smoother with shorter plasma exposure time and lower power. In addition, the plasma surface treatment was very efficient in removing the carbon contaminants on the silicon surface. The value of the initial surface energy, as estimated by using the crack propagation method, was 506 mJ/M sup 2 , which was up to about three times higher than the value for the conventional direct bonding method using wet chemical treatments.

  8. Energy density dependence of hydrogen combustion efficiency in atmospheric pressure microwave plasma

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, T.; Ezumi, N. [Nagano National College of Technology, Nagano-city, Nagano (Japan); Sawada, K. [Shinshu University, Nagano-city, Nagano (Japan); Tanaka, Y. [Kanazawa University, Kakuma-cho, Kanzawa-city, Ishikawa (Japan); Tanaka, M.; Nishimura, K. [National Insitute for Fusion Science, Toki-city, Gifu (Japan)

    2015-03-15

    The recovery of tritium in nuclear fusion plants is a key issue for safety. So far, the oxidation procedure using an atmospheric pressure plasma is expected to be part of the recovery method. In this study, in order to clarify the mechanism of hydrogen oxidation by plasma chemistry, we have investigated the dependence of hydrogen combustion efficiency on gas flow rate and input power in the atmospheric pressure microwave plasma. It has been found that the combustion efficiency depends on energy density of absorbed microwave power. Hence, the energy density is considered as a key parameter for combustion processes. Also neutral gas temperatures inside and outside the plasma were measured by an optical emission spectroscopy method and thermocouple. The result shows that the neutral gas temperature in the plasma is much higher than the outside temperature of plasma. The high neutral gas temperature may affect the combustion reaction. (authors)

  9. Enhanced conductivity of aluminum doped ZnO films by hydrogen plasma treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chang, H.P. [Department of Electrical Engineering and Graduate Institute of Optoelectronic Engineering, National Chung Hsing University, Taichung 402, Taiwan (China); Wang, F.H., E-mail: fansen@dragon.nchu.edu.t [Department of Electrical Engineering and Graduate Institute of Optoelectronic Engineering, National Chung Hsing University, Taichung 402, Taiwan (China); Wu, J.Y.; Kung, C.Y.; Liu, H.W. [Department of Electrical Engineering and Graduate Institute of Optoelectronic Engineering, National Chung Hsing University, Taichung 402, Taiwan (China)

    2010-10-01

    Aluminum doped zinc oxide (AZO) thin films prepared by radio-frequency (RF) magnetron sputtering at various RF power were treated by hydrogen plasma to enhance the characteristics for transparent electrode applications. The hydrogen plasma treatment was carried out at 300 {sup o}C in a plasma enhanced chemical vapor deposition system. X-ray diffraction analysis shows that all AZO films have a (002) preferred orientation and film crystallinity seems no significant change after plasma treatment. The plasma treatment not only significantly decreases film resistivity but enhances electrical stability as aging in air ambient. The improved electrical properties are due to desorption of weakly bonded oxygen species, formation of Zn-H type species and passivation of deep-level defects during plasma treatment.

  10. Investigation of bonded hydrogen defects in nanocrystalline diamond films grown with nitrogen/methane/hydrogen plasma at high power conditions

    Science.gov (United States)

    Tang, C. J.; Hou, Haihong; Fernandes, A. J. S.; Jiang, X. F.; Pinto, J. L.; Ye, H.

    2017-02-01

    In this work, we investigate the influence of some growth parameters such as high microwave power ranging from 3.0 to 4.0 kW and N2 additive on the incorporation of bonded hydrogen defects in nanocrystalline diamond (NCD) films grown through a small amount of pure N2 addition into conventional 4% CH4/H2 plasma using a 5 kW microwave plasma CVD system. Incorporation form and content of hydrogen point defects in the NCD films produced with pure N2 addition was analyzed by employing Fourier-transform infrared (FTIR) spectroscopy for the first time. A large amount of hydrogen related defects was detected in all the produced NCD films with N2 additive ranging from 29 to 87 μm thick with grain size from 47 nm to 31 nm. Furthermore, a specific new H related sharp absorption peak appears in all the NCD films grown with pure N2/CH4/H2 plasma at high powers and becomes stronger at powers higher than 3.0 kW and is even stronger than the 2920 cm-1 peak, which is commonly found in CVD diamond films. Based on these experimental findings, the role of high power and pure nitrogen addition on the growth of NCD films including hydrogen defect formation is analyzed and discussed.

  11. The Diagnostics Of Hydrogen-Cesium Plasma Using Fully Relativistic Electron Impact Cross Sections

    Science.gov (United States)

    Priti, Priti; Dipti, Dipti; Gangwar, Reetesh; Srivastava, Rajesh

    2016-10-01

    Electron excitation cross-sections and rate coefficients have been calculated using fully relativistic distorted wave theory for several fine-structure transitions from the ground as well as excited states of cesium atom in the wide range of incident electron energy. These processes play dominant role in low pressure hydrogen-cesium plasma relevant to the negative ion based neutral beam injectors for the ITER project. The calculated cross-sections are used to construct a reliable collisional radiative (CR) model to characterize the hydrogen-cesium plasma. The calculated plasma parameters are compared with the available experimental and theoretical results.

  12. Influence of high flux hydrogen-plasma exposure on the thermal shock induced crack formation in tungsten

    NARCIS (Netherlands)

    Wirtz, M.; Linke, J.; Pintsuk, G.; Rapp, J.; Wright, G. M.

    2012-01-01

    The influence of high flux hydrogen-plasma on the thermal shock behaviour of tungsten was investigated in a combined experiment using the linear plasma device Pilot-PSI and the electron beam facility JUDITH 1. Tungsten targets were exposed to high flux hydrogen plasma, cyclic thermal shock tests and

  13. Towards higher stability of resonant absorption measurements in pulsed plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Britun, Nikolay, E-mail: nikolay.britun@umons.ac.be [Chimie des Interactions Plasma Surface (ChIPS), CIRMAP, Université de Mons, 23 Place du Parc, B-7000 Mons (Belgium); Michiels, Matthieu [Materia Nova Research Center, Parc Initialis, B-7000 Mons (Belgium); Snyders, Rony [Chimie des Interactions Plasma Surface (ChIPS), CIRMAP, Université de Mons, 23 Place du Parc, B-7000 Mons (Belgium); Materia Nova Research Center, Parc Initialis, B-7000 Mons (Belgium)

    2015-12-15

    Possible ways to increase the reliability of time-resolved particle density measurements in pulsed gaseous discharges using resonant absorption spectroscopy are proposed. A special synchronization, called “dynamic source triggering,” between a gated detector and two pulsed discharges, one representing the discharge of interest and another being used as a reference source, is developed. An internal digital delay generator in the intensified charge coupled device camera, used at the same time as a detector, is utilized for this purpose. According to the proposed scheme, the light pulses from the reference source follow the gates of detector, passing through the discharge of interest only when necessary. This allows for the utilization of short-pulse plasmas as reference sources, which is critical for time-resolved absorption analysis of strongly emitting pulsed discharges. In addition to dynamic source triggering, the reliability of absorption measurements can be further increased using simultaneous detection of spectra relevant for absorption method, which is also demonstrated in this work. The proposed methods are illustrated by the time-resolved measurements of the metal atom density in a high-power impulse magnetron sputtering (HiPIMS) discharge, using either a hollow cathode lamp or another HiPIMS discharge as a pulsed reference source.

  14. Mass number identification by Alfvén wave diagnostics in hydrogen and helium plasmas in TCABR

    Energy Technology Data Exchange (ETDEWEB)

    Puglia, P.G.P.; Elfimov, A.G., E-mail: elfimov@if.usp.br; Andriati, A.V.; Galvão, R.M.O.; Guimarães-Filho, Z.O.; Ronchi, G.; Ruchko, L.F.

    2016-03-11

    The mass number is obtained through the identification of the Global Alfvén (GA) wave resonances in ohmic plasma discharges in the TCABR tokamak. By comparing hydrogen and helium discharges, the composition of carbon, oxygen, and iron impurities is determined. The non-perturbative Alfvén diagnostic is used that is based on the excitation of GA waves by an external antenna fed by a low power generator, in the frequency band swept just below the minimum of the Alfvén wave continuum. Odd or even toroidal modes are excited by selecting the current phase in the two antenna modules separated by 180 degrees in the toroidal direction. The density profile, determined from cross analysis of reflectometer and interferometer data, shows impurity accumulation in the plasma core. - Highlights: • A non-perturbative Alfvén diagnostic is used to find the mass number in ohmic discharges in TCABR tokamak. • Global Alfvén waves are excited by an external antenna fed by a low power generator at the minimum of the Alfvén continuum. • Comparing hydrogen and helium discharges, the composition of carbon, oxygen and iron impurities is determined. • The density profile defined reflectometer and interferometer data shows impurity accumulation in the plasma core.

  15. Surface plasmon resonance hydrogen sensor based on metallic grating with high sensitivity.

    Science.gov (United States)

    Lin, Kaiqun; Lu, Yonghua; Chen, Junxue; Zheng, Rongsheng; Wang, Pei; Ming, Hai

    2008-11-10

    High sensitivity is obtained at larger resonant incident angle if negative diffraction order of metallic grating is used to excite the surface plasmon. A highly sensitive grating-based surface plasmon resonance (SPR) sensor is designed for the hydrogen detection. A thin palladium (Pd) film deposited on the grating surface is used as transducer. The influences of grating period and the thickness of Pd on the performance of sensor are investigated using rigorous coupled-wave analysis (RCWA) method. The sensitivity as well as the width of the SPR curves and reflective amplitude is considered simultaneously for designing the grating-based SPR hydrogen sensor, and a set of optimized structural parameters is presented. The performance of grating-based SPR sensor is also compared with that of conventional prism-based SPR sensor.

  16. Plasma density characterization at SPARC-LAB through Stark broadening of Hydrogen spectral lines

    Energy Technology Data Exchange (ETDEWEB)

    Filippi, F., E-mail: francesco.filippi@roma1.infn.it [Dipartimento di Scienze di Base e Applicate per l' Ingegneria (SBAI), ‘Sapienza’ Università di Roma, Via A. Scarpa 14-16, 00161 Roma (Italy); INFN-Roma1, Piazzale Aldo Moro, 2 00161 Roma (Italy); Anania, M.P.; Bellaveglia, M.; Biagioni, A.; Chiadroni, E. [Laboratori Nazionali di Frascati, INFN, Via E. Fermi, Frascati (Italy); Cianchi, A. [Dipartimento di Fisica, Universitá di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Roma (Italy); Di Giovenale, D.; Di Pirro, G.; Ferrario, M. [Laboratori Nazionali di Frascati, INFN, Via E. Fermi, Frascati (Italy); Mostacci, A.; Palumbo, L. [Dipartimento di Scienze di Base e Applicate per l' Ingegneria (SBAI), ‘Sapienza’ Università di Roma, Via A. Scarpa 14-16, 00161 Roma (Italy); INFN-Roma1, Piazzale Aldo Moro, 2 00161 Roma (Italy); Pompili, R.; Shpakov, V.; Vaccarezza, C.; Villa, F. [Laboratori Nazionali di Frascati, INFN, Via E. Fermi, Frascati (Italy); Zigler, A. [Hebrew University of Jerusalem, Jerusalem 91904 (Israel)

    2016-09-01

    Plasma-based acceleration techniques are of great interest for future, compact accelerators due to their high accelerating gradient. Both particle-driven and laser-driven Plasma Wakefield Acceleration experiments are foreseen at the SPARC-LAB Test Facility (INFN National Laboratories of Frascati, Italy), with the aim to accelerate high-brightness electron beams. In order to optimize the efficiency of the acceleration in the plasma and preserve the quality of the accelerated beam, the knowledge of the plasma electron density is mandatory. The Stark broadening of the Hydrogen spectral lines is one of the candidates used to characterize plasma density. The implementation of this diagnostic for plasma-based experiments at SPARC-LAB is presented. - Highlights: • Stark broadening of Hydrogen lines has been measured to determine plasma density. • Plasma density diagnostic tool for plasma-based experiments at SPARC-LAB is presented. • Plasma density in tapered laser triggered ablative capillary discharge was measured. • Results of plasma density measurements in ablative capillaries are shown.

  17. Active Plasma Resonance Spectroscopy: Evaluation of a fluiddynamic-model of the planar multipole resonance probe using functional analytic methods

    Science.gov (United States)

    Friedrichs, Michael; Brinkmann, Ralf Peter; Oberrath, Jens

    2016-09-01

    Measuring plasma parameters, e.g. electron density and electron temperature, is an important procedure to verify the stability and behavior of a plasma process. For this purpose the multipole resonance probe (MRP) represents a satisfying solution to measure the electron density. However the influence of the probe on the plasma through its physical presence makes it unattractive for some processes in industrial application. A solution to combine the benefits of the spherical MRP with the ability to integrate the probe into the plasma reactor is introduced by the planar model of the MRP. By coupling the model of the cold plasma with the maxwell equations for electrostatics an analytical model for the admittance of the plasma is derivated, adjusted to cylindrical geometry and solved analytically for the planar MRP using functional analytic methods.

  18. Pure hydrogen low-temperature plasma exposure of HOPG and graphene: Graphane formation?

    Directory of Open Access Journals (Sweden)

    Baran Eren

    2012-12-01

    Full Text Available Single- and multilayer graphene and highly ordered pyrolytic graphite (HOPG were exposed to a pure hydrogen low-temperature plasma (LTP. Characterizations include various experimental techniques such as photoelectron spectroscopy, Raman spectroscopy and scanning probe microscopy. Our photoemission measurement shows that hydrogen LTP exposed HOPG has a diamond-like valence-band structure, which suggests double-sided hydrogenation. With the scanning tunneling microscopy technique, various atomic-scale charge-density patterns were observed, which may be associated with different C–H conformers. Hydrogen-LTP-exposed graphene on SiO2 has a Raman spectrum in which the D peak to G peak ratio is over 4, associated with hydrogenation on both sides. A very low defect density was observed in the scanning probe microscopy measurements, which enables a reverse transformation to graphene. Hydrogen-LTP-exposed HOPG possesses a high thermal stability, and therefore, this transformation requires annealing at over 1000 °C.

  19. Reactive radical-driven bacterial inactivation by hydrogen-peroxide-enhanced plasma-activated-water

    Science.gov (United States)

    Wu, Songjie; Zhang, Qian; Ma, Ruonan; Yu, Shuang; Wang, Kaile; Zhang, Jue; Fang, Jing

    2017-08-01

    The combined effects of plasma activated water (PAW) and hydrogen peroxide (H2O2), PAW/HP, in sterilization were investigated in this study. To assess the synergistic effects of PAW/HP, S. aureus was selected as the test microorganism to determine the inactivation efficacy. Also, the DNA/RNA and proteins released by the bacterial suspensions under different conditions were examined to confirm membrane integrity. Additionally, the intracellular pH (pHi) of S. aureus was measured in our study. Electron spin resonance spectroscopy (ESR) was employed to identify the presence of radicals. Finally, the oxidation reduction potential (ORP), conductivity and pH were measured. Our results revealed that the inactivation efficacy of PAW/HP is much greater than that of PAW, while increased H2O2 concentration result in higher inactivation potential. More importantly, as compared with PAW, the much stronger intensity ESR signals and higher ORP in PAW/HP suggests that the inactivation mechanism of the synergistic effects of PAW/HP: more reactive oxygen species (ROS) and reactive nitrogen species (RNS), especially OH and NO radicals, are generated in PAW combined with H2O2 resulting in more deaths of the bacteria.

  20. Characteristics and properties of metal aluminum thin films prepared by electron cyclotron resonance plasma-assisted atomic layer deposition technology

    Institute of Scientific and Technical Information of China (English)

    Xiong Yu-Qing; Li Xing-Cun; Chen Qiang; Lei Wen-Wen; Zhao Qiao; Sang Li-Jun; Liu Zhong-Wei; Wang Zheng-Duo; Yang Li-Zhen

    2012-01-01

    Metal aluminum (Al) thin films are prepared by 2450 MHz electron cyclotron resonance plasma-assisted atomic layer deposition on glass and p-Si substrates using trimethylaluminum as the precursor and hydrogen as the reductive gas.We focus our attention on the plasma source for the thin-film preparation and annealing of the as-deposited films relative to the surface square resistivity.The square resistivity of as-deposited Al films is greatly reduced after annealing and almost reaches the value of bulk metal.Through chemical and structural analysis,we conclude that the square resistivity is determined by neither the contaminant concentration nor the surface morphology,but by both the crystallinity and crystal size in this process.

  1. CFD Simulation of a Hydrogen/Argon Plasma Jet Reactor for Coal Pyrolysis

    Institute of Scientific and Technical Information of China (English)

    CHEN H. G.; XIE K. C.

    2004-01-01

    A Computational Fluid Dynamics (CFD) model was formulated for DC arc hydrogen/argon plasma jet reactors used in the process of the thermal H2/Ar plasma pyrolysis of coal to acetylene. In this model, fluid flow, convective heat transfer and conjugate heat conductivity are considered simultaneously. The error caused by estimating the inner-wall temperature of a reactor is avoided. The thermodynamic and transport properties of the hydrogen/argon mixture plasma system, which are usually expressed by a set of discrete dats, are fitted into expressions that can be easily implemented in the program. The effects of the turbulence are modeled by two standard k-s equations. The temperature field and velocity field in the plasma jet reactor were calculated by employing SIMPLEST algorithm. The knowledge and insight obtained are useful for the design improvement and scale-up of plasma reactors.

  2. Microwave power coupling with electron cyclotron resonance plasma using Langmuir probe

    Indian Academy of Sciences (India)

    S K Jain; V K Senecha; P A Naik; P R Hannurkar; S C Joshi

    2013-07-01

    Electron cyclotron resonance (ECR) plasma was produced at 2.45 GHz using 200 – 750 W microwave power. The plasma was produced from argon gas at a pressure of 2 × 10−4 mbar. Three water-cooled solenoid coils were used to satisfy the ECR resonant conditions inside the plasma chamber. The basic parameters of plasma, such as electron density, electron temperature, floating potential, and plasma potential, were evaluated using the current–voltage curve using a Langmuir probe. The effect of microwave power coupling to the plasma was studied by varying the microwave power. It was observed that the optimum coupling to the plasma was obtained for ∼ 600 W microwave power with an average electron density of ∼ 6 × 1011 cm−3 and average electron temperature of ∼ 9 eV.

  3. Fundamental ion cyclotron resonance heating of JET deuterium plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Krasilnikov, A. V. [Troitsk Institute of Nuclear Physics (TRINITI), Russia; Van Eester, D. [Laboratory for Plasma Physics-ERM/KMS (LPP-ERM/KMS), Brussels, Belgium; Lerche, E. [Laboratory for Plasma Physics-ERM/KMS (LPP-ERM/KMS), Brussels, Belgium; Ongena, J. [Laboratory for Plasma Physics-ERM/KMS (LPP-ERM/KMS), Brussels, Belgium; Amosov, V. N. [Troitsk Institute of Nuclear Physics (TRINITI), Russia; Biewer, Theodore M [ORNL; Bonheure, G. [Laboratory for Plasma Physics-ERM/KMS (LPP-ERM/KMS), Brussels, Belgium; Crombe, K. [Ghent University, Belgium; Ericsson, G. [Uppsala University, Uppsala, Sweden; Esposito, Basilio [ENEA, Frascati; Giacomelli, L. [Uppsala University, Uppsala, Sweden; Hellesen, C. [Uppsala University, Uppsala, Sweden; Hjalmarsson, A. [Uppsala University, Uppsala, Sweden; Jachmich, S. [EURATOM / UKAEA, UK; Kallne, J. [Uppsala University, Uppsala, Sweden; Kaschuck, Yu A [Troitsk Institute of Nuclear Physics (TRINITI), Russia; Kiptily, V. [EURATOM / UKAEA, UK; Leggate, H. [EURATOM / UKAEA, UK; Mailloux, J. [EURATOM / UKAEA, UK; Marocco, D. [ENEA, Frascati; Mayoral, M.-L. [EURATOM / UKAEA, UK; Popovichev, S. [EURATOM / UKAEA, UK; Riva, M. [ENEA, Frascati; Santala, M. [EURATOM / UKAEA, UK; Stamp, M. F. [EURATOM / UKAEA, UK; Vdovin, V. [Russian Research Center, Kurchatov Institute, Moscow, Russia; Walden, A. [EURATOM / UKAEA, UK

    2009-03-01

    Radio frequency heating of majority ions is of prime importance for understanding the basic role of auxiliary heating in the activated D T phase of ITER. Majority deuterium ion cyclotron resonance heating (ICRH) experiments at the fundamental cyclotron frequency were performed in JET. In spite of the poor antenna coupling at 25 MHz, this heating scheme proved promising when adopted in combination with D neutral beam injection (NBI). The effect of fundamental ICRH of a D population was clearly demonstrated in these experiments: by adding ~25% of heating power the fusion power was increased up to 30 50%, depending on the type of NBI adopted. At this power level, the ion and electron temperatures increased from Ti ~ 4.0 keV and Te ~ 4.5 keV (NBI-only phase) to Ti ~ 5.5 keV and Te ~ 5.2 keV (ICRH + NBI phase), respectively. The increase in the neutron yield was stronger when 80 keV rather than 130 keV deuterons were injected in the plasma. It is shown that the neutron rate, the diamagnetic energy and the electron as well as the ion temperature scale roughly linearly with the applied RF power. A synergistic effect of the combined use of ICRF and NBI heating was observed: (i) the number of neutron counts measured by the neutron camera during the combined ICRF + NBI phases of the discharges exceeded the sum of the individual counts of the NBI-only and ICRF-only phases; (ii) a substantial increase in the number of slowing-down beam ions was detected by the time of flight neutron spectrometer when ICRF power was switched on; (iii) a small D subpopulation with energies slightly above the NBI launch energy was detected by the neutral particle analyzer and -ray spectroscopy.

  4. Two-resonance probe for measuring electron density in low-pressure plasmas

    Science.gov (United States)

    Kim, D. W.; You, S. J.; Kim, S. J.; Kim, J. H.; Oh, W. Y.

    2017-04-01

    A technique for measuring double-checked electron density using two types of microwave resonance is presented. Simultaneous measurement of the resonances (plasma and quarter-wavelength resonator resonances), which were used for the cutoff probe (CP) and hairpin probe (HP), was achieved by the proposed microwave resonance probe. The developed two-resonance probe (TRP) consists of parallel separated coaxial cables exposing the radiation and detection tips. The structure resembles that of the CP, except the gapped coaxial cables operate not only as a microwave feeder for the CP but also as a U- shaped quarter-wavelength resonator for the HP. By virtue of this structure, the microwave resonances that have typically been used for measuring the electron density for the CP and HP were clearly identified on the microwave transmission spectrum of the TRP. The two types of resonances were measured experimentally under various power and pressure conditions for the plasma. A three-dimensional full-wave simulation model for the TRP is also presented and used to investigate and reproduce the resonances. The electron densities inferred from the resonances were compared and showed good agreement. Quantitative differences between the densities were attributed to the effects of the sheath width and spatial density gradient on the resonances. This accessible technique of using the TRP to obtain double-checked electron densities may be useful for comparative study and provides complementary uses for the CP and HP.

  5. Breakdown transient study of plasma distributions in a 2.45 GHz hydrogen discharge

    Energy Technology Data Exchange (ETDEWEB)

    Cortázar, O.D., E-mail: daniel.cortazar@uclm.es [Universidad de Castilla-La Mancha, ETSII-INEI, Applied Mechanics and Projects Department, C.J. Cela s/n, 13170 Ciudad Real (Spain); Megía-Macías, A. [ESS Bilbao Consortium, Polígono Ugaldeguren-III Pol. A 7B, 48170-Zamudio, Vizcaya (Spain); Tarvainen, O.; Koivisto, H. [University of Jyväskylä, Department of Physics, PO Box 35 (YFL), 40500 Jyväskylä (Finland)

    2015-05-01

    Plasma distribution transients associated with the breakdown of a 2.45 GHz hydrogen discharge similar to high current microwave ion sources are studied by means of an ultra-fast frame image acquisition system in visible light range. Eight different plasma distributions have been studied by photographing the 2D projections of the discharge through a transparent plasma electrode. The temporal evolution of images in Balmer-alpha and Fulcher band wavelengths have been recorded associated to atomic and molecular excitation and ionization processes. Some unexpected plasma distributions transient behaviors during breakdown are reported.

  6. Combined laser induced ignition and plasma spectroscopy: Fundamentals and application to a hydrogen-air combustor

    Energy Technology Data Exchange (ETDEWEB)

    Zimmer, L. [Aeroengine Technology Center, Japan Aerospace Exploration Agency, 7-44-1 Jindaiji-Higashi Chofu, 182-8522 Tokyo (Japan)], E-mail: laurent.zimmer@em2c.ecp.fr; Okai, K. [Aeroengine Technology Center, Japan Aerospace Exploration Agency, 7-44-1 Jindaiji-Higashi Chofu, 182-8522 Tokyo (Japan)], E-mail: okai@chofu.jaxa.jp; Kurosawa, Y. [Clean engine team, Japan Aerospace Exploration Agency, 7-44-1 Jindaiji-Higashi Chofu, 182-8522 Tokyo (Japan)], E-mail: kuro@chofu.jaxa.jp

    2007-12-15

    Combined Laser Induced Ignition and Plasma Spectroscopy (LI2PS) has the potential to give the exact local composition of a mixture at the ignition point and at the ignition time. However, as different laser energies are required to ignite a particular mixture as function of space, the typical approach using two power meters to calibrate the plasma spectroscopy measurement is not well suited. Furthermore, LI2PS requires single shot measurements and therefore high accuracy. In this paper, a novel calibration scheme is presented for application of Laser Induced Plasma Spectroscopy (LIPS) to gaseous analyses. Numerical simulations of air spectra are used to show that species emission can be used directly from the broadband spectra to determine the plasma conditions. The ratio of nitrogen emission around 744 nm and around 870 nm is found to be a sensitive indication of temperature in the emission ranging from 700 to 890 nm. Comparisons with experimental spectra show identical tendencies and validate the findings of the simulations. This approach is used in a partially-premixed hydrogen-air burner. First, helium is used instead of hydrogen. After an explanation of timing issue related to LIPS, it is shown that the calibration required depends only on nitrogen excitation and nitrogen-hydrogen ratio, without the need to know the deposited power. Measurements of the fuel distribution as function of injection momentum and spatial localization are reported. To illustrate the use of such a single shot approach, combined laser ignition and plasma spectroscopy is proposed. In this case, the calibration is based on hydrogen excitation and hydrogen-oxygen and hydrogen-nitrogen ratio. Results obtained with LI2PS show that ignition is successful only for high power and relatively high hydrogen concentration compared to the local mean. It is expected that LI2PS will become an important tool when dealing with partially-premixed or diffusion flame ignition.

  7. On the spectroscopic detection of neutral species in a low-pressure plasma containing boron and hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Lavrov, B P [Faculty of Physics, St. Petersburg State University, St. Petersburg, 198504 (Russian Federation); Osiac, M [Institut fuer Niedertemperatur-Plasmaphysik, 17489 Greifswald, Friedrich-Ludwig-Jahn-Str. 19 (Germany); Pipa, A V [Faculty of Physics, St. Petersburg State University, St. Petersburg, 198504 (Russian Federation); Roepcke, J [Institut fuer Niedertemperatur-Plasmaphysik, 17489 Greifswald, Friedrich-Ludwig-Jahn-Str. 19 (Germany)

    2003-11-01

    Spectroscopic studies of microwave discharges in H{sub 2}-Ar-B{sub 2}H{sub 6} gas mixtures (f = 2.45 GHz, P = 1.2-3.5 kW, p = 1-8 mbar) have been performed to improve the possibilities of diagnostics of non-equilibrium, low-pressure plasmas containing boron and hydrogen. For this purpose, UV-VIS optical emission spectroscopy and infrared absorption spectroscopy with tunable diode lasers (TDLAS) have been applied. It is shown that information about neutral species and the gas temperature may be obtained by means of new and modified spectroscopic methods. A method for the determination of the absolute number density of boron atoms from measured relative intensities of the components of the boron resonance doublet (distorted by reabsorption) is proposed and tested for validity. The maximum of the density was found to be 3.8x10{sup 11} atoms cm{sup -3} at an admixture of diborane of about 2%. The gas temperature was determined from the intensity distributions in the rotational structure of the emission bands of BH and H{sub 2} and from Doppler broadening of the absorption line profiles of the BH molecule. It was observed that values of the gas temperature obtained from the rotational intensity distributions are in good agreement with those obtained from Doppler widths (T{sub g} = 700-1070 K). Based on measurements of the relative line intensities of atomic and molecular hydrogen and the gas temperature, and using a simple excitation-deactivation model, the density of molecular hydrogen was found to be about 40 times higher than the density of atomic hydrogen. It is shown that some absorption lines of boron hydrides (B{sub 2}H{sub 6}, BH{sub 3} and BH) detected by TDLAS may be used for plasma diagnostics.

  8. Numerical simulations based on probe measurements in EUV-induced hydrogen plasma

    Science.gov (United States)

    Abrikosov, Alex; Reshetnyak, Viktor; Astakhov, Dmitry; Dolgov, Alexandr; Yakushev, Oleg; Lopaev, Dmitry; Krivtsun, Vladimir

    2017-04-01

    We use the two-dimensional particle-in-cell model with Monte Carlo collisions to study the plasma induced in hydrogen by short pulses of extreme ultraviolet (EUV) radiation at wavelengths in the range 10–20 nm with a pulse duration of about 40 ns (FWHM). This plasma is formed via both photoionization by the high-energy EUV photons and by the secondary photoelectrons emitted from the hydrogen molecules and the irradiated surface. The latter process can be enhanced by the external electric field that accelerates the electrons. In order to establish a base for our model so as to obtain accurate results, we record a temporally-resolved series of current–voltage characteristics for a small probing electrode inserted into EUV-induced hydrogen plasma. We then resort to simulating this plasma in the same geometry with the probe in our model which we validate by matching its results to the experimentally measured dynamics of the probe current–voltage curves. Having validated the model this way, we use this model as an independent instrument capable of obtaining the spatiotemporal picture of EUV-induced plasma evolution. We use this instrument to study the plasma formation during the EUV pulse and point out the processes that take part in forming this plasma, such as impact ionization and direct ionization by EUV photons.

  9. Remote operation of the GOLEM tokamak with hydrogen and helium plasmas

    Science.gov (United States)

    Svoboda, V.; Dvornova, A.; Dejarnac, R.; Prochazka, M.; Zaprianov, S.; Akhmethanov, R.; Bogdanova, M.; Dimitrova, M.; Dimitrov, Zh; Grover, O.; Hlavata, L.; Ivanov, K.; Kruglov, K.; Marinova, P.; Masherov, P.; Mogulkin, A.; Mlynar, J.; Stockel, J.; Volynets, A.

    2016-10-01

    The GOLEM tokamak was operated remotely via Internet connection during the 6th International Workshop and Summer School on Plasma Physics. Performances of hydrogen and helium discharges are compared in this paper. It is found, at similar vacuum conditions, that helium discharges are shorter but the breakdown of the working gas can be quite easily achieved at almost the same loop voltage. The plasma current in helium discharges is slightly lower than in the case of hydrogen. Turbulent fluctuations of the floating potential measured by means of an array of Langmuir probes reveal a noticeably different character in the two discharges.

  10. Reversed ageing of Fe3O4 nanoparticles by hydrogen plasma

    Science.gov (United States)

    Schmitz-Antoniak, Carolin; Schmitz, Detlef; Warland, Anne; Svechkina, Nataliya; Salamon, Soma; Piamonteze, Cinthia; Wende, Heiko

    2016-02-01

    Magnetite (Fe3O4) nanoparticles suffer from severe ageing effects when exposed to air even when they are dispersed in a solvent limiting their applications. In this work, we show that this ageing can be fully reversed by a hydrogen plasma treatment. By x-ray absorption spectroscopy and its associated magnetic circular dichroism, the electronic structure and magnetic properties were studied before and after the plasma treatment and compared to results of freshly prepared magnetite nanoparticles. While aged magnetite nanoparticles exhibit a more γ-Fe2O3 like behaviour, the hydrogen plasma yields pure Fe3O4 nanoparticles. Monitoring the temperature dependence of the intra-atomic spin dipole contribution to the dichroic spectra gives evidence that the structural, electronic and magnetic properties of plasma treated magnetite nanoparticles can outperform the ones of the freshly prepared batch.

  11. Selective etching of metallic single-wall carbon nanotubes with hydrogen plasma.

    Science.gov (United States)

    Hassanien, A; Tokumoto, M; Umek, P; Vrbanič, D; Mozetič, M; Mihailović, D; Venturini, P; Pejovnik, S

    2005-02-01

    We present Raman scattering and scanning tunnelling microscopy (STM) measurements on hydrogen plasma etched single-wall carbon nanotubes (SWNTs). Interestingly, both the STM and Raman spectroscopy show that the metallic SWNTs are dramatically altered and highly defected by the plasma treatment. In addition, structural characterizations show that metal catalysts are detached from the ends of the SWNT bundles. For semiconducting SWNTs we observe no feature of defects or etching along the nanotubes. Raman spectra in the radial breathing mode region of plasma-treated SWNT material show that most of the tubes are semiconducting. These results show that hydrogen plasma treatment favours etching of metallic nanotubes over semiconducting ones and therefore could be used to tailor the electronic properties of SWNT raw materials.

  12. Two Temperature Modeling and Experimental Measurements of Laser Sustained Hydrogen Plasmas

    Science.gov (United States)

    1993-05-01

    Thermal Rocket Performance," AIAA Paper 88-2774, AIAA Thermophysics...Krier, H., and Mazumder, J. (1990). "Continuous Wave Laser Sustained Hydrogen Plasmas for Thermal Rocket Propulsion," AIAA Paper 90-2637, AIAA/DGLR...Schwartz, S., Mertogul, A.E., Chen, X., Krier, H., and Mazumder, J. (1990). "Laser-Sustained Argon Plasmas for Thermal Rocket Propulsion," Journal of Propulsion and Power, Vol. 6, No. 1, pp. 38-45, January-February 1990.

  13. CH spectroscopy for carbon chemical erosion analysis in high density low temperature hydrogen plasma

    NARCIS (Netherlands)

    Westerhout, J.; Cardozo, N. J. L.; Rapp, J.; van Rooij, G. J.

    2009-01-01

    The CH A-X molecular band is measured upon seeding the hydrogen plasma in the linear plasma generator Pilot-PSI [electron temperature T-e=0.1-2.5 eV and electron density n(e)=(0.5-5) X 10(20) m(-3)] with methane. Calculated inverse photon efficiencies for these conditions range from 3 up to >10(6

  14. Theoretical and experimental studies of space-related plasma wave propagation and resonance phenomena

    Science.gov (United States)

    Crawford, F. W.

    1975-01-01

    A ten year summary was given of university research on the nature and characteristics of space related plasma resonance phenomena, whistler propagation in laboratory plasmas, and theoretical and experimental studies of plasma wave propagation. Data are also given on long delayed echoes, low frequency instabilities, ionospheric heating, and backscatter, and pulse propagation. A list is included of all conference papers, publications, and reports resulting from the study.

  15. Low energy, high power hydrogen neutral beam for plasma heating

    Energy Technology Data Exchange (ETDEWEB)

    Deichuli, P.; Davydenko, V.; Ivanov, A., E-mail: ivanov@inp.nsk.su; Mishagin, V.; Sorokin, A.; Stupishin, N. [Budker Institute of Nuclear Physics, Prospect Lavrentieva 11, 630090 Novosibirsk (Russian Federation); Korepanov, S.; Smirnov, A. [Tri Alpha Energy, Inc., Foothill Ranch, California 92610 (United States)

    2015-11-15

    A high power, relatively low energy neutral beam injector was developed to upgrade of the neutral beam system of the gas dynamic trap device and C2-U experiment. The ion source of the injector produces a proton beam with the particle energy of 15 keV, current of up to 175 A, and pulse duration of a few milliseconds. The plasma emitter of the ion source is produced by superimposing highly ionized plasma jets from an array of four arc-discharge plasma generators. A multipole magnetic field produced with permanent magnets at the periphery of the plasma box is used to increase the efficiency and improve the uniformity of the plasma emitter. Multi-slit grids with 48% transparency are fabricated from bronze plates, which are spherically shaped to provide geometrical beam focusing. The focal length of the Ion Optical System (IOS) is 3.5 m and the initial beam diameter is 34 cm. The IOS geometry and grid potentials were optimized numerically to ensure accurate beam formation. The measured angular divergences of the beam are ±0.01 rad parallel to the slits and ±0.03 rad in the transverse direction.

  16. Low energy, high power hydrogen neutral beam for plasma heating

    Science.gov (United States)

    Deichuli, P.; Davydenko, V.; Ivanov, A.; Korepanov, S.; Mishagin, V.; Smirnov, A.; Sorokin, A.; Stupishin, N.

    2015-11-01

    A high power, relatively low energy neutral beam injector was developed to upgrade of the neutral beam system of the gas dynamic trap device and C2-U experiment. The ion source of the injector produces a proton beam with the particle energy of 15 keV, current of up to 175 A, and pulse duration of a few milliseconds. The plasma emitter of the ion source is produced by superimposing highly ionized plasma jets from an array of four arc-discharge plasma generators. A multipole magnetic field produced with permanent magnets at the periphery of the plasma box is used to increase the efficiency and improve the uniformity of the plasma emitter. Multi-slit grids with 48% transparency are fabricated from bronze plates, which are spherically shaped to provide geometrical beam focusing. The focal length of the Ion Optical System (IOS) is 3.5 m and the initial beam diameter is 34 cm. The IOS geometry and grid potentials were optimized numerically to ensure accurate beam formation. The measured angular divergences of the beam are ±0.01 rad parallel to the slits and ±0.03 rad in the transverse direction.

  17. Modelling of the hydrogen effects on the morphogenesis of hydrogenated silicon nano-structures in a plasma reactor; Modelisation des effets de l'hydrogene sur la morphogenese des nanostructures de silicium hydrogene dans un reacteur plasma

    Energy Technology Data Exchange (ETDEWEB)

    Brulin, Q

    2006-01-15

    This work pursues the goal of understanding mechanisms related to the morphogenesis of hydrogenated silicon nano-structures in a plasma reactor through modeling techniques. Current technologies are first reviewed with an aim to understand the purpose behind their development. Then follows a summary of the possible studies which are useful in this particular context. The various techniques which make it possible to simulate the trajectories of atoms by molecular dynamics are discussed. The quantum methods of calculation of the interaction potential between chemical species are then developed, reaching the conclusion that only semi-empirical quantum methods are sufficiently fast to be able to implement an algorithm of quantum molecular dynamics on a reasonable timescale. From the tools introduced, a reflection on the nature of molecular metastable energetic states is presented for the theoretical case of the self-organized growth of a linear chain of atoms. This model - which consists of propagating the growth of a chain by the successive addition of the atom which least increases the electronic energy of the chain - shows that the Fermi level is a parameter essential to self organization during growth. This model also shows that the structure formed is not necessarily a total minimum energy structure. From all these numerical tools, the molecular growth of clusters can be simulated by using parameters from magnetohydrodynamic calculation results of plasma reactor modeling (concentrations of the species, interval between chemical reactions, energy of impact of the reagents...). The formation of silicon-hydrogen clusters is thus simulated by the successive capture of silane molecules. The structures formed in simulation at the operating temperatures of the plasma reactor predict the formation of spherical clusters constituting an amorphous silicon core covered by hydrogen. These structures are thus not in a state of minimum energy, contrary to certain experimental

  18. Plasma density characterization at SPARC_LAB through Stark broadening of Hydrogen spectral lines

    Science.gov (United States)

    Filippi, F.; Anania, M. P.; Bellaveglia, M.; Biagioni, A.; Chiadroni, E.; Cianchi, A.; Di Giovenale, D.; Di Pirro, G.; Ferrario, M.; Mostacci, A.; Palumbo, L.; Pompili, R.; Shpakov, V.; Vaccarezza, C.; Villa, F.; Zigler, A.

    2016-09-01

    Plasma-based acceleration techniques are of great interest for future, compact accelerators due to their high accelerating gradient. Both particle-driven and laser-driven Plasma Wakefield Acceleration experiments are foreseen at the SPARC_LAB Test Facility (INFN National Laboratories of Frascati, Italy), with the aim to accelerate high-brightness electron beams. In order to optimize the efficiency of the acceleration in the plasma and preserve the quality of the accelerated beam, the knowledge of the plasma electron density is mandatory. The Stark broadening of the Hydrogen spectral lines is one of the candidates used to characterize plasma density. The implementation of this diagnostic for plasma-based experiments at SPARC_LAB is presented.

  19. Second-harmonic ion cyclotron resonance heating scenarios of Aditya tokamak plasma

    Indian Academy of Sciences (India)

    Asim Kumar Chattopadhyay; S V Kulkarni; R Srinivasan; Aditya Team

    2015-10-01

    Plasma heating with the fast magnetosonic waves in the ion cyclotron range of frequencies (ICRF) is one of the auxiliary heating schemes of Aditya tokamak. Numerical simulation of second-harmonic resonance heating scenarios in low-temperature, low-density Aditya plasma has been carried out for fast magnetosonic wave absorption in ICRF range, using full-wave ion cyclotron heating code TORIC combined with Fokker–Planck quasilinear solver SSFPQL and the results are explained. In such low-temperature, low-density plasma, ion absorption for second-harmonic resonance heating is less but significant amount of direct electron heating is observed.

  20. Resonances of a hydrogen atom in strong parallel electric and magnetic fields using B-spline basis sets

    Institute of Scientific and Technical Information of China (English)

    Zhang Yue-Xia; Meng Hui-Yan; Shi Ting-Yun

    2008-01-01

    The B-spline basis set plus complex scaling method is applied to the numerical calculation of the exact resonance parameters Er and I/2 of a hydrogen atom in parallel electric and magnetic fields.The method can calculate the ground and higher excited resonances accurately and efficiently.The resonance parameters with accuracies of 10-9 - 10-12 for hydrogen atom in parallel fields with different field strengths and symmetries are presented and compared with previous ones.Extension to the calculation of Rydberg atom in crossed electric and magnetic fields and of atomic double excited states in external electric fields is discussed.

  1. The Multiple Resonance Probe: A Novel Device for Industry Compatible Plasma Diagnostics

    Science.gov (United States)

    Brinkmann, Ralf Peter; Storch, Robert; Lapke, Martin; Oberrath, Jens; Schulz, Christian; Styrnoll, Tim; Zietz, Christian; Awakowicz, Peter; Musch, Thomas; Mussenbrock, Thomas; Rolfes, Ilona

    2012-10-01

    To be useful for the supervision or control of technical plasmas, a diagnostic method must be i) robust and stable, ii) insensitive to perturbation by the process, iii) itself not perturbing the process, iv) clearly and easily interpretable without the need for calibration, v) compliant with the requirements of process integration, and, last but not least, vi) economical in terms of investment, footprint, and maintenance. Plasma resonance spectroscopy, exploiting the natural ability of plasmas to resonate on or near the electron plasma frequency, provides a good basis for such an ``industry compatible'' plasma diagnostics. The contribution will describe the general idea of active plasma resonance spectroscopy and introduce a mathematical formalism for its analysis. It will then focus on the novel multipole resonance probe (MRP), where the excited resonances can be classified explicitly and the connection between the probe response and the desired electron density can be cast as a simple formula. The current state of the MRP project will be described, including the experimental characterization of a prototype in comparison with Langmuir probes, and the development of a specialized measurement circuit.

  2. Potential applications of a new microwave ECR (electron cyclotron resonance) multicusp plasma ion source

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, C.C.

    1990-01-01

    A new microwave electron cyclotron resonance (ECR) multicusp plasma ion source using two ECR plasma production regions and multicusp plasma confinement has been developed at Oak Ridge National Laboratory. This source has been operated to produce uniform and dense plasmas over large areas of 300 to 400 cm{sup 2}. The plasma source has been operated with continuous argon gas feed and pulsed microwave power. The discharge initiation phenomena and plasma properties have been investigated and studied as functions of discharge parameters. Together with the discharge characteristics observed, a hypothetical discharge mechanism for this plasma source is reported and discussed. Potential applications, including plasma and ion-beam processing for manufacturing advanced microelectronics and for space electric propulsion, are discussed. 7 refs., 6 figs.

  3. 2D PIC modeling of the EUV induced hydrogen plasma and comparison to the observed carbon etching rate

    NARCIS (Netherlands)

    Astakhov, Dmitry; Goedheer, W.J.; Lopaev, D.; Ivanov, V.; Krivtsun, V.M.; Yakushev, O.; Koshelev, K.; Bijkerk, Frederik

    2013-01-01

    The interaction between an EUV driven hydrogen plasma and a carbon covered surface was investigated using 2D PIC modeling and results were compared with experimental observations. The plasma is formed due to ionization of a low pressure hydrogen gas by the EUV photons and the photoelectrons from the

  4. Adhesion improvement of hydrogenated diamond-like carbon thin films by pre-deposition plasma treatment of rubber substrate

    NARCIS (Netherlands)

    Bui, X.L.; Pei, Y.T.; Mulder, E.D.G.; Hosson, J.Th.M. De

    2009-01-01

    For reduction of friction and enhancement of wear resistance of dynamic rubber seals, thin films of hydrogenated diamond-like carbon (DLC) have been deposited on hydrogenated nitrile butadiene rubber (HNBR) via magnetron-enhanced plasma chemical vapor deposition (ME-PCVD). Pre-deposition plasma trea

  5. Transition of single-walled carbon nanotubes from metallic to semiconducting in field-effect transistors by hydrogen plasma treatment.

    Science.gov (United States)

    Zheng, Gang; Li, Qunqing; Jiang, Kaili; Zhang, Xiaobo; Chen, Jia; Ren, Zheng; Fan, Shoushan

    2007-06-01

    We report hydrogen plasma treatment results on converting the metallic single-walled carbon nanotubes to semiconducting single-walled carbon nanotubes. We found that the as-grown single-walled carbon nanotubes (SWNTs) can be sorted as three groups which behave as metallic, as-metallic, and semiconducting SWNTs. These three groups have different changes under hydrogen plasma treatment and successive annealing process. The SWNTs can be easily hydrogenated in the hydrogen plasma environment and the as-metallic SWNTs can be transformed to semiconducting SWNTs. The successive annealing process can break the C-H bond, so the conversion is reversible.

  6. Accessibility condition of wave propagation and multicharged ion production in electron cyclotron resonance ion source plasma

    Energy Technology Data Exchange (ETDEWEB)

    Kato, Yushi, E-mail: kato@eei.eng.osaka-u.ac.jp; Yano, Keisuke; Nishiokada, Takuya; Nagaya, Tomoki; Kimura, Daiju; Kumakura, Sho; Imai, Youta; Hagino, Shogo; Otsuka, Takuro; Sato, Fuminobu [Division of Electrical, Electronic and Information Engineering, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita-shi, Osaka 565-0871 (Japan)

    2016-02-15

    A new tandem type source of electron cyclotron resonance (ECR) plasmas has been constructing for producing synthesized ion beams in Osaka University. Magnetic mirror field configuration with octupole magnets can be controlled to various shape of ECR zones, namely, in the 2nd stage plasma to be available by a pair mirror and a supplemental coil. Noteworthy correlations between these magnetic configurations and production of multicharged ions are investigated in detail, as well as their optimum conditions. We have been considering accessibility condition of electromagnetic and electrostatic waves propagating in ECR ion source plasma, and then investigated their correspondence relationships with production of multicharged ions. It has been clarified that there exits efficient configuration of ECR zones for producing multicharged ion beams experimentally, and then has been suggested from detail accessibility conditions on the ECR plasma that new resonance, i.e., upper hybrid resonance, must have occurred.

  7. An Investigation on the He−(1s2s2 2S Resonance in Debye Plasmas

    Directory of Open Access Journals (Sweden)

    Arijit Ghoshal

    2017-01-01

    Full Text Available The effect of Debye plasma on the 1 s 2 s 2 2 S resonance states in the scattering of electron from helium atom has been investigated within the framework of the stabilization method. The interactions among the charged particles in Debye plasma have been modelled by Debye–Huckel potential. The 1 s 2 s excited state of the helium atom has been treated as consisting of a H e + ionic core plus an electron moving around. The interaction between the core and the electron has then been modelled by a model potential. It has been found that the background plasma environment significantly affects the resonance states. To the best of our knowledge, such an investigation of 1 s 2 s 2 2 S resonance states of the electron–helium system embedded in Debye plasma environment is the first reported in the literature.

  8. Design of a high particle flux hydrogen helicon plasma source for used in plasma materials interaction studies

    Energy Technology Data Exchange (ETDEWEB)

    Goulding, Richard Howell [ORNL; Chen, Guangye [ORNL; Meitner, Steven J [ORNL; Baity Jr, F Wallace [ORNL; Caughman, John B [ORNL; Owen, Larry W [ORNL

    2009-01-01

    Existing linear plasma materials interaction (PMI) facilities all use plasma sources with internal electrodes. An rf-based helicon source is of interest because high plasma densities can be generated with no internal electrodes, allowing true steady state operation with minimal impurity generation. Work has begun at Oak Ridge National Laboratory (ORNL) to develop a large (15 cm) diameter helicon source producing hydrogen plasmas with parameters suitable for use in a linear PMI device: n(e) >= 10(19)m(-3), T(e) = 4-10 eV, particle flux Gamma(p) > 10(23) m(-3) s(-1), and magnetic field strength |B| up to I T in the source region. The device, whose design is based on a previous hydrogen helicon source operated at ORNL[1], will operate at rf frequencies in the range 10 - 26 MHz, and power levels up to similar to 100 kW. Limitations in cooling will prevent operation for pulses longer than several seconds, but a major goal will be the measurement of power deposition on device structures so that a later steady state version can be designed. The device design, the diagnostics to be used, and results of rf modeling of the device will be discussed. These include calculations of plasma loading, resulting currents and voltages in antenna structures and the matching network, power deposition profiles, and the effect of high |B| operation on power absorption.

  9. Full densification of inkjet-printed copper conductive tracks on a flexible substrate utilizing a hydrogen plasma sintering

    Science.gov (United States)

    Kwon, Young-Tae; Lee, Young-In; Kim, Seil; Lee, Kun-Jae; Choa, Yong-Ho

    2017-02-01

    Low temperature sintering techniques are crucial in developing flexible printed electronics. In this work, we demonstrate a novel hydrogen plasma sintering method that achieves a full reduction and densification of inkjet-printed patterns using a copper complex ion ink. After inkjet printing on polyethylene terephthalate (PET) substrates, both hydrogen plasma and conventional hydrogen thermal treatment were employed to compare the resulting microstructures, electrical properties and anti-oxidation behavior. The plasma treated pattern shows a fully densified microstructure with a resistivity of 3.23 μΩ cm, while the thermally treated pattern shows a relatively poor microstructure and high resistivity. In addition, the hydrogen plasma-treated copper pattern retains its electrical resistivity for one month without any significant decrease. This novel hydrogen plasma sintering technique could be used to produce conductive patterns with excellent electrical properties, allowing for highly reliable flexible printed electronics.

