Flexural Behavior of RC Slabs Strengthened in Flexure with Basalt Fabric-Reinforced Cementitious Matrix

Directory of Open Access Journals (Sweden)

Sugyu Lee

2018-01-01

Full Text Available This paper presents both experimental and analytical research results for predicting the flexural capacity of reinforced concrete (RC slabs strengthened in flexure with basalt fabric-reinforced cementitious matrix (FRCM. A total of 13 specimens were fabricated to evaluate the flexural behavior of RC slabs strengthened with basalt FRCM composite and were tested under four-point loading. The fiber type, tensile reinforcement ratio, and the number of fabric layers were chosen as experimental variables. The maximum load of FRCM-strengthened specimens increased from 11.2% to 98.2% relative to the reference specimens. The energy ratio and ductility of the FRCM-strengthened specimens decreased with the higher amount of fabric and tensile reinforcement. The effective stress level of FRCM fabric can be accurately predicted by a bond strength of ACI 549 and Jung’s model.

Engineered cementitious composites with low volume of cementitious materials

NARCIS (Netherlands)

Zhou, J.; Quian, S.; Van Breugel, K.

2010-01-01

Engineered cementitious composite (ECC) is an ultra ductile cement-based material reinforced with fibers. It is characterized by high tensile ductility and tight crack width control. Thanks to the excellent performance, ECC is emerging in broad applications to enhance the loading capacity and the

Flexural Behavior of High-Volume Steel Fiber Cementitious Composite Externally Reinforced with Basalt FRP Sheet

OpenAIRE

Seungwon Kim; Cheolwoo Park

2016-01-01

High-performance fiber-reinforced cementitious composites (HPFRCCs) are characterized by unique tensile strain hardening and multiple microcracking behaviors. The HPFRCC, which demonstrates remarkable properties such as strength, ductility, toughness, durability, stiffness, and thermal resistance, is a class of fiber cement composite with fine aggregates. It can withstand tensile stresses by forming distributed microcracks owing to the embedded fibers in the concrete, which improve the energy...

Repair of Impact-Damaged Prestressed Bridge Girders Using Strand Splices and Fabric Reinforced Cementitious Matrix

OpenAIRE

Jones, Mark Stevens

2017-01-01

This thesis investigates the repair of impact-damaged prestressed concrete bridge girders with strand splices and fabric-reinforced cementitious matrix systems, specifically for repair of structural damage to the underside of an overpass bridge girder due to an overheight vehicle collision. Collision damage to bridges can range from minor to catastrophic, potentially requiring repair or replacement of a bridge girder. This thesis investigates the performance of two different types of repair...

Flexural Behavior of High-Volume Steel Fiber Cementitious Composite Externally Reinforced with Basalt FRP Sheet

Directory of Open Access Journals (Sweden)

Seungwon Kim

2016-01-01

Full Text Available High-performance fiber-reinforced cementitious composites (HPFRCCs are characterized by unique tensile strain hardening and multiple microcracking behaviors. The HPFRCC, which demonstrates remarkable properties such as strength, ductility, toughness, durability, stiffness, and thermal resistance, is a class of fiber cement composite with fine aggregates. It can withstand tensile stresses by forming distributed microcracks owing to the embedded fibers in the concrete, which improve the energy absorption capacity and apparent ductility. This high energy absorbing capacity can be enhanced further by an external stiff fiber-reinforced polymer (FRP. Basalt fabric is externally bonded as a sheet on concrete materials to enhance the durability and resistance to fire and other environmental attacks. This study investigates the flexural performance of an HPFRCC that is externally reinforced with multiple layers of basalt FRP. The HPFRCC considered in the study contains steel fibers at a volume fraction of 8%.

Study on reinforced lightweight coconut shell concrete beam behavior under shear

International Nuclear Information System (INIS)

Gunasekaran, K.; Annadurai, R.; Kumar, P.S.

2013-01-01

Highlights: • Coconut shell used as aggregate in concrete production. • Coconut shell concrete beam behavior studied under shear. • Coconut shell concrete beam behavior are compared with control concrete beams. - Abstract: Lightweight concrete has been produced using crushed coconut shell as coarse aggregate. The shear behavior of reinforced concrete beam made with coconut shell is analyzed and compared with the normal control concrete. Eight beams, four with coconut shell concrete and four with normal control concrete were fabricated and tested. Study includes the structural shear behavior, shear capacity, cracking behavior, deflection behavior, ductility, strains in concrete and in reinforcement. It was observed that the shear behavior of coconut shell concrete is comparable to that of other lightweight concretes. The results of concrete compression strain and steel tension strain showed that coconut shell concrete is able to achieve its full strain capacity under shear loadings. However, the failure zones of coconut shell concrete were larger than for control concrete beams

Coupled hygrothermal, electrochemical, and mechanical modelling for deterioration prediction in reinforced cementitious materials

DEFF Research Database (Denmark)

Michel, Alexander; Geiker, Mette Rica; Lepech, M.

2017-01-01

In this paper a coupled hygrothermal, electrochemical, and mechanical modelling approach for the deterioration prediction in cementitious materials is briefly outlined. Deterioration prediction is thereby based on coupled modelling of (i) chemical processes including among others transport of hea......, i.e. information, such as such as corrosion current density, damage state of concrete cover, etc., are constantly exchanged between the models....... and matter as well as phase assemblage on the nano and micro scale, (ii) corrosion of steel including electrochemical processes at the reinforcement surface, and (iii) material performance including corrosion- and load-induced damages on the meso and macro scale. The individual FEM models are fully coupled...

Service life prediction and cementitious composites

DEFF Research Database (Denmark)

Stoklund Larsen, E.

The present Ph.D.thesis describes and discusses the applicability of a systematic methodology recommended by CIB W80/RILEM-PSL for sevice life prediction. The report describes the most important inherent and environmental factors affecting the service life of structures of cementitious composites....... On the basis of this discription of factors and experience from a test programme described in SBI Report 222, Service life prediction and fibre reinforced cementitious composites, the applicabillity of the CIB/RILEM methodology is discussed....

Shear transfer in concrete reinforced with carbon fibers

Science.gov (United States)

El-Mokadem, Khaled Mounir

2001-10-01

Scope and method of study. The research started with preliminary tests and studies on the behavior and effect of carbon fibers in different water solutions and mortar/concrete mixes. The research work investigated the use of CF in the production of concrete pipes and prestressed concrete double-tee sections. The research then focused on studying the effect of using carbon fibers on the direct shear transfer of sand-lightweight reinforced concrete push-off specimens. Findings and conclusions. In general, adding carbon fibers to concrete improved its tensile characteristics but decreased its compressive strength. The decrease in compressive strength was due to the decrease in concrete density as fibers act as three-dimensional mesh that entrapped air. The decrease in compressive strength was also due to the increase in the total surface area of non-cementitious material in the concrete. Sand-lightweight reinforced concrete push-off specimens with carbon fibers had lower shear carrying capacity than those without carbon fibers for the same cement content in the concrete. Current building codes and specifications estimate the shear strength of concrete as a ratio of the compressive strength. If applying the same principals then the ratio of shear strength to compressive strength for concrete reinforced with carbon fibers is higher than that for concrete without carbon fibers.

Corrosion resistance and development length of steel reinforcement with cementitious coatings

Science.gov (United States)

Pei, Xiaofei

This research program focused on the corrosion resistance and development length of reinforcing steel coated with Cementitious Capillary Crystalline Waterproofing (CCCW) materials. The first part of this research program involved using the half-cell potential method to evaluate the corrosion resistance of CCCW coating materials. One hundred and two steel bars were embedded in concrete cylinders and monitored. In total, 64 steel reinforcing bars were coated with CCCW prior to embedment, 16 mortar cylinders were externally coated with CCCW, and 22 control (uncoated) samples were tested. All the samples were immersed in a 3.5% concentration chloride solution for a period of one year. Three coating types were studied: CCCW-B, CCCW-B+ C and CCCW-C+D. The test results showed that the CCCW coating materials delayed the corrosion activity to varying degrees. In particular, CCCW-C+D applied on the reinforcing steel surface dramatically delayed the corrosion activity when compared to the control samples. After being exposed to the chloride solution for a period of one year, no sign of corrosion was observed for the cylinders where the concrete surface was coated. The second part of this research evaluated the bond strength and development length of reinforcing steel coated with two types of CCCW coating materials (CCCW-B+C and CCCW-C+D) using a modified pull-out test method. A self-reacting inverted T-shaped beam was designed to avoid compression in the concrete surrounding the reinforcing steel. Steel reinforcing bars were embedded along the web portion of the T-beam with various embedded lengths and were staggered side by side. In total, six T-beams were fabricated and each beam contained 8 samples. Both short-term (7 days) and long-term (3 months) effects of water curing were evaluated. The reinforcing steel bars coated with CCCW-B+C demonstrated a higher bond strength than did samples coated with CCCW-C+D. However, the bond strengths of samples with coating materials

Physio-Microstructural Properties of Aerated Cement Slurry for Lightweight Structures

Science.gov (United States)

Salem, Talal; Hamadna, Sameer; Darsanasiri, A. G. N. D.; Soroushian, Parviz; Balchandra, Anagi; Al-Chaar, Ghassan

2018-01-01

Cementitious composites, including ferrocement and continuous fiber reinforced cement, are increasingly considered for building construction and repair. One alternative in processing of these composites is to infiltrate the reinforcement (continuous fibers or chicken mesh) with a flowable cementitious slurry. The relatively high density of cementitious binders, when compared with polymeric binders, are a setback in efforts to introduce cementitious composites as lower-cost, fire-resistant, and durable alternatives to polymer composites. Aeration of the slurry is an effective means of reducing the density of cementitious composites. This approach, however, compromises the mechanical properties of cementitious binders. An experimental program was undertaken in order to assess the potential for production of aerated slurry with a desired balance of density, mechanical performance, and barrier qualities. The potential for nondestructive monitoring of strength development in aerated cementitious slurry was also investigated. This research produced aerated slurries with densities as low as 0.9 g/cm3 with viable mechanical and barrier qualities for production of composites. The microstructure of these composites was also investigated. PMID:29649163

Structural behavior of lightweight bamboo reinforced concrete slab with EPS infill panel

Science.gov (United States)

Wibowo, Ari; Wijatmiko, Indradi; Nainggolan, Christin Remayanti

2017-09-01

Eco-friendly, green, and natural materials have become increasingly important issues in supporting sustainable development, for the substitution of nonrenewable materials such as steel. Bamboo has been considered in many studies to replace steel in reinforced concrete elements. Further investigation has been carried out to obtain lightweight and eco-friendly reinforced concrete slabs by using bamboo bars as reinforcement and recycled materials such as EPS (expanded polystyrene) as infill panel. The flexural loading test on full scale one-way slabs test has been conducted. The results showed that the flexural strength of specimens decreased marginally of about 6% but with the weight advantage of 27% less compared with those of steel rebar reinforced concrete slab with the same dimension. Two type shear-connectors comprising of concrete and bamboo studs were also investigated which showed that the bamboo stud provided better ductility compared to that of slab with concrete as shear connector. Overall, the reinforced concrete slab with bamboo reinforcement and EPS infill panel showed reasonably good performance compared to slabs with steel rebar.

Durability of low-pH cementitious materials based on OPC or CAC

International Nuclear Information System (INIS)

Garcia Calvo, J.L.; Sanchez, M.; Alonso, M.C.; Fernandez Luco, L.

2015-01-01

Low pH cementitious materials are considered to be used in underground repositories for high level waste but there are still some characteristics related to their long-term durability that must be analyzed in depth. In this sense, different shrinkage tests have been made using low-pH cement formulations based on Ordinary Portland Cement (OPC) or Calcium Aluminate Cement (CAC), on mortar and concrete specimens. The obtained results show that, regarding the autogenous shrinkage, low-pH cementitious materials show similar values than those observed in the reference samples. In fact, the main shrinkage problems in the low-pH materials are related with those based on OPC with high silica fume contents in drying conditions. Besides, as the use of reinforced concrete can be required in underground repositories, the susceptibility of reinforcements to corrosion when using low-pH cementitious materials based on OPC was analyzed, using two different reinforcements: carbon steel and galvanized steel. The lower pore solution pH of the low-pH OPC based materials generates the corrosion of the carbon steel reinforcement. However, when galvanized steels are used, any corrosion problem is detected regardless of the cement formulation. (authors)

Analysis of the mechanical resistance and porosity of a composite cement with EVA and reinforced with piacava fibers

International Nuclear Information System (INIS)

Silva, R.M.; Dominguez, D.S.; Alvim, R.C.; Iglesias, S.M.

2013-01-01

Nowadays, a lot of solid waste material is discarded into the environment. One of these residues is the EVA (Ethyl Vinyl Acetate) which has the footwear industry, as its main consumer. Studies are focused on the reusing of these materials, particularly in the civil construction, where is used as an aggregate in the production of light mortars. Due to the specific characteristics of lightweight concrete, is necessary to reinforce these materials. The palm Attalea Funifera Martius, known as piacava, may be an excellent alternative as a reinforcement element in light cement mixes. In this work, it's verified the mechanical strength of a composite lightweight cementitious with EVA and reinforced with Piacava fibers, also, the porosity of the new material was measured. To evaluate the mechanical properties of this new material was made mechanical tests and verified the importance of vegetal fibers as the material reinforcing. For the compound porosity evaluation, samples were studied using microcomputer tomography (μTC). With images processing techniques we identify and quantify the pores. The processing digital images through μTC showed up as a non-destructive method for efficient and acceptable results. (author)

Lightweight self-compacting concrete reinforced with fibres for slab rehabilitation

International Nuclear Information System (INIS)

Klein, N. S.; Fuente, A. de la; Aguado, A.; Maso, D.

2011-01-01

The slabs of some buildings in Barcelona are formed by unidirectional beams, with a ceramic arch in between, which are filled with broken pottery or construction waste. These structures often present problems such as displacement of the tiles arranged over it due to the lack of stiffness of the filling material. This supposes a risk to the user and could also cause durability problems. In order to rehabilitate it, a lightweight self-compacting concrete reinforced with fibres (HLACF) has been designed to be used as a filling material, improving the stiffness of the structure. This paper presents a structural analysis of a standard case and the results of an experimental campaign. The concrete showed a density of 1665 kg/m3, a slump flow of 605 mm and a compressive strength of 22.3 MPa, at 28 days. These results are in agreement with the requirements, overcoming common lightweight concrete segregation problems. (Author) 24 refs.

State-of-the-Art Report on Fiber-Reinforced Lightweight Aggregate Concrete Masonry

Directory of Open Access Journals (Sweden)

Saul Rico

2017-01-01

Full Text Available Masonry construction is the most widely used building method in the world. Concrete masonry is relatively low in cost due to the vast availability of aggregates used within the production process. These aggregate materials are not always reliable for structural use. One of the principal issues associated with masonry is the brittleness of the unit. When subject to seismic loads, the brittleness of the masonry magnifies. In regions with high seismic activity and unspecified building codes or standards, masonry housing has developed into a death trap for countless individuals. A common approach concerning the issue associated with the brittle characteristic of masonry is addition of steel reinforcement. However, this can be expensive, highly dependent on skillfulness of labor, and particularly dependent on the quality of available steel. A proposed solution presented in this investigation consists of introducing steel fibers to the lightweight aggregate concrete masonry mix. Previous investigations in the field of lightweight aggregate fiber-reinforced concrete have shown an increase in flexural strength, toughness, and ductility. The outcome of this research project provides invaluable data for the production of a ductile masonry unit capable of withstanding seismic loads for prolonged periods.

Load-carrying capacity of lightly reinforced, prefabricated walls of lightweight aggregate concrete with open structure

DEFF Research Database (Denmark)

Goltermann, Per

2009-01-01

The paper presents and evaluates the results of a coordinated testing of prefabricated, lightly reinforced walls of lightweight aggregate concrete with open structure. The coordinated testing covers all wall productions in Denmark and will therefore provide a representative assessment...

Elastic Composite, Reinforced Lightweight Concrete as a Type of Resilient Composite Systems

OpenAIRE

Esmaeili, Kamyar

2015-01-01

. A kind of "Elastic Composite, Reinforced Lightweight Concrete (ECRLC)" with the mentioned specifics is a type of "Resilient Composite Systems (RCS)" in which, contrary to the basic geometrical assumption of flexure theory in Solid Mechanics, "the strain changes in the beam height during bending" is typically "Non-linear". . Through employing this integrated structure, with significant high strain capability and modulus of resilience in bending, we could constructively achieve high bearing c...

Description of near-tip fracture processes in strain hardening cementitious composites using image-based analysis and the compact tension test

DEFF Research Database (Denmark)

Pereira, Eduardo B.; Fischer, Gregor; Barros, Joaquim A.O.

2013-01-01

The cracking mechanisms assume a key role in the composite behavior of Strain Hardening Cementitious Composites (SHCCs). Due to their importance, in previous studies the mechanical behavior of SHCC materials, as well as of other strain softening fiber reinforced cementitious composites......, was characterized under eccentric tensile loading using the Compact Tension Test (CTT). The present research further extends this investigation, with particular emphasis on cementitious composites reinforced with multiple types of fibers. The experimental tensile load-displacement results are discussed and compared...

High-flexibility, noncollapsing lightweight hose

Science.gov (United States)

Williams, D.A.

1993-04-20

A high-flexibility, noncollapsing, lightweight, large-bore, wire-reinforced hose is inside fiber-reinforced PVC tubing that is flexible, lightweight, and abrasion resistant. It provides a strong, kink- and collapse-free conduit for moving large quantities of dangerous fluids, e.g., removing radioactive waste water or processing chemicals.

Innovative Structural Materials and Sections with Strain Hardening Cementitious Composites

Science.gov (United States)

Dey, Vikram

The motivation of this work is based on development of new construction products with strain hardening cementitious composites (SHCC) geared towards sustainable residential applications. The proposed research has three main objectives: automation of existing manufacturing systems for SHCC laminates; multi-level characterization of mechanical properties of fiber, matrix, interface and composites phases using servo-hydraulic and digital image correlation techniques. Structural behavior of these systems were predicted using ductility based design procedures using classical laminate theory and structural mechanics. SHCC sections are made up of thin sections of matrix with Portland cement based binder and fine aggregates impregnating continuous one-dimensional fibers in individual or bundle form or two/three dimensional woven, bonded or knitted textiles. Traditional fiber reinforced concrete (FRC) use random dispersed chopped fibers in the matrix at a low volume fractions, typically 1-2% to avoid to avoid fiber agglomeration and balling. In conventional FRC, fracture localization occurs immediately after the first crack, resulting in only minor improvement in toughness and tensile strength. However in SHCC systems, distribution of cracking throughout the specimen is facilitated by the fiber bridging mechanism. Influence of material properties of yarn, composition, geometry and weave patterns of textile in the behavior of laminated SHCC skin composites were investigated. Contribution of the cementitious matrix in the early age and long-term performance of laminated composites was studied with supplementary cementitious materials such as fly ash, silica fume, and wollastonite. A closed form model with classical laminate theory and ply discount method, coupled with a damage evolution model was utilized to simulate the non-linear tensile response of these composite materials. A constitutive material model developed earlier in the group was utilized to characterize and

Low frequency electrical and magnetic methods for non-destructive analysis of fiber dispersion in fiber reinforced cementitious composites: an overview.

Science.gov (United States)

Faifer, Marco; Ferrara, Liberato; Ottoboni, Roberto; Toscani, Sergio

2013-01-21

Non-destructive analysis of fiber dispersion in structural elements made of Fiber Reinforced Concrete (FRC) and Fiber Reinforced Cementitious Composites (FRCCs) plays a significant role in the framework of quality control and performance prediction. In this paper, the research activity of the authors in the aforementioned field all over the last lustrum will be reviewed. A method based on the measurement of the inductance of a probe to be placed on the specimen will be presented and its progressive development will be described. Obtained correlation with actual fiber dispersion, as checked by means of destructive methods, as well as with the mechanical performance of the composite will also be presented, in an attempt to address the significance of the method from an engineering application perspective.

Self-Healing Capability of Fiber-Reinforced Cementitious Composites for Recovery of Watertightness and Mechanical Properties

Directory of Open Access Journals (Sweden)

Tomoya Nishiwaki

2014-03-01

Full Text Available Various types of fiber reinforced cementitious composites (FRCCs were experimentally studied to evaluate their self-healing capabilities regarding their watertightness and mechanical properties. Cracks were induced in the FRCC specimens during a tensile loading test, and the specimens were then immersed in static water for self-healing. By water permeability and reloading tests, it was determined that the FRCCs containing synthetic fiber and cracks of width within a certain range (<0.1 mm exhibited good self-healing capabilities regarding their watertightness. Particularly, the high polarity of the synthetic fiber (polyvinyl alcohol (PVA series and hybrid fiber reinforcing (polyethylene (PE and steel code (SC series showed high recovery ratio. Moreover, these series also showed high potential of self-healing of mechanical properties. It was confirmed that recovery of mechanical property could be obtained only in case when crack width was sufficiently narrow, both the visible surface cracks and the very fine cracks around the bridging of the SC fibers. Recovery of the bond strength by filling of the very fine cracks around the bridging fibers enhanced the recovery of the mechanical property.

Recycling of MSWI fly ash by means of cementitious double step cold bonding pelletization: Technological assessment for the production of lightweight artificial aggregates.

Science.gov (United States)

Colangelo, Francesco; Messina, Francesco; Cioffi, Raffaele

2015-12-15

In this work, an extensive study on the recycling of municipal solid waste incinerator fly ash by means of cold bonding pelletization is presented. The ash comes from an incineration plant equipped with rotary and stoker furnaces, in which municipal, hospital and industrial wastes are treated. Fly ash from waste incineration is classified as hazardous and cannot be utilized or even landfilled without prior treatment. The pelletization process uses cement, lime and coal fly ash as components of the binding systems. This process has been applied to several mixes in which the ash content has been varied from 50% (wt.%) up to a maximum of 70%. An innovative additional pelletization step with only cementitious binder has been performed in order to achieve satisfactory immobilization levels. The obtained lightweight porous aggregates are mostly suitable for recovery in the field of building materials with enhanced sustainability properties. Density, water absorption and crushing strength ranged from 1000 to 1600 kg/m(3), 7 to 16% and 1.3 to 6.2 MPa, respectively, and the second pelletization step increased stabilization efficiency. The feasibility of the process has been analyzed by testing also concrete specimens containing the artificial aggregates, resulting in lightweight concrete of average performance. Copyright © 2015 Elsevier B.V. All rights reserved.

Data on thermal conductivity, water vapour permeability and water absorption of a cementitious mortar containing end-of-waste plastic aggregates

OpenAIRE

Di Maio, Luciano; Coppola, Bartolomeo; Courard, Luc; Michel, Frédéric; Incarnato, Loredana; Scarfato, Paola

2018-01-01

The data presented in this article are related to the research article entitled “Hygro-thermal and durability properties of a lightweight mortar made with foamed plastic waste aggregates ” (Coppola et al., 2018). This article focuses the attention on thermal conductivity, water vapour permeability and water absorption of a lightweight cementitious mortar containing foamed end-of-waste plastic aggregates, produced via foam extrusion process. Thermal conductivity, water vapour permeability ...

Final Report - Assessment of Potential Phosphate Ion-Cementitious Materials Interactions

International Nuclear Information System (INIS)

Naus, Dan J.; Mattus, Catherine H.; Dole, Leslie Robert

2007-01-01

The objectives of this limited study were to: (1) review the potential for degradation of cementitious materials due to exposure to high concentrations of phosphate ions; (2) provide an improved understanding of any significant factors that may lead to a requirement to establish exposure limits for concrete structures exposed to soils or ground waters containing high levels of phosphate ions; (3) recommend, as appropriate, whether a limitation on phosphate ion concentration in soils or ground water is required to avoid degradation of concrete structures; and (4) provide a 'primer' on factors that can affect the durability of concrete materials and structures in nuclear power plants. An assessment of the potential effects of phosphate ions on cementitious materials was made through a review of the literature, contacts with concrete research personnel, and conduct of a 'bench-scale' laboratory investigation. Results of these activities indicate that: no harmful interactions occur between phosphates and cementitious materials unless phosphates are present in the form of phosphoric acid; phosphates have been incorporated into concrete as set retarders, and phosphate cements have been used for infrastructure repair; no standards or guidelines exist pertaining to applications of reinforced concrete structures in high-phosphate environments; interactions of phosphate ions and cementitious materials has not been a concern of the research community; and laboratory results indicate similar performance of specimens cured in phosphate solutions and those cured in a calcium hydroxide solution after exposure periods of up to eighteen months. Relative to the 'primer,' a separate NUREG report has been prepared that provides a review of pertinent factors that can affect the durability of nuclear power plant reinforced concrete structures

Final Report - Assessment of Potential Phosphate Ion-Cementitious Materials Interactions

Energy Technology Data Exchange (ETDEWEB)

Naus, Dan J [ORNL; Mattus, Catherine H [ORNL; Dole, Leslie Robert [ORNL

2007-06-01

The objectives of this limited study were to: (1) review the potential for degradation of cementitious materials due to exposure to high concentrations of phosphate ions; (2) provide an improved understanding of any significant factors that may lead to a requirement to establish exposure limits for concrete structures exposed to soils or ground waters containing high levels of phosphate ions; (3) recommend, as appropriate, whether a limitation on phosphate ion concentration in soils or ground water is required to avoid degradation of concrete structures; and (4) provide a "primer" on factors that can affect the durability of concrete materials and structures in nuclear power plants. An assessment of the potential effects of phosphate ions on cementitious materials was made through a review of the literature, contacts with concrete research personnel, and conduct of a "bench-scale" laboratory investigation. Results of these activities indicate that: no harmful interactions occur between phosphates and cementitious materials unless phosphates are present in the form of phosphoric acid; phosphates have been incorporated into concrete as set retarders, and phosphate cements have been used for infrastructure repair; no standards or guidelines exist pertaining to applications of reinforced concrete structures in high-phosphate environments; interactions of phosphate ions and cementitious materials has not been a concern of the research community; and laboratory results indicate similar performance of specimens cured in phosphate solutions and those cured in a calcium hydroxide solution after exposure periods of up to eighteen months. Relative to the "primer," a separate NUREG report has been prepared that provides a review of pertinent factors that can affect the durability of nuclear power plant reinforced concrete structures.

A fully general and adaptive inverse analysis method for cementitious materials

DEFF Research Database (Denmark)

Jepsen, Michael S.; Damkilde, Lars; Lövgren, Ingemar

2016-01-01

The paper presents an adaptive method for inverse determination of the tensile σ - w relationship, direct tensile strength and Young’s modulus of cementitious materials. The method facilitates an inverse analysis with a multi-linear σ - w function. Usually, simple bi- or tri-linear functions...... are applied when modeling the fracture mechanisms in cementitious materials, but the vast development of pseudo-strain hardening, fiber reinforced cementitious materials require inverse methods, capable of treating multi-linear σ - w functions. The proposed method is fully general in the sense that it relies...... of notched specimens and simulated data from a nonlinear hinge model. The paper shows that the results obtained by means of the proposed method is independent on the initial shape of the σ - w function and the initial guess of the tensile strength. The method provides very accurate fits, and the increased...

PENGARUH PENAMBAHAN SIKA GROUT PADA MORTAR SEBAGAI BAHAN GROUTING TERHADAP LEKATAN TULANGAN DALAM BETON DENGAN COPPER SLAG SEBAGAI CEMENTITIOUS

Directory of Open Access Journals (Sweden)

Mohammad Sulton

2012-09-01

Full Text Available Abstract: The Impact of Sika Grout Addition on Grouting Mortar Toward Concrete Reinforcement Stickness with Copper Slag as Cementitious. The aim of this research is to identify the impact of Sika Grout addition on grouting mortar toward concrete reinforcement stickness with copper slag as cementitious. The experiment result of this research shows that (1 the addition of Sika Grout 215 in grouting mortar can improve the reinforcement stickness; (2 the use of 100% Sika Grout 215 in grouting mortar produces maximum stickness; (3 the stickness of 100% Sika Grout 215 has 12.800 kg stronger (2,8% of improvement than those of using copper slag reinforcement (without grouting as 12.450 kg; (4 the use of less than 100% Sika Grout produces less stickness of no-grouting reinforcement; and (5 there is similar slip characteristic between  concrete reinforcement added with grouting and without grouting as 2,5 mm on outer part of the mortar.

Analysis of the mechanical resistance and porosity of a composite cement with EVA and reinforced with piacava fibers; Analise da resistencia mecanica e porosidade de um composito cimenticio leve com EVA e reforcado com fibras de piacava

Energy Technology Data Exchange (ETDEWEB)

Silva, R.M.; Dominguez, D.S.; Alvim, R.C.; Iglesias, S.M., E-mail: regilan@hotmail.com [Universidade Estadual de Santa Cruz (UESC), Ilheus, BA (Brazil)

2013-07-01

Nowadays, a lot of solid waste material is discarded into the environment. One of these residues is the EVA (Ethyl Vinyl Acetate) which has the footwear industry, as its main consumer. Studies are focused on the reusing of these materials, particularly in the civil construction, where is used as an aggregate in the production of light mortars. Due to the specific characteristics of lightweight concrete, is necessary to reinforce these materials. The palm Attalea Funifera Martius, known as piacava, may be an excellent alternative as a reinforcement element in light cement mixes. In this work, it's verified the mechanical strength of a composite lightweight cementitious with EVA and reinforced with Piacava fibers, also, the porosity of the new material was measured. To evaluate the mechanical properties of this new material was made mechanical tests and verified the importance of vegetal fibers as the material reinforcing. For the compound porosity evaluation, samples were studied using microcomputer tomography (μTC). With images processing techniques we identify and quantify the pores. The processing digital images through μTC showed up as a non-destructive method for efficient and acceptable results. (author)

A Review on the Use of Agriculture Waste Material as Lightweight Aggregate for Reinforced Concrete Structural Members

Directory of Open Access Journals (Sweden)

Kim Hung Mo

2014-01-01

Full Text Available The agriculture industry is one of the main industries in the Southeast Asia region due to its favourable conditions for plantations. In fact, Southeast Asia region is the world’s largest producer of palm oil and coconut. Nevertheless, vast plantation of these agriculture products leads to equally large amount of waste materials emanating from these industries. Previously, researchers have attempted to utilize the resulting waste materials such as oil palm shell, palm oil clinker, and coconut shell from these industries as lightweight aggregate to produce structural grade lightweight aggregate concrete. In order to promote the concept of using such concrete for actual structural applications, this paper reviews the use of such agriculture-based lightweight aggregate concrete in reinforced concrete structural members such as beam and slab, which were carried out by researchers in the past. The behaviour of the structural members under flexural, shear, and torsional load was also summarized. It is hoped that the knowledge attained from the paper will provide design engineers with better idea and proper application of design criteria for structural members using such agriculture waste as lightweight aggregate.

Development of Steel Fiber-Reinforced Expanded-Shale Lightweight Concrete with High Freeze-Thaw Resistance

Directory of Open Access Journals (Sweden)

Mingshuang Zhao

2018-01-01

Full Text Available For the popularized structural application, steel fiber-reinforced expanded-shale lightweight concrete (SFRELC with high freeze-thaw resistance was developed. The experimental study of this paper figured out the effects of air-entraining content, volume fraction of steel fibers, and fine aggregate type. Results showed that while the less change of mass loss rate was taken place for SFRELC after 300 freeze-thaw cycles, the relative dynamic modulus of elasticity and the relative flexural strength presented clear trends of freeze-thaw resistance of SFRELC. The compound effect of the air-entraining agent and the steel fibers was found to support the SFRELC with high freeze-thaw resistance, and the mechanisms were explored with the aid of the test results of water penetration of SFRELC. The beneficial effect was appeared from the replacement of lightweight sand with manufactured sand. Based on the test results, suggestions are given out for the optimal mix proportion of SFRELC to satisfy the durability requirement of freeze-thaw resistance.

LIGHT-WEIGHT LOAD-BEARING STRUCTURES REINFORCED BY CORE ELEMENTS MADE OF SEGMENTS AND A METHOD OF CASTING SUCH STRUCTURES

DEFF Research Database (Denmark)

2009-01-01

The invention relates to a light-weight load-bearing structure, reinforced by core elements (2) of a strong material constituting one or more compression or tension zones in the structure to be cast, which core (2) is surrounded by or adjacent to a material of less strength compared to the core (2......), where the core (2) is constructed from segments (1) of core elements (2) assembled by means of one or more prestressing elements (4). The invention further relates to a method of casting of light-weight load-bearing structures, reinforced by core elements (2) of a strong material constituting one...... or more compression or tension zones in the structure to be cast, which core (2) is surrounded by or adjacent to a material of less strength compared to the core (2), where the core (2) is constructed from segments (1) of core elements (2) assembled and hold together by means of one or more prestressing...

Bond slip and crack development in FRC and regular concrete specimens longitudinally reinforced with FRP or steel under tension loading

DEFF Research Database (Denmark)

Lárusson, Lárus Helgi; Fischer, Gregor

2012-01-01

tensile loading using high definition image analysis in two unique test setups. Two different types of cementitious materials, conventional concrete and highly ductile Engineered Cementitious Composite (ECC), and two types of reinforcement bars, regular steel and Glass Fiber Reinforcement Polymer (GFRP......The governing mechanism in the structural response of reinforced concrete members in tension is the interaction between structural reinforcement and the surrounding concrete matrix. The composite response and the mechanical integrations of reinforced cementitious members were investigated during......), were tested. It was found that the ductile ECC in contrast to regular brittle concrete decreases crack widths significantly which effectively results in decreased bond slip between the reinforcement and surrounding matrix. Furthermore the use of elastic GFRP in comparison to elastic/plastic steel...

Long Term Behaviour of Cementitious Materials in the Korean Repository Environment

International Nuclear Information System (INIS)

Park, J.-W.; Kim, C.-L.

2013-01-01

The safe management of radioactive waste is a national task required for sustainable generation of nuclear power and for energy self-reliance in Korea. After the selection of the final candidate site for low- and intermediate-level waste (LILW) disposal in Korea, a construction and operation license was issued for the Wolsong LILW Disposal Center (WLDC) for the first stage of disposal. Underground silo type disposal has been determined for the initial phase. The engineered barrier system of the disposal silo consists of waste packages, disposal containers, backfills, and a concrete lining. Main objective of our study in this IAEA-CRP is to investigate closure concepts and cementitious backfill materials for the closure of silos. For this purpose, characterisation of cementitious materials, development of silo closure concept, and evaluation of long-term behaviour of cementitious materials, including concrete degradation in repository environment, have been carried out. The overall implementation plan for the CRP comprises performance testing for the physic-chemical properties of cementitious materials, degradation modelling of concrete structures, comparisons of performance for silo closure options, radionuclide transport modelling (considering concrete degradation in repository conditions), and the implementation of an input parameter database and quality assurance for safety/performance assessment. In particular, the concrete degradation modelling study has been focused on the corrosion of reinforcement steel induced by chloride attack, which was of primary concern in the safety assessment of the WLDC. A series of electrochemical experiments were conducted to investigate the effect of dissolved oxygen, pH, and Cl on the corrosion rate of reinforcing steel in a concrete structure saturated with groundwater. Laboratory-scale experiments and a thermodynamic modelling were performed to understand the porosity change of cement pastes, which were prepared using

Multi-Scale CNT-Based Reinforcing Polymer Matrix Composites for Lightweight Structures

Science.gov (United States)

Eberly, Daniel; Ou, Runqing; Karcz, Adam; Skandan, Ganesh; Mather, Patrick; Rodriguez, Erika

2013-01-01

Reinforcing critical areas in carbon polymer matrix composites (PMCs), also known as fiber reinforced composites (FRCs), is advantageous for structural durability. Since carbon nanotubes (CNTs) have extremely high tensile strength, they can be used as a functional additive to enhance the mechanical properties of FRCs. However, CNTs are not readily dispersible in the polymer matrix, which leads to lower than theoretically predicted improvement in mechanical, thermal, and electrical properties of CNT composites. The inability to align CNTs in a polymer matrix is also a known issue. The feasibility of incorporating aligned CNTs into an FRC was demonstrated using a novel, yet commercially viable nanofiber approach, termed NRMs (nanofiber-reinforcing mats). The NRM concept of reinforcement allows for a convenient and safe means of incorporating CNTs into FRC structural components specifically where they are needed during the fabrication process. NRMs, fabricated through a novel and scalable process, were incorporated into FRC test panels using layup and vacuum bagging techniques, where alternating layers of the NRM and carbon prepreg were used to form the reinforced FRC structure. Control FRC test panel coupons were also fabricated in the same manner, but comprised of only carbon prepreg. The FRC coupons were machined to size and tested for flexural, tensile, and compression properties. This effort demonstrated that FRC structures can be fabricated using the NRM concept, with an increased average load at break during flexural testing versus that of the control. The NASA applications for the developed technologies are for lightweight structures for in-space and launch vehicles. In addition, the developed technologies would find use in NASA aerospace applications such as rockets, aircraft, aircraft/spacecraft propulsion systems, and supporting facilities. The reinforcing aspect of the technology will allow for more efficient joining of fiber composite parts, thus offering

Effect of Chloride on Tensile and Bending Capacities of Basalt FRP Mesh Reinforced Cementitious Thin Plates under Indoor and Marine Environments

Directory of Open Access Journals (Sweden)

Yan Xie

2016-01-01

Full Text Available This paper presented a durability experimental study for thin basalt fiber reinforced polymer (BFRP mesh reinforced cementitious plates under indoor and marine environment. The marine environment was simulated by wetting/drying cycles (wetting in salt water and drying in hot air. After 12 months of exposure, the effects of the chloride on the tensile and bending behaviors of the thin plate were investigated. In addition to the penetration of salt water, the chloride in the thin plate could be also from the sea sand since it is a component of the plate. Experimental results showed that the effect of the indoor exposure on the tensile capacity of the plate is not pronounced, while the marine exposure reduced the tensile capacity significantly. The bending capacity of the thin plates was remarkably reduced by both indoor and marine environmental exposure, in which the effect of the marine environment is more severe. The tensile capacity of the meshes extracted from the thin plates was tested, as well as the meshes immersed in salt solution for 30, 60, and 90 days. The test results confirmed that the chloride is the reason of the BFRP mesh deterioration. Moreover, as a comparison, the steel mesh reinforced thin plate was also tested and it has a similar durability performance.

REFERENCE CASES FOR USE IN THE CEMENTITIOUS BARRIERS PARTNERSHIP

Energy Technology Data Exchange (ETDEWEB)

Langton, C

2009-01-06

The Cementitious Barriers Project (CBP) is a multidisciplinary cross cutting project initiated by the US Department of Energy (DOE) to develop a reasonable and credible set of tools to improve understanding and prediction of the structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. The period of performance is >100 years for operating facilities and > 1000 years for waste management. The CBP has defined a set of reference cases to provide the following functions: (1) a common set of system configurations to illustrate the methods and tools developed by the CBP, (2) a common basis for evaluating methodology for uncertainty characterization, (3) a common set of cases to develop a complete set of parameter and changes in parameters as a function of time and changing conditions, and (4) a basis for experiments and model validation, and (5) a basis for improving conceptual models and reducing model uncertainties. These reference cases include the following two reference disposal units and a reference storage unit: (1) a cementitious low activity waste form in a reinforced concrete disposal vault, (2) a concrete vault containing a steel high-level waste tank filled with grout (closed high-level waste tank), and (3) a spent nuclear fuel basin during operation. Each case provides a different set of desired performance characteristics and interfaces between materials and with the environment. Examples of concretes, grout fills and a cementitious waste form are identified for the relevant reference case configurations.

Mechanical Properties and Shear Strengthening Capacity of High Volume Fly Ash-Cementitious Composite

Science.gov (United States)

Joseph, Aswin K.; Anand, K. B.

2018-02-01

This paper discusses development of Poly Vinyl Alcohol (PVA) fibre reinforced cementitious composites taking into account environmental sustainability. Composites with fly ash to cement ratios from 0 to 3 are investigated in this study. The mechanical properties of HVFA-cement composite are discussed in this paper at PVA fiber volume fraction maintained at 1% of total volume of composite. The optimum replacement of cement with fly ash was found to be 75%, i.e. fly ash to cement ratio (FA/C) of 3. The increase in fiber content from 1% to 2% showed better mechanical performance. A strain capacity of 2.38% was obtained for FA/C ratio of 3 with 2% volume fraction of fiber. With the objective of evaluating the performance of cementitious composites as a strengthening material in reinforced concrete beams, the beams deficient in shear capacity were strengthened with optimal mix having 2% volume fraction of fiber as the strengthening material and tested under four-point load. The reinforced concrete beams designed as shear deficient were loaded to failure and retrofitted with the composite in order to assess the efficiency as a repair material under shear.

The Importance of Superplastizer Dosage in the Mix Design of Lightweight Aggregate Concrete Reinforced With Plypropylene Fiber

Directory of Open Access Journals (Sweden)

Shafigh Payam

2016-01-01

Full Text Available This paper reports the results of a study conducted to investigate the effect of superplasticizer (SP dosage on the slump, density, compressive strength and splitting tensile strength under different curing conditions of a lightweight aggregate concrete reinforced with polypropylene (PP fiber. The lightweight aggregate used in this study was oil palm shell, which is an agricultural solid waste, originating from the palm oil industry. The results indicated that an increase in superplasticizer increased the workability, however, all the mechanical properties declined significantly. The reduction in the 28-day compressive and splitting tensile strengths was about 14. This study showed that although additional SP can improve the workability of the concrete, it may have a negative effect on the other properties of concrete. Therefore, the SP dosage in concrete mixtures containing PP fiber should be limited to a certain amount.

Study on reinforced lightweight coconut shell concrete beam behavior under flexure

International Nuclear Information System (INIS)

Gunasekaran, K.; Annadurai, R.; Kumar, P.S.

2013-01-01

Highlights: ► Use of coconut shell as aggregate in concrete. ► Behavior of coconut shell concrete under flexure. ► SEM images of cement, sand, coconut shell and coconut shell aggregate concrete. ► Coconut shell hollow blocks and precast slabs are used in practice. - Abstract: Coconut shell has been used as coarse aggregate in the production of concrete. The flexural behavior of reinforced concrete beam made with coconut shell is analyzed and compared with the normal control concrete. Twelve beams, six with coconut shell concrete and six with normal control concrete, were fabricated and tested. This study includes the moment capacity, deflection, cracking, ductility, corresponding strains in both compression and tension, and end rotation. It was found that the flexural behavior of coconut shell concrete is comparable to that of other lightweight concretes. The results of concrete compression strain and steel tension strain showed that coconut shell concrete is able to achieve its full strain capacity under flexural loadings. Under serviceability condition, deflection and cracking characteristics of coconut shell concrete are comparable with control concrete. However, the failure zones of coconut shell concrete were larger than for control concrete beams. The end rotations of the coconut shell concrete beams just prior to failure values are comparable to other lightweight concretes. Coconut shell concrete was used to produce hollow blocks and precast slab in 2007 and they are being subjected to some practical loading till today without any problems such as deflection, bending, cracks, and damages for the past five years

Effect of total cementitious content on shear strength of high-volume fly ash concrete beams

International Nuclear Information System (INIS)

Arezoumandi, Mahdi; Volz, Jeffery S.; Ortega, Carlos A.; Myers, John J.

2013-01-01

Highlights: ► Existing design standards conservatively predicted the capacity of the HVFAC beams. ► In general, the HVFAC beams exceeded the code predicted shear strengths. ► The cementitious content did not have effect on the shear behavior of the HVFAC beams. - Abstract: The production of portland cement – the key ingredient in concrete – generates a significant amount of carbon dioxide. However, due to its incredible versatility, availability, and relatively low cost, concrete is the most consumed manmade material on the planet. One method of reducing concrete’s contribution to greenhouse gas emissions is the use of fly ash to replace a significant amount of the cement. This paper compares two experimental studies that were conducted to investigate the shear strength of full-scale beams constructed with high-volume fly ash concrete (HVFAC) – concrete with at least 50% of the cement replaced with fly ash. The primary difference between the two studies involved the amount of cementitious material, with one mix having a relatively high total cementitious content (502 kg/m 3 ) and the other mix having a relatively low total cementitious content (337 kg/m 3 ). Both mixes utilized a 70% replacement of portland cement with a Class C fly ash. Each of these experimental programs consisted of eight beams (six without shear reinforcing and two with shear reinforcing in the form of stirrups) with three different longitudinal reinforcement ratios. The beams were tested under a simply supported four-point loading condition. The experimental shear strengths of the beams were compared with both the shear provisions of selected standards (US, Australia, Canada, Europe, and Japan) and a shear database of conventional concrete (CC) specimens. Furthermore, statistical data analyses (both parametric and nonparametric) were performed to evaluate whether or not there is any statistically significant difference between the shear strength of both mixes. Results of these

Effect of Fiber Reinforcement on the Response of Structural Members

DEFF Research Database (Denmark)

Fischer, Gregor; Li, Victor

2007-01-01

This paper describes a series of investigations on the effect of fiber reinforcement on the response of structural members in direct tension and flexure under reversed cyclic loading conditions. The design approach of the fiber reinforced cementitious composite is based on fracture mechanics...... principles, which will be described in the first part of the paper along with an introduction of the relevant material properties of the resulting engineered cementitious composite (ECC). This class of composites is characterized by strain hardening and multiple cracking properties in uniaxial tension...... and an ultimate tensile strain capacity on the order of several percent. Subsequently, the synergistic effects of composite deformation mechanisms in the ECC and structural members subjected to large shear reversals are identified. Beneficial effects observed in the reinforced ECC structural members as compared...

Surface decoration of short-cut polyimide fibers with multi-walled carbon nanotubes and their application for reinforcement of lightweight PC/ABS composites

Science.gov (United States)

Zhang, Le; Han, Enlin; Wu, Yulun; Wang, Xiaodong; Wu, Dezhen

2018-06-01

The surface decoration of short-cut polyimide (PI) fibers with multi-walled carbon nanotubes (MWCNTs) was performed by fabricating a polydopamine (PDA) coating layer on the fiber surface and then immobilizing MWCNTs onto the coating layer via covalent bonding. This successful surface decoration was confirmed by scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared microscopy and static water contact angle. The application of the surface-decorated PI fibers as reinforcing fibers for reinforcement of polycarbonate (PC)/acrylonitrile-butadiene-styrene copolymer (ABS) alloy was investigated, which indicated that the MWCNTs-decorated PI fibers not only could effectively reinforce the PC/ABS alloy but also generated a significant lightweighting effect on the resulting composites. The maximum mechanical properties were achieved for the composites at a fiber content of 20 wt.% and a fiber length of 3 mm. This significant reinforcement effect is attributed to the enhancement of interaction bonding strength between the fibers and matrix as a result of the surface decoration of PI fibers with MWCNTs. The morphological investigation suggested that fiber rupture was the major energy dissipation mechanism in the tensile and impact failures, whereas fiber debonding and pullout were partly involved in the fracture energy dissipation. In addition, the presence of surface-decorated PI fibers slightly enhanced the thermal stability and load bearing capability of composites. This work can provide a type of high-performance lightweight composite material for automobile and aviation industries.

Mechanical Properties of Steel Fiber Reinforced all Lightweight Aggregate Concrete

Science.gov (United States)

Yang, Y. M.; Li, J. Y.; Zhen, Y.; Nie, Y. N.; Dong, W. L.

2018-05-01

In order to study the basic mechanical properties and failure characteristics of all lightweight aggregate concrete with different volume of steel fiber (0%, 1%, 2%), shale ceramsite is used as light coarse aggregate. The shale sand is made of light fine aggregate and mixed with different volume of steel fiber, and the mix proportion design of all lightweight aggregate concrete is carried out. The cubic compressive strength, axial compressive strength, flexural strength, splitting strength and modulus of elasticity of steel fiber all lightweight aggregate concrete were studied. Test results show that the incorporation of steel fiber can restrict the cracking of concrete, improve crack resistance; at the same time, it shows good plastic deformation ability and failure morphology. It lays a theoretical foundation for further research on the application of all lightweight aggregate concrete in structural systems.

Flexural strengthening of reinforced lightweight polystyrene aggregate concrete beams with near-surface mounted GFRP bars

Energy Technology Data Exchange (ETDEWEB)

Tang, W.C.; Balendran, R.V.; Nadeem, A.; Leung, H.Y. [City University of Hong Kong (China). Department of Building and Construction

2006-10-15

Application of near-surface mounted (NSM) fibre reinforced polymer (FRP) bars is emerging as a promising technology for increasing flexural and shear strength of deficient reinforced concrete (RC) members. In order for this technique to perform effectively, the structural behaviour of RC elements strengthened with NSM FRP bars needs to be fully characterized. This paper focuses on the characterization of flexural behaviour of RC members strengthened with NSM glass-FRP bars. Totally, 10 beams were tested using symmetrical two-point loads test. The parameters examined under the beam tests were type of concretes (lightweight polystyrene aggregate concrete and normal concrete), type of reinforcing bars (GFRP and steel), and type of adhesives. Flexural performance of the tested beams including modes of failure, moment-deflection response and ultimate moment capacity are presented and discussed in this paper. Results of this investigation showed that beams with NSM GFRP bars showed a reduction in ultimate deflection and an improvement in flexural stiffness and bending capacity, depending on the PA content of the beams. In general, beams strengthened with NSM GFRP bars overall showed a significant increase in ultimate moment ranging from 23% to 53% over the corresponding beams without NSM GFRP bars. The influence of epoxy type was found conspicuously dominated the moment-deflection response up to the peak moment. Besides, the ultimate moment of concrete beams reinforced with GFRP bars could be predicted satisfactorily using the equation provided in ACI 318-95 Building Code. (author)

Use of flexible engineered cementitious composite in buildings

International Nuclear Information System (INIS)

Khitab, A.; Nadeem, M.; Hussain, S.

2011-01-01

This article describes the applications and benefits of a recently developed smart building material namely Engineered cementitious composite (ECC), also known as flexible or bendable concrete. Conventional concretes have a strain capacity of only 0.1 percent and are highly brittle and rigid. This lack of bend ability is a major cause of failure under strain and has been a pushing factor in the development of an elegant material which is capable to exhibit an enhanced flexibility. An ECC has a strain capacity of more than 3 percent and thus acts more like a ductile metal rather than like a brittle glass. The aim of this paper is to highlight a probable success of ECC in terms of industrial and commercial use in Pakistan. With the introduction of flexible concrete in building technology, it is likely to have safer and more durable construction. The material is expected to display reduced detrimental impacts on the natural environment. A bendable concrete is composed of all the ingredients of a traditional concrete minus coarse aggregates or crushed stones and is reinforced with micro mechanically designed polymer fibers. The mechanism of action of the micro-polymeric fibers in concrete has also been emphasized. The principles of mix designs of the mortar incorporating fibers to make an ECC have also been explained. It has also been mentioned in detail as how this technology can be used to enhance the flexibility of some modern concrete types like flowing concrete, self-compacting concrete, and lightweight concrete. ECC is a green construction material. The possible benefits like environment friendliness, cost effectiveness, and durability have been also been elucidated in the paper. (author)

Lightweight self-compacting concrete reinforced with fibres for slab rehabilitation

Directory of Open Access Journals (Sweden)

Klein, N. S.

2011-06-01

Full Text Available The slabs of some buildings in Barcelona are formed by unidirectional beams, with a ceramic arch in between, which are filled with broken pottery or construction waste. These structures often present problems such as displacement of the tiles arranged over it due to the lack of stiffness of the filling material. This supposes a risk to the user and could also cause durability problems. In order to rehabilitate it, a lightweight self-compacting concrete reinforced with fibres (HLACF has been designed to be used as a filling material, improving the stiffness of the structure. This paper presents a structural analysis of a standard case and the results of an experimental campaign. The concrete showed a density of 1665 kg/m³, a slump flow of 605 mm and a compressive strength of 22.3 MPa, at 28 days. These results are in agreement with the requirements, overcoming common lightweight concrete segregation problems.

Los forjados de ciertos edificios del ensanche de Barcelona, formados por viguetas unidireccionales con un revoltón de cerámica entre ellas y un relleno posterior (material cerámico y residuos de construcción, suelen presentar problemas de movimientos y despegues de las baldosas situadas en la parte superior, con el consiguiente riesgo para el usuario, aparte de los problemas de durabilidad asociados. Para rehabilitar esas estructuras se ha diseñado un hormigón ligero autocompactante con fibras (HLACF, como relleno de modo que mejore la rigidez a la estructura. El artículo presenta el análisis estructural de una solución tipo así como los resultados de una campaña experimental realizada. Como resultado se obtiene un hormigón de densidad de 1.665 kg/m³, escurrimiento de 605 mm y resistencia a compresión de 22,3 MPa, a los 28 días, que cumple con los requisitos y significa superar problemas de segregación previsibles para este tipo de hormigones.

Development of Flexible Link Slabs using Ductile Fiber Reinforced Concrete

DEFF Research Database (Denmark)

Lárusson, Lárus Helgi

Civil engineering structures with large dimensions, such as multi-span bridges, overpasses and viaducts, are typically equipped with mechanical expansion joints. These joints allow the individual spans of the structure to undergo unrestrained deformations due to thermal expansions and load......-deformation response and crack development of representative sections of the reinforced composites, and iv) detailing, designing and testing of large scale prefabricated link slab elements. In addition, an application of ductile Engineered Cementitious Composite (ECC) in prefabricated floor panels is presented...... crack widths and crack spacing measurements are obtained, which can characterize the tensile behavior of ECC. In chapter 3 on interfacial bond, the bond slip behavior and crack development, between the reinforcement and surrounding cementitious matrix is investigated in a unique test setup with special...

Effect of Multiwalled Carbon Nanotubes on the Mechanical Properties of Carbon Fiber-Reinforced Polyamide-6/Polypropylene Composites for Lightweight Automotive Parts

Directory of Open Access Journals (Sweden)

Huu-Duc Nguyen-Tran

2018-03-01

Full Text Available The development of lightweight automotive parts is an important issue for improving the efficiency of vehicles. Polymer composites have been widely applied to reduce weight and improve mechanical properties by mixing polymers with carbon fibers, glass fibers, and carbon nanotubes. Polypropylene (PP has been added to carbon fiber-reinforced nylon-6 (CF/PA6 composite to achieve further weight reduction and water resistance. However, the mechanical properties were reduced by the addition of PP. In this research, multiwalled carbon nanotubes (CNTs were added to compensate for the reduced mechanical properties experienced when adding PP. Tensile testing and bending tests were carried out to evaluate the mechanical properties. A small amount of CNTs improved the mechanical properties of carbon fiber-reinforced PA6/PP composites. For example, the density of CF/PA6 was reduced from 1.214 to 1.131 g/cm3 (6.8% by adding 30 wt % PP, and the tensile strength of 30 wt % PP composite was improved from 168 to 173 MPa (3.0% by adding 0.5 wt % CNTs with small increase of density (1.135 g/cm3. The developed composite will be widely used for lightweight automotive parts with improved mechanical properties.

Lightweight self-compacting concrete reinforced with fibres for slab rehabilitation; Hormigon ligero autocompactante con fibras para rehabilitacion de forjados

Energy Technology Data Exchange (ETDEWEB)

Klein, N. S.; Fuente, A. de la; Aguado, A.; Maso, D.

2011-07-01

The slabs of some buildings in Barcelona are formed by unidirectional beams, with a ceramic arch in between, which are filled with broken pottery or construction waste. These structures often present problems such as displacement of the tiles arranged over it due to the lack of stiffness of the filling material. This supposes a risk to the user and could also cause durability problems. In order to rehabilitate it, a lightweight self-compacting concrete reinforced with fibres (HLACF) has been designed to be used as a filling material, improving the stiffness of the structure. This paper presents a structural analysis of a standard case and the results of an experimental campaign. The concrete showed a density of 1665 kg/m3, a slump flow of 605 mm and a compressive strength of 22.3 MPa, at 28 days. These results are in agreement with the requirements, overcoming common lightweight concrete segregation problems. (Author) 24 refs.

Innovation of Iron Reinforcing Column of Partical From Frame of Light Steel

Science.gov (United States)

Ramadhan, M. R.; Faslih, A.; Umar, M. Z.

2018-05-01

Almost half of houses in Indonesia are using lightweight steel roof truss today. The phenomenon in the field is that lightweight steel roof truss can blend with mortar mixture. Thus this phenomenon is captured for later applied dynamically, creatively, and innovatively with new idioms such as reinforcement for columns. This research aims to investigate the comparison of the way of making and the price of the materials between the column material made of the light steel and the column material made of the iron reinforcement which is the most efficient. Type of research is qualitative with a comparative causal approach. This research is divided into several stages, namely; Literature study, column creation, and validation. This study concluds that the manufacture of column material from reinforcement is more efficient, than the lightweight steel column material. The reinforcement column material is more efficient because of the more effective way of making and the price of the working materials more economical than the lightweight steel column material. Lightweight steel columns can be used for public housing on condition made by experienced craftsmen to make the process faster, and the dimensions of lightweight steel can be scaled down to make it more economical.

Long-term performance of GFRP reinforcement : technical report.

Science.gov (United States)

2009-12-01

Significant research has been performed on glass fiber-reinforced polymer (GFRP) concrete reinforcement. : This research has shown that GFRP reinforcement exhibits high strengths, is lightweight, can decrease time of : construction, and is corrosion ...

Design of rapid hardening engineered cementitious composites for sustainable construction

Science.gov (United States)

Marushchak, Uliana; Sanytsky, Myroslav; Sydor, Nazar

2017-12-01

This paper deals with design of environmentally friendly Rapid Hardening Engineered Cementitious Composite (RHECC) nanomodified with ultrafine mineral additives, polycarboxylate ether based superplasticizer, calcium hydrosilicate nanoparticles and dispersal reinforced by fibers. The incremental coefficient of surface activity was proposed in order to estimation of ultrafine supplementary materials (fly ash, methakaolin, microsilica) efficiency. A characterization of RHECC's compressive and flexural properties at different ages is reported in this paper. Early compressive strength of ECC is 45-50 MPa, standard strength - 84-95 MPa and parameter Rc2/Rc28 - 65-70%. The microstructure of the cement matrix and RHECC was investigated. The use of ultrafine mineral supplementary materials provides reinforcement of structure on micro- and nanoscale level (cementing matrix) due to formation of sub-microreinforcing hydrate phase as AFt- and C-S-H phases in unclinker part of cement matrix, resulting in the phenomena of "self-reinforcement" on the microstructure level. Designed RHECC may be regarded as lower brittle since the crack resistance coefficient is higher comparison to conventional fine grain concrete.

Experimental research on reinforced lightweight plugging composites.

Directory of Open Access Journals (Sweden)

BEKBAEV Arstan Abaevich

2017-08-01

Full Text Available Practical aspects of the well construction show that the use of conventional cementing materials do not always provide the necessary level of quality of well casing when the requirements to resources conservation are enhanced. This is true for such complex geological conditions as the alternation of beds with different formation pressures, low fracturing pressure gradients, drilling with ERD tc. The main problems in well casing under these conditions are the losses of cement slurries, low cement top, low-quality formation isolation, and as the result of this – the emergence of cross-flows. The high quality of well casing will be provided only by means of safe contact between cement stone and limiting surfaces (casing and rock, therefore to use expansion materials for cementing is a well-recognized method. Thus, it is obvious that their application does not give positive results for intervals with a thick filter cake or intervals with cavities, i.e. where space for expansion is greater than the magnitude of the expansion. At the same time it is very challenging to create high-quality cement in formations with abnormally low formation pressure or low fracture gradient. The solution of this problem is the use of lightweight cements, which scarcely expand while hardening. This is due to the fact that lightweight cement slurries are generally obtained by increasing the content of grouting fluid in the solution, resulting in increase of the distance between the crystal hydrates – hardening products, that leads to decrease of crystallization pressure of expansion agents on the space frame of the cement stone]. Moreover, such works as secondary reservoir developing (perforation, well completion and fracturing operations create high dynamic load on the cement stone, which leads to its destruction. The stone can be completely destroyed, that often causes premature flooding of wells and incurring additional costs. In this regard, it is necessary to

Nanofibrillated cellulose (NFC) as a potential reinforcement for high performance cement mortar composites

OpenAIRE

Ardanuy Raso, Mònica; Claramunt Blanes, Josep; Arévalo Peces, Raquel; Parés Sabatés, Ferran; Aracri, Elisabetta; Vidal Lluciá, Teresa

2012-01-01

In this work, nanofibrillated cellulose (NFC) has been evaluated as a potential reinforcement for cement mortar composites. Two types of vegetable fibres with different composition and properties (cellulose content and microfibrillar angle), sisal, and cotton linters pulps, were initially characterized in order to assess their reinforcement capability. Sisal pulp was found to be most suitable as reinforcement for their brittle cementitious matrix. Nanofibrillated cellulose was produced by th...

Lightweight Thermally Stable Multi-Meter Aperture Submillimeter Reflectors, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Future astrophysics missions will require lightweight, thermally stable, submillimeter reflectors in sizes of 4m and greater. To date, graphite fiber reinforced...

Impact of carbonation on water transport properties of cementitious materials

International Nuclear Information System (INIS)

Auroy, Martin

2014-01-01

Carbonation is a very well-known cementitious materials pathology. It is the major cause of reinforced concrete structures degradation. It leads to rebar corrosion and consequent concrete cover cracking. In the framework of radioactive waste management, cement-based materials used as building materials for structures or containers would be simultaneously submitted to drying and atmospheric carbonation. Although scientific literature regarding carbonating is vast, it is clearly lacking information about the influence of carbonation on water transport properties. This work then aimed at studying and understanding the change in water transport properties induced by carbonation. Simultaneously, the representativeness of accelerated carbonation (in the laboratory) was also studied. (author) [fr

The Cementitious Barriers Partnership (CBP) Software Toolbox Capabilities In Assessing The Degradation Of Cementitious Barriers

Energy Technology Data Exchange (ETDEWEB)

Flach, G. P. [Savannah River Site (SRS), Aiken, SC (United States); Burns, H. H. [Savannah River Site (SRS), Aiken, SC (United States); Langton, C. [Savannah River Site (SRS), Aiken, SC (United States); Smith, F. G. III [Savannah River Site (SRS), Aiken, SC (United States); Brown, K. G. [Vanderbilt University, Nashville, TN (United States); Kosson, D. S. [Vanderbilt University, Nashville, TN (United States); Garrabrants, A. C. [Vanderbilt University, Nashville, TN (United States); Sarkar, S. [Vanderbilt University, Nashville, TN (United States); van der Sloot, H. [Hans van der Sloot Consultancy (The Netherlands); Meeussen, J. C.L. [Nuclear Research and Consultancy Group, Petten (The Netherlands); Samson, E. [SIMCO Technologies Inc. , 1400, boul. du Parc - Technologique , Suite 203, Quebec (Canada); Mallick, P. [United States Department of Energy, 1000 Independence Ave. SW , Washington, DC (United States); Suttora, L. [United States Department of Energy, 1000 Independence Ave. SW , Washington, DC (United States); Esh, D. W. [U .S. Nuclear Regulatory Commission , Washington, DC (United States); Fuhrmann, M. J. [U .S. Nuclear Regulatory Commission , Washington, DC (United States); Philip, J. [U .S. Nuclear Regulatory Commission , Washington, DC (United States)

2013-01-11

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy (US DOE) Office of Tank Waste and Nuclear Materials Management. The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that help improve understanding and predictions of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program have been used to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to 100 years and longer for operating facilities and longer than 1000 years for waste disposal. The CBP Software Toolbox has produced tangible benefits to the DOE Performance Assessment (PA) community. A review of prior DOE PAs has provided a list of potential opportunities for improving cementitious barrier performance predictions through the use of the CBP software tools. These opportunities include: 1) impact of atmospheric exposure to concrete and grout before closure, such as accelerated slag and Tc-99 oxidation, 2) prediction of changes in Kd/mobility as a function of time that result from changing pH and redox conditions, 3) concrete degradation from rebar corrosion due to carbonation, 4) early age cracking from drying and/or thermal shrinkage and 5) degradation due to sulfate attack. The CBP has already had opportunity to provide near-term, tangible support to ongoing DOE-EM PAs such as the Savannah River Saltstone Disposal Facility (SDF) by providing a sulfate attack analysis that predicts the extent and damage that sulfate ingress will have on the concrete vaults over extended time (i.e., > 1000 years). This analysis is one of the many technical opportunities in cementitious barrier performance that can be addressed by the DOE-EM sponsored CBP software

Research on optimizing components of microfine high-performance composite cementitious materials

International Nuclear Information System (INIS)

Hu Shuguang; Guan Xuemao; Ding Qingjun

2002-01-01

The relationship between material components and mechanical properties was studied in terms of composite material principles and orthogonal experimental design. Moreover, the microstructure of microfine high-performance composite cementitious material (MHPCC) paste was investigated by means of scanning electron microscopy (SEM) methods. The results showed that the composite material consisting of blast furnace slag (BFS), gypsum (G 2 ) and expansive agent (EA) could obviously improve the strength of the cementitious material containing 40% fly ash (FA). Although microfine cement (MC) was merely 45% percent of the MHPCC, the compressive strength of MHPCC paste was higher than that of neat MC paste. BFS played an important role in MHPCC. The optimum-added quantity of BFS was 15%. The needle-shaped ettringite obtained from the EA reacting with Ca(OH) 2 forms a three-dimensional network structure, which not only improved the early strength of MHPCC paste but also increased its late strength. The reason was that the network structure, which was similar to a fiber-reinforced composite, was formed in the late period of hydration with the progress of hydration and the deposition of hydration products into the network structure

Lightweight self-compacting concrete with light expanded clay aggregate (LECA

Directory of Open Access Journals (Sweden)

Heiza Khaled

2018-01-01

Full Text Available Lightweight concretes have been successfully applied in building constructions for many years due to their favorable material properties, particularly their low specific weight in connection with a high strength, a high capability of thermal insulation and a high durability. The development leading to lightweight self-compacting concrete (LWSCC represents an important advanced step within the recent years. This concrete combines the favorable properties of a lightweight concrete with those of a self-compacting concrete. Research work is aimed on development of (LWSCC with the use of light aggregates “Light expanded clay aggregate (LECA”. In this research, first by specific gravity factor method, twenty different mix designs of (LWSCC were cast and tested to find out the values of slump flow, J-ring , V-funnel and 28 day compressive strength. Based on the results obtained, the best mix design was selected for further investigation. This paper also focuses on studying the effect of changing the reinforcement ratio on reinforced two way slabs when the dimensions were kept constant.

