WorldWideScience

Sample records for residues process design

  1. Process Design Aspects for Scandium-Selective Leaching of Bauxite Residue with Sulfuric Acid

    OpenAIRE

    Konstantinos Hatzilyberis; Theopisti Lymperopoulou; Lamprini-Areti Tsakanika; Klaus-Michael Ochsenkühn; Paraskevas Georgiou; Nikolaos Defteraios; Fotios Tsopelas; Maria Ochsenkühn-Petropoulou

    2018-01-01

    Aiming at the industrial scale development of a Scandium (Sc)-selective leaching process of Bauxite Residue (BR), a set of process design aspects has been investigated. The interpretation of experimental data for Sc leaching yield, with sulfuric acid as the leaching solvent, has shown significant impact from acid feed concentration, mixing time, liquid to solids ratio (L/S), and number of cycles of leachate re-usage onto fresh BR. The thin film diffusion model, as the fundamental theory for l...

  2. Sampling and sample processing in pesticide residue analysis.

    Science.gov (United States)

    Lehotay, Steven J; Cook, Jo Marie

    2015-05-13

    Proper sampling and sample processing in pesticide residue analysis of food and soil have always been essential to obtain accurate results, but the subject is becoming a greater concern as approximately 100 mg test portions are being analyzed with automated high-throughput analytical methods by agrochemical industry and contract laboratories. As global food trade and the importance of monitoring increase, the food industry and regulatory laboratories are also considering miniaturized high-throughput methods. In conjunction with a summary of the symposium "Residues in Food and Feed - Going from Macro to Micro: The Future of Sample Processing in Residue Analytical Methods" held at the 13th IUPAC International Congress of Pesticide Chemistry, this is an opportune time to review sampling theory and sample processing for pesticide residue analysis. If collected samples and test portions do not adequately represent the actual lot from which they came and provide meaningful results, then all costs, time, and efforts involved in implementing programs using sophisticated analytical instruments and techniques are wasted and can actually yield misleading results. This paper is designed to briefly review the often-neglected but crucial topic of sample collection and processing and put the issue into perspective for the future of pesticide residue analysis. It also emphasizes that analysts should demonstrate the validity of their sample processing approaches for the analytes/matrices of interest and encourages further studies on sampling and sample mass reduction to produce a test portion.

  3. Recovery of transuranics from process residues

    International Nuclear Information System (INIS)

    Gray, J.H.; Gray, L.W.

    1987-01-01

    Process residues are generated at both the Rocky Flats Plant (RFP) and the Savannah River Plant (SRP) during aqueous chemical and pyrochemical operations. Frequently, process operations will result in either impure products or produce residues sufficiently contaminated with transuranics to be nondiscardable as waste. Purification and recovery flowsheets for process residues have been developed to generate solutions compatible with subsequent Purex operations and either solid or liquid waste suitable for disposal. The ''scrub alloy'' and the ''anode heel alloy'' are examples of materials generated at RFP which have been processed at SRP using the developed recovery flowsheets. Examples of process residues being generated at SRP for which flowsheets are under development include LECO crucibles and alpha-contaminated hydraulic oil

  4. Design of specimen for weld residual stress simulation

    International Nuclear Information System (INIS)

    Kim, Jin Weon; Park, Jong Sun; Lee, Kyung Soo

    2008-01-01

    The objective of this study is to design a laboratory specimen for simulating residual stress of circumferential butt welding of pipe. Specimen type and method for residual stress generation were proposed based on the review of prior studies and parametric finite element simulation. To prove the proposed specimen type and loading method, the residual stress was generated using the designed specimen by applying proposed method and was measured. The measured residual stress using X-ray diffraction reasonably agreed with the results of finite element simulation considered in the specimen design. Comparison of residual strains measured at several locations of specimen and given by finite element simulation also showed good agreement. Therefore, it is indicated that the designed specimen can reasonably simulate the residual stress of circumferential butt welding of pipe

  5. Residual stress control and design of next-generation ultra-hard gear steels

    Science.gov (United States)

    Qian, Yana

    In high power density transmission systems, Ni-Co secondary hardening steels have shown great potential for next-generation gear applications due to their excellent strength, toughness and superior fatigue performance. Study of residual stress generation and evolution in Ferrium C61 and C67 gear steels revealed that shot peening and laser peening processes effectively produce desired beneficial residual stress in the steels for enhanced fatigue performance. Surface residual stress levels of -1.4GPa and -1.5GPa were achieved in shot peened C61 and laser peened C67, respectively, without introducing large surface roughness or defects. Higher compressive residual stress is expected in C67 according to a demonstrated correlation between attainable residual stress and material hardness. Due to the lack of appropriate shot media, dual laser peening is proposed for future peening optimization in C67. A novel non-destructive synchrotron radiation technique was implemented and applied for the first time for residual stress distribution analysis in gear steels with large composition and property gradients. Observed substantial residual stress redistribution and material microstructure change during the rolling contact fatigue screening test with extremely high 5.4GPa load indicates the unsuitability of the test as a fatigue life predictor. To exploit benefits of higher case hardness and associated residual stress, a new material and process (CryoForm70) aiming at 70Rc surface hardness was designed utilizing the systems approach based on thermodynamics and secondary hardening mechanisms. The composition design was first validated by the excellent agreement between experimental and theoretical core martensite start temperature in the prototype. A novel cryogenic deformation process was concurrently designed to increase the case martensite volume fraction from 76% to 92% for enhanced strengthening efficiency and surface hardness. High temperature vacuum carburizing was

  6. Developments in hydroconversion processes for residues

    Energy Technology Data Exchange (ETDEWEB)

    Douwes, C T [Shell Res. B.V.; Wijffels, J B; Van Klinken, J; Van Zijll Langhout, W C

    1979-01-01

    A review of recent developments in hydrotreating processes for demetallization, desulfurization, and conversion to distillate products of residues covers catalyst developments for suppression of coke formation, maximum metals tolerance, and conversion selectivity; the effects of hydrogen pressure and temperature on catalyst deactivation and conversion; basic operating characteristics of conventional fixed-bed trickle-flow reactors, and of onstream catalyst replacement reactors, including the expanded-bed and the moving-bed reactor; a comparison of catalyst bed activity level, dirt tolerance, reactor effectiveness, temperature control, and thermal stability of the expanded-bed and moving-bed reactors; residue upgrading in slurry-bed reactors of dispersed vanadium sulfide catalyst in the oil; design and control features for safety and reliability; and a cost comparison between the indirect hydrotreating route, in which the asphalt fraction is separated prior to hydrotreating, and the as yet incompletely developed direct route.

  7. Design of a process for the use of residual hydrocarbons coming from the ships arriving at Moin for obtaining of a fuel

    International Nuclear Information System (INIS)

    Madrigal Calderon, Adolfo

    2015-01-01

    A process is designed to carry out the obtaining of a fuel from the residual mixture of residual oils coming from the ships arriving at Moin, Limon, Costa Rica . A sampling of the residual oil in different ships is realized for a month to quantify the water content and basic sediment, as well as the heavy metal content. The results obtained have been 20,4 ± 4,6 % v/v of water and sediment, and 6,939 ppm of heavy metals as a minimum, this value may be higher depending on the quality of lubricant. The production volume of the residual oil is estimated according to historical data of the company ACASE S.A. (company responsible for collecting the oil residue of ships arriving at dock of Moin, Limon); therefore, the plant must process 25,000 liters of dirty oil per day. The main technologies (thermal process, treatment with chemical reaction, vacuum distillation and solvent extraction) to perform the process are compared and studied through a selection matrix. The technical and economic parameters chosen for the matrix have been: environmental impact, cost of operation, cost of equipment, safety of operation, maintenance of equipment, by-products obtained, waste generated, quality of the product obtained and ease of operation. The study has concluded that the treatment with chemical reaction has been the best option for the project of used oil utilization, as well as other physical methods of cleaning as the centrifugation of the same one. The installation of a waste oil processing plant has been a project that environmentally represents a benefit and economically viable, as currently the residual oil is left untreated for later use [es

  8. Thermal Adsorption Processing Of Hydrocarbon Residues

    Directory of Open Access Journals (Sweden)

    Sudad H. Al.

    2017-04-01

    Full Text Available The raw materials of secondary catalytic processes must be pre-refined. Among these refining processes are the deasphalting and demetallization including their thermo adsorption or thermo-contact adsorption variety. In oil processing four main processes of thermo-adsorption refining of hydrocarbon residues are used ART Asphalt Residual Treating - residues deasphaltizing 3D Discriminatory Destructive Distillation developed in the US ACT Adsorption-Contact Treatment and ETCC Express Thermo-Contact Cracking developed in Russia. ART and ACT are processes with absorbers of lift type reactor while 3D and ETCC processes are with an adsorbing reactor having ultra-short contact time of the raw material with the adsorbent. In all these processes refining of hydrocarbon residues is achieved by partial Thermo-destructive transformations of hydrocarbons and hetero-atomic compounds with simultaneous adsorption of the formed on the surface of the adsorbents resins asphaltene and carboids as well as metal- sulphur - and nitro-organic compounds. Demetallized and deasphalted light and heavy gas oils or their mixtures are a quality raw material for secondary deepening refining processes catalytic and hydrogenation cracking etc. since they are characterized by low coking ability and low content of organometallic compounds that lead to irreversible deactivation of the catalysts of these deepening processes.

  9. Residual analysis for spatial point processes

    DEFF Research Database (Denmark)

    Baddeley, A.; Turner, R.; Møller, Jesper

    We define residuals for point process models fitted to spatial point pattern data, and propose diagnostic plots based on these residuals. The techniques apply to any Gibbs point process model, which may exhibit spatial heterogeneity, interpoint interaction and dependence on spatial covariates. Ou...... or covariate effects. Q-Q plots of the residuals are effective in diagnosing interpoint interaction. Some existing ad hoc statistics of point patterns (quadrat counts, scan statistic, kernel smoothed intensity, Berman's diagnostic) are recovered as special cases....

  10. Designing with residual materials

    NARCIS (Netherlands)

    Walhout, W.; Wever, R.; Blom, E.; Addink-Dölle, L.; Tempelman, E.

    2013-01-01

    Many entrepreneurial businesses have attempted to create value based on the residual material streams of third parties. Based on ‘waste’ materials they designed products, around which they built their company. Such activities have the potential to yield sustainable products. Many of such companies

  11. Residual number processing in dyscalculia ?

    OpenAIRE

    Cappelletti, Marinella; Price, Cathy J.

    2013-01-01

    Developmental dyscalculia – a congenital learning disability in understanding numerical concepts – is typically associated with parietal lobe abnormality. However, people with dyscalculia often retain some residual numerical abilities, reported in studies that otherwise focused on abnormalities in the dyscalculic brain. Here we took a different perspective by focusing on brain regions that support residual number processing in dyscalculia. All participants accurately performed semantic and ca...

  12. Solidification process for sludge residue

    International Nuclear Information System (INIS)

    Pearce, K.L.

    1998-01-01

    This report investigates the solidification process used at 100-N Basin to solidify the N Basin sediment and assesses the N Basin process for application to the K Basin sludge residue material. This report also includes a discussion of a solidification process for stabilizing filters. The solidified matrix must be compatible with the Environmental Remediation Disposal Facility acceptance criteria

  13. Process Optimization for Valuable Metal Recovery from Dental Amalgam Residues

    Directory of Open Access Journals (Sweden)

    C.M. Parra–Mesa

    2009-07-01

    Full Text Available In this paper, the methodology used for optimizing leaching in a semi pilot plant is presented. This leaching process was applied to recover value metals from dental amalgam residues. 23 factorial design was used to characterize the process during the first stage and in the second one, a central compound rotational design was used for modeling copper percentage dissolved, a function of the nitric acid concentration, leaching time and temperature. This model explained the 81% of the response variability, which is considered satisfactory given the complexity of the process kinetics and, furthermore, it allowed the definition of the operation conditions for better copper recovery, which this was of 99.15%, at a temperature of 55°C, a concentration of 30% by weight and a time of 26 hours.

  14. Aqueous recovery of plutonium from pyrochemical processing residues

    International Nuclear Information System (INIS)

    Gray, L.W.; Gray, J.H.

    1984-01-01

    Pyrochemical processes provide rapid methods to reclaim plutonium from scrap residues. Frequently, however, these processes yield an impure plutonium product and waste residues that are contaminated with actinides and are therefore nondiscardable. The Savannah River Laboratory and Plant and the Rocky Flats Plant are jointly developing new processes using both pyrochemistry and aqueous chemistry to generate pure product and discardable waste. An example of residue being treated is that from the molten salt extraction (MSE), a mixture of NaCl, KCl, MgCl 2 , PuCl 3 , AmCl 3 , PuO 2 , and Pu 0 . This mixture is scrubbed with molten aluminum containing a small amount of magnesium to produce a nonhomogeneous Al-Pu-Am-Mg alloy. This process, which rejects most of the NaCl-KCl-MgCl 2 salts, results in a product easily dissolved in 6M HNO 3 -0.1M HF. Any residual chloride in the product is removed by precipitation with Hg(I) followed by centrifuging. Plutonium and americium are then separated by the standard Purex process. The americium, initially diverted to the solvent extraction waste stream, can either be recovered or sent to waste

  15. Residue-based Coordinated Selection and Parameter Design of Multiple Power System Stabilizers (PSSs)

    DEFF Research Database (Denmark)

    Su, Chi; Hu, Weihao; Fang, Jiakun

    2013-01-01

    data from time domain simulations. Then a coordinated approach for multiple PSS selection and parameter design based on residue method is proposed and realized in MATLAB m-files. Particle swarm optimization (PSO) is adopted in the coordination process. The IEEE 39-bus New England system model...

  16. Investigating Resulting Residual Stresses during Mechanical Forming Process

    Science.gov (United States)

    Akinlabi, Stephen A.; Fatoba, Olawale S.; Mashinini, Peter M.; Akinlabi, Esther T.

    2018-03-01

    Most manufacturing processes such as machining, welding, heat treatment, laser forming, laser cladding and, laser metal deposition, etc. are subjected to a form of heat or energy to change the geometrical shape thus changing the inherent engineering and structural properties of the material. These changes often cause the development of locked up stresses referred to as residual stresses as a result of these activities. This study reports on the residual stresses developed due to the mechanical forming process to maintain a suitable structural integrity for the formed components. The result of the analysis through the X-ray diffraction confirmed that residual stresses were induced in the manufactured parts and further revealed that residual stresses were compressive in nature as found in the parent material but with values less than the parent material.

  17. Virtual Welded - Joint Design Integrating Advanced Materials and Processing Technology

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Zhishang; Ludewig, Howard W.; Babu, S. Suresh

    2005-06-30

    Virtual Welede-Joint Design, a systematic modeling approach, has been developed in this project to predict the relationship of welding process, microstructure, properties, residual stress, and the ultimate weld fatique strength. This systematic modeling approach was applied in the welding of high strength steel. A special welding wire was developed in this project to introduce compressive residual stress at weld toe. The results from both modeling and experiments demonstrated that more than 10x fatique life improvement can be acheived in high strength steel welds by the combination of compressive residual stress from the special welding wire and the desired weld bead shape from a unique welding process. The results indicate a technology breakthrough in the design of lightweight and high fatique performance welded structures using high strength steels.

  18. Reclamation of plutonium from pyrochemical processing residues

    International Nuclear Information System (INIS)

    Gray, L.W.; Gray, J.H.; Holcomb, H.P.; Chostner, D.F.

    1987-04-01

    Savannah River Laboratory (SRL), Savannah River Plant (SRP), and Rocky Flats Plant (RFP) have jointly developed a process to recover plutonium from molten salt extraction residues. These NaCl, KCL, and MgCl 2 residues, which are generated in the pyrochemical extraction of 241 Am from aged plutonium metal, contain up to 25 wt % dissolved plutonium and up to 2 wt % americium. The overall objective was to develop a process to convert these residues to a pure plutonium metal product and discardable waste. To meet this objective a combination of pyrochemical and aqueous unit operations was used. The first step was to scrub the salt residue with a molten metal (aluminum and magnesium) to form a heterogeneous ''scrub alloy'' containing nominally 25 wt % plutonium. This unit operation, performed at RFP, effectively separated the actinides from the bulk of the chloride salts. After packaging in aluminum cans, the ''scrub alloy'' was then dissolved in a nitric acid - hydrofluoric acid - mercuric nitrate solution at SRP. Residual chloride was separated from the dissolver solution by precipitation with Hg 2 (NO 3 ) 2 followed by centrifuging. Plutonium was then separated from the aluminum, americium and magnesium using the Purex solvent extraction system. The 241 Am was diverted to the waste tank farm, but could be recovered if desired

  19. Characterization of solid residues from coal liquefaction processes. Phase I

    Energy Technology Data Exchange (ETDEWEB)

    Potter, J.; McDougall, W.M.; Kybett, B.D.; Neufeld, C.

    1981-01-01

    Various coal liquefaction and beneficiation processes are being investigated by independent research groups sponsored by the Canadian Federal Government. These processes include the co-processing of heavy oils and bitumen with coal, oxygen removal and hydrogenation of coal and supercritical gas extraction of coal. The end products, gaseous and liquid fuels and insoluble organic residues, vary with the experimental conditions. The physical properties and origin of the insoluble residue may influence such factors as degree of conversion, efficiency of the process, and ultimately, gaseous and liquid yields. One of the most suitable methods of assessing the nature of the insoluble residues is the use of petrography. This report deals with petrographic assessment of the coals and residues from various coal conversion processes; attempts were made to characterize the solid phases in the residues; to assess them in a quantitative manner and where possible; to correlate the results with experimental data; and to assess their effects on conversion. (30 refs.)

  20. Determination of properties of clean coal technology post-process residue

    Directory of Open Access Journals (Sweden)

    Agnieszka Klupa

    2016-01-01

    Full Text Available This article presents the possibilities of using modern measuring devices to determine the properties of process residues (Polish acronym: UPP. UPP was taken from the combustion process from a power plant in Silesia. Determining the properties of UPP is the basis for making decisions about its practical application, for example, as a raw material to obtain useful products such as: pozzolan, cenosphere or zeolite, for which there is demand. The development of advanced technology and science has given rise to modern and precise research tools that contribute to the development of appropriate methods to assess the properties of post-process residue. For this study the following were used: scanning electron microscope with EDS microanalysis and an analyzer for particle size-, shape- and number- analysis. The study conducted confirms the effectiveness of SEM analysis to determine the properties of post-process residue from Clean Coal Technologies (CCT. The results obtained are an introduction to further research on the determination of properties of CCT post-process residue. Research to determine the properties of CCT post-process residue only began relatively recently.

  1. Treatment and processing of residues of fermentation; Behandlung und Verwertung von Gaerrueckstaenden

    Energy Technology Data Exchange (ETDEWEB)

    Doehler, H.; Schliebner, P. [Kuratorium fuer Technik und Bauwesen in der Landwirtschaft (KTBL), Darmstadt (Germany)

    2007-07-01

    With the transformation of the EEG (Renewable Energy Resources Act), the number of biogas plants increased rapidly. Additionally, an enlargement of the performance of the plants and a regional concentration process take place. Recently, processing routes for liquid manure will be considered in order to reduce problems of the surplus of nutrients as well as the costs of the transport of the water-rich residues of fermentation. Under this aspect, the authors of the contribution under consideration report on procedures for the processing of residues of fermentation as well as costs and utilization of these procedures. By the example of an agrarian society, four procedures for the output and processing of residues of fermentation are compared with one another regarding to expenditure of work time, investments and economy: Output of residues of fermentation, treatment of residues of fermentation by separation, processing of residues of fermentation by means of diaphragm technology, processing of residues of fermentation by means of evaporation technology. The processing routes reduce the residues of fermentation by 60 %. Thus, the costs of output and the necessary storage capacities for residues of fermentation are reduced. Presently, no savings regarding to work completion by the processing of the residues of fermentation can be obtained. The specific total costs of the investigated procedures are between 2.64 Euro/m{sup 3} according to the procedure with separation and to 8.64 Euro/m{sup 3} according to the diaphragm processing route. An enhanced demand of investment does not cause compellingly the highest specific total costs of the procedures. In comparison to the output of residues of fermentation, the examined procedures for the processing of residues of fermentation do not result in economical and ergonomic advantages. The high costs of investment and operating cost of the processing of residues of fermentation cannot be compensated by the reduced costs of output

  2. Gold processing residue from Jacobina Basin: chemical and physical properties

    OpenAIRE

    Lima, Luiz Rogério Pinho de Andrade; Bernardez, Letícia Alonso; Barbosa, Luís Alberto Dantas

    2007-01-01

    p. 848-852 Gold processing residues or tailings are found in several areas in the Itapicuru River region (Bahia, Brazil), and previous studies indicated significant heavy metals content in the river sediments. The present work focused on an artisanal gold processing residue found in a site from this region. Samples were taken from the processing residue heaps and used to perform a physical and chemical characterization study using X-ray diffraction, scanning electron microscopy, neutron...

  3. Use of residual wood in the cement manufacturing process

    International Nuclear Information System (INIS)

    Gue, R.

    2005-01-01

    This PowerPoint presentation discussed the use of wood residuals in the cement manufacturing process. An outline of the cement manufacturing process was presented. Raw materials are combined in exact proportions to create a chemically correct mix, which is then pulverized in a mill. The mix is then burned in a kiln. The end product is cooled to form the pellet sized material known as clinker, which is then milled to form cement. The combustion and destruction characteristics of a cement kiln were presented. Modern cement kilns require approximately 3.2 Gj of energy to produce one tonne of cement. It was noted that wood residuals do not contain halogens, sulfur or other materials detrimental to the cement manufacturing process. Possible injection points for kilns were presented. Various studies have shown that wood residuals can be safely used as a fuel in the manufacture of cement. Environmental benefits derived from using wood included the complete destruction of organic portions, and the fact that residual ash becomes an indistinguishable part of the final product. It was concluded that wood residual materials are a satisfactory alternative fuel for the cement industry. tabs., figs

  4. Treatment of waste incinerator air-pollution-control residues with FeSO4: Laboratory investigation of design parameters

    DEFF Research Database (Denmark)

    Jensen, Dorthe Lærke; Christensen, Thomas Højlund; Lundtorp, Kasper

    2002-01-01

    supplied, the liquid-to-solid ratio of the process, the separation of solids and wastewater, the sequence of material mixing, the possibilities of reuse of water, the feasibility of using secondary (brackish) water, and simple means to improve the wastewater quality. The investigation showed...... that an optimum process configuration could be obtained yielding a stabilised solid product with low leaching of heavy metals and a dischargable wastewater with high contents of salts (in order to remove salts from the solid product) and low concentrations of heavy metals. The amount of iron added to the APC......The key design parameters of a new process for treatment of air-pollution-control (APC) residues (the Ferroxprocess) were investigated in the laboratory. The optimisation involved two different APC-residues from actual incinerator plants. The design parameters considered were: amount of iron oxide...

  5. Virtual Welded-Joint Design Integrating Advanced Materials and Processing Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Z.; Dong, P.; Liu, S.; Babu, S.; Olson, G.; DebRoy, T.

    2005-04-15

    The primary goal of this project is to increase the fatigue life of a welded-joint by 10 times and to reduce energy use by 25% through product performance and productivity improvements using an integrated modeling approach. The fatigue strength of a welded-joint is currently the bottleneck to design high performance and lightweight welded structures using advanced materials such as high strength steels. In order to achieve high fatigue strength in a welded-joint it is necessary to manage the weld bead shape for lower stress concentration, produce preferable residual stress distribution, and obtain the desired microstructure for improved material toughness and strength. This is a systems challenge that requires the optimization of the welding process, the welding consumable, the base material, as well as the structure design. The concept of virtual welded-joint design has been proposed and established in this project. The goal of virtual welded-joint design is to develop a thorough procedure to predict the relationship of welding process, microstructure, property, residual stress, and the ultimate weld fatigue strength by a systematic modeling approach. The systematic approach combines five sub-models: weld thermal-fluid model, weld microstructure model, weld material property model, weld residual stress model, and weld fatigue model. The systematic approach is thus based on interdisciplinary applied sciences including heat transfer, computational fluid dynamics, materials science, engineering mechanics, and material fracture mechanics. The sub-models are based on existing models with further development. The results from modeling have been validated with critical experiments. The systematic modeling approach has been used to design high fatigue resistant welds considering the combined effects of weld bead geometry, residual stress, microstructure, and material property. In particular, a special welding wire has been developed in this project to introduce

  6. Effects of food processing on pesticide residues in fruits and vegetables: a meta-analysis approach.

    Science.gov (United States)

    Keikotlhaile, B M; Spanoghe, P; Steurbaut, W

    2010-01-01

    Pesticides are widely used in food production to increase food security despite the fact that they can have negative health effects on consumers. Pesticide residues have been found in various fruits and vegetables; both raw and processed. One of the most common routes of pesticide exposure in consumers is via food consumption. Most foods are consumed after passing through various culinary and processing treatments. A few literature reviews have indicated the general trend of reduction or concentration of pesticide residues by certain methods of food processing for a particular active ingredient. However, no review has focused on combining the obtained results from different studies on different active ingredients with differences in experimental designs, analysts and analysis equipment. In this paper, we present a meta-analysis of response ratios as a possible method of combining and quantifying effects of food processing on pesticide residue levels. Reduction of residue levels was indicated by blanching, boiling, canning, frying, juicing, peeling and washing of fruits and vegetables with an average response ratio ranging from 0.10 to 0.82. Baking, boiling, canning and juicing indicated both reduction and increases for the 95% and 99.5% confidence intervals. Copyright 2009 Elsevier Ltd. All rights reserved.

  7. Residual Stress Evaluation of Weld Inlay Process on Reactor Vessel Nozzles

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Kihyun; Cho, Hong Seok [KEPCO KPS, Naju (Korea, Republic of)

    2015-10-15

    Weld overlay, weld inlay and stress improvement are mitigation technologies for butt joints. Weld overlay is done on pressurizer nozzles which are the highest potential locations occurring PWSCC due to high temperature in Korea. Reactor vessel nozzles are other big safety concerns for butt joints. Weld overlay and stress improvement should be so difficult to apply to those locations because space is too limited. Weld inlay should be one of the solutions. KEPCO KPS has developed laser welding system and process for reactor nozzles. Welding residual stress analysis is necessary for flaw evaluation. United States nuclear regulatory commission has calculated GTAW(Gas Tungsten Arc Welding) residual stress using ABAQUS. To confirm effectiveness of weld inlay process, welding residual stress analysis was performed. and difference between GTAW and LASER welding process was compared. Evaluation of weld inlay process using ANSYS and ABAQUS is performed. All of the both results are similar. The residual stress generated after weld inlay was on range of 450-500 MPa. Welding residual stresses are differently generated by GTAW and LASER welding. But regardless of welding process type, residual tensile stress is generated on inside surface.

  8. Use of residue from paper processing as secondary raw material

    International Nuclear Information System (INIS)

    Ernstbrunner, L.

    1994-01-01

    In recent years, the paper industry has been trying to dispose of paper residues by thermal processes in its own, very expensive, combustion plants. Since 1990, the Wopfing Cement Factory, Austria, has been using paper residues in a process for which a patent has now been applied, in a similar way to the method used for the combustion of car tyres in cement rotary kilns. 30.000 t/yr of paper residue is to be processed in Wopfing cement plant from 1995, coming from PWA Ortmann, which is part of a large German paper concern. (author). 4 schemata

  9. Food processing as a means for pesticide residue dissipation

    Directory of Open Access Journals (Sweden)

    Đorđević Tijana

    2016-01-01

    Full Text Available Pesticides are one of the major inputs used for increasing agricultural productivity of crops. However, their inadequate application may produce large quantities of residues in the environment and, once the environment is contaminated with pesticides, they may easily enter into the human food chain through plants, creating a potentially serious health hazard. Nowadays, consumers are becoming more aware of the importance of safe and high quality food products. Thus it is pertinent to explore simple, cost-effective strategies for decontaminating food from pesticides. Various food processing techniques, at industrial and/or domestical level, have been found to significantly reduce the contents of pesticide residues in most food materials. The extent of reduction varies with the nature of pesticides, type of commodity and processing steps. Pesticides, especially those with limited movement and penetration ability, can be removed with reasonable efficiency by washing, and the effectiveness of washing depends on pesticide solubility in water or in different chemical solvents. Peeling of fruit and vegetable skin can dislodge pesticide residues to varying degrees, depending on constitution of a commodity, chemical nature of the pesticide and environmental conditions. Different heat treatments (drying, pasteurization, sterilization, blanching, steaming, boiling, cooking, frying or roasting during various food preparation and preservation processes can cause losses of pesticide residues through evaporation, co-distillation and/or thermal degradation. Product manufactures, from the simplest grain milling, through oil extraction and processing, juicing/pureeing or canning of fruits and vegetables, to complex bakery and dairy production, malting and brewing, wine making and various fermentation processes, play a role in the reduction of pesticide contents, whereby each operation involved during processing usually adds to a cumulative effect of reduction of

  10. Study of the flash drying of the residue from soymilk processing - "okara"

    Directory of Open Access Journals (Sweden)

    Regina Kitagawa Grizotto

    2011-09-01

    Full Text Available The objective of this research project was to study the drying of soymilk residue in a pneumatic flash dryer, using response Surface Methodology (RSM, and to evaluate the quality of the dried residue. Soymilk residue, also known as okara, was provided by a Brazilian soymilk factory. RSM showed that for a 120 second drying cycle, the lower the residue moisture contents (y obtained, the higher the recirculation rates (x1, regardless of the air drying temperature (x2, and it could be expressed by the equation y = 7.072 - 7.92x1, with R² = 92,92%. It is possible to obtain okara with 10% of moisture (dwb under the condition x1=1.25, equivalent to RR = 61%, with air drying temperatures ranging from 252 °C to 308 °C. The dried okara obtained through Central Compound Rotational Design (CCRD presented a centesimal composition similar to the okara dried in a tray dryer, known as the original okara. There were significant variations (p < 0.05 in the Emulsifying Capacity (EC, Emulsion Stability (ES and Protein Solubility (PS between the dehydrated residues obtained. It was concluded that the flash drying of okara is technically feasible and that the physicochemical composition of the residue was not altered; on the contrary, the process promoted a positive effect on the technological functional properties.

  11. NUMERICAL SIMULATION OF RESIDUAL STRESSES GENERATED IN THE WIRE DRAWING PROCESS FOR DIFFERENT PROCESS PARAMETERS

    Directory of Open Access Journals (Sweden)

    Juliana Zottis

    2014-03-01

    Full Text Available The drawing process of steel bars is usually used to check better dimensional accuracy and mechanical properties to the material. In the other hand, the major concern found in manufacturing axes through this process is the appearance of distortion of shape. Such distortions are directly linked to the accumulation of residual stresses generated during the processes. As a result, this paper aims to study the influence of process parameters such as shape of puller, speed and lubrication used in wire drawing analyzing the accumulation of residual stress after the process. The stress analysis was performed by FEM being used two simulation software: Simufact.formingGP and DeformTM. Through these analyzes, it was found that the shape of how the bar is pulled causes a reduction of up to 100 MPa in residual stresses in the center of the bar, which represents an important factor in the study of the possible causes of the distortion. As well as factors speed and homogeneity of lubrication significantly altered the profile of residual stresses in the bar.

  12. Flexible process options for the immobilisation of residues and wastes containing plutonium

    International Nuclear Information System (INIS)

    Stewart, M.W.A.; Moricca, S.A.; Day, R. A.; Begg, B. D.; Scales, C. R.; Maddrell, E. R.; Eilbeck, A. B.

    2007-01-01

    Residues and waste streams containing plutonium present unique technical, safety, regulatory, security, and socio-political challenges. In the UK these streams range from lightly plutonium contaminated materials (PCM) through to residue s resulting directly from Pu processing operations. In addition there are potentially stocks of Pu oxide powders whose future designation may be either a waste or an asset, due to their levels of contamination making their reuse uneconomic, or to changes in nuclear policy. While waste management routes exist for PCM, an immobilisation process is required for streams containing higher levels of Pu. Such a process is being developed by Nexia Solutions and ANSTO to treat and immobilise Pu waste and residues currently stored on the Sellafield site. The characteristics of these Pu waste streams are highly variable. The physical form of the Pu waste ranges from liquids, sludges, powders/granules, to solid components (e.g., test fuels), with the Pu present as an ion in solution, as a salt, metal, oxide or other compound. The chemistry of the Pu waste streams also varies considerably with a variety of impurities present in many waste streams. Furthermore, with fissile isotopes present, criticality is an issue during operations and in the store or repository. Safeguards and security concerns must be assessed and controlled. The process under development, by using a combination of tailored waste form chemistry combined with flexible process technology aims to develop a process line to handle a broad range of Pu waste streams. It aims to be capable of dealing with not only current arisings but those anticipated to arise as a result of future operations or policy changes. (authors)

  13. Bioethanol production from corn stover residues. Process design and Life Cycle Assessment

    International Nuclear Information System (INIS)

    De Bari, I.; Dinnino, G.; Braccio, G.

    2008-01-01

    In this report, the mass and energy balance along with a land-to-wheel Life Cycle Assessment (LCA) is described for a corn stover-to-ethanol industrial process assumed to consist of the main technologies being researched at ENEA TRISAIA: pretreatment by steam explosion and enzymatic hydrolysis. The modelled plant has a processing capacity of 60kt/y (dimensioned on realistic supplying basins of residues in Italy); biomass is pre-treated by acid catalyzed-steam explosion; cellulose and hemicelluloses are hydrolyzed and separately fermented; enzymes are on-site produced. The main target was to minimize the consumption of fresh water, enzymes and energy. The results indicate that the production of 1kg bio ethanol (95.4 wt%) requires 3.5 kg biomass dry matter and produces an energy surplus up to 740 Wh. The main purpose of the LCA analysis was to assess the environmental impact of the entire life cycle from the bio ethanol production up to its end-use as E10 blended gasoline. Boustead Model was used as tool to compile the life cycle inventory. The results obtained and discussed in this reports suffer of some limitations deriving from the following main points: some process yields have been extrapolated according to optimistic development scenarios; the energy and steam recovery could be lower than that projected because of lacks in the real systems; water recycle could be limited by the yeast tolerance toward the potential accumulation of toxic compounds. Nevertheless, the detailed process analysis here provided has its usefulness in: showing the challenging targets (even if they are ambitious) to bet on to make the integrated process feasible; driving the choice of the most suitable technologies to bypass some process bottlenecks [it

  14. Comparative Analysis of Processes for Recovery of Rare Earths from Bauxite Residue

    Science.gov (United States)

    Borra, Chenna Rao; Blanpain, Bart; Pontikes, Yiannis; Binnemans, Koen; Van Gerven, Tom

    2016-11-01

    Environmental concerns and lack of space suggest that the management of bauxite residue needs to be re-adressed. The utilization of the residue has thus become a topic high on the agenda for both academia and industry, yet, up to date, it is only rarely used. Nonetheless, recovery of rare earth elements (REEs) with or without other metals from bauxite residue, and utilization of the left-over residue in other applications like building materials may be a viable alternative to storage. Hence, different processes developed by the authors for recovery of REEs and other metals from bauxite residue were compared. In this study, preliminary energy and cost analyses were carried out to assess the feasibility of the processes. These analyses show that the combination of alkali roasting-smelting-quenching-leaching is a promising process for the treatment of bauxite residue and that it is justified to study this process at a pilot scale.

  15. Mobis HRH process residue hydroconversion using a recoverable nano-catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Romocki, S.; Rhodey, G. [Mobis Energy Inc., Calgary, AB (Canada)

    2009-07-01

    This presentation described a newly developed pseudo-homogeneous catalyst (PHC) for hydroconversion of heavy hydrocarbon feeds with high levels of sulphur, nitrogen, resins, asphaltenes and metals. An active catalyst is formed in the reaction system, consisting of particles that are 2-9 nm in size and whose properties resemble those of a colloid solution at both room and reaction temperature. Residue processing with this pseudo-homogeneous catalyst system results in better cracking and hydrogenation at lower process severity. The PHC system in heavy residue hydroconversion (HRH) process achieves up to 95 per cent residue conversion at pressures below 7.3 MPa, reaction temperatures between 400 to 460 degrees C, and with feed space velocity between 1 to 2 per hour, thus rendering the PHC catalyst system suitable for deep conversion of hydrocarbon residues. As much as 95 per cent of the catalyst can be recovered and regenerated within the process. Pilot plants are in operation for the hydroconversion of Athabasca vacuum bottoms using this technology. The use of the HRH process in oilsands and refinery operations were discussed along with comparative yields and economics. tabs., figs.

  16. Utilization of protein-rich residues in biotechnological processes.

    Science.gov (United States)

    Pleissner, Daniel; Venus, Joachim

    2016-03-01

    A drawback of biotechnological processes, where microorganisms convert biomass constituents, such as starch, cellulose, hemicelluloses, lipids, and proteins, into wanted products, is the economic feasibility. Particularly the cost of nitrogen sources in biotechnological processes can make up a large fraction of total process expenses. To further develop the bioeconomy, it is of considerable interest to substitute cost-intensive by inexpensive nitrogen sources. The aim of this mini-review was to provide a comprehensive insight of utilization methods of protein-rich residues, such as fish waste, green biomass, hairs, and food waste. The methods described include (i) production of enzymes, (ii) recovery of bioactive compounds, and/or (iii) usage as nitrogen source for microorganisms in biotechnological processes. In this aspect, the utilization of protein-rich residues, which are conventionally considered as waste, allows the development of value-adding processes for the production of bioactive compounds, biomolecules, chemicals, and materials.

  17. Sustainability of compressive residual stress by stress improvement processes

    International Nuclear Information System (INIS)

    Nishikawa, Satoru; Okita, Shigeru; Yamaguchi, Atsunori

    2013-01-01

    Stress improvement processes are countermeasures against stress corrosion cracking in nuclear power plant components. It is necessary to confirm whether compressive residual stress induced by stress improvement processes can be sustained under operation environment. In order to evaluate stability of the compressive residual stress in 60-year operating conditions, the 0.07% cyclic strains of 200 times at 593 K were applied to the welded specimens, then a thermal aging treatment for 1.66x10 6 s at 673 K was carried out. As the result, it was confirmed that the compressive residual stresses were sustained on both surfaces of the dissimilar welds of austenitic stainless steel (SUS316L) and nickel base alloy (NCF600 and alloy 182) processed by laser peening (LP), water jet peening (WJP), ultrasonic shot peening (USP), shot peening (SP) and polishing under 60-year operating conditions. (author)

  18. Process and catalysis for hydrocracking of heavy oil and residues

    Energy Technology Data Exchange (ETDEWEB)

    Morel, F.; Kressmann, S. [Centre d' Etudes et de developpement Indutriel ' Rene Navarre' , Vernaison (France); Harle, V.; Kasztelan, S. [Division Cinetique et Catalyse, Rueil-Malmaison (France)

    1997-07-01

    Atmospheric or vacuum residue can be converted into valuable distillates using reaction temperature, high hydrogen pressure and low contact time hydroprocessing units. Various residue hydrocracking processes are now commercially employed using fixed bed, moving bed or ebullated bed reactors. The choice of process type depends mainly on the amount of metals and asphaltenes in the feed and on the level of conversion required. Various improvements have been introduced in the last decade to increase run length, conversion level, products qualities and stability of the residual fuel. These improvements include on stream catalysts replacement systems, swing reactors, improved feed distribution, guard bed materials limiting pressure drop, coke resistant catalysts, complex association of catalysts using particle size, activity and pore size grading. Further improvement of the resistance of catalysts to deactivation by coke and metal deposits and of the hydrodenitrogenation activity are two major challenges for the development of new residue hydrocracking catalysts and processes. 29 refs.

  19. The Effect of Processing on 14C- Chlofenvinphos Residues in Maize Oil and Bioavailability of its Cake Residues on Rats

    International Nuclear Information System (INIS)

    Mahdy, F.; El-Maghraby, S.

    2008-01-01

    Maize seed obtained from 14 C-chlofenvinphos treated plants contained 0.12 % of the applied dose. The insecticide residues in crude oil, methanol and coke amounted to 10 %, 6 % and 69 %, respectively of original residues inside the seeds.The 14 C activity in the crude oil could be a gradual reduced by the refining processes. The alkali treatment and bleaching steps are more effective steps in the refining processes remove about (63 %). The refined oil contained only about 17 % of the 14 C-residues originally present. The major residues in processed oil contain parent compound, in addition to five metabolites of the insecticide. When rats fed the extracted seeds (cake), the bound residues were found to be considerably bioavailable. After feeding rats for 5 days with the cake, a substantial amount of 14 C-residues was eliminated in the urine (59.5 %), while about 20 % was excreted in the feces. About 15 % of the radioactivity was distribution among various organs

  20. Effects of storage and processing on residue levels of chlorpyrifos in soybeans.

    Science.gov (United States)

    Zhao, Liuwei; Ge, Jing; Liu, Fengmao; Jiang, Naiwen

    2014-05-01

    The residue levels of chlorpyrifos in soybeans during storage and processing were investigated. Soybeans were treated with chlorpyrifos aqueous solution and placed in a sealed plastic container. The residue of chlorpyrifos was determined in soybeans at six time points within 0 and 112days during storage and oil processing of the soybeans was conducted. The analysis of the residues of chlorpyrifos was carried out by gas chromatography-mass spectrometry (GC-MS). Results show that the dissipation of chlorpyrifos in soybeans is about 62% during the storage period. Moreover, the carryover of the residues from soybeans into oil is found to be related to the processing methods. Processing factor, which is defined as the ratio of chlorpyrifos residue concentration in oil sample to that in the soybean samples, was 11 and 0.25 after cold and hot pressing, respectively. Copyright © 2013 Elsevier Ltd. All rights reserved.

  1. Radionuclides in Bayer process residues: previous analysis for radiological protection

    International Nuclear Information System (INIS)

    Cuccia, Valeria; Rocha, Zildete; Oliveira, Arno H. de

    2011-01-01

    Natural occurring radionuclides are present in many natural resources. Human activities may enhance concentrations of radionuclides and/or enhance potential of exposure to naturally occurring radioactive material (NORM). The industrial residues containing radionuclides have been receiving a considerable global attention, because of the large amounts of NORM containing wastes and the potential long term risks of long-lived radionuclides. Included in this global concern, this work focuses on the characterization of radioactivity in the main residues of Bayer process for alumina production: red mud and sand samples. Usually, the residues of Bayer process are named red mud, in their totality. However, in the industry where the samples were collected, there is an additional residues separation: sand and red mud. The analytical techniques used were gamma spectrometry (HPGe detector) and neutron activation analysis. The concentrations of radionuclides are higher in the red mud than in the sand. These solid residues present activities concentrations enhanced, when compared to bauxite. Further uses for the residues as building material must be more evaluated from the radiological point of view, due to its potential of radiological exposure enhancement, specially caused by radon emission. (author)

  2. Harvesting and handling agricultural residues for energy

    Energy Technology Data Exchange (ETDEWEB)

    Jenkins, B.M.; Summer, H.R.

    1986-05-01

    Significant progress in understanding the needs for design of agricultural residue collection and handling systems has been made but additional research is required. Recommendations are made for research to (a) integrate residue collection and handling systems into general agricultural practices through the development of multi-use equipment and total harvest systems; (b) improve methods for routine evaluation of agricultural residue resources, possibly through remote sensing and image processing; (c) analyze biomass properties to obtain detailed data relevant to engineering design and analysis; (d) evaluate long-term environmental, social, and agronomic impacts of residue collection; (e) develop improved equipment with higher capacities to reduce residue collection and handling costs, with emphasis on optimal design of complete systems including collection, transportation, processing, storage, and utilization; and (f) produce standard forms of biomass fuels or products to enhance material handling and expand biomass markets through improved reliability and automatic control of biomass conversion and other utilization systems. 118 references.

  3. Residual number processing in dyscalculia.

    Science.gov (United States)

    Cappelletti, Marinella; Price, Cathy J

    2014-01-01

    Developmental dyscalculia - a congenital learning disability in understanding numerical concepts - is typically associated with parietal lobe abnormality. However, people with dyscalculia often retain some residual numerical abilities, reported in studies that otherwise focused on abnormalities in the dyscalculic brain. Here we took a different perspective by focusing on brain regions that support residual number processing in dyscalculia. All participants accurately performed semantic and categorical colour-decision tasks with numerical and non-numerical stimuli, with adults with dyscalculia performing slower than controls in the number semantic tasks only. Structural imaging showed less grey-matter volume in the right parietal cortex in people with dyscalculia relative to controls. Functional MRI showed that accurate number semantic judgements were maintained by parietal and inferior frontal activations that were common to adults with dyscalculia and controls, with higher activation for participants with dyscalculia than controls in the right superior frontal cortex and the left inferior frontal sulcus. Enhanced activation in these frontal areas was driven by people with dyscalculia who made faster rather than slower numerical decisions; however, activation could not be accounted for by response times per se, because it was greater for fast relative to slow dyscalculics but not greater for fast controls relative to slow dyscalculics. In conclusion, our results reveal two frontal brain regions that support efficient number processing in dyscalculia.

  4. Residual number processing in dyscalculia

    Directory of Open Access Journals (Sweden)

    Marinella Cappelletti

    2014-01-01

    Full Text Available Developmental dyscalculia – a congenital learning disability in understanding numerical concepts – is typically associated with parietal lobe abnormality. However, people with dyscalculia often retain some residual numerical abilities, reported in studies that otherwise focused on abnormalities in the dyscalculic brain. Here we took a different perspective by focusing on brain regions that support residual number processing in dyscalculia. All participants accurately performed semantic and categorical colour-decision tasks with numerical and non-numerical stimuli, with adults with dyscalculia performing slower than controls in the number semantic tasks only. Structural imaging showed less grey-matter volume in the right parietal cortex in people with dyscalculia relative to controls. Functional MRI showed that accurate number semantic judgements were maintained by parietal and inferior frontal activations that were common to adults with dyscalculia and controls, with higher activation for participants with dyscalculia than controls in the right superior frontal cortex and the left inferior frontal sulcus. Enhanced activation in these frontal areas was driven by people with dyscalculia who made faster rather than slower numerical decisions; however, activation could not be accounted for by response times per se, because it was greater for fast relative to slow dyscalculics but not greater for fast controls relative to slow dyscalculics. In conclusion, our results reveal two frontal brain regions that support efficient number processing in dyscalculia.

  5. Residual number processing in dyscalculia☆

    Science.gov (United States)

    Cappelletti, Marinella; Price, Cathy J.

    2013-01-01

    Developmental dyscalculia – a congenital learning disability in understanding numerical concepts – is typically associated with parietal lobe abnormality. However, people with dyscalculia often retain some residual numerical abilities, reported in studies that otherwise focused on abnormalities in the dyscalculic brain. Here we took a different perspective by focusing on brain regions that support residual number processing in dyscalculia. All participants accurately performed semantic and categorical colour-decision tasks with numerical and non-numerical stimuli, with adults with dyscalculia performing slower than controls in the number semantic tasks only. Structural imaging showed less grey-matter volume in the right parietal cortex in people with dyscalculia relative to controls. Functional MRI showed that accurate number semantic judgements were maintained by parietal and inferior frontal activations that were common to adults with dyscalculia and controls, with higher activation for participants with dyscalculia than controls in the right superior frontal cortex and the left inferior frontal sulcus. Enhanced activation in these frontal areas was driven by people with dyscalculia who made faster rather than slower numerical decisions; however, activation could not be accounted for by response times per se, because it was greater for fast relative to slow dyscalculics but not greater for fast controls relative to slow dyscalculics. In conclusion, our results reveal two frontal brain regions that support efficient number processing in dyscalculia. PMID:24266008

  6. Cation exchange process for molten salt extraction residues

    International Nuclear Information System (INIS)

    Proctor, S.G.

    1975-01-01

    A new method, utilizing a cation exchange technique, has been developed for processing molten salt extraction (MSE) chloride salt residues. The developed ion exchange procedure has been used to separate americium and plutonium from gross quantities of magnesium, potassium, and sodium chloride that are present in the residues. The recovered plutonium and americium contained only 20 percent of the original amounts of magnesium, potassium, and sodium and were completely free of any detectable amounts of chloride impurity. (U.S.)

  7. Design and simulation of thermal residual stresses of coatings on WC-Co cemented carbide cutting tool substrate

    International Nuclear Information System (INIS)

    Li, Anhai; Zhao, Jun; Zang, Jian; Zheng, Wei

    2016-01-01

    Large thermal residual stresses in coatings during the coating deposition process may easily lead to coating delamination of coated carbide tools in machining. In order to reduce the possibility of coating delamination during the tool failure process, a theoretical method was proposed and a numerical method was constructed for the coating design of WC-Co cemented carbide cutting tools. The thermal residual stresses of multi-layered coatings were analytically modeled based on equivalent parameters of coating properties, and the stress distribution of coatings are simulated by Finite element method (FEM). The theoretically calculated results and the FEM simulated results were verified and in good agreement with the experimental test results. The effects of coating thickness, tool substrate, coating type and interlayer were investigated by the proposed geometric and FEM model. Based on the evaluations of matchability of tool substrate and tool coatings, the basic principles of tool coating design were proposed. This provides theoretical basis for the selection and design of coatings of cutting tools in high-speed machining

  8. Numerical simulation of residual stress in laser based additive manufacturing process

    Science.gov (United States)

    Kalyan Panda, Bibhu; Sahoo, Seshadev

    2018-03-01

    Minimizing the residual stress build-up in metal-based additive manufacturing plays a pivotal role in selecting a particular material and technique for making an industrial part. In beam-based additive manufacturing, although a great deal of effort has been made to minimize the residual stresses, it is still elusive how to do so by simply optimizing the processing parameters, such as beam size, beam power, and scan speed. Amid different types of additive manufacturing processes, Direct Metal Laser Sintering (DMLS) process uses a high-power laser to melt and sinter layers of metal powder. The rapid solidification and heat transfer on powder bed endows a high cooling rate which leads to the build-up of residual stresses, that will affect the mechanical properties of the build parts. In the present work, the authors develop a numerical thermo-mechanical model for the measurement of residual stress in the AlSi10Mg build samples by using finite element method. Transient temperature distribution in the powder bed was assessed using the coupled thermal to structural model. Subsequently, the residual stresses were estimated with varying laser power. From the simulation result, it found that the melt pool dimensions increase with increasing the laser power and the magnitude of residual stresses in the built part increases.

  9. Materials for Nuclear Plants From Safe Design to Residual Life Assessments

    CERN Document Server

    Hoffelner, Wolfgang

    2013-01-01

    The clamor for non-carbon dioxide emitting energy production has directly  impacted on the development of nuclear energy. As new nuclear plants are built, plans and designs are continually being developed to manage the range of challenging requirement and problems that nuclear plants face especially when managing the greatly increased operating temperatures, irradiation doses and extended design life spans. Materials for Nuclear Plants: From Safe Design to Residual Life Assessments  provides a comprehensive treatment of the structural materials for nuclear power plants with emphasis on advanced design concepts.   Materials for Nuclear Plants: From Safe Design to Residual Life Assessments approaches structural materials with a systemic approach. Important components and materials currently in use as well as those which can be considered in future designs are detailed, whilst the damage mechanisms responsible for plant ageing are discussed and explained. Methodologies for materials characterization, material...

  10. Process for measuring residual stresses

    International Nuclear Information System (INIS)

    Elfinger, F.X.; Peiter, A.; Theiner, W.A.; Stuecker, E.

    1982-01-01

    No single process can at present solve all problems. The complete destructive processes only have a limited field of application, as the component cannot be reused. However, they are essential for the basic determination of stress distributions in the field of research and development. Destructive and non-destructive processes are mainly used if investigations have to be carried out on original components. With increasing component size, the part of destructive tests becomes smaller. The main applications are: quality assurance, testing of manufactured parts and characteristics of components. Among the non-destructive test procedures, X-raying has been developed most. It gives residual stresses on the surface and on surface layers near the edges. Further development is desirable - in assessment - in measuring techniques. Ultrasonic and magnetic crack detection processes are at present mainly used in research and development, and also in quality assurance. Because of the variable depth of penetration and the possibility of automation they are gaining in importance. (orig./RW) [de

  11. Process induced residual stresses and distortions in pultrusion

    DEFF Research Database (Denmark)

    Baran, Ismet; Tutum, Cem Celal; Nielsen, Michael Wenani

    2013-01-01

    In the present study, a coupled 3D transient Eulerian thermo-chemical analysis together with a 2D plane strain Lagrangian mechanical analysis of the pultrusion process, which has not been considered until now, is carried out. The development of the process induced residual stresses and strains...... together with the distortions are predicted during the pultrusion in which the cure hardening instantaneous linear elastic (CHILE) approach is implemented. At the end of the process, tension stresses prevail for the inner region of the composite since the curing rate is higher here as compared to the outer...... regions where compression stresses are obtained. The separation between the heating die and the part due to shrinkage is also investigated using a mechanical contact formulation at the die-part interface. The proposed approach is found to be efficient and fast for the calculation of the residual stresses...

  12. Process solutions for reducing PR residue over non-planar wafer

    Science.gov (United States)

    Lin, C. H.; Huang, C. H.; Yang, Elvis; Yang, T. H.; Chen, K. C.; Lu, Chih-Yuan

    2011-03-01

    SAS (Self-Aligned Source) process has been widely adopted on manufacturing NOR Flash devices. To form the SAS structure, the compromise between small space patterning and sufficiently removing photo resist residue in topographical substrate has been a critical challenge as the device scaling down. In this study, photo simulation, layout optimization, resist processing and tri-layer materials were evaluated to form defect-free and highly extendible SAS structure for NOR Flash devices. Photo simulation suggested more coherent light source allowed the incident light to reach the trench bottom that facilitates the removal of photo resist. Mask bias also benefited the process latitude extension for residue-free SAS printing. In the photo resist processing, both lowering the SB (Soft Bake) and raising PEB (Post-Exposure Bake) temperature of photo resist were helpful to broaden the process window but the final pattern profile was not good enough. Thermal flow for pos-exposure pattern shrinkage achieved small CD (Critical Dimension) patterning with residue-free, however the materials loading effect is another issue to be addressed at memory array boundary. Tri-layer scheme demonstrated good results in terms of free from residue, better substrate reflectivity control, enabling smaller space printing to loosen overlay specification and minimizing the poly gate clipping defect. It was finally proposed to combine with etch effort to from the SAS structure. Besides it is also promising to extend to even smaller technology nodes.

  13. 3D reconstruction of the structure of a residual limb for customising the design of a prosthetic socket.

    Science.gov (United States)

    Shuxian, Zheng; Wanhua, Zhao; Bingheng, Lu

    2005-01-01

    Aiming at overcoming the limitations of the plaster-casting method in traditional prosthetic socket fabrication, the idea of reconstructing the 3D models for bones and skin of the residual limb is proposed. Given the two-dimensional obtained image through CT scanning, using image processing and reverse engineering techniques, the 3D solid model of the residual limb can be successfully reconstructed. The new approach can reproduce both the internal and the external structure of the residual limb. It can moreover avoid making a positive mould by the way of manual modifications. In addition to this, it can provide a scientific basis for the individualization of prosthetic socket design.

  14. Anaerobic digestion of microalgae residues resulting from the biodiesel production process

    International Nuclear Information System (INIS)

    Ehimen, E.A.; Sun, Z.F.; Carrington, C.G.; Birch, E.J.; Eaton-Rye, J.J.

    2011-01-01

    The recovery of methane from post transesterified microalgae residues has the potential to improve the renewability of the 'microalgae biomass to biodiesel' conversion process as well as reduce its cost and environmental impact. This paper deals with the anaerobic digestion of microalgae biomass residues (post transesterification) using semi-continuously fed reactors. The influence of substrate loading concentrations and hydraulic retention times on the specific methane yield of the anaerobically digested microalgae residues was investigated. The co-digestion of the microalgae residues with glycerol as well as the influence of temperature was also examined. It was found that the hydraulic retention period was the most significant variable affecting methane production from the residues, with periods (>5 days) corresponding to higher energy recovery. The methane yield was also improved by a reduction in the substrate loading rates, with an optimum substrate carbon to nitrogen ratio of 12.44 seen to be required for the digestion process.

  15. 40 CFR 63.494 - Back-end process provisions-residual organic HAP limitations.

    Science.gov (United States)

    2010-07-01

    ... organic HAP limitations. 63.494 Section 63.494 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... § 63.494 Back-end process provisions—residual organic HAP limitations. (a) The monthly weighted average residual organic HAP content of all grades of elastomer processed, measured after the stripping operation...

  16. Residual stress evaluation and curvature behavior of aluminium 7050 peen forming processed

    International Nuclear Information System (INIS)

    Oliveira, R.R. de; Lima, N.B.; Braga, A.P.V.; Goncalves, M.

    2010-01-01

    Shot peening is a superficial cold work process used to increase the fatigue life evaluated by residual stress measurements. The peen forming process is a variant of the shot peening process, where a curvature in the plate is obtained by the compression of the grains near to the surface. In this paper, the influence of the parameters such as: pressure of shot, ball shot size and thickness of aluminum 7050 samples with respect to residual stress profile and resulting arc height was studied. The evaluation of the residual stress profile was obtained by sin 2 Ψ method. (author)

  17. Magnetic separation as a plutonium residue enrichment process

    International Nuclear Information System (INIS)

    Avens, L.R.; Gallegos, U.F.; McFarlan, J.T.

    1990-01-01

    Several plutonium contaminated residues have been subjected to Open Gradient Magnetic Separation (OGMS) on an experimental scale. OGMS experiments on graphite and bomb reduction residues resulted in a plutonium rich fraction and a plutonium lean fraction. Values for the bulk quantity rejected to the lean fraction varied between about 20% to 85% of the feed bulk. The plutonium content of the lean fraction can be reduced from about 2% in the feed to the 0.1% to 0.5% range dependent on the portion of the feed rejected to this lean fraction. These values are low enough in plutonium to meet economic discard limits and be considered for direct discard. Magnetic separation of pyrochemical salts gave less favorable results. While a fraction very rich in plutonium could be obtained, the lean fraction plutonium content was too high for direct discard. This may still have chemical processing applications. OGMS experiments at low magnetic field strength on incinerator ash did give two fractions but the plutonium content of each fraction was essentially identical. Thus, no chemical processing advantage was identified for magnetic separation of this residue. 6 refs., 1 fig., 9 tabs

  18. Modification of bauxite residue generated in the Bayer process by thermal treatment

    International Nuclear Information System (INIS)

    Garcia, M.C.S.; Pileggi, R.G.; John, V.M.; Gouvea, D.

    2011-01-01

    Red mud is the waste generated by the aluminum industry, and as other industrial waste presents complex characteristics with numerous difficulties in handling, as well as being a hazardous material due to its low granulometry, alkalinity and high amount generated. It is a waste with potential high polluter, aggravated by the generally adopted vulnerable disposal form, being this, the disposition of the residue in ponds designed for this purpose. The study and development of sustainable alternatives for the use of sludge, treated as raw materials from other processes, are important tendency and necessary trends in the global context of environmental preservation. This work deals with the thermal treatment as a method of modification of the characteristics of the residue, suggesting the reduction of alkalinity together with the lower leaching of alkaline ions. This approach can be a more reliable and environmentally safe disposal alternatives

  19. A novel process for heavy residue hydroconversion using a recoverable pseudo-homogenous catalyst PHC system

    Energy Technology Data Exchange (ETDEWEB)

    Romocki, S.M.; Rhodey, W.G. [Mobis Energy Inc., Calgary, AB (Canada)

    2008-10-15

    This paper described a pseudo-homogenous catalyst (PHC) designed to refine heavy hydrocarbon residues containing sulfur, nitrogen, metals, and asphaltene impurities known to clog pores and deactivate traditional hydrocrackers. The heavy residue hydroconversion (HRH) process incorporated a single particle, chemically generated PHC uniformly distributed in the feed. Thermal decomposition within the reaction system of a water-in-oil emulsion containing ammonium paramolybdate was used to form molybdenum oxide, which was then sulfided within the feed in order to create an ultra-dispersed suspension of catalytically active molybdenum disulfide particles measuring between 2 and 9 nm. A proprietary online catalyst recovery and regeneration step was used to maintain high catalyst activity. The molybdenum was then recovered from a purge stream and then reintroduced to the catalyst preparation area as a catalyst precursor. After being conditioned, the feed was combined with hydrogen and a water-oil catalyst emulsion and introduced into a furnace. Heavy components were cracked, hydrogenated and converted to lighter products. The high performance catalyst system was able to convert 95 per cent of residues at pressures below 7.3 Mpa and at reaction temperatures ranging between 400 and 460 degrees C. The catalyst was tested at a pilot plant using Athabasca vacuum bottoms. It was concluded that the HRH process is now being successfully used to produce 200 barrels of heavy oil per day. Designs for commercial installations are now being prepared. 4 refs., 2 tabs., 2 figs.

  20. Effect of process variables on the Drucker-Prager cap model and residual stress distribution of tablets estimated by the finite element method.

    Science.gov (United States)

    Hayashi, Yoshihiro; Otoguro, Saori; Miura, Takahiro; Onuki, Yoshinori; Obata, Yasuko; Takayama, Kozo

    2014-01-01

    A multivariate statistical technique was applied to clarify the causal correlation between variables in the manufacturing process and the residual stress distribution of tablets. Theophylline tablets were prepared according to a Box-Behnken design using the wet granulation method. Water amounts (X1), kneading time (X2), lubricant-mixing time (X3), and compression force (X4) were selected as design variables. The Drucker-Prager cap (DPC) model was selected as the method for modeling the mechanical behavior of pharmaceutical powders. Simulation parameters, such as Young's modulus, Poisson rate, internal friction angle, plastic deformation parameters, and initial density of the powder, were measured. Multiple regression analysis demonstrated that the simulation parameters were significantly affected by process variables. The constructed DPC models were fed into the analysis using the finite element method (FEM), and the mechanical behavior of pharmaceutical powders during the tableting process was analyzed using the FEM. The results of this analysis revealed that the residual stress distribution of tablets increased with increasing X4. Moreover, an interaction between X2 and X3 also had an effect on shear and the x-axial residual stress of tablets. Bayesian network analysis revealed causal relationships between the process variables, simulation parameters, residual stress distribution, and pharmaceutical responses of tablets. These results demonstrated the potential of the FEM as a tool to help improve our understanding of the residual stress of tablets and to optimize process variables, which not only affect tablet characteristics, but also are risks of causing tableting problems.

  1. Pesticide residues in grapes, wine, and their processing products.

    Science.gov (United States)

    Cabras, P; Angioni, A

    2000-04-01

    In this review the results obtained in the 1990s from research on the behavior of pesticide residues on grapes, from treatment to harvest, and their fate in drying, wine-making, and alcoholic beverage processing are reported. The fungicide residues on grapes (cyproconazole, hexaconazole, kresoxim-methyl, myclobutanil, penconazole, tetraconazole, and triadimenol), the application rates of which were of a few tens of grams per hectare, were very low after treatment and were not detectable at harvest. Pyrimethanil residues were constant up to harvest, whereas fluazinam, cyprodinil, mepanipyrim, azoxystrobin, and fludioxonil showed different disappearance rates (t(1/2) = 4.3, 12, 12.8, 15.2, and 24 days, respectively). The decay rate of the organophosphorus insecticides was very fast with t(1/2) ranging between 0.97 and 3.84 days. The drying process determined a fruit concentration of 4 times. Despite this, the residue levels of benalaxyl, phosalone, metalaxyl, and procymidone on sun-dried grapes equalled those on the fresh grape, whereas they were higher for iprodione (1.6 times) and lower for vinclozolin and dimethoate (one-third and one-fifth, respectively). In the oven-drying process, benalaxyl, metalaxyl, and vinclozolin showed the same residue value in the fresh and dried fruit, whereas iprodione and procymidone resides were lower in raisins than in the fresh fruit. The wine-making process begins with the pressing of grapes. From this moment onward, because the pesticide on the grape surface comes into contact with the must, it is in a biphasic system, made up of a liquid phase (the must) and a solid phase (cake and lees), and will be apportioned between the two phases. The new fungicides have shown no effect on alcoholic or malolactic fermentation. In some cases the presence of pesticides has also stimulated the yeasts, especially Kloeckera apiculata, to produce more alcohol. After fermentation, pesticide residues in wine were always smaller than those on the

  2. Aqueous electrochemical mechanisms in actinide residue processing. 1998 annual progress report

    International Nuclear Information System (INIS)

    Blanchard, D.L. Jr.; Burns, C.J.; Morris, D.E.; Smith, W.H.

    1998-01-01

    'New and/or improved solutions to the stabilization and volume reduction of nuclear materials processing residues are urgently needed. Mediated electrochemical oxidation/reduction (MEO/R) processes are one such approach for incinerator ash, combustibles, and other solid residues. However, questions remain concerning the mechanisms of these processes, and how they might be optimized. In addition, further research is merited to extend their range of applicability. Recent advances in the study of heterogeneous electron transfer in solid substrates have opened the door for the re-examination of electron transfer processes associated with redox mediated actinide dissolution. The authors develop a deeper understanding of the thermodynamic and mechanistic aspects of heterogeneous electron transfer that lie at the heart of these MEO/R processes. They will also develop and test new approaches based on the results of these fundamental studies using actual residue materials. Key aspects of this proposal include: (1) determination of the potential windows for oxidation/reduction of colloidal actinide oxides and actinide-bearing oxide and organic substrates and the e transfer kinetic parameters that govern the current--overpotential characteristics; (2) development of adaptations of mediation schemes and application of co-mediation reagents for oxidative and reductive dissolution based on complexation of the surface-bound or solid-phase actinides and/or the dissolved redox mediator;and (3) execution of bench-scale tests of new MEO/R schemes on actual residue materials.'

  3. Residual stresses generated in F-522 steel by different machining processes

    International Nuclear Information System (INIS)

    Gracia-Navas, V.; Ferreres, I.; Maranon, J. A.; Garcia-Rosales, C.; Gil-Sevillano, J.

