WorldWideScience

Sample records for relevant mineralogical transformations

  1. Mineralogy

    International Nuclear Information System (INIS)

    Klein, C.

    2006-01-01

    The classic in the field since 1848, this extraordinary reference offers readers unsurpassed coverage of mineralogy and crystallography. The book is known for integrating complete coverage of concepts and principles with a more systematic and descriptive treatment of mineralogy. The revised edition now includes a CD-ROM to let readers see the minerals and crystals, while also viewing chemical composition, symmetry, and morphological crystallography.

  2. Detailed description of oil shale organic and mineralogical heterogeneity via fourier transform infrared mircoscopy

    Science.gov (United States)

    Washburn, Kathryn E.; Birdwell, Justin E.; Foster, Michael; Gutierrez, Fernando

    2015-01-01

    Mineralogical and geochemical information on reservoir and source rocks is necessary to assess and produce from petroleum systems. The standard methods in the petroleum industry for obtaining these properties are bulk measurements on homogenized, generally crushed, and pulverized rock samples and can take from hours to days to perform. New methods using Fourier transform infrared (FTIR) spectroscopy have been developed to more rapidly obtain information on mineralogy and geochemistry. However, these methods are also typically performed on bulk, homogenized samples. We present a new approach to rock sample characterization incorporating multivariate analysis and FTIR microscopy to provide non-destructive, spatially resolved mineralogy and geochemistry on whole rock samples. We are able to predict bulk mineralogy and organic carbon content within the same margin of error as standard characterization techniques, including X-ray diffraction (XRD) and total organic carbon (TOC) analysis. Validation of the method was performed using two oil shale samples from the Green River Formation in the Piceance Basin with differing sedimentary structures. One sample represents laminated Green River oil shales, and the other is representative of oil shale breccia. The FTIR microscopy results on the oil shales agree with XRD and LECO TOC data from the homogenized samples but also give additional detail regarding sample heterogeneity by providing information on the distribution of mineral phases and organic content. While measurements for this study were performed on oil shales, the method could also be applied to other geological samples, such as other mudrocks, complex carbonates, and soils.

  3. FeII induced mineralogical transformations of ferric oxyhydroxides into magnetite of variable stoichiometry and morphology

    International Nuclear Information System (INIS)

    Usman, M.; Abdelmoula, M.; Hanna, K.

    2012-01-01

    The Mössbauer spectroscopy was used to monitor the mineralogical transformations of ferrihydrite (F), lepidocrocite (L) and goethite (G) into magnetite as a function of aging time. Ferric oxyhydroxides were reacted with soluble Fe II and OH – in stoichiometric amounts to form magnetite at an initial pH of ∼9.7. Observed transformation extent into magnetite followed the order: F>L>G with almost 30% of untransformed G after 1 month. The departure from stoichiometry, δ, of magnetite (Fe 3−δ O 4 ) generated from F (δ∼0.04) and L (δ∼0.05) was relatively low as compared to that in magnetite from G (δ∼0.08). The analysis by transmission electron microscopy and BET revealed that generated magnetite was also different in terms of morphology, particle size and surface area depending on the nature of initial ferric oxyhydroxide. This method of preparation is a possible way to form nano-sized magnetite. - Graphical abstract: Mössbauer spectrum of the early stage of magnetite formation formed from the interaction of adsorbed Fe II species with goethite. Highlights: ► Ferric oxides were reacted with hydroxylated Fe II to form magnetite. ► Magnetite formation was quantified as a function of aging time. ► Complete transformation of ferrihydrite and lepidocrocite was achieved. ► Almost 70% of initial goethite was transformed. ► Resulting magnetites have differences in stoichiometry and morphological properties.

  4. Surface-chemical and mineralogical properties relevant to the flotation of talc and other layer silicates

    International Nuclear Information System (INIS)

    Steenberg, E.; Harris, P.J.

    1985-01-01

    Certain physicochemical and mineralogical properties of different talc and pyrophylite samples were measured to show whether differences in floatability could be related to these properties. An indication of the expected hydrophobic nature of the samples was obtained by X-ray-diffraction measurements. The various samples were characterized by measurement of their zeta potentials, contact angles, suspension stability, and flotation behaviour in small-scale flotation cells. All the talc samples proved to be highly floatable and therefore only small differences in recoveries were observed. However, there was some indication that the suspension stability was related to the X-ray-diffraction measurements of the hydrophobic nature of the samples. No trends were observable from the zeta potentials and contact angles measured

  5. Transformational leadership: is this still relevant to clinical leaders?

    Science.gov (United States)

    Lo, David; McKimm, Judy; Till, Alex

    2018-06-02

    Transformational leadership theory has been at the centre of health-care leadership research for the past three decades, has had a tangible influence on the evolution of NHS leadership development strategies, and is still evident in current frameworks. This article provides an overview of the key concepts and weaknesses of transformational leadership theory and discusses its relevance within the context of the NHS working environment.

  6. Radiation transformation studies: are they relevant to radiation protection problems?

    International Nuclear Information System (INIS)

    Seymour, C.B.; Mothersill, C.

    1988-01-01

    Because of the difficulties of studying radio-carcinogenesis in humans, several in vitro systems are utilised. These cell transformation systems are reviewed, with particular emphasis on their relevance to human radiological protection problems. Most available systems use rodent fibroblasts. These are discussed in detail. Attention is drawn to certain artefacts which can cause problems with interpretation of such data. The relevance of these systems is questionable because of species differences, particularly concerning life span and because most human tumours are derived from epithelial cells. New epithelial culture systems and three-dimensional tissue culture methods becoming available are discussed in the light of their potential for addressing radiation protection problems. (author)

  7. The relevance of cell transformation to carcinogenesis in vivo

    International Nuclear Information System (INIS)

    Little, J.B.

    1989-01-01

    Despite the caveats concerning rodent as opposed to human cell transformation systems, the author concludes there are several areas in which cell transformation studies with rodent cells have shown clear relevance to carcinogenesis in vivo, especially studies of carcinogenic effects of high LET radiation, particularly dependence on dose rate. In vitro studies firmly established the generality of promotion by phorbol esters tumour promotors. Initial studies on suppression of transformation, notably by protease inhibitors, has led to the confirmation of this phenomenon in in vivo carcinogenesis; development of inhibitor preparations from natural sources suitable for long-term supplementation in human diet, is under investigation. The potential importance of these modifiers is further emphasized by mechanistic studies suggesting that radiation may initiate a large fraction of exposed cell population, and expression of transformation may be controlled to a large extent by environmental conditions including the presence of promoting or suppressing agents. Finally, cell transformation systems offer the opportunity for mechanistic studies of the initial stages of carcinogenesis. Provocative results have arisen in several areas consistent with findings in experimental animals. (author)

  8. Mineralogical characterization of Greda clays and monitoring of their phase transformations on thermal treatment

    International Nuclear Information System (INIS)

    Chavez Panduro, E.; Bravo Cabrejos, J.

    2010-01-01

    The mineralogical characterization of two clay samples from the Central Andean Region of Peru, denominated White Greda and Red Greda, is reported. These clays contain the clay minerals mica and illite respectively. Both clays were treated thermally in an oxidising atmosphere under controlled conditions up to 1,100 deg. C with the purpose of obtaining information about structural changes that may be useful for pottery manufacture. X-ray fluorescence was used for the elemental characterization of the samples and X-ray diffractometry was used to determine the collapse and formation of the mineral phases present in the samples caused by thermal treatment. At temperatures above 1,000 deg. C it is observed the formation of spinel in the case of White Greda and of hematite, corundum and cristobalite in the case of Red Greda. Room temperature transmission Moessbauer spectroscopy allowed the monitoring of the variation of the hyperfine parameters with the thermal treatment temperature; In the case of the evolution of the quadruple splitting of the paramagnetic Fe 3+ sites with temperature, in both clays, the analyses reproduced results such as the 'camel back' curve shape, found by other workers (Wagner and Wagner, Hyperfine Interact 154:35-82, 2004; Wagner and Kyek, Hyperfine Interact 154:5-33, 2004).

  9. Mineralogical characterization of Greda clays and monitoring of their phase transformations on thermal treatment

    Science.gov (United States)

    Panduro, E. Chavez; Cabrejos, J. Bravo

    2010-01-01

    The mineralogical characterization of two clay samples from the Central Andean Region of Peru, denominated White Greda and Red Greda, is reported. These clays contain the clay minerals mica and illite respectively. Both clays were treated thermally in an oxidising atmosphere under controlled conditions up to 1,100°C with the purpose of obtaining information about structural changes that may be useful for pottery manufacture. X-ray fluorescence was used for the elemental characterization of the samples and X-ray diffractometry was used to determine the collapse and formation of the mineral phases present in the samples caused by thermal treatment. At temperatures above 1,000°C it is observed the formation of spinel in the case of White Greda and of hematite, corundum and cristobalite in the case of Red Greda. Room temperature transmission Mössbauer spectroscopy allowed the monitoring of the variation of the hyperfine parameters with the thermal treatment temperature; In the case of the evolution of the quadruple splitting of the paramagnetic Fe3 + sites with temperature, in both clays, the analyses reproduced results such as the “camel back” curve shape, found by other workers (Wagner and Wagner, Hyperfine Interact 154:35-82, 2004; Wagner and Kyek, Hyperfine Interact 154:5-33, 2004).

  10. Mineralogical characterization of Greda clays and monitoring of their phase transformations on thermal treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chavez Panduro, E., E-mail: 04130127@unmsm.edu.pe; Bravo Cabrejos, J., E-mail: jbravoc@unmsm.edu.pe [Universidad Nacional Mayor de San Marcos, Facultad de Ciencias Fisicas (Peru)

    2010-01-15

    The mineralogical characterization of two clay samples from the Central Andean Region of Peru, denominated White Greda and Red Greda, is reported. These clays contain the clay minerals mica and illite respectively. Both clays were treated thermally in an oxidising atmosphere under controlled conditions up to 1,100 deg. C with the purpose of obtaining information about structural changes that may be useful for pottery manufacture. X-ray fluorescence was used for the elemental characterization of the samples and X-ray diffractometry was used to determine the collapse and formation of the mineral phases present in the samples caused by thermal treatment. At temperatures above 1,000 deg. C it is observed the formation of spinel in the case of White Greda and of hematite, corundum and cristobalite in the case of Red Greda. Room temperature transmission Moessbauer spectroscopy allowed the monitoring of the variation of the hyperfine parameters with the thermal treatment temperature; In the case of the evolution of the quadruple splitting of the paramagnetic Fe{sup 3+} sites with temperature, in both clays, the analyses reproduced results such as the 'camel back' curve shape, found by other workers (Wagner and Wagner, Hyperfine Interact 154:35-82, 2004; Wagner and Kyek, Hyperfine Interact 154:5-33, 2004).

  11. Simultaneous Helmert transformations among multiple frames considering all relevant measurements

    Science.gov (United States)

    Chang, Guobin; Lin, Peng; Bian, Hefang; Gao, Jingxiang

    2018-03-01

    Helmert or similarity models are widely employed to relate different coordinate frames. It is often encountered in practice to transform coordinates from more than one old frame into a new one. One may perform separate Helmert transformations for each old frame. However, although each transformation is locally optimal, this is not globally optimal. Transformations among three frames, namely one new and two old, are studied as an example. Simultaneous Helmert transformations among all frames are also studied. Least-squares estimation of the transformation parameters and the coordinates in the new frame of all stations involved is performed. A functional model for the transformations among multiple frames is developed. A realistic stochastic model is followed, in which not only non-common stations are taken into consideration, but also errors in all measurements are addressed. An algorithm of iterative linearizations and estimations is derived in detail. The proposed method is globally optimal, and, perhaps more importantly, it produces a unified network of the new frame providing coordinate estimates for all involved stations and the associated covariance matrix, with the latter being consistent with the true errors of the former. Simulations are conducted, and the results validate the superiority of the proposed combined method over separate approaches.

  12. The Mineralogic Transformation of Ferrihydrite Induced by Heterogeneous Reaction with Bioreduced Anthraquinone Disulfonate (AQDS) and the Role of Phosphate

    Energy Technology Data Exchange (ETDEWEB)

    Zachara, John M.; Kukkadapu, Ravi K.; Peretyazhko, Tetyana; Bowden, Mark E.; Wang, Chong M.; Kennedy, David W.; Moore, Dean A.; Arey, Bruce W.

    2011-10-12

    Anthraquinone-2-6-disulfonate (AQDS) enhances electron donor utilization and mineral product crystallization in studies of Fe(III) oxide reductive mineralization by metal reducing bacteria (MRB) through heterogeneous redox reaction. In spite of the strong effect of AQDS in these systems, little information exits on its direct role in reductive mineralization. To provide such insights, bioreduced AQDS (AH2DS; dihydro-anthraquinone) was reacted with a 2-line, Si-substituted ferrihydrite under anoxic conditions at neutral pH in PIPES buffer. Phosphate (P) and bicarbonate (C); common adsorptive oxyanions and media/buffer components known to effect ferrihydrite mineralization; and Fe(II)aq (as a catalytic mineralization agent) were used in comparative experiments. Heterogeneous AH2DS oxidation coupled with Fe(III) reduction occurred within 0.13-1 day, with mineralogic transformation occurring thereafter. The product suite included lepidocrocite, goethite, and/or magnetite, with proportions varing with reductant:oxidant ratio (r:o) and the presence of P or C. Lepidocrocite was the primary product at low r:o in the absence of P or C, with evidence for multiple formation pathways. P inhibited reductive recrystallization, while C promoted goethite formation. Stoichiometric magnetite was the sole product at higher r:o in the absence and presence of P. Lepidocrocite was the primary mineralization product in the Fe(II)aq system, with magnetite observed at near equal amounts when Fe(II) was high [Fe(II)/Fe(III)]=0.5 and P was absent. P had a greater effect on reductive mineralization in the Fe(II)aq system, while AQDS was more effective than Fe(II)aq in promoting magnetite formation. The direct AH2DS-driven reductive reaction pathway produced mineral products that were different from AH2DS-ferrihydite-MRB systems, particularly in presence of P.

  13. On the physical relevance of the discrete Fourier transform

    CSIR Research Space (South Africa)

    Greben, JM

    1991-11-01

    Full Text Available This paper originated from the author's dissatisfaction with the way the discrete Fourier transform is usually presented in the literature. Although mathematically correct, the physical meaning of the common representation is unsatisfactory...

  14. Evolution of the Petrophysical and Mineralogical Properties of Two Reservoir Rocks Under Thermodynamic Conditions Relevant for CO2 Geological Storage at 3 km Depth

    International Nuclear Information System (INIS)

    Rimmel, G.; Barlet-Gouedard, V.; Renard, F.

    2010-01-01

    Injection of carbon dioxide (CO 2 ) underground, for long-term geological storage purposes, is considered as an economically viable option to reduce greenhouse gas emissions in the atmosphere. The chemical interactions between supercritical CO 2 and the potential reservoir rock need to be thoroughly investigated under thermodynamic conditions relevant for geological storage. In the present study, 40 samples of Lavoux limestone and Adamswiller sandstone, both collected from reservoir rocks in the Paris basin, were experimentally exposed to CO 2 in laboratory autoclaves specially built to simulate CO 2 -storage-reservoir conditions. The two types of rock were exposed to wet supercritical CO 2 and CO 2 -saturated water for one month, at 28 MPa and 90 C, corresponding to conditions for a burial depth approximating 3 km. The changes in mineralogy and micro-texture of the samples were measured using X-ray diffraction analyses, Raman spectroscopy, scanning-electron microscopy, and energy-dispersion spectroscopy microanalysis. The petrophysical properties were monitored by measuring the weight, density, mechanical properties, permeability, global porosity, and local porosity gradients through the samples. Both rocks maintained their mechanical and mineralogical properties after CO 2 exposure despite an increase of porosity and permeability. Microscopic zones of calcite dissolution observed in the limestone are more likely to be responsible for such increase. In the sandstone, an alteration of the petro-fabric is assumed to have occurred due to clay minerals reacting with CO 2 . All samples of Lavoux limestone and Adamswiller sandstone showed a measurable alteration when immersed either in wet supercritical CO 2 or in CO 2 -saturated water. These batch experiments were performed using distilled water and thus simulate more severe conditions than using formation water (brine). (authors)

  15. Evaluation of Chemical and Mineralogical Transformation of Iron in Different Soils in Saturated and Field Capacity Conditions

    Directory of Open Access Journals (Sweden)

    M. Saadatpour Mogaddam

    2016-09-01

    Full Text Available Introduction: Redox potential is one of the most important factors affecting on the solubility of iron minerals in soil. Decreasing redox potential in soil reduces Fe3+ to Fe2+, thereby affecting on solubility of Fe minerals. Application of organic matter to soil under waterlogging condition, decrease redox potential and as a consequence, accelerate the transformation of Fe minerals. The objectives of this study were: 1- The effect of waterlogging on the soluble total Fe concentration and transformation of Fe minerals in different soil pH values. 2- The indirect effects of organic matter on solubility of Fe minerals by changing the redox potential of the soils. Materials and Methods: A study was conducted to determine the effects of redox potential on solubility of Fe and transformation of Fe minerals during the time. Four agricultural soils were selected from different regions of Iran. The soil samples were treated with 0 (Cand 2% (O alfalfa powder and then incubated for 12 weeks under 60% Field capacity (F and waterlogged conditions (S. Subsamples were taken after 1and 12 weeks of incubation and the redox potential, pH value, electrical conductivity (EC, soluble cations (such as Ca2+, Mg2+, K+ and Na+ and anions (such as Cl-, SO42-, PO43- and NO3- and soluble Fe concentrations in the subsamples were measured. Concentrations of Fe2+ and Fe3+ species in soil solution were also predicted using Visual MINTEQ speciation program. Mineralogical transformation of Fe minerals was also determined by X-ray diffraction (XRD technique. Results and Discussion: The results in 60% Field capacity condition showed that pH value by organic matter (alfalfa powder application (OF increased significantly (p≤ 0.05 in acid and neutral soils and decreased in calcareous soils when compared to the control (CF. Organic matter is usually capable of lowering pH of alkaline soils by releasing hydrogen ions associated with organic anions or by nitrification in an open

  16. Mineralogical and structural transformations related to alterations in hydrothermal and climatological conditions of basic vulcanic rocks from northern Parana (Ribeirao Preto region, SP, Brazil)

    International Nuclear Information System (INIS)

    Goncalves, N.M.M.

    1987-01-01

    Detailed studies of the basic vulcanic rocks of northern Parana basin (Region of Ribeirao Preto, SP) reveled that these rocks were affected by pre-meteoric activity (hydrothermal alteration) before being exposed to the supergene system of alteration linked to the lithosphere/atmosphere interface. Mineralogical and structural transformation are studied. The appearance of sequential crystalline-chemical paragenesis in zones suggest that the hydrothermal activity occurred during two successives processes of alteration: the expulsion of the water from the rock during the later stages of magma cooling and the continous process of dissolution of the rock wall and the ionic diffusion involving the rock sistem of structural voids. The hydro-thermal action was followed by weathering action developing a thin 'front' of superficial alteration. This alteration system, can lead to the formation of three major levels of alteration horizons and superficial accumulations: alterites, glebular and suil surface materials. (C.D.G.) [pt

  17. Transformation and Transformational Leadership: A Review of the Current and Relevant Literature for Academic Radiologists.

    Science.gov (United States)

    Thomson, Norman B; Rawson, James V; Slade, Catherine P; Bledsoe, Martin

    2016-05-01

    With the US healthcare system on an unsustainable course, change is inevitable. Changes in the healthcare landscape impacting radiology include changing payment models, rapid adoption of digital technology, changes in radiology resident certifying exams, and the rise of consumerism in health care. Academic Radiology will be part of that change with none of its missions spared. What matters is not that change is coming but how Academic Radiology responds to change. Do we ignore, adapt, adopt others' practices, or lead change? Change management or transformation is a management skill set that can be learned and developed. Transformational leadership is a leadership style defined by the relationships between the leaders and the followers and the results they are able to achieve together to meet organizational goals. In this paper, we provide a review of key change management theories, as well as practical advice for self-reflection and development of leadership behaviors that promote effective change management and organizational transformation, particularly in a complex industry like Academic Radiology. Copyright © 2016 The Association of University Radiologists. Published by Elsevier Inc. All rights reserved.

  18. Mineralogical, micromorphological and geochemical transformations in the initial steps of the weathering process of charnockite from the Caparaó Range, southeastern Brazil

    Science.gov (United States)

    Soares, Caroline Cibele Vieira; Varajão, Angélica Fortes Drummond Chicarino; Varajão, César Augusto Chicarino; Boulangé, Bruno

    2014-12-01

    X-ray diffraction (XRD), X-ray Fluorescence (XRF), optical microscopy, Scanning Electron Microscopy coupled with Energy Dispersive Spectrometry (SEM-EDS) and Electron Probe micro-analyser (EPMA) and Wavelength-Dispersive Spectroscopy (WDS) were conducted on charnockite from the Caparaó Suite and its alteration cortex to determine the mineralogical, micromorphological and geochemical transformations resulting from the weathering process. The hydrolysis of the charnockite occurred in different stages, in accordance with the order of stability of the minerals with respect to weathering: andesine/orthopyroxene, pargasite and alkali feldspar. The rock modifications had begun with the formation of a layer of incipient alteration due to the percolation of weathering solutions first in the pressure relief fractures and then in cleavage and mineral edges. The iron exuded from ferromagnesian minerals precipitated in the intermineral and intramineral discontinuities. The layer of incipient alteration evolves into an inner cortex where the plagioclase changes into gibbsite by direct alitisation, the ferromagnesian minerals initiate the formation of goethitic boxworks with kaolinitic cores, and the alkali feldspar initiates indirect transformation into gibbsite, forming an intermediate phase of illite and kaolinite. In the outer cortex, mostly traces of alkali feldspar remain, and they are surrounded by goethite and gibbsite as alteromorphics, characterising the formation of the isalteritic horizon that occurs along the slope and explains the bauxitization process at the Caparaó Range, SE Brazil.

  19. Mineralogical and crystallochemical transformations originated from thermal essays on ferruginous kaolinitic clays; Transformacoes mineralogicas e cristaloquimicas decorrentes dos ensaios termais em argilas cauliniticas ferruginosas

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, M.M.; Varajao, A.F.D.C.; Morales-Carrera, A.M.; Peralta-Sanchez, M.G.; Costa, G.M. da, E-mail: angelica@degeo.ufop.br [Universidade Federal de Ouro Preto, Campus Universitario, Morro do Cruzeiro s/n, Ouro Preto, MG (Brazil)

    2012-01-15

    Mineralogical and crystallochemical transformations of representative ferruginous kaolinitic clay samples were investigated in specimens burned at 800, 1000 and 1200 deg C. X-ray diffraction and differential thermal and thermogravimetric analyses showed that kaolinite was the predominant mineral in the raw samples. The Moessbauer spectroscopy results showed that the high iron content (22.5 wt.%), as determined by X-ray fluorescence, is related to the presence of goethite (18 wt.%) and hematite (16 wt.%). However, after Fe was extracted using a dithionite-citrate system buffered with sodium bicarbonate, a residue of this element (Fe{sup 3+} and Fe{sup 2+}) was found in the structure of the kaolinite. The sintering process showed the destruction of kaolinite, as well as the transformation of the goethite into hematite, the crystals growing as the temperature increases. The hematite crystal size at 1200 deg C is five times larger than in the raw sample. The mullite formation at 1000 deg C is comprised of a solid solution of Fe{sub 2}O{sub 3} and Al{sub 2}O{sub 3},which results in a resistant product with a higher thermal stability (author)

  20. Electronic patient records in action: Transforming information into professionally relevant knowledge.

    Science.gov (United States)

    Winman, Thomas; Rystedt, Hans

    2011-03-01

    The implementation of generic models for organizing information in complex institutions like those in healthcare creates a gap between standardization and the need for locally relevant knowledge. The present study addresses how this gap can be bridged by focusing on the practical work of healthcare staff in transforming information in EPRs into knowledge that is useful for everyday work. Video recording of shift handovers on a rehabilitation ward serves as the empirical case. The results show how extensive selections and reorganizations of information in EPRs are carried out in order to transform information into professionally relevant accounts. We argue that knowledge about the institutional obligations and professional ways of construing information are fundamental for these transitions. The findings point to the need to consider the role of professional knowledge inherent in unpacking information in efforts to develop information systems intended to bridge between institutional and professional boundaries in healthcare. © The Author(s) 2011.

  1. Microbial transformation of coal and coal relevant structures - presentation of a BMBF joint research project

    Energy Technology Data Exchange (ETDEWEB)

    Sinder, C.; Schacht, S.; Pfeifer, F.; Klein, J. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany)

    1997-12-31

    Investigations in the joint research project `Microbial transformation of coal and coal relevant structures` supported by the Ministry of Education, Science, Research and Technology (BMBF) of the Federal Republic of Germany and coordinated by the DMT-Gesellschaft fuer Forschung und Pruefung mbH (DMT) are focussed on research and development of biotechnological coal conversion processes. Up to now investigations carried out in the project lead to a number of important results. During work on the project a great number of different microorganisms was found able to degrade or solubilize coal or lignite. Enzymatic as well as regulation mechanisms of the microbial depolymerization processes have been characterized successfully. (orig.)

  2. The Relevant Role of Dislocations in the Martensitic Transformations in Cu-Al-Ni Single Crystals

    Science.gov (United States)

    Gastien, R.; Sade, M.; Lovey, F. C.

    2018-03-01

    The interaction between dislocations and martensitic transformations in Cu-Al-Ni alloys is shortly reviewed. Results from many researchers are critically analyzed towards a clear interpretation of the relevant role played by dislocations on the properties of shape memory alloys in Cu-based alloys. Both thermally and stress-induced transformations are considered and focus is paid on two types of transitions, the β→β' and the formation of a mixture of martensites: β→β' + γ'. After cycling in the range where both martensites are formed, the twinned γ' phase is inhibited and cycling evolves into the formation of only β'. A model which considers the difference in energy of each γ' twin variant due to the introduced dislocations quantitatively explains the inhibition of γ' in both thermally and stress-induced cycling. The type of dislocations which are mainly introduced, mixed with Burgers vector belonging to the basal plane of the β' martensite, enables also to explain the unmodified mechanical behavior during β→β' cycling. The reported behavior shows interesting advantages of Cu-Al-Ni single crystals if mechanical properties are comparatively considered with those in other Cu-based alloys.

  3. Transforming Big Data into cancer-relevant insight: An initial, multi-tier approach to assess reproducibility and relevance* | Office of Cancer Genomics

    Science.gov (United States)

    The Cancer Target Discovery and Development (CTD^2) Network was established to accelerate the transformation of "Big Data" into novel pharmacological targets, lead compounds, and biomarkers for rapid translation into improved patient outcomes. It rapidly became clear in this collaborative network that a key central issue was to define what constitutes sufficient computational or experimental evidence to support a biologically or clinically relevant finding.

  4. Structural transformation and its relevance for economic growth in sub-Saharan Africa

    OpenAIRE

    Busse, Matthias; Erdogan, Ceren; Mühlen, Henning

    2017-01-01

    In this paper, we analyse the role of structural transformation in view of the remarkable growth performance of sub-Saharan African countries since the mid-1990s. Our analysis covers 41 African countries over the period 1980 to 2014 and accounts for structural transformation by employing the analytical frameworks of (1) growth decomposition and (2) growth regression. Even though the low-productive agricultural sector continues to employ most of the African workforce, our results reveal that s...

  5. Histology of somatic embryos of eurycoma longifolia (simaroubaceae): relevance in agrobacterium rhizogenes-mediated transformation

    International Nuclear Information System (INIS)

    Balakrishnan, B.; Rabiah, S.S.; Keng, C.L.

    2014-01-01

    Histological analysis conducted on somatic embryos of Eurycoma longifolia shows the developmental structures that are remarkably similar to seeds found in the wild. The primary components of a growing somatic embryo are its shoot and root apical meristems indicated by dense layers of rapidly growing cells. The increased understanding of In vitro culture systems and anatomical changes provide information into cellular processes that govern genetic transformation of E. longifolia with Agrobacterium rhizogenes. The presence of meristematic regions on cultured somatic embryos suggests that they are suitable for genetic transformation as genetic elements could be transported to these regions where growth and differentiation are centered. This allows the successful integration and expression of transferred DNA in the host organism, leading the way for an efficient A. rhizogenes-mediated transformation protocol. (author)

  6. Opportunities for Cancer-relevant Innovative Technologies with Transformative Potential | Office of Cancer Clinical Proteomics Research

    Science.gov (United States)

    The National Cancer Institute (NCI) is seeking input from the community on identifying priorities with regards to supporting innovative technology development for cancer-relevant research. While the NCI provides support for technology development through a variety of mechanisms, it is important to understand whether or not these are sufficient for catalyzing and supporting the development of tools with significant potential for advancing important fields of cancer research or clinical care.

  7. Researching the Real: Transforming the Science Fair through Relevant and Authentic Research

    Science.gov (United States)

    Davidson, Rosemary McBryan

    This teacher research study documents the processes used to help students in an all-female, religious-based high school create science fair projects that are personally meaningful, scientifically sophisticated and up-to date in terms of science content. One-hundred sixteen young women in an honors chemistry class were introduced by their teacher to the methods used by science journalists when researching and crafting articles. The students then integrated these strategies into their science fair research through collaborative classroom activities designed by their teacher. Data collected during the process included audio and video tapes of classroom activities, student interviews, process work, finished projects, email conversations and the reflective journaling, annotated lesson plans, and memories of the lived experience by the teacher. The pedagogical changes which resulted from this project included the use of Read Aloud-Think Alouds (RATA) to introduce content and provide relevance, a discussion based topic selection process, the encouragement of relevant topic choices, the increased use of technology for learning activities and for sharing research, and an experimental design process driven by the student's personally relevant, topic choice. Built in feedback loops, provided by the teacher, peer editors and an outside editor, resulted in multiple revisions and expanded opportunities for communicating results to the community-at-large. Greater student engagement in science fair projects was evident: questioning for understanding, active involvement in decision making, collaboration within the classroom community, experience and expertise with reading, writing and the use of technology, sense of agency and interest in science related activities and careers all increased. Students communicated their evolving practices within the school community and became leaders who promoted the increased use of technology in all of their classes. Integrating journalistic

  8. Linking job-relevant personality traits, transformational leadership, and job performance via perceived meaningfulness at work: A moderated mediation model.

    Science.gov (United States)

    Frieder, Rachel E; Wang, Gang; Oh, In-Sue

    2018-03-01

    By integrating the fundamental principles of the theory of purposeful work behavior (TPWB; Barrick, Mount, & Li, 2013) with cognitive-affective personality system (CAPS) theory (Mischel, 1977; Mischel & Shoda, 1995), we examine how and when salespeople's job-relevant personality traits relate to their performance. We argue that individuals with personality traits that fit outdoor sales jobs (i.e., conscientious, extraversion, openness to experience) will perceive their work as more meaningful and as a result achieve heightened performance. Moreover, drawing from TPWB and CAPS theory, we expect that as an important element of the social context, transformational leadership moderates the indirect effect of salespeople's job-relevant personality traits on their job performance via enhanced perceptions of meaningfulness at work. Results based on data from 496 outdoor salespeople and their 218 supervisors and regional managers provide support for the hypotheses pertaining to conscientiousness and openness, but not extraversion. Specifically, the conditional indirect effects of conscientiousness or openness on performance through perceived meaningfulness are more positive under low, rather than high, levels of transformational leadership. Implications for research and practice are discussed along with study limitations and future research directions. (PsycINFO Database Record (c) 2018 APA, all rights reserved).

  9. Photochemical transformation of benzotriazole, relevant to sunlit surface waters: Assessing the possible role of triplet-sensitised processes

    Energy Technology Data Exchange (ETDEWEB)

    Bianco, Angelica [Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand (France); Fabbri, Debora; Minella, Marco [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Turin (Italy); Brigante, Marcello, E-mail: marcello.brigante@univ-bpclermont.fr [Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6296, ICCF, BP 80026, F-63177 Aubière (France); Mailhot, Gilles [Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6296, ICCF, BP 80026, F-63177 Aubière (France); Maurino, Valter; Minero, Claudio [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Turin (Italy); Vione, Davide, E-mail: davide.vione@unito.it [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Turin (Italy); Università degli Studi di Torino, Centro Interdipartimentale NatRisk, Via L. Da Vinci 44, 10095 Grugliasco (Italy)

    2016-10-01

    The corrosion inhibitor 1H-benzotriazole (pK{sub a} = 8.4) can exist in two different forms in natural waters, and photochemical transformation is a potentially significant attenuation pathway for both of them. Depending on conditions, the modelled half-life times range from some days/weeks to several months. In sunlit water bodies, the acidic (neutral) form would undergo direct photolysis (accounting for up to 7% of total phototransformation) and, most notably, reaction with the hydroxyl radicals ({sup ·}OH) and the triplet states of chromophoric dissolved organic matter ({sup 3}CDOM*). The basic (anionic) form would undergo significant transformation with {sup ·}OH and {sup 3}CDOM*. The {sup ·}OH reactions would be more important at low dissolved organic carbon (DOC) and the {sup 3}CDOM* processes at high DOC. In the presence of highly reactive triplet-state model compounds, the two benzotriazole forms react with similar rate constants. In this case, they would show comparable half-life times in surface-water environments. With less reactive triplet states, the rate constant of the anionic form can be a couple of orders of magnitude higher than that of the neutral one. Under these circumstances, the neutral form could be considerably more photostable than the anionic one at high DOC. Therefore, depending on {sup 3}CDOM* reactivity, the solution pH may or may not play an important role in the photoattenuation kinetics of 1H-benzotriazole in sunlit natural waters, especially at high DOC. Both forms of benzotriazole yield hydroxyderivatives as their main transformation intermediates under all the relevant photochemical reaction pathways. These intermediates could be formed via {sup ·}OH-induced hydroxylation, or upon electron abstraction followed by reaction with water. Differently from UVC irradiation data reported in previous studies, the concentration of aniline upon excitation of 1H-benzotriazole under environmentally significant UV wavelengths was always

  10. Photochemical transformation of benzotriazole, relevant to sunlit surface waters: Assessing the possible role of triplet-sensitised processes

    International Nuclear Information System (INIS)

    Bianco, Angelica; Fabbri, Debora; Minella, Marco; Brigante, Marcello; Mailhot, Gilles; Maurino, Valter; Minero, Claudio; Vione, Davide

    2016-01-01

    The corrosion inhibitor 1H-benzotriazole (pK a = 8.4) can exist in two different forms in natural waters, and photochemical transformation is a potentially significant attenuation pathway for both of them. Depending on conditions, the modelled half-life times range from some days/weeks to several months. In sunlit water bodies, the acidic (neutral) form would undergo direct photolysis (accounting for up to 7% of total phototransformation) and, most notably, reaction with the hydroxyl radicals ( · OH) and the triplet states of chromophoric dissolved organic matter ( 3 CDOM*). The basic (anionic) form would undergo significant transformation with · OH and 3 CDOM*. The · OH reactions would be more important at low dissolved organic carbon (DOC) and the 3 CDOM* processes at high DOC. In the presence of highly reactive triplet-state model compounds, the two benzotriazole forms react with similar rate constants. In this case, they would show comparable half-life times in surface-water environments. With less reactive triplet states, the rate constant of the anionic form can be a couple of orders of magnitude higher than that of the neutral one. Under these circumstances, the neutral form could be considerably more photostable than the anionic one at high DOC. Therefore, depending on 3 CDOM* reactivity, the solution pH may or may not play an important role in the photoattenuation kinetics of 1H-benzotriazole in sunlit natural waters, especially at high DOC. Both forms of benzotriazole yield hydroxyderivatives as their main transformation intermediates under all the relevant photochemical reaction pathways. These intermediates could be formed via · OH-induced hydroxylation, or upon electron abstraction followed by reaction with water. Differently from UVC irradiation data reported in previous studies, the concentration of aniline upon excitation of 1H-benzotriazole under environmentally significant UV wavelengths was always below the detection limit of the analytical

  11. Transformation

    DEFF Research Database (Denmark)

    Bock, Lars Nicolai

    2011-01-01

    Artiklen diskuterer ordet "transformation" med udgangspunkt i dels hvorledes ordet bruges i arkitektfaglig terminologi og dels med fokus på ordets potentielle indhold og egnethed i samme teminologi.......Artiklen diskuterer ordet "transformation" med udgangspunkt i dels hvorledes ordet bruges i arkitektfaglig terminologi og dels med fokus på ordets potentielle indhold og egnethed i samme teminologi....

  12. TRANSFORMATION

    Energy Technology Data Exchange (ETDEWEB)

    LACKS,S.A.

    2003-10-09

    Transformation, which alters the genetic makeup of an individual, is a concept that intrigues the human imagination. In Streptococcus pneumoniae such transformation was first demonstrated. Perhaps our fascination with genetics derived from our ancestors observing their own progeny, with its retention and assortment of parental traits, but such interest must have been accelerated after the dawn of agriculture. It was in pea plants that Gregor Mendel in the late 1800s examined inherited traits and found them to be determined by physical elements, or genes, passed from parents to progeny. In our day, the material basis of these genetic determinants was revealed to be DNA by the lowly bacteria, in particular, the pneumococcus. For this species, transformation by free DNA is a sexual process that enables cells to sport new combinations of genes and traits. Genetic transformation of the type found in S. pneumoniae occurs naturally in many species of bacteria (70), but, initially only a few other transformable species were found, namely, Haemophilus influenzae, Neisseria meningitides, Neisseria gonorrheae, and Bacillus subtilis (96). Natural transformation, which requires a set of genes evolved for the purpose, contrasts with artificial transformation, which is accomplished by shocking cells either electrically, as in electroporation, or by ionic and temperature shifts. Although such artificial treatments can introduce very small amounts of DNA into virtually any type of cell, the amounts introduced by natural transformation are a million-fold greater, and S. pneumoniae can take up as much as 10% of its cellular DNA content (40).

  13. TRANSFORMER

    Science.gov (United States)

    Baker, W.R.

    1959-08-25

    Transformers of a type adapted for use with extreme high power vacuum tubes where current requirements may be of the order of 2,000 to 200,000 amperes are described. The transformer casing has the form of a re-entrant section being extended through an opening in one end of the cylinder to form a coaxial terminal arrangement. A toroidal multi-turn primary winding is disposed within the casing in coaxial relationship therein. In a second embodiment, means are provided for forming the casing as a multi-turn secondary. The transformer is characterized by minimized resistance heating, minimized external magnetic flux, and an economical construction.

  14. Geochemistry and mineralogy

    Energy Technology Data Exchange (ETDEWEB)

    Plecas, I.; Dimovic, S.; Orta, M.M.; Alba, M.D.; Alvero, R.; Becerro, A.I.; Castro, M.A.; Chain, P.; Escudero, A.; Naranjo, M.; Pavon, E.; Trillo, J.M.; Vejsada, J.; Vokal, A.; Zadvernyuk, H.P.; Fedorenko, Y.G.; Zlobenko, B.P.; Koromyslichenko, T.I.; Battaglia, S.; Cervelli, M.; Millot, R.; Girard, J.P.; Missana, T.; Garcia-Gutierrez, M.; Alonso, U.; Muurinen, A.; Carlsson, T.; Chain, P.; Alba, M.D.; Becerro, A.I.; Castro, M.A.; Escudero, A.; Gonzalez-Carrascosa, T.; Hurtado, S.; Pavon, E.; Villa, M.; Bourg, I.C.; Sposito, G.; Bourg, A.C.M.; Marques Fernandes, M.; Rabung, Th.; Dahn, R.; Baeyens, B.; Bradbury, M.H.; Breynaert, E.; Maes, A.; Bruggeman, C.; Maes, I.A.; Vancluysen, J.; Credoz, A.; Bildstein, O.; Jullien, M.; Raynal, J.; Petronin, J.C.; Trotignon, L.; Pokrovsky, O.; Jacquier, P.; Beaucaire, C.; Vuillaume, A.L.; Wittebroodt, Ch.; Ly, J.; Page, J.; Savoye, S.; Pitsch, H.; Jacques, D.; Wang, L.; Galunin, E.; Chain, P.; Alba, M.D.; Vidal, M.; Grandia, F.; Domenech, C.; Arcos, D.; Duro, L.; Bruno, J.; Andre, L.; Pauwels, H.; Azaroual, M.; Albrecht, A.; Romero, M.A.; Aerts, S.; Boven, P.; Van Geet, M.; Boever, P. de; Alonso, U.; Albarran, N.; Missana, T.; Garcia-Gutierrez, M.; Truche, L.; Berger, G.; Guillaume, D.; Jacquot, E.; Tournassat, Ch.; Lerouge, C.; Brendle, J.; Greneche, J.M.; Touzelet, St.; Blanc, Ph.; Gaucher, E.C.; Thoenen, T.; Klinkenberg, M.; Kaufhold, S.; Dohrmann, R.; Siegesmund, S.; Liu, D.J.; Bruggeman, C.; Maes, N.; Weber, T.; Trotignon, L.; Pozo, C.; Bildstein, O.; Combarieu, G. de; Frugier, P.; Menut, D

    2007-07-01

    This session gathers 52 articles (posters) dealing with: the influence of natural sorbents immobilization of spent ion exchange resins in cement; the chemical stability of rare-earth silicate; the mineralogical heterogeneity of Rokle bentonite and radionuclide adsorption: A case study for cesium; the rheological and sorption properties of clay-polymer composites; the clay mineral interactions with leachate solutions in landfills; the lithium isotope fractionation during adsorption onto mineral surfaces; the sorption of Sr{sup 2+} onto mixed smectite / illite clays; Eh and pH in the pore water of compacted bentonite; the chemical interaction of {sup 152}Eu with the clay barrier; the modeling of the acid-base surface chemistry of Montmorillonite; a time resolved laser fluorescence and X-ray absorption spectroscopy study of lanthanide/actinide sorption on clay minerals: influence of carbonate complexation; the structure elucidation and occurrence of Tc(IV) pyrogallol complexes; the geochemistry of Se(0) under boom clay conditions; an experimental and modelling study of pure secondary silicate minerals reactivity in geological CO{sub 2} sequestration conditions; an experimental evaluation of a retention model for major groundwater elements on the Tournemire argillite; modelling the long term interaction of cementitious pore water with Boom clay; the sorption-desorption of radionuclides and analogues in clays suitable for barriers; the modelling of the Redox evolution in the tunnel backfill of a high level nuclear waste repository; the reactivity of nitrates in the different storage compartments of type-b wastes; an investigation into the biodiversity of sulphate reducing bacteria in Boom clay; the colloid generation mechanisms from compacted bentonite under different geochemical conditions; the experimental reduction of aqueous sulphate by hydrogen in the context of the Callovo-Oxfordian argillite; cation exchanged Fe(II) and Sr as compared to other divalent cations

  15. Transformações mineralógicas e cristaloquímicas decorrentes dos ensaios termais em argilas cauliníticas ferruginosas Mineralogical and crystalochemical transformations originated from thermal essays on ferruginous kaolinitic clays

    Directory of Open Access Journals (Sweden)

    M. M. Ferreira

    2012-03-01

    Full Text Available Transformações mineralógicas e cristaloquímicas foram investigadas em amostras de argilas cauliníticas ferruginosas aquecidas a temperaturas de 800, 1000 e 1200 °C. As análises de difração de raios X e térmica diferencial e gravimétrica mostraram ser a caulinita o argilomineral predominante nas amostras naturais. Os resultados da espectroscopia Mössbauer mostraram que o alto conteúdo em Fe (22,5% em peso, determinado por fluorescência de raios X, é relacionado à presença de goethita (18% em peso e hematita (16% em peso. Entretanto um resíduo deste elemento (Fe3+ e Fe2+ foi constatado após a extração do ferro usando solução de ditionito-citrato-bicarbonato, e possivelmente se deve à presença de ferro na estrutura da caulinita. O processo de sinterização mostra uma desestruturação da caulinita, assim como a transformação da goethita em hematita, cujo tamanho dos cristais cresce com o incremento da temperatura. O tamanho do cristal de hematita a 1200 °C é 5 vezes maior do que na amostra natural. A mulita formada a 1000 °C é constituída da solução sólida de Fe2O3, com Al2O3, o que resulta em produto resistente e de maior estabilidade térmica.Mineralogical and crystallochemical transformations of representative ferruginous kaolinitic clay samples were investigated in specimens burned at 800, 1000 and 1200 °C. X-ray diffraction and differential thermal and thermogravimetric analyses showed that kaolinite was the predominant mineral in the raw samples. The Mössbauer spectroscopy results showed that the high iron content (22.5 wt.%, as determined by X-ray fluorescence, is related to the presence of goethite (18 wt.% and hematite (16 wt.%. However, after Fe was extracted using a dithionite-citrate system buffered with sodium bicarbonate, a residue of this element (Fe3+ and Fe2+ was found in the structure of the kaolinite. The sintering process showed the destruction of kaolinite, as well as the transformation of

  16. Journal of Mineralogical and Petrological Sciences

    Science.gov (United States)

    Official journal of Japan Association of Mineralogical Sciences (JAMS), focusing on mineralogical and petrological sciences and their related fields. Journal of Mineralogical and Petrological Sciences (JMPS) is the successor journal to both “Journal of Mineralogy, Petrology and Economic Geology” and “Mineralogical Journal”. Journal of Mineralogical and Petrological Sciences (JMPS) is indexed in the ISI database (Thomson Reuters), the Science Citation Index-Expanded, Current Contents/Physical, Chemical & Earth Sciences, and ISI Alerting Services.

  17. Mineralogy. 2. rev., enlarged ed.

    International Nuclear Information System (INIS)

    Matthes, S.

    1987-01-01

    The textbook is intended for students with a basic knowledge of descriptive mineralogy and crystallography who wish to enhance their knowledge in the fields of determinative mineralogy, petrology, and the geology and genesis of mineral deposits. The material presented concentrates on the essential aspects of the subject fields and is completed by up-to-date information concerning the technical and economic significance of the minerals, rocks and ores as raw materials. With 165 figs., 2 tabs [de

  18. The Bible as Transformational Object: The Psychoanalytic Theories of Christopher Bollas and Their Relevance for Religious Educators

    Science.gov (United States)

    DeGear, Elizabeth Berne

    2016-01-01

    This article examines the psychoanalytic concepts of object-relations theorist Christopher Bollas, applying them to a view of the Bible as "transformational object." Emphasizing the connection between psychological process and religious experience, this article suggests that each person's innate ability to choose and use objects is a key…

  19. Antibacterial activity of sulfamethoxazole transformation products (TPs): general relevance for sulfonamide TPs modified at the para position.

    Science.gov (United States)

    Majewsky, Marius; Wagner, Danny; Delay, Markus; Bräse, Stefan; Yargeau, Viviane; Horn, Harald

    2014-10-20

    Sulfonamide antibiotics undergo transformation in the aquatic environment through biodegradation, photolysis, or hydrolysis. In this study, the residual antibacterial activity of 11 transformation products (TPs) of sulfamethoxazole (SMX) was investigated with regard to their in vitro growth and luminescence inhibition on Vibrio fischeri (30 min and 24 h exposure). Two transformation products, 4-hydroxy-SMX and N(4)-hydroxy-acetyl-SMX, were synthesized in-house and confirmed by nuclear magnetic resonance and high-resolution mass spectrometry. Results of individual compound experiments showed that TPs modified at the para amino group still exhibit clear antibacterial effects, whereas TPs resulting from breakdown of the SMX structure lost this mechanism of action. 4-NO2- and 4-OH-SMX were found to inhibit growth to a clearly greater extent than the parent compound, SMX. In contrast, the N(4)-acetyl- and N(4)-hydroxy-acetyl-derivatives retain less than 10 and 5% of the effect of SMX on growth and luminescence inhibition, respectively. The effect of a mixture of para-modified TPs was observed to be additive. Considering the homologous series of sulfa drugs widely prescribed and their common mechanism of action, the potential environmental impact must consider the total amount of sulfonamide antibiotics and their derivative TPs, which might end up in a water body. Extrapolating the results obtained here for the para TPs of SMX to other sulfa drugs and determining the persistence and occurrence of these compounds in the aquatic environment is required for improved risk assessment.

  20. Advances and Opportunities in Ore Mineralogy

    Directory of Open Access Journals (Sweden)

    Nigel J. Cook

    2017-11-01

    Full Text Available The study of ore minerals is rapidly transforming due to an explosion of new micro- and nano-analytical technologies. These advanced microbeam techniques can expose the physical and chemical character of ore minerals at ever-better spatial resolution and analytical precision. The insights that can be obtained from ten of today’s most important, or emerging, techniques and methodologies are reviewed: laser-ablation inductively-coupled plasma mass spectrometry; focussed ion beam-scanning electron microscopy; high-angle annular dark field scanning transmission electron microscopy; electron back-scatter diffraction; synchrotron X-ray fluorescence mapping; automated mineral analysis (Quantitative Evaluation of Mineralogy via Scanning Electron Microscopy and Mineral Liberation Analysis; nanoscale secondary ion mass spectrometry; atom probe tomography; radioisotope geochronology using ore minerals; and, non-traditional stable isotopes. Many of these technical advances cut across conceptual boundaries between mineralogy and geochemistry and require an in-depth knowledge of the material that is being analysed. These technological advances are accompanied by changing approaches to ore mineralogy: the increased focus on trace element distributions; the challenges offered by nanoscale characterisation; and the recognition of the critical petrogenetic information in gangue minerals, and, thus the need to for a holistic approach to the characterization of mineral assemblages. Using original examples, with an emphasis on iron oxide-copper-gold deposits, we show how increased analytical capabilities, particularly imaging and chemical mapping at the nanoscale, offer the potential to resolve outstanding questions in ore mineralogy. Broad regional or deposit-scale genetic models can be validated or refuted by careful analysis at the smallest scales of observation. As the volume of information at different scales of observation expands, the level of complexity

  1. Mineralogical applications of Mossbauer spectroscopy

    International Nuclear Information System (INIS)

    Fysh, S.A.; Clark, P.E.

    1981-01-01

    The Mossbauer effect has been used to study a variety of bauxites, and has been shown to be capable of accurately characterizing the iron mineralogy of bauxite. Such studies may prove to be of great use in determining the suitability of bauxite for aluminium extraction, and in optimizing extraction conditions

  2. GEOCHEMISTRY AND MINERALOGICAL EVALUATION OF ...

    African Journals Online (AJOL)

    Dr Osondu

    2011-11-05

    Nov 5, 2011 ... mica-schist. AAS and XRD techniques were employed in the determination of chemical and mineralogical composition of ten .... Sample %. British Standard. Institution (BSI). %. American standard. (ASTM) %. SiO2. Al2O3. Fe2O3. TiO2. CaO. MgO. Na2O. K2O. P2O5. LO I. 46.65. 47.67. 1.02. 1.28. 0.10. 0.02.

  3. Environmental mineralogy - Understanding element behavior in ecosystems

    International Nuclear Information System (INIS)

    Brown Jr, G.E.; Calas, G.

    2011-01-01

    Environmental Mineralogy has developed over the past decade in response to the recognition that minerals are linked in many important ways with the global ecosystem. Minerals are the main repositories of the chemical elements in Earth's crust and thus are the main sources of elements needed for the development of civilization, contaminant and pollutant elements that impact global and local ecosystems, and elements that are essential plant nutrients. These elements are released from minerals through natural processes, such as chemical weathering, and anthropogenic activities, such as mining and energy production, agriculture and industrial activities, and careless waste disposal. Minerals also play key roles in the biogeochemical cycling of the elements, sequestering elements and releasing them as the primary minerals in crustal rocks undergo various structural and compositional transformations in response to physical, chemical, and biological processes that produce secondary minerals and soils. These processes have resulted in the release of toxic elements such as arsenic in groundwater aquifers, which is having a major impact on the health of millions of people in South and Southeast Asia. The interfaces between mineral surfaces and aqueous solutions are the locations of most chemical reactions that control the composition of the natural environment, including the composition of natural waters. The nuclear fuel cycle, from uranium mining to the disposition of high-level nuclear waste, is also intimately related to minerals. A fundamental understanding of these processes requires molecular-scale information about minerals, their bulk structures and properties such as solubility, their surfaces, and their interactions with aqueous solutions, atmospheric and soil gases, natural organic matter, and biological organisms. Gaining this understanding is further complicated by the presence of natural, incidental, and manufactured nano-particles in the environment, which

  4. Mineralogy: a modern approach to teaching a traditional discipline

    Science.gov (United States)

    Cook, G. W.

    2011-12-01

    Mineralogy has traditionally been a primary component in undergraduate geoscience curriculum. In recent years, there has been a trend in which mineralogy and petrology have been combined into Earth Materials courses. This is unfortunate as these disciplines each have much to offer students, and content once considered essential is eliminated out of necessity. Mineralogy is still fundamental to students' understanding of the Earth and Earth processes. Using a modern approach to time-honored concepts, I teach a quarter-long Introductory Mineralogy class offered through the Scripps Institution of Oceanography at the University of California, San Diego. Student evaluations of this course unequivocally indicate a high degree of learning and interest in the material, confirming that mineralogy continues to be a valuable class into the 21st century. While much of the content remains similar to what has been taught over the last century, my strategy involves a well-balanced approach to old and new. The first third of the course is background including the relevance of mineralogy, crystal chemistry, and crystallography; the second third of the course is systematic mineralogy using the Dana system; the last third of the course is devoted to understanding optical mineralogy, using modern analytical equipment such as XRD and SEM, and learning to use the petrographic microscope. Throughout the quarter, a strong emphasis is placed on the importance of hand-sample identification. Field work, traditionally not emphasized in mineralogy courses, has been re-introduced to the curriculum. I use modern technology to facilitate and support student learning. A lecture-based approach is employed with carefully crafted and organized PowerPoint presentations. PowerPoint lectures can be effective and highly engaging. The key is to ensure that the lectures are not overly reliant on text, instead relying on diagrams, charts, photos, and embedded media such as 3-D animations (ex. to teach

  5. Reflectance spectroscopy and asteroid surface mineralogy

    International Nuclear Information System (INIS)

    Gaffey, M.J.; Bell, J.F.; Cruikshank, D.P.

    1989-01-01

    Information available from reflectance spectroscopy on the surface mineralogy of asteroids is discussed. Current spectral interpretive procedures used in the investigations of asteroid mineralogy are described. Present understanding of the nature and history of asteroids is discussed together with some still unresolved issues such as the source of ordinary chondrites. 100 refs

  6. Quartzites beneath pyroclastic flows – mineralogical aspects

    Czech Academy of Sciences Publication Activity Database

    Malý, Karel; Cajz, Vladimír

    2005-01-01

    Roč. 37, č. 3 (2005), s. 370-371 ISSN 0369-2086 R&D Projects: GA AV ČR(CZ) IAA3013302 Institutional research plan: CEZ:AV0Z30130516 Keywords : quartzite * ignimbrite * mineralogy Subject RIV: DB - Geology ; Mineralogy

  7. Mineralogy of the Hydrous Lower Mantle

    Science.gov (United States)

    Shim, S. H.; Chen, H.; Leinenweber, K. D.; Kunz, M.; Prakapenka, V.; Bechtel, H.; Liu, Z.

    2017-12-01

    The hydrous ringwoodite inclusions found in diamonds suggest water storage in the mantle transition zone. However, water storage in the lower mantle remains unclear. Bridgmanite and magnesiowustite appear to have very little storage capacity for water. Here, we report experimental results indicating significant changes in the lower-mantle mineralogy under the presence of water. We have synthesized Mg2SiO4 ringwoodite with 2 wt% water in multi-anvil press at 20 GPa and 1573 K at ASU. The hydrous ringwoodite sample was then loaded to diamond anvil cells with Ar or Ne as a pressure medium. We heated the pure hydrous ringwoodite samples at lower-mantle pressure using a CO2 laser heating system at ASU. We measured X-ray diffraction patterns at the GSECARS sector of the Advanced Photon Source (APS) and 12.2.2 sector of the Advanced Light Source (ALS). For the separate Pt-mixed samples, we have conducted in situ heating at the beamlines using near IR laser heating systems. We measured the infrared spectra of the heated samples at high pressure and after pressure quench at 1.4.4 sector of ALS. In the in situ experiments with hydrous ringwoodite + Pt mixture as a starting material, we found formation of stishovite together with bridgmanite and periclase during heating with a near IR laser beams at 1300-2500 K and 35-66 GPa. However, some hydrous ringwoodite still remains even after a total of 45 min of heating. In contrast, the hydrous ringwoodite samples heated without Pt by CO2 laser beams are transformed completely to bridgmanite, periclase and stishovite at 31-55 GPa and 1600-1900 K. We have detected IR active OH mode of stishovite from the samples heated at lower-mantle pressures. The unit-cell volume of stishovite measured after pressure quench is greater than that of dry stishovite by 0.3-0.6%, supporting 0.5-1 wt% of H2O in stishovite in these samples. Stishovite is a thermodynamically forbidden phase in the dry lower mantle because of the existence of periclase and

  8. Erratum to: Psammoma bodies in two types of human ovarian tumours: a mineralogical study

    Science.gov (United States)

    Meng, Fanlu; Wang, Changqiu; Li, Yan; Lu, Anhuai; Mei, Fang; Liu, Jianying; Du, Jingyun; Zhang, Yan

    2015-06-01

    Psammoma body (PB) is a common form of calcification in pathological diagnosis and closely relevant to tumours. This paper focuses on the mineralogical characteristics of PBs in ovarian serous cancer and teratoma by using polarization microscope (POM), environmental scanning electron microscope (ESEM), micro-Fourier transform infrared spectroscopy (micro-FT-IR), transmission electron microscope (TEM), micro-area synchrotron radiation X-ray powder diffraction (μ-SRXRD) and fluorescence (μ-SRXRF). Both the PBs in tissues and separated from eight typical cases were investigated. POM and ESEM observation revealed the inside-out growth pattern of PBs. μ-SRXRD and micro-FT-IR results demonstrated the dominant mineral phase of PBs in ovarian serous cancer and teratoma was AB-type carbonate hydroxyapatite (Ca10[(PO4)6-x-y(CO3)x(HPO4)y][(OH)2-u(CO3)u] with 0 ≤ x,y,u ≤ 2). As observed by ESEM and TEM, the layer-rich PBs in teratoma were up to 70 μm and mainly consisted of 5 nm-wide, 5-12 nm-long columnar crystals; the PBs in ovarian serous cancer with a maximum diameter of 35 μm were composed of slightly longer columnar crystals and granulates with 20-100 nm in diameter. The selected area electron diffraction patterns showed dispersed polycrystalline diffraction rings with arching behavior of (002) diffraction, indicating the aggregated nanocrystals grew in the preferred orientation of (002) face. The EDX and μ-SRXRF results together indicated the existence of Na, Mg, Zn and Sr in PBs. These detailed mineralogical characteristics may help uncover the nature of the pathological PBs in ovary.

  9. Psammoma bodies in two types of human ovarian tumours: a mineralogical study

    Science.gov (United States)

    Fanlu, Meng; Changqiu, Wang; Yan, Li; Anhuai, Lu; Fang, Mei; Jianying, Liu; Jingyun, Du; Yan, Zhang

    2015-06-01

    Psammoma body (PB) is a common form of calcification in pathological diagnosis and closely relevant to tumours. This paper focuses on the mineralogical characteristics of PBs in ovarian serous cancer and teratoma by using polarization microscope (POM), environmental scanning electron microscope (ESEM), micro-Fourier transform infrared spectroscopy (micro-FT-IR), transmission electron microscope (TEM), micro-area synchrotron radiation X-ray powder diffraction (μ-SRXRD) and fluorescence (μ-SRXRF). Both the PBs in tissues and separated from eight typical cases were investigated. POM and ESEM observation revealed the inside-out growth pattern of PBs. μ-SRXRD and micro-FT-IR results demonstrated the dominant mineral phase of PBs in ovarian serous cancer and teratoma was AB-type carbonate hydroxyapatite (Ca10[(PO4)6-x-y(CO3)x(HPO4 2-)y][(OH)2-u(CO3)u] with 0 ≤ x,y,u ≤ 2). As observed by ESEM and TEM, the layer-rich PBs in teratoma were up to 70 μm and mainly consisted of 5 nm-wide, 5-12 nm-long columnar crystals; the PBs in ovarian serous cancer with a maximum diameter of 35 μm were composed of slightly longer columnar crystals and granulates with 20-100 nm in diameter. The selected area electron diffraction patterns showed dispersed polycrystalline diffraction rings with arching behavior of (002) diffraction, indicating the aggregated nanocrystals grew in the preferred orientation of (002) face. The EDX and μ-SRXRF results together indicated the existence of Na, Mg, Zn and Sr in PBs. These detailed mineralogical characteristics may help uncover the nature of the pathological PBs in ovary.

  10. Geochemical and mineralogical characteristics of Lithomargic clay

    African Journals Online (AJOL)

    Administrator

    Geochemical and mineralogical characteristics of Lithomargic clay. GEOCHEMICAL AND .... tries, as filling material in the pulp and paper, toothpaste and paint industries as well ..... tions very vital to human health and other ac- tivities of man.

  11. Mineralogy of the rare earth elements

    International Nuclear Information System (INIS)

    Clark, A.M.

    1984-01-01

    This paper contains mineralogic properties of the rare earth elements (REE). Notes are given on total REE abundances, distribution patterns, and modes of occurrence. References are confined as far as possible to papers containing usable REE data. The minerals are grouped alphabetically within each major cationic group. The paper includes an alphabetic table of mineral names, chemical formulas, crystal system and section number. It functions as a handy entrance to the mineralogic and bibliographic paper. (G.J.P.)

  12. Mineralogical conversion of asbestos containing materials

    International Nuclear Information System (INIS)

    Pulsford, S.K.; Foltz, A.D.; Ek, R.B.

    1996-01-01

    The principal objective of the Technical Task Plan (TTP) is to demonstrate a thermal-chemical mineralogical asbestos conversion unit at the Hanford Site, which converts non-radiological asbestos containing materials (ACMs) into an asbestos-free material. The permanent thermal-chemical mineralogical conversion of ACMs to a non-toxic, non-hazardous, potentially marketable end product should not only significantly reduce the waste stream volumes but terminate the open-quotes cradle to graveclose quotes ownership liabilities

  13. Mineralogical and chemical characterization of various bentonite and smectite-rich clay materials Part A: Comparison and development of mineralogical characterization methods Part B: Mineralogical and chemical characterization of clay materials

    International Nuclear Information System (INIS)

    Kumpulainen, S.; Kiviranta, L.

    2010-06-01

    Mineralogy is an essential issue in understanding thermo-hydro-mechanical-chemical (THMC) behavior of bentonite materials. Mineralogy affects, among others, chemical composition of pore water, susceptibility for erosion, and transport of radionuclides. Consequently, mineralogy affects the designs of the buffer and backfill components. The objective of this work was to implement and develop mineralogical and chemical methods for characterization of reference clays considered for use as buffer and backfill materials in nuclear waste disposal. In this work, different methods were tested, compared, developed, and best available techniques selected. An additional aim was to characterize reference materials that are used in various nuclear waste disposal supporting studies, e.g., the SKB's alternative buffer material (ABM) experiment. Materials studied included three Wyoming-bentonites, two bentonites from Milos, four bentonites from Kutch district, and two Friedland clays. Minerals were identified using x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and polarizing microscopy. Mineralogical composition was estimated using Rietveld-analysis. Chemical methods were used to support and validate mineralogical interpretation. Total chemical composition was determined from decomposed samples using spectrometry (ICP-AES) and combustion (Leco-S, Leco-C). Ferric and ferrous iron species were distinguished titrimetrically and the amount of soluble sulphate was determined using ion chromatography. In addition, cation exchange capacity and original exchangeable cations were determined. Chemical composition of fine (<2 μ m) fractions and poorly crystalline Fe-, Al- and Si-phases determined by selective extractions were used in structural calculations of smectite. XRD is a basic method for all mineralogical characterization, but it is insensitive for detecting trace minerals and variations in the structural chemical composition of clay minerals. Polarizing

  14. Mineralogical diversity and geology of Humboldt crater derived using Moon Mineralogy Mapper data

    NARCIS (Netherlands)

    Martinot, M.; Besse, S.; Flahaut, J.; Quantin-Nataf, C.; Lozac'h, L.; van Westrenen, W.

    2018-01-01

    Moon Mineralogy Mapper (M3) spectroscopic data and high-resolution imagery data sets were used to study the mineralogy and geology of the 207 km diameter Humboldt crater. Analyses of M3 data, using a custom-made method for M3 spectra continuum removal and spectral parameters calculation, reveal

  15. Sensitivity analysis of alkaline plume modelling: influence of mineralogy

    International Nuclear Information System (INIS)

    Gaboreau, S.; Claret, F.; Marty, N.; Burnol, A.; Tournassat, C.; Gaucher, E.C.; Munier, I.; Michau, N.; Cochepin, B.

    2010-01-01

    young alkaline-rich concrete (pH = 13.5) and aged concrete (pH = 12.5) were also tested. Simulations were run with PHREEQC 1D at 25 deg. C and at thermodynamic equilibrium. Diffusion of solutes in the pore water of the solid media was considered to be the dominant transport process. The heterogeneous hydraulic properties of both media (porosity and diffusion) are taken into account using the 'MIX' option of PHREEQC. Simulations of interactions between concrete, with either nanocrystalline or crystalline phases, and clayey materials all led to a clogging of the porosity. The clogging times, estimated without taking into account any feedback on diffusive transport parameters, are of the same order of magnitude (from 2,700 to 20,000 years). The reaction pathways and the extent of the mineralogical transformations were very slightly different when crystalline vs. nanocrystalline materials were considered within the same system (e.g. MX80 - concrete). However, the location of the porosity clogging depended on the considered nature of concrete: all simulations performed with young high pH concrete led to clogging in the concrete part of the system while simulations performed with aged concrete led to clogging in the concrete material only when nano-crystallized material was considered. Otherwise, porosity was clogged in the clay materials. Significant extents of mineralogical transformations were always limited to less than one meter. The computed extensions of the alkaline pH plumes showed almost no difference. To complete the sensitivity analysis, some calculations were performed with a retro-action law of the porosity clogging on the transport parameters (diffusion coefficients) which are presented in Claret et al., 2009, this issue. The effect of mineral dissolution/precipitation under kinetic constraints rather than local equilibrium is the subject of further investigations. (authors)

  16. Landslide: Mineralogical and Physical Investigation

    Science.gov (United States)

    Tudor, Viluș; Grozav, Adia; Rogobete, Gheorghe

    2017-10-01

    In order to construct a road bed foundation, if land has moved, on an area with old landslides, there is a high chance of it moving again. The investigation was made in a region with hilly relief, in which the parent materials of soils are argillaceous marls of Pliocene age. Because the slope is scarped and the versant has been cut, the soil mass slide favoured of the particle-size distribution dominated by heavy clay. With a reiteratedly percolative moisture regime, the soil material is saturated in water fora long period (700-800 mm precipitation/year), and that can increase the slope mass, thereby increasing the driving forces. In a soil profile situated on the top of the hill, with landslide for about 40 m length of the road, disturbed and undisturbed soil samples were analysed physic-chemical and mineralogical. For the heavy and light minerals from the sand fraction a polarized light analyser is used, and for clay minerals X-ray, differential thermal and infrared absorption method are used. The particle-size distribution in the soil profile is dominated by the clay fraction, which reached 53.2% in the ABt horizon and 63.0% in the Bt horizon (67-93 cm depth). The structure of the light minerals, consists of quartz (41-58%); feldspar (10.16-18.10%); muscovite (14.10-26.04). The heavy minerals are oxides (2.61-15.26%), hornblende (0.58-2.87%) and biotite (0.51-2.68%). It must be mentioned the presence of the metamorphic minerals, with the source of the Poiana Rusca mountains. These minerals are epidote (1.01-1.86%), disthene (0.70-1.86%), staurolite (0.73-2.46%) and sillimanite (0.35-0.45%). The clay minerals, inherited from the parent material or formed during the soil-forming process are dominated by smectite, which represent (71-85%) from the total clay minerals, illite 10-21%, and Kaolinite, 4-12%. Rheological properties, like plastic index (53.8%), activity index (1.01%) and consistency index (0.99-1.00%) show that the shrinkage - swelling processes are

  17. Skeletal carbonate mineralogy of Scottish bryozoans

    Science.gov (United States)

    Spencer Jones, Mary; Najorka, Jens; Smith, Abigail M.

