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Sample records for reservoir thickness hydrate

  1. The Methane Hydrate Reservoir System

    Science.gov (United States)

    Flemings, P. B.; Liu, X.

    2007-12-01

    We use multi phase flow modeling and field examples (Hydrate Ridge, offshore Oregon and Blake Ridge, offshore North Carolina) to demonstrate that the methane hydrate reservoir system links traditional and non- traditional hydrocarbon system components: free gas flow is a fundamental control on this system. As in a traditional hydrocarbon reservoir, gas migrates into the hydrate reservoir as a separate phase (secondary migration) where it is trapped in a gas column beneath the base of the hydrate layer. With sufficient gas supply, buoyancy forces exceed either the capillary entry pressure of the cap rock or the fracture strength of the cap rock, and gas leaks into the hydrate stability zone, or cap rock. When gas enters the hydrate stability zone and forms hydrate, it becomes a very non traditional reservoir. Free gas forms hydrate, depletes water, and elevates salinity until pore water is too saline for further hydrate formation: salinity and hydrate concentration increase upwards from the base of the regional hydrate stability zone (RHSZ) to the seafloor and the base of the hydrate stability zone has significant topography. Gas chimneys couple the free gas zone to the seafloor through high salinity conduits that are maintained at the three-phase boundary by gas flow. As a result, significant amounts of gaseous methane can bypass the RHSZ, which implies a significantly smaller hydrate reservoir than previously envisioned. Hydrate within gas chimneys lie at the three-phase boundary and thus small increases in temperature or decreases in pressure can immediately transport methane into the ocean. This type of hydrate deposit may be the most economical for producing energy because it has very high methane concentrations (Sh > 70%) located near the seafloor, which lie on the three-phase boundary.

  2. Exploitation of subsea gas hydrate reservoirs

    Science.gov (United States)

    Janicki, Georg; Schlüter, Stefan; Hennig, Torsten; Deerberg, Görge

    2016-04-01

    Natural gas hydrates are considered to be a potential energy resource in the future. They occur in permafrost areas as well as in subsea sediments and are stable at high pressure and low temperature conditions. According to estimations the amount of carbon bonded in natural gas hydrates worldwide is two times larger than in all known conventional fossil fuels. Besides technical challenges that have to be overcome climate and safety issues have to be considered before a commercial exploitation of such unconventional reservoirs. The potential of producing natural gas from subsea gas hydrate deposits by various means (e.g. depressurization and/or injection of carbon dioxide) is numerically studied in the frame of the German research project »SUGAR«. The basic mechanisms of gas hydrate formation/dissociation and heat and mass transport in porous media are considered and implemented into a numerical model. The physics of the process leads to strong non-linear couplings between hydraulic fluid flow, hydrate dissociation and formation, hydraulic properties of the sediment, partial pressures and seawater solution of components and the thermal budget of the system described by the heat equation. This paper is intended to provide an overview of the recent development regarding the production of natural gas from subsea gas hydrate reservoirs. It aims at giving a broad insight into natural gas hydrates and covering relevant aspects of the exploitation process. It is focused on the thermodynamic principles and technological approaches for the exploitation. The effects occurring during natural gas production within hydrate filled sediment layers are identified and discussed by means of numerical simulation results. The behaviour of relevant process parameters such as pressure, temperature and phase saturations is described and compared for different strategies. The simulations are complemented by calculations for different safety relevant problems.

  3. Well testing in gas hydrate reservoirs

    OpenAIRE

    Kome, Melvin Njumbe

    2015-01-01

    Reservoir testing and analysis are fundamental tools in understanding reservoir hydraulics and hence forecasting reservoir responses. The quality of the analysis is very dependent on the conceptual model used in investigating the responses under different flowing conditions. The use of reservoir testing in the characterization and derivation of reservoir parameters is widely established, especially in conventional oil and gas reservoirs. However, with depleting conventional reserves, the ...

  4. Nuclear Well Log Properties of Natural Gas Hydrate Reservoirs

    Science.gov (United States)

    Burchwell, A.; Cook, A.

    2015-12-01

    Characterizing gas hydrate in a reservoir typically involves a full suite of geophysical well logs. The most common method involves using resistivity measurements to quantify the decrease in electrically conductive water when replaced with gas hydrate. Compressional velocity measurements are also used because the gas hydrate significantly strengthens the moduli of the sediment. At many gas hydrate sites, nuclear well logs, which include the photoelectric effect, formation sigma, carbon/oxygen ratio and neutron porosity, are also collected but often not used. In fact, the nuclear response of a gas hydrate reservoir is not known. In this research we will focus on the nuclear log response in gas hydrate reservoirs at the Mallik Field at the Mackenzie Delta, Northwest Territories, Canada, and the Gas Hydrate Joint Industry Project Leg 2 sites in the northern Gulf of Mexico. Nuclear logs may add increased robustness to the investigation into the properties of gas hydrates and some types of logs may offer an opportunity to distinguish between gas hydrate and permafrost. For example, a true formation sigma log measures the thermal neutron capture cross section of a formation and pore constituents; it is especially sensitive to hydrogen and chlorine in the pore space. Chlorine has a high absorption potential, and is used to determine the amount of saline water within pore spaces. Gas hydrate offers a difference in elemental composition compared to water-saturated intervals. Thus, in permafrost areas, the carbon/oxygen ratio may vary between gas hydrate and permafrost, due to the increase of carbon in gas hydrate accumulations. At the Mallik site, we observe a hydrate-bearing sand (1085-1107 m) above a water-bearing sand (1107-1140 m), which was confirmed through core samples and mud gas analysis. We observe a decrease in the photoelectric absorption of ~0.5 barnes/e-, as well as an increase in the formation sigma readings of ~5 capture units in the water-bearing sand as

  5. Sensitivity Analysis of Methane Hydrate Reservoirs: Effects of Reservoir Parameters on Gas Productivity and Economics

    Science.gov (United States)

    Anderson, B. J.; Gaddipati, M.; Nyayapathi, L.

    2008-12-01

    This paper presents a parametric study on production rates of natural gas from gas hydrates by the method of depressurization, using CMG STARS. Seven factors/parameters were considered as perturbations from a base-case hydrate reservoir description based on Problem 7 of the International Methane Hydrate Reservoir Simulator Code Comparison Study led by the Department of Energy and the USGS. This reservoir is modeled after the inferred properties of the hydrate deposit at the Prudhoe Bay L-106 site. The included sensitivity variables were hydrate saturation, pressure (depth), temperature, bottom-hole pressure of the production well, free water saturation, intrinsic rock permeability, and porosity. A two-level (L=2) Plackett-Burman experimental design was used to study the relative effects of these factors. The measured variable was the discounted cumulative gas production. The discount rate chosen was 15%, resulting in the gas contribution to the net present value of a reservoir. Eight different designs were developed for conducting sensitivity analysis and the effects of the parameters on the real and discounted production rates will be discussed. The breakeven price in various cases and the dependence of the breakeven price on the production parameters is given in the paper. As expected, initial reservoir temperature has the strongest positive effect on the productivity of a hydrate deposit and the bottom-hole pressure in the production well has the strongest negative dependence. Also resulting in a positive correlation is the intrinsic permeability and the initial free water of the formation. Negative effects were found for initial hydrate saturation (at saturations greater than 50% of the pore space) and the reservoir porosity. These negative effects are related to the available sensible heat of the reservoir, with decreasing productivity due to decreasing available sensible heat. Finally, we conclude that for the base case reservoir, the break-even price (BEP

  6. Production Characteristics of Oceanic Natural Gas Hydrate Reservoirs

    Science.gov (United States)

    Max, M. D.; Johnson, A. H.

    2014-12-01

    Oceanic natural gas hydrate (NGH) accumulations form when natural gas is trapped thermodynamically within the gas hydrate stability zone (GHSZ), which extends downward from the seafloor in open ocean depths greater than about 500 metres. As water depths increase, the thickness of the GHSZ thickens, but economic NGH deposits probably occur no deeper than 1 km below the seafloor. Natural gas (mostly methane) appears to emanate mostly from deeper sources and migrates into the GHSZ. The natural gas crystallizes as NGH when the pressure - temperature conditions within the GHSZ are reached and when the chemical condition of dissolved gas concentration in pore water is high enough to favor crystallization. Although NGH can form in both primary and secondary porosity, the principal economic target appears to be turbidite sands on deep continental margins. Because these are very similar to the hosts of more deeply buried conventional gas and oil deposits, industry knows how to explore for them. Recent improvements in a seismic geotechnical approach to NGH identification and valuation have been confirmed by drilling in the northern Gulf of Mexico and allow for widespread exploration for NGH deposits to begin. NGH concentrations occur in the same semi-consolidated sediments in GHSZs worldwide. This provides for a narrow exploration window with low acoustic attenuation. These sediments present the same range of relatively easy drilling conditions and formation pressures that are only slightly greater than at the seafloor and are essentially equalized by water in wellbores. Expensive conventional drilling equipment is not required. NGH is the only hydrocarbon that is stable at its formation pressures and incapable of converting to gas without artificial stimulation. We suggest that specialized, NGH-specific drilling capability will offer opportunities for much less expensive drilling, more complex wellbore layouts that improve reservoir connectivity and in which gas

  7. DOE THREE-DIMENSIONAL STRUCTURE AND PHYSICAL PROPERTIES OF A METHANE HYDRATE DEPOSIT AND GAS RESERVOIR, BLAKE RIDGE

    Energy Technology Data Exchange (ETDEWEB)

    W. Steven Holbrook

    2004-11-11

    This report contains a summary of work conducted and results produced under the auspices of award DE-FC26-00NT40921, ''DOE Three-Dimensional Structure and Physical Properties of a Methane Hydrate Deposit and Gas Reservoir, Blake Ridge.'' This award supported acquisition, processing, and interpretation of two- and three-dimensional seismic reflection data over a large methane hydrate reservoir on the Blake Ridge, offshore South Carolina. The work supported by this project has led to important new conclusions regarding (1) the use of seismic reflection data to directly detect methane hydrate, (2) the migration and possible escape of free gas through the hydrate stability zone, and (3) the mechanical controls on the maximum thickness of the free gas zone and gas escape.

  8. Reservoir controls on the occurrence and production of gas hydrates in nature

    Science.gov (United States)

    Collett, Timothy Scott

    2014-01-01

    Gas hydrates in both arctic permafrost regions and deep marine settings can occur at high concentrations in sand-dominated reservoirs, which have been the focus of gas hydrate exploration and production studies in

  9. CO2 Capture by Injection of Flue Gas or CO2-N2 Mixtures into Hydrate Reservoirs: Dependence of CO2 Capture Efficiency on Gas Hydrate Reservoir Conditions.

    Science.gov (United States)

    Hassanpouryouzband, Aliakbar; Yang, Jinhai; Tohidi, Bahman; Chuvilin, Evgeny; Istomin, Vladimir; Bukhanov, Boris; Cheremisin, Alexey

    2018-04-03

    Injection of flue gas or CO 2 -N 2 mixtures into gas hydrate reservoirs has been considered as a promising option for geological storage of CO 2 . However, the thermodynamic process in which the CO 2 present in flue gas or a CO 2 -N 2 mixture is captured as hydrate has not been well understood. In this work, a series of experiments were conducted to investigate the dependence of CO 2 capture efficiency on reservoir conditions. The CO 2 capture efficiency was investigated at different injection pressures from 2.6 to 23.8 MPa and hydrate reservoir temperatures from 273.2 to 283.2 K in the presence of two different saturations of methane hydrate. The results showed that more than 60% of the CO 2 in the flue gas was captured and stored as CO 2 hydrate or CO 2 -mixed hydrates, while methane-rich gas was produced. The efficiency of CO 2 capture depends on the reservoir conditions including temperature, pressure, and hydrate saturation. For a certain reservoir temperature, there is an optimum reservoir pressure at which the maximum amount of CO 2 can be captured from the injected flue gas or CO 2 -N 2 mixtures. This finding suggests that it is essential to control the injection pressure to enhance CO 2 capture efficiency by flue gas or CO 2 -N 2 mixtures injection.

  10. Gas hydrate saturations estimated from pore-and fracture-filling gas hydrate reservoirs in the Qilian Mountain permafrost, China.

    Science.gov (United States)

    Xiao, Kun; Zou, Changchun; Lu, Zhenquan; Deng, Juzhi

    2017-11-24

    Accurate calculation of gas hydrate saturation is an important aspect of gas hydrate resource evaluation. The effective medium theory (EMT model), the velocity model based on two-phase medium theory (TPT model), and the two component laminated media model (TCLM model), are adopted to investigate the characteristics of acoustic velocity and gas hydrate saturation of pore- and fracture-filling reservoirs in the Qilian Mountain permafrost, China. The compressional wave (P-wave) velocity simulated by the EMT model is more consistent with actual log data than the TPT model in the pore-filling reservoir. The range of the gas hydrate saturation of the typical pore-filling reservoir in hole DKXX-13 is 13.0~85.0%, and the average value of the gas hydrate saturation is 61.9%, which is in accordance with the results by the standard Archie equation and actual core test. The P-wave phase velocity simulated by the TCLM model can be transformed directly into the P-wave transverse velocity in a fracture-filling reservoir. The range of the gas hydrate saturation of the typical fracture-filling reservoir in hole DKXX-19 is 14.1~89.9%, and the average value of the gas hydrate saturation is 69.4%, which is in accordance with actual core test results.

  11. Three types of gas hydrate reservoirs in the Gulf of Mexico identified in LWD data

    Science.gov (United States)

    Lee, Myung Woong; Collett, Timothy S.

    2011-01-01

    High quality logging-while-drilling (LWD) well logs were acquired in seven wells drilled during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II in the spring of 2009. These data help to identify three distinct types of gas hydrate reservoirs: isotropic reservoirs in sands, vertical fractured reservoirs in shale, and horizontally layered reservoirs in silty shale. In general, most gas hydratebearing sand reservoirs exhibit isotropic elastic velocities and formation resistivities, and gas hydrate saturations estimated from the P-wave velocity agree well with those from the resistivity. However, in highly gas hydrate-saturated sands, resistivity-derived gas hydrate-saturation estimates appear to be systematically higher by about 5% over those estimated by P-wave velocity, possibly because of the uncertainty associated with the consolidation state of gas hydrate-bearing sands. Small quantities of gas hydrate were observed in vertical fractures in shale. These occurrences are characterized by high formation resistivities with P-wave velocities close to those of water-saturated sediment. Because the formation factor varies significantly with respect to the gas hydrate saturation for vertical fractures at low saturations, an isotropic analysis of formation factor highly overestimates the gas hydrate saturation. Small quantities of gas hydrate in horizontal layers in shale are characterized by moderate increase in P-wave velocities and formation resistivities and either measurement can be used to estimate gas hydrate saturations.

  12. Characterization of gas hydrate reservoirs by integration of core and log data in the Ulleung Basin, East Sea

    Science.gov (United States)

    Bahk, J.-J.; Kim, G.-Y.; Chun, J.-H.; Kim, J.-H.; Lee, J.Y.; Ryu, B.-J.; Lee, J.-H.; Son, B.-K.; Collett, Timothy S.

    2013-01-01

    Examinations of core and well-log data from the Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2) drill sites suggest that Sites UBGH2-2_2 and UBGH2-6 have relatively good gas hydrate reservoir quality in terms of individual and total cumulative thicknesses of gas-hydrate-bearing sand (HYBS) beds. In both of the sites, core sediments are generally dominated by hemipelagic muds which are intercalated with turbidite sands. The turbidite sands are usually thin-to-medium bedded and mainly consist of well sorted coarse silt to fine sand. Anomalies in infrared core temperatures and porewater chlorinity data and pressure core measurements indicate that “gas hydrate occurrence zones” (GHOZ) are present about 68–155 mbsf at Site UBGH2-2_2 and 110–155 mbsf at Site UBGH2-6. In both the GHOZ, gas hydrates are preferentially associated with many of the turbidite sands as “pore-filling” type hydrates. The HYBS identified in the cores from Site UBGH2-6 are medium-to-thick bedded particularly in the lower part of the GHOZ and well coincident with significant high excursions in all of the resistivity, density, and velocity logs. Gas-hydrate saturations in the HYBS range from 12% to 79% with an average of 52% based on pore-water chlorinity. In contrast, the HYBS from Site UBGH2-2_2 are usually thin-bedded and show poor correlations with both of the resistivity and velocity logs owing to volume averaging effects of the logging tools on the thin HYBS beds. Gas-hydrate saturations in the HYBS range from 15% to 65% with an average of 37% based on pore-water chlorinity. In both of the sites, large fluctuations in biogenic opal contents have significant effects on the sediment physical properties, resulting in limited usage of gamma ray and density logs in discriminating sand reservoirs.

  13. Long-term fate of hydrate-bearing reservoirs during and after production

    Science.gov (United States)

    Reagan, M. T.; Moridis, G. J.; Queiruga, A. F.

    2016-12-01

    Research into the development of feasible production strategies from gas hydrate reservoirs has largely assumed that such reservoirs are bounded by impermeable layers and free of connectivity to faults or fractures. Coupled flow-geomechnical studies have investgated wellbore and overburden stability during production, but have not answered questions about the post-production evolution of such reservoirs. This study investigates, via reservoir simulation, the possibility and potential consequences of uncontrolled gas release during production from hydrates by any of the known dissociation methods (with an emphasis on depressurization). We investigate the possibility of the free gas created by hydrate dissociation escaping along permeable faults, permeable boundaries, or other pathways adjacent to or intercepting the hydrate reservoir. We also investigate the long-term fate and transport of free gas upon the cessation of production operations in both in the presence and absence of permeable features. This work answers questions about the long-term fate of hydrate-bearing sediments, including (a) whether the cessation of production will be followed by considerable hydrate dissociation that lingers for a substantial time, (b) the potential for hydrate reformation after production to be a hazard-mitigating process, (c) the effect of common reservoir parameters and the buoyancy of the released gas on its transport through the subsurface, and (d) the possibility of significant gas emergence at environmentally sensitive locations.

  14. Water in the Martian Crust Locked in Hydrated Minerals: A Significant Planetary Reservoir of Water

    Science.gov (United States)

    Mustard, J. F.

    2017-10-01

    Calculations for a reservoir of water locked in hydrated minerals is estimated to range from a low of < 20 m global equivalent layer to approximately 1 km for the high end. This is sufficient to strongly impact surface geomorphic processes.

  15. Flue gas injection into gas hydrate reservoirs for methane recovery and carbon dioxide sequestration

    International Nuclear Information System (INIS)

    Yang, Jinhai; Okwananke, Anthony; Tohidi, Bahman; Chuvilin, Evgeny; Maerle, Kirill; Istomin, Vladimir; Bukhanov, Boris; Cheremisin, Alexey

    2017-01-01

    Highlights: • Flue gas was injected for both methane recovery and carbon dioxide sequestration. • Kinetics of methane recovery and carbon dioxide sequestration was investigated. • Methane-rich gas mixtures can be produced inside methane hydrate stability zones. • Up to 70 mol% of carbon dioxide in the flue gas was sequestered as hydrates. - Abstract: Flue gas injection into methane hydrate-bearing sediments was experimentally investigated to explore the potential both for methane recovery from gas hydrate reservoirs and for direct capture and sequestration of carbon dioxide from flue gas as carbon dioxide hydrate. A simulated flue gas from coal-fired power plants composed of 14.6 mol% carbon dioxide and 85.4 mol% nitrogen was injected into a silica sand pack containing different saturations of methane hydrate. The experiments were conducted at typical gas hydrate reservoir conditions from 273.3 to 284.2 K and from 4.2 to 13.8 MPa. Results of the experiments show that injection of the flue gas leads to significant dissociation of the methane hydrate by shifting the methane hydrate stability zone, resulting in around 50 mol% methane in the vapour phase at the experimental conditions. Further depressurisation of the system to pressures well above the methane hydrate dissociation pressure generated methane-rich gas mixtures with up to 80 mol% methane. Meanwhile, carbon dioxide hydrate and carbon dioxide-mixed hydrates were formed while the methane hydrate was dissociating. Up to 70% of the carbon dioxide in the flue gas was converted into hydrates and retained in the silica sand pack.

  16. Numerical simulations of depressurization-induced gas production from gas hydrate reservoirs at the Walker Ridge 312 site, northern Gulf of Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Myshakin, Evgeniy M.; Gaddipati, Manohar; Rose, Kelly; Anderson, Brian J.

    2012-06-01

    In 2009, the Gulf of Mexico (GOM) Gas Hydrates Joint-Industry-Project (JIP) Leg II drilling program confirmed that gas hydrate occurs at high saturations within reservoir-quality sands in the GOM. A comprehensive logging-while-drilling dataset was collected from seven wells at three sites, including two wells at the Walker Ridge 313 site. By constraining the saturations and thicknesses of hydrate-bearing sands using logging-while-drilling data, two-dimensional (2D), cylindrical, r-z and three-dimensional (3D) reservoir models were simulated. The gas hydrate occurrences inferred from seismic analysis are used to delineate the areal extent of the 3D reservoir models. Numerical simulations of gas production from the Walker Ridge reservoirs were conducted using the depressurization method at a constant bottomhole pressure. Results of these simulations indicate that these hydrate deposits are readily produced, owing to high intrinsic reservoir-quality and their proximity to the base of hydrate stability. The elevated in situ reservoir temperatures contribute to high (5–40 MMscf/day) predicted production rates. The production rates obtained from the 2D and 3D models are in close agreement. To evaluate the effect of spatial dimensions, the 2D reservoir domains were simulated at two outer radii. The results showed increased potential for formation of secondary hydrate and appearance of lag time for production rates as reservoir size increases. Similar phenomena were observed in the 3D reservoir models. The results also suggest that interbedded gas hydrate accumulations might be preferable targets for gas production in comparison with massive deposits. Hydrate in such accumulations can be readily dissociated due to heat supply from surrounding hydrate-free zones. Special cases were considered to evaluate the effect of overburden and underburden permeability on production. The obtained data show that production can be significantly degraded in comparison with a case using

  17. Methane hydrate reservoir model around the eastern Nankai trough area offshore Japan

    Energy Technology Data Exchange (ETDEWEB)

    Inamori, T.; Hayashi, M.; Kobayashi, T.; Shimoda, N.; Takano, O.; Takayama, T.; Fujii, T.; Saeki, T. [Japan Oil, Gas and Metals National Corp., Chiba (Japan). Dept. of Technology Research and Development

    2008-07-01

    This paper described a modelling study conducted to characterize gas hydrates in the eastern Nankai trough region near the coast of Japan. Two drilling campaigns were conducted in the region, and a total of 39 boreholes were drilled to obtain logging data. Data from exploratory wells drilled in the region were also presented. Methane hydrate-concentrated zones were delineated using seismic sequence analysis and 3-D seismic surveys. Methane hydrate-bearing sediments corresponded with turbidite sands using logging and coring data. A rock physics model was developed using data obtained from the analyses. The study showed that methane hydrate bearing-sediments near the eastern Nankai trough area are heterogenous and both vertically and horizontally complex, as the sediments were composed of turbidite sands with channel-levee and lobe systems. Sandy intervals had higher levels of methane hydrates than silty or muddy intervals. The reservoirs were divided into 3 distinct types: (1) low-saturation; (2) discontinuous high-saturation; and (3) continuous high-saturation. The reservoirs were delineated by selecting the bottom simulating reflector (BSM) as the top of the hydrate-bearing sediments for the turbidite channel-levee or lobe systems. The hydrate rock physics model was used to develop the matrix support model from the relationship between P and S wave velocities and methane hydrate saturation. 9 refs., 11 figs.

  18. Phase field theory modeling of methane fluxes from exposed natural gas hydrate reservoirs

    Science.gov (United States)

    Kivelä, Pilvi-Helinä; Baig, Khuram; Qasim, Muhammad; Kvamme, Bjørn

    2012-12-01

    Fluxes of methane from offshore natural gas hydrate into the oceans vary in intensity from massive bubble columns of natural gas all the way down to fluxes which are not visible within human eye resolution. The driving force for these fluxes is that methane hydrate is not stable towards nether minerals nor towards under saturated water. As such fluxes of methane from deep below hydrates zones may diffuse through fluid channels separating the hydrates from minerals surfaces and reach the seafloor. Additional hydrate fluxes from hydrates dissociating towards under saturated water will have different characteristics depending on the level of dynamics in the actual reservoirs. If the kinetic rate of hydrate dissociation is smaller than the mass transport rate of distributing released gas into the surrounding water through diffusion then hydrodynamics of bubble formation is not an issue and Phase Field Theory (PFT) simulations without hydrodynamics is expected to be adequate [1, 2]. In this work we present simulated results corresponding to thermodynamic conditions from a hydrate field offshore Norway and discuss these results with in situ observations. Observed fluxes are lower than what can be expected from hydrate dissociating and molecularly diffusing into the surrounding water. The PFT model was modified to account for the hydrodynamics. The modified model gave higher fluxes, but still lower than the observed in situ fluxes.

  19. Electrical Conductive Mechanism of Gas Hydrate-Bearing Reservoirs in the Permafrost Region of Qilian Mountain

    Science.gov (United States)

    Peng, C.; Zou, C.; Tang, Y.; Liu, A.; Hu, X.

    2017-12-01

    In the Qilian Mountain, gas hydrates not only occur in pore spaces of sandstones, but also fill in fractures of mudstones. This leads to the difficulty in identification and evaluation of gas hydrate reservoir from resistivity and velocity logs. Understanding electrical conductive mechanism is the basis for log interpretation. However, the research is insufficient in this area. We have collected well logs from 30 wells in this area. Well logs and rock samples from DK-9, DK-11 and DK-12 wells were used in this study. The experiments including SEM, thin section, NMR, XRD, synthesis of gas hydrate in consolidated rock cores under low temperature and measurement of their resistivity and others were performed for understanding the effects of pore structure, rock composition, temperature and gas hydrate on conductivity. The results show that the porosity of reservoir of pore filling type is less than 10% and its clay mineral content is high. As good conductive passages, fractures can reduce resistivity of water-saturated rock. If fractures in the mudstone are filled by calcite, resistivity increases significantly. The resistivity of water-saturated rock at 2°C is twice of that at 18°C. The gas hydrate formation process in the sandstone was studied by resistivity recorded in real time. In the early stage of gas hydrate formation, the increase of residual water salinity may lead to the decrease of resistivity. In the late stage of gas hydrate formation, the continuity decrease of water leads to continuity increase of resistivity. In summary, fractures, rock composition, temperature and gas hydrate are important factors influencing resistivity of formation. This study is helpful for more accurate evaluation of gas hydrate from resistivity log. Acknowledgment: We acknowledge the financial support of the National Special Program for Gas Hydrate Exploration and Test-production (GZH201400302).

  20. Comparison of the physical and geotechnical properties of gas-hydrate-bearing sediments from offshore India and other gas-hydrate-reservoir systems

    Science.gov (United States)

    Winters, William J.; Wilcox-Cline, R.W.; Long, P.; Dewri, S.K.; Kumar, P.; Stern, Laura A.; Kerr, Laura A.

    2014-01-01

    The sediment characteristics of hydrate-bearing reservoirs profoundly affect the formation, distribution, and morphology of gas hydrate. The presence and type of gas, porewater chemistry, fluid migration, and subbottom temperature may govern the hydrate formation process, but it is the host sediment that commonly dictates final hydrate habit, and whether hydrate may be economically developed.In this paper, the physical properties of hydrate-bearing regions offshore eastern India (Krishna-Godavari and Mahanadi Basins) and the Andaman Islands, determined from Expedition NGHP-01 cores, are compared to each other, well logs, and published results of other hydrate reservoirs. Properties from the hydrate-free Kerala-Konkan basin off the west coast of India are also presented. Coarser-grained reservoirs (permafrost-related and marine) may contain high gas-hydrate-pore saturations, while finer-grained reservoirs may contain low-saturation disseminated or more complex gas-hydrates, including nodules, layers, and high-angle planar and rotational veins. However, even in these fine-grained sediments, gas hydrate preferentially forms in coarser sediment or fractures, when present. The presence of hydrate in conjunction with other geologic processes may be responsible for sediment porosity being nearly uniform for almost 500 m off the Andaman Islands.Properties of individual NGHP-01 wells and regional trends are discussed in detail. However, comparison of marine and permafrost-related Arctic reservoirs provides insight into the inter-relationships and common traits between physical properties and the morphology of gas-hydrate reservoirs regardless of location. Extrapolation of properties from one location to another also enhances our understanding of gas-hydrate reservoir systems. Grain size and porosity effects on permeability are critical, both locally to trap gas and regionally to provide fluid flow to hydrate reservoirs. Index properties corroborate more advanced

  1. Non-equilibrium simulation of CH4 production through the depressurization method from gas hydrate reservoirs

    Science.gov (United States)

    Qorbani, Khadijeh; Kvamme, Bjørn

    2016-04-01

    Natural gas hydrates (NGHs) in nature are formed from various hydrate formers (i.e. aqueous, gas, and adsorbed phases). As a result, due to Gibbs phase rule and the combined first and second laws of thermodynamics CH4-hydrate cannot reach thermodynamic equilibrium in real reservoir conditions. CH4 is the dominant component in NGH reservoirs. It is formed as a result of biogenic degradation of biological material in the upper few hundred meters of subsurface. It has been estimated that the amount of fuel-gas reserve in NGHs exceed the total amount of fossil fuel explored until today. Thus, these reservoirs have the potential to satisfy the energy requirements of the future. However, released CH4 from dissociated NGHs could find its way to the atmosphere and it is a far more aggressive greenhouse gas than CO2, even though its life-time is shorter. Lack of reliable field data makes it difficult to predict the production potential, as well as safety of CH4 production from NGHs. Computer simulations can be used as a tool to investigate CH4 production through different scenarios. Most hydrate simulators within academia and industry treat hydrate phase transitions as an equilibrium process and those which employ the kinetic approach utilize simple laboratory data in their models. Furthermore, it is typical to utilize a limited thermodynamic description where only temperature and pressure projections are considered. Another widely used simplification is to assume only a single route for the hydrate phase transitions. The non-equilibrium nature of hydrate indicates a need for proper kinetic models to describe hydrate dissociation and reformation in the reservoir with respect to thermodynamics variables, CH4 mole-fraction, pressure and temperature. The RetrasoCodeBright (RCB) hydrate simulator has previously been extended to model CH4-hydrate dissociation towards CH4 gas and water. CH4-hydrate is added to the RCB data-base as a pseudo mineral. Phase transitions are treated

  2. Sensitivity Analysis of Parameters Governing the Recovery of Methane from Natural Gas Hydrate Reservoirs

    Directory of Open Access Journals (Sweden)

    Carlos Giraldo

    2014-04-01

    Full Text Available Naturally occurring gas hydrates are regarded as an important future source of energy and considerable efforts are currently being invested to develop methods for an economically viable recovery of this resource. The recovery of natural gas from gas hydrate deposits has been studied by a number of researchers. Depressurization of the reservoir is seen as a favorable method because of its relatively low energy requirements. While lowering the pressure in the production well seems to be a straight forward approach to destabilize methane hydrates, the intrinsic kinetics of CH4-hydrate decomposition and fluid flow lead to complex processes of mass and heat transfer within the deposit. In order to develop a better understanding of the processes and conditions governing the production of methane from methane hydrates it is necessary to study the sensitivity of gas production to the effects of factors such as pressure, temperature, thermal conductivity, permeability, porosity on methane recovery from naturally occurring gas hydrates. A simplified model is the base for an ensemble of reservoir simulations to study which parameters govern productivity and how these factors might interact.

  3. The big fat LARS - a LArge Reservoir Simulator for hydrate formation and gas production

    Science.gov (United States)

    Beeskow-Strauch, Bettina; Spangenberg, Erik; Schicks, Judith M.; Giese, Ronny; Luzi-Helbing, Manja; Priegnitz, Mike; Klump, Jens; Thaler, Jan; Abendroth, Sven

    2013-04-01

    Simulating natural scenarios on lab scale is a common technique to gain insight into geological processes with moderate effort and expenses. Due to the remote occurrence of gas hydrates, their behavior in sedimentary deposits is largely investigated on experimental set ups in the laboratory. In the framework of the submarine gas hydrate research project (SUGAR) a large reservoir simulator (LARS) with an internal volume of 425 liter has been designed, built and tested. To our knowledge this is presently a word-wide unique set up. Because of its large volume it is suitable for pilot plant scale tests on hydrate behavior in sediments. That includes not only the option of systematic tests on gas hydrate formation in various sedimentary settings but also the possibility to mimic scenarios for the hydrate decomposition and subsequent natural gas extraction. Based on these experimental results various numerical simulations can be realized. Here, we present the design and the experimental set up of LARS. The prerequisites for the simulation of a natural gas hydrate reservoir are porous sediments, methane, water, low temperature and high pressure. The reservoir is supplied by methane-saturated and pre-cooled water. For its preparation an external gas-water mixing stage is available. The methane-loaded water is continuously flushed into LARS as finely dispersed fluid via bottom-and-top-located sparger. The LARS is equipped with a mantle cooling system and can be kept at a chosen set temperature. The temperature distribution is monitored at 14 reasonable locations throughout the reservoir by Pt100 sensors. Pressure needs are realized using syringe pump stands. A tomographic system, consisting of a 375-electrode-configuration is attached to the mantle for the monitoring of hydrate distribution throughout the entire reservoir volume. Two sets of tubular polydimethylsiloxan-membranes are applied to determine gas-water ratio within the reservoir using the effect of permeability

  4. Numerical simulation of gas hydrate exploitation from subsea reservoirs in the Black Sea

    Science.gov (United States)

    Janicki, Georg; Schlüter, Stefan; Hennig, Torsten; Deerberg, Görge

    2017-04-01

    Natural gas (methane) is the most environmental friendly source of fossil energy. When coal is replace by natural gas in power production the emission of carbon dioxide is reduced by 50 %. The vast amount of methane assumed in gas hydrate deposits can help to overcome a shortage of fossil energy resources in the future. To increase their potential for energy applications new technological approaches are being discussed and developed worldwide. Besides technical challenges that have to be overcome climate and safety issues have to be considered before a commercial exploitation of such unconventional reservoirs. The potential of producing natural gas from subsea gas hydrate deposits by various means (e. g. depressurization and/or carbon dioxide injection) is numerically studied in the frame of the German research project »SUGAR - Submarine Gas Hydrate Reservoirs«. In order to simulate the exploitation of hydrate-bearing sediments in the subsea, an in-house simulation model HyReS which is implemented in the general-purpose software COMSOL Multiphysics is used. This tool turned out to be especially suited for the flexible implementation of non-standard correlations concerning heat transfer, fluid flow, hydrate kinetics, and other relevant model data. Partially based on the simulation results, the development of a technical concept and its evaluation are the subject of ongoing investigations, whereby geological and ecological criteria are to be considered. The results illustrate the processes and effects occurring during the gas production from a subsea gas hydrate deposit by depressurization. The simulation results from a case study for a deposit located in the Black Sea reveal that the production of natural gas by simple depressurization is possible but with quite low rates. It can be shown that the hydrate decomposition and thus the gas production strongly depend on the geophysical properties of the reservoir, the mass and heat transport within the reservoir, and

  5. Designing a reservoir flow rate experiment for the GOM hydrate JIP leg 2 LWD drilling

    Energy Technology Data Exchange (ETDEWEB)

    Gullapalli, I.; Silpngarmlert, S.; Reik, B.; Kamal, M.; Jones, E. [Chevron Energy Technology Co., San Ramon, CA (United States); Moridis, G. [Lawrence Berkeley National Laboratories, CA (United States); Collett, T. [United States Geological Survey, Reston, VA (United States)

    2008-07-01

    Studies have indicated that the Gulf of Mexico may contain large deep sea hydrate deposits. This paper provided details of short-term production profiles obtained from a geological model of hydrate deposits located in the Gulf area. A well test analysis tool was used to obtain the production parameters. Pressure transients from numerical simulations of various well test designs were used to provide estimates of important flow parameters. The aim of the study was to determine the type and duration of a well test capable of providing data to support the accurate modeling of gas hydrate deposits. Parameters studied in the test included the effects of permeability and hydrate saturation as a function of the duration of the flow test. Results indicated that production using a constant bottom hole pressure is an appropriate method of impacting hydrate dissociation by depressurization. However, changes in transient pressure plots could not be characterized in order to identify regions of varying saturation levels. Results suggested that the rate of effective water to effective gas was higher than rates obtained from relative permeability relations due to low gas saturation levels. Fluid saturation regions were in areas of low confidence in relative permeability curves. However, it was not possible to calculate absolute permeability of the reservoir for systems with short production periods. Further studies are needed to determine effective permeability using history matching and a hydrate simulator. 8 refs., 4 tabs., 27 figs.

  6. Physiological variation of retinal layer thickness is not caused by hydration: a randomised trial.

    Science.gov (United States)

    Balk, Lisanne J; Oberwahrenbrock, Timm; Uitdehaag, Bernard M J; Petzold, Axel

    2014-09-15

    There is evidence for physiological variation of retinal thicknesses as determined by optical coherence tomography (OCT). We tested if such changes could be explained by hydration and would exceed what may be expected from normal ageing. Subjects (n=26) of a previous study were re-assessed and were randomised to 3 groups of a hydration escalation trial (no hydration, 1× hydration, 2× hydration). Automated retinal layer segmentations were performed for the macular retinal nerve fibre layer (RNFL), ganglion cell layer (GCL), inner plexiform layer (IPL), inner nuclear layer (INL), outer plexiform layer (OPL) and outer nuclear layer (ONL). The averaged volumes were calculated for the central foveola, 3 mm and 6 mm circles of the ETDRS grid. Following oral hydration there were no significant differences of retinal layer thicknesses between the three randomised groups in any of the ETDRS regions at any time-point. Ageing related changes were significant over an 18 month period for the GCL. The negative outcome of this trial implies that, until the causes for the observed variation are resolved, investigators may need to accept, and include into trial power calculations, a small degree of variation (physiology or instrument/software related factors. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. Archie’s saturation exponent for natural gas hydrate in coarse-grained reservoirs

    Science.gov (United States)

    Cook, Ann E.; Waite, William F.

    2018-01-01

    Accurately quantifying the amount of naturally occurring gas hydrate in marine and permafrost environments is important for assessing its resource potential and understanding the role of gas hydrate in the global carbon cycle. Electrical resistivity well logs are often used to calculate gas hydrate saturations, Sh, using Archie's equation. Archie's equation, in turn, relies on an empirical saturation parameter, n. Though n = 1.9 has been measured for ice‐bearing sands and is widely used within the hydrate community, it is highly questionable if this n value is appropriate for hydrate‐bearing sands. In this work, we calibrate n for hydrate‐bearing sands from the Canadian permafrost gas hydrate research well, Mallik 5L‐38, by establishing an independent downhole Sh profile based on compressional‐wave velocity log data. Using the independently determined Sh profile and colocated electrical resistivity and bulk density logs, Archie's saturation equation is solved for n, and uncertainty is tracked throughout the iterative process. In addition to the Mallik 5L‐38 well, we also apply this method to two marine, coarse‐grained reservoirs from the northern Gulf of Mexico Gas Hydrate Joint Industry Project: Walker Ridge 313‐H and Green Canyon 955‐H. All locations yield similar results, each suggesting n ≈ 2.5 ± 0.5. Thus, for the coarse‐grained hydrate bearing (Sh > 0.4) of greatest interest as potential energy resources, we suggest that n = 2.5 ± 0.5 should be applied in Archie's equation for either marine or permafrost gas hydrate settings if independent estimates of n are not available.

  8. Physiological variation of retinal layer thickness is not caused by hydration: A randomised trial

    NARCIS (Netherlands)

    Balk, L.J.; Oberwahrenbrock, T.; Uitdehaag, B.M.J.; Petzold, A.F.S.

    2014-01-01

    There is evidence for physiological variation of retinal thicknesses as determined by optical coherence tomography (OCT). We tested if such changes could be explained by hydration and would exceed what may be expected from normal ageing. Subjects (n = 26) of a previous study were re-assessed and

  9. Analysis of formation pressure test results in the Mount Elbert methane hydrate reservoir through numerical simulation

    Science.gov (United States)

    Kurihara, M.; Sato, A.; Funatsu, K.; Ouchi, H.; Masuda, Y.; Narita, H.; Collett, T.S.

    2011-01-01

    Targeting the methane hydrate (MH) bearing units C and D at the Mount Elbert prospect on the Alaska North Slope, four MDT (Modular Dynamic Formation Tester) tests were conducted in February 2007. The C2 MDT test was selected for history matching simulation in the MH Simulator Code Comparison Study. Through history matching simulation, the physical and chemical properties of the unit C were adjusted, which suggested the most likely reservoir properties of this unit. Based on these properties thus tuned, the numerical models replicating "Mount Elbert C2 zone like reservoir" "PBU L-Pad like reservoir" and "PBU L-Pad down dip like reservoir" were constructed. The long term production performances of wells in these reservoirs were then forecasted assuming the MH dissociation and production by the methods of depressurization, combination of depressurization and wellbore heating, and hot water huff and puff. The predicted cumulative gas production ranges from 2.16??106m3/well to 8.22??108m3/well depending mainly on the initial temperature of the reservoir and on the production method.This paper describes the details of modeling and history matching simulation. This paper also presents the results of the examinations on the effects of reservoir properties on MH dissociation and production performances under the application of the depressurization and thermal methods. ?? 2010 Elsevier Ltd.

  10. Geological modeling for methane hydrate reservoir characterization in the eastern Nankai Trough, offshore Japan

    Science.gov (United States)

    Tamaki, M.; Komatsu, Y.; Suzuki, K.; Takayama, T.; Fujii, T.

    2012-12-01

    The eastern Nankai trough, which is located offshore of central Japan, is considered as an attractive potential resource field of methane hydrates. Japan Oil, Gas and Metals National Corporation is planning to conduct a production test in early 2013 at the AT1 site in the north slope of Daini-Atsumi Knoll in the eastern Nankai Trough. The depositional environment of methane hydrate-bearing sediments around the production test site is a deep submarine-fan turbidite system, and it is considered that the reservoir properties should show lateral as well as vertical heterogeneity. Since the variations in the reservoir heterogeneity have an impact on the methane hydrate dissociation and gas production performance, precise geological models describing reservoir heterogeneity would be required for the evaluation of reservoir potentials. In preparation for the production test, 3 wells; two monitoring boreholes (AT1-MC and AT1-MT1) and a coring well (AT1-C), were newly acquired in 2012. In addition to a geotechnical hole drilling survey in 2011 (AT1-GT), totally log data from 2 wells and core data from 2 wells were obtained around the production test site. In this study, we conducted well correlations between AT1 and A1 wells drilled in 2003 and then, 3D geological models were updated including AT1 well data in order to refine hydrate reservoir characterization around the production test site. The results of the well correlations show that turbidite sand layers are characterized by good lateral continuity, and give significant information for the distribution morphology of sand-rich channel fills. We also reviewed previously conducted 3D geological models which consist of facies distributions and petrophysical properties distributions constructed from integration of 3D seismic data and a well data (A1 site) adopting a geostatistical approach. In order to test the practical validity of the previously generated models, cross-validation was conducted using AT1 well data. The

  11. Sedimentological Characterization of a Deepwater Methane Hydrate Reservoir in Green Canyon 955, Northern Gulf of Mexico

    Science.gov (United States)

    Meazell, K.; Flemings, P. B.

    2017-12-01

    Grain size is a controlling factor of hydrate saturation within a Pleistocene channel-levee system investigated by the UT-GOM2-1 expedition within the deepwater northern Gulf of Mexico. Laser diffraction and settling experiments conducted on sediments from 413-440 meters below the seafloor reveal the presence of two interbedded lithologic units, identified as a silty sand and a clayey silt, according Shepard's classification system. The sand-rich lithofacies has low density and high p-wave velocity, suggesting a high degree of hydrate saturation. Conversely, the clay and silt dominated lithofacies is characterized by a higher density and low p-wave velocity, suggesting low hydrate saturation. The sand-rich lithofacies is well-sorted and displays abundant ripple lamination, indicative of deposition within a high-energy environment. The clayey-silt is poorly-sorted and lacks sedimentary structures. The two lithofacies are interbedded throughout the reservoir unit; however, the relative abundance of the sand-rich lithofacies increases with depth, suggesting a potential decrease in flow energy or sediment flux over time, resulting in the most favorable reservoir properties near the base of the unit.

  12. Investigation of gas hydrate-bearing sandstone reservoirs at the Mount Elbert stratigraphic test well, Milne Point, Alaska

    Energy Technology Data Exchange (ETDEWEB)

    Boswell, R. [United States Dept. of Energy, Morgantown, WV (United States). National Energy Technology Lab; Hunter, R. [ASRC Energy Services, Anchorage, AK (United States); Collett, T. [United States Geological Survey, Denver, CO (United States); Digert, S.; Weeks, M. [BP Exploration Alaska Inc., Anchorage, AK (United States); Hancock, S. [RPS Energy Canada, Calgary, AB (Canada)

    2008-07-01

    Gas hydrates occur within the shallow sand reservoirs on the Alaska North Slope (ANS). The mean estimate for gas hydrate in-place resources on the ANS is 16.7 trillion cubic metres. In the past, they were viewed primarily as a drilling hazard to be managed during the development of deeper oil resources. In 2002, a cooperative research program was launched to help determine the potential for environmentally-sound and economically-viable production of methane from gas hydrates. Additional objectives were to refine ANS gas hydrate resource potential, improve the geologic and geophysical methods used to locate and asses gas hydrate resources, and develop numerical modeling capabilities that are essential in both planning and evaluating gas hydrate field programs. This paper reviewed the results of the an extensive data collection effort conducted at the Mount Elbert number 1 gas hydrates stratigraphic test well on the ANS. The 22-day field program acquired significant gas hydrate-bearing reservoir data, including a suite of open-hole well logs, over 500 feet of continuous core, and open-hole formation pressure response tests. The logging program confirmed the existence of approximately 30 m of gas hydrate saturated, fine-grained sand reservoir. Gas hydrate saturations were observed to range from 60 to 75 per cent. Continuous wire-line coring operations achieved 85 per cent recovery. The Mount Elbert field program also involved gas and water sample collection. It demonstrated the ability to safely and efficiently conduct a research-level open-hole data acquisition program in shallow, sub-permafrost sediments and increased confidence in gas hydrate resource assessment methodologies for the ANS. 10 refs., 9 figs.

  13. Pore- and fracture-filling gas hydrate reservoirs in the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II Green Canyon 955 H well

    Science.gov (United States)

    Lee, M.W.; Collett, T.S.

    2012-01-01

    High-quality logging-while-drilling (LWD) downhole logs were acquired in seven wells drilled during the Gulf of MexicoGasHydrateJointIndustryProjectLegII in the spring of 2009. Well logs obtained in one of the wells, the GreenCanyon Block 955Hwell (GC955-H), indicate that a 27.4-m thick zone at the depth of 428 m below sea floor (mbsf; 1404 feet below sea floor (fbsf)) contains gashydrate within sand with average gashydrate saturations estimated at 60% from the compressional-wave (P-wave) velocity and 65% (locally more than 80%) from resistivity logs if the gashydrate is assumed to be uniformly distributed in this mostly sand-rich section. Similar analysis, however, of log data from a shallow clay-rich interval between 183 and 366 mbsf (600 and 1200 fbsf) yielded average gashydrate saturations of about 20% from the resistivity log (locally 50-60%) and negligible amounts of gashydrate from the P-wave velocity logs. Differences in saturations estimated between resistivity and P-wave velocities within the upper clay-rich interval are caused by the nature of the gashydrate occurrences. In the case of the shallow clay-rich interval, gashydrate fills vertical (or high angle) fractures in rather than fillingpore space in sands. In this study, isotropic and anisotropic resistivity and velocity models are used to analyze the occurrence of gashydrate within both the clay-rich and sand dominated gas-hydrate-bearing reservoirs in the GC955-Hwell.

  14. Utilizing Non-Equilibrium Thermodynamics and Reactive Transport to Model CH4 Production from the Nankai Trough Gas Hydrate Reservoir

    Directory of Open Access Journals (Sweden)

    Khadijeh Qorbani

    2017-07-01

    Full Text Available The ongoing search for new sources of energy has brought natural gas hydrate (NGH reservoirs to the forefront of attention in both academia and the industry. The amount of gas reserves trapped within these reservoirs surpasses all of the conventional fossil fuel sources explored so far, which makes it of utmost importance to predict their production potential and safety. One of the challenges facing those attempting to analyse their behaviour is that the large number of involved phases make NGHs unable to ever reach equilibrium in nature. Field-scale experiments are expensive and time consuming. However, computer simulations have now become capable of modelling different gas production scenarios, as well as production optimization analyses. In addition to temperature and pressure, independent thermodynamic parameters for hydrate stabilization include the hydrate composition and concentrations for all co-existing phases. It is therefore necessary to develop and implement realistic kinetic models accounting for all significant routes for dissociation and reformation. The reactive transport simulator makes it easy to deploy nonequilibrium thermodynamics for the study of CH4 production from hydrate-bearing sediments by considering each hydrate-related transition as a separate pseudo reaction. In this work, we have used the expanded version of the RetrasoCodeBright (RCB reactive transport simulator to model exploitation of the methane hydrate (MH reservoir located in the Nankai Trough, Japan. Our results showed that higher permeabilities in the horizontal direction dominated the pressure drop propagation throughout the hydrate layers and affected their hydrate dissociation rates. Additionally, the comparison of the vertical well versus the horizontal well pattern indicated that hydrate dissociation was slightly higher in the vertical well scenario compared to the horizontal.

  15. Effects of immersion solution on corneal tissue strip hydration and thickness during thermal shrinkage

    Science.gov (United States)

    Borja, David; Manns, Fabrice; Lamar, Peggy D.; Rosen, Alexander; Parel, Jean-Marie A.

    2003-07-01

    Purpose: To assess the effects of immersion solutions with different Dextran concentrations on the hydration of cornea tissue strips at normal body temperature. Methods: A 20% Dextran-BSS solution was injected via a self sealing limbal-transcorneal tunnel incision using a 30ga needle into the anterior chamber of human donor eyes until the globe was hard. The eyes were then immersed cornea down overnight in the same solution. Corneal thickness was measured by ultrasound pachymetry after the eyes were re-inflated and at regular intervals to assess dehydration. When the central cornea thickness reached 400-500μm corneal buttons were removed using a 10mm trephine. The buttons were then cut into 6x6mm strips using a custom-made jig and immediately immersed in solutions of Dextran (15 to 20% in increments of 2.5%) at 35degC. The edge thickness of the immersed strip was measured every 5 min for one hour using an optical comparator (Topcon, Japan) modified for tissue shadowphotogrammetry. Results: For five Florida Lions Eye Bank donated eyes after one hour in the Dextran solution the mean final measured thickness of corneas in 20%, 17.5% and 15% Dextran-BSS solutions were 570 (+/-75) μm, 680 (+/-70) μm, and 1080 (+/-95) μm respectively. These measured thicknesses changes correspond to an average swelling of 1.2, 1.4 and 2.2 times the initial thickness of each cornea strip in the 20%, 17.5% and 15% Dextran-BSS solutions respectively. Conclusion: We will conduct experiments at higher Dextran concentrations but our current results indicate that 20% Dextran-BSS solution was the best solution tested at keeping corneal tissue strips at or close to physiological thickness.

  16. Electrical anisotropy of gas hydrate-bearing sand reservoirs in the Gulf of Mexico

    Science.gov (United States)

    Cook, Anne E.; Anderson, Barbara I.; Rasmus, John; Sun, Keli; Li, Qiming; Collett, Timothy S.; Goldberg, David S.

    2012-01-01

    We present new results and interpretations of the electricalanisotropy and reservoir architecture in gashydrate-bearingsands using logging data collected during the Gulf of MexicoGasHydrate Joint Industry Project Leg II. We focus specifically on sandreservoirs in Hole Alaminos Canyon 21 A (AC21-A), Hole Green Canyon 955 H (GC955-H) and Hole Walker Ridge 313 H (WR313-H). Using a new logging-while-drilling directional resistivity tool and a one-dimensional inversion developed by Schlumberger, we resolve the resistivity of the current flowing parallel to the bedding, R| and the resistivity of the current flowing perpendicular to the bedding, R|. We find the sandreservoir in Hole AC21-A to be relatively isotropic, with R| and R| values close to 2 Ω m. In contrast, the gashydrate-bearingsandreservoirs in Holes GC955-H and WR313-H are highly anisotropic. In these reservoirs, R| is between 2 and 30 Ω m, and R| is generally an order of magnitude higher. Using Schlumberger's WebMI models, we were able to replicate multiple resistivity measurements and determine the formation resistivity the gashydrate-bearingsandreservoir in Hole WR313-H. The results showed that gashydrate saturations within a single reservoir unit are highly variable. For example, the sand units in Hole WR313-H contain thin layers (on the order of 10-100 cm) with varying gashydrate saturations between 15 and 95%. Our combined modeling results clearly indicate that the gashydrate-bearingsandreservoirs in Holes GC955-H and WR313-H are highly anisotropic due to varying saturations of gashydrate forming in thin layers within larger sand units.

  17. Investigation of gas hydrate-bearing sandstone reservoirs at the "Mount Elbert" stratigraphic test well, Milne Point, Alaska

    Energy Technology Data Exchange (ETDEWEB)

    Boswell, R.M.; Hunter, R. (ASRC Energy Services, Anchorage, AK); Collett, T. (USGS, Denver, CO); Digert, S. (BP Exploration (Alaska) Inc., Anchorage, AK); Hancock, S. (RPS Energy Canada, Calgary, Alberta, Canada); Weeks, M. (BP Exploration (Alaska) Inc., Anchorage, AK); Mt. Elbert Science Team

    2008-01-01

    In February 2007, the U.S. Department of Energy, BP Exploration (Alaska), Inc., and the U.S. Geological Survey conducted an extensive data collection effort at the "Mount Elbert #1" gas hydrates stratigraphic test well on the Alaska North Slope (ANS). The 22-day field program acquired significant gas hydrate-bearing reservoir data, including a full suite of open-hole well logs, over 500 feet of continuous core, and open-hole formation pressure response tests. Hole conditions, and therefore log data quality, were excellent due largely to the use of chilled oil-based drilling fluids. The logging program confirmed the existence of approximately 30 m of gashydrate saturated, fine-grained sand reservoir. Gas hydrate saturations were observed to range from 60% to 75% largely as a function of reservoir quality. Continuous wire-line coring operations (the first conducted on the ANS) achieved 85% recovery through 153 meters of section, providing more than 250 subsamples for analysis. The "Mount Elbert" data collection program culminated with open-hole tests of reservoir flow and pressure responses, as well as gas and water sample collection, using Schlumberger's Modular Formation Dynamics Tester (MDT) wireline tool. Four such tests, ranging from six to twelve hours duration, were conducted. This field program demonstrated the ability to safely and efficiently conduct a research-level openhole data acquisition program in shallow, sub-permafrost sediments. The program also demonstrated the soundness of the program's pre-drill gas hydrate characterization methods and increased confidence in gas hydrate resource assessment methodologies for the ANS.

  18. CO2 Exchange in a Methane Hydrate Reservoir: Ignik Sikumi #1 Alaska Field Trial Operations and Summary Results

    Science.gov (United States)

    Hester, K. C.; Farrell, H.; Howard, J. J.; Martin, K.; Raterman, K.; Schoderbek, D.; Smith, B.; Silpngarmlert, S.

    2012-12-01

    In the winter of 2012, a CO2 exchange field trial was performed at Prudhoe Bay, Alaska. The goal was to demonstrate the feasibility of CO2 hydrate exchange technology, developed in the laboratory, on a natural methane hydrate-bearing reservoir. This included verifying the chemical exchange of CO2 with methane in addition to maintaining injectivity. Drilled in 2011, the Ignik Sikumi #1 well was perforated in February 2012. The pilot was designed as a 'huff and puff' style test where a single well is used first for injection then followed with production. The target for the test was a 10 m sand zone estimated to contain 70-80% hydrate saturation. For 13 days, over 5600 m3 of a CO2 mixture (77mol% N2, 23 mol% CO2) were injected in the hydrate-bearing interval. Injectivity was maintained over this period. Following injection, flow back commenced over a 30 day period. The production started by maintaining a bottom hole pressure above the dissociation pressure above methane hydrate. At later times, the bottom hole pressure was lowered causing both pore space fluids to be produced along with dissociation of non-exchanged original methane hydrate. In total, over 23,700 m3 of methane was produced over the production period.

  19. Fast parametric relationships for the large-scale reservoir simulation of mixed CH4-CO2 gas hydrate systems

    Science.gov (United States)

    Reagan, Matthew T.; Moridis, George J.; Seim, Katie S.

    2017-06-01

    A recent Department of Energy field test on the Alaska North Slope has increased interest in the ability to simulate systems of mixed CO2-CH4 hydrates. However, the physically realistic simulation of mixed-hydrate simulation is not yet a fully solved problem. Limited quantitative laboratory data leads to the use of various ab initio, statistical mechanical, or other mathematic representations of mixed-hydrate phase behavior. Few of these methods are suitable for inclusion in reservoir simulations, particularly for systems with large number of grid elements, 3D systems, or systems with complex geometric configurations. In this work, we present a set of fast parametric relationships describing the thermodynamic properties and phase behavior of a mixed methane-carbon dioxide hydrate system. We use well-known, off-the-shelf hydrate physical properties packages to generate a sufficiently large dataset, select the most convenient and efficient mathematical forms, and fit the data to those forms to create a physical properties package suitable for inclusion in the TOUGH+ family of codes. The mapping of the phase and thermodynamic space reveals the complexity of the mixed-hydrate system and allows understanding of the thermodynamics at a level beyond what much of the existing laboratory data and literature currently offer.

  20. Studying methane migration mechanisms at Walker Ridge, Gulf of Mexico, via 3D methane hydrate reservoir modeling

    Energy Technology Data Exchange (ETDEWEB)

    Nole, Michael [University of Texas at Austin; Daigle, Hugh [University of Texas at Austin; Mohanty, Kishore [University of Texas at Austin; Cook, Ann [Ohio State University; Hillman, Jess [Ohio State University

    2015-12-15

    We have developed a 3D methane hydrate reservoir simulator to model marine methane hydrate systems. Our simulator couples highly nonlinear heat and mass transport equations and includes heterogeneous sedimentation, in-situ microbial methanogenesis, the influence of pore size contrast on solubility gradients, and the impact of salt exclusion from the hydrate phase on dissolved methane equilibrium in pore water. Using environmental parameters from Walker Ridge in the Gulf of Mexico, we first simulate hydrate formation in and around a thin, dipping, planar sand stratum surrounded by clay lithology as it is buried to 295mbsf. We find that with sufficient methane being supplied by organic methanogenesis in the clays, a 200x pore size contrast between clays and sands allows for a strong enough concentration gradient to significantly drop the concentration of methane hydrate in clays immediately surrounding a thin sand layer, a phenomenon that is observed in well log data. Building upon previous work, our simulations account for the increase in sand-clay solubility contrast with depth from about 1.6% near the top of the sediment column to 8.6% at depth, which leads to a progressive strengthening of the diffusive flux of methane with time. By including an exponentially decaying organic methanogenesis input to the clay lithology with depth, we see a decrease in the aqueous methane supplied to the clays surrounding the sand layer with time, which works to further enhance the contrast in hydrate saturation between the sand and surrounding clays. Significant diffusive methane transport is observed in a clay interval of about 11m above the sand layer and about 4m below it, which matches well log observations. The clay-sand pore size contrast alone is not enough to completely eliminate hydrate (as observed in logs), because the diffusive flux of aqueous methane due to a contrast in pore size occurs slower than the rate at which methane is supplied via organic methanogenesis

  1. UT-GOM2-1: Prospecting, Drilling and Sampling a Coarse-Grained Hydrate Reservoir in Green Canyon 955, the Deepwater Gulf of Mexico

    Science.gov (United States)

    Flemings, P. B.; Phillips, S. C.

    2017-12-01

    In May 2017, a science team led by the University of Texas-Austin conducted drilling and coring operations from the Helix Q4000 targeting gas hydrates in sand-rich reservoirs in the Green Canyon 955 block in the northern Gulf of Mexico. The UT-GOM2-1 expedition goals were to 1) test two configurations of pressure coring devices to assess relative performance with respect to recovery and quality of samples and 2) gather sufficient samples to allow laboratories throughout the US to investigate a range of outstanding science questions related to the origin and nature of gas hydrate-bearing sands. In the first well (UT-GOM2-1-H002), 1 of the 8 cores were recovered under pressure with 34% recovery. In the second well (UT-GOM2-1-H005), 12 of 13 cores were recovered under pressure with 77% recovery. The pressure cores were imaged and logged under pressure. Samples were degassed both shipboard and dockside to interpret hydrate concentration and gas composition. Samples for microbiological and porewater analysis were taken from the depressurized samples. 21 3 ft pressure cores were returned to the University of Texas for storage, distribution, and further analysis. Preliminary analyses document that the hydrate-bearing interval is composed of two interbedded (cm to m thickness) facies. Lithofacies II is composed of sandy silt and has trough cross bedding whereas Lithofacies III is composed of clayey silt and no bedforms are observed. Lithofacies II has low density (1.7 to 1.9 g/cc) and high velocity (3000-3250 m/s) beds whereas Lithofacies 3 has high density ( 1.9-2.1g/cc) and low velocity ( 1700 m/s). Quantitative degassing was used to determine that Lithofacies II contains high hydrate saturation (66-87%) and Lithofacies III contains moderate saturation ( 18-30%). Gas samples were analyzed periodically in each experiment and were composed of primarily methane with an average of 94 ppm ethane and detectable, but not quantifiable, propane. The core data will provide a

  2. Petrophysical Characterization and Reservoir Simulator for Methane Gas Production from Gulf of Mexico Hydrates

    Energy Technology Data Exchange (ETDEWEB)

    Kishore Mohanty; Bill Cook; Mustafa Hakimuddin; Ramanan Pitchumani; Damiola Ogunlana; Jon Burger; John Shillinglaw

    2006-06-30

    Gas hydrates are crystalline, ice-like compounds of gas and water molecules that are formed under certain thermodynamic conditions. Hydrate deposits occur naturally within ocean sediments just below the sea floor at temperatures and pressures existing below about 500 meters water depth. Gas hydrate is also stable in conjunction with the permafrost in the Arctic. Most marine gas hydrate is formed of microbially generated gas. It binds huge amounts of methane into the sediments. Estimates of the amounts of methane sequestered in gas hydrates worldwide are speculative and range from about 100,000 to 270,000,000 trillion cubic feet (modified from Kvenvolden, 1993). Gas hydrate is one of the fossil fuel resources that is yet untapped, but may play a major role in meeting the energy challenge of this century. In this project novel techniques were developed to form and dissociate methane hydrates in porous media, to measure acoustic properties and CT properties during hydrate dissociation in the presence of a porous medium. Hydrate depressurization experiments in cores were simulated with the use of TOUGHFx/HYDRATE simulator. Input/output software was developed to simulate variable pressure boundary condition and improve the ease of use of the simulator. A series of simulations needed to be run to mimic the variable pressure condition at the production well. The experiments can be matched qualitatively by the hydrate simulator. The temperature of the core falls during hydrate dissociation; the temperature drop is higher if the fluid withdrawal rate is higher. The pressure and temperature gradients are small within the core. The sodium iodide concentration affects the dissociation pressure and rate. This procedure and data will be useful in designing future hydrate studies.

  3. Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report

    Energy Technology Data Exchange (ETDEWEB)

    McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

    2007-09-01

    Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

  4. Sensitivity Studies on Productivity Performance from 3D Heterogeneous Reservoir Model Based on the L-Pad Gas Hydrate Accumulation in Prudhoe Bay Unit, North Slope Alaska

    Science.gov (United States)

    Myshakin, E. M.; Ajayi, T.; Seol, Y.; Boswell, R.

    2016-12-01

    Three-dimensional reservoir model of the "L-Pad" hydrate deposit located in the Prudhoe Bay region of the Alaska's North Slope was created including four stratigraphic units; silty shale overburden, hydrate-bearing D sand, inter-reservoir silty shale, hydrate-bearing C sand, and silty shale underburden. The model incorporates the actual geological settings, accounts for the presence of faults, reservoir dip, the hydrate-water contact in the C sand. Geostatistical porosity distributions in D and C sands conditioned to log data from 78 wells drilled in the vicinity of the Prudhoe Bay "L-pad" were developed providing vertical and lateral 3D heterogeneity in porosity and porosity-dependent hydrate saturation and intrinsic permeability. Gas production potential was estimated using a conventional vertical wellbore completion and a deviated toe-down wellbore perforated through both sand units to induce hydrate depressurization at a constant bottom-hole pressure. The results have shown the greater performance of the deviated well design over the vertical one. The scenarios involving simultaneous and sequential hydrate dissociation in sand units were explored and the effect of the underlying aquifer in the C sand was estimated. Sensitivity analysis has demonstrated that hydraulic communication with over- and underlying shale units affects production in the beginning of depressurization due to competitive water influx into producing mobile flow and could suppress efficient hydrate decomposition resulting in production lag. Another important factor greatly influencing the productivity performance is the effective permeability of hydrate-bearing sediment controlled by the relative permeability function. The results call for the necessity of thorough fundamental studies to understand multi-phase flow in hydrate-bearing sediments with different hydrate precipitation habits.

  5. Characterization and Prediction of the Gas Hydrate Reservoir at the Second Offshore Gas Production Test Site in the Eastern Nankai Trough, Japan

    Directory of Open Access Journals (Sweden)

    Machiko Tamaki

    2017-10-01

    Full Text Available Following the world’s first offshore production test that was conducted from a gas hydrate reservoir by a depressurization technique in 2013, the second offshore production test has been planned in the eastern Nankai Trough. In 2016, the drilling survey was performed ahead of the production test, and logging data that covers the reservoir interval were newly obtained from three wells around the test site: one well for geological survey, and two wells for monitoring surveys, during the production test. The formation evaluation using the well log data suggested that our target reservoir has a more significant heterogeneity in the gas hydrate saturation distribution than we expected, although lateral continuity of sand layers is relatively good. To evaluate the spatial distribution of gas hydrate, the integration analysis using well and seismic data was performed. The seismic amplitude analysis supports the lateral reservoir heterogeneity that has a significant positive correlation with the resistivity log data at the well locations. The spatial distribution of the apparent low-resistivity interval within the reservoir observed from log data was investigated by the P-velocity volume derived from seismic inversion. The integrated results were utilized for the pre-drill prediction of the reservoir quality at the producing wells. These approaches will reduce the risk of future commercial production from the gas hydrate reservoir.

  6. Thick massive gas hydrate deposits were revealed by LWD in Off-Joetsu area, eastern margin of Japan Sea.

    Science.gov (United States)

    Tanahashi, M.; Morita, S.; Matsumoto, R.

    2016-12-01

    GR14 and HR15 survey cruises, which were dedicated to the LWD (Logging While Drilling), were carried out in summers of 2014 and 2015, respectively, by Meiji University and Geological Survey of Japan, AIST to explore the "gas chimney" structures in eastern margin of Japan Sea. Shallow (33 to 172m-bsf, average 136m-bsf) 33 LWD drilling were performed in Oki Trough, Off-Joetsu, and Mogami Trough areas along eastern margin of Japan Sea during two cruises. Schlumberger LWD tools, GeoVISION (resistivity), TeleScope, ProVISION (NMR) and SonicVISION were used during GR14. NeoScope (neutron) was added and SonicScope was replaced for SonicVISION during HR14. The data quality was generally good. "Gas chimney" structures with acoustic blanking columns on the high frequency seismic sections with mound and pockmark morphologic features on the sea bottom, are well developed within survey areas. Every LWD records taken from gas chimney structures during the cruises show high resistivity and acoustic velocity anomalies which suggest the development of gas hydrate. Characteristic development of massive gas hydrate was interpreted at the Umitaka CW mound structure, Off-Joetsu. The mound lies at 890-910m in water depth and has very rough bottom surface, regional high resistivity, regional high heat flow, several natural seep sites, 200m x 300m area, and 10-20m height. 8 LWD holes, J18L to J21L and J23L to J26L, were drilled on and around the mound. There are highly anomalous intervals which suggest the development of massive gas hydrate at J24L, with high resistivity, high Vp and Vs, high neutron porosity, low natural gamma ray intensity, low neutron gamma density, low NMR porosity, low NMR permeability, low formation sigma, from 10 to 110m-bsf with intercalating some thin less hydrate layers. It is interpreted that there is several tens of meter thick massive gas hydrate in the gas chimney mound. It is partly confirmed by the later nearby coring result which showed the repetition of

  7. Gas hydrates stability zone thickness map of Indian deep offshore areas - A GIS based approach

    Digital Repository Service at National Institute of Oceanography (India)

    Rastogi, A.; Deka, B.; Bhattacharya, G.C.; Ramprasad, T.; KameshRaju, K.A.; Srinivas, K.; Murty, G.P.S.; Chaubey, A.K.; Ramana, M.V.; Subrahmanyam, V.; Sarma, K.V.L.N.S.; Desa, M.; Paropkari, A.L.; Menezes, A.A.A.; Murty, V.S.N.; Antony, M.K.; SubbaRaju, L.V.; Desa, E.; Veerayya, M.

    of gas hydrates. The required data (bathymetry, seabed temperature and geothermal gradient etc.) were obtained from published literatrue, digital data bases and unpublished source. These data were supplemented with predicted values, in areas having...