    2005-01-01

    Machining operations induce plastic deformation and heat generation in the near surface area of the machined part, giving rise to residual stresses. Depending on their magnitude and sign, these stresses can be detrimental or beneficial to the service life of the part. The final stress state depends on the machining process applied, as well as on the machining parameters. Therefore, the establishment of adequate machining guidelines requires the measurement of the residual stresses generated both at the surface and inside the material. in this work, the residual stresses generated in F-522 steel by two hard turning (conventional and laser assisted) and two grinding (production and finishing) processes were measured by X-ray diffraction. Additionally, depth profiles of the volume fraction of retained austenite, microstructure and nano hardness were obtained in order to correlate those results with the residual stress state obtained for each machining process. It has been observed that turning generates tensile stresses in the surface while grinding causes compressive stresses. Below the surface grinding generates weak tensile or nearly null stresses whereas turning generates strong compressive stresses. These results show that the optimum mechanising process (disregarding economical considerations) implies the combination of turning plus elimination of a small thickness by final grinding. (Author) 19 refs

  4. Analysis of residual stress state in sheet metal parts processed by single point incremental forming

    Science.gov (United States)

    Maaß, F.; Gies, S.; Dobecki, M.; Brömmelhoff, K.; Tekkaya, A. E.; Reimers, W.

    2018-05-01

    The mechanical properties of formed metal components are highly affected by the prevailing residual stress state. A selective induction of residual compressive stresses in the component, can improve the product properties such as the fatigue strength. By means of single point incremental forming (SPIF), the residual stress state can be influenced by adjusting the process parameters during the manufacturing process. To achieve a fundamental understanding of the residual stress formation caused by the SPIF process, a valid numerical process model is essential. Within the scope of this paper the significance of kinematic hardening effects on the determined residual stress state is presented based on numerical simulations. The effect of the unclamping step after the manufacturing process is also analyzed. An average deviation of the residual stress amplitudes in the clamped and unclamped condition of 18 % reveals, that the unclamping step needs to be considered to reach a high numerical prediction quality.

  5. Automatic residue removal for high-NA extreme illumination

    Science.gov (United States)

    Moon, James; Nam, Byong-Sub; Jeong, Joo-Hong; Kong, Dong-Ho; Nam, Byung-Ho; Yim, Dong Gyu

    2007-10-01

    An epidemic for smaller node has been that, as the device architecture shrinks, lithography process requires high Numerical Aperture (NA), and extreme illumination system. This, in turn, creates many lithography problems such as low lithography process margin (Depth of Focus, Exposure Latitude), unstable Critical Dimension (CD) uniformity and restricted guideline for device design rule and so on. Especially for high NA, extreme illumination such as immersion illumination systems, above all the related problems, restricted design rule due to forbidden pitch is critical and crucial issue. This forbidden pitch is composed of numerous optical effects but majority of these forbidden pitch compose of photo resist residue and these residue must be removed to relieve some room for already tight design rule. In this study, we propose automated algorithm to remove photo resist residue due to high NA and extreme illumination condition. This algorithm automatically self assembles assist patterns based on the original design layout, therefore insuring the safety and simplicity of the generated assist pattern to the original design and removes any resist residue created by extreme illumination condition. Also we tested our automated algorithm on full chip FLASH memory device and showed the residue removal effect by using commercial verification tools as well as on actual test wafer.

  6. Treatment of plutonium process residues by molten salt oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J. [Los Alamos National Lab., NM (United States); Heslop, M. [Naval Surface Warfare Center (United States). Indian Head Div.; Wernly, K. [Molten Salt Oxidation Corp. (United States)

    1999-04-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

  7. Treatment of plutonium process residues by molten salt oxidation

    International Nuclear Information System (INIS)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J.; Heslop, M.

    1999-01-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible 238 Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na 2 SO 4 , Na 3 PO 4 and NaAsO 2 or Na 3 AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the 238 Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox

  8. The LOMOsup(R) process: a solution for residual monomers

    International Nuclear Information System (INIS)

    Derbyshire, R.L.

    1979-01-01

    Regulatory activity over the last several years has addressed the potential problems associated with the migration of residual monomers from a number of commodity food packages. Regardless of the outcome of current debates, it will always be desirable to reduce monomer levels to as low a level as economically practicable so that they do not become indirect additives. The LOMO process is a body of technology inclusive of an ionizing radiation treatment which can result in sharp reduction of residual monomer levels in commodity plastic resins. The process may be applicable to factory intermediates, raw resins, or finished articles. Depending upon the individual system and its monomers, LOMO treatment can result in reductions to levels which press today's analytical test capability. Industrial radiation processing is normally accomplished with electron beam accelerators. Electron beam processing continues to gain in understanding and acceptance as one of the very few basic methods by which energy can be imparted to an industrial process system. Typically, whole factories are constructed around one accelerator. (author)

  9. Safeguards By Design - As applied to the Sellafield Product and Residue Store (SPRS)

    Energy Technology Data Exchange (ETDEWEB)

    Chare, Peter; Lahogue, Yves; Schwalbach, Peter; Smejkal, Andreas; Patel, Bharat [European Commission, Directorate-General for Energy, Directorate E - Nuclear Safeguards, Euroforum, Luxembourg (Luxembourg)

    2011-12-15

    Sellafield Product and Residue Store (SPRS) is a new facility that has been constructed on the site of Sellafield. The design work started in early 2001 and active commissioning commenced with the introduction of the first nuclear material which arrived in the building early 2011. The store has been designed for the long term storage of Plutonium product (PuO2) from Thorp and Magnox, MOX residue powder from Sellafield MOX Plant (SMP) as well as pellet, powder or granular PuO2 residues from the older stores on the Sellafield site. This paper describes the application of Safeguards By Design commencing at the early design stage based upon the Safeguards Approach to be applied by DG ENER at the Sellafield Product and Residue Store (SPRS). The approach had been developed based upon the requirements for implementing Commission Regulation 302(2005) and the technical measures to be implemented in order to meet Article 77(a) of the Euratom Treaty. In order to meet these requirements a close dialogue was established between the different interested parties and the design team for the installation of instrumentation with associated cabling in order to implement the agreed safeguards measures. Early contacts at the design stage facilitated the inclusion of installed safeguards supplied instrumentation into the overall design and facility construction. The equipment and cabling supplied by Euratom was incorporated into the planning and construction phases. This ensured that upon plant completion the safeguards tools were commissioned and ready for the verification of the first nuclear material to be introduced into SPRS. Detailed discussions at the early stages of the design phase raised the profile of nuclear material safeguards and made certain that the necessary instrumentation infrastructure was incorporated into the plant infrastructure.

  10. Process to recycle shredder residue

    Science.gov (United States)

    Jody, Bassam J.; Daniels, Edward J.; Bonsignore, Patrick V.

    2001-01-01

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  11. Residualization Rates of Near Infrared Dyes for the Rational Design of Molecular Imaging Agents

    Science.gov (United States)

    Cilliers, Cornelius; Liao, Jianshan; Atangcho, Lydia; Thurber, Greg M.

    2016-01-01

    Purpose Near infrared (NIR) fluorescence imaging is widely used for tracking antibodies and biomolecules in vivo. Clinical and preclinical applications include intraoperative imaging, tracking therapeutics, and fluorescent labeling as a surrogate for subsequent radiolabeling. Despite their extensive use, one of the fundamental properties of NIR dyes, the residualization rate within cells following internalization, has not been systematically studied. This rate is required for the rational design of probes and proper interpretation of in vivo results. Procedures In this brief report, we measure the cellular residualization rate of eight commonly used dyes encompassing three core structures (cyanine, BODIPY, and oxazine/thiazine/carbopyronin). Results We identify residualizing (half-life > 24 hrs) and non-residualizing dyes (half-life < 24 hrs) in both the far red (~650-680 nm) and near infrared (~740-800 nm) regions. Conclusions This data will allow researchers to independently and rationally select the wavelength and residualizing nature of dyes for molecular imaging agent design. PMID:25869081

  12. Residualization Rates of Near-Infrared Dyes for the Rational Design of Molecular Imaging Agents.

    Science.gov (United States)

    Cilliers, Cornelius; Liao, Jianshan; Atangcho, Lydia; Thurber, Greg M

    2015-12-01

    Near-infrared (NIR) fluorescence imaging is widely used for tracking antibodies and biomolecules in vivo. Clinical and preclinical applications include intraoperative imaging, tracking therapeutics, and fluorescent labeling as a surrogate for subsequent radiolabeling. Despite their extensive use, one of the fundamental properties of NIR dyes, the residualization rate within cells following internalization, has not been systematically studied. This rate is required for the rational design of probes and proper interpretation of in vivo results. In this brief report, we measure the cellular residualization rate of eight commonly used dyes encompassing three core structures (cyanine, boron-dipyrromethene (BODIPY), and oxazine/thiazine/carbopyronin). We identify residualizing (half-life >24 h) and non-residualizing (half-life <24 h) dyes in both the far-red (~650-680 nm) and near-infrared (~740-800 nm) regions. This data will allow researchers to independently and rationally select the wavelength and residualizing nature of dyes for molecular imaging agent design.

  13. Effects of processing treatment on pesticide residues in fruits and their products

    International Nuclear Information System (INIS)

    Mao Xuefei; Jiao Bining; Fu Chenmei; Qian Yongzhong; Wang Jing

    2008-01-01

    The influence of processing treatments on pesticide residues in fruits and their products was reviewed. The effects on pesticide residues and relative control treatments for each processing step, including peeling, washing, sterilization, juicing, clarification, filtration, drying and fermentation, were discussed, respectively. Meanwhile we analyzed the future development prospectin of this field, in order to provide some suggestions for commercial fruit industry and consumers' health. (authors)

  14. Sedimentation process and design of settling systems

    CERN Document Server

    De, Alak

    2017-01-01

    This book is designed to serve as a comprehensive source of information of sedimentation processes and design of settling systems, especially as applied to design of such systems in civil and environmental engineering. The book begins with an introduction to sedimentation as a whole and goes on to cover the development and details of various settling theories. The book traces the chronological developments of the comprehensive knowledge of settling studies and design of settling systems from 1889.A new concept of 'Velocity Profile Theorem', tool for settling problem analysis, has been employed to the analysis of the phenomenon of short circuiting. Complete theory of tube settling has been developed and its application to the computation of residual solids from the assorted solids through the same has been demonstrated. Experimental verification of the tube settling theory has also been presented. Field-oriented compatible design and operation methodology of settling system has been developed from the detailed...

  15. The effect of commercial processing procedures on 14C-carbendazim residues in soybean oil and tomato

    International Nuclear Information System (INIS)

    Peng Genyuan; Wang Huaguo; Qi Mengwen; Wang Fujun; Zhou Changjiu

    1994-01-01

    Under simulated agricultural practices, soybean plants were treated with 14 C-labelled carbendazim during the blooming stage. The residue in seeds was determined to be 0.067 ppm; corresponding to 0.076 ppm respectively. After subjecting the oil to degumming, alkali treatment, bleaching and deodorization, 53.7% of original radioactivity was removed. Deodorization was the most effect process, removing about 20% of the residue. The concentration of residues in the deodorized oil decreased about 30%. In soybean seed and cake, the residue was mainly present as carbendazim, the concentration of the other metabolites did not exceed 30% of the residue. Tomatoes grown on a field plot were treated with 14 C-carbendazim. After harvest, the tomatoes were processed into tomato juice and canned whole fruit. The magnitude and nature of residues in samples taken at several processing steps were determined to evaluate the effect of commercial processing on removing or eliminating the residues. The results showed that the surface residues on tomato would be removed efficiently by simple washing of tomato. A buffer solution of phosphate had the highest efficiency. Tomato juice contained lower residues than canned whole fruit

  16. Effect of paste processing on residue levels of imidacloprid, pyraclostrobin, azoxystrobin and fipronil in winter jujube.

    Science.gov (United States)

    Peng, Wei; Zhao, Liuwei; Liu, Fengmao; Xue, Jiaying; Li, Huichen; Shi, Kaiwei

    2014-01-01

    The changes of imidacloprid, pyraclostrobin, azoxystrobin and fipronil residues were studied to investigate the carryover of pesticide residues in winter jujube during paste processing. A multi-residue analytical method for winter jujube was developed based on the QuEChERS approach. The recoveries for the pesticides were between 87.5% and 116.2%. LODs ranged from 0.002 to 0.1 mg kg(-1). The processing factor (Pf) is defined as the ratio of pesticide residue concentration in the paste to that in winter jujube. Pf was higher than 1 for the removal of extra water, and other steps were generally less than 1, indicating that the whole process resulted in lower pesticide residue levels in paste. Peeling would be the critical step for pesticide removal. Processing factors varied among different pesticides studied. The results are useful to address optimisation of the processing techniques in a manner that leads to considerable pesticide residue reduction.

  17. Conceptual design of heterogeneous azeotropic distillation process for ethanol dehydration using 1-butanol as entrainer

    Directory of Open Access Journals (Sweden)

    Paritta Prayoonyong

    2014-12-01

    Full Text Available The synthesis of a heterogeneous azeotropic distillation process for ethanol dehydration using 1-butanol as entrainer is presented. The residue curve map of the ethanol/water/1-butanol mixture is computationally generated using non-random twoliquid thermodynamic model. It is found that 1-butanol leads to a residue curve map topological structure different from that generated by typical entrainers used in ethanol dehydration. Synthesised by residue curve map analysis, the distillation flowsheet for ethanol dehydration by 1-butanol comprises a double-feed column integrated with an overhead decanter and a simple column. The double-feed column is used to recover water as the top product, whereas the simple column is used for recovering ethanol and 1-butanol. The separation feasibility and the economically near-optimal designs of distillation columns in the flowsheet are evaluated and identified by using the boundary value design method. The distillation flowsheet using 1-butanol is compared with the conventional process using benzene as entrainer. Based on their total annualised costs, the ethanol dehydration process using 1-butanol is less economically attractive than the process using benzene. However, 1-butanol is less toxic than benzene.

  18. Modeling of the fatigue damage accumulation processes in the material of NPP design units under thermomechanical unstationary effects. Estimation of spent life and forecast of residual life

    International Nuclear Information System (INIS)

    Kiriushin, A.I.; Korotkikh, Yu.G.; Gorodov, G.F.

    2002-01-01

    Full text: The estimation problems of spent life and forecast of residual life of NPP equipment design units, operated at unstationary thermal force loads are considered. These loads are, as a rule, unregular and cause rotation of main stress tensor platforms of the most loaded zones of structural elements and viscoelastic plastic deformation of material in the places of stresses concentrations. The existing engineering approaches to the damages accumulation processes calculation in the material of structural units, their advantages and disadvantages are analyzed. For the processes of fatigue damages accumulation a model is proposed, which allows to take into account the unregular pattern of deformation multiaxiality of stressed state, rotation of main platforms, non-linear summation of damages at the loading mode change. The model in based on the equations of damaged medium mechanics, including the equations of viscoplastic deformation of the material and evolutionary equations of damages accumulation. The algorithms of spent life estimation and residual life forecast of the controlled equipment and systems zones are made on the bases of the given model by the known real history of loading, which is determined by real model of NPP operation. The results of numerical experiments on the basis of given model for various processes of thermal force loads and their comparison with experimental results are presented. (author)

  19. Different strategies for recovering metals from CARON process residue

    International Nuclear Information System (INIS)

    Cabrera, G.; Gomez, J.M.; Hernandez, I.; Coto, O.; Cantero, D.

    2011-01-01

    The capacity of Acidithiobacillus thiooxidans DMS 11478 to recover the heavy metals contained in the residue obtained from the CARON process has been evaluated. Different bioreactor configurations were studied: a two-stage batch system and two semi-continuous systems (stirred-tank reactor leaching and column leaching). In the two-stage system, 46.8% Co, 36.0% Mg, 26.3% Mn and 22.3% Ni were solubilised after 6 h of contact between the residue and the bacteria-free bioacid. The results obtained with the stirred-tank reactor and the column were similar: 50% of the Mg and Co and 40% of the Mn and Ni were solubilised after thirty one days. The operation in the column reactor allowed the solid-liquid ratio to be increased and the pH to be kept at low values (<1.0). Recirculation of the leachate in the column had a positive effect on metal removal; at sixty five days (optimum time) the solubilisation levels were as follows: 86% Co, 83% Mg, 72% Mn and Ni, 62% Fe and 23% Cr. The results corroborate the feasibility of the systems studied for the leaching of metals from CARON process residue and these methodologies can be considered viable for the recovery of valuable metals.

  20. An open-loop system design for deep space signal processing applications

    Science.gov (United States)

    Tang, Jifei; Xia, Lanhua; Mahapatra, Rabi

    2018-06-01

    A novel open-loop system design with high performance is proposed for space positioning and navigation signal processing. Divided by functions, the system has four modules, bandwidth selectable data recorder, narrowband signal analyzer, time-delay difference of arrival estimator and ANFIS supplement processor. A hardware-software co-design approach is made to accelerate computing capability and improve system efficiency. Embedded with the proposed signal processing algorithms, the designed system is capable of handling tasks with high accuracy over long period of continuous measurements. The experiment results show the Doppler frequency tracking root mean square error during 3 h observation is 0.0128 Hz, while the TDOA residue analysis in correlation power spectrum is 0.1166 rad.

  1. Advanced new technologies for residue upgrading

    International Nuclear Information System (INIS)

    Gillis, D.

    1997-01-01

    Viewgraphs summarizing UOP technologies for residue are provided. The upgrading technologies include: (1) Aquaconversion, (2) the Discriminatory Destructive Distillation process (3D), and (3) the RCD uniflex process. The Aquaconversion process is based on catalytic hydrovisbreaking. It makes use of a homogeneous (liquid phase) catalyst. The hydrogen is derived from water. The advantages of this process are improved residue stability and quality at higher conversion levels, high synthetic crude yields, low operational complexity, reduced transportation costs. The 3D process is a unique carbon rejection contaminant removal process which can process whole crudes through viscous residues. FCC type equipment is used. Performance characteristics and advantages of the process were highlighted. The RCD uniflex process makes use of proven fixed bed and ebullated bed technologies in a new process configuration in which the fixed bed system is located upstream of the ebullated bed system. In this process, the catalyst volume increases exponentially with increasing processing severity. Performance characteristics, design features, benefits and development progress to date are described. 1 tab., 21 figs

  2. Efficiency of the refining processes in removing 14C-dichlorvos residues in soybean oil

    International Nuclear Information System (INIS)

    Soliman, S.M.

    2006-01-01

    Crude soybean oil extracted from grains treated with 14 C-dichlorvos at a dose 24 mg insecticide / kg seeds and stored for 30 weeks was subjected to different refining processes such as alkali treatment, bleaching, winterization and deodorization. The effect of the refining processes on the nature and magnitude of the originally present residues was investigated. The insecticide residues in crude oil and cake amounted to 9.5% and 55% , respectively, of original residues inside the seeds. Extraction of the seeds with hexane gave crude oil with 9.5 % of original residues in seeds. The l4 C-activity in the crude stored Soya beans oil could be reduced by about 82% of radioactivity originally present in crude oil eliminated by simulated commercial processes locally used for oil refining. A high percentage of the residues (50-55%) were eliminated during alkali treatment and bleaching. Refining of soybeans oil fortified with '1 4 C-dichlorovos. The final refined oil had only 13% of the radioactivity originally present, mainly in the form of dichlorvos, dimethyl and monomethyl phosphate in addition to desmethyl dichlorvos in oil with aged residues

  3. Residual stress evaluation and curvature behavior of aluminium 7050 peen forming processed; Avaliacao da tensao residual em aluminio 7050 conformado pelo processo peen forming

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, R.R. de; Lima, N.B., E-mail: rolivier@ipen.b, E-mail: nblima@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Braga, A.P.V.; Goncalves, M., E-mail: anapaola@ipt.b, E-mail: mgoncalves@ipt.b [Instituto de Pesquisas Tecnologicas (IPT), Sao Paulo, SP (Brazil)

    2010-07-01

    Shot peening is a superficial cold work process used to increase the fatigue life evaluated by residual stress measurements. The peen forming process is a variant of the shot peening process, where a curvature in the plate is obtained by the compression of the grains near to the surface. In this paper, the influence of the parameters such as: pressure of shot, ball shot size and thickness of aluminum 7050 samples with respect to residual stress profile and resulting arc height was studied. The evaluation of the residual stress profile was obtained by sin{sup 2} {Psi} method. (author)

  4. Effect of processing on residues of chlorpyrifos in stored corn and rice

    International Nuclear Information System (INIS)

    Tejada, A.W.; Calumpang, S.M.F.; Gambalan, N.B.

    1990-01-01

    The effect of processing on residues of chlorpyrifos in rice and corn was determined. Chlorpyrifos solution (0.1%) sprayed on jute sacks containing corn resulted in absorption of residues in kernel and cob up to six months. A similar trend was observed in rice. Radiotracer studies revealed very low levels of bound residues (0.2 - 0.8 mg/kg) present in rice only. The usual practice of washing rice and corn before cooking reduced chlorpyrifos residues as much as 57% to 100%. Residues in wash water declined with each washing. Cooking further reduced the residues of chlorpyrifos only when volatilization was possible. Chlorpyrifos appeared to be persistent. Cooking rice in plot with the lid on did not produce any substantial reduction in the chlorpyrifos content. The practice of storing rice and corn in the Philippines does not give rice to chlorpyrifos residues which may exceed the recommended daily intake of 0.01 mg/kg-bw. (Auth.) 13 refs., 12 tabs., 3 figs

  5. Novel use of residue from direct coal liquefaction process

    Energy Technology Data Exchange (ETDEWEB)

    Jianli Yang; Zhaixia Wang; Zhenyu Liu; Yuzhen Zhang [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion

    2009-09-15

    Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA), a superior commercial modifier. Asphalts modified by two DCLRs meet the specifications of ASTM D5710 and BSI BS-3690 designated for the TLA-modified asphalts. The required addition amount for the DCLRs tested is less than that for TLA due possibly to the high content of asphaltene in DCLRs. Different compatibility was observed for the asphalts with the same penetration grade but from the different origin. Different components in the DCLR play different roles in the modification. Positive synergetic effects among the fractions were observed, which may due to the formation of the stable colloid structure. Unlike polymer-type modifier, the structure of asphalt-type modifier has a similarity with petroleum asphalts which favors the formation of a stable dispersed polar fluid (DPF) colloid structure and improves the performance of pavement asphalt. 12 refs., 1 fig., 6 tabs.

  6. Waste vinegar residue as substrate for phytase production.

    Science.gov (United States)

    Wang, Zhi-Hong; Dong, Xiao-Fang; Zhang, Guo-Qing; Tong, Jian-Ming; Zhang, Qi; Xu, Shang-Zhong

    2011-12-01

    Waste vinegar residue, the by-product of vinegar processing, was used as substrate for phytase production from Aspergillus ficuum NTG-23 in solid-state fermentation to investigate the potential for the efficient re-utilization or recycling of waste vinegar residue. Statistical designs were applied in the processing of phytase production. First, a Plackett-Burman (PB) design was used to evaluate eleven parameters: glucose, starch, wheat bran, (NH(4))(2)SO(4), NH(4)NO(3), tryptone, soybean meal, MgSO(4)·7H(2)O, CaCl(2)·7H(2)O, FeSO(4)·7H(2)O, incubation time. The PB experiments showed that there were three significant factors: glucose, soybean meal and incubation time. The closest values to the optimum point were then derived by steepest ascent path. Finally, a mathematical model was created and validated to explain the behavioural process after these three significant factors were optimized using response surface methodology (RSM). The best phytase activity was attained using the following conditions: glucose (7.2%), soybean meal (5.1%), and incubation time (271 h). The phytase activity was 7.34-fold higher due to optimization by PB design, steepest ascent path design and RSM. The phytase activity was enhanced 0.26-fold in comparison with the results by the second step of steepest ascent path design. The results indicate that with waste vinegar residue as a substrate higher production of phytase from Aspergillus ficuum NTG-23 could be obtained through an optimization process and that this method might be applied to an integrated system for recycling of the waste vinegar residue.

  7. The effect of commercial processing procedures on {sup 14}C-carbendazim residues in soybean oil and tomato

    Energy Technology Data Exchange (ETDEWEB)

    Genyuan, Peng; Huaguo, Wang; Mengwen, Qi; Fujun, Wang; Changjiu, Zhou [Laboratory for the Application of Nuclear Techniques, Beijing Agricultural University, Beijing (China)

    1994-06-01

    Under simulated agricultural practices, soybean plants were treated with {sup 14}C-labelled carbendazim during the blooming stage. The residue in seeds was determined to be 0.067 ppm; corresponding to 0.076 ppm respectively. After subjecting the oil to degumming, alkali treatment, bleaching and deodorization, 53.7% of original radioactivity was removed. Deodorization was the most effect process, removing about 20% of the residue. The concentration of residues in the deodorized oil decreased about 30%. In soybean seed and cake, the residue was mainly present as carbendazim, the concentration of the other metabolites did not exceed 30% of the residue. Tomatoes grown on a field plot were treated with {sup 14}C-carbendazim. After harvest, the tomatoes were processed into tomato juice and canned whole fruit. The magnitude and nature of residues in samples taken at several processing steps were determined to evaluate the effect of commercial processing on removing or eliminating the residues. The results showed that the surface residues on tomato would be removed efficiently by simple washing of tomato. A buffer solution of phosphate had the highest efficiency. Tomato juice contained lower residues than canned whole fruit.

  8. Yields from pyrolysis of refinery residue using a batch process

    Directory of Open Access Journals (Sweden)

    S. Prithiraj

    2017-12-01

    Full Text Available Batch pyrolysis was a valuable process of assessing the potential of recovering and characterising products from hazardous waste materials. This research explored the pyrolysis of hydrocarbon-rich refinery residue, from crude oil processes, in a 1200 L electrically-heated batch retort. Furthermore, the off-gases produced were easily processed in compliance with existing regulatory emission standards. The methodology offers a novel, cost-effective and environmentally compliant method of assessing recovery potential of valuable products. The pyrolysis experiments yielded significant oil (70% with high calorific value (40 MJ/kg, char (14% with carbon content over 80% and non-condensable gas (6% with significant calorific value (240 kJ/mol. The final gas stream was subjected to an oxidative clean-up process with continuous on-line monitoring demonstrating compliance with South African emission standards. The gas treatment was overall economically optimal as only a smaller portion of the original residue was subjected to emission-controlling steps. Keywords: Batch pyrolysis, Volatiles, Oil yields, Char, Emissions, Oil recovery

  9. Residual stress characterization of welds using x-ray diffraction techniques

    International Nuclear Information System (INIS)

    Pineault, J.A.; Brauss, M.E.

    1996-01-01

    Neglect of residual stresses created during processes lead to stress corrosion cracking, distortion, fatigue cracking, premature failures in components, and instances of over design. Automated residual stress mapping and truly portable equipment have now made the characterization of residual stresses using x-ray diffraction (XRI) practical. The nondestructive nature of the x-ray diffraction technique has made the tile residual stress characterization of welds a useful tool for process optimization and failure analysis, particularly since components can be measured before and after welding and post welding processes. This paper illustrates the importance of residual stress characterization in welds and presents examples where x-ray diffraction techniques were applied in the characterization of various kinds of welds. arc welds, TIG welds, resistance welds, laser welds and electron beam welds. Numerous techniques are available to help manage potentially harmfull residual stresses created during the welding process thus, the effects of a few example post weld processes such as grinding, heat treating and shot peening are also addressed

  10. Repairing an installation and processing the residues

    International Nuclear Information System (INIS)

    Malet, J.C.; Duverger de Cuy, G.; Sophy, Y.; Cucinotta, A.

    1989-01-01

    After a sodium leak in a locale, producing a fire, the operator's first concern is to repair the plant. Since the residual sodium and the products of combustion are chemically aggressive, the personnel will have to perform this operation in a hostile environment. This paper presents answers which can be given to the three questions which will however rise: When can the intervention begin? How will it be performed? What should be done with the residues of combustion? This document aims at presenting the different solutions to this problem, these solutions being derived from experiments carried out in France either in the Esmeralda Programme, which is managed jointly by CEA and ENEA, or in the other French programmes. As a general rule, the intervention inside the locale can be made much more easier if: it was foreseen right from the beginning of the design (access under the pipes, anchorage for handling, etc.); the incident can have been localised thanks to the monitoring of locales, enabling the video recording of the first instants, that is, as long as visibility does not fall to zero due to the aerosols from the fire. (author)

  11. Optimization of a pharmaceutical freeze-dried product and its process using an experimental design approach and innovative process analyzers.

    Science.gov (United States)

    De Beer, T R M; Wiggenhorn, M; Hawe, A; Kasper, J C; Almeida, A; Quinten, T; Friess, W; Winter, G; Vervaet, C; Remon, J P

    2011-02-15

    The aim of the present study was to examine the possibilities/advantages of using recently introduced in-line spectroscopic process analyzers (Raman, NIR and plasma emission spectroscopy), within well-designed experiments, for the optimization of a pharmaceutical formulation and its freeze-drying process. The formulation under investigation was a mannitol (crystalline bulking agent)-sucrose (lyo- and cryoprotector) excipient system. The effects of two formulation variables (mannitol/sucrose ratio and amount of NaCl) and three process variables (freezing rate, annealing temperature and secondary drying temperature) upon several critical process and product responses (onset and duration of ice crystallization, onset and duration of mannitol crystallization, duration of primary drying, residual moisture content and amount of mannitol hemi-hydrate in end product) were examined using a design of experiments (DOE) methodology. A 2-level fractional factorial design (2(5-1)=16 experiments+3 center points=19 experiments) was employed. All experiments were monitored in-line using Raman, NIR and plasma emission spectroscopy, which supply continuous process and product information during freeze-drying. Off-line X-ray powder diffraction analysis and Karl-Fisher titration were performed to determine the morphology and residual moisture content of the end product, respectively. In first instance, the results showed that - besides the previous described findings in De Beer et al., Anal. Chem. 81 (2009) 7639-7649 - Raman and NIR spectroscopy are able to monitor the product behavior throughout the complete annealing step during freeze-drying. The DOE approach allowed predicting the optimum combination of process and formulation parameters leading to the desired responses. Applying a mannitol/sucrose ratio of 4, without adding NaCl and processing the formulation without an annealing step, using a freezing rate of 0.9°C/min and a secondary drying temperature of 40°C resulted in

  12. Effects on residual stresses of aluminum alloy LC4 by laser shock processing

    Science.gov (United States)

    Zhang, Yong-kang; Lu, Jin-zhong; Kong, De-jun; Yao, Hui-xue; Yang, Chao-jun

    2007-12-01

    The influences of processing parameters on laser-induced shock waves in metal components are discussed and analyzed. The effects of different parameters of laser shock processing (LSP) on residual stress of aerospace aluminum alloy LC4 were investigated. LSP was performed by using an Nd: glass phosphate laser with 23 ns pulse width and up to ~45 J pulse energy at power densities above GW/mm -2. Special attention is paid to the residual stresses from laser shock processing. Modification of microstructure, surface morphology by laser shock processing is also discussed. Results to date indicate that laser shock processing has great potential as a means of improving the mechanical performance of components.

  13. PRODUCTION OF PASSION FRUIT SEEDLINGS WITH THE RESIDUE OF AGROINDUSTRIAL PROCESSING OF POTATOES AS A STRATEGY IN THE SUSTAINABILITY OF AGRICULTURAL FAMILY ACTIVITY

    Directory of Open Access Journals (Sweden)

    Leonardo Humberto Silva e Castro

    2012-12-01

    Full Text Available In order to contribute to family farming sustainable development and to the environmental management of the residue generated from potato processing by the company "Bem Brasil Alimentos LTDA" from Araxa, Minas Gerais, Brazil, an experiment was conducted at the Experimental Farm of Araxa (FEAX - EPAMIG between February to April of 2012, aiming to analyze passion fruit seedlings development from the use of different doses of this residue such as substrate, to reduce costs of raw materials. The experiment was conducted in randomized block design with six treatments, four repetitions and 20 plants per plot, being the treatments, blends of soil (latosol with levels of 10%, 20% and 30% of potato processing residue associated to chemical treatment and a witness. After 70 days of sowing, the height of air part (cm, root length (cm, number of leaves and total dry matter (g were evaluated. The best treatment was the M4 which used latosol + chemical treatment + 20% of residue. It was diagnosed that the use of agroindustrial potato processing residue, as part of the substrate, is a favorable alternative for passion fruit seedlings development. Thus, it gives a destination to this residue instead of discarding it into the environment, as well as decreases the costs of raw material that permit its correct ecological use, besides generating more income for family farmers.

  14. Residual stress evaluation and curvature behavior of aluminum 7050 peen forming processed

    International Nuclear Information System (INIS)

    Oliveira, Rene Ramos de

    2011-01-01

    Shot peening is a superficial cold work process used to increase the fatigue life evaluated by residual stress measurements. The peen forming process is a variant of the shot peening process, where a curvature in the plate is obtained by the compression of the grains near to the surface. In this paper, the influence of the parameters such as: pressure of shot, ball shot size and thickness of aluminum 7050 samples with respect to residual stress profile and resulting arc height was studied. The evaluation of the residual stress profile was obtained by sin 2 ψ method. The results show that the formation of the curvature arc height is proportional to the shot peening pressure, of spheres size and inversely proportional to the thickness of the sample, and that stress concentration factor is larger for samples shot peened with small balls. On final of this paper presents an additional study on micro strain and average crystallite size, which can evaluate the profile of the samples after blasting. (author)

  15. Disposal of residue from uranium ore processing in France

    International Nuclear Information System (INIS)

    Crochon, Ph.

    2011-01-01

    Between 1949 and 2001, French mines produced 76, 000 metric tons of uranium and 50 million metric tons of ore, processing residues are stored at 17 sites (in ponds enclosed by dykes or in former open-cast mines) subject to ICPE (classified facility for environment protection) regulation. These disposal sites cover surface areas of between one and several tens of hectares and several thousands to several millions of metric tons of waste are stored at them. When uranium mining stopped in France, these sites were redeveloped, with caps placed over the residue to provide mechanical and radiological protection. All these sites are still monitored by AREVA. In the last fifteen years, these sites have been the subject of a number of studies, especially regarding the long-term evolution and impact of the residue. These studies are now being pursued within the framework of the national plan for the management of nuclear materials and waste (PNGMDR). A regulatory and institutional framework regarding long-term management of these disposal sites needs to be defined. (author)

  16. Removal of azo dye using Fenton and Fenton-like processes: Evaluation of process factors by Box-Behnken design and ecotoxicity tests.

    Science.gov (United States)

    Fernandes, Neemias Cintra; Brito, Lara Barroso; Costa, Gessyca Gonçalves; Taveira, Stephânia Fleury; Cunha-Filho, Marcílio Sérgio Soares; Oliveira, Gisele Augusto Rodrigues; Marreto, Ricardo Neves

    2018-06-06

    The conventional treatment of textile effluents is usually inefficient in removing azo dyes and can even generate more toxic products than the original dyes. The aim of the present study was to optimize the process factors in the degradation of Disperse Red 343 by Fenton and Fenton-like processes, as well as to investigate the ecotoxicity of the samples treated under optimized conditions. A Box-Behnken design integrated with the desirability function was used to optimize dye degradation, the amount of residual H 2 O 2 [H 2 O 2residual ], and the ecotoxicity of the treated samples (lettuce seed, Artemia salina, and zebrafish in their early-life stages). Dye degradation was affected only by catalyst concentration [Fe] in both the Fenton and Fenton-like processes. In the Fenton reaction, [H 2 O 2residual ] was significantly affected by initial [H 2 O 2 ] and its interaction with [Fe]; however, in the Fenton-like reaction, it was affected by initial [H 2 O 2 ] only. A. salina mortality was affected by different process factors in both processes, which suggests the formation of different toxic products in each process. The desirability function was applied to determine the best process parameters and predict the responses, which were confirmed experimentally. Optimal conditions facilitated the complete degradation of the dye without [H 2 O 2residual ] or toxicity for samples treated with the Fenton-like process, whereas the Fenton process induced significant mortality for A. salina. Results indicate that the Fenton-like process is superior to the Fenton reaction to degrade Disperse Red 343. Copyright © 2018 Elsevier B.V. All rights reserved.

  17. Carbaryl residues in maize and processed products

    International Nuclear Information System (INIS)

    Qureshi, M.J.; Sattar, A. Jr.; Naqvi, M.H.

    1981-01-01

    Carbaryl residues in two local maize varieties were determined using a colorimetric method. No significant differences were observed for residues of the two varieties which ranged between 12.0 to 13.75 mg/kg in the crude oil, and averaged 1.04 and 0.67 mg/kg in the flour and cake respectively. In whole maize plants, carbaryl residues declined to approximately 2 mg/kg 35 days after treatment. Cooking in aqueous, oil or aqueous-oil media led to 63-83% loss of carbaryl residues, after 30 minutes. (author)

  18. Orientation-dependent backbone-only residue pair scoring functions for fixed backbone protein design

    Directory of Open Access Journals (Sweden)

    Bordner Andrew J

    2010-04-01

    Full Text Available Abstract Background Empirical scoring functions have proven useful in protein structure modeling. Most such scoring functions depend on protein side chain conformations. However, backbone-only scoring functions do not require computationally intensive structure optimization and so are well suited to protein design, which requires fast score evaluation. Furthermore, scoring functions that account for the distinctive relative position and orientation preferences of residue pairs are expected to be more accurate than those that depend only on the separation distance. Results Residue pair scoring functions for fixed backbone protein design were derived using only backbone geometry. Unlike previous studies that used spherical harmonics to fit 2D angular distributions, Gaussian Mixture Models were used to fit the full 3D (position only and 6D (position and orientation distributions of residue pairs. The performance of the 1D (residue separation only, 3D, and 6D scoring functions were compared by their ability to identify correct threading solutions for a non-redundant benchmark set of protein backbone structures. The threading accuracy was found to steadily increase with increasing dimension, with the 6D scoring function achieving the highest accuracy. Furthermore, the 3D and 6D scoring functions were shown to outperform side chain-dependent empirical potentials from three other studies. Next, two computational methods that take advantage of the speed and pairwise form of these new backbone-only scoring functions were investigated. The first is a procedure that exploits available sequence data by averaging scores over threading solutions for homologs. This was evaluated by applying it to the challenging problem of identifying interacting transmembrane alpha-helices and found to further improve prediction accuracy. The second is a protein design method for determining the optimal sequence for a backbone structure by applying Belief Propagation

  19. An in-depth analysis of the physico-mechanical properties imparted by agricultural fibers and food processing residues in polypropylene biocomposites

    Science.gov (United States)

    Murdy, Rachel Campbell; Mak, Michelle; Misra, Manjusri; Mohanty, Amar K.

    2015-05-01

    The use of agricultural and food processing residues as potential reinforcements in plastics has been extensively studied. However, there is a large variation in the mechanical performance of agricultural fiber-based biocomposites due to different processing materials and parameters. An in-depth comparison of the resulting effect of the agricultural filler on the matrix is often not possible given the discrepancy in processing conditions. This study seeks to determine the intrinsic properties of agricultural fibers and food processing residues for their use in polypropylene biocomposites based on a standardization of experimental design. The effect of 25wt% loading of miscanthus, fall-and spring-harvest switchgrass, wheat straw, oat hull, soy hull, soy stalk, hemp and flax on the physico-mechanical properties of polypropylene biocomposites was investigated. The addition of fiber led to an improvement in flexural strength, flexural modulus, and tensile modulus, and a general decrease in tensile strength at yield, elongation at break and Izod impact strength. Scanning electron microscopy highlighted the interfacial adhesion, orientation and distribution of the fibers within the matrix, confirming that fiber length and dispersion within the matrix are positively correlated with mechanical properties. The crystallization of the polypropylene phase and a compositional analysis of the agricultural fibers and processing residues were also compared to offer insight into the effect of the filler's intrinsic properties on the resulting material performance.

  20. An in-depth analysis of the physico-mechanical properties imparted by agricultural fibers and food processing residues in polypropylene biocomposites

    International Nuclear Information System (INIS)

    Murdy, Rachel Campbell; Mak, Michelle; Misra, Manjusri; Mohanty, Amar K.

    2015-01-01

    The use of agricultural and food processing residues as potential reinforcements in plastics has been extensively studied. However, there is a large variation in the mechanical performance of agricultural fiber-based biocomposites due to different processing materials and parameters. An in-depth comparison of the resulting effect of the agricultural filler on the matrix is often not possible given the discrepancy in processing conditions. This study seeks to determine the intrinsic properties of agricultural fibers and food processing residues for their use in polypropylene biocomposites based on a standardization of experimental design. The effect of 25wt% loading of miscanthus, fall-and spring-harvest switchgrass, wheat straw, oat hull, soy hull, soy stalk, hemp and flax on the physico-mechanical properties of polypropylene biocomposites was investigated. The addition of fiber led to an improvement in flexural strength, flexural modulus, and tensile modulus, and a general decrease in tensile strength at yield, elongation at break and Izod impact strength. Scanning electron microscopy highlighted the interfacial adhesion, orientation and distribution of the fibers within the matrix, confirming that fiber length and dispersion within the matrix are positively correlated with mechanical properties. The crystallization of the polypropylene phase and a compositional analysis of the agricultural fibers and processing residues were also compared to offer insight into the effect of the filler’s intrinsic properties on the resulting material performance

  1. An in-depth analysis of the physico-mechanical properties imparted by agricultural fibers and food processing residues in polypropylene biocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Murdy, Rachel Campbell; Mak, Michelle [Bioproducts Discovery and Development Centre, Department of Plant Agriculture, Crop Science Building, University of Guelph, Guelph, ON N1G 2W1 (Canada); Misra, Manjusri; Mohanty, Amar K. [Bioproducts Discovery and Development Centre, Department of Plant Agriculture, Crop Science Building, University of Guelph, Guelph, ON N1G 2W1 (Canada); School of Engineering, Thornbrough Building, University of Guelph, ON N1G 2W1 (Canada)

    2015-05-22

    The use of agricultural and food processing residues as potential reinforcements in plastics has been extensively studied. However, there is a large variation in the mechanical performance of agricultural fiber-based biocomposites due to different processing materials and parameters. An in-depth comparison of the resulting effect of the agricultural filler on the matrix is often not possible given the discrepancy in processing conditions. This study seeks to determine the intrinsic properties of agricultural fibers and food processing residues for their use in polypropylene biocomposites based on a standardization of experimental design. The effect of 25wt% loading of miscanthus, fall-and spring-harvest switchgrass, wheat straw, oat hull, soy hull, soy stalk, hemp and flax on the physico-mechanical properties of polypropylene biocomposites was investigated. The addition of fiber led to an improvement in flexural strength, flexural modulus, and tensile modulus, and a general decrease in tensile strength at yield, elongation at break and Izod impact strength. Scanning electron microscopy highlighted the interfacial adhesion, orientation and distribution of the fibers within the matrix, confirming that fiber length and dispersion within the matrix are positively correlated with mechanical properties. The crystallization of the polypropylene phase and a compositional analysis of the agricultural fibers and processing residues were also compared to offer insight into the effect of the filler’s intrinsic properties on the resulting material performance.

  2. Variation behavior of residual stress distribution by manufacturing processes in welded pipes of austenitic stainless steel

    International Nuclear Information System (INIS)

    Ihara, Ryohei; Hashimoto, Tadafumi; Mochizuki, Masahito

    2012-01-01

    Stress corrosion cracking (SCC) has been observed near heat affected zone (HAZ) of primary loop recirculation pipes made of low-carbon austenitic stainless steel type 316L in the nuclear power plants. For the non-sensitization material, residual stress is the important factor of SCC, and it is generated by machining and welding. In the actual plants, welding is conducted after machining as manufacturing processes of welded pipes. It could be considered that residual stress generated by machining is varied by welding as a posterior process. This paper presents residual stress variation due to manufacturing processes of pipes using X-ray diffraction method. Residual stress distribution due to welding after machining had a local maximum stress in HAZ. Moreover, this value was higher than residual stress generated by welding or machining. Vickers hardness also had a local maximum hardness in HAZ. In order to clarify hardness variation, crystal orientation analysis with EBSD method was performed. Recovery and recrystallization were occurred by welding heat near the weld metal. These lead hardness decrease. The local maximum region showed no microstructure evolution. In this region, machined layer was remained. Therefore, the local maximum hardness was generated at machined layer. The local maximum stress was caused by the superposition effect of residual stress distributions due to machining and welding. Moreover, these local maximum residual stress and hardness are exceeded critical value of SCC initiation. In order to clarify the effect of residual stress on SCC initiation, evaluation including manufacturing processes is important. (author)

  3. A Design of Portable Pesticide Residue Detection System Based on the Enzyme Electrode

    Directory of Open Access Journals (Sweden)

    Xia SUN

    2013-03-01

    Full Text Available In this paper, a portable detection system was designed based on amperometric acetylcholinesterase biosensor for rapidly detecting pesticide residues in fruits and vegetables. There were potentiostat, three electrode system, differential amplification circuit and double integral analog to digital (A/D circuit modules in this system. The measurement principle of this system was depended on the weak current from enzyme catalyzing substrate in acetylcholinesterase biosensor for detecting pesticide residues. The weak current generated by the enzyme biosensor was changed into 0-5 V standard voltage signal by this system as an output signal. The proposed system was investigated with eight kinds of standard pesticide of different concentrations, the results showed that the detection limits were all lower than 10 ng/kg. Thus, a new effective home-made system of detecting pesticide residues with portable, easy-to-use, fast response was developed. The pesticide residues rapid detection system can collect the weak current signal generated by electrochemical reaction and on-site detect the concentration of pesticide residues in real fruits and vegetables samples.

  4. The effect of initial stress induced during the steel manufacturing process on the welding residual stress in multi-pass butt welding

    Directory of Open Access Journals (Sweden)

    Jeong-ung Park

    2018-03-01

    Full Text Available A residual stress generated in the steel structure is broadly categorized into initial residual stress during manufacturing steel material, welding residual stress caused by welding, and heat treatment residual stress by heat treatment. Initial residual stresses induced during the manufacturing process is combined with welding residual stress or heat treatment residual stress, and remained as a final residual stress. Because such final residual stress affects the safety and strength of the structure, it is of utmost importance to measure or predict the magnitude of residual stress, and to apply this point on the design of the structure. In this study, the initial residual stress of steel structures having thicknesses of 25 mm and 70 mm during manufacturing was measured in order to investigate initial residual stress (hereinafter, referred to as initial stress. In addition, thermal elastic plastic FEM analysis was performed with this initial condition, and the effect of initial stress on the welding residual stress was investigated. Further, the reliability of the FE analysis result, considering the initial stress and welding residual stress for the steel structures having two thicknesses, was validated by comparing it with the measured results. In the vicinity of the weld joint, the initial stress is released and finally controlled by the weld residual stress. On the other hand, the farther away from the weld joint, the greater the influence of the initial stress. The range in which the initial stress affects the weld residual stress was not changed by the initial stress. However, in the region where the initial stress occurs in the compressive stress, the magnitude of the weld residual compressive stress varies with the compression or tension of the initial stress. The effect of initial stress on the maximum compression residual stress was far larger when initial stress was considered in case of a thickness of 25 mm with a value of 180

  5. Charred olive stones: experimental and archaeological evidence for recognizing olive processing residues used as fuel

    NARCIS (Netherlands)

    Braadbaart, Freek; Marinova, E.; Sarpaki, A.

    After extracting oil from olives a residue is left usually referred to as the olive oil processing residue (OPR). This study explores the way in which ancient societies may have used OPR as fuel for fires to generate heat and the various issues that are related to the residues of this fuel. After

  6. Residue dissipation and processing factor for dimethomorph, famoxadone and cymoxanil during raisin preparation.

    Science.gov (United States)

    Shabeer T P, Ahammed; Banerjee, Kaushik; Jadhav, Manjusha; Girame, Rushali; Utture, Sagar; Hingmire, Sandip; Oulkar, Dasharath

    2015-03-01

    A method was validated for the simultaneous analysis of the residues of dimethomorph, famoxadone and cymoxanil in grape and raisin matrix by ethyl acetate based extraction and liquid chromatography tandem mass spectrometric analysis. Field studies were conducted to evaluate the dissipation rate kinetics and processing factor (PF) for these pesticides during raisin making. Residue data during the drying process were best fitted to 1st+1st order rate kinetics with half-life ranging between 8-9 days for dimethomorph, 12-13 days for famoxadone and 9-10 days for cymoxanil at single dose (SD) and double dose (DD), respectively. PF values calculated were 1.03 and 1.14 for dimethomorph, 1.95 and 2.09 for famoxadone, and 1.99 and 1.35 for cymoxanil at SD and DD, respectively. PF value >1 indicates concentration of the residues during raisin making. The residues of detected pesticides in market samples of raisins were devoid of any risk of acute toxicity related to dietary exposure. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Design Processes

    DEFF Research Database (Denmark)

    Ovesen, Nis

    2009-01-01

    Inspiration for most research and optimisations on design processes still seem to focus within the narrow field of the traditional design practise. The focus in this study turns to associated businesses of the design professions in order to learn from their development processes. Through interviews...... and emerging production methods....

  8. Effect of Welding Processes on the Microstructure, Mechanical Properties and Residual Stresses of Plain 9Cr-1Mo Steel Weld Joints

    Science.gov (United States)

    Nagaraju, S.; Vasantharaja, P.; Brahadees, G.; Vasudevan, M.; Mahadevan, S.

    2017-12-01

    9Cr-1Mo steel designated as P9 is widely used in the construction of power plants and high-temperature applications. It is chosen for fabricating hexcan fuel subassembly wrapper components of fast breeder reactors. Arc welding processes are generally used for fabricating 9Cr-1Mo steel weld joints. A-TIG welding process is increasingly being adopted by the industries. In the present study, shielded metal arc (SMA), tungsten inert gas (TIG) and A-TIG welding processes are used for fabricating the 9Cr-1Mo steel weld joints of 10 mm thickness. Effect of the above welding processes on the microstructure evolution, mechanical properties and residual stresses of the weld joints has been studied in detail. All the three weld joints exhibited comparable strength and ductility values. 9Cr-1Mo steel weld joint fabricated by SMAW process exhibited lower impact toughness values caused by coarser grain size and inclusions. 9Cr-1Mo steel weld joint fabricated by TIG welding exhibited higher toughness due to finer grain size, while the weld joint fabricated by A-TIG welding process exhibited adequate toughness values. SMA steel weld joint exhibited compressive residual stresses in the weld metal and HAZ, while TIG and A-TIG weld joint exhibited tensile residual stresses in the weld metal and HAZ.

  9. Modelling Of Residual Stresses Induced By High Speed Milling Process

    International Nuclear Information System (INIS)

    Desmaison, Olivier; Mocellin, Katia; Jardin, Nicolas

    2011-01-01

    Maintenance processes used in heavy industries often include high speed milling operations. The reliability of the post-process material state has to be studied. Numerical simulation appears to be a very interesting way to supply an efficient residual stresses (RS) distribution prediction.Because the adiabatic shear band and the serrated chip shaping are features of the austenitic stainless steel high speed machining, a 2D high speed orthogonal cutting model is briefly presented. This finite element model, developed on Forge registered software, is based on data taken from Outeiro and al.'s paper [1]. A new behaviour law fully coupling Johnson-Cook's constitutive law and Latham and Cockcroft's damage model is detailed in this paper. It ensures results that fit those found in literature.Then, the numerical tools used on the 2D model are integrated to a 3D high speed milling model. Residual stresses distribution is analysed, on the surface and into the depth of the material. Various revolutions and passes of the two teeth hemispheric mill on the workpiece are simulated. Thus the sensitivity of the residual stresses generation to the cutting conditions can be discussed. In order to validate the 3D model, a comparison of the cutting forces measured by EDF R and D to those given by numerical simulations is achieved.

  10. Effect of processing conditions on residual stress distributions by bead-on-plate welding after surface machining

    International Nuclear Information System (INIS)

    Ihara, Ryohei; Mochizuki, Masahito

    2014-01-01

    Residual stress is important factor for stress corrosion cracking (SCC) that has been observed near the welded zone in nuclear power plants. Especially, surface residual stress is significant for SCC initiation. In the joining processes of pipes, butt welding is conducted after surface machining. Residual stress is generated by both processes, and residual stress distribution due to surface machining is varied by the subsequent butt welding. In previous paper, authors reported that residual stress distribution generated by bead on plate welding after surface machining has a local maximum residual stress near the weld metal. The local maximum residual stress shows approximately 900 MPa that exceeds the stress threshold for SCC initiation. Therefore, for the safety improvement of nuclear power plants, a study on the local maximum residual stress is important. In this study, the effect of surface machining and welding conditions on residual stress distribution generated by welding after surface machining was investigated. Surface machining using lathe machine and bead on plate welding with tungsten inert gas (TIG) arc under various conditions were conducted for plate specimens made of SUS316L. Then, residual stress distributions were measured by X-ray diffraction method (XRD). As a result, residual stress distributions have the local maximum residual stress near the weld metal in all specimens. The values of the local maximum residual stresses are almost the same. The location of the local maximum residual stress is varied by welding condition. It could be consider that the local maximum residual stress is generated by same generation mechanism as welding residual stress in surface machined layer that has high yield stress. (author)

  11. Effect of Household Coffee Processing on Pesticide Residues as a Means of Ensuring Consumers' Safety.

    Science.gov (United States)

    Mekonen, Seblework; Ambelu, Argaw; Spanoghe, Pieter

    2015-09-30

    Coffee is a highly consumed and popular beverage all over the world; however, coffee beans used for daily consumption may contain pesticide residues that may cause adverse health effects to consumers. In this monitoring study, the effect of household coffee processing on pesticide residues in coffee beans was investigated. Twelve pesticides, including metabolites and isomers (endosulfan α, endosulfan β, cypermethrin, permethrin, deltamethrin, chlorpyrifos ethyl, heptachlor epoxide, hexachlorobenzene, p'p-DDE, p'p-DDD, o'p-DDT, and p'p-DDT) were spiked in coffee beans collected from a local market in southwestern Ethiopia. The subsequent household coffee processing conditions (washing, roasting, and brewing) were established as closely as possible to the traditional household coffee processing in Ethiopia. Washing of coffee beans showed 14.63-57.69 percent reduction, while the roasting process reduced up to 99.8 percent. Chlorpyrifos ethyl, permethrin, cypermethrin, endosulfan α and β in roasting and all of the 12 pesticides in the coffee brewing processes were not detected. Kruskal-Wallis analysis indicated that the reduction of pesticide residues by washing is significantly different from roasting and brewing (P coffee roasting and brewing (P > 0.05). The processing factor (PF) was less than one (PF coffee beans. The cumulative effect of the three processing methods has a paramount importance in evaluating the risks associated with ingestion of pesticide residues, particularly in coffee beans.

  12. Effect of processing on the disappearance of pesticide residues in fresh-cut lettuce: Bioavailability and dietary risk.

    Science.gov (United States)

    Camara, Miguel A; Barba, Alberto; Cermeño, Sandra; Martinez, Gracia; Oliva, Jose

    2017-12-02

    The aim of this research is to establish the processing factors of six pesticides durong the preparation of fresh-cut lettuce and to assess the risk of ingestion of pesticide residues associated with the consumption of the same. A field study was carried out on the dissipation of three insecticides (imidacloprid, tebufenozide, cypermethrin) and three fungicides (metalaxyl, tebuconazole, azoxystrobin) during treatment conditions simulating those used for commercial fresh-cut lettuce. A simultaneous residue analysis method is validated using QuEChERS extraction with acetonitrile and CG-MS and LC-MS/MS analysis. The residues detected after field application never exceed the established Maximum Residue Limits. The processing factors were generally less than 1 (between 0.34 for tebufenozide and 0.53 for imidacloprid), indicating that the process, as a whole, considerably reduces residue levels in processed lettuce compared to fresh lettuce. It is confirmed that cutting, followed by washing and drying, considerably reduces the residues. A matrix effect in the dialyzation of the pesticides is observed and the in vitro study of bioavailability establishes a low percentage of stomach absorption capacity (lettuce showed no concerns for consumer health.

  13. Single-well experimental design for studying residual trapping of superciritcal carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Y.; Freifeld, B.; Finsterle, S.; Leahy, M.; Ennis-King, J.; Paterson, L.; Dance, T.

    2010-06-15

    The objective of our research is to design a single-well injection-withdrawal test to evaluate residual phase trapping at potential CO{sub 2} geological storage sites. Given the significant depths targeted for CO{sub 2} storage and the resulting high costs associated with drilling to those depths, it is attractive to develop a single-well test that can provide data to assess reservoir properties and reduce uncertainties in the appraisal phase of site investigation. The main challenges in a single-well test design include (1) difficulty in quantifying the amount of CO{sub 2} that has dissolved into brine or migrated away from the borehole; (2) non-uniqueness and uncertainty in the estimate of the residual gas saturation (S{sub gr}) due to correlations among various parameters; and (3) the potential biased S{sub gr} estimate due to unaccounted heterogeneity of the geological medium. To address each of these challenges, we propose (1) to use a physical-based model to simulation test sequence and inverse modeling to analyze data information content and to quantify uncertainty; (2) to jointly use multiple data types generated from different kinds of tests to constrain the Sgr estimate; and (3) to reduce the sensitivity of the designed tests to geological heterogeneity by conducting the same test sequence in both a water-saturated system and a system with residual gas saturation. To perform the design calculation, we build a synthetic model and conduct a formal analysis for sensitivity and uncertain quantification. Both parametric uncertainty and geological uncertainty are considered in the analysis. Results show (1) uncertainty in the estimation of Sgr can be reduced by jointly using multiple data types and repeated tests; and (2) geological uncertainty is essential and needs to be accounted for in the estimation of S{sub gr} and its uncertainty. The proposed methodology is applied to the design of a CO{sub 2} injection test at CO2CRC's Otway Project Site, Victoria

  14. Performance of a biogas upgrading process based on alkali absorption with regeneration using air pollution control residues.

    Science.gov (United States)

    Baciocchi, Renato; Carnevale, Ennio; Costa, Giulia; Gavasci, Renato; Lombardi, Lidia; Olivieri, Tommaso; Zanchi, Laura; Zingaretti, Daniela

    2013-12-01

    This work analyzes the performance of an innovative biogas upgrading method, Alkali absorption with Regeneration (AwR) that employs industrial residues and allows to permanently store the separated CO2. This process consists in a first stage in which CO2 is removed from the biogas by means of chemical absorption with KOH or NaOH solutions followed by a second stage in which the spent absorption solution is contacted with waste incineration Air Pollution Control (APC) residues. The latter reaction leads to the regeneration of the alkali reagent in the solution and to the precipitation of calcium carbonate and hence allows to reuse the regenerated solution in the absorption process and to permanently store the separated CO2 in solid form. In addition, the final solid product is characterized by an improved environmental behavior compared to the untreated residues. In this paper the results obtained by AwR tests carried out in purposely designed demonstrative units installed in a landfill site are presented and discussed with the aim of verifying the feasibility of this process at pilot-scale and of identifying the conditions that allow to achieve all of the goals targeted by the proposed treatment. Specifically, the CO2 removal efficiency achieved in the absorption stage, the yield of alkali regeneration and CO2 uptake resulting for the regeneration stage, as well as the leaching behavior of the solid product are analyzed as a function of the type and concentration of the alkali reagent employed for the absorption reaction. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Drawing a Transductive Ecosophy in Process: Technological Arts, Residual Matter, Associated Milieus

    Directory of Open Access Journals (Sweden)

    Gisèle Trudel

    2015-06-01

    Full Text Available Drawing a Transductive Ecosophy in Process: Technological Arts, Residual Matter, Associated Milieus by Gisèle Trudel. NANO: New American Notes Online, Issue 7: The Aesthetics of Trash - nanocrit.com. This text examines the tetralogy of media artworks about residual matter produced by Ælab between 2008 and 2014. Taking its own title as a diagram (Deleuze and Guattari Mille Plateaux, it charts and builds on the processes of these artworks, elucidating their relations to materiality, philosophy and technicity. Technological research-creation becomes in these instances a transdisciplinary aesthetic act, emerging from an ecology of practices that combine humans, non-humans and waste matter in an effort to increase attentiveness in actions.

  16. Study of residue type defect formation mechanism and the effect of advanced defect reduction (ADR) rinse process

    Science.gov (United States)

    Arima, Hiroshi; Yoshida, Yuichi; Yoshihara, Kosuke; Shibata, Tsuyoshi; Kushida, Yuki; Nakagawa, Hiroki; Nishimura, Yukio; Yamaguchi, Yoshikazu

    2009-03-01

    Residue type defect is one of yield detractors in lithography process. It is known that occurrence of the residue type defect is dependent on resist development process and the defect is reduced by optimized rinsing condition. However, the defect formation is affected by resist materials and substrate conditions. Therefore, it is necessary to optimize the development process condition by each mask level. Those optimization steps require a large amount of time and effort. The formation mechanism is investigated from viewpoint of both material and process. The defect formation is affected by resist material types, substrate condition and development process condition (D.I.W. rinse step). Optimized resist formulation and new rinse technology significantly reduce the residue type defect.

  17. Computational Prediction of Hot Spot Residues

    Science.gov (United States)

    Morrow, John Kenneth; Zhang, Shuxing

    2013-01-01

    Most biological processes involve multiple proteins interacting with each other. It has been recently discovered that certain residues in these protein-protein interactions, which are called hot spots, contribute more significantly to binding affinity than others. Hot spot residues have unique and diverse energetic properties that make them challenging yet important targets in the modulation of protein-protein complexes. Design of therapeutic agents that interact with hot spot residues has proven to be a valid methodology in disrupting unwanted protein-protein interactions. Using biological methods to determine which residues are hot spots can be costly and time consuming. Recent advances in computational approaches to predict hot spots have incorporated a myriad of features, and have shown increasing predictive successes. Here we review the state of knowledge around protein-protein interactions, hot spots, and give an overview of multiple in silico prediction techniques of hot spot residues. PMID:22316154

  18. Design and analysis of a new passive residual heat removal system

    Energy Technology Data Exchange (ETDEWEB)

    Lv, Xing [Key Subject Laboratory of Nuclear Safety and Simulation Technology, Harbin Engineering University, Harbin, Heilongjiang 150001 (China); Peng, Minjun, E-mail: heupmj@163.com [Key Subject Laboratory of Nuclear Safety and Simulation Technology, Harbin Engineering University, Harbin, Heilongjiang 150001 (China); Yuan, Xiao [Guangxi Fangchenggang Nuclear Power Co., Ltd (China); Xia, Genglei [Key Subject Laboratory of Nuclear Safety and Simulation Technology, Harbin Engineering University, Harbin, Heilongjiang 150001 (China)

    2016-07-15

    Highlights: • An air cooling passive residual heat removal System (PRHRs) is designed. • Using RELAP5/MOD3.4 code to analyze the operation characteristics of the PRHRs. • Noncondensable gas is used to simulate the hydrodynamic behavior in the air cooling tower. • The natural circulations could respectively establish in the primary circuit and the PRHRs circuit. • The PRHRs could remove the residual heat effectively. - Abstract: The inherent safety functions will mitigate the consequences of the accidents, and it can be accomplished through the passive safety systems which employed in the typical pressurized water reactor (PWR). In this paper, a new passive residual heat removal system (PRHRS) is designed for a typical nuclear power plant. PRHRS consists of a steam generator (SG), a cooling tank with two groups of cooling pipes, an air-cooling heat exchanger (AHX), an air-cooling tower, corresponding pipes and valves. The cooling tank which works as an intermediate buffer device is used to transfer the core decay heat to the AHX, and then the core decay heat will be removed to the atmosphere finally. The RELAP5/MOD3.4 code is used to analyze the operation characteristics of PRHRS and the primary loop system. It shows PRHRS could remove the decay heat from the primary loop effectively, and the natural circulations can be established in the primary circuit and the PRHRS circuit respectively. Furthermore, the sensitivity study has also been done to research the effect of various factors on the heat removal capacity.

  19. ECO DESIGN IN DESIGN PROCESS

    Directory of Open Access Journals (Sweden)

    PRALEA Jeni

    2014-05-01

    Full Text Available Eco-design is a new domain, required by the new trends and existing concerns worldwide, generated by the necessity of adopting new design principles. New design principles require the designer to provide a friendly relationship between concept created, environment and consume. This "friendly" relationship should be valid both at present and in the future, generating new opportunities for product, product components or materials from which it was made. Awareness, by the designer, the importance of this new trend, permits the establishment of concepts that have as their objective the protection of present values and ensuring the legacy of future generations. Ecodesig, by its principles, is involved in the design process, from early stage, the stage of product design. Priority objective of the designers will consist in reducing the negative effects on the environment through the entire life cycle and after it is taken out of use. The main aspects of the eco-design will consider extending product exploitation, make better use of materials, reduction of emission of waste. The design process in the "eco"domein must be started by selecting the function of the concept, materials and technological processes, causing the shape of macro and micro geometric of the product through an analysis that involves optimizing and streamlining the product. This paper presents the design process of a cross-sports footwear concept, built on the basis of the principles of ecodesign

  20. Aerobic composting of digested residue eluted from dry methane fermentation to develop a zero-emission process.

    Science.gov (United States)

    Huang, Yu-Lian; Sun, Zhao-Yong; Zhong, Xiao-Zhong; Wang, Ting-Ting; Tan, Li; Tang, Yue-Qin; Kida, Kenji

    2017-03-01

    Digested residue remained at the end of a process for the production of fuel ethanol and methane from kitchen garbage. To develop a zero-emission process, the compostability of the digested residue was assessed to obtain an added-value fertilizer. Composting of the digested residue by adding matured compost and a bulking agent was performed using a lab-scale composting reactor. The composting process showed that volatile total solid (VTS) degradation mainly occurred during the first 13days, and the highest VTS degradation efficiency was about 27% at the end. The raw material was not suitable as a fertilizer due to its high NH 4 + and volatile fatty acids (VFAs) concentration. However, the composting process produced remarkable results; the physicochemical properties indicated that highly matured compost was obtained within 62days of the composting process, and the final N concentration, NO 3 - concentration, and the germination index (GI) at the end of the composting process was 16.4gkg -1 -TS, 9.7gkg -1 -TS, and 151%, respectively. Real-time quantitative PCR (qPCR) analysis of ammonia oxidizers indicated that the occurrence of nitrification during the composting of digested residue was attributed to the activity of ammonia-oxidizing bacteria (AOB). Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. The study on process of recycling uranium in mixture of residue and liquid

    International Nuclear Information System (INIS)

    Zhang Jie; Shen Weiwei; Hao Jidong; Wu Jiangming

    2014-01-01

    The treat method of mixture of residue and liquid produced from HWR nuclear fuel chemical process using some kind of U_3O_8 powder was studied in this experiment. For recycling the uranium in mixture of residue and liquid, chemical dissolving method, washing and centrifuging method and dilute nitric acid leaching uranium method was contrasted in this test. The merit of dilute nitric acid leaching uranium method is simpler, more effective and higher uranium recycling ratio. Next, dilute nitric acid leaching uranium method was studied systematically. As a result, the main influence factors of uranium recycling ratio is dip sour degree and dip sour temperature. The influence law of factors to uranium recycling ratio and filtering effect was found out also. Along with increasing of dip sour degree and dip sour temperature, uranium recycling ratio increases and speed of filtrate increases also. At last, the process of batch treating mixture of residue and liquid was build and abundant uranium was recycled. (authors)

  2. Optimization of prehydrolysis time and substrate feeding to improve ethanol production by simultaneous saccharification and fermentation of furfural process residue.