Concrete with supplementary cementitious materials

OpenAIRE

Jensen, Ole M; Kovler, Konstantin; De Belie, Nele

2016-01-01

This volume contains the proceedings of the MSSCE 2016 conference segment on “Concrete with Supplementary Cementitious Materials” (SCM). The conference segment is organized by the RILEM technical committee TC 238-SCM: Hydration and microstructure of concrete with supplementary cementitious materials. TC 238-SCM started activities in 2011 and has about 50 members from all over the world. The main objective of the committee is to support the increasing utilisation of hydraulic...

Mechanical interaction between concrete and structural reinforcement in the tension stiffening process

DEFF Research Database (Denmark)

Lárusson, Lárus Helgi; Fischer, Gregor; Jönsson, Jeppe

2011-01-01

as Engineered Cementitious Composite (ECC), have been combined with steel and glass fiber reinforced polymer (GFRP) reinforcement to contrast the effects of brittle and ductile cement matrices as well as elastic/plastic and elastic reinforcement on the tension stiffening process. Particular focus...... investigated using an image-based deformation measurement and analysis system. This allowed for detailed view of surface deformations and the implications on the resulting response of the member in tension. In this study, conventional concrete and a ductile, strain hardening cement composite, known...

Review of Japanese recommendations on design and construction of different classes of fiber reinforced concrete and application examples

DEFF Research Database (Denmark)

Uchida, Yuichi; Fischer, Gregor; Hishiki, Yoshihiro

2008-01-01

The development of concrete and cementitious composites with fiber reinforcement to improve the tensile load-deformation behavior has resulted in three distinct classes of materials. These include conventional Fiber Reinforced Concrete (FRC) with tension softening response, High Performance Fiber...... Reinforced Cement Composites (HPFRCC) with strain hardening and multiple cracking behavior, and Ultra High-strength Fiber Reinforced concrete (UFC) with increased tensile strength. The recommendations on the design, production, and application of these classes of fiber reinforced concrete have been...

Multi-physics corrosion modeling for sustainability assessment of steel reinforced high performance fiber reinforced cementitious composites

DEFF Research Database (Denmark)

Lepech, M.; Michel, Alexander; Geiker, Mette

2016-01-01

and widespread depassivation, are the mechanism behind experimental results of HPFRCC steel corrosion studies found in the literature. Such results provide an indication of the fundamental mechanisms by which steel reinforced HPFRCC materials may be more durable than traditional reinforced concrete and other......Using a newly developed multi-physics transport, corrosion, and cracking model, which models these phenomena as a coupled physiochemical processes, the role of HPFRCC crack control and formation in regulating steel reinforcement corrosion is investigated. This model describes transport of water...... and chemical species, the electric potential distribution in the HPFRCC, the electrochemical propagation of steel corrosion, and the role of microcracks in the HPFRCC material. Numerical results show that the reduction in anode and cathode size on the reinforcing steel surface, due to multiple crack formation...

The Cementitious Barriers Partnership (CBP) Software Toolbox Capabilities in Assessing the Degradation of Cementitious Barriers - 13487

Energy Technology Data Exchange (ETDEWEB)

Flach, G.P.; Burns, H.H.; Langton, C.; Smith, F.G. III [Savannah River National Laboratory, Savannah River Site, Aiken SC 29808 (United States); Brown, K.G.; Kosson, D.S.; Garrabrants, A.C.; Sarkar, S. [Vanderbilt University, Nashville, TN (United States); Van der Sloot, H. [Hans Van der Sloot Consultancy (Netherlands); Meeussen, J.C.L. [Nuclear Research and Consultancy Group, Petten (Netherlands); Samson, E. [SIMCO Technologies Inc., 1400, boul. du Parc-Technologique, Suite 203, Quebec (Canada); Mallick, P.; Suttora, L. [United States Department of Energy, 1000 Independence Ave. SW, Washington, DC (United States); Esh, D.W.; Fuhrmann, M.J.; Philip, J. [U.S. Nuclear Regulatory Commission, Washington, DC (United States)

2013-07-01

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy (US DOE) Office of Tank Waste and Nuclear Materials Management. The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that help improve understanding and predictions of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program have been used to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to 100 years and longer for operating facilities and longer than 1000 years for waste disposal. The CBP Software Toolbox has produced tangible benefits to the DOE Performance Assessment (PA) community. A review of prior DOE PAs has provided a list of potential opportunities for improving cementitious barrier performance predictions through the use of the CBP software tools. These opportunities include: 1) impact of atmospheric exposure to concrete and grout before closure, such as accelerated slag and Tc-99 oxidation, 2) prediction of changes in K{sub d}/mobility as a function of time that result from changing pH and redox conditions, 3) concrete degradation from rebar corrosion due to carbonation, 4) early age cracking from drying and/or thermal shrinkage and 5) degradation due to sulfate attack. The CBP has already had opportunity to provide near-term, tangible support to ongoing DOE-EM PAs such as the Savannah River Saltstone Disposal Facility (SDF) by providing a sulfate attack analysis that predicts the extent and damage that sulfate ingress will have on the concrete vaults over extended time (i.e., > 1000 years). This analysis is one of the many technical opportunities in cementitious barrier performance that can be addressed by the DOE-EM sponsored CBP

Effect of different fibers on mechanical properties and ductility of alkali-activated slag cementitious material

Science.gov (United States)

Zhu, J.; Zheng, W. Z.; Qin, C. Z.; Xu, Z. Z.; Wu, Y. Q.

2018-01-01

The effect of different fibers on mechanical properties and ductility of alkali-activated slag cementitious material (AASCM) is studied. The research contents include: fiber type (plant fiber, polypropylene fiber), fiber content, mechanical property index, tensile stress-strain relationship curve, treating time. The test results showed that the compressive strength of two fibers reinforced AASCM was about 90 ~ 110MPa, and the tensile strength was about 3 ~ 5MPa. The reinforcement effect of polypropylene fiber is superior to that of plant fiber, and the mechanical properties of polypropylene fiber reinforced AASCM are superior to those of plant fiber, According to the comparison of SEM pictures, the plant fiber and polypropylene fiber are both closely bound with the matrix, and the transition zones are complete and close. Thus, it is proved that plant fiber and polypropylene fiber delay the crack extension and enhance the ductility of AASCM.

Chemical evolution of cementitious materials

International Nuclear Information System (INIS)

Lothenbach, Barbara; Wieland, Erich

2012-01-01

Barbara Lothenback of EMPA, Switzerland gave an overview of the status of thermodynamic modelling for cementitious systems. Thermodynamic modelling of cementitious systems has been greatly facilitated in recent years by the development of more sophisticated geochemical software, of solid solution models for various cement phases, and by the collection of thermodynamic data for minerals relevant to cementitious systems over a wide range of temperature (0 to 100 deg. C). Based on these developments, thermodynamic modelling, coupled with kinetic equations that describe the dissolution of clinker as a function of time, can be used to: - Quantify the liquid and solid phase compositions of ordinary Portland cement and blended cements during the hydration process. - Evaluate compositional changes that occur in cementitious materials due to the use of various aggregates and other mineral additives (e.g. silica fume and blast furnace slag). - Predict degradation of cement in contact with the repository environment. Discussion of the paper included: What is our understanding of where aluminium resides in low-pH cements and what is our ability to model the behaviour of aluminium in these systems? The location of aluminium in low-pH cements depends on the overall Ca/Si ratio of the system and on the pH, but some aluminium enters the CSH gel as a CASH gel phase. The Swiss disposal programme is currently conducting some experiments to investigate this topic

Steel fiber reinforced concrete

International Nuclear Information System (INIS)

Baloch, S.U.

2005-01-01

Steel-Fiber Reinforced Concrete is constructed by adding short fibers of small cross-sectional size .to the fresh concrete. These fibers reinforce the concrete in all directions, as they are randomly oriented. The improved mechanical properties of concrete include ductility, impact-resistance, compressive, tensile and flexural strength and abrasion-resistance. These uniqlte properties of the fiber- reinforcement can be exploited to great advantage in concrete structural members containing both conventional bar-reinforcement and steel fibers. The improvements in mechanical properties of cementitious materials resulting from steel-fiber reinforcement depend on the type, geometry, volume fraction and material-properties of fibers, the matrix mix proportions and the fiber-matrix interfacial bond characteristics. Effects of steel fibers on the mechanical properties of concrete have been investigated in this paper through a comprehensive testing-programme, by varying the fiber volume fraction and the aspect-ratio (Lid) of fibers. Significant improvements are observed in compressive, tensile, flexural strength and impact-resistance of concrete, accompanied by marked improvement in ductility. optimum fiber-volume fraction and aspect-ratio of steel fibers is identified. Test results are analyzed in details and relevant conclusions drawn. The research is finally concluded with future research needs. (author)

Disassembly Properties of Cementitious Finish Joints Using an Induction Heating Method

Science.gov (United States)

Ahn, Jaecheol; Noguchi, Takafumi; Kitagaki, Ryoma

2015-01-01

Efficient maintenance and upgrading of a building during its lifecycle are difficult because a cementitious finish uses materials and parts with low disassembly properties. Additionally, the reuse and recycling processes during building demolition also present numerous problems from the perspective of environmental technology. In this study, an induction heating (IH) method was used to disassemble cementitious finish joints, which are widely used to join building members and materials. The IH rapidly and selectively heated and weakened these joints. The temperature elevation characteristics of the cementitious joint materials were measured as a function of several resistor types, including wire meshes and punching metals, which are usually used for cementitious finishing. The disassembly properties were evaluated through various tests using conductive resistors in cementitious joints such as mortar. When steel fiber, punching metal, and wire mesh were used as conductive resistors, the cementitious modifiers could be weakened within 30 s. Cementitious joints with conductive resistors also showed complete disassembly with little residual bond strength.

Mechano-Physical Properties and Microstructure of Carbon Nanotube Reinforced Cement Paste after Thermal Load.

Science.gov (United States)

Szeląg, Maciej

2017-09-11

The article presents the results obtained in the course of a study on the use of carbon nanotubes (CNTs) for the modification of a cement matrix. Carbon nanotubes were introduced into a cement paste in the form of an aqueous dispersion in the presence of a surfactant (SDS-sodium dodecyl sulfate), which was sonicated. The selected physical and mechanical parameters were examined, and the correlations between these parameters were determined. An analysis of the local microstructure of the modified cement pastes has been carried out using scanning electron microscope (SEM) and X-ray microanalysis (EDS). In addition, the effect of carbon nanotubes on the change in characteristics of the cementitious material exposed to the sudden, short-term thermal load, was determined. The obtained material was characterized by a much lower density than a traditional cement matrix because the phenomenon of foaming occurred. The material was also characterized by reduced durability, higher shrinkage, and higher resistance to the effect of elevated temperature. Further research on the carbon nanotube reinforced cement paste, with SDS, may contribute to the development of a modified cement binder for the production of a lightweight or an aerated concrete.

Mechano-Physical Properties and Microstructure of Carbon Nanotube Reinforced Cement Paste after Thermal Load

Science.gov (United States)

2017-01-01

The article presents the results obtained in the course of a study on the use of carbon nanotubes (CNTs) for the modification of a cement matrix. Carbon nanotubes were introduced into a cement paste in the form of an aqueous dispersion in the presence of a surfactant (SDS—sodium dodecyl sulfate), which was sonicated. The selected physical and mechanical parameters were examined, and the correlations between these parameters were determined. An analysis of the local microstructure of the modified cement pastes has been carried out using scanning electron microscope (SEM) and X-ray microanalysis (EDS). In addition, the effect of carbon nanotubes on the change in characteristics of the cementitious material exposed to the sudden, short-term thermal load, was determined. The obtained material was characterized by a much lower density than a traditional cement matrix because the phenomenon of foaming occurred. The material was also characterized by reduced durability, higher shrinkage, and higher resistance to the effect of elevated temperature. Further research on the carbon nanotube reinforced cement paste, with SDS, may contribute to the development of a modified cement binder for the production of a lightweight or an aerated concrete. PMID:28891976

Corrosion aspects of steel radioactive waste containers in cementitious materials

International Nuclear Information System (INIS)

Smart, Nick

2012-01-01

Nick Smart from Serco, UK, gave an overview of the effects of cementitious materials on the corrosion of steel during storage and disposal of various low- and intermediate-level radioactive wastes. Steel containers are often used as an overpack for the containment of radioactive wastes and are routinely stored in an open atmosphere. Since this is an aerobic and typically humid environment, the steel containers can start to corrode whilst in storage. Steel containers often come into contact with cementitious materials (e.g. grout encapsulants, backfill). An extensive account of different steel container designs and of steel corrosion mechanisms was provided. Steel corrosion rates under conditions buffered by cementitious materials have been evaluated experimentally. The main conclusion was that the cementitious environment generally facilitates the passivation of steel materials. Several general and localised corrosion mechanisms need to be considered when evaluating the performance of steel containers in cementitious environments, and environmental thresholds can be defined and used with this aim. In addition, the consequences of the generation of gaseous hydrogen by the corrosion of carbon steel under anoxic conditions must be taken into account. Discussion of the paper included: Is crevice corrosion really significant in cementitious systems? Crevice corrosion is unlikely in the cementitious backfill considered because it will tend to neutralise any acidic conditions in the crevice. What is the role of microbially-induced corrosion (MIC) in cementitious systems? Microbes are likely to be present in a disposal facility but their effect on corrosion is uncertain

Design of rapid hardening engineered cementitious composites for sustainable construction

Directory of Open Access Journals (Sweden)

Marushchak Uliana

2017-12-01

Full Text Available This paper deals with design of environmentally friendly Rapid Hardening Engineered Cementitious Composite (RHECC nanomodified with ultrafine mineral additives, polycarboxylate ether based superplasticizer, calcium hydrosilicate nanoparticles and dispersal reinforced by fibers. The incremental coefficient of surface activity was proposed in order to estimation of ultrafine supplementary materials (fly ash, methakaolin, microsilica efficiency. A characterization of RHECC’s compressive and flexural properties at different ages is reported in this paper. Early compressive strength of ECC is 45-50 MPa, standard strength – 84-95 MPa and parameter Rc2/Rc28 – 65–70%. The microstructure of the cement matrix and RHECC was investigated. The use of ultrafine mineral supplementary materials provides reinforcement of structure on micro- and nanoscale level (cementing matrix due to formation of sub-microreinforcing hydrate phase as AFt- and C-S-H phases in unclinker part of cement matrix, resulting in the phenomena of “self-reinforcement” on the microstructure level. Designed RHECC may be regarded as lower brittle since the crack resistance coefficient is higher comparison to conventional fine grain concrete.

OCRWM Science and Technology Program Cementitious Materials Technologies

International Nuclear Information System (INIS)

DOE

2004-01-01

This potential project will develop and test cost effective cementitious materials for construction of Yucca Mountain (YM) inverts, drift liners, and bulkheads. These high silica cementitious materials will be designed to buffer the pH and Eh of the groundwater, to slow corrosion of waste packages (WP), and to retard radionuclide migration. While being compatible with YM repository systems, these materials are expected to be less expensive to produce, and as strong, and more durable than ordinary Portland Cement (OPC). Therefore, building out the repository with these cementitious materials may significantly reduce these costs and reduce uncertainty in short-( 10,000 yr) repository performance. Both laboratory development and natural analog studies are anticipated using a unique combination of expertise at ORNL, UT, UC Berkeley, and Minatom to develop and test high-silica hydraulic, cementitious binders for use at YM. The major tasks of this project are to (1) formulate and make candidate cementitious materials using high-silica hydraulic hinders, (2) measure the physical and chemical properties of these materials, (3) expose combinations of these materials and WP materials to static and flowing YM groundwater at temperatures consistent with the expected repository conditions, (4) examine specimens of both the cementitious materials and WP materials periodically for chemical and mineralogical changes to determine reaction mechanisms and kinetics, and (5) predict the long-term performance of the material by thermodynamic and transport modeling and by comparisons with natural analogs

Non-cementitious compositions comprising vaterite and methods thereof

Science.gov (United States)

Devenney, Martin; Fernandez, Miguel; Morgan, Samuel O.

2015-09-15

Non-cementitious compositions and products are provided. The compositions of the invention include a carbonate additive comprising vaterite such as reactive vaterite. Additional aspects of the invention include methods of making and using the non-cementitious compositions and products.

Review of durability of cementitious engineered barriers in repository environments

International Nuclear Information System (INIS)

Parrott, L.J.; Lawrence, C.D.

1992-01-01

This report is concerned with the durability of cementitious engineered barriers in a repository for low and intermediate level nuclear waste. Following the introduction the second section of the review identifies the environmental conditions associated with a deep, hard rock repository for ILW and LLW that are relevant to the durability of cementitious barriers. Section three examines the microstructure and macrostructure of cementitious materials and considers the physical and chemical processes of radionuclide immobilization. Potential repository applications and compositions of cementitious materials are reviewed in Section four. The main analysis of durability is dealt with in Section five. The different types of cementitious barrier are considered separately and their most probable modes of degradation are analysed. Concluding remarks that highlight critical technical matters are given in Section six. (author)

Influence of site curing on bond properties of reinforced lightweight ...

African Journals Online (AJOL)

... the requirements for structural lightweight concrete. The developed compressive strength and pull-out strength under both site curing conditions were relatively lower than full water curing condition but still were higher than minimum requirement as per standard. Journal of Civil Engineering Research and Practice Vol.

Entombment Using Cementitious Materials: Design Considerations and International Experience

Energy Technology Data Exchange (ETDEWEB)

Seitz, Roger Ray

2002-08-01

Cementitious materials have physical and chemical properties that are well suited for the requirements of radioactive waste management. Namely, the materials have low permeability and durability that is consistent with the time frame required for short-lived radionuclides to decay. Furthermore, cementitious materials can provide a long-term chemical environment that substantially reduces the mobility of some long-lived radionuclides of concern for decommissioning (e.g., C-14, Ni-63, Ni-59). Because of these properties, cementitious materials are common in low-level radioactive waste disposal facilities throughout the world and are an attractive option for entombment of nuclear facilities. This paper describes design considerations for cementitious barriers in the context of performance over time frames of a few hundreds of years (directed toward short-lived radionuclides) and time frames of thousands of years (directed towards longer-lived radionuclides). The emphasis is on providing an overview of concepts for entombment that take advantage of the properties of cementitious materials and experience from the design of low-level radioactive waste disposal facilities. A few examples of the previous use of cementitious materials for entombment of decommissioned nuclear facilities and proposals for the use in future decommissioning of nuclear reactors in a few countries are also included to provide global perspective.

Entombment Using Cementitious Materials: Design Considerations and International Experience

Energy Technology Data Exchange (ETDEWEB)

Seitz, R.R.

2002-05-15

Cementitious materials have physical and chemical properties that are well suited for the requirements of radioactive waste management. Namely, the materials have low permeability and durability that is consistent with the time frame required for short-lived radionuclides to decay. Furthermore, cementitious materials can provide a long-term chemical environment that substantially reduces the mobility of some long-lived radionuclides of concern for decommissioning (e.g., C-14, Ni-63, Ni-59). Because of these properties, cementitious materials are common in low-level radioactive waste disposal facilities throughout the world and are an attractive option for entombment of nuclear facilities. This paper describes design considerations for cementitious barriers in the context of performance over time frames of a few hundreds of years (directed toward short-lived radionuclides) and time frames of thousands of years (directed towards longer-lived radionuclides). The emphasis is on providing a n overview of concepts for entombment that take advantage of the properties of cementitious materials and experience from the design of low-level radioactive waste disposal facilities. A few examples of the previous use of cementitious materials for entombment of decommissioned nuclear facilities and proposals for the use in future decommissioning of nuclear reactors in a few countries are also included to provide global perspective.

Entombment Using Cementitious Materials: Design Considerations and International Experience

International Nuclear Information System (INIS)

Seitz, R.R.

2002-01-01

Cementitious materials have physical and chemical properties that are well suited for the requirements of radioactive waste management. Namely, the materials have low permeability and durability that is consistent with the time frame required for short-lived radionuclides to decay. Furthermore, cementitious materials can provide a long-term chemical environment that substantially reduces the mobility of some long-lived radionuclides of concern for decommissioning (e.g., C-14, Ni-63, Ni-59). Because of these properties, cementitious materials are common in low-level radioactive waste disposal facilities throughout the world and are an attractive option for entombment of nuclear facilities. This paper describes design considerations for cementitious barriers in the context of performance over time frames of a few hundreds of years (directed toward short-lived radionuclides) and time frames of thousands of years (directed towards longer-lived radionuclides). The emphasis is on providing a n overview of concepts for entombment that take advantage of the properties of cementitious materials and experience from the design of low-level radioactive waste disposal facilities. A few examples of the previous use of cementitious materials for entombment of decommissioned nuclear facilities and proposals for the use in future decommissioning of nuclear reactors in a few countries are also included to provide global perspective

On the Interaction between Superabsorbent Hydrogels and Cementitious Materials

Science.gov (United States)

Farzanian, Khashayar

Autogenous shrinkage induced cracking is a major concern in high performance concretes (HPC), which are produced with low water to cement ratios. Internal curing to maintain high relative humidity in HPC with the use of an internal water reservoir has proven effective in mitigating autogenous shrinkage in HPC. Superabsorbent polymers (SAP) or hydrogels have received increasing attention as an internal curing agent in recent years. A key advantage of SAP is its versatility in size distribution and absorption/desorption characteristics, which allow it to be adapted to specific mix designs. Understanding the behavior of superabsorbent hydrogels in cementitious materials is critical for accurate design of internal curing. The primary goal of this study is to fundamentally understand the interaction between superabsorbent hydrogels and cementitious materials. In the first step, the effect of chemical and mechanical conditions on the absorption of hydrogels is investigated. In the second step, the desorption of hydrogels in contact with porous cementitious materials is examined to aid in understanding the mechanisms of water release from superabsorbent hydrogels (SAP) into cementitious materials. The dependence of hydrogel desorption on the microstructure of cementitious materials and relative humidity is studied. It is shown that the capillary forces developed at the interface between the hydrogel and cementitious materials increased the desorption of the hydrogels. The size of hydrogels is shown to influence desorption, beyond the known size dependence of bulk diffusion, through debonding from the cementitious matrix, thereby decreasing the effect of the Laplace pressure on desorption. In the third step, the desorption of hydrogels synthesized with varied chemical compositions in cementitious materials are investigated. The absorption, chemical structure and mechanical response of hydrogels swollen in a cement mixture are studied. The effect of the capillary forces on

Microbiological activities in a shallow-ground repository with cementitious wasteform

International Nuclear Information System (INIS)

Varlakova, G.A.; Dyakonova, A.T.; Netrusov, A.I.; Ojovan, M.I.

2012-01-01

Cementitious wasteform with immobilised nuclear power plant operational radioactive waste disposed in a near surface testing repository for about 20 years have been analysed for microbiological activities. Clean cultures were selected from the main metabolic groups expected within repository environment e.g. anaerobic de-nitrifying, fermenting, sulphur-reducing, iron-reducing, and oxidizing, thio-bacterium and mushrooms. Microbiological species were identified within cementitious wasteform, in the clayey soil near the wasteform and in the contacting water. The most populated medium was the soil with microbial populations Bacillus, Pseudomonas and Micrococcus, and densities of populations up to 3.6*10 5 colony/g. Microbial populations of generic type Bacillus, Pseudomonas, Rhodococcus, Alcaligenes, Micrococcus, Mycobacterium, and Arthrobacter were identified within cementitious wasteform. Populations of Arthrobacter, Pseudomonas, Alcaligenes, Rhodococcus, Bacillus and Flavobacterium were identified in the water samples contacting the cementitious wasteform. Microbiological species identified are potential destructors of cementitious wasteform and containers. (authors)

Experimental study on mix proportion of fiber reinforced cementitious composites

Science.gov (United States)

Jia, Yi; Zhao, Renda; Liao, Ping; Li, Fuhai; Yuan, Yuan; Zhou, Shuang

2017-10-01

To study the mechanical property of fiber reinforced cementations composites influenced by the fiber length, quartz sand diameter, matrix of water cement ratio, volume fraction of fiber and magnesium acrylate solution. Several 40×40×160 mm standard test specimens, "8" specimens and long "8" specimens and 21 groups of fiber concrete specimens were fabricated. The flexural, compressive and uniaxial tensile strength were tested by using the bending resistance, compression resistance and electronic universal testing machine. The results show that flexural and compressive strength of fiber reinforced cementations composites increases along with the increase of quartz sand diameter, with the growth of the PVA fiber length increases; When the water-binder ratio is 0.25 and powder-binder ratio is 0.3, the PVA fiber content is 1.5% of the mass of cementations materials, there is a phenomenon of strain hardening; The addition of magnesium acrylate solution reduces the tensile strength of PVA fiber reinforced cementations composites, the tensile strength of the specimens in the curing age of 7d is decreased by about 21% and the specimens in curing age of 28d is decreased by more than 50%.

Application of trilinear softening functions based on a cohesive crack approach to the simulation of the fracture behaviour of fibre reinforced cementitious materials.

Science.gov (United States)

Enfedaque, A.; Alberti, M. G.; Gálvez, J. C.

2017-09-01

The relevance of fibre reinforced cementitious materials (FRC) has increased due to the appearance of regulations that establish the requirements needed to take into account the contribution of the fibres in the structural design. However, in order to exploit the properties of such materials it is a key aspect being able to simulate their behaviour under fracture conditions. Considering a cohesive crack approach, several authors have studied the suitability of using several softening functions. However, none of these functions can be directly applied to FRC. The present contribution analyses the suitability of multilinear softening functions in order to obtain simulation results of fracture tests of a wide variety of FRC. The implementation of multilinear softening functions has been successfully performed by means of a material user subroutine in a commercial finite element code obtaining accurate results in a wide variety of FRC. Such softening functions were capable of simulating a ductile unloading behaviour as well as a rapid unloading followed by a reloading and afterwards a slow unloading. Moreover, the implementation performed has been proven as versatile, robust and efficient from a numerical point of view.

Microfibres and hydrogels to promote autogenous healing in cementitious materials

OpenAIRE

Snoeck, Didier; Dubruel, Peter; De Belie, Nele

2013-01-01

Cementitious materials are sensitive to crack formation and it would be beneficial if the material could stop the crack propagation, repair the damage and reach again the original liquid-tightness and/or strength. Therefore, a cementitious material with synthetic microfibres and superabsorbent polymers (SAPs) is proposed. Upon crack formation, the microfibres will become active and due to the bridging action, they will stop the opening of a crack, forcing the cementitious material to crack so...

3D-printing of lightweight cellular composites.

Science.gov (United States)

Compton, Brett G; Lewis, Jennifer A

2014-09-10

A new epoxy-based ink is reported, which enables 3D printing of lightweight cellular composites with controlled alignment of multiscale, high-aspectratio fiber reinforcement to create hierarchical structures inspired by balsa wood. Young's modulus values up to 10 times higher than existing commercially available 3D-printed polymers are attainable, while comparable strength values are maintained. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Static and cyclic performance of cementitious composites reinforced with glass-fibres

International Nuclear Information System (INIS)

Arabi, N.

2018-01-01

This paper concerns an experimental study of the influence of short glass-fibres randomly oriented of a reinforced cement-based composite on the mechanical behaviour. The matrix material parameters used are: cement/sand ratio and water/cement ratio fixed at 0.5; the glass-fibre content (0%, 0.5%, 1.0%, 1.5%, 2% and 2.5%) and fibre lengths (3, 6 and 12 mm). Composites mechanical characterisation under static behaviour at flexural and compression tests, shows that the reinforcement effect is beneficial only in flexural case. A synergy (matrix-reinforcement) was observed when fibre length of 12 mm is used with application rate of 2% in flexural. The fatigue behaviour determined by Wöhler plots (stress-number of cycles to rupture), derived from experimental results; showed a large results dispersion which is attributed to many causes initiating this damage. The cyclic tests illustrate brittle character of these materials; even with low-amplitude cycles of loading no adaptation of these materials can be reported. [es

Micro- and macroscale coefficients of friction of cementitious materials

International Nuclear Information System (INIS)

Lomboy, Gilson; Sundararajan, Sriram; Wang, Kejin

2013-01-01

Millions of metric tons of cementitious materials are produced, transported and used in construction each year. The ease or difficulty of handling cementitious materials is greatly influenced by the material friction properties. In the present study, the coefficients of friction of cementitious materials were measured at the microscale and macroscale. The materials tested were commercially-available Portland cement, Class C fly ash, and ground granulated blast furnace slag. At the microscale, the coefficient of friction was determined from the interaction forces between cementitious particles using an Atomic Force Microscope. At the macroscale, the coefficient of friction was determined from stresses on bulk cementitious materials under direct shear. The study indicated that the microscale coefficient of friction ranged from 0.020 to 0.059, and the macroscale coefficient of friction ranged from 0.56 to 0.75. The fly ash studied had the highest microscale coefficient of friction and the lowest macroscale coefficient of friction. -- Highlights: •Microscale (interparticle) coefficient of friction (COF) was determined with AFM. •Macroscale (bulk) COF was measured under direct shear. •Fly ash had the highest microscale COF and the lowest macroscale COF. •Portland cement against GGBFS had the lowest microscale COF. •Portland cement against Portland cement had the highest macroscale COF

Lack of diffuseness in wave propagation in lightweight joist-floors

DEFF Research Database (Denmark)

Brunskog, Jonas; Chung, Hyuck

2007-01-01

. The structures under consideration are rib-reinforced plate structures. These may be a lightweight floor/joist structure in a building or hull of a ship. The diffuseness or rather the lack of diffuseness, in such 'ribbed-plate' structures is examined. The amount of power transported at an angle is calculated...

Characterization and modeling of fiber reinforced concrete for structural applications in beams and plates

DEFF Research Database (Denmark)

Paegle, Ieva

(i.e., stirrups) is investigated in detail using digital image correlation (DIC) measurement technique. The use of steel fibers to replace traditional shear reinforcement is not without precedent in current reinforced concrete design codes. However, more detailed information is provided......Fiber reinforced concrete (FRC) with discrete, short and randomly distributed fibers can be specified and designed for structural applications in flexural members. In certain cases, fibers are used as the only reinforcement, while in other cases fibers are used in combination with a reduced amount...... are considered in structural design, the work presented in this thesis analyzes in detail many commonly used test methods on three types of FRC, including Polypropylene Fiber Reinforced Concrete (PP-FRC), Polyvinyl Alcohol Fiber Reinforced Concrete called Engineered Cementitious Composite (ECC) and Steel Fiber...

Topology Optimization of Lightweight Lattice Structural Composites Inspired by Cuttlefish Bone

Science.gov (United States)

Hu, Zhong; Gadipudi, Varun Kumar; Salem, David R.

2018-03-01

Lattice structural composites are of great interest to various industries where lightweight multifunctionality is important, especially aerospace. However, strong coupling among the composition, microstructure, porous topology, and fabrication of such materials impedes conventional trial-and-error experimental development. In this work, a discontinuous carbon fiber reinforced polymer matrix composite was adopted for structural design. A reliable and robust design approach for developing lightweight multifunctional lattice structural composites was proposed, inspired by biomimetics and based on topology optimization. Three-dimensional periodic lattice blocks were initially designed, inspired by the cuttlefish bone microstructure. The topologies of the three-dimensional periodic blocks were further optimized by computer modeling, and the mechanical properties of the topology optimized lightweight lattice structures were characterized by computer modeling. The lattice structures with optimal performance were identified.

Modeling of Cementitious Representative Volume Element with Additives

Science.gov (United States)

Shahzamanian, M. M.; Basirun, W. J.

CEMHYD3D has been employed to simulate the representative volume element (RVE) of cementitious systems (Type I cement) containing fly ash (Class F) through a voxel-based finite element analysis (FEA) approach. Three-dimensional microstructures composed of voxels are generated for a heterogeneous cementitious material consisting of various constituent phases. The primary focus is to simulate a cementitious RVE containing fly ash and to present the homogenized macromechanical properties obtained from its analysis. Simple kinematic uniform boundary conditions as well as periodic boundary conditions were imposed on the RVE to obtain the principal and shear moduli. Our current work considers the effect of fly ash percentage on the elastic properties based on the mass and volume replacements. RVEs with lengths of 50, 100 and 200μm at different degrees of hydration are generated, and the elastic properties are modeled and simulated. In general, the elastic properties of a cementitious RVE with fly ash replacement for cement based on mass and volume differ from each other. Moreover, the finite element (FE) mesh density effect is studied. Results indicate that mechanical properties decrease with increasing mesh density.

Graphite coated PVA fibers as the reinforcement for cementitious composites

Science.gov (United States)

Zhang, Yunhua; Zhang, Zhipeng; Liu, Zhichao

2018-02-01

A new preconditioning method was developed to PVA fibers as the reinforcement in cement-based materials. Virgin PVA fibers exhibits limited adhesion to graphite powders due to the presence of oil spots on the surface. Mixing PVA fibers with a moderately concentrated KMnO4-H2SO4 solution can efficiently remove the oil spots by oxidation without creating extra precipitate (MnO2) associated with the reduction reaction. This enhances the coating of graphite powders onto fiber surface and improves the mechanical properties of PVA fiber reinforced concrete (PVA-FRC). Graphite powders yields better fiber distribution in the matrix and reduces the fiber-matrix bonding, which is beneficial in uniformly distributing the stress among embedded fibers and creating steady generation and propagation of tight microcracks. This is evidenced by the significantly enhanced strain hardening behavior and improved flexural strength and toughness.

Cementitious backfill in mining

Energy Technology Data Exchange (ETDEWEB)

Taute, A; Spice, J; Wingrove, A C [Van Niekerk, Kleyn Edwards (South Africa)

1993-03-01

This article describes the need for increased usage of backfill material in mining and presents some of the considerations for use of cemented materials. Laboratory test results obtained using a variety of cementitious binders and mine tailings are presented. 3 figs., 1 tab.

Static properties and impact resistance of a green Ultra-High Performance Hybrid Fibre Reinforced Concrete (UHPHFRC) : experiments and modeling

NARCIS (Netherlands)

Yu, R.; Spiesz, P.R.; Brouwers, H.J.H.

2014-01-01

This paper addresses the static properties and impact resistance of a "green" Ultra-High Performance Hybrid Fibre Reinforced Concrete (UHPHFRC). The design of concrete mixtures aims to achieve a densely compacted cementitious matrix, employing the modified Andreasen & Andersen particle packing

Ultrasonic assessment of early age property development in hydrating cementitious materials

Science.gov (United States)

Wang, Xiaojun

The internal structure (microstructure) of cementitious materials, such as cement paste, mortar and concrete, evolves over time because of cement hydration. The microstructure of the cementitious phase plays a very important role in determining the strength, the mechanical properties and the long-term durability of cementitious materials. Therefore any understanding of the strength gain and the long-term durability of cementitious materials requires a proper assessment of the microstructure of its cementitious phase. Current methods for evaluating the microstructure of the cement are invasive and primarily laboratory-based. These methods are not conducive for studying the pore structure changes in the first few hours after casting since the changes in microstructure occur on a time scale that is an order of magnitude faster than the time required for sample preparation. The primary objective of the research presented in this thesis is to contribute towards advancing the current state-of-the-art in assessing the microstructure of cementitious systems. An ultrasonic wave reflection technique which allows for real-time assessment of the porosity and the elastic modulus of cementitious materials is developed. The test procedure for monitoring changes in the amplitude of horizontally polarized ultrasonic shear waves from the surface of hydrating cement paste is presented. A theoretical framework based on a poro-elastic idealization of the hydrating cementitious material is developed for interpreting the ultrasonic reflection data. The poro-elastic representation of hydrating cementitious material is shown to provide simultaneous, realistic estimates of porosity and shear modulus for hydrating cement paste and mortar through setting and early strength gain. The porosity predicted by the poro-elastic representation is identical to the capillary water content within the cement paste predicted by Powers' model. The shear modulus of the poro-elastic skeleton was compares

The Recent Research on Bamboo Reinforced Concrete

Directory of Open Access Journals (Sweden)

Dewi Sri Murni

2017-01-01

Full Text Available The paper presents the last research on bamboo reinforced concrete in Brawijaya University Indonesia. Three kinds of structures studied in recent year, the mounting of pegs on reinforcement, the use of lightweight brick to reduce the weight of the beams, and the use the light weight aggregate for bamboo concrete composite frame. All that experiments overcome some problems exist in using bamboo as environmental acceptance structures.

Development of ductile cementitious composites incorporating microencapsulated phase change materials

NARCIS (Netherlands)

Savija, B.; Lukovic, M.; Chaves Figueiredo, S.; de Mendoca Filho, Fernando Franca; Schlangen, H.E.J.G.

2017-01-01

Abstract In the past two decades, much research has been devoted to overcoming the inherent brittleness of cementitious materials. To that end, several solutions have been proposed, mainly utilizing fibres. One of the most promising classes of materials is strain hardening cementitious composite

Self-degradable Cementitious Sealing Materials

Energy Technology Data Exchange (ETDEWEB)

Sugama, T.; Butcher, T., Lance Brothers, Bour, D.

2010-10-01

A self-degradable alkali-activated cementitious material consisting of a sodium silicate activator, slag, Class C fly ash, and sodium carboxymethyl cellulose (CMC) additive was formulated as one dry mix component, and we evaluated its potential in laboratory for use as a temporary sealing material for Enhanced Geothermal System (EGS) wells. The self-degradation of alkali-activated cementitious material (AACM) occurred, when AACM heated at temperatures of {ge}200 C came in contact with water. We interpreted the mechanism of this water-initiated self-degradation as resulting from the in-situ exothermic reactions between the reactants yielded from the dissolution of the non-reacted or partially reacted sodium silicate activator and the thermal degradation of the CMC. The magnitude of self-degradation depended on the CMC content; its effective content in promoting degradation was {ge}0.7%. In contrast, no self-degradation was observed from CMC-modified Class G well cement. For 200 C-autoclaved AACMs without CMC, followed by heating at temperatures up to 300 C, they had a compressive strength ranging from 5982 to 4945 psi, which is {approx}3.5-fold higher than that of the commercial Class G well cement; the initial- and final-setting times of this AACM slurry at 85 C were {approx}60 and {approx}90 min. Two well-formed crystalline hydration phases, 1.1 nm tobermorite and calcium silicate hydrate (I), were responsible for developing this excellent high compressive strength. Although CMC is an attractive, as a degradation-promoting additive, its addition to both the AACM and the Class G well cement altered some properties of original cementitious materials; among those were an extending their setting times, an increasing their porosity, and lowering their compressive strength. Nevertheless, a 0.7% CMC-modified AACM as self-degradable cementitious material displayed the following properties before its breakdown by water; {approx}120 min initial- and {approx}180 min final

Lightweight Bathrooms with Increased Durability

DEFF Research Database (Denmark)

Morelli, Martin; Brandt, Erik

2017-01-01

vulnerable and less robust than the old type of heavy wet rooms made from concrete and masonry. For example damage due to ingress of water and moisture in a lightweight construction is normally associated with very expensive repair work. However, they might perform fully satisfactorily on condition...... wet room floor made with 2 watertight layers separated by an inorganic layer e.g. fibre reinforced concrete. Both layers are drained to the floor gully in order to reduce the risk of damage from leaks in the watertight layer; i.e. if one layer fails, the layer beneath will be able to provide...

Cementitious Barriers Partnership FY2013 End-Year Report

Energy Technology Data Exchange (ETDEWEB)

Flach, G. P. [Savannah River Site (SRS), Aiken, SC (United States); Langton, C. A. [Savannah River Site (SRS), Aiken, SC (United States); Burns, H. H. [Savannah River Site (SRS), Aiken, SC (United States); Smith, F. G. [Savannah River Site (SRS), Aiken, SC (United States); Kosson, D. S. [Vanderbilt University, School of Engineering, Nashville, TN (United States); Brown, K. G. [Vanderbilt University, School of Engineering, Nashville, TN (United States); Samson, E. [SIMCO Technologies, Inc., Quebec (Canada); Meeussen, J. C.L. [Nuclear Research and Consultancy Group (NRG), Petten (The Netherlands); van der Sloot, H. A. [Hans van der Sloot Consultancy, Langedijk (The Netherlands); Garboczi, E. J. [Materials & Construction Research Division, National Institute of Standards and Technology, Gaithersburg, MD (United States)

2013-11-01

In FY2013, the Cementitious Barriers Partnership (CBP) demonstrated continued tangible progress toward fulfilling the objective of developing a set of software tools to improve understanding and prediction of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. In November 2012, the CBP released “Version 1.0” of the CBP Software Toolbox, a suite of software for simulating reactive transport in cementitious materials and important degradation phenomena. In addition, the CBP completed development of new software for the “Version 2.0” Toolbox to be released in early FY2014 and demonstrated use of the Version 1.0 Toolbox on DOE applications. The current primary software components in both Versions 1.0 and 2.0 are LeachXS/ORCHESTRA, STADIUM, and a GoldSim interface for probabilistic analysis of selected degradation scenarios. The CBP Software Toolbox Version 1.0 supports analysis of external sulfate attack (including damage mechanics), carbonation, and primary constituent leaching. Version 2.0 includes the additional analysis of chloride attack and dual regime flow and contaminant migration in fractured and non-fractured cementitious material. The LeachXS component embodies an extensive material property measurements database along with chemical speciation and reactive mass transport simulation cases with emphasis on leaching of major, trace and radionuclide constituents from cementitious materials used in DOE facilities, such as Saltstone (Savannah River) and Cast Stone (Hanford), tank closure grouts, and barrier concretes. STADIUM focuses on the physical and structural service life of materials and components based on chemical speciation and reactive mass transport of major cement constituents and aggressive species (e.g., chloride, sulfate, etc.). THAMES is a planned future CBP Toolbox component focused on simulation of the microstructure of cementitious materials and calculation of resultant

MODULTEC - Modular technology for lightweight vehicles; MODULTEC - Modultechnologie fuer Leichtmobile

Energy Technology Data Exchange (ETDEWEB)

Horlacher, M.; Efler, T.; Wegmann, S.

2003-07-01

This final report for the Swiss Federal Office of Energy presents the results of two research projects (MODULTEC I and II) that were carried out between 1995 and 2002. The project's aims were to develop and assess components for light-weight car bodies, study and test novel reinforced plastic materials and to examine the industrial implementation of light-weight vehicles. The report presents details on prototype vehicles and transport systems, as well as crash tests. The development of compound plastics and appropriate adhesives is discussed as is the co-operation with various industrial partners. Various prototype components are described and other associated topics such as recycling, storage of alternative fuels and pedestrian protection issues are discussed.

Thermal energy storage based on cementitious materials: A review

Directory of Open Access Journals (Sweden)

Khadim Ndiaye

2018-01-01

Full Text Available Renewable energy storage is now essential to enhance the energy performance of buildings and to reduce their environmental impact. Many heat storage materials can be used in the building sector in order to avoid the phase shift between solar radiation and thermal energy demand. However, the use of storage material in the building sector is hampered by problems of investment cost, space requirements, mechanical performance, material stability, and high storage temperature. Cementitious material is increasingly being used as a heat storage material thanks to its low price, mechanical performance and low storage temperature (generally lower than 100 °C. In addition, cementitious materials for heat storage have the prominent advantage of being easy to incorporate into the building landscape as self-supporting structures or even supporting structures (walls, floor, etc.. Concrete solutions for thermal energy storage are usually based on sensible heat transfer and thermal inertia. Phase Change Materials (PCM incorporated in concrete wall have been widely investigated in the aim of improving building energy performance. Cementitious material with high ettringite content stores heat by a combination of physical (adsorption and chemical (chemical reaction processes usable in both the short (daily, weekly and long (seasonal term. Ettringite materials have the advantage of high energy storage density at low temperature (around 60 °C. The encouraging experimental results in the literature on heat storage using cementitious materials suggest that they could be attractive in a number of applications. This paper summarizes the investigation and analysis of the available thermal energy storage systems using cementitious materials for use in various applications.

Ultra High Temperature and Multifunctional Ceramic Matrix Composite – Coating Systems for Light-Weight Space and Aero Systems

Data.gov (United States)

National Aeronautics and Space Administration — Revolutionary ultra-high temperature, high mechanical loading capable, oxidation resistant, durable ceramic coatings and light-weight fiber-reinforced Ceramic Matrix...

Compositions and use of cementitious materials: experience from Onkalo

International Nuclear Information System (INIS)

Hansen, Johanna

2012-01-01

Johanna Hansen of Posiva in Finland summarised experiences of working with cementitious materials in the Finnish disposal programme. Posiva is responsible for geological disposal of spent nuclear fuel from the Finnish nuclear power plants at Loviisa and Olkiluoto. Posiva plans to submit a construction license application in 2012 and, if approved, repository construction will begin in 2014-2015. The geologic disposal facility will be a KBS-3 type repository at a depth of 400 to 500 m in crystalline bedrock. Construction of the repository will require using a large quantity of cementitious materials. A 2007 estimate indicated that approximately 20 million kilograms of cementitious material will be introduced into the repository, although much of this material will be removed, with only approximately 6 million kilograms remaining in the repository after closure, mostly in the form of tunnel plugs. To minimise the potential negative effects of cementitious materials, low-pH cement and colloidal silica both were studied as alternative materials. Based on experience gained in constructing the ONKALO underground characterisation facility, Posiva decided that from the spring 2008 onwards, mainly low-pH cement will be used as grouting material because the grout cannot be removed for repository closure. The low-pH grout is composed of Portland cement, silica fume, and super-plasticizer. Various recipes were tested in the laboratory, and field mixing and grouting tests were conducted at ONKALO. The effects of organics on radionuclide retention and the leaching of organics from the cement also were evaluated. The studies indicated no impediments to the use of low-pH grout at ONKALO and showed that low-pH cementitious grout has better penetration ability and stiffness than regular grout. It was also concluded that the amount of cementitious materials in the repository can be reduced with careful design; for this, cooperation is needed between repository designers and long

State-of-Practice on the Dynamic Response of Structures Strengthened with Fiber Reinforced Polymers (FRPs)

Science.gov (United States)

2015-07-01

entitled “Design guidelines for blast strengthening of concrete and masonry structures using Fiber - Reinforced Polymer (FRP).” Seismic provision...2 Reinforced Concrete Fiber Reinforced Polymers are frequently used to retrofit and repair reinforced concrete structures. Most of the work...tested 72 laboratory-size beams (3-in. by 3-in. cross-section and 30–in. long) of unreinforced and nylon fiber reinforced light-weight concrete that

A mathematical model in charactering chloride diffusivity in unsaturated cementitious material

NARCIS (Netherlands)

Zhang, Y.; Ye, G.; Pecur, I.B.; Baricevic, A.; Stirmer, N; Bjegovic, D.

2017-01-01

In this paper, a new analytic model for predicting chloride diffusivity in unsaturated cementitious materials is developed based on conductivity theory and Nernst-Einstein equation. The model specifies that chloride diffusivity in unsaturated cementitious materials can be mathematically described as

NANOFIBRILLATED CELLULOSE (NFC AS A POTENTIAL REINFORCEMENT FOR HIGH PERFORMANCE CEMENT MORTAR COMPOSITES

Directory of Open Access Journals (Sweden)

Mònica Ardanuy,

2012-07-01

Full Text Available In this work, nanofibrillated cellulose (NFC has been evaluated as a potential reinforcement for cement mortar composites. Two types of vegetable fibres with different composition and properties (cellulose content and microfibrillar angle, sisal, and cotton linters pulps, were initially characterised in order to assess their reinforcing capability. Sisal pulp was found to be most suitable as reinforcement for the brittle cementitious matrix. Nanofibrillated cellulose was produced by the application of a high intensity refining process of the sisal pulp. It was found that 6 hours of refining time was required to obtain the desired nanofibrillation of the fibers. Cement mortar composites reinforced with both the sisal fibres and the nanofibrillated cellulose were prepared, and the mechanical properties were determined under flexural tests. The cement mortar composites reinforced with the nanofibrillated cellulose exhibited enhanced flexural properties, but lower values of fracture energy, than the ones reinforced with the conventional sisal fibres.

Development of lightweight THUNDER with fiber composite layers

Science.gov (United States)

Yoon, Kwang J.; Shin, Sukjoon; Kim, Jusik; Park, Hoon C.; Kwak, Moon K.

2000-06-01

This paper is concerned with design, manufacturing and performance test of lightweight THUNDER using a top fiber composite layer with near-zero CTE, a PZT ceramic wafer and a bottom glass/epoxy layer with high CTE. The main point of this design is to replace the heavy metal layers of THUNDER by the lightweight fiber reinforced plastic layers without losing capabilities to generate high force and displacement. It is possible to save weight up to about 30 percent if we replace the metallic backing materials by the light fiber composite layer. We can also have design flexibility by selecting the fiber direction and the size of prepreg layers. In addition to the lightweight advantage and design flexibility, the proposed device can be manufactured without adhesive layers when we use epoxy resin prepreg system. Glass/epoxy prepregs, a ceramic wafer with electrode surfaces, and a graphite/epoxy prepreg were simply stacked and cured at an elevated temperature by following autoclave bagging process. It was found that the manufactured composite laminate device had a sufficient curvature after detaching form a flat mold. From experimental actuation tests, it was observed that the developed actuator could generate larger actuation displacement than THUNDER.

Cementitious materials for radioactive waste management within IAEA coordinated research project - 59021

International Nuclear Information System (INIS)

Drace, Zoran; Ojovan, Michael I.

2012-01-01

The IAEA Coordinated Research Project (CRP) on cementitious materials for radioactive waste management was launched in 2007 [1, 2]. The objective of CRP was to investigate the behaviour and performance of cementitious materials used in radioactive waste management system with various purposes and included waste packages, waste-forms and backfills as well as investigation of interactions and interdependencies of these individual elements during long term storage and disposal. The specific research topics considered were: (i) cementitious materials for radioactive waste packaging: including radioactive waste immobilization into a solid waste form, (ii) waste backfilling and containers; (iii) emerging and alternative cementitious systems; (iv) physical-chemical processes occurring during the hydration and ageing of cement matrices and their influence on the cement matrix quality; (v) methods of production of cementitious materials for: immobilization into wasteform, backfills and containers; (vi) conditions envisaged in the disposal environment for packages (physical and chemical conditions, temperature variations, groundwater, radiation fields); (vii) testing and non-destructive monitoring techniques for quality assurance of cementitious materials; (viii) waste acceptance criteria for waste packages, waste forms and backfills; transport, long term storage and disposal requirements;and finally (ix) modelling or simulation of long term behaviours of cementations materials used for packaging, waste immobilization and backfilling, especially in the post-closure phase. The CRP has gathered overall 26 research organizations from 22 Member States aiming to share their research and practices on the use of cementitious materials [2]. The main research outcomes of the CRP were summarized in a summary report currently under preparation to be published by IAEA. The generic topical sections covered by report are: a) conventional cementitious systems; b) novel cementitious

Mechanics of Through-Thickness Reinforced Laminates: Delamination and Dynamic Response

National Research Council Canada - National Science Library

Massabo, Roberta

2002-01-01

Through-thickness reinforcement (stitching, z-pins, weaving) is a promising technology to develop fall-safe load bearing components for aeronautical structures and lightweight armor and combat vehicles with superior capabilities...

Shrinkage behaviour and related corrosion performance of low-pH cementitious materials based on OPC or CAC

Directory of Open Access Journals (Sweden)

García-Calvo, J. L.

2016-03-01

Full Text Available Prior to using low-pH cementitious materials in underground repositories for high level waste, the characteristics determining their long-term durability must be analysed in depth. In this sense, different shrinkage tests have been made on mortar and concrete specimens using low-pH cement formulations based on ordinary portland cement (OPC or calcium aluminate cement (CAC, with high mineral admixtures contents. They showed similar autogenous shrinkage than samples without mineral admixtures but higher drying shrinkage when materials based on OPC with high silica fume contents were considered. Besides, as the use of reinforced concrete could be required in underground repositories, the susceptibility of reinforcement to corrosion when using low-pH cementitious materials based on OPC was analyzed, considering carbon steel and galvanized steel. In the formers corrosion was detected due to the low pore solution pH but any problem was detected when galvanized reinforcement were used.Previo al empleo de materiales con cementos de bajo pH en almacenamientos geológicos profundos (AGP de residuos radiactivos de alta actividad, características relacionadas con su durabilidad a largo plazo deben ser verificadas. Así, su estabilidad volumétrica se ha analizado en morteros y hormigones de bajo pH basados en OPC o CAC, con elevados contenidos de adiciones minerales. Estos presentaron retracciones autógenas similares a las medidas en materiales convencionales, pero retracciones por secado mayores en los basados en OPC y altos contenidos de humo de sílice. Dado que en zonas de los AGP podría emplearse hormigón armado, también se evaluó la susceptibilidad a la corrosión de aceros al carbono y aceros galvanizados en materiales de bajo pH basados en OPC. Se detectó un inicio temprano de corrosión en los primeros debido al bajo pH presente en el fluido de los poros de estos materiales, sin detectarse problemas al emplear aceros galvanizados.

X-ray Computed Microtomography technique applied for cementitious materials: A review.

Science.gov (United States)

da Silva, Ítalo Batista

2018-04-01

The main objective of this article is to present a bibliographical review about the use of the X-ray microtomography method in 3D images processing of cementitious materials microstructure, analyzing the pores microstructure and connectivity network, enabling tthe possibility of building a relationship between permeability and porosity. The use of this technique enables the understanding of physical, chemical and mechanical properties of cementitious materials by publishing good results, considering that the quality and quantity of accessible information were significant and may contribute to the study of cementitious materials development. Copyright © 2018 Elsevier Ltd. All rights reserved.

Enhanced impact properties of cementitious composites reinforced with pultruded flax/polymeric matrix fabric

Directory of Open Access Journals (Sweden)

Magdi El-Messiry

2017-09-01

Full Text Available Fiber reinforced concrete (FRC has become increasingly applied in civil engineering in the last decades. Natural fiber fabric reinforced cement composites are considered to prevent damage resulting from an impact loading on the cementite plate. Flax woven fabric that has a high energy absorption capability was chosen. To increase the interfacial shear properties, the fabric was pultruded with different matrix properties that affect the strength and toughness of the pultruded fabric. In this study, three fabric structures are used to increase the anchoring of the cement in the fabric. The compressive strength and the impact energy were measured. The results revealed that pultruded fabric reinforced cement composite (PFRC absorbs much more impact energy. PFRC under impact loading has more micro cracks, while plain cement specimen shows brittle failure. The compressive test results of PFRC indicate that flax fiber fabric polymer enhanced compressive strength remarkably. Fiber reinforcement is a very effective in improving the impact resistance of PFRC. The study defines the influence factors that control the energy dissipation of the composite, which are the hardness of the polymer and the fabric cover factor. Significant correlation between impact energy and compressive strength was proved.

Ancient analogues concerning stability and durability of cementitious wasteform

International Nuclear Information System (INIS)

Jiang, W.; Roy, D.M.

1994-01-01

The history of cementitious materials goes back to ancient times. The Greeks and Romans used calcined limestone and later developed pozzolanic cement by grinding together lime and volcanic ash called open-quotes pozzolanclose quotes which was first found near Port Pozzuoli, Italy. The ancient Chinese used lime-pozzolanic mixes to build the Great Wall. The ancient Egyptians used calcined impure gypsum to build the Great Pyramid of Cheops. The extraordinary stability and durability of these materials has impressed us, when so much dramatically damaged infrastructure restored by using modern portland cement now requires rebuilding. Stability and durability of cementitious materials have attracted intensive research interest and contractors' concerns, as does immobilization of radioactive and hazardous industrial waste in cementitious materials. Nuclear waste pollution of the environment and an acceptable solution for waste management and disposal constitute among the most important public concerns. The analogy of ancient cementitious materials to modern Portland cement could give us some clues to study their stability and durability. This present study examines selected results of studies of ancient building materials from France, Italy, China, and Egypt, combined with knowledge obtained from the behavior of modern portland cement to evaluate the potential for stability and durability of such materials in nuclear waste forms

Evaluation of Interface Shear Strength Properties of Geogrid Reinforced Foamed Recycled Glass Using a Large-Scale Direct Shear Testing Apparatus

Directory of Open Access Journals (Sweden)

Arul Arulrajah

2015-01-01

Full Text Available The interface shear strength properties of geogrid reinforced recycled foamed glass (FG were determined using a large-scale direct shear test (DST apparatus. Triaxial geogrid was used as a geogrid reinforcement. The geogrid increases the confinement of FG particles during shear; consequently the geogrid reinforced FG exhibits smaller vertical displacement and dilatancy ratio than FG at the same normal stress. The failure envelope of geogrid reinforced FG, at peak and critical states, coincides and yields a unique linear line possibly attributed to the crushing of FG particles and the rearrangement of crushed FG after peak shear state. The interface shear strength coefficient α is approximately constant at 0.9. This value can be used as the interface parameter for designing a reinforced embankment and mechanically stabilized earth (MSE wall when FG is used as a lightweight backfill and triaxial geogrid is used as an extensible earth reinforcement. This research will enable FG, recently assessed as suitable for lightweight backfills, to be used together with geogrids in a sustainable manner as a lightweight MSE wall. The geogrid carries tensile forces, while FG reduces bearing stresses imposed on the in situ soil. The use of geogrid reinforced FG is thus significant from engineering, economical, and environmental perspectives.

Cementitious Barriers Partnership Accomplishments And Relevance To The DOE Complex

International Nuclear Information System (INIS)

Burns, H.; Langton, C.; Flach, G.; Kosson, D.

2010-01-01

The Cementitious Barriers Partnership (CBP) was initiated to reduce risk and uncertainties in the performance assessments that directly impact U.S. Department of Energy (DOE) environmental cleanup and closure programs. The CBP is supported by the DOE Office of Environmental Management (DOE-EM) and has been specifically addressing the following critical EM program needs: (i) the long-term performance of cementitious barriers and materials in nuclear waste disposal facilities and (ii) increased understanding of contaminant transport behavior within cementitious barrier systems to support the development and deployment of adequate closure technologies. To accomplish this, the CBP has two initiatives: (1) an experimental initiative to increase understanding of changes in cementitious materials over long times (> 1000 years) over changing conditions and (2) a modeling initiative to enhance and integrate a set of computational tools validated by laboratory and field experimental data to improve understanding and prediction of the long-term performance of cementitious barriers and waste forms used in nuclear applications. In FY10, the CBP developed the initial phase of an integrated modeling tool that would serve as a screening tool which could help in making decisions concerning disposal and tank closure. The CBP experimental programs are underway to validate this tool and provide increased understanding of how CM changes over time and under changing conditions. These initial CBP products that will eventually be enhanced are anticipated to reduce the uncertainties of current methodologies for assessing cementitious barrier performance and increase the consistency and transparency of the DOE assessment process. These tools have application to low activity waste forms, high level waste tank closure, D and D and entombment of major nuclear facilities, landfill waste acceptance criteria, and in-situ grouting and immobilization of vadose zone contamination. This paper

ULTRA-LIGHTWEIGHT CEMENT

International Nuclear Information System (INIS)

Fred Sabins

2001-01-01

The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses Task 1: Assess Ultra-Lightweight Cementing Issues, Task 2: Review Russian Ultra-Lightweight Cement Literature, Task 3: Test Ultra-Lightweight Cements, and Task 8: Develop Field ULHS Cement Blending and Mixing Techniques. Results reported this quarter include: preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; summary of pertinent information from Russian ultra-lightweight cement literature review; laboratory tests comparing ULHS slurries to foamed slurries and sodium silicate slurries for two different applications; and initial laboratory studies with ULHS in preparation for a field job

Study on reinforced lightweight coconut shell concrete beam behavior under torsion

International Nuclear Information System (INIS)

Gunasekaran, K.; Ramasubramani, R.; Annadurai, R.; Prakash Chandar, S.

2014-01-01

Highlights: • Use of coconut shell as aggregate in concrete production. • Behavior of coconut shell concrete under torsion. • Pre and post cracking behavior and analysis. • Torsional reinforcement and ductility. • Crack width and stiffness. - Abstract: This research investigates and evaluates the results of coconut shell concrete beams subjected to torsion and compared with conventional concrete beams. Eight beams, four with coconut shell concrete and four with conventional concrete were fabricated and tested. Study includes the general cracking characteristics, pre cracking behavior and analysis, post cracking behavior and analysis, minimum torsional reinforcement, torsional reinforcement, ductility, crack width and stiffness. It was observed that the torsional behavior of coconut shell concrete is comparable to that of conventional concrete. Compare to ACI prediction, equation suggested by Macgregor is more conservative in calculating cracking torsional resistance. But for the calculation of ultimate torque strength ACI prediction is more conservative compared to the equation suggested by Macgregor. Indian standard is also conservative in this regard, but it was under estimated compared to ACI and Macgregor equations. Minimum torsional reinforcement in beams is necessary to ensure that the beam do not fail at cracking. Compared to conventional concrete specimens, coconut shell concrete specimens have more ductility. Crack width at initial cracking torque for both conventional and coconut shell concrete with corresponding reinforcement ratios is almost similar

Cost efficient carbon fibre reinforced thermoplastics with in-situ polymerization of polyamide

Science.gov (United States)

Köhler, T.; Akdere, M.; Röding, T.; Gries, T.; Seide, G.

2017-10-01

Lightweight design has gained more and more relevance over the last decades. Especially in automotive industry it is of paramount importance to reduce weight and save fuel. At the same time the demand for safety and performance increases the components’ weight. To reach a trade-off between driving comfort and efficiency new lightweight materials have to be developed. One possible solution is the usage of carbon fibre reinforced thermoplastics (CFRTP) as a lightweight substitute material. In contrast to conventional carbon fibre reinforced plastics (CFRP), CFRTPs are cheaper and have a higher impact resistance. Furthermore they are characterized by hot forming ability, weldability and recyclability. However, the impregnation of the textile requires high pressure, because of the melted polymer’s high viscosity. A new innovative approach for CFRTP is the usage of in-situ polymerization with ɛ-caprolactam as matrix, which has a much lower viscosity and thus requires much lower pressure for impregnation and consolidation.

High strength oil palm shell concrete beams reinforced with steel fibres

Directory of Open Access Journals (Sweden)

S. Poh-Yap

2017-10-01

Full Text Available The utilization of lightweight oil palm shell to produce high strength lightweight sustainable material has led many researchers towards its commercialization as structural concrete. However, the low tensile strength of Oil Palm Shell Concrete (OPSC has hindered its development. This study aims to enhance the mechanical properties and flexural behaviours of OPSC by the addition of steel fibres of up to 3% by volume, to produce oil palm shell fibre-reinforced concrete (OPSFRC. The experimental results showed that the steel fibres significantly enhanced the mechanical properties of OPSFRC. The highest compressive strength, splitting tensile and flexural strengths of 55, 11.0 and 18.5 MPa, respectively, were achieved in the OPSFRC mix reinforced with 3% steel fibres. In addition, the flexural beam testing on OPSFRC beams with 3% steel fibres showed that the steel fibre reinforcement up to 3% produced notable increments in the moment capacity and crack resistance of OPSFRC beams, but accompanied by reduction in the ductility.