  8. Identification of Reservoir Thickness and Estimation of Hydrocarbon Reservation used the Pre-Stack Depth Migration (PSDM in Cikung Area

    Directory of Open Access Journals (Sweden)

    Sudra Irawan

    2017-05-01

    Full Text Available Information from the geological data shows that the Cikung field has the complex structure which is characterized by carbonate reef. Therefore, it is required in the domain depth migration (PSDM using interval velocity model is sensitive to variations in vertical and horizontal velocity to identify the thickness of the reservoir and estimation of hydrocarbon reserves. Stages include making the depth structure maps, map making the thickness of the reservoir, and the calculation of hydrocarbon reserves. The results showed that the thickness of the reservoir in Cikung Field, estimated to range from 71 meters to 175 meters with the prospect reservoir is at a depth of 1216 meters to 1247 meters from the surface. Hydrocarbon deposits (oil is estimated at 1,134 × 106 or 1,311 × 108 kilo litre by the porosity of 22.6% and 70.7% water saturation.

  9. The Iġnik Sikumi Field Experiment, Alaska North Slope: Design, operations, and implications for CO2−CH4 exchange in gas hydrate reservoirs

    Science.gov (United States)

    Boswell, Ray; Schoderbek, David; Collett, Timothy S.; Ohtsuki, Satoshi; White, Mark; Anderson, Brian J.

    2017-01-01

    The Iġnik Sikumi Gas Hydrate Exchange Field Experiment was conducted by ConocoPhillips in partnership with the U.S. Department of Energy, the Japan Oil, Gas and Metals National Corporation, and the U.S. Geological Survey within the Prudhoe Bay Unit on the Alaska North Slope during 2011 and 2012. The primary goals of the program were to (1) determine the feasibility of gas injection into hydrate-bearing sand reservoirs and (2) observe reservoir response upon subsequent flowback in order to assess the potential for CO2 exchange for CH4 in naturally occurring gas hydrate reservoirs. Initial modeling determined that no feasible means of injection of pure CO2 was likely, given the presence of free water in the reservoir. Laboratory and numerical modeling studies indicated that the injection of a mixture of CO2 and N2 offered the best potential for gas injection and exchange. The test featured the following primary operational phases: (1) injection of a gaseous phase mixture of CO2, N2, and chemical tracers; (2) flowback conducted at downhole pressures above the stability threshold for native CH4 hydrate; and (3) an extended (30-days) flowback at pressures near, and then below, the stability threshold of native CH4 hydrate. The test findings indicate that the formation of a range of mixed-gas hydrates resulted in a net exchange of CO2 for CH4 in the reservoir, although the complexity of the subsurface environment renders the nature, extent, and efficiency of the exchange reaction uncertain. The next steps in the evaluation of exchange technology should feature multiple well applications; however, such field test programs will require extensive preparatory experimental and numerical modeling studies and will likely be a secondary priority to further field testing of production through depressurization. Additional insights gained from the field program include the following: (1) gas hydrate destabilization is self-limiting, dispelling any notion of the potential for

  10. Well-test analysis for gas hydrate reservoirs : examination of parameters suggested by conventional analysis for the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well

    Energy Technology Data Exchange (ETDEWEB)

    Kurihara, M.; Funatsu, K. [Japan Oil Engineering Co., Tokyo (Japan); Kusaka, K.; Yasuda, M. [Japan National Oil Corp., Chiba (Japan); Dallimore, S.R. [Geological Survey of Canada, Pacific Geoscience Centre, Sidney, BC (Canada); Collett, T.S. [United States Geological Survey, Denver, CO (United States); Hancock, S.H. [APA Petroleum Engineering Ltd., Calgary, AB (Canada)

    2005-07-01

    Formation tests were conducted with a Modular Formation Dynamics Tester (MDT) tool during the Mallik 2002 Gas Hydrate Production Research Well Program. Conventional pressure-transient test analysis methods were used to analyze the test results. However, it was noted that the reliability of the reservoir-parameter estimates is uncertain due to the abrupt change in gas hydrate saturation associated with gas hydrate dissociation during the tests. In order to examine the appropriateness of these methods, the bottom-hole pressure responses during MDT tests in the hypothetical and actual gas hydrate zones were predicted using a numerical simulator. They were then analyzed by conventional test-analysis methods. It was determined that the conventional methods may indicate the average effective permeability over the area of the gas hydrate dissociation. However, the study also revealed that conventional methods might accurately indicate the radius of gas hydrate dissociation only when applying appropriate multiphase-fluid properties and production rates to the cases with high gas hydrate saturation.

  11. The genetic source and timing of hydrocarbon formation in gas hydrate reservoirs in Green Canyon, Block GC955

    Science.gov (United States)

    Moore, M. T.; Darrah, T.; Cook, A.; Sawyer, D.; Phillips, S.; Whyte, C. J.; Lary, B. A.

    2017-12-01

    Although large volumes of gas hydrates are known to exist along continental slopes and below permafrost, their role in the energy sector and the global carbon cycle remains uncertain. Investigations regarding the genetic source(s) (i.e., biogenic, thermogenic, mixed sources of hydrocarbon gases), the location of hydrocarbon generation, (whether hydrocarbons formed within the current reservoir formations or underwent migration), rates of clathrate formation, and the timing of natural gas formation/accumulation within clathrates are vital to evaluate economic potential and enhance our understanding of geologic processes. Previous studies addressed some of these questions through analysis of conventional hydrocarbon molecular (C1/C2+) and stable isotopic (e.g., δ13C-CH4, δ2H-CH4, δ13C-CO2) composition of gases, water chemistry and isotopes (e.g., major and trace elements, δ2H-H2O, δ18O-H2O), and dissolved inorganic carbon (δ13C-DIC) of natural gas hydrate systems to determine proportions of biogenic and thermogenic gas. However, the effects from contributions of mixing, transport/migration, methanogenesis, and oxidation in the subsurface can complicate the first-order application of these techniques. Because the original noble gas composition of a fluid is preserved independent of microbial activity, chemical reactions, or changes in oxygen fugacity, the integration of noble gas data can provide both a geochemical fingerprint for sources of fluids and an additional insight as to the uncertainty between effects of mixing versus post-genetic modification. Here, we integrate inert noble gases (He, Ne, Ar, and associated isotopes) with these conventional approaches to better constrain the source of gas hydrate formation and the residence time of fluids (porewaters and natural gases) using radiogenic 4He ingrowth techniques in cores from two boreholes collected as part of the University of Texas led UT-GOM2-01 drilling project. Pressurized cores were extracted from

  12. Discrete element analysis of the mechanical properties of deep-sea methane hydrate-bearing soils considering interparticle bond thickness

    Science.gov (United States)

    Jiang, Mingjing; He, Jie; Wang, Jianfeng; Zhou, Yaping; Zhu, Fangyuan

    2017-12-01

    Due to increasing global energy demands, research is being conducted on the mechanical properties of methane hydrate-bearing soils (MHBSs), from which methane hydrate (MH) will be explored. This paper presents a numerical approach to study the mechanical properties of MHBSs. The relationship between the level of MH saturation and the interparticle bond thickness is first obtained by analyzing the scanning electron microscope images of MHBS samples, in which is the bridge connecting the micromechanical behavior captured by the DEM with the macroscopic properties of MHBSs. A simplified thermal-hydromechanical (THM) bond model that considers the different bond thicknesses is then proposed to describe the contact behavior between the soil particles and those incorporated into the discrete element method (DEM). Finally, a series of biaxial compression tests are carried out with different MH saturations under different effective confining pressures to analyze the mechanical properties of deep-sea MHBSs. The results of the DEM numerical simulation are also compared with the findings from triaxial compression tests. The results show that the macromechanical properties of deep-sea MHBSs can be qualitatively captured by the proposed DEM. The shear strength, cohesion, and volumetric contraction of deep-sea MHBSs increase with increasing MH saturation, although its influence on the internal friction angle is obscure. The shear strength and volumetric contraction increase with increasing effective confining pressure. The peak shear strength and the dilation of MHBSs increase as the critical bond thickness increases, while the residual deviator stress largely remains the same at a larger axial strain. With increasing the axial strain, the percentage of broken bonds increases, along with the expansion of the shear band.

  13. An Evaluation of Common Cleaning Methodologies on the Persistence of a Clinical Isolate of Escherichia coli in Personal Hydration System Water-Reservoirs

    Science.gov (United States)

    2016-06-09

    Isolate of Escherichia coli in Personal Hydration System Water-Reservoirs CPT Stephanie Helmus DDS*, Jauchia Blythe PhD**, COL Peter Guevara DMD, MAGD...soluble cleaning tablets. The evaluation of these methods using clinical bacteria is essential given that clinical isolates are often more robust than...there environmental counterparts and given that there can be great variability in the stability of individual isolates (8). In the current study

  14. Critical pressure and multiphase flow in Blake Ridge gas hydrates

    Science.gov (United States)

    Flemings, P.B.; Liu, Xiuying; Winters, W.J.

    2003-01-01

    We use core porosity, consolidation experiments, pressure core sampler data, and capillary pressure measurements to predict water pressures that are 70% of the lithostatic stress, and gas pressures that equal the lithostatic stress beneath the methane hydrate layer at Ocean Drilling Program Site 997, Blake Ridge, offshore North Carolina. A 29-m-thick interconnected free-gas column is trapped beneath the low-permeability hydrate layer. We propose that lithostatic gas pressure is dilating fractures and gas is migrating through the methane hydrate layer. Overpressured gas and water within methane hydrate reservoirs limit the amount of free gas trapped and may rapidly export methane to the seafloor.

  15. An Evaluation of Common Cleaning Methods for the Removal of a Clinical Isolate of Escherichia coli in Personal Hydration System Water Reservoirs.

    Science.gov (United States)

    Helmus, Stephanie; Blythe, Jauchia; Guevara, Peter; Washington, Michael A

    2016-01-01

    Waterborne infection is an important cause of morbidity and mortality throughout the world. Personal hydration packs have been used by military personnel since the Gulf War and are now a common issue item. Since military personnel tend to operate under austere conditions and may use a variety of water sources, preventing the acquisition of waterborne infections is extremely important. Further, since hydration pack water reservoir replacements may not be available during combat operations, the development of a reliable cleaning protocol for use in the field is essential. Several methods for cleaning have been described. In the current study, three common cleaning methodologies-bleach treatment, baking soda treatment, and proprietary CAMELBAK Cleaning Tabs™-were evaluated for the ability to remove Escherichia coli contamination from hydration pack water reservoirs. The study results suggest that the use of bleach and proprietary CAMELBAK tablets should be encouraged since they both operate by releasing bactericidal chlorine compounds into solution, which is more effective at reducing post-treatment bacterial burden. It should be noted that no method was 100% effective at completely eliminating bacteria from the reservoirs and that mechanical cleaning was not attempted. 2016.

  16. Linking pore-scale and basin-scale effects on diffusive methane transport in hydrate bearing environments through multi-scale reservoir simulations

    Energy Technology Data Exchange (ETDEWEB)

    Nole, Michael; Daigle, Hugh; Cook, Ann; Malinverno, Alberto; Hillman, Jess

    2016-12-16

    We explore the gas hydrate-generating capacity of diffusive methane transport induced by solubility gradients due to pore size contrasts in lithologically heterogeneous marine sediments. Through the use of 1D, 2D, and 3D reactive transport simulations, we investigate scale-dependent processes in diffusion-dominated gas hydrate systems. These simulations all track a sand body, or series of sands, surrounded by clays as they are buried through the gas hydrate stability zone. Methane is sourced by microbial methanogenesis in the clays surrounding the sand layers. In 1D, simulations performed in a Lagrangian reference frame demonstrate that gas hydrate in thin sands (3.6 m thick) can occur in high saturations (upward of 70%) at the edges of sand bodies within the upper 400 meters below the seafloor. Diffusion of methane toward the center of the sand layer depends on the concentration gradient within the sand: broader sand pore size distributions with smaller median pore sizes enhance diffusive action toward the sand’s center. Incorporating downhole log- and laboratory-derived sand pore size distributions, gas hydrate saturations in the center of the sand can reach 20% of the hydrate saturations at the sand’s edges. Furthermore, we show that hydrate-free zones exist immediately above and below the sand and are approximately 5 m thick, depending on the sand-clay solubility contrast. A moving reference frame is also adopted in 2D, and the angle of gravity is rotated relative to the grid system to simulate a dipping sand layer. This is important to minimize diffusive edge effects or numerical diffusion that might be associated with a dipping sand in an Eulerian grid system oriented orthogonal to gravity. Two-dimensional simulations demonstrate the tendency for gas hydrate to accumulate downdip in a sand body because of greater methane transport at depth due to larger sand-clay solubility contrasts. In 3D, basin-scale simulations illuminate how convergent sand layers in

  17. Mathematical model of the methane replacement by carbon dioxide in the gas hydrate reservoir taking into account the diffusion kinetics

    Science.gov (United States)

    Musakaev, N. G.; Khasanov, M. K.; Rafikova, G. R.

    2018-03-01

    The problem of the replacement of methane in its hydrate by carbon dioxide in a porous medium is considered. The gas-exchange kinetics scheme is proposed in which the intensity of the process is limited by the diffusion of CO2 through the hydrate layer formed between the gas mixture flow and the CH4 hydrate. Dynamics of the main parameters of the process is numerically investigated. The main characteristic stages of the process are determined.

  18. Investigating the influence of lithologic heterogeneity on gas hydrate formation and methane recycling at the base of the gas hydrate stability zone in channelized systems

    Energy Technology Data Exchange (ETDEWEB)

    Daigle, Hugh; Nole, Michael; Cook, Ann; Malinverno, Alberto

    2017-12-14

    In marine environments, gas hydrate preferentially accumulates in coarse-grained sediments. At the meso- to micro-scale, however, hydrate distribution in these coarse-grained units is often heterogeneous. We employ a methane hydrate reservoir simulator coupling heat and mass transfer as well as capillary effects to investigate how capillary controls on methane solubility affect gas and hydrate accumulations in reservoirs characterized by graded bedding and alternating sequences of coarse-grained sands and fine-grained silt and clay. Simulations bury a channelized reservoir unit encased in homogeneous, fine-grained material characterized by small pores (150 nm) and low permeability (~1 md in the absence of hydrate). Pore sizes within each reservoir bed between vary between coarse sand and fine silt. Sands have a median pore size of 35 microns and a lognormal pore size distribution. We also investigate how the amount of labile organic carbon (LOC) affects hydrate growth due to microbial methanogenesis within the sediments. In a diffusion-dominated system, methane movies into reservoir layers along spatial gradients in dissolved methane concentration. Hydrate grows in such a way as to minimize these concentration gradients by accumulating slower in finer-grained reservoir layers and faster in coarser-grained layers. Channelized, fining-upwards sediment bodies accumulate hydrate first along their outer surfaces and thence inward from top to bottom. If LOC is present in thin beds within the channel, higher saturations of hydrate will be distributed more homogeneously throughout the unit. When buried beneath the GHSZ, gas recycling can occur only if enough hydrate is present to form a connected gas phase upon dissociation. Simulations indicate that this is difficult to achieve for diffusion-dominated systems, especially those with thick GHSZs and/or small amounts of LOC. However, capillary-driven fracturing behavior may be more prevalent in settings with thick GHSZs.

  19. Acoustic Velocity Log Numerical Simulation and Saturation Estimation of Gas Hydrate Reservoir in Shenhu Area, South China Sea

    Directory of Open Access Journals (Sweden)

    Kun Xiao

    2013-01-01

    Full Text Available Gas hydrate model and free gas model are established, and two-phase theory (TPT for numerical simulation of elastic wave velocity is adopted to investigate the unconsolidated deep-water sedimentary strata in Shenhu area, South China Sea. The relationships between compression wave (P wave velocity and gas hydrate saturation, free gas saturation, and sediment porosity at site SH2 are studied, respectively, and gas hydrate saturation of research area is estimated by gas hydrate model. In depth of 50 to 245 m below seafloor (mbsf, as sediment porosity decreases, P wave velocity increases gradually; as gas hydrate saturation increases, P wave velocity increases gradually; as free gas saturation increases, P wave velocity decreases. This rule is almost consistent with the previous research result. In depth of 195 to 220 mbsf, the actual measurement of P wave velocity increases significantly relative to the P wave velocity of saturated water modeling, and this layer is determined to be rich in gas hydrate. The average value of gas hydrate saturation estimated from the TPT model is 23.2%, and the maximum saturation is 31.5%, which is basically in accordance with simplified three-phase equation (STPE, effective medium theory (EMT, resistivity log (Rt, and chloride anomaly method.

  20. Hydrodynamic thickness of petroleum oil adsorbed layers in the pores of reservoir rocks.

    Science.gov (United States)

    Alkafeef, Saad F; Algharaib, Meshal K; Alajmi, Abdullah F

    2006-06-01

    The hydrodynamic thickness delta of adsorbed petroleum (crude) oil layers into the pores of sandstone rocks, through which the liquid flows, has been studied by Poiseuille's flow law and the evolution of (electrical) streaming current. The adsorption of petroleum oil is accompanied by a numerical reduction in the (negative) surface potential of the pore walls, eventually stabilizing at a small positive potential, attributed to the oil macromolecules themselves. After increasing to around 30% of the pore radius, the adsorbed layer thickness delta stopped growing either with time or with concentrations of asphaltene in the flowing liquid. The adsorption thickness is confirmed with the blockage value of the rock pores' area determined by the combination of streaming current and streaming potential measurements. This behavior is attributed to the effect on the disjoining pressure across the adsorbed layer, as described by Derjaguin and Churaev, of which the polymolecular adsorption films lose their stability long before their thickness has approached the radius of the rock pore.

  1. Final Scientific/Technical Report: Characterizing the Response of the Cascadia Margin Gas Hydrate Reservoir to Bottom Water Warming Along the Upper Continental Slope

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, Evan A. [Univ. of Washington, Seattle, WA (United States); Johnson, H. Paul [Univ. of Washington, Seattle, WA (United States); Salmi, Marie [Univ. of Washington, Seattle, WA (United States); Whorley, Theresa [Univ. of Washington, Seattle, WA (United States)

    2017-11-10

    continental shelf at water depths <180 m and at the upper limit of methane hydrate stability along the Washington margin. 5) The majority of the seeps cored during the 2014 research expedition on the R/V Thompson contained abundant authigenic carbonate indicating that they are locations of long-lived seepage rather than emergent seep systems related to methane hydrate dissociation. Despite the evidence for enhanced methane seepage at the upper limit of methane hydrate stability along the Washington margin, we found no unequivocal evidence for active methane hydrate dissociation as a source of fluid and gas at the seeps surveyed. The pore fluid and bottom water chemistry shows that the seeps are fed by a variety of fluid and methane sources, but that methane hydrate dissociation, if occurring, is not widespread and is only a minor source (below the detection limit of our methods). Collectively, these results provide a significant advance in our understanding of the thermal structure of the Cascadia subduction zone and the fluid and methane sources feeding seeps along the upper continental slope of the Washington-sector of the Cascadia margin. Though we did not find unequivocal evidence for methane hydrate dissociation as a source of water and methane at the upper pressure-temperature limit of methane hydrate stability at present, continued warming of North Pacific Intermediate Water in the future has the potential to impact the methane hydrate reservoir in sediments at greater depths along the slope. Thus, this study provides a strong foundation and the necessary characterization of the background state of seepage at the upper limit of methane hydrate stability for future investigations of this important process.

  2. Mathematical Model and Simulation of Gas Hydrate Reservoir Decomposition by Depressurization Modèle mathématique et simulation de dépressurisation et de décompression d’un réservoir d’hydrates de méthane

    Directory of Open Access Journals (Sweden)

    Zhao J.

    2012-05-01

    Full Text Available The numerical model for the depressurization of methane hydrates in a confined reservoir is presented based on mass conservation in porous media, incorporating multiphase flow theory and kinetics of gas hydrate dissociation. The universal implicit difference method is adopted, and the corresponding computer program is developed. During the production of the hydrate reservoir, distribution and the physical changes are analyzed and the gas hydrate dissociation and gas production law are studied from the computation. A numerical simulation shows that the reservoir pressure is descending slowly, which benefits the stabilization of the reservoir and inevitably decreases the efficiency in the production of gas hydrates in the depressurizing process. The gas production rate is controlled by the well pressure. The results are presented to show how this model may be used to estimate a lower downhole pressure of the well for hydrate recovery and how these results depend on reservoir and hydrate properties. Le modèle numérique présenté ici simule la dépressurisation d’hydrates de méthane dans un réservoir confiné; il se base sur le principe de conservation de la masse en milieu poreux, en intégrant la théorie de l’écoulement polyphasique et la cinétique de dissociation des hydrates de méthane. La méthode implicite et universelle des différences finies est utilisée et le programme informatique qui s’y rapporte est développé. Lors de l’exploitation du réservoir d’hydrates de méthane, la répartition et les changements physiques sont analysés et les lois sur la dissociation des hydrates de méthane et la production de gaz sont étudiées à partir des calculs. Une simulation numérique montre que la pression dans le réservoir diminue lentement, ce qui permet au réservoir de se stabiliser et diminue inévitablement le rendement de l’exploitation d’hydrates de méthane lors du processus de dépressurisation. Le rythme de

  3. Central Corneal Thickness Considered an Index of Corneal Hydration of the UVB Irradiated Rabbit Cornea as Influenced by UVB Absorber

    Czech Academy of Sciences Publication Activity Database

    Čejka, Čestmír; Luyckx, J.; Čejková, Jitka

    2012-01-01

    Roč. 61, č. 3 (2012), s. 299-306 ISSN 0862-8408 Institutional research plan: CEZ:AV0Z50390512 Keywords : UVB irradiation * corneal thickness * pachymetry Subject RIV: FF - HEENT, Dentistry Impact factor: 1.531, year: 2012

  4. Gas hydrate in nature

    Science.gov (United States)

    Ruppel, Carolyn D.

    2018-01-17

    Gas hydrate is a naturally occurring, ice-like substance that forms when water and gas combine under high pressure and at moderate temperatures. Methane is the most common gas present in gas hydrate, although other gases may also be included in hydrate structures, particularly in areas close to conventional oil and gas reservoirs. Gas hydrate is widespread in ocean-bottom sediments at water depths greater than 300–500 meters (m; 984–1,640 feet [ft]) and is also present in areas with permanently frozen ground (permafrost). Several countries are evaluating gas hydrate as a possible energy resource in deepwater or permafrost settings. Gas hydrate is also under investigation to determine how environmental change may affect these deposits.

  5. Modelling Changes in the Global Methane Hydrate Inventory

    Science.gov (United States)

    Hunter, S. J.; Goldobin, D.; Haywood, A. M.; Rees, J. G.; Ridgwell, A. J.; Brilliantov, N.; Jackson, P.; Rochelle, C.; Lovell, M.; Levesley, J.

    2010-12-01

    We present initial results from a study designed to investigate how the global methane hydrate reservoir has changed during the last interglacial-glacial cycle. Bottom water conditions through the last 120 kyr are derived from a series of long-integration snapshot-type HadCM3 GCM experiments (Singarayer and Valdes, 2009), these are then used to drive a modified 1-d time-dependent hydrate model (Davie and Buffett, 2003). The hydrate model is first evaluated using sensitivity experiments against a number of hydrate bearing ODP/DSDP sites. We then explore the potential initial-state hydrate inventory using Pliocene boundary conditions and compare against a modelled and previously published modern-day inventories. Using modelled bottom water conditions and a thermal diffusion model, changes in the hydrate stability zone thickness though the last 120 kyr are investigated. We consider the timing and potential role of hydrate disassociation in the triggering of submarine landslides. Finally, the glacial cycle modelling strategy is discussed and preliminary results of the transient hydrate model run are presented. We aim to use these models and simulations to investigate potential changes in the volume and stability of the marine reservoir through many pseudo glacial-cycles as a precursor to running the model forward through potential climate change scenarios. References: J. S. Singarayer, P. J. Valdes, (2009) High-latitude climate sensitivity to ice-sheet forcing over the last 120 kyr, QSR v. 29 (1-2), p. 43-55 M. K. Davie, B. A. Buffett, (2003) Sources of methane for marine gas hydrate: inferences from a comparison of observations and numerical models, EPSL v. 206, p. 51-63

  6. Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Hutchinson, D.R. (USGS); Shelander, D. (Schlumberger, Houston, TX); Dai, J. (Schlumberger, Hoston, TX); McConnell, D. (AOA Geophysics, Inc., Houston, TX); Shedd, W. (Minerals Management Service); Frye, M. (Minerals Management Service); Ruppel, C. (USGS); Boswell, R.; Jones, E. (Chevron Energy Technology Corp., Houston, TX); Collett, T.S. (USGS); Rose, K.; Dugan, B. (Rice Univ., Houston, TX); Wood, W. (U.S. Naval Research Laboratory); Latham, T. (Chevron Energy Technology Corp., Houston, TX)

    2008-07-01

    In the late spring of 2008, the Chevron-led Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) expects to conduct an exploratory drilling and logging campaign to better understand gas hydrate-bearing sands in the deepwater Gulf of Mexico. The JIP Site Selection team selected three areas to test alternative geological models and geophysical interpretations supporting the existence of potential high gas hydrate saturations in reservoir-quality sands. The three sites are near existing drill holes which provide geological and geophysical constraints in Alaminos Canyon (AC) lease block 818, Green Canyon (GC) 955, and Walker Ridge (WR) 313. At the AC818 site, gas hydrate is interpreted to occur within the Oligocene Frio volcaniclastic sand at the crest of a fold that is shallow enough to be in the hydrate stability zone. Drilling at GC955 will sample a faulted, buried Pleistocene channel-levee system in an area characterized by seafloor fluid expulsion features, structural closure associated with uplifted salt, and abundant seismic evidence for upward migration of fluids and gas into the sand-rich parts of the sedimentary section. Drilling at WR313 targets ponded sheet sands and associated channel/levee deposits within a minibasin, making this a non-structural play. The potential for gas hydrate occurrence at WR313 is supported by shingled phase reversals consistent with the transition from gas-charged sand to overlying gas-hydrate saturated sand. Drilling locations have been selected at each site to 1) test geological methods and models used to infer the occurrence of gas hydrate in sand reservoirs in different settings in the northern Gulf of Mexico; 2) calibrate geophysical models used to detect gas hydrate sands, map reservoir thicknesses, and estimate the degree of gas hydrate saturation; and 3) delineate potential locations for subsequent JIP drilling and coring operations that will collect samples for comprehensive physical property, geochemical and other

  7. Methane Hydrates: Chapter 8

    Science.gov (United States)

    Boswell, Ray; Yamamoto, Koji; Lee, Sung-Rock; Collett, Timothy S.; Kumar, Pushpendra; Dallimore, Scott

    2008-01-01

    Gas hydrate is a solid, naturally occurring substance consisting predominantly of methane gas and water. Recent scientific drilling programs in Japan, Canada, the United States, Korea and India have demonstrated that gas hydrate occurs broadly and in a variety of forms in shallow sediments of the outer continental shelves and in Arctic regions. Field, laboratory and numerical modelling studies conducted to date indicate that gas can be extracted from gas hydrates with existing production technologies, particularly for those deposits in which the gas hydrate exists as pore-filling grains at high saturation in sand-rich reservoirs. A series of regional resource assessments indicate that substantial volumes of gas hydrate likely exist in sand-rich deposits. Recent field programs in Japan, Canada and in the United States have demonstrated the technical viability of methane extraction from gas-hydrate-bearing sand reservoirs and have investigated a range of potential production scenarios. At present, basic reservoir depressurisation shows the greatest promise and can be conducted using primarily standard industry equipment and procedures. Depressurisation is expected to be the foundation of future production systems; additional processes, such as thermal stimulation, mechanical stimulation and chemical injection, will likely also be integrated as dictated by local geological and other conditions. An innovative carbon dioxide and methane swapping technology is also being studied as a method to produce gas from select gas hydrate deposits. In addition, substantial additional volumes of gas hydrate have been found in dense arrays of grain-displacing veins and nodules in fine-grained, clay-dominated sediments; however, to date, no field tests, and very limited numerical modelling, have been conducted with regard to the production potential of such accumulations. Work remains to further refine: (1) the marine resource volumes within potential accumulations that can be

  8. Dongsha Area Gas-hydrate Petroleum System in northern Slope of the South China Sea

    Science.gov (United States)

    Pibo, Su; Zhibin, Sha

    2015-04-01

    In recent years, significant progress has been made in addressing key issues on the formation, occurrence,and stability of gas hydrate in nature. The concept of a gas-hydrate petroleum system, similar to the system that guides current conventional oil and gas exploration,is gaining acceptance.A gas-hydrate petroleum systems model is a digital data model of a gas-hydrate petroleum system in which the interrelated processes and their results can be simulated by numerical modeling.A new module of gas-hydrate petroleum system simulating can predict the thickness of the gas hydrate stability field, the generation and migration of biogenic and thermogenic methane gas,and its accumulation as gas hydrates in gas hydrate stability field. Dongsha area is located to eastern part of the Pearl River Mouth basin, and is one of the key hydrate-exploration areas in China. However, the gas hydrate petroleum system and basin modeling in Dongsha area haven't been paid enough attention. In the paper,geological conditions for gas hydrate formation have been naturally prepared on the Dong sha area.The paper first analyzed the geological-tectonic conditions of gas hydrate formation in Dongsha area,and selected the typical sections in Dong sha uplift area and southwest taiwan basin.The geological models of gas hydrate reservoir in the two study area were constructed through the typical seismic image.The typical seismic lines are obtained from the two study area by Guangzhou Marine Geological Survey.In combination with physical,thermal and geochemical data,the match condition of gas hydrate formation was studied.by sedimentary basin simulation technique.The research results is as followed:1.In southwest taiwan basin Basin, thermal developing history is low in deep department stratum,Source of gas of hydrate come from shallower biogenic gas;2.In Dongsha uplift areas,the thickness of Cenozoic is thin and the Sediment is limited,so biogenic gas was scarce,Source of gas of hydrate come from a

  9. High-resolution well-log derived dielectric properties of gas-hydrate-bearing sediments, Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

    Science.gov (United States)

    Sun, Y.; Goldberg, D.; Collett, T.; Hunter, R.

    2011-01-01

    A dielectric logging tool, electromagnetic propagation tool (EPT), was deployed in 2007 in the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert Well), North Slope, Alaska. The measured dielectric properties in the Mount Elbert well, combined with density log measurements, result in a vertical high-resolution (cm-scale) estimate of gas hydrate saturation. Two hydrate-bearing sand reservoirs about 20 m thick were identified using the EPT log and exhibited gas-hydrate saturation estimates ranging from 45% to 85%. In hydrate-bearing zones where variation of hole size and oil-based mud invasion are minimal, EPT-based gas hydrate saturation estimates on average agree well with lower vertical resolution estimates from the nuclear magnetic resonance logs; however, saturation and porosity estimates based on EPT logs are not reliable in intervals with substantial variations in borehole diameter and oil-based invasion.EPT log interpretation reveals many thin-bedded layers at various depths, both above and below the thick continuous hydrate occurrences, which range from 30-cm to about 1-m thick. Such thin layers are not indicated in other well logs, or from the visual observation of core, with the exception of the image log recorded by the oil-base microimager. We also observe that EPT dielectric measurements can be used to accurately detect fine-scale changes in lithology and pore fluid properties of hydrate-bearing sediments where variation of hole size is minimal. EPT measurements may thus provide high-resolution in-situ hydrate saturation estimates for comparison and calibration with laboratory analysis. ?? 2010 Elsevier Ltd.

  10. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    Energy Technology Data Exchange (ETDEWEB)

    Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

    2005-02-01

    part of the Ugnu and throughout the West Sak. No hydrate-bearing zones were identified either in recovered core or on well logs. The base of the permafrost was found at about 1260 ft. With the exception of the deepest sands in the West Sak and some anomalous thin, tight zones, all sands recovered (after thawing) are unconsolidated with high porosity and high permeability. At 800 psi, Ugnu sands have an average porosity of 39.3% and geometrical mean permeability of 3.7 Darcys. Average grain density is 2.64 g/cc. West Sak sands have an average porosity of 35.5%, geometrical mean permeability of 0.3 Darcys, and average grain density of 2.70 g/cc. There were several 1-2 ft intervals of carbonate-cemented sandstone recovered from the West Sak. These intervals have porosities of only a few percent and very low permeability. On a well log they appear as resistive with a high sonic velocity. In shallow sections of other wells these usually are the only logs available. Given the presence of gas in Hot Ice No. 1, if only resistivity and sonic logs and a mud log had been available, tight sand zones may have been interpreted as containing hydrates. Although this finding does not imply that all previously mapped hydrate zones are merely tight sands, it does add a note of caution to the practice of interpreting the presence of hydrates from old well information. The methane hydrate stability zone below the Hot Ice No. 1 location includes thick sections of sandstone and conglomerate which would make excellent reservoir rocks for hydrates and below the permafrost zone shallow gas. The Ugnu formation comprises a more sand-rich section than does the West Sak formation, and the Ugnu sands when cleaned and dried are slightly more porous and significantly more permeable than the West Sak.

  11. Regional long-term production modeling from a single well test, Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

    Science.gov (United States)

    Anderson, B.J.; Kurihara, M.; White, M.D.; Moridis, G.J.; Wilson, S.J.; Pooladi-Darvish, M.; Gaddipati, M.; Masuda, Y.; Collett, T.S.; Hunter, R.B.; Narita, H.; Rose, K.; Boswell, R.

    2011-01-01

    Following the results from the open-hole formation pressure response test in the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert well) using Schlumberger's Modular Dynamics Formation Tester (MDT) wireline tool, the International Methane Hydrate Reservoir Simulator Code Comparison project performed long-term reservoir simulations on three different model reservoirs. These descriptions were based on 1) the Mount Elbert gas hydrate accumulation as delineated by an extensive history-matching exercise, 2) an estimation of the hydrate accumulation near the Prudhoe Bay L-pad, and 3) a reservoir that would be down-dip of the Prudhoe Bay L-pad and therefore warmer and deeper. All of these simulations were based, in part, on the results of the MDT results from the Mount Elbert Well. The comparison group's consensus value for the initial permeability of the hydrate-filled reservoir (k = 0.12 mD) and the permeability model based on the MDT history match were used as the basis for subsequent simulations on the three regional scenarios. The simulation results of the five different simulation codes, CMG STARS, HydrateResSim, MH-21 HYDRES, STOMP-HYD, and TOUGH+HYDRATE exhibit good qualitative agreement and the variability of potential methane production rates from gas hydrate reservoirs is illustrated. As expected, the predicted methane production rate increased with increasing in situ reservoir temperature; however, a significant delay in the onset of rapid hydrate dissociation is observed for a cold, homogeneous reservoir and it is found to be repeatable. The inclusion of reservoir heterogeneity in the description of this cold reservoir is shown to eliminate this delayed production. Overall, simulations utilized detailed information collected across the Mount Elbert reservoir either obtained or determined from geophysical well logs, including thickness (37 ft), porosity (35%), hydrate saturation (65%), intrinsic permeability (1000 mD), pore water

  12. Regional long-term production modeling from a single well test, Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Brian J.; Kurihara, Masanori; White, Mark D.; Moridis, George J.; Wilson, Scott J.; Pooladi-Darvish, Mehran; Gaddipati, Manohar; Masuda, Yoshihiro; Collett, Timothy S.; Hunter, Robert B.; Narita, Hideo; Rose, Kelly; Boswell, Ray

    2011-02-01

    Following the results from the open-hole formation pressure response test in the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert well) using Schlumberger's Modular Dynamics Formation Tester (MDT) wireline tool, the International Methane Hydrate Reservoir Simulator Code Comparison project performed long-term reservoir simulations on three different model reservoirs. These descriptions were based on 1) the Mount Elbert gas hydrate accumulation as delineated by an extensive history-matching exercise, 2) an estimation of the hydrate accumulation near the Prudhoe Bay L-pad, and 3) a reservoir that would be down-dip of the Prudhoe Bay L-pad and therefore warmer and deeper. All of these simulations were based, in part, on the results of the MDT results from the Mount Elbert Well. The comparison group's consensus value for the initial permeability of the hydrate-filled reservoir (k = 0.12 mD) and the permeability model based on the MDT history match were used as the basis for subsequent simulations on the three regional scenarios. The simulation results of the five different simulation codes, CMG STARS, HydrateResSim, MH-21 HYDRES, STOMP-HYD, and TOUGH+HYDRATE exhibit good qualitative agreement and the variability of potential methane production rates from gas hydrate reservoirs is illustrated. As expected, the predicted methane production rate increased with increasing in situ reservoir temperature; however, a significant delay in the onset of rapid hydrate dissociation is observed for a cold, homogeneous reservoir and it is found to be repeatable. The inclusion of reservoir heterogeneity in the description of this cold reservoir is shown to eliminate this delayed production. Overall, simulations utilized detailed information collected across the Mount Elbert reservoir either obtained or determined from geophysical well logs, including thickness (37 ft), porosity (35%), hydrate saturation (65%), intrinsic permeability (1000 mD), pore

  13. Hydrated-ion ordering in electrical double layers.

    Science.gov (United States)

    Espinosa-Marzal, Rosa M; Drobek, Tanja; Balmer, Tobias; Heuberger, Manfred P

    2012-05-07

    In this work we revisit the surface forces measured between two atomically flat mica surfaces submerged in a reservoir of potassium nitrate (KNO(3)) solution. We consider a comprehensive range of concentrations from 0.08 mM to 2.6 M. The significantly improved resolution available from the extended surface force apparatus (eSFA) allows the distinction of hydration structures and hydrated-ion correlations. Above concentrations of 0.3 mM, hydrated-ion correlations give rise to multiple collective transitions (4 ± 1 Å) in the electrical double layers upon interpenetration. These features are interpreted as the result of hydrated-ion ordering (e.g. layering), in contrast to the traditional interpretation invoking water layering. The hydrated-ion layer adjacent to the surface (i.e. outer Helmholtz layer) is particularly well defined and plays a distinctive role. It can be either collectively expelled in a 5.8 ± 0.3 Å film-thickness transition or collectively forced to associate with the surface by external mechanical work. The latter is observed as a characteristic 2.9 ± 0.3 Å film-thickness transition along with an abrupt decrease of surface adhesion at concentrations above 1 mM. At concentrations as low as 20 mM, attractive surface forces are measured in deviation to the DLVO theory. The hydration number in the confined electrolyte seems to be significantly below that of the bulk. A 1-3 nm thick ionic layer solidifies at the surfaces at concentrations >100 mM, i.e. below bulk saturation.

  14. Methane Production and Carbon Capture by Hydrate Swapping

    DEFF Research Database (Denmark)

    Mu, Liang; von Solms, Nicolas

    2017-01-01

    There are essentially two different approaches to producing methane from natural gas hydrate reservoirs, either bring the hydrate out of its thermodynamic stability region or expose the hydrate to a substance that will form a more stable hydrate structure, forcing an in situ swapping of the trapped...... in small hydrate cages, as long as the equilibrium formation pressure of (CO2 + N2) binary gas hydrate is below that of methane hydrate, even though adding nitrogen to carbon dioxide reduces the thermodynamic driving force for the formation of a new hydrate. When other conditions are similar, the methane...

  15. Evaluation of gas production potential from gas hydrate deposits in National Petroleum Reserve Alaska using numerical simulations

    Science.gov (United States)

    Nandanwar, Manish S.; Anderson, Brian J.; Ajayi, Taiwo; Collett, Timothy S.; Zyrianova, Margarita V.

    2016-01-01

    An evaluation of the gas production potential of Sunlight Peak gas hydrate accumulation in the eastern portion of the National Petroleum Reserve Alaska (NPRA) of Alaska North Slope (ANS) is conducted using numerical simulations, as part of the U.S. Geological Survey (USGS) gas hydrate Life Cycle Assessment program. A field scale reservoir model for Sunlight Peak is developed using Advanced Processes & Thermal Reservoir Simulator (STARS) that approximates the production design and response of this gas hydrate field. The reservoir characterization is based on available structural maps and the seismic-derived hydrate saturation map of the study region. A 3D reservoir model, with heterogeneous distribution of the reservoir properties (such as porosity, permeability and vertical hydrate saturation), is developed by correlating the data from the Mount Elbert well logs. Production simulations showed that the Sunlight Peak prospect has the potential of producing 1.53 × 109 ST m3 of gas in 30 years by depressurization with a peak production rate of around 19.4 × 104 ST m3/day through a single horizontal well. To determine the effect of uncertainty in reservoir properties on the gas production, an uncertainty analysis is carried out. It is observed that for the range of data considered, the overall cumulative production from the Sunlight Peak will always be within the range of ±4.6% error from the overall mean value of 1.43 × 109 ST m3. A sensitivity analysis study showed that the proximity of the reservoir from the base of permafrost and the base of hydrate stability zone (BHSZ) has significant effect on gas production rates. The gas production rates decrease with the increase in the depth of the permafrost and the depth of BHSZ. From the overall analysis of the results it is concluded that Sunlight Peak gas hydrate accumulation behaves differently than other Class III reservoirs (Class III reservoirs are composed of a single layer of hydrate with no

  16. Energy resource potential of natural gas hydrates

    Science.gov (United States)

    Collett, T.S.

    2002-01-01

    The discovery of large gas hydrate accumulations in terrestrial permafrost regions of the Arctic and beneath the sea along the outer continental margins of the world's oceans has heightened interest in gas hydrates as a possible energy resource. However, significant to potentially insurmountable technical issues must be resolved before gas hydrates can be considered a viable option for affordable supplies of natural gas. The combined information from Arctic gas hydrate studies shows that, in permafrost regions, gas hydrates may exist at subsurface depths ranging from about 130 to 2000 m. The presence of gas hydrates in offshore continental margins has been inferred mainly from anomalous seismic reflectors, known as bottom-simulating reflectors, that have been mapped at depths below the sea floor ranging from about 100 to 1100 m. Current estimates of the amount of gas in the world's marine and permafrost gas hydrate accumulations are in rough accord at about 20,000 trillion m3. Disagreements over fundamental issues such as the volume of gas stored within delineated gas hydrate accumulations and the concentration of gas hydrates within hydrate-bearing strata have demonstrated that we know little about gas hydrates. Recently, however, several countries, including Japan, India, and the United States, have launched ambitious national projects to further examine the resource potential of gas hydrates. These projects may help answer key questions dealing with the properties of gas hydrate reservoirs, the design of production systems, and, most important, the costs and economics of gas hydrate production.

  17. Ground movements associated with gas hydrate production

    International Nuclear Information System (INIS)

    Siriwardane, H.J.; Kutuk, B.

    1992-03-01

    This report deals with a study directed towards a modeling effort on production related ground movements and subsidence resulting from hydrate dissociation. The goal of this research study was to evaluate whether there could be subsidence related problems that could be an impediment to hydrate production. During the production of gas from a hydrate reservoir, it is expected that porous reservoir matrix becomes more compressible which may cause reservoir compression (compaction) under the influence of overburden weight. The overburden deformations can propagate its influence upwards causing subsidence near the surface where production equipment will be located. In the present study, the reservoir compaction is modeled by using the conventional ''stress equilibrium'' approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ''cavity'' generated by reservoir depletion. The present study is expected to provide a ''lower bound'' solution to the subsidence caused by hydrate reservoir depletion. The reservoir compaction anticipated during hydrate production was modeled by using the finite element method, which is a powerful computer modeling technique. The ground movements at the reservoir roof (i.e. reservoir compression) cause additional stresses and disturbance in the overburden strata. In this study, the reservoir compaction was modeled by using the conventional ''stress equilibrium'' approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ''cavity'' generated by reservoir depletion. The resulting stresses and ground movements were computed by using the finite element method. Based on the parameters used in this investigation, the maximum ground subsidence could vary anywhere from 0.50 to 6.50 inches depending on the overburden depth and the size of the depleted hydrate reservoir

  18. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

    2009-07-15

    A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

  19. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    Science.gov (United States)

    Boswell, R.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

    2009-01-01

    A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 #1 ("Tigershark") well shows a total gas hydrate occurrence 13??m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8??km2 and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

  20. Gas Hydrate Research Site Selection and Operational Research Plans

    Science.gov (United States)

    Collett, T. S.; Boswell, R. M.

    2009-12-01

    comprehensive set of logging-while-drilling (LWD) data through expected gas-hydrate-bearing sand reservoirs in seven wells at three sites in the Gulf of Mexico. The discovery of thick hydrate-bearing sands at two of the sites drilled in the Gulf Mexico validated the integrated geological and geophysical approach used in the pre-drill site selection process to identify gas hydrate reservoirs that may be conducive to energy production. The results of the GOM JIP Leg II LWD expedition are also being used to support the selection of sites for a future drilling, logging, and coring program. Operationally, recent drilling programs, such as ODP Leg 204, IODP Expedition 311, the Japanese Toaki-oki to Kumano-nada drilling leg, the Indian NGHP Expedition 01, and the South Korean Gas Hydrate Research and Development Organization Expedition 01 have demonstrated the great benefit of a multi-leg drilling approach, including the initial acquisition of LWD data that was used to then select sites for the drilling of complex core and wireline logging test holes. It is obvious that a fully integrated site selection approach and a “goal based” operational plan, possibly including numerous drill sites and drilling legs, are required considerations for any future gas hydrate research project.

  1. Hydrate-CASM for modeling Methane Hydrate-Bearing Sediments

    Science.gov (United States)

    De La Fuente Ruiz, M.; Vaunat, J.; Marin Moreno, H.

    2017-12-01

    A clear understanding of the geomechanical behavior of methane hydrate-bearing sediments (MHBS) is crucial to assess the stability of the seafloor and submarine infrastructures to human and natural loading changes. Here we present the Hydrate-CASM, a new elastoplastic constitutive model to predict the geomechanical behavior of MHBS. Our model employs the critical state model CASM (Clay and Sand Model) because of its flexibility in describing the shape of the yield surface and its proven ability to predict the mechanical behavior of sands, the most commercially viable hydrate reservoirs. The model considers MHBS as a deformable elastoplastic continuum, and hydrate-related changes in the stress-strain behavior are predicted by a densification mechanism. The densification attributes the mechanical contribution of hydrate to; a reduction of the available void ratio; a decrease of the swelling line slope; and an increase of the volumetric yield stress. It is described by experimentally derived physical parameters except from the swelling slope coefficient that requires empirical calibration. The Hydrate-CASM is validated against published triaxial laboratory tests performed at different confinement stresses, hydrate saturations, and hydrate morphologies. During the validation, we focused on capturing the mechanical behavior of the host sediment and consider perturbations of the sediment's mechanical properties that could result from the sample preparation. Our model successfully captures the experimentally observed influence of hydrate saturation in the magnitude and trend of the stiffness, shear strength, and dilatancy of MHBS. Hence, we propose that hydrate-related densification changes might be a major factor controlling the geomechanical response of MHBS.

  2. Geomechanical property of gas hydrate sediment in the Nankai trough

    Energy Technology Data Exchange (ETDEWEB)

    Hato, M. [Earth Remote Sensing Data Analysis Center, Tokyo (Japan); Matsuoka, T.; Ikeda, H. [Kyoto Univ., Kyoto (Japan). Dept. of Civil and Earth Resources Engineering; Inamori, T.; Saeki, T. [Japan Oil, Gas and Metals National Corp., Chiba (Japan). Technology Research Center

    2008-07-01

    Well logging data and core samples from the Nankai trough area were used to investigate the geomechanical properties and geological history of gas hydrate-bearing sediments. The Coulomb-Mohr failure criterion was used to calculate the mechanical strength of the hydrate sediments. The dynamic Young's modulus was calculated using theoretical and experimental data. The study showed that sediments below the gas hydrate later are mechanically weaker than sediments within the gas hydrate layer. The mechanical strength of the core samples was then measured both before and after dissociation. The study showed that saturated gas hydrates are 4 times stronger than gas hydrate-dissociated cores. It was concluded that hydrate-bearing sediments are mechanically stronger than non-hydrate-bearing sediments. Results of the study will be used to develop methods of predicting risk factors for sea floor deformations and well-bore collapse during gas hydrate extraction processes in hydrate reservoirs. 6 refs., 5 figs.

  3. unconventional natural gas reservoirs

    International Nuclear Information System (INIS)

    Correa G, Tomas F; Osorio, Nelson; Restrepo R, Dora P

    2009-01-01

    This work is an exploration about different unconventional gas reservoirs worldwide: coal bed methane, tight gas, shale gas and gas hydrate? describing aspects such as definition, reserves, production methods, environmental issues and economics. The overview also mentioned preliminary studies about these sources in Colombia.

  4. Chloral Hydrate

    Science.gov (United States)

    ... if you are allergic to chloral hydrate, aspirin, tartrazine (a yellow dye in some processed foods and ... in, tightly closed, and out of reach of children. Store it at room temperature, away from excess ...

  5. Study of Formation Mechanisms of Gas Hydrate

    Science.gov (United States)

    Yang, Jia-Sheng; Wu, Cheng-Yueh; Hsieh, Bieng-Zih

    2015-04-01

    Gas hydrates, which had been found in subsurface geological environments of deep-sea sediments and permafrost regions, are solid crystalline compounds of gas molecules and water. The estimated energy resources of hydrates are at least twice of that of the conventional fossil fuel in the world. Gas hydrates have a great opportunity to become a dominating future energy. In the past years, many laboratory experiments had been conducted to study chemical and thermodynamic characteristics of gas hydrates in order to investigate the formation and dissociation mechanisms of hydrates. However, it is difficult to observe the formation and dissociation of hydrates in a porous media from a physical experiment directly. The purpose of this study was to model the dynamic formation mechanisms of gas hydrate in porous media by reservoir simulation. Two models were designed for this study: 1) a closed-system static model with separated gas and water zones; this model was a hydrate equilibrium model to investigate the behavior of the formation of hydrates near the initial gas-water contact; and 2) an open-system dynamic model with a continuous bottom-up gas flow; this model simulated the behavior of gas migration and studied the formation of hydrates from flowed gas and static formation water in porous media. A phase behavior module was developed in this study for reservoir simulator to model the pressure-volume-temperature (PVT) behavior of hydrates. The thermodynamic equilibriums and chemical reactions were coupled with the phase behavior module to have functions modelling the formation and dissociation of hydrates from/to water and gas. The simulation models used in this study were validated from the code-comparison project proposed by the NETL. According to the modelling results of the closed-system static model, we found that predominated location for the formation of hydrates was below the gas-water contact (or at the top of water zone). The maximum hydrate saturation

  6. Is the Surface of Gas Hydrates Dry?

    Directory of Open Access Journals (Sweden)

    Nobuo Maeda

    2015-06-01

    Full Text Available Adhesion (cohesion and agglomeration properties of gas hydrate particles have been a key to hydrate management in flow assurance in natural gas pipelines. Despite its importance, the relevant data in the area, such as the surface energy and the interfacial energy of gas hydrates with gas and/or water, are scarce; presumably due to the experimental difficulties involved in the measurements. Here we review what is known about the surface energy and the interfacial energy of gas hydrates to date. In particular, we ask a question as to whether pre-melting can occur on the surface of gas hydrates. Surface thermodynamic analyses show that pre-melting is favoured to occur on the surface of gas hydrates, however, not sufficient data are available to assess its thickness. The effects of the existence of pre-melting layers on the cohesion and friction forces between gas hydrate particles are also discussed.

  7. Comparative Assessment of Advanced Gay Hydrate Production Methods

    Energy Technology Data Exchange (ETDEWEB)

    M. D. White; B. P. McGrail; S. K. Wurstner

    2009-06-30

    Displacing natural gas and petroleum with carbon dioxide is a proven technology for producing conventional geologic hydrocarbon reservoirs, and producing additional yields from abandoned or partially produced petroleum reservoirs. Extending this concept to natural gas hydrate production offers the potential to enhance gas hydrate recovery with concomitant permanent geologic sequestration. Numerical simulation was used to assess a suite of carbon dioxide injection techniques for producing gas hydrates from a variety of geologic deposit types. Secondary hydrate formation was found to inhibit contact of the injected CO{sub 2} regardless of injectate phase state, thus diminishing the exchange rate due to pore clogging and hydrate zone bypass of the injected fluids. Additional work is needed to develop methods of artificially introducing high-permeability pathways in gas hydrate zones if injection of CO{sub 2} in either gas, liquid, or micro-emulsion form is to be more effective in enhancing gas hydrate production rates.

  8. Gas hydrates

    Digital Repository Service at National Institute of Oceanography (India)

    Ramprasad, T.

    Fuels in India’s Energy Future. Workshop on “Alternate Fuels in India’s Energy Future”, held at Hotel International, New Delhi,19 Sept 2006 , Jointly organised by CII,ERM and British High Commission Bangs, N.L., D.S. Sawyer, X. Golovchenko... hydrates: relevance to world margin stability and climatic change, Tutorial book: Gent, Belgium, pp. 1-37. Sloan, E. D., 1998, Clathrate hydrates of natural gases. 2 nd edition: Marcel Dekker, Inc., New York, pp705. Stakes...

  9. Simulation and Characterization of Methane Hydrate Formation

    Science.gov (United States)

    Dhakal, S.; Gupta, I.

    2017-12-01

    The ever rising global energy demand dictates human endeavor to explore and exploit new and innovative energy sources. As conventional oil and gas reserves deplete, we are constantly looking for newer sources for sustainable energy. Gas hydrates have long been discussed as the next big energy resource to the earth. Its global occurrence and vast quantity of natural gas stored is one of the main reasons for such interest in its study and exploration. Gas hydrates are solid crystalline substances with trapped molecules of gas inside cage-like crystals of water molecules. Gases such as methane, ethane, propane and carbon dioxide can form hydrates but in natural state, methane hydrates are the most common. Subsurface geological conditions with high pressure and low temperature favor the formation and stability of gas hydrates. While the occurrence and potential of gas hydrates as energy source has long been studied, there are still gaps in knowledge, especially in the quantitative research of gas hydrate formation and reservoir characterization. This study is focused on exploring and understanding the geological setting in which gas hydrates are formed and the subsequent changes in rock characteristics as they are deposited. It involves the numerical simulation of methane gas flow through fault to form hydrates. The models are representative of the subsurface geologic setting of Gulf of Mexico with a fault through layers of shale and sandstone. Hydrate formation simulated is of thermogenic origin. The simulations are conducted using TOUGH+HYDRATE, a numerical code developed at the Lawrence Berkley National Laboratory for modeling multiphase flow through porous medium. Simulation results predict that as the gas hydrates form in the pores of the model, the porosity, permeability and other rock properties are altered. Preliminary simulation results have shown that hydrates begin to form in the fault zone and gradually in the sandstone layers. The increase in hydrate

  10. Effects of Geomechanical Mechanism on the Gas Production Behavior: A Simulation Study of Class-3 Type Four-Way-Closure Ridge Hydrate Deposit Offshore Southwestern Taiwan

    Science.gov (United States)

    Wu, Cheng-Yueh; Chiu, Yung-Cheng; Huang, Yi-Jyun; Hsieh, Bieng-Zih

    2017-04-01

    geophysical studies and the geo-mechanical data were analogized from Japan's hydrate production case. The first step for the geological modelling was to digitize the structure map of FWC Ridge and built a grid system for the reservoir. The formation parameters, such as formation thickness, porosity and permeability, the phase behavior parameters, rock-fluid parameters, initial conditions (including formation pressure, temperature and hydrate saturation), geo-mechanical parameters were assigned into each grid. In this case we used a horizontal well with specific operating conditions to produce water and dissociated gas from the reservoir. The sensitivity analyses on geological and geo-mechanical parameters were conducted in this study. The case of different pressure drop showed that the recovery factor (RF) was 2.50%, 13.50% and 20.47% when the pressure drop of 60%, 70% and 75% from the initial reservoir pressure was used respectively. Based on the case of pressure drop of 75% (from the initial reservoir pressure), the RF was 35.13%, 25.9%, 20.47% and 16.65% when the initial hydrate saturation of 30%, 40%, 50% and 60% was assumed respectively. The greater formation permeability, the better gas recovery. The capillary pressure had a minor affection on the gas production in this case study. The best well location was at the upper layer because of the gravity effect. For the effects of the geo-mechanics, we observed that the rock mechanisms had impacts on the final cumulative gas production. The larger the Young's Modulus and the smaller the Poisson's Ratio, the smaller the subsidence on the seabed. Our simulation results showed that the seabed subsidence in FWC Ridge was about 1 meter during the production period.

  11. Seismic-Scale Rock Physics of Methane Hydrate

    Energy Technology Data Exchange (ETDEWEB)

    Amos Nur

    2009-01-08

    We quantify natural methane hydrate reservoirs by generating synthetic seismic traces and comparing them to real seismic data: if the synthetic matches the observed data, then the reservoir properties and conditions used in synthetic modeling might be the same as the actual, in-situ reservoir conditions. This approach is model-based: it uses rock physics equations that link the porosity and mineralogy of the host sediment, pressure, and hydrate saturation, and the resulting elastic-wave velocity and density. One result of such seismic forward modeling is a catalogue of seismic reflections of methane hydrate which can serve as a field guide to hydrate identification from real seismic data. We verify this approach using field data from known hydrate deposits.

  12. Indian National Gas Hydrate Program Expedition 01 report

    Science.gov (United States)

    Collett, Timothy S.; Riedel, M.; Boswell, R.; Presley, J.; Kumar, P.; Sathe, A.; Sethi, A.; Lall, M.V.; ,

    2015-01-01

    Gas hydrate is a naturally occurring “ice-like” combination of natural gas and water that has the potential to serve as an immense resource of natural gas from the world’s oceans and polar regions. However, gas-hydrate recovery is both a scientific and a technical challenge and much remains to be learned about the geologic, engineering, and economic factors controlling the ultimate energy resource potential of gas hydrate. The amount of natural gas contained in the world’s gas-hydrate accumulations is enormous, but these estimates are speculative and range over three orders of magnitude from about 2,800 to 8,000,000 trillion cubic meters of gas. By comparison, conventional natural gas accumulations (reserves and undiscovered, technically recoverable resources) for the world are estimated at approximately 440 trillion cubic meters. Gas recovery from gas hydrate is hindered because the gas is in a solid form and because gas hydrate commonly occurs in remote Arctic and deep marine environments. Proposed methods of gas recovery from gas hydrate generally deal with disassociating or “melting” in situ gas hydrate by heating the reservoir beyond the temperature of gas-hydrate formation, or decreasing the reservoir pressure below hydrate equilibrium. The pace of energy-related gas hydrate assessment projects has accelerated over the past several years.

  13. Anaerobic oxidation of methane above gas hydrates at Hydrate Ridge, NE Pacific Ocean

    DEFF Research Database (Denmark)

    Treude, T.; Boetius, A.; Knittel, K.

    2003-01-01

    At Hydrate Ridge (HR), Cascadia convergent margin, surface sediments contain massive gas hydrates formed from methane that ascends together with fluids along faults from deeper reservoirs. Anaerobic oxidation of methane (AOM), mediated by a microbial consortium of archaea and sulfate-reducing bac......At Hydrate Ridge (HR), Cascadia convergent margin, surface sediments contain massive gas hydrates formed from methane that ascends together with fluids along faults from deeper reservoirs. Anaerobic oxidation of methane (AOM), mediated by a microbial consortium of archaea and sulfate...... oxidation was extremely low (2.1 mmol m(-2) d(-1)) and was probably due to aerobic oxidation of methane. SR was fueled largely by methane at flow-impacted sites, but exceeded AOM in some cases, most likely due to sediment heterogeneity. At the Acharax field, SR was decoupled from methane oxidation...

  14. Detection of Occupancy Differences in Methane Gas Hydrates by Raman Spectroscopy

    DEFF Research Database (Denmark)

    Hansen, Susanne Brunsgaard; Berg, Rolf W.; Stenby, Erling Halfdan

    2004-01-01

    of reservoir fluids due to plugging. Methods to prevent hydrate formation are in use, e.g. by injection of inhibitors. From environmental and security points of view an easy way to detect hydrate formation is of interest. We have tried to detect methane hydrate formation by use of Raman spectroscopy....

  15. Phase I (CATTS Theory), Phase II (Milne Point), Phase III (Hydrate Ridge)

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2009-10-31

    This study introduces a new type of cumulative seismic attribute (CATT) which quantifies gas hydrates resources in Hydrate Ridge offshore Oregon. CATT is base on case-specific transforms that portray hydrated reservoir properties. In this study we used a theoretical rock physics model to correct measured velocity log data.

  16. Mechanisms Leading to Co-Existence of Gas Hydrate in Ocean Sediments [Part 2 of 2

    Energy Technology Data Exchange (ETDEWEB)

    Bryant, Steven; Juanes, Ruben

    2011-12-31

    In this project we have sought to explain the co-existence of gas and hydrate phases in sediments within the gas hydrate stability zone. We have focused on the gas/brine interface at the scale of individual grains in the sediment. The capillary forces associated with a gas/brine interface play a dominant role in many processes that occur in the pores of sediments and sedimentary rocks. The mechanical forces associated with the same interface can lead to fracture initiation and propagation in hydrate-bearing sediments. Thus the unifying theme of the research reported here is that pore scale phenomena are key to understanding large scale phenomena in hydrate-bearing sediments whenever a free gas phase is present. Our analysis of pore-scale phenomena in this project has delineated three regimes that govern processes in which the gas phase pressure is increasing: fracturing, capillary fingering and viscous fingering. These regimes are characterized by different morphology of the region invaded by the gas. On the other hand when the gas phase pressure is decreasing, the corresponding regimes are capillary fingering and compaction. In this project, we studied all these regimes except compaction. Many processes of interest in hydrate-bearing sediments can be better understood when placed in the context of the appropriate regime. For example, hydrate formation in sub-permafrost sediments falls in the capillary fingering regime, whereas gas invasion into ocean sediments is likely to fall into the fracturing regime. Our research provides insight into the mechanisms by which gas reservoirs are converted to hydrate as the base of the gas hydrate stability zone descends through the reservoir. If the reservoir was no longer being charged, then variation in grain size distribution within the reservoir explain hydrate saturation profiles such as that at Mt. Elbert, where sand-rich intervals containing little hydrate are interspersed between intervals containing large hydrate

  17. Mechanisms Leading to Co-Existence of Gas Hydrate in Ocean Sediments [Part 1 of 2

    Energy Technology Data Exchange (ETDEWEB)

    Bryant, Steven; Juanes, Ruben

    2011-12-31

    In this project we have sought to explain the co-existence of gas and hydrate phases in sediments within the gas hydrate stability zone. We have focused on the gas/brine interface at the scale of individual grains in the sediment. The capillary forces associated with a gas/brine interface play a dominant role in many processes that occur in the pores of sediments and sedimentary rocks. The mechanical forces associated with the same interface can lead to fracture initiation and propagation in hydrate-bearing sediments. Thus the unifying theme of the research reported here is that pore scale phenomena are key to understanding large scale phenomena in hydrate-bearing sediments whenever a free gas phase is present. Our analysis of pore-scale phenomena in this project has delineated three regimes that govern processes in which the gas phase pressure is increasing: fracturing, capillary fingering and viscous fingering. These regimes are characterized by different morphology of the region invaded by the gas. On the other hand when the gas phase pressure is decreasing, the corresponding regimes are capillary fingering and compaction. In this project, we studied all these regimes except compaction. Many processes of interest in hydrate-bearing sediments can be better understood when placed in the context of the appropriate regime. For example, hydrate formation in sub-permafrost sediments falls in the capillary fingering regime, whereas gas invasion into ocean sediments is likely to fall into the fracturing regime. Our research provides insight into the mechanisms by which gas reservoirs are converted to hydrate as the base of the gas hydrate stability zone descends through the reservoir. If the reservoir was no longer being charged, then variation in grain size distribution within the reservoir explain hydrate saturation profiles such as that at Mt. Elbert, where sand-rich intervals containing little hydrate are interspersed between intervals containing large hydrate

  18. Hydrate bearing clayey sediments: Formation and gas production concepts

    KAUST Repository

    Jang, Jaewon

    2016-06-20

    Hydro-thermo-chemo and mechanically coupled processes determine hydrate morphology and control gas production from hydrate-bearing sediments. Force balance, together with mass and energy conservation analyses anchored in published data provide robust asymptotic solutions that reflect governing processes in hydrate systems. Results demonstrate that hydrate segregation in clayey sediments results in a two-material system whereby hydrate lenses are surrounded by hydrate-free water-saturated clay. Hydrate saturation can reach ≈2% by concentrating the excess dissolved gas in the pore water and ≈20% from metabolizable carbon. Higher hydrate saturations are often found in natural sediments and imply methane transport by advection or diffusion processes. Hydrate dissociation is a strongly endothermic event; the available latent heat in a reservoir can sustain significant hydrate dissociation without triggering ice formation during depressurization. The volume of hydrate expands 2-to-4 times upon dissociation or CO2single bondCH4 replacement. Volume expansion can be controlled to maintain lenses open and to create new open mode discontinuities that favor gas recovery. Pore size is the most critical sediment parameter for hydrate formation and gas recovery and is controlled by the smallest grains in a sediment. Therefore any characterization must carefully consider the amount of fines and their associated mineralogy.

  19. In-situ gas hydrate hydrate saturation estimated from various well logs at the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

    Science.gov (United States)

    Lee, M.W.; Collett, T.S.

    2011-01-01

    In 2006, the U.S. Geological Survey (USGS) completed detailed analysis and interpretation of available 2-D and 3-D seismic data and proposed a viable method for identifying sub-permafrost gas hydrate prospects within the gas hydrate stability zone in the Milne Point area of northern Alaska. To validate the predictions of the USGS and to acquire critical reservoir data needed to develop a long-term production testing program, a well was drilled at the Mount Elbert prospect in February, 2007. Numerous well log data and cores were acquired to estimate in-situ gas hydrate saturations and reservoir properties.Gas hydrate saturations were estimated from various well logs such as nuclear magnetic resonance (NMR), P- and S-wave velocity, and electrical resistivity logs along with pore-water salinity. Gas hydrate saturations from the NMR log agree well with those estimated from P- and S-wave velocity data. Because of the low salinity of the connate water and the low formation temperature, the resistivity of connate water is comparable to that of shale. Therefore, the effect of clay should be accounted for to accurately estimate gas hydrate saturations from the resistivity data. Two highly gas hydrate-saturated intervals are identified - an upper ???43 ft zone with an average gas hydrate saturation of 54% and a lower ???53 ft zone with an average gas hydrate saturation of 50%; both zones reach a maximum of about 75% saturation. ?? 2009.

  20. Swelling pressure and hydration behavior of porcine corneal stroma.

    Science.gov (United States)

    Hatami-Marbini, Hamed; Etebu, Ebitimi; Rahimi, Abdolrasol

    2013-11-01

    The aim of this study was to characterize swelling pressure-thickness, swelling pressure-hydration and hydration-thickness relations of porcine cornea. Mechanical compression tests and free swelling experiments were performed on porcine cornea. A rheometer (DHR-2, TA Instruments) with a thermally controlled fluid chamber filled with 0.9% NaCl solution was used to measure the equilibrium swelling pressure of (n = 17) corneal stromal specimens. The samples were compressed incrementally and their swelling pressure-thickness relations were obtained. In parallel to this investigation, a transient digital imaging microscope (H800-CL, American Scope Inc.), a USB autofocus camera (UM05, ViTiny), and a precision weighing scale (AGZN100, Torbal) were simultaneously used to measure the weight-thickness relation of (n = 8) corneal specimens. This experimental study gave the thickness-hydration relationship required for expressing swelling pressure measurements as a function of hydration. At the in vivo 666 ± 68 µm central corneal thickness, an average swelling pressure of 52 ± 13 mmHg and hydration of 3.36 ± 0.25 mg H2O/mg dry tissue were found. The swelling pressure was reported as functions of both tissue thickness and hydration. The average fixed charge density of ρF/F ~ 42.8 mM and dry density of 1.47±0.15 g/cm3 were found. The thickness-hydration relationship was only linear when the tissue thickness was within the range of physiological thickness. Overall, the physiological hydration and swelling pressure of the porcine cornea were within the same range of those reported previously for other mammalian corneas such as steers, rabbits and humans. Nevertheless, the thickness-hydration behavior of the porcine cornea was only similar to that of the human cornea.

  1. Simulation of Methane Recovery from Gas Hydrates Combined with Storing Carbon Dioxide as Hydrates

    Directory of Open Access Journals (Sweden)

    Georg Janicki

    2011-01-01

    Full Text Available In the medium term, gas hydrate reservoirs in the subsea sediment are intended as deposits for carbon dioxide (CO2 from fossil fuel consumption. This idea is supported by the thermodynamics of CO2 and methane (CH4 hydrates and the fact that CO2 hydrates are more stable than CH4 hydrates in a certain P-T range. The potential of producing methane by depressurization and/or by injecting CO2 is numerically studied in the frame of the SUGAR project. Simulations are performed with the commercial code STARS from CMG and the newly developed code HyReS (hydrate reservoir simulator especially designed for hydrate processing in the subsea sediment. HyReS is a nonisothermal multiphase Darcy flow model combined with thermodynamics and rate kinetics suitable for gas hydrate calculations. Two scenarios are considered: the depressurization of an area 1,000 m in diameter and a one/two-well scenario with CO2 injection. Realistic rates for injection and production are estimated, and limitations of these processes are discussed.

  2. Hydrate formation in heterogeneous sediments: To what extent does hydrate distribution record the local environmental history?

    Science.gov (United States)

    Rempel, A. W.; VanderBeek, B. P.

    2017-12-01

    deeper source region. These results hold promise for using observations of hydrate distribution within anomalous deposits, together with measured sediment properties to infer pore fluid advection rates and formation time scales during reservoir emplacement.