    Science.gov (United States)

    He, Jianlong; Zhang, Wenbo; Liu, Xiaoyan; Xu, Ning; Xiong, Peng

    2016-11-01

    Ethanol is a very important industrial chemical. In order to improve ethanol productivity using Saccharomyces cerevisiae in fermentation from furfural process residue, we developed a process of simultaneous saccharification and fermentation (SSF) of furfural process residue, optimizing prehydrolysis cellulase loading concentration, prehydrolysis time, and substrate feeding strategy. The ethanol concentration obtained from the optimized process was 19.3 g/L, corresponding 76.5% ethanol yield, achieved by running SSF for 48 h from 10% furfural process residue with prehydrolysis at 50°C for 4 h and cellulase loading of 15 FPU/g furfural process residue. For higher ethanol concentrations, fed-batch fermentation was performed. The optimized fed-batch process increased the ethanol concentration to 37.6 g/L, 74.5% yield, obtained from 10% furfural process residue with two additions of 5% substrate at 12 and 24 h. Copyright © 2016 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

  3. Prediction of microstructure, residual stress, and deformation in laser powder bed fusion process

    Science.gov (United States)

    Yang, Y. P.; Jamshidinia, M.; Boulware, P.; Kelly, S. M.

    2017-12-01

    Laser powder bed fusion (L-PBF) process has been investigated significantly to build production parts with a complex shape. Modeling tools, which can be used in a part level, are essential to allow engineers to fine tune the shape design and process parameters for additive manufacturing. This study focuses on developing modeling methods to predict microstructure, hardness, residual stress, and deformation in large L-PBF built parts. A transient sequentially coupled thermal and metallurgical analysis method was developed to predict microstructure and hardness on L-PBF built high-strength, low-alloy steel parts. A moving heat-source model was used in this analysis to accurately predict the temperature history. A kinetics based model which was developed to predict microstructure in the heat-affected zone of a welded joint was extended to predict the microstructure and hardness in an L-PBF build by inputting the predicted temperature history. The tempering effect resulting from the following built layers on the current-layer microstructural phases were modeled, which is the key to predict the final hardness correctly. It was also found that the top layers of a build part have higher hardness because of the lack of the tempering effect. A sequentially coupled thermal and mechanical analysis method was developed to predict residual stress and deformation for an L-PBF build part. It was found that a line-heating model is not suitable for analyzing a large L-PBF built part. The layer heating method is a potential method for analyzing a large L-PBF built part. The experiment was conducted to validate the model predictions.

  4. Prediction of microstructure, residual stress, and deformation in laser powder bed fusion process

    Science.gov (United States)

    Yang, Y. P.; Jamshidinia, M.; Boulware, P.; Kelly, S. M.

    2018-05-01

    Laser powder bed fusion (L-PBF) process has been investigated significantly to build production parts with a complex shape. Modeling tools, which can be used in a part level, are essential to allow engineers to fine tune the shape design and process parameters for additive manufacturing. This study focuses on developing modeling methods to predict microstructure, hardness, residual stress, and deformation in large L-PBF built parts. A transient sequentially coupled thermal and metallurgical analysis method was developed to predict microstructure and hardness on L-PBF built high-strength, low-alloy steel parts. A moving heat-source model was used in this analysis to accurately predict the temperature history. A kinetics based model which was developed to predict microstructure in the heat-affected zone of a welded joint was extended to predict the microstructure and hardness in an L-PBF build by inputting the predicted temperature history. The tempering effect resulting from the following built layers on the current-layer microstructural phases were modeled, which is the key to predict the final hardness correctly. It was also found that the top layers of a build part have higher hardness because of the lack of the tempering effect. A sequentially coupled thermal and mechanical analysis method was developed to predict residual stress and deformation for an L-PBF build part. It was found that a line-heating model is not suitable for analyzing a large L-PBF built part. The layer heating method is a potential method for analyzing a large L-PBF built part. The experiment was conducted to validate the model predictions.

  5. Environmental toxicity and radioactivity assessment of a titanium-processing residue with potential for environmental use.

    Science.gov (United States)

    Wendling, Laura A; Binet, Monique T; Yuan, Zheng; Gissi, Francesca; Koppel, Darren J; Adams, Merrin S

    2013-07-01

    Thorough examination of the physicochemical characteristics of a Ti-processing residue was undertaken, including mineralogical, geochemical, and radiochemical characterization, and an investigation of the environmental toxicity of soft-water leachate generated from the residue. Concentrations of most metals measured in the leachate were low; thus, the residue is unlikely to leach high levels of potentially toxic elements on exposure to low-ionic strength natural waters. Relative to stringent ecosystem health-based guidelines, only chromium concentrations in the leachate exceeded guideline concentrations for 95% species protection; however, sulfate was present at concentrations known to cause toxicity. It is likely that the high concentration of calcium and extreme water hardness of the leachate reduced the bioavailability of some elements. Geochemical modeling of the leachate indicated that calcium and sulfate concentrations were largely controlled by gypsum mineral dissolution. The leachate was not toxic to the microalga Chlorella sp., the cladoceran Ceriodaphnia dubia, or the estuarine bacterium Vibrio fischeri. The Ti-processing residue exhibited an absorbed dose rate of 186 nGy/h, equivalent to an annual dose of 1.63 mGy and an annual effective dose of 0.326 mGy. In summary, the results indicate that the Ti-processing residue examined is suitable for productive use as an environmental amendment following 10 to 100 times dilution to ameliorate potential toxic effects due to chromium or sulfate. Copyright © 2013 SETAC.

  6. Effect of oil refining processes on 14 C-tetrachlorvinphos residues in soya bean oil

    International Nuclear Information System (INIS)

    Farghaly, M.; Zayed, S.M.A.D.

    1986-01-01

    Crude soya bean oil extracted from grains treated with 14 C-tetrachlorvinphos and stored for 30 weeks was subjected to different refining processes. The effect of commercial refining processes, namely: alkali treatment, bleaching, winterization and deodorization on the nature and magnitude of the originally present residues was investigated. A high percentage (52%) of the residues was eliminated during alkali neutralization. No potentially toxic materials were detected among the identified degradation products. The obtained data showed that the ultimate degradation products were dimethyl phosphate and mono methyl phosphate.2 tab.,2 scheme

  7. Effect of commercial processing procedures on 14C-LINDANE residues in corn oil

    International Nuclear Information System (INIS)

    Soliman, S.M.

    2006-01-01

    At blooming, maize plants were sprayed twice, 23 days apart, at a dose of 22 mg equivalent to 5 μCi/ plant. At post harvest, maize seeds had a radioactivity corresponding to 0.36% of the applied dose. The insecticide residues in crude oil, cake and methanolic extract were amounted to 8 % and 60 % 5 % , respectively, of original residues inside the seeds.The 14 C-activity in the crude oil could be reduced by commercial processes locally used for refining. The refined oil had a residue level of about 0.7 ppm mainly in the form of unchanged lindane in addition to a number of chloro phenols as main metabolites. Refining of corn oil fortified with 14 C-lindane led to a high reduction of 14 C-lindane (88%). The refined oil contained a residue consisting lindane and its chloro phenols

  8. Reduction of tensile residual stresses during the drawing process of tungsten wires

    International Nuclear Information System (INIS)

    Rodriguez Ripoll, Manel; Weygand, Sabine M.; Riedel, Hermann

    2010-01-01

    Tungsten wires are commonly used in the lighting industry as filaments for lamps. During the drawing process, the inhomogeneous deformation imparted by the drawing die causes tensile residual stresses at the wire surface in circumferential direction. These stresses have a detrimental effect for the wire because they are responsible for driving longitudinal cracks, known as splits. This work proposes two methods for reducing the residual stresses during wire drawing, namely applying an advanced die geometry and performing an inexpensive post-drawing treatment based on targeted bending operations. These two methods are analyzed with finite element simulations using material parameters obtained by mechanical tests on tungsten wires at different temperatures as input data. The computed results predict a substantial reduction of the circumferential residual stresses, thus reducing the risk of splitting.

  9. Thermogravimetric study of the pyrolysis of biomass residues from tomato processing industry

    Energy Technology Data Exchange (ETDEWEB)

    Mangut, V.; Sabio, E.; Ganan, J.; Gonzalez, J.F.; Ramiro, A.; Gonzalez, C.M.; Roman, S.; Al-Kassir, A. [Department of Chemical and Energy Engineering, University of Extremadura, Avda. de Elvas s/n, 06071 Badajoz (Spain)

    2006-01-15

    There is an increasing concern with the environmental problems associated with the increasing CO{sub 2}, NO{sub x} and SO{sub x} emissions resulting from the rising use of fossil fuels. Renewable energy, mainly biomass, can contribute to reduce the fossil fuels consumption. Biomass is a renewable resource with a widespread world distribution. Tomato processing industry produces a high amount of biomass residue (peel and seeds) that could be used for thermal energy and electricity. A characterization and thermogravimetric study has been carried out. The residue has a high HHV and volatile content, and a low ash, and S contents. A kinetic model has been developed based on the degradation of hemicellulose, cellulose, lignin and oil that describe the pyrolysis of peel, seeds and peel and seeds residues. (author)

  10. Process for measuring the helium residual gas pressure and circuit for carrying out the process

    International Nuclear Information System (INIS)

    Schmidt, C.; Cesnak, L.

    1983-01-01

    In cryotechnic devices, the quality of the thermal insulation can be monitored by checking the pressure of the residual gas. A process is proposed in which a thin super-conducting wire or a superconducting layer acting as vacuum sensor has a heating pulse reaching the critical current applied to it, which produces a local normal conduction zone. The vacuum sensor has a measuring current of constant amount applied to it, which causes a voltage drop on its resistance during the time in which the normal conduction zone exists, the cooling time. The pressure of the residual gas is a function of the integral of the voltage drop and is measured by integrating the voltage during the cooling time. (orig./HP) [de

  11. Building flexibility into the design of a pilot plant for the immobilisation of Pu containing residues and wastes

    Energy Technology Data Exchange (ETDEWEB)

    Scales, C R; Maddrell, E R [NNL, Havelock Rd, Workington, CA14 3YQ (United Kingdom); Hobbs, J; Stephen, R [Sellafield Ltd, Sellafield, CA20 1 PG (United Kingdom); Moricca, S; Stewart, M W A [ANSTO, New Illawara Road, Lucas Heights 2234 (Australia)

    2013-07-01

    NNL and ANSTO on behalf of Sellafield Ltd have developed a process for the immobilisation of a range of Pu containing wastes and residues. Following the inactive demonstration of the technology the project is now focusing on the design of an active pilot plant capable of validating the technology and ultimately immobilising a waste inventory containing around 100 kg plutonium. The diverse wastes from which it is uneconomic to recover Pu, require a flexible process with a wide product envelope capable of producing a wasteform suitable for disposal in a UK repository. Ceramics, glass ceramics and metal encapsulated waste-forms can be delivered by the process line which incorporates size reduction and heat treatment techniques with the aim of feeding a hot isostatic pressing process designed to deliver the highly durable waste-forms. Following a demonstration of feasibility, flowsheet development is progressing to support the design which has the aim of a fully flexible facility based in NNL's Central Laboratory on the Sellafield site. Optimisation of the size reduction, mixing and blending operations is being carried out using UO{sub 2} as a surrogate for PuO{sub 2}. This work is supporting the potential of using an enhanced glass ceramic formulation in place of the full ceramic with the aim of simplifying glove box operations. Heat treatment and subsequent HIPing strategies are being explored in order to eliminate any carbon from the feeds without increasing the valence state of the uranium present in some of the inventory which can result in an unwanted increase in wasteform volumes. The HIP and ancillary systems are being specifically designed to meet the requirements of the Sellafield site and within the constraints of the NNL Central Laboratory. The HIP is being configured to produce consolidated product cans consistent with the requirements of ongoing storage and disposal. With the aim of one cycle per day, the facility will deliver its mission of

  12. Effect of Refining Processes on Magnitude and Nature of Malathion and Carbofuran Residues in Cotton Seed Oil

    International Nuclear Information System (INIS)

    Zayed, S.M.A.D.; Farghaly, M.; Mahdy, F.

    2005-01-01

    Cotton seeds obtained from 14 C-carbofuran or 14 C-malathion-treated plants contained 0.25% and 0.11% of the originally applied radioactivity, respectively. The concentration of malathion residues in oil, methanol soluble and in the seed cake amounted to 0.94, 2.6 and 1.7 ppm, respectively. Commercial processing procedures led to a gradual decrease in the total amount of 14 C-residues in oils with aged residues as well as in oil fortified with the radiolabelled insecticides. The refined oil contained only about 20% of the 14 C-residues originally present. The major residue in processed oil contained malathion, malathion monocarboxylic acid and alpha-(O,O-dimethyl phosphorodithio)-propionic acid. The concentration of 14 C-carbofuran residues in cotton seed oil, methanol extract and cake was 1.7, 12.3 and 2.4 ppm, respectively. The main residues in the oil were carbofuran and its phenol. The methanol solubles contained conjugated metabolites, which upon hydrolysis gave 3-hydroxy-carbofuran as a major product. Refinement reduced the residue in oil to 0.26 ppm. The residue in refined oil contained carbofuran and carbofuran phenol as main constituents together with smaller amounts of 3-hydroxy- and 3-keto carbofuran

  13. Non-isothermal kinetic studies on co-processing of olive residue and polypropylene

    International Nuclear Information System (INIS)

    Aboulkas, A.; El Harfi, K.; El Bouadili, A.

    2008-01-01

    Co-processing of olive residue with polypropylene was performed in a thermogravimetric analyzer (TGA) reaction system in a nitrogen atmosphere with a view to comparing the process of the mixture with those of the individual components. Experiments were conducted at different heating rates of 2, 10, 20 and 50 K min -1 in the temperature range of 300-975 K based on the results obtained, three thermal stages were identified during the thermal degradation. The first two were dominated by olive residue pyrolysis, while the third was linked to polypropylene pyrolysis, which occurred at much higher temperatures. Discrepancies between the experimental and calculated TG/DTG profiles were considered as a measurement of the extent of interactions occurring on co-pyrolysis. The maximum degradation temperature of each component in the mixture was higher than those of the individual components alone; thus, an increase in thermal stability was expected. The kinetic processing of thermogravimetric data was conducted using the Friedman method

  14. Residual stress evaluation and curvature behavior of aluminum 7050 peen forming processed; Avaliacao da tensao residual em aluminio 7050 conformado pelo processo peen forming

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Rene Ramos de

    2011-07-01

    Shot peening is a superficial cold work process used to increase the fatigue life evaluated by residual stress measurements. The peen forming process is a variant of the shot peening process, where a curvature in the plate is obtained by the compression of the grains near to the surface. In this paper, the influence of the parameters such as: pressure of shot, ball shot size and thickness of aluminum 7050 samples with respect to residual stress profile and resulting arc height was studied. The evaluation of the residual stress profile was obtained by sin{sup 2} {psi} method. The results show that the formation of the curvature arc height is proportional to the shot peening pressure, of spheres size and inversely proportional to the thickness of the sample, and that stress concentration factor is larger for samples shot peened with small balls. On final of this paper presents an additional study on micro strain and average crystallite size, which can evaluate the profile of the samples after blasting. (author)

  15. Effects of process parameters on ozone washing for denim using 3/sup 3/ factorial design

    International Nuclear Information System (INIS)

    Asim, F.; Mahmood, M.

    2017-01-01

    Denim garment is getting popular day by day. It is highly demandable because of its versatility, comfort and durability. Different techniques of denim washing increase this demand drastically. Denim washing is the process to enhance the appearance of a garment. This enhanced appearance may be the aged look, faded look, greyer cast, or any other shade setting or resin application. The two most advanced washing techniques are; ozone wash and laser wash. The effects of ozone on environment as well as on the garment are significant and cannot be neglected because number of benefits achieved such as time saving, less energy consumption, chemical, labour cost reduction, less discharge of water and chemicals. Therefore, effects of process parameters on ozone washing for denim fabric have been investigated in this research work using three level factorial design. 33 factorial design has been designed and conducted to investigate the effect of gas concentration, time and speed on the response variables namely; Shrinkage, Tensile and Tear strength of ozone washing. The influence of individual factors and their interactions has been critically examined using software Design Expert 8.0. Prior to the analysis of variance model accuracy has been examined through various residuals plots. The study of residuals plots shown that the residuals are normally distributed and significant evidence of possible outliers was not found. So the model can be used to predicted results with 95% confidence interval. The results from the experiment suggest that two out of three factors were significant, which are speed and time that influences mainly on the tear strength of the denim garment. (author)

  16. Design and simulation of a process of seawater desalination (MED) using the residual heat of a PBMR nuclear power plant; Diseno y simulacion de un proceso de desalinizacion de agua de mar (MED) utilizando el calor residual de una planta nucleoelectrica PBMR

    Energy Technology Data Exchange (ETDEWEB)

    Valle H, Julio; Morales S, J.B. [UNAM, DEPFI Campus Morelos, Jiutepec, Morelos (Mexico)]. e-mail: jms0620@yahoo.com

    2008-07-01

    In the present work it is demonstrated as the thermodynamic recuperative Brayton cycle with which operates a nuclear power plant type PBMR (Pebble Bed Modular Reactor) it allows to use the residual heat, removed in the coolers of the compression stage of the system, to produce vapor and to desalt seawater. The desalination process selected, starting from its operation characteristics and the derived advantages of them using nuclear heat, it the one of Multi-Effect Distillation, MED for its abbreviations in English, which described and it is justified to detail. This distillation process widely studied, allows us to use water vapor pressurized to temperatures between 70 and 110 C like energy source to evaporate the seawater in the first stage or effect of the process. The relatively low temperatures with which the vapor takes place of feeding to the process is it makes to the plant PBMR ideal for desalination of seawater, since does not require majors modifications to its design its operation, and on the contrary it allows to use the heat that previously was rejected, to produce the vapor. In this work an unit MED of six effects is designed, which undergoes a successive fall of pressure in each of them. Once obtained the agreed design to the conditions of operation of PBMR plant, it was model mathematically the MED process, including the coupling stage with the reactor coolers. The mathematical model was obtained by means of differential equations of mass balance and energy in the system, and with this it was implemented in SIMULINK a model equivalent to the MED process which is interconnected to the simulator coolers of the PBMR plant, constructed previously. One ran the program being obtained the results that are reported at the end of this article. (Author)

  17. Computational prediction of protein hot spot residues.

    Science.gov (United States)

    Morrow, John Kenneth; Zhang, Shuxing

    2012-01-01

    Most biological processes involve multiple proteins interacting with each other. It has been recently discovered that certain residues in these protein-protein interactions, which are called hot spots, contribute more significantly to binding affinity than others. Hot spot residues have unique and diverse energetic properties that make them challenging yet important targets in the modulation of protein-protein complexes. Design of therapeutic agents that interact with hot spot residues has proven to be a valid methodology in disrupting unwanted protein-protein interactions. Using biological methods to determine which residues are hot spots can be costly and time consuming. Recent advances in computational approaches to predict hot spots have incorporated a myriad of features, and have shown increasing predictive successes. Here we review the state of knowledge around protein-protein interactions, hot spots, and give an overview of multiple in silico prediction techniques of hot spot residues.

  18. Characterization and extraction of volatile compounds from pineapple (Ananas comosus L. Merril processing residues

    Directory of Open Access Journals (Sweden)

    Lília Calheiros de Oliveira Barretto

    2013-12-01

    Full Text Available The aim of this study was to extract and identify volatile compounds from pineapple residues generated during concentrated juice processing. Distillates of pineapple residues were obtained using the following techniques: simple hydrodistillation and hydrodistillation by passing nitrogen gas. The volatile compounds present in the distillates were captured by the solid-phase microextraction technique. The volatile compounds were identified in a system of high resolution gas chromatography system coupled with mass spectrometry using a polyethylene glycol polar capillary column as stationary phase. The pineapple residues constituted mostly of esters (35%, followed by ketones (26%, alcohols (18%, aldehydes (9%, acids (3% and other compounds (9%. Odor-active volatile compounds were mainly identified in the distillate obtained using hydrodistillation by passing nitrogen gas, namely decanal, ethyl octanoate, acetic acid, 1-hexanol, and ketones such as γ-hexalactone, γ-octalactone, δ-octalactone, γ-decalactone, and γ-dodecalactone. This suggests that the use of an inert gas and lower temperatures helped maintain higher amounts of flavor compounds. These data indicate that pineapple processing residue contained important volatile compounds which can be extracted and used as aroma enhancing products and have high potential for the production of value-added natural essences.

  19. Feasibility studies on cogeneration from industrial wood-processing residues in Ghana

    International Nuclear Information System (INIS)

    Brew-Hammond, A.; Atakora, S.B.

    1999-01-01

    Several feasibility studies have been undertaken on cogeneration from wood-processing industrial residues in Ghana; practically all concluded that it was not economically viable because of the low tariffs for electricity in Ghana (around 3.5 US cents per kWh) at the time. Tariffs have more than doubled since September 1998 and average tariffs for industrial consumers are now around 7-8 US cents/kWh. This paper reviews earlier studies and undertakes a sensitivity analysis to determine effects of the new tariff regime and the investment costs for co-generation projects. More detailed technical and economic feasibility studies are needed to prepare the ground for an investment programme in cogeneration from wood residues. (author)

  20. Analysis and modeling of simulated residual stress of mold injected plastic parts by using robust correlations

    OpenAIRE

    Vargas, Carlos; Sierra, Juan; Posada, Juan; Botero-Cadavid, Juan F.

    2017-01-01

    ABSTRACT The injection molding process is the most widely used processing technique for polymers. The analysis of residual stresses generated during this process is crucial for the part quality assessment. The present study evaluates the residual stresses in a tensile strength specimen using the simulation software Moldex3D for two polymers, polypropylene and polycarbonate. The residual stresses obtained under a simulated design of experiment were modeled using a robust multivariable regressi...

  1. The influence of punching process on residual stress and magnetic domain structure of non-oriented silicon steel

    International Nuclear Information System (INIS)

    Cao, Hongzhi; Hao, Linpo; Yi, Jingwen; Zhang, Xianglin; Luo, Zhonghan; Chen, Shenglin; Li, Rongfeng

    2016-01-01

    The main purpose of this paper is to investigate the influence of punching process on residual stress and magnetic domain structure. The residual stress in non-oriented silicon steel after punching process was measured by nanoindentation. The maximum depth was kept constant as 300 nm during nanoindentation. The material around indentation region exhibited no significant pile-up deformation. The calculation of residual stress was based on the Suresh theoretical model. Our experimental results show that residual compressive stress was generated around the sheared edge after punching. The width of residual stress affected zone by punching was around 0.4–0.5 mm. After annealing treatment, the residual stress was significantly decreased. Magnetic domain structure was observed according to the Bitter method. The un-annealed sample exhibited complicated domain patterns, and the widths of the magnetic domains varied between 3 µm and 8 µm. Most of the domain patterns of the annealed sample were 180°-domains and 90°-domains, and the widths of the domains decreased to 1–3 µm. - Highlights: • The residual stress distribution on sheared edge was measured. • The residual compressive stress was generated around the sheared edge. • The width of residual stress affected zone was about 0.4–0.5 mm. • The shape and width of the domain structure would be changed by annealing.

  2. A process for treatment of residues from dry/semidry APC systems at municipal solid waste incinerators. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hjelmar, O. [VKI, Hoersholm (Denmark)] Holland, D. [FLS miljoe a/s, Valby (Denmark)] Poulsen, B. [KARA, Roskilde (Denmark)

    1997-08-01

    The main objective of the project has been to establish and test a process for treatment of residues from the semidry (and dry) lime injection based APC processes at MSWIs, which will ensure that the residues can be managed in an environmentally safe manner. In pursuit of this goal, the following activities have been carried out: Performance of pilot scale extractions (approximately 50 kg of residue per batch) at the KARA MSWI in Roskilde of semidry APC system residues in order to establish and optimize process conditions. The optimization includes consideration of the possibilities for subsequent treatment/stabilization of the extracted solid phase as well as the possibility of treatment and safe discharge/utilization of the extract; Performance of chemical characterization, hydrogeochemical model calculations and experimental work in order to improve the understanding of the mechanisms and factors which for several contaminants control the equilibrium between the solid and liquid phases, both in the short and the long germ, and to use this information to obtain an environmentally acceptable method for stabilization/treatment of the extracted residues while at the same time minimizing the necessary amount of additives; production of treated residues and performance of leaching tests on these to assess and demonstrate the effectiveness of the entire process (extraction + stabilization/treatment); Evaluation of the technical, economical and environmental consequences of full scale implementation of the process. (EG) EFP-94. 19 refs.

  3. An analytical model to predict and minimize the residual stress of laser cladding process

    Science.gov (United States)

    Tamanna, N.; Crouch, R.; Kabir, I. R.; Naher, S.

    2018-02-01

    Laser cladding is one of the advanced thermal techniques used to repair or modify the surface properties of high-value components such as tools, military and aerospace parts. Unfortunately, tensile residual stresses generate in the thermally treated area of this process. This work focuses on to investigate the key factors for the formation of tensile residual stress and how to minimize it in the clad when using dissimilar substrate and clad materials. To predict the tensile residual stress, a one-dimensional analytical model has been adopted. Four cladding materials (Al2O3, TiC, TiO2, ZrO2) on the H13 tool steel substrate and a range of preheating temperatures of the substrate, from 300 to 1200 K, have been investigated. Thermal strain and Young's modulus are found to be the key factors of formation of tensile residual stresses. Additionally, it is found that using a preheating temperature of the substrate immediately before laser cladding showed the reduction of residual stress.

  4. Evaluation of the mercaptobenzothiazole degradation by combined adsorption process and Fenton reaction using iron mining residue.

    Science.gov (United States)

    Martins, Adriana Lau da Silva; Teixeira, Luís Alberto César; da Fonseca, Fabiana Valéria; Yokoyama, Lídia

    2017-08-01

    The present study investigated the degradation of mercaptobenzothiazole (MBT), evaluating homogeneous and heterogeneous systems. An iron mineral residue from the desliming step of iron mining was used as a source in the Fenton-like reaction (advanced oxidation process). A granulometric analysis of the residue was performed and yielded fractions with high hematite (Fe 2 O 3 ) and low quartz content in sieves from 74 to below 44 mm. In this particle size range, the hematite content from 58.9% to 67.4% and the Brunauer-Emmett-Teller area from 0.1345 to 1.3137 m 2  g -1 were obtained. The zeta potential curves as a function of pH were obtained for the residue, the MBT solution and mixtures thereof. The adsorption of MBT in the residue and its degradation through the Fenton-like reaction were investigated. Adsorption tests and the Fenton-like reaction were carried out, where the MBT species and the residue are oppositely charged, yielding, respectively, 10% MBT adsorption on the surface of the residue and 100% MBT degradation by the Fenton-like reaction at pH 3, hydrogen peroxide concentration of 25 mg L -1 , residue concentration of 3 g L -1 , 200 rpm and 25°C, from a 100 mg L -1 MBT solution. MBT degradation was found to occur mainly by the heterogeneous Fenton-like process.

  5. Investigation of Performance and Residual Stress Generation of AlSi10Mg Processed by Selective Laser Melting

    Directory of Open Access Journals (Sweden)

    Lianfeng Wang

    2018-01-01

    Full Text Available During the selective laser melting (SLM process, the scanned layers are subjected to rapid thermal cycles. By working on the mechanical properties, residual stress, and microstructure, the high-temperature gradients can have significant effect on the proper functioning and the structural integrity of built parts. This work presents a comprehensive study on the scanning path type and preheating temperature for AlSi10Mg alloy during SLM. According to the results, SLM AlSi10Mg parts fabricated in chessboard scanning strategy have higher mechanical properties or at least comparable to the parts fabricated in uniformity scanning strategy. In the SLM processing, the residual stress in different parts of the specimen varies with temperature gradient, and the residual stress at the edge of the specimen is obviously larger than that at the center. Under the chessboard scanning and preheating temperature 160°C, the residual stress in each direction of the specimens reaches the minimum. Under different forming processes, the morphology of the microstructure is obviously different. With the increase of preheating temperature, the molten pool in the side surface is obviously elongated and highly unevenly distributed. From the coupling relationship between the residual stress and microstructure, it can be found that the microstructure of top surface is affected by residual stresses σx and σy. But the side surface is mainly governed by residual stress σy; moreover, the greater the residual stress, the more obvious the grain tilt. In the XY and XZ surfaces, the scanning strategy has little influence on the tilt angle of the grain. But, the tilt angle and morphology of the microstructure are obviously affected by the preheating temperature. The results show that the residual stresses can effectively change the properties of the materials under the combined influence of scanning strategy and preheating temperature.

  6. Upgrading of automobile shredder residue via innovative granulation process 'ReGran'.

    Science.gov (United States)

    Holthaus, Philip; Kappes, Moritz; Krumm, Wolfgang

    2017-01-01

    Stricter regulatory requirements concerning end-of-life vehicles and rising disposal costs necessitate new ways for automobile shredder residue utilisation. The shredder granulate and fibres, produced by the VW-SICON-Process, have a high energy content of more than 20 MJ kg -1 , which makes energy recovery an interesting possibility. Shredder fibres have a low bulk density of 60 kg m -3 , which prevents efficient storing and utilisation as a refuse-derived fuel. By mixing fibres with plastic-rich shredder granulate and heating the mixture, defined granules can be produced. With this 'ReGran' process, the bulk density can be enhanced by a factor of seven by embedding shredder fibres in the partially melted plastic mass. A minimum of 26-33 wt% granulate is necessary to create enough melted plastic. The process temperature should be between 240 °C and 250 °C to assure fast melting while preventing extensive outgassing. A rotational frequency of the mixing tool of 1000 r min -1 during heating and mixing ensures a homogenous composition of the granules. During cooling, lower rotational frequencies generate bigger granules with particles sizes of up to 60 mm at 300 r min -1 . To keep outgassing to a minimum, it is suggested to melt shredder granulate first and then add shredder fibres. Adding coal, wood or tyre fluff as a third component reduces chlorine levels to less than 1 wt%. The best results can be achieved with tyre fluff. In combination with the VW-SICON-Process, ReGran produces a solid recovered fuel or 'design fuel' tailored to the requirements of specific thermal processes.

  7. The effectiveness of sewage treatment processes to remove faecal pathogens and antibiotic residues

    Science.gov (United States)

    Hendricks, Rahzia; Pool, Edmund John

    2012-01-01

    Pathogens and antibiotics enter the aquatic environment via sewage effluents and may pose a health risk to wild life and humans. The aim of this study was to determine the levels of faecal bacteria, and selected antibiotic residues in raw wastewater and treated sewage effluents from three different sewage treatment plants in the Western Cape, South Africa. Sewage treatment plant 1 and 2 use older technologies, while sewage treatment plant 3 has been upgraded and membrane technologies were incorporated in the treatment processes. Coliforms and Escherichia coli (E. coli) were used as bioindicators for faecal bacteria. A chromogenic test was used to screen for coliforms and E. coli. Fluoroquinolones and sulfamethoxazole are commonly used antibiotics and were selected to monitor the efficiency of sewage treatment processes for antibiotic removal. Enzyme Linked Immunosorbent Assays (ELISAs) were used to quantitate antibiotic residues in raw and treated sewage. Raw intake water at all treatment plants contained total coliforms and E. coli. High removal of E. coli by treatment processes was evident for treatment plant 2 and 3 only. Fluoroquinolones and sulfamethoxazole were detected in raw wastewater from all sewage treatment plants. Treatment processes at plant 1 did not reduce the fluoroquinolone concentration in treated sewage effluents. Treatment processes at plant 2 and 3 reduced the fluoroquinolone concentration by 21% and 31%, respectively. Treatment processes at plant 1 did not reduce the sulfamethoxazole concentration in treated sewage effluents. Treatment processes at plant 2 and 3 reduced sulfamethoxazole by 34% and 56%, respectively. This study showed that bacteria and antibiotic residues are still discharged into the environment. Further research needs to be undertaken to improve sewage treatment technologies, thereby producing a better quality treated sewage effluent. PMID:22242882

  8. Comprehensive Utilization of Filter Residue from the Preparation Process of Zeolite-Based Catalysts

    Directory of Open Access Journals (Sweden)

    Shu-Qin Zheng

    2016-05-01

    Full Text Available A novel utilization method of filter residue from the preparation process of zeolite-based catalysts was investigated. Y zeolite and a fluid catalytic cracking (FCC catalyst were synthesized from filter residue. Compared to the Y zeolite synthesized by the conventional method, the Y zeolite synthesized from filter residue exhibited better thermal stability. The catalyst possessed wide-pore distribution. In addition, the pore volume, specific surface area, attrition resistance were superior to those of the reference catalyst. The yields of gasoline and light oil increased by 1.93 and 1.48 %, respectively. At the same time, the coke yield decreased by 0.41 %. The catalyst exhibited better gasoline and coke selectivity. The quality of the cracked gasoline had been improved.

  9. Power generation with technology innovation of residual biomass utilization; Geracao de energia com inovacao tecnologica de aproveitamento de biomassa residual

    Energy Technology Data Exchange (ETDEWEB)

    Moura, Johnson Pontes de; Selvam, P.V. Pannir [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2006-07-01

    In the present work, the introduction of alternative energy of biogas in agricultural communities for the sustainable development was studied through exploitation of residual biomass and also getting as by-product the biological fertilizer. A fast composting of the domestic residue with the organic was made possible where part of this residue after processing was taken together with effluent to the biodigester. The bibliographical research on the processes of generation of biogas, about composting and the equipment for processing had been carried through. The projects engineering with the use of computational tools had been developed with the software Super Pro 4,9 Design and ORC GPEC 2004 by our research group. Five case studies had been elaborated, where different scenes related with our innovation, that uses of the residue for the composting together with domestic effluent for digestion. Several economic parameters were obtained and our work proved the viability about the use of biogas for drying of the fruits banana. A economic feasibility study was carried where it was proven that the project with the innovation of the use of residues from the fruits possess more advantages than the conventional system of drying using electric energy. Considering the viability of this process and the use solar energy, it is intended to apply this technology in rural agricultural communities providing them an energy source of low cost in substitution of the conventional energy. (author)

  10. Leaching Behavior of Circulating Fluidised Bed MSWI Air Pollution Control Residue in Washing Process

    Directory of Open Access Journals (Sweden)

    Zhiliang Chen

    2016-09-01

    Full Text Available In this study, air pollution control (APC residue is conducted with water washing process to reduce its chloride content. A novel electrical conductivily (EC measurement method is proposed to monitor the dynamic change of chloride concentrations in leachate as well as the chloride content of the residue. The method equally applies to various washing processes with different washing time, liquid/solid ratio and washing frequency. The results show that washing effectively extracts chloride salts from APC residues, including those from circulating fluidized bed (CFB municipal solid waste incineration (MSWI. The most appropriate liquid/solid ratio and washing time in the first washing are found to be around 4 L water per kg of APC residue and 30 min, respectively, and washing twice is required to obtain maximum dissolution. The pH value is the major controlling factor of the heavy metals speciation in leachate, while chloride concentration also affects the speciation of Cd. Water washing causes no perceptible transfer of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs from the APC residue to leachate. The chloride concentration is strongly related with electrical conductivity (EC, as well as with the concentrations of calcium, sodium and potassium of washing water. Their regression analyses specify that soluble chloride salts and EC could act as an indirect indicator to monitor the change of chloride concentration and remaining chloride content, thus, contributing to the selection of the optimal washing conditions.

  11. Reactive control processes contributing to residual switch cost and mixing cost across the adult lifespan.

    Science.gov (United States)

    Whitson, Lisa R; Karayanidis, Frini; Fulham, Ross; Provost, Alexander; Michie, Patricia T; Heathcote, Andrew; Hsieh, Shulan

    2014-01-01

    In task-switching paradigms, performance is better when repeating the same task than when alternating between tasks (switch cost) and when repeating a task alone rather than intermixed with another task (mixing cost). These costs remain even after extensive practice and when task cues enable advanced preparation (residual costs). Moreover, residual reaction time mixing cost has been consistently shown to increase with age. Residual switch and mixing costs modulate the amplitude of the stimulus-locked P3b. This mixing effect is disproportionately larger in older adults who also prepare more for and respond more cautiously on these "mixed" repeat trials (Karayanidis et al., 2011). In this paper, we analyze stimulus-locked and response-locked P3 and lateralized readiness potentials to identify whether residual switch and mixing cost arise from the need to control interference at the level of stimulus processing or response processing. Residual mixing cost was associated with control of stimulus-level interference, whereas residual switch cost was also associated with a delay in response selection. In older adults, the disproportionate increase in mixing cost was associated with greater interference at the level of decision-response mapping and response programming for repeat trials in mixed-task blocks. These findings suggest that older adults strategically recruit greater proactive and reactive control to overcome increased susceptibility to post-stimulus interference. This interpretation is consistent with recruitment of compensatory strategies to compensate for reduced repetition benefit rather than an overall decline on cognitive flexibility.

  12. HDHPLUS/SHP : heavy residue hydroconversion technology

    Energy Technology Data Exchange (ETDEWEB)

    Morel, F. [Axens, Rueil Malmaison (France)

    2009-07-01

    This presentation described an integrated refinery process that achieves nearly full conversion of heavy and refractory residues into ultra high quality and ultra low sulphur transportation fuels with a yield great than 100 volume per cent. The Axens, IFP and Intevep/PDVSA Alliance combined the HDHPLUS vacuum residue slurry technology with Sequential Hydro Processing (SHP) of primary hydrocracked products. Both technologies have undergone extensive testing at a refinery in Puerto La Cruz (RPLC), Venezuela to begin production of 50,000 BPSD in 2012. The demonstration unit at Intevep has been used to investigate production of effluent for the downstream SHP processing. This paper also reviewed the SHP bench unit operations at IFP's Lyon research center in France and disclosed the final product yields and qualities. The test results have shown the expected RPLC deep conversion commercial unit performances and fully secure its design basis. tabs., figs.

  13. Prediction of residue-residue contact matrix for protein-protein interaction with Fisher score features and deep learning.

    Science.gov (United States)

    Du, Tianchuan; Liao, Li; Wu, Cathy H; Sun, Bilin

    2016-11-01

    Protein-protein interactions play essential roles in many biological processes. Acquiring knowledge of the residue-residue contact information of two interacting proteins is not only helpful in annotating functions for proteins, but also critical for structure-based drug design. The prediction of the protein residue-residue contact matrix of the interfacial regions is challenging. In this work, we introduced deep learning techniques (specifically, stacked autoencoders) to build deep neural network models to tackled the residue-residue contact prediction problem. In tandem with interaction profile Hidden Markov Models, which was used first to extract Fisher score features from protein sequences, stacked autoencoders were deployed to extract and learn hidden abstract features. The deep learning model showed significant improvement over the traditional machine learning model, Support Vector Machines (SVM), with the overall accuracy increased by 15% from 65.40% to 80.82%. We showed that the stacked autoencoders could extract novel features, which can be utilized by deep neural networks and other classifiers to enhance learning, out of the Fisher score features. It is further shown that deep neural networks have significant advantages over SVM in making use of the newly extracted features. Copyright © 2016. Published by Elsevier Inc.

  14. Changes of Field Incurred Chlorpyrifos and Its Toxic Metabolite Residues in Rice during Food Processing from-RAC-to-Consumption

    Science.gov (United States)

    Zhang, Zhiyong; Jiang, Wayne W.; Jian, Qiu; Song, Wencheng; Zheng, Zuntao; Wang, Donglan; Liu, Xianjin

    2015-01-01

    The objectives of this study were to determine the effects of food processing on field incurred residues levels of chlorpyrifos and its metabolite 3,5,6-Trichloro-2-pyridinol (TCP) in rice. The chlorpyrifos and TCP were found to be 1.27 and 0.093 mg kg-1 in straw and 0.41 and 0.073 mg kg-1 in grain, respectively. It is observed that the sunlight for 2 hours does not decrease the chlorpyrifos and TCP residues in grain significantly. Their residues in rice were reduced by up to 50% by hulling. The cooking reduced the chlorpyrifos and TCP in rice to undetectable level (below 0.01 mg kg-1). Processing factors (PFs) of chlorpyrifos and TCP residues in rice during food processing were similar. Various factors have impacts on the fates of chlorpyrifos and TCP residues and the important steps to reduce their residues in rice were hulling and cooking. The results can contribute to assure the consumer of a safe wholesome food supply. PMID:25608031

  15. Model-Based Integrated Process Design and Controller Design of Chemical Processes

    DEFF Research Database (Denmark)

    Abd Hamid, Mohd Kamaruddin Bin

    that is typically formulated as a mathematical programming (optimization with constraints) problem is solved by the so-called reverse approach by decomposing it into four sequential hierarchical sub-problems: (i) pre-analysis, (ii) design analysis, (iii) controller design analysis, and (iv) final selection......This thesis describes the development and application of a new systematic modelbased methodology for performing integrated process design and controller design (IPDC) of chemical processes. The new methodology is simple to apply, easy to visualize and efficient to solve. Here, the IPDC problem...... are ordered according to the defined performance criteria (objective function). The final selected design is then verified through rigorous simulation. In the pre-analysis sub-problem, the concepts of attainable region and driving force are used to locate the optimal process-controller design solution...

  16. Effect of handling and processing on pesticide residues in food- a review.

    Science.gov (United States)

    Bajwa, Usha; Sandhu, Kulwant Singh

    2014-02-01

    Pesticides are one of the major inputs used for increasing agricultural productivity of crops. The pesticide residues, left to variable extent in the food materials after harvesting, are beyond the control of consumer and have deleterious effect on human health. The presence of pesticide residues is a major bottleneck in the international trade of food commodities. The localization of pesticides in foods varies with the nature of pesticide molecule, type and portion of food material and environmental factors. The food crops treated with pesticides invariably contain unpredictable amount of these chemicals, therefore, it becomes imperative to find out some alternatives for decontamination of foods. The washing with water or soaking in solutions of salt and some chemicals e.g. chlorine, chlorine dioxide, hydrogen peroxide, ozone, acetic acid, hydroxy peracetic acid, iprodione and detergents are reported to be highly effective in reducing the level of pesticides. Preparatory steps like peeling, trimming etc. remove the residues from outer portions. Various thermal processing treatments like pasteurization, blanching, boiling, cooking, steaming, canning, scrambling etc. have been found valuable in degradation of various pesticides depending upon the type of pesticide and length of treatment. Preservation techniques like drying or dehydration and concentration increase the pesticide content many folds due to concentration effect. Many other techniques like refining, fermentation and curing have been reported to affect the pesticide level in foods to varied extent. Milling, baking, wine making, malting and brewing resulted in lowering of pesticide residue level in the end products. Post harvest treatments and cold storage have also been found effective. Many of the decontamination techniques bring down the concentration of pesticides below MRL. However, the diminution effect depends upon the initial concentration at the time of harvest, substrate/food and type of

  17. Characterisation of agroindustrial solid residues as biofuels and potential application in thermochemical processes.

    Science.gov (United States)

    Virmond, Elaine; De Sena, Rennio F; Albrecht, Waldir; Althoff, Christine A; Moreira, Regina F P M; José, Humberto J

    2012-10-01

    In the present work, selected agroindustrial solid residues from Brazil - biosolids from meat processing wastewater treatment and mixture of sawdust with these biosolids; residues from apple and orange juice industries; sugarcane bagasse; açaí kernels (Euterpe oleracea) and rice husk - were characterised as solid fuels and an evaluation of their properties, including proximate and ultimate composition, energy content, thermal behaviour, composition and fusibility of the ashes was performed. The lower heating value of the biomasses ranged from 14.31 MJkg(-1) to 29.14 MJkg(-1), on a dry and ash free basis (daf), all presenting high volatile matter content, varying between 70.57 wt.% and 85.36 wt.% (daf) what improves the thermochemical conversion of the solids. The fouling and slagging tendency of the ashes was predicted based on the fuel ash composition and on the ash fusibility correlations proposed in the literature, which is important to the project and operation of biomass conversion systems. The potential for application of the Brazilian agroindustrial solid residues studied as alternative energy sources in thermochemical processes has been identified, especially concerning direct combustion for steam generation. Copyright © 2012 Elsevier Ltd. All rights reserved.

  18. Effects of coffee processing residues on anaerobic microorganisms and corresponding digestion performance.

    Science.gov (United States)

    Rojas-Sossa, Juan Pablo; Murillo-Roos, Mariana; Uribe, Lidieth; Uribe-Lorio, Lorena; Marsh, Terence; Larsen, Niels; Chen, Rui; Miranda, Alberto; Solís, Kattia; Rodriguez, Werner; Kirk, Dana; Liao, Wei

    2017-12-01

    The objective of this study was to delineate the effects of different coffee processing residues on the anaerobic microbes and corresponding digestion performance. The results elucidated that mucilage-rich feed enhanced the accumulation of methanogens, which consequently led to better digestion performance of biogas production. Fifty percent more methane and up to 3 times more net energy (heat and electricity) output were achieved by the digestion of the mucilage-rich feed (M3). The microbial community and statistical analyses further elucidated that different residues in the feed had significant impact on microbial distribution and correspondingly influenced the digestion performance. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Biogas systems for sisal and other agro-industrial residues

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G [Danish Technological Inst., Section for Biotechnology, Taastrup (Denmark)

    1998-12-31

    Most of the East-African agro-industries are generating very large quantities of organic residues from production and processing of different crops. In the East-African Region the most important of these crops are: Sisal, Sugar, Coffee, Cashew nuts and Pineapple. In other 3. world countries, Palm oil and Cassava (Tapioca starch) processing are main producers of organic waste products. Moreover, large quantities of organic residues are generated from other food processing activities like breweries, consumption of bananas etc. The following pages give examples of setups and system designs of anaerobic treatment systems for some of the residues mentioned above. When considering anaerobic treatment of sisal residues, which constitutes the main agro-industrial biomass resource in Tanzania, two major issues should be considered: Optimal reactor set-up and performance; And optionally, potential methods for pre-treatment of fibre fraction in order to increase the methane yield. The sisal liquid residues are degraded very fast and efficiently in UASB systems. At COD loading rates less than 11 kg COD/m{sup 3} x day, the reduction in organic matter is more than 90% and methane yields obtained are between 373 and 377 ml CH{sub 4}/g COD reduced. The treatment of sisal solid residues in CSTR systems has been examined both at mesophilic (37 deg. C) and thermophilic temperatures (55 deg. C.). (EG)

  20. Biogas systems for sisal and other agro-industrial residues

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G. [Danish Technological Inst., Section for Biotechnology, Taastrup (Denmark)

    1997-12-31

    Most of the East-African agro-industries are generating very large quantities of organic residues from production and processing of different crops. In the East-African Region the most important of these crops are: Sisal, Sugar, Coffee, Cashew nuts and Pineapple. In other 3. world countries, Palm oil and Cassava (Tapioca starch) processing are main producers of organic waste products. Moreover, large quantities of organic residues are generated from other food processing activities like breweries, consumption of bananas etc. The following pages give examples of setups and system designs of anaerobic treatment systems for some of the residues mentioned above. When considering anaerobic treatment of sisal residues, which constitutes the main agro-industrial biomass resource in Tanzania, two major issues should be considered: Optimal reactor set-up and performance; And optionally, potential methods for pre-treatment of fibre fraction in order to increase the methane yield. The sisal liquid residues are degraded very fast and efficiently in UASB systems. At COD loading rates less than 11 kg COD/m{sup 3} x day, the reduction in organic matter is more than 90% and methane yields obtained are between 373 and 377 ml CH{sub 4}/g COD reduced. The treatment of sisal solid residues in CSTR systems has been examined both at mesophilic (37 deg. C) and thermophilic temperatures (55 deg. C.). (EG)

  1. Analytical study of residual stress improvement method, delta-T process for small-diameter pipe

    International Nuclear Information System (INIS)

    Tsuruki, Masaki; Aoike, Satoru; Okido, Shinobu; Fukuda, Yuka; Oritani, Naohiko

    2012-01-01

    In order to prevent initiation of stress corrosion cracking (SCC) at the inner surface of the butt-weld region of a small-diameter pipe, a residual stress improvement process called delta-T process has been developed. During delta-T process, the outer surface of pipe is heated by an external device and the inner surface is rapidly cooled by flashing water. The large thermal stress due to temperature difference between outer and inner surface could improve tensile stress to compressive one at inner surface. In this paper, the thermal elasto-plastic finite element analysis (FEA) was conducted to clarify the mechanism of delta-T process for piping system with 50A schedule 80 in nominal pipe size. The FEA results showed good agreements with experimentally measurements of temperature and residual stress in delta-T process. In addition, the management criterion to verify the application of delta-T process to piping system by measurement of temperature at outer surface of pipe was discussed by various parametric numerical analyses. (author)

  2. Design and transient analyses of emergency passive residual heat removal system of CPR1000

    International Nuclear Information System (INIS)

    Zhang, Y.P.; Qiu, S.Z.; Su, G.H.; Tian, W.X.

    2012-01-01

    Highlights: ► Designing an EPRHRs for CPR1000. ► Developing a RELAP model of the EPRHRs. ► The EPRHRs could take away the decay heat effectively. - Abstract: The steam generator secondary emergency passive residual heat removal system (EPRHRs) is a new design for traditional generation II + reactor CPR1000. The EPRHRs is designed to improve the safety and reliability of CPR1000 by completely or partially replacing traditional emergency water cooling system in the event of the station blackout or loss of heat sink accident. The EPRHRs consists of steam generator (SG), heat exchanger (HX), emergency makeup tank (EMT), cooling water tank (CWT), and corresponding pipes and valves. In order to improve the safety and reliability of CPR1000, the model of the primary loop and the EPRHRs was developed to investigate residual heat removal capability of the EPRHRs and the transient characteristics of the primary loop affected by the EPRHRs using RELAP5/MOD3.4. The transient characteristics of the primary loop and the EPRHRs were calculated in the event of station blackout accident. Sensitivity studies of the EPRHRs were also conducted to investigate the response of the primary loop and the EPRHRs on the main parameters of the EPRHRs. The EPRHRs could supply water to the SG shell side from the EMT successfully. The calculation results showed that the EPRHRs could take away the decay heat from the primary loop effectively, and that the single-phase and two-phase natural circulations were established in the primary loop and EPRHRs loop, respectively. The results also indicated that the effect of isolation valve open time on the transient characteristics of the primary loop was little. However, the effect of isolation valve open time on the EPRHRs condensate flow was relatively greater. The isolation valves should not be opened too rapidly during the isolation valve opening process, and the isolation valve opening time should be greater than 10 s, which could avoid the

  3. Residue-free wines: fate of some quinone outside inhibitor (QoI) fungicides in the winemaking process.

    Science.gov (United States)

    Garau, Vincenzo Luigi; De Melo Abreu, Susana; Caboni, Pierluigi; Angioni, Alberto; Alves, Arminda; Cabras, Paolo

    2009-03-25

    The fate of three fungicide residues (fenamidone, pyraclostrobin, and trifloxystrobin) from vine to wine was studied to evaluate the decay ratio and the influence of the technological process. The aim of this work was to identify pesticides that can degrade rapidly or be eliminated together with byproduct (lees and cake) of the winemaking process to obtain wine free of residues. The disappearance rate on grapes was calculated as pseudo-first-order kinetics, and the half-life (t(1/2)) was in the range from 5.4 +/- 1.9 to 12.2 +/- 1.2 days. The mechanism of dissipation of the three quinone outside inhibitor (QoI) fungicides was studied using different model systems. It was observed that the main mechanism responsible for disappearance was photodegradation. For active ingredients (ai) the half-lives of fenamidone, pyraclostrobin, and trifloxystrobin were 10.2 +/- 0.8, 20.1 +/- 0.1, and 8.6 +/- 1.0 h, respectively, whereas for formulation higher half-lives were observed when epicuticular waxes were present (from 13.8 +/- 0.2 to 26.6 +/- 0.1 h). After winemaking, fenamidone, pyraclostrobin, and trifloxystrobin residues were not detected in the wine, but they were present in the cake and lees. This was due to the adsorption of pesticide residues to the solid parts, which are always eliminated at the end of the alcoholic fermentation. The data obtained in these experiments suggest that these three active ingredients could be used in a planning process to obtain residue-free wines.

  4. Process combination of thermo pressure hydrolysis and fermentation for innovative processing of residual biogenous mass; Verfahrenskombination aus Thermodruckhydrolyse und Vergaerung zur innovativen Verwertung biogener Restmassen

    Energy Technology Data Exchange (ETDEWEB)

    Prechtl, S.; Merkl, M.; Schieder, D.; Schneider, R.; Bischof, F. [Applikations- und Technikzentrum fuer Energieverfahrens-, Umwelt- und Stroemungstechnik (ATZ-EVUS), Sulzbach-Rosenberg (Germany)

    1999-07-01

    The described processing technique consisting of topped thermal hydrolysis and downstream fermentation is particularly suitable for wet, low-structure organic waste. High turnover rates at short treatment times permit to minimize residues effectively, yield a fair amount of biogas and allow compact design because of low fermenter volumes, which has a positive impact on investment cost. (orig.) [German] Das vorgestellt Verwertungsverfahren bestehend aus vorgeschalteter thermischer Hydrolyse und nachgeschalteter Vergaerung eignet sich besonders fuer nasse, strukturarme organische Abfaelle. Hohe Umsatzraten bei kurzen Behandlungszeiten ermoeglichen eine gute Reststoffminimierung und Biogasausbeute sowie eine kompakte Bauweise durch kleine Fermentervolumina, was sich positiv auf die Investitionskosten auswirkt. (orig.)

  5. Conceptual design of a calorimeter and residual ion dump for the ITER negative ion injectors

    International Nuclear Information System (INIS)

    Watson, M.

    1998-01-01

    A conceptual design for the ITER Negative Ion Injectors' Calorimeter and Residual Ion Dump systems has been carried out. The work was undertaken in support of detailed studies performed by the Russian Federation. Concepts for both systems incorporate actively water cooled hypervapotrons as the primary beam stopping elements. The Calorimeter drive has been based on the utilisation of a novel force translation system via magnetic coupling. The Residual Ion Dump necessitates the use of double sided hypervapotron elements in order to cater for the restricted space envelope defined by the Accelerator Grid hole pattern. (author)

  6. Optimizing biomass feedstock logistics for forest residue processing and transportation on a tree-shaped road network

    Science.gov (United States)

    Hee Han; Woodam Chung; Lucas Wells; Nathaniel Anderson

    2018-01-01

    An important task in forest residue recovery operations is to select the most cost-efficient feedstock logistics system for a given distribution of residue piles, road access, and available machinery. Notable considerations include inaccessibility of treatment units to large chip vans and frequent, long-distance mobilization of forestry equipment required to process...

  7. A Study on Fatigue Design Automation of Plug- and Ring-type Gas-welded Joints of STS301L Taking Welded Residual Stress into Account

    International Nuclear Information System (INIS)

    Baek, Seung yeb; Yun, Ki Ho

    2010-01-01

    This paper presents a fatigue design method for plug- and ring-type gas-welded joints, which takes into account the effects of welding residual stress. To develop this method, we simulated the gas-welding process by performing nonlinear finite element analysis (FEA) To validate the FEA results, numerically calculated residual stresses in the gas welds were then compared with experimental results obtained by the hole-drilling method. To evaluate the fatigue strength of plug- and ring-type gas-welded joints influenced by welding residual stresses, the use of stress amplitude (σ a )R, which includes the welding residual stress in gas welds, is proposed (σ a )R on the basis of a modified Goodman equation that includes the residual stress effects. Using the stress amplitude (σ a )R at the hot spot point of gas weld, the relations obtained as the fatigue test results for plug and ring type gas welded joints having various dimensions and shapes were systematically rearranged to obtain the (σ a )R-N f relationship. It was found that more systematic and accurate evaluation of the fatigue strength of plug- and ring-type gas-welded joints can be achieved by using (σ a )R

  8. Influence of the residual oxygen in the plasma immersion ion implantation (PI3) processing of materials

    International Nuclear Information System (INIS)

    Ueda, M.; Silva, A.R.; Mello, Carina B.; Silva, G.; Reuther, H.; Oliveira, V.S.

    2011-01-01

    In this work, we investigated the effects of the contaminants present in the vacuum chamber of the PI3 system, in particular, the residual oxygen, which results in the formation of the oxide compounds on the surface and hence is responsible for the high implantation energies required to achieve reasonably thick treated layers. We used a mass spectrometer (RGA) with a quadruple filter to verify the composition of the residual vacuum and pressure of the elements present in the chamber. Initially we found a high proportion of residual oxygen in a vacuum with a pressure of 1 × 10 −3 Pa. Minimizing the residual oxygen percentage in about 80%, by efficient cleaning of the chamber walls and by improving the gas feeding process, we mitigated the formation of oxides during the PI3 process. Therefore we achieved a highly efficient PI3 processing obtaining implanted layers reaching about 50 nm, even in cases such as an aluminum alloy, where is very difficult to nitrogen implant at low energies. We performed nitrogen PI3 treatment of SS304 and Al7075 using pulses of only 3 kV and 15 × 10 −6 s at 1 kHz with an operating pressure of 1 Pa.

  9. Expression regulation of design process gene in product design

    DEFF Research Database (Denmark)

    Li, Bo; Fang, Lusheng; Li, Bo

    2011-01-01

    To improve the design process efficiency, this paper proposes the principle and methodology that design process gene controls the characteristics of design process under the framework of design process reuse and optimization based on design process gene. First, the concept of design process gene...... is proposed and analyzed, as well as its three categories i.e., the operator gene, the structural gene and the regulator gene. Second, the trigger mechanism that design objectives and constraints trigger the operator gene is constructed. Third, the expression principle of structural gene is analyzed...... with the example of design management gene. Last, the regulation mode that the regulator gene regulates the expression of the structural gene is established and it is illustrated by taking the design process management gene as an example. © (2011) Trans Tech Publications....

  10. A combined process of adsorption and Fenton-like oxidation for furfural removal using zero-valent iron residue.

    Science.gov (United States)

    Li, Furong; Bao, Jianguo; Zhang, Tian C; Lei, Yutian

    2015-01-01

    In this study, the feasibility of using a combined adsorption and Fenton-like oxidation process (with zero-valent iron (ZVI) residue from heat wraps as an absorbent and catalyst) to remove furfural in the solution was evaluated. The influencing parameters (e.g. pH, H2O2 concentration, initial furfural concentration) and the reusability of ZVI residue (to replace the iron powder) were estimated. The ZVI residue was found to have much better adsorption effect on furfural at pH 2.0 compared with pH 6.7. For Fenton-like reaction alone with ZVI residue, the highest furfural removal of 97.5% was observed at the concentration of 0.176 mol/L H2O2, and all of the samples had >80% removal efficiency at different initial furfural concentrations of 2, 10, 20, 30 and 40 mmol/L. However, with a combined adsorption and Fenton-like oxidation, the removal efficiency of furfural was nearly 100% for all treatments. The ZVI residue used for furfural removal was much better than that of iron powder in the Fenton-like reaction at a seven-cycle experiment. This study suggests the combined process of adsorption and Fenton-like oxidation using ZVI residue is effective for the treatment of furfural in the liquid.

  11. Residual Neural Processing of Musical Sound Features in Adult Cochlear Implant Users

    Science.gov (United States)

    Timm, Lydia; Vuust, Peter; Brattico, Elvira; Agrawal, Deepashri; Debener, Stefan; Büchner, Andreas; Dengler, Reinhard; Wittfoth, Matthias

    2014-01-01

    Auditory processing in general and music perception in particular are hampered in adult cochlear implant (CI) users. To examine the residual music perception skills and their underlying neural correlates in CI users implanted in adolescence or adulthood, we conducted an electrophysiological and behavioral study comparing adult CI users with normal-hearing age-matched controls (NH controls). We used a newly developed musical multi-feature paradigm, which makes it possible to test automatic auditory discrimination of six different types of sound feature changes inserted within a musical enriched setting lasting only 20 min. The presentation of stimuli did not require the participants’ attention, allowing the study of the early automatic stage of feature processing in the auditory cortex. For the CI users, we obtained mismatch negativity (MMN) brain responses to five feature changes but not to changes of rhythm, whereas we obtained MMNs for all the feature changes in the NH controls. Furthermore, the MMNs to deviants of pitch of CI users were reduced in amplitude and later than those of NH controls for changes of pitch and guitar timber. No other group differences in MMN parameters were found to changes in intensity and saxophone timber. Furthermore, the MMNs in CI users reflected the behavioral scores from a respective discrimination task and were correlated with patients’ age and speech intelligibility. Our results suggest that even though CI users are not performing at the same level as NH controls in neural discrimination of pitch-based features, they do possess potential neural abilities for music processing. However, CI users showed a disrupted ability to automatically discriminate rhythmic changes compared with controls. The current behavioral and MMN findings highlight the residual neural skills for music processing even in CI users who have been implanted in adolescence or adulthood. Highlights: -Automatic brain responses to musical feature changes

  12. Conditioning of radioactive ash residue in a wave of solid-phase exothermal reactions

    International Nuclear Information System (INIS)

    Karlina, O.K.; Varlakova, G.A.; Ozhovan, M.I.; Tivanskij, V.M.; Dmitriev, S.A.

    2001-01-01

    The abilities for utilization of exothermic reaction heat in solid phase for conditioning the ash residue produced as a result of solid radioactive waste burning are analyzed. It is shown that the process of ash residue making monolithic with obtaining the glass-like finish product containing 50-60 mass % of ash residue which meets the requirements for solidified radioactive wastes may be realized without energy supplying from external heat sources. The conditioning is realized in a special crucible furnace-container designed not only for the process conducting but also for subsequent storage or disposal of the finish product [ru

  13. Concept Design of a Gravity Core Cooling Tank as a Passive Residual Heat Removal System for a Research Reactor

    International Nuclear Information System (INIS)

    Lee, Kwonyeong; Chi, Daeyoung; Kim, Seong Hoon; Seo, Kyoungwoo; Yoon, Juhyeon

    2014-01-01

    A core downward flow is considered to use a plate type fuel because it is benefit to install the fuel in the core. If a flow inversion from a downward to upward flow in the core by a natural circulation is introduced within a high heat flux region of residual heat, the fuel fails instantly due to zero flow. Therefore, the core downward flow should be sufficiently maintained until the residual heat is in a low heat flux region. In a small power research reactor, inertia generated by a flywheel of the PCP can maintain a downward flow shortly and resolve the problem of a flow inversion. However, a high power research reactor more than 10 MW should have an additional method to have a longer downward flow until a low heat flux. Usually, other research reactors have selected an active residual heat removal system as a safety class. But, an active safety system is difficult to design and expensive to construct. A Gravity Core Cooling Tank (GCCT) beside the reactor pool with a Residual Heat Removal Pipe connecting two pools was developed and designed preliminarily as a passive residual heat removal system for an open-pool type research reactor. It is very simple to design and cheap to construct. Additionally, a non-safety, but active residual heat removal system is applied with the GCCT. It is a Pool Water Cooling and Purification System. It can improve the usability of the research reactor by removing the thermal waves, and purify the reactor pool, the Primary Cooling System, and the GCCT. Moreover, it can reduce the pool top radiation level

  14. Design of A District Heating System Including The Upgrading of Residual Industrial Waste Heat

    NARCIS (Netherlands)

    Falcao, P.W.; Mesbah, A.; Suherman, M.V.; Wennekes, S.

    2005-01-01

    This study was aimed to evaluate the feasibility of using a waste heat stream from DSM for a District Heating System. A conceptual design was carried out with emphasis on the unit for upgrading the residual waste heat. Having reviewed heat pump technology, mechanical heat pump was found to be the

  15. Verification and Validation of Residual Stresses in Bi-Material Composite Rings

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Stacy Michelle [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Hanson, Alexander Anthony [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Briggs, Timothy [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Werner, Brian T. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2017-07-01

    Process-induced residual stresses commonly occur in composite structures composed of dissimilar materials. These residual stresses form due to differences in the composite materials’ coefficients of thermal expansion and the shrinkage upon cure exhibited by polymer matrix materials. Depending upon the specific geometric details of the composite structure and the materials’ curing parameters, it is possible that these residual stresses could result in interlaminar delamination or fracture within the composite. Therefore, the consideration of potential residual stresses is important when designing composite parts and their manufacturing processes. However, the experimental determination of residual stresses in prototype parts can be time and cost prohibitive. As an alternative to physical measurement, it is possible for computational tools to be used to quantify potential residual stresses in composite prototype parts. Therefore, the objectives of the presented work are to demonstrate a simplistic method for simulating residual stresses in composite parts, as well as the potential value of sensitivity and uncertainty quantification techniques during analyses for which material property parameters are unknown. Specifically, a simplified residual stress modeling approach, which accounts for coefficient of thermal expansion mismatch and polymer shrinkage, is implemented within the Sandia National Laboratories’ developed SIERRA/SolidMechanics code. Concurrent with the model development, two simple, bi-material structures composed of a carbon fiber/epoxy composite and aluminum, a flat plate and a cylinder, are fabricated and the residual stresses are quantified through the measurement of deformation. Then, in the process of validating the developed modeling approach with the experimental residual stress data, manufacturing process simulations of the two simple structures are developed and undergo a formal verification and validation process, including a mesh

  16. Detection of pyridaben residue levels in hot pepper fruit and leaves by liquid chromatography-tandem mass spectrometry: effect of household processes.