Behavior of Fiber-Reinforced Smart Soft Composite Actuators According to Material Composition

Energy Technology Data Exchange (ETDEWEB)

Han, Min-Woo; Kim, Hyung-Il; Song, Sung-Hyuk; Ahn, Sung-Hoon [Seoul Nat’l Univ., Seoul (Korea, Republic of)

2017-02-15

Fiber-reinforced polymer composites, which are made by combining a continuous fiber that acts as reinforcement and a homogeneous polymeric material that acts as a host, are engineering materials with high strength and stiffness and a lightweight structure. In this study, a shape memory alloy(SMA) reinforced composite actuator is presented. This actuator is used to generate large deformations in single lightweight structures and can be used in applications requiring a high degree of adaptability to various external conditions. The proposed actuator consists of numerous individual laminas of the glass-fiber fabric that are embedded in a polymeric matrix. To characterize its deformation behavior, the composition of the actuator was changed by changing the matrix material and the number of the glass-fiber fabric layers. In addition, current of various magnitudes were applied to each actuator to study the effect of the heating of SMA wires on applying current.

Effect of cementitious permanent formwork on moisture field of internal-cured concrete under drying

Science.gov (United States)

Wang, Jiahe; Zhang, Jun; Ding, Xiaoping; Zhang, Jiajia

2018-02-01

Drying shrinkage of concrete may still be the main source of cracking in concrete structures, even though the autogenous shrinkage of concrete can be effectively reduced by using internal curing. In the present paper, the effect of internal curing with pre-soaked lightweight aggregate and engineered cementitious composite permanent formwork (ECC-PF) on a moisture distribution in three kinds of concrete in a drying environment are investigated from both aspects of experiments and theoretical modeling. The test results show that the combination use of ECC-PF and internal curing can well maintain the humidity at a relatively high level not only at a place far from drying surface, but also at a place close to the drying surfaces. The developed model can well catch the characteristics of the moisture distribution in concrete under drying and the impacts of internal curing and ECC-PF can well be reflected as well. The model can be used for the design of concrete structures with combination use of internal curing and permanent formwork.

Research on carbon fiber–reinforced plastic bumper beam subjected to low-velocity frontal impact

Directory of Open Access Journals (Sweden)

Yefa Hu

2015-06-01

Full Text Available Lightweight and safety performance of automobiles are two important factors for automobile designs. In this article, a research on lightweight and crashworthiness of automotive bumper has been conducted. The carbon fiber–reinforced plastic bumper beam is considered to replace the traditional high-strength steel one. The low-velocity impact finite element simulations for the above two bumper beams are performed via LS-DYNA. Furthermore, the energy absorption capabilities and dynamic response characteristics of the carbon fiber–reinforced plastic bumper beam are investigated and compared with the steel one. The results show that the carbon fiber–reinforced plastic bumper beam is of the better energy absorption capabilities and dynamic response characteristics than those of the steel one; the weight has decreased remarkably close to 50%. Meanwhile, the effect of lay-up and wall thickness on the crashworthiness of the carbon fiber–reinforced plastic bumper beam under low-velocity impact is also studied in this article to select appropriate design schemes.

Reduction of minimum required weight of cementitious materials in WisDOT concrete mixes.

Science.gov (United States)

2011-12-01

This project was designed to explore the feasibility of lowering the cementitious materials content : (CMC) used in Wisconsin concrete pavement construction. The cementitious materials studied included : portland cement, fly ash, and ground granulate...

Reduction of minimum required weight of cementitious materials in WisDOT concrete mixes.

Science.gov (United States)

2011-12-01

"This project was designed to explore the feasibility of lowering the cementitious materials content : (CMC) used in Wisconsin concrete pavement construction. The cementitious materials studied included : portland cement, fly ash, and ground granulat...

Study of the Microstructure Evolution of Low-pH Cements Based on Ordinary Portland Cement (OPC by Mid- and Near-Infrared Spectroscopy, and Their Influence on Corrosion of Steel Reinforcement

Directory of Open Access Journals (Sweden)

Juan García Olmo

2013-06-01

Full Text Available Low-pH cements are designed to be used in underground repositories for high level waste. When they are based on Ordinary Portland Cements (OPC, high mineral admixture contents must be used which significantly modify their microstructure properties and performance. This paper evaluates the microstructure evolution of low-pH cement pastes based on OPC plus silica fume and/or fly ashes, using Mid-Infrared and Near-Infrared spectroscopy to detect cement pastes mainly composed of high polymerized C-A-S-H gels with low C/S ratios. In addition, the lower pore solution pH of these special cementitious materials have been monitored with embedded metallic sensors. Besides, as the use of reinforced concrete can be required in underground repositories, the influence of low-pH cementitious materials on steel reinforcement corrosion was analysed. Due to their lower pore solution pH and their different pore solution chemical composition a clear influence on steel reinforcement corrosion was detected.

Review of high and ultrahigh performance cementitious composites incorporating various combinations of fibers and ultrafines

Directory of Open Access Journals (Sweden)

M.I. Khan

2017-10-01

Full Text Available The outcomes of the research in modern cementitious composites have paved the way for their wide use in construction industry. The introduction of short, discontinuous and randomly distributed fibers to these composites has altered their inherent brittleness. Extensive research has been carried out on the effects of using of mono-fibers in a cementitious composite. However, limited reports in the approachable references on the use of hybrid fibers are available. The synergetic interaction between hybrid fibers have beneficial impact on cementitious composites. The incorporation of micro- and nano-pozzolanic materials, such as fly ash and silica fume have been used to develop high performance cementitious composites such as reactive powder concrete, DUCTAL and CEMTEC multiscale. Further developments were recently achieved by the development of ultra-high performance cementitious composites. The matter of developing high and ultrahigh cementitious composites using various kinds of fibers and particles has received enormous attention from the scientific community. This paper presents a comprehensive critical literature review on the area of high and ultra-high performance cement-based materials.

Time-Dependent Behavior of Reinforced Polymer Concrete Columns under Eccentric Axial Loading

Directory of Open Access Journals (Sweden)

Valentino Paolo Berardi

2012-11-01

Full Text Available Polymer concretes (PCs represent a promising alternative to traditional cementitious materials in the field of new construction. In fact, PCs exhibit high compressive strength and ultimate compressive strain values, as well as good chemical resistance. Within the context of these benefits, this paper presents a study on the time-dependent behavior of polymer concrete columns reinforced with different bar types using a mechanical model recently developed by the authors. Balanced internal reinforcements are considered (i.e., two bars at both the top and bottom of the cross-section. The investigation highlights relevant stress and strain variations over time and, consequently, the emergence of a significant decrease in concrete’s stiffness and strength over time. Therefore, the results indicate that deferred effects due to viscous flow may significantly affect the reliability of reinforced polymer concrete elements over time.

Implications of cementitious evolution for solubility and retention of radionuclides over long timescales

International Nuclear Information System (INIS)

Williams, Steve; Norris, Simon

2012-01-01

Simon Norris of the NDA described the current status of understanding of radionuclide solubility and retention in cementitious materials based on experience in the United Kingdom. Cementitious materials play a number of roles in the long-term management and disposal of radioactive wastes. One of these roles is to contribute to the post-closure containment and retention of radionuclides within a disposal facility by imposing conditions that minimise radionuclide solubility and provide sites for radionuclide sorption. The chemical containment provided by the highly-alkaline, chemically reducing environment imposed by cementitious materials plays an important role in the long-term retention of many radionuclides. However, the mineralogy and other properties of cementitious materials that contribute to their physical and chemical barrier performance within the engineered barrier system will evolve due to several processes, including: - Leaching. - Reaction with groundwater solutes. - Hydration and crystallisation. - Reaction with wastes, their degradation products, and with non-cementitious waste forms. - Cracking. Some of these processes are better understood than others. For example, the evolution of pH within a homogeneous repository near field can be modelled based on knowledge of cement dissolution combined with expected groundwater compositions and flow rates. The calculated changes in pH can then be coupled to radionuclide solubility and sorption in safety assessment models. Other processes are not as well constrained. Reaction of cementitious materials with groundwater will lead to changes in the mineralogical composition of the cements, accompanied by changes in porosity and permeability, and cracking can lead to localised water flow along the cracks and preferential leaching or deposition of reaction products. These processes can also alter the sorption properties of the cementitious materials. Additional complexities result from the heterogeneous

Advanced lightweight optics development for space applications

International Nuclear Information System (INIS)

Bilbro, James W.

1998-01-01

A considerable amount of effort over the past year has been devoted to exploring ultra-lightweight optics for two specific NASA programs, the Next Generation Space Telescope (NGST), and the High Throughput X-ray Spectrometer (HTXS). Experimental investigations have been undertaken in a variety of materials including glass, composites, nickel, beryllium, Carbon fiber reinforced Silicon Carbide (CSiC), Reaction Bonded Silicon Carbide, Chemical Vapor Deposited Silicon Carbide, and Silicon. Overall results of these investigations will be summarized, and specific details will be provided concerning the in-house development of ultra-lightweight nickel replication for both grazing incidence and normal incidence optics. This will include x-ray test results of the grazing incidence optic and cryogenic test results of the normal incidence optic. The status of two 1.5 meter diameter demonstration mirrors for NGST will also be presented. These two demonstrations are aimed at establishing the capability to manufacture and test mirrors that have an areal density of 15 kilograms per square meter. Efforts in thin membrane mirrors and Fresnel lenses will also be briefly discussed

Preliminary experimental study on the deterioration of cementitious materials by an acceleration method

International Nuclear Information System (INIS)

Saito, H.; Nakane, S.; Ikari, S.; Fujiwara, A.

1992-01-01

Development of a deterioration model for cementitious materials is important in assessing long-term integrity of nuclear waste repositories. The authors preliminarily examined a new test method for acceleration of aging of mortar specimens by application of electrical potential gradients and observed whether the method could throw light on the deterioration process of cementitious materials under repository conditions. As a result, it was concluded that the application of a potential gradient to a mortar specimen might be useful as an accelerated test method for assessing the deterioration behavior of cementitious materials due to leaching. (orig.)

Thermal properties of light-weight concrete with waste polypropylene aggregate

Science.gov (United States)

Záleská, Martina; Pokorný, Jaroslav; Pavlíková, Milena; Pavlík, Zbyšek

2017-07-01

Thermal properties of a sustainable light-weight concrete incorporating high volume of waste polypropylene as partial substitution of natural aggregate were studied in the paper. Glass fiber reinforced polypropylene (GFPP), a by-product of PP tubes production, partially substituted fine natural silica aggregate in 10, 20, 30, 40, and 50 mass%. In order to quantify the effect of GFPP use on concrete properties, a reference concrete mix without plastic waste was studied as well. For the applied GFPP, bulk density, matrix density, and particle size distribution were measured. Specific attention was paid to thermal transport and storage properties of GFPP that were examined in dependence on compaction time. For the developed light-weight concrete, thermal properties were accessed using transient impulse technique, whereas the measurement was done in dependence on moisture content, from the dry state to fully water saturated state. Additionally, the investigated thermal properties were plotted as function of porosity. The tested light-weight concrete was found to be prospective construction material possessing improved thermal insulation function. Moreover, the reuse of waste plastics in concrete composition was beneficial both from the environmental and financial point of view considering plastics low biodegradability and safe disposal.

Significance of steel electrical resistance method in the evaluation of reinforcement corrosion in cementitious systems

Directory of Open Access Journals (Sweden)

Krajci, L.

2004-06-01

Full Text Available The suitable detection system of steel reinforcement corrosion in concrete structures contributes to the reduction of their maintenance costs. Method of steel electrical resistance represents non-destructive monitoring of steel in cementitious systems. Specially prepared and arranged test specimen of steel as a corrosion sensor is embedded in mortar specimen. Verification tests of this method based on chloride corrosion of steel in mortars as well as its visual inspection are introduced. Significance of steel electrical resistance method lies in the expression of steel corrosion by these quantitative parameters: reduction of cross-section of steel, thickness of corroded layer and loss of weight of steel material. This method is an integral method that allows the indirect determination of mentioned corrosion characteristics. The comparison of verified method with gravimetric evaluation of steel corrosion gives a good correspondence. Test results on mortars with calcium chloride dosages between 0.5% and 4.0% by weight of cement prove high sensitiveness and reliability of steel electrical resistance method.

La utilización de un sistema de detección de la corrosión de las armaduras en estructuras de hormigón puede contribuir a la reducción de sus costes de mantenimiento. El método de la resistencia eléctrica del acero consiste en la monitorización no-destructiva realizada sobre el acero en sistemas cementantes. Dentro de la muestra de mortero se coloca el sistema de detección, especialmente preparado y fijado, actuando como un sensor de la corrosión. En este trabajo se presentan ensayos de verificación de este método, junto con inspecciones visuales, en morteros sometidos a corrosión de armaduras por efecto de los cloruros. La efectividad de este método de la resistencia eléctrica del acero se expresa, en la corrosión de armaduras, de acuerdo a los siguientes parámetros cuantitativos: reducción de la sección transversal del

Demonstration Of LEACHXS(trademark)/Orchestra Capabilities By Simulating Constituent Release From A Cementitious Waste Form In A Reinforced Concrete Vault

International Nuclear Information System (INIS)

Langton, C.; Meeussen, J.; Sloot, H.

2010-01-01

The objective of the work described in this report is to demonstrate the capabilities of the current version of LeachXS(trademark)/ORCHESTRA for simulating chemical behavior and constituent release processes in a range of applications that are relevant to the CBP. This report illustrates the use of LeachXS(trademark)/ORCHESTRA for the following applications: (1) Comparing model and experimental results for leaching tests for a range of cementitious materials including cement mortars, grout, stabilized waste, and concrete. The leaching test data includes liquid-solid partitioning as a function of pH and release rates based on laboratory column, monolith, and field testing. (2) Modeling chemical speciation of constituents in cementitious materials, including liquid-solid partitioning and release rates. (3) Evaluating uncertainty in model predictions based on uncertainty in underlying composition, thermodynamic, and transport characteristics. (4) Generating predominance diagrams to evaluate predicted chemical changes as a result of material aging using the example of exposure to atmospheric conditions. (5) Modeling coupled geochemical speciation and diffusion in a three layer system consisting of a layer of Saltstone, a concrete barrier, and a layer of soil in contact with air. The simulations show developing concentration fronts over a time period of 1000 years. (6) Modeling sulfate attack and cracking due to ettringite formation. A detailed example for this case is provided in a separate article by the authors (Sarkar et al. 2010). Finally, based on the computed results, the sensitive input parameters for this type of modeling are identified and discussed. The chemical speciation behavior of substances is calculated for a batch system and also in combination with transport and within a three layer system. This includes release from a barrier to the surrounding soil as a function of time. As input for the simulations, the physical and chemical properties of the

Reducing supply chain energy use in next-generation vehicle lightweighting

Energy Technology Data Exchange (ETDEWEB)

Hanes, Rebecca J.; Das, Sujit; Carpenter, Alberta

2016-09-29

Vehicle lightweighting reduces the amount of fuel consumed in a vehicle's use phase, but depending on what lightweight materials replace the conventional materials, and in what amounts, the manufacturing energy may increase or decrease. For carbon fiber reinforced polymer (CFRP), a next-generation lightweighting material, the increase in vehicle manufacturing energy is greater than the fuel savings, resulting in a net increase in energy consumption over a vehicle's manufacturing and use relative to a standard non-lightweighted car. [1] This work explores ways to reduce the supply chain energy of CFRP lightweighted vehicles through alternative production technologies and energy efficiency improvements. The objective is to determine if CFRP can offer energy savings comparable to or greater than aluminum, a conventional lightweighting material. Results of this analysis can be used to inform additional research and development efforts in CFRP production and future directions in lightweight vehicle production. The CFRP supply chain is modeled using the Material Flows through Industry (MFI) scenario modeling tool, which calculates 'mine to materials' energy consumption, material inventories and greenhouse gas emissions for industrial supply chains. In this analysis, the MFI tool is used to model the supply chains of two lightweighted vehicles, an aluminum intensive vehicle (AIV) and a carbon fiber intensive vehicle (CFV), under several manufacturing scenarios. Vehicle specifications are given in [1]. Scenarios investigated cover alternative carbon fiber (CF) feedstocks and energy efficiency improvements at various points in the vehicle supply chains. The alternative CF feedstocks are polyacrylonitrile, lignin and petroleum-derived mesophase pitch. Scenarios in which the energy efficiency of CF and CFRP production increases are explored using sector efficiency potential values, which quantify the reduction in energy consumption achievable when process

Use of Cementitious Materials for SRS Reactor Facility In-Situ Decommissioning

International Nuclear Information System (INIS)

Langton, C.A.; Stefanko, D.B.; Serrato, M.G.; Blankenship, J.K.; Griffin, W.G.; Long, J.T.

2013-01-01

The United States Department of Energy (US DOE) concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate intact, structurally sound facilities that are no longer needed for their original purpose of producing (reactor facilities), processing (isotope separation facilities) or storing radioactive materials. The Savannah River Site 105-P and 105-R Reactor Facility ISD project requires approximately 250000 cubic yards of cementitious materials to fill the below-grade structure. The fills are designed to prevent subsidence, reduce water infiltration, and isolate contaminated materials. This work is being performed as a Comprehensive Environmental Response, Compensations and Liability Act (CERCLA) action and is part of the overall soil and groundwater completion projects for P- and R-Areas. Funding is being provided under the American Recovery and Reinvestment Act (ARRA). Cementitious materials were designed for the following applications: (A) Below-grade massive voids / rooms: Portland cement-based structural flowable fills for: (A.1) Bulk filling; (A.2) Restricted placement and (A.3) Underwater placement. (B) Special below-grade applications for reduced load bearing capacity needs: (B.1) Cellular portland cement lightweight fill. (C) Reactor vessel fills that are compatible with reactive metal (aluminum metal) components in the reactor vessels (C.1) Blended calcium aluminate - calcium sulfate based flowable fill; (C.2) Magnesium potassium phosphate flowable fill. (D) Caps to prevent water infiltration and intrusion into areas with the highest levels of radionuclides: (D.1) Portland cement based shrinkage compensating concrete. A system engineering approach was used to identify functions and requirements of the fill and capping materials. Laboratory testing was performed to identify candidate formulations and develop final design mixes. Scale-up testing was performed to verify material production and placement as well as fresh and cured

Light-weight spherical mirrors for Cherenkov detectors

CERN Document Server

Cisbani, E; Colilli, S; Crateri, R; Cusanno, F; De Leo, R; Fratoni, R; Frullani, S; Garibaldi, F; Giuliani, F; Gricia, M; Iodice, M; Iommi, R; Lagamba, L; Lucentini, M; Mostarda, A; Nappi, E; Pierangeli, L; Santavenere, F; Urciuoli, G M; Vernin, P

2003-01-01

Light-weight spherical mirrors have been appositely designed and built for the gas threshold Cherenkov detectors of the two Hall A spectrometers. The mirrors are made of a 1 mm thick aluminized plexiglass sheet, reinforced by a rigid backing consisting of a phenolic honeycomb sandwiched between two carbon fiber mats epoxy glued. The produced mirrors have a thickness equivalent to 0.55% of radiation length, and an optical slope error of about 5.5 mrad. These characteristics make these mirrors suitable for the implementation in Cherenkov threshold detectors. Ways to improve the mirror features are also discussed in view of their possible employment in RICH detectors.

CEMENTITIOUS BARRIERS PARTNERSHIP FY13 MID-YEAR REPORT

Energy Technology Data Exchange (ETDEWEB)

Burns, H.; Flach, G.; Langton, C.; KOSSON, D.; BROWN, K.; SAMSON, E.; MEEUSSEN, J.; SLOOT, H.; GARBOCZI, E.

2013-05-01

In FY2013, the Cementitious Barriers Partnership (CBP) is continuing in its effort to develop and enhance software tools demonstrating tangible progress toward fulfilling the objective of developing a set of tools to improve understanding and prediction of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. In FY2012, the CBP released the initial inhouse “Beta-version” of the CBP Software Toolbox, a suite of software for simulating reactive transport in cementitious materials and important degradation phenomena. The current primary software components are LeachXS/ORCHESTRA, STADIUM, and a GoldSim interface for probabilistic analysis of selected degradation scenarios. THAMES is a planned future CBP Toolbox component (FY13/14) focused on simulation of the microstructure of cementitious materials and calculation of resultant hydraulic and constituent mass transfer parameters needed in modeling. This past November, the CBP Software Toolbox Version 1.0 was released that supports analysis of external sulfate attack (including damage mechanics), carbonation, and primary constituent leaching. The LeachXS component embodies an extensive material property measurements database along with chemical speciation and reactive mass transport simulation cases with emphasis on leaching of major, trace and radionuclide constituents from cementitious materials used in DOE facilities, such as Saltstone (Savannah River) and Cast Stone (Hanford), tank closure grouts, and barrier concretes. STADIUM focuses on the physical and structural service life of materials and components based on chemical speciation and reactive mass transport of major cement constituents and aggressive species (e.g., chloride, sulfate, etc.). The CBP issued numerous reports and other documentation that accompanied the “Version 1.0” release including a CBP Software Toolbox User Guide and Installation Guide. These documents, as well as, the

Calcining natural zeolites to improve their effect on cementitious mixture workability

International Nuclear Information System (INIS)

Seraj, Saamiya; Ferron, Raissa D.; Juenger, Maria C.G.

2016-01-01

Despite the benefits to long-term concrete durability, the use of natural zeolites as supplementary cementitious materials (SCMs) is uncommon due to their high water demand. The motivation of the research presented here was to better understand how the physical and chemical characteristics of natural zeolites influenced the workability of cementitious mixtures and whether those properties could be modified through calcination to mitigate the high water demand of natural zeolites. In this research, three different natural zeolites were characterized in their original and calcined states using x-ray diffraction (XRD) and Brunauer–Emmett–Teller (BET) surface area measurements. Rheology experiments were then conducted on cementitious pastes containing these natural zeolites, in their original and calcined states, to assess mixture viscosity and yield stress. Results showed that calcination destabilized the structure of the natural zeolites and reduced their surface area, which led to an improvement in mixture viscosity and yield stress.

Cementitious Barriers Partnership (CBP): Using the CBP Software Toolbox to Simulate Sulfate Attack and Carbonation of Concrete Structures - 13481

International Nuclear Information System (INIS)

Brown, K.G.; Kosson, D.S.; Garrabrants, A.C.; Sarkar, S.; Flach, G.; Langton, C.; Smith, F.G.III; Burns, H.; Van der Sloot, H.; Meeussen, J.C.L.; Seignette, P.F.A.B.; Samson, E.; Mallick, P.; Suttora, L.; Esh, D.; Fuhrmann, M.; Philip, J.

2013-01-01

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy Office of Tank Waste Management. The CBP project has developed a set of integrated modeling tools and leaching test methods to help improve understanding and prediction of the long-term hydraulic and chemical performance of cementitious materials used in nuclear applications. State-of-the-art modeling tools, including LeachXS TM /ORCHESTRA and STADIUM R , were selected for their demonstrated abilities to simulate reactive transport and degradation in cementitious materials. The new U.S. Environmental Protection Agency leaching test methods based on the Leaching Environmental Assessment Framework (LEAF), now adopted as part of the SW-846 RCRA methods, have been used to help make the link between modeling and experiment. Although each of the CBP tools has demonstrated utility as a standalone product, coupling the models over relevant spatial and temporal solution domains can provide more accurate predictions of cementitious materials behavior over relevant periods of performance. The LeachXS TM /ORCHESTRA and STADIUM R models were first linked to the GoldSim Monte Carlo simulator to better and more easily characterize model uncertainties and as a means to coupling the models allowing linking to broader performance assessment evaluations that use CBP results for a source term. Two important degradation scenarios were selected for initial demonstration: sulfate ingress / attack and carbonation of cementitious materials. When sufficient sulfate is present in the pore solution external to a concrete barrier, sulfate can diffuse into the concrete, react with the concrete solid phases, and cause cracking that significantly changes the transport and structural properties of the concrete. The penetration of gaseous carbon dioxide within partially saturated concrete usually initiates a series of carbonation reactions with

Cementitious Barriers Partnership (CBP): Using the CBP Software Toolbox to Simulate Sulfate Attack and Carbonation of Concrete Structures - 13481

Energy Technology Data Exchange (ETDEWEB)

Brown, K.G.; Kosson, D.S.; Garrabrants, A.C.; Sarkar, S. [Vanderbilt University, School of Engineering, CRESP, Nashville, TN 37235 (United States); Flach, G.; Langton, C.; Smith, F.G.III; Burns, H. [Savannah River National Laboratory, Aiken, SC 29808 (United States); Van der Sloot, H. [Hans Van der Sloot Consultancy, Dorpsstraat 216, 1721BV Langedijk (Netherlands); Meeussen, J.C.L. [Nuclear Research and Consultancy Group, Westerduinweg 3, Petten (Netherlands); Seignette, P.F.A.B. [Energy Research Center of The Netherlands, Petten (Netherlands); Samson, E. [SIMCO Technologies, Inc., Quebec (Canada); Mallick, P.; Suttora, L. [U.S. Department of Energy, Washington, DC (United States); Esh, D.; Fuhrmann, M.; Philip, J. [U.S. Nuclear Regulatory Commission, Washington, DC (United States)

2013-07-01

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy Office of Tank Waste Management. The CBP project has developed a set of integrated modeling tools and leaching test methods to help improve understanding and prediction of the long-term hydraulic and chemical performance of cementitious materials used in nuclear applications. State-of-the-art modeling tools, including LeachXS{sup TM}/ORCHESTRA and STADIUM{sup R}, were selected for their demonstrated abilities to simulate reactive transport and degradation in cementitious materials. The new U.S. Environmental Protection Agency leaching test methods based on the Leaching Environmental Assessment Framework (LEAF), now adopted as part of the SW-846 RCRA methods, have been used to help make the link between modeling and experiment. Although each of the CBP tools has demonstrated utility as a standalone product, coupling the models over relevant spatial and temporal solution domains can provide more accurate predictions of cementitious materials behavior over relevant periods of performance. The LeachXS{sup TM}/ORCHESTRA and STADIUM{sup R} models were first linked to the GoldSim Monte Carlo simulator to better and more easily characterize model uncertainties and as a means to coupling the models allowing linking to broader performance assessment evaluations that use CBP results for a source term. Two important degradation scenarios were selected for initial demonstration: sulfate ingress / attack and carbonation of cementitious materials. When sufficient sulfate is present in the pore solution external to a concrete barrier, sulfate can diffuse into the concrete, react with the concrete solid phases, and cause cracking that significantly changes the transport and structural properties of the concrete. The penetration of gaseous carbon dioxide within partially saturated concrete usually initiates a series of carbonation

Carbonation of ternary cementitious concrete systems containing fly ash and silica fume

Directory of Open Access Journals (Sweden)

Eehab Ahmed Badreldin Khalil

2015-04-01

Full Text Available Carbonation is quite a complex physical negative effect phenomenon on concrete especially in the ones containing ternary blends of Portland Cement, fly ash, and silica fume. Nine selected concrete mixtures were prepared with various water to cementitious materials’ ratios and various cementitious contents. The concrete mixtures were adapted in such a way to have the same workability and air content. The fresh concrete properties were kept near identical in slump, air content, and unit weight. The variation was in the hardened concrete mechanical properties of compression and tension strength. The carbonation phenomenon was studied for these mixes showing at which mixes of ternary cementitious content heavy carbonation attacks maybe produced. The main components of such mixes that do affect the carbonation process with time were presented.

Research on carbon fiber–reinforced plastic bumper beam subjected to low-velocity frontal impact

OpenAIRE

Yefa Hu; Can Liu; Jinguang Zhang; Guoping Ding; Qiong Wu

2015-01-01

Lightweight and safety performance of automobiles are two important factors for automobile designs. In this article, a research on lightweight and crashworthiness of automotive bumper has been conducted. The carbon fiber–reinforced plastic bumper beam is considered to replace the traditional high-strength steel one. The low-velocity impact finite element simulations for the above two bumper beams are performed via LS-DYNA. Furthermore, the energy absorption capabilities and dynamic response c...

REVIEW OF MECHANISTIC UNDERSTANDING AND MODELING AND UNCERTAINTY ANALYSIS METHODS FOR PREDICTING CEMENTITIOUS BARRIER PERFORMANCE

Energy Technology Data Exchange (ETDEWEB)

Langton, C.; Kosson, D.

2009-11-30

Cementitious barriers for nuclear applications are one of the primary controls for preventing or limiting radionuclide release into the environment. At the present time, performance and risk assessments do not fully incorporate the effectiveness of engineered barriers because the processes that influence performance are coupled and complicated. Better understanding the behavior of cementitious barriers is necessary to evaluate and improve the design of materials and structures used for radioactive waste containment, life extension of current nuclear facilities, and design of future nuclear facilities, including those needed for nuclear fuel storage and processing, nuclear power production and waste management. The focus of the Cementitious Barriers Partnership (CBP) literature review is to document the current level of knowledge with respect to: (1) mechanisms and processes that directly influence the performance of cementitious materials (2) methodologies for modeling the performance of these mechanisms and processes and (3) approaches to addressing and quantifying uncertainties associated with performance predictions. This will serve as an important reference document for the professional community responsible for the design and performance assessment of cementitious materials in nuclear applications. This review also provides a multi-disciplinary foundation for identification, research, development and demonstration of improvements in conceptual understanding, measurements and performance modeling that would be lead to significant reductions in the uncertainties and improved confidence in the estimating the long-term performance of cementitious materials in nuclear applications. This report identifies: (1) technology gaps that may be filled by the CBP project and also (2) information and computational methods that are in currently being applied in related fields but have not yet been incorporated into performance assessments of cementitious barriers. The various

Review Of Mechanistic Understanding And Modeling And Uncertainty Analysis Methods For Predicting Cementitious Barrier Performance

International Nuclear Information System (INIS)

Langton, C.; Kosson, D.

2009-01-01

Cementitious barriers for nuclear applications are one of the primary controls for preventing or limiting radionuclide release into the environment. At the present time, performance and risk assessments do not fully incorporate the effectiveness of engineered barriers because the processes that influence performance are coupled and complicated. Better understanding the behavior of cementitious barriers is necessary to evaluate and improve the design of materials and structures used for radioactive waste containment, life extension of current nuclear facilities, and design of future nuclear facilities, including those needed for nuclear fuel storage and processing, nuclear power production and waste management. The focus of the Cementitious Barriers Partnership (CBP) literature review is to document the current level of knowledge with respect to: (1) mechanisms and processes that directly influence the performance of cementitious materials (2) methodologies for modeling the performance of these mechanisms and processes and (3) approaches to addressing and quantifying uncertainties associated with performance predictions. This will serve as an important reference document for the professional community responsible for the design and performance assessment of cementitious materials in nuclear applications. This review also provides a multi-disciplinary foundation for identification, research, development and demonstration of improvements in conceptual understanding, measurements and performance modeling that would be lead to significant reductions in the uncertainties and improved confidence in the estimating the long-term performance of cementitious materials in nuclear applications. This report identifies: (1) technology gaps that may be filled by the CBP project and also (2) information and computational methods that are in currently being applied in related fields but have not yet been incorporated into performance assessments of cementitious barriers. The various

Application of Glass Fiber Waste Polypropylene Aggregate in Lightweight Concrete – thermal properties

Science.gov (United States)

Citek, D.; Rehacek, S.; Pavlik, Z.; Kolisko, J.; Dobias, D.; Pavlikova, M.

2018-03-01

Actual paper focus on thermal properties of a sustainable lightweight concrete incorporating high volume of waste polypropylene aggregate as partial substitution of natural aggregate. In presented experiments a glass fiber reinforced polypropylene (GFPP) which is a by-product of PP tubes production, partially substituted fine natural silica aggregate in 10, 20, 30, 40 and 50 mass %. Results were compared with a reference concrete mix without plastic waste in order to quantify the effect of GFPP use on concrete properties. Main material physical parameters were studied (bulk density, matrix density without air content, and particle size distribution). Especially a thermal transport and storage properties of GFPP were examined in dependence on compaction time. For the developed lightweight concrete, thermal properties were accessed using transient impulse technique, where the measurement was done in dependence on moisture content (from the fully water saturated state to dry state). It was found that the tested lightweight concrete should be prospective construction material possessing improved thermal insulation function and the reuse of waste plastics in concrete composition was beneficial both from the environmental and financial point of view.

ULTRA-LIGHTWEIGHT CEMENT

Energy Technology Data Exchange (ETDEWEB)

Fred Sabins

2001-10-23

The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses tasks performed in the fourth quarter as well as the other three quarters of the past year. The subjects that were covered in previous reports and that are also discussed in this report include: Analysis of field laboratory data of active cement applications from three oil-well service companies; Preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; Summary of pertinent information from Russian ultra-lightweight cement literature review; and Comparison of compressive strengths of ULHS systems using ultrasonic and crush methods Results reported from the fourth quarter include laboratory testing of ULHS systems along with other lightweight cement systems--foamed and sodium silicate slurries. These comparison studies were completed for two different densities (10.0 and 11.5 lb/gal) and three different field application scenarios. Additional testing included the mechanical properties of ULHS systems and other lightweight systems. Studies were also performed to examine the effect that circulation by centrifugal pump during mixing has on breakage of ULHS.

Chloride diffusion in partially saturated cementitious material

DEFF Research Database (Denmark)

Nielsen, Erik Pram; Geiker, Mette Rica

2003-01-01

The paper proposes a combined application of composite theory and Powers' model for microstructural development for the estimation of the diffusion coefficient as a function of the moisture content of a defect-free cementitious material. Measurements of chloride diffusion in mortar samples (440 kg...

Potential of Carbon Nanotube Reinforced Cement Composites as Concrete Repair Material

Directory of Open Access Journals (Sweden)

Tanvir Manzur

2016-01-01

Full Text Available Carbon nanotubes (CNTs are a virtually ideal reinforcing agent due to extremely high aspect ratios and ultra high strengths. It is evident from contemporary research that utilization of CNT in producing new cement-based composite materials has a great potential. Consequently, possible practical application of CNT reinforced cementitious composites has immense prospect in the field of applied nanotechnology within construction industry. Several repair, retrofit, and strengthening techniques are currently available to enhance the integrity and durability of concrete structures with cracks and spalling, but applicability and/or reliability is/are often limited. Therefore, there is always a need for innovative high performing concrete repair materials with good mechanical, rheological, and durability properties. Considering the mechanical properties of carbon nanotubes (CNTs and the test results of CNT reinforced cement composites, it is apparent that such composites could be used conveniently as concrete repair material. With this end in view, the applicability of multiwalled carbon nanotube (MWNT reinforced cement composites as concrete repair material has been evaluated in this study in terms of setting time, bleeding, and bonding strength (slant shear tests. It has been found that MWNT reinforced cement mortar has good prospective as concrete repair material since such composites exhibited desirable behavior in setting time, bleeding, and slant shear.

Overview Of The U.S. Department Of Energy And Nuclear Regulatory Commission Performance Assessment Approaches: Cementitious Barriers Partnership

International Nuclear Information System (INIS)

Langton, C.; Burns, H.

2009-01-01

Engineered barriers including cementitious barriers are used at sites disposing or contaminated with low-level radioactive waste to enhance performance of the natural environment with respect to controlling the potential spread of contaminants. Drivers for using cementitious barriers include: high radionuclide inventory, radionuclide characteristics (e.g., long half-live, high mobility due to chemical form/speciation, waste matrix properties, shallow water table, and humid climate that provides water for leaching the waste). This document comprises the first in a series of reports being prepared for the Cementitious Barriers Partnership. The document is divided into two parts which provide a summary of: (1) existing experience in the assessment of performance of cementitious materials used for radioactive waste management and disposal and (2) sensitivity and uncertainty analysis approaches that have been applied for assessments. Each chapter is organized into five parts: Introduction, Regulatory Considerations, Specific Examples, Summary of Modeling Approaches and Conclusions and Needs. The objective of the report is to provide perspective on the state of the practice for conducting assessments for facilities involving cementitious barriers and to identify opportunities for improvements to the existing approaches. Examples are provided in two contexts: (1) performance assessments conducted for waste disposal facilities and (2) performance assessment-like analyses (e.g., risk assessments) conducted under other regulatory regimes. The introductory sections of each section provide a perspective on the purpose of performance assessments and different roles of cementitious materials for radioactive waste management. Significant experience with assessments of cementitious materials associated with radioactive waste disposal concepts exists in the US Department of Energy Complex and the commercial nuclear sector. Recently, the desire to close legacy facilities has created

OVERVIEW OF THE U.S. DEPARTMENT OF ENERGY AND NUCLEAR REGULATORY COMMISSION PERFORMANCE ASSESSMENT APPROACHES: CEMENTITIOUS BARRIERS PARTNERSHIP

Energy Technology Data Exchange (ETDEWEB)

Langton, C.; Burns, H.

2009-05-29

Engineered barriers including cementitious barriers are used at sites disposing or contaminated with low-level radioactive waste to enhance performance of the natural environment with respect to controlling the potential spread of contaminants. Drivers for using cementitious barriers include: high radionuclide inventory, radionuclide characteristics (e.g., long half-live, high mobility due to chemical form/speciation, waste matrix properties, shallow water table, and humid climate that provides water for leaching the waste). This document comprises the first in a series of reports being prepared for the Cementitious Barriers Partnership. The document is divided into two parts which provide a summary of: (1) existing experience in the assessment of performance of cementitious materials used for radioactive waste management and disposal and (2) sensitivity and uncertainty analysis approaches that have been applied for assessments. Each chapter is organized into five parts: Introduction, Regulatory Considerations, Specific Examples, Summary of Modeling Approaches and Conclusions and Needs. The objective of the report is to provide perspective on the state of the practice for conducting assessments for facilities involving cementitious barriers and to identify opportunities for improvements to the existing approaches. Examples are provided in two contexts: (1) performance assessments conducted for waste disposal facilities and (2) performance assessment-like analyses (e.g., risk assessments) conducted under other regulatory regimes. The introductory sections of each section provide a perspective on the purpose of performance assessments and different roles of cementitious materials for radioactive waste management. Significant experience with assessments of cementitious materials associated with radioactive waste disposal concepts exists in the US Department of Energy Complex and the commercial nuclear sector. Recently, the desire to close legacy facilities has created

Using a centrifuge for quality control of pre-wetted lightweight aggregate in internally cured concrete

Science.gov (United States)

Miller, Albert E.

Early age shrinkage of cementitious systems can result in an increased potential for cracking which can lead to a reduction in service life. Early age shrinkage cracking can be particularly problematic for high strength concretes, which are often specified due to their high strength and low permeability. However, these high strength concretes frequently exhibit a reduction in the internal relative humidity (RH) due to the hydration reaction (chemical shrinkage) and self-desiccation which results in a bulk shrinkage, termed autogenous shrinkage, which is substantial at early ages. Due to the low permeability of these concretes, standard external curing is not always efficient in addressing this reduction in internal RH since the penetration of water can be limited. Internal curing has been developed to reduce autogenous shrinkage. Internally cured mixtures use internal reservoirs filled with fluid (generally water) that release this fluid at appropriate times to counteract the effects of self-desiccation thereby maintaining a high internal RH. Internally cured concrete is frequently produced in North America using pre-wetted lightweight aggregate. One important aspect associated with preparing quality internally cured concrete is being able to determine the absorbed moisture and surface moisture associated with the lightweight aggregate which enables aggregate moisture corrections to be made for the concrete mixture. This thesis represents work performed to develop a test method using a centrifuge to determine the moisture state of pre-wetted fine lightweight aggregate. The results of the test method are then used in a series of worksheets that were developed to assist field technicians when performing the tests and applying the results to a mixture design. Additionally, research was performed on superabsorbent polymers to assess their ability to be used as an internal curing reservoir.

Bond characteristics of steel fiber and deformed reinforcing steel bar embedded in steel fiber reinforced self-compacting concrete (SFRSCC)

Science.gov (United States)

Aslani, Farhad; Nejadi, Shami

2012-09-01

Steel fiber reinforced self-compacting concrete (SFRSCC) is a relatively new composite material which congregates the benefits of the self-compacting concrete (SCC) technology with the profits derived from the fiber addition to a brittle cementitious matrix. Steel fibers improve many of the properties of SCC elements including tensile strength, ductility, toughness, energy absorption capacity, fracture toughness and cracking. Although the available research regarding the influence of steel fibers on the properties of SFRSCC is limited, this paper investigates the bond characteristics between steel fiber and SCC firstly. Based on the available experimental results, the current analytical steel fiber pullout model (Dubey 1999) is modified by considering the different SCC properties and different fiber types (smooth, hooked) and inclination. In order to take into account the effect of fiber inclination in the pullout model, apparent shear strengths ( τ ( app)) and slip coefficient ( β) are incorporated to express the variation of pullout peak load and the augmentation of peak slip as the inclined angle increases. These variables are expressed as functions of the inclined angle ( ϕ). Furthurmore, steel-concrete composite floors, reinforced concrete floors supported by columns or walls and floors on an elastic foundations belong to the category of structural elements in which the conventional steel reinforcement can be partially replaced by the use of steel fibers. When discussing deformation capacity of structural elements or civil engineering structures manufactured using SFRSCC, one must be able to describe thoroughly both the behavior of the concrete matrix reinforced with steel fibers and the interaction between this composite matrix and discrete steel reinforcement of the conventional type. However, even though the knowledge on bond behavior is essential for evaluating the overall behavior of structural components containing reinforcement and steel fibers

Cementitious Composites Engineered with Embedded Carbon Nanotube Thin Films for Enhanced Sensing Performance

International Nuclear Information System (INIS)

Loh, Kenneth J; Gonzalez, Jesus

2015-01-01

Cementitious composites such as concrete pavements are susceptible to different damage modes, which are primarily caused by repeated loading and long-term deterioration. There is even greater concern that damage could worsen and occur more frequently with the use of heavier vehicles or new aircraft carrying greater payloads. Thus, the objective of this research is to engineer cementitious composites with capabilities of self-sensing or detecting damage. The approach was to enhance the damage sensitivity of cementitious composites by incorporating multi-walled carbon nanotubes (MWNT) as part of the mix design and during casting. However, as opposed to directly dispersing MWNTs in the cement matrix, which is the current state-of-art, MWNT-based thin films were airbrushed and coated onto sand particles. The film-coated sand was then used as part of the mix design for casting mortar specimens. Mortar specimens were subjected to compressive cyclic loading tests while their electrical properties were recorded simultaneously. The results showed that the electrical properties of these cementitious composites designed with film-coated sand exhibited extremely high strain sensitivities. The electrical response was also stable and consistent between specimens. (paper)

Cementitious Composites Engineered with Embedded Carbon Nanotube Thin Films for Enhanced Sensing Performance

Science.gov (United States)

Loh, Kenneth J.; Gonzalez, Jesus

2015-07-01

Cementitious composites such as concrete pavements are susceptible to different damage modes, which are primarily caused by repeated loading and long-term deterioration. There is even greater concern that damage could worsen and occur more frequently with the use of heavier vehicles or new aircraft carrying greater payloads. Thus, the objective of this research is to engineer cementitious composites with capabilities of self-sensing or detecting damage. The approach was to enhance the damage sensitivity of cementitious composites by incorporating multi-walled carbon nanotubes (MWNT) as part of the mix design and during casting. However, as opposed to directly dispersing MWNTs in the cement matrix, which is the current state-of-art, MWNT-based thin films were airbrushed and coated onto sand particles. The film-coated sand was then used as part of the mix design for casting mortar specimens. Mortar specimens were subjected to compressive cyclic loading tests while their electrical properties were recorded simultaneously. The results showed that the electrical properties of these cementitious composites designed with film-coated sand exhibited extremely high strain sensitivities. The electrical response was also stable and consistent between specimens.

About the possibility of obtaining cementitious soil composites of high strength on the basis of belozems of carbonate composition

Science.gov (United States)

Karapetyan, K. A.; Hayroyan, S. G.; Manukyan, E. S.

2018-04-01

The problem of manufacturing high strength cementitious soils based on belozems of carbonate composition, which experience compression (no less than 10 MPa), without application of surface active substances is considered. The portland cement of type 400 was used as a binding agent to develop compositions of cementitious soil composites, and the ordinary pipe water was used to obtain solutions of cementitious soils. The chemical and mineralogical composition of the initial ingredients and the granulometric composition of belozems were determined. The measurements showed that the upper and lower plasticity limits, the optimum moisture content, and the maximal density of the skeleton of belozems, as well as the considered compositions of cementitious soils, are insignificant, while the plasticity index of cementitious soils is less than one for belozems. It is experimentally proved that an increase in the portland cement amount lead to an increase in the compressive strength of cementitious soils with a decreasing speed. But for the same amount of portland cement used in the cementitious soil compositions, the values of the strength ratio of the pieces tested at the age of 60 and 28 days remain the same and are approximately equal to 1.2. A comparison of experimental data showed that it seems to be real to manufacture a cementitious soil on the basis of belozems of carbonate composition, which contain 10% of cement of the weight of dry mixture and have strength more than 10 MPa, without adding any surfactants to the material composition.

Finite element analysis of GFRP reinforced concrete pavement under static load

Science.gov (United States)

Li, Shiping; Hu, Chunhua

2018-02-01

GFRP was more corrosion resistant than traditional reinforced, it is lightweight, high strength thermal expansion coefficient is more close to the concrete and a poor conductor of electromagnetic. Therefore, the use of GFRP to replace the traditional reinforcement in concrete pavement application has excellent practical value. This paper uses ANSYS to establish delamination and reinforcement of Pavement model and analyzed response of GFRP concrete and ordinary concrete pavement structural mechanics on effects of different factors under the action of static. The results showed that under static load, pavement surface layer presented similar changes on stress of surface layer, vertical and horizontal deformation in two kinds of pavement structure, but indicators of GFRP reinforced concrete pavement were obviously better than that of ordinary concrete pavement.

Effect of different dispersants in compressive strength of carbon fiber cementitious composites

Science.gov (United States)

Lestari, Yulinda; Bahri, Saiful; Sugiarti, Eni; Ramadhan, Gilang; Akbar, Ari Yustisia; Martides, Erie; Khaerudini, Deni S.

2013-09-01

Carbon Fiber Cementitious Composites (CFCC) is one of the most important materials in smart concrete applications. CFCC should be able to have the piezoresistivity properties where its resistivity changes when there is applied a stress/strain. It must also have the compressive strength qualification. One of the important additives in carbon fiber cementitious composites is dispersant. Dispersion of carbon fiber is one of the key problems in fabricating piezoresistive carbon fiber cementitious composites. In this research, the uses of dispersants are methylcellulose, mixture of defoamer and methylcellulose and superplasticizer based polycarboxylate. The preparation of composite samples is similar as in the mortar technique according to the ASTM C 109/109M standard. The additives material are PAN type carbon fibers, methylcellulose, defoamer and superplasticizer (as water reducer and dispersant). The experimental testing conducts the compressive strength and resistivity at various curing time, i.e. 3, 7 and 28 days. The results obtained that the highest compressive strength value in is for the mortar using superplasticizer based polycarboxylate dispersant. This also shown that the distribution of carbon fiber with superplasticizer is more effective, since not reacting with the cementitious material which was different from the methylcellulose that creates the cement hydration reaction. The research also found that the CFCC require the proper water cement ratio otherwise the compressive strength becomes lower.

Development of textile-reinforced carbon fibre aluminium composites manufactured with gas pressure infiltration methods

OpenAIRE

W. Hufenbach; M. Gude; A. Czulak; J. Śleziona; A. Dolata-Grosz; M. Dyzia

2009-01-01

Purpose: The aim of his paper is to show potential of textile-reinforced carbon fibre aluminium composite with advantage of the lightweight construction of structural components subjected to thermo-mechanical stress.Design/methodology/approach: The manufacture of specimens of the carbon fibre-reinforced aluminium was realised with the aid of an advanced differential gas pressure infiltration technique, which was developed at ILK, TU Dresden.Findings: The gas pressure infiltration technology e...

Transport properties of damaged materials. Cementitious barriers partnership

Energy Technology Data Exchange (ETDEWEB)

Langton, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2014-11-01

The objective of the Cementitious Barriers Partnership (CBP) project is to develop tools to improve understanding and prediction of the long-term structural, hydraulic, and chemical performance of cementitious barriers used in low-level waste storage applications. One key concern for the long-term durability of concrete is the degradation of the cementitious matrix, which occurs as a result of aggressive chemical species entering the material or leaching out in the environment, depending on the exposure conditions. The objective of the experimental study described in this report is to provide experimental data relating damage in cementitious materials to changes in transport properties, which can eventually be used to support predictive model development. In order to get results within a reasonable timeframe and to induce as much as possible uniform damage level in materials, concrete samples were exposed to freezing and thawing (F/T) cycles. The methodology consisted in exposing samples to F/T cycles and monitoring damage level with ultrasonic pulse velocity measurements. Upon reaching pre-selected damage levels, samples were tested to evaluate changes in transport properties. Material selection for the study was motivated by the need to get results rapidly, in order to assess the relevance of the methodology. Consequently, samples already available at SIMCO from past studies were used. They consisted in three different concrete mixtures cured for five years in wet conditions. The mixtures had water-to-cement ratios of 0.5, 0.65 and 0.75 and were prepared with ASTM Type I cement only. The results showed that porosity is not a good indicator for damage caused by the formation of microcracks. Some materials exhibited little variations in porosity even for high damage levels. On the other hand, significant variations in tortuosity were measured in all materials. This implies that damage caused by internal pressure does not necessarily create additional pore space in

Transport properties of damaged materials. Cementitious barriers partnership

International Nuclear Information System (INIS)

Langton, C.

2014-01-01

The objective of the Cementitious Barriers Partnership (CBP) project is to develop tools to improve understanding and prediction of the long-term structural, hydraulic, and chemical performance of cementitious barriers used in low-level waste storage applications. One key concern for the long-term durability of concrete is the degradation of the cementitious matrix, which occurs as a result of aggressive chemical species entering the material or leaching out in the environment, depending on the exposure conditions. The objective of the experimental study described in this report is to provide experimental data relating damage in cementitious materials to changes in transport properties, which can eventually be used to support predictive model development. In order to get results within a reasonable timeframe and to induce as much as possible uniform damage level in materials, concrete samples were exposed to freezing and thawing (F/T) cycles. The methodology consisted in exposing samples to F/T cycles and monitoring damage level with ultrasonic pulse velocity measurements. Upon reaching pre-selected damage levels, samples were tested to evaluate changes in transport properties. Material selection for the study was motivated by the need to get results rapidly, in order to assess the relevance of the methodology. Consequently, samples already available at SIMCO from past studies were used. They consisted in three different concrete mixtures cured for five years in wet conditions. The mixtures had water-to-cement ratios of 0.5, 0.65 and 0.75 and were prepared with ASTM Type I cement only. The results showed that porosity is not a good indicator for damage caused by the formation of microcracks. Some materials exhibited little variations in porosity even for high damage levels. On the other hand, significant variations in tortuosity were measured in all materials. This implies that damage caused by internal pressure does not necessarily create additional pore space in

Electrochemical migration technique to accelerate ageing of cementitious materials

Directory of Open Access Journals (Sweden)

Abbas Z.

2013-07-01

Full Text Available Durability assessment of concrete structures for constructions in nuclear waste repositories requires long term service life predictions. As deposition of low and intermediate level radioactive waste (LILW takes up to 100 000 years, it is necessary to analyze the service life of cementitious materials in this time perspective. Using acceleration methods producing aged specimens would decrease the need of extrapolating short term data sets. Laboratory methods are therefore, needed for accelerating the ageing process without making any influencing distortion in the properties of the materials. This paper presents an electro-chemical migration method to increase the rate of calcium leaching from cementitious specimens. This method is developed based on the fact that major long term deterioration process of hardened cement paste in concrete structures for deposition of LILW is due to slow diffusion of calcium ions. In this method the cementitious specimen is placed in an electrochemical cell as a porous path way through which ions can migrate at a rate far higher than diffusion process. The electrical field is applied to the cell in a way to accelerate the ion migration without making destructions in the specimen’s micro and macroscopic properties. The anolyte and catholyte solutions are designed favoring dissolution of calcium hydroxide and compensating for the leached calcium ions with another ion like lithium.

Electrochemical migration technique to accelerate ageing of cementitious materials

Science.gov (United States)

Babaahmadi, A.; Tang, L.; Abbas, Z.

2013-07-01

Durability assessment of concrete structures for constructions in nuclear waste repositories requires long term service life predictions. As deposition of low and intermediate level radioactive waste (LILW) takes up to 100 000 years, it is necessary to analyze the service life of cementitious materials in this time perspective. Using acceleration methods producing aged specimens would decrease the need of extrapolating short term data sets. Laboratory methods are therefore, needed for accelerating the ageing process without making any influencing distortion in the properties of the materials. This paper presents an electro-chemical migration method to increase the rate of calcium leaching from cementitious specimens. This method is developed based on the fact that major long term deterioration process of hardened cement paste in concrete structures for deposition of LILW is due to slow diffusion of calcium ions. In this method the cementitious specimen is placed in an electrochemical cell as a porous path way through which ions can migrate at a rate far higher than diffusion process. The electrical field is applied to the cell in a way to accelerate the ion migration without making destructions in the specimen's micro and macroscopic properties. The anolyte and catholyte solutions are designed favoring dissolution of calcium hydroxide and compensating for the leached calcium ions with another ion like lithium.

Thermodynamics of Autogenous Self-healing in Cementitious Materials

NARCIS (Netherlands)

Huang, H.

2014-01-01

Concrete is a brittle composite cementitious material that easily fractures under tensile loading. Microcracks can appear throughout the concrete prior to application of any load because of temperature-induced strain and autogenous and drying shrinkage. There is no doubt that these cracks provide

Experimental Study of Reinforced Light Weight Concrete Beams

Directory of Open Access Journals (Sweden)

Hassanien Mohammed Thiyab

2016-12-01

Full Text Available This study provides a new technique for a lightweight concrete on one side and contribute to the application of sustainability principle by another side. The lightweight concrete was produced by replacing the coarse aggregate in the concrete mix by crushed bricks after conducting the sieve analysis process. To apply this technique to reinforced concrete beams, seven specimens having dimensions (1200 mm length × 200mm height × 100 mm width for each were poured. The first of these beams had made from ordinary concrete, and the rest lightweight different mix design as well as the casting of three cubes and a three-cylinder with each beam. After curing the specimens with water to the age 28 days, they were examined in the laboratory. Using different design mixes of concrete and with the help of super stabilizer material , good compressive strength of concrete was obtained so it become more effective lightweight in structure. By comparing between the results of the light and normal weight concrete beams, it is found reducing in the weight of concrete by about 23% due to using this technique ,the ultimate strength increased to about 32.1% and the deflection decreased about 46.7% .

ULTRA-LIGHTWEIGHT CEMENT

International Nuclear Information System (INIS)

Fred Sabins

2001-01-01

The objective of this project is to develop an improved ultra-lightweight cement using ultralight hollow glass spheres (ULHS). Work reported herein addresses Task 1: Assess Ultra-Lightweight Cementing Problems and Task 3: Test Ultra-Lightweight Cements. Results reported this quarter include a review and summary of Halliburton Energy Services (HES) and BJ Services historical performance data for lightweight cement applications. These data are analyzed and compared to ULHS cement and foamed cement performances. Similar data is expected from Schlumberger, and an analysis of this data will be completed in the following phases of the project. Quality control testing of materials used to formulate ULHS cements in the laboratory was completed to establish baseline material performance standards. A testing protocol was developed employing standard procedures as well as procedures tailored to evaluate ULHS and foamed cement. This protocol is presented and discussed. Results of further testing of ULHS cements are presented along with an analysis to establish cement performance design criteria to be used during the remainder of the project. Finally, a list of relevant literature on lightweight cement performance is compiled for review during the next quarter

Cementitious Barriers Partnership - FY2015 End-Year Report

International Nuclear Information System (INIS)

Burns, H. H.; Flach, G. P.; Langton, C. A.; Smith, F. G.; Kosson, D. S.; Meeussen, J. C. L.; Seignette, Paul; Van der Sloot, H. A.

2015-01-01

The DOE-EM Office of Tank Waste Management Cementitious Barriers Partnership (CBP) is chartered with providing the technical basis for implementing cement-based waste forms and radioactive waste containment structures for long-term disposal. Therefore, the CBP ultimate purpose is to support progress in final treatment and disposal of legacy waste and closure of High-Level Waste (HLW) tanks in the DOE complex. This status report highlights the CBP 2015 Software and Experimental Program efforts and accomplishments that support DOE needs in environmental cleanup and waste disposal. DOE needs in this area include: Long-term performance predictions to provide credibility (i.e., a defensible technical basis) for regulator and DOE review and approvals, Facility flow sheet development/enhancements, and Conceptual designs for new disposal facilities. In 2015, the CBP developed a beta release of the CBP Software Toolbox - ''Version 3.0'', which includes new STADIUM carbonation and damage models, a new SRNL module for estimating hydraulic properties and flow in fractured and intact cementitious materials, and a new LeachXS/ORCHESTRA (LXO) oxidation module. In addition, the STADIUM sulfate attack and chloride models have been improved as well as the LXO modules for sulfate attack, carbonation, constituent leaching, and percolation with radial diffusion (for leaching and transport in cracked cementitious materials). These STADIUM and LXO models are applicable to and can be used by both DOE and the Nuclear Regulatory Commission (NRC) end-users for service life prediction and long-term leaching evaluations of radioactive waste containment structures across the DOE complex.

Cementitious Barriers Partnership - FY2015 End-Year Report

Energy Technology Data Exchange (ETDEWEB)

Burns, H. H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Flach, G. P. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Langton, C. A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Smith, F. G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Kosson, D. S. [Vanderbilt Univ., Nashville, TN (United States). School of Engineering; Brown, K. G. [Vanderbilt Univ., Nashville, TN (United States). School of Engineering; Samson, E. [SIMCO Technologies, Inc., QC (Canada); Meeussen, J. C. L. [Nuclear Research and Consultancy Group (NRG); Seignette, Paul [Energy Research Center of the Netherlands; van der Sloot, H. A. [Hans van der Sloot Consultancy

2015-09-17

The DOE-EM Office of Tank Waste Management Cementitious Barriers Partnership (CBP) is chartered with providing the technical basis for implementing cement-based waste forms and radioactive waste containment structures for long-term disposal. Therefore, the CBP ultimate purpose is to support progress in final treatment and disposal of legacy waste and closure of High-Level Waste (HLW) tanks in the DOE complex. This status report highlights the CBP 2015 Software and Experimental Program efforts and accomplishments that support DOE needs in environmental cleanup and waste disposal. DOE needs in this area include: Long-term performance predictions to provide credibility (i.e., a defensible technical basis) for regulator and DOE review and approvals, Facility flow sheet development/enhancements, and Conceptual designs for new disposal facilities. In 2015, the CBP developed a beta release of the CBP Software Toolbox – “Version 3.0”, which includes new STADIUM carbonation and damage models, a new SRNL module for estimating hydraulic properties and flow in fractured and intact cementitious materials, and a new LeachXS/ORCHESTRA (LXO) oxidation module. In addition, the STADIUM sulfate attack and chloride models have been improved as well as the LXO modules for sulfate attack, carbonation, constituent leaching, and percolation with radial diffusion (for leaching and transport in cracked cementitious materials). These STADIUM and LXO models are applicable to and can be used by both DOE and the Nuclear Regulatory Commission (NRC) end-users for service life prediction and long-term leaching evaluations of radioactive waste containment structures across the DOE complex.

Properties of Fiber-Reinforced Mortars Incorporating Nano-Silica

Directory of Open Access Journals (Sweden)

Ahmed Ghazy

2016-02-01

Full Text Available Repair and rehabilitation of deteriorating concrete elements are of significant concern in many infrastructural facilities and remain a challenging task. Concerted research efforts are needed to develop repair materials that are sustainable, durable, and cost-effective. Research data show that fiber-reinforced mortars/concretes have superior performance in terms of volume stability and toughness. In addition, it has been recently reported that nano-silica particles can generally improve the mechanical and durability properties of cement-based systems. Thus, there has been a growing interest in the use of nano-modified fiber-reinforced cementitious composites/mortars (NFRM in repair and rehabilitation applications of concrete structures. The current study investigates various mechanical and durability properties of nano-modified mortar containing different types of fibers (steel, basalt, and hybrid (basalt and polypropylene, in terms of compressive and flexural strengths, toughness, drying shrinkage, penetrability, and resistance to salt-frost scaling. The results highlight the overall effectiveness of the NFRM owing to the synergistic effects of nano-silica and fibers.

Water absorption of superabsorbent polymers in a cementitious environment

DEFF Research Database (Denmark)

Jensen, Ole Mejlhede

2011-01-01

This paper focuses on the water absorption of superabsorbent polymers in a cementitious environment. The paper discusses different techniques to measure the water absorption capacity, and in particular it describes a technique which enables a simple and quick estimation of the water absorption...... capacity in a cementitious environment. The challenges met in defining the concept of water absorption capacity are treated, and the appropriateness of different types of superabsorbent polymers is also briefly dealt with. The concept “water absorption capacity” and its measurement seem straightforwardly...... simple, but a closer examination of the topic discloses many, significant difficulties. However, given proper cautiousness it is possible both to quickly estimate the water absorption capacity through a simple measurement as well as to examine how it will be influenced by different factors....

Use of Fiber-Reinforced Cements in Masonry Construction and Structural Rehabilitation

Directory of Open Access Journals (Sweden)

Ece Erdogmus

2015-02-01

Full Text Available The use of fiber reinforcement in traditional concrete mixes has been extensively studied and has been slowly finding its regular use in practice. In contrast, opportunities for the use of fibers in masonry applications and structural rehabilitation projects (masonry and concrete structures have not been as deeply investigated, where the base matrix may be a weaker cementitious mixture. This paper will summarize the findings of the author’s research over the past 10 years in these particular applications of fiber reinforced cements (FRC. For masonry, considering both mortar and mortar-unit bond characteristics, a 0.5% volume fraction of micro fibers in type N Portland cement lime mortar appear to be a viable recipe for most masonry joint applications both for clay and concrete units. In general, clay units perform better with high water content fiber reinforced mortar (FRM while concrete masonry units (CMUs perform better with drier mixtures, so 130% and 110% flow rates should be targeted, respectively. For earth block masonry applications, fibers’ benefits are observed in improving local damage and water pressure resistance. The FRC retrofit technique proposed for the rehabilitation of reinforced concrete two-way slabs has exceeded expectations in terms of capacity increase for a relatively low cost in comparison to the common but expensive fiber reinforced polymer applications. For all of these applications of fiber-reinforced cements, further research with larger data pools would lead to further optimization of fiber type, size, and amount.

Applications of graphite-enabled phase change material composites to improve thermal performance of cementitious materials

Science.gov (United States)

Li, Mingli; Lin, Zhibin; Wu, Lili; Wang, Jinhui; Gong, Na

2017-11-01

Enhancing the thermal efficiency to decrease the energy consumption of structures has been the topic of much research. In this study, a graphite-enabled microencapsulated phase change material (GE-MEPCM) was used in the production of a novel thermal energy storage engineered cementitious composite feathering high heat storage capacity and enhanced thermal conductivity. The surface morphology and particle size of the microencapsulated phase change material (MEPCM) were investigated by scanning electron microscopy (SEM). Thermal properties of MEPCM was determined using differential scanning calorimetry (DSC). In addition, thermal and mechanical properties of the cementitious mortar with different admixtures were explored and compared with those of a cementitious composite. It was shown that the latent heat of MEPCM was 162 J/g, offering much better thermal energy storage capacity to the cementitious composite. However, MEPCM was found to decrease the thermal conductivity of the composite, which can be effectively solved by adding natural graphite (NG). Moreover, the incorporation of MEPCM has a certain decrease in the compressive strength, mainly due to the weak interfaces between MEPCM and cement matrix.

Cellulose nanomaterials as additives for cementitious materials

Science.gov (United States)

Tengfei Fu; Robert J. Moon; Pablo Zavatierri; Jeffrey Youngblood; William Jason Weiss

2017-01-01

Cementitious materials cover a very broad area of industries/products (buildings, streets and highways, water and waste management, and many others; see Fig. 20.1). Annual production of cements is on the order of 4 billion metric tons [2]. In general these industries want stronger, cheaper, more durable concrete, with faster setting times, faster rates of strength gain...

Monitoring reinforcement corrosion and corrosion-induced cracking using non-destructive x-ray attenuation measurements

DEFF Research Database (Denmark)

Michel, Alexander; Pease, Bradley Justin; Geiker, Mette Rica

2011-01-01

To test the applicability of the x-ray attenuation method to monitor the movement of corrosion products as well as the formation and propagation of cracks in cementitious materials reinforced mortar samples were prepared and tested under accelerated corrosion conditions. It is evident from the ex...... of the corrosion products averaged through the specimen thickness. The total mass loss of steel, obtained by the x-ray attenuation method, was found to be in very good agreement with the mass loss obtained by gravimetric method as well as Faraday's law....

Development of PLA hybrid yarns for biobased self-reinforced polymer composites

Science.gov (United States)

Köhler, T.; Gries, T.; Seide, G.