  3. Geomechanical Performance of Hydrate-Bearing Sediment in Offshore Environments

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Holditch; Tad Patzek; Jonny Rutqvist; George Moridis; Richard Plumb

    2008-03-31

    The objective of this multi-year, multi-institutional research project was to develop the knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate-bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus was on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. We have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. We also investigated the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. The objective of the UC Berkeley work was to develop a grain-scale model of hydrate-bearing sediments. Hydrate dissociation alters the strength of HBS. In particular, transformation of hydrate clusters into gas and liquid water weakens the skeleton and, simultaneously, reduces the effective stress by increasing the pore pressure. The large-scale objective of the study is evaluation of geomechanical stability of offshore oil and gas production infrastructure. At Lawrence Berkeley National Laboratory (LBNL), we have developed the numerical model TOUGH + Hydrate + FLAC3D to evaluate how the formation and disassociation of hydrates in seafloor sediments affects seafloor stability. Several technical papers were published using results from this model. LBNL also developed laboratory equipment and methods to produce realistic laboratory samples of sediments containing gas hydrates so that mechanical properties could be measured in the laboratory. These properties are required to run TOUGH + Hydrate + FLAC3D to evaluate seafloor stability issues. At Texas A&M University we performed a detailed literature review to determine what gas hydrate formation properties had been measured and reported in the literature. We

  4. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    Energy Technology Data Exchange (ETDEWEB)

    Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the

  5. Molecular simulation of non-equilibrium methane hydrate decomposition process

    Energy Technology Data Exchange (ETDEWEB)

    Bagherzadeh, S.Alireza; Englezos, Peter [Department of Chemical and Biological Engineering, University of British Columbia, Vancouver, British Columbia, V6T 1Z3 (Canada); Alavi, Saman, E-mail: saman.alavi@nrc-cnrc.gc.ca [Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Dr., Ottawa, Ontario, K1A 0R6 (Canada); Ripmeester, John A., E-mail: john.ripmeester@nrc-cnrc.gc.ca [Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Dr., Ottawa, Ontario, K1A 0R6 (Canada)

    2012-01-15

    Graphical abstract: Highlights: > Decomposition of methane hydrate is studied with molecular dynamics simulations. > Simulations are performed under adiabatic conditions (no thermostats). > The effects of heat and mass transfer during the decomposition are observed. > Temperature gradients are established as the hydrate decomposes. > Intrinsic reaction kinetics picture of hydrate dissociation is revisited. - Abstract: We recently performed constant energy molecular dynamics simulations of the endothermic decomposition of methane hydrate in contact with water to study phenomenologically the role of mass and heat transfer in the decomposition rate [S. Alavi, J.A. Ripmeester, J. Chem. Phys. 132 (2010) 144703]. We observed that with the progress of the decomposition front temperature gradients are established between the remaining solid hydrate and the solution phases. In this work, we provide further quantitative macroscopic and molecular level analysis of the methane hydrate decomposition process with an emphasis on elucidating microscopic details and how they affect the predicted rate of methane hydrate decomposition in natural methane hydrate reservoirs. A quantitative criterion is used to characterize the decomposition of the hydrate phase at different times. Hydrate dissociation occurs in a stepwise fashion with rows of sI cages parallel to the interface decomposing simultaneously. The correlations between decomposition times of subsequent layers of the hydrate phase are discussed.

  6. Numerical Simulation of the Depressurization Process of a Natural Gas Hydrate Reservoir: An Attempt at Optimization of Field Operational Factors with Multiple Wells in a Real 3D Geological Model

    Directory of Open Access Journals (Sweden)

    Zhixue Sun

    2016-09-01

    Full Text Available Natural gas hydrates, crystalline solids whose gas molecules are so compressed that they are denser than a typical fluid hydrocarbon, have extensive applications in the areas of climate change and the energy crisis. The hydrate deposit located in the Shenhu Area on the continental slope of the South China Sea is regarded as the most promising target for gas hydrate exploration in China. Samples taken at drilling site SH2 have indicated a high abundance of methane hydrate reserves in clay sediments. In the last few decades, with its relatively low energy cost, the depressurization gas recovery method has been generally regarded as technically feasible and the most promising one. For the purpose of a better acquaintance with the feasible field operational factors and processes which control the production behavior of a real 3D geological CH4-hydrate deposit, it is urgent to figure out the effects of the parameters such as well type, well spacing, bottom hole pressure, and perforation intervals on methane recovery. One years’ numerical simulation results show that under the condition of 3000 kPa constant bottom hole pressure, 1000 m well spacing, perforation in higher intervals and with one horizontal well, the daily peak gas rate can reach 4325.02 m3 and the cumulative gas volume is 1.291 × 106 m3. What’s more, some new knowledge and its explanation of the curve tendency and evolution for the production process are provided. Technically, one factor at a time design (OFAT and an orthogonal design were used in the simulation to investigate which factors dominate the productivity ability and which is the most sensitive one. The results indicated that the order of effects of the factors on gas yield was perforation interval > bottom hole pressure > well spacing.

  7. Fracturing Behavior of Methane-Hydrate-Bearing Sediment

    Science.gov (United States)

    Konno, Y.; Jin, Y.; Yoneda, J.; Uchiumi, T.; Shinjou, K.; Nagao, J.

    2016-12-01

    As a part of a Japanese national hydrate research program (MH21, funded by the Ministry of Economy, Trade, and Industry), we performed laboratory experiments of hydraulic fracturing in methane-hydrate-bearing sediment. Distilled water was injected into methane-hydrate-bearing sand which was artificially made in a tri-axial pressure cell. X-ray computed tomography revealed that tensile failure was occurred after a rapid drop in the injection pressure. It was found that generated fractures cause a significant increase in the effective water permeability of hydrate-bearing sand. The result contributes fundamental understanding of the accumulation mechanism of gas hydrates in sediments and shows that hydraulic fracturing is one of promising enhanced recovery methods for low-permeable gas hydrate reservoirs.

  8. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    Energy Technology Data Exchange (ETDEWEB)

    Moridis, G.J.; Collett, T.S.; Pooladi-Darvish, M.; Hancock, S.; Santamarina, C.; Boswell, R.; Kneafsey, T.; Rutqvist, J.; Kowalsky, M.; Reagan, M.T.; Sloan, E.D.; Sum, A.K.; Koh, C.

    2010-11-01

    The current paper complements the Moridis et al. (2009) review of the status of the effort toward commercial gas production from hydrates. We aim to describe the concept of the gas hydrate petroleum system, to discuss advances, requirement and suggested practices in gas hydrate (GH) prospecting and GH deposit characterization, and to review the associated technical, economic and environmental challenges and uncertainties, including: the accurate assessment of producible fractions of the GH resource, the development of methodologies for identifying suitable production targets, the sampling of hydrate-bearing sediments and sample analysis, the analysis and interpretation of geophysical surveys of GH reservoirs, well testing methods and interpretation of the results, geomechanical and reservoir/well stability concerns, well design, operation and installation, field operations and extending production beyond sand-dominated GH reservoirs, monitoring production and geomechanical stability, laboratory investigations, fundamental knowledge of hydrate behavior, the economics of commercial gas production from hydrates, and the associated environmental concerns.

  9. Methane Recovery from Hydrate-bearing Sediments

    Energy Technology Data Exchange (ETDEWEB)

    J. Carlos Santamarina; Costas Tsouris

    2011-04-30

    Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with

  10. Amplitude various angles (AVA) phenomena in thin layer reservoir: Case study of various reservoirs

    International Nuclear Information System (INIS)

    thfloor, Physics Dept., FMIPA, Institut Teknologi Bandung (Indonesia); Rock Fluid Imaging Lab., Bandung (Indonesia))" data-affiliation=" (Wave Inversion and Subsurface Fluid Imaging Research Laboratory (WISFIR), Basic Science Center A 4thfloor, Physics Dept., FMIPA, Institut Teknologi Bandung (Indonesia); Rock Fluid Imaging Lab., Bandung (Indonesia))" >Nurhandoko, Bagus Endar B.; Susilowati

    2015-01-01

    Amplitude various offset is widely used in petroleum exploration as well as in petroleum development field. Generally, phenomenon of amplitude in various angles assumes reservoir’s layer is quite thick. It also means that the wave is assumed as a very high frequency. But, in natural condition, the seismic wave is band limited and has quite low frequency. Therefore, topic about amplitude various angles in thin layer reservoir as well as low frequency assumption is important to be considered. Thin layer reservoir means the thickness of reservoir is about or less than quarter of wavelength. In this paper, I studied about the reflection phenomena in elastic wave which considering interference from thin layer reservoir and transmission wave. I applied Zoeppritz equation for modeling reflected wave of top reservoir, reflected wave of bottom reservoir, and also transmission elastic wave of reservoir. Results show that the phenomena of AVA in thin layer reservoir are frequency dependent. Thin layer reservoir causes interference between reflected wave of top reservoir and reflected wave of bottom reservoir. These phenomena are frequently neglected, however, in real practices. Even though, the impact of inattention in interference phenomena caused by thin layer in AVA may cause inaccurate reservoir characterization. The relation between classes of AVA reservoir and reservoir’s character are different when effect of ones in thin reservoir and ones in thick reservoir are compared. In this paper, I present some AVA phenomena including its cross plot in various thin reservoir types based on some rock physics data of Indonesia

  11. Artificial Hydration and Nutrition

    Science.gov (United States)

    ... Crisis Situations Pets and Animals myhealthfinder Food and Nutrition Healthy Food Choices Weight Loss and Diet Plans ... Your Health Resources Healthcare Management Artificial Hydration and Nutrition Artificial Hydration and Nutrition Share Print Patients who ...

  12. Oceanic hydrates: more questions than answers

    International Nuclear Information System (INIS)

    Laherrere, Jean

    2000-01-01

    Methane hydrates create problems by blocking pipelines and casing; they are also accused of contributing to environmental problems (e.g. global warming). Methane hydrates are also found in permafrost areas and in oceanic sediments where the necessary temperature and pressure for stability occur. Claims for the widespread occurrence in thick oceanic deposits are unfounded: apparently indirect evidence from seismic reflectors, seismic hydrocarbon indicators, logs and free samples is unreliable. At one time, hydrate was seen as a static, biogenic, continuous, huge resource but that view is changing to one of a dynamic, overpressurised, discontinuous and unreliable resource. Only Japan and India are currently showing any serious interest in hydrates. Academic research has raised more questions than answers. It is suggested that more hard exploratory evidence rather than theoretical study is required

  13. Detection and Production of Methane Hydrate

    Energy Technology Data Exchange (ETDEWEB)

    George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

    2011-12-31

    This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand

  14. The interaction of climate change and methane hydrates

    Science.gov (United States)

    Ruppel, Carolyn D.; Kessler, John D.

    2017-01-01

    Gas hydrate, a frozen, naturally-occurring, and highly-concentrated form of methane, sequesters significant carbon in the global system and is stable only over a range of low-temperature and moderate-pressure conditions. Gas hydrate is widespread in the sediments of marine continental margins and permafrost areas, locations where ocean and atmospheric warming may perturb the hydrate stability field and lead to release of the sequestered methane into the overlying sediments and soils. Methane and methane-derived carbon that escape from sediments and soils and reach the atmosphere could exacerbate greenhouse warming. The synergy between warming climate and gas hydrate dissociation feeds a popular perception that global warming could drive catastrophic methane releases from the contemporary gas hydrate reservoir. Appropriate evaluation of the two sides of the climate-methane hydrate synergy requires assessing direct and indirect observational data related to gas hydrate dissociation phenomena and numerical models that track the interaction of gas hydrates/methane with the ocean and/or atmosphere. Methane hydrate is likely undergoing dissociation now on global upper continental slopes and on continental shelves that ring the Arctic Ocean. Many factors—the depth of the gas hydrates in sediments, strong sediment and water column sinks, and the inability of bubbles emitted at the seafloor to deliver methane to the sea-air interface in most cases—mitigate the impact of gas hydrate dissociation on atmospheric greenhouse gas concentrations though. There is no conclusive proof that hydrate-derived methane is reaching the atmosphere now, but more observational data and improved numerical models will better characterize the climate-hydrate synergy in the future.

  15. Gas hydrate and humans

    Science.gov (United States)

    Kvenvolden, K.A.

    2000-01-01

    The potential effects of naturally occurring gas hydrate on humans are not understood with certainty, but enough information has been acquired over the past 30 years to make preliminary assessments possible. Three major issues are gas hydrate as (1) a potential energy resource, (2) a factor in global climate change, and (3) a submarine geohazard. The methane content is estimated to be between 1015 to 1017 m3 at STP and the worldwide distribution in outer continental margins of oceans and in polar regions are significant features of gas hydrate. However, its immediate development as an energy resource is not likely because there are various geological constraints and difficult technological problems that must be solved before economic recovery of methane from hydrate can be achieved. The role of gas hydrate in global climate change is uncertain. For hydrate methane to be an effective greenhouse gas, it must reach the atmosphere. Yet there are many obstacles to the transfer of methane from hydrate to the atmosphere. Rates of gas hydrate dissociation and the integrated rates of release and destruction of the methane in the geo/hydro/atmosphere are not adequately understood. Gas hydrate as a submarine geohazard, however, is of immediate and increasing importance to humans as our industrial society moves to exploit seabed resources at ever-greater depths in the waters of our coastal oceans. Human activities and installations in regions of gas-hydrate occurrence must take into account the presence of gas hydrate and deal with the consequences of its presence.

  16. Impact of Hydration Media on Ex Vivo Corneal Elasticity Measurements.

    Science.gov (United States)

    Dias, Janice; Ziebarth, Noël M

    2015-09-01

    To determine the effect of hydration media on ex vivo corneal elasticity. Experiments were conducted on 40 porcine eyes retrieved from an abattoir (10 eyes each for phosphate-buffered saline (PBS), balanced salt solution, Optisol, 15% dextran). The epithelium was removed, and the cornea was excised with an intact scleral rim and placed in 20% dextran overnight to restore its physiological thickness. For each hydration media, corneas were evenly divided into two groups: one with an intact scleral rim and the other without. Corneas were mounted onto a custom chamber and immersed in a hydration medium for elasticity testing. Although in each medium, corneal elasticity measurements were performed for 2 hr: at 5-min intervals for the first 30 min and then 15-min intervals for the remaining 90 min. Elasticity testing was performed using nanoindentation with spherical indenters, and Young modulus was calculated using the Hertz model. Thickness measurements were taken before and after elasticity testing. The percentage change in corneal thickness and elasticity was calculated for each hydration media group. Balanced salt solution, PBS, and Optisol showed an increase in thickness and Young moduli for corneas with and without an intact scleral rim. Fifteen percent dextran exhibited a dehydrating effect on corneal thickness and provided stable maintenance of corneal elasticity for both groups. Hydration media affects the stability of corneal thickness and elasticity measurements over time. Fifteen percent dextran was most effective in maintaining corneal hydration and elasticity, followed by Optisol.

  17. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    Energy Technology Data Exchange (ETDEWEB)

    Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

    2005-02-01

    production data and provide this information to scientists developing reservoir models and to research teams for developing future gas-hydrate projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and has been documented by the project team. This Topical Report documents drilling and coring operations and other daily activities.

  18. Formation of hydrate plug within rectangular natural gas passage

    Energy Technology Data Exchange (ETDEWEB)

    Seong, K.; Song, M.H.; Ahn, J.H.; Yoo, K.S. [Dong Guk Univ., Joong-ku, Seoul (Korea, Republic of)

    2008-07-01

    Oil and gas reservoirs in off-shore shallow areas are being depleted. At the same time, the industry is expanding its production sites into deeper waters resulting in higher pressure and lower temperature and more isolated locations. In response, connecting pipelines have been extended, but because of these pressure, temperature and distance changes in pipelines, a more favorable condition for hydrate formation is created, making the problem of flow assurance more critical for safe and economic operations at deep off-shore oil and gas production sites. Another challenge in flow assurance lies in hydrate formation and potential blockage due to hydrate plugs in gas pipelines, where no free water phase is present. This paper presented an experimental study that examined the formation and the growth of hydrates from a gas mixture of methane and propane with different moisture concentrations. The hydrates were formed in a rectangular passage cooled to temperatures below equilibrium hydrate formation temperature. The paper described the experimental procedure and apparatus that was designed and fabricated for the study. A schematic layout of the hydrate formation and plug test experimental apparatus was illustrated. The paper also described the results of two sets of experiments that were conducted. It was concluded that with enough moisture content, hydrates formed without a fresh water phase under equilibrium conditions. It was also concluded that the results of the study could be used in verifying numerical models developed to predict hydrate plugging of natural gas pipelines. 4 refs., 6 figs.

  19. Reservoir management

    International Nuclear Information System (INIS)

    Satter, A.; Varnon, J.E.; Hoang, M.T.

    1992-01-01

    A reservoir's life begins with exploration leading to discovery followed by delineation of the reservoir, development of the field, production by primary, secondary and tertiary means, and finally to abandonment. Sound reservoir management is the key to maximizing economic operation of the reservoir throughout its entire life. Technological advances and rapidly increasing computer power are providing tools to better manage reservoirs and are increasing the gap between good and neutral reservoir management. The modern reservoir management process involves goal setting, planning, implementing, monitoring, evaluating, and revising plans. Setting a reservoir management strategy requires knowledge of the reservoir, availability of technology, and knowledge of the business, political, and environmental climate. Formulating a comprehensive management plan involves depletion and development strategies, data acquisition and analyses, geological and numerical model studies, production and reserves forecasts, facilities requirements, economic optimization, and management approval. This paper provides management, engineers geologists, geophysicists, and field operations staff with a better understanding of the practical approach to reservoir management using a multidisciplinary, integrated team approach

  20. Origins of hydration lubrication.

    Science.gov (United States)

    Ma, Liran; Gaisinskaya-Kipnis, Anastasia; Kampf, Nir; Klein, Jacob

    2015-01-14

    Why is friction in healthy hips and knees so low? Hydration lubrication, according to which hydration shells surrounding charges act as lubricating elements in boundary layers (including those coating cartilage in joints), has been invoked to account for the extremely low sliding friction between surfaces in aqueous media, but not well understood. Here we report the direct determination of energy dissipation within such sheared hydration shells. By trapping hydrated ions in a 0.4-1 nm gap between atomically smooth charged surfaces as they slide past each other, we are able to separate the dissipation modes of the friction and, in particular, identify the viscous losses in the subnanometre hydration shells. Our results shed light on the origins of hydration lubrication, with potential implications both for aqueous boundary lubricants and for biolubrication.

  1. Gas hydrate nucleation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The overall aim of the project was to gain more knowledge about the kinetics of gas hydrate formation especially the early growth phase. Knowledge of kinetics of gas hydrate formation is important and measurements of gas hydrate particle size and concentration can contribute to improve this knowledge. An experimental setup for carrying out experimental studies of the nucleation and growth of gas hydrates has been constructed and tested. Multi wavelength extinction (MWE) was the experimental technique selected for obtaining particle diameter and concentration. The principle behind MWE is described as well as turbidity spectrum analysis that in an initial stage of the project was considered as an alternative experimental technique. Details of the experimental setup and its operation are outlined. The measuring cell consists of a 1 litre horizontal tube sustaining pressures up to 200 bar. Laser light for particle size determination can be applied through sapphire windows. A description of the various auxiliary equipment and of another gas hydrate cell used in the study are given. A computer program for simulation and analysis of gas hydrate experiments is based on the gas hydrate kinetics model proposed by Skovborg and Rasmussen (1993). Initial measurements showed that knowledge of the refractive index of gas hydrates was important in order to use MWE. An experimental determination of the refractive index of methane and natural gas hydrate is described. The test experiments performed with MWE on collectives of gas hydrate particles and experiments with ethane, methane and natural gas hydrate are discussed. Gas hydrate particles initially seem to grow mainly in size and at latter stages in number. (EG) EFP-94; 41 refs.

  2. Simulation of subsea gas hydrate exploitation

    Science.gov (United States)

    Janicki, Georg; Schlüter, Stefan; Hennig, Torsten; Deerberg, Görge

    2014-05-01

    The recovery of methane from gas hydrate layers that have been detected in several subsea sediments and permafrost regions around the world is a promising perspective to overcome future shortages in natural gas supply. Being aware that conventional natural gas resources are limited, research is going on to develop technologies for the production of natural gas from such new sources. Thus various research programs have started since the early 1990s in Japan, USA, Canada, India, and Germany to investigate hydrate deposits and develop required technologies. In recent years, intensive research has focussed on the capture and storage of CO2 from combustion processes to reduce climate impact. While different natural or man-made reservoirs like deep aquifers, exhausted oil and gas deposits or other geological formations are considered to store gaseous or liquid CO2, the storage of CO2 as hydrate in former methane hydrate fields is another promising alternative. Due to beneficial stability conditions, methane recovery may be well combined with CO2 storage in the form of hydrates. Regarding technological implementation many problems have to be overcome. Especially mixing, heat and mass transfer in the reservoir are limiting factors causing very long process times. Within the scope of the German research project »SUGAR« different technological approaches for the optimized exploitation of gas hydrate deposits are evaluated and compared by means of dynamic system simulations and analysis. Detailed mathematical models for the most relevant chemical and physical processes are developed. The basic mechanisms of gas hydrate formation/dissociation and heat and mass transport in porous media are considered and implemented into simulation programs. Simulations based on geological field data have been carried out. The studies focus on the potential of gas production from turbidites and their fitness for CO2 storage. The effects occurring during gas production and CO2 storage within

  3. Producing Gas-Oil Ratio Performance of Conventional and Unconventional Reservoirs

    OpenAIRE

    Lei, Guowen

    2012-01-01

    This study presents a detailed analysis of producing gas-oil ratio performance characteristics from conventional reservoir to unconventional reservoir. Numerical simulations of various reservoir fluid systems are included for comparison. In a wide sense of the word, the term of unconventional reservoir is including tight gas sand, coal bed methane, gas hydrate deposits, heavy oil gas shale and etc. In this study we specify the unconventional reservoir to only mean the low and ultra low permea...

  4. Major factors influencing the generation of natural gas hydrate in porous media

    Directory of Open Access Journals (Sweden)

    V.N. Khlebnikov

    2017-11-01

    Full Text Available Current researches related to natural gas hydrate mainly focus on its physical and chemical properties, as well as the approaches to the production (decomposition of hydrate. Physical modeling of the flow process in hydrate deposits is critical to the study on the exploitation or decomposition of hydrate. However, investigation of the dynamic hydrate process by virtue of porous media like sand-packed tubes which are widely used in petroleum production research is rarely reported in literature. In this paper, physical simulation of methane hydrate generation process was conducted using river sand-packed tubes in the core displacement apparatus. During the simulation, the influences of parameters such as reservoir temperature, methane pressure and reservoir model properties on the process of hydrate generation were investigated. The following results are revealed. First, the use of ice-melted water as the immobile water in the reservoir model can significantly enhance the rate of methane hydrate generation. Second, the process driving force in porous media (i.e., extents to which the experimental pressure or temperature deviating those corresponding to the hydrate phase equilibrium plays a key role in the generation of methane hydrate. Third, the induction period of methane hydrate generation almost does not change with temperature or pressure when the methane pressure is above 1.4 folds of the hydrate phase equilibrium pressure or the laboratory temperature is lower than the phase equilibrium temperature by 3 °C or more. Fourth, the parameters such as permeability, water saturation and wettability don't have much influence on the generation of methane hydrate.

  5. The Role of Bottom Simulating Reflectors in Gas Hydrate Assessment

    Science.gov (United States)

    Majumdar, U.; Shedd, W. W.; Cook, A.; Frye, M.

    2015-12-01

    In this research we test the viability of using a bottom simulating reflector (BSR) to detect gas hydrate. Bottom simulating reflectors (BSRs) occur at many gas hydrate sites near the thermodynamic base of the gas hydrate stability zone (GHSZ), and are frequently used to identify possible presence of gas hydrate on a regional scale. To find if drilling a BSR actually increases the chances of finding gas hydrate, we combine an updated dataset of BSR distribution from the Bureau of Ocean Energy Management with a comprehensive dataset of natural gas hydrate distribution as appraised from well logs, covering an area of around 200,000 square kilometers in the northern Gulf of Mexico. The BSR dataset compiles industry 3-D seismic data, and includes mostly good-quality and high-confidence traditional and non-traditional BSRs. Resistivity well logs were used to identify the presence of gas hydrate from over 700 existing industry wells and we have found over 110 wells with likely gas hydrate occurrences. By integrating the two datasets, our results show that the chances of encountering gas hydrate when drilling through a BSR is ~ 42%, while that when drilling outside the BSR is ~15%. Our preliminary analysis indicates that a positive relationship exists between BSRs and gas hydrate accumulations, and the chances of encountering gas hydrate increases almost three-fold when drilling through a BSR. One interesting observation is that ~ 58% of the wells intersecting a BSR show no apparent evidence of gas hydrate. In this case, a BSR may occur at sites with no gas hydrate accumulations due to the presence of very low concentration of free gas that is not detected on resistivity logs. On the other hand, in a few wells, accumulations of gas hydrate were observed where no BSR is present. For example in a well in Atwater Valley Block 92, two intervals of gas hydrate accumulation in fractures have been identified on resistivity logs, of which, the deeper interval has 230 feet thick

  6. Prediction of gas hydrate saturation throughout the seismic section in Krishna Godavari basin using multivariate linear regression and multi-layer feed forward neural network approach

    Digital Repository Service at National Institute of Oceanography (India)

    Singh, Y.; Nair, R.R.; Singh, H.; Datta, P.; Jaiswal, P.; Dewangan, P.; Ramprasad, T.

    , the present study used well log-derived data on P-wave velocity, porosity, resistivity, and gas hydrate saturation. Gas hydrate saturation used for this study is estimated by Lee and Collett (2009) for anisotropic reservoir (Fig. 1). Gas hydrates can be pore... filling, fracture filling, or a com- bination of both. In sand reservoirs, the pore filling morpholo- gy dominates while in the case of clay/silt reservoir, the hydrate can be fracture filling or combination of these. The NGHP-01 expedition first...

  7. 3D pore-type digital rock modeling of natural gas hydrate for permafrost and numerical simulation of electrical properties

    Science.gov (United States)

    Dong, Huaimin; Sun, Jianmeng; Lin, Zhenzhou; Fang, Hui; Li, Yafen; Cui, Likai; Yan, Weichao

    2018-02-01

    Natural gas hydrate is being considered as an alternative energy source for sustainable development and has become a focus of research throughout the world. In this paper, based on CT scanning images of hydrate reservoir rocks, combined with the microscopic distribution of hydrate, a diffusion limited aggregation (DLA) model was used to construct 3D hydrate digital rocks of different distribution types, and the finite-element method was used to simulate their electrical characteristics in order to study the influence of different hydrate distribution types, hydrate saturation and formation of water salinity on electrical properties. The results show that the hydrate digital rocks constructed using the DLA model can be used to characterize the microscopic distribution of different types of hydrates. Under the same conditions, the resistivity of the adhesive hydrate digital rock is higher than the cemented and scattered type digital rocks, and the resistivity of the scattered hydrate digital rock is the smallest among the three types. Besides, the difference in the resistivity of the different types of hydrate digital rocks increases with an increase in hydrate saturation, especially when the saturation is larger than 55%, and the rate of increase of each of the hydrate types is quite different. Similarly, the resistivity of the three hydrate types decreases with an increase in the formation of water salinity. The single distribution hydrate digital rock constructed, combined with the law of microscopic distribution and influence of saturation on the electrical properties, can effectively improve the accuracy of logging identification of hydrate reservoirs and is of great significance for the estimation of hydrate reserves.

  8. Maximum Recoverable Gas from Hydrate Bearing Sediments by Depressurization

    KAUST Repository

    Terzariol, Marco

    2017-11-13

    The estimation of gas production rates from hydrate bearing sediments requires complex numerical simulations. This manuscript presents a set of simple and robust analytical solutions to estimate the maximum depressurization-driven recoverable gas. These limiting-equilibrium solutions are established when the dissociation front reaches steady state conditions and ceases to expand further. Analytical solutions show the relevance of (1) relative permeabilities between the hydrate free sediment, the hydrate bearing sediment, and the aquitard layers, and (2) the extent of depressurization in terms of the fluid pressures at the well, at the phase boundary, and in the far field. Close form solutions for the size of the produced zone allow for expeditious financial analyses; results highlight the need for innovative production strategies in order to make hydrate accumulations an economically-viable energy resource. Horizontal directional drilling and multi-wellpoint seafloor dewatering installations may lead to advantageous production strategies in shallow seafloor reservoirs.

  9. Gas hydrates in Krishna-Godavari offshore basin

    Digital Repository Service at National Institute of Oceanography (India)

    Ramprasad, T.; Mazumdar, A.; Dewangan, P.

     geography and you T Ramprasad, A Mazumdar and P Dewangan Gas hydrates in Krishna- Godavari offshore basin Earth science technologies geography and you  july - august 2013  45 Methane from gas hydrate deposits could be a viable energy alternative... areas get buried deep under few kilometres of thick ocean sediments and is degraded by the bacterial activity for eons under very high temperatures. The methane molecules thus generated find their way into the overlying sediments through...

  10. Gas in Place Resource Assessment for Concentrated Hydrate Deposits in the Kumano Forearc Basin, Offshore Japan, from NanTroSEIZE and 3D Seismic Data

    Science.gov (United States)

    Taladay, K.; Boston, B.

    2015-12-01

    Natural gas hydrates (NGHs) are crystalline inclusion compounds that form within the pore spaces of marine sediments along continental margins worldwide. It has been proposed that these NGH deposits are the largest dynamic reservoir of organic carbon on this planet, yet global estimates for the amount of gas in place (GIP) range across several orders of magnitude. Thus there is a tremendous need for climate scientists and countries seeking energy security to better constrain the amount of GIP locked up in NGHs through the development of rigorous exploration strategies and standardized reservoir characterization methods. This research utilizes NanTroSEIZE drilling data from International Ocean Drilling Program (IODP) Sites C0002 and C0009 to constrain 3D seismic interpretations of the gas hydrate petroleum system in the Kumano Forearc Basin. We investigate the gas source, fluid migration mechanisms and pathways, and the 3D distribution of prospective HCZs. There is empirical and interpretive evidence that deeply sourced fluids charge concentrated NGH deposits just above the base of gas hydrate stability (BGHS) appearing in the seismic data as continuous bottoms simulating reflections (BSRs). These HCZs cover an area of 11 by 18 km, range in thickness between 10 - 80 m with an average thickness of 40 m, and are analogous to the confirmed HCZs at Daini Atsumi Knoll in the eastern Nankai Trough where the first offshore NGH production trial was conducted in 2013. For consistency, we calculated a volumetric GIP estimate using the same method employed by Japan Oil, Gas and Metals National Corporation (JOGMEC) to estimate GIP in the eastern Nankai Trough. Double BSRs are also common throughout the basin, and BGHS modeling along with drilling indicators for gas hydrates beneath the primary BSRs provides compelling evidence that the double BSRs reflect a BGHS for structure-II methane-ethane hydrates beneath a structure-I methane hydrate phase boundary. Additional drilling

  11. Arctic Gas hydrate, Environment and Climate

    Science.gov (United States)

    Mienert, Jurgen; Andreassen, Karin; Bünz, Stefan; Carroll, JoLynn; Ferre, Benedicte; Knies, Jochen; Panieri, Giuliana; Rasmussen, Tine; Myhre, Cathrine Lund

    2015-04-01

    Arctic methane hydrate exists on land beneath permafrost regions and offshore in shelf and continental margins sediments. Methane or gas hydrate, an ice-like substrate, consists mainly of light hydrocarbons (mostly methane from biogenic sources but also ethane and propane from thermogenic sources) entrapped by a rigid cage of water molecules. The pressure created by the overlying water and sediments offshore stabilizes the CH4 in continental margins at a temperature range well above freezing point; consequently CH4 exists as methane ice beneath the seabed. Though the accurate volume of Arctic methane hydrate and thus the methane stored in hydrates throughout the Quaternary is still unknown it must be enormous if one considers the vast regions of Arctic continental shelves and margins as well as permafrost areas offshore and on land. Today's subseabed methane hydrate reservoirs are the remnants from the last ice age and remain elusive targets for both unconventional energy and as a natural methane emitter influencing ocean environments and ecosystems. It is still contentious at what rate Arctic warming may govern hydrate melting, and whether the methane ascending from the ocean floor through the hydrosphere reaches the atmosphere. As indicated by Greenland ice core records, the atmospheric methane concentration rose rapidly from ca. 500 ppb to ca. 750 ppb over a short time period of just 150 years at the termination of the younger Dryas period ca. 11600 years ago, but the dissociation of large quantities of methane hydrates on the ocean floor have not been documented yet (Brook et al., 2014 and references within). But with the major projected warming and sea ice melting trend (Knies et al., 2014) one may ask, for how long will CH4 stay trapped in methane hydrates if surface and deep-ocean water masses will warm and permafrost continuous to melt (Portnov et al. 2014). How much of the Arctic methane will be consumed by the micro- and macrofauna, how much will

  12. Site selection for DOE/JIP gas hydrates drilling in the northern Gulf of Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Hutchinson, D.R.; Ruppel, C. [United States Geological Survey, Woods Hole, MA (United States); Shelander, D.; Dai, J. [Schlumberger, Houston, TX (United States); McConnell, D. [AOA Geophysics Inc., Houston, TX (United States); Shedd, W. [Minerals Management Service, New Orleans, LA (United States); Frye, M. [Minerals Management Service, Herndon, VA (United States); Boswell, R.; Rose, K. [United States Dept. of Energy, Morgantown, WV (United States). National Energy Technology Lab; Jones, E.; Latham, T. [Chevron Energy Technology Corp., Houston, TX (United States); Collett, T. [United States Geological Survey, Denver, CO (United States); Dugan, B. [Rice Univ., Houston, TX (United States). Dept. of Earth Science; Wood, W. [United States Naval Research Lab, Stennis Space Center, MS (United States)

    2008-07-01

    As drilling operations in the Gulf of Mexico shift from shallow water to deeper water targets, operators are encountering sediments with pressure-temperature regimes for gas hydrate stability. The Chevron-led Joint Industry Project (JIP) on methane hydrates was formed in 2001 to study the hazards associated with drilling these types of hydrate-bearing sediments and to assess the capacity of geological and geophysical tools to predict gas hydrate distributions and concentrations. Selected reservoirs units with high concentrations of gas hydrate were sampled to obtain physical data on hydrate bearing sediments. The JIP work validates methods devised to estimate gas hydrate distribution and concentrations in order to analyze the resource potential of these hydrate-bearing sediments. This paper described the geologic and geophysical setting of 3 sites in the northern Gulf of Mexico that contain hydrate-bearing reservoir sands. The three sites that will undergo exploratory drilling and a logging campaign in late spring 2008 include the Alaminos Canyon (AC) lease block 818, Green Canyon (GC) 955, and Walker Ridge (WR) 313. At the AC818 site, gas hydrate is interpreted to occur within the Oligocene Frio volcaniclastic sand at the crest of a fold that is shallow enough to be in the hydrate stability zone. Drilling at GC955 will sample a faulted, buried Pleistocene channel-levee system characterized with seafloor fluid expulsion features, structural closure associated with uplifted salt, and seismic evidence for upward migration of fluids and gas into the sand-rich parts of the sedimentary section. Drilling at WR313 targets sheet sands and associated channel deposits within a small basin. The potential for gas hydrate occurrence at WR313 is supported by shingled phase reversals consistent with the transition from gas-charged sand to overlying gas-hydrate saturated sand. 39 refs., 1 tab., 4 figs.

  13. Exploitation of marine gas hydrates: Benefits and risks (Invited)

    Science.gov (United States)

    Wallmann, K. J.

    2013-12-01

    Vast amounts of natural gas are stored in marine gas hydrates deposited at continental margins. The global inventory of carbon bound as methane in gas hydrates is currently estimated as 1000 × 500 Gt. Large-scale national research projects located mostly in South-East Asia but also in North America and Europe are aiming to exploit these ice-like solids as new unconventional resource of natural gas. Japan, South Korea and other Asian countries are taking the lead because their national waters harbor exploitable gas hydrate deposits which could be developed to reduce the dependency of these nations on costly LGN imports. In 2013, the first successful production test was performed off Japan at water depths of ca. 1000 m demonstrating that natural gas can be released and produced from marine hydrates by lowering the pressure in the sub-seabed hydrate reservoirs. In an alternative approach, CO2 from coal power plans and other industrial sources is used to release natural gas (methane) from hydrates while CO2 is bound and stored in the sub-surface as solid hydrate. These new approaches and technologies are still in an early pre-commercial phase; the costs of field development and gas production exceed the value of natural gas being produced from the slowly dissociating hydrates. However, new technologies are currently under development in the German SUGAR project and elsewhere to reduce costs and enhance gas production rates such that gas hydrates may become commercially exploitable over the coming decade(s). The exploitation of marine gas hydrates may help to reduce CO2 emissions from the fossil fuel sector if the produced natural gas is used to replace coal and/or LNG. Hydrate development could also provide important incentives for carbon capture technologies since CO2 can be used to produce natural gas from hydrates. However, leakage of gas may occur during the production process while slope failure may be induced by the accompanying dissociation/conversion of gas

  14. Mineralogy of Gas Hydrate Bearing Sediment in Green Canyon Block 955 Northern Gulf of Mexico

    Science.gov (United States)

    Heber, R.; Kinash, N.; Cook, A.; Sawyer, D.; Sheets, J.; Johnson, J. E.

    2017-12-01

    Natural gas hydrates are of interest as a future hydrocarbon source, however, the formation and physical properties of such systems are not fully understood. In May 2017, the University of Texas drilled two holes in Green Canyon Block 955, northern Gulf of Mexico to collect pressurized core from a thick, 100 m accumulation of gas hydrate in a silt dominated submarine canyon levee system. The expedition, known as UT-GOM2-01, collected 21, 10-m pressure cores from Holes H002 and H005. Approximately half of the cores successfully pressurized and were fully recovered. Unsuccessful cores that did not pressurize generally had low core recovery. By analyzing the sediment composition in known gas hydrate reservoirs, we can construct a more detailed picture of how and why gas hydrates accumulate, as mineralogy can affect physical properties such as porosity and permeability as well as geophysical measurements such as resistivity. Using X-ray diffraction (XRD) on bulk sediment powders, we determined the bulk mineralogy of the samples. Moreover, we investigated drilling mud contamination using XRD and light optical analysis. In some cores, contamination was easily recognized visually as dense sludge between the core barrel and the recovered sediment core, however drilling mud is best observed both along the liner and interbedded within the sediment on X-ray computed tomography scans. To fully identify the presence and influence of drilling mud, we use XRD to analyze samples on cores collected both while drilling mud was used in hole and when only seawater was used in hole and consider the density anomalies observed on the XCT scans. The preliminary XRD light optical microscopy results show that the silt-dominated reservoir is primarily composed of quartz, with minor alkali feldspar, amphibole, muscovite, dolomite, and calcite. Samples from intervals with suspected drilling mud contamination show a similar composition, but with the addition of barite, a common component in

  15. Numerical Simulations for Enhanced Methane Recovery from Gas Hydrate Accumulations by Utilizing CO2 Sequestration

    Science.gov (United States)

    Sridhara, Prathyusha

    In 2013, the International Energy Outlook (EIA, 2013) projected that global energy demand will grow by 56% between 2010 and 2040. Despite strong growth in renewable energy supplies, much of this growth is expected to be met by fossil fuels. Concerns ranging from greenhouse gas emissions and energy security are spawning new interests for other sources of energy including renewable and unconventional fossil fuel such as shale gas and oil as well as gas hydrates. The production methods as well as long-term reservoir behavior of gas hydrate deposits have been under extensive investigation. Reservoir simulators can be used to predict the production potentials of hydrate formations and to determine which technique results in enhanced gas recovery. In this work, a new simulation tool, Mix3HydrateResSim (Mix3HRS), which accounts for complex thermodynamics of multi-component hydrate phase comprised of varying hydrate solid crystal structure, is used to perform the CO2-assisted production technique simulations from CH4 hydrate accumulations. The simulator is one among very few reservoir simulators which can simulate the process of CH4 substitution by CO2 (and N2 ) in the hydrate lattice. Natural gas hydrate deposits around the globe are categorized into three different classes based on the characteristics of the geological sediments present in contact with the hydrate bearing deposits. Amongst these, the Class 2 hydrate accumulations predominantly confirmed in the permafrost and along seashore, are characterized by a mobile aqueous phase underneath a hydrate bearing sediment. The exploitation of such gas hydrate deposits results in release of large amounts of water due to the presence of permeable water-saturated sediments encompassing the hydrate deposits, thus lowering the produced gas rates. In this study, a suite of numerical simulation scenarios with varied complexity are considered which aimed at understanding the underlying changes in physical, thermodynamic and

  16. Gas hydrate dissociation off Svalbard induced by isostatic rebound rather than global warming.

    Science.gov (United States)

    Wallmann, Klaus; Riedel, M; Hong, W L; Patton, H; Hubbard, A; Pape, T; Hsu, C W; Schmidt, C; Johnson, J E; Torres, M E; Andreassen, K; Berndt, C; Bohrmann, G

    2018-01-08

    Methane seepage from the upper continental slopes of Western Svalbard has previously been attributed to gas hydrate dissociation induced by anthropogenic warming of ambient bottom waters. Here we show that sediment cores drilled off Prins Karls Foreland contain freshwater from dissociating hydrates. However, our modeling indicates that the observed pore water freshening began around 8 ka BP when the rate of isostatic uplift outpaced eustatic sea-level rise. The resultant local shallowing and lowering of hydrostatic pressure forced gas hydrate dissociation and dissolved chloride depletions consistent with our geochemical analysis. Hence, we propose that hydrate dissociation was triggered by postglacial isostatic rebound rather than anthropogenic warming. Furthermore, we show that methane fluxes from dissociating hydrates were considerably smaller than present methane seepage rates implying that gas hydrates were not a major source of methane to the oceans, but rather acted as a dynamic seal, regulating methane release from deep geological reservoirs.

  17. A prediction method of natural gas hydrate formation in deepwater gas well and its application

    Directory of Open Access Journals (Sweden)

    Yanli Guo

    2016-09-01

    Full Text Available To prevent the deposition of natural gas hydrate in deepwater gas well, the hydrate formation area in wellbore must be predicted. Herein, by comparing four prediction methods of temperature in pipe with field data and comparing five prediction methods of hydrate formation with experiment data, a method based on OLGA & PVTsim for predicting the hydrate formation area in wellbore was proposed. Meanwhile, The hydrate formation under the conditions of steady production, throttling and shut-in was predicted by using this method based on a well data in the South China Sea. The results indicate that the hydrate formation area decreases with the increase of gas production, inhibitor concentrations and the thickness of insulation materials and increases with the increase of thermal conductivity of insulation materials and shutdown time. Throttling effect causes a plunge in temperature and pressure in wellbore, thus leading to an increase of hydrate formation area.

  18. Environmental Impact of Natural Gas Hydrate Production

    Science.gov (United States)

    Max, M. D.; Johnson, A. H.

    2017-12-01

    Unmet conventional energy demand is encouraging a number of deep energy importing nations closer to production of their potentially very large Natural Gas Hydrate (NGH) resources. As methane and other natural gases are potent greenhouse gases, concerns exist about the possible environmental risks associated NGH development. Accidental of natural gas would have environmental consequences. However, the special characteristics of NGH and production models indicate a very low environmental risk from the reservoir to the deepwater wellhead that is much lower than for conventional deepwater gas. NGH is naturally stable in its solid form in the reservoir and shutting in the gas can be achieved by stopping NGH conversion and gas production in the reservoir. Rapid shut down results in re-crystallization of gas and stabilization of the reservoir through NGH reformation. In addition, new options for innovative technologies have the potential to allow safe development of NGH at a fraction of the current estimated cost. Gas produced from NGH is about the same as processed conventional gas, although almost certainly more pure. Leakage of gas during transport is not a production issue. Gas transport leakage is a matter for best practices regulation that is rigorously enforced.

  19. Protein hydration and dynamics

    International Nuclear Information System (INIS)

    Nakagawa, Hiroshi; Kataoka, Mikio

    2015-01-01

    Inelastic neutron scattering can measure the protein thermal fluctuations under the physiological aqueous environment, especially it is powerful to observe the low-energy protein dynamics in THz region, which are revealed theoretically to be coupled with solvations. Neutron enables the selective observation of protein and hydration water by deuteration. The complementary analysis with molecular dynamics simulation is also effective for the study of protein hydration. Some examples of the application toward the understanding of molecular basis of protein functions will be introduced. (author)

  20. Geological & Geophysical findings from seismic, well log and core data for marine gas hydrate deposits at the 1st offshore methane hydrate production test site in the eastern Nankai Trough, offshore Japan: An overview

    Science.gov (United States)

    Fujii, T.; Noguchi, S.; Takayama, T.; Suzuki, K.; Yamamoto, K.

    2012-12-01

    In order to evaluate productivity of gas from marine gas hydrate by the depressurization method, Japan Oil, Gas and Metals National Corporation is planning to conduct a full-scale production test in early 2013 at the AT1 site in the north slope of Daini-Atsumi Knoll in the eastern Nankai Trough, Japan. The test location was determined using the combination of detailed 3D seismic reflection pattern analysis, high-density velocity analysis, and P-impedance inversion analysis, which were calibrated using well log data obtained in 2004. At the AT1 site, one production well (AT1-P) and two monitoring wells (AT1-MC and MT1) were drilled from February to March 2012, followed by 1 coring well (AT1-C) from June to July 2012. An extensive logging program with logging while drilling (LWD) and wireline-logging tools, such as GeoVISION (resistivity image), EcoScope (neutron/density porosity, mineral spectroscopy etc.), SonicScanner (Advanced Sonic tool), CMR/ProVISION (Nuclear Magnetic Resonance Tools), XPT (formation pressure, fluid mobility), and IsolationScanner (ultrasonic cement evaluation tools) was conducted at AT1-MC well to evaluate physical reservoir properties of gas hydrate-bearing sediments, to determine production test interval in 2013, and to evaluate cement bonding. Methane hydrate concentrated zone (MHCZ) confirmed by the well logging at AT1-MC was thin turbidites (tens of centimeters to few meters) with 60 m of gross thickness, which is composed of lobe type sequences in the upper part of it and channel sand sequences in the lower part. The gross thickness of MHCZ in the well is thicker than previous wells in 2004 (A1, 45 m) located around 150 m northeast, indicating that the prediction given by seismic inversion analysis was reasonable. Well-to-well correlation between AT1-MC and MT1 wells within 40 m distance exhibited that lateral continuity of these sand layers (upper part of reservoir) are fairly good, which representing ideal reservoir for the production

  1. Low-δD hydration rinds in Yellowstone perlites record rapid syneruptive hydration during glacial and interglacial conditions

    Science.gov (United States)

    Bindeman, Ilya N.; Lowenstern, Jacob B.

    2016-01-01

    Hydration of silicic volcanic glass forms perlite, a dusky, porous form of altered glass characterized by abundant “onion-skin” fractures. The timing and temperature of perlite formation are enigmatic and could plausibly occur during eruption, during post-eruptive cooling, or much later at ambient temperatures. To learn more about the origin of natural perlite, and to fingerprint the hydration waters, we investigated perlitic glass from several synglacial and interglacial rhyolitic lavas and tuffs from the Yellowstone volcanic system. Perlitic cores are surrounded by a series of conchoidal cracks that separate 30- to 100-µm-thick slivers, likely formed in response to hydration-induced stress. H2O and D/H profiles confirm that most D/H exchange happens together with rapid H2O addition but some smoother D/H variations may suggest separate minor exchange by deuterium atom interdiffusion following hydration. The hydrated rinds (2–3 wt% H2O) transition rapidly (within 30 µm, or by 1 wt% H2O per 10 µm) to unhydrated glass cores. This is consistent with quenched “hydration fronts” where H2O diffusion coefficients are strongly dependent on H2O concentrations. The chemical, δ18O, and δD systematics of bulk glass records last equilibrium between ~110 and 60 °C without chemical exchange but with some δ18O exchange. Similarly, the δ18O of water extracted from glass by rapid heating suggests that water was added to the glass during cooling at higher rates of diffusion at 60–110 °C temperatures, compared with values expected from extrapolation of high-temperature (>400 °C) experimental data. The thick hydration rinds in perlites, measuring hundreds of microns, preserve the original D/H values of hydrating water as a recorder of paleoclimate conditions. Measured δD values in perlitic lavas are −150 to −191 or 20–40 ‰ lower than glass hydrated by modern Yellowstone waters. This suggests that Yellowstone perlites record the low-δD signature

  2. Aluminum Sulfate 18 Hydrate

    Science.gov (United States)

    Young, Jay A.

    2004-01-01

    A chemical laboratory information profile (CLIP) of the chemical, aluminum sulfate 18 hydrate, is presented. The profile lists physical and harmful properties, exposure limits, reactivity risks, and symptoms of major exposure for the benefit of teachers and students using the chemical in the laboratory.

  3. NATURAL GAS HYDRATES STORAGE PROJECT PHASE II. CONCEPTUAL DESIGN AND ECONOMIC STUDY

    Energy Technology Data Exchange (ETDEWEB)

    R.E. Rogers

    1999-09-27

    DOE Contract DE-AC26-97FT33203 studied feasibility of utilizing the natural-gas storage property of gas hydrates, so abundantly demonstrated in nature, as an economical industrial process to allow expanded use of the clean-burning fuel in power plants. The laboratory work achieved breakthroughs: (1) Gas hydrates were found to form orders of magnitude faster in an unstirred system with surfactant-water micellar solutions. (2) Hydrate particles were found to self-pack by adsorption on cold metal surfaces from the micellar solutions. (3) Interstitial micellar-water of the packed particles were found to continue forming hydrates. (4) Aluminum surfaces were found to most actively collect the hydrate particles. These laboratory developments were the bases of a conceptual design for a large-scale process where simplification enhances economy. In the design, hydrates form, store, and decompose in the same tank in which gas is pressurized to 550 psi above unstirred micellar solution, chilled by a brine circulating through a bank of aluminum tubing in the tank employing gas-fired refrigeration. Hydrates form on aluminum plates suspended in the chilled micellar solution. A low-grade heat source, such as 110 F water of a power plant, circulates through the tubing bank to release stored gas. The design allows a formation/storage/decomposition cycle in a 24-hour period of 2,254,000 scf of natural gas; the capability of multiple cycles is an advantage of the process. The development costs and the user costs of storing natural gas in a scaled hydrate process were estimated to be competitive with conventional storage means if multiple cycles of hydrate storage were used. If more than 54 cycles/year were used, hydrate development costs per Mscf would be better than development costs of depleted reservoir storage; above 125 cycles/year, hydrate user costs would be lower than user costs of depleted reservoir storage.

  4. Permafrost-associated gas hydrates of Northern Alaska: A possible source of atmospheric methane

    International Nuclear Information System (INIS)

    Collett, T.S.

    1991-01-01

    Numerous researchers have suggested that destabilized gas hydrates may be contributing to this buildup in atmospheric methane. Little is known about the geologic or geochemical nature of gas hydrates, even though they are known to occur in numerous arctic sedimentary basins. Because of the abundance of available geologic data, the author's research has focused on assessing the distribution of gas hydrates within the onshore regions of northern Alaska; currently, onshore permafrost-associated gas hydrates are believed to be insulated from most atmospheric temperature changes and are not at this time an important source of atmospheric methane. Their onshore gas hydrate studies, however, can be used to develop geologic analogs for potential gas hydrate occurrences within unexplored areas, such as the thermally unstable nearshore continental shelf. On the North Slope, gas hydrates have been identified in 36 industry wells by using well-log responses calibrated to the response of an interval in one well where gas hydrates were recovered in a core by an oil company. Most gas hydrates they identified occur in six laterally continuous Upper Cretaceous and lower Tertiary sandstone and conglomerate units; all these hydrates are geographically restricted to the area overlying the eastern part of the Kuparuk River Oil Field and the western part of the Prudhoe Bay Oil Field. Stable carbon isotope geochemical analysis of well cuttings suggests that the identified hydrates originated from a mixture of deep-source thermogenic gas and shallow microbial gas that was either directly converted to gas hydrate or first concentrated in existing traps and later converted to gas hydrate. They postulate that the thermogenic gas migrated from deeper reservoirs along the faults thought to be migration pathways for the large volumes of shallow, heavy oil found in the same area

  5. Assessing the conditions favorable for the occurrence of gas hydrate in the Tuonamu area Qiangtang basin, Qinghai–Tibetan, China

    International Nuclear Information System (INIS)

    He Jianglin; Wang Jian; Fu Xiugen; Zheng Chenggang; Chen Yanting

    2012-01-01

    Highlights: ► This is a pioneer research on the exploration of gas hydrate in Qiangtang basin. ► The factors influencing the stable of gas hydrate in Tuonamu area were studied. ► Simulation shows that gas hydrate stable zone is about 300 m thick in target area. ► Source condition is the key factor for the formation of gas hydrate in this area. ► The areas around the deeper faults are favorable targets for gas hydrate. - Abstract: Qiangtang basin, which is located in the largest continuous permafrost area in Qinghai–Tibetan Plateau, is expected to be a strategic area of gas hydrate exploitation in China. However, relatively little work has been done on the exploration of gas hydrate in this area. In this work, we evaluated the factors controlling the formation of gas hydrate in the Tuonamu area and provided a preliminary insight into gas hydrate distribution in it on the basis of the core samples, seismic data and laboratory analysis. It can be concluded that the source rock in the deeper formation would be dominant thermogenic source for the formation of gas hydrate in Tuonamu area. The thickness of gas hydrate stable zone in this area is about 300 m. The gas hydrate in the area most probably is in the form of gas-hydrate-water. The source condition is the key factor for the formation of gas hydrate and the gas hydrate layer would be mainly present in the form of interlayer in this area. The areas around the deeper faults are the favorable targets for the exploration of gas hydrate in the Tuonamu area.

  6. Fundamentals of Natural Gas and Species Flows from Hydrate Dissociation - Applications to Safety and Sea Floor Instability

    Energy Technology Data Exchange (ETDEWEB)

    Ahmadi, Goodarz

    2006-09-30

    Semi-analytical computational models for natural gas flow in hydrate reservoirs were developed and the effects of variations in porosity and permeability on pressure and temperature profiles and the movement of a dissociation front were studied. Experimental data for variations of gas pressure and temperature during propane hydrate formation and dissociation for crushed ice and mixture of crushed ice and glass beads under laboratory environment were obtained. A thermodynamically consistent model for multiphase liquid-gas flows trough porous media was developed. Numerical models for hydrate dissociation process in one dimensional and axisymmetric reservoir were performed. The computational model solved the general governing equations without the need for linearization. A detail module for multidimensional analysis of hydrate dissociation which make use of the FLUENT code was developed. The new model accounts for gas and liquid water flow and uses the Kim-Boshnoi model for hydrate dissociation.

  7. Analysis of bubble plume distributions to evaluate methane hydrate decomposition on the continental slope

    Science.gov (United States)

    Johnson, H. Paul; Miller, Una K.; Salmi, Marie S.; Solomon, Evan A.

    2015-11-01

    Cascadia margin sediments contain a rich reservoir of carbon derived both from terrestrial input and sea surface productivity. A portion of this carbon exists as solid gas hydrate within sediment pore spaces which previous studies have shown to be a methane reservoir of substantial size on both the Vancouver Island and Oregon portions of the Cascadia margin. Multichannel seismic reflection profiles on the Cascadia margin show the widespread presence of Bottom Simulating Reflectors (BSRs) within the sediment column, indicating the gas hydrate reservoir extends from the deformation front at 3000 m depth to the upper limit of gas hydrate stability near 500 m water depth. In this study, we compile an inventory of methane bubble plume sites on the Cascadia margin identified in investigations carried out for a range of interdisciplinary goals that also include sites volunteered by commercial fishermen. High plume density anomalies are associated with both the continental shelf (<180 m) and the depth of the upper limit of methane hydrate stability depth (MHSD) that occurs near 500 m in the NE Pacific. The observed anomalies on the Cascadia slope may be due to the warming of seawater at intermediate depths, suggesting that modern climate change has begun to destabilize the climate-sensitive hydrate reservoir within the Cascadia margin sediments. Reanalysis of similar plume images on the North American Atlantic slope suggests a lack of correlation between observed plume depths and the MHSD for much of the latitudinal range.

  8. Observations of mass fractionation of noble gases in synthetic methane hydrate

    Science.gov (United States)

    Hunt, Andrew G.; Pohlman, John; Stern, Laura A.; Ruppel, Carolyn D.; Moscati, Richard J.; Landis, Gary P.; Pinkston, John C.

    2011-01-01

    As a consequence of contemporary or longer term (since 15 ka) climate warming, gas hydrates in some settings are presently dissociating and releasing methane and other gases to the oceanatmosphere system. A key challenge in assessing the susceptibility of gas hydrates to warming climate is the lack of a technique able to distinguish between methane recently released from gas hydrates and methane emitted from leaky thermogenic reservoirs, shallow sublake and subseafloor sediments, coalbeds, and other sources. Carbon and deuterium stable isotopic data provide only a first-order characterization of methane sources, while gas hydrate can sequester any type of methane. Here, we investigate the possibility of exploiting the pattern of noble gas fractionation within the gas hydrate lattice to fingerprint methane released from gas hydrates. Starting with synthetic gas hydrate formed under careful laboratory conditions, we document complex noble gas fractionation patterns in the gases liberated during dissociation and explore the effects of aging and storage (e.g., in liquid nitrogen), as well as sampling and preservation procedures. The laboratory results confirm a unique noble gas fractionation pattern for gas hydrates, one that shows promise in evaluating modern natural gas seeps for a signature associated with gas hydrate dissociation.

  9. Natural gas hydrate formation and inhibition in gas/crude oil/aqueous systems

    DEFF Research Database (Denmark)

    Daraboina, Nagu; Pachitsas, Stylianos; von Solms, Nicolas

    2015-01-01

    Gas hydrate formation in multi phase mixtures containing an aqueous phase (with dissolved salts), reservoir fluid (crude oil) and natural gas phase was investigated by using a standard rocking cell (RC-5) apparatus. The hydrate formation temperature was reduced in the presence of crude oils...... of the biodegradable commercial kinetic inhibitor (Luvicap-Bio) on natural gas hydrate formation with and without crude oil (30%) was investigated. The strength of kinetic inhibitor was not affected by salts, but decreased significantly in the presence of crude oil. Data for hydrate formation at practical conditions...... inhibition mechanisms and potentially a competition among inhibition-promotion mechanisms. Moreover, the hydrate formation time has been determined at different water cuts in each crude oil and it was found that the inhibition capability increases with an increase in the oil content. The effect...

  10. Historical methane hydrate project review

    Science.gov (United States)

    Collett, Timothy; Bahk, Jang-Jun; Frye, Matt; Goldberg, Dave; Husebo, Jarle; Koh, Carolyn; Malone, Mitch; Shipp, Craig; Torres, Marta

    2013-01-01

    In 1995, U.S. Geological Survey made the first systematic assessment of the volume of natural gas stored in the hydrate accumulations of the United States. That study, along with numerous other studies, has shown that the amount of gas stored as methane hydrates in the world greatly exceeds the volume of known conventional gas resources. However, gas hydrates represent both a scientific and technical challenge and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of gas hydrates in nature, (2) assessing the volume of natural gas stored within various gas hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural gas hydrates, and (5) analyzing the effects of methane hydrate on drilling safety.Methane hydrates are naturally occurring crystalline substances composed of water and gas, in which a solid water-­‐lattice holds gas molecules in a cage-­‐like structure. The gas and water becomes a solid under specific temperature and pressure conditions within the Earth, called the hydrate stability zone. Other factors that control the presence of methane hydrate in nature include the source of the gas included within the hydrates, the physical and chemical controls on the migration of gas with a sedimentary basin containing methane hydrates, the availability of the water also included in the hydrate structure, and the presence of a suitable host sediment or “reservoir”. The geologic controls on the occurrence of gas hydrates have become collectively known as the “methane hydrate petroleum system”, which has become the focus of numerous hydrate research programs.Recognizing the importance of methane hydrate research and the need for a coordinated

  11. TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media

    Energy Technology Data Exchange (ETDEWEB)

    Moridis, George; Moridis, George J.; Kowalsky, Michael B.; Pruess, Karsten

    2008-03-01

    TOUGH+HYDRATE v1.0 is a new code for the simulation of the behavior of hydrate-bearing geologic systems. By solving the coupled equations of mass and heat balance, TOUGH+HYDRATE can model the non-isothermal gas release, phase behavior and flow of fluids and heat under conditions typical of common natural CH{sub 4}-hydrate deposits (i.e., in the permafrost and in deep ocean sediments) in complex geological media at any scale (from laboratory to reservoir) at which Darcy's law is valid. TOUGH+HYDRATE v1.0 includes both an equilibrium and a kinetic model of hydrate formation and dissociation. The model accounts for heat and up to four mass components, i.e., water, CH{sub 4}, hydrate, and water-soluble inhibitors such as salts or alcohols. These are partitioned among four possible phases (gas phase, liquid phase, ice phase and hydrate phase). Hydrate dissociation or formation, phase changes and the corresponding thermal effects are fully described, as are the effects of inhibitors. The model can describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects and inhibitor-induced effects. TOUGH+HYDRATE is the first member of TOUGH+, the successor to the TOUGH2 [Pruess et al., 1991] family of codes for multi-component, multiphase fluid and heat flow developed at the Lawrence Berkeley National Laboratory. It is written in standard FORTRAN 95, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available.

  12. The Hydrated Electron

    Science.gov (United States)

    Herbert, John M.; Coons, Marc P.

    2017-05-01

    Existence of a hydrated electron as a byproduct of water radiolysis was established more than 50 years ago, yet this species continues to attract significant attention due to its role in radiation chemistry, including DNA damage, and because questions persist regarding its detailed structure. This work provides an overview of what is known in regards to the structure and spectroscopy of the hydrated electron, both in liquid water and in clusters [Formula: see text], the latter of which provide model systems for how water networks accommodate an excess electron. In clusters, the existence of both surface-bound and internally bound states of the excess electron has elicited much debate, whereas in bulk water there are questions regarding how best to understand the structure of the excess electron's spin density. The energetics of the equilibrium species e-(aq) and its excited states, in bulk water and at the air/water interface, are also addressed.

  13. Modeling Hydrates and the Gas Hydrate Markup Language

    Directory of Open Access Journals (Sweden)

    Weihua Wang

    2007-06-01

    Full Text Available Natural gas hydrates, as an important potential fuels, flow assurance hazards, and possible factors initiating the submarine geo-hazard and global climate change, have attracted the interest of scientists all over the world. After two centuries of hydrate research, a great amount of scientific data on gas hydrates has been accumulated. Therefore the means to manage, share, and exchange these data have become an urgent task. At present, metadata (Markup Language is recognized as one of the most efficient ways to facilitate data management, storage, integration, exchange, discovery and retrieval. Therefore the CODATA Gas Hydrate Data Task Group proposed and specified Gas Hydrate Markup Language (GHML as an extensible conceptual metadata model to characterize the features of data on gas hydrate. This article introduces the details of modeling portion of GHML.

  14. Overview: Nucleation of clathrate hydrates

    Science.gov (United States)

    Warrier, Pramod; Khan, M. Naveed; Srivastava, Vishal; Maupin, C. Mark; Koh, Carolyn A.

    2016-12-01

    Molecular level knowledge of nucleation and growth of clathrate hydrates is of importance for advancing fundamental understanding on the nature of water and hydrophobic hydrate formers, and their interactions that result in the formation of ice-like solids at temperatures higher than the ice-point. The stochastic nature and the inability to probe the small length and time scales associated with the nucleation process make it very difficult to experimentally determine the molecular level changes that lead to the nucleation event. Conversely, for this reason, there have been increasing efforts to obtain this information using molecular simulations. Accurate knowledge of how and when hydrate structures nucleate will be tremendously beneficial for the development of sustainable hydrate management strategies in oil and gas flowlines, as well as for their application in energy storage and recovery, gas separation, carbon sequestration, seawater desalination, and refrigeration. This article reviews various aspects of hydrate nucleation. First, properties of supercooled water and ice nucleation are reviewed briefly due to their apparent similarity to hydrates. Hydrate nucleation is then reviewed starting from macroscopic observations as obtained from experiments in laboratories and operations in industries, followed by various hydrate nucleation hypotheses and hydrate nucleation driving force calculations based on the classical nucleation theory. Finally, molecular simulations on hydrate nucleation are discussed in detail followed by potential future research directions.

  15. Gas hydrates of the Black sea sediment section

    International Nuclear Information System (INIS)

    Byakov, Y.A.; Kruglyakova, R.P.; Kruglyakova, M.V.

    2002-01-01

    Full text : This article shows how gas formation and its genesis in the Black sea sediments forms two types of gas hydrates. The first is diagenetic, formed from biochemical methane. The second type is thermogenic, formed from the thermogenic gases and represented not only by methane, but also by its light homologues, like ethane and propane. The most favourable area for formation of the gas hydrates of the first type in the Black sea is the foot of the continental slope and areas of underwater cones of paleorivers drift-over. Gas hydrates of the second type are accumulated in the areas of underwater mud volcanoes. In accordance with the results of seismic and seismoacoustic studies in deposited thickness of the Black sea the specific anomalies of the BSR and VAMP's types are revealed that associate with the foot of gas hydrate deposits. Two gas hydrates are distinguished according to sources of gas supply and genesis : type 1 - diagenetic, type 2 - thermogenic. When some critique is reached the gas hydrate trap breaks and volcanic eruption occurs. Thus, occurrence of underwater volcanism may testify the presence of deposits.

  16. Mineralogy and Oxygen Isotope Compositions of Two C-Rich Hydrated Interplanetary Dust Particles

    Science.gov (United States)

    Snead, C. J.; McKeegan, K. D.; Messenger, S.; Nakamura-Messenger, K.

    2012-01-01

    Oxygen isotopic compositions of chondrites reflect mixing between a O-16-rich reservoir and a O-17,O-18-rich reservoir produced via mass-independent fractionation. The composition of the O-16-rich reservoir is reasonably well constrained, but material representing the O-17,O-18-rich end-member is rare. Self-shielding models predict that cometary water, presumed to represent this reservoir, should be enriched in O-17 and O-18 18O by > 200%. Hydrated interplanetary dust particles (IDPs) rich in carbonaceous matter may be derived from comets; such particles likely contain the products of reaction between O-16-poor water and anhydrous silicates that formed in the inner solar system. Here we present mineralogy and oxygen isotope compositions of two C-rich hydrated IDPs, L2083E47 and L2071E35.

  17. Rapid gas hydrate formation process

    Science.gov (United States)

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  18. Interrelation of Hydration, Collagen Cross-Linking Treatment, and Biomechanical Properties of the Cornea.

    Science.gov (United States)

    Hatami-Marbini, Hamed; Rahimi, Abdolrasol

    2016-05-01

    The present study was designed to investigate the effects of hydration and collagen cross-linking treatment on biomechanical properties of the cornea. The original corneal collagen cross-linking protocol was used to induce cross-links in bovine corneas. The thickness of samples was used as a measure of their hydration and five different thickness groups (n = 5 each) were considered. The cross-linked corneal strips were allowed to hydrate/dehydrate until their thickness reached 500, 700, 900, 1100, and 1500 μm. The tensile behavior of specimens in each thickness group was characterized by conducting uniaxial tensile experiments. The experiments were done in mineral oil in order to keep the thickness of samples constant and minimize hydration changes. It was observed that collagen cross-linking treatment significantly increased both the maximum tensile stress and the equilibrium (relaxed) stress of the bovine cornea (p  0.99), respectively. Hydration and collagen cross-linking treatment concomitantly affect biomechanical properties of the cornea. Therefore, an accurate estimate of stiffening effects of collagen cross-linking treatment option using uniaxial tensile experiments is only possible if the hydration of specimens is fully controlled.

  19. Hydrate Evolution in Response to Ongoing Environmental Shifts

    Energy Technology Data Exchange (ETDEWEB)

    Rempel, Alan [Univ. of Oregon, Eugene, OR (United States)

    2015-12-31

    Natural gas hydrates have the potential to become a vital domestic clean-burning energy source. However, past changes in environmental conditions have caused hydrates to become unstable and trigger both massive submarine landslides and the development of crater-like pockmarks, thereby releasing methane into the overlying seawater and atmosphere, where it acts as a powerful greenhouse gas. This project was designed to fill critical gaps in our understanding of domestic hydrate resources and improve forecasts for their response to environmental shifts. Project work can be separated into three interrelated components, each involving the development of predictive mathematical models. The first project component concerns the role of sediment properties on the development and dissociation of concentrated hydrate anomalies. To this end, we developed numerical models to predict equilibrium solubility of methane in twophase equilibrium with hydrate as a function of measureable porous medium characteristics. The second project component concerned the evolution of hydrate distribution in heterogeneous reservoirs. To this end, we developed numerical models to predict the growth and decay of anomalies in representative physical environments. The third project component concerned the stability of hydrate-bearing slopes under changing environmental conditions. To this end, we developed numerical treatments of pore pressure evolution and consolidation, then used "infinite-slope" analysis to approximate the landslide potential in representative physical environments, and developed a "rate-and-state" frictional formulation to assess the stability of finite slip patches that are hypothesized to develop in response to the dissociation of hydrate anomalies. The increased predictive capabilities that result from this work provide a framework for interpreting field observations of hydrate anomalies in terms of the history of environmental forcing that led to their development. Moreover

  20. Hydration-controlled bacterial motility and dispersal on surfaces

    DEFF Research Database (Denmark)

    Dechesne, Arnaud; Wang, G.; Gulez, Gamze

    2010-01-01

    Flagellar motility, a mode of active motion shared by many prokaryotic species, is recognized as a key mechanism enabling population dispersal and resource acquisition in microbial communities living in marine, freshwater, and other liquid-replete habitats. By contrast, its role in variably...... resume motility in response to periodic increases in hydration. We propose a biophysical model that captures key effects of hydration and liquid-film thickness on individual cell velocity and use a simple roughness network model to simulate colony expansion. Model predictions match experimental results...... the costs associated with flagella synthesis and explain the sustained presence of flagellated prokaryotes in partially saturated habitats such as soil surfaces....