    Science.gov (United States)

    Kim, Sung-Woo; Abd El-Aty, A M; Rahman, Md Musfiqur; Choi, Jeong-Heui; Choi, Ok-Ja; Rhee, Gyu-Seek; Chang, Moon-Ik; Kim, Heejung; Abid, Morad D N; Shin, Sung Chul; Shim, Jae-Han

    2015-07-01

    Following quick, easy, cheap, effective, rugged and safe (QuEChERS) and LC/MS/MS analysis, pyridaben residual levels were determined in unprocessed and processed hot pepper fruit and leaves. The linearities were satisfactory with determination coefficients (R(2)) in excess of 0.995 in processed and unprocessed pepper fruit and leaves. Recoveries at various concentrations were 79.9-105.1% with relative standard deviations ≤15%. The limits of quantitation of 0.003-0.012 mg/kg were very low compared with the maximum residue limits (2-5 mg/kg) set by the Ministry of Food and Drug Safety, Republic of Korea. The effects of various household processes, including washing, blanching, frying and drying under different conditions (water volume, blanching time and temperature) on residual concentrations were evaluated. Both washing and blanching (in combination with high water volume and time factor) significantly reduced residue levels in hot pepper fruit and leaves compared with other processes. In sum, the developed method was satisfactory and could be used to accurately detect residues in unprocessed and processed pepper fruit and leaves. It is recommended that pepper fruit/leaves be blanched after washing before being consumed to protect consumers from the negative health effects of detected pesticide residues. Copyright © 2014 John Wiley & Sons, Ltd.

  17. Stability of tetrachlorvinphos residues in faba beans and soya bean oil towards different processing procedures

    International Nuclear Information System (INIS)

    Zayed, S.M.A.D.; Farghaly, M.

    1987-01-01

    Cooking of contaminated faba beans did not degrade the originally present potentially toxic residues, namely, tetrachlorvinphos and its desmethyl derivative to any appreciable extent. Processing of contaminated soya bean oil, on the other hand, led to degradation of tetrachlorvinphos and its metabolites to give mono and dimethyl phosphates. Feeding of mice with bound residues of tetrachlorvinphos in beans for 90 days led to an apparent decrease in the rate of body weight gain. (author)

  18. Conversion of plutonium scrap and residue to boroilicate glass using the GMODS process

    International Nuclear Information System (INIS)

    Forsberg, C.W.; Beahm, E.C.; Parker, G.W.; Rudolph, J.; Elam, K.R.; Ferrada, J.J.

    1995-01-01

    Plutonium scrap and residue represent major national and international concerns because (1) significant environmental, safety, and health (ES ampersand H) problems have been identified with their storage; (2) all plutonium recovered from the black market in Europe has been from this category; (3) storage costs are high; and (4) safeguards are difficult. It is proposed to address these problems by conversion of plutonium scrap and residue to a CRACHIP (CRiticality, Aerosol, and CHemically Inert Plutonium) glass using the Glass Material Oxidation and Dissolution System (GMODS). CRACHIP refers to a set of requirements for plutonium storage forms that minimize ES ampersand H concerns. The concept is several decades old. Conversion of plutonium from complex chemical mixtures and variable geometries into a certified, qualified, homogeneous CRACHIP glass creates a stable chemical form that minimizes ES ampersand H risks, simplifies safeguards and security, provides an easy-to-store form, decreases storage costs, and allows for future disposition options. GMODS is a new process to directly convert metals, ceramics, and amorphous solids to glass; oxidize organics with the residue converted to glass; and convert chlorides to borosilicate glass and a secondary sodium chloride stream. Laboratory work has demonstrated the conversion of cerium (a plutonium surrogate), uranium (a plutonium surrogate), Zircaloy, stainless steel, and other materials to glass. GMODS is an enabling technology that creates new options. Conventional glassmaking processes require conversion of feeds to oxide-like forms before final conversion to glass. Such chemical conversion and separation processes are often complex and expensive

  19. Residual fMRI sensitivity for identity changes in acquired prosopagnosia.

    Science.gov (United States)

    Fox, Christopher J; Iaria, Giuseppe; Duchaine, Bradley C; Barton, Jason J S

    2013-01-01

    While a network of cortical regions contribute to face processing, the lesions in acquired prosopagnosia are highly variable, and likely result in different combinations of spared and affected regions of this network. To assess the residual functional sensitivities of spared regions in prosopagnosia, we designed a rapid event-related functional magnetic resonance imaging (fMRI) experiment that included pairs of faces with same or different identities and same or different expressions. By measuring the release from adaptation to these facial changes we determined the residual sensitivity of face-selective regions-of-interest. We tested three patients with acquired prosopagnosia, and all three of these patients demonstrated residual sensitivity for facial identity changes in surviving fusiform and occipital face areas of either the right or left hemisphere, but not in the right posterior superior temporal sulcus. The patients also showed some residual capabilities for facial discrimination with normal performance on the Benton Facial Recognition Test, but impaired performance on more complex tasks of facial discrimination. We conclude that fMRI can demonstrate residual processing of facial identity in acquired prosopagnosia, that this adaptation can occur in the same structures that show similar processing in healthy subjects, and further, that this adaptation may be related to behavioral indices of face perception.

  20. Residual fMRI sensitivity for identity changes in acquired prosopagnosia

    Directory of Open Access Journals (Sweden)

    Christopher J Fox

    2013-10-01

    Full Text Available While a network of cortical regions contribute to face processing, the lesions in acquired prosopagnosia are highly variable, and likely result in different combinations of spared and affected regions of this network. To assess the residual functional sensitivities of spared regions in prosopagnosia, we designed a rapid event-related functional magnetic resonance imaging (fMRI experiment that included pairs of faces with same or different identities and same or different expressions. By measuring the release from adaptation to these facial changes we determined the residual sensitivity of face-selective regions-of-interest. We tested three patients with acquired prosopagnosia, and all three of these patients demonstrated residual sensitivity for facial identity changes in surviving fusiform and occipital face areas of either the right or left hemisphere, but not in the right posterior superior temporal sulcus. The patients also showed some residual capabilities for facial discrimination with normal performance on the Benton Facial Recognition Test, but impaired performance on more complex tasks of facial discrimination. We conclude that fMRI can demonstrate residual processing of facial identity in acquired prosopagnosia, that this adaptation can occur in the same structures that show similar processing in healthy subjects, and further, that this adaptation may be related to behavioral indices of face perception.

  1. Lifetime and residual strength of materials

    DEFF Research Database (Denmark)

    Nielsen, Lauge Fuglsang

    1997-01-01

    of load amplitude, load average, fractional time under maximum load, and load frequency.The analysis includes prediction of residual strength (re-cycle strength) during the process of load cycling. It is concluded that number of cycles to failure is a very poor design criterion. It is demonstrated how...... the theory developed can be generalized also to consider non-harmonic load variations.Algorithms are presented for design purposes which may be suggested as qualified alternatives to the Palmgren-Miner's methods normally used in fatigue analysis of materials under arbitrary load variations. Prediction...

  2. The Critical Design Process

    DEFF Research Database (Denmark)

    Brunsgaard, Camilla; Knudstrup, Mary-Ann; Heiselberg, Per

    2014-01-01

    within Danish tradition of architecture and construction. The objective of the research presented in this paper, is to compare the different design processes behind the making of passive houses in a Danish context. We evaluated the process with regard to the integrated and traditional design process....... Data analysis showed that the majority of the consortiums worked in an integrated manner; though there was room for improvment. Additionally, the paper discusses the challanges of implementing the integrated design process in practice and suggests ways of overcomming some of the barriers . In doing so...

  3. Study for process and equipment design of wet gelation stages in vibropacking process

    International Nuclear Information System (INIS)

    Tanimoto, Ryoji; Kikuchi, Toshiaki; Tanaka, Hirokazu; Amino, Masaki; Yanai, Minoru

    2004-02-01

    Process and layout design of external wet gelation stages in vibropacking process was examined for the feasibility study of commercialized FBR cycle system. In this study, following process stages for the oxide core fuel production line were covered, that is, solidification, washing, drying, calcination, reduction, sintering stages including interim storage of sintering particles and reagent recovery stage. The main results obtained by this study are as follows: (1) Based on the process examination results conducted previously, process-flow, mass-balance and number of production line/equipment were clarified. The process is covered from the receive tank of feed solution to the interim storage equipment. Reagent recovery process-flow, mass-balance were also clarified. And preliminary design of the main equipment was reexamined. (2) Normal operation procedure and the procedure after process failure were summarized along with a remote automated operation procedure. Operation sequence of each production line was mapped out by using a time-chart. (3) Design outline of reagent recovery equipments, installed to recover waste liquid from the wet gelation stages in the view of environmental impact were examined. Effective techniques such as collection of solvent, residue waste treatment method were examined its applicability and selected. Schematic block diagram was presented. (4) Analytical items and analyzing apparatus were extracted taking into account of quality control and process management. Analytical sample taking position and frequency of sampling were also examined. (5) A schematic layout drawing of main manufacturing process and reagent recovery process was presented taking into account of material handling. (6) A feature of the operating rate at each process stage was examined by analyzing failure rate reliability of each component. applying the reliability-centred method. (RCM), the operating rate was evaluated and annual maintenance period was estimated using

  4. Composite Cure Process Modeling and Simulations using COMPRO(Registered Trademark) and Validation of Residual Strains using Fiber Optics Sensors

    Science.gov (United States)

    Sreekantamurthy, Thammaiah; Hudson, Tyler B.; Hou, Tan-Hung; Grimsley, Brian W.

    2016-01-01

    Composite cure process induced residual strains and warping deformations in composite components present significant challenges in the manufacturing of advanced composite structure. As a part of the Manufacturing Process and Simulation initiative of the NASA Advanced Composite Project (ACP), research is being conducted on the composite cure process by developing an understanding of the fundamental mechanisms by which the process induced factors influence the residual responses. In this regard, analytical studies have been conducted on the cure process modeling of composite structural parts with varied physical, thermal, and resin flow process characteristics. The cure process simulation results were analyzed to interpret the cure response predictions based on the underlying physics incorporated into the modeling tool. In the cure-kinetic analysis, the model predictions on the degree of cure, resin viscosity and modulus were interpreted with reference to the temperature distribution in the composite panel part and tool setup during autoclave or hot-press curing cycles. In the fiber-bed compaction simulation, the pore pressure and resin flow velocity in the porous media models, and the compaction strain responses under applied pressure were studied to interpret the fiber volume fraction distribution predictions. In the structural simulation, the effect of temperature on the resin and ply modulus, and thermal coefficient changes during curing on predicted mechanical strains and chemical cure shrinkage strains were studied to understand the residual strains and stress response predictions. In addition to computational analysis, experimental studies were conducted to measure strains during the curing of laminated panels by means of optical fiber Bragg grating sensors (FBGs) embedded in the resin impregnated panels. The residual strain measurements from laboratory tests were then compared with the analytical model predictions. The paper describes the cure process

  5. Effect of residual H2O2 from advanced oxidation processes on subsequent biological water treatmen : A laboratory batch study

    NARCIS (Netherlands)

    Wang, F.; van Halem, D.; Liu, G.; Lekkerkerker-Teunissen, K.; van der Hoek, J.P.

    2017-01-01

    H2O2 residuals from advanced oxidation processes (AOPs) may have critical impacts on the microbial ecology and performance of subsequent biological treatment processes, but little is known. The objective of this study was to evaluate how H2O2 residuals influence sand systems with an emphasis on

  6. Behavioural design: A process for integrating behaviour change and design

    DEFF Research Database (Denmark)

    Cash, Philip; Hartlev, Charlotte Gram; Durazo, Christine Boysen

    2017-01-01

    Nudge, persuasion, and the influencing of human behaviour through design are increasingly important topics in design research and in the wider public consciousness. However, current theoretical approaches to behaviour change have yet to be operationalized this in design process support....... Specifically, there are few empirically grounded processes supporting designers in realising behaviour change projects. In response to this, 20 design projects from a case company are analysed in order to distil a core process for behavioural design. Results show a number of process stages and activities...... associated with project success, pointing to a new perspective on the traditional design process, and allowing designers to integrate key insights from behaviour change theory. Using this foundation we propose the Behavioural Design process....

  7. Optimizing Biomass Feedstock Logistics for Forest Residue Processing and Transportation on a Tree-Shaped Road Network

    Directory of Open Access Journals (Sweden)

    Hee Han

    2018-03-01

    Full Text Available An important task in forest residue recovery operations is to select the most cost-efficient feedstock logistics system for a given distribution of residue piles, road access, and available machinery. Notable considerations include inaccessibility of treatment units to large chip vans and frequent, long-distance mobilization of forestry equipment required to process dispersed residues. In this study, we present optimized biomass feedstock logistics on a tree-shaped road network that take into account the following options: (1 grinding residues at the site of treatment and forwarding ground residues either directly to bioenergy facility or to a concentration yard where they are transshipped to large chip vans, (2 forwarding residues to a concentration yard where they are stored and ground directly into chip vans, and (3 forwarding residues to a nearby grinder location and forwarding the ground materials. A mixed-integer programming model coupled with a network algorithm was developed to solve the problem. The model was applied to recovery operations on a study site in Colorado, USA, and the optimal solution reduced the cost of logistics up to 11% compared to the conventional system. This is an important result because this cost reduction propagates downstream through the biomass supply chain, reducing production costs for bioenergy and bioproducts.

  8. Utilization of residue from cassava starch processing for production of fermentable sugar by enzymatic hydrolysis

    Directory of Open Access Journals (Sweden)

    Luciana Reis Fontinelle SOUTO

    Full Text Available Abstract The aim of this study was to characterize and perform enzymatic hydrolysis of cassava peeling residue (peel and inner peel, mainly composed of peels and small pieces. Residue was sanitized, dried at 55 °C for 24 hours and ground. The obtained flour showed pH of 4.85; 72.53 g 100 g–1 moisture; 5.18 mL 1M NaOH 100 g–1 acidity; 60.68 g 100 g–1 starch; 1.08 g 100 g–1 reducing sugar; 1.63 g 100g–1 ash; 0.86 g 100 g–1 lipid and 3.97 g 100 g–1 protein. Enzymatic hydrolysis was carried out by means of rotational central composite design, analyzing the effects of concentrations of α-amylase enzyme (10 to 50 U g starch–1, and the amyloglucosidase enzyme (80 to 400 U g starch–1 on variable responses: percent conversion of starch into reducing sugars (RSC and soluble solid content (SS. Highest values of RSC (110% and SS (12 °Brix were observed when using the maximum concentration of amyloglucosidase and throughout the concentration range of α-amylase. Enzymatic hydrolysis of cassava peel is feasible and allows the use of hydrolysate in fermentation processes for the production of various products, such as alcoholic drinks, vinegar, among others.

  9. Utilization of residue from cassava starch processing for production of fermentable sugar by enzymatic hydrolysis

    Directory of Open Access Journals (Sweden)

    Luciana Reis Fontinelle SOUTO

    2016-01-01

    Full Text Available Abstract The aim of this study was to characterize and perform enzymatic hydrolysis of cassava peeling residue (peel and inner peel, mainly composed of peels and small pieces. Residue was sanitized, dried at 55 °C for 24 hours and ground. The obtained flour showed pH of 4.85; 72.53 g 100 g–1 moisture; 5.18 mL 1M NaOH 100 g–1 acidity; 60.68 g 100 g–1 starch; 1.08 g 100 g–1 reducing sugar; 1.63 g 100g–1 ash; 0.86 g 100 g–1 lipid and 3.97 g 100 g–1 protein. Enzymatic hydrolysis was carried out by means of rotational central composite design, analyzing the effects of concentrations of α-amylase enzyme (10 to 50 U g starch–1, and the amyloglucosidase enzyme (80 to 400 U g starch–1 on variable responses: percent conversion of starch into reducing sugars (RSC and soluble solid content (SS. Highest values of RSC (110% and SS (12 °Brix were observed when using the maximum concentration of amyloglucosidase and throughout the concentration range of α-amylase. Enzymatic hydrolysis of cassava peel is feasible and allows the use of hydrolysate in fermentation processes for the production of various products, such as alcoholic drinks, vinegar, among others.

  10. Reactive control processes contributing to residual switch cost and mixing cost in young and old adults

    Directory of Open Access Journals (Sweden)

    Lisa Rebecca Whitson

    2014-04-01

    Full Text Available In task-switching paradigms, performance is better when repeating the same task than when alternating between tasks (switch cost and when repeating a task alone rather than intermixed with another task (mixing cost. These costs remain even after extensive practice and when task cues enable advanced preparation (residual costs. Moreover, residual RT mixing cost has been consistently shown to increase with age. Residual switch and mixing costs modulate the amplitude of the stimulus-locked P3b. This mixing effect is disproportionately larger in older adults who also prepare more for and respond more cautiously on these ‘mixed’ repeat trials (Karayanidis et al., 2011. In this study, we examine stimulus-locked and response-locked P3 and lateralized readiness potentials to identify whether residual switch and mixing cost arise from the need to control interference at the level of stimulus processing or response processing. Residual mixing cost was associated with control of stimulus-level interference, whereas residual switch cost was also associated with a delay in response selection. In older adults, the disproportionate increase in mixing cost was associated with greater interference at the level of decision-response mapping and response programming for repeat trials in mixed-task blocks. We argue that, together with evidence of greater proactive control and more cautious responding for these trials, these findings suggest that older adults strategically recruit greater proactive and reactive control to overcome increased susceptibility to post-stimulus interference. This interpretation is consistent with recruitment of compensatory strategies to compensate for reduced repetition benefit rather than an overall decline on cognitive flexibility.

  11. Processing and display of nuclear magnetism logging signals: application to residual oil determination

    International Nuclear Information System (INIS)

    Brown, R.J.S.; Neuman, C.H.

    1980-01-01

    A presentation is made of a series of computations and signal displays which help to show the nature of NML signals in general as well as to show the response to particular formation, hole, and tool conditions. Such processing of digitally recorded signals enables improved accuracy and bed resolution over that presented with the raw log. The treatment of drilling mud filtrate to eliminate NML signal from the brine phase in the invaded zone is described. Logs are shown as recorded before and after invasion of treated mud filtrate. This treatment causes the NML signal to correspond to residual oil only, enabling accurate and relatively inexpensive measurement of residual oil. 24 refs

  12. Nondestructive assay of plutonium residue in horizontal storage tanks

    International Nuclear Information System (INIS)

    Marsh, S.F.

    1985-01-01

    Aqueous plutonium recovery and purification processes often involve the temporary storage of plutonium solutions in holding tanks. Because plutonium is known to precipitate from aqueous solutions under certain conditions, there is a continuing need to assay emptied tanks for plutonium residue. A portable gamma spectrometer system, specifically designed for this purpose, provides rapid assay of such plutonium residues in horizontal storage tanks. A means is thus available for the nondestructive analysis of these tanks on a regular schedule to ensure that significant deposits of plutonium are not allowed to accumulate. 5 figs

  13. Occurrence and distribution study of residues from pesticides applied under controlled conditions in the field during rice processing.

    Science.gov (United States)

    Pareja, Lucía; Colazzo, Marcos; Pérez-Parada, Andrés; Besil, Natalia; Heinzen, Horacio; Böcking, Bernardo; Cesio, Verónica; Fernández-Alba, Amadeo R

    2012-05-09

    The results of an experiment to study the occurrence and distribution of pesticide residues during rice cropping and processing are reported. Four herbicides, nine fungicides, and two insecticides (azoxystrobin, byspiribac-sodium, carbendazim, clomazone, difenoconazole, epoxiconazole, isoprothiolane, kresoxim-methyl, propanil, quinclorac, tebuconazole, thiamethoxam, tricyclazole, trifloxystrobin, λ-cyhalotrin) were applied to an isolated rice-crop plot under controlled conditions, during the 2009-2010 cropping season in Uruguay. Paddy rice was harvested and industrially processed to brown rice, white rice, and rice bran, which were analyzed for pesticide residues using the original QuEChERS methodology and its citrate variation by LC-MS/MS and GC-MS. The distribution of pesticide residues was uneven among the different matrices. Ten different pesticide residues were found in paddy rice, seven in brown rice, and eight in rice bran. The highest concentrations were detected in paddy rice. These results provide information regarding the fate of pesticides in the rice food chain and its safety for consumers.

  14. Design Process-System and Methodology of Design Research

    Science.gov (United States)

    Bashier, Fathi

    2017-10-01

    Studies have recognized the failure of the traditional design approach both in practice and in the studio. They showed that design problems today are too complex for the traditional approach to cope with and reflected a new interest in a better quality design services in order to meet the challenges of our time. In the mid-1970s and early 1980s, there has been a significant shift in focus within the field of design research towards the aim of creating a ‘design discipline’. The problem, as will be discussed, is the lack of an integrated theory of design knowledge that can explicitly describe the design process in a coherent way. As a consequence, the traditional approach fails to operate systematically, in a disciplinary manner. Addressing this problem is the primary goal of the research study in the design process currently being conducted in the research-based master studio at Wollega University, Ethiopia. The research study seeks to make a contribution towards a disciplinary approach, through proper understanding the mechanism of knowledge development within design process systems. This is the task of the ‘theory of design knowledge’. In this article the research project is introduced, and a model of the design process-system is developed in the studio as a research plan and a tool of design research at the same time. Based on data drawn from students’ research projects, the theory of design knowledge is developed and empirically verified through the research project.

  15. Detection of organic residues on poultry processing equipment surfaces by LED-induced fluorescence imaging

    Science.gov (United States)

    Organic residues on equipment surfaces in poultry processing plants can generate cross- contamination and increase the risk of unsafe food for consumers. This research was aimed to investigate the potential of LED-induced fluorescence imaging technique for rapid inspection of stainless steel proces...

  16. Residual stresses

    International Nuclear Information System (INIS)

    Macherauch, E.

    1978-01-01

    Residual stresses are stresses which exist in a material without the influence of external powers and moments. They come into existence when the volume of a material constantly changes its form as a consequence of mechanical, thermal, and/or chemical processes and is hindered by neighbouring volumes. Bodies with residual stress are in mechanical balance. These residual stresses can be manifested by means of all mechanical interventions disturbing this balance. Acoustical, optical, radiological, and magnetical methods involving material changes caused by residual stress can also serve for determining residual stress. Residual stresses have an ambivalent character. In technical practice, they are feared and liked at the same time. They cause trouble because they can be the cause for unexpected behaviour of construction elements. They are feared since they can cause failure, in the worst case with catastrophical consequences. They are appreciated, on the other hand, because, in many cases, they can contribute to improvements of the material behaviour under certain circumstances. But they are especially liked for their giving convenient and (this is most important) mostly uncontrollable explanations. For only in very few cases we have enough knowledge and possibilities for the objective evaluation of residual stresses. (orig.) [de

  17. Process design of press hardening with gradient material property influence

    International Nuclear Information System (INIS)

    Neugebauer, R.; Schieck, F.; Rautenstrauch, A.

    2011-01-01

    Press hardening is currently used in the production of automotive structures that require very high strength and controlled deformation during crash tests. Press hardening can achieve significant reductions of sheet thickness at constant strength and is therefore a promising technology for the production of lightweight and energy-efficient automobiles. The manganese-boron steel 22MnB5 have been implemented in sheet press hardening owing to their excellent hot formability, high hardenability, and good temperability even at low cooling rates. However, press-hardened components have shown poor ductility and cracking at relatively small strains. A possible solution to this problem is a selective increase of steel sheet ductility by press hardening process design in areas where the component is required to deform plastically during crash tests. To this end, process designers require information about microstructure and mechanical properties as a function of the wide spectrum of cooling rates and sequences and austenitizing treatment conditions that can be encountered in production environments. In the present work, a Continuous Cooling Transformation (CCT) diagram with corresponding material properties of sheet steel 22MnB5 was determined for a wide spectrum of cooling rates. Heating and cooling programs were conducted in a quenching dilatometer. Motivated by the importance of residual elasticity in crash test performance, this property was measured using a micro-bending test and the results were integrated into the CCT diagrams to complement the hardness testing results. This information is essential for the process design of press hardening of sheet components with gradient material properties.

  18. Proposed residual stress model for roller bent wide flange sections

    NARCIS (Netherlands)

    Spoorenberg, R.C.; Snijder, H.H.; Hoenderkamp, J.C.D.

    2011-01-01

    The manufacturing process of structural wide flange steel sections introduces residual stresses in the material. These stresses due to hot-rolling or welding influence the inelastic buckling response of structural steel members and need to be taken into account in the design. Based on experimental

  19. Impact of residual by-products from tungsten film deposition on process integration due to nonuniformity of the tungsten film

    CERN Document Server

    Sidhwa, A; Gandy, T; Melosky, S; Brown, W; Ang, S; Naseem, H; Ulrich, R

    2002-01-01

    The effects of residual by products from a tungsten film deposition process and their impact on process integration due to the nonuniformity of the tungsten film were investigated in this work. The tungsten film deposition process involves three steps: nucleation, stabilization, and tungsten bulk fill. Six experiments were conducted in search for a solution to the problem. The resulting data suggest that excess nitrogen left in the chamber following the tungsten nucleation step, along with residual by products, causes a shift in the tungsten film uniformity during the tungsten bulk fill process. Data reveal that, due to the residual by products, an abnormal grain growth occurs causing a variation in the tungsten thickness across the wafer during the bulk fill step. Although several possible solutions were revealed by the experiments, potential integration problems limited the acceptable solutions to one. The solution chosen was the introduction of a 10 s pumpdown immediately following the nucleation step. Thi...

  20. Designing future learning. A posthumanist approach to researching design processes

    DEFF Research Database (Denmark)

    Juelskjær, Malou

    I investigate how a design process – leading up to the design of a new education building - enact, transform and highlight tacit everyday practices and experiences in an education setting, whereby becoming an art of managing. I apply a post-humanist performative perspective, highlighting entangled...... agencies rather than focusing on human agency. I focus on the design process rather than the designer. The design process accelerated and performed past and future experiences of schooling, learning, teaching. This called for analytical attention to agential forces of not only the material but also...... and temporalities matter in design processes. Furthermore, the analysis emphasise how design translate affective economies and that attention to those affective economies are vital for the result of the design process....

  1. Dissipation kinetics, safety evaluation, and assessment of pre-harvest interval (PHI) and processing factor for kresoxim methyl residues in grape.

    Science.gov (United States)

    Sabale, Rupali; Shabeer, T P Ahammed; Utture, Sagar C; Banerjee, Kaushik; Jadhav, Manjusha R; Oulkar, Dasharath P; Adsule, Pandurang G; Deshmukh, Madhukar B

    2014-04-01

    A field dissipation study was conducted to evaluate the pre-harvest interval (PHI) and processing factor (PF) for kresoxim methyl (Ergon 44.3 SC) residues in grapes and during raisin making process at recommended dose (RD) and double the recommended dose (DRD). Kresoxim methyl residues dissipated following 1st-order kinetics with a half-life of 10 and 18 days at RD and DRD, respectively. The PHIs with respect to the European Union maximum residue limit (EU-MRL) of 1 mg kg(-1) for grapes were 13 and 30 days at RD and DRD, respectively. The degradation data during grape to raisin making process were best fitted to nonlinear 1st + 1st-order kinetics with a half-life ranging between 4 and 8 days for both shade drying and with raisin dryer at different doses. The PFs were 1.19 and 1.24 with shade drying and 1.09 and 1.10 with raisin dryer, respectively, which indicates concentration of the residues during raisin making process. The dietary exposure of kresoxim methyl on each sampling day was less than the respective maximum permissible intake both at RD and DRD. The residues of kresoxim methyl in market samples of grapes and raisins were well below the EU-MRL and were also devoid of any risk of acute toxicity related to dietary exposure.

  2. Effects of advanced laser processing on the microstructure and residual stresses of H13 tool steel

    OpenAIRE

    Trojan, Karel; Ocelík, Václav; Ganev, Nikolaj; Němeček, Stanislav; Čapek, Jiří

    2017-01-01

    The aim of this paper is to describe the effects of laser processing on the microstructure and residual stresses of laser cladded H13 tool steel on the classical construct steel S355 substrate. This research paper concludes that in this case of laser cladding, phase transformation and not shrinkage is likely to be a dominant effect on the formation of compressive residual stresses along the clad. Furthermore, martensitic structure and unequal concentration of alloying elements was observed on...

  3. Process for recovery of plutonium from fabrication residues of mixed fuels consisting of uranium oxide and plutonium oxide

    International Nuclear Information System (INIS)

    Heremanns, R.H.; Vandersteene, J.J.

    1983-01-01

    The invention concerns a process for recovery of plutonium from fabrication residues of mixed fuels consisting of uranium oxide and plutonium oxide in the form of PuO 2 . Mixed fuels consisting of uranium oxide and plutonium oxide are being used more and more. The plants which prepare these mixed fuels have around 5% of the total mass of fuels as fabrication residue, either as waste or scrap. In view of the high cost of plutonium, it has been attempted to recover this plutonium from the fabrication residues by a process having a purchase price lower than the price of plutonium. The problem is essentially to separate the plutonium, the uranium and the impurities. The residues are fluorinated, the UF 6 and PuF 6 obtained are separated by selective absorption of the PuF 6 on NaF at a temperature of at least 400 0 C, the complex obtained by this absorption is dissolved in nitric acid solution, the plutonium is precipitated in the form of plutonium oxalate by adding oxalic acid, and the precipitated plutonium oxalate is calcined

  4. Reengineering the Project Design Process

    Science.gov (United States)

    Casani, E.; Metzger, R.

    1994-01-01

    In response to NASA's goal of working faster, better and cheaper, JPL has developed extensive plans to minimize cost, maximize customer and employee satisfaction, and implement small- and moderate-size missions. These plans include improved management structures and processes, enhanced technical design processes, the incorporation of new technology, and the development of more economical space- and ground-system designs. The Laboratory's new Flight Projects Implementation Office has been chartered to oversee these innovations and the reengineering of JPL's project design process, including establishment of the Project Design Center and the Flight System Testbed. Reengineering at JPL implies a cultural change whereby the character of its design process will change from sequential to concurrent and from hierarchical to parallel. The Project Design Center will support missions offering high science return, design to cost, demonstrations of new technology, and rapid development. Its computer-supported environment will foster high-fidelity project life-cycle development and cost estimating.

  5. Design Thinking in Elementary Students' Collaborative Lamp Designing Process

    Science.gov (United States)

    Kangas, Kaiju; Seitamaa-Hakkarainen, Pirita; Hakkarainen, Kai

    2013-01-01

    Design and Technology education is potentially a rich environment for successful learning, if the management of the whole design process is emphasised, and students' design thinking is promoted. The aim of the present study was to unfold the collaborative design process of one team of elementary students, in order to understand their multimodal…

  6. Ethanol production process from banana fruit and its lignocellulosic residues: Energy analysis

    Energy Technology Data Exchange (ETDEWEB)

    Velasquez-Arredondo, H.I. [Grupo de Investigacion Bioprocesos y Flujos Reactivos, Universidad Nacional de Colombia, Sede Medellin, Calle 59 A N 63-20 (Colombia); Departamento de Engenharia Mecanica, Escola Politecnica, Universidade de Sao Paulo, Avenida Professor Mello Moraes 2231 (Brazil); Ruiz-Colorado, A.A. [Grupo de Investigacion Bioprocesos y Flujos Reactivos, Universidad Nacional de Colombia, Sede Medellin, Calle 59 A N 63-20 (Colombia); De Oliveira, S. Jr. [Departamento de Engenharia Mecanica, Escola Politecnica, Universidade de Sao Paulo, Avenida Professor Mello Moraes 2231 (Brazil)

    2010-07-15

    Tropical countries, such as Brazil and Colombia, have the possibility of using agricultural lands for growing biomass to produce bio-fuels such as biodiesel and ethanol. This study applies an energy analysis to the production process of anhydrous ethanol obtained from the hydrolysis of starch and cellulosic and hemicellulosic material present in the banana fruit and its residual biomass. Four different production routes were analyzed: acid hydrolysis of amylaceous material (banana pulp and banana fruit) and enzymatic hydrolysis of lignocellulosic material (flower stalk and banana skin). The analysis considered banana plant cultivation, feedstock transport, hydrolysis, fermentation, distillation, dehydration, residue treatment and utility plant. The best indexes were obtained for amylaceous material for which mass performance varied from 346.5 L/t to 388.7 L/t, Net Energy Value (NEV) ranged from 9.86 MJ/L to 9.94 MJ/L and the energy ratio was 1.9 MJ/MJ. For lignocellulosic materials, the figures were less favorable; mass performance varied from 86.1 to 123.5 L/t, NEV from 5.24 to 8.79 MJ/L and energy ratio from 1.3 to 1.6 MJ/MJ. The analysis showed, however, that both processes can be considered energetically feasible. (author)

  7. Valid knowledge for the professional design of large and complex design processes

    NARCIS (Netherlands)

    Aken, van J.E.

    2004-01-01

    The organization and planning of design processes, which we may regard as design process design, is an important issue. Especially for large and complex design-processes traditional approaches to process design may no longer suffice. The design literature gives quite some design process models. As

  8. Immobilization of acid digestion residue

    International Nuclear Information System (INIS)

    Greenhalgh, W.O.; Allen, C.R.

    1983-01-01

    Acid digestion treatment of nuclear waste is similar to incineration processes and results in the bulk of the waste being reduced in volume and weight to some residual solids termed residue. The residue is composed of various dispersible solid materials and typically contains the resultant radioactivity from the waste. This report describes the immobilization of the residue in portland cement, borosilicate glass, and some other waste forms. Diagrams showing the cement and glass virtification parameters are included in the report as well as process steps and candidate waste product forms. Cement immobilization is simplest and probably least expensive; glass vitrification exhibits the best overall volume reduction ratio

  9. The Pharmaceutical Capping Process-Correlation between Residual Seal Force, Torque Moment, and Flip-off Removal Force.

    Science.gov (United States)

    Mathaes, Roman; Mahler, Hanns-Christian; Vorgrimler, Lothar; Steinberg, Henrik; Dreher, Sascha; Roggo, Yves; Nieto, Alejandra; Brown, Helen; Roehl, Holger; Adler, Michael; Luemkemann, Joerg; Huwyler, Joerg; Lam, Philippe; Stauch, Oliver; Mohl, Silke; Streubel, Alexander

    2016-01-01

    The majority of parenteral drug products are manufactured in glass vials with an elastomeric rubber stopper and a crimp cap. The vial sealing process is a critical process step during fill-and-finish operations, as it defines the seal quality of the final product. Different critical capping process parameters can affect rubber stopper defects, rubber stopper compression, container closure integrity, and also crimp cap quality. A sufficiently high force to remove the flip-off button prior to usage is required to ensure quality of the drug product unit by the flip-off button during storage, transportation, and until opening and use. Therefore, the final product is 100% visually inspected for lose or defective crimp caps, which is subjective as well as time- and labor-intensive. In this study, we sealed several container closure system configurations with different capping equipment settings (with corresponding residual seal force values) to investigate the torque moment required to turn the crimp cap. A correlation between torque moment and residual seal force has been established. The torque moment was found to be influenced by several parameters, including diameter of the vial head, type of rubber stopper (serum or lyophilized) and type of crimp cap (West(®) or Datwyler(®)). In addition, we measured the force required to remove the flip-off button of a sealed container closure system. The capping process had no influence on measured forces; however, it was possible to detect partially crimped vials. In conclusion, a controlled capping process with a defined target residual seal force range leads to a tight crimp cap on a sealed container closure system and can ensure product quality. The majority of parenteral drug products are manufactured in a glass vials with an elastomeric rubber stopper and a crimp cap. The vial sealing process is a critical process step during fill-and-finish operations, as it defines the seal quality of the final product. An adequate force

  10. A Design of Finite Memory Residual Generation Filter for Sensor Fault Detection

    Directory of Open Access Journals (Sweden)

    Kim Pyung Soo

    2017-04-01

    Full Text Available In the current paper, a residual generation filter with finite memory structure is proposed for sensor fault detection. The proposed finite memory residual generation filter provides the residual by real-time filtering of fault vector using only the most recent finite measurements and inputs on the window. It is shown that the residual given by the proposed residual generation filter provides the exact fault for noisefree systems. The proposed residual generation filter is specified to the digital filter structure for the amenability to hardware implementation. Finally, to illustrate the capability of the proposed residual generation filter, extensive simulations are performed for the discretized DC motor system with two types of sensor faults, incipient soft bias-type fault and abrupt bias-type fault. In particular, according to diverse noise levels and windows lengths, meaningful simulation results are given for the abrupt bias-type fault.

  11. Dissipation pattern, safety evaluation, and generation of processing factor (PF) for pyraclostrobin and metiram residues in grapes during raisin preparation.

    Science.gov (United States)

    Shabeer T P, Ahammed; Girame, Rushali; Hingmire, Sandip; Banerjee, Kaushik; Sharma, Ajay Kumar; Oulkar, Dasharath; Utture, Sagar; Jadhav, Manjusha

    2015-02-01

    A residue analysis method was validated for trace level estimation of pyraclostrobin by liquid chromatography-mass spectrometry and metiram (analyzed as CS2) by gas chromatography mass spectrometry in grapes and raisin matrix. Dissipation of their residues and processing factors (PFs) during raisin making were evaluated through field studies with applications at single dose (SD) and double dose (DD). Residue data during drying process were best fitted to first + first-order kinetics model giving half-life ranging between 6 and 7 days for pyroclostrobin and 4 days for metiram. PFs for metiram and pyraclostrobin related to washing and oil dipping were 0.47 and 0.41, and 0.78 and 0.63 at single dose (SD) and double dose (DD), respectively. PF value of >1 for drying (1.01 and 1.31 for metiram and 1.34 and 1.10 for pyraclostrobin) indicates concentration of the residues during the drying process. The dietary exposure corresponding to average daily consumption of 0.0043 kg raisin per day on each sampling day was less than the respective maximum permissible intake at both the doses.

  12. Modeling and Parameter Optimization for Surface Roughness and Residual Stress in Dry Turning Process

    Directory of Open Access Journals (Sweden)

    M. H. El-Axir

    2017-10-01

    Full Text Available The influence of some turning variables and tool overhang on surface roughness parameters and residual stress induced due to machining 6061-T6 aluminum alloy is investigated in this paper. Four input parameters (cutting speed, feed rate, depth of cut and tool overhang are considered. Tests are carried out by precision turning operation on a lathe. Design of experiment techniques, i.e. response surface methodology (RSM and Taguchi's technique have been used to accomplish the objective of the experimental study. Surface roughness parameters are measured using a portable surface roughness device while residual stresses are measured employing deflection-etching technique using electrochemical analysis. The results obtained reveal that feed and rotational speed play significant role in determining the average surface roughness. Furthermore, the depth of cut and tool overhang are less significant parameters, whereas tool overhang interacts with feed rate. The best result of surface roughness was obtained using low or medium values of overhang with low speed and /or feed rate. Minimum maximum tensile residual stress can be obtained with a combination of tool overhang of 37 mm with very low depth of cut, low rotational speed and feed rate of 0.188 mm/rev.

  13. [Effects of rice cleaning and cooking process on the residues of flutolanil, fenobucarb, silafluofen and buprofezin in rice].

    Science.gov (United States)

    Satoh, Motoaki; Sakaguchi, Masayuki; Kobata, Masakazu; Sakaguchi, Yoko; Tanizawa, Haruna; Miura, Yuri; Sasano, Ryoichi; Nakanishi, Yutaka

    2003-02-01

    We studied the effect of cleaning and cooking on the residues of flutolanil, fenobucarb, silafluofen and buprofezin in rice. The rice had been sprayed in a paddy field in Wakayama city, with 3 kinds of pesticide application protocols: spraying once at the usual concentration of pesticides, repeated spraying (3 times) with the usual concentration of pesticides and spraying once with 3 times the usual concentration of pesticides. The residue levels of pesticide decreased during the rice cleaning process. Silafluofen, which has a higher log Pow value, remained in the hull of the rice. Fenobucarb, which has a lower log Pow value, penetrated inside the rice. The residue concentration of pesticide in polished rice was higher than that in pre-washed rice processed ready for cooking. During the cooking procedure, the reduction of pesticides in polished rice was higher than that in brown rice.

  14. Environmental sustainability assessment of fruit cultivation and processing using fruit and cocoa residues for bioenergy and compost. Case study from Ghana

    DEFF Research Database (Denmark)

    Kamp, Andreas; Østergård, Hanne

    2016-01-01

    and electricity production using farming and processing residues and by recycling of nutrients and carbon to soil. Cocoa shells are used as a co-substrate in the biogas production. Estimating the environmental impact of cocoa shell residues exposes the multifunctionality issue, continuously debated in ESA......, particularly concerning bioenergy production. We compare the use of allocation of cocoa production impacts and system expansion that includes cocoa production as possible methods to manage multifunctionality of inputs. Inassessments of residue-based production, we recommend using the latter method. Applying......Agro-industrial businesses often have easy access to agricultural and processing residues with whichthey may reduce costs and pollution by integrating their production with bioenergy production. In regionswith unreliable power supply, on-site electricity generation is a means to secure stable...

  15. Finite Element Residual Stress Analysis of Planetary Gear Tooth

    Directory of Open Access Journals (Sweden)

    Jungang Wang

    2013-01-01

    Full Text Available A method to simulate residual stress field of planetary gear is proposed. In this method, the finite element model of planetary gear is established and divided to tooth zone and profile zone, whose different temperature field is set. The gear's residual stress simulation is realized by the thermal compression stress generated by the temperature difference. Based on the simulation, the finite element model of planetary gear train is established, the dynamic meshing process is simulated, and influence of residual stress on equivalent stress of addendum, pitch circle, and dedendum of internal and external meshing planetary gear tooth profile is analyzed, according to non-linear contact theory, thermodynamic theory, and finite element theory. The results show that the equivalent stresses of planetary gear at both meshing and nonmeshing surface are significantly and differently reduced by residual stress. The study benefits fatigue cracking analysis and dynamic optimization design of planetary gear train.

  16. Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 2: Residual-fired nocogeneration process boiler

    Science.gov (United States)

    Knightly, W. F.

    1980-01-01

    Computer generated data on the performance of the cogeneration energy conversion system are presented. Performance parameters included fuel consumption and savings, capital costs, economics, and emissions of residual fired process boilers.

  17. Rigid Residue Scan Simulations Systematically Reveal Residue Entropic Roles in Protein Allostery.

    Directory of Open Access Journals (Sweden)

    Robert Kalescky

    2016-04-01

    Full Text Available Intra-protein information is transmitted over distances via allosteric processes. This ubiquitous protein process allows for protein function changes due to ligand binding events. Understanding protein allostery is essential to understanding protein functions. In this study, allostery in the second PDZ domain (PDZ2 in the human PTP1E protein is examined as model system to advance a recently developed rigid residue scan method combining with configurational entropy calculation and principal component analysis. The contributions from individual residues to whole-protein dynamics and allostery were systematically assessed via rigid body simulations of both unbound and ligand-bound states of the protein. The entropic contributions of individual residues to whole-protein dynamics were evaluated based on covariance-based correlation analysis of all simulations. The changes of overall protein entropy when individual residues being held rigid support that the rigidity/flexibility equilibrium in protein structure is governed by the La Châtelier's principle of chemical equilibrium. Key residues of PDZ2 allostery were identified with good agreement with NMR studies of the same protein bound to the same peptide. On the other hand, the change of entropic contribution from each residue upon perturbation revealed intrinsic differences among all the residues. The quasi-harmonic and principal component analyses of simulations without rigid residue perturbation showed a coherent allosteric mode from unbound and bound states, respectively. The projection of simulations with rigid residue perturbation onto coherent allosteric modes demonstrated the intrinsic shifting of ensemble distributions supporting the population-shift theory of protein allostery. Overall, the study presented here provides a robust and systematic approach to estimate the contribution of individual residue internal motion to overall protein dynamics and allostery.

  18. Bio-gasification of post transesterified microalgae residues: A route to improving overall process renewabilities

    DEFF Research Database (Denmark)

    Ehimen, Ehiazesebhor Augustine

    Using results from experiments and process modelling tools, a renewability assessment was carried out for the use of the conventional and in-situ transesterification processes for a large scale microalgae biodiesel production. In a present day scenario, all the transesterification processes were...... shown to be non-renewable. The process renewability of biodiesel production from microalgae was found to significantly improve with the use of renewable electricity, reacting alcohols from biomass fermentation and process heating and biomass drying using heat from wood pellet combustion or heat pump...... technology. The anaerobic digestion of the microalgae residues to generate methane from was further seen to lead to positive renewabilities for the considered microalgae-biodiesel processes....

  19. Management of NORM Residues

    International Nuclear Information System (INIS)

    2013-06-01

    The IAEA attaches great importance to the dissemination of information that can assist Member States in the development, implementation, maintenance and continuous improvement of systems, programmes and activities that support the nuclear fuel cycle and nuclear applications, and that address the legacy of past practices and accidents. However, radioactive residues are found not only in nuclear fuel cycle activities, but also in a range of other industrial activities, including: - Mining and milling of metalliferous and non-metallic ores; - Production of non-nuclear fuels, including coal, oil and gas; - Extraction and purification of water (e.g. in the generation of geothermal energy, as drinking and industrial process water; in paper and pulp manufacturing processes); - Production of industrial minerals, including phosphate, clay and building materials; - Use of radionuclides, such as thorium, for properties other than their radioactivity. Naturally occurring radioactive material (NORM) may lead to exposures at some stage of these processes and in the use or reuse of products, residues or wastes. Several IAEA publications address NORM issues with a special focus on some of the more relevant industrial operations. This publication attempts to provide guidance on managing residues arising from different NORM type industries, and on pertinent residue management strategies and technologies, to help Member States gain perspectives on the management of NORM residues

  20. Mechanical Characterization of Thermomechanical Matrix Residual Stresses Incurred During MMC Processing

    Science.gov (United States)

    Castelli, Michael G.

    1998-01-01

    In recent years, much effort has been spent examining the residual stress-strain states of advanced composites. Such examinations are motivated by a number of significant concerns that affect composite development, processing, and analysis. The room-temperature residual stress states incurred in many advanced composite systems are often quite large and can introduce damage even prior to the first external mechanical loading of the material. These stresses, which are induced during the cooldown following high-temperature consolidation, result from the coefficient of thermal expansion mismatch between the fiber and matrix. Experimental techniques commonly used to evaluate composite internal residual stress states are non-mechanical in nature and generally include forms of x-ray and neutron diffraction. Such approaches are usually complex, involving a number of assumptions and limitations associated with a wide range of issues, including the depth of penetration, the volume of material being assessed, and erroneous effects associated with oriented grains. Furthermore, and more important to the present research, these techniques can assess only "single time" stress in the composite. That is, little, if any, information is obtained that addresses the time-dependent point at which internal stresses begin to accumulate, the manner in which the accumulation occurs, and the presiding relationships between thermoelastic, thermoplastic, and thermoviscous behaviors. To address these critical issues, researchers at the NASA Lewis Research Center developed and implemented an innovative mechanical test technique to examine in real time, the time-dependent thermomechanical stress behavior of a matrix alloy as it went through a consolidation cycle.

  1. Application of Safeguards-by-Design to a Reactor Design Process

    International Nuclear Information System (INIS)

    Whitlock, J.J.

    2010-01-01

    The application of 'Safeguards-by-Design' (SBD) to a reactor design process is described. The SBD concept seeks to improve the efficiency and effectiveness of IAEA safeguards by incorporating the needs of safeguards at an early stage of reactor design. Understanding and accommodating safeguards in the design process requires a set of 'design requirements for safeguards'; however, such requirements (a) do not traditionally exist, and (b) must exist alongside other more traditional design requirements based upon compliance and operational goals. In the absence of design requirements, a 'Design Guide' for safeguards was created, consisting of recommendations based on best practices. To acquire an understanding of safeguards requirements at the design level, a systematic accounting of diversion pathways was required. However, because of the crowded field of other design requirements, this process needed a methodology that was also flexible in interpretation. The GenIV Proliferation Resistance and Physical Protection (PR and PP) methodology (Rev.5, 2005) was chosen for this exercise. The PR and PP methodology is a general approach and therefore it was necessary to restrict its application; in effect, turning 'off' various options so as to simplify the process. The results of this exercise were used to stimulate discussions with the design team and initiate changes that accommodate safeguards without negatively impacting other design requirements. The process yielded insights into the effective application of SBD, and highlighted issues that must be resolved for effective incorporation of an 'SBD culture' within the design process. (author)

  2. Neutron residual stress measurements in linepipe

    International Nuclear Information System (INIS)

    Law, Michael; Gnaepel-Herold, Thomas; Luzin, Vladimir; Bowie, Graham

    2006-01-01

    Residual stresses in gas pipelines are generated by manufacturing and construction processes and may affect the subsequent pipe integrity. In the present work, the residual stresses in eight samples of linepipe were measured by neutron diffraction. Residual stresses changed with some coating processes. This has special implications in understanding and mitigating stress corrosion cracking, a major safety and economic problem in some gas pipelines

  3. Chemical analysis and biorefinery of red algae Kappaphycus alvarezii for efficient production of glucose from residue of carrageenan extraction process.

    Science.gov (United States)

    Masarin, Fernando; Cedeno, Fernando Roberto Paz; Chavez, Eddyn Gabriel Solorzano; de Oliveira, Levi Ezequiel; Gelli, Valéria Cress; Monti, Rubens

    2016-01-01

    Biorefineries serve to efficiently utilize biomass and their by-products. Algal biorefineries are designed to generate bioproducts for commercial use. Due to the high carbohydrate content of algal biomass, biorefinery to generate biofuels, such as bioethanol, is of great interest. Carrageenan is a predominant polysaccharide hydrocolloid found in red macroalgae and is widely used in food, cosmetics, and pharmaceuticals. In this study, we report the biorefinery of carrageenan derived from processing of experimental strains of the red macroalgae Kappaphycus alvarezii. Specifically, the chemical composition and enzymatic hydrolysis of the residue produced from carrageenan extraction were evaluated to determine the conditions for efficient generation of carbohydrate bioproducts. The productivity and growth rates of K. alvarezii strains were assessed along with the chemical composition (total carbohydrates, ash, sulfate groups, proteins, insoluble aromatics, galacturonic acid, and lipids) of each strain. Two strains, brown and red, were selected based on their high growth rates and productivity and were treated with 6 % KOH for extraction of carrageenan. The yields of biomass from treatment with 6 % KOH solution of the brown and red strains were 89.3 and 89.5 %, respectively. The yields of carrageenan and its residue were 63.5 and 23 %, respectively, for the brown strain and 60 and 27.8 %, respectively, for the red strain. The residues from the brown and red strains were assessed to detect any potential bioproducts. The galactan, ash, protein, insoluble aromatics, and sulfate groups of the residue were reduced to comparable extents for the two strains. However, KOH treatment did not reduce the content of glucan in the residue from either strain. Glucose was produced by enzymatic hydrolysis for 72 h using both strains. The glucan conversion was 100 % for both strains, and the concentrations of glucose from the brown and red strains were 13.7 and 11.5 g L(-1

  4. Evaluation of removal efficiency of residual diclofenac in aqueous solution by nanocomposite tungsten-carbon using design of experiment.

    Science.gov (United States)

    Salmani, M H; Mokhtari, M; Raeisi, Z; Ehrampoush, M H; Sadeghian, H A

    2017-09-01

    Wastewater containing pharmaceutical residual components must be treated before being discharged to the environment. This study was conducted to investigate the efficiency of tungsten-carbon nanocomposite in diclofenac removal using design of experiment (DOE). The 27 batch adsorption experiments were done by choosing three effective parameters (pH, adsorbent dose, and initial concentration) at three levels. The nanocomposite was prepared by tungsten oxide and activated carbon powder in a ratio of 1 to 4 mass. The remaining concentration of diclofenac was measured by a spectrometer with adding reagents of 2, 2'-bipyridine, and ferric chloride. Analysis of variance (ANOVA) was applied to determine the main and interaction effects. The equilibrium time for removal process was determined as 30 min. It was observed that the pH had the lowest influence on the removal efficiency of diclofenac. Nanocomposite gave a high removal at low concentration of 5.0 mg/L. The maximum removal for an initial concentration of 5.0 mg/L was 88.0% at contact time of 30 min. The results of ANOVA showed that adsorbent mass was among the most effective variables. Using DOE as an efficient method revealed that tungsten-carbon nanocomposite has high efficiency in the removal of residual diclofenac from the aqueous solution.

  5. Effect of an absorbent overlay on the residual stress field induced by laser shock processing on aluminum samples

    International Nuclear Information System (INIS)

    Rubio-Gonzalez, C.; Gomez-Rosas, G.; Ocana, J.L.; Molpeceres, C.; Banderas, A.; Porro, J.; Morales, M.

    2006-01-01

    Laser shock processing (LSP) or laser shock peening is a new technique for strengthening metals. This process induces a compressive residual stress field, which increases fatigue crack initiation life and reduces fatigue crack growth rate. Specimens of 6061-T6 aluminum alloy are used in this investigation. A convergent lens is used to deliver 2.5 J, 8 ns laser pulses by a Q-switch Nd:YAG laser, operating at 10 Hz. The pulses are focused to a diameter of 1.5 mm onto aluminum samples. Density of 2500 pulses/cm 2 with infrared (1064 nm) radiation was used. The effect of an absorbent overlay on the residual stress field using this LSP setup and this energy level is evaluated. Residual stress distribution as a function of depth is assessed by the hole drilling method. It is observed that the overlay makes the compressive residual stress profile move to the surface. This effect is explained on the basis of the vaporization of the coat layer suppressing thermal effects on the metallic substrate. The effect of coating the specimen surface before LSP treatment may have advantages on improving wear and contact fatigue properties of this aluminum alloy

  6. Alkali activation processes for incinerator residues management.

    Science.gov (United States)

    Lancellotti, Isabella; Ponzoni, Chiara; Barbieri, Luisa; Leonelli, Cristina

    2013-08-01

    Incinerator bottom ash (BA) is produced in large amount worldwide and in Italy, where 5.1 millionstons of municipal solid residues have been incinerated in 2010, corresponding to 1.2-1.5 millionstons of produced bottom ash. This residue has been used in the present study for producing dense geopolymers containing high percentage (50-70 wt%) of ash. The amount of potentially reactive aluminosilicate fraction in the ash has been determined by means of test in NaOH. The final properties of geopolymers prepared with or without taking into account this reactive fraction have been compared. The results showed that due to the presence of both amorphous and crystalline fractions with a different degree of reactivity, the incinerator BA geopolymers exhibit significant differences in terms of Si/Al ratio and microstructure when reactive fraction is considered. Copyright © 2013 Elsevier Ltd. All rights reserved.

  7. HTGR process heat program design and analysis. Semiannual progress report, October 1, 1979-March 28, 1980

    International Nuclear Information System (INIS)

    1980-10-01

    This report summarizes the results of concept design studies implemented at General Atomic Company (GA) during the first half of FY-80. The studies relate to a plant design for an 842-MW(t) High-Temperature Gas-Cooled Reactor utilizing an intermediate helium heat transfer loop to provide high temperature thermal energy for the production of hydrogen or synthesis gas (H 2 + CO) by steam-reforming a light hydrocarbon. Basic carbon sources may be coal, residual oil, or oil shale. Work tasks conducted during this period included the 842-MW(t) plant concept design and cost estimate for an 850 0 C reactor outlet temperature. An assessment of the main-loop cooling shutdown system is reported. Major component cost models were prepared and programmed into the Process Heat Reactor Evaluation and Design (PHRED) code

  8. Reengineering the project design process

    Science.gov (United States)

    Kane Casani, E.; Metzger, Robert M.

    1995-01-01

    In response to the National Aeronautics and Space Administration's goal of working faster, better, and cheaper, the Jet Propulsion Laboratory (JPL) has developed extensive plans to minimize cost, maximize customer and employee satisfaction, and implement small- and moderate-size missions. These plans include improved management structures and processes, enhanced technical design processes, the incorporation of new technology, and the development of more economical space- and ground-system designs. The Laboratory's new Flight Projects Implementation Development Office has been chartered to oversee these innovations and the reengineering of JPL's project design process, including establishment of the Project Design Center (PDC) and the Flight System Testbed (FST). Reengineering at JPL implies a cultural change whereby the character of the Laboratory's design process will change from sequential to concurrent and from hierarchical to parallel. The Project Design Center will support missions offering high science return, design to cost, demonstrations of new technology, and rapid development. Its computer-supported environment will foster high-fidelity project life-cycle development and more accurate cost estimating. These improvements signal JPL's commitment to meeting the challenges of space exploration in the next century.

  9. The Digital Design Process - Reflections on a Single Design Case

    NARCIS (Netherlands)

    Achten, H.H.; Joosen, G.; Dokonal, W.; Hirschberg, U.

    2003-01-01

    CAD tools are increasing their expressive and geometric power to enable a design process in which the computer model can be used throughout the whole design process for realizing the design. Such a process, in which other media such as physical scale models or drawings are no longer required by

  10. Differential RF MEMS interwoven capacitor immune to residual stress warping

    KAUST Repository

    Elshurafa, Amro M.

    2012-07-27

    A RF MEMS capacitor with an interwoven structure is designed, fabricated in the PolyMUMPS process and tested in an effort to address fabrication challenges usually faced in MEMS processes. The interwoven structure was found to offer several advantages over the typical MEMS parallel-plate design including eliminating the warping caused by residual stress, eliminating the need for etching holes, suppressing stiction, reducing parasitics and providing differential capability. The quality factor of the proposed capacitor was higher than five throughout a 2–10 GHz range and the resonant frequency was in excess of 20 GHz.

  11. Differential RF MEMS interwoven capacitor immune to residual stress warping

    KAUST Repository

    Elshurafa, Amro M.; Salama, Khaled N.

    2012-01-01

    A RF MEMS capacitor with an interwoven structure is designed, fabricated in the PolyMUMPS process and tested in an effort to address fabrication challenges usually faced in MEMS processes. The interwoven structure was found to offer several advantages over the typical MEMS parallel-plate design including eliminating the warping caused by residual stress, eliminating the need for etching holes, suppressing stiction, reducing parasitics and providing differential capability. The quality factor of the proposed capacitor was higher than five throughout a 2–10 GHz range and the resonant frequency was in excess of 20 GHz.

  12. Imperfect Information in Software Design Processes

    NARCIS (Netherlands)

    Noppen, J.A.R.

    2007-01-01

    The process of designing high-quality software systems is one of the major issues in software engineering research. Over the years, this has resulted in numerous design methods, each with specific qualities and drawbacks. For example, the Rational Unified Process is a comprehensive design process,

  13. PROPOSAL OF SPATIAL OPTIMIZATION OF PRODUCTION PROCESS IN PROCESS DESIGNER

    Directory of Open Access Journals (Sweden)

    Peter Malega

    2015-03-01

    Full Text Available This contribution is focused on optimizing the use of space in the production process using software Process Designer. The aim of this contribution is to suggest possible improvements to the existing layout of the selected production process. Production process was analysed in terms of inputs, outputs and course of actions. Nowadays there are many software solutions aimed at optimizing the use of space. One of these software products is the Process Designer, which belongs to the product line Tecnomatix. This software is primarily aimed at production planning. With Process Designer is possible to design the layout of production and subsequently to analyse the production or to change according to the current needs of the company.

  14. Energy generation for sustainable development with innovation technology and utilization of biomass residue; Geracao de energia para o desenvolvimento rural sustentavel com inovacao tecnologica de aproveitamento de biomassa residual

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Maria Roseane de Pontes; Lopes, Carlos Eduardo Bezerra; Costa Neto, Manoel Bezerra da; Selvam, P.V. Pannir [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2004-07-01

    In the present work, the introduction of alternative energy of biogas in agricultural communities for the sustainable development was studied through exploitation of residual biomass and also getting as by-product the biological fertilizer. A fast composting of the domestic residue with the organic was made possible where part of this residue after processing was taken together with effluent to the biodigestor. The bibliographical research on the processes of generation of biogas, about composting and the equipment for processing had been carried through. The projects Engineering with the use of computational tools had been developed with the Software Super Pro 4,9 Design and ORC GPEC 2004 by our research group. Five case studies had been elaborated, where different scenes related with our innovation, that uses of the residue for the composting together with domestic effluent for digestion. Several economic parameters were obtained and our work proved the viability about the use of biogas for drying of the fruits banana. A economic feasibility study was carried where it was proven that the project with the innovation of the use of residues from the fruits possesses more advantages than the conventional system of drying using electric energy. Considering the viability of this process and the use solar energy, it is intended to apply this technology in rural agricultural communities providing them an energy source of low cost in substitution of the conventional energy. (author)

  15. Prevalence of antibiotic residues in commercial milk and its variation by season and thermal processing methods

    Directory of Open Access Journals (Sweden)

    Fathollah Aalipour

    2013-01-01

    Full Text Available Aims: In this study, the prevalence of antibiotic residues in pasteurized and sterilized commercial milk available in Shahre-kourd, Iran, was investigated. In addition, the influence of seasonal temperature changes on the prevalence of contamination was studied. Materials and Methods: Commercial milk samples of 187, including 154 pasteurized and 33 sterilized, milk samples were collected from the market between early January 2012 and late July of the same year. The presence of antibiotic residues was detected using the microbiological detection test kit, Eclipse 100, as a semi-quantitative method. Results: The results showed that 37 of the samples (19.8% have contained antibiotic residues above the European Union Maximum Residues Limits (EU-MRLs, of which 28 samples (14.97% were found to be contaminated but at the concentrations below the EU-MRLs. There was no significant difference between the contamination rate of pasteurized and Ultra High Temperature (UHT-sterilized samples. Similarly, variation of weather temperature with seasons had no effect on the contamination prevalence of milk samples ( P > 0.05. Conclusion: Based on the result of this study, antibiotics residues were present in the majority of milk samples. Neither the season nor the type of thermal processing of the commercial milks had noticeable impact on the prevalence level of the milk samples. However, an increasing trend of prevalence level for antibiotic residues was observed with increasing the temperature through the warm season.

  16. Predictive hydrogeochemical modelling of bauxite residue sand in field conditions.

    Science.gov (United States)

    Wissmeier, Laurin; Barry, David A; Phillips, Ian R

    2011-07-15

    The suitability of residue sand (the coarse fraction remaining from Bayer's process of bauxite refining) for constructing the surface cover of closed bauxite residue storage areas was investigated. Specifically, its properties as a medium for plant growth are of interest to ensure residue sand can support a sustainable ecosystem following site closure. The geochemical evolution of the residue sand under field conditions, its plant nutrient status and soil moisture retention were studied by integrated modelling of geochemical and hydrological processes. For the parameterization of mineral reactions, amounts and reaction kinetics of the mineral phases natron, calcite, tricalcium aluminate, sodalite, muscovite and analcime were derived from measured acid neutralization curves. The effective exchange capacity for ion adsorption was measured using three independent exchange methods. The geochemical model, which accounts for mineral reactions, cation exchange and activity corrected solution speciation, was formulated in the geochemical modelling framework PHREEQC, and partially validated in a saturated-flow column experiment. For the integration of variably saturated flow with multi-component solute transport in heterogeneous 2D domains, a coupling of PHREEQC with the multi-purpose finite-element solver COMSOL was established. The integrated hydrogeochemical model was applied to predict water availability and quality in a vertical flow lysimeter and a cover design for a storage facility using measured time series of rainfall and evaporation from southwest Western Australia. In both scenarios the sand was fertigated and gypsum-amended. Results show poor long-term retention of fertilizer ions and buffering of the pH around 10 for more than 5 y of leaching. It was concluded that fertigation, gypsum amendment and rainfall leaching alone were insufficient to render the geochemical conditions of residue sand suitable for optimal plant growth within the given timeframe. The

  17. Wetland-based passive treatment systems for gold ore processing effluents containing residual cyanide, metals and nitrogen species.

    Science.gov (United States)

    Alvarez, R; Ordóñez, A; Loredo, J; Younger, P L

    2013-10-01

    Gold extraction operations generate a variety of wastes requiring responsible disposal in compliance with current environmental regulations. During recent decades, increased emphasis has been placed on effluent control and treatment, in order to avoid the threat to the environment posed by toxic constituents. In many modern gold mining and ore processing operations, cyanide species are of most immediate concern. Given that natural degradation processes are known to reduce the toxicity of cyanide over time, trials have been made at laboratory and field scales into the feasibility of using wetland-based passive systems as low-cost and environmentally friendly methods for long-term treatment of leachates from closed gold mine tailing disposal facilities. Laboratory experiments on discrete aerobic and anaerobic treatment units supported the development of design parameters for the construction of a field-scale passive system at a gold mine site in northern Spain. An in situ pilot-scale wetland treatment system was designed, constructed and monitored over a nine-month period. Overall, the results suggest that compost-based constructed wetlands are capable of detoxifying cyanidation effluents, removing about 21.6% of dissolved cyanide and 98% of Cu, as well as nitrite and nitrate. Wetland-based passive systems can therefore be considered as a viable technology for removal of residual concentrations of cyanide from leachates emanating from closed gold mine tailing disposal facilities.