2017-10-01

Lightweight materials are a necessity in various industries. Lightweight design is in the key interest of the mobility sector, e.g. the automotive and aerospace industry. This trend applies also for the consumer industries, e.g. sporting goods. In addition, the worldwide demand for replacing fossil-based materials has led to a significant growth of bioplastics. Due to their low mechanical performance and durability, their use is still limited. Therefore, it is necessary to develop biobased, sustainable polymeric materials with high stiffness, high impact and high durability without impairing recyclability at a similar price level of non-biobased solutions. Biobased self-reinforced polymer composites offer these unique properties.

Use of hyghly reactive rice husk ash in the production of cement matrix reinforced with Green coconut fiber

OpenAIRE

Pereira, C.L.; Savastano, H. Jr; Paya Bernabeu, Jorge Juan; Santos, S. F.; Borrachero Rosado, María Victoria; Monzó Balbuena, José Mª; Soriano Martinez, Lourdes

2013-01-01

This study evaluated the influence of partial replacement of Portland cement by rice husk ash (RHA) to enable the use of green coconut husk fiber as reinforcement for cementitious matrix. The use of highly reactive pozzolanic ash contributes for decreasing the alkaline attack on the vegetable fiber, originated from waste materials. The slurry dewatering technique was used for dispersion of the raw materials in aqueous solution, followed by vacuum drainage of water and pressing for the product...

Predicting Mechanical Properties of Metal Matrix Syntactic Foams Reinforced with Ceramic Spheres

Science.gov (United States)

2012-01-01

predicting the properties of interest listed above. Kiser et al. [12] extended a metal foam model to account for ceramic reinforcement to predict the...Daoud A. J Alloys Compd. 2009; 487:618. 11. Drury WJ, Rickles SA, Sanders Jr TH, Cochran JK. In Light-Weight Alloys for Aerospace Applications, ed. Loe

Self Healing Fibre-reinforced Polymer Composites: an Overview

Science.gov (United States)

Bond, Ian P.; Trask, Richard S.; Williams, Hugo R.; Williams, Gareth J.

Lightweight, high-strength, high-stiffness fibre-reinforced polymer composite materials are leading contenders as component materials to improve the efficiency and sustainability of many forms of transport. For example, their widespread use is critical to the success of advanced engineering applications, such as the Boeing 787 and Airbus A380. Such materials typically comprise complex architectures of fine fibrous reinforcement e.g. carbon or glass, dispersed within a bulk polymer matrix, e.g. epoxy. This can provide exceptionally strong, stiff, and lightweight materials which are inherently anisotropic, as the fibres are usually arranged at a multitude of predetermined angles within discrete stacked 2D layers. The direction orthogonal to the 2D layers is usually without reinforcement to avoid compromising in-plane performance, which results in a vulnerability to damage in the polymer matrix caused by out-of-plane loading, i.e. impact. Their inability to plastically deform leaves only energy absorption via damage creation. This damage often manifests itself internally within the material as intra-ply matrix cracks and inter-ply delaminations, and can thus be difficult to detect visually. Since relatively minor damage can lead to a significant reduction in strength, stiffness and stability, there has been some reticence by designers for their use in safety critical applications, and the adoption of a `no growth' approach (i.e. damage propagation from a defect constitutes failure) is now the mindset of the composites industry. This has led to excessively heavy components, shackling of innovative design, and a need for frequent inspection during service (Richardson 1996; Abrate 1998).

Lightweight, fire-retardant, crashworthy aircraft seat cushioning

Science.gov (United States)

Haslim, Leonard A.; Mcdonough, Paul T.

1991-01-01

A two page discussion of non-aerospace seating applications and the design of NASA's safety seat cushioning (SSC) is presented. The SSC was designed for both safety and comfort in order to replace polyurethane cushioning which is flammable and produces lethal fumes upon combustion. The SSC is composed of advanced fabric reinforced composites and is lightweight, fire-retardent, and crashworthy. The seat design consists of central elliptical tubular spring supports made of fire-resistant and fatigue-durable composites surrounded by a fire-blocking sheath. The cushioning is made crashworthy by incorporating energy-absorbing, viscoelastic layers between the nested, elliptical-hoop springs. The design is intended to provide comfortable seating that meets aircraft-loading requirements without using the conventional polyurethane materials. The designs of an aircraft seat and structural components of the SSC are also presented.

The effect of nitrates on the alteration of the cementitious material

International Nuclear Information System (INIS)

Takei, Akihiko; Owada, Hitoshi; Fujita, Hideki; Negishi, Kumi

2002-02-01

TRU waste includes various chemical compounds such as nitrates. The influence of the chemical compounds on the performance of the barrier system should be estimated. Since the temperature of the deep-underground is higher than that of the near surface and a part of the TRU waste generates the heat accompanied with the decay of the radioactive nuclides, the influences of the heat to the barrier material also should be taken into account. In this study, we estimated the influence of sodium nitrate and also that of the leachate from the ROBE-waste (borate-solidified body of concentrated low-level waste) to the degradation of the cementitious material. We also obtained the mineralogical data of cementitious mineral after alteration in elevated temperature conditions. Results in this year are described below. 1) Alteration of characteristics of cementitious material in nitrate solution were evaluated by the water permeation test using sodium nitrate solution. The enhancement of the alteration of cementitious material due to sodium nitrate was observed. The dissolution quantity of the calcium of sodium nitrate solution permeated sample was larger than that of deionized water permeated sample (denoted as 'blank' in following). Hydraulic conductivity of sodium nitrate solution permeated sample was lower than blank, but after changing permeation liquid from sodium nitrate solution to deionized water, hydraulic conductivity rose quickly. The increase of porosity and the decrease of compressive strength were observed in the case of sodium nitrate solution compared with blank. In the nitrate solution, sulfate type and carbonate type of AFm changed into the nitrate type AFm. The nitrate type AFm altered to the carbonate type AFm when the nitrate concentration was lowered. 2) The influence of the leachate from the two types of ROBE-waste on the dissolution of the cementitious material was evaluated by the leaching experiments. Dissolution of the calcium from the cementitious

Light-weight plastination.

Science.gov (United States)

Steinke, Hanno; Rabi, Suganthy; Saito, Toshiyuki; Sawutti, Alimjan; Miyaki, Takayoshi; Itoh, Masahiro; Spanel-Borowski, Katharina

2008-11-20

Plastination is an excellent technique which helps to keep the anatomical specimens in a dry, odourless state. Since the invention of plastination technique by von Hagens, research has been done to improve the quality of plastinated specimens. In this paper, we have described a method of producing light-weight plastinated specimens using xylene along with silicone and in the final step, substitute xylene with air. The finished plastinated specimens were light-weight, dry, odourless and robust. This method requires less use of resin thus making the plastination technique more cost-effective. The light-weight specimens are easy to carry and can easily be used for teaching.

Mechanical Properties of High Performance Cementitious Grout (II)

DEFF Research Database (Denmark)

Sørensen, Eigil V.

The present report is an update of the report “Mechanical Properties of High Performance Cementitious Grout (I)” [1] and describes tests carried out on the high performance grout MASTERFLOW 9500, marked “WMG 7145 FP”, developed by BASF Construction Chemicals A/S and designed for use in grouted...

Degradation Of Cementitious Materials Associated With Saltstone Disposal Units

International Nuclear Information System (INIS)

Flach, G. P; Smith, F. G. III

2013-01-01

The Saltstone facilities at the DOE Savannah River Site (SRS) stabilize and dispose of low-level radioactive salt solution originating from liquid waste storage tanks at the site. The Saltstone Production Facility (SPF) receives treated salt solution and mixes the aqueous waste with dry cement, blast furnace slag, and fly ash to form a grout slurry which is mechanically pumped into concrete disposal cells that compose the Saltstone Disposal Facility (SDF). The solidified grout is termed ''saltstone''. Cementitious materials play a prominent role in the design and long-term performance of the SDF. The saltstone grout exhibits low permeability and diffusivity, and thus represents a physical barrier to waste release. The waste form is also reducing, which creates a chemical barrier to waste release for certain key radionuclides, notably Tc-99. Similarly, the concrete shell of an SDF disposal unit (SDU) represents an additional physical and chemical barrier to radionuclide release to the environment. Together the waste form and the SDU compose a robust containment structure at the time of facility closure. However, the physical and chemical state of cementitious materials will evolve over time through a variety of phenomena, leading to degraded barrier performance over Performance Assessment (PA) timescales of thousands to tens of thousands of years. Previous studies of cementitious material degradation in the context of low-level waste disposal have identified sulfate attack, carbonation influenced steel corrosion, and decalcification (primary constituent leaching) as the primary chemical degradation phenomena of most relevance to SRS exposure conditions. In this study, degradation time scales for each of these three degradation phenomena are estimated for saltstone and concrete associated with each SDU type under conservative, nominal, and best estimate assumptions. The nominal value (NV) is an intermediate result that is more probable than the conservative estimate

Degradation Of Cementitious Materials Associated With Saltstone Disposal Units

Energy Technology Data Exchange (ETDEWEB)

Flach, G. P; Smith, F. G. III

2013-03-19

The Saltstone facilities at the DOE Savannah River Site (SRS) stabilize and dispose of low-level radioactive salt solution originating from liquid waste storage tanks at the site. The Saltstone Production Facility (SPF) receives treated salt solution and mixes the aqueous waste with dry cement, blast furnace slag, and fly ash to form a grout slurry which is mechanically pumped into concrete disposal cells that compose the Saltstone Disposal Facility (SDF). The solidified grout is termed “saltstone”. Cementitious materials play a prominent role in the design and long-term performance of the SDF. The saltstone grout exhibits low permeability and diffusivity, and thus represents a physical barrier to waste release. The waste form is also reducing, which creates a chemical barrier to waste release for certain key radionuclides, notably Tc-99. Similarly, the concrete shell of an SDF disposal unit (SDU) represents an additional physical and chemical barrier to radionuclide release to the environment. Together the waste form and the SDU compose a robust containment structure at the time of facility closure. However, the physical and chemical state of cementitious materials will evolve over time through a variety of phenomena, leading to degraded barrier performance over Performance Assessment (PA) timescales of thousands to tens of thousands of years. Previous studies of cementitious material degradation in the context of low-level waste disposal have identified sulfate attack, carbonation influenced steel corrosion, and decalcification (primary constituent leaching) as the primary chemical degradation phenomena of most relevance to SRS exposure conditions. In this study, degradation time scales for each of these three degradation phenomena are estimated for saltstone and concrete associated with each SDU type under conservative, nominal, and best estimate assumptions. The nominal value (NV) is an intermediate result that is more probable than the conservative

Engineering feasibility for the fabrication and emplacement of cementitious repository materials: results from the EC-ESDRED project

International Nuclear Information System (INIS)

Alonso, Maria Cruz; Garcia-Sineriz, Jose Luis

2012-01-01

Maria Cruz Alonso of the Spanish National Research Council gave a presentation that summarised relevant findings on cementitious materials from the EC ESDRED (Engineering Studies and Demonstration of Repository Designs) Project. Concrete will be used for different purposes during the construction of geologic repositories for radioactive waste. These purposes include grouting, tunnel and drift lining, and tunnel plugging and sealing. Although some of the concrete may be removed before repository closure, a significant amount of concrete will remain in the repository. An important concern regarding the use of cementitious materials in geologic repositories for HLW and spent fuel is their interaction with the bentonite buffer, backfill material, and the host rock close to the repository near-field. For this reason, the ESDRED project has developed a low-pH concrete formulation as an alternative to standard ordinary Portland cement (OPC) concrete formulations with the aim of reducing the interaction of the cementitious materials with the near-field components. The main functional requirement required in the development of the low-pH material was a pore fluid pH < 11, which is considered acceptable for preventing or reducing the alteration of the bentonite EBS. Other functional requirements considered in the development of the low-pH concrete were: - Hydraulic conductivity. - Mechanical properties. - Durability. - Workability and pumpability. - Slumping. - Peak hydration temperature. - Thermal conductivity. - Use of organic components. - Use of other products. The development of the low-pH concrete involved laboratory work, as well as field testing at the Aespoe underground research laboratory (URL) in Sweden, and in the Grimsel URL and at the Hagerbach site in Switzerland. The ESDRED project demonstrated that low-pH cements can be formulated and used for production of concrete plugs and rock support. OPC can be used as the cement included in low-pH blends, but at least

Development and Demonstration of Material Properties Database and Software for the Simulation of Flow Properties in Cementitious Materials

Energy Technology Data Exchange (ETDEWEB)

Smith, F. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Flach, G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2015-03-30

This report describes work performed by the Savannah River National Laboratory (SRNL) in fiscal year 2014 to develop a new Cementitious Barriers Project (CBP) software module designated as FLOExcel. FLOExcel incorporates a uniform database to capture material characterization data and a GoldSim model to define flow properties for both intact and fractured cementitious materials and estimate Darcy velocity based on specified hydraulic head gradient and matric tension. The software module includes hydraulic parameters for intact cementitious and granular materials in the database and a standalone GoldSim framework to manipulate the data. The database will be updated with new data as it comes available. The software module will later be integrated into the next release of the CBP Toolbox, Version 3.0. This report documents the development efforts for this software module. The FY14 activities described in this report focused on the following two items that form the FLOExcel package; 1) Development of a uniform database to capture CBP data for cementitious materials. In particular, the inclusion and use of hydraulic properties of the materials are emphasized; and 2) Development of algorithms and a GoldSim User Interface to calculate hydraulic flow properties of degraded and fractured cementitious materials. Hydraulic properties are required in a simulation of flow through cementitious materials such as Saltstone, waste tank fill grout, and concrete barriers. At SRNL these simulations have been performed using the PORFLOW code as part of Performance Assessments for salt waste disposal and waste tank closure.

CEMENTITIOUS BARRIERS MODELING FOR PERFORMANCE ASSESSMENTS OF SHALLOW LAND BURIAL OF LOW LEVEL RADIOACTIVE WASTE - 9243

International Nuclear Information System (INIS)

Taylor, G.

2009-01-01

The Cementitious Barriers Partnership (CBP) was created to develop predictive capabilities for the aging of cementitious barriers over long timeframes. The CBP is a multi-agency, multi-national consortium working under a U.S. Department of Energy (DOE) Environmental Management (EM-21) funded Cooperative Research and Development Agreement (CRADA) with the Savannah River National Laboratory (SRNL) as the lead laboratory. Members of the CBP are SRNL, Vanderbilt University, the U.S. Nuclear Regulatory Commission (USNRC), National Institute of Standards and Technology (NIST), SIMCO Technologies, Inc. (Canada), and the Energy Research Centre of the Netherlands (ECN). A first step in developing advanced tools is to determine the current state-of-the-art. A review has been undertaken to assess the treatment of cementitious barriers in Performance Assessments (PA). Representatives of US DOE sites which have PAs for their low level waste disposal facilities were contacted. These sites are the Idaho National Laboratory, Oak Ridge National Laboratory, Los Alamos National Laboratory, Nevada Test Site, and Hanford. Several of the more arid sites did not employ cementitious barriers. Of those sites which do employ cementitious barriers, a wide range of treatment of the barriers in a PA was present. Some sites used conservative, simplistic models that even though conservative still showed compliance with disposal limits. Other sites used much more detailed models to demonstrate compliance. These more detailed models tend to be correlation-based rather than mechanistically-based. With the US DOE's Low Level Waste Disposal Federal Review Group (LFRG) moving towards embracing a risk-based, best estimate with an uncertainties type of analysis, the conservative treatment of the cementitious barriers seems to be obviated. The CBP is creating a tool that adheres to the LFRG chairman's paradigm of continuous improvement

Reinforcing method for reinforced concrete structures by using carbon fibers; Tanso sen`i ni yoru tekkin concrete kozobutsu no hokyo koho

Energy Technology Data Exchange (ETDEWEB)

Tanaka, T.; Taniki, K. [Mitsubishi Kasei Corp., Tokyo (Japan); Kojima, N.; Kimura, K.; Katsumata, H. [Obayashi Corp., Osaka (Japan)

1994-08-15

This paper describes the development of a reinforcing method for reinforced concrete (hereinafter RC) structures by using carbon fibers (hereinafter CF). This developed method attaches a light-weight CFUD prepreg material for reinforcement by laterally winding CF strand impregnated with epoxy resin, which is hardened under normal temperature. This method is economical because no skills and special tools are required. An RC pillar with circular cross section and a hollow RC test body assuming a chimney were used as models. The paper details the experiment. This method has been used in several ten existing RC stacks with effective reinforcing result. Resistance strengths of CF strands and UD prepregs were verified in an accelerated exposure test performed according to JIS A 1415, standard for plastic building materials. The effects of the anti-seismic reinforcement have resulted in improvement in shear resistance force in RC pillars by means of CF winding method, improvement in bending stress in RC structures as a result of CF attaching method, and effectiveness in repair of existing RC stacks. Sufficient exposure resistance has also been proved. A bending test by means of two-point concentrated loading has been performed as a weighted test. 4 figs.

Self-cementitious properties of fly ashes from CFBC boilers co-firing coal and high-sulphur petroleum coke

International Nuclear Information System (INIS)

Sheng Guanghong; Li Qin; Zhai Jianping; Li Feihu

2007-01-01

Self-cementitious properties of fly ash from circulating fluidized bed combustion boiler co-firing coal and high-sulphur petroleum coke (CPFA) were investigated. CPFA was self-cementitious which was affected by its fineness and chemical compositions, especially the contents of SO 3 and free lime (f-CaO). Higher contents of SO 3 and f-CaO were beneficial to self-cementitious strength; the self-cementitious strength increases with a decrease of its 45 μm sieve residue. The expansive ratio of CPFA hardened paste was high because of generation of ettringite (AFt), which was influenced by its water to binder ratio (W/A), curing style and grinding of the ash. The paste cured in water had the highest expansive ratio, and grinding of CPFA was beneficial to its volume stability. The hydration products of CPFA detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM) were portlandite, gypsum, AFt and hydrated calcium silicate (C-S-H)

Hydration characteristics and environmental friendly performance of a cementitious material composed of calcium silicate slag

Energy Technology Data Exchange (ETDEWEB)

Zhang, Na; Li, Hongxu [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Beijing Key Laboratory of Rare and Precious Metals Green Recycling and Extraction, University of Science and Technology Beijing, Beijing 100083 (China); Zhao, Yazhao [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Liu, Xiaoming, E-mail: liuxm@ustb.edu.cn [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Beijing Key Laboratory of Rare and Precious Metals Green Recycling and Extraction, University of Science and Technology Beijing, Beijing 100083 (China)

2016-04-05

Highlights: • Cementitious material was designed according to [SiO{sub 4}] polymerization degree of raw materials. • The cementitious material composed of calcium silicate slag yields excellent physical and mechanical properties. • Amorphous C–A–S–H gel and rod-like ettringite are predominantly responsible for the strength development. • Leaching toxicity and radioactivity tests show the cementitious material is environmentally acceptable. - Abstract: Calcium silicate slag is an alkali leaching waste generated during the process of extracting Al{sub 2}O{sub 3} from high-alumina fly ash. In this research, a cementitious material composed of calcium silicate slag was developed, and its mechanical and physical properties, hydration characteristics and environmental friendly performance were investigated. The results show that an optimal design for the cementitious material composed of calcium silicate slag was determined by the specimen CFSC7 containing 30% calcium silicate slag, 5% high-alumina fly ash, 24% blast furnace slag, 35% clinker and 6% FGD gypsum. This blended system yields excellent physical and mechanical properties, confirming the usefulness of CFSC7. The hydration products of CFSC7 are mostly amorphous C–A–S–H gel, rod-like ettringite and hexagonal-sheet Ca(OH){sub 2} with small amount of zeolite-like minerals such as CaAl{sub 2}Si{sub 2}O{sub 8}·4H{sub 2}O and Na{sub 2}Al{sub 2}Si{sub 2}O{sub 8}·H{sub 2}O. As the predominant hydration products, rod-like ettringite and amorphous C–A–S–H gel play a positive role in promoting densification of the paste structure, resulting in strength development of CFSC7 in the early hydration process. The leaching toxicity and radioactivity tests results indicate that the developed cementitious material composed of calcium silicate slag is environmentally acceptable. This study points out a promising direction for the proper utilization of calcium silicate slag in large quantities.

A combined wet chemistry and EXAFS study of U(VI) uptake by cementitious materials

International Nuclear Information System (INIS)

Wieland, E.; Harfouche, M.; Tits, J.; Kunz, D.; Daehn, R.; Fujita, T.; Tsukamoto, M.

2006-01-01

The sorption behaviour and speciation of U(VI) in cementitious systems was investigated by a combination of wet chemistry experiments and synchrotron-based X-ray absorption spectroscopy (XAS) measurements. Radiotracer studies using 233 U were carried out on hardened cement paste (HCP) and calcium silicate hydrates (C-S-H), which are the major constituents of HCP, to determine the uptake kinetics and sorption isotherms. C-S-H phases were synthesized using different methods for solid phase preparation, which enabled us to study the U(VI) uptake by different types of C-S-H phases and a wide range of Ca/Si compositions, and to distinguish U(VI) sorption on the surface of C-S-H from U(VI) incorporation into the structure. XAS measurements were performed using U(VI) loaded HCP and C-S-H materials (sorption and co-precipitation samples) to gain structural information on the U(VI) speciation in these systems, i.e., the type and number of neighbouring atoms, and bond distances. Examples of studies that have utilized XAS to characterize U(VI) speciation in cementitious systems are still rare, and to the best of our knowledge, detailed XAS investigations of the U(VI)/C-S-H system are lacking. The results obtained from the combined use of wet chemical and spectroscopic techniques allow mechanistic models of the immobilization process to be proposed for cementitious waste forms containing low and high U(VI) inventories. In the latter case U(VI) immobilization is controlled by a solubility-limiting process with the U(VI) mineral predominantly formed under the conditions prevailing in cementitious systems. At low U(VI) concentrations, however, U(VI) appears to be predominantly bound onto C-S-H phases. The coordination environment of U(VI) taken up by C-S-H was found to resemble that of U(VI) in uranophane. A mechanistic understanding of the U(VI) binding by cementitious materials will allow more detailed and scientifically well founded predictions of the retention of

Hydration mechanism and leaching behavior of bauxite-calcination-method red mud-coal gangue based cementitious materials

International Nuclear Information System (INIS)

Zhang, Na; Li, Hongxu; Liu, Xiaoming

2016-01-01

Highlights: • Nanocrystalline regions in size of ∼5 nm were found in the amorphous C-A-S-H gel. • A hydration model was proposed to clarify the hydration mechanism. • The developed cementitious materials are environmentally acceptable. - Abstract: A deep investigation on the hydration mechanism of bauxite-calcination-method red mud-coal gangue based cementitious materials was conducted from viewpoints of hydration products and hydration heat analysis. As a main hydration product, the microstructure of C-A-S-H gel was observed using high resolution transmission electron microscopy. It was found that the C-A-S-H gel is composed of amorphous regions and nanocrystalline regions. Most of regions in the C-A-S-H gel are amorphous with continuous distribution, and the nanocrystalline regions on scale of ∼5 nm are dispersed irregularly within the amorphous regions. The hydration heat of red mud-coal gangue based cementitious materials is much lower than that of the ordinary Portland cement. A hydration model was proposed for this kind of cementitious materials, and the hydration process mainly consists of four stages which are dissolution of materials, formation of C-A-S-H gels and ettringite, cementation of hydration products, and polycondensation of C-A-S-H gels. There are no strict boundaries among these four basic stages, and they proceed crossing each other. Moreover, the leaching toxicity tests were also performed to prove that the developed red mud-coal gangue based cementitious materials are environmentally acceptable.

Hydration mechanism and leaching behavior of bauxite-calcination-method red mud-coal gangue based cementitious materials

Energy Technology Data Exchange (ETDEWEB)

Zhang, Na; Li, Hongxu [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Beijing Key Laboratory of Rare and Precious Metals Green Recycling and Extraction, University of Science and Technology Beijing, Beijing 100083 (China); Liu, Xiaoming, E-mail: liuxm@ustb.edu.cn [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Beijing Key Laboratory of Rare and Precious Metals Green Recycling and Extraction, University of Science and Technology Beijing, Beijing 100083 (China)

2016-08-15

Highlights: • Nanocrystalline regions in size of ∼5 nm were found in the amorphous C-A-S-H gel. • A hydration model was proposed to clarify the hydration mechanism. • The developed cementitious materials are environmentally acceptable. - Abstract: A deep investigation on the hydration mechanism of bauxite-calcination-method red mud-coal gangue based cementitious materials was conducted from viewpoints of hydration products and hydration heat analysis. As a main hydration product, the microstructure of C-A-S-H gel was observed using high resolution transmission electron microscopy. It was found that the C-A-S-H gel is composed of amorphous regions and nanocrystalline regions. Most of regions in the C-A-S-H gel are amorphous with continuous distribution, and the nanocrystalline regions on scale of ∼5 nm are dispersed irregularly within the amorphous regions. The hydration heat of red mud-coal gangue based cementitious materials is much lower than that of the ordinary Portland cement. A hydration model was proposed for this kind of cementitious materials, and the hydration process mainly consists of four stages which are dissolution of materials, formation of C-A-S-H gels and ettringite, cementation of hydration products, and polycondensation of C-A-S-H gels. There are no strict boundaries among these four basic stages, and they proceed crossing each other. Moreover, the leaching toxicity tests were also performed to prove that the developed red mud-coal gangue based cementitious materials are environmentally acceptable.

Flexural behavior of the fibrous cementitious composites (FCC) containing hybrid fibres

Science.gov (United States)

Ramli, Mahyuddin; Ban, Cheah Chee; Samsudin, Muhamad Fadli

2018-02-01

In this study, the flexural behavior of the fibrous cementitious composites containing hybrid fibers was investigated. Waste materials or by product materials such as pulverized fuel ash (PFA) and ground granulated blast-furnace slag (GGBS) was used as supplementary cement replacement. In addition, barchip and kenaf fiber will be used as additional materials for enhance the flexural behavior of cementitious composites. A seven mix design of fibrous cementitious composites containing hybrid fiber mortar were fabricated with PFA-GGBS as cement replacement at 50% with hybridization of barchip and kenaf fiber between 0.5% and 2.0% by total volume weight. The FCC with hybrid fibers mortar will be fabricated by using 50 × 50 × 50 mm, 40 × 40 × 160 mm and 350 × 125 × 30 mm steel mold for assessment of mechanical performances and flexural behavior characteristics. The flexural behavior and mechanical performance of the PFA-GGBS with hybrid fiber mortar block was assessed in terms of load deflection response, stress-strain response, crack development, compressive and flexural strength after water curing for 28 days. Moreover, the specimen HBK 1 and HBK 2 was observed equivalent or better in mechanical performance and flexural behavior as compared to control mortar.

Technetium Sorption By Cementitious Materials Under Reducing Conditions

International Nuclear Information System (INIS)

Kaplan, Daniel I.; Estes, Shanna L.; Arai, Yuji; Powell, Brian A.

2013-01-01

The objective of this study was to measure Tc sorption to cementitious materials under reducing conditions to simulate Saltstone Disposal Facility conditions. Earlier studies were conducted and the experimental conditions were found not to simulate those of the facility. Through a five month subcontract with Clemson University, sorption of 99 Tc to four cementitious materials was examined within an anaerobic glovebag targeting a 0.1% H 2 (g)/ 99.9% N 2 (g) atmosphere. Early experiments based on Tc sorption and Eh indicated that 0.1% H 2 (g) (a reductant) was necessary to preclude experimental impacts from O 2 (g) diffusion into the glovebag. Preliminary data to date (up to 56 days) indicates that sorption of 99 Tc to cementitious materials increased with increasing slag content for simulated saltstone samples. This is consistent with the conceptual model that redox active sulfide groups within the reducing slag facilitate reduction of Tc(VII) to Tc(IV). These experiments differ from previous experiments where a 2% H 2 (g) atmosphere was maintained (Kaplan et al., 2011 (SRNL-STI-2010-00668)). The impact of the 2% H 2 (g) reducing atmosphere on this data was examined and determined to cause the reduction of Tc in experimental samples without slag. In the present ongoing study, after 56 days, Tc sorption by the 50-year old cement samples (no slag) was undetectable, whereas Tc sorption in the cementitious materials containing slag continues to increase with contact time (measured after 1, 4, 8, 19 and 56 days). Sorption was not consistent with spike concentrations and steady state has not been demonstrated after 56 days. The average conditional K d value for the Vault 2 cementitious material was 873 mL/g (17% slag), for the TR547 Saltstone (45% slag) the conditional K d was 168 mL/g, and for TR545 (90% slag) the conditional K d was 1,619 mL/g. It is anticipated that additional samples will be collected until steady state conditions are established to permit measuring

Cementitious building material incorporating end-capped polyethylene glycol as a phase change material

Science.gov (United States)

Salyer, Ival O.; Griffen, Charles W.

1986-01-01

A cementitious composition comprising a cementitious material and polyethylene glycol or end-capped polyethylene glycol as a phase change material, said polyethylene glycol and said end-capped polyethylene glycol having a molecular weight greater than about 400 and a heat of fusion greater than about 30 cal/g; the compositions are useful in making pre-formed building materials such as concrete blocks, brick, dry wall and the like or in making poured structures such as walls or floor pads; the glycols can be encapsulated to reduce their tendency to retard set.

A Plastic Damage Mechanics Model for Engineered Cementitious Composites

DEFF Research Database (Denmark)

Dick-Nielsen, Lars; Stang, Henrik; Poulsen, Peter Noe

2007-01-01

This paper discusses the establishment of a plasticity-based damage mechanics model for Engineered Cementitious Composites (ECC). The present model differs from existing models by combining a matrix and fiber description in order to describe the behavior of the ECC material. The model provides...

Effects of using silica fume and polycarboxylate-type superplasticizer on physical properties of cementitious grout mixtures for semiflexible pavement surfacing.

Science.gov (United States)

Koting, Suhana; Karim, Mohamed Rehan; Mahmud, Hilmi; Mashaan, Nuha S; Ibrahim, Mohd Rasdan; Katman, Herdayati; Husain, Nadiah Md

2014-01-01

Semi-flexible pavement surfacing is a composite pavement that utilizes the porous pavement structure of the flexible bituminous pavement, which is subsequently grouted with appropriate cementitious materials. This study aims to investigate the compressive strength, flexural strength, and workability performance of cementitious grout. The grout mixtures are designed to achieve high strength and maintain flow properties in order to allow the cement slurries to infiltrate easily through unfilled compacted skeletons. A paired-sample t-test was carried out to find out whether water/cement ratio, SP percentages, and use of silica fume influence the cementitious grout performance. The findings showed that the replacement of 5% silica fume with an adequate amount of superplasticizer and water/cement ratio was beneficial in improving the properties of the cementitious grout.

Prediction of Bending Stiffness for Laminated CFRP and Its Application to Manufacturing of Roof Reinforcement

Directory of Open Access Journals (Sweden)

Jeong-Min Lee

2014-05-01

Full Text Available Recently, carbon fiber reinforced plastic (CFRP with high strength, stiffness, and lightweight is used widely in number of composite applications such as commercial aircraft, transportation, machinery, and sports equipment. Especially, it is necessary to apply lightweight materials to car components for reducing energy consumption and CO2 emissions. In case of car roof reinforcement manufactured using CFRP, superior strength and bending stiffness are required for the safety of drivers in the rollover accident. Mechanical properties of CFRP laminates are generally dependent on the stacking sequence. Therefore, research of stacking sequence using CFRP prepreg is required for superior bending stiffness. In this study, the 3-point bending FE-analysis for predicting the bending stiffness of CFRP roof reinforcement was carried out on three cases [0PW∘]5, [0PW°/0UD°/0-PW°]s, and [0UD∘]5. Material properties that the six independent elastic constants are E11, E22, G12, G23, G13, and ν12 used in FE-analysis were evaluated by the tensile test in 0°, 45°, and 90° directions. Through structural strength analysis of the automobile roof reinforcement fabricated using CFRP, the effect of the stacking sequence on the bending stiffness was evaluated and validated through experiments under the same conditions as the analysis.

Performance of alusilica as mineral admixture in cementitious systems

DEFF Research Database (Denmark)

Chi, Lin; Jensen, Ole Mejlhede

2016-01-01

This paper presents a preliminary study of the effect of alusilica (ALS) as a mineral admixture on the fresh properties and development of mechanical properties of cementitious systems. Cement was substituted with ALS with the ratio of 10% during grinding or blended during mixing. The produced ALS...

Vehicle Lightweighting: 40% and 45% Weight Savings Analysis: Technical Cost Modeling for Vehicle Lightweighting

Energy Technology Data Exchange (ETDEWEB)

Mascarin, Anthony [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hannibal, Ted [Idaho National Lab. (INL), Idaho Falls, ID (United States); Raghunathan, Anand [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ivanic, Ziga [Idaho National Lab. (INL), Idaho Falls, ID (United States); Francfort, James [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2015-04-01

The U.S. Department of Energy’s Vehicle Technologies Office, Materials area commissioned a study to model and assess manufacturing economics of alternative design and production strategies for a series of lightweight vehicle concepts. The strategic targets were a 40% and a 45% mass reduction relative to a standard North American midsize passenger sedan at an effective cost of $3.42 per pound (lb) saved. The baseline vehicle was an average of several available vehicles in this class. Mass and cost breakdowns from several sources were used, including original equipment manufacturers’ (OEMs’) input through U.S. Department of Energy’s Vehicle Technologies Office programs and public presentations, A2Mac1 LLC’s teardown information, Lotus Engineering Limited and FEV, Inc. breakdowns in their respective lightweighting studies, and IBIS Associates, Inc.’s decades of experience in automotive lightweighting and materials substitution analyses. Information on lightweighting strategies in this analysis came from these same sources and the ongoing U.S. Department of Energy-funded Vehma International of America, Inc. /Ford Motor Company Multi-Material Lightweight Prototype Vehicle Demonstration Project, the Aluminum Association Transportation Group, and many United States Council for Automotive Research’s/United States Automotive Materials Partnership LLC lightweight materials programs.

Production of lightweight Geopolymer concrete using artificial local lightweight aggregate

Directory of Open Access Journals (Sweden)

Abbas Waleed

2018-01-01

Full Text Available Due to the rapid depletion of natural resources, the use of waste materials and by-products from different industries of building construction has been gaining increased attention. Geopolymer concrete based on Pozzolana is a new material that does not need the presence of Portland cement as a binder. The main focus of this research is to produce lightweight geopolymer concrete (LWGPC using artificial coarse lightweight aggregate which produced from locally available bentonite clays. In this investigation, the binder is low calcium fly ash (FA and the alkali activator is sodium hydroxide and sodium silicate in different molarities. The experimental tests including workability, fresh density, also, the compressive strength, splitting tensile strength, flexural strength, water absorption and ultrasonic pulse velocity at the age of 7, 28 and 56 days were studied. The oven dry density and thermal conductivity at 28 days age are investigated. The results show that it is possible to produce high strength lightweight geopolymer concrete successfully used as insulated structural lightweight concrete. The 28-day compressive strength, tensile strength, flexural strength, dry density, and thermal conductivity of the produced LWGPC are 35.8 MPa, 2.6MPa, 5.5 MPa, 1835kg/m3, and 0.9567 W/ (m. K, respectively.

Rigid-body-spring model numerical analysis of joint performance of engineered cementitious composites and concrete

Science.gov (United States)

Khmurovska, Y.; Štemberk, P.; Křístek, V.

2017-09-01

This paper presents a numerical investigation of effectiveness of using engineered cementitious composites with polyvinyl alcohol fibers for concrete cover layer repair. A numerical model of a monolithic concaved L-shaped concrete structural detail which is strengthened with an engineered cementitious composite layer with polyvinyl alcohol fibers is created and loaded with bending moment. The numerical analysis employs nonlinear 3-D Rigid-Body-Spring Model. The proposed material model shows reliable results and can be used in further studies. The engineered cementitious composite shows extremely good performance in tension due to the strain-hardening effect. Since durability of the bond can be decreased significantly by its degradation due to the thermal loading, this effect should be also taken into account in the future work, as well as the experimental investigation, which should be performed for validation of the proposed numerical model.

Polymer-Reinforced, Non-Brittle, Lightweight Cryogenic Insulation

Science.gov (United States)

Hess, David M.

2013-01-01

The primary application for cryogenic insulating foams will be fuel tank applications for fueling systems. It is crucial for this insulation to be incorporated into systems that survive vacuum and terrestrial environments. It is hypothesized that by forming an open-cell silica-reinforced polymer structure, the foam structures will exhibit the necessary strength to maintain shape. This will, in turn, maintain the insulating capabilities of the foam insulation. Besides mechanical stability in the form of crush resistance, it is important for these insulating materials to exhibit water penetration resistance. Hydrocarbon-terminated foam surfaces were implemented to impart hydrophobic functionality that apparently limits moisture penetration through the foam. During the freezing process, water accumulates on the surfaces of the foams. However, when hydrocarbon-terminated surfaces are present, water apparently beads and forms crystals, leading to less apparent accumulation. The object of this work is to develop inexpensive structural cryogenic insulation foam that has increased impact resistance for launch and ground-based cryogenic systems. Two parallel approaches will be pursued: a silica-polymer co-foaming technique and a post foam coating technique. Insulation characteristics, flexibility, and water uptake can be fine-tuned through the manipulation of the polyurethane foam scaffold. Silicate coatings for polyurethane foams and aerogel-impregnated polyurethane foams have been developed and tested. A highly porous aerogel-like material may be fabricated using a co-foam and coated foam techniques, and can insulate at liquid temperatures using the composite foam

Designing bioinspired composite reinforcement architectures via 3D magnetic printing

Science.gov (United States)

Martin, Joshua J.; Fiore, Brad E.; Erb, Randall M.

2015-10-01

Discontinuous fibre composites represent a class of materials that are strong, lightweight and have remarkable fracture toughness. These advantages partially explain the abundance and variety of discontinuous fibre composites that have evolved in the natural world. Many natural structures out-perform the conventional synthetic counterparts due, in part, to the more elaborate reinforcement architectures that occur in natural composites. Here we present an additive manufacturing approach that combines real-time colloidal assembly with existing additive manufacturing technologies to create highly programmable discontinuous fibre composites. This technology, termed as `3D magnetic printing', has enabled us to recreate complex bioinspired reinforcement architectures that deliver enhanced material performance compared with monolithic structures. Further, we demonstrate that we can now design and evolve elaborate reinforcement architectures that are not found in nature, demonstrating a high level of possible customization in discontinuous fibre composites with arbitrary geometries.

Designing bioinspired composite reinforcement architectures via 3D magnetic printing.

Science.gov (United States)

Martin, Joshua J; Fiore, Brad E; Erb, Randall M

2015-10-23

Discontinuous fibre composites represent a class of materials that are strong, lightweight and have remarkable fracture toughness. These advantages partially explain the abundance and variety of discontinuous fibre composites that have evolved in the natural world. Many natural structures out-perform the conventional synthetic counterparts due, in part, to the more elaborate reinforcement architectures that occur in natural composites. Here we present an additive manufacturing approach that combines real-time colloidal assembly with existing additive manufacturing technologies to create highly programmable discontinuous fibre composites. This technology, termed as '3D magnetic printing', has enabled us to recreate complex bioinspired reinforcement architectures that deliver enhanced material performance compared with monolithic structures. Further, we demonstrate that we can now design and evolve elaborate reinforcement architectures that are not found in nature, demonstrating a high level of possible customization in discontinuous fibre composites with arbitrary geometries.

Stay-in-Place Formwork of TRC Designed as Shear Reinforcement for Concrete Beams

Directory of Open Access Journals (Sweden)

S. Verbruggen

2013-01-01

Full Text Available In order to reduce on-site building time, the construction industry shows an increasing interest in stay-in-place formwork with a reinforcement function after concrete hardening, such as CFRP formwork confinement for columns. The current combined systems however do not answer the demand of the building industry for a material system that is both lightweight and fire safe. High performance textile reinforced cement (TRC composites can address this need. They can be particularly interesting for the shear reinforcement of concrete beams. This paper describes a preliminary analysis and feasibility study on structural stay-in-place formwork made of TRC. Comparative bending experiments demonstrate that a fully steel reinforced beam and an equivalent beam with shear reinforcement in TRC formwork show similar yielding behaviour, indicating that the TRC shear reinforcement system actually works. Moreover, the cracking moment of the concrete was more or less doubled, resulting in a much lower deflection in serviceability limit state than calculated. Digital image correlation measurements show that the latter is due to the crack bridging capacity of the external TRC shear reinforcement.

Effects of Using Silica Fume and Polycarboxylate-Type Superplasticizer on Physical Properties of Cementitious Grout Mixtures for Semiflexible Pavement Surfacing

Directory of Open Access Journals (Sweden)

Suhana Koting

2014-01-01

Full Text Available Semi-flexible pavement surfacing is a composite pavement that utilizes the porous pavement structure of the flexible bituminous pavement, which is subsequently grouted with appropriate cementitious materials. This study aims to investigate the compressive strength, flexural strength, and workability performance of cementitious grout. The grout mixtures are designed to achieve high strength and maintain flow properties in order to allow the cement slurries to infiltrate easily through unfilled compacted skeletons. A paired-sample t-test was carried out to find out whether water/cement ratio, SP percentages, and use of silica fume influence the cementitious grout performance. The findings showed that the replacement of 5% silica fume with an adequate amount of superplasticizer and water/cement ratio was beneficial in improving the properties of the cementitious grout.

Damage development, phase changes, transport properties, and freeze-thaw performance of cementitious materials exposed to chloride based salts

Science.gov (United States)

Farnam, Yaghoob

Recently, there has been a dramatic increase in premature deterioration in concrete pavements and flat works that are exposed to chloride based salts. Chloride based salts can cause damage and deterioration in concrete due to the combination of factors which include: increased saturation, ice formation, salt crystallization, osmotic pressure, corrosion in steel reinforcement, and/or deleterious chemical reactions. This thesis discusses how chloride based salts interact with cementitious materials to (1) develop damage in concrete, (2) create new chemical phases in concrete, (3) alter transport properties of concrete, and (4) change the concrete freeze-thaw performance. A longitudinal guarded comparative calorimeter (LGCC) was developed to simultaneously measure heat flow, damage development, and phase changes in mortar samples exposed to sodium chloride (NaCl), calcium chloride (CaCl 2), and magnesium chloride (MgCl2) under thermal cycling. Acoustic emission and electrical resistivity measurements were used in conjunction with the LGCC to assess damage development and electrical response of mortar samples during cooling and heating. A low-temperature differential scanning calorimetry (LT-DSC) was used to evaluate the chemical interaction that occurs between the constituents of cementitious materials (i.e., pore solution, calcium hydroxide, and hydrated cement paste) and salts. Salts were observed to alter the classical phase diagram for a salt-water system which has been conventionally used to interpret the freeze-thaw behavior in concrete. An additional chemical phase change was observed for a concrete-salt-water system resulting in severe damage in cementitious materials. In a cementitious system exposed to NaCl, the chemical phase change occurs at a temperature range between -6 °C and 8 °C due to the presence of calcium sulfoaluminate phases in concrete. As a result, concrete exposed to NaCl can experience additional freeze-thaw cycles due to the chemical

Cementitious Materials in Safety Cases for Geological Repositories for Radioactive Waste: Role, Evolution and Interactions. A Workshop organised by the OECD/NEA Integration Group for the Safety Case and hosted by ONDRAF/NIRAS. Cementitious materials in safety cases for radioactive waste: role, evolution and interactions

International Nuclear Information System (INIS)

2012-01-01

The OECD Nuclear Energy Agency (NEA) Integration Group for the Safety Case (IGSC) organised a workshop to assess current understanding on the use of cementitious materials in radioactive waste disposal. The workshop was hosted by the Belgian Agency for Radioactive Waste and Enriched Fissile Materials (Ondraf/Niras), in Brussels, Belgium on 17-19 November 2009. The workshop brought together a wide range of people involved in supporting safety case development and having an interest in cementitious materials: namely, cement and concrete experts, repository designers, scientists, safety assessors, disposal programme managers and regulators. The workshop was designed primarily to consider issues relevant to the post-closure safety of radioactive waste disposal, but also addressed some related operational issues, such as cementitious barrier emplacement. Where relevant, information on cementitious materials from analogous natural and anthropogenic systems was also considered. This report provides a synthesis of the workshop, and summarises its main results and findings. The structure of this report follows the workshop agenda: - Section 2 summarises plenary and working group discussions on the uses, functions and evolution of cementitious materials in geological disposal, and highlights key aspects and discussions points. - Section 3 summarises plenary and working group discussions on interactions of cementitious materials with other disposal system components, and highlights key aspects and discussions points. - Section 4 summarises the workshop session on the integration of issues related to cementitious materials using the safety case. - Section 5 presents the main conclusions from the workshop. - Section 6 contains a list of references. - Appendix A presents the workshop agenda. - Appendix B contains the abstracts and, where provided, technical papers supporting oral presentations at the workshop. - Appendix C contains the abstracts and, where provided, technical

Review of Carbon Fiber Reinforced Polymer Reinforced Material in Concrete Structure

Directory of Open Access Journals (Sweden)

Ayuddin Ayuddin

2016-05-01

Full Text Available Carbon Fiber Reinforced Polymer (FRP is a material that is lightweight, strong, anti-magnetic and corrosion resistant. This material can be used as an option to replace the steel material in concrete construction or as material to improve the strength of existing construction. CFRP is quite easy to be attached to the concrete structure and proved economically used as a material for repairing damaged structures and increase the resilience of structural beams, columns, bridges and other parts of the structure against earthquakes. CFRP materials can be shaped sheet to be attached to the concrete surface. Another reason is due to the use of CFRP has a higher ultimate strength and lower weight compared to steel reinforcement so that the handling is significantly easier. Through this paper suggests that CFRP materials can be applied to concrete structures, especially on concrete columns. Through the results of experiments conducted proved that the concrete columns externally wrapped with CFRP materials can increase the strength. This treatment is obtained after testing experiments on 130 mm diameter column with a height of 700 mm with concentric loading method to collapse. The experimental results indicate that a column is wrapped externally with CFRP materials can achieve a load capacity of 250 kN compared to the concrete columns externally without CFRP material which only reached 150 kN. If the column is given internally reinforcing steel and given externally CFRP materials can reach 270 kN. It shows that CFRP materials can be used for concrete structures can even replace reinforcing steel that has been widely used in building construction in Indonesia.

X-ray computed microtomography of three-dimensional microcracks and self-healing in engineered cementitious composites

International Nuclear Information System (INIS)

Fan, Shuai; Li, Mo

2015-01-01

Concrete cracking and deterioration can potentially be addressed by innovative self-healing cementitious materials, which can autogenously regain transport properties and mechanical characteristics after the damage self-healing process. For the development of such materials, it is crucial, but challenging, to precisely characterize the extent and quality of self-healing due to a variety of factors. This study adopted x-ray computed microtomography (μCT) to derive three-dimensional morphological data on microcracks before and after healing in engineered cementitious composite (ECC). Scanning electron microscope and energy dispersive x-ray spectroscopy were also used to morphologically and chemically analyze the healing products. This work showed that the evolution of the microcrack 3D structure due to self-healing in cementitious materials can be directly and quantitatively characterized by μCT. A detailed description of the μCT image analysis method applied to ECC self-healing was presented. The results revealed that the self-healing extent and rate strongly depended on initial surface crack width, with smaller crack width favoring fast and robust self-healing. We also found that the self-healing mechanism in cementitious materials is dependent on crack depth. The region of a crack close to the surface (from 0 to around 50–150 μm below the surface) can be sealed quickly with crystalline precipitates. However, at greater depths the healing process inside the crack takes a significantly longer time to occur, with healing products more likely resulting from continued hydration and pozzolanic reactions. Finally, the μCT method was compared with other self-healing characterization methods, with discussions on its importance in generating new scientific knowledge for the development of robust self-healing cementitious materials. (paper)

Microstructural changes in a cementitious membrane due to the application of a DC electric field.

Science.gov (United States)

Covelo, Alba; Diaz, Belen; Freire, Lorena; Novoa, X Ramon; Perez, M Consuelo

2008-07-01

The use of electromigration techniques to accelerate chloride ions motion is commonly employed to characterise the permeability of cementitious samples to chlorides, a relevant parameter in reinforced concrete corrosion. This paper is devoted to the study of microstructure's changes occurring in mortar samples when submitted to natural diffusion and migration experiments. The application of an electric field reduces testing time in about one order of magnitude with respect to natural diffusion experiments. Nevertheless, the final sample's microstructure differs in both tests. Impedance Spectroscopy is employed for real time monitoring of microstructural changes. During migration experiments the global impedance undergoes important increase in shorter period of time compared to natural diffusion tests. So, the forced motion of ions through the concrete membrane induces significant variations in the porous structure, as confirmed by Mercury Intrusion Porosimetry. After migration experiments, an important increase in the capillary pore size (10-100 nm) was detected. Conversely, no relevant variations are found after natural diffusion tests. Results presented in this work cast doubt on the significance of diffusion coefficient values obtained under accelerated conditions.

Micromechanical Properties of a New Polymeric Microcapsule for Self-Healing Cementitious Materials

Directory of Open Access Journals (Sweden)

Leyang Lv

2016-12-01

Full Text Available Self-healing cementitious materials containing a microencapsulated healing agent are appealing due to their great application potential in improving the serviceability and durability of concrete structures. In this study, poly(phenol–formaldehyde (PF microcapsules that aim to provide a self-healing function for cementitious materials were prepared by an in situ polymerization reaction. Size gradation of the synthesized microcapsules was achieved through a series of sieving processes. The shell thickness and the diameter of single microcapsules was accurately measured under environmental scanning electron microscopy (ESEM. The relationship between the physical properties of the synthesized microcapsules and their micromechanical properties were investigated using nanoindentation. The results of the mechanical tests show that, with the increase of the mean size of microcapsules and the decrease of shell thickness, the mechanical force required to trigger the self-healing function of microcapsules increased correspondingly from 68.5 ± 41.6 mN to 198.5 ± 31.6 mN, featuring a multi-sensitive trigger function. Finally, the rupture behavior and crack surface of cement paste with embedded microcapsules were observed and analyzed using X-ray computed tomography (XCT. The synthesized PF microcapsules may find potential application in self-healing cementitious materials.

Preparation of Cementitious Material Using Smelting Slag and Tailings and the Solidification and Leaching of Pb2+

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Dan Zhang

2015-01-01

Full Text Available The composite cementitious materials were prepared with lead-zinc tailings, lead-zinc smelting slag, and cement clinker. The effect of material ratio on the mechanical properties, the phase analysis, and microstructures were investigated. The effect of the pH and stripping time on the leaching amount of lead ion was discussed. The results show that the additive amount of the tailings should be minimized for the cementitious materials meeting the strength requirements, controlled within 10%. The leaching amount of cementitious materials remains low in a larger range of pH, which can effectively reduce the leaching of heavy metal lead. The leaching kinetics of lead ions in the three kinds of samples could be better described by the pseudo-second-model.

Degradation of cementitious materials associated with salstone disposal units

Energy Technology Data Exchange (ETDEWEB)

Flach, G. P. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Smith, F. G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2014-09-01

The Saltstone facilities at the DOE Savannah River Site (SRS) stabilize and dispose of low-level radioactive salt solution originating from liquid waste storage tanks at the site. The Saltstone Production Facility (SPF) receives treated salt solution and mixes the aqueous waste with dry cement, blast furnace slag, and fly ash to form a grout slurry which is mechanically pumped into concrete disposal cells that compose the Saltstone Disposal Facility (SDF). The solidified grout is termed “saltstone”. Cementitious materials play a prominent role in the design and long-term performance of the SDF. The saltstone grout exhibits low permeability and diffusivity, and thus represents a physical barrier to waste release. The waste form is also reducing, which creates a chemical barrier to waste release for certain key radionuclides, notably Tc-99. Similarly, the concrete shell of a saltstone disposal unit (SDU) represents an additional physical and chemical barrier to radionuclide release to the environment. Together the waste form and the SDU compose a robust containment structure at the time of facility closure. However, the physical and chemical state of cementitious materials will evolve over time through a variety of phenomena, leading to degraded barrier performance over Performance Assessment (PA) timescales of thousands to tens of thousands of years. Previous studies of cementitious material degradation in the context of low-level waste disposal have identified sulfate attack, carbonation influenced steel corrosion, and decalcification (primary constituent leaching) as the primary chemical degradation phenomena of most relevance to SRS exposure conditions. In this study, degradation time scales for each of these three degradation phenomena are estimated for saltstone and concrete associated with each SDU type under conservative, nominal, and best estimate assumptions.

DEVELOPMENT OF NON-DESTRUCTIVE MONITORING SYSTEM FOR CHLORIDE PENETRATION INTO REINFORCED CONCRETE STRUCTURES

Directory of Open Access Journals (Sweden)

Antoni Antoni

2006-01-01

Full Text Available Reinforced concrete structures in marine environment are subjected to chloride penetration, which significantly degrades the structural performance due to the occurrence of corrosion in the steel reinforcement. The performance degradation of the structures would reduce the intended service life and caused higher maintenance and repair cost. Therefore, system to monitor chloride penetration into reinforced concrete before the starting corrosion of reinforcement is indispensable. An embedded probe system to detect chloride penetration into concrete was developed in Japan. This probe consists of a cementitious material body and some number of wires as sensors, which are set in the shallow ditches around the probe body. The system detect the chloride penetration by monitoring the initiation time of wire corrosion, it also has the advantages of continuous monitoring and early warning on the onset of corrosion in the reinforcement. However, the probe had not yet had high sensitivity for detecting critical chloride content in concrete. Therefore to increase its sensitivity, four types of improvements, namely partial coating of the wires, waterproofing on the probe body, filling the ditches with porous material and supplying small current on the wires were evaluated in this study. From the experimental result, it was observed that supplying small current and partial coating of the wires could improve the sensitivity of the probe significantly, while waterproofing treatment on the probe body and filling the ditches did not have significant contribution.

Engineering Properties and Correlation Analysis of Fiber Cementitious Materials

Directory of Open Access Journals (Sweden)

Wei-Ting Lin

2014-11-01

Full Text Available This study focuses on the effect of the amount of silica fume addition and volume fraction of steel fiber on the engineering properties of cementitious materials. Test variables include dosage of silica fume (5% and 10%, water/cement ratio (0.35 and 0.55 and steel fiber dosage (0.5%, 1.0% and 2.0%. The experimental results included: compressive strength, direct tensile strength, splitting tensile strength, surface abrasion and drop-weight test, which were collected to carry out the analysis of variance to realize the relevancy and significance between material parameters and those mechanical properties. Test results illustrate that the splitting tensile strength, direct tensile strength, strain capacity and ability of crack-arresting increase with increasing steel fiber and silica fume dosages, as well as the optimum mixture of the fiber cementitious materials is 5% replacement silica fume and 2% fiber dosage. In addition, the Pearson correlation coefficient was conducted to evaluate the influence of the material variables and corresponds to the experiment result.

Treated Coconut Coir Pith as Component of Cementitious Materials

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Dana Koňáková

2015-01-01

Full Text Available The presented paper deals with utilization of raw and treated coir pith as potential component of cementitious composites. The studied material is coir pith originating from a coconut production. Its applicability as cement mixture component was assessed in terms of the physical properties of concrete containing different amount of coir pith. Basic physical properties, compressive and bending strength, and hygric transport characteristics as well as thermal properties belong among the studied characteristics. It was proved that the concrete with 5% (by mass of cement of this waste material shows appropriate physical properties and it gives rise to an applicable material for building structures. Generally, the coir pith can be regarded as lightening additive. When 10% of coir pith was added, it has led to higher deterioration of properties than what is acceptable since such dosing is greatly increasing the total porosity. The influence of chemical treatment of coir pith was evaluated as well; both tested treatment methods improved the performance of cementitious composites while the acetylation was somewhat more effective the treatment by NaOH.

Cold surface treatments on fiber-reinforced plastics by pulsed laser

OpenAIRE

Gebauer, Jana; Franke, Volker; Klotzbach, Udo; Beyer, Eckhard

2017-01-01

The importance of lightweight materials increases in all aspects of manufacturing, e.g. automotive, sports equipment and aerospace [1]. Making fiber reinforced plastics suitable for use in mass production new technologies have to be developed to overcome existing challenges e.g. shorter cycle times or more efficient resource usage. Innovative laser systems are used for a full range of treatments for all materials, like structuring, drilling, joining and cutting [2] - [4]. This paper presents ...

Upgrading the Center for Lightweighting Automotive Materials and Processing - a GATE Center of Excellence at the University of Michigan-Dearborn

Energy Technology Data Exchange (ETDEWEB)

Mallick, P. K.

2012-08-30

The Center for Lightweighting Materials and Processing (CLAMP) was established in September 1998 with a grant from the Department of Energy’s Graduate Automotive Technology Education (GATE) program. The center received the second round of GATE grant in 2005 under the title “Upgrading the Center for Lightweighting Automotive Materials and Processing”. Using the two grants, the Center has successfully created 10 graduate level courses on lightweight automotive materials, integrated them into master’s and PhD programs in Automotive Systems Engineering, and offered them regularly to the graduate students in the program. In addition, the Center has created a web-based lightweight automotive materials database, conducted research on lightweight automotive materials and organized seminars/symposia on lightweight automotive materials for both academia and industry. The faculty involved with the Center has conducted research on a variety of topics related to design, testing, characterization and processing of lightweight materials for automotive applications and have received numerous research grants from automotive companies and government agencies to support their research. The materials considered included advanced steels, light alloys (aluminum, magnesium and titanium) and fiber reinforced polymer composites. In some of these research projects, CLAMP faculty have collaborated with industry partners and students have used the research facilities at industry locations. The specific objectives of the project during the current funding period (2005 – 2012) were as follows: (1) develop new graduate courses and incorporate them in the automotive systems engineering curriculum (2) improve and update two existing courses on automotive materials and processing (3) upgrade the laboratory facilities used by graduate students to conduct research (4) expand the Lightweight Automotive Materials Database to include additional materials, design case studies and make it more

Implementation of Highly-Flowable Strain Hardening Fiber Reinforced Concrete in New RC Beam-Column Joints

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Liao Wen-Cheng

2018-01-01

Full Text Available The purpose of New RC project was aimed to reduce the member sections and increase the available space of high rise buildings by using high strength concrete (f’c > 70 MPa and high strength rebars (fy > 685 MPa. Material consumptions and member section sizes can be further reduced owing to the upgrade of strength. However, the nature of brittleness of high strength may also cause early cover spalling and other ductility issues. Addition of steel fibers is an alternative as transverse reinforcement. Highly flowable strain hardening fiber reinforced concrete (HF-SHFRC has excellent workability in the fresh state and exhibits the strain-hardening and multiple cracking characteristics of high performance fiber reinforced cementitious composites (HPFRCC in their hardened state. The objective of this study is to investigate the feasibility of implementing HF-SHFRC in New RC building systems, particularly for beam-column joints as an alternative of transverse reinforcements. Four full-scale exterior beam-column joints, including two specimens with intensive transverse reinforcements and two specimens made of HF-SHFRC without any stirrup, are tested. Test results show that the HF-SHFRC specimens perform as well as specimens with intensive transverse reinforcements regarding failure mode, ductility, energy dissipation and crack width control. Integration of New RC building systems and HF-SHFRC can assuring construction qualities and further diminish labor work and give infrastructure longer service life, and eventually lower the life-cycle cost.

Development of Ecoefficient Engineered Cementitious Composites Using Supplementary Cementitious Materials as a Binder and Bottom Ash Aggregate as Fine Aggregate

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Jin Wook Bang

2015-01-01

Full Text Available The purpose of this study is to develop ecoefficient engineered cementitious composites (ECC using supplementary cementitious materials (SCMs, including fly ash (FA and blast furnace slag (SL as a binder material. The cement content of the ECC mixtures was replaced by FA and SL with a replacement rate of 25%. In addition, the fine aggregate of the ECC was replaced by bottom ash aggregate (BA with a substitution rate of 10%, 20%, and 30%. The influences of ecofriendly aggregates on fresh concrete properties and on mechanical properties were experimentally investigated. The test results revealed that the substitution of SCMs has an advantageous effect on fresh concrete’s properties; however, the increased water absorption and the irregular shape of the BA can potentially affect the fresh concrete’s properties. The substitution of FA and SL in ECC led to an increase in frictional bond at the interface between PVA fibers and matrix, improved the fiber dispersion, and showed a tensile strain capacity ranging from 3.3% to 3.5%. It is suggested that the combination of SCMs (12.5% FA and 12.5% SL and the BA aggregate with the substitution rate of 10% can be effectively used in ECC preparation.

A new system for crack closure of cementitious materials using shrinkable polymers

International Nuclear Information System (INIS)

Jefferson, Anthony; Joseph, Christopher; Lark, Robert; Isaacs, Ben; Dunn, Simon; Weager, Brendon

2010-01-01

This paper presents details of an original crack-closure system for cementitious materials using shrinkable polymer tendons. The system involves the incorporation of unbonded pre-oriented polymer tendons in cementitious beams. Crack closure is achieved by thermally activating the shrinkage mechanism of the restrained polymer tendons after the cement-based material has undergone initial curing. The feasibility of the system is demonstrated in a series of small scale experiments on pre-cracked prismatic mortar specimens. The results from these tests show that, upon activation, the polymer tendon completely closes the preformed macro-cracks and imparts a significant stress across the crack faces. The potential of the system to enhance the natural autogenous crack healing process and generally improve the durability of concrete structures is addressed.

The solubility of uranium in cementitious near-field chemical conditions

Energy Technology Data Exchange (ETDEWEB)

Baston, G.M.N.; Brownsword, M.; Cross, J.E.; Hobley, J.; Moreton, A.D.; Smith-Briggs, J.L.; Thomason, H.P. [AEA Decommissioning and Waste Management, Harwell (United Kingdom)

1993-05-01

Tetravalent and hexavalent uranium solubilities have been measured in cement-equilibriated water for pH values from 4 to 13. Tetravalent uranium solubilities at pH 12 have been measured by three experimental techniques: oversaturation, undersaturation and by the use of an electrochemical cell which controlled the redox conditions. The experimentally obtained data have been simulated using the thermodynamic equilibrium program HARPHRQ in conjunction with three different sets of thermodynamic data for uranium. In each case, differences were found between the predicted and measured uranium behaviour. For hexavalent uranium at high pH values the model suggested the formation of anionic hydrolysis products which led to the prediction of uranium solubilities significantly higher than those observed. Refinement of the thermodynamic data used in the model enabled the derivation of maximum values for the formation constants of these species under cementitious conditions. Similarly, the experimental data have been used to refine a model of tetravalent uranium solubility under cementitious near-field conditions. (author).

The solubility of uranium in cementitious near-field chemical conditions

International Nuclear Information System (INIS)

Baston, G.M.N.; Brownsword, M.; Cross, J.E.; Hobley, J.; Moreton, A.D.; Smith-Briggs, J.L.; Thomason, H.P.

1993-05-01

Tetravalent and hexavalent uranium solubilities have been measured in cement-equilibriated water for pH values from 4 to 13. Tetravalent uranium solubilities at pH 12 have been measured by three experimental techniques: oversaturation, undersaturation and by the use of an electrochemical cell which controlled the redox conditions. The experimentally obtained data have been simulated using the thermodynamic equilibrium program HARPHRQ in conjunction with three different sets of thermodynamic data for uranium. In each case, differences were found between the predicted and measured uranium behaviour. For hexavalent uranium at high pH values the model suggested the formation of anionic hydrolysis products which led to the prediction of uranium solubilities significantly higher than those observed. Refinement of the thermodynamic data used in the model enabled the derivation of maximum values for the formation constants of these species under cementitious conditions. Similarly, the experimental data have been used to refine a model of tetravalent uranium solubility under cementitious near-field conditions. (author)

Can superabsorbent polymers mitigate shrinkage in cementitious materials blended with supplementary cementitious materials?

DEFF Research Database (Denmark)

Snoeck, Didier; Jensen, Ole Mejlhede; De Belie, Nele

2016-01-01

A promising way to mitigate autogenous shrinkage in cementitious materials with a low water-to-binder ratio is internal curing by the use of superabsorbent polymers. Superabsorbent polymers are able to absorb multiple times their weight in water and can be applied as an internal water reservoir...... to induce internal curing and mitigation of self-desiccation. Their purposefulness has been demonstrated in Portland cement pastes with and without silica fume. Nowadays, fly ash and blast-furnace slag containing binders are also frequently used in the construction industry. The results on autogenous...... shrinkage in materials blended with fly ash or blast-furnace slag remain scarce, especially after one week of age. This paper focuses on the autogenous shrinkage by performing manual and automated shrinkage measurements up to one month of age. Without superabsorbent polymers, autogenous shrinkage...

Modelling the carbonation of cementitious matrixes by means of the unreacted-core model, UR-CORE

International Nuclear Information System (INIS)

Castellote, M.; Andrade, C.