  1. TOUGH+HYDRATE v1.2 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media

    Energy Technology Data Exchange (ETDEWEB)

    Moridis, George J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kowalsky, Michael B. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Pruess, Karsten [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2012-08-01

    TOUGH+HYDRATE v1.2 is a code for the simulation of the behavior of hydratebearing geologic systems, and represents the second update of the code since its first release [Moridis et al., 2008]. By solving the coupled equations of mass and heat balance, TOUGH+HYDRATE can model the non-isothermal gas release, phase behavior and flow of fluids and heat under conditions typical of common natural CH4-hydrate deposits (i.e., in the permafrost and in deep ocean sediments) in complex geological media at any scale (from laboratory to reservoir) at which Darcy’s law is valid. TOUGH+HYDRATE v1.2 includes both an equilibrium and a kinetic model of hydrate formation and dissociation. The model accounts for heat and up to four mass components, i.e., water, CH4, hydrate, and water-soluble inhibitors such as salts or alcohols. These are partitioned among four possible phases (gas phase, liquid phase, ice phase and hydrate phase). Hydrate dissociation or formation, phase changes and the corresponding thermal effects are fully described, as are the effects of inhibitors. The model can describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects and inhibitor-induced effects. TOUGH+HYDRATE is a member of TOUGH+, the successor to the TOUGH2 [Pruess et al., 1991] family of codes for multi-component, multiphase fluid and heat flow developed at the Lawrence Berkeley National Laboratory. It is written in standard FORTRAN 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available.

  2. Coupled numerical modeling of gas hydrates bearing sediments from laboratory to field-scale conditions

    Science.gov (United States)

    Sanchez, M. J.; Santamarina, C.; Gai, X., Sr.; Teymouri, M., Sr.

    2017-12-01

    Stability and behavior of Hydrate Bearing Sediments (HBS) are characterized by the metastable character of the gas hydrate structure which strongly depends on thermo-hydro-chemo-mechanical (THCM) actions. Hydrate formation, dissociation and methane production from hydrate bearing sediments are coupled THCM processes that involve, amongst other, exothermic formation and endothermic dissociation of hydrate and ice phases, mixed fluid flow and large changes in fluid pressure. The analysis of available data from past field and laboratory experiments, and the optimization of future field production studies require a formal and robust numerical framework able to capture the very complex behavior of this type of soil. A comprehensive fully coupled THCM formulation has been developed and implemented into a finite element code to tackle problems involving gas hydrates sediments. Special attention is paid to the geomechanical behavior of HBS, and particularly to their response upon hydrate dissociation under loading. The numerical framework has been validated against recent experiments conducted under controlled conditions in the laboratory that challenge the proposed approach and highlight the complex interaction among THCM processes in HBS. The performance of the models in these case studies is highly satisfactory. Finally, the numerical code is applied to analyze the behavior of gas hydrate soils under field-scale conditions exploring different features of material behavior under possible reservoir conditions.

  3. Molecular dynamics simulation of the intercalation behaviors of methane hydrate in montmorillonite.

    Science.gov (United States)

    Yan, KeFeng; Li, XiaoSen; Xu, ChunGang; Lv, QiuNan; Ruan, XuKe

    2014-06-01

    The formation and mechanism of CH4 hydrate intercalated in montmorillonite are investigated by molecular dynamics (MD) simulation. The formation process of CH4 hydrate in montmorillonite with 1 ~ 8 H2O layers is observed. In the montmorillonite, the "surface H2O" constructs the network by hydrogen bonds with the surface Si-O ring of clay, forming the surface cage. The "interlayer H2O" constructs the network by hydrogen bonds, forming the interlayer cage. CH4 molecules and their surrounding H2O molecules form clathrate hydrates. The cation of montmorillonite has a steric effect on constructing the network and destroying the balance of hydrogen bonds between the H2O molecules, distorting the cage of hydrate in clay. Therefore, the cages are irregular, which is unlike the ideal CH4 clathrate hydrates cage. The pore size of montmorillonite is another impact factor to the hydrate formation. It is quite easier to form CH4 hydrate nucleation in montmorillonite with large pore size than in montmorillonite with small pore. The MD work provides the constructive information to the investigation of the reservoir formation for natural gas hydrate (NGH) in sediments.

  4. Different Mechanism Effect between Gas-Solid and Liquid-Solid Interface on the Three-Phase Coexistence Hydrate System Dissociation in Seawater: A Molecular Dynamics Simulation Study

    Directory of Open Access Journals (Sweden)

    Zhixue Sun

    2017-12-01

    Full Text Available Almost 98% of methane hydrate is stored in the seawater environment, the study of microscopic mechanism for methane hydrate dissociation on the sea floor is of great significance to the development of hydrate production, involving a three-phase coexistence system of seawater (3.5% NaCl + hydrate + methane gas. The molecular dynamics method is used to simulate the hydrate dissociation process. The dissociation of hydrate system depends on diffusion of methane molecules from partially open cages and a layer by layer breakdown of the closed cages. The presence of liquid or gas phases adjacent to the hydrate has an effect on the rate of hydrate dissociation. At the beginning of dissociation process, hydrate layers that are in contact with liquid phase dissociated faster than layers adjacent to the gas phase. As the dissociation continues, the thickness of water film near the hydrate-liquid interface became larger than the hydrate-gas interface giving more resistance to the hydrate dissociation. Dissociation rate of hydrate layers adjacent to gas phase gradually exceeds the dissociation rate of layers adjacent to the liquid phase. The difficulty of methane diffusion in the hydrate-liquid side also brings about change in dissociation rate.

  5. Ductile flow of methane hydrate

    Science.gov (United States)

    Durham, W.B.; Stern, L.A.; Kirby, S.H.

    2003-01-01

    Compressional creep tests (i.e., constant applied stress) conducted on pure, polycrystalline methane hydrate over the temperature range 260-287 K and confining pressures of 50-100 MPa show this material to be extraordinarily strong compared to other icy compounds. The contrast with hexagonal water ice, sometimes used as a proxy for gas hydrate properties, is impressive: over the thermal range where both are solid, methane hydrate is as much as 40 times stronger than ice at a given strain rate. The specific mechanical response of naturally occurring methane hydrate in sediments to environmental changes is expected to be dependent on the distribution of the hydrate phase within the formation - whether arranged structurally between and (or) cementing sediments grains versus passively in pore space within a sediment framework. If hydrate is in the former mode, the very high strength of methane hydrate implies a significantly greater strain-energy release upon decomposition and subsequent failure of hydrate-cemented formations than previously expected.

  6. The Effect of Hydration on the Cation-π Interaction Between ...

    Indian Academy of Sciences (India)

    6-31G(d,p) basis set reveal a qualitative trend in the relative affinity of different cations for benzene and water in these complexes. The π–cloud thickness values for benzene have also been estimated for these systems. Keywords. Cation-π interaction; π-thickness; non-covalent interaction; hydration; alkali and alkaline earth.

  7. Comparing the sensitivity of permafrost and marine gas hydrate to climate warming

    International Nuclear Information System (INIS)

    Taylor, A.E.; Dallimore, S.R.; Hyndman, R.D.; Wright, F.

    2005-01-01

    The sensitivity of Arctic subpermafrost gas hydrate at the Mallik borehole was compared to temperate marine gas hydrate located offshore southwestern Canada. In particular, a finite element geothermal model was used to determine the sensitivity to the end of the ice age, and contemporary climate warming of a 30 m thick methane hydrate layer lying at the base of a gas hydrate stability zone prior to 13.5 kiloannum (ka) before present (BP). It was suggested that the 30 m gas-hydrate-bearing layer would have disappeared by now, according to the thermal signal alone. However, the same gas-hydrate-bearing layer underlying permafrost would persist until at least 4 ka after present, even with contemporary climate warming. The longer time for subpermafrost gas hydrate comes from the thawing pore ice at the base of permafrost, at the expense of dissociation of the deeper gas hydrate. The dissociation of underlying gas hydrate from climate surface warming is buffered by the overlying permafrost

  8. Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Overview of scientific and technical program

    Science.gov (United States)

    Hunter, R.B.; Collett, T.S.; Boswell, R.; Anderson, B.J.; Digert, S.A.; Pospisil, G.; Baker, R.; Weeks, M.

    2011-01-01

    The Mount Elbert Gas Hydrate Stratigraphic Test Well was drilled within the Alaska North Slope (ANS) Milne Point Unit (MPU) from February 3 to 19, 2007. The well was conducted as part of a Cooperative Research Agreement (CRA) project co-sponsored since 2001 by BP Exploration (Alaska), Inc. (BPXA) and the U.S. Department of Energy (DOE) in collaboration with the U.S. Geological Survey (USGS) to help determine whether ANS gas hydrate can become a technically and commercially viable gas resource. Early in the effort, regional reservoir characterization and reservoir simulation modeling studies indicated that up to 0.34 trillion cubic meters (tcm; 12 trillion cubic feet, tcf) gas may be technically recoverable from 0.92 tcm (33 tcf) gas-in-place within the Eileen gas hydrate accumulation near industry infrastructure within ANS MPU, Prudhoe Bay Unit (PBU), and Kuparuk River Unit (KRU) areas. To further constrain these estimates and to enable the selection of a test site for further data acquisition, the USGS reprocessed and interpreted MPU 3D seismic data provided by BPXA to delineate 14 prospects containing significant highly-saturated gas hydrate-bearing sand reservoirs. The "Mount Elbert" site was selected to drill a stratigraphic test well to acquire a full suite of wireline log, core, and formation pressure test data. Drilling results and data interpretation confirmed pre-drill predictions and thus increased confidence in both the prospect interpretation methods and in the wider ANS gas hydrate resource estimates. The interpreted data from the Mount Elbert well provide insight into and reduce uncertainty of key gas hydrate-bearing reservoir properties, enable further refinement and validation of the numerical simulation of the production potential of both MPU and broader ANS gas hydrate resources, and help determine viability of potential field sites for future extended term production testing. Drilling and data acquisition operations demonstrated that gas hydrate

  9. Electromagnetic Heating Methods for Heavy Oil Reservoirs

    International Nuclear Information System (INIS)

    Sahni, A.; Kumar, M.; Knapp, R.B.

    2000-01-01

    The most widely used method of thermal oil recovery is by injecting steam into the reservoir. A well-designed steam injection project is very efficient in recovering oil, however its applicability is limited in many situations. Simulation studies and field experience has shown that for low injectivity reservoirs, small thickness of the oil-bearing zone, and reservoir heterogeneity limits the performance of steam injection. This paper discusses alternative methods of transferring heat to heavy oil reservoirs, based on electromagnetic energy. They present a detailed analysis of low frequency electric resistive (ohmic) heating and higher frequency electromagnetic heating (radio and microwave frequency). They show the applicability of electromagnetic heating in two example reservoirs. The first reservoir model has thin sand zones separated by impermeable shale layers, and very viscous oil. They model preheating the reservoir with low frequency current using two horizontal electrodes, before injecting steam. The second reservoir model has very low permeability and moderately viscous oil. In this case they use a high frequency microwave antenna located near the producing well as the heat source. Simulation results presented in this paper show that in some cases, electromagnetic heating may be a good alternative to steam injection or maybe used in combination with steam to improve heavy oil production. They identify the parameters which are critical in electromagnetic heating. They also discuss past field applications of electromagnetic heating including technical challenges and limitations

  10. Flow assurance intervention, hydrates remediation

    Energy Technology Data Exchange (ETDEWEB)

    Mancini, Christopher S. [Oceaneering International Inc., Houston, TX (United States)

    2012-07-01

    This paper addresses the issues of removing hydrates in sub sea flow lines and associated equipment with an Remotely Operated Vehicle (ROV) of opportunity and a multi-service-vessel (MSV). The paper is split into three topics: the equipment used with the ROV, assessing the interface points and handling fluids produced from drawing down the pressure. Each section is explained thoroughly and backed up with real world experience. The equipment section details information from actual jobs performed and why the particular components were utilized. The system is generally contained in an ROV mounted skid. Pumps are utilized to draw down the pressure inside the hydrated section of equipment, removing one of the three necessary components for hydrates formation. Once the section is pumped down, several options exist for handling the fluids pumped out of the system: pumping to surface, re-injection into the well, or injection into an operating flow line. This method of hydrates remediation is both economical and timely. Hydrate blockages form in low temperatures and high pressures. Reducing the pressure or increasing the temperature so the conditions lie to the right of the hydrate dissociation curve will slowly decompose the blockage. Depressurization and the use of MEG or methanol will give favorable conditions to remove the hydrate plug. Oceaneering has the capabilities to remove hydrates using the FRS in conjunction with an installation vessel to dispose of the gas and fluid removed from the flow line. Hydrate remediation techniques should be implemented into the initial design to reduce costs later. The cost of stopped production combined with the day rate for equipment needed for hydrate removal outweighs the costs if no technique is utilized. (author)

  11. Modeling the formation of methane hydrate-bearing intervals in fine-grained sediments

    Energy Technology Data Exchange (ETDEWEB)

    Malinverno, Alberto; Cook, Ann; Daigle, Hugh

    2016-09-30

    Sediment grain size exerts a fundamental control on how methane hydrates are distributed within the pore space. Fine-grained muds are the predominant sediments in continental margins, and hydrates in these sediments have often been observed in semi-vertical veins and fractures. In several instances, these hydrate veins/fractures are found in discrete depth intervals a few tens meters thick within the gas hydrate stability zone (GHSZ) surrounded by hydrate-free sediments above and below. As they are not obviously connected with free gas occurring beneath the base of the GHSZ, these isolated hydrate-bearing intervals have been interpreted as formed by microbial methane generated in situ. To investigate further the formation of these hydrate deposits, we applied a time-dependent advection-diffusion-reaction model that includes the effects of sedimentation, solute diffusion, and microbial methane generation. The microbial methane generation term depends on the amount of metabolizable organic carbon deposited at the seafloor, which is degraded at a prescribed rate resulting in methane formation beneath the sulfate reduction zone. In the model, methane hydrate precipitates once the dissolved methane concentration is greater than solubility, or hydrate dissolves if concentration goes below solubility. If the deposition of organic carbon at the seafloor is kept constant in time, we found that the predicted amounts of hydrate formed in discrete intervals within the GHSZ are much less than those estimated from observations. We then investigated the effect of temporal variations in the deposition of organic carbon. If greater amounts of organic carbon are deposited during some time interval, methane generation is enhanced during burial in the corresponding sediment interval. With variations in organic carbon deposition that are consistent with observations in continental margin sediments, we were able to reproduce the methane hydrate contents estimated in discrete depth

  12. Hydrate prevention in petroleum production sub sea system

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Paula L.F.; Rocha, Humberto A.R. [Universidade Estacio de Sa (UNESA), Rio de Janeiro, RJ (Brazil); Rodrigues, Antonio P. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2012-07-01

    In spite of the merits of the several hydrate prevention techniques used nowadays, such as: chemical product injection for inhibition and use of thick thermal insulate lines; hydrates per times happen and they are responsible for considerable production losses. Depressurization techniques can be used so much for prevention as in the remediation. Some hydrate removal techniques need a rig or vessel, resources not readily available and with high cost, reason that limits such techniques just for remediation and not for prevention. In the present work it is proposed and described an innovative depressurization system, remote and resident, for hydrate prevention and removal, applicable as for individual sub sea wells as for grouped wells by manifold. Based on low cost jet pumps, without movable parts and with a high reliability, this technique allows hydrate prevention or remediation in a fast and remote way, operated from the production unit. The power fluid line and fluid return line can be integrated in the same umbilical or annulus line structure, without significant increase in the construction costs and installation. It is not necessary to wait for expensive resource mobilization, sometimes not available quickly, such as: vessels or rigs. It still reduces the chemical product consumption and permits to depressurized stopped lines. Other additional advantage, depressurization procedure can be used in the well starting, removing fluid until riser emptying. (author)

  13. Shifting Focus: From Hydration for Performance to Hydration for Health.

    Science.gov (United States)

    Perrier, Erica T

    2017-01-01

    Over the past 10 years, literature on hydration biomarkers has evolved considerably - from (de)hydration assessment towards a more global definition of biomarkers of hydration in daily life. This shift in thinking about hydration markers was largely driven by investigating the differences that existed between otherwise healthy individuals whose habitual, ad-libitum drinking habits differ, and by identifying physiological changes in low-volume drinkers who subsequently increase their water intake. Aside from obvious differences in urinary volume and concentration, a growing body of evidence is emerging that links differences in fluid intake with small, but biologically significant, differences in vasopressin (copeptin), glomerular filtration rate, and markers of metabolic dysfunction or disease. Taken together, these pieces of the puzzle begin to form a picture of how much water intake should be considered adequate for health, and represent a shifting focus from hydration for performance, toward hydration for health outcomes. This narrative review outlines the key areas of research in which the global hydration process - including water intake, urinary hydration markers, and vasopressin - has been associated with health outcomes, focusing on kidney and metabolic endpoints. It will also provide a commentary on how various hydration biomarkers may be used in hydration for health assessment. Finally, if adequate water intake can play a role in maintaining health, how might we tell if we are drinking enough? Urine output is easily measured, and can take into account differences in daily physical activity, climate, dietary solute load, and other factors that influence daily water needs. Today, targets have been proposed for urine osmolality, specific gravity, and color that may be used by researchers, clinicians, and individuals as simple indicators of optimal hydration. However, there remain a large number of incomplete or unanswered research questions regarding the

  14. New Approaches for the Production of Hydrocarbons from Hydrate Bearing Sediments

    Directory of Open Access Journals (Sweden)

    Ronny Giese

    2011-01-01

    Full Text Available The presence of natural gas hydrates at all active and passive continental margins has been proven. Their global occurrence as well as the fact that huge amounts of methane and other lighter hydrocarbons are stored in natural gas hydrates has led to the idea of using hydrate bearing sediments as an energy resource. However, natural gas hydrates remain stable as long as they are in mechanical, thermal and chemical equilibrium with their environment. Thus, for the production of gas from hydrate bearing sediments, at least one of these equilibrium states must be disturbed by depressurization, heating or addition of chemicals such as CO2. Depressurization, thermal or chemical stimulation may be used alone or in combination, but the idea of producing hydrocarbons from hydrate bearing sediments by CO2 injection suggests the potential of an almost emission free use of this unconventional natural gas resource. However, up to now there are still open questions regarding all three production principles. Within the framework of the German national research project SUGAR the thermal stimulation method by use of in situ combustion was developed and tested on a pilot plant scale and the CH4-CO2 swapping process in gas hydrates studied on a molecular level. Microscopy, confocal Raman spectroscopy and X-ray diffraction were used for in situ investigations of the CO2-hydrocarbon exchange process in gas hydrates and its driving forces. For the thermal stimulation a heat exchange reactor was designed and tested for the exothermal catalytic oxidation of methane. Furthermore, a large scale reservoir simulator was realized to synthesize hydrates in sediments under conditions similar to nature and to test the efficiency of the reactor. Thermocouples placed in the reservoir simulator with a total volume of 425 L collect data regarding the propagation of the heat front. In addition, CH4 sensors are placed in the water saturated sediment to detect the distribution of CH4

  15. Effect of well construction on the mechanical state of unconsolidated methane hydrate-bearing sediment

    Science.gov (United States)

    Sasaki, T.; Soga, K.; Yamamoto, K.

    2016-12-01

    World's first offshore production of gas from methane hydrate-bearing sediment was accomplished in Nankai Trough off the coast of Japan. The achievement signals the beginning of exploitation of methane hydrate as a new source of energy, as an estimated amount of the new gas resource significantly exceeds that of the existing conventional oil and gas resources. Conventional gas reservoirs exist in consolidated sediment (i.e. rocks) thousands of metres below seafloor, and such sediment is hard enough to resist deformation. Methane hydrate reservoirs, on the other hand, lies only a couple of hundreds of metres down the seafloor, which means the sediment is unconsolidated (i.e. soils) and is readily deformed. In addition, the hydrate melts away in the pore space when it releases gas, giving rise to a significant rearrangement of stresses in the sediment. Well construction in methane hydrate reservoir might affect the mechanical state of the sediment to the point where the interpretation of the fracture pressure test becomes difficult and sand production could be enhanced. Existing numerical simulations tend to overlook soil mechanics, which is more appropriate than rock mechanics to model unconsolidated sediment, and the effect of methane hydrate on soil's mechanical behaviour is missed. In the present research, the construction of well in unconsolidated hydrate-bearing sediment was modelled with finite element analysis incorporating the critical state soil mechanics. Results showed that cement shrinkage in the well annulus would have a significant effect on the principal stresses and directions of the sediment even if the magnitude of the shrinkage was 0.1%. Cement shrinkage would also promote the generation of plastic strains, potentially enhancing sand production. Results also showed that the direction of fracture inferred from a fracture pressure test at Nankai Trough might have been vertical, indicating it was developed at the cement-sediment interface.

  16. Study on gas hydrate as a new energy resource in the 21th century

    Energy Technology Data Exchange (ETDEWEB)

    Ryu, Byeong-Jae; Kwak Young-Hoon; Kim, Won-Sik [Korea Institute of Geology Mining and Materials, Taejon (KR)] (and others)

    1999-12-01

    Natural gas hydrate, a special type of clathrate hydrates, is a metastable solid compound which mainly consists of methane and water, and generally called as gas hydrate. It is stable in the specific low-temperature/high-pressure conditions. Gas hydrates play an important role as major reservoir of methane on the earth. On the other hand, the formation and dissociation of gas hydrates could cause the plugging in pipeline, gas kick during production, atmospheric pollution and geohazard. To understand the formation and dissociation of the gas hydrate, the experimental equilibrium conditions of methane hydrate were measured in pure water, 3 wt.% NaCl and MgCl{sub 2} solutions. The equilibrium conditions of propane hydrates were also measured in pure water. The relationship between methane hydrate formation time and overpressure was also analyzed through the laboratory work. The geophysical surveys using air-gun system and multibeam echo sounder were implemented to develop exploration techniques and to evaluate the gas hydrate potential in the East Sea, Korea. General indicators of submarine gas hydrates on seismic data is commonly inferred from the BSR developed parallel to the see floor, amplitude blanking at the upper part of the BSR, and phase reversal and decrease of the interval velocity at BSR. The field data were processed using Geobit 2.9.5 developed by KIGAM to detect the gas hydrate indicators. The accurate velocity analysis was performed by XVA (X-window based Velocity Analysis). Processing results show that the strong reflector occurred parallel to the sea floor were shown at about 1800 ms two way travel time. The interval velocity decrease at this strong reflector and at the reflection phase reversal corresponding to the reflection at the sea floor. Gas hydrate stability field in the study area was determined using the data of measured hydrate equilibrium condition, hydrothermal gradient and geothermal gradient. The depth of BSR detected in the seismic

  17. Geological Characterisation of Depleted Oil and Gas Reservoirs for ...

    African Journals Online (AJOL)

    Comparison of the derived reservoir and seal properties such as porosity, permeability, thickness and depth with the minimum recommended site selection criteria shows that the reservoirs are potential candidates for carbon geosequestration with a total theoretical storage capacity of 147MM tons. © JASEM ...

  18. Development of Alaskan gas hydrate resources: Annual report, October 1986--September 1987

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, G.D.; Kamath, V.A.; Godbole, S.P.; Patil, S.L.; Paranjpe, S.G.; Mutalik, P.N.; Nadem, N.

    1987-10-01

    Solid ice-like mixtures of natural gas and water in the form of natural gas hydrated have been found immobilized in the rocks beneath the permafrost in Arctic basins and in muds under the deep water along the American continental margins, in the North Sea and several other locations around the world. It is estimated that the arctic areas of the United States may contain as much as 500 trillion SCF of natural gas in the form of gas hydrates (Lewin and Associates, 1983). While the US Arctic gas hydrate resources may have enormous potential and represent long term future source of natural gas, the recovery of this resource from reservoir frozen with gas hydrates has not been commercialized yet. Continuing study and research is essential to develop technologies which will enable a detailed characterization and assessment of this alternative natural gas resource, so that development of cost effective extraction technology.

  19. Preface to the special issue on gas hydrate drilling in the Eastern Nankai Trough

    Science.gov (United States)

    Yamamoto, Koji; Ruppel, Carolyn D.

    2015-01-01

    Methane hydrate traps enormous amounts of methane in frozen deposits in continental margin sediments, and these deposits have long been targeted for studies investigating their potential as an energy resource. As a concentrated form of methane that occurs at shallower depths than conventional and most unconventional gas reservoirs, methane hydrates could be a readily accessible source of hydrocarbons for countries hosting deposits within their Exclusive Economic Zones. Japan is one such country, and since 2001 the Research Consortium for Methane Hydrate Resources in Japan (referred to as MH21) has conducted laboratory, modeling, and field-based programs to study methane hydrates as an energy resource. The MH21 consortium is funded by the Japanese Ministry of Trade and Industry (METI) and led by the Japan Oil, Gas and Metals National Oil Corporation (JOGMEC) and the National Institute of Advanced Industrial Science and Technology (AIST).

  20. Relict thermokarst carbon source kept stable within gas hydrate stability zone of the South Kara Sea

    Science.gov (United States)

    Portnov, A.; Mienert, J.; Winsborrow, M.; Vadakkepuliyambatta, S.; Semenov, P.

    2017-12-01

    Substantial shallow sources of carbon can exist in the South Kara Sea shelf, extending offshore from the permafrost areas of Yamal Peninsula and the Polar Ural coast. Our study presents new evidence for >250 buried relict thermokarst units. These amalgamated thawing wedges formed in the uppermost permafrost of the past and are still recognizable in today's non-permafrost areas. Part of these potential carbon reservoirs are kept stable within the South Kara Sea gas hydrate stability zone (GHSZ). We utilize an extensive 2D high-resolution seismic dataset, collected in the South Kara Sea in 2005-2006 by Marine Arctic Geological Expedition (MAGE), to map distinctive U-shaped units that are acoustically transparent. These units appear all over the study area in water depths 50-250 m. Created by thermal erosion into Cretaceous-Paleogene bedrock, they are buried under the younger glacio-marine deposits and reach hundreds of meters wide and up to 100 meters thick. They show the characteristics of relict thermokarst, generated during ancient episode(s) of sea level regression of the South Kara Sea. These thermokarst units are generally limited by the Upper Regional Unconformity, which is an erosional horizon created by several glaciation events during the Pleistocene. On land, permafrost is known to sequester large volumes of carbon, half of which is concentrated within thermokarst structures. Based on modern thermokarst analogues we demonstrate with our study that a significant amount of organic carbon can be stored under the Kara Sea. To assess the stability of these shallow carbon reservoirs we carried out GHSZ modeling, constrained by geochemical analyses, temperature measurements and precise bathymetry. This revealed a significant potential for a GHSZ in water depths >225 m. The relict thermokast carbon storage system is stable under today's extremely low bottom water temperatures ( -1.7 °C) that allows for buried GHSZ, located tens of meters below the seabed

  1. IMPACT OF DYNAMICAL HYDRATION SHELL AROUND HA PROTEIN ON NONLINEAR CONCENTRATION DEPENDENT T-RAYS ABSORPTION

    Directory of Open Access Journals (Sweden)

    YIWEN SUN

    2013-10-01

    Full Text Available T-rays is sensitive to covalently cross-linked proteins and can be used to probe unique dynamic properties of water surrounding a protein. In this paper, we demonstrate the unique absorption properties of the dynamic hydration shells determined by hemagglutinin (HA protein in terahertz frequency. We study the changes arising from different concentrations in detail and show that nonlinear absorption coefficient is induced by the dynamic hydration water. The binary and ternary component model were used to interpret the nonlinearity absorption behaviors and predict the thickness of the hydration shells around the HA protein in aqueous phase.

  2. Controlled formation of cyclopentane hydrate suspensions via capillary-driven jet break-up

    Science.gov (United States)

    Geri, Michela; McKinley, Gareth

    2017-11-01

    Clathrate hydrates are crystalline compounds that form when a lattice of hydrogen-bonded water molecules is filled by guest molecules sequestered from an adjacent gas or liquid phase. Being able to rapidly produce and transport synthetic hydrates is of great interest given their significant potential as a clean energy source and safe option for hydrogen storage. We propose a new method to rapidly produce cyclopentane hydrate suspensions at ambient pressure with tunable particle size distribution by taking advantage of the Rayleigh-Plateau instability to form a mono-disperse stream of droplets during the controlled break-up of a water jet. The droplets are immediately frozen into ice particles through immersion in a subcooled reservoir and converted into hydrates with a dramatic reduction in the nucleation induction time. By measuring the evolution of the rheological properties with time, we monitor the process of hydrates formation via surface crystallization and agglomeration with different droplet size distributions. This new method enables us to gain new insights into hydrate formation and transport which was previously hindered by uncontrolled droplet formation and hydrate nucleation processes. MITei Chevron Fellowship.

  3. The relation between hydration and mechanical behavior of bovine cornea in tension.

    Science.gov (United States)

    Hatami-Marbini, Hamed; Rahimi, Abdolrasol

    2014-08-01

    The cornea is a transparent soft tissue covering the front of the eye. The biomechanical properties of the cornea have been commonly investigated by uniaxial tensile and inflation testing methods. The cornea like many other hydrated tissue swells when immersed in an ionic solution. Previous studies on hydrated tissues have shown that mechanical properties and hydration are closely related. The present study was designed to investigate the effects of thickness (hydration) variation due to swelling/dehydration on non-linear stress-strain response of the bovine cornea. Corneal strips were first air-dried and then soaked in a bathing solution until they reached an average thickness ranging from 0.3mm to 1.1mm. Based on their thickness, the samples were divided into different groups and uniaxial tests were performed to measure tensile properties. All experiments were done in mineral oil to prevent any hydration gain or loss during the tests. It was observed that swollen corneas had softer tensile properties in comparison with dehydrated ones. In particular, there was a significant difference between elastic tangent modulus of different groups (P<0.05). It was also shown that tensile behavior of bovine strips at any thickness within the range of 0.4-1.1mm can be obtained from a single experiment conducted on samples with known thickness (hydration). The findings of the present study confirm that mechanical properties obtained from uniaxial tensile experiments are strongly dependent on thickness (water amount) of samples; therefore, careful attention must be taken in interpreting previous studies which did not fully control the thickness of specimens. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. RESOURCE CHARACTERIZATION AND QUANTIFICATION OF NATURAL GAS-HYDRATE AND ASSOCIATED FREE-GAS ACCUMULATIONS IN THE PRUDHOE BAY - KUPARUK RIVER AREA ON THE NORTH SLOPE OF ALASKA

    Energy Technology Data Exchange (ETDEWEB)

    Robert Hunter; Shirish Patil; Robert Casavant; Tim Collett

    2003-06-02

    Interim results are presented from the project designed to characterize, quantify, and determine the commercial feasibility of Alaska North Slope (ANS) gas-hydrate and associated free-gas resources in the Prudhoe Bay Unit (PBU), Kuparuk River Unit (KRU), and Milne Point Unit (MPU) areas. This collaborative research will provide practical input to reservoir and economic models, determine the technical feasibility of gas hydrate production, and influence future exploration and field extension of this potential ANS resource. The large magnitude of unconventional in-place gas (40-100 TCF) and conventional ANS gas commercialization evaluation creates industry-DOE alignment to assess this potential resource. This region uniquely combines known gas hydrate presence and existing production infrastructure. Many technical, economical, environmental, and safety issues require resolution before enabling gas hydrate commercial production. Gas hydrate energy resource potential has been studied for nearly three decades. However, this knowledge has not been applied to practical ANS gas hydrate resource development. ANS gas hydrate and associated free gas reservoirs are being studied to determine reservoir extent, stratigraphy, structure, continuity, quality, variability, and geophysical and petrophysical property distribution. Phase 1 will characterize reservoirs, lead to recoverable reserve and commercial potential estimates, and define procedures for gas hydrate drilling, data acquisition, completion, and production. Phases 2 and 3 will integrate well, core, log, and long-term production test data from additional wells, if justified by results from prior phases. The project could lead to future ANS gas hydrate pilot development. This project will help solve technical and economic issues to enable government and industry to make informed decisions regarding future commercialization of unconventional gas-hydrate resources.

  5. Reservoir fisheries of Asia

    International Nuclear Information System (INIS)

    Silva, S.S. De.

    1990-01-01

    At a workshop on reservoir fisheries research, papers were presented on the limnology of reservoirs, the changes that follow impoundment, fisheries management and modelling, and fish culture techniques. Separate abstracts have been prepared for three papers from this workshop

  6. Hydration water and microstructure in calcium silicate and aluminate hydrates

    International Nuclear Information System (INIS)

    Fratini, Emiliano; Ridi, Francesca; Chen, Sow-Hsin; Baglioni, Piero

    2006-01-01

    Understanding the state of the hydration water and the microstructure development in a cement paste is likely to be the key for the improvement of its ultimate strength and durability. In order to distinguish and characterize the reacted and unreacted water, the single-particle dynamics of water molecules in hydrated calcium silicates (C 3 S, C 2 S) and aluminates (C 3 A, C 4 AF) were studied by quasi-elastic neutron scattering, QENS. The time evolution of the immobile fraction represents the hydration kinetics and the mobile fraction follows a non-Debye relaxation. Less sophisticated, but more accessible and cheaper techniques, like differential scanning calorimetry, DSC, and near-infrared spectroscopy, NIR, were validated through QENS results and they allow one to easily and quantitatively follow the cement hydration kinetics and can be widely applied on a laboratory scale to understand the effect of additives (i.e., superplasticizers, cellulosic derivatives, etc) on the thermodynamics of the hydration process. DSC provides information on the free water index and on the activation energy involved in the hydration process while the NIR band at 7000 cm -1 monitors, at a molecular level, the increase of the surface-interacting water. We report as an example the effect of two classes of additives widely used in the cement industry: superplasticizers, SPs, and cellulose derivatives. SPs interact at the solid surface, leading to a consistent increment of the activation energy for the processes of nucleation and growth of the hydrated phases. In contrast, the cellulosic additives do not affect the nucleation and growth activation energy, but cause a significant increment in the water availability: in other words the hydration process is more efficient without any modification of the solid/liquid interaction, as also evidenced by the 1 H-NMR. Additional information is obtained by scanning electron microscopy (SEM), ultra small angle neutron scattering (USANS) and wide

  7. Hydration water and microstructure in calcium silicate and aluminate hydrates

    Energy Technology Data Exchange (ETDEWEB)

    Fratini, Emiliano [Department of Chemistry and CSGI, University of Florence, via della Lastruccia 3-Sesto Fiorentino, I-50019 Florence (Italy); Ridi, Francesca [Department of Chemistry and CSGI, University of Florence, via della Lastruccia 3-Sesto Fiorentino, I-50019 Florence (Italy); Chen, Sow-Hsin [Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Baglioni, Piero [Department of Chemistry and CSGI, University of Florence, via della Lastruccia 3-Sesto Fiorentino, I-50019 Florence (Italy)

    2006-09-13

    Understanding the state of the hydration water and the microstructure development in a cement paste is likely to be the key for the improvement of its ultimate strength and durability. In order to distinguish and characterize the reacted and unreacted water, the single-particle dynamics of water molecules in hydrated calcium silicates (C{sub 3}S, C{sub 2}S) and aluminates (C{sub 3}A, C{sub 4}AF) were studied by quasi-elastic neutron scattering, QENS. The time evolution of the immobile fraction represents the hydration kinetics and the mobile fraction follows a non-Debye relaxation. Less sophisticated, but more accessible and cheaper techniques, like differential scanning calorimetry, DSC, and near-infrared spectroscopy, NIR, were validated through QENS results and they allow one to easily and quantitatively follow the cement hydration kinetics and can be widely applied on a laboratory scale to understand the effect of additives (i.e., superplasticizers, cellulosic derivatives, etc) on the thermodynamics of the hydration process. DSC provides information on the free water index and on the activation energy involved in the hydration process while the NIR band at 7000 cm{sup -1} monitors, at a molecular level, the increase of the surface-interacting water. We report as an example the effect of two classes of additives widely used in the cement industry: superplasticizers, SPs, and cellulose derivatives. SPs interact at the solid surface, leading to a consistent increment of the activation energy for the processes of nucleation and growth of the hydrated phases. In contrast, the cellulosic additives do not affect the nucleation and growth activation energy, but cause a significant increment in the water availability: in other words the hydration process is more efficient without any modification of the solid/liquid interaction, as also evidenced by the {sup 1}H-NMR. Additional information is obtained by scanning electron microscopy (SEM), ultra small angle neutron

  8. Large reservoirs: Chapter 17

    Science.gov (United States)

    Miranda, Leandro E.; Bettoli, Phillip William

    2010-01-01

    Large impoundments, defined as those with surface area of 200 ha or greater, are relatively new aquatic ecosystems in the global landscape. They represent important economic and environmental resources that provide benefits such as flood control, hydropower generation, navigation, water supply, commercial and recreational fisheries, and various other recreational and esthetic values. Construction of large impoundments was initially driven by economic needs, and ecological consequences received little consideration. However, in recent decades environmental issues have come to the forefront. In the closing decades of the 20th century societal values began to shift, especially in the developed world. Society is no longer willing to accept environmental damage as an inevitable consequence of human development, and it is now recognized that continued environmental degradation is unsustainable. Consequently, construction of large reservoirs has virtually stopped in North America. Nevertheless, in other parts of the world construction of large reservoirs continues. The emergence of systematic reservoir management in the early 20th century was guided by concepts developed for natural lakes (Miranda 1996). However, we now recognize that reservoirs are different and that reservoirs are not independent aquatic systems inasmuch as they are connected to upstream rivers and streams, the downstream river, other reservoirs in the basin, and the watershed. Reservoir systems exhibit longitudinal patterns both within and among reservoirs. Reservoirs are typically arranged sequentially as elements of an interacting network, filter water collected throughout their watersheds, and form a mosaic of predictable patterns. Traditional approaches to fisheries management such as stocking, regulating harvest, and in-lake habitat management do not always produce desired effects in reservoirs. As a result, managers may expend resources with little benefit to either fish or fishing. Some locally

  9. Geomechanical Performance of Hydrate-Bearing Sediments in Offshore Environments

    Energy Technology Data Exchange (ETDEWEB)

    Stephen A. Holditch

    2006-12-31

    The main objective of this study is to develop the necessary knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus is on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. To achieve this objective, we have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. To be sure our geomechanical modeling is realistic, we are also investigating the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. In Phase II of the project, we will review all published core data and generate additional core data to verify the models. To generate data for our models, we are using data from the literature and we will be conducting laboratory studies in 2007 that generate data to (1) evaluate the conceptual pore-scale models, (2) calibrate the mathematical models, (3) determine dominant relations and critical parameters defining the geomechanical behavior of HBS, and (4) establish relationships between the geomechanical status of HBS and the corresponding geophysical signature. The milestones for Phase I of this project are given as follows: Literature survey on typical sediments containing gas hydrates in the ocean (TAMU); Recommendations on how to create typical sediments in the laboratory (TAMU); Demonstrate that typical sediments can be created in a repeatable manner in the laboratory and gas hydrates can be created in the pore space (TAMU); Develop a conceptual pore-scale model based on available data and reports (UCB); Test the developed pore-scale concepts on simple configurations and verify the results against known measurements and observations (UCB

  10. Mechanism of gypsum hydration

    Directory of Open Access Journals (Sweden)

    Pacheco, G.

    1991-06-01

    Full Text Available There is an hypothesis that the mechanism o f gypsum hydration and dehydration is performed through two simultaneous phenomena. In this study we try to clear up this phenomenon using chlorides as accelerators or a mixture of ethanol-methanol as retarders to carry out the gypsum setting. Natural Mexican gypsum samples and a hemihydrate prepared in the laboratory are used. The following analytical techniques are used: MO, DRX, DTA, TG and DTG. In agreement with the obtained results, it can be concluded: that colloid formation depends on the action of accelerators or retarders and the crystals are a consequence of the quantity of hemihydrate formed.

    En el mecanismo de hidratación y deshidratación del yeso existe la hipótesis de que éste se efectúa por dos fenómenos simultáneos. Este estudio intenta esclarecer estos fenómenos, empleando: cloruros como aceleradores o mezcla etanol-metanol como retardadores para efectuar el fraguado del yeso. Se emplean muestras de yeso de origen natural mexicano y hemihydrate preparado en laboratorio; se utilizan técnicas analíticas: MO, DRX, DTA, TG y DTG. De acuerdo a los resultados obtenidos se puede deducir: que la formación del coloide depende de la acción de los agentes aceleradores o retardadores y que los cristales son consecuencia de la cantidad de hemihidrato formado.

  11. Observed correlation between the depth to base and top of gas hydrate occurrence from review of global drilling data

    Science.gov (United States)

    Riedel, M.; Collett, T. S.

    2017-07-01

    A global inventory of data from gas hydrate drilling expeditions is used to develop relationships between the base of structure I gas hydrate stability, top of gas hydrate occurrence, sulfate-methane transition depth, pressure (water depth), and geothermal gradients. The motivation of this study is to provide first-order estimates of the top of gas hydrate occurrence and associated thickness of the gas hydrate occurrence zone for climate-change scenarios, global carbon budget analyses, or gas hydrate resource assessments. Results from publically available drilling campaigns (21 expeditions and 52 drill sites) off Cascadia, Blake Ridge, India, Korea, South China Sea, Japan, Chile, Peru, Costa Rica, Gulf of Mexico, and Borneo reveal a first-order linear relationship between the depth to the top and base of gas hydrate occurrence. The reason for these nearly linear relationships is believed to be the strong pressure and temperature dependence of methane solubility in the absence of large difference in thermal gradients between the various sites assessed. In addition, a statistically robust relationship was defined between the thickness of the gas hydrate occurrence zone and the base of gas hydrate stability (in meters below seafloor). The relationship developed is able to predict the depth of the top of gas hydrate occurrence zone using observed depths of the base of gas hydrate stability within less than 50 m at most locations examined in this study. No clear correlation of the depth to the top and base of gas hydrate occurrences with geothermal gradient and sulfate-methane transition depth was identified.

  12. Observed correlation between the depth to base and top of gas hydrate occurrence from review of global drilling data

    Science.gov (United States)

    Riedel, Michael; Collett, Timothy S.

    2017-01-01

    A global inventory of data from gas hydrate drilling expeditions is used to develop relationships between the base of structure I gas hydrate stability, top of gas hydrate occurrence, sulfate-methane transition depth, pressure (water depth), and geothermal gradients. The motivation of this study is to provide first-order estimates of the top of gas hydrate occurrence and associated thickness of the gas hydrate occurrence zone for climate-change scenarios, global carbon budget analyses, or gas hydrate resource assessments. Results from publically available drilling campaigns (21 expeditions and 52 drill sites) off Cascadia, Blake Ridge, India, Korea, South China Sea, Japan, Chile, Peru, Costa Rica, Gulf of Mexico, and Borneo reveal a first-order linear relationship between the depth to the top and base of gas hydrate occurrence. The reason for these nearly linear relationships is believed to be the strong pressure and temperature dependence of methane solubility in the absence of large difference in thermal gradients between the various sites assessed. In addition, a statistically robust relationship was defined between the thickness of the gas hydrate occurrence zone and the base of gas hydrate stability (in meters below seafloor). The relationship developed is able to predict the depth of the top of gas hydrate occurrence zone using observed depths of the base of gas hydrate stability within less than 50 m at most locations examined in this study. No clear correlation of the depth to the top and base of gas hydrate occurrences with geothermal gradient and sulfate-methane transition depth was identified.

  13. Stream, Lake, and Reservoir Management.

    Science.gov (United States)

    Dai, Jingjing; Mei, Ying; Chang, Chein-Chi

    2017-10-01

    This review on stream, lake, and reservoir management covers selected 2016 publications on the focus of the following sections: Stream, lake, and reservoir management • Water quality of stream, lake, and reservoirReservoir operations • Models of stream, lake, and reservoir • Remediation and restoration of stream, lake, and reservoir • Biota of stream, lake, and reservoir • Climate effect of stream, lake, and reservoir.

  14. Reconsideration on Hydration of Sodium Ion: From Micro-Hydration to Bulk Hydration

    Science.gov (United States)

    Yongquan, Zhou; Chunhui, Fang; Yan, Fang; Fayan, Zhu; Haiwen, Ge; Hongyan, Liu

    2017-12-01

    Micro hydration structures of the sodium ion, [Na(H2O) n ]+, n = 1-12, were probed by density functional theory (DFT) at B3LYP/aug-cc-pVDZ level in both gaseous and aqueous phase. The predicted equilibrium sodium-oxygen distance of 0.240 nm at the present level of theory. The four-, five- and six-coordinated cluster can transform from each other at the ambient condition. The analysis of the successive water binding energy and natural charge population (NBO) on Na+ clearly shows that the influence of Na+ on the surrounding water molecules goes beyond the first hydration shell with the hydration number of 6. The Car-Parrinello molecular dynamic simulation shows that only the first hydration sphere can be found, and the hydration number of Na+ is 5.2 and the hydration distance ( r Na-O) is 0.235 nm. All our simulations mentioned in the present paper show an excellent agreement with the diffraction result from X-ray scattering study.

  15. Geomechanical response of permafrost-associated hydrate deposits to depressurization-induced gas production

    Energy Technology Data Exchange (ETDEWEB)

    Rutqvist, J.; Moridis, G.J.; Grover, T.; Collett, T.

    2009-02-01

    In this simulation study, we analyzed the geomechanical response during depressurization production from two known hydrate-bearing permafrost deposits: the Mallik (Northwest Territories, Canada) deposit and Mount Elbert (Alaska, USA) deposit. Gas was produced from these deposits at constant pressure using horizontal wells placed at the top of a hydrate layer (HL), located at a depth of about 900 m at the Mallik and 600 m at the Mount Elbert. The simulation results show that general thermodynamic and geomechanical responses are similar for the two sites, but with substantially higher production and more intensive geomechanical responses at the deeper Mallik deposit. The depressurization-induced dissociation begins at the well bore and then spreads laterally, mainly along the top of the HL. The depressurization results in an increased shear stress within the body of the receding hydrate and causes a vertical compaction of the reservoir. However, its effects are partially mitigated by the relatively stiff permafrost overburden, and compaction of the HL is limited to less than 0.4%. The increased shear stress may lead to shear failure in the hydrate-free zone bounded by the HL overburden and the downward-receding upper dissociation interface. This zone undergoes complete hydrate dissociation, and the cohesive strength of the sediment is low. We determined that the likelihood of shear failure depends on the initial stress state as well as on the geomechanical properties of the reservoir. The Poisson's ratio of the hydrate-bearing formation is a particularly important parameter that determines whether the evolution of the reservoir stresses will increase or decrease the likelihood of shear failure.

  16. Status of Wheeler Reservoir

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    This is one in a series of status reports prepared by the Tennessee Valley Authority (TVA) for those interested in the conditions of TVA reservoirs. This overview of Wheeler Reservoir summarizes reservoir purposes and operation, reservoir and watershed characteristics, reservoir uses and use impairments, and water quality and aquatic biological conditions. The information presented here is from the most recent reports, publications, and original data available. If no recent data were available, historical data were summarized. If data were completely lacking, environmental professionals with special knowledge of the resource were interviewed. 12 refs., 2 figs.

  17. Protons in hydrated protein powders

    International Nuclear Information System (INIS)

    Careri, G.; Bruni, F.; Consolini, G.

    1995-01-01

    Previous work from this laboratory has shown that hydrated lysozyme powders exhibit a dielectric behaviour, due to proton conductivity, explainable within the frame of percolation theory. Long range proton displacement appears only above the critical hydration for percolation, when the 2-dimensional motion takes place on fluctuating clusters of hydrogen-bonded water molecules adsorbed on the protein surface. The emergence of biological function, enzyme catalysis, was found to coincide with the critical hydration for percolation. More recently, we have evaluated the protonic conductivity of hydrated lysozyme powders, from room down to liquid N 2 temperature. In the high temperature limit a classical isotopic effect can be detected, and the conductivity follows the familiar Arrhenius law for thermally activated hopping. In the low temperature region the conductivity shows a temperature dependence in agreement with prediction by the theory of dissipative quantum tunneling. Below room temperature the static dielectric constant, and the dielectric relaxation time for charge transport showed an increase likely to be identified with the formation of a polaronic-solitonic species as predicted by the theory of proton transport in water chains, a species which displays a larger effective mass and a larger dipole moment that the usual hydrated protonic defects. The purpose of this paper is twofold. In the first section we present a tutorial report of some previous experimental results on proton displacement in slightly hydrated biological systems at room temperature, to show that in these systems the emergence of biological systems at room temperature, to show that in these systems the emergence of biological function coincides with the onset of percolative pathways in the water molecules network adsorbed on the surface of biomolecules. In the second section, we report on preliminary data on the dielectric relaxation of hydrated lysozyme below room temperature, to suggest

  18. Thermoresponsive Microcarriers for Smart Release of Hydrate Inhibitors under Shear Flow.

    Science.gov (United States)

    Lee, Sang Seok; Park, Juwoon; Seo, Yutaek; Kim, Shin-Hyun

    2017-05-24

    The hydrate formation in subsea pipelines can cause oil and gas well blowout. To avoid disasters, various chemical inhibitors have been developed to prevent or delay the hydrate formation and growth. Nevertheless, direct injection of the inhibitors results in environmental contamination and cross-suppression of inhibition performance in the presence of other inhibitors against corrosion and/or formation of scale, paraffin, and asphaltene. Here, we suggest a new class of microcarriers that encapsulate hydrate inhibitors at high concentration and release them on demand without active external triggering. The key to the success in microcarrier design lies in the temperature dependence of polymer brittleness. The microcarriers are microfluidically created to have an inhibitor-laden water core and polymer shell by employing water-in-oil-in-water (W/O/W) double-emulsion drops as a template. As the polymeric shell becomes more brittle at a lower temperature, there is an optimum range of shell thickness that renders the shell unstable at temperature responsible for hydrate formation under a constant shear flow. We precisely control the shell thickness relative to the radius by microfluidics and figure out the optimum range. The microcarriers with the optimum shell thickness are selectively ruptured by shear flow only at hydrate formation temperature and release the hydrate inhibitors. We prove that the released inhibitors effectively retard the hydrate formation without reduction of their performance. The microcarriers that do not experience the hydration formation temperature retain the inhibitors, which can be easily separated from ruptured ones for recycling by exploiting the density difference. Therefore, the use of microcarriers potentially minimizes the environmental damages.

  19. Quantitative degassing of gas hydrate-bearing pressure cores from Green Canyon 955, Gulf of Mexico

    Science.gov (United States)

    Phillips, S. C.; Holland, M. E.; Flemings, P. B.; Schultheiss, P. J.; Waite, W. F.; Petrou, E. G.; Jang, J.; Polito, P. J.; O'Connell, J.; Dong, T.; Meazell, K.

    2017-12-01

    We present results from 20 quantitative degassing experiments of pressure-core sections collected during Expedition UT-GOM2-1 from Green Canyon 955 in the northern Gulf of Mexico. These experiments highlight an average pore-space methane hydrate saturation, Sh, of 59% (min: 12%; max 87%) in sediments between 413 and 440 mbsf in 2032 m water depth. There is a strong lithofacies control of hydrate saturation within the reservoir, with a high saturation sandy silt facies (Sh of 65 to 87%) interbedded with a low saturation clayey silt facies (Sh of 12 to 30%). Bedding occurs on the scale of tens of centimeters. Outside of the main hydrate reservoir, methane hydrate occurs in low saturations (Sh of 0.8 to 3%). Hydrate saturations exhibit a strong correlation (R2=0.89) with the average P-wave velocity measured through the degassed sections. These preliminary hydrate saturations were calculated assuming a porosity of 40% with core filling the full internal diameter of the core liner. Gas recovered during these experiments is composed of almost entirely methane, with an average of 94 ppm ethane and detectable, but not quantifiable, propane. Degassed pressure cores were depressurized through a manifold by the stepwise release of fluid, and the volumes of produced gas and water were monitored. The core's hydrostatic pressure was measured and recorded continuously at the manifold. Pressure and temperature were also measured by data storage tags within the sample chambers. Two slow, multi-day degassing experiments were performed to estimate the in situ salinity within core sections. Based on temperature and pressure observations at the point of the initial pressure rebound due to hydrate dissociation, we estimate the salinity within these samples to be between 33 and 42 g kg-1.

  20. Clinker mineral hydration at reduced relative humidities

    DEFF Research Database (Denmark)

    Jensen, Ole Mejlhede; Hansen, Per Freiesleben; Lachowski, Eric E.

    1999-01-01

    Vapour phase hydration of purl cement clinker minerals at reduced relative humidities is described. This is relevant to modern high performance concrete that may self-desiccate during hydration and is also relevant to the quality of the cement during storage. Both the oretical considerations...... and experimental data are presented showing that C(3)A can hydrate at lower humidities than either C3S or C2S. It is suggested that the initiation of hydration during exposure to water vapour is nucleation controlled. When C(3)A hydrates at low humidity, the characteristic hydration product is C(3)AH(6...

  1. Is Obsidian Hydration Dating Affected by Relative Humidity?

    Science.gov (United States)

    Friedman, I.; Trembour, F.W.; Smith, G.I.; Smith, F.L.

    1994-01-01

    Experiments carried out under temperatures and relative humidities that approximate ambient conditions show that the rate of hydration of obsidian is a function of the relative humidity, as well as of previously established variables of temperature and obsidian chemical composition. Measurements of the relative humidity of soil at 25 sites and at depths of between 0.01 and 2 m below ground show that in most soil environments, at depths below about 0.25 m, the relative humidity is constant at 100%. We have found that the thickness of the hydrated layer developed on obsidian outcrops exposed to the sun and to relative humidities of 30-90% is similar to that formed on other portions of the outcrop that were shielded from the sun and exposed to a relative humidity of approximately 100%. Surface samples of obsidian exposed to solar heating should hydrate more rapidly than samples buried in the ground. However, the effect of the lower mean relative humidity experiences by surface samples tends to compensate for the elevated temperature, which may explain why obsidian hydration ages of surface samples usually approximate those derived from buried samples.

  2. Occurrences of intrapermafrost gas hydrates and shallow gas in the Mackenzie Delta area, N.W.T., Canada

    International Nuclear Information System (INIS)

    Wright, J.F.; Dallimore, S.R.; Nixon, F.M.

    2007-01-01

    The thickness of permafrost in the Mackenzie Delta area has been influenced by ground surface temperature history during the past several million years. Important considerations include periods of glacial ice cover, duration of post-glacial terrestrial exposure, and periods of marine incursions. Permafrost conditions vary considerably in the region. Some areas with less than 50 m of permafrost lie in close proximity to terrain characterized by more than 700 m of permafrost. Assuming normal geopressure conditions, stable Structure 1 methane hydrate can exist in locations where permafrost is greater than 250 m in thickness. As such, conditions supporting the occurrence of intrapermafrost gas hydrate are widespread throughout much of the coastal and offshore areas of the Beaufort Sea. Current research issues include the sensitivity of intrapermafrost gas hydrates to climate warming, and their potential as a geohazard for exploration drilling and hydrocarbon production. This presentation reviewed the geologic factors that influence the occurrence and stability of intrapermafrost and sub-permafrost gas hydrates. The presence of shallow free gas within the gas hydrate pressure-temperature stability field was also discussed. Core samples from a research well at the Taglu Field has shown evidence for the occurrence of intrapermafrost gas hydrate. Data from constrained laboratory experiments have also documented the unique behavior of gas hydrate within sediment-gas hydrate-liquid water/ice systems

  3. Onset and stability of gas hydrates under permafrost in an environment of surface climatic change : past and future

    International Nuclear Information System (INIS)

    Majorowicz, J.A.; Osadetz, K.; Safanda, J.

    2008-01-01

    This paper presented a model designed to simulate permafrost and gas hydrate formation in a changing surface temperature environment in the Beaufort-Mackenzie Basin (BMB). The numerical model simulated surface forcing due to general cooling trends that began in the late Miocene era. This study modelled the onset of permafrost formation and subsequent gas hydrate formation in the changing surface temperature environment for the BMB. Paleoclimatic data were used. The 1-D model was constrained by deep heat flow from well bottom hole temperatures; conductivity; permafrost thickness; and the thickness of the gas hydrates. The model used latent heat effects for the ice-bearing permafrost and hydrate intervals. Surface temperatures for glacial and interglacial histories for the last 14 million years were considered. The model also used a detailed Holocene temperature history as well as a scenario in which atmospheric carbon dioxide (CO 2 ) levels were twice as high as current levels. Two scenarios were considered: (1) the formation of gas hydrates from gas entrapped under geological seals; and (2) the formation of gas hydrates from gas located in free pore spaces simultaneously with permafrost formation. Results of the study showed that gas hydrates may have formed at a depth of 0.9 km only 1 million years ago. Results of the other modelling scenarios suggested that the hydrates formed 6 million years ago, when temperature changes caused the gas hydrate layer to expand both downward and upward. Detailed models of more recent glacial and interglacial histories showed that the gas hydrate zones will persist under the thick body of the BMB permafrost through current interglacial warming as well as in scenarios where atmospheric CO 2 is doubled. 28 refs., 13 figs

  4. Gas hydrates forming and decomposition conditions analysis

    Directory of Open Access Journals (Sweden)

    А. М. Павленко

    2017-07-01

    Full Text Available The concept of gas hydrates has been defined; their brief description has been given; factors that affect the formation and decomposition of the hydrates have been reported; their distribution, structure and thermodynamic conditions determining the gas hydrates formation disposition in gas pipelines have been considered. Advantages and disadvantages of the known methods for removing gas hydrate plugs in the pipeline have been analyzed, the necessity of their further studies has been proved. In addition to the negative impact on the process of gas extraction, the hydrates properties make it possible to outline the following possible fields of their industrial use: obtaining ultrahigh pressures in confined spaces at the hydrate decomposition; separating hydrocarbon mixtures by successive transfer of individual components through the hydrate given the mode; obtaining cold due to heat absorption at the hydrate decomposition; elimination of the open gas fountain by means of hydrate plugs in the bore hole of the gushing gasser; seawater desalination, based on the hydrate ability to only bind water molecules into the solid state; wastewater purification; gas storage in the hydrate state; dispersion of high temperature fog and clouds by means of hydrates; water-hydrates emulsion injection into the productive strata to raise the oil recovery factor; obtaining cold in the gas processing to cool the gas, etc.

  5. Joint Measurements Of Acoustic And Mechanical Properties For Methane Hydrate-Bearing Unconsolidated Sediments Synthesized In Laboratory

    Science.gov (United States)

    Yang, Z.; He, T.

    2017-12-01

    To more accurately explain geophysical exploration data of natural gas hydrate reservoir and to better assess the formation stability for geological or engineering hazards, it is important to comprehensively understand the geophysical and mechanical properties of hydrate-bearing unconsolidated marine sediments, which are significantly different from sea-water saturated ones. Compared to hard-to-control in-situ measurement, laboratory methods are important and feasible to investigate the parameter effects. With the new designed experimental apparatus, we measured ultrasonic velocity, resistivity and stress-strain relation of methane hydrate-bearing unconsolidated sediments. The experimental mineral mixture is prepared as the composition of sample HY-3 of core SH-7 from Shenhu area, South China Sea. It composed of 0.4 wt. % kaolinite, 23.5 wt. % silt (4 - 63 μm), 32.1 wt. % fine sand (63 - 250 μm), 29.2 wt. % medium sand (250 - 500 μm) and 14.8 wt. % coarse sand (500 - 2000 μm). The pure methane enters into the brine (NaCl salinity of 3.5%) saturated sample all around to synthesis methane hydrate. The methane hydrate saturation was calculated by methane consumption amount, which was in turn calculated by gas state equation using the measured methane pressure drop in high pressure reactor. The ultrasonic velocities and resistivity were measured frequently during methane hydrate saturation increasing to examine the velocity varying pattern, especially for S-wave velocities, which may reflect different hydrate occurrence states in sediment pores: load-bearing or not. The stress - strain curves of methane hydrate - bearing sediments showed typical elastic - plastic characteristics and were used to obtain Young's modulus, Poisson's ratio, failure strength and other mechanical parameters. With these results, we can know better about the hydrate reservoir at Shenhu area.

  6. Overview of pressure drawdown production test results for the Japex/JNOC/GSC Mallik 5L-38 gas hydrate research well

    Energy Technology Data Exchange (ETDEWEB)

    Hancock, S.; Carle, D. [APA Petroleum Engineering Ltd., Calgary, AB (Canada); Dallimore, S. [Geological Survey of Canada, Sidney, BC (Canada); Collett, T. [United States Geological Survey, Denver, CO (United States); Satoh, T. [Japan Petroleum Exploration Co. Ltd., Tokyo (Japan); Inoue, T. [Japan National Oil Corp., Chiba (Japan)

    2004-07-01

    Schlumberger's Modular Dynamic Tester (MDT) cased hole wireline tool was used during a pressure drawdown production test at the Mallik 5L-38 well to successfully test 3 separate hydrate intervals as well as free gas and water zones. The MDT test was initially performed to reduce reservoir pressure below the hydrate stability point, and to shut-in and observe the pressure build-up. It was assumed that the rate of gas production would be too small to measure, so the rate of hydrate dissociation would have to be inferred from changing pressure versus time data. Two important phenomena were observed during the hydrate tests: (1) free gas was produced on a steady state basis following the initial clean-up flow of water, and (2) the pressure response upon shut-in displayed porous media effects and indicated both flow contribution and pressure effects beyond the surface area of the hydrate open to the wellbore. In response to these observations, the MDT test procedures for the hydrate intervals were changed to include multiple flow and build-up periods, as well as injection and pressure fall-off periods. The factors that should be considered in interpreting the pressure transient data obtained during the MDT tests of the hydrate intervals include wellbore and perforation geometry with respect to the pressure affected area in the reservoir; radial and time dependent hydrate saturation changes which result in dynamic multiphase fluid flow, changing relative permeability, and changing system compressibility; the addition of free gas during the shut-in periods from continued hydrate dissociation; and the changing presence and character of boundaries due either to localized fractures or the limit of the hydrate dissociation front. Since analytical pressure transient analysis software cannot incorporate such dynamic reservoir parameters, conventional analytical techniques were used to evaluate the test data. 1 fig.

  7. Preliminary report on the commercial viability of gas production from natural gas hydrates

    Science.gov (United States)

    Walsh, M.R.; Hancock, S.H.; Wilson, S.J.; Patil, S.L.; Moridis, G.J.; Boswell, R.; Collett, T.S.; Koh, C.A.; Sloan, E.D.

    2009-01-01

    Economic studies on simulated gas hydrate reservoirs have been compiled to estimate the price of natural gas that may lead to economically viable production from the most promising gas hydrate accumulations. As a first estimate, $CDN2005 12/Mscf is the lowest gas price that would allow economically viable production from gas hydrates in the absence of associated free gas, while an underlying gas deposit will reduce the viability price estimate to $CDN2005 7.50/Mscf. Results from a recent analysis of the simulated production of natural gas from marine hydrate deposits are also considered in this report; on an IROR basis, it is $US2008 3.50-4.00/Mscf more expensive to produce marine hydrates than conventional marine gas assuming the existence of sufficiently large marine hydrate accumulations. While these prices represent the best available estimates, the economic evaluation of a specific project is highly dependent on the producibility of the target zone, the amount of gas in place, the associated geologic and depositional environment, existing pipeline infrastructure, and local tariffs and taxes. ?? 2009 Elsevier B.V.

  8. Rates and mechanisms of conversion of ice nanocrystals to hydrates of HCl and HBr: acid diffusion in the ionic hydrates.

    Science.gov (United States)

    Devlin, J Paul; Gulluru, Dheeraj B; Buch, Victoria

    2005-03-03

    This FTIR study focuses on solid-state chemistry associated with formation and interconversion of the ionic HX (X = Cl, Br) hydrates. Kinetic data are reported for conversions of ice nanocrystal arrays exposed to the saturation pressure of the acids in the 110 approximately 125 K range. The product is amorphous acid dihydrate in the case of HBr, and amorphous monohydrate for HCl. The rate-determining step is identified as HX diffusion through the hydrate product crust toward the interfacial reaction zone, rather than diffusion through ice, as commonly believed. Slowing of the conversion process is thus observed with increasing thickness of the crust. The diffusion coefficient (D(e)) and activation energy values for HX diffusion through the hydrates were evaluated with the help of the shrinking-core model. Hydrate crystallization occurs as a separate step, upon heating above 130 K. Subsequently, rates of reversible transitions between crystal di- and monohydrates were observed upon exposure to acid vapor and acid evacuation. In conversion from di- to monohydrate, the rate slows after fast formation of several layers; subsequently, diffusion through the product crust appears to be the rate-controlling step. The activation energy for HBr diffusion through crystal dihydrate is found to be significantly higher than that for the amorphous analogue. Conjecture is offered for a molecular mechanism of HX transport through the crystal hydrate, based on (i) spectroscopic/computational evidence for the presence of molecular HX bonded to X(-) in each of the ionic hydrate phases and (ii) the relative E(a) values found for HBr and HCl diffusion. Monte Carlo modeling suggests acid transport to the reaction zone along boundaries between "nanocrystallites" generated by multiple hydrate nucleation events at the particle surfaces. The reverse conversion, of crystalline monohydrate particles to the dihydrate phase, as well as dihydrate to trihydrate, displays nearly constant rate

  9. Sedimentological Properties of Natural Gas Hydrates-Bearing Sands in the Nankai Trough and Mallik Areas

    Science.gov (United States)

    Uchida, T.; Tsuji, T.; Waseda, A.

    2009-12-01

    The Nankai Trough parallels the Japanese Island, where extensive BSRs have been interpreted from seismic reflection records. High resolution seismic surveys have definitely indicated gas hydrate distributions, and drilling the MITI Nankai Trough wells in 2000 and the METI Tokai-oki to Kumano-nada wells in 2004 have revealed subsurface gas hydrate in the eastern part of Nankai Trough. In 1998 and 2002 Mallik wells were drilled at Mackenzie Delta in the Canadian Arctic that also clarified the characteristics of gas hydrate-dominant sandy layers at depths from 890 to 1110 m beneath the permafrost zone. During the field operations, the LWD and wire-line well log data were continuously obtained and plenty of gas hydrate-bearing sand cores were recovered. Subsequence sedimentological and geochemical analyses performed on those core samples revealed the crucial geologic controls on the formation and preservation of natural gas hydrate in sediments. Pore-space gas hydrates reside in sandy sediments mostly filling intergranular porosity. Pore waters chloride anomalies, core temperature depression and core observations on visible gas hydrates confirm the presence of pore-space gas hydrates within moderate to thick sandy layers, typically 10 cm to a meter thick. Sediment porosities and pore-size distributions were obtained by mercury porosimetry, which indicate that porosities of gas hydrate-bearing sandy strata are approximately 45 %. According to grain size distribution curves, gas hydrate is dominant in fine- to very fine-grained sandy strata. Gas hydrate saturations are typically up to 80 % in pore volume throughout most of the hydrate-dominant sandy layers, which are estimated by well log analyses as well as pore water chloride anomalies. It is necessary for investigating subsurface fluid flow behaviors to evaluate both porosity and permeability of gas hydrate-bearing sandy sediments, and the measurements of water permeability for them indicated that highly saturated

  10. Evaluation of superpave mixtures containing hydrated lime.

    Science.gov (United States)

    2013-07-01

    The use of hydrated lime in Hot-Mix Asphalt (HMA) mixtures can reduce permanent deformation, long-term aging, and moisture : susceptibility of mixtures. In addition, hydrated lime increases the stiffness and fatigue resistance of mixtures. This study...

  11. Novel understanding of calcium silicate hydrate from dilute hydration

    KAUST Repository

    Zhang, Lina

    2017-05-13

    The perspective of calcium silicate hydrate (C-S-H) is still confronting various debates due to its intrinsic complicated structure and properties after decades of studies. In this study, hydration at dilute suspension of w/s equaling to 10 was conducted for tricalcium silicate (C3S) to interpret long-term hydration process and investigate the formation, structure and properties of C-S-H. Based on results from XRD, IR, SEM, NMR and so forth, loose and dense clusters of C-S-H with analogous C/S ratio were obtained along with the corresponding chemical formulae proposed as Ca5Si4O13∙6.2H2O. Crystalline structure inside C-S-H was observed by TEM, which was allocated at the foil-like proportion as well as the edge of wrinkles of the product. The long-term hydration process of C3S in dilute suspension could be sketchily described as migration of calcium hydroxide and in-situ growth of C-S-H with equilibrium silicon in aqueous solution relatively constant and calcium varied.

  12. Evaluation of influence of proteoglycans on hydration of articular cartilage with the use of ultrasound

    Directory of Open Access Journals (Sweden)

    Yi-yi YANG

    2015-04-01

    Full Text Available Objective To monitor the changes in hydration behaviour of articular cartilage induced by degradation of proteoglycans, and to explore the effect of proteoglycans on hydration behaviour of articular cartilage by using high-frequency ultrasound. Methods Twelve porcine patellae with smooth cartilage surface were prepared and equally divided into two groups: normal group without any enzyme treatment, and trypsin group they were treated with 0.25% trypsin for 8h to digest proteoglycan in the cartilage. The hydration behaviour of the cartilage tissue was scanned by high-frequency ultrasound system with a central frequency of 25MHz. Parameters including cartilage hydration strain and cartilage thickness were measured. The histopathological changes in the articular cartilage were observed under a light microscope. Results It took approximately 20min to reach equilibrium during the hydration process in the normal cartilages, while proteoglycan-degraded cartilage took only about 5min to achieve equilibrium. The equilibrium strain of normal cartilage was 3.5%±0.5%. The degradation of proteoglycans induced a significant decrease in equilibrium strain (1.8%±0.2%, P0.05. Conclusion Proteoglycans play an important role in hydration behaviour of articular cartilage. The degradation of proteoglycans could induce degeneration of cartilage structure and decrease in hydration behaviour after dehydration. DOI: 10.11855/j.issn.0577-7402.2015.03.03

  13. Delineation, Characterization and Assessment of Gas-hydrates: Examples from Indian Offshore

    Science.gov (United States)

    Sain, K.