  18. The effect of processing on veterinary residues in foods.

    Science.gov (United States)

    Moats, W A

    1999-01-01

    Heat stability of antibiotics in foods to cooking has been determined by a variety of methods. These include heating in such liquid media as milk, water, buffers and meat extracts, and in solids such as buffered meat homogenates and various sausages. Inactivation of incurred residues in tissues and eggs was also studied. Time and temperature of heating were more easily controlled in liquid media, but results in actual meat products are more indicative of actual cooking processes. Ordinary cooking procedures for meat, even to "well-done", cannot be relied on to inactivate even the more heat sensitive compounds such as penicillins and tetracyclines. More severe heating as for canning or prolonged cooking with moist heat can inactivate the more heat sensitive compounds. The relevance to food safety is uncertain since the nature of the degradation products is unknown in most cases.

  19. Engineering design: A cognitive process approach

    Science.gov (United States)

    Strimel, Greg Joseph

    The intent of this dissertation was to identify the cognitive processes used by advanced pre-engineering students to solve complex engineering design problems. Students in technology and engineering education classrooms are often taught to use an ideal engineering design process that has been generated mostly by educators and curriculum developers. However, the review of literature showed that it is unclear as to how advanced pre-engineering students cognitively navigate solving a complex and multifaceted problem from beginning to end. Additionally, it was unclear how a student thinks and acts throughout their design process and how this affects the viability of their solution. Therefore, Research Objective 1 was to identify the fundamental cognitive processes students use to design, construct, and evaluate operational solutions to engineering design problems. Research Objective 2 was to determine identifiers within student cognitive processes for monitoring aptitude to successfully design, construct, and evaluate technological solutions. Lastly, Research Objective 3 was to create a conceptual technological and engineering problem-solving model integrating student cognitive processes for the improved development of problem-solving abilities. The methodology of this study included multiple forms of data collection. The participants were first given a survey to determine their prior experience with engineering and to provide a description of the subjects being studied. The participants were then presented an engineering design challenge to solve individually. While they completed the challenge, the participants verbalized their thoughts using an established "think aloud" method. These verbalizations were captured along with participant observational recordings using point-of-view camera technology. Additionally, the participant design journals, design artifacts, solution effectiveness data, and teacher evaluations were collected for analysis to help achieve the

  20. Process of converting actinide ions present in the solid residues of a sulphating process for radioactive solid waste containing actinides into a useful state

    International Nuclear Information System (INIS)

    Wieczorek, H.; Oser, B.

    1985-01-01

    Stages of the process: a) The residue is dissolved in water or 1 to 2 mole nitric acid, where the greater part is dissolved. b) The solution formed is separated from the insoluble part of the residue and is heated to a temperature below its boiling point. c) The hot solution has an aquaeous barium nitrate solution added to it with a quantity which slightly exceeds that required for the stochiometric complete precipitation of the sulphate ions. The solution is kept at the selected temperature for a period of 0.5 to 2 hours. d) After subsequent cooling to room temperature, the precipitated barium sulphate is separated and e) the actinide-nitrate solution is fed into an extractive reprocessing process. (orig./PW) [de

  1. Sustainable Process Design of Lignocellulose based Biofuel

    DEFF Research Database (Denmark)

    Mangnimit, Saranya; Malakul, Pomthong; Gani, Rafiqul

    the production and use of alternative and sustainable energy sources as rapidly as possible. Biofuel is a type of alternative energy that can be produced from many sources including sugar substances (such as sugarcane juice and molasses), starchy materials (such as corn and cassava), and lignocellulosic...... materials such as agricultural residual, straw and wood chips, the residual from wood industry. However, those sugar and starchy materials can be used not only to make biofuels but they are also food sources. Thus, lignocellulosic materials are interesting feed-stocls as they are inexpensive, abundantly...... available, and are also non-food crops. In this respect, Cassava rhizome has several characteristics that make it a potential feedstock for fuel ethanol production. It has high content of cellulose and hemicelluloses . The objective of this paper is to present a study focused on the sustainable process...

  2. Design of CAREM-25 Residual Heat Removal System: Nuclear Safety Aspects

    International Nuclear Information System (INIS)

    Zanocco, Pablo; Gimenez, Marcelo; Schlamp, Miguel; Barrera, M.

    2000-01-01

    In this paper Carem-25 residual heat removal system (RHRS) design is analyzed from the nuclear safety point of view.The proposed RHRS is a condenser that transfers the heat to a pool located in the upper level of the containment.The RHRS design basis accident is a reactor loss of heat sink.The following requirements were settled to be verified: a) To remove 2 MW, for a primary circuit pressure of 12.25 MPa and a pool temperature of 100 0 C. b) No condenser tubes flooding, for a primary circuit pressure of 14 MPa and a pool temperature of 100 0 C. c) To reach hot shutdown in 48-hrs, that is to remove of 0.6 MW for a primary circuit pressure of 2.3 MPa and a pool temperature of 120 0 C.Heat transfer regimes inside and outside the condenser and flow patterns were analyzed.Steady state conditions for the above design conditions were modeled.The design requirements were verified taking into account heat transfer coefficients uncertainties and their propagation to the equipment elevation in the containment over the RPV, in order to minimize its elevation and its possible flooding.The resulting condenser tubes were 2 S CH 160 TP 347 SS, with a total area of 4 m 2 and a required minimum height of 6 m from the RPV water level to the condenser outlet headers

  3. Optimisation of process parameters in friction stir welding based on residual stress analysis: a feasibility study

    DEFF Research Database (Denmark)

    Tutum, Cem Celal; Hattel, Jesper Henri

    2010-01-01

    The present paper considers the optimisation of process parameters in friction stir welding (FSW). More specifically, the choices of rotational speed and traverse welding speed have been investigated using genetic algorithms. The welding process is simulated in a transient, two......-dimensional sequentially coupled thermomechanical model in ANSYS. This model is then used in an optimisation case where the two objectives are the minimisation of the peak residual stresses and the maximisation of the welding speed. The results indicate that the objectives for the considered case are conflicting......, and this is presented as a Pareto optimal front. Moreover, a higher welding speed for a fixed rotational speed results, in general, in slightly higher stress levels in the tension zone, whereas a higher rotational speed for a fixed welding speed yields somewhat lower peak residual stress, however, a wider tension zone...

  4. Gas-Cooled Fast Breeder Reactor Preliminary Safety Information Document, Amendment 10. GCFR residual heat removal system criteria, design, and performance

    International Nuclear Information System (INIS)

    1980-01-01

    This report presents a comprehensive set of safety design bases to support the conceptual design of the gas-cooled fast breeder reactor (GCFR) residual heat removal (RHR) systems. The report is structured to enable the Nuclear Regulatory Commission (NRC) to review and comment in the licensability of these design bases. This report also presents information concerning a specific plant design and its performance as an auxiliary part to assist the NRC in evaluating the safety design bases

  5. Bioethanol production from corn stover residues. Process design and Life Cycle Assessment; Bioetanolo da resuidui della lavorazione del mais: process design e analisi del ciclo di vita

    Energy Technology Data Exchange (ETDEWEB)

    De Bari, I; Dinnino, G; Braccio, G [Dipartimento Tecnologie per l' Energia, Fonti Rinnovabili e Risparmio Energetico, ENEA, Centro Ricerche Trisaia, Matera (Italy)

    2008-07-01

    In this report, the mass and energy balance along with a land-to-wheel Life Cycle Assessment (LCA) is described for a corn stover-to-ethanol industrial process assumed to consist of the main technologies being researched at ENEA TRISAIA: pretreatment by steam explosion and enzymatic hydrolysis. The modelled plant has a processing capacity of 60kt/y (dimensioned on realistic supplying basins of residues in Italy); biomass is pre-treated by acid catalyzed-steam explosion; cellulose and hemicelluloses are hydrolyzed and separately fermented; enzymes are on-site produced. The main target was to minimize the consumption of fresh water, enzymes and energy. The results indicate that the production of 1kg bio ethanol (95.4 wt%) requires 3.5 kg biomass dry matter and produces an energy surplus up to 740 Wh. The main purpose of the LCA analysis was to assess the environmental impact of the entire life cycle from the bio ethanol production up to its end-use as E10 blended gasoline. Boustead Model was used as tool to compile the life cycle inventory. The results obtained and discussed in this reports suffer of some limitations deriving from the following main points: some process yields have been extrapolated according to optimistic development scenarios; the energy and steam recovery could be lower than that projected because of lacks in the real systems; water recycle could be limited by the yeast tolerance toward the potential accumulation of toxic compounds. Nevertheless, the detailed process analysis here provided has its usefulness in: showing the challenging targets (even if they are ambitious) to bet on to make the integrated process feasible; driving the choice of the most suitable technologies to bypass some process bottlenecks. [Italian] Questo rapporto illustra il bilancio di massa e di energia insieme alla valutazione del Ciclo di vita (LCA) per un processo industriale di produzione di bioetanolo da residui di mais costituito dalle principali tecnologie studiate

  6. Plastic deformation, residual stress, and crystalline texture measurements for in-process characterization of FCC metal alloys

    International Nuclear Information System (INIS)

    Ruud, C.O.; Jacobs, M.E.; Weedman, S.D.; Snoha, D.J.

    1989-01-01

    This paper describes the results of several on-going investigations on the measurement of plastic deformation, residual stress, and crystalline texture in nickel, copper, and aluminum base alloys by x-ray diffraction techniques. X-ray diffraction techniques have been shown to be effective in the measurement of plastic deformation, residual stress, and crystalline texture in FCC metals, from the breadth, position, and intensity of the x-ray diffraction peaks. The Ruud-Barrett position-sensitive scintillation detector has been demonstrated to be fast, non-contacting, and tolerant of detector to component distance variation -- necessary requirements for cost-effective in-process inspection of materials

  7. Materials in Participatory Design Processes

    DEFF Research Database (Denmark)

    Hansen, Nicolai Brodersen

    This dissertation presents three years of academic inquiry into the question of what role materials play in interaction design and participatory design processes. The dissertation aims at developing conceptual tools, based on Deweys pragmatism, for understanding how materials aid design reflection....... It has been developed using a research-through-design approach in which the author has conducted practical design work in order to investigate and experiment with using materials to scaffold design inquiry. The results of the PhD work is submitted as seven separate papers, submitted to esteemed journals...... and conferences within the field of interaction design and HCI. The work is motivated both by the growing interest in materials in interaction design and HCI and the interest in design processes and collaboration within those fields. At the core of the dissertation lies an interest in the many different materials...

  8. Distortion and residual stresses in structures reinforced with titanium straps for improved damage tolerance

    International Nuclear Information System (INIS)

    Liljedahl, C.D.M.; Fitzpatrick, M.E.; Edwards, L.

    2008-01-01

    Distortion and residual stresses induced during the manufacturing process of bonded crack retarders have been investigated. Titanium alloy straps were adhesively bonded to an aluminium alloy SENT specimen to promote fatigue crack growth retardation. The effect of three different strap dimensions was investigated. The spring-back of a component when released from the autoclave and the residual stresses are important factors to take into account when designing a selective reinforcement, as this may alter the local aerodynamic characteristics and reduce the crack bridging effect of the strap. The principal problem with residual stresses is that the tensile nature of the residual stresses in the primary aluminium structure has a negative impact on the crack initiation and crack propagation behaviour in the aluminium. The residual stresses were measured with neutron diffraction and the distortion of the specimens was measured with a contour measurement machine. The bonding process was simulated with a three-dimensional FE model. The residual stresses were found to be tensile close to the strap and slightly compressive on the un-bonded side. Both the distortion and the residual stresses increased with the thickness and the width of the strap. Very good agreement between the measured stresses and the measured distortion and the FE simulation was found

  9. Optimization of the Process Parameters for Controlling Residual Stress and Distortion in Friction Stir Welding

    DEFF Research Database (Denmark)

    Tutum, Cem Celal; Schmidt, Henrik Nikolaj Blicher; Hattel, Jesper Henri

    2008-01-01

    In the present paper, numerical optimization of the process parameters, i.e. tool rotation speed and traverse speed, aiming minimization of the two conflicting objectives, i.e. the residual stresses and welding time, subjected to process-specific thermal constraints in friction stir welding......, is investigated. The welding process is simulated in 2-dimensions with a sequentially coupled transient thermo-mechanical model using ANSYS. The numerical optimization problem is implemented in modeFRONTIER and solved using the Multi-Objective Genetic Algorithm (MOGA-II). An engineering-wise evaluation or ranking...

  10. External designers in product design processes of small manufacturing firms

    NARCIS (Netherlands)

    Berends, Hans; Reymen, Isabelle; Stultiëns, Rutger G L; Peutz, Murk

    Small manufacturing firms often fail to reap the benefits of good design practices. This study investigates how the involvement of external designers influences the evolution of product design processes in small manufacturing firms. Qualitative and quantitative process research methods were used to

  11. Influences of Processing and Fatigue Cycling on Residual Stresses in a NiCrY-Coated Powder Metallurgy Disk Superalloy

    Science.gov (United States)

    Gabb, T. P.; Rogers, R. B.; Nesbitt, J. A.; Miller, R. A.; Puleo, B. J.; Johnson, D.; Telesman, J.; Draper, S. L.; Locci, I. E.

    2017-11-01

    Oxidation and corrosion can attack superalloy disk surfaces exposed to increasing operating temperatures in some turbine engine environments. Any potential protective coatings must also be resistant to harmful fatigue cracking during service. The objective of this study was to investigate how residual stresses evolve in one such coating. Fatigue specimens of a powder metallurgy-processed disk superalloy were coated with a NiCrY coating, shot peened, and then subjected to fatigue in air at room and high temperatures. The effects of this processing and fatigue cycling on axial residual stresses and other aspects of the coating were assessed. While shot peening did induce beneficial compressive residual stresses in the coating and substrate, these stresses relaxed in the coating with subsequent heating. Several cast alloys having compositions near the coating were subjected to thermal expansion and tensile stress relaxation tests to help explain this response of residual stresses in the coating. For the coated fatigue specimens, this response contributed to earlier cracking of the coating than for the uncoated surface during long intervals of cycling at 760 °C. Yet, substantial compressive residual stresses still remained in the substrate adjacent to the coating, which were sufficient to suppress fatigue cracking there. The coating continued to protect the substrate from hot corrosion pitting, even after fatigue cracks initiated in the coating.

  12. Biomimetic design processes in architecture: morphogenetic and evolutionary computational design

    International Nuclear Information System (INIS)

    Menges, Achim

    2012-01-01

    Design computation has profound impact on architectural design methods. This paper explains how computational design enables the development of biomimetic design processes specific to architecture, and how they need to be significantly different from established biomimetic processes in engineering disciplines. The paper first explains the fundamental difference between computer-aided and computational design in architecture, as the understanding of this distinction is of critical importance for the research presented. Thereafter, the conceptual relation and possible transfer of principles from natural morphogenesis to design computation are introduced and the related developments of generative, feature-based, constraint-based, process-based and feedback-based computational design methods are presented. This morphogenetic design research is then related to exploratory evolutionary computation, followed by the presentation of two case studies focusing on the exemplary development of spatial envelope morphologies and urban block morphologies. (paper)

  13. Comparison of the composting process using ear corn residue and three other conventional bulking agents during cow manure composting under high-moisture conditions.

    Science.gov (United States)

    Hanajima, Dai

    2014-10-01

    To elucidate the characteristics of ear corn residue as a bulking agent, the composting process using this residue was compared with processes using three other conventional materials such as sawdust, wheat straw and rice husk, employing a bench-scale composting reactor. As evaluated via biochemical oxygen demand (BOD), ear corn residue contains 3.3 and 2.0 times more easily digestible materials than sawdust and rice husk, respectively. In addition, mixing ear corn residue with manure resulted in reduced bulk density, which was the same as that of wheat straw and was 0.58 and 0.67 times lower than that of sawdust and a rice husk mixture, respectively. To evaluate temperature generation during the composting process, the maximum temperature and area under the temperature curve (AUCTEMP) were compared among the mixed composts of four bulking agents. Maximum temperature (54.3°C) as well as AUCTEMP (7310°C●h) of ear corn residue were significantly higher than those of sawdust and rice husk (Pcompost. Along with the value of AUCTEMP, the highest organic matter losses of 31.1% were observed in ear corn residue mixed compost, followed by wheat straw, saw dust and rice husk. © 2014 Japanese Society of Animal Science.

  14. Formal analysis of design process dynamics

    NARCIS (Netherlands)

    Bosse, T.; Jonker, C.M.; Treur, J.

    2010-01-01

    This paper presents a formal analysis of design process dynamics. Such a formal analysis is a prerequisite to come to a formal theory of design and for the development of automated support for the dynamics of design processes. The analysis was geared toward the identification of dynamic design

  15. Formal Analysis of Design Process Dynamics

    NARCIS (Netherlands)

    Bosse, T.; Jonker, C.M.; Treur, J.

    2010-01-01

    This paper presents a formal analysis of design process dynamics. Such a formal analysis is a prerequisite to come to a formal theory of design and for the development of automated support for the dynamics of design processes. The analysis was geared toward the identification of dynamic design

  16. Weld residual stress according to the ways of heat input in the simulation of weld process using finite element analysis

    International Nuclear Information System (INIS)

    Yang, Jun Seog; Lee, Kyoung Soo; Park, Chi Yong

    2008-01-01

    This paper is to discuss distribution of welding residual stresses of a ferritic low alloy steel nozzle with dissimilar metal weld using Alloy 82/182. Two Dimensional (2D) thermo-mechanical finite element analyses are carried out to simulate multi-pass welding process on the basis of the detailed and fabrication data. On performing the welding analysis generally, the characteristics on the heat input and heat transfer of weld are affected on the weld residual stress analyses. Thermal analyses in the welding heat cycle process is very important process in weld residual stress analyses. Therefore, heat is rapidly input to the weld pass material, using internal volumetric heat generation, at a rate which raises the peak weld metal temperature to 2200 .deg. C and the base metal adjacent to the weld to about 1400 .deg. C. These are approximately the temperature that the weld metal and surrounding base materials reach during welding. Also, According to the various ways of applying the weld heat source, the predicted residual stress results are compared with measured axial, hoop and radial through-wall profiles in the heat affected zone of test component. Also, those results are compared with those of full 3-dimensional simulation

  17. Residual stress concerns in containment analysis

    International Nuclear Information System (INIS)

    Costantini, F.; Kulak, R. F.; Pfeiffer, P. A.

    1997-01-01

    The manufacturing of steel containment vessels starts with the forming of flat plates into curved plates. A steel containment structure is made by welding individual plates together to form the sections that make up the complex shaped vessels. The metal forming and welding process leaves residual stresses in the vessel walls. Generally, the effect of metal forming residual stresses can be reduced or virtually eliminated by thermally stress relieving the vesseL In large containment vessels this may not be practical and thus the residual stresses due to manufacturing may become important. The residual stresses could possibly tiect the response of the vessel to internal pressurization. When the level of residual stresses is significant it will affect the vessel's response, for instance the yielding pressure and possibly the failure pressure. The paper will address the effect of metal forming residual stresses on the response of a generic pressure vessel to internal pressurization. A scoping analysis investigated the effect of residual forming stresses on the response of an internally pressurized vessel. A simple model was developed to gain understanding of the mechanics of the problem. Residual stresses due to the welding process were not considered in this investigation

  18. Development of separation process of Dy, Y, Tm and Yb from heavier rare earth residue by solvent impregnated resin

    International Nuclear Information System (INIS)

    Shibata, J.; Matsumoto, S.

    1998-01-01

    Full text: Heavier rare earth which is contained in a small amount in ores such as bastnesite and monazite has been accumulated as heavier rare earth residue without doing separation and purification due to lack of suitable methods. The heavier rare earth residue includes seven rare earth elements such as Tb, Dy, Ho, Y, Er, Tm and Yb. Separation and recovery process of Dy, Y, Tm and Yb from leached solution of the heavier rare earth residue was investigated by using a column method with a solvent impregnated resin. The solvent impregnated resin was prepared by impregnation of organophosphorous extractant whose trade name is PC-88A into a macro porous resin, Amberlite XAD-7. It was almost impossible to separate them in simple adsorption and elution steps. However, we attained to individually separate Dy, Y, Tm and Yb from the leached solution first by changing eluent concentration gradually from pH 2 to 2mol/ l HCl in the elution step, and secondly by using a development column and changing eluent concentration in the elution step. The separation process flow was proposed for heavier rare earth residue by using the solvent impregnated resin method

  19. FAST PYROLYSIS PROCESS OF ORANGE SOLID WASTE. FACTORS INFLUENCE IN THE PROCESS

    Directory of Open Access Journals (Sweden)

    Leonardo Aguiar Trujillo

    2015-04-01

    Full Text Available The orange processing industry generates high volumes of solid residue. This residue has been used in animal feeding and biochemical processes. A possible energy use of the waste can be thermochemical fast pyrolysis process. The objective was to determine the influence of the heating rate and temperature in the process of rapid pyrolysis of orange solid residue. In the process a design, 2k full factorial experiment was used, evaluating the influence of the independent variables and its interactions on the answers, using a 95 % significance level. We found that temperature is the most significant influence on the responses parameter having significant influence on the yields to: gas, coal, tar and the calorific value of the gas and the heating rate does not influence the answers. Finally, the interaction affects the gas yield. The results obtained in this study are: Rgas (19 – 38 %, Rchar (25 – 42 %, Ralq (6 – 12 %, PCIgas entre (140 – 1050 kJ/m3N.

  20. Implementing The Safeguards-By-Design Process

    International Nuclear Information System (INIS)

    Whitaker, J. Michael; McGinnis, Brent; Laughter, Mark D.; Morgan, Jim; Bjornard, Trond; Bean, Robert; Durst, Phillip; Hockert, John; DeMuth, Scott; Lockwood, Dunbar

    2010-01-01

    The Safeguards-by-Design (SBD) approach incorporates safeguards into the design and construction of nuclear facilities at the very beginning of the design process. It is a systematic and structured approach for fully integrating international and national safeguards for material control and accountability (MC and A), physical protection, and other proliferation barriers into the design and construction process for nuclear facilities. Implementing SBD is primarily a project management or project coordination challenge. This paper focuses specifically on the design process; the planning, definition, organization, coordination, scheduling and interaction of the safeguards experts and stakeholders as they participate in the design and construction of a nuclear facility. It delineates the steps in a nuclear facility design and construction project in order to provide the project context within which the safeguards design activities take place, describes the involvement of the safeguards experts in the design process, the nature of their analyses, interactions and decisions, and describes the documents created and how they are used. This report highlights the project context of safeguards activities, and identifies the safeguards community (nuclear facility operator, designer/builder, state regulator, SSAC and IAEA) must accomplish in order to implement SBD within the project.

  1. Experimental and numerical investigation on cold flat rolling processes of DC04 sheets with special focus on residual stresses

    International Nuclear Information System (INIS)

    Bauer, A; Binotsch, C; Awiszus, B; Mehner, T; Sieber, M; Lampke, T

    2016-01-01

    The process of cold flat rolling is a widespread industrial technique to manufacture semi-finished products, e.g., for the automotive or homewares industry. Basic knowledge of the process regarding dimensioning and adjustment of defined characteristics is already state of the art. However, a detailed consideration and analysis with respect to local inhomogeneous residual stresses in several process steps mostly remains disregarded. A broad understanding of the process due to the distribution of residual stresses in the workpiece and the direction of the stress tensors allows for a definition of the characteristics of the workpiece even before the actual manufacturing process. For that purpose, it is necessary to perform numerical investigations by means of the finite element analysis (FEA) of cold flat rolling processes. Within this contribution, several approaches for the calibration of the FEA with the real flat rolling process will be addressed and discussed. To ensure that the numerical consideration provides realistic results, this calibration is indispensable. General parameters such as geometry, height reduction, rolling temperature, process time, and the rolling speed are considered as well as a photogrammetric survey, and calculated residual stresses with results of X-ray diffraction (XRD) will be compared. In the course of the experiments, a good agreement between the stress results of the FEA and the XRD was found in the center of the specimen. In combination with the allocation of the stress orientations, the agreement close to the edges is also fine. Some issues that cause differences between the FEA and the experiment are dis-cussed. (paper)

  2. Solid residues

    International Nuclear Information System (INIS)

    Mulder, E.; Duin, P.J. van; Grootenboer, G.J.

    1995-01-01

    A summary is presented of the many investigations that have been done on solid residues of atmospheric fluid bed combustion (AFBC). These residues are bed ash, cyclone ash and bag filter ash. Physical and chemical properties are discussed and then the various uses of residues (in fillers, bricks, gravel, and for recovery of aluminium) are summarised. Toxicological properties of fly ash and stack ash are discussed as are risks of pneumoconiosis for workers handling fly ash, and contamination of water by ashes. On the basis of present information it is concluded that risks to public health from exposure to emissions of coal fly ash from AFBC appear small or negligible as are health risk to workers in the coal fly ash processing industry. 35 refs., 5 figs., 12 tabs

  3. Determination of Pesticides Residues in Cucumbers Grown in Greenhouse and the Effect of Some Procedures on Their Residues.

    Science.gov (United States)

    Leili, Mostafa; Pirmoghani, Amin; Samadi, Mohammad Taghi; Shokoohi, Reza; Roshanaei, Ghodratollah; Poormohammadi, Ali

    2016-11-01

    The objective of this study was to determine the residual concentrations of ethion and imidacloprid in cucumbers grown in greenhouse. The effect of some simple processing procedures on both ethion and imidacloprid residues were also studied. Ten active greenhouses that produce cucumber were randomly selected. Ethion and imidacloprid as the most widely used pesticides were measured in cucumber samples of studied greenhouses. Moreover, the effect of storing, washing, and peeling as simple processing procedures on both ethion and imidacloprid residues were investigated. One hour after pesticide application; the maximum residue levels (MRLs) of ethion and imidacloprid were higher than that of Codex standard level. One day after pesticide application, the levels of pesticides were decreased about 35 and 31% for ethion and imidacloprid, respectively, which still were higher than the MRL. Washing procedure led to about 51 and 42.5% loss in ethion and imidacloprid residues, respectively. Peeling procedure also led to highest loss of 93.4 and 63.7% in ethion and imidacloprid residues, respectively. The recovery for both target analytes was in the range between 88 and 102%. The residue values in collected samples one hour after pesticides application were higher than standard value. The storing, washing, and peeling procedures lead to the decrease of pesticide residues in greenhouse cucumbers. Among them, the peeling procedure has the greatest impact on residual reduction. Therefore, these procedures can be used as simple and effective processing techniques for reducing and removing pesticides from greenhouse products before their consumption.

  4. Initial design process of the repository

    International Nuclear Information System (INIS)

    Osmanlioglu, A.E.

    2001-01-01

    The concept of the final disposal of high level wastes is to isolate the waste from the biosphere for extremely long periods of time by emplacement of wastes into deep stable geological formations. Several geological formations have been considered as candidate host environments for high level waste disposal and several techniques have been developed for repository design. In this study, interrelationships of main parameters of a general repository design have been defined and effective parameters are shown at each step. Initial design process is based on the long term stability of underground openings as disposal galleries. For this reason, this design process includes two main analyses: mechanical analysis and thermal analysis. Each of the analysis systems is directly related to each other by technical precautions. As a result of this design process, general information about the acceptable depth of the repository, layout and emplacement pattern can be taken. Final design study can be established on the result of initial design process. (author)

  5. Development of a Chlorine Dosing Strategy for Fresh Produce Washing Process to Maintain Microbial Food Safety and Minimize Residual Chlorine.

    Science.gov (United States)

    Chen, Xi; Hung, Yen-Con

    2018-05-22

    The residual free chlorine level in fresh produce wash solution is closely correlated to the chemical and microbial safety of produce. Excess amount of free chlorine can quickly react with organic matters to form hazardous disinfection by-products (DBPs) above EPA-permitted levels, whereas deficiency of residual chlorine in produce wash solution may result in incompletely removing pathogens on produce. The purpose of this study was to develop a chlorine dosing strategy to optimize the chlorine dosage during produce washing process without impacting the microbial safety of fresh produce. Prediction equations were developed to estimate free chlorine needed to reach targeted residual chlorine at various sanitizer pH and organic loads, and then validated using fresh-cut iceberg lettuce and whole strawberries in an automated produce washer. Validation results showed that equations successfully predicted the initial chlorine concentration needed to achieve residual chlorine at 10, 30, 60, and 90 mg/L for both lettuce and strawberry washing processes, with the root mean squared error at 4.45 mg/L. The Escherichia coli O157:H7 reductions only slightly increased on iceberg lettuce and strawberries with residual chlorine increasing from 10 to 90 mg/L, indicating that lowering residual chlorine to 10 mg/L would not compromise the antimicrobial efficacy of chlorine-based sanitizer. Based on the prediction equations and E. coli O157:H7 reduction results, a chlorine dosing strategy was developed to help the produce industry to maintain microbial inactivation efficacy without adding excess amount of free chlorine. The chlorine dosing strategy can be used for fresh produce washing process to enhance the microbial food safety and minimize the DBPs formation potential. © 2018 Institute of Food Technologists®.

  6. Fundamentals of a moderate thermocracking-deep deasphalting combined process of Karamay vacuum residue

    Energy Technology Data Exchange (ETDEWEB)

    Zhiming, X; Tonghua, L.; Suogi, Z.; Renan, W. [University of Petroleum, State Key Laboratory of Heavy Oil Processing, Beijing (China); Lailong, L.; Zhen, L. [Karamay Petrochemical Company, Petrochemical Research Institute, Karamay (China)

    2004-07-01

    Thermocracking of heavy oil vacuum residue was carried out to determine the optimum conditions for the thermal cracking of Karamay vacuum residue prior to coke formation. The vacuum residue and the cracked residue after distillation were separated using supercritical fluid extraction and fractionation techniques. Sixteen and thirteen fractions and non-extractable end cuts respectively were separated, and their properties, compositions and average structures determined. Solubility parameters of the end cuts were measured, and those of the fractions calculated. The solubility parameter of the end cut of distilled residue was found to have greatly increased. It was determined that when the difference of the end cut and the extractable fractions amounts to 6.37MPa1/2, in the case of Karamay vacuum residue coke will deposit under thermocracking conditions. Based on the results of a series of solvent deep deasphalting experiments, a scheme for vacuum residue thermocracking and deasphalting of the cracked residue was proposed.

  7. High level compressive residual stresses produced in aluminum alloys by laser shock processing

    International Nuclear Information System (INIS)

    Gomez-Rosas, G.; Rubio-Gonzalez, C.; Ocana, J.L; Molpeceres, C.; Porro, J.A.; Chi-Moreno, W.; Morales, M.

    2005-01-01

    Laser shock processing (LSP) has been proposed as a competitive alternative technology to classical treatments for improving fatigue and wear resistance of metals. We present a configuration and results for metal surface treatments in underwater laser irradiation at 1064 nm. A convergent lens is used to deliver 1.2 J/cm 2 in a 8 ns laser FWHM pulse produced by 10 Hz Q-switched Nd:YAG, two laser spot diameters were used: 0.8 and 1.5 mm. Results using pulse densities of 2500 pulses/cm 2 in 6061-T6 aluminum samples and 5000 pulses/cm 2 in 2024 aluminum samples are presented. High level of compressive residual stresses are produced -1600 MPa for 6061-T6 Al alloy, and -1400 MPa for 2024 Al alloy. It has been shown that surface residual stress level is higher than that achieved by conventional shot peening and with greater depths. This method can be applied to surface treatment of final metal products

  8. Conceptual Chemical Process Design for Sustainability.

    Science.gov (United States)

    This chapter examines the sustainable design of chemical processes, with a focus on conceptual design, hierarchical and short-cut methods, and analyses of process sustainability for alternatives. The chapter describes a methodology for incorporating process sustainability analyse...

  9. Development of standardized approaches to reporting of minimal residual disease data using a reporting software package designed within the European LeukemiaNet

    DEFF Research Database (Denmark)

    Ostergaard, M; Nyvold, Charlotte Guldborg; Jovanovic, J V

    2011-01-01

    Quantitative PCR (qPCR) for detection of fusion transcripts and overexpressed genes is a promising tool for following minimal residual disease (MRD) in patients with hematological malignancies. Its widespread clinical use has to some extent been hampered by differences in data analysis and presen......Quantitative PCR (qPCR) for detection of fusion transcripts and overexpressed genes is a promising tool for following minimal residual disease (MRD) in patients with hematological malignancies. Its widespread clinical use has to some extent been hampered by differences in data analysis...... and presentation that complicate multicenter clinical trials. To address these issues, we designed a highly flexible MRD-reporting software program, in which data from various qPCR platforms can be imported, processed, and presented in a uniform manner to generate intuitively understandable reports. The software...... was tested in a two-step quality control (QC) study; the first step involved eight centers, whose previous experience with the software ranged from none to extensive. The participants received cDNA from consecutive samples from a BCR-ABL+ chronic myeloid leukemia (CML) patient and an acute myeloid leukemia...

  10. Practicing universal design to actual hand tool design process.

    Science.gov (United States)

    Lin, Kai-Chieh; Wu, Chih-Fu

    2015-09-01

    UD evaluation principles are difficult to implement in product design. This study proposes a methodology for implementing UD in the design process through user participation. The original UD principles and user experience are used to develop the evaluation items. Difference of product types was considered. Factor analysis and Quantification theory type I were used to eliminate considered inappropriate evaluation items and to examine the relationship between evaluation items and product design factors. Product design specifications were established for verification. The results showed that converting user evaluation into crucial design verification factors by the generalized evaluation scale based on product attributes as well as the design factors applications in product design can improve users' UD evaluation. The design process of this study is expected to contribute to user-centered UD application. Copyright © 2015 Elsevier Ltd and The Ergonomics Society. All rights reserved.

  11. Process Variations and Probabilistic Integrated Circuit Design

    CERN Document Server

    Haase, Joachim

    2012-01-01

    Uncertainty in key parameters within a chip and between different chips in the deep sub micron era plays a more and more important role. As a result, manufacturing process spreads need to be considered during the design process.  Quantitative methodology is needed to ensure faultless functionality, despite existing process variations within given bounds, during product development.   This book presents the technological, physical, and mathematical fundamentals for a design paradigm shift, from a deterministic process to a probability-orientated design process for microelectronic circuits.  Readers will learn to evaluate the different sources of variations in the design flow in order to establish different design variants, while applying appropriate methods and tools to evaluate and optimize their design.  Trains IC designers to recognize problems caused by parameter variations during manufacturing and to choose the best methods available to mitigate these issues during the design process; Offers both qual...

  12. Distribution of multiple pesticide residues in apple segments after home processing

    DEFF Research Database (Denmark)

    Rasmussen, Rie Romme; Poulsen, Mette Erecius; Hansen, H. C. B.

    2003-01-01

    The effects of washing, storing, boiling, peeling, coring and juicing on pesticide residue were investigated for field-sprayed Discovery and Jonagold apples. Residues of chlorpyrifos, cypermethrin, deltamethrin, diazinon, endosulfan, endosulfan sulfate, fenitrothion, fenpropathrin, iprodione, kre...

  13. Thermal-hydraulic processes involved in loss of residual heat removal during reduced inventory operation

    International Nuclear Information System (INIS)

    Fletcher, C.D.; McHugh, P.R.; Naff, S.A.; Johnsen, G.W.

    1991-02-01

    This paper identifies the topics needed to understand pressurized water reactor response to an extended loss of residual heat removal event during refueling and maintenance outages. By identifying the possible plant conditions and cooling methods that would be used for each cooling mode, the controlling thermal-hydraulic processes and phenomena were identified. Controlling processes and phenomena include: gravity drain, core water boil-off, and reflux cooling processes. Important subcategories of the reflux cooling processes include: the initiation of reflux cooling from various plant conditions, the effects of air on reflux cooling, core level depression effects, issues regarding the steam generator secondaries, and the special case of boiler-condenser cooling with once-through steam generators. 25 refs., 6 figs., 1 tab

  14. Effect of processing conditions and methods on residual stress in CeO2 buffer layers and YBCO superconducting films

    International Nuclear Information System (INIS)

    Xiong Jie; Qin Wenfeng; Cui Xumei; Tao Bowan; Tang Jinlong; Li Yanrong

    2006-01-01

    CeO 2 layers have been fabricated by pulsed laser deposition (PLD) technique on (1 1 0 2) sapphire substrate. Microstructure of CeO 2 layers is characterized by X-ray diffraction as functions of substrate temperature. The effects of the substrate temperature on the residual stress have been studied. The results show that residual stress in CeO 2 film decreased with increasing substrate temperature, not the same development tendency as that of thermal stress. This means that the thermal stress is only a fraction of the residual stress. Moreover, YBCO superconducting films were prepared by direct current (DC) sputtering and pulsed laser deposition (PLD) technique. The residual stress and thermal stress of both YBCO films were measured. PLD processing apparently generated higher intrinsic compressive stresses in comparison to DC sputtering

  15. Ergonomics approaches to sociotechnical design processes

    DEFF Research Database (Denmark)

    Broberg, Ole

    2003-01-01

    A five-year design process of a continuous process wok has been studied with the aim of elucidating the conditions for integrating work environment aspects. The design process was seen as a network building activity and as a social shaping process of the artefact. A work environment log is sugges...

  16. Technospheric Mining of Rare Earth Elements from Bauxite Residue (Red Mud): Process Optimization, Kinetic Investigation, and Microwave Pretreatment.

    Science.gov (United States)

    Reid, Sable; Tam, Jason; Yang, Mingfan; Azimi, Gisele

    2017-11-10

    Some rare earth elements (REEs) are classified under critical materials, i.e., essential in use and subject to supply risk, due to their increasing demand, monopolistic supply, and environmentally unsustainable and expensive mining practices. To tackle the REE supply challenge, new initiatives have been started focusing on their extraction from alternative secondary resources. This study puts the emphasis on technospheric mining of REEs from bauxite residue (red mud) produced by the aluminum industry. Characterization results showed the bauxite residue sample contains about 0.03 wt% REEs. Systematic leaching experiments showed that concentrated HNO 3 is the most effective lixiviant. However, because of the process complexities, H 2 SO 4 was selected as the lixiviant. To further enhance the leaching efficiency, a novel process based on microwave pretreatment was employed. Results indicated that microwave pretreatment creates cracks and pores in the particles, enabling the lixiviant to diffuse further into the particles, bringing more REEs into solution, yielding of 64.2% and 78.7% for Sc and Nd, respectively, which are higher than the maximum obtained when HNO 3 was used. This novel process of "H 2 SO 4 leaching-coupled with-microwave pretreatment" proves to be a promising technique that can help realize the technological potential of REE recovery from secondary resources, particularly bauxite residue.

  17. A design method for process design kit based on an SMIC 65 nm process

    International Nuclear Information System (INIS)

    Luo Haiyan; Chen Lan; Yin Minghui

    2010-01-01

    The frame structure of a process design kit (PDK) is described in detail, and a practical design method for PDK is presented. Based on this method, a useful SMIC 65 nm PDK has been successfully designed and realized, which is applicable to native EDA software of Zeni. The design process and difficulties of PDK are introduced by developing and analyzing these parameterized cell (Pcell) devices (MOS, resistor, etc.). A structured design method was proposed to implement Pcell, which makes thousands upon thousands of source codes of Pcell concise, readable, easy-to-upkeep and transplantable. Moreover, a Pcase library for each Pcell is designed to verify the Pcell in batches. By this approach, the Pcell can be verified efficiently and the PDK will be more reliable and steady. In addition, the component description format parameters and layouts of the Pcell are optimized by adding flexibility and improving performance, which benefits analog and custom IC designers to satisfy the demand of design. Finally, the SMIC 65 nm PDK was applied to IC design. The results indicate that the SMIC 65 nm PDK is competent to support IC design. (semiconductor integrated circuits)

  18. NMR studies of stock process water and reaction pathways in hydrothermal carbonization of furfural residue

    Directory of Open Access Journals (Sweden)

    Fen Yue

    2018-04-01

    Full Text Available Hydrothermal carbonization (HTC is a valuable approach to convert furfural residue (FR into carbon material. The prepared biochars are usually characterized comprehensively, while the stock process water still remains to be studied in detail. Herein, a NMR study of the main components in stock process water generated at different HTC reaction conditions was reported. Various qualitative and quantitative NMR techniques (1H and 13C NMR, 1H–1H COSY and 1H13C HSQC etc. especially 1D selective gradient total correlation spectroscopy (TOCSY NMR were strategically applied in the analysis of HTC stock process water. Without separation and purification, it was demonstrated that the main detectable compounds are 5-hydroxymethylfurfural, formic acid, methanol, acetic acid, levulinic acid, glycerol, hydroxyacetone and acetaldehyde in this complicate mixture. Furthermore, the relationship between the concentration of major products and the reaction conditions (180–240 °C at 8 h, and 1–24 h at 240 °C was established. Finally, reasonable reaction pathways for hydrothermal conversion of FR were proposed based on this result and our previously obtained characteristics of biochars. The routine and challenging NMR methods utilized here would be an alternative other than HPLC or GC for biomass conversion research and can be extended to more studies. Keywords: NMR, Hydrothermal carbonization, Furfural residue, Stock process water

  19. An investigative approach to explore optimum assembly process design for annular targets carrying LEU foil

    Science.gov (United States)

    Hoyer, Annemarie

    Technetium-99m is the most widely used nuclear isotope in the medical field, with nearly 80 to 85% of all diagnostic imaging procedures. The daughter isotope of molybdenum-99 is currently produced using weapons-grade uranium. A suggested design for aluminum targets carrying low-enriched uranium (LEU) foil is presented for the fulfillment of eliminating highly enriched uranium (HEU) for medical isotope production. The assembly process that this research focuses on is the conventional draw-plug process which is currently used and lastly the sealing process. The research is unique in that it is a systematic approach to explore the optimal target assembly process to produce those targets with the required quality and integrity. Conducting 9 parametric experiments, aluminum tubes with a nickel foil fission-barrier and a surrogate stainless steel foil are assembled, welded and then examined to find defects, to determine residual stresses, and to find the best cost-effective target dimensions. The experimental design consists of 9 assembly combinations that were found through orthogonal arrays in order to explore the significance of each factor. Using probabilistic modeling, the parametric study is investigated using the Taguchi method of robust analysis. Depending on the situation, optimal conditions may be a nominal, a minimized or occasionally a maximized condition. The results will provide the best target design and will give optimal quality with little or no assembly defects.

  20. Determination of neomycin residues in pasteurized milks produced in some dairy processing establishments in East-Azarbaijan Province, Iran

    Directory of Open Access Journals (Sweden)

    M.H Movassagh

    2014-11-01

    Full Text Available Antibiotic residues in milk have a potential hazard for the consumer and may cause allergic reactions, interference in the intestinal flora that result in development of resistant populations of bacteria, thereby rendering antibiotic treatment ineffective. The aim of this study was to determine neomycin residues in pasteurized milk in East-Azarbaijan province. For this, a total of 200 samples of pasteurized milk produced by five dairy processing establishments of East Azarbaijan province was randomly collected. The samples were obtained over the spring and autumn (100 samples for each season of 2010. First, antibiotic residues were determined by Copan milk test. Afterwards, the competitive ELISA assay was used for the determination of neomycin concentration in positive samples. Of all samples, neomycin residues were observed in 9 and 13 samples and the mean neomycin residues amount were 43.20 ± 8.10 and 26.63±2.08 µg/L in spring and autumn, respectively. According to the limit of neomycin (1500 µg/l in cow raw milk in Iran, despite all the remaining drugs in pasteurized milk, in any of the samples exceeded level of neomycin was not observed.Based on the results, continuousmonitoringofantibiotic residues inmilk samples is recommended.

  1. A test of a design process scale

    NARCIS (Netherlands)

    Marinakis, Yorgos; Harms, Rainer; Walsh, Steven Thomas

    2015-01-01

    Design is a type of innovation that focuses on creating new product and service meanings. Models of the design process are important because they can help firms manage their product and service design processes to obtain competitive advantage. Empirically-based models of the design process are

  2. Advanced immobilization processes for fuel hulls and dissolver residues

    International Nuclear Information System (INIS)

    Hebel, W.; Boehme, G.; Findlay, J.R.; Sombret, C.

    1984-08-01

    Various research and development projects for the conditioning of cladding scraps and dissolver residues are pursued within the scope of the R and D programme on nuclear waste Management of the European Community. They include the characterization of the waste materials arising from industrial fuel reprocessing and the development of different waste immobilization techniques. These concern the embedment of scraps and residues into inert matrices like cement, metal alloys, compacted graphite and sintered ceramics as well as the treatment of the fuel hulls by melting or chemical conversion. The conditioned waste forms are tested as to their relevant properties for activity enclosure

  3. Advanced immobilization processes for fuel hulls and dissolver residues

    International Nuclear Information System (INIS)

    Hebel, W.; Boehme, G.; Findlay, J.R.; Sombert, C.

    1984-01-01

    Various research and development projects for the conditioning of cladding scraps and dissolver residues are pursued within the scope of the R and D programme on nuclear waste Management of the European Community. They include the characterization of the waste materials arising from industrial fuel reprocessing and the development of different waste immobilization techniques. These concern the embedment of the scraps and residues into inert matrices like cement, metal alloys, compacted graphite and sintered ceramics as well as the treatment of the fuel hulls by melting or chemical conversion. The conditioned waste forms are tested as to their relevant properties for activity enclosure

  4. Model-checking techniques based on cumulative residuals.

    Science.gov (United States)

    Lin, D Y; Wei, L J; Ying, Z

    2002-03-01

    Residuals have long been used for graphical and numerical examinations of the adequacy of regression models. Conventional residual analysis based on the plots of raw residuals or their smoothed curves is highly subjective, whereas most numerical goodness-of-fit tests provide little information about the nature of model misspecification. In this paper, we develop objective and informative model-checking techniques by taking the cumulative sums of residuals over certain coordinates (e.g., covariates or fitted values) or by considering some related aggregates of residuals, such as moving sums and moving averages. For a variety of statistical models and data structures, including generalized linear models with independent or dependent observations, the distributions of these stochastic processes tinder the assumed model can be approximated by the distributions of certain zero-mean Gaussian processes whose realizations can be easily generated by computer simulation. Each observed process can then be compared, both graphically and numerically, with a number of realizations from the Gaussian process. Such comparisons enable one to assess objectively whether a trend seen in a residual plot reflects model misspecification or natural variation. The proposed techniques are particularly useful in checking the functional form of a covariate and the link function. Illustrations with several medical studies are provided.

  5. Teaching Process Design through Integrated Process Synthesis

    Science.gov (United States)

    Metzger, Matthew J.; Glasser, Benjamin J.; Patel, Bilal; Hildebrandt, Diane; Glasser, David

    2012-01-01

    The design course is an integral part of chemical engineering education. A novel approach to the design course was recently introduced at the University of the Witwatersrand, Johannesburg, South Africa. The course aimed to introduce students to systematic tools and techniques for setting and evaluating performance targets for processes, as well as…

  6. Information-Processing Models and Curriculum Design

    Science.gov (United States)

    Calfee, Robert C.

    1970-01-01

    "This paper consists of three sections--(a) the relation of theoretical analyses of learning to curriculum design, (b) the role of information-processing models in analyses of learning processes, and (c) selected examples of the application of information-processing models to curriculum design problems." (Author)

  7. Decontamination of chlorantraniliprole residues on cabbage and cauliflower through household processing methods.

    Science.gov (United States)

    Kar, Abhijit; Mandal, Kousik; Singh, Balwinder

    2012-04-01

    A supervised field trial was conducted to study the residues of chlorantraniliprole on cabbage and cauliflower. Three applications of chlorantraniliprole at 10 days interval were made @ 9.25 and 18.50 g a.i. ha(-1). The samples of marketable size heads and curds of cabbage and cauliflower were collected at 0 and 1 day after the last application. QuEChERS sample preparation was used for the determination of chlorantraniliprole residues on cabbage heads and cauliflower curds. The residues of chlorantraniliprole were quantified by high performance liquid chromatography (HPLC) with photo diode array (PDA) detector and confirmed by high performance thin layer chromatography (HPTLC). Washing of cabbage and cauliflower with tap water removed about 17%-40% of chlorantraniliprole residues. However, boiling removed 100% of chlorantraniliprole residues on cabbage and cauliflower in both the cases.

  8. Applications of bauxite residue: A mini-review.

    Science.gov (United States)

    Verma, Ajay S; Suri, Narendra M; Kant, Suman

    2017-10-01

    Bauxite residue is the waste generated during alumina production by Bayer's process. The amount of bauxite residue (40-50 wt%) generated depends on the quality of bauxite ore used for the processing. High alkalinity and high caustic content in bauxite residue causes environmental risk for fertile soil and ground water contamination. The caustic (NaOH) content in bauxite residue leads to human health risks, like dermal problems and irritation to eyes. Moreover, disposal of bauxite residue requires a large area; such problems can only be minimised by utilising bauxite residue effectively. For two decades, bauxite residue has been used as a binder in cement industries and filler/reinforcement for composite materials in the automobile industry. Valuable metals and oxides, like alumina (Al 2 O 3 ), titanium oxide (TiO 2 ) and iron oxide Fe 2 O 3 , were extracted from bauxite residue to reduce waste. Bauxite residue was utilised in construction and structure industries to make geopolymers. It was also used in the making of glass-ceramics and a coating material. Recently bauxite residue has been utilised to extract rare earth elements like scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), neodymium (Nd) and dysprosium (Dy). In this review article, the mineralogical characteristics of bauxite residue are summarised and current progresses on utilisation of bauxite residue in different fields of science and engineering are presented in detail.

  9. Sustainable System for Residual Hazards Management

    International Nuclear Information System (INIS)

    Kevin M. Kostelnik; James H. Clarke; Jerry L. Harbour

    2004-01-01

    Hazardous, radioactive and other toxic substances have routinely been generated and subsequently disposed of in the shallow subsurface throughout the world. Many of today's waste management techniques do not eliminate the problem, but rather only concentrate or contain the hazardous contaminants. Residual hazards result from the presence of hazardous and/or contaminated material that remains on-site following active operations or the completion of remedial actions. Residual hazards pose continued risk to humans and the environment and represent a significant and chronic problem that require continuous long-term management (i.e. >1000 years). To protect human health and safeguard the natural environment, a sustainable system is required for the proper management of residual hazards. A sustainable system for the management of residual hazards will require the integration of engineered, institutional and land-use controls to isolate residual contaminants and thus minimize the associated hazards. Engineered controls are physical modifications to the natural setting and ecosystem, including the site, facility, and/or the residual materials themselves, in order to reduce or eliminate the potential for exposure to contaminants of concern (COCs). Institutional controls are processes, instruments, and mechanisms designed to influence human behavior and activity. System failure can involve hazardous material escaping from the confinement because of system degradation (i.e., chronic or acute degradation) or by external intrusion of the biosphere into the contaminated material because of the loss of institutional control. An ongoing analysis of contemporary and historic sites suggests that the significance of the loss of institutional controls is a critical pathway because decisions made during the operations/remedial action phase, as well as decisions made throughout the residual hazards management period, are key to the long-term success of the prescribed system. In fact

  10. Actinide recovery from pyrochemical residues

    International Nuclear Information System (INIS)

    Avens, L.R.; Clifton, D.G.; Vigil, A.R.

    1984-01-01

    A new process for recovery of plutonium and americium from pyrochemical waste has been demonstrated. It is based on chloride solution anion exchange at low acidity, which eliminates corrosive HCl fumes. Developmental experiments of the process flowsheet concentrated on molten salt extraction (MSE) residues and gave >95% plutonium and >90% americium recovery. The recovered plutonium contained 6 = from high chloride-low acid solution. Americium and other metals are washed from the ion exchange column with 1N HNO 3 -4.8M NaCl. The plutonium is recovered, after elution, via hydroxide precipitation, while the americium is recovered via NaHCO 3 precipitation. All filtrates from the process are discardable as low-level contaminated waste. Production-scale experiments are now in progress for MSE residues. Flow sheets for actinide recovery from electrorefining and direct oxide reduction residues are presented and discussed

  11. Actinide recovery from pyrochemical residues

    International Nuclear Information System (INIS)

    Avens, L.R.; Clifton, D.G.; Vigil, A.R.

    1985-05-01

    We demonstrated a new process for recovering plutonium and americium from pyrochemical waste. The method is based on chloride solution anion exchange at low acidity, or acidity that eliminates corrosive HCl fumes. Developmental experiments of the process flow chart concentrated on molten salt extraction (MSE) residues and gave >95% plutonium and >90% americium recovery. The recovered plutonium contained 6 2- from high-chloride low-acid solution. Americium and other metals are washed from the ion exchange column with lN HNO 3 -4.8M NaCl. After elution, plutonium is recovered by hydroxide precipitation, and americium is recovered by NaHCO 3 precipitation. All filtrates from the process can be discardable as low-level contaminated waste. Production-scale experiments are in progress for MSE residues. Flow charts for actinide recovery from electro-refining and direct oxide reduction residues are presented and discussed

  12. Prediction of interface residue based on the features of residue interaction network.

    Science.gov (United States)

    Jiao, Xiong; Ranganathan, Shoba

    2017-11-07

    Protein-protein interaction plays a crucial role in the cellular biological processes. Interface prediction can improve our understanding of the molecular mechanisms of the related processes and functions. In this work, we propose a classification method to recognize the interface residue based on the features of a weighted residue interaction network. The random forest algorithm is used for the prediction and 16 network parameters and the B-factor are acting as the element of the input feature vector. Compared with other similar work, the method is feasible and effective. The relative importance of these features also be analyzed to identify the key feature for the prediction. Some biological meaning of the important feature is explained. The results of this work can be used for the related work about the structure-function relationship analysis via a residue interaction network model. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Hanford Site Tank 241-C-108 Residual Waste Contaminant Release Models and Supporting Data

    Energy Technology Data Exchange (ETDEWEB)

    Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Arey, Bruce W.; Schaef, Herbert T.

    2010-06-18

    This report presents the results of laboratory characterization, testing, and analysis for a composite sample (designated 20578) of residual waste collected from single-shell tank C-108 during the waste retrieval process after modified sluicing. These studies were completed to characterize concentration and form of contaminant of interest in the residual waste; assess the leachability of contaminants from the solids; and develop release models for contaminants of interest. Because modified sluicing did not achieve 99% removal of the waste, it is expected that additional retrieval processing will take place. As a result, the sample analyzed here is not expected to represent final retrieval sample.

  14. Process from removing benzine, toluene, etc. , from petroleum residues, coal tar, and shale tar, etc

    Energy Technology Data Exchange (ETDEWEB)

    Hlawaty, F

    1888-08-11

    A process is described for the preparation of ligroin and its homologs as well as naphthalene and anthracene consisting in leading superheated water vapor into a mixture of petroleum residues (or mineral coal tar, etc.) heated to about 400/sup 0/C with cellulosic substances as sage shreds, sea grass, or straw, with addition of caustic alkali.

  15. Detection of Salmonella spp., Candida albicans, Aspergillus spp., and Antimicrobial Residues in Raw and Processed Cow Milk from Selected Smallholder Farms of Zimbabwe

    Directory of Open Access Journals (Sweden)

    Tryness Anastazia Mhone

    2012-01-01

    Full Text Available A cross-sectional study was conducted to detect the presence of Salmonella spp., Candida albicans, Aspergillus spp., and antimicrobial residues in raw milk (n=120 and processed cow milk (n=20 from smallholder dairy farms from three sites in Zimbabwe. Culture and isolation of Salmonella spp., C. albicans, and Aspergillus spp. were performed using selective media, while antimicrobial residues were detected by a dye reduction test. No Salmonella, but C. albicans (17.5%; 21/120, Aspergillus spp. (0.8%; 1/120, and antimicrobial residues (2.5%; 3/120 were detected from raw milk. C. albicans was isolated from all three sites, while Aspergillus spp. and antimicrobial residues were detected from sites 1 and 3, respectively. From processed milk, only C. albicans (5% was isolated while Aspergillus spp. and antimicrobial residues were not detected. These results suggested low prevalence of Salmonella spp. and Aspergillus spp. and a relatively high prevalence of C. albicans in raw milk from the smallholder farms. The potential public health risks of C. albicans and the detected antimicrobial residues need to be considered. Thus, educating farmers on improving milking hygiene and storage of milk and establishing programmes for monitoring antimicrobial residues may help to improve the safety of milk from smallholder farms.

  16. Facilitating Teamwork in the Design Process

    DEFF Research Database (Denmark)

    Bang, Anne Louise; Nissen, Kirsten

    2009-01-01

    By approaching the Repertory Grid as an exploratory design game and drawing on insight in diagrammatic reasoning we argue that this approach is useful in supporting team work in the design process. In this paper we draw on two courses inviting textile design students to contribute to the developm......By approaching the Repertory Grid as an exploratory design game and drawing on insight in diagrammatic reasoning we argue that this approach is useful in supporting team work in the design process. In this paper we draw on two courses inviting textile design students to contribute...

  17. Assessment of residual life of fast breeder test reactor

    International Nuclear Information System (INIS)

    Srinivasan, G.

    2016-01-01

    The Fast Breeder Test Reactor (FBTR) is a loop type sodium cooled fast reactor and has been in operation since 1985. As a part of regulatory requirement for relicensing, residual life assessment had to be carried out. The systems are made of SS 316, and designed for creep and fatigue. The design life for creep is 100,000 h at 550°C. The design fatigue cycle for operation from shutdown to full power varies from component to component. In general, most of the components are designed for 2000 cycles. The reactor has operated mostly below the design temperatures. It is seen that enough creep-fatigue life is available for the non-replaceable, permanent components. The residual life was found to be governed by the residual ductility of the Grid Plate supporting the core after neutron irradiation. Fast flux measurements were carried out at the grid plate location. Samples were irradiated and tensile tested. Results indicate the allowable dpa for a 10% residual ductility criterion as 4.37. This gave a residual life of ~ 6 Effective Full Power Years for the reactor as of Feb 2012. Measures to reduce the neutron dose on the grid plate are being taken. (author)

  18. Integrating ergonomic knowledge into engineering design processes

    DEFF Research Database (Denmark)

    Hall-Andersen, Lene Bjerg

    Integrating ergonomic knowledge into engineering design processes has been shown to contribute to healthy and effective designs of workplaces. However, it is also well-recognized that, in practice, ergonomists often have difficulties gaining access to and impacting engineering design processes...... employed in the same company, constituted a supporting factor for the possibilities to integrate ergonomic knowledge into the engineering design processes. However, the integration activities remained discrete and only happened in some of the design projects. A major barrier was related to the business...... to the ergonomic ambitions of the clients. The ergonomists’ ability to navigate, act strategically, and compromise on ergonomic inputs is also important in relation to having an impact in the engineering design processes. Familiarity with the engineering design terminology and the setup of design projects seems...

  19. Real time loss detection for SNM in process

    International Nuclear Information System (INIS)

    Candy, J.V.; Dunn, D.R.; Gavel, D.T.

    1980-01-01

    This paper discusses the basis of a design for real time special nuclear material (SNM) loss detectors. The design utilizes process measurements and signal processing techniques to produce a timely estimate of material loss. A state estimator is employed as the primary signal processing algorithm. Material loss is indicated by changes in the states or process innovations (residuals). The design philosophy is discussed in the context of these changes

  20. An Integrated Design Process

    DEFF Research Database (Denmark)

    Petersen, Mads Dines; Knudstrup, Mary-Ann

    2010-01-01

    Present paper is placed in the discussion about how sustainable measures are integrated in the design process by architectural offices. It presents results from interviews with four leading Danish architectural offices working with sustainable architecture and their experiences with it, as well...... as the requirements they meet in terms of how to approach the design process – especially focused on the early stages like a competition. The interviews focus on their experiences with working in multidisciplinary teams and using digital tools to support their work with sustainable issues. The interviews show...... the environmental measures cannot be discarded due to extra costs....

  1. Conceptual Design of Industrial Process Displays

    DEFF Research Database (Denmark)

    Pedersen, C.R.; Lind, Morten

    1999-01-01

    discusses aspects of process display design taking into account both the designer's and the operator's points of view. Three aspects are emphasized: the operator tasks, the display content and the display form. The distinction between these three aspects is the basis for proposing an outline for a display......Today, process displays used in industry are often designed on the basis of piping and instrumentation diagrams without any method of ensuring that the needs of the operators are fulfilled. Therefore, a method for a systematic approach to the design of process displays is needed. This paper...... by a simple example from a plant with batch processes. Later the method is applied to develop a supervisory display for a condenser system in a nuclear power plant. The differences between the continuous plant domain of power production and the batch processes from the example are analysed and broad...

  2. Integrating Thermal Tools Into the Mechanical Design Process

    Science.gov (United States)

    Tsuyuki, Glenn T.; Siebes, Georg; Novak, Keith S.; Kinsella, Gary M.

    1999-01-01

    The intent of mechanical design is to deliver a hardware product that meets or exceeds customer expectations, while reducing cycle time and cost. To this end, an integrated mechanical design process enables the idea of parallel development (concurrent engineering). This represents a shift from the traditional mechanical design process. With such a concurrent process, there are significant issues that have to be identified and addressed before re-engineering the mechanical design process to facilitate concurrent engineering. These issues also assist in the integration and re-engineering of the thermal design sub-process since it resides within the entire mechanical design process. With these issues in mind, a thermal design sub-process can be re-defined in a manner that has a higher probability of acceptance, thus enabling an integrated mechanical design process. However, the actual implementation is not always problem-free. Experience in applying the thermal design sub-process to actual situations provides the evidence for improvement, but more importantly, for judging the viability and feasibility of the sub-process.

  3. Biodrying of animal slaughterhouse residues and heat production

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, Y. [Centre de recherche industrielle, Quebec City, PQ (Canada)

    2010-07-01

    Animal carcasses from slaughterhouses are usually composted on farms, but the composting process is not optimized and a large volumes of carbonaceous residues are needed. This type of composting takes place over a period of 6 to 9 months in a nonaerated static pile. Quebec's industrial research centre (CRIQ) developed an organic biodrying process (BIOSECO) adapted to large-scale operations in order to optimize the treatment of slaughterhouse residues. Biodrying is a form of composting, in which the thermophilic phase is optimized, making it possible to evaporate large amounts of water. Biodrying is done inside a building and reduces the amount of carbonaceous residues considerably. The process is optimized by the sequence in which the slaughterhouse residues are added, the choice of input and the aeration flow. Slaughterhouse residues can be treated non-stop throughout the entire year. Since the odours are nearly completed limited to the building, the biodrying can be done near the slaughterhouse. A large amount of heat was produced by the process during the pilot project. It was concluded that the BIOSECO biodrying process is suitable for treating slaughterhouse residues in an effective and economic manner, and has the added advantage of producing heat that could be used for various purposes.

  4. A computer-aided approach for achieving sustainable process design by process intensification

    DEFF Research Database (Denmark)

    Anantasarn, Nateetorn; Suriyapraphadilok, Uthaiporn; Babi, Deenesh Kavi

    2017-01-01

    to generate flowsheet alternatives that satisfy the design targets thereby, minimizing and/or eliminating the process hot-spots. The application of the framework is highlighted through the production of para-xylene via toluene methylation where more sustainable flowsheet alternatives that consist of hybrid......Process intensification can be applied to achieve sustainable process design. In this paper, a systematic, 3-stage synthesis-intensification framework is applied to achieve more sustainable design. In stage 1, the synthesis stage, an objective function and design constraints are defined and a base...... case is synthesized. In stage 2, the design and analysis stage, the base case is analyzed using economic and environmental analyses to identify process hot-spots that are translated into design targets. In stage 3, the innovation design stage, phenomena-based process intensification is performed...

  5. Homology modeling and docking analyses of M. leprae Mur ligases reveals the common binding residues for structure based drug designing to eradicate leprosy.

    Science.gov (United States)

    Shanmugam, Anusuya; Natarajan, Jeyakumar

    2012-06-01

    Multi drug resistance capacity for Mycobacterium leprae (MDR-Mle) demands the profound need for developing new anti-leprosy drugs. Since most of the drugs target a single enzyme, mutation in the active site renders the antibiotic ineffective. However, structural and mechanistic information on essential bacterial enzymes in a pathway could lead to the development of antibiotics that targets multiple enzymes. Peptidoglycan is an important component of the cell wall of M. leprae. The biosynthesis of bacterial peptidoglycan represents important targets for the development of new antibacterial drugs. Biosynthesis of peptidoglycan is a multi-step process that involves four key Mur ligase enzymes: MurC (EC:6.3.2.8), MurD (EC:6.3.2.9), MurE (EC:6.3.2.13) and MurF (EC:6.3.2.10). Hence in our work, we modeled the three-dimensional structure of the above Mur ligases using homology modeling method and analyzed its common binding features. The residues playing an important role in the catalytic activity of each of the Mur enzymes were predicted by docking these Mur ligases with their substrates and ATP. The conserved sequence motifs significant for ATP binding were predicted as the probable residues for structure based drug designing. Overall, the study was successful in listing significant and common binding residues of Mur enzymes in peptidoglycan pathway for multi targeted therapy.

  6. 40 CFR 279.59 - Management of residues.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Management of residues. 279.59 Section 279.59 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... Management of residues. Owners and operators who generate residues from the storage, processing, or re...

  7. Effects of advanced laser processing on the microstructure and residual stresses of H13 tool steel

    NARCIS (Netherlands)

    Trojan, Karel; Ocelík, Václav; Ganev, Nikolaj; Němeček, Stanislav; Čapek, Jiří

    2017-01-01

    The aim of this paper is to describe the effects of laser processing on the microstructure and residual stresses of laser cladded H13 tool steel on the classical construct steel S355 substrate. This research paper concludes that in this case of laser cladding, phase transformation and not shrinkage

  8. Life cycle design and design management strategies in fashion apparel manufacturing

    Science.gov (United States)

    Tutia, R.; Mendes, FD; Ventura, A.

    2017-10-01

    The generation of solid textile waste in the process of development and clothing production is an error that causes serious damages to the environment and must be minimized. The greatest volume of textile residues is generated by the department of cut, such as textiles parings and snips that are not used in the productive process. (MILAN et al, 2007). One way to conceive new products environmently conscious is turned to the adoption of a methodology based on Life Cycle Design (LCD) and Design Management.

