Thermodynamics and flow-frames for dissipative relativistic fluids
Ván, P. [Dept. of Theoretical Physics, Wigner Research Centre for Physics, Institute for Particle and Nuclear Physics, H-1525 Budapest, Konkoly Thege Miklós út 29-33, Hungary and Dept. of Energy Engineering, Budapest Univ. of Technology and Econ (Hungary); Biró, T. S. [Dept. of Theoretical Physics, Wigner Research Centre for Physics, Institute for Particle and Nuclear Physics, H-1525 Budapest, Konkoly Thege Miklós út 29-33 (Hungary)
2014-01-14
A general thermodynamic treatment of dissipative relativistic fluids is introduced, where the temperature four vector is not parallel to the velocity field of the fluid. Generic stability and kinetic equilibrium points out a particular thermodynamics, where the temperature vector is parallel to the enthalpy flow vector and the choice of the flow fixes the constitutive functions for viscous stress and heat. The linear stability of the homogeneous equilibrium is proved in a mixed particle-energy flow-frame.
Quantum relativistic fluid at global thermodynamic equilibrium in curved spacetime
Becattini, F
2015-01-01
We present a new approach to the problem of the thermodynamical equilibrium of a quantum relativistic fluid in a curved spacetime in the limit of small curvature. We calculate the mean value of local operators by expanding the four-temperature Killing vector field in Riemann normal coordinates about the same spacetime point and we derive corrections with respect to the flat spacetime expressions. Thereby, we clarify the origin of the terms proportional to Riemann and Ricci tensors introduced in general hydrodynamic expansion of the stress-energy tensor.
Local thermodynamical equilibrium and the β frame for a quantum relativistic fluid
Becattini, Francesco; Bucciantini, Leda; Grossi, Eduardo; Tinti, Leonardo
2015-01-01
We discuss the concept of local thermodynamical equilibrium in relativistic hydrodynamics in flat spacetime in a quantum statistical framework without an underlying kinetic description, suitable for strongly interacting fluids. We show that the appropriate definition of local equilibrium naturally leads to the introduction of a relativistic hydrodynamical frame in which the four-velocity vector is the one of a relativistic thermometer at equilibrium with the fluid, parallel to the inverse tem...
Local thermodynamical equilibrium and the β frame for a quantum relativistic fluid
Becattini, Francesco; Grossi, Eduardo [Universita di Firenze, Florence (Italy); INFN, Florence (Italy); Bucciantini, Leda [Dipartimento di Fisica, Universita di Pisa (Italy); INFN, Pisa (Italy); Tinti, Leonardo [Jan Kochanowski University, Kielce (Poland)
2015-05-15
We discuss the concept of local thermodynamical equilibrium in relativistic hydrodynamics in flat spacetime in a quantum statistical framework without an underlying kinetic description, suitable for strongly interacting fluids. We show that the appropriate definition of local equilibrium naturally leads to the introduction of a relativistic hydrodynamical frame in which the four-velocity vector is the one of a relativistic thermometer at equilibrium with the fluid, parallel to the inverse temperature four-vector β, which then becomes a primary quantity. We show that this frame is the most appropriate for the expansion of the stress-energy tensor from local thermodynamical equilibrium and that therein the local laws of thermodynamics take on their simplest form. We discuss the difference between the β frame and Landau frame and present an instance where they differ. (orig.)
Local thermodynamical equilibrium and the β frame for a quantum relativistic fluid
Becattini, Francesco, E-mail: becattini@fi.infn.it [Università di Firenze and INFN Sezione di Firenze, Florence (Italy); Bucciantini, Leda, E-mail: leda.bucciantini@df.unipi.it [Dipartimento di Fisica dell’Università di Pisa and INFN, 56127, Pisa (Italy); Grossi, Eduardo, E-mail: grossi@fi.infn.it [Università di Firenze and INFN Sezione di Firenze, Florence (Italy); Tinti, Leonardo, E-mail: dr.leonardo.tinti@gmail.com [Jan Kochanowski University, Kielce (Poland)
2015-05-05
We discuss the concept of local thermodynamical equilibrium in relativistic hydrodynamics in flat spacetime in a quantum statistical framework without an underlying kinetic description, suitable for strongly interacting fluids. We show that the appropriate definition of local equilibrium naturally leads to the introduction of a relativistic hydrodynamical frame in which the four-velocity vector is the one of a relativistic thermometer at equilibrium with the fluid, parallel to the inverse temperature four-vector β, which then becomes a primary quantity. We show that this frame is the most appropriate for the expansion of the stress-energy tensor from local thermodynamical equilibrium and that therein the local laws of thermodynamics take on their simplest form. We discuss the difference between the β frame and Landau frame and present an instance where they differ.
The regular conducting fluid model for relativistic thermodynamics
Carter, Brandon
2012-01-01
The "regular" model presented here can be considered to be the most natural solution to the problem of constructing the simplest possible relativistic analogue of the category of classical Fourier--Euler thermally conducting fluid models as characterised by a pair of equations of state for just two dependent variables (an equilibrium density and a conducting scalar). The historically established but causally unsatisfactory solution to this problem due to Eckart is shown to be based on an ansatz that is interpretable as postulating a most unnatural relation between the (particle and entropy) velocities and their associated momenta, which accounts for the well known bad behaviour of that model which has recently been shown to have very pathological mixed-elliptic-hyperbolic comportments. The newer (and more elegant) solution of Landau and Lifshitz has a more mathematically respectable parabolic-hyperbolic comportment, but is still compatible with a well posed initial value problem only in such a restricted limi...
Relativistic viscoelastic fluid mechanics.
Fukuma, Masafumi; Sakatani, Yuho
2011-08-01
A detailed study is carried out for the relativistic theory of viscoelasticity which was recently constructed on the basis of Onsager's linear nonequilibrium thermodynamics. After rederiving the theory using a local argument with the entropy current, we show that this theory universally reduces to the standard relativistic Navier-Stokes fluid mechanics in the long time limit. Since effects of elasticity are taken into account, the dynamics at short time scales is modified from that given by the Navier-Stokes equations, so that acausal problems intrinsic to relativistic Navier-Stokes fluids are significantly remedied. We in particular show that the wave equations for the propagation of disturbance around a hydrostatic equilibrium in Minkowski space-time become symmetric hyperbolic for some range of parameters, so that the model is free of acausality problems. This observation suggests that the relativistic viscoelastic model with such parameters can be regarded as a causal completion of relativistic Navier-Stokes fluid mechanics. By adjusting parameters to various values, this theory can treat a wide variety of materials including elastic materials, Maxwell materials, Kelvin-Voigt materials, and (a nonlinearly generalized version of) simplified Israel-Stewart fluids, and thus we expect the theory to be the most universal description of single-component relativistic continuum materials. We also show that the presence of strains and the corresponding change in temperature are naturally unified through the Tolman law in a generally covariant description of continuum mechanics.
Galilean relativistic fluid mechanics
Ván, Péter
2015-01-01
Single component Galilean-relativistic (nonrelativistic) fluids are treated independently of reference frames. The basic fields are given, their balances, thermodynamic relations and the entropy production is calculated. The usual relative basic fields, the mass, momentum and energy densities, the diffusion current density, the pressure tensor and the heat flux are the time- and spacelike components of the third order mass-momentum-energy density tensor according to a velocity field. The transformation rules of the basic fields are derived and prove that the non-equilibrium thermodynamic background theory, that is the Gibbs relation, extensivity condition and the entropy production is absolute, that is independent of the reference frame and also of the fluid velocity. --- Az egykomponensu Galilei-relativisztikus (azaz nemrelativisztikus) disszipativ folyadekokat vonatkoztatasi rendszertol fuggetlenul targyaljuk. Megadjuk az alapmennyisegeket, ezek merlegeit, a termodinamikai osszefuggeseket es kiszamoljuk az ...
Variational thermodynamics of relativistic thin disks
Gutiérrez-Piñeres, Antonio C.; Lopez-Monsalvo, Cesar S.; Quevedo, Hernando
2015-12-01
We present a relativistic model describing a thin disk system composed of two fluids. The system is surrounded by a halo in the presence of a non-trivial electromagnetic field. We show that the model is compatible with the variational multifluid thermodynamics formalism, allowing us to determine all the thermodynamic variables associated with the matter content of the disk. The asymptotic behavior of these quantities indicates that the single fluid interpretation should be abandoned in favor of a two-fluid model.
Variational thermodynamics of relativistic thin disks
Gutiérrez-Piñeres, A C; Quevedo, H
2013-01-01
We present a relativistic model describing a thin disk system composed of two fluids. The system is surrounded by a halo in the presence of a non-trivial electromagnetic field. We show that the model is compatible with the variational multi-fluid thermodynamics formalism, allowing us to determine all the thermodynamic variables associated with the matter content of the disk. The asymptotic behaviour of these quantities indicates that the single fluid interpretation should be abandoned in favour of a two-fluid model.
Vector Theory in Relativistic Thermodynamics
刘泽文
1994-01-01
It is pointed out that five defects occur in Planck-Einstein’s relativistic thermodynamics (P-E theory). A vector theory in relativistic thermodynamics (VTRT) is established. Defining the internal energy as a 4-vector, and supposing the entropy and the number of. particles to be invariants we have derived the transformations of all quantities, and subsequently got the Lagrangian and 4-D forms of thermodynamic laws. In order to test the new theory, several exact solutions with classical limits are given. The VTRT is free from the defects of the P-E theory.
Entropy current for non-relativistic fluid
Banerjee, Nabamita; Jain, Akash; Roychowdhury, Dibakar
2014-01-01
We study transport properties of a parity-odd, non-relativistic charged fluid in presence of background electric and magnetic fields. To obtain stress tensor and charged current for the non-relativistic system we start with the most generic relativistic fluid, living in one higher dimension and reduce the constituent equations along the light-cone direction. We also reduce the equation satisfied by the entropy current of the relativistic theory and obtain a consistent entropy current for the non-relativistic system (we call it "canonical form" of the entropy current). Demanding that the non-relativistic fluid satisfies the second law of thermodynamics we impose constraints on various first order transport coefficients. For parity even fluid, this is straight forward; it tells us positive definiteness of different transport coefficients like viscosity, thermal conductivity, electric conductivity etc. However for parity-odd fluid, canonical form of the entropy current fails to confirm the second law of thermody...
Thermodynamic and relativistic uncertainty relations
Artamonov, A. A.; Plotnikov, E. M.
2017-01-01
Thermodynamic uncertainty relation (UR) was verified experimentally. The experiments have shown the validity of the quantum analogue of the zeroth law of stochastic thermodynamics in the form of the saturated Schrödinger UR. We have also proposed a new type of UR for the relativistic mechanics. These relations allow us to consider macroscopic phenomena within the limits of the ratio of the uncertainty relations for different physical quantities.
Density perturbations with relativistic thermodynamics
Maartens, R
1997-01-01
We investigate cosmological density perturbations in a covariant and gauge- invariant formalism, incorporating relativistic causal thermodynamics to give a self-consistent description. The gradient of density inhomogeneities splits covariantly into a scalar part, a rotational vector part that is determined by the vorticity, and a tensor part that describes the shape. We give the evolution equations for these parts in the general dissipative case. Causal thermodynamics gives evolution equations for viswcous stress and heat flux, which are coupled to the density perturbation equation and to the entropy and temperature perturbation equations. We give the full coupled system in the general dissipative case, and simplify the system in certain cases.
Relativistic perfect fluids in local thermal equilibrium
Coll, Bartolomé; Sáez, Juan Antonio
2016-01-01
The inverse problem for conservative perfect fluid energy tensors provides a striking result. Namely that, in spite of its name, its historic origin or its usual conceptualization, the notion of {\\em local thermal equilibrium} for a perfect fluid is a {\\em purely hydrodynamic}, not thermodynamic, notion. This means that it may be thought, defined and detected using exclusively hydrodynamic quantities, without reference to temperature or any other thermodynamic concept, either of equilibrium or irreversible: a relativistic perfect fluid evolves in local thermal equilibrium if, and only if, its hydrodynamic variables evolve keeping a certain relation among them. This relation fixes, but only fixes, a precise fraction of the thermodynamics of the fluid, namely that relating the speed of its sound waves to the hydrodynamic variables. All thermodynamic schemes (sets of thermodynamic variables and their mutual relations) compatible with such a relation on the sole hydrodynamic variables are obtained. This hydrodyna...
Galilean relativistic fluid mechanics
Ván, Péter
2015-01-01
Single component nonrelativistic dissipative fluids are treated independently of reference frames and flow-frames. First the basic fields and their balances, then the related thermodynamic relations and the entropy production are calculated and the linear constitutive relations are given. The usual basic fields of mass, momentum, energy and their current densities, the heat flux, pressure tensor and diffusion flux are the time- and spacelike components of the third order mass-momentum-energy ...
DYNAMICS OF RELATIVISTIC FLUID FOR COMPRESSIBLE GAS
无
2011-01-01
In this paper the relativistic fluid dynamics for compressible gas is studied.We show that the strict convexity of the negative thermodynamical entropy preserves invariant under the Lorentz transformation if and only if the local speed of sound in this gas is strictly less than that of light in the vacuum.A symmetric form for the equations of relativistic hydrodynamics is presented,and thus the local classical solutions to these equations can be deduced.At last,the non-relativistic limits of these local cla...
A two-fluid model for relativistic heat conduction
López-Monsalvo, César S. [Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México (Mexico)
2014-01-14
Three years ago it was presented in these proceedings the relativistic dynamics of a multi-fluid system together with various applications to a set of topical problems [1]. In this talk, I will start from such dynamics and present a covariant formulation of relativistic thermodynamics which provides us with a causal constitutive equation for the propagation of heat in a relativistic setting.
Speeds of Propagation in Classical and Relativistic Extended Thermodynamics
Müller Ingo
1999-01-01
Full Text Available The Navier-Stokes-Fourier theory of viscous, heat-conducting fluids provides parabolic equations and thus predicts infinite pulse speeds. Naturally this feature has disqualified the theory for relativistic thermodynamics which must insist on finite speeds and, moreover, on speeds smaller than $c$. The attempts at a remedy have proved heuristically important for a new systematic type of thermodynamics: Extended thermodynamics. That new theory has symmetric hyperbolic field equations and thus it provides finite pulse speeds. Extended thermodynamics is a whole hierarchy of theories with an increasing number of fields when gradients and rates of thermodynamic processes become steeper and faster. The first stage in this hierarchy is the 14-field theory which may already be a useful tool for the relativist in many applications. The 14 fields -- and further fields -- are conveniently chosen from the moments of the kinetic theory of gases. The hierarchy is complete only when the number of fields tends to infinity. In that case the pulse speed of non-relativistic extended thermodynamics tends to infinity while the pulse speed of relativistic extended thermodynamics tends to $c$, the speed of light. In extended thermodynamics symmetric hyperbolicity -- and finite speeds -- are implied by the concavity of the entropy density. This is still true in relativistic thermodynamics for a privileged entropy density which is the entropy density of the rest frame for non-degenerate gases.
Relativistic non-equilibrium thermodynamics revisited
García-Colin, L S
2006-01-01
Relativistic irreversible thermodynamics is reformulated following the conventional approach proposed by Meixner in the non-relativistic case. Clear separation between mechanical and non-mechanical energy fluxes is made. The resulting equations for the entropy production and the local internal energy have the same structure as the non-relativistic ones. Assuming linear constitutive laws, it is shown that consistency is obtained both with the laws of thermodynamics and causality.
Galilean relativistic fluid mechanics
Ván, P.
2017-01-01
Single-component nonrelativistic dissipative fluids are treated independently of reference frames and flow-frames. First the basic fields and their balances are derived, then the related thermodynamic relations and the entropy production are calculated and the linear constitutive relations are given. The usual basic fields of mass, momentum, energy and their current densities, the heat flux, pressure tensor and diffusion flux are the time- and spacelike components of the third-order mass-momentum-energy density-flux four-tensor. The corresponding Galilean transformation rules of the physical quantities are derived. It is proved that the non-equilibrium thermodynamic frame theory, including the thermostatic Gibbs relation and extensivity condition and also the entropy production, is independent of the reference frame and also the flow-frame of the fluid. The continuity-Fourier-Navier-Stokes equations are obtained almost in the traditional form if the flow of the fluid is fixed to the temperature. This choice of the flow-frame is the thermo-flow. A simple consequence of the theory is that the relation between the total, kinetic and internal energies is a Galilean transformation rule.
Cattaneo, Carlo
2011-01-01
This title includes: Pham Mau Quam: Problemes mathematiques en hydrodynamique relativiste; A. Lichnerowicz: Ondes de choc, ondes infinitesimales et rayons en hydrodynamique et magnetohydrodynamique relativistes; A.H. Taub: Variational principles in general relativity; J. Ehlers: General relativistic kinetic theory of gases; K. Marathe: Abstract Minkowski spaces as fibre bundles; and, G. Boillat: Sur la propagation de la chaleur en relativite.
Relativistic Thermodynamics: A Modern 4-Vector Approach
J. Güémez
2011-01-01
Full Text Available Using the Minkowski relativistic 4-vector formalism, based on Einstein's equation, and the relativistic thermodynamics asynchronous formulation (Grøn (1973, the isothermal compression of an ideal gas is analyzed, considering an electromagnetic origin for forces applied to it. This treatment is similar to the description previously developed by Van Kampen (van Kampen (1969 and Hamity (Hamity (1969. In this relativistic framework Mechanics and Thermodynamics merge in the first law of relativistic thermodynamics expressed, using 4-vector notation, such as ΔUμ = Wμ + Qμ, in Lorentz covariant formulation, which, with the covariant formalism for electromagnetic forces, constitutes a complete Lorentz covariant formulation for classical physics.
Thermodynamic Laws and Equipartition Theorem in Relativistic Brownian Motion
Koide, T.; Kodama, T.
2011-01-01
We extend the stochastic energetics to a relativistic system. The thermodynamic laws and equipartition theorem are discussed for a relativistic Brownian particle and the first and the second law of thermodynamics in this formalism are derived. The relation between the relativistic equipartition relation and the rate of heat transfer is discussed in the relativistic case together with the nature of the noise term.
Thermodynamic laws and equipartition theorem in relativistic Brownian motion.
Koide, T; Kodama, T
2011-06-01
We extend the stochastic energetics to a relativistic system. The thermodynamic laws and equipartition theorem are discussed for a relativistic Brownian particle and the first and the second law of thermodynamics in this formalism are derived. The relation between the relativistic equipartition relation and the rate of heat transfer is discussed in the relativistic case together with the nature of the noise term.
Is a Relativistic Thermodynamics possible?; Es posible una Termodinamica Relativista?
Guemez, J.
2010-07-01
A brief historical review the literature on developing the concept of Thermodynamics Relativistic. We analyze two examples of application of the Galilean and Relativistic Thermodynamics discussed under what circumstances could build a relativistic Thermodynamics Lorentz covariant with physical sense. (Author) 19 refs.
Thermodynamics of polarized relativistic matter
Kovtun, Pavel
2016-07-01
We give the free energy of equilibrium relativistic matter subject to external gravitational and electromagnetic fields, to one-derivative order in the gradients of the external fields. The free energy allows for a straightforward derivation of bound currents and bound momenta in equilibrium. At leading order, the energy-momentum tensor admits a simple expression in terms of the polarization tensor. Beyond the leading order, electric and magnetic polarization vectors are intrinsically ambiguous. The physical effects of polarization, such as the correlation between the magneto-vortically induced surface charge and the electro-vortically induced surface current, are not ambiguous.
Thermodynamics of polarized relativistic matter
Kovtun, Pavel
2016-01-01
We give the free energy of equilibrium relativistic matter subject to external gravitational and electromagnetic fields, to one-derivative order in the gradients of the external fields. The free energy allows for a straightforward derivation of bound currents and bound momenta in equilibrium. At leading order, the energy-momentum tensor admits a simple expression in terms of the polarization tensor. Beyond the leading order, electric and magnetic polarization vectors are intrinsically ambiguous. The physical effects of polarization, such as the correlation between the magneto-vortically induced surface charge and the electro-vortically induced surface current, are not ambiguous.
Relativistic like structure of classical thermodynamics
Quevedo, Hernando; Sánchez, Alberto; Vázquez, Alejandro
2015-04-01
We analyze in the context of geometrothermodynamics a Legendre invariant metric structure in the equilibrium space of an ideal gas. We introduce the concept of thermodynamic geodesic as a succession of points, each corresponding to a state of equilibrium, so that the resulting curve represents a quasi-static process. A rigorous geometric structure is derived in which the thermodynamic geodesics at a given point split the equilibrium space into two disconnected regions separated by adiabatic geodesics. This resembles the causal structure of special relativity, which we use to introduce the concept of adiabatic cone for thermodynamic systems. This result might be interpreted as an alternative indication of the inter-relationship between relativistic physics and classical thermodynamics.
Simple waves in relativistic fluids.
Lyutikov, Maxim
2010-11-01
We consider the Riemann problem for relativistic flows of polytropic fluids and find relations for the flow characteristics. Evolution of physical quantities takes especially simple form for the case of cold magnetized plasmas. We find exact explicit analytical solutions for one-dimensional expansion of magnetized plasma into vacuum, valid for arbitrary magnetization. We also consider expansion into cold unmagnetized external medium both for stationary initial conditions and for initially moving plasma, as well as reflection of rarefaction wave from a wall. We also find self-similar structure of three-dimensional magnetized outflows into vacuum, valid close to the plasma-vacuum interface.
Molecular thermodynamics of nonideal fluids
Lee, Lloyd L
2013-01-01
Molecular Thermodynamics of Nonideal Fluids serves as an introductory presentation for engineers to the concepts and principles behind and the advances in molecular thermodynamics of nonideal fluids. The book covers related topics such as the laws of thermodynamics; entropy; its ensembles; the different properties of the ideal gas; and the structure of liquids. Also covered in the book are topics such as integral equation theories; theories for polar fluids; solution thermodynamics; and molecular dynamics. The text is recommended for engineers who would like to be familiarized with the concept
Thermodynamic properties of cryogenic fluids
Leachman, Jacob; Lemmon, Eric; Penoncello, Steven
2017-01-01
This update to a classic reference text provides practising engineers and scientists with accurate thermophysical property data for cryogenic fluids. The equations for fifteen important cryogenic fluids are presented in a basic format, accompanied by pressure-enthalpy and temperature-entropy charts and tables of thermodynamic properties. It begins with a chapter introducing the thermodynamic relations and functional forms for equations of state, and goes on to describe the requirements for thermodynamic property formulations, needed for the complete definition of the thermodynamic properties of a fluid. The core of the book comprises extensive data tables and charts for the most commonly-encountered cryogenic fluids. This new edition sees significant updates to the data presented for air, argon, carbon monoxide, deuterium, ethane, helium, hydrogen, krypton, nitrogen and xenon. The book supports and complements NIST’s REFPROP - an interactive database and tool for the calculation of thermodynamic propertie...
Non-Newtonian Properties of Relativistic Fluids
Koide, Tomoi
2010-01-01
We show that relativistic fluids behave as non-Newtonian fluids. First, we discuss the problem of acausal propagation in the diffusion equation and introduce the modified Maxwell-Cattaneo-Vernotte (MCV) equation. By using the modified MCV equation, we obtain the causal dissipative relativistic (CDR) fluid dynamics, where unphysical propagation with infinite velocity does not exist. We further show that the problems of the violation of causality and instability are intimately related, and the relativistic Navier-Stokes equation is inadequate as the theory of relativistic fluids. Finally, the new microscopic formula to calculate the transport coefficients of the CDR fluid dynamics is discussed. The result of the microscopic formula is consistent with that of the Boltzmann equation, i.e., Grad's moment method.
Thermodynamics of Relativistic Fermions with Chern-Simons Coupling
Bralic, N; Schaposnik, F A
1994-01-01
We study the thermodynamics of the relativistic Quantum Field Theory of massive fermions in three space-time dimensions coupled to an Abelian Maxwell-Chern-Simons gauge field. We evaluate the specific heat at finite temperature and density and find that the variation with the statistical angle is consistent with the non-relativistic ideas on generalized statistics.
Benedicks effect in a relativistic simple fluid
Garcia-Perciante, A L; Garcia-Colin, L S
2013-01-01
According to standard thermophysical theories, cross effects are mostly present in multicomponent systems. In this paper we show that for relativistic fluids an electric field generates a heat flux even in the single component case. In the non-relativistic limit the effect vanishes and Fourier's law is recovered. This result is novel and may have applications in the transport properties of very hot plasmas.
Thermodynamics of Van der Waals Fluids with quantum statistics
Redlich, Krzysztof
2016-01-01
We consider thermodynamics of the van der Waals fluid of quantum systems. We derive general relations of thermodynamic functions and parameters of any ideal gas and the corresponding van der Waals fluid. This provides unambiguous generalization of the classical van der Waals theory to quantum statistical systems. As an example, we apply the van der Waals fluid with fermi statistics to characterize the liquid-gas critical point in nuclear matter. We also introduce the Bose-Einstein condensation in the relativistic van der Waals boson gas, and argue, that it exhibits two-phase structure separated in space.
Relabeling symmetry in relativistic fluids and plasmas
Kawazura, Yohei; Fukumoto, Yasuhide
2014-01-01
The conservation of the recently formulated relativistic canonical helicity [Yoshida Z, Kawazura Y, and Yokoyama T 2014 J. Math. Phys. 55 043101] is derived from Noether's theorem by constructing an action principle on the relativistic Lagrangian coordinates (we obtain general cross helicities that include the helicity of the canonical vorticity). The conservation law is, then, explained by the relabeling symmetry pertinent to the Lagrangian label of fluid elements. Upon Eulerianizing the Noether current, the purely spatial volume integral on the Lagrangian coordinates is mapped to a space-time mixed three-dimensional integral on the four-dimensional Eulerian coordinates. The relativistic conservation law in the Eulerian coordinates is no longer represented by any divergence-free current; hence, it is not adequate to regard the relativistic helicity (represented by the Eulerian variables) as a Noether charge, and this stands the reason why the "conventional helicity" is no longer a constant of motion. We have...
Magnetohydrodynamics of Chiral Relativistic Fluids
Boyarsky, Alexey; Ruchayskiy, Oleg
2015-01-01
We study the dynamics of a plasma of charged relativistic fermions at very high temperature $T\\gg m$, where $m$ is the fermion mass, coupled to the electromagnetic field. In particular, we derive a magneto-hydrodynamical description of the evolution of such a plasma. We show that, as compared to conventional MHD for a plasma of non-relativistic particles, the hydrodynamical description of the relativistic plasma involves new degrees of freedom described by a pseudo-scalar field originating in a local asymmetry in the densities of left-handed and right-handed fermions. This field can be interpreted as an effective axion field. Taking into account the chiral anomaly we present dynamical equations for the evolution of this field, as well as of other fields appearing in the MHD description of the plasma. Due to its non-linear coupling to helical magnetic fields, the axion field significantly affects the dynamics of a magnetized plasma and can give rise to a novel type of inverse cascade.
Thermodynamics of perfect fluids from scalar field theory
Ballesteros, Guillermo; Pilo, Luigi
2016-01-01
The low-energy dynamics of relativistic continuous media is given by a shift-symmetric effective theory of four scalar fields. These scalars describe the embedding in spacetime of the medium and play the role of Stuckelberg fields for spontaneously broken spatial and time translations. Perfect fluids are selected imposing a stronger symmetry group or reducing the field content to a single scalar. We explore the relation between the field theory description of perfect fluids to thermodynamics. By drawing the correspondence between the allowed operators at leading order in derivatives and the thermodynamic variables, we find that a complete thermodynamic picture requires the four Stuckelberg fields. We show that thermodynamic stability plus the null energy condition imply dynamical stability. We also argue that a consistent thermodynamic interpretation is not possible if any of the shift symmetries is explicitly broken.
Instabilities in a Relativistic Viscous Fluid
Corona-Galindo, M. G.; Klapp, J.; Vazquez, A.
1990-11-01
RESUMEN. Las ecuaciones hidrodinamicas de un fluido imperfecto relativista son resueltas, y los modos hidrodinamicos son analizados con el prop6sito de estabiecer correlaciones con las estructuras cosmol6gicas. ABSTRACT The hydrodynamical equations of a relativistic imperfect fluid are solved, and the hydrodynamical modes are analysed with the aim to establish correlations with cosmological structures. Ke, words: COSMOLOGY - HYDRODYNAMICS - RELATIVITY
Experimental thermodynamics experimental thermodynamics of non-reacting fluids
Neindre, B Le
2013-01-01
Experimental Thermodynamics, Volume II: Experimental Thermodynamics of Non-reacting Fluids focuses on experimental methods and procedures in the study of thermophysical properties of fluids. The selection first offers information on methods used in measuring thermodynamic properties and tests, including physical quantities and symbols for physical quantities, thermodynamic definitions, and definition of activities and related quantities. The text also describes reference materials for thermometric fixed points, temperature measurement under pressures, and pressure measurements. The publicatio
Relativistic mechanical-thermodynamical formalism -- description of inelastic collisions
Guemez, Julio; Fernandez, Luis A
2016-01-01
We present a relativistic formalism inspired on the Minkowski four-vectors that also includes conservation laws such as the first law of thermodynamics. It remains close to the relativistic four-vector formalism developed for a single particle, but it is also related to the classical treatment of problems that imperatively require both the Newton's second law and the energy conservation law. We apply the developed formalism to inelastic collisions to better show how it works.
Nonlinear waves in strongly interacting relativistic fluids
Fogaça, D A; Filho, L G Ferreira
2013-01-01
During the past decades the study of strongly interacting fluids experienced a tremendous progress. In the relativistic heavy ion accelerators, specially the RHIC and LHC colliders, it became possible to study not only fluids made of hadronic matter but also fluids of quarks and gluons. Part of the physics program of these machines is the observation of waves in this strongly interacting medium. From the theoretical point of view, these waves are often treated with li-nearized hydrodynamics. In this text we review the attempts to go beyond linearization. We show how to use the Reductive Perturbation Method to expand the equations of (ideal and viscous) relativistic hydrodynamics to obtain nonlinear wave equations. These nonlinear wave equations govern the evolution of energy density perturbations (in hot quark gluon plasma) or baryon density perturbations (in cold quark gluon plasma and nuclear matter). Different nonlinear wave equations, such as the breaking wave, Korteweg-de Vries and Burgers equations, are...
An Undergraduate Exercise in the First Law of Relativistic Thermodynamics
Guemez, J.
2010-01-01
The isothermal compression of an ideal gas is analysed using a relativistic thermodynamics formalism based on the principle of inertia of energy (Einstein's equation) and the asynchronous formulation (Cavalleri and Salgarelli 1969 "Nuovo Cimento" 42 722-54), which is similar to the formalism developed by van Kampen (1968 "Phys. Rev." 173 295-301)…
Hadron thermodynamics in relativistic nuclear collisions
Ammiraju, P.
1985-01-01
Various phenomenological models based on statistical thermodynamical considerations were used to fit the experimental data at high P sub T to a two temperature distribution. Whether this implies that the two temperatures belong to two different reaction mechanisms, or consequences of Lorentz-contraction factor, or related in a fundamental way to the intrinsic thermodynamics of Space-Time can only be revealed by further theoretical and experimental investigations of high P sub T phenomena in extremely energetic hadron-hadron collisions.
Formulation of relativistic dissipative fluid dynamics and its applications in heavy-ion collisions
Jaiswal, Amaresh
2014-01-01
Relativistic fluid dynamics finds application in astrophysics, cosmology and the physics of high-energy heavy-ion collisions. In this thesis, we present our work on the formulation of relativistic dissipative fluid dynamics within the framework of relativistic kinetic theory. We employ the second law of thermodynamics as well as the relativistic Boltzmann equation to obtain the dissipative evolution equations. We present a new derivation of the dissipative hydrodynamic equations using the second law of thermodynamics wherein all the second-order transport coefficients get determined uniquely within a single theoretical framework. An alternate derivation of the dissipative equations which does not make use of the two major approximations/assumptions namely, Grad's 14-moment approximation and second moment of Boltzmann equation, inherent in the Israel-Stewart theory, is also presented. Moreover, by solving the Boltzmann equation iteratively in a Chapman-Enskog like expansion, we have derived the form of second-...
Muronga, A
2007-01-01
In the causal theory of relativistic dissipative fluid dynamics, there are conditions on the equation of state and other thermodynamic properties such as the second-order coefficients of a fluid that need to be satisfied to guarantee that the fluid perturbations propagate causally and obey hyperbolic equations. The second-order coefficients in the causal theory, which are the relaxation times for the dissipative degrees of freedom and coupling constants between different forms of dissipation (relaxation lengths), are presented for partonic and hadronic systems. These coefficients involves relativistic thermodynamic integrals. The integrals are presented for general case and also for different regimes in the temperature--chemical potential plane. It is shown that for a given equation of state these second-order coefficients are not additional parameters but they are determined by the equation of state. We also present the prescription on the calculation of the freeze-out particle spectra from the dynamics of r...
New interior solution describing relativistic fluid sphere
KSH NEWTON SINGH; NARENDRA PRADHAN; NEERAJ PANT
2017-08-01
Anewexact solution of embedding class I is presented for a relativistic anisotropicmassive fluid sphere. The new exact solution satisfies Karmarkar condition, is well-behaved in all respects, and therefore is suitable for the modelling of superdense stars. Consequently, using this solution, we have studied in detail two compact stars, namely, XTE J1739-289 (strange star 1.51$M_{\\odot}$, 10.9 km) and PSR J1614-2230 (neutron star 1.97$M_{\\odot}$, 14 km). The solution also satisfies all energy conditions with the compactness parameter lying within the Buchdahl limit.
Thermodynamics of the relativistic Fermi gas in D dimensions
Sevilla, Francisco J.; Piña, Omar
2017-09-01
The influence of spatial dimensionality and particle-antiparticle pair production on the thermodynamic properties of the relativistic Fermi gas, at finite chemical potential, is studied. Resembling a ;phase transition;, qualitatively different behaviors of the thermodynamic susceptibilities, namely the isothermal compressibility and the specific heat, are markedly observed at different temperature regimes as function of the system dimensionality and of the rest mass of the particles. A minimum in the temperature dependence of the isothermal compressibility marks a characteristic temperature, in the range of tenths of the Fermi temperature, at which the system transit from a ;normal; phase, to a phase where the gas compressibility grows as a power law of the temperature.
Relativistic elasticity of stationary fluid branes
Armas, J.; Obers, N.A.
2013-01-01
Fluid mechanics can be formulated on dynamical surfaces of arbitrary codimension embedded in a background space-time. This has been the main object of study of the blackfold approach in which the emphasis has primarily been on stationary fluid configurations. Motivated by this approach we show...... under certain conditions that a given stationary fluid configuration living on a dynamical surface of vanishing thickness and satisfying locally the first law of thermodynamics will behave like an elastic brane when the surface is subject to small deformations. These results, which are independent...... of the number of space-time dimensions and of the fluid arising from a gravitational dual, reveal the (electro)elastic character of (charged) black branes when considering extrinsic perturbations....
Relativistic Elasticity of Stationary Fluid Branes
Armas, Jay
2012-01-01
Fluid mechanics can be formulated on dynamical surfaces of arbitrary co-dimension embedded in a background space-time. This has been the main object of study of the blackfold approach in which the emphasis has primarily been on stationary fluid configurations. Motivated by this approach we show under certain conditions that a given stationary fluid configuration living on a dynamical surface of vanishing thickness and satisfying locally the first law of thermodynamics will behave like an elastic brane when the surface is subject to small deformations. These results, which are independent of the number of space-time dimensions and of the fluid arising from a gravitational dual, reveal the (electro)elastic character of (charged) black branes when considering extrinsic perturbations.
Relativistic fluid dynamics in heavy ion collisions
Pu, Shi
2011-01-01
This dissertation is about the study of three important issues in the theory of relativistic fluid dynamics: the stability of dissipative fluid dynamics, the shear viscosity, and fluid dynamics with triangle anomaly.(1)The second order theory of fluid dynamics is necessary for causality. However the causality cannot be guaranteed for all parameters. The constraints for parameters are then given. We also point out that the causality and the stability are inter-correlated. It is found that a causal system must be stable, but an acausal system in the boost frame at high speed must be unstable. (2)The transport coefficients can be determined in kinetic theory. We will firstly discuss about derivation of the shear viscosity via variational method in the Boltzmann equation. Secondly, we will compute the shear viscosity via AdS/CFT duality in a Bjorken boost invariant fluid with radial flow. It is found that the ratio of the shear viscosity to entropy density is consistent with the work of Policastro, Son and Starin...
Supercritical fluid thermodynamics from equations of state
Giovangigli, Vincent; Matuszewski, Lionel
2012-03-01
Supercritical multicomponent fluid thermodynamics are often built from equations of state. We investigate mathematically such a construction of a Gibbsian thermodynamics compatible at low density with that of ideal gas mixtures starting from a pressure law. We further study the structure of chemical production rates obtained from nonequilibrium statistical thermodynamics. As a typical application, we consider the Soave-Redlich-Kwong cubic equation of state and investigate mathematically the corresponding thermodynamics. This thermodynamics is then used to study the stability of H2-O2-N2 mixtures at high pressure and low temperature as well as to illustrate the role of nonidealities in a transcritical H2-O2-N2 flame.
Effective actions for relativistic fluids from holography
de Boer, Jan; Pinzani-Fokeeva, Natalia
2015-01-01
Motivated by recent progress in developing action formulations of relativistic hydrodynamics, we use holography to derive the low energy dissipationless effective action for strongly coupled conformal fluids. Our analysis is based on the study of novel double Dirichlet problems for the gravitational field, in which the boundary conditions are set on two codimension one timelike hypersurfaces (branes). We provide a geometric interpretation of the Goldstone bosons appearing in such constructions in terms of a family of spatial geodesics extending between the ultraviolet and the infrared brane. Furthermore, we discuss supplementing double Dirichlet problems with information about the near-horizon geometry. We show that upon coupling to a membrane paradigm boundary condition, our approach reproduces correctly the complex dispersion relation for both sound and shear waves. We also demonstrate that upon a Wick rotation, our formulation reproduces the equilibrium partition function formalism, provided the near-horiz...
Relativistic transport theory for simple fluids at first order in the gradients: a stable picture
Sandoval-Villalbazo, A; García-Colin, L S
2008-01-01
In this paper we show how using a relativistic kinetic equation. The ensuing expression for the heat flux can be casted in the form required by Classical Irreversible Thermodynamics. Indeed, it is linearly related to the temperature and number density gradients and not to the acceleration as the so called first order in the gradients theories contend. Since the specific expressions for the transport coefficients are irrelevant for our purposes, the BGK form of the kinetic equation is used. Moreover, from the resulting hydrodynamic equations it is readily seen that no instabilities are present in the transverse hydrodynamic velocity mode of the simple relativistic fluid.
On the relative importance of second-order terms in relativistic dissipative fluid dynamics
Molnár, E; Denicol, G S; Rischke, D H
2013-01-01
In Denicol et al., Phys. Rev. D 85, 114047 (2012), the equations of motion of relativistic dissipative fluid dynamics were derived from the relativistic Boltzmann equation. These equations contain a multitude of terms of second order in Knudsen number, in inverse Reynolds number, or their product. Terms of second order in Knudsen number give rise to non-hyperbolic (and thus acausal) behavior and must be neglected in (numerical) solutions of relativistic dissipative fluid dynamics. The coefficients of the terms which are of the order of the product of Knudsen and inverse Reynolds numbers have been explicitly computed in the above reference, in the limit of a massless Boltzmann gas. Terms of second order in inverse Reynolds number arise from the collision term in the Boltzmann equation, upon expansion to second order in deviations from the single-particle distribution function in local thermodynamical equilibrium. In this work, we compute these second-order terms for a massless Boltzmann gas with constant scatt...
Time-dependent closure relations for relativistic collisionless fluid equations.
Bendib-Kalache, K; Bendib, A; El Hadj, K Mohammed
2010-11-01
Linear fluid equations for relativistic and collisionless plasmas are derived. Closure relations for the fluid equations are analytically computed from the relativistic Vlasov equation in the Fourier space (ω,k), where ω and k are the conjugate variables of time t and space x variables, respectively. The mathematical method used is based on the projection operator techniques and the continued fraction mathematical tools. The generalized heat flux and stress tensor are calculated for arbitrary parameter ω/kc where c is the speed of light, and for arbitrary relativistic parameter z=mc²/T , where m is the particle rest mass and T, the plasma temperature in energy units.
Thermodynamics of relativistic quantum fields: extracting energy from gravitational waves
Bruschi, David Edward
2016-01-01
We investigate the quantum thermodynamical properties of localised relativistic quantum fields that can be used as quantum thermal machines. We study the efficiency and power of energy transfer between the classical degrees of freedom, such as the energy input due to motion or to an impinging gravitational wave, and the excitations of the confined quantum field. We find that the efficiency of energy transfer depends dramatically on the input initial state of the system. Furthermore, we investigate the ability to extract the energy and to store it in a battery. This process is inefficient in optical cavities but is significantly enhanced when employing trapped Bose Einstein Condensates. Finally, we apply our techniques to a setup where an impinging gravitational wave excites the phononic modes of a Bose Einstein Condensate. We find that, in this case, the amount of energy transfer to the phonons increases with time and quickly approaches unity. These results suggest that, in the future, it might be possible to...
The case for hyperbolic theories of dissipation in relativistic fluids
Anile, A M; Romano, V; Anile, Angelo Marcello; Pavon, Diego; Romano, Vittorio
1998-01-01
In this paper we higlight the fact that the physical content of hyperbolic theories of relativistic dissipative fluids is, in general, much broader than that of the hyperbolic ones. This is substantiated by presenting an ample range of dissipative fluids whose behavior noticeably departs from Navier-Stokes.
The thermoelectric working fluid: Thermodynamics and transport
Benenti, Giuliano; Ouerdane, Henni; Goupil, Christophe
2016-12-01
Thermoelectric devices are heat engines, which operate as generators or refrigerators using the conduction electrons as a working fluid. The thermoelectric heat-to-work conversion efficiency has always been typically quite low, but much effort continues to be devoted to the design of new materials boasting improved transport properties that would make them of the electron crystal-phonon glass type of systems. On the other hand, there are comparatively few studies where a proper thermodynamic treatment of the electronic working fluid is proposed. The present article aims at contributing to bridge this gap by addressing both the thermodynamic and transport properties of the thermoelectric working fluid covering a variety of models, including interacting systems. xml:lang="fr"
Thermodynamics of Fluids Under Flow Second Edition
Jou, David; Criado-Sancho, Manuel
2011-01-01
This is the second edition of the book “Thermodynamics of Fluids under Flow,” which was published in 2000 and has now been corrected, expanded and updated. This is a companion book to our other title Extended irreversible thermodynamics (D. Jou, J. Casas-Vázquez and G. Lebon, Springer, 4th edition 2010), and of the textbook Understanding non-equilibrium thermodynamics (G. Lebon, D. Jou and J. Casas-Vázquez, Springer, 2008. The present book is more specialized than its counterpart, as it focuses its attention on the non-equilibrium thermodynamics of flowing fluids, incorporating non-trivial thermodynamic contributions of the flow, going beyond local equilibrium theories, i.e., including the effects of internal variables and of external forcing due to the flow. Whereas the book's first edition was much more focused on polymer solutions, with brief glimpses into ideal and real gases, the present edition covers a much wider variety of systems, such as: diluted and concentrated polymer solutions, polymer ble...
Relativistic Fluid Dynamics: Physics for Many Different Scales
Comer Gregory L.
2007-01-01
Full Text Available The relativistic fluid is a highly successful model used to describe the dynamics of many-particle, relativistic systems. It takes as input basic physics from microscopic scales and yields as output predictions of bulk, macroscopic motion. By inverting the process, an understanding of bulk features can lead to insight into physics on the microscopic scale. Relativistic fluids have been used to model systems as “small” as heavy ions in collisions, and as large as the Universe itself, with “intermediate” sized objects like neutron stars being considered along the way. The purpose of this review is to discuss the mathematical and theoretical physics underpinnings of the relativistic (multiple fluid model. We focus on the variational principle approach championed by Brandon Carter and his collaborators, in which a crucial element is to distinguish the momenta that are conjugate to the particle number density currents. This approach differs from the “standard” text-book derivation of the equations of motion from the divergence of the stress-energy tensor in that one explicitly obtains the relativistic Euler equation as an “integrability” condition on the relativistic vorticity. We discuss the conservation laws and the equations of motion in detail, and provide a number of (in our opinion interesting and relevant applications of the general theory.
Special-relativistic model flows of viscous fluid
Rogava, A D
1996-01-01
Two, the most simple cases of special-relativistic flows of a viscous, incompressible fluid are considered: plane Couette flow and plane Poiseuille flow. Considering only the regular motion of the fluid we found the distribution of velocity in the fluid (velocity profiles) and the friction force, acting on immovable wall. The results are expressed through simple analytical functions for the Couette flow, while for the Poiseiulle flow they are expressed by higher transcendental functions (Jacobi's elliptic functions).
General relativistic aspects of ferromagneto-fluid
Asgekar, G.G.; Patwardhan, C.G.
1988-03-01
The implications of Bianchi identities pertaining to the spacetime of relativistic ferrofluid with infinite conductivity and variable magnetic permeability are investigated. Some kinematical and dynamical corollaries emerging out of a preferred geometrical symmetry called an isometry with respect to the flow vector and the magnetic field vector are developed.
General relativistic aspects of ferromagneto-fluid.
Asgekar, G. G.; Patwardhan, C. G.
1988-03-01
The implications of Bianchi identities pertaining to the spacetime of relativistic ferrofluid with infinite conductivity and variable magnetic permeability are investigated. Some kinematical and dynamical corollaries emerging out of a preferred geometrical symmetry called an isometry with respect to the flow vector and the magnetic field vector are developed.
Instabilities in relativistic two-component (super)fluids
Haber, Alexander; Stetina, Stephan
2016-01-01
We study two-fluid systems with nonzero fluid velocities and compute their sound modes, which indicate various instabilities. For the case of two zero-temperature superfluids we employ a microscopic field-theoretical model of two coupled bosonic fields, including an entrainment coupling and a non-entrainment coupling. We analyse the onset of the various instabilities systematically and point out that the dynamical two-stream instability can only occur beyond Landau's critical velocity, i.e., in an already energetically unstable regime. A qualitative difference is found for the case of two normal fluids, where certain transverse modes suffer a two-stream instability in an energetically stable regime if there is entrainment between the fluids. Since we work in a fully relativistic setup, our results are very general and of potential relevance for (super)fluids in neutron stars and, in the non-relativistic limit of our results, in the laboratory.
Fields and fluids on curved non-relativistic spacetimes
Geracie, Michael; Roberts, Matthew M
2015-01-01
We consider non-relativistic curved geometries and argue that the background structure should be generalized from that considered in previous works. In this approach the derivative operator is defined by a Galilean spin connection valued in the Lie algebra of the Galilean group. This includes the usual spin connection plus an additional "boost connection" which parameterizes the freedom in the derivative operator not fixed by torsion or metric compatibility. As an example of this approach we develop the theory of non-relativistic dissipative fluids and find significant differences in both equations of motion and allowed transport coefficients from those found previously. Our approach also immediately generalizes to systems with independent mass and charge currents as would arise in multicomponent fluids. Along the way we also discuss how to write general locally Galilean invariant non-relativistic actions for multiple particle species at any order in derivatives. A detailed review of the geometry and its rela...
Entropy production for a relativistic simple fluid in a weak electromagnetic field
García-Perciante, A. L.; Sandoval-Villalbazo, A.; Brun-Battistini, D.
2016-11-01
Thermal dissipation in plasmas includes a variety of effects, most of them arising from the fact that these gases are usually composed of at least two species. In the case of a mild temperature single component charged fluid kinetic theory indicates that the temperature gradient is the only source of vector-type dissipation. However, if the temperature increases to a point in which the molecule's velocities approach the speed of light, electrothermal dissipation is possible even for the single component charged gas. The modification to the structure of the entropy production introduced by this effect is established in order to address the second law of thermodynamics for such a system. The entropy balance equation is obtained from the relativistic Boltzmann equation and the vector contribution to the entropy production is calculated in terms of the thermodynamic forces and the electromagnetic field using Chapman-Enskog's expansion. It is shown that the structure is consistent with the constitutive equation previously reported, in which a thermoelectric effect was found for a single component relativistic fluid. This effect does not have a non-relativistic counterpart and presents no ambiguity regarding the frame chosen as the comoving frame, which is an issue in the mixture case.
Relativistic thermodynamic properties of a weakly interacting Fermi gas in a weak magnetic field
Men Fu-Dian; Liu Hui; Fan Zhao-Lan; Zhu Hou-Yu
2009-01-01
This paper derives the analytical expression of free energy for a weakly interacting Fermi gas in a weak magnetic field, by using the methods of quantum statistics as well as considering the relativistic effect. Based on the derived expression, the thermodynamic properties of the system at both high and low temperatures are given and the relativistic effect on the properties of the system is discussed. It shows that, in comparison with a nonrelativistic situation,the relativistic effect changes the influence of temperature on the thermodynamic properties of the system at high temperatures, and changes the influence of particle-number density on them at extremely low temperature. But the relativistic effect does not change the influence of the magnetic field and inter-particle interactions on the thermodynamic properties of the system at both high and extremely low temperatures.
Thermodynamics phase changes of nanopore fluids
Islam, Akand W.
2015-07-01
The van der Waals (vdW) equation (Eq.) is modified to describe thermodynamic of phase behavior of fluids confined in nanopore. Our aim is to compute pressures exerted by the fluid molecules and to investigate how they change due to pore proximity by assuming the pore wall is inert. No additional scaling of model parameters is imposed and original volume and energy parameters are used in the calculations. Our results clearly show the phase changes due to confinement. The critical shifts of temperatures and pressures are in good agreement compared to the laboratory data and molecular simulation. Peng-Robinson (PR) equation-of-state (EOS) has resulted in different effect than the vdW. This work delivers insights into the nature of fluid behavior in extremely low-permeability nanoporous media, especially in the tight shale reservoirs, below the critical temperatures. © 2015 Elsevier B.V.
International thermodynamic tables of the fluid state propylene (propene)
Angus, S; De Reuck, K M
2013-01-01
International Thermodynamic Tables of the Fluid State - 7 Propylene (Propene) is a compilation of internationally agreed values of the equilibrium thermodynamic properties of propylene. This book is composed of three chapters, and begins with the presentation of experimental result of thermodynamic studies compared with the equations used to generate the tables. The succeeding chapter deals with correlating equations for thermodynamic property determination of propylene. The last chapter provides the tabulations of the propylene's thermodynamic properties and constants. This book will prove
Relativistic Quantum Thermodynamics of Ideal Gases in 2 Dimensions
Blas, H.; Pimentel, B. M.; Tomazelli, J. L.
1999-01-01
In this work we study the behavior of relativistic ideal Bose and Fermi gases in two space dimensions. Making use of polylogarithm functions we derive a closed and unified expression for their densities. It is shown that both type of gases are essentially inequivalent, and only in the non-relativistic limit the spinless and equal mass Bose and Fermi gases are equivalent as known in the literature.
Relativistic quantum thermodynamics of ideal gases in two dimensions.
Blas, H; Pimentel, B M; Tomazelli, J L
1999-11-01
In this work we study the behavior of relativistic ideal Bose and Fermi gases in two space dimensions. Making use of polylogarithm functions we derive a closed and unified expression for their densities. It is shown that both type of gases are essentially inequivalent, and only in the non-relativistic limit the spinless and equal mass Bose and Fermi gases are equivalent as known in the literature.
Thermodynamics of relativistic Newton—Wigner particle in external potential field
Larkin, A. S.; Filinov, V. S.