    2017-12-01

    Successful test productions in McKenzie delta, Alaska, Nankai Trough and more recently in South China Sea have provided great hopes for production of gas-hydrates in near future, and boosted national programs of many countries including India. It has been imperative to map the prospective zones of gas-hydrates and evaluate their resource potential. Hence, we have adopted a systematic strategy for the delineation, characterization and quantification of gas-hydrates based on seismic traveltime tomography, full-waveform inversion, impedance inversion, attributes computation and rock-physical modeling. The bathymetry, seafloor temperature, total organic carbon content, sediment-thickness, rate of sedimentation, geothermal gradient imply that shallow sediments of Indian deep water are good hosts for occurrences of gas-hydrates. From the analysis of multi-channel seismic (MCS) data, we have identified the Krishna-Godavari (KG), Mahanadi and Andaman basins as prospective for gas-hydrates, and their presence has been validated by drilling and coring of Indian Expeditions-01 and -02. The MCS data also shows BSR-like features in the Cauvery, Kerala-Konkan and Saurashtra basins indicating that gas-hydrates cannot be ruled out from these basins also. We shall present several approaches that have been applied to field seismic and well-log data for the detection, characterization and quantification of gas-hydrates along the Indian margin.

  14. Freshwater lake to salt-water sea causing widespread hydrate dissociation in the Black Sea.

    Science.gov (United States)

    Riboulot, Vincent; Ker, Stephan; Sultan, Nabil; Thomas, Yannick; Marsset, Bruno; Scalabrin, Carla; Ruffine, Livio; Boulart, Cédric; Ion, Gabriel

    2018-01-09

    Gas hydrates, a solid established by water and gas molecules, are widespread along the continental margins of the world. Their dynamics have mainly been regarded through the lens of temperature-pressure conditions. A fluctuation in one of these parameters may cause destabilization of gas hydrate-bearing sediments below the seafloor with implications in ocean acidification and eventually in global warming. Here we show throughout an example of the Black Sea, the world's most isolated sea, evidence that extensive gas hydrate dissociation may occur in the future due to recent salinity changes of the sea water. Recent and forthcoming salt diffusion within the sediment will destabilize gas hydrates by reducing the extension and thickness of their thermodynamic stability zone in a region covering at least 2800 square kilometers which focus seepages at the observed sites. We suspect this process to occur in other world regions (e.g., Caspian Sea, Sea of Marmara).

  15. Evaluation of hydration indexes in kale leaves

    OpenAIRE

    Calbo, Adonai G.; Ferreira, Marcos D.

    2011-01-01

    Hydration indexes are practical variables for quantifying plant water stress and can be useful for agronomic purposes. Three adapted hydration indexes based on relative water content, volumetric hydration, and leaf turgor pressure were evaluated in kale (Brassica oleracea var. acephala) leaf segments. Relative water content and volumetric hydration were measured in leaf segments after a water infiltration procedure with the aim of filling its large intercellular volumes (@18%v/v). The infiltr...

  16. Hydration modeling of calcium sulphates

    NARCIS (Netherlands)

    de Korte, A.C.J.; Brouwers, H.J.H.; Al-Mattarneh, Hashem; Mustapha, Kamal N.; Nuruddin, Muhd Fadhil

    2008-01-01

    The CEMHYD3D model has been extended at the University of Twente in the last ten years [1,2]. At present the cement hydration model is extended for the use of gypsum. Although gypsum was present in the model already, the model was not suitable for high contents of gypsum and did not include the

  17. Is Br2 hydration hydrophobic?

    Science.gov (United States)

    Alcaraz-Torres, A; Gamboa-Suárez, A; Bernal-Uruchurtu, M I

    2017-02-28

    The spectroscopic properties of bromine in aqueous systems suggest it can behave as either hydrophilic or hydrophobic solute. In small water clusters, the halogen bond and the hydrogen-halogen interaction are responsible for its specific way of binding. In water hydrates, it is efficiently hosted by two different cages forming the crystal structure and it has been frequently assumed that there is little or no interaction between the guest and the host. Bromine in liquid solution poses a challenging question due to its non-negligible solubility and the large blue shift measured in its absorption spectra. Using a refined semi-empirical force field, PM3-PIF, we performed a Born-Oppenheimer molecular dynamics study of bromine in liquid water. Here we present a detailed study in which we retrieved the most representative hydration structures in terms of the most frequent positions around bromine and the most common water orientations. Albeit being an approximate description of the total hydration phenomenon, it captures the contribution of the leading molecular interactions in form of the recurrent structures. Our findings confirm that the spectroscopic signature is mainly caused by the closest neighbors. The dynamics of the whole first hydration shell strongly suggests that the external molecules in that structure effectively isolate the bulk from the presence of bromine. The solvation structure fluctuates from a hydrophilic to a hydrophobic-like environment along the studied trajectory.

  18. Determining gas hydrate distribution in sands using integrated analysis of well log and seismic data in the Terrebonne Basin, Gulf of Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Hillman, Jess; Cook, Ann; Daigle, Hugh; Nole, Michael; Malinverno, Alberto

    2016-09-30

    The Terrebonne Basin is a salt bounded mini-basin in the northeast section of the Walker Ridge protraction area in the Gulf of Mexico, and the main site for an upcoming gas-hydrate focused International Ocean Discovery Program (IODP) cruise. The basin is infilled by an increasingly mud rich sedimentary sequence with several 5-15 meter gas-hydrate filled sand units of Miocene to Pliocene age overlying the up-domed salt. These gas-hydrate filled sand units can be identified in logging while drilling data from two existing wells in the Terrebonne Basin, drilled in 2009 by the Gas Hydrate Joint Industry Project (JIP) Leg 2. The sand units are cross cut by a distinct bottom-simulating reflector (BSR), and are clearly characterized by a polarity reversal in the sand units. The polarity reversal is caused by a positive gas-hydrate filled sand within the stability zone changing to negative gas-bearing sand. Using well data and calculated synthetic seismogram well ties we are able to identify several additional 1-4 meter gas-hydrate and water-saturated sand units associated with thick (100-200 m-thick), fine grained, hydrate bearing fractured units in the upper sedimentary sequence on the seismic data. Following on previous work, we propose that microbial generation of methane occurring within the fine-grained, fractured units acts as a source for gas hydrate formation in the thin sands. In contrast, it has been proposed that the gas hydrate in the 5-15 m-thick sands first discovered by the JIP was originates from a deeper thermogenic source. Through correlating hydrate occurrence in sands from well data, to amplitudes derived from the seismic data, we can estimate possible distribution of hydrate across the basin. Overall, we find the Terrebonne basin to be a complex gas hydrate system with multiple mechanisms of methane generation and migration.

  19. Borehole Tool for the Comprehensive Characterization of Hydrate-bearing Sediments

    KAUST Repository

    Dai, Sheng

    2018-02-01

    Reservoir characterization and simulation require reliable parameters to anticipate hydrate deposits responses and production rates. The acquisition of the required fundamental properties currently relies on wireline logging, pressure core testing, and/or laboratory ob-servations of synthesized specimens, which are challenged by testing capabilities and in-nate sampling disturbances. The project reviews hydrate-bearing sediments, properties, and inherent sampling effects, albeit lessen with the developments in pressure core technology, in order to develop robust correlations with index parameters. The resulting information is incorporated into a tool for optimal field characterization and parameter selection with un-certainty analyses. Ultimately, the project develops a borehole tool for the comprehensive characterization of hydrate-bearing sediments at in situ, with the design recognizing past developments and characterization experience and benefited from the inspiration of nature and sensor miniaturization.

  20. Borehole Tool for the Comprehensive Characterization of Hydrate-bearing Sediments

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Sheng [Georgia Inst. of Technology, Atlanta, GA (United States); Santamarina, J. Carlos [Georgia Inst. of Technology, Atlanta, GA (United States); King Abdullah Univ. of Science and Technology (KAUST), Thuwal (Saudi Arabia)

    2017-12-30

    Reservoir characterization and simulation require reliable parameters to anticipate hydrate deposits responses and production rates. The acquisition of the required fundamental properties currently relies on wireline logging, pressure core testing, and/or laboratory observations of synthesized specimens, which are challenged by testing capabilities and innate sampling disturbances. The project reviews hydrate-bearing sediments, properties, and inherent sampling effects, albeit lessen with the developments in pressure core technology, in order to develop robust correlations with index parameters. The resulting information is incorporated into a tool for optimal field characterization and parameter selection with uncertainty analyses. Ultimately, the project develops a borehole tool for the comprehensive characterization of hydrate-bearing sediments at in situ, with the design recognizing past developments and characterization experience and benefited from the inspiration of nature and sensor miniaturization.

  1. Hydration mechanisms of mineral trioxide aggregate.

    Science.gov (United States)

    Camilleri, J

    2007-06-01

    To report the hydration mechanism of white mineral trioxide aggregate (White MTA, Dentsply, Tulsa Dental Products, Tulsa, OK, USA). The chemical constitution of white MTA was studied by viewing the powder in polished sections under the scanning electron microscope (SEM). The hydration of both white MTA and white Portland cement (PC) was studied by characterizing cement hydrates viewed under the SEM, plotting atomic ratios, performing quantitative energy dispersive analyses with X-ray (EDAX) and by calculation of the amount of anhydrous clinker minerals using the Bogue calculation. Un-hydrated MTA was composed of impure tri-calcium and di-calcium silicate and bismuth oxide. The aluminate phase was scarce. On hydration the white PC produced a dense structure made up of calcium silicate hydrate, calcium hydroxide, monosulphate and ettringite as the main hydration products. The un-reacted cement grain was coated with a layer of hydrated cement. In contrast MTA produced a porous structure on hydration. Levels of ettringite and monosulphate were low. Bismuth oxide was present as un-reacted powder but also incorporated with the calcium silicate hydrate. White MTA was deficient in alumina suggesting that the material was not prepared in a rotary kiln. On hydration this affected the production of ettringite and monosulphate usually formed on hydration of PC. The bismuth affected the hydration mechanism of MTA; it formed part of the structure of C-S-H and also affected the precipitation of calcium hydroxide in the hydrated paste. The microstructure of hydrated MTA would likely be weaker when compared with that of PC.

  2. Transport of reservoir fines

    DEFF Research Database (Denmark)

    Yuan, Hao; Shapiro, Alexander; Stenby, Erling Halfdan

    Modeling transport of reservoir fines is of great importance for evaluating the damage of production wells and infectivity decline. The conventional methodology accounts for neither the formation heterogeneity around the wells nor the reservoir fines’ heterogeneity. We have developed an integral...

  3. SILTATION IN RESERVOIRS

    African Journals Online (AJOL)

    Calls have been made to the government through various media to assist its populace in combating this nagging problem. It was concluded that sediment maximum accumulation is experienced in reservoir during the periods of maximum flow. Keywords: reservoir model, siltation, sediment, catchment, sediment transport. 1.

  4. Dynamic reservoir well interaction

    NARCIS (Netherlands)

    Sturm, W.L.; Belfroid, S.P.C.; Wolfswinkel, O. van; Peters, M.C.A.M.; Verhelst, F.J.P.C.M.

    2004-01-01

    In order to develop smart well control systems for unstable oil wells, realistic modeling of the dynamics of the well is essential. Most dynamic well models use a semi-steady state inflow model to describe the inflow of oil and gas from the reservoir. On the other hand, reservoir models use steady

  5. Reservoir Engineering Management Program

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J.H.; Schwarz, W.J.

    1977-12-14

    The Reservoir Engineering Management Program being conducted at Lawrence Berkeley Laboratory includes two major tasks: 1) the continuation of support to geothermal reservoir engineering related work, started under the NSF-RANN program and transferred to ERDA at the time of its formation; 2) the development and subsequent implementation of a broad plan for support of research in topics related to the exploitation of geothermal reservoirs. This plan is now known as the GREMP plan. Both the NSF-RANN legacies and GREMP are in direct support of the DOE/DGE mission in general and the goals of the Resource and Technology/Resource Exploitation and Assessment Branch in particular. These goals are to determine the magnitude and distribution of geothermal resources and reduce risk in their exploitation through improved understanding of generically different reservoir types. These goals are to be accomplished by: 1) the creation of a large data base about geothermal reservoirs, 2) improved tools and methods for gathering data on geothermal reservoirs, and 3) modeling of reservoirs and utilization options. The NSF legacies are more research and training oriented, and the GREMP is geared primarily to the practical development of the geothermal reservoirs. 2 tabs., 3 figs.

  6. The Comparison Study of gas source between two hydrate expeditions in ShenHu area, SCS

    Science.gov (United States)

    Cong, X. R.

    2016-12-01

    Two gas hydrate expeditions (GMGS 01&03) were conducted in the Pearl River Mouth Basin, SCS, which were organized by Guangzhou Marine Geological Survey in 2007 and 2015, respectively. Compared with the drilling results of "mixed bio-thermogenic gas and generally dominated by biogenic gas" in 2007, hydrocarbon component measurements revealed a higher content of ethane and propane in 2015 drilling, providing direct evidence that deep thermogenic gas was the source for shallow hydrate formation. According to the geochemical analyses of the results obtained from the industrial boreholes in Baiyun sag, the deep hydrocarbon gas obviously leaked from the reservoir as escape caused by Dongsha movement in the late Miocene, as a result thermogenic gas from Wenchang, Enping and Zhuhai hydrocarbon source rocks migrated to late Miocene shallow strata through faults, diapirs and gas chimney vertically migration. In this paper we report the differences in fluid migration channel types and discuss their effect in fluid vertical migration efficiency in the two Shenhu hydrate drilling areas. For the drilling area in 2007,when the limited deep thermogenic gas experienced long distance migration process from bottom to up along inefficient energy channel, the gas composition might have changed and the carbon isotope fractionation might have happened, which were reflected in the results of higher C1/C2 ratios and lighter carbon isotope in gas hydrate bearing sediments. As a result the gas is with more "biogenic gas" features. It means thermogenic gases in the deep to contributed the formation of shallow gas hydrate indirectly in 2007 Shenhu drill area. On another hand, the gases were transported to the shallow sediment layers efficiently, where gas hydrate formed, through faults and fractures from deep hydrocarbon reservoirs, and as the result they experienced less changes in both components and isotopes in 2015 drilling site.

  7. Apparatus investigates geological aspects of gas hydrates

    Science.gov (United States)

    Booth, J.S.; Winters, W.J.; Dillon, William P.

    1999-01-01

    The US Geological Survey (USGS), in response to potential geohazards, energy resource potential, and climate issues associated with marine gas hydrates, has developed a laboratory research system that permits hydrate genesis and dissociation under deep-sea conditions, employing user-selected sediment types and pore fluids.The apparatus, GHASTI (gas hydrate and sediment test laboratory instrument), provides a means to link field studies and theory and serves as a tool to improve gas hydrate recognition and assessment, using remote sensing techniques.GHASTLI's use was proven in an exploration well project led by the Geological Survey of Canada and the Japanese National Oil Corp., collaborating with Japan Petroleum Exploration Co. and the USGS. The site was in the Mackenzie Delta region of the Northwest Territories (Mallik 2L-38 drillsite).From tests on natural methane hydrate-bearing sand recovered at about 1,000 m subsurface, the in situ quantity of hydrate was estimated from acoustic properties, and a substantial increase in shear strength due to the presence of the hydrate was measured.1 2GHASTI can mimic a wide range of geologic settings and processes. Initial goals involve improved recognition and mapping of gas hydrate-bearing sediments, understanding factors that control the occurrence and concentration of gas hydrates, knowledge of hydrate's significance to slope failure and foundation problems, and analysis of gas hydrate's potential use as an energy resource.

  8. Influence of fluorosurfactants on hydrate formation rates

    Energy Technology Data Exchange (ETDEWEB)

    Kim, C.U.; Jeong, K.E.; Chae, H.J.; Jeong, S.Y. [Korea Reasearch Inst. of Chemical Technology, Alternative Chemicals/Fuel Research Center, Yuseong-Gu, Daejon (Korea, Republic of)

    2008-07-01

    Gas hydrates, or clathrates, are ice-like solids that forms when natural gas is in contact with liquid water or ice under high pressure and low temperature. There is significant interest in studying the storage and transportation of gas in the form of hydrates. However, a critical problem impacting the industrial application of gas hydrates for storage and transportation of natural gas is the slow formation rate of natural gas hydrate. Researchers have previously reported on the promotion effect of some additives on gas hydrate formation and hydrate gas content. Fluorosurfactants are significantly superior to nonfluorinated surfactants in wetting action, as well as stability in harsh environments, both thermal and chemical. This paper discussed an experimental investigation into the effects of fluorosurfactants with different ionic types on the formation of methane hydrate. The surfactants used were FSN-100 of DuPont Zonyl as non-ionic surfactant and FC-143 of DuPont as anionic surfactant. The paper discussed the experimental apparatus for methane hydrate formation. It also discussed hydrate formation kinetics and the series of hydrate formation experiments that were conducted in the presence of fluorosurfactants. Last, the paper explored the results of the study. It was concluded that anionic fluorosurfactant of FC-143 had a better promoting effect on methane hydrate formation compared with nonionic surfactant of FSN-100. 8 refs., 2 tabs., 2 figs.

  9. Terahertz Time Domain Spectroscopy for Structure-II Gas Hydrates

    DEFF Research Database (Denmark)

    Takeya, Kei; Zhang, Caihong; Kawayama, Iwao

    2009-01-01

    For the nondestructive inspection of gas hydrates, terahertz (THz) time-domain spectroscopy (TDS) was applied to tetrahydrofuran (THF) hydrate and propane hydrate. The absorption of propane hydrate monotonically increases with frequency, similar to the case of ice, while THF hydrate has a charact......For the nondestructive inspection of gas hydrates, terahertz (THz) time-domain spectroscopy (TDS) was applied to tetrahydrofuran (THF) hydrate and propane hydrate. The absorption of propane hydrate monotonically increases with frequency, similar to the case of ice, while THF hydrate has...

  10. Characterization of gas hydrate distribution using conventional 3D seismic data in the Pearl River Mouth Basin, South China Sea

    Science.gov (United States)

    Wang, Xiujuan; Qiang, Jin; Collett, Timothy S.; Shi, Hesheng; Yang, Shengxiong; Yan, Chengzhi; Li, Yuanping; Wang, Zhenzhen; Chen, Duanxin

    2016-01-01

    A new 3D seismic reflection data volume acquired in 2012 has allowed for the detailed mapping and characterization of gas hydrate distribution in the Pearl River Mouth Basin in the South China Sea. Previous studies of core and logging data showed that gas hydrate occurrence at high concentrations is controlled by the presence of relatively coarse-grained sediment and the upward migration of thermogenic gas from the deeper sediment section into the overlying gas hydrate stability zone (BGHSZ); however, the spatial distribution of the gas hydrate remains poorly defined. We used a constrained sparse spike inversion technique to generate acoustic-impedance images of the hydrate-bearing sedimentary section from the newly acquired 3D seismic data volume. High-amplitude reflections just above the bottom-simulating reflectors (BSRs) were interpreted to be associated with the accumulation of gas hydrate with elevated saturations. Enhanced seismic reflections below the BSRs were interpreted to indicate the presence of free gas. The base of the BGHSZ was established using the occurrence of BSRs. In areas absent of well-developed BSRs, the BGHSZ was calculated from a model using the inverted P-wave velocity and subsurface temperature data. Seismic attributes were also extracted along the BGHSZ that indicate variations reservoir properties and inferred hydrocarbon accumulations at each site. Gas hydrate saturations estimated from the inversion of acoustic impedance of conventional 3D seismic data, along with well-log-derived rock-physics models were also used to estimate gas hydrate saturations. Our analysis determined that the gas hydrate petroleum system varies significantly across the Pearl River Mouth Basin and that variability in sedimentary properties as a product of depositional processes and the upward migration of gas from deeper thermogenic sources control the distribution of gas hydrates in this basin.

  11. Handbook of gas hydrate properties and occurrence

    Energy Technology Data Exchange (ETDEWEB)

    Kuustraa, V.A.; Hammershaimb, E.C.

    1983-12-01

    This handbook provides data on the resource potential of naturally occurring hydrates, the properties that are needed to evaluate their recovery, and their production potential. The first two chapters give data on the naturally occurring hydrate potential by reviewing published resource estimates and the known and inferred occurrences. The third and fourth chapters review the physical and thermodynamic properties of hydrates, respectively. The thermodynamic properties of hydrates that are discussed include dissociation energies and a simplified method to calculate them; phase diagrams for simple and multi-component gases; the thermal conductivity; and the kinetics of hydrate dissociation. The final chapter evaluates the net energy balance of recovering hydrates and shows that a substantial positive energy balance can theoretically be achieved. The Appendices of the Handbook summarize physical and thermodynamic properties of gases, liquids and solids that can be used in designing and evaluating recovery processes of hydrates. 158 references, 67 figures, 47 tables.

  12. Glacial Cycles Influence Marine Methane Hydrate Formation

    Science.gov (United States)

    Malinverno, A.; Cook, A. E.; Daigle, H.; Oryan, B.

    2018-01-01

    Methane hydrates in fine-grained continental slope sediments often occupy isolated depth intervals surrounded by hydrate-free sediments. As they are not connected to deep gas sources, these hydrate deposits have been interpreted as sourced by in situ microbial methane. We investigate here the hypothesis that these isolated hydrate accumulations form preferentially in sediments deposited during Pleistocene glacial lowstands that contain relatively large amounts of labile particulate organic carbon, leading to enhanced microbial methanogenesis. To test this hypothesis, we apply an advection-diffusion-reaction model with a time-dependent organic carbon deposition controlled by glacioeustatic sea level variations. In the model, hydrate forms in sediments with greater organic carbon content deposited during the penultimate glacial cycle ( 120-240 ka). The model predictions match hydrate-bearing intervals detected in three sites drilled on the northern Gulf of Mexico continental slope, supporting the hypothesis of hydrate formation driven by enhanced organic carbon burial during glacial lowstands.

  13. Evidence of mud volcanism rooted in gas hydrate-rich cryosphere linking surface and subsurface for the search for life on Mars

    Science.gov (United States)

    De Toffoli, Barbara; Pozzobon, Riccardo; Mazzarini, Francesco; Massironi, Matteo; Cremonese, Gabriele

    2017-04-01

    We mapped around 6000 mounds in three different portions of the Martian surface on an average area of about 90.000 Km2 for each region. The study areas are located in Hellas basin, Utopia basin and a portion of the Northern Plains lying north of Arabia Terra, between Acidalia and Utopia Planitia. The aim of the study was to understand the nature of the observed features, particularly if they could be interpreted as mud volcanoes or not, and improve our knowledge about the Martian mound fields origin. The analysis of Context Camera (onboard Mars Reconnaissance Orbiter) images showed circular, elliptical and coalescent mounds with central and/or distal pits and flow features such as concentric annular lobes around the source pits and apron-like extensions. We produced DTMs and then high-to-diameter morphometric analysis on two groups of mounds located in Utopia and Hellas basins to enhance the geomorphological observations. We inferred, by means of cluster and fractal analyses, the thickness of the medium cracked by connected fractures and, consequently, the depths of reservoirs that fed the mounds. We found that the fields, which are seated at different latitudes, has been fed, at least partially, by reservoirs located at the base of the gas hydrate stability zone according to Clifford et al., 2010. This evidence produces a meaningful relationship between the clathrates distribution underneath the Martian surface and the occurrence of mound fields on the surface leading to the assumption that the involvement of water, ostensibly as a result of gas hydrate dissociation, plays a key role in the subsurface processes that potentially worked as triggers. These outcomes corroborate the hypothesis that the mapped mounds are actually mud volcanoes and make these structures outstanding targets for astrobiology and habitability studies. In fact, mud volcanoes, extruding material from depths that are still not affordable by our present-day instrumentations, could have sampled

  14. Controls on methane expulsion during melting of natural gas hydrate systems. Topic area 2

    Energy Technology Data Exchange (ETDEWEB)

    Flemings, Peter [Univ. of Texas, Austin, TX (United States)

    2016-01-14

    1.1. Project Goal The project goal is to predict, given characteristic climate-induced temperature change scenarios, the conditions under which gas will be expelled from existing accumulations of gas hydrate into the shallow ocean or directly to the atmosphere. When those conditions are met, the fraction of the gas accumulation that escapes and the rate of escape shall be quantified. The predictions shall be applicable in Arctic regions and in gas hydrate systems at the up dip limit of the stability zone on continental margins. The behavior shall be explored in response to two warming scenarios: longer term change due to sea level rise (e.g. 20 thousand years) and shorter term due to atmospheric warming by anthropogenic forcing (decadal time scale). 1.2. Project Objectives During the first budget period, the objectives are to review and categorize the stability state of existing well-studied hydrate reservoirs, develop conceptual and numerical models of the melting process, and to design and conduct laboratory experiments that dissociate methane hydrate in a model sediment column by systematically controlling the temperature profile along the column. The final objective of the first budget period shall be to validate the models against the experiments. In the second budget period, the objectives are to develop a model of gas flow into sediment in which hydrate is thermodynamically stable, and conduct laboratory experiments of this process to validate the model. The developed models shall be used to quantify the rate and volume of gas that escapes from dissociating hydrate accumulations. In addition, specific scaled simulations characteristic of Arctic regions and regions near the stability limit at continental margins shall be performed. 1.3. Project Background and Rationale The central hypothesis proposed is that hydrate melting (dissociation) due to climate change generates free gas that can, under certain conditions, propagate through the gas hydrate stability

  15. Engineering a segmented dual-reservoir polyurethane intravaginal ring for simultaneous prevention of HIV transmission and unwanted pregnancy.

    Directory of Open Access Journals (Sweden)

    Justin T Clark

    Full Text Available The HIV/AIDS pandemic and its impact on women prompt the investigation of prevention strategies to interrupt sexual transmission of HIV. Long-acting drug delivery systems that simultaneously protect womenfrom sexual transmission of HIV and unwanted pregnancy could be important tools in combating the pandemic. We describe the design, in silico, in vitro and in vivo evaluation of a dual-reservoir intravaginal ring that delivers the HIV-1 reverse transcriptase inhibitor tenofovir and the contraceptive levonorgestrel for 90 days. Two polyether urethanes with two different hard segment volume fractions were used to make coaxial extruded reservoir segments with a 100 µm thick rate controlling membrane and a diameter of 5.5 mm that contain 1.3 wt% levonorgestrel. A new mechanistic diffusion model accurately described the levonorgestrel burst release in early time points and pseudo-steady state behavior at later time points. As previously described, tenofovir was formulated as a glycerol paste and filled into a hydrophilic polyurethane, hollow tube reservoir that was melt-sealed by induction welding. These tenofovir-eluting segments and 2 cm long coaxially extruded levonorgestrel eluting segments were joined by induction welding to form rings that released an average of 7.5 mg tenofovir and 21 µg levonorgestrel per day in vitro for 90 days. Levonorgestrel segments placed intravaginally in rabbits resulted in sustained, dose-dependent levels of levonorgestrel in plasma and cervical tissue for 90 days. Polyurethane caps placed between segments successfully prevented diffusion of levonorgestrel into the tenofovir-releasing segment during storage.Hydrated rings endured between 152 N and 354 N tensile load before failure during uniaxial extension testing. In summary, this system represents a significant advance in vaginal drug delivery technology, and is the first in a new class of long-acting multipurpose prevention drug delivery systems.

  16. Engineering a Segmented Dual-Reservoir Polyurethane Intravaginal Ring for Simultaneous Prevention of HIV Transmission and Unwanted Pregnancy

    Science.gov (United States)

    Clark, Justin T.; Clark, Meredith R.; Shelke, Namdev B.; Johnson, Todd J.; Smith, Eric M.; Andreasen, Andrew K.; Nebeker, Joel S.; Fabian, Judit; Friend, David R.; Kiser, Patrick F.

    2014-01-01

    The HIV/AIDS pandemic and its impact on women prompt the investigation of prevention strategies to interrupt sexual transmission of HIV. Long-acting drug delivery systems that simultaneously protect womenfrom sexual transmission of HIV and unwanted pregnancy could be important tools in combating the pandemic. We describe the design, in silico, in vitro and in vivo evaluation of a dual-reservoir intravaginal ring that delivers the HIV-1 reverse transcriptase inhibitor tenofovir and the contraceptive levonorgestrel for 90 days. Two polyether urethanes with two different hard segment volume fractions were used to make coaxial extruded reservoir segments with a 100 µm thick rate controlling membrane and a diameter of 5.5 mm that contain 1.3 wt% levonorgestrel. A new mechanistic diffusion model accurately described the levonorgestrel burst release in early time points and pseudo-steady state behavior at later time points. As previously described, tenofovir was formulated as a glycerol paste and filled into a hydrophilic polyurethane, hollow tube reservoir that was melt-sealed by induction welding. These tenofovir-eluting segments and 2 cm long coaxially extruded levonorgestrel eluting segments were joined by induction welding to form rings that released an average of 7.5 mg tenofovir and 21 µg levonorgestrel per day in vitro for 90 days. Levonorgestrel segments placed intravaginally in rabbits resulted in sustained, dose-dependent levels of levonorgestrel in plasma and cervical tissue for 90 days. Polyurethane caps placed between segments successfully prevented diffusion of levonorgestrel into the tenofovir-releasing segment during storage.Hydrated rings endured between 152 N and 354 N tensile load before failure during uniaxial extension testing. In summary, this system represents a significant advance in vaginal drug delivery technology, and is the first in a new class of long-acting multipurpose prevention drug delivery systems. PMID:24599325

  17. Relict gas hydrates as possible reason of gas emission from shallow permafrost at the northern part of West Siberia

    Science.gov (United States)

    Chuvilin, Evgeny; Bukhanov, Boris; Tumskoy, Vladimir; Istomin, Vladimir; Tipenko, Gennady

    2017-04-01

    zone) permafrost horizons. The results show that all investigated frozen hydrate-bearing sandy and silty sand samples in the temperature range from -16 °C to -2 °C are characterized by not complete decomposition of pore hydrate at relieving pressure below the equilibrium. It was observed that at typical north Western Siberian permafrost temperature of -6 ° C the safety of pore hydrate in frozen samples can reach 60% at the pressure reducing below the equilibrium. In was found that with increasing temperature and particle size (dispersity) the efficiency of pore hydrate self-preservation is decreased, but even at the temperature of -2 °C there is residual pore methane hydrate content in non-saline sandy samples. All this suggests about high preservation of methane hydrates in frozen sediments at non-equilibrium thermobaric conditions, close to reservoir conditions. Based on the results of mathematical and experimental simulations about the possibility of relic gas hydrates existence on permafrost depth up to 200 m in the northern part of Western Siberia on the less than 200 m due to geological manifestation of the self-preservation effect of gas hydrates. References. 1.Chuvilin EM, Yakushev VS, Perlova EV. Gas and gas hydrates in the permafrost of Bovanenkovo gas field, Yamal Peninsula, West Siberia. // Polarforschung 68: 215-219, 1998. (erschienen 2000). 2.Yakushev V.S., Chuvilin E.M. 2000. Natural gas and hydrate accumulation within permafrost in Russia. Cold Regions Science and Technology. 31: 189-197. These researches are supported by grant RSF №16-17-00051.

  18. Elasticity of methane hydrate phases at high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Beam, Jennifer; Yang, Jing; Liu, Jin [Department of Geological Sciences, Jackson School of Geosciences, The University of Texas at Austin, Austin, Texas 78712 (United States); Liu, Chujie [Laboratory of Seismology and Physics of Earth’s Interior, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026 (China); Lin, Jung-Fu, E-mail: afu@jsg.utexas.edu [Department of Geological Sciences, Jackson School of Geosciences, The University of Texas at Austin, Austin, Texas 78712 (United States); Center for High Pressure Science and Advanced Technology Research (HPSTAR), Shanghai 201203 (China)

    2016-04-21

    Determination of the full elastic constants (c{sub ij}) of methane hydrates (MHs) at extreme pressure-temperature environments is essential to our understanding of the elastic, thermodynamic, and mechanical properties of methane in MH reservoirs on Earth and icy satellites in the solar system. Here, we have investigated the elastic properties of singe-crystal cubic MH-sI, hexagonal MH-II, and orthorhombic MH-III phases at high pressures in a diamond anvil cell. Brillouin light scattering measurements, together with complimentary equation of state (pressure-density) results from X-ray diffraction and methane site occupancies in MH from Raman spectroscopy, were used to derive elastic constants of MH-sI, MH-II, and MH-III phases at high pressures. Analysis of the elastic constants for MH-sI and MH-II showed intriguing similarities and differences between the phases′ compressional wave velocity anisotropy and shear wave velocity anisotropy. Our results show that these high-pressure MH phases can exhibit distinct elastic, thermodynamic, and mechanical properties at relevant environments of their respective natural reservoirs. These results provide new insight into the determination of how much methane exists in MH reservoirs on Earth and on icy satellites elsewhere in the solar system and put constraints on the pressure and temperature conditions of their environment.

  19. Investigation of hydrate formation and transportability in multiphase flow systems

    Science.gov (United States)

    Grasso, Giovanny A.

    cohesion force (3.32 mN/m). These measurements prove the importance of natural surfactants in crude oil for particle dispersion. An experimental methodology was provided to determine the effectiveness of asphaltenes as a dispersant. Even though hydrate deposition was inferred from the flowloop tests, it could not be verified from these measurements. Custom-made experimental set-ups (a recirculation liquid system, a rocking cell and a lab-scale mini-loop) were used to isolate the hydrate deposi- tion investigation. Besides water, mineral oil 70T and King Ranch condensate were used in combination with water for the deposition investigation. One of the most important deliverables of this thesis was the construction of a lab-scale flowloop that provides insight on deposition phenomenon in multiphase flow, representing the only set-up, reported in the literature, suitable for this investigation. The miniloop can handle gas-liquid flow (maximum flow rates of 10 Nm3/m for gas and 22 GPM for liquid) through a 10 ft. long straight section (2 in. standard tubing). The testing section (30 in. long) was designed to observe hydrate deposition on the wall. Three mechanisms of hydrate deposition were identified: film growth, particles adhering and particle bedding. The maximum water conversions were: 27.5 ml in the rocking cell, 2400 ml in the miniloop with 100 % WC and 250 ml in the miniloop for dispersed water in mineral oil 70T. The measured DP across to the testing section ranged from 0 to 8 in. H2O. Deposits were obtained for different flow regimes, including 100 % LL, stratified, stratified- wavy and slug flow. The maximum deposit thickness was 1.5 in., obtained in the gas flowing section. When deposits form from particle cohesion, they were easy to slough. From all the experimental worked in this thesis, hydrates accumulated depending on the degrees of subcooling of the bulk fluid, film growth (between 3 to 5 F), deposition from a combination of film growth and particle cohesion

  20. Microbeam recoil detection for hydration of minerals studies

    Energy Technology Data Exchange (ETDEWEB)

    Sie, S.H.; Suter, G.F. [CSIRO, North Ryde, NSW (Australia). Exploration and Mining Div.; Chekhmir, A.; Green, T.H. [Macquarie Univ., North Ryde, NSW (Australia)

    1993-12-31

    The glancing angle geometry is chosen to enable application of the elastic recoil detection microanalysis on thick geological samples, for hydrogen content determination. Simultaneous PIXE measurements can be used to eliminate the problem of uncertainties in beam charge collection. The method is applied to determine the hydration characteristics of silicates, produced experimentally at high pressure and temperature simulating the lower crust and upper mantle conditions. Preliminary results show that the technique can be applied readily on a microscopic (<100 {mu}m) scale for determination of H at fraction of atomic percent level. 9 refs., 3 figs.

  1. Sediment management for reservoir

    International Nuclear Information System (INIS)

    Rahman, A.

    2005-01-01

    All natural lakes and reservoirs whether on rivers, tributaries or off channel storages are doomed to be sited up. Pakistan has two major reservoirs of Tarbela and Managla and shallow lake created by Chashma Barrage. Tarbela and Mangla Lakes are losing their capacities ever since first impounding, Tarbela since 1974 and Mangla since 1967. Tarbela Reservoir receives average annual flow of about 62 MAF and sediment deposits of 0.11 MAF whereas Mangla gets about 23 MAF of average annual flows and is losing its storage at the rate of average 34,000 MAF annually. The loss of storage is a great concern and studies for Tarbela were carried out by TAMS and Wallingford to sustain its capacity whereas no study has been done for Mangla as yet except as part of study for Raised Mangla, which is only desk work. Delta of Tarbala reservoir has advanced to about 6.59 miles (Pivot Point) from power intakes. In case of liquefaction of delta by tremor as low as 0.12g peak ground acceleration the power tunnels I, 2 and 3 will be blocked. Minimum Pool of reservoir is being raised so as to check the advance of delta. Mangla delta will follow the trend of Tarbela. Tarbela has vast amount of data as reservoir is surveyed every year, whereas Mangla Reservoir survey was done at five-year interval, which has now been proposed .to be reduced to three-year interval. In addition suspended sediment sampling of inflow streams is being done by Surface Water Hydrology Project of WAPDA as also some bed load sampling. The problem of Chasma Reservoir has also been highlighted, as it is being indiscriminately being filled up and drawdown several times a year without regard to its reaction to this treatment. The Sediment Management of these reservoirs is essential and the paper discusses pros and cons of various alternatives. (author)

  2. Study On Seismic Identification And Distribution Characters Of Marine Gas Hydrate In Okinawa Trough

    Science.gov (United States)

    Fang, Y.; Jin, X.; Li, M.; Tang, Y.

    2003-04-01

    The paper studies the formation processes and distribution of marine gas hydrate, through systematically and thoroughly analyzing the geological setting, gas sources and distribution features of the most marine gas hydrate deposits around the world. Based on study of the geologic features in Okinawa Trough and adjacent area, it is showed that there exist favorable geological conditions for the formation of gas hydrate, and the seismic indicator -BSR has also been identified from multi-channel digit seismic data by re-processing and analyzing. This shows that Okinawa Trough and adjacent sea area may distribute a mass of gas hydrate sedimentary deposit. Then the paper discusses the prospect of the gas hydrate resource in Okinawa Trough and adjacent sea area, based on the calculating of the hydrate stability zone thickness. Main conclusions of the paper can be summed up as follows: Based on the systematically comparative analysis of the marine gas hydrate deposits in different marine gas hydrate accumulate belts, the paper summarizes the different geologic formation processes and characters of the gas hydrate. And the importance of the continuous supplementation of the gas source, the transporting and accumulating of the gaseous fluid during the formation processes of the gas hydrate, and the preservation conditions of the gas hydrate deposit are discussed. It is thought that the Okinawa Trough (especially the west slope of the Trough) has the favorable conditions for gas hydrate through the analysis of its geologic features. The geologic features of Okinawa Trough, such as water depth, low temperature of bottom water, very thick sediments with high organic matter content, a large amount of gas from deep parts induced by the upward of the high temperature mantle flow under the Trough, very developed fracture system, and lots of pore space in the under-compacted sediment induced by the rapid sedimentation-are beneficial to form gas hydrate. This provided the advantaged

  3. Proceedings of the 6. international conference on gas hydrates : ICGH 2008

    International Nuclear Information System (INIS)

    Englezos, P.; Ripmeester, J.; Dallimore, S.R.; Collett, T.S.; Mehta, A.; Paull, C.K.; Sloan, E.D.Jr.; Uchida, T.

    2008-01-01

    This international conference provided a forum to highlight gas hydrate research that is underway at academic institutions as well as government and industrial laboratories around the world. The gas or clathrate hydrate research community includes chemical, petroleum and mechanical engineers, geologists, geophysicists, marine biologists, chemists and physicists. The conference was attended by more than 500 delegates who presented their professional knowledge in all areas of the gas hydrates field, emphasizing new aspects. The topics of discussion included resource delineation, reservoir simulation modeling and production technology. Environmental considerations involving natural gas hydrates and global climate change were also highlighted along with carbon dioxide disposal in aquifers and deep oceans. Issues facing oil and gas operations were also discussed, with reference to flow assurance in pipelines, safety issues, permafrost and marine geohazards. Novel technologies involving hydrogen storage, carbon dioxide capture and sequestration were also highlighted along with basic science and engineering aspects of gas hydrate systems. All 417 presentations from the conference have been catalogued separately for inclusion in this database. refs., tabs., figs

  4. Proceedings of the 6. international conference on gas hydrates : ICGH 2008

    Energy Technology Data Exchange (ETDEWEB)

    Englezos, P. (ed.) [British Columbia Univ., Vancouver, BC (Canada); Ripmeester, J. (ed.) [National Research Council of Canada, Ottawa, ON (Canada); Dallimore, S.R. [Natural Resources Canada, Ottawa, ON (Canada). Geological Survey of Canada; Servio, P. [McGill Univ., Montreal, PQ (Canada). Dept. of Chemical Engineering; Austvik, T. [Statoil, Trondheim (Norway); Collett, T.S. [United States Geological Survey, Denver, CO (United States); Mehta, A. [Shell E and P Asia Pacific, Sarawak (Malaysia); Paull, C.K. [Monterey Bay Aquarium Research Inst., CA (United States); Sloan, E.D.Jr. [Colorado School of Mines, Golden, CO (United States); Uchida, T. [Hokkaido Univ., Sapporo (Japan)] (comps.)

    2008-07-01

    This international conference provided a forum to highlight gas hydrate research that is underway at academic institutions as well as government and industrial laboratories around the world. The gas or clathrate hydrate research community includes chemical, petroleum and mechanical engineers, geologists, geophysicists, marine biologists, chemists and physicists. The conference was attended by more than 500 delegates who presented their professional knowledge in all areas of the gas hydrates field, emphasizing new aspects. The topics of discussion included resource delineation, reservoir simulation modeling and production technology. Environmental considerations involving natural gas hydrates and global climate change were also highlighted along with carbon dioxide disposal in aquifers and deep oceans. Issues facing oil and gas operations were also discussed, with reference to flow assurance in pipelines, safety issues, permafrost and marine geohazards. Novel technologies involving hydrogen storage, carbon dioxide capture and sequestration were also highlighted along with basic science and engineering aspects of gas hydrate systems. All 417 presentations from the conference have been catalogued separately for inclusion in this database. refs., tabs., figs.

  5. A fermented barley and soybean formula enhances skin hydration.

    Science.gov (United States)

    Lee, Sein; Kim, Jong-Eun; Suk, Sujin; Kwon, Oh Wook; Park, Gaeun; Lim, Tae-Gyu; Seo, Sang Gwon; Kim, Jong Rhan; Kim, Dae Eung; Lee, Miyeong; Chung, Dae Kyun; Jeon, Jong Eun; Cho, Dong Woon; Hurh, Byung Serk; Kim, Sun Yeou; Lee, Ki Won

    2015-09-01

    Skin hydration is one of the primary aims of beauty and anti-aging treatments. Barley (Hordeum vulgare) and soybean (Glycine max) are major food crops, but can also be used as ingredients for the maintenance of skin health. We developed a natural product-based skin treatment using a barley and soybean formula (BS) incorporating yeast fermentation, and evaluated its skin hydration effects as a dietary supplement in a clinical study. Participants ingested a placebo- (n = 33) or BS- (3 g/day) containing drink (n = 32) for 8 weeks. A significant increase in hydration in the BS group as compared to the placebo group was observed on the faces of subjects after 4 and 8 weeks, and on the forearm after 4 weeks. Decreases in stratum corneum (SC) thickness were also observed on the face and forearm. BS enhanced hyaluronan (HA) and skin barrier function in vitro and reduced Hyal2 expression in human dermal fibroblasts (HDF). BS also recovered ultraviolet (UV) B-induced downregulation of HA in HaCaT cells. These results suggest that BS has promising potential for development as a health functional food to enhance skin health.

  6. Growth of hydrated gel layers in nuclear waste glasses

    International Nuclear Information System (INIS)

    Sullivan, T.M.; Machiels, A.J.

    1984-01-01

    The hydration kinetics of waste glasses in contact with an aqueous solution has been studied by using three different approaches. Emphasis has been placed on modeling processes in the transition zone defined as the region in which the nature of the glass changes from the original dry glass to an open hydrated structure. The first model relies on concentration-dependent diffusion coefficients to obtain a transition zone in which the ions mobility is extremely low compared to that in the gel layer. In the second model, the transition zone and hydrated layer are treated as distinct phases and it is assumed that ion exchange at their common boundary is the rate-controlling process. The third model treats the transition zone as a thin film of constant thickness and low diffusivity. In the absence of appreciable network dissolution, all three models indicate that growth of the gel layer becomes eventually proportional to the square root of time; however, as long as processes in the transition zone are rate controlling, growth is linearly proportional to time

  7. Determination of Priority Study Areas for Coupling CO2 Storage and CH4 Gas Hydrates Recovery in the Portuguese Offshore Area

    Directory of Open Access Journals (Sweden)

    Luís Bernardes

    2015-09-01

    Full Text Available Gas hydrates in sub-seabed sediments is an unexploited source of energy with estimated reserves larger than those of conventional oil. One of the methods for recovering methane from gas hydrates involves injection of Carbon Dioxide (CO2, causing the dissociation of methane and storing CO2. The occurrence of gas hydrates offshore Portugal is well known associated to mud volcanoes in the Gulf of Cadiz. This article presents a determination of the areas with conditions for the formation of biogenic gas hydrates in Portugal’s mainland geological continental margin and assesses their overlap with CO2 hydrates stability zones defined in previous studies. The gas hydrates stability areas are defined using a transfer function recently published by other authors and takes into account the sedimentation rate, the particulate organic carbon content and the thickness of the gas hydrate stability zone. An equilibrium equation for gas hydrates, function of temperature and pressure, was adjusted using non-linear regression and the maximum stability zone thickness was found to be 798 m. The gas hydrates inventory was conducted in a Geographic Information System (GIS environment and a full compaction scenario was adopted, with localized vertical flow assumed in the accrecionary wedge where mud volcanoes occur. Four areas where temperature and pressure conditions may exist for formation of gas hydrates were defined at an average of 60 km from Portugal’s mainland coastline. Two of those areas coincide with CO2 hydrates stability areas previously defined and should be the subject of further research to evaluate the occurrence of gas hydrate and the possibility of its recovery coupled with CO2 storage in sub-seabed sediments.

  8. Lithological control on gas hydrate saturation as revealed by signal classification of NMR logging data

    Science.gov (United States)

    Bauer, Klaus; Kulenkampff, Johannes; Henninges, Jan; Spangenberg, Erik

    2015-09-01

    In this paper, nuclear magnetic resonance (NMR) downhole logging data are analyzed with a new strategy to study gas hydrate-bearing sediments in the Mackenzie Delta (NW Canada). In NMR logging, transverse relaxation time (T2) distribution curves are usually used to determine single-valued parameters such as apparent total porosity or hydrocarbon saturation. Our approach analyzes the entire T2 distribution curves as quasi-continuous signals to characterize the rock formation. We apply self-organizing maps, a neural network clustering technique, to subdivide the data set of NMR curves into classes with a similar and distinctive signal shape. The method includes (1) preparation of data vectors, (2) unsupervised learning, (3) cluster definition, and (4) classification and depth mapping of all NMR signals. Each signal class thus represents a specific pore size distribution which can be interpreted in terms of distinct lithologies and reservoir types. A key step in the interpretation strategy is to reconcile the NMR classes with other log data not considered in the clustering analysis, such as gamma ray, hydrate saturation, and other logs. Our results defined six main lithologies within the target zone. Gas hydrate layers were recognized by their low signal amplitudes for all relaxation times. Most importantly, two subtypes of hydrate-bearing shaly sands were identified. They show distinct NMR signals and differ in hydrate saturation and gamma ray values. An inverse linear relationship between hydrate saturation and clay content was concluded. Finally, we infer that the gas hydrate is not grain coating, but rather, pore filling with matrix support is the preferred growth habit model for the studied formation.

  9. Reservoir characterization of Pennsylvanian sandstone reservoirs. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Kelkar, M.

    1995-02-01

    This final report summarizes the progress during the three years of a project on Reservoir Characterization of Pennsylvanian Sandstone Reservoirs. The report is divided into three sections: (i) reservoir description; (ii) scale-up procedures; (iii) outcrop investigation. The first section describes the methods by which a reservoir can be described in three dimensions. The next step in reservoir description is to scale up reservoir properties for flow simulation. The second section addresses the issue of scale-up of reservoir properties once the spatial descriptions of properties are created. The last section describes the investigation of an outcrop.

  10. The thickness of glaciers

    International Nuclear Information System (INIS)

    Faraoni, Valerio; Vokey, Marshall W

    2015-01-01

    Basic formulae and results of glacier physics appearing in glaciology textbooks can be derived from first principles introduced in algebra-based first year physics courses. We discuss the maximum thickness of alpine glaciers and ice sheets and the relation between maximum thickness and length of an ice sheet. Knowledge of ordinary differential equations allows one to derive also the local ice thickness. (paper)

  11. The thickness of glaciers

    Science.gov (United States)

    Faraoni, Valerio; Vokey, Marshall W.

    2015-09-01

    Basic formulae and results of glacier physics appearing in glaciology textbooks can be derived from first principles introduced in algebra-based first year physics courses. We discuss the maximum thickness of alpine glaciers and ice sheets and the relation between maximum thickness and length of an ice sheet. Knowledge of ordinary differential equations allows one to derive also the local ice thickness.

  12. Fundamentals and applications of gas hydrates.

    Science.gov (United States)

    Koh, Carolyn A; Sloan, E Dendy; Sum, Amadeu K; Wu, David T

    2011-01-01

    Fundamental understanding of gas hydrate formation and decomposition processes is critical in many energy and environmental areas and has special importance in flow assurance for the oil and gas industry. These areas represent the core of gas hydrate applications, which, albeit widely studied, are still developing as growing fields of research. Discovering the molecular pathways and chemical and physical concepts underlying gas hydrate formation potentially can lead us beyond flowline blockage prevention strategies toward advancing new technological solutions for fuel storage and transportation, safely producing a new energy resource from natural deposits of gas hydrates in oceanic and arctic sediments, and potentially facilitating effective desalination of seawater. The state of the art in gas hydrate research is leading us to new understanding of formation and dissociation phenomena that focuses on measurement and modeling of time-dependent properties of gas hydrates on the basis of their well-established thermodynamic properties.

  13. Separation of water through gas hydrate formation

    DEFF Research Database (Denmark)

    Boch Andersen, Torben; Thomsen, Kaj

    2009-01-01

    Gas hydrate is normally recognized as a troublemaker in the oil and gas industry. However, gas hydrate has some interesting possibilities when used in connection with separation of water. Nordic Sugar has investigated the possibility of using gas hydrates for concentration of sugar juice. The goa...... volumes and the needs for high pressure. The process could be interesting for concentration of heat sensitive, high value products...

  14. Natural gas hydrate occurrence and issues

    Science.gov (United States)

    Kvenvolden, K.A.

    1994-01-01

    Naturally occurring gas hydrate is found in sediment of two regions: (1) continental, including continental shelves, at high latitudes where surface temperatures are very cold, and (2) submarine outer continental margins where pressures are very high and bottom-water temperatures are near 0??C. Continental gas hydrate is found in association with onshore and offshore permafrost. Submarine gas hydrate is found in sediment of continental slopes and rises. The amount of methane present in gas hydrate is thought to be very large, but the estimates that have been made are more speculative than real. Nevertheless, at the present time there has been a convergence of ideas regarding the amount of methane in gas hydrate deposits worldwide at about 2 x 1016 m3 or 7 x 1017 ft3 = 7 x 105 Tcf [Tcf = trillion (1012) ft3]. The potentially large amount of methane in gas hydrate and the shallow depth of gas hydrate deposits are two of the principal factors driving research concerning this substance. Such a large amount of methane, if it could be commercially produced, provides a potential energy resource for the future. Because gas hydrate is metastable, changes of surface pressure and temperature affect its stability. Destabilized gas hydrate beneath the sea floor leads to geologic hazards such as submarine mass movements. Examples of submarine slope failures attributed to gas hydrate are found worldwide. The metastability of gas hydrate may also have an effect on climate. The release of methane, a 'greenhouse' gas, from destabilized gas hydrate may contribute to global warming and be a factor in global climate change.

  15. Thermal conductivity of hydrate-bearing sediments

    Science.gov (United States)

    Cortes, Douglas D.; Martin, Ana I.; Yun, Tae Sup; Francisca, Franco M.; Santamarina, J. Carlos; Ruppel, Carolyn D.

    2009-01-01

    A thorough understanding of the thermal conductivity of hydrate-bearing sediments is necessary for evaluating phase transformation processes that would accompany energy production from gas hydrate deposits and for estimating regional heat flow based on the observed depth to the base of the gas hydrate stability zone. The coexistence of multiple phases (gas hydrate, liquid and gas pore fill, and solid sediment grains) and their complex spatial arrangement hinder the a priori prediction of the thermal conductivity of hydrate-bearing sediments. Previous studies have been unable to capture the full parameter space covered by variations in grain size, specific surface, degree of saturation, nature of pore filling material, and effective stress for hydrate-bearing samples. Here we report on systematic measurements of the thermal conductivity of air dry, water- and tetrohydrofuran (THF)-saturated, and THF hydrate–saturated sand and clay samples at vertical effective stress of 0.05 to 1 MPa (corresponding to depths as great as 100 m below seafloor). Results reveal that the bulk thermal conductivity of the samples in every case reflects a complex interplay among particle size, effective stress, porosity, and fluid-versus-hydrate filled pore spaces. The thermal conductivity of THF hydrate–bearing soils increases upon hydrate formation although the thermal conductivities of THF solution and THF hydrate are almost the same. Several mechanisms can contribute to this effect including cryogenic suction during hydrate crystal growth and the ensuing porosity reduction in the surrounding sediment, increased mean effective stress due to hydrate formation under zero lateral strain conditions, and decreased interface thermal impedance as grain-liquid interfaces are transformed into grain-hydrate interfaces.

  16. Hydrogen speciation in hydrated layers on nuclear waste glass

    International Nuclear Information System (INIS)

    Aines, R.D.; Weed, H.C.; Bates, J.K.

    1987-01-01

    The hydration of an outer layer on nuclear waste glasses is known to occur during leaching, but the actual speciation of hydrogen (as water or hydroxyl groups) in these layers has not been determined. As part of the Nevada Nuclear Waste Storage Investigations Project, we have used infrared spectroscopy to determine hydrogen speciations in three nuclear waste glass compositions (SRL-131 and 165, and PNL 76-68), which were leached at 90 0 C (all glasses) or hydrated in a vapor-saturated atmosphere at 202 0 C (SRL-131 only). Hydroxyl groups were found in the surface layers of all the glasses. Molecular water was found in the surface of SRL-131 and PNL 76-68 glasses that had been leached for several months in deionized water, and in the vapor-hydrated sample. The water/hydroxyl ratio increases with increasing reaction time; molecular water makes up most of the hydrogen in the thick reaction layers on vapor-phase hydrated glass while only hydroxyl occurs in the least reacted samples. Using the known molar absorptivities of water and hydroxyl in silica-rich glass the vapor-phase layer contained 4.8 moles/liter of molecular water, and 0.6 moles water in the form hydroxyl. A 15 μm layer on SRL-131 glass formed by leaching at 90 0 C contained a total of 4.9 moles/liter of water, 2/3 of which was as hydroxyl. The unreacted bulk glass contains about 0.018 moles/liter water, all as hydroxyl. The amount of hydrogen added to the SRL-131 glass was about 70% of the original Na + Li content, not the 300% that would result from alkali=hydronium ion interdiffusion. If all the hydrogen is then assumed to be added as the result of alkali-H + interdiffusion, the molecular water observed may have formed from condensation of the original hydroxyl groups

  17. Do Pleistocene Glacial-Interglacial Cycles Control Methane Hydrate Formation? An Example from Green Canyon, Gulf of Mexico

    Science.gov (United States)

    Oryan, B.; Malinverno, A.; Goldberg, D.; Fortin, W.

    2017-12-01

    Well GC955-H was drilled in the Green Canyon region under the Gulf of Mexico Gas Hydrates Joint Industry Project in 2009. Logging-while-drilling resistivity logs obtained at the well indicate that the saturation of gas hydrate varies between high and low values in an alternating fashion. This trend is observed from 180 to 360mbsf, depths that correspond to the Late Pleistocene. Similar gas hydrate saturation patterns have been observed in other Gulf of Mexico locations (Walker Ridge sites WR313-G and 313-H) in Late Pleistocene sediments. Our hypothesis is that these variations in saturation can be explained by sea level changes through time during glacial-interglacial cycles. A higher amount of organic matter is deposited and buried in the sediment column during glacial intervals when sea level is low. Microbes in the sediment column degrade organic matter and produce methane gas as a byproduct. Higher availability of organic matter in the sediment column can increase the concentration of methane in the sediment pore water and in turn lead to the formation of gas hydrate. We use a time-dependent numerical model of the formation of gas hydrate to test this hypothesis. The model predicts the volume and distribution of gas hydrates using mass balance equations. Model inputs include in situ porosity determined from bulk density logs; local thermal gradient estimated from the depth of the bottom of the gas hydrate stability zone in proximity to the well; and sedimentation rate determined using the biostratigraphy of an industry well in the vicinity of GC955-H. Initial results show a good match between gas hydrate saturation predicted by the model and resistivity logs obtained in the well. We anticipate that this correlation will establish whether a causal link exists between the saturation of gas hydrate in this reservoir and glacioeustatic sea level changes in the Late Pleistocene.

  18. Accelerated hydration of high silica cements

    International Nuclear Information System (INIS)

    Walker, Colin; Yui, Mikazu

    2012-01-01

    Current Japanese designs for high level radioactive waste (HLW) repositories anticipate the use of both bentonite (buffer and backfill material) and cement based materials. Using hydrated Ordinary Portland Cement (OPC) as a grouting material is undesirable because the associated high pH buffer will have an undisputed detrimental effect on the performance of the bentonite buffer and backfill and of the host rock by changing its porosity. Instead, hydrated low pH cement (LopHC) grouting materials are being developed to provide a pH inferior or equal to 11 to reduce these detrimental effects. LopHC grouting materials use mixtures of superfine OPC (SOPC) clinker and silica fume (SF), and are referred as high silica cements (HSC). The focus of the present study was to identify the development of the unhydrated and hydrated mineral assemblage and the solution chemistry during the hydration of HSC. Since hydration experiments of cementitious materials are notably slow, a ball mill was used to accelerate hydration. This was done for two reasons. Firstly, to develop a method to rapidly hydrate cement based materials without the need for higher temperatures (which can alter the mineral assemblage), and secondly, to ensure that the end point of hydration was reached in a reasonable time frame and so to realize the final mineralogy and solution chemistry of hydrated HSC

  19. Surrogate reservoir models for CSI well probabilistic production forecast

    Directory of Open Access Journals (Sweden)

    Saúl Buitrago

    2017-09-01

    Full Text Available The aim of this work is to present the construction and use of Surrogate Reservoir Models capable of accurately predicting cumulative oil production for every well stimulated with cyclic steam injection at any given time in a heavy oil reservoir in Mexico considering uncertain variables. The central composite experimental design technique was selected to capture the maximum amount of information from the model response with a minimum number of reservoir models simulations. Four input uncertain variables (the dead oil viscosity with temperature, the reservoir pressure, the reservoir permeability and oil sand thickness hydraulically connected to the well were selected as the ones with more impact on the initial hot oil production rate according to an analytical production prediction model. Twenty five runs were designed and performed with the STARS simulator for each well type on the reservoir model. The results show that the use of Surrogate Reservoir Models is a fast viable alternative to perform probabilistic production forecasting of the reservoir.

  20. Waters of Hydration of Cupric Hydrates: A Comparison between Heating and Absorbance Methods

    Science.gov (United States)

    Barlag, Rebecca; Nyasulu, Frazier

    2011-01-01

    The empirical formulas of four cupric hydrates are determined by measuring the absorbance in aqueous solution. The Beer-Lambert Law is verified by constructing a calibration curve of absorbance versus known Cu[superscript 2+](aq) concentration. A solution of the unknown hydrate is prepared by using 0.2-0.3 g of hydrate, and water is added such…

  1. Methane hydrates as potential energy resource: Part 2 - Methane production processes from gas hydrates

    International Nuclear Information System (INIS)

    Demirbas, Ayhan

    2010-01-01

    Three processes have been proposed for dissociation of methane hydrates: thermal stimulation, depressurization, and inhibitor injection. The obvious production approaches involve depressurization, heating and their combinations. The depressurization method is lowering the pressure inside the well and encouraging the methane hydrate to dissociate. Its objective is to lower the pressure in the free-gas zone immediately beneath the hydrate stability zone, causing the hydrate at the base of the hydrate stability zone to decompose. The thermal stimulation method is applied to the hydrate stability zone to raise its temperature, causing the hydrate to decompose. In this method, a source of heat provided directly in the form of injected steam or hot water or another heated liquid, or indirectly via electric or sonic means. This causes methane hydrate to decompose and generates methane gas. The methane gas mixes with the hot water and returns to the surface, where the gas and hot water are separated. The chemical inhibition method seeks to displace the natural-gas hydrate equilibrium condition beyond the hydrate stability zone's thermo-dynamic conditions through injection of a liquid inhibitor chemical adjacent to the hydrate. In this method, inhibitor such as methanol is injected from surface down to methane hydrate-bearing layers. The thermal stimulation method is quite expensive. The chemical inhibitor injection method is also expensive. The depressurization method may prove useful to apply more than one production.

  2. Geochemical Monitoring Of The Gas Hydrate Production By CO2/CH4 Exchange In The Ignik Sikumi Gas Hydrate Production Test Well, Alaska North Slope

    Science.gov (United States)

    Lorenson, T. D.; Collett, T. S.; Ignik Sikumi, S.

    2012-12-01

    Hydrocarbon gases, nitrogen, carbon dioxide and water were collected from production streams at the Ignik Sikumi gas hydrate production test well (TD, 791.6 m), drilled on the Alaska North Slope. The well was drilled to test the feasibility of producing methane by carbon dioxide injection that replaces methane in the solid gas hydrate. The Ignik Sikumi well penetrated a stratigraphically-bounded prospect within the Eileen gas hydrate accumulation. Regionally, the Eileen gas hydrate accumulation overlies the more deeply buried Prudhoe Bay, Milne Point, and Kuparuk River oil fields and is restricted to the up-dip portion of a series of nearshore deltaic sandstone reservoirs in the Sagavanirktok Formation. Hydrate-bearing sandstones penetrated by Ignik Sikumi well occur in three primary horizons; an upper zone, ("E" sand, 579.7 - 597.4 m) containing 17.7 meters of gas hydrate-bearing sands, a middle zone ("D" sand, 628.2 - 648.6 m) with 20.4 m of gas hydrate-bearing sands and a lower zone ("C" sand, 678.8 - 710.8 m), containing 32 m of gas hydrate-bearing sands with neutron porosity log-interpreted average gas hydrate saturations of 58, 76 and 81% respectively. A known volume mixture of 77% nitrogen and 23% carbon dioxide was injected into an isolated section of the upper part of the "C" sand to start the test. Production flow-back part of the test occurred in three stages each followed by a period of shut-in: (1) unassisted flowback; (2) pumping above native methane gas hydrate stability conditions; and (3) pumping below the native methane gas hydrate stability conditions. Methane production occurred immediately after commencing unassisted flowback. Methane concentration increased from 0 to 40% while nitrogen and carbon dioxide concentrations decreased to 48 and 12% respectively. Pumping above the hydrate stability phase boundary produced gas with a methane concentration climbing above 80% while the carbon dioxide and nitrogen concentrations fell to 2 and 18

  3. Hydration in soccer: a review

    Directory of Open Access Journals (Sweden)

    Monteiro Cristiano Ralo

    2003-01-01

    Full Text Available Hydration should be considered before, during and after the exercise. This review intends to approach the main points of hydration process in soccer. The replacement of fluids during exercise is proportional to some factors, such as: exercise intensity; climatic conditions; the athlete's acclimatization; the athlete's physical conditioning; physiologic individual characteristics and the player's biomechanics. Performance is improved when players ingest not only water but also carbohydrate. The rates that carbohydrate and water are absorbed by the organism are limited by the rates of gastric emptying and intestinal absorption. The composition of drinks offered to the players should be influenced by the relative importance of the need of supplying carbohydrates or water; it should be remembered that the depletion of carbohydrate can result in fatigue and decrease of performance, but it is not usually a life-threatening condition. The addition of carbohydrate in these drinks increases the concentrations of blood glucose, increases the use of external fuel through the increase of the glucose oxidation in the muscles and it spares muscle glycogen. So, the ingestion of carbohydrate before and during the exercise can delay the emergence of fatigue and increase the players' performance. Several tactics can be used to avoid dehydration, like hyperhydration before exercise and player's acclimatization. The ideal situation to restore the player's fluid losses is between the sessions of exercises. Since soccer is a sport with quite peculiar characteristics related to hydration, the players should be concerned and educated about the importance of fluid ingestion before, during and after the exercise.

  4. Analysis of USANS data from hydrated cement paste

    International Nuclear Information System (INIS)

    Bertram, W.K.; Sabine, T.M.; Aldridge, L.P.

    2000-01-01

    Full text: The Bonse-Hart technique for Ultra Small Angle Neutron Scattering (USANS) has been used to investigate the microstructure of hydrated cement. Data from these USANS measurements are usually affected by multiple scattering and slit smearing. In the case of cement samples, the simple expedient of reducing the target thickness to eliminate multiple scattering is not a practical one owing firstly, to the difficulty of preparing the samples sufficiently thin, and secondly, to the subsequent low count rates of the scattered beam relative to the transmitted. In this paper we present a method which obviates the need to desmear the USANS data by analyzing the fast Fourier transform of the data. The method also allows us to takes advantage of the process of multiple scattering in thick samples to provide not only information on the shape and size of the scattering entities but also provide absolute values of the scattering contrast between the entities responsible for USANS and the matrix. The method of analysis is applied to USANS data on hydrated cement paste collected on the Ultra High Resolution SANS Diffractometer at Oak Ridge National Laboratory, USA

  5. Protein dynamics: hydration and cavities

    Directory of Open Access Journals (Sweden)

    Heremans K.

    2005-01-01

    Full Text Available The temperature-pressure behavior of proteins seems to be unique among the biological macromolecules. Thermodynamic as well as kinetic data show the typical elliptical stability diagram. This may be extended by assuming that the unfolded state gives rise to volume and enthalpy-driven liquid-liquid transitions. A molecular interpretation follows from the temperature and the pressure dependence of the hydration and cavities. We suggest that positron annihilation spectroscopy can provide additional quantitative evidence for the contributions of cavities to the dynamics of proteins. Only mature amyloid fibrils that form from unfolded proteins are very resistant to pressure treatment.

  6. Modeling the Formation of Hydrate-Filled Veins in Fine-Grained Sediments from in Situ Microbial Methane

    Energy Technology Data Exchange (ETDEWEB)

    Malinverno, Alberto [Lamont-Doherty Earth Observatory, Palisades, NY (United States); Cook, Ann [The Ohio State Univ., Columbus, OH (United States); Daigle, Hugh [Univ. of Texas, Austin, TX (United States)

    2016-12-16

    Continental margin sediments are dominantly fine-grained silt and clay, and methane hydrates in these sediments are often found in semi-vertical veins and fractures. In several instances, these hydrate veins occupy discrete depth intervals that are a few tens of meters thick and are surrounded by hydrate-free sediments. As they are not connected with gas sources beneath the base of the gas hydrate stability zone (GHSZ), these isolated hydrate-bearing intervals have been interpreted as formed by in situ microbial methane. To investigate the formation of these hydrate deposits, we applied a time-dependent advection-diffusion-reaction model that includes the effects of sedimentation, compaction, solute diffusion, and microbial methane generation. Microbial methane generation depends on the amount of metabolizable organic carbon deposited at the seafloor, whose progressive degradation produces methane beneath the sulfate reduction zone. If the amount of organic carbon entering the methanogenic zone is kept constant in time, we found that the computed amounts of hydrate formed in discrete intervals within the GHSZ are well below those estimated from observations. On the other hand, if the deposition of organic carbon is higher in a given time interval, methane generation during burial is more intense in the corresponding sediment interval, resulting in enhanced hydrate formation. With variations in organic carbon deposition comparable to those generally observed in continental margins, our model was able to reproduce the methane hydrate contents that were estimated from drilling. These results support the suggestion that in situ microbial generation associated with transient organic carbon deposition is the source of methane that forms isolated intervals of hydrate-filled veins in fine-grained sediments.