  10. Picosecond all-optical switching in hydrogenated amorphous silicon microring resonators

    CERN Document Server

    Pelc, Jason S; Vo, Sonny; Santori, Charles; Fattal, David A; Beausoleil, Raymond G

    2014-01-01

    We utilize cross-phase modulation to observe all-optical switching in microring resonators fabricated with hydrogenated amorphous silicon (a-Si:H). Using 2.7-ps pulses from a mode-locked fiber laser in the telecom C-band, we observe optical switching of a cw telecom-band probe with full-width at half-maximum switching times of 14.8 ps, using approximately 720 fJ of energy deposited in the microring. In comparison with telecom-band optical switching in crystalline silicon microrings, a-Si:H exhibits substantially higher switching speeds due to reduced impact of free-carrier processes.

  11. Resonant electron transfer in slow collisions of protons with Rydberg hydrogen atoms

    Energy Technology Data Exchange (ETDEWEB)

    Janev, R.K.; Joachain, C.J.; Nedeljkovic, N.N.

    1984-05-01

    The resonant charge-transfer reaction of protons on highly excited hydrogen atoms is considered by taking into account both the tunneling (under-barrier) and the over-barrier (classically allowed) electron transitions. It is demonstrated that in a wide range of variation of the reduced ve- locity v = vn, the classical transition mechanism is predominant. Cross-section calculations for principal quantum numbers n between 10 and 50 are presented. The results for 45< or =n< or =50 are compared with the available experimental data and with other theoretical calculations.

  12. Nanosecond pulsed humid Ar plasma jet in air: shielding, discharge characteristics and atomic hydrogen production

    Science.gov (United States)

    Yatom, Shurik; Luo, Yuchen; Xiong, Qing; Bruggeman, Peter J.

    2017-10-01

    Gas phase non-equilibrium plasmas jets containing water vapor are of growing interest for many applications. In this manuscript, we report a detailed study of an atmospheric pressure nanosecond pulsed Ar  +  0.26% H2O plasma jet. The plasma jet operates in an atmospheric pressure air surrounding but is shielded with a coaxial argon flow to limit the air diffusion into the jet effluent core. The jet impinges on a metal plate electrode and produces a stable plasma filament (transient spark) between the needle electrode in the jet and the metal plate. The stable plasma filament is characterized by spatially and time resolved electrical and optical diagnostics. This includes Rayleigh scattering, Stark broadening of the hydrogen Balmer lines and two-photon absorption laser induced fluorescence (TaLIF) to obtain the gas temperature, the electron density and the atomic hydrogen density respectively. Electron densities and atomic hydrogen densities up to 5 × 1022 m-3 and 2 × 1022 m-3 have been measured. This shows that atomic hydrogen is one of the main species in high density Ar-H2O plasmas. The gas temperature does not exceed 550 K in the core of the plasma. To enable in situ calibration of the H TaLIF at atmospheric pressure a previously published O density calibration scheme is extended to include a correction for the line profiles by including overlap integrals as required by H TaLIF. The line width of H TaLIF, due to collision broadening has the same trend as the neutral density obtained by Rayleigh scattering. This suggests the possibility to use this technique to in situ probe neutral gas densities.

  13. Capacitively coupled hydrogen plasmas sustained by tailored voltage waveforms: excitation dynamics and ion flux asymmetry

    NARCIS (Netherlands)

    Bruneau, B.; Diomede, P.; Economou, D. J.; Longo, S.; Gans, T.; O’Connell, D.; Greb, A.; Johnson, E.; Booth, J. P.

    2016-01-01

    Parallel plate capacitively coupled plasmas in hydrogen at relatively high pressure ( 1 Torr) are excited with tailored voltage waveforms containing up to five frequencies. Predictions of a hybrid model combining a particle-in-cell simulation with Monte Carlo collisions and a fluid model

  14. Capacitively coupled hydrogen plasmas sustained by tailored voltage waveforms: vibrational kinetics and negative ions control

    NARCIS (Netherlands)

    Diomede, P.; Bruneau, B.; Longo, S.; Johnson, E.; Booth, J. P.

    2017-01-01

    A comprehensive hybrid model of a hydrogen capacitively coupled plasmas (CCP), including a detailed description of the molecular vibrational kinetics, has been applied to the study of the effect of tailored voltage waveforms (TVWs) on the production kinetics and transport of negative ions in these

  15. Synergistic effects of hydrogen plasma exposure, pulsed laser heating and temperature on rhodium surfaces

    NARCIS (Netherlands)

    Marot, L.; De Temmerman, G.; Doerner, R. P.; Umstadter, K.; Wagner, R. S.; Mathys, D.; Duggelin, M.; Meyer, E.

    2013-01-01

    The combined effect of hydrogen plasma exposure and surface heating, either continuous or by short laser pulses (5 ns), on the surface morphology of rhodium layers has been studied. Investigations were performed by reflectivity measurements, scanning electron microscopy (SEM), X-ray

  16. Coal pyrolysis to acetylene using dc hydrogen plasma torch: effects of system variables on acetylene concentration

    Energy Technology Data Exchange (ETDEWEB)

    Chen Longwei; Meng Yuedong; Shen Jie; Shu Xingsheng; Fang Shidong [Laboratory of Applied Low-temperature Plasma Physics, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, 230031 (China); Xiong Xinyang, E-mail: lwchen@ipp.ac.c [Xinjiang Tianye Group, Xinjiang, 832000 (China)

    2009-03-07

    In order to unveil the inner mechanisms that determine acetylene concentration, experimental studies on the effect of several parameters such as plasma torch power, hydrogen flux and coal flux were carried out from coal pyrolysis in a dc plasma torch. Xinjiang long flame coals including volatile constituents at a level of about 42% were used in the experiment. Under the following experimental conditions, namely plasma torch power, hydrogen flow rate and pulverized coal feed speed of 2.12 MW, 32 kg h{sup -1} and 900 kg h{sup -1}, respectively, acetylene volume concentration of about 9.4% was achieved. The experimental results indicate that parameters such as plasma torch power and coal flux play important roles in the formation of acetylene. Acetylene concentration increases inconspicuously with hydrogen flux. A chemical thermodynamic equilibrium model using the free energy method is introduced in this paper to numerically simulate each experimental condition. The numerical results are qualitatively consistent with the experimental results. Two parameters, i.e. the gas temperature and the ratio of hydrogen/carbon, are considered to be the dominant and independent factors that determine acetylene concentration.

  17. Coal pyrolysis to acetylene using dc hydrogen plasma torch: effects of system variables on acetylene concentration

    Science.gov (United States)

    Chen, Longwei; Meng, Yuedong; Shen, Jie; Shu, Xingsheng; Fang, Shidong; Xiong, Xinyang

    2009-03-01

    In order to unveil the inner mechanisms that determine acetylene concentration, experimental studies on the effect of several parameters such as plasma torch power, hydrogen flux and coal flux were carried out from coal pyrolysis in a dc plasma torch. Xinjiang long flame coals including volatile constituents at a level of about 42% were used in the experiment. Under the following experimental conditions, namely plasma torch power, hydrogen flow rate and pulverized coal feed speed of 2.12 MW, 32 kg h-1 and 900 kg h-1, respectively, acetylene volume concentration of about 9.4% was achieved. The experimental results indicate that parameters such as plasma torch power and coal flux play important roles in the formation of acetylene. Acetylene concentration increases inconspicuously with hydrogen flux. A chemical thermodynamic equilibrium model using the free energy method is introduced in this paper to numerically simulate each experimental condition. The numerical results are qualitatively consistent with the experimental results. Two parameters, i.e. the gas temperature and the ratio of hydrogen/carbon, are considered to be the dominant and independent factors that determine acetylene concentration.

  18. Arc Root Motions in an Argon-Hydrogen Direct-Current Plasma Torch at Reduced Pressure

    Institute of Scientific and Technical Information of China (English)

    HUANG He-Ji; PAN Wen-Xia; WU Cheng-Kang

    2008-01-01

    Arc root motions in generating dc argon hydrogen plasma at reduced pressure are optically observed using a high-speed video camera. The time resolved angular position of the arc root attachment point is measured and analysed. The arc root movement is characterized as a chaotic and jumping motion along the circular direction on the anode surface.

  19. Microscopic and thermodynamic properties of dense semiclassical partially ionized hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Ramazanov, T S; Dzhumagulova, K N; Gabdullin, M T [IETP, Al-Farabi Kazakh National University, 96a, Tole Bi St, Almaty, 050012 (Kazakhstan)

    2006-04-28

    Microscopic and thermodynamic properties of dense semiclassical partially ionized hydrogen plasma were investigated on the basis of pseudopotential models. Radial distribution functions (RDF) of particles were obtained using a system of the Ornstein-Zernike integral equations. The corrections to internal energy and the equation of state were calculated using RDF.

  20. Atomic hydrogen and diatomic titanium-monoxide molecular spectroscopy in laser-induced plasma

    Science.gov (United States)

    Parigger, Christian G.; Woods, Alexander C.

    2017-03-01

    This article gives a brief review of experimental studies of hydrogen Balmer series emission spectra. Ongoing research aims to evaluate early plasma evolution following optical breakdown in laboratory air. Of interest is as well laser ablation of metallic titanium and characterization of plasma evolution. Emission of titanium monoxide is discussed together with modeling of diatomic spectra to infer temperature. The behavior of titanium particles in plasma draws research interests ranging from the modeling of stellar atmospheres to the enhancement of thin film production via pulsed laser deposition.

  1. Analysis and characterization of microwave plasma generated with rectangular all-dielectric resonators

    Science.gov (United States)

    Kourtzanidis, K.; Raja, L. L.

    2017-04-01

    We report on a computational modeling study of small scale plasma discharge formation with rectangular dielectric resonators (DR). An array of rectangular dielectric slabs, separated by a gap of millimeter dimensions is used to provide resonant response when illuminated by an incident wave of 1.26 GHz. A coupled electromagnetic (EM) wave–plasma model is used to describe the breakdown, early response and steady state of the argon discharge. We characterize the plasma generation with respect to the input power, background gas pressure and gap size. It is found that the plasma discharge is generated mainly inside the gaps between the DR at positions that correspond to the antinodes of the resonant enhanced electric field pattern. The enhancement of the electric field inside the gaps is due to a combination of leaking and displacement current radiation from the DR. The plasma is sustained in over-critical densities due to the large skin depth with respect to the gap and plasma size. Electron densities are calculated in the order of {10}18{--}{10}19 {{{m}}}-3 for a gas pressure of 10 Torr, while they exceed 1020 {{{m}}}-3 in atmospheric conditions. Increase of input power leads to more intense ionization and thus faster plasma formation and results to a more symmetric plasma pattern. For low background gas pressure the discharge is diffusive and extends away from the gap region while in high pressure it is constricted inside the gap. An optimal gap size can be found to provide maximum EM energy transfer to the plasma. This fact demonstrates that the gap size dictates to a certain extent the resonant frequency and the Q-factor of the dielectric array and the breakdown fields can not be determined in a straight-forward way but they are functions of the resonators geometry and incident field frequency.

  2. Novel Composite Hydrogen-Permeable Membranes for Non-Thermal Plasma Reactors for the Decomposition of Hydrogen Sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Morris D. Argyle; John F. Ackerman; Suresh Muknahallipatna; Jerry C. Hamann; Stanislaw Legowski; Guibling Zhao; Ji-Jun Zhang; Sanil John

    2005-10-01

    The goal of this experimental project is to design and fabricate a reactor and membrane test cell to dissociate hydrogen sulfide (H{sub 2}S) in a non-thermal plasma and recover hydrogen (H{sub 2}) through a superpermeable multi-layer membrane. Superpermeability of hydrogen atoms (H) has been reported by some researchers using membranes made of Group V transition metals (niobium, tantalum, vanadium, and their alloys), although it has yet to be confirmed in this study. A pulsed corona discharge (PCD) reactor has been fabricated and used to dissociate H{sub 2}S into hydrogen and sulfur. A nonthermal plasma cannot be produced in pure H{sub 2}S with our reactor geometry, even at discharge voltages of up to 30 kV, because of the high dielectric strength of pure H{sub 2}S ({approx}2.9 times higher than air). Therefore, H{sub 2}S was diluted in another gas with lower breakdown voltage (or dielectric strength). Breakdown voltages of H{sub 2}S in four balance gases (Ar, He, N{sub 2} and H{sub 2}) have been measured at different H{sub 2}S concentrations and pressures. Breakdown voltages are proportional to the partial pressure of H{sub 2}S and the balance gas. H{sub 2}S conversion and the reaction energy efficiency depend on the balance gas and H{sub 2}S inlet concentrations. With increasing H{sub 2}S concentrations, H{sub 2}S conversion initially increases, reaches a maximum, and then decreases. H{sub 2}S conversion in atomic balance gases, such as Ar and He, is more efficient than that in diatomic balance gases, such as N{sub 2} and H{sub 2}. These observations can be explained by the proposed reaction mechanism of H{sub 2}S dissociation in different balance gases. The results show that nonthermal plasmas are effective for dissociating H{sub 2}S into hydrogen and sulfur.

  3. Novel Composite Hydrogen-Permeable Membranes for Non-Thermal Plasma Reactors for the Decomposition of Hydrogen Sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Morris D. Argyle; John F. Ackerman; Suresh Muknahallipatna; Jerry C. Hamann; Stanislaw Legowski; Guibling Zhao; Ji-Jun Zhang; Sanil John

    2005-10-01

    The goal of this experimental project is to design and fabricate a reactor and membrane test cell to dissociate hydrogen sulfide (H{sub 2}S) in a non-thermal plasma and recover hydrogen (H{sub 2}) through a superpermeable multi-layer membrane. Superpermeability of hydrogen atoms (H) has been reported by some researchers using membranes made of Group V transition metals (niobium, tantalum, vanadium, and their alloys), although it has yet to be confirmed in this study. A pulsed corona discharge (PCD) reactor has been fabricated and used to dissociate H{sub 2}S into hydrogen and sulfur. A nonthermal plasma cannot be produced in pure H{sub 2}S with our reactor geometry, even at discharge voltages of up to 30 kV, because of the high dielectric strength of pure H{sub 2}S ({approx}2.9 times higher than air). Therefore, H{sub 2}S was diluted in another gas with lower breakdown voltage (or dielectric strength). Breakdown voltages of H{sub 2}S in four balance gases (Ar, He, N{sub 2} and H{sub 2}) have been measured at different H{sub 2}S concentrations and pressures. Breakdown voltages are proportional to the partial pressure of H{sub 2}S and the balance gas. H{sub 2}S conversion and the reaction energy efficiency depend on the balance gas and H{sub 2}S inlet concentrations. With increasing H{sub 2}S concentrations, H{sub 2}S conversion initially increases, reaches a maximum, and then decreases. H{sub 2}S conversion in atomic balance gases, such as Ar and He, is more efficient than that in diatomic balance gases, such as N{sub 2} and H{sub 2}. These observations can be explained by the proposed reaction mechanism of H{sub 2}S dissociation in different balance gases. The results show that nonthermal plasmas are effective for dissociating H{sub 2}S into hydrogen and sulfur.

  4. Effects of resistivity on linear plasma responses to resonant magnetic perturbations in tokamak plasmas

    Science.gov (United States)

    Kim, Juhyung; Kim, S. S.; Jhang, Hogun

    2016-09-01

    Numerical studies are made of the effects of resistivity on linear plasma responses to resonant magnetic perturbations (RMPs) in tokamaks based on a reduced magnetohydrodynamic model. From a local two-field model, it is suggested that the ratio of the poloidal electron advection to the resistivity diffusion rate α m can be a figure of merit parameter in linear RMP penetration physics. The shielding efficiency is governed by α m , and when α m ≳ 1 , RMPs are effectively shielded. Global simulations using a four-field model [Hazeltine and Meiss, Phys. Rep. 121, 1 (1985)] show that there exists an effective threshold of the perpendicular electron flow ( Ve , ⊥ c ) beyond which RMPs cannot penetrate. Resistivity is found to determine Ve , ⊥ c which increases as resistivity becomes higher, making RMP penetration easier. At low resistivity, small Ve , ⊥ c renders the RMP penetration sensitive to ion collisionality and the change in q95. The kink response is observed to be closely related to the residual level of RMPs at rational surfaces and can be also strongly affected by resistivity.

  5. Inclined slot-excited annular electron cyclotron resonance plasma source for hyperthermal neutral beam generation.

    Science.gov (United States)

    You, H-J; Kim, D-W; Koo, M; Jang, S-O; Jung, Y-H; Hong, S-H; Lee, B-J

    2011-01-01

    An inclined slot-excited antenna (ISLAN) electron cyclotron resonance (ECR) plasma source is newly designed and constructed for higher flux hyperthermal neutral beam (HNB) generation. The developed ISLAN source is modified from vertical slot-excited antenna (VSLAN) source in two aspects: one is the use of inclined slots instead of vertical slots, and the other is a cusp magnetic field configuration rather than a toroidal configuration. Such modifications allow us to have more uniform arrangement of slots and magnets, then enabling plasma generation more uniform and thinner. Moreover, ECR plasma allows higher ionization rate, enabling plasma density higher even in submillitorr pressures, therefore decreasing the collision rate and∕or the reionization rate of the reflected atoms while passing through the plasma, and eventually getting higher flux of HNBs. In this paper, we report the design features and the plasma characteristics of the ISLAN source by doing plasma measurements and electromagnetic simulations. It was found that ISLAN source can be a high potential source for larger flux HNB generation; the source was found to give higher plasma densities and better uniformities than inductively coupled plasma source, particularly in low pressure ranges. Also, it is important that using ISLAN gives easier matching and better stability, i.e., ISLAN shows similar field patterns and good plasma symmetries irrespective of the variations of the mean diameter of the ring resonator and∕or the presence of a limiter or a reflector, and the operating pressures.

  6. The dispersion and matching characteristics of the helical resonator plasma source

    Energy Technology Data Exchange (ETDEWEB)

    Niazi, K.; Lichtenberg, A.J.; Lieberman, M.A. [Univ. of California, Berkeley, CA (United States)

    1995-10-01

    The dispersion characteristics and the fields of a helical resonator are obtained. The coil is approximated by a helical current layer with infinite conductivity along the current direction (a ``sheath helix``). The plasma column is modeled as a cylindrical dielectric in which the dielectric losses can be neglected in determining the propagation properties of the resonator. Assuming the plasma losses are known, the model can be used to study the matching of the helical resonator to an external power source which is connected to the helix by a tap. The resonator is modeled as a parallel connection of two transmission line segments on each side of the tap position. The authors determine the efficiency of power transfer to the resonator as a function of the tap position driving frequency, and plasma loading. They find that whereas for a small plasma loading it is possible to achieve perfect matching, there exists a critical value of plasma loading beyond which a perfect match is no longer possible.

  7. Reduced description of light impurities in hydrogen coronal plasmas

    Directory of Open Access Journals (Sweden)

    D. Kh. Morozov

    2000-01-01

    Full Text Available Se aplica la teor a de impurezas radiativas a plasmas de reactores termonu- cleares, as como a nubes interestelares e intergal acticas, atm osferas estelares y prominencias solares. Las impurezas radiativas son capaces de cambiar la din amica del plasma. Permiten la aparici on de nuevos tipos de equilibrio, de ondas lineales y no-lineales y cambian signi cativamente los criterios de estabilidad. Para una de- scripci on completa de las impurezas, uno necesita un gran conjunto de ecuaciones que describan a cada uno de los estados de ionizaci on. Se muestra que es posible describir impurezas ligeras, con exactitud aceptable, con s olo dos o tres estados representativos de ionizaci on. Se muestra que la descripci on de cinco estados puede reducirse a uno de tres estados de ionizaci on. Se propone un modelo reducido para impurezas ligeras o para impurezas pesadas altamente ionizadas en plasmas coro- nales. Esto permite obtener soluciones anal ticas en muchos casos, reduciendo los tiempos de c omputo. Se deriva un conjunto de ecuaciones simples para determinar la din amica de la distribuci on de impurezas en los diferentes estados de ionizaci on.

  8. Coherent and incoherent Thomson scattering on an argon/hydrogen microwave plasma torch with transient behaviour

    Science.gov (United States)

    Obrusník, A.; Synek, P.; Hübner, S.; van der Mullen, J. J. A. M.; Zajíčková, L.; Nijdam, S.

    2016-10-01

    A new method of processing time-integrated coherent Thomson scattering spectra is presented, which provides not only the electron density and temperature but also information about the transient behaviour of the plasma. Therefore, it is an alternative to single-shot Thomson scattering measurements as long as the scattering is coherent. The method is applied to a microwave plasma torch operating in argon or a mixture of argon with hydrogen at atmospheric pressure. Electron densities up to 8\\cdot {{10}21} m-3 (ionization degree above 10-3) were observed, which is more than two times higher than presented in earlier works on comparable discharges. Additionally, a parametric study with respect to the argon/hydrogen ratio and the input power was carried out and the results are discussed together with earlier Stark broadening measurements on the same plasma.

  9. Renormalization shielding and eikonal analysis on the atomic collision in dense partially ionized hydrogen plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sung Soo [Department of Applied Mathematics, Hanyang University, Ansan, Kyunggi-Do 426-791 (Korea, Republic of); Jung, Young-Dae [Department of Applied Physics and Department of Bionanotechnology, Hanyang University, Ansan, Kyunggi-Do 426-791 (Korea, Republic of); Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, 110 Eighth Street, Troy, New York 12180-3590 (United States)

    2013-12-15

    The renormalization plasma screening effects on the electron-ion collision are investigated in dense partially ionized hydrogen plasmas. The Hamilton-Jacobi and eikonal methods with the effective interaction potential are employed to obtain the eikonal scattering phase shift and eikonal cross section for the electron-ion collision. It is found that the influence of renormalization screening strongly suppresses the eikonal scattering phase shift as well as the eikonal cross section, especially, for small impact parameter regions. In addition, the renormalization screening effect reduces the total eikonal cross section in all energy domains. The variation of the renormalization effects on the electron-ion collision in dense partially ionized hydrogen plasmas is also discussed.

  10. Multicusp type machine for electron cyclotron resonance plasma with reduced dimensions

    Science.gov (United States)

    Amemiya, H.; Maeda, M.

    1996-03-01

    Plasmas are created in a cusp type magnetic trap using electron cyclotron resonance heating. The magnetic field is generated with permanent magnets forming a 12-pole, whereby the polarity at the ends of the rods has been reversed in order to obtain end plugs and to improve the plasma confinement. In this way, the plasma volume could be reduced such that the cross section was close to or smaller than the cutoff width of a circular waveguide. This increases the microwave power absorbed and gives a high plasma density even above the cutoff value.

  11. Multicusp type machine for electron cyclotron resonance plasma with reduced dimensions

    Energy Technology Data Exchange (ETDEWEB)

    Amemiya, H.; Maeda, M. [The Institute of Physical and Chemical Research (RIKEN), Hirosawa 2-1, Wako-shi, Saitama-Pref., 351-01 (Japan)

    1996-03-01

    Plasmas are created in a cusp type magnetic trap using electron cyclotron resonance heating. The magnetic field is generated with permanent magnets forming a 12-pole, whereby the polarity at the ends of the rods has been reversed in order to obtain end plugs and to improve the plasma confinement. In this way, the plasma volume could be reduced such that the cross section was close to or smaller than the cutoff width of a circular waveguide. This increases the microwave power absorbed and gives a high plasma density even above the cutoff value. {copyright} {ital 1996 American Institute of Physics.}

  12. Resonance between heat-carrying electrons and Langmuir waves in inertial confinement fusion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Rozmus, W. [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2G7 (Canada); Chapman, T.; Berger, R. L. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Brantov, A.; Bychenkov, V. Yu. [P.N. Lebedev Physics Institute, Russian Academy of Sciences, Moscow 119991 Russia and Center for Fundamental and Applied Research, VNIIA, ROSATOM, 127055 Moscow (Russian Federation); Winjum, B. J. [Department of Electrical Engineering, UCLA, Los Angeles, California 90095 (United States); Brunner, S. [Association EURATOM-Confederation Suisse, EPFL, 1015 Lausanne (Switzerland); Tableman, A.; Tzoufras, M. [Department of Physics and Astronomy, UCLA, Los Angeles, California 90095 (United States); Glenzer, S. [LCLS, Stanford, California 94025 (United States)

    2016-01-15

    In ignition scale hot plasmas, temperature gradients and thermal transport modify electron distributions in a velocity range resonant with Langmuir waves typical of those produced by stimulated Raman scattering. We examine the resultant changes to the Landau damping experienced by these Langmuir waves and the levels of thermal plasma fluctuations. The form factor and Thomson scattering cross-section in such plasmas display unique characteristics of the background conditions. A theoretical model and high-order Vlasov-Fokker-Planck simulations are used in our analysis. An experiment to measure changes in thermal plasma fluctuation levels due to a thermal gradient is proposed.

  13. Ionization cross section of partially ionized hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Baimbetov, F B; Kudyshev, Z A [Department of Physics, al - Farabi Kazakh National University, Almaty (Kazakhstan)], E-mail: Bfb77@kazsu.kz, E-mail: Z.Kudyshev@mail.ru

    2008-05-01

    In present work the electron impact ionization cross section is considered. The electron impact ionization cross section is calculated, based on pseudopotential model of interaction between plasma particles which accounts correlation effects. It is calculated with help of two methods: classical and quantum - mechanical (Born approximation). The ionization cross section is compared with corresponding results of other authors and experimental data. It has been shown that it is very important to take into account an influence of the surrounding during consideration of ionization processes.

  14. Recent Advances on Hydrogenic Retention in ITER's Plasma-Facing Materials: BE, C, W.

    Energy Technology Data Exchange (ETDEWEB)

    Skinner, C H; Alimov, Kh; Bekris, N; Causey, R A; Clark, R.E.H.; Coad, J P; Davis, J W; Doerner, R P; Mayer, M; Pisarev, A; Roth, J

    2008-03-29

    Management of tritium inventory remains one of the grand challenges in the development of fusion energy and the choice of plasma-facing materials is a key factor for in-vessel tritium retention. The Atomic and Molecular Data Unit of the International Atomic Energy Agency organized a Coordinated Research Project (CRP) on the overall topic of tritium inventory in fusion reactors during the period 2001-2006. This dealt with hydrogenic retention in ITER's plasma-facing materials, Be, C, W, and in compounds (mixed materials) of these elements as well as tritium removal techniques. The results of the CRP are summarized in this article together with recommendations for ITER. Basic parameters of diffusivity, solubility and trapping in Be, C and W are reviewed. For Be, the development of open porosity can account for transient hydrogenic pumping but long term retention will be dominated by codeposition. Codeposition is also the dominant retention mechanism for carbon and remains a serious concern for both Be and C containing layers. Hydrogenic trapping in unirradiated tungsten is low but will increase with ion and neutron damage. Mixed materials will be formed in a tokamak and these can also retain significant amounts of hydrogen isotopes. Oxidative and photon-based techniques for detritiation of plasma-facing components are described.

  15. Helium-3 Generation from the Interaction of Deuterium Plasma inside a Hydrogenated Lattice: Red Fusion

    Science.gov (United States)

    Leal-Quiros, Edbertho; Leal-Escalante, David A.

    2015-03-01

    Helium-3 has been created in a nuclear fusion reaction by fusing deuterium ions from deuterium plasma with hydrogen ions in a “RED” (the Spanish word for net) or crystal lattice, a method we called red fusion ("Fusion en la red cristalina"), because is a new method to make nuclear fusion reaction. In this paper, it will be show the experimental results where the helium-3 has been generated for the first time in this kind of new method to confine deuterium and hydrogen inside the RED or lattice of the hydrogenated crystal and that confinement inside the RED facilitated overcoming the Coulomb barrier between them and helium-3 and phonons are produced in this fusion reaction. The results of a long time research in which helium-3, has been created in a fusion reaction inside the lattice or RED of the crystal that contained hydrogen after adequate interaction of deuterium plasma at appropriate high temperature and magnetic confinement of the Mirror/Cusp Plasma Machine at Polytechnic University of Puerto Rico, designed by the authors. Several mass spectra and visible light spectrum where the presence of helium-3 was detected are shown. The experiment was repeated more than 200 times showing always the generation of helium-3. In this experiment no gamma rays were detected. For this experiment several diagnostic instruments were used. The data collection with these control instrumentation are shown. Thus, it is an important new way to generate Helium-3. reserved.

  16. Uncertainty propagation in modeling of plasma-assisted hydrogen production from biogas

    Science.gov (United States)

    Zaherisarabi, Shadi; Venkattraman, Ayyaswamy

    2016-10-01

    With the growing concern of global warming and the resulting emphasis on decreasing greenhouse gas emissions, there is an ever-increasing need to utilize energy-production strategies that can decrease the burning of fossil fuels. In this context, hydrogen remains an attractive clean-energy fuel that can be oxidized to produce water as a by-product. In spite of being an abundant species, hydrogen is seldom found in a form that is directly usable for energy-production. While steam reforming of methane is one popular technique for hydrogen production, plasma-assisted conversion of biogas (carbon dioxide + methane) to hydrogen is an attractive alternative. Apart from producing hydrogen, the other advantage of using biogas as raw material is the fact that two potent greenhouse gases are consumed. In this regard, modeling is an important tool to understand and optimize plasma-assisted conversion of biogas. The primary goal of this work is to perform a comprehensive statistical study that quantifies the influence of uncertain rate constants thereby determining the key reaction pathways. A 0-D chemical kinetics solver in the OpenFOAM suite is used to perform a series of simulations to propagate the uncertainty in rate constants and the resulting mean and standard deviation of outcomes.

  17. Kinetic modeling and experimental studies of hydrogen production by non-equilibrium plasma discharge decomposition of methane and other hydrogen-containing species

    Energy Technology Data Exchange (ETDEWEB)

    Boutot, T.; Liu, Z. [Atlantic Hydrogen Inc., Fredericton, NB (Canada); Whidden, T.K.; Yang, Y. [New Brunswick Univ., Fredericton, NB (Canada)

    2007-07-01

    Hydrogen as an energy source is an option that is being explored in order to reduce anthropogenic greenhouse gas (GHG) emissions. In particular, proton exchange membrane (PEM) fuel cells using hydrogen and emitting no GHGs are under global development. The long-term production process of choice is hydrogen derived directly from water. However, hydrogen from electrolysis is not economically viable and bridging technologies for green hydrogen production must be found. Any new technology for hydrogen production should also accommodate the fact that no infrastructure for the widespread distribution of pure hydrogen exists. Hydrogen production technologies that leverage existing infrastructure for delivery will therefore have a significant economic advantage. This paper described the anaerobic high frequency pulsed plasma pyrolysis of methane using a proprietary reactor system. The paper discussed modeling studies and progress in scaling this reactor to pilot scale operation. It also discussed several experiments on using the system for the dissociation of another hydrogen source, hydrogen sulphide (H2{sub S}). Hydrogen and solid carbon were produced for methane or natural gas as the feedstock. The prototype bench-scale process was scaled to near pilot-scale, treating significant flows of natural gas. Long term data on system performance at conversions producing 20 per cent hydrogen in natural gas as the product were presented. Chemical kinetic models for the dissociation process and characterizational data for the solid carbon product were presented. 48 refs., 2 tabs., 9 figs.

  18. Resonance-like structure for soliton characteristics in an electron beam-plasma system

    Energy Technology Data Exchange (ETDEWEB)

    Gell, Y.; Nakach, R.

    1978-08-01

    The characteristics of ion acoustic solitons in an electron beam-plasma system are considered. The dependence of the amplitude of the soliton on the density of the beam electrons is found to exhibit a pronounced resonance-like structure. A numerical analysis of the analytic expressions for the soliton characteristics (amplitude and width) is performed for different values of the relevant parameters of the system. The existence and origin of the resonance structure is discussed.

  19. Efficient new process for the desulfurization of mixtures of air and hydrogen sulfide via a dielectric barrier discharge plasma

    Directory of Open Access Journals (Sweden)

    S. Dahle

    2015-10-01

    Full Text Available The efficient removal of hydrogen sulfide, H2S, from streams of H2S in air via a dielectric barrier discharge (DBD plasma has been investigated using a quadrupole mass spectrometer. A suitable plasma device with a reservoir for storing sorbent powder of various kinds within the plasma region was constructed. Plasma treatments of gas streams with high concentrations of hydrogen sulfide in air yielded a removal of more than 98% of the initial hydrogen sulfide and a deposition of sulfur at the surface of the dielectric, while small amounts of sulfur dioxide were generated. The presence of calcium carbonate within the plasma region of the DBD device resulted in the removal of over 99% of the initial hydrogen sulfide content and the removal of 98% of the initial sulfur dioxide impurities from the gas mixture.

  20. Nonlinear resonant absorption of fast magnetoacoustic waves in strongly anisotropic and dispersive plasmas

    CERN Document Server

    Clack, C

    2009-01-01

    The nonlinear theory of driven magnetohydrodynamics (MHD) waves in strongly anisotropic and dispersive plasmas, developed for slow resonance by Clack and Ballai [Phys. Plasmas, 15, 2310 (2008)] and Alfv\\'en resonance by Clack \\emph{et al.} [A&A,494, 317 (2009)], is used to study the weakly nonlinear interaction of fast magnetoacoustic (FMA) waves in a one-dimensional planar plasma. The magnetic configuration consists of an inhomogeneous magnetic slab sandwiched between two regions of semi-infinite homogeneous magnetic plasmas. Laterally driven FMA waves penetrate the inhomogeneous slab interacting with the localized slow or Alfv\\'{e}n dissipative layer and are partly reflected, dissipated and transmitted by this region. The nonlinearity parameter defined by Clack and Ballai (2008) is assumed to be small and a regular perturbation method is used to obtain analytical solutions in the slow dissipative layer. The effect of dispersion in the slow dissipative layer is to further decrease the coefficient of ener...

  1. Influence of external resonant magnetic perturbation field on edge plasma of small tokamak HYBTOK-II

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, Y., E-mail: hayashi-yuki13@ees.nagoya-u.ac.jp [Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603 (Japan); Suzuki, Y.; Ohno, N. [Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603 (Japan); Okamoto, M. [Ishikawa National College of Technology, Kitachujo, Tsubata-cho, Kahoku-gun, Ishikawa 929-0392 (Japan); Kikuchi, Y. [University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280 (Japan); Sakakibara, S.; Watanabe, K.; Takemura, Y. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki, Gifu 509-5292 (Japan)

    2015-08-15

    Radial profile of externally applied resonant magnetic perturbation (RMP) field with mode numbers of m = 6 and n = 2 in a small tokamak device HYBTOK-II have been investigated using a magnetic probe array, which is able to measure the radial profile of magnetic field perturbation induced by applying RMP. Results of RMP penetration into the plasma show that the RMP decreased toward the plasma center, while they were amplified around the resonant surface with a safety factor q = 3 due to the formation of magnetic islands. This suggests that RMP fields for controlling edge plasmas may trigger some kind of MHD instabilities. In addition, simulation results, based on a linearized four-field model, which agrees with the experimental ones, indicates that the penetration and amplification process of RMP strongly depend on a Doppler-shifted frequency between the RMP and plasma rotation.

  2. Investigation of the resonance frequency and performance of a partially plasma filled reconfigurable cylindrical TE111 mode cavity

    Science.gov (United States)

    Hadaegh, Mostafa; Mohajeri, Farzad

    2017-05-01

    A partially plasma filled reconfigurable cylindrical cavity is proposed. Plasma offers an encouraging alternative to metal for a wide variety of microwave engineering applications. Implementation of a low-cost plasma element permits the resonant frequency to be changed electrically. The level of the resonant frequency shifts toward the empty-cavity resonant frequency and depends on certain parameters, such as the plasma diameter, relative permittivity and thickness of the plasma tube. In this article, we first introduce the partially plasma filled reconfigurable cylindrical cavity; then, the resonant frequency equation of the cavity is obtained by variational methods. Finally, we plot the resonant frequency versus different parameters of the cavity, which we compare with the results of the CST software. We show that the two results are compatible with each other.

  3. Electromagnetic, complex image model of a large area RF resonant antenna as inductive plasma source

    Science.gov (United States)

    Guittienne, Ph; Jacquier, R.; Howling, A. A.; Furno, I.

    2017-03-01

    A large area antenna generates a plasma by both inductive and capacitive coupling; it is an electromagnetically coupled plasma source. In this work, experiments on a large area planar RF antenna source are interpreted in terms of a multi-conductor transmission line coupled to the plasma. This electromagnetic treatment includes mutual inductive coupling using the complex image method, and capacitive matrix coupling between all elements of the resonant network and the plasma. The model reproduces antenna input impedance measurements, with and without plasma, on a 1.2× 1.2 m2 antenna used for large area plasma processing. Analytic expressions are given, and results are obtained by computation of the matrix solution. This method could be used to design planar inductive sources in general, by applying the termination impedances appropriate to each antenna type.

  4. Multicusp type electron cyclotron resonance plasma with arrangement of permanent magnets

    Energy Technology Data Exchange (ETDEWEB)

    Amemiya, H.; Maeda, M. [Institute of Physical and Chemical Research, Wako, Saitama (Japan)

    1995-09-01

    ECR (electron cyclotron resonance) plasmas are generated in a multicusp field of 12-pole formed by permanent magnets, where the polarity of the magnetic field at the end sections is reversed to reflect axially drifting electrons as in the mirror field. Furthermore, the radius of multicusp is contracted below the cut-off radius of the waveguide in vacuum. This is effective in increasing the microwave power absorbed in the plasma and the ion density. (author).

  5. Amorphous hydrogenated carbon films treated by SF{sub 6} plasma

    Energy Technology Data Exchange (ETDEWEB)

    Marins, N M S; Mota, R P; Santos, D C R; Honda, R Y; Kayama, M E; Kostov, K G; Algatti, M A [Laboratorio de Plasma, Faculdade de Engenharia, UNESP, Av. Dr. Ariberto Pereira da Cunha-333, 12516-410, Guaratingueta, SP (Brazil); Cruz, N C; Rangel, E C, E-mail: nazir@feg.unesp.b [Laboratorio de Plasmas Tecnologicos, Unidade Diferenciada Sorocaba/Ipero, UNESP, Av. Tres de Marco-511, 18085-180, Sorocaba, SP (Brazil)

    2009-05-01

    This work was performed to verify the chemical structure, mechanical and hydrophilic properties of amorphous hydrogenated carbon films prepared by plasma enhanced chemical vapor deposition, using acetylene/argon mixture as monomer. Films were prepared in a cylindrical quartz reactor, fed by 13.56 MHz radiofrequency. The films were grown during 5 min, for power varying from 25 to 125 W at a fixed pressure of 9.5 Pa. After deposition, all samples were treated by SF{sub 6} plasma with the aim of changing their hydrophilic character. Film chemical structure investigated by Raman spectroscopy, revealed the increase of sp{sup 3} hybridized carbon bonds as the plasma power increases. Hardness measurements performed by the nanoindentation technique showed an improvement from 5 GPa to 14 GPa following the increase discharge power. The untreated films presented a hydrophilic character, which slightly diminished after SF{sub 6} plasma treatment.

  6. Limitations of electron cyclotron resonance ion source performances set by kinetic plasma instabilities.

    Science.gov (United States)

    Tarvainen, O; Laulainen, J; Komppula, J; Kronholm, R; Kalvas, T; Koivisto, H; Izotov, I; Mansfeld, D; Skalyga, V

    2015-02-01

    Electron cyclotron resonance ion source (ECRIS) plasmas are prone to kinetic instabilities due to anisotropy of the electron energy distribution function stemming from the resonant nature of the electron heating process. Electron cyclotron plasma instabilities are related to non-linear interaction between plasma waves and energetic electrons resulting to strong microwave emission and a burst of energetic electrons escaping the plasma, and explain the periodic oscillations of the extracted beam currents observed in several laboratories. It is demonstrated with a minimum-B 14 GHz ECRIS operating on helium, oxygen, and argon plasmas that kinetic instabilities restrict the parameter space available for the optimization of high charge state ion currents. The most critical parameter in terms of plasma stability is the strength of the solenoid magnetic field. It is demonstrated that due to the instabilities the optimum Bmin-field in single frequency heating mode is often ≤0.8BECR, which is the value suggested by the semiempirical scaling laws guiding the design of modern ECRISs. It is argued that the effect can be attributed not only to the absolute magnitude of the magnetic field but also to the variation of the average magnetic field gradient on the resonance surface.

  7. Limitations of electron cyclotron resonance ion source performances set by kinetic plasma instabilities

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, O., E-mail: olli.tarvainen@jyu.fi; Laulainen, J.; Komppula, J.; Kronholm, R.; Kalvas, T.; Koivisto, H. [Department of Physics, University of Jyväskylä, 40500 Jyväskylä (Finland); Izotov, I.; Mansfeld, D. [Institute of Applied Physics, RAS, 46 Ul‘yanova St., 603950 Nizhny Novgorod (Russian Federation); Skalyga, V. [Institute of Applied Physics, RAS, 46 Ul‘yanova St., 603950 Nizhny Novgorod (Russian Federation); Lobachevsky State University of Nizhny Novgorod (UNN), 23 Gagarina St., 603950 Nizhny Novgorod (Russian Federation)

    2015-02-15

    Electron cyclotron resonance ion source (ECRIS) plasmas are prone to kinetic instabilities due to anisotropy of the electron energy distribution function stemming from the resonant nature of the electron heating process. Electron cyclotron plasma instabilities are related to non-linear interaction between plasma waves and energetic electrons resulting to strong microwave emission and a burst of energetic electrons escaping the plasma, and explain the periodic oscillations of the extracted beam currents observed in several laboratories. It is demonstrated with a minimum-B 14 GHz ECRIS operating on helium, oxygen, and argon plasmas that kinetic instabilities restrict the parameter space available for the optimization of high charge state ion currents. The most critical parameter in terms of plasma stability is the strength of the solenoid magnetic field. It is demonstrated that due to the instabilities the optimum B{sub min}-field in single frequency heating mode is often ≤0.8B{sub ECR}, which is the value suggested by the semiempirical scaling laws guiding the design of modern ECRISs. It is argued that the effect can be attributed not only to the absolute magnitude of the magnetic field but also to the variation of the average magnetic field gradient on the resonance surface.

  8. Analytical investigation of microwave resonances of a curling probe for low and high-pressure plasma diagnostics

    Science.gov (United States)

    Arshadi, Ali; Brinkmann, Ralf Peter

    2017-01-01

    The concept of ‘active plasma resonance spectroscopy’ (APRS) has attracted greater interest in recent years as an established plasma diagnostic technique. The APRS describes a class of related methods utilizing the intrinsic ability of plasma to resonate at or near the electron plasma frequency {ω\\text{pe}} . The Curling probe (CP) as a novel realization of the APRS idea, is a miniaturized spiral slot embedded flatly in the chamber wall. Consequently, a plasma diagnostic technique with minimum disturbance and without metal contamination can be developed. To measure the plasma parameters the CP is fed with a weak frequency-swept signal from the exterior of the plasma chamber by a network analyzer which also records the response of the plasma versus the frequency. The resonance behavior is strongly dependent on the electron density and the gas pressure. The CP has also the advantage of resonating at a frequency greater than {ω\\text{pe}} which is dependent on the spiral’s length. The double resonance characteristic gives the CP the ability to be applied in varying plasma regimes. Assuming that the spiralization does not have a considerable effect on the resonances, a ‘straightened’ infinite length CP has recently been investigated (Arshadi and Brinkmann 2016 Plasma Sources Sci. Technol. 25 045014) to obtain the surface wave resonances. This work generalizes the approach and models the CP by a rectangular slot-type resonator located between plasma and quartz. Cold plasma theory and Maxwell’s equations are utilized to compute the electromagnetic fields propagating into the plasma by the diffraction of an incident plane wave at the slot. A mathematical model is employed and both kinds of resonances are derived. The analytical study of this paper shows good agreement with the numerical results of the probe inventors.

  9. The effect of biasing the plasma electrode on hydrogen ion formations in a multicusp ion source

    Energy Technology Data Exchange (ETDEWEB)

    Ego, Hiroyasu; Iwashita, Yoshihisa (Kyoto Univ., Uji (Japan). Inst. for Chemical Research); Takekoshi, Hidekuni

    1992-03-01

    The plasma electrode covered with magnetic cusp fields acting as a magnetic filter was installed in a multicusp ion source. The formation processes of the negative and positive hydrogen ions in this source have been investigated when an electrostatic positive bias is applied to the plasma electrode with respect to the anode chamber. The dominant H[sup -] volume-production process is the recombinational attachment rather than the dissociative attachment when the bias voltage is more than +3V. This recombinational attachment improves the H[sup +] ratio in the extracted positive beam, keeping its current value. (author) 52 refs.

  10. The effect of a hydrogen plasma on the diamond (110) surface

    Science.gov (United States)

    Mercer, Thomas W.; Russell, John N.; Pehrsson, Pehr E.

    1997-12-01

    Hydrogen plasma processing has become a valuable method for generating smooth C(100) and C(111) surfaces. Herein, the generality of the method is examined by applying it to the C(110) surface. Using scanning force microscopy (SFM) and low energy electron diffraction (LEED), it is found that plasma conditions appropriate for smoothing C(100) and C(111) result in (111) faceted pits on the C(110) surface. LEED indicates that a freshly polished C(110) surface also consists of (111) facets despite its optically smooth appearance.

  11. Hydrogen Plasma Durability of Chemically Treated SnO2 Thin Films

    Science.gov (United States)

    Kawabata, Keishi; Tanaka, Takeshi; Hirose, Masataka

    1993-10-01

    The chemical stability of SnO2 surfaces against hydrogen plasma exposure has been studied by treating a SnO2/glass system either in steam at a substrate temperature of 200 and 400°C or in ethyl alcohol at 200 and 400°C, or by fluorinating the surface at 400°C in an NF3+O2 gas mixture. Also, an electroplated Zn layer on SnO2 has been oxidized at 400°C. X-ray photoelectron spectroscopy of such surfaces has revealed that the reduction reaction of the SnO2 surface exposed to hydrogen plasma is dramatically suppressed by the steam treatment at 400°C.

  12. Laser plasma ion implantation and deposition of platinum for SiC-based hydrogen detector fabrication

    Energy Technology Data Exchange (ETDEWEB)

    Fominski, V. Yu., E-mail: vyfominskij@mephi.ru [National Research Nuclear University MEPhI, Kashirskoe sh., 31, Moscow 115409 (Russian Federation); Grigoriev, S.N. [Moscow State University of Technology STANKIN, Vadkovskii per., 3a, Moscow 127005 (Russian Federation); Romanov, R.I. [National Research Nuclear University MEPhI, Kashirskoe sh., 31, Moscow 115409 (Russian Federation); Gnedovets, A.G. [Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Leninsky Prospect 49, Moscow 119991 (Russian Federation); Chernykh, P.N. [Lomonosov Moscow State University Scobeltsyn Institute of Nuclear Physics, 1(2) Leninskie Gory, GSP-1, Moscow 119991 (Russian Federation)

    2013-10-15

    Highlights: •Pt ion implantation and film deposition were carried out using pulsed laser plume. •Experimental diagnostics and modeling of Pt ion implantation in SiC were performed. •Mechanism of Pt depth distribution in SiC substrate was determined. •Layered structure of Pt on Pt-doped SiC crystal was used to detect hydrogen at 500 °C. •The response of sensor to hydrogen was pronounced and stable after long-term tests. -- Abstract: A pulsed plasma plume obtained by pulsed laser irradiation of a Pt target was used to fabricate a hydrogen sensor on a 6H–SiC single crystal by means of ion implantation followed by thin film deposition. To realize the ion implantation, high voltage pulses with positive polarity were applied to the Pt target when the laser plasma expanded from the target to the SiC substrate. Experimental diagnostics of pulsed ion beams extracted from laser-produced plasma were performed and the structure of the SiC crystal after high-temperature (500 °C) ion implantation was studied by Rutherford backscattering spectroscopy of {sup 4}He{sup +} ions. At the same time, a one-dimensional model of the plasma movement in a pulsed electric field was developed and simulations were carried out using the particle-in-cell method. Modeling allowed determination of the ion energy distribution depending on the delay time of the high voltage pulse after the laser pulse. The calculated energy distribution of Pt ions was used to predict the depth profile of implanted Pt ions in the SiC substrate. The predicted profile agreed sufficiently well with the experimentally measured depth distribution of Pt in the SiC substrate. To characterize the fabricated SiC sensor, the current flow through a barrier structure was studied. The volt–ampere characteristics of the structure were measured in air and in a mixture of air and hydrogen (2%) at a temperature of 500 °C. The characteristic value of the change in voltage exceeded 2 V at the bias current of 1 mA when

  13. Novel Composite Hydrogen-Permeable Membranes for Non-Thermal Plasma Reactors for the Decomposition of Hydrogen Sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Morris D. Argyle; John F. Ackerman; Suresh Muknahallipatna; Jerry C. Hamann; Stanislaw Legowski; Guibing Zhao; Sanil John

    2006-09-30

    The goal of this experimental project is to design and fabricate a reactor and membrane test cell to dissociate hydrogen sulfide (H{sub 2}S) in a non-thermal plasma and recover hydrogen (H{sub 2}) through a superpermeable multi-layer membrane. Superpermeability of hydrogen atoms (H) has been reported by some researchers using membranes made of Group V transition metals (niobium, tantalum, vanadium, and their alloys), although it has yet to be confirmed in this study. Several pulsed corona discharge (PCD) reactors have been fabricated and used to dissociate H{sub 2}S into hydrogen and sulfur. Visual observation shows that the corona is not uniform throughout the reactor. The corona is stronger near the top of the reactor in argon, while nitrogen and mixtures of argon or nitrogen with H{sub 2}S produce stronger coronas near the bottom of the reactor. Both of these effects appear to be explainable base on the different electron collision interactions with monatomic versus polyatomic gases. A series of experiments varying reactor operating parameters, including discharge capacitance, pulse frequency, and discharge voltage were performed while maintaining constant power input to the reactor. At constant reactor power input, low capacitance, high pulse frequency, and high voltage operation appear to provide the highest conversion and the highest energy efficiency for H{sub 2}S decomposition. Reaction rates and energy efficiency per H{sub 2}S molecule increase with increasing flow rate, although overall H{sub 2}S conversion decreases at constant power input. Voltage and current waveform analysis is ongoing to determine the fundamental operating characteristics of the reactors. A metal infiltrated porous ceramic membrane was prepared using vanadium as the metal and an alumina tube. Experiments with this type of membrane are continuing, but the results thus far have been consistent with those obtained in previous project years: plasma driven permeation or superpermeability

  14. Steam Reforming of Dimethyl Ether by Gliding Arc Gas Discharge Plasma for Hydrogen Production

    Institute of Scientific and Technical Information of China (English)

    王保伟; 孙启梅; 吕一军; 杨美琳; 闫文娟

    2014-01-01

    Gliding arc gas discharge plasma was used for the generation of hydrogen from steam reforming of di-methyl ether (DME). A systemic procedure was employed to determine the suitable experimental conditions. It was found that DME conversion first increased up to the maximum and then decreased slightly with the increase of added water and air. The increase of total feed gas flow rate resulted in the decrease of DME conversion and hy-drogen yield, but hydrogen energy consumption dropped down to the lowest as total feed gas flow rate increased to 76 ml·min-1. Larger electrode gap and higher discharge voltage were advantageous. Electrode shape had an impor-tant effect on the conversion of DME and production of H2. Among the five electrodes, electrode 2# with valid length of 55 mm and the radian of 34 degrees of the top electrode section was the best option, which enhanced ob-viously the conversion of DME.