  9. Release process for non-real property containing residual radioactive material

    International Nuclear Information System (INIS)

    Ranek, N.L.; Chen, S.Y.; Kamboj, S.; Hensley, J.; Burns, D.; Fleming, R.; Warren, S.; Wallo, A.

    1997-01-01

    It is DOE's objective to operate its facilities and to conduct its activities so that radiation exposures to members of the public are maintained within acceptable limits and exposures to residual radioactive materials are controlled. To accomplish this, DOE has adopted Order DOE 5400.51 'Radiation Protection of the Public and the Environment', and will be promulgating IO CR Part 834 to codify and clarify the requirements of DOE 5400.5. Under both DOE 5400.5 and 10 CR Part 834, radioactively contaminated DOE property is prohibited from release unless specific actions have been completed prior to the release. This paper outlines a ten-step process that, if followed, will assist DOE Operations and contractor personnel in ensuring that the required actions established by Order DOE 5400.5 and 10 CR Part 834 have been appropriately completed prior to the release for reuse or recycle of non-real property (e.g., office furniture, computers, hand tools, machinery, vehicles and scrap metal). Following the process will assist in ensuring that radiological doses to the public from the released materials will meet applicable regulatory standards and be as low as reasonably achievable (ALARA)

  10. Reliability assessment of underground pipelines under the combined effect of active corrosion and residual stress

    International Nuclear Information System (INIS)

    Amirat, A.; Mohamed-Chateauneuf, A.; Chaoui, K.

    2006-01-01

    Lifetime management of underground pipelines is mandatory for safe hydrocarbon transmission and distribution systems. Reliability analysis is recognized as a powerful decision-making tool for risk-based design and maintenance. Both the residual stresses generated during the manufacturing process and in-service corrosion reduce the ability to resist internal and external loading. In this study, the residual stress distribution in large diameter pipes has been characterized experimentally in order to be coupled with the corrosion model. During the pipe lifetime, residual stress relaxation occurs due to the loss of pipe thickness as material layers are consumed by corrosion. The reliability-based assessment of residual stress effects is applied to underground pipelines under a roadway, with and without active corrosion. It has been found that the residual stress greatly increases the failure probability, especially in the early stage of the pipe lifetime

  11. Decomposition of residual oil by large scale HSC plant

    Energy Technology Data Exchange (ETDEWEB)

    Washimi, Koichi; Ogata, Yoshitaka; Limmer, H.; Schuetter, H. (Toyo Engineering Corp., funabashi, Japan VEB Petrolchemisches Kombinat Schwedt, Schwedt (East Germany))

    1989-07-01

    Regarding large scale and high decomposition ratio visbreaker HSC, characteristic points and operation conditions of a new plant in East Germany were introduced. As for the characteristics of the process, high decomposition ratio and stable decpmposed oil, availability of high sulfur content oil or even decomposed residuum of visbreaker, stableness of produced light oil with low content of unsaturated components, low investment with low running cost, were indicated. For the realization of high decomposition ratio, designing for suppressing the decomposition in heating furnace and accelaration of it in soaking drum, high space velocity of gas phase for better agitation, were raised. As the main subject of technical development, design of soaking drum was indicated with main dimensions for the designing. Operation conditions of the process in East Germany using residual oil supplied from already working visbreaker for USSR crude oil were introduced. 6 refs., 4 figs., 2 tabs.

  12. Human Integration Design Processes (HIDP)

    Science.gov (United States)

    Boyer, Jennifer

    2014-01-01

    The purpose of the Human Integration Design Processes (HIDP) document is to provide human-systems integration design processes, including methodologies and best practices that NASA has used to meet human systems and human rating requirements for developing crewed spacecraft. HIDP content is framed around human-centered design methodologies and processes in support of human-system integration requirements and human rating. NASA-STD-3001, Space Flight Human-System Standard, is a two-volume set of National Aeronautics and Space Administration (NASA) Agency-level standards established by the Office of the Chief Health and Medical Officer, directed at minimizing health and performance risks for flight crews in human space flight programs. Volume 1 of NASA-STD-3001, Crew Health, sets standards for fitness for duty, space flight permissible exposure limits, permissible outcome limits, levels of medical care, medical diagnosis, intervention, treatment and care, and countermeasures. Volume 2 of NASASTD- 3001, Human Factors, Habitability, and Environmental Health, focuses on human physical and cognitive capabilities and limitations and defines standards for spacecraft (including orbiters, habitats, and suits), internal environments, facilities, payloads, and related equipment, hardware, and software with which the crew interfaces during space operations. The NASA Procedural Requirements (NPR) 8705.2B, Human-Rating Requirements for Space Systems, specifies the Agency's human-rating processes, procedures, and requirements. The HIDP was written to share NASA's knowledge of processes directed toward achieving human certification of a spacecraft through implementation of human-systems integration requirements. Although the HIDP speaks directly to implementation of NASA-STD-3001 and NPR 8705.2B requirements, the human-centered design, evaluation, and design processes described in this document can be applied to any set of human-systems requirements and are independent of reference

  13. New Vistas in Chemical Product and Process Design

    DEFF Research Database (Denmark)

    Zhang, Lei; Babi, Deenesh Kavi; Gani, Rafiqul

    2016-01-01

    Design of chemicals-based products is broadly classified into those that are process centered and those that are product centered. In this article, the designs of both classes of products are reviewed from a process systems point of view; developments related to the design of the chemical product......, its corresponding process, and its integration are highlighted. Although significant advances have been made in the development of systematic model-based techniques for process design (also for optimization, operation, and control), much work is needed to reach the same level for product design....... Timeline diagrams illustrating key contributions in product design, process design, and integrated product-process design are presented. The search for novel, innovative, and sustainable solutions must be matched by consideration of issues related to the multidisciplinary nature of problems, the lack...

  14. Solar hydrogen project - Thermochemical process design

    Energy Technology Data Exchange (ETDEWEB)

    Allen, D.J.; Ng, L.F.; Rao, M.S.M.; Wu, S.F.; Zoschak, R.J.

    1984-08-01

    The thermochemical decomposition of water using solar energy offers an elegant way of combining solar and chemical technologies to produce a high quality fuel. The DOE has sponsored Foster Wheeler to develop a process design for a solar water-splitting process based on the sulfuric acid/iodine cycle. The study has centered around the design of a sulfuric acid decomposition reactor and the central receiver. Materials' properties impose severe constraints upon the design of decomposition reactor. In this paper, the constraints imposed on the design are specified and a reactor and receiver design is presented together with a preliminary design of the balance of plant.

  15. Effect of Tip Shape of Frictional Stir Burnishing Tool on Processed Layer’s Hardness, Residual Stress and Surface Roughness

    Directory of Open Access Journals (Sweden)

    Yoshimasa Takada

    2018-01-01

    Full Text Available Friction stir burnishing (FSB is a surface-enhancement method used after machining, without the need for an additional device. The FSB process is applied on a machine that uses rotation tools (e.g., machining center or multi-tasking machine. Therefore, the FSB process can be applied immediately after the cutting process using the same machine tool. Here, we apply the FSB to the shaft materials of 0.45% C steel using a multi-tasking machine. In the FSB process, the burnishing tool rotates at a high-revolution speed. The thin surface layer is rubbed and stirred as the temperature is increased and decreased. With the FSB process, high hardness or compressive residual stress can be obtained on the surface layer. However, when we applied the FSB process using a 3 mm diameter sphere tip shape tool, the surface roughness increased substantially (Ra = 20 µm. We therefore used four types of tip shape tools to examine the effect of burnishing tool tip radius on surface roughness, hardness, residual stress in the FSB process. Results indicated that the surface roughness was lowest (Ra = 10 µm when the tip radius tool diameter was large (30 mm.

  16. Influence of turkey meat on residual nitrite in cured meat products.

    Science.gov (United States)

    Kilic, B; Cassens, R G; Borchert, L L

    2001-02-01

    A response surface experimental design was employed to estimate residual nitrite level at various initial nitrite concentrations, percent turkey meat in the formula, and heat quantity (F) values using a typical wiener as the test system. Pork and mechanically separated turkey were used as the meat ingredients. Residual nitrite and pH were measured at day 1, 7 days, 14 days, and 49 days after processing. Protein, fat, salt, moisture, and CIE (L*a*b*) color values were also determined. Results showed that the effect of turkey meat on residual nitrite level was significant (P meat in the formula resulted in lower residual nitrite levels at a fixed pH. The residual nitrite level was initially proportional to initial nitrite concentration, but it became a nonsignificant factor during longer storage time. Differences in heat quantity had a significant effect (P nitrite level initially. Greater heat quantity decreased residual nitrite level in finished cured meat products at a fixed pH. However, this effect became nonsignificant during longer storage. Reduction of residual nitrite in wieners because of turkey meat addition at a fixed pH was due to characteristics of the turkey tissue, but the mechanism of action remains unknown. It was also established that commercial wieners had a higher pH if poultry meat was included in the formulation.

  17. A Preliminary Study for Safety Shutter design to Protect Streaming of Residual Radiation Passing through Beamline in Pre-Separator Room of ISOL

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jong Woo; Kim, Do Hyun; Kim, Song Hyun; Shin, Chang Ho; Nam, Shin Woo [KAERI, Daejeon (Korea, Republic of)

    2016-05-15

    RAON is a heavy ion accelerator under construction by the Institute for Basic Science (IBS) in Korea. As one part of the RAON accelerator, ISOL is a facility to generate and separate rare isotopes for various experiments. In ISOL facility, isotopes generated from the reaction between 70 MeV proton beam and UC{sub 2} target are transferred to pre-separator room. Almost all isotopes accumulated in slit of pre-separator except specific isobars, which are set for experiments. Residual radiations are generated from accumulated isotopes because these isotopes are unstable. Streaming of residual radiation by the beamline is weak point for radiation shielding design. In this study, safety shutter was designed. Residual radiation generated from accumulated isotopes at slit of pre-separator was estimated using following conditions: (1) the isotopes generated by proton-target reactions are accumulated at slit with 10 % accumulation rate; (2) it was assumed that the radioactive isotopes are uniformly distributed in the cylindrical slit which have 1 cm height and 15 diameter. To design optimized safety shutter, following steps were performed: (1) thickness and diameter of the bulk shield material were evaluated to optimize safety shutter material; (2) additional shielding structure was proposed using dose contribution of each additional shielding wall.

  18. The design process seen through the eyes of a type designer

    DEFF Research Database (Denmark)

    Beier, Sofie

    2015-01-01

    To understand how the design process works, the paper takes the outset in the work of one of the first innovating type designers: the English printer and typefounder John Baskerville (1706-1775). By comparing his way of working with a model for a contemporary design process, the paper reflects upon...

  19. A Review on the Mechanical Modeling of Composite Manufacturing Processes

    DEFF Research Database (Denmark)

    Baran, Ismet; Cinar, Kenan; Ersoy, Nuri

    2016-01-01

    The increased usage of fiber reinforced polymer composites in load bearing applications requires a detailed understanding of the process induced residual stresses and their effect on the shape distortions. This is utmost necessary in order to have more reliable composite manufacturing since...... the residual stresses alter the internal stress level of the composite part during the service life and the residual shape distortions may lead to not meeting the desired geometrical tolerances. The occurrence of residual stresses during the manufacturing process inherently contains diverse interactions...... between the involved physical phenomena mainly related to material flow, heat transfer and polymerization or crystallization. Development of numerical process models is required for virtual design and optimization of the composite manufacturing process which avoids the expensive trial-and-error based...

  20. Structural and chemical analysis of process residue from biochemical conversion of wheat straw (Triticum aestivum L.) to ethanol

    DEFF Research Database (Denmark)

    Hansen, Mads Anders Tengstedt; Jørgensen, Henning; Laursen, Kristian Holst

    2013-01-01

    Biochemical conversion of lignocellulose to fermentable carbohydrates for ethanol production is now being implemented in large-scale industrial production. Applying hydrothermal pretreatment and enzymatic hydrolysis for the conversion process, a residue containing substantial amounts of lignin...

  1. Radiation processing studies on residual fractions of Olowi petroleum crude oil

    International Nuclear Information System (INIS)

    Sarfo, A.K.

    2011-01-01

    Residual fuel oil is an inexpensive boiler fuel that can replace diesel in some industrial boilers. The viscous waxy nature of residual fuel oil makes it very difficult to use in industries where fuel storage tanks have no heating elements to keep the fuel at temperatures at which it would easily flow. Irradiation is currently being studied as a cost effective means of cracking heavy petroleum crude oil into lighter and more valuable products. Research has shown that irradiation can replace the conventional methods of cracking petroleum with economical benefits. Gamma radiation from a cobalt-60 source was applied to the residue obtained after refining crude oil in this research study, with the intention of causing a similar cracking phenomenon. The main objective of the study was to evaluate the possibility of using gamma radiation to reduce the viscosity of residual fractions of crude oil used as residual fuel oil. This was done by exposing samples of residual fuel oil in glass jars to 9 different doses of gamma radiation, at room temperature and an elevated temperature of 60 degrees Celsius to determine and quantify the effect of radiation on residual fuel oil obtained from the Tema Oil Refinery. The pour points of the irradiated samples were not affected by radiation doses up to 200 kGy while the changes in viscosity for irradiation at room temperature were not significant. Irradiation at 60 degrees Celsius induced a small but significant increase in viscosity at 1 kGy and 200 kGy absorbed doses of irradiation. Irradiation fuels were stable in relation to viscosity, density and pour point over a period of 20 days after exposure. The flash point of irradiated samples, however, decreased by 5.26, 10.53 and 11.34% for 30, 50 and 80 kGy absorbed doses of radiation respectively. Cumulative and continuous doses gave similar results for pour point, density, viscosity and flash point measurements up to 50 kGy. Comparative cost analysis of methods used in maintaining low

  2. Assessment and Development of Engineering Design Processes

    DEFF Research Database (Denmark)

    Ulrikkeholm, Jeppe Bjerrum

    , the engineering companies need to have efficient engineering design processes in place, so they can design customised product variants faster and more efficiently. It is however not an easy task to model and develop such processes. To conduct engineering design is often a highly iterative, illdefined and complex...... the process can be fully understood and eventually improved. Taking its starting point in this proposition, the outcome of the research is an operational 5-phased procedure for assessing and developing engineering design processes through integrated modelling of product and process, designated IPPM......, and eventually the results are discussed, overall conclusions are made and future research is proposed. The results produced throughout the research project are developed in close collaboration with the Marine Low Speed business unit within the company MAN Diesel & Turbo. The business unit is the world market...

  3. Designing with video focusing the user-centred design process

    CERN Document Server

    Ylirisku, Salu Pekka

    2007-01-01

    Digital video for user-centered co-design is an emerging field of design, gaining increasing interest in both industry and academia. It merges the techniques and approaches of design ethnography, participatory design, interaction analysis, scenario-based design, and usability studies. This book covers the complete user-centered design project. It illustrates in detail how digital video can be utilized throughout the design process, from early user studies to making sense of video content and envisioning the future with video scenarios to provoking change with video artifacts. The text includes

  4. Reactivity of Athabasca residue and of its SARA fractions during residue hydroconversion

    Energy Technology Data Exchange (ETDEWEB)

    Verstraete, J.; Danial-Fortain, P.; Gauthier, T.; Merdrignac, I. [IFP-Lyon, Vermaison (France); Budzinski, H. [Bordeaux Univ. (France). ISM-LPTC, UMR CNRS

    2009-07-01

    Residue conversion processes are becoming increasingly important because of the declining market for residual fuel oil and a greater demand for middle distillates. Ebullated-bed hydroconversion is a commercially proven technology for converting heavy feedstocks with high amounts of impurities. The process enables the conversion of atmospheric or vacuum residues at temperatures up to 440 degrees C, and at liquid hourly space velocity (LHSV) conditions in the range of 0.15 to 0.5 per hour. A 540 degrees C conversion of up to 80 weight per cent can be achieved under these conditions. This paper reported on a research study conducted at IFP Lyon in which the residue hydroconversion in a large-scale ebullated bed bench unit was investigated to determine the impact of operating conditions and feed properties on yield and product qualities. Hydrogen was added to the feed in the bench units to keep a high hydrogen partial pressure and favour the catalytic hydroconversion reactions. In a typical test, the reactor was fed with 50 g of feedstock and 0.45 g of crushed equilibrium industrial NiMo catalyst, pressurized hydrogen and quickly heated at the reaction temperature. This paper also discussed the conversion of Athabasca bitumen residue in the large-scale pilot plant and also in the small scale batch reactor. The effect of operating temperature and space velocity was examined. The reactivity of the saturates, aromatics, resins and asphaltenes (SARA) fractions of the bitumen was studied separately in order to better understand the conversion mechanisms and reactivities. The Athabasca bitumen feed and SARA fractions were also analyzed in terms of standard petroleum analysis, SARA fractionation, elemental analysis, size exclusion chromatography (SEC) and 13C NMR. Hydroconversion experiments were conducted in the batch unit at different reaction temperatures and reaction times. A comparison of small-scale batch results with those obtained with the continuous large-scale bench

  5. What do information reuse and automated processing require in engineering design? Semantic process

    Directory of Open Access Journals (Sweden)

    Ossi Nykänen

    2011-12-01

    Full Text Available Purpose: The purpose of this study is to characterize, analyze, and demonstrate machine-understandable semantic process for validating, integrating, and processing technical design information. This establishes both a vision and tools for information reuse and semi-automatic processing in engineering design projects, including virtual machine laboratory applications with generated components.Design/methodology/approach: The process model has been developed iteratively in terms of action research, constrained by the existing technical design practices and assumptions (design documents, expert feedback, available technologies (pre-studies and experiments with scripting and pipeline tools, benchmarking with other process models and methods (notably the RUP and DITA, and formal requirements (computability and the critical information paths for the generated applications. In practice, the work includes both quantitative and qualitative components.Findings: Technical design processes may be greatly enhanced in terms of semantic process thinking, by enriching design information, and automating information validation and transformation tasks. Contemporary design information, however, is mainly intended for human consumption, and needs to be explicitly enriched with the currently missing data and interfaces. In practice, this may require acknowledging the role of technical information or knowledge engineer, to lead the development of the semantic design information process in a design organization. There is also a trade-off between machine-readability and system complexity that needs to be studied further, both empirically and in theory.Research limitations/implications: The conceptualization of the semantic process is essentially an abstraction based on the idea of progressive design. While this effectively allows implementing semantic processes with, e.g., pipeline technologies, the abstraction is valid only when technical design is organized into

  6. Effect of the spray volume adjustment model on the efficiency of fungicides and residues in processing tomato

    Energy Technology Data Exchange (ETDEWEB)

    Ratajkiewicz, H.; Kierzek, R.; Raczkowski, M.; Hołodyńska-Kulas, A.; Łacka, A.; Wójtowicz, A.; Wachowiak, M.

    2016-11-01

    This study compared the effects of a proportionate spray volume (PSV) adjustment model and a fixed model (300 L/ha) on the infestation of processing tomato with potato late blight (Phytophthora infestans (Mont.) de Bary) (PLB) and azoxystrobin and chlorothalonil residues in fruits in three consecutive seasons. The fungicides were applied in alternating system with or without two spreader adjuvants. The proportionate spray volume adjustment model was based on the number of leaves on plants and spray volume index. The modified Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) method was optimized and validated for extraction of azoxystrobin and chlorothalonil residue. Gas chromatography with a nitrogen and phosphorus detector and an electron capture detector were used for the analysis of fungicides. The results showed that higher fungicidal residues were connected with lower infestation of tomato with PLB. PSV adjustment model resulted in lower infestation of tomato than the fixed model (300 L/ha) when fungicides were applied at half the dose without adjuvants. Higher expected spray interception into the tomato canopy with the PSV system was recognized as the reasons of better control of PLB. The spreader adjuvants did not have positive effect on the biological efficacy of spray volume application systems. The results suggest that PSV adjustment model can be used to determine the spray volume for fungicide application for processing tomato crop. (Author)

  7. Effect of the spray volume adjustment model on the efficiency of fungicides and residues in processing tomato

    Directory of Open Access Journals (Sweden)

    Henryk Ratajkiewicz

    2016-08-01

    Full Text Available This study compared the effects of a proportionate spray volume (PSV adjustment model and a fixed model (300 L/ha on the infestation of processing tomato with potato late blight (Phytophthora infestans (Mont. de Bary (PLB and azoxystrobin and chlorothalonil residues in fruits in three consecutive seasons. The fungicides were applied in alternating system with or without two spreader adjuvants. The proportionate spray volume adjustment model was based on the number of leaves on plants and spray volume index. The modified Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS method was optimized and validated for extraction of azoxystrobin and chlorothalonil residue. Gas chromatography with a nitrogen and phosphorus detector and an electron capture detector were used for the analysis of fungicides. The results showed that higher fungicidal residues were connected with lower infestation of tomato with PLB. PSV adjustment model resulted in lower infestation of tomato than the fixed model (300 L/ha when fungicides were applied at half the dose without adjuvants. Higher expected spray interception into the tomato canopy with the PSV system was recognized as the reasons of better control of PLB. The spreader adjuvants did not have positive effect on the biological efficacy of spray volume application systems. The results suggest that PSV adjustment model can be used to determine the spray volume for fungicide application for processing tomato crop.

  8. New Vistas in Chemical Product and Process Design.

    Science.gov (United States)

    Zhang, Lei; Babi, Deenesh K; Gani, Rafiqul

    2016-06-07

    Design of chemicals-based products is broadly classified into those that are process centered and those that are product centered. In this article, the designs of both classes of products are reviewed from a process systems point of view; developments related to the design of the chemical product, its corresponding process, and its integration are highlighted. Although significant advances have been made in the development of systematic model-based techniques for process design (also for optimization, operation, and control), much work is needed to reach the same level for product design. Timeline diagrams illustrating key contributions in product design, process design, and integrated product-process design are presented. The search for novel, innovative, and sustainable solutions must be matched by consideration of issues related to the multidisciplinary nature of problems, the lack of data needed for model development, solution strategies that incorporate multiscale options, and reliability versus predictive power. The need for an integrated model-experiment-based design approach is discussed together with benefits of employing a systematic computer-aided framework with built-in design templates.

  9. Analytical and Experimental Study of Residual Stresses in CFRP

    Directory of Open Access Journals (Sweden)

    Chia-Chin Chiang

    2013-01-01

    Full Text Available Fiber Bragg Grating sensors (FBGs have been utilized in various engineering and photoelectric fields because of their good environment tolerance. In this research, residual stresses of carbon fiber reinforced polymer composites (CFRP were studied using both experimental and analytical approach. The FBGs were embedded inside middle layers of CFRP to study the formation of residual stress during curing process. Finite element analysis was performed using ABAQUS software to simulate the CFRP curing process. Both experimental and simulation results showed that the residual stress appeared during cooling process and the residual stresses could be released when the CFRP was machined to a different shape.

  10. Subnanomolar Inhibitor of Cytochrome bc1 Complex Designed via Optimizing Interaction with Conformationally Flexible Residues

    Science.gov (United States)

    Zhao, Pei-Liang; Wang, Le; Zhu, Xiao-Lei; Huang, Xiaoqin; Zhan, Chang-Guo; Wu, Jia-Wei; Yang, Guang-Fu

    2009-01-01

    Cytochrome bc1 complex (EC 1.10.2.2, bc1), an essential component of the cellular respiratory chain and the photosynthetic apparatus in photosynthetic bacteria, has been identified as a promising target for new drugs and agricultural fungicides. X-ray diffraction structures of the free bc1 complex and its complexes with various inhibitors revealed that the phenyl group of Phe274 in the binding pocket exhibited significant conformational flexibility upon different inhibitors binding to optimize respective π-π interactions, whereas the side chains of other hydrophobic residues showed conformational stability. Therefore, in the present study, a strategy of optimizing the π-π interaction with conformationally flexible residues was proposed to design and discover new bc1 inhibitors with a higher potency. Eight new compounds were designed and synthesized, among which compound 5c with a Ki value of 570 pM was identified as the most promising drug or fungicide candidate, significantly more potent than the commercially available bc1 inhibitors including azoxystrobin (AZ), kresoxim-methyl (KM), and pyraclostrobin (PY). To our knowledge, this is the first bc1 inhibitor discovered from structure-based design with a potency of subnanomolar Ki value. For all of the compounds synthesized and assayed, the calculated binding free energies correlated reasonably well with the binding free energies derived from the experimental Ki values with a correlation coefficient of r2 = 0.89. The further inhibitory kinetics studies revealed that compound 5c is a non-competitive inhibitor with respect to substrate cytochrome c, but is a competitive inhibitor with respect to substrate ubiquinol. Due to its subnanomolar Ki potency and slow dissociation rate constant (k−0 = 0.00358 s−1), compound 5c could be used as a specific probe for further elucidation of the mechanism of bc1 function and as a new lead compound for future drug discovery. PMID:19928849

  11. Enhanced extraction of phenolic compounds from coffee industry’s residues through solid state fermentation by Penicillium purpurogenum

    Directory of Open Access Journals (Sweden)

    Lady Rossana PALOMINO García

    2015-01-01

    Full Text Available Abstract The use of agroindustrial residues is an economical solution to industrial biotechnology. Coffee husk and pulp are abounding residues from coffee industry which can be used as substrates in solid state fermentation process, thus allowing a liberation and increase in the phenolic compound content with high added value. By employing statistical design, initial moisture content, pH value in the medium, and the incubation temperature were evaluated, in order to increase the polyphenol content in a process of solid state fermentation by Penicillium purpurogenum. The main phenolic compounds identified through HPLC in fermented coffee residue were chlorogenic acid, caffeic acid, and rutin. Data obtained through HPLC with the radical absorbance capacity assay suggest the fermented coffee husk and pulp extracts potential as a source of phenolic acids and flavonoids. Results showed good perspectives when using P. purpurogenum strain to enhance the liberation of phenolic compounds in coffee residues.

  12. SOLVING GLOBAL PROBLEMS USING COLLABORATIVE DESIGN PROCESSES

    DEFF Research Database (Denmark)

    Lenau, Torben Anker; Mejborn, Christina Okai

    2011-01-01

    In this paper we argue that use of collaborative design processes is a powerful means of bringing together different stakeholders and generating ideas in complex design situations. The collaborative design process was used in a workshop with international participants where the goal was to propos...

  13. Gasificación con aire en lecho fluidizado de los residuos sólidos del proceso industrial de la naranja//Air gasification in fluidized bed of solid residue the orange industrial process

    Directory of Open Access Journals (Sweden)

    Leonardo Aguiar-Trujillo

    2012-12-01

    Full Text Available La industria procesadora de la naranja genera elevados volúmenes de residuos sólidos. Este residuo se ha utilizado en la alimentación animal y en procesos bioquímicos; pero no se ha aprovechado a través de la gasificación. El objetivo del trabajo fue determinar el aporte energético por medio del proceso de gasificación, realizándose estudios de los residuos sólidos de naranja, utilizando aire en reactor de lecho fluidizado burbujeante (variando la temperatura de gasificación, relación estequiométrica y altura del lecho. En el proceso se utilizó un diseño de experimento factorial completo de 2k, valorando la influencia de las variables independientes y sus interacciones en las respuestas, con un grado de significación del 95 %. Se obtuvieron los parámetros para efectuar el proceso de gasificación de los residuos sólidos de naranja, obteniendo un gas de bajo poder calórico, próximo a 5046 kJ/m3N, demostrando sus cualidades para su aprovechamiento energético.Palabras claves: gasificación con aire, lecho fluidizado, residuo de naranja._______________________________________________________________________________AbstractThe orange industrial process generates high volumes of solid residue. This residue has been used as complement in the animal feeding and biochemical processes; but it has not taken advantage through of the gasification process. The objective of the work was to determine the energy contribution by means ofthe gasification process, were carried out studies of the orange solid residue, using air in reactor of bubbling fluidized bed (varying the gasification temperature, air ratio and bed height. In the process a design of complete factorial experiment of 2k, was used, valuing the influence of the independent variables and its interactions in the answers, using a confidence level of 95 %. Were obtained the parameters to make the process of gasification of the orange solid residue, obtaining a gas of lower heating

  14. Hidden realities inside PBL design processes

    DEFF Research Database (Denmark)

    Pihl, Ole Verner

    2015-01-01

    Design Process, but is a group-based architecture and design education better than that which is individually based? How does PBL affect space, form, and creative processes? Hans Kiib, professor and one of the founders of the Department of Architecture and Design in Aalborg, describes his intentions...... are passing from a complex world into one based on super complexity? Could Gaston Bachelard (1958), who writes in his book The Poetic of Space "that poets and artists are born phenomenologists," help architecture and design students in their journey to find his/her own professional expression? This paper...

  15. Detoxification and immobilization of chromite ore processing residue in spinel-based glass-ceramic

    Energy Technology Data Exchange (ETDEWEB)

    Liao, Chang-Zhong [Guangdong Key Laboratory of Agricultural Environment Pollution Integrated Control, Guangdong Institute of Eco-Environmental and Soil Sciences, Guangzhou 510650 (China); Department of Civil Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong Special Administrative Region (China); Tang, Yuanyuan [School of Environmental Science and Engineering, South University of Science and Technology of China, Shenzhen 518055 (China); Lee, Po-Heng [Department of Civil & Environmental Engineering, The Hong Kong Polytechnic University, Hong Kong Special Administrative Region (China); Liu, Chengshuai, E-mail: csliu@soil.gd.cn [Guangdong Key Laboratory of Agricultural Environment Pollution Integrated Control, Guangdong Institute of Eco-Environmental and Soil Sciences, Guangzhou 510650 (China); State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550009 (China); Shih, Kaimin, E-mail: kshih@hku.hk [Department of Civil Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong Special Administrative Region (China); Li, Fangbai [Guangdong Key Laboratory of Agricultural Environment Pollution Integrated Control, Guangdong Institute of Eco-Environmental and Soil Sciences, Guangzhou 510650 (China)

    2017-01-05

    Graphical abstract: Schematic illustration of detoxification and immobilization of chromite ore processing residue in spinel-based glass-ceramic matrix. All Cr(VI) species is reduced to Cr(III) and most chromium contents are incorporated into spinel structure where the residual chromium are resided in the glass networks. - Highlights: • COPR was detoxified and immobilized in a spinel-based glass-ceramic matrix. • Cr-rich crystalline phase was determined to be MgCr{sub 1.32}Fe{sub 0.19}Al{sub 0.49}O{sub 4} spinel. • The partitioning ratio of Cr into spinel in the glass-ceramic can be up to 77%. • No Cr(VI) was observed after conversion of COPR into a glass-ceramic. • TCLP results demonstrate the superiority of the final product in immobilizing Cr. - Abstract: A promising strategy for the detoxification and immobilization of chromite ore processing residue (COPR) in a spinel-based glass-ceramic matrix is reported in this study. In the search for a more chemically durable matrix for COPR, the most critical crystalline phase for Cr immobilization was found to be a spinel solid solution with a chemical composition of MgCr{sub 1.32}Fe{sub 0.19}Al{sub 0.49}O{sub 4}. Using Rietveld quantitative X-ray diffraction analysis, we identified this final product is with the phases of spinel (3.5 wt.%), diopside (5.2 wt.%), and some amorphous contents (91.2 wt.%). The partitioning ratio of Cr reveals that about 77% of the Cr was incorporated into the more chemically durable spinel phase. The results of Cr K-edge X-ray absorption near-edge spectroscopy show that no Cr(VI) was observed after conversion of COPR into a glass-ceramic, which indicates successful detoxification of Cr(VI) into Cr(III) in the COPR-incorporated glass-ceramic. The leaching performances of Cr{sub 2}O{sub 3} and COPR-incorporated glass-ceramic were compared with a prolonged acid-leaching test, and the results demonstrate the superiority of the COPR-incorporated glass-ceramic matrix in the

  16. Detoxification and immobilization of chromite ore processing residue in spinel-based glass-ceramic

    International Nuclear Information System (INIS)

    Liao, Chang-Zhong; Tang, Yuanyuan; Lee, Po-Heng; Liu, Chengshuai; Shih, Kaimin; Li, Fangbai

    2017-01-01

    Graphical abstract: Schematic illustration of detoxification and immobilization of chromite ore processing residue in spinel-based glass-ceramic matrix. All Cr(VI) species is reduced to Cr(III) and most chromium contents are incorporated into spinel structure where the residual chromium are resided in the glass networks. - Highlights: • COPR was detoxified and immobilized in a spinel-based glass-ceramic matrix. • Cr-rich crystalline phase was determined to be MgCr 1.32 Fe 0.19 Al 0.49 O 4 spinel. • The partitioning ratio of Cr into spinel in the glass-ceramic can be up to 77%. • No Cr(VI) was observed after conversion of COPR into a glass-ceramic. • TCLP results demonstrate the superiority of the final product in immobilizing Cr. - Abstract: A promising strategy for the detoxification and immobilization of chromite ore processing residue (COPR) in a spinel-based glass-ceramic matrix is reported in this study. In the search for a more chemically durable matrix for COPR, the most critical crystalline phase for Cr immobilization was found to be a spinel solid solution with a chemical composition of MgCr 1.32 Fe 0.19 Al 0.49 O 4 . Using Rietveld quantitative X-ray diffraction analysis, we identified this final product is with the phases of spinel (3.5 wt.%), diopside (5.2 wt.%), and some amorphous contents (91.2 wt.%). The partitioning ratio of Cr reveals that about 77% of the Cr was incorporated into the more chemically durable spinel phase. The results of Cr K-edge X-ray absorption near-edge spectroscopy show that no Cr(VI) was observed after conversion of COPR into a glass-ceramic, which indicates successful detoxification of Cr(VI) into Cr(III) in the COPR-incorporated glass-ceramic. The leaching performances of Cr 2 O 3 and COPR-incorporated glass-ceramic were compared with a prolonged acid-leaching test, and the results demonstrate the superiority of the COPR-incorporated glass-ceramic matrix in the immobilization of Cr. The overall results suggest that

  17. Extraction of Iron and Manganese from Pyrolusite Absorption Residue by Ammonium Sulphate Roasting–Leaching Process

    Directory of Open Access Journals (Sweden)

    Lin Deng

    2018-01-01

    Full Text Available The residue from desulfurization and denitrification of exhaust gas treatment process with pyrolusite ore as absorbent is regarded as a potential source of iron and manganese. In this study, an extraction process is proposed for recovery of iron and manganese with ammonium sulphate roasting followed by sulphuric acid leaching. Firstly, the conversion mechanism was analyzed through mineral phase analysis of roasting products at different roasting temperature by means of X-ray diffraction (XRD technology. Then, the parameters of the roasting procedure such as roasting temperature and time, ammonium sulphate dosage, leaching temperature, leaching time, and sulphuric acid concentration are examined. The results implicate that the iron oxide and manganese dioxide in the residue are firstly converted into the water-soluble ( NH 4 3 Fe ( SO 4 3 and ( NH 4 2 Mn 2 ( SO 4 3 at 200–350 °C, and then the more stable NH 4 Fe ( SO 4 2 and MnSO 4 are formed, at temperature higher than 350 °C. Under optimum conditions, 95.2% Fe and 97.0% Mn can be extracted. Reactant diffusion through inert layer of silicon dioxide was considered as the rate-limiting step for iron extraction with an activation energy of 20.56 kJ/mol, while, the recovery process of Mn was controlled by both reactant diffusion and chemical reaction with an activation energy of 29.52 kJ/mol.

  18. Graphic Design in Libraries: A Conceptual Process

    Science.gov (United States)

    Ruiz, Miguel

    2014-01-01

    Providing successful library services requires efficient and effective communication with users; therefore, it is important that content creators who develop visual materials understand key components of design and, specifically, develop a holistic graphic design process. Graphic design, as a form of visual communication, is the process of…

  19. Visualization of residual organic liquid trapped in aquifers

    International Nuclear Information System (INIS)

    Conrad, S.H.; Wilson, J.L.; Mason, W.R.; Peplinski, W.J.

    1992-01-01

    Organic liquids that are essentially immiscible with water migrate through the subsurface under the influence of capillary, viscous, and buoyancy forces. These liquids originate from the improper disposal of hazardous wastes, and the spills and leaks of petroleum hydrocarbons and solvents. The flow visualization experiments described in this study examined the migration of organic liquids through the saturated zone of aquifers, with a primary focus on the behavior of the residual organic liquid saturation, referring to that portion of the organic liquid that is trapped by capillary forces. Etched glass micromodels were used to visually observe dynamic multiphase displacement processes in pore networks. The resulting fluid distributions were photographed. Pore and blob casts were produced by a technique in which an organic liquid was solidified in place within a sand column at the conclusion of a displacement. The columns were sectioned and examined under optical and scanning electron microscopes. Photomicrographs of these sections show the morphology of the organic phase and its location within the sand matrix. The photographs from both experimental techniques reveal that in the saturated zone large amounts of residual organic liquid are trapped as isolated blobs of microscopic size. The size, shape, and spatial distribution of these blobs of residual organic liquid affect the dissolution of organic liquid into the water phase and the biotransformation of organic components. These processes are of concern for the prediction of pollution migration and the design of aquifer remediation schemes

  20. EPR design tools. Integrated data processing tools

    International Nuclear Information System (INIS)

    Kern, R.

    1997-01-01

    In all technical areas, planning and design have been supported by electronic data processing for many years. New data processing tools had to be developed for the European Pressurized Water Reactor (EPR). The work to be performed was split between KWU and Framatome and laid down in the Basic Design contract. The entire plant was reduced to a logical data structure; the circuit diagrams and flowsheets of the systems were drafted, the central data pool was established, the outlines of building structures were defined, the layout of plant components was planned, and the electrical systems were documented. Also building construction engineering was supported by data processing. The tasks laid down in the Basic Design were completed as so-called milestones. Additional data processing tools also based on the central data pool are required for the phases following after the Basic Design phase, i.e Basic Design Optimization; Detailed Design; Management; Construction, and Commissioning. (orig.) [de

  1. Quantification of Drive-Response Relationships Between Residues During Protein Folding.

    Science.gov (United States)

    Qi, Yifei; Im, Wonpil

    2013-08-13

    Mutual correlation and cooperativity are commonly used to describe residue-residue interactions in protein folding/function. However, these metrics do not provide any information on the causality relationships between residues. Such drive-response relationships are poorly studied in protein folding/function and difficult to measure experimentally due to technical limitations. In this study, using the information theory transfer entropy (TE) that provides a direct measurement of causality between two times series, we have quantified the drive-response relationships between residues in the folding/unfolding processes of four small proteins generated by molecular dynamics simulations. Instead of using a time-averaged single TE value, the time-dependent TE is measured with the Q-scores based on residue-residue contacts and with the statistical significance analysis along the folding/unfolding processes. The TE analysis is able to identify the driving and responding residues that are different from the highly correlated residues revealed by the mutual information analysis. In general, the driving residues have more regular secondary structures, are more buried, and show greater effects on the protein stability as well as folding and unfolding rates. In addition, the dominant driving and responding residues from the TE analysis on the whole trajectory agree with those on a single folding event, demonstrating that the drive-response relationships are preserved in the non-equilibrium process. Our study provides detailed insights into the protein folding process and has potential applications in protein engineering and interpretation of time-dependent residue-based experimental observables for protein function.

  2. Conceptual design of distillation-based hybrid separation processes.

    Science.gov (United States)

    Skiborowski, Mirko; Harwardt, Andreas; Marquardt, Wolfgang

    2013-01-01

    Hybrid separation processes combine different separation principles and constitute a promising design option for the separation of complex mixtures. Particularly, the integration of distillation with other unit operations can significantly improve the separation of close-boiling or azeotropic mixtures. Although the design of single-unit operations is well understood and supported by computational methods, the optimal design of flowsheets of hybrid separation processes is still a challenging task. The large number of operational and design degrees of freedom requires a systematic and optimization-based design approach. To this end, a structured approach, the so-called process synthesis framework, is proposed. This article reviews available computational methods for the conceptual design of distillation-based hybrid processes for the separation of liquid mixtures. Open problems are identified that must be addressed to finally establish a structured process synthesis framework for such processes.

  3. Handling of Solid Residues

    International Nuclear Information System (INIS)

    Medina Bermudez, Clara Ines

    1999-01-01

    The topic of solid residues is specifically of great interest and concern for the authorities, institutions and community that identify in them a true threat against the human health and the atmosphere in the related with the aesthetic deterioration of the urban centers and of the natural landscape; in the proliferation of vectorial transmitters of illnesses and the effect on the biodiversity. Inside the wide spectrum of topics that they keep relationship with the environmental protection, the inadequate handling of solid residues and residues dangerous squatter an important line in the definition of political and practical environmentally sustainable. The industrial development and the population's growth have originated a continuous increase in the production of solid residues; of equal it forms, their composition day after day is more heterogeneous. The base for the good handling includes the appropriate intervention of the different stages of an integral administration of residues, which include the separation in the source, the gathering, the handling, the use, treatment, final disposition and the institutional organization of the administration. The topic of the dangerous residues generates more expectation. These residues understand from those of pathogen type that are generated in the establishments of health that of hospital attention, until those of combustible, inflammable type, explosive, radio-active, volatile, corrosive, reagent or toxic, associated to numerous industrial processes, common in our countries in development

  4. The Role(s) of Process Models in Design Practice

    DEFF Research Database (Denmark)

    Iversen, Søren; Jensen, Mads Kunø Nyegaard; Vistisen, Peter

    2018-01-01

    This paper investigates how design process models are implemented and used in design-driven organisations. The archetypical theoretical framing of process models, describe their primary role as guiding the design process, and assign roles and deliverables throughout the process. We hypothesise...... that the process models also take more communicative roles in practice, both in terms of creating an internal design rationale, as well as demystifying the black box of design thinking to external stakeholders. We investigate this hypothesis through an interview study of four major danish design......-driven organisations, and analyse the different roles their archetypical process models take in their organisations. The main contribution is the identification of three, often overlapping roles, which design process models showed to assume in design-driven organisations: process guidance, adding transparency...

  5. Residual effects of ecstasy (3,4-methylenedioxymethamphetamine) on low level visual processes.

    Science.gov (United States)

    Murray, Elizabeth; Bruno, Raimondo; Brown, John

    2012-03-01

    'Ecstasy' (3,4-methylenedioxymethamphetamine) induces impaired functioning in the serotonergic system, including the occipital lobe. This study employed the 'tilt aftereffect' paradigm to operationalise the function of orientation-selective neurons among ecstasy consumers and controls as a means of investigating the role of reduced serotonin on visual orientation processing. The magnitude of the tilt aftereffect reflects the extent of lateral inhibition between orientation-selective neurons and is elicited to both 'real' contours, processed in visual cortex area V1, and illusory contours, processed in V2. The magnitude of tilt aftereffect to both contour types was examined among 19 ecstasy users (6 ecstasy only; 13 ecstasy-plus-cannabis users) and 23 matched controls (9 cannabis-only users; 14 drug-naive). Ecstasy users had a significantly greater tilt magnitude than non-users for real contours (Hedge's g = 0.63) but not for illusory contours (g = 0.20). These findings provide support for literature suggesting that residual effects of ecstasy (and reduced serotonin) impairs lateral inhibition between orientation-selective neurons in V1, which however suggests that ecstasy may not substantially affect this process in V2. Multiple studies have now demonstrated ecstasy-related deficits on basic visual functions, including orientation and motion processing. Such low-level effects may contribute to the impact of ecstasy use on neuropsychological tests of visuospatial function. Copyright © 2012 John Wiley & Sons, Ltd.

  6. A Robust Process Analytical Technology (PAT) System Design for Crystallization Processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli Bin; Sin, Gürkan; Gernaey, Krist

    2013-01-01

    A generic computer-aided framework for systematic design of a process monitoring and control system for crystallization processes has been developed to study various aspects of crystallization operations. The design framework contains a generic multidimensional modelling framework, a tool for gen...

  7. Model based process-product design and analysis

    DEFF Research Database (Denmark)

    Gani, Rafiqul

    This paper gives a perspective on modelling and the important role it has within product-process design and analysis. Different modelling issues related to development and application of systematic model-based solution approaches for product-process design is discussed and the need for a hybrid...... model-based framework is highlighted. This framework should be able to manage knowledge-data, models, and associated methods and tools integrated with design work-flows and data-flows for specific product-process design problems. In particular, the framework needs to manage models of different types......, forms and complexity, together with their associated parameters. An example of a model-based system for design of chemicals based formulated products is also given....

  8. Information processing theory in the early design stages

    DEFF Research Database (Denmark)

    Cash, Philip; Kreye, Melanie

    2014-01-01

    suggestions for improvements and support. One theory that may be particularly applicable to the early design stages is Information Processing Theory (IPT) as it is linked to the design process with regard to the key concepts considered. IPT states that designers search for information if they perceive......, the new knowledge is shared between the design team to reduce ambiguity with regards to its meaning and to build a shared understanding – reducing perceived uncertainty. Thus, we propose that Information-Processing Theory is suitable to describe designer activity in the early design stages...... uncertainty with regard to the knowledge necessary to solve a design challenge. They then process this information and compare if the new knowledge they have gained covers the previous knowledge gap. In engineering design, uncertainty plays a key role, particularly in the early design stages which has been...

  9. Design of a diagnostic residual gas analyzer for the ITER divertor

    Energy Technology Data Exchange (ETDEWEB)

    Klepper, C.C., E-mail: kleppercc@ornl.gov [Oak Ridge National Laboratory, Oak Ridge, TN 37831-6169 (United States); Biewer, T.M.; Graves, V.B. [Oak Ridge National Laboratory, Oak Ridge, TN 37831-6169 (United States); Andrew, P. [ITER Organisation, Route de Vinon-sur-Verdon, 13067 St. Paul-lez-Durance (France); Lukens, P.C. [US ITER Project Office, 1055 Commerce Park Dr #1, Oak Ridge, TN 37830 (United States); Marcus, C. [Oak Ridge National Laboratory, Oak Ridge, TN 37831-6169 (United States); Shimada, M., E-mail: shimada.michiya@jaea.go.jp [ITER Organisation, Route de Vinon-sur-Verdon, 13067 St. Paul-lez-Durance (France); Hughes, S.; Boussier, B. [ITER Organisation, Route de Vinon-sur-Verdon, 13067 St. Paul-lez-Durance (France); Johnson, D.W. [US ITER Diagnostics Office, Princeton Plasma Physics Laboratory, Princeton, NJ 08540 (United States); Gardner, W.L. [US ITER Project Office, 1055 Commerce Park Dr #1, Oak Ridge, TN 37830 (United States); Hillis, D.L. [Oak Ridge National Laboratory, Oak Ridge, TN 37831-6169 (United States); Vayakis, G.; Walsh, M. [ITER Organisation, Route de Vinon-sur-Verdon, 13067 St. Paul-lez-Durance (France)

    2015-10-15

    Highlights: • The divertor DRGA for ITER will measure neutral gas composition in the pumping ducts during plasma. • System must respond in timescales relevant to compositional changes in the divertor plasma. • It is shown that times can vary from 1 to 6 s for fuel (H2, D2, T2) up to 50 s for He (fusion reaction ash). • It is shown that present design delivers ∼ 1 s response even via an 8m long sampling pipe sampling. • Response time validated with VacTran{sup ®} over anticipated the 0.1–10 Pa pressure range in the ducts. - Abstract: One of the ITER diagnostics having reached an advanced design stage is a diagnostic RGA for the divertor, i.e. residual gas analysis system for the ITER divertor, which is intended to sample the divertor pumping duct region during the plasma pulse and to have a response time compatible with plasma particle and impurity lifetimes in the divertor region. Main emphasis is placed on helium (He) concentration in the ducts, as well as the relative concentration between the hydrogen isotopes (mainly in the form of diatomic molecules of H, D, and T). Measurement of the concentration of radiative gases, such as neon (Ne) and nitrogen (N{sub 2}), is also intended. Numerical modeling of the gas flow from the sampled region to the cluster of analysis sensors, through a long (∼8 m long, ∼110 mm diameter) sampling pipe originating from a pressure reducing orifice, confirm that the desired response time (∼1 s for He or D{sub 2}) is achieved with the present design.

  10. Residual stresses in Inconel 718 engine disks

    Directory of Open Access Journals (Sweden)

    Dahan Yoann

    2014-01-01

    Full Text Available Aubert&Duval has developed a methodology to establish a residual stress model for Inconel 718 engine discs. To validate the thermal, mechanical and metallurgical parts of the model, trials on lab specimens with specific geometry were carried out. These trials allow a better understanding of the residual stress distribution and evolution during different processes (quenching, ageing, machining. A comparison between experimental and numerical results reveals the residual stresses model accuracy. Aubert&Duval has also developed a mechanical properties prediction model. Coupled with the residual stress prediction model, Aubert&Duval can now propose improvements to the process of manufacturing in Inconel 718 engine disks. This model enables Aubert&Duval customers and subcontractors to anticipate distortions issues during machining. It could also be usedt to optimise the engine disk life.

  11. Characteristics of residues from thermally treated anaerobic sludges

    International Nuclear Information System (INIS)

    Friedman, A.A.; Smith, J.E.; De Santis, J.; Ptak, T.; Ganley, R.C.

    1988-01-01

    Sludge management and disposal are probably the most difficult and expensive operations involved in wastewater treatment today. To minimize final disposal costs many waste treatment facilities practice some form of anaerobic digestion and dewatering to reduce the volume and offensiveness of their by-product sludges. One potential alternative for reducing sludge volumes consists of high temperature, partial oxidation of these previously digested sludges (PDS) and subsequent anaerobic biological conversion of resulting soluble organics to methane. This paper describes solids destruction, residue characteristics and biodegradability factors that should be considered in the design of liquid thermal treatment processes for the management of anaerobic sludges. To date only very limited information is available concerning the suitability of thermally treated PDS to serve as a substrate for the generation of methane. The primary objective of this research was to determine the feasibility of producing methane efficiently from the residual VSS in anaerobically digested sludges. Secondary goals were to establish the ''best'' conditions for thermal treatment for solubilizing PDS, to observe the effect of the soluble products on methanogenesis and to evaluate process sidestreams for dewaterability and anaerobic biodegradability

  12. On Intelligent Design and Planning Method of Process Route Based on Gun Breech Machining Process

    Science.gov (United States)

    Hongzhi, Zhao; Jian, Zhang

    2018-03-01

    The paper states an approach of intelligent design and planning of process route based on gun breech machining process, against several problems, such as complex machining process of gun breech, tedious route design and long period of its traditional unmanageable process route. Based on gun breech machining process, intelligent design and planning system of process route are developed by virtue of DEST and VC++. The system includes two functional modules--process route intelligent design and its planning. The process route intelligent design module, through the analysis of gun breech machining process, summarizes breech process knowledge so as to complete the design of knowledge base and inference engine. And then gun breech process route intelligently output. On the basis of intelligent route design module, the final process route is made, edited and managed in the process route planning module.

  13. Design of plutonium processing facilities

    International Nuclear Information System (INIS)

    Derbyshire, W.; Sills, R.J.

    1982-01-01

    Five considerations for the design of plutonium processing facilities are identified. These are: Toxicity, Radiation, Criticality, Containment and Remote Operation. They are examined with reference to reprocessing spent nuclear fuel and application is detailed both for liquid and dry processes. (author)

  14. Residual stress by repair welds

    International Nuclear Information System (INIS)

    Mochizuki, Masahito; Toyoda, Masao

    2003-01-01

    Residual stress by repair welds is computed using the thermal elastic-plastic analysis with phase-transformation effect. Coupling phenomena of temperature, microstructure, and stress-strain fields are simulated in the finite-element analysis. Weld bond of a plate butt-welded joint is gouged and then deposited by weld metal in repair process. Heat source is synchronously moved with the deposition of the finite-element as the weld deposition. Microstructure is considered by using CCT diagram and the transformation behavior in the repair weld is also simulated. The effects of initial stress, heat input, and weld length on residual stress distribution are studied from the organic results of numerical analysis. Initial residual stress before repair weld has no influence on the residual stress after repair treatment near weld metal, because the initial stress near weld metal releases due to high temperature of repair weld and then stress by repair weld regenerates. Heat input has an effect for residual stress distribution, for not its magnitude but distribution zone. Weld length should be considered reducing the magnitude of residual stress in the edge of weld bead; short bead induces high tensile residual stress. (author)

  15. Thermal inertializing of solid incinerator residues

    International Nuclear Information System (INIS)

    Proelss, J.

    2003-01-01

    Inertialization of residues is a key task of incinerators. Residues of conventional incineration processes may contain high levels of inorganic or organic pollutants and must be treated prior to recycling. the most effective process is thermal treatment above the melting point. This will destroy organic pollutants like dioxins/furans and pathogenic compounds, while the heavy metals will be partly volatilized. The glassy slag obtained as end product is low in heavy metals and more or less resistant to leaching. The The author describes a method for calculating activity coefficients of volatile components of diluted, liquid multicomponent systems. With these data, the data base for thermodynamic description of fluid mixtures was updated, and a set of characteristic data was established for describing transport in an inflatable module. Once the activity coefficients of interesting constituents of the slag are known along with the transport conditions in the volatilization process, it is possible to optimize the thermal treatment of critical ashes and dusts with a view to energy consumption and process control. In two different exemplary process concepts, the energy consumption for residue treatment is estimated. The processes proposed are compared with published process proposals, and their energy consumption is assessed in a comoparative study [de

  16. Process Materialization Using Templates and Rules to Design Flexible Process Models

    Science.gov (United States)

    Kumar, Akhil; Yao, Wen

    The main idea in this paper is to show how flexible processes can be designed by combining generic process templates and business rules. We instantiate a process by applying rules to specific case data, and running a materialization algorithm. The customized process instance is then executed in an existing workflow engine. We present an architecture and also give an algorithm for process materialization. The rules are written in a logic-based language like Prolog. Our focus is on capturing deeper process knowledge and achieving a holistic approach to robust process design that encompasses control flow, resources and data, as well as makes it easier to accommodate changes to business policy.

  17. Chemical modelling of trace elements in pore water from PFBC residues containing ammonia

    International Nuclear Information System (INIS)

    Karlsson, L.G.; Brandberg, F.

    1993-01-01

    Ammonia is added to the PFBC process with the purpose to reduce the emissions of NO x in the stack gases. The design of the system for cleaning the stack gases will lead to an increased adsorption of ammonia and an accumulation of soluble ammonium salts in the cyclone ash from PFBC processes. This can be an environmental problem since the amounts will increase over the coming years and there will be a need to dispose the residues. When infiltrating rainwater penetrates the disposed residues ammonia and ammonium salts result in a contamination of the pore water with ammonia in the disposed residues. This entail the solubility of several trace elements in the residues that form soluble complexes with ammonia will increase and cause an increased contamination of groundwater and surface water. In this study the increased solubilities is calculated for the trace elements cadmium, cobalt, copper, mercury, nickel, silver and zinc in the residues using thermodynamical data. The calculations have been performed with probable solid phases of the trace elements at oxidizing and reducing conditions as a function of pH and at varying concentration of ammonia in the pore water. The thermodynamic calculations have been performed with the geochemical code EQ3NR. The results from the calculations show that as a concentration of 17 mg NH 3 /l in the pore water of the residues increases the solubilities for copper and silver. If the concentration of ammonia increases to 170 mg NH 3 /l will the solubilities increase also for cadmium, nickel and zinc. (12 refs., 39 figs.)

  18. Residual nilpotence and residual solubility of groups

    International Nuclear Information System (INIS)

    Mikhailov, R V

    2005-01-01

    The properties of the residual nilpotence and the residual solubility of groups are studied. The main objects under investigation are the class of residually nilpotent groups such that each central extension of these groups is also residually nilpotent and the class of residually soluble groups such that each Abelian extension of these groups is residually soluble. Various examples of groups not belonging to these classes are constructed by homological methods and methods of the theory of modules over group rings. Several applications of the theory under consideration are presented and problems concerning the residual nilpotence of one-relator groups are considered.

  19. Modeling and simulation for process and safeguards system design

    International Nuclear Information System (INIS)

    Gutmacher, R.G.; Kern, E.A.; Duncan, D.R.; Benecke, M.W.

    1983-01-01

    A computer modeling and simulation approach that meets the needs of both the process and safeguards system designers is described. The results have been useful to Westinghouse Hanford Company process designers in optimizing the process scenario and operating scheme of the Secure Automated Fabrication line. The combined process/measurements model will serve as the basis for design of the safeguards system. Integration of the process design and the safeguards system design should result in a smoothly operating process that is easier to safeguard

  20. Evaluation of in-plant neutron coincidence counters for the measurement of molten salt extraction residues

    International Nuclear Information System (INIS)

    Langner, D.G.; Russo, P.A.; Wachter, J.R.

    1993-01-01

    Americium is extracted from plutonium by a molten salt extraction (MSE) process. The residual americium-laden salts are a significant waste stream in this pyrochemical purification process. Rapid assay of MSE residues is desirable to minimize the exposure of personnel to these often high-level emissions. However, the quantitative assay of plutonium in MSE residues is difficult. Variable, unknown (a,n) rates and variable emitted-neutron energy spectra preclude the use of standard neutron coincidence counting techniques with old-generation neutron coincidence counters. Gamma-ray assay methods have not been successful with some residues because of random lumps of plutonium metal. In this paper, we present measurements of MSE residues with two state-of-the-art neutron coincidence counters at the Los Alamos Plutonium Processing Facility: an in-line counter built for the assay of bulk waste material and the pyrochemical multiplicity counter that underwent test and evaluation at that facility. Both of these counters were designed to minimize the effects on measurements of variations in the sample geometry and variable energy spectra of emitted neutrons. These results are compared to measurements made with an HLNCII and with a 20-yr-old in-line well counter. The latter two counters are not optimized in ft sense. We conclude that the newer counters provide significantly improved assay results. The pyrochemical multiplicity counter operated in the conventional coincidence mode provided the best assays overall

  1. Design of object processing systems

    NARCIS (Netherlands)

    Grigoras, D.R.; Hoede, C.

    Object processing systems are met rather often in every day life, in industry, tourism, commerce, etc. When designing such a system, many problems can be posed and considered, depending on the scope and purpose of design. We give here a general approach which involves graph theory, and which can

  2. Sociotechnical design processes and working environment: The case of a continuous process wok

    DEFF Research Database (Denmark)

    Broberg, Ole

    2000-01-01

    A five-year design process of a continuous process wok has been studied with the aim of elucidating the conditions for integrating working environment aspects. The design process is seen as a network building activity and as a social shaping process of the artefact. A working environment log...... is suggested as a tool designers can use to integrate considerations of future operators' working environment....

  3. Integrated Process Design and Control of Multi-element Reactive Distillation Processes

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil; Sales-Cruz, Mauricio; Huusom, Jakob Kjøbsted

    2016-01-01

    In this work, integrated process design and control of reactive distillation processes involving multi-elements is presented. The reactive distillation column is designed using methods and tools which are similar in concept to non-reactive distillation design methods, such as driving force approach....... The methods employed in this work are based on equivalent element concept. This concept facilitates the representation of a multi-element reactive system as equivalent binary light and heavy key elements. First, the reactive distillation column is designed at the maximum driving force where through steady...

  4. Computational fluid dynamics (CFD) analysis of the combustion process of a leather residuals gasification fuel gas: influence of fuel moisture content

    Energy Technology Data Exchange (ETDEWEB)

    Antonietti, Anderson Jose; Beskow, Arthur Bortolin; Silva, Cristiano Vitorino da [Universidade Regional Integrada do Alto Uruguai e das Missoes (URI), Erechim, RS (Brazil)], E-mails: arthur@uricer.edu.br, mlsperb@unisinos.br; Indrusiak, Maria Luiza Sperb [Universidade do Vale do Rio dos Sinos (UNISINOS), Sao Leopoldo, RS (Brazil)], E-mail: cristiano@uricer.edu.br

    2010-07-01

    This work presents a numerical study of the combustion process of leather residuals gasification gas, aiming the improvement of the process efficiency, considering different concentrations of water on the gas. The heating produced in this combustion process can be used to generation of thermal and/or electrical energy, for use at the leather industrial plant. However, the direct burning of this leather-residual-gas into the chambers is not straightforward. The alternative in development consists in processing this leather residuals by gasification or pyrolysis, separating the volatiles and products of incomplete combustion, for after use as fuel in a boiler. At these processes, different quantities of water can be used, resulting at different levels of moisture content in this fuel gas. This humidity can affect significantly the burning of this fuel, producing unburnt gases, as the carbon monoxide, or toxic gases as NOx, which must have their production minimized on the process, with the purpose of reducing the emission of pollutants to the atmosphere. Other environment-harmful-gases, remaining of the chemical treatment employed at leather manufacture, as cyanide, and hydrocarbons as toluene, must burn too, and the moisture content has influence on it. At this way, to increase understanding of the influence of moisture in the combustion process, it was made a numerical investigation study of reacting flow in the furnace, evaluating the temperature field, the chemical species concentration fields, flow mechanics and heat transfer at the process. The commercial CFD code CFX Ansys Inc. was used. Considering different moisture contents in the fuel used on the combustion process, with this study was possible to achieve the most efficient burning operation parameters, with improvement of combustion efficiency, and reduction of environmental harmful gases emissions. It was verified that the different moisture contents in the fuel gas demand different operation conditions

  5. Recipe for residual oil saturation determination

    Energy Technology Data Exchange (ETDEWEB)

    Guillory, A.J.; Kidwell, C.M.

    1979-01-01

    In 1978, Shell Oil Co., in conjunction with the US Department of Energy, conducted a residual oil saturation study in a deep, hot high-pressured Gulf Coast Reservoir. The work was conducted prior to initiation of CO/sub 2/ tertiary recovery pilot. Many problems had to be resolved prior to and during the residual oil saturation determination. The problems confronted are outlined such that the procedure can be used much like a cookbook in designing future studies in similar reservoirs. Primary discussion centers around planning and results of a log-inject-log operation used as a prime method to determine the residual oil saturation. Several independent methods were used to calculate the residual oil saturation in the subject well in an interval between 12,910 ft (3935 m) and 12,020 ft (3938 m). In general, these numbers were in good agreement and indicated a residual oil saturation between 22% and 24%. 10 references.

  6. Americium recovery from reduction residues

    Science.gov (United States)

    Conner, W.V.; Proctor, S.G.

    1973-12-25

    A process for separation and recovery of americium values from container or bomb'' reduction residues comprising dissolving the residues in a suitable acid, adjusting the hydrogen ion concentration to a desired level by adding a base, precipitating the americium as americium oxalate by adding oxalic acid, digesting the solution, separating the precipitate, and thereafter calcining the americium oxalate precipitate to form americium oxide. (Official Gazette)

  7. Documenting the Engineering Design Process

    Science.gov (United States)

    Hollers, Brent

    2017-01-01

    Documentation of ideas and the engineering design process is a critical, daily component of a professional engineer's job. While patent protection is often cited as the primary rationale for documentation, it can also benefit the engineer, the team, company, and stakeholders through creating a more rigorously designed and purposeful solution.…

  8. Bioethanol production from forestry residues: A comparative techno-economic analysis

    International Nuclear Information System (INIS)

    Frankó, Balázs; Galbe, Mats; Wallberg, Ola

    2016-01-01

    Highlights: • A proposed cellulosic ethanol biorefinery in Sweden was simulated with Aspen Plus. • Forestry residues with different bark contents were evaluated as raw materials. • The bark content negatively influenced the minimum ethanol selling price. • Sensitivity analyses were performed to assess the influence of raw material cost. - Abstract: A techno-economic analysis was conducted to assess the feasibility of using forestry residues with different bark contents for bioethanol production. A proposed cellulosic ethanol biorefinery in Sweden was simulated with Aspen Plus. The plant was assumed to convert different forestry assortments (sawdust and shavings, fuel logs, early thinnings, tops and branches, hog fuel and pulpwood) to ethanol, pellets, biogas and electricity. The intention was not to obtain absolute ethanol production costs for future facilities, but to assess and compare the future potential of utilizing different forestry residues for bioethanol production. The same plant design and operating conditions were assumed in all cases, and the effect of including bark on the whole conversion process, especially how it influenced the ethanol production cost, was studied. While the energy efficiency (not including district heating) obtained for the whole process was between 67 and 69% regardless of the raw material used, the ethanol production cost differed considerably; the minimum ethanol selling price ranging from 0.77 to 1.52 USD/L. Under the basic assumptions, all the forestry residues apart from sawdust and shavings exhibited a negative net present value at current market prices. The profitability decreased with increasing bark content of the raw material. Sensitivity analyses showed that, at current market prices, the utilization of bark-containing forestry residues will not provide significant cost improvement compared with pulpwood unless the conversion of cellulose and hemicellulose to monomeric sugars is improved.

  9. Proposal for management and alkalinity transformation of bauxite residue in China.

    Science.gov (United States)

    Xue, Shengguo; Kong, Xiangfeng; Zhu, Feng; Hartley, William; Li, Xiaofei; Li, Yiwei

    2016-07-01

    Bauxite residue is a hazardous solid waste produced during the production of alumina. Its high alkalinity is a potential threat to the environment which may disrupt the surrounding ecological balance of its disposal areas. China is one of the major global producers of alumina and bauxite residue, but differences in alkalinity and associated chemistry exist between residues from China and those from other countries. A detailed understanding of the chemistry of bauxite residue remains the key to improving its management, both in terms of minimizing environmental impacts and reducing its alkaline properties. The nature of bauxite residue and the chemistry required for its transformation are still poorly understood. This review focuses on various transformation processes generated from the Bayer process, sintering process, and combined Bayer-sintering process in China. Problems associated with transformation mechanisms, technical methods, and relative merits of these technologies are reviewed, while current knowledge gaps and research priorities are recommended. Future research should focus on transformation chemistry and its associated mechanisms and for the development of a clear and economic process to reduce alkalinity and soda in bauxite residue.