    2018-01-01

    This paper describes the skeletal carbonate mineralogy of 156 bryozoan species collected from Scotland (sourced both from museum collections and from waters around Scotland) and collated from literature. This collection represents 79% of the species which inhabit Scottish waters and is a greater number and proportion of extant species than any previous regional study. The study is also of significance globally where the data augment the growing database of mineralogical analyses and offers first analyses for 26 genera and four families. Specimens were collated through a combination of field sampling and existing collections and were analysed by X-ray diffraction (XRD) and micro-XRD to determine wt% MgCO3 in calcite and wt% aragonite. Species distribution data and phylogenetic organisation were applied to understand distributional, taxonomic and phylo-mineralogical patterns. Analysis of the skeletal composition of Scottish bryozoans shows that the group is statistically different from neighbouring Arctic fauna but features a range of mineralogy comparable to other temperate regions. As has been previously reported, cyclostomes feature low Mg in calcite and very little aragonite, whereas cheilostomes show much more variability, including bimineralic species. Scotland is a highly variable region, open to biological and environmental influx from all directions, and bryozoans exhibit this in the wide range of within-species mineralogical variability they present. This plasticity in skeletal composition may be driven by a combination of environmentally-induced phenotypic variation, or physiological factors. A flexible response to environment, as manifested in a wide range of skeletal mineralogy within a species, may be one characteristic of successful invasive bryozoans. PMID:29897916

  18. Mineralogical behaviour of bentonites in open and closed systems

    International Nuclear Information System (INIS)

    Herbert, H.J.; Kasbohm, J.

    2004-01-01

    Mineralogical and chemical changes of bentonites were investigated in a natural analogue study and in laboratory experiments. As a working hypothesis we assumed that in geological, i.e. open systems, bentonites may be penetrated over geological time scales by larger water volumes than high compacted bentonites used as technical barriers in repositories in salt formations. Under this assumption open geological systems are characterised by low solid/liquid ratios and closed repository systems by high solid/liquid ratios. Consequently in laboratory experiments the mineralogical changes were investigated under different solid/liquid ratios and compared with results of a natural analogue study. In the natural analogue study in deep boreholes in the East Slovakian Basin the expandability of montmorillonite and the degree of transformation in illite-smectite (IS) mixed layer structures was found to be dependent not only on depth and temperature but also on the salinity of the pore waters. In this open geological system with a comparatively low solid/liquid ratio the observed changes in the montmorillonite were significantly different than those observed in the laboratory study on compacted MX-80 bentonite. (authors)

  19. Mineralogical and particulate morphological characterization of ...

    African Journals Online (AJOL)

    Six representative geophagic clayey soils from Botswana were mineralogically characterized using X-ray powder diffractometry (XRPD), optical microscopy, and environmental scanning electron microscopy (ESEM). Results of identified mineral phases revealed quartz (SiO2) as the most dominant in all samples constituting ...

  20. Chemical and mineralogical characterization and ceramic suitability ...

    African Journals Online (AJOL)

    The chemical and mineralogical characterization of raw feldspathic materials from Dschang (Cameroon) was realized by means of X-ray diffraction, differential thermal analyses, optical and scanning electron microscopies, and analytical techniques. It was found that these materials consist of albite (43 ± 3 wt.%), microcline ...

  1. Influence of mineralogical and heavy metal composition on natural radionuclide concentrations in the river sediments

    Energy Technology Data Exchange (ETDEWEB)

    Suresh, G., E-mail: gsureshphy_1983@yahoo.co.in [Department of Physics Thiruvalluvar College of Engg and Tech, Ponnur hills, Vandavasi, Tamilnadu 604 505 (India); Ramasamy, V. [Department of Physics, Annamalai University, Tamilnadu (India); Meenakshisundaram, V. [Health and Safety Division, IGCAR, Kalpakkam, Tamilnadu (India); Venkatachalapathy, R. [CAS in Marine Biology, Faculty of Marine Sciences, Annamalai University, Tamilnadu (India); Ponnusamy, V. [Department of Physics, MIT Campus, Anna University Chennai, Tamilnadu (India)

    2011-10-15

    The natural radiation level has been determined for the sediment samples of the Ponnaiyar River with an aim of evaluating the radiation hazard. The mineralogical characterizations of the sediments have been carried out using the Fourier Transform Infrared (FTIR) spectroscopic technique. The relative distribution of major minerals is determined by calculating extinction coefficient. The concentration and spatial distribution of heavy metals (Pb, Cr, Cu, Zn and Ni) have been studied to understand the heavy metal contamination and its level of toxicity. To evaluate the potential toxicity, heavy metal concentrations are compared with different toxicological and geological reference values. The comparison results suggest that the present metals create an adverse effect on the aquatic ecosystems associated with this river. To assess the sediment contamination due to the studied heavy metals, the Pollution Load Index (PLI) is calculated. Multivariate Statistical analyses (Pearson Correlation, Cluster and Factor analysis) were carried out between the parameters obtained from radioactivity, mineralogical and geochemical analysis to know the existing relations. Obtained results showed that the effect of mineralogy on level of radioactivity should be significant. However, mineralogy effect on heavy metal composition in the sediments should be limited, indicating that other factors such as vicinity of the pollution sources are more important. Also, the influence of mineralogical characterization on level of radioactivity is significant, whereas the influence of the heavy metal composition on level of radioactivity should be limited. - Highlights: >Sediments radioactivity, mineralogical and heavy metal characterization have been analyzed. > Absorbed dose rate, PLI and kaolinite increase towards the river mouth. > Influence of minerals and heavy metals on level of radioactivity is assessed.

  2. Influence of mineralogical and heavy metal composition on natural radionuclide concentrations in the river sediments

    International Nuclear Information System (INIS)

    Suresh, G.; Ramasamy, V.; Meenakshisundaram, V.; Venkatachalapathy, R.; Ponnusamy, V.

    2011-01-01

    The natural radiation level has been determined for the sediment samples of the Ponnaiyar River with an aim of evaluating the radiation hazard. The mineralogical characterizations of the sediments have been carried out using the Fourier Transform Infrared (FTIR) spectroscopic technique. The relative distribution of major minerals is determined by calculating extinction coefficient. The concentration and spatial distribution of heavy metals (Pb, Cr, Cu, Zn and Ni) have been studied to understand the heavy metal contamination and its level of toxicity. To evaluate the potential toxicity, heavy metal concentrations are compared with different toxicological and geological reference values. The comparison results suggest that the present metals create an adverse effect on the aquatic ecosystems associated with this river. To assess the sediment contamination due to the studied heavy metals, the Pollution Load Index (PLI) is calculated. Multivariate Statistical analyses (Pearson Correlation, Cluster and Factor analysis) were carried out between the parameters obtained from radioactivity, mineralogical and geochemical analysis to know the existing relations. Obtained results showed that the effect of mineralogy on level of radioactivity should be significant. However, mineralogy effect on heavy metal composition in the sediments should be limited, indicating that other factors such as vicinity of the pollution sources are more important. Also, the influence of mineralogical characterization on level of radioactivity is significant, whereas the influence of the heavy metal composition on level of radioactivity should be limited. - Highlights: →Sediments radioactivity, mineralogical and heavy metal characterization have been analyzed. → Absorbed dose rate, PLI and kaolinite increase towards the river mouth. → Influence of minerals and heavy metals on level of radioactivity is assessed.

  3. SITE-94. Mineralogy of the Aespoe site

    International Nuclear Information System (INIS)

    Andersson, Karin

    1996-12-01

    The water composition has several impacts on the repository. It will influence the behaviour of the engineered materials (e.g. corrosion). It may also determine the possible solubility and speciation of released radionuclides. It also acts as a transport medium for the released elements. The groundwater composition and the potential development of the composition due to the presence of the repository as well as due to external variations is thus an important issue in a safety analysis. The development of the groundwater composition is strongly dependent on reactions with the minerals present in water bearing fractures. Here equilibrium chemistry may be of importance, but also reaction kinetics is important to the long-term behaviour. Within the SITE-94 project, a safety analysis is performed for the conditions at the Aespoe site. The mineralogy of the area has been evaluated from drill cores at various places at the site. In this report a recommendation for selection of mineralogy to be used in geochemical modelling of the repository is given. Calcite and iron containing minerals dominate the fracture filling mineralogy at the Aespoe site. Some typical fracture filling mineralogies may be identified in the fractures: epidote, chlorite, calcite, hematite, some illite/smectite + quartz, fluorite, pyrite and goethite. In addition to these a number of minor minerals are found in the fractures. Uncertainties in the fracture filling data may be due to problems when taking out the drill cores. Drilling water may remove important clay minerals and sealed fractures may be reopened mechanically and treated as water conducting fractures. The problem of determining the variability of the mineralogy along the flow paths also remains. This problem will never be solved when the investigation is performed by drilling investigation holes

  4. Mineralogical composition changes of postagrogenic soils under different plant communities.

    Science.gov (United States)

    Churilin, Nikita; Chizhikova, Natalia; Varlamov, Evgheni; Churilina, Alexandra

    2017-04-01

    Plant communities play the leading role in transformation of soil. The need of studying former arable lands increases due to large number of abandoned lands in Russia. It is necessary to study mineralogical composition of soils involved into natural processes to understand the trends of their development after agricultural activities in the past. The aim of the study is to identify changes in mineralogical composition of soils under the influence of different plant communities. Soils were sampled in the south of Arkhangelsk region, Ustyansky district, near Akichkin Pochinok village. Soils are formed on clay moraine of Moscow glaciation. Soil profiles were dug on interfluve. We selected 4 plant communities on different stages of succession: upland meadow with domination of sod grasses (Phleum pratense, Agrostis tenuis), 16-year-old birch forest where dominants are herbaceous plants such as Poa sp., Chamerion angustiflium, Agrostis tenuis, 16-year-old spruce forest with no herbaceous vegetation and 70-year-old bilberry spruce forest with domination of Vaccinium myrtillus and Vaccinium vitis-idaea. To separate soil fractions mineral content. We noticed a clear differentiation of studied soils both in the content of fraction and composition of minerals. Mineralogical composition and major mineral phases correlation of profiles under 70 years and 16 years of spruce forests are different. Mineralogical content in upper part of profile under the young spruce is more differentiated than in old spruce forest: the amount of quartz and kaolinite increases in upper horizon, although in this case the overall pattern of profile formation of clay material during podzolization remains unchanged. There is more substantial desilting under the birch forest, compared with profile under the spruce of same age within top 50 cm. Under the meadow vegetation we've discovered differentiation in mineral composition. Upper horizons contain smectite phase and differ from the underlying

  5. Mineralogical characterization of uranium yellow cake concentrates

    International Nuclear Information System (INIS)

    Hausen, D.M.

    1992-01-01

    Uranium yellow cake concentrates have been analyzed and characterized mineralogically by means of differential thermal analysis, X-ray diffraction, infrared spectra and wet chemical methods. On the basis of mineralogical methods of characterization, the following four major structural types of yellow cake may be classified: Uranyl Hydroxide Hydrate, UO 2 (OH) 2 nH 2 O; Basic Uranyl Sulfate Hydrate, (UO 2 ) x (SO 4 ) y (OH) s(x-y ).nH 2 O; Sodium Para-Uranate, Na 5 U 7 O 24 and Uranyl Peroxide Hydrate, UO 4 .nH 2 O. In this paper conditions of yellow cake preparation and characterization are described, along with discussion of significance of structural types to the physical and chemical properties of yellow cake production

  6. Mineralogical characterization of West Chestnut Ridge soils

    International Nuclear Information System (INIS)

    Lee, S.Y.; Kopp, O.C.; Lietzke, D.A.

    1984-12-01

    The morphological, physicochemical, and mineralogical properties of the soils and residua from the proposed site of the Central Waste Disposal Facility were characterized. The proposed site is underlain by cherty dolostones, limestones, and shales of the Knox Group covered by a thick residuum. Three diagnostic horizons from four soil profiles and six samples from residuum cores were selected for mineralogical analysis. The coarse fractions (gravel and sand) of the samples included different types of chert, iron-manganese oxide nodules, and quartz. The samples were high in clay content (except those from the A and E horizons) and low in pH and base saturation. The clay fractions were composed of varying amounts of kaolinite, mica, vermiculite, aluminum hydroxy-interlayered vermiculite, amorphous iron and aluminum oxides, gibbsite, and quartz. Aluminum hydroxy-interlayered vermiculite is the major component in surface horizons, but kaolinite becomes dominant in subsurface horizons of the soils. Degradation of kaolinite and formation of aluminum hydroxy-interlayered vermiculite and iron and aluminum oxides are pronounced chemical weathering processes in the surface soils. The aluminum hydroxy interlayering of vermiculite reduces cation exchange and selective sorption capacities of soils. In the residua, micaceous minerals free of aluminum hydroxy interlayering, kaolinite, and amorphous iron and aluminum oxides are major components in the clay fraction. The sorption ratios of 137 Cs, 90 Sr, 60 Co, and the uranium isotopes expected to be in the radioactive wastes should be very high for the clays having such mineralogical composition. The low acid-buffering capacity (base saturation) of the residua suggest that the fragile chemical and mineralogical equilibria can be easily broken if an extreme chemical condition is imposed on the residua

  7. Mineralogical Diversity and Geology of Humboldt Crater Derived Using Moon Mineralogy Mapper Data

    Science.gov (United States)

    Martinot, M.; Besse, S.; Flahaut, J.; Quantin-Nataf, C.; Lozac'h, L.; van Westrenen, W.

    2018-02-01

    Moon Mineralogy Mapper (M3) spectroscopic data and high-resolution imagery data sets were used to study the mineralogy and geology of the 207 km diameter Humboldt crater. Analyses of M3 data, using a custom-made method for M3 spectra continuum removal and spectral parameters calculation, reveal multiple pure crystalline plagioclase detections within the Humboldt crater central peak complex, hinting at its crustal origin. However, olivine, spinel, and glass are observed in the crater walls and rims, suggesting these minerals derive from shallower levels than the plagioclase of the central peak complex. High-calcium pyroxenes are detected in association with volcanic deposits emplaced on the crater's floor. Geologic mapping was performed, and the age of Humboldt crater's units was estimated from crater counts. Results suggest that volcanic activity within this floor-fractured crater spanned over a billion years. The felsic mineralogy of the central peak complex region, which presumably excavated deeper material, and the shallow mafic minerals (olivine and spinel) detected in Humboldt crater walls and rim are not in accordance with the general view of the structure of the lunar crust. Our observations can be explained by the presence of a mafic pluton emplaced in the anorthositic crust prior to the Humboldt-forming impact event. Alternatively, the excavation of Australe basin ejecta could explain the observed mineralogical detections. This highlights the importance of detailed combined mineralogical and geological remote sensing studies to assess the heterogeneity of the lunar crust.

  8. Mineralogical Diversity and Geology of Humboldt Crater Derived Using Moon Mineralogy Mapper Data.

    Science.gov (United States)

    Martinot, M; Besse, S; Flahaut, J; Quantin-Nataf, C; Lozac'h, L; van Westrenen, W

    2018-02-01

    Moon Mineralogy Mapper (M 3 ) spectroscopic data and high-resolution imagery data sets were used to study the mineralogy and geology of the 207 km diameter Humboldt crater. Analyses of M 3 data, using a custom-made method for M 3 spectra continuum removal and spectral parameters calculation, reveal multiple pure crystalline plagioclase detections within the Humboldt crater central peak complex, hinting at its crustal origin. However, olivine, spinel, and glass are observed in the crater walls and rims, suggesting these minerals derive from shallower levels than the plagioclase of the central peak complex. High-calcium pyroxenes are detected in association with volcanic deposits emplaced on the crater's floor. Geologic mapping was performed, and the age of Humboldt crater's units was estimated from crater counts. Results suggest that volcanic activity within this floor-fractured crater spanned over a billion years. The felsic mineralogy of the central peak complex region, which presumably excavated deeper material, and the shallow mafic minerals (olivine and spinel) detected in Humboldt crater walls and rim are not in accordance with the general view of the structure of the lunar crust. Our observations can be explained by the presence of a mafic pluton emplaced in the anorthositic crust prior to the Humboldt-forming impact event. Alternatively, the excavation of Australe basin ejecta could explain the observed mineralogical detections. This highlights the importance of detailed combined mineralogical and geological remote sensing studies to assess the heterogeneity of the lunar crust.

  9. Superficial alteration mineralogy in active volcanic systems : An example of Poás volcano, Costa Rica

    NARCIS (Netherlands)

    Rodríguez, Alejandro; van Bergen, Manfred J.

    2017-01-01

    The alteration mineralogy in the crater area of Poás volcano (Costa Rica) has been studied to constrain acid fluid-rock interaction processes and conditions relevant for the formation of sulphate-bearing mineral assemblages found on the surface of Mars. Individual sub-environments, which include the

  10. Uranium geochemistry, mineralogy, geology, exploration and resources

    International Nuclear Information System (INIS)

    De Vivo, B.

    1984-01-01

    This book comprises papers on the following topics: history of radioactivity; uranium in mantle processes; transport and deposition of uranium in hydrothermal systems at temperatures up to 300 0 C: Geological implications; geochemical behaviour of uranium in the supergene environment; uranium exploration techniques; uranium mineralogy; time, crustal evolution and generation of uranium deposits; uranium exploration; geochemistry of uranium in the hydrographic network; uranium deposits of the world, excluding Europe; uranium deposits in Europe; uranium in the economics of energy; role of high heat production granites in uranium province formation; and uranium deposits

  11. Mineralogic Model (MM3.0) Report

    International Nuclear Information System (INIS)

    Sanchez, A.

    2004-01-01

    The purpose of this report is to provide a three-dimensional (3-D) representation of the mineral abundance within the geologic framework model domain. The mineralogic model enables project personnel to estimate mineral abundances at any position, within the model region, and within any stratigraphic unit in the model area. The model provides the abundance and distribution of 10 minerals and mineral groups within 22 stratigraphic sequences or model layers in the Yucca Mountain area. The uncertainties and limitations associated with this model are discussed in Section 6.4. Model validation accomplished by corroboration with data not cited as direct input is discussed in Section 7

  12. Fine particle magnetic mineralogy of archaeological ceramics

    International Nuclear Information System (INIS)

    Atkinson, D; King, J A

    2005-01-01

    This study investigated the magnetic mineralogy of a worldwide collection of archaeological pottery. The mineral types, the mass fractions and the domain states of the constituent magnetic fine particles were elucidated from a range of measurements including magnetic hysteresis behaviour, the acquisition of isothermal remanence, low field susceptibility and thermomagnetic curves. The magnetic mineralogy of most samples was dominated by magnetite. Titanomagnetites with limited titanium substitution and cation deficient magnetites (indicative of low temperature oxidation) were dominant in some samples. Haematite was detected in 53% of the samples, but seldom contributed much to the saturation magnetization. Magnetic particle sizes are skewed to smaller sizes, with sherds mostly having a large superparamagnetic or a stable single domain fraction. Low temperature susceptibility data suggest that 30% of samples had some multidomain component. The percentage by mass of magnetic material in the ancient pottery studied was less than 0.8% for all but one of the samples and the majority of samples contain less than 0.3% by weight of magnetic fine particles. The presence of low temperature oxidation in many samples and the occurrence of a multidomain component in a third of the collection suggest that ancient pottery may not always be suitable for determining the intensity of the ancient geomagnetic field

  13. Contribution to chemical-mineralogical study of carbonatites

    International Nuclear Information System (INIS)

    Costa, M.Q. da; Lima, W.N. de; Correa, S.L.A.

    1982-01-01

    A preliminary chemical-mineralogical study of carbonatites from Jacupiranga (SP,Brazil) and Alto Pinheiros (SC,Brazil) enabled not only to ratify hypotheses previously described by Brazilian researchers but also made clear certain aspects related to the geochemistry of carbonatites concerning their occurrence, the probable genesis of these species and their chemical and mineralogical characteristics.(Author) [pt

  14. Mineralogical composition and functionality of clays used for pottery ...

    African Journals Online (AJOL)

    Mineralogical composition and functionality of clays used for pottery education by physically challenged learners at the Ikwezi-Lokusa Educational Centre, Eastern Cape, South Africa. ... The clays were mineralogically characterised using Munsell Soil Color Chart, X-ray powder diffractometry (XRPD) and optical microscopy.

  15. Impact of pulp and paper mill effluents and solid wastes on soil mineralogical and physicochemical properties.

    Science.gov (United States)

    Adhikari, Gopi; Bhattacharyya, Krishna G

    2015-03-01

    The present study was carried out to evaluate the impact of the effluents and the solid wastes generated by a giant pulp and paper mill in the northeastern part of India on soil mineralogy of the area. The impacts were monitored by analysis of soil samples from seven sites located in the potential impact zone and a control site where any kind of effluent discharge or solid waste dumping was absent. The soil belonged to medium texture type (sandy clay loam, sandy loam, loamy sand, and silt loam), and the soil aggregate analysis indicated higher levels of organic carbon, pH, electrical conductivity, effective cation exchange capacity, and mean weight diameter at sites receiving effluents and solid wastes from the pulp and paper mill. Depletion in soil silica level and in feldspar and quartz contents and rise in iron and calcium contents at the sites receiving effluents from the pulp and paper mill indicated significant influence on soil mineralogy. The soil contained a mixture of minerals consisting of tectosilicates (with silicate frameworks as in quartz or feldspar), phylosilicates (layered clays like kaolinite, smectite, chlorite, illite, etc.), and carbonates. Absence of pure clay minerals indicated a state of heterogeneous intermediate soil clay transformation. The significance of the mixed mineralogy in relation to the disposal of effluents and dumping of solid wastes is discussed in details.

  16. Mineralogy of Non-Silicified Fossil Wood

    Directory of Open Access Journals (Sweden)

    George E. Mustoe

    2018-03-01

    Full Text Available The best-known and most-studied petrified wood specimens are those that are mineralized with polymorphs of silica: opal-A, opal-C, chalcedony, and quartz. Less familiar are fossil woods preserved with non-silica minerals. This report reviews discoveries of woods mineralized with calcium carbonate, calcium phosphate, various iron and copper minerals, manganese oxide, fluorite, barite, natrolite, and smectite clay. Regardless of composition, the processes of mineralization involve the same factors: availability of dissolved elements, pH, Eh, and burial temperature. Permeability of the wood and anatomical features also plays important roles in determining mineralization. When precipitation occurs in several episodes, fossil wood may have complex mineralogy.

  17. Mineralogical aspects of the laterites of Maicuru

    International Nuclear Information System (INIS)

    Lemos, V.P.; Costa, M.C. da

    1989-01-01

    This paper presents the prelimary mineralogical data of the weathering materials derived from the alkaline-ultramafic-carbonatitic Maicuru complex, State of Para. These material include several minerals species: iron, titanium and aluminium oxides/hydroxides as aluminous goethite, geothite, hematite, maghemite, lepidocrocite, anatase; and gibbsite; clay minerals of the smectite, chlorite, vermiculite and kaolinite groups and interstratified chlorite-smectite, mica-vermiculite, vermiculite-chlorite and Kaolinite-smectite; and aluminous phosphates of the crandalite group, wardite, augelite, senegalite, wavelite and variscite. The principal characteristics of these minerals were obtained by X-ray diffraction, optical methods, electron probe microanalysis, energy dispersive scanning electron microscope, X-ray fluorescence, atomic absorption, inductively coupled plasma-ICP source spectrometry and colorimetric methods. (author) [pt

  18. Multiscale characteristics of mechanical and mineralogical heterogeneity using nanoindentation and Maps Mineralogy in Mancos Shale

    Science.gov (United States)

    Yoon, H.; Mook, W. M.; Dewers, T. A.

    2017-12-01

    Multiscale characteristics of textural and compositional (e.g., clay, cement, organics, etc.) heterogeneity profoundly influence the mechanical properties of shale. In particular, strongly anisotropic (i.e., laminated) heterogeneities are often observed to have a significant influence on hydrological and mechanical properties. In this work, we investigate a sample of the Cretaceous Mancos Shale to explore the importance of lamination, cements, organic content, and the spatial distribution of these characteristics. For compositional and structural characterization, the mineralogical distribution of thin core sample polished by ion-milling is analyzed using QEMSCAN® with MAPS MineralogyTM (developed by FEI Corporoation). Based on mineralogy and organic matter distribution, multi-scale nanoindentation testing was performed to directly link compositional heterogeneity to mechanical properties. With FIB-SEM (3D) and high-magnitude SEM (2D) images, key nanoindentation patterns are analyzed to evaluate elastic and plastic responses. Combined with MAPs Mineralogy data and fine-resolution BSE images, nanoindentation results are explained as a function of compositional and structural heterogeneity. Finite element modeling is used to quantitatively evaluate the link between the heterogeneity and mechanical behavior during nanoindentation. In addition, the spatial distribution of compositional heterogeneity, anisotropic bedding patterns, and mechanical anisotropy are employed as inputs for multiscale brittle fracture simulations using a phase field model. Comparison of experimental and numerical simulations reveal that proper incorporation of additional material information, such as bedding layer thickness and other geometrical attributes of the microstructures, may yield improvements on the numerical predictions of the mesoscale fracture patterns and hence the macroscopic effective toughness. Sandia National Laboratories is a multimission laboratory managed and operated by

  19. Clay Mineralogy of AN Alluvial Aquifer in a Mountainous, Semiarid Terrain, AN Example from Rifle, Colorado

    Science.gov (United States)

    Elliott, W. C.; Lim, D.; Zaunbrecher, L. K.; Pickering, R. A.; Williams, K. H.; Navarre-Sitchler, A.; Long, P. E.; Noel, V.; Bargar, J.; Qafoku, N. P.

    2015-12-01

    Alluvial sediments deposited along the Colorado River corridor in the semi-arid regions of central to western Colorado can be important hosts for legacy contamination including U, V, As and Se. These alluvial sediments host aquifers which are thought to provide important "hot spots" and "hot moments" for microbiological activity controlling organic carbon processing and fluxes in the subsurface. Relatively little is known about the clay mineralogy of these alluvial aquifers and the parent alluvial sediments in spite of the fact that they commonly include lenses of silt-clay materials. These lenses are typically more reduced than coarser grained materials, but zones of reduced and more oxidized materials are present in these alluvial aquifer sediments. The clay mineralogy of the non-reduced parent alluvial sediments of the alluvial aquifer located in Rifle, CO (USA) is composed of chlorite, smectite, illite, kaolinite and quartz. The clay mineralogy of non-reduced fine-grained materials at Rifle are composed of the same suite of minerals found in the sediments plus a vermiculite-smectite intergrade that occurs near the bottom of the aquifer near the top of the Wasatch Formation. The clay mineral assemblages of the system reflect the mineralogically immature character of the source sediments. These assemblages are consistent with sediments and soils that formed in a moderately low rainfall climate and suggestive of minimal transport of the alluvial sediments from their source areas. Chlorite, smectite, smectite-vermiculite intergrade, and illite are the likely phases involved in the sorption of organic carbon and related microbial redox transformations of metals in these sediments. Both the occurrence and abundance of chlorite, smectite-vermiculite, illite and smectite can therefore exert an important control on the contaminant fluxes and are important determinants of biogeofacies in mountainous, semiarid terrains.

  20. Mineralogical and geochemical characterization of the Jurassic coal from Egypt

    Energy Technology Data Exchange (ETDEWEB)

    Baioumy, H.M. [Central Metallurgical Research and Development Institute, Cairo (Egypt)

    2009-06-15

    The Jurassic coal deposit in the Maghara area, Sinai, Egypt contains at least 11 coal seams of lenticular shape. The thickness of the main coal seams ranges from 130 cm to 2 m and are underlain and overlain by thin black shale beds. Mineralogical analysis indicated that this coal is characterized by low mineral matter with traces of quartz in some samples. However, coal ash is made up of quartz with traces of calcite, anhydrite, and hematite. Analysis of coal rank parameters indicated that the Maghara coal can be classified as medium volatile bituminous coal. The high sulfur contents and the relatively high proportion of pyritic sulfur suggest a possible marine transgression after the deposition of precursor peat. This interpretation is supported by the relatively high B contents. The relatively high Ge in the Maghara coal could be attributed to an infiltration of Ge enriched water from the surrounding siliceous sediments probably during diagenesis. The high Au contents were contributed to an Au-rich provenance of the ash contents of this coal. Rare earth elements geochemistry indicated low concentrations of these elements with slight enrichment of light rare earth elements (LREEs), slight negative Eu anomaly, and relatively flat heavy rare earth elements (HREEs) patterns. The low contents of trace and rare earth elements, particularly those with environmental relevance, compared to the usual concentration ranges in worldwide coal gives an advantage for this coal.

  1. Automated Quantitative Rare Earth Elements Mineralogy by Scanning Electron Microscopy

    Science.gov (United States)

    Sindern, Sven; Meyer, F. Michael

    2016-09-01

    Increasing industrial demand of rare earth elements (REEs) stems from the central role they play for advanced technologies and the accelerating move away from carbon-based fuels. However, REE production is often hampered by the chemical, mineralogical as well as textural complexity of the ores with a need for better understanding of their salient properties. This is not only essential for in-depth genetic interpretations but also for a robust assessment of ore quality and economic viability. The design of energy and cost-efficient processing of REE ores depends heavily on information about REE element deportment that can be made available employing automated quantitative process mineralogy. Quantitative mineralogy assigns numeric values to compositional and textural properties of mineral matter. Scanning electron microscopy (SEM) combined with a suitable software package for acquisition of backscatter electron and X-ray signals, phase assignment and image analysis is one of the most efficient tools for quantitative mineralogy. The four different SEM-based automated quantitative mineralogy systems, i.e. FEI QEMSCAN and MLA, Tescan TIMA and Zeiss Mineralogic Mining, which are commercially available, are briefly characterized. Using examples of quantitative REE mineralogy, this chapter illustrates capabilities and limitations of automated SEM-based systems. Chemical variability of REE minerals and analytical uncertainty can reduce performance of phase assignment. This is shown for the REE phases parisite and synchysite. In another example from a monazite REE deposit, the quantitative mineralogical parameters surface roughness and mineral association derived from image analysis are applied for automated discrimination of apatite formed in a breakdown reaction of monazite and apatite formed by metamorphism prior to monazite breakdown. SEM-based automated mineralogy fulfils all requirements for characterization of complex unconventional REE ores that will become

  2. Multivariate analysis of the geochemistry and mineralogy of soils along two continental-scale transects in North America

    Science.gov (United States)

    Drew, L.J.; Grunsky, E.C.; Sutphin, D.M.; Woodruff, L.G.

    2010-01-01

    Soils collected in 2004 along two North American continental-scale transects were subjected to geochemical and mineralogical analyses. In previous interpretations of these analyses, data were expressed in weight percent and parts per million, and thus were subject to the effect of the constant-sum phenomenon. In a new approach to the data, this effect was removed by using centered log-ratio transformations to 'open' the mineralogical and geochemical arrays. Multivariate analyses, including principal component and linear discriminant analyses, of the centered log-ratio data reveal the effects of soil-forming processes, including soil parent material, weathering, and soil age, at the continental-scale of the data arrays that were not readily apparent in the more conventionally presented data. Linear discriminant analysis of the data arrays indicates that the majority of the soil samples collected along the transects can be more successfully classified with Level 1 ecological regional-scale classification by the soil geochemistry than soil mineralogy. A primary objective of this study is to discover and describe, in a parsimonious way, geochemical processes that are both independent and inter-dependent and manifested through compositional data including estimates of the elements and corresponding mineralogy. ?? 2010.

  3. Mineralogical microanalysis of idiopathic pulmonary fibrosis

    International Nuclear Information System (INIS)

    Monso, E.; Tura, J.M.; Marsal, M.; Morell, F.; Pujadas, J.; Morera, J.

    1990-01-01

    A mineralogical analysis of lung tissue was conducted on 25 samples from patients who had been diagnosed as having idiopathic pulmonary fibrosis (IPF). Scanning electron microscopy (SEM) at low magnification and energy-dispersive x-ray analysis (EDXA) was used. In all samples, the surface silicon/sulfur (Si/S) ratio was calculated. The Si/S ratio for 25 samples of normal lung and 6 samples of pneumoconiotic lung was also determined (upper limit of normal Si/S ratio = 0.3). The difference between the Si/S ratio in the group with IPF and group with normal lung tissue was significantly significant (p less than .007, Wilcoxon test). Six of 12 patients with a previous diagnosis of IPF and a Si/S ratio greater than 0.3 had an exposure history that could imply inhalation of silica/silicates, and the correct diagnosis for these patients is most probably pneumoconiosis. The silica/silicate deposits detected in patients with IPF, and who had a ratio and no past exposure to dusts, could be either a cause or an effect of the disease

  4. Mineralogical microanalysis of idiopathic pulmonary fibrosis

    Energy Technology Data Exchange (ETDEWEB)

    Monso, E.; Tura, J.M.; Marsal, M.; Morell, F.; Pujadas, J.; Morera, J. (Hospital Germans Trias i Pujol, Badalona (Spain))

    1990-05-01

    A mineralogical analysis of lung tissue was conducted on 25 samples from patients who had been diagnosed as having idiopathic pulmonary fibrosis (IPF). Scanning electron microscopy (SEM) at low magnification and energy-dispersive x-ray analysis (EDXA) was used. In all samples, the surface silicon/sulfur (Si/S) ratio was calculated. The Si/S ratio for 25 samples of normal lung and 6 samples of pneumoconiotic lung was also determined (upper limit of normal Si/S ratio = 0.3). The difference between the Si/S ratio in the group with IPF and group with normal lung tissue was significantly significant (p less than .007, Wilcoxon test). Six of 12 patients with a previous diagnosis of IPF and a Si/S ratio greater than 0.3 had an exposure history that could imply inhalation of silica/silicates, and the correct diagnosis for these patients is most probably pneumoconiosis. The silica/silicate deposits detected in patients with IPF, and who had a ratio and no past exposure to dusts, could be either a cause or an effect of the disease.

  5. chemical and mineralogical characterization of lateritic iron ore

    African Journals Online (AJOL)

    DJFLEX

    2010-04-22

    Apr 22, 2010 ... The laterite iron ore deposit at Auchi, Edo State, Nigeria was studied chemically and mineralogically. The results of the chemical ... SAMPLE PREPARATION. The samples .... 2µm) and were subjected to X-ray diffraction using.

  6. Mineralogy of halloysites and their interaction with porphyrine

    Czech Academy of Sciences Publication Activity Database

    Vašutová, V.; Bezdička, Petr; Lang, Kamil; Hradil, David

    2013-01-01

    Roč. 57, č. 3 (2013), s. 243-250 ISSN 0862-5468 Institutional support: RVO:61388980 Keywords : organoclays * mineralogy * porphyrine * CEC Subject RIV: CA - Inorganic Chemistry Impact factor: 0.434, year: 2013

  7. The mineralogy of ordinary chondrites and implications for asteroid spectrophotometry

    Science.gov (United States)

    Mcsween, Harry Y., Jr.; Bennett, Marvin E., III; Jarosewich, Eugene

    1991-01-01

    Published data from bulk chemical analyses of 94 ordinary chondrites are compiled in a table of normative mineralogy and discussed in detail. Significant variations in olivine, pyroxene, and metal abundance ratios are found within each chondrite class and attributed to redox processes superimposed on initial differences in metal/silicate ratios. The use of the diagrams constructed here to predict the mineralogic characteristics of asteroids on the basis of spectrophotometric observations is suggested.

  8. Iron oxide and hydroxide precipitation from ferrous solutions and its relevance to Martian surface mineralogy

    Science.gov (United States)

    Posey-Dowty, J.; Moskowitz, B.; Crerar, D.; Hargraves, R.; Tanenbaum, L.

    1986-01-01

    Experiments were performed to examine if the ubiquitousness of a weak magnetic component in all Martian surface fines tested with the Viking Landers can be attributed to ferric iron precipitation in aqueous solution under oxidizing conditions at neutral pH. Ferrous solutions were mixed in deionized water and various minerals were added to separate liquid samples. The iron-bearing additives included hematite, goethite, magnetite, maghemite, lepidocrocite and potassium bromide blank at varying concentrations. IR spectroscopic scans were made to identify any precipitates resulting from bubbling oxygen throughout the solutions; the magnetic properties of the precipitates were also examined. The data indicated that the lepidocrocite may have been preferentially precipitated, then aged to maghemite. The process would account for the presumed thin residue of maghemite on the present Martian surface, long after abundant liquid water on the Martian surface vanished.

  9. Iron oxide and hydroxide precipitation from ferrous solutions and its relevance to Martian surface mineralogy

    International Nuclear Information System (INIS)

    Posey-Dowty, J.; Moskowitz, B.; Crerar, D.; Hargraves, R.; Tanenbaum, L.

    1986-01-01

    Experiments were performed to examine if the ubiquitousness of a weak magnetic component in all Martian surface fines tested with the Viking Landers can be attributed to ferric iron precipitation in aqueous solution under oxidizing conditions at neutral pH. Ferrous solutions were mixed in deionized water and various minerals were added to separate liquid samples. The iron-bearing additives included hematite, goethite, magnetite, maghemite, lepidocrocite and potassium bromide blank at varying concentrations. IR spectroscopic scans were made to identify any precipitates resulting from bubbling oxygen throughout the solutions; the magnetic properties of the precipitates were also examined. The data indicated that the lepidocrocite may have been preferentially precipitated, then aged to maghemite. The process would account for the presumed thin residue of maghemite on the present Martian surface, long after abundant liquid water on the Martian surface vanished. 40 references

  10. Comparison of the mineralogical effects of an experimental forest fire on a goethite/ferrihydrite soil with a topsoil that contains hematite, maghemite and goethite

    DEFF Research Database (Denmark)

    Nørnberg, Per; Vendelboe, Anders Lindblad; Gunnlaugsson, Haraldur Pall

    2009-01-01

    as the result of high temperature as found after forest fires. However, a body of evidence argues against these sites having been exposed to fire. In an attempt to get closer to an explanation of this Fe mineralogy, an experimental forest fire was produced. The results showed a clear mineralogical zonation down...... to 10 cm depth. This was not observed at the natural sites, which contained a mixture of goethite/ferrihydrite, hematite and maghemite down to 20 cm depth. The experimental forest fire left charcoal and ashes at the topsoil, produced high pH and decreased organic matter content, all of which...... is in contrast to the natural sites. The conclusion from this work is that the mineralogy of these sites is not consistent with exposure to forest fire, but may instead result from long-term transformation in a reducing environment, possibly involving microbiology....

  11. Geomicrobiology; inseparable from low temperature geochemistry & mineralogy

    Science.gov (United States)

    Southam, G.

    2009-05-01

    Bacteria play an important role in catalyzing a wide array of biogeochemical processes that affect the dissolution of minerals, the aqueous geochemistry of their surroundings and secondary mineral formation. Processes occurring at the bacteria-mineral interface can occur on the scale of nanoenvironments and will normally extend to microenvironments or even, to macroscopic features where extensive growth of bacteria is supported. The action of bacteria in these systems can produce a wide range of biomarkers that can be preserved over geologic time periods. Possible biomarkers include dissolution features in mineral substrates, fossil structures of individual cells to complex cell-cell associations, and chemical (isotopic and organic) signatures. In any system, we need to focus at the scale of the bacteria themselves to appreciate the actual chemistry of their surroundings and the kinds of reactions that they can catalyse. For example, photosynthetic microbial mats in an Atlin, BC wetland create ideal conditions for biologically induced precipitation of magnesium carbonates, specifically dypingite Mg5(CO3)4(OH)25H2O, which we were unable to reproduce abiotically. The preservation of biosignatures over geologic time presents obvious challenges, and the effect of diagenesis on fossils and their mineralogical assemblages deserves attention, especially with respect to the preservation and analysis of materials on (or from) Mars. For this, we need to rely on our Earth analogue sites as a way to triage the wide range of samples that are available for collection and analysis. The preservation of organic materials and cells in salts is particularly interesting. Conversely, the hematite nodules on Mars may not be good samples to target in the search for a Martian biosphere. The possibility of finding an extant biosphere increases with depth; however, evidence from Earth's deep subsurface demonstrates that it does not contain an abundant biosphere. Bacteria thrive in

  12. Bulk mineralogy of the NE Syrtis and Jezero crater regions of Mars derived through thermal infrared spectral analyses

    Science.gov (United States)

    Salvatore, M. R.; Goudge, T. A.; Bramble, M. S.; Edwards, C. S.; Bandfield, J. L.; Amador, E. S.; Mustard, J. F.; Christensen, P. R.

    2018-02-01

    We investigated the area to the northwest of the Isidis impact basin (hereby referred to as "NW Isidis") using thermal infrared emission datasets to characterize and quantify bulk surface mineralogy throughout this region. This area is home to Jezero crater and the watershed associated with its two deltaic deposits in addition to NE Syrtis and the strong and diverse visible/near-infrared spectral signatures observed in well-exposed stratigraphic sections. The spectral signatures throughout this region show a diversity of primary and secondary surface mineralogies, including olivine, pyroxene, smectite clays, sulfates, and carbonates. While previous thermal infrared investigations have sought to characterize individual mineral groups within this region, none have systematically assessed bulk surface mineralogy and related these observations to visible/near-infrared studies. We utilize an iterative spectral unmixing method to statistically evaluate our linear thermal infrared spectral unmixing models to derive surface mineralogy. All relevant primary and secondary phases identified in visible/near-infrared studies are included in the unmixing models and their modeled spectral contributions are discussed in detail. While the stratigraphy and compositional diversity observed in visible/near-infrared spectra are much better exposed and more diverse than most other regions of Mars, our thermal infrared analyses suggest the dominance of basaltic compositions with less observed variability in the amount and diversity of alteration phases. These results help to constrain the mineralogical context of these previously reported visible/near-infrared spectral identifications. The results are also discussed in the context of future in situ investigations, as the NW Isidis region has long been promoted as a region of paleoenvironmental interest on Mars.

  13. Automated quantitative micro-mineralogical characterization for environmental applications

    Science.gov (United States)

    Smith, Kathleen S.; Hoal, K.O.; Walton-Day, Katherine; Stammer, J.G.; Pietersen, K.

    2013-01-01

    Characterization of ore and waste-rock material using automated quantitative micro-mineralogical techniques (e.g., QEMSCAN® and MLA) has the potential to complement traditional acid-base accounting and humidity cell techniques when predicting acid generation and metal release. These characterization techniques, which most commonly are used for metallurgical, mineral-processing, and geometallurgical applications, can be broadly applied throughout the mine-life cycle to include numerous environmental applications. Critical insights into mineral liberation, mineral associations, particle size, particle texture, and mineralogical residence phase(s) of environmentally important elements can be used to anticipate potential environmental challenges. Resources spent on initial characterization result in lower uncertainties of potential environmental impacts and possible cost savings associated with remediation and closure. Examples illustrate mineralogical and textural characterization of fluvial tailings material from the upper Arkansas River in Colorado.

  14. X-ray Spectroscopy and Magnetism in Mineralogy

    Science.gov (United States)

    Sainctavit, Philippe; Brice-Profeta, Sandrine; Gaudry, Emilie; Letard, Isabelle; Arrio, Marie-Anne

    The objective of this paper is to present the kind of information that can be gained in the field of mineralogy from the use of x-ray magnetic spectroscopies. We review some of the questions that are unsettled and that could benefit from an interdisciplinary approach where magnetism, spectroscopy and mineralogy could be mixed. Most of the attention is focused on iron and some other 3d transition elements. The mineralogy of planetary cores and its relation with known meteorites are exemplified. The various oxide phases in the mantle and the nature of iron in these phases is also underlined. The presence of transition elements in insulating minerals and its relation with macroscopic properties such as the color of gemstones are reviewed. Finally an introduction to paleomagnetism is given with a special attention to nanomaghemites.

  15. Mineralogical and geological study of fault rocks and associated strata

    International Nuclear Information System (INIS)

    Kim, Jeon Jin; Jeong, Gyo Cheol; Bae, Doo Won; Park, Seong Min; Kim, Jun Yeong

    2007-01-01

    Mineralogical characterizations of fault clay and associated strata in fault zone with field study and analytical methods. Mineral composition and color of fault clay and rock occur in fracture zone different from bed rocks. Fault clay mainly composed of smectite with minor zeolite such as laumontite and stilbite, and halloysite, illite, Illite and halloysite grow on the surface of smectite, and laumontite and stilbite result from precipitation or alteration of Ca rich bed rock. The result of mineralogical study at Ipsil, Wangsan, Gaegok, Yugyeori, Gacheon in Gyeongju area, the detail research of microstructure in the fault clay making it possible for prediction to age of fault activity

  16. Mineralogical and geological study of fault rocks and associated strata

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jeon Jin; Jeong, Gyo Cheol; Bae, Doo Won; Park, Seong Min; Kim, Jun Yeong [Andong Univ., Andong (Korea, Republic of)

    2007-01-15

    Mineralogical characterizations of fault clay and associated strata in fault zone with field study and analytical methods. Mineral composition and color of fault clay and rock occur in fracture zone different from bed rocks. Fault clay mainly composed of smectite with minor zeolite such as laumontite and stilbite, and halloysite, illite, Illite and halloysite grow on the surface of smectite, and laumontite and stilbite result from precipitation or alteration of Ca rich bed rock. The result of mineralogical study at Ipsil, Wangsan, Gaegok, Yugyeori, Gacheon in Gyeongju area, the detail research of microstructure in the fault clay making it possible for prediction to age of fault activity.

  17. Mineralogy of Rocks and Sediments at Gale Crater, Mars

    Science.gov (United States)

    Achilles, Cherie; Downs, Robert; Blake, David; Vaniman, David; Ming, Doug; Rampe, Elizabeth; Morris, Dick; Morrison, Shaunna; Treiman, Allan; Chipera, Steve; Yen, Albert; Bristow, Thomas; Craig, Patricia; Hazen, Robert; Crisp, Joy; Grotzinger, John; Des Marias, David; Farmer, Jack; Sarrazin, Philippe; Morookian, John Michael

    2017-04-01

    The Mars Science Laboratory rover, Curiosity, is providing in situ mineralogical, geochemical, and sedimentological assessments of rocks and soils in Gale crater. Since landing in 2012, Curiosity has traveled over 15 km, providing analyses of mudstones and sandstones to build a stratigraphic history of the region. The CheMin X-ray diffraction (XRD) instrument is the first instrument on Mars to provide quantitative mineralogical analyses of drilled powders and scooped sediment based on X-ray crystallography. CheMin identifies and determines mineral abundances and unit-cell parameters of major crystalline phases, and identifies minor phases at abundances >1 wt%. In conjunction with elemental analyses, CheMin-derived crystal chemistry allows for the first calculations of crystalline and amorphous material compositions. These mineralogy, crystal chemistry, and amorphous chemistry datasets are playing central roles in the characterization of Gale crater paleoenvironments. CheMin has analyzed 17 rock and sediment samples. In the first phase of the mission, Curiosity explored the sedimentary units of Aeolis Palus (Bradbury group), including two mudstones from Yellowknife Bay. CheMin analyses of the Yellowknife Bay mudstones identified clay minerals among an overall basaltic mineral assemblage. These mineralogical results, along with imaging and geochemical analyses, were used to characterize an ancient lacustrine setting that is thought to have once been a habitable environment. Following the investigations of the Bradbury group, Curiosity arrived at the lower reaches of Aeolis Mons, commonly called Mt. Sharp. A strategic sample campaign was initiated, drilling bedrock at X-ray amorphous phases. Adjacent to fractures, light-toned, halo-like zones are thought to result from significant aqueous alteration of the primary sandstone and show decreased abundances of feldspar and pyroxene, and an increase in the amorphous component, specifically high-silica phases. The Murray

  18. The postglacial Stuoragurra Fault, North Norway - A textural and mineralogical study.

    Science.gov (United States)

    Roaldset, E.

    2012-04-01

    The postglacial Stuoragurra Fault, North Norway - A textural and mineralogical study Elen Roaldset(1), Mari Åm (2), and Oddleiv Olesen(3) 1) Natural History Museum, University of Oslo, P.O.Box 1172 Blindern, 0318 Oslo, Norway 2) Statoil R &D, P. O. Box 2470, 7005 Trondheim, Norway 3) Norwegian Geological Survey, P.O.Box 6315 Sluppen, 7491 Trondheim, Norway The Stuoragurra Fault is part of the Lapland province of postglacial faults and was identified in 1983 during a colloborative project between the Geological Surveys of Finland Norway and Sweden. The Stuoragurra Fault is an 80 km long fault zone which contains three main segments of eastward dipping faults (30-55 deg.) with up to 10 m of reverse displacement and a 7 m high escarpment. It cross-cuts glaciofluvial deposits and consequently being younger than 10.000 years. The postglacial fault segments follow to a large extent older fault zones represented by lithified breccias and diabases of Proterozoic age. In this paper we will present textural and mineralogical study of a 135 m continous core drilled across the fault zone. The investigation methods include quality assessments by rock quality designation methods (RQD and Q- methods), textural and petrological descriptions visually and by thin section microscopy, and mineralogical analysis by X-ray diffraction. Special attention is drawn to neoformed and/or degraded minerals like clay minerals and iron oxides/hydroxides. The quality assessments of the cored material reflect the degree of rock deformation and fragmentation and show the quality of the bedrock generally to be of very poor (about 60%) to poor quality" (25%) The main minerals in the fresh rock are quarts, feldspar, mica and iron oxides (magnetite and ilmenite). Throughout the cored borehole products of weathering have formed on fissures, fractures and in strongly deformed, gravelly, zones. The neoformed minerals include kaolinite, smectite, and vermiculite, as well as goethite. The mineralogical

  19. Methods of stoichiography in geochemistry and mineralogy

    International Nuclear Information System (INIS)

    Malakhov, V.V.; Petrov, L.L.; Vlasov, A.A.; Dovlitova, L.S.

    2003-01-01

    Reported is a novel reference-free technique, based on stoichiography, for the molecular and phase analysis of complex mixtures with unknown compositions. The concept of stoichiography is based on the stoichiometry of mass transfer of the constituents in transient, homogeneous and heterogeneous phase transformation processes. The technique utilizes both the separation of components according to their differential dissolution characteristics as well as the dynamics of the changes in stoichiometry. The detailed study of the dissolution processes has been made possible by the use of a specially designed instrumental system, termed a Stoichiograph, which consists of a high sensitive inductively coupled plasma atomic emission spectrometer as the detector-analyzer. Fundamentals, methodology, and instrumentation of the technique are discussed and its application for the phase analysis of multielement-multiphase samples such as minerals, aerosols, and archaeological materials is demonstrated

  20. Mineralogy and sealing properties of various bentonites and smectite-rich clay materials

    Energy Technology Data Exchange (ETDEWEB)

    Karnland, Ola; Olsson, Siv; Nilsson, Ulf (Clay Technology AB (SE))

    2006-12-15

    The present work includes a coherent study of Wyoming bentonite with respect to the most relevant properties for use in a repository, and a parallel study of other potential buffer and tunnel backfilling materials. The reason for this is twofold; to quantify the effect of mineralogical variations on the various important sealing properties of bentonite, and to verify that there are alternative potential sources of bentonite. The latter is motivated by the fact that Sweden alone plans to deposit at least 6,000 copper canisters which include approximately 130,000 metric tones bentonite buffer material and several times more as tunnel backfill material. Different types of sealing clay materials may also be relevant to use, since the demands on the clay will be different at the various locations in a repository. Alternative sources of bentonite would consequently be valuable in order to secure quality, supply, and price. Important aspects on buffer and tunnel backfilling materials may be summarized as: Original sealing properties. Hazardous substances in any respect. Short-term effects of ground-water chemistry. Long-term stability, i.e. effects of temperature and ground-water chemistry. Availability. Costs. The focus in this study is on the first three items. The long-term stability is indirectly considered in that mineralogical composition is determined. The availability is only considered in such a way that most of the analyzed materials represent huge clay formations, which contain much more material than needed for a repository. The cost aspects have not been included, mainly because the present day price is not relevant due to the time frame of the construction of a repository

  1. Current status of application of Moessbauer effect in geology and mineralogy

    International Nuclear Information System (INIS)

    Xu Binfu

    1995-01-01

    The paper briefly introduces the current status of the application of Moessbauer effect in geology and mineralogy. It shows that geology and mineralogy are very active fields in the application of Moessbauer effect

  2. Mineralogical Results from the Mars Science Laboratory Rover Curiosity

    Science.gov (United States)

    Blake, David Frederick.

    2017-01-01

    NASA's CheMin instrument, the first X-ray Diffractometer flown in space, has been operating on Mars for nearly five years. CheMin was first to establish the quantitative mineralogy of the Mars global soil (1). The instrument was next used to determine the mineralogy of a 3.7 billion year old lacustrine mudstone, a result that, together with findings from other instruments on the MSL Curiosity rover, documented the first habitable environment found on another planet (2). The mineralogy of this mudstone from an ancient playa lake was also used to derive the maximum concentration of CO2 in the early Mars atmosphere, a surprisingly low value that calls into question the current theory that CO2 greenhouse warming was responsible for the warm and wet environment of early Mars. CheMin later identified the mineral tridymite, indicative of silica-rich volcanism, in mudstones of the Murray formation on Mt. Sharp. This discovery challenges the paradigm of Mars as a basaltic planet and ushers in a new chapter of comparative terrestrial planetology (3). CheMin is now being used to systematically sample the sedimentary layers that comprise the lower strata of Mt. Sharp, a 5,000 meter sequence of sedimentary rock laid down in what was once a crater lake, characterizing isochemical sediments that through their changing mineralogy, document the oxidation and drying out of the Mars in early Hesperian time.

  3. Mineralogy and geochemistry of bauxite and bentonite deposits from Mozambique

    NARCIS (Netherlands)

    Dos Muchangos, A.C.

    2000-01-01

    Results of mineralogical and geochemical studies of bauxites, kaolinitic clays and bentoniteS from Mozambique are presented in this thesis. The bauxite and kaolinitic clay deposits in Penhalonga area (in the central western part of Mozambique) are associated with Precambrian magmatic rocks and

  4. Moessbauer mineralogy on the Moon: The lunar regolith

    International Nuclear Information System (INIS)

    Morris, Richard V.; Klingelhoefer, Goestar; Korotev, Randy L.; Shelfer, Tad D.

    1998-01-01

    A first-order requirement for spacecraft missions that land on solid planetary objects is instrumentation for mineralogical analyses. For purposes of providing diagnostic information about naturally-occurring materials, the element iron is particularly important because it is abundant and multivalent. Knowledge of the oxidation state of iron and its distribution among iron-bearing mineralogies tightly constrains the types of materials present and provides information about formation and modification (weathering) processes. Because Moessbauer spectroscopy is sensitive to both the valence of iron and its local chemical environment, the technique is unique in providing information about both the relative abundance of iron-bearing phases and oxidation state of the iron. The Moessbauer mineralogy of lunar regolith samples (primarily soils from the Apollo 16 and 17 missions to the Moon) were measured in the laboratory to demonstrate the strength of the technique for in-situ mineralogical exploration of the Moon. The regolith samples were modeled as mixtures of five iron-bearing phases: olivine, pyroxene, glass, ilmenite, and metal. Based on differences in relative proportions of iron associated with these phases, volcanic-ash regolith can be distinguished from impact-derived regolith, impact-derived soils of different geologic affinity (e.g., highlands and maria) can be distinguished on the basis of their constituent minerals, and soil maturity can be estimated. The total resonant absorption area of the Moessbauer spectrum can be used to estimate total FeO concentrations

  5. Mineralogy and geochemistry of density-separated Greek lignite fractions

    NARCIS (Netherlands)

    Iordanidis, A.; Doesburg, van J.D.J.

    2006-01-01

    In this study, lignite samples were collected from the Ptolemais region, northern Greece, homogenized, crushed to less than I nun, and separated in three density fractions using heavy media. The mineralogical investigation of the density fractions showed a predominance of pyrite in the light

  6. Mineralogy of Tailings Dump around Selebi Phikwe Nickel-Copper ...

    African Journals Online (AJOL)

    This study aimed at mineralogically characterizing the tailings dump emanating from the mining and smelting of nickel-copper (Ni-Cu) at Selebi Phikwe, Botswana, Southern Africa. Samples of tailings dump around the Selebi Phikwe Ni-Cu plant were studied using petrographic microscopy and X-ray Powder Diffraction ...

  7. Mineralogical and geochemical studies of phosphorite nodules in ...

    African Journals Online (AJOL)

    Mineralogical and geochemical studies of phosphorite nodules in the Dange Formation Sokoto Basin, Northwestern Niveria. OA Adekeye, SO Akande. Abstract. No Abstract Available Journal of Mining and Geology Vol.40(2) 2004: 101-106. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT ...

  8. Mineralogy and pedogenesis in a soil chronosequence on a ...

    African Journals Online (AJOL)

    Studies on soils of the floodplain of lower Niger river are scanty although this floodplain forms a very important agricultural resource base in Nigeria. The objective of this study is to provide comprehensive information on the characteristics of the soils with respect to their mineralogy and the effect of seasonal flooding on their ...

  9. Clay mineralogy of the mud banks of Cochin

    Digital Repository Service at National Institute of Oceanography (India)

    Nair, R.R.; Murty, P.S.N.

    The mineralogy of the sediments constituting the mud banks formed off Cochin, Kerala, India was studied. The clay mineral composition was used as a means of understanding the nature and source of origin of the muds. Fine fraction of the mud samples...

  10. Mineralogy and trace element chemistry of the Siliceous Earth of ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    We report the presence of a 3–5 cm thick loose fragmental layer in the Siliceous Earth at Matti ka. Gol in the Barmer basin of Rajasthan. Petrographic, chemical and mineralogical study reveals the presence of abundant volcanic debris such as glass shards, agglutinates, hollow spheroids, kinked biotites, feldspars showing ...

  11. Physico-chemical and Mineralogical Characterisation of Subsurface ...

    African Journals Online (AJOL)

    Studies were carried out on subsurface sediments obtained around the Gaborone landfill area Botswana, in order to characterize their mineralogy and physico-chemistry, appraise any contaminant inputs from the landfill and assess their ability to attenuate contaminants from the landfill. Physico-chemical properties ...

  12. Characterization of North American lignite fly ashes. II. XRD Mineralogy

    International Nuclear Information System (INIS)

    McCarthy, G.J.; Johansen, D.M.; Thedchanamoorthy, A.; Steinwand, S.J.; Swanson, K.D.

    1988-01-01

    X-ray powder diffraction has been used to determine the crystalline phase mineralogy in samples of fly ash from each of the lignite mining areas of North America. The characteristic phases of North Dakota lignite fly ashes were periclase, lime, merwinite and the sulfate phases anhydrite, thenardite and a sodalite-structure phase. Mullite was absent in these low-Al/sub 2/O/sub 3/ ashes. Montana lignite ash mineralogy had characteristics of ND lignite and MT subbituminous coal fly ashes; mullite and C/sub 3/A were present and the alkali sulfates were absent. Texas and Louisiana lignite fly ashes had the characteristic mineralogy of bituminous coal fly ash: quartz, mullite, ferrite-spinel (magnetite) and minor hematite. Even though their analytical CaO contents were 7-14%, all but one lacked crystalline CaO-containing phases. Lignite fly ashes from Saskatchewan were generally the least crystalline of those studied and had a mineralogy consisting of quartz, mullite, ferrite spinel and periclase. Quantitative XRD data were obtained. The position of the diffuse scattering maximum in the x-ray diffractograms was indicative of the glass composition of the lignite fly ash

  13. Impact of chemical oxidation and water acidification on the mineralogical and physico-chemical properties of the Tournemire argillaceous formation

    International Nuclear Information System (INIS)

    Charpentier, D.

    2001-11-01

    The French Institute for Protection and Nuclear Safety (IPSN) has selected a site near Tournemire (France) for research programmes on deep geological waste disposal in clay-rich rock formation. A railway tunnel was built about 100 years ago through the thick indurated Toarcian argillite of the Tournemire Massif and two galleries were constructed five years ago. They are used to study the evolution of rock mineralogical composition, texture, water content and water-rock interactions in the excavated disturbed zone. Multi-scale and multi-technique investigations were carried out on the evolution of physical and mineralogical rock properties. Experiments and numerical modelling were used to predict changes due to water-rock interactions and subsequent rock mineralogy and water chemistry modifications. The argillite consists of detrital clay-rich layers and carbonate layers. Pyrites are always present in significant amounts (2 to 2.5 %). The rock presents very low porosity and very low water content (around 3 %). Leaching experiments show that the interstitial water is Na and SO 4 -rich and Cl-poor. The tunnel and galleries digging induces fracture formation. In the altered samples, the clay particles show a better orientation in the stratification plan, which increases the porosity. The oxidation effect yields to mineralogical transformation on the surfaces of the argillite: oxidation of pyrite, dissolution of calcite, dissolution of illite layers in interstratified I/S and formation of gypsum, Fe-oxi/hydroxides, celestite and jarosite. During cycles of hydration/dehydration, condensation water interacts with the argillite and quickly becomes Ca and SO 4 -rich. The local dissolution of clay particles leads to an increase of the chloride and potassium water content. These phenomena are important for the consideration of the underground work stability, especially the evolution of the water-rock equilibria during the re-hydration of the excavated disturbed zones. (author)

  14. Teaching Mineralogy, Petrology and Geochemistry in the 21st Century: Instructional Resources for Geoscience Faculty

    Science.gov (United States)

    Mogk, D. W.; Beane, R. J.; Whitney, D. L.; Nicolaysen, K. E.; Panero, W. R.; Peck, W. H.

    2011-12-01

    Mineralogy, petrology and geochemistry (MPG) are pillars of the geoscience curriculum because of their relevance in interpreting Earth history and processes, application to geo-hazards, resources, and environmental issues, and contributions to emerging fields such as geology and human health. To keep faculty current in scientific advances in these fields, and in modern instructional methods, the On the Cutting Edge program convened a workshop at the University of Minnesota in August, 2011. This workshop builds on the previous 15 year's work that has been focused on identifying, aggregating, and developing high-quality collections of teaching activities and related resources, and in building a community of scholars in support of excellence in instruction in MPG courses. The goals of the workshop were to: a) develop an integrated, comprehensive and reviewed curriculum for MPG courses, and to seek ways to make connections with the larger geoscience curriculum; b) to explore emerging topics in MPG such as geobiology and climate change; c) demonstrate effective methods in teaching MPG in the context of Earth system science; d) share effective teaching activities and strategies for the classroom, laboratory and field including advances in pedagogy, assessments and research on learning; e) keep faculty current on recent advances in mineralogy, petrology and geochemistry research and to apply these findings to our teaching; f) explore and utilize current societal and global issues that intersect mineralogy, petrology and geochemistry to heighten the relevancy of course content for students; and h) meet colleagues and foster future teaching and research collaborations. A significant outcome of this workshop is a peer reviewed of collection of 300+ existing teaching activities, and a gap analysis to identify teaching activities needed to make these collections comprehensive and coherent. In addition, a series of thematic collections were developed to assist high priority

  15. Astrobiological Significance of Definitive Mineralogical Analysis of Martian Surface Samples Using the CheMin XRD/XRF Instrument

    Science.gov (United States)

    Feldman, S. M.; Blake, D. F.; Sarrazin, P.; Bish, D. L.; Chipera, S. J.; Vaniman, D. T.; Collins, S.

    2004-01-01

    The search for evidence of habitability, or of extant or extinct life on Mars, will initially be a search for evidence of past or present conditions supportive of life. The three key requirements for the emergence of life are thought to be liquid water; a suitable energy source; and chemical building blocks. CheMin is a miniaturized XRD/XRF (X-Ray diffraction / X-ray fluorescence) instrument which has been developed for definitive mineralogic analysis of soils and rocks on the Martian surface. The CheMin instrument can provide information that is highly relevant to each of these habitability requirements as summarized below.

  16. Why relevance theory is relevant for lexicography

    DEFF Research Database (Denmark)

    Bothma, Theo; Tarp, Sven

    2014-01-01

    This article starts by providing a brief summary of relevance theory in information science in relation to the function theory of lexicography, explaining the different types of relevance, viz. objective system relevance and the subjective types of relevance, i.e. topical, cognitive, situational...... that is very important for lexicography as well as for information science, viz. functional relevance. Since all lexicographic work is ultimately aimed at satisfying users’ information needs, the article then discusses why the lexicographer should take note of all these types of relevance when planning a new...... dictionary project, identifying new tasks and responsibilities of the modern lexicographer. The article furthermore discusses how relevance theory impacts on teaching dictionary culture and reference skills. By integrating insights from lexicography and information science, the article contributes to new...

  17. Mineralogy of the Martian Surface: Crustal Composition to Surface Processes

    Science.gov (United States)

    Mustard, John F.

    1999-01-01

    Over the course of this award we have: 1) Completed and published the results of a study of the effects of hyperfine particles on reflectance spectra of olivine and quartz, which included the development of scattering codes. Research has also progressed in the analysis of the effects of fine particle sizes on clay spectra. 2) Completed the analysis of the mineralogy of dark regions, showed the insitu compositions are highly correlated to the SNC meteorites, and determined that the martian mantle was depleted in aluminum prior to 2-3 GA ago; Studies of the mineralogic heterogeneity of surficial materials on Mars have also been conducted. and 3) Performed initial work on the study of the physical and chemical processes likely to form and modify duricrust. This includes assessments of erosion rates, solubility and transport of iron in soil environments, and models of pedogenic crust formation.

  18. Fracture mineralogy of the Forsmark site. SDM-Site Forsmark

    Energy Technology Data Exchange (ETDEWEB)

    Sandstroem, Bjoern (Dept. of Earth Sciences, Univ. of Goeteborg (Sweden)); Tullborg, Eva-Lena (Terralogica AB, Graabo (Sweden)); Smellie, John (Conterra AB, Luleaa (Sweden)); MacKenzie, Angus B. (SUERC, Scottish Enterprise Technology Park, East Kilbride (United Kingdom)); Suksi, Juhani (Dept. of Chemistry, Univ. of Helsinki, Helsinki (Finland))

    2008-08-15

    Detailed investigations of the fracture mineralogy and altered wall rock have been carried out as part of the site characterisation programme between 2003 and 2007 at Forsmark. The results have been published in a number of P-reports and in contributions to scientific journals. This report summarises and evaluates the data obtained during the detailed fracture mineralogical studies. The report includes descriptions of the identified fracture minerals and their chemical composition. A sequence of fracture mineralisations has been distinguished and provides information of the low to moderate temperature (brittle) geological and hydrogeological evolution at the site. Special focus has been paid to the chemical and stable isotopic composition of calcite to obtain palaeohydrogeological information. Chemical analyses of bulk fracture filling material have been carried out to identify possible sinks for certain elements and also to reveal the presence of minor phases rich in certain elements which have not been possible to detect by X-ray diffraction (XRD). Statistical analysis of the mineralogy in fractures outside deformation zones (i.e. within fracture domains FFM01, FFM02, FFM03 and FFM06) have been carried out concerning variation of fracture mineral distribution at depth and in different fracture domains. Uranium contents and uranium-series isotopes have been analysed on fracture coating material from hydraulically conductive fractures. Such analyses are also available from the groundwaters and the results are combined in order to reveal recent (< 1 Ma) removal/deposition of uranium in the fracture system. The redox conditions in the fracture system have been evaluated based on mineralogical and chemical indicators as well as Moessbauer analyses

  19. Clay Mineralogy of Brazilian Oxisols with Shrinkage Properties

    Directory of Open Access Journals (Sweden)

    Samara Alves Testoni

    2017-08-01

    Full Text Available ABSTRACT Shrinkage capacity (caráter retrátil in Portuguese is a new diagnostic characteristic recently introduced in the Brazilian System of Soil Classification (SiBCS to indicate shrink and swell properties observed in subtropical soils from highland plateaus in southern Brazil, specifically in Oxisols with brown colors. In soils located in road cuts exposed to drying for some weeks, strong shrinkage of soil volume is observed in these soils, resulting in the formation of pronounced vertical cracks and large and very large prismatic structures, which crumble in blocks when handled. We hypothesize that such properties are related to their clay mineralogy, although there are no conclusive studies about this, the motive for the present study. Samples of the A and B horizons from six Oxisols with expansive capacity from the states of Santa Catarina and Rio Grande do Sul were analyzed. One Rhodic Hapludox, from the state of Paraná, without expansive capacity, was used for comparison. All the soils are very clayey, originated from basalt, and have similar iron oxide content. For identification of clay mineralogy, X-ray diffraction techniques were employed, together with the use of NEWMOD® software to investigate and describe the interstratified minerals. The results showed that most expansive soils have a similar mineralogical composition, with kaolinite, interstratified kaolinite-smectite (K-S, and hydroxy-Al interlayered smectites (HIS, unlike the non-expansive Rhodic Hapludox, which exhibited kaolinite with significant amounts of gibbsite and low amount of interstratified K-S. According to the mineralogical assemblage identified in the expansive soils, we can affirm that the mechanism of smectite expansion and contraction is related to the shrinkage capacity of the soil, considering that the level of hydroxy-Al intercalation is low. In addition, these mechanisms also are related to the presence of quasicrystals and domains that control the

  20. Mineralogy affects geoavailability, bioaccessibility and bioavailability of zinc

    International Nuclear Information System (INIS)

    Molina, Ramon M.; Schaider, Laurel A.; Donaghey, Thomas C.; Shine, James P.; Brain, Joseph D.