2015-11-01
Thermodynamic properties of relativistic spinless particle described by the Klein-Gordon equation have been studied using the Newton-Wigner theory of particle in external potential field. Concept of Wiener path integral was extended on relativistic case. A new path integral Monte-Carlo method was developed for relativistic particle in external potential field. The bounds of applicability of available analytical approaches and related results have been specified by comparison with Monte-Carlo calculations. Developed path integral formalism can be directly extended on systems of many identical Newton-Wigner particles, which interact with external field and each other.
Relativistic temperature and Higgs-like coupling of thermodynamic interactions
JIANG Wei-zhou
2006-01-01
The thermodynamic interaction at thermodynamic equilibrium in the free fermion gas is described in an alternative way by the coupling of particles with a scalar thermodynamic field that features self-interaction.This alternative coupling is similar to the Higgs coupling and is helpful in understanding the temperature transformation at thermodynamic equilibrium under the Lorentz boost.As this coupling is applied in the abelian interaction fermion gas,nothing nontrivial is obtained.However,an interesting thing happens in the nonabelian interaction fermion gas where the difference appears for the diagonal and off-diagonal intermediate bosons as the Higgs-like coupling is added.
Relativistic vortex dynamics in axisymmetric stationary perfect fluid configuration
Prasad, G.
2017-06-01
Relativistic formulation of Helmholtz's vorticity transport equation is presented on the basis of Maxwell-like version of Euler's equation of motion. Entangled characteristics associated with vorticity flux conservation in a vortex tube and in a stream tube are displayed on basis of Greenberg's theory of spacelike congruence of vortex lines and 1+1+(2) decomposition of the gradient of fluid's 4-velocity. Vorticity flux surfaces are surfaces of revolution about the rotation axis and are rotating with fluid's angular velocity due to gravitational isorotation in a stationary axisymmetric perfect fluid configuration. Fluid's angular velocity, angular momentum per baryon, injection energy, and invariant rotational potential are constant on such vorticity flux surfaces. Gravitation causes distortion of coaxial cylindrical vorticity flux surfaces in the limit of post-Newtonian approximation. The rotation of the fluid with angular velocity relative to vorticity flux surfaces generates swirl which causes the stretching of material vortex lines being wrapped on vorticity flux surfaces. Fluid helicity which is conserved in the fluid's rest frame does not remain conserved in a locally nonrotating frame because of the existence of swirl. Vortex lines are twist free in the absence of meridional circulations, but the twisting of spacetime due to dragging effect leads to the increase in vorticity flux in a vortex tube.
Vacaru, Olivia
2013-01-01
Using $3+1$ spacetime fibrations on Lorentz manifolds, we define an analogous W--entropy for gravitational fields. Such F- and W-functionals were introduced in the Ricci flow theory of three dimensional Riemannian metrics by G. Perelman, arXiv: math.DG/0211159. The main goal of this paper is to solve and study one of the mentioned there problems: how associated statistical thermodynamical functions could reproduce in a relativistic manner the black hole thermodynamics and, in a more general context, provide a thermodynamic description of gravitational interactions? In our approach, the gravitational W--entropy characterizes the geometric evolution of three dimensional (3-d) hypersurface metrics nonoholonomically imbedded into certain classes of 4-d solutions of gravitational field equations. A geometric method for generating generic off-diagonal exact solutions for Einstein manifolds of pseudo-Euclidean signature determined by relativistic Ricci flow evolution of 3-d Riemannian metrics is applied. To relate s...
Relativistic thermodynamics, a Lagrangian field theory for general flows including rotation
Frønsdal, Christian
Any theory that is based on an action principle has a much greater predictive power than one that does not have such a formulation. The formulation of a dynamical theory of General Relativity, including matter, is here viewed as a problem of coupling Einstein’s theory of pure gravity to an independently chosen and well-defined field theory of matter. It is well known that this is accomplished in a most natural way when both theories are formulated as relativistic, Lagrangian field theories, as is the case with Einstein-Maxwell theory. Special matter models of this type have been available; here a more general thermodynamical model that allows for vortex flows is presented. In a wider context, the problem of subjecting hydrodynamics and thermodynamics to an action principle is one that has been pursued for at least 150 years. A solution to this problem has been known for some time, but only under the strong restriction to potential flows. A variational principle for general flows has become available. It represents a development of the Navier-Stokes-Fourier approach to fluid dynamics. The principal innovation is the recognition that two kinds of flow velocity fields are needed, one the gradient of a scalar field and the other the time derivative of a vector field, the latter closely associated with vorticity. In the relativistic theory that is presented here, the latter is the Hodge dual of an exact 3-form, well known as the notoph field of Ogievetskij and Palubarinov, the B-field of Kalb and Ramond and the vorticity field of Lund and Regge. The total number of degrees of freedom of a unary system, including the density and the two velocity fields is 4, as expected — as in classical hydrodynamics. In this paper, we do not reduce Einstein’s dynamical equation for the metric to phenomenology, which would have denied the relevance of any intrinsic dynamics for the matter sector, nor do we abandon the equation of continuity - the very soul of hydrodynamics.
International thermodynamic tables of the fluid state helium-4
Angus, S; McCarty, R D
2013-01-01
International Thermodynamic Tables of the Fluid State Helium-4 presents the IUPAC Thermodynamic Tables for the thermodynamic properties of helium. The IUPAC Thermodynamic Tables Project has therefore encouraged the critical analysis of the available thermodynamic measurements for helium and their synthesis into tables. This book is divided into three chapters. The first chapter discusses the experimental results and compares with the equations used to generate the tables. These equations are supplemented by a vapor pressure equation, which represents the 1958 He-4 scale of temperature that is
Modelling general relativistic perfect fluids in field theoretic language
Mitskievich, N V
1999-01-01
Skew-symmetric massless fields, their potentials being $r$-forms, are close analogues of Maxwell's field (though the non-linear cases also should be considered). We observe that only two of them ($r=$2 and 3) automatically yield stress-energy tensors characteristic to normal perfect fluids. It is shown that they naturally describe both non-rotating ($r=2$) and rotating (then a combination of $r=2$ and $r=3$ fields is indispensable) general relativistic perfect fluids possessing every type of equations of state. Meanwile, a free $r=3$ field is completely equivalent to appearance of the cosmological term in Einstein's equations. Sound waves represent perturbations propagating on the background of the $r=2$ field. Some exotic properties of these two fields are outlined.
grim: A Flexible, Conservative Scheme for Relativistic Fluid Theories
Chandra, Mani; Foucart, Francois; Gammie, Charles F.
2017-03-01
Hot, diffuse, relativistic plasmas such as sub-Eddington black-hole accretion flows are expected to be collisionless, yet are commonly modeled as a fluid using ideal general relativistic magnetohydrodynamics (GRMHD). Dissipative effects such as heat conduction and viscosity can be important in a collisionless plasma and will potentially alter the dynamics and radiative properties of the flow from that in ideal fluid models; we refer to models that include these processes as Extended GRMHD. Here we describe a new conservative code, grim, that enables all of the above and additional physics to be efficiently incorporated. grim combines time evolution and primitive variable inversion needed for conservative schemes into a single step using an algorithm that only requires the residuals of the governing equations as inputs. This algorithm enables the code to be physics agnostic as well as flexibility regarding time-stepping schemes. grim runs on CPUs, as well as on GPUs, using the same code. We formulate a performance model and use it to show that our implementation runs optimally on both architectures. grim correctly captures classical GRMHD test problems as well as a new suite of linear and nonlinear test problems with anisotropic conduction and viscosity in special and general relativity. As tests and example applications, we resolve the shock substructure due to the presence of dissipation, and report on relativistic versions of the magneto-thermal instability and heat flux driven buoyancy instability, which arise due to anisotropic heat conduction, and of the firehose instability, which occurs due to anisotropic pressure (i.e., viscosity). Finally, we show an example integration of an accretion flow around a Kerr black hole, using Extended GRMHD.
Ideal relativistic fluid limit for a medium with polarization
Montenegro, David; Tinti, Leonardo; Torrieri, Giorgio
2017-09-01
We use Lagrangian effective field theory techniques to construct the equations of motion for an ideal relativistic fluid of which the constituent degrees of freedom have microscopic polarization. We discuss the meaning of such a system and argue that it is the first term in the Effective Field Theory (EFT) appropriate for describing polarization observables in heavy ion collisions, such as final-state particle polarization and chiral magnetic and vortaic effects. We show that this system will generally require nondissipative dynamics at higher order in the gradient than second order, leading to potential stability issues known with such systems. We comment on the significance of this in the light of conjectured lower limits on viscosity.
Effects of smooth random surface on fluid monolayer thermodynamics
Khlyupin, A. N.
2016-11-01
We consider the lattice gas approach to statistical mechanics of fluid adsorbed on random surfaces with fluid-fluid and fluid-surface potentials. It was shown that effective Hamiltonian contains quenched random interactions and random site fields. Their statistical features combine the properties of random geometry and fluid-fluid pair interaction potential. The high-temperature expansion leads to infinite-ranged random field model and Sherrington-Kirkpatrick spin-glass model. Thermodynamic properties are evaluated using replica theory procedure widely used to analyze quenched disorder systems. On the other hand we consider the random field model in random graph with finite connectivity instead of previous “infinite-ranged” approximations. This model has been investigated using finite connectivity technique. The replica symmetry ansatz for the order function is expressed in terms of an effective-field distribution. Analysis of random geometry effects on thermodynamic properties in such approach was done for the first time.
Light scattering test regarding the relativistic nature of heat
Sandoval-Villalbazo, A
2006-01-01
The dynamic structure factor of a simple relativistic fluid is calculated. The coupling of acceleration with the heat flux present in Eckart's version of irreversible relativistic thermodynamics is examined using the Rayleigh-Brillouin spectrum of the fluid. A modification of the width of the Rayleigh peak associated to Eckart's picture of the relativistic nature of heat is predicted and estimated.
Light scattering test regarding the relativistic nature of heat
2005-01-01
The dynamic structure factor of a simple relativistic fluid is calculated. The coupling of acceleration with the heat flux present in Eckart's version of irreversible relativistic thermodynamics is examined using the Rayleigh-Brillouin spectrum of the fluid. A modification of the width of the Rayleigh peak associated to Eckart's picture of the relativistic nature of heat is predicted and estimated.
Supercritical fluid thermodynamics for coal processing
van Swol, F. (Illinois Univ., Urbana, IL (United States). Dept. of Chemical Engineering); Eckert, C.A. (Georgia Inst. of Tech., Atlanta, GA (United States). School of Chemical Engineering)
1988-09-15
The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)
Thermodynamics of Angular Propulsion in Fluids
Polihronov, Jeliazko G.; Straatman, Anthony G.
2012-08-01
The presented study examines the energetics of confined fluid flow in a rotating reference frame. Parallels are drawn to the corresponding scenario of rectilinear motion, where ejection of fluid results in linear propulsion of the frame. Absorption of flow energy into the frame motion leads to cooling of the ejected fluid. Relevance of the observed energetics to the temperature separation phenomenon in Ranque-Hilsch vortex tubes is discussed.
Abstract composition rule for relativistic kinetic energy in the thermodynamical limit
Biro, T S
2008-01-01
We demonstrate by simple mathematical considerations that a power-law tailed distribution in the kinetic energy of relativistic particles can be a limiting distribution seen in relativistic heavy ion experiments. We prove that the infinite repetition of an arbitrary composition rule on an infinitesimal amount leads to a rule with a formal logarithm. As a consequence the stationary distribution of energy in the thermodynamical limit follows the composed function of the Boltzmann-Gibbs exponential with this formal logarithm. In particular, interactions described as solely functions of the relative four-momentum squared lead to kinetic energy distributions of the Tsallis-Pareto (cut power-law) form in the high energy limit.
Garcia-Perciante, A L; Brun-Battistini, D; Sandoval-Villalbazo, A
2014-01-01
Extended theories are widely used in the literature to describe relativistic fluids. The motivation for this is mostly due to the causality issues allegedly present in the first order in the gradients theories. However, the decay of fluctuations in the system is also at stake when first order theories that couple heat with acceleration are used. This paper shows that although the introduction of the Maxwell-Cattaneo equation in the description of a simple relativistic fluid formally eliminates the generic instabilities identified by Hiscock and Lindblom in 1985, the hypothesis on the order of magnitude of the corresponding relaxation term contradicts the basic ordering in Knudsen's parameter present in the kinetic approach to hydrodynamics. It is shown that the time derivative, stabilizing term is of second order in such parameter and thus does not belong to the Navier-Stokes regime where the so-called instability arises.
Charged relativistic fluids and non-linear electrodynamics
Dereli, T.; Tucker, R. W.
2010-01-01
The electromagnetic fields in Maxwell's theory satisfy linear equations in the classical vacuum. This is modified in classical non-linear electrodynamic theories. To date there has been little experimental evidence that any of these modified theories are tenable. However with the advent of high-intensity lasers and powerful laboratory magnetic fields this situation may be changing. We argue that an approach involving the self-consistent relativistic motion of a smooth fluid-like distribution of matter (composed of a large number of charged or neutral particles) in an electromagnetic field offers a viable theoretical framework in which to explore the experimental consequences of non-linear electrodynamics. We construct such a model based on the theory of Born and Infeld and suggest that a simple laboratory experiment involving the propagation of light in a static magnetic field could be used to place bounds on the fundamental coupling in that theory. Such a framework has many applications including a new description of the motion of particles in modern accelerators and plasmas as well as phenomena in astrophysical contexts such as in the environment of magnetars, quasars and gamma-ray bursts.
Computer program for calculating thermodynamic and transport properties of fluids
Hendricks, R. C.; Braon, A. K.; Peller, I. C.
1975-01-01
Computer code has been developed to provide thermodynamic and transport properties of liquid argon, carbon dioxide, carbon monoxide, fluorine, helium, methane, neon, nitrogen, oxygen, and parahydrogen. Equation of state and transport coefficients are updated and other fluids added as new material becomes available.
PREDICTION OF THERMODYNAMIC PROPERTIES OF COMPLEX FLUIDS
Marc Donohue
2006-01-05
ABSTRACT The goal of this research has been to generalize Density Functional Theory (DFT) for complex molecules, i.e. molecules whose size, shape, and interaction energies cause them to show significant deviations from mean-field behavior. We considered free energy functionals and minimized them for systems with different geometries and dimensionalities including confined fluids (such as molecular layers on surfaces and molecules in nano-scale pores), systems with directional interactions and order-disorder transitions, amphiphilic dimers, block copolymers, and self-assembled nano-structures. The results of this procedure include equations of equilibrium for these systems and the development of computational tools for predicting phase transitions and self-assembly in complex fluids. DFT was developed for confined fluids. A new phenomenon, surface compression of confined fluids, was predicted theoretically and confirmed by existing experimental data and by simulations. The strong attraction to a surface causes adsorbate molecules to attain much higher densities than that of a normal liquid. Under these conditions, adsorbate molecules are so compressed that they repel each other. This phenomenon is discussed in terms of experimental data, results of Monte Carlo simulations, and theoretical models. Lattice version of DFT was developed for modeling phase transitions in adsorbed phase including wetting, capillary condensation, and ordering. Phase behavior of amphiphilic dimers on surfaces and in solutions was modeled using lattice DFT and Monte Carlo simulations. This study resulted in predictive models for adsorption isotherms and for local density distributions in solutions. We have observed a wide variety of phase behavior for amphiphilic dimers, including formation of lamellae and micelles. Block copolymers were modeled in terms of configurational probabilities and in the approximation of random mixing entropy. Probabilities of different orientations for the
The Thermodynamical Instability Induced by Pressure Ionization in Fluid Helium
Li, Qiong; Zhang, Gong-Mu; Zhao, Yan-Hong; Lu, Guo; Tian, Ming-Feng; Song, Hai-Feng
2016-01-01
A systematic study of pressure ionization is carried out in the chemical picture by the example of fluid helium. By comparing the variants of the chemical model, it is demonstrated that the behavior of pressure ionization depends on the construction of the free energy function. In the chemical model with the Coulomb free energy described by the Pad\\'e interpolation formula, thermodynamical instability induced by pressure ionization is found to be manifested by a discontinuous drop or a continuous fall and rise along the pressure-density curve as well as the pressure-temperature curve, which is very much like the first order liquid-liquid phase transition of fluid hydrogen from the first principles simulations. In contrast, in the variant chemical model with the Coulomb free energy term empirically weakened, no thermodynamical instability is induced when pressure ionization occurs, and the resulting equation of state achieves good agreement with the first principles simulations of fluid helium.
Perturbation theories for the thermodynamic properties of fluids and solids
Solana, J R
2013-01-01
This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories-as well as integral equation theories and density functional theories-for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, i
Continuum thermodynamics of chemically reacting fluid mixtures
Bothe, Dieter
2014-01-01
We consider viscous and heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, a first main aim is the derivation of a closed system of partial mass and partial momentum balances plus a common balance of internal energy. This is achieved by careful exploitation of the entropy principle which, in particular, requires appropriate definitions of absolute temperature and chemical potentials based on an adequate definition of thermal energy that excludes diffusive contributions. The latter is crucial in order to obtain a closure framework for the interaction forces between the different species. The interaction forces split into a thermo-mechanical and a chemical part, where the former turns out to be symmetric if binary interactions are assumed. In the non-reactive case, this leads to a system of Navier-Stokes type sub-systems, coupled by interspecies friction forces. For chemical...
Intermolecular interactions and the thermodynamic properties of supercritical fluids.
Yigzawe, Tesfaye M; Sadus, Richard J
2013-05-21
The role of different contributions to intermolecular interactions on the thermodynamic properties of supercritical fluids is investigated. Molecular dynamics simulation results are reported for the energy, pressure, thermal pressure coefficient, thermal expansion coefficient, isothermal and adiabatic compressibilities, isobaric and isochoric heat capacities, Joule-Thomson coefficient, and speed of sound of fluids interacting via both the Lennard-Jones and Weeks-Chandler-Andersen potentials. These properties were obtained for a wide range of temperatures, pressures, and densities. For each thermodynamic property, an excess value is determined to distinguish between attraction and repulsion. It is found that the contributions of intermolecular interactions have varying effects depending on the thermodynamic property. The maxima exhibited by the isochoric and isobaric heat capacities, isothermal compressibilities, and thermal expansion coefficient are attributed to interactions in the Lennard-Jones well. Repulsion is required to obtain physically realistic speeds of sound and both repulsion and attraction are necessary to observe a Joule-Thomson inversion curve. Significantly, both maxima and minima are observed for the isobaric and isochoric heat capacities of the supercritical Lennard-Jones fluid. It is postulated that the loci of these maxima and minima converge to a common point via the same power law relationship as the phase coexistence curve with an exponent of β = 0.32. This provides an explanation for the terminal isobaric heat capacity maximum in supercritical fluids.
Thermodynamic optimization of fluid flow over an isothermal moving plate
A. Malvandi
2013-09-01
Full Text Available In this paper, entropy generation minimization (EGM was employed in order to achieve a thermodynamic optimization of fluid flow and heat transfer over a flat plate. The basic boundary layer equations including continuity, momentum, energy, and entropy generation have been reduced to a two-point boundary value problem via similarity variables and solved numerically via Runge–Kutta–Fehlberg scheme. The novelty of this study was to consider the effects of velocity ratio λ – which represents the ratio of the wall velocity to the free stream fluid velocity – in a thermodynamic system. Focusing on the velocity ratio as a pivotal parameter, in view of minimizing the entropy generation, the optimum value of λ=λo was achieved. Moreover, considering Bejan number, it was shown that the region, in which the maximum entropy generates, gets closer to the plate as λ increases.
Molecular Thermodynamics of Charged Hard-Dumbbell Fluids
秦原; 刘洪来; 胡英
2001-01-01
Chemical potentials of charged hard-dumbbell fluids are obtained by Monte Carlo simulations using Widom's test-particle method, corresponding compressibility factors are achieved by integration of chemical potentials at different densities. A molecular thermodynamic model is also developed for these charged hard-dumbbell fluids where the residual Helmholtz function is composed of two terms: a reference term responsible for the charged hard spheres and a bonding contribution measuring the sticky interactions between positive and negative hard ions.Model predictions are in good agreement with simulation results.
Kaluza-Klein reduction of relativistic fluids and their gravity duals
Di Dato, Adriana
2013-01-01
We study the hydrodynamics of relativistic fluids with several conserved global charges (i.e., several species of particles) by performing a Kaluza-Klein dimensional reduction of a neutral fluid on a N-torus. Via fluid/gravity correspondence, this allows us to describe the long-wavelength dynamics of black branes with several Kaluza-Klein charges. We obtain the equation of state and transport coefficients of the charged fluid directly from those of the higher-dimensional neutral fluid. We specialize these results for the fluids dual to Kaluza-Klein black branes.
Waves in General Relativistic Two-fluid Plasma around a Schwarzschild Black Hole
Rahman, M Atiqur
2010-01-01
Waves propagating in the relativistic electron-positron or ions plasma are investigated in a frame of two-fluid equations using the 3+1 formalism of general relativity developed by Thorne, Price and Macdonald (TPM). The plasma is assumed to be freefalling in the radial direction toward the event horizon due to the strong gravitational field of a Schwarzschild black hole. The local dispersion relations for transverse and longitudinal waves have been derived, in analogy with the special relativistic formulation as explained in an earlier paper, to take account of relativistic effects due to the event horizon using WKB approximation
Structure and thermodynamics of hard-core Yukawa fluids: thermodynamic perturbation approaches.
Kim, Eun-Young; Kim, Soon-Chul; Seong, Baek-Seok
2011-07-21
The thermodynamic perturbation theories, which are based on the power series of a coupling constant (λ-expansion), have been proposed for studying the structural and thermodynamic properties of a hard-core Yukawa (HCY) fluid: one (A1-approximation) is the perturbation theory based on the hard-sphere repulsion as a reference system. The other (A2-approximation) is the perturbation theory based on the reference system which incorporates both the repulsive and short-range attractive interactions. The first-order mean-spherical approximation (FMSA) provided by Tang and Lu [J. Chem. Phys. 99, 9828 (1993)] has been employed for investigating the thermodynamic properties of a HCY fluid using the alternative method via the direct correlation function. The calculated results show that (i) the A1 and A2 approximations are in excellent agreements with previous computer simulation results in the literature and compare with the semi-empirical works of Shukla including the higher-order free energy terms, (ii) the A1 and A2 approximations are better than the FMSA and the mean-spherical approximation, (iii) the A2-approximation compares with the A1-approximation, even though the perturbation effect of an A2-approximation is much smaller than that of an A1-approximation, and that (iv) the FMSA study is particularly of advantage in providing the structure and thermodynamics in a simple and analytic manner.
Amano, Takanobu
2016-01-01
A new multidimensional simulation code for relativistic two-fluid electrodynamics (RTFED) is described. The basic equations consist of the full set of Maxwell's equations coupled with relativistic hydrodynamic equations for separate two charged fluids, representing the dynamics of either an electron-positron or an electron-proton plasma. It can be recognized as an extension of conventional relativistic magnetohydrodynamics (RMHD). Finite resistivity may be introduced as a friction between the two species, which reduces to resistive RMHD in the long wavelength limit without suffering from a singularity at infinite conductivity. A numerical scheme based on HLL (Harten-Lax-Van Leer) Riemann solver is proposed that exactly preserves the two divergence constraints for Maxwell's equations simultaneously. Several benchmark problems demonstrate that it is capable of describing RMHD shocks/discontinuities at long wavelength limit, as well as dispersive characteristics due to the two-fluid effect appearing at small sca...
Thermodynamic Behavior of a Perfect Fluid with Negative Energy Density
Christensen, W
2005-01-01
Starting from a perfect cosmolgical fluid, one class of frequency metrics that satisfies both Einstein's General Relativitic equation and the perfect fluid condition is: g_uv = e^iwt N_uv. Such a metric indicates spacetime behaves locally like a simple harmonic oscillator. During spacetime compressions and rarefactions particles are exuded with a mass equal to the compressive work that produced them. They comprise the cosmic dark matter that makes up this perfect fluid. By treating spacetime as a classical thermodynamic problem, the mass of these particles is determined to be in the range of an axion particle sought by the Lawrence Livermore National Laboratory. When axion particles collide they give off a photon having a microwave frequency inversely equal to that of the frequency of the spacetime compression that produced them. These microwave photons make up the 2.7K cosmic background radiation.
INVERSE CASCADE OF NONHELICAL MAGNETIC TURBULENCE IN A RELATIVISTIC FLUID
Zrake, Jonathan [Kavli Institute for Particle Astrophysics and Cosmology, Stanford University, Menlo Park, CA 94025 (United States)
2014-10-20
The free decay of nonhelical relativistic magnetohydrodynamic turbulence is studied numerically, and found to exhibit cascading of magnetic energy toward large scales. Evolution of the magnetic energy spectrum P{sub M} (k, t) is self-similar in time and well modeled by a broken power law with subinertial and inertial range indices very close to 7/2 and –2, respectively. The magnetic coherence scale is found to grow in time as t {sup 2/5}, much too slow to account for optical polarization of gamma-ray burst afterglow emission if magnetic energy is to be supplied only at microphysical length scales. No bursty or explosive energy loss is observed in relativistic MHD turbulence having modest magnetization, which constrains magnetic reconnection models for rapid time variability of GRB prompt emission, blazars, and the Crab nebula.
Resistive relativistic magnetohydrodynamics from a charged multi-fluids perspective
Andersson, N
2012-01-01
We consider general relativistic magnetohydrodynamics from a charged multifluids point-of-view, taking a variational approach as our starting point. We develop the case of two charged components in detail, accounting for a phenomenological resistivity, providing specific examples for pair plasmas and proton-electron systems. We discuss both cold, low velocity, plasmas and hot systems where we account for a dynamical entropy component. The results for the cold case (which accord with recent work in the literature) provide a complete model for resistive relativistic magnetohydrodynamics, clarifying the assumptions that lead to various models that have been used in astrophysical applications. The analysis of the hot case is (as far as we are aware) novel, accounting for the relaxation times that are required to ensure causality and demonstrating the explicit coupling between fluxes of heat and charge.
Massively parallel simulations of relativistic fluid dynamics on graphics processing units with CUDA
Bazow, Dennis; Strickland, Michael
2016-01-01
Relativistic fluid dynamics is a major component in dynamical simulations of the quark-gluon plasma created in relativistic heavy-ion collisions. Simulations of the full three-dimensional dissipative dynamics of the quark-gluon plasma with fluctuating initial conditions are computationally expensive and typically require some degree of parallelization. In this paper, we present a GPU implementation of the Kurganov-Tadmor algorithm which solves the 3+1d relativistic viscous hydrodynamics equations including the effects of both bulk and shear viscosities. We demonstrate that the resulting CUDA-based GPU code is approximately two orders of magnitude faster than the corresponding serial implementation of the Kurganov-Tadmor algorithm. We validate the code using (semi-)analytic tests such as the relativistic shock-tube and Gubser flow.
New Developments in Relativistic Viscous Hydrodynamics
Romatschke, Paul
2009-01-01
Starting with a brief introduction into the basics of relativistic fluid dynamics, I discuss our current knowledge of a relativistic theory of fluid dynamics in the presence of (mostly shear) viscosity. Derivations based on the generalized second law of thermodynamics, kinetic theory, and a complete second-order gradient expansion are reviewed. The resulting fluid dynamic equations are shown to be consistent for all these derivations, when properly accounting for the respective region of appl...
Chlorine international thermodynamic tables of the fluid state
Angus, S; de Reuck, K M
1985-01-01
Chlorine: International Thermodynamic Tables of the Fluid State-8 is a four-chapter book that covers available and estimated data on chlorine; estimation of the element's properties; the correlating equations for the element; and how the tabulated properties are calculated from chosen equation. The tables in this book give the volume, entropy, enthalpy, isobaric heat capacity, compression factor, fugacity/pressure ratio, Joule-Thomson coefficient, ratio of the heat capacities, and speed of sound as a function of pressure and temperature. Given in the tables as well are the pressure, entropy, i
A Dynamical Approach to the Exterior Geometry of a Perfect Fluid as a Relativistic Star
Fathi, Mohsen
2011-01-01
The aim of this article is to compare some of the solution classes, which were presented for a perfect charged fluid in Ref. [8], through studying the motion of a test charged particle on a relativistic charged star. We will show that how the interior solutions of such star, can affect its exterior geometry, by illustrating the corresponding effective potentials.
Fluid physics, thermodynamics, and heat transfer experiments in space
Dodge, F. T.; Abramson, H. N.; Angrist, S. W.; Catton, I.; Churchill, S. W.; Mannheimer, R. J.; Otrach, S.; Schwartz, S. H.; Sengers, J. V.
1975-01-01
An overstudy committee was formed to study and recommend fundamental experiments in fluid physics, thermodynamics, and heat transfer for experimentation in orbit, using the space shuttle system and a space laboratory. The space environment, particularly the low-gravity condition, is an indispensable requirement for all the recommended experiments. The experiments fell broadly into five groups: critical-point thermophysical phenomena, fluid surface dynamics and capillarity, convection at reduced gravity, non-heated multiphase mixtures, and multiphase heat transfer. The Committee attempted to assess the effects of g-jitter and other perturbations of the gravitational field on the conduct of the experiments. A series of ground-based experiments are recommended to define some of the phenomena and to develop reliable instrumentation.
Open/closed string duality and relativistic fluids
Niarchos, Vasilis
2016-07-01
We propose an open/closed string duality in general backgrounds extending previous ideas about open string completeness by Ashoke Sen. Our proposal sets up a general version of holography that works in gravity as a tomographic principle. We argue, in particular, that previous expectations of a supergravity/Dirac-Born-Infeld (DBI) correspondence are naturally embedded in this conjecture and can be tested in a well-defined manner. As an example, we consider the correspondence between open string field theories on extremal D-brane setups in flat space in the large-N , large 't Hooft limit, and asymptotically flat solutions in ten-dimensional type II supergravity. We focus on a convenient long-wavelength regime, where specific effects of higher-spin open string modes can be traced explicitly in the dual supergravity computation. For instance, in this regime we show how the full Abelian DBI action arises from supergravity as a straightforward reformulation of relativistic hydrodynamics. In the example of a (2 +1 )-dimensional open string theory this reformulation involves an Abelian Hodge duality. We also point out how different deformations of the DBI action, related to higher-derivative corrections and non-Abelian effects, can arise in this context as deformations in corresponding relativistic hydrodynamics.
Vacaru, Olivia [National College of Iasi (Romania); Vacaru, Sergiu I. [Quantum Gravity Research, Topanga, CA (United States); University ' ' Al.I. Cuza' ' Iasi, Project IDEI, Iasi (Romania); Werner-Heisenberg-Institute, Max-Planck-Institute for Physics, Munich (Germany); Leibniz University of Hannover, Institute for Theoretical Physics (Germany); Ruchin, Vyacheslav
2017-03-15
Using double 2 + 2 and 3 + 1 nonholonomic fibrations on Lorentz manifolds, we extend the concept of W-entropy for gravitational fields in general relativity (GR). Such F- and W-functionals were introduced in the Ricci flow theory of three dimensional (3-d) Riemannian metrics by Perelman (the entropy formula for the Ricci flow and its geometric applications. arXiv:math.DG/0211159). Non-relativistic 3-d Ricci flows are characterized by associated statistical thermodynamical values determined by W-entropy. Generalizations for geometric flows of 4-d pseudo-Riemannian metrics are considered for models with local thermodynamical equilibrium and separation of dissipative and non-dissipative processes in relativistic hydrodynamics. The approach is elaborated in the framework of classical field theories (relativistic continuum and hydrodynamic models) without an underlying kinetic description, which will be elaborated in other work. The 3 + 1 splitting allows us to provide a general relativistic definition of gravitational entropy in the Lyapunov-Perelman sense. It increases monotonically as structure forms in the Universe. We can formulate a thermodynamic description of exact solutions in GR depending, in general, on all spacetime coordinates. A corresponding 2 + 2 splitting with nonholonomic deformation of linear connection and frame structures is necessary for generating in very general form various classes of exact solutions of the Einstein and general relativistic geometric flow equations. Finally, we speculate on physical macrostates and microstate interpretations of the W-entropy in GR, geometric flow theories and possible connections to string theory (a second unsolved problem also contained in Perelman's work) in Polyakov's approach. (orig.)
Fluid-magnetic helicity in axisymmetric stationary relativistic magnetohydrodynamics
Prasad, G.
2017-10-01
The present work is intended to gain a fruitful insight into the understanding of the formations of magneto-vortex configurations and their role in the physical processes of mutual exchange of energies associated with fluid's motion and the magnetic fields in an axisymmetric stationary hydromagnetic system subject to strong gravitational field (e.g., neutron star/magnetar). It is found that the vorticity flux vector field associated with vorticity 2-form is a linear combination of fluid's vorticity vector and of magnetic vorticity vector. The vorticity flux vector obeys Helmholtz's flux conservation. The energy equation associated with the vorticity flux vector field is deduced. It is shown that the mechanical rotation of vorticity flux surfaces contributes to the formation of vorticity flux vector field. The dynamo action for the generation of toroidal components of vorticity flux vector field is described in the presence of meridional circulations. It is shown that the stretching of twisting magnetic lines due to differential rotation leads to the breakdown of gravitational isorotation in the absence of meridional circulations. An explicit expression consists of rotation of vorticity flux surface, energy and angular momentum per baryon for the fluid-magnetic helicity current vector is obtained. The conservation of fluid-magnetic helicity is demonstrated. It is found that the fluid-magnetic helicity displays the energy spectrum arising due to the interaction between the mechanical rotation of vorticity flux surfaces and the fluid's motion obeying Euler's equations. The dissipation of a linear combination of modified fluid helicity and magnetic twist is shown to occur due to coupled effect of frame dragging and meridional circulation. It is found that the growing twist of magnetic lines causes the dissipation of modified fluid helicity in the absence of meridional circulations.
Solutions of Conformal Israel-Stewart Relativistic Viscous Fluid Dynamics
Marrochio, Hugo; Denicol, Gabriel S; Luzum, Matthew; Jeon, Sangyong; Gale, Charles
2013-01-01
We use symmetry arguments developed by Gubser to construct the first radially-expanding explicit solutions of the Israel-Stewart formulation of hydrodynamics. Along with a general semi-analytical solution, an exact analytical solution is given which is valid in the cold plasma limit where viscous effects from shear viscosity and the relaxation time coefficient are important. The radially expanding solutions presented in this paper can be used as nontrivial checks of numerical algorithms employed in hydrodynamic simulations of the quark-gluon plasma formed in ultra-relativistic heavy ion collisions. We show this explicitly by comparing such analytic and semi-analytic solutions with the corresponding numerical solutions obtained using the MUSIC viscous hydrodynamics simulation code.
Open/closed string duality and relativistic fluids
Niarchos, Vasilis
2015-01-01
We propose an open/closed string duality in general backgrounds extending previous ideas about open string completeness by Ashoke Sen. Our proposal sets up a general version of holography that works in gravity as a tomographic principle. We argue, in particular, that previous expectations of a supergravity/Dirac-Born-Infeld (DBI) correspondence are naturally embedded in this conjecture and can be tested in a well-defined manner. As an example, we consider the correspondence between open string field theories on extremal D-brane setups in flat space in the large-N, large 't Hooft limit, and asymptotically flat solutions in ten-dimensional type II supergravity. We focus on a convenient long-wavelength regime, where specific effects of higher-spin open string modes can be traced explicitly in the dual supergravity computation. For instance, in this regime we show how the full abelian DBI action arises from supergravity as a straightforward reformulation of relativistic hydrodynamics. In the example of a (2+1)-di...
Relativistic theories of materials
Bressan, Aldo
1978-01-01
The theory of relativity was created in 1905 to solve a problem concerning electromagnetic fields. That solution was reached by means of profound changes in fundamental concepts and ideas that considerably affected the whole of physics. Moreover, when Einstein took gravitation into account, he was forced to develop radical changes also in our space-time concepts (1916). Relativistic works on heat, thermodynamics, and elasticity appeared as early as 1911. However, general theories having a thermodynamic basis, including heat conduction and constitutive equations, did not appear in general relativity until about 1955 for fluids and appeared only after 1960 for elastic or more general finitely deformed materials. These theories dealt with materials with memory, and in this connection some relativistic versions of the principle of material indifference were considered. Even more recently, relativistic theories incorporating finite deformations for polarizable and magnetizable materials and those in which couple s...
Composite self-similar solutions for relativistic shocks: The transition to cold fluid temperatures
Pan, Margaret [School of Natural Sciences, Institute for Advanced Study, Princeton, New Jersey 08540 (United States); Sari, Re' em [California Institute of Technology, MS 130-33, Pasadena, California 91125 (United States) and Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel)
2009-11-15
The flow resulting from a strong ultrarelativistic shock moving through a stellar envelope with a polytropelike density profile has been studied analytically and numerically at early times while the fluid temperature is relativistic--that is, just before and after the shock breaks out of the star. Such a flow should expand and accelerate as its internal energy is converted to bulk kinetic energy; at late enough times, the assumption of relativistic temperatures becomes invalid. Here we present a new self-similar solution for the postbreakout flow when the accelerating fluid has bulk kinetic Lorentz factors much larger than unity but is cooling through p/n of order unity to subrelativistic temperatures. This solution gives a relation between a fluid element's terminal Lorentz factor and that element's Lorentz factor just after it is shocked. Our numerical integrations agree well with the solution. While our solution assumes a planar flow, we show that corrections due to spherical geometry are important only for extremely fast ejecta originating in a region very close to the stellar surface. This region grows if the shock becomes relativistic deeper in the star.
Amano, Takanobu
2016-11-01
A new multidimensional simulation code for relativistic two-fluid electrodynamics (RTFED) is described. The basic equations consist of the full set of Maxwell’s equations coupled with relativistic hydrodynamic equations for separate two charged fluids, representing the dynamics of either an electron-positron or an electron-proton plasma. It can be recognized as an extension of conventional relativistic magnetohydrodynamics (RMHD). Finite resistivity may be introduced as a friction between the two species, which reduces to resistive RMHD in the long wavelength limit without suffering from a singularity at infinite conductivity. A numerical scheme based on HLL (Harten-Lax-Van Leer) Riemann solver is proposed that exactly preserves the two divergence constraints for Maxwell’s equations simultaneously. Several benchmark problems demonstrate that it is capable of describing RMHD shocks/discontinuities at long wavelength limit, as well as dispersive characteristics due to the two-fluid effect appearing at small scales. This shows that the RTFED model is a promising tool for high energy astrophysics application.
Gomez, A. L.; Mansoori, G. A.
1983-01-01
A methodology is developed for the application of thermodynamic equations of state of fluids and fluid mixtures in evaluating working fluid combinations of absorption cooling cycles. Thermodynamic phase equilibrium formulation of this methodology is presented. In the application of this approach for the comparative study and choice of working fluids, the Redlich-Kwong equation of state is used for a number of possible working fluid combinations for solar absorption cooling cycles. It is demonstrated that when limited experimental data are at hand this approach could be a useful screening technique for potential working fluid combinations.
Local Existence of Solutions of Self Gravitating Relativistic Perfect Fluids
Brauer, Uwe; Karp, Lavi
2014-01-01
This paper deals with the evolution of the Einstein gravitational fields which are coupled to a perfect fluid. We consider the Einstein-Euler system in asymptotically flat spacestimes and therefore use the condition that the energy density might vanish or tend to zero at infinity, and that the pressure is a fractional power of the energy density. In this setting we prove local in time existence, uniqueness and well-posedness of classical solutions. The zero order term of our system contains an expression which might not be a C ∞ function and therefore causes an additional technical difficulty. In order to achieve our goals we use a certain type of weighted Sobolev space of fractional order. In Brauer and Karp (J Diff Eqs 251:1428-1446, 2011) we constructed an initial data set for these of systems in the same type of weighted Sobolev spaces. We obtain the same lower bound for the regularity as Hughes et al. (Arch Ratl Mech Anal 63(3):273-294, 1977) got for the vacuum Einstein equations. However, due to the presence of an equation of state with fractional power, the regularity is bounded from above.
Local Existence of Solutions of Self Gravitating Relativistic Perfect Fluids
Brauer, Uwe
2011-01-01
This paper deals with the evolution of the Einstein gravitational fields which are coupled to a perfect fluid. We consider the Einstein--Euler system in asymptotically flat spacestimes and therefore use the condition that the energy density might vanish or tend to zero at infinity, and that the pressure is a fractional power of the energy density. In this setting we prove a local in time existence, uniqueness and well-posedness of classical solutions. The zero order term of our system contains an expression which might not be a $C^\\infty$ function and therefore causes an additional technical difficulty. In order to achieve our goals we use a certain type of weighted Sobolev space of fractional order. Previously the authors constructed an initial data set for these of systems in the same type of weighted Sobolev spaces. We obtain the same lower bound for the regularity as the one of the classical result of Hughes, Kato and Marsden for the vacuum Einstein equations. However, due to the presence of an equation o...
Mode-by-mode fluid dynamics for relativistic heavy ion collisions
Floerchinger, Stefan
2014-01-01
We propose to study the fluid dynamic propagation of fluctuations in relativistic heavy ion collisions differentially with respect to their azimuthal, radial and longitudinal wavelength. To this end, we introduce a background-fluctuation splitting and a Bessel-Fourier decomposition of the fluctuating modes. We demonstrate how the fluid dynamic evolution of realistic events can be build up from the propagation of individual modes. We describe the main elements of this mode-by-mode fluid dynamics, and we discuss its use in the fluid dynamic analysis of heavy ion collisions. As a first illustration, we quantify to what extent only fluctuations of sufficiently large radial wave length contribute to harmonic flow coefficients. We find that fluctuations of short wave length are suppressed not only due to larger dissipative effects, but also due to a geometrical averaging over the freeze-out hyper surface. In this way, our study further substantiates the picture that harmonic flow coefficients give access to a coars...
A unified treatment of general fluid thermodynamics and its application to a preconditioning scheme
Meng, Hua; Yang, Vigor
2003-07-01
A unified treatment of general fluid thermodynamics is developed to handle fluid flows over their entire thermodynamic states. The analysis is based on the concepts of partial-mass and partial-density properties, and accommodates thermodynamic non-idealities and transport anomalies in the transcritical regime. The resultant routine is incorporated into a preconditioning scheme. All the thermophysical properties and numerical Jacobian matrices are derived directly from fundamental thermodynamic theories, rendering a robust algorithm valid for fluid flows at all speeds and at all thermodynamic states. As a specific example, a modified Soave-Redlich-Kwong equation of state is employed to obtain the fluid p- V- T properties. Several test cases concerning supercritical droplet vaporization in both quiescent and convective environments are presented to demonstrate the effectiveness of the present algorithm.
Muronga, A
2007-01-01
Relativistic non-ideal fluid dynamics is formulated in 3+1 space--time dimensions. The equations governing dissipative relativistic hydrodynamics are given in terms of the time and the 3-space quantities which correspond to those familiar from non-relativistic physics. Dissipation is accounted for by applying the causal theory of relativistic dissipative fluid dynamics. As a special case we consider a fluid without viscous/heat couplings in the causal system of transport/relaxation equations. For the study of physical systems we consider pure (1+1)-dimensional expansion in planar geometry, (1+1)-dimensional spherically symmetric ({\\em fireball}) expansion, (1+1)-dimensional cylindrically symmetric expansion and a (2+1)-dimensional expansion with cylindrical symmetry in the transverse plane ({\\em firebarell} expansion). The transport/relaxation equations are given in terms of the spatial components of the dissipative fluxes, since these are not independent. The choice for the independent components is analogou...
Thermodynamic Property Model of Wide-Fluid Phase Propane
I Made Astina
2007-05-01
Full Text Available A new thermodynamic property model for propane is expressed in form of the Helmholtz free energy function. It consists of eight terms of the ideal-gas part and eighteen terms of the residual part. Accurate experimental data of fluid properties and theoretical approach from the intermolecular potential were simultaneously considered in the development to insure accuracy and to improve reliability of the equation of state over wide range of pressures and temperatures. Based on the state range of experimental data used in the model development, the validity range is judged from the triple-point of 85.48 K to temperature of 450 K and pressure up to 60 MPa. The uncertainties with respect to different properties are estimated to be 0.03% in ideal-gas isobaric specific heat, 0.2% in liquid phase density, 0.3% in gaseous phase density 1% in specific heats, 0.1% in vapor-pressure except at very low temperatures, 0.05% in saturated-liquid density, 0.02% in speed of sound of the gaseous phase and 1% in speed of sound of the liquid phase.
Numerical Construction of Magnetosphere with Relativistic Two-fluid Plasma Flows
Kojima, Yasufumi
2009-01-01
We present a numerical model in which a cold pair plasma is ejected with relativistic speed through a polar cap region and flows almost radially outside the light cylinder. Stationary axisymmetric structures of electromagnetic fields and plasma flows are self-consistently calculated. In our model, motions of positively and negatively charged particles are assumed to be determined by electromagnetic forces and inertial terms, without pair creation and annihilation or radiation loss. The global electromagnetic fields are calculated by the Maxwell's equations for the plasma density and velocity, without using ideal MHD condition. Numerical result demonstrates the acceleration and deceleration of plasma due to parallel component of the electric fields. Numerical model is successfully constructed for weak magnetic fields or highly relativistic fluid velocity, i.e, kinetic energy dominated outflow. It is found that appropriate choices of boundary conditions and plasma injection model at the polar cap should be expl...
A Shock-Patching Code for Ultra-Relativistic Fluid Flows
Wen, L; Laguna, P
1996-01-01
We have developed a one-dimensional code to solve ultra-relativistic hydrodynamic problems, using the Glimm method for an accurate treatment of shocks and contact discontinuities. The implementation of the Glimm method is based on an exact Riemann solver and van der Corput sampling sequence. In order to improve computational efficiency, the Glimm method is replaced by a finite differencing scheme in those regions where the fluid flow is sufficiently smooth. The accuracy and convergence of this hybrid method is investigated in tests involving planar, cylindrically and spherically symmetric flows that exhibit strong shocks and Lorentz factors of up to $\\sim 2000$. This hybrid code has proven to be successful in simulating the interaction between a thin, ultra-relativistic, spherical shell and a low density stationary medium, a situation likely to appear in Gamma-Ray Bursts, supernovae explosions, pulsar winds and AGNs.
Many-Body Effects on the Thermodynamics of Fluids, Mixtures, and Nanoconfined Fluids.
Desgranges, Caroline; Delhommelle, Jerome
2015-11-10
Using expanded Wang-Landau simulations, we show that taking into account the many-body interactions results in sharp changes in the grand-canonical partition functions of single-component systems, binary mixtures, and nanoconfined fluids. The many-body contribution, modeled with a 3-body Axilrod-Teller-Muto term, results in shifts toward higher chemical potentials of the phase transitions from low-density phases to high-density phases and accounts for deviations of more than, e.g., 20% of the value of the partition function for a single-component liquid. Using the statistical mechanics formalism, we analyze how this contribution has a strong impact on some properties (e.g., pressure, coexisting densities, and enthalpy) and a moderate impact on others (e.g., Gibbs or Helmholtz free energies). We also characterize the effect of the 3-body terms on adsorption isotherms and adsorption thermodynamic properties, thereby providing a full picture of the effect of the 3-body contribution on the thermodynamics of nanoconfined fluids.
Composite self-similar solutions for relativistic shocks: the transition to cold fluid temperatures
Pan, Margaret
2008-01-01
The flow resulting from a strong ultrarelativistic shock moving through a stellar envelope with a polytrope-like density profile has been studied analytically and numerically at early times while the fluid temperature is relativistic--that is, just before and just after the shock breaks out of the star. Such a flow should expand and accelerate as its internal energy is converted to bulk kinetic energy; at late enough times, the assumption of relativistic temperatures becomes invalid. Here we present a new self-similar solution for the post-breakout flow when the accelerating fluid has bulk kinetic Lorentz factors much larger than unity but is cooling through $p/n$ of order unity to subrelativistic temperatures. This solution gives a relation between a fluid element's terminal Lorentz factor and that element's Lorentz factor just after it is shocked. Our numerical integrations agree well with the solution. While our solution assumes a planar flow, we show that corrections due to spherical geometry are importan...
High order numerical simulations of the Richtmyer Meshkov instability in a relativistic fluid
Zanotti, Olindo
2014-01-01
We study the Richtmyer--Meshkov (RM) instability of a relativistic perfect fluid by means of high order numerical simulations with adaptive mesh refinement (AMR). The numerical scheme adopts a finite volume Weighted Essentially Non-Oscillatory (WENO) reconstruction to increase accuracy in space, a local space-time discontinuous Galerkin predictor method to obtain high order of accuracy in time and a high order one-step time update scheme together with a "cell-by-cell" space-time AMR strategy with time-accurate local time stepping. In this way, third order accurate (both in space and in time) numerical simulations of the RM instability are performed, spanning a wide parameter space. We present results both for the case in which a light fluid penetrates into a higher density one (Atwood number $A>0$), and for the case in which a heavy fluid penetrates into a lower density one (Atwood number $A<0$). We find that, for large Lorentz factors \\gamma_s of the incident shock wave, the relativistic RM instability is...
Thermodynamic scaling of the shear viscosity of Mie n-6 fluids and their binary mixtures
Delage-Santacreu, Stephanie [Laboratoire de Mathématiques et leurs Applications (UMR-5142 with CNRS), Université de Pau et des Pays de l’Adour, BP 1155, F-64013 PAU Cedex (France); Galliero, Guillaume, E-mail: guillaume.galliero@univ-pau.fr; Hoang, Hai; Bazile, Jean-Patrick; Boned, Christian [Laboratoire des Fluides Complexes et leurs Reservoirs (UMR-5150 with CNRS and TOTAL), Université de Pau et des Pays de l’Adour, BP 1155, F-64013 PAU Cedex (France); Fernandez, Josefa [Laboratorio de Propiedades Termofisicas, Universidade Santiago de Compostela, Campus Vida, E-15782 Santiago de Compostela (Spain)
2015-05-07
In this work, we have evaluated the applicability of the so-called thermodynamic scaling and the isomorph frame to describe the shear viscosity of Mie n-6 fluids of varying repulsive exponents (n = 8, 12, 18, 24, and 36). Furthermore, the effectiveness of the thermodynamic scaling to deal with binary mixtures of Mie n-6 fluids has been explored as well. To generate the viscosity database of these fluids, extensive non-equilibrium molecular dynamics simulations have been performed for various thermodynamic conditions. Then, a systematic approach has been used to determine the gamma exponent value (γ) characteristic of the thermodynamic scaling approach for each system. In addition, the applicability of the isomorph theory with a density dependent gamma has been confirmed in pure fluids. In both pure fluids and mixtures, it has been found that the thermodynamic scaling with a constant gamma is sufficient to correlate the viscosity data on a large range of thermodynamic conditions covering liquid and supercritical states as long as the density is not too high. Interestingly, it has been obtained that, in pure fluids, the value of γ is directly proportional to the repulsive exponent of the Mie potential. Finally, it has been found that the value of γ in mixtures can be deduced from those of the pure component using a simple logarithmic mixing rule.
Demianski, Marek
2013-01-01
Relativistic Astrophysics brings together important astronomical discoveries and the significant achievements, as well as the difficulties in the field of relativistic astrophysics. This book is divided into 10 chapters that tackle some aspects of the field, including the gravitational field, stellar equilibrium, black holes, and cosmology. The opening chapters introduce the theories to delineate gravitational field and the elements of relativistic thermodynamics and hydrodynamics. The succeeding chapters deal with the gravitational fields in matter; stellar equilibrium and general relativity
A Thermodynamic Model for Square-well Chain Fluid: Theory and Monte Carlo Simulation
无
2001-01-01
A thermodynamic model for the freely jointed square-well chain fluids was developed based on the thermodynamic perturbation theory of Barker-Henderson, Zhang and Wertheim. In this derivation Zhang's expressions for square-well monomers improved from Barker-Henderson compressibility approximation were adopted as the reference fluid, and Wertheim＇s polymerization method was used to obtain the free energy term due to the bond connectivity. An analytic expression for the Helmholtz free energy of the square-well chain fluids was obtained. The expression without adjustable parameters leads to the thermodynamic consistent predictions of the compressibility factors, residual internal energy and constant-volume heat capacity for dimer,4-mer, 8-mer and 16-mer square-well fluids. The results are in good agreement with the Monte Carlo simulation. To obtain the MC data of residual internal energy and the constant-volume heat capacity needed, NVT MC simulations were performed for these square-well chain fluids.