  15. Demonstration of resonant backward Raman amplification in high-density gas-jet plasma

    Science.gov (United States)

    Wu, Z. H.; Zhou, K. N.; Zheng, X. M.; Wei, X. F.; Zhu, Q. H.; Su, J. Q.; Xie, N.; Jiao, Z. H.; Peng, H.; Wang, X. D.; Sun, L.; Li, Q.; Huang, Z.; Zuo, Y. L.

    2016-10-01

    Backward Raman amplification was observed in a 0.7 mm-long high-density gas jet plasma. The 800 nm 30 fs seed pulse was amplified by a factor  ∼28, with an output energy of 2.8 mJ. The output spectra showed that the waveband around 800 nm was significantly amplified. The experimental result demonstrated that the resonant Raman amplification can be realized in high-density plasma against strong plasma instability.

  16. Fullerene-rare gas mixed plasmas in an electron cyclotron resonance ion source

    CERN Document Server

    Asaji, T; Uchida, T; Minezaki, H; Ishihara, S; Racz, R; Muramatsu, M; Biri, S; Kitagawa, A; Kato, Y; Yoshida, Y

    2015-01-01

    A synthesis technology of endohedral fullerenes such as Fe@C60 has developed with an electron cyclotron resonance (ECR) ion source. The production of N@C60 was reported. However, the yield was quite low, since most fullerene molecules were broken in the ECR plasma. We have adopted gas-mixing techniques in order to cool the plasma and then reduce fullerene dissociation. Mass spectra of ion beams extracted from fullerene-He, Ar or Xe mixed plasmas were observed with a Faraday cup. From the results, the He gas mixing technique is effective against fullerene destruction.

  17. Experimental Study of Plasma Under-liquid Electrolysis in Hydrogen Generation

    Institute of Scientific and Technical Information of China (English)

    严宗诚; 陈砺; 王红林

    2006-01-01

    The application and characteristics of relatively big volume plasma produced with cathodic glow discharges taking place across a gaseous envelope over the cathode which was dipped into electrolyte in hydrogen generation were studied. A critical investigation of the influence of methanol concentration and voltage across the circuit on the composition and power consumption per cubic meter of cathode liberating gas was carried out. The course of plasma under-liquid electrolysis has the typical characteristics of glow discharge electrolysis. The cathode liberating gas was in substantial excess of the Faraday law value. When the voltage across the circuit was equal to 550 V, the volume of cathodic gas with sodium carbonate solution was equal to 16.97 times the Faraday law value. The study showed that methanol molecules are more active than water molecules.The methanol molecules were decomposed at the plasma-catholyte interface by the radicals coming out the plasma mantle.Energy consumption per cubic meter of cathodic gases (WV) decreased while methanol concentration of the electrolytes increased. When methanol concentration equaled 5% (ψ), WV was 10.381×103 kJ/m3, less than the corresponding theoretic value of conventional water electrolysis method. The cathodic liberating gas was a mixture of hydrogen, carbon dioxide and carbon monoxide with over 95% hydrogen, if methanol concentration was more than 15% (ψ). The present research work revealed an innovative application of glow discharge and a new highly efficient hydrogen generation method, which depleted less resource and energy than normal electrolysis and is environmentally friendly.

  18. Methane Coupling Using Hydrogen Plasma and Pt/γ-Al2O3 Catalyst

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    In this paper, methane coupling at ambient temperature, under atmospheric pressure and in the presence of hydrogen was firstly investigated by using pulse corona plasma and Pt/γ-Al2O3 catalyst. Experimental results showed that Pt/γ-Al2O3 catalyst has catalytic activity for methane coupling to C2H4. Over sixty percent of outcomes of C2 hydrocarbons were detected to be ethylene.

  19. On RF heating of inhomogeneous collisional plasma under ion-cyclotron resonance conditions

    Energy Technology Data Exchange (ETDEWEB)

    Timofeev, A. V., E-mail: Timofeev-AV@nrcki.ru [Kurchatov Institute (Russian Federation)

    2015-11-15

    During ion-cyclotron resonance (ICR) heating of plasma by the magnetic beach method, as well as in some other versions of ICR heating, it is necessary to excite Alfvén oscillations. In this case, it is difficult to avoid the phenomenon of the Alfvén resonance, in which Alfvén oscillations transform into lower hybrid oscillations. The latter efficiently interact with electrons, due to which most of the deposited RF energy is spent on electron (rather than ion) heating. The Alfvén resonance takes place due to plasma inhomogeneity across the external magnetic field. Therefore, it could be expected that variations in the plasma density profile would substantially affect the efficiency of the interaction of RF fields with charged particles. However, the results obtained for different plasma density profiles proved to be nearly the same. In the present work, a plasma is considered the parameters of which correspond to those planned in future ICR plasma heating experiments on the PS-1 facility at the Kurchatov Institute. When analyzing the interaction of RF fields with charged particles, both the collisionless resonance interaction and the interaction caused by Coulomb collisions are taken into account, because, in those experiments, the Coulomb collision frequency will be comparable with the frequency of the heating field. Antennas used for ICR heating excite RF oscillations with a wide spectrum of wavenumbers along the magnetic field. After averaging over the spectrum, the absorbed RF energy calculated with allowance for collisions turns out to be close to that absorbed in collisionless plasma, the energy fraction absorbed by electrons being substantially larger than that absorbed by ions.

  20. On RF heating of inhomogeneous collisional plasma under ion-cyclotron resonance conditions

    Science.gov (United States)

    Timofeev, A. V.

    2015-11-01

    During ion-cyclotron resonance (ICR) heating of plasma by the magnetic beach method, as well as in some other versions of ICR heating, it is necessary to excite Alfvén oscillations. In this case, it is difficult to avoid the phenomenon of the Alfvén resonance, in which Alfvén oscillations transform into lower hybrid oscillations. The latter efficiently interact with electrons, due to which most of the deposited RF energy is spent on electron (rather than ion) heating. The Alfvén resonance takes place due to plasma inhomogeneity across the external magnetic field. Therefore, it could be expected that variations in the plasma density profile would substantially affect the efficiency of the interaction of RF fields with charged particles. However, the results obtained for different plasma density profiles proved to be nearly the same. In the present work, a plasma is considered the parameters of which correspond to those planned in future ICR plasma heating experiments on the PS-1 facility at the Kurchatov Institute. When analyzing the interaction of RF fields with charged particles, both the collisionless resonance interaction and the interaction caused by Coulomb collisions are taken into account, because, in those experiments, the Coulomb collision frequency will be comparable with the frequency of the heating field. Antennas used for ICR heating excite RF oscillations with a wide spectrum of wavenumbers along the magnetic field. After averaging over the spectrum, the absorbed RF energy calculated with allowance for collisions turns out to be close to that absorbed in collisionless plasma, the energy fraction absorbed by electrons being substantially larger than that absorbed by ions.

  1. ParaHydrogen Induced Polarization of 13C carboxylate resonance in acetate and pyruvate.

    Science.gov (United States)

    Reineri, Francesca; Boi, Tommaso; Aime, Silvio

    2015-01-05

    The advent of nuclear spins hyperpolarization techniques represents a breakthrough in the field of medical diagnoses by magnetic resonance imaging. Dynamic nuclear polarization (DNP) is the most widely used method, and hyperpolarized metabolites such as [1-(13)C]-pyruvate are shown to report on status of tumours. Parahydrogen-induced polarization (PHIP) is a chemistry-based technique, easier to handle and much less expensive in respect to DNP, with significantly shorter polarization times. Its main limitation is the availability of unsaturated precursors for the target substrates; for instance, acetate and pyruvate cannot be obtained by direct incorporation of the parahydrogen molecule. Herein we report a method that allows us to achieve hyperpolarization in this kind of molecule by means of a tailored precursor containing a hydrogenable functionality that, after polarization transfer to the target (13)C moiety, is cleaved to obtain the metabolite of interest. The reported procedure can be extended to a number of other biologically relevant substrates.

  2. Study of hydrogen in coals, polymers, oxides, and muscle water by nuclear magnetic resonance; extension of solid-state high-resolution techniques. [Hydrogen molybdenum bronze

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, L.M.

    1981-10-01

    Nuclear magnetic resonance (NMR) spectroscopy has been an important analytical and physical research tool for several decades. One area of NMR which has undergone considerable development in recent years is high resolution NMR of solids. In particular, high resolution solid state /sup 13/C NMR spectra exhibiting features similar to those observed in liquids are currently achievable using sophisticated pulse techniques. The work described in this thesis develops analogous methods for high resolution /sup 1/H NMR of rigid solids. Applications include characterization of hydrogen aromaticities in fossil fuels, and studies of hydrogen in oxides and bound water in muscle.

  3. Excellent Silicon Surface Passivation Achieved by Industrial Inductively Coupled Plasma Deposited Hydrogenated Intrinsic Amorphous Silicon Suboxide

    Directory of Open Access Journals (Sweden)

    Jia Ge

    2014-01-01

    Full Text Available We present an alternative method of depositing a high-quality passivation film for heterojunction silicon wafer solar cells, in this paper. The deposition of hydrogenated intrinsic amorphous silicon suboxide is accomplished by decomposing hydrogen, silane, and carbon dioxide in an industrial remote inductively coupled plasma platform. Through the investigation on CO2 partial pressure and process temperature, excellent surface passivation quality and optical properties are achieved. It is found that the hydrogen content in the film is much higher than what is commonly reported in intrinsic amorphous silicon due to oxygen incorporation. The observed slow depletion of hydrogen with increasing temperature greatly enhances its process window as well. The effective lifetime of symmetrically passivated samples under the optimal condition exceeds 4.7 ms on planar n-type Czochralski silicon wafers with a resistivity of 1 Ωcm, which is equivalent to an effective surface recombination velocity of less than 1.7 cms−1 and an implied open-circuit voltage (Voc of 741 mV. A comparison with several high quality passivation schemes for solar cells reveals that the developed inductively coupled plasma deposited films show excellent passivation quality. The excellent optical property and resistance to degradation make it an excellent substitute for industrial heterojunction silicon solar cell production.

  4. One-step preparation of hydrogenated ZrO2 microspheres by cathode plasma electrolysis

    Science.gov (United States)

    Liu, Chenxu; Xiang, Qingyun; Yang, Mu; Wang, Shengdian; Wang, Linxiu; Zhang, Jin; He, Yedong

    2017-07-01

    Hydrogenated ZrO2 microspheres were directly prepared by cathode plasma electrolysis (CPE) in an aqueous solution of Zr(NO3)4•5H2O. Owing to the energy of plasma and the cathodic hydrogen evolution reactions, the CPE method combined the preparation of ZrO2 ceramic and the hydrogen treatment into only one step. The results showed regular microspheres consisting of tetragonal-ZrO2 and monoclinic-ZrO2 with 1-10 µm in diameter were formed at relatively high concentration of Zr(NO3)3•5H2O. These ZrO2 microspheres contained about 52.54 µg g-1 hydrogen which caused a narrow band gap (3.10 eV). Thus, the microspheres showed good photocatalytic activity under simulated sunlight, and the degradation of RhB dye reached nearly 58% for 3 h of irradiation, much better than the ZrO2 microspheres after dehydrogenation treatment.

  5. Charged particle dynamics and molecular kinetics in the hydrogen postdischarge plasma

    Science.gov (United States)

    Diomede, P.; Longo, S.; Capitelli, M.

    2006-11-01

    The afterglow of a parallel plate radio frequency discharge in hydrogen is studied by numerical modelling to compare ion dynamics and chemical effects on the behavior of negative ions. While the ion dynamics requires a kinetic description of space dependent plasma relaxation (at least 1D), chemical effects require a vibrational kinetics of hydrogen molecules. Since previous models did not include both features it has not been possible until now to realize both effects in a single simulation. We apply an updated version of the 1D Bari model which includes a 1.5D (1Dr2Dv) Particle in Cell/Monte Carlo (PIC/MC) multispecies module coupled to the space and time dependent master equation for H2(X1Σg+,v=0,…,14) vibrational level population. Negative ion fronts are described in hydrogen for the first time and their impact on the plasma limiting surfaces produces a negative ion current evolution compatible with experimental findings. In the same conditions, the attachment rate overshoot is found to contribute about 7% to the average ion density in the plasma.

  6. Temperature dependence of the cosphi conductance in Josephson tunnel junctions determined from plasma resonance experiments

    DEFF Research Database (Denmark)

    Pedersen, Niels Falsig; Sørensen, O. H.; Mygind, Jesper

    1978-01-01

    The microwave response at 9 GHz of Sn-O-Sn tunnel-junction current biased at zero dc voltage has been measured just below the critical temperature Tc of the Sn films. The temperature dependence of the cosφ conductance is determined from the resonant response at the junction plasma frequency fp...... of the experiment....

  7. Optimization of hydrogen production by Halobacterium salinarium coupled with E coli using milk plasma as fermentative substrate

    Directory of Open Access Journals (Sweden)

    Brijesh Prasad

    2011-08-01

    Full Text Available Batch experiments were conducted to investigate the fermentative hydrogen production by coupled system of Halobacterium salinarium and E. coli. Increase in the light intensity from 6000 lux to 12000 lux and changing the inoculums level of E coli resulted in 10 fold increase in the rate of hydrogen production using the coupled system. Statistical based design of experiments was applied to optimize the rate of hydrogen production using milk plasma,popularly known as cheese whey, a dairy industry byproduct. An optimal rate of hydrogen production of 56.7 ml/l h was achieved with 14.42 % (by volume of milk plasma and an initial pH of 6.6. The investigations provided information on achieving higher yields with milk plasma as substrate, its optimal concentration, and importance of media pH for producing higher rate of hydrogen.

  8. Resonant Kα Spectroscopy of Solid-Density Aluminum Plasmas

    Science.gov (United States)

    Cho, B. I.; Engelhorn, K.; Vinko, S. M.; Chung, H.-K.; Ciricosta, O.; Rackstraw, D. S.; Falcone, R. W.; Brown, C. R. D.; Burian, T.; Chalupský, J.; Graves, C.; Hájková, V.; Higginbotham, A.; Juha, L.; Krzywinski, J.; Lee, H. J.; Messersmidt, M.; Murphy, C.; Ping, Y.; Rohringer, N.; Scherz, A.; Schlotter, W.; Toleikis, S.; Turner, J. J.; Vysin, L.; Wang, T.; Wu, B.; Zastrau, U.; Zhu, D.; Lee, R. W.; Nagler, B.; Wark, J. S.; Heimann, P. A.

    2012-12-01

    The x-ray intensities made available by x-ray free electron lasers (FEL) open up new x-ray matter interaction channels not accessible with previous sources. We report here on the resonant generation of Kα emission, that is to say the production of copious Kα radiation by tuning the x-ray FEL pulse to photon energies below that of the K edge of a solid aluminum sample. The sequential absorption of multiple photons in the same atom during the 80 fs pulse, with photons creating L-shell holes and then one resonantly exciting a K-shell electron into one of these holes, opens up a channel for the Kα production, as well as the absorption of further photons. We demonstrate rich spectra of such channels, and investigate the emission produced by tuning the FEL energy to the K-L transitions of those highly charged ions that have transition energies below the K edge of the cold material. The spectra are sensitive to x-ray intensity dependent opacity effects, with ions containing L-shell holes readily reabsorbing the Kα radiation.

  9. Resonant Kα spectroscopy of solid-density aluminum plasmas.

    Science.gov (United States)

    Cho, B I; Engelhorn, K; Vinko, S M; Chung, H-K; Ciricosta, O; Rackstraw, D S; Falcone, R W; Brown, C R D; Burian, T; Chalupský, J; Graves, C; Hájková, V; Higginbotham, A; Juha, L; Krzywinski, J; Lee, H J; Messersmidt, M; Murphy, C; Ping, Y; Rohringer, N; Scherz, A; Schlotter, W; Toleikis, S; Turner, J J; Vysin, L; Wang, T; Wu, B; Zastrau, U; Zhu, D; Lee, R W; Nagler, B; Wark, J S; Heimann, P A

    2012-12-14

    The x-ray intensities made available by x-ray free electron lasers (FEL) open up new x-ray matter interaction channels not accessible with previous sources. We report here on the resonant generation of Kα emission, that is to say the production of copious Kα radiation by tuning the x-ray FEL pulse to photon energies below that of the K edge of a solid aluminum sample. The sequential absorption of multiple photons in the same atom during the 80 fs pulse, with photons creating L-shell holes and then one resonantly exciting a K-shell electron into one of these holes, opens up a channel for the Kα production, as well as the absorption of further photons. We demonstrate rich spectra of such channels, and investigate the emission produced by tuning the FEL energy to the K-L transitions of those highly charged ions that have transition energies below the K edge of the cold material. The spectra are sensitive to x-ray intensity dependent opacity effects, with ions containing L-shell holes readily reabsorbing the Kα radiation.

  10. Hydrogen Ionic Plasma and Particle Dynamics in Negative Ion Source for NBI

    Science.gov (United States)

    Tsumori, Katsuyoshi

    2013-10-01

    Three negative-ion-based neutral beam injectors (NBIs) have been developed for plasma heating in the Large Helical Device. The NBIs achieve successfully the nominal injection power and beam energy, and understanding of the production and transport mechanisms of H- ion is required to obtain more stable high power beam. In the ion source development, we have found hydrogen ionic plasmas with extremely low electron density are produced in the beam extraction region. The plasma is measured with a combination of an electrostatic probe, millimeter-wave interferometer and cavity ring down (CRD). It has been observed for the first time that the charge neutrality of the ionic plasma is broken with H- extraction and electrons compensate the extracted H- charge. The influence of the extraction field widely affects to the ionic plasma in the extraction region. Two-dimensional particle-in-cell simulation (2D-PIC) has been applied to investigate the particle transport and reproduces the production of the ionic plasma and electron compensation due to H- extraction. In particle model, produced H- ions leave from the Cs covered PG surface in opposite direction to beam extraction. The direction can be changed with the electric field and collective effect due to the presence of plasma. A new technique using CCD camera with H α filter applied to measure the two-dimensional distribution of H- density. In the ionic plasma, H α light is emitted via electron-impact excitation and mutual neutralization processes with H- ion and proton. Comparing the results obtained with optical emission spectroscopy, electrostatic probe and CRD, it is shown the H α emission is dominated with the mutual neutralization. By subtracting the CCD images with and without beam extraction, it becomes clear that H- ions are extracted not directly from the PG surface but from the bulk of the ionic plasma. The result suggests the initial energy of H- ion is dumped rapidly in the ionic plasma.

  11. Observations of rotation in JET plasmas with electron heating by ion cyclotron resonance heating

    DEFF Research Database (Denmark)

    Hellsten, T.; Johnson, T. J.; Van Eester, D.

    2012-01-01

    The rotation of L-mode plasmas in the JET tokamak heated by waves in the ion cyclotron range of frequencies (ICRF) damped on electrons, is reported. The plasma in the core is found to rotate in the counter-current direction with a high shear and in the outer part of the plasma with an almost...... constant angular rotation. The core rotation is stronger in magnitude than observed for scenarios with dominating ion cyclotron absorption. Two scenarios are considered: the inverted mode conversion scenarios and heating at the second harmonic He-3 cyclotron resonance in H plasmas. In the latter case......, electron absorption of the fast magnetosonic wave by transit time magnetic pumping and electron Landau damping (TTMP/ELD) is the dominating absorption mechanism. Inverted mode conversion is done in (He-3)-H plasmas where the mode converted waves are essentially absorbed by electron Landau damping. Similar...

  12. Plasma instability in the afterglow of electron cyclotron resonance discharge sustained in a mirror trap

    Energy Technology Data Exchange (ETDEWEB)

    Izotov, I.; Mansfeld, D.; Skalyga, V.; Zorin, V. [Institute of Applied Physics, RAS, 46 Ulyanova St., 603950 Nizhny Novgorod (Russian Federation); Grahn, T.; Kalvas, T.; Koivisto, H.; Komppula, J.; Peura, P.; Tarvainen, O.; Toivanen, V. [Department of Physics, University of Jyvaeskylae, P.O. Box 35 (YFL), 40500 Jyvaeskylae (Finland)

    2012-12-15

    The work presented in this article is devoted to time-resolved diagnostics of non-linear effects observed during the afterglow plasma decay of a 14 GHz electron cyclotron resonance ion source operated in pulsed mode. Plasma instabilities that cause perturbations of the extracted ion current during the decay were observed and studied. It is shown that these perturbations are associated with precipitation of high energy electrons along the magnetic field lines and strong bursts of bremsstrahlung emission. The effect of ion source settings on the onset of the observed instabilities was investigated. Based on the experimental data and estimated plasma properties, it is assumed that the instabilities are of cyclotron type. The conclusion is supported by a comparison to other types of plasma devices which exhibit similar characteristics but which operate in a different plasma confinement regime.

  13. The nature of resonance-assisted hydrogen bonds: a quantum chemical topology perspective.

    Science.gov (United States)

    Guevara-Vela, José Manuel; Romero-Montalvo, Eduardo; Costales, Aurora; Pendás, Ángel Martín; Rocha-Rinza, Tomás

    2016-10-14

    Resonance Assisted Hydrogen Bonds (RAHBs) are particularly strong H-Bonds (HBs) which are relevant in several fields of chemistry. The traditional explanation for the occurrence of these HBs is built on mesomeric structures evocative of electron delocalisation in the system. Nonetheless, there are several theoretical studies which have found no evidence of such electron delocalisation. We considered the origin of RAHBs by employing Quantum Chemical Topology tools, more specifically, the Quantum Theory of Atoms in Molecules (QTAIM) and the Interacting Quantum Atoms energy partition. Our results indicate that the π-conjugated bonds allow for a larger adjustment of electron density throughout the H-bonded system as compared with non-conjugated carbonyl molecules. This rearrangement of charge distribution is a response to the electric field due to the H atom involved in the hydrogen bonding of the considered compounds. As opposed to the usual description of RAHB interactions, these HBs lead to a larger electron localisation in the system, and concomitantly to larger QTAIM charges which in turn lead to stronger electrostatic, polarization and charge transfer components of the interaction. Overall, the results presented here offer a new perspective on the cause of strengthening of these important interactions.

  14. Spectral Interpretation of Radio Sounder-Stimulated Magnetospheric Plasma Resonances in Terms of Kappa Distributions

    Science.gov (United States)

    Benson, Robert F.; Vinas, Adolfo, F.; Fainberg, Joseph; Osherovich, Vladimir A.; Purser, Carola M.; Galkin, Ivan A.; Reinisch, Bodo W.

    2011-01-01

    Magnetosphere sounders stimulate plasma resonances between the harmonics of the electron cyclotron frequency and above the upper-hybrid frequency. More than three decades ago they were recognized as equivalent to ionospheric topside-sounder-stimulated resonances, designated as Qn resonances a decade earlier, with one important difference: the magnetospheric Qn frequencies often indicated that the background electron-velocity distribution was non-Maxwellian. Interpretations based on bi-Maxwellian and kappa distributions have been proposed. Here we expand on the latter, which requires fewer free parameters, by comparing kappa-derived Qn frequencies with observations from the Radio Plasma Imager on the Imager for Magnetopause-to-Aurora Global Exploration (IMAGE) satellite.

  15. Gallium-assisted growth of silicon nanowires by electron cyclotron resonance plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez, M J; Cervera, M; Ruiz, E; Pau, J L; Piqueras, J [Laboratorio de Microelectronica, Departamento de Fisica Aplicada, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Avella, M; Jimenez, J, E-mail: maria.jesus.hernandez@uam.es [Fisica de la Materia Condensada, ETSII, Universidad de Valladolid, 47011 Valladolid (Spain)

    2010-11-12

    The use of gallium droplets for growing Si nanowires (SiNWs) by electron cyclotron resonance plasmas is investigated. First, the relationship between evaporation time and resultant size of the gallium droplets is studied. Through the use of spectroscopic ellipsometry, the dependence of the surface plasmon resonance (SPR) energy on the droplet size is determined. From these gallium droplets, SiNWs were grown at 300 and 550 deg. C in electron cyclotron resonance plasmas containing SiH{sub 4}, Ar, and H{sub 2}. Scanning electron microscopy results show that tapered NWs are obtained for a wide range of growth conditions. Besides, it is found that H{sub 2} plays an important role in the parasitic axial growth of the SiNWs. Namely, H{sub 2} inhibits the radial growth and contributes dramatically to increasing the SiNW defects.

  16. Calculation of Internal Energy and Pressure of Dense hydrogen Plasma by Direct Path Integral Monte Carlo Approach

    Institute of Scientific and Technical Information of China (English)

    刘松芬; 胡北来

    2003-01-01

    The internal energy and pressure of dense hydrogen plasma are calculated by the direct path integral Monte Carlo approach. The Kelbg potential is used as interaction potentials both between electrons and between protons and electrons in the calculation. The complete formulae for internal energy and pressure in dense hydrogen plasma derived for the simulation are presented. The correctness of the derived formulae are validated by the obtained simulation results. The numerical results are discussed in details.

  17. Adhesion improvement of hydrogenated diamond-like carbon thin films by pre-deposition plasma treatment of rubber substrate

    OpenAIRE

    Bui, X. L.; Pei, Y.T.; Mulder, E.D.G.; De Hosson, J. Th. M.

    2009-01-01

    For reduction of friction and enhancement of wear resistance of dynamic rubber seals, thin films of hydrogenated diamond-like carbon (DLC) have been deposited on hydrogenated nitrile butadiene rubber (HNBR) via magnetron-enhanced plasma chemical vapor deposition (ME-PCVD). Pre-deposition plasma treatment of HNBR substrate is proved to be crucial for the improvement of film performance due to enhanced interfacial adhesion. The columnar structure and the crack network formed during deposition e...

  18. Modeling of Plasma-Assisted Conversion of Liquid Ethanol into Hydrogen Enriched Syngas in the Nonequilibrium Electric Discharge Plasma-Liquid System

    CERN Document Server

    Levko, Dmitry; Naumov, Vadim; Chernyak, Valery; Yukhymenko, Vitaly; Prysiazhnevych, Irina; Olszewski, Sergey

    2008-01-01

    In this work we report recent results of our experimental and theoretical studies related to plasma conversion of liquid ethanol into hydrogen-enriched syngas in the plasma-liquid system with the electric discharge in a gas channel with liquid wall using available diagnostics and numerical modeling.

  19. Effect of hydrogen addition on the deposition of titanium nitride thin films in nitrogen added argon magnetron plasma

    Science.gov (United States)

    Saikia, P.; Bhuyan, H.; Diaz-Droguett, D. E.; Guzman, F.; Mändl, S.; Saikia, B. K.; Favre, M.; Maze, J. R.; Wyndham, E.

    2016-06-01

    The properties and performance of thin films deposited by plasma assisted processes are closely related to their manufacturing techniques and processes. The objective of the current study is to investigate the modification of plasma parameters occurring during hydrogen addition in N2  +  Ar magnetron plasma used for titanium nitride thin film deposition, and to correlate the measured properties of the deposited thin film with the bulk plasma parameters of the magnetron discharge. From the Langmuir probe measurements, it was observed that the addition of hydrogen led to a decrease of electron density from 8.6 to 6.2  ×  (1014 m-3) and a corresponding increase of electron temperature from 6.30 to 6.74 eV. The optical emission spectroscopy study reveals that with addition of hydrogen, the density of argon ions decreases. The various positive ion species involving hydrogen are found to increase with increase of hydrogen partial pressure in the chamber. The thin films deposited were characterized using standard surface diagnostic tools such as x-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS), x-ray diffraction (XRD), Raman spectroscopy (RS), scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS). Although it was possible to deposit thin films of titanium nitride with hydrogen addition in nitrogen added argon magnetron plasma, the quality of the thin films deteriorates with higher hydrogen partial pressures.

  20. An argon–nitrogen–hydrogen mixed-gas plasma as a robust ionization source for inductively coupled plasma mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Makonnen, Yoseif; Beauchemin, Diane, E-mail: diane.beauchemin@chem.queensu.ca

    2014-09-01

    Multivariate optimization of an argon–nitrogen–hydrogen mixed-gas plasma for minimum matrix effects, while maintaining analyte sensitivity as much as possible, was carried out in inductively coupled plasma mass spectrometry. In the presence of 0.1 M Na, the 33.9 ± 3.9% (n = 13 elements) analyte signal suppression on average observed in an all-argon plasma was alleviated with the optimized mixed-gas plasma, the average being − 4.0 ± 8.8%, with enhancement in several cases. An addition of 2.3% v/v N{sub 2} in the outer plasma gas, and 0.50% v/v H{sub 2} to the central channel, as a sheath around the nebulizer gas flow, was sufficient for this drastic increase in robustness. It also reduced the background from ArO{sup +} and Ar{sub 2}{sup +} as well as oxide levels by over an order of magnitude. On the other hand, the background from NO{sup +} and ArN{sup +} increased by up to an order of magnitude while the levels of doubly-charged ions increased to 7% (versus 2.7% in an argon plasma optimized for sensitivity). Furthermore, detection limits were generally degraded by 5 to 15 fold when using the mixed-gas plasma versus the argon plasma for matrix-free solution (although they were better for several elements in 0.1 M Na). Nonetheless, the drastically increased robustness allowed the direct quantitative multielement analysis of certified ore reference materials, as well as the determination of Mo and Cd in seawater, without using any matrix-matching or internal standardization. - Highlights: • Addition of N{sub 2} to the plasma gas and H{sub 2} as a sheath gas results in a very robust ICP. • ArO{sup +} and Ar{sub 2}{sup +} background and oxide levels are reduced by over an order of magnitude. • Multielement analysis of rock digests is possible with a simple external calibration. • No internal standardization or matrix-matching is required for accurate analysis. • Cd and Mo were accurately determined in undiluted seawater.

  1. New algorithm for computing the ablation of hydrogenic pellets in hot plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Milora, S.L.

    1983-04-01

    A method is presented for calculating the evaporation rate of hydrogenic pellets immersed in an unmagnetized plasma with a suprathermal particle component of arbitrary distribution function. The computational procedure is based on hydrodynamic solutions for the expansion of the gaseous cloud, obtained in a previous treatment that considered the effects of thermal particles only. The appropriate heat source terms, derived from the stopping power of the gaseous shield, are worked out for energetic ions produced by neutral beam injection heating. The model predicts 27-cm penetration in a Poloidal Divertor Experiment (PDX) plasma, compared with experimentally measured values in the range of 29 to 32 cm. An application to the Tokamak Fusion Test Reactor (TFTR) gives an estimated 21-cm penetration for a 2.5-mm-diam tritium pellet injection at 2000 m/s into a 55-cm-bore plasma heated to a central electron temperature of 4 keV by 34 MW of neutral injection.

  2. Hydrogen plasma treatment for improved conductivity in amorphous aluminum doped zinc tin oxide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Morales-Masis, M., E-mail: monica.moralesmasis@epfl.ch; Ding, L.; Dauzou, F. [Photovoltaics and Thin-Film Electronics Laboratory (PVLab), Institute of Microengineering (IMT), Ecole Polytechnique Fédérale de Lausanne - EPFL, Rue de la Maladière 71b, CH-2002 Neuchatel (Switzerland); Jeangros, Q. [Interdisciplinary Centre for Electron Microscopy, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne (Switzerland); Hessler-Wyser, A. [Photovoltaics and Thin-Film Electronics Laboratory (PVLab), Institute of Microengineering (IMT), Ecole Polytechnique Fédérale de Lausanne - EPFL, Rue de la Maladière 71b, CH-2002 Neuchatel (Switzerland); Interdisciplinary Centre for Electron Microscopy, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne (Switzerland); Nicolay, S. [Centre Suisse d’Electronique et de Microtechnique (CSEM) SA, Rue Jaquet-Droz 1, CH-2002 Neuchatel (Switzerland); Ballif, C. [Photovoltaics and Thin-Film Electronics Laboratory (PVLab), Institute of Microengineering (IMT), Ecole Polytechnique Fédérale de Lausanne - EPFL, Rue de la Maladière 71b, CH-2002 Neuchatel (Switzerland); Centre Suisse d’Electronique et de Microtechnique (CSEM) SA, Rue Jaquet-Droz 1, CH-2002 Neuchatel (Switzerland)

    2014-09-01

    Improving the conductivity of earth-abundant transparent conductive oxides (TCOs) remains an important challenge that will facilitate the replacement of indium-based TCOs. Here, we show that a hydrogen (H{sub 2})-plasma post-deposition treatment improves the conductivity of amorphous aluminum-doped zinc tin oxide while retaining its low optical absorption. We found that the H{sub 2}-plasma treatment performed at a substrate temperature of 50 °C reduces the resistivity of the films by 57% and increases the absorptance by only 2%. Additionally, the low substrate temperature delays the known formation of tin particles with the plasma and it allows the application of the process to temperature-sensitive substrates.

  3. Fast Identification of Recycling Properties of Wall-Released Hydrogenic Neutrals in Divertor Plasma

    Institute of Scientific and Technical Information of China (English)

    LI Chengyue; DENG Baiquan; YAN Jiancheng; G. A. EMMERT

    2007-01-01

    A new bipartition neutral transport model was developed for quick identification of the recycling properties of the wall-released hydrogenic neutral particles in the vicinity of the divertor target plate. Based on this model, the numerical calculation results are fairly consistent with the results obtained with the 'multi-generation method'. This model can not only be utilized to provide a source term from neutral transport calculations for the B2 edge plasma transport code, which has been used to simulate edge plasma transport of an HL-2A divertor configuration, but can also be specifically applied for fast classification of the divertor plasma as high recycling or low recycling. Our results also show that the transmissivity is lower in the high-recycling regime.

  4. Study of Anti-Hydrogen and Plasma Physics 4.Observation of Antiproton Beams and Nonneutral Plasmas

    CERN Document Server

    Hori, Masaki; Fujiwara, Makoto; Kuroda, Naofumi

    2004-01-01

    Diagnostics of antiproton beams and nonneutral plasmas are described in this chapter. Parallel plate secondary electron emission detectors are used to non-destructively observe the beam position and intensity without loss. Plastic scintillation tracking detectors are useful in determining the position of annihilations of antiprotons in the trap. Three-dimensional imaging of antiprotons in a Penning trap is discussed. The unique capability of antimatter particle imaging has allowed the observation of the spatial distribution of particle loss in a trap. Radial loss is localized to small spots, strongly breaking the azimuthal symmetry expected for an ideal trap. By observing electrostatic eigen-modes of nonneutral plasmas trapped in the Multi-ring electrode trap, the non-destructive measurement of plasma parameters is performed.

  5. Clinical Implication of Plasma Hydrogen Sulfide Levels in Japanese Patients with Type 2 Diabetes

    Science.gov (United States)

    Suzuki, Kunihiro; Sagara, Masaaki; Aoki, Chie; Tanaka, Seiichi; Aso, Yoshimasa

    2017-01-01

    Objective The goal of the present study was to investigate the plasma hydrogen sulfide (H2S) levels in patients with type 2 diabetes, as the plasma H2S levels in Japanese patients with type 2 diabetes remain unclear. Methods The plasma H2S levels were measured in 154 outpatients with type 2 diabetes and 66 outpatients without diabetes. All blood samples were collected in the outpatient department from 09:00 to 10:00. The patients had fasted from 21:00 the previous evening and had not consumed alcohol or caffeine or smoked until sample collection. The plasma H2S levels were measured using the methylene blue assay. The plasma H2S levels were determined in triplicate, and the average concentrations were calculated against a calibration curve of sodium sulfide. Results The patients with type 2 diabetes showed a progressive reduction in the plasma H2S levels (45.1±15.5 μM versus 54.0±26.4 μM, p<0.05), which paralleled poor glycemic control. There was a significant correlation between a reduction in the plasma H2S levels and the HbA1c levels (β=-0.505, p<0.01), Furthermore, a reduction in the plasma H2S levels was found to be related to a history of cardiovascular diseases in patients with type 2 diabetes (39.9±13.8 μM versus 47.5±15.9 μM, p<0.01). Conclusion Collectively, the plasma H2S levels were reduced in patients with type 2 diabetes, which may have implications in the pathophysiology of cardiovascular disease in diabetic patients. The trial was registered with the University Hospital Medical Information Network (UMIN no. #000020549). PMID:28049995

  6. Resonant- and avalanche-ionization amplification of laser-induced plasma in air

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Yue; Zhang, Zhili, E-mail: zzhang24@utk.edu [Department of Mechanical, Aerospace and Biomedical Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Jiang, Naibo; Roy, Sukesh [Spectral Energies, LLC, 5100 Springfield St., Suite 301, Dayton, Ohio 45431 (United States); Gord, James R. [Air Force Research Laboratory, Aerospace Systems Directorate, Wright-Patterson Air Force Base, Ohio 45433 (United States)

    2014-10-14

    Amplification of laser-induced plasma in air is demonstrated utilizing resonant laser ionization and avalanche ionization. Molecular oxygen in air is ionized by a low-energy laser pulse employing (2 + 1) resonance-enhanced multi-photon ionization (REMPI) to generate seed electrons. Subsequent avalanche ionization of molecular oxygen and nitrogen significantly amplifies the laser-induced plasma. In this plasma-amplification effect, three-body attachments to molecular oxygen dominate the electron-generation and -loss processes, while either nitrogen or argon acts as the third body with low electron affinity. Contour maps of the electron density within the plasma obtained in O₂/N₂ and O₂/Ar gas mixtures are provided to show relative degrees of plasma amplification with respect to gas pressure and to verify that the seed electrons generated by O₂ 2 + 1 REMPI are selectively amplified by avalanche ionization of molecular nitrogen in a relatively low-pressure condition (≤100 Torr). Such plasma amplification occurring in air could be useful in aerospace applications at high altitude.

  7. NOVEL COMPOSITE HYDROGEN-PERMEABLE MEMBRANES FOR NON-THERMAL PLASMA REACTORS FOR THE DECOMPOSITION OF HYDROGEN SULFIDE

    Energy Technology Data Exchange (ETDEWEB)

    Morris D. Argyle; John F. Ackerman; Suresh Muknahallipatna; Jerry C. Hamann; Stanislaw Legowski; Ji-Jun Zhang; Guibing Zhao; Robyn J. Alcanzare; Linna Wang; Ovid A. Plumb

    2004-07-01

    The goal of this experimental project is to design and fabricate a reactor and membrane test cell to dissociate hydrogen sulfide (H{sub 2}S) in a non-thermal plasma and recover hydrogen (H{sub 2}) through a superpermeable multi-layer membrane. Superpermeability of hydrogen atoms (H) has been reported by some researchers using membranes made of Group V transition metals (niobium, tantalum, vanadium, and their alloys), although it has yet to be confirmed in this study. Experiments involving methane conversion reactions were conducted with a preliminary pulsed corona discharge reactor design in order to test and improve the reactor and membrane designs using a non-toxic reactant. This report details the direct methane conversion experiments to produce hydrogen, acetylene, and higher hydrocarbons utilizing a co-axial cylinder (CAC) corona discharge reactor, pulsed with a thyratron switch. The reactor was designed to accommodate relatively high flow rates (655 x 10{sup -6} m{sup 3}/s) representing a pilot scale easily converted to commercial scale. Parameters expected to influence methane conversion including pulse frequency, charge voltage, capacitance, residence time, and electrode material were investigated. Conversion, selectivity and energy consumption were measured or estimated. C{sub 2} and C{sub 3} hydrocarbon products were analyzed with a residual gas analyzer (RGA). In order to obtain quantitative results, the complex sample spectra were de-convoluted via a linear least squares method. Methane conversion as high as 51% was achieved. The products are typically 50%-60% acetylene, 20% propane, 10% ethane and ethylene, and 5% propylene. First Law thermodynamic energy efficiencies for the system (electrical and reactor) were estimated to range from 38% to 6%, with the highest efficiencies occurring at short residence time and low power input (low specific energy) where conversion is the lowest (less than 5%). The highest methane conversion of 51% occurred at a

  8. NOVEL COMPOSITE HYDROGEN-PERMEABLE MEMBRANES FOR NON-THERMAL PLASMA REACTORS FOR THE DECOMPOSITION OF HYDROGEN SULFIDE

    Energy Technology Data Exchange (ETDEWEB)

    Morris D. Argyle; John F. Ackerman; Suresh Muknahallipatna; Jerry C. Hamann; Stanislaw Legowski; Ji-Jun Zhang; Guibing Zhao; Robyn J. Alcanzare; Linna Wang; Ovid A. Plumb

    2004-07-01

    The goal of this experimental project is to design and fabricate a reactor and membrane test cell to dissociate hydrogen sulfide (H{sub 2}S) in a non-thermal plasma and recover hydrogen (H{sub 2}) through a superpermeable multi-layer membrane. Superpermeability of hydrogen atoms (H) has been reported by some researchers using membranes made of Group V transition metals (niobium, tantalum, vanadium, and their alloys), although it has yet to be confirmed in this study. Experiments involving methane conversion reactions were conducted with a preliminary pulsed corona discharge reactor design in order to test and improve the reactor and membrane designs using a non-toxic reactant. This report details the direct methane conversion experiments to produce hydrogen, acetylene, and higher hydrocarbons utilizing a co-axial cylinder (CAC) corona discharge reactor, pulsed with a thyratron switch. The reactor was designed to accommodate relatively high flow rates (655 x 10{sup -6} m{sup 3}/s) representing a pilot scale easily converted to commercial scale. Parameters expected to influence methane conversion including pulse frequency, charge voltage, capacitance, residence time, and electrode material were investigated. Conversion, selectivity and energy consumption were measured or estimated. C{sub 2} and C{sub 3} hydrocarbon products were analyzed with a residual gas analyzer (RGA). In order to obtain quantitative results, the complex sample spectra were de-convoluted via a linear least squares method. Methane conversion as high as 51% was achieved. The products are typically 50%-60% acetylene, 20% propane, 10% ethane and ethylene, and 5% propylene. First Law thermodynamic energy efficiencies for the system (electrical and reactor) were estimated to range from 38% to 6%, with the highest efficiencies occurring at short residence time and low power input (low specific energy) where conversion is the lowest (less than 5%). The highest methane conversion of 51% occurred at a

  9. Electron heating via the self-excited plasma series resonance in geometrically symmetric multi-frequency capacitive plasmas

    CERN Document Server

    Schuengel, E; Donko, Z; Korolov, I; Derzsi, A; Schulze, J

    2016-01-01

    The self-excitation of Plasma Series Resonance (PSR) oscillations plays an important role in the electron heating dynamics in Capacitively Coupled Radio Frequency (CCRF) plasmas. In a combined approach of PIC/MCC simulations and a theoretical model based on an equivalent circuit, we investigate the self-excitation of PSR oscillations and their effect on the electron heating in geometrically symmetric CCRF plasmas driven by multiple consecutive harmonics. The discharge symmetry is controlled via the Electrical Asymmetry Effect, i.e. by varying the total number of harmonics and tuning the phase shifts between them. It is demonstrated that PSR oscillations will be self-excited under both symmetric and asymmetric conditions, if (i) the charge-voltage relation of the plasma sheaths deviates from a simple quadratic behavior and if (ii) the inductance of the plasma bulk exhibits a temporal modulation. These two effects have been neglected up to now, but we show that they must be included in the model in order to pro...

  10. Bright gamma-rays from betatron resonance acceleration in near critical density plasma

    CERN Document Server

    Liu, B; Wu, D; Liu, J; Chen, C E; Yan, X Q; He, X T

    2013-01-01

    We show that electron betatron resonance acceleration by an ultra-intense ultra-short laser pulse in a near critical density plasma works as a high-brightness gamma-ray source. Compared with laser plasma X-ray sources in under-dense plasma, near critical density plasma provides three benefits for electron radiation: more radiation electrons, larger transverse amplitude, and higher betatron oscillation frequency. Three-dimensional particle-in-cell simulations show that, by using a 7.4J laser pulse, 8.3mJ radiation with critical photon energy 1MeV is emitted. The critical photon energy $E_c$ increases with the incident laser energy %faster than a linear relation. $W_I$ as $E_c \\propto W_I^{1.5}$, and the corresponding photon number is proportional to $W_I$. A simple analytical synchrotron-like radiation model is built, which can explain the simulation results.

  11. Hydrogen sulfide decreases the plasma lipid peroxidation induced by homocysteine and its thiolactone.

    Science.gov (United States)

    Olas, Beata; Kontek, Bogdan

    2015-06-01

    Hydrogen sulfide (H2S) has been investigated widely in recent years. H2S plays a variety of roles in different biological systems, including cardiovascular system. It is the final product of amino acids metabolism, which contains sulfur-cysteine and homocysteine (Hcy). In human plasma, there are several various forms of homocysteine: free Hcy, protein-bound Hcy (S-linked, and N-linked), and homocysteine thiolactone (HTL). Our previous works have shown that both Hcy in the reduced form and its thiolactone may modify fibrinolysis, coagulation process, and biological activity of blood platelets. Moreover, we have observed that HTL, like its precursor-Hcy stimulated the generation of superoxide anion radicals (O 2 (-•) ) in blood platelets. The aim of our study in vitro was to establish the influence of sodium hydrosulfide (NaHS, as a fast-releasing H2S donor; at tested concentrations: 10-1000 µM) on the plasma lipid peroxidation induced by the reduced Hcy (at final concentrations of 0.01-1 mM) and HTL (at final concentrations of 0.1-1 µM). Our results indicate that 10 and 100 µM NaHS decreased the lipid peroxidation in plasma treated with 1 mM Hcy or 1 µM HTL (when NaHS and Hcy/HTL were added to plasma together). The protective effect of 10 and 100 µM NaHS against the lipid peroxidation in plasma preincubated with 1 mM Hcy or 1 µM HTL was also observed. Considering the data presented in this study, we suggest that the lipid peroxidation (induced by different forms of homocysteine) may be reduced by hydrogen sulfide.

  12. Stark broadening measurements in plasmas produced by laser ablation of hydrogen containing compounds

    Science.gov (United States)

    Burger, Miloš; Hermann, Jörg

    2016-08-01

    We present a method for the measurement of Stark broadening parameters of atomic and ionic spectral lines based on laser ablation of hydrogen containing compounds. Therefore, plume emission spectra, recorded with an echelle spectrometer coupled to a gated detector, were compared to the spectral radiance of a plasma in local thermal equilibrium. Producing material ablation with ultraviolet nanosecond laser pulses in argon at near atmospheric pressure, the recordings take advantage of the spatially uniform distributions of electron density and temperature within the ablated vapor. By changing the delay between laser pulse and detector gate, the electron density could be varied by more than two orders of magnitude while the temperature was altered in the range from 6,000 to 14,000 K. The Stark broadening parameters of transitions were derived from their simultaneous observation with the hydrogen Balmer alpha line. In addition, assuming a linear increase of Stark widths and shifts with electron density for non-hydrogenic lines, our measurements indicate a change of the Stark broadening-dependence of Hα over the considered electron density range. The presented results obtained for hydrated calcium sulfate (CaSO4ṡ2H2O) can be extended to any kind of hydrogen containing compounds.

  13. Electrical characterization of deep levels in n-type GaAs after hydrogen plasma treatment

    Energy Technology Data Exchange (ETDEWEB)

    Nyamhere, C., E-mail: s210239522@live.nmmu.ac.z [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Botha, J.R.; Venter, A. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa)

    2011-05-15

    Deep level transient spectroscopy (DLTS) and Laplace-DLTS (L-DLTS) have been used to investigate defects in an n-type GaAs before and after exposure to a dc hydrogen plasma (hydrogenation). DLTS revealed the presence of three prominent electron traps in the material in the temperature range 20-300 K. However, L-DLTS with its higher resolution enabled the splitting of two narrowly spaced emission rates. Consequently four electron traps at, E{sub C}-0.33 eV, E{sub C}-0.36 eV, E{sub C}-0.38 eV and E{sub C}-0.56 eV were observed in the control sample. Following hydrogenation, all these traps were passivated with a new complex (presumably the M3), emerging at E{sub C}-0.58 eV. Isochronal annealing of the passivated material between 50 and 300 {sup o}C, revealed the emergence of a secondary defect, not previously observed, at E{sub C}-0.37 eV. Finally, the effect of hydrogen passivation is completely reversed upon annealing at 300 {sup o}C, as all the defects originally observed in the reference sample were recovered.

  14. Absolute hydrogen depth profiling using the resonant $^{1}$H($^{15}$N,$\\alpha\\gamma$)$^{12}$C nuclear reaction

    CERN Document Server

    Reinhardt, Tobias P; Bemmerer, Daniel; Stöckel, Klaus; Wagner, Louis

    2016-01-01

    Resonant nuclear reactions are a powerful tool for the determination of the amount and profile of hydrogen in thin layers of material. Usually, this tool requires the use of a standard of well-known composition. The present work, by contrast, deals with standard-less hydrogen depth profiling. This approach requires precise nuclear data, e.g. on the widely used $^{1}$H($^{15}$N,$\\alpha\\gamma$)$^{12}$C reaction, resonant at 6.4\\,MeV $^{15}$N beam energy. Here, the strongly anisotropic angular distribution of the emitted $\\gamma$-rays from this resonance has been re-measured, resolving a previous discrepancy. Coefficients of (0.38$\\pm$0.04) and (0.80$\\pm$0.04) have been deduced for the second and fourth order Legendre polynomials, respectively. In addition, the resonance strength has been re-evaluated to (25.0$\\pm$1.5)\\,eV, 10\\% higher than previously reported. A simple working formula for the hydrogen concentration is given for cases with known $\\gamma$-ray detection efficiency. Finally, the absolute approach i...

  15. Non-linear magnetohydrodynamic modeling of plasma response to resonant magnetic perturbations

    Energy Technology Data Exchange (ETDEWEB)

    Orain, F.; Bécoulet, M.; Dif-Pradalier, G.; Nardon, E.; Passeron, C.; Latu, G.; Grandgirard, V.; Fil, A.; Ratnani, A. [CEA, IRFM, F-13108 Saint-Paul-Lez-Durance (France); Huijsmans, G. [ITER Organization, Route de Vinon, F-13115 Saint-Paul-Lez-Durance (France); Pamela, S. [IIFS-PIIM. Aix Marseille Université - CNRS, 13397 Marseille Cedex20 (France); Chapman, I.; Kirk, A.; Thornton, A. [EURATOM/CCFE Fusion Association, Culham Science Centre, Oxon OX14 3DB (United Kingdom); Hoelzl, M. [Max-Planck-Institut für Plasmaphysik, EURATOM Association, Garching (Germany); Cahyna, P. [Association EURATOM/IPP.CR, Prague (Czech Republic)

    2013-10-15

    The interaction of static Resonant Magnetic Perturbations (RMPs) with the plasma flows is modeled in toroidal geometry, using the non-linear resistive MHD code JOREK, which includes the X-point and the scrape-off-layer. Two-fluid diamagnetic effects, the neoclassical poloidal friction and a source of toroidal rotation are introduced in the model to describe realistic plasma flows. RMP penetration is studied taking self-consistently into account the effects of these flows and the radial electric field evolution. JET-like, MAST, and ITER parameters are used in modeling. For JET-like parameters, three regimes of plasma response are found depending on the plasma resistivity and the diamagnetic rotation: at high resistivity and slow rotation, the islands generated by the RMPs at the edge resonant surfaces rotate in the ion diamagnetic direction and their size oscillates. At faster rotation, the generated islands are static and are more screened by the plasma. An intermediate regime with static islands which slightly oscillate is found at lower resistivity. In ITER simulations, the RMPs generate static islands, which forms an ergodic layer at the very edge (ψ≥0.96) characterized by lobe structures near the X-point and results in a small strike point splitting on the divertor targets. In MAST Double Null Divertor geometry, lobes are also found near the X-point and the 3D-deformation of the density and temperature profiles is observed.