    2013-01-01

    We correlated mineralogical and particle characteristics of Zn-containing particles with Zn geoavailability, bioaccessibility, and bioavailability following gavage and intranasal (IN) administration in rats. We compared samples of Zn/Pb mine waste and five pulverized pure-phase Zn minerals ( 65 Zn. We assessed geoavailability using sequential extractions and bioaccessibility using in vitro extraction tests simulating various pH and biological conditions. Zn in vivo bioavailability and in vitro bioaccessibility decreased as follows: mine waste > hydrozincite > hemimorphite > zincite ≈ smithsonite >> sphalerite. We found significant correlations among geoavailability, bioaccessibility and bioavailability. In particular, Zn bioavailability post-gavage and post-IN was significantly correlated with bioaccessibility in simulated phagolysosomal fluid and gastric fluid. These data indicate that solid phase speciation influences biological uptake of Zn and that in vitro tests can be used to predict Zn bioavailability in exposure assessment and effective remediation design. Highlights: •Zinc particle mineralogy influences bioaccessibility and bioavailability. •Zn bioavailability via gavage was 1.2–1.6 times higher than via intranasal route. •Zn particle geoavailability correlates with bioaccessibility. •In vitro bioaccessibility tests can predict in vivo Zn bioavailability. •Metal speciation and geochemical alterations can impact Zn bioavailability. -- Zinc mineralogy influences in vitro bioaccessibility and in vivo bioavailability and in vitro extraction tests can be used to predict Zn bioavailability from particles

  1. Mineralogical and geological study of quaternary deposits and weathering profiles

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Gi Young; Lee, Bong Ho [Andong National Univ., Andong (Korea, Republic of)

    2004-01-15

    Movement history of a quaternary reverse fault cutting marine terrace deposit and tertiary bentonite in the Yangnammyon, Gyoungju city was studied by the mineralogical and microtextural analysis of the fault clays and weathered terrace deposits. Two types of fault clays were identified as greenish gray before the deposition of the marine terrace deposits and reddish brown after deposition. Greenish gray fault clay is composed mostly of smectite probably powdered from bentonite showing at least two events of movement from microtextures. After the bentonite was covered by quaternary marine gravel deposits, the reverse fault was reactivated cutting marine gravel deposits to form open spaces along the fault plane which allowed the hydrological infiltration of soil particles and deposition of clays in deep subsurface. The reddish brown 'fault' clays enclosed the fragments of dark brown ultrafine varved clay, proving two events of faulting, and slicken sides bisecting reddish brown clays suggest another faulting event in the final stage. Mineralogical and microtextural analysis of the fault clay show total five events of faulting, which had not been recognized even by thorough conventional paleoseismological investigation using trench, highlighting the importance of microtextural and mineralogical analysis in paleoseismology.

  2. Martian Surface Mineralogy from Rovers with Spirit, Opportunity, and Curiosity

    Science.gov (United States)

    Morris, Richard V.

    2016-01-01

    Beginning in 2004, NASA has landed three well-instrumented rovers on the equatorial martian surface. The Spirit rover landed in Gusev crater in early January, 2004, and the Opportunity rover landed on the opposite side of Mars at Meridian Planum 21 days later. The Curiosity rover landed in Gale crater to the west of Gusev crater in August, 2012. Both Opportunity and Curiosity are currently operational. The twin rovers Spirit and Opportunity carried Mossbauer spectrometers to determine the oxidation state of iron and its mineralogical composition. The Curiosity rover has an X-ray diffraction instrument for identification and quantification of crystalline materials including clay minerals. Instrument suites on all three rovers are capable of distinguishing primary rock-forming minerals like olivine, pyroxene and magnetite and products of aqueous alteration in including amorphous iron oxides, hematite, goethite, sulfates, and clay minerals. The oxidation state of iron ranges from that typical for unweathered rocks and soils to nearly completely oxidized (weathered) rocks and soils as products of aqueous and acid-sulfate alteration. The in situ rover mineralogy also serves as ground-truth for orbital observations, and orbital mineralogical inferences are used for evaluating and planning rover exploration.

  3. Arsenic mineralogy and mobility in the arsenic-rich historical mine waste dump

    International Nuclear Information System (INIS)

    Filippi, Michal; Drahota, Petr; Machovič, Vladimír; Böhmová, Vlasta; Mihaljevič, Martin

    2015-01-01

    A more than 250 year-old mine dump was studied to document the products of long-term arsenopyrite oxidation under natural conditions in a coarse-grained mine waste dump and to evaluate the environmental hazards associated with this material. Using complementary mineralogical and chemical approaches (SEM/EDS/WDS, XRD, micro-Raman spectroscopy, pore water analysis, chemical extraction techniques and thermodynamic PHREEQC-2 modeling), we documented the mineralogical/geochemical characteristics of the dumped arsenopyrite-rich material and environmental stability of the newly formed secondary minerals. A distinct mineralogical zonation was found (listed based on the distance from the decomposed arsenopyrite): scorodite (locally associated with native sulfur pseudomorphs) plus amorphous ferric arsenate (AFA/pitticite), kaňkite, As-bearing ferric (hydr)oxides and jarosite. Ferric arsenates and ferric (hydr)oxides were found to dissolve and again precipitate from downward migrating As-rich solutions cementing rock fragments. Acidic pore water (pH 3.8) has elevated concentrations of As with an average value of about 2.9 mg L −1 . Aqueous As is highly correlated with pH (R 2 = 0.97, p < 0.001) indicating that incongruent dissolution of ferric arsenates controls dissolved As well as the pH of the percolating waste solution. Arsenic released from the dissolution of ferric arsenates into the pore water is, however, trapped by latter and lower-down precipitating jarosite and especially ferric (hydr)oxides. The efficiency of As sequestration by ferric (hydr)oxides in the waste dump and underlying soil has been found to be very effective, suggesting limited environmental impact of the mine waste dump on the surrounding soil ecosystems. - Highlights: • More than 250 year-old arsenopyrite-rich mine waste dump was studied. • Mineral transformation and the environmental stability of different secondary arsenic mineral phases were assessed. • High efficiency of As

  4. Transformative Learning

    Science.gov (United States)

    Wang, Victor C. X.; Cranton, Patricia

    2011-01-01

    The theory of transformative learning has been explored by different theorists and scholars. However, few scholars have made an attempt to make a comparison between transformative learning and Confucianism or between transformative learning and andragogy. The authors of this article address these comparisons to develop new and different insights…

  5. An unpublished text of Jovellanos about mineralogy Notas inéditas de Jovellanos sobre mineralogía

    Directory of Open Access Journals (Sweden)

    Jorge ORDAZ GARGALLO

    2012-01-01

    Full Text Available An unpublished manuscript of Gaspar Melchor de Jovellanos about the history of mineralogy, written during his captivity in Bellver Castle (Palma de Mallorca is presented and analyzed. In this writing the importance of the chemical knowledge as a source of other branches of science and its applications in different fields of agriculture, mining and industry is considered. The author made a historical synthesis reviewing the men of science that contributed in a great extent to the advance of the chemistry and mineralogy. The text clearly supports the new contributions of Lavoisier and other supporters of experimentation as a scientific method, which agrees with Jovellanos’ ideas about the development of the «useful» sciences for the progress of the countries.Se presenta y analiza un manuscrito inédito de Gaspar Melchor de Jovellanos sobre la historia de la mineralogía, que redactó durante su cautiverio en el Castillo de Bellver (Palma de Mallorca. En el escrito considera de gran importancia los conocimientos químicos como fuente de otras ramas del saber científico y sus aplicaciones en distintos ámbitos de la agricultura, minería e industria. El autor hace una síntesis histórica repasando los hombres de ciencia que en mayor medida contribuyeron al avance de la química y la mineralogía. El texto apoya claramente las nuevas aportaciones de Lavoisier y otros químicos partidarios de la experimentación como método científico, y es acorde con las ideas de Jovellanos acerca del cultivo de las ciencias «útiles» para el progreso de los pueblos.

  6. Deep learning relevance

    DEFF Research Database (Denmark)

    Lioma, Christina; Larsen, Birger; Petersen, Casper

    2016-01-01

    train a Recurrent Neural Network (RNN) on existing relevant information to that query. We then use the RNN to "deep learn" a single, synthetic, and we assume, relevant document for that query. We design a crowdsourcing experiment to assess how relevant the "deep learned" document is, compared...... to existing relevant documents. Users are shown a query and four wordclouds (of three existing relevant documents and our deep learned synthetic document). The synthetic document is ranked on average most relevant of all....

  7. Backlund transformations as canonical transformations

    International Nuclear Information System (INIS)

    Villani, A.; Zimerman, A.H.

    1977-01-01

    Toda and Wadati as well as Kodama and Wadati have shown that the Backlund transformations, for the exponential lattice equation, sine-Gordon equation, K-dV (Korteweg de Vries) equation and modifies K-dV equation, are canonical transformation. It is shown that the Backlund transformation for the Boussinesq equation, for a generalized K-dV equation, for a model equation for shallow water waves and for the nonlinear Schroedinger equation are also canonical transformations [pt

  8. Study of the mineralogical transformations of granite by underground nuclear explosions

    International Nuclear Information System (INIS)

    Faure, Jean

    1970-01-01

    The object of the following communication is to prove new data about the petrographic effects of the underground nuclear explosions. It is founded on the results of trench tests in granite rock. The samples are collected by drilling and the temperature of the rock was measured in the hole. Four types of melted rocks can be sorted, grey-green glass and pumices, beige to red-brown pumices, dark lavas, dark veinlets and crushed granite. The distribution of these rocks is studied. Optical microscopy, X-rays and chemical analysis, study by electron probe, are made. The results complete previously published data. They are interesting as far as the use of nuclear explosions for industrial applications is concerned. (author)

  9. Study of the mineralogical transformations of granite by underground nuclear explosions

    Energy Technology Data Exchange (ETDEWEB)

    Faure, Jean [Commissariat a I' Energie Atomique, Centre d' Etudes de Bruyeres-le-Chatel (France)

    1970-05-15

    The object of the following communication is to prove new data about the petrographic effects of the underground nuclear explosions. It is founded on the results of trench tests in granite rock. The samples are collected by drilling and the temperature of the rock was measured in the hole. Four types of melted rocks can be sorted, grey-green glass and pumices, beige to red-brown pumices, dark lavas, dark veinlets and crushed granite. The distribution of these rocks is studied. Optical microscopy, X-rays and chemical analysis, study by electron probe, are made. The results complete previously published data. They are interesting as far as the use of nuclear explosions for industrial applications is concerned. (author)

  10. Fundamentals of algebraic graph transformation

    CERN Document Server

    Ehrig, Hartmut; Prange, Ulrike; Taentzer, Gabriele

    2006-01-01

    Graphs are widely used to represent structural information in the form of objects and connections between them. Graph transformation is the rule-based manipulation of graphs, an increasingly important concept in computer science and related fields. This is the first textbook treatment of the algebraic approach to graph transformation, based on algebraic structures and category theory. Part I is an introduction to the classical case of graph and typed graph transformation. In Part II basic and advanced results are first shown for an abstract form of replacement systems, so-called adhesive high-level replacement systems based on category theory, and are then instantiated to several forms of graph and Petri net transformation systems. Part III develops typed attributed graph transformation, a technique of key relevance in the modeling of visual languages and in model transformation. Part IV contains a practical case study on model transformation and a presentation of the AGG (attributed graph grammar) tool envir...

  11. Hadamard Transforms

    CERN Document Server

    Agaian, Sos; Egiazarian, Karen; Astola, Jaakko

    2011-01-01

    The Hadamard matrix and Hadamard transform are fundamental problem-solving tools in a wide spectrum of scientific disciplines and technologies, such as communication systems, signal and image processing (signal representation, coding, filtering, recognition, and watermarking), digital logic (Boolean function analysis and synthesis), and fault-tolerant system design. Hadamard Transforms intends to bring together different topics concerning current developments in Hadamard matrices, transforms, and their applications. Each chapter begins with the basics of the theory, progresses to more advanced

  12. Automated mineralogy and petrology - applications of TESCAN Integrated Mineral Analyzer (TIMA)

    Czech Academy of Sciences Publication Activity Database

    Hrstka, Tomáš; Gottlieb, P.; Skála, Roman; Breiter, Karel; Motl, D.

    2018-01-01

    Roč. 63, č. 1 (2018), s. 47-63 ISSN 1802-6222 Grant - others:AV ČR(CZ) StrategieAV21/4 Program:StrategieAV Institutional support: RVO:67985831 Keywords : TIMA * Automated SEM/EDS * applied mineralogy * modal analysis * artificial intelligence * neural networks Subject RIV: DB - Geology ; Mineralogy OBOR OECD: Mineralogy Impact factor: 0.609, year: 2016

  13. Influence of clay mineralogy on clay based ceramic products

    International Nuclear Information System (INIS)

    Radzali Othman; Tuan Besar Tuan Sarif; Zainal Arifin Ahmad; Ahmad Fauzi Mohd Noor; Abu Bakar Aramjat

    1996-01-01

    Clay-based ceramic products can either be produced directly from a suitable clay source without the need further addition or such products can be produced from a ceramic body formulated by additions of other raw materials such as feldspar and silica sand. In either case, the mineralogical make-up of the clay component plays a dominating role in the fabrication and properties of the ceramic product. This study was sparked off by a peculiar result observed in one of five local ball clay samples that were used to reformulate a ceramic body. Initial characterisation tests conducted on the clays indicated that these clays can be classified as kaolinitic. However, one of these clays produced a ceramic body that is distinctively different in terms of whiteness, smoothness and density as compared to the other four clays. Careful re-examination of other characterisation data, such as particle size distribution and chemical analysis, failed to offer any plausible explanation. Consequently, the mineralogical analysis by x-ray diffraction was repeated by paying meticulous attention to specimen preparation. Diffraction data for the clay with anomalous behaviour indicated the presence of a ∼ 10A peak that diminished when the same specimen was re-tested after heating in an oven at 12O degree C whilst the other four clays only exhibit the characteristic kaolinite (Al sub 2 O sub 3. 2SiO sub 2. 2H sub 2 0) and muscovite peaks at ∼ 7A and ∼ 10A before and after heat treatment. This suggests the presence of the mineral halloysite (A1 sub 2 0 sub 3. 2SiO sub 2.4H sub 2 0) in that particular clay. This difference in mineralogy can be attributed to account for the variations in physical properties of the final product. Consequently, this paper reviews in general the precautionary measures that must be adhered to during any mineralogical investigation of clay minerals or clay-based materials. The common pitfalls during specimen preparation, machine settings and interpretation of

  14. Temperature buffer test. Hydro-mechanical and chemical/ mineralogical characterizations

    International Nuclear Information System (INIS)

    Aakesson, Mattias; Olsson, Siv; Dueck, Ann; Nilsson, Ulf; Karnland, Ola; Kiviranta, Leena; Kumpulainen, Sirpa; Linden, Johan

    2012-01-01

    The Temperature Buffer Test (TBT) is a joint project between SKB/ANDRA and supported by ENRESA (modeling) and DBE (instrumentation), which aims at improving the understanding and to model the thermo-hydro-mechanical behavior of buffers made of swelling clay submitted to high temperatures (over 100 deg C) during the water saturation process. The test has been carried out in a KBS-3 deposition hole at Aspo HRL. It was installed during the spring of 2003. Two steel heaters (3 m long, 0.6 m diameter) and two buffer arrangements have been investigated: the lower heater was surrounded by rings of compacted Wyoming bentonite only, whereas the upper heater was surrounded by a composite barrier, with a sand shield between the heater and the bentonite. The test was dismantled and sampled during the winter of 2009/2010. This report presents the hydro-mechanical and chemical/mineralogical characterization program which was launched subsequent to the dismantling operation. The main goal has been to investigate if any significant differences could be observed between material from the field experiment and the reference material. The field samples were mainly taken from Ring 4 (located at the mid-section around the lower heater), in which the temperature in the innermost part reached 155 deg C. The following hydro-mechanical properties have been determined for the material (test technique within brackets): hydraulic conductivity (swelling pressure device), swelling pressure (swelling pressure device), unconfined compression strength (mechanical press), shear strength (triaxial cell) and retention properties (jar method). The following chemical/mineralogical properties (methods within brackets) were determined: anion analysis of water leachates (IC), chemical composition (ICP/AES+MS, EGA), cation exchange capacity (CEC, Cu-trien method) and exchangeable cations (exchange with NH4, ICPAES), mineralogical composition (XRD and FTIR), element distribution and microstructure (SEM and

  15. Application of Moessbauer spectrum to geological and mineralogical problems

    International Nuclear Information System (INIS)

    Korovushkin, V.V.

    1985-01-01

    Main parameters of γ-resonance spectra (resonance effect value, chemical isomer shift, quadrupole splitting, nuclear Zeeman splitting) are considered. Methods of the sample preparation and technique for geological sample analysis using nuclear gamma-resonance (NGR) spectroscopy are described in brief. Possibility of direct application of the above method to determine the iron valence in minerals, their diagnosis and determination of quantitative distribution of iron between the mineral forms in rocks in the process of uranium ore formation and destruction, are discussed. Prospects for NGR-spectroscopy application to geology and mineralogy are pointed out

  16. Petrology, mineralogy and geochemistry of surficial uranium deposits

    International Nuclear Information System (INIS)

    Pagel, M.

    1984-01-01

    A comprehensive understanding of the petrology, mineralogy, and geochemistry of surficial uranium ore deposits is important for developing prospecting and evaluation strategies. Carnotite is the main uranium mineral and is found in those deposits that have the greatest potential uranium resources. The following uranium-bearing minerals have been reported to occur in surficial deposits: carnotite, tyuyamunite, soddyite, weeksite, haiweeite, uranophane, betauranophane, metaankoleite, torbernite, autunite, phosphuranylite, schroeckingerite, Pb-V-U hydroxide (unnamed mineral), uraninite and organourano complexes. The interrelationships between some of the minerals of the host rocks (especially the clays) are not well understood. (author)

  17. Clay Mineralogy of Soils on Quaternary Sediment in Northeast of Urmia

    Directory of Open Access Journals (Sweden)

    Parisa Farzamnia

    2017-03-01

    10.83 °C respectively and the soil moisture and temperature regimes are dry xeric and mesic respectively. In this study, eight soil profiles in quaternary sediments were dug and sampled and the morphological, physical, chemical and mineralogical properties were determined using standard methods. Results and Discussion: According to the results, Illite, smectite, Kaolinite, chlorite, vermiculite and hydroxy interlayer vermiculite (HIV were the dominant clay minerals in these soils. The origin of illite, chlorite and kaolinite were related to inheritance from parent material. Regarding to the present of some smectite in the parent material of these soils, some of smectites have been inherited from parent material. Nevertheless it seems that, the most of smectites in these soils have pedogenic origin. Based on mineralogical results and trends variation of smectite and illite along studied profiles, we concluded that some of smectites in these soils have been formed from illite transformation. In profiles 4 and 6, regarding to low depth water table and consequently poor drainage, high pH and high values of calcium and magnesium cations, provide suitable conditions for the neoformation of smectit and so, some of smectites have been formed via neoformation from soil solution. In these soils, vermiculites were pedogenic and have been formed during transformation of illite to smectite. Small amounts of hydroxy interlayer vermiculites were present in buried horizons and regarding that they were not present in parent material, it might be because these minerals are pedogenic and have been formed in a past wetter climate. The transformation of illite to smectite in lower horizons needs high moisture and regarding to recent semiarid climate of study area, the suitable amount of moisture for this transformation, especially in lower depths and also in buried horizons, is not present. Thus, it seems the transformation of illite to smectite in lower depths and buried horizons has

  18. Visualizing Transformation

    DEFF Research Database (Denmark)

    Pedersen, Pia

    2012-01-01

    Transformation, defined as the step of extracting, arranging and simplifying data into visual form (M. Neurath, 1974), was developed in connection with ISOTYPE (International System Of TYpographic Picture Education) and might well be the most important legacy of Isotype to the field of graphic...... design. Recently transformation has attracted renewed interest because of the book The Transformer written by Robin Kinross and Marie Neurath. My on-going research project, summarized in this paper, identifies and depicts the essential principles of data visualization underlying the process...... of transformation with reference to Marie Neurath’s sketches on the Bilston Project. The material has been collected at the Otto and Marie Neurath Collection housed at the University of Reading, UK. By using data visualization as a research method to look directly into the process of transformation, the project...

  19. Thermodynamic modeling of mineralogical phases formed by continuous casting powders

    International Nuclear Information System (INIS)

    Romo-Castaneda, Julio; Cruz-Ramirez, Alejandro; Romero-Serrano, Antonio; Vargas-Ramirez, Marissa; Hallen-Lopez, Manuel

    2011-01-01

    A great amount of mineralogical phases were predicted and represented in stability phase diagrams, which were obtained by the use of the thermodynamic software FACTSage considering both the chemical composition and the melting temperature of the mould flux. Melting-solidification tests on commercial mould flux glasses for thin slab casting of steel revealed the existence of cuspidine (Ca 4 Si 2 O 7 F 2 ) as the main mineralogical phase formed during the flux solidification by X-ray powder diffraction (XRD). This phase directly influences the heat transfer phenomena from the strand to the mould and it is obtained with higher fluorite content (22% CaF 2 ). Cuspidine is desirable only in fluxes to produce medium carbon (included peritectic grade) steels, because it reduces the heat flux from the strand to the mould, thus controlling the shrinkage rate during the flux solidification. The experimental results are in agreement with those obtained by the thermodynamic software. The stability phase diagrams could be used as an important tool in the flux design for continuous casting process.

  20. Thermodynamic modeling of mineralogical phases formed by continuous casting powders

    Energy Technology Data Exchange (ETDEWEB)

    Romo-Castaneda, Julio [Metallurgy and Materials Department, Instituto Politecnico Nacional-ESIQIE, Apdo. P. 118-431, 07051 Mexico D.F. (Mexico); Cruz-Ramirez, Alejandro, E-mail: alcruzr@ipn.mx [Metallurgy and Materials Department, Instituto Politecnico Nacional-ESIQIE, Apdo. P. 118-431, 07051 Mexico D.F. (Mexico); Romero-Serrano, Antonio; Vargas-Ramirez, Marissa; Hallen-Lopez, Manuel [Metallurgy and Materials Department, Instituto Politecnico Nacional-ESIQIE, Apdo. P. 118-431, 07051 Mexico D.F. (Mexico)

    2011-01-10

    A great amount of mineralogical phases were predicted and represented in stability phase diagrams, which were obtained by the use of the thermodynamic software FACTSage considering both the chemical composition and the melting temperature of the mould flux. Melting-solidification tests on commercial mould flux glasses for thin slab casting of steel revealed the existence of cuspidine (Ca{sub 4}Si{sub 2}O{sub 7}F{sub 2}) as the main mineralogical phase formed during the flux solidification by X-ray powder diffraction (XRD). This phase directly influences the heat transfer phenomena from the strand to the mould and it is obtained with higher fluorite content (22% CaF{sub 2}). Cuspidine is desirable only in fluxes to produce medium carbon (included peritectic grade) steels, because it reduces the heat flux from the strand to the mould, thus controlling the shrinkage rate during the flux solidification. The experimental results are in agreement with those obtained by the thermodynamic software. The stability phase diagrams could be used as an important tool in the flux design for continuous casting process.

  1. Automated mineralogical logging of coal and coal measure core

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Fraser; Joan Esterle; Colin Ward; Ruth Henwood; Peter Mason; Jon Huntington; Phil Connor; Reneta Sliwa; Dave Coward; Lew Whitbourn [CSIRO Exploration & Mining (Australia)

    2006-06-15

    A mineralogical core logging system based on spectral reflectance (HyLogger{trademark}) has been used to detect and quantify mineralogies in coal and coal measure sediments. The HyLogger{trademark} system, as tested, operates in the visible-to-shortwave infrared spectral region, where iron oxides, sulphates, hydroxyl-bearing and carbonate minerals have characteristic spectral responses. Specialized software assists with mineral identification and data display. Three Phases of activity were undertaken. In Phase I, carbonates (siderite, ankerite, calcite) and clays (halloysite, dickite) were successfully detected and mapped in coal. Repeat measurements taken from one of the cores after three months demonstrated the reproducibility of the spectral approach, with some spectral differences being attributed to variations in moisture content and oxidation. Also, investigated was HyLogger{trademark} ability to create a 'brightness-profile' on coal materials, and these results were encouraging. In Phase II, geotechnically significant smectitic clays (montmorillonite) were detected and mapped in cores of clastic roof and floor materials. Such knowledge would be useful for mine planning and design purposes. In Phase III, our attempts at determining whether phosphorus-bearing minerals such as apatite could be spectrally detected were less than conclusive. A spectral index could only be created for apatite, and the relationships between the spectrally-derived apatite-index, the XRD results and the analytically-derived phosphorus measurements were ambiguous.

  2. Iron concretions in Brazilian Soils. 2. Mineralogical characterization

    International Nuclear Information System (INIS)

    Fontes, M.R.; Silva, E.G. da

    1985-01-01

    The mineralogy of six concretionary material from several pedological domains in Brazil were examined by x-ray diffratometry analysis and room temperature (RT) 57 Fe Moessbauer Spectroscopy. In two samples (from 'Quadrilatero Ferrifero' and Itaituba, in the state of Para) hematite was the predominant mineralogical phase, while in the other samples, from Chapada do Apodi (State of Rio Grande do Norte), Calciolandia (State of Minas Gerais), and Vicosa (State of Minas Gerais), goethite appeared as the main occurring mineral, in the (hydr) oxide crystallized fraction. The goethitic character was related to the manganese content in the concretions. The Moessbauer patterns exhibited superparamagnetic relaxation effects, although a six line hyperfine magnetic splitting, and a central doublet appeared at least in three cases. Exceptionally, in the two samples from Chapada do Apodi the six line pattern collapsed completely, and only a central doublet remained. The hyperfine magnetic field was drastically reduced both by particle size and isomorphically substituted aluminum in the iron oxide structure, probably, of Al-hematites. From the Moessbauer parameters, Al-goethite seemed to be present only in the sample from Vicosa, although it should be emphasized that the RT measurements do not always permit access to the hyperfine strucutre in this kind of material, as a result of small size particle effects. (Author) [pt

  3. Mineralogical and chemical characteristics of marble of Bela Pola deposite

    International Nuclear Information System (INIS)

    Shijakova-Ivanova, Tena; Boev, Blazho; Panov, Zoran; Pavlov, Dejan

    2009-01-01

    This paper presents mineralogical characteristics of marbles from the Bela Pola deposit. We have made mineralogical-chemical analyses of marbles and associated minerals in them. The investigation was carried out at the Faculty of natural and technical sciences - Shtip. Marbles from Bela Pola are dolomite and dolomite-calcite types. Microscope investigations have shown that marbles from Bela Pola have granoblastic structure but at some places it can be found with porphyroblastic structures. Percentage on calcite and dolomite is: 94.08% dolomite, 6.25% is calcite in white marbles. On the other hand calcite is present with 93% in gray marbles. Except dolomite and calcite also appear the following accessoring minerals: quartz, fluorite, corundum and paragonite. In general, after summarizing all the facts, which have resulted from this research we could say that, the Bela Pola marbles are massive, compact and white with high quality. In accordance to all formerly mentioned features, this marbles can be classified in the commercial group of marbles suitable for external application or internal design

  4. Mineralogic studies of tuff for high-level waste disposal

    International Nuclear Information System (INIS)

    Vaniman, D.; Bish, D.; Broxton, D.; Byers, F.; Carlos, B.; Levy, S.

    1986-01-01

    The volcanic rocks at Yucca Mountain, Nevada, consist predominantly of tuff that originated 12 to 14 million years ago as flows and airfalls of hot volcanic particulates. On cooling these units formed two major rock types: crystallized zones formed mostly of feldspar and silica minerals, and zones of glass. Alteration of glass to zeolite minerals occurred largely during structural tilting of Yucca Mountain in the ∼1-3 million years following the major eruptions. The compositions of zeolites formed from glasses strongly indicate open-system chemical exchange. Superimposed on this general alteration of glasses are areas of local high-temperature alteration. High-temperature alteration ended by 11 million years ago. Zeolites such as clinoptilolite persisted during high-temperature alteration at temperatures up to 100 degree C, suggesting that clinoptilolite at Yucca Mountain close to the thermally disturbed zone around a repository may also survive heating to temperatures at least this high. The mineralogic data from tuff at Yucca Mountain will ultimately be used by the Department of Energy Nevada Nuclear Waste storage Investigations for (1) defining the mineralogic component in estimating waste element travel times away from the repository and (2) determining the past history of alteration and the anticipated stability of minerals near the repository

  5. Mineralogic Model (MM3.0) Analysis Model Report

    Energy Technology Data Exchange (ETDEWEB)

    C. Lum

    2002-02-12

    The purpose of this report is to document the Mineralogic Model (MM), Version 3.0 (MM3.0) with regard to data input, modeling methods, assumptions, uncertainties, limitations and validation of the model results, qualification status of the model, and the differences between Version 3.0 and previous versions. A three-dimensional (3-D) Mineralogic Model was developed for Yucca Mountain to support the analyses of hydrologic properties, radionuclide transport, mineral health hazards, repository performance, and repository design. Version 3.0 of the MM was developed from mineralogic data obtained from borehole samples. It consists of matrix mineral abundances as a function of x (easting), y (northing), and z (elevation), referenced to the stratigraphic framework defined in Version 3.1 of the Geologic Framework Model (GFM). The MM was developed specifically for incorporation into the 3-D Integrated Site Model (ISM). The MM enables project personnel to obtain calculated mineral abundances at any position, within any region, or within any stratigraphic unit in the model area. The significance of the MM for key aspects of site characterization and performance assessment is explained in the following subsections. This work was conducted in accordance with the Development Plan for the MM (CRWMS M&O 2000). The planning document for this Rev. 00, ICN 02 of this AMR is Technical Work Plan, TWP-NBS-GS-000003, Technical Work Plan for the Integrated Site Model, Process Model Report, Revision 01 (CRWMS M&O 2000). The purpose of this ICN is to record changes in the classification of input status by the resolution of the use of TBV software and data in this report. Constraints and limitations of the MM are discussed in the appropriate sections that follow. The MM is one component of the ISM, which has been developed to provide a consistent volumetric portrayal of the rock layers, rock properties, and mineralogy of the Yucca Mountain site. The ISM consists of three components: (1

  6. Mineralogic Model (MM3.0) Analysis Model Report

    International Nuclear Information System (INIS)

    Lum, C.

    2002-01-01

    The purpose of this report is to document the Mineralogic Model (MM), Version 3.0 (MM3.0) with regard to data input, modeling methods, assumptions, uncertainties, limitations and validation of the model results, qualification status of the model, and the differences between Version 3.0 and previous versions. A three-dimensional (3-D) Mineralogic Model was developed for Yucca Mountain to support the analyses of hydrologic properties, radionuclide transport, mineral health hazards, repository performance, and repository design. Version 3.0 of the MM was developed from mineralogic data obtained from borehole samples. It consists of matrix mineral abundances as a function of x (easting), y (northing), and z (elevation), referenced to the stratigraphic framework defined in Version 3.1 of the Geologic Framework Model (GFM). The MM was developed specifically for incorporation into the 3-D Integrated Site Model (ISM). The MM enables project personnel to obtain calculated mineral abundances at any position, within any region, or within any stratigraphic unit in the model area. The significance of the MM for key aspects of site characterization and performance assessment is explained in the following subsections. This work was conducted in accordance with the Development Plan for the MM (CRWMS M and O 2000). The planning document for this Rev. 00, ICN 02 of this AMR is Technical Work Plan, TWP-NBS-GS-000003, Technical Work Plan for the Integrated Site Model, Process Model Report, Revision 01 (CRWMS M and O 2000). The purpose of this ICN is to record changes in the classification of input status by the resolution of the use of TBV software and data in this report. Constraints and limitations of the MM are discussed in the appropriate sections that follow. The MM is one component of the ISM, which has been developed to provide a consistent volumetric portrayal of the rock layers, rock properties, and mineralogy of the Yucca Mountain site. The ISM consists of three components

  7. Clay mineralogy of soils located on islands in the upper Paraná River, PR/MS

    Directory of Open Access Journals (Sweden)

    Paulo Henrique Marques de Castro

    2014-10-01

    Full Text Available The Mutum and Porto Rico islands are part of the archipelago Mutum-Porto Rico, located in the upper Paraná River between the cities Porto Rico, PR and Taquaruçu, MS. The soils are formed by constituents inherited from parent materials, organic compounds, and various minerals with varying degrees of complexity and stages of weathering. Among the constituents inherited of the parent materials, the most active are called clay minerals, derived from the weathering or transformation of primary minerals. The clay minerals has a key role in behavior morphological, chemical, physical and hydraulic of soil. They comprise a large family of minerals that can be classified into several groups according to their crystalline structure, like the kaolinites, smectite and ilitas. The aim of this study was to conduct mineralogical analyzes by X-ray in eight soils from the Mutum and Porto Rico islands. The mineralogical data were generated from the Panalytical X-ray diffractometer and X’pert Highscore Plus software. The results show that all soils showed a pattern of peaks comprising illite, kaolinite and gibbsite. Some soils also had characteristic peaks of iron oxyhydroxide.

  8. Chemical and mineralogical characterization of the bentonite buffer for the acceptance control procedure in a KBS-3 repository

    Energy Technology Data Exchange (ETDEWEB)

    Karnland, Ola (Clay Technology AB, Lund (Sweden))

    2010-09-15

    The present report concerns the chemical and mineralogical characterization of potential buffer materials. A short mineralogical description of bentonite and montmorillonite is given. The report defines, and exemplifies analyses and tests planned for the acceptance control of the bulk material concerning chemical composition, mineralogical composition, original exchangeable cations, cation exchange capacity (CEC), grain density, specific surface area, granule size, water content. In addition, analyses of the clay fraction, i.e. material with a grain size smaller than 2 mum, are described with respect to chemical composition including layer charge, layer charge distribution and cation exchange capacity (CEC). Results from the report by /Karnland et al. 2006/ concerning the two reference bentonites MX-80 and IBECO RWC are used to illustrate the accuracy and precision of the analyses. For each type of analyses the purpose, technique and, in relevant cases, also limits are discussed briefly. An empirical model for determining swelling pressure is presented and used for the quantification of the expected sealing properties given the limits concerning buffer density and montmorillonite content. For the reference bentonites MX-80, the stipulated montmorillonite content interval from 0.75 to 0.9 gives a pressure interval from 8 to 11 MPa at the nominal saturated density 2,000 kg/m3. The stipulated saturated density interval from 1,950 to 2,050 kg/m3 gives a pressure range from 6 to 15 MPa at the measured montmorillonite content of 83% by weight. The combined effects of the stipulated montmorillonite content interval and saturated density interval lead to a pressure range from 5 to 17 MPa. If the increasing effect of accessory minerals, which is proposed by the model, is not taken into account then the combined pressure range is 3 to 14 MPa

  9. Transformation of industrial territories

    Science.gov (United States)

    Plotnikova, N. I.; Kolocova, I. I.

    2017-08-01

    The problem of removing industrial enterprises from the historical center of the city and the subsequent effective use of the territories has been relevant for Western countries. Nowadays, the problem is crucial for Russia, its megacities and regional centers. The paper analyzes successful projects of transforming industrial facilities into cultural, business and residential objects in the world and in Russia. The patterns of the project development have been determined and presented in the paper.

  10. Mineralogy of an Active Eolian Sediment from the Namib Dune, Gale Crater, Mars

    OpenAIRE

    Achilles, C. N.; Downs, R. T.; Ming, D. W.; Rampe, E. B.; Morris, R. V.; Treiman, A. H.; Morrison, S. M.; Blake, D. F.; Vaniman, D. T.; Ewing, R. C.; Chipera, S. J.; Yen, A. S.; Bristow, T. F.; Ehlmann, B. L.; Gellert, R.

    2017-01-01

    The Mars Science Laboratory rover, Curiosity, is using a comprehensive scientific payload to explore rocks and soils in Gale crater, Mars. Recent investigations of the Bagnold Dune Field provided the first in situ assessment of an active dune on Mars. The Chemistry and Mineralogy (CheMin) X-ray diffraction instrument on Curiosity performed quantitative mineralogical analyses of the

  11. Chemical and mineralogical characterization of iron concretions of some Brazilian soils

    International Nuclear Information System (INIS)

    Soares, M.F.

    1980-01-01

    Chemical and physical analyses of concretionary materials were carried out, with the purpose of getting chemical and mineralogical characteristics of concretions found in some Brazilian soils in different ecosystems spectrophotometry was used for the chemical characterization, and x-ray diffraction and Moessbauer spectroscopy for the mineralogical characterization of the materials studied. (A.R.H.) [pt

  12. Mineral Supertrumps: A New Card Game to Assist Learning of Mineralogy

    Science.gov (United States)

    Spandler, Carl

    2016-01-01

    Mineralogy is an essential component of Earth Science education, yet many students struggle to obtain adequate comprehension and knowledge of mineralogy during tertiary (postsecondary) degree programs. The use of educational games can be an effective strategy for science teaching as games provide an active learning environment that enhances…

  13. Correlation between thermal behavior of clays and their chemical and mineralogical composition: a review

    Science.gov (United States)

    Dwi Yanti, Evi; Pratiwi, I.

    2018-02-01

    Clay's abundance has been widely used as industrial raw materials, especially ceramic and tile industries. Utilization of these minerals needs a thermal process for producing ceramic products. Two studies conducted by Septawander et al. and Chin C et al., showed the relationship between thermal behavior of clays and their chemical and mineralogical composition. Clays are characterized by XRD analysis and thermal analysis, ranging from 1100°C to 1200°C room temperature. Specimen of raw materials of clay which is used for the thermal treatment is taken from different geological conditions and formation. In raw material, Quartz is almost present in all samples. Halloysite, montmorillonite, and feldspar are present in Tanjung Morawa raw clay. KC and MC similar kaolinite and illite are present in the samples. The research illustrates the interrelationships of clay minerals and chemical composition with their heat behavior. As the temperature of combustion increases, the sample reduces a significant weight. The minerals which have undergone a transformation phase became mullite, cristobalite or illite and quartz. Under SEM analysis, the microstructures of the samples showed irregularity in shape; changes occurred due the increase of heat.

  14. Applied nuclear γ-resonance as fingerprint technique in geochemistry and mineralogy

    International Nuclear Information System (INIS)

    Constantinescu, S.

    2003-01-01

    The aim of the present paper is to evidence the new developments of one of the most refined technique, the nuclear γ resonance or the well-known Moessbauer effect, in the field of mineralogical and geo-chemical investigation. There are many Moessbauer studies on minerals, but the development, the new performance of the Moessbauer equipment and of the computers impose to review more profoundly and more thoroughly the information, which this non-destructive technique offers. This task became more and more pressingly because a lot of minerals contain in high proportion, the Moessbauer isotopes. Generally, the mineralogists, physicists and chemists hope to obtain more refined and complete information about the physics and chemistry synthesis aspects in solid state transformation of some natural and synthetic materials and also about the structural aspects, by these kind of techniques. On this line, the authors very shortly review the principal aspects of the Moessbauer spectroscopy and underline the most important information one can obtain from spectra. The recent results, which have been obtained on minerals extracted from Romanian geological deposits by the authors, will be discussed in detail in the second part of this article. (authors)

  15. Detection and context of hydrated mineralogy in the Tyrrhena Terra region, Mars

    Science.gov (United States)

    den Haan, J.; Zegers, T. E.; van Ruitenbeek, F. J. A.; van der Werff, H. M. A.; Rossi, A.

    2008-09-01

    two spectra taken at base and summit of Olympus Mons provides the atmospheric spectrum. To quickly assess the mineralogy of a large region, CRISM multispectral summary products [5] are applied to OMEGA datasets. Hydrated mineral deposits are located on the basis of the absorption feature centered at ~1.9um. This feature is the result of a combination of v2 bend and v3 (asymmetrical) stretch mode overtones. Noise reduction is performed by applying a principal component transform to the OMEGA data. Principal components which are dominated by noise are manually selected and discarded, after which the data are transformed back to the wavelength domain. Using this approach, a large degree of system noise can be effectively eliminated without significantly affecting signal quality [6]. Results The methods described have led to positive identification of large deposits of hydrated mineralogy in Tyrrhena Terra. Whilst several deposits are evidently associated with cratering processes (e.g. [7]), one major deposit in particular draws attention (figure 1). In this deposit, the light-colored hydrated minerals are generally associated with very rough morphology. In addition, they seem to be located underneath a dark, crater-saturated unit. Given the limited quality of local OMEGA-derived spectra, it is impossible to unambiguously determine the exact mineralogy of the deposit. The hydrated signature is correlated with high night-time temperatures as observed in THEMIS IRnight observations (figure 2). This indicates the hydrated material is present as a solid bedrock mass (e.g. mudstone) instead of a loose concretion. The deposit is situated in a topographic low, bounded by a channel-rich unit in the north and a sharp unit contact in the south. Discussion The sharp unit contact south of the hydrated deposit coincides with a sharp contrast in topographic elevation. It strikes parallel to the contours of Isidis Planitia, a trend which is continued on larger scale. Given the strike

  16. Security Transformation

    National Research Council Canada - National Science Library

    Metz, Steven

    2003-01-01

    ... adjustment. With American military forces engaged around the world in both combat and stabilization operations, the need for rigorous and critical analysis of security transformation has never been greater...

  17. Comparative mineralogical characteristics of red soils from South Bulgaria

    Directory of Open Access Journals (Sweden)

    Marlena Yaneva

    2015-01-01

    Full Text Available The present study aims to compare mineralogical composition of red soils, formed on marbles in South Bulgaria. We used mineralogical analysis of heavy and light mineral fraction in immersion under polarizing microscope and X-ray diffraction analysis of bulk sample and clay fraction. Three test polygons, located in South Bulgaria were examined: Petrovo, Nova Lovcha and Dobrostan, which are characterized with different latitude, altitude, and exposition. Three or more sites from each polygon were sampled and analyzed. The red soils are formed on white and gray calcite and calcite-dolomite marbles, impure silicate-rich marbles and only in one site – on marble breccias. We determined the following mineral phases in red soils: calcite, dolomite, quarts, and feldspars, mica, illite-type mica, illite, smectite, vermiculite-smectite, and kaolinite. Heavy minerals are represented by amphibole, titanite and epidote, and minor amounts of zircon, garnet, tourmaline, rutile, pyroxene, andalusite, kyanite, sillimanite and apatite. Opaque minerals are predominantly goethite and hematite. Plant tissue is abundant in light fraction from the uppermost soil horizons. Analyses of heavy mineral fraction show presence of metamorphic and igneous minerals which indicate participation of weathering products from other rock types in the nearby area. The types of heavy minerals in soils depend more on composition of parent rocks and geomorphic position than on climate type. Soils from Nova Lovcha show similar composition, but the quantity of goethite and hematite significantly increase in soil from plain. Typical high-metamorphic minerals as andalusite, kyanite and sillimanite present only in Nova Lovcha, while garnet dominates in Petrovo and opaque minerals - in Dobrostan. Red soils, formed on slopes, where erosion prevails over accumulation, contain more illite, smectite and vermiculite-smectite, and very few or no kaolinite, whereas the kaolinite is dominant in soils

  18. Characterization of rock samples and mineralogical controls on leachates

    Science.gov (United States)

    Hammarstrom, Jane M.; Cravotta, Charles A.; Galeone, Daniel G.; Jackson, John C.; Dulong, Frank T.; Hornberger, Roger J.; Brady, Keith B.C.

    2009-01-01

    Rocks associated with coal beds typically include shale, sandstone, and (or) limestone. In addition to common rock-forming minerals, all of these rock types may contain sulfide and sulfate minerals, various carbonate minerals, and organic material. These different minerals have inherently different solubility characteristics, as well as different acid-generating or acid-neutralizing potentials. The abundance and composition of sulfur- and carbonate-bearing minerals are of particular interest in interpreting the leaching column data because (1) pyrite and carbonate minerals are the primary controls on the acid-base account of a sample, (2) these minerals incorporate trace metals that can be released during weathering, and (3) these minerals readily react during weathering due to mineral dissolution and oxidation of iron.Rock samples were collected by the Pennsylvania Department of Environmental Protection (PaDEP) from five different sites to assess the draft standardized leaching column method (ADTI-WP2) for the prediction of weathering rates and water quality at coal mines. Samples were sent to USGS laboratories for mineralogical characterization and to ActLabs for chemical analysis. The samples represent a variety of rock types (shales, sandstones, and coal refuse) that are typical of coal overburden in the eastern United States. These particular samples were chosen for testing the weathering protocols because they represent a range of geochemical and lithologic characteristics, sulfur contents, and acid-base accounting characteristics (Hornberger et al., 2003). The rocks contain variable amounts of pyrite and carbonate minerals and vary in texture.This chapter includes bulk rock chemical data and detailed mineralogical and textural data for unweathered starting materials used in the interlaboratory validation study, and for two samples used in the early phases of leaching column tests (Wadesville Sandstone, Leechburg Coal Refuse). We also characterize some of the

  19. Landskabets transformation

    DEFF Research Database (Denmark)

    Munck Petersen, Rikke

    2005-01-01

    Seminaroplæg fra forskere. Faglige seminarer på KA, forår 2005. Belyser transformation af det danske landskab fysisk som holdningsmæssigt, samt hvordan phd-arbejdets egen proces håndterer den.......Seminaroplæg fra forskere. Faglige seminarer på KA, forår 2005. Belyser transformation af det danske landskab fysisk som holdningsmæssigt, samt hvordan phd-arbejdets egen proces håndterer den....

  20. Covariant Transform

    OpenAIRE

    Kisil, Vladimir V.

    2010-01-01

    The paper develops theory of covariant transform, which is inspired by the wavelet construction. It was observed that many interesting types of wavelets (or coherent states) arise from group representations which are not square integrable or vacuum vectors which are not admissible. Covariant transform extends an applicability of the popular wavelets construction to classic examples like the Hardy space H_2, Banach spaces, covariant functional calculus and many others. Keywords: Wavelets, cohe...

  1. Transforming Anatomy

    OpenAIRE

    Hall, Anndee

    2017-01-01

    Abstract: Transforming Anatomy Studying historic books allows people to witness the transformation of the world right before their very eyes. The Bruxellensis Icones Anatomicae[1] by Andreas Vesalius is a vital piece of evidence in the movement from a more rudimentary understanding of the human body into the more complex and accurate development of modern anatomy. Vesalius’ research worked to both refute and confirm findings of his predecessor, the great historical Greek philosopher, Galen...

  2. Integrated acoustic, mineralogy, and geomechanics characterization of the Huron shale southern West Virginia, USA

    Energy Technology Data Exchange (ETDEWEB)

    Franquet, J.A.; Mitra, Arijit; Warrington, D.S.; Moos, Daniel; Lacazette, Alfred [Society of Petroleum Engineers (Canada)

    2011-07-01

    Successful hydraulic fracturing and horizontal drilling are the key to exploiting unconventional shale gas reservoirs. Acoustic anisotropy, in-situ stress, mineralogy and organic matter content are important factors in well completion design. This paper explores an integrated acoustic, mineralogy and geomechanics characterization of the Huron shale, located in south west Virginia, USA. The study consisted of acquiring the borehole acoustic and mineralogy logging data, in addition to conventional logs, from a vertical well prior to hydraulic fracturing and microseismic monitoring. The acoustic data were processed for borehole Stoneley reflective indicators and radial velocity variations. Substantial transverse acoustic anisotropy was noticed and used to acquire vertical and horizontal dynamic elastic properties. A micromechanical constitutive model, arrived at through mineralogy and petrophysical analysis, was used to produce the stress-strain behavior of the rock. This stress profile, with accurate mineralogy and petrophysical analysis, provides important information for best selection of lateral wells and helps in the identification of natural fracture barriers.

  3. Effects of thermal treatment on mineralogy and heavy metal behavior in iron oxide stabilized air pollution control residues

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Bender-Koch, C.; Starckpoole, M. M.

    2000-01-01

    Stabilization of air pollution control residues by coprecipitation with ferrous iron and subsequent thermal treatment (at 600 and 900 °C) has been examined as a means to reduce heavy metal leaching and to improve product stability. Changes in mineralogy and metal binding were analyzed using various...... analytical and environmental techniques. Ferrihydrite was formed initially but transformed upon thermal treatment to more stable and crystalline iron oxides (maghemite and hematite). For some metals leaching studies showed more substantial binding after thermal treatment, while other metals either....... Thermal treatment of the stabilized residues produced structures with an inherently better iron oxide stability. However, the concentration of metals in the leachate generally increased as a consequence of the decreased solubility of metals in the more stable iron oxide structure....

  4. Mineralogy of dust deposited during the Harmattan season in Ghana

    DEFF Research Database (Denmark)

    He, Changling; Breuning-Madsen, Henrik; Awadzi, Theodore W.

    2007-01-01

    Ocean. In this project, we studied samples of dust and topsoils in various agroecological zones, from the north to the south of Ghana, focussing mainly on the mineralogy of these materials. Some data about grain sizes and morphology of the samples are also presented. Feldspars, together with quartz......In Ghana, a dust-laden Harmattan wind blows from the Sahara in the period November to March. Some of the dust is trapped in the vegetation, in lakes and other inland waters, and a little on the bare land, whereas the rest of the dust is blown further away to the Ivory Coast or out into the Atlantic......, are the common minerals found in Harmattan dust, but the relative contents of K-feldspars and plagioclase vary markedly in the different zones. This variation is consistent with changes in the relative content of the feldspars in the topsoil, indicating a substantial local contribution to the Harmattan dust...

  5. Soil chemistry and mineralogy of the Santa Cruz coastal terraces

    Science.gov (United States)

    Pinney, Colin; Aniku, Jacob; Burke, Raymond; Harden, Jennifer; Singer, Michael; Munster, Jennie

    2002-01-01

    Marine terraces in the central coast of California provide an opportunity to study a soil chronosequence in which similar materials (beach deposits) have been weathered under similar slope, climatic, and vegetation conditions during the Quaternary. The terraces between Santa Cruz and Año Nuevo, California, have been studied for decades and are thought to be one of the best example of marine terraces in California {Lawson (1893), Wilson (1907); Branner and others (1909), Rode (1930) Page and Holmes (1945), Alexander (1953), Bradley (1956, 1957, 1958, and 1965), Bradley and Addicott (1968), Clark (1966 and 1970), Jahns and Hamilton (1971), Lajoie and others (1972), Bradley and Griggs (1976). Hanks and others (1986), Aniku (1986), Fine and others (1988), Anderson (1990 and 1994), and Rosenbloom and Anderson (1994).} Here we report morphological, chemical, physical, and mineralogical data for the soils that were formed in deposits on the Santa Cruz marine terraces in order to examine soil characteristics as a function of increasing terrace age.

  6. Handbook of soil analysis. Mineralogical, organic and inorganic methods

    Energy Technology Data Exchange (ETDEWEB)

    Pansu, M. [Centre IRD, 34 - Montpellier (France); Gautheyrou, J.

    2006-07-01

    This handbook is a reference guide for selecting and carrying out numerous methods of soil analysis. It is written in accordance with analytical standards and quality control approaches.It covers a large body of technical information including protocols, tables, formulae, spectrum models, chromatograms and additional analytical diagrams. The approaches are diverse, from the simplest tests to the most sophisticated determination methods in the physical chemistry of mineralogical and organic structures, available and total elements, soil exchange complex, pesticides and contaminants, trace elements and isotopes.As a basic reference, it will be particularly useful to scientists, engineers, technicians, professors and students, in the areas of soil science, agronomy, earth and environmental sciences as well as in related fields such as analytical chemistry, geology, hydrology, ecology, climatology, civil engineering and industrial activities associated with soil. (orig.)

  7. Mineralogy and geochemistry of soils from glass houses and solariums

    Science.gov (United States)

    Bulgariu, Dumitru; Filipov, Feodor; Rusu, Constantin; Bulgariu, Laura

    2010-05-01

    The experimental studies have been performed on soil samples from Copou-Iaşi, Bacău and Bârlad (România) glass houses. We have specially follow the aspects concerning to the distribution of occurrence forms, composition and structure of mineral and organic components, and the genetic correlations between these in conditions of soils from glass houses, respectively. The results regarding the distribution tendencies on profile and the correlations between mineral and organic components of studied soils have been correlated with the results of microscopic, spectral (IR and Raman) and X-ray diffraction studies, and with the results of thermodynamic modelling of mineral equilibriums and dynamics of pedogenesis processes, in conditions of soils from glass houses. The utilization of intensive cultivation technologies of vegetables in glass houses determined the degradation of morphological, physical and chemical characteristics of soils, by fast evolution of salted processes (salinization and / or sodization), compaction, carbonatation, eluviation-illuviation, frangipane formation, stagnogleization, gleization, etc. Under these conditions, at depth of 30-40 cm is formed a compact and impenetrable horizon with frangipane characteristics, expresses more or less. The aspects about the formation of frangipane horizon in soils from glasshouses are not yet sufficiently know. Whatever of the formation processes, the frangipane horizons determined a sever segregation in pedo-geochemical evolution of soils from glasshouses, with very important consequences on the agrochemical quality of these soils. The soils from glass houses are characterized by a very large variability of mineralogy and chemistry, which are traduced by intense modifications of superior horizons, in many cases there are conditions for the apparition of new pedogenetic horizons through new-pedogenesis processes. Under these conditions the definition of some general characteristics of soils from glasshouses is

  8. Minerals cave, Volcan Irazu, Costa Rica: description, mineralogy and origin

    International Nuclear Information System (INIS)

    Ulloa, Andres; Campos-Fernandez, Cristian S.; Rojas, Leonardo

    2013-01-01

    Two caves are found in the NW sector of the main crater of the Volcan Irazu at the base of the crown of a glide. The caves are located in an area of structural weakness of the massif developed in sequences of pyroclasts with hydrothermal alteration. Several explorations are organized for the recognition of the caves. The purpose has been of collecting samples and photographs for mineralogical and topographic analyses, through X-ray diffractometry. The minerals present in the samples are compared and identified by means of PDF-2 power x-ray diffraction database of the 2007 ICDD, International Center for Diffraction Data. The origin of the caves has been studied, and it is suggested to carry out other of complement studies [es

  9. Raman spectroscopic analysis of real samples: Brazilian bauxite mineralogy

    Science.gov (United States)

    Faulstich, Fabiano Richard Leite; Castro, Harlem V.; de Oliveira, Luiz Fernando Cappa; Neumann, Reiner

    2011-10-01

    In this investigation, Raman spectroscopy with 1064 and 632.8 nm excitation was used to investigate real mineral samples of bauxite ore from mines of Northern Brazil, together with Raman mapping and X-rays diffraction. The obtained results show clearly that the use of microRaman spectroscopy is a powerful tool for the identification of all the minerals usually found in bauxites: gibbsite, kaolinite, goethite, hematite, anatase and quartz. Bulk samples can also be analysed, and FT-Raman is more adequate due to better signal-to-noise ratio and representativity, although not efficient for kaolinite. The identification of fingerprinting vibrations for all the minerals allows the acquisition of Raman-based chemical maps, potentially powerful tools for process mineralogy applied to bauxite ores.

  10. The mineralogy of bauxite for producing smelter-grade alumina

    Science.gov (United States)

    Authier-Martin, M.; Forte, G.; Ostap, S.; See, J.

    2001-12-01

    Aluminum-producing companies rely on low-cost, high-purity, smelter-grade alumina (aluminum oxide), and alumina production utilizes the bulk of bauxites mined world-wide. The mineralogy of the bauxites has a significant impact on the operation of the Bayer process for alumina production. Typically, the Bayer process produces smelter-grade alumina of 99.5% Al2O3, starting from bauxite containing 30% to 60% Al2O3. The main objective of the Bayer process is to extract the maximum amount of aluminum from the bauxite at as high an aluminate concentration in solution as possible, while limiting any troublesome side reactions. Only with a better understanding of the chemistry of the mineral species and a strict control of the operating/processing conditions can the Bayer process produce efficiently, a low cost, high-quality alumina with minimum detrimental environmental impact.

  11. Mineralogical and paragenetical problems of the Mecsek uranium ore

    International Nuclear Information System (INIS)

    Vincze, J.; Fazekas, V.

    1979-01-01

    The latest results of the ore-mineralogical examination of the uranium ore of a deposit included in Permian sandstones in the Mecsek Mountains, southern Hungary, are presented. The phases of the minerals belonging to the uranium oxide series and their types of development, the post-coffinite nasturan pseudomorphs and the relationship between nasturan and coffinite are dealt with. Of the sulphide ore minerals associated with uranium ore mineralization the type determinant mineral is pyrite, i.e. the mineral forming their bulk and partly represented by characteristically finely aggregated ''bacteriopyrite'' and/or spherical pyrite and ''framboidal pyrite. The textural pattern of the ore mineralization is of typically matrix type. The matrix of sandstone is constituted by carbonate minerals, ''hydromicas'' and ore minerals. The matrix and, consequently, the ore minerals will corrode and consume the allothigenic detrital rockforming minerals, the feldspar, quartz-porphyry and quartz. (A.L.)

  12. Comet Mineralogy as Inferred from Infrared Spectra of Comets

    Science.gov (United States)

    Wooden, Diane H.

    2006-01-01

    For most comets, infrared (IR) spectroscopy (remote sensing) is the method through which we diagnose the mineralogy and size distribution of dust in their comae. The shape and contrast of the IR spectral features depend on the particle size: optically active minerals (absorbing of visible and near-IR solar photons) and submicron solid grains or highly porous (> 90% vacuum) grains primarily contribute to the shapes of the observed resonances. Comet mineralogies typically are determined by fitting thermal emission models of ensembles of discrete mineral grains to observed IR spectral energy distributions. The absorptivities (Q-abs) and scattering efficiencies (Q-scat) of the discrete mineral grains are computed using Mie scattering, Maxwell-Garnet mixing, Discrete Dipole Approximation, and Multi-Layered Sphere codes. These techniques when applied to crystalline minerals, specifically olivine (Mg_x, Fe_1-x)2 Si04, x>0.9, require the use of ellipsoidal shaped particles with elongated axial ratios or hollow spheres to produce the shapes of the resonances observed both from comet comae and laboratory samples. The wavelength positions of the distinct resonances from submicron-radii crystalline silicates, as well as their thermal equilibrium temperatures, constrain the crystalline olivine to have a relatively high Mg-content (x>0.9, or Fo>90). Only resonances computed for submicron Mg-rich crystalline olivine and crystalline orthopyroxene match the observed IR spectral features. However, this has led to the interpretation that micron-radii and larger crystals are absent from comet comae. Furthermore, the mass fraction of silicate crystals is dependent upon whether just the submicron portion of the size distribution is being compared or the submicron crystals compare to the aggregates of porous amorphous silicates that are computationally tractable as porous spheres. We will discuss the Deep Impact results as examples of these challenges to interpreting mid-IR spectra of

  13. Preliminary Results on Mineralogy and Geochemistry of Loki's Castle Arctic Vents and Host Sediments

    Science.gov (United States)

    Barriga, Fernando; Carvalho, Carlos; Inês Cruz, M.; Dias, Ágata; Fonseca, Rita; Relvas, Jorge; Pedersen, Rolf

    2010-05-01

    The Loki's Castle hydrothermal vent field was discovered in the summer of 2008, during a cruise led by the Centre of Geobiology of the University of Bergen, integrated in the H2Deep Project (Eurocores, ESF). Loki's Castle is the northernmost hydrothermal vent field discovered to date. It is located at the junction between the Mohns Ridge and the South Knipovich Ridge, in the Norwegian-Greenland Sea, at almost 74°N. This junction shows unique features and apparently there is no transform fault to accommodate the deformation generated by the bending of the rift valley from WSW-ENE to almost N-S. The Knipovich Rigde, being a complex structure, is an ultra-slow spreading ridge, with an effective spreading rate of only ~ 6 mm/y. It is partly masked by a substantial cover of glacial and post-glacial sediments, estimated to be between 12 and 20 ky old, derived from the nearby Bear Island fan, to the East of the ridge. The Loki's Castle vent site is composed of several active, over 10 m tall chimneys, producing up to 320°C fluid, at the top of a very large sulphide mound, which is estimated to be around 200 m in diameter. About a dozen gravity cores were obtained in the overall area. From these we collected nearly 200 subsamples. Eh and pH were measured in all subsamples. The Portuguese component of the H2Deep project is aimed at characterizing, chemically and mineralogically, the sulphide chimneys and the collected sediments around the vents (up to 5 meters long gravity cores). These studies are aimed at understanding the ore-forming system, and its implications for submarine mineral exploration, as well as the relation of the microbial population with the hydrothermal component of sediments. Here we present an overview of preliminary data on the mineralogical assemblage found in the analyzed sediments and chimneys. The identification of the different mineral phases was obtained through petrographic observations of polished thin sections under the microscope (with both

  14. Impact of chloride on the mineralogy of hydrated Portland cement systems

    International Nuclear Information System (INIS)

    Balonis, Magdalena; Lothenbach, Barbara; Le Saout, Gwenn; Glasser, Fredrik P.

    2010-01-01

    Chloride ion is in part bound into ordinary Portland cement paste and modifies its mineralogy. To understand this a literature review of its impacts has been made and new experimental data were obtained. Phase pure preparations of Friedel's salt, Ca 4 Al 2 (Cl) 1.95 (OH) 12.05 .4H 2 O, and Kuzel's salt, Ca 4 Al 2 (Cl)(SO 4 ) 0.5 (OH) 12 .6H 2 O, were synthesized and their solubilities were measured at 5, 25, 55 and 85 o C. After equilibration, solid phases were analysed by X-ray diffraction while the aqueous solutions were analysed by atomic absorption spectroscopy and ion chromatography. The solid solutions and interactions of Friedel's salt with other AFm phases were determined at 25 o C experimentally and by calculations. In hydrated cements, anion sites in AFm are potentially occupied by OH, SO 4 and CO 3 ions whereas Cl may be introduced under service conditions. Chloride readily displaces hydroxide, sulfate and carbonate in the AFm structures. A comprehensive picture of phase relations of AFm phases and their binding capacity for chloride is provided for pH ∼ 12 and 25 o C. The role of chloride in AFt formation and its relevance to corrosion of embedded steel are discussed in terms of calculated aqueous [Cl - ]/[OH - ] molar ratios.

  15. Detailed mineralogical characterization of the Bullfrog and Tram members USW-G1, with emphasis on clay mineralogy

    International Nuclear Information System (INIS)

    Bish, D.L.

    1981-10-01

    The detailed mineralogy of the Bullfrog and Tram Members of the Crater Flat Tuff from drill hole USW-G1 has been examined, primarily to characterize fully the amounts and types of clay minerals in the tuffs and the possible effects clay minerals have on rock properties. Results of bulk sample x-ray diffraction analyses agree closely with previous determinations, although slightly higher clay mineral contents were found in this study. X-ray diffraction analysis of fine fractions revealed that the clay minerals in the tuffs are sodium-saturated montmorillonite-beidellites with typical layer charges and no high-charge layers. These smectites are found in virtually all samples of the Bullfrog and Tram, and there is no correlation between the amounts of smectites and the amounts of zeolite, quartz, and feldspar. Smectites are present in both welded and nonwelded horizons and are scarce in some zones with slight-to-absent welding

  16. Schooling Culturally Relevant Pedagogy: One Story about Tension and Transformation

    Science.gov (United States)

    Mason, Ann Mogush

    2013-01-01

    The need for multifaceted analyses of the relationship between how the United States acknowledges racism and how schooling can be structured to mitigate its negative impacts has never been greater, especially given the rising and often simplistic attention to the racial "achievement gap." In suburban, elite Pioneer City, a series of…

  17. "Let's take back our roots through Science". The Sicilian Sulfur: a mineralogical treasure to rediscover.

    Science.gov (United States)

    Parisi, Bianca

    2015-04-01

    The name of sulfur is synonymous of Sicily! Sicilian Sulfur minerals and evaporitic deposits are well-known because they are connected with an important evolution stage of the old mediterranean area. In this Island, in the southern part of Italy, a geological formation of Messinian age, called "gessoso solfifera", outcrops. These rocks are widespread in the south and south-west Sicily, and, there, salt mines and "zolfare", sulfur mines, were located. The formation is characterized by large amounts of gypsum, potassium salts, sodium chlorates and other deposits. Most of the main mineralogical museum collections all over the world have at least a sample of one of these minerals that are usually characterized by a high aesthetic quality. When I proposed a lesson on the origin of sulfur in evaporitic rocks, I realized that an important part of the hystory of our region was in danger to be forgotten by younger generation. The exploitation of this mineral resource in the past is strictly linked to the troubled social and cultural transformation of Sicily during the last century. Thus, this is a particularly suitable topic for a multidisciplinary approach. In cooperation with the Mineralogical Museum (SteBiCeF Department, University of Palermo), a learning project was proposed to a group of 4th year high school students. It has been carrying on in order to develop the knowledge of the geological and chemical features of evaporitic deposits and to promote scientific abilities together with a better understanding of social-environmental issues. Project aims and activities include: ➢ Solubility and saturation experiments to reconstruct a simplified model of minerals deposition ➢ Working in groups: collection of data about old geological outcrops and current evaporating basins where rocks are forming in the world as well as information on sicilian mines from literature and historical documents (video, interviews, pictures, newspapers and others) ➢ a guided tour of the

  18. Sustainable transformation

    DEFF Research Database (Denmark)

    Andersen, Nicolai Bo

    This paper is about sustainable transformation with a particular focus on listed buildings. It is based on the notion that sustainability is not just a question of energy conditions, but also about the building being robust. Robust architecture means that the building can be maintained and rebuilt......, that it can be adapted to changing functional needs, and that it has an architectural and cultural value. A specific proposal for a transformation that enhances the architectural qualities and building heritage values of an existing building forms the empirical material, which is discussed using different...... theoretical lenses. It is proposed that three parameters concerning the ꞌtransformabilityꞌ of the building can contribute to a more nuanced understanding of sustainable transformation: technical aspects, programmatic requirements and narrative value. It is proposed that the concept of ꞌsustainable...

  19. Identity transformation

    DEFF Research Database (Denmark)

    Neergaard, Helle; Robinson, Sarah; Jones, Sally

    , as well as the resources they have when they come to the classroom. It also incorporates perspectives from (ii) transformational learning and explores the concept of (iii) nudging from a pedagogical viewpoint, proposing it as an important tool in entrepreneurship education. The study incorporates......This paper develops the concept of ‘pedagogical nudging’ and examines four interventions in an entrepreneurship classroom and the potential it has for student identity transformation. Pedagogical nudging is positioned as a tool, which in the hands of a reflective, professional......) assists students in straddling the divide between identities, the emotions and tensions this elicits, and (iv) transform student understanding. We extend nudging theory into a new territory. Pedagogical nudging techniques may be able to unlock doors and bring our students beyond the unacknowledged...

  20. Making Deferred Taxes Relevant

    NARCIS (Netherlands)

    Brouwer, Arjan; Naarding, Ewout

    2018-01-01

    We analyse the conceptual problems in current accounting for deferred taxes and provide solutions derived from the literature in order to make International Financial Reporting Standards (IFRS) deferred tax numbers value-relevant. In our view, the empirical results concerning the value relevance of

  1. Parsimonious relevance models

    NARCIS (Netherlands)

    Meij, E.; Weerkamp, W.; Balog, K.; de Rijke, M.; Myang, S.-H.; Oard, D.W.; Sebastiani, F.; Chua, T.-S.; Leong, M.-K.