  10. Characterization of Residual Stress Effects on Fatigue Crack Growth of a Friction Stir Welded Aluminum Alloy

    Science.gov (United States)

    Newman, John A.; Smith, Stephen W.; Seshadri, Banavara R.; James, Mark A.; Brazill, Richard L.; Schultz, Robert W.; Donald, J. Keith; Blair, Amy

    2015-01-01

    An on-line compliance-based method to account for residual stress effects in stress-intensity factor and fatigue crack growth property determinations has been evaluated. Residual stress intensity factor results determined from specimens containing friction stir weld induced residual stresses are presented, and the on-line method results were found to be in excellent agreement with residual stress-intensity factor data obtained using the cut compliance method. Variable stress-intensity factor tests were designed to demonstrate that a simple superposition model, summing the applied stress-intensity factor with the residual stress-intensity factor, can be used to determine the total crack-tip stress-intensity factor. Finite element, VCCT (virtual crack closure technique), and J-integral analysis methods have been used to characterize weld-induced residual stress using thermal expansion/contraction in the form of an equivalent delta T (change in local temperature during welding) to simulate the welding process. This equivalent delta T was established and applied to analyze different specimen configurations to predict residual stress distributions and associated residual stress-intensity factor values. The predictions were found to agree well with experimental results obtained using the crack- and cut-compliance methods.

  11. Mild hypothermic culture conditions affect residual host cell protein composition post-Protein A chromatography.

    Science.gov (United States)

    Goey, Cher Hui; Bell, David; Kontoravdi, Cleo

    2018-04-01

    Host cell proteins (HCPs) are endogenous impurities, and their proteolytic and binding properties can compromise the integrity, and, hence, the stability and efficacy of recombinant therapeutic proteins such as monoclonal antibodies (mAbs). Nonetheless, purification of mAbs currently presents a challenge because they often co-elute with certain HCP species during the capture step of protein A affinity chromatography. A Quality-by-Design (QbD) strategy to overcome this challenge involves identifying residual HCPs and tracing their source to the harvested cell culture fluid (HCCF) and the corresponding cell culture operating parameters. Then, problematic HCPs in HCCF may be reduced by cell engineering or culture process optimization. Here, we present experimental results linking cell culture temperature and post-protein A residual HCP profile. We had previously reported that Chinese hamster ovary cell cultures conducted at standard physiological temperature and with a shift to mild hypothermia on day 5 produced HCCF of comparable product titer and HCP concentration, but with considerably different HCP composition. In this study, we show that differences in HCP variety at harvest cascaded to downstream purification where different residual HCPs were present in the two sets of samples post-protein A purification. To detect low-abundant residual HCPs, we designed a looping liquid chromatography-mass spectrometry method with continuous expansion of a preferred, exclude, and targeted peptide list. Mild hypothermic cultures produced 20% more residual HCP species, especially cell membrane proteins, distinct from the control. Critically, we identified that half of the potentially immunogenic residual HCP species were different between the two sets of samples.

  12. Hazardous drug residue on exterior vial surfaces: evaluation of a commercial manufacturing process.

    Science.gov (United States)

    Power, Luci A; Sessink, Paul J M; Gesy, Kathy; Charbonneau, Flay

    2014-04-01

    Hazardous drug residue on the exterior surface of drug vials poses a potential risk for exposure of health care workers involved in handling these products. The purpose of this article is to heighten the awareness of this serious issue and to evaluate a commercial manufacturing process for removing and containing hazardous drug (HD) residue on exterior vial surfaces. Additionally, findings from this study are interpreted, incorporated into the current body of evidence, and discussed by experts in this field. This study includes separate evaluations for the presence or absence of surface drug contamination on the vials of 3 HD products: 5-fluorouracil, cisplatin, and methotrexate. The drug products were packaged in vials using a patented prewashing/decontamination method, application of a polyvinylchloride (PVC) base, and use of clear glass vials. An additional step of encasing the vial in a shrink-wrapped sheath was used for 5-fluorouracil and cisplatin. Of all 5-fluorouracil (110 vials), methotrexate (60 vials), and cisplatin (60 vials) tested, only 2 had detectable amounts of surface residue. One 5-fluorouracil vial was found to have approximately 4 mg of 5-fluorouracil on the surface of the vial. The second contaminated vial was cisplatin, which was discovered to have 131 ng of platinum, equal to 200 ng of cisplatin or 0.2 μL of cisplatin solution, on the vial sheath. Using validated extraction and analytic methods, all but 2 of the 230 tested vials were found to be free of surface drug contamination. Pharmacy leaders need to take an active role in promoting the need for clean HD vials. Manufacturers should be required to provide their clients with data derived from externally validated analytic studies, reporting the level of HD contamination on the exterior of their vial products.

  13. Breaking through the bitumen upgrading barriers with the UOP Uniflex Process

    Energy Technology Data Exchange (ETDEWEB)

    Gillis, D. [UOP LLC, Des Plaines, IL (United States)

    2009-07-01

    High costs and environmental concerns are some of the challenges facing bitumen upgrading. In addition, yields from conventional process such as coking and ebullated bed hydrocracking are much lower than desired. As such, there is a need for processes that can maximize conversion and selectively produce transportation boiling range products, particularly distillates. There are both technical and financial challenges in providing a reliable high-conversion technology. UOP has developed the UOP Uniflex Process, a commercially based high-conversion residue upgrading process that selectively converts residues from conventional crude oils and bitumen to transportation fuels and high quality synthetic crude oil. The unique features of this technology were described along with commercialization background. Recent advances being developed by UOP under the AERI Hydrocarbon Upgrading Demonstration Program were also described, with particular reference to catalyst design, engineering design and residue by-product utilization. This presentation also outlined UOP's latest flow scheme options for use with existing upgrading technologies. tabs., figs.

  14. Process and device for separating gaseous and solid noxious substances from residues occurring in thermal processes, particularly in the pyrolysis of waste material. Verfahren und Vorrichtung zur Abscheidung von gasfoermigen und festen Schadstoffen aus Rueckstaenden, die bei thermischen Prozessen, insbesondere der Pyrolyse von Abfallstoffen, anfallen

    Energy Technology Data Exchange (ETDEWEB)

    1981-12-10

    The invention concerns a process for separating gaseous and solid noxious substances from residues which occur in a thermal process, particularly the pyrolysis of waste material in the form of crude gas and solid remnants. The purpose of the invention is to create a process and a device of this kind, where it is possible to remove the part containing the noxious substances separately from the remaining solid residue of the thermal process, particularly the residue from pyrolysis, and to deposit it, and also to make it possible to free the crude gas, particularly pyrolysis gas, from gaseous noxious substances. According to the invention the problem is solved by taking the fine solid part of the solid residue together with the crude gas from the solid residue, which is removed from the thermal process as free falling material, to a reaction vessel, where, by adding additives the sold part or the gaseous noxious substances are bound and removed.

  15. High-temperature vitrification of Hanford residual-liquid waste in a continuous melter

    International Nuclear Information System (INIS)

    Barnes, S.M.

    1980-04-01

    Over 270 kg of high-temperature borosilicate glass have been produced in a series of three short-term tests in the High-Temperature Ceramic Melter vitrification system at PNL. The glass produced was formulated to vitrify simulated Hanford residual-liquid waste. The tests were designed to (1) demonstrate the feasibility of utilizing high-temperature, continuous-vitrification technology for the immobilization of the residual-liquid waste, (2) test the airlift draining technique utilized by the high-temperature melter, (3) compare glass produced in this process to residual-liquid glass produced under laboratory conditions, (4) investigate cesium volatility from the melter during waste processing, and (5) determine the maximum residual-liquid glass production rate in the high-temperature melter. The three tests with the residual-liquid composition confirmed the viability of the continuous-melting vitrification technique for the immobilization of this waste. The airlift draining technique was demonstrated in these tests and the glass produced from the melter was shown to be less porous than the laboratory-produced glass. The final glass produced from the second test was compared to a glass of the same composition produced under laboratory conditions. The comparative tests found the glasses to be indistinguishable, as the small differences in the test results fell within the precision range of the characterization testing equipment. The cesium volatility was examined in the final test. This examination showed that 0.44 wt % of the cesium (assumed to be cesium oxide) was volatilized, which translates to a volatilization rate of 115 mg/cm 2 -h

  16. Design of microreactor by integration of reverse engineering and direct metal laser sintering process

    Energy Technology Data Exchange (ETDEWEB)

    Bineli, Aulus Roberto Romao; Gimenez Perez, Ana Paula; Bernardes, Luiz Fernando; Munhoz, Andre Luiz Jardini; Maciel Filho, Rubens [Universidade de Campinas (LOPCA/UNICAMP), SP (Brazil). School of Chemical Engineering. Laboratory of Optimization, Design and Advanced Process Control], Email: aulus@feq.unicamp.br

    2010-07-01

    The propose of this work is to present high precision microfabrication facilities using computer aided technologies as Reverse Engineering (RE) and Rapid Manufacturing (RM) to analyze, design and construct micro reactors to produce high content hydrogen gas. Micro reactors are very compact, have a high surface to volume ratio, exhibit enhanced heat and mass transfer rates, denotes extremely low pressure drop and allow improved thermal integration in the processes involved. The main goals of micro reactors are the optimization of conventional chemical plants and low footprint, opening different ways to research new process technologies and synthesis of new products. In this work, a microchannels plate and housing structure of these plates were fabricated using DMLS method (Direct Metal Laser Sintering). The plates were analyzed to verify the minimum thickness wall that machine can produce, and the housing structure were digitalized, using a 3D scanning, to perform a 3D inspection and to verify the deflection of the constructed part in comparison with original CAD design models. It was observed that DMLS systems are able to produce micro reactors and microchannels plates with high precision at different metallic materials. However, it is important to choose appropriate conditions to avoid residual stresses and consequently warping parts. (author)

  17. Effects of thermal processing on the enzyme-linked immunosorbent assay (ELISA) detection of milk residues in a model food matrix.

    Science.gov (United States)

    Downs, Melanie L; Taylor, Steve L

    2010-09-22

    Food products and ingredients are frequently tested for the presence of undeclared allergenic food residues (including milk) using commercial enzyme-linked immunosorbent assays (ELISAs). However, little is understood about the efficacy of these kits with thermally processed foods. This study evaluated the performance of three milk ELISA kits with a model food processed by several methods. A model food (pastry dough squares) was spiked with nonfat dry milk at several concentrations. The pastry squares were processed by boiling (100 °C for 2 min), baking (190 °C for 30 min), frying (190 °C for 2 min), and retorting (121 °C for 20 min with 17 psi overpressure). Samples were analyzed with three commercial ELISA kits: Neogen Veratox Total Milk, ELISA Systems β-lactoglobulin, and ELISA Systems casein. The detection of milk residues depended upon the type of processing applied to the food and the specific milk analyte targeted by the ELISA kit. Poor recoveries were obtained in all processed samples (2-10% of expected values) using the β-lactoglobulin kit. Better recoveries were obtained in boiled samples (44 and 59%, respectively) using the total milk and casein kits. However, these kits performed poorly with baked (9 and 21%) and fried (7 and 18%) samples. Moderate recoveries were observed in retorted samples (23 and 28%). The decreased detection in processed samples is likely due to protein modifications, including aggregation and Maillard reactions, which affect the solubility and immunoreactivity of the antigens detected by the ELISA methods. The observed decreases in ELISA detection of milk are dramatic enough to affect risk-assessment decisions. However, a lower detection of milk residues does not necessarily indicate decreased allergenicity. These ELISA kits are not acceptable for all applications, and users should understand the strengths and limitations of each method.

  18. Cellulosic ethanol production from agricultural residues in Nigeria

    International Nuclear Information System (INIS)

    Iye, Edward; Bilsborrow, Paul

    2013-01-01

    Nigeria′s Biofuels Policy introduced in 2007 mandates a 10% blend (E10) of bioethanol with gasoline. This study investigates the potential for the development of a cellulosic ethanol industry based on the availability of agricultural residues and models the number of commercial processing facilities that could be sited in the six Geo-political zones. The potential for cellulosic ethanol production from agricultural residues in Nigeria is 7556 km 3 per annum exceeding the mandate of 10% renewable fuel required and providing the potential for 12 large- and 11 medium-scale processing facilities based on the use of a single feedstock. Cassava and yam peelings provided in excess of 80% of the process residues available with enough feedstock to supply 10 large-scale facilities with a fairly even distribution across the zones. Sorghum straw, millet straw and maize stalks represented 75% of the potential resource available from field residues with the potential to supply 2 large- and 7 medium-scale processing facilities, all of which would be located in the north of the country. When a multi-feedstock approach is used, this provides the potential for either 29 large- or 58 medium-scale facilities based on outputs of 250 and 125 km 3 per annum respectively. - Highlights: • Nigeria′s Biofuels Policy mandates a 10% blend of bioethanol with gasoline. • Total bioethanol production from agricultural residues was 7556 km 3 per annum. • Process residues offer the greatest potential accounting for 62% of production. • Nigeria has the potential for 12 large- and 11 medium scale commercial. • The use of mixed feedstocks significantly increases the potential for production

  19. Simulation-based optimization for product and process design

    NARCIS (Netherlands)

    Driessen, L.

    2006-01-01

    The design of products and processes has gradually shifted from a purely physical process towards a process that heavily relies on computer simulations (virtual prototyping). To optimize this virtual design process in terms of speed and final product quality, statistical methods and mathematical

  20. Systematic Integrated Process Design and Control of Binary Element Reactive Distillation Processes

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil; Sales-Cruz, Mauricio; Huusom, Jakob Kjøbsted

    2016-01-01

    In this work, integrated process design and control of reactive distillation processes is considered through a computer-aided framework. First, a set of simple design methods for reactive distillation column that are similar in concept to non-reactive distillation design methods are extended...... to design-control of reactive distillation columns. These methods are based on the element concept where the reacting system of compounds is represented as elements. When only two elements are needed to represent the reacting system of more than two compounds, a binary element system is identified....... It is shown that the same design-control principles that apply to a non-reacting binary system of compounds are also valid for a reactive binary system of elements for distillation columns. Application of this framework shows that designing the reactive distillation process at the maximum driving force...

  1. Pesticide residue quantification analysis by hyperspectral imaging sensors

    Science.gov (United States)

    Liao, Yuan-Hsun; Lo, Wei-Sheng; Guo, Horng-Yuh; Kao, Ching-Hua; Chou, Tau-Meu; Chen, Junne-Jih; Wen, Chia-Hsien; Lin, Chinsu; Chen, Hsian-Min; Ouyang, Yen-Chieh; Wu, Chao-Cheng; Chen, Shih-Yu; Chang, Chein-I.

    2015-05-01

    Pesticide residue detection in agriculture crops is a challenging issue and is even more difficult to quantify pesticide residue resident in agriculture produces and fruits. This paper conducts a series of base-line experiments which are particularly designed for three specific pesticides commonly used in Taiwan. The materials used for experiments are single leaves of vegetable produces which are being contaminated by various amount of concentration of pesticides. Two sensors are used to collected data. One is Fourier Transform Infrared (FTIR) spectroscopy. The other is a hyperspectral sensor, called Geophysical and Environmental Research (GER) 2600 spectroradiometer which is a batteryoperated field portable spectroradiometer with full real-time data acquisition from 350 nm to 2500 nm. In order to quantify data with different levels of pesticide residue concentration, several measures for spectral discrimination are developed. Mores specifically, new measures for calculating relative power between two sensors are particularly designed to be able to evaluate effectiveness of each of sensors in quantifying the used pesticide residues. The experimental results show that the GER is a better sensor than FTIR in the sense of pesticide residue quantification.

  2. Study on residual stress across the pipes' thickness using outer surface rapid heating. Development of pipe outer surface irradiated laser stress improvement process (L-SIP)

    International Nuclear Information System (INIS)

    Ohta, Takahiro; Terasaki, Toshio

    2009-01-01

    The new process called L-SIP (outer surface irradiated Laser Stress Improvement Process) is developed to improve the tensile residual stress of the inner surface near the butt welded joints of pipes in the compression stress. The temperature gradient occurs in the thickness of pipes in heating the outer surface rapidly by laser beam. By the thermal expansion difference between the inner surface and the outer surface, the compression plastic strain generates near the outer surface and the tensile plastic strain generates near the inner surface of pipes. The compression stress occurs near the inner surface of pipes by the plastic deformation. In this paper, the theoretical equation which calculates residual stress distribution from the inherent strain distribution in the thickness of pipes is derived. And, the relation between the distribution of temperature and the residual stress in the thickness is examined for various pipes size. (1) By rapidly heating from the outer surface, the residual stress near the inner surface of the pipe is improved to the compression stress. (2) Pipes size hardly affects the distribution of the residual stress in the stainless steel pipes for piping (JISG3459). (3) The temperature rising area from the outside is smaller, the area of the compression residual stress near the inner surface becomes wider. (author)

  3. Process design (exterior – interior design)

    OpenAIRE

    Sandeva, Vaska; Despot, Katerina

    2013-01-01

    The design is a complex process of spatial organization and creative problem object. It switched to the study of complex natural conditions (analysis and evaluation) and the development of compositional solution structure of the object. Construction and shaping of all buildings whether it is exterior or interior, be it street, Square apartment building, park or greater forest massif, public facility (administrative buildings, hospitals, schools, galleries etc.), residential object (garsion...

  4. Design of remote handled process assemblies for the process facility modifications project

    International Nuclear Information System (INIS)

    Smets, J.L.; Ajifu, D.A.

    1987-01-01

    The modular design philosophy for the process facility modification project utilizes an integrated design of components to facilitate operations and maintenance of nuclear fuel reprocessing equipment in a hot cell environment. The utilization of a matrix of remoteable base frames combines with process equipment designed as remote assemblies and sub-assemblies has simplified the overall design. Modularity will allow future flexibility while providing advantages for construction and maintenance in the initial installation

  5. Towars a chemical reagents and residues management at the teaching laboratories of the Chemistry School of the Universidad Nacional

    OpenAIRE

    Ana Cristina Benavides Benavides; Xinia Vargas González; Gustavo Chaves Barboza; José Ángel Rodríguez Corrales

    2016-01-01

    The academic activities carried out at the School of Chemistry make indispensable to develop actions oriented toward the consolidation of a reagent and residue management system, especially in the teaching laboratories. The project “Management of reagents and residues in the teaching laboratories of the School of Chemistry” works under the Green Chemistry values which designs products and chemical processes that reduce or eliminate the use and production of dangerous substances, to benefit th...

  6. Potential for thermochemical conversion of biomass residues from the integrated sugar-ethanol process - Fate of ash and ash-forming elements.

    Science.gov (United States)

    Dirbeba, Meheretu Jaleta; Brink, Anders; DeMartini, Nikolai; Zevenhoven, Maria; Hupa, Mikko

    2017-06-01

    In this work, potential for thermochemical conversion of biomass residues from an integrated sugar-ethanol process and the fate of ash and ash-forming elements in the process are presented. Ash, ash-forming elements, and energy flows in the process were determined using mass balances and analyses of eight different biomass samples for ash contents, elemental compositions, and heating values. The results show that the ash content increases from the sugarcane to the final residue, vinasse. The cane straw, which is left in the field, contains one-third of the energy and 25% of the K and Cl while the vinasse contains 2% of the energy and 40% of the K and Cl in the cane. K and Cl in biomass fuels cause corrosion and fouling problems in boilers and gasifiers. Over 85% of these elements in the straw are water soluble indicating that water leaching would improve it for utilization in thermochemical conversion. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Characterization of Hospital Residuals

    International Nuclear Information System (INIS)

    Blanco Meza, A.; Bonilla Jimenez, S.

    1997-01-01

    The main objective of this investigation is the characterization of the solid residuals. A description of the handling of the liquid and gassy waste generated in hospitals is also given, identifying the source where they originate. To achieve the proposed objective the work was divided in three stages: The first one was the planning and the coordination with each hospital center, in this way, to determine the schedule of gathering of the waste can be possible. In the second stage a fieldwork was made; it consisted in gathering the quantitative and qualitative information of the general state of the handling of residuals. In the third and last stage, the information previously obtained was organized to express the results as the production rate per day by bed, generation of solid residuals for sampled services, type of solid residuals and density of the same ones. With the obtained results, approaches are settled down to either determine design parameters for final disposition whether for incineration, trituration, sanitary filler or recycling of some materials, and storage politics of the solid residuals that allow to determine the gathering frequency. The study concludes that it is necessary to improve the conditions of the residuals handling in some aspects, to provide the cleaning personnel of the equipment for gathering disposition and of security, minimum to carry out this work efficiently, and to maintain a control of all the dangerous waste, like sharp or polluted materials. In this way, an appreciable reduction is guaranteed in the impact on the atmosphere. (Author) [es

  8. Facilitating Teamwork in the Design Process

    DEFF Research Database (Denmark)

    Bang, Anne Louise; Nissen, Kirsten

    2009-01-01

    By approaching the Repertory Grid as an exploratory design game and drawing on insight in diagrammatic reasoning we argue that this approach is useful in supporting team work in the design process. In this paper we draw on two courses inviting textile design students to contribute to the developm...

  9. Residual stress improvement in multi-layer welded plates using water-shower cooling during welding process

    International Nuclear Information System (INIS)

    Yanagida, Nobuyoshi; Koide, Hiroo

    2006-01-01

    To reduce tensile residual stress in a welded region, we developed a new welding method that applies a water-shower behind the welding torch. When this method is applied to welding of austenitic stainless steel plates, cooling conditions mainly determine how much the residual stress can be reduced. To determine the conditions, we first used FEM to evaluate the effects of interpass temperature on the residual stress. And we found effective conditions for reducing tensile residual stress. To verify the validity of the conditions, specimens welded with or without water shower cooling were manufactured. Residual stresses of the specimens were experimentally measured. It was found that tensile residual stresses were generated on the surface of the welds and those were reduced in the case that the water-shower was applied. These measurement results agree well with the FEM analyses. It can therefore be concluded that the water-shower cooling during welding is appropriate for reducing tensile residual stress in austenitic stainless steel welding. (author)

  10. REVERSING THE CO-DESIGN PROCESS

    DEFF Research Database (Denmark)

    Lundsgaard, Christina

    2011-01-01

    a traditional codesign process the POE looks back on the process in order to adjust or redesign the building. The paper argues that co-design tools can be an instrument to make architects and other stakeholders reflect on the project once again in order to see it from a different perspective....

  11. Design variables and constraints in fashion store design processes

    DEFF Research Database (Denmark)

    Haug, Anders; Borch Münster, Mia

    2015-01-01

    is to identify the most important store design variables, organise these variables into categories, understand the design constraints between categories, and determine the most influential stakeholders. Design/methodology/approach: – Based on a discussion of existing literature, the paper defines a framework...... into categories, provides an understanding of constraints between categories of variables, and identifies the most influential stakeholders. The paper demonstrates that the fashion store design task can be understood through a system perspective, implying that the store design task becomes a matter of defining......Purpose: – Several frameworks of retail store environment variables exist, but as shown by this paper, they are not particularly well-suited for supporting fashion store design processes. Thus, in order to provide an improved understanding of fashion store design, the purpose of this paper...

  12. Residual Wage Differences by Gender: Bounding the Estimates.

    Science.gov (United States)

    Sakellariou, Chris N.; Patrinos, Harry A.

    1996-01-01

    Uses data from the 1986 Canadian labor market activity survey file to derive estimates of residual gender wage gap differences. Investigates these estimates' dependence on experimental design and on assumptions about discrimination-free wage structures. Residual differences persist, even after restricting the sample to a group of highly motivated,…

  13. Integrating rock mechanics issues with repository design through design process principles and methodology

    International Nuclear Information System (INIS)

    Bieniawski, Z.T.

    1996-01-01

    A good designer needs not only knowledge for designing (technical know-how that is used to generate alternative design solutions) but also must have knowledge about designing (appropriate principles and systematic methodology to follow). Concepts such as open-quotes design for manufactureclose quotes or open-quotes concurrent engineeringclose quotes are widely used in the industry. In the field of rock engineering, only limited attention has been paid to the design process because design of structures in rock masses presents unique challenges to the designers as a result of the uncertainties inherent in characterization of geologic media. However, a stage has now been reached where we are be able to sufficiently characterize rock masses for engineering purposes and identify the rock mechanics issues involved but are still lacking engineering design principles and methodology to maximize our design performance. This paper discusses the principles and methodology of the engineering design process directed to integrating site characterization activities with design, construction and performance of an underground repository. Using the latest information from the Yucca Mountain Project on geology, rock mechanics and starter tunnel design, the current lack of integration is pointed out and it is shown how rock mechanics issues can be effectively interwoven with repository design through a systematic design process methodology leading to improved repository performance. In essence, the design process is seen as the use of design principles within an integrating design methodology, leading to innovative problem solving. In particular, a new concept of open-quotes Design for Constructibility and Performanceclose quotes is introduced. This is discussed with respect to ten rock mechanics issues identified for repository design and performance

  14. Characterization of Mechanical Properties and Residual Stress in API 5L X80 Steel Welded Joints

    Science.gov (United States)

    de Sousa Lins, Amilton; de Souza, Luís Felipe Guimarães; Fonseca, Maria Cindra

    2018-01-01

    The use of high-strength and low-alloy steels, high design factors and increasingly stringent safety requirements have increased the operating pressure levels and, consequently, the need for further studies to avoid and prevent premature pipe failure. To evaluate the possibility of improving productivity in manual arc welding of this type of steel, this work characterizes the mechanical properties and residual stresses in API 5L X80 steel welded joints using the SMAW and FCAW processes. The residual stresses were analyzed using x-ray diffraction with the sin2 ψ method at the top and root of the welded joints in the longitudinal and transverse directions of the weld bead. The mechanical properties of the welded joints by both processes were characterized in terms of tensile strength, impact toughness and Vickers microhardness in the welded and shot peening conditions. A predominantly compressive residual stress was found, and shot peening increased the tensile strength and impact toughness in both welded joints.

  15. Evaluation of low-residue soldering for military and commercial applications: A report from the Low-Residue Soldering Task Force

    Energy Technology Data Exchange (ETDEWEB)

    Iman, R.L.; Anderson, D.J. [Sandia National Labs., Albuquerque, NM (United States); Burress, R.V. [SEHO (United States)] [and others

    1995-06-01

    The LRSTF combined the efforts of industry, military, and government to evaluate low-residue soldering processes for military and commercial applications. These processes were selected for evaluation because they provide a means for the military to support the presidential mandate while producing reliable hardware at a lower cost. This report presents the complete details and results of a testing program conducted by the LRSTF to evaluate low-residue soldering for printed wiring assemblies. A previous informal document provided details of the test plan used in this evaluation. Many of the details of that test plan are contained in this report. The test data are too massive to include in this report, however, these data are available on disk as Excel spreadsheets upon request. The main purpose of low-residue soldering is to eliminate waste streams during the manufacturing process.

  16. DOE's process and implementation guidance for decommissioning, deactivation, decontamination, and remedial action of property with residual contamination

    International Nuclear Information System (INIS)

    Domotor, S.; Peterson, H. Jr.; Wallo, A. III

    1999-01-01

    This paper presents DOE's requirements, process, and implementation guidance for the control and release of property that may contain residual radioactive material. DOE requires that criteria and protocols for release of property be approved by DOE and that such limits be selected using DOE's As Low as is Reasonably Achievable (ALARA) process. A DOE Implementation Guide discusses how the levels and details (e.g., cleanup volumes, costs of surveys, disposal costs, dose to workers and doses to members of the public, social and economic factors) of candidate release options are to be evaluated using DOE's ALARA process. Supporting tools and models for use within the analysis are also highlighted. (author)

  17. Creativity Processes of Students in the Design Studio

    Science.gov (United States)

    Huber, Amy Mattingly; Leigh, Katharine E.; Tremblay, Kenneth R., Jr.

    2012-01-01

    The creative process is a multifaceted and dynamic path of thinking required to execute a project in design-based disciplines. The goal of this research was to test a model outlining the creative design process by investigating student experiences in a design project assignment. The study used an exploratory design to collect data from student…

  18. Effect of welding processes and joint configuration on the residual stresses and distortion in type 316 LN stainless steel weld joints

    International Nuclear Information System (INIS)

    Vasantharaja, P.; Vasudevan, M.; Palanichamy, P.

    2012-01-01

    Fabrication by welding introduces significant residual stresses in the welded structure/component due to non-uniform heat distribution during heating and cooling cycle. To control, reduce, or beneficially redistribute the residual stresses in weld joints, the stress distribution needs to be known. In the present study, weld joints of 16 mm thick 316LN stainless steel were made by multi-pass TIG, A-TIG welding and combination of TIG and A-TIG welding processes with various joint configurations. While V-groove edge preparation was required for making multi-pass TIG weld joint, square-edge preparation was sufficient for making A-TIG weld joint. Ultrasonic nondestructive technique based on the critically refracted longitudinal waves (LCR waves) has been used for the quantitative surface/sub-surface residual stress measurements in the weld joints. Distortion measurements were carried out before and after welding using height gauge. A-TIG weld joint was found to exhibit significant reduction in tensile residual stresses and distortion in comparison to that of other joints. (author)

  19. Process Optimization of Ultrasonic-Assisted Extraction of Arabinogalactan from Dihydroquercetin Extracted Residues by Response Surface Methodology and Evaluation of Its Antioxidant Activity

    Directory of Open Access Journals (Sweden)

    Zaizhi Liu

    2013-01-01

    Full Text Available Ultrasound was used for the extraction of larch arabinogalactan from Larix gmelinii. The optimal conditions for ultrasound extraction were determined by response surface methodology. Specifically, the Box-Behnken design was employed to evaluate the effects of three independent variables: ultrasound time, temperature, and liquid-solid ratio. The highest arabinogalactan yield (11.18% was obtained under the optimal extraction condition (extraction temperature 41.5°C, extraction time 24.3 min, and liquid-solid ratio 40 mL/g. In addition, the antioxidant activity of arabinogalactan that was extracted from dihydroquercetin extraction residues exhibited a moderate and concentration-dependent hydroxyl radical-scavenging capacity, ferric-reducing power, and reducing power. The wood material was characterized before and after processing by scanning electron microscopy and Fourier-transform infrared spectroscopy.

  20. Modeling the Influence of Process Parameters and Additional Heat Sources on Residual Stresses in Laser Cladding

    Science.gov (United States)

    Brückner, F.; Lepski, D.; Beyer, E.

    2007-09-01

    In laser cladding thermal contraction of the initially liquid coating during cooling causes residual stresses and possibly cracks. Preweld or postweld heating using inductors can reduce the thermal strain difference between coating and substrate and thus reduce the resulting stress. The aim of this work is to better understand the influence of various thermometallurgical and mechanical phenomena on stress evolution and to optimize the induction-assisted laser cladding process to get crack-free coatings of hard materials at high feed rates. First, an analytical one-dimensional model is used to visualize the most important features of stress evolution for a Stellite coating on a steel substrate. For more accurate studies, laser cladding is simulated including the powder-beam interaction, the powder catchment by the melt pool, and the self-consistent calculation of temperature field and bead shape. A three-dimensional finite element model and the required equivalent heat sources are derived from the results and used for the transient thermomechanical analysis, taking into account phase transformations and the elastic-plastic material behavior with strain hardening. Results are presented for the influence of process parameters such as feed rate, heat input, and inductor size on the residual stresses at a single bead of Stellite coatings on steel.

  1. Adsorption Property and Mechanism of Oxytetracycline onto Willow Residues

    Directory of Open Access Journals (Sweden)

    Di Wang

    2017-12-01

    Full Text Available To elucidate the adsorption property and the mechanism of plant residues to reduce oxytetracycline (OTC, the adsorption of OTC onto raw willow roots (WR-R, stems (WS-R, leaves (WL-R, and adsorption onto desugared willow roots (WR-D, stems (WS-D, and leaves (WL-D were investigated. The structural characterization was analyzed by scanning electron microscopy, Fourier-transform infrared spectra, and an elemental analyzer. OTC adsorption onto the different tissues of willow residues was compared and correlated with their structures. The adsorption kinetics of OTC onto willow residues was found to follow the pseudo-first-order model. The isothermal adsorption process of OTC onto the different tissues of willow residues followed the Langmuir and Freundlich model and the process was also a spontaneous endothermic reaction, which was mainly physical adsorption. After the willow residues were desugared, the polarity decreased and the aromaticity increased, which explained why the adsorption amounts of the desugared willow residues were higher than those of the unmodified residues. These observations suggest that the raw and modified willow residues have great potential as adsorbents to remove organic pollutants.

  2. Prediction of residual stress distributions due to surface machining and welding and crack growth simulation under residual stress distribution

    International Nuclear Information System (INIS)

    Ihara, Ryohei; Katsuyama, JInya; Onizawa, Kunio; Hashimoto, Tadafumi; Mikami, Yoshiki; Mochizuki, Masahito

    2011-01-01

    Research highlights: → Residual stress distributions due to welding and machining are evaluated by XRD and FEM. → Residual stress due to machining shows higher tensile stress than welding near the surface. → Crack growth analysis is performed using calculated residual stress. → Crack growth result is affected machining rather than welding. → Machining is an important factor for crack growth. - Abstract: In nuclear power plants, stress corrosion cracking (SCC) has been observed near the weld zone of the core shroud and primary loop recirculation (PLR) pipes made of low-carbon austenitic stainless steel Type 316L. The joining process of pipes usually includes surface machining and welding. Both processes induce residual stresses, and residual stresses are thus important factors in the occurrence and propagation of SCC. In this study, the finite element method (FEM) was used to estimate residual stress distributions generated by butt welding and surface machining. The thermoelastic-plastic analysis was performed for the welding simulation, and the thermo-mechanical coupled analysis based on the Johnson-Cook material model was performed for the surface machining simulation. In addition, a crack growth analysis based on the stress intensity factor (SIF) calculation was performed using the calculated residual stress distributions that are generated by welding and surface machining. The surface machining analysis showed that tensile residual stress due to surface machining only exists approximately 0.2 mm from the machined surface, and the surface residual stress increases with cutting speed. The crack growth analysis showed that the crack depth is affected by both surface machining and welding, and the crack length is more affected by surface machining than by welding.

  3. Design of a continuous process setup for precipitated calcium carbonate production from steel converter slag.

    Science.gov (United States)

    Mattila, Hannu-Petteri; Zevenhoven, Ron

    2014-03-01

    A mineral carbonation process "slag2PCC" for carbon capture, utilization, and storage is discussed. Ca is extracted from steel slag by an ammonium salt solvent and carbonated with gaseous CO2 after the separation of the residual slag. The solvent is reused after regeneration. The effects of slag properties such as the content of free lime, fractions of Ca, Si, Fe, and V, particle size, and slag storage on the Ca extraction efficiency are studied. Small particles with a high free-lime content and minor fractions of Si and V are the most suitable. To limit the amount of impurities in the process, the slag-to-liquid ratio should remain below a certain value, which depends on the slag composition. Also, the design of a continuous test setup (total volume ∼75 L) is described, which enables quick process variations needed to adapt the system to the varying slag quality. Different precipitated calcium carbonate crystals (calcite and vaterite) are generated in different parts of the setup. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. The design process and the use of computerized tools in control room design

    International Nuclear Information System (INIS)

    Wahlstroem, B.; Heinonen, R.; Ranta, J.; Haarla, J.

    1985-09-01

    Control room design has proven an important component when the safety and availability of a complex industrial process plant are considered. Many control room deficiencies can be traced back to oversights and other errors during the design process. The introduction of powerful computers and software for computer-aided design (CAD) offers one possibility when tools for improving the quality of design are being selected. The report gives a broad assessment of problems of design and the benefits of using computer-aided design. One proposal for a structure of a computer-aided design system is considered in more detail. In this system special emphasis has been laid on dealing with requirements during design process. A demonstration system has been built and sample system user dialogues are described. The report is the final report of the LIT3.1 project of the Nordic cooperation on human reliability in the energy production field. (author)

  5. Biotransformation of some industries residuals and evaluation of their humification process

    International Nuclear Information System (INIS)

    Bravo Isabel; Giraldo E; Garces P

    2001-01-01

    At the Cauca Department, manures are using obtained by means of compost of agricultural and cattle waste, with base in a Central American formula (Bocashi). Fifteen days after their preparation, these manures are applied to different crops. It is sought to replace some components to give it use to agro industrial waste that have not been found utility, among them residual fine dust of bagasse cane (marrow) generated during paper production; vinasse and husk of coffee and hen-dung that is expensive and of difficult access for all farmers. The humification process is also evaluated in 60 days period. Three bio-organic fertilizers were prepared by means of compost of materials: coffee husk until 26.7%. Fine dust until 11% and vinasse until 34% the following parameters were evaluated: humification degree by determination of organic matter (MO), humic acid, fulvic acid, humification relationships, cation exchange capacity (CIC) and C/N relationship. Physicochemical parameters like: temperature, pH, and content of nutrients. The presence of fine dust in manure improved the physicochemical properties achieving a better microbial development that is translated in a better humification process and bigger content of nutrients. The results demonstrate that at 15 days it is still incipient the maturation process, and that in the evaluated period it has not finished the humification; that hen-dung can be replaced by cattle manure whenever it is in fine e dust presence and that coffee husk is useful for obtaining bio-organic fertilizers

  6. Ethanol production from residual wood chips of cellulose industry: acid pretreatment investigation, hemicellulosic hydrolysate fermentation, and remaining solid fraction fermentation by SSF process.

    Science.gov (United States)

    Silva, Neumara Luci Conceição; Betancur, Gabriel Jaime Vargas; Vasquez, Mariana Peñuela; Gomes, Edelvio de Barros; Pereira, Nei

    2011-04-01

    Current research indicates the ethanol fuel production from lignocellulosic materials, such as residual wood chips from the cellulose industry, as new emerging technology. This work aimed at evaluating the ethanol production from hemicellulose of eucalyptus chips by diluted acid pretreatment and the subsequent fermentation of the generated hydrolysate by a flocculating strain of Pichia stipitis. The remaining solid fraction generated after pretreatment was subjected to enzymatic hydrolysis, which was carried out simultaneously with glucose fermentation [saccharification and fermentation (SSF) process] using a strain of Saccharomyces cerevisiae. The acid pretreatment was evaluated using a central composite design for sulfuric acid concentration (1.0-4.0 v/v) and solid to liquid ratio (1:2-1:4, grams to milliliter) as independent variables. A maximum xylose concentration of 50 g/L was obtained in the hemicellulosic hydrolysate. The fermentation of hemicellulosic hydrolysate and the SSF process were performed in bioreactors and the final ethanol concentrations of 15.3 g/L and 28.7 g/L were obtained, respectively.

  7. Integrated Design Process in Problem-Based Learning

    DEFF Research Database (Denmark)

    Knudstrup, Mary-Ann

    2004-01-01

    This article reports and reflects on the learning achievements and the educational experiences in connection with the first years of the curriculum in Architecture at Aalborg University ?s Civil Engineer Education in Architecture & Design. In the article I will focus on the learning activity and ...... the students need in order to concentrate, mobilize creativity and find the personal design language which is a precondition for making good architecture....... and the method that are developed during the semester when working with an Integrated Design Process combining architecture, design, functional aspects, energy consumption, indoor environment, technology, and construction. I will emphasize the importance of working with different tools in the design process, e...

  8. Analysis and radiological assessment of residues containing NORM materials resulting from earlier activities including modelling of typical industrial residues. Pt. 1. Historical investigation of the radiological relevance of NORM residues and concepts for site identification

    International Nuclear Information System (INIS)

    Reichelt, Andreas; Niedermayer, Matthias; Sitte, Beate; Hamel, Peter Michael

    2007-01-01

    Natural radionuclides are part of the human environment and of the raw materials used. Technical processes may cause their accumulation in residues, and the result will be so-called NORM materials (Naturally occurring radioactive material). The amended Radiation Protection Ordinance (StrlSchV 2001) specifies how the public should be protected, but there are also residues dating back before the issuing of the StrlSchV 2001, the so-called NORM residues. The project intended to assess the risks resulting from these residues. It comprises four parts. Part 1 was for clarification of the radiological relevance of NORM residues and for the development of concepts to detect them. The criterion for their radiological relevance was their activity per mass unit and the material volume accumulated through the centuries. The former was calculated from a wide bibliographic search in the relevant literature on radiation protection, while the mass volume was obtained by a detailed historical search of the consumption of materials that may leave NORM residues. These are, in particular, residues from coal and ore mining and processing. To identify concrete sites, relevant data sources were identified, and a concept for identification of concrete NORM residues was developed on this basis. (orig.) [de

  9. Mineral CO2 sequestration in alkaline solid residues

    International Nuclear Information System (INIS)

    Huijgen, W.J.J.; Comans, R.N.J.; Witkamp, G.J.

    2004-12-01

    Mineral carbonation is a promising sequestration route for the permanent and safe storage of carbon dioxide. In addition to calcium- or magnesium-containing primary minerals, suitable alkaline solid residues can be used as feedstock. The use of alkaline residues has several advantages, such as their availability close to CO2 sources and their higher reactivity for carbonation than primary minerals. In addition, the environmental quality of residues can potentially be improved by carbonation. In this study, key factors of the mineral CO2 sequestration process are identified, their influence on the carbonation process is examined, and environmental properties of the reaction products with regard to their possible beneficial utilization are investigated. The use of alkaline solid residues forms a potentially attractive alternative for the first mineral sequestration plants

  10. Engineering of an inhalable DDA/TDB liposomal adjuvant: a quality-by-design approach towards optimization of the spray drying process.

    Science.gov (United States)

    Ingvarsson, Pall Thor; Yang, Mingshi; Mulvad, Helle; Nielsen, Hanne Mørck; Rantanen, Jukka; Foged, Camilla

    2013-11-01

    The purpose of this study was to identify and optimize spray drying parameters of importance for the design of an inhalable powder formulation of a cationic liposomal adjuvant composed of dimethyldioctadecylammonium (DDA) bromide and trehalose-6,6'-dibehenate (TDB). A quality by design (QbD) approach was applied to identify and link critical process parameters (CPPs) of the spray drying process to critical quality attributes (CQAs) using risk assessment and design of experiments (DoE), followed by identification of an optimal operating space (OOS). A central composite face-centered design was carried out followed by multiple linear regression analysis. Four CQAs were identified; the mass median aerodynamic diameter (MMAD), the liposome stability (size) during processing, the moisture content and the yield. Five CPPs (drying airflow, feed flow rate, feedstock concentration, atomizing airflow and outlet temperature) were identified and tested in a systematic way. The MMAD and the yield were successfully modeled. For the liposome size stability, the ratio between the size after and before spray drying was modeled successfully. The model for the residual moisture content was poor, although, the moisture content was below 3% in the entire design space. Finally, the OOS was drafted from the constructed models for the spray drying of trehalose stabilized DDA/TDB liposomes. The QbD approach for the spray drying process should include a careful consideration of the quality target product profile. This approach implementing risk assessment and DoE was successfully applied to optimize the spray drying of an inhalable DDA/TDB liposomal adjuvant designed for pulmonary vaccination.

  11. THEORETICAL FRAMES FOR DESIGNING REVERSE LOGISTICS PROCESSES

    OpenAIRE

    Janusz K. Grabara; Sebastian Kot

    2009-01-01

    Logistics processes of return flow became more and more important in present business practice. Because of better customer satisfaction, environmental and financial aspects many enterprises deal with reverse logistics performance. The paper is a literature review focused on the design principles of reverse logistics processes Keywords: reverse logistics, designing.

  12. Residual stress analysis in BWR pressure vessel attachments

    International Nuclear Information System (INIS)

    Dexter, R.J.; Leung, C.P.; Pont, D.

    1992-06-01

    Residual stresses from welding processes can be the primary driving force for stress corrosion cracking (SCC) in BWR components. Thus, a better understanding of the causes and nature of these residual stresses can help assess and remedy SCC. Numerical welding simulation software, such as SYSWELD, and material property data have been used to quantify residual stresses for application to SCC assessments in BWR components. Furthermore, parametric studies using SYSWELD have revealed which variables significantly affect predicted residual stress. Overall, numerical modeling techniques can be used to evaluate residual stress for SCC assessments of BWR components and to identify and plan future SCC research

  13. Knowledge and Processes in Design. DPS Final Report.

    Science.gov (United States)

    Pirolli, Peter

    Four papers from a project concerning information-processing characterizations of the knowledge and processes involved in design are presented. The project collected and analyzed verbal protocols from instructional designers, architects, and mechanical engineers. A framework was developed for characterizing the problem spaces of design that…

  14. describing a collaborative clothing design process between

    African Journals Online (AJOL)

    user

    ISSN 0378-5254 Journal of Family Ecology and Consumer Sciences, Vol 43, 2015. Designing success: describing a ... PROCESS BETWEEN APPRENTICE DESIGNERS AND EXPERT DESIGN .... 5 Evaluation and decisions. (a) Outcomes.

  15. Minimization of zirconium chlorinator residues

    International Nuclear Information System (INIS)

    Green, G.K.; Harbuck, D.D.

    1995-01-01

    Zirconium chlorinator residues contain an array of rare earths, scandium, unreacted coke, and radioactive thorium and radium. Because of the radioactivity, the residues must be disposed in special waste containment facilities. As these sites become more congested, and with stricter environmental regulations, disposal of large volumes of wastes may become more difficult. To reduce the mass of disposed material, the US Bureau of Mines (USBM) developed technology to recover rare earths, thorium and radium, and unreacted coke from these residues. This technology employs an HCl leach to solubilize over 99% of the scandium and thorium, and over 90% of the rare earths. The leach liquor is processed through several solvent extraction stages to selectively recover scandium, thorium, and rare earths. The leach residue is further leached with an organic acid to solubilize radium, thus allowing unreacted coke to be recycled to the chlorinator. The thorium and radium waste products, which comprise only 2.1% of the original residue mass, can then be sent to the radioactive waste facility

  16. Blocking of proteolytic processing and deletion of glycosaminoglycan side chain of mouse DMP1 by substituting critical amino acid residues.

    Science.gov (United States)

    Peng, Tao; Huang, Bingzhen; Sun, Yao; Lu, Yongbo; Bonewald, Lynda; Chen, Shuo; Butler, William T; Feng, Jerry Q; D'Souza, Rena N; Qin, Chunlin

    2009-01-01

    Dentin matrix protein 1 (DMP1) is present in the extracellular matrix (ECM) of dentin and bone as processed NH(2)- and COOH-terminal fragments, resulting from proteolytic cleavage at the NH(2) termini of 4 aspartic acid residues during rat DMP1 processing. One cleavage site residue, Asp(181) (corresponding to Asp(197) of mouse DMP1), and its flanking region are highly conserved across species. We speculate that cleavage at the NH(2) terminus of Asp(197) of mouse DMP1 represents an initial, first-step scission in the whole cascade of proteolytic processing. To test if Asp(197) is critical for initiating the proteolytic processing of mouse DMP1, we substituted Asp(197) with Ala(197) by mutating the corresponding nucleotides of mouse cDNA that encode this amino acid residue. This mutant DMP1 cDNA was cloned into a pcDNA3.1 vector. Data from transfection experiments indicated that this single substitution blocked the proteolytic processing of mouse DMP1 in HEK-293 cells, indicating that cleavage at the NH(2) terminus of Asp(197) is essential for exposing other cleavage sites for the conversion of DMP1 to its fragments. The NH(2)-terminal fragment of DMP1 occurs as a proteoglycan form (DMP1-PG) that contains a glycosaminoglycan (GAG) chain. Previously, we showed that a GAG chain is linked to Ser(74) in rat DMP1 (Ser(89) in mouse DMP1). To confirm that mouse DMP1-PG possesses a single GAG chain attached to Ser(89), we substituted Ser(89) by Gly(89). Data from transfection analysis indicated that this substitution completely prevented formation of the GAG-containing form, confirming that DMP1-PG contains a single GAG chain attached to Ser(89) in mouse DMP1. Copyright 2008 S. Karger AG, Basel.

  17. Solid propellant processing factor in rocket motor design

    Science.gov (United States)

    1971-01-01

    The ways are described by which propellant processing is affected by choices made in designing rocket engines. Tradeoff studies, design proof or scaleup studies, and special design features are presented that are required to obtain high product quality, and optimum processing costs. Processing is considered to include the operational steps involved with the lining and preparation of the motor case for the grain; the procurement of propellant raw materials; and propellant mixing, casting or extrusion, curing, machining, and finishing. The design criteria, recommended practices, and propellant formulations are included.

  18. SHIPBUILDING PRODUCTION PROCESS DESIGN METHODOLOGY USING COMPUTER SIMULATION

    OpenAIRE

    Marko Hadjina; Nikša Fafandjel; Tin Matulja

    2015-01-01

    In this research a shipbuilding production process design methodology, using computer simulation, is suggested. It is expected from suggested methodology to give better and more efficient tool for complex shipbuilding production processes design procedure. Within the first part of this research existing practice for production process design in shipbuilding was discussed, its shortcomings and problem were emphasized. In continuing, discrete event simulation modelling method, as basis of sugge...

  19. On residual gas analysis during high temperature baking of graphite tiles

    International Nuclear Information System (INIS)

    Prakash, A A; Chaudhuri, P; Khirwadkar, S; Reddy, D Chenna; Saxena, Y C; Chauhan, N; Raole, P M

    2008-01-01

    Steady-state Super-conducting Tokamak-1 (SST-1) is a medium size tokamak with major radius of 1.1 m and minor radius of 0.20 m. It is designed for plasma discharge duration of 1000 seconds to obtain fully steady-state plasma operation. Plasma Facing Components (PFC), consisting of divertors, passive stabilizers, baffles and poloidal limiters are also designed to be UHV compatible for steady state operation. All PFC are made up of graphite tiles mechanically attached to the copper alloy substrate. Graphite is one of the preferred first wall armour material in present day tokamaks. High thermal shock resistance and low atomic number of carbon are the most important properties of graphite for this application. High temperature vacuum baking of graphite tiles is the standard process to remove the impurities. Residual Gas Analyzer (RGA) has been used for qualitative and quantitative measurements of released gases from graphite tiles during baking. Surface Analysis of graphite tiles has also been done before and after baking. This paper describes the residual gas analysis during baking and surface analysis of graphite tiles

  20. On residual gas analysis during high temperature baking of graphite tiles

    Energy Technology Data Exchange (ETDEWEB)

    Prakash, A A; Chaudhuri, P; Khirwadkar, S; Reddy, D Chenna; Saxena, Y C [Institute for Plasma Research, Bhat, Gandhinagar - 382 428 (India); Chauhan, N; Raole, P M [Facilitation Center for Industrial Plasma Technologies, IPR, Gandhinagar (India)], E-mail: arun@ipr.res.in

    2008-05-01

    Steady-state Super-conducting Tokamak-1 (SST-1) is a medium size tokamak with major radius of 1.1 m and minor radius of 0.20 m. It is designed for plasma discharge duration of 1000 seconds to obtain fully steady-state plasma operation. Plasma Facing Components (PFC), consisting of divertors, passive stabilizers, baffles and poloidal limiters are also designed to be UHV compatible for steady state operation. All PFC are made up of graphite tiles mechanically attached to the copper alloy substrate. Graphite is one of the preferred first wall armour material in present day tokamaks. High thermal shock resistance and low atomic number of carbon are the most important properties of graphite for this application. High temperature vacuum baking of graphite tiles is the standard process to remove the impurities. Residual Gas Analyzer (RGA) has been used for qualitative and quantitative measurements of released gases from graphite tiles during baking. Surface Analysis of graphite tiles has also been done before and after baking. This paper describes the residual gas analysis during baking and surface analysis of graphite tiles.

  1. Design for embedded image processing on FPGAs

    CERN Document Server

    Bailey, Donald G

    2011-01-01

    "Introductory material will consider the problem of embedded image processing, and how some of the issues may be solved using parallel hardware solutions. Field programmable gate arrays (FPGAs) are introduced as a technology that provides flexible, fine-grained hardware that can readily exploit parallelism within many image processing algorithms. A brief review of FPGA programming languages provides the link between a software mindset normally associated with image processing algorithms, and the hardware mindset required for efficient utilization of a parallel hardware design. The bulk of the book will focus on the design process, and in particular how designing an FPGA implementation differs from a conventional software implementation. Particular attention is given to the techniques for mapping an algorithm onto an FPGA implementation, considering timing, memory bandwidth and resource constraints, and efficient hardware computational techniques. Extensive coverage will be given of a range of image processing...

  2. The residual stress evaluation for expansion process of steam generator tubes

    International Nuclear Information System (INIS)

    King, C.-S.; Lee, S.-C.; Shim, D.-N.

    2004-01-01

    The reliability of a nuclear power plant is affected by the reliability of steam generator tube and the reliability of steam generator tube is affected by stress corrosion cracking(SCC). Many steam generator tubes were experiencing stress corrosion cracking and stress corrosion cracking is affected material characteristics, corrosive environments and added stresses. The added stresses have the manufacturing stresses and operating stresses, the manufacturing stresses include the residual stresses generating in the tube manufacture and tube expanding procedure. We will investigate for influence which affected to residual stresses with tube plastic deformation method and measurement region. (author)

  3. Microscopic residual stress evolution during deformation process of an Fe---Mn---Si---Cr shape memory alloy investigated using white X-ray microbeam diffraction

    International Nuclear Information System (INIS)

    Kwon, E.P.; Sato, S.; Fujieda, S.; Shinoda, K.; Kajiwara, K.; Sato, M.; Suzuki, S.

    2013-01-01

    Microscopic residual stress evolution in different austenite (γ) grains during shape memory process in an Fe---Mn---Si---Cr alloy was investigated using the white X-ray microbeam diffraction technique. The use of high-energy white X-ray microbeam with small beam size allowed us to measure the microscopic residual stress in coarse γ grains with specific orientation. After tensile deformation large compressive residual stress was evolved in γ grains due to the formation of stress-induced ε martensite, but upon recovery heating it almost disappeared as a result of reverse transformation of martensite. The magnitude of compressive residual stress was higher in grains with orientations close to 〈144〉 and 〈233〉 orientations than in a grain with near 〈001〉 orientation. Analysis of the microstructure of each grain using electron backscattering diffraction suggested that the difference in the magnitude of compressive residual stress could be attributed to different martensitic transformation characteristics in the grains

  4. Novel processing of Barkhausen noise signal for assessment of residual stress in surface ground components exhibiting poor magnetic response

    International Nuclear Information System (INIS)

    Vashista, M.; Paul, S.

    2011-01-01

    The Barkhausen Noise Analysis (BNA) technique has been utilised to assess surface integrity of steels. But the BNA technique is not very successful in evaluating surface integrity of ground steels that exhibit poor micro-magnetic response. A new approach has been proposed for the processing of BN signal and two newly proposed parameters, namely 'count' and 'event', have been shown to correlate linearly with the residual stress upon grinding, with judicious choice of user defined 'threshold', even when the micro-magnetic response of the work material is poor. In the present study, residual stress induced upon conventional plunge surface grinding of hardened bearing steel has been investigated along with unhardened bearing steel for benchmarking. Moreover, similar correlation has been established, when primarily compressive stress is induced upon high speed grinding using cBN wheel with moderately deep cut suppressing the micro-magnetic response from the ground medium carbon steel as the work material. - Highlights: → The problem of work materials exhibiting poor BN response and poor Barkhausen Noise response is identified. → A novel signal processing strategy is introduced to address the issue of poor micro-magnetic response of some ferromagnetic material. → Potential of newly introduced BN parameters has been studied. → These two BN parameters exhibited linear correlation with residual stress for work material with poor micro-magnetic response.

  5. Musical Instrument Design Process for Mobile Technology

    OpenAIRE

    Barraclough, Timothy J.; Carnegie, Dale A.; Kapur, Ajay

    2015-01-01

    This paper presents the iterative design process based upon multiple rounds of user studies that guided the the design of a novel social music application, Pyxis Minor. The application was designed based on the concept of democratising electronic music creation and performance. This required the development to be based upon user studies to inform and drive the development process in order to create a novel musical interface that can be enjoyed by users of any prior musicianship training.

  6. Acephate and buprofezin residues in olives and olive oil.

    Science.gov (United States)

    Cabras, P; Angioni, A; Garau, V L; Pirisi, F M; Cabitza, F; Pala, M

    2000-10-01

    Field trials were carried out to study the persistence of acephate and buprofezin on olives. Two cultivars, pizz'e carroga and pendolino, with very large and small fruits respectively were used. After treatment, no difference was found between the two pesticide deposits on the olives. The disappearance rates, calculated as pseudo first order kinetics, were similar for both pesticides (on average 12 days). Methamidophos, the acephate metabolite, was always present on all olives, and in some pendolino samples it showed higher residues than the maximum residue limit (MRL). During washing, the first step of olive processing, the residue level of both pesticides on the olives did not decrease. After processing of the olives into oil, no residues of acephate or methamidophos were found in the olive oil, while the residues of buprofezin were on average four times higher than on olives.

  7. Influence of organic waste and residue mud additions on chemical, physical and microbial properties of bauxite residue sand.

    Science.gov (United States)

    Jones, Benjamin E H; Haynes, Richard J; Phillips, Ian R

    2011-02-01

    In an alumina refinery, bauxite ore is treated with sodium hydroxide at high temperatures and pressures and for every tone of alumina produced, about 2 tones of alkaline, saline bauxite processing waste is also produced. At Alcoa, a dry stacking system of disposal is used, and it is the sand fraction of the processing waste that is rehabilitated. There is little information available regarding the most appropriate amendments to add to the processing sand to aid in revegetation. The purpose of this study was to investigate how the addition of organic wastes (biosolids and poultry manure), in the presence or absence of added residue mud, would affect the properties of the residue sand and its suitability for revegetation. Samples of freshly deposited residue sand were collected from Alcoa's Kwinana refinery. Samples were treated with phosphogypsum (2% v/v), incubated, and leached. A laboratory experiment was then set up in which the two organic wastes were applied at 0 or the equivalent to 60 tones ha(-1) in combination with residue mud added at rates of 0%, 10% and 20% v/v. Samples were incubated for 8 weeks, after which, key chemical, physical and microbial properties of the residue sand were measured along with seed germination. Additions of residue mud increased exchangeable Na(+), ESP and the pH, and HCO (3) (-) and Na(+) concentrations in saturation paste extracts. Additions of biosolids and poultry manure increased concentrations of extractable P, NH (4) (+) , K, Mg, Cu, Zn, Mn and Fe. Addition of residue mud, in combination with organic wastes, caused a marked decrease in macroporosity and a concomitant increase in mesoporosity, available water holding capacity and the quantity of water held at field capacity. With increasing residue mud additions, the percentage of sample present as sand particles (2 mm diameter) increased; greatest aggregation occurred where a combination of residue mud and poultry manure were added. Stability of aggregates, as measured by

  8. Electrodialytic remediation of air pollution control residues

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland

    Air pollution control (APC) residue from municipal solid waste incineration (MSWI) consists of the fly ash, and, in dry and semi-dry systems, also the reaction products from the flue gas cleaning process. APC residue is considered a hazardous waste due to its high alkalinity, high content of salt...

  9. Multidisciplinary systems engineering architecting the design process

    CERN Document Server

    Crowder, James A; Demijohn, Russell

    2016-01-01

    This book presents Systems Engineering from a modern, multidisciplinary engineering approach, providing the understanding that all aspects of systems design, systems, software, test, security, maintenance and the full life-cycle must be factored in to any large-scale system design; up front, not factored in later. It lays out a step-by-step approach to systems-of-systems architectural design, describing in detail the documentation flow throughout the systems engineering design process. It provides a straightforward look and the entire systems engineering process, providing realistic case studies, examples, and design problems that will enable students to gain a firm grasp on the fundamentals of modern systems engineering.  Included is a comprehensive design problem that weaves throughout the entire text book, concluding with a complete top-level systems architecture for a real-world design problem.

  10. Quadratic residues and non-residues selected topics

    CERN Document Server

    Wright, Steve

    2016-01-01

    This book offers an account of the classical theory of quadratic residues and non-residues with the goal of using that theory as a lens through which to view the development of some of the fundamental methods employed in modern elementary, algebraic, and analytic number theory. The first three chapters present some basic facts and the history of quadratic residues and non-residues and discuss various proofs of the Law of Quadratic Reciprosity in depth, with an emphasis on the six proofs that Gauss published. The remaining seven chapters explore some interesting applications of the Law of Quadratic Reciprocity, prove some results concerning the distribution and arithmetic structure of quadratic residues and non-residues, provide a detailed proof of Dirichlet’s Class-Number Formula, and discuss the question of whether quadratic residues are randomly distributed. The text is a valuable resource for graduate and advanced undergraduate students as well as for mathematicians interested in number theory.

  11. 'What-if' design: a synthesis method in the design process

    NARCIS (Netherlands)

    Lutters, Diederick; Vaneker, Thomas H.J.; van Houten, Frederikus J.A.M.

    2004-01-01

    In integrating functions, information and control in the design and engineering cycle, the information content acts as a facilitator, whereas the processes involved actually effectuate the results of the development cycle. As combining processes in an effective and efficient manner becomes

  12. Conceptual design of heterogeneous azeotropic distillation process for ethanol dehydration using 1-butanol as entrainer

    OpenAIRE

    Paritta Prayoonyong

    2014-01-01

    The synthesis of a heterogeneous azeotropic distillation process for ethanol dehydration using 1-butanol as entrainer is presented. The residue curve map of the ethanol/water/1-butanol mixture is computationally generated using non-random twoliquid thermodynamic model. It is found that 1-butanol leads to a residue curve map topological structure different from that generated by typical entrainers used in ethanol dehydration. Synthesis...

  13. Designing Participation Processes for Water Management and Beyond

    Directory of Open Access Journals (Sweden)

    Yorck von Korff

    2010-09-01

    Full Text Available This article addresses the question of how to design participation processes in water management and other fields. Despite a lot of work on participation, and especially its evaluation, this question has received little attention in the research literature. However, it is important, because previous research has made it clear that participation may yield important benefits for humans and the environment but that these benefits do not occur automatically. One precondition is sound design. The design of participation processes has been addressed in detail in the so-called "craft" literature but more rarely in the scientific literature. This article helps close this gap by systematically analyzing and comparing five design guides to determine whether it is possible to combine them into a more robust guide. The article confirms that possibility and presents a preliminary outline for such a guide. Principles for participatory process orientation are presented, as well as numerous partially iterative steps. The adaptive process is laid out in a way intended to help designers determine the objectives of the participation process and the initial design context, and make preplanning choices that eventually lead to the selection of suitable participation mechanisms. There are also design tools that facilitate this work. We discuss how our findings are largely compatible with previous research on participation, notably the work on criteria for "good" or "effective" participation processes. We also argue that our article advances research on an important remaining question in the scientific literature on participation: What process should be chosen in which context?

  14. Dissecting the functional role of key residues in triheme cytochrome PpcA: a path to rational design of G. sulfurreducens strains with enhanced electron transfer capabilities.

    Directory of Open Access Journals (Sweden)

    Leonor Morgado

    Full Text Available PpcA is the most abundant member of a family of five triheme cytochromes c7 in the bacterium Geobacter sulfurreducens (Gs and is the most likely carrier of electrons destined for outer surface during respiration on solid metal oxides, a process that requires extracellular electron transfer. This cytochrome has the highest content of lysine residues (24% among the family, and it was suggested to be involved in e-/H(+ energy transduction processes. In the present work, we investigated the functional role of lysine residues strategically located in the vicinity of each heme group. Each lysine was replaced by glutamine or glutamic acid to evaluate the effects of a neutral or negatively charged residue in each position. The results showed that replacing Lys9 (located near heme IV, Lys18 (near heme I or Lys22 (between hemes I and III has essentially no effect on the redox properties of the heme groups and are probably involved in redox partner recognition. On the other hand, Lys43 (near heme IV, Lys52 (between hemes III and IV and Lys60 (near heme III are crucial in the regulation of the functional mechanism of PpcA, namely in the selection of microstates that allow the protein to establish preferential e-/H(+ transfer pathways. The results showed that the preferred e-/H(+ transfer pathways are only established when heme III is the last heme to oxidize, a feature reinforced by a higher difference between its reduction potential and that of its predecessor in the order of oxidation. We also showed that K43 and K52 mutants keep the mechanistic features of PpcA by establishing preferential e-/H+ transfer pathways at lower reduction potential values than the wild-type protein, a property that can enable rational design of Gs strains with optimized extracellular electron transfer capabilities.

  15. 40 CFR 180.434 - Propiconazole; tolerances for residues.

    Science.gov (United States)

    2010-07-01

    ...: Commodity Parts per million Cranberry 1.0 Rice, wild, grain 0.5 (d) Indirect or inadvertent residues... 4.5 Pineapple, process residue 7.0 Pistachio 0.1 Rice, bran 15 Rice, grain 7.0 Rice, hulls 20 Rice...

  16. Multi-Criteria Approach in Multifunctional Building Design Process

    Science.gov (United States)

    Gerigk, Mateusz

    2017-10-01

    The paper presents new approach in multifunctional building design process. Publication defines problems related to the design of complex multifunctional buildings. Currently, contemporary urban areas are characterized by very intensive use of space. Today, buildings are being built bigger and contain more diverse functions to meet the needs of a large number of users in one capacity. The trends show the need for recognition of design objects in an organized structure, which must meet current design criteria. The design process in terms of the complex system is a theoretical model, which is the basis for optimization solutions for the entire life cycle of the building. From the concept phase through exploitation phase to disposal phase multipurpose spaces should guarantee aesthetics, functionality, system efficiency, system safety and environmental protection in the best possible way. The result of the analysis of the design process is presented as a theoretical model of the multifunctional structure. Recognition of multi-criteria model in the form of Cartesian product allows to create a holistic representation of the designed building in the form of a graph model. The proposed network is the theoretical base that can be used in the design process of complex engineering systems. The systematic multi-criteria approach makes possible to maintain control over the entire design process and to provide the best possible performance. With respect to current design requirements, there are no established design rules for multifunctional buildings in relation to their operating phase. Enrichment of the basic criteria with functional flexibility criterion makes it possible to extend the exploitation phase which brings advantages on many levels.