  16. Non-linear magnetohydrodynamic modeling of plasma response to resonant magnetic perturbations

    Science.gov (United States)

    Orain, F.; Bécoulet, M.; Dif-Pradalier, G.; Huijsmans, G.; Pamela, S.; Nardon, E.; Passeron, C.; Latu, G.; Grandgirard, V.; Fil, A.; Ratnani, A.; Chapman, I.; Kirk, A.; Thornton, A.; Hoelzl, M.; Cahyna, P.

    2013-10-01

    The interaction of static Resonant Magnetic Perturbations (RMPs) with the plasma flows is modeled in toroidal geometry, using the non-linear resistive MHD code JOREK, which includes the X-point and the scrape-off-layer. Two-fluid diamagnetic effects, the neoclassical poloidal friction and a source of toroidal rotation are introduced in the model to describe realistic plasma flows. RMP penetration is studied taking self-consistently into account the effects of these flows and the radial electric field evolution. JET-like, MAST, and ITER parameters are used in modeling. For JET-like parameters, three regimes of plasma response are found depending on the plasma resistivity and the diamagnetic rotation: at high resistivity and slow rotation, the islands generated by the RMPs at the edge resonant surfaces rotate in the ion diamagnetic direction and their size oscillates. At faster rotation, the generated islands are static and are more screened by the plasma. An intermediate regime with static islands which slightly oscillate is found at lower resistivity. In ITER simulations, the RMPs generate static islands, which forms an ergodic layer at the very edge (ψ ≥0.96) characterized by lobe structures near the X-point and results in a small strike point splitting on the divertor targets. In MAST Double Null Divertor geometry, lobes are also found near the X-point and the 3D-deformation of the density and temperature profiles is observed.

  17. Optimization of negative ion current in a compact microwave driven upper hybrid resonance multicusp plasma source.

    Science.gov (United States)

    Sahu, D; Bhattacharjee, S; Singh, M J; Bandyopadhyay, M; Chakraborty, A

    2012-02-01

    Performance of a microwave driven upper hybrid resonance multicusp plasma source as a volume negative ion source is reported. Microwaves are directly launched into the plasma chamber predominantly in the TE(11) mode. The source is operated at different discharge conditions to obtain the optimized negative H(-) ion current which is ∼33 μA (0.26 mA∕cm(2)). Particle balance equations are solved to estimate the negative ion density, which is compared with the experimental results. Future prospects of the source are discussed.

  18. Optimization of negative ion current in a compact microwave driven upper hybrid resonance multicusp plasma sourcea)

    Science.gov (United States)

    Sahu, D.; Bhattacharjee, S.; Singh, M. J.; Bandyopadhyay, M.; Chakraborty, A.

    2012-02-01

    Performance of a microwave driven upper hybrid resonance multicusp plasma source as a volume negative ion source is reported. Microwaves are directly launched into the plasma chamber predominantly in the TE11 mode. The source is operated at different discharge conditions to obtain the optimized negative H- ion current which is ˜33 μA (0.26 mA/cm2). Particle balance equations are solved to estimate the negative ion density, which is compared with the experimental results. Future prospects of the source are discussed.

  19. The effects of added hydrogen on a helium atmospheric-pressure plasma jet ambient desorption/ionization source.

    Science.gov (United States)

    Wright, Jonathan P; Heywood, Matthew S; Thurston, Glen K; Farnsworth, Paul B

    2013-03-01

    We present mass spectrometric data demonstrating the effect that hydrogen has on a helium-based dielectric-barrier discharge (DBD) atmospheric-pressure plasma jet used as an ambient desorption/ionization (ADI) source. The addition of 0.9 % hydrogen to the helium support gas in a 35-W plasma jet increased signals for a range of test analytes, with enhancement factors of up to 68, without proportional increases in background levels. The changes in signal levels result from a combination of changes in the desorption kinetics from the surface and increased ion production in the gas phase. The enhancement in ADI-MS performance despite the quenching of key plasma species reported in earlier studies suggests that ionization with a H2/He plasma jet is the result of an alternate mechanism involving the direct generation of ionized hydrogen.

  20. Plasmas for environmental issues: from hydrogen production to 2D materials assembly

    Science.gov (United States)

    Tatarova, E.; Bundaleska, N.; Sarrette, J. Ph; Ferreira, C. M.

    2014-12-01

    It is well recognized at present that the unique, high energy density plasma environment provides suitable conditions to dissociate/atomize molecules in remediation systems, to convert waste and biomass into sustainable energy sources, to purify water, to assemble nanostructures, etc. The remarkable plasma potential is based on its ability to supply simultaneously high fluxes of charged particles, chemically active molecules, radicals (e.g. O, H, OH), heat, highly energetic photons (UV and extreme UV radiation), and strong electric fields in intrinsic sheath domains. Due to this complexity, low-temperature plasma science and engineering is a huge, highly interdisciplinary field that spans many research disciplines and applications across many areas of our daily life and industrial activities. For this reason, this review deals only with some selected aspects of low-temperature plasma applications for a clean and sustainable environment. It is not intended to be a comprehensive survey, but just to highlight some important works and achievements in specific areas. The selected issues demonstrate the diversity of plasma-based applications associated with clean and sustainable ambiance and also show the unity of the underlying science. Fundamental plasma phenomena/processes/features are the common fibers that pass across all these areas and unify all these applications. Browsing through different topics, we try to emphasize these phenomena/processes/features and their uniqueness in an attempt to build a general overview. The presented survey of recently published works demonstrates that plasma processes show a significant potential as a solution for waste/biomass-to-energy recovery problems. The reforming technologies based on non-thermal plasma treatment of hydrocarbons show promising prospects for the production of hydrogen as a future clean energy carrier. It is also shown that plasmas can provide numerous agents that influence biological activity. The simultaneous

  1. The possible role of hydrogen sulfide as a modulator of hemostatic parameters of plasma.

    Science.gov (United States)

    Olas, Beata; Kontek, Bogdan

    2014-09-05

    Hydrogen sulfide (H2S) is a well known toxic gas at high levels. However, at physiological levels, H2S may play a role in the pathogenesis of various cardiovascular diseases. The objective was to study the effects of exogenous H2S on the hemostatic parameters (coagulation and fibrinolytic activity) of human plasma. Human plasma was incubated (5, 15 and 30 min) with NaHS as a H2S donor at the final concentration of 0.01-100 μM. Hemostatic factors, such as maximum velocity of clot formation, fibrin lysis half-time, the activated partial thromboplastin time (APTT), prothrombin time (PT), and thrombin time (TT) were estimated. Moreover, the aim of our study was to establish the influence of NaHS (10 μM; 5, 15 and 30 min) on the clot formation using the purified fibrinogen. We demonstrated that coagulation/fibrinolytic properties of human plasma incubated with NaHS were changed. APPT, PT and TT of plasma treated with NaHS at tested concentrations--0.01-100 μM were prolonged. We observed that NaHS (0.01-100 μM) reduced fibrin polymerization in whole plasma and 10 μM NaHS also reduced polymerization of purified fibrinogen. In the presence of NaHS (at the low tested concentration--1 μM) the decrease was about 18% (in plasma, p<0.05). Our experiments also showed that NaHS (0.01-100 μM) stimulated the fibrin lysis in whole plasma. However, the time-dependent (5, 15 and 30 min) reduction of fibrin/fibrinogen polymerization and stimulation of fibrin lysis by NaHS (10 μM) was not observed. In conclusion, the present study demonstrates the anticoagulant properties of exogenous H2S in vitro.

  2. Growth of graphene on Cu foils by microwave plasma chemical vapor deposition: The effect of in-situ hydrogen plasma post-treatment

    Science.gov (United States)

    Fang, Liping; Yuan, Wen; Wang, Bing; Xiong, Ying

    2016-10-01

    Microwave plasma chemical vapor deposition (MPCVD) is a promising method for the large-scale production of high-quality graphene. The aim of this work is to investigate the effect of in-situ hydrogen plasma post-treatment on the MPCVD-grown graphene films. By simply varying the duration time of in-situ hydrogen plasma, surface morphology, number of layers and defect density of as-grown graphene films can be manipulated. The role of hydrogen plasma can be proposed from our observations, promoting to further grow graphene films in the early stage and consequently acting as an etching agent to thin graphene films in the later stage. On the basis of above mechanism, monolayer graphene films with low defect density and smooth surface can be grown by adjusting the times of the growing step and the plasma post-treatment step. This additional in-situ hydrogen plasma post-treatment may be significant for growing well-defined graphene films with controllable defects and number of layers.

  3. MM-wave cyclotron auto-resonance maser for plasma heating

    Energy Technology Data Exchange (ETDEWEB)

    Ceccuzzi, S.; Ravera, G. L.; Tuccillo, A. A. [Associazione Euratom-ENEA sulla Fusione, C.R. Frascati, Via Enrico Fermi 45, 00044, Frascati, Roma (Italy); Dattoli, G.; Di Palma, E.; Doria, A.; Gallerano, G. P.; Giovenale, E.; Spassovsky, I.; Surrenti, V. [ENEA UTAPRAD, C.R. Frascati, Via Enrico Fermi 45, 00044, Frascati, Roma (Italy); Mirizzi, F. [Consorzio CREATE, Via Claudio 21, 80125, Napoli (Italy)

    2014-02-12

    Heating and Current Drive systems are of outstanding relevance in fusion plasmas, magnetically confined in tokamak devices, as they provide the tools to reach, sustain and control burning conditions. Heating systems based on the electron cyclotron resonance (ECRH) have been extensively exploited on past and present machines DEMO, and the future reactor will require high frequencies. Therefore, high power (≥1MW) RF sources with output frequency in the 200 - 300 GHz range would be necessary. A promising source is the so called Cyclotron Auto-Resonance Maser (CARM). Preliminary results of the conceptual design of a CARM device for plasma heating, carried out at ENEA-Frascati will be presented together with the planned R and D development.

  4. MM-wave cyclotron auto-resonance maser for plasma heating

    Science.gov (United States)

    Ceccuzzi, S.; Dattoli, G.; Di Palma, E.; Doria, A.; Gallerano, G. P.; Giovenale, E.; Mirizzi, F.; Spassovsky, I.; Ravera, G. L.; Surrenti, V.; Tuccillo, A. A.

    2014-02-01

    Heating and Current Drive systems are of outstanding relevance in fusion plasmas, magnetically confined in tokamak devices, as they provide the tools to reach, sustain and control burning conditions. Heating systems based on the electron cyclotron resonance (ECRH) have been extensively exploited on past and present machines DEMO, and the future reactor will require high frequencies. Therefore, high power (≥1MW) RF sources with output frequency in the 200 - 300 GHz range would be necessary. A promising source is the so called Cyclotron Auto-Resonance Maser (CARM). Preliminary results of the conceptual design of a CARM device for plasma heating, carried out at ENEA-Frascati will be presented together with the planned R&D development.

  5. Crystal orientation effects on implantation of low-energy hydrogen, helium and hydrogen/helium mixtures in plasma-facing tungsten surfaces

    Science.gov (United States)

    Linn, Brian C.

    The development of plasma-facing materials (PFM) is one of the major challenges in. realizing fusion reactors. Materials deployed in PFMs must be capable of withstanding the high-flux of low-energy hydrogen and helium ions omitted from the plasma. while not hindering the plasma. Tungsten is considered a promising candidate material due to desirable material properties including its high melting temperature, good thermal conductivity and relatively low physical and chemical sputtering yields. This thesis uses molecular dynamic simulations to investigate helium and hydrogen bombardment of tungsten and the underlying physical effects (e.g. sputtering, erosion, blistering). Non-cumulative and cumulative bombardment simulations of helium, hydrogen, and hydrogen/helium bombardment of tungsten were modeled using the molecular dynamics code LAMMPS. Two orientations of monocrystalline bcc tungsten surfaces were considered, (001) and (111). Simulations were performed for temperatures ranging from 600K up to 1500K and helium / hydrogen incident energies of 20eV to 100eV . The results of these simulations showed the effect of temperature and incident particle energy on retention rates and implantation/deposition profiles in tungsten.

  6. Axisymmetric Alfvén resonances in a multi-component plasma at finite ion gyrofrequency

    Directory of Open Access Journals (Sweden)

    D. Yu. Klimushkin

    2006-05-01

    Full Text Available This paper deals with the spatial structure of zero azimuthal wave number ULF oscillations in a 1-D inhomogeneous multi-component plasma when a finite ion gyrofrequency is taken into account. Such oscillations may occur in the terrestrial magnetosphere as Pc1-3 waves or in the magnetosphere of the planet Mercury. The wave field was found to have a sharp peak on some magnetic surfaces, an analogy of the Alfvén (field line resonance in one-fluid MHD theory. The resonance can only take place for waves with frequencies in the intervals ω<ωch or Ω0<ω< ωcp, where ωch and ωcp are heavy and light ions gyrofrequencies, and Ω0 is a kind of hybrid frequency. Contrary to ordinary Alfvén resonance, the wave resonance under consideration takes place even at the zero azimuthal wave number. The radial component of the wave electric field has a pole-type singularity, while the azimuthal component is finite but has a branching point singularity on the resonance surface. The later singularity can disappear at some frequencies. In the region adjacent to the resonant surface the mode is standing across the magnetic shells.

  7. Compact Cryogenic Source of Periodic Hydrogen and Argon Droplet Beams for Intense Laser-Plasma Generation

    CERN Document Server

    Fraga, R A Costa; Kühnel, M; Hochhaus, D C; Schottelius, A; Polz, J; Kaluza, M C; Neumayer, P; Grisenti, R E

    2011-01-01

    We present a cryogenic source of periodic streams of micrometer-sized hydrogen (H2) and argon (Ar) droplets as ideal mass-limited target systems for fundamental intense laser-driven plasma applications. The highly compact design combined with a high temporal and spatial droplet stability makes our injector ideally suited for experiments using state-of-the-art low-repetition rate high-power lasers, in which a precise synchronization between the laser pulses and the droplets is mandatory. We demonstrate this explicitly by irradiating Ar droplets with pulses from a Petawatt laser.

  8. Compact cryogenic source of periodic hydrogen and argon droplet beams for relativistic laser-plasma generation

    Energy Technology Data Exchange (ETDEWEB)

    Fraga, R. A. Costa; Kalinin, A.; Kuehnel, M.; Schottelius, A. [Institut fuer Kernphysik, J. W. Goethe-Universitaet, Max-von-Laue-Str. 1, 60438 Frankfurt am Main (Germany); Hochhaus, D. C.; Neumayer, P. [EMMI Extreme Matter Institute and Research Division, GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, 64291 Darmstadt (Germany); FIAS Frankfurt Institute for Advanced Studies, J. W. Goethe-Universitaet, Ruth-Moufang-Str. 1, 60438 Frankfurt am Main (Germany); Polz, J. [Institut fuer Optik und Quantenelektronik, Max-Wien-Platz 1, 07743 Jena (Germany); Kaluza, M. C. [Institut fuer Optik und Quantenelektronik, Max-Wien-Platz 1, 07743 Jena (Germany); Helmholtz-Institut Jena, Froebelstieg 3, 07743 Jena (Germany); Grisenti, R. E. [Institut fuer Kernphysik, J. W. Goethe-Universitaet, Max-von-Laue-Str. 1, 60438 Frankfurt am Main (Germany); GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, 64291 Darmstadt (Germany)

    2012-02-15

    We present a cryogenic source of periodic streams of micrometer-sized hydrogen and argon droplets as ideal mass-limited target systems for fundamental intense laser-driven plasma applications. The highly compact design combined with a high temporal and spatial droplet stability makes our injector ideally suited for experiments using state-of-the-art high-power lasers in which a precise synchronization between the laser pulses and the droplets is mandatory. We show this by irradiating argon droplets with multi-terawatt pulses.

  9. Diagnosis of Hydrogen Plasma in a Miniature Penning Ion Source by Double Probes

    Institute of Scientific and Technical Information of China (English)

    JIN Dazhi; YANG Zhonghai; XIAO Kunxiang; DAI Jingyi

    2009-01-01

    Parameters of hydrogen plasma in a miniature Penning discharge ion source,including the electron temperature and the electron density,were measured by using double probes.The results indicate that the electron density increases and the electron temperature decreases with the increase in gas pressure and the discharge current.The electron temperature is about 5~9 eV and the electron density is 6.0x1013~1.2×1014 m-3 while the discharge current is in a range of 50~12μA.

  10. Time-dependent calculations of hydrogen spectral line shapes in dense plasmas

    Science.gov (United States)

    Olchawa, Wiesław

    2001-04-01

    A new formalism has been elaborated for calculations of hydrogen line profiles emitted by dense plasmas. Calculated line shapes are broadened, shifted and asymmetrical. The formalism is very general and yields full line shapes, shifts and widths at relatively small number of assumptions. For this purpose a new basis of the appropriate subspace of the Hilbert space has been built. This basis gives an accurate description of the quadratic Stark effect and the interaction of the emitter with field gradients. A computer simulation has been used to determine the emitter perturbations by electrons and ions. Final results have been compared with experimental and theoretical findings of other authors.

  11. Inactivation of possible microorganism food contaminants on packaging foils using nonthermal plasma and hydrogen peroxide

    Energy Technology Data Exchange (ETDEWEB)

    Scholtz, V., E-mail: Vladimir.Scholtz@vscht.cz; Khun, J. [Institute of Chemical Technology in Prague, Department of Physics and Measurements, Faculty of Chemical Engineering (Czech Republic); Soušková, H. [Institute of Chemical Technology in Prague, Department of Computing and Control Engineering, Faculty of Chemical Engineering (Czech Republic); Čeřovský, M. [Institute of Chemical Technology in Prague, Department of Food Preservation, Faculty of Food and Biochemical Technology (Czech Republic)

    2015-07-15

    The inactivation effect of nonthermal plasma generated in electric discharge burning in air atmosphere with water or hydrogen peroxide aerosol for the application to the microbial decontamination of packaging foils is studied. The microbial inactivation is studied on two bacterial, two yeasts, and two filamentous micromycete species. The inactivation of all contaminating microorganisms becomes on the area of full 8.5 cm in diameter circular sample after short times of several tens of seconds. Described apparatus may present a possible alternative method of microbial decontamination of food packaging material or other thermolabile materials.

  12. Phase shifts and the second virial coefficient for a partially ionized hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Omarbakiyeva, Y.A. [Institut fuer Physik, Universitaet Rostock, 18051 Rostock (Germany); IETP, al-Farabi Kazakh National University, 96a Tole bi str., 050012 Almaty (Kazakhstan); Roepke, G. [Institut fuer Physik, Universitaet Rostock, 18051 Rostock (Germany); Ramazanov, T.S. [IETP, al-Farabi Kazakh National University, 96a Tole bi str., 050012 Almaty (Kazakhstan)

    2009-12-15

    The influence of the interaction of electrons with hydrogen atoms on the thermodynamical properties of dense plasmas is investigated using a virial expansion approach. The second virial coefficient for the electron-atom interaction is obtained from the Beth-Uhlenbeck formula. Elastic scattering phase shifts are calculated with the help of the phase function method for different polarization potential models. Results for the second virial coefficient are given that take into account both the bound state part and the scattering state contribution (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  13. On the plasma confinement by acoustic resonance. An innovation for electrodeless high-pressure discharge lamps

    Science.gov (United States)

    Courret, Gilles; Nikkola, Petri; Wasterlain, Sébastien; Gudozhnik, Olexandr; Girardin, Michel; Braun, Jonathan; Gavin, Serge; Croci, Mirko; Egolf, Peter W.

    2017-08-01

    In an applied research project on the development of a pulsed microwave sulfur lamp prototype of 1 kW, we have discovered an amazing phenomenon in which the plasma forms a ball staying at the center of the bulb despite gravity, thus protecting the glass from melting. In this paper, it is shown that this results from an acoustic resonance in a spherical mode. Measurements of the plasma response to short pulses are presented showing beats at the spherical resonance. It is demonstrated that the beats could result from the simultaneous excitation of two normal modes with a frequency difference of approximately 1%. One of the two frequencies matches precisely the microwave pulses repetition, a little below 30 kHz. Thus this one is due to a forced oscillation, whereas the other one is due to a free oscillation. The phase velocity of sound was calculated as a function of temperature in order to find the series of temperatures at which a resonance would occur if the bulb were an isothermal solid sphere. The mean temperature inside the actual bulb was determined from the only doublet of this series, that has characteristic frequencies close enough to cause the observed beats. In addition, one of these two modes has a spherical symmetry that can explain the plasma ball formation. The obtained mean temperature is consistent with the direct measurements on the bulb surface as well as with the temperature in the core of a similar plasma found in the literature. We have also proposed a model of the resonance onset based on the acoustic dispersion and the sound amplification due to electromagnetic coupling.

  14. Hybrid electrodynamics and kinetics simulation for electromagnetic wave propagation in weakly ionized hydrogen plasmas.

    Science.gov (United States)

    Chen, Qiang; Chen, Bin

    2012-10-01

    In this paper, a hybrid electrodynamics and kinetics numerical model based on the finite-difference time-domain method and lattice Boltzmann method is presented for electromagnetic wave propagation in weakly ionized hydrogen plasmas. In this framework, the multicomponent Bhatnagar-Gross-Krook collision model considering both elastic and Coulomb collisions and the multicomponent force model based on the Guo model are introduced, which supply a hyperfine description on the interaction between electromagnetic wave and weakly ionized plasma. Cubic spline interpolation and mean filtering technique are separately introduced to solve the multiscalar problem and enhance the physical quantities, which are polluted by numerical noise. Several simulations have been implemented to validate our model. The numerical results are consistent with a simplified analytical model, which demonstrates that this model can obtain satisfying numerical solutions successfully.

  15. Design study of electron cyclotron resonance-ion plasma accelerator for heavy ion cancer therapy

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, T., E-mail: ttinoue@juntendo.ac.jp; Sugimoto, S.; Sasai, K. [Graduate School of Medicine, Juntendo University, Tokyo 113–8421 (Japan); Hattori, T. [National Institute of Radiological Sciences, Chiba 263–0024 (Japan)

    2014-02-15

    Electron Cyclotron Resonance-Ion Plasma Accelerator (ECR-IPAC) device, which theoretically can accelerate multiple charged ions to several hundred MeV with short acceleration length, has been proposed. The acceleration mechanism is based on the combination of two physical principles, plasma electron ion adiabatic ejection (PLEIADE) and Gyromagnetic Autoresonance (GYRAC). In this study, we have designed the proof of principle machine ECR-IPAC device and simulated the electromagnetic field distribution generating in the resonance cavity. ECR-IPAC device consisted of three parts, ECR ion source section, GYRAC section, and PLEIADE section. ECR ion source section and PLEIADE section were designed using several multi-turn solenoid coils and sextupole magnets, and GYRAC section was designed using 10 turns coil. The structure of ECR-IPAC device was the cylindrical shape, and the total length was 1024 mm and the maximum diameter was 580 mm. The magnetic field distribution, which maintains the stable acceleration of plasma, was generated on the acceleration center axis throughout three sections. In addition, the electric field for efficient acceleration of electrons was generated in the resonance cavity by supplying microwave of 2.45 GHz.

  16. Study of selective heating at ion cyclotron resonance for the plasma separation process

    Science.gov (United States)

    Compant La Fontaine, A.; Pashkovsky, V. G.

    1995-12-01

    The plasma separation process by ion cyclotron resonance heating (ICRH) is studied both theoretically and experimentally on two devices: the first one called ERIC (Ion Cyclotron Resonance Experiment) at Saclay (France) [P. Louvet, Proceedings of the 2nd Workshop on Separation Phenomena in Liquids and Gases, Versailles, France, 1989, edited by P. Louvet, P. Noe, and Soubbaramayer (Centre d'Etudes Nucléaires de Saclay and Cité Scientifique Parcs et Technopoles, Ile de France Sud, France, 1989), Vol. 1, p. 5] and the other one named SIRENA at the Kurchatov Institute, Moscow, Russia [A. I. Karchevskii et al., Plasma Phys. Rep. 19, 214 (1993)]. The radio frequency (RF) transversal magnetic field is measured by a magnetic probe both in plasma and vacuum and its Fourier spectrum versus the axial wave number kz is obtained. These results are in agreement with the electromagnetic (EM) field calculation model based on resolution of Maxwell equations by a time-harmonic scheme studied here. Various axial boundary conditions models used to compute the EM field are considered. The RF magnetic field is weakly influenced by the plasma while the electric field components are strongly disturbed due to space-charge effects. In the plasma the transversal electric field is enhanced and the kz spectrum is narrower than in vacuum. The calculation of the resonant isotope heating is made by the Runge-Kutta method. The influence of ion-ion collisions, inhomogeneity of the static magnetic field B0, and the RF transversal magnetic field component on the ion acceleration is examined. These results are successfully compared with experiments of a minor isotope 44Ca heating measurements, made with an energy analyzer.

  17. Study of selective heating at ion cyclotron resonance for the plasma separation process

    Energy Technology Data Exchange (ETDEWEB)

    Compant La Fontaine, A. [Direction du Cycle du Combustible/Departement des Procedes d` Enrichissement, Service de Physique, d` Experimentation et d` Analyse, Commissariat a l` Energie Atomique, Centre d` Etudes de Saclay, 91191 Gif-sur-Yvette Cedex (France); Pashkovsky, V.G. [Molecular Physics Institute, RRC Kurchatov Institute 123182, Moscow (Russian Federation)

    1995-12-01

    The plasma separation process by ion cyclotron resonance heating (ICRH) is studied both theoretically and experimentally on two devices: the first one called ERIC (Ion Cyclotron Resonance Experiment) at Saclay (France) [P. Louvet, {ital Proceedings} {ital of} {ital the} 2{ital nd} {ital Workshop} {ital on} {ital Separation} {ital Phenomena} {ital in} {ital Liquids} {ital and} {ital Gases}, Versailles, France, 1989, edited by P. Louvet, P. Noe, and Soubbaramayer (Centre d`Etudes Nucleaires de Saclay and Cite Scientifique Parcs et Technopoles, Ile de France Sud, France, 1989), Vol. 1, p. 5] and the other one named SIRENA at the Kurchatov Institute, Moscow, Russia [A. I. Karchevskii {ital et} {ital al}., Plasma Phys. Rep. {bold 19}, 214 (1993)]. The radio frequency (RF) transversal magnetic field is measured by a magnetic probe both in plasma and vacuum and its Fourier spectrum versus the axial wave number {ital k}{sub {ital z}} is obtained. These results are in agreement with the electromagnetic (EM) field calculation model based on resolution of Maxwell equations by a time-harmonic scheme studied here. Various axial boundary conditions models used to compute the EM field are considered. The RF magnetic field is weakly influenced by the plasma while the electric field components are strongly disturbed due to space-charge effects. In the plasma the transversal electric field is enhanced and the {ital k}{sub {ital z}} spectrum is narrower than in vacuum. The calculation of the resonant isotope heating is made by the Runge--Kutta method. The influence of ion--ion collisions, inhomogeneity of the static magnetic field {ital B}{sub 0}, and the RF transversal magnetic field component on the ion acceleration is examined. These results are successfully compared with experiments of a minor isotope {sup 44}Ca heating measurements, made with an energy analyzer. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  18. Electron density and temperature measurements in a magnetized expanding hydrogen plasma

    Science.gov (United States)

    Leyte-González, R.; Palomares, J. M.; Schram, D. C.; Engeln, R.

    2016-08-01

    We report measurements of electron densities, ne, and temperatures, Te, in a magnetized expanding hydrogen plasma performed using Thomson scattering. The effects of applying an axial magnetic field and changing the background pressure in the plasma vessel on ne and Te along the expansion axis are reported. Magnetic field strengths (B field) up to 170 mT were applied, which are one order of magnitude larger than previously reported. The main effect of the applied B field is the plasma confinement, which leads to higher ne. At B fields larger than 88 mT the electron density along the expansion axis does not depend strongly on the magnetic field strength. However, Te is susceptible to the B field and reaches at 170 mT a maximum of 2.5 eV at a distance of 1.5 cm from the exit of the cascaded arc. To determine also the effect of the arc current through the arc, measurements were performed with arc currents of 45, 60, and 75 A at background pressures of 9.7 and 88.3 Pa. At constant magnetic field ne decreases from the exit of the arc along the expansion axis when the arc current is decreased. At 88.3 Pa ne shows a higher value close to the exit of the arc, but a faster decay along the expansion axis with respect to the 9.7 Pa case. Te is overall higher at lower pressure reaching a maximum of 3.2 eV at the lower arc current of 45 A. The results of this study complement our understanding and the characterization of expanding hydrogen plasmas.

  19. Oxidation of Inconel 625 superalloy upon treatment with oxygen or hydrogen plasma at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Vesel, Alenka; Drenik, Aleksander; Elersic, Kristina; Mozetic, Miran; Kovac, Janez [Jozef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Gyergyek, Tomaz [University of Ljubljana, Faculty of Electrical Engineering, Trzaska 25, SI-1000 Ljubljana (Slovenia); Stockel, Jan; Varju, Jozef; Panek, Radomir [Institute of Plasma Physics, Academy of Sciences of the Czech Republic, Ze Slovankou 3, Praha 8 (Czech Republic); Balat-Pichelin, Marianne, E-mail: marianne.balat@promes.cnrs.fr [PROMES-CNRS Laboratory, 7 rue du four solaire, 66120 Font Romeu Odeillo (France)

    2014-06-01

    Initial stages of Inconel 625 superalloy (Ni{sub 60}Cr{sub 30}Mo{sub 10}Ni{sub 4}Nb{sub 1}) oxidation upon short treatment with gaseous plasma at different temperatures up to about 1600 K were studied. Samples were treated for different periods up to a minute by oxygen or hydrogen plasma created with a microwave discharge in the standing-wave mode at a pressure of 40 Pa and a power 500 W. Simultaneous heating of the samples was realized by focusing concentrated solar radiation from a 5 kW solar furnace directly onto the samples. The morphological changes upon treatment were monitored using scanning electron microscopy, compositional depth profiling was performed using Auger electron spectroscopy, while structural changes were determined by X-ray diffraction. The treatment in oxygen plasma caused formation of metal oxide clusters of three dimensional crystallites initially rich in nickel oxide with the increasing chromium oxide content as the temperature was increasing. At about 1100 K iron and niobium oxides prevailed on the surface causing a drop of the material emissivity at 5 μm. Simultaneously the NiCr{sub 2}O{sub 4} compound started growing at the interface between the oxide film and bulk alloy and the compound persisted up to temperatures close to the Inconel melting point. Intensive migration of minority alloying elements such as Fe and Ti was observed at 1600 K forming mixed surface oxides of sub-micrometer dimensions. The treatment in hydrogen plasma with small admixture of water vapor did not cause much modification unless the temperature was close to the melting point. At such conditions aluminum segregated on the surface and formed well-defined Al{sub 2}O{sub 3} crystals.

  20. Electron transport in the plasma edge with rotating resonant magnetic perturbations at the TEXTOR tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Stoschus, Henning

    2011-10-13

    Small three-dimensional (3D) magnetic perturbations can be used as a tool to control the edge plasma parameters in magnetically confined plasmas in high confinement mode (''H-mode'') to suppress edge instabilities inherent to this regime, the Edge Localized Modes (ELMs). In this work, the impact of rotating 3D resonant magnetic perturbation (RMP) fields on the edge plasma structure characterized by electron density and temperature fields is investigated. We study a low confinement (L-mode) edge plasma (r/a>0.9) with high resistivity (edge electron collisionality {nu}{sup *}{sub e}>4) at the TEXTOR tokamak. The plasma structure in the plasma edge is measured by a set of high resolution diagnostics: a fast CCD camera ({delta}t=20 {mu}s) is set up in order to visualize the plasma structure in terms of electron density variations. A supersonic helium beam diagnostic is established as standard diagnostic at TEXTOR to measure electron density n{sub e} and temperature T{sub e} with high spatial ({delta}r=2 mm) and temporal resolution ({delta}t=20 {mu}s). The measured plasma structure is compared to modeling results from the fluid plasma and kinetic neutral transport code EMC3-EIRENE. A sequence of five new observations is discussed: (1) Imaging of electron density variations in the plasma edge shows that a fast rotating RMP field imposes an edge plasma structure, which rotates with the external RMP rotation frequency of vertical stroke {nu}{sub RMP} vertical stroke =1 kHz. (2) Measurements of the electron density and temperature provide strong experimental evidence that in the far edge a rotating 3D scrape-off layer (SOL) exists with helical exhaust channels to the plasma wall components. (3) Radially inward, the plasma structure at the next rational flux surface is found to depend on the relative rotation between external RMP field and intrinsic plasma rotation. For low relative rotation the plasma structure is dominated by a particle and energy loss

  1. Production of electron cyclotron resonance plasma by using multifrequencies microwaves and active beam profile control on a large bore electron cyclotron resonance ion source with permanent magnets.

    Science.gov (United States)

    Kato, Yushi; Watanabe, Takeyoshi; Matsui, Yuuki; Hirai, Yoshiaki; Kutsumi, Osamu; Sakamoto, Naoki; Sato, Fuminobu; Iida, Toshiyuki

    2010-02-01

    A new concept on magnetic field with all magnets on plasma production and confinement has been proposed to enhance efficiency of an electron cyclotron resonance (ECR) plasma for broad and dense ion beam source under the low pressure. The magnetic field configuration is constructed by a pair of magnets assembly, i.e., comb-shaped magnet which cylindrically surrounds the plasma chamber. The resonance zones corresponding to the fundamental ECR for 2.45 GHz and 11-13 GHz frequencies are constructed at different positions. The profiles of the plasma parameters in the ECR ion source are different from each frequency of microwave. Large bore extractor is set at the opposite side against the microwave feeds. It is found that differences of their profiles also appear at those of ion beam profiles. We conducted to launch simultaneously multiplex frequencies microwaves controlled individually, and tried to control the profiles of the plasma parameters and then those of extracted ion beam.

  2. Plasma-chemical treatment of hydrogen sulfide in natural gas processing. Final report, May 1991--December 1992

    Energy Technology Data Exchange (ETDEWEB)

    Harkness, J.B.L.; Doctor, R.D. [Argonne National Lab., IL (United States)

    1993-05-01

    A new process for the treatment of hydrogen sulfide waste that uses microwave plasma-chemical technology has been under development in Russia and the United States. Whereas the present waste-treatment technology, at best, only recovers sulfur, this novel process recovers both hydrogen and sulfur by dissociating hydrogen sulfide in a plasma by means of a microwave or radio-frequency reactor. A research project has been undertaken to determine the suitability of the plasma process in natural gas processing applications. The experiments tested acid-gas compositions with 30--65% carbon dioxide, 0--7% water, and 0--0.2% of a standard mixture of pipeline gas. The balance gas in all cases was hydrogen sulfide. The reactor pressure for the experiments was 50 torr, and the microwave power was 1.0 kW. Conversions of hydrogen sulfide ranged from 80 to 100%, while 35--50% of the carbon dioxide was converted to carbon monoxide. This conversion of carbon dioxide resulted in a loss of hydrogen production and an energy loss from a hydrogen sulfide waste-treatment perspective. Tests of a direct natural gas treatment concept showed that hydrocarbon losses were unacceptably high; consequently, the concept would not be economically viable.

  3. Etching of a-Si:H thin films by hydrogen plasma: A view from in situ spectroscopic ellipsometry

    Energy Technology Data Exchange (ETDEWEB)

    Hadjadj, Aomar, E-mail: aomar.hadjadj@univ-reims.fr; Larbi, Fadila; Gilliot, Mickaël [Laboratoire d’Ingénierie et Sciences des Matériaux (LISM, EA 4695), Université de Reims Champagne-Ardenne (France); Roca i Cabarrocas, Pere [Laboratoire de Physique des Interfaces et Couches Minces (LPICM, CNRS UMR 7647), Ecole Polytechnique (France)

    2014-08-28

    When atomic hydrogen interacts with hydrogenated amorphous silicon (a-Si:H), the induced modifications are of crucial importance during a-Si:H based devices manufacturing or processing. In the case of hydrogen plasma, the depth of the modified zone depends not only on the plasma processing parameters but also on the material. In this work, we exposed a-Si:H thin films to H{sub 2} plasma just after their deposition. In situ UV-visible spectroscopic ellipsometry measurements were performed to track the H-induced changes in the material. The competition between hydrogen insertion and silicon etching leads to first order kinetics in the time-evolution of the thickness of the H-modified zone. We analyzed the correlation between the steady state structural parameters of the H-modified layer and the main levers that control the plasma-surface interaction. In comparison with a simple doped layer, exposure of a-Si:H based junctions to the same plasma treatment leads to a thinner H-rich subsurface layer, suggesting a possible charged state of hydrogen diffusing.

  4. Etching of a-Si:H thin films by hydrogen plasma: a view from in situ spectroscopic ellipsometry.

    Science.gov (United States)

    Hadjadj, Aomar; Larbi, Fadila; Gilliot, Mickaël; Roca i Cabarrocas, Pere

    2014-08-28

    When atomic hydrogen interacts with hydrogenated amorphous silicon (a-Si:H), the induced modifications are of crucial importance during a-Si:H based devices manufacturing or processing. In the case of hydrogen plasma, the depth of the modified zone depends not only on the plasma processing parameters but also on the material. In this work, we exposed a-Si:H thin films to H2 plasma just after their deposition. In situ UV-visible spectroscopic ellipsometry measurements were performed to track the H-induced changes in the material. The competition between hydrogen insertion and silicon etching leads to first order kinetics in the time-evolution of the thickness of the H-modified zone. We analyzed the correlation between the steady state structural parameters of the H-modified layer and the main levers that control the plasma-surface interaction. In comparison with a simple doped layer, exposure of a-Si:H based junctions to the same plasma treatment leads to a thinner H-rich subsurface layer, suggesting a possible charged state of hydrogen diffusing.

  5. Resonant charge transfer of hydrogen Rydberg atoms incident at a Cu(100) projected band-gap surface

    CERN Document Server

    Gibbard, J A; Kohlhoff, M; Rennick, C J; So, E; Ford, M; Softley, T P

    2015-01-01

    The charge transfer (ionization) of hydrogen Rydberg atoms (principal quantum number $n=25-34$) incident at a Cu(100) surface is investigated. Unlike fully metallic surfaces, where the Rydberg electron energy is degenerate with the conduction band of the metal, the Cu(100) surface has a projected bandgap at these energies, and only discrete image states are available through which charge transfer can take place. Resonant enhancement of charge transfer is observed at hydrogen principal quantum numbers for which the Rydberg energy matches the energy of one of the image states. The integrated surface ionization signals show clear periodicity as the energies of states with increasing $n$ come in and out of resonance with the image states. The velocity dependence of the surface ionization dynamics is also investigated. Decreased velocity of the incident H atom leads to a greater mean distance of ionization and a lower field required to extract the ion. The surface-ionization profiles (signal versus applied field) ...

  6. Collisional damping of helicon waves in a high density hydrogen linear plasma device

    Science.gov (United States)

    Caneses, Juan F.; Blackwell, Boyd D.

    2016-10-01

    In this paper, we investigate the propagation and damping of helicon waves along the length (50 cm) of a helicon-produced 20 kW hydrogen plasma ({{n}\\text{e}}∼ 1–2 × 1019 m‑3, {{T}\\text{e}}∼ 1–6 eV, H2 8 mTorr) operated in a magnetic mirror configuration (antenna region: 50–200 G and mirror region: 800 G). Experimental results show the presence of traveling helicon waves (4–8 G and {λz}∼ 10–15 cm) propagating away from the antenna region which become collisionally absorbed within 40–50 cm. We describe the use of the WKB method to calculate wave damping and provide an expression to assess its validity based on experimental measurements. Theoretical calculations are consistent with experiment and indicate that for conditions where Coulomb collisions are dominant classical collisionality is sufficient to explain the observed wave damping along the length of the plasma column. Based on these results, we provide an expression for the scaling of helicon wave damping relevant to high density discharges and discuss the location of surfaces for plasma-material interaction studies in helicon based linear plasma devices.

  7. Discontinuity of mode transition and hysteresis in hydrogen inductively coupled plasma via a fluid model

    Institute of Scientific and Technical Information of China (English)

    徐会静; 赵书霞; 高飞; 张钰如; 李雪春; 王友年

    2015-01-01

    A new type of two-dimensional self-consistent fluid model that couples an equivalent circuit module is used to in-vestigate the mode transition characteristics and hysteresis in hydrogen inductively coupled plasmas at different pressures, by varying the series capacitance of the matching box. The variations of the electron density, temperature, and the cir-cuit electrical properties are presented. As cycling the matching capacitance, at high pressure both the discontinuity and hysteresis appear for the plasma parameters and the transferred impedances of both the inductive and capacitive discharge components, while at low pressure only the discontinuity is seen. The simulations predict that the sheath plays a determi-native role on the presence of discontinuity and hysteresis at high pressure, by influencing the inductive coupling efficiency of applied power. Moreover, the values of the plasma transferred impedances at different pressures are compared, and the larger plasma inductance at low pressure due to less collision frequency, as analyzed, is the reason why the hysteresis is not seen at low pressure, even with a wider sheath. Besides, the behaviors of the coil voltage and current parameters during the mode transitions are investigated. They both increase (decrease) at the E to H (H to E) mode transition, indicating an improved (worsened) inductive power coupling efficiency.

  8. Fossil fuel and hydrocarbon conversion using hydrogen-rich plasmas. Topical report February 1994--February 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    Experiments were made on use of H and CH plasmas for converting waste materials and heavy oils to H-rich transportation fuels. Batch and continuous experiments were conducted with an industrial microwave generator and a commercial microwave oven. A continuously circulating reactor was constructed for conducting experiments on flowing oils. Experiments on decomposition of scrap tires showed that microwave plasmas can be used to decompose scrap tires into potentially useful liquid products. In a batch experiment using a commercial microwave oven, about 20% of the tire was converted to liquid products in about 9 minutes. Methane was decomposed in a microwave plasma to yield a liquid products composed of various compound types; GC/MS analyses identified unsaturated compounds including benzene, toluene, ethyl benzene, methyl and ethyl naphthalene, small amounts of larger aromatic rings, and olefinic compounds. Experiments on a crude oil in a continuously flowing reactor showed that distillate materials are produced using H and CH plasmas. Also, the recycle oils had an overall carbon aromaticity lower than that of starting feed material, indicating that some hydrogenation and methanation had taken place in the recycle oils.

  9. In-situ hydrogen and oxygen plasma purification of carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Mi Hyun; Kim, Yang Do; Jeon, Hyeong Tag [Hanyang Univ., Seoul (Korea, Republic of)

    2001-12-01

    Bulk bundles, which are obtained after purification of carbon soot containing nanotubes (CNTs), are commonly used as electron emitters. However, CNTs grown by chemical vapor deposition (CVD) at low temperature using a nickel (Ni) catalyst still contain impurities, such as amorphous carbon and catalytic metal particles, and need to be purified. We grew CNTs on silicon substrates with native oxides by using a Ni catalyst and plasma-enhanced CVD at 600 .deg. C with a mixture of CH{sub 4}, NH{sub 3}, and H{sub 2} gases. CNTs were observed to have multi-wall structures with large inside hollow cores containing Ni. CNTs with a typical dimension of a few tens of nm in diameter and several m in length were observed. In-situ hydrogen plasma treatment successfully removed the residual carbonaceous particles and metallic impurities without significant structural damage to the individual CNTs. This study demonstrated a simple and efficient in-situ plasma purification process for CNTs grown by using plasma-enhanced CVD.

  10. Discontinuity of mode transition and hysteresis in hydrogen inductively coupled plasma via a fluid model

    Science.gov (United States)

    Xu, Hui-Jing; Zhao, Shu-Xia; Fei, Gao; Yu-Ru, Zhang; Xue-Chun, Li; You-Nian, Wang

    2015-11-01

    A new type of two-dimensional self-consistent fluid model that couples an equivalent circuit module is used to investigate the mode transition characteristics and hysteresis in hydrogen inductively coupled plasmas at different pressures, by varying the series capacitance of the matching box. The variations of the electron density, temperature, and the circuit electrical properties are presented. As cycling the matching capacitance, at high pressure both the discontinuity and hysteresis appear for the plasma parameters and the transferred impedances of both the inductive and capacitive discharge components, while at low pressure only the discontinuity is seen. The simulations predict that the sheath plays a determinative role on the presence of discontinuity and hysteresis at high pressure, by influencing the inductive coupling efficiency of applied power. Moreover, the values of the plasma transferred impedances at different pressures are compared, and the larger plasma inductance at low pressure due to less collision frequency, as analyzed, is the reason why the hysteresis is not seen at low pressure, even with a wider sheath. Besides, the behaviors of the coil voltage and current parameters during the mode transitions are investigated. They both increase (decrease) at the E to H (H to E) mode transition, indicating an improved (worsened) inductive power coupling efficiency. Project supported by the National Natural Science Foundation of China (Grant Nos. 11175034, 11205025, 11305023, and 11075029).

  11. Anti-tumor Effects of Plasma Activated Media and Correlation with Hydrogen Peroxide Concentration

    Science.gov (United States)

    Laroussi, Mounir; Mohades, Soheila; Barekzi, Nazir; Maruthamuthu, Venkat; Razavi, Hamid

    2016-09-01

    Plasma activated media (PAM) can induce death in cancer cells. In our research, PAM is produced by exposing liquid culture medium to a helium plasma pencil. Reactive oxygen and nitrogen species in the aqueous state are known factors in anti-tumor effects of PAM. The duration of plasma exposure determines the concentrations of reactive species produced in PAM. Stability of the plasma generated reactive species and their lifetime depend on parameters such as the chemical composition of the medium. Here, a complete cell culture medium was employed to make PAM. Later, PAM was used to treat SCaBER cancer cells either as an immediate PAM (right after exposure) or as an aged-PAM (after storage). SCaBER (ATCC®HTB-3™) is an epithelial cell line from a human bladder with the squamous carcinoma disease. A normal epithelial cell line from a kidney tissue of a dog - MDCK (ATCC®CCL-34™) - was used to analyze the selective effect of PAM. Correspondingly, we measured the concentration of hydrogen peroxide- as a stable species with biological impact on cell viability- in both immediate PAM and aged-PAM. In addition, we report on the effect of serum supplemented in PAM on the H2O2 concentration measured by Amplex red assay kit. Finally, we evaluate the effects of PAM on growth and morphological changes in MDCK cells using fluorescence microscopy.

  12. Numerical studies from quantum to macroscopic scales of carbon nanoparticules in hydrogen plasma

    Science.gov (United States)

    Lombardi, Guillaume; Ngandjong, Alain; Mezei, Zsolt; Mougenot, Jonathan; Michau, Armelle; Hassouni, Khaled; Seydou, Mahamadou; Maurel, François

    2016-09-01

    Dusty plasmas take part in large scientific domains from Universe Science to nanomaterial synthesis processes. They are often generated by growth from molecular precursor. This growth leads to the formation of larger clusters which induce solid germs nucleation. Particle formed are described by an aerosol dynamic taking into account coagulation, molecular deposition and transport processes. These processes are controlled by the elementary particle. So there is a strong coupling between particle dynamics and plasma discharge equilibrium. This study is focused on the development of a multiscale physic and numeric model of hydrogen plasmas and carbon particles around three essential coupled axes to describe the various physical phenomena: (i) Macro/mesoscopic fluid modeling describing in an auto-coherent way, characteristics of the plasma, molecular clusters and aerosol behavior; (ii) the classic molecular dynamics offering a description to the scale molecular of the chains of chemical reactions and the phenomena of aggregation; (iii) the quantum chemistry to establish the activation barriers of the different processes driving the nanopoarticule formation.

  13. Effect of resonant magnetic perturbations on ELMs in connected double null plasmas in MAST

    Science.gov (United States)

    Kirk, A.; Liu, Yueqiang; Chapman, I. T.; Harrison, J.; Nardon, E.; Scannell, R.; Thornton, A. J.; the MAST Team

    2013-04-01

    The application of resonant magnetic perturbations (RMPs) with a toroidal mode number of n = 3 to connected double null plasmas in the MAST tokamak produces up to a factor of 9 increase in edge-localized mode (ELM) frequency and reduction in plasma energy loss associated with type-I ELMs. A threshold current for ELM mitigation is observed above which the ELM frequency increases approximately linearly with current in the coils. The effect of the RMPs is found to be scenario dependent. In one scenario the mitigation is only due to a large density pump out event and if the density is recovered by gas puffing a return to type-I ELMs is observed. In another scenario sustained ELM mitigation can be achieved irrespective of the amount of fuelling. Despite a large scan of parameters complete ELM suppression has not been achieved. The results are compared with modelling performed using either the vacuum approximation or including the plasma response. The requirement for a resonant condition, that is an optimum alignment of the perturbation with the plasma, is confirmed by performing a scan in the pitch angle of the applied field.

  14. Diagnostics of recombining laser plasma parameters based on He-like ion resonance lines intensity ratios

    Science.gov (United States)

    Ryazantsev, S. N.; Skobelev, I. Yu; Faenov, A. Ya; Pikuz, T. A.; Grum-Grzhimailo, A. N.; Pikuz, S. A.

    2016-11-01

    While the plasma created by powerful laser expands from the target surface it becomes overcooled, i.e. recombining one. Improving of diagnostic methods applicable for such plasma is rather important problem in laboratory astrophysics nowadays because laser produced jets are fully scalable to young stellar objects. Such scaling is possible because of the plasma hydrodynamic equations invariance under some transformations. In this paper it is shown that relative intensities of the resonance transitions in He-like ions can be used to measure the parameters of recombining plasma. Intensity of the spectral lines corresponding to these transitions is sensitive to the density in the range of 1016-1020 cm-3 while the temperature ranges from 10 to 100 eV for ions with nuclear charge Zn ∼ 10. Calculations were carried out for F VIII ion and allowed to determine parameters of plasma jets created by nanosecond laser system ELFIE (Ecole Polytechnique, France) for astrophysical phenomenon modelling. Obtained dependencies are quite universal and can be used for any recombining plasma containing He-like fluorine ions.

