From fire whirls to blue whirls and combustion with reduced pollution

Science.gov (United States)

Xiao, Huahua; Gollner, Michael J.; Oran, Elaine S.

2016-08-01

Fire whirls are powerful, spinning disasters for people and surroundings when they occur in large urban and wildland fires. Whereas fire whirls have been studied for fire-safety applications, previous research has yet to harness their potential burning efficiency for enhanced combustion. This article presents laboratory studies of fire whirls initiated as pool fires, but where the fuel sits on a water surface, suggesting the idea of exploiting the high efficiency of fire whirls for oil-spill remediation. We show the transition from a pool fire, to a fire whirl, and then to a previously unobserved state, a “blue whirl.” A blue whirl is smaller, very stable, and burns completely blue as a hydrocarbon flame, indicating soot-free burning. The combination of fast mixing, intense swirl, and the water-surface boundary creates the conditions leading to nearly soot-free combustion. With the worldwide need to reduce emissions from both wanted and unwanted combustion, discovery of this state points to possible new pathways for reduced-emission combustion and fuel-spill cleanup. Because current methods to generate a stable vortex are difficult, we also propose that the blue whirl may serve as a research platform for fundamental studies of vortices and vortex breakdown in fluid mechanics.

From fire whirls to blue whirls and combustion with reduced pollution.

Science.gov (United States)

Xiao, Huahua; Gollner, Michael J; Oran, Elaine S

2016-08-23

Fire whirls are powerful, spinning disasters for people and surroundings when they occur in large urban and wildland fires. Whereas fire whirls have been studied for fire-safety applications, previous research has yet to harness their potential burning efficiency for enhanced combustion. This article presents laboratory studies of fire whirls initiated as pool fires, but where the fuel sits on a water surface, suggesting the idea of exploiting the high efficiency of fire whirls for oil-spill remediation. We show the transition from a pool fire, to a fire whirl, and then to a previously unobserved state, a "blue whirl." A blue whirl is smaller, very stable, and burns completely blue as a hydrocarbon flame, indicating soot-free burning. The combination of fast mixing, intense swirl, and the water-surface boundary creates the conditions leading to nearly soot-free combustion. With the worldwide need to reduce emissions from both wanted and unwanted combustion, discovery of this state points to possible new pathways for reduced-emission combustion and fuel-spill cleanup. Because current methods to generate a stable vortex are difficult, we also propose that the blue whirl may serve as a research platform for fundamental studies of vortices and vortex breakdown in fluid mechanics.

Reducing NOx emissions from a biodiesel-fueled engine by use of low-temperature combustion.

Science.gov (United States)

Fang, Tiegang; Lin, Yuan-Chung; Foong, Tien Mun; Lee, Chia-Fon

2008-12-01

Biodiesel is popularly discussed in many countries due to increased environmental awareness and the limited supply of petroleum. One of the main factors impacting general replacement of diesel by biodiesel is NOx (nitrogen oxides) emissions. Previous studies have shown higher NOx emissions relative to petroleum diesel in traditional direct-injection (DI) diesel engines. In this study, effects of injection timing and different biodiesel blends are studied for low load [2 bar IMEP (indicated mean effective pressure)] conditions. The results show that maximum heat release rate can be reduced by retarding fuel injection. Ignition and peak heat release rate are both delayed for fuels containing more biodiesel. Retarding the injection to post-TDC (top dead center) lowers the peak heat release and flattens the heat release curve. It is observed that low-temperature combustion effectively reduces NOx emissions because less thermal NOx is formed. Although biodiesel combustion produces more NOx for both conventional and late-injection strategies, with the latter leading to a low-temperature combustion mode, the levels of NOx of B20 (20 vol % soy biodiesel and 80 vol % European low-sulfur diesel), B50, and B100 all with post-TDC injection are 68.1%, 66.7%, and 64.4%, respectively, lower than pure European low-sulfur diesel in the conventional injection scenario.

Highly time-resolved imaging of combustion and pyrolysis product concentrations in solid fuel combustion: NO formation in a burning cigarette.