    2008-01-01

    We describe a method for applying parsimonious language models to re-estimate the term probabilities assigned by relevance models. We apply our method to six topic sets from test collections in five different genres. Our parsimonious relevance models (i) improve retrieval effectiveness in terms of

  2. Chemical characterization, nano-particle mineralogy and particle size distribution of basalt dust wastes

    Energy Technology Data Exchange (ETDEWEB)

    Dalmora, Adilson C. [Laboratory of Environmental Researches and Nanotechnology Development, Centro Universitário La Salle, Mestrado em Avaliação de Impactos Ambientais em Mineração. Victor Barreto, 2288 Centro 92010-000, Canoas, RS (Brazil); Institute for Environmental Assessment and Water Studies (IDÆA), Spanish National Research Council (CSIC), C/Jordi Girona 18-26, 08034 Barcelona (Spain); Ramos, Claudete G.; Oliveira, Marcos L.S. [Laboratory of Environmental Researches and Nanotechnology Development, Centro Universitário La Salle, Mestrado em Avaliação de Impactos Ambientais em Mineração. Victor Barreto, 2288 Centro 92010-000, Canoas, RS (Brazil); Teixeira, Elba C. [Fundação Estadual de Proteção Ambiental Henrique Luis Roessler, Porto Alegre, RS (Brazil); Kautzmann, Rubens M.; Taffarel, Silvio R. [Laboratory of Environmental Researches and Nanotechnology Development, Centro Universitário La Salle, Mestrado em Avaliação de Impactos Ambientais em Mineração. Victor Barreto, 2288 Centro 92010-000, Canoas, RS (Brazil); Brum, Irineu A.S. de [Universidade Federal do Rio Grande do Sul, Escola de Engenharia, Departamento de Metalurgia, Centro de Tecnologia, Av. Bento Gonçalves, 9500. Bairro Agronomia. CEP: 91501-970 Porto Alegre, RS (Brazil); and others

    2016-01-01

    -particle mineralogy and chemical composition in typical BDW samples highlights the need to develop cleaning procedures to minimize exposure to these natural fertilizing basalt dust wastes and is, thus, of direct relevance to both the industrial sector of basalt mining and to agriculture in the region. - Highlights: • Expansion in Brazilian basalt mining studies will increase human health information in this area. • Several samples were advanced nanoparticles techniques. • The compounds showed strong sorption ability to hazardous elements. • The advanced methodology has been applied to investigate elements occurrence and ultra-fine/nano-particles properties.

  3. Chemical characterization, nano-particle mineralogy and particle size distribution of basalt dust wastes

    International Nuclear Information System (INIS)

    Dalmora, Adilson C.; Ramos, Claudete G.; Oliveira, Marcos L.S.; Teixeira, Elba C.; Kautzmann, Rubens M.; Taffarel, Silvio R.; Brum, Irineu A.S. de

    2016-01-01

    Understanding the geochemistry of basalt alteration is central to the study of agriculture systems. Various nano-minerals play an important role in the mobilization of contaminants and their subsequent uptake by plants. We present a new analytical experimental approach in combination with an integrated analytical protocol designed to study basalt alteration processes. Recently, throughout the world, ultra-fine and nano-particles derived from basalt dust wastes (BDW) during “stonemeal” soil fertilizer application have been of great concern for their possible adverse effects on human health and environmental pollution. Samples of BDW utilized were obtained from companies in the Nova Prata mining district in southern Brazil for chemical characterization and nano-mineralogy investigation, using an integrated application of advanced characterization techniques such as X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/Energy Dispersive Spectroscopy (EDS)/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM/EDS), and granulometric distribution analysis. The investigation has revealed that BDW materials are dominated by SiO 2 , Al 2 O 3 , and Fe 2 O 3, with a complex micromineralogy including alkali feldspar, augite, barite, labradorite, hematite, heulandrite, gypsum, kaolinite, quartz, and smectite. In addition, we have identified a number of trace metals such as Cd, Cu, Cr, and Zn, that are preferentially concentrated into the finer, inhalable, dust fraction and, thus, could present a health hazard in the urban areas around the basalt mining zone. The implication of this observation is that use of these nanometric-sized particulates as soil fertilizer may present different health challenges to those of conventional fertilizers, inviting future work regarding the relative toxicities of these materials. Our investigation on the particle size distribution, nano-particle mineralogy and chemical

  4. Temperature buffer test. Hydro-mechanical and chemical/ mineralogical characterizations

    Energy Technology Data Exchange (ETDEWEB)

    Aakesson, Mattias; Olsson, Siv; Dueck, Ann; Nilsson, Ulf; Karnland, Ola [Clay Technology AB, Lund (Sweden); Kiviranta, Leena; Kumpulainen, Sirpa [BandTech Oy, Helsinki (Finland); Linden, Johan [Aabo Akademi, Aabo (Finland)

    2012-01-15

    The Temperature Buffer Test (TBT) is a joint project between SKB/ANDRA and supported by ENRESA (modeling) and DBE (instrumentation), which aims at improving the understanding and to model the thermo-hydro-mechanical behavior of buffers made of swelling clay submitted to high temperatures (over 100 deg C) during the water saturation process. The test has been carried out in a KBS-3 deposition hole at Aspo HRL. It was installed during the spring of 2003. Two steel heaters (3 m long, 0.6 m diameter) and two buffer arrangements have been investigated: the lower heater was surrounded by rings of compacted Wyoming bentonite only, whereas the upper heater was surrounded by a composite barrier, with a sand shield between the heater and the bentonite. The test was dismantled and sampled during the winter of 2009/2010. This report presents the hydro-mechanical and chemical/mineralogical characterization program which was launched subsequent to the dismantling operation. The main goal has been to investigate if any significant differences could be observed between material from the field experiment and the reference material. The field samples were mainly taken from Ring 4 (located at the mid-section around the lower heater), in which the temperature in the innermost part reached 155 deg C. The following hydro-mechanical properties have been determined for the material (test technique within brackets): hydraulic conductivity (swelling pressure device), swelling pressure (swelling pressure device), unconfined compression strength (mechanical press), shear strength (triaxial cell) and retention properties (jar method). The following chemical/mineralogical properties (methods within brackets) were determined: anion analysis of water leachates (IC), chemical composition (ICP/AES+MS, EGA), cation exchange capacity (CEC, Cu-trien method) and exchangeable cations (exchange with NH4, ICPAES), mineralogical composition (XRD and FTIR), element distribution and microstructure (SEM and

  5. DNA Uptake by Transformable Bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Lacks, Sanford A.

    1999-03-31

    The various processes of DNA uptake by cells can be categorized as: viral DNA entry, conjugation, or transformation. Within each category, a variety of mechanisms have been found. However, considerable similarities occur among the different mechanisms of conjugation and, especially, transformation. All of these natural mechanisms of DNA transfer are quite elaborate and involve multiple protein components, as the case may be, of the virus, the donor cell, and the recipient cell. The mechanisms of viral infection and conjugation will be discussed mainly with respect to their relevance to transformation.

  6. DNA UPTAKE BY TRANSFORMABLE BACTERIA

    Energy Technology Data Exchange (ETDEWEB)

    LACKS,S.A.

    1999-09-07

    The various processes of DNA uptake by cells can be categorized as: viral DNA entry, conjugation, or transformation. Within each category, a variety of mechanisms have been found. However, considerable similarities occur among the different mechanisms of conjugation and, especially, transformation. All of these natural mechanisms of DNA transfer are quite elaborate and involve multiple protein components, as the case may be, of the virus, the donor cell, and the recipient cell. The mechanisms of viral infection and conjugation will be discussed mainly with respect to their relevance to transformation.

  7. Piezoelectric Transformers: An Historical Review

    Directory of Open Access Journals (Sweden)

    Alfredo Vazquez Carazo

    2016-04-01

    Full Text Available Piezoelectric transformers (PTs are solid-state devices that transform electrical energy into electrical energy by means of a mechanical vibration. These devices are manufactured using piezoelectric materials that are driven at resonance. With appropriate design and circuitry, it is possible to step up and step down the voltages between the input and output sections of the piezoelectric transformer, without making use of magnetic materials and obtaining excellent conversion efficiencies. The initial concept of a piezoelectric ceramic transformer was proposed by Charles A. Rosen in 1954. Since then, the evolution of piezoelectric transformers through history has been linked to the relevant work of some excellent researchers as well as to the evolution in materials, manufacturing processes, and driving circuit techniques. This paper summarizes the historical evolution of the technology.

  8. Sustainable transformation

    DEFF Research Database (Denmark)

    Andersen, Nicolai Bo

    This paper is about sustainable transformation with a particular focus on listed buildings. It is based on the notion that sustainability is not just a question of energy conditions, but also about the building being robust. Robust architecture means that the building can be maintained and rebuil...

  9. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad

    2008-01-01

    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  10. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad

    2010-01-01

    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  11. Superconducting transformer

    International Nuclear Information System (INIS)

    Murphy, J.H.

    1982-01-01

    A superconducting transformer having a winding arrangement that provides for current limitation when subjected to a current transient as well as more efficient utilization of radial spacing and winding insulation. Structural innovations disclosed include compressed conical shaped winding layers and a resistive matrix to promote rapid switching of current between parallel windings

  12. Transformation & Metamorphosis

    Science.gov (United States)

    Lott, Debra

    2009-01-01

    The sculptures of Canadian artist Brian Jungen are a great inspiration for a lesson on creating new forms. Jungen transforms found objects into unique creations without fully concealing their original form or purpose. Frank Stella's sculpture series, including "K.132,2007" made of stainless steel and spray paint, is another great example of…

  13. Transforming Society

    DEFF Research Database (Denmark)

    Enemark, Stig; Dahl Højgaard, Pia

    2017-01-01

    , was a result of transforming society from a feudal system to a capitalistic and market based economy. This story is interesting in itself - but it also provides a key to understanding the cadastral system of today. The system has evolved over time and now serves a whole range of functions in society. The paper...

  14. The global influence of dust mineralogical composition on heterogeneous ice nucleation in mixed-phase clouds

    International Nuclear Information System (INIS)

    Hoose, C; Lohmann, U; Erdin, R; Tegen, I

    2008-01-01

    Mineral dust is the dominant natural ice nucleating aerosol. Its ice nucleation efficiency depends on the mineralogical composition. We show the first sensitivity studies with a global climate model and a three-dimensional dust mineralogy. Results show that, depending on the dust mineralogical composition, coating with soluble material from anthropogenic sources can lead to quasi-deactivation of natural dust ice nuclei. This effect counteracts the increased cloud glaciation by anthropogenic black carbon particles. The resulting aerosol indirect effect through the glaciation of mixed-phase clouds by black carbon particles is small (+0.1 W m -2 in the shortwave top-of-the-atmosphere radiation in the northern hemisphere)

  15. Kaolin clays from Patagonia - Argentina. Relationship between the mineralogy and ceramic properties

    International Nuclear Information System (INIS)

    Factorovich, J.C.; Badino, D.; Cravero, F.; Dominguez, E.

    1997-01-01

    The mineralogy, grain size distribution, chemical composition, S and C contents, plasticity, and cationic exchange capacity are determined in the sedimentary kaolinitic clays from the clay pits Puma Negra, Puma Gris, Tincar Super; and Chenque and Cardenal located in Santa Cruz and Chubut Provinces. Mineralogy and Particle size distribution of > 5, 5-2 and <2μ fractions are determined. Modulus of rupture, 1100 and 1250 deg C shrinkage and water absorption and whiteness are found. It is accomplished a statistics correlation between the characteristics of grain size distribution, mineralogy, and other physical properties with the main ceramic properties to understand its influence in the ceramic process. (author)

  16. Mineralogy of an active eolian sediment from the Namib dune, Gale crater, Mars

    Science.gov (United States)

    Achilles, C. N.; Downs, R. T.; Ming, D. W.; Rampe, E. B.; Morris, R. V.; Treiman, A. H.; Morrison, S. M.; Blake, D. F.; Vaniman, D. T.; Ewing, R. C.; Chipera, S. J.; Yen, A. S.; Bristow, T. F.; Ehlmann, B. L.; Gellert, R.; Hazen, R. M.; Fendrich, K. V.; Craig, P. I.; Grotzinger, J. P.; Des Marais, D. J.; Farmer, J. D.; Sarrazin, P. C.; Morookian, J. M.

    2017-11-01

    The Mars Science Laboratory rover, Curiosity, is using a comprehensive scientific payload to explore rocks and soils in Gale crater, Mars. Recent investigations of the Bagnold Dune Field provided the first in situ assessment of an active dune on Mars. The Chemistry and Mineralogy (CheMin) X-ray diffraction instrument on Curiosity performed quantitative mineralogical analyses of the history of the dune material and offers an important opportunity for ground truth of orbital observations. CheMin's analysis of the mineralogy and phase chemistry of modern and ancient Gale crater dune fields, together with other measurements by Curiosity's science payload, provides new insights into present and past eolian processes on Mars.

  17. Kinetics of Cs adsorption on soils with different mineralogical composition

    International Nuclear Information System (INIS)

    Nakao, Atsushi; Funakawa, Shinya; Kosaki, Takashi

    2004-01-01

    137 Cs is one of the main radioisotopes released into the environment by nuclear powerstation accidents (e.g. Chernobyl) and nuclear weapons tests. Many studies have shown that Cs tends to remain at surface soils due to the high adsorption selectivity of clay minerals for this element. This behavior of the Cs + ion is, however, assumed to vary significantly depending on the mineralogical composition of the soil. The main objective of this study is to analyze the kinetics of Cs adsorption on soils with different mineralogical composition. Soil samples used in this study were Mollisols (Um) and Alfisols (Ua) from Ukraine, Ultisols (Tu) from Thailand and Spodosols (Js) from Japan. The dominant clay species of these soils are montmorillonite (Um, Ua), kaolinite and mica (Tu) and beidellite (Js). The rates of Cs adsorption and Ca or K desorption were measured using a continuous flow method. Soil samples that were previously saturated with Ca 2+ were leached with a 0.75 mmol/l Cs + solution at a constant rate of 2.0 ml/min. The leachate was collected every 10 minutes and the concentrations of Cs + , Ca 2+ and K + of each aliquot were measured by atomic adsorption spectrophotometry (Cs + , Ca 2+ ) and flame spectrophotometry (K + ). The datasets obtained were simulated using the first order kinetic model: y = a(1 - exp(-kt)), where a is the adsorption (desorption) maximum and k the rate constant. It is here assumed that Ca 2+ is desorbed from cation exchange sites and K + desorbed from the frayed edges of micaceous minerals. The values of a obtained for both Cs adsorption and Ca desorption was in the order Js>Um>Tu>Ua, whereas the values of k were in the order Tu>Ua>Um>Js. This result reflects the values of permanent negative charge of clays which are originated from the substitution of cations in the structure of 2:1 clay minerals. The value of a for K + desorption was, however, highest in Tu, suggesting that the values of Cs + -exchangeable K + correspond to the amount

  18. Mineralogy of the Chaparra IOCG deposit, southern Peru

    Science.gov (United States)

    Yáñez, Juan; Alfonso, Pura

    2014-05-01

    The Chaparra IOCG, located in southern Peru, near Chala, is mined and exploited by small-scale miners for gold, however, it has not been studied until now. Here we present a preliminary geological and mineralogic study of this deposit. Powder X ray diffraction, electron microscopy and electron microprobe were used to characterize the mineralization. This deposit is hosted in magmatic rocks from the Coastal Batholith. Host rocks belong to the Linga Super-unit, of Upper Cretaceous age and are mainly constituted by monzonites, monzogabbros and diorites. Major alterations are the propylitic (chlorite - albite - quartz), advanced argillic (jarosite - natrojarosite) and sericitic (muscovite-sericite-quartz). Gypsum and other alteration minerals such as potassium feldspar and phlogopite, vermiculite and natrolite are widespread. Mineralization occurs mainly in quartz veins up to 1 m thick, emplaced filling fractures. Ore mineralogy is mainly composed of hematite, goethite, and sulphides (mainly pyrite, chalcopyrite and covellite). Gold and REE-rich minerals also occur. Native gold can reach up to 1 mm in size, but usually is few μm in size. Its composition is 82-92 wt% Au, up to 12 wt% of Ag and Fe can reach up to 4 wt%. The paragenetic sequence in the Chaparra deposit was divided into three stages: (I) primary mineralization, (II) Fracture filling, and (III) supergene alteration. The sequence begins with the crystallization of magnetite, quartz, pyrrhotite and pyrite. Subsequently, native gold, native Bismuth and uraninite crystallices together with the former minerals, in which are enclosed. Later, monacite is formed, being enclosed in quartz. Pyrite also presents small grains of chalcopyrite inside. Galena, sphalerite and arsenopyrite also are formed, whether included in pyrite or outside. Scarce grains of sakuraiite also occur in this stage. Structural formula of sakuraiie from this deposit is Cu 01.78-1.90 Zn 0.07-12Fe 1.16-124In 0.22-0.26Sn 0.79-082S4). Indium

  19. Ancient mortars from Cape Verde: mineralogical and physical characterization

    Science.gov (United States)

    Rocha, Fernando; Costa, Cristiana; Velosa, Ana; Quintela, Ana; Terroso, Denise; Marques, Vera

    2014-05-01

    Times and locations of different building constructions means different knowledge, habits, different construction methods and materials. The study and safeguarding of the architectural heritage takes nowadays a progressive importance as a vehicle for transmission of cultures and history of nations. The coatings are of great importance in the durability of a building due to the protective role of the masonry. The compatibility between the materials with which they are executed (masonry, mortar and grout settlement) promotes the proper functioning of the wall and a consequent increase in durability. Therefore, it becomes important to study and characterize the mortar coating of buildings to know its characteristics and to use compatible materials in the rehabilitation and maintenance of buildings. This study aims to characterize the chemical, physical, mechanical and mineralogical mortar samples collected in buildings in three islands of Cape Verde, for the conservation, rehabilitation and preservation of them. The collected samples belong to buildings constructed in the end of XIX century and in the beginning of XX century. In order to characterize the mortar samples some tests was made, such as X-Ray Diffraction, X- Ray Fluorescence, acid attack and mechanical strength. The samples were divided into three groups depending on origin; so we have a first group collected on the island of Santiago, the second on the island of Saint Vincent and the third on the island of Santo Antao. The samples are all carbonated, but Santiago samples have a lower carbonates content. In terms of insoluble residue (from the acid attack) it was concluded that the samples have similar value ranging from 9 to 26%. The compressive strength of the mortars have a range between 1.36 and 4.55 MPa, which is related to the presence of more binder in samples with higher resistance. The chemical and mineralogical analyzes showed that these consist of lime mortars (binder), natural pozzolan and

  20. Mid-IR Reflectance (DRIFT) Spectral Variations in Basaltic Mineralogy with Direction of Impact at Lonar Crater, India

    Science.gov (United States)

    Basavaiah, N.; Chavan, R. S.; Arif, M.

    2012-12-01

    Identification of spectral changes with the direction of impact has important implications for understanding the impact cratering phenomenon occurring on both terrestrial and extraterrestrial planets and also for geology of the crater. Fortuitously, Lonar Impact Crater (India) is the only well-preserved terrestrial simple crater excavated on Deccan basalts and serves as an excellent analogue to craters on Mars and Moon. An ~570 ka old Lonar crater was suggested to be formed by an oblique impact of a chondritic impactor that struck the pre-impact target from the east into a sequence of six basaltic Deccan flows and created a 1.88 km diameter crater with two layers of ejecta blanket. Here we report preliminary laboratory studies of spectral results on fine-grained rock powers (IR (4000-400 cm-1) Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy. The basalts were collected from two profiles in the east and south sections of the crater wall and the upper most crater rim, which later subdivided into sector-wise samples to carry out a systematic study of spectral properties of Lonar basalts, together with impact related samples of breccias and impact melts. For the first time, data of the shock metamorphism of Lonar basalt is examined using DRIFT spectroscopy. Infrared spectra of rock powders of relatively unshocked and shocked basalts are obtained to document the mineralogical variations and the distribution of primary (e.g. Plagioclase Feldspar, Pyroxene), and secondary Phyllosilicate minerals (e.g. Illite, Smectite, Montmorillonite, Saponite, Serpentine) with direction of impact. The spectral data between pre-impact unshocked and post-impact shocked basalts are interpreted to reflect the effect of shock pressure and alteration that rock have undergone. On western crater rim sector, typical silicate spectral features in 900-1200 cm-1 which attributed to Si-O stretching, are observed to change slightly in the width and shift in position as a result of

  1. Culturally Relevant Cyberbullying Prevention

    OpenAIRE

    Phillips, Gregory John

    2017-01-01

    In this action research study, I, along with a student intervention committee of 14 members, developed a cyberbullying intervention for a large urban high school on the west coast. This high school contained a predominantly African American student population. I aimed to discover culturally relevant cyberbullying prevention strategies for African American students. The intervention committee selected video safety messages featuring African American actors as the most culturally relevant cyber...

  2. Mineralogy and microstructure of sintered lignite coal fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Marina Ilic; Christopher Cheeseman; Christopher Sollars; Jonathan Knight [Faculty of Technology and Metallurgy, Belgrade (Yugoslavia)

    2003-02-01

    Lignite coal fly ash from the 'Nikola Tesla' power plant in Yugoslavia has been characterised, milled, compacted and sintered to form monolithic ceramic materials. The effect of firing at temperatures between 1130 and 1190{sup o}C on the density, water accessible porosity, mineralogy and microstructure of sintered samples is reported. This class C fly ash has an initial average particle size of 82 {mu}m and contains siliceous glass together with the crystalline phases quartz, anorthite, gehlenite, hematite and mullite. Milling the ash to an average particle size of 5.6 m, compacting and firing at 1170{sup o}C for 1 h produces materials with densities similar to clay-based ceramics that exhibit low water absorption. Sintering reduces the amount of glass, quartz, gehlenite and anhydrite, but increases formation of anorthite, mullite, hematite and cristobalite. SEM confirms the formation of a dense ceramic at 1170{sup o}C and indicates that pyroplastic effects cause pore formation and bloating at 1190{sup o}C. 23 refs., 6 figs., 2 tabs.

  3. Surface Mineralogy Mapping of Ceres from the Dawn Mission

    Science.gov (United States)

    McCord, T. B.; Zambon, F.

    2017-12-01

    Ceres' surface composition is of special interest because it is a window into the interior state and the past evolution of this dwarf planet. Disk-integrated telescopic spectral observations indicated that Ceres' surface is hydroxylated, similar to but not exactly the same as some of the carbonaceous chondrite classes of meteorites. Furthermore, Ceres' bulk density is low, indicating significant water content. The Dawn mission in orbit around Ceres, provided a new and larger set of observations on the mineralogy, molecular and elemental composition, and their distributions in association with surface features and geology. A set of articles was prepared, from which this presentation is derived, that is the first treatment of the entire surface composition of Ceres using the complete High Altitude Mapping Orbit (HAMO) Dawn Ceres data set and the calibrations from all the Dawn instruments. This report provides a current and comprehensive view of Ceres' surface composition and integrates them into general conclusions. Ceres' surface composition shows a fairly uniform distribution of NH4- and Mg-phyllosilicates, carbonates, mixed with a dark component. The widespread presence of phyllosilicates, and salts on Ceres' surface is indicative of the presence of aqueous alteration processes, which involved the whole dwarf planet. There is also likely some contamination by low velocity infall, as seen on Vesta, but it is more difficult to distinguish this infall from native Ceres material, unlike for the Vesta case.

  4. MMA-EoS: A Computational Framework for Mineralogical Thermodynamics

    Science.gov (United States)

    Chust, T. C.; Steinle-Neumann, G.; Dolejš, D.; Schuberth, B. S. A.; Bunge, H.-P.

    2017-12-01

    We present a newly developed software framework, MMA-EoS, that evaluates phase equilibria and thermodynamic properties of multicomponent systems by Gibbs energy minimization, with application to mantle petrology. The code is versatile in terms of the equation-of-state and mixing properties and allows for the computation of properties of single phases, solution phases, and multiphase aggregates. Currently, the open program distribution contains equation-of-state formulations widely used, that is, Caloric-Murnaghan, Caloric-Modified-Tait, and Birch-Murnaghan-Mie-Grüneisen-Debye models, with published databases included. Through its modular design and easily scripted database, MMA-EoS can readily be extended with new formulations of equations-of-state and changes or extensions to thermodynamic data sets. We demonstrate the application of the program by reproducing and comparing physical properties of mantle phases and assemblages with previously published work and experimental data, successively increasing complexity, up to computing phase equilibria of six-component compositions. Chemically complex systems allow us to trace the budget of minor chemical components in order to explore whether they lead to the formation of new phases or extend stability fields of existing ones. Self-consistently computed thermophysical properties for a homogeneous mantle and a mechanical mixture of slab lithologies show no discernible differences that require a heterogeneous mantle structure as has been suggested previously. Such examples illustrate how thermodynamics of mantle mineralogy can advance the study of Earth's interior.

  5. Iron Mineralogy and Uranium-Binding Environment in the ...

    Science.gov (United States)

    Wetlands mitigate the migration of groundwater contaminants through a series of biogeochemical gradients that enhance multiple contaminant-binding processes. The hypothesis of this study was that wetland plant roots contribute organic carbon and release O2 within the rhizosphere (plant-impact soil zone) that promote the formation of Fe(III)-(oxyhydr)oxides. In turn, these Fe(III)-(oxyhydr)oxides stabilize organic matter that together contribute to contaminant immobilization. Mineralogy and U binding environments of the rhizosphere were evaluated in samples collected from contaminated and non-contaminated areas of a wetland on the Savannah River Site in South Carolina. Based on Mössbauer spectroscopy, rhizosphere soil was greatly enriched with nanogoethite, ferrihydrite-like nanoparticulates, and hematite, with negligible Fe(II) present. X-ray computed tomography and various microscopy techniques showed that root plaques were tens-of-microns thick and consisted of highly oriented Fe-nanoparticles, suggesting that the roots were involved in creating the biogeochemical conditions conducive to the nanoparticle formation. XAS showed that a majority of the U in the bulk wetland soil was in the +6 oxidation state and was not well correlated spatially to Fe concentrations. SEM/EDS confirm that U was enriched on root plaques, where it was always found in association with P. Together these findings support our hypothesis and suggest that plants can alter mineralo

  6. The Morro do Resende orthogneiss: mineralogy, petrography, geochemistry and geochronology

    International Nuclear Information System (INIS)

    Vasconcelos, Fabiana Franco de; Avila, Ciro Alexandre; Bongiolo, Everton Marques; Camara, Beatriz de Oliveira; Menezes, Victor Hugo Riboura; Cunha, Fernanda Caetano de Mattos; Neumann, Reiner; Teixeira, Wilson; Barbosa, Natali

    2017-01-01

    The Morro do Resende orthogneiss is a hololeucocratic to leucocratic, fine-grained body with monzogranitic to granodioritic composition, cropping out near the Volta Grande mine in Nazareno County, State of Minas Gerais, Brazil. It bears xenoliths of metamafic rocks of the Rio das Mortes metavolcano-sedimentary sequence and yields a U-Pb SHRIMP crystallization age of 2174 ± 4 Ma, relating it to one of the magmatic pulses of the Mineiro Belt. The primary mineralogy includes quartz, albite, microcline, biotite, allanite, zircon, magnetite, titanite and apatite, while sericite, epidote, zoisite, clinozoisite, carbonate and chlorite are metamorphic minerals. Maghemite, barite, fluorite, monazite, xenotime, garnet and REE fluorides (possibly gagarinite) are hydrothermal, as they fill the fractures, intergrow or replace the primary and metamorphic minerals. Fluid interaction was not homogeneous throughout the body. Metamorphic paragenesis points to greenschist facies conditions, which could be related to the Paleoproterozoic II event of the Mineiro Belt, which lasted from 2131 to 2101 Ma. The Morro do Resende orthogneiss is distinguished by significant REE enrichment, as well as a negative Eu anomaly linked to the magmatic crystallization and a negative Ce anomaly related to oxidizing hydrothermal fluids circulation. (author)

  7. The mineralogical characterization of tellurium in copper anodes

    Science.gov (United States)

    Chen, T. T.; Dutrizac, J. E.

    1993-12-01

    A mineralogical study of a «normal» commercial copper anode and six tellurium-rich copper anodes from the CCR Refinery of the Noranda Copper Smelting and Refining Company was carried out to identify the tellurium carriers and their relative abundances. In all the anodes, the major tellurium carrier is the Cu2Se-Cu2Te phase which occurs as a constituent of complex inclusions at the copper grain boundaries. In tellurium-rich anodes, the molar tellurium content of the Cu2Se-Cu2Te phase can exceed that of selenium. Although >85 pct of the tellurium occurs as the Cu2Se-Cu2Te phase, minor amounts are present in Cu-Pb-As-Bi-Sb oxide, Cu-Bi-As oxide, and Cu-Te-As oxide phases which form part of the grain-boundary inclusions. About 1 pct of the tellurium content of silver-rich anodes occurs in various silver alloys, but gold tellurides were never detected. Surprising is the fact that 2 to 8 pct of the total tellurium content of the anodes occurs in solid solution in the copper-metal matrix, and presumably, this form of tellurium dissolves at the anode interface during electrorefining.

  8. Discrete transforms

    CERN Document Server

    Firth, Jean M

    1992-01-01

    The analysis of signals and systems using transform methods is a very important aspect of the examination of processes and problems in an increasingly wide range of applications. Whereas the initial impetus in the development of methods appropriate for handling discrete sets of data occurred mainly in an electrical engineering context (for example in the design of digital filters), the same techniques are in use in such disciplines as cardiology, optics, speech analysis and management, as well as in other branches of science and engineering. This text is aimed at a readership whose mathematical background includes some acquaintance with complex numbers, linear differen­ tial equations, matrix algebra, and series. Specifically, a familiarity with Fourier series (in trigonometric and exponential forms) is assumed, and an exposure to the concept of a continuous integral transform is desirable. Such a background can be expected, for example, on completion of the first year of a science or engineering degree cour...

  9. XML Transformations

    Directory of Open Access Journals (Sweden)

    Felician ALECU

    2012-04-01

    Full Text Available XSLT style sheets are designed to transform the XML documents into something else. The two most popular parsers of the moment are the Document Object Model (DOM and the Simple API for XML (SAX. DOM is an official recommendation of the W3C (available at http://www.w3.org/TR/REC-DOM-Level-1, while SAX is a de facto standard. A good parser should be fast, space efficient, rich in functionality and easy to use.

  10. RF transformer

    Science.gov (United States)

    Smith, James L.; Helenberg, Harold W.; Kilsdonk, Dennis J.

    1979-01-01

    There is provided an improved RF transformer having a single-turn secondary of cylindrical shape and a coiled encapsulated primary contained within the secondary. The coil is tapered so that the narrowest separation between the primary and the secondary is at one end of the coil. The encapsulated primary is removable from the secondary so that a variety of different capacity primaries can be utilized with one secondary.

  11. Transformative Agency

    DEFF Research Database (Denmark)

    Majgaard, Klaus

    The purpose of this paper is to enhance the conceptual understanding of the mediatory relationship between paradoxes on an organizational and an individual level. It presents a concept of agency that comprises and mediates between a structural and individual pole. The constitution of this agency ...... is achieved through narrative activity that oscillates between the poles and transforms paradoxes through the configuration of plots and metaphors. Empirical cases are introduced in order to illustrate the implications of this understanding....

  12. Mineralogical Composition of the Mexican Ordinary Chondrite Type Meteorite: A Raman, Infrared and XRD Study

    Science.gov (United States)

    Ostrooumov, M.

    2016-08-01

    The Raman microprobe (RMP), infrared (IR) and XRD analysis have been applied to the examination of mineralogical composition of seven mexican meteorites: Aldama, Cosina, El Pozo, Escalon, Nuevo Mercurio,Pacula, Zapotitlan Salinas.

  13. X-Ray Diffraction and Fluorescence Instrument for Mineralogical Analysis at the Lunar Surface, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop LUNA, a compact and lightweight X-Ray Diffraction (XRD) / X-Ray Fluorescence (XRF) instrument for mineralogical analysis of regolith, rock...

  14. X-Ray Diffraction and Fluorescence Instrument for Mineralogical Analysis at the Lunar Surface, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a compact and lightweight X-Ray Diffraction (XRD) / X-Ray Fluorescence (XRF) instrument for analysis of mineralogical composition of regolith,...

  15. Slags and ashes from municipal waste incineration in Poland - mineralogical and chemical composition

    Science.gov (United States)

    Kowalski, Piotr; Michalik, Marek

    2013-04-01

    In the next few years there will be a large change in the waste management system in Poland. Its primary aim will be reduction of the amount of landfilled waste by enhancing level of recycling, waste segregation, composting of biomass and incineration. The biggest investment during this transformation is construction of nine incinerators with assumed slags production around 200 thousand tons per year. Slag production is accompanied by fly ash generating. This ash can be a valuable raw material as fly ash from the power industry. Waste management system transformation will cause big increase in slag production in comparison to the present amount and will require taking necessary steps to ensure environmental safety. For this purpose, studies of slags and fly ashes in terms of environmental risk and potential impact on human health are significant. The object of the study are fly ashes and slags produced in the biggest municipal waste incineration power plant in Poland. Two series of samples obtained in municipal waste incineration process were studied in order to characterize mineralogical and chemical composition and to determine the concentrations of heavy metals and their possible negative environmental impact. Characteristics of these materials will be the basis for determining their value in application, for example in building industry. Mineralogical characteristic of slags was based on X-ray diffraction. Characteristic of structures and forms of occurrence of mineral phases was based on the optical microscopy and SEM imaging coupled with EDS analysis. Chemical analysis were performed using ICP-MS/ICP-AES methods. They allowed to follow variability between studied samples and gave basic information about metals. Metals in samples of slag and ashes are present as component of mineral phases and in the form of metallic inclusions in glass or minerals. Potentially hazardous concentrations for environment are observed for copper (330-4900ppm), zinc (1500-8100ppm

  16. Processing of copper converter slag for metals reclamation: Part II: mineralogical study.

    Science.gov (United States)

    Deng, Tong; Ling, Yunhan

    2004-10-01

    Chemical and mineralogical characterizations of a copper converter slag, and its products obtained by curing with strong sulphuric acid and leaching with hot water, were carried out using ore microscopy, scanning electronic microscopy with energy dispersive spectrometry, wave-length dispersive X-ray fluorescence spectrometry, X-ray diffractometry and chemical phase analysis, which provided necessary information to develop a new process for treating such slag and further understanding of the chemical and mineralogical changes in the process.

  17. Skeletal mineralogy of coral recruits under high temperature and pCO2

    Directory of Open Access Journals (Sweden)

    T. Foster

    2016-03-01

    Our results show that elevated pCO2 alone is unlikely to drive changes in the skeletal mineralogy of young corals. Not having an ability to switch from aragonite to calcite precipitation may leave corals and ultimately coral reef ecosystems more susceptible to predicted ocean acidification. An important area for prospective research would be the investigation of the combined impact of high pCO2 and reduced Mg ∕ Ca ratio on coral skeletal mineralogy.

  18. Kaolin from Acoculco (Puebla, Mexico) as a raw material: mineralogical and thermal characterization

    OpenAIRE

    Garcia Vallès, Maite; Pi, T.; Alfonso, P.; Canet, C.; Martínez Manent, Salvador; Jiménez-Franco, A.; Tarragó Aymerich, Mariona; Hernández-Cruz, B.

    2015-01-01

    The present study determined the mineralogy and thermal properties of kaolin from Acoculco (Puebla), at the eastern Trans-Mexican Volcanic Belt and compared it with the nearby deposits of Agua Blanca (Hidalgo) and Huayacocotla (Veracruz). The mineralogy of the kaolins was determined by X-ray diffraction, infrared spectroscopy and scanning electron microscopy. Thermal behaviour was studied by differential thermal analysis, dilatometry and hot-stage microscopy. The Acoculco deposit is composed ...

  19. Mineralogy and Oxygen Isotope Compositions of an Unusual Hibonite-Perovskite Refractory Inclusion from Allende

    Science.gov (United States)

    Keller, L. P.; Snead, C.; Rahman, Z.; McKeegan, K. D.

    2012-01-01

    Hibonite-rich Ca- and Al-rich inclusions (CAIs) are among the earliest formed solids that condensed in the early nebula. We discovered an unusual refractory inclusion from the Allende CV3 chondrite (SHAL) containing an approx 500 micron long single crystal of hibonite and co-existing coarse-grained perovskite. The mineralogy and petrography of SHAL show strong similarities to some FUN inclusions, especially HAL. Here we report on the mineralogy, petrography, mineral chemistry and oxygen isotopic compositions in SHAL.

  20. Qualitative characterization by x-ray diffraction from soils: mineralogy conditions to benefit the environment

    International Nuclear Information System (INIS)

    Fujiyama, Bruna Sayuri; Tavares, Mauricio de Moraes

    2010-01-01

    Four samples were collected from four soil profiles located in the Rural Federal University of Amazonia. These, were analyzed parameters such as color, texture, consistency, granulometry, porosity and water absorption. We identified the following soil types: Distrofic Yellow Latosoil; Lateritic Concretionary; distrofic Low Humic Gley. The work was to continue the qualitative analysis by X-rays diffraction, identifying the mineralogical composition of each sample. Explaining the mineralogical conditions that affect or benefit the environment. (author)

  1. Mini-review: The Morphology, Mineralogy and Microbiology of Accumulated Iron Corrosion Products

    Science.gov (United States)

    2014-03-11

    including the morphology, mineralogy , microbiology and the mecha- nisms for formation. Use of descriptive terms to denote specific iron corrosion product...RESPONSIBLE PERSON 19b. TELEPHONE NUMBER (Include area code) 11-03-2014 Journal Article Mini-review: the morphology, mineralogy and microbiology of...oxides/ hydroxides with a preponderance of α-FeOOH (goethite) and accumulation of metals. Bacteria, particularly iron-oxidizing and sulfatereducing

  2. Technical characterization by image analysis: an automatic method of mineralogical studies

    International Nuclear Information System (INIS)

    Oliveira, J.F. de

    1988-01-01

    The application of a modern method of image analysis fully automated for the study of grain size distribution modal assays, degree of liberation and mineralogical associations is discussed. The image analyser is interfaced with a scanning electron microscope and an energy dispersive X-rays analyser. The image generated by backscattered electrons is analysed automatically and the system has been used in accessment studies of applied mineralogy as well as in process control in the mining industry. (author) [pt

  3. Nano-mineralogy of suspended sediment during the beginning of coal rejects spill.

    Science.gov (United States)

    Civeira, Matheus S; Ramos, Claudete G; Oliveira, Marcos L S; Kautzmann, Rubens M; Taffarel, Silvio R; Teixeira, Elba C; Silva, Luis F O

    2016-02-01

    Ultrafine and nanometric sediment inputs into river systems can be a major source of nutrients and hazardous elements and have a strong impact on water quality and ecosystem functions of rivers and lakes regions. However, little is known to date about the spatial distribution of sediment sources in most large scale river basins in South America. The objective of this work was to study the coal cleaning rejects (CCRs) spill that occurred from a CCRs impoundment pond into the Tubarão River, South Brazil, provided a unique occasion to study the importance and role of incidental nanoparticles associated with pollutant dispersal from a large-scale, acute aquatic pollution event. Multifaceted geochemical research by X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/(Energy Dispersive Spectroscopy) EDS/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM)/EDS, and Raman spectroscopy, provided an in-depth understanding of importance of a nano-mineralogy approach of Aqueous Pollution Scenarios. The electron beam studies showed the presence of a number of potentially hazardous elements (PHEs) in nanoparticles (amorphous and minerals). Some of the neoformed ultrafine/nanoparticles found in the contaminated sediments are the same as those commonly associated with oxidation/transformation of oxides, silicates, sulfides, and sulfates. These data of the secondary ultra/nanoparticles, puts in evidence their ability to control the mobility of PHEs, suggesting possible presentations in environmental technology, including recuperation of sensitive coal mine. The developed methodology facilitated the sediment transport of the catchment providing consistent results and suggesting its usefulness as a tool for temporary rivers management. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Environmental mineralogy - Understanding element behavior in ecosystems; Mineralogie environnementale: comprendre le comportement des elements dans les ecosystemes

    Energy Technology Data Exchange (ETDEWEB)

    Brown Jr, G.E. [Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115 (United States); Department of Photon Science and Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA 94025 (United States); Calas, G. [Institut de mineralogie et de physique des milieux condenses (IMPMC), universite Paris-6 - universite Paris-7, IPGP, CNRS, case 115, 75252 Paris (France)

    2011-02-15

    Environmental Mineralogy has developed over the past decade in response to the recognition that minerals are linked in many important ways with the global ecosystem. Minerals are the main repositories of the chemical elements in Earth's crust and thus are the main sources of elements needed for the development of civilization, contaminant and pollutant elements that impact global and local ecosystems, and elements that are essential plant nutrients. These elements are released from minerals through natural processes, such as chemical weathering, and anthropogenic activities, such as mining and energy production, agriculture and industrial activities, and careless waste disposal. Minerals also play key roles in the biogeochemical cycling of the elements, sequestering elements and releasing them as the primary minerals in crustal rocks undergo various structural and compositional transformations in response to physical, chemical, and biological processes that produce secondary minerals and soils. These processes have resulted in the release of toxic elements such as arsenic in groundwater aquifers, which is having a major impact on the health of millions of people in South and Southeast Asia. The interfaces between mineral surfaces and aqueous solutions are the locations of most chemical reactions that control the composition of the natural environment, including the composition of natural waters. The nuclear fuel cycle, from uranium mining to the disposition of high-level nuclear waste, is also intimately related to minerals. A fundamental understanding of these processes requires molecular-scale information about minerals, their bulk structures and properties such as solubility, their surfaces, and their interactions with aqueous solutions, atmospheric and soil gases, natural organic matter, and biological organisms. Gaining this understanding is further complicated by the presence of natural, incidental, and manufactured nano-particles in the environment

  5. Electrical transformer handbook

    Energy Technology Data Exchange (ETDEWEB)

    Hurst, R.W.; Horne, D. (eds.)

    2005-07-01

    This handbook is a valuable user guide intended for electrical engineering and maintenance personnel, electrical contractors and electrical engineering students. It provides current information on techniques and technologies that can help extend the life of transformers. It discusses transformer testing, monitoring, design, commissioning, retrofitting and other elements involved in keeping electrical transformers in safe and efficient operation. It demonstrates how a power transformer can be put to use and common problems faced by owners. In addition to covering control techniques, testing and maintenance procedures, this handbook covers the power transformer; control electrical power transformer; electrical power transformer; electrical theory transformer; used electrical transformer; down electrical step transformer; electrical manufacturer transformer; electrical picture transformer; electrical transformer work; electrical surplus transformer; current transformer; step down transformer; voltage transformer; step up transformer; isolation transformer; low voltage transformer; toroidal transformer; high voltage transformer; and control power transformer. The handbook includes articles from leading experts on overcurrent protection of transformers; ventilated dry-type transformers; metered load factors for low-voltage, and dry-type transformers in buildings. The maintenance of both dry-type or oil-filled transformers was discussed with reference to sealing, gaskets, oils, moisture and testing. The adoption of dynamic load practices was also discussed along with the reclamation or recycling of used lube oil, transformer dielectric fluids and aged solid insulation. A buyer's guide and directory of transformer manufacturers and suppliers was also included. refs., tabs., figs.

  6. The Limits to Relevance

    Science.gov (United States)

    Averill, M.; Briggle, A.

    2006-12-01

    Science policy and knowledge production lately have taken a pragmatic turn. Funding agencies increasingly are requiring scientists to explain the relevance of their work to society. This stems in part from mounting critiques of the "linear model" of knowledge production in which scientists operating according to their own interests or disciplinary standards are presumed to automatically produce knowledge that is of relevance outside of their narrow communities. Many contend that funded scientific research should be linked more directly to societal goals, which implies a shift in the kind of research that will be funded. While both authors support the concept of useful science, we question the exact meaning of "relevance" and the wisdom of allowing it to control research agendas. We hope to contribute to the conversation by thinking more critically about the meaning and limits of the term "relevance" and the trade-offs implicit in a narrow utilitarian approach. The paper will consider which interests tend to be privileged by an emphasis on relevance and address issues such as whose goals ought to be pursued and why, and who gets to decide. We will consider how relevance, narrowly construed, may actually limit the ultimate utility of scientific research. The paper also will reflect on the worthiness of research goals themselves and their relationship to a broader view of what it means to be human and to live in society. Just as there is more to being human than the pragmatic demands of daily life, there is more at issue with knowledge production than finding the most efficient ways to satisfy consumer preferences or fix near-term policy problems. We will conclude by calling for a balanced approach to funding research that addresses society's most pressing needs but also supports innovative research with less immediately apparent application.

  7. Hamlet's Transformation.

    Science.gov (United States)

    Usher, P. D.

    1997-12-01

    William Shakespeare's Hamlet has much evidence to suggest that the Bard was aware of the cosmological models of his time, specifically the geocentric bounded Ptolemaic and Tychonic models, and the infinite Diggesian. Moreover, Shakespeare describes how the Ptolemaic model is to be transformed to the Diggesian. Hamlet's "transformation" is the reason that Claudius, who personifies the Ptolemaic model, summons Rosencrantz and Guildenstern, who personify the Tychonic. Pantometria, written by Leonard Digges and his son Thomas in 1571, contains the first technical use of the word "transformation." At age thirty, Thomas Digges went on to propose his Perfit Description, as alluded to in Act Five where Hamlet's age is given as thirty. In Act Five as well, the words "bore" and "arms" refer to Thomas' vocation as muster-master and his scientific interest in ballistics. England's leading astronomer was also the father of the poet whose encomium introduced the First Folio of 1623. His oldest child Dudley became a member of the Virginia Company and facilitated the writing of The Tempest. Taken as a whole, such manifold connections to Thomas Digges support Hotson's contention that Shakespeare knew the Digges family. Rosencrantz and Guildenstern in Hamlet bear Danish names because they personify the Danish model, while the king's name is latinized like that of Claudius Ptolemaeus. The reason Shakespeare anglicized "Amleth" to "Hamlet" was because he saw a parallel between Book Three of Saxo Grammaticus and the eventual triumph of the Diggesian model. But Shakespeare eschewed Book Four, creating this particular ending from an infinity of other possibilities because it "suited his purpose," viz. to celebrate the concept of a boundless universe of stars like the Sun.

  8. Relevant Subspace Clustering

    DEFF Research Database (Denmark)

    Müller, Emmanuel; Assent, Ira; Günnemann, Stephan

    2009-01-01

    Subspace clustering aims at detecting clusters in any subspace projection of a high dimensional space. As the number of possible subspace projections is exponential in the number of dimensions, the result is often tremendously large. Recent approaches fail to reduce results to relevant subspace...... clusters. Their results are typically highly redundant, i.e. many clusters are detected multiple times in several projections. In this work, we propose a novel model for relevant subspace clustering (RESCU). We present a global optimization which detects the most interesting non-redundant subspace clusters...... achieves top clustering quality while competing approaches show greatly varying performance....

  9. TRANSFORMER APPARATUS

    Science.gov (United States)

    Wolfgang, F.; Nicol, J.

    1962-11-01

    Transformer apparatus is designed for measuring the amount of a paramagnetic substance dissolved or suspended in a diamagnetic liquid. The apparatus consists of a cluster of tubes, some of which are closed and have sealed within the diamagnetic substance without any of the paramagnetic material. The remaining tubes are open to flow of the mix- ture. Primary and secondary conductors are wrapped around the tubes in such a way as to cancel noise components and also to produce a differential signal on the secondaries based upon variations of the content of the paramagnetic material. (AEC)

  10. Rotary Transformer

    Science.gov (United States)

    McLyman, Colonel Wm. T.

    1996-01-01

    None given. From first Par: Many spacecraft (S/C) and surface rovers require the transfer of signals and power across rotating interfaces. Science instruments, antennas and solar arrays are elements needing rotary power transfer for certain (S/C) configurations. Delivery of signal and power has mainly been done by using the simplest means, the slip ring approach. This approach, although simple, leaves debris generating noise over a period of time...The rotary transformer is a good alternative to slip rings for signal and power transfer.

  11. Timescales of carbon turnover in soils with mixed crystalline mineralogies

    Science.gov (United States)

    Khomo, Lesego; Trumbore, Susan E.; Bern, Carleton R.; Chadwick, Oliver A.

    2017-01-01

    Organic matter–mineral associations stabilize much of the carbon (C) stored globally in soils. Metastable short-range-order (SRO) minerals such as allophane and ferrihydrite provide one mechanism for long-term stabilization of organic matter in young soil. However, in soils with few SRO minerals and a predominance of crystalline aluminosilicate or Fe (and Al) oxyhydroxide, C turnover should be governed by chemisorption with those minerals. Here, we correlate mineral composition from soils containing small amounts of SRO minerals with mean turnover time (TT) of C estimated from radiocarbon (14C) in bulk soil, free light fraction and mineral-associated organic matter. We varied the mineral amount and composition by sampling ancient soils formed on different lithologies in arid to subhumid climates in Kruger National Park (KNP), South Africa. Mineral contents in bulk soils were assessed using chemical extractions to quantify Fe oxyhydroxides and SRO minerals. Because of our interest in the role of silicate clay mineralogy, particularly smectite (2 : 1) and kaolinite (1 : 1), we separately quantified the mineralogy of the clay-sized fraction using X-ray diffraction (XRD) and measured 14C on the same fraction. Density separation demonstrated that mineral associated C accounted for 40–70 % of bulk soil organic C in A and B1 horizons for granite, nephelinite and arid-zone gabbro soils, and > 80 % in other soils. Organic matter strongly associated with the isolated clay-sized fraction represented only 9–47 % of the bulk soil C. The mean TT of C strongly associated with the clay-sized fraction increased with the amount of smectite (2 : 1 clays); in samples with > 40 % smectite it averaged 1020 ± 460 years. The C not strongly associated with clay-sized minerals, including a combination of low-density C, the C associated with minerals of sizes between 2 µm and 2 cm (including Fe oxyhydroxides as coatings), and C removed from clay

  12. Clay mineralogy in different geomorphic surfaces in sugarcane areas

    Science.gov (United States)

    Camargo, L.; Marques, J., Jr.

    2012-04-01

    The crystallization of the oxides and hydroxides of iron and aluminum and kaolinite of clay fraction is the result of pedogenetic processes controlled by the relief. These minerals have influence on the physical and chemical attributes of soil and exhibit spatial dependence. The pattern of spatial distribution is influenced by forms of relief as the geomorphic surfaces. In this sense, the studies aimed at understanding the relationship between relief and the distribution pattern of the clay fraction attributes contribute to the delineation of specific areas of management in the field. The objective of this study was to evaluate the spatial distribution of oxides and hydroxides of iron and aluminum and kaolinite of clay fraction and its relationship with the physical and chemical attributes in different geomorphic surfaces. Soil samples were collected in a transect each 25 m (100 samples) and in the sides of the same (200 samples) as well as an area of 500 ha (1 sample each six hectare). Geomorphic surfaces (GS) in the transect were mapped in detail to support mapping the entire area. The soil samples were taken to the laboratory for chemical, physical, and mineralogical analysis, and the pattern of spatial distribution of soil attributes was obtained by statistics and geostatistics. The GS I is considered the oldest surface of the study area, with depositional character, and a slope ranging from 0 to 4%. GS II and III are considered to be eroded, and the surface II plan a gentle slope that extends from the edge of the surface until the beginning of I and III. The crystallographic characteristics of the oxides and hydroxides of iron and aluminum and kaolinite showed spatial dependence and the distribution pattern corresponding to the limits present of the GS in the field. Surfaces I and II showed the best environments to the degree of crystallinity of hematite and the surface III to the greatest degree of crystallinity of goethite agreeing to the pedoenvironment

  13. Timescales of carbon turnover in soils with mixed crystalline mineralogies

    Science.gov (United States)

    Khomo, Lesego; Trumbore, Susan; Bern, Carleton R.; Chadwick, Oliver A.

    2017-01-01

    Organic matter-mineral associations stabilize much of the carbon (C) stored globally in soils. Metastable short-range-order (SRO) minerals such as allophane and ferrihydrite provide one mechanism for long-term stabilization of organic matter in young soil. However, in soils with few SRO minerals and a predominance of crystalline aluminosilicate or Fe (and Al) oxyhydroxide, C turnover should be governed by chemisorption with those minerals. Here, we correlate mineral composition from soils containing small amounts of SRO minerals with mean turnover time (TT) of C estimated from radiocarbon (14C) in bulk soil, free light fraction and mineral-associated organic matter. We varied the mineral amount and composition by sampling ancient soils formed on different lithologies in arid to subhumid climates in Kruger National Park (KNP), South Africa. Mineral contents in bulk soils were assessed using chemical extractions to quantify Fe oxyhydroxides and SRO minerals. Because of our interest in the role of silicate clay mineralogy, particularly smectite (2 : 1) and kaolinite (1 : 1), we separately quantified the mineralogy of the clay-sized fraction using X-ray diffraction (XRD) and measured 14C on the same fraction. Density separation demonstrated that mineral associated C accounted for 40-70 % of bulk soil organic C in A and B1 horizons for granite, nephelinite and arid-zone gabbro soils, and > 80 % in other soils. Organic matter strongly associated with the isolated clay-sized fraction represented only 9-47 % of the bulk soil C. The mean TT of C strongly associated with the clay-sized fraction increased with the amount of smectite (2 : 1 clays); in samples with > 40 % smectite it averaged 1020 ± 460 years. The C not strongly associated with clay-sized minerals, including a combination of low-density C, the C associated with minerals of sizes between 2 µm and 2 cm (including Fe oxyhydroxides as coatings), and C removed from clay-sized material by 2 % hydrogen peroxide had

  14. Clay mineralogy and magnetic susceptibility of Oxisols in geomorphic surfaces

    Directory of Open Access Journals (Sweden)

    Livia Arantes Camargo

    2014-06-01

    Full Text Available Studies analyzing the variability of clay minerals and magnetic susceptibility provide data for the delineation of site-specific management areas since many of their attributes are important to agronomy and the environment. This study aimed to evaluate the spatial variability of clay minerals, magnetic susceptibility, adsorbed phosphorus and physical attributes in Oxisols of sandstones in different geomorphic surfaces. For that purpose, soil samples were collected every 25 m along a transect located within the area where the geomorphic surfaces were identified and mapped. The transect occupied the central portion of 500 ha, where it was also sampled for density purposes with one sample per six hectares. Soil samples were collected at a depth of 0.0-0.2 m. The results of the physical, chemical, mineralogical and magnetic susceptibility analyses were subjected to statistical and geostatistical analyses. The nature of the clay minerals and magnetic susceptibility was dependent on the variation of the soil parent material. High values of magnetic susceptibility were associated with the presence of maghemite and magnetite of coarse size. The spatial variability of crystallinity and the content of Fe oxides, as well as magnetic susceptibility, were dependent on the age of the geomorphic surfaces. The youngest surface had greater spatial variability of these attributes. The iron (goethite and hematite and aluminum (gibbsite oxides in the youngest geomorphic surface influenced the low values of soil density and high values of total pore volume, micropores and P adsorption. The characterization of the spatial variability of Fe oxides and susceptibility allowed for the delineation of homogeneous areas.

  15. Chemical-mineralogical characterisation of coarse recycled concrete aggregate

    International Nuclear Information System (INIS)

    Limbachiya, M.C.; Marrocchino, E.; Koulouris, A.

    2007-01-01

    The construction industry is now putting greater emphasis than ever before on increasing recycling and promoting more sustainable waste management practices. In keeping with this approach, many sectors of the industry have actively sought to encourage the use of recycled concrete aggregate (RCA) as an alternative to primary aggregates in concrete production. The results of a laboratory experimental programme aimed at establishing chemical and mineralogical characteristics of coarse RCA and its likely influence on concrete performance are reported in this paper. Commercially produced coarse RCA and natural aggregates (16-4 mm size fraction) were tested. Results of X-ray fluorescence (XRF) analyses showed that original source of RCA had a negligible effect on the major elements and a comparable chemical composition between recycled and natural aggregates. X-ray diffraction (XRD) analyses results indicated the presence of calcite, portlandite and minor peaks of muscovite/illite in recycled aggregates, although they were directly proportioned to their original composition. The influence of 30%, 50%, and 100% coarse RCA on the chemical composition of equal design strength concrete has been established, and its suitability for use in a concrete application has been assessed. In this work, coarse RCA was used as a direct replacement for natural gravel in concrete production. Test results indicated that up to 30% coarse RCA had no effect on the main three oxides (SiO 2 , Al 2 O 3 and CaO) of concrete, but thereafter there was a marginal decrease in SiO 2 and increase in Al 2 O 3 and CaO contents with increase in RCA content in the mix, reflecting the original constituent's composition

  16. Chemical-mineralogical characterisation of coarse recycled concrete aggregate.

    Science.gov (United States)

    Limbachiya, M C; Marrocchino, E; Koulouris, A

    2007-01-01

    The construction industry is now putting greater emphasis than ever before on increasing recycling and promoting more sustainable waste management practices. In keeping with this approach, many sectors of the industry have actively sought to encourage the use of recycled concrete aggregate (RCA) as an alternative to primary aggregates in concrete production. The results of a laboratory experimental programme aimed at establishing chemical and mineralogical characteristics of coarse RCA and its likely influence on concrete performance are reported in this paper. Commercially produced coarse RCA and natural aggregates (16-4 mm size fraction) were tested. Results of X-ray fluorescence (XRF) analyses showed that original source of RCA had a negligible effect on the major elements and a comparable chemical composition between recycled and natural aggregates. X-ray diffraction (XRD) analyses results indicated the presence of calcite, portlandite and minor peaks of muscovite/illite in recycled aggregates, although they were directly proportioned to their original composition. The influence of 30%, 50%, and 100% coarse RCA on the chemical composition of equal design strength concrete has been established, and its suitability for use in a concrete application has been assessed. In this work, coarse RCA was used as a direct replacement for natural gravel in concrete production. Test results indicated that up to 30% coarse RCA had no effect on the main three oxides (SiO2, Al2O3 and CaO) of concrete, but thereafter there was a marginal decrease in SiO2 and increase in Al2O3 and CaO contents with increase in RCA content in the mix, reflecting the original constituent's composition.

  17. Rare Mineralogy in Alkaline Ultramafic Rocks, Western Kentucky Fluorspar District

    Science.gov (United States)

    Anderson, W.

    2017-12-01

    The alkaline ultramafic intrusive dike complex in the Western Kentucky Fluorspar District contains unusual mineralogy that was derived from mantle magma sources. Lamprophyre and peridotite petrologic types occur in the district where altered fractionated peridotites are enriched in Rare Earth Elements (REE) and some lamprophyre facies are depleted in incompatible elements. Unusual minerals in dikes, determined by petrography and X-ray diffraction, include schorlomite and andradite titanium garnets, astrophyllite, spodumene, niobium rutile, wüstite, fluoro-tetraferriphlogopite, villiaumite, molybdenite, and fluocerite, a REE-bearing fluoride fluorescent mineral. Mixing of MVT sphalerite ore fluids accompanies a mid-stage igneous alteration and intrusion event consistent with paragenetic studies. The presence of lithium in the spodumene and fluoro-tetraferriphlogopite suggests a lithium phase in the mineral fluids, and the presence of enriched REE in dikes and fluorite mineralization suggest a metasomatic event. Several of these rare minerals have never been described in the fluorspar district, and their occurrence suggests deep mantle metasomatism. Several REE-bearing fluoride minerals occur in the dikes and in other worldwide occurrences, they are usually associated with nepheline syenite and carbonatite differentiates. There is an early and late stage fluoride mineralization, which accompanied dike intrusion and was also analyzed for REE content. One fluorite group is enriched in LREE and another in MREE, which suggests a bimodal or periodic fluorite emplacement. Whole-rock elemental analysis was chondrite normalized and indicates that some of the dikes are slightly enriched in light REE and show a classic fractionation enrichment. Variations in major-element content; high titanium, niobium, and zirconium values; and high La/Yb, Zr/Y, Zr/Hf, and Nb/Ta ratios suggest metasomatized lithospheric-asthenospheric mantle-sourced intrusions. The high La/Yb ratios in some

  18. Mineralogical and physico-chemical characterization of Mbodiene palygorskite for pharmaceutical applications

    Science.gov (United States)

    Sylla Gueye, Rokhaya; Davy, Catherine A.; Cazaux, Frédéric; Ndiaye, Augustin; Diop, Mouhamadou Bassir; Skoczylas, Frédéric; Wele, Alassane

    2017-11-01

    This contribution provides a wide morphological, mineralogical, chemical and physical characterization of Mbodiene palygorskite (Senegal), to serve as a basis for the formulation of antidiarrheal and cosmetic products. Data are compared with other palygorskite deposits, either in Senegal or on other continents. Qualitative total rock XRD, semi-quantitative XRD of the clay fraction and quantitative X-Ray fluorescence (XRF) show the presence of 72%wt palygorskite (±2%wt), 13%wt montmorillonite (±2%wt), 8%wt dolomite (±2%wt), 5%wt quartz SiO2 (±2%wt) and 2%wt inter-stratified illite/smectite (±2%wt). Coupled SEM + EDX and TEM + EDX confirm the presence of fibrous palygorskite, with greater amounts of Mg than Al, and Fe substitution to Mg and Al, interspersed with dolomite cubes CaMg(CO3)2. The presence of carbonates in Mbodiene palygorskite may limit its use in the Pharmacopoeia, and make its purification necessary. A specific signature of Mbodiene palygorskite, relevant to the palygorskite family, is deduced from both FTIR and TGA analysis. In terms of physico-chemical characterization, Mbodiene palygorskite has usual values when compared to the literature (for its specific surface area, specific gravity, compressibility and Haussner indexes, CEC, loss on ignition, etc.). After grinding (down to a peak grain size of 500 nm), Mbodiene palygorskite is considered a normal clay, extremely highly plastic, with hard consistency owing to the values of its Atterberg plasticity and liquidity limits, with good flowability owing to its compressibility and Haussner indexes. Its physical characteristics are suitable for manufacturing pastes and colloidal suspensions.

  19. Is Information Still Relevant?

    Science.gov (United States)

    Ma, Lia

    2013-01-01

    Introduction: The term "information" in information science does not share the characteristics of those of a nomenclature: it does not bear a generally accepted definition and it does not serve as the bases and assumptions for research studies. As the data deluge has arrived, is the concept of information still relevant for information…

  20. Mineralogy and environmental geochemistry of historical iron slag, Hopewell Furnace National Historic Site, Pennsylvania, USA

    Science.gov (United States)

    Piatak, Nadine; Seal, Robert

    2012-01-01

    compared to the other piles. In general, piles 1 and 2 are chemically similar to each other, whereas pile 3 is distinct – a conclusion that reflects their mineralogy. The similarities and differences among piles in terms of mineralogy and major element chemistry result from the different smelting conditions under which the slag formed and include the fuel source, the composition of the ore and flux, the type of blast (cold versus hot), which affects the furnace temperature, and other beneficiation methods.The three distinct slag piles at Hopewell are enriched in numerous trace elements, such as As (up to 12 mg/kg), Cd (up to 0.4 mg/kg), Co (up to 31.8 mg/kg), Cu (up to 647 mg/kg), Mn (up to 0.69 wt.%), Pb (up to 172 mg/kg) and Zn (up to 393 mg/kg), together with Fe (13.9 wt.%), when compared to the average for the continental crust, with the <2 mm-size fraction commonly containing the highest concentrations. Enrichments in various elements (e.g., Cd, Co, Cu, Pb, Zn) were also found in the ore samples. Despite these enrichments, comparison of bulk chemistry trace-element concentrations to the environmental guidelines suggests most elements are likely not problematic with the exception of As, Co, Fe and Mn. Leachate tests that simulate weathering indicate Fe (up to 973 μg/L) and Mn (up to 133 μg/L) are readily released in potentially harmful concentrations compared to secondary drinking water and some aquatic ecosystem toxicity criteria. Aluminum and Cu, although not high in the solid compared to environmental guidelines, also exceed relevant criteria in leachate extracts with maximum concentrations of 2700 μg/L and 17.7 μg/L, respectively. In contrast, As and Co, which are significant in the solids, are not leached in concentrations that exceed guidelines (i.e., 3 μg/L or less for both elements). The weathering rates of the Fe metal and Fe oxides, which host Cu and some Fe, are likely higher than the silicate glass, which hosts the majority of Al, Mn and

  1. Superficial alteration mineralogy in active volcanic systems: An example of Poás volcano, Costa Rica

    Science.gov (United States)

    Rodríguez, Alejandro; van Bergen, Manfred J.

    2017-10-01

    The alteration mineralogy in the crater area of Poás volcano (Costa Rica) has been studied to constrain acid fluid-rock interaction processes and conditions relevant for the formation of sulphate-bearing mineral assemblages found on the surface of Mars. Individual sub-environments, which include the hyperacid lake (Laguna Caliente), ephemeral hot springs, fumarole vents and areas affected by acid rain and/or spray from the lake, are marked by distinct secondary mineral associations, with sulphates commonly as prevailing component. The sulphates occur in a wide mineralogical diversity comprising gypsum/anhydrite, various polyhydrated Al-sulphates, alunite-jarosite group minerals, halotrichite-, voltaite- and copiapite-group minerals, epsomite and römerite. Depending on the sub-environment, they are variably associated with clay minerals (kaolinite-group and smectite-group), zeolites, SiO2-polymorphs, Fe-(hydro)oxides, Ti-oxides, native sulphur, sulphides, chlorides, fluorides, phosphates and carbonates. Geochemical modelling was performed to identify mechanisms responsible for the formation of the secondary minerals found in the field, and to predict their possible stability under conditions not seen at the surface. The results indicate that the appearance of amorphous silica, hematite, anhydrite/gypsum, pyrite, anatase and kaolinite is relatively insensitive to the degree of acidity of the local aqueous system. On the other hand, alunite-jarosite group minerals, elemental sulphur and Al(OH)SO4 only form under acidic conditions (pH rain or brine spray. Modelling suggests that their formation required a repetitive sequence of olivine dissolution and evaporation in an open system involving limited amounts of fluid. The mineral variety in the crater of Poás is remarkably similar to sulphate-bearing assemblages considered to be the product of acid-sulphate alteration on Mars. The analogy suggests that comparable fluid-rock interaction controls operated in Martian

  2. Forestry transformation

    International Nuclear Information System (INIS)

    Beer, G.

    2003-01-01

    State forestry company Lesy, s.p., Banska Bystrica have chosen Austrian state forestry company to operate as their restructuring advisor. 20 million Sk (0.142 mn Euro) were assigned to transformation of Lesy SR from a state enterprise to a state-owned joint-stock company. The whole process should take two years. The joint-stock company should be established at the beginning of next year. 'What we have to do first is to define the objectives and perspectives of this restructuring,' claims new director, Karol Vins. The new boss recalled all directors of the 26 branches. They were given a lot of freedom to trade with wood. The new management wants to establish a profit-making company. At the moment the company has total claims of 600 million Sk (14.59 million Eur) it will have to provision for

  3. Transforming vulnerability.

    Science.gov (United States)

    Jones, Patricia S; Zhang, Xinwei Esther; Meleis, Afaf I

    2003-11-01

    Asian American immigrant women engaged in filial caregiving are at special risk for health problems due to complex contextual factors related to immigration, cultural traditions, and role transition. This study examines the experience of two groups of immigrant Asian American women who are caring for older parents. A total of 41 women (22 Chinese American and 19 Filipino American) were interviewed in a study based on Strauss and Corbin's grounded theory methodology. The women were determined to be loyal to their traditional culture, which included strong filial values, while adapting to a new culture. Through the struggle of meeting role expectations and coping with paradox, the women mobilized personal and family resources to transform vulnerability into strength and well-being.

  4. Radioactive transformations

    CERN Document Server

    Rutherford, Ernest

    2012-01-01

    Radioactive Transformations describes Ernest Rutherford's Nobel Prize-winning investigations into the mysteries of radioactive matter. In this historic work, Rutherford outlines the scientific investigations that led to and coincided with his own research--including the work of Wilhelm Rӧntgen, J. J. Thomson, and Marie Curie--and explains in detail the experiments that provided a glimpse at special relativity, quantum mechanics, and other concepts that would shape modern physics. This new edition features a comprehensive introduction by Nobel Laureate Frank Wilczek which engagingly explains how Rutherford's early research led to a better understanding of topics as diverse as the workings of the atom's nucleus, the age of our planet, and the fusion in stars.

  5. The effects of metamorphism on iron mineralogy and the iron speciation redox proxy

    Science.gov (United States)

    Slotznick, Sarah P.; Eiler, John M.; Fischer, Woodward W.