  15. Resonant-magnetic-perturbation-induced plasma transport in H-mode pedestals

    Energy Technology Data Exchange (ETDEWEB)

    Callen, J. D.; Hegna, C. C. [University of Wisconsin, 1500 Engineering Drive, Madison, Wisconsin 53706-1609 (United States); Cole, A. J. [Columbia University, 201 S.W. Mudd, New York, New York 10027 (United States)

    2012-11-15

    Plasma toroidal rotation reduces reconnection of externally applied resonant magnetic perturbation (RMP) fields {delta}B on rational (q = m/n) magnetic flux surfaces. Hence, it causes radial perturbations {delta}B{sub {rho}m/n} to be small there, and thus inhibits magnetic island formation and stochasticity in the edge of high (H-) mode confinement tokamak plasmas. However, electron collisional damping combined with the spatial magnetic flutter {delta}B{sub {rho}m/n} induced by RMPs in the vicinity of rational surfaces causes a radial electron heat diffusivity in which {chi}{sub e Parallel-To }{sup eff}{approx}(v{sub Te}{sup 2}/{nu}{sub e})/(1+x{sup 2}/{delta}{sub Parallel-To }{sup 2}) is an effective parallel electron thermal diffusivity. These effects are reduced by magnetic shear effects at a distance x from rational surfaces for |x|>{delta}{sub Parallel-To} but amplified for {delta}B-caret{sub {rho}m/n}(x)>{delta}B-caret{sub {rho}m/n}(0). A kinetic, toroidal model of these RMP-flutter-induced plasma transport effects is developed and compared to a previously developed cylindrical model. The RMP-induced increases in plasma transport can be large enough to reduce plasma gradients in H-mode pedestals. Thus, they may contribute to suppressing edge localized modes in tokamak plasmas.

  16. Ultrathin oxide grown on polysilicon by using an electron cyclotron resonance N sub 2 O plasma

    CERN Document Server

    Han, S Y

    2000-01-01

    We have developed a process for growing ultrathin oxide on a polysilicon layer by using an electron cyclotron resonance (ECR) N sub 2 O plasma. Sub-4-nm thick polyoxides were grown on n sup + and p sup + polysilicon layers and were characterized. These oxides had larger breakdown fields, smaller electron trapping characteristics, and larger Q sub B sub D values than those of thermal polyoxides. The electron trapping characteristics of ECR N sub 2 O plasma polyoxides, which were smaller than those of thermal polyoxides at positive bias, resulted from the smaller roughness of the polysilicon surface after the oxidation process. Under a negative constant-current stress of 20 mA/cm sup 2 for polyoxide on p sup + polysilicon were obtained. These ultrathin plasma polyoxides would be good candidates for future inter-poly dielectrics and gate oxides for thin film transistors.

  17. Intrinsic Kinetics of Dimethyl Ether Synthesis from Plasma Activation of CO2 Hydrogenation over Cu-Fe-Ce/HZSM-5.

    Science.gov (United States)

    Su, Tongming; Zhou, Xinhui; Qin, Zuzeng; Ji, Hongbing

    2017-02-02

    CO2 is activated in a plasma reactor followed by hydrogenation over a Cu-Fe-Ce/HZSM-5 catalyst, and the intrinsic kinetics of the plasma catalytic process are studied. Compared with CO2 hydrogenation using Cu-Fe-Ce/HZSM-5 alone, the CO2 conversion and the dimethyl ether selectivity for the plasma catalytic process are increased by 16.3 %, and 10.1 %, respectively, indicating that the CO2 was activated by the plasma to promote hydrogenation. A study of the intrinsic kinetics shows that the activation energies of methanol formation, the reverse water-gas shift reaction, and methanol dehydration to dimethyl ether are 149.34, 75.47, and 73.18 kJ mol(-1) , respectively, which are lower than if Cu-Fe-Ce/HZSM-5 is used without plasma, indicating that the activation of CO2 in the plasma reduces the activation energy of the hydrogenation reaction and improves the yield of dimethyl ether.

  18. Hydrogen uptake from plasma and its effect on EUROFER 97 and ODS-EUROFER steels at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Malitckii, Evgenii, E-mail: evgeny.malitskiy@aalto.fi; Yagodzinskyy, Yuriy; Hänninen, Hannu

    2015-10-15

    Highlights: • Dispersion strengthening increases markedly the hydrogen uptake of the ODS steel. • Hydrogen reduces markedly the elongation to fracture of both studied steels at RT. • EUROFER 97 steel manifests similar sensitivity to hydrogen at RT and 300 °C. • ODS-EUROFER steel is less sensitive to HE at temperature of 300 °C. • Hydrogen has only minor effect on tensile strength at elevated temperatures. - Abstract: Hydrogen effects on the mechanical properties of the ferrite-martensite EUROFER 97 and oxide dispersion strengthened ODS-EUROFER steels were studied under continuous hydrogen charging from hydrogen-enriched plasma at temperatures up to 300 °C. Hydrogen uptake measured using thermal desorption spectroscopy was found to be markedly higher in ODS-EUROFER steel in comparison to that in EUROFER 97 steel evidencing on high hydrogen trapping ability of the oxide-dispersion strengthening yttria nanoparticles. It is found that EUROFER 97 and ODS-EUROFER steels manifest rather different sensitivity to hydrogen embrittlement with increase of temperature. It is shown that increase of the temperature up to 300 °C decreases the hydrogen effects on the mechanical properties of ODS-EUROFER steel, while sensitivity to hydrogen of EUROFER 97 steel remains the same as at room temperature. FEG-SEM fractography was performed to investigate of the hydrogen-induced fracture mode at elevated testing temperatures. Possible role of the interface between yttria nanoparticles and steel matrix and the distribution of yttria nanoparticles in the hydrogen embrittlement mechanism are discussed.

  19. Resonant laser ablation of metals detected by atomic emission in a microwave plasma and by inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Cleveland, Danielle; Stchur, Peter; Hou, Xiandeng; Yang, Karl X; Zhou, Jack; Michel, Robert G

    2005-12-01

    It has been shown that an increase in sensitivity and selectivity of detection of an analyte can be achieved by tuning the ablation laser wavelength to match that of a resonant gas-phase transition of that analyte. This has been termed resonant laser ablation (RLA). For a pulsed tunable nanosecond laser, the data presented here illustrate the resonant enhancement effect in pure copper and aluminum samples, chromium oxide thin films, and for trace molybdenum in stainless steel samples, and indicate two main characteristics of the RLA phenomenon. The first is that there is an increase in the number of atoms ablated from the surface. The second is that the bandwidth of the wavelength dependence of the ablation is on the order of 1 nm. The effect was found to be virtually identical whether the atoms were detected by use of a microwave-induced plasma with atomic emission detection, by an inductively coupled plasma with mass spectrometric detection, or by observation of the number of laser pulses required to penetrate through thin films. The data indicate that a distinct ablation laser wavelength dependence exists, probably initiated via resonant radiation trapping, and accompanied by collisional broadening. Desorption contributions through radiation trapping are substantiated by changes in crater morphology as a function of wavelength and by the relatively broad linewidth of the ablation laser wavelength scans, compared to gas-phase excitation spectra. Also, other experiments with thin films demonstrate the existence of a distinct laser-material interaction and suggest that a combination of desorption induced by electronic transition (DIET) with resonant radiation trapping could assist in the enhancement of desorption yields. These results were obtained by a detailed inspection of the effect of the wavelength of the ablation laser over a narrow range of energy densities that lie between the threshold of laser-induced desorption of species and the usual analytical

  20. Simulation of the Partially Ionized Reacting Plasma Flow in a Negative Hydrogen Ion Source

    Science.gov (United States)

    Gatsonis, Nikolaos; Averkin, Sergey; Olson, Lynn

    2012-10-01

    A High Pressure Discharge Negative Ion Source (HPDNIS) operating on hydrogen is been under investigation. The Negative Ion Production (NIP) section of the HPDNIS attaches to the 10-100 Torr RF-discharge chamber with a micronozzle and ends with a grid that extracts the negative ion beam. The partially ionized and reacting plasma flow in the NIP section is simulated using an unstructured three-dimensional Direct Simulation Monte Carlo (U3DSMC) code. The NIP section contains a low-pressure plasma that includes H2, vibrationally-rotationally excited H2^*, negative hydrogen atoms H^-, and electrons. Primary reactions in the NIP section are dissociate attachment, H2^*+e->H^0+H^-and electron collisional detachment, e+H^-->H+2e. The U3DSMC computational domain includes the entrance to the NIP nozzle and the extraction grid at the exit. The flow parameters at the entrance are based on conditions in the RF-discharge chamber and are implemented in U3DSMC using a Kinetic-Moment subsonic boundary conditions method. The rotational and vibrational degrees of freedom in U3DSMC are implemented using the Larsen-Borgnakke model. Chemical reactions are implemented in U3DSMC using the Quantum-Kinetic model. Simulations cover the regime of operation of the HPDNIS and examine the flow characteristics inside the NIP section.

  1. Electron cyclotron resonance ion source plasma chamber studies using a network analyzer as a loaded cavity probe

    Energy Technology Data Exchange (ETDEWEB)

    Toivanen, V.; Tarvainen, O.; Kauppinen, J.; Komppula, J.; Koivisto, H. [Department of Physics, University of Jyvaeskylae, Jyvaeskylae 40500 (Finland); Lyneis, C. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    2012-02-15

    A method and first results utilizing a network analyzer as a loaded cavity probe to study the resonance properties of a plasma filled electron cyclotron resonance ion source (ECRIS) plasma chamber are presented. The loaded cavity measurements have been performed using a dual port technique, in which two separate waveguides were used simultaneously. One port was used to ignite and sustain the plasma with a microwave source operating around 11 GHz and the other was used to probe the cavity properties with the network analyzer using a frequency range around 14 GHz. The first results obtained with the JYFL 14 GHz ECRIS demonstrate that the presence of plasma has significant effects on the resonance properties of the cavity. With plasma the frequency dependent behavior is strongly damped and this trend strengthens with increasing microwave power.

  2. Ellipsometric study of crystalline silicon hydrogenated by plasma immersion ion implantation

    Energy Technology Data Exchange (ETDEWEB)

    Szekeres, A. [Institute of Solid State Physics, 72 Tzarigradsko Chaussee Blvd., 1784 Sofia (Bulgaria); Alexandrova, S. [Department of Applied Physics, Technical University of Sofia, Kl. Ohridski 8, 1797 Sofia (Bulgaria); Petrik, P., E-mail: petrik@mfa.kfki.hu [MFA Institute for Technical Physics and Materials Science, TTK Research Centre for Natural Sciences, Konkoly Thege Rd. 29-33, 1121 Budapest (Hungary); Fodor, B. [MFA Institute for Technical Physics and Materials Science, TTK Research Centre for Natural Sciences, Konkoly Thege Rd. 29-33, 1121 Budapest (Hungary); Bakalova, S. [Institute of Solid State Physics, 72 Tzarigradsko Chaussee Blvd., 1784 Sofia (Bulgaria)

    2013-09-15

    The structure and the optical properties of thin Si layer hydrogenated by shallow plasma ion implantation with different fluences up to 10{sup 15} cm{sup −2} are studied using spectroscopic ellipsometry and simulation of the distributions of the ions and implantation induced defects. The implantation was regarded to proceed into Si through the native SiO{sub 2}. Two-layer optical models are applied for examination of the composition and dielectric function behavior of the formed structures. The native oxide is found to be 3 nm thick. The thickness of the Si modified layer decreased 23 to 14 nm with ion fluence due to increased formation of highly hydrogenated surface region that hinder further H-penetration into the Si bulk, especially at the highest fluence. Shifts of the features in the obtained dielectric functions related with Si interband transitions at about 3.4 and 4.2 eV are found caused by process-induced tensile stress. The modified Si region is related rather to defects created by the ion implantation process than the projected range of hydrogen ions. The overall layer modification can be characterized by a low degree of amorphization (up to 5.8%), creation of structural defects and internal tensile stress.

  3. A feature of negative hydrogen ion production in the Uramoto-type sheet plasma

    Energy Technology Data Exchange (ETDEWEB)

    Jimbo, Kouichi [Kyoto Univ., Uji (Japan). Inst. of Atomic Energy

    1997-02-01

    It seems that negative hydrogen ions H{sup -} are formed directly from atomic hydrogens H. When the chamber was biased more negative against the anode potential at constant are power, forming a much deeper electrostatic well in the Uramoto-type sheet plasma negative ion source, more negative hydrogen ion currents were extracted. The chamber potential V{sub B} was biased down to -100V in the 150V discharge. The negative ion current J{sup -} was evaluated by the JAERI-probe measurement. J{sup -} increases linearly with the chamber current I{sub B}. The largest J{sup -} value was obtained at absolute value of |V{sub prob,f}|=15V and absolute value of |V{sub B}|=100V; the discharge was not operated for absolute value of |V{sub B}|>100V. We speculate the following collisional (three-body) electron attachment to H as a possible production process for H{sup -}; e+e+H{yields}e+H{sup -}. This process may explain the linear increase of J{sup -} with absolute value of |V{sub prob,f}|. (S.Y.)

  4. Correlation between Balmer {alpha} emission and hydrogen flux through a superpermeable niobium membrane in a low-pressure multicusp plasma source

    Energy Technology Data Exchange (ETDEWEB)

    Bruneteau, A.M.; Notkin, M.E.; Livshits, A.I.; Bacal, M. E-mail: bacal@lptp.polytechnique.fr

    2002-03-01

    The purpose of this paper is to correlate hydrogen or deuterium flux through super permeable membranes with incident hydrogen or deuterium atom flux from the plasma. To this aim a hydrogen or deuterium plasma is created in a hybrid multicusp plasma source. We investigate Balmer {alpha} emission from the multicusp plasma and the output pressure behind a superpermeable niobium membrane immersed in the plasma.The output pressure is proportional to the flux of atoms and ions arriving on the membrane. We find that both output pressure and excited atoms emission satisfy plasma parameters relations. It is thus verified that plasma-driven superpermeation of hydrogen is due essentially to neutral atoms from the plasma incident to the membrane.

  5. Correlation between Balmer /α emission and hydrogen flux through a superpermeable niobium membrane in a low-pressure multicusp plasma source

    Science.gov (United States)

    Bruneteau, A. M.; Notkin, M. E.; Livshits, A. I.; Bacal, M.

    2002-03-01

    The purpose of this paper is to correlate hydrogen or deuterium flux through superpermeable membranes with incident hydrogen or deuterium atom flux from the plasma. To this aim a hydrogen or deuterium plasma is created in a hybrid multicusp plasma source. We investigate Balmer α emission from the multicusp plasma and the output pressure behind a superpermeable niobium membrane immersed in the plasma.The output pressure is proportional to the flux of atoms and ions arriving on the membrane. We find that both output pressure and excited atoms emission satisfy plasma parameters relations. It is thus verified that plasma-driven superpermeation of hydrogen is due essentially to neutral atoms from the plasma incident to the membrane.

  6. Resonant scattering as a sensitive diagnostic of current collisional plasma models

    Science.gov (United States)

    Ogorzalek, Anna; Zhuravleva, Irina; Allen, Steven W.; Pinto, Ciro; Werner, Norbert; Mantz, Adam; Canning, Rebecca; Fabian, Andrew C.; Kaastra, Jelle S.; de Plaa, Jelle

    2017-08-01

    Resonant scattering is a subtle process that suppresses fluxes of some of the brightest optically thick X-ray emission lines produced by collisional plasmas in galaxy clusters and massive early-type galaxies. The amplitude of the effect depends on the turbulent structure of the hot gas, making it a sensitive velocity probe. It is therefore crucial to properly model this effect in order to correctly interpret high resolution X-ray spectra. Our measurements of resonant scattering with XMM-Newton Reflection Grating Spectrometer in giant elliptical galaxies and with Hitomi in the center of Perseus Cluster show that the potentially rich inference from this effect is limited by the uncertainties in the atomic data underlying plasma codes such as APEC and SPEX. Typically, the effect is of the order of 10-20%, while the discrepancy between the two codes is of similar order or even higher. Precise knowledge of the emissivity and oscillator strengths of lines emitted by Fe XVII and Fe XXV, as well as their respective uncertainties propagated through plasma codes are key to understanding gas dynamics and microphysics in giant galaxies and cluster ICM, respectively. This is especially crucial for massive ellipticals, where sub-eV resolution would be needed to measure line broadening precisely, making resonant scattering an important velocity diagnostic in these systems for the foreseeable future. In this poster, I will summarize current status of resonant scattering measurements and show how they depend on the assumed atomic data. I will also discuss which improvements are essential to maximize scientific inference from future high resolution X-ray spectra.

  7. Effects of hydrogen-damaged layer on tin-doped indium oxide etching by H2/Ar plasma

    Science.gov (United States)

    Hirata, Akiko; Fukasawa, Masanaga; Shigetoshi, Takushi; Okamoto, Masaki; Nagahata, Kazunori; Li, Hu; Karahashi, Kazuhiro; Hamaguchi, Satoshi; Tatsumi, Tetsuya

    2017-06-01

    The etch rate of tin-doped indium oxide (or indium tin oxide, ITO) and the effects of a hydrogen-damaged layer caused by H2/Ar plasma were investigated using several surface analysis techniques. The ITO etch rate strongly depended on the H2/Ar flow rate ratio. The ITO was reduced by hydrogen injection and generated an In-rich (hydrogen-induced damage) layer on the surface. Because this In-rich layer had a higher sputtering yield, the hydrogen-damaged layer enhanced the ITO etch rate. Thus, the etching of ITO in H2/Ar plasma is determined by the balance between the formation of the In-rich damaged layer by H ion irradiation and the sputtering by Ar (relatively heavy inert gas) ions.

  8. Thermodynamic diagrams for high temperature plasmas of air, air-carbon, carbon-hydrogen mixtures, and argon

    CERN Document Server

    Kroepelin, H; Hoffmann, K-U

    2013-01-01

    Thermodynamic Diagrams for High Temperature Plasmas of Air, Air-Carbon, Carbon-Hydrogen Mixtures, and Argon provides information relating to the properties of equilibrium gas plasmas formed from hydrocarbons, from air without argon, from pure argon, and from mixtures of air and carbon at various compositions, temperatures and pressures. The data are presented in graphical rather than tabular form to provide a clearer picture of the plasma processes investigated. This book is composed of four chapters, and begins with the introduction to the characteristics of plasmas, with emphasis on their th

  9. Hydrogen and oxygen plasma enhancement in the Cu electrodeposition and consolidation processes on BDD electrode applied to nitrate reduction

    Science.gov (United States)

    Couto, A. B.; Santos, L. C. D.; Matsushima, J. T.; Baldan, M. R.; Ferreira, N. G.

    2011-09-01

    Copper nanoparticle electrodeposition and consolidation processes were studied on boron doped diamond (BDD) electrode submitted to hydrogen and oxygen plasma treatments. The modified BDD films were applied as electrodes for nitrate electroreduction. The results showed that both treatments have a strong influence on the copper deposition and dissolution processes. For BDD treated with hydrogen plasma the copper electrodeposit was homogeneous with high particle density. This behavior was attributed to the BDD surface hydrogenation that improved its conductivity. On the other hand, the treatment with oxygen plasma was important for the copper nanoparticle consolidation on BDD surface, confirmed by the result's reproducibility for nitrate reduction. This performance may be associated with the formation of oxygen groups that can act as anchor points for Cu-clusters, enhancing the interfacial adhesion between diamond and the metal coating. The best electrochemical nitrate reduction response was obtained in acid media, where occurred the separation of the nitrate reduction process and the water reduction reaction.

  10. Inductively Coupled Plasma and Electron Cyclotron Resonance Plasma Etching of InGaAlP Compound Semiconductor System

    Energy Technology Data Exchange (ETDEWEB)

    Abernathy, C.R.; Hobson, W.S.; Hong, J.; Lambers, E.S.; Pearton, S.J.; Shul, R.J.

    1998-11-04

    Current and future generations of sophisticated compound semiconductor devices require the ability for submicron scale patterning. The situation is being complicated since some of the new devices are based on a wider diversity of materials to be etched. Conventional IUE (Reactive Ion Etching) has been prevalent across the industry so far, but has limitations for materials with high bond strengths or multiple elements. IrI this paper, we suggest high density plasmas such as ECR (Electron Cyclotron Resonance) and ICP (Inductively Coupled Plasma), for the etching of ternary compound semiconductors (InGaP, AIInP, AlGaP) which are employed for electronic devices like heterojunction bipolar transistors (HBTs) or high electron mobility transistors (HEMTs), and photonic devices such as light-emitting diodes (LEDs) and lasers. High density plasma sources, opeiating at lower pressure, are expected to meet target goals determined in terms of etch rate, surface morphology, surface stoichiometry, selectivity, etc. The etching mechanisms, which are described in this paper, can also be applied to other III-V (GaAs-based, InP-based) as well as III-Nitride since the InGaAIP system shares many of the same properties.

  11. Stark spectroscopy of atomic hydrogen balmer-alpha line for electric field measurement in plasmas by saturation spectroscopy

    Science.gov (United States)

    Nishiyama, S.; Katayama, K.; Nakano, H.; Goto, M.; Sasaki, K.

    2016-09-01

    Detailed structures of electric fields in sheath and pre-sheath regions of various plasmas are interested from the viewpoint of basic plasma physics. Several researchers observed Stark spectra of Doppler-broadened Rydberg states to evaluate electric fields in plasmas; however, these measurements needed high-power, expensive tunable lasers. In this study, we carried out another Stark spectroscopy with a low-cost diode laser system. We applied saturation spectroscopy, which achieves a Doppler-free wavelength resolution, to observe the Stark spectrum of the Balmer-alpha line of atomic hydrogen in the sheath region of a low-pressure hydrogen plasma. The hydrogen plasma was generated in an ICP source which was driven by on-off modulated rf power at 20 kHz. A planar electrode was inserted into the plasma. Weak probe and intense pump laser beams were injected into the plasma from the counter directions in parallel to the electrode surface. The laser beams crossed with a small angle above the electrode. The observed fine-structure spectra showed shifts, deformations, and/or splits when varying the distance between the observation position and the electrode surface. The detection limit for the electric field was estimated to be several tens of V/cm.

  12. Ultrafast all-optical arithmetic logic based on hydrogenated amorphous silicon microring resonators

    Science.gov (United States)

    Gostimirovic, Dusan; Ye, Winnie N.

    2016-03-01

    For decades, the semiconductor industry has been steadily shrinking transistor sizes to fit more performance into a single silicon-based integrated chip. This technology has become the driving force for advances in education, transportation, and health, among others. However, transistor sizes are quickly approaching their physical limits (channel lengths are now only a few silicon atoms in length), and Moore's law will likely soon be brought to a stand-still despite many unique attempts to keep it going (FinFETs, high-k dielectrics, etc.). This technology must then be pushed further by exploring (almost) entirely new methodologies. Given the explosive growth of optical-based long-haul telecommunications, we look to apply the use of high-speed optics as a substitute to the digital model; where slow, lossy, and noisy metal interconnections act as a major bottleneck to performance. We combine the (nonlinear) optical Kerr effect with a single add-drop microring resonator to perform the fundamental AND-XOR logical operations of a half adder, by all-optical means. This process is also applied to subtraction, higher-order addition, and the realization of an all-optical arithmetic logic unit (ALU). The rings use hydrogenated amorphous silicon as a material with superior nonlinear properties to crystalline silicon, while still maintaining CMOS-compatibility and the many benefits that come with it (low cost, ease of fabrication, etc.). Our method allows for multi-gigabit-per-second data rates while maintaining simplicity and spatial minimalism in design for high-capacity manufacturing potential.

  13. Electron paramagnetic resonance study of lipid and protein membrane components of erythrocytes oxidized with hydrogen peroxide

    Energy Technology Data Exchange (ETDEWEB)

    Mendanha, S.A.; Anjos, J.L.V.; Silva, A.H.M.; Alonso, A. [Instituto de Física, Universidade Federal de Goiás, Goiânia, GO (Brazil)

    2012-04-05

    Electron paramagnetic resonance (EPR) spectroscopy of spin labels was used to monitor membrane dynamic changes in erythrocytes subjected to oxidative stress with hydrogen peroxide (H{sub 2}O{sub 2}). The lipid spin label, 5-doxyl stearic acid, responded to dramatic reductions in membrane fluidity, which was correlated with increases in the protein content of the membrane. Membrane rigidity, associated with the binding of hemoglobin (Hb) to the erythrocyte membrane, was also indicated by a spin-labeled maleimide, 5-MSL, covalently bound to the sulfhydryl groups of membrane proteins. At 2% hematocrit, these alterations in membrane occurred at very low concentrations of H{sub 2}O{sub 2} (50 µM) after only 5 min of incubation at 37°C in azide phosphate buffer, pH 7.4. Lipid peroxidation, suggested by oxidative hemolysis and malondialdehyde formation, started at 300 µM H{sub 2}O{sub 2} (for incubation of 3 h), which is a concentration about six times higher than those detected with the probes. Ascorbic acid and α-tocopherol protected the membrane against lipoperoxidation, but did not prevent the binding of proteins to the erythrocyte membrane. Moreover, the antioxidant (+)-catechin, which also failed to prevent the cross-linking of cytoskeletal proteins with Hb, was very effective in protecting erythrocyte ghosts from lipid peroxidation induced by the Fenton reaction. This study also showed that EPR spectroscopy can be useful to assess the molecular dynamics of red blood cell membranes in both the lipid and protein domains and examine oxidation processes in a system that is so vulnerable to oxidation.

  14. Amorphous-to-microcrystalline transition in a-Si:H under hydrogen plasma: Optical and electrical detection

    Energy Technology Data Exchange (ETDEWEB)

    Hadjadj, Aomar; Larbi, Fadila [Groupe de Recherche en Sciences pour l' Ingenieur (GRESPI), Universite de Reims, 51687 Reims cedex 2 (France); Pham, Nans [Groupe de Recherche en Sciences pour l' Ingenieur (GRESPI), Universite de Reims, 51687 Reims cedex 2 (France); Laboratoire de Physique des Interfaces et Couches Minces (LPICM), Ecole Polytechnique, 91128 Palaiseau (France); Roca i Cabarrocas, Pere [Laboratoire de Physique des Interfaces et Couches Minces (LPICM), Ecole Polytechnique, 91128 Palaiseau (France)

    2012-06-15

    The exact role of hydrogen in the crystallization process is still a subject of broad controversies due to the complexity of the overall plasma enhanced chemical vapor deposition (PECVD) process. We have investigated by ellipsometry the amorphous-to-microcrystalline the phase transition in intrinsic and doped hydrogenated amorphous silicon (a-Si:H) thin films during their exposure to a hydrogen plasma in conditions of chemical transport. The whole ellipsometry diagnostics reveal that, while intrinsic and phosphorus-doped a-Si:H present a similar trend during the plasma treatment, boron-doped a-Si:H differs by special features such as a rapid formation of the hydrogen-rich subsurface layer and an early amorphous-to-microcrystalline phase transition. The particular behavior of boron-doped material is also pointed out through the time-evolution of the self-bias voltage on the radio-frequency electrode during the hydrogen plasma treatment (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  15. Resonant shadowgraph and schlieren studies of magnetized laser-produced plasmas

    Science.gov (United States)

    Jellison, G.; Parsons, C. R.

    1981-10-01

    Resonant shadowgraph and schlieren techniques are used to photograph the flow of laser-produced barium plasma, across a magnetic field. The plasma is formed by focusing a CO2 TEA laser onto a solid barium target in a vacuum chamber. Long 7-J pulses and short 2-J pulses are obtained, and the CO2 wavelength is 10.6 microns. A transverse magnetic field of 200-2000 G is provided by electromagnetic coils. The tunable dye laser used for optical diagnostics is pumped by a frequency-doubled Q-switched ruby laser and yields a 10-mJ, 20-nsec pulse with a spectral width of 0.25 A. For the schlieren studies, a knife edge is placed at the laser focal spot, and the camera is focused onto the plasma region. Some of the features in the photographs are understandable in view of previous work, while others are unexpected. The appearance of a narrow collimated beam has been noted in other studies (e.g., Sucov et al., 1967; Bruneteau et al., 1970). It is shown that the traditional concept of polarization drift across the field is applicable to the present experiment. The slow plasma component displays internal striations, which are interpreted as shock waves excited by the plasma.

  16. Suppression of runaway electrons with a resonant magnetic perturbation in MST tokamak plasmas

    Science.gov (United States)

    Munaretto, Stefano; Chapman, B. E.; Almagri, A. F.; Cornille, B. S.; Dubois, A. M.; Goetz, J. A.; McCollam, K. J.; Sovinec, C. R.

    2016-10-01

    Runaway electrons generated in MST tokamak plasmas are now being probed with resonant magnetic perturbations (RMP's). An RMP with m =3 strongly suppresses the runaway electrons. Initial modeling of these plasmas with NIMROD shows the degradation of flux surfaces with an m =3 RMP, which may account for the runaway electron suppression. These MST tokamak plasmas have Bt =0.14 T, Ip =50kA, and q(a) =2.2, with a bulk electron density and temperature of 5x1017 m-3 and 150 eV. Runaway electrons are detected via x-ray emission. The RMP is produced by a poloidal array of 32 saddle coils at the narrow vertical insulated cut in MST's thick conducting shell. Each RMP has a single m but a broad n spectrum. A sufficiently strong m =3 RMP completely suppresses the runaway electrons, while a comparable m =1 RMP has little effect. The impact of the RMP's on the magnetic topology of these plasmas is being studied with the nonlinear MHD code, NIMROD. With an m =3 RMP, stochasticity is introduced in the outer third of the plasma. No such change is observed with the m =1 RMP. NIMROD also predicts regularly occurring sawtooth oscillations with a period comparable to MHD activity observed in the experiment. Work supported by USDOE.

  17. TRANSPORT PROPERTIES OF μc-Si:H FILMS PREPARED BY VERY HIGH HYDROGEN-DILUTED SILANE PLASMA

    Institute of Scientific and Technical Information of China (English)

    SHI JIAN-JUN; HUANG SHAO-YUN; CHEN KUN-JI; HUANG XIN-FAN; XU JUN

    2001-01-01

    Highly hydrogen-diluted silane plasma is used to fabricate microcrystalline silicon films in a plasma-enhanced chemical vapour deposition system. X-ray diffraction and micro-Raman scattering spectroscopy are utilized to characterize their microstructure properties. Dark conductivity and drift mobility are measured by the travelling wave method.With the decreasing gas flow ratio of silane-to-hydrogen from 2% to 0.2%, the crystalline volume fraction and the drift mobility increase at room temperature. Meanwhile, the dark conductivity increases initially and then decreases. The relationship between the microstructures and transport properties is discussed.

  18. Pulsed microwave-driven argon plasma jet with distinctive plume patterns resonantly excited by surface plasmon polaritons

    Institute of Scientific and Technical Information of China (English)

    陈兆权; 殷志祥; 夏广庆; 洪伶俐; 胡业林; 刘明海; 胡希伟

    2015-01-01

    Atmospheric lower-power pulsed microwave argon cold plasma jets are obtained by using coaxial transmission line resonators in ambient air. The plasma jet plumes are generated at the end of a metal wire placed in the middle of the dielec-tric tubes. The electromagnetic model analyses and simulation results suggest that the discharges are excited resonantly by the enhanced electric field of surface plasmon polaritons. Moreover, for conquering the defect of atmospheric argon filamentation discharges excited by 2.45-GHz continued microwave, the distinctive patterns of the plasma jet plumes can be maintained by applying different gas flow rates of argon gas, frequencies of pulsed modulator, duty cycles of pulsed microwave, peak values of input microwave power, and even by using different materials of dielectric tubes. In addition, the emission spectrum, the plume temperature, and other plasma parameters are measured, which shows that the proposed pulsed microwave plasma jets can be adjusted for plasma biomedical applications.

  19. Comparison of surface vacuum ultraviolet emissions with resonance level number densities. I. Argon plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Boffard, John B., E-mail: jboffard@wisc.edu; Lin, Chun C. [Department of Physics, University of Wisconsin, Madison, WI 53706 (United States); Culver, Cody [Materials Science Program, University of Wisconsin, Madison, WI 53706 (United States); Wang, Shicong; Wendt, Amy E. [Department of Electrical and Computer Engineering, University of Wisconsin, Madison, WI 53706 (United States); Radovanov, Svetlana; Persing, Harold [Varian Semiconductor Equipment, Applied Materials Inc., Gloucester, MA 01939 (United States)

    2014-03-15

    Vacuum ultraviolet (VUV) photons emitted from excited atomic states are ubiquitous in material processing plasmas. The highly energetic photons can induce surface damage by driving surface reactions, disordering surface regions, and affecting bonds in the bulk material. In argon plasmas, the VUV emissions are due to the decay of the 1s{sub 4} and 1s{sub 2} principal resonance levels with emission wavelengths of 104.8 and 106.7 nm, respectively. The authors have measured the number densities of atoms in the two resonance levels using both white light optical absorption spectroscopy and radiation-trapping induced changes in the 3p{sup 5}4p→3p{sup 5}4s branching fractions measured via visible/near-infrared optical emission spectroscopy in an argon inductively coupled plasma as a function of both pressure and power. An emission model that takes into account radiation trapping was used to calculate the VUV emission rate. The model results were compared to experimental measurements made with a National Institute of Standards and Technology-calibrated VUV photodiode. The photodiode and model results are in generally good accord and reveal a strong dependence on the neutral gas temperature.

  20. Effect of resonant magnetic perturbations on ELMs in connected double null plasmas in MAST

    CERN Document Server

    Kirk, A; Chapman, I T; Harrison, J; Nardon, E; Scannell, R; Thornton, A J

    2013-01-01

    The application of resonant magnetic perturbations (RMPs) with a toroidal mode number of n=3 to connected double null plasmas in the MAST tokamak produces up to a factor of 9 increase in Edge Localized Mode (ELM) frequency and reduction in plasma energy loss associated with type-I ELMs. A threshold current for ELM mitigation is observed above which the ELM frequency increases approximately linearly with current in the coils. The effect of the RMPs is found to be scenario dependent. In one scenario the mitigation is only due to a large density pump out event and if the density is recovered by gas puffing a return to type I ELMs is observed. In another scenario sustained ELM mitigation can be achieved irrespective of the amount of fuelling. Despite a large scan of parameters complete ELM suppression has not been achieved. The results have been compared to modelling performed using either the vacuum approximation or including the plasma response. The requirement for a resonant condition, that is an optimum align...

  1. Surface plasmon resonance investigation of optical detection in plasma-modified phospholipid layers

    Energy Technology Data Exchange (ETDEWEB)

    Park, Byoungchoo; Cho, Chanyoun; Choi, Kyoungho; Jeon, Honggoo [Kwangwoon University, Seoul (Korea, Republic of)

    2012-03-15

    We herein report on a study of surface plasmon resonance (SPR) in thin gold (Au) films coated with thin layers of phospholipid material, which had been exposed to an atmospheric pressure (AP) plasma containing both pure Ar and Ar mixed with O{sub 2} (Ar/O{sub 2}, 0.8%). The phospholipid material that we used for the SPR experiments was lecithin, and the AP plasma system was applied in air by means of a radio-frequency (RF) plasma generator. A thin (∼60 nm) film of Au and a thin (∼15 nm) layer of lecithin were deposited and attached to the face of a prism, and surface plasmon modes were excited along the interfaces of the prism-Au-lecithin-air system by means of prism coupling using a He-Ne Laser (632.8 nm). The experimental SPR reflectance curves of the Au-lecithin-air modes were found to be shifted towards those of the Au-air mode with increasing applications of AP RF plasma treatment. From the shifts in the SPR curves, we found that the estimated thickness of the lecithin layer treated with a pure Ar plasma showed a linear decrease with etching rate of about 3 nm per treatment while the thickness of the lecithin layer treated with a mixed Ar/O{sub 2} plasma showed a tendency to saturate following a large initial decrease (ca. 14 nm). All these results demonstrate that the use of SPR sensing could facilitate the detection of extremely small variations in plasma-treated films of biomaterials.

  2. Study of the hydrogen behavior in amorphous hydrogenated materials of type a - C:H and a - SiC:H facing fusion reactor plasma; Etude du comportament de l`hydrogene dans des materiaux amorphes hydrogenes de type a - C:H et a - SiC:H devant faire face au plasma des reacteurs a fusion

    Energy Technology Data Exchange (ETDEWEB)

    Barbier, G. [Lyon-1 Univ., 69 - Villeurbanne (France). Inst. de Physique Nucleaire

    1997-04-10

    Plasma facing components of controlled fusion test devices (tokamaks) are submitted to several constraints (irradiation, high temperatures). The erosion (physical sputtering and chemical erosion) and the hydrogen recycling (retention and desorption) of these materials influence many plasma parameters and thus affect drastically the tokamak running. First, we will describe the different plasma-material interactions. It will be pointed out, how erosion and hydrogen recycling are strongly related to both chemical and physical properties of the material. In order to reduce these interactions, we have selected two amorphous hydrogenated materials (a-C:H and a-SiC:H), which are known for their good thermal and chemical qualities. Some samples have been then implanted with lithium ions at different fluences. Our materials have been then irradiated with deuterium ions at low energy. From our results, it is shown that both the lithium implantation and the use of an a - SiC:H substrate can be beneficial in enhancing the hydrogen retention. These results were completed with thermal desorption studies of these materials. It was evidenced that the hydrogen fixation was more efficient in a-SiC:H than in a-C:H substrate. Results in good agreement with those described above have been obtained by exposing a - C:H and a - SiC:H samples to the scrape off layer of the tokamak of Varennes (TdeV, Canada). A modelling of hydrogen diffusion under irradiation has been also proposed. (author) 176 refs.

  3. The quenching effect of hydrogen on the nitrogen in metastable state in atmospheric-pressure N{sub 2}-H{sub 2} microwave plasma torch

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shou-Zhe, E-mail: lisz@dlut.edu.cn; Zhang, Xin; Chen, Chuan-Jie; Zhang, Jialiang [Key Laboratory of Materials Modification by Laser, Ion, Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); School of Physics and Optoelectronic Technology, Dalian 116024 (China); Wang, Yong-Xing [College of Electrical Engineering, Dalian 116024 (China); Xia, Guang-Qing [School of Aeronautics and Astronautics, Dalian University of Technology, Dalian 116024 (China)

    2014-07-15

    The atmospheric-pressure microwave N{sub 2}-H{sub 2} plasma torch is generated and diagnosed by optical emission spectroscopy. It is found that a large amount of N atoms and NH radicals are generated in the plasma torch and the emission intensity of N{sub 2}{sup +} first negative band is the strongest over the spectra. The mixture of hydrogen in nitrogen plasma torch causes the morphology of the plasma discharge to change with appearance that the afterglow shrinks greatly and the emission intensity of N{sub 2}{sup +} first negative band decreases with more hydrogen mixed into nitrogen plasma. In atmospheric-pressure microwave-induced plasma torch, the hydrogen imposes a great influence on the characteristics of nitrogen plasma through the quenching effect of the hydrogen on the metastable state of N{sub 2}.

  4. An investigation of resonances in e{sup +}-H scattering embedded in Debye plasma

    Energy Technology Data Exchange (ETDEWEB)

    Ning, Ye; Yan, Zong-Chao [Department of Physics, University of New Brunswick, Fredericton, New Brunswick E3B 5A3 (Canada); Ho, Yew Kam [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, Taiwan (China)

    2015-01-15

    We carry out calculations for S-wave and P-wave resonances in e{sup +}-H scattering in weakly coupled Debye plasma in which the interaction between two charged particles is represented by a screened Coulomb potential. We employ the complex-scaling method with Hylleraas-type basis set to take correlation effects into account. In the complex-scaling treatment of the screened Coulomb potential, we first perform a Taylor series expansion for the exponential function that contains the distance r between two particles into a polynomial with various powers r{sup n}. We then make the complex scaling transformation of r→r e{sup iθ} in the expansion. The complex resonant eigenvalues are obtained by searching for stabilized points in the complex energy plane with respect to the changes of rotational angle θ and other parameters in the basis set.

  5. Properties of the ion-ion hybrid resonator in fusion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Morales, George J. [Univ. of California, Los Angeles, CA (United States)

    2015-10-06

    The project developed theoretical and numerical descriptions of the properties of ion-ion hybrid Alfvén resonators that are expected to arise in the operation of a fusion reactor. The methodology and theoretical concepts were successfully compared to observations made in basic experiments in the LAPD device at UCLA. An assessment was made of the excitation of resonator modes by energetic alpha particles for burning plasma conditions expected in the ITER device. The broader impacts included the generation of basic insight useful to magnetic fusion and space science researchers, defining new avenues for exploration in basic laboratory experiments, establishing broader contacts between experimentalists and theoreticians, completion of a Ph.D. dissertation, and promotion of interest in science through community outreach events and classroom instruction.

  6. Second-Order Nonlinearity in Triangular Lattice Perforated Gold Film due to Surface Plasmas Resonance

    Directory of Open Access Journals (Sweden)

    Renlong Zhou

    2014-01-01

    Full Text Available We have studied the excitation second-order nonlinearity through a triangular lattice perforated gold film instead of square lattice in many papers. Under the excitation of surface plasmas resonance effect, the second order nonlinearity exists in the noncentrosymmetric split-ring resonators arrays. Reflection of fundamental frequency wave through a triangular lattice perforated gold film is obtained. We also described the second harmonic conversion efficiencies in the second order nonlinear optical process with the spectra. Moreover, the electric field distributions of fundamental frequency above the gold film region are calculated. The light propagation through the holes results in the enhancement of the second order nonlinearity including second harmonic generation as well as the sum (difference frequency generation.

  7. Non-resonant interacting ion acoustic waves in a magnetized plasma

    Energy Technology Data Exchange (ETDEWEB)

    Maccari, Attilio [Technical Institute ' G Cardano' , Monterotondo, Rome (Italy)

    1999-01-29

    We perform an analytical and numerical investigation of the interaction among non-resonant ion acoustic waves in a magnetized plasma. Waves are supposed to be non-resonant, i.e. with different group velocities that are not close to each other. We use an asymptotic perturbation method, based on Fourier expansion and spatio-temporal rescaling. We show that the amplitude slow modulation of Fourier modes cannot be described by the usual nonlinear Schroedinger equation but by a new model system of nonlinear evolution equations. This system is C-integrable, i.e. it can be linearized through an appropriate transformation of the dependent and independent variables. We demonstrate that a subclass of solutions gives rise to envelope solitons. Each envelope soliton propagates with its own group velocity. During a collision solitons maintain their shape, the only change being a phase shift. Numerical results are used to check the validity of the asymptotic perturbation method. (author)

  8. Spectroscopic characterization of H 2 and D 2 helicon plasmas generated by a resonant antenna for neutral beam applications in fusion

    Science.gov (United States)

    Marini, C.; Agnello, R.; Duval, B. P.; Furno, I.; Howling, A. A.; Jacquier, R.; Karpushov, A. N.; Plyushchev, G.; Verhaegh, K.; Guittienne, Ph.; Fantz, U.; Wünderlich, D.; Béchu, S.; Simonin, A.

    2017-03-01

    A new generation of neutral beam systems will be required in future fusion reactors, such as DEMO, able to deliver high power (up to 50 MW) with high (800 keV or higher) neutral energy. Only negative ion beams may be able to attain this performance, which has encouraged a strong research focus on negative ion production from both surface and volumetric plasma sources. A novel helicon plasma source, based on the resonant birdcage network antenna configuration, is currently under study at the Swiss Plasma Centre before installation on the Cybele negative ion source at the Institute for Magnetic Fusion Research, CEA, Cadarache, France. This source is driven by up to 10 kW at 13.56 MHz, and is being tested on a linear resonant antenna ion device. Passive spectroscopic measurements of the first three Balmer lines α, β and γ and of the Fulcher-α bands were performed with an f/2 spectrometer, for both hydrogen and deuterium. Multiple viewing lines and an absolute intensity calibration were used to determine the plasma radiance profile, with a spatial resolution  emissivity profile for each emission line for cylindrical symmetry, which was experimentally confirmed. An uncertainty estimate of the inverted profiles was performed using a Monte Carlo approach. Finally, a radiofrequency-compensated Langmuir probe was inserted to measured the electron temperature and density profiles. The absolute line emissivities are interpreted using the collisional-radiative code YACORA which estimates the degree of dissociation and the distribution of the atomic and molecular species, including the negative ion density. This paper reports the results of a power scan up to 5 kW in conditions satisfying Cybele requirements for the plasma source, namely a low neutral pressure, p≤slant 0.3 Pa and magnetic field B≤slant 150 G.

  9. On the self-excitation mechanisms of Plasma Series Resonance oscillations in single- and multi-frequency capacitive discharges

    CERN Document Server

    Schuengel, Edmund; Korolov, Ihor; Derzsi, Aranka; Donko, Zoltan; Schulze, Julian

    2016-01-01

    The self-excitation of plasma series resonance (PSR) oscillations is a prominent feature in the current of low pressure capacitive radio frequency (RF) discharges. This resonance leads to high frequency oscillations of the charge in the sheaths and enhances electron heating. Up to now, the phenomenon has only been observed in asymmetric discharges. There, the nonlinearity in the voltage balance, which is necessary for the self-excitation of resonance oscillations with frequencies above the applied frequencies, is caused predominantly by the quadratic contribution to the charge-voltage relation of the plasma sheaths. Using PIC/MCC simulations of single- and multi- frequency capacitive discharges and an equivalent circuit model, we demonstrate that other mechanisms such as a cubic contribution to the charge-voltage relation of the plasma sheaths and the time dependent bulk electron plasma frequency can cause the self-excitation of PSR oscillations, as well. These mechanisms have been neglected in previous model...

  10. Advanced Fuels Reactor using Aneutronic Rodless Ultra Low Aspect Ratio Tokamak Hydrogenic Plasmas

    Science.gov (United States)

    Ribeiro, Celso

    2015-11-01

    The use of advanced fuels for fusion reactor is conventionally envisaged for field reversed configuration (FRC) devices. It is proposed here a preliminary study about the use of these fuels but on an aneutronic Rodless Ultra Low Aspect Ratio (RULART) hydrogenic plasmas. The idea is to inject micro-size boron pellets vertically at the inboard side (HFS, where TF is very high and the tokamak electron temperature is relatively low because of profile), synchronised with a proton NBI pointed to this region. Therefore, p-B reactions should occur and alpha particles produced. These pellets will act as an edge-like disturbance only (cp. killer pellet, although the vertical HFS should make this less critical, since the unablated part should appear in the bottom of the device). The boron cloud will appear at midplance, possibly as a MARFE-look like. Scaling of the p-B reactions by varying the NBI energy should be compared with the predictions of nuclear physics. This could be an alternative to the FRC approach, without the difficulties of the optimization of the FRC low confinement time. Instead, a robust good tokamak confinement with high local HFS TF (enhanced due to the ultra low aspect ratio and low pitch angle) is used. The plasma central post makes the RULART concept attractive because of the proximity of NBI path and also because a fraction of born alphas will cross the plasma post and dragged into it in the direction of the central plasma post current, escaping vertically into a hole in the bias plate and reaching the direct electricity converter, such as in the FRC concept.

  11. Plasma-wall interactions data compendium-1. ''Hydrogen retention property, diffusion and recombination coefficients database for selected plasma-facing materials''

    Energy Technology Data Exchange (ETDEWEB)

    Iwakiri, Hirotomo [Kyushu Univ., Fukuoka (Japan). Research Inst. for Applied Mechanics; Matsuhiro, Kenjirou [Osaka Univ., Osaka (Japan); Hirooka, Yoshi [National Inst. for Fusion Science, Toki, Gifu (Japan); Yamamura, Yasunori [Okayama Univ. of Scinece, Okayama (Japan)

    2002-05-01

    A summary on the recent activities of the plasma-wall interactions database task group at the National Institute for Fusion Science is presented in this report. These activities are focused on the compilation of literature data on the key parameters related to wall recycling characteristics that affect dynamic particle balance during plasma discharges and also on-site tritium inventory. More specifically, in this task group a universal fitting formula has been proposed and successfully applied to help compile hydrogen implantation-induced retention data. Also, presented here are the data on hydrogen diffusion and surface recombination coefficients, both critical in modeling dynamic wall recycling behavior. Data compilation has been conducted on beryllium, carbon, tungsten and molybdenum, all currently used for plasma-facing components in magnetic fusion experiments. (author)

  12. The parametric resonance features for theory of energy transfer in dusty plasma

    Science.gov (United States)

    Semyonov, V. P.; Timofeev, A. V.

    2015-11-01

    One of the mechanisms of energy transfer between degrees of freedom of dusty plasma system can be described by equations similar to Mathieu equation with account of stochastic forces. Such equation is studied by analytical approach. The solutions for higher order of accuracy are obtained. The method for numerical solution and resonance zone detection is proposed. The solution for the extended Mathieu equation is obtained for wide range of parameter values. The results of numerical solution are compared with analytical solutions of different order and known analytical results for Mathieu equation.

  13. Strong higher-order resonant contributions to x-ray line polarization in hot plasmas

    CERN Document Server

    Shah, Chintan; Steinbrügge, Rene; Beilmann, Christian; Bernitt, Sven; Fritzsche, Stephan; Surzhykov, Andrey; López-Urrutia, José R Crespo; Tashenov, Stanislav

    2016-01-01

    We studied angular distributions of x rays emitted in resonant recombination of highly charged iron and krypton ions, resolving dielectronic, trielectronic, and quadruelectronic channels. A tunable electron beam drove these processes, inducing x rays registered by two detectors mounted along and perpendicular to the beam axis. The measured emission asymmetries comprehensively benchmarked full-order atomic calculations. We conclude that accurate polarization diagnostics of hot plasmas can only be obtained under the premise of inclusion of higher-order processes that were neglected in earlier work.

  14. Preliminary Analysis of the Hysteresis Phenomenon in Electron Cyclotron Resonance Plasma

    Institute of Scientific and Technical Information of China (English)

    LIU Ming-Hai; HU Xi-Wei; YU Guo-Yang; WU Qin-Chong; PAN Yuan

    2001-01-01

    The hysteresis phenomenon in electron cyclotron resonance plasma has been investigated theoretically by solvingthe equations of the density and energy balance of electrons and by taking the effects of several collisions suchas ionization and recombination into account. The results show that multiple steady states in experimentalmeasurements can be characterized by considering the fact that the energy balance function has three differentreal roots in certain regions of parameters. One root represents a saddle point and other roots represent stablepoints, that is, the system is bistable. The effects of ionization and the energy transformation due to the collisionsbetween the electron and neutral gas are also discussed.

  15. Fractional Boltzmann equation for multiple scattering of resonance radiation in low-temperature plasma

    Energy Technology Data Exchange (ETDEWEB)

    Uchaikin, V V; Sibatov, R T, E-mail: vuchaikin@gmail.com, E-mail: ren_sib@bk.ru [Ulyanovsk State University, 432000, 42 Leo Tolstoy str., Ulyanovsk (Russian Federation)

    2011-04-08

    The fractional Boltzmann equation for resonance radiation transport in plasma is proposed. We start with the standard Boltzmann equation; averaging over photon frequencies leads to the appearance of a fractional derivative. This fact is in accordance with the conception of latent variables leading to hereditary and non-local dynamics (in particular, fractional dynamics). The presence of a fractional material derivative in the equation is concordant with heavy tailed distribution of photon path lengths and with spatiotemporal coupling peculiar to the process. We discuss some methods of solving the obtained equation and demonstrate numerical results in some simple cases.