2008-01-01

This paper presents a model for the carbonation of cementitious matrixes (UR-CORE). The model is based on the principles of the 'unreacted-core' systems, typical of chemical engineering processes, in which the reacted product remains in the solid as a layer of inert ash, adapted for the specific case of carbonation. Development of the model has been undertaken in three steps: 1) Establishment of the controlling step in the global carbonation rate, by using data of fractional conversion of different phases of the cementitious matrixes, obtained by the authors through neutron diffraction data experiments, and reported in [M. Castellote, C. Andrade, X. Turrillas, J. Campo, G. Cuello, Accelerated carbonation of cement pastes in situ monitored by neutron diffraction, Cem. Concr. Res. (2008), doi:10.1016/j.cemconres.2008.07.002]. 2) Then, the model has been adapted and applied to the cementitious materials using different concentrations of CO 2 , with the introduction of the needed assumptions and factors. 3) Finally, the model has been validated with laboratory data at different concentrations (taken from literature) and for long term natural exposure of concretes. As a result, the model seems to be reliable enough to be applied to cementitious materials, being able to extrapolate the results from accelerated tests in any conditions to predict the rate of carbonation in natural exposure, being restricted, at present stage, to conditions with a constant relative humidity

Study on rich alumina alkali-activated slag clay minerals cementitious materials for immobilization of radioactive waste

International Nuclear Information System (INIS)

Li Yuxiang; Qian Guangren; Yi Facheng; Shi Rongming; Fu Yibei; Li Lihua; Zhang Jun

1999-01-01

The composition and some properties of its pastes of rich alumina alkali-activated slag clay minerals (RAAASCM) cementitious materials for immobilization of radioactive waste are studied. Experimental results show that heat activated kaolinite, Xingjiang zeolite, modified attapulgite clay are better constituents of RAAASCM. RAAASCM cementitious materials pastes exhibit high strength, low porosity, fewer harmful pore, and high resistance to sulphate corrosion as well as gamma irradiation. The Sr 2+ , Cs + leaching portion of the simulated radioactive waste forms based on RAAASCM, is low

Variability Of KD Values In Cementitious Materials And Sediments

International Nuclear Information System (INIS)

Almond, P.; Kaplan, D.; Shine, E.

2012-01-01

Measured distribution coefficients (K d values) for environmental contaminants provide input data for performance assessments (PA) that evaluate physical and chemical phenomena for release of radionuclides from wasteforms, degradation of engineered components and subsequent transport of radionuclides through environmental media. Research efforts at SRNL to study the effects of formulation and curing variability on the physiochemical properties of the saltstone wasteform produced at the Saltstone Disposal Facility (SDF) are ongoing and provide information for the PA and Saltstone Operations. Furthermore, the range and distribution of plutonium K d values in soils is not known. Knowledge of these parameters is needed to provide guidance for stochastic modeling in the PA. Under the current SRS liquid waste processing system, supernate from F and H Tank Farm tanks is processed to remove actinides and fission products, resulting in a low-curie Decontaminated Salt Solution (DSS). At the Saltstone Production Facility (SPF), DSS is mixed with premix, comprised of blast furnace slag (BFS), Class F fly ash (FA), and portland cement (OPC) to form a grout mixture. The fresh grout is subsequently placed in SDF vaults where it cures through hydration reactions to produce saltstone, a hardened monolithic waste form. Variation in saltstone composition and cure conditions of grout can affect the saltstone's physiochemical properties. Variations in properties may originate from variables in DSS, premix, and water to premix ratio, grout mixing, placing, and curing conditions including time and temperature (Harbour et al. 2007; Harbour et al. 2009). There are no previous studies reported in the literature regarding the range and distribution of K d values in cementitious materials. Presently, the Savannah River Site (SRS) estimate ranges and distributions of K d values based on measurements of K d values made in sandy SRS sediments (Kaplan 2010). The actual cementitious material K d

Setup of Extruded Cementitious Hollow Tubes as Containing/Releasing Devices in Self-Healing Systems

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Alessandra Formia

2015-04-01

Full Text Available The aim of this research is to produce self-healing cementitious composites based on the use of cylindrical capsules containing a repairing agent. Cementitious hollow tubes (CHT having two different internal diameters (of 2 mm and 7.5 mm were produced by extrusion and used as containers and releasing devices for cement paste/mortar healing agents. Based on the results of preliminary mechanical tests, sodium silicate was selected as the healing agent. The morphological features of several mix designs used to manufacture the extruded hollow tubes, as well as the coatings applied to increase the durability of both core and shell materials are discussed. Three-point bending tests were performed on samples produced with the addition of the above-mentioned cementitious hollow tubes to verify the self-healing effectiveness of the proposed solution. Promising results were achieved, in particular when tubes with a bigger diameter were used. In this case, a substantial strength and stiffness recovery was observed, even in specimens presenting large cracks (>1 mm. The method is inexpensive and simple to scale up; however, further research is needed in view of a final optimization.

Design and manufacture of a lightweight piezo-composite curved actuator

Science.gov (United States)

Yoon, K. Joon; Shin, Seokjun; Park, Hoon C.; Goo, Nam Seo

2002-02-01

In this paper we are concerned with the design, manufacture and performance test of a lightweight piezo-composite curved actuator (called LIPCA) using a top carbon fiber composite layer with near-zero coefficient of thermal expansion (CTE), a middle PZT ceramic wafer, and a bottom glass/epoxy layer with a high CTE. The main point of the design for LIPCA is to replace the heavy metal layers of THUNDERTM by lightweight fiber reinforced plastic layers without losing the capabilities for generating high force and large displacement. It is possible to save up to about 40% of the weight if we replace the metallic backing material by the light fiber composite layer. We can also have design flexibility by selecting the fiber direction and the size of prepreg layers. In addition to the lightweight advantage and design flexibility, the proposed device can be manufactured without adhesive layers when we use an epoxy resin prepreg system. Glass/epoxy prepregs, a ceramic wafer with electrode surfaces, and a carbon prepreg were simply stacked and cured at an elevated temperature (177 °C) after following an autoclave bagging process. We found that the manufactured composite laminate device had a sufficient curvature after being detached from a flat mould. An analysis method using the classical lamination theory is presented to predict the curvature of LIPCA after curing at an elevated temperature. The predicted curvatures are in quite good agreement with the experimental values. In order to investigate the merits of LIPCA, performance tests of both LIPCA and THUNDERTM have been conducted under the same boundary conditions. From the experimental actuation tests, it was observed that the developed actuator could generate larger actuation displacement than THUNDERTM.

Superhydrophobic engineered cementitious composites for highway bridge applications : technology transfer and implementation.

Science.gov (United States)

2013-09-01

The strength and durability of highway bridges are two of the key components in maintaining a : high level of freight transportation capacity on the nations highways. Superhydrophobic : engineered cementitious composite (SECC) is a new advanced con...

Vibro-acoustics of lightweight sandwich structures

CERN Document Server

Lu, Tianjian

2014-01-01

Vibro-Acoustics of Lightweight Sandwich Structures introduces the study of the coupled vibration and acoustic behavior of lightweight sandwich structures in response to harmonic force and sound pressure. This book focuses on the theoretical modeling and experimental investigation of lightweight sandwich structures in order to provide a predictive framework for vibro-acoustic characteristics of typical engineering structures. Furthermore, by developing solution tools, it concentrates on the influence of key systematic parameters leading to effective guidance for optimal structure design toward lightweight, high-stiffness and superior sound insulation capability. This book is intended for researchers, scientists, engineers and graduate students in mechanical engineering especially in structural mechanics, mechanics and acoustics. Fengxian Xin and Tianjian Lu both work at the School of Aerospace, Xi’an Jiaotong University.

Analytical and numerical models of transport in porous cementitious materials

International Nuclear Information System (INIS)

Garboczi, E.J.; Bentz, D.P.

1990-01-01

Most chemical and physical processes that degrade cementitious materials are dependent on an external source of either water or ions or both. Understanding the rates of these processes at the microstructural level is necessary in order to develop a sound scientific basis for the prediction and control of the service life of cement-based materials, especially for radioactive-waste containment materials that are required to have service lives on the order of hundreds of years. An important step in developing this knowledge is to understand how transport coefficients, such as diffusivity and permeability, depend on the pore structure. Fluid flow under applied pressure gradients and ionic diffusion under applied concentration gradients are important transport mechanisms that take place in the pore space of cementitious materials. This paper describes: (1) a new analytical percolation-theory-based equation for calculating the permeability of porous materials, (2) new computational methods for computing effective diffusivities of microstructural models or digitized images of actual porous materials, and (3) a new digitized-image mercury intrusion simulation technique

Viscoelastic stress modeling in cementitious materials using constant viscoelastic hydration modulus

NARCIS (Netherlands)

Hansen, W.; Liu, Z.; Koenders, E.A.B.

2014-01-01

Viscoelastic stress modeling in ageing cementitious materials is of major importance in high performance concrete of low water cement ratio (e.g. w/c ~0.35) where crack resistance due to deformation restraint needs to be determined. Total stress analysis is complicated by the occurrence of internal

Methyl methacrylate as a healing agent for self-healing cementitious materials

International Nuclear Information System (INIS)

Van Tittelboom, K; De Belie, N; Adesanya, K; Dubruel, P; Van Puyvelde, P

2011-01-01

Different types of healing agents have already been tested on their efficiency for use in self-healing cementitious materials. Generally, commercial healing agents are used while their properties are adjusted for manual crack repair and not for autonomous crack healing. Consequently, the amount of regain in properties due to self-healing of cracks is limited. In this research, a methyl methacrylate (MMA)-based healing agent was developed specifically for use in self-healing cementitious materials. Various parameters were optimized including the viscosity, curing time, strength, etc. After the desired properties were obtained, the healing agent was encapsulated and screened for its self-healing efficiency. The decrease in water permeability due to autonomous crack healing using MMA as a healing agent was similar to the results obtained for manually healed cracks. First results seem promising: however, further research needs to be undertaken in order to obtain an optimal healing agent ready for use in practice

Performance of lightweight large C/SiC mirror

Science.gov (United States)

Yui, Yukari Y.; Goto, Ken; Kaneda, Hidehiro; Katayama, Haruyoshi; Kotani, Masaki; Miyamoto, Masashi; Naitoh, Masataka; Nakagawa, Takao; Saruwatari, Hideki; Suganuma, Masahiro; Sugita, Hiroyuki; Tange, Yoshio; Utsunomiya, Shin; Yamamoto, Yasuji; Yamawaki, Toshihiko

2017-11-01

Very lightweight mirror will be required in the near future for both astronomical and earth science/observation missions. Silicon carbide is becoming one of the major materials applied especially to large and/or light space-borne optics, such as Herschel, GAIA, and SPICA. On the other hand, the technology of highly accurate optical measurement of large telescopes, especially in visible wavelength or cryogenic circumstances is also indispensable to realize such space-borne telescopes and hence the successful missions. We have manufactured a very lightweight Φ=800mm mirror made of carbon reinforced silicon carbide composite that can be used to evaluate the homogeneity of the mirror substrate and to master and establish the ground testing method and techniques by assembling it as the primary mirror into an optical system. All other parts of the optics model are also made of the same material as the primary mirror. The composite material was assumed to be homogeneous from the mechanical tests of samples cut out from the various areas of the 800mm mirror green-body and the cryogenic optical measurement of the mirror surface deformation of a 160mm sample mirror that is also made from the same green-body as the 800mm mirror. The circumstance and condition of the optical testing facility has been confirmed to be capable for the highly precise optical measurements of large optical systems of horizontal light axis configuration. Stitching measurement method and the algorithm for analysis of the measurement is also under study.

Enhancement Experiment on Cementitious Activity of Copper-Mine Tailings in a Geopolymer System

Directory of Open Access Journals (Sweden)

Lin Yu

2017-12-01

Full Text Available Copper-mine tailings are the residual products after the extraction of precious copper metal from copper ores, and their storage can create numerous environmental problems. Many researchers have used copper-mine tailings for the preparation of geopolymers. This paper studies the enhancement of the cementitious activity of copper-mine tailings in geopolymer systems. First, copper-mine tailings are activated through mechanical grinding activation. Then, the mechanically activated copper-mine tailings are further processed through thermal activation and alkaline-roasting activation. The cementitious activity index of copper-mine tailings is characterized through the degree of leaching concentration of Si and Al. It was observed that the Si and Al leaching concentration of mechanically activated tailings was increased by 26.03% and 93.33%, respectively. The concentration of Si and Al was increased by 54.19% and 119.92%, respectively. For alkaline-roasting activation, roasting time, temperature and the mass ratio of copper-mine tailings to NaOH (C/N ratio were evaluated through orthogonal tests, and the best condition for activation was 120 min at 600 °C with a C/N ratio of 5:1. In this study, scanning electron microscopy (SEM, X-ray diffraction (XRD and infra-red (IR analysis show that mechanical, thermal and alkaline-roasting activation could be used to improve the cementitious activity index of copper-mine tailings.

Evaluation of the Strength Variation of Normal and Lightweight Self-Compacting Concrete in Full Scale Walls

DEFF Research Database (Denmark)

Hosseinali, M.; Ranjbar, M. M.; Rezvani, S. M.

2011-01-01

-destructive testing. Self-compacting concrete (SCC) and lightweight self-compacting concrete (LWSCC) with different admixtures were tested and compared with normal concrete (NC). The results were also compared with results for standard cubic samples. The results demonstrate the effect of concrete type on the in situ......The strength of cast concrete along the height and length of large structural members might vary due to inadequate compaction, segregation, bleeding, head pressure, and material type. The distribution of strength within a series of full scale reinforced concrete walls was examined using non...

Cryptanalysis of Some Lightweight Symmetric Ciphers

DEFF Research Database (Denmark)

Abdelraheem, Mohamed Ahmed Awadelkareem Mohamed Ahmed

In recent years, the need for lightweight encryption systems has been increasing as many applications use RFID and sensor networks which have a very low computational power and thus incapable of performing standard cryptographic operations. In response to this problem, the cryptographic community...... on a variant of PRESENT with identical round keys. We propose a new attack named the Invariant Subspace Attack that was specifically mounted against the lightweight block cipher PRINTcipher. Furthermore, we mount several attacks on a recently proposed stream cipher called A2U2....... of the international standards in lightweight cryptography. This thesis aims at analyzing and evaluating the security of some the recently proposed lightweight symmetric ciphers with a focus on PRESENT-like ciphers, namely, the block cipher PRESENT and the block cipher PRINTcipher. We provide an approach to estimate...

sp2 carbon allotropes in elastomer matrix: From master curves for the mechanical reinforcement to lightweight materials

Directory of Open Access Journals (Sweden)

M. Galimberti

2018-03-01

Full Text Available This work presents high surface area sp2 carbon allotropes as important tools to design and prepare lightweight materials. Composites were prepared based on either carbon black (CB or carbon nanotubes (CNT or hybrid CB/CNT filler systems, with either poly(1,4-cis-isoprene or poly(styrene-co-butadiene as the polymer matrix. A correlation was established between the specific interfacial area (i.a., i.e. the surface made available by the filler per unit volume of composite, and the initial modulus of the composite (G′γmin, determined through dynamic mechanical shear tests. Experimental points could be fitted with a common line, a sort of master curve, up to about 30.2 and 9.8 mass% as CB and CNT content, respectively. The equation of such master curve allowed to correlate modulus and density of the composite. Thanks to the master curve, composites with the same modulus and lower density could be designed by substituting part of CB with lower amount of the carbon allotrope with larger surface area, CNT. This work establishes a quantitative correlation as a tool to design lightweight materials and paves the way for large scale application in polymer matrices of innovative sp2 carbon allotropes.

Micromechanical properties of a new polymeric microcapsule for self-healing cementitious materials

NARCIS (Netherlands)

Lv, Leyang; Schlangen, H.E.J.G.; Yang, Z.; Xing, Feng

2016-01-01

Self-healing cementitious materials containing a microencapsulated healing agent are appealing due to their great application potential in improving the serviceability and durability of concrete structures. In this study, poly(phenol-formaldehyde) (PF) microcapsules that aim to provide a

Investigation on Wall Panel Sandwiched With Lightweight Concrete

Science.gov (United States)

Lakshmikandhan, K. N.; Harshavardhan, B. S.; Prabakar, J.; Saibabu, S.

2017-08-01

The rapid population growth and urbanization have made a massive demand for the shelter and construction materials. Masonry walls are the major component in the housing sector and it has brittle characteristics and exhibit poor performance against the uncertain loads. Further, the structure requires heavier sections for carrying the dead weight of masonry walls. The present investigations are carried out to develop a simple, lightweight and cost effective technology for replacing the existing wall systems. The lightweight concrete is developed for the construction of sandwich wall panel. The EPS (Expanded Polystyrene) beads of 3 mm diameter size are mixed with concrete and developed a lightweight concrete with a density 9 kN/m3. The lightweight sandwich panel is cast with a lightweight concrete inner core and ferrocement outer skins. This lightweight wall panel is tested for in-plane compression loading. A nonlinear finite element analysis with damaged plasticity model is carried out with both material and geometrical nonlinearities. The experimental and analytical results were compared. The finite element study predicted the ultimate load carrying capacity of the sandwich panel with reasonable accuracy. The present study showed that the lightweight concrete is well suitable for the lightweight sandwich wall panels.

Cementitious Barriers Partnership (CBP): Training and Release of CBP Toolbox Software, Version 1.0 - 13480

International Nuclear Information System (INIS)

Brown, K.G.; Kosson, D.S.; Garrabrants, A.C.; Sarkar, S.; Flach, G.; Langton, C.; Smith, F.G. III; Burns, H.; Van der Sloot, H.; Meeussen, J.C.L.; Samson, E.; Mallick, P.; Suttora, L.; Esh, D.; Fuhrmann, M.; Philip, J.

2013-01-01

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the Office of Tank Waste Management within the Office of Environmental Management of U.S. Department of Energy (US DOE). The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that improve understanding and predictions of the long-term hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program are intended to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to or longer than 100 years for operating facilities and longer than 1,000 years for waste management purposes. CBP software tools were made available to selected DOE Office of Environmental Management and field site users for training and evaluation based on a set of important degradation scenarios, including sulfate ingress/attack and carbonation of cementitious materials. The tools were presented at two-day training workshops held at U.S. National Institute of Standards and Technology (NIST), Savannah River, and Hanford included LeachXS TM /ORCHESTRA, STADIUM R , and a CBP-developed GoldSim Dashboard interface. Collectively, these components form the CBP Software Toolbox. The new U.S. Environmental Protection Agency leaching test methods based on the Leaching Environmental Assessment Framework (LEAF) were also presented. The CBP Dashboard uses a custom Dynamic-link library developed by CBP to couple to the LeachXS TM /ORCHESTRA and STADIUM R codes to simulate reactive transport and degradation in cementitious materials for selected performance assessment scenarios. The first day of the workshop introduced participants to the software components via presentation materials, and the second day included hands-on tutorial exercises followed by discussions

FY2016 Lightweight Materials Annual Progress Report

Energy Technology Data Exchange (ETDEWEB)

None, None

2017-10-31

The Lightweight Materials research and development (R&D) area within the DOE Vehicle Technologies Office (VTO) provides support and guidance for many cutting-edge automotive technologies under development. Research focuses on addressing critical barriers to commercializing lightweight materials for passenger and commercial vehicles. This report describes the progress made on the research and development projects funded by the Lightweight Materials area.

Bond Characteristics of Macro Polypropylene Fiber in Cementitious Composites Containing Nanosilica and Styrene Butadiene Latex Polymer

Directory of Open Access Journals (Sweden)

Jae-Woong Han

2015-01-01

Full Text Available This study evaluated the bond properties of polypropylene (PP fiber in plain cementitious composites (PCCs and styrene butadiene latex polymer cementitious composites (LCCs at different nanosilica contents. The bond tests were evaluated according to JCI SF-8, in which the contents of nanosilica in the cement were 0, 2, 4, 6, 8, and 10 wt%, based on cement weight. The addition of nanosilica significantly affected the bond properties between macro PP fiber and cementitious composites. For PCCs, the addition of 0–2 wt% nanosilica enhanced bond strength and interface toughness, whereas the addition of 4 wt% or more reduced bond strength and interface toughness. The bond strength and interfacial toughness of LCCs also increased with the addition of up to 6% nanosilica. The analysis of the relative bond strength showed that the addition of nanosilica affects the bond properties of both PCC and LCC. This result was confirmed via microstructural analysis of the macro PP fiber surface after the bond tests, which revealed an increase in scratches due to frictional forces and fiber tearing.

Treated Coconut Coir Pith as Component of Cementitious Materials

OpenAIRE

Koňáková, Dana; Vejmelková, Eva; Čáchová, Monika; Siddique, Jamal Akhter; Polozhiy, Kirill; Reiterman, Pavel; Keppert, Martin; Černý, Robert

2015-01-01

The presented paper deals with utilization of raw and treated coir pith as potential component of cementitious composites. The studied material is coir pith originating from a coconut production. Its applicability as cement mixture component was assessed in terms of the physical properties of concrete containing different amount of coir pith. Basic physical properties, compressive and bending strength, and hygric transport characteristics as well as thermal properties belong among the studied...

LIGHT-WEIGHT LOAD-BEARING STRUCTURE

DEFF Research Database (Denmark)

2009-01-01

The invention relates to a light-weight load-bearing structure (1) with optimized compression zone (2), where along one or more compression zones (2) in the structure (1) to be cast a core (3) of strong concrete is provided, which core (3) is surrounded by concrete of less strength (4) compared...... to the core (3) of strong concrete. The invention also relates to a method of casting of light-weight load-bearing structures (1) with optimized compression zone (2) where one or more channels, grooves, ducts, pipes and/or hoses (5) formed in the load-bearing structure (1) serves as moulds for moulding one...... or more cores (3) of strong concrete in the light-weight load-bearing structure (1)....

Mix design and properties of fly ash waste lightweight aggregates in structural lightweight concrete

Directory of Open Access Journals (Sweden)

Manu S. Nadesan

2017-12-01

Full Text Available Concrete is one of the most widely used construction materials and has the ability to consume industrial wastes in high volume. As the demand for concrete is increasing, one of the effective ways to reduce the undesirable environmental impact of the concrete is by the use of waste and by-product materials as cement and aggregate substitutes in concrete. One such waste material is fly ash, which is produced in large quantities from thermal power plants as a by-product. A substantial amount of fly ash is left unused posing environmental and storage problems. The production of sintered lightweight aggregate with fly ash is an effective method to dispose of fly ash in large quantities. Due to lack of a proper mix design procedure, the production and application of lightweight aggregate in structural concrete are not much entertained. The absorption characteristic of lightweight aggregate is a major concern, while developing the mix proportioning of lightweight concretes. The present study is an attempt to establish a new mix design procedure for the development of sintered fly ash lightweight aggregate concretes, which is simple and more reliable than the existing procedures. Also, the proposed methodology has been validated by developing a spectrum of concretes having water cement ratios varying from 0.25 to 0.75. From the study, it is obvious that the development of 70 MPa concrete is possible by using cement alone without any additives. Also, it is ensured that all the concretes have densities less than 2000 kg/m3.

An alternative approach to the management of reactive metals: tolerant cementitious systems

International Nuclear Information System (INIS)

Swift, P.; Cox, J.; Wise, M.; McKinney, J.; Rhodes, C.

2015-01-01

In recent years research has focused on preventing or minimising corrosion of reactive metals to ensure long-term waste package integrity. An alternative approach to the encapsulation of reactive metals is being explored. The approach will identify a cementitious-based encapsulating material that will allow corrosion of reactive metals to occur in a controlled and predictable manner, rather than seeking to limit or prevent the corrosion, whilst retaining waste package integrity. A low strength grout will be developed that will be 'tolerant' to the expansive forces generated by the corrosion products of reactive metals. Novel cementitious systems (e.g. foamed cements, rubber composite cements, cenosphere composite cements, lime mortars, bentonite cements etc.) that may be tolerant to potentially expansive waste products, such as reactive metals will be considered and assessed in a series of small-scale preliminary trials (compressive strength, porosity, permeability, pore solution pH, etc.)

Detection of metal fibres in cementitious composites based on signal and image processing approaches

Czech Academy of Sciences Publication Activity Database

Vala, J.; Hobst, L.; Kozák, Vladislav

2015-01-01

Roč. 10, č. 1 (2015), s. 39-46 ISSN 1991-8747 Institutional support: RVO:68081723 Keywords : Cementitious composites * Computational simulation * Non-destructive testing Subject RIV: JI - Composite Materials

Design of ultra-lightweight concrete: towards monolithic concrete structures

Directory of Open Access Journals (Sweden)

Yu Qing Liang

2014-04-01

Full Text Available This study addresses the development of ultra-lightweight concrete. A moderate strength and an excellent thermal conductivity of the lightweight concrete are set as the design targets. The designed lightweight aggregates concrete is targeted to be used in monolithic concrete façade structure, performing as both load bearing element and thermal insulator. The developed lightweight concrete shows excellent thermal properties, with a low thermal conductivity of about 0.12 W/(m·K; and moderate mechanical properties, with 28-day compressive strengths of about 10-12 N/mm . This combination of values exceeds, to the researchers’ knowledge, the performance of all other lightweight building materials. Furthermore, the developed lightweight concrete possesses excellent durability properties.

Security Isolation Strategy Mechanism for Lightweight Virtualization Environment

Directory of Open Access Journals (Sweden)

Liu Qian

2017-01-01

Full Text Available For cloud service providers, lightweight virtualization is a more economical way of virtualization. While the user is worried about the safety of applications and data of the container, due to the container sharing the underlying interface and the kernel, therefore the security and trusted degree of lightweight virtualization container isolation mechanism is critical for the promotion of lightweight virtualization service. Because the user cannot directly participate in the process of the construction and management of container isolation mechanism, it is difficult for them to establish confidence in the security and trusted degree of container isolation mechanism. Based on the research and analysis of system credible and virtualization isolation mechanism, this paper puts forward a set of lightweight virtualization security isolation strategy mechanism, divides lightweight virtualization container storage address space into several parts, puts forward the definition of lightweight virtualization security isolation, gives the formal description and proof of container security isolation strategy, and combines with related technology to verify the feasibility of lightweight virtualization security isolation strategy mechanism. The mechanism has important guiding significance for cloud services providers to deploy container security isolation.

Implications of the use of low-pH cementitious materials in high activity radioactive waste repositories

International Nuclear Information System (INIS)

Garcia Calvo, J.L.; Alonso, M.C.; Fernandez Luco, L.; Hidalgo, A.; Sanchez, M.

2008-01-01

One of the most accepted engineering construction concepts for high radioactive nuclear waste of underground repositories considers the use of low pH cementitious materials, in order to avoid the formation of an alkaline plume fluid which perturbs one of the engineered barriers of the repository, the bentonite. The accepted solution to maintain the bentonite stability, which is function of the pH, is to develop cementitious materials that generate pore waters with pH ≤ 11, because the corrosion velocity of the clay is significantly reduced below this value. The IETcc-CSIC has focused the research activity on low-pH cementitious materials using two cements: Ordinary Portland Cements (OPC) and Calcium Aluminates Cements (CAC). In both cases, the achievement of a low-pH environment implies the use of high content of mineral admixtures to prepare the binder. Obviously, the inclusion of high contents of mineral admixtures in the cement formulation modifies most of the concrete 'standard' properties and the microstructure of the obtained cement products. When designing a concrete based on low-pH binders, not only the functional requirements have to be reached but also the modifications of the basic properties of the concrete must be taken into account. Besides, due to the location and the long service life of this type of products, their durability properties must be also guaranteed. This paper deals with the procedure followed in the design of a specific application of low pH cements; for instance, the shotcrete plug fabrication. The challenge of this type of use (shotcreting) is more complex taking into account that requires the employment of additives that must be compatible with the concrete mixture. Furthermore, their effectiveness must be assured without increase the pH above the admissible levels. Therefore, their compatibility with admixtures is tested in the present work. The compliance of the requirements for a shotcrete plug was evaluated at laboratory scale

Temporary Cementitious Sealers in Enhanced Geothermal Systems

Energy Technology Data Exchange (ETDEWEB)

Sugama T.; Pyatina, T.; Butcher, T.; Brothers, L.; Bour, D.

2011-12-31

Unlike conventional hydrothennal geothermal technology that utilizes hot water as the energy conversion resources tapped from natural hydrothermal reservoir located at {approx}10 km below the ground surface, Enhanced Geothermal System (EGS) must create a hydrothermal reservoir in a hot rock stratum at temperatures {ge}200 C, present in {approx}5 km deep underground by employing hydraulic fracturing. This is the process of initiating and propagating a fracture as well as opening pre-existing fractures in a rock layer. In this operation, a considerable attention is paid to the pre-existing fractures and pressure-generated ones made in the underground foundation during drilling and logging. These fractures in terms of lost circulation zones often cause the wastage of a substantial amount of the circulated water-based drilling fluid or mud. Thus, such lost circulation zones must be plugged by sealing materials, so that the drilling operation can resume and continue. Next, one important consideration is the fact that the sealers must be disintegrated by highly pressured water to reopen the plugged fractures and to promote the propagation of reopened fractures. In response to this need, the objective of this phase I project in FYs 2009-2011 was to develop temporary cementitious fracture sealing materials possessing self-degradable properties generating when {ge} 200 C-heated scalers came in contact with water. At BNL, we formulated two types of non-Portland cementitious systems using inexpensive industrial by-products with pozzolanic properties, such as granulated blast-furnace slag from the steel industries, and fly ashes from coal-combustion power plants. These byproducts were activated by sodium silicate to initiate their pozzolanic reactions, and to create a cemetitious structure. One developed system was sodium silicate alkali-activated slag/Class C fly ash (AASC); the other was sodium silicate alkali-activated slag/Class F fly ash (AASF) as the binder of temper

Lightweight Materials for Automotive Application: An Assessment of Material Production Data for Magnesium and Carbon Fiber

Energy Technology Data Exchange (ETDEWEB)

Johnson, M. C. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; Sullivan, J. L. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division

2014-09-01

The use of lightweight materials in vehicle components, also known as “lightweighting,” can result in automobile weight reduction, which improves vehicle fuel economy and generally its environmental footprint. Materials often used for vehicle lightweighting include aluminum, magnesium, and polymers reinforced with either glass or carbon fiber. However, because alternative materials typically used for vehicle lightweighting require more energy to make on a per part basis than the material being replaced (often steel or iron), the fuel efficiency improvement induced by a weight reduction is partially offset by an increased energy for the vehicle material production. To adequately quantify this tradeoff, reliable and current values for life-cycle production energy are needed for both conventional and alternative materials. Our focus here is on the production of two such alternative materials: magnesium and carbon fibers. Both these materials are low density solids with good structural properties. These properties have enabled their use in applications where weight is an issue, not only for automobiles but also for aerospace applications. This report addresses the predominant production methods for these materials and includes a tabulation of available material and energy input data necessary to make them. The life cycle inventory (LCI) information presented herein represents a process chain analysis (PCA) approach to life cycle assessment (LCA) and is intended for evaluation as updated materials production data for magnesium and carbon fiber for inclusion into the Greenhouse gases, Regulated Emissions, and Energy use in Transportation model (GREET2_2012). The summary life-cycle metrics used to characterize the cradle-to-gate environmental performance of these materials are the cumulative energy demand (CED) and greenhouse gas emissions (GHG) per kilogram of material.

A Comprehensive Study of the Polypropylene Fiber Reinforced Fly Ash Based Geopolymer

DEFF Research Database (Denmark)

Ranjbar, Navid; Mehrali, Mehdi; Behnia, Arash

2016-01-01

and long term impacts of different volume percentages of polypropylene fiber (PPF) reinforcement on fly ash based geopolymer composites. Different characteristics of the composite were compared at fresh state by flow measurement and hardened state by variation of shrinkage over time to assess the response...... of composites under flexural and compressive load conditions. The fiber-matrix interface, fiber surface and toughening mechanisms were assessed using field emission scan electron microscopy (FESEM) and atomic force microscopy (AFM). The results show that incorporation of PPF up to 3 wt % into the geopolymer......As a cementitious material, geopolymers show a high quasi-brittle behavior and a relatively low fracture energy. To overcome such a weakness, incorporation of fibers to a brittle matrix is a well-known technique to enhance the flexural properties. This study comprehensively evaluates the short...

Analytical design model for a piezo-composite unimorph actuator and its verification using lightweight piezo-composite curved actuators

Science.gov (United States)

Yoon, K. J.; Park, K. H.; Lee, S. K.; Goo, N. S.; Park, H. C.

2004-06-01

This paper describes an analytical design model for a layered piezo-composite unimorph actuator and its numerical and experimental verification using a LIPCA (lightweight piezo-composite curved actuator) that is lighter than other conventional piezo-composite type actuators. The LIPCA is composed of top fiber composite layers with high modulus and low CTE (coefficient of thermal expansion), a middle PZT ceramic wafer, and base layers with low modulus and high CTE. The advantages of the LIPCA design are to replace the heavy metal layer of THUNDER by lightweight fiber-reinforced plastic layers without compromising the generation of high force and large displacement and to have design flexibility by selecting the fiber direction and the number of prepreg layers. In addition to the lightweight advantage and design flexibility, the proposed device can be manufactured without adhesive layers when we use a resin prepreg system. A piezo-actuation model for a laminate with piezo-electric material layers and fiber composite layers is proposed to predict the curvature and residual stress of the LIPCA. To predict the actuation displacement of the LIPCA with curvature, a finite element analysis method using the proposed piezo-actuation model is introduced. The predicted deformations are in good agreement with the experimental ones.

Geochemical performance of earthen and cementitious sealing materials for radioactive waste repositories

International Nuclear Information System (INIS)

Melchoir, D.; Glazier, R.; Marton, R.

1988-01-01

Earthen and cementitious materials are proposed as part of the sealing system for radioactive waste repositories. Compacted clay-bearing earthen materials could be used in sealing shafts and shaft entryways; and in the waste emplacement boundary areas in some repository designs. Earthen material mixtures are being considered because they can be engineered and emplaced to achieve low permeabilities, appropriate swelling characteristics, and adequate strength with little tendency to degrade during changing environmental conditions. The proposed earthen sealing materials include sodium and calcium mont-morillonites, illites, and mixtures with graded aggregates of sand. To assess the relative advantages and disadvantages of various pure and mixed materials, important geochemical processes (e.g., ion-exchange, phase transformation, dissolution, and precipitation of secondary minerals) need to be evaluated. These processes could impact seal integrity by changing permeability and/or mineral swell potential. Hydrous calcium-silicate-based cementitious materials such as grouts or concrete might also be used in some proposed sealing systems

Fracture propagation in cementitious materials

DEFF Research Database (Denmark)

Skocek, Jan

, it is experimentally observed and numerically veried that the cracking plays an important role in mode-I as well as compressive experiments. The approximative particle model extended for materials with heterogeneous matrices predicts strengths matching favorably experimental records in a qualitative way.......Mechanical behavior of structures made from cementitious materials has been successfully modeled using non-linear fracture mechanics in recent decades. On the structural scale, an assumption of homogeneity of the material is valid and well established theories can be applied. However, if focus...... is put on phenomena of a similar scale as is the characteristic size of inhomogeneities of the material, a model which re ects the heterogeneous nature of the material needs to be applied. This is, indeed, the case for prediction of mechanical properties of a material based on the knowledge of properties...

Lightweight Composite Materials for Heavy Duty Vehicles

Energy Technology Data Exchange (ETDEWEB)

Pruez, Jacky; Shoukry, Samir; Williams, Gergis; Shoukry, Mark

2013-08-31

The main objective of this project is to develop, analyze and validate data, methodologies and tools that support widespread applications of automotive lightweighting technologies. Two underlying principles are guiding the research efforts towards this objective: • Seamless integration between the lightweight materials selected for certain vehicle systems, cost-effective methods for their design and manufacturing, and practical means to enhance their durability while reducing their Life-Cycle-Costs (LCC). • Smooth migration of the experience and findings accumulated so far at WVU in the areas of designing with lightweight materials, innovative joining concepts and durability predictions, from applications to the area of weight savings for heavy vehicle systems and hydrogen storage tanks, to lightweighting applications of selected systems or assemblies in light–duty vehicles.

Numerical estimation of transport properties of cementitious materials using 3D digital images

NARCIS (Netherlands)

Ukrainczyk, N.; Koenders, E.A.B.; Van Breugel, K.

2012-01-01

A multi-scale characterisation of the transport process within cementitious microstructure possesses a great challenge in terms of modelling and schematization. In this paper a numerical method is proposed to mitigate the resolution problems in numerical methods for calculating effective transport

Lightweight Phase-Change Material For Solar Power

Science.gov (United States)

Stark, Philip

1993-01-01

Lightweight panels containing phase-change materials developed for use as heat-storage elements of compact, lightweight, advanced solar dynamic power system. During high insolation, heat stored in panels via latent heat of fusion of phase-change material; during low insolation, heat withdrawn from panels. Storage elements consist mainly of porous carbon-fiber structures imbued with germanium. Developed for use aboard space station in orbit around Earth, also adapted to lightweight, compact, portable solar-power systems for use on Earth.

Cementitious artificial aggregate particles for high-skid resistance pavements

OpenAIRE

DE LARRARD, François; MARTINEZ CASTILLO, Rafael; SEDRAN, Thierry; HAUZA, Philippe; POIRIER, Jean Eric

2012-01-01

For some critical road sections, a high skid resistance of wearing course is required to minimise the risk of traffic accidents. Nowadays this skid resistance is mainly brought by the use of special aggregates as calcined bauxite, a scarce and expensive material. The paper presents a patented technology, where a special high-performance mortar is produced and crushed at early age. These cementitious artificial aggregates (CAA) can display aggregate properties close to those of calcined bauxit...

Crushing damage estimation for pavement with lightly cementitious bases

CSIR Research Space (South Africa)

De Beer, Morris

2014-07-01

Full Text Available . Department of Transport. Pretoria, South Africa. Litwinowicz and De Beer., 2013. Long term crushing performance of lightly cementitious pavement materials – update to the South African procedures. Road Materials and Pavement Design. Maina, J.W., De... Beer, M. and van Rensburg, Y., 2013. Modelling Tyre-Road Contact Stresses in Pavement Design and Analysis. Proceedings of 32nd Southern Africa transport conference, Pretoria, July 2013. pp 336-345: SAPDM, (2014). http://www.sapdm.co.za/, last...

Chloride transport in mortar at low moisture concentration

NARCIS (Netherlands)

Taher, A.; Zanden, van der A.J.J.; Brouwers, H.J.H.

2014-01-01

Chloride penetration into cementitious structures with a steel reinforcement results in corrosion of the steel. Concrete columns of bridges, which are in frequent contact with sea water, are an example of these structures. Understanding the chloride transport in cementitious materials can lead to

Cementitious Barriers Partnership (CBP): Training and Release of CBP Toolbox Software, Version 1.0 - 13480

Energy Technology Data Exchange (ETDEWEB)

Brown, K.G.; Kosson, D.S.; Garrabrants, A.C.; Sarkar, S. [Vanderbilt University, School of Engineering, CRESP, Nashville, TN 37235 (United States); Flach, G.; Langton, C.; Smith, F.G. III; Burns, H. [Savannah River National Laboratory, Aiken, SC 29808 (United States); Van der Sloot, H. [Hans Van der Sloot Consultancy, Dorpsstraat 216, 1721BV Langedijk (Netherlands); Meeussen, J.C.L. [Nuclear Research and Consultancy Group, Westerduinweg 3, Petten (Netherlands); Samson, E. [SIMCO Technologies, Inc., Quebec (Canada); Mallick, P.; Suttora, L. [U.S. Department of Energy, Washington, DC (United States); Esh, D.; Fuhrmann, M.; Philip, J. [U.S. Nuclear Regulatory Commission, Washington, DC (United States)

2013-07-01

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the Office of Tank Waste Management within the Office of Environmental Management of U.S. Department of Energy (US DOE). The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that improve understanding and predictions of the long-term hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program are intended to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to or longer than 100 years for operating facilities and longer than 1,000 years for waste management purposes. CBP software tools were made available to selected DOE Office of Environmental Management and field site users for training and evaluation based on a set of important degradation scenarios, including sulfate ingress/attack and carbonation of cementitious materials. The tools were presented at two-day training workshops held at U.S. National Institute of Standards and Technology (NIST), Savannah River, and Hanford included LeachXS{sup TM}/ORCHESTRA, STADIUM{sup R}, and a CBP-developed GoldSim Dashboard interface. Collectively, these components form the CBP Software Toolbox. The new U.S. Environmental Protection Agency leaching test methods based on the Leaching Environmental Assessment Framework (LEAF) were also presented. The CBP Dashboard uses a custom Dynamic-link library developed by CBP to couple to the LeachXS{sup TM}/ORCHESTRA and STADIUM{sup R} codes to simulate reactive transport and degradation in cementitious materials for selected performance assessment scenarios. The first day of the workshop introduced participants to the software components via presentation materials, and the second day included hands-on tutorial exercises followed

Micro-structural characterization of the hydration products of bauxite-calcination-method red mud-coal gangue based cementitious materials.

Science.gov (United States)

Liu, Xiaoming; Zhang, Na; Yao, Yuan; Sun, Henghu; Feng, Huan

2013-11-15

In this research, the micro-structural characterization of the hydration products of red mud-coal gangue based cementitious materials has been investigated through SEM-EDS, (27)Al MAS NMR and (29)Si MAS NMR techniques, in which the used red mud was derived from the bauxite calcination method. The results show that the red mud-coal gangue based cementitious materials mainly form fibrous C-A-S-H gel, needle-shaped/rod-like AFt in the early hydration period. With increasing of the hydration period, densification of the pastes were promoted resulting in the development of strength. EDS analysis shows that with the Ca/Si of red mud-coal gangue based cementitious materials increases, the average Ca/Si and Ca/(Si+Al) atomic ratio of C-A-S-H gel increases, while the average Al/Si atomic ratio of C-A-S-H gel decreases. MAS NMR analysis reveals that Al in the hydration products of red mud-coal gangue based cementitious materials exists in the forms of Al(IV) and Al(VI), but mainly in the form of Al(VI). Increasing the Ca/Si ratio of raw material promotes the conversion of [AlO4] to [AlO6] and inhibits the combination between [AlO4] and [SiO4] to form C-A-S-H gel. Meanwhile, the polymerization degree of [SiO4] in the hydration products declines. Published by Elsevier B.V.

Toughness increase of self compacting concrete reinforced with polypropylene short fibers

Directory of Open Access Journals (Sweden)

Melián, G.

2010-12-01

Full Text Available Increases in bending tests by the addition of low volume fractions of Polypropylene (PP Short Fibers PP. These toughness increases are similar to those attained by Fiber Reinforced Concrete (FRC referred elsewhere as Engineered Cementitious Composites (ECC, having some ductility and strain hardening in direct tensile and flexural tests. Concretes mixtures were manufactured using natural pozzolanic blended Portland cement, volcanic crushed coarse aggregates and fine sand from Sahara desert dunes (0-1 mm from Canary Islands quarries and sand reservoirs, respectively, besides ordinary siliceous sand (0-4 mm and fly ash from an anthracite-coal heat generator.

Se presentan en este artículo hormigones autocompactables que, mediante la adición de pequeñas fracciones volumétricas de fibras cortas de polipropileno, consiguen incrementos importantes de tenacidad en su comportamiento mecánico a flexión. Estos aumentos de tenacidad son semejantes a los que presentan un grupo de hormigones reforzados con fibras, denominados ECC (Engineered Cementitious Composites, que muestran también alguna ductilidad y endurecimiento por deformación en ensayos de tracción directa y flexión. Los hormigones se dosificaron empleando cemento Pórtland con Puzolana natural, áridos volcánicos de machaqueo y arena fina procedente de dunas del desierto del Sáhara (0-1 mm, de canteras y depósitos de Las Palmas de Gran Canaria (Islas Canarias, respectivamente, además de arena silícea ordinaria (0-4 mm y cenizas volantes de una central térmica de combustible antracita.

Interaction between microcapsules and cementitious matrix after cracking in a self-healing system

NARCIS (Netherlands)

Wang, X.; Xing, F.; Zhang, M.; Han, N.; Qian, Z.

2013-01-01

A new type of self-healing cementitious composites by using organic microcapsules is designed in Guangdong Key Laboratory of Durability for Coastal Civil Engineering, Shenzhen University. For the organic microcapsules, the shell material is urea formoldehyde (UF), and the core healing agent is

Interaction of low pH cementitious concretes with groundwaters

International Nuclear Information System (INIS)

Garcia Calvo, Jose Luis; Alonso, Maria Cruz; Hidalgo, Ana; Fernandez Luco, Luis

2012-01-01

Some engineering construction concepts for high level radioactive waste underground repositories consider the use of a bentonite barrier in contact with cementitious materials with a pore fluid pH value inferior or equal to 11 (based on low-pH cements) to maintain the bentonite stability. The research on low-pH cementitious materials is mainly addressed from two different approaches, one with Calcium Silicate Cements (OPC, Ordinary Portland Cement based), the other with Calcium Aluminates Cements (CAC based). The use of these both types of cements (OPC based or CAC based) implies the use of high mineral additions contents in the binder that should significantly modify most of the concrete 'standard' properties. Taking into account the long life expected in this type of repositories, parameters related to the durability of the low-pH concretes must be analyzed. This work shows some recent studies that deal with the evaluation of the resistance of low-pH concretes to long term groundwater aggression. After a presentation of the accelerated leaching test (based on a percolation method), results are given for the characterization of the leaching solution evolution and the evaluation of the modifications generated in the solid phases. Results show that the low-pH concretes evaluated have good resistance against groundwater interaction, although an altered front can be observed from the surface in all the tested samples

Mechanical behaviour of textile-reinforced thermoplastics with integrated sensor network components

International Nuclear Information System (INIS)

Hufenbach, W.; Adam, F.; Fischer, W.-J.; Kunadt, A.; Weck, D.

2011-01-01

Highlights: → Consideration of two types of integrated bus systems for textile-reinforced thermoplastics with embedded sensor networks. → Specimens with bus systems made of flexible printed circuit boards show good mechanical performance compared to the reference. → Inhomogeneous interface and reduced stiffnesses and strengths for specimens with bus systems basing on single copper wires. -- Abstract: The embedding of sensor networks into textile-reinforced thermoplastics enables the design of function-integrative lightweight components suitable for high volume production. In order to investigate the mechanical behaviour of such functionalised composites, two types of bus systems are selected as exemplary components of sensor networks. These elements are embedded into glass fibre-reinforced polypropylene (GF/PP) during the layup process of unconsolidated weft-knitted GF/PP-preforms. Two fibre orientations are considered and orthotropic composite plates are manufactured by hot pressing technology. Micrograph investigations and computer tomography analyses show different interface qualities between the thermoplastic composite and the two types of bus systems. Mechanical tests under tensile and flexural loading indicate a significant influence of the embedded bus system elements on the structural stiffness and strength.

Direct Shear Behavior of Fiber Reinforced Concrete Elements

Directory of Open Access Journals (Sweden)

Hussein Al-Quraishi

2018-01-01

Full Text Available Improving the accuracy of load-deformation behavior, failure mode, and ultimate load capacity for reinforced concrete members subjected to in-plane loadings such as corbels, wall to foundation connections and panels need shear strength behavior to be included. Shear design in reinforced concrete structures depends on crack width, crack slippage and roughness of the surface of cracks. This paper illustrates results of an experimental investigation conducted to investigate the direct shear strength of fiber normal strength concrete (NSC and reactive powder concrete (RPC. The tests were performed along a pre-selected shear plane in concrete members named push-off specimens. The effectiveness of concrete compressive strength, volume fraction of steel fiber, and shear reinforcement ratio on shear transfer capacity were considered in this study. Furthermore, failure modes, shear stress-slip behavior, and shear stress-crack width behavior were also presented in this study. Tests’ results showed that volume fraction of steel fiber and compressive strength of concrete in NSC and RPC play a major role in improving the shear strength of concrete. As expectedly, due to dowel action, the shear reinforcement is the predominant factor in resisting the shear stress. The shear failure of NSC and RPC has the sudden mode of failure (brittle failure with the approximately linear behavior of shear stress-slip relationship till failure. Using RPC instead of NSC with the same amount of steel fibers in constructing the push-off specimen result in high shear strength. In NSC, shear strength influenced by the three major factors; crack surface friction, aggregate interlock and steel fiber content if present. Whereas, RPC has only steel fiber and cracks surface friction influencing the shear strength. Due to cementitious nature of RPC in comparisons with NSC, the RPC specimen shows greater cracks width. It is observed that the Mattock model gives very satisfactory

Towards more sustainable construction–application of superabsorbent polymers in cementitious matrices with reduced carbon footprint

Directory of Open Access Journals (Sweden)

Klemm Agnieszka J.

2018-01-01

Full Text Available Construction industry is constantly searching for sustainable innovations to mitigate negative environmental impacts. Ground granulated blast-furnace slag (GGBS is a well-known supplementary cementitious material which contributes to reduction of energy and CO2 emissions from cement industry. However, its use in cementitious systems leads to materials with high cracking susceptibility due to their greater autogenous shrinkage triggered by self-desiccation processes. This problem is even more pronounced when concrete is exposed to severe dry-hot weather conditions, such as in North Africa. In order to mitigate this negative effect of cracking, internal curing agents in the form of Superabsorbent polymers (SAP can be successfully used. This approach leads to more durable cement based materials and in turn more sustainable constructions.

Lightweight males of Podisus nigrispinus (Heteroptera: Pentatomidae neglect lightweight females due low reproductive fitness

Directory of Open Access Journals (Sweden)

A. I. A. Pereira

Full Text Available Abstract Sexual choice by male stink bugs is important because females that experience food shortages lay fewer eggs with lower viability compared with well-fed females. In this study, we investigated whether Podisus nigrispinus (Dallas (Heteroptera: Pentatomidae males fed with a low-quality diet during its nymphal stage show selectivity for sexual partners resulting in high-quality progeny. Lightweight males and females were obtained from nymphs fed weekly with Tenebrio molitor L. (Coleoptera: Tenebrionidae pupae. By contrast, heavyweight males and females were fed three times a week and received an extra nutritional source: cotton leaves, Gossypium hirsutum L. (Malvaceae. Lightweight males preferred to mate with heavy females (77.78 ± 14.69%, whereas heavyweight males did not discriminated between light or heavyweight females. Females mated with lightweight males showed similar levels of reproduction to those mated with heavyweight males. The results provide an indication of the importance of male and female body weight for sexual selection in Asopinae stink bugs.

The Behaviours of Cementitious Materials in Long Term Storage and Disposal of Radioactive Waste. Results of a Coordinated Research Project

International Nuclear Information System (INIS)

2013-09-01

Radioactive waste with widely varying characteristics is generated from the operation and maintenance of nuclear power plants, nuclear fuel cycle facilities, research laboratories and medical facilities. This waste must be treated and conditioned, as necessary, to provide waste forms acceptable for safe storage and disposal. Many countries use cementitious materials (concrete, mortar, etc.) as a containment matrix for immobilization, as well as for engineered structures of disposal facilities. Radionuclide release is dependent on the physicochemical properties of the waste forms and packages, and on environmental conditions. In the use of cement, the diffusion process and metallic corrosion can induce radionuclide release. The advantage of cementitious materials is the added stability and mechanical support during storage and disposal of waste. Long interim storage is becoming an important issue in countries where it is difficult to implement low level waste and intermediate level waste disposal facilities, and in countries where cement is used in the packaging of waste that is not suitable for shallow land disposal. This coordinated research project (CRP), involving 24 research organizations from 21 Member States, investigated the behaviour and performance of cementitious materials used in an overall waste conditioning system based on the use of cement - including waste packaging (containers), waste immobilization (waste form) and waste backfilling - during long term storage and disposal. It also considered the interactions and interdependencies of these individual elements (containers, waste, form, backfill) to understand the processes that may result in degradation of their physical and chemical properties. The main research outcomes of the CRP are summarized in this report under four topical sections: (i) conventional cementitious systems; (ii) novel cementitious materials and technologies; (iii) testing and waste acceptance criteria; and (iv) modelling long

The Behaviours of Cementitious Materials in Long Term Storage and Disposal of Radioactive Waste. Results of a Coordinated Research Project

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-09-15

Radioactive waste with widely varying characteristics is generated from the operation and maintenance of nuclear power plants, nuclear fuel cycle facilities, research laboratories and medical facilities. This waste must be treated and conditioned, as necessary, to provide waste forms acceptable for safe storage and disposal. Many countries use cementitious materials (concrete, mortar, etc.) as a containment matrix for immobilization, as well as for engineered structures of disposal facilities. Radionuclide release is dependent on the physicochemical properties of the waste forms and packages, and on environmental conditions. In the use of cement, the diffusion process and metallic corrosion can induce radionuclide release. The advantage of cementitious materials is the added stability and mechanical support during storage and disposal of waste. Long interim storage is becoming an important issue in countries where it is difficult to implement low level waste and intermediate level waste disposal facilities, and in countries where cement is used in the packaging of waste that is not suitable for shallow land disposal. This coordinated research project (CRP), involving 24 research organizations from 21 Member States, investigated the behaviour and performance of cementitious materials used in an overall waste conditioning system based on the use of cement - including waste packaging (containers), waste immobilization (waste form) and waste backfilling - during long term storage and disposal. It also considered the interactions and interdependencies of these individual elements (containers, waste, form, backfill) to understand the processes that may result in degradation of their physical and chemical properties. The main research outcomes of the CRP are summarized in this report under four topical sections: (i) conventional cementitious systems; (ii) novel cementitious materials and technologies; (iii) testing and waste acceptance criteria; and (iv) modelling long

Mechanical resilience and cementitious processes in Imperial Roman architectural mortar.

Science.gov (United States)

Jackson, Marie D; Landis, Eric N; Brune, Philip F; Vitti, Massimo; Chen, Heng; Li, Qinfei; Kunz, Martin; Wenk, Hans-Rudolf; Monteiro, Paulo J M; Ingraffea, Anthony R

2014-12-30

The pyroclastic aggregate concrete of Trajan's Markets (110 CE), now Museo Fori Imperiali in Rome, has absorbed energy from seismic ground shaking and long-term foundation settlement for nearly two millenia while remaining largely intact at the structural scale. The scientific basis of this exceptional service record is explored through computed tomography of fracture surfaces and synchroton X-ray microdiffraction analyses of a reproduction of the standardized hydrated lime-volcanic ash mortar that binds decimeter-sized tuff and brick aggregate in the conglomeratic concrete. The mortar reproduction gains fracture toughness over 180 d through progressive coalescence of calcium-aluminum-silicate-hydrate (C-A-S-H) cementing binder with Ca/(Si+Al) ≈ 0.8-0.9 and crystallization of strätlingite and siliceous hydrogarnet (katoite) at ≥ 90 d, after pozzolanic consumption of hydrated lime was complete. Platey strätlingite crystals toughen interfacial zones along scoria perimeters and impede macroscale propagation of crack segments. In the 1,900-y-old mortar, C-A-S-H has low Ca/(Si+Al) ≈ 0.45-0.75. Dense clusters of 2- to 30-µm strätlingite plates further reinforce interfacial zones, the weakest link of modern cement-based concrete, and the cementitious matrix. These crystals formed during long-term autogeneous reaction of dissolved calcite from lime and the alkali-rich scoriae groundmass, clay mineral (halloysite), and zeolite (phillipsite and chabazite) surface textures from the Pozzolane Rosse pyroclastic flow, erupted from the nearby Alban Hills volcano. The clast-supported conglomeratic fabric of the concrete presents further resistance to fracture propagation at the structural scale.

Mechanical resilience and cementitious processes in Imperial Roman architectural mortar

Science.gov (United States)

Landis, Eric N.; Brune, Philip F.; Vitti, Massimo; Chen, Heng; Li, Qinfei; Kunz, Martin; Wenk, Hans-Rudolf; Monteiro, Paulo J. M.; Ingraffea, Anthony R.

2014-01-01

The pyroclastic aggregate concrete of Trajan’s Markets (110 CE), now Museo Fori Imperiali in Rome, has absorbed energy from seismic ground shaking and long-term foundation settlement for nearly two millenia while remaining largely intact at the structural scale. The scientific basis of this exceptional service record is explored through computed tomography of fracture surfaces and synchroton X-ray microdiffraction analyses of a reproduction of the standardized hydrated lime–volcanic ash mortar that binds decimeter-sized tuff and brick aggregate in the conglomeratic concrete. The mortar reproduction gains fracture toughness over 180 d through progressive coalescence of calcium–aluminum-silicate–hydrate (C-A-S-H) cementing binder with Ca/(Si+Al) ≈ 0.8–0.9 and crystallization of strätlingite and siliceous hydrogarnet (katoite) at ≥90 d, after pozzolanic consumption of hydrated lime was complete. Platey strätlingite crystals toughen interfacial zones along scoria perimeters and impede macroscale propagation of crack segments. In the 1,900-y-old mortar, C-A-S-H has low Ca/(Si+Al) ≈ 0.45–0.75. Dense clusters of 2- to 30-µm strätlingite plates further reinforce interfacial zones, the weakest link of modern cement-based concrete, and the cementitious matrix. These crystals formed during long-term autogeneous reaction of dissolved calcite from lime and the alkali-rich scoriae groundmass, clay mineral (halloysite), and zeolite (phillipsite and chabazite) surface textures from the Pozzolane Rosse pyroclastic flow, erupted from the nearby Alban Hills volcano. The clast-supported conglomeratic fabric of the concrete presents further resistance to fracture propagation at the structural scale. PMID:25512521

The solubility of nickel and its migration through the cementitious backfill of a geological disposal facility for nuclear waste.

Science.gov (United States)

Felipe-Sotelo, M; Hinchliff, J; Field, L P; Milodowski, A E; Holt, J D; Taylor, S E; Read, D

2016-08-15

This work describes the solubility of nickel under the alkaline conditions anticipated in the near field of a cementitious repository for intermediate level nuclear waste. The measured solubility of Ni in 95%-saturated Ca(OH)2 solution is similar to values obtained in water equilibrated with a bespoke cementitious backfill material, on the order of 5×10(-7)M. Solubility in 0.02M NaOH is one order of magnitude lower. For all solutions, the solubility limiting phase is Ni(OH)2; powder X-ray diffraction and scanning transmission electron microscopy indicate that differences in crystallinity are the likely cause of the lower solubility observed in NaOH. The presence of cellulose degradation products causes an increase in the solubility of Ni by approximately one order of magnitude. The organic compounds significantly increase the rate of Ni transport under advective conditions and show measurable diffusive transport through intact monoliths of the cementitious backfill material. Copyright © 2016 Elsevier B.V. All rights reserved.

Registration of Crystallization Process of Ultra-Lightweight Mg-Li Alloys with Use of ATND Method

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A. Białobrzeski

2007-07-01

Full Text Available Magnesium alloys are characterized by advantageous ratio of strength and/or elastic modulus to density, that is, can sustain static and dynamic loads similar to iron and aluminium, and additionally feature good vibration damping. Castings from magnesium alloys are lighter with about 20 – 30% than aluminium alloys and with 50 – 75% than iron alloys, that is why they are used in aviation and rocket industry and everywhere the weight of a product is of important significance for conditions of its operation. Also automotive industry introduces to vehicle’s structure an elements (castings manufactured from such alloys. On metallic matrix of magnesium alloys with lithium are also manufactured a composites reinforced with e.g. ceramic fiber, which are used as lightweight and resistant structure materials. The paper presents an attempt of implementation of ATND method (Thermal-Voltage-Derivative Analysis to monitoring of crystallization process of ultra-lightweight Mg-Li alloys. Investigated magnesium alloys with contents of about 2,3% Li, 10% Li and 11 % Li were produced in the Foundry Research Institute. Registration of melting and crystallization processes was made with use of the ATND method. Results of preliminary tests are shown in graphical form.

Discrete Model for the Structure and Strength of Cementitious Materials

Science.gov (United States)

Balopoulos, Victor D.; Archontas, Nikolaos; Pantazopoulou, Stavroula J.

2017-12-01

Cementitious materials are characterized by brittle behavior in direct tension and by transverse dilatation (due to microcracking) under compression. Microcracking causes increasingly larger transverse strains and a phenomenological Poisson's ratio that gradually increases to about ν =0.5 and beyond, at the limit point in compression. This behavior is due to the underlying structure of cementitious pastes which is simulated here with a discrete physical model. The computational model is generic, assembled from a statistically generated, continuous network of flaky dendrites consisting of cement hydrates that emanate from partially hydrated cement grains. In the actual amorphous material, the dendrites constitute the solid phase of the cement gel and interconnect to provide the strength and stiffness against load. The idealized dendrite solid is loaded in compression and tension to compute values for strength and Poisson's effects. Parametric studies are conducted, to calibrate the statistical parameters of the discrete model with the physical and mechanical characteristics of the material, so that the familiar experimental trends may be reproduced. The model provides a framework for the study of the mechanical behavior of the material under various states of stress and strain and can be used to model the effects of additives (e.g., fibers) that may be explicitly simulated in the discrete structure.

Carbody structural lightweighting based on implicit parameterized model

Science.gov (United States)

Chen, Xin; Ma, Fangwu; Wang, Dengfeng; Xie, Chen

2014-05-01

Most of recent research on carbody lightweighting has focused on substitute material and new processing technologies rather than structures. However, new materials and processing techniques inevitably lead to higher costs. Also, material substitution and processing lightweighting have to be realized through body structural profiles and locations. In the huge conventional workload of lightweight optimization, model modifications involve heavy manual work, and it always leads to a large number of iteration calculations. As a new technique in carbody lightweighting, the implicit parameterization is used to optimize the carbody structure to improve the materials utilization rate in this paper. The implicit parameterized structural modeling enables the use of automatic modification and rapid multidisciplinary design optimization (MDO) in carbody structure, which is impossible in the traditional structure finite element method (FEM) without parameterization. The structural SFE parameterized model is built in accordance with the car structural FE model in concept development stage, and it is validated by some structural performance data. The validated SFE structural parameterized model can be used to generate rapidly and automatically FE model and evaluate different design variables group in the integrated MDO loop. The lightweighting result of body-in-white (BIW) after the optimization rounds reveals that the implicit parameterized model makes automatic MDO feasible and can significantly improve the computational efficiency of carbody structural lightweighting. This paper proposes the integrated method of implicit parameterized model and MDO, which has the obvious practical advantage and industrial significance in the carbody structural lightweighting design.

Rapid replacement of Tangier Island bridges including lightweight and durable fiber-reinforced polymer deck systems.

Science.gov (United States)

2009-01-01

Fiber-reinforced polymer (FRP) composite cellular deck systems were used as new bridge decks on two replacement bridges on Tangier Island, Virginia. The most important characteristics of this application were reduced self-weight and increased durabil...

Experimental study on microstructure characters of foamed lightweight soil

Science.gov (United States)

Qiu, Youqiang; Li, Yongliang; Li, Meixia; Liu, Yaofu; Zhang, Liujun

2018-01-01

In order to verify the microstructure of foamed lightweight soil and its characters of compressive strength, four foamed lightweight soil samples with different water-soild ratio were selected and the microstructure characters of these samples were scanned by electron microscope. At the same time, the characters of compressive strength of foamed lightweight soil were analyzed from the microstructure. The study results show that the water-soild ratio has a prominent effect on the microstructure and compressive strength of foamed lightweight soil, with the decrease of water-solid ratio, the amount and the perforation of pores would be reduced significantly, thus eventually forming a denser and fuller interior structure. Besides, the denser microstructure and solider pore-pore wall is benefit to greatly increase mechanical intensity of foamed lightweight soil. In addition, there are very few acicular ettringite crystals in the interior of foamed lightweight soil, its number is also reduced with the decrease in water-soild ratio.

Check of hybrid structures and lightweight construction materials. Usage of 3D-CT

Energy Technology Data Exchange (ETDEWEB)

Szepanski, Kamil David [Hachtel Werkzeugbau GmbH und Co.KG, Aalen (Germany)

2015-07-01

Lightweight structures and modern methods of generating samples require in most cases non-destructive-testing to verify their state. They often must not be destroyed for initial testing as they are unique and irreplaceable. So computed tomography serves well as the sample is not being touched or manipulated for the analysis. Meanwhile in-situ testing of stable stress situations, for example pressure and tension is available and gives insight where only the measured data were before. This allows the identification of seeds for failure. The production process can be recorded also within the sample and not only its surface. We demonstrate detectable defects in carbon reinforced plastic parts, laser sintered metal parts and an example for optimizing the process of printing a plastic part for function.

Check of hybrid structures and lightweight construction materials. Usage of 3D-CT

International Nuclear Information System (INIS)

Szepanski, Kamil David

2015-01-01

Lightweight structures and modern methods of generating samples require in most cases non-destructive-testing to verify their state. They often must not be destroyed for initial testing as they are unique and irreplaceable. So computed tomography serves well as the sample is not being touched or manipulated for the analysis. Meanwhile in-situ testing of stable stress situations, for example pressure and tension is available and gives insight where only the measured data were before. This allows the identification of seeds for failure. The production process can be recorded also within the sample and not only its surface. We demonstrate detectable defects in carbon reinforced plastic parts, laser sintered metal parts and an example for optimizing the process of printing a plastic part for function.