  7. Experimental investigation of gas hydrate formation, plugging and transportability in partially dispersed and water continuous systems

    Science.gov (United States)

    Vijayamohan, Prithvi

    As oil/gas subsea fields mature, the amount of water produced increases significantly due to the production methods employed to enhance the recovery of oil. This is true especially in the case of oil reservoirs. This increase in the water hold up increases the risk of hydrate plug formation in the pipelines, thereby resulting in higher inhibition cost strategies. A major industry concern is to reduce the severe safety risks associated with hydrate plug formation, and significantly extending subsea tieback distances by providing a cost effective flow assurance management/safety tool for mature fields. Developing fundamental understanding of the key mechanistic steps towards hydrate plug formation for different multiphase flow conditions is a key challenge to the flow assurance community. Such understanding can ultimately provide new insight and hydrate management guidelines to diminish the safety risks due to hydrate formation and accumulation in deepwater flowlines and facilities. The transportability of hydrates in pipelines is a function of the operating parameters, such as temperature, pressure, fluid mixture velocity, liquid loading, and fluid system characteristics. Specifically, the hydrate formation rate and plugging onset characteristics can be significantly different for water continuous, oil continuous, and partially dispersed systems. The latter is defined as a system containing oil/gas/water, where the water is present both as a free phase and partially dispersed in the oil phase (i.e., entrained water in the oil). Since hydrate formation from oil dispersed in water systems and partially dispersed water systems is an area which is poorly understood, this thesis aims to address some key questions in these systems. Selected experiments have been performed at the University of Tulsa flowloop to study the hydrate formation and plugging characteristics for the partially dispersed water/oil/gas systems as well as systems where the oil is completely dispersed

  8. Formation rate of natural gas hydrate

    Energy Technology Data Exchange (ETDEWEB)

    Mork, Marit

    2002-07-01

    The rate of methane hydrate and natural gas hydrate formation was measured in a 9.5 litre stirred tank reactor of standard design. The experiments were performed to better understand the performance and scale-up of a reactor for continuous production of natural gas hydrates. The hydrate formation rate was measured at steady-state conditions at pressures between 70 and 90 bar and temperatures between 7 and 15 deg C. Between 44 and 56 % of the gas continuously supplied to the reactor was converted to hydrate. The experimental results show that the rate of hydrate formation is strongly influenced by gas injection rate and pressure. The effect of stirring rate is less significant and subcooling has no observable effect on the formation rate. Hydrate crystal concentration and gas composition do not influence the hydrate formation rate. Observations of produced hydrate crystals indicate that the crystals are elongated, about 5 micron in diameter and 10 micron long. Analysis of the results shows that the rate of hydrate formation is dominated by gas-liquid mass transfer. A mass transfer model, the bubble-to-crystal model, was developed for the hydrate formation rate in a continuous stirred tank reactor, given in terms of concentration driving force and an overall mass transfer coefficient. The driving force is the difference between the gas concentration at the gas-liquid interface and at the hydrate crystal surface. These concentrations correspond to the solubility of gas in water at experimental temperature and pressure and the solubility of gas at hydrate equilibrium temperature and experimental pressure, respectively. The overall mass transfer coefficient is expressed in terms of superficial gas velocity and impeller power consumption, parameters commonly used in study of stirred tank reactors. Experiments and modeling show that the stirred tank reactor has a considerable potential for increased production capacity. However, at higher hydrate production rates the

  9. Ray-based stochastic inversion of pre-stack seismic data for improved reservoir characterisation

    NARCIS (Netherlands)

    van der Burg, D.W.

    2007-01-01

    To estimate rock and pore-fluid properties of oil and gas reservoirs in the subsurface, techniques can be used that invert seismic data. Hereby, the detailed information about the reservoir that is available at well locations, such as the thickness and porosity of individual layers, is extrapolated

  10. Optimising reservoir operation

    DEFF Research Database (Denmark)

    Ngo, Long le

    Anvendelse af optimeringsteknik til drift af reservoirer er blevet et væsentligt element i vandressource-planlægning og -forvaltning. Traditionelt har reservoirer været styret af heuristiske procedurer for udtag af vand, suppleret i en vis udstrækning af subjektive beslutninger. Udnyttelse af...... reservoirer involverer en lang række interessenter med meget forskellige formål (f.eks. kunstig vanding, vandkraft, vandforsyning mv.), og optimeringsteknik kan langt bedre lede frem til afbalancerede løsninger af de ofte modstridende interesser. Afhandlingen foreslår en række tiltag, hvormed traditionelle...... driftsstrategier kan erstattes af optimale strategier baseret på den nyeste udvikling indenfor computer-baserede beregninger. Hovedbidraget i afhandlingen er udviklingen af et beregningssystem, hvori en simuleringsmodel er koblet til en model for optimering af nogle udvalgte beslutningsvariable, der i særlig grad...

  11. Clinker mineral hydration at reduced relative humidities

    DEFF Research Database (Denmark)

    Jensen, Ole Mejlhede

    1998-01-01

    This report deals with gas phase hydration of pure cement clinker minerals at reduced relative humidities. This is an important subject in relation to modern high performance concrete which may self-desiccate during hydration. In addition the subject has relevance to storage stability where...

  12. Raman Spectroscopic Studies of Methane Gas Hydrates

    DEFF Research Database (Denmark)

    Hansen, Susanne Brunsgaard; Berg, Rolf W.

    2009-01-01

    A brief review of the Raman spectroscopic studies of methane gas hydrates is given, supported by some new measurements done in our laboratory.......A brief review of the Raman spectroscopic studies of methane gas hydrates is given, supported by some new measurements done in our laboratory....

  13. Investigations into surfactant/gas hydrate relationship

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, Rudy; Zhang, Guochang; Dearman, Jennifer; Woods, Charles [Swalm School of Chemical Engineering, Mississippi State University, Mississippi State, MS 39762 (United States)

    2007-03-15

    Gas hydrates have unique physical properties portending useful industrial applications of gas storage, gas separation, or water desalination. When gas hydrates were found in the early 1990s to occur naturally and abundantly in seafloors, three other primary interests and concerns emerged: potential new energy source, climate threat from their greenhouse gases, and seafloor instabilities. This paper presents research showing how anionic synthetic surfactants helped develop an industrial gas hydrate storage process for natural gas and how naturally-occurring in-situ anionic biosurfactants influence the formation and placement of gas hydrates in ocean sediments. The catalytic effects, mechanisms, and surface specificities imparted by synthetic surfactants in the gas storage process and imparted by biosurfactants in porous media are discussed. The Bacillus subtilis bacterium that is indigenous to gas hydrate mounds in the Gulf of Mexico was cultured in the laboratory. Its biosurfactant was separated and found to catalyze gas hydrates in porous media. The experiments indicate that seafloor-biosurfactants can be produced rapidly in-situ to achieve threshold concentrations whereby hydrates are promoted. The biosurfactants accumulate and promote hydrate formation on specific mineral surfaces such as sodium montmorillonite. (author)

  14. Free energy of hydration of niobium oxide

    International Nuclear Information System (INIS)

    Plodinec, M.J.

    1996-01-01

    Some of the glasses being formulated by SRTC researchers contain niobium oxide. In this report, the free energy of hydration of the oxide is calculated from the free energies of formation of the oxide, the hydroxide, and water. This value can be used in calculations of the free energy of hydration of glasses containing niobium

  15. Pentagonal dodecahedron methane hydrate cage and methanol ...

    Indian Academy of Sciences (India)

    Abstract. Density functional theory based studies have been performed to elucidate the role of methanol as an methane hydrate inhibitor. A methane hydrate pentagonal dodecahedron cage's geometry optimization, natural bond orbital (NBO) analysis, Mullikan charge determination, electrostatic potential evaluation and ...

  16. Multicomponent modelling of Portland cement hydration reactions

    NARCIS (Netherlands)

    Ukrainczyk, N.; Koenders, E.A.B.; Van Breugel, K.

    2012-01-01

    The prospect of cement and concrete technologies depends on more in depth understanding of cement hydration reactions. Hydration reaction models simulate the development of the microstructures that can finally be used to estimate the cement based material properties that influence performance and

  17. 78 FR 26337 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2013-05-06

    ... DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of Open Meeting. SUMMARY: This notice announces a meeting of the Methane.... SUPPLEMENTARY INFORMATION: Purpose of the Committee: The purpose of the Methane Hydrate Advisory Committee is to...

  18. 75 FR 9886 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2010-03-04

    ... DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee AGENCY: Department of Energy, Office of Fossil Energy. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the Methane... the Committee: The purpose of the Methane Hydrate Advisory Committee is to provide advice on potential...

  19. 76 FR 59667 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2011-09-27

    ... DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of Open Meeting. SUMMARY: This notice announces a meeting of the Methane...-5600. SUPPLEMENTARY INFORMATION: Purpose of the Committee: The purpose of the Methane Hydrate Advisory...

  20. 78 FR 37536 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2013-06-21

    ... DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the Methane... Committee: The purpose of the Methane Hydrate Advisory Committee is to provide advice on potential...

  1. 77 FR 40032 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2012-07-06

    ... DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the Methane... of the Methane Hydrate Advisory Committee is to provide advice on potential applications of methane...

  2. Geothermal reservoir engineering

    CERN Document Server

    Grant, Malcolm Alister

    2011-01-01

    As nations alike struggle to diversify and secure their power portfolios, geothermal energy, the essentially limitless heat emanating from the earth itself, is being harnessed at an unprecedented rate.  For the last 25 years, engineers around the world tasked with taming this raw power have used Geothermal Reservoir Engineering as both a training manual and a professional reference.  This long-awaited second edition of Geothermal Reservoir Engineering is a practical guide to the issues and tasks geothermal engineers encounter in the course of their daily jobs. The bo

  3. Session: Reservoir Technology

    Energy Technology Data Exchange (ETDEWEB)

    Renner, Joel L.; Bodvarsson, Gudmundur S.; Wannamaker, Philip E.; Horne, Roland N.; Shook, G. Michael

    1992-01-01

    This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of five papers: ''Reservoir Technology'' by Joel L. Renner; ''LBL Research on the Geysers: Conceptual Models, Simulation and Monitoring Studies'' by Gudmundur S. Bodvarsson; ''Geothermal Geophysical Research in Electrical Methods at UURI'' by Philip E. Wannamaker; ''Optimizing Reinjection Strategy at Palinpinon, Philippines Based on Chloride Data'' by Roland N. Horne; ''TETRAD Reservoir Simulation'' by G. Michael Shook

  4. Effects of Fluid Saturation on Gas Recovery from Class-3 Hydrate Accumulations Using Depressurization: Case Study of Yuan-An Ridge Site in Southwestern Offshore Taiwan

    Science.gov (United States)

    Huang, Yi-Jyun; Wu, Cheng-Yueh; Hsieh, Bieng-Zih

    2016-04-01

    Gas hydrates are crystalline compounds in which guest gas molecules are trapped in host lattices of ice crystals. In Taiwan, the significant efforts have recently begun to evaluate the reserves of hydrate because the vast accumulations of gas hydrates had been recognized in southwestern offshore Taiwan. Class-3 type hydrate accumulations are referred to an isolated hydrate layer without an underlying zone of mobile fluids, and the entire hydrate layer may be well within the hydrate stability zone. The depressurization method is a useful dissociation method for gas production from Class-3 hydrate accumulations. The dissociation efficiency is controlled by the responses of hydrate to the propagating pressure disturbance, and the pressure propagation is relating to the amount (or saturation) of the mobile fluid in pore space of the hydrate layer. The purpose of this study is to study the effects of fluid saturation on the gas recovery from a class-3 hydrate accumulation using depressurization method. The case of a class-3 hydrate deposit of Yuan-An Ridge in southwestern offshore Taiwan is studied. The numerical method was used in this study. The reservoir simulator we used to study the dissociation of hydrate and the production of gas was the STARS simulator developed by CMG, which coupled heat transfer, geo-chemical, geo-mechanical, and multiphase fluid flow mechanisms. The study case of Yuan-An Ridge is located in southwestern offshore Taiwan. The hydrate deposit was found by the bottom simulating reflectors (BSRs). The geological structure of the studied hydrate deposit was digitized to build the geological model (grids) of the case. The formation parameters, phase behavior data, rock and fluid properties, and formation's initial conditions were assigned sequentially to grid blocks, and the completion and operation conditions were designed to wellbore blocks to finish the numerical model. The changes of reservoir pressure, temperature, saturation due to the hydrate

  5. Experimental Setup to Characterize Bentonite Hydration Processes

    International Nuclear Information System (INIS)

    Bru, A.; Casero, D.; Pastor, J. M.

    2001-01-01

    We present an experimental setup to follow-up the hydration process of a bentonite. Clay samples, of 2 cm x 12 cm x 12 cm, were made and introduced in a Hele-Shaw cell with two PMM windows and two steel frames. In hydration experiments, a fluid enters by an orifice in the frame, located both at the top and the bottom of the cell, to perform hydration in both senses. To get a uniform hydration we place a diffuser near the orifice. Volume influxes in hydration cells are registered in time. The evolution of the developed interface was recorded on a videotape. The video cameras was fixed to a holder so that the vertical direction in the monitor was the same as the direction of the larger extension of the cell. (Author) 6 refs

  6. Hydration shells exchange charge with their protein

    DEFF Research Database (Denmark)

    Abitan, Haim; Lindgård, Per-Anker; Nielsen, Bjørn Gilbert

    2010-01-01

    . In our experiments, the amplitude of an ultrasonic pressure wave is gradually increased (0–20 atm) while we simultaneously measure the Raman spectra from the hydrated protein (β-lactoglobulin and lysozyme). We detected two types of spectral changes: first, up to 70% increase in the intensity......Investigation of the interaction between a protein and its hydration shells is an experimental and theoretical challenge. Here, we used ultrasonic pressure waves in aqueous solutions of a protein to explore the conformational states of the protein and its interaction with its hydration shells...... the presence of an ultrasonic pressure, a protein and its hydration shells are in thermodynamic and charge equilibrium, i.e. a protein and its hydration shells exchange charges. The ultrasonic wave disrupts these equilibria which are regained within 30–45 min after the ultrasonic pressure is shut off....

  7. Overview on Hydrate Coring, Handling and Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jon Burger; Deepak Gupta; Patrick Jacobs; John Shillinglaw

    2003-06-30

    Gas hydrates are crystalline, ice-like compounds of gas and water molecules that are formed under certain thermodynamic conditions. Hydrate deposits occur naturally within ocean sediments just below the sea floor at temperatures and pressures existing below about 500 meters water depth. Gas hydrate is also stable in conjunction with the permafrost in the Arctic. Most marine gas hydrate is formed of microbially generated gas. It binds huge amounts of methane into the sediments. Worldwide, gas hydrate is estimated to hold about 1016 kg of organic carbon in the form of methane (Kvenvolden et al., 1993). Gas hydrate is one of the fossil fuel resources that is yet untapped, but may play a major role in meeting the energy challenge of this century. In June 2002, Westport Technology Center was requested by the Department of Energy (DOE) to prepare a ''Best Practices Manual on Gas Hydrate Coring, Handling and Analysis'' under Award No. DE-FC26-02NT41327. The scope of the task was specifically targeted for coring sediments with hydrates in Alaska, the Gulf of Mexico (GOM) and from the present Ocean Drilling Program (ODP) drillship. The specific subjects under this scope were defined in 3 stages as follows: Stage 1: Collect information on coring sediments with hydrates, core handling, core preservation, sample transportation, analysis of the core, and long term preservation. Stage 2: Provide copies of the first draft to a list of experts and stakeholders designated by DOE. Stage 3: Produce a second draft of the manual with benefit of input from external review for delivery. The manual provides an overview of existing information available in the published literature and reports on coring, analysis, preservation and transport of gas hydrates for laboratory analysis as of June 2003. The manual was delivered as draft version 3 to the DOE Project Manager for distribution in July 2003. This Final Report is provided for records purposes.

  8. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    Energy Technology Data Exchange (ETDEWEB)

    Thomas E. Williams; Keith Millheim; Bill Liddell

    2005-03-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated

  9. Reservoir characteristics and control factors of Carboniferous volcanic gas reservoirs in the Dixi area of Junggar Basin, China

    Directory of Open Access Journals (Sweden)

    Ji'an Shi

    2017-02-01

    volcanic breccia reservoir more easily leached by fresh water or groundwater, leading to secondary erosion pores. Volcanic rock weathering obviously has control on reservoir properties, and while the thickness of the weathering crust is 200–300 m, the properties of volcanic rock reservoir are the best. This is attributed mainly to the period during and after the volcano eruption, in which tectonism made the brittle volcanic rock develop a large number of fractures and micro cracks. This has led to the increased permeability of volcanic rock reservoir, the weathering and leaching effect of volcanic rock diagenetic late phase (which also formed lots of secondary pores, and greatly improved reservoir conditions. The overlying Permian Wutonggou formation mudstone provided high-quality cap rock for oil and gas accumulation.

  10. Computational Recreation of Carbon Dioxide Hydrates at Habitable Planetary Conditions

    Science.gov (United States)

    Recio, J. M.; Izquierdo-Ruiz, F.; Prieto-Ballesteros, O.

    2017-12-01

    Gas clathrate hydrates are proposed as constituents of the icy moons of the giant planets in the Solar System [1]. Carbon dioxide has been detected on the surface of the moons of Jupiter, supposedly originated by internal degasification. In Ganymede, an aqueous ocean is proposed to exist under a thick ice crust in coexistence with several forms of ice, with pressure reaching up to 1.3 GPa [2]. Due to the limited available data on these systems under these conditions, we propose a combination of computational and experimental studies to describe microscopically and macroscopically the structural and chemical behavior of CO2@H2O polymorphs. This will allow us to understand how their presence affects the geophysical structure and activity and their impact on the habitability of the icy moon. A transition from the sI cubic structure to a high pressure phase at around 0.7 GPa has been found for CO2@H2O. In spite of different attempts to characterize the new structure, a definite answer has not been provided yet. A MH-III Filled Ice Structure type was proposed after neutron diffraction experiments in contrast with an alternative structure similar to the hexagonal C0 type for H2 hydrates [3]. It has an estimated hydration level ratio up to 2H2O:1CO2 and 6 water molecules per unit cell. In the figure below, our optimized unit cell based on this hexagonal C0 structure is displayed. Ab initio calculations using the XDM approximation to include van der Waals effects are performed in our search for the pressure evolution of the equilibrium geometries of the C0-CO2@H2O phase and those of a close related structure to this one called Ih-C0, with 8 water molecules per unit cell. We obtain occupation energies at different hydration ratios, densities, equations of state parameters, and stability energies with respect to decomposition. Raman and IR frequencies are also computed in the 0-2 GPa range. High pressure experiments are also being done in a newly designed chamber able to

  11. Growth mode transition of tetrahydrofuran clathrate hydrates in the guest/host concentration boundary layer.

    Science.gov (United States)

    Sabase, Yuichiro; Nagashima, Kazushige

    2009-11-19

    Clathrate hydrates are known to form a thin film along a guest/host boundary. We present here the first report of tetrahydrofuran (THF) clathrate hydrate formation in a THF/water concentration boundary layer. We found that the THF-water system also forms a hydrate film separating the guest/host phases. The lateral growth rate of the film increases as supercooling increases. The thickness of the film at the growth tip decreases as supercooling and the lateral growth rate increase. These tendencies are consistent with reports of experiments for other hydrates and predictions of heat-transfer models. After film formation and slight melting, two types of growth modes are observed, depending on temperature T. At T = 3.0 degrees C, the film slowly thickens. The thickening rate is much lower than the lateral growth rate, as reported for other hydrates. At T agglomerate of small polycrystalline hydrates forms in each phase. Grain boundaries in the film and pore spaces in the agglomerate act as paths for permeation of each liquid. Timing when continuous nucleation starts is dominantly controlled by the time of initiation of liquid permeation through the film. Digital particle image velocimetry analysis of the agglomerate shows that it expands not by growth at the advancing front but rather by continuous nucleation in the interior. Expansion rates of the agglomerate tend to be higher for the cases of multipermeation paths in the film and the thinner film. We suppose that the growth mode transition to continuous nucleation is caused by the memory effect due to slight melting of the hydrate film.

  12. A Counter-Current Heat-Exchange Reactor for the Thermal Stimulation of Hydrate-Bearing Sediments

    Directory of Open Access Journals (Sweden)

    Manja Luzi-Helbing

    2013-06-01

    Full Text Available Since huge amounts of CH4 are bound in natural gas hydrates occurring at active and passive continental margins and in permafrost regions, the production of natural gas from hydrate-bearing sediments has become of more and more interest. Three different methods to destabilize hydrates and release the CH4 gas are discussed in principle: thermal stimulation, depressurization and chemical stimulation. This study focusses on the thermal stimulation using a counter-current heat-exchange reactor for the in situ combustion of CH4. The principle of in situ combustion as a method for thermal stimulation of hydrate bearing sediments has been introduced and discussed earlier [1,2]. In this study we present the first results of several tests performed in a pilot plant scale using a counter-current heat-exchange reactor. The heat of the flameless, catalytic oxidation of CH4 was used for the decomposition of hydrates in sand within a LArge Reservoir Simulator (LARS. Different catalysts were tested, varying from diverse elements of the platinum group to a universal metal catalyst. The results show differences regarding the conversion rate of CH4 to CO2. The promising results of the latest reactor test, for which LARS was filled with sand and ca. 80% of the pore space was saturated with CH4 hydrate, are also presented in this study. The data analysis showed that about 15% of the CH4 gas released from hydrates would have to be used for the successful dissociation of all hydrates in the sediment using thermal stimulation via in situ combustion.

  13. The assessment of different production methods for hydrate bearing sediments - results from small and large scale experiments

    Science.gov (United States)

    Schicks, Judith; Heeschen, Katja; Spangenberg, Erik; Luzi-Helbing, Manja; Beeskow-Strauch, Bettina; Priegnitz, Mike; Giese, Ronny; Abendroth, Sven; Thaler, Jan

    2017-04-01

    Natural gas hydrates occur at all active and passive continental margins, in permafrost regions, and deep lakes. Since they are supposed to contain enormous amounts of methane, gas hydrates are discussed as an energy resource. For the production of gas from hydrate bearing sediments, three different production methods were tested during the last decade: depressurization, thermal and chemical stimulation as well as combinations of these methods. In the framework of the SUGAR project we developed a Large Scale Reservoir Simulator (LARS) with a total volume of 425L to test these three methods in a pilot plant scale. For this purpose we formed hydrate from methane saturated brine in sediments under conditions close to natural gas hydrate deposits. The obtained hydrate saturations varied between 40-90%. Hydrate saturation and distribution were determined using electrical resistivity tomography (ERT). The volumes of the produced gas and water were determined and the gas phase was analyzed via gas chromatography. Multi-step depressurization, thermal stimulation applying in-situ combustion as well as chemical stimulation via the injection of CO2 and a CO2-N2-mixture were tested. Depressurization and thermal stimulation appear to be less complicated compared to the chemical stimulation. For the understanding of the macroscopically observed processes on a molecular level, we also performed experiments on a smaller scale using microscopic observation, Raman spectroscopy and X-ray diffraction. The results of these experiments are of particular importance for the understanding of the processes occurring during the CO2-CH4 swapping. Under the chosen experimental conditions the observations indicate a (partial) decomposition and reformation of the hydrate structure rather than a diffusion-controlled exchange of the molecules.

  14. Parallel reservoir simulator computations

    International Nuclear Information System (INIS)

    Hemanth-Kumar, K.; Young, L.C.

    1995-01-01

    The adaptation of a reservoir simulator for parallel computations is described. The simulator was originally designed for vector processors. It performs approximately 99% of its calculations in vector/parallel mode and relative to scalar calculations it achieves speedups of 65 and 81 for black oil and EOS simulations, respectively on the CRAY C-90

  15. Education and "Thick" Epistemology

    Science.gov (United States)

    Kotzee, Ben

    2011-01-01

    In this essay Ben Kotzee addresses the implications of Bernard Williams's distinction between "thick" and "thin" concepts in ethics for epistemology and for education. Kotzee holds that, as in the case of ethics, one may distinguish between "thick" and "thin" concepts of epistemology and, further, that this distinction points to the importance of…

  16. Gas Hydrate Storage of Natural Gas

    Energy Technology Data Exchange (ETDEWEB)

    Rudy Rogers; John Etheridge

    2006-03-31

    Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a

  17. Clathrate hydrate tuning for technological purposes

    Science.gov (United States)

    di Profio, Pietro; Germani, Raimondo; Savelli, Gianfranco

    2010-05-01

    Gas hydrates are being increasingly considered as convenient media for gas storage and transportation as the knowledge of their properties increases, in particular as relates to methane and hydrogen. Clathrate hydrates may also represent a feasible sequestration technology for carbon dioxide, due to a well defined P/T range of stability, and several research programs are addressing this possibility. Though the understanding of the molecular structure and supramolecular interactions which are responsible of most properties of hydrates have been elucitated in recent years, the underlying theoretical physico-chemical framework is still poor, especially as relates to the role of "conditioners" (inhibitors and promoters) from the molecular/supramolecular point of view. In the present communication we show some results from our research approach which is mainly focused on the supramolecular properties of clathrate hydrate systems - and their conditioners - as a way to get access to a controlled modulation of the formation, dissociation and stabilization of gas hydrates. In particular, this communication will deal with: (a) a novel, compact apparatus for studying the main parameters of formation and dissociation of gas hydrates in a one-pot experiment, which can be easily and rapidly carried out on board of a drilling ship;[1] (b) the effects of amphiphile molecules (surfactants) as inhibitors or promoters of gas hydrate formation;[2] (c) a novel nanotechnology for a reliable and quick production of hydrogen hydrates, and its application to fuel cells;[3,4] and (d) the development of a clathrate hydrate tecnology for the sequestration and geological storage of man-made CO2, possibly with concomitant recovery of natural gas from NG hydrate fields. Furthermore, the feasibility of catalyzing the reduction of carbon dioxide to energy-rich species by hydrates is being investigated. [1] Di Profio, P., Germani, R., Savelli, G., International Patent Application PCT/IT2006

  18. Hydration water dynamics around a protein surface: a first passage time approach

    Science.gov (United States)

    Sharma, Shivangi; Biswas, Parbati

    2018-01-01

    A stochastic noise-driven dynamic model is proposed to study the diffusion of water molecules around a protein surface, under the effect of thermal fluctuations that arise due to the collision of water molecules with the surrounding environment. The underlying dynamics of such a system may be described in the framework of the generalized Langevin equation, where the thermal fluctuations are assumed to be algebraically correlated in time, which governs the non-Markovian behavior of the system. Results of the calculations of mean-square displacement and the velocity autocorrelation function reveal that the hydration water around the protein surface follows subdiffusive dynamics at long times. Analytical expressions for the first passage time distribution, survival probability, mean residence time and mean first passage time of water molecules are derived for different boundary conditions, to analyze hydration water dynamics under the effect of thermally correlated noise. The results depict a unimodal distribution of the first passage time unlike Brownian motion. The survival probability of hydration water follows a stretched exponential decay for both boundary conditions. The mean residence time of the hydration water molecule for different initial positions increases with increase in the complexity/heterogeneity of the surrounding environment for both boundary conditions. The mean first passage time of the water molecule to reach the absorbing/reflecting boundary follows an asymptotic power law with respect to the thickness of the hydration layer, and increases with increase in the complexity/heterogeneity of the environment.

  19. Simulations of single-particle imaging of hydrated proteins with x-ray free-electron lasers

    Science.gov (United States)

    Fortmann-Grote, C.; Bielecki, J.; Jurek, Z.; Santra, R.; Ziaja-Motyka, B.; Mancuso, A. P.

    2017-08-01

    We employ start-to-end simulations to model coherent diffractive imaging of single biomolecules using x-ray free electron lasers. This technique is expected to yield new structural information about biologically relevant macromolecules thanks to the ability to study the isolated sample in its natural environment as opposed to crystallized or cryogenic samples. The effect of the solvent on the diffraction pattern and interpretability of the data is an open question. We present first results of calculations where the solvent is taken into account explicitly. They were performed with a molecular dynamics scheme for a sample consisting of a protein and a hydration layer of varying thickness. Through R-factor analysis of the simulated diffraction patterns from hydrated samples, we show that the scattering background from realistic hydration layers of up to 3 Å thickness presents no obstacle for the resolution of molecular structures at the sub-nm level.

  20. The Use of Horizontal Wells in Gas Production from Hydrate Accumulations

    Energy Technology Data Exchange (ETDEWEB)

    Reagan, Matthew; Moridis, George J.; Reagan, Matthew T.; Zhang, Keni

    2008-04-15

    The amounts of hydrocarbon gases trapped in natural hydrate accumulations are enormous, leading to a recent interest in the evaluation of their potential as an energy source. Earlier studies have demonstrated that large volumes of gas can be readily produced at high rates for long times from gas hydrate accumulations by means of depressurization-induced dissociation, using conventional technology and vertical wells. The results of this numerical study indicate that the use of horizontal wells does not confer any practical advantages to gas production from Class 1 deposits. This is because of the large disparity in permeabilities between the hydrate layer (HL) and the underlying free gas zone, leading to a hydrate dissociation that proceeds in a horizontally dominant direction and is uniform along the length of the reservoir. When horizontal wells are placed near the base of the HL in Class 2 deposits, the delay in the evolution of a significant gas production rate outweighs their advantages, which include higher rates and the prevention of flow obstruction problems that often hamper the performance of vertical wells. Conversely, placement of a horizontal well near to top of the HL can lead to dramatic increases in gas production from Class 2 and Class 3 deposits over the corresponding production from vertical wells.

  1. Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments

    International Nuclear Information System (INIS)

    Moridis, George J.; Sloan, E. Dendy

    2007-01-01

    In this paper, we evaluate the gas production potential of disperse, low-saturation (S H H hydrate-bearing sediments subject to depressurization-induced dissociation over a 10-year production period. We investigate the sensitivity of items (a)-(c) to the following hydraulic properties, reservoir conditions, and operational parameters: intrinsic permeability, porosity, pressure, temperature, hydrate saturation, and constant pressure at which the production well is kept. The results of this study indicate that, despite wide variations in the aforementioned parameters (covering the entire spectrum of such deposits), gas production is very limited, never exceeding a few thousand cubic meters of gas during the 10-year production period. Such low production volumes are orders of magnitude below commonly accepted standards of economic viability, and are further burdened with very unfavorable gas-to-water ratios. The unequivocal conclusion from this study is that disperse, low-S H hydrate accumulations in oceanic sediments are not promising targets for gas production by means of depressurization-induced dissociation, and resources for early hydrate exploitation should be focused elsewhere

  2. Pf1 bacteriophage hydration by magic angle spinning solid-state NMR

    Energy Technology Data Exchange (ETDEWEB)

    Sergeyev, Ivan V.; Bahri, Salima; McDermott, Ann E., E-mail: aem5@columbia.edu [Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027 (United States); Day, Loren A. [Public Health Research Institute, Rutgers University, 225 Warren St., Newark, New Jersey 07103 (United States)

    2014-12-14

    High resolution two- and three-dimensional heteronuclear correlation spectroscopy ({sup 1}H–{sup 13}C, {sup 1}H–{sup 15}N, and {sup 1}H–{sup 13}C–{sup 13}C HETCOR) has provided a detailed characterization of the internal and external hydration water of the Pf1 virion. This long and slender virion (2000 nm × 7 nm) contains highly stretched DNA within a capsid of small protein subunits, each only 46 amino acid residues. HETCOR cross-peaks have been unambiguously assigned to 25 amino acids, including most external residues 1–21 as well as residues 39–40 and 43–46 deep inside the virion. In addition, the deoxyribose rings of the DNA near the virion axis are in contact with water. The sets of cross-peaks to the DNA and to all 25 amino acid residues were from the same hydration water {sup 1}H resonance; some of the assigned residues do not have exchangeable side-chain protons. A mapping of the contacts onto structural models indicates the presence of water “tunnels” through a highly hydrophobic region of the capsid. The present results significantly extend and modify results from a lower resolution study, and yield a comprehensive hydration surface map of Pf1. In addition, the internal water could be distinguished from external hydration water by means of paramagnetic relaxation enhancement. The internal water population may serve as a conveniently localized magnetization reservoir for structural studies.

  3. Calcium and magnesium silicate hydrates

    International Nuclear Information System (INIS)

    Lothenbach, B.; L'Hopital, E.; Nied, D.; Achiedo, G.; Dauzeres, A.

    2015-01-01

    Deep geological disposals are planed to discard long-lived intermediate-level and high-level radioactive wastes. Clay-based geological barriers are expected to limit the ingress of groundwater and to reduce the mobility of radioelements. In the interaction zone between the cement and the clay based material alteration can occur. Magnesium silicate hydrates (M-S-H) have been observed due to the reaction of magnesium sulfate containing groundwater with cements or in the interaction zone between low-pH type cement and clays. M-S-H samples synthesized in the laboratory showed that M-S-H has a variable composition within 0.7 ≤ Mg/Si ≤ 1.5. TEM/EDS analyses show an homogeneous gel with no defined structure. IR and 29 Si NMR data reveal a higher polymerization degree of the silica network in M-S-H compared to calcium silicate hydrates (C-S-H). The presence of mainly Q 3 silicate tetrahedrons in M-S-H indicates a sheet like or a triple-chain silica structure while C-S-H is characterised by single chain-structure. The clear difference in the silica structure and the larger ionic radius of Ca 2+ (1.1 Angstrom) compared to Mg 2+ (0.8 Angstrom) make the formation of an extended solid solution between M-S-H and C-S-H gel improbable. In fact, the analyses of synthetic samples containing both magnesium and calcium in various ratios indicate the formation of separate M-S-H and C-S-H gels with no or very little uptake of magnesium in CS-H or calcium in M-S-H

  4. Hydration Properties of Ground Granulated Blast-Furnace Slag (GGBS Under Different Hydration Environments

    Directory of Open Access Journals (Sweden)

    Shuhua LIU

    2017-02-01

    Full Text Available The hydration properties of various cementitious materials containing Ground Granulated Blast-furnace Slag (GGBS, two alkali-activated slag cements (AAS-1 and AAS-2 in which sodium silicate and sodium hydroxide act as alkaline activators respectively, supersulfated cement (SSC and slag Portland cement(PSC, are compared with ordinary Portland cement (OPC to investigate the effect of activating environment on the hydration properties in this study by determining the compressive strength of the pastes, the hydration heat of binders within 96 hours, and the hydration products at age of 28 days. The results show that C-S-H gels are the main hydrated products for all cementitious systems containing GGBS. Ca(OH2 is the hydration products of OPC and PSC paste. However, ettringite and gypsum crystals instead of Ca(OH2 are detected in SSC paste. Additionally, tobermorite, a crystalline C-S-H, and calcite are hydrated products in AAS-1. Tobermorite, cowlesite and calcite are hydrated products of AAS-2 as well. Based on strength results, AAS-1 paste exhibits the highest compressive strength followed by POC, PSC, SSC in order at all testing ages and AAS-2 give the lowest compressive strength except for the early age at 3 days, which is higher than SSC but still lower than PSC. From hydration heat analysis, alkalinity in the reaction solution is a vital factor influencing the initial hydration rate and the initial hydration rate from higher to lower is AAS-2, AAS-1, OPC, PSC and SSC. Although AAS possesses a faster reaction rate in the initial hours, cumulative hydration heat of AAS is comparably lower than that of OPC, but higher than those of PSC and SSC in turn, which indicates that the hydration heat of clinkers is much higher than that of slag.DOI: http://dx.doi.org/10.5755/j01.ms.23.1.14934

  5. Gas Hydrates Research Programs: An International Review

    Energy Technology Data Exchange (ETDEWEB)

    Jorge Gabitto; Maria Barrufet

    2009-12-09

    Gas hydrates sediments have the potential of providing a huge amount of natural gas for human use. Hydrate sediments have been found in many different regions where the required temperature and pressure conditions have been satisfied. Resource exploitation is related to the safe dissociation of the gas hydrate sediments. Basic depressurization techniques and thermal stimulation processes have been tried in pilot efforts to exploit the resource. There is a growing interest in gas hydrates all over the world due to the inevitable decline of oil and gas reserves. Many different countries are interested in this valuable resource. Unsurprisingly, developed countries with limited energy resources have taken the lead in worldwide gas hydrates research and exploration. The goal of this research project is to collect information in order to record and evaluate the relative strengths and goals of the different gas hydrates programs throughout the world. A thorough literature search about gas hydrates research activities has been conducted. The main participants in the research effort have been identified and summaries of their past and present activities reported. An evaluation section discussing present and future research activities has also been included.

  6. Electrical properties of methane hydrate + sediment mixtures

    Science.gov (United States)

    Du Frane, Wyatt L.; Stern, Laura A.; Weitemeyer, Karen A.; Constable, Steven; Roberts, Jeffery J.

    2011-01-01

    As part of our DOE-funded proposal to characterize gas hydrate in the Gulf of Mexico using marine electromagnetic methods, a collaboration between SIO, LLNL, and USGS with the goal of measuring the electrical properties of lab-created methane (CH4) hydrate and sediment mixtures was formed. We examined samples with known characteristics to better relate electrical properties measured in the field to specific gas hydrate concentration and distribution patterns. Here we discuss first-ever electrical conductivity (σ) measurements on unmixed CH4 hydrate (Du Frane et al., 2011): 6 x 10-5 S/m at 5 °C, which is ~5 orders of magnitude lower than seawater. This difference allows electromagnetic (EM) techniques to distinguish highly resistive gas hydrate deposits from conductive water saturated sediments in EM field surveys. More recently, we performed measurements on CH4 hydrate mixed with sediment and we also discuss those initial findings here. Our results on samples free of liquid water are important for predicting conductivity of sediments with pores highly saturated with gas hydrate, and are an essential starting point for comprehensive mixing models.

  7. Prospecting for marine gas hydrate resources

    Science.gov (United States)

    Boswell, Ray; Shipp, Craig; Reichel, Thomas; Shelander, Dianna; Saeki, Tetsuo; Frye, Matthew; Shedd, William; Collett, Timothy S.; McConnell, Daniel R.

    2016-01-01

    As gas hydrate energy assessment matures worldwide, emphasis has evolved away from confirmation of the mere presence of gas hydrate to the more complex issue of prospecting for those specific accumulations that are viable resource targets. Gas hydrate exploration now integrates the unique pressure and temperature preconditions for gas hydrate occurrence with those concepts and practices that are the basis for conventional oil and gas exploration. We have aimed to assimilate the lessons learned to date in global gas hydrate exploration to outline a generalized prospecting approach as follows: (1) use existing well and geophysical data to delineate the gas hydrate stability zone (GHSZ), (2) identify and evaluate potential direct indications of hydrate occurrence through evaluation of interval of elevated acoustic velocity and/or seismic events of prospective amplitude and polarity, (3) mitigate geologic risk via regional seismic and stratigraphic facies analysis as well as seismic mapping of amplitude distribution along prospective horizons, and (4) mitigate further prospect risk through assessment of the evidence of gas presence and migration into the GHSZ. Although a wide range of occurrence types might ultimately become viable energy supply options, this approach, which has been tested in only a small number of locations worldwide, has directed prospect evaluation toward those sand-hosted, high-saturation occurrences that were presently considered to have the greatest future commercial potential.

  8. Overview of pressure-drawdown production-test results for the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well

    Energy Technology Data Exchange (ETDEWEB)

    Hancock, S.H.; Carle, D.; Weatherill, B. [APA Petroleum Engineering Ltd., Calgary, AB (Canada); Dallimore, S.R. [Geological Survey of Canada, Pacific Geoscience Centre, Sidney, BC (Canada); Collett, T.S. [United States Geological Survey, Denver, CO (United States); Satoh, T. [Japan Petroleum Exploration Co. Ltd., Tokyo (Japan); Inoue, T. [Japan National Oil Corp., Chiba (Japan)

    2005-07-01

    Schlumberger's Modular Dynamic Tester (MDT) cased hole wireline tool was used during a pressure drawdown production test at the Mallik 5L-38 well to successfully test separate hydrate intervals as well as free gas and water zones. This paper provided an overview of the pressure-drawdown testing operations and results. Preliminary analysis of the gas hydrate porous-media response was also presented. Two important phenomena were observed during the hydrate tests: (1) free gas was produced on a steady state basis following the initial clean-up flow of water, and (2) the pressure response upon shut-in displayed porous media effects and indicated both flow contribution and pressure effects beyond the surface area of the hydrate open to the wellbore. Since analytical pressure transient analysis software cannot incorporate dynamic reservoir parameters, conventional analytical techniques were used to evaluate the test data.

  9. Towards bio-silicon interfaces: formation of an ultra-thin self-hydrated artificial membrane composed of dipalmitoylphosphatidylcholine (DPPC) and chitosan deposited in high vacuum from the gas-phase.

    Science.gov (United States)

    Retamal, María J; Cisternas, Marcelo A; Gutierrez-Maldonado, Sebastian E; Perez-Acle, Tomas; Seifert, Birger; Busch, Mark; Huber, Patrick; Volkmann, Ulrich G

    2014-09-14

    The recent combination of nanoscale developments with biological molecules for biotechnological research has opened a wide field related to the area of biosensors. In the last years, device manufacturing for medical applications adapted the so-called bottom-up approach, from nanostructures to larger devices. Preparation and characterization of artificial biological membranes is a necessary step for the formation of nano-devices or sensors. In this paper, we describe the formation and characterization of a phospholipid bilayer (dipalmitoylphosphatidylcholine, DPPC) on a mattress of a polysaccharide (Chitosan) that keeps the membrane hydrated. The deposition of Chitosan (~25 Å) and DPPC (~60 Å) was performed from the gas phase in high vacuum onto a substrate of Si(100) covered with its native oxide layer. The layer thickness was controlled in situ using Very High Resolution Ellipsometry (VHRE). Raman spectroscopy studies show that neither Chitosan nor DPPC molecules decompose during evaporation. With VHRE and Atomic Force Microscopy we have been able to detect phase transitions in the membrane. The presence of the Chitosan interlayer as a water reservoir is essential for both DPPC bilayer formation and stability, favoring the appearance of phase transitions. Our experiments show that the proposed sample preparation from the gas phase is reproducible and provides a natural environment for the DPPC bilayer. In future work, different Chitosan thicknesses should be studied to achieve a complete and homogeneous interlayer.

  10. Towards bio-silicon interfaces: Formation of an ultra-thin self-hydrated artificial membrane composed of dipalmitoylphosphatidylcholine (DPPC) and chitosan deposited in high vacuum from the gas-phase

    Energy Technology Data Exchange (ETDEWEB)

    Retamal, María J., E-mail: moretama@uc.cl; Cisternas, Marcelo A.; Seifert, Birger; Volkmann, Ulrich G. [Instituto de Física, Pontificia Universidad Católica de Chile, Avda. Vicuña Mackenna 4860, 7820436 Santiago (Chile); Centro de Investigación en Nanotecnología y Materiales Avanzados (CIEN-UC), Pontificia Universidad Católica de Chile, Avda. Vicuña Mackenna 4860, 7820436 Santiago (Chile); Gutierrez-Maldonado, Sebastian E.; Perez-Acle, Tomas [Computational Biology Lab (DLab), Fundación Ciencia y Vida, Av. Zañartu 1482, Santiago (Chile); Centro Interdisciplinario de Neurociencias de Valparaiso (CINV), Universidad de Valparaiso, Pasaje Harrington 287, Valparaiso (Chile); Busch, Mark; Huber, Patrick [Institute of Materials Physics and Technology, Hamburg University of Technology (TUHH), D-21073 Hamburg-Harburg (Germany)

    2014-09-14

    The recent combination of nanoscale developments with biological molecules for biotechnological research has opened a wide field related to the area of biosensors. In the last years, device manufacturing for medical applications adapted the so-called bottom-up approach, from nanostructures to larger devices. Preparation and characterization of artificial biological membranes is a necessary step for the formation of nano-devices or sensors. In this paper, we describe the formation and characterization of a phospholipid bilayer (dipalmitoylphosphatidylcholine, DPPC) on a mattress of a polysaccharide (Chitosan) that keeps the membrane hydrated. The deposition of Chitosan (∼25 Å) and DPPC (∼60 Å) was performed from the gas phase in high vacuum onto a substrate of Si(100) covered with its native oxide layer. The layer thickness was controlled in situ using Very High Resolution Ellipsometry (VHRE). Raman spectroscopy studies show that neither Chitosan nor DPPC molecules decompose during evaporation. With VHRE and Atomic Force Microscopy we have been able to detect phase transitions in the membrane. The presence of the Chitosan interlayer as a water reservoir is essential for both DPPC bilayer formation and stability, favoring the appearance of phase transitions. Our experiments show that the proposed sample preparation from the gas phase is reproducible and provides a natural environment for the DPPC bilayer. In future work, different Chitosan thicknesses should be studied to achieve a complete and homogeneous interlayer.

  11. APPLICATION OF INTEGRATED RESERVOIR MANAGEMENT AND RESERVOIR CHARACTERIZATION

    Energy Technology Data Exchange (ETDEWEB)

    Jack Bergeron; Tom Blasingame; Louis Doublet; Mohan Kelkar; George Freeman; Jeff Callard; David Moore; David Davies; Richard Vessell; Brian Pregger; Bill Dixon; Bryce Bezant

    2000-03-01

    Reservoir performance and characterization are vital parameters during the development phase of a project. Infill drilling of wells on a uniform spacing, without regard to characterization does not optimize development because it fails to account for the complex nature of reservoir heterogeneities present in many low permeability reservoirs, especially carbonate reservoirs. These reservoirs are typically characterized by: (1) large, discontinuous pay intervals; (2) vertical and lateral changes in reservoir properties; (3) low reservoir energy; (4) high residual oil saturation; and (5) low recovery efficiency. The operational problems they encounter in these types of reservoirs include: (1) poor or inadequate completions and stimulations; (2) early water breakthrough; (3) poor reservoir sweep efficiency in contacting oil throughout the reservoir as well as in the nearby well regions; (4) channeling of injected fluids due to preferential fracturing caused by excessive injection rates; and (5) limited data availability and poor data quality. Infill drilling operations only need target areas of the reservoir which will be economically successful. If the most productive areas of a reservoir can be accurately identified by combining the results of geological, petrophysical, reservoir performance, and pressure transient analyses, then this ''integrated'' approach can be used to optimize reservoir performance during secondary and tertiary recovery operations without resorting to ''blanket'' infill drilling methods. New and emerging technologies such as geostatistical modeling, rock typing, and rigorous decline type curve analysis can be used to quantify reservoir quality and the degree of interwell communication. These results can then be used to develop a 3-D simulation model for prediction of infill locations. The application of reservoir surveillance techniques to identify additional reservoir ''pay'' zones

  12. Geomechanical, Hydraulic and Thermal Characteristics of Deep Oceanic Sandy Sediments Recovered during the Second Ulleung Basin Gas Hydrate Expedition

    Directory of Open Access Journals (Sweden)

    Yohan Cha

    2016-09-01

    Full Text Available This study investigates the geomechanical, hydraulic and thermal characteristics of natural sandy sediments collected during the Ulleung Basin gas hydrate expedition 2, East Sea, offshore Korea. The studied sediment formation is considered as a potential target reservoir for natural gas production. The sediments contained silt, clay and sand fractions of 21%, 1.3% and 77.7%, respectively, as well as diatomaceous minerals with internal pores. The peak friction angle and critical state (or residual state friction angle under drained conditions were ~26° and ~22°, respectively. There was minimal or no apparent cohesion intercept. Stress- and strain-dependent elastic moduli, such as tangential modulus and secant modulus, were identified. The sediment stiffness increased with increasing confining stress, but degraded with increasing strain regime. Variations in water permeability with water saturation were obtained by fitting experimental matric suction-water saturation data to the Maulem-van Genuchen model. A significant reduction in thermal conductivity (from ~1.4–1.6 to ~0.5–0.7 W·m−1·K−1 was observed when water saturation decreased from 100% to ~10%–20%. In addition, the electrical resistance increased quasi-linearly with decreasing water saturation. The geomechanical, hydraulic and thermal properties of the hydrate-free sediments reported herein can be used as the baseline when predicting properties and behavior of the sediments containing hydrates, and when the hydrates dissociate during gas production. The variations in thermal and hydraulic properties with changing water and gas saturation can be used to assess gas production rates from hydrate-bearing deposits. In addition, while depressurization of hydrate-bearing sediments inevitably causes deformation of sediments under drained conditions, the obtained strength and stiffness properties and stress-strain responses of the sedimentary formation under drained loading conditions

  13. Assessing fluid-gas expulsion geology and gas hydrate deposits across the Gulf of Mexico with multicomponent and multifrequency seismic data

    Energy Technology Data Exchange (ETDEWEB)

    Hardage, B.A.; Sava, D.C.; Murray, P.E.; DeAngelo, M.V.; Backus, M.M.; Graebner, R.J. [Texas Univ., Austin, TX (United States). Bureau of Economic Geology; Roberts, H.H. [Louisiana State Univ., Baton Rouge, LA (United States). Coastal Studies Inst.

    2008-07-01

    This paper reported on a study of 2 fluid-gas expulsion sites across a portion of the Green Canyon area of the Gulf of Mexico, where deep-water fields and oil and gas seeps are numerous. Hydrates are pervasive across the 2 expulsion sites studied at Typhoon and Genesis Fields. The 2 sites GD 237 and GC 204 are positioned on the flank of an intraslope basin containing a thick sedimentary sequence. Major fluid-gas migration pathways occur near the edges of shallow subsurface salt masses. The two-fluid gas expulsion sites were investigated with 4-component ocean-bottom-cable (4C OBC) seismic data and chirp-sonar data acquired by an autonomous underwater vehicle (AUV). The study examined the near-seafloor geology of the deep-water, fluid-gas expulsion features to estimate hydrate concentrations in strata spanned by the hydrate stability zone local to these expulsion sites. In some units, hydrate concentrations were more than 30 per cent of the available pore space of the host sediment. A free-gas layer was discovered immediately under the base of the hydrate stability zone across each expulsion site area. It was revealed by a reduction in V{sub p} velocity. Although the amount of free-gas in this zone has not been estimated, it is expected that the zone has a gas saturation of only a few percentage points. This free-gas zone was not obviously different from hydrate-bearing zones when examining resistivity logs. It was concluded that interpreting the thickness of a hydrate stability zone from resistivity logs alone could result in an overestimation of the thickness of the hydrate stability zone and the amount of hydrate that exists near deep-water expulsion features. 10 refs., 13 figs.

  14. Gas hydrates and permafrost in continental northern West Siberia; Gashydrate und Permafrost im kontinentalen noerdlichen Westsibirien

    Energy Technology Data Exchange (ETDEWEB)

    Cramer, B. [Bundesanstalt fuer Geowissenschaften und Rohstoffe, Hannover (Germany); Braun, A.; Poelchau, H.S. [Forschungszentrum Juelich (Germany). Inst. fuer Erdoel und Organische Geochemie; Littke, R. [RWTH Aachen (Germany). Lehrstuhl fuer Geologie, Geochemie und Lagerstaetten des Erdoels und der Kohle

    1997-12-31

    The largest natural gas pool in the world is located in northern part of the West Siberian Basin. During the Quaternary this reservoir became overlaid with several hundreds of metres of permafrost. The pressure and temperature conditions prevailing under this permafrost zone have led to the development of gas hydrates. As far as is known today there is no genetic relationship between the formation of the gas pool and the development of gas hydrates. The present contribution deals with these questions in detail. (MSK) [Deutsch] Im Nordteil des westsibirischen Beckens liegt die groesste Erdgaslagerstaette der Erde. Darueber hat sich im Quartaer ein mehrere hundert Meter maechtiger Permafrost gebildet. Die unter der Premafrostzone herrschenden Druck-und Temperaturbedingungen ermoeglichten die Bildung von Gashydraten. Nach heutigen Erkenntnisse besteht kein genetischer Zusammenhang zwischen Lagerstaettenbildung und Gashydraten. Im Folgenden werden Einzelheiten geschildert.

  15. Aspects of Hydrate Management - Deposition Phenomena

    OpenAIRE

    Langen, Heidi

    2016-01-01

    The purpose of this thesis has been to investigate the factors with the largest influence on the adhesion strength of a hydrate deposit on a solid surface. This has been done through a literature study on the subject, and a thorough experimental project in a laboratory. The experiments involved forming hydrate deposits on a pipe of steel, before removing the deposits and finding the pressure required to do so. The hydrate was formed by a solution of tetrahydrofuran and water in a tank where t...

  16. Gasbuggy reservoir evaluation - 1969 report

    International Nuclear Information System (INIS)

    Atkinson, C.H.; Ward, Don C.; Lemon, R.F.

    1970-01-01

    The December 10, 1967, Project Gasbuggy nuclear detonation followed the drilling and testing of two exploratory wells which confirmed reservoir characteristics and suitability of the site. Reentry and gas production testing of the explosive emplacement hole indicated a collapse chimney about 150 feet in diameter extending from the 4,240-foot detonation depth to about 3,900 feet, the top of the 300-foot-thick Pictured Cliffs gas sand. Production tests of the chimney well in the summer of 1968 and during the last 12 months have resulted in a cumulative production of 213 million cubic feet of hydrocarbons, and gas recovery in 20 years is estimated to be 900 million cubic feet, which would be an increase by a factor of at least 5 over estimated recovery from conventional field wells in this low permeability area. At the end of production tests the flow rate was 160,000 cubic feet per day, which is 6 to 7 times that of an average field well in the area. Data from reentry of a pre-shot test well and a new postshot well at distances from the detonation of 300 and 250 feet, respectively, indicate low productivity and consequently low permeability in any fractures at these locations. (author)

  17. Methane hydrate morphology of natural hydrate-bearing sediment from Nankai trough, Japan

    Science.gov (United States)

    Konno, Y.; Jin, Y.; Yoneda, J.; Kida, M.; Nagao, J.

    2016-12-01

    As a part of MH21, the Research Consortium for Methane Hydrate Resources in Japan, who initiated Japan's Methane Hydrate R&D Program (managed by the Ministry of Economy, Trade, and Industry (METI)), we developed newly pressured hydrate sediment analyzing apparatus (Pressured Non-destructive Analysis Tools, here after PNATs) including an X-ray computed-tomography (CT) system, gamma-ray density measurement system, an instrumented pressure testing chamber (IPTC). The Japanese IPTC was developed with strong cooperation from Georgia Tech and the U.S. Geological Survey. In this study, we investigated the hydrate morphology in natural gas hydrate-bearing (GH) sediment recovered from eastern Nankai trough area under hydro-pressurized condition using PNATs. In addition to P-wave measurement via the IPTC, we assessed hydrate saturation Sh in sediment sample by using our newly ATR-IR probe for the IPTC. Our analysis reveals that the pressurized sample shows load-bearing GH sediment.

  18. Hydration and nutrition knowledge in adolescent swimmers. Does water intake affect urine hydration markers after swimming?

    OpenAIRE

    Cesare Altavilla; Maria Soledad Prats Moya; Pablo Caballero Pérez

    2017-01-01

    Little data exists regarding nutritional knowledge and hydration in adolescent swimmers. The aim of this study was to assess the level of nutrition and hydration knowledge and to describe the fluid balance in adolescent swimmers during training. A study was carried out with a cross-sectional descriptive part and a longitudinal part with repeated measurements over five swimming sessions. Eighty-six adolescent swimmers completed a questionnaire to assess their sport nutrition and hydration know...

  19. Experimental investigation of smectite hydration from the simulation of 001 X-ray diffraction lines. Implications for the characterization of mineralogical modifications of the 'argilite' from the Meuse - Haute Marne site as a result of a thermal perturbation

    International Nuclear Information System (INIS)

    Ferrage, E.

    2004-10-01

    The structural modifications affecting the reactive mineral constituents of the clay barriers (smectite) and possibly resulting from the thermal pulse related to nuclear waste storage are essentially limited to the amount and location of the layer charge deficit. These modifications likely impact the hydration properties of these minerals, and a specific methodology has thus been developed to describe, using simulation of X-ray diffraction profiles (001 reflections), these hydration properties and specifically the heterogeneity resulting from the inter-stratification of different layer types, each exhibiting a specific hydration state. The detailed study of the hydration properties of a low-charge montmorillonite (octahedral charge) has shown that the affinity of the interlayer cation for water rules the hydration state and the thickness of hydrated smectite layers. If the layer charge is increased, the transition between the different hydration states is shifted, following a water desorption isotherm, towards lower relative humidities. In addition, the hydration of studied beidellites (tetrahedral charge) was shown to be more heterogeneous than that of montmorillonites. The developed methodology also allowed describing the structural modifications resulting from a chemical perturbation (chlorinated anionic background, pH). Finally, the link between the thickness of elementary layers and the amount of interlayer water molecules has been evidenced. A new structure model has also been determined for these interlayer species allowing an improved description of their positional distribution in bi-hydrated interlayers. (author)

  20. Experimental Investigation of Effect on Hydrate Formation in Spray Reactor

    Directory of Open Access Journals (Sweden)

    Jianzhong Zhao

    2015-01-01

    Full Text Available The effects of reaction condition on hydrate formation were conducted in spray reactor. The temperature, pressure, and gas volume of reaction on hydrate formation were measured in pure water and SDS solutions at different temperature and pressure with a high-pressure experimental rig for hydrate formation. The experimental data and result reveal that additives could improve the hydrate formation rate and gas storage capacity. Temperature and pressure can restrict the hydrate formation. Lower temperature and higher pressure can promote hydrate formation, but they can increase production cost. So these factors should be considered synthetically. The investigation will promote the advance of gas storage technology in hydrates.

  1. Work reservoirs in thermodynamics

    Science.gov (United States)

    Anacleto, Joaquim

    2010-05-01

    We stress the usefulness of the work reservoir in the formalism of thermodynamics, in particular in the context of the first law. To elucidate its usefulness, the formalism is then applied to the Joule expansion and other peculiar and instructive experimental situations, clarifying the concepts of configuration and dissipative work. The ideas and discussions presented in this study are primarily intended for undergraduate students, but they might also be useful to graduate students, researchers and teachers.

  2. Loess Thickness Variations Across the Loess Plateau of China

    Science.gov (United States)

    Zhu, Yuanjun; Jia, Xiaoxu; Shao, Mingan

    2018-01-01

    The soil thickness is very important for investigating and modeling soil-water processes, especially on the Loess Plateau of China with its deep loess deposit and limited water resources. A digital elevation map (DEM) of the Loess Plateau and neighborhood analysis in ArcGIS software were used to generate a map of loess thickness, which was then validated by 162 observations across the plateau. The generated loess thickness map has a high resolution of 100 m × 100 m. The map indicates that loess is thick in the central part of the plateau and becomes gradually shallower in the southeast and northwest directions. The areas near mountains and river basins have the shallowest loess deposit. The mean loess thickness is the deepest in the zones with 400-600-mm precipitation and decreases gradually as precipitation varies beyond this range. Our validation indicates that the map just slightly overestimates loess thickness and is reliable. The loess thickness is mostly between 0 and 350 m in the Loess Plateau region. The calculated mean loess thickness is 105.7 m, with the calibrated value being 92.2 m over the plateau exclusive of the mountain areas. Our findings provide very basic data of loess thickness and demonstrate great progress in mapping the loess thickness distribution for the plateau, which are valuable for a better study of soil-water processes and for more accurate estimations of soil water, carbon, and solute reservoirs in the Loess Plateau of China.

  3. Exogenous origin of hydration on asteroid (16) Psyche: the role of hydrated asteroid families

    Science.gov (United States)

    Avdellidou, C.; Delbo', M.; Fienga, A.

    2018-04-01

    Asteroid (16) Psyche, which for a long time was the largest M-type with no detection of hydration features in its spectrum, was recently discovered to have a weak 3-μm band and thus it was eventually added to the group of hydrated asteroids. Its relatively high density, in combination with the high radar albedo, led researchers to classify the asteroid as a metallic object. It is believed that it is possibly a core of a differentiated body, a remnant of `hit-and-run' collisions. The detection of hydration is, in principle, inconsistent with a pure metallic origin for this body. Here, we consider the scenario in which the hydration on its surface is exogenous and was delivered by hydrated impactors. We show that impacting asteroids that belong to families whose members have the 3-μm band can deliver hydrated material to Psyche. We developed a collisional model with which we test all dark carbonaceous asteroid families, which contain hydrated members. We find that the major source of hydrated impactors is the family of Themis, with a total implanted mass on Psyche of the order of ˜1014 kg. However, the hydrated fraction could be only a few per cent of the implanted mass, as the water content in carbonaceous chondrite meteorites, the best analogue for the Themis asteroid family, is typically a few per cent of their mass.

  4. Separation of water through gas hydrate formation

    DEFF Research Database (Denmark)

    Boch Andersen, Torben; Thomsen, Kaj

    2009-01-01

    Gas hydrate is normally recognized as a troublemaker in the oil and gas industry. However, gas hydrate has some interesting possibilities when used in connection with separation of water. Nordic Sugar has investigated the possibility of using gas hydrates for concentration of sugar juice. The goal...... of the project was to formulate an alternative separation concept, which can replace the traditional water evaporation process in the sugar production. Work with the separation concept showed that gas hydrates can be used for water separation. The process is not suitable for sugar production because of large...... volumes and the needs for high pressure. The process could be interesting for concentration of heat sensitive, high value products...

  5. Proton NMR relaxation of hydrated insulin powder

    International Nuclear Information System (INIS)

    Sanches, R.; Donoso, J.P.; Mascarenhas, S.; Panepucci, H.C.

    1985-01-01

    Water proton nuclear magnetic relaxation measurements were obtained for hydrated insulin powder as a function of the water content. For samples containing enough water to complete the hydration shell, the data for the spin-lattice and spin-spin relaxation times are consistent with a model in which water molecules exist in two phases, one exhibiting restricted motion and identified with water of hydration and another identified as free water with motions similar to ordinary water. For samples containing only water of hydration, a model for the spin-spin relaxation time is discussed, in which the water molecules relaxation is described in terms for four relaxation times. Estimates are obtained for these relaxation times, in good agreement with the experimental data. (Author) [pt

  6. Polyethylene oxide hydration in grafted layers

    Science.gov (United States)

    Dormidontova, Elena; Wang, Zilu

    Hydration of water soluble polymers is one of the key-factors defining their conformation and properties, similar to biopolymers. Polyethylene oxide (PEO) is one of the most important biomedical-applications polymers and is known for its reverse temperature solubility due to hydrogen bonding with water. As in many practical applications PEO chains are grafted to surfaces, e.g. of nanoparticles or planar surfaces, it is important to understand PEO hydration in such grafted layers. Using atomistic molecular dynamic simulations we investigate the details of molecular conformation and hydration of PEO end-grafted to gold surfaces. We analyze polymer and water density distribution as a function of distance from the surface for different grafting densities. Based on a detailed analysis of hydrogen bonding between polymer and water in grafted PEO layers, we will discuss the extent of PEO hydration and its implication for polymer conformation, mobility and layer properties. This research is supported by NSF (DMR-1410928).

  7. ConocoPhillips Gas Hydrate Production Test

    Energy Technology Data Exchange (ETDEWEB)

    Schoderbek, David [ConocoPhillips Co., Houston, TX (United States); Farrell, Helen [ConocoPhillips Co., Houston, TX (United States); Howard, James [ConocoPhillips Co., Houston, TX (United States); Raterman, Kevin [ConocoPhillips Co., Houston, TX (United States); Silpngarmlert, Suntichai [ConocoPhillips Co., Houston, TX (United States); Martin, Kenneth [ConocoPhillips Co., Houston, TX (United States); Smith, Bruce [ConocoPhillips Co., Houston, TX (United States); Klein, Perry [ConocoPhillips Co., Houston, TX (United States)

    2013-06-30

    Work began on the ConocoPhillips Gas Hydrates Production Test (DOE award number DE-NT0006553) on October 1, 2008. This final report summarizes the entire project from January 1, 2011 to June 30, 2013.

  8. Vibrational dynamics of hydration water in amylose

    CERN Document Server

    Cavatorta, F; Albanese, G; Angelini, N

    2002-01-01

    We present a study of the dynamical properties of hydration water associated with amylose helices, based on low-temperature vibrational spectra collected using the TOSCA inelastic spectrometer at ISIS. The structural constraints of the polysaccharidic chains favour the formation of a high-density structure for water, which has been suggested by Imberty and Perez on the basis of conformational analysis. According to this model, hydration water can only enter the pores formed by six adjacent helices and completely fills the pores at a hydration level of about 0.27-g water/g dry amylose. Our measurements show that the dynamical behaviour of hydration water is similar to that observed in high-density amorphous ice. (orig.)

  9. Hydration states of AFm cement phases

    Energy Technology Data Exchange (ETDEWEB)

    Baquerizo, Luis G., E-mail: luis.baquerizoibarra@holcim.com [Innovation, Holcim Technology Ltd., CH-5113 Holderbank (Switzerland); Matschei, Thomas [Innovation, Holcim Technology Ltd., CH-5113 Holderbank (Switzerland); Scrivener, Karen L. [Laboratory of Construction Materials, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland); Saeidpour, Mahsa; Wadsö, Lars [Building Materials, Lund University, Box 124, 221 000 Lund (Sweden)

    2015-07-15

    The AFm phase, one of the main products formed during the hydration of Portland and calcium aluminate cement based systems, belongs to the layered double hydrate (LDH) family having positively charged layers and water plus charge-balancing anions in the interlayer. It is known that these phases present different hydration states (i.e. varying water content) depending on the relative humidity (RH), temperature and anion type, which might be linked to volume changes (swelling and shrinkage). Unfortunately the stability conditions of these phases are insufficiently reported. This paper presents novel experimental results on the different hydration states of the most important AFm phases: monocarboaluminate, hemicarboaluminate, strätlingite, hydroxy-AFm and monosulfoaluminate, and the thermodynamic properties associated with changes in their water content during absorption/desorption. This data opens the possibility to model the response of cementitious systems during drying and wetting and to engineer systems more resistant to harsh external conditions.

  10. Hydrate Control for Gas Storage Operations

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey Savidge

    2008-10-31

    The overall objective of this project was to identify low cost hydrate control options to help mitigate and solve hydrate problems that occur in moderate and high pressure natural gas storage field operations. The study includes data on a number of flow configurations, fluids and control options that are common in natural gas storage field flow lines. The final phase of this work brings together data and experience from the hydrate flow test facility and multiple field and operator sources. It includes a compilation of basic information on operating conditions as well as candidate field separation options. Lastly the work is integrated with the work with the initial work to provide a comprehensive view of gas storage field hydrate control for field operations and storage field personnel.

  11. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    Energy Technology Data Exchange (ETDEWEB)

    Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling

  12. Spectroscopic methods in gas hydrate research.

    Science.gov (United States)

    Rauh, Florian; Mizaikoff, Boris

    2012-01-01

    Gas hydrates are crystalline structures comprising a guest molecule surrounded by a water cage, and are particularly relevant due to their natural occurrence in the deep sea and in permafrost areas. Low molecular weight molecules such as methane and carbon dioxide can be sequestered into that cage at suitable temperatures and pressures, facilitating the transition to the solid phase. While the composition and structure of gas hydrates appear to be well understood, their formation and dissociation mechanisms, along with the dynamics and kinetics associated with those processes, remain ambiguous. In order to take advantage of gas hydrates as an energy resource (e.g., methane hydrate), as a sequestration matrix in (for example) CO(2) storage, or for chemical energy conservation/storage, a more detailed molecular level understanding of their formation and dissociation processes, as well as the chemical, physical, and biological parameters that affect these processes, is required. Spectroscopic techniques appear to be most suitable for analyzing the structures of gas hydrates (sometimes in situ), thus providing access to such information across the electromagnetic spectrum. A variety of spectroscopic methods are currently used in gas hydrate research to determine the composition, structure, cage occupancy, guest molecule position, and binding/formation/dissociation mechanisms of the hydrate. To date, the most commonly applied techniques are Raman spectroscopy and solid-state nuclear magnetic resonance (NMR) spectroscopy. Diffraction methods such as neutron and X-ray diffraction are used to determine gas hydrate structures, and to study lattice expansions. Furthermore, UV-vis spectroscopic techniques and scanning electron microscopy (SEM) have assisted in structural studies of gas hydrates. Most recently, waveguide-coupled mid-infrared spectroscopy in the 3-20 μm spectral range has demonstrated its value for in situ studies on the formation and dissociation of gas

  13. Architecture of an Upper Jurassic barrier island sandstone reservoir, Danish Central Graben:

    DEFF Research Database (Denmark)

    Johannessen, Peter N.; Nielsen, Lars H.; Nielsen, Lars

    2010-01-01

    An unusually thick (c. 88 m), transgressive barrier island and shoreface sandstone succession characterizes the Upper Jurassic Heno Formation reservoir of the Freja oil field situated on the boundary of Denmark and Norway. The development and preservation of such thick transgressive barrier islan...

  14. Advantageous Reservoir Characterization Technology in Extra Low Permeability Oil Reservoirs

    Directory of Open Access Journals (Sweden)

    Yutian Luo

    2017-01-01

    Full Text Available This paper took extra low permeability reservoirs in Dagang Liujianfang Oilfield as an example and analyzed different types of microscopic pore structures by SEM, casting thin sections fluorescence microscope, and so on. With adoption of rate-controlled mercury penetration, NMR, and some other advanced techniques, based on evaluation parameters, namely, throat radius, volume percentage of mobile fluid, start-up pressure gradient, and clay content, the classification and assessment method of extra low permeability reservoirs was improved and the parameter boundaries of the advantageous reservoirs were established. The physical properties of reservoirs with different depth are different. Clay mineral variation range is 7.0%, and throat radius variation range is 1.81 μm, and start pressure gradient range is 0.23 MPa/m, and movable fluid percentage change range is 17.4%. The class IV reservoirs account for 9.56%, class II reservoirs account for 12.16%, and class III reservoirs account for 78.29%. According to the comparison of different development methods, class II reservoir is most suitable for waterflooding development, and class IV reservoir is most suitable for gas injection development. Taking into account the gas injection in the upper section of the reservoir, the next section of water injection development will achieve the best results.

  15. Supramolecular Organization of Nonstoichiometric Drug Hydrates: Dapsone

    Directory of Open Access Journals (Sweden)

    Doris E. Braun

    2018-02-01

    Full Text Available The observed moisture- and temperature dependent transformations of the dapsone (4,4′-diaminodiphenyl sulfone, DDS 0. 33-hydrate were correlated to its structure and the number and strength of the water-DDS intermolecular interactions. A combination of characterization techniques was used, including thermal analysis (hot-stage microscopy, differential scanning calorimetry and thermogravimetric analysis, gravimetric moisture sorption/desorption studies and variable humidity powder X-ray diffraction, along with computational modeling (crystal structure prediction and pair-wise intermolecular energy calculations. Depending on the relative humidity the hydrate contains between 0 and 0.33 molecules of water per molecule DDS. The crystal structure is retained upon dehydration indicating that DDS hydrate shows a non-stoichiometric (dehydration behavior. Unexpectedly, the water molecules are not located in structural channels but at isolated-sites of the host framework, which is counterintuitively for a hydrate with non-stoichiometric behavior. The water-DDS interactions were estimated to be weaker than water-host interactions that are commonly observed in stoichiometric hydrates and the lattice energies of the isomorphic dehydration product (hydrate structure without water molecules and (form III differ only by ~1 kJ mol−1. The computational generation of hypothetical monohydrates confirms that the hydrate with the unusual DDS:water ratio of 3:1 is more stable than a feasible monohydrate structure. Overall, this study highlights that a deeper understanding of the formation of hydrates with non-stoichiometric behavior requires a multidisciplinary approach including suitable experimental and computational methods providing a firm basis for the development and manufacturing of high quality drug products.