Propagation of an ultra-short, intense laser in a relativistic fluid
Ritchie, A.B.; Decker, C.D. [Lawrence Livermore National Lab., CA (United States)
1997-12-31
A Maxwell-relativistic fluid model is developed to describe the propagation of an ultrashort, intense laser pulse through an underdense plasma. The model makes use of numerically stabilizing fast Fourier transform (FFT) computational methods for both the Maxwell and fluid equations, and it is benchmarked against particle-in-cell (PIC) simulations. Strong fields generated in the wake of the laser are calculated, and the authors observe coherent wake-field radiation generated at harmonics of the plasma frequency due to nonlinearities in the laser-plasma interaction. For a plasma whose density is 10% of critical, the highest members of the plasma harmonic series begin to overlap with the first laser harmonic, suggesting that widely used multiple-scales-theory, by which the laser and plasma frequencies are assumed to be separable, ceases to be a useful approximation.
Thermodynamics and fluid dynamics of effusive subglacial eruptions
Höskuldsson, A.; Sparks, R. S. J.
We consider the thermodynamic and fluid dynamic processes that occur during subglacial effusive eruptions. Subglacial eruptions typically generate catastrophic floods (jökulhlaups) due to melting of ice by lava and generation of a large water cavity. We consider the heat transfer from basaltic and rhyolitic lava eruptions to the ice for typical ranges of magma discharge and geometry of subglacial lavas in Iceland. Our analysis shows that the heat flux out of cooling lava is large enough to sustain vigorous natural convection in the surrounding meltwater. In subglacial eruptions the temperature difference driving convection is in the range 10-100 °C. Average temperature of the meltwater must exceed 4 °C and is usually substantially greater. We calculate melting rates of the walls of the ice cavity in the range 1-40m/day, indicating that large subglacial lakes can form rapidly as observed in the 1918 eruption of Katla and the 1996 eruption of Gjálp fissure in Vatnajökull. The volume changes associated with subglacial eruptions can cause large pressure changes in the developing ice cavity. These pressure changes can be much larger than those associated with variation of bedrock and glacier surface topography. Previous models of water-cavity stability based on hydrostatic and equilibrium conditions may not be applicable to water cavities produced rapidly in volcanic eruptions. Energy released by cooling of basaltic lava at the temperature of 1200 °C results in a volume deficiency due to volume difference between ice and water, provided that heat exchange efficiency is greater than approximately 80%. A negative pressure change inhibits escape of water, allowing large cavities to build up. Rhyolitic eruptions and basaltic eruptions, with less than approximately 80% heat exchange efficiency, cause positive pressure changes promoting continual escape of meltwater. The pressure changes in the water cavity can cause surface deformation of the ice. Laboratory
Theoretical models for fluid thermodynamics based on the quasi-Gaussian entropy theory
Amadei, Andrea
1998-01-01
Summary The theoretical modeling of fluid thermodynamics is one of the most challenging fields in physical chemistry. In fact the fluid behavior, except at very low density conditions, is still extremely difficult to be modeled from a statistical mechanical point of view, as for any realistic model
Shogin, Dmitry
2015-01-01
We test the physical relevance of the full and truncated versions of the Israel-Stewart theory of irreversible thermodynamics in a cosmological setting. Using a dynamical systems method, we determine the asymptotic future of plane symmetric Bianchi type I spacetimes filled with a viscous {\\gamma}-fluid, keeping track of the magnitude of relative dissipative fluxes, which determines the applicability of the Israel-Stewart theory. We consider the situations when the dissipative mechanisms of shear and bulk viscosity are involved separately and simultaneously. Also, we apply two different temperature models in the full version of the theory in order to compare the results. We demonstrate that the only case when the fluid asymptotically approaches local equilibrium, and the underlying assumptions of the IS theory are therefore not violated, is that of a dissipative fluid with vanishing bulk viscosity. The truncated Israel-Stewart equations for shear viscosity are found to produce solutions which manifest patholog...
Mode-by-mode fluid dynamics for relativistic heavy ion collisions
Floerchinger, Stefan, E-mail: stefan.floerchinger@cern.ch; Wiedemann, Urs Achim, E-mail: urs.wiedemann@cern.ch
2014-01-20
We propose to study the fluid dynamic propagation of fluctuations in relativistic heavy ion collisions differentially with respect to their azimuthal, radial and longitudinal wavelength. To this end, we introduce a background-fluctuation splitting and a Bessel–Fourier decomposition of the fluctuating modes. We demonstrate how the fluid dynamic evolution of realistic events can be built up from the propagation of individual modes. We describe the main elements of this mode-by-mode fluid dynamics, and we discuss its use in the fluid dynamic analysis of heavy ion collisions. As a first illustration, we quantify to what extent only fluctuations of sufficiently large radial wave length contribute to harmonic flow coefficients. We find that fluctuations of short wave length are suppressed not only due to larger dissipative effects, but also due to a geometrical averaging over the freeze-out hyper-surface. In this way, our study further substantiates the picture that harmonic flow coefficients give access to a coarse-grained version of the initial conditions for heavy ion collisions, only.
Mode-by-mode fluid dynamics for relativistic heavy ion collisions
Floerchinger, Stefan; Wiedemann, Urs Achim
2014-01-01
We propose to study the fluid dynamic propagation of fluctuations in relativistic heavy ion collisions differentially with respect to their azimuthal, radial and longitudinal wavelength. To this end, we introduce a background-fluctuation splitting and a Bessel-Fourier decomposition of the fluctuating modes. We demonstrate how the fluid dynamic evolution of realistic events can be built up from the propagation of individual modes. We describe the main elements of this mode-by-mode fluid dynamics, and we discuss its use in the fluid dynamic analysis of heavy ion collisions. As a first illustration, we quantify to what extent only fluctuations of sufficiently large radial wave length contribute to harmonic flow coefficients. We find that fluctuations of short wave length are suppressed not only due to larger dissipative effects, but also due to a geometrical averaging over the freeze-out hyper-surface. In this way, our study further substantiates the picture that harmonic flow coefficients give access to a coarse-grained version of the initial conditions for heavy ion collisions, only.
Some universal trends of the Mie(n,m) fluid thermodynamics
Orea, Pedro; Reyes-Mercado, Yuri [Programa de Ingenieria Molecular, Instituto Mexicano del Petroleo, 07730 Mexico D.F. (Mexico); Duda, Yurko [Programa de Ingenieria Molecular, Instituto Mexicano del Petroleo, 07730 Mexico D.F. (Mexico)], E-mail: yduda@lycos.com
2008-11-24
By using canonical Monte Carlo simulation, the liquid-vapor phase diagram, surface tension, interface width, and pressure for the Mie(n,m) model fluids are calculated for six pairs of parameters m and n. It is shown that after certain re-scaling of fluid density the corresponding states rule can be applied for the calculations of the thermodynamic properties of the Mie model fluids, and for some real substances.
Shogin, Dmitry; Amund Amundsen, Per
2016-10-01
We test the physical relevance of the full and the truncated versions of the Israel–Stewart (IS) theory of irreversible thermodynamics in a cosmological setting. Using a dynamical systems method, we determine the asymptotic future of plane symmetric Bianchi type I spacetimes with a viscous mathematical fluid, keeping track of the magnitude of the relative dissipative fluxes, which determines the applicability of the IS theory. We consider the situations where the dissipative mechanisms of shear and bulk viscosity are involved separately and simultaneously. It is demonstrated that the only case in the given model when the fluid asymptotically approaches local thermal equilibrium, and the underlying assumptions of the IS theory are therefore not violated, is that of a dissipative fluid with vanishing bulk viscosity. The truncated IS equations for shear viscosity are found to produce solutions which manifest pathological dynamical features and, in addition, to be strongly sensitive to the choice of initial conditions. Since these features are observed already in the case of an oversimplified mathematical fluid model, we have no reason to assume that the truncation of the IS transport equations will produce relevant results for physically more realistic fluids. The possible role of bulk and shear viscosity in cosmological evolution is also discussed.
The effect of a two-fluid atmosphere on relativistic stars
Govender, Gabriel; Maharaj, Sunil D
2015-01-01
We model the physical behaviour at the surface of a relativistic radiating star in the strong gravity limit. The spacetime in the interior is taken to be spherically symmetrical and shear-free. The heat conduction in the interior of the star is governed by the geodesic motion of fluid particles and a nonvanishing radially directed heat flux. The local atmosphere in the exterior region is a two-component system consisting of standard pressureless (null) radiation and an additional null fluid with nonzero pressure and constant energy density. We analyse the generalised junction condition for the matter and gravitational variables on the stellar surface and generate an exact solution. We investigate the effect of the exterior energy density on the temporal evolution of the radiating fluid pressure, luminosty, gravitational redshift and mass flow at the boundary of the star. The influence of the density on the rate of gravitational collapse is also probed and the strong, dominant and weak energy conditions are al...
Rayleigh-Brillouin spectrum in special relativistic hydrodynamics.
Garcia-Perciante, A L; Garcia-Colin, L S; Sandoval-Villalbazo, A
2009-06-01
In this paper we calculate the Rayleigh-Brillouin spectrum for a relativistic simple fluid according to three different versions available for a relativistic approach to nonequilibrium thermodynamics. An outcome of these calculations is that Eckart's version predicts that such spectrum does not exist. This provides an argument to question its validity. The remaining two results, which differ one from another, do provide a finite form for such spectrum. This raises the rather intriguing question as to which of the two theories is a better candidate to be taken as a possible version of relativistic nonequilibrium thermodynamics. The answer will clearly require deeper examination of this problem.
The Rayleigh-Brillouin Spectrum in Special Relativistic Hydrodynamics
García-Perciante, A L; Sandoval-Villalbazo, A
2009-01-01
In this paper we calculate the Rayleigh-Brillouin spectrum for a relativistic simple fluid according to three different versions available for a relativistic approach to non-equilibrium thermodynamics. An outcome of these calculations is that Eckart's version predicts that such spectrum does not exist. This provides an argument to question its validity. The remaining two results, which differ one from another, do provide a finite form for such spectrum. This raises the rather intriguing question as to which of the two theories is a better candidate to be taken as a possible version of relativistic non-equilibrium thermodynamics. The answer will clearly require deeper examination of this problem.
Ab initio interatomic potentials and the thermodynamic properties of fluids
Vlasiuk, Maryna; Sadus, Richard J.
2017-07-01
Monte Carlo simulations with accurate ab initio interatomic potentials are used to investigate the key thermodynamic properties of argon and krypton in both vapor and liquid phases. Data are reported for the isochoric and isobaric heat capacities, the Joule-Thomson coefficient, and the speed of sound calculated using various two-body interatomic potentials and different combinations of two-body plus three-body terms. The results are compared to either experimental or reference data at state points between the triple and critical points. Using accurate two-body ab initio potentials, combined with three-body interaction terms such as the Axilrod-Teller-Muto and Marcelli-Wang-Sadus potentials, yields systematic improvements to the accuracy of thermodynamic predictions. The effect of three-body interactions is to lower the isochoric and isobaric heat capacities and increase both the Joule-Thomson coefficient and speed of sound. The Marcelli-Wang-Sadus potential is a computationally inexpensive way to utilize accurate two-body ab initio potentials for the prediction of thermodynamic properties. In particular, it provides a very effective way of extending two-body ab initio potentials to liquid phase properties.
Convexity and symmetrization in relativistic theories
Ruggeri, T.
1990-09-01
There is a strong motivation for the desire to have symmetric hyperbolic field equations in thermodynamics, because they guarantee well-posedness of Cauchy problems. A generic quasi-linear first order system of balance laws — in the non-relativistic case — can be shown to be symmetric hyperbolic, if the entropy density is concave with respect to the variables. In relativistic thermodynamics this is not so. This paper shows that there exists a scalar quantity in relativistic thermodynamics whose concavity guarantees a symmetric hyperbolic system. But that quantity — we call it —bar h — is not the entropy, although it is closely related to it. It is formed by contracting the entropy flux vector — ha with a privileged time-like congruencebar ξ _α . It is also shown that the convexity of h plus the requirement that all speeds be smaller than the speed of light c provide symmetric hyperbolic field equations for all choices of the direction of time. At this level of generality the physical meaning of —h is unknown. However, in many circumstances it is equal to the entropy. This is so, of course, in the non-relativistic limit but also in the non-dissipative relativistic fluid and even in relativistic extended thermodynamics for a non-degenerate gas.
MALFLIET, R
1993-01-01
We discuss the present status of relativistic transport theory. Special emphasis is put on problems of topical interest: hadronic features, thermodynamical consistent approximations and spectral properties.
Tidal Interaction between a Fluid Star and a Kerr Black Hole Relativistic Roche-Riemann Model
Wiggins, P; Wiggins, Paul; Lai, Dong
1999-01-01
We present a semi-analytic study of the equilibrium models of close binary systems containing a fluid star (mass $m$ and radius $R_0$) and a Kerr black hole (mass $M$) in circular orbit. We consider the limit $M\\gg m$ where spacetime is described by the Kerr metric. The tidally deformed star is approximated by an ellipsoid, and satisfies the polytropic equation of state. The models also include fluid motion in the stellar interior, allowing binary models with nonsynchronized stellar spin (as expected for coalescing neutron star--black hole binaries) to be constructed. Tidal disruption occurs at orbital radius $r_{\\rm tide}\\sim R_0(M/m)^{1/3}$, but the dimensionless ratio of the black hole as well as on the equation of state and the internal rotation of the star. We find that the general relativistic tidal field disrupts the star at a larger $\\hat r_{\\rm tide}$ than the Newtonian tide; the difference is particularly prominent if the disruption occurs in the vicinity of the black hole's horizon. In general, $\\h...
Sdowski, Aleksander; Tchekhovskoy, Alexander; Zhu, Yucong
2012-01-01
A numerical scheme is described for including radiation in multi-dimensional general-relativistic conservative fluid dynamics codes. In this method, a covariant form of the M1 closure scheme is used to close the radiation moments, and the radiative source terms are treated semi-implicitly in order to handle both optically thin and optically thick regimes. The scheme has been implemented in a conservative general relativistic radiation hydrodynamics code KORAL. The robustness of the code is demonstrated on a number of test problems, including radiative relativistic shock tubes, static radiation pressure supported atmosphere, shadows, beams of light in curved spacetime, and radiative Bondi accretion. The advantages of M1 closure relative to other approaches such as Eddington closure and flux-limited diffusion are discussed, and its limitations are also highlighted.
Fluid lipid bilayers: Intermonolayer coupling and its thermodynamic manifestations
Hansen, Per Lyngs; Miao, Ling; Ipsen, John Hjorth
1998-01-01
A fluid membrane of lipid bilayer consists of two individual molecular monolayers physically opposed to each other. This unique molecular architecture naturally necessitates the need to treat a lipid-bilayer membrane as one entity of two coupled two-dimensional systems (monolayers), each of which...
Thermodynamics and Kinetic Theory of Relativistic Gases in 2-D Cosmological Models
Kremer, G M
2002-01-01
A kinetic theory of relativistic gases in a two-dimensional space is developed in order to obtain the equilibrium distribution function and the expressions for the fields of energy per particle, pressure, entropy per particle and heat capacities in equilibrium. Furthermore, by using the method of Chapman and Enskog for a kinetic model of the Boltzmann equation the non-equilibrium energy-momentum tensor and the entropy production rate are determined for a universe described by a two-dimensional Robertson-Walker metric. The solutions of the gravitational field equations that consider the non-equilibrium energy-momentum tensor - associated with the coefficient of bulk viscosity - show that opposed to the four-dimensional case, the cosmic scale factor attains a maximum value at a finite time decreasing to a "big crunch" and that there exists a solution of the gravitational field equations corresponding to a "false vacuum". The evolution of the fields of pressure, energy density and entropy production rate with th...
Vanishing condition for the heat flux of a relativistic fluid in a moving frame
Romero-Muñoz, Martín; Dagdug, Leonardo; Chacón-Acosta, Guillermo
2014-11-01
It has been asked if is appropriate to introduce the heat flow in the energy- momentum tensor, due to the non-mechanical nature of heat [1]. Although this could be answered by both kinetic and symmetry arguments, we address the problem by checking the validity of the second law of thermodynamics in a fluid that is boosted by a Lorentz transformation to a non comoving frame. In this contribution we found that this only can happen under certain conditions. Indeed, we found that there are a family of reference frames that satisfies these conditions, where Landau-Lifshitz frame is one of those. Additionally we relate such conditions with the null energy condition and the entropy production.
Property Uncertainty Analysis and Methods for Optimal Working Fluids of Thermodynamic Cycles
Frutiger, Jerome
There is an increasing interest in recovering industrial waste heat at low tempera-tures (70-250◦C). Thermodynamic cycles, such as heat pumps or organic Rankine cycles, can recover this heat and transfer it to other process streams or convert it into electricity. The working fluid, circulating...... in the context of an industrial organic Rankine cycle, used for the recovery of waste heat from an engine of a marine container ship. The study illustrates that the model structure is vital for the uncertainties of equations of state and suggests that uncertainty becomes a criterion (along with e.g. goodness......-of-fit or ease of use) for the selection of an equation of state for a specific application. Furthermore, two studies on the identification of suitable working fluids for thermodynamic cycles are presented. The first one selects and assesses working fluid candidates for an organic Rankine cycle system to recover...
Murad, Mohammad Hassan
2014-01-01
In this work some families of relativistic anisotropic charged fluid spheres have been obtained by solving Einstein-Maxwell field equations with preferred form of one of the metric potentials, a suitable forms of electric charge distribution and pressure anisotropy functions. The resulting equation of state (EOS) of the matter distribution has been obtained. Physical analysis shows that the relativistic stellar structure for matter distribution obtained in this work may reasonably model an electrically charged compact star whose energy density associated with the electric fields is on the same order of magnitude as the energy density of fluid matter itself (e.g. electrically charged bare strange stars). These models permit a simple method of systematically fixing bounds on the maximum possible mass of cold compact electrically charged self-bound stars. It has been demonstrated numerically that the maximum compactness and mass increase in the presence of electric field and anisotropic pressures. Based on the a...
A thermodynamic model to predict wax formation in petroleum fluids
Coutinho, J.A.P. [Universidade de Aveiro (Portugal). Dept. de Quimica. Centro de Investigacao em Quimica]. E-mail: jcoutinho@dq.ua.pt; Pauly, J.; Daridon, J.L. [Universite de Pau et des Pays de l' Adour, Pau (France). Lab. des Fluides Complexes
2001-12-01
Some years ago the authors proposed a model for the non-ideality of the solid phase, based on the Predictive Local Composition concept. This was first applied to the Wilson equation and latter extended to NRTL and UNIQUAC models. Predictive UNIQUAC proved to be extraordinarily successful in predicting the behaviour of both model and real hydrocarbon fluids at low temperatures. This work illustrates the ability of Predictive UNIQUAC in the description of the low temperature behaviour of petroleum fluids. It will be shown that using Predictive UNIQUAC in the description of the solid phase non-ideality a complete prediction of the low temperature behaviour of synthetic paraffin solutions, fuels and crude oils is achieved. The composition of both liquid and solid phases, the amount of crystals formed and the cloud points are predicted within the accuracy of the experimental data. The extension of Predictive UNIQUAC to high pressures, by coupling it with an EOS/G{sup E} model based on the SRK EOS used with the LCVM mixing rule, is proposed and predictions of phase envelopes for live oils are compared with experimental data. (author)
A THERMODYNAMIC MODEL TO PREDICT WAX FORMATION IN PETROLEUM FLUIDS
J.A.P. Coutinho
2001-12-01
Full Text Available Some years ago the authors proposed a model for the non-ideality of the solid phase, based on the Predictive Local Composition concept. This was first applied to the Wilson equation and latter extended to NRTL and UNIQUAC models. Predictive UNIQUAC proved to be extraordinarily successful in predicting the behaviour of both model and real hydrocarbon fluids at low temperatures. This work illustrates the ability of Predictive UNIQUAC in the description of the low temperature behaviour of petroleum fluids. It will be shown that using Predictive UNIQUAC in the description of the solid phase non-ideality a complete prediction of the low temperature behaviour of synthetic paraffin solutions, fuels and crude oils is achieved. The composition of both liquid and solid phases, the amount of crystals formed and the cloud points are predicted within the accuracy of the experimental data. The extension of Predictive UNIQUAC to high pressures, by coupling it with an EOS/G E model based on the SRK EOS used with the LCVM mixing rule, is proposed and predictions of phase envelopes for live oils are compared with experimental data.
Transport properties of the fluid produced at Relativistic Heavy-Ion Collider
Rajeev S Bhalerao
2010-08-01
It is by now well known that the relativistic heavy-ion collisions at RHIC, BNL have produced a strongly interacting fluid with remarkable properties, among them the lowest ever observed ratio of the coefficient of shear viscosity to entropy density. Arguments based on ideas from the string theory, in particular the AdS/CFT correspondence, led to the conjecture – now known to be violated – that there is an absolute lower limit 1/4 on the value of this ratio. Causal viscous hydrodynamics calculations together with the RHIC data have put an upper limit on this ratio, a small multiple of 1/4, in the relevant temperature regime. Less well-determined is the ratio of the coefficient of bulk viscosity to entropy density. These transport coefficients have also been studied non-perturbatively in the lattice QCD framework, and perturbatively in the limit of high-temperature QCD. Another interesting transport coefficient is the coefficient of diffusion which is also being studied in this context. In this paper some of these recent developments are reviewed and then the opportunities presented by the anticipated LHC data are discussed, for the general nuclear physics audience.
Xiang, Hong Wei
2005-01-01
The corresponding-states principle helps the understanding and calculating of thermodynamic, transport, and surface properties of substances in various states, required by our modern lifestyle. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids describes the origins and applications of the principle from a universal point of view with comparisons to experimental data where possible. It uses the universal theory to explain present theories. Emphasis is on the properties of pure systems, and the corresponding-states theory can also be e
Mccarty, R. D.
1980-01-01
The thermodynamic and transport properties of selected cryogens had programmed into a series of computer routines. Input variables are any two of P, rho or T in the single phase regions and either P or T for the saturated liquid or vapor state. The output is pressure, density, temperature, entropy, enthalpy for all of the fluids and in most cases specific heat capacity and speed of sound. Viscosity and thermal conductivity are also given for most of the fluids. The programs are designed for access by remote terminal; however, they have been written in a modular form to allow the user to select either specific fluids or specific properties for particular needs. The program includes properties for hydrogen, helium, neon, nitrogen, oxygen, argon, and methane. The programs include properties for gaseous and liquid states usually from the triple point to some upper limit of pressure and temperature which varies from fluid to fluid.
Generalised equilibrium of cosmological fluids in second-order thermodynamics
Zimdahl, W; Le Denmat, G; Zimdahl, Winfried
1999-01-01
Combining the second-order entropy flow vector of the causal Israel-Stewart theory with the conformal Killing-vector property of $u_{i}/T$, where $u_{i}$ is the four-velocity of the medium and T its equilibrium temperature, we investigate generalized equilibrium states for cosmological fluids with nonconserved particle number. We calculate the corresponding equilibrium particle production rate and show that this quantity is reduced compared with the results of the previously studied first-order theory. Generalized equilibrium for massive particles turns out to be compatible with a dependence of the Robertson-Walker metric and may be regarded as a realization of so-called K-matter.
Harko, T
2016-01-01
Obtaining exact solutions of the spherically symmetric general relativistic gravitational field equations describing the interior structure of an isotropic fluid sphere is a long standing problem in theoretical and mathematical physics. The usual approach to this problem consists mainly in the numerical investigation of the Tolman-Oppenheimer-Volkoff and of the mass continuity equations, which describes the hydrostatic stability of the dense stars. In the present paper we introduce an alternative approach for the study of the relativistic fluid sphere, based on the relativistic mass equation, obtained by eliminating the energy density in the Tolman-Oppenheimer-Volkoff equation. Despite its apparent complexity, the relativistic mass equation can be solved exactly by using a power series representation for the mass, and the Cauchy convolution for infinite power series. We obtain exact series solutions for general relativistic dense astrophysical objects described by the linear barotropic and the polytropic equa...
Monte Carlo simulation of thermodynamic properties for two-dimensional Lennard-Jones fluids
无
2000-01-01
Canonical ensemble Monte Carlo simulations have been carried out to investigate the thermodynamic properties of two-dimensional fluids subjected to truncated Lennard-Jones 12-6 potential. The simulations of thermodynamic states sweep across liquid-vapor regime over a wide range of thermodynamic conditions. Simulated isotherms behave van der Waals loop-like characteristics in the liquid-vapor phase-transition region. It suggests a continuous isothermal phase transition in the case of micro system, in which the system size prohibits phase separation. Two-dimensional dimensionless van der Waals equation of states has been obtained from theoretical analysis. By fitting simulated data to this equation, temperature-dependent parameters in the equation have been determined.
Fermi, Enrico
1956-01-01
Indisputably, this is a modern classic of science. Based on a course of lectures delivered by the author at Columbia University, the text is elementary in treatment and remarkable for its clarity and organization. Although it is assumed that the reader is familiar with the fundamental facts of thermometry and calorimetry, no advanced mathematics beyond calculus is assumed.Partial contents: thermodynamic systems, the first law of thermodynamics (application, adiabatic transformations), the second law of thermodynamics (Carnot cycle, absolute thermodynamic temperature, thermal engines), the entr
Global thermodynamic behaviour of supercritical fluids: example of methane and ethane
Rizi A.
2013-07-01
Full Text Available Do to the fluctuations associated with the critical region of fluids. The behavior of thermodynamic properties these can not be predicted by mean field theories. To do so, a global equation of state based on the crossover model has been used. This equation of state is formulated on the basis of comparison of selected measurements of pressure-density-temperature data, isochoric and isobaric heat capacity of fluids.The model can be applied in a wide range of temperatures and densities around the critical point for ethane and methane. It is found that the developed model represents most of the reliable experimental data accurately.
Canonical fluid thermodynamics. [variational principles of stability for compressible adiabatic flow
Schmid, L. A.
1974-01-01
The space-time integral of the thermodynamic pressure plays in a certain sense the role of the thermodynamic potential for compressible adiabatic flow. The stability criterion can be converted into a variational minimum principle by requiring the molar free-enthalpy and temperature to be generalized velocities. In the fluid context, the definition of proper-time differentiation involves the fluid velocity expressed in terms of three particle identity parameters. The pressure function is then converted into a functional which is the Lagrangian density of the variational principle. Being also a minimum principle, the variational principle provides a means for comparing the relative stability of different flows. For boundary conditions with a high degree of symmetry, as in the case of a uniformly expanding spherical gas box, the most stable flow is a rectilinear flow for which the world-trajectory of each particle is a straight line. Since the behavior of the interior of a freely expanding cosmic cloud may be expected to be similar to that of the fluid in the spherical box of gas, this suggests that the cosmic principle is a consequence of the laws of thermodynamics, rather than just an ad hoc postulate.
Covariant Thermodynamics and Relativity
Lopez-Monsalvo, C S
2011-01-01
This thesis deals with the dynamics of irreversible processes within the context of the general theory of relativity. In particular, we address the problem of the 'infinite' speed of propagation of thermal disturbances in a dissipative fluid. The present work builds on the multi-fluid variational approach to relativistic dissipation, pioneered by Carter, and provides a dynamical theory of heat conduction. The novel property of such approach is the thermodynamic interpretation associated with a two-fluid system whose constituents are matter and entropy. The dynamics of this model leads to a relativistic generalisation of the Cattaneo equation; the constitutive relation for causal heat transport. A comparison with the Israel and Stewart model is presented and its equivalence is shown. This discussion provides new insights into the not-well understood definition of a non-equilibrium temperature. The variational approach to heat conduction presented in this thesis constitutes a mathematically promising formalism ...
García-Perciante, A L; Sandoval-Villalbazo, A
2008-01-01
It is shown that the generic instabilities that appear in the framework of relativistic linear irreversible thermodynamics, describing the fluctuations of a simple fluid close to equilibrium, arise due to the inclusion of heat in the energy-momentum tensor that governs the fluid evolution. Further, it is also shown how such instabilities can be avoided within a relativistic linear framework if a Meixner-like approach to the phenomenological equations is employed.
Santos, Andrés; de Haro, Mariano López; Yuste, Santos B.
2009-01-01
Different theoretical approaches for the thermodynamic properties and the equation of state for multicomponent mixtures of nonadditive hard spheres in $d$ dimensions are presented in a unified way. These include the theory by Hamad, our previous formulation, the original MIX1 theory, a recently proposed modified MIX1 theory, as well as a nonlinear extension of the MIX1 theory proposed in this paper. Explicit expressions for the compressibility factor, Helmholtz free energy, and second, third,...
Thermodynamically consistent mesoscopic fluid particle models for a van der Waals fluid
Serrano, Mar; Español, Pep
2000-01-01
The GENERIC structure allows for a unified treatment of different discrete models of hydrodynamics. We first propose a finite volume Lagrangian discretization of the continuum equations of hydrodynamics through the Voronoi tessellation. We then show that a slight modification of these discrete equations has the GENERIC structure. The GENERIC structure ensures thermodynamic consistency and allows for the introduction of correct thermal noise. In this way, we obtain a consistent discrete model ...
Hess, Julian; Wang, Yongqi
2016-11-01
A new mixture model for granular-fluid flows, which is thermodynamically consistent with the entropy principle, is presented. The extra pore pressure described by a pressure diffusion equation and the hypoplastic material behavior obeying a transport equation are taken into account. The model is applied to granular-fluid flows, using a closing assumption in conjunction with the dynamic fluid pressure to describe the pressure-like residual unknowns, hereby overcoming previous uncertainties in the modeling process. Besides the thermodynamically consistent modeling, numerical simulations are carried out and demonstrate physically reasonable results, including simple shear flow in order to investigate the vertical distribution of the physical quantities, and a mixture flow down an inclined plane by means of the depth-integrated model. Results presented give insight in the ability of the deduced model to capture the key characteristics of granular-fluid flows. We acknowledge the support of the Deutsche Forschungsgemeinschaft (DFG) for this work within the Project Number WA 2610/3-1.
Saha, Subhajit
2016-01-01
Thermodynamics on the cosmological apparent horizon of a flat Friedmann-Lemaitre-Robertson-Walker metric has been investigated with Bekenstein entropy and Hawking temperature on the horizon, and Unruh temperature for the fluid inside the horizon. This temperature is experienced by a radial comoving observer infinitesimally close to the horizon due to the pressure exerted by the fluid bounded by the horizon. An expression for the entropy of the fluid has been obtained which is found to be proportional to the volume of the thermodynamic system which implies that the Unruh temperature of the fluid is inconsistent with the holographic principle. Further, we have been able to find an expression for the effective entropy of the system. Finally, assuming a barotropic equation of state $p=w\\rho$ ($w$ constant) for the fluid, it has been shown that the generalized second law holds good for a non-phantom w, while thermodynamic equilibrium is never possible for such a scenario.
Panta, Baradan; Glasoe, Walker A; Zollner, Juliana H; Carlson, Kimberly K; Hanson, David R
2012-10-18
Particle formation and growth with H(2)SO(4) molecules in an axially symmetric flow reactor was simulated with computational fluid dynamics. A warm (~310 K) gas containing H(2)SO(4) flows into a cooled section (296 K) that induces particle formation. The fluid dynamics gives flow fields, temperatures, and reactant and cluster distributions. Particle formation and growth are simulated with detailed H(2)SO(4) cluster kinetics with chemistry based on measured small cluster thermodynamics and on bulk thermodynamics for large clusters. Results show that particle number densities have power law dependencies on sulfuric acid of ~7, in accord with the thermodynamics of the cluster chemistry. The region where particle formation rates are largest has a temperature that is within 3 K of the wall. Additional simulations show that the H(2)SO(4) concentration in this region is 5 to 10 times greater than the measured H(2)SO(4): this information allows for direct comparisons of experiment and theory. Experiments where ammonia was added as a third nucleating species were simulated with a three-dimensional model. Ammonia was dispersed quickly and particle formation during this mixing was seen to be low. Downstream of the initial mixing region, however, ammonia greatly affected particle formation.
Amooie, Mohammad Amin; Soltanian, Mohammad Reza; Moortgat, Joachim
2016-11-01
Fluid mixing and its interplay with viscous fingering as well as flow channeling through heterogeneous media have been traditionally studied for fully (im)miscible conditions in which a (two-) single-phase system is represented by two components, e.g. a solvent and a solute, with (zero) infinite mutual solubility. However, many subsurface problems, e.g. gas injection/migration in hydrocarbon reservoirs, involve multiple species transfer. Multicomponent fluid properties behave non-linearly, through an equation of state, as a function of temperature, pressure, and compositions. Depending on the minimum miscibility pressure, a two-phase region with finite, non-zero mutual solubility may develop, e.g. in a partially-miscible system. Here we study mixing of fluids with partial mutual solubility, induced by viscous flow fingering, channeling, and species transport within and between phases. We uncover non-linear mixing dynamics of a finite-size slug of a less viscous fluid attenuated by a carrier fluid during rectilinear displacement. We perform accurate numerical simulations that are thermodynamically-consistent to capture fingering patterns and complex phase behavior of mixtures. The results provide a broad perspective into how multiphase flow can alter fluid mixing in porous media.
Santos, Andrés; López de Haro, Mariano; Yuste, Santos B
2010-05-28
Different theoretical approaches for the thermodynamic properties and the equation of state for multicomponent mixtures of nonadditive hard spheres in d dimensions are presented in a unified way. These include the theory by Hamad, our previous formulation, the original MIX1 theory, a recently proposed modified MIX1 theory, as well as a nonlinear extension of the MIX1 theory proposed in this paper. Explicit expressions for the compressibility factor, Helmholtz free energy, and second, third, and fourth virial coefficients are provided. A comparison is carried out with recent Monte Carlo data for the virial coefficients of asymmetric mixtures and with available simulation data for the compressibility factor, the critical consolute point, and the liquid-liquid coexistence curves. The merits and limitations of each theory are pointed out.
Reference Equations of State for the Thermodynamic Properties of Fluid Phase n-Butane and Isobutane
Bücker, D.; Wagner, W.
2006-06-01
New formulations for the thermodynamic properties of fluid phase n-butane and isobutane in the form of fundamental equations explicit in the Helmholtz energy are presented. The functional form of the correlation equations for the residual parts was developed simultaneously for both substances considering data for the thermodynamic properties of ethane, propane, n-butane, and isobutane. Each contains 25 coefficients which were fitted to selected data for the thermal and caloric properties of the respective fluid both in the single-phase region and on the vapor-liquid phase boundary. This work provides information on the available experimental data for the thermodynamic properties of n- and isobutane, and presents all details of the new formulations. The new equations of state describe the pρT surfaces with uncertainties in density of 0.02% (coverage factor k=2 corresponding to a confidence level of about 95%) from the melting line up to temperatures of 340 K and pressures of 12 MPa. The available reliable data sets in other regions are represented within their experimental uncertainties. The primary data, to which the equation for n-butane was fitted, cover the fluid region from the melting line to temperatures of 575 K and pressures of 69 MPa. The equation for isobutane was fitted to primary data that cover the fluid region from the melting line to temperatures of 575 K and pressures of 35 MPa. Beyond the range described by experimental data, the equations yield reasonable extrapolation behavior up to very high temperatures and pressures. In addition to the equations of state, independent equations for the vapor pressures, the saturated-liquid and saturated-vapor densities, and the melting pressures are given. Tables of thermodynamic properties calculated from the new formulations are listed in Appendix 2. Additionally, a preliminary equation of state for propane is presented that was developed in the course of the simultaneous optimization. This equation has the
A Thermodynamically-Consistent Non-Ideal Stochastic Hard-Sphere Fluid
Donev, A; Alder, B J; Garcia, A L
2009-08-03
A grid-free variant of the Direct Simulation Monte Carlo (DSMC) method is proposed, named the Isotropic DSMC (I-DSMC) method, that is suitable for simulating collision-dominated dense fluid flows. The I-DSMC algorithm eliminates all grid artifacts from the traditional DSMC algorithm and is Galilean invariant and microscopically isotropic. The stochastic collision rules in I-DSMC are modified to introduce a non-ideal structure factor that gives consistent compressibility, as first proposed in [Phys. Rev. Lett. 101:075902 (2008)]. The resulting Stochastic Hard Sphere Dynamics (SHSD) fluid is empirically shown to be thermodynamically identical to a deterministic Hamiltonian system of penetrable spheres interacting with a linear core pair potential, well-described by the hypernetted chain (HNC) approximation. We develop a kinetic theory for the SHSD fluid to obtain estimates for the transport coefficients that are in excellent agreement with particle simulations over a wide range of densities and collision rates. The fluctuating hydrodynamic behavior of the SHSD fluid is verified by comparing its dynamic structure factor against theory based on the Landau-Lifshitz Navier-Stokes equations. We also study the Brownian motion of a nano-particle suspended in an SHSD fluid and find a long-time power-law tail in its velocity autocorrelation function consistent with hydrodynamic theory and molecular dynamics calculations.
Murad, Mohammad Hassan [BRAC University, Department of Mathematics and Natural Sciences, Dhaka (Bangladesh); Fatema, Saba [Daffodil International University, Department of Natural Sciences, Dhaka (Bangladesh)
2015-11-15
In this work some families of relativistic anisotropic charged fluid spheres have been obtained by solving the Einstein-Maxwell field equations with a preferred form of one of the metric potentials, and suitable forms of electric charge distribution and pressure anisotropy functions. The resulting equation of state (EOS) of the matter distribution has been obtained. Physical analysis shows that the relativistic stellar structure for the matter distribution considered in this work may reasonably model an electrically charged compact star whose energy density associated with the electric fields is on the same order of magnitude as the energy density of fluid matter itself (e.g., electrically charged bare strange stars). Furthermore these models permit a simple method of systematically fixing bounds on the maximum possible mass of cold compact electrically charged self-bound stars. It has been demonstrated, numerically, that the maximum compactness and mass increase in the presence of an electric field and anisotropic pressures. Based on the analytic models developed in this present work, the values of some relevant physical quantities have been calculated by assuming the estimated masses and radii of some well-known potential strange star candidates like PSR J1614-2230, PSR J1903+327, Vela X-1, and 4U 1820-30. (orig.)
Cervantes-Cota, Jorge L
2014-01-01
We review the role of fluids in cosmology by first introducing them in General Relativity and then applied to a FRW Universe's model. We describe how relativistic and non-relativistic components evolve in the background dynamics. We also introduce scalar fields to show that they are able to yield an inflationary dynamics at very early times (inflation) and late times (quintessence). Then, we proceed to study the thermodynamical properties of the fluids and, lastly, its perturbed kinematics. We make emphasis in the constrictions of parameters by recent cosmological probes.
周世琦
2003-01-01
Based on the functional integral procedure, a recently proposed bridge density function [J. Chem. Phys. 112 (2000) 8079] is developed to calculate global thermodynamic properties of non-uniform fluids. The resulting surface tension of a hard wall-hard sphere interface as a function of the bulk hard sphere fluid density is in good agreement with the available simulation data. The proposed numerical procedure from the approximation of non-uniform first=order direct correlation function to a non=uniform system with excess Helmholtz free energy is of fundamental importance for phase behaviour under the confined condition due to the fact that many available simple approximations in classical density functional theory are for non=uniform first=order direct correlation function.
Non-Perfect-Fluid Space-Times in Thermodynamic Equilibrium and Generalized Friedmann Equations
Konrad Schatz
2016-01-01
Full Text Available We determine the energy-momentum tensor of nonperfect fluids in thermodynamic equilibrium and, respectively, near to it. To this end, we derive the constitutive equations for energy density and isotropic and anisotropic pressure as well as for heat-flux from the corresponding propagation equations and by drawing on Einstein’s equations. Following Obukhov on this, we assume the corresponding space-times to be conform-stationary and homogeneous. This procedure provides these quantities in closed form, that is, in terms of the structure constants of the three-dimensional isometry group of homogeneity and, respectively, in terms of the kinematical quantities expansion, rotation, and acceleration. In particular, we find a generalized form of the Friedmann equations. As special cases we recover Friedmann and Gödel models as well as nontilted Bianchi solutions with anisotropic pressure. All of our results are derived without assuming any equations of state or other specific thermodynamic conditions a priori. For the considered models, results in literature are generalized to rotating fluids with dissipative fluxes.
Non-perfect-fluid space-times in thermodynamic equilibrium and generalized Friedmann equations
Schatz, Konrad; Chrobok, Thoralf
2014-01-01
Assuming homogeneous and parallax-free space-times, in the case of thermodynamic equilibrium, we construct the energy-momentum tensor of non-perfect fluids. To this end we derive the constitutive equations for energy density, isotropic and anisotropic pressure as well as heat-flux from the respective propagation equations. This provides these quantities in closed form, i. e. in terms of the structure constants of the three-dimensional isometry group of homogeneity and, respectively, of the kinematical quantities expansion, rotation and acceleration. Using Einstein's equations, the thereby occurring constants of integration can be determined such that one gets bounds on the kinematical quantities and finds a generalized form of the Friedmann equations. As a consequence, it is shown that, e. g., for a perfect fluid the Friedmann and G\\"odel models can be recovered. All this is derived without assuming any equations of state or other specific thermodynamic conditions, and, in principle, allows one to go beyond t...
Balsara, Dinshaw S; Garain, Sudip; Kim, Jinho
2016-01-01
In various astrophysics settings it is common to have a two-fluid relativistic plasma that interacts with the electromagnetic field. While it is common to ignore the displacement current in the ideal, classical magnetohydrodynamic limit, when the flows become relativistic this approximation is less than absolutely well-justified. In such a situation, it is more natural to consider a positively charged fluid made up of positrons or protons interacting with a negatively charged fluid made up of electrons. The two fluids interact collectively with the full set of Maxwell's equations. As a result, a solution strategy for that coupled system of equations is sought and found here. Our strategy extends to higher orders, providing increasing accuracy. Three important innovations are reported here. In our first innovation, the magnetic field within each zone is reconstructed in a divergence-free fashion while the electric field within each zone is reconstructed in a form that is consistent with Gauss' law. In our seco...
Osman, Alfatih A A; Geipel, Gerhard; Barkleit, Astrid; Bernhard, Gert
2015-02-16
Human exposure to uranium increasingly becomes a subject of interest in many scientific disciplines such as environmental medicine, toxicology, and radiation protection. Knowledge about uranium chemical binding forms(speciation) in human body fluids can be of great importance to understand not only its biokinetics but also its relevance in risk assessment and in designing decorporation therapy in the case of accidental overexposure. In this study, thermodynamic calculations of uranium speciation in relevant simulated and original body fluids were compared with spectroscopic data after ex-situ uranium addition. For the first time, experimental data on U(VI) speciation in body fluids (saliva, sweat, urine) was obtained by means of cryogenic time-resolved laser-induced fluorescence spectroscopy (cryo-TRLFS) at 153 K. By using the time dependency of fluorescence decay and the band positions of the emission spectra, various uranyl complexes were demonstrated in the studied samples. The variations of the body fluids in terms of chemical composition, pH, and ionic strength resulted in different binding forms of U(VI). The speciation of U(VI) in saliva and in urine was affected by the presence of bioorganic ligands, whereas in sweat, the distribution depends mainly on inorganic ligands. We also elucidated the role of biological buffers, i.e., phosphate (H(2)PO(4−)/HPO(4)(2−)) on U(VI) distribution, and the system Ca(2+)/UO(2)(2+)/PO(4)(3−) was discussed in detail in both saliva and urine. The theoretical speciation calculations of the main U(VI) species in the investigated body fluids were significantly consistent with the spectroscopic data. Laser fluorescence spectroscopy showed success and reliability for direct determination of U(VI) in such biological matrices with the possibility for further improvement.
KARSCH, F.
2006-03-26
At high temperatures or densities matter formed by strongly interacting elementary particles (hadronic matter) is expected to undergo a transition to a new form of matter--the quark gluon plasma--in which elementary particles (quarks and gluons) are no longer confined inside hadrons but are free to propagate in a thermal medium much larger in extent than the typical size of a hadron. The transition to this new form of matter as well as properties of the plasma phase are studied in large scale numerical calculations based on the theory of strong interactions--Quantum Chromo Dynamics (QCD). Experimentally properties of hot and dense elementary particle matter are studied in relativistic heavy ion collisions such as those currently performed at the relativistic heavy ion collider (RHIC) at BNL. We review here recent results from studies of thermodynamic properties of strongly interacting elementary particle matter performed on Teraflops-Computer. We present results on the QCD equation of state and discuss the status of studies of the phase diagram at non-vanishing baryon number density.
Statistical thermodynamics for a self-gravitating fluid of rotating particles
Escamilla, L.; Torres-Arenas, J.; Benavides, A. L. [División de Ciencias e Ingenierías Campus León, Universidad de Guanajuato, Lomas del Bosque 103, León Guanajuato (Mexico)
2013-07-23
Systems with long-range interactions (those which decay at large distances as r{sup -l}, with l≥d, where d is the dimensionality of the considered space), like gravitational or charged ones, present difficulties when treated by conventional statistical mechanics perturbation methods. In this work a self-gravitating fluid of rotating spherical particles is considered. The corresponding inter-particle potential model is a long-ranged one and was obtained from the application of the Newtonian limit to the Kerr metric. This potential has been expressed as a finite sum of hard-core Yukawa potentials. This new potential mimics the original long-ranged one and can be treated with conventional statistical mechanics methods. The first-order mean spherical approximation is applied to this potential to obtain the thermodynamic response functions.
Díez, A; Largo, J; Solana, J R
2006-08-21
Computer simulations have been performed for fluids with van der Waals potential, that is, hard spheres with attractive inverse power tails, to determine the equation of state and the excess energy. On the other hand, the first- and second-order perturbative contributions to the energy and the zero- and first-order perturbative contributions to the compressibility factor have been determined too from Monte Carlo simulations performed on the reference hard-sphere system. The aim was to test the reliability of this "exact" perturbation theory. It has been found that the results obtained from the Monte Carlo perturbation theory for these two thermodynamic properties agree well with the direct Monte Carlo simulations. Moreover, it has been found that results from the Barker-Henderson [J. Chem. Phys. 47, 2856 (1967)] perturbation theory are in good agreement with those from the exact perturbation theory.
Zaghloul, Mofreh R
2015-01-01
We present computational results and tables of the equation-of-state, thermodynamic properties, and shock Hugoniot for hot dense fluid deuterium. The present results are generated using a recently developed chemical model that takes into account different high density effects such as Coulomb interactions among charged particles, partial degeneracy, and intensive short range hard core repulsion. Internal partition functions are evaluated in a statistical-mechanically consistent way implementing recent developments in the literature. The shock Hugoniot curve derived from the present tables is in reasonable overall agreement with the Hugoniot derived from the Nova-laser shock wave experiments on liquid deuterium, showing that deuterium has a significantly higher compressibility than predicted by the SESAME tables or by Path Integral Monte Carlo (PIMC) calculations. Computational results are presented as surface plots for the dissociated fraction, degree of ionization, pressure, and specific internal energy for d...
Harko, T.; Mak, M. K.
2016-09-01
Obtaining exact solutions of the spherically symmetric general relativistic gravitational field equations describing the interior structure of an isotropic fluid sphere is a long standing problem in theoretical and mathematical physics. The usual approach to this problem consists mainly in the numerical investigation of the Tolman-Oppenheimer-Volkoff and of the mass continuity equations, which describes the hydrostatic stability of the dense stars. In the present paper we introduce an alternative approach for the study of the relativistic fluid sphere, based on the relativistic mass equation, obtained by eliminating the energy density in the Tolman-Oppenheimer-Volkoff equation. Despite its apparent complexity, the relativistic mass equation can be solved exactly by using a power series representation for the mass, and the Cauchy convolution for infinite power series. We obtain exact series solutions for general relativistic dense astrophysical objects described by the linear barotropic and the polytropic equations of state, respectively. For the polytropic case we obtain the exact power series solution corresponding to arbitrary values of the polytropic index n. The explicit form of the solution is presented for the polytropic index n=1, and for the indexes n=1/2 and n=1/5, respectively. The case of n=3 is also considered. In each case the exact power series solution is compared with the exact numerical solutions, which are reproduced by the power series solutions truncated to seven terms only. The power series representations of the geometric and physical properties of the linear barotropic and polytropic stars are also obtained.
Frutiger, Jerome; Abildskov, Jens; Sin, Gürkan
2015-01-01
Computer Aided Molecular Design (CAMD) is an important tool to generate, test and evaluate promising chemical products. CAMD can be used in thermodynamic cycle for the design of pure component or mixture working fluids in order to improve the heat transfer capacity of the system. The safety assessment of novel working fluids relies on accurate property data. Flammability data like the lower and upper flammability limit (LFL and UFL) play an important role in quantifying the risk of fire and e...
de B. Alves Leonardo S.
2013-01-01
Full Text Available The classical thermodynamic model for near critical heat transfer is an integral-differential equation with constant coefficients. It is similar to the heat equation, except for a source term containing the time derivative of the bulk temperature. Despite its simple form, analytical methods required the use of approximations to generate solutions for it, such as an approximate Fourier transformation or a numerical Laplace inversion. Recently, the Generalized Integral Transform Technique or GITT has been successfully applied to this problem, providing a highly accurate analytical solution for it and a new expression of its relaxation time. Nevertheless, very small temperature differences, on the order of mK, have to be imposed so that constant thermal properties can be assumed very close to the critical point. The present paper generalizes this study by relaxing its restriction and accounting for the strong dependence on temperature and pressure of supercritical fluid properties, demonstrating that a the GITT can be applied to realistic nonlinear unsteady compressible heat transfer in fluids with diverging thermal properties and b temperature and pressure have opposite effects on all properties, but their variation causes no additional thermo-acoustic effect, increasing the validity range of the constant property model.
Conformal anisotropic relativistic charged fluid spheres with a linear equation of state
Esculpi, M.; Alomá, E.
2010-06-01
We obtain two new families of compact solutions for a spherically symmetric distribution of matter consisting of an electrically charged anisotropic fluid sphere joined to the Reissner-Nordstrom static solution through a zero pressure surface. The static inner region also admits a one parameter group of conformal motions. First, to study the effect of the anisotropy in the sense of the pressures of the charged fluid, besides assuming a linear equation of state to hold for the fluid, we consider the tangential pressure p ⊥ to be proportional to the radial pressure p r , the proportionality factor C measuring the grade of anisotropy. We analyze the resulting charge distribution and the features of the obtained family of solutions. These families of solutions reproduce for the value C=1, the conformal isotropic solution for quark stars, previously obtained by Mak and Harko. The second family of solutions is obtained assuming the electrical charge inside the sphere to be a known function of the radial coordinate. The allowed values of the parameters pertained to these solutions are constrained by the physical conditions imposed. We study the effect of anisotropy in the allowed compactness ratios and in the values of the charge. The Glazer’s pulsation equation for isotropic charged spheres is extended to the case of anisotropic and charged fluid spheres in order to study the behavior of the solutions under linear adiabatic radial oscillations. These solutions could model some stage of the evolution of strange quark matter fluid stars.