    2018-03-01

    utilized. The presence of diagenetic iron carbonates in many samples severely affected the proxy even at low grade, engendering an interpretation of ferruginous conditions in all lithologies, but particularly in carbonate-bearing rocks. Increasing metamorphic grades transformed iron in carbonates into iron in silicate minerals, which when combined with a slight increase in the amount of pyrrhotite, drove the proxy toward more oxic and more euxinic conditions. Broad-classes of metamorphic reactions (e.g. decarbonation, silicate formation) occurred at distinct temperatures-pressures in carbonates versus siliciclastics, and could be either abrupt between metamorphic facies or more gradual in nature. Notably, these analyses highlighted the importance of trace iron in phases like calcite, which otherwise might not be included in iron-focused research i.e. ore-system petrogenesis, metamorphic evolution, or normative calculations of mineral abundance. The observations show that iron is mobile and reactive during diagenesis and metamorphism, and these post-depositional processes can readily overprint primary redox information held by iron speciation. However, in principle, additional mineralogical and petrographic approaches can be combined with iron speciation data to help untangle many of these post-depositional processes and arrive at more accurate estimates of paleoenvironmental redox conditions and processes, even for metamorphosed samples.

  6. Clinical Relevance of Adipokines

    Directory of Open Access Journals (Sweden)

    Matthias Blüher

    2012-10-01

    Full Text Available The incidence of obesity has increased dramatically during recent decades. Obesity increases the risk for metabolic and cardiovascular diseases and may therefore contribute to premature death. With increasing fat mass, secretion of adipose tissue derived bioactive molecules (adipokines changes towards a pro-inflammatory, diabetogenic and atherogenic pattern. Adipokines are involved in the regulation of appetite and satiety, energy expenditure, activity, endothelial function, hemostasis, blood pressure, insulin sensitivity, energy metabolism in insulin sensitive tissues, adipogenesis, fat distribution and insulin secretion in pancreatic β-cells. Therefore, adipokines are clinically relevant as biomarkers for fat distribution, adipose tissue function, liver fat content, insulin sensitivity, chronic inflammation and have the potential for future pharmacological treatment strategies for obesity and its related diseases. This review focuses on the clinical relevance of selected adipokines as markers or predictors of obesity related diseases and as potential therapeutic tools or targets in metabolic and cardiovascular diseases.

  7. Information Needs/Relevance

    OpenAIRE

    Wildemuth, Barbara M.

    2009-01-01

    A user's interaction with a DL is often initiated as the result of the user experiencing an information need of some kind. Aspects of that experience and how it might affect the user's interactions with the DL are discussed in this module. In addition, users continuously make decisions about and evaluations of the materials retrieved from a DL, relative to their information needs. Relevance judgments, and their relationship to the user's information needs, are discussed in this module. Draft

  8. Mineralogic Zonation Within the Tuff Confining Unit, Yucca Flat, Nevada Test Site

    International Nuclear Information System (INIS)

    Lance Prothro

    2005-01-01

    Recently acquired mineralogic data from drill hole samples in Yucca Flat show that the tuff confining unit (TCU) can be subdivided into three mineralogic zones based on the relative abundances of primary and secondary mineral assemblages. These zones are (1) an upper zone characterized by the abundance of the zeolite mineral clinoptilolite with lesser amounts of felsic and clay minerals; (2) a middle zone with felsic minerals dominant over clinoptilolite and clay minerals; and (3) a basal argillic zone where clay minerals are dominant over felsic minerals and clinoptilolite. Interpretation of the mineralogic data, along with lithologic, stratigraphic, and geophysical data from approximately 500 drill holes, reveals a three-layer mineralogic model for the TCU that shows all three zones are extensive beneath Yucca Flat. The mineralogic model will be used to subdivide the TCU in the Yucca Flat hydrostratigraphic framework model, resulting in a more accurate and versatile framework model. In addition, the identification of the type, quantity, and distribution of minerals within each TCU layer will permit modelers to better predict the spatial distribution and extent of contaminant transport from underground tests in Yucca Flat, at both the level of the hydrologic source term and the corrective action unit

  9. CCD-Based XRD/XRF for Determining Environmental Mineralogy on Mars

    Science.gov (United States)

    Vaniman, D. T.; Bish, D. L.; Blake, D. F.; Chipera, S. J.

    2000-01-01

    Health effects from Martian dusts will be a concern for any manned Mars missions. Nuisance dusts plagued the Apollo astronauts, but dusts of more hazardous mineralogy, in habitats occupied by Mars astronauts weakened by a long-duration mission, may be more than a nuisance. Chemical hazards in Martian regolith attributable to S, Cl, Br, Cd, and Pb are known or strongly suspected to be present, but terrestrial studies of the health effects of dusts indicate that accurate determination of mineralogy is a critical factor in evaluating inhalation hazards. Mineral inhalation hazards such as the Group-I carcinogenic zeolite erionite, which is demonstrated to cause mesothelioma, cannot be identified by chemical analysis alone. Studies of palagonite analogs raise the possibility that erionite may occur on Mars. In addition to health effects concerns, environmental mineralogy has significant importance in resource extraction, groundwater use, and sustained agriculture. The high sulfur and chlorine content of Martian regolith will affect all of these uses, but the nature of mineralogic reservoirs for S and Cl will determine their uptake and concentration in extracted groundwater and in agricultural applications of regolith. Wet chemistry experiments planned for the Mars Environmental Compatibility Assessment (MECA) will define some of the consequences of water/soil interaction, but an understanding of the mineralogic basis for water-rock reactions is needed to understand the mechanisms of reaction and to apply the results of a few experiments to larger scales and different conditions.

  10. A national-scale geochemical and mineralogical survey of soils of the conterminous United States

    International Nuclear Information System (INIS)

    Smith, David B.; Cannon, William F.; Woodruff, Laurel G.

    2011-01-01

    Highlights: → Sampling for national-scale soil geochemical and mineralogical survey completed for conterminous USA. → Natural variation for most elements is approximately three orders of magnitude. → Composition of soil parent material is the major controlling factor. → Climate (average annual precipitation) is also an important controlling factor for some elements. → Sample archive (4800 sites) available for future investigations. - Abstract: In 2007, the US Geological Survey initiated a low-density (1 site per 1600 km 2 , c. 4800 sites) geochemical and mineralogical survey of soils of the conterminous USA. The ideal sampling protocol at each site includes a sample from 0-5 cm depth, a composite of the soil A horizon, and a sample from the soil C horizon. The 3 , HClO 4 and HF. Separate methods are used for As, Hg, Se and total C on this same size fraction. The major mineralogical components are determined by a quantitative X-ray diffraction method. Sampling was completed in 2010 with chemical and mineralogical analysis currently underway. Preliminary results for a swath from the central USA to Florida clearly show the effects of soil parent material and climate on the chemical and mineralogical composition of soils. A sample archive will be established and made available for future investigations.

  11. Mineralogical and lithochemical studies of strata beneath the Harwell research site

    International Nuclear Information System (INIS)

    Wilmot, R.D.; Morgan, D.J.

    1982-11-01

    Determinations have been made of the mineralogy and lithochemistry of the principal lithological units of the Mesozoic and Palaeozoic rocks penetrated by boreholes at the Harwell Research Site. Samples were taken at approximately 9m intervals from the Upper Greensand to the Coal Measures, together with a number from the Chalk. Mineralogical analyses were carried out using X-ray diffraction, with thermal analysis and surface area measurements aiding quantification. Major and trace element determinations were made using direct electron excitation X-ray spectrometry and X-ray fluorescence respectively. Other chemical determinations included organic carbon, sulphate and 'exchangeable' cations. The mineralogical and lithochemical variations within and between the major litho-stratigraphic units are discussed and compared with published data for other localities. (author)

  12. Mineralogic and petrologic investigation of post-test core samples from the Spent Fuel Test - Climax

    International Nuclear Information System (INIS)

    Ryerson, F.J.; Beiriger, J.

    1985-02-01

    We have characterized a suite of samples taken subsequent to the end of the Spent Fuel Test - Climax by petrographic and microanalytical techniques and determined their mineral assemblage, modal properties, and mineral chemistry. The samples were obtained immediately adjacent to the canister borehole at a variety of depths and positions within the canister drift, as well as radially outward from each canister hole. This method of sampling allows variations in post-test mineralogic properties to be evaluated on the basis of (1) depth along a particular canister hole and (2) position within the canister drift, with respect to the heat and radiation sources, and with respect to the pre - test samples. In no case did we find any significant correlation between the mineralogical properties and variables listed above. In short, the Spent Fuel Test - Climax has produced no identifiable mineralogical response in the Climax quartz monzonite. 12 refs., 11 figs., 5 tabs

  13. Mineralogy of selected sedimentary interbeds at or near the Idaho National Engineering Laboratory, Idaho

    International Nuclear Information System (INIS)

    Reed, M.F.; Bartholomay, R.C.

    1994-08-01

    The US Geological Survey's (USGS) Project Office at the Idaho National Engineering Laboratory (INEL) analyzed 66 samples from sedimentary interbed cores during a 38-month period beginning in October 1990 to determine bulk and clay mineralogy. These cores had been collected from 19 sites in the Big Lost River Basin, 2 sites in the Birch Creek Basin, and 1 site in the Mud Lake Basin, and were archived at the USGS lithologic core library at the INEL. Mineralogy data indicate that core samples from the Big Lost River Basin have larger mean and median percentages of quartz, total feldspar, and total clay minerals, but smaller mean and median percentages of calcite than the core samples from the Birch Creek Basin. Core samples from the Mud Lake Basin have abundant quartz, total feldspar, calcite, and total clay minerals. Identification of the mineralogy of the Snake River Plain is needed to aid in the study of the hydrology and geochemistry of subsurface waste disposal

  14. [Relevant public health enteropathogens].

    Science.gov (United States)

    Riveros, Maribel; Ochoa, Theresa J

    2015-01-01

    Diarrhea remains the third leading cause of death in children under five years, despite recent advances in the management and prevention of this disease. It is caused by multiple pathogens, however, the prevalence of each varies by age group, geographical area and the scenario where cases (community vs hospital) are recorded. The most relevant pathogens in public health are those associated with the highest burden of disease, severity, complications and mortality. In our country, norovirus, Campylobacter and diarrheagenic E. coli are the most prevalent pathogens at the community level in children. In this paper we review the local epidemiology and potential areas of development in five selected pathogens: rotavirus, norovirus, Shiga toxin-producing E. coli (STEC), Shigella and Salmonella. Of these, rotavirus is the most important in the pediatric population and the main agent responsible for child mortality from diarrhea. The introduction of rotavirus vaccination in Peru will have a significant impact on disease burden and mortality from diarrhea. However, surveillance studies are needed to determine the impact of vaccination and changes in the epidemiology of diarrhea in Peru following the introduction of new vaccines, as well as antibiotic resistance surveillance of clinical relevant bacteria.

  15. Transforming giants.

    Science.gov (United States)

    Kanter, Rosabeth Moss

    2008-01-01

    Large corporations have long been seen as lumbering, inflexible, bureaucratic--and clueless about global developments. But recently some multinationals seem to be transforming themselves: They're engaging employees, moving quickly, and introducing innovations that show true connection with the world. Harvard Business School's Kanter ventured with a research team inside a dozen global giants--including IBM, Procter & Gamble, Omron, CEMEX, Cisco, and Banco Real--to discover what has been driving the change. After conducting more than 350 interviews on five continents, she and her colleagues came away with a strong sense that we are witnessing the dawn of a new model of corporate power: The coordination of actions and decisions on the front lines now appears to stem from widely shared values and a sturdy platform of common processes and technology, not from top-down decrees. In particular, the values that engage the passions of far-flung workforces stress openness, inclusion, and making the world a better place. Through this shift in what might be called their guidance systems, the companies have become as creative and nimble as much smaller ones, even while taking on social and environmental challenges of a scale that only large enterprises could attempt. IBM, for instance, has created a nonprofit partnership, World Community Grid, through which any organization or individual can donate unused computing power to research projects and see what is being done with the donation in real time. IBM has gained an inspiring showcase for its new technology, helped business partners connect with the company in a positive way, and offered individuals all over the globe the chance to contribute to something big.

  16. Mineralogy of Interplanetary Dust Particles from the Comet Giacobini-Zinner Dust Stream Collections

    Science.gov (United States)

    Nakamura-Messenger, K.; Messenger, S.; Westphal, A. J.; Palma, R. L.

    2015-01-01

    The Draconoid meteor shower, originating from comet 21P/Giacobini-Zinner, is a low-velocity Earth-crossing dust stream that had a peak anticipated flux on Oct. 8, 2012. In response to this prediction, NASA performed dedicated stratospheric dust collections to target interplanetary dust particles (IDPs) from this comet stream on Oct 15-17, 2012 [3]. Twelve dust particles from this targeted collection were allocated to our coordinated analysis team for studies of noble gas (Univ. Minnesota, Minnesota State Univ.), SXRF and Fe-XANES (SSL Berkeley) and mineralogy/isotopes (JSC). Here we report a mineralogical study of 3 IDPs from the Draconoid collection..

  17. Vertical evolution of the Cínovec granite cupola – chemical and mineralogical record

    Czech Academy of Sciences Publication Activity Database

    Breiter, Karel

    2016-01-01

    Roč. 46 (2016), s. 4-6 E-ISSN 1434-7512. [Late Paleozoic magmatism in the Erzgebirge / Krušné hory: Magma genesis, tectonics, geophysics, and mineral deposits : abstracts. 11.11.2016-12.11.2016, Freiberg] R&D Projects: GA ČR GA14-13600S Institutional support: RVO:67985831 Keywords : granite * Cínovec * geology * mineralogy * geochemistry Subject RIV: DB - Geology ; Mineralogy http://tu-freiberg.de/sites/default/files/media/institut-fuer-geologie-718/pdf/fog_volume_46.pdf

  18. Mineralogical investigations of the area to the North-West of Qattara Depression, Western Desert, Egypt

    International Nuclear Information System (INIS)

    Tosson, S.; Roshdy, H.M.K.

    2000-01-01

    Petrophysical and mineralogical investigations are given for subsurface samples from this area. The paper deals with mineralogical investigations of Middle Jurassic, Lower Cretaceous and Upper Cretaceous sedimentary rocks. It includes thin section examinations for 14 samples of sandstone, siltstone and carbonates, and x-ray powder diffraction analyses of some argillaceous samples, untreated and glycolated. It was found that the kaolinite group is the main clay mineral recorded in the argillaceous sandstone and siltstone samples. Illite and montmorillonite are identified in the shale sample representing the Kharita Formation. Siderite was also recorded in the sample. Illite and montmorillonite were recorded as well as kaolinite in two siltstone samples. (Author)

  19. Biostimulation of Iron Reduction and Uranium Immobilization: Microbial and Mineralogical Controls

    International Nuclear Information System (INIS)

    Joel E. Kostka; Lainie Petrie; Nadia North; David L. Balkwill; Joseph W. Stucki; Lee Kerkhof

    2004-01-01

    The overall objective of our project is to understand the microbial and geochemical mechanisms controlling the reduction and immobilization of U(VI) during biostimulation in subsurface sediments of the Field Research Center (FRC) which are cocontaminated with uranium and nitrate. The focus will be on activity of microbial populations (metal- and nitrate-reducing bacteria) and iron minerals which are likely to make strong contributions to the fate of uranium during in situ bioremediation. The project will: (1) quantify the relationships between active members of the microbial communities, iron mineralogy, and nitrogen transformations in the field and in laboratory incubations under a variety of biostimulation conditions, (2) purify and physiologically characterize new model metal-reducing bacteria isolated from moderately acidophilic FRC subsurface sediments, and (3) elucidate the biotic and abiotic mechanisms by which FRC aluminosilicate clay minerals are reduced and dissolved under environmental conditions resembling those during biostimulation. Active microbial communities will be assessed using quantitative molecular techniques along with geochemical measurements to determine the different terminal-electron-accepting pathways. Iron minerals will be characterized using a suite of physical, spectroscopic, and wet chemical methods. Monitoring the activity and composition of the denitrifier community in parallel with denitrification intermediates during nitrate removal will provide a better understanding of the indirect effects of nitrate reduction on uranium speciation. Through quantification of the activity of specific microbial populations and an in-depth characterization of Fe minerals likely to catalyze U sorption/precipitation, we will provide important inputs for reaction-based biogeochemical models which will provide the basis for development of in situ U bioremediation strategies. In collaboration with Jack Istok and Lee Krumholz, we have begun to study the

  20. Organic petrology, mineralogy and depositional environment of the Kipra lignite seam, Maritza-West basin, Bulgaria

    Energy Technology Data Exchange (ETDEWEB)

    Kostova, Irena [Department of Geology and Palaeontology, Sofia University ' ' St. Kliment Ohridski' ' , 1000, Sofia (Bulgaria); Zdravkov, Alexander [Department of Economic Geology, University of Mining and Geology ' ' St. Ivan Rilski' ' , 1700, Sofia (Bulgaria)

    2007-08-01

    The aim of the present study is to provide additional information about the properties and depositional environment of the Kipra lignite seam, which was deposited during the regressive stage of development of the Maritza-West basin. Petrographical and mineralogical data, along with ash yields and sulphur contents of 24 samples from a seam profile, have been used to study the vertical variation of the depositional settings during peat accumulation and subsequent coalification. The Kipra lignite is characterized by high ash yields and sulphur contents. It formed in a rheotrophic, low-lying mire with alkaline pH value. Vegetation with low preservation potential dominated within the palaeomire. During peat formation, frequent changes of the water level controlled the depositional environment. During the deposition of units 1 and 2, high water energy caused the transportation of high amounts of inorganic material into the mire, resulting in the formation of weakly gelified mineral-rich lignite. The organic matter from units 3 and 4 is characterized by enhanced gelification, which probably reflects the decreasing energy of the system. Good positive correlation between sulphur contents and the GI values was established in units 4, indicating that the gelification of the tissues was probably mainly controlled by the bacterial activity. In contrast, the gelification of the samples from unit 3 of the Kipra seam was probably governed by the redox conditions. The organic matter deposited under relatively wet conditions, in which the thermal and oxidative destruction of the tissues, was limited. A variety of major, minor and accessory minerals are present in Maritza-West lignite. The mineral composition is dominated mainly by pyrite, gypsum and calcite, and to a lesser extent limonite, quartz, kaolinite, montmorillonite, illite, chlorite and plagioclase. Jarosite, hematite, halloysite, mica, K-feldspar, aragonite, siderite, and dolomite were also determined in very low

  1. Scale transformation and massless limit in neutral-vector field theory. [Gauge transformation unified theory

    Energy Technology Data Exchange (ETDEWEB)

    Kubo, R; Takahashi, Y; Yokoyama, K

    1975-01-01

    In a wide class of neutral vector field theories, in which massive and massless fields are described in a unified way and a unique massless limit exists to quantum electrodynamics in covariant gauges, the commutability of the scale transformation and the massless limit is examined. It is shown that there occurs no anomaly with respect to the assignment for scale dimensions of relevant fields. Connection of scale transformation and gauge transformation is also discussed.

  2. Chemical and Mineralogical Characterization of a Hematite-bearing Ridge on Mauna Kea, Hawaii: A Potential Mineralogical Process Analog for the Mount Sharp Hematite Ridge

    Science.gov (United States)

    Graff, T. G.; Morris, R. V.; Ming, D. W.; Hamilton, J. C.; Adams, M.; Fraeman, A. A.; Arvidson, R. E.; Catalano, J. G.; Mertzman, S. A.

    2014-01-01

    The Mars Science Laboratory (MSL) rover Curiosity landed in Gale Crater in August 2012 and is currently roving towards the layered central mound known as Mount Sharp [1]. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) hyperspectral data indicate Mount Sharp contains an 5 km stratigraphic sequence including Fe-Mg smectites, hematite, and hydrated sulfates in the lower layers separated by an unconformity from the overlying anhydrous strata [1,2,3]. Hematite was initially detected in CRISM data to occur in the lower sulfate layers on the north side of the mound [2]. [3] further mapped a distinct hematite detection occurring as part of a 200 m wide ridge that extends 6.5 km NE-SW, approximately parallel with the base of Mount Sharp. It is likely a target for in-situ analyses by Curiosity. We document here the occurrence of a stratum of hematite-bearing breccia that is exposed on the Puu Poliahu cinder cone near the summit of Mauna Kea volcano (Hawaii) (Fig.1). The stratum is more resistant to weathering than surrounding material, giving it the appearance of a ridge. The Mauna Kea hematite ridge is thus arguably a potential terrestrial mineralogical and process analog for the Gale Crater hematite ridge. We are acquiring a variety of chemical and mineralogical data on the Mauna Kea samples, with a focus on the chemical and mineralogical information already available or planned for the Gale hematite ridge.

  3. Other relevant biological papers

    International Nuclear Information System (INIS)

    Shimizu, M.

    1989-01-01

    A considerable number of CRESP-relevant papers concerning deep-sea biology and radioecology have been published. It is the purpose of this study to call attention to them. They fall into three general categories. The first is papers of general interest. They are mentioned only briefly, and include text references to the global bibliography at the end of the volume. The second are papers that are not only mentioned and referenced, but for various reasons are described in abstract form. The last is a list of papers compiled by H.S.J. Roe specifically for this volume. They are listed in bibliographic form, and are also included in the global bibliography at the end of the volume

  4. Mineralogy and environmental geochemistry of historical iron slag, Hopewell Furnace National Historic Site, Pennsylvania, USA

    International Nuclear Information System (INIS)

    Piatak, Nadine M.; Seal, Robert R.

    2012-01-01

    The Hopewell Furnace National Historic Site in southeastern Pennsylvania, which features an Fe smelter that was operational in the 18th and 19th centuries, is dominated by three slag piles. Pile 1 slag, from the Hopewell Furnace, and pile 2 slag, likely from the nearby Cornwall Furnace, were both produced in cold-blast charcoal-fired smelters. In contrast, pile 3 slag was produced in an anthracite furnace. Ore samples from the nearby Jones and Hopewell mines that fed the smelter are mainly magnetite-rich with some sulfides (pyrite, chalcopyrite, sphalerite) and accessory silicates (quartz, garnet, feldspar, and clay minerals). Slag piles 1 and 2 are similar mineralogically containing predominantly skeletal and dendritic aluminian diopside and augite, skeletal forsteritic olivine, glass, rounded blebs of metallic Fe, and exotic quartz. Olivine is a major phase in all samples from pile 2, whereas it occurs in only a few samples from pile 1. Samples of the 2 O 3 (8.5–16.2 wt.%), CaO (8.2–26.2 wt.%), MgO (4.2–24.7 wt.%), and SiO 2 (36.4–59.8 wt.%), constituting between 81% and 97% of the mass of the samples. Piles 1 and 2 are chemically similar; pile 1 slag overall contains the highest Fe 2 O 3 , K 2 O and MnO, and the lowest MgO concentrations. Pile 3 slag is high in Al 2 O 3 , CaO and S, and low in Fe 2 O 3 , K 2 O and SiO 2 compared to the other piles. In general, piles 1 and 2 are chemically similar to each other, whereas pile 3 is distinct – a conclusion that reflects their mineralogy. The similarities and differences among piles in terms of mineralogy and major element chemistry result from the different smelting conditions under which the slag formed and include the fuel source, the composition of the ore and flux, the type of blast (cold versus hot), which affects the furnace temperature, and other beneficiation methods. The three distinct slag piles at Hopewell are enriched in numerous trace elements, such as As (up to 12 mg/kg), Cd (up to 0.4 mg

  5. Mineralogy and environmental geochemistry of historical iron slag, Hopewell Furnace National Historic Site, Pennsylvania, USA

    Science.gov (United States)

    Piatak, Nadine; Seal, Robert

    2012-01-01

    The Hopewell Furnace National Historic Site in southeastern Pennsylvania, which features an Fe smelter that was operational in the 18th and 19th centuries, is dominated by three slag piles. Pile 1 slag, from the Hopewell Furnace, and pile 2 slag, likely from the nearby Cornwall Furnace, were both produced in cold-blast charcoal-fired smelters. In contrast, pile 3 slag was produced in an anthracite furnace. Ore samples from the nearby Jones and Hopewell mines that fed the smelter are mainly magnetite-rich with some sulfides (pyrite, chalcopyrite, sphalerite) and accessory silicates (quartz, garnet, feldspar, and clay minerals). Slag piles 1 and 2 are similar mineralogically containing predominantly skeletal and dendritic aluminian diopside and augite, skeletal forsteritic olivine, glass, rounded blebs of metallic Fe, and exotic quartz. Olivine is a major phase in all samples from pile 2, whereas it occurs in only a few samples from pile 1. Samples of the bearing aluminian diopside, dendritic or fine-grained subhedral melilite, glass, euhedral spinel, metallic Fe, alabandite–oldhamite solid solution, as well as a sparse Ti carbonitride phase. The bulk chemistry of the slag is dominated by Al2O3 (8.5–16.2 wt.%), CaO (8.2–26.2 wt.%), MgO (4.2–24.7 wt.%), and SiO2 (36.4–59.8 wt.%), constituting between 81% and 97% of the mass of the samples. Piles 1 and 2 are chemically similar; pile 1 slag overall contains the highest Fe2O3, K2O and MnO, and the lowest MgO concentrations. Pile 3 slag is high in Al2O3, CaO and S, and low in Fe2O3, K2O and SiO2 compared to the other piles. In general, piles 1 and 2 are chemically similar to each other, whereas pile 3 is distinct – a conclusion that reflects their mineralogy. The similarities and differences among piles in terms of mineralogy and major element chemistry result from the different smelting conditions under which the slag formed and include the fuel source, the composition of the ore and flux, the type of

  6. Effects of vegetation on chemical and mineralogical characteristics of soils developed on a decantation bank from a copper mine.

    Science.gov (United States)

    Cerqueira, Beatriz; Vega, Flora A; Silva, Luis F O; Andrade, Luisa

    2012-04-01

    Open cast mining has a strong impact on the environment, the intensity depending on the morphology of the deposit and on the nature of the minerals. At Touro mine (NW Spain) there is a large area covered by tailings, one of which, called the "sedimentation bank", was used to deposit sludge resulting from the extraction of copper in the flotation plant. Three zones were selected and the soils were sampled to analyse the changes brought about by vegetation on the chemical and mineralogical properties of the soils developed over the sedimentation bank and its development over time. The vegetation increased the pH, contents of organic material, nitrogen, clay and free oxides of Fe and Al, and the cationic exchange capacity of the soils. The decrease in the sulphide content, benefited by the vegetation process, led to a reduction in the total content of Cr and Cu. The vegetation also contributed towards the alteration of the primary minerals. The transformation of jarosite, the formation of nanocrystals of hematite, goethite, hydroxypolymers, and amorphous minerals that contained Cu, Cr and Pb were observed. Nevertheless the high Cu and Cr contents indicate that it is advisable to change the restoration process. Copyright © 2012 Elsevier B.V. All rights reserved.

  7. Clay mineralogy and geochemistry of the soils derived from metamorphic and mafic igneous parent rocks in Lahijan area

    International Nuclear Information System (INIS)

    Ramezanpour, H.; Hesami, R.; Zanjanchi, M. A.

    2007-01-01

    The mineralogical and geochemical composition of the soils of three representative pedons formed on basaltic andesite, andesitic basalt and phyllite were investigated. Results by x-ray diffraction showed that progressive weathering of rocks have been marked by gradual accumulation of Al, Fe, Ti, Mg, H 3 O + and depletion of Na, K, Ca and Si in the soil; although, predominant clay, loss and gain trend of elements was different on the various rocks. Based on x-ray diffraction analysis, minerals in basaltic andesite and andesitic basalt were similar but, the intensity of mica to smectite or vermiculite transformation for latter was relatively higher than the former. This process revealed the degradation mineral because of two reasons: (i) - smectite and vermiculite increased whereas mica decreased in surface horizons. (i i)-Irregular mixed layer of mica-smectite or vermiculite was present in deeper part (170 cm) of the soils from andesitic basalt but shallower depth (75 em) of the soils from basaltic andesite. Clay minerals in phyllite were mica and chlorite that stratified with vermiculite. However, the absence of smectite in phyllite might be attributed to more acidic condition or position of the Fe ion in the mineral lattice of chlorite (higher Fe in the interlayer hydroxide sheet)

  8. Transformer Protection Using the Wavelet Transform

    OpenAIRE

    ÖZGÖNENEL, Okan; ÖNBİLGİN, Güven; KOCAMAN, Çağrı

    2014-01-01

    This paper introduces a novel approach for power transformer protection algorithm. Power system signals such as current and voltage have traditionally been analysed by the Fast Fourier Transform. This paper aims to prove that the Wavelet Transform is a reliable and computationally efficient tool for distinguishing between the inrush currents and fault currents. The simulated results presented clearly show that the proposed technique for power transformer protection facilitates the a...

  9. Mineralogy, geologic and physico-chemical characteristics of uranotitanate formation

    International Nuclear Information System (INIS)

    Korolev, K.G.; Miguta, A.K.; Polyakova, V.M.; Rumyantseva, G.V.

    1979-01-01

    Results of experimental and field study of varieties of brannerite and davidite are described. Special attention is paid to medium-low temperature variety of brannerite, which is the component of the majority of known uranotitanate ores. Natural concentrations of uranium are characterized: geologic peculiarities of their localization, mineral paragenesis, periore alterations. Syntheses of brannerite and davidite have been realized for the first time under hydrothermal conditions. Complex multiphase products of uranium titanate transformation, decomposition reactions of brannerite into constituent oxides in particular. Peculiarities of uranium and titanium migration in aqueous solutions at high temperatures and pressures are discussed. The processes of brannerite and davidite formation in hydrothermal conditions and from the melts are considered. Application of thermodynamic calculations of equilibria to the reactions of solid phase formation out of diluted ( -6 M) solutions and to the solid dispersoids in general is found to be erroneous as the formation of the latters is connected with kinetic phenomena

  10. The Bargmann transform and canonical transformations

    International Nuclear Information System (INIS)

    Villegas-Blas, Carlos

    2002-01-01

    This paper concerns a relationship between the kernel of the Bargmann transform and the corresponding canonical transformation. We study this fact for a Bargmann transform introduced by Thomas and Wassell [J. Math. Phys. 36, 5480-5505 (1995)]--when the configuration space is the two-sphere S 2 and for a Bargmann transform that we introduce for the three-sphere S 3 . It is shown that the kernel of the Bargmann transform is a power series in a function which is a generating function of the corresponding canonical transformation (a classical analog of the Bargmann transform). We show in each case that our canonical transformation is a composition of two other canonical transformations involving the complex null quadric in C 3 or C 4 . We also describe quantizations of those two other canonical transformations by dealing with spaces of holomorphic functions on the aforementioned null quadrics. Some of these quantizations have been studied by Bargmann and Todorov [J. Math. Phys. 18, 1141-1148 (1977)] and the other quantizations are related to the work of Guillemin [Integ. Eq. Operator Theory 7, 145-205 (1984)]. Since suitable infinite linear combinations of powers of the generating functions are coherent states for L 2 (S 2 ) or L 2 (S 3 ), we show finally that the studied Bargmann transforms are actually coherent states transforms

  11. Corrigendum to "Arsenic mineralogy and mobility in the arsenic-rich historical mine waste dump" [Sci. Total Environ. 536 (2015) 713-728

    Czech Academy of Sciences Publication Activity Database

    Filippi, Michal; Drahota, P.; Machovič, V.; Böhmová, Vlasta; Mihaljevič, M.

    2016-01-01

    Roč. 541, January 15 (2016), s. 1639 ISSN 0048-9697 Institutional support: RVO:67985831 Keywords : corrigendum * erratum * arsenic mineralogy Subject RIV: DB - Geology ; Mineralogy Impact factor: 4.900, year: 2016

  12. Arsenic mineralogy of near-neutral soils and mining waste at the Smolotely-Líšnice historical gold district, Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Drahota, P.; Kulakowski, O.; Culka, A.; Knappová, M.; Rohovec, Jan; Veselovský, F.; Racek, M.

    2018-01-01

    Roč. 89, February (2018), s. 243-254 ISSN 0883-2927 Institutional support: RVO:67985831 Keywords : soil * mining waste * pharmacosiderite * yukonite * arseniosiderite Subject RIV: DB - Geology ; Mineralogy OBOR OECD: Mineralogy Impact factor: 2.581, year: 2016

  13. User perspectives on relevance criteria

    DEFF Research Database (Denmark)

    Maglaughlin, Kelly L.; Sonnenwald, Diane H.

    2002-01-01

    , partially relevant, or not relevant to their information need; and explained their decisions in an interview. Analysis revealed 29 criteria, discussed positively and negatively, that were used by the participants when selecting passages that contributed or detracted from a document's relevance......This study investigates the use of criteria to assess relevant, partially relevant, and not-relevant documents. Study participants identified passages within 20 document representations that they used to make relevance judgments; judged each document representation as a whole to be relevant...... matter, thought catalyst), full text (e.g., audience, novelty, type, possible content, utility), journal/publisher (e.g., novelty, main focus, perceived quality), and personal (e.g., competition, time requirements). Results further indicate that multiple criteria are used when making relevant, partially...

  14. Mineralogical association in the zone of argillic advanced alteration in a kaolin deposit of Patagonia Argentina

    International Nuclear Information System (INIS)

    Rainoldi, A; Oviedo, P.; Maiza, P.; Marfil, S.

    2010-01-01

    This work is about the mineralogical and petrological relations of the para genetic association of advanced argillic zone in the kaolin deposit in Patagonia.This study allowed to establish the sequence of events that took place in the deposit as well as the conditions under which they were generated

  15. Mineralogy and pore water chemistry of a boiler ash from a MSW fluidized-bed incinerator.

    Science.gov (United States)

    Bodénan, F; Guyonnet, D; Piantone, P; Blanc, P

    2010-07-01

    This paper presents an investigation of the mineralogy and pore water chemistry of a boiler ash sampled from a municipal solid waste fluidized-bed incinerator, subject to 18 months of dynamic leaching in a large percolation column experiment. A particular focus is on the redox behaviour of Cr(VI) in relation to metal aluminium Al(0), as chromium may represent an environmental or health hazard. The leaching behaviour and interaction between Cr(VI) and Al(0) are interpreted on the basis of mineralogical evolutions observed over the 18-month period and of saturation indices calculated with the geochemical code PhreeqC and reviewed thermodynamic data. Results of mineralogical analyses show in particular the alteration of mineral phases during leaching (e.g. quartz and metal aluminium grains), while geochemical calculations suggest equilibria of percolating fluids with respect to specific mineral phases (e.g. monohydrocalcite and aluminium hydroxide). The combination of leaching data on a large scale and mineralogical analyses document the coupled leaching behaviour of aluminium and chromium, with chromium appearing in the pore fluids in its hexavalent and mobile state once metal aluminium is no longer available for chromium reduction. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  16. Pedogennyje i litogennyje osobennosti mineralogičeskogo sostava černozema na krasnocvetnych porodach

    Czech Academy of Sciences Publication Activity Database

    Lesovaja, S. N.; Kapička, Aleš; Petrovský, Eduard; Aparin, B. F.

    2003-01-01

    Roč. 36, č. 12 (2003), s. 1482-1490 ISSN 0032-180X Grant - others:RFFI(RU) 01-04-48815 Institutional research plan: CEZ:AV0Z3012916 Keywords : mineralogical composition * chernozem * magnetic minerals Subject RIV: DE - Earth Magnetism, Geodesy, Geography

  17. Pedogenic and lithogenic features in the mineralogical composition of chernozem developed from red-earth deposits

    Czech Academy of Sciences Publication Activity Database

    Lesovaya, S. N.; Kapička, Aleš; Petrovský, Eduard; Aparin, B. F.

    2003-01-01

    Roč. 36, č. 12 (2003), s. 1325-1333 ISSN 1064-2293 Grant - others:RFFI(RU) 01-04-48815 Institutional research plan: CEZ:AV0Z3012916 Keywords : mineralogical composition * chernozem * magnetic minerals Subject RIV: DE - Earth Magnetism, Geodesy, Geography Impact factor: 0.136, year: 2003

  18. Mineralogical Approaches to Sourcing Pipes and Figurines from the Eastern Woodlands, U.S.A.

    Science.gov (United States)

    Wisseman, S.U.; Moore, D.M.; Hughes, R.E.; Hynes, M.R.; Emerson, T.E.

    2002-01-01

    Provenance studies of stone artifacts often rely heavily upon chemical techniques such as neutron activation analysis. However, stone specimens with very similar chemical composition can have different mineralogies (distinctive crystalline structures as well as variations within the same mineral) that are not revealed by multielemental techniques. Because mineralogical techniques are often cheap and usually nondestructive, beginning with mineralogy allows the researcher to gain valuable information and then to be selective about how many samples are submitted for expensive and somewhat destructive chemical analysis, thus conserving both valuable samples and funds. Our University of Illinois team of archaeologists and geologists employs Portable Infrared Mineral Analyzer (PIMA) spectroscopy, X-ray diffraction (XRD), and Sequential acid dissolution/XRD/Inductively coupled plasma (SAD-XRD-ICP) analyses. Two case studies of Hopewellian pipes and Mississippian figurines illustrate this mineralogical approach. The results for both studies identify sources relatively close to the sites where the artifacts were recovered: Sterling, Illinois (rather than Ohio) for the (Hopewell) pipes and Missouri (rather than Arkansas or Oklahoma) for the Cahokia figurines. ?? 2002 Wiley Periodicals, Inc.

  19. Remote In-Situ Quantitative Mineralogical Analysis Using XRD/XRF

    Science.gov (United States)

    Blake, D. F.; Bish, D.; Vaniman, D.; Chipera, S.; Sarrazin, P.; Collins, S. A.; Elliott, S. T.

    2001-01-01

    X-Ray Diffraction (XRD) is the most direct and accurate method for determining mineralogy. The CHEMIN XRD/XRF instrument has shown promising results on a variety of mineral and rock samples. Additional information is contained in the original extended abstract.

  20. Sand and clay mineralogy of sal forest soils of the Doon Siwalik ...

    Indian Academy of Sciences (India)

    3Forest Soil & Land Reclamation Division, Forest Research Institute, Dehradun 248 006, India. .... also helps in characterizing the soil mineralogical make-up in relation to the growth and develop- ment of the species essential for sustainable forest management. ...... and Weed S B (Madison: Soil Science Society of America).

  1. Textural and mineralogical study of the San Gregorio de Polanco mesozoic basic dams

    International Nuclear Information System (INIS)

    Scaglia, S.; Muzio, R.; Masquelin, H.

    2010-01-01

    This work is about the preliminary results of petrographic study in Mesozoic basic dikes located around San Gregorio de Polanco (Tacuarembo department. Uruguay). The textural mineralogical study conducted by scanning electron microscopy confirms the presence of significant late hydrothermal activity which are represented by the conspicuous presence of interstitial barite mineralization level

  2. Size, surface texture, chemical composition and mineralogy interrelations in ferromanganese nodules of central Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Banakar, V.K; Pattan, J.N.; Jauhari, P.

    Fiftyseven ferromanganese nodules, classified into 3 size class (4,4-6 and 6-8 cm diam.), from the siliceous sediments of central Indian Ocean were analysed for transition metals and representative sample from each size class for mineralogy. Smaller...

  3. Lithological and mineralogical changes observed in a core from the western Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)

    Reddy, N.P.C.; Rao, K.M.; Putra, S.V.S; Rao, Ch.M.

    Lithological and mineralogical studies were carried out on sediments from a 650 cm long core from the north western Bay of Bengal at a depth of 2700 m. These studies demarcate a boundary at 380 cm designated as unit 1 from 0-380 cm and unit 2 from...

  4. Prediction of potential compressive strength of Portland clinker from its mineralogy

    DEFF Research Database (Denmark)

    Svinning, K.; Høskuldsson, Agnar; Justnes, H.

    2010-01-01

    Based on a statistical model first applied for prediction of compressive strength up to 28 d from the microstructure of Portland cement, potential compressive strength of clinker has been predicted from its mineralogy. The prediction model was evaluated by partial least squares regression...

  5. Mineralogical characteristics of andradite and grossular of te Sasa Ore Field

    International Nuclear Information System (INIS)

    Shijakova-Ivanova, Tena; Zajkova-Paneva, Vesna

    2003-01-01

    The paper presents the mineralogical characteristics of garnets (andradite and grossular) of the Sasa ore field, Investigations were carried out in the Institute for Crystallography and Petrography in Zurich, Switzerland and in the laboratory of the Faculty of Mining and Geology, Shtip. (Original)

  6. Mineralogical Composition of Urinary Stones and Their Frequency in Patients: Relationship to Gender and Age

    Directory of Open Access Journals (Sweden)

    Behnam Keshavarzi

    2016-12-01

    Full Text Available This investigation reports the mineralogy and possible pathological significance of urinary stones removed from patients in Fars province, Iran. X-ray diffraction (XRD, scanning electron microscopy (SEM and polarizing microscope (PM techniques were used to investigate the mineralogical compositions of urinary stones. The identified mineral components include whewellite, weddellite, hydroxyapatite, uricite and cystine. These techniques revealed that the whewellite and uricite were the most common mineral phases. Platy-like/monoclinic whewellite, prismatic/monoclinic uric acid and hexagonal cystine crystals were revealed by SEM. Biominerals (calcium carbonate and quartz were also identified in PM images. Of the variables determining the type of precipitated minerals, the effects of pH on depositional conditions proved to be the most apparent parameter, as shown by occurrences and relationships among the studied minerals. Our results revealed the importance of detailed knowledge of mineralogical composition in assessing the effects of age and sex. The highest incidence of urinary stones was observed in the 40–60 age group. Calcium oxalate and uric acid stones are more frequent in men than women. Finally, the study concluded that knowledge of the mineralogical composition of urinary stones is important as it helps the scientific community to explain the chemistry and the etiology of the calculi in the urinary system.

  7. Arsenic-rich acid mine water with extreme arsenic concentration: mineralogy, geochemistry, microbiology, and environmental implications

    Czech Academy of Sciences Publication Activity Database

    Majzlan, J.; Plášil, Jakub; Škoda, R.; Gescher, J.; Kögler, F.; Rusznyak, A.; Küsel, K.; Neu, T.R.; Mangold, S.; Rothe, J.

    2014-01-01

    Roč. 48, č. 23 (2014), s. 13685-13693 ISSN 0013-936X R&D Projects: GA ČR GP13-31276P Institutional support: RVO:68378271 Keywords : extreme arsenic concentration Subject RIV: DB - Geology ; Mineralogy Impact factor: 5.330, year: 2014

  8. Mineralogy and pore water chemistry of a boiler ash from a MSW fluidized-bed incinerator

    International Nuclear Information System (INIS)

    Bodenan, F.; Guyonnet, D.; Piantone, P.; Blanc, P.

    2010-01-01

    This paper presents an investigation of the mineralogy and pore water chemistry of a boiler ash sampled from a municipal solid waste fluidized-bed incinerator, subject to 18 months of dynamic leaching in a large percolation column experiment. A particular focus is on the redox behaviour of Cr(VI) in relation to metal aluminium Al 0 , as chromium may represent an environmental or health hazard. The leaching behaviour and interaction between Cr(VI) and Al 0 are interpreted on the basis of mineralogical evolutions observed over the 18-month period and of saturation indices calculated with the geochemical code PhreeqC and reviewed thermodynamic data. Results of mineralogical analyses show in particular the alteration of mineral phases during leaching (e.g. quartz and metal aluminium grains), while geochemical calculations suggest equilibria of percolating fluids with respect to specific mineral phases (e.g. monohydrocalcite and aluminium hydroxide). The combination of leaching data on a large scale and mineralogical analyses document the coupled leaching behaviour of aluminium and chromium, with chromium appearing in the pore fluids in its hexavalent and mobile state once metal aluminium is no longer available for chromium reduction.

  9. Mineralogy of Air-Pollution-Control Residues from a Secondary Lead Smellter: Environmental Implications

    Czech Academy of Sciences Publication Activity Database

    Ettler, V.; Johan, Z.; Baronnet, A.; Jankovský, F.; Gilles, C.; Mihaljevič, M.; Šebek, O.; Strnad, L.; Bezdička, Petr

    2005-01-01

    Roč. 39, č. 23 (2005), s. 9309-9316 ISSN 0013-936X R&D Projects: GA ČR(CZ) GP205/01/D132 Institutional research plan: CEZ:AV0Z40320502 Keywords : mineralogy * environmental aplications Subject RIV: CA - Inorganic Chemistry Impact factor: 4.054, year: 2005

  10. The mineralogical phase transformation of invisible gold-concentrate by microwave heating, and enhancement of their gold leaching rate

    Science.gov (United States)

    Bak, Geonyoung; Kim, Bongju; Choi, Nagchoul; Park*, Cheonyoung

    2015-04-01

    In this study, in order to obtain the maximum Au leaching rate, an invisible gold concentrate sample was microwave-treated and a thiourea leaching experiment was performed. It is found that gold exists as invisible as a result of observation with an optical microscope and an electron microscope. As the invisible gold concentrate sample was exposed to microwave longer, its temperature and weight loss were increased together and its S content was decreased. The conditions for the maximum Au leaching rate and the fast leaching effect were a particle size of -325×400 mesh, exposure to microwave for 70 minutes, 1.0 g of thiourea, 0.0504 g of sodium sulfite and 0.425 g of ferric sulfate. However, the condition under which Au was leached out to the maximum was applied to the control sample, but its Au leaching rate was just in a range of 78% to 88%. Such results suggest that the effect of sodium sulfite and ferric sulfate was more effective in the microwave-treated sample than in the control sample. Therefore, it was confirmed that the complete and very fast Au leaching can be achieved by means of the microwave pretreatment of invisible gold concentrate.

  11. Generalized Fourier transforms classes

    DEFF Research Database (Denmark)

    Berntsen, Svend; Møller, Steen

    2002-01-01

    The Fourier class of integral transforms with kernels $B(\\omega r)$ has by definition inverse transforms with kernel $B(-\\omega r)$. The space of such transforms is explicitly constructed. A slightly more general class of generalized Fourier transforms are introduced. From the general theory foll...... follows that integral transform with kernels which are products of a Bessel and a Hankel function or which is of a certain general hypergeometric type have inverse transforms of the same structure....

  12. Evaluation of past and future alterations in tuff at Yucca Mountain, Nevada, based on the clay mineralogy of drill cores USW G-1, G-2, and G-3

    International Nuclear Information System (INIS)

    Bish, D.L.

    1989-03-01

    The tuffs at Yucca Mountain in south-central Nevada are being studied by the Yucca Mountain Project (YMP) to determine their suitability for a high-level radioactive waste repository. For predictive purposes, it is important to understand the alteration history of Yucca Mountain and to know how the minerals in Yucca Mountain tuffs respond to changing conditions such as elevated temperatures. The clay mineralogy of these tuffs has been examined using x-ray powder diffraction, and approximation temperatures of alteration have been determined using available clay mineral data and fluid inclusion analyses. Also, several illites from drill holes USW G-1 and G-2 have been dated using K/Ar techniques, yielding ages of about 11 Myr. The clay mineral in Yucca Mountain tuffs are predominantly interstratified illite/smectites, with minor amounts of chloride, kaolinite, and interstratified chlorite/smectite at depth in USW G-1 and G-2. The reactions observed for these illite/smectites are similar to those observed in pelitic rocks. With depths, the illite/smectites transform from random interstratifications (R = 0) through ordered intermediates (R = 1) to illite in USW G-2 and to Kalkberg (R ≥ 3) interstratifications in USW G-1. The illite/smectites in USW G-3 have not significantly transformed. It appears that the illites in deeper rock results from hydrothermal and diagenetic reactions of earlier-formed smectites. These data demonstrate that the rocks at depth in the northern end of Yucca Mountain were significantly altered about 11 Myr ago. Both clay mineralogy and fluid inclusions suggest that the rocks at depth in USW G-2 have been subjected to postdepositional temperatures of at least 275/degree/C, those in USW G-1 have reached 200/degree/C, and USW G-3 rocks probably have not exceeded 100/degree/C. 64 refs., 9 figs., 3 tabs

  13. Army Maintenance System Transformation

    National Research Council Canada - National Science Library

    Gilbertson, Frank V

    2006-01-01

    .... Used in conjunction with pertinent historical data and developed with Army transformation goals in mind, General Systems thinking can provide the framework for guiding maintenance transformation...

  14. Skeletal mineralogy of coral recruits under high temperature and pCO2

    Science.gov (United States)

    Foster, T.; Clode, P. L.

    2016-03-01

    Aragonite, which is the polymorph of CaCO3 precipitated by modern corals during skeletal formation, has a higher solubility than the more stable polymorph calcite. This higher solubility may leave animals that produce aragonitic skeletons more vulnerable to anthropogenic ocean acidification. It is therefore important to determine whether scleractinian corals have the plasticity to adapt and produce calcite in their skeletons in response to changing environmental conditions. Both high pCO2 and lower Mg / Ca ratios in seawater are thought to have driven changes in the skeletal mineralogy of major marine calcifiers in the past ˜ 540 Ma. Experimentally reduced Mg / Ca ratios in ambient seawater have been shown to induce some calcite precipitation in both adult and newly settled modern corals; however, the impact of high pCO2 on the mineralogy of recruits is unknown. Here we determined the skeletal mineralogy of 1-month-old Acropora spicifera coral recruits grown under high temperature (+3 °C) and pCO2 (˜ 900 µatm) conditions, using X-ray diffraction and Raman spectroscopy. We found that newly settled coral recruits produced entirely aragonitic skeletons regardless of the treatment. Our results show that elevated pCO2 alone is unlikely to drive changes in the skeletal mineralogy of young corals. Not having an ability to switch from aragonite to calcite precipitation may leave corals and ultimately coral reef ecosystems more susceptible to predicted ocean acidification. An important area for prospective research would be the investigation of the combined impact of high pCO2 and reduced Mg / Ca ratio on coral skeletal mineralogy.

  15. A Paleoseismic Record of Earthquakes for the Dead Sea Transform Fault between the First and Seventh Centuries C.E.: Nonperiodic Behavior of a Plate Boundary Fault

    Czech Academy of Sciences Publication Activity Database

    Wechsler, N.; Rockwell, T.K.; Klinger, Y.; Štěpančíková, Petra; Kanari, M.; Marco, S.; Agnon, A.

    2014-01-01

    Roč. 104, č. 3 (2014), s. 1329-1347 ISSN 0037-1106 R&D Projects: GA ČR GAP210/12/0573 Institutional support: RVO:67985891 Keywords : active tectonics * paleoseismology * paleoearthquake * Dead Sea Transform fault * Jordan Gorge fault Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.322, year: 2014

  16. Geochemical and mineralogical characteristics of percolates and its evaporates from Technosols before and after limestone filler stabilisation.

    Science.gov (United States)

    Pérez-Sirvent, Carmen; Martinez-Sanchez, Maria Jose; Garcia-Lorenzo, Maria Luz; Hernandez-Cordoba, Manuel

    2017-04-01

    The chemistry of waters is recognized as a relevant monitoring tool when assessing the adverse effects of acid mine drainage. The weathering of sulphide minerals produces a great variety of efflorescences of soluble sulphate salts. These minerals play an important role for environmental pollution, since they can be either a sink or a source for acidity and trace elements. This communication deals with the leachability of potentially toxic elements (PTE) eluting from technosols formed from soils affected by mining activities and limestone filler. A total of three contaminated soils affected by opencast mining were selected and mixed with limestone filler at three percentages: 10 %, 20 % and 30 %, providing nine stabilised samples. These samples were stored in containers and moistened simulating rainfall. The percolates obtained were collected, and the PTEs content (As, Cd, Cu, Fe, Pb and Zn) was determined. Evaporation-precipitation experiments were carried out in these waters, and the mineralogical composition of efflorescences was evaluated. The study area is heavily polluted as a result of historical mining and processing activities, producing large amount of wastes, characterised by high trace elements content and acidic pH. The results obtained for the percolates after the rain episode showed that, before the stabilization approach, waters had an acidic pH, high electrical conductivity and high PTEs content. When these soils were mixed with 10, 20 and 30 % of limestone filler, the pH was neutral and the soluble trace element content strongly decreased, being under the detection limit when limestone percentage was 20 % and 30 %. The mineralogical composition of efflorescences before the stabilisation approach showed that predominant minerals were copiapite, followed by gypsum and bilinite. Other soluble sulphates were determined in lower percentage, such as hexahydrite, halotriquite or pickeringite. After the mixing with 10 % of limestone filler, the evaporates

  17. Negotiated Grammar Transformation

    NARCIS (Netherlands)

    V. Zaytsev (Vadim)

    2012-01-01

    htmlabstractIn this paper, we study controlled adaptability of metamodel transformations. We consider one of the most rigid metamodel transformation formalisms — automated grammar transformation with operator suites, where a transformation script is built in such a way that it is essentially meant

  18. On Hurwitz transformations

    International Nuclear Information System (INIS)

    Kibler, M.; Hage Hassan, M.

    1991-04-01

    A bibliography on the Hurwitz transformations is given. We deal here, with some details, with two particular Hurwitz transformations, viz, the R 4 → R 3 Kustaanheimo-Stiefel transformation and its R 8 → R 5 compact extension. These transformations are derived in the context of Fock-Bargmann-Schwinger calculus with special emphasis on angular momentum theory

  19. Generalized Fourier transforms classes

    DEFF Research Database (Denmark)

    Berntsen, Svend; Møller, Steen

    2002-01-01

    The Fourier class of integral transforms with kernels $B(\\omega r)$ has by definition inverse transforms with kernel $B(-\\omega r)$. The space of such transforms is explicitly constructed. A slightly more general class of generalized Fourier transforms are introduced. From the general theory...

  20. Mineralogical Control on Microbial Diversity in a Weathered Granite?

    Science.gov (United States)

    Gleeson, D.; Clipson, N.; McDermott, F.

    2003-12-01

    Mineral transformation reactions and the behaviour of metals in rock and soils are affected not only by physicochemical parameters but also by biological factors, particularly by microbial activity. Microbes inhabit a wide range of niches in surface and subsurface environments, with mineral-microbe interactions being generally poorly understood. The focus of this study is to elucidate the role of microbial activity in the weathering of common silicate minerals in granitic rocks. A site in the Wicklow Mountains (Ireland) has been identified that consists of an outcrop surface of Caledonian (ca. 400 million years old) pegmatitic granite from which large intact crystals of variably weathered muscovite, plagioclase, K-feldspar and quartz were sampled, together with whole-rock granite. Culture-based microbial approaches have been widely used to profile microbial communities, particularly from copiotrophic environments, but it is now well established that for oligotrophic environments such as those that would be expected on weathering faces, perhaps less than 1% of microbial diversity can be profiled by cultural means. A number of culture-independent molecular based approaches have been developed to profile microbial diversity and community structure. These rely on successfully isolating environmental DNA from a given environment, followed by the use of the polymerase chain reaction (PCR) to amplify the typically small quantities of extracted DNA. Amplified DNA can then be analysed using cloning based approaches as well as community fingerprinting systems such as denaturing gradient gel electrophoresis (DGGE), terminal restriction fragment length polymorphism (TRFLP) and ribosomal intergenic spacer analysis (RISA). Community DNA was extracted and the intergenic spacer region (ITS) between small (16S) and large (23S) bacterial subunit rRNA genes was amplified. RISA fragments were then electrophoresed on a non-denaturing polyacrylamide gel. Banding patterns suggest that

  1. Monochloramine Cometabolism by Nitrifying Biofilm Relevant ...

    Science.gov (United States)

    Recently, biological monochloramine removal (i.e., cometabolism) by a pure culture ammonia–oxidizing bacteria, Nitrosomonas europaea, and a nitrifying mixed–culture have been shown to increase monochloramine demand. Although important, these previous suspended culture batch kinetic experiments were not representative of drinking water distribution systems where bacteria grow predominantly as biofilm attached to pipe walls or sediments and physiological differences may exist between suspension and biofilm growth. Therefore, the current research was an important next step in extending the previous results to investigate monochloramine cometabolism by biofilm grown in annular reactors under drinking water relevant conditions. Estimated monochloramine cometabolism kinetics were similar to those of ammonia metabolism, and monochloramine cometabolism was a significant loss mechanism (25–40% of the observed monochloramine loss). These results demonstrated that monochloramine cometabolism occurred in drinking water relevant nitrifying biofilm; thus, cometabolism may be a significant contribution to monochloramine loss during nitrification episodes in distribution systems. Investigate whether or not nitrifying biofilm can biologically transform monochloramine under drinking water relevant conditions.

  2. An integrated view of the chemistry and mineralogy of martian soils

    Science.gov (United States)

    Yen, A. S.; Gellert, Ralf; Schroder, C.; Morris, R.V.; Bell, J.F.; Knudson, A.T.; Clark, B. C.; Ming, D. W.; Crisp, J.A.; Arvidson, R. E.; Blaney, D.; Brückner, J.; Christensen, P.R.; DesMarais, D.J.; De Souza, P.A.; Economou, T.E.; Ghosh, A.; Hahn, B.C.; Herkenhoff, K. E.; Haskin, L.A.; Hurowitz, J.A.; Joliff, B.L.; Johnson, J. R.; Klingelhofer, G.; Madsen, M.B.; McLennan, S.M.; McSween, H.Y.; Richter, L.; Rieder, R.; Rodionov, D.; Soderblom, L.; Squyres, S. W.; Tosca, N.J.; Wang, A.; Wyatt, M.; Zipfel, J.

    2005-01-01

    The mineralogical and elemental compositions of the martian soil are indicators of chemical and physical weathering processes. Using data from the Mars Exploration Rovers, we show that bright dust deposits on opposite sides of the planet are part of a global unit and not dominated by the composition of local rocks. Dark soil deposits at both sites have similar basaltic mineralogies, and could reflect either a global component or the general similarity in the compositions of the rocks from which they were derived. Increased levels of bromine are consistent with mobilization of soluble salts by thin films of liquid water, but the presence of olivine in analysed soil samples indicates that the extent of aqueous alteration of soils has been limited. Nickel abundances are enhanced at the immediate surface and indicate that the upper few millimetres of soil could contain up to one per cent meteoritic material.

  3. X-ray Diffraction Results from Mars Science Laboratory: Mineralogy of Rocknest at Gale Crater

    Science.gov (United States)

    Bish, D. L.; Blake, D. F.; Vaniman, D. T.; Chipera, S. J.; Morris, R. V.; Ming, D. W.; Treiman, A. H.; Sarrazin, P.; Morrison, S. M.; Downs, R. T.; Achilles, C. N.; Yen, A. S.; Bristow, T. F.; Crisp, J. A.; Morookian, J. M.; Farmer, J. D.; Rampe, E. B.; Stolper, E. M.; Spanovich, N.; Achilles, Cherie; Agard, Christophe; Verdasca, José Alexandre Alves; Anderson, Robert; Anderson, Ryan; Archer, Doug; Armiens-Aparicio, Carlos; Arvidson, Ray; Atlaskin, Evgeny; Atreya, Sushil; Aubrey, Andrew; Baker, Burt; Baker, Michael; Balic-Zunic, Tonci; Baratoux, David; Baroukh, Julien; Barraclough, Bruce; Bean, Keri; Beegle, Luther; Behar, Alberto; Bell, James; Bender, Steve; Benna, Mehdi; Bentz, Jennifer; Berger, Gilles; Berger, Jeff; Berman, Daniel; Bish, David; Blake, David F.; Avalos, Juan J. Blanco; Blaney, Diana; Blank, Jen; Blau, Hannah; Bleacher, Lora; Boehm, Eckart; Botta, Oliver; Böttcher, Stephan; Boucher, Thomas; Bower, Hannah; Boyd, Nick; Boynton, Bill; Breves, Elly; Bridges, John; Bridges, Nathan; Brinckerhoff, William; Brinza, David; Bristow, Thomas; Brunet, Claude; Brunner, Anna; Brunner, Will; Buch, Arnaud; Bullock, Mark; Burmeister, Sönke; Cabane, Michel; Calef, Fred; Cameron, James; Campbell, John "Iain"; Cantor, Bruce; Caplinger, Michael; Rodríguez, Javier Caride; Carmosino, Marco; Blázquez, Isaías Carrasco; Charpentier, Antoine; Chipera, Steve; Choi, David; Clark, Benton; Clegg, Sam; Cleghorn, Timothy; Cloutis, Ed; Cody, George; Coll, Patrice; Conrad, Pamela; Coscia, David; Cousin, Agnès; Cremers, David; Crisp, Joy; Cros, Alain; Cucinotta, Frank; d'Uston, Claude; Davis, Scott; Day, Mackenzie "Kenzie"; Juarez, Manuel de la Torre; DeFlores, Lauren; DeLapp, Dorothea; DeMarines, Julia; DesMarais, David; Dietrich, William; Dingler, Robert; Donny, Christophe; Downs, Bob; Drake, Darrell; Dromart, Gilles; Dupont, Audrey; Duston, Brian; Dworkin, Jason; Dyar, M. Darby; Edgar, Lauren; Edgett, Kenneth; Edwards, Christopher; Edwards, Laurence; Ehlmann, Bethany; Ehresmann, Bent; Eigenbrode, Jen; Elliott, Beverley; Elliott, Harvey; Ewing, Ryan; Fabre, Cécile; Fairén, Alberto; Farley, Ken; Farmer, Jack; Fassett, Caleb; Favot, Laurent; Fay, Donald; Fedosov, Fedor; Feldman, Jason; Feldman, Sabrina; Fisk, Marty; Fitzgibbon, Mike; Flesch, Greg; Floyd, Melissa; Flückiger, Lorenzo; Forni, Olivier; Fraeman, Abby; Francis, Raymond; François, Pascaline; Franz, Heather; Freissinet, Caroline; French, Katherine Louise; Frydenvang, Jens; Gaboriaud, Alain; Gailhanou, Marc; Garvin, James; Gasnault, Olivier; Geffroy, Claude; Gellert, Ralf; Genzer, Maria; Glavin, Daniel; Godber, Austin; Goesmann, Fred; Goetz, Walter; Golovin, Dmitry; Gómez, Felipe Gómez; Gómez-Elvira, Javier; Gondet, Brigitte; Gordon, Suzanne; Gorevan, Stephen; Grant, John; Griffes, Jennifer; Grinspoon, David; Grotzinger, John; Guillemot, Philippe; Guo, Jingnan; Gupta, Sanjeev; Guzewich, Scott; Haberle, Robert; Halleaux, Douglas; Hallet, Bernard; Hamilton, Vicky; Hardgrove, Craig; Harker, David; Harpold, Daniel; Harri, Ari-Matti; Harshman, Karl; Hassler, Donald; Haukka, Harri; Hayes, Alex; Herkenhoff, Ken; Herrera, Paul; Hettrich, Sebastian; Heydari, Ezat; Hipkin, Victoria; Hoehler, Tori; Hollingsworth, Jeff; Hudgins, Judy; Huntress, Wesley; Hurowitz, Joel; Hviid, Stubbe; Iagnemma, Karl; Indyk, Steve; Israël, Guy; Jackson, Ryan; Jacob, Samantha; Jakosky, Bruce; Jensen, Elsa; Jensen, Jaqueline Kløvgaard; Johnson, Jeffrey; Johnson, Micah; Johnstone, Steve; Jones, Andrea; Jones, John; Joseph, Jonathan; Jun, Insoo; Kah, Linda; Kahanpää, Henrik; Kahre, Melinda; Karpushkina, Natalya; Kasprzak, Wayne; Kauhanen, Janne; Keely, Leslie; Kemppinen, Osku; Keymeulen, Didier; Kim, Myung-Hee; Kinch, Kjartan; King, Penny; Kirkland, Laurel; Kocurek, Gary; Koefoed, Asmus; Köhler, Jan; Kortmann, Onno; Kozyrev, Alexander; Krezoski, Jill; Krysak, Daniel; Kuzmin, Ruslan; Lacour, Jean Luc; Lafaille, Vivian; Langevin, Yves; Lanza, Nina; Lasue, Jeremie; Le Mouélic, Stéphane; Lee, Ella Mae; Lee, Qiu-Mei; Lees, David; Lefavor, Matthew; Lemmon, Mark; Malvitte, Alain Lepinette; Leshin, Laurie; Léveillé, Richard; Lewin-Carpintier, Éric; Lewis, Kevin; Li, Shuai; Lipkaman, Leslie; Little, Cynthia; Litvak, Maxim; Lorigny, Eric; Lugmair, Guenter; Lundberg, Angela; Lyness, Eric; Madsen, Morten; Mahaffy, Paul; Maki, Justin; Malakhov, Alexey; Malespin, Charles; Malin, Michael; Mangold, Nicolas; Manhes, Gérard; Manning, Heidi; Marchand, Geneviève; Jiménez, Mercedes Marín; García, César Martín; Martin, Dave; Martin, Mildred; Martínez-Frías, Jesús; Martín-Soler, Javier; Martín-Torres, F. Javier; Mauchien, Patrick; Maurice, Sylvestre; McAdam, Amy; McCartney, Elaina; McConnochie, Timothy; McCullough, Emily; McEwan, Ian; McKay, Christopher; McLennan, Scott; McNair, Sean; Melikechi, Noureddine; Meslin, Pierre-Yves; Meyer, Michael; Mezzacappa, Alissa; Miller, Hayden; Miller, Kristen; Milliken, Ralph; Ming, Douglas; Minitti, Michelle; Mischna, Michael; Mitrofanov, Igor; Moersch, Jeff; Mokrousov, Maxim; Jurado, Antonio Molina; Moores, John; Mora-Sotomayor, Luis; Morookian, John Michael; Morris, Richard; Morrison, Shaunna; Mueller-Mellin, Reinhold; Muller, Jan-Peter; Caro, Guillermo Muñoz; Nachon, Marion; López, Sara Navarro; Navarro-González, Rafael; Nealson, Kenneth; Nefian, Ara; Nelson, Tony; Newcombe, Megan; Newman, Claire; Newsom, Horton; Nikiforov, Sergey; Niles, Paul; Nixon, Brian; Dobrea, Eldar Noe; Nolan, Thomas; Oehler, Dorothy; Ollila, Ann; Olson, Timothy; Owen, Tobias; Hernández, Miguel Ángel de Pablo; Paillet, Alexis; Pallier, Etienne; Palucis, Marisa; Parker, Timothy; Parot, Yann; Patel, Kiran; Paton, Mark; Paulsen, Gale; Pavlov, Alex; Pavri, Betina; Peinado-González, Verónica; Pepin, Robert; Peret, Laurent; Perez, Rene; Perrett, Glynis; Peterson, Joe; Pilorget, Cedric; Pinet, Patrick; Pla-García, Jorge; Plante, Ianik; Poitrasson, Franck; Polkko, Jouni; Popa, Radu; Posiolova, Liliya; Posner, Arik; Pradler, Irina; Prats, Benito; Prokhorov, Vasily; Purdy, Sharon Wilson; Raaen, Eric; Radziemski, Leon; Rafkin, Scot; Ramos, Miguel; Rampe, Elizabeth; Raulin, François; Ravine, Michael; Reitz, Günther; Rennó, Nilton; Rice, Melissa; Richardson, Mark; Robert, François; Robertson, Kevin; Manfredi, José Antonio Rodriguez; Romeral-Planelló, Julio J.; Rowland, Scott; Rubin, David; Saccoccio, Muriel; Salamon, Andrew; Sandoval, Jennifer; Sanin, Anton; Fuentes, Sara Alejandra Sans; Saper, Lee; Sarrazin, Philippe; Sautter, Violaine; Savijärvi, Hannu; Schieber, Juergen; Schmidt, Mariek; Schmidt, Walter; Scholes, Daniel "Dan"; Schoppers, Marcel; Schröder, Susanne; Schwenzer, Susanne; Martinez, Eduardo Sebastian; Sengstacken, Aaron; Shterts, Ruslan; Siebach, Kirsten; Siili, Tero; Simmonds, Jeff; Sirven, Jean-Baptiste; Slavney, Susie; Sletten, Ronald; Smith, Michael; Sánchez, Pablo Sobrón; Spanovich, Nicole; Spray, John; Squyres, Steven; Stack, Katie; Stalport, Fabien; Steele, Andrew; Stein, Thomas; Stern, Jennifer; Stewart, Noel; Stipp, Susan Louise Svane; Stoiber, Kevin; Stolper, Ed; Sucharski, Bob; Sullivan, Rob; Summons, Roger; Sumner, Dawn; Sun, Vivian; Supulver, Kimberley; Sutter, Brad; Szopa, Cyril; Tan, Florence; Tate, Christopher; Teinturier, Samuel; ten Kate, Inge; Thomas, Peter; Thompson, Lucy; Tokar, Robert; Toplis, Mike; Redondo, Josefina Torres; Trainer, Melissa; Treiman, Allan; Tretyakov, Vladislav; Urqui-O'Callaghan, Roser; Van Beek, Jason; Van Beek, Tessa; VanBommel, Scott; Vaniman, David; Varenikov, Alexey; Vasavada, Ashwin; Vasconcelos, Paulo; Vicenzi, Edward; Vostrukhin, Andrey; Voytek, Mary; Wadhwa, Meenakshi; Ward, Jennifer; Webster, Chris; Weigle, Eddie; Wellington, Danika; Westall, Frances; Wiens, Roger Craig; Wilhelm, Mary Beth; Williams, Amy; Williams, Joshua; Williams, Rebecca; Williams, Richard B. "Mouser"; Wilson, Mike; Wimmer-Schweingruber, Robert; Wolff, Mike; Wong, Mike; Wray, James; Wu, Megan; Yana, Charles; Yen, Albert; Yingst, Aileen; Zeitlin, Cary; Zimdar, Robert; Mier, María-Paz Zorzano

    2013-09-01

    The Mars Science Laboratory rover Curiosity scooped samples of soil from the Rocknest aeolian bedform in Gale crater. Analysis of the soil with the Chemistry and Mineralogy (CheMin) x-ray diffraction (XRD) instrument revealed plagioclase (~An57), forsteritic olivine (~Fo62), augite, and pigeonite, with minor K-feldspar, magnetite, quartz, anhydrite, hematite, and ilmenite. The minor phases are present at, or near, detection limits. The soil also contains 27 ± 14 weight percent x-ray amorphous material, likely containing multiple Fe3+- and volatile-bearing phases, including possibly a substance resembling hisingerite. The crystalline component is similar to the normative mineralogy of certain basaltic rocks from Gusev crater on Mars and of martian basaltic meteorites. The amorphous component is similar to that found on Earth in places such as soils on the Mauna Kea volcano, Hawaii.