  16. Hydrate Shell Growth Measured Using NMR.

    Science.gov (United States)

    Haber, Agnes; Akhfash, Masoumeh; Loh, Charles K; Aman, Zachary M; Fridjonsson, Einar O; May, Eric F; Johns, Michael L

    2015-08-18

    Benchtop nuclear magnetic resonance (NMR) pulsed field gradient (PFG) and relaxation measurements were used to monitor the clathrate hydrate shell growth occurring in water droplets dispersed in a continuous cyclopentane phase. These techniques allowed the growth of hydrate inside the opaque exterior shell to be monitored and, hence, information about the evolution of the shell's morphology to be deduced. NMR relaxation measurements were primarily used to monitor the hydrate shell growth kinetics, while PFG NMR diffusion experiments were used to determine the nominal droplet size distribution (DSD) of the unconverted water inside the shell core. A comparison of mean droplet sizes obtained directly via PFG NMR and independently deduced from relaxation measurements showed that the assumption of the shell model-a perfect spherical core of unconverted water-for these hydrate droplet systems is correct, but only after approximately 24 h of shell growth. Initially, hydrate growth is faster and heat-transfer-limited, leading to porous shells with surface areas larger than that of spheres with equivalent volumes. Subsequently, the hydrate growth rate becomes mass-transfer-limited, and the shells become thicker, spherical, and less porous.

  17. Raman spectroscopic measurements on fluoromethane clathrate hydrates

    Energy Technology Data Exchange (ETDEWEB)

    Uchida, T. [Hokkaido Univ., Sapporo (Japan). Graduate School of Engineering, Div. of Applied Physics; Ohmura, R. [Keio Univ., Kohoku-ku, Yokohama (Japan). Dept. of Mechanical Engineering; Hori, A. [Kitami Inst. of Technology, Kitami (Japan). Course of Civil Engineering

    2008-07-01

    The occupation of guest molecules in clathrate-structure cages is of interest to researchers, since this property is involved in the estimation of guest molecule density, the stability of clathrate hydrates, and other features. However, such occupation is known to be non-stoichiometric. It remains difficult to accurately estimate the total amount of natural gases in the hydrates located in the deep ocean or in permafrost. This paper discussed the systematic observations of fluoromethane clathrate hydrates using Raman spectroscopy in conjunction with previously obtained Raman spectra for methane (CH{sub 4}) hydrate. Four types of fluoromethane were utilized as standard guest molecules to investigate cage occupation in the hydrates, as all of them were included in the same crystal structure and shared similar functional groups. The types of fluoromethane that were used included fluoromethane (CH{sub 3}F), difluoromethane (CH{sub 2}F{sub 2}), trifluoromethane (CHF{sub 3}), and tetrafluoromethane (CF{sub 4}). The paper discussed the experimental methods including the temperature and pressure conditions of fluorocarbon hydrate formation. It was concluded that the summary of the Raman peak positions of fluoromethane molecules indicate that the influence of deuterized host molecules on the intramolecular vibration frequencies is less than that suggested by experimental error. The obtained data were confirmed to agree with the empirical model for the Raman peak positions on guest molecules, when the relative position of the guest molecule in a host cage structure is considered. 28 refs., 1 tab., 7 figs.

  18. Electrical properties of polycrystalline methane hydrate

    Science.gov (United States)

    Du Frane, W. L.; Stern, L.A.; Weitemeyer, K.A.; Constable, S.; Pinkston, J.C.; Roberts, J.J.

    2011-01-01

    Electromagnetic (EM) remote-sensing techniques are demonstrated to be sensitive to gas hydrate concentration and distribution and complement other resource assessment techniques, particularly seismic methods. To fully utilize EM results requires knowledge of the electrical properties of individual phases and mixing relations, yet little is known about the electrical properties of gas hydrates. We developed a pressure cell to synthesize gas hydrate while simultaneously measuring in situ frequency-dependent electrical conductivity (σ). Synthesis of methane (CH4) hydrate was verified by thermal monitoring and by post run cryogenic scanning electron microscope imaging. Impedance spectra (20 Hz to 2 MHz) were collected before and after synthesis of polycrystalline CH4 hydrate from polycrystalline ice and used to calculate σ. We determined the σ of CH4 hydrate to be 5 × 10−5 S/m at 0°C with activation energy (Ea) of 30.6 kJ/mol (−15 to 15°C). After dissociation back into ice, σ measurements of samples increased by a factor of ~4 and Ea increased by ~50%, similar to the starting ice samples.

  19. CHARACTERIZING NATURAL GAS HYDRATES IN THE DEEP WATER GULF OF MEXICO: APPLICATIONS FOR SAFE EXPLORATION AND PRODUCTION ACTIVITIES

    Energy Technology Data Exchange (ETDEWEB)

    Steve Holditch; Emrys Jones

    2003-01-01

    In 2000, Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deepwater portions of the Gulf of Mexico. A Joint Industry Participation (JIP) group was formed in 2001, and a project partially funded by the U.S. Department of Energy (DOE) began in October 2001. The primary objective of this project is to develop technology and data to assist in the characterization of naturally occurring gas hydrates in the deep water Gulf of Mexico (GOM). These naturally occurring gas hydrates can cause problems relating to drilling and production of oil and gas, as well as building and operating pipelines. Other objectives of this project are to better understand how natural gas hydrates can affect seafloor stability, to gather data that can be used to study climate change, and to determine how the results of this project can be used to assess if and how gas hydrates act as a trapping mechanism for shallow oil or gas reservoirs. During April-September 2002, the JIP concentrated on: Reviewing the tasks and subtasks on the basis of the information generated during the three workshops held in March and May 2002; Writing Requests for Proposals (RFPs) and Cost, Time and Resource (CTRs) estimates to accomplish the tasks and subtasks; Reviewing proposals sent in by prospective contractors; Selecting four contractors; Selecting six sites for detailed review; and Talking to drill ship owners and operators about potential work with the JIP.

  20. CHARACTERIZING NATURAL GAS HYDRATES IN THE DEEP WATER GULF OF MEXICO: APPLICATIONS FOR SAFE EXPLORATION AND PRODUCTION ACTIVITIES

    Energy Technology Data Exchange (ETDEWEB)

    Steve Holditch; Emrys Jones

    2003-01-01

    In 2000, Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deepwater portions of the Gulf of Mexico. A Joint Industry Participation (JIP) group was formed in 2001, and a project partially funded by the U.S. Department of Energy (DOE) began in October 2001. The primary objective of this project is to develop technology and data to assist in the characterization of naturally occurring gas hydrates in the deep water Gulf of Mexico (GOM). These naturally occurring gas hydrates can cause problems relating to drilling and production of oil and gas, as well as building and operating pipelines. Other objectives of this project are to better understand how natural gas hydrates can affect seafloor stability, to gather data that can be used to study climate change, and to determine how the results of this project can be used to assess if and how gas hydrates act as a trapping mechanism for shallow oil or gas reservoirs. During the first six months of operation, the primary activities of the JIP were to conduct and plan Workshops, which were as follows: (1) Data Collection Workshop--March 2002 (2) Drilling, Coring and Core Analyses Workshop--May 2002 (3) Modeling, Measurement and Sensors Workshop--May 2002.

  1. The transformation of uranyl oxide hydrates: The effect of dehydration on synthetic metaschoepite and its alteration to becquerelite

    International Nuclear Information System (INIS)

    Sowder, A.G.; Clark, S.B.; Fjeld, R.A.

    1999-01-01

    The U(VI) solid phases schoepite, metaschoepite, and dehydrated schoepite are important reservoirs of mobile uranium in the environment. These simple uranyl oxide hydrates result from weathering of uranium minerals and the corrosion of anthropogenic uranium solids. The authors have studied the role of hydrational water among these phases and in subsequent transformation to other secondary metal-U(VI) oxide hydrates. Synthetic metaschoepite (MS, UO 3 ·2.0H 2 O), its dehydrated phases, and its secondary alteration products were characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS), and high-resolution thermogravimetric analysis (HRTGA). Drying MS at 105 C resulted in the formation of a dehydrated phase (UO 3 ·0.9H 2 O) that was structurally distinct from natural dehydrated schoepite (DS, UO 3 ·0.75H 2 O) reported by others. Unlike natural DS, their dehydrated material was easily rehydrated, although crystallinity of the rehydrated phase was reduced. The rates of transformation of synthetic MS and dehydrated MS in the presence of Ca 2+ to form becquerelite (Ca[(UO 2 ) 6 O 4 (OH) 6 ]·8H 2 O) were determined. Alteration rates were significantly faster when the starting material had been dehydrated. These results are explained in the context of structural aspects of U(VI) solid phases, and the possible impact of hydration on long-term stability of U(VI) oxide hydrates in environmental systems is discussed

  2. Hydration during intense exercise training.

    Science.gov (United States)

    Maughan, R J; Meyer, N L

    2013-01-01

    Hydration status has profound effects on both physical and mental performance, and sports performance is thus critically affected. Both overhydration and underhydration - if sufficiently severe - will impair performance and pose a risk to health. Athletes may begin exercise in a hypohydrated state as a result of incomplete recovery from water loss induced in order to achieve a specific body mass target or due to incomplete recovery from a previous competition or training session. Dehydration will also develop in endurance exercise where fluid intake does not match water loss. The focus has generally been on training rather than on competition, but sweat loss and fluid replacement in training may have important implications. Hypohydration may impair training quality and may also increase stress levels. It is unclear whether this will have negative effects (reduced training quality, impaired immunity) or whether it will promote a greater adaptive response. Hypohydration and the consequent hyperthermia, however, can enhance the effectiveness of a heat acclimation program, resulting in improved endurance performance in warm and temperate environments. Drinking in training may be important in enhancing tolerance of the gut when athletes plan to drink in competition. The distribution of water between body water compartments may also be important in the initiation and promotion of cellular adaptations to the training stimulus. Copyright © 2013 Nestec Ltd., Vevey/S. Karger AG, Basel.

  3. The heterogeneous ice shell thickness of Enceladus

    Science.gov (United States)

    Lucchetti, Alice; Pozzobon, Riccardo; Mazzarini, Francesco; Cremonese, Gabriele; Massironi, Matteo

    2016-10-01

    Saturn's moon Enceladus is the smallest Solar System body that presents an intense geologic activity on its surface. Plumes erupting from Enceladus' South Polar terrain (SPT) provide direct evidence of a reservoir of liquid below the surface. Previous analysis of gravity data determined that the ice shell above the liquid ocean must be 30-40 km thick from the South Pole up to 50° S latitude (Iess et al., 2014), however, understand the global or regional nature of the ocean beneath the ice crust is still challenging. To infer the thickness of the outer ice shell and prove the global extent of the ocean, we used the self-similar clustering method (Bonnet et al., 2001; Bour et al., 2002) to analyze the widespread fractures of the Enceladus's surface. The spatial distribution of fractures has been analyzed in terms of their self-similar clustering and a two-point correlation method was used to measure the fractal dimension of the fractures population (Mazzarini, 2004, 2010). A self-similar clustering of fractures is characterized by a correlation coefficient with a size range defined by a lower and upper cut-off, that represent a mechanical discontinuity and the thickness of the fractured icy crust, thus connected to the liquid reservoir. Hence, this method allowed us to estimate the icy shell thickness values in different regions of Enceladus from SPT up to northern regions.We mapped fractures in ESRI ArcGis environment in different regions of the satellite improving the recently published geological map (Crow-Willard and Pappalardo, 2015). On these regions we have taken into account the fractures, such as wide troughs and narrow troughs, located in well-defined geological units. Firstly, we analyzed the distribution of South Polar Region fracture patterns finding an ice shell thickness of ~ 31 km, in agreement with gravity measurements (Iess et al., 2014). Then, we applied the same approach to other four regions of the satellite inferring an increasing of the ice

  4. Effect of corneal hydration on the quality of the femtosecond laser anterior lamellar cut.

    Directory of Open Access Journals (Sweden)

    Ossama Nada

    Full Text Available The goal of this study was to assess the effect of corneal hydration on the quality of the femtosecond laser (FSL anterior lamellar cut. The Visumax FSL was used to dissect an 8-mm-diameter corneal flap in 22 eye bank corneas showing various levels of hydration. The intended ablation depth was 220 µm in all eyes, which corresponded to the maximal depth available with this laser. After the cut, the achieved ablation depth was measured using optical coherence tomography images, flap separability was assessed by measuring the mean force generated to detach the flap, and stromal bed roughness was assessed by measuring the Haralick contrast level on the 1000× scanning electron microscopy images of the ablated surfaces. The preoperative central corneal thickness ranged from 547 to 1104 µm (mean ± SEM: 833 ± 30 µm. A negative correlation was found between the level of corneal hydration and the ablation depth measured in the mid-peripheral cornea (r =  -0.626, p = 0.003, the ablation being more superficial in more edematous corneas. The Haralick contrast also tended to increase as a function of corneal hydration (r = 0.416, p = 0.061, suggesting that laser ablation in edematous corneas results in rougher stromal surfaces. These results support the hypothesis that the quality of the FSL lamellar cut decreases as the level of corneal hydration increases. Although FSL is still considered in the field as the tool of the future for corneal dissection, a better understanding of the limits of this tool will be needed before it can replace manual or automated stromal dissection techniques in hydrated corneas.

  5. Seismic Characterization of the Terrebonne Mini-basin, a Hydrate Rich Depositional System in the Gulf of Mexico

    Science.gov (United States)

    Dafov, L. N.; Eze, P. C.; Haines, S. S.; Graham, S. A.; McHargue, T.; Hosford Scheirer, A.

    2017-12-01

    Natural gas bearing hydrates are a focus of research as a potential source of energy and carbon storage because they occur globally in permafrost regions and marine sediment along every continent. This study focuses on the structural and stratigraphic architecture of the Terrebonne mini-basin, northwest Walker Ridge, Gulf of Mexico, to characterize the depositional architecture and to describe possible migration pathways for petroleum. Questions addressed include: a) continuity of sand layers b) effects of faulting and c) ponding versus fill and spill. To address these questions, seven of forty-two high resolution USGS 2D seismic lines were interpreted and then verified with WesternGeco 3D seismic data, yielding three qualitative models for the depositional environment of hydrate-bearing sand intervals. Deeper hydrate-bearing sand reservoirs were deposited as sheet-like turbidite lobes. Two shallower hydrate-bearing intervals display two possible depositional systems which form reservoirs- 1) sandy to muddy channel sealed laterally by muddy levees with associated sandy crevasse splays, and 2) ponded sandy lobes cut by channels filled with sand lags and mud. Additional observations in the 2D seismic include mass transport deposits and possible contourites. Salt movement facilitated mini-basin formation which was then ponded by sediment and followed by episodes of fill-and-spill and erosion. These seismic interpretations indicate periodic salt uplift. Overturn of salt along the northwestern edge of the basin resulted in thrust faults. The faults and erosional surfaces act as seals to reservoirs. The greatest volume of sandy reservoir potential occurs in sheet-like turbidite lobes with high lateral continuity, which facilitates updip migration of deep-sourced thermogenic gas along bedding surfaces. Channel levees serve as lateral seals to gas hydrate reservoirs, whereas faults, erosional surfaces, and shales provide vertical seals. Characterization of the Terrebonne

  6. 3D Seismic Stratigraphic Analysis of Gas Hydrate Bearing Turbidite Channel-Overbank System in Northern Gulf of Mexico

    Science.gov (United States)

    Santra, M.; Flemings, P. B.; Scott, E.; Meazell, K.; Petrou, E. G.

    2017-12-01

    We present a depositional model for a gas hydrate bearing deepwater channel-overbank system in Green Canyon area (around Block 955) in northern Gulf of Mexico. The gas-hydrate bearing reservoir was tested by three wells drilled in 2009 as part of the Gulf of Mexico Gas Hydrate Joint Industry Project (JIP). The same reservoir was sampled during the recent UT-GOM2-1 pressure-coring expedition. Analysis of a newly available wide-azimuth 3D seismic data shows two distinct stages of development of the channel system that significantly impacted the reservoir characteristics. The study area is located near the present-day Green Canyon reentrant, where a succession of Miocene to recent clastic sediments overlies an extensive salt diapir connected to the autochthonous level. The entire supra-salt sedimentary section is intersected by a system of large-scale normal faults formed as a result of salt movement. The channel system containing the gas hydrate reservoir has a well-defined basal surface, and is capped by a channel abandonment surface. Seismic analysis shows at least two distinct phases of channel development. In the first phase, levees undergo progressive gravitational collapse along series of normal faults that dip towards the channel axis. The normal faults on either side of channel axis are linked to a zone of compression located at the channel axis by a decollement surface at the base of the channel. The compression is recorded by bulging and/or thrusting at the channel center. This compressional bulge was eroded at the channel axis. During this phase, no axial channel deposits have been preserved. However, the position of the channel axis is indicated by a prominent linear ridge of fine-grained material that represents the remnant of the compressional bulge. Mapping of gravitational failure surfaces shows significant rotation and displacement of levee deposits along them. The second phase of development of the channel system is marked by the termination of

  7. Geothermal reservoir management

    Energy Technology Data Exchange (ETDEWEB)

    Scherer, C.R.; Golabi, K.

    1978-02-01

    The optimal management of a hot water geothermal reservoir was considered. The physical system investigated includes a three-dimensional aquifer from which hot water is pumped and circulated through a heat exchanger. Heat removed from the geothermal fluid is transferred to a building complex or other facility for space heating. After passing through the heat exchanger, the (now cooled) geothermal fluid is reinjected into the aquifer. This cools the reservoir at a rate predicted by an expression relating pumping rate, time, and production hole temperature. The economic model proposed in the study maximizes discounted value of energy transferred across the heat exchanger minus the discounted cost of wells, equipment, and pumping energy. The real value of energy is assumed to increase at r percent per year. A major decision variable is the production or pumping rate (which is constant over the project life). Other decision variables in this optimization are production timing, reinjection temperature, and the economic life of the reservoir at the selected pumping rate. Results show that waiting time to production and production life increases as r increases and decreases as the discount rate increases. Production rate decreases as r increases and increases as the discount rate increases. The optimal injection temperature is very close to the temperature of the steam produced on the other side of the heat exchanger, and is virtually independent of r and the discount rate. Sensitivity of the decision variables to geohydrological parameters was also investigated. Initial aquifer temperature and permeability have a major influence on these variables, although aquifer porosity is of less importance. A penalty was considered for production delay after the lease is granted.

  8. Phenomenology of tremor-like signals observed over hydrocarbon reservoirs

    Science.gov (United States)

    Dangel, S.; Schaepman, M. E.; Stoll, E. P.; Carniel, R.; Barzandji, O.; Rode, E.-D.; Singer, J. M.

    2003-11-01

    We have observed narrow-band, low-frequency (1.5-4 Hz, amplitude 0.01-10 μm/s) tremor signals on the surface over hydrocarbon reservoirs (oil, gas and water multiphase fluid systems in porous media) at currently 15 sites worldwide. These 'hydrocarbon tremors' possess remarkably similar spectral and signal structure characteristics, pointing to a common source mechanism, even though the depth (some hundreds to several thousands of meters), specific fluid content (oil, gas, gas condensate of different compositions and combinations) and reservoir rock type (such as sandstone, carbonates, etc.) for each of those sites are quite different. About half of the sites are fully explored or even developed and producing fields, and hard quantitative data on the reservoirs are available (well data, reservoir monitoring data, seismic surveys, etc.). The other areas are essentially either explored prospect areas where we did not have access to hard reservoir data or (in only one case) areas where no exploration wells have been drilled at all. The tremor signal itself was observed over ALL locations investigated so far. The signals weaken at the rim of the reservoirs and are not observed outside the reservoir area. There is a strong correlation of the tremor power with the thickness of the hydrocarbon-bearing layers ('pay zone thickness') determined by borehole log measurements. The overall correlation between surface tremor measurements and accessible subsurface well data is higher than 90%. The phenomenological comparison of hydrocarbon tremor signals with volcanic tremor signals from Stromboli and Arenal volcanoes using both conventional spectral analysis tools and non-linear dynamics methods reveals fundamental similarities between those two phenomena as well as their close relation to bandpass filtered noise. Nevertheless, the specific signal sources are expected to be different for volcanoes and hydrocarbon reservoirs. Using the currently available data we present possible

  9. Controls on Gas Hydrate Formation and Dissociation

    Energy Technology Data Exchange (ETDEWEB)

    Miriam Kastner; Ian MacDonald

    2006-03-03

    The main objectives of the project were to monitor, characterize, and quantify in situ the rates of formation and dissociation of methane hydrates at and near the seafloor in the northern Gulf of Mexico, with a focus on the Bush Hill seafloor hydrate mound; to record the linkages between physical and chemical parameters of the deposits over the course of one year, by emphasizing the response of the hydrate mound to temperature and chemical perturbations; and to document the seafloor and water column environmental impacts of hydrate formation and dissociation. For these, monitoring the dynamics of gas hydrate formation and dissociation was required. The objectives were achieved by an integrated field and laboratory scientific study, particularly by monitoring in situ formation and dissociation of the outcropping gas hydrate mound and of the associated gas-rich sediments. In addition to monitoring with the MOSQUITOs, fluid flow rates and temperature, continuously sampling in situ pore fluids for the chemistry, and imaging the hydrate mound, pore fluids from cores, peepers and gas hydrate samples from the mound were as well sampled and analyzed for chemical and isotopic compositions. In order to determine the impact of gas hydrate dissociation and/or methane venting across the seafloor on the ocean and atmosphere, the overlying seawater was sampled and thoroughly analyzed chemically and for methane C isotope ratios. At Bush hill the pore fluid chemistry varies significantly over short distances as well as within some of the specific sites monitored for 440 days, and gas venting is primarily focused. The pore fluid chemistry in the tub-warm and mussel shell fields clearly documented active gas hydrate and authigenic carbonate formation during the monitoring period. The advecting fluid is depleted in sulfate, Ca Mg, and Sr and is rich in methane; at the main vent sites the fluid is methane supersaturated, thus bubble plumes form. The subsurface hydrology exhibits both

  10. Distinguishing between hydrated, partially hydrated or unhydrated clinker in hardened concrete using microscopy

    NARCIS (Netherlands)

    Valcke, S.L.A.; Rooij, M.R. de; Visser, J.H.M.; Nijland, T.G.

    2010-01-01

    Hydration of clinker particles is since long a topic of interest in both designing and optimizing cement composition and its quantity used in concrete. The interest for carefully observing and also quantifying the type or stage of clinker hydration in hardened cement paste is twofold. Firstly, the

  11. Three-dimensional distribution of gas hydrate beneath southern Hydrate Ridge: Constraints from ODP Leg 204

    Science.gov (United States)

    Trehu, A.M.; Long, P.E.; Torres, M.E.; Bohrmann, G.; Rack, F.R.; Collett, T.S.; Goldberg, D.S.; Milkov, A.V.; Riedel, M.; Schultheiss, P.; Bangs, N.L.; Barr, S.R.; Borowski, W.S.; Claypool, G.E.; Delwiche, M.E.; Dickens, G.R.; Gracia, E.; Guerin, G.; Holland, M.; Johnson, J.E.; Lee, Y.-J.; Liu, C.-S.; Su, X.; Teichert, B.; Tomaru, H.; Vanneste, M.; Watanabe, M. E.; Weinberger, J.L.

    2004-01-01

    Large uncertainties about the energy resource potential and role in global climate change of gas hydrates result from uncertainty about how much hydrate is contained in marine sediments. During Leg 204 of the Ocean Drilling Program (ODP) to the accretionary complex of the Cascadia subduction zone, we sampled the gas hydrate stability zone (GHSZ) from the seafloor to its base in contrasting geological settings defined by a 3D seismic survey. By integrating results from different methods, including several new techniques developed for Leg 204, we overcome the problem of spatial under-sampling inherent in robust methods traditionally used for estimating the hydrate content of cores and obtain a high-resolution, quantitative estimate of the total amount and spatial variability of gas hydrate in this structural system. We conclude that high gas hydrate content (30-40% of pore space or 20-26% of total volume) is restricted to the upper tens of meters below the seafloor near the summit of the structure, where vigorous fluid venting occurs. Elsewhere, the average gas hydrate content of the sediments in the gas hydrate stability zone is generally change. ?? 2004 Published by Elsevier B.V.

  12. Hydrate-phobic surfaces: fundamental studies in clathrate hydrate adhesion reduction.

    Science.gov (United States)

    Smith, J David; Meuler, Adam J; Bralower, Harrison L; Venkatesan, Rama; Subramanian, Sivakumar; Cohen, Robert E; McKinley, Gareth H; Varanasi, Kripa K

    2012-05-07

    Clathrate hydrate formation and subsequent plugging of deep-sea oil and gas pipelines represent a significant bottleneck for deep-sea oil and gas operations. Current methods for hydrate mitigation are expensive and energy intensive, comprising chemical, thermal, or flow management techniques. In this paper, we present an alternate approach of using functionalized coatings to reduce hydrate adhesion to surfaces, ideally to a low enough level that hydrodynamic shear stresses can detach deposits and prevent plug formation. Systematic and quantitative studies of hydrate adhesion on smooth substrates with varying solid surface energies reveal a linear trend between hydrate adhesion strength and the practical work of adhesion (γ(total)[1 + cos θ(rec)]) of a suitable probe liquid, that is, one with similar surface energy properties to those of the hydrate. A reduction in hydrate adhesion strength by more than a factor of four when compared to bare steel is achieved on surfaces characterized by low Lewis acid, Lewis base, and van der Waals contributions to surface free energy such that the practical work of adhesion is minimized. These fundamental studies provide a framework for the development of hydrate-phobic surfaces, and could lead to passive enhancement of flow assurance and prevention of blockages in deep-sea oil and gas operations.

  13. Investigation of the hydration and bioactivity of radiopacified tricalcium silicate cement, Biodentine and MTA Angelus.

    Science.gov (United States)

    Camilleri, Josette; Sorrentino, François; Damidot, Denis

    2013-05-01

    calcium silicate was higher for Biodentine™ than for TCS-20-Z owing to its optimized particle size distribution, the presence of CaCO₃ and the use of CaCl₂. Tricalcium calcium silicate in MTA hydrated even more slowly than TCS-20-Z as evident from the size of reaction rim representative of calcium silicate hydrate (C-S-H) around tricalcium silicate grains and the calorimetry measurements. On the other hand, calcium oxide contained in MTA Angelus™ hydrated very fast inducing an intense exothermic reaction. Calcium hydroxide was produced as a by-product of reaction in all hydrated cements but in greater quantities in MTA due to the hydration of calcium oxide. This lead to less dense microstructure than the one observed for both Biodentine™ and TCS-20-Z. All the materials were bioactive and allowed the deposition of hydroxyapatite on the cement surface in the presence of simulated body fluid and the radiopacity was greater than 3mm aluminum thickness. All the cement pastes tested were composed mainly of tricalcium silicate and a radiopacifier. The laboratory manufactured cement contained no other additives. Biodentine™ included calcium carbonate which together with the additives in the mixing liquid resulted in a material with enhanced chemical properties relative to TCS-20-Z prototype cement. On the other hand MTA Angelus™ displayed the presence of calcium, aluminum and silicon oxides in the un-hydrated powder. These phases are normally associated with the raw materials indicating that the clinker of MTA Angelus™ is incompletely sintered leading to a potential important variability in its mineralogy depending on the sintering conditions. As a consequence, the amount of tricalcium silicate is less than in the two other cements leading to a slower reaction rate and more porous microstructure. Copyright © 2013 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  14. Heat flow pattern in the gas hydrate drilling areas of northern south china sea and the implication for further study

    Science.gov (United States)

    Wang, Lifeng; Sha, Zhibin

    2015-04-01

    observations bring new insights to our growing understanding of the stability of this dynamic hydrate reservoir in the continental margin shallow subsurface, and alert us that occurrence patterns may be more complex than previously thought. So the future aim of this program is to better understand the factors constraining the distribution of hydrate deposits, and the processes involved in gas hydrate formation.

  15. Advances in photonic reservoir computing

    Science.gov (United States)

    Van der Sande, Guy; Brunner, Daniel; Soriano, Miguel C.

    2017-05-01

    We review a novel paradigm that has emerged in analogue neuromorphic optical computing. The goal is to implement a reservoir computer in optics, where information is encoded in the intensity and phase of the optical field. Reservoir computing is a bio-inspired approach especially suited for processing time-dependent information. The reservoir's complex and high-dimensional transient response to the input signal is capable of universal computation. The reservoir does not need to be trained, which makes it very well suited for optics. As such, much of the promise of photonic reservoirs lies in their minimal hardware requirements, a tremendous advantage over other hardware-intensive neural network models. We review the two main approaches to optical reservoir computing: networks implemented with multiple discrete optical nodes and the continuous system of a single nonlinear device coupled to delayed feedback.

  16. Forming mechanism of the Ordovician karst carbonate reservoirs on the northern slope of central Tarim Basin

    Directory of Open Access Journals (Sweden)

    Heng Fu

    2017-07-01

    Full Text Available The Ordovician karst carbonate reservoirs on the northern slope of central Tarim Basin are important oil and gas exploration targets in the basin, but their dissolution mechanisms are in controversy. In this paper, based on the integrated study of sedimentation, sequence and reservoir, together with microscopic analysis and macroscopic seismic data analysis, the carbonate karst reservoirs in the study area were divided into three types: dissolved pore-cavity limestone reservoir, pore-cavity dolomite reservoir and fracture-cavity siliceous reservoir, and their forming mechanisms were discussed respectively. Some findings were obtained. First, dissolved pore-cavity limestone reservoirs are distributed in the upper Yingshan Fm and Yijianfang Fm of the Ordovician vertically, while pore-cavity dolomite reservoirs are mainly developed in the Penglai Fm and lower Yingshan Fm of the Ordovician with great thickness. Second, dissolved pore-cavity limestone reservoirs were formed by karstification on the third-order sequence boundary (lowstand tract, while pore-cavity dolomite reservoirs were formed by deep burial dolomitization controlled by karstification on the third-order sequence boundary, both of which are distributed in the highstand tract below the third-order sequence boundary. Third, siliceous reservoirs are developed under the control of faulting, as a result of reworking of deep hydrothermal fluids along faults to the limestone, and the siliceous reservoirs and their hydrothermal solution fracture-cavity systems are distributed near faults. It is further predicted that, in addition to the three types of reservoir above, platform-margin reef-flat reservoirs are developed in the Ordovician on the northern slope of central Tarim Basin.

  17. Hydration of urea and alkylated urea derivatives

    Science.gov (United States)

    Kaatze, Udo

    2018-01-01

    Compressibility data and broadband dielectric spectra of aqueous solutions of urea and some of its alkylated derivatives have been evaluated to yield their numbers Nh of hydration water molecules per molecule of solute. Nh values in a broad range of solute concentrations are discussed and are compared to hydration numbers of other relevant molecules and organic ions. Consistent with previous results, it is found that urea differs from other solutes in its unusually small hydration number, corresponding to just one third of the estimated number of nearest neighbor molecules. This remarkable hydration behavior is explained by the large density φH of hydrogen bonding abilities offered by the urea molecule. In terms of currently discussed models of reorientational motions and allied dynamics in water and related associating liquids, the large density φH causes a relaxation time close to that of undisturbed water with most parts of water encircling the solute. Therefore only a small part of disturbed ("hydration") water is left around each urea molecule. Adding alkyl groups to the basic molecule leads to Nh values which, within the series of n-alkylurea derivatives, progressively increase with the number of methyl groups per solute. With n-butylurea, Nh from dielectric spectra, in conformity with many other organic solutes, slightly exceeds the number of nearest neighbors. Compared to such Nh values, hydration numbers from compressibility data are substantially smaller, disclosing incorrect assumptions in the formula commonly used to interpret the experimental compressibilities. Similar to other series of organic solutes, effects of isomerization have been found with alkylated urea derivatives, indicating that factors other than the predominating density φH of hydrogen bond abilities contribute also to the hydration properties.

  18. X-ray microanalysis of freeze-dried and frozen-hydrated cryosections

    International Nuclear Information System (INIS)

    Zierold, K.

    1988-01-01

    The elemental composition and the ultrastructure of biological cells were studied by scanning transmission electron microscopy (STEM) combined with energy dispersive X-ray microanalysis. The preparation technique involves cryofixation, cryoultramicrotomy, cryotransfer, and freeze-drying of samples. Freeze-dried cryosections 100-nm thick appeared to be appropriate for measuring the distribution of diffusible elements and water in different compartments of the cells. The lateral analytical resolution was less than 50 nm, depending on ice crystal damage and section thickness. The detection limit was in the range of 10 mmol/kg dry weight for all elements with an atomic number higher than 12; for sodium and magnesium the detection limits were about 30 and 20 mmol/kg dry weight, respectively. The darkfield intensity in STEM is linearly related to the mass thickness. Thus, it becomes possible to measure the water content in intracellular compartments by using the darkfield signal of the dry mass remaining after freeze-drying. By combining the X-ray microanalytical data expressed as dry weight concentrations with the measurements of the water content, physiologically more meaningful wet weight concentrations of elements were determined. In comparison to freeze-dried cryosections frozen-hydrated sections showed poor contrast and were very sensitive against radiation damage, resulting in mass loss. The high electron exposure required for recording X-ray spectra made reproducible microanalysis of ultrathin (about 100-nm thick) frozen-hydrated sections impossible. The mass loss could be reduced by carbon coating; however, the improvement achieved thus far is still insufficient for applications in X-ray microanalysis. Therefore, at present only bulk specimens or at least 1-micron thick sections can be used for X-ray microanalysis of frozen-hydrated biological samples

  19. Encapsulated microsensors for reservoir interrogation

    Energy Technology Data Exchange (ETDEWEB)

    Scott, Eddie Elmer; Aines, Roger D.; Spadaccini, Christopher M.

    2016-03-08

    In one general embodiment, a system includes at least one microsensor configured to detect one or more conditions of a fluidic medium of a reservoir; and a receptacle, wherein the receptacle encapsulates the at least one microsensor. In another general embodiment, a method include injecting the encapsulated at least one microsensor as recited above into a fluidic medium of a reservoir; and detecting one or more conditions of the fluidic medium of the reservoir.

  20. Gas hydrate quantification from ocean-bottom seismometer data along the continental margin of Western Svalbard.

    Science.gov (United States)

    Chabert, A.; Minshull, T. A.; Westbrook, G. K.; Berndt, C.

    2009-04-01

    The stability of shallow gas hydrate in the Arctic region is expected to be affected by the warming of the bottom-water in the next decades. It is, therefore, important to evaluate how the gas hydrate systems will react to future increases in bottom-water temperature and the impact on climate of the spatial and temporal variability of the release of methane from these reservoirs. As part of the International Polar Year initiative, a multidisciplinary marine expedition was carried out in September 2008 along the continental margin west of Svalbard in the Arctic. One of the objectives was to investigate the extent of the gas hydrate stability zone (GHSZ) along and across the continental slope and to estimate the quantity of methane present using the geophysical properties of methane hydrate- and gas-bearing sediments, which occur in and beneath the GHSZ. Three seismic experiments employing ocean-bottom seismometers (OBS) were carried out across and along the continental margin as part of the project. Seismic data from 13 OBS in closely spaced arrays were acquired from 5 representative sites off west Svalbard, above and below the upper limit of the GHSZ. Two to four OBSs were deployed at each site, with a spacing of 200 m. The high frequency airguns were fired at 5-s intervals, concurrently with the acquisition of multi-channel seismic reflection profiles. The OBSs were equipped with a 3-component 4.5 Hz geophone package and a broadband hydrophone; the data-loggers were operated at 1 kHz sample rate. The OBS experiments were designed to recover P- and S-wave velocities to depths of a few hundreds metres below the seabed in order to estimate the amount of hydrate in the region, hydrate increasing both the P- and S-wave velocities of the sediments in which it is present. The data show clearly recorded P reflections at short offsets, as well as refracted arrivals at larger offsets, from depths of 1 to 2 kilometres below the seabed. S waves, generated by P-S conversion on

  1. Thick-Big Descriptions

    DEFF Research Database (Denmark)

    Lai, Signe Sophus

    to a commercial logic (boyd & Crawford 2011) and is as such directed by motives that call for specific types of sellable user data and specific segmentation strategies. In combining big data and ‘thick descriptions’ (Geertz 1973) scholars need to question how ethnographic fieldwork might map the ‘data not seen...

  2. Development of hydrate risk quantification in oil and gas production

    Science.gov (United States)

    Chaudhari, Piyush N.

    Subsea flowlines that transport hydrocarbons from wellhead to the processing facility face issues from solid deposits such as hydrates, waxes, asphaltenes, etc. The solid deposits not only affect the production but also pose a safety concern; thus, flow assurance is significantly important in designing and operating subsea oil and gas production. In most subsea oil and gas operations, gas hydrates form at high pressure and low temperature conditions, causing the risk of plugging flowlines, with a undesirable impact on production. Over the years, the oil and gas industry has shifted their perspective from hydrate avoidance to hydrate management given several parameters such as production facility, production chemistry, economic and environmental concerns. Thus, understanding the level of hydrate risk associated with subsea flowlines is an important in developing efficient hydrate management techniques. In the past, hydrate formation models were developed for various flow-systems (e.g., oil dominated, water dominated, and gas dominated) present in the oil and gas production. The objective of this research is to extend the application of the present hydrate prediction models for assessing the hydrate risk associated with subsea flowlines that are prone to hydrate formation. It involves a novel approach for developing quantitative hydrate risk models based on the conceptual models built from the qualitative knowledge obtained from experimental studies. A comprehensive hydrate risk model, that ranks the hydrate risk associated with the subsea production system as a function of time, hydrates, and several other parameters, which account for inertial, viscous, interfacial forces acting on the flow-system, is developed for oil dominated and condensate systems. The hydrate plugging risk for water dominated systems is successfully modeled using The Colorado School of Mines Hydrate Flow Assurance Tool (CSMHyFAST). It is found that CSMHyFAST can be used as a screening tool in

  3. Complex admixtures of clathrate hydrates in a water desalination method

    Science.gov (United States)

    Simmons, Blake A [San Francisco, CA; Bradshaw, Robert W [Livermore, CA; Dedrick, Daniel E [Berkeley, CA; Anderson, David W [Riverbank, CA

    2009-07-14

    Disclosed is a method that achieves water desalination by utilizing and optimizing clathrate hydrate phenomena. Clathrate hydrates are crystalline compounds of gas and water that desalinate water by excluding salt molecules during crystallization. Contacting a hydrate forming gaseous species with water will spontaneously form hydrates at specific temperatures and pressures through the extraction of water molecules from the bulk phase followed by crystallite nucleation. Subsequent dissociation of pure hydrates yields fresh water and, if operated correctly, allows the hydrate-forming gas to be efficiently recycled into the process stream.

  4. Seismic model of Mars. 1. Effects of temperature, composition and hydration

    Science.gov (United States)

    Zharkov, Vladimir; Gudkova, Tamara

    At present in the geophysics of the Earth, scientists highlight to the study of the effect of water traces in mantle minerals on physical properties of Earth’s interiors. It turned out, that at the base of the upper mantle near the seismic boundary of 410 km depth olivine can accumulate up to 0.4 wt. % H _{2}O. According to (Mao et al., 2010, 2011, 2012) oivine can accumulate up to 1 wt % of water, wadesleite - up to 2 wt % of water and ringwoodite up to 1 wt % of water. It is considered, that Mars was basically formed from protobodies of two types: a highly reduced component A and an oxidized component B. In two-component DW geochemical model (Dreibus, Wanke, 1989), oxidized component B (40%) contains up to 20 wt % H _{2}O. Important character of Mars is that under its formation a lot amount of water could be incorporated into the planet. The important parameter of mantle silicates is an iron number, which is defined as a molecular ratio Fe#=Fe/(Fe+Mg)x100. In the DW model Fe#=25 for the silicate reservoir of a planet. The thickness of the Martian crust is assumed to lie in the range of 50 - 100 km. When melting of such a thick crust, the iron number of the Martian mantle decreases, and its value is taken to be Fe# ≈ 20 - 25 at modeling Martian interiors. The iron number of the Earth’s mantle is noticeably less ≈ 10. The higher the iron value Fe# is, the larger corresponding capacity of minerals to accumulate water. Thus, from one side, Mars could get larger amount of water with the component B under its formation, than the Earth; and from the other side, in principle, Martian minerals could accumulate larger amount of water than the Earth, as the iron number Fe# for Mars is two times higher than in Earth’s minerals. Our analysis is based on a four-layer model M14_3 (Zharkov et al., 2009), for which all the effects of studied model parameters are considered. It consists of a two-layer crust, a mantle and a core. The composition of the crust is derived

  5. Irrigation port hydration in phacoemulsification surgery.

    Science.gov (United States)

    Suzuki, Hisaharu; Masuda, Yoichiro; Hamajima, Yuki; Takahashi, Hiroshi

    2018-01-01

    In most cases, hydration is performed by water injection into the stromal tissue with a needle. The technique is simple, however it is sometimes troublesome. We describe a simple technique for hydrating the corneal stroma in cataract surgery using an irrigation port. The technique began by pushing the irrigation port against the corneal stroma for a few seconds during phacoemulsification, which generated edema in the corneal incision that subsequently prevented leakage. This procedure is called the hydration using irrigation port (HYUIP) technique. A total of 60 eyes were randomized and placed in two groups, 30 eyes underwent surgeries using the HYUIP technique (HYUIP group) and 30 eyes underwent surgeries without the HYUIP technique (control). The three points evaluated during each surgery included 1) the occurrence of anterior chamber collapse during the pulling out of the I/A tip after inserting the intraocular lens, 2) the need for conventional hydration, and 3) watertight completion at the end stage of surgery. The anterior chamber collapse and the need for conventional hydration were significantly smaller in the HYUIP group compared to the control group. Regarding the self-sealing completion, no significant difference was observed between the two groups. The HYUIP technique is an effective method for creating self-sealing wound. In addition, this technique helps to prevent anterior chamber collapse.

  6. Blue LED irradiation to hydration of skin

    Science.gov (United States)

    Menezes, Priscila F. C.; Requena, Michelle B.; Lizarelli, Rosane F., Z.; Bagnato, Vanderlei S.

    2015-06-01

    Blue LED system irradiation shows many important properties on skin as: bacterial decontamination, degradation of endogenous skin chromophores and biostimulation. In this clinical study we prove that the blue light improves the skin hydration. In the literature none authors reports this biological property on skin. Then this study aims to discuss the role of blue light in the skin hydration. Twenty patients were selected to this study with age between 25-35 years old and phototype I, II and III. A defined area from forearm was pre determined (A = 4.0 cm2). The study was randomized in two treatment groups using one blue light device (power of 5.3mW and irradiance of 10.8mW/cm2). The first treatment group was irradiated with 3J/cm2 (277seconds) and the second with 6J/cm2 (555 seconds). The skin hydration evaluations were done using a corneometer. The measurements were collected in 7, 14, 21 and 30 days, during the treatment. Statistical test of ANOVA, Tukey and T-Student were applied considering 5% of significance. In conclusion, both doses were able to improve the skin hydration; however, 6J/cm2 has kept this hydration for 30 days.

  7. First-principles elasticity of monocarboaluminate hydrates

    KAUST Repository

    Moon, J.

    2014-07-01

    The elasticity of monocarboaluminate hydrates, 3CaO·Al2O3·CaCO3·xH2O (x = 11 or 8), has been investigated by first-principles calculations. Previous experimental study revealed that the fully hydrated monocarboaluminate (x = 11) exhibits exceptionally low compressibility compared to other reported calcium aluminate hydrates. This stiff hydration product can contribute to the strength of concrete made with Portland cements containing calcium carbonates. In this study, full elastic tensors and mechanical properties of the crystal structures with different water contents (x = 11 or 8) are computed by first-principles methods based on density functional theory. The results indicate that the compressibility of monocarboaluminate is highly dependent on the water content in the interlayer region. The structure also becomes more isotropic with the addition of water molecules in this region. Since the monocarboaluminate is a key hydration product of limestone added cement, elasticity of the crystal is important to understand its mechanical impact on concrete. Besides, it is put forth that this theoretical calculation will be useful in predicting the elastic properties of other complex cementitous materials and the influence of ion exchange on compressibility.

  8. Reservoir Simulations of Low-Temperature Geothermal Reservoirs

    Science.gov (United States)

    Bedre, Madhur Ganesh

    The eastern United States generally has lower temperature gradients than the western United States. However, West Virginia, in particular, has higher temperature gradients compared to other eastern states. A recent study at Southern Methodist University by Blackwell et al. has shown the presence of a hot spot in the eastern part of West Virginia with temperatures reaching 150°C at a depth of between 4.5 and 5 km. This thesis work examines similar reservoirs at a depth of around 5 km resembling the geology of West Virginia, USA. The temperature gradients used are in accordance with the SMU study. In order to assess the effects of geothermal reservoir conditions on the lifetime of a low-temperature geothermal system, a sensitivity analysis study was performed on following seven natural and human-controlled parameters within a geothermal reservoir: reservoir temperature, injection fluid temperature, injection flow rate, porosity, rock thermal conductivity, water loss (%) and well spacing. This sensitivity analysis is completed by using ‘One factor at a time method (OFAT)’ and ‘Plackett-Burman design’ methods. The data used for this study was obtained by carrying out the reservoir simulations using TOUGH2 simulator. The second part of this work is to create a database of thermal potential and time-dependant reservoir conditions for low-temperature geothermal reservoirs by studying a number of possible scenarios. Variations in the parameters identified in sensitivity analysis study are used to expand the scope of database. Main results include the thermal potential of reservoir, pressure and temperature profile of the reservoir over its operational life (30 years for this study), the plant capacity and required pumping power. The results of this database will help the supply curves calculations for low-temperature geothermal reservoirs in the United States, which is the long term goal of the work being done by the geothermal research group under Dr. Anderson at

  9. Effects of Nanosilica on Early Age Stages of Cement Hydration

    Directory of Open Access Journals (Sweden)

    Forood Torabian Isfahani

    2017-01-01

    Full Text Available Effects of nanosilica on cement hydration have been broadly investigated in the literature and early age cement hydration, as a whole, has been mainly considered, disregarding the substages of the hydration. The hydration of cement is characterized by different substages and nanosilica effect on the hydration could be a result of diverse, even contradictory, behavior of nanosilica in individual stages of the hydration. In this study, effects of nanosilica on different substages of cement hydration are investigated. Isothermal calorimetry results show that at early ages (initial 72 hours the effects of nanosilica depend on the phenomenon by which the hydration is governed: when the hydration is chemically controlled, that is, during initial reaction, dormant period, and acceleratory period, the hydration rate is accelerated by adding nanosilica; when the hydration is governed by diffusion process, that is, during postacceleratory period, the hydration rate is decelerated by adding nanosilica. The Thermal Gravimetric Analysis on the samples at the hardened state (after 28 days of curing reveals that, after adding nanosilica, the hydration degree slightly increased compared to the plain paste.

  10. Predicting hydration energies for multivalent ions

    DEFF Research Database (Denmark)

    Andersson, Martin Peter; Stipp, Susan Louise Svane

    2014-01-01

    We have predicted the free energy of hydration for 40 monovalent and multivalent cations and anions using density functional theory and the implicit solvent model COnductor like Screening MOdel for Real Solvents (COSMO-RS) at the Becke-Perdew (BP)/Triple zeta valence with polarization functions...... errors. Our results indicate that quantum chemical calculations combined with COSMO-RS solvent treatment is a reliable method for treating multivalent ions in solution, provided one hydration shell of explicit water molecules is included for metal cations. The accuracy is not high enough to allow...... absolute predictions of hydration energies but could be used to investigate trends for several ions, thanks to the low computational cost, in particular for ligand exchange reactions....

  11. THz characterization of hydrated and anhydrous materials

    Science.gov (United States)

    Sokolnikov, Andre

    2011-06-01

    The characterization of anhydrous and hydrated forms of materials is of great importance to science and industry. Water content poses difficulties for successful identification of the material structure by THz radiation. However, biological tissues and hydrated forms of nonorganic substances still may be investigated by THz radiation. This paper outlines the range of possibilities of the above characterization, as well as provides analysis of the physical mechanism that allows or prevents penetration of THz waves through the substance. THz-TDS is used to measure the parameters of the characterization of anhydrous and hydrated forms of organic and nonorganic samples. Mathematical methods (such as prediction models of time-series analysis) are used to help identifying the absorption coefficient and other parameters of interest. The discovered dependencies allow designing techniques for material identification/characterization (e.g. of drugs, explosives, etc. that may have water content). The results are provided.

  12. Method for production of hydrocarbons from hydrates

    Science.gov (United States)

    McGuire, Patrick L.

    1984-01-01

    A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl.sub.2 or CaBr.sub.2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl.sub.2 /CaBr.sub.2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl.sub.2 /CaBr.sub.2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

  13. Hydration dynamics of hyaluronan and dextran.

    Science.gov (United States)

    Hunger, Johannes; Bernecker, Anja; Bakker, Huib J; Bonn, Mischa; Richter, Ralf P

    2012-07-03

    Hyaluronan is a polysaccharide, which is ubiquitous in vertebrates and has been reported to be strongly hydrated in a biological environment. We study the hydration of hyaluronan in solution using the rotational dynamics of water as a probe. We measure these dynamics with polarization-resolved femtosecond-infrared and terahertz time-domain spectroscopies. Both experiments reveal that a subensemble of water molecules is slowed down in aqueous solutions of hyaluronan amounting to ∼15 water molecules per disaccharide unit. This quantity is consistent with what would be expected for the first hydration shell. Comparison of these results to the water dynamics in aqueous dextran solution, a structurally similar polysaccharide, yields remarkably similar results. This suggests that the observed interaction with water is a common feature for hydrophilic polysaccharides and is not specific to hyaluronan. Copyright © 2012 Biophysical Society. Published by Elsevier Inc. All rights reserved.

  14. Methane hydrates in nature - Current knowledge and challenges

    Science.gov (United States)

    Collett, Timothy S.

    2014-01-01

    Recognizing the importance of methane hydrate research and the need for a coordinated effort, the United States Congress enacted the Methane Hydrate Research and Development Act of 2000. At the same time, the Ministry of International Trade and Industry in Japan launched a research program to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. India, China, the Republic of Korea, and other nations also have established large methane hydrate research and development programs. Government-funded scientific research drilling expeditions and production test studies have provided a wealth of information on the occurrence of methane hydrates in nature. Numerous studies have shown that the amount of gas stored as methane hydrates in the world may exceed the volume of known organic carbon sources. However, methane hydrates represent both a scientific and technical challenge, and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of methane hydrates in nature, (2) assessing the volume of natural gas stored within various methane hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural methane hydrates, (5) analyzing the methane hydrate role as a geohazard, (6) establishing the means to detect and characterize methane hydrate accumulations using geologic and geophysical data, and (7) establishing the thermodynamic phase equilibrium properties of methane hydrates as a function of temperature, pressure, and gas composition. The U.S. Department of Energy (DOE) and the Consortium for Ocean Leadership (COL) combined their efforts in 2012 to assess the contributions that scientific drilling has made and could continue to make to advance

  15. Calcium silicate-based sealers: Assessment of physicochemical properties, porosity and hydration.

    Science.gov (United States)

    Marciano, Marina Angélica; Duarte, Marco Antonio Hungaro; Camilleri, Josette

    2016-02-01

    Investigation of hydration, chemical, physical properties and porosity of experimental calcium silicate-based sealers. Experimental calcium silicate-based sealers with calcium tungstate and zirconium oxide radio-opacifiers were prepared by mixing 1g of powder to 0.3 mL of 80% distilled water and 20% propylene glycol. MTA and MTA Fillapex were used as controls. The raw materials and set sealers were characterized using a combination of scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. Physical properties were analyzed according to ANSI/ADA. The pH and calcium ion release were assessed after 3, 24, 72 and 168 h. The porosity was assessed using mercury intrusion porosimetry. The analysis of hydration of prototype sealers revealed calcium hydroxide as a by-product resulting in alkaline pH and detection of calcium ion release, with high values in initial periods. The radiopacity was similar to MTA for the sealers containing high amounts of radio-opacifiers (p>0.05). Flowability was higher and film thickness was lower for resinous MTA Fillapex sealer (p0.05). The prototype sealers presented adequate hydration, elevated pH and calcium ion release. Regarding physical properties, elevated proportions of radio-opacifiers were necessary to accomplish adequate radiopacity, enhance flowability and reduce film thickness. All the tested sealers presented water sorption and porosity similar to MTA. Copyright © 2015 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  16. Dynamics of fault-fluid-hydrate system around a shale-cored anticline in deepwater Nigeria

    Science.gov (United States)

    Sultan, N.; Riboulot, V.; Ker, S.; Marsset, B.; GéLi, L.; Tary, J. B.; Klingelhoefer, F.; Voisset, M.; Lanfumey, V.; Colliat, J. L.; Adamy, J.; Grimaud, S.

    2011-12-01

    Gas hydrates were recovered by coring at the eastern border of a shale-cored anticline in the eastern Niger Delta. To characterize the link between faults and fluid release and to identify the role of fluid flow in the gas hydrate dynamics, three piezometers were deployed for periods ranging from 387 to 435 days. Two of them were deployed along a major fault linked to a shallow hydrocarbon reservoir while the third monitored the fluid pressure in a pockmark aligned above the same major fault. In addition, 10 ocean-bottom seismometers (OBS) were deployed for around 60 days. The piezometers simultaneously registered a prolonged fluid flow event lasting 90 days. During this time, OBS measurements record several episodic fluid release events. By combining and analyzing existing and newly acquired data, we show that the fluid-fault system operates according to the following three stages: (1) upward pore fluid migration through existing conduits and free gas circulation within several shallow sandy layers intersecting the major fault, (2) gas accumulation and pore pressure increases within sandy-silty layers, and (3) hydrofracturing and fluid pressure dissipation through sporadic degassing events, causing pore fluid circulation through shallow sandy layers and drawing overlying seawater into the sediment. This paper clearly demonstrates how an integrated approach based on seafloor observations, in situ measurements, and monitoring is essential for understanding fault-fluid-hydrate systems.

  17. A review of reservoir desiltation

    DEFF Research Database (Denmark)

    Brandt, Anders

    2000-01-01

    physical geography, hydrology, desilation efficiency, reservoir flushing, density-current venting, sediment slucing, erosion pattern, downstream effects, flow characteristics, sedimentation......physical geography, hydrology, desilation efficiency, reservoir flushing, density-current venting, sediment slucing, erosion pattern, downstream effects, flow characteristics, sedimentation...

  18. Reservoir sedimentation; a literature survey

    NARCIS (Netherlands)

    Sloff, C.J.

    1991-01-01

    A survey of literature is made on reservoir sedimentation, one of the most threatening processes for world-wide reservoir performance. The sedimentation processes, their impacts, and their controlling factors are assessed from a hydraulic engineering point of view with special emphasis on

  19. FRACTURED PETROLEUM RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Abbas Firoozabadi

    1999-06-11

    The four chapters that are described in this report cover a variety of subjects that not only give insight into the understanding of multiphase flow in fractured porous media, but they provide also major contribution towards the understanding of flow processes with in-situ phase formation. In the following, a summary of all the chapters will be provided. Chapter I addresses issues related to water injection in water-wet fractured porous media. There are two parts in this chapter. Part I covers extensive set of measurements for water injection in water-wet fractured porous media. Both single matrix block and multiple matrix blocks tests are covered. There are two major findings from these experiments: (1) co-current imbibition can be more efficient than counter-current imbibition due to lower residual oil saturation and higher oil mobility, and (2) tight fractured porous media can be more efficient than a permeable porous media when subjected to water injection. These findings are directly related to the type of tests one can perform in the laboratory and to decide on the fate of water injection in fractured reservoirs. Part II of Chapter I presents modeling of water injection in water-wet fractured media by modifying the Buckley-Leverett Theory. A major element of the new model is the multiplication of the transfer flux by the fractured saturation with a power of 1/2. This simple model can account for both co-current and counter-current imbibition and computationally it is very efficient. It can be orders of magnitude faster than a conventional dual-porosity model. Part II also presents the results of water injection tests in very tight rocks of some 0.01 md permeability. Oil recovery from water imbibition tests from such at tight rock can be as high as 25 percent. Chapter II discusses solution gas-drive for cold production from heavy-oil reservoirs. The impetus for this work is the study of new gas phase formation from in-situ process which can be significantly

  20. Reservoir engineering and hydrogeology

    International Nuclear Information System (INIS)

    Anon.

    1983-01-01

    Summaries are included which show advances in the following areas: fractured porous media, flow in single fractures or networks of fractures, hydrothermal flow, hydromechanical effects, hydrochemical processes, unsaturated-saturated systems, and multiphase multicomponent flows. The main thrust of these efforts is to understand the movement of mass and energy through rocks. This has involved treating fracture rock masses in which the flow phenomena within both the fractures and the matrix must be investigated. Studies also address the complex coupling between aspects of thermal, hydraulic, and mechanical processes associated with a nuclear waste repository in a fractured rock medium. In all these projects, both numerical modeling and simulation, as well as field studies, were employed. In the theoretical area, a basic understanding of multiphase flow, nonisothermal unsaturated behavior, and new numerical methods have been developed. The field work has involved reservoir testing, data analysis, and case histories at a number of geothermal projects

  1. Chalk as a reservoir

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    basin, so stylolite formation in the chalk is controlled by effective burial stress. The stylolites are zones of calcite dissolution and probably are the source of calcite for porefilling cementation which is typical in water zone chalk and also affect the reservoirs to different extent. The relatively...... 50% calcite, leaving the remaining internal surface to the fine grained silica and clay. The high specific surface of these components causes clay- and silica rich intervals to have high irreducible water saturation. Although chalks typically are found to be water wet, chalk with mixed wettability...... stabilizes chemically by recrystallization. This process requires energy and is promoted by temperature. This recrystallization in principle does not influence porosity, but only specific surface, which decreases during recrystallization, causing permeability to increase. The central North Sea is a warm...

  2. Pacifiers: a microbial reservoir.

    Science.gov (United States)

    Comina, Elodie; Marion, Karine; Renaud, François N R; Dore, Jeanne; Bergeron, Emmanuelle; Freney, Jean

    2006-12-01

    The permanent contact between the nipple part of pacifiers and the oral microflora offers ideal conditions for the development of biofilms. This study assessed the microbial contamination on the surface of 25 used pacifier nipples provided by day-care centers. Nine were made of silicone and 16 were made of latex. The biofilm was quantified using direct staining and microscopic observations followed by scraping and microorganism counting. The presence of a biofilm was confirmed on 80% of the pacifier nipples studied. This biofilm was mature for 36% of them. Latex pacifier nipples were more contaminated than silicone ones. The two main genera isolated were Staphylococcus and Candida. Our results confirm that nipples can be seen as potential reservoirs of infections. However, pacifiers do have some advantages; in particular, the potential protection they afford against sudden infant death syndrome. Strict rules of hygiene and an efficient antibiofilm cleaning protocol should be established to answer the worries of parents concerning the safety of pacifiers.

  3. Coating thickness measuring device

    International Nuclear Information System (INIS)

    Joffe, B.B.; Sawyer, B.E.; Spongr, J.J.

    1984-01-01

    A device especially adapted for measuring the thickness of coatings on small, complexly-shaped parts, such as, for example, electronic connectors, electronic contacts, or the like. The device includes a source of beta radiation and a radiation detector whereby backscatter of the radiation from the coated part can be detected and the thickness of the coating ascertained. The radiation source and detector are positioned in overlying relationship to the coated part and a microscope is provided to accurately position the device with respect to the part. Means are provided to control the rate of descent of the radiation source and radiation detector from its suspended position to its operating position and the resulting impact it makes with the coated part to thereby promote uniformity of readings from operator to operator, and also to avoid excessive impact with the part, thereby improving accuracy of measurement and eliminating damage to the parts

  4. Hydration and nutrition knowledge in adolescent swimmers. Does water intake affect urine hydration markers after swimming?

    Directory of Open Access Journals (Sweden)

    Cesare Altavilla

    2017-12-01

    Full Text Available Little data exists regarding nutritional knowledge and hydration in adolescent swimmers. The aim of this study was to assess the level of nutrition and hydration knowledge and to describe the fluid balance in adolescent swimmers during training. A study was carried out with a cross-sectional descriptive part and a longitudinal part with repeated measurements over five swimming sessions. Eighty-six adolescent swimmers completed a questionnaire to assess their sport nutrition and hydration knowledge. Fluid balance and urine hydration markers were studied during training. Swimmers showed a limited nutrition knowledge (33.26 % ± SD 12.59 and meagre hydration knowledge (28.61 % ± SD 28.59. Females showed lower scores than male swimmers in nutrition and hydration knowledge. Based on urine specific gravity, swimmers started the training close to the euhydrated threshold (1.019 g/mL ± SD 0.008. Although urine specific gravity and urine colour were reduced after the training, there were minimal changes in body mass (-0.12 Kg ± SD 0.31. Sweat loss (2.67 g/min ± SD 3.23 and the net changes in the fluid balance (-0.22 % ± SD 0.59 were low. The poor knowledge in nutrition and hydration encountered in the swimmers can justify the development of a strategy to incorporate nutritional education programmes for this group. Body water deficit from swimming activity seems to be easily replaced with the water intake to maintain hydration. After the training, the urine of swimmers was diluted regardless of their water intake. Dilution of urine did not reflect real hydration state in swimming.

  5. Nanostructure of Calcium Silicate Hydrates in Cements

    KAUST Repository

    Skinner, L. B.

    2010-05-11

    Calcium silicate hydrate (CSH) is the major volume phase in the matrix of Portland cement concrete. Total x-ray scattering measurements with synchrotron x rays on synthetic CSH(I) shows nanocrystalline ordering with a particle diameter of 3.5(5) nm, similar to a size-broadened 1.1 nm tobermorite crystal structure. The CSH component in hydrated tricalcium silicate is found to be similar to CSH(I). Only a slight bend and additional disorder within the CaO sheets is required to explain its nanocrystalline structure. © 2010 The American Physical Society.

  6. Morphology of methane hydrate host sediments

    Science.gov (United States)

    Jones, K.W.; Feng, H.; Tomov, S.; Winters, W.J.; Eaton, M.; Mahajan, D.

    2005-01-01

    The morphological features including porosity and grains of methane hydrate host sediments were investigated using synchrotron computed microtomography (CMT) technique. The sediment sample was obtained during Ocean Drilling Program Leg 164 on the Blake Ridge at water depth of 2278.5 m. The CMT experiment was performed at the Brookhaven National Synchrotron Light Source facility. The analysis gave ample porosity, specific surface area, mean particle size, and tortuosity. The method was found to be highly effective for the study of methane hydrate host sediments.

  7. Hydrate Technology For Transporting Natural Gas

    OpenAIRE

    Dawe, R. A.

    2003-01-01

    Natural gas hydrate (NGH) is a viable alternative to LNG (Liquefied Natural Gas) or pipelines for the transportation of natural gas from source to demand. It involves three stages: production, transportation and re-gasification. The production of the hydrate occurs at pressures >50 bar at temperatures ~10oC in the presence of water and natural gas (particularly methane, ethane, propane). Transportation is by insulated bulk carrier at around –5 oC and atmospheric pressure or 0 oC at 10 bar, an...

  8. What are gas hydrates?: Chapter 1

    Science.gov (United States)

    Beaudoin, Y.C.; Waite, W.; Boswell, R.; Dallimore, Scott

    2014-01-01

    The English chemistry pioneer Sir Humphry Davy first combined gas and water to produce a solid substance in his lab in 1810. For more than a century after that landmark moment, a small number of scientists catalogued various solid “hydrates” formed by combining water with an assortment of gases and liquids. Sloan and Koh (2007) review this early research, which was aimed at discerning the chemical structures of gas hydrates (Fig. 1.1), as well as the pressures and temperatures at which they are stable. Because no practical applications were found for these synthetic gas hydrates, they remained an academic curiosity.

  9. Dehydration of plutonium or neptunium trichloride hydrate

    Science.gov (United States)

    Foropoulos, J. Jr.; Avens, L.R.; Trujillo, E.A.

    1992-03-24

    A process is described for preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride.

  10. Experimental Study of Gas Hydrate Dynamics

    Science.gov (United States)

    Fandino, O.; Ruffine, L.

    2011-12-01

    Important quantities of methane and other gases are trapped below the seafloor and in the permafrost by an ice-like solid, called gas hydrates or clathrate hydrates. The latter is formed when water is mixing with different gases at high pressures and low temperatures. Due to a their possible use as a source of energy [1] or the problematic related to flow assurance failure in pipelines [2] the understanding of their processes of formation/destabilisation of these structures becomes a goal for many laboratories research as well as industries. In this work we present an experimental study on the stochastic behaviour of hydrate formation from a bulk phase. The method used here for the experiments was to repeat several time the same hydrate formation procedure and to notice the different from one experiment to another. A variable-volume type high-pressure apparatus with two sapphire windows was used. This device, already presented by Ruffine et al.[3], allows us to perform both kinetics and phase equilibrium measurements. Three initial pressure conditions were considered here, 5.0 MPa, 7.5 MPa and 10.0 MPa. Hydrates have been formed, then allowed to dissociate by stepwise heating. The memory effect has also been investigated after complete dissociation. It turned out that, although the thermodynamics conditions of formation and/or destabilization were reproducible. An attempt to determine the influence of pressure on the nucleation induction time will be discussed. References 1. Sum, A. K.; Koh, C. A.; Sloan, E. D., Clathrate Hydrates: From Laboratory Science to Engineering Practice. Industrial & Engineering Chemistry Research 2009, 48, 7457-7465. 2. Sloan, E. D., A changing hydrate paradigm-from apprehension to avoidance to risk management. Fluid Phase Equilibria 2005, 228, 67-74. 3. Ruffine, L.; Donval, J. P.; Charlou, J. L.; Cremière, A.; Zehnder, B. H., Experimental study of gas hydrate formation and destabilisation using a novel high-pressure apparatus. Marine

  11. Thermal Conductivity of Methane-Hydrate

    OpenAIRE

    Krivchikov, A. I.; Gorodilov, B. Ya.; Korolyuk, O. A.; Manzhelii, V. G.; Conrad, H.; Press, W.

    2004-01-01

    The thermal conductivity of the methane hydrate CH4 (5.75 H2O) was measured in the interval 2-140 K using the steady-state technique. The thermal conductivity corresponding to a homogeneous substance was calculated from the measured effective thermal conductivity obtained in the experiment. The temperature dependence of the thermal conductivity is typical for the thermal conductivity of amorphous solids. It is shown that after separation of the hydrate into ice and methane, at 240 K, the ther...

  12. Morphology and side-chain dynamics in hydrated hard α-keratin fibres by 1H solid-state NMR

    Science.gov (United States)

    Melian, Claudiu; Demco, Dan E.; Istrate, Monica; Balaceanu, Andreea; Moldovan, Dumitrita; Fechete, Radu; Popescu, Crisan; Möller, Martin

    2009-10-01

    The effect of hydration on phase composition, aminoacids side-chain dynamics, and domain thickness of hard α-keratin was investigated by 1H solid-state NMR. Decomposition of wide-line 1H NMR spectra was used to determine the phase composition and to obtain information on molecular motion. Proton spin-diffusion NMR experiments using a double-quantum dipolar filter were used to estimate the rigid domain sizes for the hydrated Caucasian hair fibres. The relative domain sizes were obtained from the solution of spin-diffusion equation for cylindrical morphologies in the initial-rate approximation by a novel approach. A qualitative model describing the morphological and molecular dynamics changes induced by hydration was developed.

  13. Bacterial dominance in subseafloor sediments characterized by methane hydrates

    Science.gov (United States)

    Briggs, Brandon R.; Inagaki, Fumio; Morono, Yuki; Futagami, Taiki; Huguet, Carme; Rosell-Mele, Antoni; Lorenson, T.D.; Colwell, Frederick S.

    2015-01-01

    The degradation of organic carbon in subseafloor sediments on continental margins contributes to the largest reservoir of methane on Earth. Sediments in the Andaman Sea are composed of ~ 1% marine-derived organic carbon and biogenic methane is present. Our objective was to determine microbial abundance and diversity in sediments that transition the gas hydrate occurrence zone (GHOZ) in the Andaman Sea. Microscopic cell enumeration revealed that most sediment layers harbored relatively low microbial abundance (103–105 cells cm−3). Archaea were never detected despite the use of both DNA- and lipid-based methods. Statistical analysis of terminal restriction fragment length polymorphisms revealed distinct microbial communities from above, within, and below the GHOZ, and GHOZ samples were correlated with a decrease in organic carbon. Primer-tagged pyrosequences of bacterial 16S rRNA genes showed that members of the phylum Firmicutes are predominant in all zones. Compared with other seafloor settings that contain biogenic methane, this deep subseafloor habitat has a unique microbial community and the low cell abundance detected can help to refine global subseafloor microbial abundance.

  14. Advances in photonic reservoir computing

    Directory of Open Access Journals (Sweden)

    Van der Sande Guy

    2017-05-01

    Full Text Available We review a novel paradigm that has emerged in analogue neuromorphic optical computing. The goal is to implement a reservoir computer in optics, where information is encoded in the intensity and phase of the optical field. Reservoir computing is a bio-inspired approach especially suited for processing time-dependent information. The reservoir’s complex and high-dimensional transient response to the input signal is capable of universal computation. The reservoir does not need to be trained, which makes it very well suited for optics. As such, much of the promise of photonic reservoirs lies in their minimal hardware requirements, a tremendous advantage over other hardware-intensive neural network models. We review the two main approaches to optical reservoir computing: networks implemented with multiple discrete optical nodes and the continuous system of a single nonlinear device coupled to delayed feedback.