  17. What are the Characteristics of Engineering Design Processes?

    DEFF Research Database (Denmark)

    Maier, Anja; Störrle, Harald

    2011-01-01

    This paper studies the characteristic properties of Engineering Design (ED) processes from a process modelling perspective. In a first step, we extracted nine characteristics of engineering design processes from the literature and in a second step validated the findings using results from our...... survey among academic and industrial ED process modelling experts. In a third step, we added a further nine characteristics from personal experiences in the Language Engineering Domain to capture the pragmatic perspective. We arrive at a comprehensive set of 18 characteristics grouped into 6 challenges...... for process modelling in the engineering design domain. The challenges process modelers need to address when using and developing process modelling approaches and tools are: Development, Collaboration, Products & Services, Formality, Pragmatics, and Flexibility. We then compare the importance of elicited...

  18. Automated simulation and study of spatial-structural design processes

    NARCIS (Netherlands)

    Davila Delgado, J.M.; Hofmeyer, H.; Stouffs, R.; Sariyildiz, S.

    2013-01-01

    A so-called "Design Process Investigation toolbox" (DPI toolbox), has been developed. It is a set of computational tools that simulate spatial-structural design processes. Its objectives are to study spatial-structural design processes and to support the involved actors. Two case-studies are

  19. Calcination/dissolution residue treatment

    International Nuclear Information System (INIS)

    Knight, R.C.; Creed, R.F.; Patello, G.K.; Hollenberg, G.W.; Buehler, M.F.; O'Rourke, S.M.; Visnapuu, A.; McLaughlin, D.F.

    1994-09-01

    Currently, high-level wastes are stored underground in steel-lined tanks at the Hanford site. Current plans call for the chemical pretreatment of these wastes before their immobilization in stable glass waste forms. One candidate pretreatment approach, calcination/dissolution, performs an alkaline fusion of the waste and creates a high-level/low-level partition based on the aqueous solubilities of the components of the product calcine. Literature and laboratory studies were conducted with the goal of finding a residue treatment technology that would decrease the quantity of high-level waste glass required following calcination/dissolution waste processing. Four elements, Fe, Ni, Bi, and U, postulated to be present in the high-level residue fraction were identified as being key to the quantity of high-level glass formed. Laboratory tests of the candidate technologies with simulant high-level residues showed reductive roasting followed by carbonyl volatilization to be successful in removing Fe, Ni, and Bi. Subsequent bench-scale tests on residues from calcination/dissolution processing of genuine Hanford Site tank waste showed Fe was separated with radioelement decontamination factors of 70 to 1,000 times with respect to total alpha activity. Thermodynamic analyses of the calcination of five typical Hanford Site tank waste compositions also were performed. The analyses showed sodium hydroxide to be the sole molten component in the waste calcine and emphasized the requirement for waste blending if fluid calcines are to be achieved. Other calcine phases identified in the thermodynamic analysis indicate the significant thermal reconstitution accomplished in calcination

  20. Integrated Process Design, Control and Analysis of Intensified Chemical Processes

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil

    chemical processes; for example, intensified processes such as reactive distillation. Most importantly, it identifies and eliminates potentially promising design alternatives that may have controllability problems later. To date, a number of methodologies have been proposed and applied on various problems......, that the same principles that apply to a binary non-reactive compound system are valid also for a binary-element or a multi-element system. Therefore, it is advantageous to employ the element based method for multicomponent reaction-separation systems. It is shown that the same design-control principles...

  1. [Migrants from disposable gloves and residual acrylonitrile].

    Science.gov (United States)

    Wakui, C; Kawamura, Y; Maitani, T

    2001-10-01

    Disposable gloves made from polyvinyl chloride with and without di(2-ethylhexyl) phthalate (PVC-DEHP, PVC-NP), polyethylene (PE), natural rubber (NR) and nitrile-butadiene rubber (NBR) were investigated with respect to evaporation residue, migrated metals, migrants and residual acrylonitrile. The evaporation residue found in n-heptane was 870-1,300 ppm from PVC-DEHP and PVC-NP, which was due to the plasticizers. Most of the PE gloves had low evaporation residue levels and migrants, except for the glove designated as antibacterial, which released copper and zinc into 4% acetic acid. For the NR and NBR gloves, the evaporation residue found in 4% acetic acid was 29-180 ppm. They also released over 10 ppm of calcium and 6 ppm of zinc into 4% acetic acid, and 1.68-8.37 ppm of zinc di-ethyldithiocarbamate and zinc di-n-butyldithiocarbamate used as vulcanization accelerators into n-heptane. The acrylonitrile content was 0.40-0.94 ppm in NBR gloves.

  2. Chemical activation of gasification carbon residue for phosphate removal

    Science.gov (United States)

    Kilpimaa, Sari; Runtti, Hanna; Lassi, Ulla; Kuokkanen, Toivo

    2012-05-01

    Recycling of waste materials provides an economical and environmentally significant method to reduce the amount of waste. Bioash formed in the gasification process possesses a notable amount of unburned carbon and therefore it can be called a carbon residue. After chemical activation carbon residue could be use to replace activated carbon for example in wastewater purification processes. The effect of chemical activation process variables such as chemical agents and contact time in the chemical activation process were investigated. This study also explored the effectiveness of the chemically activated carbon residue for the removal of phosphate from an aqueous solution. The experimental adsorption study was performed in a batch reactor and the influence of adsorption time, initial phosphate concentration and pH was studied. Due to the carbon residue's low cost and high adsorption capacity, this type of waste has the potential to be utilised for the cost-effective removal of phosphate from wastewaters. Potential adsorbents could be prepared from these carbonaceous by-products and used as an adsorbent for phosphate removal.

  3. Modular design of synthetic protein mimics. Characterization of the helical conformation of a 13-residue peptide in crystals

    International Nuclear Information System (INIS)

    Karle, I.L.; Flippen-Anderson, J.L.; Uma, K.; Balaram, P.

    1989-01-01

    The incorporation of α-aminoisobutyryl (Aib) residues into peptide sequences facilitates helical folding. Aib-containing sequences have been chosen for the design of rigid helical segments in a modular approach to the construction of a synthetic protein mimic. The helical conformation of the synthetic peptide Boc-Aib-(Val-Ala-Leu-Aib) 3 -OMe in crystals is established by X-ray diffraction. The 13-residue apolar peptide adopts a helical form in the crystal with seven α-type hydrogen bonds in the middle and 3 10 -type hydrogen bonds at either end. The helices stack in columns, zigzag rather than linear, by means of direct NH hor-ellipsis OC head to tail hydrogen bonds. Leucyl side chains are extended on one side of the helix and valyl side chains on the other side. Water molecules form hydrogen bonds with several backbone carbonyl oxygens that also participate in α-helix hydrogen bonds. There is no apparent distortion of the helix caused by hydration

  4. Drug and chemical residues in domestic animals.

    Science.gov (United States)

    Mussman, H C

    1975-02-01

    Given the large number of chemical substances that may find their way into the food supply, a system is needed to monitor their presence. The U. S. Department of Agriculture's Meat and Poultry Inspection Program routinely tests for chemical residues in animals coming to slaughter. Pesticides, heavy metals, growth promotants (hormones and hormonelike agents), and antibiotics are included. Samples are taken statistically so that inferences as to national incidence of residues can be drawn. When a problem is identified, a more selective sampling is designed to help follow up on the initial regulatory action. In testing for pesticides, only DDT and dieldrin are found with any frequency and their levels are decreasing; violative residues of any chlorinated hydrocarbon are generally a result of an industrial accident rather than agricultural usage. Analyses for heavy metals have revealed detectable levels of mercury, lead, and others, but none at levels that are considered a health hazard. Of the hormone or hormonelike substances, only diethylstilbestrol has been a residue problem and its future is uncertain. The most extensive monitoring for veterinary drugs is on the antimicrobials, including sulfonamides, streptomycin, and the tetracycline group of antibiotics that constitute the bulk of the violations; their simultaneous use prophylactically and therapeutically has contributed to the problem in certain cases. A strong, well-designed user education program on proper application of pesticides, chemicals, and veterinary drugs appears to be one method of reducing the incidence of unwanted residues.

  5. Active pharmaceutical ingredient (API) production involving continuous processes--a process system engineering (PSE)-assisted design framework.

    Science.gov (United States)

    Cervera-Padrell, Albert E; Skovby, Tommy; Kiil, Søren; Gani, Rafiqul; Gernaey, Krist V

    2012-10-01

    A systematic framework is proposed for the design of continuous pharmaceutical manufacturing processes. Specifically, the design framework focuses on organic chemistry based, active pharmaceutical ingredient (API) synthetic processes, but could potentially be extended to biocatalytic and fermentation-based products. The method exploits the synergic combination of continuous flow technologies (e.g., microfluidic techniques) and process systems engineering (PSE) methods and tools for faster process design and increased process understanding throughout the whole drug product and process development cycle. The design framework structures the many different and challenging design problems (e.g., solvent selection, reactor design, and design of separation and purification operations), driving the user from the initial drug discovery steps--where process knowledge is very limited--toward the detailed design and analysis. Examples from the literature of PSE methods and tools applied to pharmaceutical process design and novel pharmaceutical production technologies are provided along the text, assisting in the accumulation and interpretation of process knowledge. Different criteria are suggested for the selection of batch and continuous processes so that the whole design results in low capital and operational costs as well as low environmental footprint. The design framework has been applied to the retrofit of an existing batch-wise process used by H. Lundbeck A/S to produce an API: zuclopenthixol. Some of its batch operations were successfully converted into continuous mode, obtaining higher yields that allowed a significant simplification of the whole process. The material and environmental footprint of the process--evaluated through the process mass intensity index, that is, kg of material used per kg of product--was reduced to half of its initial value, with potential for further reduction. The case-study includes reaction steps typically used by the pharmaceutical

  6. Design Process Improvement for Electric CAR Harness

    Science.gov (United States)

    Sawatdee, Thiwarat; Chutima, Parames

    2017-06-01

    In an automobile parts design company, the customer satisfaction is one of the most important factors for product design. Therefore, the company employs all means to focus its product design process based on the various requirements of customers resulting in high number of design changes. The objective of this research is to improve the design process of the electric car harness that effects the production scheduling by using Fault Tree Analysis (FTA) and Failure Mode and Effect Analysis (FMEA) as the main tools. FTA is employed for root cause analysis and FMEA is used to ranking a High Risk Priority Number (RPN) which is shows the priority of factors in the electric car harness that have high impact to the design of the electric car harness. After the implementation, the improvements are realized significantly since the number of design change is reduced from 0.26% to 0.08%.

  7. Application of residual polysaccharide-degrading enzymes in dried shiitake mushrooms as an enzyme preparation in food processing.

    Science.gov (United States)

    Tatsumi, E; Konishi, Y; Tsujiyama, S

    2016-11-01

    To examine the activities of residual enzymes in dried shiitake mushrooms, which are a traditional foodstuff in Japanese cuisine, for possible applications in food processing. Polysaccharide-degrading enzymes remained intact in dried shiitake mushrooms and the activities of amylase, β-glucosidase and pectinase were high. A potato digestion was tested using dried shiitake powder. The enzymes reacted with potato tuber specimens to solubilize sugars even under a heterogeneous solid-state condition and that their reaction modes were different at 38 and 50 °C. Dried shiitake mushrooms have a potential use in food processing as an enzyme preparation.

  8. Reducing Design Cycle Time and Cost Through Process Resequencing

    Science.gov (United States)

    Rogers, James L.

    2004-01-01

    In today's competitive environment, companies are under enormous pressure to reduce the time and cost of their design cycle. One method for reducing both time and cost is to develop an understanding of the flow of the design processes and the effects of the iterative subcycles that are found in complex design projects. Once these aspects are understood, the design manager can make decisions that take advantage of decomposition, concurrent engineering, and parallel processing techniques to reduce the total time and the total cost of the design cycle. One software tool that can aid in this decision-making process is the Design Manager's Aid for Intelligent Decomposition (DeMAID). The DeMAID software minimizes the feedback couplings that create iterative subcycles, groups processes into iterative subcycles, and decomposes the subcycles into a hierarchical structure. The real benefits of producing the best design in the least time and at a minimum cost are obtained from sequencing the processes in the subcycles.

  9. [Development of residual voltage testing equipment].

    Science.gov (United States)

    Zeng, Xiaohui; Wu, Mingjun; Cao, Li; He, Jinyi; Deng, Zhensheng

    2014-07-01

    For the existing measurement methods of residual voltage which can't turn the power off at peak voltage exactly and simultaneously display waveforms, a new residual voltage detection method is put forward in this paper. First, the zero point of the power supply is detected with zero cross detection circuit and is inputted to a single-chip microcomputer in the form of pulse signal. Secend, when the zero point delays to the peak voltage, the single-chip microcomputer sends control signal to power off the relay. At last, the waveform of the residual voltage is displayed on a principal computer or oscilloscope. The experimental results show that the device designed in this paper can turn the power off at peak voltage and is able to accurately display the voltage waveform immediately after power off and the standard deviation of the residual voltage is less than 0.2 V at exactly one second and later.

  10. Method for innovative synthesis-design of chemical process flowsheets

    DEFF Research Database (Denmark)

    Kumar Tula, Anjan; Gani, Rafiqul

    Chemical process synthesis-design involve the identification of the processing route to reach a desired product from a specified set of raw materials, design of the operations involved in the processing route, the calculations of utility requirements, the calculations of waste and emission...... to the surrounding and many more. Different methods (knowledge-based [1], mathematical programming [2], hybrid, etc.) have been proposed and are also currently employed to solve these synthesis-design problems. D’ Anterroches [3] proposed a group contribution based approach to solve the synthesis-design problem...... of chemical processes, where, chemical process flowsheets could be synthesized in the same way as atoms or groups of atoms are synthesized to form molecules in computer aided molecular design (CAMD) techniques [4]. That, from a library of building blocks (functional process-groups) and a set of rules to join...

  11. Structural design considerations for a radwaste processing facility

    International Nuclear Information System (INIS)

    Foelber, S.C.; Sabbe, M.A.

    1985-01-01

    The structural engineer needs to consider several criteria when designing a radioactive-waste processing facility in order to properly balance the requirements of safety and economy. This paper addresses the design criteria and structural design of a vitrification building and the special equipment and supports associated with remote process operations. In addition, approaches to construction, and the role of scale models to aid in engineering design and construction are discussed. 5 figures

  12. Crop residue decomposition in Minnesota biochar amended plots

    OpenAIRE

    S. L. Weyers; K. A. Spokas

    2014-01-01

    Impacts of biochar application at laboratory scales are routinely studied, but impacts of biochar application on decomposition of crop residues at field scales have not been widely addressed. The priming or hindrance of crop residue decomposition could have a cascading impact on soil processes, particularly those influencing nutrient availability. Our objectives were to evaluate biochar effects on field decomposition of crop residue, using plots that were amended with ...

  13. Propoxur (2-iso propoxy-phenyl-N-methylcarbamate) residues in cocoa beans. Part of a coordinated programme on isotopic-tracer aided studies of chemical residues in cotton seed, feed, oil and related products

    International Nuclear Information System (INIS)

    Adomako, D.

    1982-05-01

    Pod-bearing Amazon and Amelonado cocoa plants were sprayed with Unden 20% (propoxur, arprocarb, baygon) at the recommended rate of 210 g a.i./ha and twice the recommended rate at monthly intervals from July to October 1976, and cured beans from the ripe pods analysed for propoxur residues by gas chromatography. In a radiotracer study with 14 C-labelled propoxur, the effect of processing methods on residues and systemic uptake of propoxur from insecticide deposits on pod surfaces were also investigated. Residues did not exceed 0.03 mg/kg. There was no relationship between residues and harvesting time, cocoa type or rate of application. Contamination of beans with insecticide deposits on the pod surface during processing, and systemic uptake of insecticide from pod surfaces were negligible. Experiments were also designed to provide data on 14 C-propoxur residues in cocoa beans, uptake of the chemical from pod surfaces and persistence on the leaves and in the soil. Leaves were picked from the lowest five branches of the cocoa trees, 13 months after the application of 14 C-propoxur, dried at 80 0 for 4 days, stored and analysed for their 14 C-activity. Soil samples were collected at 15 cm and 30 cm distances from the trunk base of treated trees, dried, stored and analysed. The analytical procedure involved extraction and clean-up steps after a standard method using acetone, chloroform and a coagulating agent. Propoxur residues in cocoa leaves collected 13 months after the insecticide application ranged from 0.01 to 0.04 mg/kg. Residues in shells from cocoa pods treated with 14 C-propoxur 2 months prior to harvest did not exceed 0.02 mg/kg. Propoxur residues in soil samples collected at 6, 16, and 19 months following application ranged from 0.01 to 0.03 mg/kg. These low levels are probably related to volatilization and heavy rains. Possible binding to soil cannot be precluded. The low levels of propoxur are unlikely to present any toxicological hazard to humans

  14. Self-bioremediation of cork-processing wastewaters by (chloro)phenol-degrading bacteria immobilised onto residual cork particles.

    Science.gov (United States)

    del Castillo, I; Hernández, P; Lafuente, A; Rodríguez-Llorente, I D; Caviedes, M A; Pajuelo, E

    2012-04-15

    Cork manufacturing is a traditional industry in Southern Europe, being the main application of this natural product in wine stoppers and insulation. Cork processing begins at boiling the raw material. As a consequence, great volumes of dark wastewaters, with elevated concentrations of chlorophenols, are generated, which must be depurated through costly physicochemical procedures before discarding them into public water courses. This work explores the potential of bacteria, isolated from cork-boiling waters storage ponds, in bioremediation of the same effluent. The bacterial population present in cork-processing wastewaters was analysed by DGGE; low bacterial biodiversity was found. Aerobic bacteria were isolated and investigated for their tolerance against phenol and two chlorophenols. The most tolerant strains were identified by sequencing 16S rDNA. The phenol-degrading capacity was investigated by determining enzyme activities of the phenol-degrading pathway. Moreover, the capacity to form biofilms was analysed in a microtitre plate assay. Finally, the capacity to form biofilms onto the surface of residual small cork particles was evaluated by acridine staining followed by epifluorescence microscopy and by SEM. A low-cost bioremediation system, using phenol-degrading bacteria immobilised onto residual cork particles (a by-product of the industry) is proposed for the remediation of this industrial effluent (self-bioremediation). Copyright © 2011 Elsevier Ltd. All rights reserved.

  15. Using a Design Science Perspective to Understand a Complex Design-Based Research Process

    DEFF Research Database (Denmark)

    Bækgaard, Lars

    2012-01-01

    The purpose of the paper is to demonstrate how a design science perspective can be used to describe and understand a set of related design-based research processes. We describe and analyze a case study in a manner that is inspired by design science. The case study involves the design of modeling......-based research processes. And we argue that a design science perspective may be useful for both researchers and practitioners....... tools and the redesign of an information service in a library. We use a set of guidelines from a design science perspective to organize the description and analysis of the case study. By doing this we demonstrate the usefulness of design science as an analytical tool for understanding related design...

  16. Recovering recyclable materials from shredder residue

    Science.gov (United States)

    Jody, Bassam J.; Daniels, Edward J.; Bonsignore, Patrick V.; Brockmeier, Norman F.

    1994-02-01

    Each year, about 11 million tons of metals are recovered in the United States from about 10 million discarded automobiles. The recovered metals account for about 75 percent of the total weight of the discarded vehicles. The balance of the material, known as shredder residue, amounts to about three million tons annually and is currently landfilled. The residue contains a diversity of potentially recyclable materials, including polyurethane foams, iron oxides, and certain thermoplastics. This article discusses a process under development at Argonne National Laboratory to separate and recover the recyclable materials from this waste stream. The process consists essentially of two stages. First, a physical separation is used to recover the foams and the metal oxides, followed by a chemical process to extract certain thermoplastics. The status of the technology and the process economics are reviewed here.

  17. Physicochemical and functional characteristics of residual pulp of potato

    Directory of Open Access Journals (Sweden)

    Webber Tavares de CARVALHO

    Full Text Available Abstract Starch-rich liquid effluent is generated after peeling, cutting and washing of tubers during the fries processing. After sedimentation of this effluent is recovered a wet residual pulp, and after drying is obtained dry residual pulp or simply named in this study residual pulp of potato (RPP. In order to convert the effluent into a material easy to store for long periods (such as the potato starch, which would make it suitable for various applications. The aim of this study was to evaluate the effect of the drying conditions, specifically variables temperature and air flow on the drying time and water activity, pH, titratable acidity, instrumental colour parameters, water absorption index, water solubility index and oil absorption capacity of dry RPP. Central Composite Design was used, with temperature levels from 50.0 to 70.0 °C and air flow from 0.06 to 0.092 m3 m–2 s–1. Temperature and airflow affected the study characteristics, except for lightness (L*, water solubility index and oil absorption capacity. It was concluded that milder conditions (lower temperatures and intermediate air flow resulted in higher-quality final products (lighter, less acidic, although requiring higher drying time. Therefore, depending on the product application, different drying conditions can be used.

  18. Sustainable Chemical Processes and Products. New Design Methodology and Design Tools

    OpenAIRE

    Korevaar, G.

    2004-01-01

    The current chemical industry is not sustainable, which leads to the fact that innovation of chemical processes and products is too often hazardous for society in general and the environment in particular. It really is a challenge to implement sustainability considerations in the design activities of chemical engineers. Therefore, the main question of this thesis is: how can a trained chemical engineer develop a conceptual design of a chemical process or a chemical product in such a way that ...

  19. Defining process design space for monoclonal antibody cell culture.

    Science.gov (United States)

    Abu-Absi, Susan Fugett; Yang, LiYing; Thompson, Patrick; Jiang, Canping; Kandula, Sunitha; Schilling, Bernhard; Shukla, Abhinav A

    2010-08-15

    The concept of design space has been taking root as a foundation of in-process control strategies for biopharmaceutical manufacturing processes. During mapping of the process design space, the multidimensional combination of operational variables is studied to quantify the impact on process performance in terms of productivity and product quality. An efficient methodology to map the design space for a monoclonal antibody cell culture process is described. A failure modes and effects analysis (FMEA) was used as the basis for the process characterization exercise. This was followed by an integrated study of the inoculum stage of the process which includes progressive shake flask and seed bioreactor steps. The operating conditions for the seed bioreactor were studied in an integrated fashion with the production bioreactor using a two stage design of experiments (DOE) methodology to enable optimization of operating conditions. A two level Resolution IV design was followed by a central composite design (CCD). These experiments enabled identification of the edge of failure and classification of the operational parameters as non-key, key or critical. In addition, the models generated from the data provide further insight into balancing productivity of the cell culture process with product quality considerations. Finally, process and product-related impurity clearance was evaluated by studies linking the upstream process with downstream purification. Production bioreactor parameters that directly influence antibody charge variants and glycosylation in CHO systems were identified.

  20. THORP - the management of the design process

    International Nuclear Information System (INIS)

    Thorpe, E.; Thurrell, B.H.; Varey, L.S.

    1991-01-01

    This Paper sets out to describe the organization of the design of the Thermal Oxide Reprocessing Plant (THORP) head end and chemical separation building. This posed many challenges not only because the building itself is a complicated engineering entity, but also because of the logistical aspects of administering the large number of engineers and draughtsmen -600 in total at peak- employed on the project. The effects of the necessary iterative design process, both technical and logistical, are outlined, together with a description of the manner in which the whole design process was managed. (author)

  1. Mapping and quantification of organic agro-industrial residues in East Africa

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G. [Dansk Teknologisk Inst. (Denmark); Kivaisi, A.; Rubindamayugi, M. [Univ. of Dar es Salaam (Tanzania, United Republic of)

    1998-05-01

    The East-African agro-industries generate very large quantities of organic residues from production and processing of different crops. These residues form a major contribution to the pollution of air, soil and water ways, but, at the same time they constitute a large potential for production of bioenergy through anaerobic digestion as well as potential substrate for other biological fermentation processes. The utilization of these resources for production of valuable products would contribute significantly to: Improvement of the local energy supply, through production of bio-energy; Improvement of the economy of the East African agro-industry; Reduction of the environmental impact from the agro-industrial sector. Except for production of cane sugar, most agro-industrial residues are generated from cash crops, which are produced and processed in the developing countries and where the final products mainly are used for export. In the East-African Region the most important of these crops are: Sisal, coffee, Cashew nuts and Pineapple. In addition significant quantities of organic residues are generated from other food processing activities like breweries, consumption of bananas etc. The total potential methane production of the residues available for use in biomethanization systems in East Africa is 189.61 million m{sup 3} of methane per year. Converted to diesel oil equivalents and including the residues only feasible for combustion systems, the total bioenergy potential of agro-industrial residues in Eastern Africa is 279,176 TOE. If this potential was fully utilized for production of electricity, it would correspond to installed effects of 37,68 and 31 MW in Tanzania, Kenya and Uganda, respectively, equivalent to 10%, 11% and 18% of the currently installed effect is these countries. Residues from sisal and coffee processing constitute the main part of the bioenergy potential, on average approximately 75%, while the remaining 25% of the potential are formed by the

  2. Cost of the radioactive residues of nuclear power

    International Nuclear Information System (INIS)

    1986-06-01

    The calculation of cost for the management and final storage of spent nuclear fuel and radioactive waste is presented. The continuing Research and Development activities are judged to render simplified designs. The existing and planned systems and and plans are as follows: - transport system for radioactive residues - central intermediate storage of spent fuel, CLAB - processing of spent fuel - final storing of long-lived waste - final storing of reactor waste and decommissioning waste, SFR. The total future cost of the Swedish waste management is calculated to be 39 billion SEK from 1987 and 60 years onwards. 5.3 billion SEK have been spent up to the year 1986. (G.B.)

  3. An evaluation of preservation of residual hearing using the suprameatal approach for cochlear implantation: can this implantation technique be used for preservation of residual hearing?

    NARCIS (Netherlands)

    Postelmans, Job T. F.; van Spronsen, Erik; Grolman, Wilko; Stokroos, Robert J.; Tange, Rinze A.; Maré, Marcel J.; Dreschler, Wouter A.

    2011-01-01

    The preservation of residual hearing has become a high priority in cochlear implant surgery. This study was designed to substantiate whether conservation of residual hearing can be preserved after cochlear implantation using the suprameatal approach. Retrospective chart review. Retrospective chart

  4. Implementation of a digital optical matrix-vector multiplier using a holographic look-up table and residue arithmetic

    Science.gov (United States)

    Habiby, Sarry F.

    1987-01-01

    The design and implementation of a digital (numerical) optical matrix-vector multiplier are presented. The objective is to demonstrate the operation of an optical processor designed to minimize computation time in performing a practical computing application. This is done by using the large array of processing elements in a Hughes liquid crystal light valve, and relying on the residue arithmetic representation, a holographic optical memory, and position coded optical look-up tables. In the design, all operations are performed in effectively one light valve response time regardless of matrix size. The features of the design allowing fast computation include the residue arithmetic representation, the mapping approach to computation, and the holographic memory. In addition, other features of the work include a practical light valve configuration for efficient polarization control, a model for recording multiple exposures in silver halides with equal reconstruction efficiency, and using light from an optical fiber for a reference beam source in constructing the hologram. The design can be extended to implement larger matrix arrays without increasing computation time.

  5. The design of photoelectric signal processing system for a nuclear magnetic resonance gyroscope based on FPGA

    Science.gov (United States)

    Zhang, Xian; Zhou, Binquan; Li, Hong; Zhao, Xinghua; Mu, Weiwei; Wu, Wenfeng

    2017-10-01

    Navigation technology is crucial to the national defense and military, which can realize the measurement of orientation, positioning, attitude and speed for moving object. Inertial navigation is not only autonomous, real-time, continuous, hidden, undisturbed but also no time-limited and environment-limited. The gyroscope is the core component of the inertial navigation system, whose precision and size are the bottleneck of the performance. However, nuclear magnetic resonance gyroscope is characteristic of the advantage of high precision and small size. Nuclear magnetic resonance gyroscope can meet the urgent needs of high-tech weapons and equipment development of new generation. This paper mainly designs a set of photoelectric signal processing system for nuclear magnetic resonance gyroscope based on FPGA, which process and control the information of detecting laser .The photoelectric signal with high frequency carrier is demodulated by in-phase and quadrature demodulation method. Finally, the processing system of photoelectric signal can compensate the residual magnetism of the shielding barrel and provide the information of nuclear magnetic resonance gyroscope angular velocity.

  6. Analysis of the residual strain change of Bi2212, Ag alloy and Ag during the heating and cooling process in Bi2212/Ag/Ag alloy composite wire

    International Nuclear Information System (INIS)

    Shin, J K; Ochiai, S; Okuda, H; Mukai, Y; Sugano, M; Sato, M; Oh, S S; Ha, D W; Kim, S C

    2008-01-01

    The residual strain change of Bi2212 and Ag during the cooling and heating process in the Bi2212/Ag/Ag alloy composite superconductor was studied. First, the residual strain of Bi2212 filaments at room temperature was measured by the x-ray diffraction method. Then, the Young's moduli of the constituents (Bi2212 filaments, Ag and Ag alloy) and yield strains of Ag and Ag alloy were estimated from the analysis of the measured stress-strain curve, based on the rule of mixtures. Also, the coefficient of thermal expansion of the Bi2212 filaments was estimated from the analysis of the measured thermal expansion curve of the composite wire. From the modeling analysis using the estimated property values and the residual strain of Bi2212 filaments, the changes of residual strain of Bi2212, Ag alloy and Ag with temperature during the cooling and heating process were revealed

  7. Transfer shuttle for vitrified residue canisters control of risks associated with external exposure and heat release

    Energy Technology Data Exchange (ETDEWEB)

    BIndel, L.; Gamess, A.; Lejeune, E.; Cellier, P.; Maillard, A. [SGN Reseau Eurisys, 78 - Saint Quentin (France)

    1998-07-01

    In the La Hague COGEMA's plant area, nuclear residue isolated by reprocessing are transported by means of specific transfer shuttles between the different processing and/or conditioning facilities and the storage ones. These shuttles are designed by reference to the applicable dose equivalent rate (DER) limits for transport on the site and the thermal behavior limitations of certain mechanical components which guarantee the containment of the transported waste. This paper describes and example of a study conducted on a transfer shuttle for vitrified residue canisters. Concerning the control of risks associated with external exposure and with heat releases, these were handled by the 'Shielding-Criticality-Dispersion' and 'process Modelling and Simulation' Sections of the Technical Division of SGN. The dose profiles around the shuttle, as a function of the shielding heterogeneities and possible radiation leakage, as well as the thermal fields within the shuttle, were calculated using 3D models. These design studies ultimately helped to select and validate the optimal solutions. (authors)

  8. Thermal treatment system of hazardous residuals in three heating zones based on a microprocessor

    International Nuclear Information System (INIS)

    Luna H, C.L.

    1997-01-01

    Thermal treatment system consists of a high power electric oven of three heating zones where each zone works up to 1200 Centigrades; it has the capacity of rising the central zone temperature up to 1000 Centigrades in 58 minutes approximately. This configuration of three zones could be programmed to different temperatures and they will be digitally controlled by a control microprocessor, which has been controlled by its own assembler language, in function of the PID control. There are also other important controls based on this microprocessor, as a signal amplification, starting and shutdown of high power step relays, activation and deactivation of both analogic/digital and digital/analogic convertors, port activation and basic data storage of the system. Two main characteristics were looked for this oven design; the first was the possibility of controlling the three zone temperature and the second was to reduce the rising and stabilization operation time and its digitized control. The principal function of the three zone oven is to accelerate the degradation of hazardous residuals by an oxidation instead combustion, through relatively high temperatures (minimum 800 Centigrades and maximum 1200 Centigrades); this process reduces the ash and volatile particulate production. The hazardous residuals will be pumped into the degradation system and after atomized through a packaged column; this step will avoid the direct contact of the residuals with the oven cores. These features make this system as closed process, which means that the residuals can not leak to the working area, reducing the exposure risk to the personnel. This three step oven system is the first stage of the complete hazardous residuals degradation system; after this, the flow will go into a cold plasma region where the process is completed, making a closed system. (Author)

  9. Biodiesel of distilled hydrogenated fat and biodiesel of distilled residual oil: fuel consumption in agricultural tractor

    Energy Technology Data Exchange (ETDEWEB)

    Camara, Felipe Thomaz da; Lopes, Afonso; Silva, Rouverson Pereira da; Oliveira, Melina Cais Jejcic; Furlani, Carlos Eduardo Angeli [Universidade Estadual Paulista (UNESP), Jaboticabal, SP (Brazil); Dabdoub, Miguel Joaquim [Universidade de Sao Paulo (USP), Ribeirao Preto (Brazil)

    2008-07-01

    Great part of the world-wide oil production is used in fry process; however, after using, such product becomes an undesirable residue, and the usual methods of discarding of these residues, generally contaminate the environment, mainly the rivers. In function of this, using oil and residual fat for manufacturing biodiesel, besides preventing ambient contamination, turning up an undesirable residue in to fuel. The present work had as objective to evaluate the fuel consumption of a Valtra BM100 4x2 TDA tractor functioning with methylic biodiesel from distilled hydrogenated fat and methylic biodiesel from distilled residual oil, in seven blends into diesel. The work was conducted at the Department of Agricultural Engineering, at UNESP - Jaboticabal, in an entirely randomized block statistical design, factorial array of 2 x 7, with three repetitions. The factors combinations were two types of methylic distilled biodiesel (residual oil and hydrogenated fat) and seven blends (B{sub 0}, B{sub 5}, B{sub 1}5, B{sub 2}5, B{sub 5}0, B{sub 7}5 and B{sub 1}00). The results had evidenced that additioning 15% of biodiesel into diesel, the specific consumption was similar, and biodiesel of residual oil provided less consumption than biodiesel from hydrogenated fat. (author)

  10. [Application of quality by design in granulation process for Ginkgo leaf tablet (Ⅲ): process control strategy based on design space].

    Science.gov (United States)

    Cui, Xiang-Long; Xu, Bing; Sun, Fei; Dai, Sheng-Yun; Shi, Xin-Yuan; Qiao, Yan-Jiang

    2017-03-01

    In this paper, under the guidance of quality by design (QbD) concept, the control strategy of the high shear wet granulation process of the ginkgo leaf tablet based on the design space was established to improve the process controllability and product quality consistency. The median granule size (D50) and bulk density (Da) of granules were identified as critical quality attributes (CQAs) and potential critical process parameters (pCPPs) were determined by the failure modes and effect analysis (FMEA). The Plackeet-Burmann experimental design was used to screen pCPPs and the results demonstrated that the binder amount, the wet massing time and the wet mixing impeller speed were critical process parameters (CPPs). The design space of the high shear wet granulation process was developed within pCPPs range based on the Box-Behnken design and quadratic polynomial regression models. ANOVA analysis showed that the P-values of model were less than 0.05 and the values of lack of fit test were more than 0.1, indicating that the relationship between CQAs and CPPs could be well described by the mathematical models. D₅₀ could be controlled within 170 to 500 μm, and the bulk density could be controlled within 0.30 to 0.44 g•cm⁻³ by using any CPPs combination within the scope of design space. Besides, granules produced by process parameters within the design space region could also meet the requirement of tensile strength of the ginkgo leaf tablet.. Copyright© by the Chinese Pharmaceutical Association.

  11. Integrated Process Design and Control of Reactive Distillation Processes

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil; Sales-Cruz, Mauricio; Huusom, Jakob Kjøbsted

    2015-01-01

    on the element concept, which is used to translate a system of compounds into elements. The operation of the reactive distillation column at the highest driving force and other candidate points is analyzed through analytical solution as well as rigorous open-loop and closed-loop simulations. By application...... of this approach, it is shown that designing the reactive distillation process at the maximum driving force results in an optimal design in terms of controllability and operability. It is verified that the reactive distillation design option is less sensitive to the disturbances in the feed at the highest driving...

  12. Air temperature determination inside residual heat removal pump room of Angra-1 nuclear power plant after a design basic accident

    International Nuclear Information System (INIS)

    Siniscalchi, Marcio Rezende

    2005-01-01

    This work develops heat transfer theoretical models for determination of air temperature inside the Residual Heat Removal Pump Room of Angra 1 Nuclear Power Plant after a Design Basis Accident without forced ventilation. Two models had been developed. The differential equations are solved by analytical methods. A software in FORTRAN language are developed for simulations of temperature inside rooms for different geometries and materials. (author)

  13. A Design Support Framework through Dynamic Deployment of Hypothesis and Verification in the Design Process

    Science.gov (United States)

    Nomaguch, Yutaka; Fujita, Kikuo

    This paper proposes a design support framework, named DRIFT (Design Rationale Integration Framework of Three layers), which dynamically captures and manages hypothesis and verification in the design process. A core of DRIFT is a three-layered design process model of action, model operation and argumentation. This model integrates various design support tools and captures design operations performed on them. Action level captures the sequence of design operations. Model operation level captures the transition of design states, which records a design snapshot over design tools. Argumentation level captures the process of setting problems and alternatives. The linkage of three levels enables to automatically and efficiently capture and manage iterative hypothesis and verification processes through design operations over design tools. In DRIFT, such a linkage is extracted through the templates of design operations, which are extracted from the patterns embeded in design tools such as Design-For-X (DFX) approaches, and design tools are integrated through ontology-based representation of design concepts. An argumentation model, gIBIS (graphical Issue-Based Information System), is used for representing dependencies among problems and alternatives. A mechanism of TMS (Truth Maintenance System) is used for managing multiple hypothetical design stages. This paper also demonstrates a prototype implementation of DRIFT and its application to a simple design problem. Further, it is concluded with discussion of some future issues.

  14. Fluidised-bed combustion of gasification residue

    Energy Technology Data Exchange (ETDEWEB)

    Korpela, T.; Kudjoi, A.; Hippinen, I.; Heinolainen, A.; Suominen, M.; Lu Yong [Helsinki Univ. of Technology (Finland). Lab of Energy Economics and Power Plant Engineering

    1996-12-01

    Partial gasification processes have been presented as possibilities for future power production. In the processes, the solid materials removed from a gasifier (i.e. fly ash and bed material) contain unburnt fuel and the fuel conversion is increased by burning this gasification residue either in an atmospheric or a pressurised fluidised-bed. In this project, which is a part of European JOULE 2 EXTENSION research programme, the main research objectives are the behaviour of calcium and sulphur compounds in solids and the emissions of sulphur dioxide and nitrogen oxides (NO{sub x} and N{sub 2}O) in pressurised fluidised-bed combustion of gasification residues. (author)

  15. European experience in transport/storage cask for vitrified residues

    International Nuclear Information System (INIS)

    Otton, Camille; Sicard, Damien

    2007-01-01

    Available in abstract form only. Full text of publication follows: Because of the evolution of burnup of spent fuel to be reprocessed, the high activity vitrified residues would not be transported in the existing cask designs. Therefore, TN International has decided in the late nineties to develop a brand new design of casks with optimized capacity able to store and transport the most active and hottest canisters: the TN TM 81 casks currently in use in Switzerland and the TN TM 85 cask which shall permit in the near future in Germany the storage and the transport of the most active vitrified residues defining a thermal power of 56 kW (kilowatts). The challenges for the TN TM 81 and TN TM 85 cask designs were that the geometry entry data were very restrictive and were combined with a fairly wide range set by the AREVA NC Specification relative to vitrified residue canister. The TN TM 81 and the TN TM 85 casks have been designed to fully anticipate shipment constraints of the present vitrified residue production. It also used the feedback of current shipments and the operational constraints and experience of receiving and shipping facilities. The casks had to fit as much as possible in the existing procedures for the already existing flasks such as the TN TM 28 cask and TS 28 V cask, all along the logistics chain of loading, unloading, transport and maintenance. (authors)

  16. Study of residual stresses generated in P91 pipe steel welded by MCAW / FCAW processes; Estudo das tensoes residuais geradas na soldagem de tubulacao de aco P91 pelos processos MCAW/FCAW

    Energy Technology Data Exchange (ETDEWEB)

    Chuvas, Tatiane C.; Pardal, Juan M.; Garcia, Pedro P.; Souza, Guttemberg C. de; Fonseca, Maria P. Cindra, E-mail: chuvas@vm.uff.br [Universidade Federal Fluminense (PGMEC/UFF), Niteroi, RJ (Brazil). Departamento de Engenharia Mecanica; Cardote, Ismael [UTC Engenharia S/A, Niteroi, Rio de Janeiro, RJ (Brazil)

    2014-07-01

    The welding is one of the main industrial manufacturing processes structures and piping, knowledge of residual stress from this process is of paramount importance because the mechanical properties of welded components are not only determined by the microstructures present in the joint, but also by residual stresses heterogeneous introduced by thermal cycling during the process. The aim of this work is the characterization ASTM P91 joints welded by MCAW / FCAW (Metal Cored Arc Welding / Flux Cored Arc Welding) processes through the residual stresses evaluating associated with welding and post-weld heat treatments. Residual stresses were measured using X-rays diffraction sin2psi method, with Crκα radiation and they presented tensile at the root joints with larger magnitudes in the weld metal region and compressive on the surface. The post weld heat treatment resulted relief of residual stresses at the root of the joints. However, the same effect was observed in compressive surface stresses, which could adversely affect the service life of the pipe, reducing the fatigue and stress corrosion cracking resistances. (author)

  17. Designing a Process for Tracking Business Model Change

    DEFF Research Database (Denmark)

    Groskovs, Sergejs

    The paper has adopted a design science research approach to design and verify with key stakeholders a fundamental management process of revising KPIs (key performance indicators), including those indicators that are related to business model change. The paper proposes a general guide for such pro......The paper has adopted a design science research approach to design and verify with key stakeholders a fundamental management process of revising KPIs (key performance indicators), including those indicators that are related to business model change. The paper proposes a general guide...... for such process design, which is applicable in similar settings, i.e. other multi-subsidiary global firms operating in dynamic industries. The management of the focal case uses a set of KPIs to track performance and thus to allow for bringing about strategic and tactical changes, including the initiatives...... by establishing new KPIs on an ongoing basis together with the business units on the ground, and is thus of key importance to strategic management of the firm. The paper concludes with a discussion of its methodological compliance to design science research guidelines and revisits the literature in process...

  18. The importance of understanding process holdup. A Department of Energy (DOE) view

    International Nuclear Information System (INIS)

    Hammond, G.A.; Hawkins, R.L.

    1988-01-01

    Residual material in processing equipment is today and will in the future continue to be one of the major problems in controlling and accounting for nuclear material. Existing facilities were designed for product quantity, quality, and safety; not for minimization and quantification of residual material in process. With the development of measurement systems, and with enhanced material control and accounting practices and procedures, inventory differences have been emphasized. The improvement in processing input and output measurements has highlighted the problems of quantifying residual process material. The primary purpose for quantifying material held up in process is to determine the inventory difference and its related uncertainties or statistical variances. This qualification and its associated problems must be addressed if we are to prevent, deter, and detect theft and/or diversion of nuclear materials

  19. Group Contribution Based Process Flowsheet Synthesis, Design and Modelling

    DEFF Research Database (Denmark)

    d'Anterroches, Loïc; Gani, Rafiqul

    2004-01-01

    This paper presents a process-group-contribution Method to model. simulate and synthesize a flowsheet. The process-group based representation of a flowsheet together with a process "property" model are presented. The process-group based synthesis method is developed on the basis of the computer...... aided molecular design methods and gives the ability to screen numerous process alternatives without the need to use the rigorous process simulation models. The process "property" model calculates the design targets for the generated flowsheet alternatives while a reverse modelling method (also...... developed) determines the design variables matching the target. A simple illustrative example highlighting the main features of the methodology is also presented....

  20. Forging And Milling Contribution On Residual Stresses For A Textured Biphasic Titanium Alloy

    International Nuclear Information System (INIS)

    Deleuze, C.; Fabre, A.; Barrallier, L.; Molinas, O.

    2011-01-01

    Ti-10V-2Fe-3Al is a biphasic titanium alloy (α+β) used in aeronautical applications for its mechanical properties, such as its yield strength of 1200 MPa and it weighs 40% less than steel. This alloy is particularly useful for vital parts with complex geometry, because of its high forging capability. In order to predict the capability for fatigue lifetime, the designers need to know the residual stresses. X-Ray diffraction is the main experimental technique used to determine residual stresses on the surface. In this case, stress levels are primarily influenced by the complex forging and milling process. On this alloy in particular, it may be difficult to characterize stress due to modification of the microstructure close to the surface. Results obtained by x-ray analysis depend on the correct definition of the shape of the diffraction peaks. The more precisely defined the position of the peak, the more accurately the stresses are evaluated. This paper presents a method to detect if residual stresses can be characterized by x-ray diffraction. The characterization of hardness seems to be a relevant technique to quickly analyze the capability of x-ray diffraction to determine residual stresses.

  1. Pyrolysis kinetics and thermodynamic parameters of castor (Ricinus communis) residue using thermogravimetric analysis.

    Science.gov (United States)

    Kaur, Ravneet; Gera, Poonam; Jha, Mithilesh Kumar; Bhaskar, Thallada

    2018-02-01

    Castor plant is a fast-growing, perennial shrub from Euphorbiaceae family. More than 50% of the residue is generated from its stems and leaves. The main aim of this work is to study the pyrolytic characteristics, kinetics and thermodynamic properties of castor residue. The TGA experiments were carried out from room temperature to 900 °C under an inert atmosphere at different heating rates of 5, 10, 15, 20, 30 and 40 °C/min. The kinetic analysis was carried using different models namely Kissinger, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS). The average E ɑ calculated by FWO and KAS methods were 167.10 and 165.86 kJ/mole respectively. Gibbs free energy varied from 150.62-154.33 to 150.59-154.65 kJ/mol for FWO and KAS respectively. The HHV of castor residue was 14.43 MJ/kg, considered as potential feedstock for bio-energy production. Kinetic and thermodynamic results will be useful input for the design of pyrolytic process using castor residue as feedstock. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. The effect of delignification process with alkaline peroxide on lactic acid production from furfural residues

    Directory of Open Access Journals (Sweden)

    Yong Tang

    2012-11-01

    Full Text Available Furfural residues produced from the furfural industry were investigated as a substrate for lactic acid production by simultaneous saccharification and fermentation (SSF. Alkaline peroxide was used for delignification of furfural residues to improve the final lactic acid concentration. The residue was treated with 1.3% to 1.7% hydrogen peroxide at 80 °C for 1 h with a substrate concentration of 3.33%. SSF of furfural residues with different delignification degrees were carried out to evaluate the effect of delignification degree on lactic acid production. Using corn hydrolysates/ furfural residues as substrates, SSF with different media were carried out to investigate the effect of lignin on the interaction between enzymes and lactic acid bacteria. Lactic acid bacteria had a negative effect on cellulase, thus resulting in the reduction of enzyme activity. Lignin and nutrients slowed down the decreasing trend of enzyme activity. A higher delignification resulted in a slower fermentation rate and lower yield due to degradation products of lignin and the effect of lignin on the interaction between enzymes and lactic acid bacteria. For the purpose of lactic acid production, a moderate delignification (furfural residues with the lignin content of 14.8% was optimum.

  3. Manufacturing process design for multi commodities in agriculture

    Science.gov (United States)

    Prasetyawan, Yudha; Santosa, Andrian Henry

    2017-06-01

    High-potential commodities within particular agricultural sectors should be accompanied by maximum benefit value that can be attained by both local farmers and business players. In several cases, the business players are small-medium enterprises (SMEs) which have limited resources to perform added value process of the local commodities into the potential products. The weaknesses of SMEs such as the manual production process with low productivity, limited capacity to maintain prices, and unattractive packaging due to conventional production. Agricultural commodity is commonly created into several products such as flour, chips, crackers, oil, juice, and other products. This research was initiated by collecting data by interview method particularly to obtain the perspectives of SMEs as the business players. Subsequently, the information was processed based on the Quality Function Deployment (QFD) to determine House of Quality from the first to fourth level. A proposed design as the result of QFD was produced and evaluated with Technology Assessment Model (TAM) and continued with a revised design. Finally, the revised design was analyzed with financial perspective to obtain the cost structure of investment, operational, maintenance, and workers. The machine that performs manufacturing process, as the result of revised design, was prototyped and tested to determined initial production process. The designed manufacturing process offers IDR 337,897, 651 of Net Present Value (NPV) in comparison with the existing process value of IDR 9,491,522 based on similar production input.

  4. Reactor and process design in sustainable energy technology

    CERN Document Server

    Shi, Fan

    2014-01-01

    Reactor Process Design in Sustainable Energy Technology compiles and explains current developments in reactor and process design in sustainable energy technologies, including optimization and scale-up methodologies and numerical methods. Sustainable energy technologies that require more efficient means of converting and utilizing energy can help provide for burgeoning global energy demand while reducing anthropogenic carbon dioxide emissions associated with energy production. The book, contributed by an international team of academic and industry experts in the field, brings numerous reactor design cases to readers based on their valuable experience from lab R&D scale to industry levels. It is the first to emphasize reactor engineering in sustainable energy technology discussing design. It provides comprehensive tools and information to help engineers and energy professionals learn, design, and specify chemical reactors and processes confidently. Emphasis on reactor engineering in sustainable energy techn...

  5. Identification of residue pairing in interacting β-strands from a predicted residue contact map.

    Science.gov (United States)

    Mao, Wenzhi; Wang, Tong; Zhang, Wenxuan; Gong, Haipeng

    2018-04-19

    Despite the rapid progress of protein residue contact prediction, predicted residue contact maps frequently contain many errors. However, information of residue pairing in β strands could be extracted from a noisy contact map, due to the presence of characteristic contact patterns in β-β interactions. This information may benefit the tertiary structure prediction of mainly β proteins. In this work, we propose a novel ridge-detection-based β-β contact predictor to identify residue pairing in β strands from any predicted residue contact map. Our algorithm RDb 2 C adopts ridge detection, a well-developed technique in computer image processing, to capture consecutive residue contacts, and then utilizes a novel multi-stage random forest framework to integrate the ridge information and additional features for prediction. Starting from the predicted contact map of CCMpred, RDb 2 C remarkably outperforms all state-of-the-art methods on two conventional test sets of β proteins (BetaSheet916 and BetaSheet1452), and achieves F1-scores of ~ 62% and ~ 76% at the residue level and strand level, respectively. Taking the prediction of the more advanced RaptorX-Contact as input, RDb 2 C achieves impressively higher performance, with F1-scores reaching ~ 76% and ~ 86% at the residue level and strand level, respectively. In a test of structural modeling using the top 1 L predicted contacts as constraints, for 61 mainly β proteins, the average TM-score achieves 0.442 when using the raw RaptorX-Contact prediction, but increases to 0.506 when using the improved prediction by RDb 2 C. Our method can significantly improve the prediction of β-β contacts from any predicted residue contact maps. Prediction results of our algorithm could be directly applied to effectively facilitate the practical structure prediction of mainly β proteins. All source data and codes are available at http://166.111.152.91/Downloads.html or the GitHub address of https://github.com/wzmao/RDb2C .

  6. Property Modelling and Databases in Product-Process Design

    DEFF Research Database (Denmark)

    Gani, Rafiqul; Sansonetti, Sascha

    of the PC-SAFT is used. The developed database and property prediction models have been combined into a properties-software that allows different product-process design related applications. The presentation will also briefly highlight applications of the software for virtual product-process design...

  7. Influence of Different Container Closure Systems and Capping Process Parameters on Product Quality and Container Closure Integrity (CCI) in GMP Drug Product Manufacturing.

    Science.gov (United States)

    Mathaes, Roman; Mahler, Hanns-Christian; Roggo, Yves; Huwyler, Joerg; Eder, Juergen; Fritsch, Kamila; Posset, Tobias; Mohl, Silke; Streubel, Alexander

    2016-01-01

    Capping equipment used in good manufacturing practice manufacturing features different designs and a variety of adjustable process parameters. The overall capping result is a complex interplay of the different capping process parameters and is insufficiently described in literature. It remains poorly studied how the different capping equipment designs and capping equipment process parameters (e.g., pre-compression force, capping plate height, turntable rotating speed) contribute to the final residual seal force of a sealed container closure system and its relation to container closure integrity and other drug product quality parameters. Stopper compression measured by computer tomography correlated to residual seal force measurements.In our studies, we used different container closure system configurations from different good manufacturing practice drug product fill & finish facilities to investigate the influence of differences in primary packaging, that is, vial size and rubber stopper design on the capping process and the capped drug product. In addition, we compared two large-scale good manufacturing practice manufacturing capping equipment and different capping equipment settings and their impact on product quality and integrity, as determined by residual seal force.The capping plate to plunger distance had a major influence on the obtained residual seal force values of a sealed vial, whereas the capping pre-compression force and the turntable rotation speed showed only a minor influence on the residual seal force of a sealed vial. Capping process parameters could not easily be transferred from capping equipment of different manufacturers. However, the residual seal force tester did provide a valuable tool to compare capping performance of different capping equipment. No vial showed any leakage greater than 10(-8)mbar L/s as measured by a helium mass spectrometry system, suggesting that container closure integrity was warranted in the residual seal force range

  8. Finite element modelling of shot peening process: Prediction of the compressive residual stresses, the plastic deformations and the surface integrity

    International Nuclear Information System (INIS)

    Frija, M.; Hassine, T.; Fathallah, R.; Bouraoui, C.; Dogui, A.

    2006-01-01

    This paper presents a numerical simulation of the shot peening process using finite element method. The majority of the controlling parameters of the process have been taken into account. The shot peening loading has been characterised by using energy equivalence between the dynamic impact and a static indentation of a peening shot in the treated surface. The behaviour of the subjected material is supposed to be elastic plastic with damage. An integrated law of the damage proposed by Lemaitre and Chaboche has been used. The proposed model leads to obtain the residual stress, the plastic deformation profiles and the surface damage. An application on a shot peened Ni-based super alloy Waspaloy has been carried out. The comparison of the residual stresses, obtained by X-ray diffraction method and by finite element calculation, shows a good correlation. The in-depth profile of the plastic deformations and the superficial damage values are in good agreement with the experimental observations

  9. A manual for implementing residual radioactive material guidelines

    International Nuclear Information System (INIS)

    Gilbert, T.L.; Yu, C.; Yuan, Y.C.; Zielen, A.J.; Jusko, M.J.; Wallo, A. III; Argonne National Lab., IL; Dames and Moore, West Valley, NY; Argonne National Lab., IL; USDOE Assistant Secretary for Nuclear Energy, Washington, DC

    1989-06-01

    This manual presents information for implementing US Department of Energy (DOE) guidelines for residual radioactive material at sites identified by the Formerly Utilized Sites Remedial Action Program (FUSRAP) and the Surplus Facilities Management Program (SFMP). It describes the analysis and models used to derive site-specific guidelines for allowable residual concentrations of radionuclides in soil and the design and use of the RESRAD computer code for calculating guideline values. It also describes procedures for implementing DOE policy for reducing residual radioactivity to levels that are as low as reasonably achievable. 36 refs., 16 figs, 22 tabs

  10. Induction Heating Process Design Using COMSOL Multiphysics Software

    Directory of Open Access Journals (Sweden)

    Andy Triwinarko

    2011-08-01

    Full Text Available Induction heating is clean environmental heating process due to a non-contact heating process. There is lots of the induction heating type that be used in the home appliance but it is still new technology in Indonesia. The main interesting area of the induction heating design is the efficiency of the usage of energy and choice of the plate material. COMSOL Multiphysics Software can be used to simulate and estimate the induction heating process. Therefore, the software can be used to design the induction heating process that will have a optimum efficiency. The properties of the induction heating design were also simulated and analyzed such as effect of inductors width, inductors distance, and conductive plate material. The result was shown that the good design of induction heating must have a short width and distance inductor and used silicon carbide as material plate with high frequency controller.

  11. Environmental dredging residual generation and management.

    Science.gov (United States)

    Patmont, Clay; LaRosa, Paul; Narayanan, Raghav; Forrest, Casey

    2018-05-01

    The presence and magnitude of sediment contamination remaining in a completed dredge area can often dictate the success of an environmental dredging project. The need to better understand and manage this remaining contamination, referred to as "postdredging residuals," has increasingly been recognized by practitioners and investigators. Based on recent dredging projects with robust characterization programs, it is now understood that the residual contamination layer in the postdredging sediment comprises a mixture of contaminated sediments that originate from throughout the dredge cut. This mixture of contaminated sediments initially exhibits fluid mud properties that can contribute to sediment transport and contamination risk outside of the dredge area. This article reviews robust dredging residual evaluations recently performed in the United States and Canada, including the Hudson River, Lower Fox River, Ashtabula River, and Esquimalt Harbour, along with other projects. These data better inform the understanding of residuals generation, leading to improved models of dredging residual formation to inform remedy evaluation, selection, design, and implementation. Data from these projects confirm that the magnitude of dredging residuals is largely determined by site conditions, primarily in situ sediment fluidity or liquidity as measured by dry bulk density. While the generation of dredging residuals cannot be avoided, residuals can be successfully and efficiently managed through careful development and implementation of site-specific management plans. Integr Environ Assess Manag 2018;14:335-343. © 2018 The Authors. Integrated Environmental Assessment and Management Published by Wiley Periodicals, Inc. on behalf of Society of Environmental Toxicology & Chemistry (SETAC). © 2018 The Authors. Integrated Environmental Assessment and Management Published by Wiley Periodicals, Inc. on behalf of Society of Environmental Toxicology & Chemistry (SETAC).

  12. Quality-by-Design (QbD): An integrated process analytical technology (PAT) approach for a dynamic pharmaceutical co-precipitation process characterization and process design space development.

    Science.gov (United States)

    Wu, Huiquan; White, Maury; Khan, Mansoor A

    2011-02-28

    The aim of this work was to develop an integrated process analytical technology (PAT) approach for a dynamic pharmaceutical co-precipitation process characterization and design space development. A dynamic co-precipitation process by gradually introducing water to the ternary system of naproxen-Eudragit L100-alcohol was monitored at real-time in situ via Lasentec FBRM and PVM. 3D map of count-time-chord length revealed three distinguishable process stages: incubation, transition, and steady-state. The effects of high risk process variables (slurry temperature, stirring rate, and water addition rate) on both derived co-precipitation process rates and final chord-length-distribution were evaluated systematically using a 3(3) full factorial design. Critical process variables were identified via ANOVA for both transition and steady state. General linear models (GLM) were then used for parameter estimation for each critical variable. Clear trends about effects of each critical variable during transition and steady state were found by GLM and were interpreted using fundamental process principles and Nyvlt's transfer model. Neural network models were able to link process variables with response variables at transition and steady state with R(2) of 0.88-0.98. PVM images evidenced nucleation and crystal growth. Contour plots illustrated design space via critical process variables' ranges. It demonstrated the utility of integrated PAT approach for QbD development. Published by Elsevier B.V.

  13. Property Based Process and Product Synthesis and Design

    DEFF Research Database (Denmark)

    Eden, Mario Richard

    2003-01-01

    in terms of the constitutive (synthesis/design) variables instead of the process variables, thus providing the synthesis/design targets. The second reverse problem (reverse property prediction) solves the constitutive equations to identify unit operations, operating conditions and/or products by matching......This thesis describes the development of a general framework for solving process and product design problems. Targeting the desired performance of the system in a systematic manner relieves the iterative nature of conventional design techniques. Furthermore, conventional component based methods...... are not capable of handling problems, where the process or product objectives are driven by functionalities or properties rather than chemical constituency. The framework is meant to complement existing composition based methods by being able to handle property driven problems. By investigating the different...

  14. Stabilization of plutonium bearing residues at Lawrence Livermore National Laboratory

    International Nuclear Information System (INIS)

    Bronson, M.C.; Van Konynenburg, R.A.; Ebbinghaus, B.B.

    1995-01-01

    The US Department of Energy's (US DOE) Lawrence Livermore National Laboratory (LLNL) has plutonium holdings including metal, oxide and residue materials, all of which need stabilization of some type. Residue materials include calcined ash, calcined precipitates, pyrochemical salts, glove box sweepings, metallurgical samples, graphite, and pyrochemical ceramic crucibles. These residues are typical of residues stored throughout the US DOE plutonium sites. The stabilization process selected for each of these residues requires data on chemical impurities, physical attributes, and chemical forms of the plutonium. This paper outlines the characterization and stabilization of LLNL ash residues, pyrochemical salts, and graphite

  15. Optimal temperature profiles for minimum residual stress in the cure process of polymer composites

    CSIR Research Space (South Africa)

    Gopal, AK

    2000-01-01

    Full Text Available include the minimum residual stresses, minimum cure cycle lime and full degree of cure. The development of residual stresses during the cure cycle is one of the most important problems as they affect the strength and the mechanical properties of the final...

  16. Residue behaviour of six pesticides in button crimini during home canning.

    Science.gov (United States)

    Du, Pengqiang; Liu, Xingang; Gu, Xiaojun; Dong, Fengshou; Xu, Jun; Kong, Zhiqiang; Li, Yuanbo; Zheng, Yongquan

    2014-01-01

    The effect of home canning (including washing, boiling, cooling, adding solution and sterilisation) on residue levels of imidacloprid, diflubenzuron, abamectin, pyriproxyfen and β-cypermethrin and chlorothalonilin on button crimini was assessed. Residues of imidacloprid, diflubenzuron, abamectin and pyriproxyfen were measured by UPLC-MS/MS; the residues of β-cypermethrin and chlorothalonil were measured by GC. Results showed that washing resulted in a 3.8% reduction of the initial residue level of imidacloprid (p ≤ 0.05). From washing to sterilisation the processing effect was significant compared with raw crimini (p ≤ 0.05), but processing through cooling and adding solution had no effect. For diflubenzuron, from raw crimini to sterilisation the processing effect was significant by comparison with the initial level (p ≤ 0.05); the processing effect was not obvious between two sequential steps, and the sequential steps have list: washing and boiling, boiling and cooling, boiling and adding of solution, cooling and adding solution. The changes in abamectin levels were also significant from raw crimini to sterilisation compared with raw crimini (p ≤ 0.05), but the changes were not obvious from boiling to adding solution and amongst them. For pyriproxyfen, washing resulted in a 39% reduction, but changes were not obvious from washing to sterilisation, p ≤ 0.05 between two consecutive steps. The whole procedure could significantly decrease residues of β-cypermethrin (p ≤ 0.05); washing could significantly reduce residues of β-cypermethrin; the effects of last procedures were complicated, and p ≤ 0.05 between two consecutive steps. Washing resulted in an 80% reduction of chlorothalonil; after washing there were no detectable residues. After the whole process, the processing factors for imidacloprid, diflubenzuron, abamectin, pyriproxyfen, β-cypermethrin and chlorothalonil were 0.40, 0.22, 0.04, 0.85, 0.28 and 0, respectively.

  17. Study on Product Innovative Design Process Driven by Ideal Solution

    Science.gov (United States)

    Zhang, Fuying; Lu, Ximei; Wang, Ping; Liu, Hui

    Product innovative design in companies today relies heavily on individual members’ experience and creative ideation as well as their skills of integrating creativity and innovation tools with design methods agilely. Creative ideation and inventive ideas generation are two crucial stages in product innovative design process. Ideal solution is the desire final ideas for given problem, and the striving reaching target for product design. In this paper, a product innovative design process driven by ideal solution is proposed. This design process encourages designers to overcome their psychological inertia, to foster creativity in a systematic way for acquiring breakthrough creative and innovative solutions in a reducing sphere of solution-seeking, and results in effective product innovative design rapidly. A case study example is also presented to illustrate the effectiveness of the proposed design process.

  18. Shot-peening of carbonitrided steel: influence of the process on the mechanical state

    Directory of Open Access Journals (Sweden)

    François M.

    2010-06-01

    Full Text Available Residual stresses have a significant role in affecting engineering properties of materials and shot peening process is an effective production technique to ensure required residual stress levels. This paper presents an analysis of an orthogonal design of experiment to establish an empirical relationship between main parameters of shot peening process and residual stress profiles for a carbonitrided steel. The hardening / softening evolution of the material is followed using hardness and diffraction peak width. Four critical peening parameters, i.e. shot size, incident angle, exposure time, airblast pressure, have been chosen and the range of peening conditions are established by using the Taguchi technique. In this study, a shot velocity measurement system is used to obtain the on-line velocity during the peening process and the relationship between the maximum compressive residual stresses and the shot velocity is also developed. Analysis of the experimental data showed that it is possible to optimize the shot peening process by an effective control of process parameters.

  19. Accessibility through user-centred and Inclusive Design processes

    DEFF Research Database (Denmark)

    Herriott, Richard

    2014-01-01

    This PhD dissertation addresses the subject of accessibility through user-centred and Inclusive Design processes (ID). The project takes as its starting point the observation that the concept of Inclusive Design is not adequately delimited. The supporting literature in the field of ID is structured...... around the fact that the needs of individuals with reduced capabilities compared to the norm (referred to for convenience as "the elderly and disabled") have not been properly addressed by standard design processes. In response to this fact, ID is a proposed design method to find more effective means...

  20. Design and construction of a prototype for the continuous extraction of Sacha Inchi seed oil with a cold pressing process

    Directory of Open Access Journals (Sweden)

    Nelson Ramiro Gutiérrez Suquillo

    2017-03-01

    Full Text Available This work presents the design of an oil extractor from the Sacha Inchi seed with an extruder screw mechanism allows a maximum yield of 34% through a continuous cold extraction process at working temperatures below 45 ° C. The temperature is a critical parameter because when it exceeds 50 ° C, the oil decreases its nutritional value by the loss of its most important properties such as: Omega 3 (48%, Omega 6 (36%, Omega 9 (8%, digestibility (96%, vitamin A and E. The methodology used for the development of the work was the concurrent and simultaneous design according to the recommendations of National Instruments. The prototype consists of the extruder screw, pressure chamber, feed chamber, sieve and filter. The advantage of modular design is the flexibility it offers, so that when changing certain components it is possible to use the prototype to extract oil of different types and sizes of seeds. The products obtained from this mechanism are: 33.34% of oil and the solid residue known as Cake in 66.66% which has many applications in the field of human food and pets. Due to the processing of a food product, the requirements of ISO 22005 were applied for the design and implementation of the prototype.