  16. Plasma-induced magnetic responses during nonlinear dynamics of magnetic islands due to resonant magnetic perturbations

    Energy Technology Data Exchange (ETDEWEB)

    Nishimura, Seiya, E-mail: n-seiya@kobe-kosen.ac.jp [Kobe City College of Technology, Kobe, Hyogo 651-2194 (Japan)

    2014-12-15

    Resonant magnetic perturbations (RMPs) produce magnetic islands in toroidal plasmas. Self-healing (annihilation) of RMP-induced magnetic islands has been observed in helical systems, where a possible mechanism of the self-healing is shielding of RMP penetration by plasma flows, which is well known in tokamaks. Thus, fundamental physics of RMP shielding is commonly investigated in both tokamaks and helical systems. In order to check this mechanism, detailed informations of magnetic island phases are necessary. In experiments, measurement of radial magnetic responses is relatively easy. In this study, based on a theoretical model of rotating magnetic islands, behavior of radial magnetic fields during the self-healing is investigated. It is confirmed that flips of radial magnetic fields are typically observed during the self-healing. Such behavior of radial magnetic responses is also observed in LHD experiments.

  17. Optimization of a coaxial electron cyclotron resonance plasma thruster with an analytical model

    Science.gov (United States)

    Cannat, F.; Lafleur, T.; Jarrige, J.; Chabert, P.; Elias, P.-Q.; Packan, D.

    2015-05-01

    A new cathodeless plasma thruster currently under development at Onera is presented and characterized experimentally and analytically. The coaxial thruster consists of a microwave antenna immersed in a magnetic field, which allows electron heating via cyclotron resonance. The magnetic field diverges at the thruster exit and forms a nozzle that accelerates the quasi-neutral plasma to generate a thrust. Different thruster configurations are tested, and in particular, the influence of the source diameter on the thruster performance is investigated. At microwave powers of about 30 W and a xenon flow rate of 0.1 mg/s (1 SCCM), a mass utilization of 60% and a thrust of 1 mN are estimated based on angular electrostatic probe measurements performed downstream of the thruster in the exhaust plume. Results are found to be in fair agreement with a recent analytical helicon thruster model that has been adapted for the coaxial geometry used here.

  18. Optimization of a coaxial electron cyclotron resonance plasma thruster with an analytical model

    Energy Technology Data Exchange (ETDEWEB)

    Cannat, F., E-mail: felix.cannat@onera.fr, E-mail: felix.cannat@gmail.com; Lafleur, T. [Physics and Instrumentation Department, Onera -The French Aerospace Lab, Palaiseau, Cedex 91123 (France); Laboratoire de Physique des Plasmas, CNRS, Sorbonne Universites, UPMC Univ Paris 06, Univ Paris-Sud, Ecole Polytechnique, 91128 Palaiseau (France); Jarrige, J.; Elias, P.-Q.; Packan, D. [Physics and Instrumentation Department, Onera -The French Aerospace Lab, Palaiseau, Cedex 91123 (France); Chabert, P. [Laboratoire de Physique des Plasmas, CNRS, Sorbonne Universites, UPMC Univ Paris 06, Univ Paris-Sud, Ecole Polytechnique, 91128 Palaiseau (France)

    2015-05-15

    A new cathodeless plasma thruster currently under development at Onera is presented and characterized experimentally and analytically. The coaxial thruster consists of a microwave antenna immersed in a magnetic field, which allows electron heating via cyclotron resonance. The magnetic field diverges at the thruster exit and forms a nozzle that accelerates the quasi-neutral plasma to generate a thrust. Different thruster configurations are tested, and in particular, the influence of the source diameter on the thruster performance is investigated. At microwave powers of about 30 W and a xenon flow rate of 0.1 mg/s (1 SCCM), a mass utilization of 60% and a thrust of 1 mN are estimated based on angular electrostatic probe measurements performed downstream of the thruster in the exhaust plume. Results are found to be in fair agreement with a recent analytical helicon thruster model that has been adapted for the coaxial geometry used here.

  19. Plasma breakdown diagnostics with the biased disc of electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, O; Ropponen, T; Toivanen, V; Arje, J; Koivisto, H [University of Jyvaeskylae, Department of Physics, Accelerator Laboratory, PO Box 35 (YFL), 40500 Jyvaeskylae (Finland)], E-mail: olli.tarvainen@jyu.fi

    2009-08-15

    The electron cyclotron resonance ion sources at the JYFL (University of Jyvaeskylae, Department of Physics) accelerator laboratory have been operated in pulsed mode to study the time-resolved current signal from the biased discs of the ion sources. The purpose of the experiments is to gain an understanding of the ion source parameters affecting the time required for the transition from neutral gas to plasma. It was observed that the plasma breakdown time depends strongly on the neutral gas density, gas species and density of seed electrons. In particular, it was observed that a low power microwave signal at secondary frequency makes the breakdown time virtually independent of the neutral gas density. The results can be utilized for operation of ECR ion sources in the so-called preglow mode. A simple qualitative model, which is in good agreement with the experiments, has been developed to interpret the results.

  20. Novel Diamond Films Synthesis Strategy: Methanol and Argon Atmosphere by Microwave Plasma CVD Method Without Hydrogen

    Science.gov (United States)

    Yang, Li; Jiang, Caiyi; Guo, Shenghui; Zhang, Libo; Gao, Jiyun; Peng, Jinhui; Hu, Tu; Wang, Liang

    2016-09-01

    Diamond thin films are grown on silicon substrates by only using methanol and argon mixtures in microwave plasma chemical vapor deposition (MPCVD) reactor. It is worth mentioning that the novel strategy makes the synthesis reaction works smoothly without hydrogen atmosphere, and the substrates temperature is only 500 °C. The evidence of surface morphology and thickness under different time is obtained by characterizing the samples using scanning electron microscopy (SEM). X-ray diffractometer (XRD) spectrum reveals that the preferential orientation of (111) plane sample is obtained. The Raman spectra indicate that the dominant component of all the samples is a diamond. Moreover, the diamond phase content of the targeted films was quantitatively analyzed by X-ray photoelectron spectroscopy (XPS) method, and the surface roughness of diamond films was investigated by atomic force microscope (AFM). Meanwhile, the possible synthesis mechanism of the diamond films in methanol- and argon-mixed atmosphere was discussed.

  1. Hydrogen-plasma-induced magnetocrystalline anisotropy ordering in self-assembled magnetic nanoparticle monolayers.

    Science.gov (United States)

    Weddemann, Alexander; Meyer, Judith; Regtmeier, Anna; Janzen, Irina; Akemeier, Dieter; Hütten, Andreas

    2013-01-01

    Self-assembled two-dimensional arrays of either 14 nm hcp-Co or 6 nm ε-Co particle components were treated by hydrogen plasma for various exposure times. A change of hysteretic sample behavior depending on the treatment duration is reported, which can be divided in two time scales: oxygen reduction increases the particle magnetization during the first 20 min, which is followed by an alteration of the magnetic response shape. The latter depends on the respective particle species. Based on the Landau-Lifshitz equations for a discrete set of magnetic moments, we propose a model that relates the change of the hysteresis loops to a dipole-driven ordering of the magnetocrystalline easy axes within the particle plane due to the high spatial aspect ratio of the system.

  2. Hydrogen-plasma-induced magnetocrystalline anisotropy ordering in self-assembled magnetic nanoparticle monolayers

    Directory of Open Access Journals (Sweden)

    Alexander Weddemann

    2013-03-01

    Full Text Available Self-assembled two-dimensional arrays of either 14 nm hcp-Co or 6 nm ε-Co particle components were treated by hydrogen plasma for various exposure times. A change of hysteretic sample behavior depending on the treatment duration is reported, which can be divided in two time scales: oxygen reduction increases the particle magnetization during the first 20 min, which is followed by an alteration of the magnetic response shape. The latter depends on the respective particle species. Based on the Landau–Lifshitz equations for a discrete set of magnetic moments, we propose a model that relates the change of the hysteresis loops to a dipole-driven ordering of the magnetocrystalline easy axes within the particle plane due to the high spatial aspect ratio of the system.

  3. Double Glow Plasma Hydrogen-free Carburizing on Commercial Purity Titanium

    Institute of Scientific and Technical Information of China (English)

    ZHANG Gaohui; PAN Junde; HE Zhiyong; ZHANG Pingze; GAO Yuan; XU Zhong

    2005-01-01

    A carburized layer with special physical and chemical properties was formed on the surface of commercial purity titanium by a double glow plasma hydrogen-free carburizing technique. High-purity netlike solid graphite was used as a raw material and commercial purity titanium was used as the substrate material. Argon gas was used as the working gas. The carburized layer can be obviously observed under a microscope. X-ray diffraction indicates that TiC phase with higher hardness and dissociate state carbon phase was formed in the carburized layer. The glow discharge spectrum (GDS) analysis shows that the carbon concentration distributes gradiently along the depth of carburized layer. The surface hardness of the substrate increases obviously. The hardness distributes gradiently from the surface to inner of carburized layer. The friction coefficient reduces by more than 1/2, the ratio wear rate decreases by above three orders of magnitude. The wear resistance of the substrate material is improved consumedly.

  4. Density Distributions of H and H2 in Pulsed Microwave hydrogen Plasmas

    Institute of Scientific and Technical Information of China (English)

    DUAN Xu-Ru(段旭如); H.Lange; QIAN shang-Jie(钱尚介); N.Lang

    2003-01-01

    Temporal distribution of the H atom and Hz densities in a pulsed microwave hydrogen plasmas has been measured simultaneously by two-photon absorption laser-induced fluorescence (TALIF). The measurement of the H-atom absolute density obtained by NO2 titration in a flow tube reactor shows that the density of H2 could be determined by the measured effective lifetime of the TALIF signal via the quenching equation. The H-atom density of about 1.5×1015cm-3 in both pulsed and stationary phases does not obviously change. It is found that the gas temperature volume effect plays an important role in governing the distributions of the H-atom density and it is mole fraction. The calculated gas temperature is in good consistent with the rotational temperature of H2measured by optical emission spectroscopy in pulsed phase.

  5. Time Ordering Effects on Hydrogen Zeeman-Stark Line Profiles in Low-Density Magnetized Plasmas

    Directory of Open Access Journals (Sweden)

    J. Rosato

    2010-01-01

    Full Text Available Stark broadening of hydrogen lines is investigated in low-density magnetized plasmas, at typical conditions of magnetic fusion experiments. The role of time ordering is assessed numerically, by using a simulation code accounting for the evolution of the microscopic electric field generated by the charged particles moving at the vicinity of the atom. The Zeeman effect due to the magnetic field is also retained. Lyman lines with a low principal quantum number n are first investigated, for an application to opacity calculations; next Balmer lines with successively low and high principal quantum numbers are considered for diagnostic purposes. It is shown that neglecting time ordering results in a dramatic underestimation of the Stark effect on the low-n lines. Another conclusion is that time ordering becomes negligible only when ion dynamics effects vanish, as shown in the case of high-n lines.

  6. Kinetic model of stimulated emission created by resonance pumping of aluminum laser-induced plasma

    Science.gov (United States)

    Gornushkin, I. B.; Kazakov, A. Ya.

    2017-06-01

    Stimulated emission observed experimentally in an aluminum laser induced plasma is modeled via a kinetic approach. The simulated emission at several cascade transitions is created by a pump laser guided through the plasma at several microseconds after its creation and tuned in resonance with the strong 3s23p-3s24s transition at 266 nm. A two-dimensional space-time collisional radiative plasma model explains the creation of the population inversion and lasing at wavelengths of 2100 n m and 396.1 nm. The population inversion for lasing at 2100 n m is created by depopulation of the ground 3s23p state and population of the 3s25s state via the absorption of the resonant radiation at 266 nm. The population inversion for lasing at 396.1 nm occurs during the laser pulse via the decay of the population of the pumped 3s25s state to the excited 3s24s state via cascade transitions driven optically and by collisions. In particular, efficient are the mixing transitions between neighboring states separated by small gaps on the order of k T at plasma temperatures of 5000-10 000 K. The model predicts that the population inversion and corresponding gain may reach high values even at very moderate pump energy of several μJ per pulse. The efficiency of lasing at 2100 n m and 396.1 nm is estimated to be ˜3% and 0.05%, correspondingly with respect to the pump laser intensity. The gain for lasing at 396.1 nm can reach as high as ˜40 cm-1. The polarization effect that the pump radiation at 266 nm imposes on the stimulated emission at 396.1 nm is discussed. The calculated results are favorably compared to experimental data.

  7. Microwave Plasma Chemical Vapor Deposition of Diamond Films on Silicon From Ethanol and Hydrogen

    Institute of Scientific and Technical Information of China (English)

    马志斌; 汪建华; 王传新; 满卫东

    2003-01-01

    Diamond films with very smooth surface and good optical quality have been deposited onto silicon substrate using microwave plasma chemical vapor deposition (MPCVD) from a gas mixture of ethanol and hydrogen at a low substrate temperature of 450 ℃. The effects of the substrate temperature on the diamond nucleation and the morphology of the diamond film have been investigated and observed with scanning electron microscopy (SEM). The microstructure and the phase of the film have been characterized using Raman spectroscopy and X-ray diffraction (XRD). The diamond nucleation density significantly decreases with the increasing of the substrate temperature. There are only sparse nuclei when the substrate temperature is higher than 800 ℃ although the ethanol concentration in hydrogen is very high. That the characteristic diamond peak in the Raman spectrum of a diamond film prepared at a low substrate temperature of 450 ℃ extends into broadband indicates that the film is of nanophase. No graphite peak appeared in the XRD pattern confirms that the film is mainly composed of SP3 carbon. The diamond peak in the XRD pattern also broadens due to the nanocrystalline of the film.

  8. Capacitively coupled hydrogen plasmas sustained by tailored voltage waveforms: vibrational kinetics and negative ions control

    Science.gov (United States)

    Diomede, P.; Bruneau, B.; Longo, S.; Johnson, E.; Booth, J.-P.

    2017-07-01

    A comprehensive hybrid model of a hydrogen capacitively coupled plasma, including a detailed description of the molecular vibrational kinetics, has been applied to the study of the effect of tailored voltage waveforms (TVWs) on the production kinetics and transport of negative ions in these discharges. Two kinds of TVWs are considered, valleys-to-peaks and saw-tooth, with amplitude and slope asymmetry respectively. By tailoring the voltage waveform only, it is possible to exert substantial control over the peak density and position of negative ions inside the discharge volume. This control is particularly effective for saw-tooth waveforms. Insight into the mechanisms allowing this control is provided by an analysis of the model results. This reveals the roles of the vibrational distribution function and of the electron energy distribution and their correlations, as well as changes in the negative ion transport in the electric field when using different TVWs. Considering the chemical reactivity of H- ions, the possibility of a purely electrical control of the negative ion cloud in a reactor operating with a feedstock gas diluted by hydrogen may find interesting applications. This is the first study of vibrational kinetics in the context of TVWs in molecular gases.

  9. A Transition to Metallic Hydrogen: Evidence of the Plasma Phase Transition

    Science.gov (United States)

    Silvera, Isaac; Zaghoo, Mohamed; Salamat, Ashkan

    The insulator-metal transition in hydrogen is one of the most outstanding problems in condensed matter physics. The high-pressure metallic phase is now predicted to be liquid atomic from T =0 K to very high temperatures. We have conducted measurements of optical properties of hot dense hydrogen in the region of 1.1-1.7 Mbar and up to 2200 K in a diamond anvil cell using pulsed laser heating of the sample. We present evidence in two forms: a plateau in the heating curves (average laser power vs temperature) characteristic of a first-order phase transition with latent heat, and changes in transmittance and reflectance characteristic of a metal for temperatures above the plateau temperature. For thick films the reflectance saturates at ~0.5. The phase line of this transition has a negative slope in agreement with theories of the so-called plasma phase transition. The NSF, Grant DMR-1308641, the DOE Stockpile Stewardship Academic Alliance Program, Grant DE-FG52-10NA29656, and NASA Earth and Space Science Fellowship Program, Award NNX14AP17H supported this research.

  10. Experimental and theoretical determination of the efficiency of a sub-atmospheric flowing high power cascaded arc hydrogen plasma source

    NARCIS (Netherlands)

    Vijvers, W. A. J.; D.C. Schram,; Shumack, A. E.; Cardozo, N. J. L.; Rapp, J.; van Rooij, G. J.

    2010-01-01

    Cascaded arc plasma sources with channel diameters between 4 and 8mm were experimentally investigated at discharge currents up to 900A and hydrogen (H-2) flow rates up to 10 slm. Pressure measurements at the arc exit showed that the heavy particle temperature in the discharge channel was about 0.8 e

  11. Gaseous hydrocarbon production by the reaction of coal char with hydrogen plasma at relatively lower microwave power

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, S.; Nishikubo, K.; Imamura, T. [Kyushu National Industrial Research Institute, Tosu (Japan)

    1998-07-01

    Experimental conditions such as reaction temperature, microwave power and reaction pressure were changed in the reaction of carbon with hydrogen plasma. Methane was major product and other hydrocarbons such as acetylene and C2-C4 hydrocarbons were also produced. Methane production shows its maximum at 700-900 K and at 30W of microwave power. 2 figs.

  12. Coal pyrolysis to acetylene using DC hydrogen plasma torch: effects of system variables on acetylene concentration - article no. 055505

    Energy Technology Data Exchange (ETDEWEB)

    Chen, L.W.; Meng, Y.D.; Shen, J.; Shu, X.S.; Fang, S.D.; Xiong, X.Y. [Chinese Academy of Sciences, Hefei (China). Inst. of Plasma Physics

    2009-03-15

    In order to unveil the inner mechanisms that determine acetylene concentration, experimental studies on the effect of several parameters such as plasma torch power, hydrogen flux and coal flux were carried out from coal pyrolysis in a DC plasma torch. Xinjiang long flame coals including volatile constituents at a level of about 42% were used in the experiment. Under the following experimental conditions, namely plasma torch power, hydrogen flow rate and pulverized coal feed speed of 2.12 MW, 32 kg h{sup -1} and 900 kg h{sup -1}, respectively, acetylene volume concentration of about 9.4% was achieved. The experimental results indicate that parameters such as plasma torch power and coal flux play important roles in the formation of acetylene. Acetylene concentration increases inconspicuously with hydrogen flux. A chemical thermodynamic equilibrium model using the free energy method is introduced in this paper to numerically simulate each experimental condition. The numerical results are qualitatively consistent with the experimental results. Two parameters, i.e. the gas temperature and the ratio of hydrogen/carbon, are considered to be the dominant and independent factors that determine acetylene concentration.

  13. Hydrogen-bonding studies of pyridine and 0-phenylphenol with coal asphaltenes by multi-nuclei magnetic resonance

    Energy Technology Data Exchange (ETDEWEB)

    Schweighardt, F.K.; Friedel, R.A.; Retcofsky, H.L.

    1976-01-01

    Proton, carbon, and nitrogen-14 nuclear magnetic resonance studies are reported of hydrogen bonding between the OH proton of o-phenylphenol (OPP) and the nitrogen electron donor of pyridine (Py). Data are also reported on the hydrogen bonding of the acid and base components of coal-derived asphaltenes with the model system. Determination was made of the equilibrium constant of the 1:1 complex between OPP and Py from the proton NMR studies. Qualitative results are reported from the /sup 13/C and /sup 14/N studies of the model system (OPP-Py) with the individual asphaltene fractions. Because of the recent renewed interest in coal liquefaction this investigation may provide a starting point for future research. 7 figures.

  14. Probing the resonance potential in the F atom reaction with hydrogen deuteride with spectroscopic accuracy

    Science.gov (United States)

    Ren, Zefeng; Che, Li; Qiu, Minghui; Wang, Xingan; Dong, Wenrui; Dai, Dongxu; Wang, Xiuyan; Yang, Xueming; Sun, Zhigang; Fu, Bina; Lee, Soo-Y.; Xu, Xin; Zhang, Dong H.

    2008-01-01

    Reaction resonances are transiently trapped quantum states along the reaction coordinate in the transition state region of a chemical reaction that could have profound effects on the dynamics of the reaction. Obtaining an accurate reaction potential that holds these reaction resonance states and eventually modeling quantitatively the reaction resonance dynamics is still a great challenge. Up to now, the only viable way to obtain a resonance potential is through high-level ab initio calculations. Through highly accurate crossed-beam reactive scattering studies on isotope-substituted reactions, the accuracy of the resonance potential could be rigorously tested. Here we report a combined experimental and theoretical study on the resonance-mediated F + HD → HF + D reaction at the full quantum state resolved level, to probe the resonance potential in this benchmark system. The experimental result shows that isotope substitution has a dramatic effect on the resonance picture of this important system. Theoretical analyses suggest that the full-dimensional FH2 ground potential surface, which was believed to be accurate in describing the resonance picture of the F + H2 reaction, is found to be insufficiently accurate in predicting quantitatively the resonance picture for the F + HD → HF + D reaction. We constructed a global potential energy surface by using the CCSD(T) method that could predict the correct resonance peak positions as well as the dynamics for both F + H2 → HF + H and F + HD → HF + D, providing an accurate resonance potential for this benchmark system with spectroscopic accuracy. PMID:18687888

  15. Hydrogen and Carbon Black Production from the Degradation of Methane by Thermal Plasma

    Directory of Open Access Journals (Sweden)

    Leila Cottet

    2014-05-01

    Full Text Available Methane gas (CH4 is the main inducer of the so called greenhouse gases effect. Recent scientific research aims to minimize the accumulation of this gas in the atmosphere and to develop processes capable of producing stable materials with added value. Thermal plasma technology is a promising alternative to these applications, since it allows obtaining H2 and solid carbon from CH4, without the parallel formation of byproducts such as CO2 and NOx. In this work, CH4 was degraded by thermal plasma in order to produce hydrogen (H2 and carbon black. The degradation efficiency of CH4, selectivity for H2 production as well as the characterization of carbon black were studied. The best results were obtained in the CH4 flow rate of 5 L min-1 the degradation percentage and the selectivity for H2 production reached 98.8 % and 48.4 %, respectively. At flow rates of less than 5 L min-1 the selectivity for H2 production increases and reaches 91.9 %. The carbon black has obtained amorphous with hydrophobic characteristics and can be marketed to be used in composite material, and can also be activated chemically and/or physically and used as adsorbent material.

  16. Synthesis of Fe-Al nanoparticles by hydrogen plasma-metal reaction

    CERN Document Server

    Liu Tong; Li Xing Guo

    2003-01-01

    Fe-Al nanoparticles of eight kinds have been prepared by hydrogen plasma-metal reaction. The morphology, crystal structure, and chemical composition of the nanoparticles obtained were investigated by transmission electron microscopy (TEM), x-ray diffractometry (XRD), and induction-coupled plasma spectroscopy. The particle size was determined by TEM and Brunaumer-Emmet-Teller gas adsorption. It was found that all the nanoparticles have spherical shapes, with average particle size in the range of 29-46 nm. The oxide layer in nanoparticles containing Al after passivation is not observable by XRD and TEM. The Al contents in Fe-Al ultrafine particles are about 1.2-1.5 times those in the master alloys. The evaporation speeds of Al and Fe in Fe-Al alloys are mutually accelerated at a certain composition. The crystal structures of the Fe-Al nanoparticles vary with the composition of the master alloys. Pure Fe sub 3 Al (D0 sub 3) and FeAl (B2) structures are successfully produced with 15 and 25 at.% Al in bulks, respe...

  17. Effect of radicals combination on acetylene yield in process of coal pyrolysis by hydrogen plasma

    Energy Technology Data Exchange (ETDEWEB)

    Dai, B.; Fan, Y.; Yang, J.; Xiao, J. [Tsinghua University, Beijing (China). Dept. of Engineering Mechanics

    1999-07-01

    A new process for production of acetylene by pyrolysis of coal in hydrogen plasma overcomes the disadvantage of discontinuity and pollution in the conventional carbide method. Complex homogeneous reactions take place after pulverized coal is injected into a high-temperature plasma reactor. In order to preserve C{sub 2}H{sub 2} in low-temperature gas, quenching is needed to avoid the dissociation of acetylene. The objective of this paper is to indicate that radicals recombination is also important in acetylene production. Therefore the quenching process should be optimized to obtain high yield of acetylene. In this work, C-H equilibrium system in high-temperature range of 2000-5000 K is obtained using the free energy minimization method. At lower temperature, the decomposition of acetylene can be avoided while the recombination reaction of radicals C{sub 2}H and H will not be interrupted. As a result, the acetylene concentration in quenched gas will increase. The theoretical acetylene content in quenched gas is computed using the radical recombination mechanism based on the composition of thermal equilibrium, and the optimized C/H ratio is determined simultaneously. The maximum acetylene content is 59.9% in volume. 4 refs., 3 figs., 1 tab.

  18. Thermodynamic analysis of coal pyrolysis to acetylene in hydrogen plasma reactor

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Changning; Chen, Jiaqi; Cheng, Yi [Department of Chemical Engineering, Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Tsinghua University, Beijing 100084 (China)

    2010-08-15

    A systematic re-examination of the thermodynamic study on the process of coal pyrolysis to acetylene in a hydrogen plasma reactor was performed with referenced pilot-plant data at the scale of 2-MW plasma. At the ultra-high temperature conditions, the gas phase composition may reach thermodynamic equilibrium immediately no matter whether the solid carbon exists or not. The mass ratio of C/H in the gaseous phase plays a significant role in the acetylene concentration at the thermodynamic equilibrium states. It is demonstrated either in thermodynamics calculation or in hot tests that a mass ratio of C/H near or above 2 is essential to gain an acceptable concentration of acetylene in the mixed gases, which indicates that the mixing efficiency between gas and coal particles near the coal injection point becomes pivotal to the yield of acetylene for its direct influence on the devolatilization of coal, i.e., the gaseous C/H ratio. Being consistent with the hot test experience, the extra amount of water added into the system may inhibit the production of acetylene. However, the addition of methane might impose a positive effect on the yield of acetylene and therefore on the overall reactor performance. (author)

  19. Ion acceleration enhancement in laser-generated plasmas by metallic doped hydrogenated polymers

    Directory of Open Access Journals (Sweden)

    Angela Maria Mezzasalma

    2009-05-01

    Full Text Available Laser-generated plasmas in vacuum were obtained by ablating hydrogenated polymers at the Physics Department of the University of Messina and at the PALS Laboratory in Prague. In the first case a 3 ns,532 nm Nd:Yag laser, at 1010 W/cm2 intensity was employed.In the second case a 300 ps, 438 nm iodine laser, at 5x1014W/cm2 intensity was employed. Different ion collectors were usedin a time-of-flight configuration to monitor the ejected ions from theplasma at different angles with respect to the direction normal tothe target surface. Measurements demonstrated that the mean ionvelocity, directed orthogonally to the target surface, increases forablation of polymers doped with metallic elements with respect tothe nondoped one. The possible mechanism explaining theresults can be found in the different electron density of theplasma, due to the higher number of electrons coming from the dopingelements. This charge enhancement increases the equivalent ionvoltage acceleration, i.e. the electric field generated in the non-equilibrium plasma placed in front of the ablated target surface.

  20. Plasma expansion across a transverse magnetic field in a negative hydrogen ion source for fusion

    Science.gov (United States)

    Fantz, U.; Schiesko, L.; Wünderlich, D.

    2014-08-01

    High power negative hydrogen ion sources operating at 0.3 Pa are a key component of the neutral beam injection systems for the international fusion experiment ITER. To achieve the required large ion current at a tolerable number of co-extracted electrons the source is equipped with a magnetic filter field (up to 10 mT). The IPP prototype source (1/8 of the area of the ITER source) has been equipped with a flexible magnetic filter frame to perform filter field studies (position, polarity, strength). Axial profiles of the plasma parameters are measured with two Langmuir probes, positioned in the upper and the lower half of the expansion chamber. In addition to the expected decrease in electron temperature and density a vertical drift develops the direction depending on the polarity of the field. Without field no drift is observed. The drift is less pronounced in caesium seeded discharges and almost vanishes in deuterium, indicating an influence of the ion mass on the drift. A comparison with results from a half-size ITER source reveals that the plasma is much more uniform in the large source.

  1. Hydrogen.

    Science.gov (United States)

    Bockris, John O'M

    2011-11-30

    The idea of a "Hydrogen Economy" is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO₂ in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H₂ from the electrolyzer. Methanol made with CO₂ from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan). Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs) by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  2. Helium and hydrogen plasma waveguides for high-intensity laser channeling

    Science.gov (United States)

    Zgadzaj, Rafal Bogumil

    The results of cross polarized pump-probe experiments in preformed He plasma waveguides are reported. Pump and probe have same wavelength and duration of 800nm and 80fs respectively. Peak pump intensity is Iguided = 0.2x1018 W/cm2 ˜1000 Iprobe. Single shot probe spectra and mode profiles at the channel exit are discriminated from the pump with a polarization analyzer and captured at various relative time delays Deltat. Frequency-domain interference (FDI) between the probe and a weak depolarized component of the pump is observed for |Deltat| ≳ 100fs. Although the depolarized component is nearly undetectable through measurement of pump leakage alone, FDI sensitively reveals its substantially non-Gaussian structure. The possible depolarization mechanisms are analyzed. When probe is positioned at the leading edge of the pump, Deltat ≲ 0, its spectrum suffers a blue shift not measurable in the transmitted pump itself. The evidence suggests the channel interior is fully ionized and the partially formed channel ends are the origin of both depolarization and blue shift. A robust, pulsed, differentially-pumped plasma channel generation cell for high intensity guiding experiments has been developed. The design includes an axicon lens, windows for transverse interferometry, and permits injection of one or two different gases (main gas plus high Z seed gas) with several millisecond injection times and simultaneous 0.1ms pressure sensing resolution. Very well formed plasma waveguides have been formed in helium as well as hydrogen, at repeatable and well controlled pressures up to 1000Torr, with very uniform interior density, rapid density drop at boundaries, and very low exterior density. The possible danger associated with the use of large amounts of hydrogen was considered and a complex safety system was designed, constructed and used. Extensive analysis of channel profile reconstruction through transverse interferometry was performed. This includes an intuitive

  3. Hydrogen atom in a quantum plasma environment under the influence of Aharonov-Bohm flux and electric and magnetic fields

    CERN Document Server

    Falaye, Babatunde James; Silva-Ortigoza, Ramón; Dong, Shi-Hai

    2016-01-01

    This study presents the confinement influences of Aharonov-Bohm-flux (AB-flux), electric and magnetic fields directed along $z$-axis and encircled by quantum plasmas, on the hydrogen atom. The all-inclusive effects result to a strongly attractive system while the localizations of quantum levels change and the eigenvalues decrease. We find that, the combined effect of the fields is stronger than solitary effect and consequently, there is a substantial shift in the bound state energy of the system. We also find that to perpetuate a low-energy medium for hydrogen atom in quantum plasmas, strong electric field and weak magnetic field are required, where AB-flux field can be used as a regulator. The application of perturbation technique utilized in this paper is not restricted to plasma physics, it can also be applied in molecular physics.

  4. The influence of methane/argon plasma composition on the formation of the hydrogenated amorphous carbon films

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Hsin-Hung [Department of Materials Science and Engineering, National Cheng Kung University, No. 1, University Road, Tainan 70101, Taiwan (China); Liao, Jiunn-Der, E-mail: jdliao@mail.ncku.edu.t [Department of Materials Science and Engineering, National Cheng Kung University, No. 1, University Road, Tainan 70101, Taiwan (China); Weng, Chih-Chiang; Hsieh, Jui-Fu; Chang, Chia-Wei [Department of Materials Science and Engineering, National Cheng Kung University, No. 1, University Road, Tainan 70101, Taiwan (China); Lin, Chao-Hsien; Cho, Ting-Pin [Metal Industries Development and Research Centre, 1001 Kaonan Highway, Kaohsiung 811, Taiwan (China)

    2011-01-03

    The quality of the a-C:H films was particularly correlated with the mixed ratio of methane/argon plasma. For a constant supply of energy and flowing rate, the optical emission from H{sub {alpha}} intensity linearly increased with the addition of methane in argon plasma, while that from intensities of radiation of diatmoic radicals (CH*and C{sub 2}*) exponentially decreased. For the a-C:H films, the added methane in argon plasma tended to raise the quantity of hydrogenated carbon or sp{sup 3} C-H structure, which exponentially decreased the nano-hardness and friction coefficient of the films. In contrast, the electric resistance of the films enlarged dramatically with the increase of the methane content in argon plasma. It is therefore advantageous to balance the mechanical properties and electrical resistance of the a-C:H film by adjusting plasma composition in the course of the film-growing process.

  5. Laser interaction based on resonance saturation (LIBORS): an alternative to inverse bremsstrahlung for coupling laser energy into a plasma.

    Science.gov (United States)

    Measures, R M; Drewell, N; Cardinal, P

    1979-06-01

    Resonance saturation represents an efficient and rapid method of coupling laser energy into a gaseous medium. In the case of a plasma superelastic collision quenching of the laser maintained resonance state population effectively converts the laser beam energy into translational energy of the free electrons. Subsequently, ionization of the laser pumped species rapidly ensues as a result of both the elevated electron temperature and the effective reduction of the ionization energy for those atoms maintained in the resonance state by the laser radiation. This method of coupling laser energy into a plasma has several advantages over inverse bremsstrahlung and could therefore be applicable to several areas of current interest including plasma channel formation for transportation of electron and ion beams, x-ray laser development, laser fusion, negative ion beam production, and the conversion of laser energy to electricity.

  6. Nanoscale femtosecond imaging of transient hot solid density plasmas with elemental and charge state sensitivity using resonant coherent diffraction

    CERN Document Server

    Kluge, Thomas; Chung, H -K; Gutt, C; Huang, L G; Zacharias, M; Schramm, U; Cowan, T E

    2015-01-01

    Here we propose to exploit the low energy bandwidth, small wavelength and penetration power of ultrashort pulses from XFELs for resonant Small Angle Scattering (SAXS) on plasma structures in laser excited plasmas. Small angle scattering allows to detect nanoscale density fluctuations in forward scattering direction. Typically, the SAXS signal from laser excited plasmas is expected to be dominated by the free electron distribution. We propose that the ionic scattering signal becomes visible when the X-ray energy is in resonance with an electron transition between two bound states (Resonant coherent X-ray diffraction, RCXD). In this case the scattering cross-section dramatically increases so that the signal of X-ray scattering from ions silhouettes against the free electron scattering background which allows to measure the opacity and derived quantities with high spatial and temporal resolution, being fundamentally limited only by the X-ray wavelength and timing. Deriving quantities such as ion spatial distribu...

  7. Zwitterionic polymer-modified silicon microring resonators for label-free biosensing in undiluted human plasma.

    Science.gov (United States)

    Kirk, James T; Brault, Norman D; Baehr-Jones, Tom; Hochberg, Michael; Jiang, Shaoyi; Ratner, Daniel M

    2013-04-15

    A widely acknowledged goal in personalized medicine is to radically reduce the costs of highly parallelized, small fluid volume, point-of-care and home-based diagnostics. Recently, there has been a surge of interest in using complementary metal-oxide-semiconductor (CMOS)-compatible silicon photonic circuits for biosensing, with the promise of producing chip-scale integrated devices containing thousands of orthogonal sensors, at minimal cost on a per-chip basis. A central challenge in biosensor translation is to engineer devices that are both sensitive and specific to a target analyte within unprocessed biological fluids. Despite advances in the sensitivity of silicon photonic biosensors, poor biological specificity at the sensor surface remains a significant factor limiting assay performance in complex media (i.e. whole blood, plasma, serum) due to the non-specific adsorption of proteins and other biomolecules. Here, we chemically modify the surface of silicon microring resonator biosensors for the label-free detection of an analyte in undiluted human plasma. This work highlights the first application of a non-fouling zwitterionic surface coating to enable silicon photonic-based label-free detection of a protein analyte at clinically relevant sensitivities in undiluted human plasma.

  8. Diagnostics of plasma decay and afterglow transient of an electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, O; Ropponen, T; Toivanen, V; Kalvas, T; Arje, J; Koivisto, H, E-mail: olli.tarvainen@jyu.f [University of Jyvaeskylae, Department of Physics, Accelerator Laboratory PO Box 35 (YFL), 40500 Jyvaeskylae (Finland)

    2010-08-15

    The electron cyclotron resonance ion sources at the JYFL (University of Jyvaeskylae, Department of Physics) accelerator laboratory have been operated in pulsed mode to study the decay of bremsstrahlung emission and ion beam currents of different charge states. The purpose of the experiments is to gain understanding on the ion source parameters affecting the afterglow. It was observed that the bremsstrahlung emission characteristics during the afterglow and decay times of extracted ion beam currents are virtually independent of the ion source tuning parameters. The decay time of different charge states was found to be almost inversely proportional to the square of the ion charge. The result is in good agreement with a simple theoretical model based on diffusion of ions from the magnetic field of the ion source. It was observed that the plasma decay time is shorter in the case of the ion source with lower operation frequency and, thus, lower magnetic field strength. The scaling between the ion sources supports a model based on Bohm diffusion, arising from non-linear effects such as instabilities and fluctuating fields in turbulent plasma. The experiments provide information on the mechanisms causing instabilities during the plasma decay.

  9. Hydrogen

    Directory of Open Access Journals (Sweden)

    John O’M. Bockris

    2011-11-01

    Full Text Available The idea of a “Hydrogen Economy” is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO2 in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H2 from the electrolyzer. Methanol made with CO2 from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan. Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  10. Surface cleaning and etching of 4H-SiC(0001) using high-density atmospheric pressure hydrogen plasma.

    Science.gov (United States)

    Watanabe, Heiji; Ohmi, Hiromasa; Kakiuchi, Hiroaki; Hosoi, Takuji; Shimura, Takayoshi; Yasutake, Kiyoshi

    2011-04-01

    We propose low-damage and high-efficiency treatment of 4H-SiC(0001) surfaces using atmospheric pressure (AP) hydrogen plasma. Hydrogen radicals generated by the AP plasma was found to effectively remove damaged layers on SiC wafers and improve surface morphology by isotropic etching. Localized high-density AP plasma generated with a cylindrical rotary electrode provides a high etching rate of 1.6 microm/min and yields smooth morphology by eliminating surface corrugation and scratches introduced by wafer slicing and lapping procedures. However, high-rate etching with localized plasma was found to cause an inhomogeneous etching profile depending on the plasma density and re-growth of the poly-Si layer at the downstream due to the decomposition of the vaporized SiH(x) products. On the other hand, for the purpose of achieving moderate etching and ideal cleaning of SiC surfaces, we demonstrated the application of a novel porous carbon electrode to form delocalized and uniform AP plasma over 4 inches in diameter. We obtained a reasonably moderate etching rate of 0.1 microm/min and succeeded in fabricating damage-free SiC surfaces.

  11. Removal of gas-phase ammonia and hydrogen sulfide using photocatalysis, nonthermal plasma, and combined plasma and photocatalysis at pilot scale.

    Science.gov (United States)

    Maxime, Guillerm; Amine, Assadi Aymen; Abdelkrim, Bouzaza; Dominique, Wolbert

    2014-11-01

    This study focuses on the removal of gas-phase ammonia (NH3) and hydrogen sulfide (H2S) in a continuous reactor. Photocatalysis and surface dielectric barrier discharge (SDBD) plasma are studied separately and combined. Though the removal of volatile organic compounds by coupling plasma and photocatalysis has been reported on a number of studies in laboratory scale, this is as far as we know the first time that it is used to remove inorganic malodorous pollutants. While each separate process is able to degrade ammonia and hydrogen sulfide, a synergetic effect appears when they are combined at a pilot scale, leading to removal capacity higher than the sum of each separate process. The removal capacity is higher when the gas circulates at a higher flow rate and when pollutant concentration is higher. The presence of water vapor in the gas is detrimental to the efficiency of the process. Operating conditions also influence the production of nitrogen oxides and ozone.

  12. A Proposal for a Novel H- Ion Source Based on Electron Cyclotron Resonance Plasma Heating and Surface Ionization

    Science.gov (United States)

    Tarvainen, O.; Kurennoy, S.

    2009-03-01

    A design for a novel H- ion source based on electron cyclotron resonance plasma heating and surface ionization is presented. The plasma chamber of the source is an rf-cavity designed for TE111 eigenmode at 2.45 GHz. The desired mode is excited with a loop antenna. The ionization process takes place on a cesiated surface of a biased converter electrode. The H- ion beam is further "self-extracted" through the plasma region. The magnetic field of the source is optimized for plasma generation by electron cyclotron resonance heating, and beam extraction. The design features of the source are discussed in detail and the attainable H- ion current, beam emittance and duty factor of the novel source are estimated.

  13. Intramolecular resonance-assisted hydrogen bonds: A theoretical description by means of atomic charges and charge fluxes

    Science.gov (United States)

    Baranović, Goran

    2014-01-01

    The characterization of intramolecular H-bonds in terms of atomic charges and charge fluxes (at the B3LYP/cc-pVTZ level of theory) has been extended to the case of the so called resonance-assisted (RA) H-bonds. A quadratic correlation between the charge fluxes ϕH and the molecular IR absorption coefficients E that includes the entire family of the studied systems (31 of them) containing both intra- and intermolecular hydrogen bonds (O-H⋯O/N) confirmed the critical importance of the charge fluxes on the IR intensity enhancements. Since they reflect changing of the atomic charge distribution during the normal modes of vibrations, the dynamic nature of hydrogen bonding properties has been re-emphasized. The changes of the charge flux of the hydroxyl hydrogen in an RA intramolecular H-bond are between those for “free” OH bonds and the values calculated for intermolecular H-bonds. The transition “free” → intramolecular → intermolecular is gradual and therefore the hydrogen charge flux can be considered as practically sufficient to give quantitative measure to the intuitively obvious statement that “intramolecular H-bonding is somehow in between no H-bonding situation and intermolecular H-bonding” and thus provide a quantitative and yet simple parameterization of H-bond strength. In strictly planar molecules, the difference of the sums of charges of atoms participating in the 6-membered H-bond ring ΔΣ can serve as a measure of the charge delocalization after the H-bond is formed. The electronic charge is withdrawn from the group of six atoms when the H-bond is formed in nitrophenol (ΔΣ = -0.07), while the opposite is true (ΔΣ = +0.03) for 2-hydroxy benzylidene amine. The corresponding values of the geometrical resonance parameter Δ are 0.39 and 0.37, respectively, similar to those found for 2-hydroxy acetophenone and 2-hydroxy benzaldehyde. The extent of the π-electron delocalization as measured by the resonance parameter Δ does not follow

  14. Influence of the initial transient state of plasma and hydrogen pre-treatment on the interface properties of a silicon heterojunction fabricated by PECVD

    Institute of Scientific and Technical Information of China (English)

    Wu Chunbo; Zhou Yuqin; Li Guorong; Liu Fengzhen

    2011-01-01

    Amorphous/crystalline silicon heterojunctions (a-Si:H/c-Si SHJ) were prepared by plasma-enhanced chemical vapor deposition (PECVD).The influence of the initial transient state of the plasma and the hydrogen pre-treatment on the interfacial properties of the heterojunctions was studied.Experimental results indicate that:(1) The instability of plasma in the initial stage will damage the surface ofc-Si.Using a shutter to shield the substrate for 100 s from the starting discharge can prevent the influence of the instable plasma process on the Si surface and also the interface between a-Si and c-Si.(2) The effect of hydrogen pre-treatment on interfacial passivation is constrained by the extent of hydrogen plasma bombardment and the optimal time for hydrogen pre-treatment is about 60 s.

  15. Individual variation in macronutrient regulation measured by proton magnetic resonance spectroscopy of human plasma.

    Science.gov (United States)

    Park, Youngja; Kim, Seoung Bum; Wang, Bing; Blanco, Roberto A; Le, Ngoc-Anh; Wu, Shaoxiong; Accardi, Carolyn J; Alexander, R Wayne; Ziegler, Thomas R; Jones, Dean P

    2009-07-01

    Proton nuclear magnetic resonance ((1)H-NMR) spectroscopy of plasma provides a global metabolic profiling method that shows promise for clinical diagnostics. However, cross-sectional studies are complicated by a lack of understanding of intraindividual variation, and this limits experimental design and interpretation of data. The present study determined the diurnal variation detected by (1)H NMR spectroscopy of human plasma. Data reduction methods revealed three time-of-day metabolic patterns, which were associated with morning, afternoon, and night. Major discriminatory regions for these time-of-day patterns included the various kinds of lipid signals (-CH(2)- and -CH(2)OCOR), and the region between 3 and 4 ppm heavily overlapped with amino acids that had alpha-CH and alpha-CH(2). The phasing and duration of time-of-day patterns were variable among individuals, apparently because of individual difference in food processing/digestion and absorption and clearance of macronutrient energy sources (fat, protein, carbohydrate). The times of day that were most consistent among individuals, and therefore most useful for cross-sectional studies, were fasting morning (0830-0930), postprandial afternoon (1430-1630), and nighttime samples (0430-0530). Importantly, the integrated picture of metabolism provided by (1)H-NMR spectroscopy of plasma suggests that this approach is suitable to study complex regulatory processes, including eating patterns/eating disorders, upper gastrointestinal functions (gastric emptying, pancreatic, biliary functions), and absorption/clearance of macronutrients. Hence, (1)H-NMR spectroscopy of plasma could provide a global metabolic tolerance test to assess complex processes involved in disease, including eating disorders and the range of physiological processes causing dysregulation of energy homeostasis.

  16. Plasma Kinetics in Electrical Discharge in Mixture of Air, Water and Ethanol Vapors for Hydrogen Enriched Syngas Production

    CERN Document Server

    Shchedrin, A I; Ryabtsev, A V; Chernyak, V Ya; Yukhymenko, V V; Olszewski, S V; Naumov, V V; Prysiazhnevych, I V; Solomenko, E V; Demchina, V P; Kudryavtsev, V S

    2008-01-01

    The complex theoretical and experimental investigation of plasma kinetics of the electric discharge in the mixture of air and ethanol-water vapors is carried out. The discharge was burning in the cavity, formed by air jets pumping between electrodes, placed in aqueous ethanol solution. It is found out that the hydrogen yield from the discharge is maximal in the case when ethanol and water in the solution are in equal amounts. It is shown that the hydrogen production increases with the discharge power and reaches the saturation at high value. The concentrations of the main stable gas-phase components, measured experimentally and calculated numerically, agree well in the most cases.

  17. Rovibrationally Resolved Time-Dependent Collisional-Radiative Model of Molecular Hydrogen and Its Application to a Fusion Detached Plasma

    Directory of Open Access Journals (Sweden)

    Keiji Sawada

    2016-12-01

    Full Text Available A novel rovibrationally resolved collisional-radiative model of molecular hydrogen that includes 4,133 rovibrational levels for electronic states whose united atom principal quantum number is below six is developed. The rovibrational X 1 Σ g + population distribution in a SlimCS fusion demo detached divertor plasma is investigated by solving the model time dependently with an initial 300 K Boltzmann distribution. The effective reaction rate coefficients of molecular assisted recombination and of other processes in which atomic hydrogen is produced are calculated using the obtained time-dependent population distribution.

  18. Ultralow field emission from thinned, open-ended, and defected carbon nanotubes by using microwave hydrogen plasma processing

    Energy Technology Data Exchange (ETDEWEB)

    Deng, Jian-Hua, E-mail: jhdeng1983@163.com [College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387 (China); Cheng, Lin; Wang, Fan-Jie; Yu, Bin; Li, Guo-Zheng; Li, De-Jun [College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387 (China); Cheng, Guo-An [Key Laboratory of Beam Technology and Material Modification of Ministry of Education, Beijing Normal University, Beijing 100875 (China)

    2015-01-01

    Graphical abstract: Thinned, open-ended, and defected carbon nanotubes were prepared by using hydrogen plasma processing. The processed carbon nanotubes have far better field emission performance than that of the pristine ones. - Highlights: • CVD prepared CNT arrays were processed by microwave hydrogen plasma. • Thinned, open-ended, and defected CNTs were obtained. • Processed CNTs have far better field emission performance than the pristine ones. • Processed CNTs have applicable emission stability after being perfectly aged. - Abstract: Ultralow field emission is achieved from carbon nanotubes (CNTs) by using microwave hydrogen plasma processing. After the processing, typical capped CNT tips are removed, with thinned, open-ended, and defected CNTs left. Structural analyses indicate that the processed CNTs have more SP{sup 3}-hybridized defects as compared to the pristine ones. The morphology of CNTs can be readily controlled by adjusting microwave powers, which change the shape of CNTs by means of hydrogen plasma etching. Processed CNTs with optimal morphology are found to have an ultralow turn-on field of 0.566 V/μm and threshold field of 0.896 V/μm, much better than 0.948 and 1.559 V/μm of the as-grown CNTs, respectively. This improved FE performance is ascribed to the structural changes of CNTs after the processing. The thinned and open-ended shape of CNTs can facilitate electron tunneling through barriers and additionally, the increased defects at tube walls can serve as new active emission sites. Furthermore, our plasma processed CNTs exhibit excellent field emission stability at a large emission current density of 10.36 mA/cm{sup 2} after being perfectly aged, showing promising prospects in applications as high-performance vacuum electron sources.

  19. Dynamical resonances in the fluorine atom reaction with the hydrogen molecule.

    Science.gov (United States)

    Yang, Xueming; Zhang, Dong H

    2008-08-01

    [Reaction: see text]. The concept of transition state has played a crucial role in the field of chemical kinetics and reaction dynamics. Resonances in the transition state region are important in many chemical reactions at reaction energies near the thresholds. Detecting and characterizing isolated reaction resonances, however, have been a major challenge in both experiment and theory. In this Account, we review the most recent developments in the study of reaction resonances in the benchmark F + H 2 --> HF + H reaction. Crossed molecular beam scattering experiments on the F + H 2 reaction have been carried out recently using the high-resolution, highly sensitive H-atom Rydberg tagging technique with HF rovibrational states almost fully resolved. Pronounced forward scattering for the HF (nu' = 2) product has been observed at the collision energy of 0.52 kcal/mol in the F + H 2 (j = 0) reaction. Quantum dynamical calculations based on two new potential energy surfaces, the Xu-Xie-Zhang (XXZ) surface and the Fu-Xu-Zhang (FXZ) surface, show that the observed forward scattering of HF (nu' = 2) in the F + H 2 reaction is caused by two Feshbach resonances (the ground resonance and first excited resonance). More interestingly, the pronounced forward scattering of HF (nu' = 2) at 0.52 kcal/mol is enhanced considerably by the constructive interference between the two resonances. In order to probe the resonance potential more accurately, the isotope substituted F + HD --> HF + D reaction has been studied using the D-atom Rydberg tagging technique. A remarkable and fast changing dynamical picture has been mapped out in the collision energy range of 0.3-1.2 kcal/mol for this reaction. Quantum dynamical calculations based on the XXZ surface suggest that the ground resonance on this potential is too high in comparison with the experimental results of the F + HD reaction. However, quantum scattering calculations on the FXZ surface can reproduce nearly quantitatively the resonance

  20. Resonant Damping of Propagating Kink Waves in Time-Dependent Magnetic Flux Tube. I. Zero Plasma-pmb{\\upbeta}

    Science.gov (United States)

    Williamson, A.; Erdélyi, R.