  4. Preliminary analysis in a clayey mass aimed at ceramic blocks production: physical and mineralogical characteristics

    International Nuclear Information System (INIS)

    Silva, L.J.M.D. da; Apolonio, T.G.; Salviano, A.F.; Taveira, S.K.A.; Garcia, T.G.C.; Silva, J; Luna, P.A.; Macedo, R.S.

    2016-01-01

    The physical, chemical and mineralogical characterization of the clayey mass are important in determining its properties, allowing a better knowledge of the raw material used in the manufacture of ceramic products. This work aims to characterize the raw material used in the manufacture of ceramic sealing blocks in a ceramic industry. Thus, it was evaluated by laboratory tests the raw material used in the production of ceramic blocks in a ceramics industry in the region of Carnauba dos Dantas, RN. The methodology used in the tests is the same as the IPT, which consists in carrying out the plasticity testing, particle size, chemical analysis and X-ray diffraction. Results indicate that the sample studied by the physical and mineralogical characteristics, has the potential to be applied in the manufacture of red ceramic products for use in construction. (author)

  5. Mechanical properties of cohesive soils in dependence on the water quantity and mineralogical composition

    Directory of Open Access Journals (Sweden)

    Ludvik Trauner

    2003-12-01

    Full Text Available This article explains the relationships between the water content, mineralogical properties and mechanical properties of saturated clays. The findings are based on theoretical analysis and were confirmed experimentally on monomineral clay samples. It was foundthat the quantity of intergrain water, which determines the undrained shear strength and compressibility of clays, consists of free pore water, and the firmly adsorbed water on the external surfaces of the clay grains. The free water quantity is the same for differentsaturated clays, at the same undrained shear strength, and same effective stress after consolidation and, likewise, the thickness of the water film around the clay grains. The total quantity of firmly adsorbed water depends on the specific surfaces of the clays. Theresult of this work is a new analytical formulation that gives the relationship between the water content and the mechanical properties of clays, taking into account their mineralogical characteristics.

  6. Expected Geochemical and Mineralogical Properties of Meteorites from Mercury: Inferences from Messenger Data

    Science.gov (United States)

    McCubbin, F. M.; McCoy, T. J.

    2016-01-01

    Meteorites from the Moon, Mars, and many types of asteroid bodies have been identified among our global inventory of meteorites, however samples of Mercury and Venus have not been identified. The absence of mercurian and venusian meteorites could be attributed to an inability to recognize them in our collections due to a paucity of geochemical information for Venus and Mercury. In the case of mercurian meteorites, this possibility is further supported by dynamical calculations that suggest mercurian meteorites should be present on Earth at a factor of 2-3 less than meteorites from Mars [1]. In the present study, we focus on the putative mineralogy of mercurian meteorites using data obtained from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft, which has provided us with our first quantitative constraints on the geochemistry of planet Mercury. We have used the MESSENGER data to compile a list of mineralogical and geochemical characteristics that a meteorite from Mercury is likely to exhibit.

  7. Mineralogical characterization of selected shales in support of nuclear waste repository studies: Progress report

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.Y.; Hyder, L.K.; Alley, P.D.

    1987-12-01

    Because baseline characterization of shale mineralogy is critical to the interpretation of results from experiments on radionuclide retardation, groundwater-shale interactions, and physicochemical characteristics, a protocol for quantitative mineralogical analyses has been developed by integrating geochemical and instrumental techniques for the investigation of properties related to repository performance. Thermal analyses were used to estimate total organic matter and carbonate mineral contents. Scanning electron microscope backscattering and elemental mapping of polished sectors and particle-size distribution data were used to estimate the amounts of quartz plus feldspar and pyrite in the shales. X-ray diffraction, neutron activation, and size-distribution data were utilized to estimate phyllosilicate mineral contents. High-resolution transmission electron microscopy was used to identify clay mineral components.

  8. Mineralogical characterization of selected shales in support of nuclear waste repository studies: Progress report

    International Nuclear Information System (INIS)

    Lee, S.Y.; Hyder, L.K.; Alley, P.D.

    1987-12-01

    Because baseline characterization of shale mineralogy is critical to the interpretation of results from experiments on radionuclide retardation, groundwater-shale interactions, and physicochemical characteristics, a protocol for quantitative mineralogical analyses has been developed by integrating geochemical and instrumental techniques for the investigation of properties related to repository performance. Thermal analyses were used to estimate total organic matter and carbonate mineral contents. Scanning electron microscope backscattering and elemental mapping of polished sectors and particle-size distribution data were used to estimate the amounts of quartz plus feldspar and pyrite in the shales. X-ray diffraction, neutron activation, and size-distribution data were utilized to estimate phyllosilicate mineral contents. High-resolution transmission electron microscopy was used to identify clay mineral components

  9. Characterisation of some Clays Used for Whiteware Ceramics I. Mineralogical composition

    Directory of Open Access Journals (Sweden)

    Marcel Benea

    2002-04-01

    Full Text Available In order to obtain a semiquantitative mineralogical composition of raw materials used for whiteware ceramics, four different clay types were analysed by X-ray diffraction. Studies were carried out by using a combination of analyses of the bulk sample, and of the fine fraction. Using a well-established pre-treatment methodology (use of chemicals, ultrasonic treatment, dispersion procedures, clay mineral concentration by centrifugation and sedimentation, oriented and random powder preparation, cation saturation, expansion/dehydration methods, 12 X-ray diffractometer traces were obtained from each sample. Based on these informations it was possible to establish the qualitative mineralogical composition, and also a semiquantitative one using peak intensities and peak area corrected by various factors. Scanning electron microscopy was also used in order to illustrate the identified mineral phases.

  10. Thermal and mineralogical characterization of drill cuttings from north capixaba: initial studies

    International Nuclear Information System (INIS)

    Fialho, P.F.; Goncalves, G. dos R.; Calmon, J.L.; Tristao, F.A.; Nunes, E.; Cunha, A.G.

    2011-01-01

    The drilling of oil wells generates various wastes among which are the cuttings and drilling fluids. The management of these wastes have been a problem for the oil and gas industry because of the amount generated and its contaminants, which can be organic and inorganic. This paper presents initial studies of thermal and mineralogical characterization of the drill cuttings from oil wells and gas in Southeast Brazilian, state of Espirito Santo with aim of reuse them as raw material in building materials. Characterizations were performed physical, thermal and mineralogical by particle size distribution, thermogravimetric analysis, differential scanning calorimetry and X-ray diffraction. The results indicate that there are potential replacements of natural raw materials or drill cuttings in the production of building materials. (author)

  11. Mineralogical characterization of quarry fines from Tracuateua city, state of Para, Brazil

    International Nuclear Information System (INIS)

    Costa, J.H.B. da; Negrao, R.C.; Angelica, R.S.; Universidade Federal do Para

    2011-01-01

    The aim of this study was to characterize the mineralogy quarry fines samples for its reuse and thus contributing to mitigate the environmental impact caused by this waste. In order to achieve the results, samples were collected and prepared for assays and identification of the mineralogical phases present in the quarry fines from the samples. X-ray diffraction and optical microscopy techniques were used. The quarry of fines characterization was based on qualitatively identification the minerals present in the samples. It was detected the presence of quartz, muscovite and feldspar (albite and microclinite) by x-ray diffraction technique and microscopic and macroscopic observations. Moreover, the size distribution was determined, and the samples presented a medium to fine size (ranging from 9,5 mm to 0,075 mm) and the grains presented an irregular and angular shapes. (author)

  12. Mineralogical test as a preliminary step for metallurgical proses of Kalan ores

    International Nuclear Information System (INIS)

    Affandi, K.

    1998-01-01

    Mineralogical tests as a preliminary step for hydrometallurgy of Kalan ores, including Eko Remaja and Rirang have been carried out to identify the elements and minerals content which affect the metallurgical process, especially the leaching and purification of uranium. Mineralogical tests have been done by means of radioactive and radioluxugraph tests to identify radioactive minerals; thin specimen analysis, Scanning Electron Microscopy (SEM) to identify elements and morphology, EPMA to analyse qualitatively the elements, X-ray Diffractometer (XRD) to identify of minerals content; and X-ray Fluorescence (XRF) and chemical analyses to determine total elements qualitatively and quantitatively. The experimental results show that the Eko Remaja ores contain uraninite and brannerite, iron and titan oxides, sulfides, phosphates and silicates minerals, while the Rirang ores contain uraninite, monazite and molybdenite

  13. Confidence Hills Mineralogy and Chemin Results from Base of Mt. Sharp, Pahrump Hills, Gale Crater, Mars

    Science.gov (United States)

    Cavanagh, P. D.; Bish, D. L.; Blake, D. F.; Vaniman, D. T.; Morris, R. V.; Ming, D. W.; Rampe, E. B.; Achilles, C. N.; Chipera, S. J.; Treiman, A. H.; hide

    2015-01-01

    The Mars Science Laboratory (MSL) rover Curiosity recently completed its fourth drill sampling of sediments on Mars. The Confidence Hills (CH) sample was drilled from a rock located in the Pahrump Hills region at the base of Mt. Sharp in Gale Crater. The CheMin X-ray diffractometer completed five nights of analysis on the sample, more than previously executed for a drill sample, and the data have been analyzed using Rietveld refinement and full-pattern fitting to determine quantitative mineralogy. Confidence Hills mineralogy has several important characteristics: 1) abundant hematite and lesser magnetite; 2) a 10 angstrom phyllosilicate; 3) multiple feldspars including plagioclase and alkali feldspar; 4) mafic silicates including forsterite, orthopyroxene, and two types of clinopyroxene (Ca-rich and Ca-poor), consistent with a basaltic source; and 5) minor contributions from sulfur-bearing species including jarosite.

  14. Influence of Oxygen and Nitrate on Fe (Hydr)oxide Mineral Transformation and Soil Microbial Communities during Redox Cycling.

    Science.gov (United States)

    Mejia, Jacqueline; Roden, Eric E; Ginder-Vogel, Matthew

    2016-04-05

    Oscillations between reducing and oxidizing conditions are observed at the interface of anaerobic/oxic and anaerobic/anoxic environments, and are often stimulated by an alternating flux of electron donors (e.g., organic carbon) and electron acceptors (e.g., O2 and NO3(-)). In iron (Fe) rich soils and sediments, these oscillations may stimulate the growth of both Fe-reducing bacteria (FeRB) and Fe-oxidizing bacteria (FeOB), and their metabolism may induce cycling between Fe(II) and Fe(III), promoting the transformation of Fe (hydr)oxide minerals. Here, we examine the mineralogical evolution of lepidocrocite and ferrihydrite, and the adaptation of a natural microbial community to alternating Fe-reducing (anaerobic with addition of glucose) and Fe-oxidizing (with addition of nitrate or air) conditions. The growth of FeRB (e.g., Geobacter) is stimulated under anaerobic conditions in the presence of glucose. However, the abundance of these organisms depends on the availability of Fe(III) (hydr)oxides. Redox cycling with nitrate results in decreased Fe(II) oxidation thereby decreasing the availability of Fe(III) for FeRB. Additionally, magnetite is detected as the main product of both lepidocrocite and ferrihydrite reduction. In contrast, introduction of air results in increased Fe(II) oxidation, increasing the availability of Fe(III) and the abundance of Geobacter. In the lepidocrocite reactors, Fe(II) oxidation by dissolved O2 promotes the formation of ferrihydrite and lepidocrocite, whereas in the ferrihydrite reactors we observe a decrease in magnetite stoichiometry (e.g., oxidation). Understanding Fe (hydr)oxide transformation under environmentally relevant redox cycling conditions provides insight into nutrient availability and transport, contaminant mobility, and microbial metabolism in soils and sediments.

  15. Transforming the Way We Teach Function Transformations

    Science.gov (United States)

    Faulkenberry, Eileen Durand; Faulkenberry, Thomas J.

    2010-01-01

    In this article, the authors discuss "function," a well-defined rule that relates inputs to outputs. They have found that by using the input-output definition of "function," they can examine transformations of functions simply by looking at changes to input or output and the respective changes to the graph. Applying transformations to the input…

  16. Mineralogical characterization of the argillaceous material from the Municipality of Santa Barbara, Para, Brazil

    International Nuclear Information System (INIS)

    Hildebrando, E.A.; Sheller, T.; Angelica, R.S.; Neves, R.S.

    2009-01-01

    In the present work were investigated mineralogical phases in a material with argillaceous characteristic of the region of Genipauba, Santa Barbara, State of Para. Characterization of the collected sample was performed by X-ray diffraction (XRD), differential thermal analysis (DTA), thermogravimetric analysis (TG) and infrared spectroscopy (IR). The results of the assays indicate the presence of the clay minerals like kaolinite and muscovite, as well as minerals as quartz and anatase. (author)

  17. Mineralogy of Fluvio-Lacustrine Sediments Investigated by Curiosity During the Prime Mission: Implications for Diagenesis

    Science.gov (United States)

    Rampe, Elizabeth B.; Morris, R. V.; Bish, D. L.; Vaniman, D. T.; Bristow, T. F.; Chipera, S. J.; Blake, D. F.; Ming, D. W.; Farmer, J. D.; Morrison, S. M.; hide

    2014-01-01

    The Mars Science Laboratory rover Curiosity investigated sedimentary rocks that were deposited in a diversity of fluvio-lacustrine settings. The entire science payload was employed to characterize the mineralogy and chemistry of the Sheepbed mudstone at Yellowknife Bay and the Windjana sandstone at the Kimberley. Data from the CheMin instrument, a transmission Xray diffractometer, were used to determine the quantitative mineralogy of both samples. The Sheepbed mudstone contains detrital basaltic minerals, calcium sulfates, iron oxides or hydroxides, iron sulfides, trioctahedral smectite, and amorphous material. The mineral assemblage and chemical data from APXS suggest that the trioctahedral smectite and magnetite formed authigenically as a result of alteration of olivine. The apparent lack of higher-grade phyllosilicates (e.g., illite and chlorite) and the presence of anhydrite indicate diagenesis at 50- 80 ºC. The mineralogy of the Windjana sandstone is different than the Sheepbed mudstone. Windjana contains significant abundances of K-feldspar, low- and high-Ca pyroxenes, magnetite, phyllosilicates, and amorphous material. At least two distinct phyllosilicate phases exist: a 10 Å phase and a component that is expanded with a peak at 11.8 Å. The identity of the expanded phase is currently unknown, but could be a smectite with interlayer H2O, and the 10 Å phase could be illite or collapsed smectite. Further work is necessary to characterize the phyllosilicates, but the presence of illite could suggest that Windjana experienced burial diagenesis. Candidates for the cementing agents include fine-grained phyllosilicates, Fe-oxides, and/or amorphous material. Interpretations of CheMin data from the Windjana sandstone are ongoing at the time of writing, but we will present an estimate of the composition of the amorphous material from mass balance calculations using the APXS bulk chemistry and quantitative mineralogy from CheMin.

  18. A Mineralogical Assessment on Residues after Acidic Leaching of Bauxite Residue (Red Mud) for Titanium Recovery

    OpenAIRE

    Gözde Alkan; Claudia Schier; Lars Gronen; Srecko Stopic; Bernd Friedrich

    2017-01-01

    Due to its alkalinity, red mud produced by the Bayer process may affect both the environment and human health. For this reason, its further utilization instead of disposal is of great importance. Numerous methods have already been studied for hydrometallurgical treatment of red mud, especially for the recovery of various metallic components such as iron, aluminum, titanium or rare earth elements. This study focuses on the extraction of titanium from red mud and in particular the mineralogical...

  19. Study of bismuth minerals belonging to the mineralogical collection from the National Museum

    International Nuclear Information System (INIS)

    Baptista, A.; Baptista, N.R.

    1991-09-01

    With the purpose of searching the presence of Tellurium minerals in the Ouro Preto-Mariana country, Minas Gerais State, and considering the existence of a great number of minerals in which this element come across allied with Bismuth, samples of the mineralogical collection of the Museu Nacional, proceeding that region and classified as Bismuth minerals were studied by X-ray fluorescence analysis and diffractometric analysis. In this report the results of this research are presented. (Author)

  20. Using mineralogy as a guide to understanding slagging: a case study

    Energy Technology Data Exchange (ETDEWEB)

    Creelman, R.A. [R.A. Creelman & Associates (Australia)

    1994-12-31

    This paper details the mineralogy that accompanied the Callide B Power station slagging investigations. Investigations were made of coal mineral matter, particles collected from the furnace, flyash and the slag deposits. Objectives were to characterise the particles formed from burning Callide coal, to relate them to the slag deposits and flyash, and by applying thermodynamics gain an understanding of the underlying mechanisms that lead to attachment and accumulation of particles in the furnace. 9 refs., 2 figs., 7 tabs.

  1. Mineralogical Study of Zard Koh and Kulli Koh Iron Ore Deposits of Pakistan

    Directory of Open Access Journals (Sweden)

    SULTAN AHMED KHOSO

    2017-10-01

    Full Text Available Zard Koh and Kulli Koh are two recently discovered iron ore deposits, existing in the Chagai district, Balochistan, Pakistan. PSM (Pakistan Steel Mill Limited is interested to utilize these ore deposits at priority. Purpose of the present study was to assess the mineralogy of the Zard Koh and Kulli Koh iron ore deposits, as it plays a vital role in the selection of an appropriate processing method. The mineralogical study of ore deposits was carried out by XRD (X-Ray Diffraction, XRF (X-Ray Fluorescence, SEM (Scanning Electron Microscope attached with EDS (Energy Dispersive Spectroscope and SM (Stereomicroscope techniques. Results indicated that the Zard Koh ore is mainly composed of 60.15% maghemite, 23.57% pyrite, 4.07% chlorite, 10.30% grossular and 1.65% admontite minerals. The chemical analysis revealed that Zard Koh iron ore contains an average of 54.27% Fe, 12.73% S, 8.70% Si, 3.07% Al, 4.07% Ca, and 2.16% Mg. Similarly, the mineralogical study of the Kulli Koh iron ore indicated that, ore is containing 51.16% hematite, 29.24% quartz, 8.89% dravite, and 8.76% kaolinite minerals. Elemental analysis of different samples indicated that Kulli Koh iron ore contains an average composition of 40.23% Fe, 20.67% Si, 3.44% Ca, 3.81% Al and 3.25% Mg. Mineralogical study of the Zard Koh and Kulli Koh iron ore deposits suggested that these ore deposits can be beneficiated costeffectively by using magnetic separation techniques.

  2. Mineralogical impact on long-term patterns of soil nitrogen and phosphorus enzyme activities

    Science.gov (United States)

    Mikutta, Robert; Turner, Stephanie; Meyer-Stüve, Sandra; Guggenberger, Georg; Dohrmann, Reiner; Schippers, Axel

    2014-05-01

    Soil chronosequences provide a unique opportunity to study microbial activity over time in mineralogical diverse soils of different ages. The main objective of this study was to test the effect of mineralogical properties, nutrient and organic matter availability over whole soil pro-files on the abundance and activity of the microbial communities. We focused on microbio-logical processes involved in nitrogen and phosphorus cycling at the 120,000-year Franz Josef soil chronosequence. Microbial abundances (microbial biomass and total cell counts) and enzyme activities (protease, urease, aminopeptidase, and phosphatase) were determined and related to nutrient contents and mineralogical soil properties. Both, microbial abundances and enzyme activities decreased with soil depth at all sites. In the organic layers, microbial biomass and the activities of N-hydrolyzing enzymes showed their maximum at the intermediate-aged sites, corresponding to a high aboveground biomass. In contrast, the phosphatase activity increased with site age. The activities of N-hydrolyzing enzymes were positively correlated with total carbon and nitrogen contents, whereas the phosphatase activity was negatively correlated with the phosphorus content. In the mineral soil, the enzyme activities were generally low, thus reflecting the presence of strongly sorbing minerals. Sub-strate-normalized enzyme activities correlated negatively to clay content as well as poorly crystalline Al and Fe oxyhydroxides, supporting the view that the evolution of reactive sec-ondary mineral phases alters the activity of the microbial communities by constraining sub-strate availability. Our data suggest a strong mineralogical influence on nutrient cycling par-ticularly in subsoil environments.

  3. Qualitative mineralogical characterization of the sinter by X-ray diffraction

    International Nuclear Information System (INIS)

    Greca, M.C.; Pietroluongo, L.R.V.; Baliza, S.V.; Costa Pereira, E.A. da

    1987-01-01

    This paper aims the qualitative mineralogical characterization of sinters and raw materials employed on its fabrication, via X-ray diffraction technique. Thus, sample with constant coke breeze content and variable contents of sand, limestone, dunite and dolomite were prepared to obtain current sinter compositions, with variable basicity. The tests were performed at the research of the following institutions: Companhia Siderurgica Nacional, Centro de Tecnologia Mineral and Instituto Nacional de Tecnologia. (author) [pt

  4. Mineralogical Study of Workable Material Coming from Mina Fe Ciudad Rodrigo

    International Nuclear Information System (INIS)

    Mingarro Martin, E.

    1962-01-01

    A mineralogical analysis is made to ascertain the effects of acid bleaching on normalized conditions. Uranium is mainly found under uranotile, pitchblende and autunite form with an average assay of 0.4 p. ct. The loss of uranium in tailings under current conditions of attach, mainly is due to pitchblende resistance, being practically no leachable, and to uranium absorption by hydrated iron oxides and colloidal ores. This last problem will be discussed in a next paper. (Author) 5 refs

  5. Mineralogical study of zard koh and kulli koh iron ore deposits of pakistan

    International Nuclear Information System (INIS)

    Khoso, S.A.; Abro, M.I.

    2017-01-01

    Zard Koh and Kulli Koh are two recently discovered iron ore deposits, existing in the Chagai district, Balochistan, Pakistan. PSM (Pakistan Steel Mill Limited) is interested to utilize these ore deposits at priority. Purpose of the present study was to assess the mineralogy of the Zard Koh and Kulli Koh iron ore deposits, as it plays a vital role in the selection of an appropriate processing method. The mineralogical study of ore deposits was carried out by XRD (X-Ray Diffraction), XRF (X-Ray Fluorescence), SEM (Scanning Electron Microscope) attached with EDS (Energy Dispersive Spectroscope) and SM (Stereomicroscope) techniques. Results indicated that the Zard Koh ore is mainly composed of 60.15% maghemite, 23.57% pyrite, 4.07% chlorite, 10.30% grossular and 1.65% admontite minerals. The chemical analysis revealed that Zard Koh iron ore contains an average of 54.27% Fe, 12.73% S, 8.70% Si, 3.07% Al, 4.07% Ca, and 2.16% Mg. Similarly, the mineralogical study of the Kulli Koh iron ore indicated that, ore is containing 51.16% hematite, 29.24% quartz, 8.89% dravite, and 8.76% kaolinite minerals. Elemental analysis of different samples indicated that Kulli Koh iron ore contains an average composition of 40.23% Fe, 20.67% Si, 3.44% Ca, 3.81% Al and 3.25% Mg. Mineralogical study of the Zard Koh and Kulli Koh iron ore deposits suggested that these ore deposits can be beneficiated costeffectively by using magnetic separation techniques. (author)

  6. Mineralogy, Petrology, Chronology, and Exposure History of the Chelyabinsk Meteorite and Parent Body

    Science.gov (United States)

    Righter, K.; Abell, P.; Agresti, D.; Berger, E. L.; Burton, A. S.; Delaney, J. S.; Fries, M. D.; Gibson, E. K.; Harrington, R.; Herzog, G. F.; hide

    2015-01-01

    The Chelyabinsk meteorite fall on February 15, 2013 attracted much more attention worldwide than do most falls. A consortium led by JSC received 3 masses of Chelyabinsk (Chel-101, -102, -103) that were collected shortly after the fall and handled with care to minimize contamination. Initial studies were reported in 2013; we have studied these samples with a wide range of analytical techniques to better understand the mineralogy, petrology, chronology and exposure history of the Chelyabinsk parent body.

  7. Mineralogical, chemical and physical study of potential buffer and backfill materials from ABM. Test Package 1

    International Nuclear Information System (INIS)

    Kumpulainen, S.; Kiviranta, L.

    2011-07-01

    In the ABM experiment, three test packages with centre steel heaters surrounded by stacks of compacted bentonite rings of various clay materials were placed in boreholes in Aespoe tunnel. The first parcel was saturated with Aespoe groundwater and the heater was turned on simultaneously with the start of saturation. This parcel was excavated 30 months after its installation. Chemical, mineralogical and physical properties of the MX-80, Dep-CaN, Asha and Friedland clay samples from the ABM parcel 1 were analysed and compared to reference samples. Chemical analyses (ICP-AES, C, CO 3 , S, water soluble SO 4 , Fe 2+ /Fe 3+ ), exchangeable cation analyses, mineralogical analyses (XRD, FTIR) and selective extractions were used to determine changes in the chemistry and mineralogy of ABM materials. Swelling pressure and hydraulic conductivity measurements were performed both for extracted samples and for ground and recompacted samples. Major changes in exchangeable cation composition were observed in all samples originating from equilibration with Aespoe groundwater and interactions with equilibrated waters from neighbouring block materials. Some minor changes in chemical composition were observed as well. Increases in soluble sulphate content in the vicinity of the heater were thought to result from precipitation of sulphate salts. Decreases in sodium content and increases in calcium content were ascribed to changes in exchangeable cations. Interaction with iron was observed to occur only in the close vicinity (first few mm) of the heater. No significantly measureable change in mineralogical composition was seen in any of the studied materials. Extracted Dep-CaN samples showed a slight decrease in swelling pressure. However, when the material was ground, compacted and measured again the swelling pressure was fully recovered. No related change in hydraulic conductivities was observed. (orig.)

  8. Influence of the chemical, physical and mineralogical characteristics on the three latosoils compacting

    International Nuclear Information System (INIS)

    Fernandes, Rafael Braganca Alves; Fontes, Luiz Eduardo Ferreira; Costa, Liovando Marciano da

    1997-01-01

    This work studies the behavior of three brazilian latosoils (Purple, Una and yellow latosoils) concerning to the tendency of compacting, by using the trail analysis for evaluation of the physical, chemical, mineralogical and other compacting estimation effects on this process. Two conditions of soil use were considered: intensive cultivation, with field evaluation which indicates the compacting and not worked area, with natural forest or old and abandoned reforesting

  9. Mineralogical Studies Related to Endemic Diseases in Rural P. R. China

    Science.gov (United States)

    Belkin, H. E.; Zheng, B.; Finkelman, R. B.

    2003-12-01

    Domestic combustion of coal for heating and cooking is mostly confined to the world's developing countries and probably involves about 1 billion persons in China, India, Indonesia, and Africa. Various endemic diseases affecting millions of people involving arsenic, selenium, and fluorine poisoning have been associated with domestic coal combustion in rural China. We have investigated the relationship between mineralized coals (and stone coals) and disease occurrences in Guizhou and Hubei Provinces. The mineralogy of the coals has been studied by a wide variety of techniques, including optical petrography, scanning electron microscopy, electron microprobe analysis, ion probe, Synchrotron XANES-EXAFS, and Raman spectroscopy. Arsenic enrichment (up to 3 weight percent) in Upper Permian Longtan Formation coals, southwestern Guizhou Province, occurs in both 3+ and 5+ valence states. Arsenic occurs in arsenopyrite, pyrite, Al-phosphate, scorodite, Fe-oxides, and as an organically-bound species. Fluorine poisoning, much more widespread than arsenic-poisoning, is related to burning F-rich coals and F-rich clays as admixtures. Mineralogical and chemical analysis suggests that the clays contain the fluorine probably substituting for the hydroxyl group. Localized selenium poisoning in Hubei Province is related to Se-rich stone coals. The selenium occurs as a native element and in rare mandarinoite. In these three cases, knowledge of the paragenesis and mineralogy of the element enrichment in coal was vital to help understand and mitigate the endemic diseases. For the situation concerning arsenic and selenium poisoning, suspect coals have been identified and mining from these deposits has been curtailed. Fluorine has been a much more difficult problem for the local public health officials as both the coal and clay in the burning admixture can contain high fluorine. Regional geochemical and mineralogical studies will help to define coal and clay with low fluorine, suitable for

  10. Iron mineralogy and uranium-binding environment in the rhizosphere of a wetland soil

    Energy Technology Data Exchange (ETDEWEB)

    Kaplan, Daniel I., E-mail: daniel.kaplan@srnl.doe.gov [Savannah River National Laboratory, Aiken, SC 29808 (United States); Kukkadapu, Ravi [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Seaman, John C. [Savannah River Ecology Laboratory, University of Georgia, Aiken, SC 29802 (United States); Arey, Bruce W.; Dohnalkova, Alice C. [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Buettner, Shea [Savannah River Ecology Laboratory, University of Georgia, Aiken, SC 29802 (United States); Li, Dien [Savannah River National Laboratory, Aiken, SC 29808 (United States); Varga, Tamas [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Scheckel, Kirk G. [US Environmental Protection Agency, National Risk Management Research Laboratory, Cincinnati, OH 45224 (United States); Jaffé, Peter R. [Princeton University, Princeton, NJ 08540 (United States)

    2016-11-01

    Wetlands mitigate the migration of groundwater contaminants through a series of biogeochemical gradients that enhance multiple contaminant-binding processes. The hypothesis of this study was that wetland plant roots contribute organic carbon and release O{sub 2} within the rhizosphere (plant-impact soil zone) that promote the formation of Fe(III)-(oxyhydr)oxides. In turn, these Fe(III)-(oxyhydr)oxides stabilize organic matter that together contribute to contaminant immobilization. Mineralogy and U binding environments of the rhizosphere were evaluated in samples collected from contaminated and non-contaminated areas of a wetland on the Savannah River Site in South Carolina. Based on Mössbauer spectroscopy, rhizosphere soil was greatly enriched with nanogoethite, ferrihydrite-like nanoparticulates, and hematite, with negligible Fe(II) present. X-ray computed tomography and various microscopy techniques showed that root plaques were tens-of-microns thick and consisted of highly oriented Fe-nanoparticles, suggesting that the roots were involved in creating the biogeochemical conditions conducive to the nanoparticle formation. XAS showed that a majority of the U in the bulk wetland soil was in the + 6 oxidation state and was not well correlated spatially to Fe concentrations. SEM/EDS confirm that U was enriched on root plaques, where it was always found in association with P. Together these findings support our hypothesis and suggest that plants can alter mineralogical conditions that may be conducive to contaminant immobilization in wetlands. - Highlights: • Uranium concentrated in wetland environments • Hypothesized that plant roots change mineralogy and contaminant binding environment, promoting contaminant immobilization • Field study showed sharp dissolved U concentration profiles over the centimeter scale. • Spectroscopy identified unique mineralogy in rhizosphere compared to non-rhizosphere soil. • Uranium concentrated in root plaques in the + 6

  11. Mineralogical characteristics of the silica polymorphs in relation to their biological activities

    Energy Technology Data Exchange (ETDEWEB)

    Guthrie, G.D. Jr. [Los Alamos National Lab., NM (United States); Heaney, P.J. [Princeton Univ., NJ (United States). Dept. of Geological and Geophysical Sciences

    1993-10-01

    Numerous aspects of minerals (including the silica polymorphs) can effect their biological activities. These include periodic structures, compositional variations, dissolution characteristics, surface properties, and particle size/shape. In order to understand mineral-induced pathogenesis in a mechanistic way, the links between these properties and biochemical processes must be elucidated. This paper presents some of the basic properties of the silica polymorphs that may relate to pathogenicity and mineralogical strategies for designing biological assays to evaluate these properties.

  12. Iron mineralogy and uranium-binding environment in the rhizosphere of a wetland soil

    International Nuclear Information System (INIS)

    Kaplan, Daniel I.; Kukkadapu, Ravi; Seaman, John C.; Arey, Bruce W.; Dohnalkova, Alice C.; Buettner, Shea; Li, Dien; Varga, Tamas; Scheckel, Kirk G.; Jaffé, Peter R.

    2016-01-01

    Wetlands mitigate the migration of groundwater contaminants through a series of biogeochemical gradients that enhance multiple contaminant-binding processes. The hypothesis of this study was that wetland plant roots contribute organic carbon and release O_2 within the rhizosphere (plant-impact soil zone) that promote the formation of Fe(III)-(oxyhydr)oxides. In turn, these Fe(III)-(oxyhydr)oxides stabilize organic matter that together contribute to contaminant immobilization. Mineralogy and U binding environments of the rhizosphere were evaluated in samples collected from contaminated and non-contaminated areas of a wetland on the Savannah River Site in South Carolina. Based on Mössbauer spectroscopy, rhizosphere soil was greatly enriched with nanogoethite, ferrihydrite-like nanoparticulates, and hematite, with negligible Fe(II) present. X-ray computed tomography and various microscopy techniques showed that root plaques were tens-of-microns thick and consisted of highly oriented Fe-nanoparticles, suggesting that the roots were involved in creating the biogeochemical conditions conducive to the nanoparticle formation. XAS showed that a majority of the U in the bulk wetland soil was in the + 6 oxidation state and was not well correlated spatially to Fe concentrations. SEM/EDS confirm that U was enriched on root plaques, where it was always found in association with P. Together these findings support our hypothesis and suggest that plants can alter mineralogical conditions that may be conducive to contaminant immobilization in wetlands. - Highlights: • Uranium concentrated in wetland environments • Hypothesized that plant roots change mineralogy and contaminant binding environment, promoting contaminant immobilization • Field study showed sharp dissolved U concentration profiles over the centimeter scale. • Spectroscopy identified unique mineralogy in rhizosphere compared to non-rhizosphere soil. • Uranium concentrated in root plaques in the + 6 oxidation

  13. Test and Delivery of the Chemin Mineralogical Instrument for Mars Science Laboratory

    Science.gov (United States)

    Blake, D. F.; Vaniman, D.; Anderson, R.; Bish, D.; Chipera, S.; Chemtob, S.; Crisp, J.; DesMarais, D. J.; Downs, R.; Feldman, S.; hide

    2010-01-01

    The CheMin mineralogical instrument on MSL will return quantitative powder X-ray diffraction data (XRD) and qualitative X-ray fluorescence data (XRF; 14

  14. Contents and composition of organic matter in subsurface soils affected by land use and soil mineralogy

    Science.gov (United States)

    Ellerbrock, Ruth H.; Kaiser, Michael

    2010-05-01

    Land use and mineralogy affect the ability of surface as well as subsurface soils to sequester organic carbon and their contribution to mitigate the greenhouse effect. This study aimed to investigate the long-term impact of land use (i.e., arable and forest) and soil mineralogy on contents and composition of soil organic matter (SOM) from subsurface soils. Seven soils different in mineralogy (Albic and Haplic Luvisol, Colluvic and Haplic Regosol, Haplic and Vertic Cambisol, Haplic Stagnosol) were selected within Germany. Soil samples were taken from forest and adjacent arable sites. First, particulate and water soluble organic matter were separated from the subsurface soil samples. From the remaining solid residues the OM(PY) fractions were separated, analyzed for its OC content (OCPY) and characterized by FTIR spectroscopy. For the arable subsurface soils multiple regression analyses indicate significant positive relationships between the soil organic carbon contents and the contents of i) exchangeable Ca and oxalate soluble Fe, and Alox contents. Further for the neutral arable subsurface soils the contents OCPY weighted by its C=O contents were found to be related to the contents of Ca indicating interactions between OM(PY) and Ca cations. For the forest subsurface soils (pH <5) the OCPY contents were positively related with the contents of Na-pyrophosphate soluble Fe and Al. For the acidic forest subsurface soils such findings indicate interactions between OM(PY) and Fe3+ and Al3+ cations. The effects of land use and soil mineralogy on contents and composition of SOM and OM(PY) will be discussed.

  15. Potential effects of ocean acidification on Alaskan corals based on calcium carbonate mineralogy composition analysis (NCEI Accession 0157223)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains potential effects of ocean acidification on Alaskan corals based on calcium carbonate mineralogy composition analysis. Effects of...

  16. Nano-FTIR Spectroscopy to Investigate the Silicate Mineralogy of Mercury Analogues: Supporting MERTIS Onboard BepiColombo Mission

    Science.gov (United States)

    Varatharajan, I.; Maturilli, A.; Helbert, J.; Ulrich, G.; Born, K.; Namur, O.; Kästner, B.; Hecht, L.; Charlier, B.; Hiesinger, H.

    2018-05-01

    Nano-FTIR Spectroscopy is used to investigate the silicate mineralogy of synthetic Mercury analogues produced under reduced conditions representing different Mercury terrains. The study will support MERTIS payload onboard BepiColombo mission.

  17. Lack of cross-shelf transport of sediments on the western margin of India: Evidence from clay mineralogy

    Digital Repository Service at National Institute of Oceanography (India)

    Ramaswamy, V.; Nair, R.R.

    transported long distances along the shelf, cross-shelf transport appears to be minimal. Confirmatory evidence of qualitative differences in outer and inner shelf clays is provided by sediment trap clay mineralogy on the outer shelf. Clay bound pollutant...

  18. Bioleaching of two different genetic types of chalcopyrite and their comparative mineralogical assessment.

    Science.gov (United States)

    Deng, Sha; Gu, Guohua; Ji, Jing; Xu, Baoke

    2018-02-01

    The bioleaching of two different genetic types of chalcopyrite by the moderate thermophile Sulfobacillus thermosulfidooxidans was investigated by leaching behaviors elucidation and their comparative mineralogical assessment. The leaching experiment showed that the skarn-type chalcopyrite (STC) revealed a much faster leaching rate with 33.34% copper extracted finally, while only 23.53% copper was bioleached for the porphyry-type chalcopyrite (PTC). The mineralogical properties were analyzed by XRD, SEM, XPS, and Fermi energy calculation. XRD indicated that the unit cell volume of STC was a little larger than that of PTC. SEM indicated that the surface of STC had more steps and ridges. XPS spectra showed that Cu(I) was the dominant species of copper on the surfaces of the two chalcopyrite samples, and STC had much more copper with lower Cu 2p 3/2 binding energy. Additionally, the Fermi energy of STC was much higher than that of PTC. These mineralogical differences were in good agreement with the bioleaching behaviors of chalcopyrite. This study will provide some new information for evaluating the oxidation kinetics of chalcopyrite.

  19. Mineralogical Plasticity Acts as a Compensatory Mechanism to the Impacts of Ocean Acidification.

    Science.gov (United States)

    Leung, Jonathan Y S; Russell, Bayden D; Connell, Sean D

    2017-03-07

    Calcifying organisms are considered particularly susceptible to the future impacts of ocean acidification (OA), but recent evidence suggests that they may be able to maintain calcification and overall fitness. The underlying mechanism remains unclear but may be attributed to mineralogical plasticity, which modifies the energetic cost of calcification. To test the hypothesis that mineralogical plasticity enables the maintenance of shell growth and functionality under OA conditions, we assessed the biological performance of a gastropod (respiration rate, feeding rate, somatic growth, and shell growth of Austrocochlea constricta) and analyzed its shell mechanical and geochemical properties (shell hardness, elastic modulus, amorphous calcium carbonate, calcite to aragonite ratio, and magnesium to calcium ratio). Despite minor metabolic depression and no increase in feeding rate, shell growth was faster under OA conditions, probably due to increased precipitation of calcite and trade-offs against inner shell density. In addition, the resulting shell was functionally suitable for increasingly "corrosive" oceans, i.e., harder and less soluble shells. We conclude that mineralogical plasticity may act as a compensatory mechanism to maintain overall performance of calcifying organisms under OA conditions and could be a cornerstone of calcifying organisms to acclimate to and maintain their ecological functions in acidifying oceans.

  20. Chemistry and Mineralogy of Antarctica Dry Valley Soils: Implications for Mars

    Science.gov (United States)

    Quinn, J. E.; Golden, D. C.; Graff, T. G.; Ming, D. W.; Morris, R. V.; Douglas, S.; Kounaves, S. P.; McKay, C. P.; Tamppari, L, K.; Smith, P. H.; hide

    2011-01-01

    The Antarctic Dry Valleys (ADV) comprise the largest ice-free region of Antarctica. Precipitation almost always occurs as snow, relative humidity is frequently low, and mean annual temperatures are about -20 C. The ADV soils have previously been categorized into three soil moisture regimes: subxerous, xerous and ultraxerous, based on elevation and climate influences. The subxerous regime is predominately a coastal zone soil, and has the highest average temperature and precipitation, while the ultraxerous regime occurs at high elevation (>1000 m) and have very low temperature and precipitation. The amounts and types of salts present in the soils vary between regions. The nature, origin and significance of salts in the ADV have been previously investigated. Substantial work has focused on soil formation in the ADVs, however, little work has focused on the mineralogy of secondary alteration phases. The dominant weathering process in the ADV region is physical weathering, however, chemical weathering has been well documented. The objective of this study was to characterize the chemistry and mineralogy, including the alteration mineralogy, of soils from two sites, a subxerous soil in Taylor Valley, and an ultraxerous soil in University Valley. The style of aqueous alteration in the ADVs may have implications for pedogenic processes on Mars.

  1. Effect of Aggregate Mineralogy and Concrete Microstructure on Thermal Expansion and Strength Properties of Concrete

    Directory of Open Access Journals (Sweden)

    Jinwoo An

    2017-12-01

    Full Text Available Aggregate type and mineralogy are critical factors that influence the engineering properties of concrete. Temperature variations result in internal volume changes could potentially cause a network of micro-cracks leading to a reduction in the concrete’s compressive strength. The study specifically studied the effect of the type and mineralogy of fine and coarse aggregates in the normal strength concrete properties. As performance measures, the coefficient of thermal expansion (CTE and compressive strength were tested with concrete specimens containing different types of fine aggregates (manufactured and natural sands and coarse aggregates (dolomite and granite. Petrographic examinations were then performed to determine the mineralogical characteristics of the aggregate and to examine the aggregate and concrete microstructure. The test results indicate the concrete CTE increases with the silicon (Si volume content in the aggregate. For the concrete specimens with higher CTE, the micro-crack density in the interfacial transition zone (ITZ tended to be higher. The width of ITZ in one of the concrete specimens with a high CTE displayed the widest core ITZ (approx. 11 µm while the concrete specimens with a low CTE showed the narrowest core ITZ (approx. 3.5 µm. This was attributed to early-age thermal cracking. Specimens with higher CTE are more susceptible to thermal stress.

  2. Hydrothermally-induced changes in mineralogy and magnetic properties of oxidized A-type granites

    Science.gov (United States)

    Nédélec, Anne; Trindade, Ricardo; Peschler, Anne; Archanjo, Carlos; Macouin, Mélina; Poitrasson, Franck; Bouchez, Jean-Luc

    2015-01-01

    The changes in magnetic mineralogy due to the hydrothermal alteration of A-type granitic rocks have been thoroughly investigated in samples from the granite of Tana (Corsica, France), and compared with other A-type granites: Meruoca (NE Brazil), Bushveld (South Africa), Mount Scott (Wichita Mountains, Oklahoma, USA) and the stratoid hypersolvus granites of Madagascar. The altered red-colored samples and their non-altered equivalents were magnetically characterized by means of magnetic susceptibility measurements, hysteresis loops, remanent coercivity spectra, and Lowrie test. It is shown that hydrothermalization in magnetite-bearing granites is related to the formation of fine-grained magnetite and hematite, and to coeval depletion in the content of primary low-coercive coarse-grained magnetite. These mineralogical changes give typical rock magnetic signatures, namely lower susceptibility magnitudes and anisotropy degrees, prolate AMS (anisotropy of magnetic susceptibility) fabrics and increased coercivities. Optical microscopy and SEM (scanning electronic microscopy) images suggest that the orientation of the secondary magnetic minerals is related to fluid-pathways and micro-fractures formed during the hydrothermal event and therefore may be unrelated to magma emplacement and crystallization fabrics. Changes in magnetic mineralogy and grain-size distribution have also to be considered for any paleomagnetic and iron isotope studies in granites.

  3. Mineralogical controls on aluminum and magnesium in uranium mill tailings: Key Lake, Saskatchewan, Canada.

    Science.gov (United States)

    Gomez, M A; Hendry, M J; Koshinsky, J; Essilfie-Dughan, J; Paikaray, S; Chen, J

    2013-07-16

    The mineralogy and evolution of Al and Mg in U mill tailings are poorly understood. Elemental analyses (ICP-MS) of both solid and aqueous phases show that precipitation of large masses of secondary Al and Mg mineral phases occurs throughout the raffinate neutralization process (pH 1-11) at the Key Lake U mill, Saskatchewan, Canada. Data from a suite of analytical methods (ICP-MS, EMPA, laboratory- and synchrotron-based XRD, ATR-IR, Raman, TEM, EDX, ED) and equilibrium thermodynamic modeling showed that nanoparticle-sized, spongy, porous, Mg-Al hydrotalcite is the dominant mineralogical control on Al and Mg in the neutralized raffinate (pH ≥ 6.7). The presence of this secondary Mg-Al hydrotalcite in mineral samples of both fresh and 15-year-old tailings indicates that the Mg-Al hydrotalcite is geochemically stable, even after >16 years in the oxic tailings body. Data shows an association between the Mg-Al hydrotalcite and both As and Ni and point to this Mg-Al hydrotalcite exerting a mineralogical control on the solubility of these contaminants.

  4. A regional mineralogical study of the manganese-bearing Voelwater subgroup in the northern Cape Province

    International Nuclear Information System (INIS)

    Kleyenstueber, A.S.E.

    1985-11-01

    The Voelwater Subgroup, of the Proterozoic Transvaal Sequence, in the Hotazel area, is preserved in five structurally controlled basins, on the eastern side of the Dimoten syncline. The Subgroup represents a relatively undisturbed unit of mixed volcanogenic - chemical sedimentary rocks. The Hotazel Formation within the Voelwater Subgroup, consists of a finely banded carbonate - silicate - hematite - manganese lutite sequence of banded iron-formation and must be unique in that it contains the world's largest land-based repository of manganese. Twenty-one drill cores, sampled lithologically at intervals of approximately one metre through the total sedimentary sequence, were studied by microscopic, X-ray diffraction and electron microprobe methods. The mineralogy of the Voelwater Subgroup was studied on a regional scale, with the emphasis on the minerals within the manganese beds of the Hotazel Formation. The objective of the study was: a. To study the variation and distrubution of minerals in the various manganese ores on a regional scale. b. To compare the mineralogical differences of the different ores mined, in order to gain a better understanding of their metallurgical behaviour. c. To try to locate high-grade manganese ore target areas for future exploration, with the aid of mineralogical information. d. To try to establish the origin of the manganese in the Voelwater Formation. e. To study the relationship of the manganese units with the adjacent chemical sediments of the Hotazel Formation

  5. Characterization of raw and burnt oil shale from Dotternhausen: Petrographical and mineralogical evolution with temperature

    International Nuclear Information System (INIS)

    Thiéry, Vincent; Bourdot, Alexandra; Bulteel, David

    2015-01-01

    The Toarcian Posidonia shale from Dotternhausen, Germany, is quarried and burnt in a fluidized bed reactor to produce electricity. The combustion residue, namely burnt oil shale (BOS), is used in the adjacent cement work as an additive in blended cements. The starting material is a typical laminated oil shale with an organic matter content ranging from 6 to 18%. Mineral matter consists principally of quartz, feldspar, pyrite and clays. After calcination in the range, the resulting product, burnt oil shale, keeps the macroscopic layered texture however with different mineralogy (anhydrite, lime, iron oxides) and the formation of an amorphous phase. This one, studied under STEM, reveals a typical texture of incipient partial melting due to a long retention time (ca. 30 min) and quenching. An in-situ high temperature X-ray diffraction (HTXRD) allowed studying precisely the mineralogical changes associated with the temperature increase. - Highlights: • We present oil shale/burnt oil shale characterization. • The Posidonia Shale is burnt in a fluidized bed. • Mineralogical evolution with temperature is complex. • The burnt oil shale is used in composite cements

  6. Three dimensional canonical transformations

    International Nuclear Information System (INIS)

    Tegmen, A.

    2010-01-01

    A generic construction of canonical transformations is given in three-dimensional phase spaces on which Nambu bracket is imposed. First, the canonical transformations are defined as based on cannonade transformations. Second, it is shown that determination of the generating functions and the transformation itself for given generating function is possible by solving correspondent Pfaffian differential equations. Generating functions of type are introduced and all of them are listed. Infinitesimal canonical transformations are also discussed as the complementary subject. Finally, it is shown that decomposition of canonical transformations is also possible in three-dimensional phase spaces as in the usual two-dimensional ones.

  7. Geochemistry and mineralogy of recent sediments of Guanabara Bay (NE sector) and its major rivers - Rio de Janeiro State - Brazil

    OpenAIRE

    FARIA, MARCIA DE MELO; SANCHEZ, BRAZ A.

    2001-01-01

    Geochemical and clay mineralogical studies of bottom sediments collected along the Macacu and Caceribu rivers and Guanabara Bay were carried out in order to investigate the relationship between major source areas and recent sediments of the bay. Clay mineralogy includes different groups with selective distribution conditioned by geomorphic features and depositional settings. Micaceous clay minerals are abundant near parent rock in the upper course, whereas kaolinite derived from varied source...

  8. SEDIMENTOLOGY, MINERALOGY AND ORIGIN OF THE FIRST DISCOVER MAGNESITE-DOLOMITE BELT IN MA'RIB DISTRICT, SW ARABIAN PENINSULA

    Directory of Open Access Journals (Sweden)

    Sa’ad Zeki A.kader AL-MASHAIKIE

    2016-10-01

    Full Text Available Magnesite mineralization of high purity was discovered and described herein for the first time from metamorphosed folded belt from Al-Thanyiah locality in Rub’Al-Khali sector, 360 km east of Sana’a City, northwest Yemen. The magnesite-metamorphic belt, belonging to the Precambrian/Neoproterozoic age? comprises thrust belt, which trends generally N-S direction.Magnesite mineralization was identified in an extended carbonate-metamorphic belt for several tens of kilometers cf. 31 km and occurred in association with 8 stratigraphic units. The thicknesses of pure magnesite bearing units are variable and ranges from 20 to 60 m. associated with dark green chlorite-schist with intersecting huge ultrabasic intrusions.Geochemical, mineralogical and petrographic analysis show that the magnesite concentrations in the stratigraphic units are ranging from 78% up to high purity of 99.6% cf. 35 to 48.9% MgO, with minor dolomite and calcite respectively. Little to rare content of talc and brucite were also recognized. Two thick, productive and high purity magnesite beds, the first is of 40 m thick and the second is 60 m in thickness, which reveals more than 95% MgCO3 and considered to be economic. The suggested origin of the magnesite mineralization is coming from high stress of regional metamorphism associated with ultramafic intrusions cf. amphibolite and harzburgite associated with diagenetic solutions rich in Mg2+, associated with the heat of magma. The alteration of dolomite to magnesite was formed by multiple phases to transform calcite and/or dolomite to magnesite.

  9. Forced and natural carbonation of lime-based mortars with and without additives: Mineralogical and textural changes

    International Nuclear Information System (INIS)

    Cultrone, G.; Sebastian, E.; Huertas, M. Ortega

    2005-01-01

    We have studied the carbonation process in different types of mortars, with and without pozzolana or air-entraining additives, subject to a CO 2 -rich atmosphere and compared the results with those of similar naturally carbonated mortars. We used X-ray diffraction technique to demonstrate that high CO 2 concentrations favour a faster, more complete carbonation process with 8 days being sufficient to convert portlandite into 90 wt.% calcite. Full carbonation, however, is not reached during the life-span of the tests, not even in forced carbonation experiments. This could be due to at least one of the following phenomena: a premature drying of samples during carbonation reaction, the temperature at which the carbonation process was carried out or the reduction of pore volume occupied by newly formed calcite crystals. This last option seems to be the least probable. We observed a more prolific development of calcite crystals in the pores and fissures through which the carbonic anhydride flows. Under natural conditions, carbonation is much slower and similar levels are not reached for 6 months. These differences suggest that the carbonation process is influenced by the amount of CO 2 used. Both the mineralogy and texture of mortars vary depending on the type of additive used but the speed of the portlandite-calcite transformation does not change significantly. Pozzolana produces hydraulic mortars although the quantity of calcium aluminosilicate crystals is low. The air-entraining agent significantly alters the texture of the mortars creating rounded pores and eliminating or reducing the drying cracks

  10. University Transformation: New Demands and Coping Strategies

    Science.gov (United States)

    Chidindi, Joseph

    2012-01-01

    University education system is undergoing transformation requirements particularly in the developing world. The demands require adaptation to the prevailing circumstances hence the need for relevant strategies for universities. Issues such as institutional profiles, organizational structure and work integration, research activities, and funding…

  11. Mineralogical effects of an experimental forest fire on a goethite/ferrihydrite soil - an attempt to solve the presence of hematite and maghemite in topsoils in a temperate region

    Science.gov (United States)

    Nørnberg, Per; Vendelboe, Anders L.; Gunnlaugsson, Haraldur P.; Merrison, Jonathan P.; Finster, Kai; Jensen, Svend K.

    2010-05-01

    Isolated soil spots, a few square metres in size, as red as Munsell colour 10R ¾ are found in Denmark. These spots are well known as places that have been exposed to fire. However, a long-standing unresolved puzzle is the presence of extended areas with high iron content (8-40 %) where goethite and ferrihydrite are present in the topsoil along with hematite and maghemite. Hematite and particularly maghemite would normally not be expected to occur under the temperate humid Danish climate, but be interpreted as the result of high temperature as found in tropical areas or after forest fires. However, a body of evidence argues against these sites having been exposed to fire. In an attempt to get closer to an explanation of this iron mineralogy, an experimental forest fire was produced. The results showed a clear mineralogical zonation down to 10 cm depth. This was not observed at the natural sites, which contained a uniform mixture of goethite/ferrihydrite, hematite and maghemite down to 20 cm depth. The experimental forest fire furthermore left charcoal and ashes at the topsoil, produced high pH and decreased organic matter content, all of which is in contrast to the natural sites. Physical and chemical date as well as XRD, Mössbauer spectroscopic data and TEM micrographs from the sites will be presented. The conclusion from this work is that the mineralogy of these sites is not consistent with exposure to fire, but may rather result from long term transformation within a reducing environment, possibly involving microorganisms. References: Nørnberg, P., Vendelboe, A.L., Gunnlaugsson, H.P., Merrison, J.P., Finster, K., Jensen, S.K. 2009 Mineralogy after an experimental forest fire on Quaternary soil goethite, compared with a hematite, maghemite, goethite containing topsoil. Clay Minerals, 44, 239-247. Nørnberg, P., Gunnlaugsson, H.P., Merrison, J.P., Vendelboe, A.L. 2009: Salten Skov I: A Martian dust analogue. Planetary and Space Science, 57, 628-631. Nørnberg, P

  12. Alpha power gates relevant information during working memory updating.

    Science.gov (United States)

    Manza, Peter; Hau, Chui Luen Vera; Leung, Hoi-Chung

    2014-04-23

    Human working memory (WM) is inherently limited, so we must filter out irrelevant information in our environment or our mind while retaining limited important relevant contents. Previous work suggests that neural oscillations in the alpha band (8-14 Hz) play an important role in inhibiting incoming distracting information during attention and selective encoding tasks. However, whether alpha power is involved in inhibiting no-longer-relevant content or in representing relevant WM content is still debated. To clarify this issue, we manipulated the amount of relevant/irrelevant information using a task requiring spatial WM updating while measuring neural oscillatory activity via EEG and localized current sources across the scalp using a surface Laplacian transform. An initial memory set of two, four, or six spatial locations was to be memorized over a delay until an updating cue was presented indicating that only one or three locations remained relevant for a subsequent recognition test. Alpha amplitude varied with memory maintenance and updating demands among a cluster of left frontocentral electrodes. Greater postcue alpha power was associated with the high relevant load conditions (six and four dots cued to reduce to three relevant) relative to the lower load conditions (four and two dots reduced to one). Across subjects, this difference in alpha power was correlated with condition differences in performance accuracy. In contrast, no significant effects of irrelevant load were observed. These findings demonstrate that, during WM updating, alpha power reflects maintenance of relevant memory contents rather than suppression of no-longer-relevant memory traces.

  13. Leading to Transgress: Critical Considerations for Transforming Leadership Learning.

    Science.gov (United States)

    Osteen, Laura; Guthrie, Kathy L; Jones, Tamara Bertrand

    2016-12-01

    The culturally relevant leadership learning (CRLL) model is explored through the lens of theory and practice. This creates critical questions to guide leadership educators in the ongoing process of transforming leadership programs. © 2016 Wiley Periodicals, Inc., A Wiley Company.

  14. Reconstructing the Holocene depositional environments along the northern coast of Sfax (Tunisia): Mineralogical and sedimentological approaches

    Science.gov (United States)

    Lamourou, Ali; Touir, Jamel; Fagel, Nathalie

    2017-05-01

    A sedimentological and mineralogical study of sedimentary cores allowed reconstructing the evolution of depositional environments along the Northern coast of Sfax (Tunisia). The aim of this research work is to identify the factors controlling the sedimentation from the Holocene to the Present time. Three 30-m sediment cores collected by drilling at 30 m water depth were analyzed for their color, magnetic susceptibility signal, grain size by laser diffraction, organic matter content by loss of ignition, carbonate content by calcimetry and mineralogy by X-ray diffraction on bulk powder and clay <2 μm. They broadly present the same sedimentological and mineralogical features. Microscopical observations of petrographic slides allowed identifying six main sedimentary facies. Bulk mineralogical assemblages comprised clay minerals, quartz, calcite, gypsum and K-feldspars were examined. Considerable change was observed in the carbonate content that mimicked the bioclaste abundance and diluted the detrital minerals (clay minerals, quartz and feldspars). The gypsum mainly occurred in the lower sedimentary columns (SC12 and SC9) and in the upper/middle of core SC6. The clay fraction was made of a mixture of kaolinite, illite, smectite and palygorskite with no clear variation through core depth. Both grain-size parameters and magnetic susceptibility profile showed a sharp transition in the upper 2-5 m of the sedimentological columns. Coarse, sandy to gravely sediments characterized by a low magnetic susceptibility signal were replaced by fine bioclastic-rich clayey sediments. The analysis of vertical succession of depositional facies revealed a fluvial depositional environment (coastal plain) basically marked by fluvial channels and inundation plains at the bottom of all cores. However, core-top sediments recorded a littoral marine environment with sand depositions rich in gastropods, lamellibranches and algæ. Depositional facies, sedimentological and mineralogical

  15. Laplace Transforms without Integration

    Science.gov (United States)

    Robertson, Robert L.

    2017-01-01

    Calculating Laplace transforms from the definition often requires tedious integrations. This paper provides an integration-free technique for calculating Laplace transforms of many familiar functions. It also shows how the technique can be applied to probability theory.

  16. On Poisson Nonlinear Transformations

    Directory of Open Access Journals (Sweden)

    Nasir Ganikhodjaev

    2014-01-01

    Full Text Available We construct the family of Poisson nonlinear transformations defined on the countable sample space of nonnegative integers and investigate their trajectory behavior. We have proved that these nonlinear transformations are regular.

  17. Chemical Transformation Simulator

    Science.gov (United States)

    The Chemical Transformation Simulator (CTS) is a web-based, high-throughput screening tool that automates the calculation and collection of physicochemical properties for an organic chemical of interest and its predicted products resulting from transformations in environmental sy...

  18. Diffusionless phase transformations

    International Nuclear Information System (INIS)

    Vejman, K.M.

    1987-01-01

    Diffusionless phase transformations in metals and alloys in the process of which atomic displacements occur at the distances lower than interatomic ones and relative correspondence of neighbour atoms is preserved, are considered. Special attention is paid to the mechanism of martensitic transformations. Phenomenologic crystallographical theory of martensitic transformations are presented. Two types of martensitic transformations different from the energy viewpoint are pointed out - thermoelastic and non-thermoelastic ones - which are characterized by transformation hysteresis and ways of martensite - initial phase reverse transformation realization. Mechanical effect in the martensitic transformations have been analyzed. The problem of diffusionless formation of ω-phases and the effect of impurities and vacancies on the process are briefly discussed. The role of charge density waves in phase transformations of the second type (transition of initial phase into noncommensurate one) and of the first type (transition of noncommensurate phase into commensurate one) is considered

  19. Equations For Rotary Transformers

    Science.gov (United States)

    Salomon, Phil M.; Wiktor, Peter J.; Marchetto, Carl A.

    1988-01-01

    Equations derived for input impedance, input power, and ratio of secondary current to primary current of rotary transformer. Used for quick analysis of transformer designs. Circuit model commonly used in textbooks on theory of ac circuits.

  20. Entropy of Baker's Transformation

    Institute of Scientific and Technical Information of China (English)

    栾长福

    2003-01-01

    Four theorems about four different kinds of entropies for Baker's transformation are presented. The Kolmogorov entropy of Baker's transformation is sensitive to the initial flips by the time. The topological entropy of Baker's transformation is found to be log k. The conditions for the state of Baker's transformation to be forbidden are also derived. The relations among the Shanonn, Kolmogorov, topological and Boltzmann entropies are discussed in details.

  1. Hydrogeochemical and mineralogical characteristics related to heavy metal attenuation in a stream polluted by acid mine drainage:A case study in Dabaoshan Mine, China

    Institute of Scientific and Technical Information of China (English)

    Huarong Zhao; Beicheng Xia; Jianqiao Qin; Jiaying Zhang

    2012-01-01

    Dabaoshan Mine,the largest mine in south China,has been developed since the 1970s.Acid mine drainage (AMD) discharged from the mine has caused severe environmental pollution and human health problems.In this article,chemical characteristics,mineralogy of ocher precipitations and heavy metal attenuation in the AMD are discussed based on physicochemical analysis,mineral analysis,sequential extraction experiments and hydrogeochemistry.The AMD chemical characteristics were determined from the initial water composition,water-rock interactions and dissolved sulfide minerals in the mine tailings.The waters,affected and unaffected by AMD,were Ca-SO4 and Ca-HCO3 types,respectively.The affected water had a low pH,high SO42- and high heavy metal content and oxidation as determined by the Fe2+/Fe3+ couple.Heavy metal and SO42- contents of Hengshi River water decreased,while pH increased,downstream.Schwertmannite was the major mineral at the waste dump,while goethite and quartz were dominant at the tailings dam and streambed.Schwertmannite was transformed into goethite at the tailings dam and streambed.The sulfate ions of the secondary minerals changed from bidentate- to monodentate-complexes downstream.Fe-Mn oxide phases of Zn,Cd and Pb in sediments increased downstream.However,organic matter complexes of Cu in sediments increased further away from the tailings.Fe3+ mineral precipitates and transformations controlled the AMD water chemistry.

  2. Electrostatic shielding of transformers

    Energy Technology Data Exchange (ETDEWEB)

    De Leon, Francisco

    2017-11-28

    Toroidal transformers are currently used only in low-voltage applications. There is no published experience for toroidal transformer design at distribution-level voltages. Toroidal transformers are provided with electrostatic shielding to make possible high voltage applications and withstand the impulse test.

  3. Defense Business Transformation

    Science.gov (United States)

    2009-12-01

    Defense Business Transformation by Jacques S. Gansler and William Lucyshyn The Center for Technology and National...REPORT TYPE 3. DATES COVERED 00-00-2009 to 00-00-2009 4. TITLE AND SUBTITLE Defense Business Transformation 5a. CONTRACT NUMBER 5b. GRANT NUMBER...vii Part One: DoD Business Transformation

  4. Transforming the Force and Logistics Transformation

    National Research Council Canada - National Science Library

    Cook, Katherine M

    2006-01-01

    U.S. Army transformation strategy addresses the imperative to change the Army from a Cold War-oriented design to one that is more responsive, agile, and adaptable to present and emerging threats across...

  5. The relevance of "non-relevant metabolites" from plant protection products (PPPs) for drinking water: the German view.

    Science.gov (United States)

    Dieter, Hermann H

    2010-03-01

    "Non-relevant metabolites" are those degradation products of plant protection products (PPPs), which are devoid of the targeted toxicities of the PPP and devoid of genotoxicity. Most often, "non-relevant metabolites" have a high affinity to the aquatic environment, are very mobile within this environment, and, usually, are also persistent. Therefore, from the point of drinking water hygiene, they must be characterized as "relevant for drinking water" like many other hydrophilic/polar environmental contaminants of different origins. "Non-relevant metabolites" may therefore penetrate to water sources used for abstraction of drinking water and may thus ultimately be present in drinking water. The presence of "non-relevant metabolites" and similar trace compounds in the water cycle may endanger drinking water quality on a long-term scale. During oxidative drinking water treatment, "non-relevant metabolites" may also serve as the starting material for toxicologically relevant transformation products similar to processes observed by drinking water disinfection with chlorine. This hypothesis was recently confirmed by the detection of the formation of N-nitroso-dimethylamine from ozone and dimethylsulfamide, a "non-relevant metabolite" of the fungicide tolylfluanide. In order to keep drinking water preferably free of "non-relevant metabolites", the German drinking water advisory board of the Federal Ministry of Health supports limiting their penetration into raw and drinking water to the functionally (agriculturally) unavoidable extent. On this background, the German Federal Environment Agency (UBA) recently has recommended two health related indication values (HRIV) to assess "non-relevant metabolites" from the view of drinking water hygiene. Considering the sometimes incomplete toxicological data base for some "non-relevant metabolites", HRIV also have the role of health related precautionary values. Depending on the completeness and quality of the toxicological

  6. Report on hydro-mechanical and chemical-mineralogical analyses of the bentonite buffer in Canister Retrieval Test

    Energy Technology Data Exchange (ETDEWEB)

    Dueck, Ann; Johannesson, Lars-Erik; Kristensson, Ola; Olsson, Siv [Clay Technology AB (Sweden)

    2011-12-15

    The effect of five years of exposure to repository-like conditions on compacted Wyoming bentonite was determined by comparing the hydraulic, mechanical, and mineralogical properties of samples from the bentonite buffer of the Canister Retrieval Test (CRT) with those of reference material. The CRT, located at the Swedish Aspo Hard Rock Laboratory (HRL), was a full-scale field experiment simulating conditions relevant for the Swedish KBS-3 concept for disposal of high-level radioactive waste in crystalline host rock. The compacted bentonite, surrounding a copper canister equipped with heaters, had been subjected to heating at temperatures up to 95 deg C and hydration by natural Na-Ca-Cl type groundwater for almost five years at the time of retrieval. Under the thermal and hydration gradients that prevailed during the test, sulfate in the bentonite was redistributed and accumulated as anhydrite close to the canister. The major change in the exchangeable cation pool was a loss in Mg in the outer parts of the blocks, suggesting replacement of Mg mainly by Ca along with the hydration with groundwater. Close to the copper canister, small amounts of Cu were incorporated in the bentonite. A reduction of strain at failure was observed in the innermost part of the bentonite buffer, but no influence was seen on the shear strength. No change of the swelling pressure was observed, while a modest decrease in hydraulic conductivity was found for the samples with the highest densities. No coupling was found between these changes in the hydro-mechanical properties and the montmorillonite . the X-ray diffraction characteristics, the cation exchange properties, and the average crystal chemistry of the Na-converted < 1 {mu}m fractions provided no evidence of any chemical/structural changes in the montmorillonite after the 5-year hydrothermal test.