  15. Structure and composition analysis of natural gas hydrates: 13C NMR spectroscopic and gas uptake measurements of mixed gas hydrates.

    Science.gov (United States)

    Seo, Yutaek; Kang, Seong-Pil; Jang, Wonho

    2009-09-03

    Gas hydrates are becoming an attractive way of storing and transporting large quantities of natural gas, although there has been little effort to understand the preferential occupation of heavy hydrocarbon molecules in hydrate cages. In this work, we present the formation kinetics of mixed hydrate based on a gas uptake measurement during hydrate formation, and how the compositions of the hydrate phase are varied under corresponding formation conditions. We also examine the effect of silica gel pores on the physical properties of mixed hydrate, including thermodynamic equilibrium, formation kinetics, and hydrate compositions. It is expected that the enclathration of ethane and propane is faster than that of methane early stage hydrate formation, and later methane becomes the dominant component to be enclathrated due to depletion of heavy hydrocarbons in the vapor phase. The composition of the hydrate phase seems to be affected by the consumed amount of natural gas, which results in a variation of heating value of retrieved gas from mixed hydrates as a function of formation temperature. 13C NMR experiments were used to measure the distribution of hydrocarbon molecules over the cages of hydrate structure when it forms either from bulk water or water in silica gel pores. We confirm that 70% of large cages of mixed hydrate are occupied by methane molecules when it forms from bulk water; however, only 19% of large cages of mixed hydrate are occupied by methane molecules when it forms from water in silica gel pores. This result indicates that the fractionation of the hydrate phase with heavy hydrocarbon molecules is enhanced in silica gel pores. In addition when heavy hydrocarbon molecules are depleted in the vapor phase during the formation of mixed hydrate, structure I methane hydrate forms instead of structure II mixed hydrate and both structures coexist together, which is also confirmed by 13C NMR spectroscopic analysis.

  16. Spectral Decomposition and Other Seismic Attributes for Gas Hydrate Prospecting

    Energy Technology Data Exchange (ETDEWEB)

    McConnell, Dan

    2018-02-25

    Studying the sediments at the base of gas hydrate stability is ideal for determining the seismic response to gas hydrate saturation. First, assuming gas migration to the shallow section, this area is more likely to have concentrated gas hydrate because it encompasses the zone in which upward moving buoyant gas transitions to form immobile gas hydrate deposits. Second, this zone is interesting because these areas have the potential to show a hydrate filled zone and a gas filled zone within the same sediments. Third, the fundamental measurement within seismic data is impedance contrasts between velocity*density layers. High saturation gas hydrates and free gas inhabit opposite ends of these measurements making the study of this zone ideal for investigating the seismic characteristics of gas hydrate and, hence, the investigation of other seismic attributes that may indicate gas hydrate fill.

  17. Hydration behaviors of calcium silicate-based biomaterials

    Directory of Open Access Journals (Sweden)

    Yuan-Ling Lee

    2017-06-01

    Conclusion: Mineral oxides might not result in significant changes in the crystal phases or microstructures during the hydration of CS-based biomaterials, but these compounds affected the hydration behavior at the molecular level.

  18. Polymer hydration and stiffness at biointerfaces and related cellular processes.

    Science.gov (United States)

    Kerch, Garry

    2018-01-01

    The direct and indirect (by changing mechanical properties) effects of hydration at interfaces on cellular processes and tissue diseases are reviewed. The essential effect of substrate stiffness on cellular processes was demonstrated in the last decade. The combined effect of surface stiffness and hydration at interfaces has garnered much less attention, though hydration and dehydration play important roles in biological processes. This review focuses on the studies that demonstrate how hydration affects biological processes at interfaces. Elevated sodium and dehydration stimulate inflammatory signaling in endothelial cells and promote atherosclerosis. Various types of implant and blood contacting device coatings with varied surface stiffness and hydration have been reported. Effect of hydration on polymer modulus of elasticity and viscoelasticity was discussed taking into account cells adhesion, migration, proliferation, differentiation on surfaces with various degree of hydration. Future directions of research were considered, including the use of nanotechnology to regulate the hydration degree. Copyright © 2017 Elsevier Inc. All rights reserved.

  19. Methane hydrates in marine sediments - Untapped source of energy

    Digital Repository Service at National Institute of Oceanography (India)

    Jauhari, P.

    will be required to turn this potential resource into gas reserves while developing technologies to conduct safe petroleum operation in hydrate areas, and defining the role of methane hydrates in global climate....

  20. Architecture of an Upper Jurassic barrier island sandstone reservoir, Danish Central Graben:

    DEFF Research Database (Denmark)

    Johannessen, Peter N.; Nielsen, Lars H.; Nielsen, Lars

    2010-01-01

    An unusually thick (c. 88 m), transgressive barrier island and shoreface sandstone succession characterizes the Upper Jurassic Heno Formation reservoir of the Freja oil field situated on the boundary of Denmark and Norway. The development and preservation of such thick transgressive barrier island...... sands is puzzling since a barrier island typically migrates landwards during transgression and only a thin succession of back-barrier and shoreface sands is preserved. Investigation of the development and geometry of the Freja reservoir sandstones is problematic since the reservoir is buried c. 5 km...... sandstones. Using the nearest maximum flooding surface above the reservoir as a datum for well-log correlations, the base of the barrier island succession in the wells is reconstructed as a surface with steep, seaward-dipping palaeotopography. The relief is c. 270 m over a distance of c. 8 km and dips WNW...

  1. Reversible hydration and aqueous exfoliation of the acetate-intercalated layered double hydroxide of Ni and Al: Observation of an ordered interstratified phase

    International Nuclear Information System (INIS)

    Manohara, G.V.; Vishnu Kamath, P.; Milius, Wolfgang

    2012-01-01

    Acetate-intercalated layered double hydroxides (LDHs) of Ni and Al undergo reversible hydration in the solid state in response to the ambient humidity. The LDH with a high layer charge (0.33/formula unit) undergoes facile hydration in a single step, whereas the LDH with a lower layer charge (0.24/formula unit) exhibits an ordered interstratified intermediate, comprising the hydrated and dehydrated layers stacked alternatively. This phase, also known as the staged S-2 phase, coexists with the end members suggesting the existence of a solution-type equilibrium between the S-2 phase and the end members of the hydration cycle. These LDHs also undergo facile aqueous exfoliation into 2–5 nm-thick tactoids with a radial dimension of 0.2–0.5 μm. - Graphical abstract: Schematic of the hydrated, dehydrated and interstratified phases observed during the hydration–dehydration of Ni/Al–CH 3 COO LDH. Highlights: ► Ni/Al-acetate LDHs were synthesized by HPFS method by hydrolysis of acetamide. ► Intercalated acetate ion shows reversible hydration with variation in humidity. ► An ordered interstratified phase was observed during hydration/dehydration cycle. ► A solution type equilibrium is observed between hydration–dehydration phases. ► These LDHs undergo facile aqueous exfoliation.

  2. Gravity observations for hydrocarbon reservoir monitoring

    NARCIS (Netherlands)

    Glegola, M.A.

    2013-01-01

    In this thesis the added value of gravity observations for hydrocarbon reservoir monitoring and characterization is investigated. Reservoir processes and reservoir types most suitable for gravimetric monitoring are identified. Major noise sources affecting time-lapse gravimetry are analyzed. The

  3. Marine Gas Hydrates - An Untapped Non-conventional Energy ...

    Indian Academy of Sciences (India)

    Table of contents. Marine Gas Hydrates - An Untapped Non-conventional Energy Resource · Slide 2 · Slide 3 · Slide 4 · Gas Hydrate Stability Zone · Slide 6 · Slide 7 · Exploration of gas hydrates (seismic) · Characteristics of BSR · Slide 10 · Slide 11 · Slide 12 · Slide 13 · Slide 14 · Slide 15 · Distribution of Gas Hydrates in KG ...

  4. Global Assessment of Methane Gas Hydrates: Outreach for the public and policy makers

    Science.gov (United States)

    Beaudoin, Yannick

    2010-05-01

    The United Nations Environment Programme (UNEP), via its official collaborating center in Norway, GRID-Arendal, is in the process of implementing a Global Assessment of Methane Gas Hydrates. Global reservoirs of methane gas have long been the topic of scientific discussion both in the realm of environmental issues such as natural forces of climate change and as a potential energy resource for economic development. Of particular interest are the volumes of methane locked away in frozen molecules known as clathrates or hydrates. Our rapidly evolving scientific knowledge and technological development related to methane hydrates makes these formations increasingly prospective to economic development. In addition, global demand for energy continues, and will continue to outpace supply for the foreseeable future, resulting in pressure to expand development activities, with associated concerns about environmental and social impacts. Understanding the intricate links between methane hydrates and 1) natural and anthropogenic contributions to climate change, 2) their role in the carbon cycle (e.g. ocean chemistry) and 3) the environmental and socio-economic impacts of extraction, are key factors in making good decisions that promote sustainable development. As policy makers, environmental organizations and private sector interests seek to forward their respective agendas which tend to be weighted towards applied research, there is a clear and imminent need for a an authoritative source of accessible information on various topics related to methane gas hydrates. The 2008 United Nations Environment Programme Annual Report highlighted methane from the Arctic as an emerging challenge with respect to climate change and other environmental issues. Building upon this foundation, UNEP/GRID-Arendal, in conjunction with experts from national hydrates research groups from Canada, the US, Japan, Germany, Norway, India and Korea, aims to provide a multi-thematic overview of the key

  5. Analysis of real-time reservoir monitoring : reservoirs, strategies, & modeling.

    Energy Technology Data Exchange (ETDEWEB)

    Mani, Seethambal S.; van Bloemen Waanders, Bart Gustaaf; Cooper, Scott Patrick; Jakaboski, Blake Elaine; Normann, Randy Allen; Jennings, Jim (University of Texas at Austin, Austin, TX); Gilbert, Bob (University of Texas at Austin, Austin, TX); Lake, Larry W. (University of Texas at Austin, Austin, TX); Weiss, Chester Joseph; Lorenz, John Clay; Elbring, Gregory Jay; Wheeler, Mary Fanett (University of Texas at Austin, Austin, TX); Thomas, Sunil G. (University of Texas at Austin, Austin, TX); Rightley, Michael J.; Rodriguez, Adolfo (University of Texas at Austin, Austin, TX); Klie, Hector (University of Texas at Austin, Austin, TX); Banchs, Rafael (University of Texas at Austin, Austin, TX); Nunez, Emilio J. (University of Texas at Austin, Austin, TX); Jablonowski, Chris (University of Texas at Austin, Austin, TX)

    2006-11-01

    The project objective was to detail better ways to assess and exploit intelligent oil and gas field information through improved modeling, sensor technology, and process control to increase ultimate recovery of domestic hydrocarbons. To meet this objective we investigated the use of permanent downhole sensors systems (Smart Wells) whose data is fed real-time into computational reservoir models that are integrated with optimized production control systems. The project utilized a three-pronged approach (1) a value of information analysis to address the economic advantages, (2) reservoir simulation modeling and control optimization to prove the capability, and (3) evaluation of new generation sensor packaging to survive the borehole environment for long periods of time. The Value of Information (VOI) decision tree method was developed and used to assess the economic advantage of using the proposed technology; the VOI demonstrated the increased subsurface resolution through additional sensor data. Our findings show that the VOI studies are a practical means of ascertaining the value associated with a technology, in this case application of sensors to production. The procedure acknowledges the uncertainty in predictions but nevertheless assigns monetary value to the predictions. The best aspect of the procedure is that it builds consensus within interdisciplinary teams The reservoir simulation and modeling aspect of the project was developed to show the capability of exploiting sensor information both for reservoir characterization and to optimize control of the production system. Our findings indicate history matching is improved as more information is added to the objective function, clearly indicating that sensor information can help in reducing the uncertainty associated with reservoir characterization. Additional findings and approaches used are described in detail within the report. The next generation sensors aspect of the project evaluated sensors and packaging

  6. Application of various water soluble polymers in gas hydrate inhibition

    DEFF Research Database (Denmark)

    Kamal, Muhammad Shahzad; Hussein, Ibnelwaleed A.; Sultan, Abdullah S.

    2016-01-01

    Formation of hydrates in gas transmission lines due to high pressures and low temperatures is a serious problem in the oil and gas industry with potential hazards and/or economic losses. Kinetic hydrate inhibitors are water soluble polymeric compounds that prevent or delay hydrate formation. This...

  7. Small angle X-ray scattering from hydrating tricalcium silicate

    International Nuclear Information System (INIS)

    Vollet, D.

    1983-01-01

    The small-angle X-ray scattering technique was used to study the structural evolution of hydrated tricalcium silicate at room temperature. The changes in specific area of the associated porosity and the evolution of density fluctuations in the solid hydrated phase were deduced from the scattering data. A correlation of these variations with the hydration mechanism is tried. (Author) [pt

  8. Sediment Characteristics of Tennessee Streams and Reservoirs

    National Research Council Canada - National Science Library

    Trimble, Stanley W; Carey, William P

    1984-01-01

    Suspended-sediment and reservoir sedimentation data have been analyzed to determine sediment yields and transport characteristics of Tennessee streams Data from 31 reservoirs plus suspended-sediment...

  9. Gel phase in hydrated calcium dipicolinate

    Science.gov (United States)

    Rajak, Pankaj; Mishra, Ankit; Sheng, Chunyang; Tiwari, Subodh; Krishnamoorthy, Aravind; Kalia, Rajiv K.; Nakano, Aiichiro; Vashishta, Priya

    2017-11-01

    The mineralization of dipicolinic acid (DPA) molecules in bacterial spore cores with Ca2+ ions to form Ca-DPA is critical to the wet-heat resistance of spores. This resistance to "wet-heat" also depends on the physical properties of water and DPA in the hydrated Ca-DPA-rich protoplasm. Using reactive molecular dynamics simulations, we have determined the phase diagram of hydrated Ca-DPA as a function of temperature and water concentration, which shows the existence of a gel phase along with distinct solid-gel and gel-liquid phase transitions. Simulations reveal monotonically decreasing solid-gel-liquid transition temperatures with increasing hydration, which explains the experimental trend of wet-heat resistance of bacterial spores. Our observation of different phases of water also reconciles previous conflicting experimental findings on the state of water in bacterial spores. Further comparison with an unmineralized hydrated DPA system allows us to quantify the importance of Ca mineralization in decreasing diffusivity and increasing the heat resistance of the spore.

  10. A positron annihilation study of hydrated DNA

    DEFF Research Database (Denmark)

    Warman, J. M.; Eldrup, Morten Mostgaard

    1986-01-01

    Positron annihilation measurements are reported for hydrated DNA as a function of water content and as a function of temperature (20 to -180.degree. C) for samples containing 10 and 50% wt of water. The ortho-positronium mean lifetime and its intensity show distinct variations with the degree of ...

  11. Unraveling halide hydration: A high dilution approach

    Science.gov (United States)

    Migliorati, Valentina; Sessa, Francesco; Aquilanti, Giuliana; D'Angelo, Paola

    2014-07-01

    The hydration properties of halide aqua ions have been investigated combining classical Molecular Dynamics (MD) with Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Three halide-water interaction potentials recently developed [M. M. Reif and P. H. Hünenberger, J. Chem. Phys. 134, 144104 (2011)], along with three plausible choices for the value of the absolute hydration free energy of the proton (Δ G^{ominus }_{hyd}[H^+]), have been checked for their capability to properly describe the structural properties of halide aqueous solutions, by comparing the MD structural results with EXAFS experimental data. A very good agreement between theory and experiment has been obtained with one parameter set, namely LE, thus strengthening preliminary evidences for a Δ G^{ominus }_{hyd}[H^+] value of -1100 kJ mol-1 [M. M. Reif and P. H. Hünenberger, J. Chem. Phys. 134, 144104 (2011)]. The Cl-, Br-, and I- ions have been found to form an unstructured and disordered first hydration shell in aqueous solution, with a broad distribution of instantaneous coordination numbers. Conversely, the F- ion shows more ordered and defined first solvation shell, with only two statistically relevant coordination geometries (six and sevenfold complexes). Our thorough investigation on the effect of halide ions on the microscopic structure of water highlights that the perturbation induced by the Cl-, Br-, and I- ions does not extend beyond the ion first hydration shell, and the structure of water in the F- second shell is also substantially unaffected by the ion.

  12. Gypsum hydration: a theoretical and experimental study

    NARCIS (Netherlands)

    Yu, Qingliang; Brouwers, Jos; de Korte, A.C.J.; Fischer, H.B; Bode, K.A.

    2009-01-01

    Calcium sulphate dihydrate (CaSO4·2H2O or gypsum) is used widely as building material because of its excellent fire resistance, aesthetics, and low price. Hemihydrate occurs in two formations of α- and β-type. Among them β-hemihydrate is mainly used to produce gypsum plasterboard since the hydration

  13. Gas hydrate resource quantification in Uruguay

    International Nuclear Information System (INIS)

    Tomasini, J.; De Santa Ana, H.; Veroslavsky, G.

    2012-01-01

    The gas hydrates are crystalline solids formed by natural gas (mostly methane) and water, which are stable in thermobaric conditions given under high pressures and low temperatures. These conditions are given in permafrost zones and continental margin basins offshore in the nature

  14. Gold(III)-Catalyzed Hydration of Phenylacetylene

    Science.gov (United States)

    Leslie, J. Michelle; Tzeel, Benjamin A.

    2016-01-01

    A guided inquiry-based experiment exploring the regioselectivity of the hydration of phenylacetylene is described. The experiment uses an acidic gold(III) catalyst in a benign methanol/water solvent system to introduce students to alkyne chemistry and key principles of green chemistry. The experiment can be easily completed in approximately 2 h,…

  15. A new approach to model mixed hydrates

    Czech Academy of Sciences Publication Activity Database

    Hielscher, S.; Vinš, Václav; Jäger, A.; Hrubý, Jan; Breitkopf, C.; Span, R.

    2018-01-01

    Roč. 459, March (2018), s. 170-185 ISSN 0378-3812 R&D Projects: GA ČR(CZ) GA17-08218S Institutional support: RVO:61388998 Keywords : gas hydrate * mixture * modeling Subject RIV: BJ - Thermodynamics Impact factor: 2.473, year: 2016 https://www. science direct.com/ science /article/pii/S0378381217304983

  16. [Terminal phase hydration, pain and delirium

    DEFF Research Database (Denmark)

    Heick, A.

    2009-01-01

    Hydration of the terminal patient may relieve confusion and complaints of "dry mouth". But it may worsen oedema of the brain, lungs, and extremities, worsen terminal rattling and cause a need for frequent changing of diapers. The decision of whether and how to treat a dying patient with fluids sh...

  17. Alkali binding in hydrated Portland cement paste

    NARCIS (Netherlands)

    Chen, Wei; Brouwers, Jos

    2010-01-01

    The alkali-binding capacity of C–S–H in hydrated Portland cement pastes is addressed in this study. The amount of bound alkalis in C–S–H is computed based on the alkali partition theories firstly proposed by Taylor (1987) and later further developed by Brouwers and Van Eijk (2003). Experimental data

  18. A positron annihilation study of hydrated DNA

    DEFF Research Database (Denmark)

    Warman, J. M.; Eldrup, Morten Mostgaard

    1986-01-01

    Positron annihilation measurements are reported for hydrated DNA as a function of water content and as a function of temperature (20 to -180.degree. C) for samples containing 10 and 50% wt of water. The ortho-positronium mean lifetime and its intensity show distinct variations with the degree...

  19. Changes to the Bakomi Reservoir

    Directory of Open Access Journals (Sweden)

    Kubinský Daniel

    2014-08-01

    Full Text Available This article is focused on the analysis and evaluation of the changes of the bottom of the Bakomi reservoir, the total volume of the reservoir, ecosystems, as well as changes in the riparian zone of the Bakomi reservoir (situated in the central Slovakia. Changes of the water component of the reservoir were subject to the deposition by erosion-sedimentation processes, and were identifed on the basis of a comparison of the present relief of the bottom of reservoir obtained from feld measurements (in 2011 with the relief measurements of the bottom obtained from the 1971 historical maps, (i.e. over a period of 40 years. Changes of landscape structures of the riparian zone have been mapped for the time period of 1949–2013; these changes have been identifed with the analysis of ortophotomaps and the feld survey. There has been a signifcant rise of disturbed shores with low herb grassland. Over a period of 40 years, there has been a deposition of 667 m3 of sediments. The results showed that there were no signifcant changes in the local ecosystems of the Bakomi reservoir in comparison to the other reservoirs in the vicinity of Banská Štiavnica.

  20. TRITIUM RESERVOIR STRUCTURAL PERFORMANCE PREDICTION

    Energy Technology Data Exchange (ETDEWEB)

    Lam, P.S.; Morgan, M.J

    2005-11-10

    The burst test is used to assess the material performance of tritium reservoirs in the surveillance program in which reservoirs have been in service for extended periods of time. A materials system model and finite element procedure were developed under a Savannah River Site Plant-Directed Research and Development (PDRD) program to predict the structural response under a full range of loading and aged material conditions of the reservoir. The results show that the predicted burst pressure and volume ductility are in good agreement with the actual burst test results for the unexposed units. The material tensile properties used in the calculations were obtained from a curved tensile specimen harvested from a companion reservoir by Electric Discharge Machining (EDM). In the absence of exposed and aged material tensile data, literature data were used for demonstrating the methodology in terms of the helium-3 concentration in the metal and the depth of penetration in the reservoir sidewall. It can be shown that the volume ductility decreases significantly with the presence of tritium and its decay product, helium-3, in the metal, as was observed in the laboratory-controlled burst tests. The model and analytical procedure provides a predictive tool for reservoir structural integrity under aging conditions. It is recommended that benchmark tests and analysis for aged materials be performed. The methodology can be augmented to predict performance for reservoir with flaws.

  1. Experimental investigation of smectite hydration from the simulation of 001 X-ray diffraction lines. Implications for the characterization of mineralogical modifications of the 'argilite' from the Meuse - Haute Marne site as a result of a thermal perturbation; Etude experimentale de l'hydratation des smectites par simulation des raies OOl de diffraction des rayons X. Implications pour l'etude d'une perturbation thermique sur la mineralogie de l'argilite du site Meuse-Haute Marne

    Energy Technology Data Exchange (ETDEWEB)

    Ferrage, E

    2004-10-15

    The structural modifications affecting the reactive mineral constituents of the clay barriers (smectite) and possibly resulting from the thermal pulse related to nuclear waste storage are essentially limited to the amount and location of the layer charge deficit. These modifications likely impact the hydration properties of these minerals, and a specific methodology has thus been developed to describe, using simulation of X-ray diffraction profiles (001 reflections), these hydration properties and specifically the heterogeneity resulting from the inter-stratification of different layer types, each exhibiting a specific hydration state. The detailed study of the hydration properties of a low-charge montmorillonite (octahedral charge) has shown that the affinity of the interlayer cation for water rules the hydration state and the thickness of hydrated smectite layers. If the layer charge is increased, the transition between the different hydration states is shifted, following a water desorption isotherm, towards lower relative humidities. In addition, the hydration of studied beidellites (tetrahedral charge) was shown to be more heterogeneous than that of montmorillonites. The developed methodology also allowed describing the structural modifications resulting from a chemical perturbation (chlorinated anionic background, pH). Finally, the link between the thickness of elementary layers and the amount of interlayer water molecules has been evidenced. A new structure model has also been determined for these interlayer species allowing an improved description of their positional distribution in bi-hydrated interlayers. (author)

  2. Effect of minodronic acid hydrate on hip geometry in Japanese women with postmenopausal osteoporosis.

    Science.gov (United States)

    Ito, Masako; Sone, Teruki; Fukunaga, Masao

    2010-05-01

    Dual-energy X-ray absorptiometry-based hip structural analysis was performed to evaluate the effect of a bisphosphonate, minodronic acid hydrate, on the geometry of the proximal femur in Japanese patients with osteoporosis. The subjects were 103 postmenopausal patients (average age 63.9 +/- 6.4 years) with primary osteoporosis. Minodronic acid hydrate was administered orally at a dose of 1 mg/day for 12 months. Significant early responses at 3-6 months after the start of administration were observed in all three regions of the proximal femur (narrow neck, intertrochanter, and shaft) in terms of bone density, geometry, and bone strength indices. The outcomes of therapy included a reduction of the internal diameter of the cortical bone (-0.1, -0.6, and -0.2% in the neck, intertrochanter, and shaft, respectively, at 12 months; not significant) and a significant increase in cortical thickness (3.1, 3.7, and 2.0% in the respective regions at 12 months). Furthermore, minodronic acid hydrate induced a significant enlargement of the cross-sectional bone area, which is related to compressive strength; a significant increase in cross-sectional moment of inertia and section modulus (SM 4.9, 5.8, and 2.9% in the neck, intertrochanter, and shaft, respectively, at 12 months; P < 0.001), which are related to the bending strength; and a significant reduction in buckling ratio (BR -3.0% (P < 0.001), -4.2% (P < 0.001), and -1.4% (P < 0.05) in the respective regions at 12 months), which reflects improved cortical stability. These findings show that minodronic acid hydrate reduces age-related endocortical bone resorption, leading to increased cortical thickness and sustained or enhanced bone strength.

  3. A predictive numerical model for potential mapping of the gas hydrate stability zone in the Gulf of Cadiz

    Science.gov (United States)

    Leon, R.; Somoza, L.

    2009-04-01

    This comunication presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment. The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.

  4. Location of the major seepage zones in ''Las alazanas'' dam reservoir

    International Nuclear Information System (INIS)

    Ortiz A, J.L.; Andreu, B.

    1978-01-01

    The reservoir of the ''Las Alazanas'' dam is located on the Soto La Marina River in the State of Tamaulipas. The filling of the reservoir began on December 24, 1971, and beginning on January 18, 1972, a 10 cm. daily (corresponding to an approximate 5 m 3 /sec outflow) fall in the reservoir level was noted, exclusively due to infiltration and evaporation. It is important to call attention to the existence of several springs below the curtain on the river approximately 8 kms. downstream. There is an increase in the outflow from these springs in accordance with raises in the reservoir level, causing thought about a connection between them. A study made with tracers to verify this connection and to locate the reservoir's infiltration zones is presented in this paper. A geophysical study was made to learn the thickness of the drifting material and the consequent possibility of carrying out some work tending to decrease infiltration. (author)

  5. A reservoir simulation approach for modeling of naturally fractured reservoirs

    Directory of Open Access Journals (Sweden)

    H. Mohammadi

    2012-12-01

    Full Text Available In this investigation, the Warren and Root model proposed for the simulation of naturally fractured reservoir was improved. A reservoir simulation approach was used to develop a 2D model of a synthetic oil reservoir. Main rock properties of each gridblock were defined for two different types of gridblocks called matrix and fracture gridblocks. These two gridblocks were different in porosity and permeability values which were higher for fracture gridblocks compared to the matrix gridblocks. This model was solved using the implicit finite difference method. Results showed an improvement in the Warren and Root model especially in region 2 of the semilog plot of pressure drop versus time, which indicated a linear transition zone with no inflection point as predicted by other investigators. Effects of fracture spacing, fracture permeability, fracture porosity, matrix permeability and matrix porosity on the behavior of a typical naturally fractured reservoir were also presented.

  6. Drilling and Production Testing the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields

    Energy Technology Data Exchange (ETDEWEB)

    Steve McRae; Thomas Walsh; Michael Dunn; Michael Cook

    2010-02-22

    In November of 2008, the Department of Energy (DOE) and the North Slope Borough (NSB) committed funding to develop a drilling plan to test the presence of hydrates in the producing formation of at least one of the Barrow Gas Fields, and to develop a production surveillance plan to monitor the behavior of hydrates as dissociation occurs. This drilling and surveillance plan was supported by earlier studies in Phase 1 of the project, including hydrate stability zone modeling, material balance modeling, and full-field history-matched reservoir simulation, all of which support the presence of methane hydrate in association with the Barrow Gas Fields. This Phase 2 of the project, conducted over the past twelve months focused on selecting an optimal location for a hydrate test well; design of a logistics, drilling, completion and testing plan; and estimating costs for the activities. As originally proposed, the project was anticipated to benefit from industry activity in northwest Alaska, with opportunities to share equipment, personnel, services and mobilization and demobilization costs with one of the then-active exploration operators. The activity level dropped off, and this benefit evaporated, although plans for drilling of development wells in the BGF's matured, offering significant synergies and cost savings over a remote stand-alone drilling project. An optimal well location was chosen at the East Barrow No.18 well pad, and a vertical pilot/monitoring well and horizontal production test/surveillance well were engineered for drilling from this location. Both wells were designed with Distributed Temperature Survey (DTS) apparatus for monitoring of the hydrate-free gas interface. Once project scope was developed, a procurement process was implemented to engage the necessary service and equipment providers, and finalize project cost estimates. Based on cost proposals from vendors, total project estimated cost is $17.88 million dollars, inclusive of design work

  7. Environmental impact studies for gas hydrate production test in the Ulleung Basin, East Sea of Korea

    Science.gov (United States)

    Ryu, Byong-Jae

    2017-04-01

    To develop potential future energy resources, the Korean National Gas Hydrate Program has been carried out since 2005. The program has been supported by the Ministry of Trade, Industry and Energy (MOTIE), and carried out by the Korea Institute of Geoscience and Mineral Resources (KIGAM), the Korea Gas Corporation (KOGAS) and the Korea National Oil Corporation (KNOC) under the management of Gas Hydrate R&D Organization (GHDO). As a part of this national program, geophysical surveys, geological studies on gas hydrates and two deep drilling expeditions were performed. Gas hydrate-bearing sand layers suitable for production using current technologies were found during the Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2) in 2010. Environmental impact studies (EIS) also have been carried out since 2012 by KIGAM in cooperation with domestic and foreign universities and research organizations to ensure safe production test that will be performed in near future. The schedule of production test is being planned. The EIS includes assessment of environmental risks, examination on domestic environmental laws related with production test, collection of basic oceanographic information, and baseline and monitoring surveys. Oceanographic information and domestic environmental laws are already collected and analyzed. Baseline survey has been performed using the in-house developed system, KIGAM Seafloor Observation System (KISOS) since 2013. It will also be performed. R/V TAMHAE II of KIGAM used for KISOS operation. As a part of this EIS, pseudo-3D Chirp survey also was carried out in 2014 to determine the development of fault near the potential testing site. Using KIGAM Seafloor Monitoring System (KIMOS), monitoring survey is planned to be performed from three month before production test to three months after production test. The geophysical survey for determining the change of gas hydrate reservoirs and production-efficiency around the production well would also be

  8. Clathrate Hydrates for Thermal Energy Storage in Buildings: Overview of Proper Hydrate-Forming Compounds

    Directory of Open Access Journals (Sweden)

    Beatrice Castellani

    2014-09-01

    Full Text Available Increasing energy costs are at the origin of the great progress in the field of phase change materials (PCMs. The present work aims at studying the application of clathrate hydrates as PCMs in buildings. Clathrate hydrates are crystalline structures in which guest molecules are enclosed in the crystal lattice of water molecules. Clathrate hydrates can form also at ambient pressure and present a high latent heat, and for this reason, they are good candidates for being used as PCMs. The parameter that makes a PCM suitable to be used in buildings is, first of all, a melting temperature at about 25 °C. The paper provides an overview of groups of clathrate hydrates, whose physical and chemical characteristics could meet the requirements needed for their application in buildings. Simulations with a dynamic building simulation tool are carried out to evaluate the performance of clathrate hydrates in enhancing thermal comfort through the moderation of summer temperature swings and, therefore, in reducing energy consumption. Simulations suggest that clathrate hydrates have a potential in terms of improvement of indoor thermal comfort and a reduction of energy consumption for cooling. Cooling effects of 0.5 °C and reduced overheating hours of up to 1.1% are predicted.

  9. MORPHOLOGY OF METHANE HYDRATE HOST SEDIMENTS.

    Energy Technology Data Exchange (ETDEWEB)

    JONES,K.W.; FENG,H.; TOMOV,S.; WINTER,W.J.; EATON,M.; MAHAJAN,D.

    2004-12-01

    Results from simulated experiments in several laboratories show that host sediments influence hydrate formation in accord with known heterogeneity of host sediments at sites of gas hydrate occurrence (1). For example, in Mackenzie Delta, NWT Canada (Mallik 2L-38 well), coarser-grained units (pore-filling model) are found whereas in the Gulf of Mexico, the found hydrate samples do not appear to be lithologically controlled. We have initiated a systematic study of sediments, initially focusing on samples from various depths at a specific site, to establish a correlation with hydrate occurrence (or variations thereof) to establish differences in their microstructure, porosity, and other associated properties. The synchrotron computed microtomography (CMT) set-up at the X-27A tomography beam line at the National Synchrotron Light Source (NSLS), Brookhaven National Laboratory was used as a tool to study sediments from Blake Ridge at three sub bottom depths of 0.2, 50, and 667 meters. Results from the tomographic analysis of the deepest sample (667 m) are presented here to illustrate how tomography can be used to obtain new insights into the structures of methane hydrate host sediments. The investigation shows the internal grain/pore space resolution in the microstructure and a 3-D visualization of the connecting pathways obtained following data segmentation into pore space and grains within the sediment sample. The analysis gives the sample porosity, specific surface area, mean particle size, and tortuosity, as well. An earlier report on the experimental program has been given by Mahajan et al. (2).

  10. THE SURDUC RESERVOIR (ROMANIA

    Directory of Open Access Journals (Sweden)

    Niculae Iulian TEODORESCU

    2008-06-01

    Full Text Available The Surduc reservoir was projected to ensure more water when water is scarce and to thus provide especially the city Timisoara, downstream of it with water.The accumulation is placed on the main affluent of the Bega river, Gladna in the upper part of its watercourse.The dam behind which this accumulation was created is of a frontal type made of enrochements with a masque made of armed concrete on the upstream part and protected/sustained by grass on the downstream. The dam is 130m long on its coping and a constructed height of 34 m. It is also endowed with spillway for high water and two bottom outlets formed of two conduits, at the end of which is the microplant. The second part of my paper deals with the hydrometric analysis of the Accumulation Surduc and its impact upon the flow, especially the maximum run-off. This influence is exemplified through the high flood from the 29th of July 1980, the most significant flood recorded in the basin with an apparition probability of 0.002%.

  11. Solid state interconversion between anhydrous norfloxacin and its hydrates.

    Science.gov (United States)

    Chongcharoen, Wanchai; Byrn, Stephen R; Sutanthavibul, Narueporn

    2008-01-01

    This work is focused on characterizing and evaluating the solid state interconversion of norfloxacin (NF) hydrates. Four stoichiometric NF hydrates, dihydrate, hemipentahydrate, trihydrate, pentahydrate and a disordered NF state, were generated by various methods and characterized by X-ray powder diffractometry (XRPD), thermal analysis and Karl Fisher titrimetry. XRPD patterns of all NF hydrates exhibited crystalline structures. NF hydrate conversion was studied with respect to mild elevated temperature and various degrees of moisture levels. NF hydrates transformed to anhydrous NF Form A after gentle heating at 60 degrees C for 48 h except dihydrate and trihydrate where mixture in XRPD patterns between anhydrous NF Form A and former structures existed. Desiccation of NF hydrates at 0% RH for 7 days resulted in only partial removal of water molecules from the hydrated structures. The hydrated transitional phase and the disordered NF state were obtained from the incomplete dehydration of NF hydrates after thermal treatment and pentahydrate NF after desiccation, respectively. Anhydrous NF Form A and NF hydrates transformed to pentahydrate NF when exposed to high moisture environment except dihydrate. In conclusion, surrounding moisture levels, temperatures and the duration of exposure strongly influenced the interconversion pathways and stoichiometry of anhydrous NF and its hydrates. (c) 2007 Wiley-Liss, Inc.

  12. A method of harvesting gas hydrates from marine sediments

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, H.Q.; Brill, J.P.; Sarica, C. [Tulsa Univ., Tulsa, OK (United States). Dept. of Petroleum Engineering

    2008-07-01

    Methane is known to exist in gas hydrates, but low productivity is expected for gas production from gas hydrates in marine sediments because of the shallow depths, low hydrate concentration, low permeability of the gas hydrate stability zone, lack of driving pressure and the slow melting process. This paper presented a newly developed methane harvesting method which aims to overcome technical barriers, maintain cost and energy efficiencies and minimize safety and environmental concerns. The method is based on the concept of capturing the gas released from hydrate dissociation in the sediments. The captured gases can reform hydrates inside and overhead receiver, which once full, can be lifted to shallow warm water for gas collection. This simple and open production system does not require high pressure and does not involve any flow assurance issues. As such, technical difficulties, safety issues and environmental concerns are minimized. The proposed gas harvesting method makes the best use of the nature of hydrates and the subsea pressure and temperature profiles. It combines many new concepts, including electrically adding heat inside the hydrate rich sediments to release gas, using an overhead receiver to capture the gas, allowing the gas to reform hydrates again in the overhead receiver, and lifting produced hydrates to warm water where it can be released and collected. It was concluded that this newly proposed production system enables the development of massive hydrate production fields on the sea bed with high production rates that are economically viable. 4 refs., 7 figs.

  13. Methane hydrate in the global organic carbon cycle

    Science.gov (United States)

    Kvenvolden, K.A.

    2002-01-01

    The global occurrence of methane hydrate in outer continental margins and in polar regions, and the magnitude of the amount of methane sequestered in methane hydrate suggest that methane hydrate is an important component in the global organic carbon cycle. Various versions of this cycle have emphasized the importance of methane hydrate, and in the latest version the role of methane hydrate is considered to be analogous to the workings of an electrical circuit. In this circuit the methane hydrate is a condenser and the consequences of methane hydrate dissociation are depicted as a resistor and inductor, reflecting temperature change and changes in earth surface history. These consequences may have implications for global change including global climate change.

  14. Understanding the True Stimulated Reservoir Volume in Shale Reservoirs

    KAUST Repository

    Hussain, Maaruf

    2017-06-06

    Successful exploitation of shale reservoirs largely depends on the effectiveness of hydraulic fracturing stimulation program. Favorable results have been attributed to intersection and reactivation of pre-existing fractures by hydraulically-induced fractures that connect the wellbore to a larger fracture surface area within the reservoir rock volume. Thus, accurate estimation of the stimulated reservoir volume (SRV) becomes critical for the reservoir performance simulation and production analysis. Micro-seismic events (MS) have been commonly used as a proxy to map out the SRV geometry, which could be erroneous because not all MS events are related to hydraulic fracture propagation. The case studies discussed here utilized a fully 3-D simulation approach to estimate the SRV. The simulation approach presented in this paper takes into account the real-time changes in the reservoir\\'s geomechanics as a function of fluid pressures. It is consisted of four separate coupled modules: geomechanics, hydrodynamics, a geomechanical joint model for interfacial resolution, and an adaptive re-meshing. Reservoir stress condition, rock mechanical properties, and injected fluid pressure dictate how fracture elements could open or slide. Critical stress intensity factor was used as a fracture criterion governing the generation of new fractures or propagation of existing fractures and their directions. Our simulations were run on a Cray XC-40 HPC system. The studies outcomes proved the approach of using MS data as a proxy for SRV to be significantly flawed. Many of the observed stimulated natural fractures are stress related and very few that are closer to the injection field are connected. The situation is worsened in a highly laminated shale reservoir as the hydraulic fracture propagation is significantly hampered. High contrast in the in-situ stresses related strike-slip developed thereby shortens the extent of SRV. However, far field nature fractures that were not connected to

  15. Radioactive thickness gauge (1962)

    International Nuclear Information System (INIS)

    Guizerix, J.

    1962-01-01

    The author describes a thickness gauge in which the scintillating crystal detector alternately 'sees' a radioactive source through the material which is to be measured and then a control source of the same material; the radiations are separated in time by an absorbing valve whose sections are alternately full and hollow. The currents corresponding to the two sources are separated beyond the photomultiplier tube by a detector synchronized with the rotation of the valve. The quotient of these two currents is then obtained with a standard recording potentiometer. It is found that the average value of the response which is in the form G = f(I 1 /I 2 ) is not affected by decay of the radioactive sources, and that it is little influenced by variations of high tension, temperature, or properties of the air in the source detector interval. The performance of the gauge is given. (author) [fr

  16. Chickamauga reservoir embayment study - 1990

    Energy Technology Data Exchange (ETDEWEB)

    Meinert, D.L.; Butkus, S.R.; McDonough, T.A.

    1992-12-01

    The objectives of this report are three-fold: (1) assess physical, chemical, and biological conditions in the major embayments of Chickamauga Reservoir; (2) compare water quality and biological conditions of embayments with main river locations; and (3) identify any water quality concerns in the study embayments that may warrant further investigation and/or management actions. Embayments are important areas of reservoirs to be considered when assessments are made to support water quality management plans. In general, embayments, because of their smaller size (water surface areas usually less than 1000 acres), shallower morphometry (average depth usually less than 10 feet), and longer detention times (frequently a month or more), exhibit more extreme responses to pollutant loadings and changes in land use than the main river region of the reservoir. Consequently, embayments are often at greater risk of water quality impairments (e.g. nutrient enrichment, filling and siltation, excessive growths of aquatic plants, algal blooms, low dissolved oxygen concentrations, bacteriological contamination, etc.). Much of the secondary beneficial use of reservoirs occurs in embayments (viz. marinas, recreation areas, parks and beaches, residential development, etc.). Typically embayments comprise less than 20 percent of the surface area of a reservoir, but they often receive 50 percent or more of the water-oriented recreational use of the reservoir. This intensive recreational use creates a potential for adverse use impacts if poor water quality and aquatic conditions exist in an embayment.

  17. LABORATORY STRATEGIES FOR HYDRATE FORMATION IN FINE-GRAINED SEDIMENTS

    KAUST Repository

    Lei, L.

    2018-04-02

    Fine‐grained sediments limit hydrate nucleation, shift the phase boundary and hinder gas supply. Laboratory experiments in this study explore different strategies to overcome these challenges, including the use of a more soluble guest molecule rather than methane, grain‐scale gas‐storage within porous diatoms, ice‐to‐hydrate transformation to grow lenses at predefined locations, forced gas injection into water saturated sediments, and long‐term guest molecule transport. Tomographic images, thermal and pressure data provide rich information on hydrate formation and morphology. Results show that hydrate formation is inherently displacive in fine‐grained sediments; lenses are thicker and closer to each other in compressible, high specific surface area sediments subjected to low effective stress. Temperature and pressure trajectories follow a shifted phase boundary that is consistent with capillary effects. Exo‐pore growth results in freshly formed hydrate with a striped and porous structure; this open structure becomes an effective pathway for gas transport to the growing hydrate front. Ice‐to‐hydrate transformation goes through a liquid stage at pre‐melt temperatures; then, capillarity and cryogenic suction compete, and some water becomes imbibed into the sediment faster than hydrate reformation. The geometry of hydrate lenses and the internal hydrate structure continue evolving long after the exothermal response to hydrate formation has completely decayed. Multiple time‐dependent processes occur during hydrate formation, including gas, water and heat transport, sediment compressibility, reaction rate and the stochastic nucleation process. Hydrate formation strategies conceived for this study highlight the inherent difficulties in emulating hydrate formation in fine‐grained sediments within the relatively short time‐scale available for laboratory experiments.

  18. Spectroscopic determination of gas-water interactions in clathrate hydrates

    International Nuclear Information System (INIS)

    Richardson, H.H. Jr.

    1985-01-01

    The technique of forming clathrate hydrates by first forming the amorphous deposits of gas-water mixture and, secondly, annealing this deposit was used to form the clathrate hydrates of ethylene oxide, hydrogen sulfide and sulfur dioxide. Once the clathrate hydrate formed as a thin film on the CsI substrate, the infrared spectrum of these hydrates could be obtained. The clathrate hydrates could be irradiated with 1.7 MeV electrons to promote high proton concentrations in the clathrate hydrate lattice at low temperatures (approx.30K) where the Bjerrum defects in the lattice are not mobile. The ring breathing model of ethylene oxide in the clathrate hydrate can be assigned. It was possible to incorporate D 2 O into the hydrogen bonded lattice of the ethylene oxide clathrate hydrate by growing the clathrate hydrate epitaxially on a thin film of clathrate hydrate at 100 K. The half-life of the D 2 O molecules in the ethylene oxide clathrate hydrate was only 9 minutes at 120 K. The activation energy determined from the hopping rate constant in ethylene oxide clathrate hydrate was 4.5 +/- 1.8 Kcal/mole. Irradiation of the ethylene oxide clathrate hydrate with 1.7 MeV electrons transformed some of the ethylene oxide molecules in the cages to (a) CH 2 = CH 2 , (b) CH 2 = C = O, (c) CH 3 -CH 2 -OH, (d) CO 2 , and (e) CO. A steady state concentration of coupled HOD was maintained in irradiated samples of ethylene oxide clathrate hydrates at a temperature around 80 K. The enclathrated H 2 S molecule in the small cages had a different infrared spectrum (broad band complex centered at 2600 cm -1 ) from the H 2 S molecules which had been enclathrated in the large cages (broad band complex centered at 2550 cm -1 )

  19. Reservoir characterization of Pennsylvanian Sandstone Reservoirs. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Kelkar, M.

    1992-09-01

    This annual report describes the progress during the second year of a project on Reservoir Characterization of Pennsylvanian Sandstone Reservoirs. The report is divided into three sections: (i) reservoir description and scale-up procedures; (ii) outcrop investigation; (iii) in-fill drilling potential. The first section describes the methods by which a reservoir can be characterized, can be described in three dimensions, and can be scaled up with respect to its properties, appropriate for simulation purposes. The second section describes the progress on investigation of an outcrop. The outcrop is an analog of Bartlesville Sandstone. We have drilled ten wells behind the outcrop and collected extensive log and core data. The cores have been slabbed, photographed and the several plugs have been taken. In addition, minipermeameter is used to measure permeabilities on the core surface at six inch intervals. The plugs have been analyzed for the permeability and porosity values. The variations in property values will be tied to the geological descriptions as well as the subsurface data collected from the Glen Pool field. The third section discusses the application of geostatistical techniques to infer in-fill well locations. The geostatistical technique used is the simulated annealing technique because of its flexibility. One of the important reservoir data is the production data. Use of production data will allow us to define the reservoir continuities, which may in turn, determine the in-fill well locations. The proposed technique allows us to incorporate some of the production data as constraints in the reservoir descriptions. The technique has been validated by comparing the results with numerical simulations.

  20. Geologic implications of gas hydrates in the offshore of India: results of the National Gas Hydrate Program Expedition 01

    Science.gov (United States)

    Collett, Timothy S.; Boswell, Ray; Cochran, J.R.; Kumar, Pushpendra; Lall, Malcolm; Mazumdar, Aninda; Ramana, Mangipudi Venkata; Ramprasad, Tammisetti; Riedel, Michael; Sain, Kalachand; Sathe, Arun Vasant; Vishwanath, Krishna

    2014-01-01

    The Indian National Gas Hydrate Program Expedition 01 (NGHP-01) is designed to study the occurrence of gas hydrate along the passive continental margin of the Indian Peninsula and in the Andaman convergent margin, with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. The NGHP-01 expedition established the presence of gas hydrates in the Krishna-Godavari and Mahanadi Basins, and the Andaman Sea. The expedition discovered in the Krishna-Godavari Basin one of the thickest gas hydrate accumulations ever documented, in the Andaman Sea one of the thickest and deepest gas hydrate stability zones in the world, and established the existence of a fully developed gas hydrate petroleum system in all three basins.

  1. Petroleum reservoir data for testing simulation models

    Energy Technology Data Exchange (ETDEWEB)

    Lloyd, J.M.; Harrison, W.

    1980-09-01

    This report consists of reservoir pressure and production data for 25 petroleum reservoirs. Included are 5 data sets for single-phase (liquid) reservoirs, 1 data set for a single-phase (liquid) reservoir with pressure maintenance, 13 data sets for two-phase (liquid/gas) reservoirs and 6 for two-phase reservoirs with pressure maintenance. Also given are ancillary data for each reservoir that could be of value in the development and validation of simulation models. A bibliography is included that lists the publications from which the data were obtained.

  2. Detecting surface oil slick related to gas hydrate/petroleum on the ocean bed of South China Sea by ENVI/ASAR radar data

    Science.gov (United States)

    Wang, Yunpeng; Chen, Duofu; Song, Zhiguang

    2013-03-01

    For exploring the distribution of oil slick related to gas hydrate or petroleum in the northern part of South China Sea and evaluating the potential of ENVI/ASAR radar data for detecting oil slick, this paper tries to detect the oil slick on ocean surface of some potential areas in South China Sea and map oil slick from anomaly area in radar image. Seven surface oil slicks in Qiongdongnan Basin and four potential targets of oil slicks in Taixi-Dongsha Basin were detected and extracted by using ENIV/ASAR data. The anomalies of the radar image representing oil slick are validated by in-site sampling and laboratory analyzing. The Gas Chromatograph (GC) results of the extracted oil from the water samples gathered from the sites of detected oil slick demonstrate a typical composition of oil rather than that of ocean microbial origins, and Total Organic Carbon (TOC) concentrations in two designed vertical profiles keep steady in different depths, showing that the organic contents in water column are steady from the deep area to ocean surface. These results suggest the detected oil slick is a thin floating oil rather than a thick spill. Influencing factors to the results of oil slick detection including wind speed, current, small islands and capes as well as deep-sea petroleum reservoirs are discussed. The results in this study exhibit that extracting the anomaly signals related to oil slick related to oil/gas seeps using image processing techniques from ENVI/ASAR data is helpful to predict anomaly areas as potential targets for further exploration in this area.

  3. Computational Material Modeling of Hydrated Cement Paste Calcium Silicate Hydrate (C-S-H) Chemistry Structure - Influence of Magnesium Exchange on Mechanical Stiffness: C-S-H Jennite

    Science.gov (United States)

    2015-04-27

    hydrated cement paste constituent - calcium silicate hydrate (C-S-H) based on its material chemistry structure are studied following a molecular dynamics...2015 Approved for public release; distribution is unlimited. Computational Material Modeling of Hydrated Cement Paste Calcium Silicate Hydrate (C-S-H...1601 East Market Street Greensboro, NC 27411 -0001 ABSTRACT Computational Material Modeling of Hydrated Cement Paste Calcium Silicate Hydrate (C-S-H

  4. Methane hydrates and contemporary climate change

    Science.gov (United States)

    Ruppel, Carolyn D.

    2011-01-01

    As the evidence for warming climate became better established in the latter part of the 20th century (IPCC 2001), some scientists raised the alarm that large quantities of methane (CH4) might be liberated by widespread destabilization of climate-sensitive gas hydrate deposits trapped in marine and permafrost-associated sediments (Bohannon 2008, Krey et al. 2009, Mascarelli 2009). Even if only a fraction of the liberated CH4 were to reach the atmosphere, the potency of CH4 as a greenhouse gas (GHG) and the persistence of its oxidative product (CO2) heightened concerns that gas hydrate dissociation could represent a slow tipping point (Archer et al. 2009) for Earth's contemporary period of climate change.

  5. Experimental techniques for cement hydration studies

    Directory of Open Access Journals (Sweden)

    Andreas Luttge

    2011-10-01

    Full Text Available Cement hydration kinetics is a complex problem of dissolution, nucleation and growth that is still not well understood, particularly in a quantitative way. While cement systems are unique in certain aspects they are also comparable to natural mineral systems. Therefore, geochemistry and particularly the study of mineral dissolution and growth may be able to provide insight and methods that can be utilized in cement hydration research. Here, we review mainly what is not known or what is currently used and applied in a problematic way. Examples are the typical Avrami approach, the application of Transition State Theory (TST to overall reaction kinetics and the problem of reactive surface area. Finally, we suggest an integrated approach that combines vertical scanning interferometry (VSI with other sophisticated analytical techniques such as atomic force microscopy (AFM and theoretical model calculations based on a stochastic treatment.

  6. Modelling porewater chemistry in hydrated Portland cement

    International Nuclear Information System (INIS)

    Berner, U.R.

    1987-01-01

    Extensive employment of concrete is foreseen in radioactive waste repositories. A prerequisite for modelling the interactions between concrete and formation waters is characterization of the concrete system. Available experimental data from high pressure squeezing of cement pore-water indicate that, besides the high pH due to alkali hydroxide dissolution, cement composition itself influences the solubility determining solid phases. A model which simulates the hydration of Portland cement assuming complete hydration of the main clinker minerals is presented. The model also includes parameters describing the reactions between the cement and blending agents. Comparison with measured pore-water data generally gives a consistent picture and, as expected, the model gives correct predictions for pure Portland cements. For blended cements, the required additional parameters can, to some extent, be derived from pore-water analysis. 14 references, 1 figure, 4 tables

  7. Phosphate vibrations as reporters of DNA hydration

    Science.gov (United States)

    Corcelli, Steven

    The asymmetric phosphate stretch vibrational frequency is extraordinarily sensitive to its local solvent environment. Using density functional theory calculations on the model compound dimethyl phosphate, the asymmetric phosphate stretch vibrational frequency was found to shift linearly with the magnitude of an electric field along the symmetry axis of the PO2 moiety (i.e. the asymmetric phosphate stretch is an excellent linear vibrational Stark effect probe). With this linear relationship established, asymmetric phosphate stretch vibrational frequencies were computed during the course of a molecular dynamics simulation of fully hydrated DNA. Moreover, contributions to shifts in the frequencies from subpopulations of water molecules (e.g. backbone, minor groove, major groove, etc.) were calculated to reveal how phosphate vibrations report the onset of DNA hydration in experiments that vary the relative humidity of non-condensing (dry) DNA samples.

  8. Effects of hydration on blood rheology.

    Science.gov (United States)

    Vlastos, George A; Tangney, Christine C; Rosenson, Robert S

    2003-01-01

    This study investigated the impact of oral fluid intake on blood rheology of 17 healthy adults following a 12-14 hour overnight fast from food and drink. An oral fluid load of 500 ml was consumed every 30 minutes for 2 hours. Blood viscosity values at shear rates of 1, 10 and 100 s(-1) were reduced (p<0.05 to p<0.01) at 30 and 120 minutes following hydration; however, these differences were not significant after hematocrit correction. With fluid intake, both uncorrected and corrected viscous component of blood viscoelasticity at oscillatory shear rate of 1 s(-1) and at a constant frequency of 2 Hz were reduced (p<0.05 to p<0.001) at all time points as compared to fasting values. The corrected elastic component of blood viscoelasticity increased 90 minutes after hydration (p<0.05). An overnight fast is accompanied by rheological abnormalities that are altered by fluid intake.

  9. Gravity observations for hydrocarbon reservoir monitoring

    OpenAIRE

    Glegola, M.A.

    2013-01-01

    In this thesis the added value of gravity observations for hydrocarbon reservoir monitoring and characterization is investigated. Reservoir processes and reservoir types most suitable for gravimetric monitoring are identified. Major noise sources affecting time-lapse gravimetry are analyzed. The added value of gravity data for reservoir monitoring and characterization is analyzed within closed-loop reservoir management concept. Synthetic 2D and 3D numerical experiments are performed where var...

  10. Mesostructure from hydration gradients in demosponge biosilica.

    Science.gov (United States)

    Neilson, James R; George, Nathan C; Murr, Meredith M; Seshadri, Ram; Morse, Daniel E

    2014-04-22

    Organisms of the phylum Porifera, that is, sponges, utilize enzymatic hydrolysis to concatenate bioavailable inorganic silicon to produce lightweight, strong, and often flexible skeletal elements called spicules. In their optical transparency, these remarkable biomaterials resemble fused silica, despite having been formed under ambient marine biological conditions. Although previous studies have elucidated the chemical mechanisms of spicule formation and revealed the extensive hydration of these glasses, their precise composition and local and medium-range structures had not been determined. We have employed a combination of compositional analysis, (1) H and (29) Si solid-state nuclear magnetic resonance spectroscopy, and synchrotron X-ray total scattering to characterize spicule-derived silica produced by the demosponge Tethya aurantia. These studies indicate that the materials are highly hydrated, but in an inhomogeneous manner. The spicule-derived silica is, on average, perfectly dense for the given extent of hydration and regions of fully condensed and unstrained SiO networks persist throughout each monolithic spicule. To accommodate chemical strain and defects, the extensive hydration is concentrated in distinct regions that give rise to mesostructural features. The chemistry responsible for producing spicule silica resembles hydrolytic sol-gel processing, which offers exceptional control over the precise local atomic arrangement of materials. However, the specific processing involved in forming the sponge spicule silica further results in regions of fully condensed silica coexisting with regions of incomplete condensation. This mesostructure suggests a mechanism for atomistic defect tolerance and strain relief that may account for the unusual mechanical properties of the biogenic spicules. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Sherbet natural gas resources. ; Gas hydrate. Sherbet jo no tennen gas shigen. ; Gas hydrate

    Energy Technology Data Exchange (ETDEWEB)

    Okuda, Y. (Geological Survey of Japan, Tsukuba (Japan))

    1993-04-01

    The present of methane hydrate exploration is reviewed. Methane hydrate contains more than 95% methane in cages composed of water molecules, and it was probably formed from saturated methane in water and excess methane under specific temperature and pressure by biofermentation or pyrolysis of petroleum. It is found only under the sea bottom around continents or permanent frozen soil districts, and nearly 40 expected sites have been found at 500-5,000 m in depth of water, while 8 ones in Siberia, Canada and Alaska. In Japan, the Nankai trough, Kurile trench and Okushiri ridge are expected sites. Control of hydrate decomposition rates is essential for exploitation, while promotion of hydrate decomposition for methane gas production. The estimated amount of methane hydrate is larger in sea area than land area, and it is estimated to be 2.5-5 [times] 10[sup 14] m[sup 3] in the whole sea area of the globe, while 6 [times] 10[sup 12] m[sup 3] in the sea area around Japan. 17 refs., 6 figs., 4 tabs.

  12. Gas hydrate occurrences in the Danube Delta, Western Black Sea: Results from 2D and 3D controlled source electromagnetics

    Science.gov (United States)

    Schwalenberg, Katrin; Hölz, Sebastian; Gehrmann, Romina; Rippe, Dennis; Dannowski, Anke; Zander, Timo; Duan, Shuangmin; Jegen, Marion; Bialas, Jörg

    2017-04-01

    Marine controlled source electromagnetic (CSEM) data have been collected over gas hydrate targets in the Danube Delta off the coasts of Bulgaria and Romania in early 2014 during voyage MSM35 on R/V Maria S. MERIAN. The cruise was part of the German SUGAR Project, a joint venture project with the goal to study submarine gas hydrates as a source of methane. Within European waters the Black Sea is one of the most prospective hydrocarbon areas. Thick sedimentary basins, the existence of an extended gas hydrate stability zone and the observation of multiple bottom simulating reflectors (BSR) in the western part indicate a huge gas hydrate potential in sandy sediments. Low pore-water salinities between 1 and 4 ppt have been observed in borehole data at depths below 30 mbsf, and are attributed to sea level low stands in the past. 2D and 3D CSEM data sets have been collected over one of the channel levee systems of the Danube Delta fan. High-resolution 2D and 3D seismic, and OBS data are available in the same target area providing structural information and porosity profiles from seismic velocity data. Analysis of subsets of the 3D CSEM data reveal pore-water salinities around 4 ppt for the shallow sediment section, thus are not as low as suggested by the borehole data. The inversion of both 2D and 3D CSEM data sets reveal highly anomalous resistivities within the gas hydrate stability field. We believe that high gas hydrate saturations are the likely cause, as low pore-water salinities are not sufficient to explain the high resistivities, seismic data indicate no clear gas migration pathways through the stability field, nor do hydro-acoustic data show areas of gas seepage which are confined to the landward edge of the stability field. Estimates of the gas hydrate saturation are commonly derived from Archie's Law, and strongly depend on the proper choice of input parameters. We apply porosities from seismic velocity profiles, pore-water resistivities derived from salinity

  13. Intermolecular Hydrogen Transfer in Isobutane Hydrate

    Directory of Open Access Journals (Sweden)

    Takeshi Sugahara

    2012-05-01

    Full Text Available Electron spin resonance (ESR spectra of butyl radicals induced with γ-ray irradiation in the simple isobutane (2-methylpropane hydrate (prepared with deuterated water were investigated. Isothermal annealing results of the γ-ray-irradiated isobutane hydrate reveal that the isobutyl radical in a large cage withdraws a hydrogen atom from the isobutane molecule through shared hexagonal-faces of adjacent large cages. During this “hydrogen picking” process, the isobutyl radical is apparently transformed into a tert-butyl radical, while the sum of isobutyl and tert-butyl radicals remains constant. The apparent transformation from isobutyl to tert-butyl radicals is an irreversible first-order reaction and the activation energy was estimated to be 35 ± 3 kJ/mol, which was in agreement with the activation energy (39 ± 5 kJ/mol of hydrogen picking in the γ-ray-irradiated propane hydrate with deuterated water.

  14. Gas Hydrate Growth Kinetics: A Parametric Study

    Directory of Open Access Journals (Sweden)

    Remi-Erempagamo Tariyemienyo Meindinyo

    2016-12-01

    Full Text Available Gas hydrate growth kinetics was studied at a pressure of 90 bars to investigate the effect of temperature, initial water content, stirring rate, and reactor size in stirred semi-batch autoclave reactors. The mixing energy during hydrate growth was estimated by logging the power consumed. The theoretical model by Garcia-Ochoa and Gomez for estimation of the mass transfer parameters in stirred tanks has been used to evaluate the dispersion parameters of the system. The mean bubble size, impeller power input per unit volume, and impeller Reynold’s number/tip velocity were used for analyzing observed trends from the gas hydrate growth data. The growth behavior was analyzed based on the gas consumption and the growth rate per unit initial water content. The results showed that the growth rate strongly depended on the flow pattern in the cell, the gas-liquid mass transfer characteristics, and the mixing efficiency from stirring. Scale-up effects indicate that maintaining the growth rate per unit volume of reactants upon scale-up with geometric similarity does not depend only on gas dispersion in the liquid phase but may rather be a function of the specific thermal conductance, and heat and mass transfer limitations created by the limit to the degree of the liquid phase dispersion is batched and semi-batched stirred tank reactors.

  15. Polymorphism in Br2 clathrate hydrates.

    Science.gov (United States)

    Goldschleger, I U; Kerenskaya, G; Janda, K C; Apkarian, V A

    2008-02-07

    The structure and composition of bromine clathrate hydrate has been controversial for more than 170 years due to the large variation of its observed stoichiometries. Several different crystal structures were proposed before 1997 when Udachin et al. (Udachin, K. A.; Enright, G. D.; Ratcliffe, C. I.; Ripmeester, J. A. J. Am. Chem. Soc. 1997, 119, 11481) concluded that Br2 forms only the tetragonal structure (TS-I). We show polymorphism in Br2 clathrate hydrates by identifying two distinct crystal structures through optical microscopy and resonant Raman spectroscopy on single crystals. After growing TS-I crystals from a liquid bromine-water solution, upon dropping the temperature slightly below -7 degrees C, new crystals of cubic morphology form. The new crystals, which have a limited thermal stability range, are assigned to the CS-II structure. The two structures are clearly distinguished by the resonant Raman spectra of the enclathrated Br2, which show long overtone progressions and allow the extraction of accurate vibrational parameters: omega(e) = 321.2 +/- 0.1 cm(-1) and omega(e)x(e) = 0.82 +/- 0.05 cm(-1) in TS-I and omega(e) = 317.5 +/- 0.1 cm(-1) and omega(e)x(e) = 0.70 +/- 0.1 cm(-1) in CS-II. On the basis of structural analysis, the discovery of the CS-II crystals implies stability of a large class of bromine hydrate structures and, therefore, polymorphism.

  16. The role of hydration in vocal fold physiology.

    Science.gov (United States)

    Sivasankar, Mahalakshmi; Leydon, Ciara

    2010-06-01

    Increased vocal fold hydration is a popular target in the prevention and management of voice disorders. Current intervention strategies focus on enhancing both systemic (internal) and superficial (surface) hydration. We review relevant bench and human research on the role of hydration in vocal fold physiology. Bench and human studies provide converging evidence that systemic and superficial dehydration are detrimental to vocal fold physiology. Dehydration challenges increase the viscous properties of excised vocal fold tissue. Systemic, superficial, and combined drying challenges increase aerodynamic and acoustic measures of voice production in speakers. Emerging theoretical and clinical data suggest that increasing both systemic and superficial hydration levels may benefit voice production; however, robust evidence for positive outcomes of hydration treatments is lacking. Increased systemic and superficial vocal fold hydration as a component of vocal hygiene may improve overall health and efficiency of the vocal apparatus. However, continued exploration of biological mechanisms regulating vocal fold hydration is needed to optimize clinical hydration interventions. Specifically, the development of hydration treatments that maximize positive phonatory outcomes will necessitate understanding of the signaling pathways linking systemic and superficial hydration.

  17. Overview of thermal stimulation production test results for the Japex/JNOC/GSC Mallik 5L-38 gas hydrate research well

    Energy Technology Data Exchange (ETDEWEB)

    Hancock, S. [APA Petroleum Engineering Ltd., Calgary, AB (Canada); Collett, T. [United States Geological Survey, Denver, CO (United States); Dallimore, S. [Geological Survey of Canada, Sidney, BC (Canada); Satoh, T. [Japan Petroleum Exploration Co. Ltd., Tokyo (Japan); Inoue, T. [Japan National Oil Corp., Chiba (Japan); Huenges, E.; Henninges, J. [GeoForschungsZentrum Potsdam, Potsdam (Germany)

    2004-07-01

    The production data obtained during a thermal stimulation test program at the Mallik 5L-38 research test well was presented. The test was used to observe the dissociation of a well-defined and constrained hydrate interval at temperatures above the hydrate stability point and at constant pressure. Tests results were used to calibrate numerical simulation models to determine the in-situ kinetic and thermodynamic properties of the hydrate. The Mallik 5L-38 program involved the collection of surface and downhole data as well as the use of several advanced monitoring and investigation tools and services such as mass flow meters to measure low and unsteady-state gas production volumes; a fibre-optic distributed temperature sensing system installed on the outside of the production casing to measure temperature from the surface to below the hydrate thermal test interval; a chemical tracer in the thermal circulation fluid to detect dilution; continuous on-line gas chromatograph readings; a gas sampling program for conventional and isotope analyses; cross-hole tomography and other seismic surveys; and a post-test cased hole logging program with Schlumberger's Reservoir Saturation Tool and Cased Hole Formation Resistivity tools to determine the radius of hydrate dissociation. The thermal stimulation test resulted in increased bottom hole temperature which remained constant above 50 degrees C. Dissociated gas was produced, sampled, and flared at surface. In addition, large amounts of real-time downhole temperature and pressure data was obtained. 1 fig.

  18. Reservoir-induced seismicity at Castanhao reservoir, NE Brazil

    Science.gov (United States)

    Nunes, B.; do Nascimento, A.; Ferreira, J.; Bezerra, F.

    2012-04-01

    Our case study - the Castanhão reservoir - is located in NE Brazil on crystalline rock at the Borborema Province. The Borborema Province is a major Proterozoic-Archean terrain formed as a consequence of convergence and collision of the São Luis-West Africa craton and the São Francisco-Congo-Kasai cratons. This reservoir is a 60 m high earth-filled dam, which can store up to 4.5 billion m3 of water. The construction begun in 1990 and finished in October 2003.The first identified reservoir-induced events occurred in 2003, when the water level was still low. The water reached the spillway for the first time in January 2004 and, after that, an increase in seismicity occured. The present study shows the results of a campaign done in the period from November 19th, 2009 to December 31th, 2010 at the Castanhão reservoir. We deployed six three-component digital seismographic station network around one of the areas of the reservoir. We analyzed a total of 77 events which were recorded in at least four stations. To determine hypocenters and time origin, we used HYPO71 program (Lee & Lahr, 1975) assuming a half-space model with following parameters: VP= 5.95 km/s and VP/VS=1.73. We also performed a relocation of these events using HYPODD (Waldhauser & Ellsworth, 2000) programme. The input data used we used were catalogue data, with all absolute times. The results from the spatio-temporal suggest that different clusters at different areas and depths are triggered at different times due to a mixture of: i - pore pressure increase due to diffusion and ii - increase of pore pressure due to the reservoir load.

  19. Cruise report for a seismic investigation of gas hydrates in the Mississippi Canyon region, northern Gulf of Mexico; cruise M1-98-GM

    Science.gov (United States)

    Cooper, Alan K.; Hart, Patrick E.; Pecher, Ingo

    1998-01-01

    property) analyses based on the acoustic data. The cruise was conducted in two regions, on opposite flanks of the Mississippi Canyon, where gas hydrates are known and suspected from prior coring and seismic operations (e.g., Neurauter and Bryant, 1989). The regions are also characterized by thick surficial, relatively young (Pleistocene and younger) sediments. Swath-bathymetry data (Fig. 2) show extensive sea-floor faults, piercement features, and slumps—features whose development could potentially be related to gas hydrates. The specific objectives of the cruise were (a) to image the gas-hydrate stability zone across the continental margin to document bottom-simulating reflections (BSRs) and changes in geometry of the hydrate stability zone; (b) to image known hydrate features (with several seismic systems) to estimate physical properties for hydrate and non-hydrate areas; (c) to outline the shallow structures of the hydrate stability zone to ascertain their potential effects on the formation/distribution of hydrates and on stability of the sea floor; and (d) to estimate, if possible, the amounts of hydrates present in the shallow sub surface.

  20. Influence of Physical Activity and Ambient Temperature on Hydration: The European