    2014-11-01

    We explore the notion of resonant absorption in a dynamic time-dependent magnetised plasma background. Very many works have investigated resonance in the Alfvén and slow MHD continua under both ideal and dissipative MHD regimes. Jump conditions in static and steady systems have been found in previous works, connecting solutions at both sides of the resonant layer. Here, we derive the jump conditions in a temporally dependent, magnetised, inhomogeneous plasma background to leading order in the Wentzel-Kramers-Billouin (WKB) approximation. Next, we exploit the results found in Williamson and Erdélyi ( Solar Phys. 289, 899, 2014) to describe the evolution of the jump condition in the dynamic model considered. The jump across the resonant point is shown to increase exponentially in time. We determined the damping as a result of the resonance over the same time period and investigated the temporal evolution of the damping itself. We found that the damping coefficient, as a result of the evolution of the resonance, decreases as the density gradient across the transitional layer decreases. This has the consequence that in such time-dependent systems resonant absorption may not be as efficient as time progresses.

  1. Parametric decay instability near the upper hybrid resonance in magnetically confined fusion plasmas

    Science.gov (United States)

    Hansen, S. K.; Nielsen, S. K.; Salewski, M.; Stejner, M.; Stober, J.; the ASDEX Upgrade Team

    2017-10-01

    In this paper we investigate parametric decay of an electromagnetic pump wave into two electrostatic daughter waves, particularly an X-mode pump wave decaying into a warm upper hybrid wave (a limit of an electron Bernstein wave) and a warm lower hybrid wave. We describe the general theory of the above parametric decay instability (PDI), unifying earlier treatments, and show that it may occur in underdense and weakly overdense plasmas. The PDI theory is used to explain anomalous sidebands observed in collective Thomson scattering (CTS) spectra at the ASDEX Upgrade tokamak. The theory may also account for similar observations during CTS experiments in stellarators, as well as in some 1st harmonic electron cyclotron resonance and O-X-B heating experiments.

  2. Spectroscopic ellipsometry analysis of silicon nanotips obtained by electron cyclotron resonance plasma etching.

    Science.gov (United States)

    Mendoza-Galván, Arturo; Järrendahl, Kenneth; Arwin, Hans; Huang, Yi-Fan; Chen, Li-Chyong; Chen, Kuei-Hsien

    2009-09-10

    Silicon nanotips fabricated by electron cyclotron resonance plasma etching of silicon wafers are studied by spectroscopic ellipsometry. The structure of the nanotips is composed of columns 100-140 nm wide and spaced by about 200 nm. Ellipsometry data covering a wide spectral range from the midinfrared to the visible are described by modeling the nanotip layer as a graded uniaxial film using the Bruggeman effective medium approximation. The ellipsometry data in the infrared range reveal two absorption bands at 754 and 955 cm(-1), which cannot be resolved with transmittance measurements. These bands indicate that the etching process is accompanied with formation of carbonaceous SiC and CH(n) species that largely modify the composition of the original crystalline silicon material affecting the optical response of the nanotips.

  3. Beam dynamics in resonant plasma wakefield acceleration at SPARC_LAB

    Science.gov (United States)

    Romeo, S.; Anania, M. P.; Chiadroni, E.; Croia, M.; Ferrario, M.; Marocchino, A.; Pompili, R.; Vaccarezza, C.

    2016-09-01

    Strategies to mitigate the increase of witness emittance and energy spread in beam driven plasma wakefield acceleration are investigated. Starting from the proposed resonant wakefield acceleration scheme in quasi-non-linear regime that is going to be carried out at SPARC_LAB, we performed systematic scans of the parameters to be used for drivers. The analysis will show that one of the main requirements to preserve witness quality during the acceleration is to have accelerating and focusing fields that are very stable during all the accelerating length. The difference between the dynamics of the leading bunch and the trailing bunch is pointed out. The classical condition on bunch length kpσz =√{ 2 } seems to be an ideal condition for the first driver within long accelerating lengths. The other drivers show to follow different longitudinal matching conditions. In the end a new method for the investigation of the matching for the first driver is introduced.

  4. Development and experimental evaluation of theoretical models for ion cyclotron resonance frequency heating of tokamak plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Mantsinen, M. [Helsinki Univ. of Technology, Espoo (Finland). Dept. of Technical Physics

    1999-06-01

    Heating with electromagnetic waves in the ion cyclotron range of frequencies (ICRF) is a well-established method for auxiliary heating of present-day tokamak plasmas and is envisaged as one of the main heating techniques for the International Thermonuclear Experimental Reactor (ITER) and future reactor plasmas. In order to predict the performance of ICRF heating in future machines, it is important to benchmark present theoretical modelling with experimental results on present tokamaks. This thesis reports on development and experimental evaluation of theoretical models for ICRF heating at the Joint European Torus (JET). Several ICRF physics effects and scenarios have been studied. Direct importance to the ITER is the theoretical analysis of ICRF heating experiments with deuterium-tritium (D-T) plasmas. These experiments clearly demonstrate the potential of ICRF heating for auxiliary heating of reactor plasmas. In particular, scenarios with potential for good bulk ion heating and enhanced D-T fusion reactivity have been identified. Good bulk ion heating is essential for reactor plasmas in order to obtain a high ion temperature and a high fusion reactivity. In JET good bulk ion heating with ICRF waves has been achieved in high-performance discharges by adding ICRF heating to neutral beam injection. In these experiments, as in other JET discharges where damping at higher harmonics of the ion cyclotron frequency takes place, so-called finite Larmor radius (FLR) effects play an important role. Due to FLR effects, the resonating ion velocity distribution function can have a strong influence on the power deposition. Evidence for this effect has been obtained from the third harmonic deuterium heating experiments. Because of FLR effects, the wave-particle interaction can also become weak at certain ion energies, which prevents resonating ions from reaching higher energies. When interacting with the wave, an ion receives not only a change in energy but also a change in

  5. Vacuum ultraviolet emission from hydrogen microwave plasmas driven by surface waves

    Science.gov (United States)

    Espinho, S.; Felizardo, E.; Tatarova, E.

    2016-10-01

    The vacuum ultraviolet (VUV) radiation emitted by hydrogen surface-wave-driven plasmas operating at microwave frequency (2.45 GHz) and low-pressure conditions (0.1-2 mbar) was investigated, in particular the influence of microwave power and gas pressure on the intensity of the emissions. The strong emission of Lyman H2 ≤ft(\\text{B}{}1 Σ u+-\\text{X}{}1 Σ g+\\right) and Werner H2 ≤ft(\\text{C}{}1{{ \\Pi }u}-\\text{X}{}1 Σ g+\\right) molecular bands in the 80-125 nm spectral range was detected, while the most intense atomic emissions observed correspond to Lyman-α and Lyman-β lines at 121.6 nm and 102.6 nm respectively. An increase of the atomic lines and molecular bands intensities with increasing microwave power at pressure 0.1 mbar was observed. At 2 mbar the VUV spectra are entirely dominated by molecular bands. Theoretical predictions, as obtained from a collisional-radiative model, were validated by the experimental results.

  6. Capacitively coupled hydrogen plasmas sustained by tailored voltage waveforms: excitation dynamics and ion flux asymmetry

    Science.gov (United States)

    Bruneau, B.; Diomede, P.; Economou, D. J.; Longo, S.; Gans, T.; O'Connell, D.; Greb, A.; Johnson, E.; Booth, J.-P.

    2016-08-01

    Parallel plate capacitively coupled plasmas in hydrogen at relatively high pressure (~1 Torr) are excited with tailored voltage waveforms containing up to five frequencies. Predictions of a hybrid model combining a particle-in-cell simulation with Monte Carlo collisions and a fluid model are compared to phase resolved optical emission spectroscopy measurements, yielding information on the dynamics of the excitation rate in these discharges. When the discharge is excited with amplitude asymmetric waveforms, the discharge becomes electrically asymmetric, with different ion energies at each of the two electrodes. Unexpectedly, large differences in the \\text{H}2+ fluxes to each of the two electrodes are caused by the different \\text{H}3+ energies. When the discharge is excited with slope asymmetric waveforms, only weak electrical asymmetry of the discharge is observed. In this case, electron power absorption due to fast sheath expansion at one electrode is balanced by electron power absorption at the opposite electrode due to a strong electric field reversal.

  7. Collisional thermalization of hydrogen and helium in solar-wind plasma.

    Science.gov (United States)

    Maruca, B A; Bale, S D; Sorriso-Valvo, L; Kasper, J C; Stevens, M L

    2013-12-13

    In situ observations of the solar wind frequently show the temperature of α particles (fully ionized helium) Tα to significantly differ from that of protons (ionized hydrogen) Tp. Many heating processes in the plasma act preferentially on α particles, even as collisions among ions act to gradually establish thermal equilibrium. Measurements from the Wind spacecraft's Faraday cups reveal that, at r=1.0  AU from the Sun, the observed values of the α-proton temperature ratio, θαp≡Tα/Tp, has a complex, bimodal distribution. This study applied a simple model for the radial evolution of θαp to these data to compute expected values of θαp at r=0.1  AU. These inferred θαp values have no trace of the bimodality seen in the θαp values measured at r=1.0  AU but are instead consistent with the actions of the known mechanisms for α-particle preferential heating. This result underscores the importance of collisional processes in the dynamics of the solar wind and suggests that similar mechanisms may lead to preferential α-particle heating in both slow and fast wind.

  8. Influence of Wall Material on VUV Emission from Hydrogen Plasma in H- Source

    Science.gov (United States)

    Bacal, M.; Glass-Maujean, M.; Ivanov, A. A., Jr; Nishiura, M.; Sasao, M.; Wada, M.

    2002-11-01

    The study of VUV emission from a hydrogen plasma produced in a filament discharge in a magnetic multicusp device showed that the use of tantalum and tungsten filaments leads to significant differences in the spectra. The effect of the filament material is interpreted in terms of the fresh film of this material, deposited on the wall. The synthetic spectrum convoluted with our apparatus function for the conditions of this experiment (gas temperature 500 K, electron energy 100 eV) agrees roughly well with the spectrum obtained with tungsten covered walls, but not with the spectrum obtained with tantalum covered walls. We show that in the case of tungsten covered walls the E-V singlet excitation is indeed a two-step Franck-Condon transition, going through either B or C state from an initial H2 molecule with v"=0, added to a Franck-Condon transition to highly excited states cascading to the B or C states. The excitation process to high v" states in the case of tantalum covered walls is a three step process, in which the first step is the formation by recombinative desorption on the wall of a vibrationally excited molecule with v"=1 or 2, which serves as the initial molecule in the subsequent E-V excitation through the B state. The results indicate a larger recombination coefficient of atoms on the tantalum covered wall.

  9. Molecular dynamics studies of electron-ion temperature equilibration in hydrogen plasmas within the coupled-mode regime

    Science.gov (United States)

    Benedict, Lorin X.; Surh, Michael P.; Stanton, Liam G.; Scullard, Christian R.; Correa, Alfredo A.; Castor, John I.; Graziani, Frank R.; Collins, Lee A.; Čertík, Ondřej; Kress, Joel D.; Murillo, Michael S.

    2017-04-01

    We use classical molecular dynamics (MD) to study electron-ion temperature equilibration in two-component plasmas in regimes for which the presence of coupled collective modes has been predicted to substantively reduce the equilibration rate. Guided by previous kinetic theory work, we examine hydrogen plasmas at a density of n =1026cm-3 , Ti=105K , and 107K theory including the QSPs. In particular, it is shown that the energy equilibration rates from MD are more similar to those of the theory when coupled modes are neglected. We suggest possible reasons for this surprising result and propose directions of further research along these lines.

  10. Direct Microscopic Study of Doubly Polarized Atomic-Hydrogen by Electron-Spin Resonance

    NARCIS (Netherlands)

    van Yperen, G.H.; Silvera, I.F.; Walraven, J.T.M.; Berkhout, J.; Brisson, J.G.

    1983-01-01

    By means of ESR in a high magnetic field the hyperfine states of a gas of spin-polarized atomic hydrogen are directly probed. This allows a direct determination of the spin-state populations and nuclear polarization. The unusual ESR line shape is attributed to field inhomogeneities. The temperature

  11. Resonant three-photon ionization of hydrogenic atoms by a non-monochromatic laser field

    NARCIS (Netherlands)

    Yakhontov, V.; Santra, R.; Jungmann, K.

    1999-01-01

    We present ionization probability and lineshape calculations for the two-step three- photon ionization process, 1S (2(h)over-bar-omega)under-right-arrow, 2S ((h)over-bar-omega)under-right-arrow epsilon P, of the ground state of hydrogenic atoms in a non-monochromatic laser field with a time-dependen

  12. Resonant three-photon ionization of hydrogenic atoms by a non-monochromatic laser field

    NARCIS (Netherlands)

    Yakhontov, V.; Santra, R.; Jungmann, K.

    1999-01-01

    We present ionization probability and lineshape calculations for a specifed two-step three-photon ionization process of the ground state of hydrogenic atoms in a non-monochromatic laser field with a time-dependent amplitude. Within the framework of a three-level model, the AC Stark shifts and non-ze

  13. Effects of Low Energy and High Flux Helium/Hydrogen Plasma Irradiation on Tungsten as Plasma Facing Material

    Institute of Scientific and Technical Information of China (English)

    Ye Minyou

    2005-01-01

    The High-Z material tungsten (W) has been considered as a plasma facing material in the divertor region of ITER (International Thermonuclear Experimental Reactor). In ITER, the divertor is expected to operate under high particle fluxes (> 1023 m-2s-1) from the plasma as well as from intrinsic impurities with a very low energy (< 200 eV). During the past dacade, the effects of plasma irradiation on tungsten have been studied extensively as functions of the ion energy,fluence and surface temperature in the burning plasma conditions. In this paper, recent results concerning blister and bubble formations on the tungsten surface under low energy (< 100 eV) and high flux (> 1021 m-2s-1) He/H plasma irradiation are reviewed to gain a better understanding of the performance of tungsten as a plasma facing material under the burning plasma conditions.

  14. Hydrogen production from banyan leaves using an atmospheric-pressure microwave plasma reactor.

    Science.gov (United States)

    Lin, Yuan-Chung; Wu, Tzi-Yi; Jhang, Syu-Ruei; Yang, Po-Ming; Hsiao, Yi-Hsing

    2014-06-01

    Growth of the hydrogen market has motivated increased study of hydrogen production. Understanding how biomass is converted to hydrogen gas can help in evaluating opportunities for reducing the environmental impact of petroleum-based fuels. The microwave power used in the reaction is found to be proportional to the rate of production of hydrogen gas, mass of hydrogen gas produced per gram of banyan leaves consumed, and amount of hydrogen gas formed with respect to the H-atom content of banyan leaves decomposed. Increase the microwave power levels results in an increase of H2 and decrease of CO2 concentrations in the gaseous products. This finding may possibly be ascribed to the water-gas shift reaction. These results will help to expand our knowledge concerning banyan leaves and hydrogen yield on the basis of microwave-assisted pyrolysis, which will improve the design of hydrogen production technologies.

  15. Ion beam driven resonant ion-cyclotron instability in a magnetized dusty plasma

    Energy Technology Data Exchange (ETDEWEB)

    Prakash, Ved; Vijayshri [School of Sciences, Indira Gandhi National Open University, Maidan Garhi, New Delhi 110 068 (India); Sharma, Suresh C. [Department of Applied Physics, Delhi Technological University, Shahbad Daulatpur, Bawana Road, Delhi 110 042 (India); Gupta, Ruby [Department of Physics, Swami Shraddhanand College, University of Delhi, Alipur, Delhi 110 036 (India)

    2014-03-15

    Electrostatic ion cyclotron waves are excited by axial ion beam in a dusty plasma via Cerenkov and slow cyclotron interaction. The dispersion relation of the instability is derived in the presence of positively/negatively charged dust grains. The minimum beam velocity needed for the excitation is estimated for different values of relative density of negatively charged dust grains. It is shown that the minimum beam velocity needed for excitation increases as the charge density carried by dust increases. Temperature of electrons and ions, charge and mass of dust grains, external static magnetic field and finite boundary of dusty plasma significantly modify the dispersion properties of these waves and play a crucial role in the growth of resonant ion cyclotron instability. The ion cyclotron modes with phase velocity comparable to the beam velocity possess a large growth rate. The maximum value of growth rate increases with the beam density and scales as the one-third power of the beam density in Cerenkov interaction and is proportional to the square root of beam density in slow cyclotron interaction.

  16. The creation of strongly coupled plasmas using an intense heavy ion beam: low-entropy compression of hydrogen and the problem of hydrogen metallization

    Energy Technology Data Exchange (ETDEWEB)

    Tahir, N A [Institut fuer Theoretische Physik, Universitaet Frankfurt, Postfach 11 19 32, 60054 Frankfurt (Germany); Piriz, A R [ETSI Industriales, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain); Shutov, A [Institute for Problems in Chemical Physics Research, Chernogolovka, Russia (Russian Federation); Varentsov, D [Institut fuer Kernphysik, Technische Universitaet Darmstadt, Schlossgarten Str. 9, 64289 Darmstadt (Germany); Udrea, S [Institut fuer Kernphysik, Technische Universitaet Darmstadt, Schlossgarten Str. 9, 64289 Darmstadt (Germany); Hoffmann, D H H [Institut fuer Kernphysik, Technische Universitaet Darmstadt, Schlossgarten Str. 9, 64289 Darmstadt (Germany); Juranek, H [Fachbereich Physik, Universitaet Rostock, 18051 Rostock (Germany); Redmer, R [Fachbereich Physik, Universitaet Rostock, 18051 Rostock (Germany); Portugues, R F [ETSI Industriales, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain); Lomonosov, I [Institute for Problems in Chemical Physics Research, Chernogolovka, Russia (Russian Federation); Fortov, V E [Institute for Problems in Chemical Physics Research, Chernogolovka, Russia (Russian Federation)

    2003-06-06

    Intense heavy ion beams deposit energy very efficiently over extended volumes of solid density targets, thereby creating large samples of strongly coupled plasmas. Intense beams of energetic heavy ions are therefore an ideal tool to research this interesting field. It is also possible to design experiments using special beam-target geometries to achieve low-entropy compression of samples of matter. This type of experiments is of particular interest for studying the problem of hydrogen metallization. In this paper we present a design study of such a proposed experiment that will be carried out at the future heavy ion synchrotron facility SIS100, at the Gesellschaft fuer Schwerionenforschung, Darmstadt. This study has been done using a two-dimensional hydrodynamic computer code. The target consists of a solid hydrogen cylinder that is enclosed in a thick shell of lead whose one face is irradiated with an ion beam which has an annular (ring shaped) focal spot. The beam intensity and other parameters are considered to be the same as expected at the future SIS100 facility. The simulations show that due to multiple shock reflection between the cylinder axis and the lead-hydrogen boundary, one can achieve up to 20 times solid density in hydrogen while keeping the temperature as low as a few thousand K. The corresponding pressure is of the order of 10 Mbar. These values of the physical parameters lie within the range of theoretically predicted values for hydrogen metallization. We have also carried out a parameter study of this problem by varying the target and beam parameters over a wide range. It has been found that the results are very insensitive to such changes in the input parameters.

  17. Hydrogen-1 nuclear magnetic resonance of the nitrogenase iron protein (Cp2) from Clostridium pasteurianum.

    Science.gov (United States)

    Meyer, J; Gaillard, J; Moulis, J M

    1988-08-09

    Proton NMR spectra (250 MHz) of the nitrogenase iron protein from Clostridium pasteurianum (Cp2) were found to display 9 or 10 paramagnetically shifted resonances in the 15-50 ppm range. The most shifted resonances belonged to two approximately equal subsets having temperature dependences of opposite sign. The latter occurrence is consistent with the interaction of the corresponding protons with an antiferromagnetically coupled metal center. The number of proton resonances of Cp2, their positions, and their temperature dependences were similar to those observed in spectra of (4Fe-4S)+ ferredoxins, particularly those of the latter that contain a single tetranuclear cluster, such as the ferredoxin from Bacillus stearothermophilus. The effects of several adenine nucleotides on the paramagnetically shifted proton resonances of Cp2 have been investigated. Whereas MgAMP had no effect at all, MgADP and MgATP were found to induce different modifications, which in both cases involved approximately half only of the shifted proton resonances. These data suggest that nucleotide binding affects mainly one part of the iron-sulfur cluster. A remarkable feature of the spectra of Cp2 in the presence of MgATP is the grouping of the shifted proton resonances in sets of two or four having identical chemical shifts and temperature dependences. A nearly perfect 2-fold symmetry is thus suggested for the arrangement of the cysteine protons around the active site. These observations lend support to the proposal that the (4Fe-4S) cluster is held symmetrically between the two identical subunits and are consistent with the existence of two MgATP binding sites on nitrogenase iron proteins.(ABSTRACT TRUNCATED AT 250 WORDS)

  18. Outer magnetospheric resonances and transport: discrete and turbulent cascades in the dynamic pressure and plasma flux

    Science.gov (United States)

    Savin, Sergey; Büchner, Jörg; Zelenyi, Lev; Kronberg, Elena; Kozak, Lyudmila; Blecki, Jan; Lezhen, Liudmila; Nemecek, Zdenek; Safrankova, Jana; Skalsky, Alexander; Budaev, Vyacheslav; Amata, Ermanno

    We explore interactions of Supersonic Plasma Streams (SPS) with the Earth magnetosphere in the context of the planetary and astrophysical magnetospheres and of that of laboratory plasmas. The interactions can be inherently non-local and non-equilibrium, and even explosive due to both solar wind (SW) induced and self-generated coherent structures in the multiscale system with the scales ranging from the micro to global scales. We concentrate on the main fundamental processes arising from the SPS cascading and interactions with surface and cavity resonances in the Earth’s magnetosphere, using multi-spacecraft data (SPECTR-R, DOUBLE STAR, CLUSTER, GEOTAIL, ACE, WIND etc.). We will address the following key problems to advance our understanding of anomalous transport and boundary dynamics: - generalizations of the SPS generation mechanisms, e.g., by bow shock (BS) surface or magnetosheath (MSH) cavity resonances, triggering by interplanetary shocks, solar wind (SW) dynamic pressure jumps, foreshock nonlinear structures, etc. - the clarification of BS rippling mechanisms requires base on the relevant databases from the CLUSTER/ DOUBLE STAR/ GEOTAIL/SPECTR-R/ ACE/ WIND spacecraft, which will be used for a statistical analysis targeting the SPS statistical features as extreme events. - substantial part of the SW kinetic energy can be pumped into the BS membrane and MSH cavity modes and initiate further cascades towards higher frequencies. Accordingly we present the multipoint studies of the SPS and of related nonlinear discrete cascades (carried generally by the SPS), along with the transformation of discrete cascades of the dynamic pressure into turbulent cascades. - investigation of spectral and bi-spectral cross-correlations in SW, foreshock, MSH and in vicinity of BS and magnetopause (MP) would demonstrate that both inflow and outflow into/ from magnetosphere can be modulated by the SPS and by the related outer magnetospheric resonances as well. We demonstrate in

  19. Resonant magnetic perturbations of edge-plasmas in toroidal confinement devices

    Science.gov (United States)

    Evans, T. E.

    2015-12-01

    Controlling the boundary layer in fusion-grade, high-performance, plasma discharges is essential for the successful development of toroidal magnetic confinement power generating systems. A promising approach for controlling the boundary plasma is based on the use of small, externally applied, edge resonant magnetic perturbation (RMP) fields (δ b\\bot\\text{ext}≈ {{10}-4}\\to {{10}-3}~\\text{T} ). A long-term focus area in tokamak fusion research has been to find methods, involving the use of non-axisymmetric magnetic perturbations to reduce the intense particle and heat fluxes to the wall. Experimental RMP research has progressed from the early pioneering work on tokamaks with material limiters in the 1970s, to present day research in separatrix-limited tokamaks operated in high-confinement mode, which is primarily aimed at the mitigation of the intermittent fluxes due edge localized modes (ELMs). At the same time, theoretical research has evolved from analytical models to numerical simulations, including the full 3D complexities of the problem. Following the first demonstration of ELM suppression in the DIII-D tokamak during 2003, there has been a rapid worldwide growth in theoretical, numerical and experimental edge RMP research resulting in the addition of ELM control coils to the ITER baseline design (Loarte et al 2014 Nucl. Fusion 54 033007). This review provides an overview of edge RMP research including a summary of the early theoretical and numerical background along with recent experimental results on improved particle and energy confinement in tokamaks triggered by edge RMP fields. The topics covered make up the basic elements needed for developing a better understanding of 3D magnetic perturbation physics, which is required in order to utilize the full potential of edge RMP fields in fusion relevant high performance, H-mode, plasmas.

  20. Effect of Hydrogen Dilution on Growth of Silicon Nanocrystals Embedded in Silicon Nitride Thin Film bv Plasma-Enhanced CVD

    Institute of Scientific and Technical Information of China (English)

    DING Wenge; ZHEN Lanfang; ZHANG Jiangyong; LI Yachao; YU Wei; FU Guangsheng

    2007-01-01

    An investigation was conducted into the effect of hydrogen dilution on the mi-crostructure and optical properties of silicon nanograins embedded in silicon nitride (Si/SiNx) thin film deposited by the helicon wave plasma-enhanced chemical vapour deposition technique. With Ar-diluted SiH4 and N2 as the reactant gas sources in the fabrication of thin film, the film was formed at a high deposition rate. There was a high density of defect at the amorphous silicon (a-Si)/SiNx interface and a relative low optical gap in the film. An addition of hydrogen into the reactant gas reduced the film deposition rate sharply. The silicon nanograins in the SiNx matrix were in a crystalline state, and the density of defects at the silicon nanocrystals (nc-Si)/SiNx interface decreased significantly and the optical gap of the films widened. These results suggested that hydrogen activated by the plasma could not only eliminate in the defects between the interface of silicon nanograins and SiNx matrix, but also helped the nanograins transform from the amorphous into crystalline state. By changing the hydrogen dilution ratio in the reactant gas sources, a tunable band gap from 1.87 eV to 3.32 eV was obtained in the Si/SiNx film.

  1. Activating basal-plane catalytic activity of two-dimensional MoS2 monolayer with remote hydrogen plasma

    KAUST Repository

    Cheng, Chia-Chin

    2016-09-10

    Two-dimensional layered transition metal dichalcogenide (TMD) materials such as Molybdenum disufide (MoS2) have been recognized as one of the low-cost and efficient electrocatalysts for hydrogen evolution reaction (HER). The crystal edges that account for a small percentage of the surface area, rather than the basal planes, of MoS2 monolayer have been confirmed as their active catalytic sites. As a result, extensive efforts have been developing in activating the basal planes of MoS2 for enhancing their HER activity. Here, we report a simple and efficient approach-using a remote hydrogen-plasma process-to creating S-vacancies on the basal plane of monolayer crystalline MoS2; this process can generate high density of S-vacancies while mainly maintaining the morphology and structure of MoS2 monolayer. The density of S-vacancies (defects) on MoS2 monolayers resulted from the remote hydrogen-plasma process can be tuned and play a critical role in HER, as evidenced in the results of our spectroscopic and electrical measurements. The H2-plasma treated MoS2 also provides an excellent platform for systematic and fundamental study of defect-property relationships in TMDs, which provides insights for future applications including electrical, optical and magnetic devices. © 2016 Elsevier Ltd.

  2. Normally-off p-GaN/AlGaN/GaN high electron mobility transistors using hydrogen plasma treatment

    Science.gov (United States)

    Hao, Ronghui; Fu, Kai; Yu, Guohao; Li, Weiyi; Yuan, Jie; Song, Liang; Zhang, Zhili; Sun, Shichuang; Li, Xiajun; Cai, Yong; Zhang, Xinping; Zhang, Baoshun

    2016-10-01

    In this letter, we report a method by introducing hydrogen plasma treatment to realize normally-off p-GaN/AlGaN/GaN HEMT devices. Instead of using etching technology, hydrogen plasma was adopted to compensate holes in the p-GaN above the two dimensional electron gas (2DEG) channel to release electrons in the 2DEG channel and form high-resistivity area to reduce leakage current and increase gate control capability. The fabricated p-GaN/AlGaN/GaN HEMT exhibits normally-off operation with a threshold voltage of 1.75 V, a subthreshold swing of 90 mV/dec, a maximum transconductance of 73.1 mS/mm, an ON/OFF ratio of 1 × 107, a breakdown voltage of 393 V, and a maximum drain current density of 188 mA/mm at a gate bias of 6 V. The comparison of the two processes of hydrogen plasma treatment and p-GaN etching has also been made in this work.

  3. Magnetic resonance studies of atomic hydrogen at zero field and low temperature. Recombination and binding on liquid helium

    Energy Technology Data Exchange (ETDEWEB)

    Jochemsen, R.; Morrow, M.; Berlinsky, A.J.; Hardy, W.N. (British Columbia Univ., Vancouver (Canada). Dept. of Physics)

    1982-07-01

    Magnetic resonance studies at zero field are reported for atomic hydrogen gas confined in a closed glass bulb with helium-coated walls for T<1 K in a dilution refrigerator. Low-energy r.f. discharge pulses have been used to produce H atoms at temperatures as low as T=0.06 K. The atom density nsub(H) (10/sup 9/..H/sub 2/+wall. From the temperature dependence of the rate constant K we have determined the binding energy of H on liquid /sup 4/He and /sup 3/He, and also the cross section for recombination on the surface.

  4. Functionalization of Hydrogen-free Diamond-like Carbon Films using Open-air Dielectric Barrier Discharge Atmospheric Plasma Treatments

    Energy Technology Data Exchange (ETDEWEB)

    Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA; Instituto de Materiales de Madrid, C.S.I.C., Cantoblanco, 28049 Madrid, Spain; Instituto de Quimica-Fisica" Rocasolano" C.S.I.C., 28006 Madrid, Spain; Mahasarakham University, Mahasarakham 44150, Thailand; CASTI, CNR-INFM Regional Laboratory, L' Aquila 67100, Italy; SUNY Upstate Medical University, Syracuse, NY 13210, USA; Endrino, Jose; Endrino, J. L.; Marco, J. F.; Poolcharuansin, P.; Phani, A.R.; Allen, M.; Albella, J. M.; Anders, A.

    2007-12-28

    A dielectric barrier discharge (DBD) technique has been employed to produce uniform atmospheric plasmas of He and N2 gas mixtures in open air in order to functionalize the surface of filtered-arc deposited hydrogen-free diamond-like carbon (DLC) films. XPS measurements were carried out on both untreated and He/N2 DBD plasma treated DLC surfaces. Chemical states of the C 1s and N 1s peaks were collected and used to characterize the surface bonds. Contact angle measurements were also used to record the short- and long-term variations in wettability of treated and untreated DLC. In addition, cell viability tests were performed to determine the influence of various He/N2 atmospheric plasma treatments on the attachment of osteoblast MC3T3 cells. Current evidence shows the feasibility of atmospheric plasmas in producing long-lasting variations in the surface bonding and surface energy of hydrogen-free DLC and consequently the potential for this technique in the functionalization of DLC coated devices.

  5. Removal of carbon deposited film and hydrogen retention control by low temperature H–C–N reactive plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, A., E-mail: me121030@ec.t.kanazawa-u.ac.jp [Kanazawa University, Kanazawa, Ishikawa (Japan); Takai, Y.; Uesugi, Y.; Tanaka, Y.; Ishijima, T. [Kanazawa University, Kanazawa, Ishikawa (Japan); Masuzaki, S. [NIFS, Toki, Gifu (Japan)

    2013-07-15

    Control of tritium retention and its removal from the first wall of future fusion devices are the most crucial issues for safety and effective use of the fuel. Nitrogen injection into edge plasmas has been considered and tested as an effective method for suppression of carbon dust growth and reduction of hydrogen isotope inventory. In this paper we have investigated scavenger effects of nitrogen injected into H{sub 2}/CH{sub 4} plasmas using a small helical device where low density (n{sub e} ∼ 10{sup 16} m{sup −3}) and low temperature (T{sub e} = 5–10 eV) hydrogen plasmas are generated in steady state condition like remote plasmas in fusion devices. It is shown from the comparison of the carbon film deposition and particle growth between those with and without N{sub 2} injection that the chemical erosion effects of nitrogen gas on the carbon film and particle growth strongly depends on the surface temperature. With increasing the surface temperature higher than ∼400 K, the nitrogen chemical erosion significantly works to reduce the hydrocarbon deposition.

  6. Enhancement of hydrogen isotope retention capacity for the impurity deposited tungsten by long-term plasma exposure in LHD

    Energy Technology Data Exchange (ETDEWEB)

    Oya, Yasuhisa, E-mail: syoya@ipc.shizuoka.ac.jp [Radioscience Research Laboratory, Faculty of Science, Shizuoka University, Shizuoka 422-8529 (Japan); Masuzaki, Suguru; Tokitani, Masayuki [National Institute for Fusion Science, Gifu 509-5292 (Japan); Yoshida, Naoaki; Watanabe, Hideo [Kyushu University, Fukuoka 816-8580 (Japan); Yamauchi, Yuji; Hino, Tomoaki [Hokkaido University, Sapporo 060-8628 (Japan); Miyamoto, Mitsutaka [Shimane University, Shimane 690-8504 (Japan); Hatano, Yuji [University of Toyama, Toyama 930-8555 (Japan); Okuno, Kenji [Radioscience Research Laboratory, Faculty of Science, Shizuoka University, Shizuoka 422-8529 (Japan)

    2013-10-15

    Highlights: • The carbon-dominant mixed-material layer was formed on the tungsten surface after 15{sup th} plasma exposure in LHD. • The largest enhancement of deuterium retention was found to be about 21. • The major deuterium desorption temperature was shifted toward higher temperature side. -- Abstract: The stress relieved tungsten samples were placed at three positions, PI (sputtering erosion dominated area), DP (deposition dominated area) and HL (Higher heat load area) during 15th plasma experiment campaign in Large Helical Device (LHD) at National Institute for Fusion Science (NIFS), Japan and were exposed to ∼ 6700 shots of hydrogen plasma in a 15th long-term experiment campaign in LHD. Thereafter, the additional deuterium ion implantation to these tungsten samples was performed to evaluate the change of hydrogen isotope retention capacity in the samples by long-term plasma exposure. It was found that the carbon-dominant mixed-material layer with more than 100 nm thickness was formed on a wide area of the tungsten surface. The thicker mixed-material layer was formed on the DP sample, where the deuterium retention was about 21 times as high as that for pure W. The major desorption temperature of deuterium was shifted toward higher temperature side, which was comparable to the trapping characteristic of carbon or irradiation damages.

  7. Resonances

    DEFF Research Database (Denmark)

    an impetus or drive to that account: change, innovation, rupture, or discontinuity. Resonances: Historical Essays on Continuity and Change explores the historiographical question of the modes of interrelation between these motifs in historical narratives. The essays in the collection attempt to realize...... theoretical consciousness through historical narrative ‘in practice’, by discussing selected historical topics from Western cultural history, within the disciplines of history, literature, visual arts, musicology, archaeology, philosophy, and theology. The title Resonances indicates the overall perspective...

  8. On the role of atomic metastability in the production of Balmer line radiation from ‘cold’ atomic hydrogen, deuterium and hydrogenic ion impurities in fusion edge plasmas

    Science.gov (United States)

    Hey, J. D.

    2012-03-01

    Published arguments, which assign an important role to atomic metastability in the production of ‘narrow’ Zeeman component radiation from the boundary region of fusion plasmas, are examined critically in relation to l-redistribution by proton and electron collisions, and mixing of unperturbed atomic states by the ion microfield and microfield gradient. It is concluded that these important processes indeed severely constrain the contribution from ‘metastable’ states to the generation of the hydrogen Balmer spectra, for electron concentrations above 1012 cm-3, as pointed out before by the present author (Hey et al 1999 J. Phys. B: At. Mol. Opt. Phys. 32 3555). The analysis of collision-induced l-redistribution represents an extension of that used previously (Hey et al 1996 Contrib. Plasma Phys. 36 583), applicable up to higher electron densities. For comparison purposes, we also consider the question of metastability of ionized helium in a low-temperature plasma, and that of some common hydrogenic impurities (C5+ and Ne9+) in a hydrogen (deuterium) fusion plasma. While for low nuclear charge Z the metastability of 2s1/2 levels is quenched by the plasma environment, it is much reduced in high-Z ions owing to the rapid increase with Z of the two-photon electric dipole (2E1) and magnetic dipole (M1) spontaneous transition rates to the ground state, whereas the role of the plasma in these cases is less important. The main new principle elaborated in this work is the sensitivity of atomic line strengths, and hence collision strengths, to perturbation by the plasma environment for transitions between fine-structure sublevels of the same principal quantum number. As the plasma microfield strength grows, ‘allowed’ transitions diminish in strength, while ‘forbidden’ transitions grow. However, owing to violation of the parity selection rule, there is an overall loss of collision strength available to transitions, resulting from the appearance of significant

  9. A study on vacuum aspects of electron cyclotron resonance ion source plasma

    Science.gov (United States)

    Ghosh, S.; Taki, G. S.; Mallick, C.; Bhandari, R. K.

    2008-05-01

    The electron cyclotron resonance (ECR) ion source is special type hot plasma machine where the high temperature electrons co-exist with multiply charge state ions and neutrals. A few years ago 6.4 GHz. ECR ion source (VEC-ECR) was developed indigenously at VECC. This multiply charged ion source is being used continuously to inject heavy ion beams into the cyclotron. Vacuum plays the major role in ECR ion source. The water cooled plasma chamber is made from an oxygen free high conductivity copper billet to meet the suitable surface condition for vacuum purpose. The entire volume of the ion source is pumped by two 900 1/s special type oil diffusion pumps to achieve 5×10-8 Torr. Usually main plasma chamber is pumped by the plasma itself. Moreover a few 1/s additional pumping speed is provided through extraction hole and pumping slot on the extraction electrode. A study has been carried out to understand the role of vacuum on the multiply charged heavy ion production process. Considering the ion production and loss criteria, it is seen that for getting Ar18+ better vacuum is essential for lower frequency operation. So, an ECR ion source can give better charge state current output operating at higher frequency and stronger confining magnetic field under a specific vacuum condition. The low pressure condition is essential to minimize charge exchange loss due to recombination of multiply charged ions with the neutral atoms. A fixed ratio of neutral to electron density must be maintained for optimizing a particular charge state in the steady state condition. As the electron density is proportional to square of the injected microwave frequency (nevpropf2) a particular operating pressure is essential for a specific charge state. From the study, it has been obtained that the production of Ar18+ ions needs a pressure ~ 9.6×10-8 Torr for 6.4 GHz. ECR ion source. It is also obtained that an ECR ion source, works at a particular vacuum level, can give better charge state

  10. Experimental observation of electron bounce resonance through electron energy distribution measurement in a finite size inductively coupled plasma

    Energy Technology Data Exchange (ETDEWEB)

    Gu, Seuli [Department of Nanoscale Semiconductor Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763 (Korea, Republic of); Kang, Hyun-Ju; Kim, Yu-Sin; Chang, Yoon-Min; Chung, Chin-Wook, E-mail: joykang@hanyang.ac.kr [Department of Electrical Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763 (Korea, Republic of); Kwon, Deuk-Chul [Plasma Technology Research Center, National Fusion Research Institute, 169-148 Gwahak-ro, Yuseong-gu, Daejeon 34133 (Korea, Republic of)

    2016-06-15

    The electron bounce resonance was experimentally investigated in a low pressure planar inductively coupled plasma. The electron energy probability functions (EEPFs) were measured at different chamber heights and the energy diffusion coefficients were calculated by the kinetic model. It is found that the EEPFs begin to flatten at the first electron bounce resonance condition, and the plateau shifts to a higher electron energy as the chamber height increases. The plateau which indicates strong electron heating corresponds not only to the electron bounce resonance condition but also to the peaks of the first component of the energy diffusion coefficients. As a result, the plateau formation in the EEPFs is mainly due to the electron bounce resonance in a finite inductive discharge.

  11. Electron cyclotron resonance ion source plasma characterization by X-ray spectroscopy and X-ray imaging

    Energy Technology Data Exchange (ETDEWEB)

    Mascali, David, E-mail: davidmascali@lns.infn.it; Castro, Giuseppe; Celona, Luigi; Neri, Lorenzo; Gammino, Santo [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Biri, Sándor; Rácz, Richárd; Pálinkás, József [Institute for Nuclear Research (Atomki), Hungarian Academy of Sciences, Bem tér 18/c, H-4026 Debrecen (Hungary); Caliri, Claudia [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Università degli Studi di Catania, Dip.to di Fisica e Astronomia, via Santa Sofia 64, 95123 Catania (Italy); Romano, Francesco Paolo [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); CNR, Istituto per i Beni Archeologici e Monumentali, Via Biblioteca 4, 95124 Catania (Italy); Torrisi, Giuseppe [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Università Mediterranea di Reggio Calabria, DIIES, Via Graziella, I-89100 Reggio Calabria (Italy)

    2016-02-15

    An experimental campaign aiming to investigate electron cyclotron resonance (ECR) plasma X-ray emission has been recently carried out at the ECRISs—Electron Cyclotron Resonance Ion Sources laboratory of Atomki based on a collaboration between the Debrecen and Catania ECR teams. In a first series, the X-ray spectroscopy was performed through silicon drift detectors and high purity germanium detectors, characterizing the volumetric plasma emission. The on-purpose developed collimation system was suitable for direct plasma density evaluation, performed “on-line” during beam extraction and charge state distribution characterization. A campaign for correlating the plasma density and temperature with the output charge states and the beam intensity for different pumping wave frequencies, different magnetic field profiles, and single-gas/gas-mixing configurations was carried out. The results reveal a surprisingly very good agreement between warm-electron density fluctuations, output beam currents, and the calculated electromagnetic modal density of the plasma chamber. A charge-coupled device camera coupled to a small pin-hole allowing X-ray imaging was installed and numerous X-ray photos were taken in order to study the peculiarities of the ECRIS plasma structure.

  12. Pulsed microwave-driven argon plasma jet with distinctive plume patterns resonantly excited by surface plasmon polaritons

    Science.gov (United States)

    Chen, Zhao-Quan; Yin, Zhi-Xiang; Xia, Guang-Qing; Hong, Ling-Li; Hu, Ye-Lin; Liu, Ming-Hai; Hu, Xi-Wei; A. Kudryavtsev, A.

    2015-02-01

    Atmospheric lower-power pulsed microwave argon cold plasma jets are obtained by using coaxial transmission line resonators in ambient air. The plasma jet plumes are generated at the end of a metal wire placed in the middle of the dielectric tubes. The electromagnetic model analyses and simulation results suggest that the discharges are excited resonantly by the enhanced electric field of surface plasmon polaritons. Moreover, for conquering the defect of atmospheric argon filamentation discharges excited by 2.45-GHz of continued microwave, the distinctive patterns of the plasma jet plumes can be maintained by applying different gas flow rates of argon gas, frequencies of pulsed modulator, duty cycles of pulsed microwave, peak values of input microwave power, and even by using different materials of dielectric tubes. In addition, the emission spectrum, the plume temperature, and other plasma parameters are measured, which shows that the proposed pulsed microwave plasma jets can be adjusted for plasma biomedical applications. Project supported by the National Natural Science Foundation of China (Grant Nos. 11105002 and 61170172), the Natural Science Foundation of Anhui Province, China (Grant Nos. 1408085QA16 and 1408085ME101), the China Postdoctoral Science Foundation (Grant No. 2014M551788), and the Open-end Fund of State Key Laboratory of Advanced Electromagnetic Engineering and Technology (HUST), China (Grant No. GZ1301).

  13. Effect of hydrogen plasma on electroless-plating Ni-B films and its Cu diffusion barrier property.

    Science.gov (United States)

    Choi, Kyeong-Keun; Kee, Jong; Kwon, Da-Jung; Kim, Deok-Kee

    2014-12-01

    Electroless-plating Ni-B films have been evaluated for the application as the diffusion barrier and metal cap for copper integration. The effect of post plasma treatment in a hydrogen environment on the characteristics of Ni-B films such as chemical composition, surface roughness, crystallinity, and resistivity was investigated. By treating electroless-plating Ni-B films with H2 plasma, the resistance and the roughness of the films decreased. The leakage current of Ni-B bottom electrode/30-nm-thick Al2O3/Al top electrode structures improved after the H2 plasma treatment on the Ni-B films. 40 nm-thick electroless-plating Ni-B film was able to block Cu diffusion up to 350 degrees C.

  14. Interaction between a high density-low temperature plasma and a frozen hydrogen pellet in a railgun injector

    Energy Technology Data Exchange (ETDEWEB)

    Grapperhaus, M.J. [Illinois Univ., Urbana, IL (United States)

    1993-10-01

    A model has been developed which describes the ablation process of frozen hydrogen pellets in an electromagnetic railgun. The model incorporates the neutral gas shielding model in which the pellet surface is heated by incident electrons from the plasma arc. The heated surface then ablates, forming a neutral cloud which attenuates the incoming electrons. The energy lost in the cloud by the electrons heats the ablatant material as it flows into the plasma arc. Under steady-state conditions, a scaling law for the ablation rate was derived as a function of plasma-arc temperature and density. In addition, flow conditions and the criteria for the existence of a steady-state solution were formulated and subsequently examined under simplifying assumptions. Comparison with experimentally observed ablation rates shows good qualitative agreement.

  15. Spin transport, magnetoresistance, and electrically detected magnetic resonance in amorphous hydrogenated silicon nitride

    Science.gov (United States)

    Mutch, Michael J.; Lenahan, Patrick M.; King, Sean W.

    2016-08-01

    We report on a study of spin transport via electrically detected magnetic resonance (EDMR) and near-zero field magnetoresistance (MR) in silicon nitride films. Silicon nitrides have long been important materials in solid state electronics. Although electronic transport in these materials is not well understood, electron paramagnetic resonance studies have identified a single dominating paramagnetic defect and have also provided physical and chemical descriptions of the defects, called K centers. Our EDMR and MR measurements clearly link the near-zero field MR response to the K centers and also indicate that K center energy levels are approximately 3.1 eV above the a-SiN:H valence band edge. In addition, our results suggest an approach for the study of defect mediated spin-transport in inorganic amorphous insulators via variable electric field and variable frequency EDMR and MR which may be widely applicable.

  16. Plasmonically Enhanced Photocatalytic Hydrogen Production from Water: The Critical Role of Tunable Surface Plasmon Resonance from Gold-Silver Nanoshells.

    Science.gov (United States)

    Li, Chien-Hung; Li, Min-Chih; Liu, Si-Ping; Jamison, Andrew C; Lee, Dahye; Lee, T Randall; Lee, Tai-Chou

    2016-04-13

    Gold-silver nanoshells (GS-NSs) having a tunable surface plasmon resonance (SPR) were employed to facilitate charge separation of photoexcited carriers in the photocalytic production of hydrogen from water. Zinc indium sulfide (ZnIn2S4; ZIS), a visible-light-active photocatalyst, where the band gap varies with the [Zn]/[In] ratio, was used as a model ZIS system (E(g) = 2.25 eV) to investigate the mechanisms of plasmonic enhancement associated with the nanoshells. Three types of GS-NS cores with intense absorptions centered roughly at 500, 700, and 900 nm were used as seeds for preparing GS-NS@ZIS core-shell structures via a microwave-assisted hydrothermal reaction, yielding core-shell particles with composite diameters of ∼200 nm. Notably, an interlayer of dielectric silica (SiO2) between the GS-NSs and the ZIS photocatalyst provided another parameter to enhance the production of hydrogen and to distinguish the charge-transfer mechanisms. In particular, the direct transfer of hot electrons from the GS-NSs to the ZIS photocatalyst was blocked by this layer. Of the 10 particle samples examined in this study, the greatest hydrogen gas evolution rate was observed for GS-NSs having a SiO2 interlayer thickness of ∼17 nm and an SPR absorption centered at ∼700 nm, yielding a rate 2.6 times higher than that of the ZIS without GS-NSs. The apparent quantum efficiencies for these core-shell particles were recorded and compared to the absorption spectra. Analyses of the charge-transfer mechanisms were evaluated and are discussed based on the experimental findings.

  17. Changes in plasma hydrogen sulfide and nitric oxide levels and their clinical significance in children with Kawasaki disease

    Institute of Scientific and Technical Information of China (English)

    LI Xiao-hui; ZHANG Chao-ying; WU Jian-xin; ZHANG Ting

    2011-01-01

    Background Cardiac involvement is the most common complication of Kawasaki disease (KD); however,the underlying mechanisms are not understood.The present study was designed to investigate changes in plasma hydrogen sulfide (H2S) and nitric oxide (NO) levels in the acute and recovery stages of KD children and to examine their clinical significance.Methods Thirty-five KD patients and 32 healthy children were enrolled in the study.KD patients were divided into two subgroups:a non-cardiac involvement group and a cardiac involvement group.Plasma H2S levels were measured using the sulfur-sensitive electrode method and plasma NO levels and NO synthase activity were determined using the nitrate reductase method both before and after intravenous immune globulin (IVIG) therapy.Results Plasma H2S levels significantly decreased in KD patients during the acute phase of the disease and NO levels were significantly increased,compared with the control group (P <0.01).After treatment with IVIG,both plasma H2S and NO levels significantly increased (P <0.01).The plasma levels of H2S were significantly lower in the cardiac involvement group compared with the non-cardiac involvement group (P<0.05).Conclusion H2S and NO may play a role in the pathophysiological process of inflammation during the acute phase of KD.Endogenous H2S may exert protective effects with respect to cardiac complications in KD.

  18. The study of hydrogen proton magnetic resonance spectroscopy of the hippocampus of patients with dementia with Lewy bodies and Alzheimer’s disease

    Institute of Scientific and Technical Information of China (English)

    钟笑梅

    2013-01-01

    Objective To investigate the characteristics of hydrogen proton magnetic resonance spectroscopy(1H-MRS) in the bilateral hippocampus in patients with dementia with Lewy bodies(DLB) and Alzheimer’s disease(AD) and their value in differentiating DLB from AD.

  19. A solid-state nuclear magnetic resonance study of post-plasma reactions in organosilicone microwave plasma-enhanced chemical vapor deposition (PECVD) coatings.