Exploring Polymer-Modified Concrete and Cementitious Coating with High-Durability for Roadside Structures in Xinjiang, China

Directory of Open Access Journals (Sweden)

Yinchuan Guo

2017-01-01

Full Text Available The concrete roadside structures in Xinjiang, China, such as roadside barriers, bridge rails, and drainage holes, are severely damaged by the coupled effect of seasonal freeze-thaw cycles and deicer salts. To solve the corrosion problems of roadside structures, polymer-modified concrete was recommended for the future construction of roadside structures and polymer-modified cementitious coating was suggested for the protection of the current corroded ones. In this study, air-entraining agent and carboxylated styrene-butadiene latex were added for concrete modification and the corresponding performance tests were conducted. In addition, the performances of six types of readily available coating materials, including the acrylic latex modified cementitious coating designed in this study, were tested in freeze-thaw condition with the presence of chloride ions. The results show that 0.013% of the air-entraining agent and 10% of the carboxylated styrene-butadiene latex were appropriate dosage rates for the modification of Portland cement concrete, in terms of the improvement of the freeze-thaw resistance, compressive strength, and chloride impermeability. For the protection of the current corroded roadside structures, the acrylic-modified cementitious coating material demonstrated a good performance and the field monitoring confirmed that the coating is suitable for the protection of the roadside structures in Xinjiang.

An experimental study of mechanical behavior of natural fiber reinforced polymer matrix composites

Science.gov (United States)

Ratna, Sanatan; Misra, Sheelam

2018-05-01

Fibre-reinforced polymer composites have played a dominant role for a long time in a variety of applications for their high specific strength and modulus. The fibre which serves as a reinforcement in reinforced plastics may be synthetic or natural. Past studies show that only synthetic fibres such as glass, carbon etc., have been used in fibre reinforced plastics. Although glass and other synthetic fibre-reinforced plastics possess high specific strength, their fields of application are very limited because of their inherent higher cost of production. In this connection, an investigation has been carried out to make use of horse hair, an animal fibre abundantly available in India. Animal fibres are not only strong and lightweight but also relatively very cheaper than mineral fibre. The present work describes the development and characterization of a new set of animal fiber based polymer composites consisting of horse hair as reinforcement and epoxy resin. The newly developed composites are characterized with respect to their mechanical characteristics. Experiments are carried out to study the effect of fibre length on mechanical behavior of these epoxy based polymer composites. Composite made form horse hair can be used as a potential reinforcing material for many structural and non-structural applications. This work can be further extended to study other aspects of such composites like effect of fiber content, loading pattern, fibre treatment on mechanical behavior of horse hair based polymer horse hair.

Glass science tutorial: Lecture No. 8, introduction cementitious systems for Low-Level Waste immobilization

International Nuclear Information System (INIS)

Young, J.F.; Kirkpatrick, R.J.; Mason, T.O.; Brough, A.

1995-07-01

This report presents details about cementitious systems for low-level waste immobilization. Topics discussed include: composition and properties of portland cement; hydration properties; microstructure of concrete; pozzolans; slags; zeolites; transport properties; and geological aspects of long-term durability of concrete

Glass science tutorial: Lecture No. 8, introduction cementitious systems for Low-Level Waste immobilization

Energy Technology Data Exchange (ETDEWEB)

Young, J.F.; Kirkpatrick, R.J.; Mason, T.O.; Brough, A.

1995-07-01

This report presents details about cementitious systems for low-level waste immobilization. Topics discussed include: composition and properties of portland cement; hydration properties; microstructure of concrete; pozzolans; slags; zeolites; transport properties; and geological aspects of long-term durability of concrete.

Infinte Periodic Structure of Lightweight Elements

DEFF Research Database (Denmark)

Domadiya, Parthkumar Gandalal; Andersen, Lars Vabbersgaard; Sorokin, Sergey

2013-01-01

Lightweight wooden structures have become more popular as a sustainable, environmental- friendly and cost-effective alternative to concrete, steel and masonry buildings. However, there are certain drawbacks regarding noise and vibration due to the smaller weight and stiffness of wooden buildings....... Furthermore, lightweight building elements are typically periodic structures that behave as filters for sound propagation within certain frequency ranges (stop bands), thus only allowing transmission within the pass bands. Hence, traditional methods based on statistical energy analysis cannot be used...... for proper dynamic assessment of lightweight buildings. Instead, this paper discusses and compares the use of finite element analysis and a wave approach based on Floquet theory. The present analysis has focus on the effect of periodicity on vibration transmission within semi-infinite beam structures. Two...

Degradation processes of reinforced concretes by combined sulfate–phosphate attack

Energy Technology Data Exchange (ETDEWEB)

Secco, Michele, E-mail: michele.secco@unipd.it [Inter-Departmental Research Center for the Study of Cement Materials and Hydraulic Binders (CIRCe), University of Padova, Via Gradenigo 6, 35131 Padova (Italy); Department of Civil, Environmental and Architectural Engineering (ICEA), University of Padova, Via Marzolo 9, 35131 Padova (Italy); Lampronti, Giulio Isacco, E-mail: gil21@cam.ac.uk [Department of Earth Sciences, University of Cambridge, Downing Street, CB2 3EQ Cambridge (United Kingdom); Schlegel, Moritz-Caspar, E-mail: moritz-caspar.schlegel@helmholtz-berlin.de [BAM Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205 Berlin (Germany); Helmholtz-Zentrum Berlin fürMaterialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Maritan, Lara, E-mail: lara.maritan@unipd.it [Department of Geosciences, University of Padova, Via Gradenigo 6, 35131 Padova (Italy); Zorzi, Federico, E-mail: federico.zorzi@unipd.it [Department of Geosciences, University of Padova, Via Gradenigo 6, 35131 Padova (Italy)

2015-02-15

A novel form of alteration due to the interaction between hydrated cement phases and sulfate and phosphate-based pollutants is described, through the characterization of concrete samples from an industrial reinforced concrete building. Decalcification of the cement matrices was observed, with secondary sulfate and phosphate-based mineral formation, according to a marked mineralogical and textural zoning. Five alteration layers may be detected: the two outermost layers are characterized by the presence of gypsum–brushite solid solution phases associated with anhydrous calcium sulfates and phosphates, respectively, while a progressive increase in apatite and ammonium magnesium phosphates is observable in the three innermost layers, associated with specific apatite precursors (brushite, octacalcium phosphate and amorphous calcium phosphate, respectively). The heterogeneous microstructural development of secondary phases is related to the chemical, pH and thermal gradients in the attacked cementitious systems, caused by different sources of pollutants and the exposure to the sun's radiation.

Degradation processes of reinforced concretes by combined sulfate–phosphate attack

International Nuclear Information System (INIS)

Secco, Michele; Lampronti, Giulio Isacco; Schlegel, Moritz-Caspar; Maritan, Lara; Zorzi, Federico

2015-01-01

A novel form of alteration due to the interaction between hydrated cement phases and sulfate and phosphate-based pollutants is described, through the characterization of concrete samples from an industrial reinforced concrete building. Decalcification of the cement matrices was observed, with secondary sulfate and phosphate-based mineral formation, according to a marked mineralogical and textural zoning. Five alteration layers may be detected: the two outermost layers are characterized by the presence of gypsum–brushite solid solution phases associated with anhydrous calcium sulfates and phosphates, respectively, while a progressive increase in apatite and ammonium magnesium phosphates is observable in the three innermost layers, associated with specific apatite precursors (brushite, octacalcium phosphate and amorphous calcium phosphate, respectively). The heterogeneous microstructural development of secondary phases is related to the chemical, pH and thermal gradients in the attacked cementitious systems, caused by different sources of pollutants and the exposure to the sun's radiation

Metallic Glasses as Potential Reinforcements in Al and Mg Matrices: A Review

Directory of Open Access Journals (Sweden)

S. Jayalakshmi

2018-04-01

Full Text Available Development of metal matrix composites (MMCs with metallic glass/amorphous alloy reinforcements is an emerging research field. As reinforcements, metallic glasses with their high strength (up to ~2 GPa and high elastic strain limit (~2% can provide superior mechanical properties. Being metallic in nature, the glassy alloys can ensure better interfacial properties when compared to conventional ceramic reinforcements. Given the metastable nature of metallic glasses, lightweight materials such as aluminum (Al and magnesium (Mg with relatively lower melting points are suitable matrix materials. Synthesis of these advanced composites is a challenge as selection of processing method and appropriate reinforcement type (which does not allow devitrification of the metallic glass during processing is important. Non-conventional techniques such as high frequency induction sintering, bidirectional microwave sintering, friction stir processing, accumulative roll-bonding, and spark plasma sintering are being explored to produce these novel materials. In this paper, an overview on the synthesis and properties of aluminum and magnesium based composites with glassy reinforcement produced by various unconventional methods is presented. Evaluation of properties of the produced composites indicate: (i retention of amorphous state of the reinforcement after processing; (ii significant improvement in hardness and strength; (iii improvement/retention of ductility; and (iv high wear resistance and low coefficient of friction. Further, a comparative understanding of the properties highlights that the selection of the processing method is important in producing high performance composites.

A Brief Research Review for Improvement Methods the Wettability between Ceramic Reinforcement Particulate and Aluminium Matrix Composites

Science.gov (United States)

Razzaq, Alaa Mohammed; Majid, Dayang Laila Abang Abdul; Ishak, M. R.; B, Uday M.

2017-05-01

The development of new methods for addition fine ceramic powders to Al aluminium alloy melts, which would lead to more uniform distribution and effective incorporation of the reinforcement particles into the aluminium matrix alloy. Recently the materials engineering research has moved to composite materials from monolithic, adapting to the global need for lightweight, low cost, quality, and high performance advanced materials. Among the different methods, stir casting is one of the simplest ways of making aluminium matrix composites. However, it suffers from poor distribution and combination of the reinforcement ceramic particles in the metal matrix. These problems become significantly effect to reduce reinforcement size, more agglomeration and tendency with less wettability for the ceramic particles in the melt process. Many researchers have carried out different studies on the wettability between the metal matrix and dispersion phase, which includes added wettability agents, fluxes, preheating the reinforcement particles, coating the reinforcement particles, and use composting techniques. The enhancement of wettability of ceramic particles by the molten matrix alloy and the reinforcement particles distribution improvement in the solidified matrix is the main objective for many studies that will be discussed in this paper.

THERMALLY CONDUCTIVE CEMENTITIOUS GROUTS FOR GEOTHERMAL HEAT PUMPS. PROGRESS REPORT BY 1998

Energy Technology Data Exchange (ETDEWEB)

ALLAN,M.L.; PHILIPPACOPOULOS,A.J.

1998-11-01

Research commenced in FY 97 to determine the suitability of superplasticized cement-sand grouts for backfilling vertical boreholes used with geothermal heat pump (GHP) systems. The overall objectives were to develop, evaluate and demonstrate cementitious grouts that could reduce the required bore length and improve the performance of GHPs. This report summarizes the accomplishments in FY 98.

An applied investigation of kenaf-based fiber/polymer composites as potential lightweight materials for automotive components

Science.gov (United States)

Du, Yicheng

Natural fibers have the potential to replace glass fibers in fiber-reinforced composite applications. However, the natural fibers' intrinsic properties cause these issues: (1) the mechanical property variation; (2) moisture uptake by natural fibers and their composites; (3) lack of sound, cost-effective, environment-friendly fiber-matrix compounding processes; (4) incompatibility between natural fibers and polymer matrices; and (5) low heat-resistance of natural fibers and their composites. This dissertation systematically studied the use of kenaf bast fiber bundles, obtained via a mechanical retting method, as a light-weight reinforcement material for fiber-reinforced thermoset polymer composites for automotive applications. Kenaf bast fiber bundle tensile properties were tested, and the effects of locations in the kenaf plant, loading rates, retting methods, and high temperature treatments and their durations on kenaf bast fiber bundle tensile properties were evaluated. A process has been developed for fabricating high fiber loading kenaf bast fiber bundle-reinforced unsaturated polyester composites. The generated composites possessed high elastic moduli and their tensile strengths were close to specification requirements for glass fiber-reinforced sheet molding compounds. Effects of fiber loadings and lengths on resultant composite's tensile properties were evaluated. Fiber loadings were very important for composite tensile modulus. Both fiber loadings and fiber lengths were important for composite tensile strengths. The distributions of composite tensile, flexural and impact strengths were analyzed. The 2-parameter Weibull model was found to be the most appropriate for describing the composite strength distributions and provided the most conservative design values. Kenaf-reinforced unsaturated polyester composites were also proved to be more cost-effective than glass fiber-reinforced SMCs at high fiber loadings. Kenaf bast fiber bundle-reinforced composite

Thermally sprayed prepregs for thixoforging of UD fiber reinforced light metal MMCs

Science.gov (United States)

Silber, Martin; Wenzelburger, Martin; Gadow, Rainer

2007-04-01

Low density and good mechanical properties are the basic requirements for lightweight structures in automotive and aerospace applications. With their high specific strength and strain to failure values, aluminum alloys could be used for such applications. Only the insufficient stiffness and thermal and fatigue strength prevented their usage in high-end applications. One possibility to solve this problem is to reinforce the light metal with unidirectional fibers. The UD fiber allows tailoring of the reinforcement to meet the direction of the component's load. In this study, the production of thermally sprayed prepregs for the manufacturing of continuous fiber reinforced MMC by thixoforging is analysed. The main aim is to optimize the winding procedure, which determines the fiber strand position and tension during the coating process. A method to wind and to coat the continuous fibers with an easy-to-use handling technique for the whole manufacturing process is presented. The prepregs were manufactured by producing arc wire sprayed AlSi6 coatings on fibers bundles. First results of bending experiments showed appropriate mechanical properties.

Experimental Study on Fatigue Performance of Foamed Lightweight Soil

Science.gov (United States)

Qiu, Youqiang; Yang, Ping; Li, Yongliang; Zhang, Liujun

2017-12-01

In order to study fatigue performance of foamed lightweight soil and forecast its fatigue life in the supporting project, on the base of preliminary tests, beam fatigue tests on foamed lightweight soil is conducted by using UTM-100 test system. Based on Weibull distribution and lognormal distribution, using the mathematical statistics method, fatigue equations of foamed lightweight soil are obtained. At the same time, according to the traffic load on real road surface of the supporting project, fatigue life of formed lightweight soil is analyzed and compared with the cumulative equivalent axle loads during the design period of the pavement. The results show that even the fatigue life of foamed lightweight soil has discrete property, the linear relationship between logarithmic fatigue life and stress ratio still performs well. Especially, the fatigue life of Weibull distribution is more close to that derived from the lognormal distribution, in the instance of 50% guarantee ratio. In addition, the results demonstrated that foamed lightweight soil as subgrade filler has good anti-fatigue performance, which can be further adopted by other projects in the similar research domain.

Lightweight, Thermally Insulating Structural Panels

Science.gov (United States)

Eisen, Howard J.; Hickey, Gregory; Wen, Liang-Chi; Layman, William E.; Rainen, Richard A.; Birur, Gajanana C.

1996-01-01

Lightweight, thermally insulating panels that also serve as structural members developed. Honeycomb-core panel filled with low-thermal-conductivity, opacified silica aerogel preventing convection and minimizes internal radiation. Copper coating on face sheets reduces radiation. Overall thermal conductivities of panels smaller than state-of-art commercial non-structurally-supporting foam and fibrous insulations. On Earth, panels suitable for use in low-air-pressure environments in which lightweight, compact, structurally supporting insulation needed; for example, aboard high-altitude aircraft or in partially evacuated panels in refrigerators.

Behaviour of hybrid fibre reinforced concrete beam–column joints under reverse cyclic loads

International Nuclear Information System (INIS)

Ganesan, N.; Indira, P.V.; Sabeena, M.V.

2014-01-01

Highlights: • Developed a high performance hybrid fibre reinforced cementitious composite. • Exterior beam-column joints have been tested under reversed cyclic loading. • Ductility factor, energy dissipation and stiffness degradation have been evaluated. • Contribution to reduce congestion of reinforcement in beam column joints. - Abstract: An experimental investigation was carried out to study the effect of hybrid fibres on the strength and behaviour of High performance concrete beam column joints subjected to reverse cyclic loads. A total of 12 reinforced concrete beams column joints were cast and tested in the present investigation. High performance concrete of M60 grade was designed using the modified ACI method suggested by Aïtcin. Crimped steel fibres and polypropylene fibres were used in hybrid form. The main variables considered were the volume fraction of (i) crimped steel fibres viz. 0.5% (39.25 kg/m 3 ) and 1.0% (78.5 kg/m 3 ) and (ii) polypropylene fibres viz. 0.1% (0.9 kg/m 3 ), 0.15% (1.35 kg/m 3 ), and 0.2% (1.8 kg/m 3 ). Addition of fibres in hybrid form improved many of the engineering properties such as the first crack load, ultimate load and ductility factor of the composite. The combination of 1% (78.5 kg/m 3 ) volume fraction of steel fibres and 0.15% (1.35 kg/m 3 ) volume fraction of polypropylene fibres gave better performance with respect to energy dissipation capacity and stiffness degradation than the other combinations

Significance of Shrinkage Induced Clamping Pressure in Fiber-Matrix Bonding in Cementitious Composite Materials

DEFF Research Database (Denmark)

Stang, Henrik

1996-01-01

used in high performance cementitious composite materials.Assuming a Coulomb type of friction on the fiber/matrix interface andusing typical values for the frictional coefficient it is shownthat the shrinkage induced clamping pressure could be one of the mostimportant factors determining the frictional...

Lightweight Cryptography for Passive RFID Tags

DEFF Research Database (Denmark)

David, Mathieu

2012-01-01

were mostly unsatisfactory. As a conclusion, a new branch of cryptography, commonly called Lightweight Cryptography, emerged to address the issues of these tiny ubiquitous devices. This Thesis presents a comprehensive engineering to lightweight cryptography, proposes a classification and explores its...... various ramifications by giving key examples in each of them. We select two of these branches, ultralightweight cryptography and symmetric-key cryptography, and propose a cryptographic primitive in each of them. In the case of symmetric-key cryptography, we propose a stream cipher that has a footprint...... of an integrator for a particular application. Finally, we conclude that the research for finding robust cryptographic primitive in the branch of lightweight cryptography still has some nice days ahead, and that providing a secure cryptosystem for printed electronics RFID tags remains an open research topic....

Carbonated miscanthus mineralized aggregates for reducing environmental impact of lightweight concrete blocks

Directory of Open Access Journals (Sweden)

Courard Luc

2017-01-01

Full Text Available At a time when the cement industry is largely responsible for the production of CO2 in the construction sector, it is useful to make this production a reverse phenomenon: that is CO2 capture. The CO2 absorption process called carbonation, improves specific properties of the concrete during the conversion of carbon dioxide CO2 into calcium carbonate CaCO3. Current environmental concerns motivate the study of carbonation in order to maximize the absorption of carbon dioxide. Moreover, lightweight concrete with bio-based products knows an interesting development in the construction field, especially as thermal insulation panels for walls in buildings. Before identifying and quantifying the basic physical characteristics of concrete made from miscanthus, it is necessary to optimize the composition of the product. The long-term stability as well as the reinforcement may be obtained by means of a mineralization process of the natural product: a preparation with a lime and/or cement-based material is necessary to reinforce the cohesion of the bio-based product. Mineralization process is described as well as the way of producing blocks for CO2 capture by means of accelerated carbonation. Finally, concrete blocks produced with miscanthus mineralized aggregates offer interesting mechanical properties and minimal environmental impact.

FY2015 Lightweight Materials R&D Annual Progress Report

Energy Technology Data Exchange (ETDEWEB)

None, None

2016-09-30

The Lightweight Materials research and development (R&D) area within the DOE Vehicle Technologies Office (VTO) provides support and guidance for many cutting-edge automotive technologies under development. Research focuses on addressing critical barriers to commercializing lightweight materials for passenger and commercial vehicles. This report describes the progress made on the research and development projects funded by the Lightweight Materials area.

Micro-structural characterization of the hydration products of bauxite-calcination-method red mud-coal gangue based cementitious materials

International Nuclear Information System (INIS)

Liu, Xiaoming; Zhang, Na; Yao, Yuan; Sun, Henghu; Feng, Huan

2013-01-01

Highlights: • Al IV and Al VI both exist in the hydration products. • Increase of Ca/Si ratio promotes the conversion from [AlO 4 ] to [AlO 6 ]. • Polymerization degree of [SiO 4 ] in the hydration products declines. -- Abstract: In this research, the micro-structural characterization of the hydration products of red mud-coal gangue based cementitious materials has been investigated through SEM-EDS, 27 Al MAS NMR and 29 Si MAS NMR techniques, in which the used red mud was derived from the bauxite calcination method. The results show that the red mud-coal gangue based cementitious materials mainly form fibrous C-A-S-H gel, needle-shaped/rod-like AFt in the early hydration period. With increasing of the hydration period, densification of the pastes were promoted resulting in the development of strength. EDS analysis shows that with the Ca/Si of red mud-coal gangue based cementitious materials increases, the average Ca/Si and Ca/(Si + Al) atomic ratio of C-A-S-H gel increases, while the average Al/Si atomic ratio of C-A-S-H gel decreases. MAS NMR analysis reveals that Al in the hydration products of red mud-coal gangue based cementitious materials exists in the forms of Al IV and Al VI , but mainly in the form of Al VI . Increasing the Ca/Si ratio of raw material promotes the conversion of [AlO 4 ] to [AlO 6 ] and inhibits the combination between [AlO 4 ] and [SiO 4 ] to form C-A-S-H gel. Meanwhile, the polymerization degree of [SiO 4 ] in the hydration products declines

Deflection Prediction of No-Fines Lightweight Concrete Wall Using Neural Network Caused Dynamic Loads

Directory of Open Access Journals (Sweden)

Ridho Bayuaji

2018-04-01

Full Text Available No-fines lightweight concrete wall with horizontal reinforcement refers to an alternative material for wall construction with an aim of improving the wall quality towards horizontal loads. This study is focused on artificial neural network (ANN application to predicting the deflection deformation caused by dynamic loads. The ANN method is able to capture the complex interactions among input/output variables in a system without any knowledge of interaction nature and without any explicit assumption to model form. This paper explains the existing data research, data selection and process of ANN modelling training process and validation. The results of this research show that the deformation can be predicted more accurately, simply and quickly due to the alternating horizontal loads.

Vehicle Lightweighting: Mass Reduction Spectrum Analysis and Process Cost Modeling

Energy Technology Data Exchange (ETDEWEB)

Mascarin, Anthony [IBIS Associates, Inc., Waltham, MA (United States); Hannibal, Ted [IBIS Associates, Inc., Waltham, MA (United States); Raghunathan, Anand [Energetics Inc., Columbia, MD (United States); Ivanic, Ziga [Energetics Inc., Columbia, MD (United States); Clark, Michael [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2016-03-01

The U.S. Department of Energy’s Vehicle Technologies Office, Materials area commissioned a study to model and assess manufacturing economics of alternative design and production strategies for a series of lightweight vehicle concepts. In the first two phases of this effort examined combinations of strategies aimed at achieving strategic targets of 40% and a 45% mass reduction relative to a standard North American midsize passenger sedan at an effective cost of $3.42 per pound (lb) saved. These results have been reported in the Idaho National Laboratory report INL/EXT-14-33863 entitled Vehicle Lightweighting: 40% and 45% Weight Savings Analysis: Technical Cost Modeling for Vehicle Lightweighting published in March 2015. The data for these strategies were drawn from many sources, including Lotus Engineering Limited and FEV, Inc. lightweighting studies, U.S. Department of Energy-funded Vehma International of America, Inc./Ford Motor Company Multi-Material Lightweight Prototype Vehicle Demonstration Project, the Aluminum Association Transportation Group, many United States Council for Automotive Research’s/United States Automotive Materials Partnership LLC lightweight materials programs, and IBIS Associates, Inc.’s decades of experience in automotive lightweighting and materials substitution analyses.

Vehicle Lightweighting: Mass Reduction Spectrum Analysis and Process Cost Modeling

International Nuclear Information System (INIS)

Mascarin, Anthony; Hannibal, Ted; Raghunathan, Anand; Ivanic, Ziga; Clark, Michael

2016-01-01

The U.S. Department of Energy's Vehicle Technologies Office, Materials area commissioned a study to model and assess manufacturing economics of alternative design and production strategies for a series of lightweight vehicle concepts. In the first two phases of this effort examined combinations of strategies aimed at achieving strategic targets of 40% and a 45% mass reduction relative to a standard North American midsize passenger sedan at an effective cost of $3.42 per pound (lb) saved. These results have been reported in the Idaho National Laboratory report INL/EXT-14-33863 entitled Vehicle Lightweighting: 40% and 45% Weight Savings Analysis: Technical Cost Modeling for Vehicle Lightweighting published in March 2015. The data for these strategies were drawn from many sources, including Lotus Engineering Limited and FEV, Inc. lightweighting studies, U.S. Department of Energy-funded Vehma International of America, Inc./Ford Motor Company Multi-Material Lightweight Prototype Vehicle Demonstration Project, the Aluminum Association Transportation Group, many United States Council for Automotive Research's/United States Automotive Materials Partnership LLC lightweight materials programs, and IBIS Associates, Inc.'s decades of experience in automotive lightweighting and materials substitution analyses.

Flexural Behaviour Of Reinforced Concrete Beams Containing Expanded Glass As Lightweight Aggregates

Directory of Open Access Journals (Sweden)

Khatib Jamal

2015-12-01

Full Text Available The flexural properties of reinforced concrete beams containing expanded glass as a partial fine aggregate (sand replacement are investigated. Four concrete mixes were employed to conduct this study. The fine aggregate was replaced with 0%, 25%, 50% and 100% (by volume expanded glass. The results suggest that the incorporation of 50% expanded glass increased the workability of the concrete. The compressive strength was decreasing linearly with the increasing amount of expanded glass. The ductility of the concrete beam significantly improved with the incorporation of the expanded glass. However, the load-carrying capacity of the beam and load at which the first crack occurs was reduced. It was concluded that the inclusion of expanded glass in structural concrete applications is feasible.

Secondary Waste Cementitious Waste Form Data Package for the Integrated Disposal Facility Performance Assessment

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Westsik, Joseph H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Serne, R Jeffrey [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Um, Wooyong [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Cozzi, Alex D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2016-05-16

A review of the most up-to-date and relevant data currently available was conducted to develop a set of recommended values for use in the Integrated Disposal Facility (IDF) performance assessment (PA) to model contaminant release from a cementitious waste form for aqueous wastes treated at the Hanford Effluent Treatment Facility (ETF). This data package relies primarily upon recent data collected on Cast Stone formulations fabricated with simulants of low-activity waste (LAW) and liquid secondary wastes expected to be produced at Hanford. These data were supplemented, when necessary, with data developed for saltstone (a similar grout waste form used at the Savannah River Site). Work is currently underway to collect data on cementitious waste forms that are similar to Cast Stone and saltstone but are tailored to the characteristics of ETF-treated liquid secondary wastes. Recommended values for key parameters to conduct PA modeling of contaminant release from ETF-treated liquid waste are provided.

The measurement and estimation method of the sorption of lead onto cementitious materials

International Nuclear Information System (INIS)

Nakanishi, Kiyoshi; Tsukamoto, Masaki; Fujita, Tomonari; Sugiyama, Daisuke

2002-01-01

Cementitious material is a potential waste packaging material for radioactive waste disposal, and is expected to provide chemical containment. In particular, the sorption of radionuclides onto cementitious material is a very important parameter when considering the release of radionuclides from radioactive waste. In this study, sorption of lead, onto hydrated Ordinary Portland Cement (OPC), OPC/Blast Furnace Slag blended cement (BFS), Highly containing Flyash and Silica Fume Cement (HFSC) and cement constituent minerals (portlandite, ettringite, hydrotalcite and C-S-H gels (Ca/Si = 0.9 and 1.65)) was measured using the batch sorption technique. Lead is one of the important nuclides for safety assessment. The obtained distribution ratios, Rd values, for sorption of lead onto hydrated (freshly cured) OPC and HFSC are very high:>1000 cm3g-1. The distribution ratio for sorption of lead onto OPC/BFS could not be determined quantitatively due to the precipitation of PbS. Comparing the Rd values onto cements and minerals, it was suggested the sorption onto C-S-H gel phases dominate the sorption for lead onto hydrated cements. Once a cementitious material is altered in the disposal environment, its sorption ability may be affected. The sorption of lead onto degraded OPC and degraded HFSC, which were altered in the presence of distilled water, was also measured. It was observed that the alteration did not cause changes that decreased the sorption of lead onto OPC and HFSC. An approach, in which it is assumed that each of the component phases contributes to the composite material, is proposed and discussed to describe the sorption of lead onto cement using a knowledge of the phase components in a linear additive manner. The results showed reasonably good agreement between the predicted and measured Rd values for lead onto freshly cured and altered cements. (author)

Development of low alkaline cementitious grouting materials for a deep geological repository

International Nuclear Information System (INIS)

Suzuki, Kenichiro; Miura, Norihiko; Iriya, Keishiro; Kobayashi, Yasushi

2012-01-01

In order to reduce uncertainties of long-term safety assessment for a High Level radioactive Waste (HLW) repository system, low alkaline cementitious grouting materials have been studied. The pH of the leachate from the grouting material is targeted to be below 11.0, since the degradation of the bentonite buffer and host rock is limited. The current work focused on the effects of pozzolanic reactions to reduce pH and the development of low alkaline cementitious injection materials in which super-micro ordinary Portland cement (SOPC) was partially replaced by silica fume (SF), micro silica (MS) and fly ash (FA). As it is important to realize how the grouting material will respond to a high injection pressure into the fracture, and in order to understand the penetrability of different low alkaline cement mixes and to observe their flow behavior through the fracture, injection tests were conducted by using a simulated model fracture of 2 m diameter made from parallel plates of acrylic acid resin and stainless steel. Experimental results of the basic properties for selecting suitable materials and that of injecting into a simulated fracture to assess the grouting performance are described

Recycling polyethylene terephthalate wastes as short fibers in Strain-Hardening Cementitious Composites (SHCC).

Science.gov (United States)

Lin, Xiuyi; Yu, Jing; Li, Hedong; Lam, Jeffery Y K; Shih, Kaimin; Sham, Ivan M L; Leung, Christopher K Y

2018-05-26

As an important portion of the total plastic waste bulk but lack of reuse and recycling, the enormous amounts of polyethylene terephthalate (PET) solid wastes have led to serious environmental issues. This study explores the feasibility of recycling PET solid wastes as short fibers in Strain-Hardening Cementitious Composites (SHCCs), which exhibit strain-hardening and multiple cracking under tension, and therefore have clear advantages over conventional concrete for many construction applications. Based on micromechanical modeling, fiber dispersion and alkali resistance, the size of recycled PET fibers was first determined. Then the hydrophobic PET surface was treated with NaOH solution followed by a silane coupling agent to achieve the dual purpose of improving the fiber/matrix interfacial frictional bond (from 0.64 MPa to 0.80 MPa) and enhancing the alkali resistance for applications in alkaline cementitious environment. With surface treatment, recycling PET wastes as fibers in SHCCs is a promising approach to significantly reduce the material cost of SHCCs while disposing hazardous PET wastes in construction industry. Copyright © 2018 Elsevier B.V. All rights reserved.

Olive pomace based lightweight concrete, an experimental approach and contribution

Directory of Open Access Journals (Sweden)

Lynda Amel Chaabane

2018-01-01

Full Text Available Due to conventional aggregates resources depletion, material recycling has become an economic and ecologic alternative. In this paper, locally available natural residues such as olive pomace were investigated, when partially incorporated in the concrete formulation, since the mechanical characteristics of lightweight aggregate concrete strongly depend on its properties and proportions. Lightweight aggregates are more deformable than the cement matrix because of their high porosity, and their influence on the concrete strength remains complex. The purpose of this paper is to investigate the aggregates properties on lightweight concrete mechanical behaviour through an experimental approach. In addition, the different substitution sequences and the W/C ratio on lightweight concrete behaviour were evaluated, in order to determine the W/C ratio influence on the improvement of the lightweight concrete mechanical properties while knowing that the mixing water quantity gives the cement paste manoeuvrability and mechanical strength effects. The last part of this paper, therefore, was to provide statistical survey for estimating strength and weight reduction through the different natural aggregate substitutions to improve the lightweight concrete properties. The results achieved in a significant olive-pomace lower adhesion with the matrix after the cement setting, making the lightweight concrete mechanical strength weak. However, this work can open several perspectives: Results modeling and correlation with an experimental approach, the evolution and determination of lightweight concrete characteristics when exposed to high temperatures and thermohydric properties.

Effects of Low Volume Fraction of Polyvinyl Alcohol Fibers on the Mechanical Properties of Oil Palm Shell Lightweight Concrete

Directory of Open Access Journals (Sweden)

Ming Kun Yew

2015-01-01

Full Text Available This paper presents the effects of low volume fraction (Vf of polyvinyl alcohol (PVA fibers on the mechanical properties of oil palm shell (OPS high strength lightweight concrete mixtures. The slump, density, compressive strength, splitting tensile strength, flexural strength, and modulus of elasticity under various curing conditions have been measured and evaluated. The results indicate that an increase in PVA fibers decreases the workability of the concrete and decreases the density slightly. The 28-day compressive strength of oil palm shell fiber-reinforced concrete (OPSFRC high strength lightweight concrete (HSLWC subject to continuous moist curing was within the range of 43–49 MPa. The average modulus of elasticity (E value is found to be 16.1 GPa for all mixes, which is higher than that reported in previous studies and is within the range of normal weight concrete. Hence, the findings of this study revealed that the PVA fibers can be used as an alternative material to enhance the properties of OPS HSLWC for building and construction applications.

3D morphological and micromechanical modeling of cementitious materials

International Nuclear Information System (INIS)

Escoda, Julie

2012-01-01

The goal of this thesis is to develop morphological models of cementitious materials and use these models to study their local and effective response. To this aim, 3D images of cementitious materials (mortar and concrete), obtained by micro-tomography, are studied. First, the mortar image is segmented in order to obtain an image of a real microstructure, to be used for linear elasticity computations. The image of concrete is used, after being processed, to determine various morphological characteristics of the material. A random model of concrete is then developed and validated by means of morphological data. This model is made up of three phases, corresponding to the matrix, aggregates and voids. The aggregates phase is modelled by implantation of Poisson polyhedra without overlap. For this purpose, an algorithm suited to the vector generation of Poisson polyhedra is introduced and validated with morphological measurements. Finally, the effective linear elastic properties of the mortar and other simulated microstructures are estimated with the FFT (Fast-Fourier Transform) method, for various contrasts between the aggregates and matrix' Young moduli. To complete this work, focused on effective properties, an analysis of the local elastic response in the matrix phase is undertaken, in order to determine the spatial arrangement between stress concentration zones in the matrix and the phases of the microstructure (aggregates and voids). Moreover, a statistical fields characterization, in the matrix, is achieved, including the determination of the Representative Volume Element (RVE) size. Furthermore, a comparison between effective and local elastic properties obtained from microstructures containing polyhedra and spheres is carried out. (author)

Assessing the Contribution of the CFRP Strip of Bearing the Applied Load Using Near-Surface Mounted Strengthening Technique with Innovative High-Strength Self-Compacting Cementitious Adhesive (IHSSC-CA

Directory of Open Access Journals (Sweden)

Alyaa Mohammed

2018-01-01

Full Text Available Efficient transfer of load between concrete substrate and fibre reinforced polymer (FRP by the bonding agent is the key factor in any FRP strengthening system. An innovative high-strength self-compacting non-polymer cementitious adhesive (IHSSC-CA was recently developed by the authors and has been used in a number of studies. Graphene oxide and cementitious materials are used to synthesise the new adhesive. The successful implementation of IHSSC-CA significantly increases carbon FRP (CFRP strip utilization and the load-bearing capacity of the near-surface mounted (NSM CFRP strengthening system. A number of tests were used to inspect the interfacial zone in the bonding area of NSM CFRP strips, including physical examination, pore structure analysis, and three-dimensional laser profilometery analysis. It was deduced from the physical inspection of NSM CFRP specimens made with IHSSC-CA that a smooth surface for load transfer was found in the CFRP strip without stress concentrations in some local regions. A smooth surface of the adhesive layer is very important for preventing localized brittle failure in the concrete. The pore structure analysis also confirmed that IHSSC-CA has better composite action between NSM CFRP strips and concrete substrate than other adhesives, resulting in the NSM CFRP specimens made with IHSSC-CA sustaining a greater load. Finally, the results of three-dimensional laser profilometery revealed a greater degree of roughness and less deformation on the surface of the CFRP strip when IHSSC-CA was used compared to other adhesives.

Enabling lightweight designs by a new laser based approach for joining aluminum to steel

Science.gov (United States)

Brockmann, Rüdiger; Kaufmann, Sebastian; Kirchhoff, Marc; Candel-Ruiz, Antonio; Müllerschön, Oliver; Havrilla, David

2015-03-01

As sustainability is an essential requirement, lightweight design becomes more and more important, especially for mobility. Reduced weight ensures more efficient vehicles and enables better environmental impact. Besides the design, new materials and material combinations are one major trend to achieve the required weight savings. The use of Carbon Fiber Reinforced Plastics (abbr. CFRP) is widely discussed, but so far high volume applications are rarely to be found. This is mainly due to the fact that parts made of CFRP are much more expensive than conventional parts. Furthermore, the proper technologies for high volume production are not yet ready. Another material with a large potential for lightweight design is aluminum. In comparison to CFRP, aluminum alloys are generally more affordable. As aluminum is a metallic material, production technologies for high volume standard cutting or joining applications are already developed. In addition, bending and deep-drawing can be applied. In automotive engineering, hybrid structures such as combining high-strength steels with lightweight aluminum alloys retain significant weight reduction but also have an advantage over monolithic aluminum - enhanced behavior in case of crash. Therefore, since the use of steel for applications requiring high mechanical properties is unavoidable, methods for joining aluminum with steel parts have to be further developed. Former studies showed that the use of a laser beam can be a possibility to join aluminum to steel parts. In this sense, the laser welding process represents a major challenge, since both materials have different thermal expansion coefficients and properties related to the behavior in corrosive media. Additionally, brittle intermetallic phases are formed during welding. A promising approach to welding aluminum to steel is based on the use of Laser Metal Deposition (abbr. LMD) with deposit materials in the form of powders. Within the present work, the advantages of this

Investigation on the Activity Activation and Cementitious Property of Coal Gangue with High Iron and Silica Contents

Science.gov (United States)

Wu, Hong; Li, Yu; Teng, Min; Yang, Yu

2017-11-01

The activity of coal gangue by thermal activation and composite activation technologies was investigated. The crystal composition, framework structure and morphology change were analyzed by XRD, FT-IR and SEM, respectively. The cementitious property of coal gangue was measured by strength test. The results showed that thermal activation decomposed kaolinite in coal gangue, and formed the metastable structure with a porous state, multiple internal broken bonds and large specific surface areas. Based on thermal activation, the added lime provided the alkaline environment, then this reduced the bond energy of reactant particles and the degree of crystallinity of quartz in coal gangue. The two activation methods could effectively improve the cementitious property of coal gangue based unburned bricks, and that the composite activation technology was superior performance.

Heavy ion beam measurement of the hydration of cementitious materials

International Nuclear Information System (INIS)

Livingston, R.A.; Schweitzer, J.S.; Rolfs, C.; Becker, H.-W.; Kubsky, S.; Spillane, T.; Zickefoose, J.; Castellote, M.; Viedma, P.G. de; Cheung, J.

2010-01-01

The setting and development of strength of Portland cement concrete depends upon the reaction of water with various phases in the Portland cement. Nuclear resonance reaction analysis (NRRA) involving the 1 H( 15 N,α,γ) 12 C reaction has been applied to measure the hydrogen depth profile in the few 100 nm thick surface layer that controls the early stage of the reaction. Specific topics that have been investigated include the reactivity of individual cementitious phases and the effects of accelerators and retarders.

Micro-structural characterization of the hydration products of bauxite-calcination-method red mud-coal gangue based cementitious materials

Energy Technology Data Exchange (ETDEWEB)

Liu, Xiaoming [State Key Laboratory of Advanced Metallurgy, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Zhang, Na [Green Construction Materials and Circulation Economy Center, Architectural Design and Research Institute of Tsinghua University Co., Ltd., Beijing 100084 (China); Yao, Yuan, E-mail: yuanyaocas@163.com [School of Engineering and Computer Science, University of the Pacific, Stockton, CA 95211 (United States); Sun, Henghu; Feng, Huan [School of Engineering and Computer Science, University of the Pacific, Stockton, CA 95211 (United States)

2013-11-15

Highlights: • Al{sup IV} and Al{sup VI} both exist in the hydration products. • Increase of Ca/Si ratio promotes the conversion from [AlO{sub 4}] to [AlO{sub 6}]. • Polymerization degree of [SiO{sub 4}] in the hydration products declines. -- Abstract: In this research, the micro-structural characterization of the hydration products of red mud-coal gangue based cementitious materials has been investigated through SEM-EDS, {sup 27}Al MAS NMR and {sup 29}Si MAS NMR techniques, in which the used red mud was derived from the bauxite calcination method. The results show that the red mud-coal gangue based cementitious materials mainly form fibrous C-A-S-H gel, needle-shaped/rod-like AFt in the early hydration period. With increasing of the hydration period, densification of the pastes were promoted resulting in the development of strength. EDS analysis shows that with the Ca/Si of red mud-coal gangue based cementitious materials increases, the average Ca/Si and Ca/(Si + Al) atomic ratio of C-A-S-H gel increases, while the average Al/Si atomic ratio of C-A-S-H gel decreases. MAS NMR analysis reveals that Al in the hydration products of red mud-coal gangue based cementitious materials exists in the forms of Al{sup IV} and Al{sup VI}, but mainly in the form of Al{sup VI}. Increasing the Ca/Si ratio of raw material promotes the conversion of [AlO{sub 4}] to [AlO{sub 6}] and inhibits the combination between [AlO{sub 4}] and [SiO{sub 4}] to form C-A-S-H gel. Meanwhile, the polymerization degree of [SiO{sub 4}] in the hydration products declines.

Durability of reinforced concrete beams strengthened with fiber reinforced polymers under varying environmental conditions

International Nuclear Information System (INIS)

El-Sadani, R.A.M.G

2008-01-01

Fiber reinforced polymers (FRP) materials were adopted by the aerospace and marine industries, not only for their lightweight and high strength characteristics but also due to their tough and durable nature . As the engineering community has become more familiar with the performance advantages of these materials, new applications have been investigated and implemented. Researches and design guidelines concluded that externally bonded FRP to concrete elements could efficiently increase the capacity of RC elements. Long-term exposure to harsh environments deteriorates concrete and the need for repair and rehabilitation is evident. In order to accept these FRP materials, they must be evaluated for durability in harsh environments. An experimental program was conducted at the materials laboratory- faculty of engineering-Ain Shams university to study the durability of RC beams strengthened with FRP sheets and to compare them with un strengthened beams.The effect of gamma rays on FRP materials and concrete specimens bonded to FRP sheets were also investigated.

FRCM and FRP composites for the repair of damaged PC girders.

Science.gov (United States)

2015-01-01

Fabric-reinforced-cementitious-matrix (FRCM) and fiber-reinforced polymer (FRP) composites have : emerged as novel strengthening technologies. FRCM is a composite material consisting of a sequence of : one or more layers of cement-based matrix reinfo...

Testosterone and BMD in elite male lightweight rowers

DEFF Research Database (Denmark)

Vinther, A; Kanstrup, I-L; Christiansen, E

2008-01-01

The purpose of the present study was to investigate if a relationship between BMD and testosterone levels could be identified in elite male lightweight rowers. Thirteen male lightweight national team rowers had their BMD measured in a DEXA scanner. Plasma concentrations of total testosterone (TT)...

The Design of a Lightweight RFID Middleware

Directory of Open Access Journals (Sweden)

Fengqun Lin

2009-10-01

Full Text Available Radio Frequency Identification (RFID middleware is often regarded as the central nervous system of RFID systems. In this paper, a lightweight RFID middleware is designed and implemented without the need of an Application Level Events (ALE structure, and its implementation process is described using a typical commerical enterprise. A short review of the current RFID middleware research and development is also included. The characteristics of RFID middleware are presented with a two-centric framework. The senarios of RFID data integration based on the simplified structure are provided to illuminats the design and implementation of the lightweight middleware structure and its development process. The lightweight middleware is easy to maintain and extend because of the simplified and streamlined structure and the short development cycle.

Reinforced plastics and aerogels by nanocrystalline cellulose

Energy Technology Data Exchange (ETDEWEB)

Leung, Alfred C. W.; Lam, Edmond; Chong, Jonathan; Hrapovic, Sabahudin; Luong, John H. T., E-mail: john.luong@cnrc-nrc.gc.ca [National Research Council Canada (Canada)

2013-05-15

Nanocrystalline cellulose (NCC), a rigid rod-like nanoscale material, can be produced from cellulosic biomass in powder, liquid, or gel forms by acid and chemical hydrolysis. Owing to its unique and exceptional physicochemical properties, the incorporation of a small amount of NCC into plastic enhances the mechanical strength of the latter by several orders of magnitudes. Carbohydrate-based NCC poses no serious environmental concerns, providing further impetus for the development and applications of this green and renewable biomaterial to fabricate lightweight and biodegradable composites and aerogels. Surface functionalization of NCC remains the main focus of NCC research to tailor its properties for dispersion in hydrophilic or hydrophobic media. It is of uttermost importance to develop tools and protocols for imaging of NCC in a complex matrix and quantify its reinforcement effect.

Energy-momentum conserving higher-order time integration of nonlinear dynamics of finite elastic fiber-reinforced continua

Science.gov (United States)

Erler, Norbert; Groß, Michael

2015-05-01

Since many years the relevance of fibre-reinforced polymers is steadily increasing in fields of engineering, especially in aircraft and automotive industry. Due to the high strength in fibre direction, but the possibility of lightweight construction, these composites replace more and more traditional materials as metals. Fibre-reinforced polymers are often manufactured from glass or carbon fibres as attachment parts or from steel or nylon cord as force transmission parts. Attachment parts are mostly subjected to small strains, but force transmission parts usually suffer large deformations in at least one direction. Here, a geometrically nonlinear formulation is necessary. Typical examples are helicopter rotor blades, where the fibres have the function to stabilize the structure in order to counteract large centrifugal forces. For long-run analyses of rotor blade deformations, we have to apply numerically stable time integrators for anisotropic materials. This paper presents higher-order accurate and numerically stable time stepping schemes for nonlinear elastic fibre-reinforced continua with anisotropic stress behaviour.

Using mixture experiments to develop cementitious waste forms

International Nuclear Information System (INIS)

Spence, R.D.; Anderson, C.M.; Piepel, G.F.

1993-01-01

Mixture experiments are presented as a means to develop cementitious waste forms. The steps of a mixture experiment are (1) identifying the waste form ingredients; (2) determining the compositional constraints of these ingredients; (3) determining the extreme vertices, edge midpoints, and face centroids of the constrained multidimensional volume (these points along with some interior points represent the set of possible compositions for testing); (4) picking a subset of these points for the experimental design; (5) measuring the properties of the selected subset; and (6) generating the response surface models. The models provide a means for predicting the properties within the constrained region. This article presents an example of this process for one property: unconfined compressive strength

Argillite / cementitious materials interaction: in-situ investigations and modeling of engineered analogues from the Tournemire experimental station

International Nuclear Information System (INIS)

Techer, I.; Bartier, D.; Dauzeres, A.; Boulvais, P.

2012-01-01

Document available in extended abstract form only. Deep geological disposal of high-activity and long-period radioactive wastes is designed by the French National Agency for Radioactive Waste Management (Andra) with a confinement system based on the multiplication of argillaceous and cement-bearing barriers called 'engineered barriers'. The role of these barriers is to avoid the release of radioelements into the biosphere, as well as to prevent the potential addition of external fluids to the waste materials. In a deep clay-rich medium, cementitious materials will compose most of the building structures and will be emplaced at the immediate contact with the natural argillaceous formation. Cementitious materials are known to produce hyper-alkaline pore fluids (with pHs ranging between 10 and 13.5) during their aging. Their introduction in a deep clayey disposal is thus expected to induce a chemical disequilibrium which imprint on the safety assessment of the storage must be characterized. One way to evaluate the potential disturbing of a clayey formation at the contact to a cementitious material and thus towards the percolation of hyper-alkaline fluids consists with the investigation of natural analogues or engineered analogues. These systems deals with clayey formations that have been maintained over several years to hundred of years at the contact with a natural or engineered cementitious material. The Tournemire Experimental Platform of the French Institute for Radioprotection and Nuclear Safety (IRSN) (Aveyron, SE France) presents many contexts of so-defined engineered analogues. For instance, exploration boreholes that were drilled vertically from the tunnel basement into the Toarcian argillite in 1990/1991 were filled soon after their drilling with CEM II cement paste and concrete. Today, the over coring of such concreted boreholes gives opportunities to examine the cementitious and the clayey materials and to discuss potential changes of their intrinsic

Glass fiber -reinforced plastic tapered poles for transmission and distribution lines: development and experimental study

International Nuclear Information System (INIS)

Ibrahim, S.; Burachysnsky, V.; Polyzois, D.

1999-01-01

A research project to develop lightweight poles for use in power transmission and distribution lines and involving the use of glass fiber-reinforced plastic using the filament winding process is described. Twelve full scale specimen poles were designed, fabricated and subjected to cantilever bending to test failure modes. The test parameters included fiber orientation, ratio of longitudinal-to-circumferential fiber, and the number of layers. Results showed that local buckling was the most dominant failure mode, attributable to the high radius-to-thickness ratio of the specimen poles. Overall, however, these fiber-reinforced plastic poles compared favourably to wooden poles in carrying capacity with significant weight reduction. Lateral displacement at ultimate loads did not exceed the acceptable limit of 10 per cent of the specimen free length. 7 refs., 3 tabs., 2 figs

Lightweight landscape enhancing design through minimal mass structures

CERN Document Server

Spinelli, Luigi; Monticelli, Carol; Pedrali, Paolo

2016-01-01

This book explains how lightweight materials and structures can be deployed in buildings to meet high environmental and aesthetic standards and emphasizes how the concept of lightness in building technology and design dovetails with the desire to enhance landscape. The first part of the book, on lightweight construction, aims to foster the use of membranes within the specific climatic context and in particular considers how lightweight materials and innovative technologies can enrich the quality of temporary spaces. The second part focuses exclusively on landscape, presenting novel approaches in the search for visual lightness and the quest to improve urban spaces. Particular attention is paid to the Italian experience, where the traditional appreciation of brick and stone has limited the scope for use of lightweight structures and membrane materials, often relegating them to a secondary or inappropriate role. The reader will come to appreciate how this attitude demeans a very advanced productive sector and n...

Lightweight mechanical amplifiers for rolled dielectric elastomer actuators and their integration with bio-inspired wing flappers

International Nuclear Information System (INIS)

Lau, Gih-Keong; Lim, Hoong-Ta; Teo, Jing-Ying; Chin, Yao-Wei

2014-01-01

Dielectric elastomer actuators (DEAs) are attractive for use in bio-inspired flapping-wing robots because they have high work density (specific energy) and can produce a large actuation strain. Although the active membrane of a dielectric elastomer is lightweight, the support structure that pre-tensions the elastomeric membrane is massive and it lowers the overall work density. If the DEA is to be used successfully to drive flapping-wing robots, its support structure must be as lightweight as possible. In this work, we designed, analysed, and developed a lightweight shell using a cross-ply laminate of carbon fibre reinforced polymer (CFRP) to pre-strain a rolled DEA. The CFRP shell was shown to weigh 24.3% of the total mass for the whole DEA assembly, while providing up to 35.0% axial pre-strain to a rolled DEA (BJB-5005 silicone rubber). This DEA assembly using the CFRP shell achieved 30.9% of the theoretical work density for a BJB-TC5005 membrane at 33.5 MV m −1 . In comparison, spring rolls with a massive spring core were reported with overall work density merely 10–20% of the maximum value. Furthermore, this CFRP shell can amplify an axial DEA stroke into a larger transverse shell deformation. With these deformation characteristics, this CFRP shell and a rolled DEA were successfully integrated with an insect-inspired thoracic mechanism and they were shown to be feasible to drive it for a flapping wing. (paper)

Inclusion of geopolymers derivate from fly ash and pumice in reinforced concrete

Science.gov (United States)

Montaño, A. M.; González, C. P.; Castro, D.; Gualdron, G.; Atencio, R.

2017-12-01

This paper presents results of a research project related to the development of alkali-activated geopolymers, synthesized from alumina-silicate minerals (fly ash and pumice) which are added to concrete. Alkali sources used in geopolymer synthesis were sodium hydroxide and sodium silicate solution. New materials were structurally characterized by Infra-Red spectroscopy (IR) and X-Ray Diffraction (XRD). Concretes obtained after geopolymers addition as Portland cement substitutes at 10%, 20% and 30%, were mechanically analysed by compression resistance at 7, 14, 28 and 90 drying days. Results were referred to standard (concrete of Portland cement) allows to know cementitious characteristics of geopolymers are lower than those for standard, but it keeps growing at longer drying time than Portland cement. By Electrochemical Impedance Spectroscopy (EIS) it is found that this new material shows high electrical resistance and have been proved as a protection agent against corrosion in reinforced concrete exhibiting anticorrosive properties higher than those showed by the conventional concrete mixture.

Treatments of non-wood plant fibres used as reinforcement in composite materials

Directory of Open Access Journals (Sweden)

Marie-Ange Arsène

2013-01-01

Full Text Available This paper presents a summary of the knowledge on fibres and pulps of non wood tropical plants used as reinforcement in cementitious composites accumulated during the recent years by Guadeloupean and Brazilian teams participating in collaborative work. Vegetable fibres represent a good alternative as non-conventional materials for the construction of ecological and sustainable buildings. The use of such renewable resources contributes to the development of sustainable technologies. The main objective of the paper is to emphasize the use of agricultural wastes in the production of cement based composites. The botanical, chemical, physical, morphological and mechanical properties of fibres from various plants are described. The effects of different treatments on physical, chemical and mechanical properties of fibres are presented. The most effective treatments in influencing the mechanical and physical properties are pyrolysis and alkaline ones, according to the type of plant. The final choice will have to consider fibre availability, and treatment costs.

A Comprehensive Study of the Polypropylene Fiber Reinforced Fly Ash Based Geopolymer.

Directory of Open Access Journals (Sweden)

Navid Ranjbar

Full Text Available As a cementitious material, geopolymers show a high quasi-brittle behavior and a relatively low fracture energy. To overcome such a weakness, incorporation of fibers to a brittle matrix is a well-known technique to enhance the flexural properties. This study comprehensively evaluates the short and long term impacts of different volume percentages of polypropylene fiber (PPF reinforcement on fly ash based geopolymer composites. Different characteristics of the composite were compared at fresh state by flow measurement and hardened state by variation of shrinkage over time to assess the response of composites under flexural and compressive load conditions. The fiber-matrix interface, fiber surface and toughening mechanisms were assessed using field emission scan electron microscopy (FESEM and atomic force microscopy (AFM. The results show that incorporation of PPF up to 3 wt % into the geopolymer paste reduces the shrinkage and enhances the energy absorption of the composites. While, it might reduce the ultimate flexural and compressive strength of the material depending on fiber content.

Uncertainty and Variation of Vibration in Lightweight Structures

DEFF Research Database (Denmark)

Dickow, Kristoffer Ahrens

2012-01-01

Multi-family dwellings and offices build from lightweight materials are becoming a cost efficient and environmentally friendly alternative to traditional heavy structures.......Multi-family dwellings and offices build from lightweight materials are becoming a cost efficient and environmentally friendly alternative to traditional heavy structures....

Selection of nutrient used in biogenic healing agent for cementitious materials

Science.gov (United States)

Tziviloglou, Eirini; Wiktor, Virginie; Jonkers, Henk M.; Schlangen, Erik

2017-06-01

Biogenic self-healing cementitious materials target on the closure of micro-cracks with precipitated inorganic minerals originating from bacterial metabolic activity. Dormant bacterial spores and organic mineral compounds often constitute a biogenic healing agent. The current paper focuses on the investigation of the most appropriate organic carbon source to be used as component of a biogenic healing agent. It is of great importance to use an appropriate organic source, since it will firstly ensure an optimal bacterial performance in terms of metabolic activity, while it should secondly affect the least the properties of the cementitious matrix. The selection is made among three different organic compounds, namely calcium lactate, calcium acetate and sodium gluconate. The methodology that was used for the research was based on continuous and non-continuous oxygen consumption measurements of washed bacterial cultures and on compressive strength tests on mortar cubes. The oxygen consumption investigation revealed a preference for calcium lactate and acetate, but an indifferent behaviour for sodium gluconate. The compressive strength on mortar cubes with different amounts of either calcium lactate or acetate (up to 2.24% per cement weight) was not or it was positively affected when the compounds were dissolved in the mixing water. In fact, for calcium lactate the increase in compressive strength reached 8%, while for calcium acetate the maximum strength increase was 13.4%.

Production of lightweight refractory material by hydrothermal process

International Nuclear Information System (INIS)

Sulejmani, Ramiz B.

2002-01-01

Many different processes of production of lightweight refractories are well known over the World. Traditional production of lightweight refractories is by addition of combustibles or by a special frothing process. This work is concerned with hydrothermal of lightweight refractories from rice husk ash. The rice husk ash, used in present investigations were from Kocani region, R. Macedonia. The chemical analysis of the rice husk ash shows that it contains 91,8 - 93,7% SiO 2 and some alkaline and alkaline earth oxides. Microscopic and X - ray diffraction examinations of the rice husk ash have shown that it is composed of cristobalite, tridimite and amorphous silica. The composition of the mixture for lightweight refractory brick production is 93,4% rice husk ash and 6,6% Ca(OH) 2 . The mixtures were well mixed, moistened and pressed at 5 - 10 MPa. The hydrothermal reactions between calcium hydroxide and rice husk ash over the temperature range 80 - 160 o C were investigated. The period of autoclave treatment was from 2 to 72 h. After the hydrothermal treatment of the samples, the mineralogical composition, bulk density, density, cold crushing strength, porosity, refractoriness and thermal expansion were examined. Analysing the properties of the obtained samples it can be concluded that from rice husk ash and calcium hydroxide under hydrothermal condition it is possible to obtain lightweight acid refractory material with high quality.(Author)

Impact of cementitious materials decalcification on transfer properties: application to radioactive waste deep repository

International Nuclear Information System (INIS)

Perlot, C.

2005-09-01

Cementitious materials have been selected to compose the engineering barrier system (EBS) of the French radioactive waste deep repository, because of concrete physico-chemical properties: the hydrates of the cementitious matrix and the pH of the pore solution contribute to radionuclides retention; furthermore the compactness of these materials limits elements transport. The confinement capacity of the system has to be assessed while a period at least equivalent to waste activity (up to 100.000 years). His durability was sustained by the evolution of transfer properties in accordance with cementitious materials decalcification, alteration that expresses structure long-term behavior. Then, two degradation modes were carried out, taking into account the different physical and chemical solicitations imposed by the host formation. The first mode, a static one, was an accelerated decalcification test using nitrate ammonium solution. It replicates the EBS alteration dues to underground water. Degradation kinetic was estimated by the amount of calcium leached and the measurement of the calcium hydroxide dissolution front. To evaluate the decalcification impact, samples were characterized before and after degradation in term of microstructure (porosity, pores size distribution) and of transfer properties (diffusivity, gas and water permeability). The influence of cement nature (ordinary Portland cement, blended cement) and aggregates type (lime or siliceous) was observed: experiments were repeated on different mortars mixes. On this occasion, an essential reflection on this test metrology was led. The second mode, a dynamical degradation, was performed with an environmental permeameter. It recreates the EBS solicitations ensured during the re-saturation period, distinguished by the hydraulic pressure imposed by the geologic layer and the waste exothermicity. This apparatus, based on triaxial cell functioning, allows applying on samples pressure drop between 2 and 10 MPa and

The Expanded Capabilities Of The Cementitious Barriers Partnership Software Toolbox Version 2.0 - 14331

Energy Technology Data Exchange (ETDEWEB)

Burns, Heather; Flach, Greg; Smith, Frank; Langton, Christine; Brown, Kevin; Kosson, David; Samson, Eric; Mallick, Pramod

2014-01-10

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy (US DOE) Office of Tank Waste Management. The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that help improve understanding and predictions of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. The CBP Software Toolbox – “Version 1.0” was released early in FY2013 and was used to support DOE-EM performance assessments in evaluating various degradation mechanisms that included sulfate attack, carbonation and constituent leaching. The sulfate attack analysis predicted the extent and damage that sulfate ingress will have on concrete vaults over extended time (i.e., > 1000 years) and the carbonation analysis provided concrete degradation predictions from rebar corrosion. The new release “Version 2.0” includes upgraded carbonation software and a new software module to evaluate degradation due to chloride attack. Also included in the newer version are a dual regime module allowing evaluation of contaminant release in two regimes – both fractured and un-fractured. The integrated software package has also been upgraded with new plotting capabilities and many other features that increase the “user-friendliness” of the package. Experimental work has been generated to provide data to calibrate the models to improve the credibility of the analysis and reduce the uncertainty. Tools selected for and developed under this program have been used to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to or longer than 100 years for operating facilities and longer than 1000 years for waste disposal. The CBP Software Toolbox is and will continue to produce tangible benefits to the working DOE

Lightweight superconducting alternators

International Nuclear Information System (INIS)

Keim, T.A.

1988-01-01

One of the most efficient and most lightweight means of converting high-temperature heat energy to electricity is a turboalternator set. Turboalternators are potentially important components of burst-mode power systems, either chemical or nuclear powered. Also, they are probable key components in future electric propulsion systems. Existing examples of multimegawatt turbomachines have been optimized for a variety of aerospace uses, ranging from aircraft propulsion to rocket engine fuel pump drives. There is no corresponding history of multimegawatt alternators built to aerospace standards of mass, performance, and reliability. This paper discusses one of the few such development efforts presently in progress, and gives an indication of possible future potential. In large power ratings, superconducting generators offer substantial power density, specific weight, and efficiency advantages over competing technologies. A program at GE has led to the construction of a lightweight high-voltage 20-MW generator with a superconducting field winding. The first part of this paper describes the design of the generator. The second projects the capabilities of the generator to other ratings

Recent IAEA activities to support utilisation of cementitious materials in radioactive waste management

International Nuclear Information System (INIS)

Ojowan, M.I.; Samanta, S.K.

2015-01-01

The International Atomic Energy Agency promotes a safe and effective management of radioactive waste and has suitable programmes in place to serve the needs of Member States in this area. In support of these programmes the Waste Technology Section fosters technology transfer, promotes information exchange and cooperative research, as well as builds capacity in Member States to manage radioactive wastes, resulting both from the nuclear fuel cycle and nuclear applications. Technical assistance in pre disposal area covers all of these activities and is delivered through established Agency mechanisms including publication of technical documents. While the Agency does not conduct any in-house research activities, its Coordinated Research Projects (CRPs) foster research in Member States. There are 2 CRPs concerning cementitious materials: a CRP on cements and an on-going CRP on irradiated graphite waste. The CRP on cements has resulted in the recent IAEA publication TECDOC-1701. An important activity concerned with characterisation of cementitious waste forms is the LABONET network of laboratory-based centres of expertise involved in the characterization of low and intermediate level radioactive wastes. The Waste Technology Section is preparing a series of comprehensive state of the art technical handbooks

Impact resistance of sustainable construction material using light weight oil palm shells reinforced geogrid concrete slab

International Nuclear Information System (INIS)

Muda, Z C; Usman, F; Beddu, S; Alam, M A; Mustapha, K N; Birima, A H; Sidek, L M; Rashid, M A; Malik, G; Zarroq, O S

2013-01-01

This paper investigate the performance of lightweight oil palm shells (OPS) concrete slab with geogrid reinforcement of 300mm × 300mm size with 20mm, 30mm and 40 mm thick casted with different geogrid orientation and boundary conditions subjected to low impact projectile test. A self-fabricated drop-weight impact test rig with a steel ball weight of 1.2 kg drop at 1 m height has been used in this research work. The main variables for the study is to find the relationship of the impact resistance the slab thickness, boundary conditions and geogrid reinforcement orientation. Test results indicate that the used of the geogrid reinforcement increased the impact resistance under service (first) limit crack up to 5.9 times and at ultimate limit crack up to 20.1 times against the control sample (without geogrid). A good linear relationship has been established between first and ultimate crack resistance against the slab thickness. The orientation of the geogrid has minor significant to the crack resistance of the OPS concrete slab. OPS geogrid reinforced slab has a good crack resistance properties that can be utilized as a sustainable impact resistance construction materials.