A consistent thermodynamics of the MHD wave-heated two-fluid solar wind
I. V. Chashei
Full Text Available We start our considerations from two more recent findings in heliospheric physics: One is the fact that the primary solar wind protons do not cool off adiabatically with distance, but appear to be heated. The other one is that secondary protons, embedded in the solar wind as pick-up ions, behave quasi-isothermal at their motion to the outer heliosphere. These two phenomena must be physically closely connected with each other. To demonstrate this we solve a coupled set of enthalpy flow conservation equations for the two-fluid solar wind system consisting of primary and secondary protons. The coupling of these equations comes by the heat sources that are relevant, namely the dissipation of MHD turbulence power to the respective protons at the relevant dissipation scales. Hereby we consider both the dissipation of convected turbulences and the dissipation of turbulences locally driven by the injection of new pick-up ions into an unstable mode of the ion distribution function. Conversion of free kinetic energy of freshly injected secondary ions into turbulence power is finally followed by partial reabsorption of this energy both by primary and secondary ions. We show solutions of simultaneous integrations of the coupled set of differential thermodynamic two-fluid equations and can draw interesting conclusions from the solutions obtained. We can show that the secondary proton temperature with increasing radial distance asymptotically attains a constant value with a magnitude essentially determined by the actual solar wind velocity. Furthermore, we study the primary proton temperature within this two-fluid context and find a polytropic behaviour with radially and latitudinally variable polytropic indices determined by the local heat sources due to dissipated turbulent wave energy. Considering latitudinally variable solar wind conditions, as published by McComas et al. (2000, we also predict latitudinal variations of primary proton temperatures at
Kolesnichenko, A. V.
2010-08-01
This paper considers the modern approach to the thermodynamic modeling of developed turbulent flows of a compressible fluid based on the systematic application of the formalism of extended irreversible thermodynamics (EIT) that goes beyond the local equilibrium hypothesis, which is an inseparable attribute of classical nonequilibrium thermodynamics (CNT). In addition to the classical thermodynamic variables, EIT introduces new state parameters—dissipative flows and the means to obtain the respective evolutionary equations consistent with the second law of thermodynamics. The paper presents a detailed discussion of a number of physical and mathematical postulates and assumptions used to build a thermodynamic model of turbulence. A turbulized liquid is treated as an indiscrete continuum consisting of two thermodynamic sub-systems: an averaged motion subsystem and a turbulent chaos subsystem, where turbulent chaos is understood as a conglomerate of small-scale vortex bodies. Under the above formalism, this representation enables the construction of new models of continual mechanics to derive cause-and-effect differential equations for turbulent heat and impulse transfer, which describe, together with the averaged conservations laws, turbulent flows with transverse shear. Unlike gradient (noncausal) relationships for turbulent flows, these differential equations can be used to investigate both hereditary phenomena, i.e., phenomena with history or memory, and nonlocal and nonlinear effects. Thus, within EIT, the second-order turbulence models underlying the so-called invariant modeling of developed turbulence get a thermodynamic explanation. Since shear turbulent flows are widespread in nature, one can expect the given modification of the earlier developed thermodynamic approach to developed turbulence modeling (see Kolesnichenko, 1980; 1998; 2002-2004; Kolesnichenko and Marov, 1985; Kolesnichenko and Marov, 2009) to be used in research on a broad class of dissipative
On Radiative Fluids in Anisotropic Spacetimes
Shogin, Dmitry; Amundsen, Per Amund
2016-01-01
We apply the second-order Israel-Stewart theory of relativistic fluid- and thermodynamics to a physically realistic model of a radiative fluid in a simple anisotropic cosmological background. We investigate the asymptotic future of the resulting cosmological model and review the role of the dissipative phenomena in the early Universe. We demonstrate that the transport properties of the fluid alone, if described appropriately, do not explain the presently observed accelerated expansion of the ...
Mulyana, Cukup; Adiprana, Reza; Saad, Aswad H.; M. Ridwan, H.; Muhammad, Fajar
2016-02-01
The scarcity of fossil energy accelerates the development of geothermal power plant in Indonesia. The main issue is how to minimize the energy loss from the geothermal working fluid so that the power generated can be increased. In some of geothermal power plant, the hot water which is resulted from flashing is flown to injection well, and steam out from turbine is condensed in condenser, while the temperature and pressure of the working fluid is still high. The aim of this research is how the waste energy can be re-used as energy source to generate electric power. The step of the research is started by studying the characteristics of geothermal fluid out from the well head. The temperature of fluid varies from 140°C - 250°C, the pressure is more than 7 bar and the fluid phase are liquid, gas, or mixing phase. Dry steam power plant is selected for vapor dominated source, single or multiple flash power plant is used for dominated water with temperature > 225°C, while the binary power plant is used for low temperature of fluid power plant can be described by thermodynamic cycle. Utilizing the heat loss of the brine and by considering the broad range of working fluid temperature, the integrated geothermal power plant has been developed. Started with two ordinary single flash power plants named unit 1 and unit 2, with the temperature 250°C resulting power is W1'+W2'. The power is enhanced by utilizing the steam that is out from first stage of the turbine by inputting the steam to the third stage, the power of the plant increase with W1''+W2" or 10% from the original power. By using flasher, the water from unit 1 and 2 is re-flashed at 200°C, and the steam is used to drive the turbine in unit 3, while the water is re-flashed at the temperature170°C and the steam is flown to the same turbine (unit 3) resulting the power of W3+W4. Using the fluid enthalpy, the calculated power of these double and triple flash power plant are 50% of W1+W2. At the last step, the steam
Gögelein, Christoph; Romano, Flavio; Sciortino, Francesco; Giacometti, Achille
2012-03-01
We study the Kern-Frenkel model for patchy colloids using Barker-Henderson second-order thermodynamic perturbation theory. The model describes a fluid where hard sphere particles are decorated with one patch, so that they interact via a square-well potential if they are sufficiently close one another, and if patches on each particle are properly aligned. Both the gas-liquid and fluid-solid phase coexistences are computed and contrasted against corresponding Monte Carlo simulations results. We find that the perturbation theory describes rather accurately numerical simulations all the way from a fully covered square-well potential down to the Janus limit (half coverage). In the region where numerical data are not available (from Janus to hard-spheres), the method provides estimates of the location of the critical lines that could serve as a guideline for further efficient numerical work at these low coverages. A comparison with other techniques, such as integral equation theory, highlights the important aspect of this methodology in the present context.
Thermodynamic and fluid mechanic analysis of rapid pressurization in a dead-end tube
Leslie, Ian H.
1989-01-01
Three models have been applied to very rapid compression of oxygen in a dead-ended tube. Pressures as high as 41 MPa (6000 psi) leading to peak temperatures of 1400 K are predicted. These temperatures are well in excess of the autoignition temperature (750 K) of teflon, a frequently used material for lining hoses employed in oxygen service. These findings are in accord with experiments that have resulted in ignition and combustion of the teflon, leading to the combustion of the stainless steel braiding and catastrophic failure. The system analyzed was representative of a capped off-high-pressure oxygen line, which could be part of a larger system. Pressurization of the larger system would lead to compression in the dead-end line, and possible ignition of the teflon liner. The model consists of a large plenum containing oxygen at the desired pressure (500 to 6000 psi). The plenum is connected via a fast acting valve to a stainless steel tube 2 cm inside diameter. Opening times are on the order of 15 ms. Downstream of the valve is an orifice sized to increase filling times to around 100 ms. The total length from the valve to the dead-end is 150 cm. The distance from the valve to the orifice is 95 cm. The models describe the fluid mechanics and thermodynamics of the flow, and do not include any combustion phenomena. A purely thermodynamic model assumes filling to be complete upstream of the orifice before any gas passes through the orifice. This simplification is reasonable based on experiment and computer modeling. Results show that peak temperatures as high as 4800 K can result from recompression of the gas after expanding through the orifice. An approximate transient model without an orifice was developed assuming an isentropic compression process. An analytical solution was obtained. Results indicated that fill times can be considerably shorter than valve opening times. The third model was a finite difference, 1-D transient compressible flow model. Results from
Jover, Julio; Galindo, Amparo; Jackson, George; Müller, Erich A.; Haslam, Andrew J.
2015-09-01
Using both theory and continuum simulation, we examine a system comprising a mixture of polymer chains formed from 100 hard-sphere (HS) segments and HS colloids with a diameter which is 20 times that of the polymer segments. According to Wertheim's first-order thermodynamic perturbation theory (TPT1) this athermal system is expected to phase separate into a colloid-rich and a polymer-rich phase. Using a previously developed continuous pseudo-HS potential [J. F. Jover, A. J. Haslam, A. Galindo, G. Jackson, and E. A. Muller, J. Chem. Phys. 137, 144505 (2012)], we simulate the system at a phase point indicated by the theory to be well within the two-phase binodal region. Molecular-dynamics simulations are performed from starting configurations corresponding to completely phase-separated and completely pre-mixed colloids and polymers. Clear evidence is seen of the stabilisation of two coexisting fluid phases in both cases. An analysis of the interfacial tension of the phase-separated regions is made; ultra-low tensions are observed in line with previous values determined with square-gradient theory and experiment for colloid-polymer systems. Further simulations are carried out to examine the nature of these coexisting phases, taking as input the densities and compositions calculated using TPT1 (and corresponding to the peaks in the probability distribution of the density profiles obtained in the simulations). The polymer chains are seen to be fully penetrable by other polymers. By contrast, from the point of view of the colloids, the polymers behave (on average) as almost-impenetrable spheres. It is demonstrated that, while the average interaction between the polymer molecules in the polymer-rich phase is (as expected) soft-repulsive in nature, the corresponding interaction in the colloid-rich phase is of an entirely different form, characterised by a region of effective intermolecular attraction.
Null Fluids - A New Viewpoint of Galilean Fluids
Banerjee, Nabamita; Jain, Akash
2015-01-01
This article is a detailed version of our short letter `On equilibrium partition function for non-relativistic fluid' [arXiv:1505.05677] extended to include an anomalous $U(1)$ symmetry. We construct a relativistic system, which we call null fluid and show that it is in one-to-one correspondence with a Galilean fluid living in one lower dimension. The correspondence is based on light cone reduction, which is known to reduce the Poincare symmetry of a theory to Galilean in one lower dimension. We show that the proposed null fluid and the corresponding Galilean fluid have exactly same symmetries, thermodynamics, constitutive relations, and equilibrium partition to all orders in derivative expansion. We also devise a mechanism to introduce $U(1)$ anomaly in even dimensional Galilean theories using light cone reduction, and study its effect on the constitutive relations of a Galilean Fluid.
Thermodynamically self-consistent theories of fluids interacting through short-range forces.
Caccamo, C; Pellicane, G; Costa, D; Pini, D; Stell, G
1999-11-01
The self-consistent Ornstein-Zernike approximation (SCOZA), the generalized mean spherical approximation (GMSA), the modified hypernetted chain (MHNC) approximation, and the hierarchical reference theory (HRT) are applied to the determination of thermodynamic and structural properties, and the phase diagram of the hard-core Yukawa fluid (HCYF). We investigate different Yukawa-tail screening lengths lambda, ranging from lambda=1.8 (a value appropriate to approximate the shape of the Lennard-Jones potential) to lambda=9 (suitable for a simple one-body modelization of complex fluids like colloidal suspensions and globular protein solutions). The comparison of the results obtained with computer simulation data shows that at relatively low lambda's all the theories are fairly accurate in the prediction of thermodynamic and structural properties; as far as the phase diagram is concerned, the SCOZA and HRT are able to predict the binodal line and the critical parameters in a quantitative manner. At lambda=4 some discrepancies begin to emerge in the performances of the different theoretical approaches: the MHNC remains, on the whole, reasonably accurate in predicting the energy and the contact value of the radial distribution function; the SCOZA predicts well the equation of state up to the highest lambda values investigated. The GMSA and the MHNC underestimate and overestimate, respectively, the liquid coexisting density, while the SCOZA and HRT yield liquid branches that fall between the two former theoretical predictions, although both appear to overestimate the critical temperature somewhat. At higher lambda's the GMSA and MHNC binodals further worsen, while the SCOZA appears to remain usefully predictive. In general, the predictions of all the theories tend to slightly worsen at low temperatures and high density. The determination of the freezing line, performed by means of a one-phase "freezing criterion" (due to other authors) is not particularly satisfactory within
Cryogenic fluid management technologies for space transportation. Zero G thermodynamic vent system
1994-01-01
Long term storage of subcritical cryogens in space must address the problem of thermal stratification in the storage tanks, liquid acquisition devices, and associated feed systems. Due to the absence of gravity induced body forces, thermal stratification in zero-g is more severe than commonly experienced in a one-g environment. If left uncontrolled, the thermal gradients result in excessive tank pressure rise and the formation of undesirable liquid/vapor mixtures within the liquid bulk, liquid acquisition system, and propellant transfer lines. Since external heat leakage cannot be eliminated, a means of minimizing the thermal stratification in the ullage gas, liquid, and feed system is required. A subsystem which minimizes the thermal stratification and rejects the environmental heat leakage in an efficient manner is therefore needed for zero-g subcritical cryogenic systems. In ground based storage systems the ullage gas location is always known (top of the tank) and therefore direct venting of gases as a means of heat rejection is easily accomplished. In contrast, because the ullage location in a zero-g environment is not easily predictable, heat rejection through direct gaseous venting is difficult in space (requires liquid settling, or surface tension devices). A means of indirect venting through the use of a thermodynamic vent system (TVS) is therefore required. A thermodynamic vent system allows indirect venting of vapor through heat exchange between the vented fluid and the stored fluid. The objective is to ensure that only gas and not liquid is vented, in order to minimize the propellant losses. Consequently, the design of a TVS is a critical enabling technology for future applications such as solar thermal and electric propulsion, single-stage-to-orbit vertical landers and upper stages, and any space based operations involving subcritical cryogenics. To bridge this technology gap NASA MSFC initiated an effort to build and verify through ground tests a zero
Conformal higher-order viscoelastic fluid mechanics
Fukuma, Masafumi
2012-01-01
We present a generally covariant formulation of conformal higher-order viscoelastic fluid mechanics with strain allowed to take arbitrarily large values. We give a general prescription to determine the dynamics of a relativistic viscoelastic fluid in a way consistent with the hypothesis of local thermodynamic equilibrium and the second law of thermodynamics. We then elaborately study the transient time scales at which the strain almost relaxes and becomes proportional to the gradients of velocity. We particularly show that a conformal second-order fluid with all possible parameters in the constitutive equations can be obtained without breaking the hypothesis of local thermodynamic equilibrium, if the conformal fluid is defined as the long time limit of a conformal second-order viscoelastic system. We also discuss how local thermodynamic equilibrium could be understood in the context of the fluid/gravity correspondence.
Conformal higher-order viscoelastic fluid mechanics
Fukuma, Masafumi; Sakatani, Yuho
2012-06-01
We present a generally covariant formulation of conformal higher-order viscoelastic fluid mechanics with strain allowed to take arbitrarily large values. We give a general prescription to determine the dynamics of a relativistic viscoelastic fluid in a way consistent with the hypothesis of local thermodynamic equilibrium and the second law of thermodynamics. We then elaborately study the transient time scales at which the strain almost relaxes and becomes proportional to the gradients of velocity. We particularly show that a conformal second-order fluid with all possible parameters in the constitutive equations can be obtained without breaking the hypothesis of local thermodynamic equilibrium, if the conformal fluid is defined as the long time limit of a conformal second-order viscoelastic system. We also discuss how local thermodynamic equilibrium could be understood in the context of the fluid/gravity correspondence.
Thermodynamic bounds for existence of normal shock in compressible fluid flow in pipes
SERGIO COLLE
Full Text Available Abstract The present paper is concerned with the thermodynamic theory of the normal shock in compressible fluid flow in pipes, in the lights of the pioneering works of Lord Rayleigh and G. Fanno. The theory of normal shock in pipes is currently presented in terms of the Rayleigh and Fanno curves, which are shown to cross each other in two points, one corresponding to a subsonic flow and the other corresponding to a supersonic flow. It is proposed in this paper a novel differential identity, which relates the energy flux density, the linear momentum flux density, and the entropy, for constant mass flow density. The identity so obtained is used to establish a theorem, which shows that Rayleigh and Fanno curves become tangent to each other at a single sonic point. At the sonic point the entropy reaches a maximum, either as a function of the pressure and the energy density flux or as a function of the pressure and the linear momentum density flux. A Second Law analysis is also presented, which is fully independent of the Second Law analysis based on the Rankine-Hugoniot adiabatic carried out by Landau and Lifshitz (1959.
Thermodynamic bounds for existence of normal shock in compressible fluid flow in pipes.
Colle, Sergio
2017-01-01
The present paper is concerned with the thermodynamic theory of the normal shock in compressible fluid flow in pipes, in the lights of the pioneering works of Lord Rayleigh and G. Fanno. The theory of normal shock in pipes is currently presented in terms of the Rayleigh and Fanno curves, which are shown to cross each other in two points, one corresponding to a subsonic flow and the other corresponding to a supersonic flow. It is proposed in this paper a novel differential identity, which relates the energy flux density, the linear momentum flux density, and the entropy, for constant mass flow density. The identity so obtained is used to establish a theorem, which shows that Rayleigh and Fanno curves become tangent to each other at a single sonic point. At the sonic point the entropy reaches a maximum, either as a function of the pressure and the energy density flux or as a function of the pressure and the linear momentum density flux. A Second Law analysis is also presented, which is fully independent of the Second Law analysis based on the Rankine-Hugoniot adiabatic carried out by Landau and Lifshitz (1959).
Thermodynamic properties of a geothermal working fluid; 90% isobutane-10% isopentane: Final report
Gallagher, J.S.; Linsky, D.; Morrison, G.; Levelt Sengers, J.M.H.
1987-04-01
We present tables of thermodynamic properties, and dew and bubble properties, of a mixture of 90 mol % isobutane and 10 mol % isopentane, a working fluid in a binary geothermal power cycle. The tables are generated by a formulation of the Helmholtz free energy, in which the mixture properties are mapped onto the known properties of pure isobutane by means of the principle of generalized corresponding states. The data base for the Helmholtz free energy formulation is new. We report data obtained in three different apparatus: critical-line and isopentane vapor pressure data obtained in a visual cell; vapor-liquid equilibria data obtained in a mercury-operated variable-volume cell; and pressure-volume-temperature data for the 90 mol %-10 mol % mixture obtained in a semi-automated Burnett-isochoric apparatus. The principles of the methods, and estimates of the reliability, are discussed and all experimental data are compared with the surface. The results are tables of specific volume, enthalpy, entropy, specific heat and density and temperature derivatives of the pressure at 10 K temperature increments from 240 to 600 K along isobars from 0.01 to 20 MPa. Separate tables are prepared from the dew and bubble properties of the 90-10 mixture. Estimates of the effects of isomeric impurity of isobutane are given in graphical form.
Zaghloul, Mofreh R. [Department of Physics, College of Science, United Arab Emirates University, P.O. Box 15551, Al-Ain (United Arab Emirates)
2015-11-15
We present computational results and tables of the equation-of-state, thermodynamic properties, and shock Hugoniot for hot dense fluid deuterium. The present results are generated using a recently developed chemical model that takes into account different high density effects such as Coulomb interactions among charged particles, partial degeneracy, and intensive short range hard core repulsion. Internal partition functions are evaluated in a statistical-mechanically consistent way implementing recent developments in the literature. The shock Hugoniot curve derived from the present tables is overall in reasonable agreement with the Hugoniot derived from the Nova-laser shock wave experiments on liquid deuterium, showing that deuterium has a significantly higher compressibility than predicted by the SESAME tables or by Path Integral Monte Carlo calculations. Computational results are presented as surface plots for the dissociated fraction, degree of ionization, pressure, and specific internal energy for densities ranging from 0.0001 to 40 g/cm{sup 3} and temperatures from 2000 to ∼10{sup 6 }K. Tables for values of the above mentioned quantities in addition to the specific heat at constant pressure, c{sub p}, ratio of specific heats, c{sub p}/c{sub v}, sound speed and Hugoniot curve (for a specific initial state) are presented for practical use.
Quasi-chemical Theory for the Statistical Thermodynamics of the Hard Sphere Fluid
Pratt, L R; Gómez, M A; Gentile, M E; Pratt, Lawrence R.; Violette, Randall A. La; Gomez, Maria A.; Gentile, Mary E.
2001-01-01
We develop a quasi-chemical theory for the study of packing thermodynamics in dense liquids. The situation of hard-core interactions is addressed by considering the binding of solvent molecules to a precisely defined `cavity' in order to assess the probability that the `cavity' is entirely evacuated. The primitive quasi-chemical approximation corresponds to a extension of the Poisson distribution used as a default model in an information theory approach. This primitive quasi-chemical theory is in good qualitative agreement with the observations for the hard sphere fluid of occupancy distributions that are central to quasi-chemical theories but begins to be quantitatively erroneous for the equation of state in the dense liquid regime of $\\rho d^3>$0.6. How the quasi-chemical approach can be iterated to treat correlation effects is addressed. Consideration of neglected correlation effects leads to a simple model for the form of those contributions neglected by the primitive quasi-chemical approximation. These c...
Viscosity spectral function of a scale invariant non-relativistic fluid from holography
Schaefer, Thomas
2014-01-01
We study the viscosity spectral function of a holographic 2+1 dimensional fluid with Schroedinger symmetry. The model is based on a twisted compactification of $Ads_5\\times S_5$. We numerically compute the spectral function of the stress tensor correlator for all frequencies, and analytically study the limits of high and low frequency. We compute the shear viscosity, the viscous relaxation time, and the quasi-normal mode spectrum in the shear channel. We find a number of unexpected results: The high frequency behavior is governed by a fractional 1/3 power law, the viscous relaxation time is negative, and the quasi-normal mode spectrum in the shear channel is not doubled.
Studies of Entanglement Entropy, and Relativistic Fluids for Thermal Field Theories
Spillane, Michael
In this dissertation we consider physical consequences of adding a finite temperature to quantum field theories. At small length scales entanglement is a critically important feature. It is therefore unsurprising that entanglement entropy and Renyi entropy are useful tools in studying quantum phase transition, and quantum information. In this thesis we consider the corrections to entanglement and Renyi entropies due to addition of a finite temperature. More specifically, we investigate the entanglement entropy of a massive scalar field in 1+1 dimensions at nonzero temperature. In the small mass ( m) and temperature (T) limit, we put upper and lower bounds on the two largest eigenvalues of the covariance matrix used to compute the entanglement entropy. We argue that the entanglement entropy has e-m/T scaling in the limit T blackhole. We discuss the "phase diagram" associated with the steady state of the dual, dynamical black hole and its relation to the fluid/gravity correspondence.
Müller, Ingo
1993-01-01
Physicists firmly believe that the differential equations of nature should be hyperbolic so as to exclude action at a distance; yet the equations of irreversible thermodynamics - those of Navier-Stokes and Fourier - are parabolic. This incompatibility between the expectation of physicists and the classical laws of thermodynamics has prompted the formulation of extended thermodynamics. After describing the motifs and early evolution of this new branch of irreversible thermodynamics, the authors apply the theory to mon-atomic gases, mixtures of gases, relativistic gases, and "gases" of phonons and photons. The discussion brings into perspective the various phenomena called second sound, such as heat propagation, propagation of shear stress and concentration, and the second sound in liquid helium. The formal mathematical structure of extended thermodynamics is exposed and the theory is shown to be fully compatible with the kinetic theory of gases. The study closes with the testing of extended thermodynamics thro...
Mathematical foundations of thermodynamics
Giles, R; Stark, M; Ulam, S
2013-01-01
Mathematical Foundations of Thermodynamics details the core concepts of the mathematical principles employed in thermodynamics. The book discusses the topics in a way that physical meanings are assigned to the theoretical terms. The coverage of the text includes the mechanical systems and adiabatic processes; topological considerations; and equilibrium states and potentials. The book also covers Galilean thermodynamics; symmetry in thermodynamics; and special relativistic thermodynamics. The book will be of great interest to practitioners and researchers of disciplines that deal with thermodyn
A variational approach to resistive relativistic plasmas
Andersson, N; Hawke, I
2016-01-01
We develop an action principle to construct the field equations for a multi-fluid system containing charge-neutral fluids, plasmas, and dissipation (via resistive interactions), by combining the standard, Maxwell action and minimal coupling of the electromagnetic field with a recently developed action for relativistic dissipative fluids. We use a pull-back formalism from spacetime to abstract matter spaces to build unconstrained variations for both the charge-neutral fluids and currents making up the plasmas. Using basic linear algebra techniques, we show that a general "relabeling" invariance exists for the abstract matter spaces. With the field equations in place, a phenomenological model for the resistivity is developed, using as constraints charge conservation and the Second Law of Thermodynamics. A minimal model for a system of electrons, protons, and heat is developed using the Onsager procedure for incorporating dissipation.
A variational approach to resistive relativistic plasmas
Andersson, N.; Comer, G. L.; Hawke, I.
2017-06-01
We develop an action principle to construct the field equations for a multi-fluid system containing charge-neutral fluids, plasmas, and dissipation (via resistive interactions), by combining the standard, Maxwell action and minimal coupling of the electromagnetic field with a recently developed action for relativistic dissipative fluids. We use a pull-back formalism from spacetime to abstract matter spaces to build unconstrained variations for both the charge-neutral fluids and currents making up the plasmas. Using basic linear algebra techniques, we show that a general ‘relabeling’ invariance exists for the abstract matter spaces. With the field equations in place, a phenomenological model for the resistivity is developed, using as constraints charge conservation and the Second Law of Thermodynamics. A minimal model for a system of electrons, protons, and heat is developed using the Onsager procedure for incorporating dissipation.
Bakker, R.J.
1992-01-01
Fluids in rocks can be traced to great depths, and are found in crustal rocks as well as in mantle rocks. Information about the deep fluid which is obtained from fluid inclusions must be handled with care, for the way up after entrapment in a crystal is long and full of interferences at different pr
Ustinov, E. A.
2017-01-01
The paper aims at a comparison of techniques based on the kinetic Monte Carlo (kMC) and the conventional Metropolis Monte Carlo (MC) methods as applied to the hard-sphere (HS) fluid and solid. In the case of the kMC, an alternative representation of the chemical potential is explored [E. A. Ustinov and D. D. Do, J. Colloid Interface Sci. 366, 216 (2012)], which does not require any external procedure like the Widom test particle insertion method. A direct evaluation of the chemical potential of the fluid and solid without thermodynamic integration is achieved by molecular simulation in an elongated box with an external potential imposed on the system in order to reduce the particle density in the vicinity of the box ends. The existence of rarefied zones allows one to determine the chemical potential of the crystalline phase and substantially increases its accuracy for the disordered dense phase in the central zone of the simulation box. This method is applicable to both the Metropolis MC and the kMC, but in the latter case, the chemical potential is determined with higher accuracy at the same conditions and the number of MC steps. Thermodynamic functions of the disordered fluid and crystalline face-centered cubic (FCC) phase for the hard-sphere system have been evaluated with the kinetic MC and the standard MC coupled with the Widom procedure over a wide range of density. The melting transition parameters have been determined by the point of intersection of the pressure-chemical potential curves for the disordered HS fluid and FCC crystal using the Gibbs-Duhem equation as a constraint. A detailed thermodynamic analysis of the hard-sphere fluid has provided a rigorous verification of the approach, which can be extended to more complex systems.
Konrad-Schmolke, M.; Jahn, S.
2012-12-01
The subduction of oceanic lithosphere induces one of the major element cycles on Earth. Devolatilisation reactions in the subducted plate, the associated major and trace element transport as well as fluid-rock interaction within the slab and the mantle wedge control the flux of matter from the down-going plate into the upper plate and the atmosphere. Prediction and quantification of these fluxes is therefore a fundamental task in geosciences. The amount and composition of liberated fluids in a subducted slab is controlled by thermodynamic constraints, the fluid-rock element distribution as well as reaction kinetics in the affected rocks. Consequently, prediction of the element transfer within the slab and into the overlying rocks must consider these processes and their complex interactions. In this contribution we focus on the thermodynamic constraints on devolatilisation reactions in slab-crust and -mantle, the associated fluid migration and the chemical aspect of fluid-rock interaction within a hydrated subducted plate. Based on numerically modeled isotherm patterns of contrasting subduction settings we calculate phase relations in different layers of the subducted slabs. We use incremental Gibbs energy minimisation models and consider upward migration of liberated fluids during subduction. Moreover, modeled phase relations, fluid amounts and trace element partition coefficients, are used to calculate mass balanced distribution of fluid-mobile trace elements among the stable phases within the slab. Trace element transport occurs within the migrating fluid phase that equilibrates with the wall rock during ascent. This process controls element depletion and/or enrichment of fluid and wall rock and enables detailed prediction of the trace element transfer along the slab mantle interface. Our results show that fluid fluxes at the slab surface are clearly bimodal: at fore-arc depths water is continuously released predominantly from the MORB layer whereas at sub- and
Equilibrium and non-equilibrium properties of a relativistic gas at the transition temperature
Chacón-Acosta, Guillermo
2016-11-01
The Jüttner distribution function for equilibrium relativistic fluids has two well-known limits, the non-relativistic limit at low temperatures and ultra-relativistic limit for high temperatures. Recently, the description of this transition in velocity space in the system, from a gaussian to a bimodal distribution was made by Mendoza et al. Physically, it is a transition between a regime where the relativistic energy is dominated by kinetic to another where the rest energy dominates. It has been found that the critical temperature at which the relativistic corrections becomes relevant, depends just on the dimension of the system, this allowed a description in terms of the theory of critical points (Montakhab et al.). In this contribution a review of the thermodynamic quantities that are only dependent on the ratio between temperature and critical temperature, and the dimension is made. We will also analyze the effects of critical temperature on dissipative processes in simple special relativistic fluids. Particularly, purely relativistic terms that are usually proportional to the number density gradient are studied. The transport coefficients can be written in terms of the transition temperature, this will allow us to identify the lower order relativistic effects just in terms of the dimension of the system.
Brun-Battistini, D; Sandoval-Villalbazo, A
2016-01-01
Richard C. Tolman analyzed the relation between a temperature gradient and a gravitational field in an equilibrium situation. In 2012, Tolman\\textquoteright s law was generalized to a non-equilibrium situation for a simple dilute relativistic fluid. The result in that scenario, obtained by introducing the gravitational force through the molecular acceleration, couples the heat flux with the metric coefficients and the gradients of the state variables. In the present paper it is shown, by \\textquotedblleft suppressing\\textquotedblright{} the molecular acceleration in Boltzmann\\textquoteright s equation, that a gravitational field drives a heat flux. This procedure corresponds to the description of particle motion through geodesics, in which a Newtonian limit to the Schwarzschild metric is assumed. The effect vanishes in the non-relativistic regime, as evidenced by the direct evaluation of the corresponding limit.
Huggins, David J
2012-11-21
The structures of biomolecules and the strengths of association between them depend critically on interactions with water molecules. Thus, understanding these interactions is a prerequisite for understanding the structure and function of all biomolecules. Inhomogeneous fluid solvation theory provides a framework to derive thermodynamic properties of individual water molecules from a statistical mechanical analysis. In this work, two biomolecules are analysed to probe the distribution and thermodynamics of surrounding water molecules. The great majority of hydration sites are predicted to contribute favourably to the total free energy with respect to bulk water, though hydration sites close to non-polar regions of the solute do not contribute significantly. Analysis of a biomolecule with a positively and negatively charged functional group predicts that a charged species perturbs the free energy of water molecules to a distance of approximately 6.0 Å. Interestingly, short simulations are found to provide converged predictions if samples are taken with sufficient frequency, a finding that has the potential to significantly reduce the required computational cost of such analysis. In addition, the predicted thermodynamic properties of hydration sites with the potential for direct hydrogen bonding interactions are found to disagree significantly for two different water models. This study provides important information on how inhomogeneous fluid solvation theory can be employed to understand the structures and intermolecular interactions of biomolecules.
On Radiative Fluids in Anisotropic Spacetimes
Shogin, Dmitry
2016-01-01
We apply the second-order Israel-Stewart theory of relativistic fluid- and thermodynamics to a physically realistic model of a radiative fluid in a simple anisotropic cosmological background. We investigate the asymptotic future of the resulting cosmological model and review the role of the dissipative phenomena in the early Universe. We demonstrate that the transport properties of the fluid alone, if described appropriately, do not explain the presently observed accelerated expansion of the Universe. Also, we show that, in constrast to the mathematical fluid models widely used before, the radiative fluid does approach local thermal equilibrium at late times, although very slowly, due to the cosmological expansion.
Relativistic magnetohydrodynamics
Hernandez, Juan; Kovtun, Pavel
2017-05-01
We present the equations of relativistic hydrodynamics coupled to dynamical electromagnetic fields, including the effects of polarization, electric fields, and the derivative expansion. We enumerate the transport coefficients at leading order in derivatives, including electrical conductivities, viscosities, and thermodynamic coefficients. We find the constraints on transport coefficients due to the positivity of entropy production, and derive the corresponding Kubo formulas. For the neutral state in a magnetic field, small fluctuations include Alfvén waves, magnetosonic waves, and the dissipative modes. For the state with a non-zero dynamical charge density in a magnetic field, plasma oscillations gap out all propagating modes, except for Alfvén-like waves with a quadratic dispersion relation. We relate the transport coefficients in the "conventional" magnetohydrodynamics (formulated using Maxwell's equations in matter) to those in the "dual" version of magnetohydrodynamics (formulated using the conserved magnetic flux).
Balsara, Dinshaw S.; Amano, Takanobu; Garain, Sudip; Kim, Jinho
2016-08-01
In various astrophysics settings it is common to have a two-fluid relativistic plasma that interacts with the electromagnetic field. While it is common to ignore the displacement current in the ideal, classical magnetohydrodynamic limit, when the flows become relativistic this approximation is less than absolutely well-justified. In such a situation, it is more natural to consider a positively charged fluid made up of positrons or protons interacting with a negatively charged fluid made up of electrons. The two fluids interact collectively with the full set of Maxwell's equations. As a result, a solution strategy for that coupled system of equations is sought and found here. Our strategy extends to higher orders, providing increasing accuracy. The primary variables in the Maxwell solver are taken to be the facially-collocated components of the electric and magnetic fields. Consistent with such a collocation, three important innovations are reported here. The first two pertain to the Maxwell solver. In our first innovation, the magnetic field within each zone is reconstructed in a divergence-free fashion while the electric field within each zone is reconstructed in a form that is consistent with Gauss' law. In our second innovation, a multidimensionally upwinded strategy is presented which ensures that the magnetic field can be updated via a discrete interpretation of Faraday's law and the electric field can be updated via a discrete interpretation of the generalized Ampere's law. This multidimensional upwinding is achieved via a multidimensional Riemann solver. The multidimensional Riemann solver automatically provides edge-centered electric field components for the Stokes law-based update of the magnetic field. It also provides edge-centered magnetic field components for the Stokes law-based update of the electric field. The update strategy ensures that the electric field is always consistent with Gauss' law and the magnetic field is always divergence-free. This
Balsara, Dinshaw S., E-mail: dbalsara@nd.edu [Physics Department, University of Notre Dame (United States); Amano, Takanobu, E-mail: amano@eps.s.u-tokyo.ac.jp [Department of Earth and Planetary Science, University of Tokyo, Tokyo 113-0033 (Japan); Garain, Sudip, E-mail: sgarain@nd.edu [Physics Department, University of Notre Dame (United States); Kim, Jinho, E-mail: jkim46@nd.edu [Physics Department, University of Notre Dame (United States)
2016-08-01
In various astrophysics settings it is common to have a two-fluid relativistic plasma that interacts with the electromagnetic field. While it is common to ignore the displacement current in the ideal, classical magnetohydrodynamic limit, when the flows become relativistic this approximation is less than absolutely well-justified. In such a situation, it is more natural to consider a positively charged fluid made up of positrons or protons interacting with a negatively charged fluid made up of electrons. The two fluids interact collectively with the full set of Maxwell's equations. As a result, a solution strategy for that coupled system of equations is sought and found here. Our strategy extends to higher orders, providing increasing accuracy. The primary variables in the Maxwell solver are taken to be the facially-collocated components of the electric and magnetic fields. Consistent with such a collocation, three important innovations are reported here. The first two pertain to the Maxwell solver. In our first innovation, the magnetic field within each zone is reconstructed in a divergence-free fashion while the electric field within each zone is reconstructed in a form that is consistent with Gauss' law. In our second innovation, a multidimensionally upwinded strategy is presented which ensures that the magnetic field can be updated via a discrete interpretation of Faraday's law and the electric field can be updated via a discrete interpretation of the generalized Ampere's law. This multidimensional upwinding is achieved via a multidimensional Riemann solver. The multidimensional Riemann solver automatically provides edge-centered electric field components for the Stokes law-based update of the magnetic field. It also provides edge-centered magnetic field components for the Stokes law-based update of the electric field. The update strategy ensures that the electric field is always consistent with Gauss' law and the magnetic field is
Bonnaud, G.; Dussy, S.; Lefebvre, E. [CEA Bruyeres-le-Chatel, 91 (France). Dept. de Physique Theorique et Appliquee; Bouchut, F. [Orleans Univ., 45 (France). Dept. de Mathematiques, UMR CNRS
1998-12-31
This report presents a numerical model to simulate the electromagnetic processes involved by electrically-charged relativistic fluids. The physical model is first given. Second, the numerical methods are explained with the various packages of the code RHEA, with indication methods are explained with the various packages of the code RHEA, with indication of its performances, within a 1.5.- dimensional framework. Results from test-simulations are shown to validate the use of the code, for both academic situations and realistic context of laser-plasma interaction, for which the code has been designed: the non-linear phenomena in the context of inertial confinement fusion and the ultra-intense laser pulses. (author) 25 refs.
Bonnaud, G.; Dussy, S.; Lefebvre, E. [CEA Bruyeres-le-Chatel, 91 (France). Dept. de Physique Theorique et Appliquee; Bouchut, F. [Orleans Univ., 45 (France). Dept. de Mathematiques, UMR CNRS
1998-12-31
This report presents a numerical model to simulate the electromagnetic processes involved by electrically-charged relativistic fluids. The physical model is first given. Second, the numerical methods are explained with the various packages of the code RHEA, with indication methods are explained with the various packages of the code RHEA, with indication of its performances, within a 1.5.- dimensional framework. Results from test-simulations are shown to validate the use of the code, for both academic situations and realistic context of laser-plasma interaction, for which the code has been designed: the non-linear phenomena in the context of inertial confinement fusion and the ultra-intense laser pulses. (author) 25 refs.
van Swol, F. [Illinois Univ., Urbana, IL (United States). Dept. of Chemical Engineering; Eckert, C.A. [Georgia Inst. of Tech., Atlanta, GA (United States). School of Chemical Engineering
1988-09-15
The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)
Behnejad, Hassan; Cheshmpak, Hashem; Jamali, Asma
2015-01-01
In this paper, a theoretical method has been introduced for developing the crossover Peng-Robinson (CPR) equation of state (EoS) which incorporates the non-classical scaling laws asymptotically near the critical point into a classical analytic equation further away from the critical point. The CPR EoS has been adopted to describe the thermodynamic properties of some pure fluids (normal alkanes from methane to n-butane and carbon dioxide) such as density, saturated pressure, isochoric heat capacity and speed of sound. Unlike the original method for the crossover transformation made by Chen et al. (Phys Rev A 42:4470-4484, 1990), we have proposed a procedure which adding an additional term into the crossover transformation to obtain the thermophysical properties at the critical point more exactly. It is shown that this new crossover method yields a satisfactory representation of the thermodynamic properties close to the critical point for pure fluids relative to the original PR EoS.
Rodríguez-López, Tonalli; Moreno-Razo, J. Antonio; del Río, Fernando
2013-03-01
In this work, we explore transport properties of a special type of repulsive spheres that exhibit remarkable scaling of their thermodynamic properties. In order to accomplish that we propose a new way to derive and express effective hard-sphere diameters for transport properties of simple fluids. The procedure relies on mapping the system's transport properties, in the low density limit, to the hard-sphere fluid. We have chosen a set of soft-sphere systems characterised by a well-defined variation of their softness. These systems represent an extension of the repulsive Lennard-Jones potential widely used in statistical mechanics of fluids and are an accurate representation of the effective repulsive potentials of real systems. The self-diffusion coefficient of the soft-sphere fluids is obtained by equilibrium molecular dynamics. The soft-sphere collision integrals of different systems are shown to follow quite simple relationships between each other. These collision integrals are incorporated, through the definition of the effective hard-sphere diameter, in the resulting equation for the self-diffusion coefficient. The approach followed exhibits a density rescaling that leads to a single master curve for all systems and temperatures. The scaling is carried through to the level of the mean-squared displacement.
Heidenreich, Sebastian
2008-02-01
Full Text Available Shear thickening, i.e. the increase of the viscosity with increasing shear rate as it occurs in dense colloidal dispersions and polymeric fluids is an intriguing phenomenon with a considerable potential for technical applications. The theoretical description of this phenomenon is patterned after the thermodynamic and mesoscopic modeling of the orientational dynamics and the flow behavior of liquid crystals in the isotropic and nematic phases, where the theoretical basis is well-established. Even there the solutions of the relevant equations recently yielded surprises: not only stable flow alignment and a periodic behavior (tumbling are found as response to an imposed stationary shear flow but also irregular and chaotic dynamics occurs for certain parameter ranges. To treat shear-thickening fluids, a non-linear Maxwell model equation for the symmetric traceless part of the stress tensor has been proposed in analogy to the equations obeyed by the alignment tensor of nematics. The fluid-solid transition is formally analogous to the isotropic-nematic transition. In addition to shear-thickening and shear-thinning fluids, substances with yield stress can be modeled. Furthermore, periodic stick-slip-like motions and also chaotic behavior are found. In the latter cases, the instantaneous entropy production is not always positive. Yet it is comforting that its long-time average is in accord with the second law.
Cosmological particle production and generalized thermodynamic equilibrium
Zimdahl, W
1998-01-01
With the help of a conformal, timelike Killing-vector we define generalized equilibrium states for cosmological fluids with particle production. For massless particles the generalized equilibrium conditions require the production rate to vanish and the well known ``global'' equilibrium of standard relativistic thermodynamics is recovered as a limiting case. The equivalence between the creation rate for particles with nonzero mass and an effective viscous fluid pressure follows as a consequence of the generalized equilibrium properties. The implications of this equivalence for the cosmological dynamics are discussed, including the possibility of a power-law inflationary behaviour. For a simple gas a microscopic derivation for such kind of equilibrium is given on the basis of relativistic kinetic theory.
Fast lattice Boltzmann solver for relativistic hydrodynamics.
Mendoza, M; Boghosian, B M; Herrmann, H J; Succi, S
2010-07-01
A lattice Boltzmann formulation for relativistic fluids is presented and numerically validated through quantitative comparison with recent hydrodynamic simulations of relativistic fluids. In order to illustrate its capability to handle complex geometries, the scheme is also applied to the case of a three-dimensional relativistic shock wave, generated by a supernova explosion, impacting on a massive interstellar cloud. This formulation opens up the possibility of exporting the proven advantages of lattice Boltzmann methods, namely, computational efficiency and easy handling of complex geometries, to the context of (mildly) relativistic fluid dynamics at large, from quark-gluon plasmas up to supernovae with relativistic outflows.
S. A. El-Wakil
2012-01-01
Full Text Available The reductive perturbation method has been employed to derive the Korteweg-de Vries (KdV equation for small- but finite-amplitude electrostatic ion-acoustic waves in weakly relativistic plasma consisting of warm ions and isothermal electrons. An algebraic method with computerized symbolic computation is applied in obtaining a series of exact solutions of the KdV equation. Numerical studies have been made using plasma parameters which reveal different solutions, that is, bell-shaped solitary pulses, rational pulses, and solutions with singularity at finite points, which called “blowup” solutions in addition to the propagation of an explosive pulses. The weakly relativistic effect is found to significantly change the basic properties (namely, the amplitude and the width of the ion-acoustic waves. The result of the present investigation may be applicable to some plasma environments, such as ionosphere region.
Momentum and charge transport in non-relativistic holographic fluids from Ho\\v{r}ava gravity
Davison, Richard A; Janiszewski, Stefan; Kaminski, Matthias
2016-01-01
We study the linearized transport of transverse momentum and charge in a conjectured field theory dual to a black brane solution of Ho\\v{r}ava gravity with Lifshitz exponent $z=1$. As expected from general hydrodynamic reasoning, we find that both of these quantities are diffusive over distance and time scales larger than the inverse temperature. We compute the diffusion constants and conductivities of transverse momentum and charge, as well the ratio of shear viscosity to entropy density, and find that they differ from their relativistic counterparts. To derive these results, we propose how the holographic dictionary should be modified to deal with the multiple horizons and differing propagation speeds of bulk excitations in Ho\\v{r}ava gravity. When possible, as a check on our methods and results, we use the covariant Einstein-Aether formulation of Ho\\v{r}ava gravity, along with field redefinitions, to re-derive our results from a relativistic bulk theory.
Coe, Joshua D; Sewell, Thomas D; Shaw, M Sam
2009-08-21
An optimized variant of the nested Markov chain Monte Carlo [n(MC)(2)] method [J. Chem. Phys. 130, 164104 (2009)] is applied to fluid N(2). In this implementation of n(MC)(2), isothermal-isobaric (NPT) ensemble sampling on the basis of a pair potential (the "reference" system) is used to enhance the efficiency of sampling based on Perdew-Burke-Ernzerhof density functional theory with a 6-31G(*) basis set (PBE6-31G(*), the "full" system). A long sequence of Monte Carlo steps taken in the reference system is converted into a trial step taken in the full system; for a good choice of reference potential, these trial steps have a high probability of acceptance. Using decorrelated samples drawn from the reference distribution, the pressure and temperature of the full system are varied such that its distribution overlaps maximally with that of the reference system. Optimized pressures and temperatures then serve as input parameters for n(MC)(2) sampling of dense fluid N(2) over a wide range of thermodynamic conditions. The simulation results are combined to construct the Hugoniot of nitrogen fluid, yielding predictions in excellent agreement with experiment.
Null fluids: A new viewpoint of Galilean fluids
Banerjee, Nabamita; Dutta, Suvankar; Jain, Akash
2016-05-01
In this article, we study a Galilean fluid with a conserved U (1 ) current up to anomalies. We construct a relativistic system, which we call a null fluid and show that it is in one-to-one correspondence with a Galilean fluid living in one lower dimension. The correspondence is based on light cone reduction, which is known to reduce the Poincaré symmetry of a theory to Galilean in one lower dimension. We show that the proposed null fluid and the corresponding Galilean fluid have exactly same symmetries, thermodynamics, constitutive relations, and equilibrium partition to all orders in the derivative expansion. We also devise a mechanism to introduce U (1 ) anomaly in even dimensional Galilean theories using light cone reduction, and study its effect on the constitutive relations of a Galilean fluid.
Thermodynamic of fluids from a general equation of state: The molecular discrete perturbation theory
Gámez, Francisco, E-mail: fgammar@upo.es [C/ Clavel 101, Mairena del Aljarafe, 41927 Seville (Spain)
2014-06-21
An extensive generalisation of the discrete perturbation theory for molecular multipolar non-spherical fluids is presented. An analytical expression for the Helmholtz free energy for an equivalent discrete potential is given as a function of density, temperature, and intermolecular parameters with implicit shape and multipolar dependence. By varying the intermolecular parameters through their geometrical and multipolar dependence, a set of molecular fluids are considered and their vapor–liquid phase diagrams are tested against available simulation data. Concretely, multipolar and non-polar Kihara and chainlike fluids are tested and it is found that this theoretical approach is able to reproduce qualitatively and quantitatively well the Monte Carlo data for the selected molecular potentials, except near the critical region.
M. Moradi
2007-06-01
Full Text Available In this paper, a uniform classical fluid mixture comprising ellipsoidal molecules is studied. This mixture is composed of two types of ellipsoidal molecules interacting through the Gay-Berne potential with different sizes at temperature T. For this system, the Ornstein-Zernike equation using the Percus-Yevick closure relation is solved. Then the direct correlation function, pair correlation function and the pressure of the fluid at temperature T are calculated. The obtained results are in agreement with the previous theories and the results of molecular dynamic computer simulation.
Bharate, Sonali S; Vishwakarma, Ram A
2015-04-01
An early prediction of solubility in physiological media (PBS, SGF and SIF) is useful to predict qualitatively bioavailability and absorption of lead candidates. Despite of the availability of multiple solubility estimation methods, none of the reported method involves simplified fixed protocol for diverse set of compounds. Therefore, a simple and medium-throughput solubility estimation protocol is highly desirable during lead optimization stage. The present work introduces a rapid method for assessment of thermodynamic equilibrium solubility of compounds in aqueous media using 96-well microplate. The developed protocol is straightforward to set up and takes advantage of the sensitivity of UV spectroscopy. The compound, in stock solution in methanol, is introduced in microgram quantities into microplate wells followed by drying at an ambient temperature. Microplates were shaken upon addition of test media and the supernatant was analyzed by UV method. A plot of absorbance versus concentration of a sample provides saturation point, which is thermodynamic equilibrium solubility of a sample. The established protocol was validated using a large panel of commercially available drugs and with conventional miniaturized shake flask method (r(2)>0.84). Additionally, the statistically significant QSPR models were established using experimental solubility values of 52 compounds.
An Analysis of the Thermodynamic Cycle and Possible Working Fluids for a Space Heat Rejection System
1960-08-12
absorption cross section - the neutron absorption cross section should be low to assure reliable long-term operation with the nuclear re- actor heat...and structure. For the power cycle as considered In this paper, the fol- lowing properties of the working fluid are also of interest: (1) Neutron
Radhakrishnan, Ravi; Yu, Hsiu-Yu; Eckmann, David M; Ayyaswamy, Portonovo S
2017-03-01
Traditionally, the numerical computation of particle motion in a fluid is resolved through computational fluid dynamics (CFD). However, resolving the motion of nanoparticles poses additional challenges due to the coupling between the Brownian and hydrodynamic forces. Here, we focus on the Brownian motion of a nanoparticle coupled to adhesive interactions and confining-wall-mediated hydrodynamic interactions. We discuss several techniques that are founded on the basis of combining CFD methods with the theory of nonequilibrium statistical mechanics in order to simultaneously conserve thermal equipartition and to show correct hydrodynamic correlations. These include the fluctuating hydrodynamics (FHD) method, the generalized Langevin method, the hybrid method, and the deterministic method. Through the examples discussed, we also show a top-down multiscale progression of temporal dynamics from the colloidal scales to the molecular scales, and the associated fluctuations, hydrodynamic correlations. While the motivation and the examples discussed here pertain to nanoscale fluid dynamics and mass transport, the methodologies presented are rather general and can be easily adopted to applications in convective heat transfer.
Thermodynamic Cycles using Carbon Dioxide as Working Fluid : CO2 transcritical power cycle study
Yang, Chen
2011-01-01
The interest in utilizing the energy in low‐grade heat sources and waste heat is increasing. There is an abundance of such heat sources, but their utilization today is insufficient, mainly due to the limitations of the conventional power cycles in such applications, such as low efficiency, bulky size or moisture at the expansion outlet (e.g. problems for turbine blades). Carbon dioxide (CO2) has been widely investigated for use as a working fluid in refrigeration cycles, because it has no ozo...
R. Feistel
2008-12-01
Full Text Available A new seawater standard for oceanographic and engineering applications has been developed that consists of three independent thermodynamic potential functions, derived from extensive distinct sets of very accurate experimental data. The results have been formulated as Releases of the International Association for the Properties of Water and Steam, IAPWS (1996, 2006, 2008 and are expected to be adopted internationally by other organizations in subsequent years. In order to successfully perform computations such as phase equilibria from combinations of these potential functions, mutual compatibility and consistency of these independent mathematical functions must be ensured. In this article, a brief review of their separate development and ranges of validity is given. We analyse background details on the conditions specified at their reference states, the triple point and the standard ocean state, to ensure the mutual consistency of the different formulations, and the necessity and possibility of numerically evaluating metastable states of liquid water. Computed from this formulation in quadruple precision (128-bit floating point numbers, tables of numerical reference values are provided as anchor points for the consistent incorporation of additional potential functions in the future, and as unambiguous benchmarks to be used in the determination of numerical uncertainty estimates of double-precision implementations on different platforms that may be customized for special purposes.