  7. Profiles of Dialogue for Relevance

    Directory of Open Access Journals (Sweden)

    Douglas Walton

    2016-12-01

    Full Text Available This paper uses argument diagrams, argumentation schemes, and some tools from formal argumentation systems developed in artificial intelligence to build a graph-theoretic model of relevance shown to be applicable (with some extensions as a practical method for helping a third party judge issues of relevance or irrelevance of an argument in real examples. Examples used to illustrate how the method works are drawn from disputes about relevance in natural language discourse, including a criminal trial and a parliamentary debate.

  8. Change and Deeper Change: Transforming Social Work Education

    Science.gov (United States)

    Witkin, Stanley L.

    2014-01-01

    In recent years, the concept of transformation has become more prevalent in the social work literature; however, its use is quite varied. In this article, I attempt to disentangle some of these uses. I then propose a conceptualization of transformation and discuss its relevance for social work education. In this conceptualization, transformation…

  9. Fractional finite Fourier transform.

    Science.gov (United States)

    Khare, Kedar; George, Nicholas

    2004-07-01

    We show that a fractional version of the finite Fourier transform may be defined by using prolate spheroidal wave functions of order zero. The transform is linear and additive in its index and asymptotically goes over to Namias's definition of the fractional Fourier transform. As a special case of this definition, it is shown that the finite Fourier transform may be inverted by using information over a finite range of frequencies in Fourier space, the inversion being sensitive to noise. Numerical illustrations for both forward (fractional) and inverse finite transforms are provided.

  10. Critical Wave Forms in Dry Type Transformers

    DEFF Research Database (Denmark)

    Pedersen, Kenneth; Holbøll, Joachim; Henriksen, Mogens

    2005-01-01

    This paper concerns critical wave forms in dry type transformers under transient voltage application. A very general approach has been applied, meaning that many of the results will be applicable to various types of power transformers. The results can be very useful if they are combined...... with knowledge of the ageing effects of the insulation. Especially fast transients are likely to become a major issue due to fast breakers and power electronics. In order to perform relevant research in transformer insulation with respect to this subject, fundamental knowledge about the transmission...... and distortion of incoming transients is required. Thus, in this paper it is illustrated how the resulting internal wave forms are affected by different transformer characteristics....

  11. Nonsynchronous Noncommensurate Impedance Transformers

    DEFF Research Database (Denmark)

    Zhurbenko, Vitaliy; Kim, K

    2012-01-01

    Nonsynchronous noncommensurate impedance transformers consist of a combination of two types of transmission lines: transmission lines with a characteristic impedance equal to the impedance of the source, and transmission lines with a characteristic impedance equal to the load. The practical...... advantage of such transformers is that they can be constructed using sections of transmission lines with a limited variety of characteristic impedances. These transformers also provide comparatively compact size in applications where a wide transformation ratio is required. This paper presents the data...... matrix approach and experimentally verified by synthesizing a 12-section nonsynchronous noncommensurate impedance transformer. The measured characteristics of the transformer are compared to the characteristics of a conventional tapered line transformer....

  12. Mineralogical, chemical, organic and microbial properties of subsurface soil cores from Mars Desert Research Station (Utah, USA): Phyllosilicate and sulfate analogues to Mars mission landing sites

    Science.gov (United States)

    Stoker, Carol R.; Clarke, Jonathan; Direito, Susana O. L.; Blake, David; Martin, Kevin R.; Zavaleta, Jhony; Foing, Bernard

    2011-07-01

    We collected and analysed soil cores from four geologic units surrounding Mars Desert Research Station (MDRS) Utah, USA, including Mancos Shale, Dakota Sandstone, Morrison formation (Brushy Basin member) and Summerville formation. The area is an important geochemical and morphological analogue to terrains on Mars. Soils were analysed for mineralogy by a Terra X-ray diffractometer (XRD), a field version of the CheMin instrument on the Mars Science Laboratory (MSL) mission (2012 landing). Soluble ion chemistry, total organic content and identity and distribution of microbial populations were also determined. The Terra data reveal that Mancos and Morrison soils are rich in phyllosilicates similar to those observed on Mars from orbital measurements (montmorillonite, nontronite and illite). Evaporite minerals observed include gypsum, thenardite, polyhalite and calcite. Soil chemical analysis shows sulfate the dominant anion in all soils and SO4>>CO3, as on Mars. The cation pattern Na>Ca>Mg is seen in all soils except for the Summerville where Ca>Na. In all soils, SO4 correlates with Na, suggesting sodium sulfates are the dominant phase. Oxidizable organics are low in all soils and range from a high of 0.7% in the Mancos samples to undetectable at a detection limit of 0.1% in the Morrison soils. Minerals rich in chromium and vanadium were identified in Morrison soils that result from diagenetic replacement of organic compounds. Depositional environment, geologic history and mineralogy all affect the ability to preserve and detect organic compounds. Subsurface biosphere populations were revealed to contain organisms from all three domains (Archaea, Bacteria and Eukarya) with cell density between 3.0×106 and 1.8×107 cells ml-1 at the deepest depth. These measurements are analogous to data that could be obtained on future robotic or human Mars missions and results are relevant to the MSL mission that will investigate phyllosilicates on Mars.

  13. Relevance theory: pragmatics and cognition.

    Science.gov (United States)

    Wearing, Catherine J

    2015-01-01

    Relevance Theory is a cognitively oriented theory of pragmatics, i.e., a theory of language use. It builds on the seminal work of H.P. Grice(1) to develop a pragmatic theory which is at once philosophically sensitive and empirically plausible (in both psychological and evolutionary terms). This entry reviews the central commitments and chief contributions of Relevance Theory, including its Gricean commitment to the centrality of intention-reading and inference in communication; the cognitively grounded notion of relevance which provides the mechanism for explaining pragmatic interpretation as an intention-driven, inferential process; and several key applications of the theory (lexical pragmatics, metaphor and irony, procedural meaning). Relevance Theory is an important contribution to our understanding of the pragmatics of communication. © 2014 John Wiley & Sons, Ltd.

  14. Models of the Economic Growth and their Relevance

    Directory of Open Access Journals (Sweden)

    Nicolae MOROIANU

    2012-06-01

    Full Text Available Until few years ago, the economic growth was something perfect normal, part of an era marked by the transformation speed. Normality itself has been transformed and we currently are influenced by other rules, unknown yet, which should answer the question: “How do we return to the economic growth?” The economic growth and the models aiming to solve this problem concern the economic history even since its beginnings. In this paper we would like to find out what is the relevance that the well-known macroeconomic models still have and which might be their applicability level in a framework created by a black swan event type.

  15. Clinical relevance in anesthesia journals

    DEFF Research Database (Denmark)

    Lauritsen, Jakob; Møller, Ann M

    2006-01-01

    The purpose of this review is to present the latest knowledge and research on the definition and distribution of clinically relevant articles in anesthesia journals. It will also discuss the importance of the chosen methodology and outcome of articles.......The purpose of this review is to present the latest knowledge and research on the definition and distribution of clinically relevant articles in anesthesia journals. It will also discuss the importance of the chosen methodology and outcome of articles....

  16. Quantum decoration transformation for spin models

    Energy Technology Data Exchange (ETDEWEB)

    Braz, F.F.; Rodrigues, F.C.; Souza, S.M. de; Rojas, Onofre, E-mail: ors@dfi.ufla.br

    2016-09-15

    It is quite relevant the extension of decoration transformation for quantum spin models since most of the real materials could be well described by Heisenberg type models. Here we propose an exact quantum decoration transformation and also showing interesting properties such as the persistence of symmetry and the symmetry breaking during this transformation. Although the proposed transformation, in principle, cannot be used to map exactly a quantum spin lattice model into another quantum spin lattice model, since the operators are non-commutative. However, it is possible the mapping in the “classical” limit, establishing an equivalence between both quantum spin lattice models. To study the validity of this approach for quantum spin lattice model, we use the Zassenhaus formula, and we verify how the correction could influence the decoration transformation. But this correction could be useless to improve the quantum decoration transformation because it involves the second-nearest-neighbor and further nearest neighbor couplings, which leads into a cumbersome task to establish the equivalence between both lattice models. This correction also gives us valuable information about its contribution, for most of the Heisenberg type models, this correction could be irrelevant at least up to the third order term of Zassenhaus formula. This transformation is applied to a finite size Heisenberg chain, comparing with the exact numerical results, our result is consistent for weak xy-anisotropy coupling. We also apply to bond-alternating Ising–Heisenberg chain model, obtaining an accurate result in the limit of the quasi-Ising chain.

  17. Quantum decoration transformation for spin models

    International Nuclear Information System (INIS)

    Braz, F.F.; Rodrigues, F.C.; Souza, S.M. de; Rojas, Onofre

    2016-01-01

    It is quite relevant the extension of decoration transformation for quantum spin models since most of the real materials could be well described by Heisenberg type models. Here we propose an exact quantum decoration transformation and also showing interesting properties such as the persistence of symmetry and the symmetry breaking during this transformation. Although the proposed transformation, in principle, cannot be used to map exactly a quantum spin lattice model into another quantum spin lattice model, since the operators are non-commutative. However, it is possible the mapping in the “classical” limit, establishing an equivalence between both quantum spin lattice models. To study the validity of this approach for quantum spin lattice model, we use the Zassenhaus formula, and we verify how the correction could influence the decoration transformation. But this correction could be useless to improve the quantum decoration transformation because it involves the second-nearest-neighbor and further nearest neighbor couplings, which leads into a cumbersome task to establish the equivalence between both lattice models. This correction also gives us valuable information about its contribution, for most of the Heisenberg type models, this correction could be irrelevant at least up to the third order term of Zassenhaus formula. This transformation is applied to a finite size Heisenberg chain, comparing with the exact numerical results, our result is consistent for weak xy-anisotropy coupling. We also apply to bond-alternating Ising–Heisenberg chain model, obtaining an accurate result in the limit of the quasi-Ising chain.

  18. A new and improved methodology for qualitative and quantitative mineralogical analysis of Boom Clay

    International Nuclear Information System (INIS)

    Zeelmaekers, E.; Vandenberghe, N.; Honty, M.; De Craen, M.; Derkowski, A.; Van Geet, M.

    2010-01-01

    Document available in extended abstract form only. A good knowledge of the mineralogy of any host formation studied for geological disposal of high-level radioactive waste, is a prerequisite for understanding the geochemical environment which will determine the migration and retention behaviour of radionuclides. In this respect, the Boom Clay mineralogical composition has been extensively studied last decades as reference host formation (e.g. ARCHIMEDEARGILE project, OECD-NEA clay catalogue report) with the aim to provide reliable data for a safety assessment. However, a comparison of the available literature data clearly showed a serious discrepancy among studies, not only in the quantitative, but also in the qualitative mineralogical composition of the Boom Clay (SAFIR II). The reason for such a huge disagreement could be related, among others, to variable grain size distributions of the studied samples (sample heterogeneity) and differences in the methodological approaches. In particular, the unambiguous characterisation of clay minerals and the quantification of mixed-layer phases appeared as an everlasting problem. This study is aimed at achieving a consensus on the qualitative and quantitative mineralogical data of the Boom Clay using the most advanced techniques currently available in the clay science. A new sampling campaign was performed in such a way that samples are (20 in total) more or less regularly distributed over Boom Clay Formation, ensuring that variations in the grain size distributions due to silty clay-clayey silt layers alternations are accounted for. The novel concept based on an analysis at two levels was applied: (1) bulk rock and (2) clay fraction analysis. (1) A bulk rock analysis consists of conventional XRD analysis with the identification of the principal mineral phases. As a next step, the bulk rock was mixed with a ZnO internal standard and experimental diffraction patterns of randomly oriented powders were analyzed using &apos

  19. Mineralogical and geochemical patterns of urban surface soils, the example of Pforzheim, Germany

    International Nuclear Information System (INIS)

    Norra, Stefan; Lanka-Panditha, Mahesh; Kramar, Utz; Stueben, Doris

    2006-01-01

    This study presents a combined geochemical and mineralogical survey of urban surface soils. Many studies on urban soils are restricted to purely chemical surveys in order to investigate soil pollution caused by anthropogenic activities such as traffic, heating, industrial processing, waste disposal and many more. In environmental studies, chemical elements are often distinguished as lithogenic and anthropogenic elements. As a novel contribution to those studies, the authors combined the analysis of a broad set of chemical elements with the analysis of the main mineralogical phases. The semi-quantification of mineralogical phases supported the assignment of groups of chemical elements to lithogenic or anthropogenic origin. Minerals are important sinks for toxic elements. Thus, knowledge about their distribution in soils is crucial for the assessment of the environmental hazards due to pollution of urban soils. In Pforzheim, surface soils (0-5 cm depth) from various land use types (forest, agriculture, urban green space, settlement areas of various site densities) overlying different geological units (clastic and chemical sediments) were investigated. Urban surface soils of Pforzheim reflect to a considerable degree the mineral and chemical composition of parent rocks. Irrespective of the parent rocks, elevated concentrations of heavy metals (Zn, Cu, Pb, Sn, Ag) were found in soils throughout the whole inner urban settlement area of Pforzheim indicating pollution. These pollutants will tend to accumulate in inner urban surface soils according to the available adsorption capacity, which is normally higher in soils overlying limestone than in soils overlying sandstone. However, inner urban surface soils overlying sandstone show elevated concentrations of carbonates, phyllo-silicates and Fe and elevated pH values compared with forest soils overlying sandstone. Thus, in comparison to forest soils overlying sandstones, inner urban soils overlying sandstone affected by

  20. Lime treatment of an Italian pyroclastic soil: a multi-scale analysis for the correlation of mechanical and chemo-mineralogical effects.

    Science.gov (United States)

    Guidobaldi, Giulia; Cambi, Costanza; Cecconi, Manuela; Comodi, Paola; Zucchini, Azzurra

    2017-04-01

    improvements. Direct shear tests on treated soil samples revealed a brittle and dilatant behaviour; both features are more evident with increasing lime content, curing time and stress levels. Mechanical and chemo-mineralogical observations were coupled to obtain a better comprehension of the treated soil system evolution. During the chemo-mineralogical investigation phase, the ongoing system modifications at particle level were extremely stressed mixing soil and lime in the same weight proportions. This also led to a clear identification of the reaction products and kinetics through µX-Ray Fluorescence, X-Ray Diffraction, Thermogravimetry, Fourier Transformed Infra-Red and 29Si Nuclear Magnetic Resonance spectroscopy. The performed multi-scale analysis of the treated pyroclastic soil revealed the high reactivity of the system to lime addition, and the occurrence of pozzolanic reactions since the very beginning. The availability of secondary phases, in both crystalline and gel-like state, and their structural features are the main responsible for the observed mechanical behavior of the treated soil, showing the effectiveness of the treatment and the key role of zeolites in the chemo-physical evolution of the system. The obtained results, validated and supported by a deep comprehension of the micro-scale processes induced by lime treatment might open new perspective for future fruitful applications of pyroclastic problematic soils.

  1. Mineralogical characterization of historical portuguese wall tiles of Sao Luis, Maranhao, Brazil

    International Nuclear Information System (INIS)

    Rivas Mercury, J.M.; Vasconcelos, N.S.L.S.; Cabral, A.A.; Pereira, D.J. Costa; Angelica, R.S.

    2010-01-01

    Portuguese wall tiles from centuries, XVII, XVIII and XIX, found in Sao Luis Maranhao has been studied by X-ray diffraction, in order to interpret the possible raw material and burning temperature. The mineral phases, Quartz, Wollastonite, Calcite and Gehlenite were identified in all samples. Based on the results it is possible to affirm that the main raw materials used to manufacture this materials was probably mixtures of kaolinite clay and calcite. Based on the mineralogical information it was also possible to state that burning temperature of this wall tiles was lower than 1000 deg C. (author)

  2. Mineralogical and textural characteristics of Kakul (Hazara) phosphate rock, NWFP, Pakistan

    International Nuclear Information System (INIS)

    Mehmood, R.; Bhatti, M.A.; Kazmi, K.R.; Mehmood, A.; Sheikh, S.T.; Aleem Shah, S.A.

    2010-01-01

    Various types of minerals, present in phosphate rock of Hazara area of Khyber Pukhtoonkhwa Province of Pakistan, were identified and their concentration was determined using a suitable method. The characteristics of the rock were defined by petrography, X-ray diffraction, and chemical analysis and the textural characteristics such as grain size, grain shape and their arrangement in the rock body were also investigated. The degree of liberation of phosphate-bearing mineral was studied by the particle-counting method. Mineralogical and textural observations indicated that fine-grained rock may be suitable for beneficiation by the froth flotation separation technique. (author)

  3. Soil mineralogy and microbes determine forest life history strategy and carbon cycling in humid tropical forests

    Science.gov (United States)

    Soong, J.; Verbruggen, E.; Peñuelas, J.; Janssens, I. A.; Grau, O.

    2017-12-01

    Tropical forests account for over one third of global terrestrial gross primary productivity and cycle more C than any other ecosystem on Earth. However, we still lack a mechanistic understanding of how such high productivity is maintained on the old, highly weathered and phosphorus depleted soils in the tropics. We hypothesized that heterogeneity in soil texture, mineralogy and microbial community composition may be the major drivers of differences in soil C storage and P limitation across tropical forests. We sampled 12 forest sites across a 200 km transect in the humid neo-tropics of French Guiana that varied in soil texture, precipitation and mineralogy. We found that soil texture was a major driver of soil carbon stocks and forest life history strategy, where sandy forests have lower soil C stocks, slower turnover and decomposition and a more closed nutrient cycle while clayey forests have higher soil C stocks, faster turnover and a more leaky nutrient cycle (using natural abundance stable isotope evidence). We found that although the presence of Al and Fe oxides in the clayey soils occludes soil organic matter and P, a greater abundance of arbuscular mycorrhizal fungi help forests to access occluded P in clayey soils fueling higher turnover and faster decomposition rates. Evidence from a laboratory incubation of tropical soils with nutrient additions further demonstrates the de-coupling of microbial P demands from C:N limitations providing further evidence for the need to examine microbial stoichiometry to explain C cycling in the P-limited tropics. We argue that microbial community composition and physiological demands, constrained within the limitations of soil mineralogical reactivity, largely controls nutrient and C cycling in tropical forest soils. Together our observational field study and laboratory incubation provide a unique dataset to shed light on the mineralogical and microbial controls on C and nutrient cycling in tropical soils. By integrating

  4. In Situ Planetary Mineralogy Using Simultaneous Time Resolved Fluorescence and Raman Spectroscopy

    Science.gov (United States)

    Blacksberg, J.; Rossman , G.R.

    2011-01-01

    Micro-Raman spectroscopy is one of the primary methods of mineralogical analysis in the laboratory, and more recently in the field. Because of its versatility and ability to interrogate rocks in their natural form it is one of the front runners for the next generation of in situ instruments designed to explore adverse set of solar system bodies (e.g. Mars, Venus, the Moon, and other primitive bodies such as asteroids and the Martian moons Phobos and Deimos), as well as for pre-selection of rock and soil samples for potential cache and return missions.

  5. The uranium source-term mineralogy and geochemistry at the Broubster natural analogue site, Caithness

    International Nuclear Information System (INIS)

    Milodowski, A.E.; Pearce, J.M.; Basham, I.R.; Hyslop, E.K.

    1991-01-01

    The British Geological Survey (BGS) has been conducting a coordinated research programme at the Broubster natural analogue site in Caithness, north Scotland. This work on a natural radioactive geochemical system has been carried out with the aim of improving our confidence in using predictive models of radionuclide migration in the geosphere. This report is one of a series being produced and it concentrates on the mineralogical characterization of the uranium distribution in the limestone unit considered as the 'source-term' in the natural analogue model

  6. The mineralogic evolution of the Martian surface through time: Implications from chemical reaction path modeling studies

    Science.gov (United States)

    Plumlee, G. S.; Ridley, W. I.; Debraal, J. D.; Reed, M. H.

    1993-01-01

    Chemical reaction path calculations were used to model the minerals that might have formed at or near the Martian surface as a result of volcano or meteorite impact driven hydrothermal systems; weathering at the Martian surface during an early warm, wet climate; and near-zero or sub-zero C brine-regolith reactions in the current cold climate. Although the chemical reaction path calculations carried out do not define the exact mineralogical evolution of the Martian surface over time, they do place valuable geochemical constraints on the types of minerals that formed from an aqueous phase under various surficial and geochemically complex conditions.

  7. Mineralogical, geochemical and hydrocarbon potential of subsurface Cretaceous shales, Northern Western Desert, Egypt

    Directory of Open Access Journals (Sweden)

    D.A. Mousa

    2014-03-01

    Full Text Available Twenty four Cretaceous shale core samples of Gibb Afia-1, Betty-1, Salam-1X and Mersa Matruh-1 wells were mineralogically and geochemically studied using XRD, XRF and Rock Eval Pyrolysis. Kaolinite, smectite and illite are the main clay minerals in addition to rare chlorite, while the non-clay minerals include quartz, calcite, dolomite and rare siderite. The shales were derived through intensive chemical weathering of mafic basement and older sedimentary rocks. These sediments were deposited in a near-shore shallow marine environment with some terrestrial material input. The shales have poor to fair organic content. It is marginally to rarely mature.

  8. Comparison of the Mineralogy of Comet Wild 2 Coma Grains to Other Astromaterials

    Science.gov (United States)

    Frank, David; Zolensky, Michael

    2010-01-01

    We propose that Kuiper Belt samples (in this case comet coma grains from the Jupiter family comet Wild 2) are recognizably different from the bulk of materials in outer belt asteroids, because of their different formation positions and times in the early solar system. We believe this despite similarities found between some Wild 2 grains and components of carbonaceous chondrites (i.e. some CAI and chondrules). Kuiper Belt samples must preserve measurable mineralogical and compositional evidence of formation at unique positions and times in the early solar nebula, and these formational differences must have imparted recognizable special characteristics. We hypothesize that these characteristics include: (1) Unique major element compositional ranges of common astromaterial minerals, especially olivine and pyroxene; (2) Unique minor element compositions of major silicate phases, especially olivine and low-Ca pyroxene; (3) Degree and effects of radiation processing -- including amorphous rims, metal coatings, and Glass with Embedded Metal and Sulfides (GEMS); (4) Presence of abundant presolar silicate grains as recognized by anomalous oxygen in silicates; (5) Oxidation state of the mineral assemblage. We are working our way through all available Wild 2 samples, selecting 1-2 non-consecutive viable TEM grids from each possible extracted Wild 2 grain. We especially prefer TEM grids from grains for which complete mineralogical details have not been published (which is to say the majority of the extracted grains). We are performing a basic mineralogic survey by E-beam techniques, to establish the essential features of the extracted Wild 2 grains. We are making a particular effort to carefully and accurately measure minor elements of olivine and pyroxene, as these minerals are widespread in astromaterials, and comparisons of their compositions will serve to place the Wild 2 silicates in contact with asteroids, meteorites and chondritic interplanetary dust particles

  9. Mineralogical and geochemical study of contaminated soils on abandoned Sb deposits Dubrava and Poproc

    International Nuclear Information System (INIS)

    Klimko, T.; Jurkovic, L.

    2010-01-01

    In this paper we present initial results of mineralogical and geochemical study of secondary mineral phases, often with a high content of Sb and As, resulting from oxidation of sulphide minerals in the soil environment on two, now abandoned Sb deposits. Dubrava deposit is situated on the northern slopes of the Dumbier Low Tatras and Poproc deposit is located in the eastern part of Spis-Gemer Rudohorie. Both studied sites were in the past (second half of 20 th century) significant producers of antimony ore and Dubrava deposit belonged to medium-sized Sb deposits in the world.

  10. Basalts as probes of planetary interiors: constraints on the chemistry and mineralogy of their source regions

    International Nuclear Information System (INIS)

    Bence, A.E.; Grove, T.L.; Papike, J.J.

    1980-01-01

    Basalt magmas, derived by the partial melting of planetary interiors, have compositions that reflect the pre-accretionary history of the material from which the planet formed, the planets, subsequent evolutionary history, the chemistry and mineralogy of the source regions, and the intensive thermodynamic parameters operating at the source and emplacement sites. Studies of basalt suites from the Earth, its Moon, and the eucrite parent body reveal compositional differences intrinsic to their source regions which are, in turn, a characteristic of the planet and its formational and evolutionary history. (Auth.)

  11. Mineralogy, early marine diagenesis, and the chemistry of shallow-water carbonate sediments

    Science.gov (United States)

    Higgins, J. A.; Blättler, C. L.; Lundstrom, E. A.; Santiago-Ramos, D. P.; Akhtar, A. A.; Crüger Ahm, A.-S.; Bialik, O.; Holmden, C.; Bradbury, H.; Murray, S. T.; Swart, P. K.

    2018-01-01

    Shallow-water carbonate sediments constitute the bulk of sedimentary carbonates in the geologic record and are widely used archives of Earth's chemical and climatic history. One of the main limitations in interpreting the geochemistry of ancient carbonate sediments is the potential for post-depositional diagenetic alteration. In this study, we use paired measurements of calcium (44Ca/40Ca or δ44Ca) and magnesium (26Mg/24Mg or δ26Mg) isotope ratios in sedimentary carbonates and associated pore-fluids as a tool to understand the mineralogical and diagenetic history of Neogene shallow-water carbonate sediments from the Bahamas and southwest Australia. We find that the Ca and Mg isotopic composition of bulk carbonate sediments at these sites exhibits systematic stratigraphic variability that is related to both mineralogy and early marine diagenesis. The observed variability in bulk sediment Ca isotopes is best explained by changes in the extent and style of early marine diagenesis from one where the composition of the diagenetic carbonate mineral is determined by the chemistry of the fluid (fluid-buffered) to one where the composition of the diagenetic carbonate mineral is determined by the chemistry of the precursor sediment (sediment-buffered). Our results indicate that this process, together with variations in carbonate mineralogy (aragonite, calcite, and dolomite), plays a fundamental and underappreciated role in determining the regional and global stratigraphic expressions of geochemical tracers (δ13C, δ18O, major, minor, and trace elements) in shallow-water carbonate sediments in the geologic record. Our results also provide evidence that a large shallow-water carbonate sink that is enriched in 44Ca can explain the mismatch between the δ44/40Ca value of rivers and deep-sea carbonate sediments and call into question the hypothesis that the δ44/40Ca value of seawater depends on the mineralogy of primary carbonate precipitations (e.g. 'aragonite seas' and

  12. Mineralogical and Thermal Properties of Poly(methyl methacrylate) Alite Composite

    International Nuclear Information System (INIS)

    Ismail, M.R.; El-Fass, M.M.; Abd-El-Rahman, H.A.; El-Miligy, A.A.

    1999-01-01

    The X-ray diffraction (XRD) characteristics and thermal stability of PMMA alite composite have been studied. The dried alite samples were impregnated by methyl methacrylate monomer and then subjected to gamma irradiation. The mineralogical and thermal properties of the PMMA alite composite materials were investigated by using XRD, DTA, and TGA techniques. The results indicate that, a markedly reduction of the peaks intensities of XRD for tricalcium silicate and calcium hydroxide. TGA data showed that PMMA alite composite has a high thermal stability as compared to PMMA

  13. Subsurface variations in arsenic mineralogy and geochemistry following long-term weathering of gold mine tailings

    International Nuclear Information System (INIS)

    DeSisto, Stephanie L.; Jamieson, Heather E.; Parsons, Michael B.

    2016-01-01

    Variations in arsenic (As) mineralogy and geochemical controls on its mobility were evaluated in subsurface tailings at the historical Montague and Goldenville mine sites in Nova Scotia, Canada. Tailings at these sites contain some of the highest As concentrations in Nova Scotia and are located in close proximity to local communities. Pore water in the subsurface tailings is characterized by circumneutral to alkaline pH (6.2 to 8.7) and mildly reducing to oxidizing redox conditions (+130 mV to +347 mV). Bulk chemistry, scanning electron microscopy, and synchrotron micro-X-ray diffraction analyses showed As mineral hosts differ with depth. The deepest tailings (max. 2 m) are in direct contact with partially decomposed vegetation, which supports reducing conditions and the precipitation of authigenic As and Fe sulfides. Under reducing conditions, dissolved As concentrations are also controlled by desorption of As from dissolution of Fe and Mn oxides and the sorption or co-precipitation of As with carbonates. These geochemical controls differ from those influencing dissolved As concentrations under oxidizing conditions. In the near surface, As mobility is controlled by oxidative dissolution of primary arsenopyrite, precipitation of secondary Fe arsenates, Fe oxyhydroxides and Mn oxides, secondary Ca-Fe arsenates, and sorption onto Fe oxyhydroxides and gangue minerals. Some of these mineral species are stable under different conditions yet occur in close association, indicating the importance of microenvironments. The results of this study show that the weathering characteristics of these tailings vary with depth, leading to the formation of new As hosts that are distinct from those observed in the near surface. Identification of these As hosts provides an understanding of current controls on As mobility and has implications for future reprocessing and/or remediation efforts. - Highlights: • Subsurface mineralogy does not reflect surface tailings end

  14. Mineralogia de um latossolo vermelho distrófico submetido a diferentes manejos por 24 anos Mineralogy of a red latosol under different management systems for twenty-four years

    Directory of Open Access Journals (Sweden)

    Daniele Gonçalves

    2008-12-01

    Full Text Available Atualmente, procuram-se sistemas de manejo que preservem ou melhorem as qualidades do solo, tanto mineralógicas como orgânicas, priorizando maior produtividade. Este trabalho teve como objetivo verificar qualitativamente, por meio das técnicas de fluorescência de raios X, difração de raios X e infravermelho com transformada de Fourier, os efeitos provocados pela utilização dos manejos: plantio convencional, preparo mínimo e plantio direto, por 24 anos, na mineralogia de um Latossolo Vermelho distrófico de Ponta Grossa, PR. Não foram observadas mudanças significativas na mineralogia do Latossolo estudado, por meio das técnicas utilizadas, quanto aos diferentes manejos durante os anos de sua aplicação. Pôde-se verificar, qualitativamente, a presença dos minerais gibbsita, caulinita, haloisita, montmorilonita, hematita, rutilo, anatásio, goethita e quartzo.The search for management systems that preserve or improve soil qualities, the mineralogical as well as the organic composition, with a view to higher yields, is becoming more and more intense. The objective this study was to qualitatively verify the mineralogical effects of different management types: conventional , minimum and no-tillage for 24 years on a Red Latosol in Ponta Grossa, PR, Brazil, by the following techniques: X-ray diffraction, X-ray fluorescence and Fourier transform infrared. No significant changes in the mineralogy of the Red Latosol were observed by the techniques applied, as a result of the different management types. It was however possible to qualitatively verify the presence of the following minerals: gibbsite, kaolinite, halloysite, montmorillonite, hematite, rutile, anatase, goethite and quartz.

  15. Transformative environmental governance

    Science.gov (United States)

    Chaffin, Brian C.; Garmestani, Ahjond S.; Gunderson, Lance H.; Harm Benson, Melinda; Angeler, David G.; Arnold, Craig Anthony (Tony); Cosens, Barbara; Kundis Craig, Robin; Ruhl, J.B.; Allen, Craig R.

    2016-01-01

    Transformative governance is an approach to environmental governance that has the capacity to respond to, manage, and trigger regime shifts in coupled social-ecological systems (SESs) at multiple scales. The goal of transformative governance is to actively shift degraded SESs to alternative, more desirable, or more functional regimes by altering the structures and processes that define the system. Transformative governance is rooted in ecological theories to explain cross-scale dynamics in complex systems, as well as social theories of change, innovation, and technological transformation. Similar to adaptive governance, transformative governance involves a broad set of governance components, but requires additional capacity to foster new social-ecological regimes including increased risk tolerance, significant systemic investment, and restructured economies and power relations. Transformative governance has the potential to actively respond to regime shifts triggered by climate change, and thus future research should focus on identifying system drivers and leading indicators associated with social-ecological thresholds.

  16. Mid-IR Spectra of Refractory Minerals Relevant to Comets

    Science.gov (United States)

    Jauhari, Shekeab

    2008-09-01

    On 4 July 2005 the Spitzer Space Telescope obtained mid-IR ( 5-40 µm) spectra of the ejecta from the hypervelocity impact of the Deep Impact projectile with comet 9P/Tempel 1. Spectral modeling demonstrates that there are abundant minerals present in the ejecta including Ca/Fe/Mg-rich silicates, carbonates, phyllosilicates, water ice, amorphous carbon, and sulfides [1]. However, precise mineralogical identifications are hampered by the lack of comprehensive 5 - 40 µm spectral measurements of the emissivity for a broad compositional range of these materials. Here, we present our initial results for 2 - 50 µm transmission spectra and absorption constants for materials relevant to comets, including pyrrhotite, pyrite, and several phyllosilicate (clay) minerals. Measuring the transmission of materials over the full spectral range sensitive by Spitzer requires grinding the minerals into submicron powders and then mixing them with KBr (for the 1-25 um region) and polyethylene (16-50 um region) to form pellets. Transmission measurements of sub-micron sulfides are particularly difficult to obtain because the minerals oxidize rapidly upon grinding and subsequent handling unless special care is taken. A detailed description of our sample preparation and measurement technique will be provided to assist other researchers in their attempts to acquire similar spectra. References: [1] Lisse, C.M. et al., Science 313, 635 - 640 (2006)

  17. Quantized Bogoliubov transformations

    International Nuclear Information System (INIS)

    Geyer, H.B.

    1984-01-01

    The boson mapping of single fermion operators in a situation dominated by the pairing force gives rise to a transformation that can be considered a quantized version of the Bogoliubov transformation. This transformation can also be obtained as an exact special case of operators constructed from an approximate treatment of particle number projection, suggesting a method of obtaining the boson mapping in cases more complicated than that of pairing force domination

  18. Phase transformation and diffusion

    CERN Document Server

    Kale, G B; Dey, G K

    2008-01-01

    Given that the basic purpose of all research in materials science and technology is to tailor the properties of materials to suit specific applications, phase transformations are the natural key to the fine-tuning of the structural, mechanical and corrosion properties. A basic understanding of the kinetics and mechanisms of phase transformation is therefore of vital importance. Apart from a few cases involving crystallographic martensitic transformations, all phase transformations are mediated by diffusion. Thus, proper control and understanding of the process of diffusion during nucleation, g

  19. The convolution transform

    CERN Document Server

    Hirschman, Isidore Isaac

    2005-01-01

    In studies of general operators of the same nature, general convolution transforms are immediately encountered as the objects of inversion. The relation between differential operators and integral transforms is the basic theme of this work, which is geared toward upper-level undergraduates and graduate students. It may be read easily by anyone with a working knowledge of real and complex variable theory. Topics include the finite and non-finite kernels, variation diminishing transforms, asymptotic behavior of kernels, real inversion theory, representation theory, the Weierstrass transform, and

  20. Coaxial pulse matching transformer

    International Nuclear Information System (INIS)

    Ledenev, V.V.; Khimenko, L.T.

    1986-01-01

    This paper describes a coaxial pulse matching transformer with comparatively simple design, increased mechanical strength, and low stray inductance. The transformer design makes it easy to change the turns ratio. The circuit of the device and an expression for the current multiplication factor are presented; experiments confirm the efficiency of the transformer. Apparatus with a coaxial transformer for producing high-power pulsed magnetic fields is designed (current pulses of 1-10 MA into a load and a natural frequency of 100 kHz)

  1. Distributed photovoltaic grid transformers

    CERN Document Server

    Shertukde, Hemchandra Madhusudan

    2014-01-01

    The demand for alternative energy sources fuels the need for electric power and controls engineers to possess a practical understanding of transformers suitable for solar energy. Meeting that need, Distributed Photovoltaic Grid Transformers begins by explaining the basic theory behind transformers in the solar power arena, and then progresses to describe the development, manufacture, and sale of distributed photovoltaic (PV) grid transformers, which help boost the electric DC voltage (generally at 30 volts) harnessed by a PV panel to a higher level (generally at 115 volts or higher) once it is

  2. Shippingport: A relevant decommissioning project

    International Nuclear Information System (INIS)

    Crimi, F.P.

    1988-01-01

    Because of Shippingport's low electrical power rating (72 MWe), there has been some misunderstanding on the relevancy of the Shippingport Station Decommissioning Project (SSDP) to a modern 1175 MWe commercial pressurized water reactor (PWR) power station. This paper provides a comparison of the major components of the reactor plant of the 72 MWe Shippingport Atomic Power Station and an 1175 MWe nuclear plant and the relevancy of the Shippingport decommissioning as a demonstration project for the nuclear industry. For the purpose of this comparison, Portland General Electric Company's 1175 MWe Trojan Nuclear Plant at Rainier, Oregon, has been used as the reference nuclear power plant. 2 refs., 2 figs., 1 tab

  3. A relation connecting scale transformation, Galilean transformation and Baecklund transformation for the nonlinear Schroedinger equation

    International Nuclear Information System (INIS)

    Steudel, H.

    1980-01-01

    It is shown that the two-parameter manifold of Baecklund transformations known for the nonlinear Schroedinger equation can be generated from one Baecklund transformation with specified parameters by use of scale transformation and Galilean transformation. (orig.)

  4. Discrete Gabor transform and discrete Zak transform

    NARCIS (Netherlands)

    Bastiaans, M.J.; Namazi, N.M.; Matthews, K.

    1996-01-01

    Gabor's expansion of a discrete-time signal into a set of shifted and modulated versions of an elementary signal or synthesis window is introduced, along with the inverse operation, i.e. the Gabor transform, which uses an analysis window that is related to the synthesis window and with the help of

  5. Significance of mineralogy in the development of flowsheets for processing uranium ores

    International Nuclear Information System (INIS)

    1980-01-01

    This report has been prepared from material developed at and subsequent to a consultants' meeting held in Vienna in January 1978. The main purpose of the meeting was to prepare a document in the form of a guide for planning and developing treatment flowsheets for uranium ore processing. It was apparent that ore mineralogy, analysed, described and interpreted in ways most meaningful to the metallurgist, is the most essential information required for forming the basis of such planning. This topic, here termed metallurgical mineralogy, is therefore a major theme of this publication. In preparing the report the Agency has borne in mind the important need to impart the experience and knowledge gained in the more developed countries to those who are in the early stages of exploiting their uranium resources. The contents may be criticized as lacking, in some respects, the requisite depth and detail of treatment. The Agency and the consultants are conscious of the need to expand the information in a number of ways. However, the report is presented in its present form in the belief that, as the first attempt to correlate, on a world-wide basis, ore type with processing, it will be considered as a useful basis for future development of these themes

  6. Relationship between water chemistry and sediment mineralogy in the Cerro Prieto geothermal field: a preliminary report

    Energy Technology Data Exchange (ETDEWEB)

    Valette-Silver, J.N. (Univ. de Perpignan, France); Thompson, J.M.; Ball, J.W.

    1981-01-01

    The chemical compositions of waters collected from the Cerro Prieto geothermal production wells and hydrothermal emanations are different. Compared to the Cerro Prieto well waters, the surficial waters generally contain significantly less potassium, slightly less calcium and chloride, and significantly more magnesium and sulfate. In comparison to the unaltered sediments, the changes in the mineralogy of the altered sediments appear to be controlled by the type of emanation (well, spring, mud pot, geyser, fumarole, or cold pool). However, an increase in quartz and potassium feldspar percentages seems to be characteristic of the majority of the sediments in contact with geothermal fluids. Preliminary attempts to model the chemical processes occurring in the Cerro Prieto geothermal field using chemical equilibrium calculations are reported. For this purpose the chemical compositions of thermal waters (well and surficial emanation) were used as input data to make calculations with SOLMNEQ and WATEQ2 computer programs. Then the theoretical mineral composition of altered sediments was predicted and compared to the mineralogy actually observed in the solid samples.

  7. The mineralogical behavior of the phosphatic sedimentation in Pernambuco-Paraiba sedimentar coastal basin

    International Nuclear Information System (INIS)

    Albuquerque Menor, E. de; Amaral, A.J.R. do

    1979-01-01

    This work reports the execution of the ''Phosphate in the Sedimentary coastal zone of Pernambuco-Paraiba'' Project, resulting from the execution of 35 drilling holes distributed between Paulista City, State of Pernambuco and the Miriri river valley, State of Paraiba. The rocks were analysed by X-ray diffraction, and the results were used in the working up of mineralogical logs. The mineralogical logs interpretation makes possible to distinguish phosphorite and sandy phosphorite areas inside a mineralization zone, wich laterally passes to a phosphatic carbonatic rocks area situated far from cost line of that epoch. Differences of the mineral paragenesis are used under a regional sedimentar model conception and indicated as prospecting guides. The dominance of Kaolinite is related to continental sediments (Beberibe Formation). The dominance of montmorillonite, on the other hand, is more to marine facies than to particular conditions of the phosphatic mineralization. The analysis of these conditions shows that the continental areas resistant to the pre-Maestrichtrian transegressive oscillations coincide to the more favourable places to the phosphatic mineralization. (author) [pt

  8. Mineralogy and origin of atmospheric particles in the industrial area of Huelva (SW Spain)

    Science.gov (United States)

    Bernabé, J. M.; Carretero, M. I.; Galán, E.

    The mineralogy of atmospheric particles at the confluence of the Tinto and Odiel rivers, south of Huelva (a highly industrialized city in the SW Spain), was characterized in view to identify source origins. In spite of the small amount of sample collected, mineralogical characterization was performed by X-ray diffraction, polarized light microscopy and scanning electron microscopy with EDS analysis system, using an adequate sample preparation methodology. Sedimentable (SP) and aerosols particles were sampled an one-week basis every two months for one year. Quartz, calcite and feldspars were found to be the major minerals in both fractions, and phyllosilicates, dolomite and gypsum were also identified in lower content. Minor mineral particles included barite, apatite, sphalerite and pyrite. SEM studies revealed the additional presence of chalcopyrite in both SP and aerosols, and of chalcocite-covellite, halite and sylvite in the latter. Siderite, hematite and ankerite were only detected in the SP fraction. The concentrations of the previous minerals increased in summer by effect of the limited rain and the resulting scarcity of atmosphere washing. Non-mineral particles detected by SEM in SP and aerosol fractions included spherical, biological and compositionally complex particles. The main source of mineral particles was found to be the soil suspension in addition to the metallurgical and fertilizer production industries in the area.

  9. Iron Mineralogy and Speciation in Clay-Sized Fractions of Chinese Desert Sediments

    Science.gov (United States)

    Lu, Wanyi; Zhao, Wancang; Balsam, William; Lu, Huayu; Liu, Pan; Lu, Zunli; Ji, Junfeng

    2017-12-01

    Iron released from Asian desert dust may be an important source of bioavailable iron for the North Pacific Ocean and thereby may stimulate primary productivity. However, the Fe species of the fine dusts from this source region are poorly characterized. Here we investigate iron species and mineralogy in the clay-sized fractions (iron phases (ferrihydrite and lepidocrocite) and reducible iron oxides (dominated by goethite) are 0.81 wt % and 2.39 wt %, respectively, and Fe dissolved from phyllosilicates extracted by boiling HCl (dominated by chlorite) is 3.15 wt %. Dusts originating from deserts in northwestern China, particularly the Taklimakan desert, are relatively enriched in easily reducible Fe phases, probably due to abundant Fe contained in fresh weathering products resulting from the rapid erosion associated with active uplift of mountains to the west. Data about Fe speciation and mineralogy in Asian dust sources will be useful for improving the quantification of soluble Fe supplied to the oceans, especially in dust models.

  10. Mineralogy and petrography of Caithness Flagstones used in sorption experiments by Harwell Laboratories

    International Nuclear Information System (INIS)

    Bloodworth, A.J.; Kemp, S.J.; Inglethorpe, S.D.J.; Morgan, D.J.

    1989-03-01

    The mineralogy and petrography of a suite of samples taken from the Caithness Flagstones are described. Samples were collected from core material obtained from a borehole beneath DNE Dounreay, Highland Region, and are duplicates of those used in sorption experiments by Harwell Laboratories. The geological background of the samples is described, with particular emphasis on the development of lithologically distinct facies within the laminated lacustrine sediments examined in this study. Optical examination reveals distinctive sedimentary structures and petrofabrics associated with different lithofacies. Lithofacies type is also reflected in mineralogical variation within the sequence. Highly-laminated, deeper-water facies rocks are typified by the presence of ferroan-dolomite cement, with relatively high clay and organic matter contents. Detrital quartz and feldspar are more abundant in the shallow water facies and the carbonate assemblage in these rocks is dominated by calcite. Though total clay content varies with facies, the distribution of clay mineral species remains largely identical. There is a complex pattern of carbonate and pyrite diagenesis within these sediments. (author)

  11. Chemical, mineralogical and ceramic properties of clays from Northern Santa Catarina, Brazil

    International Nuclear Information System (INIS)

    Correia, S.L.; Bloot, E.L.; Folgueras, M.V.; Hotza, D.

    2009-01-01

    Clay materials crop out in the northern Santa Catarina mining district were investigated in order to assess their potential in the ceramic industry. Four different clays (A, B, C and D) were selected. Their chemical composition was obtained by Xray fluorescence and their mineralogy by X-ray diffraction, coupled with numerical rational analysis. Their thermal behaviour was studied by differential thermal analysis. Technological testing consisted in a simulation of the industrial processing performed at a laboratory scale. The test pieces were obtained by pressing and fired in the range of 850-1200 deg C. In each case their technological properties were studied. The main mineralogical phases detected were kaolinite, quartz and mica. Hematite and feldspars may be present in the clays. The clays show two groups of particle sizes almost equally frequent in the range of 1 to 60 μm. The northern Santa Catarina clays are suitable for the production of bricks and earthenware in the 900- 1100 deg C range. (author)

  12. Mineralogical, textural, structural and geochemical aspects of Nakhlak lead mine, Isfahan

    Directory of Open Access Journals (Sweden)

    Mohammad Ali Jazi

    2010-11-01

    Full Text Available Nakhlak lead mine is located at the Nakhlak mountain 55 km NE of Anarak town in Isfahan province. The mineralogy is simple; galena and barite are the main primary minerals and cerussite is the main secondary mineral. Sphalerite, pyrite, chalcopyrite, tetrahedrite-tennantite and acanthite occur as minor and trace mineral inclusions in galena. Secondary minerals are anglesite, plattnerite, wulfenite and malachite. The host rock has undergone a pre-mineralization dolomitization process. Four types of dolomite have been identified which saddle dolomite is the most distinguished. Open space filling textures occur in the form of breccia, cockade, crustification and colloform. Analysis of the galena samples indicates presence of many trace elements in galena among which silver is the most important. Element pairs such as Ag-As, Zn-Cd, As-Cu and As-Sb are highly correlated. This correlation may be explained by the presence of inclusions. Ag-Sb-Bi ternary diagram indicates that galena samples from Nakhlak are rich in Ag and Sb and poor in Bi. Sb/Bi (3773 ratio in galena is suggestive of a low temperature of formation for the deposit. The Upper Cretaceous carbonate host rocks and their dolomitization, the stratabound and epigenetic mineralization, the absence of igneous activity, the open space filling texture, the simple mineralogy and geochemistry all point to a Mississippi valley type model for the Nakhlak Pb deposit.

  13. Clays for brick manufacturing in Actopan, Hidalgo: physical, chemical and mineralogical characterization

    Energy Technology Data Exchange (ETDEWEB)

    Moreno-Tovar, Raul; Yañez-Hernández, Osiris Annel; Pérez-Moreno, Fidel; Rodríguez-Lugo, Ventura [Área de Ciencias de la Tierra y Materiales, Universidad Autónoma del Estado de Hidalgo (Mexico); Rivera, José de Jesús Cruz [Universidad Autónoma de San Luis Potosí (Mexico); Rivera, Ana Leonor, E-mail: analeonor.ventura.2016@gmail.com [Universidad Nacional Autónoma de México, DF (Mexico)

    2017-10-15

    Samples of clays from Actopan, Hidalgo employed in brick manufacturing are physical, chemical and mineralogical characterized. Transmitted polarized light microscopy showed a uniform particle size with grain morphology characteristic of euhedral crystals with quartz, feldspars, nontronite, and iron oxides particles. Scanning Electron Microscopy revealed 75 μm to 90 μm wide subhedral structures formed by particles from 2.0 μm to 5.0 μm; and rombohedrales forms 40 μm wide, 70 µm long, constituted of silicon, aluminum, iron, titanium, calcium, minor amounts of potassium, magnesium, and sodium. Minerals such as quartz, albite, cristobalite, calcium and Hematite phases were recognized by X-Ray Diffraction technique. Chemical analysis by atomic emission spectrometry with Inductively Coupled Plasma confirmed this mineralogy composition while laser granulometry method found the same particle size. Grain size analysis determined submicrometric dimensions, and multimodal type curves, that can be interpreted as the mixing of two or more different mineral phases in each sample. (author)

  14. The Private Lives of Minerals: Social Network Analysis Applied to Mineralogy and Petrology

    Science.gov (United States)

    Hazen, R. M.; Morrison, S. M.; Fox, P. A.; Golden, J. J.; Downs, R. T.; Eleish, A.; Prabhu, A.; Li, C.; Liu, C.

    2016-12-01

    Comprehensive databases of mineral species (rruff.info/ima) and their geographic localities and co-existing mineral assemblages (mindat.org) reveal patterns of mineral association and distribution that mimic social networks, as commonly applied to such varied topics as social media interactions, the spread of disease, terrorism networks, and research collaborations. Applying social network analysis (SNA) to common assemblages of rock-forming igneous and regional metamorphic mineral species, we find patterns of cohesion, segregation, density, and cliques that are similar to those of human social networks. These patterns highlight classic trends in lithologic evolution and are illustrated with sociograms, in which mineral species are the "nodes" and co-existing species form "links." Filters based on chemistry, age, structural group, and other parameters highlight visually both familiar and new aspects of mineralogy and petrology. We quantify sociograms with SNA metrics, including connectivity (based on the frequency of co-occurrence of mineral pairs), homophily (the extent to which co-existing mineral species share compositional and other characteristics), network closure (based on the degree of network interconnectivity), and segmentation (as revealed by isolated "cliques" of mineral species). Exploitation of large and growing mineral data resources with SNA offers promising avenues for discovering previously hidden trends in mineral diversity-distribution systematics, as well as providing new pedagogical approaches to teaching mineralogy and petrology.

  15. Clays for brick manufacturing in Actopan, Hidalgo: physical, chemical and mineralogical characterization

    International Nuclear Information System (INIS)

    Moreno-Tovar, Raul; Yañez-Hernández, Osiris Annel; Pérez-Moreno, Fidel; Rodríguez-Lugo, Ventura; Rivera, José de Jesús Cruz; Rivera, Ana Leonor

    2017-01-01

    Samples of clays from Actopan, Hidalgo employed in brick manufacturing are physical, chemical and mineralogical characterized. Transmitted polarized light microscopy showed a uniform particle size with grain morphology characteristic of euhedral crystals with quartz, feldspars, nontronite, and iron oxides particles. Scanning Electron Microscopy revealed 75 μm to 90 μm wide subhedral structures formed by particles from 2.0 μm to 5.0 μm; and rombohedrales forms 40 μm wide, 70 µm long, constituted of silicon, aluminum, iron, titanium, calcium, minor amounts of potassium, magnesium, and sodium. Minerals such as quartz, albite, cristobalite, calcium and Hematite phases were recognized by X-Ray Diffraction technique. Chemical analysis by atomic emission spectrometry with Inductively Coupled Plasma confirmed this mineralogy composition while laser granulometry method found the same particle size. Grain size analysis determined submicrometric dimensions, and multimodal type curves, that can be interpreted as the mixing of two or more different mineral phases in each sample. (author)

  16. Tracing of aerosol sources in an urban environment using chemical, Sr isotope, and mineralogical characterization.

    Science.gov (United States)

    Duarte, Regina M B O; Matos, João T V; Paula, Andreia S; Lopes, Sónia P; Ribeiro, Sara; Santos, José Francisco; Patinha, Carla; da Silva, Eduardo Ferreira; Soares, Rosário; Duarte, Armando C

    2017-04-01

    In the framework of two national research projects (ORGANOSOL and CN-linkAIR), fine particulate matter (PM 2.5 ) was sampled for 17 months at an urban location in the Western European Coast. The PM 2.5 samples were analyzed for organic carbon (OC), water-soluble organic carbon (WSOC), elemental carbon (EC), major water-soluble inorganic ions, mineralogical, and for the first time in this region, strontium isotope ( 87 Sr/ 86 Sr) composition. Organic matter dominates the identifiable urban PM 2.5 mass, followed by secondary inorganic aerosols. The acquired data resulted also in a seasonal overview of the carbonaceous and inorganic aerosol composition, with an important contribution from primary biomass burning and secondary formation processes in colder and warmer periods, respectively. The fossil-related primary EC seems to be continually present throughout the sampling period. The 87 Sr/ 86 Sr ratios were measured on both the labile and residual PM 2.5 fractions as well as on the bulk PM 2.5 samples. Regardless of the air mass origin, the residual fractions are more radiogenic (representative of a natural crustal dust source) than the labile fractions, whose 87 Sr/ 86 Sr ratios are comparable to that of seawater. The 87 Sr/ 86 Sr ratios and the mineralogical composition data further suggest that sea salt and mineral dust are important primary natural sources of fine aerosols throughout the sampling period.

  17. Data-driven exploration of copper mineralogy and its application to Earth's near-surface oxidation

    Science.gov (United States)

    Morrison, S. M.; Eleish, A.; Runyon, S.; Prabhu, A.; Fox, P. A.; Ralph, J.; Golden, J. J.; Downs, R. T.; Liu, C.; Meyer, M.; Hazen, R. M.

    2017-12-01

    Earth's atmospheric composition has changed radically throughout geologic history.1,2 The oxidation of our atmosphere, driven by biology, began with the Great Oxidation Event (GOE) 2.5 Ga and has heavily influenced Earth's near surface mineralogy. Therefore, temporal trends in mineral occurrence elucidate large and small scale geologic and biologic processes. Cu, and other first-row transition elements, are of particular interest due to their variation in valance state and sensitivity to ƒO2. Widespread formation of oxidized Cu mineral species (Cu2+) would not have been possible prior to the GOE and we have found that the proportion of oxidized Cu minerals increased steadily with the increase in atmospheric O2 on Earth's surface (see Fig. 1). To better characterize the changes in Cu mineralogy through time, we have employed advanced analytical and visualization methods. These techniques rely on large and growing mineral databases (e.g., rruff.info, mindat.org, earthchem.org, usgs.gov) and allow us to quantify and visualize multi-dimensional trends.5

  18. Mineralogy of drill hole UE-25pnumber1 at Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    Chipera, S.J.; Bish, D.L.

    1988-05-01

    Drill hole UE-25p/number sign/1 is located east of the candidate repository block at Yucca Mountain, Nevada, and as such provides information on the geology of the accessible environment. The hole was drilled to a depth of 1807 m (5923 ft) and is unique in that it penetrates tuffs that are older than any volcanic units previously encountered in drill holes at Yucca Mountain. In addition, it is the only hole drilled to date that penetrates the base of the tuff sequence and enters the underlying Paleozoic dolomite basement. We have examined the mineralogy of drill cuttings, core, and sidewall samples from drill hole UE-25p/number sign/1 is similar to that in the other drill holes examined at Yucca Mountain. The only significant differences in mineralogy from other drill holes include the presence of dolomite in the Paleozoic carbonate rocks and the occurrence of up to 3% laumontite, a Ca-zeolite, in four samples of the Lithic Ridge Tuff. 15 refs., 5 figs., 4 tabs

  19. Study of chemical-mineralogical properties of modified soils with polymers addition

    Directory of Open Access Journals (Sweden)

    Patricio Jonny

    2016-01-01

    Full Text Available On highways, the soil is considered a supported material and compound pavements layers. For this, they must have such characteristics that confer stability and mechanical resistance to traffic internal forces during the pavement life. When soils do not have required characteristics by the project can be used stabilization techniques that make the natural soil adequately to roads requirement. Based on this assumption, this study aimed to evaluate the efficacy of polymer association in soil stabilization for use in roads pavements. Were evaluated chemical and mineralogical properties on two (2 different soils with sample of pure soil and with the addition of the polymer association. Based on the obtained results, polymer association changes was observed on X-ray fluorescent spectrometry (XRF; X-ray diffraction (XRD; scanning electron microscopy (SEM and Methylene blue. In general, the polymeric association studied in this research was effective in chemical and mineralogical analyzes for use on stabilized soils, making this technique efficient for use in layers of road pavements.

  20. Magnetism and magnetic mineralogy of ash flow tuffs from Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    Schlinger, C.M.; Veblen, D.R.; Rosenbaum, J.G.

    1991-01-01

    The magnetic susceptibility χ and remanent magnetization of an ash flow sheet are profoundly influenced by cooling history after emplacement. Maxima and minima in χ measured along profiles at Yucca Mountain, Nevada, identify persistent magnetic marker horizons within vitric portions of the Tiva Canyon and underlying Topopah Spring Members of the Paintbrush Tuff. The observed stratigraphic changes in magnetic properties reflect variations in amounts and mineralogy of Fe-Ti oxide phenocrysts, and the presence, shape, size, and mineralogy of magnetic Fe-oxide microcrystals that precipitated at high temperature after emplacement of each sheet. The size variations of the precipitated Fe-oxides, which were established using transmission electron microscopy (TEM) and petrographic observation, are consistent both with variations in magnetic susceptibility measured at the outcrop and with variations in the intensity of remanent magnetization. Several interpretations of the shape anisotropy of the precipitated Fe-oxide are possible, including growth by a dislocation mechanism. Additionally, the observed elongation of precipitated microcrystals is consistent with theoretical predictions for growth in a uniaxial stress field. Susceptibility variations as established at the outcrop, as well as in the borehole, offer a potentially useful tool for stratigraphic correlation of ash flow sheets

  1. Long term mineralogical changes in salt formations due to water and brine interactions

    International Nuclear Information System (INIS)

    Herbert, H.J.; Brewitz, W.

    1996-01-01

    Four very common long term mineralogical changes in salt formations are discussed in the view of the safety considerations for underground repositories. Two of these processes, the 'Hartsalz' and 'Carnallite' dissolution were studied in two scale in situ experiments. The results are presented and compared with the results of the geochemical modelling with the computer code EQ3/6. Furthermore the reactions leading to the formation of the gypsum cap rock on the top of the Zechstein salt formations and to the polyhalitization of anhydrite are discussed. Geological field observations and mineral assemblages agree well with the results of the geochemical modelling employing the Pitzer formalism along with the Harvie, Moller and Weare database. We conclude that once the mechanisms of the chemical reactions are well understood it becomes possible to evaluate realistically whether such processes, when encountered in the repository, are still active or whether they are finished. It also becomes possible to estimate the volume changes associated with the reactions and thus the impact of these reactions on the integrity and the geomechanical stability of the salt formation. The intimate knowledge of the reaction mechanisms of the short and long term changes in the mineralogical assemblages and the associated brine chemistry is a first prerequisite for the correct evaluation of the origin of brines. Thus, it is essential for the correct assessment of the hazards which brine inflows may pose for the safety of a repository in salt formations. (authors). 8 refs., 14 figs., 8 tabs

  2. Assessment of a sequential extraction protocol by examining solution chemistry and mineralogical evolution

    Science.gov (United States)

    Maubec, Nicolas; Pauwels, Hélène; Noël, Hervé; Bourrat, Xavier

    2015-04-01

    Knowledge of the behavior of heavy metals, such as copper and zinc in sediments, is a key factor to improve the management of rivers. The mobility of these metals, which may be harmful to the environment, depends directly on their concentration and speciation , which in turn depend on physico-chemical parameters such as mineralogy of the sediment fraction, pH, redox potential, salinity etc ... (Anderson et al., 2000; Sterckeman et al., 2004; Van Oort et al., 2008). Several methods based on chemical extractions are currently applied to assess the behavior of heavy metals in soils and sediments. Among them, sequential extraction procedure is widely used in soil and sediment science and provides details about the origin, biological and physicochemical availability, mobilization and transports of trace metals elements. It is based on the use of a series of extracting reagents to extract selectively heavy metals according to their association within the solid phase (Cornu and Clozel, 2000) including the following different fraction : exchangeable, bound to carbonates, associated to oxides (reducible fraction), linked to organic matter and sulfides (oxidizable fraction) as well as silicate minerals so called residual fraction (Hickey and Kittrick, 1984; Tessier et al., 1979). Consequently sequential extraction method is expected to simulate a lot of potential natural and anthropogenic modifications of environmental conditions (Arey et al., 1999; Brannon and Patrick, 1987; Hickey and Kittrick, 1984; La Force et al., 1999; Tessier et al., 1979). For three decades, a large number of protocols has been proposed, characterized by specific reagents and experimental conditions (concentrations, number of steps, extraction orders and solid/solution ratio) (Das et al., 1995; Gomez Ariza et al., 2000; Quevauviller et al., 1994; Rauret, 1998; Tack and Verloo, 1995), but it appeared that several of them suffer from a lack of selectivity of applied reagents: besides target ones, some

  3. Mineralogic and petrologic investigation of pre-test core samples from the spent fuel test-climax

    International Nuclear Information System (INIS)

    Ryerson, F.J.; Qualheim, B.J.

    1983-12-01

    Pre-test samples obtained from just inside the perimeter of the canister emplacement holes of the Spent Fuel Test-Climax have been characterized by petrographic and microanalytical techniques. The primary quartz monzonite has undergone various degrees of hydrothermal alteration as a result of natural processes. Alteration is most apparent on primary plagioclase and biotite. The most common secondary phases on plagioclase are muscovite and calcite, while the most common secondary phases on biotite are epidote and chlorite. The major alteration zones encountered are localized along filled fractures, i.e. veins. The thickness and mineralogy of the alteration zones can be correlated with the vein mineralogy, becoming wider and more complex mineralogically when the veins contain calcite. 7 references, 10 figures, 4 tables

  4. The solonetzic process in surface soils and buried paleosols and its reflection in the mineralogical soil memory

    Science.gov (United States)

    Chizhikova, N. P.; Kovda, I. V.; Borisov, A. V.; Shishlina, N. I.

    2009-10-01

    The development of the solonetzic process in paleosols buried under kurgans and in the modern surface soils has been studied on the basis of the analysis of the clay (memory“ of the solid-phase soil components. The mineralogical characteristics show that the solonetzic process in the modern background soil is more developed. The mineralogical approach allows us to reveal the long-term changes in the soil status; it is less useful for studying the effect of short-term bioclimatic fluctuations. In the latter case, more labile soil characteristics should be used. The mineralogical method, combined with other methods, becomes more informative upon the study of soil chronosequences. Our studies have shown that the data on the clay minerals in the buried paleosols may contain specific information useful for paleoreconstructions that is not provided by other methods.

  5. Applications of Siroquant in mineralogical analysis at BHP Billiton minerals technology

    International Nuclear Information System (INIS)

    Reynolds, J.; England, B.M.

    2002-01-01

    Full text: Newcastle Technology Centre is currently investigating ways of improving the accuracy and efficiency of quantitative mineralogical analysis of iron ores and environmental dusts using Siroquant. The only readily available technique for the quantification of iron oxide and gangue species in iron ores has been the time-consuming modal analysis (point counting) of specially prepared polished sections in reflected light using a petrological microscope. However there are uncertainties associated with bulk sampling and the true reprensensitivity of material mounted in these sections. In addition, the quality of the data depends largely on the training, skill and mineralogical experience of the operator as well as on the quality of the polished section. The data obtained from modal analysis is volumetric and must be converted to weight percent using calculations involving theoretical rather than actual densities. Previous X-ray powder diffraction (XRD) techniques using internal standards (such as corundum) have proved inaccurate and unreliable. To test the validity of using Siroquant to obtain quantitative mineralogical data for iron ores, a series of validation samples was made up to simulate a selection of BHP Billiton iron ores. The results show that reliable and reproducible data can be obtained for hematite/goethite ratios in a wide variety of ore types. However the technique was not without its problems and it was found that particle size, both actual and entered, had a significant effect on the results. It was also found that optimum particle size for samples containing such a wide range of absorption coefficients is smaller than that indicated by standard milling curves, but that longer milling times resulted in overgrinding and non-detection of softer species. Hence the quantification of minor species, especially kaolinite, still presents some problems and these will be investigated through the use of further validation samples. The quantitative

  6. Dramatic lives and relevant becomings

    DEFF Research Database (Denmark)

    Henriksen, Ann-Karina; Miller, Jody

    2012-01-01

    of marginality into positions of relevance. The analysis builds on empirical data from Copenhagen, Denmark, gained through ethnographic fieldwork with the participation of 20 female informants aged 13–22. The theoretical contribution proposes viewing conflicts as multi-linear, multi-causal and non...

  7. Regularization in Matrix Relevance Learning

    NARCIS (Netherlands)

    Schneider, Petra; Bunte, Kerstin; Stiekema, Han; Hammer, Barbara; Villmann, Thomas; Biehl, Michael

    A In this paper, we present a regularization technique to extend recently proposed matrix learning schemes in learning vector quantization (LVQ). These learning algorithms extend the concept of adaptive distance measures in LVQ to the use of relevance matrices. In general, metric learning can

  8. Mineralogical correlation of surficial sediment from area drainages with selected sedimentary interbeds at the Idaho National Engineering Laboratory, Idaho

    Energy Technology Data Exchange (ETDEWEB)

    Bartholomay, R.C.

    1990-08-01

    Ongoing research by the US Geological Survey at the INEL involves investigation of the migration of radioactive elements contained in low-level radioactive waste, hydrologic and geologic factors affecting waste movement, and geochemical factors that influence the chemical composition of the waste. Identification of the mineralogy of the Snake River Plain is needed to aid in the study of the hydrology and geochemistry of subsurface waste disposal. The US Geological Surveys project office at the Idaho National Engineering Laboratory, in cooperation with the US Department of Energy, used mineralogical data to correlate surficial sediment samples from the Big Lost River, Little Lost River, and Birch Greek drainages with selected sedimentary interbed core samples taken from test holes at the RWMC (Radioactive Waste Management Complex), TRA (Test Reactors Area), ICPP (Idaho Chemical Processing Plant), and TAN (Test Area North). Correlating the mineralogy of a particular present-day drainage area with a particular sedimentary interbed provides information on historical source of sediment for interbeds in and near the INEL. Mineralogical data indicate that surficial sediment samples from the Big Lost River drainage contained a larger amount of feldspar and pyroxene and a smaller amount of calcite and dolomite than samples from the Little Lost River and Birch Creek drainages. Mineralogical data from sedimentary interbeds at the RWMC, TRA, and ICPP correlate with surficial sediment of the present-day big Lost River drainage. Mineralogical data from a sedimentary interbed at TAN correlate with surficial sediment of the present-day Birch Creek drainage. 13 refs., 5 figs., 3 tabs.

  9. Mineralogical correlation of surficial sediment from area drainages with selected sedimentary interbeds at the Idaho National Engineering Laboratory, Idaho

    International Nuclear Information System (INIS)

    Bartholomay, R.C.

    1990-08-01

    Ongoing research by the US Geological Survey at the INEL involves investigation of the migration of radioactive elements contained in low-level radioactive waste, hydrologic and geologic factors affecting waste movement, and geochemical factors that influence the chemical composition of the waste. Identification of the mineralogy of the Snake River Plain is needed to aid in the study of the hydrology and geochemistry of subsurface waste disposal. The US Geological Surveys project office at the Idaho National Engineering Laboratory, in cooperation with the US Department of Energy, used mineralogical data to correlate surficial sediment samples from the Big Lost River, Little Lost River, and Birch Greek drainages with selected sedimentary interbed core samples taken from test holes at the RWMC (Radioactive Waste Management Complex), TRA (Test Reactors Area), ICPP (Idaho Chemical Processing Plant), and TAN (Test Area North). Correlating the mineralogy of a particular present-day drainage area with a particular sedimentary interbed provides information on historical source of sediment for interbeds in and near the INEL. Mineralogical data indicate that surficial sediment samples from the Big Lost River drainage contained a larger amount of feldspar and pyroxene and a smaller amount of calcite and dolomite than samples from the Little Lost River and Birch Creek drainages. Mineralogical data from sedimentary interbeds at the RWMC, TRA, and ICPP correlate with surficial sediment of the present-day big Lost River drainage. Mineralogical data from a sedimentary interbed at TAN correlate with surficial sediment of the present-day Birch Creek drainage. 13 refs., 5 figs., 3 tabs

  10. Transformative environmental governance

    Science.gov (United States)

    Transformative governance is an approach to environmental governance that has the capacity to respond to, manage, and trigger regime shifts in coupled social-ecological systems (SESs) at multiple scales. The goal of transformative governance is to actively shift degraded SESs to ...