Design of Light-Weight High-Entropy Alloys

Directory of Open Access Journals (Sweden)

Rui Feng

2016-09-01

Full Text Available High-entropy alloys (HEAs are a new class of solid-solution alloys that have attracted worldwide attention for their outstanding properties. Owing to the demand from transportation and defense industries, light-weight HEAs have also garnered widespread interest from scientists for use as potential structural materials. Great efforts have been made to study the phase-formation rules of HEAs to accelerate and refine the discovery process. In this paper, many proposed solid-solution phase-formation rules are assessed, based on a series of known and newly-designed light-weight HEAs. The results indicate that these empirical rules work for most compositions but also fail for several alloys. Light-weight HEAs often involve the additions of Al and/or Ti in great amounts, resulting in large negative enthalpies for forming solid-solution phases and/or intermetallic compounds. Accordingly, these empirical rules need to be modified with the new experimental data. In contrast, CALPHAD (acronym of the calculation of phase diagrams method is demonstrated to be an effective approach to predict the phase formation in HEAs as a function of composition and temperature. Future perspectives on the design of light-weight HEAs are discussed in light of CALPHAD modeling and physical metallurgy principles.

STRENGTH OF NANOMODIFIED HIGH-STRENGTH LIGHTWEIGHT CONCRETES

Directory of Open Access Journals (Sweden)

NOZEMTСEV Alexandr Sergeevich

2013-02-01

Full Text Available The paper presents the results of research aimed at development of nanomodified high-strength lightweight concrete for construction. The developed concretes are of low average density and high ultimate compressive strength. It is shown that to produce this type of concrete one need to use hollow glass and aluminosilicate microspheres. To increase the durability of adhesion between cement stone and fine filler the authors offer to use complex nanodimensinal modifier based on iron hydroxide sol and silica sol as a surface nanomodifier for hollow microspheres. It is hypothesized that the proposed modifier has complex effect on the activity of the cement hydration and, at the same time increases bond strength between filler and cement-mineral matrix. The compositions for energy-efficient nanomodified high-strength lightweight concrete which density is 1300…1500 kg/m³ and compressive strength is 40…65 MPa have been developed. The approaches to the design of high-strength lightweight concrete with density of less than 2000 kg/m³ are formulated. It is noted that the proposed concretes possess dense homogeneous structure and moderate mobility. Thus, they allow processing by vibration during production. The economic and practical implications for realization of high-strength lightweight concrete in industrial production have been justified.

Lightweight geopolymer composites as structural elements with improved insulation capacity

Directory of Open Access Journals (Sweden)

Kakali Glikeria

2018-01-01

Full Text Available This study concerns the development of lightweight fly ash based geopolymers which can be applied as alternatives to the traditional lightweight concrete. Different kinds of expanded polystyrene were used as lightweight agents. The results showed that lightweight geopolymers were successfully prepared, exhibiting compressive strength and density in the range 7.70 – 29.57 MPa and 0.97 – 1.57 g/cm3, respectively. The product containing 3% w/w of commercial expanded polystyrene possesses low thermal conductivity (0.16 W/mK combined with sufficient mechanical strengths (11 MPa, excellent stability and fire resistance while its water absorption is comparable to that of conventional construction materials (cement mortars, concrete.

Lightweight Robotic Excavation, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Robust, lightweight, power-efficient excavation robots are mission enablers for lunar outposts and surface systems. Lunar excavators of this type cost-effectively...

Fiber breakage phenomena in long fiber reinforced plastic preparation

International Nuclear Information System (INIS)

Huang, Chao-Tsai; Tseng, Huan-Chang; Chang, Rong-Yeu; Vlcek, Jiri

2015-01-01

Due to the high demand of smart green, the lightweight technologies have become the driving force for the development of automotives and other industries in recent years. Among those technologies, using short and long fiber-reinforced plastics (FRP) to replace some metal components can reduce the weight of an automotive significantly. However, the microstructures of fibers inside plastic matrix are too complicated to manage and control during the injection molding through the screw, the runner, the gate, and then into the cavity. This study focuses on the fiber breakage phenomena during the screw plastification. Results show that fiber breakage is strongly dependent on screw design and operation. When the screw geometry changes, the fiber breakage could be larger even with lower compression ratio. (paper)

FY2014 Lightweight Materials R&D Annual Progress Report

Energy Technology Data Exchange (ETDEWEB)

None

2015-03-01

The Lightweight Materials research and development (R&D) area within the DOE Vehicle Technologies Office (VTO) provides support and guidance for many cutting-edge automotive technologies under development. Research focuses on addressing critical barriers to commercializing lightweight materials for passenger and commercial vehicles.

Impact resistance performance of green construction material using light weight oil palm shells reinforced bamboo concrete slab

International Nuclear Information System (INIS)

Muda, Z C; Usman, F; Beddu, S; Alam, M A; Thiruchelvam, S; Sidek, L M; Basri, H; Saadi, S

2013-01-01

This paper investigate the performance of lightweight oil palm shells (OPS) concrete with varied bamboo reinforcement content for the concrete slab of 300mm x 300mm size reinforced with different thickness subjected to low impact projectile test. A self-fabricated drop-weight impact test rig with a steel ball weight of 1.2 kg drop at 1 m height has been used in this research work. The main variables for the study is to find the relationship of the impact resistance against the amount of bamboo reinforcement and slab thickness. A linear relationship has been established between first and ultimate crack resistance against bamboo diameters and slab thickness by the experiment. The linear relationship has also been established between the service (first) crack and ultimate crack resistance against the bamboo reinforcement diameter for a constant spacing for various slab thickness using 0.45 OPS and 0.6 OPS bamboo reinforced concrete. The increment in bamboo diameter has more effect on the first crack resistance than the ultimate crack resistance. The linear relationship has also been established between the service (first) crack and ultimate crack resistance against the various slab thickness. Increment in slab thickness of the slab has more effect on the crack resistance as compare to the increment in the diameter of the bamboo reinforcement.

Review on supplymentary cementitious materials used in inorganic polymer concrete

Science.gov (United States)

Srinivasreddy, K.; Srinivasan, K.

2017-11-01

This paper presents a review on various supplementary cementitious materials generated from industries are used in concrete, which one is considered a waste material. These materials are rich in aluminosilicates and are activated by sodium/potassium based alkaline solution to form geopolymer concrete. When these geopolymer concrete is used in civil engineering applications has showed better or similar mechanical properties and durability properties than ordinary Portland cement concrete. This paper also given the overview on sodium hydroxide (NaOH) & sodium silicate solution (Na2SiO3) ratios, curing adopted for different geopolymer concretes and the effect of adding fibres in geopolymer concretes.

Environmental assessment of lightweight electric vehicles

CERN Document Server

Egede, Patricia

2017-01-01

This monograph adresses the challenge of the environmental assessment of leightweight electric vehicles. It poses the question whether the use of lightweight materials in electric vehicles can reduce the vehicles’ environmental impact and compares the environmental performance of a lightweight electric vehicle (LEV) to other types of vehicles. The topical approach focuses on methods from life cycle assessment (LCA), and the book concludes with a comprehensive concept on the environmental assessment of LEVs. The target audience primarily comprises LCA practitioners from research institutes and industry, but it may also be beneficial for graduate students specializing in the field of environmental assessment.

Numerical simulation of a high velocity impact on fiber reinforced materials

International Nuclear Information System (INIS)

Thoma, Klaus; Vinckier, David

1994-01-01

Whereas the calculation of a high velocity impact on isotropical materials can be done on a routine basis, the simulation of the impact and penetration process into nonisotropical materials such as reinforced concrete or fiber reinforced materials still is a research task.We present the calculation of an impact of a metallic fragment on a modern protective wall structure. Such lightweight protective walls typically consist of two layers, a first outer layer made out of a material with high hardness and a backing layer. The materials for the backing layer are preferably fiber reinforced materials. Such types of walls offer a protection against fragments in a wide velocity range.For our calculations we used a non-linear finite element Lagrange code with explicit time integration. To be able to simulate the high velocity penetration process with a continuous erosion of the impacting metallic fragment, we used our newly developed contact algorithm with eroding surfaces. This contact algorithm is vectorized to a high degree and especially robust as it was developed to work for a wide range of contact-impact problems. To model the behavior of the fiber reinforced material under the highly dynamic loads, we present a material model which initially was developed to calculate the crash behavior (automotive applications) of modern high strength fiber-matrix systems. The model can describe the failure and the postfailure behavior up to complete material crushing.A detailed simulation shows the impact of a metallic fragment with a velocity of 750ms -1 on a protective wall with two layers, the deformation and erosion of fragment and wall material and the failure of the fiber reinforced material. ((orig.))

Development of Abaca Fiber-reinforced Foamed Fly Ash Geopolymer

Directory of Open Access Journals (Sweden)

Janne Pauline S. Ngo

2018-01-01

Full Text Available The growing environmental and economic concerns have led to the need for more sustainable construction materials. The development of foamed geopolymer combines the benefit of reduced environmental footprint and attractive properties of geopolymer technology with foam concrete’s advantages of being lightweight, insulating and energy-saving. In this study, alkali-treated abaca fiber-reinforced geopolymer composites foamed with H2O2 were developed using fly ash as the geopolymer precursor. The effects of abaca fiber loading, foaming agent dosage, and curing temperature on mechanical strength were evaluated using Box-Behken design of experiment with three points replicated. Volumetric weight of samples ranged from 1966 kg/m3 to 2249 kg/m3. Measured compressive strength and flexural ranged from 19.56 MPa to 36.84 MPa, and 2.41 MPa to 6.25 MPa, respectively. Results suggest enhancement of compressive strength by abaca reinforcement and elevated temperature curing. Results, however, indicate a strong interaction between curing temperature and foaming agent dosage, which observably caused the composite’s compressive strength to decline when simultaneously set at high levels. Foaming agent dosage was the only factor detected to significantly affect flexural strength.

Thermoplastic Composites Reinforced with Textile Grids: Development of a Manufacturing Chain and Experimental Characterisation

Science.gov (United States)

Böhm, R.; Hufnagl, E.; Kupfer, R.; Engler, T.; Hausding, J.; Cherif, C.; Hufenbach, W.

2013-12-01

A significant improvement in the properties of plastic components can be achieved by introducing flexible multiaxial textile grids as reinforcement. This reinforcing concept is based on the layerwise bonding of biaxially or multiaxially oriented, completely stretched filaments of high-performance fibers, e.g. glass or carbon, and thermoplastic components, using modified warp knitting techniques. Such pre-consolidated grid-like textiles are particularly suitable for use in injection moulding, since the grid geometry is very robust with respect to flow pressure and temperature on the one hand and possesses an adjustable spacing to enable a complete filling of the mould cavity on the other hand. The development of pre-consolidated textile grids and their further processing into composites form the basis for providing tailored parts with a large number of additional integrated functions like fibrous sensors or electroconductive fibres. Composites reinforced in that way allow new product groups for promising lightweight structures to be opened up in future. The article describes the manufacturing process of this new composite class and their variability regarding reinforcement and function integration. An experimentally based study of the mechanical properties is performed. For this purpose, quasi-static and highly dynamic tensile tests have been carried out as well as impact penetration experiments. The reinforcing potential of the multiaxial grids is demonstrated by means of evaluating drop tower experiments on automotive components. It has been shown that the load-adapted reinforcement enables a significant local or global improvement of the properties of plastic components depending on industrial requirements.

Overview of recent work on self-healing in cementitious materials

Directory of Open Access Journals (Sweden)

Lv, Z.

2014-12-01

Full Text Available Cracks, especially microcracks, in concrete are of paramount importance to the durability and the service life of cementitious composite. However, the self-healing technology, including autogenous healing and autonomous healing, is expected to be one of effective tools to overcome this boring problem. In this paper, we focus on the autogenous healing of concrete material and a few of recent works of autonomous healing are also mentioned. The durability and the mechanical properties improved by the self-healing phenomenon are reviewed from experimental investigation and practical experience. Several aspects of researches, such as autogenous healing capability of an innovative concrete incorporated geo-materials, self-healing of engineered cementitious composite and fire-damaged concrete, effect of mineral and admixtures on mechanism and efficiency of self-healing concrete are summarized to evaluate the presented progresses in the past several years and to outline the perspective for the further developments. Moreover, a special emphasis is given on the analytical models and computer simulation method of the researches of self-healing in cementitious materials.Las fisuras, y sobre todo las microfisuras, tienen una gran repercusión en la durabilidad y en la vida útil de los materiales cementantes. Ante este problema, la tecnología de la autorreparación, tanto autógena como autónoma, se presenta como una solución eficaz. El artículo se centra en la reparación autógena del hormigón, así como en algunos trabajos recientes sobre la reparación autónoma. Se describen las mejoras de las propiedades de durabilidad y de resistencia que proporciona la técnica del hormigón autorreparable, tanto desde el punto de vista de la investigación experimental como del de la experiencia práctica. A fin de evaluar los avances logrados en los últimos años y de trazar las grandes líneas de desarrollo futuro, se resumen varios de los aspectos

Potential emissions savings of lightweight composite aircraft components evaluated through life cycle assessment

Directory of Open Access Journals (Sweden)

2011-03-01

Full Text Available A cradle-to-grave life cycle assessment (LCA of structural aircraft materials has been utilised to assess and compare the total emissions produced during manufacturing, use and disposal of aerospace materials and their selected components. First, a comparison of aluminium, GLARE and carbon fibre reinforced polymer (CFRP plates was performed to investigate the potential of lightweight composites in reducing aviation emissions. Subsequently, a case study is presented on a tubular component for which more accurate manufacturing data were directly available. A structural steel tube was replaced with a composite tubular component. The analysis has shown that once the composite material is used as a component in the aircraft, there is a cumulative saving of aircraft fuel and emissions, in particular from CFRP structures. The environmental analysis included the long-term use predictions for CFRPs, involving detailed raw materials production, use and operation, and disposal scenarios.

The Influence of Disorder in Multifilament Yarns on the Bond Performance in Textile Reinforced Concrete

Directory of Open Access Journals (Sweden)

M. Konrad

2004-01-01

Full Text Available In this paper we analyze the performance of a bond layer between the multi-filament yarn and the cementitious matrix. The performance of the bond layer is a central issue in the development of textile-reinforced concrete. The changes in the microstructure during the loading result in distinguished failure mechanisms on the micro, meso and macro scales. The paper provides a brief review of these effects and describes a modeling strategy capable of reflecting the failure process. Using the model of the bond layer we illuminate the correspondence between the disorder in the microstructure of the yarn and the bonding behavior at the meso- and macro level. Particular interest is paid to the influence of irregularities in the micro-structure (relative differences in filament lengths, varying bond quality, bond-free length for different levels of local bond quality between the filament surface and the matrix. 

Reuse of thermosetting plastic waste for lightweight concrete.

Science.gov (United States)

Panyakapo, Phaiboon; Panyakapo, Mallika

2008-01-01

This paper presents the utilization of thermosetting plastic as an admixture in the mix proportion of lightweight concrete. Since this type of plastic cannot be melted in the recycling process, its waste is expected to be more valuable by using as an admixture for the production of non-structural lightweight concrete. Experimental tests for the variation of mix proportion were carried out to determine the suitable proportion to achieve the required properties of lightweight concrete, which are: low dry density and acceptable compressive strength. The mix design in this research is the proportion of plastic, sand, water-cement ratio, aluminum powder, and lignite fly ash. The experimental results show that the plastic not only leads to a low dry density concrete, but also a low strength. It was found that the ratio of cement, sand, fly ash, and plastic equal to 1.0:0.8:0.3:0.9 is an appropriate mix proportion. The results of compressive strength and dry density are 4.14N/mm2 and 1395 kg/m3, respectively. This type of concrete meets most of the requirements for non-load-bearing lightweight concrete according to ASTM C129 Type II standard.

Self-healing of Micro-cracks in Engineered Cementitious Composites

Directory of Open Access Journals (Sweden)

Suryanto B.

2015-12-01

Full Text Available The performance of an Engineered Cementitious Composite (ECC to self-heal micro-cracks under a controlled laboratory environment is presented. Ten dog-bone shaped samples were prepared; five of them were preloaded to known strains and then left to heal in water in a temperature-controlled laboratory. Ultrasonic pulse velocity (UPV measurements were undertaken to monitor the crack-healing process. It was found that all samples exhibited recoveries in UPV and were able to recover to between 96.6% and 98% of their pre-test UPV values over a period of four weeks. An accelerated rate of healing was observed in the initial two-day period immediately following the preloading test.

Niobium Carbide-Reinforced Al Matrix Composites Produced by High-Energy Ball Milling

Science.gov (United States)

Travessa, Dilermando Nagle; Silva, Marina Judice; Cardoso, Kátia Regina

2017-06-01

Aluminum and its alloys are key materials for the transportation industry as they contribute to the development of lightweight structures. The dispersion of hard ceramic particles in the Al soft matrix can lead to a substantial strengthening effect, resulting in composite materials exhibiting interesting mechanical properties and inspiring their technological use in sectors like the automotive and aerospace industries. Powder metallurgy techniques are attractive to design metal matrix composites, achieving a homogeneous distribution of the reinforcement into the metal matrix. In this work, pure aluminum has been reinforced with particles of niobium carbide (NbC), an extremely hard and stable refractory ceramic. Its use as a reinforcing phase in metal matrix composites has not been deeply explored. Composite powders produced after different milling times, with 10 and 20 vol pct of NbC were produced by high-energy ball milling and characterized by scanning electron microscopy and by X-ray diffraction to establish a relationship between the milling time and size, morphology, and distribution of the particles in the composite powder. Subsequently, an Al/10 pct NbC composite powder was hot extruded into cylindrical bars. The strength of the obtained composite bars is comparable to the commercial high-strength, aeronautical-grade aluminum alloys.

Effects of different crumb rubber sizes on the flowability and compressive strength of hybrid fibre reinforced ECC

Science.gov (United States)

Khed, Veerendrakumar C.; Mohammed, Bashar S.; Fadhil Nuruddin, Muhd

2018-04-01

The different sizes of crumb rubber have been used to investigate the effects on flowability and the compressive strength of the hybrid fibre reinforced engineered cementitious composite. Two sizes of crumb rubber 30 mesh and 1 to 3mm were used in partial replacement with the fine aggregate up to 60%. The experimental study was carried out through mathematical and statistical analysis by response surface methodology (RSM) using the Design Expert software. The response models have been developed and the results were validated by analysis of variance (ANOVA). It was found that finer sized crumb rubber inclusion had produced better workability and higher compressive strength when compared to the larger size and it was concluded that crumb rubber has negative effect on compressive strength and positive effect on workability. The optimization results are found to an approximately good agreement with the experimental results.

Cementitious composite materials with improved self-healing potential

Directory of Open Access Journals (Sweden)

Cornelia BAERA

2015-12-01

Full Text Available Cement-based composites have proved, over the time, certain abilities of self-healing the damages (cracks and especially microcracs that occur within their structure. Depending on the level of damage and of the composite type in which this occurs, the self - healing process (SH can range from crack closing or crack sealing to the stage of partial or even complete recovery of material physical - mechanical properties. The aim of this paper is to present the general concept of Engineered Cementitious Composites (ECCs with their unique properties including their self-healing (SH capacity, as an innovative direction for a global sustainable infrastructure. The experimental steps initiated for the development in Romania of this unique category of materials, using materials available on the local market, are also presented.

Development of a self-compacting gypsum-based lightweight composite

NARCIS (Netherlands)

Yu, Q.; Brouwers, H.J.H.

2012-01-01

This article addresses experiments and theories of a self-compacting gypsum-based lightweight composite (SGLC). A ß-hemihydrate is used as binder and lightweight aggregate (LWA, 0–2 mm in different size ranges) is used as aggregate into this composite. The mix of the new composite is designed based

Concrete mixture characterization. Cementitious barriers partnership

Energy Technology Data Exchange (ETDEWEB)

Langton, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Protiere, Yannick [SIMCO Technologies, Inc., Quebec (Canada)

2014-12-01

This report summarizes the characterization study performed on two concrete mixtures used for radioactive waste storage. Both mixtures were prepared with approximately 425 kg of binder. The testing protocol mostly focused on determining the transport properties of the mixtures; volume of permeable voids (porosity), diffusion coefficients, and water permeability were evaluated. Tests were performed after different curing durations. In order to obtain data on the statistical distribution of transport properties, the measurements after 2 years of curing were performed on 10+ samples. Overall, both mixtures exhibited very low tortuosities and permeabilities, a direct consequence of their low water-to-binder ratio and the use of supplementary cementitious materials. The data generated on 2-year old samples showed that porosity, tortuosity and permeability follow a normal distribution. Chloride ponding tests were also performed on test samples. They showed limited chloride ingress, in line with measured transport properties. These test results also showed that both materials react differently with chloride, a consequence of the differences in the binder chemical compositions.

Modelling and experimental study of low temperature energy storage reactor using cementitious material

International Nuclear Information System (INIS)

Ndiaye, Khadim; Ginestet, Stéphane; Cyr, Martin

2017-01-01

Highlights: • Numerical study of a thermochemical reactor using a cementitious material for TES. • Development and test of an original prototype based on this original material. • Comparison of the experimental and numerical results. • Energy balance of the experimental setup (charging and discharging phases). - Abstract: Renewable energy storage is now essential to enhance the energy performance of buildings and to reduce their environmental impact. Most adsorbent materials are capable of storing heat, in a large range of temperature. Ettringite, the main product of the hydration of sulfoaluminate binders, has the advantage of high energy storage density at low temperature, around 60 °C. The objective of this study is, first, to predict the behaviour of the ettringite based material in a thermochemical reactor during the heat storage process, by heat storage modelling, and then to perform experimental validation by tests on a prototype. A model based on the energy and mass balance in the cementitious material was developed and simulated in MatLab software, and was able to predict the spatiotemporal behaviour of the storage system. This helped to build a thermochemical reactor prototype for heat storage tests in both the charging and discharging phases. Thus experimental tests validated the numerical model and served as proof of concept.

Use Of Cementitious Materials For SRS Reactor Facility In-Situ Decommissioning - 11620

International Nuclear Information System (INIS)

Langton, C.; Stefanko, D.; Serrato, M.; Blankenship, J.; Griffin, W.; Waymer, J.; Matheny, D.; Singh, D.

2010-01-01

The United States Department of Energy (US DOE) concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., producing (reactor facilities), processing (isotope separation facilities) or storing radioactive materials. The Savannah River Site 105-P and 105-R Reactor Facility ISD requires about 250,000 cubic yards of grout to fill the below grade structure. The fills are designed to prevent subsidence, reduce water infiltration, and isolate contaminated materials. This work is being performed as a Comprehensive Environmental Response, Compensations and Liability Act (CERCLA) action and is part of the overall soil and groundwater completion projects for P- and R-Areas. Cementitious materials were designed for the following applications: (1) Below grade massive voids/rooms: Portland cement-based structural flowable fills for - Bulk filling, Restricted placement and Underwater placement. (2) Special below grade applications for reduced load bearing capacity needs: Cellular portland cement lightweight fill (3) Reactor vessel fills that are compatible with reactive metal (aluminum metal) components in the reactor vessels: Calcium sulfoaluminate flowable fill, and Magnesium potassium phosphate flowable fill. (4) Caps to prevent water infiltration and intrusion into areas with the highest levels of radionuclides: Portland cement based shrinkage compensating concrete. A system engineering approach was used to identify functions and requirements of the fill and capping materials. Laboratory testing was performed to identify candidate formulations and develop final design mixes. Scale-up testing was performed to verify material production and placement as well as fresh and cured properties. The 105-P and 105-R ISD projects are currently in progress and are expected to be complete in 2012. The focus of this paper is to describe the (1) grout mixes

USE OF CEMENTITIOUS MATERIALS FOR SRS REACTOR FACILITY IN-SITU DECOMMISSIONING - 11620

Energy Technology Data Exchange (ETDEWEB)

Langton, C.; Stefanko, D.; Serrato, M.; Blankenship, J.; Griffin, W.; Waymer, J.; Matheny, D.; Singh, D.

2010-12-07

The United States Department of Energy (US DOE) concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., producing (reactor facilities), processing (isotope separation facilities) or storing radioactive materials. The Savannah River Site 105-P and 105-R Reactor Facility ISD requires about 250,000 cubic yards of grout to fill the below grade structure. The fills are designed to prevent subsidence, reduce water infiltration, and isolate contaminated materials. This work is being performed as a Comprehensive Environmental Response, Compensations and Liability Act (CERCLA) action and is part of the overall soil and groundwater completion projects for P- and R-Areas. Cementitious materials were designed for the following applications: (1) Below grade massive voids/rooms: Portland cement-based structural flowable fills for - Bulk filling, Restricted placement and Underwater placement. (2) Special below grade applications for reduced load bearing capacity needs: Cellular portland cement lightweight fill (3) Reactor vessel fills that are compatible with reactive metal (aluminum metal) components in the reactor vessels: Calcium sulfoaluminate flowable fill, and Magnesium potassium phosphate flowable fill. (4) Caps to prevent water infiltration and intrusion into areas with the highest levels of radionuclides: Portland cement based shrinkage compensating concrete. A system engineering approach was used to identify functions and requirements of the fill and capping materials. Laboratory testing was performed to identify candidate formulations and develop final design mixes. Scale-up testing was performed to verify material production and placement as well as fresh and cured properties. The 105-P and 105-R ISD projects are currently in progress and are expected to be complete in 2012. The focus of this paper is to describe the (1) grout mixes

Technological developments for ultra-lightweight, large aperture, deployable mirror for space telescopes

Science.gov (United States)

Zuccaro Marchi, Alessandro; D'Amato, Francesco; Gallieni, Daniele; Biasi, Roberto; Molina, Marco; Duò, Fabrizio; Ruder, Nikolaus; Salinari, Piero; Lisi, Franco; Riccardi, Armando; Gambicorti, Lisa; Simonetti, Francesca; Pereira do Carmo, Joao Pedro N.

2017-11-01

The increasing interest on space telescopes for scientific applications leads to implement the manufacturing technology of the most critical element, i.e. the primary mirror: being more suitable a large aperture, it must be lightweight and deployable. The presented topic was originally addressed to a spaceborne DIAL (Differential Absorption LIDAR) mission operating at 935.5 nm for the measurement of water vapour profile in atmosphere, whose results were presented at ICSO 2006 and 2008. Aim of this paper is to present the latest developments on the main issues related to the fabrication of a breadboard, covering two project critical areas identified during the preliminary studies: the design and performances of the long-stroke actuators used to implement the mirror active control and the mirror survivability to launch via Electrostatic Locking (EL) between mirror and backplane. The described work is developed under the ESA/ESTEC contract No. 22321/09/NL/RA. The lightweight mirror is structured as a central sector surrounded by petals, all of them actively controlled to reach the specified shape after initial deployment and then maintained within specs for the entire mission duration. The presented study concerns: a) testing the Carbon Fiber Reinforced Plastic (CFRP) backplane manufacturing and EL techniques, with production of suitable specimens; b) actuator design optimisation; c) design of the deployment mechanism including a high precision latch; d) the fabrication of thin mirrors mock-ups to validate the fabrication procedure for the large shells. The current activity aims to the construction of an optical breadboard capable of demonstrating the achievement of all these coupled critical aspects: optical quality of the thin shell mirror surface, actuators performances and back-plane - EL subsystem functionality.

A MAC Mode for Lightweight Block Ciphers

DEFF Research Database (Denmark)

Luykx, Atul; Preneel, Bart; Tischhauser, Elmar Wolfgang

2016-01-01

Lightweight cryptography strives to protect communication in constrained environments without sacrificing security. However, security often conflicts with efficiency, shown by the fact that many new lightweight block cipher designs have block sizes as low as 64 or 32 bits. Such low block sizes lead...... no effect on the security bound, allowing an order of magnitude more data to be processed per key. Furthermore, LightMAC is incredibly simple, has almost no overhead over the block cipher, and is parallelizable. As a result, LightMAC not only offers compact authentication for resource-constrained platforms...

Light-weight Mutual Authentication with Non-repudiation

Directory of Open Access Journals (Sweden)

V. Clupek

2018-04-01

Full Text Available In this paper, we focused on a problem of authentication on low-cost devices. We have proposed a new light-weight protocol for mutual authentication of communication entities with non-repudiation of realized events. The protocol is simple and suitable for implementation on low-cost devices. Non-repudiation of realized events is achieved by involving a Trusted Third Party (TTP to the communication. The proposed protocol uses only an appropriate lightweight hash function and pre-shared secret data. Security of the proposed protocol was verified by the BAN (Burrows-Abadi-Needham logic.

Cases of Lightweight Structures for Polar Areas

DEFF Research Database (Denmark)

Pedreros, Jessica Fernandoy; Christ, Julian; Shepherd, Paul

2017-01-01

The paper focuses on what the authors call ‘Polar Lightweight Structures’. The first part presents a collection of lightweight structures (LWS) designed and built for Antarctic conditions, with the aim of demonstrating the diversity of approaches attempted by designers. The second part of the paper...... presents two studies where different computational methods were applied for the design of generic LWS based on the local conditions of two particular Polar locations; namely, the Arctic region and Glacier Union in the Antarctic plateau. Both studies were conducted independently with the aim...

Experimental Evaluation of Lightweight AAC Masonry Wall Prisms with Ferrocement Layers in Compression and Flexure

KAUST Repository

Abdel Mooty, Mohamed; Hendam, Ahmed; Fahmy, Ezzat; Abou Zeid, Mohamed; Haroun, Medhat

2012-01-01

An experimental program is designed to evaluate the performance of lightweight autoclaved aerated concrete masonry wall strengthened using ferrocement layers, in a sandwich structure, under in-plane compression and out-of-plane bending. The 25 mm thick ferrocement mortar is reinforced with steel welded wire mesh of 1 mm diameters at 15 mm spacing. Different types of shear connectors are used to evaluate their effect on failure loads. The effect of different design parameters on the wall strength are considered including wall thickness, mortar strength, and type and distribution of shear connectors. A total of 20 prisms are tested in compression and 5 prisms are tested under bending. The proposed ferrocement strengthening technique is easy to apply on existing wall system and results in significant strength and stiffness enhancement of the tested wall specimens. © (2012) Trans Tech Publications.

Experimental Evaluation of Lightweight AAC Masonry Wall Prisms with Ferrocement Layers in Compression and Flexure

KAUST Repository

Abdel Mooty, Mohamed

2012-05-01

An experimental program is designed to evaluate the performance of lightweight autoclaved aerated concrete masonry wall strengthened using ferrocement layers, in a sandwich structure, under in-plane compression and out-of-plane bending. The 25 mm thick ferrocement mortar is reinforced with steel welded wire mesh of 1 mm diameters at 15 mm spacing. Different types of shear connectors are used to evaluate their effect on failure loads. The effect of different design parameters on the wall strength are considered including wall thickness, mortar strength, and type and distribution of shear connectors. A total of 20 prisms are tested in compression and 5 prisms are tested under bending. The proposed ferrocement strengthening technique is easy to apply on existing wall system and results in significant strength and stiffness enhancement of the tested wall specimens. © (2012) Trans Tech Publications.

Measurement of volume change in cementitious materials at early ages - Review of testing protocols and interpretation of results

DEFF Research Database (Denmark)

Sant, Gaurav; Lura, Pietro; Weiss, Jason

2006-01-01

Early-age cracking in concrete bridge decks, pavements, and superstructure elements has served as the impetus for substantial research on early-age shrinkage in cementitious materials. Much of this research has indicated how mixture proportions, constituent materials, and construction operations...

Conserved role of unc-79 in ethanol responses in lightweight mutant mice.

Directory of Open Access Journals (Sweden)

David J Speca

2010-08-01

Full Text Available The mechanisms by which ethanol and inhaled anesthetics influence the nervous system are poorly understood. Here we describe the positional cloning and characterization of a new mouse mutation isolated in an N-ethyl-N-nitrosourea (ENU forward mutagenesis screen for animals with enhanced locomotor activity. This allele, Lightweight (Lwt, disrupts the homolog of the Caenorhabditis elegans (C. elegans unc-79 gene. While Lwt/Lwt homozygotes are perinatal lethal, Lightweight heterozygotes are dramatically hypersensitive to acute ethanol exposure. Experiments in C. elegans demonstrate a conserved hypersensitivity to ethanol in unc-79 mutants and extend this observation to the related unc-80 mutant and nca-1;nca-2 double mutants. Lightweight heterozygotes also exhibit an altered response to the anesthetic isoflurane, reminiscent of unc-79 invertebrate mutant phenotypes. Consistent with our initial mapping results, Lightweight heterozygotes are mildly hyperactive when exposed to a novel environment and are smaller than wild-type animals. In addition, Lightweight heterozygotes exhibit increased food consumption yet have a leaner body composition. Interestingly, Lightweight heterozygotes voluntarily consume more ethanol than wild-type littermates. The acute hypersensitivity to and increased voluntary consumption of ethanol observed in Lightweight heterozygous mice in combination with the observed hypersensitivity to ethanol in C. elegans unc-79, unc-80, and nca-1;nca-2 double mutants suggests a novel conserved pathway that might influence alcohol-related behaviors in humans.

Physical and Mechanical Properties of LoVAR: A New Lightweight Particle-Reinforced Fe-36Ni Alloy

Science.gov (United States)

Stephenson, Timothy; Tricker, David; Tarrant, Andrew; Michel, Robert; Clune, Jason

2015-01-01

Fe-36Ni is an alloy of choice for low thermal expansion coefficient (CTE) for optical, instrument and electrical applications in particular where dimensional stability is critical. This paper outlines the development of a particle-reinforced Fe-36Ni alloy that offers reduced density and lower CTE compared to the matrix alloy. A summary of processing capability will be given relating the composition and microstructure to mechanical and physical properties.

The Cementitious Barriers Partnership Experimental Programs and Software Advancing DOE@@@s Waste Disposal/Tank Closure Efforts @@@ 15436

International Nuclear Information System (INIS)

Burns, Heather; Flach, Greg; Smith, Frank; Langton, Christine; Brown, Kevin; Kosson, David; Samson, Eric; Mallick, Pramod

2015-01-01

The U.S. Department of Energy Environmental Management (DOE-EM) Office of Tank Waste Management-sponsored Cementitious Barriers Partnership (CBP) is chartered with providing the technical basis for implementing cement-based waste forms and radioactive waste containment structures for long-term disposal. DOE needs in this area include the following to support progress in final treatment and disposal of legacy waste and closure of High-Level Waste (HLW) tanks in the DOE complex: long-term performance predictions, flow sheet development and flow sheet enhancements, and conceptual designs for new disposal facilities. The DOE-EM Cementitious Barriers Partnership is producing software and experimental programs resulting in new methods and data needed for end-users involved with environmental cleanup and waste disposal. Both the modeling tools and the experimental data have already benefited the DOE sites in the areas of performance assessments by increasing confidence backed up with modeling support, leaching methods, and transport properties developed for actual DOE materials. In 2014, the CBP Partnership released the CBP Software Toolbox @@ @@Version 2.0@@@ which provides concrete degradation models for 1) sulfate attack, 2) carbonation, and 3) chloride initiated rebar corrosion, and includes constituent leaching. These models are applicable and can be used by both DOE and the Nuclear Regulatory Commission (NRC) for service life and long-term performance evaluations and predictions of nuclear and radioactive waste containment structures across the DOE complex, including future SRS Saltstone and HLW tank performance assessments and special analyses, Hanford site HLW tank closure projects and other projects in which cementitious barriers are required, the Advanced Simulation Capability for Environmental Management (ASCEM) project which requires source terms from cementitious containment structures as input to their flow simulations, regulatory reviews of DOE performance

Shock Response of Lightweight Adobe Masonry

Science.gov (United States)

Sauer, C.; Bagusat, F.; Heine, A.; Riedel, W.

2018-04-01

The behavior of a low density and low-strength building material under shock loading is investigated. The considered material is lightweight adobe masonry characterized by a density of 1.2 g/cm3 and a quasi-static uniaxial compressive strength of 2.8 MPa. Planar-plate-impact (PPI) tests with velocities in between 295 and 950 m/s are performed in order to obtain Hugoniot data and to derive parameters for an equation of state (EOS) that captures the occurring phenomenology of porous compaction and subsequent unloading. The resulting EOS description is validated by comparing the experimental free surface velocity time curves with those obtained by numerical simulations of the performed PPI tests. The non-linear compression behavior, including the pore compaction mechanism, constitutes a main ingredient for modelling the response of adobe to blast and high-velocity impact loading. We hence present a modeling approach for lightweight adobe which can be applied to such high rate loading scenarios in future studies. In general, this work shows that PPI tests on lightweight and low-strength geological materials can be used to extract Hugoniot data despite significant material inhomogeneity. Furthermore, we demonstrate that a homogenous material model is able to numerically describe such a material under shock compression and release with a reasonable accuracy.

Bonding Properties of Basalt Fiber and Strength Reduction According to Fiber Orientation

Directory of Open Access Journals (Sweden)

Jeong-Il Choi

2015-09-01

Full Text Available The basalt fiber is a promising reinforcing fiber because it has a relatively higher tensile strength and a density similar to that of a concrete matrix as well as no corrosion possibility. This study investigated experimentally the bonding properties of basalt fiber with cementitious material as well as the effect of fiber orientation on the tensile strength of basalt fiber for evaluating basalt fiber’s suitability as a reinforcing fiber. Single fiber pullout tests were performed and then the tensile strength of fiber was measured according to fiber orientation. The test results showed that basalt fiber has a strong chemical bond with the cementitious matrix, 1.88 times higher than that of polyvinyl alcohol fibers with it. However, other properties of basalt fiber such as slip-hardening coefficient and strength reduction coefficient were worse than PVA and polyethylene fibers in terms of fiber bridging capacity. Theoretical fiber-bridging curves showed that the basalt fiber reinforcing system has a higher cracking strength than the PVA fiber reinforcing system, but the reinforcing system showed softening behavior after cracking.

Bonding Properties of Basalt Fiber and Strength Reduction According to Fiber Orientation.

Science.gov (United States)

Choi, Jeong-Il; Lee, Bang Yeon

2015-09-30

The basalt fiber is a promising reinforcing fiber because it has a relatively higher tensile strength and a density similar to that of a concrete matrix as well as no corrosion possibility. This study investigated experimentally the bonding properties of basalt fiber with cementitious material as well as the effect of fiber orientation on the tensile strength of basalt fiber for evaluating basalt fiber's suitability as a reinforcing fiber. Single fiber pullout tests were performed and then the tensile strength of fiber was measured according to fiber orientation. The test results showed that basalt fiber has a strong chemical bond with the cementitious matrix, 1.88 times higher than that of polyvinyl alcohol fibers with it. However, other properties of basalt fiber such as slip-hardening coefficient and strength reduction coefficient were worse than PVA and polyethylene fibers in terms of fiber bridging capacity. Theoretical fiber-bridging curves showed that the basalt fiber reinforcing system has a higher cracking strength than the PVA fiber reinforcing system, but the reinforcing system showed softening behavior after cracking.

Effect of various supplementary cementitious materials on rheological properties of self-consolidating concrete

OpenAIRE

Saleh Ahari, Reza; Erdem, Tahir Kemal; Ramyar, Kambiz

2015-01-01

In design of self-consolidating concrete (SCC) for a given application, the mixture's rheological parameters should be adjusted to achieve a given profile of yield stress and plastic viscosity. Supplementary cementitious materials (SCM) can be useful for this adjustment in addition to their other advantages. In this study, the rheological properties of 57 SCC mixtures with various SCM were investigated for a constant slump flow value. For this aim, various amounts of silica fume (SF), metakao...

3D-printed lightweight drones

DEFF Research Database (Denmark)

Geiger, Raphael

2018-01-01

New Materials within additive manufacturing offer new potentials for drone production - especially in lightweight design. Flying drones benefit significantly from this developments. In regards to quality assurance the technical challenge is to offer a complete quality control within production. T...

Feasibility Study on Manufacturing Lightweight Aggregates from Water Purification Sludge

Science.gov (United States)

Peng, Ching-Fang; Chen, How-Ji

2018-02-01

This study mainly discussed the feasibility of manufacturing lightweight aggregates from water purification sludge in Taiwan. They were analysed for the physical and chemical composition before the sintering test for lightweight aggregates in a laboratory. Then the physical and mechanical properties of the synthesized aggregates were assessed. The result showed that the chemical composition of sludge in the water purification plants was within the appropriate range for manufacturing lightweight aggregate as proposed in the literature. The sintering test demonstrated that the particle density of aggregates from the ten types of water purification sludge were mostly less than 1.8 g/cm3. In addition, the dry unit weight, the organic impurity, the ignition loss, and other characteristics of synthesized aggregates met the requirement of CNS standards, while its water absorption and crushing strength also fulfilled the general commercial specifications. Therefore, reclamation of water purification sludge for production of lightweight aggregate is indeed feasible.

Utilization of red mud and Pb/Zn smelter waste for the synthesis of a red mud-based cementitious material.

Science.gov (United States)

Li, Yuan-Cheng; Min, Xiao-Bo; Ke, Yong; Chai, Li-Yuan; Shi, Mei-Qing; Tang, Chong-Jian; Wang, Qing-Wei; Liang, Yan-Jie; Lei, Jie; Liu, De-Gang

2018-02-15

A new method in which Pb/Zn smelter waste containing arsenic and heavy metals (arsenic sludge), red mud and lime are utilized to prepare red mud-based cementitious material (RCM) is proposed in this study. XRD, SEM, FTIR and unconfined compressive strength (UCS) tests were employed to assess the physicochemical properties of RCM. In addition, ettringite and iron oxide-containing ettringite were used to study the hydration mechanism of RCM. The results show that the UCS of the RCM (red mud+arsenic sludge+lime) was higher than that of the binder (red mud+arsenic sludge). When the mass ratio of m (binder): m (lime) was 94:6 and then maintained 28days at ambient temperature, the UCS reached 12.05MPa. The red mud has potential cementitious characteristics, and the major source of those characteristics was the aluminium oxide. In the red mud-arsenic sludge-lime system, aluminium oxide was effectively activated by lime and gypsum to form complex hydration products. Some of the aluminium in ettringite was replaced by iron to form calcium sulfoferrite hydrate. The BCR and leaching toxicity results show that the leaching concentration was strongly dependent on the chemical speciation of arsenic and the hydration products. Therefore, the investigated red mud and arsenic sludge can be successfully utilized in cement composites to create a red mud-based cementitious material. Copyright © 2017 Elsevier B.V. All rights reserved.

High Efficency Lightweight Radiators, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — XC Associates proposes to build on prior work to develop and characterize a very high efficiency, lightweight radiator constructed from high thermal conductivity...

Mechanical, Spectroscopic and Micro-structural Characterization of Banana Particulate Reinforced PVC Composite as Piping Material

Directory of Open Access Journals (Sweden)

B. Dan-asabe

2016-06-01

Full Text Available A banana particulate reinforced polyvinyl chloride (PVC composite was developed with considerabley low cost materials having an overall light-weight and good mechanical properties for potential application as piping material. The specimen composite material was produced with the banana (stem particulate as reinforcement using compression molding. Results showed that density and elastic Modulus of the composite decreases and increases respectively with increasing weight fraction of the particulate reinforcement. The tensile strength increased to a maximum of 42 MPa and then decreased steadily. The composition with optimum mechanical property (42 MPa was determined at 8, 62 and 30 % formulation of banana stem particulates (reinforcement, PVC (matrix and Kankara clay (filler respectively with corresponding percentage water absorption of 0.79 %, Young’s Modulus of 1.3 GPa, flexural strength of 92 MPa and density of 1.24 g/cm3. Fourier Transform Infrared (FTIR analysis of the constituents showed identical bands within the range 4000–1000 cm-1 with renown research work. Scanning Electron Microscopy (SEM result showed fairly uniform distribution of constituents’ phases. X-Ray Fluorescence (XRF confirms the X-ray diffraction (XRD result of the presence of minerals of kaolinite, quartz, rutile and illite in the kaolin clay. Comparison with conventional piping materials showed the composite offered a price savings per meter length of 84 % and 25 % when compared with carbon steel and PVC material.

Laser surface forming of AlCoCrCuFeNi particle reinforced AZ91D matrix composites

Science.gov (United States)

Meng, Guanghui; Yue, T. M.; Lin, Xin; Yang, Haiou; Xie, Hui; Ding, Xu

2015-07-01

Traditionally, the laser melt injection (LMI) technique can only be used for forming ceramic particles reinforced metal matrix composites (MMCs) for enhancing surface properties of lightweight engineering materials. In this research, the LMI method was employed to form metal particles reinforced MMCs on AZ91D instead. This was viable because of the unique properties of the AlCoCrCuFeNi high-entropy alloy (HEA) metal particles used. The large difference in melting point between the HEA and the substrate material (AZ91D), and the limited reaction and the lack of fusion between the HEA and Mg have made it possible that a metal particles reinforced AZ91D composite material was produced. The reason of limited reaction was considered mainly due to the relatively high mixing enthalpy between the HEA constituent elements and Mg. Although there was some melting occurred at the particles surface with some solute segregation found in the vicinity close to the surface, intermetallic compounds were not observed. With regard to the wear resistance of the MMCs, it was found that when the volume fraction of the reinforcement phase, i.e. the HEA particles, reached about 0.4, the wear volume loss of the coating was only one-seventh of that of the substrate material.

Lightweighting Impacts on Fuel Economy, Cost, and Component Losses

Energy Technology Data Exchange (ETDEWEB)

Brooker, A. D.; Ward, J.; Wang, L.

2013-01-01

The Future Automotive Systems Technology Simulator (FASTSim) is the U.S. Department of Energy's high-level vehicle powertrain model developed at the National Renewable Energy Laboratory. It uses a time versus speed drive cycle to estimate the powertrain forces required to meet the cycle. It simulates the major vehicle powertrain components and their losses. It includes a cost model based on component sizing and fuel prices. FASTSim simulated different levels of lightweighting for four different powertrains: a conventional gasoline engine vehicle, a hybrid electric vehicle (HEV), a plug-in hybrid electric vehicle (PHEV), and a battery electric vehicle (EV). Weight reductions impacted the conventional vehicle's efficiency more than the HEV, PHEV and EV. Although lightweighting impacted the advanced vehicles' efficiency less, it reduced component cost and overall costs more. The PHEV and EV are less cost effective than the conventional vehicle and HEV using current battery costs. Assuming the DOE's battery cost target of $100/kWh, however, the PHEV attained similar cost and lightweighting benefits. Generally, lightweighting was cost effective when it costs less than $6/kg of mass eliminated.

Reducing CO2 Emissions through Lightweight Design and Manufacturing

Science.gov (United States)

Carruth, Mark A.; Allwood, Julian M.; Milford, Rachel L.

2011-05-01

To meet targeted 50% reductions in industrial CO2 emissions by 2050, demand for steel and aluminium must be cut. Many steel and aluminium products include redundant material, and the manufacturing routes to produce them use more material than is necessary. Lightweight design and optimized manufacturing processes offer a means of demand reduction, whilst creating products to perform the same service as existing ones. This paper examines two strategies for demand reduction: lightweight product design; and minimizing yield losses through the product supply chain. Possible mass savings are estimated for specific case-studies on metal-intensive products, such as I-beams and food cans. These estimates are then extrapolated to other sectors to produce a global estimate for possible demand reductions. Results show that lightweight product design may offer potential mass savings of up to 30% for some products, whilst yield in the production of others could be improved by over 20%. If these two strategies could be combined for all products, global demand for steel and aluminium would be reduced by nearly 50%. The impact of demand reduction on CO2 emissions is presented, and barriers to the adoption of new, lightweight technologies are discussed.

Cement technology for borehole plugging: an interim report on permeability measurements of cementitious solids

International Nuclear Information System (INIS)

McDaniel, E.W.

1980-01-01

The permeability of borehole plug solids and plug-wall rock junctions is a property of major interest in the Borehole Plugging Program. This report describes the equipment and techniques used to determine the permeabilities of possible borehole plugging materials and presents results from tests on various cementitious solids and plug-rock combinations. The cementitious solids were made from mixtures of cement, sand, salt, fly ash, and water. Three different types of cement and four different fly ashes were used. Permeabilities ranged from a high value of 3 x 10 -4 darcy for a neat cement paste to a low of 5 x 10 -8 darcy for a saltcrete containing 30 wt % sodium chloride. Miniature boreholes were made in the following four different types of rock: Westerly granite, Dresser basalt, Sioux quartzite, and St. Cloud granodiorite. These small holes were plugged with a mix consisting of 23 wt % Type I Portland cement, 20 wt % bituminous fy ash, 43.2 wt % sand, and 13.8 wt % water. After curing for 91 days at ambient temperature, the permeability of the plug-wall rock junctions ranged from 3 x 10 -5 to -8 darcy. Three of the four miniature plugged boreholes exhibited permeabilities of < 10 microdarcys

Desorption isotherms of cementitious materials: study of an accelerated protocol and estimation of RVE

International Nuclear Information System (INIS)

Wu, Qier

2014-01-01

In the framework of French radioactive waste management and storage, the durability evaluation and prediction of concrete structures requires the knowledge of desorption isotherm of concrete. The aim of the present study is to develop an accelerated experimental method to obtain desorption isotherm of cementitious materials more quickly and to estimate the Representative Volume Element (RVE) size related to the desorption isotherm of concrete. In order to ensure that experimental results can be statistically considered representative, a great amount of sliced samples of cementitious materials with three different thicknesses (1 mm, 2 mm and 3 mm) have been de-saturated. The effect of slice thickness and the saturation condition on the mass variation kinetics and the desorption isotherms is analyzed. The influence of the aggregate distribution on the water content and the water saturation degree is also analyzed. A method based on statistical analysis of water content and water saturation degree is proposed to estimate the RVE for water desorption experiment of concrete. The evolution of shrinkage with relative humidity is also followed for each material during the water desorption experiment. A protocol of cycle of rapid desaturation-re-saturation is applied and shows the existence of hysteresis between desorption and adsorption. (author)

A poly-dispersed particle system representation of the porosity for non-saturated cementitious materials

International Nuclear Information System (INIS)

Bary, B.

2006-01-01

In this paper, the porosity of cementitious materials is described in terms of pore size distribution by means of a 3-dimensional overlapping sphere system with poly-dispersivity in size. On the basis of results established by Lu and Torquato [B. Lu, S. Torquato, Nearest-surface distribution functions for poly-dispersed particle systems, Phys. Rev. A 45(8) (1992) 5530-5544] and Torquato [S. Torquato, Random Heterogeneous Media: Microstructure and Macroscopic Properties. Springer-Verlag: New York, 2001] providing relations for nearest-neighbor distribution functions, the volume fraction of pores having a radius larger than a prescribed value is explicitly expressed. By adopting an appropriate size distribution function for the sphere system, it is shown that the pore size distribution of cementitious materials as detected for instance by mercury intrusion porosimetry (MIP), which generally points out several pore classes, can be well approached. On the basis of this porosity representation, the evaluation of the capillary pressure in function of the saturation degree is provided. The model is then applied to the simulation of the saturation degree versus relative humidity adsorption curves. The impact of the pore size distribution, the temperature and the thickness of the adsorbed water layer on these parameters are assessed and analyzed for three model materials having different pore characteristics. (author)

Bench-scale feasibility testing of pulsed-air technology for in-tank mixing of dry cementitious solids with tank liquids and settled solids

International Nuclear Information System (INIS)

Whyatt, G.A.; Hymas, C.R.

1997-09-01

This report documents the results of testing performed to determine the feasibility of using a pulsed-air mixing technology (equipment developed by Pulsair Systems, Inc., Bellevue, WA) to mix cementitious dry solids with supernatant and settled solids within a horizontal tank. The mixing technology is being considered to provide in situ stabilization of the open-quotes Vclose quotes tanks at the Idaho National Engineering and Environmental Laboratory (INEEL). The testing was performed in a vessel roughly 1/6 the scale of the INEEL tanks. The tests used a fine soil to simulate settled solids and water to simulate tank supernatants. The cementitious dry materials consisted of Portland cement and Aquaset-2H (a product of Fluid Tech Inc. consisting of clay and Portland cement). Two scoping tests were conducted to allow suitable mixing parameters to be selected. The scoping tests used only visual observations during grout disassembly to assess mixing performance. After the scoping tests indicated the approach may be feasible, an additional two mixing tests were conducted. In addition to visual observations during disassembly of the solidified grout, these tests included addition of chemical tracers and chemical analysis of samples to determine the degree of mixing uniformity achieved. The final two mixing tests demonstrated that the pulsed-air mixing technique is capable of producing slurries containing substantially more cementitious dry solids than indicated by the formulations suggested by INEEL staff. Including additional cement in the formulation may have benefits in terms of increasing mobilization of solids, reducing water separation during curing, and increasing the strength of the solidified product. During addition to the tank, the cementitious solids had a tendency to form clumps which broke down with continued mixing

Acoustic Modeling of Lightweight Structures: A Literature Review

Science.gov (United States)

Yang, Shasha; Shen, Cheng

2017-10-01

This paper gives an overview of acoustic modeling for three kinds of typical lightweight structures including double-leaf plate system, stiffened single (or double) plate and porous material. Classical models are citied to provide frame work of theoretical modeling for acoustic property of lightweight structures; important research advances derived by our research group and other authors are introduced to describe the current state of art for acoustic research. Finally, remaining problems and future research directions are concluded and prospected briefly

Wet-Treated MSWI Fly Ash Used as Supplementary Cementitious Material

Directory of Open Access Journals (Sweden)

Martin Keppert

2015-01-01

Full Text Available Municipal solid waste incineration (MSWI is a common technique in treatment of domestic waste. This technique annually produces approximately 25 Mt solid residues (i.e., bottom and fly ash worldwide which is also a major issue in current research. In this research we are concerned with reusing the fly ash (FA as supplementary cementitious material (SCM in concrete. Such application solves the problem with heavy metal immobilization as well. To remove the high content of undesired soluble salts, number of washing treatments has been applied. Chemical composition of FA has been examined before and after treatments. The impact of cement substitution by FA in concrete was evaluated by measurement of its compressive strength and durability.

Cost-Effective Cementitious Material Compatible with Yucca Mountain Repository Geochemistry

Energy Technology Data Exchange (ETDEWEB)

Dole, LR

2004-12-17

The current plans for the Yucca Mountain (YM) repository project (YMP) use steel structures to stabilize the disposal drifts and connecting tunnels that are collectively over 100 kilometers in length. The potential exist to reduce the underground construction cost by 100s of millions of dollars and improve the repository's performance. These economic and engineering goals can be achieved by using the appropriate cementitious materials to build out these tunnels. This report describes the required properties of YM compatible cements and reviews the literature that proves the efficacy of this approach. This report also describes a comprehensive program to develop and test materials for a suite of underground construction technologies.

Cementitious waste option scoping study report

International Nuclear Information System (INIS)

Lee, A.E.; Taylor, D.D.

1998-02-01

A Settlement Agreement between the Department of Energy (DOE) and the State of Idaho mandates that all high-level radioactive waste (HLW) now stored at the Idaho Chemical Processing Plant (ICPP) on the Idaho National Engineering and Environmental Laboratory (INEEL) will be treated so that it is ready to be moved out of Idaho for disposal by a target date of 2035. This study investigates the nonseparations Cementitious Waste Option (CWO) as a means to achieve this goal. Under this option all liquid sodium-bearing waste (SBW) and existing HLW calcine would be recalcined with sucrose, grouted, canisterized, and interim stored as a mixed-HLW for eventual preparation and shipment off-Site for disposal. The CWO waste would be transported to a Greater Confinement Disposal Facility (GCDF) located in the southwestern desert of the US on the Nevada Test Site (NTS). All transport preparation, shipment, and disposal facility activities are beyond the scope of this study. CWO waste processing, packaging, and interim storage would occur over a 5-year period between 2013 and 2017. Waste transport and disposal would occur during the same time period

Cementitious waste option scoping study report

Energy Technology Data Exchange (ETDEWEB)

Lee, A.E.; Taylor, D.D.

1998-02-01

A Settlement Agreement between the Department of Energy (DOE) and the State of Idaho mandates that all high-level radioactive waste (HLW) now stored at the Idaho Chemical Processing Plant (ICPP) on the Idaho National Engineering and Environmental Laboratory (INEEL) will be treated so that it is ready to be moved out of Idaho for disposal by a target date of 2035. This study investigates the nonseparations Cementitious Waste Option (CWO) as a means to achieve this goal. Under this option all liquid sodium-bearing waste (SBW) and existing HLW calcine would be recalcined with sucrose, grouted, canisterized, and interim stored as a mixed-HLW for eventual preparation and shipment off-Site for disposal. The CWO waste would be transported to a Greater Confinement Disposal Facility (GCDF) located in the southwestern desert of the US on the Nevada Test Site (NTS). All transport preparation, shipment, and disposal facility activities are beyond the scope of this study. CWO waste processing, packaging, and interim storage would occur over a 5-year period between 2013 and 2017. Waste transport and disposal would occur during the same time period.

Acoustic Emission Monitoring of Cementitious Wasteforms

International Nuclear Information System (INIS)

Spasova, L.M.; Ojovan, M.I.

2013-01-01

A summary is presented of the potential of non-destructive acoustic emission (AE) method to be applied for structures immobilising nuclear wastes. The use and limitations of the method are discussed with given examples of experimental configurations and results obtained from AE monitoring and data analysis of two different processes addressing particular issues related to the nuclear waste immobilisation. These are (a) corrosion of aluminium, classified as intermediate level waste (ILW) in the UK, encapsulated in cementitious structures and (b) partial melting and solidification during cooling of granite at a pressure of 0.15 GPa which simulates the conditions in a deep borehole disposal of canisters of vitrified high level waste (HLW). Methodology for analysis of the collected data and characterisation of the potential AE sources is performed at different steps including simple signals count and more complex signal parameter-based approach and advanced signal processing. The AE method has been shown as a potential tool for monitoring and inspection of structures immobilising nuclear wastes in relation to the time progress of different interactions of the waste with the encapsulating matrix or the wasteform with the hosting environment for permanent disposal. (author)

EFFECTS OF LIGHTWEIGHT MULLITE-SILICA RICH GLASS COMPOSITE AGGREGATES ON PROPERTIES OF CASTABLES

Directory of Open Access Journals (Sweden)

Li Y.

2013-09-01

Full Text Available Mullite-silica rich glass (MSRG composite is a material which is more efficient than chamotte for refractory utilization of clay. The effects of lightweight MSRG composite aggregate on the properties of refractory castables were studied by XRD, SEM and EDS, etc. Comparing with a common lightweight chamotte aggregate, it was found that the hot modulus of rupture, refractoriness under load and thermal shock resistance of the castable with lightweight MSRG aggregate were higher than those of the castable with a common lightweight chamotte aggregate because MSRG did not contain silica crystalline phases and contained a liquid phase with very high viscosity at high temperature. The castables with lightweight chamotte aggregate have higher thermal expansion because of existence of cristobalite and quartz, and have lower thermal conductivity because of higher porosity.

Spongent: A lightweight hash function

DEFF Research Database (Denmark)

Bogdanov, Andrey; Knežević, Miroslav; Leander, Gregor

2011-01-01

This paper proposes spongent - a family of lightweight hash functions with hash sizes of 88 (for preimage resistance only), 128, 160, 224, and 256 bits based on a sponge construction instantiated with a present-type permutation, following the hermetic sponge strategy. Its smallest implementations...

A New Ultra-lightweight Authentication Protocol for Low Cost RFID Tags

Directory of Open Access Journals (Sweden)

Xin Wang

2013-05-01

Full Text Available The Radio Frequency Identification (RFID system has been widely used in almost every aspects of the society. At present, the problem of security and privacy become a key factor of severely blocking the widespread of its usage. However, due to restraints on RFID tag’s manufacturing cost, the traditional methods of encryption are not good candidate to defend the security of wireless communication channel between reader and tag. Designing lightweight or ultra-lightweight RFID authentication protocol has become a hot research topic recently. This paper proposes a new ultra-lightweight RFID authentication protocol with high robustness and execution efficiency. The proposed protocol requires only simple bit-wise operations, it has the characteristics of low storage requirement and communication cost. At the same time, through elaborate mechanism design, avoid the vulnerability of the existing ultra-lightweight authentication protocols.

Innovation in use and research on cementitious material

International Nuclear Information System (INIS)

Scrivener, Karen L.; Kirkpatrick, R. James

2008-01-01

In this paper we discuss innovations in concrete technology which are currently being applied in the field-namely high and ultra high performance (strength), and self consolidating concrete. We discuss the factors which have enabled these developments and ongoing needs in these areas. The importance of sustainability as the major driver for future innovations and prospects for development of new cementitious materials with lower environmental impact is briefly discussed. Finally the importance of innovation in research is examined. The dramatic development in experimental and computational techniques over recent years opens up wide-ranging possibilities for understanding the micro- and nano- scale chemical and physical processes which underlie performance at a macroscopic level. The example of computational approaches at the atomic and molecular scale is presented in detail. In order to exploit the opportunities presented by such new techniques, there needs to be greater efforts to structure interdisciplinary, multi-group research

Cementitious Stabilization of Mixed Wastes with High Salt Loadings

International Nuclear Information System (INIS)

Spence, R.D.; Burgess, M.W.; Fedorov, V.V.; Downing, D.J.

1999-01-01

Salt loadings approaching 50 wt % were tolerated in cementitious waste forms that still met leach and strength criteria, addressing a Technology Deficiency of low salt loadings previously identified by the Mixed Waste Focus Area. A statistical design quantified the effect of different stabilizing ingredients and salt loading on performance at lower loadings, allowing selection of the more effective ingredients for studying the higher salt loadings. In general, the final waste form needed to consist of 25 wt % of the dry stabilizing ingredients to meet the criteria used and 25 wt % water to form a workable paste, leaving 50 wt % for waste solids. The salt loading depends on the salt content of the waste solids but could be as high as 50 wt % if all the waste solids are salt

Determination of Chloride Content in Cementitious Materials : From Fundamental Aspects to Application of Ag/AgCl Chloride Sensors

NARCIS (Netherlands)

Pargar, F.; Koleva, D.A.; van Breugel, K.

2017-01-01

This paper reports on the advantages and drawbacks of available test methods for the determination of chloride content in cementitious materials in general, and the application of Ag/AgCl chloride sensors in particular. The main factors that affect the reliability of a chloride sensor are presented.

Lightweight panel study 2012: Perceptions and usage by North American wood products manufacturers

Science.gov (United States)

Urs Buehlmann; Matt Bumgardner; Karl D. Forth

2012-01-01

Lightweight panels (panels made of two thin panels on the outside and a lightweight material in the core) can offer enhanced performance, reduced material use, and new design opportunities over traditional types of panels. Opportunities exist for the adoption of lightweight panels by the secondary wood industry in North America, as 62 percent of respondents to a recent...

Lightweight Brick by Carbon Ash from The Mixed Plastic Waste Treatment Plant

OpenAIRE

Chen Kuo-Wei

2016-01-01

This study was designed to investigate the mixed plastic waste from the production of light carbon ash bricks performance. The mixed waste plastic pyrolysis process generated waste - Carbon ash. After extrusion, a Lightweight brick was made by carbon ash, additive and Cement mortar. In general, the set compressive strength and insulation effect of lightweight bricks with carbon ash proportion for significant impact. The set water absorption and thermal conductivity of lightweight bricks with ...

Southern Regional Center for Lightweight Innovative Design

Energy Technology Data Exchange (ETDEWEB)

Wang, Paul T. [Mississippi State Univ., Mississippi State, MS (United States)

2012-12-01

The Southern Regional Center for Lightweight Innovative Design (SRCLID) has developed an experimentally validated cradle-to-grave modeling and simulation effort to optimize automotive components in order to decrease weight and cost, yet increase performance and safety in crash scenarios. In summary, the three major objectives of this project are accomplished: To develop experimentally validated cradle-to-grave modeling and simulation tools to optimize automotive and truck components for lightweighting materials (aluminum, steel, and Mg alloys and polymer-based composites) with consideration of uncertainty to decrease weight and cost, yet increase the performance and safety in impact scenarios; To develop multiscale computational models that quantify microstructure-property relations by evaluating various length scales, from the atomic through component levels, for each step of the manufacturing process for vehicles; and To develop an integrated K-12 educational program to educate students on lightweighting designs and impact scenarios. In this final report, we divided the content into two parts: the first part contains the development of building blocks for the project, including materials and process models, process-structure-property (PSP) relationship, and experimental validation capabilities; the second part presents the demonstration task for Mg front-end work associated with USAMP projects.

Titanium Nanocomposite: Lightweight Multifunction Structural Material

Data.gov (United States)

National Aeronautics and Space Administration — We propose to research and develop lightweight metal matrix nanocomposites (MMnC) using a Titanium (Ti) metal matrix. Ti MMnC will crosscut the advancement of both...