R. Feistel
2008-07-01
Full Text Available A new seawater standard has been developed for oceanographic and engineering applications that consists of three independent thermodynamic potential functions, derived from extended distinct sets of very accurate experimental data. The results have been formulated as Releases of the International Association for the Properties of Water and Steam, IAPWS (1996, 2006, 2008 and are to be adopted internationally by other organizations in subsequent years. In order to successfully perform computations such as phase equilibria from combinations of these potential functions, mutual compatibility and consistency of these independent mathematical functions must be ensured. In this article, a brief review of their separate development and ranges of validity is given. We analyse background details on the conditions specified at their reference states, the triple point and the standard ocean state, to ensure the mutual consistency of the different formulations, and we consider the necessity and possibility of numerically evaluating metastable states of liquid water. Computed from this formulation in quadruple precision (128 bit floating point numbers, tables of numerical reference values are provided as anchor points for the consistent incorporation of additional potential functions in the future, and as unambiguous benchmarks to be used in the determination of numerical uncertainty estimates of double-precision implementations on different platforms that may be customized for special purposes.
Kinetic and Thermodynamic Fragilities of Square Well Fluids with Tunable Barriers to Bond Breaking.
Parmar, Anshul D S; Sastry, Srikanth
2015-08-27
An understanding of the origin of fragility, which the rapidity of change of viscosity and related dynamical quantities, has been sought by a variety of approaches over the years. Within the framework of the Adam-Gibbs relation, fragility is in principle related to both the temperature variation of configurational entropy and the high temperature activation energy. Many theoretical analyses have been focused on the variation of configuration entropy, although the importance of the high temperature activation energy in determining the fragility of a glass former has also been emphasized. We explore the latter aspect by considering a model liquid whose high temperature activation energy is modified by hand, through the introduction of a tunable barrier to bond breaking. We show that changes in such a barrier are able to modify the fragility measured from the temperature dependence of dynamical quantities, while a thermodynamic measure of fragility obtained from the configurational entropy remains unchanged. We discuss the implications of our results to our understanding of fragility, and outline open questions that merit further investigation.
Emanuel Carrilho
2001-08-01
Full Text Available Under the chromatographic point of view, the physico-chemical properties of a supercritical fluid are intermediate to those of the gases and liquids. Many times they approach the best features of each one, as for example, the solubilization power of liquids and low viscosity of gases. The thermodynamic definitions and main physico-chemical features of a supercritical fluid will be presented in this article. The use of supercritical fluids in analytical chemistry has been extremely modest in Brazil, even considering the enormous potential of their applications, and their use in several techniques, such as chromatography (SFC and supercritical fluid extration (SFE. This article series is intended to discuss the historical evolution, instrumentation features and potential and limitations of the supercritical fluid use in analytical chemistry. A special focus will be centered on chromatography and extration techniques using supercritical fluids.
Eu, Byung Chan
2016-01-01
This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on relativistic theories, it provides a comprehensive picture of the kinetic theory formulated from the viewpoint of nonequilibrium ensembles in both nonrelativistic and, in Vol. 2, relativistic contexts. Theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids) on the basis of irreversible kinetic equations satisfying the H theorem. They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respe...
Pourtier, E
2006-11-15
Standard thermodynamic properties (STP) of lanthanides (Ln{sup 3+}) are necessary to predict their transport in hydrothermal fluids. New STP (apparent molal volumes and heat capacities) of Ln{sup 3+} are determined with dilute (La{sup 3+}, Nd{sup 3+}, Gd{sup 3+}, Yb{sup 3+}) triflates solutions, up to 300 deg. C and 300 bars, using a vibrating tube flow densimeter and a differential heat flow calorimeter. The triflate anion (CF{sub 3}SO{sub 3}), stable at high temperature, does not form complexes with Ln{sup 3+}. The STP of HCF{sub 3}SO{sub 3} and NaCF{sub 3}SO{sub 3} are measured in order to get the STP of CF{sub 3}SO{sub 3}. The solubility of the Nd-pure pole of monazite (NdPO{sub 4}) studied between 300 and 800 deg. C at 2 kbars in H{sub 2}O and H{sub 2}O+NaCl using weight loss and isotope dilution methods, is prograde for neutral pH. The study of Nd{sup 3+} speciation at 650 deg. C and 300 deg. C, 2 kbars, shows that only hydroxylated species are present. These data allow the revision of Ln{sup 3+} parameters in the HKF model. (author)
Godunov, S. K.
2012-05-01
Minkowski's classical work underlying modern electrodynamics is described. Primary attention is given to the mathematical refinements that are required if the parameters ɛ and μ depend on the properties of the dielectric fluid, i.e., the medium carrying charges in the field under study. It is shown that the motion of the medium and the accompanying evolution of the electromagnetic field are described by differential equations that are symmetric and hyperbolic in the sense of Friedrichs. This property guarantees their well-posedness. Note that this class of equations was not known in Minkowski's time. At present, it plays an important role in the mathematical simulation of nonstationary processes and in the design of numerical algorithms. The author's view of the mathematical foundations of Minkowski's work is presented, which relates the latter to present-day insights into the theory of differential equations. This paper can possibly be of interest to physicists.
Herrera, L
2011-01-01
We identify the factors responsible for the appearance of energy-density inhomogeneities in a self-gravitating fluid, and describe the evolution of those factors from an initially homogeneous distribution. It is shown that a specific combination of the Weyl tensor and/or local anisotropy of pressure and/or dissipative fluxes entails the formation of energy-density inhomogeneities. Different cases are analyzed in detail and in the particular case of dissipative fluids, the role of relaxational processes as well as non-local effects are brought out.
Bulk and shear viscosity in Hagedorn fluid
Tawfik, A.; Wahba, M. [Egyptian Center for Theoretical Physics (ECTP), MTI University, Faculty of Engineering, Cairo (Egypt)
2010-11-15
Assuming that the Hagedorn fluid composed of known particles and resonances with masses m <2 GeV obeys the first-order theory (Eckart) of relativistic fluid, we discuss the transport properties of QCD confined phase. Based on the relativistic kinetic theory formulated under the relaxation time approximation, expressions for bulk and shear viscosity in thermal medium of hadron resonances are derived. The relaxation time in the Hagedorn dynamical fluid exclusively takes into account the decay and eventually van der Waals processes. We comment on the in-medium thermal effects on bulk and shear viscosity and averaged relaxation time with and without the excluded-volume approach. As an application of these results, we suggest the dynamics of heavy-ion collisions, non-equilibrium thermodynamics and the cosmological models, which require thermo- and hydro-dynamics equations of state. (Abstract Copyright [2010], Wiley Periodicals, Inc.)
Bulk and Shear Viscosity in Hagedorn Fluid
Tawfik, A
2010-01-01
Assuming that the Hagedorn fluid composed of known particles and resonances with masses $m<2\\,$GeV obeys the {\\it first-order} theory (Eckart) of relativistic fluid, we discuss the transport properties of QCD confined phase. Based on the relativistic kinetic theory formulated under the relaxation time approximation, expressions for bulk and shear viscosity in thermal medium are derived. The relaxation time in the Hagedorn dynamical fluid exclusively takes into account the decay and eventually van der Waals processes. We comment on the {\\it in-medium} thermal effects on bulk and shear viscosities and averaged relaxation time with and without the excluded-volume approach. As an application of these results, we suggest the dynamics of heavy-ion collisions, non-equlibrium thermodynamics and the cosmological models, which require thermo and hydrodynamics equations of state.
Bell, Aaron S.; Shearer, Charles; deMoor, J. Maarten; Provencio, Paula
2015-12-01
In this work, we investigate the compositions and origin of metasomatic fluids responsible for the formation of sulfide replacement textures in Mg-Suite lithologies of lunar samples 67915-149 and 67915-150. We have constructed a quantitative thermodynamic model of the composition of the metasomatic fluid using fO2, fS2, and temperature constraints derived from a thermodynamic analysis of the metasomatic fluid-mineral reactions and the measured compositions of the phases in the sulfide assemblages. Results from this modeling indicate that the metasomatic fluid responsible for the formation of the sulfide replacement textures was likely dominated by a combination of H2 and CH4, with minor abundances of H2O, CO, and H2S. The modeling indicates that H2S was, by orders of magnitude, the dominant S-species present in the metasomatic fluid and S isotopes in the replacement sulfides suggest that the fluid experienced significant removal of H2S by sulfide precipitation. The calculated H2 and H2O contents of the metasomatic fluid are consistent with those that might be expected for the late stage degassing of shallowly emplaced, intrusive magma bodies. Sulfur, heat, and other volatile constituents (i.e., chalcophile metals and carbon) were sourced from the breccia-producing impactor; the volatile phase produced by the impact event subsequently metasomatized the crust (Haskin and Warren, 1991); The sulfide metasomatism occurred in an ejecta blanket, where both the heat and sulfur that were produced by the impactor re-mobilized volatiles, causing hydrothermal circulation within the crust that redistributed both sulfur and chalcophile elements to produce sulfide-silicate intergrowths (Haskin and Warren, 1991); and Sulfur, heat, and other volatile constituents, sourced from degassing intrusive magmas and sulfur-bearing fluid from the degassing magma, percolated into surrounding crust, metasomatizing the adjacent country rock (Norman et al., 1995). The development of these models
带电硬哑铃流体的分子热力学%Molecular Thermodynamics of Charged Hard-Dumbbell Fluids
秦原; 刘洪来; 胡英
2001-01-01
Chemical potentials of charged hard-dumbbell fluids are obtained by Monte Carlo simulations using Widom's test-particle method, corresponding compressibility factors are achieved by integration of chemical potentials at different densities. A molecular thermodynamic model is also developed for these charged hard-dumbbell fluids where the residual Helmholtz function is composed of two terms: a reference term responsible for the charged hard spheres and a bonding contribution measuring the sticky interactions between positive and negative hard ions.Model predictions are in good agreement with simulation results.``
Thermal fluids for CSP systems: Alkaline nitrates/nitrites thermodynamics modelling method
Tizzoni, A. C.; Sau, S.; Corsaro, N.; Giaconia, A.; D'Ottavi, C.; Licoccia, S.
2016-05-01
Molten salt (MS) mixtures are used for the transport (HTF-heat transfer fluid) and storage of heat (HSM-heat storage material) in Concentration Solar Plants (CSP). In general, alkaline and earth-alkaline nitrate/nitrite mixtures are employed. Along with its upper stability temperature, the melting point (liquidus point) of a MS mixture is one of the main parameters which defines its usefulness as a HTF and HSM medium. As a result, we would like to develop a predictive model which will allow us to forecast freezing points for different MS mixture compositions; thus circumventing the need to determine experimentally the phase diagram for each MS mixture. To model ternary/quaternary phase diagram, parameters for the binary subsystems are to be determined, which is the purpose of the concerned work. In a binary system with components A and B, in phase equilibrium conditions (e.g. liquid and solid) the chemical potentials (partial molar Gibbs energy) for each component in each phase are equal. For an ideal solution it is possible to calculate the mixing (A+B) Gibbs energy:ΔG = ΔH - TΔS = RT(xAlnxA + xBlnxB) In case of non-ideal solid/liquid mixtures, such as the nitrates/nitrites compositions investigated in this work, the actual value will differ from the ideal one by an amount defined as the "mixing" (mix) Gibbs free energy. If the resulting mixtures is assumed, as indicated in the previous literature, to follow a "regular solution" model, where all the non-ideality is considered included in the enthalpy of mixing value and considering, for instance, the A component:Δ G ≡0 =(Δ HA-T Δ SA)+(ΔH¯ m i x AL-T ΔS¯ m i x AL)-(ΔH¯ m i x AS-T ΔS¯ m i x AS)where the molar partial amounts can be calculated from the total value by the Gibbs Duhem equation: (ΔH¯m i x AL=ΔHm i x-XB Ld/Δ Hm i x d XB L ) L;(ΔH¯m i x AS=ΔHm i x-XB Sd/Δ Hm i x d XB S ) S and, in general, it is possible to express the mixing enthalpy for solids and liquids as a function of the mol
Kuskov, Oleg L.; Belashchenko, David K.
2016-09-01
Density and sound velocity of Fe-S liquids for the P-T parameters of the lunar core have not been constrained well. From the analysis of seismic wave travel time, Weber et al. (2011) proposed that the lunar core is composed of iron alloyed with ⩽6 wt% of light elements, such as S. A controversial issue in models of planetary core composition concerns whether Fe-S liquids under high pressure - temperature conditions provide sound velocity and density data, which match the seismic model. Here we report the results of molecular dynamics (MD) simulations of iron-sulfur alloys based on Embedded Atom Model (EAM). The results of calculations include caloric, thermal and elastic properties of Fe-S alloys at concentrations of sulfur 0-18 at.%, temperatures up to 2500 K and pressures up to 14 GPa. The effect of sulfur on the elastic properties of Fe-rich melts is most evident in the notably decreased density with added S content. In the MD simulation, the density and bulk modulus KT of liquid Fe-S decrease with increasing sulfur content, while the bulk modulus KS decreases as a whole but has some fluctuations with increasing sulfur content. The sound velocity increases with increasing pressure, but depends weakly on temperature and the concentration of sulfur. For a fluid Fe-S core of the Moon (∼5 GPa/2000 K) with 6-16 at.% S (3.5-10 wt%), the sound velocity and density may be estimated at the level of 4000 m s-1 and 6.25-7.0 g cm-3. Comparison of thermodynamic calculations with the results of interpretation of seismic observations shows good agreement of P-wave velocities in the liquid outer core, while the core density does not match the seismic models. At such concentrations of sulfur and a density by 20-35% higher than the model seismic density, a radius for the fluid outer core should be less than about 330 km found by Weber et al. because at the specified mass and moment of inertia values of the Moon an increase of the core density leads to a decrease of the core
Soliton propagation in relativistic hydrodynamics
Fogaça, D A; 10.1016/j.nuclphysa.2007.03.104
2013-01-01
We study the conditions for the formation and propagation of Korteweg-de Vries (KdV) solitons in nuclear matter. In a previous work we have derived a KdV equation from Euler and continuity equations in non-relativistic hydrodynamics. In the present contribution we extend our formalism to relativistic fluids. We present results for a given equation of state, which is based on quantum hadrodynamics (QHD).
On the convexity of Relativistic Hydrodynamics
Ibáñez, José María; Martí, José María; Miralles, Juan Antonio; 10.1088/0264-9381/30/5/057002
2013-01-01
The relativistic hydrodynamic system of equations for a perfect fluid obeying a causal equation of state is hyperbolic (Anile 1989 {\\it Relativistic Fluids and Magneto-Fluids} (Cambridge: Cambridge University Press)). In this report, we derive the conditions for this system to be convex in terms of the fundamental derivative of the equation of state (Menikoff and Plohr 1989 {\\it Rev. Mod. Phys.} {\\bf 61} 75). The classical limit is recovered.
Thermodynamics and statistical mechanics
Landsberg, Peter T
1990-01-01
Exceptionally articulate treatment combines precise mathematical style with strong physical intuition. Wide range of applications includes negative temperatures, negative heat capacities, special and general relativistic effects, black hole thermodynamics, gravitational collapse, more. Over 100 problems with worked solutions. Advanced undergraduate, graduate level. Table of applications. Useful formulas and other data.
Luciano, Rezzolla
2013-01-01
Relativistic hydrodynamics is a very successful theoretical framework to describe the dynamics of matter from scales as small as those of colliding elementary particles, up to the largest scales in the universe. This book provides an up-to-date, lively, and approachable introduction to the mathematical formalism, numerical techniques, and applications of relativistic hydrodynamics. The topic is typically covered either by very formal or by very phenomenological books, but is instead presented here in a form that will be appreciated both by students and researchers in the field. The topics covered in the book are the results of work carried out over the last 40 years, which can be found in rather technical research articles with dissimilar notations and styles. The book is not just a collection of scattered information, but a well-organized description of relativistic hydrodynamics, from the basic principles of statistical kinetic theory, down to the technical aspects of numerical methods devised for the solut...
Petri, M
2003-01-01
A simple thermodynamic model for the final state of a collapsed, spherically symmetric star is presented. It is assumed, that the star's interior at the endpoint of the collapse consists of an ideal gas of ultra-relativistic fermions and bosons in thermal equilibrium and that the metric approaches the static metric of the so called holostar-solution of general relativity. The final configuration has a radius slightly exceeding the gravitational radius of the star. The radial coordinate difference between gravitational and actual radius is of order of the Planck length. The total number of ultra-relativistic particles within the star is proportional its proper surface-area, measured in units of the Planck-area. This is first direct evidence for the microscopic-statistical nature of the Hawking entropy and indicates, that the holographic principle is valid for compact self gravitating objects of any size. A "Stephan-Boltzmann-type" relation between the surface temperature and the surface area of the star is der...
Curved non-relativistic spacetimes, Newtonian gravitation and massive matter
Geracie, Michael, E-mail: mgeracie@uchicago.edu; Prabhu, Kartik, E-mail: kartikp@uchicago.edu; Roberts, Matthew M., E-mail: matthewroberts@uchicago.edu [Kadanoff Center for Theoretical Physics, Enrico Fermi Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)
2015-10-15
There is significant recent work on coupling matter to Newton-Cartan spacetimes with the aim of investigating certain condensed matter phenomena. To this end, one needs to have a completely general spacetime consistent with local non-relativistic symmetries which supports massive matter fields. In particular, one cannot impose a priori restrictions on the geometric data if one wants to analyze matter response to a perturbed geometry. In this paper, we construct such a Bargmann spacetime in complete generality without any prior restrictions on the fields specifying the geometry. The resulting spacetime structure includes the familiar Newton-Cartan structure with an additional gauge field which couples to mass. We illustrate the matter coupling with a few examples. The general spacetime we construct also includes as a special case the covariant description of Newtonian gravity, which has been thoroughly investigated in previous works. We also show how our Bargmann spacetimes arise from a suitable non-relativistic limit of Lorentzian spacetimes. In a companion paper [M. Geracie et al., e-print http://arxiv.org/abs/1503.02680 ], we use this Bargmann spacetime structure to investigate the details of matter couplings, including the Noether-Ward identities, and transport phenomena and thermodynamics of non-relativistic fluids.
Bansal, Artee; Valiya Parambathu, Arjun; Asthagiri, D; Cox, Kenneth R; Chapman, Walter G
2017-04-28
We present a theory to predict the structure and thermodynamics of mixtures of colloids of different diameters, building on our earlier work [A. Bansal et al., J. Chem. Phys. 145, 074904 (2016)] that considered mixtures with all particles constrained to have the same size. The patchy, solvent particles have short-range directional interactions, while the solute particles have short-range isotropic interactions. The hard-sphere mixture without any association site forms the reference fluid. An important ingredient within the multi-body association theory is the description of clustering of the reference solvent around the reference solute. Here we account for the physical, multi-body clusters of the reference solvent around the reference solute in terms of occupancy statistics in a defined observation volume. These occupancy probabilities are obtained from enhanced sampling simulations, but we also present statistical mechanical models to estimate these probabilities with limited simulation data. Relative to an approach that describes only up to three-body correlations in the reference, incorporating the complete reference information better predicts the bonding state and thermodynamics of the physical solute for a wide range of system conditions. Importantly, analysis of the residual chemical potential of the infinitely dilute solute from molecular simulation and theory shows that whereas the chemical potential is somewhat insensitive to the description of the structure of the reference fluid, the energetic and entropic contributions are not, with the results from the complete reference approach being in better agreement with particle simulations.
Bansal, Artee; Valiya Parambathu, Arjun; Asthagiri, D.; Cox, Kenneth R.; Chapman, Walter G.
2017-04-01
We present a theory to predict the structure and thermodynamics of mixtures of colloids of different diameters, building on our earlier work [A. Bansal et al., J. Chem. Phys. 145, 074904 (2016)] that considered mixtures with all particles constrained to have the same size. The patchy, solvent particles have short-range directional interactions, while the solute particles have short-range isotropic interactions. The hard-sphere mixture without any association site forms the reference fluid. An important ingredient within the multi-body association theory is the description of clustering of the reference solvent around the reference solute. Here we account for the physical, multi-body clusters of the reference solvent around the reference solute in terms of occupancy statistics in a defined observation volume. These occupancy probabilities are obtained from enhanced sampling simulations, but we also present statistical mechanical models to estimate these probabilities with limited simulation data. Relative to an approach that describes only up to three-body correlations in the reference, incorporating the complete reference information better predicts the bonding state and thermodynamics of the physical solute for a wide range of system conditions. Importantly, analysis of the residual chemical potential of the infinitely dilute solute from molecular simulation and theory shows that whereas the chemical potential is somewhat insensitive to the description of the structure of the reference fluid, the energetic and entropic contributions are not, with the results from the complete reference approach being in better agreement with particle simulations.
Haba, Z
2009-02-01
We discuss relativistic diffusion in proper time in the approach of Schay (Ph.D. thesis, Princeton University, Princeton, NJ, 1961) and Dudley [Ark. Mat. 6, 241 (1965)]. We derive (Langevin) stochastic differential equations in various coordinates. We show that in some coordinates the stochastic differential equations become linear. We obtain momentum probability distribution in an explicit form. We discuss a relativistic particle diffusing in an external electromagnetic field. We solve the Langevin equations in the case of parallel electric and magnetic fields. We derive a kinetic equation for the evolution of the probability distribution. We discuss drag terms leading to an equilibrium distribution. The relativistic analog of the Ornstein-Uhlenbeck process is not unique. We show that if the drag comes from a diffusion approximation to the master equation then its form is strongly restricted. The drag leading to the Tsallis equilibrium distribution satisfies this restriction whereas the one of the Jüttner distribution does not. We show that any function of the relativistic energy can be the equilibrium distribution for a particle in a static electric field. A preliminary study of the time evolution with friction is presented. It is shown that the problem is equivalent to quantum mechanics of a particle moving on a hyperboloid with a potential determined by the drag. A relation to diffusions appearing in heavy ion collisions is briefly discussed.
Sahoo, Raghunath
2016-01-01
This lecture note covers Relativistic Kinematics, which is very useful for the beginners in the field of high-energy physics. A very practical approach has been taken, which answers "why and how" of the kinematics useful for students working in the related areas.
AMIN HABIBZADEH
2016-01-01
Full Text Available In this paper, the performance of 13 working fluids in two Organic Rankine Cycles, which operate as the bottoming cycles for recovering waste heat from gas turbine modular helium reactor (GT-MHR, is investigated. Working fluids are classified in three dry, isentropic and wet fluids. The effect of varying pump temperature and evaporator pressure on the thermal efficiency, total exergy loss of the combined cycle is studied for each category, and the results are compared. The results are calculated for an optimum pressure ratio in which thermal efficiency is maximum. According to the results, dry fluids show a higher thermal efficiency while wet fluids have the lowest values. However, the highest value for thermal efficiency is for R141b, which is an isentropic fluid. Furthermore, the results indicate that pump temperature increase, reduces the total thermal efficiency and increases the total exergy loss of the combined cycle. Increasing evaporator pressure leads to an optimum pressure that maximizes total thermal efficiency. According to the optimized pressure ratio and evaporator pressure, R141b in isentropic fluids, R123 in dry fluids and R717 in wet fluids have the highest thermal efficiency values.
Holographic Aspects of a Relativistic Nonconformal Theory
Chanyong Park
2013-01-01
Full Text Available We study a general D-dimensional Schwarzschild-type black brane solution of the Einstein-dilaton theory and derive, by using the holographic renormalization, its thermodynamics consistent with the geometric results. Using the membrane paradigm, we calculate the several hydrodynamic transport coefficients and compare them with the results obtained by the Kubo formula, which shows the self-consistency of the gauge/gravity duality in the relativistic nonconformal theory. In order to understand more about the relativistic non-conformal theory, we further investigate the binding energy, drag force, and holographic entanglement entropy of the relativistic non-conformal theory.
Sengers, J. V.; Basu, R. S.; Sengers, J. M. H. L.
1981-01-01
A survey is presented of representative equations for various thermophysical properties of fluids in the critical region. Representative equations for the transport properties are included. Semi-empirical modifications of the theoretically predicted asymtotic critical behavior that yield simple and practical representations of the fluid properties in the critical region are emphasized.
Cignitti, Stefano; Andreasen, Jesper Graa; Haglind, Fredrik
2017-01-01
recovery. Inthis paper, an organic Rankine cycle process and its pure working fluid are designed simultaneously forwaste heat recovery of the exhaust gas from a marine diesel engine. This approach can overcome designissues caused by the high sensitivity between the fluid and cycle design variables...... and otherwise highresource demands, which through conventional methods cannot be addressed. The global optimal designwas a 1.2MW cycle with 2,2,3,3,4,4,5,5-octafluorohexane as the new fluid. The fluid has no ozone depletionpotential and a global warming potential under the regulatory limit. By using...... the simultaneousdesign approach the optimum solution was found in 5.04 s, while a decomposed approach found thesame solution in 5.77 h. However, the decomposed approach provided insights on the correlationbetween the fluid and cycle design variables by analyzing all possible solutions. It was shown that thehigh...
Abdurakhmanov, U U
2013-01-01
By the methods of mathematical statistics we test a qualitative prediction of the old theory of relativistic hydrodynamics non-viscous liquid which can be used as a part of the process of hadronization within the modern hydrodynamical approach for the description of the quark-gluon plasma. Experimental data on the interaction of protons with the energies of 0.8 TeV with emulsion nuclei are used. Results do not contradict the formation of relativistic ideal non-viscous liquid in rare central collisions.
Kim, Jung Min; Castañeda-Priego, Ramón; Liu, Yun; Wagner, Norman J.
2011-02-01
Understanding the mechanisms of clustering in colloids, nanoparticles, and proteins is of significant interest in material science and both chemical and pharmaceutical industries. Recently, using an integral equation theory formalism, Bomont et al. [J. Chem. Phys. 132, 184508 (2010)] studied theoretically the temperature dependence, at a fixed density, of the cluster formation in systems where particles interact with a hard-core double Yukawa potential composed of a short-range attraction and a long-range repulsion. In this paper, we provide evidence that the low-q peak in the static structure factor, frequently associated with the formation of clusters, is a common behavior in systems with competing interactions. In particular, we demonstrate that, based on a thermodynamic self-consistency criterion, accurate structural functions are obtained for different choices of closure relations. Moreover, we explore the dependence of the low-q peak on the particle number density, temperature, and potential parameters. Our findings indicate that enforcing thermodynamic self-consistency is the key factor to calculate both thermodynamic properties and static structure factors, including the low-q behavior, for colloidal dispersions with both attractive and repulsive interactions. Additionally, a simple analysis of the mean number of neighboring particles provides a qualitative description of some of the cluster features.
Hakim, Rémi
1994-01-01
Il existe à l'heure actuelle un certain nombre de théories relativistes de la gravitation compatibles avec l'expérience et l'observation. Toutefois, la relativité générale d'Einstein fut historiquement la première à fournir des résultats théoriques corrects en accord précis avec les faits.
Rational extended thermodynamics
Müller, Ingo
1998-01-01
Ordinary thermodynamics provides reliable results when the thermodynamic fields are smooth, in the sense that there are no steep gradients and no rapid changes. In fluids and gases this is the domain of the equations of Navier-Stokes and Fourier. Extended thermodynamics becomes relevant for rapidly varying and strongly inhomogeneous processes. Thus the propagation of high frequency waves, and the shape of shock waves, and the regression of small-scale fluctuation are governed by extended thermodynamics. The field equations of ordinary thermodynamics are parabolic while extended thermodynamics is governed by hyperbolic systems. The main ingredients of extended thermodynamics are • field equations of balance type, • constitutive quantities depending on the present local state and • entropy as a concave function of the state variables. This set of assumptions leads to first order quasi-linear symmetric hyperbolic systems of field equations; it guarantees the well-posedness of initial value problems and f...
Bernier, J. [Syrec SA (France)
1996-12-31
The R-22 refrigerant has been used as a substitute of chlorofluorocarbons in refrigerating machineries but its use will become prohibited very soon. This paper raises the problem of its replacement by other HFC or natural fluids. The problem of natural fluids like ammonia or propane concerns their toxicity, flammability and explosion risk. If a regulation about the greenhouse effect is defined, the performance of the installation will be the decisive parameter for the choice of a refrigerant. R-22 fluid has multiple applications from air-conditioning systems to freezing tunnels and the most suitable substitutes will be different from one application to the other. The different criteria that influence the choice of a refrigerating fluid are: the condensation pressure, the delivery temperature, the compressor volume efficiency, the volume refrigerating power, the coefficient of performance, the variation of vaporization temperature, the global greenhouse effect, the toxicity, flammability and explosive character. A comparison between several fluids has been performed with a single-stage airtight compressor of 10 m{sup 3}/h, at a 40 deg. C constant condensation temperature, a 5 deg. C overheating and a 3 deg. C under-cooling. (J.S.) 6 refs.
AMIN HABIBZADEH; MOHAMMAD MEHDI RASHIDI
2016-01-01
In this paper, the performance of 13 working fluids in two Organic Rankine Cycles, which operate as the bottoming cycles for recovering waste heat from gas turbine modular helium reactor (GT-MHR), is investigated...
Jones, Bernard J. T.; Markovic, Dragoljub
1997-06-01
Preface; Prologue: Conference overview Bernard Carr; Part I. The Universe At Large and Very Large Redshifts: 2. The size and age of the Universe Gustav A. Tammann; 3. Active galaxies at large redshifts Malcolm S. Longair; 4. Observational cosmology with the cosmic microwave background George F. Smoot; 5. Future prospects in measuring the CMB power spectrum Philip M. Lubin; 6. Inflationary cosmology Michael S. Turner; 7. The signature of the Universe Bernard J. T. Jones; 8. Theory of large-scale structure Sergei F. Shandarin; 9. The origin of matter in the universe Lev A. Kofman; 10. New guises for cold-dark matter suspects Edward W. Kolb; Part II. Physics and Astrophysics Of Relativistic Compact Objects: 11. On the unification of gravitational and inertial forces Donald Lynden-Bell; 12. Internal structure of astrophysical black holes Werner Israel; 13. Black hole entropy: external facade and internal reality Valery Frolov; 14. Accretion disks around black holes Marek A. Abramowicz; 15. Black hole X-ray transients J. Craig Wheeler; 16. X-rays and gamma rays from active galactic nuclei Roland Svensson; 17. Gamma-ray bursts: a challenge to relativistic astrophysics Martin Rees; 18. Probing black holes and other exotic objects with gravitational waves Kip Thorne; Epilogue: the past and future of relativistic astrophysics Igor D. Novikov; I. D. Novikov's scientific papers and books.
Relativistic Radiation Mediated Shocks
Budnik, Ran; Sagiv, Amir; Waxman, Eli
2010-01-01
The structure of relativistic radiation mediated shocks (RRMS) propagating into a cold electron-proton plasma is calculated and analyzed. A qualitative discussion of the physics of relativistic and non relativistic shocks, including order of magnitude estimates for the relevant temperature and length scales, is presented. Detailed numerical solutions are derived for shock Lorentz factors $\\Gamma_u$ in the range $6\\le\\Gamma_u\\le30$, using a novel iteration technique solving the hydrodynamics and radiation transport equations (the protons, electrons and positrons are argued to be coupled by collective plasma processes and are treated as a fluid). The shock transition (deceleration) region, where the Lorentz factor $ \\Gamma $ drops from $ \\Gamma_u $ to $ \\sim 1 $, is characterized by high plasma temperatures $ T\\sim \\Gamma m_ec^2 $ and highly anisotropic radiation, with characteristic shock-frame energy of upstream and downstream going photons of a few~$\\times\\, m_ec^2$ and $\\sim \\Gamma^2 m_ec^2$, respectively.P...
Relativistic Gravothermal Instabilities
Roupas, Zacharias
2014-01-01
The thermodynamic instabilities of the self-gravitating, classical ideal gas are studied in the case of static, spherically symmetric configurations in General Relativity taking into account the Tolman-Ehrenfest effect. One type of instabilities is found at low energies, where thermal energy becomes too weak to halt gravity and another at high energies, where gravitational attraction of thermal pressure overcomes its stabilizing effect. These turning points of stability are found to depend on the total rest mass $\\mathcal{M}$ over the radius $R$. The low energy instability is the relativistic generalization of Antonov instability, which is recovered in the limit $G\\mathcal{M} \\ll R c^2$ and low temperatures, while in the same limit and high temperatures, the high energy instability recovers the instability of the radiation equation of state. In the temperature versus energy diagram of series of equilibria, the two types of gravothermal instabilities make themselves evident as a double spiral! The two energy l...
Thermodynamic properties of fluid n-D/sub 2/ in the 75 to 300 K and 2- to 20-kbar range
Liebenberg, D.H.; Mills, R.L.; Bronson, J.C.
1978-03-01
The hydrogen isotope deuterium is an important material for use in various energy technologies. This report is a summary of new pressure, volume, temperature, and sound velocity measurements of fluid n-D/sub 2/ in the 75 to 300 K and 2- to 20-kbar range. An equation of state (EOS) was fit to these data. The thermodynamic quantities, volume V, sound velocity v/sub s/, thermal expansivity ..cap alpha../sub p/, heat capacity at constant pressure C/sub p/, isothermal compressibility chi/sub T/, and molar entropy S, are given at 25/sup 0/K and 0.5-kbar increments over the range of measurements. Computer-drawn graphs of the isothermal pressure variation of these quantities are shown. Characteristics of the EOS at high temperature and pressure are determined and compared with theoretical and phenomenological equations of state.
Mei, Yuan; Etschmann, Barbara; Liu, Weihua; Sherman, David M.; Testemale, Denis; Brugger, Joël
2016-04-01
Chlorine and sulfur are the main elements involved in the complexing of metals in ore-forming fluids. The nature and thermodynamic properties of the Zn(II)-Cl complexes have been investigated by previous experimental and theoretical studies and are now well established up to high temperatures (600 °C). In contrast, the role of bisulfide complexes for zinc speciation in sulfur-bearing fluids remains poorly known, and a better understanding of Zn(II)-HS complexation is required for modeling zinc transport in magmatic and metamorphic fluids and for optimizing the hydrometallurgical processing of sulfide ores. We have conducted ab initio molecular dynamics (MD) simulations to calculate the speciation of Zn(II)-HS complexes from ambient to hydrothermal-magmatic conditions (25-600 °C, up to 2000 bar). These theoretical calculations were complemented by X-ray absorption spectroscopy (XAS) measurements of Zn(II) in HS--rich solutions at 200-500 °C and 600-1000 bar. The speciation and geometrical properties predicted by the ab initio MD simulations and the in situ XAS data are in excellent agreement. Upon heating from room temperature to 250 °C, Zn(II) speciation in HS--rich solutions shows a transition from the sixfold octahedral hexaaquo complex [Zn(H2O)6]2+ to fourfold tetrahedral [Zn(HS)n(H2O)4-n]2-n complexes (n = 1-4). Ab initio MD simulations also show that at temperatures > 250 °C, the threefold trigonal-planar [Zn(HS)3]- complex becomes increasingly stable, and predominates in S-rich solutions; in contrast, chloro-complexes display a tetrahedral geometry at 25-500 °C, while trigonal planar ZnCl3- predominates at temperatures > 500 °C. The stability constants of Zn(II)-HS complexes were calculated by thermodynamic integration of constrained ab initio MD simulations at 200, 350 and 600 °C. The stability constants generated from this study predict that zinc can be transported by HS- at high temperature in reduced, neutral to alkaline solutions, while Zn
Frutiger, Jerome; Abildskov, Jens; Sin, Gürkan
assessment of novel working fluids relies on accurate property data. Flammability data like the lower and upper flammability limit (LFL and UFL) play an important role in quantifying the risk of fire and explosion. For novel working fluid candidates experimental values are not available for the safety...... analysis. In this case property prediction models like group contribution (GC) models can estimate flammability data. The estimation needs to be accurate, reliable and as less time consuming as possible [1]. However, GC property prediction methods frequently lack rigorous uncertainty analysis. Hence...
Dilational Symmetry-Breaking in Thermodynamics
Lin, Chris L
2016-01-01
Using thermodynamic relations and dimensional analysis we derive a general formula for the thermodynamical trace $2\\mathcal{E}-DP$ for non-relativistic systems and $\\mathcal{E-DP}$ for relativistic systems, where $D$ is the number of spatial dimensions, in terms of the microscopic scales of the system within the grand canonical ensemble. We demonstrate the formula for several cases, including anomalous systems which develop scales through dimensional transmutation. Using this relation, we make explicit the connection between dimensional analysis and the virial theorem. This paper is focused mainly on the non-relativistic aspects of this relation.
Turbulent Comptonization in Relativistic Accretion Disks
Socrates, A; Blaes, Omer M; Socrates, Aristotle; Davis, Shane W.; Blaes, Omer
2006-01-01
Turbulent Comptonization, a potentially important damping and radiation mechanism in relativistic accretion flows, is discussed. Particular emphasis is placed on the physical basis, relative importance, and thermodynamics of turbulent Comptonization. The effects of metal-absorption opacity on the spectral component resulting from turbulent Comptonization is considered as well.
Relativistic and non-relativistic geodesic equations
Giambo' , R.; Mangiarotti, L.; Sardanashvily, G. [Camerino Univ., Camerino, MC (Italy). Dipt. di Matematica e Fisica
1999-07-01
It is shown that any dynamic equation on a configuration space of non-relativistic time-dependent mechanics is associated with connections on its tangent bundle. As a consequence, every non-relativistic dynamic equation can be seen as a geodesic equation with respect to a (non-linear) connection on this tangent bundle. Using this fact, the relationships between relativistic and non-relativistic equations of motion is studied.
Polanco, J D; Ujevic, M; Polanco, Jose D.; Letelier, Patricio S.; Ujevic, Maximiliano
2004-01-01
A numerical solution of Einstein field equations for a spherical symmetric and stationary system of identical and auto-gravitating particles in phase transition is presented. The fluid possess a perfect fluid energy momentum tensor, and the internal interactions of the system are represented by a van der Walls like equation of state able to describe a first order phase transition of the type gas-liquid. We find that the space-time curvature, the radial component of the metric, and the pressure and density show discontinuities in their radial derivatives in the phase coexistence region. This region is found to be a spherical surface concentric with the star and the system can be thought as a foliation of acronal, concentric and isobaric surfaces in which the coexistence of phases occurs in only one of these surfaces. This kind of system can be used to represent a star with a high energy density core and low energy density mantle in hydrodynamic equilibrium.
LOCAL CLASSICAL SOLUTIONS TO THE EQUATIONS OF RELATIVISTIC HYDRODYNAMICS
史一蓬
2001-01-01
In this paper, we prove that the convexity of the negative thermodynamical entropy of the equations of relativistic hydrodynamics for ideal gas keeps its invariance under the Lorentz transformation if and only if the local sound speed is less than the light speed in vacuum. Then a symmetric form for the equations of relativistic hydrodynamics is presented and the local classical solution is obtained. Based on this,we prove that the nonrelativistic limit of the local classical solution to the relativistic hydrodynamics equations for relativistic gas is the local classical solution of the Euler equations for polytropic gas.
Leardini, Fabrice
2013-01-01
This manuscript presents a problem on special relativity theory (SRT) which embodies an apparent paradox relying on the concept of simultaneity. The problem is represented in the framework of Greek epic poetry and structured in a didactic way. Owing to the characteristic properties of Lorenz transformations, three events which are simultaneous in a given inertial reference system, occur at different times in the other two reference frames. In contrast to the famous twin paradox, in the present case there are three, not two, different inertial observers. This feature provides a better framework to expose some of the main characteristics of SRT, in particular, the concept of velocity and the relativistic rule of addition of velocities.
On Lorentz invariants in relativistic magnetic reconnection
Yang, Shu-Di; Wang, Xiao-Gang
2016-08-01
Lorentz invariants whose nonrelativistic correspondences play important roles in magnetic reconnection are discussed in this paper. Particularly, the relativistic invariant of the magnetic reconnection rate is defined and investigated in a covariant two-fluid model. Certain Lorentz covariant representations for energy conversion and magnetic structures in reconnection processes are also investigated. Furthermore, relativistic measures for topological features of reconnection sites, particularly magnetic nulls and separatrices, are analyzed.
A Warm Fluid Model of Intense Laser-Plasma Interactions
Tarkenton, G. M.; Shadwick, B. A.; Esarey, E. H.; Leemans, W. P.
2001-10-01
Following up on our previous work on modeling intense laser-plasma interactions with cold fluids,(B.A.Shadwick, G. M. Tarkenton, E.H. Esarey, and W.P. Leemans, ``Fluid Modeling of Intense Laser-Plasma Interactions'', in Advanced Accelerator Concepts), P. Colestock and S. Kelley editors, AIP Conf. Proc. 569 (AIP, NY 2001), pg. 154. we are exploring warm fluid models. These models represent the next level in a hierarchy of complexity beyond the cold fluid approximation. With only a modest increase in computation effort, warm fluids incorporate effects that are relevant to a variety of technologically interesting cases. We present a derivation of the warm fluid from a kinetic (i.e. Vlasov) perspective and make a connection with the usual relativistic thermodynamic approach.(S. R. de Groot, W. A. van Leeuwen and Ch. G. van Weert, Relativistic Kinetic Theory: Principles and Applications), North-Holland (1980). We will provide examples where the warm fluids yield physics results not contained in the cold model and discuss experimental parameters where these effects are believed to be important.
Rock, P.A.
1983-01-01
This book, suitable as an introductory text for undergraduates, presents temperature, internal energy, and entropy with a minimum of mathematics. The basic mathematical models of classical chemical thermodynamics are developed later in the text. Includes numerous problems at the end of each chapter, an appendix giving thermodynamic data for common substances, a short list of references, answers to selected problems, and a subject index. Contents, abridged: Energy and the first law of thermodynamics. Thermodynamic functions. The third law of thermodynamics and absolute entropies. Thermodynamics of chemical reactions. Phase equilibria: the activity function. Thermodynamics of ions in solution. Statistical thermodynamics. Appendices. Index.
Thermodynamics - basic conception
Wee, Eul Bok
1979-08-15
This book tells of basic conception of thermodynamics, condition and property of matter, work and power, thermal efficiency, the principle of the conservation of energy, relationship between work and heat, enthalpy, Jouel's law, complete gasification, the second low of thermodynamics such as thermal efficiency and quality factor, carnot cycle, and entropy, condensation of gas like press of internal combustion engine, vapor, steam power plant and structure, internal combustion cycle, freeze cycle, flow of fluid, combustion and heat transfer.
Yu.V. Kalyuzhnyi
2012-06-01
Full Text Available The liquid-gas phase diagram for polydisperse dipolar hard-sphere fluid with polydispersity in the hard-sphere size and dipolar moment is calculated using extension of the recently proposed thermodynamic perturbation theory for central force (TPT-CF associating potential. To establish the connection with the phase behavior of ferrocolloidal dispersions it is assumed that the dipole moment is proportional to the cube of the hard-sphere diameter. We present and discuss the full phase diagram, which includes cloud and shadow curves, binodals and distribution functions of the coexisting daughter phases at different degrees of the system polydispersity. In all cases studied polydispersity increases the region of the phase instability and shifts the critical point to the higher values of the temperature and density. The larger size particles always fractionate to the liquid phase and the smaller size particles tend to move to the gas phase. At relatively high values of the system polydispersity three-phase coexistence is observed.
Non-equilibrium thermodynamics
De Groot, Sybren Ruurds
1984-01-01
The study of thermodynamics is especially timely today, as its concepts are being applied to problems in biology, biochemistry, electrochemistry, and engineering. This book treats irreversible processes and phenomena - non-equilibrium thermodynamics.S. R. de Groot and P. Mazur, Professors of Theoretical Physics, present a comprehensive and insightful survey of the foundations of the field, providing the only complete discussion of the fluctuating linear theory of irreversible thermodynamics. The application covers a wide range of topics: the theory of diffusion and heat conduction, fluid dyn
Relativistic neoclassical radial fluxes in the 1/nu regime
Marushchenko, I; Marushchenko, N B
2013-01-01
The radial neoclassical fluxes of electrons in the 1/nu-regime are calculated with relativistic effects taken into account and compared with those in the non-relativistic approach. The treatment is based on the relativistic drift-kinetic equation with the thermodynamic equilibrium given by the relativistic J\\"uttner-Maxwellian distribution function. It is found that for the range of fusion temperatures, T_e < 100 keV, the relativistic effects produce a reduction of the radial fluxes which does not exceed 10%. This rather small effect is a consequence of the non-monotonic temperature dependence of the relativistic correction caused by two counteracting factors: a reduction of the contribution from the bulk and a significant broadening with the temperature growth of the energy range of electrons contributing to transport. The relativistic formulation for the radial fluxes given in this paper is expressed in terms a set of relativistic thermodynamic forces which is not identical to the canonical set since it ...
Thermodynamics of diffusive DM/DE systems
Haba, Z.
2017-04-01
We discuss the energy density, temperature and entropy of dark matter (DM) and dark energy (DE) as functions of the scale factor a in an expanding universe. In a model of non-interacting dark components we repeat a derivation from thermodynamics of the well-known relations between the energy density, entropy and temperature. In particular, the entropy is constant as a consequence of the energy conservation. We consider a model of a DM/DE interaction where the DM energy density increase is proportional to the particle density. In such a model the dependence of the energy density and the temperature on the scale factor a is substantially modified. We discuss (as a realization of the model) DM which consists of relativistic particles diffusing in an environment of DE. The energy gained by the dark matter comes from a cosmological fluid with a negative pressure. We define the entropy and free energy of such a non-equilibrium system. We show that during the universe evolution the entropy of DM is increasing whereas the entropy of DE is decreasing. The total entropy can increase (in spite of the energy conservation) as the DM and DE temperatures are different. We discuss non-equilibrium thermodynamics on the basis of the notion of the relative entropy.
Sussman, R A; Sussman, Roberto A.; Pavon, Diego
1999-01-01
We derive a new class of exact solutions of Einstein's equations providing a physically plausible hydrodynamical description of cosmological matter in the radiative era ($10^6 K > T > 10^3 K$), between nucleosynthesis and decoupling. The solutions are characterized by the Lemaître-Tolman -Bondi metric with a viscous fluid source, subjected to the following conditions: (a) the equilibrium state variables satisfy the equation of state of a mixture of an ultra-relativistic and a non-relativistic ideal gases, where the internal energy of the latter has been neglected, (b) the particle numbers of the mixture components are independently conserved, (c) the viscous stress is consistent with the transport equation and entropy balance law of Extended Irreversible Thermodynamics, with the coefficient of shear viscosity provided by Kinetic Theory for the `radiative gas' model. The fulfilment of (a), (b) and (c) restricts initial conditions in terms of an initial value function, fluctuations of photon entropy per baryon...
Parallel, grid-adaptive approaches for relativistic hydro and magnetohydrodynamics
Keppens, R.; Meliani, Z.; van Marle, A. J.; Delmont, P.; Vlasis, A.; van der Holst, B.
2012-01-01
Relativistic hydro and magnetohydrodynamics provide continuum fluid descriptions for gas and plasma dynamics throughout the visible universe. We present an overview of state-of-the-art modeling in special relativistic regimes, targeting strong shock-dominated flows with speeds approaching the speed
Vanishing condition for the heat flux and slow evolution of a spherically fluid distribution
Romero-Muñoz, M.; Dagdug, L.; Chacón-Acosta, G.
2015-01-01
Recently, it has been found conditions for the heat flux where its introduction into the energy-momentum tensor, given his no mechanical nature, has no problems [1]. This has been achieved by checking the validity of the second law of thermodynamics in a fluid that is boosted by a Lorentz transformation of a non-commoving frame [2]. It is known that the condition, that turns out to be the null energy condition, involves the presence of a set of reference frames where Landau-Lifshitz frame is one of them. Moreover the entropy production remains positive, implying that there are no problems or issues that violate the second law of thermodynamics. In the present contribution we review the above condition, and apply it for a self-gravitating relativistic fluid in a spherically symmetric distribution in pure local coordinates. We find that our condition influences Schwarzschild fields, relating the condition of slow evolution with thermal quantities of the fluid.
Thermodynamic equilibrium in relativity: four-temperature, Killing vectors and Lie derivatives
Becattini, F
2016-01-01
The main concepts of general relativistic thermodynamics and general relativistic statistical mechanics are reviewed. The main building block of the proper relativistic extension of the classical thermodynamics laws is the four-temperature vector \\beta, which plays a major role in the quantum framework and defines a very convenient hydrodynamic frame. The general relativistic thermodynamic equilibrium condition demands \\beta to be a Killing vector field. We show that a remarkable consequence is that all Lie derivatives of all physical observables along the four-temperature flow must then vanish.
Relativistic calculations of coalescing binary neutron stars
Joshua Faber; Phillippe Grandclément; Frederic Rasio
2004-10-01
We have designed and tested a new relativistic Lagrangian hydrodynamics code, which treats gravity in the conformally flat approximation to general relativity. We have tested the resulting code extensively, finding that it performs well for calculations of equilibrium single-star models, collapsing relativistic dust clouds, and quasi-circular orbits of equilibrium solutions. By adding a radiation reaction treatment, we compute the full evolution of a coalescing binary neutron star system. We find that the amount of mass ejected from the system, much less than a per cent, is greatly reduced by the inclusion of relativistic gravitation. The gravity wave energy spectrum shows a clear divergence away from the Newtonian point-mass form, consistent with the form derived from relativistic quasi-equilibrium fluid sequences.
Cari, C., E-mail: cari@staff.uns.ac.id; Suparmi, A., E-mail: soeparmi@staff.uns.ac.id; Yunianto, M., E-mail: muhtaryunianto@staff.uns.ac.id; Husein, A. S. [Physics Department, Faculty of Mathematics and Science, SebelasMaret University, Jl. Ir. Sutami 36A Kentingan Surakarta 57126 (Indonesia)
2016-02-08
The analytical solution of Ddimensional Dirac equation for Coulombic potential is investigated using Nikiforov-Uvarov method. The D dimensional relativistic energy spectra are obtained from relativistic energy eigenvalue equation by using Mat Lab software.The corresponding D dimensional radial wave functions are formulated in the form of generalized Jacobi and Laguerre Polynomials. In the non-relativistic limit, the relativistic energy equation reduces to the non-relativistic energy which will be applied to determine some thermodynamical properties of the system. The thermodynamical properties of the system are expressed in terms of error function and imaginary error function.
Pastoriza-Gallego, María José; Sánchez-Paz, Verónica; Losada-Barreiro, Sonia; Bravo-Díaz, Carlos; Gunaseelan, K; Romsted, Laurence S
2009-03-03
The combined linear sweep voltammetry (LSV)/pseudophase kinetic model method was used to obtain the first estimates of the free energies, enthalpy, and entropies of transfer of alpha-tocopherol (TOC) between the oil and interfacial regions of fluid, opaque, emulsions of n-octane, acidic water, and the nonionic surfactant hexaethyleneglycol mono dodecyl ether (C12E6) from the temperature dependence of TOC's partition constant. Determining structure-reactivity relationships for chemical reactions in emulsions is difficult because traditional methods for monitoring reactions are unsuitable and because the partitioning of reactive components between the oil, interfacial, and aqueous regions of opaque emulsions are difficult to measure. The dependence of the observed rate constant, k(obs), for the reaction of an arenediazonium probe, 16-ArN2+, with TOC was determined as a function of C12E6 volume fraction. The pseudophase kinetic model was used to estimate the interfacial rate constant, k1, and the partition constants of antioxidants between the oil and interfacial, Po(I), regions in the emulsion from k(obs) versus phiI profiles. The thermodynamic parameters of transfer from the oil to the interfacial region at a series of temperatures were respectively obtained from the PoI values (deltaGT0,O-->I), by the van't Hoff method (deltaHT0,O-->I), and from the Gibbs equation (deltaST0,O-->I). The free energy of transfer is spontaneous, and a large positive entropy of transfer dominates a positive enthalpy of transfer, indicating that the TOC headgroup disrupts the structure of the interfacial region in its immediate vicinity upon transfer from n-octane. The methods described here are applicable to any bimolecular reaction in emulsions in which one of the reactants is restricted to the interfacial region and the rate of its reaction with a second component can be monitored electrochemically.