Science.gov (United States)

Zimmermann, Ralf; Hertz-Schünemann, Romy; Ehlert, Sven; Liu, Chuan; McAdam, Kevin; Baker, Richard; Streibel, Thorsten

2015-02-03

The highly dynamic, heterogeneous combustion process within a burning cigarette was investigated by a miniaturized extractive sampling probe (microprobe) coupled to photoionization mass spectrometry using soft laser single photon ionization (SPI) for online real-time detection of molecular ions of combustion and pyrolysis products. Research cigarettes smoked by a smoking machine are used as a reproducible model system for solid-state biomass combustion, which up to now is not addressable by current combustion-diagnostic tools. By combining repetitively recorded online measurement sequences from different sampling locations in an imaging approach, highly time- and space-resolved quantitative distribution maps of, e.g., nitrogen monoxide, benzene, and oxygen concentrations were obtained at a near microscopic level. The obtained quantitative distribution maps represent a time-resolved, movie-like imaging of the respective compound's formation and destruction zones in the various combustion and pyrolysis regions of a cigarette during puffing. Furthermore, spatially resolved kinetic data were ascertainable. The here demonstrated methodology can also be applied to various heterogenic combustion/pyrolysis or reaction model systems, such as fossil- or biomass-fuel pellet combustion or to a positional resolved analysis of heterogenic catalytic reactions.

Reduced Gravity Studies of Soret Transport Effects in Liquid Fuel Combustion

Science.gov (United States)

Shaw, Benjamin D.

2004-01-01

Soret transport, which is mass transport driven by thermal gradients, can be important in practical flames as well as laboratory flames by influencing transport of low molecular weight species (e.g., monatomic and diatomic hydrogen). In addition, gas-phase Soret transport of high molecular weight fuel species that are present in practical liquid fuels (e.g., octane or methanol) can be significant in practical flames (Rosner et al., 2000; Dakhlia et al., 2002) and in high pressure droplet evaporation (Curtis and Farrell, 1992), and it has also been shown that Soret transport effects can be important in determining oxygen diffusion rates in certain classes of microgravity droplet combustion experiments (Aharon and Shaw, 1998). It is thus useful to obtain information on flames under conditions where Soret effects can be clearly observed. This research is concerned with investigating effects of Soret transport on combustion of liquid fuels, in particular liquid fuel droplets. Reduced-gravity is employed to provide an ideal (spherically-symmetrical) experimental model with which to investigate effects of Soret transport on combustion. The research will involve performing reduced-gravity experiments on combustion of liquid fuel droplets in environments where Soret effects significantly influence transport of fuel and oxygen to flame zones. Experiments will also be performed where Soret effects are not expected to be important. Droplets initially in the 0.5 to 1 mm size range will be burned. Data will be obtained on influences of Soret transport on combustion characteristics (e.g., droplet burning rates, droplet lifetimes, gas-phase extinction, and transient flame behaviors) under simplified geometrical conditions that are most amenable to theoretical modeling (i.e., spherical symmetry). The experiments will be compared with existing theoretical models as well as new models that will be developed. Normal gravity experiments will also be performed.

Reduced chemical kinetic mechanisms for NOx emission prediction in biomass combustion

DEFF Research Database (Denmark)

Houshfar, Ehsan; Skreiberg, Øyvind; Glarborg, Peter

2012-01-01

Because of the complex composition of biomass, the chemical mechanism contains many different species and therefore a large number of reactions. Although biomass gas‐phase combustion is fairly well researched and understood, the proposed mechanisms are still complex and need very long computational...... time and powerful hardware resources. A reduction of the mechanism for biomass volatile oxidation has therefore been performed to avoid these difficulties. The selected detailed mechanism in this study contains 81 species and 703 elementary reactions. Necessity analysis is used to determine which...... reactions and chemical species, that is, 35 species and 198 reactions, corresponding to 72% reduction in the number of reactions and, therefore, improving the computational time considerably. Yet, the model based on the reduced mechanism predicts correctly concentrations of NOx and CO that are essentially...