Lightweight enterprise architectures

CERN Document Server

Theuerkorn, Fenix

2004-01-01

STATE OF ARCHITECTUREArchitectural ChaosRelation of Technology and Architecture The Many Faces of Architecture The Scope of Enterprise Architecture The Need for Enterprise ArchitectureThe History of Architecture The Current Environment Standardization Barriers The Need for Lightweight Architecture in the EnterpriseThe Cost of TechnologyThe Benefits of Enterprise Architecture The Domains of Architecture The Gap between Business and ITWhere Does LEA Fit? LEA's FrameworkFrameworks, Methodologies, and Approaches The Framework of LEATypes of Methodologies Types of ApproachesActual System Environmen

Southern Regional Center for Lightweight Innovative Design

Energy Technology Data Exchange (ETDEWEB)

Horstemeyer, Mark F. [Mississippi State Univ., Mississippi State, MS (United States); Wang, Paul [Mississippi State Univ., Mississippi State, MS (United States)

2011-12-27

The three major objectives of this Phase III project are: To develop experimentally validated cradle-to-grave modeling and simulation tools to optimize automotive and truck components for lightweighting materials (aluminum, steel, and Mg alloys and polymer-based composites) with consideration of uncertainty to decrease weight and cost, yet increase the performance and safety in impact scenarios; To develop multiscale computational models that quantify microstructure-property relations by evaluating various length scales, from the atomic through component levels, for each step of the manufacturing process for vehicles; and To develop an integrated K-12 educational program to educate students on lightweighting designs and impact scenarios.

Lightweight Space Tug body structure

International Nuclear Information System (INIS)

Lager, J.R.

1976-01-01

Lightweight honeycomb sandwich construction using a wide variety of metal and fibrous composite faceskins was used in the design of a typical Space Tug skirt structure. Relatively low magnitude combined loading of axial compression and torsion resulted in designs using ultrathin faceskins, light-weight honeycomb cores, and thin faceskin/core adhesive bond layers. Two of the designs with metal faceskins (aluminum and titanium) and four with fibrous composite faceskins (using combinations of fiberglass, boron, and graphite) were evaluated through the fabrication and structural test of a series of small development panels. The two most promising concepts with aluminum and graphite/epoxy faceskins, were further evaluated through the fabrication and structural test of larger compression and shear panels. All panels tested exceeded design ultimate load levels, thereby, verifying the structural integrity of the selected designs. Projected skirt structural weights for the graphite/epoxy and aluminum concepts fall within original weight guidelines established for the Space Tug vehicle

Development of lightweight mortars targeted on the high strength, low density and low permeability

NARCIS (Netherlands)

Spiesz, P.R.; Yu, Q.; Brouwers, H.J.H.; Uzoegbo, H.C.; Schmidt, W.

2013-01-01

This article presents a mix design methodology for the development of cement-based lightweight mortars. Expanded-glass lightweight aggregates were used in this study as the lightweight material. The mix design was developed applying the packing theory using the modified Andreasen and Andersen model

46 CFR 170.200 - Estimated lightweight vertical center of gravity.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Estimated lightweight vertical center of gravity. 170... Centers of Gravity § 170.200 Estimated lightweight vertical center of gravity. (a) Each tank vessel that... calculations required by §§ 170.170 and 172.065, the vertical center of gravity of a tank vessel in the...

The Cementitious Barriers Partnership Experimental Programs and Software Advancing DOE’s Waste Disposal/Tank Closure Efforts – 15436

Energy Technology Data Exchange (ETDEWEB)

Burns, Heather [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Flach, Greg [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Smith, Frank [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Langton, Christine [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Brown, Kevin [Vanderbilt Univ./CRESP, Nashville, TN (United States); Kosson, David [Vanderbilt Univ./CRESP, Nashville, TN (United States); Samson, Eric [SIMCO Technologies, Inc. (United States); Mallick, Pramod [US DOE, Washington, DC (United States)

2015-01-27

The U.S. Department of Energy Environmental Management (DOE-EM) Office of Tank Waste Management-sponsored Cementitious Barriers Partnership (CBP) is chartered with providing the technical basis for implementing cement-based waste forms and radioactive waste containment structures for long-term disposal. DOE needs in this area include the following to support progress in final treatment and disposal of legacy waste and closure of High-Level Waste (HLW) tanks in the DOE complex: long-term performance predictions, flow sheet development and flow sheet enhancements, and conceptual designs for new disposal facilities. The DOE-EM Cementitious Barriers Partnership is producing software and experimental programs resulting in new methods and data needed for end-users involved with environmental cleanup and waste disposal. Both the modeling tools and the experimental data have already benefited the DOE sites in the areas of performance assessments by increasing confidence backed up with modeling support, leaching methods, and transport properties developed for actual DOE materials. In 2014, the CBP Partnership released the CBP Software Toolbox –“Version 2.0” which provides concrete degradation models for 1) sulfate attack, 2) carbonation, and 3) chloride initiated rebar corrosion, and includes constituent leaching. These models are applicable and can be used by both DOE and the Nuclear Regulatory Commission (NRC) for service life and long-term performance evaluations and predictions of nuclear and radioactive waste containment structures across the DOE complex, including future SRS Saltstone and HLW tank performance assessments and special analyses, Hanford site HLW tank closure projects and other projects in which cementitious barriers are required, the Advanced Simulation Capability for Environmental Management (ASCEM) project which requires source terms from cementitious containment structures as input to their flow simulations, regulatory reviews of DOE performance

Round robin test for define an accurate protocol to measure the pore fluid pH of low-pH cementitious materials

International Nuclear Information System (INIS)

Alonso, M.C.; Garcia Calvo, J.L.; Pettersson, S.; Puigdomenech, I.; Cunado, M.A.; Vuorio, M.; Weber, H.; Ueda, H.; Naito, M.; Walker, C.; Takeshi, Y.; Cau Dit Coumes, C.

2012-01-01

The present research belongs to an international project where several of the main nuclear waste management agencies have been involved. The main objective is the development of agreed procedures or protocols for measuring the pH value using low-pH cementitious products (LopHC). The Pore Fluid Expression (PFE) has been identified as reference method and Ex-situ Leaching methods (ELS) with two variants (filtering and without filtering the obtained suspension) have been identified as routine methods. Both methodologies are based on the extraction of the pore solution of the concrete before pH determination. The protocols employed were based on a broad literature review and in fitting the more critical parameters, such as the sample size, the carbonation affection, the leaching of cement hydrates during the measurement, etc. Moreover, the routine methods were validated with respect to the pore fluid expression results. It appears that the repeatability of the 3 pH measurement protocols is very good and that the results obtained with both ESL procedures agree well with the results given by the PFE technique in the case of low-pH cementitious materials and are acceptable in the case of cementitious materials with high pore fluid pH values, in that case some corrections considering the Ca content of the solution may be needed

Production of NbC reinforced aluminum matrix composites by mechanical alloying

International Nuclear Information System (INIS)

Silva, Marina Judice; Cardoso, Katia Regina; Travessa, Dilermando Nagle

2014-01-01

Aluminum and their alloys are key materials for the automotive and aerospace industries. The dispersion of hard ceramic particles in the Al soft matrix produces lightweight composites with interesting properties, as environmental resistance, high specific strength and stiffness, high thermal and electrical conductivity, and good wear resistance, encouraging their technological use. Powder metallurgy techniques like mechanical alloying (MA) are very attractive to design metal matrix composites, as they are able to achieve a homogeneous distribution of well dispersed particles inside the metal matrix. In this work, pure aluminum has been reinforced with particles of Niobium carbide (NbC), an extremely hard and stable refractory ceramic. NbC is frequently used as a grain growth inhibitor in micro-alloyed steel due to their low solubility in austenite. In the present work, NbC is expected to act as a reinforcing phase by its fine dispersion into the aluminum matrix, produced by MA. Composite powders produced after different milling times (up to 50h), with 10 and 20% (volume) of NbC were characterized by diffraction laser particle size analysis, scanning electron microscopy (SEM) and by X-ray diffraction (DRX), in order to establish a relationship between the milling time and the characteristics of the powder produced, as size and morphology, crystallite size and reinforcement distribution. This characterization is important in defining the MA process for production of composites for further consolidation by hot extrusion process. (author)

Production of NbC reinforced aluminum matrix composites by mechanical alloying

Energy Technology Data Exchange (ETDEWEB)

Silva, Marina Judice; Cardoso, Katia Regina; Travessa, Dilermando Nagle, E-mail: dilermando.travessa@unifesp.br [Universidade Federal de Sao Paulo (UNIFESP), Sao Jose dos Campos, SP (Brazil). Instituto de Ciencia e Tecnologia

2014-07-01

Aluminum and their alloys are key materials for the automotive and aerospace industries. The dispersion of hard ceramic particles in the Al soft matrix produces lightweight composites with interesting properties, as environmental resistance, high specific strength and stiffness, high thermal and electrical conductivity, and good wear resistance, encouraging their technological use. Powder metallurgy techniques like mechanical alloying (MA) are very attractive to design metal matrix composites, as they are able to achieve a homogeneous distribution of well dispersed particles inside the metal matrix. In this work, pure aluminum has been reinforced with particles of Niobium carbide (NbC), an extremely hard and stable refractory ceramic. NbC is frequently used as a grain growth inhibitor in micro-alloyed steel due to their low solubility in austenite. In the present work, NbC is expected to act as a reinforcing phase by its fine dispersion into the aluminum matrix, produced by MA. Composite powders produced after different milling times (up to 50h), with 10 and 20% (volume) of NbC were characterized by diffraction laser particle size analysis, scanning electron microscopy (SEM) and by X-ray diffraction (DRX), in order to establish a relationship between the milling time and the characteristics of the powder produced, as size and morphology, crystallite size and reinforcement distribution. This characterization is important in defining the MA process for production of composites for further consolidation by hot extrusion process. (author)

Lightweight Brick by Carbon Ash from The Mixed Plastic Waste Treatment Plant

Directory of Open Access Journals (Sweden)

Chen Kuo-Wei

2016-01-01

Full Text Available This study was designed to investigate the mixed plastic waste from the production of light carbon ash bricks performance. The mixed waste plastic pyrolysis process generated waste - Carbon ash. After extrusion, a Lightweight brick was made by carbon ash, additive and Cement mortar. In general, the set compressive strength and insulation effect of lightweight bricks with carbon ash proportion for significant impact. The set water absorption and thermal conductivity of lightweight bricks with carbon ash proportion for significant impact. The set density of lightweight brick ameliorates with M3824 additive and CM3 cement mortar for significant impact. Under conditions of technology and economic, the results of this study as reference for market-oriented marketing and commercialization of production.

Incorporation mode effect of Nano-silica on the rheological and mechanical properties of cementitious pastes and cement mortars

Science.gov (United States)

Safi, B.; Aknouche, H.; Mechakra, H.; Aboutaleb, D.; Bouali, K.

2018-04-01

Previous research indicates that the inclusion of nanosilica (NS) modifies the properties of the fresh and hardened state, compared to the traditional mineral additions. NS decreases the setting times of the cement mortar compared to silica fume (SF) and reduce of required water while improving the cohesion of the mixtures in the fresh state. Some authors estimate that the appropriate percentage of Nano-silica should be small (1 to 5% by weight) because of difficulties caused by agglomeration to particles during mixing, while others indicate that 10% by weight, if adjustments are made to the formulation to avoid an excess of self-drying and micro cracks that could impede strength. For this purpose, the present work aim to see the effect of the introduction mode of the nanosilica on the rheological and physic mechanical properties of cement mortars. In this study, NS was used either powdered with cement or in solution with the superplasticizer (Superplasticizer doped in nanosilica). Results show that the use of nanosilica powder (replacing cement on the one hand) has a negative influence on the rheological parameters and the rheological behavior of cementitious pastes. However, the introduction of nanosilica in solution in the superplasticizer (SP) was significantly improved the rheological parameters and the rheological behavior of cementitious pastes. Indeed, more the dosage of NS-doped SP increases more the shear stress and viscosities of the cementitious pastes become more fluid and manageable. A significant reduction of shear stress and plastic viscosity were observed that due to the increase in superplasticizer. A dosage of 1.5% NS-doped SP gave adequate fluidity and the shear rate was lower.

Analytical Model for the Probability Characteristics of a Crack Penetrating Capsules in Capsule-Based Self-Healing Cementitious Materials

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Zhong LV

2017-08-01

Full Text Available Autonomous crack healing using pre-embedded capsules containing healing agent is becoming a promising approach to restore the strength of damaged structures. In addition to the material properties, the size and volume fraction of capsules influence crack healing in the matrix. Understanding the crack and capsule interaction is critical in the development and design of structures made of capsule-based self-healing materials. Continuing our previous study, in this contribution a more practical rupturing mode of capsules characterizing the rupturing manner of capsules fractured by cracks in cementitious materials is presented, i.e., penetrating mode. With the underlying assumption that a crack penetrating capsules undoubtedly leads to crack healing, geometrical probability theory is employed to develop the quantitative relationship between crack size and capsule size, capsule concentration in capsule-based self-healing virtual cementitious material. Moreover, an analytical expression of probability of a crack penetrating with randomly dispersed capsules is developed in two-dimensional material matrix setup. The influences of the induced rupturing modes of capsules embedded on the self-healing efficiency are analyzed. Much attention is paid to compare the penetrating probability and the hitting probability, in order to assist the designer to make a choice of the optimal rupturing modes of capsules embedded. The accuracy of results of the theoretical model is also compared with Monte-Carlo numerical analysis of crack interacting with capsules. It shows that the developed probability characteristics of a crack interaction with capsules for different rupturing modes is helpful to provide guidelines for designer working with capsule-based self-healing cementitious materials.DOI: http://dx.doi.org/10.5755/j01.ms.23.3.16888

Cementitious stabilization of chromium, arsenic, and selenium in a cooling tower sludge

International Nuclear Information System (INIS)

Spence, R.D.; Gilliam, T.M.; Bleier, A.

1995-01-01

The Federal Facility Compliance Agreement (FFCA) establishes an aggressive schedule for conducting studies and treatment method development under the treatability exclusion of RCRA for those mixed wastes for which treatment methods and capabilities have yet to be defined. One of these wastes is a radioactive cooling tower sludge. This paper presents some results of a treatability study of the stabilization of this cooling tower sludge in cementitious waste forms. The sample of the cooling tower sludge obtained for this study was found to be not characteristically hazardous in regard to arsenic, barium, chromium, lead, and selenium, despite the waste codes associated with this waste. However, the scope of this study included spiking three RCRA metals to two orders of magnitude above the initial concentration to test the limits of cementitious stabilization. Chromium and arsenic were spiked at concentrations of 200, 2,000, and 20,000 mg/kg, and selenium was spiked at 100, 1,000, and 10,000 mg/kg (concentrations based on the metal in the sludge solids). Portland cement, Class F fly ash, and slag were selected as stabilizing agents in the present study. Perlite, a fine, porous volcanic rock commonly used as a filter aid, was used as a water-sorptive agent in this study in order to control bleed water for high water contents. The highly porous perlite dust absorbs large amounts of water by capillary action and does not present the handling and processing problems exhibited by clays used for bleed water control

Utilization of Construction Waste Composite Powder Materials as Cementitious Materials in Small-Scale Prefabricated Concrete

OpenAIRE

Cuizhen Xue; Aiqin Shen; Yinchuan Guo; Tianqin He

2016-01-01

The construction and demolition wastes have increased rapidly due to the prosperity of infrastructure construction. For the sake of effectively reusing construction wastes, this paper studied the potential use of construction waste composite powder material (CWCPM) as cementitious materials in small-scale prefabricated concretes. Three types of such concretes, namely, C20, C25, and C30, were selected to investigate the influences of CWCPM on their working performances, mechanical properties, ...

Reinforcement of cement-based matrices with graphite nanomaterials

Science.gov (United States)

Sadiq, Muhammad Maqbool

micro-scale fibers were used for comparison purposes at different volume fractions. Replicated mixes and tests were considered to provide the basis for statistically reliable inferences. Theoretical studies were conducted in order to develop insight into the reinforcement mechanisms of properly functionalized graphite nanomaterials. The results suggested that modified graphite nanomaterials improve the mechanical performance of cement-based matrices primarily through control of microcrack size and propagation, relying on their close spacing within matrix and dissipation of substantial energy by debonding and frictional pullout over their enormous surface areas. The gains in barrier qualities of cement-based materials with introduction of modified graphite nanomaterials could be attributed to the increased tortuosity of diffusion paths in the presence of closely spaced nanomaterials. Experimental investigations were designed and implemented towards identification of the optimum (nano- and micro-scale) reinforcement systems for high-performance concrete through RSA (Response Surface Analysis). A comprehensive experimental data base was developed on the mechanical, physical and durability characteristics as well as the structure and composition of high-performance cementitious nanocomposites reinforced with modified graphite nanomaterials and/ or different micro-fibers.

New methods to quantify the cracking performance of cementitious systems made with internal curing

Science.gov (United States)

Schlitter, John L.

The use of high performance concretes that utilize low water-cement ratios have been promoted for use in infrastructure based on their potential to increase durability and service life because they are stronger and less porous. Unfortunately, these benefits are not always realized due to the susceptibility of high performance concrete to undergo early age cracking caused by shrinkage. This problem is widespread and effects federal, state, and local budgets that must maintain or replace deterioration caused by cracking. As a result, methods to reduce or eliminate early age shrinkage cracking have been investigated. Internal curing is one such method in which a prewetted lightweight sand is incorporated into the concrete mixture to provide internal water as the concrete cures. This action can significantly reduce or eliminate shrinkage and in some cases causes a beneficial early age expansion. Standard laboratory tests have been developed to quantify the shrinkage cracking potential of concrete. Unfortunately, many of these tests may not be appropriate for use with internally cured mixtures and only provide limited amounts of information. Most standard tests are not designed to capture the expansive behavior of internally cured mixtures. This thesis describes the design and implementation of two new testing devices that overcome the limitations of current standards. The first device discussed in this thesis is called the dual ring. The dual ring is a testing device that quantifies the early age restrained shrinkage performance of cementitious mixtures. The design of the dual ring is based on the current ASTM C 1581-04 standard test which utilizes one steel ring to restrain a cementitious specimen. The dual ring overcomes two important limitations of the standard test. First, the standard single ring test cannot restrain the expansion that takes place at early ages which is not representative of field conditions. The dual ring incorporates a second restraining ring

Literature Review of Shear Performance of Light-weight Steel Framing Wall Panels

Science.gov (United States)

Zhang, Zhuangnan; Liu, Shen; Liu, Hong

2018-03-01

In this paper, a comprehensive review of light-weight steel framing wall panels was carried out. The structure and force characteristics of light-weight steel framing wall panels were introduced. The testing and theoretical research results on the shear behaviour of light-weight steel framing wall panels were summarized in the domestic and foreign. And combined with the existing standards in China, the author's views and ideas are put forward to the problems in the research field of this kind of structural system.

COMBS: open source python library for RVE generation - Application to microscale diffusion simulations in cementitious materials

International Nuclear Information System (INIS)

Bourcier, C.; Laucoin, E.; Dridi, W.; Chomat, L.; Bary, B.; Adam, E.

2013-01-01

In the context of radioactive waste storage and disposal, the knowledge of the concrete diffusivity is primordial in the numerical simulations of the long term behavior of these materials. COMBS is an open source python library, it is used to define the shapes of the inclusions, to insert them in the box featuring the representative volume element (RVE) of the cementitious medium, and to assess their diffusive properties. The algorithms developed in COMBS target a fast placement of the inclusions and a fast generation of the RVE shape and mesh. Two application cases are considered: the unaltered material diffusivity and the degraded material diffusivity. The first case of application focuses on the description of the capillary porosity. The second application case focuses on the description of the degradation of cementitious material (mineral and porosity) and the diffusive properties associated. The reliability of the analytical effective medium approximations (MT and SC) is confirmed from 3D finite elements (FE) calculations performed on a matrix-inclusions microstructure obtained by RVE generation with Combs. The results also show the need to take into account the percolation behavior

Effects of carbonation, irradiation and temperature onto strontium immobilization into a cementitious matrix

International Nuclear Information System (INIS)

Bar-Nes, G.; Arbel-Haddad, M.; Chomat, L.; Poyet, S.; Mace, N.; Hossepied, C.

2015-01-01

In the present study, the decoupled effects of carbonation, irradiation and temperature on strontium immobilization in a CEM-I cement matrix are described. After 6 months of treatment, mineralogical characterization (X-ray diffraction - XRD and thermogravimetric analysis - TGA), leaching tests (according to ANSI.ANS-16.1 standard method) and sorption experiments were carried out. The mineralogical evolution was shown to be similar for samples submitted to irradiation at atmospheric conditions or carbonation at a controlled temperature of 40 C. degrees. The main mineralogical change during these two treatments is the formation of calcium carbonate; calcite is detected at the sample surface and the two carbonate metastable phases (aragonite and vaterite) in the depth of the sample. Although it was not possible to identify, by the techniques used, the association of Sr with any specific cementitious phase present in the investigated samples, the leaching results showed that the fraction of Sr leached from samples exposed to carbonation during their degradation process, was approximately 6 times lower compared to the corresponding samples degraded under inert conditions. The sorption experiments onto the hydrated cement paste show a small but significant retention of Sr in these matrices without allowing a possible identification of the phase responsible for the retention. Post leaching mineralogical characterization is to be performed in order to study the effect of the leaching process on the sample mineralogy and to locate the binding sites of the Sr ions within the cementitious paste. (authors)

The use of spent glauconite in lightweight aggregate production

OpenAIRE

Franus, Wojciech; Franus, Małgorzata; Latosińska, Jolanta; Wójcik, Rafał

2011-01-01

The presented work has shown an application of spent glauconite bed after purification of wastewater for production of lightweight expanded clay aggregates. Sewage, from which it was removed Zn ions, came from technological line (zincworks) of Communication Equipment Factory „PZL” Świdnik. Spent glauconite bed was used as an additive in lightweight aggregate production which was obtained using plastic method by sintering, at temperature 1140 ºC and 1200 ºC, of spent glauconite amouts 10, 15, ...

Some aspects to improve sound insulation prediction models for lightweight elements

NARCIS (Netherlands)

Gerretsen, E.

2007-01-01

The best approach to include lightweight building elements in prediction models for airborne and impact sound insulation between rooms, as in EN 12354, is not yet completely clear. Two aspects are at least of importance, i.e. to derive the sound reduction index R for lightweight elements for

Simulation and Failure Analysis of Car Bumper Made of Pineapple Leaf Fiber Reinforced Composite

Science.gov (United States)

Arbintarso, E. S.; Muslim, M.; Rusianto, T.

2018-02-01

The bumper car made of the Pineapple Leaf Fiber Reinforced Composite (PLFRC) is possible to be produced with the advantage of easy to get, and cheap. Pineapple leaf fiber has chosen as a natural fiber, which the maximum of the strength of 368 MPa. The objective of this study was to determine the maximum capability of front car bumpers using Pineapple Leaf Fiber Reinforced Composite materials through the process of simulating stress analysis with Solidworks 2014 software. The aim also to know the distribution of loads that occur on the front car bumper and predict the critical point position on the design of the bumper. The result will use to develop the alternative lightweight, cheap and environmentally friendly materials in general and the development of the use of pineapple fiber for automotive purposes in particular. Simulations and failure analysis have been conducted and showed an increased impact speed in line with increased displacement, strain, and stress that occur on the surface of the bumper. The bumper can withstand collisions at a speed of less than 70 kph.

Utilization of Local Ingredients for the Production of High-Early-Strength Engineered Cementitious Composites

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Hanwen Deng

2018-01-01

Full Text Available The rapid repair and retrofitting of existing transportation infrastructure requires dimensional stability and ductile repair material that can obtain sufficiently high strength in a few hours to accommodate the large loading and deformation at an early age. Engineering cementitious composites (ECCs is a class representative of the new generation of high-performance fiber-reinforced cement-based composites (HPFRCC with medium fiber content. The unique properties of tremendous ductility and tight multiple crack behavior indicate that ECC can be used as an effective retrofit material. The wide application of this material in China will require the use of all local ingredients. In this study, based on Chinese domestic ingredients, including matrix materials and all fibers, high-early-strength ECC (HES-ECC was designed under the guidance of strain-hardening criterion of ECC. The matrix properties and fiber/matrix interfacial micromechanics properties were obtained from three-point-bending test and single-fiber pullout test. The mechanical properties of HES-ECC were achieved by direct tensile test. The experimental results show that HES-ECC was successfully developed by using all Chinese materials. When using the domestic PVA fiber at 2%, the strength requirement can be achieved but only a low ductility. When using the domestic PE fiber at 0.8%, the strength and deformation requirement both can be obtained. The HES-ECC developed in this study exhibited compressive strength of more than 25 MPa within 6 hours, and an ultimate tensile strength of 5-6 MPa and tensile strain capacity of 3-4% after 60 days. Moreover, the cost of using domestic fiber can be largely reduced compared with using imported fiber, up to 70%; it is beneficial to the promotion of these high-early-strength ECCs in the Chinese market.

From the Palais des Papes in Avignon to the 'Chateau d'eau Perret' at Saclay: study of historical monuments to understand the long term behaviour on metal/concrete interface

International Nuclear Information System (INIS)

L'Hostis, V.; Dillmann, Ph.; Chitty, W.J.; Millard, A.; Faquin, R.

2007-01-01

Corrosion of reinforcement is one of the major causes of concrete cracking and degradation of reinforced concrete structures in atmospheric environments. The life time of several reinforced concrete buildings (civil engineering, nuclear infrastructures, bridges, historical monuments...) depends on the interaction between metallic and cementitious materials. For instance, historical monuments contain an important quantity of iron since the roman period (30 tons for the dungeon of the 'Chateau de Vincennes', 100 tons for the Palais des Papes in Avignon), and play a role in the mechanical behaviour of the building. It is then necessary to determine the degradation state of metallic objects submitted to corrosion and to predict their behaviour with time. In this context, this paper shows how analysis of the metal/cementitious materials interface from a corpus of historical monuments allows to understand the corrosion mechanisms and to model them. Moreover, corrosion rates and products that are characterized can be used as input data for a macroscopic mechanical damage model of reinforced concrete submitted to corrosion of steels. This model is able to predict the cracking pattern of the monument. (authors)

Influence of reinforcement type on the mechanical behavior and fire response of hybrid composites and sandwich structures

Science.gov (United States)

Giancaspro, James William

Lightweight composites and structural sandwich panels are commonly used in marine and aerospace applications. Using carbon, glass, and a host of other high strength fiber types, a broad range of laminate composites and sandwich panels can be developed. Hybrid composites can be constructed by laminating multiple layers of varying fiber types while sandwich panels are manufactured by laminating rigid fiber facings onto a lightweight core. However, the lack of fire resistance of the polymers used for the fabrication remains a very important problem. The research presented in this dissertation deals with an inorganic matrix (Geopolymer) that can be used to manufacture laminate composites and sandwich panels that are resistant up to 1000°C. This dissertation deals with the influence of fiber type on the mechanical behavior and the fire response of hybrid composites and sandwich structures manufactured using this resin. The results are categorized into the following distinct studies. (i) High strength carbon fibers were combined with low cost E-glass fibers to obtain hybrid laminate composites that are both economical and strong. The E-glass fabrics were used as a core while the carbon fibers were placed on the tension face and on both tension and compression faces. (ii) Structural sandwich beams were developed by laminating various types of reinforcement onto the tension and compression faces of balsa wood cores. The flexural behavior of the beams was then analyzed and compared to beams reinforced with organic composite. The effect of core density was evaluated using oak beams reinforced with inorganic composite. (iii) To measure the fire response, balsa wood sandwich panels were manufactured using a thin layer of a fire-resistant paste to serve for fire protection. Seventeen sandwich panels were fabricated and tested to measure the heat release rates and smoke-generating characteristics. The results indicate that Geopolymer can be effectively used to fabricate both

Performance of Reinforced Concrete Beam with Differently Positioned Replacement Zones of Block Infill under Low Impact Loads

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Mokhatar Shahrul Niza

2017-01-01

Full Text Available This paper reveals a study performed on reinforced concrete with artificial aggregate concrete block infill composite beams to innovate a lightweight reinforced concrete utilizing polyethylene (PE waste materials, such as waste plastic bags. Six beam specimens of normal reinforced concrete (NRC and different block infill replacement zone positions RCAI (RZ1 beams containing 100% MAPEA with 50, 95, and 1,000 mm width, height, and length, respectively, were provided for the block infill, whereas RCAI (RZ2 with different block infill positions containing a 100% MAPEA with 50, 115, and 1000 mm width, height, and length were provided and tested under low impact load. The steel impactor with blunt nose dropped at 0.6 m height which equivalent to 3.5 m/s. The behaviors of the beams were studied relative to the impact force-time and displacement-time histories, the flexural/ bending cracks, and the impact failure. Results show that the overall failure modes of all the beam specimens were successfully recorded. In addition, the residual displacements of the RZ2 was almost same than those of the RZ1 and the significantly lower than those of the NRC. In the reinforced concrete beams, less stressed concrete near the neutral axis can be replaced by certain light weight material like waste plastic bags as modified artificial polyethylene aggregates to serve as an artificial aggregate.

Proceedings of the research conference on cementitious composites in decommissioning and waste management (RCWM2017)

International Nuclear Information System (INIS)

Sano, Yuichi; Ashida, Takashi

2017-11-01

Collaborative Laboratories for Advanced Decommissioning Science (CLADS) is responsible to promote international cooperation in the R and D activities on the decommissioning of Fukushima Daiichi Nuclear Power Station and to develop the necessary human resources. CLADS held the Research Conference on Cementitious Composites in Decommissioning and Waste Management (RCWM2017) on 20th and 21st June, 2017. This report compiles the abstracts and the presentation materials in the above conference. (author)

A field trail for sealing abandoned mine shafts and adits with lightweight concrete

International Nuclear Information System (INIS)

Skinner, E.H.; Beckett, L.A.

1994-01-01

An abandoned mine shaft near Omar, in Logan County, WV, was permanently sealed through a cooperative agreement between the West Virginia Department of Commerce, Labor, and Environmental Resources, Division of Environmental Protection, and the US Bureau of Mines (USBM), Abandoned Mine Lands (AML) Program. An engineered shaft seal design was developed and demonstrated that featured lightweight concrete as a key material component at a wet density of about 45 lb/ft 3 . A reinforced concrete cap designed for 5 psi live load was placed over the shaft seal. Applicable new concrete technologies relating to a 100-yr design life were utilized to assure future integrity of the shaft seal. Waterproofing methods were included in the shaft seal design to provide protection from ambient moisture and corrosive mine waters and to increase the long-term durability of the shaft seal. All construction methods used in the field trial are fully adaptable for the mine-reclamation contractor. The USBM research objectives were to develop a broad generic design that will be widely applicable to other adit-sealing and shaft-sealing problems throughout the mining industry

Multi-component lightweight gearwheels with deep-drawn wheel body for automotive applications

Science.gov (United States)

Benkert, Tim; Hiller, Maria; Volk, Wolfram

2017-09-01

Multi-component gearwheels offer great lightweight opportunities for automotive applications. An assembly of a gear ring and a wheel body joined by press fit replaces the monolithic gearwheel. To save weight, the wheel body uses lightweight design. This lightweight design influences the assembled gearwheel’s mechanical properties like stiffness, weight and torque capacity. Further, the wheel body material influences the mentioned properties as well. In this paper, the effects of the lightweight wheel body manufactured by deep-drawing on the mechanical properties of the assembled gearwheel are investigated. Three different wheel body designs are examined regarding their stiffness and weight compared to a reference gearwheel. Using the best design, the influence of five materials with increasing yield strength on the maximum torque the gearwheel can transmit is studied. All research is done virtually using Abaqus 6.12-3.

Effect of the Fiber Type and Axial Stiffness of FRCM on the Flexural Strengthening of RC Beams

Directory of Open Access Journals (Sweden)

Abdulla Jabr

2017-01-01

Full Text Available The use of externally-bonded fiber-reinforced polymer (FRP sheets has been successfully used in the repair and strengthening of both the shear and flexural capacities of reinforced concrete (RC beams, slabs and columns since the 1990s. However, the externally-bonded FRP reinforcements still present many disadvantages, such as poor performance in elevated temperature and fire, lack of permeability and strength degradation when exposed to ultraviolet radiation. To remedy such drawbacks, the fiber-/fabric-reinforced cementitious matrix (FRCM has been recently introduced. The FRCM system consists of a fiber mesh or grid embedded in a cementitious bonding material. The present research investigates the flexural strengthening of reinforced concrete (RC beams with FRCM. The experimental testing included eight large-scale concrete beams, 150 mm × 250 mm × 2400 mm, internally reinforced with steel bars and strengthened in flexure with FRCM. The investigated parameters were the internal steel reinforcement ratio and the FRCM systems. Two steel reinforcement ratios of 0.18 and 0.36 of the balanced reinforcement ratio, as well as three FRCM systems using glass, carbon and PBO fibers were investigated. Test results are presented in terms of load-deflection, load-strain and load-crack width relationships. The test results indicated that the PBO FRCM significantly increased the ultimate capacity of the strengthened RC beams with both low and moderate internal reinforcement ratios compared to the glass and carbon FRCM.

Ceramic/polymer functionally graded material (FGM) lightweight armor system

Energy Technology Data Exchange (ETDEWEB)

Petrovic, J.J.; McClellan, K.J.

1998-12-31

This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Functionally graded material is an enabling technology for lightweight body armor improvements. The objective was to demonstrate the ability to produce functionally graded ceramic-polymer and ceramic-metal lightweight armor materials. This objective involved two aspects. The first and key aspect was the development of graded-porosity boron-carbide ceramic microstructures. The second aspect was the development of techniques for liquid infiltration of lightweight metals and polymers into the graded-porosity ceramic. The authors were successful in synthesizing boron-carbide ceramic microstructures with graded porosity. These graded-porosity boron-carbide hot-pressed pieces were then successfully liquid-infiltrated in vacuum with molten aluminum at 1,300 C, and with liquid polymers at room temperature. Thus, they were able to demonstrate the feasibility of producing boron carbide-aluminum and boron carbide-polymer functionally graded materials.

Development of an accurate pH measurement methodology for the pore fluids of low pH cementitious materials

International Nuclear Information System (INIS)

Alonso, M. C.; Garcia Calvo, J. L.; Walker, C.

2012-08-01

The main objective of this project has been the development of an agreed set of protocols for the pH measurement of the pore fluid of a low pH cementitious material. Three protocols have been developed (Chapter 2), a reference method, based on pore fluid expression (PFE), and two routine methods with and without filtering, based on Ex Situ Leaching (ESL) procedures. Templates have been designed on which to record details of the pH measurement for the reference (PFE) method (Appendix C) and the routine (ESL) methods without and with filtering (Appendix D). Preliminary protocols were based on a broad review of the literature (Appendix A) and refined through a series of test experiments of the more critical parameters (Appendix B). After definition of the preliminary protocols, two phases of interlaboratory tests were performed. The first phase (Chapter 3) used the same low pH cement paste and enabled the nine participating laboratories to use, become familiar with and to identify any problems/uncertainties in the preliminary protocols. The reported pH values were subjected to a statistical analysis of the (within laboratory) repeatability and (between-laboratory) reproducibility and so provided a reliability test of the preliminary protocols. The second phase (Chapter 4) of interlaboratory tests used four different candidate low pH cementitious materials in the same nine laboratories, which allowed testing, validation and comparison of the reported pH values, which were obtained using the final protocols for the reference (PFE) and routine (ESL) methods by statistical analysis. The proposed final protocols (Chapter 2) have resulted in the reported pH values having low deviation and high reproducibility and repeatability. This will allow confidence in the pH value when selecting a candidate low pH cementitious material to be used in the engineered component of a high-level nuclear waste repository

Development of an accurate pH measurement methodology for the pore fluids of low pH cementitious materials

Energy Technology Data Exchange (ETDEWEB)

Alonso, M. C.; Garcia Calvo, J. L. [The Spanish National Research Council (CSIC), Madrid (Spain); Walker, C. [Japan Atomic Energy Agency (JAEA), Ibaraki (Japan)] [and others

2012-08-15

The main objective of this project has been the development of an agreed set of protocols for the pH measurement of the pore fluid of a low pH cementitious material. Three protocols have been developed (Chapter 2), a reference method, based on pore fluid expression (PFE), and two routine methods with and without filtering, based on Ex Situ Leaching (ESL) procedures. Templates have been designed on which to record details of the pH measurement for the reference (PFE) method (Appendix C) and the routine (ESL) methods without and with filtering (Appendix D). Preliminary protocols were based on a broad review of the literature (Appendix A) and refined through a series of test experiments of the more critical parameters (Appendix B). After definition of the preliminary protocols, two phases of interlaboratory tests were performed. The first phase (Chapter 3) used the same low pH cement paste and enabled the nine participating laboratories to use, become familiar with and to identify any problems/uncertainties in the preliminary protocols. The reported pH values were subjected to a statistical analysis of the (within laboratory) repeatability and (between-laboratory) reproducibility and so provided a reliability test of the preliminary protocols. The second phase (Chapter 4) of interlaboratory tests used four different candidate low pH cementitious materials in the same nine laboratories, which allowed testing, validation and comparison of the reported pH values, which were obtained using the final protocols for the reference (PFE) and routine (ESL) methods by statistical analysis. The proposed final protocols (Chapter 2) have resulted in the reported pH values having low deviation and high reproducibility and repeatability. This will allow confidence in the pH value when selecting a candidate low pH cementitious material to be used in the engineered component of a high-level nuclear waste repository.

Behavior of reinforced concrete beams reinforced with GFRP bars

Directory of Open Access Journals (Sweden)

D. H. Tavares

Full Text Available The use of fiber reinforced polymer (FRP bars is one of the alternatives presented in recent studies to prevent the drawbacks related to the steel reinforcement in specific reinforced concrete members. In this work, six reinforced concrete beams were submitted to four point bending tests. One beam was reinforced with CA-50 steel bars and five with glass fiber reinforced polymer (GFRP bars. The tests were carried out in the Department of Structural Engineering in São Carlos Engineering School, São Paulo University. The objective of the test program was to compare strength, reinforcement deformation, displacement, and some anchorage aspects between the GFRP-reinforced concrete beams and the steel-reinforced concrete beam. The results show that, even though four GFRP-reinforced concrete beams were designed with the same internal tension force as that with steel reinforcement, their capacity was lower than that of the steel-reinforced beam. The results also show that similar flexural capacity can be achieved for the steel- and for the GFRP-reinforced concrete beams by controlling the stiffness (reinforcement modulus of elasticity multiplied by the bar cross-sectional area - EA and the tension force of the GFRP bars.

Compact, Lightweight Servo-Controllable Brakes

Science.gov (United States)

Lovchik, Christopher S.; Townsend, William; Guertin, Jeffrey; Matsuoka, Yoky

2010-01-01

Compact, lightweight servo-controllable brakes capable of high torques are being developed for incorporation into robot joints. A brake of this type is based partly on the capstan effect of tension elements. In a brake of the type under development, a controllable intermediate state of torque is reached through on/off switching at a high frequency.

Acoustic performance and microstructural analysis of bio-based lightweight concrete containing miscanthus

NARCIS (Netherlands)

Chen, Yuxuan; Yu, Q. L.; Brouwers, H. J.H.

2017-01-01

Miscanthus Giganteus (i.e. Elephant Grass) is a cost-effective and extensively available ecological resource in many agricultural regions. This article aims at a fundamental research on a bio-based lightweight concrete using miscanthus as aggregate, i.e. miscanthus lightweight concrete (MLC), with

Free and bound chloride contents in cementitious materials

NARCIS (Netherlands)

Marinescu, M.V.A.; Brouwers, H.J.H.; Fischer, G.; Geiker, M.; Hededal, O.; Ottoson, L.; Stang, H.

2010-01-01

Chloride attack is the main cause of structural damage in reinforced concrete buildings exposed to marine environments. When a certain threshold concentration of chlorides is reached at the concrete-reinforcement interface, the corrosion of the steel rebars is initiated. A part of the intruding

Durability of Cement Composites Reinforced with Sisal Fiber

Science.gov (United States)

Wei, Jianqiang

understanding of degradation mechanisms, two approaches are proposed to mitigate the degradation of sisal fiber in the cement matrix. In order to relieve the aggressive environment of hydrated cement, cement substitution by a combination of metakaolin and nanoclay, and a combination of rice husk ash and limestone are studied. Both metakaolin and nanoclay significantly optimize the cement hydration, while the combination of these two supplementary cementitious materials validates their complementary and synergistic effect at different stages of aging. The presented approaches effectively reduce the calcium hydroxide content and the alkalinity of the pore solution, thereby mitigating the fiber degradation and improving both the initial mechanical properties and durability of the fiber-cement composites. The role of rice husk ash in cement modification is mainly as the active cementitious supplementary material. In order to improve the degradation resistance of sisal fiber itself, two novel, simple, and economical pretreatments of the fibers (thermal and sodium carbonate treatment) are investigated. Both thermal treatment and Na 2CO3 treatment effectively improve the durability of sisal fiber-reinforced concrete. The thermal treatment achieves improvement of cellulose's crystallization, which ensures the initial strength and improved durability of sisal fiber. A layer consisting of calcium carbonate sediments, which protects the internals of a fiber from the strong alkali pore solution, is formed and filled in pits and cavities on the Na2CO3 treated sisal fiber's surface.

Development of low-pH cementitious materials for HLRW repositories. Resistance against ground waters aggression

OpenAIRE

Garcia Calvo, Jose Luis; Hidalgo, A.; Fernandez Luco, L.; Alonso Alonso, Maria Cruz

2010-01-01

One of the most accepted engineering construction concepts of underground repositories for high radioactive waste considers the use of low-pH cementitious materials. This paper deals with the design of those based on Ordinary Portland Cements with high contents of silica fume and/or fly ashes that modify most of the concrete “standard” properties, the pore fluid composition and the microstructure of the hydrated products. Their resistance to long-term groundwater aggression is also evaluated....

Thin fiber and textile reinforced cementitious systems

National Research Council Canada - National Science Library

Aldea, Corina-Maria

2007-01-01

.... The topics of the papers cover experimental and theoretical materials aspects, such as the effect of different input fibers, fabric type, and construction and matrix on mechanical and long-term...

Durability of Geopolymer Lightweight Concrete Infilled LECA in Seawater Exposure

Science.gov (United States)

Razak, R. A.; Abdullah, M. M. A. B.; Yahya, Z.; Hamid, M. S. A.

2017-11-01

This paper describes a development of lightweight concrete using lightweight expanded clay aggregate (LECA) in fly ash (FA) based geopolymer immersed in seawater. The objective of this research is to compare the performance of geopolymer concrete (GPC) with ordinary Portland cement (OPC) concrete infilled lightweight expanded clay aggregate (LECA) in seawater exposure. Geopolymer concrete is produced by using alkaline activator to activate the raw material, FA. The highest compressive strength of this study is 42.0 MPa at 28 days and 49.8 MPa at 60 days. The density for this concrete is in the range of 1580 kg/m3 to 1660 kg/m3. The result for water absorption is in the range of 6.82% to 14.72%. However, the test results of weight loss is in the range between 0.30% to 0.43%.

LIGHTWEIGHT CONCRETE BASED GRANSHLAK

Directory of Open Access Journals (Sweden)

NETESA M. I.

2016-02-01

Full Text Available Raising of problem. Concrete advisable to obtain a low strength with local secondary resources for recycling and reduce the environmental burden on the environment. But it is important to design such concrete compositions with a reduced flow of cement. It is known that the coefficient of efficiency of use of cement in the concrete of the heavy and B10 is less than about 0.5, which is almost two times smaller than in class B15 concrete and above. Even lower coefficient of efficiency in light concrete cement low strength. Therefore, it is important to find patterns determining the composition of lightweight concrete based on local-products industry with more efficient use of cement in them. Purpose.. Based on the analysis of earlier research results, including with the use of methods of mathematical planning of experiments to determine the concrete contents, which can provide the requirements for the underlying layers of the floor, the compressive strength of which should correspond to the class B5. It is important to provide the required strength at minimum flow of the cement, which is the most expensive and energy-intensive part of concrete. Conclusion. Analysis of the test results of control samples of concrete in 28-day-old, the following laws. The required tensile strength of concrete compressive strength of 7.0 MPa can be obtained in the test range when used in formulations as a filler as the Dnieper hydroelectric power station fly ash and tailings Krivoy Rog iron ore YuGOK. To ensure providing the required characteristic strength of the concrete in the underlying layers of the floor is advisable to use a nominal composition per cubic meter of concrete: cement 160 kg granshlaka Plant named after Petrovsky, 675 kg of fly ash Dnieper HPP 390 kg, 400 kg of sand, 230 liters of water. Thus, while ensuring rational grain composition components can obtain the desired strength lightweight concrete based granshlaka plant Petrovsky, using as fillers

Methods to assess radioisotope migration in cementitious media using radial diffusion and advection

International Nuclear Information System (INIS)

Hinchliff, J.; Felipe-Sotero, M.; Evans, N.D.M.; Read, D.; Drury, D.

2012-01-01

One of the primary aims of this project is to understand how a range of isotopes associated with radioactive wastes, move through the cementitious media potentially present in a geological disposal facility (GDF). This paper describes the development of experimental methods that use radial flow from intact cylinders of cementitious material to evaluate the potential for diffusion and advection of relevant isotopes through Nirex reference vault backfill (NRVB). The small scale and cost effectiveness of the approach means that multiple experiments can be undertaken encompassing the full range of physical (and chemical) variations. The radial flow experimental method uses small pre-cast cylinders of the matrix under investigation. For diffusion an appropriate concentration of the isotope of interest ( 90 Sr in the present experiments) is introduced into a cavity in the centre of the cylinder, which is then sealed, and placed in a solution previously equilibrated with the matrix. The increase in concentration of the isotope in the external solution is then determined at defined time intervals. For advection 90 Sr is similarly introduced into the central core of the cylinder and then equilibrated water is forced under nitrogen pressure, from the central core to the outside of the cylinder where it is collected in a tray prior to analysis. Both experimental set ups and results have been modelled using conventional numerical solutions and the simulation package GoldSim. Concerning diffusion experiments the modelled data reproduces the observed data effectively with a right diffusivity value of 9*10 -11 m 2 /s. Concerning advection results are more mitigated and need further investigation

Interactive mathematical model of self-healing in carbonated cementitious materials

NARCIS (Netherlands)

Zemskov, S.V.; Copuroglu, O.; Vermolen, F.J.

2013-01-01

A mathematical model for the post-damage recovery of carbonated cement is described. The model is based on a two-dimensional initial-boundary value problem for a system of partial differential equations. The study is embedded within the framework of investigating the effect of using lightweight

INFLUENCE OF KENAF AND POLYPROPYLENE FIBRES ON MECHANICAL AND DURABILITY PROPERTIES OF FIBRE REINFORCED LIGHTWEIGHT FOAMED CONCRETE

Directory of Open Access Journals (Sweden)

H. AWANG

2015-04-01

Full Text Available This paper investigates the mechanical and durability properties of lightweight foamed concrete (LFC with the inclusion of kenaf and polypropylene fibres. A density of 1000kg/m3 foamed concrete was used for all the tested specimens. The ratio of cement, sand and water used was 1:1.5:0.45. Polypropylene and kenaf fibres were used as additives at 0.25% and 0.4% by volume of the total mix. A 30% cement replacement by fly ash was used with each type of additive. All the experiments were set up in accordance with International standard methods of testing. Scanning electron microscopy (SEM analysis is included to have a better view of the concrete behavior with fibre inclusions. In reference to the analysis and discussion, the types of fibre used were proven to have a lesser contribution towards compressive strength or might even have reduced the result. However, the integration of fly ash enhanced the compressive strength. In addition, a higher percentage of fiber inclusions had been recorded to have a positive contribution towards flexural, tensile spiltting and shrinkage properties of LFC.

Hybrid Electrostatic/Flextensional Mirror for Lightweight, Large-Aperture, and Cryogenic Space Telescopes

Science.gov (United States)

Patrick, Brian; Moore, James; Hackenberger, Wesley; Jiang, Xiaoning

2013-01-01

A lightweight, cryogenically capable, scalable, deformable mirror has been developed for space telescopes. This innovation makes use of polymer-based membrane mirror technology to enable large-aperture mirrors that can be easily launched and deployed. The key component of this innovation is a lightweight, large-stroke, cryogenic actuator array that combines the high degree of mirror figure control needed with a large actuator influence function. The latter aspect of the innovation allows membrane mirror figure correction with a relatively low actuator density, preserving the lightweight attributes of the system. The principal components of this technology are lightweight, low-profile, high-stroke, cryogenic-capable piezoelectric actuators based on PMN-PT (piezoelectric lead magnesium niobate-lead titanate) single-crystal configured in a flextensional actuator format; high-quality, low-thermal-expansion polymer membrane mirror materials developed by NeXolve; and electrostatic coupling between the membrane mirror and the piezoelectric actuator assembly to minimize problems such as actuator print-through.

Volume changes in unrestrained structural lightweight concrete.

Science.gov (United States)

1964-08-01

In this study a comparator-type measuring system was developed to accurately determine volume change characteristics of one structural lightweight concrete. The specific properties studied were the coefficient of linear thermal expansion and unrestra...

HOKES/POKES : Light-weight resource sharing

NARCIS (Netherlands)

Bos, Herbert; Samwel, Bart

2003-01-01

In this paper, we explain mechanisms for providing embedded network processors and other low-level programming environments with light-weight support for safe resource sharing. The solution consists of a host part, known as HOKES, and a network processor part, known as POKES. As common operating

Approaches to control the quality of cementitious PFA grouts for nuclear waste encapsulation

Energy Technology Data Exchange (ETDEWEB)

Rice, G.; Miles, N.; Farris, S. [University of Nottingham, Nottingham (United Kingdom). Nottingham Mining & Minerals Centre

2007-05-15

Pulverised Fuel Ash (PFA) is combined with Ordinary Portland Cement (OPC) powder and water to form cementitious grouts for use in various aspects of nuclear waste encapsulation. Whilst specific PFA supplies in the United Kingdom currently deliver adequate grout performance it is also clear that some alternative supplies result in inferior performance, leading to concern over the long term availability of suitable raw material. This paper presents the results of an investigation into the characteristics of PFA that affect critical aspects of grout performance and identifies strategies that could be used to ensure high quality PFA supplies in the future.

Studies of ancient concrete as analogs of cementitious sealing materials for a repository in tuff

Energy Technology Data Exchange (ETDEWEB)

Roy, D.M.; Langton, C.A.

1989-03-01

The durability of ancient cementitious materials has been investigated to provide data applicable to determining the resistance to weathering of concrete materials for sealing a repository for storage of high-level radioactive waste. Because tuff and volcanic ash are used in the concretes in the vicinity of Rome, the results are especially applicable to a waste repository in tuff. Ancient mortars, plasters, and concretes collected from Rome, Ostia, and Cosa dating to the third century BC show remarkable durability. The aggregates used in the mortars, plasters, and concretes included basic volcanic and pyroclastic rocks (including tuff), terra-cotta, carbonates, sands, and volcanic ash. The matrices of ancient cementitious materials have been characterized and classified into four categories: (1) hydraulic hydrated lime and hydrated lime cements, (2) hydraulic aluminous and ferruginous hydrated lime cements ({plus_minus} siliceous components), (3) pozzolana/hydrated lime cements, and (4) gypsum cements. Most of the materials investigated are in category (3). The materials were characterized to elucidate aspects of the technology that produced them and their response to the environmental exposure throughout their centuries of existence. Their remarkable properties are the result of a combination of chemical, mineralogical, and microstructural factors. Their durability was found to be affected by the matrix mineralogy, particle size, and porosity; aggregate type, grading and proportioning; and the methodology of placement. 30 refs.

Computational imaging using lightweight diffractive-refractive optics

KAUST Repository

Peng, Yifan

2015-11-23

Diffractive optical elements (DOE) show great promise for imaging optics that are thinner and more lightweight than conventional refractive lenses while preserving their light efficiency. Unfortunately, severe spectral dispersion currently limits the use of DOEs in consumer-level lens design. In this article, we jointly design lightweight diffractive-refractive optics and post-processing algorithms to enable imaging under white light illumination. Using the Fresnel lens as a general platform, we show three phase-plate designs, including a super-thin stacked plate design, a diffractive-refractive-hybrid lens, and a phase coded-aperture lens. Combined with cross-channel deconvolution algorithm, both spherical and chromatic aberrations are corrected. Experimental results indicate that using our computational imaging approach, diffractive-refractive optics is an alternative candidate to build light efficient and thin optics for white light imaging.

Computational imaging using lightweight diffractive-refractive optics

KAUST Repository

Peng, Yifan; Fu, Qiang; Amata, Hadi; Su, Shuochen; Heide, Felix; Heidrich, Wolfgang

2015-01-01

Diffractive optical elements (DOE) show great promise for imaging optics that are thinner and more lightweight than conventional refractive lenses while preserving their light efficiency. Unfortunately, severe spectral dispersion currently limits the use of DOEs in consumer-level lens design. In this article, we jointly design lightweight diffractive-refractive optics and post-processing algorithms to enable imaging under white light illumination. Using the Fresnel lens as a general platform, we show three phase-plate designs, including a super-thin stacked plate design, a diffractive-refractive-hybrid lens, and a phase coded-aperture lens. Combined with cross-channel deconvolution algorithm, both spherical and chromatic aberrations are corrected. Experimental results indicate that using our computational imaging approach, diffractive-refractive optics is an alternative candidate to build light efficient and thin optics for white light imaging.

Strength properties of cement slurries with lightweights applied in oil and gas wells

International Nuclear Information System (INIS)

Bubnov, A S; Drilling Mud and Cement Slurry (Russian Federation))" data-affiliation=" (Head of Laboratory Drilling Mud and Cement Slurry (Russian Federation))" >Boyko, I A; Drilling Mud and Cement Slurry (Russian Federation))" data-affiliation=" (PhD, Engineer, Laboratory Drilling Mud and Cement Slurry (Russian Federation))" >Khorev, V S

2015-01-01

The article is focused on the cement stone strength properties resulted from lightweight cement slurries that meet GOST-1581-96 (state Standards) requirements. Exfoliated vermiculite, hollow aluminosilicate microspheres (HAMs), diatomite and perlite were used as lightweighting additives

Study on conversion relationships of compressive strength indexes for recycled lightweight aggregate concrete

Science.gov (United States)

Zhang, Xiang-gang; Yang, Jian-hui; Kuang, Xiao-mei

2017-01-01

In order to study cube compressive strength and axial compressive strength of recycled lightweight aggregate concrete(RLAC), and conversion relationship between the two, with the replacement rate of recycled lightweight coarse aggregate as change parameters, 15 standard cube test specimens and 15 standard prism test specimens were produced to carry out the test. Then compressive strength of test specimens were measured, and the law of different replacement rate of recycled lightweight coarse aggregate influencing compressive strength of RLAC was analyzed, as the method of statistical regression adopted, the conversion relationships between of cube compressive strength and axial compressive strength of RLAC was obtained. It is shown that compressive strength of RLAC are lower than compressive strength of ordinary concrete; and that compressive strength of RLAC gradually decreases as replacement rate of recycled lightweight coarse aggregate increases; as well as, the conversion relationship between axial compressive strength and cube compressive strength of RLAC is different from ordinary concrete; based on the experimental data, conversion relationship formula between compressive strength indexes of RLAC was established. It is suggested that the replacement rate of recycled lightweight aggregate should be controlled within 25%.

Experimental study on the effect of volcanic residue on the performance of recycled lightweight aggregate concrete

Science.gov (United States)

Xiao, Li-guang; Li, Ji-heng; Liu, Qing-shun

2017-08-01

Recycled lightweight aggregate concrete prepared with waste brick recycled light aggregate has high water absorption, large apparent density and poor frost resistance. The technical measures of regen-erating lightweight aggregate concrete with modified waste bricks from volcanic slag are put forward. The effects of volcanic slag on the properties of waste lightweight aggregate concrete were studied. The experi-mental results show that volcanic slag can significantly reduce the apparent density of recycled lightweight aggregate concrete and improve its frost resistance.

Cryptanalysis of Compact-LWE and Related Lightweight Public Key Encryption

Directory of Open Access Journals (Sweden)

Dianyan Xiao

2018-01-01

Full Text Available In the emerging Internet of Things (IoT, lightweight public key cryptography plays an essential role in security and privacy protection. With the approach of quantum computing era, it is important to design and evaluate lightweight quantum-resistant cryptographic algorithms applicable to IoT. LWE-based cryptography is a widely used and well-studied family of postquantum cryptographic constructions whose hardness is based on worst-case lattice problems. To make LWE friendly to resource-constrained IoT devices, a variant of LWE, named Compact-LWE, was proposed and used to design lightweight cryptographic schemes. In this paper, we study the so-called Compact-LWE problem and clarify that under certain parameter settings it can be solved in polynomial time. As a consequence, our result leads to a practical attack against an instantiated scheme based on Compact-LWE proposed by Liu et al. in 2017.

Mechanical and Physical Properties of Hydrophobized Lightweight Aggregate Concrete with Sewage Sludge.

Science.gov (United States)

Suchorab, Zbigniew; Barnat-Hunek, Danuta; Franus, Małgorzata; Łagód, Grzegorz

2016-04-27

This article is focused on lightweight aggregate-concrete modified by municipal sewage sludge and lightweight aggregate-concrete obtained from light aggregates. The article presents laboratory examinations of material physical parameters. Water absorptivity of the examined material was decreased by the admixture of water emulsion of reactive polysiloxanes. Water transport properties were determined using Time Domain Reflectometry, an indirect technique for moisture detection in porous media. Together with basic physical parameters, the heat conductivity coefficient λ was determined for both types of lightweight aggregate-concrete. Analysis of moisture and heat properties of the examined materials confirmed the usefulness of light aggregates supplemented with sewage sludge for prospective production.

Effect of water absorption by the aggregate on properties of high-strength lightweight concrete

Energy Technology Data Exchange (ETDEWEB)

Punkki, J

1996-12-31

Recently, high-strength lightweight concrete has become an interesting building material for the offshore oil industry. This doctoral thesis presents an experimental investigation of the effect of water absorption by three different types of lightweight aggregates. One type did not show any water absorption ability at all and so represented no problem to the concrete production. For the two other high-strength aggregates, which were of more conventional types, the water absorption depended not only on the properties of the aggregates, but also on the concrete mixing procedure and the properties of the fresh cement paste. When water absorbing lightweight aggregate was used in a dry condition, the workability of the concrete was significantly reduced by the water absorption of the aggregate. This effect was not present when prewetted aggregate was used. The water absorption by the lightweight aggregate also affected the early compressive strength of concrete. After one day, dry aggregate gave on the average 10 MPa higher compressive strength than did prewetted aggregate. The strength-density ratio was affected by the moisture condition of the aggregate. Dry lightweight aggregate gave 9 MPa higher compressive strength at a density of 2000 kg/m{sup 3} compared to that of prewetted aggregate. The water absorption by the lightweight also affected the microstructure of the hardened concrete. Dry lightweight aggregate gave a slightly better microstructure than normal weight aggregate. The results indicate that the use of prewetted aggregate adversely affected the transition zone between the aggregate and the cement paste. 69 refs., 58 figs., 42 tabs.

Effect of water absorption by the aggregate on properties of high-strength lightweight concrete

Energy Technology Data Exchange (ETDEWEB)

Punkki, J.

1995-12-31

Recently, high-strength lightweight concrete has become an interesting building material for the offshore oil industry. This doctoral thesis presents an experimental investigation of the effect of water absorption by three different types of lightweight aggregates. One type did not show any water absorption ability at all and so represented no problem to the concrete production. For the two other high-strength aggregates, which were of more conventional types, the water absorption depended not only on the properties of the aggregates, but also on the concrete mixing procedure and the properties of the fresh cement paste. When water absorbing lightweight aggregate was used in a dry condition, the workability of the concrete was significantly reduced by the water absorption of the aggregate. This effect was not present when prewetted aggregate was used. The water absorption by the lightweight aggregate also affected the early compressive strength of concrete. After one day, dry aggregate gave on the average 10 MPa higher compressive strength than did prewetted aggregate. The strength-density ratio was affected by the moisture condition of the aggregate. Dry lightweight aggregate gave 9 MPa higher compressive strength at a density of 2000 kg/m{sup 3} compared to that of prewetted aggregate. The water absorption by the lightweight also affected the microstructure of the hardened concrete. Dry lightweight aggregate gave a slightly better microstructure than normal weight aggregate. The results indicate that the use of prewetted aggregate adversely affected the transition zone between the aggregate and the cement paste. 69 refs., 58 figs., 42 tabs.

Braided reinforced composite rods for the internal reinforcement of concrete

Science.gov (United States)

Gonilho Pereira, C.; Fangueiro, R.; Jalali, S.; Araujo, M.; Marques, P.

2008-05-01

This paper reports on the development of braided reinforced composite rods as a substitute for the steel reinforcement in concrete. The research work aims at understanding the mechanical behaviour of core-reinforced braided fabrics and braided reinforced composite rods, namely concerning the influence of the braiding angle, the type of core reinforcement fibre, and preloading and postloading conditions. The core-reinforced braided fabrics were made from polyester fibres for producing braided structures, and E-glass, carbon, HT polyethylene, and sisal fibres were used for the core reinforcement. The braided reinforced composite rods were obtained by impregnating the core-reinforced braided fabric with a vinyl ester resin. The preloading of the core-reinforced braided fabrics and the postloading of the braided reinforced composite rods were performed in three and two stages, respectively. The results of tensile tests carried out on different samples of core-reinforced braided fabrics are presented and discussed. The tensile and bending properties of the braided reinforced composite rods have been evaluated, and the results obtained are presented, discussed, and compared with those of conventional materials, such as steel.

Nano-modification to improve the ductility of cementitious composites

International Nuclear Information System (INIS)

Yeşilmen, Seda; Al-Najjar, Yazin; Balav, Mohammad Hatam; Şahmaran, Mustafa; Yıldırım, Gürkan; Lachemi, Mohamed

2015-01-01

Effect of nano-sized mineral additions on ductility of engineered cementitious composites (ECC) containing high volumes of fly ash was investigated at different hydration degrees. Various properties of ECC mixtures with different mineral additions were compared in terms of microstructural properties of matrix, fiber-matrix interface, and fiber surface to assess improvements in ductility. Microstructural characterization was made by measuring pore size distributions through mercury intrusion porosimetry (MIP). Hydration characteristics were assessed using thermogravimetric analysis/differential thermal analysis (TGA/DTA), and fiber-matrix interface and fiber surface characteristics were assessed using scanning electron microscopy (SEM) through a period of 90 days. Moreover, compressive and flexural strength developments were monitored for the same period. Test results confirmed that mineral additions could significantly improve both flexural strength and ductility of ECC, especially at early ages. Cheaper Nano-CaCO 3 was more effective compared to nano-silica. However, the crystal structure of CaCO 3 played a very important role in the range of expected improvements

Lightweight and Energy Efficient Heat Pump, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Future Spacecraft from the JPL will require increasingly sophisticated thermal control technology. A need exists for efficient, lightweight Vapor Compression Cycle...

Flexural reinforced concrete member with FRP reinforcement

OpenAIRE

Putzolu, Mariana

2017-01-01

One of the most problematic point in construction is the durability of the concrete especially related to corrosion of the steel reinforcement. Due to this problem the construction sector, introduced the use of Fiber Reinforced Polymer, the main fibers used in construction are Glass, Carbon and Aramid. In this study, the author aim to analyse the flexural behaviour of concrete beams reinforced with FRP. This aim is achieved by the analysis of specimens reinforced with GFRP bars, with theoreti...

Properties and shaping of lightweight ceramics based on phosphate-bonded hollow silica microspheres

NARCIS (Netherlands)

With, de G.; Verweij, H.

1986-01-01

The values for the Young's modulus, strength, fracture toughness and thermal conductivity of lightweight ceramics based on phosphate-bonded hollow silica microspheres are reported as a function of the processing conditions. They are compared with the relevant data for other lightweight ceramic

Development of lightweight concrete mixes for construction industry at the state of Arkansas

Science.gov (United States)

Almansouri, Mohammed Abdulwahab

As the construction industry evolved, the need for more durable, long lasting infrastructure increased. Therefore, more efforts have been put to find new methods to improve the properties of the concrete to prolong the service life of the structural elements. One of these methods is the use of lightweight aggregate as an internal curing agent to help reducing self-desiccation and shrinkage. This research studied the effects of using locally available lightweight aggregate (expanded clay), as a partial replacement of normal weight aggregate in the concrete matrix. The concrete mixtures contained lightweight aggregate with a replacement percentage of 12.5, 25, 37.5, and 50 percent by volume. Fresh properties as well as compressive strength, modulus of rupture, and drying shrinkage were measured. While was effective in reducing drying shrinkage, the use of lightweight aggregate resulted in slightly reducing both the compressive strength and modulus of rupture.