Coppa, P.; Bovesecchi, G.; Fabrizi, F.
2010-08-01
Molten salts (sodium and potassium nitrides) are going to be used in many different plants as heat transferring fluids, e.g. concentration solar plants, nuclear power plants, etc. In fact they present may important advantages: their absolute safety and non toxicity, availability and low cost. But their use, e.g. in the energy receiving pipe in the focus of the parabolic mirror concentrator of the solar thermodynamic plant, requires the accurate knowledge of the thermophysical properties, above all thermal conductivity, viscosity, specific heat and thermal linear expansion, in the temperature range 200°C÷600°C. In the new laboratory by ENEA Casaccia, SolTerm Department all these properties are going to be measured. Thermal conductivity is measured with the standard probe method (linear heat source inserted into the material) manufacturing a special probe suited to the foreseen temperature range (190-550°C). The probe is made of a ceramic quadrifilar pipe containing in different holes the heater (Ni wire) and the thermometer (type J thermocouple). The thermal linear expansion will be measured by a special system designed and built to this end, measuring the sample dilatation by the reflection of a laser beam by the bottom of the meniscus in the liquid solid interface. The viscosity will be evaluated detecting the start of the natural convection in the same experiment as to measure thermal conductivity. In the paper the construction of the devices, the results of preliminary tests and an evaluation of the obtainable accuracy are reported.
Heinz, U; Denicol, G S; Martinez, M; Nopoush, M; Noronha, J; Ryblewski, R; Strickland, M
2015-01-01
Several recent results are reported from work aiming to improve the quantitative precision of relativistic viscous fluid dynamics for relativistic heavy-ion collisions. The dense matter created in such collisions expands in a highly anisotropic manner. Due to viscous effects this also renders the local momentum distribution anisotropic. Optimized hydrodynamic approaches account for these anisotropies already at leading order in a gradient expansion. Recently discovered exact solutions of the relativistic Boltzmann equation in anisotropically expanding systems provide a powerful testbed for such improved hydrodynamic approximations. We present the latest status of our quest for a formulation of relativistic viscous fluid dynamics that is optimized for applications to relativistic heavy-ion collisions.
Relativistic radiative transfer in relativistic spherical flows
Fukue, Jun
2017-02-01
Relativistic radiative transfer in relativistic spherical flows is numerically examined under the fully special relativistic treatment. We first derive relativistic formal solutions for the relativistic radiative transfer equation in relativistic spherical flows. We then iteratively solve the relativistic radiative transfer equation, using an impact parameter method/tangent ray method, and obtain specific intensities in the inertial and comoving frames, as well as moment quantities, and the Eddington factor. We consider several cases; a scattering wind with a luminous central core, an isothermal wind without a core, a scattering accretion on to a luminous core, and an adiabatic accretion on to a dark core. In the typical wind case with a luminous core, the emergent intensity is enhanced at the center due to the Doppler boost, while it reduces at the outskirts due to the transverse Doppler effect. In contrast to the plane-parallel case, the behavior of the Eddington factor is rather complicated in each case, since the Eddington factor depends on the optical depth, the flow velocity, and other parameters.
Radiative transfer in ultra-relativistic outflows
Beloborodov, Andrei M.
2010-01-01
Analytical and numerical solutions are obtained for the equation of radiative transfer in ultra-relativistic opaque jets. The solution describes the initial trapping of radiation, its adiabatic cooling, and the transition to transparency. Two opposite regimes are examined: (1) Matter-dominated outflow. Surprisingly, radiation develops enormous anisotropy in the fluid frame before decoupling from the fluid. The radiation is strongly polarized. (2) Radiation-dominated outflow. The transfer occu...
Relativistic Remnants of Non-Relativistic Electrons
Kashiwa, Taro
2015-01-01
Electrons obeying the Dirac equation are investigated under the non-relativistic $c \\mapsto \\infty$ limit. General solutions are given by derivatives of the relativistic invariant functions whose forms are different in the time- and the space-like region, yielding the delta function of $(ct)^2 - x^2$. This light-cone singularity does survive to show that the charge and the current density of electrons travel with the speed of light in spite of their massiveness.
Relativistic quantum mechanics
Wachter, Armin
2010-01-01
Which problems do arise within relativistic enhancements of the Schrödinger theory, especially if one adheres to the usual one-particle interpretation, and to what extent can these problems be overcome? And what is the physical necessity of quantum field theories? In many books, answers to these fundamental questions are given highly insufficiently by treating the relativistic quantum mechanical one-particle concept very superficially and instead introducing field quantization as soon as possible. By contrast, this monograph emphasizes relativistic quantum mechanics in the narrow sense: it extensively discusses relativistic one-particle concepts and reveals their problems and limitations, therefore motivating the necessity of quantized fields in a physically comprehensible way. The first chapters contain a detailed presentation and comparison of the Klein-Gordon and Dirac theory, always in view of the non-relativistic theory. In the third chapter, we consider relativistic scattering processes and develop the...
韩中合; 于一达; 王智; 杜燕
2013-01-01
Under the proposed working conditions,R123,R141 b,R245ca,R245fa,R601,R601 a are chosen as the working fluids of the low-temperature Rankine cycle system,then those working fluids are investigated and compared based on first law of thermodynamics and second law of thermodynamics.Results show that R141b is an available and effective working fluid for low-temperature Rankine cycle.The impact of the turbine output temperature and pressure on the system performance of organic Rankine system was investigated.Including system net output power,heat absorption capacity and thermal efficiency.%选取R123,R141b,R245ca,R245fa,R601,R601a作为有机朗肯循环的工质,在不同蒸发温度条件下,对其热力循环特性进行了计算分析,以热力学第一定律和第二定律为基础进行了比较.结果表明,R141b是适合本循环系统的最佳工质.同时还研究了汽轮机进口温度和进口压力对该系统的净功量、吸热量及热效率的影响.
ZHANG Peng-Fei; RUAN Tu-Nan
2001-01-01
A systematic theory on the appropriate spin operators for the relativistic states is developed. For a massive relativistic particle with arbitrary nonzero spin, the spin operator should be replaced with the relativistic one, which is called in this paper as moving spin. Further the concept of moving spin is discussed in the quantum field theory. A new is constructed. It is shown that, in virtue of the two operators, problems in quantum field concerned spin can be neatly settled.
Relativistic Guiding Center Equations
White, R. B. [PPPL; Gobbin, M. [Euratom-ENEA Association
2014-10-01
In toroidal fusion devices it is relatively easy that electrons achieve relativistic velocities, so to simulate runaway electrons and other high energy phenomena a nonrelativistic guiding center formalism is not sufficient. Relativistic guiding center equations including flute mode time dependent field perturbations are derived. The same variables as used in a previous nonrelativistic guiding center code are adopted, so that a straightforward modifications of those equations can produce a relativistic version.
Relativistic Linear Restoring Force
Clark, D.; Franklin, J.; Mann, N.
2012-01-01
We consider two different forms for a relativistic version of a linear restoring force. The pair comes from taking Hooke's law to be the force appearing on the right-hand side of the relativistic expressions: d"p"/d"t" or d"p"/d["tau"]. Either formulation recovers Hooke's law in the non-relativistic limit. In addition to these two forces, we…
Generalized magnetofluid connections in relativistic magnetohydrodynamics.
Asenjo, Felipe A; Comisso, Luca
2015-03-20
The concept of magnetic connections is extended to nonideal relativistic magnetohydrodynamical plasmas. Adopting a general set of equations for relativistic magnetohydrodynamics including thermal-inertial, thermal electromotive, Hall, and current-inertia effects, we derive a new covariant connection equation showing the existence of generalized magnetofluid connections that are preserved during the dissipationless plasma dynamics. These connections are intimately linked to a general antisymmetric tensor that unifies the electromagnetic and fluid fields, allowing the extension of the magnetic connection notion to a much broader concept.
Mechanics, Waves and Thermodynamics
Ranjan Jain, Sudhir
2016-05-01
Figures; Preface; Acknowledgement; 1. Energy, mass, momentum; 2. Kinematics, Newton's laws of motion; 3. Circular motion; 4. The principle of least action; 5. Work and energy; 6. Mechanics of a system of particles; 7. Friction; 8. Impulse and collisions; 9. Central forces; 10. Dimensional analysis; 11. Oscillations; 12. Waves; 13. Sound of music; 14. Fluid mechanics; 15. Water waves; 16. The kinetic theory of gases; 17. Concepts and laws of thermodynamics; 18. Some applications of thermodynamics; 19. Basic ideas of statistical mechanics; Bibliography; Index.
BOOK REVIEW: Relativistic Figures of Equilibrium
Mars, M.
2009-08-01
Compact fluid bodies in equilibrium under its own gravitational field are abundant in the Universe and a proper treatment of them can only be carried out using the full theory of General Relativity. The problem is of enormous complexity as it involves two very different regimes, namely the interior and the exterior of the fluid, coupled through the surface of the body. This problem is very challenging both from a purely theoretical point of view, as well as regarding the obtaining of realistic models and the description of their physical properties. It is therefore an excellent piece of news that the book 'Relativistic Figures of Equilibrium' by R Meinel, M Ansorg, A Kleinwächter, G Neugebauer and D Petroff has been recently published. This book approaches the topic in depth and its contents will be of interest to a wide range of scientists working on gravitation, including theoreticians in general relativity, mathematical physicists, astrophysicists and numerical relativists. This is an advanced book that intends to present some of the present-day results on this topic. The most basic results are presented rather succinctly, and without going into the details, of their derivations. Although primarily not intended to serve as a textbook, the presentation is nevertheless self-contained and can therefore be of interest both for experts on the field as well as for anybody wishing to learn more about rotating self-gravitating compact bodies in equilibrium. It should be remarked, however, that this book makes a rather strong selection of topics and concentrates fundamentally on presenting the main results obtained by the authors during their research in this field. The book starts with a chapter where the fundamental aspects of rotating fluids in equilibrium, including its thermodynamic properties, are summarized. Of particular interest are the so-called mass-shedding limit, which is the limit where the body is rotating so fast that it is on the verge of starting
Generalized Relativistic Chapman-Enskog Solution of the Boltzmann Equation
García-Perciante, A L; García-Colin, L S
2007-01-01
The Chapman-Enskog method of solution of the relativistic Boltzmann equation is generalized in order to admit a time-derivative term associated to the thermodynamic force in its first order solution. Both existence and uniqueness of such a solution are proved based on the standard theory of integral equations. The mathematical implications of the generalization here introduced are briefly explored.
Relativistic quantum mechanics; Mecanique quantique relativiste
Ollitrault, J.Y. [CEA Saclay, 91 - Gif-sur-Yvette (France). Service de Physique Theorique]|[Universite Pierre et Marie Curie, 75 - Paris (France)
1998-12-01
These notes form an introduction to relativistic quantum mechanics. The mathematical formalism has been reduced to the minimum in order to enable the reader to calculate elementary physical processes. The second quantification and the field theory are the logical followings of this course. The reader is expected to know analytical mechanics (Lagrangian and Hamiltonian), non-relativistic quantum mechanics and some basis of restricted relativity. The purpose of the first 3 chapters is to define the quantum mechanics framework for already known notions about rotation transformations, wave propagation and restricted theory of relativity. The next 3 chapters are devoted to the application of relativistic quantum mechanics to a particle with 0,1/5 and 1 spin value. The last chapter deals with the processes involving several particles, these processes require field theory framework to be thoroughly described. (A.C.) 2 refs.
Towards relativistic quantum geometry
Ridao, Luis Santiago [Instituto de Investigaciones Físicas de Mar del Plata (IFIMAR), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Mar del Plata (Argentina); Bellini, Mauricio, E-mail: mbellini@mdp.edu.ar [Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes 3350, C.P. 7600, Mar del Plata (Argentina); Instituto de Investigaciones Físicas de Mar del Plata (IFIMAR), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Mar del Plata (Argentina)
2015-12-17
We obtain a gauge-invariant relativistic quantum geometry by using a Weylian-like manifold with a geometric scalar field which provides a gauge-invariant relativistic quantum theory in which the algebra of the Weylian-like field depends on observers. An example for a Reissner–Nordström black-hole is studied.
Relativistic modeling capabilities in PERSEUS extended MHD simulation code for HED plasmas
Hamlin, Nathaniel D., E-mail: nh322@cornell.edu [438 Rhodes Hall, Cornell University, Ithaca, NY, 14853 (United States); Seyler, Charles E., E-mail: ces7@cornell.edu [Cornell University, Ithaca, NY, 14853 (United States)
2014-12-15
We discuss the incorporation of relativistic modeling capabilities into the PERSEUS extended MHD simulation code for high-energy-density (HED) plasmas, and present the latest hybrid X-pinch simulation results. The use of fully relativistic equations enables the model to remain self-consistent in simulations of such relativistic phenomena as X-pinches and laser-plasma interactions. By suitable formulation of the relativistic generalized Ohm’s law as an evolution equation, we have reduced the recovery of primitive variables, a major technical challenge in relativistic codes, to a straightforward algebraic computation. Our code recovers expected results in the non-relativistic limit, and reveals new physics in the modeling of electron beam acceleration following an X-pinch. Through the use of a relaxation scheme, relativistic PERSEUS is able to handle nine orders of magnitude in density variation, making it the first fluid code, to our knowledge, that can simulate relativistic HED plasmas.
Relativistic and Non-relativistic Equations of Motion
Mangiarotti, L
1998-01-01
It is shown that any second order dynamic equation on a configuration space $X$ of non-relativistic time-dependent mechanics can be seen as a geodesic equation with respect to some (non-linear) connection on the tangent bundle $TX\\to X$ of relativistic velocities. Using this fact, the relationship between relativistic and non-relativistic equations of motion is studied.
Olander, Donald
2007-01-01
The book’s methodology is unified, concise, and multidisciplinary, allowing students to understand how the principles of thermodynamics apply to all technical fields that touch upon this most fundamental of scientific theories. It also offers a rigorous approach to the quantitative aspects of thermodynamics, accompanied by clear explanations to help students transition smoothly from the physical concepts to their mathematical representations
Relativistic simulation of the Vlasov equation for plasma expansion into vacuum
H Abbasi
2012-12-01
Full Text Available In this study, relativistic Vlasov simulation of plasma for expansion of collisionless plasma for into vacuum is presented. The model is based on 1+1 dimensional phase space and electrostatic approximation. For this purpose, the electron dynamics is studied by the relativistic Vlasov equation. Regardless of the ions temperature, fluid equations are used for their dynamics. The initial electrons distribution function is the relativistic Maxwellian. The results show that due to the electrons relativistic temperature, the process of the plasma expansion takes place faster, the resulting electric field is stronger and the ions are accelerated to higher velocities, in comparison to the non-relativistic case.
Hussain, S.; Mahmood, S.; Rehman, Aman-ur- [Theoretical Physics Division (TPD), PINSTECH, P.O. Nilore, Islamabad 44000, Pakistan and Pakistan Institute of Engineering and Applied Sciences (PIEAS), P.O. Nilore, Islamabad 44000 (Pakistan)
2014-11-15
Linear and nonlinear propagation of magnetosonic waves in the perpendicular direction to the ambient magnetic field is studied in dense plasmas for non-relativistic and ultra-relativistic degenerate electrons pressure. The sources of nonlinearities are the divergence of the ions and electrons fluxes, Lorentz forces on ions and electrons fluids and the plasma current density in the system. The Korteweg-de Vries equation for magnetosonic waves propagating in the perpendicular direction of the magnetic field is derived by employing reductive perturbation method for non-relativistic as well as ultra-relativistic degenerate electrons pressure cases in dense plasmas. The plots of the magnetosonic wave solitons are also shown using numerical values of the plasma parameters such a plasma density and magnetic field intensity of the white dwarfs from literature. The dependence of plasma density and magnetic field intensity on the magnetosonic wave propagation is also pointed out in dense plasmas for both non-relativistic and ultra-relativistic degenerate electrons pressure cases.
Relativistic dissipative hydrodynamics: where do we stand?
García-Perciante, A L; García-Colin, L S
2009-01-01
In this paper we analyze three different proposals that have been advanced to account for dissipative relativistic processes. Two of them are the so-called 'first order' theories of Eckart and Landau-Lifshitz, and a third one which is an extension of the classical Onsager-Meixner formulation of linear irreversible thermodynamics. We show that the two former ones, which are equivalent, do not obey the linear regression of fluctuations assumption which, besides being verified experimentally for the non-relativistic regime, lies at the heart of the proof of Onsager's reciprocity theorem. On the other hand, the third proposal is in agreement with such assumption. The consequence of these results, in particular those related to the so-called 'second order' theories, are thoroughly considered.
Behaviour of charged collapsing fluids after hydrostatic equilibrium in R{sup n} gravity
Kausar, Hafiza Rizwana [University of Central Punjab, Faculty of Management Studies, Centre for Applicable Mathematics and Statistics, UCP Business School, Lahore (Pakistan)
2017-06-15
The purpose of this paper is to study the transport equation and its coupling with the Maxwell equation in the framework of R{sup n} gravity. Using Mueller-Israel-Stewart theory for the conduction of dissipative fluids, we analyze the temperature, heat flux, viscosity and thermal conductivity in the scenario of relaxation time. All these thermodynamical variables appear in the form of a single factor whose influence is discussed on the evolution of relativistic model for the heat conducting collapsing star. (orig.)
New Relativistic Effects in the Dynamics of Nonlinear Hydrodynamical Waves
Rezzolla, L
2002-01-01
In Newtonian and relativistic hydrodynamics the Riemann problem consists of calculating the evolution of a fluid which is initially characterized by two states having different values of uniform rest-mass density, pressure and velocity. When the fluid is allowed to relax, one of three possible wave-patterns is produced, corresponding to the propagation in opposite directions of two nonlinear hydrodynamical waves. New effects emerge in a special relativistic Riemann problem when velocities tangential to the initial discontinuity surface are present. We show that a smooth transition from one wave-pattern to another can be produced by varying the initial tangential velocities while otherwise maintaining the initial states unmodified. These special relativistic effects are produced by the coupling through the relativistic Lorentz factors and do not have a Newtonian counterpart.
Estakhr, Ahmad Reza
2016-10-01
DJ̲μ/Dτ =J̲ν ∂νU̲μ + ∂νT̲μν +Γαβμ J̲αU̲β ︷ Steady Component + ∂νRμν +Γαβμ Rαβ ︷ Perturbations EAMG equations are proper time-averaged equations of relativistic motion for fluid flow and used to describe Relativistic Turbulent Flows. The EAMG equations are used to describe Relativistic Jet.
无
2002-01-01
It is a very difficult problem to directly determine fluid pressure during hydrocarbon migration and accumulation in sedimentary basins. pVt modeling of coupling hydrocarbon fluid inclusion of its coeval aqueous fluid inclusion provides a powerful tool for establishing the relationship of formation pressure evolution with time. Homogenization temperature of fluid inclusion can routinely be measured under microthermometric microscopy. Crushing technique has been employed to obtain the composition of fluid inclusions, and the commercial software VTFLINC easily and rapidly completes the construction of p-t phase diagram. The minimum trapping pressure of hydrocarbon fluid inclusion would be then determined in the p-t space. In this paper, three samples of YC21-1-1 and YC21-1-4 wells at YC21-1 structural closure, Qiongdongnan basin, South China Sea, were selected for the pVt modeling practice, and the formation pressure coefficient (equals to fluid pressure/hydrostatic pressure) changing trend with time has primarily been established. The modeling results also indicate that the reservoirs of Lingshui and Yacheng formations in YC21-1 structure are within a very high potential system and would have undergone a discharging of thermal fluids through top seal rupture, which depicts that there is a very high risk for natural gas exploration in this area.
Hydrodynamics of ultra-relativistic bubble walls
Leonardo Leitao
2016-04-01
Full Text Available In cosmological first-order phase transitions, gravitational waves are generated by the collisions of bubble walls and by the bulk motions caused in the fluid. A sizeable signal may result from fast-moving walls. In this work we study the hydrodynamics associated to the fastest propagation modes, namely, ultra-relativistic detonations and runaway solutions. We compute the energy injected by the phase transition into the fluid and the energy which accumulates in the bubble walls. We provide analytic approximations and fits as functions of the net force acting on the wall, which can be readily evaluated for specific models. We also study the back-reaction of hydrodynamics on the wall motion, and we discuss the extrapolation of the friction force away from the ultra-relativistic limit. We use these results to estimate the gravitational wave signal from detonations and runaway walls.
Magnetogenesis through Relativistic Velocity Shear
Miller, Evan
Magnetic fields at all scales are prevalent in our universe. However, current cosmological models predict that initially the universe was bereft of large-scale fields. Standard magnetohydrodynamics (MHD) does not permit magnetogenesis; in the MHD Faraday's law, the change in magnetic field B depends on B itself. Thus if B is initially zero, it will remain zero for all time. A more accurate physical model is needed to explain the origins of the galactic-scale magnetic fields observed today. In this thesis, I explore two velocity-driven mechanisms for magnetogenesis in 2-fluid plasma. The first is a novel kinematic 'battery' arising from convection of vorticity. A coupling between thermal and plasma oscillations, this non-relativistic mechanism can operate in flows that are incompressible, quasi-neutral and barotropic. The second mechanism results from inclusion of thermal effects in relativistic shear flow instabilities. In such flows, parallel perturbations are ubiquitously unstable at small scales, with growth rates of order with the plasma frequency over a defined range of parameter-space. Of these two processes, instabilities seem far more likely to account for galactic magnetic fields. Stable kinematic effects will, at best, be comparable to an ideal Biermann battery, which is suspected to be orders of magnitude too weak to produce the observed galactic fields. On the other hand, instabilities grow until saturation is reached, a topic that has yet to be explored in detail on cosmological scales. In addition to investigating these magnetogenesis sources, I derive a general dispersion relation for three dimensional, warm, two species plasma with discontinuous shear flow. The mathematics of relativistic plasma, sheared-flow instability and the Biermann battery are also discussed.
Classical thermodynamics of non-electrolyte solutions
Van Ness, H C
1964-01-01
Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for
An HLLC Solver for Relativistic Flows
Mignone, A
2005-01-01
We present an extension of the HLLC approximate Riemann solver by Toro, Spruce and Speares to the relativistic equations of fluid dynamics. The solver retains the simplicity of the original two-wave formulation proposed by Harten, Lax and van Leer (HLL) but it restores the missing contact wave in the solution of the Riemann problem. The resulting numerical scheme is computationally efficient, robust and positively conservative. The performance of the new solver is evaluated through numerical testing in one and two dimensions.
Relativistic spherical plasma waves
Bulanov, S. S.; Maksimchuk, A.; Schroeder, C. B.; Zhidkov, A. G.; Esarey, E.; Leemans, W. P.
2012-02-01
Tightly focused laser pulses that diverge or converge in underdense plasma can generate wake waves, having local structures that are spherical waves. Here we study theoretically and numerically relativistic spherical wake waves and their properties, including wave breaking.
Relativistic GLONASS and geodesy
Mazurova, E. M.; Kopeikin, S. M.; Karpik, A. P.
2016-12-01
GNSS technology is playing a major role in applications to civil, industrial and scientific areas. Nowadays, there are two fully functional GNSS: American GPS and Russian GLONASS. Their data processing algorithms have been historically based on the Newtonian theory of space and time with only a few relativistic effects taken into account as small corrections preventing the system from degradation on a fairly long time. Continuously growing accuracy of geodetic measurements and atomic clocks suggests reconsidering the overall approach to the GNSS theoretical model based on the Einstein theory of general relativity. This is essentially more challenging but fundamentally consistent theoretical approach to relativistic space geodesy. In this paper, we overview the basic principles of the relativistic GNSS model and explain the advantages of such a system for GLONASS and other positioning systems. Keywords: relativistic GLONASS, Einstein theory of general relativity.
Bliokh, Konstantin Y
2011-01-01
We consider the relativistic deformation of quantum waves and mechanical bodies carrying intrinsic angular momentum (AM). When observed in a moving reference frame, the centroid of the object undergoes an AM-dependent transverse shift. This is the relativistic analogue of the spin Hall effect, which occurs in free space without any external fields. Remarkably, the shifts of the geometric and energy centroids differ by a factor of 2, and both centroids are crucial for the correct Lorentz transformations of the AM tensor. We examine manifestations of the relativistic Hall effect in quantum vortices, mechanical flywheel, and discuss various fundamental aspects of the phenomenon. The perfect agreement of quantum and relativistic approaches allows applications at strikingly different scales: from elementary spinning particles, through classical light, to rotating black-holes.
Beyond ideal magnetohydrodynamics: Resistive, reactive and relativistic plasmas
Andersson, N; Hawke, I; Comer, G L
2016-01-01
We develop a new framework for the modelling of charged fluid dynamics in general relativity. The model, which builds on a recently developed variational multi-fluid model for dissipative fluids, accounts for relevant effects like the inertia of both charge currents and heat and, for mature systems, the decoupling of superfluid components. We discuss how the model compares to standard relativistic magnetohydronamics and consider the connection between the fluid dynamics, the microphysics and the underlying equation of state. As illustrations of the formalism, we consider three distinct two-fluid models describing i) an Ohm's law for resistive charged flows, ii) a relativistic heat equation, and iii) an equation representing the momentum of a decoupled superfluid component. As a more complex example, we also formulate a three-fluid model which demonstrates the thermo-electric effect. This framework allows us to model neutron stars (and related systems) at a hierarchy of increasingly complex levels, and should ...
Relativistic and non-relativistic solitons in plasmas
Barman, Satyendra Nath
This thesis entitled as "Relativistic and Non-relativistic Solitons in Plasmas" is the embodiment of a number of investigations related to the formation of ion-acoustic solitary waves in plasmas under various physical situations. The whole work of the thesis is devoted to the studies of solitary waves in cold and warm collisionless magnetized or unmagnetized plasmas with or without relativistic effect. To analyze the formation of solitary waves in all our models of plasmas, we have employed two established methods namely - reductive perturbation method to deduce the Korteweg-de Vries (KdV) equation, the solutions of which represent the important but near exact characteristic concepts of soliton-physics. Next, the pseudopotential method to deduce the energy integral with total nonlinearity in the coupling process for exact characteristic results of solitons has been incorporated. In Chapter 1, a brief description of plasma in nature and laboratory and its generation are outlined elegantly. The nonlinear differential equations to characterize solitary waves and the relevant but important methods of solutions have been mentioned in this chapter. The formation of solitary waves in unmagnetized and magnetized plasmas, and in relativistic plasmas has been described through mathematical entity. Applications of plasmas in different fields are also put forwarded briefly showing its importance. The study of plasmas as they naturally occur in the universe encompasses number of topics including sun's corona, solar wind, planetary magnetospheres, ionospheres, auroras, cosmic rays and radiation. The study of space weather to understand the universe, communications and the activities of weather satellites are some useful areas of space plasma physics. The surface cleaning, sterilization of food and medical appliances, killing of bacteria on various surfaces, destroying of viruses, fungi, spores and plasma coating in industrial instruments ( like computers) are some of the fields
Exact Relativistic 'Antigravity' Propulsion
Felber, F S
2006-01-01
The Schwarzschild solution is used to find the exact relativistic motion of a payload in the gravitational field of a mass moving with constant velocity. At radial approach or recession speeds faster than 3^-1/2 times the speed of light, even a small mass gravitationally repels a payload. At relativistic speeds, a suitable mass can quickly propel a heavy payload from rest nearly to the speed of light with negligible stresses on the payload.
Exact Relativistic `Antigravity' Propulsion
Felber, Franklin S.
2006-01-01
The Schwarzschild solution is used to find the exact relativistic motion of a payload in the gravitational field of a mass moving with constant velocity. At radial approach or recession speeds faster than 3-1/2 times the speed of light, even a small mass gravitationally repels a payload. At relativistic speeds, a suitable mass can quickly propel a heavy payload from rest nearly to the speed of light with negligible stresses on the payload.
Relativistic quantum revivals.
Strange, P
2010-03-26
Quantum revivals are now a well-known phenomena within nonrelativistic quantum theory. In this Letter we display the effects of relativity on revivals and quantum carpets. It is generally believed that revivals do not occur within a relativistic regime. Here we show that while this is generally true, it is possible, in principle, to set up wave packets with specific mathematical properties that do exhibit exact revivals within a fully relativistic theory.
Cengel, Y.A. [Nevada Univ., Reno, NV (United States). Dept. of Mechanical Engineering
2006-07-01
Green components of thermodynamics were identified and general aspects of green practices associated with thermodynamics were assessed. Energy uses associated with fossil fuels were reviewed. Green energy sources such as solar, wind, geothermal and hydropower were discussed, as well as biomass plantations. Ethanol production practices were reviewed. Conservation practices in the United States were outlined. Energy efficiency and exergy analyses were discussed. Energy intensity measurements and insulation products for houses were also reviewed. Five case studies were presented to illustrate aspects of green thermodynamics: (1) light in a classroom; (2) fuel saved by low-resistance tires; and (3) savings with high-efficiency motors; (4) renewable energy; and (5) replacing a valve with a turbine at a cryogenic manufacturing facility. It was concluded that the main principles of green thermodynamics are to ensure that all material and energy inputs minimize the depletion of energy resources; prevent waste; and improve or innovate technologies that achieve sustainability. 17 refs., 2 tabs., 9 figs.
Iribarne, J V
1973-01-01
The thermodynamics of the atmosphere is the subject of several chapters in most textbooks on dynamic meteorology, but there is no work in English to give the subject a specific and more extensive treatment. In writing the present textbook, we have tried to fill this rather remarkable gap in the literature related to atmospheric sciences. Our aim has been to provide students of meteorology with a book that can playa role similar to the textbooks on chemical thermodynamics for the chemists. This implies a previous knowledge of general thermodynamics, such as students acquire in general physics courses; therefore, although the basic principles are reviewed (in the first four chapters), they are only briefly discussed, and emphasis is laid on those topics that will be useful in later chapters, through their application to atmospheric problems. No attempt has been made to introduce the thermodynamics of irreversible processes; on the other hand, consideration of heterogeneous and open homogeneous systems permits a...
Akinfiev, Nikolai; Zotov, Alexander
1999-07-01
A new method for computing complicated equilibria in hydrothermal mixed fluids, H 2O-non-polar gas, is proposed. The computation algorithm is based on the electrostatic approach for the interaction between aqueous species and H 2O. The approach uses the SUPCRT92 database and the HKF format and may be considered as an application of the revised HKF model for mixed H 2O-non-polar gas fluids. Thermodynamic properties of dissolved gases at high temperatures and pressures are calculated using the Redlich-Kwong approach. Dielectric permittivity of the mixed solvent is estimated by the modified Kirkwood equation. The proposed approach is validated using available experimental data on the dissociation constants of H 2O and NaCl and the solubility of both covalent and ion crystals (SiO 2, AgCl, Ag 2SO 4, Ca(OH) 2, CaCO 3) in H 2O-non-polar component (dioxane, Ar, CO 2) mixtures. Predicted and experimental data are in close agreement over a wide range of P- T- xgas conditions (up to 500°C, 4 kbar and 0.25-0.3 mole fraction of non-polar gas). It is also shown how the computation method can be applied to estimate the Born parameters of aqueous species. The proposed approach enables not only examination of isolated reactions, but the study of equilibria of whole systems. Thus, it allows modelling of mixed natural fluids.
Noether Theorem of Relativistic-Electromagnetic Ideal Hydrodynamics
Elsas, J H Gaspar; Kodama, T
2014-01-01
We present a variational approach for relativistic ideal hydrodynamics interacting with electromagnetic fields. The momentum of fluid is introduced as the canonical conjugate variable of the position of a fluid element, which coincides with the conserved quantity derived from the Noether theorem. We further show that our formulation can reproduce the usual electromagnetic hydrodynamics which is obtained so as to satisfy the conservation of the inertia of fluid motion.
Thermophysical Properties of Fluids and Fluid Mixtures
Sengers, Jan V.; Anisimov, Mikhail A.
2004-05-03
The major goal of the project was to study the effect of critical fluctuations on the thermophysical properties and phase behavior of fluids and fluid mixtures. Long-range fluctuations appear because of the presence of critical phase transitions. A global theory of critical fluctuations was developed and applied to represent thermodynamic properties and transport properties of molecular fluids and fluid mixtures. In the second phase of the project, the theory was extended to deal with critical fluctuations in complex fluids such as polymer solutions and electrolyte solutions. The theoretical predictions have been confirmed by computer simulations and by light-scattering experiments. Fluctuations in fluids in nonequilibrium states have also been investigated.
The relativistic electro-vortical field—revisiting magneto-genesis and allied problems
Mahajan, Swadesh M.
2016-11-01
Following the idea of MagnetoFluid unification [S. M. Mahajan, Phys. Rev. Lett. 90, 035001 (2003)], a very general Electro-Vortical (EV) field is constructed to describe the dynamics of a perfect relativistic fluid. Structurally similar to the electromagnetic field Fμν , the Electro-Vortical field Mνμ unifies the macroscopic forces into a single grand force that is the weighted sum of the electromagnetic and the inertial/thermal forces. The new effective force may be viewed either as a vortico-thermal generalization of the electromagnetic force or as the electromagnetic generalization of the vortico-thermal forces that a fluid element experiences in course of its evolution. Two fundamental consequences follow from this grand unification: (1) emergences of a new helicity that is conserved for arbitrary thermodynamics and (2) the entire dynamics is formally expressible as an MHD (magnetohydrodynamics) like ideal Ohm's law in which the "electric" and "magnetic" components of the EV field replace the standard electric and magnetic fields. In the light of these more and more encompassing conserved helicities, the "scope and significance" of the classical problem of magneto-genesis (need for a seed field to get a dynamo started) is reexamined. It is shown that in models more advanced than MHD, looking for exotic seed-generation mechanisms (like the baroclinic thermodynamics) should not constitute a fundamental pursuit; the totally ideal dynamics is perfectly capable of generating and sustaining magnetic fields entirely within its own devices. For a specified thermodynamics, a variety of exact and semi exact self-consistent analytical solutions for equilibrium magnetic and flow fields are derived for a single species charged fluid. The scale lengths of the fields are determined by two natural scale lengths: the skin depth and the gradient length of the thermodynamic quantities. Generally, the skin depth, being the shorter (even much shorter) than the gradient length
Fluid Dynamics and Entropic Gravity
Nagle, Ian
2016-01-01
A new entropic gravity inspired derivation of general relativity from thermodynamics is presented. This generalizes, within Einstein gravity, the "Thermodynamics of Spacetime" approach by T. Jacobson, which relies on the Raychaudhuri evolution equation. Here the rest of the first law of thermodynamics is incorporated by using the Damour-Navier-Stokes equation, known from the membrane paradigm for describing fluid dynamics on the horizon.
Relativistic MHD with adaptive mesh refinement
Anderson, Matthew [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803-4001 (United States); Hirschmann, Eric W [Department of Physics and Astronomy, Brigham Young University, Provo, UT 84602 (United States); Liebling, Steven L [Department of Physics, Long Island University-C W Post Campus, Brookville, NY 11548 (United States); Neilsen, David [Department of Physics and Astronomy, Brigham Young University, Provo, UT 84602 (United States)
2006-11-22
This paper presents a new computer code to solve the general relativistic magnetohydrodynamics (GRMHD) equations using distributed parallel adaptive mesh refinement (AMR). The fluid equations are solved using a finite difference convex ENO method (CENO) in 3 + 1 dimensions, and the AMR is Berger-Oliger. Hyperbolic divergence cleaning is used to control the {nabla} . B = 0 constraint. We present results from three flat space tests, and examine the accretion of a fluid onto a Schwarzschild black hole, reproducing the Michel solution. The AMR simulations substantially improve performance while reproducing the resolution equivalent unigrid simulation results. Finally, we discuss strong scaling results for parallel unigrid and AMR runs.
Relativistic heavy-ion collisions
Bhalerao, Rajeev S
2014-01-01
The field of relativistic heavy-ion collisions is introduced to the high-energy physics students with no prior knowledge in this area. The emphasis is on the two most important observables, namely the azimuthal collective flow and jet quenching, and on the role fluid dynamics plays in the interpretation of the data. Other important observables described briefly are constituent quark number scaling, ratios of particle abundances, strangeness enhancement, and sequential melting of heavy quarkonia. Comparison is made of some of the basic heavy-ion results obtained at LHC with those obtained at RHIC. Initial findings at LHC which seem to be in apparent conflict with the accumulated RHIC data are highlighted.
The relativistic bound states of a non-central potential
MAHDI ESHGHI; HOSSEIN MEHRABAN; SAMEER MIKHDAIR
2017-04-01
We investigate the relativistic effects of a moving particle in the field of a pseudoharmonic oscillatory ring-shaped potential under the spin and pseudospin symmetric Dirac wave equation. We obtain the bound-state energy eigenvalue equation and the corresponding two-components spinor wave functions by using the formalism of supersymmetric quantum mechanics (SUSYQM). Furthermore, the non-relativistic limits are obtained by simply making a proper replacement of parameters. The thermodynamic properties are also studied. Our numerical results for the energy eigenvalues are also presented.
Relativistic simulation of the Vlasov equation for plasma expansion into vacuum
H ABBASI; R Shokoohi; Moridi, M.
2012-01-01
In this study, relativistic Vlasov simulation of plasma for expansion of collisionless plasma for into vacuum is presented. The model is based on 1+1 dimensional phase space and electrostatic approximation. For this purpose, the electron dynamics is studied by the relativistic Vlasov equation. Regardless of the ions temperature, fluid equations are used for their dynamics. The initial electrons distribution function is the relativistic Maxwellian. The results show that due to the electrons ...
Bansal, Artee; Asthagiri, D; Cox, Kenneth R; Chapman, Walter G
2016-08-21
A mixture of solvent particles with short-range, directional interactions and solute particles with short-range, isotropic interactions that can bond multiple times is of fundamental interest in understanding liquids and colloidal mixtures. Because of multi-body correlations, predicting the structure and thermodynamics of such systems remains a challenge. Earlier Marshall and Chapman [J. Chem. Phys. 139, 104904 (2013)] developed a theory wherein association effects due to interactions multiply the partition function for clustering of particles in a reference hard-sphere system. The multi-body effects are incorporated in the clustering process, which in their work was obtained in the absence of the bulk medium. The bulk solvent effects were then modeled approximately within a second order perturbation approach. However, their approach is inadequate at high densities and for large association strengths. Based on the idea that the clustering of solvent in a defined coordination volume around the solute is related to occupancy statistics in that defined coordination volume, we develop an approach to incorporate the complete information about hard-sphere clustering in a bulk solvent at the density of interest. The occupancy probabilities are obtained from enhanced sampling simulations but we also develop a concise parametric form to model these probabilities using the quasichemical theory of solutions. We show that incorporating the complete reference information results in an approach that can predict the bonding state and thermodynamics of the colloidal solute for a wide range of system conditions.
Stiegler, Thomas [Technische Fakultät, Friedrich-Alexander-Universität Erlangen-Nürnberg, Martensstraße 5a, 91058 Erlangen (Germany); Sadus, Richard J., E-mail: rsadus@swin.edu.au [Centre for Molecular Simulation, Swinburne University of Technology, P.O. Box 218 Hawthorn, Victoria 3122 (Australia)
2015-02-28
General methods for combining interactions between particles characterised by non-identical intermolecular potentials are investigated. The combination methods are tested by performing molecular dynamics simulations to determine the pressure, energy, isochoric and isobaric heat capacities, thermal expansion coefficient, isothermal compressibility, Joule-Thomson coefficient, and speed of sound of 10-5 + 12-6 Mie potential binary mixtures. In addition to the two non-identical Mie potentials, mixtures are also studied with non-identical intermolecular parameters. The combination methods are compared with results obtained by simply averaging the Mie exponents. When either the energy or size parameters are non-identical, very significant differences emerge in the thermodynamic properties predicted by the alternative combination methods. The isobaric heat capacity is the thermodynamic property that is most affected by the relative magnitude of the intermolecular potential parameters and the method for combining non-identical potentials. Either the arithmetic or geometric combination of potentials provides a simple and effective way of performing simulations involving mixtures of components characterised by non-identical intermolecular potentials, which is independent of their functional form.
Stiegler, Thomas; Sadus, Richard J.
2015-02-01
General methods for combining interactions between particles characterised by non-identical intermolecular potentials are investigated. The combination methods are tested by performing molecular dynamics simulations to determine the pressure, energy, isochoric and isobaric heat capacities, thermal expansion coefficient, isothermal compressibility, Joule-Thomson coefficient, and speed of sound of 10-5 + 12-6 Mie potential binary mixtures. In addition to the two non-identical Mie potentials, mixtures are also studied with non-identical intermolecular parameters. The combination methods are compared with results obtained by simply averaging the Mie exponents. When either the energy or size parameters are non-identical, very significant differences emerge in the thermodynamic properties predicted by the alternative combination methods. The isobaric heat capacity is the thermodynamic property that is most affected by the relative magnitude of the intermolecular potential parameters and the method for combining non-identical potentials. Either the arithmetic or geometric combination of potentials provides a simple and effective way of performing simulations involving mixtures of components characterised by non-identical intermolecular potentials, which is independent of their functional form.
Bansal, Artee; Asthagiri, D.; Cox, Kenneth R.; Chapman, Walter G.
2016-08-01
A mixture of solvent particles with short-range, directional interactions and solute particles with short-range, isotropic interactions that can bond multiple times is of fundamental interest in understanding liquids and colloidal mixtures. Because of multi-body correlations, predicting the structure and thermodynamics of such systems remains a challenge. Earlier Marshall and Chapman [J. Chem. Phys. 139, 104904 (2013)] developed a theory wherein association effects due to interactions multiply the partition function for clustering of particles in a reference hard-sphere system. The multi-body effects are incorporated in the clustering process, which in their work was obtained in the absence of the bulk medium. The bulk solvent effects were then modeled approximately within a second order perturbation approach. However, their approach is inadequate at high densities and for large association strengths. Based on the idea that the clustering of solvent in a defined coordination volume around the solute is related to occupancy statistics in that defined coordination volume, we develop an approach to incorporate the complete information about hard-sphere clustering in a bulk solvent at the density of interest. The occupancy probabilities are obtained from enhanced sampling simulations but we also develop a concise parametric form to model these probabilities using the quasichemical theory of solutions. We show that incorporating the complete reference information results in an approach that can predict the bonding state and thermodynamics of the colloidal solute for a wide range of system conditions.
Molecular Thermodynamics for Chemical Process Design
Prausnitz, J. M.
1976-01-01
Discusses that aspect of thermodynamics which is particularly important in chemical process design: the calculation of the equilibrium properties of fluid mixtures, especially as required in phase-separation operations. (MLH)
Whale, MacMurray D.; Cravalho, Ernest G.
This paper describes two parallel efforts that attempt to implement a new approach to the teaching of thermal fluids engineering. In one setting, at the Massachusetts Institute of Technology (MIT), the subject matter is integrated into a single year-long subject at the introductory level. In the second setting, at Victoria (British Columbia,…
Eichhorn, Ralf; Aurell, Erik
2014-04-01
'Stochastic thermodynamics as a conceptual framework combines the stochastic energetics approach introduced a decade ago by Sekimoto [1] with the idea that entropy can consistently be assigned to a single fluctuating trajectory [2]'. This quote, taken from Udo Seifert's [3] 2008 review, nicely summarizes the basic ideas behind stochastic thermodynamics: for small systems, driven by external forces and in contact with a heat bath at a well-defined temperature, stochastic energetics [4] defines the exchanged work and heat along a single fluctuating trajectory and connects them to changes in the internal (system) energy by an energy balance analogous to the first law of thermodynamics. Additionally, providing a consistent definition of trajectory-wise entropy production gives rise to second-law-like relations and forms the basis for a 'stochastic thermodynamics' along individual fluctuating trajectories. In order to construct meaningful concepts of work, heat and entropy production for single trajectories, their definitions are based on the stochastic equations of motion modeling the physical system of interest. Because of this, they are valid even for systems that are prevented from equilibrating with the thermal environment by external driving forces (or other sources of non-equilibrium). In that way, the central notions of equilibrium thermodynamics, such as heat, work and entropy, are consistently extended to the non-equilibrium realm. In the (non-equilibrium) ensemble, the trajectory-wise quantities acquire distributions. General statements derived within stochastic thermodynamics typically refer to properties of these distributions, and are valid in the non-equilibrium regime even beyond the linear response. The extension of statistical mechanics and of exact thermodynamic statements to the non-equilibrium realm has been discussed from the early days of statistical mechanics more than 100 years ago. This debate culminated in the development of linear response
Black hole chemistry: thermodynamics with Lambda
Kubiznak, David; Teo, Mae
2016-01-01
We review recent developments on the thermodynamics of black holes in extended phase space, where the cosmological constant is interpreted as thermodynamic pressure and treated as a thermodynamic variable in its own right. In this approach, the mass of the black hole is no longer regarded as internal energy, rather it is identified with the chemical enthalpy. This leads to an extended dictionary for black hole thermodynamic quantities, in particular a notion of thermodynamic volume emerges for a given black hole spacetime. This volume is conjectured to satisfy the reverse isoperimetric inequality - an inequality imposing a bound on the amount of entropy black hole can carry for a fixed thermodynamic volume. New thermodynamic phase transitions naturally emerge from these identifications. Namely, we show that black holes can be understood from the viewpoint of chemistry, in terms of concepts such as Van der Waals fluids, reentrant phase transitions, and triple points. We also review the recent attempts at exten...
Ben-Naim, Arieh
2017-01-01
This textbook introduces thermodynamics with a modern approach, starting from four fundamental physical facts (the atomic nature of matter, the indistinguishability of atoms and molecules of the same species, the uncertainty principle, and the existence of equilibrium states) and analyzing the behavior of complex systems with the tools of information theory, in particular with Shannon's measure of information (or SMI), which can be defined on any probability distribution. SMI is defined and its properties and time evolution are illustrated, and it is shown that the entropy is a particular type of SMI, i.e. the SMI related to the phase-space distribution for a macroscopic system at equilibrium. The connection to SMI allows the reader to understand what entropy is and why isolated systems follow the Second Law of Thermodynamics. The Second Llaw is also formulated for other systems, not thermally isolated and even open with respect to the transfer of particles. All the fundamental aspects of thermodynamics are d...
Relativistic hadrons and the origin of relativistic outflows in active galactic nuclei
Contopoulos, John; Kazanas, D.
1995-01-01
We examine the hydrodynamic origin of relativistic outflows in active galactic nuclei (AGN). Specifically, we propose that the presence of a population of relativistic hadrons in the AGN 'central engine' and the associated neutron production suffices to produce outflows which under rather general conditions could be relativistic. The main such condition is that the size of the neutron production region be larger than the neutron flight path tau(sub n) approximately 3 x 10(exp 13) cm. This condition guarantees that the mean energy per particle in the proton fluid, resulting from the decay of the neutrons outside their production region, be greater than the proton rest mass. The expansion of this fluid can then lead naturally to a relativistic outflow by conversion of its internal energy to directed motion. We follow the development of such flows by solving the mass, energy as well as the kinetic equation for the proton gas in steady state, taking into account the source terms due to compute accurately the adiabatic index of the expanding gas, and in conjunction with Bernoulli's equation the detailed evolution of the bulk Lorentz factor. We further examine the role of large-scale magnetic fields in confining these outflows to produce the jets observed at larger scales.
Demtröder, Wolfgang
2017-01-01
This introduction to classical mechanics and thermodynamics provides an accessible and clear treatment of the fundamentals. Starting with particle mechanics and an early introduction to special relativity this textbooks enables the reader to understand the basics in mechanics. The text is written from the experimental physics point of view, giving numerous real life examples and applications of classical mechanics in technology. This highly motivating presentation deepens the knowledge in a very accessible way. The second part of the text gives a concise introduction to rotational motion, an expansion to rigid bodies, fluids and gases. Finally, an extensive chapter on thermodynamics and a short introduction to nonlinear dynamics with some instructive examples intensify the knowledge of more advanced topics. Numerous problems with detailed solutions are perfect for self study.
Relativistic Quantum Communication
Hosler, Dominic
2013-01-01
In this Ph.D. thesis, I investigate the communication abilities of non-inertial observers and the precision to which they can measure parametrized states. I introduce relativistic quantum field theory with field quantisation, and the definition and transformations of mode functions in Minkowski, Schwarzschild and Rindler spaces. I introduce information theory by discussing the nature of information, defining the entropic information measures, and highlighting the differences between classical and quantum information. I review the field of relativistic quantum information. We investigate the communication abilities of an inertial observer to a relativistic observer hovering above a Schwarzschild black hole, using the Rindler approximation. We compare both classical communication and quantum entanglement generation of the state merging protocol, for both the single and dual rail encodings. We find that while classical communication remains finite right up to the horizon, the quantum entanglement generation tend...
Relativistic quantum mechanics
Horwitz, Lawrence P
2015-01-01
This book describes a relativistic quantum theory developed by the author starting from the E.C.G. Stueckelberg approach proposed in the early 40s. In this framework a universal invariant evolution parameter (corresponding to the time originally postulated by Newton) is introduced to describe dynamical evolution. This theory is able to provide solutions for some of the fundamental problems encountered in early attempts to construct a relativistic quantum theory. A relativistically covariant construction is given for which particle spins and angular momenta can be combined through the usual rotation group Clebsch-Gordan coefficients. Solutions are defined for both the classical and quantum two body bound state and scattering problems. The recently developed quantum Lax-Phillips theory of semigroup evolution of resonant states is described. The experiment of Lindner and coworkers on interference in time is discussed showing how the property of coherence in time provides a simple understanding of the results. Th...
Matsas, G E A
2003-01-01
We investigate and solve in the context of General Relativity the apparent paradox which appears when bodies floating in a background fluid are set in relativistic motion. Suppose some macroscopic body, say, a submarine designed to lie just in equilibrium when it rests (totally) immersed in a certain background fluid. The puzzle arises when different observers are asked to describe what is expected to happen when the submarine is given some high velocity parallel to the direction of the fluid surface. On the one hand, according to observers at rest with the fluid, the submarine would contract and, thus, sink as a consequence of the density increase. On the other hand, mariners at rest with the submarine using an analogous reasoning for the fluid elements would reach the opposite conclusion. The general relativistic extension of the Arquimedes law for moving bodies shows that the submarine sinks.
Handbook of relativistic quantum chemistry
Liu, Wenjian (ed.) [Peking Univ., Beijing (China). Center for Computational Science and Engineering
2017-03-01
This handbook focuses on the foundations of relativistic quantum mechanics and addresses a number of fundamental issues never covered before in a book. For instance: How can many-body theory be combined with quantum electrodynamics? How can quantum electrodynamics be interfaced with relativistic quantum chemistry? What is the most appropriate relativistic many-electron Hamiltonian? How can we achieve relativistic explicit correlation? How can we formulate relativistic properties? - just to name a few. Since relativistic quantum chemistry is an integral component of computational chemistry, this handbook also supplements the ''Handbook of Computational Chemistry''. Generally speaking, it aims to establish the 'big picture' of relativistic molecular quantum mechanics as the union of quantum electrodynamics and relativistic quantum chemistry. Accordingly, it provides an accessible introduction for readers new to the field, presents advanced methodologies for experts, and discusses possible future perspectives, helping readers understand when/how to apply/develop the methodologies.