  11. Genetic Transformation of Bacteria.

    Science.gov (United States)

    Moss, Robert.

    1991-01-01

    An activity in which students transform an ampicillin-sensitive strain of E. coli with a plasmid containing a gene for ampicillin resistance is described. The procedure for the preparation of competent cells and the transformation of competent E. coli is provided. (KR)

  12. Adaptive Wavelet Transforms

    Energy Technology Data Exchange (ETDEWEB)

    Szu, H.; Hsu, C. [Univ. of Southwestern Louisiana, Lafayette, LA (United States)

    1996-12-31

    Human sensors systems (HSS) may be approximately described as an adaptive or self-learning version of the Wavelet Transforms (WT) that are capable to learn from several input-output associative pairs of suitable transform mother wavelets. Such an Adaptive WT (AWT) is a redundant combination of mother wavelets to either represent or classify inputs.

  13. On an integral transform

    Directory of Open Access Journals (Sweden)

    D. Naylor

    1986-01-01

    Full Text Available This paper establishes properties of a convolution type integral transform whose kernel is a Macdonald type Bessel function of zero order. An inversion formula is developed and the transform is applied to obtain the solution of some related integral equations.

  14. A Transformation Called "Twist"

    Science.gov (United States)

    Hwang, Daniel

    2010-01-01

    The transformations found in secondary mathematics curriculum are typically limited to stretches and translations (e.g., ACARA, 2010). Advanced students may find the transformation, twist, to be of further interest. As most available resources are written for professional-level readers, this article is intended to be an introduction accessible to…

  15. Transformation of technical infrastructure

    DEFF Research Database (Denmark)

    Nielsen, Susanne Balslev

    1998-01-01

    article about the need of new planning forums in order to initiate transformations with in management of large technical systems for energy, waste and water supply.......article about the need of new planning forums in order to initiate transformations with in management of large technical systems for energy, waste and water supply....

  16. Flames of Transformation

    DEFF Research Database (Denmark)

    Sørensen, Tim Flohr; Bille, Mikkel

    2008-01-01

    This paper explores the transformative power of fire, its fundamental ability to change material worlds and affect our experience of its materiality. The paper examines material transformations related to death as a means of illustrating the powerful property of fire as a materially destructive yet...

  17. Disc piezoelectric ceramic transformers.

    Science.gov (United States)

    Erhart, Jirií; Půlpán, Petr; Doleček, Roman; Psota, Pavel; Lédl, Vít

    2013-08-01

    In this contribution, we present our study on disc-shaped and homogeneously poled piezoelectric ceramic transformers working in planar-extensional vibration modes. Transformers are designed with electrodes divided into wedge, axisymmetrical ring-dot, moonie, smile, or yin-yang segments. Transformation ratio, efficiency, and input and output impedances were measured for low-power signals. Transformer efficiency and transformation ratio were measured as a function of frequency and impedance load in the secondary circuit. Optimum impedance for the maximum efficiency has been found. Maximum efficiency and no-load transformation ratio can reach almost 100% and 52 for the fundamental resonance of ring-dot transformers and 98% and 67 for the second resonance of 2-segment wedge transformers. Maximum efficiency was reached at optimum impedance, which is in the range from 500 Ω to 10 kΩ, depending on the electrode pattern and size. Fundamental vibration mode and its overtones were further studied using frequency-modulated digital holographic interferometry and by the finite element method. Complementary information has been obtained by the infrared camera visualization of surface temperature profiles at higher driving power.

  18. A Selective CPS Transformation

    DEFF Research Database (Denmark)

    Nielsen, Lasse Riechstein

    2001-01-01

    characterize this involvement as a control effect and we present a selective CPS transformation that makes functions and expressions continuation-passing if they have a control effect, and that leaves the rest of the program in direct style. We formalize this selective CPS transformation with an operational...

  19. Integral transformational coaching

    NARCIS (Netherlands)

    Keizer, W.A.J.; Nandram, S.S.

    2009-01-01

    In Chap. 12, Keizer and Nandram present the concept of Integral Transformational Coaching based on the concept of Flow and its effects on work performance. Integral Transformational Coaching is a method that prevents and cures unhealthy stress and burnout. They draw on some tried and tested

  20. Lectures on integral transforms

    CERN Document Server

    Akhiezer, N I

    1988-01-01

    This book, which grew out of lectures given over the course of several years at Kharkov University for students in the Faculty of Mechanics and Mathematics, is devoted to classical integral transforms, principally the Fourier transform, and their applications. The author develops the general theory of the Fourier transform for the space L^1(E_n) of integrable functions of n variables. His proof of the inversion theorem is based on the general Bochner theorem on integral transforms, a theorem having other applications within the subject area of the book. The author also covers Fourier-Plancherel theory in L^2(E_n). In addition to the general theory of integral transforms, connections are established with other areas of mathematical analysis--such as the theory of harmonic and analytic functions, the theory of orthogonal polynomials, and the moment problem--as well as to mathematical physics.

  1. The transformativity approach

    DEFF Research Database (Denmark)

    Holm, Isak Winkel; Lauta, Kristian Cedervall

    2017-01-01

    During the last five to ten years, a considerable body of research has begun to explore how disasters, real and imagined, trigger social transformations. Even if the contributions to this this research stems from a multitude of academic disciplines, we argue in the article, they constitute...... an identifiable and promising approach for future disaster research. We suggest naming it the transformativity approach. Whereas the vulnerability approach explores the social causation of disasters, the transformativity approach reverses the direction of the gaze and investigates the social transformation...... brought about by disasters. Put simply, the concept of vulnerability is about the upstream causes of disaster and the concept of transformativity about the downstream effects. By discussing three recent contributions (by the historian Greg Bankoff, the legal sociologist Michelle Dauber...

  2. Transformation of Digital Ecosystems

    DEFF Research Database (Denmark)

    Henningsson, Stefan; Hedman, Jonas

    2014-01-01

    the Digital Ecosystem Technology Transformation (DETT) framework for explaining technology-based transformation of digital ecosystems by integrating theories of business and technology ecosystems. The framework depicts ecosystem transformation as distributed and emergent from micro-, meso-, and macro- level......In digital ecosystems, the fusion relation between business and technology means that the decision of technical compatibility of the offering is also the decision of how to position the firm relative to the coopetive relations that characterize business ecosystems. In this article we develop...... coopetition. The DETT framework consists an alternative to the existing explanations of digital ecosystem transformation as the rational management of one central actor balancing ecosystem tensions. We illustrate the use of the framework by a case study of transformation in the digital payment ecosystem...

  3. Ferromanganese nodules from MANOP Sites H, S, and R-Control of mineralogical and chemical composition by multiple accretionary processes

    Science.gov (United States)

    Dymond, J.; Lyle, M.; Finney, B.; Piper, D.Z.; Murphy, K.; Conard, R.; Pisias, N.

    1984-01-01

    The chemical composition of ferromanganese nodules from the three nodule-bearing MANOP sites in the Pacific can be accounted for in a qualitative way by variable contributions of distinct accretionary processes. These accretionary modes are: 1. (1) hydrogenous, i.e., direct precipitation or accumulation of colloidal metal oxides in seawater, 2. (2) oxic diagenesis which refers to a variety of ferromanganese accretion processes occurring in oxic sediments; and 3. (3) suboxic diagenesis which results from reduction of Mn+4 by oxidation of organic matter in the sediments. Geochemical evidence suggests processes (1) and (2) occur at all three MANOP nodule-bearing sites, and process (3) occurs only at the hemipelagic site, H, which underlies the relatively productive waters of the eastern tropical Pacific. A normative model quantitatively accounts for the variability observed in nearly all elements. Zn and Na, however, are not well explained by the three end-member model, and we suggest that an additional accretionary process results in greater variability in the abundances of these elements. Variable contributions from the three accretionary processes result in distinct top-bottom compositional differences at the three sites. Nodule tops from H are enriched in Ni, Cu, and Zn, instead of the more typical enrichments of these elements in nodule bottoms. In addition, elemental correlations typical of most pelagic nodules are reversed at site H. The three accretionary processes result in distinct mineralogies. Hydrogenous precipitation produces ??MnO2. Oxic diagenesis, however, produces Cu-Ni-rich todorokite, and suboxic diagenesis results in an unstable todorokite which transforms to a 7 A?? phase ("birnessite") upon dehydration. The presence of Cu and Ni as charge-balancing cations influence the stability of the todorokite structure. In the bottoms of H nodules, which accrete dominantly by suboxic diagenesis, Na+ and possibly Mn+2 provide much of the charge balance for

  4. Environmental assessment and nano-mineralogical characterization of coal, overburden and sediment from Indian coal mining acid drainage

    Directory of Open Access Journals (Sweden)

    Madhulika Dutta

    2017-11-01

    Full Text Available The deterioration of environmental conditions is the major contributory factor to poor health and quality of life that hinders sustainable development in any region. Coal mining is one of the major industries that contribute to the economy of a country but it also impacts the environment. The chemical parameters of the coal, overburden, soil and sediments along with the coal mine drainage (CMD were investigated in order to understand the overall environmental impact from high sulphur coal mining at northeastern coalfield (India. It was found that the total sulphur content of the coal is noticeably high compared to the overburden (OB and soil. The volatile matter of the coal is sufficiently high against the high ash content of the soil and overburden. The water samples have a High Electrical Conductivity (EC and high Total Dissolve Solid (TDS. Lower values of pH, indicate the dissolution of minerals present in the coal as well as other minerals in the mine rejects/overburden. The chemical and nano-mineralogical composition of coal, soil and overburden samples was studied using a High Resolution-Transmission Electron Microscopy (HR-TEM, Energy Dispersive Spectroscopy (EDS, Selected-Area Diffraction (SAED, Field Emission-Scanning Electron Microscopy (FE-SEM/EDS, X-ray diffraction (XRD, Fourier Transform Infrared Spectroscopy (FTIR, Raman and Ion-Chromatographic analysis, and Mössbauer spectroscopy. From different geochemical analysis it has been found that the mine water sample from Ledo colliery has the lowest pH value of 3.30, Tirap colliery samples have the highest electrical conductivity value of 5.40 ms cm−1. Both Ledo and Tirap coals have total sulphur contents within the range 3–3.50%. The coal mine water from Tirap colliery (TW-15B has high values of Mg2+ (450 ppm, and Br− (227.17 ppm. XRD analysis revealed the presence of minerals including quartz and hematite in the coals. Mineral analysis of coal mine overburden (OB indicates

  5. Grain surface features and clay mineralogy of the quaternary sediments from Western Deccan Trap Region, India, and their palaeoclimatic significance

    Directory of Open Access Journals (Sweden)

    Veena U. Joshi

    2011-06-01

    Full Text Available Quartz sand grains obtained from a deeply gullied topography along the banks of two tributaries of River Pravara in Maharashtra (India have been examined with a scanning electron microscope (SEM. Quartz grains have been selected after a heavy mineral separation and micro-photographs of each grain were taken at various angles and magnifications. The sediments reveal features resulting from mechanical grinding as well as from chemical alteration. Conchoidal fractures, cleavage planes, grooves, v-shaped indentations etc. are the mechanical features documented on the grains whereas solution pits of varying sizes and intensity, precipitation surfaces, oriented v-pits, solution crevasses and etching are the features of chemical origin. Several evidences indicate that the samples have undergone digenetic changes. Few grains show the features of intense chemical breakdown. The overall assemblages of the grain surface features suggest that the samples have been subjected to subaqueous transport for a considerable period of time. The minor chemical features such as solution pits or semi circular arcuate steps found in abundance on these grains are due to the dissolution of the sediments in a low energy fluviatile environment. For clay mineralogy, fractions between <2 and <0.2 mm were separated out from the sediments. The clay fractions were then subjected to examination by X-ray diffraction (XRD of oriented K/Ca saturated samples using a Philips Diffractometer and Ni-filtered Cu Ka radiation with the scanning speed of 10 2Ө min -1. The main clay minerals for all the samples are identical and show the presence of hydroxy-interlayered smectites with minor quantities of mica, kaolinite, smectites, quartz and feldspar. The first weathering product of the Deccan Basalt (DB is the dioctahedral smectite. Since the present semi aridic climatic condition of the study area can not transform a smectite to HIS and either smectite to kaolin, it is quite likely that

  6. Coprecipitation of arsenate with metal oxides. 3. Nature, mineralogy, and reactivity of iron(III)-aluminum precipitates.

    Science.gov (United States)

    Violante, Antonio; Pigna, Massimo; Del Gaudio, Stefania; Cozzolino, Vincenza; Banerjee, Dipanjan

    2009-03-01

    Coprecipitation involving arsenic with aluminum or iron has been studied because this technique is considered particularly efficient for removal of this toxic element from polluted waters. Coprecipitation of arsenic with mixed iron-aluminum solutions has received scant attention. In this work we studied (i)the mineralogy, surface properties, and chemical composition of mixed iron-aluminum oxides formed at initial Fe/Al molar ratio of 1.0 in the absence or presence of arsenate [As/ Fe+Al molar ratio (R) of 0, 0.01, or 0.1] and at pH 4.0, 7.0, and 10.0 and aged for 30 and 210 days at 50 degrees C and (ii) the removal of arsenate from the coprecipitates after addition of phosphate. The amounts of short-range ordered precipitates (ferrihydrite, aluminous ferrihydrite and/or poorly crystalline boehmite) were greater than those found in iron and aluminum systems (studied in previous works), due to the capacity of both aluminum and arsenate to retard or inhibitthe transformation of the initially formed precipitates into well-crystallized oxides (gibbsite, bayerite, and hematite). As a consequence, the surface areas of the iron-aluminum oxides formed in the absence or presence of arsenate were usually much larger than those of aluminum or iron oxides formed under the same conditions. Arsenate was found to be associated mainly into short-range ordered materials. Chemical composition of all samples was affected by pH, initial R, and aging. Phosphate sorption was facilitated by the presence of short-range ordered materials, mainly those richer in aluminum, but was inhibited by arsenate present in the samples. The quantities of arsenate replaced by phosphate, expressed as percentages of its total amount present in the samples, were particularly low, ranging from 10% to 26%. A comparison of the desorption of arsenate by phosphate from aluminum-arsenate and iron-arsenate (studied in previous works) and iron-aluminum-arsenate coprecipitates evidenced that phosphate has a greater

  7. Investigation of Different Forms of Potassium as a Function of Clay Mineralogy and Soil Evolution in Some Soils of Fars Province

    Directory of Open Access Journals (Sweden)

    N. Sadri

    2016-10-01

    Full Text Available Introduction: The optimum and sustainable use of soil is only possible with a correct and complete understanding of its properties. Potassium (K+ is an essential element for plant growth and is a dynamic ion in the soil system and its importance in agriculture is well recognized. According to increasing order of plant availability, soil K exists in four forms: mineral (5000-25000 ppm, nonexchangeable (50-750 ppm, exchangeable (40-600 ppm, and solution (1-10 ppm. K cycling or transformations among the K forms in soils are dynamic. The objectives of the present research were to study the relationship between different forms of potassium and clay mineralogy as well as soil evolution of 14 surface soil samples from some selected locations of Fars Province. Materials and methods: Fars provinces, with an area of 122000 km2 located in southern Iran. The elevation varies from 500 m to 4400 m above mean sea level. Mean annual precipitation ranges from about 350 mm to 850 mm. Mean annual temperature ranges from 10°C to 24°C. According to Soil Moisture and Temperature Regime Map of Iran, the soils comprise xeric, and ustic moisture regimes along with mesic, thermic and hyperthemic temperature regimes. Based on the previous soil survey maps of Fars province, 14 surface soil samples were collected. Routine physicochemical analyses and clay mineralogy were performed on soil samples. Soil reaction, texture, electrical conductivity, calcium carbonate, and gypsum were identified. Soluble potassium, exchangeable potassium, non exchangeable potassium, and mineral potassium were measured. The amounts of K forms in each sample were determined. Total K was determined following digestion (110°C of soil with 48 % HF and 6 M HCl. Water soluble K was measured in the saturated extract. Exchangeable K was extracted with 20 ml 1.0 M NH4OAc (pH 7.0 for 5 min. Nitric acid-extractable K was measured by extraction of a soil sample with boiling 1.0 M HNO3 for 1 h. Potassium

  8. The Improved Relevance Voxel Machine

    DEFF Research Database (Denmark)

    Ganz, Melanie; Sabuncu, Mert; Van Leemput, Koen

    The concept of sparse Bayesian learning has received much attention in the machine learning literature as a means of achieving parsimonious representations of features used in regression and classification. It is an important family of algorithms for sparse signal recovery and compressed sensing....... Hence in its current form it is reminiscent of a greedy forward feature selection algorithm. In this report, we aim to solve the problems of the original RVoxM algorithm in the spirit of [7] (FastRVM).We call the new algorithm Improved Relevance Voxel Machine (IRVoxM). Our contributions...... and enables basis selection from overcomplete dictionaries. One of the trailblazers of Bayesian learning is MacKay who already worked on the topic in his PhD thesis in 1992 [1]. Later on Tipping and Bishop developed the concept of sparse Bayesian learning [2, 3] and Tipping published the Relevance Vector...

  9. Continuous cooling transformation behaviors of CLAM steel

    International Nuclear Information System (INIS)

    Wu, Qing-sheng; Zheng, Shu-hui; Huang, Qun-ying; Liu, Shao-jun; Han, Yang-yang

    2013-01-01

    The continuous cooling transformation (CCT) behaviors of CLAM (China Low Activation Martensitic) steel were studied, the CCT diagram was constructed, and the influence of cooling rates on the microstructures was also investigated. The microstructures were investigated using optical microscopy (OM) and microhardness tests were also carried out. The results showed that CLAM steel possessed high hardenability and there were ferrite and martensite transformation regions only. The maximum cooling rate to form ferrite microstructure was found to be 10–12 K/min. In order to obtain fully ferrite microstructure, the cooling rate should be lower than 1 K/min. The CCT diagram also gave relevant parameters such as the transformation temperatures, i.e., A c1 , A c3 , M s and M f were 1124 K, 1193 K, 705 K and 593 K, respectively. The diagram made it possible to predict the microstructures and properties of CLAM steel with different cooling rates

  10. Clay Mineralogy of Basaltic Hillsides Soils in the Western State of Santa Catarina

    Directory of Open Access Journals (Sweden)

    Jaime Antonio de Almeida

    2018-02-01

    Full Text Available ABSTRACT A commonly accepted concept holds that highly fertile, shallow soils are predominant in the Basaltic Hillsides of Santa Catarina State, in southern Brazil, but their agricultural use is restricted, either by excessive stoniness, low effective depth or steep slopes. Information about soil properties and distribution along the slopes in this region is, however, scarce, especially regarding genesis and clay fraction mineralogy. The objective of this study was to evaluate soil properties of 12 profiles distributed in three toposequences (T of the Basaltic Hillsides in the State of Santa Catarina, two located in the valley of the Peixe River (Luzerna - T1 and Ipira - T2 and one in Descanso, in the far West of the state (T3. The main focus was the mineralogical composition of the clay fraction, identified by X-ray diffractometry (XRD, and its relations with the soil chemical properties. The morphological, chemical, and mineralogical properties of the soils of the toposequences differed from each other. In most soils, the position of the most intense XRD reflections indicated predominance of kaolinite (K however, for being broad and asymmetric, a participation of interstratified kaolinite-smectite (K-S was assumed. Soils of T2 and T3, located in regions with higher temperatures, lower water surplus, and lower altitude than those of T1, were more fertile, mostly redder, and contained higher proportions of smectites (S and interstratified K-S mineral, accounting for a higher activity of the clay fraction of most soils. The T1 soils were generally less fertile, with lower clay activity and, aside from kaolinite, contained smectites with interlayered hydroxy-Al polymers (HIS. The low estimated smectite contents of the most fertile soils of all toposequences disagree with the high values of cation exchange capacity (CEC and clay activity related to pure kaolinite soils. The broad and asymmetric reflections of most of the supposed kaolinites

  11. Initial Results on the Mineralogy and Geochemistry of the Mar Exploration Rover Gusev Landing Site

    Science.gov (United States)

    Christensen, P. R.

    2004-05-01

    The Spirit rover has investigated the geochemistry and mineralogy of the Gusev crater site using in situ Alpha Proton X-Ray, Mossbauer, visible, and infrared spectroscopy. The Gusev site is covered with angular to sub-rounded rocks that are typically less than 1 m in maximum dimension. More than 90 percent of these rocks are dark-toned, with the remainder being lighter-toned rocks that may predominantly be dark rocks with a thin (10's of microns) coating of easily removed fines. APXS analysis has been obtained of a rock (Adirondack) following the removal by grinding of the surface dust and the upper few mm of the rock surface. These data give a modal mineralogy corresponding to olivine basalt. High quality Mini-TES data have not been obtained of a completely dust-free rock surface. The Mini-TES data of Adirondack do show long wavelength (15-25 microns) absorptions due to olivine of composition ~Fo60. All of the rocks observed are very compositionally homogeneous in the Mini-TES spectra. These findings are consistent with the detection of olivine-bearing basalt at this site from orbital TES infrared spectroscopy. Mossbauer spectra of Adirondack show the presence of forsteritic olivine and magnetite, with possible pyroxene. The soils at Gusev are a mixture of reddish fine-grained to sandy materials, granular-sized particles that occur in ripple forms, and minor pebbles. Mini-TES spectra of the soil show an excellent match to the TES spectra of high-albedo, fine-grained material found in regional bright regions that is interpreted to be windblown dust. This agreement suggests at least the uppermost layer of the soil at Gusev has been accumulated from airfall dust. By analogy with prior analysis of TES data these materials contain several percent carbonate, minor bound water, and a framework silicate interpreted to be either feldspar or zeolite. APXS spectra show similar oxide abundances to those determined for the Pathfinder site, except for higher MgO, and lower

  12. Technical note: Mineralogical, chemical, morphological, and optical interrelationships of mineral dust re-suspensions

    Directory of Open Access Journals (Sweden)

    J. P. Engelbrecht

    2016-08-01

    Full Text Available This paper promotes an understanding of the mineralogical, chemical, and physical interrelationships of re-suspended mineral dusts collected as grab samples from global dust sources. Surface soils were collected from arid regions, including the southwestern USA, Mali, Chad, Morocco, Canary Islands, Cabo Verde, Djibouti, Afghanistan, Iraq, Kuwait, Qatar, UAE, Serbia, China, Namibia, Botswana, Australia, and Chile. The  <  38 µm sieved fraction of each sample was re-suspended in a chamber, from which the airborne mineral dust could be extracted, sampled, and analyzed. Instruments integrated into the entrainment facility included two PM10 and two PM2.5 filter samplers, a beta attenuation gauge for the continuous measurement of PM10 and PM2.5 particulate mass fractions, an aerodynamic particle size analyzer, and a three-wavelength (405, 532, 781 nm photoacoustic instrument with integrating reciprocal nephelometer for monitoring absorption and scattering coefficients during the dust re-suspension process. Filter sampling media included Teflon® membrane and quartz fiber filters for chemical analysis and Nuclepore® filters for individual particle analysis by scanning electron microscopy (SEM. The  <  38 µm sieved fractions were also analyzed by X-ray diffraction for their mineral content while the  >  75,  <  125 µm soil fractions were mineralogically assessed by optical microscopy. Presented here are results of the optical measurements, showing the interdependency of single-scattering albedos (SSA at three different wavelengths and mineralogical content of the entrained dust samples. To explain the elevated concentrations of iron (Fe and Fe ∕ Al ratios in the soil re-suspensions, we propose that dust particles are to a large extent composed of nano-sized particles of micas, clays, metal oxides, and ions of potassium (K+, calcium (Ca2+, and sodium (Na+ evenly dispersed as a colloid or adsorbed in amorphous

  13. Transformers and motors

    CERN Document Server

    Shultz, George

    1991-01-01

    Transformers and Motors is an in-depth technical reference which was originally written for the National Joint Apprenticeship Training Committee to train apprentice and journeymen electricians. This book provides detailed information for equipment installation and covers equipment maintenance and repair. The book also includes troubleshooting and replacement guidelines, and it contains a minimum of theory and math.In this easy-to-understand, practical sourcebook, you'll discover:* Explanations of the fundamental concepts of transformers and motors* Transformer connections and d

  14. Transforming Consumers Into Brands

    DEFF Research Database (Denmark)

    Erz, Antonia; Christensen, Anna-Bertha Heeris

    2018-01-01

    The goal of this research is to explore the transformational power of a new consumption and production practice, the practice of blogging, to understand its impact on consumers' identity transformations beyond their self-concept as consumers and on the blogosphere as an organizational field....... Through an exploratory study of over 12,000 blog posts from five fashion bloggers, complemented by in-depth interviews, we trace the transformation of consumer bloggers. We identify and describe three identity phases, the individual consumer, collective blogger and blogger identity phase, and two...

  15. On numerical Bessel transformation

    International Nuclear Information System (INIS)

    Sommer, B.; Zabolitzky, J.G.

    1979-01-01

    The authors present a computer program to calculate the three dimensional Fourier or Bessel transforms and definite integrals with Bessel functions. Numerical integration of systems containing Bessel functions occurs in many physical problems, e.g. electromagnetic form factor of nuclei, all transitions involving multipole expansions at high momenta. Filon's integration rule is extended to spherical Bessel functions. The numerical error is of the order of the Simpson error term of the function which has to be transformed. Thus one gets a stable integral even at large arguments of the transformed function. (Auth.)

  16. Energy Transformation of Croatia

    International Nuclear Information System (INIS)

    Potocnik, V.

    2014-01-01

    Due to obvious climate change, caused mainly by combustion of the fossil fuels, as well as to their modest reserves, energy transformation is under way. It is the transition from the fossil fuels to improved energy efficiency (ENEF) and renewable energy sources (RES). Leading role in the energy transformation has Germany with 'Energiewende', which among other includes closing of existing nuclear power plants until 2022. Croatia has very limited proven fossil fuels reserves, which cover 3/4 of primary energy in consumption. Croatia also has large potential for improvements in ENEF and RES. Therefore, energy transformation of Croatia is justified. (author).

  17. Biolistics Transformation of Wheat

    Science.gov (United States)

    Sparks, Caroline A.; Jones, Huw D.

    We present a complete, step-by-step guide to the production of transformed wheat plants using a particle bombardment device to deliver plasmid DNA into immature embryos and the regeneration of transgenic plants via somatic embryogenesis. Currently, this is the most commonly used method for transforming wheat and it offers some advantages. However, it will be interesting to see whether this position is challenged as facile methods are developed for delivering DNA by Agrobacterium tumefaciens or by the production of transformants via a germ-line process (see other chapters in this book).

  18. Laplace transforms essentials

    CERN Document Server

    Shafii-Mousavi, Morteza

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Laplace Transforms includes the Laplace transform, the inverse Laplace transform, special functions and properties, applications to ordinary linear differential equations, Fourier tr

  19. Fourier transform NMR

    International Nuclear Information System (INIS)

    Hallenga, K.

    1991-01-01

    This paper discusses the concept of Fourier transformation one of the many precious legacies of the French mathematician Jean Baptiste Joseph Fourier, essential for understanding the link between continuous-wave (CW) and Fourier transform (FT) NMR. Although in modern FT NMR the methods used to obtain a frequency spectrum from the time-domain signal may vary greatly, from the efficient Cooley-Tukey algorithm to very elaborate iterative least-square methods based other maximum entropy method or on linear prediction, the principles for Fourier transformation are unchanged and give invaluable insight into the interconnection of many pairs of physical entities called Fourier pairs

  20. Ligand Exchange Kinetics of Environmentally Relevant Metals

    Energy Technology Data Exchange (ETDEWEB)

    Panasci, Adele Frances [Univ. of California, Davis, CA (United States)

    2014-07-15

    The interactions of ground water with minerals and contaminants are of broad interest for geochemists but are not well understood. Experiments on the molecular scale can determine reaction parameters (i.e. rates of ligand exchange, activation entropy, activation entropy, and activation volume) that can be used in computations to gain insight into reactions that occur in natural groundwaters. Experiments to determine the rate of isotopic ligand exchange for three environmentally relevant metals, rhodium (Rh), iron (Fe), and neptunium (Np), are described. Many environmental transformations of metals (e.g. reduction) in soil occur at trivalent centers, Fe(III) in particular. Contaminant ions absorb to mineral surfaces via ligand exchange, and the reversal of this reaction can be dangerous, releasing contaminants into the environment. Ferric iron is difficult to study spectroscopically because most of its complexes are paramagnetic and are generally reactive toward ligand exchange; therefore, Rh(III), which is diamagnetic and less reactive, was used to study substitution reactions that are analogous to those that occur on mineral oxide surfaces. Studies on both Np(V) and Np(VI) are important in their own right, as 237Np is a radioactive transuranic element with a half-life of 2 million years.

  1. Mineralogy in the Waste Isolation Pilot Plant (WIPP) facility stratigraphic horizon

    International Nuclear Information System (INIS)

    Stein, C.L.

    1985-09-01

    Forty-six samples were selected for this study from two cores, one extending 50 ft up through the roof of the WIPP facility and the other penetrating 50 ft below the facility floor. These samples, selected from approximately every other foot of core length, represent the major lithologies present in the immediate vicinity of the WIPP facility horizon: ''clean'' halite, polyhalitic halite, argillaceous halite, and mixed polyhalitic-argillaceous halite. Samples were analyzed for non-NaCl mineralogy by determining weight percents of water- and EDTA-insoluble residues, which were then identified by x-ray diffraction. In general, WIPP halite contains at most 5 wt % non-NaCl residue. The major mineral constituents are quartz, magnesite, anhydrite, gypsum, polyhalite, and clays. Results of this study confirm that, in previous descriptions of WIPP core, trace mineral quantities have been visually overestimated by approximately an order of magnitude. 9 refs., 5 figs., 5 tabs

  2. Mineralogy and paragenetic study of uranium mineralisation in Rabau Hulu sector west Kalimantan

    International Nuclear Information System (INIS)

    Soeprapto, Tj.; Retno, W.; Mudjo, S.; Manto, W.

    1987-01-01

    Mineralogy and paragenetic study of uranium mineralization in Rabau Hulu sector west Kalimantan. Uranium mineralisation in Rabau Hulu was found in favourable bed of metasiltstone. Genetically the mineralization seems to be hydrothermal type, and occured at temperatures 200 0 C -500 0 C and deposited in tectonic traps. Uranium mineral found in this sector is uraninite and the associates are pyrrhotite, molybdenite pyrite, sphalterite, chalcopyrite, lollingite, bornite, tourmaline and quartz. The paragenetic can be devided into 3 paragenetic stages: 1st stage characterized by ilmenite magnetite, pyrrhotite, pyrite, rutil, and tourmaline; 2nd stage characterized by veins of uraninite, pyrrhotite, molybdenite, pyrite, spalerite, chalcopyrite, lollingite, bornite, tourmaline, and quartz; and 3rd stage contains pyrite, calcite and gypsum. (author). 7 refs.; 8 figs

  3. The lateritic profile of Balkouin, Burkina Faso: Geochemistry, mineralogy and genesis

    Science.gov (United States)

    Giorgis, Ilaria; Bonetto, Sabrina; Giustetto, Roberto; Lawane, Abdou; Pantet, Anne; Rossetti, Piergiorgio; Thomassin, Jean-Hugues; Vinai, Raffaele

    2014-02-01

    This study reports on the geochemical and mineralogical characterization of a lateritic profile cropping out in the Balkouin area, Central Burkina Faso, aimed at obtaining a better understanding of the processes responsible for the formation of the laterite itself and the constraints to its development. The lateritic profile rests on a Paleoproterozoic basement mostly composed of granodioritic rocks related to the Eburnean magmatic cycle passing upwards to saprolite and consists of four main composite horizons (bottom to top): kaolinite and clay-rich horizons, mottled laterite and iron-rich duricrust. In order to achieve such a goal, a multi-disciplinary analytical approach was adopted, which includes inductively coupled plasma (ICP) atomic emission and mass spectrometries (ICP-AES and ICP-MS respectively), X-ray powder diffraction (XRPD), scanning electron microscopy with energy dispersive spectrometry (SEM-EDS) and micro-Raman spectroscopy.

  4. Mineralogy and petrography of HAL, an isotopically-unusual Allende inclusion

    Science.gov (United States)

    Allen, J. M.; Grossman, L.; Lee, T.; Wasserburg, G. J.

    1980-01-01

    Results of a detailed mineralogical and textural study of the HAL (Hibonite ALlende) inclusion of the Allende meteorite, which has been found to exhibit no Mg-26 excesses despite very high Al-27/Mg-24 ratios and large fractionation effects with small nuclear effects in its Ca, are reported. The inclusion is found to consist of three up to 1-mm diameter hibonite crystals partially surrounded by a black rim resembling a devitrified glass and containing an anisotropic Al-Fe oxide, which is in turn surrounded by a 2-mm thick friable rim sequence consisting of five layers distinguishable by mineral composition. From the available evidence, it is concluded that each of the layers of the friable rim formed by the accretion of an assemblage of condensate grains rather than by the complete reaction of a HAL precursor with a nebular gas, thus explaining its unusual isotopic characteristics and supporting the conclusion that the solar nebular contained isotopically-distinct reservoirs.

  5. Chemical and mineralogical characterization of two commercial cements and its evolution in function of time

    International Nuclear Information System (INIS)

    Gutierrez B, O.

    2014-01-01

    Mineralogical evolution of Portland cement is studied during hydration process using materials characterization techniques as X-ray diffraction (XRD) and scanning electron microscopy (Sem) in order to analyze the changes in the various cement minerals as alite, belite, celite, during processing to the hydrated phases of tobermorite gel, portlandite and ettringite, respectively, in the cement paste setting at different ages (3, 7 and 28 days). It was found that the hydration process occurs differently in each mineral because of their reaction rates or changes they experience in their crystals during processing of anhydrous to hydrated phase. You may notice changes in the appearance of the dough as you go hydration and the formation of tobermorite gel, portlandite and ettringite. (Author)

  6. Mineralogy, petrology and whole-rock chemistry data compilation for selected samples of Yucca Mountain tuffs

    International Nuclear Information System (INIS)

    Connolly, J.R.

    1991-12-01

    Petrologic, bulk chemical, and mineralogic data are presented for 49 samples of tuffaceous rocks from core holes USW G-1 and UE-25a number-sign 1 at Yucca Mountain, Nevada. Included, in descending stratigraphic order, are 11 samples from the Topopah Spring Member of the Paintbrush Tuff, 12 samples from the Tuffaceous Beds of Calico Hills, 3 samples from the Prow Pass Member of the Crater Flat Tuff, 20 samples from the Bullfrog Member of the Crater Flat Tuff and 3 samples from the Tram Member of the Crater Flat Tuff. The suite of samples contains a wide variety of petrologic types, including zeolitized, glassy, and devitrified tuffs. Data vary considerably between groups of samples, and include thin section descriptions (some with modal analyses for which uncertainties are estimated), electron microprobe analyses of mineral phases and matrix, mineral identifications by X-ray diffraction, and major element analyses with uncertainty estimates

  7. Thermogravimetric analyses and mineralogical study of polymer modified mortar with silica fume

    Directory of Open Access Journals (Sweden)

    Alessandra Etuko Feuzicana de Souza Almeida

    2006-09-01

    Full Text Available Mineral and organic additions are often used in mortars to improve their properties. Microstructural investigation concerning the effects of styrene acrylic polymer and silica fume on the mineralogical composition of high-early-strength portland cement pastes after 28 days of hydration are presented in this paper. Thermogravimetry and derivative thermogravimetry were used to study the interaction between polymers and cement, as well as the extent of pozzolanic reaction of the mortars with silica fume. Differential scanning calorimetry and X ray diffraction were used to investigate the cement hydration and the effect of the additions. The results showed that the addition of silica fume and polymer reduces the portlandite formation due to delaying of Portland cement hydration and pozzolanic reaction.

  8. Quantitative mineralogical analysis of sandstones using x-ray diffraction techniques

    International Nuclear Information System (INIS)

    Ward, C.R.; Taylor, J.C.

    1999-01-01

    Full text: X-ray diffraction has long been used as a definitive technique for mineral identification based on the measuring the internal atomic or crystal structures present in powdered rocks; soils and other mineral mixtures. Recent developments in data gathering and processing, however, have provided an improved basis for its use as a quantitative tool, determining not only the nature of the minerals but also the relative proportions of the different minerals present. The mineralogy of a series of sandstone samples from the Sydney and Bowen Basins of eastern Australia has been evaluated by X-ray diffraction (XRD) on a quantitative basis using the Australian-developed SIROQUANT data processing technique. Based on Rietveld principles, this technique generates a synthetic X-ray diffractogram by adjusting and combining full-profile patterns of minerals nominated as being present in the sample and interactively matches the synthetic diffractogram under operator instructions to the observed diffractogram of the sample being analysed. The individual mineral patterns may be refined in the process, to allow for variations in crystal structure of individual components or for factors such as preferred orientation in the sample mount. The resulting output provides mass percentages of the different minerals in the mixture, and an estimate of the error associated with each individual percentage determination. The chemical composition of the mineral mixtures indicated by SIROQUANT for each individual sandstone studied was estimated using a spreadsheet routine, and the indicated proportion of each oxide in each sample compared to the actual chemical analysis of the same sandstone as determined independently by X-ray fluorescence spectrometry. The results show a high level of agreement for all major chemical constituents, indicating consistency between the SIROQUANT XRD data and the whole-rock chemical composition. Supplementary testing with a synthetic corundum spike further

  9. Petrographic and mineralogical features of the uraniferous pink granites in the north eastern desert of egypt

    International Nuclear Information System (INIS)

    Atawiya, M.Y.; Salman, A.B.; El-Bayyomi, R.M.

    1998-01-01

    The present work is concerned with the petrological, mineralogical and geochemical studies of some uranium bearing younger granites in the north eastern desert of egypt particularly Gebel Gattar area. The area around Gebel Gattar comprises the following rock units (starting from the oldest): meta volcanic, diorite-grano-diorite complex- Dokhan volcanics- Hammamat sediments, younger granites and dykes. The most significant structural features are represented by NNE-ENE dominantly trending faults and joints. Petrographicaly, the pink granites are divided into normal and mineralized (uraniferous) granites. Normal granites are classified into three types; a) leucocratic perthitic granite, b) hornblende- biotite perthitic granite and c) two feldspars perthitic granite. Mineralized granites are sheared, deformed, pinkish brown in colour and strongly altered. A remarkable secondary uranium mineralization has been recorded along fault and fracture zones

  10. Matrix mineralogy of the Lance CO3 carbonaceous chondrite - A transmission electron microscope study

    Science.gov (United States)

    Keller, Lindsay P.; Buseck, Peter R.

    1990-01-01

    Results are presented on electron microprobe analyses of three CO chondrites, all of which are falls: Lance, Kainsaz, and Warrenton. The TEM mineralogy results of Lance chondrite show that Fe-rich matrix olivines have been altered to Fe-bearing serpentine and Fe(3+) oxide; matrix metal was also altered to produce Fe(3+) oxides, leaving the residual metal enriched in Ni. Olivine grains in Lance's matrix contain channels along their 100-line and 001-line directions; the formation and convergence of such channels resulted in a grain-size reduction of the olivine. A study of Kainsaz and Warrenton showed that these meteorites do not contain phyllosilicates in their matrices, although both contain Fe(3+) oxide between olivine grains. It is suggested that, prior to its alteration, Lance probably resembled Kainsaz, an unaltered CO3 chondrite.

  11. Mineralogical, Microstructural and Thermal Characterization of Coal Fly Ash Produced from Kazakhstani Power Plants

    Science.gov (United States)

    Tauanov, Z.; Abylgazina, L.; Spitas, C.; Itskos, G.; Inglezakis, V.

    2017-09-01

    Coal fly ash (CFA) is a waste by-product of coal combustion. Kazakhstan has vast coal deposits and is major consumer of coal and hence produces huge amounts of CFA annually. The government aims to recycle and effectively utilize this waste by-product. Thus, a detailed study of the physical and chemical properties of material is required as the data available in literature is either outdated or not applicable for recently produced CFA samples. The full mineralogical, microstructural and thermal characterization of three types of coal fly ash (CFA) produced in two large Kazakhstani power plants is reported in this work. The properties of CFAs were compared between samples as well as with published values.

  12. Mineralogical and petrographic investigations at Strasbourg on the Oklo natural reactors

    International Nuclear Information System (INIS)

    Gauthier-Lafaye, F.; Weber, F.

    1978-01-01

    Petrographic and mineralogical investigations have revealed the presence around the reaction zones of aureoles characterized by the nature of the phyllitic minerals which they enclose. Running from the outside towards the core, these are: illite 1Md and ferriferous chlorite (normal sediment), illite 2M 1 , magnesium chlorite and kaolinite, illite 1M and vermiculite chlorite. Detritic quartz dissolution figures are observed which disappear in the illite 2M aureole or in the magnesium chlorite aureole, depending on the degree of sandiness of the country rock. This zonal stucture could be attributable to the combined effect of neutron bombardment and hydrothermal alteration due to the action of a thermal syphon triggered off by the nuclear reactions. (author)

  13. Mineralogy, petrology and geochemistry of carbonaceous chondritic clasts in the LEW 85300 polymict eucrite

    Science.gov (United States)

    Zolensky, M. E.; Hewins, R. H.; Mittlefehldt, D. W.; Lindstrom, M. M.; Xiao, X.; Lipschutz, M. E.

    1992-01-01

    We have performed a detailed petrologic and mineralogic study of two chondritic clasts from the polymict eucrite Lewis Cliff (LEW) 85300, and performed chemical analyses by INAA and RNAA on one of these. Petrologically, the clasts are identified and are composed of dispersed aggregates, chondrules, and chondrule fragments supported by matrix. The aggregates and chondrules are composed of olivine, orthopyroxene, plus some diopside. The matrix consists of fine-grained olivine, and lesser orthopyroxene and augite. Fine-grained saponite is common in the matrix. The bulk major composition of the clast studied by INAA and RNAA shows unusual abundance patterns for lithophile, siderophile and chalcophile elements but is basically chondritic. The INAA/RNAA data preclude assignment of the LEW 85300,15 clast to any commonly accepted group of carbonaceous chondrite.

  14. Coordinating Chemical and Mineralogical Analyses of Antarctic Dry Valley Sediments as Potential Analogs for Mars

    Science.gov (United States)

    Patel, S. N.; Bishop, J. L.; Englert, P.; Gibson, E. K.

    2015-01-01

    The Antarctic Dry Valleys (ADV) provide a unique terrestrial analog for Martian surface processes as they are extremely cold and dry sedimentary environments. The surface geology and the chemical composition of the Dry Valleys that are similar to Mars suggest the possible presence of these soil-formation processes on Mars. The soils and sediments from Wright Valley, Antarctica were investigated in this study to examine mineralogical and chemical changes along the surface layer in this region and as a function of depth. Surface samples collected near Prospect Mesa and Don Juan Pond of the ADV were analyzed using visible/near-infrared (VNIR) and mid-IR reflectance spectroscopy and major and trace element abundances.

  15. The mineralogy and geochemistry of some of the iron-formations of Bushmanland

    International Nuclear Information System (INIS)

    Meyer, T.Q.

    1986-01-01

    A great diversity of metasedimentary and metavolcanic rock types form inselbergs on the sandcovered plains of Bushmanland in the north-western Cape Province. Algoma-type iron-formation occurs as isolated units in the Proterozoic metasediments of Namaqualand and Bushmanland, varying in size and stratigraphical position. In many cases, the iron-formations are closely associated with base metal mineralization. Examples are the huge base metal deposits at Black Mountain, Gamsberg and Broken Hill in the Aggeneys area. The oxidation zones are expressed as black magnetite-rich outcrops which can in some cases be traced for as much as a kilometre. This study was undertaken to investigate the mineralogy and geochemistry of a selection of the iron-formations of Bushmanland. Some of the iron-formations, associated ferriferous metasediments and gossans contain a wide variety of secondary minerals. These minerals were examined by X-ray diffraction and analyses were obtained by means of an electron microprobe

  16. The Mineralosphere Concept: Mineralogical Control of the Distribution and Function of Mineral-associated Bacterial Communities.

    Science.gov (United States)

    Uroz, Stephane; Kelly, Laura Catherine; Turpault, Marie-Pierre; Lepleux, Cendrella; Frey-Klett, Pascale

    2015-12-01

    Soil is composed of a mosaic of different rocks and minerals, usually considered as an inert substrata for microbial colonization. However, recent findings suggest that minerals, in soils and elsewhere, favour the development of specific microbial communities according to their mineralogy, nutritive content, and weatherability. Based upon recent studies, we highlight how bacterial communities are distributed on the surface of, and in close proximity to, minerals. We also consider the potential role of the mineral-associated bacterial communities in mineral weathering and nutrient cycling in soils, with a specific focus on nutrient-poor and acidic forest ecosystems. We propose to define this microbial habitat as the mineralosphere, where key drivers of the microbial communities are the physicochemical properties of the minerals. Copyright © 2015 Elsevier Ltd. All rights reserved.

  17. Mineralogical Response of the Post harvest Mango (Mangifera Indica L.) to Different Levels of Bavistin DF

    International Nuclear Information System (INIS)

    Islam, M.K.; Absar, N.; Sarkar, M.A.R; Khan, M.Z.H.; Yeasmin, S.; Hakim, K.A.

    2013-01-01

    This study was carried out with the post harvest mangoes (viz., the Langra and the Khirshapat) treating with different levels of Bavistin DF solution (namely, 250, 500, and 750 PPM) for obtaining results on the mineral content changes as well as storability of post harvest mango. The results of the experiments exhibited that only the single effect of varieties was found to be significant in most of the parameters studied. The Langra enriched a greater quantity of magnesium, iron and manganese constituents over the Khirshapat. On the other hand, Khirshapat enriched higher quantities of calcium, copper and zinc content at all the storage duration. Different post harvest treatments subjected to the investigation demonstrated significant variation in most of the mineralogical properties of mango at different days of storage. The result explored that calcium, magnesium, iron, and manganese contents were rapidly increased. On the other hand copper and zinc content drastically decreased from untreated mangoes. (author)

  18. Microstructural and mineralogical characterization of selected shales in support of nuclear waste repository studies

    International Nuclear Information System (INIS)

    Lee, S.Y.; Hyder, L.K.; Alley, P.D.

    1988-01-01

    Five shales were examined as part of the Sedimentary Rock Program evaluation of this medium as a potential host for a US civilian nuclear waste repository. The units selected for characterization were the Chattanooga Shale from Fentress County, Tennessee; the Pierre Shale from Gregory County, South Dakota; the Green River Formation from Garfield County, Colorado; and the Nolichucky Shale and Pumpkin Valley Shale from Roane County, Tennessee. The micromorphology and structure of the shales were examined by petrographic, scanning electron, and high-resolution transmission electron microscopy. Chemical and mineralogical compositions were studied through the use of energy-dispersive x-ray, neutron activation, atomic absorption, thermal, and x-ray diffraction analysis techniques. 18 refs., 12 figs., 2 tabs

  19. Mineralogy and crystal chemistry of iron in the Timan bauxite and products of their technological processing

    Science.gov (United States)

    Kotova, O.; Silaev, V.; Lutoev, V.; Vakhrushev, A.

    2016-04-01

    Mineralogical and geochemical features of two series of samples of typical bauxites from two deposits of Middle Timan mining area (Vezhayu-Vorykva and Svetlinskoe) were studied. The phase composition of ferrous bauxites generally is boehmite, hematite, ultradisperse low-ordered goethite and berthierine. In a boehmite and kaolinite structural impurity of iron to 10%, and in the iron oxidehydroxides aluminum impurity is revealed. On iron content bauxites are subdivided into three mineral types for which quantitative data on valence states of ions of iron and proportions of their distribution last on nonequivalent structural positions in hematite, goethite and berthierine are obtained. Noble metals (Ag, Au, Ir, Rh, Pd) concentrating in bauxites are revealed for the first time. Obtained data can lead to decrease of power consumption during aluminum production and high quality ceramics, to provide production of valuable iron oxide, and also to minimize the ecological harm from accumulation of bauxite wastes.

  20. Mineralogy of auriferous deposits of the quaternary deposits in the San Luis Province, Argentina

    International Nuclear Information System (INIS)

    Karlsson, A.; Ayala, R. . E mail: Karlsson@arnet.com.ar

    2004-01-01

    The objective of this work is to study the mineralogy of the sands and clays of the quaternary deposits in the San Luis Mountain, Argentina. A series of algorithms applied to the sand fraction has permitted to determine sedimentary discontinuities. The two micron fraction of the sediments has been studied by a quantification technique based on X-ray diffraction by means of oriented preparations and run with copper tube. These quaternary silts have received fluvial lateral contributions. The high cristalinidad of non expandibles and fireclay clay show the antique of the silts. The polygenic processes have generated a great variety of clay mineral species like a large quantities of illite and in lesser extend kaolinite and smectites. The illite was probably generated by diagenetic changes. The high cristalinidad of non expandibles and fireclay clay show the antique of the silts [es

  1. Geochemical and mineralogical studies of dinosaur bone from the Morrison Formation at Dinosaur Ridge

    Science.gov (United States)

    Modreski, P.J.

    2001-01-01

    The dinosaur bones first discovered in 1877 in the Upper Jurassic Morrison Formation at Morrison, Colorado were the first major find of dinosaur skeletons in the western U.S. and led to the recognition of four new dinosaur genera (Apatosaurus, Allosaurus, Diplodocus, and Stegosaurus). Eight articles dealing with these bones which appeared as research reports in the annual reports of the Friends of Dinosaur Ridge from 1990-1999 are condensed and summarized with some additional comments. Two of the articles are about the mineralogy and preservation of the bones; two are about the physical description of the bone occurrence; two are about the history of the site, and two are about use of novel instrumental methods (ground-penetrating radar and a directional scintillometer) to search for new bones.

  2. MSL Chemistry and Mineralogy X-Ray Diffraction X-Ray Fluorescence (CheMin) Instrument

    Science.gov (United States)

    Zimmerman, Wayne; Blake, Dave; Harris, William; Morookian, John Michael; Randall, Dave; Reder, Leonard J.; Sarrazin, Phillipe

    2013-01-01

    This paper provides an overview of the Mars Science Laboratory (MSL) Chemistry and Mineralogy Xray Diffraction (XRD), X-ray Fluorescence (XRF) (CheMin) Instrument, an element of the landed Curiosity rover payload, which landed on Mars in August of 2012. The scientific goal of the MSL mission is to explore and quantitatively assess regions in Gale Crater as a potential habitat for life - past or present. The CheMin instrument will receive Martian rock and soil samples from the MSL Sample Acquisition/Sample Processing and Handling (SA/SPaH) system, and process it utilizing X-Ray spectroscopy methods to determine mineral composition. The Chemin instrument will analyze Martian soil and rocks to enable scientists to investigate geophysical processes occurring on Mars. The CheMin science objectives and proposed surface operations are described along with the CheMin hardware with an emphasis on the system engineering challenges associated with developing such a complex instrument.

  3. Infrared detection of the mineralogical aspects that influence the processing of calcined kaolin

    Science.gov (United States)

    Groenheide, Stefan; Guatame-Garcia, Adriana; Buxton, Mike; van der Werff, Harald

    2017-04-01

    Calcined kaolin is an industrial minerals product used in the production of paper, paint, rubber and other specialty applications. It is produced from kaolinite through a series of refinement steps and final calcination at temperatures of above 900°C, with the aim of generating a whiter and more abrasive material. The raw kaolin ore is a mixture of clay minerals, quartz and feldspars, where kaolinite is the main constituent. The optimal kaolin ores to feed the processing plant should ideally have high kaolinite abundance, be free in Fe-bearing mineralogy (to avoid influence in the colour of the product), and the kaolinite itself should be of high crystallinity (to ensure the correct abrasiveness after calcination). This work presents a case study from the kaolin deposits in the St. Austell Granite (South-West England), which are known for their high quality and world-class size. In this area, the kaolin is of primary-hydrothermal origin, with mineral associations that are related to the genetic history. The eventual depletion of the high-quality reserves is bringing now the attention to the lower grade zones, where the amount of impurities increases. As a consequence, it is critical to developing strategies that ensure the supply of high-quality ore to the processing plant. For this, it is necessary to acquire a thorough knowledge of the ore, including relative abundance of the minerals and their textural relationships. Hyperspectral images in the visible-near infrared (VNIR) and short-wave infrared (SWIR) ranges were collected from drill cores and run-off-mine (ROM) samples, obtained from one of the kaolin pits in the St. Austell area, where the kaolin quality is known to be lower than in the rest of the deposit. A series of mineral maps were generated to assess the distribution, texture and abundance of the Fe-bearing mineralogy and the other kaolin-associated minerals, as well as the variations in the crystallinity of kaolinite. The mineral maps enabled the

  4. Transformations in destination texture

    DEFF Research Database (Denmark)

    Gyimóthy, Szilvia

    2018-01-01

    This article takes heterogeographical approaches to understand Bollywood-induced destination transformations in Switzerland. Positioned within the theoretical field of mediatized mobility, the study contextualizes Bollywood-induced tourism in Europe the concept of texture. Textural analysis (base...

  5. Matrices and transformations

    CERN Document Server

    Pettofrezzo, Anthony J

    1978-01-01

    Elementary, concrete approach: fundamentals of matrix algebra, linear transformation of the plane, application of properties of eigenvalues and eigenvectors to study of conics. Includes proofs of most theorems. Answers to odd-numbered exercises.

  6. Fourier Transform Mass Spectrometry

    Science.gov (United States)

    Scigelova, Michaela; Hornshaw, Martin; Giannakopulos, Anastassios; Makarov, Alexander

    2011-01-01

    This article provides an introduction to Fourier transform-based mass spectrometry. The key performance characteristics of Fourier transform-based mass spectrometry, mass accuracy and resolution, are presented in the view of how they impact the interpretation of measurements in proteomic applications. The theory and principles of operation of two types of mass analyzer, Fourier transform ion cyclotron resonance and Orbitrap, are described. Major benefits as well as limitations of Fourier transform-based mass spectrometry technology are discussed in the context of practical sample analysis, and illustrated with examples included as figures in this text and in the accompanying slide set. Comparisons highlighting the performance differences between the two mass analyzers are made where deemed useful in assisting the user with choosing the most appropriate technology for an application. Recent developments of these high-performing mass spectrometers are mentioned to provide a future outlook. PMID:21742802

  7. Transformation on Abandonment

    DEFF Research Database (Denmark)

    Krag, Mo Michelsen Stochholm

    2016-01-01

    This paper outlines a research project on the increasing quantity of abandoned houses in the depopulating rural villages, and it reports on how an attempt is made to establish a counter-practice of radical preservation based on a series of full-scale transformations of abandoned buildings. The aim...... of the transformations is to reveal and preserve material and immaterial values such as aspects of cultural heritage, local narratives, and building density. The responses of local people are used as a feedback mechanism and considered an important impact indicator. Eleven transformations of varying strategies have...... houses. Transformation prototypes are tested as present manifestations in rural villages as an alternative way to preserve buildings as well as memories....

  8. A DC Transformer

    Data.gov (United States)

    National Aeronautics and Space Administration — The goal of the project was to demonstrate a true direct current (DC) transformer, a new electro-mechanical component with potentially high power applications; in...

  9. Commutation and Darboux transformation

    Indian Academy of Sciences (India)

    1College of Military Engineering, Pune 411 031, India. 2Department of ... Liouville equation is a particular application of the commutation method. Darboux ... transformation of a differential operator L, then there exists a differential operator A of.

  10. Retrofilling of Railroad Transformers

    Science.gov (United States)

    1978-09-01

    The objective of this program was to assess the effectiveness of retrofilling an askarel transformer supplied by the United States Department of Transportation with a 50 centistokes silicone fluid. The work tasks included an assessment of the electri...

  11. Petrographic-mineralogical characterization with liberation grade, X ray and chemical diffractometry in ore samples of Itataia-CE mine

    International Nuclear Information System (INIS)

    Salas, H.T.

    1985-01-01

    From samples collected by geologists in several points of G2 and G3 gallery of Itataia Uranium Phosphate mine, intended to get knowledge about several lithologic types of ores, mainly its alteration grades. Petrographic-mineralogical studies, liberation grade calculation of apatite, X-ray diffractometry analysis and dosage of oxydes by X-ray fluorencence are executed. (C.M.) [pt

  12. The influence of mineralogical, chemical and physical properties on grindability of commercial clinkers with high MgO level

    International Nuclear Information System (INIS)

    Souza, Vladia Cristina G. de; Koppe, Jair Carlos; Costa, Joao F.C.L.; Vargas, Andre Luis Marin; Blando, Eduardo; Huebler, Roberto

    2008-01-01

    This research investigates various methods able to identify possible mineralogical, physical and chemical influences on the grindability of commercial clinkers with high MgO level. The aim of the study is to evaluate the hardness and elastic modulus of the clinker mineral phases and their fracture strength during the comminution processes, comparing samples from clinkers with low MgO level (0.5%) and clinkers with elevated MgO levels (> 5.0%). The study of the influence of mineralogical, chemical and physical properties was carried out using several analytical techniques, such as: optical microscopy, X-ray diffraction with Rietveld refinement (XRD) and X-ray fluorescence (XRF). These techniques were useful in qualifying the different clinker samples. The drop weight test (DWT) and the Bond ball mill grindability test were performed to characterize the mechanical properties of clinkers. Nanoindentation tests were also carried out. Results from the Bond ball mill grindability test were found to be related to the hardness of the mineral phase and to mineralogical characteristics, such as type and amount of inclusions in silicates, belite and alite crystals shape, or microcracked alites. In contrast, the results obtained by the DWT were associated to the macro characteristics of clinkers, such as porosity, as well as to the hardness and mineralogical characteristics of belite crystals in clusters. Hardness instrumented tests helped to determine the Vickers hardness and elastic modulus from the mineral phases in commercial clinkers and produced different values for the pure phases compared to previous publications

  13. THE MINERALOGY OF PB SCALES IN DRINKING WATER DISTRIBUTION SYSTEMS AS REVEALED BY COMBINED XRD AND MICRO-RAMAN SPECTROSCOPY

    Science.gov (United States)

    Dissolving Pb from lead service lines and Pb-containing brasses and solders has become a major health issue for many water distribution systems. Knowledge of the mineralogy of scales in these pipes is key to modeling this dissolution. The traditional method of determining their ...

  14. Rare Earth Elements (La, Ce, Pr, Nd, and Sm from a Carbonatite Deposit: Mineralogical Characterization and Geochemical Behavior

    Directory of Open Access Journals (Sweden)

    Mohamed Edahbi

    2018-02-01

    Full Text Available Geochemical characterization including mineralogical measurements and kinetic testing was completed on samples from the Montviel carbonatite deposit, located in Quebec (Canada. Three main lithological units representing both waste and ore grades were sampled from drill core. A rare earth element (REE concentrate was produced through a combination of gravity and magnetic separation. All samples were characterized using different mineralogical techniques (i.e., quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN, X-ray diffraction (XRD, and scanning electron microscopy with X-ray microanalysis (SEM-EDS in order to quantify modal mineralogy, liberation, REE deportment and composition of REE-bearing phases. The REE concentrate was then submitted for kinetic testing (weathering cell in order to investigate the REE leaching potential. The mineralogical results indicate that: (i the main REE-bearing minerals in all samples are burbankite, kukharenkoite-Ce, monazite, and apatite; (ii the samples are dominated by REE-free carbonates (i.e., calcite, ankerite, and siderite; and (iii LREE is more abundant than HREE. Grades of REE minerals, sulfides and oxides are richer in the concentrate than in the host lithologies. The geochemical test results show that low concentrations of light REE are leached under kinetic testing conditions (8.8–139.6 µg/L total light REE. These results are explained by a low reactivity of the REE-bearing carbonates in the kinetic testing conditions, low amounts of REE in solids, and by precipitation of secondary REE minerals.

  15. On the role of clay and its mineralogic components in low- and intermediary-level radioactive waste disposal

    International Nuclear Information System (INIS)

    Craciun, C.; Balan, V.

    2001-01-01

    In site selection for radioactive waste disposal a special attention is paid to clay and its mineralogic components as it has an important potential of retarding for both the radionuclides in radioactive wastes and fluid dynamics in the disposal site. The most frequent reaction implied in the radioisotope migration from liquid to solid phase is the cationic exchange. This work aimed at finding the relationship of clay and its mineralogic components, on one hand, and the exchange properties of the deposits, on the other hand. These relationships are based on the data obtained from about 50 cores sampled in 5 drillings performed in Saligny site, selected for radioactive waste disposal. Four levels different from physical, chemical and mineralogical properties were evidenced. The ionic exchange rate, with values within 5 to 30 me/100 g, has a trend of reflecting the clay contents. The relations between the cationic exchange rate and the clay contents appears to be linear with correlation coefficients varying within 0.81 - 0.97. The mineralogical composition of clay includes smectite (predominantly), illite and kaolin. Close, linear relations between the cationic exchange rate and the smectite fraction in clay and deposits were established with correlation coefficients within 0.74-0.76 and 0.85-0.95, respectively. These results show that the potential of the investigated deposits of acting as natural barriers with retarding effects on both radionuclides and the fluids in the disposal zone is strongly correlated to the amount and the content of the clay in these deposits

  16. Sedimentological and mineralogical characteristics of recent sediments at selected sites in the southern basin of Lake Michigan

    International Nuclear Information System (INIS)

    Tisue, G.T.; Merk, G.

    1976-01-01

    During the 1976 field season, sediment traps and current meters were set out in the southern basin of Lake Michigan to study the relationship between suspended material and currents. The gross mineralogical and chemical characteristics of the bottom sediments at the locations of these experiments were determined

  17. Steeply dipping heaving bedrock, Colorado: Part 2 - Mineralogical and engineering properties

    Science.gov (United States)

    Noe, D.C.; Higgins, J.D.; Olsen, H.W.

    2007-01-01

    This paper describes the mineralogical and engineering properties of steeply dipping, differentially heaving bedrock, which has caused severe damage near the Denver area. Several field sites in heave-prone areas have been characterized using high sample densities, numerous testing methodologies, and thousands of sample tests. Hydrometer testing shows that the strata range from siltstone to claystone (33 to 66 percent clay) with occasional bentonite seams (53 to 98 percent clay mixed with calcite). From X-ray diffraction analyses, the claystone contains varying proportions of illite-smectite and discrete (pure) smectite, and the bentonite contains discrete smectite. Accessory minerals include pyrite, gypsum, calcite, and oxidized iron compounds. The dominant exchangeable cation is Ca2+, except where gypsum is prevalent, and Mg2+ and Na1+ are elevated. Scanning electron microscope analyses show that the clay fabric is deformed and porous and that pyrite is absent within the weathered zone. Unified Soil Classification for the claystone varies from CL to CH, and the bentonite is CH to MH. Average moisture content values are 17 percent for claystone and 32 percent for bentonite, and these are typically 0 to 5 percent lower than the plastic limit. Swell-consolidation and suction testing shows a full range of swelling potentials from low to very high. These findings confirm that type I (bed-parallel, symmetrical to asymmetrical) heave features are strongly associated with changes in bedrock composition and mineralogy. Composition changes are not necessarily a factor for type II (bed-parallel to bed-oblique, strongly asymmetrical) heave features, which are associated with movements along subsurface shear zones.

  18. The letter, the dictionary and the laboratory: translating chemistry and mineralogy in eighteenth-century France.

    Science.gov (United States)

    Bret, Patrice

    2016-04-01

    Eighteenth-century scientific translation was not just a linguistic or intellectual affair. It included numerous material aspects requiring a social organization to marshal the indispensable human and non-human actors. Paratexts and actors' correspondences provide a good observatory to get information about aspects such as shipments and routes, processes of translation and language acquisition (dictionaries, grammars and other helpful materials, such as translated works in both languages), texts acquisition and dissemination (including author's additions and corrections, oral presentations in academic meetings and announcements of forthcoming translations). The nature of scientific translation changed in France during the second half of the eighteenth century. Beside solitary translators, it also happened to become a collective enterprise, dedicated to providing abridgements (Collection académique, 1755-79) or enriching the learned journals with full translations of the most recent foreign texts (Guyton de Morveau's 'Bureau de traduction de Dijon', devoted to chemistry and mineralogy, 1781-90). That new trend clearly had a decisive influence on the nature of the scientific press itself. A way to set up science as a social activity in the provincial capital of Dijon, translation required a local and international network for acquiring the linguistic and scientific expertise, along with the original texts, as quickly as possible. Laboratory results and mineralogical observations were used to compare material facts (colour, odour, shape of crystals, etc.) with those described in the original text. By providing a double kind of validation - with both the experiments and the translations - the laboratory thus happened to play a major role in translation.

  19. Holocene debris flows on the Colorado Plateau: The influence of clay mineralogy and chemistry

    Science.gov (United States)

    Webb, R.H.; Griffiths, P.G.; Rudd, L.P.

    2008-01-01

    Holocene debris flows do not occur uniformly on the Colorado Plateau province of North America. Debris flows occur in specific areas of the plateau, resulting in general from the combination of steep topography, intense convective precipitation, abundant poorly sorted material not stabilized by vegetation, and the exposure of certain fine-grained bedrock units in cliffs or in colluvium beneath those cliffs. In Grand and Cataract Canyons, fine-grained bedrock that produces debris flows contains primarily single-layer clays - notably illite and kaolinite - and has low multilayer clay content. This clay-mineral suite also occurs in the colluvium that produces debris flows as well as in debris-flow deposits, although unconsolidated deposits have less illite than the source bedrock. We investigate the relation between the clay mineralogy and major-cation chemistry of fine-grained bedrock units and the occurrence of debris flows on the entire Colorado Plateau. We determined that 85 mapped fine-grained bedrock units potentially could produce debris flows, and we analyzed clay mineralogy and major-cation concentration of 52 of the most widely distributed units, particularly those exposed in steep topography. Fine-grained bedrock units that produce debris flows contained an average of 71% kaolinite and illite and 5% montmorillonite and have a higher concentration of potassium and magnesium than nonproducing units, which have an average of 51% montmorillonite and a higher concentration of sodium. We used multivariate statistics to discriminate fine-grained bedrock units with the potential to produce debris flows, and we used digital-elevation models and mapped distribution of debris-flow producing units to derive a map that predicts potential occurrence of Holocene debris flows on the Colorado Plateau. ?? 2008 Geological Society of America.

  20. Combined mineralogical and EXAFS characterization of polluted sediments for the definition of technological variables and constraints

    Science.gov (United States)

    Brigatti, M. F.; Elmi, C.; Laurora, A.; Malferrari, D.; Medici, L.

    2009-04-01

    An extremely severe aspect, both from environmental and economic viewpoint, is the management of polluted sediments removed from drainage and irrigation canals. Canals, in order to retain their functionality over the time, need to have their beds, periodically cleaned from sediments there accumulating. The management of removed sediments is extremely demanding, also from an economical perspective, if these latter needs to be treated as dangerous waste materials, as stated in numerous international standards. Furthermore the disposal of such a large amount of material may introduce a significant environmental impact as well. An appealing alternative is the recovery or reuse of these materials, for example in brick and tile industry, after obviously the application of appropriate techniques and protocols that could render these latter no longer a threat for human health. The assessment of the effective potential danger for human health and ecosystem of sediments before and after treatment obviously requires both a careful chemical and mineralogical characterization and, even if not always considered in the international standards, the definition of the coordination shell of heavy metals dangerous for human health, as a function of their oxidation state and coordination (e.g. Cr and Pb), and introducing technological constraints or affecting the features of the end products. Fe is a good representative for this second category, as the features of the end product, such as color, strongly depend not only from Fe concentration but also from its oxidation state, speciation and coordination. This work will first of all provide mineralogical characterization of sediments from various sampling points of irrigation and drainage canals of Po river region in the north-eastern of Italy. Samples were investigated with various approaches including X-ray powder diffraction under non-ambient conditions, thermal analysis and EXAFS spectroscopy. Obtained results, and in particular