    Science.gov (United States)

    Hall, Colin J; Ponnusamy, Thirunavukkarasu; Murphy, Peter J; Lindberg, Mats; Antzutkin, Oleg N; Griesser, Hans J

    2014-06-11

    Plasma-polymerized organosilicone coatings can be used to impart abrasion resistance and barrier properties to plastic substrates such as polycarbonate. Coating rates suitable for industrial-scale deposition, up to 100 nm/s, can be achieved through the use of microwave plasma-enhanced chemical vapor deposition (PECVD), with optimal process vapors such as tetramethyldisiloxane (TMDSO) and oxygen. However, it has been found that under certain deposition conditions, such coatings are subject to post-plasma changes; crazing or cracking can occur anytime from days to months after deposition. To understand the cause of the crazing and its dependence on processing plasma parameters, the effects of post-plasma reactions on the chemical bonding structure of coatings deposited with varying TMDSO-to-O2 ratios was studied with (29)Si and (13)C solid-state magic angle spinning nuclear magnetic resonance (MAS NMR) using both single-pulse and cross-polarization techniques. The coatings showed complex chemical compositions significantly altered from the parent monomer. (29)Si MAS NMR spectra revealed four main groups of resonance lines, which correspond to four siloxane moieties (i.e., mono (M), di (D), tri (T), and quaternary (Q)) and how they are bound to oxygen. Quantitative measurements showed that the ratio of TMDSO to oxygen could shift the chemical structure of the coating from 39% to 55% in Q-type bonds and from 28% to 16% for D-type bonds. Post-plasma reactions were found to produce changes in relative intensities of (29)Si resonance lines. The NMR data were complemented by Fourier transform infrared (FTIR) spectroscopy. Together, these techniques have shown that the bonding environment of Si is drastically altered by varying the TMDSO-to-O2 ratio during PECVD, and that post-plasma reactions increase the cross-link density of the silicon-oxygen network. It appears that Si-H and Si-OH chemical groups are the most susceptible to post-plasma reactions. Coatings produced at a

  20. Nanoscale femtosecond imaging of transient hot solid density plasmas with elemental and charge state sensitivity using resonant coherent diffraction

    Science.gov (United States)

    Kluge, T.; Bussmann, M.; Chung, H.-K.; Gutt, C.; Huang, L. G.; Zacharias, M.; Schramm, U.; Cowan, T. E.

    2016-03-01

    Here, we propose to exploit the low energy bandwidth, small wavelength, and penetration power of ultrashort pulses from XFELs for resonant Small Angle Scattering (SAXS) on plasma structures in laser excited plasmas. Small angle scattering allows to detect nanoscale density fluctuations in forward scattering direction. Typically, the SAXS signal from laser excited plasmas is expected to be dominated by the free electron distribution. We propose that the ionic scattering signal becomes visible when the X-ray energy is in resonance with an electron transition between two bound states (resonant coherent X-ray diffraction). In this case, the scattering cross-section dramatically increases so that the signal of X-ray scattering from ions silhouettes against the free electron scattering background which allows to measure the opacity and derived quantities with high spatial and temporal resolution, being fundamentally limited only by the X-ray wavelength and timing. Deriving quantities such as ion spatial distribution, charge state distribution, and plasma temperature with such high spatial and temporal resolution will make a vast number of processes in shortpulse laser-solid interaction accessible for direct experimental observation, e.g., hole-boring and shock propagation, filamentation and instability dynamics, electron transport, heating, and ultrafast ionization dynamics.

  1. On the determination of plasma electron number density from Stark broadened hydrogen Balmer series lines in Laser-Induced Breakdown Spectroscopy experiments

    Energy Technology Data Exchange (ETDEWEB)

    Pardini, L., E-mail: loren.pard@gmail.com [Istituto di Chimica dei Composti Organometallici del CNR, Area della Ricerca del CNR di Pisa, Via G. Moruzzi 1, 56124 Pisa (Italy); Legnaioli, S.; Lorenzetti, G.; Palleschi, V. [Istituto di Chimica dei Composti Organometallici del CNR, Area della Ricerca del CNR di Pisa, Via G. Moruzzi 1, 56124 Pisa (Italy); Gaudiuso, R.; De Giacomo, A. [Dipartimento di Chimica, Università di Bari, Via Orabona 4, 70126 Bari (Italy); Diaz Pace, D.M. [Instituto de Física ‘Arroyo Seco’, Facultad de Ciencias Exactas, Paraje Arroyo Seco, B7000GHG Tandil (Argentina); Anabitarte Garcia, F. [Photonic Engineering Group, Universidad de Cantabria, Edificio I+D+iTelecomunicación, Dpto. TEISA, 39005 Santander (Spain); Holanda Cavalcanti, G. de [Institute of Physics, Universidade Federal Fluminense, UFF, Campus da Praia Vermelha, Av. Gal Milton Tavares de Souza, Gragoatá, 24310 240 Niterói, RJ (Brazil); Parigger, C. [University of Tennessee Space Institute, 411 B. H. Goethert Parkway, Tullahoma, TN 37388-9700 (United States)

    2013-10-01

    In this work, different theories for the determination of the electron density in Laser-Induced Breakdown Spectroscopy (LIBS) utilizing the emission lines belonging to the hydrogen Balmer series have been investigated. The plasmas were generated by a Nd:Yag laser (1064 nm) pulsed irradiation of pure hydrogen gas at a pressure of 2 · 10{sup 4} Pa. H{sub α}, Η{sub β}, Η{sub γ}, Η{sub δ}, and H{sub ε} Balmer lines were recorded at different delay times after the laser pulse. The plasma electron density was evaluated through the measurement of the Stark broadenings and the experimental results were compared with the predictions of three theories (the Standard Theory as developed by Kepple and Griem, the Advanced Generalized Theory by Oks et al., and the method discussed by Gigosos et al.) that are commonly employed for plasma diagnostics and that describe LIBS plasmas at different levels of approximations. A simple formula for pure hydrogen plasma in thermal equilibrium was also proposed to infer plasma electron density using the H{sub α} line. The results obtained showed that at high hydrogen concentration, the H{sub α} line is affected by considerable self-absorption. In this case, it is preferable to use the H{sub β} line for a reliable calculation of the electron density. - Highlights: • We evaluated the electron density in LIPs utilizing the hydrogen Balmer series. • Plasmas were generated by a Nd:Yag laser (1064 nm) on pure hydrogen gas. • We show that at high hydrogen concentration, H{sub b}eta line is preferable than H{sub a}lpha. • We propose a formula to derive the plasma electron density using the H{sub a}lpha line.

  2. Moderate plasma treatment enhances the quality of optically detected magnetic resonance signals of nitrogen-vacancy centres in nanodiamonds

    Science.gov (United States)

    Sotoma, Shingo; Igarashi, Ryuji; Shirakawa, Masahiro

    2016-05-01

    We demonstrate that a moderate plasma treatment increases the quality of optically detected magnetic resonance (ODMR) signals from negatively charged nitrogen-vacancy centres in nanodiamonds (NDs). We measured the statistics of the ODMR spectra of 50-nm-size NDs before and after plasma treatment. We then evaluated each ODMR spectrum in terms of fluorescence and ODMR intensities, line width and signal-to-noise (SN) ratio. Our results showed that plasma treatment for more than 10 min contributes to higher-quality ODMR signals, i.e. signals that are brighter, stronger, sharper and have a higher SN ratio. We showed that such signal improvement is due to alteration of the surface chemical states of the NDs by the plasma treatment. Our study contributes to the advancement of biosensing applications using ODMR of NDs.

  3. Aging of oxygen and hydrogen plasma discharge treated a-C:H and ta-C coatings

    Energy Technology Data Exchange (ETDEWEB)

    Bachmann, Svenja [Physics of Surfaces, Institute of Materials Science, Technische Universität Darmstadt, Alarich-Weiss-Str. 16, 64287 Darmstadt (Germany); BMW Group, Hufelandstraße 4, 80788 Munich (Germany); Schulze, Marcus [Physics of Surfaces, Institute of Materials Science, Technische Universität Darmstadt, Alarich-Weiss-Str. 16, 64287 Darmstadt (Germany); Center of Smart Interfaces, Technische Universität Darmstadt, Alarich-Weiss-Str. 10, 64287 Darmstadt (Germany); Morasch, Jan [Institute of Materials Science, Technische Universität Darmstadt, Surface Science Division, Jovanka-Bonschits-Straße 2, 64287 Darmstadt (Germany); Hesse, Sabine [Physics of Surfaces, Institute of Materials Science, Technische Universität Darmstadt, Alarich-Weiss-Str. 16, 64287 Darmstadt (Germany); Center of Smart Interfaces, Technische Universität Darmstadt, Alarich-Weiss-Str. 10, 64287 Darmstadt (Germany); Hussein, Laith [Eduard-Zintl-Institut, Department of Chemistry, Technische Universität Darmstadt, Alarich-Weiss-Str. 12, 64287, Darmstadt (Germany); Krell, Lisa; Schnagl, Johann [BMW Group, Hufelandstraße 4, 80788 Munich (Germany); Stark, Robert W. [Physics of Surfaces, Institute of Materials Science, Technische Universität Darmstadt, Alarich-Weiss-Str. 16, 64287 Darmstadt (Germany); Center of Smart Interfaces, Technische Universität Darmstadt, Alarich-Weiss-Str. 10, 64287 Darmstadt (Germany); and others

    2016-05-15

    Highlights: • The water CA of O{sub 2} and H{sub 2} plasma treated a-C:H and ta-C changes from hydrophillic to hydrophobic on aging. • XPS study indicates that the decrease in surface energy of plasma treated a-C:H and ta-C could be due to adsorption of organic component from air. • The COFLFM of O{sub 2} and H{sub 2} plasma treated a-C:H and ta-C decreased upon aging. • The COF of glycerol lubricated ta-C showed no sign of change upon aging. - Abstract: Surface modification with gas plasma is an efficient and easy way to improve the surface energy and the tribological behavior of diamond-like carbon (DLC) coatings, e.g., in biomedical implants or as protective coatings. However, the long-term performance of the plasma treated DLC coatings is not fully clear. We thus studied the long-term stability of two kinds of DLC coatings, namely (a) hydrogenated amorphous carbon (a-C:H) and (b) tetrahedral amorphous carbon (ta-C) treated at different radio frequency (RF) power and time of oxygen (O{sub 2}) and hydrogen (H{sub 2}) plasma. Their surface properties, e.g. surface wettability, structure and tribological behavior, were studied at regular intervals for a period of two months using contact angle goniometer, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), lateral force microscopy (LFM) and ball on disc apparatus. The surface energy of both the coatings decreased upon aging. The higher the RF power and time of treatment, the higher was the hydrophobicity upon aging. XPS analysis showed that the increase in hydrophobicity could be due to adsorption of unavoidable volatile organic components in the atmosphere. The H{sub 2} plasma treated ta-C was capable of rearranging its structural bonds upon aging. The nano-friction measurements by LFM showed that the coefficient of friction of plasma treated a-C:H and ta-C decreased upon aging. The results indicate that the surface properties of plasma treated a‐C:H and ta‐C are not stable on long-term and are

  4. Two Contemporary Problems in Magnetized Plasmas: the ion-ion hybrid resonator and MHD stability in a snowflake divertor

    Energy Technology Data Exchange (ETDEWEB)

    Farmer, William Anthony [Univ. of California, Los Angeles, CA (United States)

    2014-01-01

    The rst part of the dissertation investigates the e ects of multiple-ions on the propagation of shear Alfv en waves. It is shown that the presence of a second ion-species allows for the formation of an ion-ion hybrid resonator in the presence of a magnetic well. A fullwave description is shown to explain the measured eigenfrequencies and spatial form of the resonator modes identi ed in experiments in the Large Plasma Device (LAPD) at UCLA. However, it is determined that neither electron collisions or radial convection of the mode due to coupling to either the compressional or ion-Bernstein wave can explain the observed dissipation.

  5. Quasilinear transport due to the magnetic drift resonance with the ion temperature gradient instability in a rotating plasma

    Science.gov (United States)

    Zhang, Debing; Xu, Yingfeng; Wang, Shaojie

    2017-08-01

    The quasilinear transport fluxes due to the ion temperature gradient instability are calculated in a toroidal plasma, in which the magnetic drift resonance is treated rigorously. The effects of the equilibrium parallel flow and flow shear on the radial particle and heat fluxes are studied numerically in detail. In the radial component of parallel viscosity, there exist the pinches driven by the density gradient, the temperature gradient, and the curvature of the background magnetic field. The direction of these pinches is discussed. It is found that each pinch can be inward or outward, which depends crucially on the resonance condition.

  6. Nuclear magnetic resonance-based metabonomics reveals strong sex effect on plasma metabolism in 17-year-old Scandinavians and correlation to retrospective infant plasma parameters.

    Science.gov (United States)

    Bertram, Hanne Christine; Duus, Jens Ø; Petersen, Bent O; Hoppe, Camilla; Larnkjaer, Anni; Schack-Nielsen, Lene; Mølgaard, Christian; Michaelsen, Kim F

    2009-07-01

    Nuclear magnetic resonance (NMR)-based metabonomics was carried out on plasma samples from a total of seventy-five 17-year-old Danes to investigate the impact of key parameters such as sex, height, weight, and body mass index on the plasma metabolite profile in a normal, healthy population. Principal component analysis identified sex to have a large impact on the NMR plasma metabolome, whereas no apparent effects of height, weight, and body mass index were found. Partial least square regression discriminant analysis and quantification of relative metabolite concentrations by integration of NMR signals revealed that the sex effect included differences in plasma lipoproteins (mainly high-density lipoprotein), glucose, choline, and amino acid content. Accordingly, the present study suggests a higher lipid synthesis in young women than young men and a higher protein turnover in young men compared with women. Data on plasma content of triglyceride, lipoprotein fractions, and cholesterol at an age of 9 months were available for selected individuals (n = 40); and partial least square regressions revealed correlations between these infant parameters and the NMR plasma metabolome at an age of 17 years. In conclusion, the present study demonstrates the feasibility of NMR-based metabonomics for obtaining a deeper insight into interindividual differences in metabolism and for exploring relationships between parameters measured early in life and metabolic status at a later stage.

  7. Para-hydrogen raser delivers sub-millihertz resolution in nuclear magnetic resonance

    Science.gov (United States)

    Suefke, Martin; Lehmkuhl, Sören; Liebisch, Alexander; Blümich, Bernhard; Appelt, Stephan

    2017-06-01

    The precision of nuclear magnetic resonance spectroscopy (NMR) is limited by the signal-to-noise ratio, the measurement time Tm and the linewidth Δν = 1/(πT2). Overcoming the T 2 limit is possible if the nuclear spins of a molecule emit continuous radio waves. Lasers and masers are self-organized systems which emit coherent radiation in the optical and micro-wave regime. Both are based on creating a population inversion of specific energy states. Here we show continuous oscillations of proton spins of organic molecules in the radiofrequency regime (raser). We achieve this by coupling a population inversion created through signal amplification by reversible exchange (SABRE) to a high-quality-factor resonator. For the case of 15N labelled molecules, we observe multi-mode raser activity, which reports different spin quantum states. The corresponding 1H-15N J-coupled NMR spectra exhibit unprecedented sub-millihertz resolution and can be explained assuming two-spin ordered quantum states. Our findings demonstrate a substantial improvement in the frequency resolution of NMR.

  8. Collisional broadening of Mg, Sr, Ca and Na resonance lines by atomic hydrogen

    Science.gov (United States)

    Kerkeni, B.; Barklem, P. S.; Spielfiedel, A.; Feautrier, N.

    2004-02-01

    This paper compares different approaches used in the calculation of the broadening of spectral lines by H-atom collisions. Firstly, the validity of the semi-classical approach for the collision versus the quantum one is discussed. It is shown that, at the temperatures typical of stellar atmospheres (from 3000 to 10 000 K), a classical approach (with the advantage of reduced computation times) is sufficient. The dependence of the broadening constants on interatomic potentials is also studied. Two different approaches were used to derive these potentials: in the first approach, the interaction energy is determined by the usual methods of quantum chemistry. The second approach, developed by Anstee, Barklem and O'Mara (ABO potentials), is based on second-order perturbation theory. In the case of Mg H, a hybrid potential obtained from ab initio values for the short distances and from the perturbation method in the asymptotic region was also tested. The results for the Na resonance line show that even significant differences in the potentials lead to relatively small changes in the calculated widths. From the comparison of the results for the Mg, Sr and Ca resonance lines, it appears that ABO potentials give results of the order of 8 20% smaller than results from ab initio and hybrid potentials. This difference is attributed to the presence of an avoided ionic crossing in the upper singlet Sgr states that coincides roughly with the Weisskopf radius.

  9. Electromagnetic wave energy flow control with a tunable and reconfigurable coupled plasma split-ring resonator metamaterial: A study of basic conditions and configurations

    Energy Technology Data Exchange (ETDEWEB)

    Kourtzanidis, Konstantinos, E-mail: kkourt@utexas.edu; Pederson, Dylan M.; Raja, Laxminarayan L. [Department of Aerospace Engineering and Engineering Mechanics, The University of Texas at Austin, Austin, Texas 78712-1221 (United States)

    2016-05-28

    We propose and study numerically a tunable and reconfigurable metamaterial based on coupled split-ring resonators (SRRs) and plasma discharges. The metamaterial couples the magnetic-electric response of the SRR structure with the electric response of a controllable plasma slab discharge that occupies a volume of the metamaterial. Because the electric response of a plasma depends on its constitutive parameters (electron density and collision frequency), the plasma-based metamaterial is tunable and active. Using three-dimensional numerical simulations, we analyze the coupled plasma-SRR metamaterial in terms of transmittance, performing parametric studies on the effects of electron density, collisional frequency, and the position of the plasma slab with respect to the SRR array. We find that the resonance frequency can be controlled by the plasma position or the plasma-to-collision frequency ratio, while transmittance is highly dependent on the latter.

  10. Exploring the electron density in plasma induced by EUV radiation: I. Experimental study in hydrogen

    NARCIS (Netherlands)

    van der Horst, R. M.; Beckers, J.; Osorio, E. A.; Astakhov, D. I.; Goedheer, W. J.; Lee, C. J.; Ivanov, V. V.; Krivtsun, V. M.; Koshelev, K. N.; Lopaev, D. V.; Bijkerk, F.; Banine, V.

    2016-01-01

    Plasmas induced by EUV radiation are unique since they are created without the need of any discharge. Moreover, it is essential to characterize these plasmas to understand and predict their long term impact on highly delicate optics in EUV lithography tools. In this paper we study plasmas induced by

  11. Real-time In Situ Electron Spin Resonance Measurements on Fungal Spores of Penicillium digitatum during Exposure of Oxygen Plasmas

    CERN Document Server

    Ishikawa, Kenji; Tanaka, Hiromasa; Tamiya, Kazuhiro; Hashizume, Hiroshi; Ohta, Takayuki; Ito, Masafumi; Iseki, Sachiko; Takeda, Keigo; Kondo, Hiroki; Sekine, Makoto; Hori, Masaru

    2012-01-01

    We report the kinetic analysis of free radicals on fungal spores of Penicillium digitatum interacted with atomic oxygen generated plasma electric discharge using real time in situ electron spin resonance (ESR) measurements. We have obtained information that the ESR signal from the spores was observed and preliminarily assignable to semiquinone radical with a g-value of around 2.004 and a line width of approximately 5G. The decay of the signal is possibly linked to the inactivation of the fungal spore. The real-time in situ ESR has proven to be a useful method to elucidate plasma-induced surface reactions on biological specimens.

  12. Real-time in situ electron spin resonance measurements on fungal spores of Penicillium digitatum during exposure of oxygen plasmas

    Science.gov (United States)

    Ishikawa, Kenji; Mizuno, Hiroko; Tanaka, Hiromasa; Tamiya, Kazuhiro; Hashizume, Hiroshi; Ohta, Takayuki; Ito, Masafumi; Iseki, Sachiko; Takeda, Keigo; Kondo, Hiroki; Sekine, Makoto; Hori, Masaru

    2012-07-01

    We report the kinetic analysis of free radicals on fungal spores of Penicillium digitatum interacted with atomic oxygen generated plasma electric discharge using real time in situ electron spin resonance (ESR) measurements. We have obtained information that the ESR signal from the spores was observed and preliminarily assignable to semiquinone radical with a g-value of around 2.004 and a line width of approximately 5G. The decay of the signal is possibly linked to the inactivation of the fungal spore. The real-time in situ ESR has proven to be a useful method to elucidate plasma-induced surface reactions on biological specimens.

  13. H$^{-}$ ion source for CERN's Linac4 accelerator: simulation, experimental validation and optimization of the hydrogen plasma

    CERN Document Server

    Mattei, Stefano; Lettry, Jacques

    2017-07-25

    Linac4 is the new negative hydrogen ion (H$^-$) linear accelerator of the European Organization for Nuclear Research (CERN). Its ion source operates on the principle of Radio-Frequency Inductively Coupled Plasma (RF-ICP) and it is required to provide 50~mA of H$^-$ beam in pulses of 600~$\\mu$s with a repetition rate up to 2 Hz and within an RMS emittance of 0.25~$\\pi$~mm~mrad in order to fullfil the requirements of the accelerator. This thesis is dedicated to the characterization of the hydrogen plasma in the Linac4 H$^-$ ion source. We have developed a Particle-In-Cell Monte Carlo Collision (PIC-MCC) code to simulate the RF-ICP heating mechanism and performed measurements to benchmark the fraction of the simulation outputs that can be experimentally accessed. The code solves self-consistently the interaction between the electromagnetic field generated by the RF coil and the resulting plasma response, including a kinetic description of charged and neutral species. A fully-implicit implementation allowed to si...

  14. Ultralow field emission from thinned, open-ended, and defected carbon nanotubes by using microwave hydrogen plasma processing

    Science.gov (United States)

    Deng, Jian-Hua; Cheng, Lin; Wang, Fan-Jie; Yu, Bin; Li, Guo-Zheng; Li, De-Jun; Cheng, Guo-An

    2015-01-01

    Ultralow field emission is achieved from carbon nanotubes (CNTs) by using microwave hydrogen plasma processing. After the processing, typical capped CNT tips are removed, with thinned, open-ended, and defected CNTs left. Structural analyses indicate that the processed CNTs have more SP3-hybridized defects as compared to the pristine ones. The morphology of CNTs can be readily controlled by adjusting microwave powers, which change the shape of CNTs by means of hydrogen plasma etching. Processed CNTs with optimal morphology are found to have an ultralow turn-on field of 0.566 V/μm and threshold field of 0.896 V/μm, much better than 0.948 and 1.559 V/μm of the as-grown CNTs, respectively. This improved FE performance is ascribed to the structural changes of CNTs after the processing. The thinned and open-ended shape of CNTs can facilitate electron tunneling through barriers and additionally, the increased defects at tube walls can serve as new active emission sites. Furthermore, our plasma processed CNTs exhibit excellent field emission stability at a large emission current density of 10.36 mA/cm2 after being perfectly aged, showing promising prospects in applications as high-performance vacuum electron sources.

  15. The Geometry Variation of As-Grown Carbon Coils with Ni Layer Thickness and Hydrogen Plasma Pretreatment

    Directory of Open Access Journals (Sweden)

    Young-Chul Jeon

    2013-01-01

    Full Text Available Carbon coils could be synthesized using C2H2/H2 as source gases and SF6 as an incorporated additive gas under thermal chemical vapor deposition system. Ni layer on SiO2 substrate was used as a catalyst for the formation of carbon coils. Ni powder was evaporated to form Ni layer on the substrate. The characteristics (formation densities, morphologies, and geometries of as-grown carbon coils on the substrate were investigated as a function of the evaporation time for Ni catalyst layer formation. By hydrogen plasma pretreatment prior to carbon coils synthesis reaction, the dominant formation of the nanosized wave-like geometry of carbon coils could be achieved. The characteristics of as-grown carbon coils with or without hydrogen plasma pretreatment process were investigated. The cause for the control of the carbon coils geometries from the microsized type to the nanosized wave-like one by H2 plasma pretreatment was discussed in association with the stress of Ni catalyst layer on the substrate.

  16. Hot bubbles of planetary nebulae with hydrogen-deficient winds I. Heat conduction in a chemically stratified plasma

    CERN Document Server

    Sandin, Christer; Schönberner, Detlef; Rühling, Ute

    2016-01-01

    Heat conduction has been found a plausible solution to explain discrepancies between expected and measured temperatures in hot bubbles of planetary nebulae (PNe). While the heat conduction process depends on the chemical composition, to date it has been exclusively studied for pure hydrogen plasmas in PNe. A smaller population of PNe show hydrogen-deficient and helium- and carbon-enriched surfaces surrounded by bubbles of the same composition; considerable differences are expected in physical properties of these objects in comparison to the pure hydrogen case. The aim of this study is to explore how a chemistry-dependent formulation of the heat conduction affects physical properties and how it affects the X-ray emission from PN bubbles of hydrogen-deficient stars. We extend the description of heat conduction in our radiation hydrodynamics code to work with any chemical composition. We then compare the bubble-formation process with a representative PN model using both the new and the old descriptions. We also ...

  17. Study on the effect of hydrogen addition on the variation of plasma parameters of argon-oxygen magnetron glow discharge for synthesis of TiO2 films

    Directory of Open Access Journals (Sweden)

    Partha Saikia

    2016-04-01

    Full Text Available We report the effect of hydrogen addition on plasma parameters of argon-oxygen magnetron glow discharge plasma in the synthesis of H-doped TiO2 films. The parameters of the hydrogen-added Ar/O2 plasma influence the properties and the structural phases of the deposited TiO2 film. Therefore, the variation of plasma parameters such as electron temperature (Te, electron density (ne, ion density (ni, degree of ionization of Ar and degree of dissociation of H2 as a function of hydrogen content in the discharge is studied. Langmuir probe and Optical emission spectroscopy are used to characterize the plasma. On the basis of the different reactions in the gas phase of the magnetron discharge, the variation of plasma parameters and sputtering rate are explained. It is observed that the electron and heavy ion density decline with gradual addition of hydrogen in the discharge. Hydrogen addition significantly changes the degree of ionization of Ar which influences the structural phases of the TiO2 film.

  18. Waveguide slot-excited long racetrack electron cyclotron resonance plasma source for roll-to-roll (scanning) processing.

    Science.gov (United States)

    You, H-J

    2013-07-01

    We present a SLot-excited ANtenna (SLAN) long racetrack ECR plasma source that is utilized for roll-to-roll plasma processing such as thin film encapsulation of large-area OLED (organic light emitting diode) panel or modification of fabric surfaces. This source is designed to be long, and to operate under high density uniform plasma with sub-milli-torr pressures. The above features are accomplished by a slot-excited long racetrack resonator with a toroidal geometry of magnetic field ECR configuration, and reinforced microwave electric distributions along the central region of plasma chamber. Also, a new feature has been added to the source. This is to employ a tail plunger, which allows the microwave electric field and the uniformity of the plasma profile to be easily adjustable. We have successfully generated Ar plasmas operating with the microwave power of 0.5-3 kW in the pressure range of 0.2-10 mTorr. The plasma is uniform (racetrack-SLAN source.

  19. Structural and Physical Characteristics of Ultrananocrystalline Diamond/Hydrogenated Amorphous Carbon Composite Films Deposited Using a Coaxial Arc Plasma Gun

    Science.gov (United States)

    Yoshitake, Tsuyoshi; Nakagawa, You; Nagano, Akira; Ohtani, Ryota; Setoyama, Hiroyuki; Kobayashi, Eiichi; Sumitani, Kazushi; Agawa, Yoshiaki; Nagayama, Kunihito

    2010-01-01

    Ultrananocrystalline diamond (UNCD)/hydrogenated amorphous carbon (a-C:H) films were formed without initial nucleation using a coaxial arc plasma gun. The UNCD crystallite diameters estimated from the X-ray diffraction peaks were approximately 2 nm. The Fourier transform infrared absorption spectrum exhibited an intense sp3-CH peak that might originate from the grain boundaries between UNCD crystallites whose dangling bonds are terminated with hydrogen atoms. A narrow sp3 peak in the photoemission spectrum implied that the film comprises a large number of UNCD crystallites. Large optical absorption coefficients at photon energies larger than 3 eV that might be due to the grain boundaries are specific to the UNCD/a-C:H films.

  20. Elastic, charge transfer, and related transport cross sections for proton impact of atomic hydrogen for astrophysical and laboratory plasma modeling

    Science.gov (United States)

    Schultz, D. R.; Ovchinnikov, S. Yu; Stancil, P. C.; Zaman, T.

    2016-04-01

    Updating and extending previous work (Krstić and Schultz 1999 J. Phys. B: At. Mol. Opt. Phys. 32 3458 and other references) comprehensive calculations were performed for elastic scattering and charge transfer in proton—atomic hydrogen collisions. The results, obtained for 1301 collision energies in the center-of-mass energy range of 10-4-104 eV, are provided for integral and differential cross sections relevant to transport modeling in astrophysical and other plasma environments, and are made available through a website. Use of the data is demonstrated through a Monte Carlo transport simulation of solar wind proton propagation through atomic hydrogen gas representing a simple model of the solar wind interaction with heliospheric neutrals.

  1. The creation of strongly coupled plasmas using an intense heavy ion beam: low-entropy compression of hydrogen and the problem of hydrogen metallization

    CERN Document Server

    Tahir, N A; Shutov, A; Varentsov, D; Udrea, S; Hoffmann, Dieter H H; Juranek, H; Redmer, R; Portugues, R F; Lomonosov, I V; Fortov, V E

    2003-01-01

    Intense heavy ion beams deposit energy very efficiently over extended volumes of solid density targets, thereby creating large samples of strongly coupled plasmas. Intense beams of energetic heavy ions are therefore an ideal tool to research this interesting field. It is also possible to design experiments using special beam-target geometries to achieve low-entropy compression of samples of matter. This type of experiments is of particular interest for studying the problem of hydrogen metallization. In this paper we present a design study of such a proposed experiment that will be carried out at the future heavy ion synchrotron facility SIS100, at the Gesellschaft fuer Schwerionenforschung, Darmstadt. This study has been done using a two-dimensional hydrodynamic computer code. The target consists of a solid hydrogen cylinder that is enclosed in a thick shell of lead whose one face is irradiated with an ion beam which has an annular (ring shaped) focal spot. The beam intensity and other parameters are consider...

  2. Hydrogen storage and hydrolysis properties of core-shell structured Mg-MFx (M=V, Ni, La and Ce) nano-composites prepared by arc plasma method

    Science.gov (United States)

    Mao, Jianfeng; Zou, Jianxin; Lu, Chong; Zeng, Xiaoqin; Ding, Wenjiang

    2017-10-01

    In this work, core-shell structured Mg-MFx (M = V, Ni, La and Ce) nano-composites are prepared by using arc plasma method. The particle size distribution, phase components, microstructures, hydrogen sorption properties of these composites and hydrolysis properties of their corresponding hydrogenated powders are carefully investigated. It is shown that the addition of MFx through arc plasma method can improve both the hydrogen absorption kinetics of Mg and the hydrolysis properties of corresponding hydrogenated powders. Among them, the Mg-NiF2 composite shows the best hydrogen absorption properties at relatively low temperatures, which can absorb 3.26 wt% of H2 at 373 K in 2 h. Such rapid hydrogen absorption rate is mainly due to the formation of Mg2Ni and MgF2 on Mg particles during arc evaporation and condensation. In contrast, measurements also show that the hydrogenated Mg-VF3 composite has the lowest peak desorption temperature and the fastest hydrolysis rate among all the hydrogenated Mg-MFx composites. The less agglomeration tendency of Mg particles and VO2 covered on MgH2 particles account for the reduced hydrogen desorption temperature and enhanced hydrolysis rate.

  3. Options for laser compression of matter to study dense-plasma phases at low entropy, including metallization of hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Meyer-ter-Vehn, J.; Oparin, A. [Max-Planck-Institut fuer Quantenoptik, D-85748 Garching (Germany); Aoki, T. [Tokyo Institute of Technology, 4259 Nagatsuta, Midori-Ku, Yokohama 227 (Japan)

    1996-05-01

    The potential of high-power lasers for detailed studies of strongly coupled plasmas at low entropy is discussed, emphasizing multiple-shock techniques. Some outstanding features like metallization in solids and related ionization phase transitions in the fluid phase{emdash}predicted theoretically, but not yet observed experimentally{emdash}are reviewed. Planar multiple shock compression of solid hydrogen is described, using reverberating shocks between massive liners and, alternatively, a stepped pressure pulse acting from one side. In the latter case, shock splitting and a rarefaction shock show up at the metallic phase transition. {copyright} {ital 1996 American Institute of Physics.}

  4. Photoelectron Emission from Metal Surfaces Induced by VUV-emission of Filament Driven Hydrogen Arc Discharge Plasma

    CERN Document Server

    Laulainen, J; Koivisto, H; Komppula, J; Tarvainen, O

    2015-01-01

    Photoelectron emission measurements have been performed using a filament-driven multi-cusp arc discharge volume production H^- ion source (LIISA). It has been found that photoelectron currents obtained with Al, Cu, Mo, Ta and stainless steel (SAE 304) are on the same order of magnitude. The photoelectron currents depend linearly on the discharge power. It is shown experimentally that photoelectron emission is significant only in the short wavelength range of hydrogen spectrum due to the energy dependence of the quantum efficiency. It is estimated from the measured data that the maximum photoelectron flux from plasma chamber walls is on the order of 1 A per kW of discharge power.

  5. Spectral line shapes using the dicenter approach for dense hot plasmas: hydrogen and helium-like lines.

    Science.gov (United States)

    Sauvan, P.; Leboucher-Dalimier, E.; Angelo, P.; Derfoul, H.; Ceccotti, T.; Poquerusse, A.; Calisti, A.; Talin, B.

    2000-05-01

    This paper reports on the spectral line shape of hydrogen and helium-like lines relevant to the quasi-static dicenter model. This treatment is justified for hot dense, moderate Z plasmas. The code IDEFIX developed for the quasi-static dicenter model involves a self-consistent description of the interactions and of the radiative properties. Strong dependence of the transition energies and of the dipole moments on the interionic separation are pointed out and novel density-dependent spectroscopic features such as asymmetries, satellite-like features, molecular transitions are exhibited. The theoretical spectra presented are discussed in connection with experimental results where these exist.

  6. Photoelectron emission from metal surfaces induced by VUV-emission of filament driven hydrogen arc discharge plasma

    Science.gov (United States)

    Laulainen, J.; Kalvas, T.; Koivisto, H.; Komppula, J.; Tarvainen, O.

    2015-04-01

    Photoelectron emission measurements have been performed using a filament-driven multi-cusp arc discharge volume production H- ion source (LIISA). It has been found that photoelectron currents obtained with Al, Cu, Mo, Ta and stainless steel (SAE 304) are on the same order of magnitude. The photoelectron currents depend linearly on the discharge power. It is shown experimentally that photoelectron emission is significant only in the short wavelength range of hydrogen spectrum due to the energy dependence of the quantum efficiency. It is estimated from the measured data that the maximum photoelectron flux from plasma chamber walls is on the order of 1 A per kW of discharge power.

  7. Profiles of ion beams and plasma parameters on a multi-frequencies microwaves large bore electron cyclotron resonance ion source with permanent magnets.

    Science.gov (United States)

    Kato, Yushi; Sakamoto, Naoki; Kiriyama, Ryutaro; Takenaka, Tomoya; Kurisu, Yosuke; Nozaki, Dai; Sato, Fuminobu; Iida, Toshiyuki

    2012-02-01

    In order to contribute to various applications of plasma and beams based on an electron cyclotron resonance, a new concept on magnetic field with all magnets on plasma production and confinement has been proposed with enhanced efficiency for broad and dense ion beam. The magnetic field configuration consists of a pair of comb-shaped magnet surrounding plasma chamber cylindrically. Resonance zones corresponding for 2.45 GHz and 11-13 GHz frequencies are positioned at spatially different positions. We launch simultaneously multiplex frequencies microwaves operated individually, try to control profiles of the plasma parameters and the extracted ion beams, and to measure them in detail.

  8. Spectroscopy between parabolic states in hydrogen: Enhancement of the Stark-induced resonances in its photoionization

    Energy Technology Data Exchange (ETDEWEB)

    Glab, W.L.; Ng, K.; Yao, D.; Nayfeh, M.H.

    1985-06-01

    We present calculations of the photoionization spectrum of excited hydrogen using ..pi.. polarization in the presence of a strong electric field as a function of the spherical (applicable to complex atoms) and parabolic quantum numbers of the excited state. We also present corresponding measurements of the photoionization yield from the individual parabolic states of n = 2. Both the calculations and the measurements show an enhancement of the depth of the so-called ''Stark-induced modulation'' in the region E> or =0 when the initial excited state is a pure m/sub l/ = 0 blue state, and disappear almost completely when the initial state is a pure m/sub l/ = 0 red state. These results are understood using arguments based on the fact that the charge distribution of the Stark-induced states is tremendously extended up field. Because of the excellent signal to noise ratio of the enhanced modulations, we were able to measure the field dependence of the spacings with sufficient accuracy to confirm the (3/4) power law and rule out the recently suggested (2/3) power law.

  9. Resonance broadening of argon lines in a micro-scaled atmospheric pressure plasma jet (argon μAPPJ)

    Science.gov (United States)

    Pipa, A. V.; Ionikh, Yu. Z.; Chekishev, V. M.; Dünnbier, M.; Reuter, S.

    2015-06-01

    Optical emission from atmospheric pressure micro-jet operating with pure argon (argon μAPPJ) flow has been detected with a moderate resolution spectrometer. Large broadening of the several argon (Ar) lines has been observed in the near infrared spectral region. This effect was attributed to resonance broadening of the s2 (Paschen notation) level in 3p54s configuration. In the present work, corresponding line profiles are suggested for plasma diagnostics. For this, a general case of resonance broadening coefficient of noble gases is discussed. As broadening reflects the Ar density, and the static gas pressure of the jet is in equilibrium with the ambient, the local gas temperature can be inferred. An estimation of gas temperature from the width of the 750 nm Ar line is in agreement with rotational temperature of OH radicals determined from the A2Σ+ → X2Π (0, 0) band. At low temperatures (300-600 K) and at partial Ar pressure near atmospheric, the resonance width of the suggested lines is very sensitive to small temperature variations. High temperature sensitivity and large width make the resonance broadened lines very attractive for diagnostics of low temperature discharges at elevated pressure, e.g., as they are used in plasma-medicine.

  10. Maintenance of the resonance in a cavity filled with a variable density plasma; Entretien de la resonance d'une cavite chargee par un plasma de densite variable

    Energy Technology Data Exchange (ETDEWEB)

    Melin, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    A study has been made of the possibility of keeping in resonance a cavity filled with a plasma of variable density; only the low HF power zone has been examined (less than a few dozen W). A calculation is first made, for the chosen experimental conditions, of the slipping of the resonance frequency of a cavity as a function of the plasma parameters (density, temperature), with a view to obtaining an idea of its importance. A description is then given of the experimental set-up: the S band cavity (3000 Mc/sec) is supplied by a carcinotron type generator; use is made of the plasma of a positive column whose density ({approx}10{sup 11} cm{sup -3}) can easily be controlled so as to obtain slipping of the cavity frequency ({delta}F{sub max} {approx} 50 Mc/s). The zone of automatic agreement thus obtained for the S band is 3 per cent continuously ({approx}100 Mc/s) and 1 per cent ({approx}30 Mc/s) with a response time of 10 {mu}s (sudden changes in density, {delta}n {approx} 5.10{sup 10} cm{sup 3}). These characteristics already compare very favorably with existing systems, and can easily be improved. (author) [French] On etudie une possibilite de maintenir a la resonance une cavite chargee par un plasma dont la densite varie; on se limite au domaine des puissances HF faibles (< quelques dizaines de W). On calcule tout d'abord, pour les conditions experimentales choisies, le glissement de la frequence de resonance d'une cavite en fonction des parametres du plasma, densite, temperature, pour en evaluer les ordres de grandeur. On decrit ensuite la realisation experimentale: la cavite bande S (3000 Mc/s) est alimentee par un generateur du type carcinotron; on utilise le plasma d'une colonne positive, dont on controle facilement la densite ({approx}10{sup 11} cm{sup -3}) pour faire glisser en frequence la cavite ({delta}F{sub max} {approx} 50 Mc/s). La zone d'accord automatique obtenue ainsi pour la bande S est de 3 pour cent en continu ({approx}100 Mc

  11. Ion beam emission within a low energy focus plasma (0.1 kJ) operating with hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    El-Aragi, Gamal E. [Nuclear Research Center, Cairo (Egypt). Plasma Physics and Nuclear Fusion Dept.

    2010-06-15

    An investigation of energetic ion beam emission from a low energy plasma focus (0.1 kJ Mather type) device operating with hydrogen gas is studied. The ion beam emission is investigated using time-integrated and time-resolved detectors. The present plasma focus device is powered by a capacitor bank of 1 {mu}F at 18 kV maximum charging voltage. The correlation of ion beam intensity with filling gas pressure indicates that the beam emission is maximized at the optimum pressure for the focus formation at peak current. Energy of ions is determined with a time-of-flight (TOF) method, taking into account distance from the center electrode to the detection plane. (orig.)

  12. A Luminescence Characterization of Adsorbed Hydrogen Atoms on Plasma Facing Materials

    Energy Technology Data Exchange (ETDEWEB)

    Grankin, V.P. [Azov Sea State Technical Univ., Mariupol (Ukraine). Computer Science Dept.; Styrov, V.V. [Azov Sea State Technical Univ., Mariupol (Ukraine). Phisics Dept.

    2004-06-01

    An atomic probe technique for characterization of hydrogen atoms on fusion related materials is described. The technique for determining surface coverage by hydrogen atoms or isotopes under both non-steady-state and stationary conditions is based on detection of heterogeneous chemiluminescence (HCL) excited in the interaction between adsorbed atoms and the pulsed normalized probing atomic flow. The recombination of hydrogen atoms from the gas phase was found to occur in general case via both collision Rideal-Eley (RE) and diffusion Langmuir-Hinshelwood (LH) mechanisms. The instantaneous optical response allows extracting the contributions of these two mechanisms to the overall reaction rate for various experimental conditions. The HCL method is also applicable for quick measurement of the reactivity of adatoms (in terms of the recombination coefficient {gamma}) for all the materials including metals. The spectra and kinetics of HCL are useful for estimation of heats of adsorption for hydrogen atoms or isotopes.

  13. Use of hydrogen peroxide vapour & plasma irradiation in combination for quick decontamination of closed chambers

    National Research Council Canada - National Science Library

    Mourya, DevendraT; Shahani, HamishC; Yadav, PragyaD; Barde, PradipV

    2016-01-01

    .... However, being extremely corrosive in nature generating very irritating fumes and difficulty in maintaining a high level of gas concentration, many laboratories prefer the vaporization of hydrogen peroxide (H 2 O 2 ) as an alternative...

  14. Advanced nanoporous TiO2 photocatalysts by hydrogen plasma for efficient solar-light photocatalytic application

    Science.gov (United States)

    An, Ha-Rim; Park, So Young; Kim, Hyeran; Lee, Che Yoon; Choi, Saehae; Lee, Soon Chang; Seo, Soonjoo; Park, Edmond Changkyun; Oh, You-Kwan; Song, Chan-Geun; Won, Jonghan; Kim, Youn Jung; Lee, Jouhahn; Lee, Hyun Uk; Lee, Young-Chul

    2016-07-01

    We report an effect involving hydrogen (H2)-plasma-treated nanoporous TiO2(H-TiO2) photocatalysts that improve photocatalytic performance under solar-light illumination. H-TiO2 photocatalysts were prepared by application of hydrogen plasma of assynthesized TiO2(a-TiO2) without annealing process. Compared with the a-TiO2, the H-TiO2 exhibited high anatase/brookite bicrystallinity and a porous structure. Our study demonstrated that H2 plasma is a simple strategy to fabricate H-TiO2 covering a large surface area that offers many active sites for the extension of the adsorption spectra from ultraviolet (UV) to visible range. Notably, the H-TiO2 showed strong ·OH free-radical generation on the TiO2 surface under both UV- and visible-light irradiation with a large responsive surface area, which enhanced photocatalytic efficiency. Under solar-light irradiation, the optimized H-TiO2 120(H2-plasma treatment time: 120 min) photocatalysts showed unprecedentedly excellent removal capability for phenol (Ph), reactive black 5(RB 5), rhodamine B (Rho B) and methylene blue (MB) — approximately four-times higher than those of the other photocatalysts (a-TiO2 and P25) — resulting in complete purification of the water. Such well-purified water (>90%) can utilize culturing of cervical cancer cells (HeLa), breast cancer cells (MCF-7), and keratinocyte cells (HaCaT) while showing minimal cytotoxicity. Significantly, H-TiO2 photocatalysts can be mass-produced and easily processed at room temperature. We believe this novel method can find important environmental and biomedical applications.

  15. Hydrogen bonding study of quinoline and coal-derived asphaltene components with o-phenylphenol by proton magnetic resonance. [9 references

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, S.R.; Galya, L.G.; Brown, B.J.; Li, N.C.

    1976-01-01

    Proton magnetic resonance (PMR) studies are reported of hydrogen bonding between the OH proton of o-phenylphenol (OPP) and the nitrogen electron donor of quinoline (Qu). Data are also reported on the hydrogen bonding of a coal-derived asphaltene and its acid and base components with OPP. Determination was made of the equilibrium constants of the 1 : 1 complex between OPP and Qu at 39, 32, 1, and -18/sup 0/C from the PMR studies. Qualitative results are reported for the interaction between the base fraction of asphaltene and OPP at 32, 1, and -26/sup 0/C.

  16. Hydrogen bonding study of quinoline and coal-derived asphaltene components with o-phenylphenol by proton magnetic resonance. [9 refs

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, S.C.; Galya, L.G.; Brown, B.J.; Li, N.C.

    1976-01-01

    Proton magnetic resonance (PMR) studies are reported of hydrogen bonding between the OH proton of o-phenylphenol (OPP) and the nitrogen electron donor of quinoline (Qu). Data are also reported on the hydrogen bonding of a coal-derived asphaltene and its acid and base components with OPP. Determination was made of the equilibrium constants of the 1:1 complex between OPP and Qu at 39, 32, 1, and -18/sup 0/C from the PMR studies. Qualitative results are reported for the interaction between the base fraction of asphaltene and OPP at 32, 1, and -26/sup 0/C.

  17. Study of a continuous plasma generated by electron bombardment and its mixing with a laser induced plasma. Influence of collisions on resonance cone phenomenon; Contribution a l`etude d`un plasma cree de facon continue par bombardement electronique et de son melange avec un photo-plasma pulse. Influence des collisions sur les cones de resonance

    Energy Technology Data Exchange (ETDEWEB)

    Besuelle, E.

    1997-02-25

    This thesis deals with three different fields of plasma physics. In the first part, we studied free expansion of an ionised uranium vapour generated in an electron beam evaporator. The electron temperature and the electron density of the expanding plasma have been measured by a Langmuir probe. The experimental results have been compared with the ones obtained by numerical simulation using a fluid code. The calculated points are in the error bars. We observe that there are two electron populations with different temperatures, which undergo a mixing during the plasma expansion. The neutral density influence on the electron temperature by collisional relaxation is also studied. The second part deals with a plasma diagnostic which can replace Langmuir probe in the case of a cold magnetized plasma: the resonance cone phenomenon. After recalling the wave propagation theory in a cold plasma, we introduce a new calculation of the potential radiated by an antenna in a collisional magnetized plasma. The domain where the resonance cone exists in considerably reduced because of collisions. More of that, the cone angle is reduced by this phenomenon too. The experiments performed show that we must take into account a wave turbulence phenomenon to explain the High collision frequency that we observe. The third part is about the study of the expansion of a plasma into another one. We solve this problem with fluid codes and Particle-In-Cell (PIC) code. THe electron families have a counter stream motion locally. Then, we study the electrostatic extraction of two plasmas-one pulsed, one continuous-in which we observe electron unfurling. (author).

  18. The role of seed electrons on the plasma breakdown and preglow of electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, O.; Ropponen, T.; Toivanen, V.; Kalvas, T.; Koivisto, H. [Department of Physics, University of Jyvaskyla, Jyvaskyla 40500 (Finland); Thuillier, T. [LPSC, Universite Joseph Fourier Grenoble 1, CNRS/IN2P3, 38026 Grenoble, France and Institut National Polytechnique de Grenoble, 38026 Grenoble (France); Noland, J. [Lawrence Berkeley National Laboratory, One Cyclotron Road, Berkeley, California 94720 (United States)

    2010-02-15

    The 14 GHz Electron Cyclotron Resonance Ion Source at University of Jyvaeskylae, Department of Physics (JYFL) has been operated in pulsed mode in order to study the plasma breakdown and preglow effect. It was observed that the plasma breakdown time and preglow characteristics are affected by seed electrons provided by a continuous low power microwave signal at secondary frequency. Sustaining low density plasma during the off-period of high power microwave pulses at the primary frequency shifts the charge state distribution of the preglow transient toward higher charge states. This could be exploited for applications requiring fast and efficient ionization of radioactive elements as proposed for the Beta Beam project within the EURISOL design study, for example. In this article we present results measured with helium and neon.

  19. The effect of an anti-hydrogen bond on Fermi resonance:A Raman spectroscopic study of the Fermi doublet v1-v12 of liquid pyridine

    Institute of Scientific and Technical Information of China (English)

    Li Dong-Fei; Gao Shu-Qin; Sun Cheng-Lin; Li Zuo-Wei

    2012-01-01

    The effects of an anti-hydrogen bond on the v1-v12 Fermi resonance (FR) of pyridine are experimentally investigated by using Raman scattering spectroscopy.Three systems,pyridine/water,pyridine/formamide,and pyridine/carbon tetrachloride,provide varying degrees of strength for the diluent-pyridine anti-hydrogen bond complex.Water forms a stronger anti-hydrogen bond with pyridine than with formamide,and in the case of adding non-polar solvent carbon tetrachloride,which is neither a hydrogen bond donor nor an acceptor and incapable of forming a hydrogen bond with pyridine,the intermolecular distance of pyridine will increase and the interaction of pyridine molecules will reduce.The dilution studies are performed on the three systems.Comparing with the values of the Fermi coupling coefficient W of the ring breathing mode v1 and triangle mode v12 of pyridine at different volume concentrations,which are calculated according to the Bertran equations,in three systems,we find that the solution with the strongest anti-hydrogen bond,water,shows the fastest change in thev1-v12 Fermi coupling coefficient W with the volume concentration varying,followed by the formamide and carbon tetrachloride solutions.These results suggest that the stronger anti-hydrogen bond-forming effect will cause a greater reduction in the strength of the v1-v12 FR of pyridine.According to the mechanism of the formation of an anti-hydrogen bond in the complexes and the FR theory,a qualitative explanation for the anti-hydrogen bond effect in reducing the strength of the v1 - v12 FR of pyridine is given.

  20. Laer Pulse Driven THz Generation via Resonant Transition Radiation in Inhomogeneous Plasmas

    CERN Document Server

    Miao, Chenlong; Antonsen, Thomas M

    2016-01-01

    An intense, short laser pulse propagating across a plasma boundary ponderomotively drives THz radiation. Full format PIC simulations and theoretical analysis are conducted to investigate the properties of this radiation. Simulation results show the THz emission originates in regions of varying density and covers a broad spectrum with maximum frequency close to the maximum plasma frequency. In the case of a sharp vacuum-plasma boundary, the radiation is generated symmetrically at the plasma entrance and exit, and its properties are independent of plasma density when the density exceeds a characteristic value determined by the product of the plasma frequency and the laser pulse duration. For a diffuse vacuum-plasma boundary, the emission from the plasma entrance and exit is asymmetric: increasing and decreasing density ramps enhance and diminish the radiated energy respectively. Enhancements by factors of 50 are found and simulations show that a 1.66 J, 50 fs driver pulse can generate ~400 \\mu J of THz radiatio...