Bansal, Artee; Cox, Kenneth R; Chapman, Walter G
2016-01-01
A mixture of solvent particles with short-range, directional interactions and solute particles with short-range, isotropic interactions that can bond multiple times is of fundamental interest in understanding liquids and colloidal mixtures. Because of multi-body correlations predicting the structure and thermodynamics of such systems remains a challenge. Earlier Marshall and Chapman developed a theory wherein association effects due to interactions multiply the partition function for clustering of particles in a reference hard-sphere system. The multi-body effects are incorporated in the clustering process, which in their work was obtained in the absence of the bulk medium. The bulk solvent effects were then modeled approximately within a second order perturbation approach. However, their approach is inadequate at high densities and for large association strengths. Based on the idea that the clustering of solvent in a defined coordination volume around the solute is related to occupancy statistics in that def...
Relativistic electronic dressing
Attaourti, Y
2002-01-01
We study the effects of the relativistic electronic dressing in laser-assisted electron-hydrogen atom elastic collisions. We begin by considering the case when no radiation is present. This is necessary in order to check the consistency of our calculations and we then carry out the calculations using the relativistic Dirac-Volkov states. It turns out that a simple formal analogy links the analytical expressions of the differential cross section without laser and the differential cross section in presence of a laser field.
Fabian, A C; Parker, M L
2014-01-01
Broad emission lines, particularly broad iron-K lines, are now commonly seen in the X-ray spectra of luminous AGN and Galactic black hole binaries. Sensitive NuSTAR spectra over the energy range of 3-78 keV and high frequency reverberation spectra now confirm that these are relativistic disc lines produced by coronal irradiation of the innermost accretion flow around rapidly spinning black holes. General relativistic effects are essential in explaining the observations. Recent results are briefly reviewed here.
Relativistic Rotating Vector Model
Lyutikov, Maxim
2016-01-01
The direction of polarization produced by a moving source rotates with the respect to the rest frame. We show that this effect, induced by pulsar rotation, leads to an important correction to polarization swings within the framework of rotating vector model (RVM); this effect has been missed by previous works. We construct relativistic RVM taking into account finite heights of the emission region that lead to aberration, time-of-travel effects and relativistic rotation of polarization. Polarizations swings at different frequencies can be used, within the assumption of the radius-to-frequency mapping, to infer emission radii and geometry of pulsars.
The special relativistic shock tube
Thompson, Kevin W.
1986-01-01
The shock-tube problem has served as a popular test for numerical hydrodynamics codes. The development of relativistic hydrodynamics codes has created a need for a similar test problem in relativistic hydrodynamics. The analytical solution to the special relativistic shock-tube problem is presented here. The relativistic shock-jump conditions and rarefaction solution which make up the shock tube are derived. The Newtonian limit of the calculations is given throughout.
Causal dissipation for the relativistic dynamics of ideal gases
Freistühler, Heinrich; Temple, Blake
2017-05-01
We derive a general class of relativistic dissipation tensors by requiring that, combined with the relativistic Euler equations, they form a second-order system of partial differential equations which is symmetric hyperbolic in a second-order sense when written in the natural Godunov variables that make the Euler equations symmetric hyperbolic in the first-order sense. We show that this class contains a unique element representing a causal formulation of relativistic dissipative fluid dynamics which (i) is equivalent to the classical descriptions by Eckart and Landau to first order in the coefficients of viscosity and heat conduction and (ii) has its signal speeds bounded sharply by the speed of light. Based on these properties, we propose this system as a natural candidate for the relativistic counterpart of the classical Navier-Stokes equations.
Causal dissipation for the relativistic dynamics of ideal gases.
Freistühler, Heinrich; Temple, Blake
2017-05-01
We derive a general class of relativistic dissipation tensors by requiring that, combined with the relativistic Euler equations, they form a second-order system of partial differential equations which is symmetric hyperbolic in a second-order sense when written in the natural Godunov variables that make the Euler equations symmetric hyperbolic in the first-order sense. We show that this class contains a unique element representing a causal formulation of relativistic dissipative fluid dynamics which (i) is equivalent to the classical descriptions by Eckart and Landau to first order in the coefficients of viscosity and heat conduction and (ii) has its signal speeds bounded sharply by the speed of light. Based on these properties, we propose this system as a natural candidate for the relativistic counterpart of the classical Navier-Stokes equations.
Numerical Simulations of Driven Supersonic Relativistic MHD Turbulence
Zrake, Jonathan; 10.1063/1.3621748
2011-01-01
Models for GRB outflows invoke turbulence in relativistically hot magnetized fluids. In order to investigate these conditions we have performed high-resolution three-dimensional numerical simulations of relativistic magneto-hydrodynamical (RMHD) turbulence. We find that magnetic energy is amplified to several percent of the total energy density by turbulent twisting and folding of magnetic field lines. Values of epsilon_B near 1% are thus naturally expected. We study the dependence of saturated magnetic field energy fraction as a function of Mach number and relativistic temperature. We then present power spectra of the turbulent kinetic and magnetic energies. We also present solenoidal (curl-like) and dilatational (divergence-like) power spectra of kinetic energy. We propose that relativistic effects introduce novel couplings between these spectral components. The case we explore in most detail is for equal amounts of thermal and rest mass energy, corresponding to conditions after collisions of shells with re...
Bruce, Adam L
2015-01-01
We show the traditional rocket problem, where the ejecta velocity is assumed constant, can be reduced to an integral quadrature of which the completely non-relativistic equation of Tsiolkovsky, as well as the fully relativistic equation derived by Ackeret, are limiting cases. By expanding this quadrature in series, it is shown explicitly how relativistic corrections to the mass ratio equation as the rocket transitions from the Newtonian to the relativistic regime can be represented as products of exponential functions of the rocket velocity, ejecta velocity, and the speed of light. We find that even low order correction products approximate the traditional relativistic equation to a high accuracy in flight regimes up to $0.5c$ while retaining a clear distinction between the non-relativistic base-case and relativistic corrections. We furthermore use the results developed to consider the case where the rocket is not moving relativistically but the ejecta stream is, and where the ejecta stream is massless.
Instability of Extremal Relativistic Charged Spheres
Anninos, P; Anninos, Peter; Rothman, Tony
2002-01-01
With the question, ``Can relativistic charged spheres form extremal black holes?" in mind, we investigate the properties of such spheres from a classical point of view. The investigation is carried out numerically by integrating the Oppenheimer-Volkov equation for relativistic charged fluid spheres and finding interior Reissner-Nordstr\\"om solutions for these objects. We consider both constant density and adiabatic equations of state, as well as several possible charge distributions, and examine stability by both a normal mode and an energy analysis. In all cases, the stability limit for these spheres lies between the extremal ($Q = M$) limit and the black hole limit ($R = R_+$). That is, we find that charged spheres undergo gravitational collapse before they reach $Q = M$, suggesting that extremal Reissner-Nordtr\\"om black holes produced by collapse are ruled out. A general proof of this statement would support a strong form of the cosmic censorship hypothesis, excluding not only stable naked singularities, ...
Exact Relativistic Magnetized Haloes around Rotating Disks
Antonio C. Gutiérrez-Piñeres
2015-01-01
Full Text Available The study of the dynamics of magnetic fields in galaxies is one of important problems in formation and evolution of galaxies. In this paper, we present the exact relativistic treatment of a rotating disk surrounded by a magnetized material halo. The features of the halo and disk are described by the distributional energy-momentum tensor of a general fluid in canonical form. All the relevant quantities and the metric and electromagnetic potentials are exactly determined by an arbitrary harmonic function only. For instance, the generalized Kuzmin-disk potential is used. The particular class of solutions obtained is asymptotically flat and satisfies all the energy conditions. Moreover, the motion of a charged particle on the halo is described. As far as we know, this is the first relativistic model describing analytically the magnetized halo of a rotating disk.
Jentsch, Marie; Tropper, Peter
2015-04-01
A common feature of HP and UHP terranes is the subduction of crustal rocks to great depths. Previous investigations have shown that this process is triggered by fluids present during an eclogite-facies metamorphic overprint. An examples is exposed in the metapelites at Val Savenca in the Sesia-Lanzo Zone, Italy where Alpine eclogite-facies metamorphism and fluid flow led to partial transformation of Variscan amphibolite-eclogite facies metapelites (garnet + biotite + sillimanite + K-feldspar + plagioclase + quartz) to zoisite ± jadeite + kyanite + phengite + quartz. This transformation took place under P-T conditions of 1.7 - 2.1 GPa at 600°C and low a(H2O) of 0.3-0.6. The replacement of plagioclase by jadeite + zoisite + kyanite + quartz takes place also along former fractures. Biotite is replaced by the assemblage phengite + omphacite ± kyanite adjacent to former plagioclase, otherwise by phengite + rutile/titanite. Garnet and clinopyroxene show variable compositions depending in which micro-domain (plagioclase or biotite) they grew. The extreme development of microdomains can best be studied by thermodynamic pseudosection modelling of individual microdomains using stoichiometric mixtures of protolith minerals from this domain and the program DOMINO (De Capitani & Petrakakis, 2010). The aim of these calculations was: 1.) to reproduce the observed mineral assemblage and 2.) to provide constraints on the amount of fluid present in the transformation. The results so far indicate that the amount of fluid was very low, otherwise paragonite would have formed instead of jadeite and reproduction of the observed mineral assemblage has only been partly successful so far since biotite is still stable in the calculations. In addition to understand the role of fluids in the mineralogical and textural transformation piston-cylinder experiments with a fresh, natural orthogneiss granulite from the Moldanubic Unit in upper Austria with the assemblage garnet + biotite + K
Relativistic cosmology; Cosmologia Relativista
Bastero-Gil, M.
2015-07-01
Relativistic cosmology is nothing but the study of the evolution of our universe expanding from the General Theory of Relativity, which describes the gravitational interaction at any scale and given its character far-reaching is the force that dominate the evolution of the universe. (Author)
Relativistic impulse dynamics.
Swanson, Stanley M
2011-08-01
Classical electrodynamics has some annoying rough edges. The self-energy of charges is infinite without a cutoff. The calculation of relativistic trajectories is difficult because of retardation and an average radiation reaction term. By reconceptuallizing electrodynamics in terms of exchanges of impulses rather than describing it by forces and potentials, we eliminate these problems. A fully relativistic theory using photonlike null impulses is developed. Numerical calculations for a two-body, one-impulse-in-transit model are discussed. A simple relationship between center-of-mass scattering angle and angular momentum was found. It reproduces the Rutherford cross section at low velocities and agrees with the leading term of relativistic distinguishable-particle quantum cross sections (Møller, Mott) when the distance of closest approach is larger than the Compton wavelength of the particle. Magnetism emerges as a consequence of viewing retarded and advanced interactions from the vantage point of an instantaneous radius vector. Radiation reaction becomes the local conservation of energy-momentum between the radiating particle and the emitted impulse. A net action is defined that could be used in developing quantum dynamics without potentials. A reinterpretation of Newton's laws extends them to relativistic motion.
Antippa, Adel F.
2009-01-01
We solve the problem of the relativistic rocket by making use of the relation between Lorentzian and Galilean velocities, as well as the laws of superposition of successive collinear Lorentz boosts in the limit of infinitesimal boosts. The solution is conceptually simple, and technically straightforward, and provides an example of a powerful…
Relativistic length agony continued
Redžić D.V.
2014-01-01
Full Text Available We made an attempt to remedy recent confusing treatments of some basic relativistic concepts and results. Following the argument presented in an earlier paper (Redžić 2008b, we discussed the misconceptions that are recurrent points in the literature devoted to teaching relativity such as: there is no change in the object in Special Relativity, illusory character of relativistic length contraction, stresses and strains induced by Lorentz contraction, and related issues. We gave several examples of the traps of everyday language that lurk in Special Relativity. To remove a possible conceptual and terminological muddle, we made a distinction between the relativistic length reduction and relativistic FitzGerald-Lorentz contraction, corresponding to a passive and an active aspect of length contraction, respectively; we pointed out that both aspects have fundamental dynamical contents. As an illustration of our considerations, we discussed briefly the Dewan-Beran-Bell spaceship paradox and the ‘pole in a barn’ paradox. [Projekat Ministarstva nauke Republike Srbije, br. 171028
Weak rigidity in almost-thermodynamic material schemes
del Olmo, V.; Olivert, J.
1985-06-01
To avoid the restrictions that the Born rigidity supposes for the motions in relativity, the definition of a weakly rigid almost-thermodynamic material scheme is proposed. From it the relativistic incompressibility condition given by Ferrando and Olivert is obtained. Moreover, it is proved that, for the weakly rigid irrotational and geodesic almost-thermodynamic material schemes, the scalar curvature of the Landau manifolds is constant along the streamlines.
Uniqueness of Landau-Lifshitz energy frame in relativistic dissipative hydrodynamics.
Tsumura, Kyosuke; Kunihiro, Teiji
2013-05-01
We show that the relativistic dissipative hydrodynamic equation derived from the relativistic Boltzmann equation by the renormalization-group method uniquely leads to the one in the energy frame proposed by Landau and Lifshitz, provided that the macroscopic-frame vector, which defines the local rest frame of the flow velocity, is independent of the momenta of constituent particles, as it should. We argue that the relativistic hydrodynamic equations for viscous fluids must be defined on the energy frame if consistent with the underlying relativistic kinetic equation.
Ion-Acoustic Envelope Modes in a Degenerate Relativistic Electron-Ion Plasma
McKerr, M; Kourakis, I
2016-01-01
A self-consistent relativistic two-fluid model is proposed for one-dimensional electron-ion plasma dynamics. A multiple scales perturbation technique is employed, leading to an evolution equation for the wave envelope, in the form of a nonlinear Schr\\"odinger type equation (NLSE). The inclusion of relativistic effects is shown to introduce density-dependent factors, not present in the non-relativistic case - in the conditions for modulational instability. The role of relativistic effects on the linear dispersion laws and on envelope soliton solutions of the NLSE is discussed.
Acoustic perturbations in special-relativistic parallel flows
Rogava, A D; Mahajan, S M
1996-01-01
Acoustic perturbations in a parallel relativistic flow of an inviscid fluid are considered. The general expression for the frequency of the sound waves in a uniformly (with zero shear) moving medium is derived. It is shown that relativity evokes a difference in the frequencies of the sound-type perturbations propagating along and against the current. Besides, it is shown that the perturbations are not purely irrotational as they are in nonrelativistic case. For a non-uniformly (with nonzero shear) moving fluid a general set of equations, describing the evolution of the acoustic perturbations in relativistic sheared flows, is obtained and analysed when the temperature is nonrelativistic. It is shown that, like the nonrelativistic case, in the new system: (a) the excitation of vortical, transiently growing perturbations, and (b) the excitation of sound-type perturbations, extracting the kinetic energy of the background flow, are possible. It is demonstrated that the relativistic character of the motion signific...
Electrovacuum Static Counterrotating Relativistic Dust Disks
García-Reyes, Gonzalo
2004-01-01
A detailed study is presented of the counterrotating model (CRM) for generic electrovacuum static axially symmetric relativistic thin disks without radial pressure. We find a general constraint over the counterrotating tangential velocities needed to cast the surface energy-momentum tensor of the disk as the superposition of two counterrotating charged dust fluids. We also find explicit expressions for the energy densities, charge densities and velocities of the counterrotating fluids. We then show that this constraint can be satisfied if we take the two counterrotating streams as circulating along electro-geodesics. However, we show that, in general, it is not possible to take the two counterrotating fluids as circulating along electro-geodesics nor take the two counterrotating tangential velocities as equal and opposite. Four simple families of models of counterrotating charged disks based on Chazy-Curzon-like, Zipoy-Voorhees-like, Bonnor-Sackfield-like and Kerr-like electrovacuum solutions are considered w...
Applied statistical thermodynamics
Lucas, Klaus
1991-01-01
The book guides the reader from the foundations of statisti- cal thermodynamics including the theory of intermolecular forces to modern computer-aided applications in chemical en- gineering and physical chemistry. The approach is new. The foundations of quantum and statistical mechanics are presen- ted in a simple way and their applications to the prediction of fluid phase behavior of real systems are demonstrated. A particular effort is made to introduce the reader to expli- cit formulations of intermolecular interaction models and to show how these models influence the properties of fluid sy- stems. The established methods of statistical mechanics - computer simulation, perturbation theory, and numerical in- tegration - are discussed in a style appropriate for newcom- ers and are extensively applied. Numerous worked examples illustrate how practical calculations should be carried out.
Shukla, Chandrasekhar; Patel, Kartik
2016-01-01
We carry out Particle-in-Cell (PIC) simulations to study the instabilities associated with a 2-D sheared electron flow configuration against a neutralizing background of ions. Both weak and strong relativistic flow velocities are considered. In the weakly relativistic case, we observe the development of electromagnetic Kelvin Helmholtz instability with similar characteristics as that predicted by the electron Magnetohydrodynamic (EMHD) model. On other hand, in strong relativistic case the compressibility effects of electron fluid dominate and introduce upper hybrid electrostatic oscillations transverse to the flow which are very distinct from EMHD fluid behaviour. In the nonlinear regime, both weak and strong relativistic cases lead to turbulence with broad power law spectrum.
Reiss, Howard; Manzanares, José A.
2016-09-01
Using several theoretical toolsldots (i) the nucleation theorem, (ii) an equivalent cavity, (iii) the reversible work of adding a cavity to an open hard sphere system, and (iv) the theory of "stability"... the authors estimated the density at which the hard sphere freezing transition occurs. No direct involvement of the equilibrium solid phase is involved. The reduced density \\uppi a^3ρ _f/6 (where a is the hard sphere diameter and ρ _f is the actual density at which freezing occurs) is found to be 0.4937 while the value obtained by computer simulation is 0.494. The agreement is good, but the new method still contains some approximation. However, the approximation is based on the idea that at a density just below ρ _f the fluid adopts a distorted structure resembling the solid, but different enough so that long-range order vanishes. Initial loss of stability may not be involved in every fluid-solid transition, but it may be an early step in the hard sphere and related systems.
Mesmer, R.E.
1990-09-12
The purpose of this travel was for the traveler to participate in the 11th IUPAC International Conference on Chemical Thermodynamics and to present a paper of which he is co-author entitled The Transition from Strong-to-Weak Electrolyte Behavior Near the Critical Point of Water'' in the session on Solutions. The conference brought together nearly 500 scientists from around the world to discuss broad aspects of experimental thermodynamics and theoretical modeling. The traveler also visited the University of Karlsruhe to discuss current research with E.U. Franck and his collaborators. This institution has been for many years one of the leading centers for experimental studies on phase equilibrium and physical chemical studies especially on pure substances under the direction of Franck.
Relativistic Processes and the Internal Structure of Neutron Stars
Alvarez-Castillo, D E
2011-01-01
Models for the internal composition of Dense Compact Stars are reviewed as well as macroscopic properties derived by observations of relativistic processes. Modeling of pure neutron matter Neutron Stars is presented and crust properties are studied by means of a two fluid model.
Ben-Naim, Arieh
1987-01-01
This book deals with a subject that has been studied since the beginning of physical chemistry. Despite the thousands of articles and scores of books devoted to solvation thermodynamics, I feel that some fundamen tal and well-established concepts underlying the traditional approach to this subject are not satisfactory and need revision. The main reason for this need is that solvation thermodynamics has traditionally been treated in the context of classical (macroscopic) ther modynamics alone. However, solvation is inherently a molecular pro cess, dependent upon local rather than macroscopic properties of the system. Therefore, the starting point should be based on statistical mechanical methods. For many years it has been believed that certain thermodynamic quantities, such as the standard free energy (or enthalpy or entropy) of solution, may be used as measures of the corresponding functions of solvation of a given solute in a given solvent. I first challenged this notion in a paper published in 1978 b...
Corcovilos, Theodore Allen
Although fluids are typically the first systems studied in undergraduate thermodynamics classes, we still have only a rudimentary phenomenological understanding of these systems outside of the classical and equilibrium regimes. Two experiments will be presented. First, we present progress on precise measurements of helium-4 gas at low temperatures (1 K-5 K). We study helium because at low densities it is an approximately ideal gas but at high densities the thermodynamic properties can be predicted by numerical solutions of Schroedinger's equation. By utilizing the high resolution and stability in frequency of a superconducting microwave cavity resonator we can measure the dielectric constant of helium-4 to parts in 109, corresponding to an equivalent resolution in density. These data will be used to calculate the virial coefficients of the helium gas so that we may compare with numerical predictions from the literature. Additionally, our data may allow us to measure Boltzmann's constant to parts in 108, a factor of 100 improvement over previous measurements. This work contains a description of the nearly-completed apparatus and the methods of operation and data analysis for this experiment. Data will be taken by future researchers.The second experiment discussed is a study of nucleate pool boiling. To date, no adequate quantitative model exists of this everyday phenomenon. In our experiment, we vary one parameter inaccessible to most researchers, gravity, by applying a magnetic force to our test fluid, oxygen. Using this technique, we may apply effective gravities of 0-80 times Earth's gravitational acceleration (g). In this work we present heat transfer data for the boiling of oxygen at one atmosphere ambient pressure for effective gravity values between 1g and 16g . Our data describe two relationships between applied heat flux and temperature differential: at low heat flux the system obeys a power law and at high heat flux the behavior is linear. We find that the
Bhuwakietkumjohn, N.; Parametthanuwat, T.
2015-09-01
This research focused on the thermal behaviour of oscillating heat pipe with a check valve (CLOHP/CV). The CLOHP/CV was made from a copper capillary tube with an internal diameter of 2.03 mm, 40 turns, and 2 check valves. The CLOHP/CV had three sections: the evaporator and adiabatic condenser of a length of 50, 100, and 150 mm. The angles of inclinations were 90°, 80°, 60°, 40°, 20° and 0° at normal operating conditions. The two working fluids were an ethanol and silver nanoparticles concentration of 0.5 wt% contained in the ethanol ( NE). The filling ratio was 50 % with respect to the total volume of the tube. The operating temperature ( T w ) was 45, 65, 85, 105, 125 and 150 °C. The results of the study showed that the heat flux increased significantly when the operating temperature increased, and the heat flux increased when the L e decreased from 150 to 50 mm. Furthermore, the thermal behaviour of CLOHP/CV showed the highest heat flux of 2,012.63 W/m2 at L e of 50, with an angle of inclination of 90° and operating temperature of 150 °C with NE. The behaviour of 0.5 wt% of silver nanoparticles contained in the ethanol produced a good contact angle. The 0.5 wt% of silver nanoparticles decreased the wet ability, thus increasing the thermal behaviour. The optimum concentration for the addition of silver nanoparticles in the working fluid was 0.5 wt%.
Relativistic Hydrodynamics with Wavelets
DeBuhr, Jackson; Anderson, Matthew; Neilsen, David; Hirschmann, Eric W
2015-01-01
Methods to solve the relativistic hydrodynamic equations are a key computational kernel in a large number of astrophysics simulations and are crucial to understanding the electromagnetic signals that originate from the merger of astrophysical compact objects. Because of the many physical length scales present when simulating such mergers, these methods must be highly adaptive and capable of automatically resolving numerous localized features and instabilities that emerge throughout the computational domain across many temporal scales. While this has been historically accomplished with adaptive mesh refinement (AMR) based methods, alternatives based on wavelet bases and the wavelet transformation have recently achieved significant success in adaptive representation for advanced engineering applications. This work presents a new method for the integration of the relativistic hydrodynamic equations using iterated interpolating wavelets and introduces a highly adaptive implementation for multidimensional simulati...
Virial theorem and Gibbs thermodynamic potential for Coulomb systems
Bobrov, V. B., E-mail: vic5907@mail.ru, E-mail: satron@mail.ru [Joint Institute for High Temperatures, Russian Academy of Sciences, Izhorskaya St. 13, Bd. 2, Moscow 125412 (Russian Federation); National Research University “MPEI,” Krasnokazarmennaya str. 14, Moscow 111250 (Russian Federation); Trigger, S. A., E-mail: vic5907@mail.ru, E-mail: satron@mail.ru [Joint Institute for High Temperatures, Russian Academy of Sciences, Izhorskaya St. 13, Bd. 2, Moscow 125412 (Russian Federation); Institut für Physik, Humboldt-Universität zu Berlin, Newtonstraße 15, Berlin D-12489 (Germany)
2014-10-15
Using the grand canonical ensemble and the virial theorem, we show that the Gibbs thermodynamic potential of the non-relativistic system of charged particles is uniquely defined by single-particle Green functions of electrons and nuclei. This result is valid beyond the perturbation theory with respect to the interparticle interaction.
Relativistic Solutions of Anisotropic Compact Objects
Paul, Bikash Chandra
2016-01-01
We present a class of new relativistic solutions with anisotropic fluid for compact stars in hydrostatic equilibrium. The interior space-time geometry considered here for compact objects are described by parameters namely, $\\lambda$, $k$, $A$, $R$ and $n$. The values of the geometrical parameters are determined here for obtaining a class of physically viable stellar models. The energy-density, radial pressure and tangential pressure are finite and positive inside the anisotropic stars. Considering some stars of known mass we present stellar models which describe compact astrophysical objects with nuclear density.
Relativistic heavy ion reactions
Brink, D.M.
1989-08-01
The theory of quantum chromodynamics predicts that if nuclear matter is heated to a sufficiently high temperature then quarks might become deconfined and a quark-gluon plasma could be produced. One of the aims of relativistic heavy ion experiments is to search for this new state of matter. These lectures survey some of the new experimental results and give an introduction to the theories used to interpret them. 48 refs., 4 tabs., 11 figs.
Relativistic spherical plasma waves
Bulanov, S S; Schroeder, C B; Zhidkov, A G; Esarey, E; Leemans, W P
2011-01-01
Tightly focused laser pulses as they diverge or converge in underdense plasma can generate wake waves, having local structures that are spherical waves. Here we report on theoretical study of relativistic spherical wake waves and their properties, including wave breaking. These waves may be suitable as particle injectors or as flying mirrors that both reflect and focus radiation, enabling unique X-ray sources and nonlinear QED phenomena.
Relativistic Quantum Noninvasive Measurements
Bednorz, Adam
2014-01-01
Quantum weak, noninvasive measurements are defined in the framework of relativity. Invariance with respect to reference frame transformations of the results in different models is discussed. Surprisingly, the bare results of noninvasive measurements are invariant for certain class of models, but not the detection error. Consequently, any stationary quantum realism based on noninvasive measurements will break, at least spontaneously, relativistic invariance and correspondence principle at zero temperature.
Relativistic cosmological hydrodynamics
Hwang, J
1997-01-01
We investigate the relativistic cosmological hydrodynamic perturbations. We present the general large scale solutions of the perturbation variables valid for the general sign of three space curvature, the cosmological constant, and generally evolving background equation of state. The large scale evolution is characterized by a conserved gauge invariant quantity which is the same as a perturbed potential (or three-space curvature) in the comoving gauge.
Exploring the thermodynamics of non-commutative scalar fields
Brito, Francisco A
2015-01-01
We study the thermodynamic properties of the Bose-Einstein condensate (BEC) in the context of the quantum field theory with non-commutative target space. Our main goal is to investigate in which temperature and/or energy regimes the non-commutativity can characterize some influence in the BEC properties described by a relativistic massive non-commutative boson gas. The non-commutative parameters play a key role in the modified dispersion relations of the non-commutative fields, leading to a new phenomenology. We have obtained the condensate fraction, internal energy, pressure and specific heat of the system and taken ultra-relativistic (UR) and non-relativistic limits (NR). The non-commutative effects in the thermodynamic properties of the system are discussed. We found that there appear interesting signatures around the critical temperature.
Relativistic gravity gradiometry
Bini, Donato; Mashhoon, Bahram
2016-12-01
In general relativity, relativistic gravity gradiometry involves the measurement of the relativistic tidal matrix, which is theoretically obtained from the projection of the Riemann curvature tensor onto the orthonormal tetrad frame of an observer. The observer's 4-velocity vector defines its local temporal axis and its local spatial frame is defined by a set of three orthonormal nonrotating gyro directions. The general tidal matrix for the timelike geodesics of Kerr spacetime has been calculated by Marck [Proc. R. Soc. A 385, 431 (1983)]. We are interested in the measured components of the curvature tensor along the inclined "circular" geodesic orbit of a test mass about a slowly rotating astronomical object of mass M and angular momentum J . Therefore, we specialize Marck's results to such a "circular" orbit that is tilted with respect to the equatorial plane of the Kerr source. To linear order in J , we recover the gravitomagnetic beating phenomenon [B. Mashhoon and D. S. Theiss, Phys. Rev. Lett. 49, 1542 (1982)], where the beat frequency is the frequency of geodetic precession. The beat effect shows up as a special long-period gravitomagnetic part of the relativistic tidal matrix; moreover, the effect's short-term manifestations are contained in certain post-Newtonian secular terms. The physical interpretation of this effect is briefly discussed.
Gravitationally confined relativistic neutrinos
Vayenas, C. G.; Fokas, A. S.; Grigoriou, D.
2017-09-01
Combining special relativity, the equivalence principle, and Newton’s universal gravitational law with gravitational rather than rest masses, one finds that gravitational interactions between relativistic neutrinos with kinetic energies above 50 MeV are very strong and can lead to the formation of gravitationally confined composite structures with the mass and other properties of hadrons. One may model such structures by considering three neutrinos moving symmetrically on a circular orbit under the influence of their gravitational attraction, and by assuming quantization of their angular momentum, as in the Bohr model of the H atom. The model contains no adjustable parameters and its solution, using a neutrino rest mass of 0.05 eV/c2, leads to composite state radii close to 1 fm and composite state masses close to 1 GeV/c2. Similar models of relativistic rotating electron - neutrino pairs give a mass of 81 GeV/c2, close to that of W bosons. This novel mechanism of generating mass suggests that the Higgs mass generation mechanism can be modeled as a latent gravitational field which gets activated by relativistic neutrinos.
Parker, Edward
2017-08-01
A nonrelativistic particle released from rest at the edge of a ball of uniform charge density or mass density oscillates with simple harmonic motion. We consider the relativistic generalizations of these situations where the particle can attain speeds arbitrarily close to the speed of light; generalizing the electrostatic and gravitational cases requires special and general relativity, respectively. We find exact closed-form relations between the position, proper time, and coordinate time in both cases, and find that they are no longer harmonic, with oscillation periods that depend on the amplitude. In the highly relativistic limit of both cases, the particle spends almost all of its proper time near the turning points, but almost all of the coordinate time moving through the bulk of the ball. Buchdahl's theorem imposes nontrivial constraints on the general-relativistic case, as a ball of given density can only attain a finite maximum radius before collapsing into a black hole. This article is intended to be pedagogical, and should be accessible to those who have taken an undergraduate course in general relativity.
Point form relativistic quantum mechanics and relativistic SU(6)
Klink, W. H.
1993-01-01
The point form is used as a framework for formulating a relativistic quantum mechanics, with the mass operator carrying the interactions of underlying constituents. A symplectic Lie algebra of mass operators is introduced from which a relativistic harmonic oscillator mass operator is formed. Mass splittings within the degenerate harmonic oscillator levels arise from relativistically invariant spin-spin, spin-orbit, and tensor mass operators. Internal flavor (and color) symmetries are introduced which make it possible to formulate a relativistic SU(6) model of baryons (and mesons). Careful attention is paid to the permutation symmetry properties of the hadronic wave functions, which are written as polynomials in Bargmann spaces.
General relativistic neutrino transport using spectral methods
Peres, Bruno; Penner, Andrew Jason; Novak, Jérôme; Bonazzola, Silvano
2014-02-01
We present a new code, Lorene's Ghost (for Lorene's gravitational handling of spectral transport) developed to treat the problem of neutrino transport in supernovae with the use of spectral methods. First, we derive the expression for the nonrelativistic Liouville operator in doubly spherical coordinates (r, θ, ϕ, ɛ, Θ, Φ), and further its general relativistic counterpart. We use the 3 + 1 formalism with the conformally flat approximation for the spatial metric, to express the Liouville operator in the Eulerian frame. Our formulation does not use any approximations when dealing with the angular arguments (θ, ϕ, Θ, Φ), and is fully energy-dependent. This approach is implemented in a spherical shell, using either Chebyshev polynomials or Fourier series as decomposition bases. It is here restricted to simplified collision terms (isoenergetic scattering) and to the case of a static fluid. We finish this paper by presenting test results using basic configurations, including general relativistic ones in the Schwarzschild metric, in order to demonstrate the convergence properties, the conservation of particle number and correct treatment of some general relativistic effects of our code. The use of spectral methods enables to run our test cases in a six-dimensional setting on a single processor.
Weakly nonlocal non-equilibrium thermodynamics - variational principles and Second Law
Ván, P.
2009-01-01
A general, uniform, rigorous and constructive thermodynamic approach to weakly nonlocal non-equilibrium thermodynamics is reviewed. A method is given to construct and restrict the evolution equations of physical theories according to the Second Law of thermodynamics and considering weakly nonlocal constitutive state spaces. The evolution equations of internal variables, the classical irreversible thermodynamics and Korteweg fluids are treated.
Qi, Weihong
2016-09-20
Conventional thermodynamics for bulk substances encounters challenges when one considers materials on the nanometer scale. Quantities such as entropy, enthalpy, free energy, melting temperature, ordering temperature, Debye temperature, and specific heat no longer remain constant but change with the crystal dimension, size, and morphology. Often, one phenomenon is associated with a variety of theories from different perspectives. Still, a model that can reconcile the size and shape dependence of the thermal properties of the nanoscaled substances remains one of the goals of nanoscience and nanotechnology. This Account highlights the nanoscopic thermodynamics for nanoparticles, nanowires, and nanofilms, with particular emphasis on the bond energy model. The central idea is that the atomic cohesive energy determines the thermodynamic performance of a substance and the cohesive energy varies with the atomic coordination environment. It is the cohesive energy difference between the core and the shell that dictates the nanoscopic thermodynamics. This bond energy model rationalizes the following: (i) how the surface dangling bonds depress the melting temperature, entropy, and enthalpy; (ii) how the order-disorder transition of the nanoparticles depends on particle size and how their stability may vary when they are embedded in an appropriate matrix; (iii) predictions of the existence of face-centered cubic structures of Ti, Zr, and Hf at small size; (iv) how two elements that are immiscible in the bulk can form an alloy on the nanoscale, where the critical size can be predicted. The model has enabled us to reproduce the size and shape dependence of a number of physical properties, such as melting temperature, melting entropy, melting enthalpy, ordering temperature, Gibbs free energy, and formation heat, among others, for materials such as Pd, Au, Ag, Cu, Ni, Sn, Pb, In, Bi, Al, Ti, Zr, Hf, In-Al, Ag-Ni, Co-Pt, Cu-Ag, Cu-Ni, Au-Ni, Ag-Pt, and Au-Pt on the nanometer scale
Sainz, M A; Pena, P; Serena, S; Caballero, A
2010-07-01
A new type of bioactive ceramic has been designed and obtained from high-temperature phase information from the wollastonite (CaSiO(3))-diopside (CaMg(SiO(3))(2)) phase equilibrium diagram. The selected composition was that corresponding to the eutectic point of the pseudobinary CaSiO(3)-CaMg(SiO(3))(2) system. The sintering behaviour, phase evolution, microstructural changes and in vitro bioactivity of CaSiO(3)-CaMg(SiO(3))(2) eutectic bioceramics were analysed by differential thermal analysis, X-ray diffraction, field emission scanning electron microscopy (FE-SEM) and image analysis. A simulation of the dissolution properties of the different materials studied, in water as well as in simulated body fluid (SBF), was also carried out by thermodynamic calculations, with the purpose of understanding the in vitro results obtained. The results demonstrate that the CaMg(SiO(3))(2) is significantly less soluble than CaSiO(3), developing an in situ porous structure (biomimetic porous bone material) with adequate biodegradation rate and stability strength when immersed in SBF. The influence of the microstructure (porosity, grain size and phase composition) on the in vitro bioactivity of the obtained bioceramics was also examined.
Hendricks, R. C.; Baron, A. K.; Peller, I. C.
1975-01-01
A FORTRAN IV subprogram called GASP is discussed which calculates the thermodynamic and transport properties for 10 pure fluids: parahydrogen, helium, neon, methane, nitrogen, carbon monoxide, oxygen, fluorine, argon, and carbon dioxide. The pressure range is generally from 0.1 to 400 atmospheres (to 100 atm for helium and to 1000 atm for hydrogen). The temperature ranges are from the triple point to 300 K for neon; to 500 K for carbon monoxide, oxygen, and fluorine; to 600 K for methane and nitrogen; to 1000 K for argon and carbon dioxide; to 2000 K for hydrogen; and from 6 to 500 K for helium. GASP accepts any two of pressure, temperature and density as input conditions along with pressure, and either entropy or enthalpy. The properties available in any combination as output include temperature, density, pressure, entropy, enthalpy, specific heats, sonic velocity, viscosity, thermal conductivity, and surface tension. The subprogram design is modular so that the user can choose only those subroutines necessary to the calculations.
杨亦文; 严全鸿; 任其龙
2005-01-01
The resolution of ibuprofen enantiomers was conducted on a chiral stationary phase of Kromasil CHI-TBB column (250 mm×4.6 mm I.D., 5μm, Eka Chemicals AB, Bohus, Sweden). The thermodynamic properties of the enantiomers in supercritical/subcritical fluid chromatography were investigated in the ranges of 293-323 K and 12.0-21.0 MPa, and compared with those in high performance liquid chromatography in the range of 288-328 K. The mobile phases were isopropanol/carbon dioxide (2 : 98, by mass), 690.0 ml·min-1 (at ambient temperature and pressure), and isopropanol/hexane (3 : 97, by volume), 2.0 ml·min-1, respectively. The plots of lnk′ and lnα versus 1/T were straight lines in HPLC. The plots of lnα versus 1/T were still straight lines but the linear relationship of lnk′ versus 1/T could not be observed in SFC. The differences of enthalpy changes and entropy changes for the transfer of enantiomers from the mobile phase to the stationary phase were calculated. In both cases, |ΔR.SΔH0|>|TΔR.SΔS0|, therefore, the enthalpie contribution to the overall enantiomer transfer energy is more important than the entropic contribution in the temperature range examined, and furthermore, lower temperature is better for chiral resolution of ibuprofen.
Relativistic magnetohydrodynamics in one dimension.
Lyutikov, Maxim; Hadden, Samuel
2012-02-01
We derive a number of solutions for one-dimensional dynamics of relativistic magnetized plasma that can be used as benchmark estimates in relativistic hydrodynamic and magnetohydrodynamic numerical codes. First, we analyze the properties of simple waves of fast modes propagating orthogonally to the magnetic field in relativistically hot plasma. The magnetic and kinetic pressures obey different equations of state, so that the system behaves as a mixture of gases with different polytropic indices. We find the self-similar solutions for the expansion of hot strongly magnetized plasma into vacuum. Second, we derive linear hodograph and Darboux equations for the relativistic Khalatnikov potential, which describe arbitrary one-dimensional isentropic relativistic motion of cold magnetized plasma and find their general and particular solutions. The obtained hodograph and Darboux equations are very powerful: A system of highly nonlinear, relativistic, time-dependent equations describing arbitrary (not necessarily self-similar) dynamics of highly magnetized plasma reduces to a single linear differential equation.
Schreckenberg, Jens M. A.; Dufal, Simon; Haslam, Andrew J.; Adjiman, Claire S.; Jackson, George; Galindo, Amparo
2014-09-01
An improved formulation of the extension of the statistical associating fluid theory for potentials of variable range to electrolytes (SAFT-VRE) is presented, incorporating a representation for the dielectric constant of the solution that takes into account the temperature, density and composition of the solvent. The proposed approach provides an excellent correlation of the dielectric-constant data available for a number of solvents including water, representative alcohols and carbon dioxide, and it is shown that the methodology can be used to treat mixed-solvent electrolyte solutions. Models for strong electrolytes of the metal-halide family are considered here. The salts are treated as fully dissociated and ion-specific interaction parameters are presented. Vapour pressure, density, and mean ionic activity coefficient data are used to determine the ion-ion and solvent-ion parameters, and mixed-salt electrolyte solutions (brines) are then treated predictively. We find that the resulting intermolecular potential models follow physical trends in terms of energies and ion sizes with a close relationship observed with well-established ionic diameters. A good description is obtained for the densities, mean ionic activity coefficients, and vapour pressures of the electrolyte solutions studied. The theory is also seen to provide excellent predictions of the osmotic coefficient and of the depression of the freezing temperature, and provides a qualitative estimate of the solvation free energy. The vapour pressure of aqueous brines is predicted accurately, as is the density of these solutions, although not at the highest pressures considered. Calculations for the vapour-liquid and liquid-liquid equilibria of salts in water+methanol and water+n-butan-1-ol are presented. In addition, it is shown that the salting-out of carbon dioxide in sodium chloride solutions is captured well using a predictive model.
Thermodynamics a complete undergraduate course
Steane, Andrew M
2016-01-01
This is an undergraduate textbook in thermodynamics—the science of heat, work, temperature, and entropy. The text presents thermodynamics in and of itself, as an elegant and powerful set of ideas and methods. These methods open the way to understanding a very wide range of phenomena in physics, chemistry, engineering, and biology. Starting out from an introduction of concepts at first year undergraduate level, the roles of temperature, internal energy, and entropy are explained via the laws of thermodynamics. The text employs a combination of examples, exercises, and careful discussion, with a view to conveying the feel of the subject as well as avoiding common misunderstandings. The Feynman–Smuluchowski ratchet, Szilard’s engine, and Maxwell’s daemon are used to elucidate entropy and the second law. Free energy and thermodynamic potentials are discussed at length, with applications to solids as well as fluids and flow processes. Thermal radiation is discussed, and the main ideas significant to global...
Nanofluidics thermodynamic and transport properties
Michaelides, Efstathios E (Stathis)
2014-01-01
This volume offers a comprehensive examination of the subject of heat and mass transfer with nanofluids as well as a critical review of the past and recent research projects in this area. Emphasis is placed on the fundamentals of the transport processes using particle-fluid suspensions, such as nanofluids. The nanofluid research is examined and presented in a holistic way using a great deal of our experience with the subjects of continuum mechanics, statistical thermodynamics, and non-equilibrium thermodynamics of transport processes. Using a thorough database, the experimental, analytical, and numerical advances of recent research in nanofluids are critically examined and connected to past research with medium and fine particles as well as to functional engineering systems. Promising applications and technological issues of heat/mass transfer system design with nanofluids are also discussed. This book also: Provides a deep scientific analysis of nanofluids using classical thermodynamics and statistical therm...
Post-Newtonian reference-ellipsoid for relativistic geodesy
Kopeikin, Sergei; Mazurova, Elena
2015-01-01
We apply general relativity to construct the post-Newtonian background manifold that serves as a reference level surface in relativistic geodesy for conducting calculation of geoid's undulation. We chose the perfect homogeneous fluid uniformly rotating around a fixed axis as a source of the background manifold. We, then, reformulate and extend rotating-fluid calculations done by a number of previous researchers for astrophysical applications to the realm of relativistic geodesy to find out the algebraic equation of the post-Newtonian reference-ellipsoid. We explicitly perform all integrals characterizing gravitational potentials inside the fluid body and represent them in terms of elementary functions depending on the body's eccentricity. We fully explore the coordinate freedom of the equations describing the post-Newtonian ellipsoid and demonstrate that the fractional deviation of the post-Newtonian level surface from the Maclaurin ellipsoid can be made much smaller than the previously anticipated estimate a...
Recurrence relation for relativistic atomic matrix elements
Martínez y Romero, R P; Salas-Brito, A L
2000-01-01
Recurrence formulae for arbitrary hydrogenic radial matrix elements are obtained in the Dirac form of relativistic quantum mechanics. Our approach is inspired on the relativistic extension of the second hypervirial method that has been succesfully employed to deduce an analogous relationship in non relativistic quantum mechanics. We obtain first the relativistic extension of the second hypervirial and then the relativistic recurrence relation. Furthermore, we use such relation to deduce relativistic versions of the Pasternack-Sternheimer rule and of the virial theorem.
Slowly Rotating General Relativistic Superfluid Neutron Stars
Andersson, N
2001-01-01
We present a general formalism to treat slowly rotating general relativistic superfluid neutron stars. As a first approximation, their matter content can be described in terms of a two-fluid model, where one fluid is the neutron superfluid, which is believed to exist in the core and inner crust of mature neutron stars, and the other fluid represents a conglomerate of all other constituents (crust nuclei, protons, electrons, etc.). We obtain a system of equations, good to second-order in the rotational velocities, that determines the metric and the matter variables, irrespective of the equation of state for the two fluids. In particular, allowance is made for the so-called entrainment effect, whereby the momentum of one constituent (e.g. the neutrons) carries along part of the mass of the other constituent. As an illustration of the developed framework, we consider a simplified equation of state for which the two fluids are described by different polytropes. We determine numerically the effects of the two flui...
Relativistic twins or sextuplets?
Sheldon, E S
2003-01-01
A recent study of the relativistic twin 'paradox' by Soni in this journal affirmed that 'A simple solution of the twin paradox also shows anomalous behaviour of rigidly connected distant clocks' but entailed a pedagogic hurdle which the present treatment aims to surmount. Two scenarios are presented: the first 'flight-plan' is akin to that depicted by Soni, with constant-velocity segments, while the second portrays an alternative mission undertaken with sustained acceleration and deceleration, illustrated quantitatively for a two-way spacecraft flight from Earth to Polaris (465.9 light years distant) and back.
Numerical Relativistic Quantum Optics
2013-11-08
µm and a = 1. The condition for an atomic spectrum to be non-relativistic is Z α−1 ≈ 137, as follows from elementary Dirac theory. One concludes that...peculiar result that B0 = 1 TG is a weak field. At present, such fields are observed only in connection with astrophysical phenomena [14]. The highest...pulsars. The Astrophysical Journal, 541:367–373, Sep 2000. [15] M. Tatarakis, I. Watts, F.N. Beg, E.L. Clark, A.E. Dangor, A. Gopal, M.G. Haines, P.A
Relativistic quantum information
Mann, R. B.; Ralph, T. C.
2012-11-01
Over the past few years, a new field of high research intensity has emerged that blends together concepts from gravitational physics and quantum computing. Known as relativistic quantum information, or RQI, the field aims to understand the relationship between special and general relativity and quantum information. Since the original discoveries of Hawking radiation and the Unruh effect, it has been known that incorporating the concepts of quantum theory into relativistic settings can produce new and surprising effects. However it is only in recent years that it has become appreciated that the basic concepts involved in quantum information science undergo significant revision in relativistic settings, and that new phenomena arise when quantum entanglement is combined with relativity. A number of examples illustrate that point. Quantum teleportation fidelity is affected between observers in uniform relative acceleration. Entanglement is an observer-dependent property that is degraded from the perspective of accelerated observers moving in flat spacetime. Entanglement can also be extracted from the vacuum of relativistic quantum field theories, and used to distinguish peculiar motion from cosmological expansion. The new quantum information-theoretic framework of quantum channels in terms of completely positive maps and operator algebras now provides powerful tools for studying matters of causality and information flow in quantum field theory in curved spacetimes. This focus issue provides a sample of the state of the art in research in RQI. Some of the articles in this issue review the subject while others provide interesting new results that will stimulate further research. What makes the subject all the more exciting is that it is beginning to enter the stage at which actual experiments can be contemplated, and some of the articles appearing in this issue discuss some of these exciting new developments. The subject of RQI pulls together concepts and ideas from
Corinaldesi, Ernesto
1963-01-01
Geared toward advanced undergraduate and graduate students of physics, this text provides readers with a background in relativistic wave mechanics and prepares them for the study of field theory. The treatment originated as a series of lectures from a course on advanced quantum mechanics that has been further amplified by student contributions.An introductory section related to particles and wave functions precedes the three-part treatment. An examination of particles of spin zero follows, addressing wave equation, Lagrangian formalism, physical quantities as mean values, translation and rotat
Rössler, O E; Matsuno, K
1998-04-01
The two mindsets of absolutism and relativism are juxtaposed, and the relational or relativist stance is vindicated. The only 'absolute' entity which undeniably exists, consciousness has the reality of a dream. The escape hatch from this prison is relational, as Descartes and Levinas found out: Unfalsified relational consistency implies exteriority. Exteriority implies infinite power which in turn makes compassion inevitable. Aside from ethics as a royal way to enlightenment, a new technology called 'deep technology' may be accessible. It changes the whole world in a demonstrable fashion by manipulation of the micro frame--that is, the observer-world interface.
de Oliveira, Mário J
2017-01-01
This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Néel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This new edit...
Oliveira, Mário J
2013-01-01
This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Néel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This textbo...
Dynamics of Complex Fluid-Fluid Interfaces
Sagis, L.M.C.
2016-01-01
This chapter presents an overview of recent progress in modelling the behaviour of complex fluid–fluid interfaces with non-equilibrium thermodynamics. We will limit ourselves to frameworks employing the Gibbs dividing surface model, and start with a general discussion of the surface excess variables
The exact solution of the Riemann problem in relativistic MHD with tangential magnetic fields
Romero, R; Pons, J A; Ibáñez, J M; Miralles, J A; Romero, Roberto; Marti, Jose M.; Pons, Jose A.; Ibanez, Jose M.; Miralles, Juan A.
2005-01-01
We have extended the procedure to find the exact solution of the Riemann problem in relativistic hydrodynamics to a particular case of relativistic magnetohydrodynamics in which the magnetic field of the initial states is tangential to the discontinuity and orthogonal to the flow velocity. The wave pattern produced after the break up of the initial discontinuity is analogous to the non--magnetic case and we show that the problem can be understood as a purely relativistic hydrodynamical problem with a modified equation of state. The new degree of freedom introduced by the non-zero component of the magnetic field results in interesting effects consisting in the change of the wave patterns for given initial thermodynamical states, in a similar way to the effects arising from the introduction of tangential velocities. Secondly, when the magnetic field dominates the thermodynamical pressure and energy, the wave speeds approach the speed of light leading to fast shocks and fast and arbitrarily thin rarefaction wave...
AN INTERIM THERMODYNAMIC PROPERTY FORMULATION FOR SUPERCRITICAL n-HEXANE
Azzedine Abbaci
2010-07-01
Full Text Available Accurate information on the thermodynamic properties of supercritical fluids is highly sought for the chemical technology, especially, supercritical extraction technology. The thermodynamic properties of fluids near the critical region are strongly affected by the presence of fluctuations and therefore, can not be described by conventional equation. We have investigated an interim formulation for the behavior of the thermodynamic properties of n-hexane in the vicinity of the critical region. For this reason we have used the so-called “crossover model” to describe the thermodynamic properties of n-hexane in a wide range of temperatures and densities around the critical point.
Exotic Non-relativistic String
Casalbuoni, Roberto; Longhi, Giorgio
2007-01-01
We construct a classical non-relativistic string model in 3+1 dimensions. The model contains a spurion tensor field that is responsible for the non-commutative structure of the model. Under double dimensional reduction the model reduces to the exotic non-relativistic particle in 2+1 dimensions.
'Antigravity' Propulsion and Relativistic Hyperdrive
Felber, F S
2006-01-01
Exact payload trajectories in the strong gravitational fields of compact masses moving with constant relativistic velocities are calculated. The strong field of a suitable driver mass at relativistic speeds can quickly propel a heavy payload from rest to a speed significantly faster than the driver, a condition called hyperdrive. Hyperdrive thresholds and maxima are calculated as functions of driver mass and velocity.
A Simple Relativistic Bohr Atom
Terzis, Andreas F.
2008-01-01
A simple concise relativistic modification of the standard Bohr model for hydrogen-like atoms with circular orbits is presented. As the derivation requires basic knowledge of classical and relativistic mechanics, it can be taught in standard courses in modern physics and introductory quantum mechanics. In addition, it can be shown in a class that…
A Simple Relativistic Bohr Atom
Terzis, Andreas F.
2008-01-01
A simple concise relativistic modification of the standard Bohr model for hydrogen-like atoms with circular orbits is presented. As the derivation requires basic knowledge of classical and relativistic mechanics, it can be taught in standard courses in modern physics and introductory quantum mechanics. In addition, it can be shown in a class that…
Komissarov, S S; Lyutikov, M
2015-01-01
In this paper we describe a simple numerical approach which allows to study the structure of steady-state axisymmetric relativistic jets using one-dimensional time-dependent simulations. It is based on the fact that for narrow jets with v~c the steady-state equations of relativistic magnetohydrodynamics can be accurately approximated by the one-dimensional time-dependent equations after the substitution z=ct. Since only the time-dependent codes are now publicly available this is a valuable and efficient alternative to the development of a high-specialized code for the time-independent equations. The approach is also much cheaper and more robust compared to the relaxation method. We tested this technique against numerical and analytical solutions found in literature as well as solutions we obtained using the relaxation method and found it sufficiently accurate. In the process, we discovered the reason for the failure of the self-similar analytical model of the jet reconfinement in relatively flat atmospheres a...
Robust relativistic bit commitment
Chakraborty, Kaushik; Chailloux, André; Leverrier, Anthony
2016-12-01
Relativistic cryptography exploits the fact that no information can travel faster than the speed of light in order to obtain security guarantees that cannot be achieved from the laws of quantum mechanics alone. Recently, Lunghi et al. [Phys. Rev. Lett. 115, 030502 (2015), 10.1103/PhysRevLett.115.030502] presented a bit-commitment scheme where each party uses two agents that exchange classical information in a synchronized fashion, and that is both hiding and binding. A caveat is that the commitment time is intrinsically limited by the spatial configuration of the players, and increasing this time requires the agents to exchange messages during the whole duration of the protocol. While such a solution remains computationally attractive, its practicality is severely limited in realistic settings since all communication must remain perfectly synchronized at all times. In this work, we introduce a robust protocol for relativistic bit commitment that tolerates failures of the classical communication network. This is done by adding a third agent to both parties. Our scheme provides a quadratic improvement in terms of expected sustain time compared with the original protocol, while retaining the same level of security.
A relativistic trolley paradox
Matvejev, Vadim N.; Matvejev, Oleg V.; Grøn, Ø.
2016-06-01
We present an apparent paradox within the special theory of relativity, involving a trolley with relativistic velocity and its rolling wheels. Two solutions are given, both making clear the physical reality of the Lorentz contraction, and that the distance on the rails between each time a specific point on the rim touches the rail is not equal to 2 π R , where R is the radius of the wheel, but 2 π R / √{ 1 - R 2 Ω 2 / c 2 } , where Ω is the angular velocity of the wheels. In one solution, the wheel radius is constant as the velocity of the trolley increases, and in the other the wheels contract in the radial direction. We also explain two surprising facts. First that the shape of a rolling wheel is elliptical in spite of the fact that the upper part of the wheel moves faster than the lower part, and thus is more Lorentz contracted, and second that a Lorentz contracted wheel with relativistic velocity rolls out a larger distance between two successive touches of a point of the wheel on the rails than the length of a circle with the same radius as the wheels.
Fractional Dynamics of Relativistic Particle
Tarasov, Vasily E
2011-01-01
Fractional dynamics of relativistic particle is discussed. Derivatives of fractional orders with respect to proper time describe long-term memory effects that correspond to intrinsic dissipative processes. Relativistic particle subjected to a non-potential four-force is considered as a nonholonomic system. The nonholonomic constraint in four-dimensional space-time represents the relativistic invariance by the equation for four-velocity u_{\\mu} u^{\\mu}+c^2=0, where c is a speed of light in vacuum. In the general case, the fractional dynamics of relativistic particle is described as non-Hamiltonian and dissipative. Conditions for fractional relativistic particle to be a Hamiltonian system are considered.
Martínez Reyes, José; Gonzalez Partida, Eduardo; Perez, Renee J.; Tinoco, Michel; Jorge, A.
2008-10-01
Based on information of enthalpies of the fluids of wells from the geothermal reservoir of Los Humeros, Puebla, Mexico, we determined the thermodynamic conditions of the reservoir comparing the values of enthalpies of the fluids of discharge of the wells with the values published in the literature for different thermodynamic state of fluids.
Arellano Gomez, Victor Manuel; Aragon Aguilar, Alfonso; Barragan Reyes, Rosa Maria [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Cuernavaca, Morelos (Mexico); Flores Armenta, Magaly; Ramirez Montes, Miguel [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico); Tovar Aguado, Rigoberto [Comision Federal de Electricidad (Mexico)]. E-mail: vag@iie.org.mx
2008-07-15
Production data from 22 wells of the Los Humeros geothermal field in Puebla, Mexico, were analyzed to estimate the thermodynamic conditions (pressure and enthalpy) of the bottom-hole fluids entering the wells and the changes to the fluids after exploitation. The bottom-well conditions were obtained by simulating the production histories of the wells, using the WELLSIM numerical simulator. The reservoir temperature was estimated by the FT-HSH2 gas-equilibrium method, which provided values matching very well the measured-well temperatures under static conditions. To estimate the rates of change of the well-bottom thermodynamic variables-pressure and enthalpy-the linear and the harmonic methods were used. According to these models, overall results indicated pressure-decline rates of between 0.92 (linear method) and 1.03 bar/year (harmonic method), average enthalpy increases of between 9.4 (linear) and 10.3 (harmonic) kJ/kg/year, and a temperature increase of about 1.2 degrees Celsius/year (linear method). These rates of parameter change were considered moderate, likely due to recharge from the deeper reservoir. The wells showing higher-pressure declines were H-35, H-1, and H-1D; and the wells showing higher-enthalpy increases were H-1D, H-3D, and H-19D. Most wells showed temperature increases, although a temperature decrease was noticed in wells H-16R and H-36, probably due to mechanical damage in the wells or weak communication with the deeper reservoir. [Spanish] Se realizo un analisis de los datos de produccion de 22 pozos del campo geotermico de Los Humeros, Pue., Mexico, con objeto de estimar las condiciones termodinamicas (presion y entalpia) de sus fluidos de alimentacion y su evolucion en el tiempo como respuesta a la explotacion. Las condiciones a fondo de pozo se obtuvieron al simular las historias de produccion de los pozos mediante el simulador numerico WELLSIM. La temperatura de fondo se estimo mediante el metodo de equilibrio gaseoso FT-HSH2 ya que fue
Hidden Symmetry of a Fluid Dynamical Model
Neves, C
2001-01-01
A connection between solutions of the relativistic d-brane system in (d+1) dimensions with the solutions of a Galileo invariant fluid in d-dimensions is by now well established. However, the physical nature of the light-cone gauge description of a relativistic membrane changes after the reduction to the fluid dynamical model since the gauge symmetry is lost. In this work we argue that the original gauge symmetry present in a relativistic d-brane system can be recovered after the reduction process to a d-dimensional fluid model. To this end we propose, without introducing Wess-Zumino fields, a gauge invariant theory of isentropic fluid dynamics and show that this symmetry corresponds to the invariance under local translation of the velocity potential in the fluid dynamics picture. We show that different but equivalent choices of the sympletic sector lead to distinct representations of the embedded gauge algebra.
AdS and dS black hole solutions in analogue gravity: The relativistic and non-relativistic cases
Dey, Ramit; Turcati, Rodrigo
2016-01-01
We show that Schwarzschild black hole solutions in asymptotically Anti-de Sitter (AdS) and de Sitter (dS) spaces may, up to a conformal factor, be reproduced in the framework of analogue gravity. The aforementioned derivation is performed using relativistic and non-relativistic Bose-Einstein condensates. In addition, we demonstrate that the (2+1) planar AdS black hole can be mapped into the non-relativistic acoustic metric. Given that AdS black holes are extensively employed in the gauge/gravity duality, we then comment on the possibility to study the AdS/CFT correspondence and gravity/fluid duality from an analogue gravity perspective.
Introduction to physics mechanics, hydrodynamics thermodynamics
Frauenfelder, P
2013-01-01
Introduction of Physics: Mechanics , Hydrodynamics, Thermodynamics covers the principles of matter and its motion through space and time, as well as the related concepts of energy and force. This book is composed of eleven chapters, and begins with an introduction to the basic principles of mechanics, hydrodynamics, and thermodynamics. The subsequent chapters deal with the statics of rigid bodies and the dynamics of particles and rigid bodies. These topics are followed by discussions on elasticity, mechanics of fluids, the basic concept of thermodynamic, kinetic theory, and crystal structure o
Necessity of Dark Energy from Thermodynamic Arguments
H. Moradpour
2014-01-01
Full Text Available Considering the cosmic fluid as a quasi-static thermodynamic system, the status of the generalized second law of thermodynamics is investigated and the valid range of the equation of state parameter is derived for a few important cosmological models. Our study shows that the satisfaction of the laws of thermodynamics in these cosmological models requires the existence of some kind of energy in our universe with ω<−1/3. In other words, the existence of a dark energy component, or equivalently modified gravity theory, is unavoidable if the cosmological model is to approach thermal equilibrium in late times.
Duan, Zhenhao; Mao, Shide
2006-07-01
A thermodynamic model is presented to calculate methane solubility, liquid phase density and gas phase composition of the H 2O-CH 4 and H 2O-CH 4-NaCl systems from 273 to 523 K (possibly up to 573 K), from 1 to 2000 bar and from 0 to 6 mol kg -1 of NaCl with experimental accuracy. By a more strict theoretical approach and using updated experimental data, this model made substantial improvements over previous models: (1) the accuracy of methane solubility in pure water in the temperature range between 273 and 283 K is increased from about 10% to about 5%, but confirms the accuracy of the Duan model [Duan Z., Moller N., Weare J.H., 1992a. Prediction of methane solubilities in natural waters to high ionic strength from 0 to 250 °C and from 0 to 1600 bar. Geochim. Cosmochim. Acta56, 1451-1460] above 283 K up to 2000 bar; (2) the accuracy of methane solubility in the NaCl aqueous solutions is increased from >12% to about 6% on average from 273 K and 1 bar to 523 K and 2000 bar; (3) this model is able to calculate water content in the gas phase and liquid phase density, which cannot be calculated by previous models; and (4) it covers a wider range of temperature and pressure space. With a simple approach, this model is extended to predict CH 4 solubility in other aqueous salt solutions containing Na +, K +, Mg 2+, Ca 2+, Cl - and SO42-, such as seawater and geothermal brines, with excellent accuracy. This model is also able to calculate homogenization pressure of fluid inclusions (CH 4-H 2O-NaCl) and CH 4 solubility in water at gas-liquid-hydrate phase equilibrium. A computer code is developed for this model and can be downloaded from the website: www.geochem-model.org/programs.htm.
Maiden, D E
1998-10-01
A method for constructing bicubic interpolation polynomials for the pressure P and internal energy E that are thermodynamically consistent at the mesh ponts and continuous across mesh boundaries is presented. The slope boundary conditions for the pressure and energy are derived from finite differences of the data and from Maxwell's consistency relation. Monotonicity of the sound speed and the specific heat is obtained by a bilinear interpolation of the slopes of the tabulated data. Monotonicity of the functions near steep gradients may be achieved by mesh refinement or by using a non-consistent bilinear to the data. Mesh refinement is very efficient for uniform-linear or uniform-logarithmic spaced data because a direct table lookup can be used. The direct method was compared to binary search and was 37 percent faster for logarithmic-spaced data and 106 percent faster for linear-spaced data. This improvement in speed is very important in the radiation-transport opacity-lookup part of the calculation. Interpolation in P-E space, with mesh refinement, can be made simple, robust, and conserve energy. In the final analysis the interpolation of the free energy and entropy (Maiden and Cook) remains a competitor.
First and Second Laws of Thermodynamics in Modified Ho\\v{r}ava-Lifshitz $F(R)$ Gravity
Jawad, Abdul; Momeni, Davood; Gulshan, Faiza; Myrzakulov, Ratbay
2016-01-01
In this paper we discuss the thermodynamics of the apparent horizon in $F(R)$ Ho\\v{r}ava-Lifshitz gravity in equilibrium and non-equilibrium ensembles. We show that the second law of thermodynamics can be satisfied in this non relativistic theory.
Thermodynamics of Radiation Modes
Pina, Eduardo; de la Selva, Sara Maria Teresa
2010-01-01
We study the equilibrium thermodynamics of the electromagnetic radiation in a cavity of a given volume and temperature. We found three levels of description, the thermodynamics of one mode, the thermodynamics of the distribution of frequencies in a band by summing over the frequencies in it and the global thermodynamics by summing over all the…
Magnetic Dissipation in Relativistic Jets
Yosuke Mizuno
2016-10-01
Full Text Available The most promising mechanisms for producing and accelerating relativistic jets, and maintaining collimated structure of relativistic jets involve magnetohydrodynamical (MHD processes. We have investigated the magnetic dissipation mechanism in relativistic jets via relativistic MHD simulations. We found that the relativistic jets involving a helical magnetic field are unstable for the current-driven kink instability, which leads to helically distorted structure in relativistic jets. We identified the regions of high current density in filamentary current sheets, indicative of magnetic reconnection, which are associated to the kink unstable regions and correlated to the converted regions of magnetic to kinetic energies of the jets. We also found that an over-pressured relativistic jet leads to the generation of a series of stationary recollimation shocks and rarefaction structures by the nonlinear interaction of shocks and rarefaction waves. The differences in the recollimation shock structure due to the difference of the magnetic field topologies and strengths may be observable through mm-VLBI observations and space-VLBI mission.
Relativistic Fractal Cosmologies
Ribeiro, Marcelo B
2009-01-01
This article reviews an approach for constructing a simple relativistic fractal cosmology whose main aim is to model the observed inhomogeneities of the distribution of galaxies by means of the Lemaitre-Tolman solution of Einstein's field equations for spherically symmetric dust in comoving coordinates. This model is based on earlier works developed by L. Pietronero and J.R. Wertz on Newtonian cosmology, whose main points are discussed. Observational relations in this spacetime are presented, together with a strategy for finding numerical solutions which approximate an averaged and smoothed out single fractal structure in the past light cone. Such fractal solutions are shown, with one of them being in agreement with some basic observational constraints, including the decay of the average density with the distance as a power law (the de Vaucouleurs' density power law) and the fractal dimension in the range 1 <= D <= 2. The spatially homogeneous Friedmann model is discussed as a special case of the Lemait...
Lock, Maximilian P E
2016-01-01
The conflict between quantum theory and the theory of relativity is exemplified in their treatment of time. We examine the ways in which their conceptions differ, and describe a semiclassical clock model combining elements of both theories. The results obtained with this clock model in flat spacetime are reviewed, and the problem of generalizing the model to curved spacetime is discussed, before briefly describing an experimental setup which could be used to test of the model. Taking an operationalist view, where time is that which is measured by a clock, we discuss the conclusions that can be drawn from these results, and what clues they contain for a full quantum relativistic theory of time.
Two-fluid models of superfluid neutron star cores
Chamel, N
2008-01-01
Both relativistic and non-relativistic two-fluid models of neutron star cores are constructed, using the constrained variational formalism developed by Brandon Carter and co-workers. We consider a mixture of superfluid neutrons and superconducting protons at zero temperature, taking into account mutual entrainment effects. Leptons, which affect the interior composition of the neutron star and contribute to the pressure, are also included. We provide the analytic expression of the Lagrangian density of the system, the so-called master function, from which the dynamical equations can be obtained. All the microscopic parameters of the models are calculated consistently using the non-relativistic nuclear energy density functional theory. For comparison, we have also considered relativistic mean field models. The correspondence between relativistic and non-relativistic hydrodynamical models is discussed in the framework of the recently developed 4D covariant formalism of Newtonian multi-fluid hydrodynamics. We hav...
Relativistic Runaway Electrons
Breizman, Boris
2014-10-01
This talk covers recent developments in the theory of runaway electrons in a tokamak with an emphasis on highly relativistic electrons produced via the avalanche mechanism. The rapidly growing population of runaway electrons can quickly replace a large part of the initial current carried by the bulk plasma electrons. The magnetic energy associated with this current is typically much greater than the particle kinetic energy. The current of a highly relativistic runaway beam is insensitive to the particle energy, which separates the description of the runaway current evolution from the description of the runaway energy spectrum. A strongly anisotropic distribution of fast electrons is generally prone to high-frequency kinetic instabilities that may cause beneficial enhancement of runaway energy losses. The relevant instabilities are in the frequency range of whistler waves and electron plasma waves. The instability thresholds reported in earlier work have been revised considerably to reflect strong dependence of collisional damping on the wave frequency and the role of plasma non-uniformity, including radial trapping of the excited waves in the plasma. The talk also includes a discussion of enhanced scattering of the runaways as well as the combined effect of enhanced scattering and synchrotron radiation. A noteworthy feature of the avalanche-produced runaway current is a self-sustained regime of marginal criticality: the inductive electric field has to be close to its critical value (representing avalanche threshold) at every location where the runaway current density is finite, and the current density should vanish at any point where the electric field drops below its critical value. This nonlinear Ohm's law enables complete description of the evolving current profile. Work supported by the U.S. Department of Energy Contract No. DEFG02-04ER54742 and by ITER contract ITER-CT-12-4300000273. The views and opinions expressed herein do not necessarily reflect those of
Introduction to thermo-fluids systems design
Garcia McDonald, André
2012-01-01
A fully comprehensive guide to thermal systems design covering fluid dynamics, thermodynamics, heat transfer and thermodynamic power cycles Bridging the gap between the fundamental concepts of fluid mechanics, heat transfer and thermodynamics, and the practical design of thermo-fluids components and systems, this textbook focuses on the design of internal fluid flow systems, coiled heat exchangers and performance analysis of power plant systems. The topics are arranged so that each builds upon the previous chapter to convey to the reader that topics are not stand-alone i
Black hole chemistry: thermodynamics with Lambda
Kubizňák, David; Mann, Robert B.; Teo, Mae
2017-03-01
We review recent developments on the thermodynamics of black holes in extended phase space, where the cosmological constant is interpreted as thermodynamic pressure and treated as a thermodynamic variable in its own right. In this approach, the mass of the black hole is no longer regarded as internal energy, rather it is identified with the chemical enthalpy. This leads to an extended dictionary for black hole thermodynamic quantities; in particular a notion of thermodynamic volume emerges for a given black hole spacetime. This volume is conjectured to satisfy the reverse isoperimetric inequality—an inequality imposing a bound on the amount of entropy black hole can carry for a fixed thermodynamic volume. New thermodynamic phase transitions naturally emerge from these identifications. Namely, we show that black holes can be understood from the viewpoint of chemistry, in terms of concepts such as Van der Waals fluids, reentrant phase transitions, and triple points. We also review the recent attempts at extending the AdS/CFT dictionary in this setting, discuss the connections with horizon thermodynamics, applications to Lifshitz spacetimes, and outline possible future directions in this field.
What is "Relativistic Canonical Quantization"?
Arbatsky, D. A.
2005-01-01
The purpose of this review is to give the most popular description of the scheme of quantization of relativistic fields that was named relativistic canonical quantization (RCQ). I do not give here the full exact account of this scheme. But with the help of this review any physicist, even not a specialist in the relativistic quantum theory, will be able to get a general view of the content of RCQ, of its connection with other known approaches, of its novelty and of its fruitfulness.
Fluid mechanics and thermodynamics of turbomachinery
Dixon, S Larry
2005-01-01
The new edition will continue to be of use to engineers in industry and technological establishments, especially as brief reviews are included on many important aspects of Turbomachinery, giving pointers towards more advanced sources of information. For readers looking towards the wider reaches of the subject area, very useful additional reading is referenced in the bibliography. The subject of Turbomachinery is in continual review, and while the basics do not change, research can lead to refinements in popular methods, and new data can emerge. This book has applications for professiona
Probing the early-time dynamics of relativistic heavy-ion collisions with electromagnetic radiation
Vujanovic, Gojko; Denicol, Gabriel S; Luzum, Matthew; Schenke, Bjoern; Jeon, Sangyong; Gale, Charles
2014-01-01
Using 3+1D viscous relativistic fluid dynamics, we show that electromagnetic probes are sensitive to the initial conditions and to the out-of-equilibrium features of relativistic heavy-ion collisions. Within the same approach, we find that hadronic observables show a much lesser sensitivity to these aspects. We conclude that electromagnetic observables allow access to dynamical regions that are beyond the reach of soft hadronic probes.
A causality analysis of the linearized relativistic Navier-Stokes equations
Sandoval-Villalbazo, A
2010-01-01
It is shown by means of a simple analysis that the linearized system of transport equations for a relativistic, single component ideal gas at rest obeys the \\textit{antecedence principle}, which is often referred to as causality principle. This task is accomplished by examining the roots of the dispersion relation for such a system. This result is important for recent experiments performed in relativistic heavy ion colliders, since it suggests that the Israel-Stewart like formalisms may be unnecessary in order to describe relativistic fluids.
Mendez, A R; Sandoval-Villalbazo, A
2016-01-01
A correction to the Jeans stability criterion due to heat conduction is established for the case of high temperature gases. This effect is only relevant for relativistic fluids and includes an additional term due to a density gradient driven heat flux. The result is obtained by thoroughly analyzing the exponentially growing modes present in the dynamics of density fluctuations in the linearized relativistic Navier-Stokes regime. The corrections to the corresponding Jeans mass and wavenumber are explicitly obtained and are compared to the non-relativistic and non-dissipative values using the transport coefficients obtained in the BGK approximation.
A J John; S D Maharaj
2011-09-01
We obtain a class of solutions to the Einstein–Maxwell equations describing charged static spheres. Upon specifying particular forms for one of the gravitational potentials and the electric ﬁeld intensity, the condition for pressure isotropy is transformed into a hypergeometric equation with two free parameters. For particular parameter values we recover uncharged solutions corresponding to speciﬁc neutron star models. We ﬁnd two charged solutions in terms of elementary functions for particular parameter values. The ﬁrst charged model is physically reasonable and the metric functions and thermodynamic variables are well behaved. The second charged model admits a negative energy density and violates the energy conditions.
A Study of Universal Thermodynamics in Lanczos-Lovelock gravity
Mitra, Saugata; Chakraborty, Subenoy
2016-01-01
A study of Universal thermodynamics is done in Lanczos-Lovelock gravity. The Universe is chosen as FRW model bounded by apparent or event horizon. The unified first law is examined, assuming extended Hawking temperature on the horizon. As a result there is a modification of Bekenstein entropy on the horizons. Further the validity of generalized second law of thermodynamics and thermodynamical equilibrium are also investigated for perfect fluid (with constant equation of state), modified chaplygin gas model and holographic dark energy model.
Simulating relativistic binaries with Whisky
Baiotti, L.
We report about our first tests and results in simulating the last phase of the coalescence and the merger of binary relativistic stars. The simulations were performed using our code Whisky and mesh refinement through the Carpet driver.
Relativistic effects in atom gravimeters
Tan, Yu-Jie; Shao, Cheng-Gang; Hu, Zhong-Kun
2017-01-01
Atom interferometry is currently developing rapidly, which is now reaching sufficient precision to motivate laboratory tests of general relativity. Thus, it is extremely significant to develop a general relativistic model for atom interferometers. In this paper, we mainly present an analytical derivation process and first give a complete vectorial expression for the relativistic interferometric phase shift in an atom interferometer. The dynamics of the interferometer are studied, where both the atoms and the light are treated relativistically. Then, an appropriate coordinate transformation for the light is performed crucially to simplify the calculation. In addition, the Bordé A B C D matrix combined with quantum mechanics and the "perturbation" approach are applied to make a methodical calculation for the total phase shift. Finally, we derive the relativistic phase shift kept up to a sensitivity of the acceleration ˜1 0-14 m/s 2 for a 10 -m -long atom interferometer.
Hamiltonian analysis of interacting fluids
Banerjee, Rabin; Mitra, Arpan Krishna [S. N. Bose National Centre for Basic Sciences, Kolkata (India); Ghosh, Subir [Indian Statistical Institute, Kolkata (India)
2015-05-15
Ideal fluid dynamics is studied as a relativistic field theory with particular stress on its hamiltonian structure. The Schwinger condition, whose integrated version yields the stress tensor conservation, is explicitly verified both in equal-time and light-cone coordinate systems. We also consider the hamiltonian formulation of fluids interacting with an external gauge field. The complementary roles of the canonical (Noether) stress tensor and the symmetric one obtained by metric variation are discussed. (orig.)
Scattering in Relativistic Particle Mechanics.
de Bievre, Stephan
The problem of direct interaction in relativistic particle mechanics has been extensively studied and a variety of models has been proposed avoiding the conclusions of the so-called no-interaction theorems. In this thesis we study scattering in the relativistic two-body problem. We use our results to analyse gauge invariance in Hamiltonian constraint models and the uniqueness of the symplectic structure in manifestly covariant relativistic particle mechanics. We first present a general geometric framework that underlies approaches to relativistic particle mechanics. This permits a model-independent and geometric definition of the notions of asymptotic completeness and of Moller and scattering operators. Subsequent analysis of these concepts divides into two parts. First, we study the kinematic properties of the scattering transformation, i.e. those properties that arise solely from the invariance of the theory under the Poincare group. We classify all canonical (symplectic) scattering transformations on the relativistic phase space for two free particles in terms of a single function of the two invariants of the theory. We show how this function is determined by the center of mass time delay and scattering angle and vice versa. The second part of our analysis of the relativistic two-body scattering problem is devoted to the dynamical properties of the scattering process. Hence, we turn to two approaches to relativistic particle mechanics: the Hamiltonian constraint models and the manifestly covariant formalism. Using general geometric arguments, we prove "gauge invariance" of the scattering transformation in the Todorov -Komar Hamiltonian constraint model. We conclude that the scattering cross sections of the Todorov-Komar models have the same angular dependence as their non-relativistic counterpart, irrespective of a choice of gauge. This limits the physical relevance of those models. We present a physically non -trivial Hamiltonian constraint model, starting from
Relativistic formulation and reference frame
Klioner, Sergei A.
2004-01-01
After a short review of experimental foundations of metric theories of gravity, the choice of general relativity as a theory to be used for the routine modeling of Gaia observations is justified. General principles of relativistic modeling of astronomical observations are then sketched and compared to the corresponding Newtonian principles. The fundamental reference system -- Barycentric Celestial Reference System, which has been chosen to be the relativistic reference system underlying the f...
Thermodynamic tables to accompany Modern engineering thermodynamics
Balmer, Robert T
2011-01-01
This booklet is provided at no extra charge with new copies of Balmer's Modern Engineering Thermodynamics. It contains two appendices. Appendix C contains 40 thermodynamic tables, and Appendix D consists of 6 thermodynamic charts. These charts and tables are provided in a separate booklet to give instructors the flexibility of allowing students to bring the tables into exams. The booklet may be purchased separately if needed.
Lattice QCD Thermodynamics with Physical Quark Masses
Soltz, R A; Karsch, F; Mukherjee, Swagato; Vranas, P
2015-01-01
Over the past few years new physics methods and algorithms as well as the latest supercomputers have enabled the study of the QCD thermodynamic phase transition using lattice gauge theory numerical simulations with unprecedented control over systematic errors. This is largely a consequence of the ability to perform continuum extrapolations with physical quark masses. Here we review recent progress in lattice QCD thermodynamics, focussing mainly on results that benefit from the use of physical quark masses: the crossover temperature, the equation of state, and fluctuations of the quark number susceptibilities. In addition, we place a special emphasis on calculations that are directly relevant to the study of relativistic heavy ion collisions at RHIC and the LHC.
Linear wave propagation in relativistic magnetohydrodynamics
Keppens, R
2008-01-01
The properties of linear Alfv\\'en, slow, and fast magnetoacoustic waves for uniform plasmas in relativistic magnetohydrodynamics (MHD) are discussed, augmenting the well-known expressions for their phase speeds with knowledge on the group speed. A 3+1 formalism is purposely adopted to make direct comparison with the Newtonian MHD limits easier and to stress the graphical representation of their anisotropic linear wave properties using the phase and group speed diagrams. By drawing these for both the fluid rest frame and for a laboratory Lorentzian frame which sees the plasma move with a three-velocity having an arbitrary orientation with respect to the magnetic field, a graphical view of the relativistic aberration effects is obtained for all three MHD wave families. Moreover, it is confirmed that the classical Huygens construction relates the phase and group speed diagram in the usual way, even for the lab frame viewpoint. Since the group speed diagrams correspond to exact solutions for initial conditions co...
Classical and statistical thermodynamics
Rizk, Hanna A
2016-01-01
This is a text book of thermodynamics for the student who seeks thorough training in science or engineering. Systematic and thorough treatment of the fundamental principles rather than presenting the large mass of facts has been stressed. The book includes some of the historical and humanistic background of thermodynamics, but without affecting the continuity of the analytical treatment. For a clearer and more profound understanding of thermodynamics this book is highly recommended. In this respect, the author believes that a sound grounding in classical thermodynamics is an essential prerequisite for the understanding of statistical thermodynamics. Such a book comprising the two wide branches of thermodynamics is in fact unprecedented. Being a written work dealing systematically with the two main branches of thermodynamics, namely classical thermodynamics and statistical thermodynamics, together with some important indexes under only one cover, this treatise is so eminently useful.
Noether's theorem of relativistic-electromagnetic ideal hydrodynamics
Elsas, J.H. Gaspar; Koide, T.; Kodama, T., E-mail: jhelsas@gmail.com, E-mail: kodama.takeshi@gmail.com, E-mail: tomoikoide@gmail.com [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Instituto de Fisica
2015-06-15
We present a variational approach for relativistic ideal hydrodynamics interacting with electromagnetic fields. The momentum of fluid is introduced as the canonical conjugate variable of the position of a fluid element, which coincides with the conserved quantity derived from Noether's theorem. We further show that our formulation can reproduce the usual electromagnetic hydrodynamics which is obtained so as to satisfy the conservation of the inertia of fluid motion. (author)
Thermodynamic geometry of supercooled water
May, Helge-Otmar; Mausbach, Peter; Ruppeiner, George
2015-03-01
The thermodynamic curvature scalar R is evaluated for supercooled water with a two-state equation of state correlated with the most recent available experimental data. This model assumes a liquid-liquid critical point. Our investigation extends the understanding of the thermodynamic behavior of R considerably. We show that R diverges to -∞ when approaching the assumed liquid-liquid critical point. This limit is consistent with all of the fluid critical point models known so far. In addition, we demonstrate a sign change of R along the liquid-liquid line from negative near the critical point to positive on moving away from the critical point in the low density "ice-like" liquid phase. We also trace out the Widom line in phase space. In addition, we investigate increasing correlation length in supercooled water and compare our results with recent published small angle x-ray scattering measurements.
Thermodynamic behaviour of supercritical matter.
Bolmatov, Dima; Brazhkin, V V; Trachenko, K
2013-01-01
Since their discovery in 1822, supercritical fluids have been of enduring interest and have started to be deployed in many important applications. Theoretical understanding of the supercritical state is lacking and is seen to limit further industrial deployment. Here we study thermodynamic properties of the supercritical state and discover that specific heat shows a crossover between two different regimes, an unexpected result in view of currently perceived homogeneity of supercritical state in terms of physical properties. We subsequently formulate a theory of system thermodynamics above the crossover, and find good agreement between calculated and experimental specific heat with no free-fitting parameters. In this theory, energy and heat capacity are governed by the minimal length of the longitudinal mode in the system only, and do not explicitly depend on system-specific structure and interactions. We derive a power law and analyse supercritical scaling exponents in the system above the Frenkel line.
Applied Fluid Mechanics. Lecture Notes.
Gregg, Newton D.
This set of lecture notes is used as a supplemental text for the teaching of fluid dynamics, as one component of a thermodynamics course for engineering technologists. The major text for the course covered basic fluids concepts such as pressure, mass flow, and specific weight. The objective of this document was to present additional fluids…
Applied Fluid Mechanics. Lecture Notes.
Gregg, Newton D.
This set of lecture notes is used as a supplemental text for the teaching of fluid dynamics, as one component of a thermodynamics course for engineering technologists. The major text for the course covered basic fluids concepts such as pressure, mass flow, and specific weight. The objective of this document was to present additional fluids…
Relativistic HD and MHD modelling for AGN jets
Keppens, R.; Porth, O.; Monceau-Baroux, R.; Walg, S.
2013-12-01
Relativistic hydro and magnetohydrodynamics (MHD) provide a continuum fluid description for plasma dynamics characterized by shock-dominated flows approaching the speed of light. Significant progress in its numerical modelling emerged in the last two decades; we highlight selected examples of modern grid-adaptive, massively parallel simulations realized by our open-source software MPI-AMRVAC (Keppens et al 2012 J. Comput. Phys. 231 718). Hydrodynamical models quantify how energy transfer from active galactic nuclei (AGN) jets to their surrounding interstellar/intergalactic medium (ISM/IGM) gets mediated through shocks and various fluid instability mechanisms (Monceau-Baroux et al 2012 Astron. Astrophys. 545 A62). With jet parameters representative for Fanaroff-Riley type-II jets with finite opening angles, we can quantify the ISM volumes affected by jet injection and distinguish the roles of mixing versus shock-heating in cocoon regions. This provides insight in energy feedback by AGN jets, usually incorporated parametrically in cosmological evolution scenarios. We discuss recent axisymmetric studies up to full 3D simulations for precessing relativistic jets, where synthetic radio maps can confront observations. While relativistic hydrodynamic models allow one to better constrain dynamical parameters like the Lorentz factor and density contrast between jets and their surroundings, the role of magnetic fields in AGN jet dynamics and propagation characteristics needs full relativistic MHD treatments. Then, we can demonstrate the collimating properties of an overal helical magnetic field backbone and study differences between poloidal versus toroidal field dominated scenarios (Keppens et al 2008 Astron. Astrophys. 486 663). Full 3D simulations allow one to consider the fate of non-axisymmetric perturbations on relativistic jet propagation from rotating magnetospheres (Porth 2013 Mon. Not. R. Astron. Soc. 429 2482). Self-stabilization mechanisms related to the detailed
Measuring Thermodynamic Length
Crooks, Gavin E
2007-09-07
Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It is also connected to the Jensen-Shannon divergence, Fisher information, and Rao's entropy differential metric. Therefore, thermodynamic length is of central interestin understanding matter out of equilibrium. In this Letter, we will consider how to denethermodynamic length for a small system described by equilibrium statistical mechanics and how to measure thermodynamic length within a computer simulation. Surprisingly, Bennett's classic acceptance ratio method for measuring free energy differences also measures thermodynamic length.
On relativistic models of strange stars
Ramesh Tikekar; Kanti Jotania
2007-03-01
The superdense stars with mass-to-size ratio exceeding 0.3 are expected to be made of strange matter. Assuming that the 3-space of the interior space-time of a strange star is that of a three-paraboloid immersed in a four-dimensional Euclidean space, we obtain a two-parameter family of their physically viable relativistic models. This ansatz determines density distribution of the interior self-gravitating matter up to one unknown parameter. The Einstein's field equations determine the fluid pressure and the remaining geometrical variables. The information about mass-to-size ratio together with the conventional boundary conditions lead to the determination of total mass, radius and other parameters of the stellar configuration.
General relativistic neutrino transport using spectral methods
Peres, Bruno; Novak, Jerome; Bonazzola, Silvano
2014-01-01
We present a new code, Lorene's Ghost (for Lorene's gravitational handling of spectral transport) developed to treat the problem of neutrino transport in supernovae with the use of spectral methods. First, we derive the expression for the nonrelativistic Liouville operator in doubly spherical coordinates (r, theta, phi, epsilon, Theta, Phi)$, and further its general relativistic counterpart. We use the 3 + 1 formalism with the conformally flat approximation for the spatial metric, to express the Liouville operator in the Eulerian frame. Our formulation does not use any approximations when dealing with the angular arguments (theta, phi, Theta, Phi), and is fully energy-dependent. This approach is implemented in a spherical shell, using either Chebyshev polynomials or Fourier series as decomposition bases. It is here restricted to simplified collision terms (isoenergetic scattering) and to the case of a static fluid. We finish this paper by presenting test results using basic configurations, including general r...
Dissipation in relativistic superfluid neutron stars
Gusakov, M E; Chugunov, A I; Gualtieri, L
2012-01-01
We analyze damping of oscillations of general relativistic superfluid neutron stars. To this aim we extend the method of decoupling of superfluid and normal oscillation modes first suggested in [Gusakov & Kantor PRD 83, 081304(R) (2011)]. All calculations are made self-consistently within the finite temperature superfluid hydrodynamics. The general analytic formulas are derived for damping times due to the shear and bulk viscosities. These formulas describe both normal and superfluid neutron stars and are valid for oscillation modes of arbitrary multipolarity. We show that: (i) use of the ordinary one-fluid hydrodynamics is a good approximation, for most of the stellar temperatures, if one is interested in calculation of the damping times of normal f-modes; (ii) for radial and p-modes such an approximation is poor; (iii) the temperature dependence of damping times undergoes a set of rapid changes associated with resonance coupling of neighboring oscillation modes. The latter effect can substantially accel...
Determining the Macroscopic Properties of Relativistic Jets
Hardee, P. E.
2004-08-01
The resolved relativistic jets contain structures whose observed proper motions are typically assumed to indicate the jet flow speed. In addition to structures moving with the flow, various normal mode structures such as pinching or helical and elliptical twisting can be produced by ejection events or twisting perturbations to the jet flow. The normal mode structures associated with relativistic jets, as revealed by numerical simulation, theoretical calculation, and suggested by observation, move more slowly than the jet speed. The pattern speed is related to the jet speed by the sound speed in the jet and in the surrounding medium. In the event that normal mode structures are observed, and where proper motions of pattern and flow speed are available or can be estimated, it is possible to determine the sound speed in the jet and surrounding medium. Where spatial development of normal mode structures is observed, it is possible to make inferences as to the heating rate/macroscopic viscosity of the jet fluid. Ultimately it may prove possible to separate the microscopic energization of the synchrotron radiating particles from the macroscopic heating of the jet fluid. Here I present the relevant properties of useful normal mode structures and illustrate the use of this technique. Various aspects of the work presented here have involved collaboration with I. Agudo (Max-Planck, Bonn), M.A. Aloy (Max-Planck, Garching), J. Eilek (NM Tech), J.L. Gómez (U. Valencia), P. Hughes (U. Michigan), A. Lobanov (Max-Planck, Bonn), J.M. Martí (U. Valencia), & C. Walker (NRAO).
Stacey, Frank D [CSIRO Exploration and Mining, PO Box 883, Kenmore, Qld. 4069 (Australia)], E-mail: Frank.Stacey@csiro.au
2010-04-15
Applications of elementary thermodynamic principles to the dynamics of the Earth lead to robust, quantitative conclusions about the tectonic effects that arise from convection. The grand pattern of motion conveys deep heat to the surface, generating mechanical energy with a thermodynamic efficiency corresponding to that of a Carnot engine operating over the adiabatic temperature gradient between the heat source and sink. Referred to the total heat flux derived from the Earth's silicate mantle, the efficiency is 24% and the power generated, 7.7 x 10{sup 12} W, causes all the material deformation apparent as plate tectonics and the consequent geological processes. About 3.5% of this is released in seismic zones but little more than 0.2% as seismic waves. Even major earthquakes are only localized hiccups in this motion. Complications that arise from mineral phase transitions can be used to illuminate details of the motion. There are two superimposed patterns of convection, plate subduction and deep mantle plumes, driven by sources of buoyancy, negative and positive respectively, at the top and bottom of the mantle. The patterns of motion are controlled by the viscosity contrasts (>10{sup 4} : 1) at these boundaries and are self-selected as the least dissipative mechanisms of heat transfer for convection in a body with very strong viscosity variation. Both are subjects of the thermodynamic efficiency argument. Convection also drives the motion in the fluid outer core that generates the geomagnetic field, although in that case there is an important energy contribution by compositional separation, as light solute is rejected by the solidifying inner core and mixed into the outer core, a process referred to as compositional convection. Uncertainty persists over the core energy balance because thermal conduction is a drain on core energy that has been a subject of diverse estimates, with attendant debate over the need for radiogenic heat in the core. The geophysical
Noncommutative Fluid and Cosmological Perturbations
Das, Praloy
2016-01-01
In the present paper we have developed a Non-Commutative (NC) generalization of perfect fluid model from first principles, in a Hamiltonian framework. The noncommutativity is introduced at the Lagrangian (particle) coordinate space brackets and the induced NC fluid bracket algebra for the Eulerian (fluid) field variables is derived. Together with a Hamiltonian this NC algebra generates the generalized fluid dynamics that satisfies exact local conservation laws for mass and energy thereby maintaining mass and energy conservation. However, nontrivial NC correction terms appear in charge and energy fluxes. Other non-relativistic spacetime symmetries of the NC fluid are also discussed in detail. This constitutes the NC fluid dynamics and kinematics. In the second part we construct an extension of Friedmann-Robertson-Walker (FRW) cosmological model based on the NC fluid dynamics presented here. We outline the way in which NC effects generate cosmological perturbations bringing in anisotropy and inhomogeneity in th...
Refining a relativistic, hydrodynamic solver: Admitting ultra-relativistic flows
Bernstein, J. P.; Hughes, P. A.
2009-09-01
We have undertaken the simulation of hydrodynamic flows with bulk Lorentz factors in the range 102-106. We discuss the application of an existing relativistic, hydrodynamic primitive variable recovery algorithm to a study of pulsar winds, and, in particular, the refinement made to admit such ultra-relativistic flows. We show that an iterative quartic root finder breaks down for Lorentz factors above 102 and employ an analytic root finder as a solution. We find that the former, which is known to be robust for Lorentz factors up to at least 50, offers a 24% speed advantage. We demonstrate the existence of a simple diagnostic allowing for a hybrid primitives recovery algorithm that includes an automatic, real-time toggle between the iterative and analytical methods. We further determine the accuracy of the iterative and hybrid algorithms for a comprehensive selection of input parameters and demonstrate the latter’s capability to elucidate the internal structure of ultra-relativistic plasmas. In particular, we discuss simulations showing that the interaction of a light, ultra-relativistic pulsar wind with a slow, dense ambient medium can give rise to asymmetry reminiscent of the Guitar nebula leading to the formation of a relativistic backflow harboring a series of internal shockwaves. The shockwaves provide thermalized energy that is available for the continued inflation of the PWN bubble. In turn, the bubble enhances the asymmetry, thereby providing positive feedback to the backflow.
Chemical thermodynamics: plenary review.
Fegley, B., Jr.
1990-05-01
The invited and contributed papers dealing with the applications of chemical thermodynamics to planetary atmospheres research are briefly reviewed. The key areas for future applications of chemical thermodynamics research to planetary atmospheres are also described.
Death and resurrection of the zeroth principle of thermodynamics
Haggard, Hal M.; Rovelli, Carlo
2013-01-01
The zeroth principle of thermodynamics in the form "temperature is uniform at equilibrium" is notoriously violated in relativistic gravity. Temperature uniformity is often derived from the maximization of the total number of microstates of two interacting systems under energy exchanges. Here we discuss a generalized version of this derivation, based on informational notions, which remains valid in the general context. The result is based on the observation that the time taken by any system to...
Saxena, A K
2014-01-01
Heat and thermodynamics aims to serve as a textbook for Physics, Chemistry and Engineering students. The book covers basic ideas of Heat and Thermodynamics, Kinetic Theory and Transport Phenomena, Real Gases, Liquafaction and Production and Measurement of very Low Temperatures, The First Law of Thermodynamics, The Second and Third Laws of Thermodynamics and Heat Engines and Black Body Radiation. KEY FEATURES Emphasis on concepts Contains 145 illustrations (drawings), 9 Tables and 48 solved examples At the end of chapter exercises and objective questions
Superheated emulsions: neutronics and thermodynamics
d`Errico, F. [Pisa Univ. (Italy). Dipt. di Costruzioni Meccaniche e Nucleari]|[Yale Univ., New Haven, CT (United States). School of Medicine; Curzio, G. [Pisa Univ. (Italy). Dipt. di Costruzioni Meccaniche e Nucleari; Nath, R. [Yale Univ., New Haven, CT (United States). School of Medicine; Apfel, R.E. [Yale Univ., New Haven, CT (United States). Dept. of Mechanical Engineering; Dietz, E.; Guldbakke, S.; Siebert, B.R.L. [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany); Egger, E. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Gualdrini, G.F. [ENEA, Bologna (Italy)
1997-09-01
The results of some recent theoretical and experimental investigations on the physics of superheated emulsions are presented. Computational fluid thermodynamics allowed for a detailed description of the temporal and spatial history of the energy deposition process by a charged particle in a superheated liquid. Despite the assumptions it is based upon, this model gives information in agreement with experimental data on bubble nucleation. The experimental findings concern the role of interfacial reactions between drops and emulsifier, the existence of inhibition temperatures for the detector`s response, and the progressive sensitisation to protons. (author).
Mathematical theory of compressible fluid flow
Von Mises, Richard
2012-01-01
Mathematical Theory of Compressible Fluid Flow covers the conceptual and mathematical aspects of theory of compressible fluid flow. This five-chapter book specifically tackles the role of thermodynamics in the mechanics of compressible fluids. This text begins with a discussion on the general theory of characteristics of compressible fluid with its application. This topic is followed by a presentation of equations delineating the role of thermodynamics in compressible fluid mechanics. The discussion then shifts to the theory of shocks as asymptotic phenomena, which is set within the context of
Empirical Foundations of Relativistic Gravity
Ni, W T
2005-01-01
In 1859, Le Verrier discovered the mercury perihelion advance anomaly. This anomaly turned out to be the first relativistic-gravity effect observed. During the 141 years to 2000, the precisions of laboratory and space experiments, and astrophysical and cosmological observations on relativistic gravity have been improved by 3 orders of magnitude. In 1999, we envisaged a 3-6 order improvement in the next 30 years in all directions of tests of relativistic gravity. In 2000, the interferometric gravitational wave detectors began their runs to accumulate data. In 2003, the measurement of relativistic Shapiro time-delay of the Cassini spacecraft determined the relativistic-gravity parameter gammaγ with a 1.5-order improvement. In October 2004, Ciufolini and Pavlis reported a measurement of the Lense-Thirring effect on the LAGEOS and LAGEOS2 satellites to 10 percent of the value predicted by general relativity. In April 2004, Gravity Probe B was launched and has been accumulating science data for more than ...
On the thermodynamics of scale factor dual Universes
Sotkov, G M; da Silva, U Camara
2016-01-01
The thermodynamical aspects of the conformal time scale factor duality (SFD) of cosmological models within Einstein Gravity are investigated. We derive the SFD transformations of the thermodynamical quantities describing the thermal evolution of the matter fluid and of the apparent horizon. The thermodynamical properties of the self-dual cosmological models with a modified Chaplygin gas are studied in detail. We deduce the restrictions on the equation of state parameters that allow to extend scale factor duality as a UV/IR symmetry of the cosmological models consistent with their thermodynamical behavior.
Relativistic causality and clockless circuits
Matherat, Philippe; 10.1145/2043643.2043650
2011-01-01
Time plays a crucial role in the performance of computing systems. The accurate modelling of logical devices, and of their physical implementations, requires an appropriate representation of time and of all properties that depend on this notion. The need for a proper model, particularly acute in the design of clockless delay-insensitive (DI) circuits, leads one to reconsider the classical descriptions of time and of the resulting order and causal relations satisfied by logical operations. This questioning meets the criticisms of classical spacetime formulated by Einstein when founding relativity theory and is answered by relativistic conceptions of time and causality. Applying this approach to clockless circuits and considering the trace formalism, we rewrite Udding's rules which characterize communications between DI components. We exhibit their intrinsic relation with relativistic causality. For that purpose, we introduce relativistic generalizations of traces, called R-traces, which provide a pertinent des...
Pauken, Mike
2011-01-01
Take some heat off the complexity of thermodynamics Does the mere thought of thermodynamics make you sweat? It doesn't have to! This hands-on guide helps you score your highest in a thermodynamics course by offering easily understood, plain-English explanations of how energy is used in things like automobiles, airplanes, air conditioners, and electric power plants. Thermodynamics 101 - take a look at some examples of both natural and man-made thermodynamic systems and get a handle on how energy can be used to perform work Turn up the heat - discover how to use the firs
Introduction to applied thermodynamics
Helsdon, R M; Walker, G E
1965-01-01
Introduction to Applied Thermodynamics is an introductory text on applied thermodynamics and covers topics ranging from energy and temperature to reversibility and entropy, the first and second laws of thermodynamics, and the properties of ideal gases. Standard air cycles and the thermodynamic properties of pure substances are also discussed, together with gas compressors, combustion, and psychrometry. This volume is comprised of 16 chapters and begins with an overview of the concept of energy as well as the macroscopic and molecular approaches to thermodynamics. The following chapters focus o
Twenty lectures on thermodynamics
Buchdahl, H A
2013-01-01
Twenty Lectures on Thermodynamics is a course of lectures, parts of which the author has given various times over the last few years. The book gives the readers a bird's eye view of phenomenological and statistical thermodynamics. The book covers many areas in thermodynamics such as states and transition; adiabatic isolation; irreversibility; the first, second, third and Zeroth laws of thermodynamics; entropy and entropy law; the idea of the application of thermodynamics; pseudo-states; the quantum-static al canonical and grand canonical ensembles; and semi-classical gaseous systems. The text
Shahmansouri, M.; Misra, A. P.
2016-12-01
The modulational instability (MI) and the evolution of weakly nonlinear two-dimensional (2D) Langmuir wave (LW) packets are studied in an unmagnetized collisionless plasma with weakly relativistic electron flow. By using a 2D self-consistent relativistic fluid model and employing the standard multiple-scale technique, a coupled set of Davey-Stewartson (DS)-like equations is derived, which governs the slow modulation and the evolution of LW packets in relativistic plasmas. It is found that the relativistic effects favor the instability of LW envelopes in the k - θ plane, where k is the wave number and θ ( 0 ≤ θ ≤ π ) the angle of modulation. It is also found that as the electron thermal velocity or θ increases, the growth rate of MI increases with cutoffs at higher wave numbers of modulation. Furthermore, in the nonlinear evolution of the DS-like equations, it is seen that with an effect of the relativistic flow, a Gaussian wave beam collapses in a finite time, and the collapse can be arrested when the effect of the thermal pressure or the relativistic flow is slightly relaxed. The present results may be useful to the MI and the formation of localized LW envelopes in cosmic plasmas with a relativistic flow of electrons.
One dimensional PIC simulation of relativistic Buneman instability
Rajawat, Roopendra Singh; Sengupta, Sudip
2016-10-01
Spatio-temporal evolution of the relativistic Buneman instability has been investigated in one dimension using an in-house developed particle-in-cell simulation code. Starting from the excitation of the instability, its evolution has been followed numerically till its quenching and beyond. The simulation results have been quantitatively compared with the fluid theory and are found to be in conformity with the well known fact that the maximum growth rate (γmax) reduces due to relativistic effects and varies with γ e 0 and m/M as γ m a x ˜ /√{ 3 } 2 √{ γ e 0 } ( /m 2 M ) 1 / 3 , where γ e 0 is the Lorentz factor associated with the initial electron drift velocity (v0) and (m/M) is the electron to ion mass ratio. Further it is observed that in contrast to the non-relativistic results [A. Hirose, Plasma Phys. 20, 481 (1978)] at the saturation point, the ratio of electrostatic field energy density ( ∑ k | E k | 2 / 8 π ) to initial drift kinetic energy density (W0) scales with γ e 0 as ˜ 1 / γe 0 2 . This novel result on the scaling of energy densities has been found to be in quantitative agreement with the scalings derived using fluid theory.
Relativistic RPA in axial symmetry
Arteaga, D Pena; 10.1103/PhysRevC.77.034317
2009-01-01
Covariant density functional theory, in the framework of self-consistent Relativistic Mean Field (RMF) and Relativistic Random Phase approximation (RPA), is for the first time applied to axially deformed nuclei. The fully self-consistent RMF+RRPA equations are posed for the case of axial symmetry and non-linear energy functionals, and solved with the help of a new parallel code. Formal properties of RPA theory are studied and special care is taken in order to validate the proper decoupling of spurious modes and their influence on the physical response. Sample applications to the magnetic and electric dipole transitions in $^{20}$Ne are presented and analyzed.