Combustion of Methanol Droplets in Air-Diluent Environments with Reduced and Normal Gravity

Directory of Open Access Journals (Sweden)

Benjamin Shaw

2012-01-01

Full Text Available Reduced and normal gravity combustion experiments were performed with fiber-supported methanol droplets with initial diameters in the 1 mm size range. Experiments were performed with air-diluent mixtures at about 0.101 MPa and 298 K, where carbon dioxide, helium, or xenon was separately used as the diluent gas. Results indicate that ambient gas transport properties play an important role in determining flammability and combustion behaviors including burning rates and radiant heat output histories of the droplets. Droplets would burn with significantly higher mole fractions of xenon than helium or carbon dioxide. In reduced gravity, droplets would burn steadily with a xenon mole fraction of 0.50 but would not burn steadily if helium or carbon dioxide mole fractions were 0.50. Comparison with previous experimental data shows that ignitability and combustion characteristics of droplets are influenced by the fuel type and also the gravitational level. Burning rates were about 40% to 70% higher in normal gravity than in reduced gravity. Methanol droplets also had burning rates that were typically larger than 1-propanol burning rates by about 20% in reduced gravity. In normal gravity, however, burning rate differences between the two fuels were significantly smaller.

Progress Toward Analytic Predictions of Supersonic Hydrocarbon-Air Combustion: Computation of Ignition Times and Supersonic Mixing Layers

Science.gov (United States)

Sexton, Scott Michael

Combustion in scramjet engines is faced with the limitation of brief residence time in the combustion chamber, requiring fuel and preheated air streams to mix and ignite in a matter of milliseconds. Accurate predictions of autoignition times are needed to design reliable supersonic combustion chambers. Most efforts in estimating non-premixed autoignition times have been devoted to hydrogen-air mixtures. The present work addresses hydrocarbon-air combustion, which is of interest for future scramjet engines. Computation of ignition in supersonic flows requires adequate characterization of ignition chemistry and description of the flow, both of which are derived in this work. In particular, we have shown that activation energy asymptotics combined with a previously derived reduced chemical kinetic mechanism provides analytic predictions of autoignition times in homogeneous systems. Results are compared with data from shock tube experiments, and previous expressions which employ a fuel depletion criterion. Ignition in scramjet engines has a strong dependence on temperature, which is found by perturbing the chemically frozen mixing layer solution. The frozen solution is obtained here, accounting for effects of viscous dissipation between the fuel and air streams. We investigate variations of thermodynamic and transport properties, and compare these to simplified mixing layers which neglect these variations. Numerically integrating the mixing layer problem reveals a nonmonotonic temperature profile, with a peak occurring inside the shear layer for sufficiently high Mach numbers. These results will be essential in computation of ignition distances in supersonic combustion chambers.

Renew, reduce or become more efficient? The climate contribution of biomass co-combustion in a coal-fired power plant

International Nuclear Information System (INIS)

Miedema, Jan H.; Benders, René M.J.; Moll, Henri C.; Pierie, Frank

2017-01-01

Highlights: • Coal mining is more energy and CO_2 efficient than biomass production. • Co-combustion of 60% biomass with coal doubles mass transport compared to 100% coal. • Low co-combustion levels reduce GHG emissions, but the margins are small. • Total supply chain efficiency is the highest for the coal reference at 41.2%. - Abstract: Within this paper, biomass supply chains, with different shares of biomass co-combustion in coal fired power plants, are analysed on energy efficiency, energy consumption, renewable energy production, and greenhouse gas (GHG) emissions and compared with the performance of a 100% coal supply chain scenario, for a Dutch situation. The 60% biomass co-combustion supply chain scenarios show possibilities to reduce emissions up to 48%. The low co-combustion levels are effective to reduce GHG emissions, but the margins are small. Currently co-combustion of pellets is the norm. Co-combustion of combined torrefaction and pelleting (TOP) shows the best results, but is also the most speculative. The indicators from the renewable energy directive cannot be aligned. When biomass is regarded as scarce, co-combustion of small shares or no co-combustion is the best option from an energy perspective. When biomass is regarded as abundant, co-combustion of large shares is the best option from a GHG reduction perspective.

Evaluating the acute effects of oral, non-combustible potential reduced exposure products marketed to smokers.

Science.gov (United States)

Cobb, C O; Weaver, M F; Eissenberg, T

2010-10-01

Non-combustible potential reduced exposure products (PREPs; eg, Star Scientific's Ariva; a variety of other smokeless tobacco products) are marketed to reduce the harm associated with smoking. This marketing occurs despite an absence of objective data concerning the toxicant exposure and effects of these PREPs. Methods used to examine combustible PREPs were adapted to assess the acute effects of non-combustible PREPs for smokers. 28 overnight abstinent cigarette smokers (17 men, 14 non-white) each completed seven, Latin-squared ordered, approximately 2.5 h laboratory sessions that differed by product administered: Ariva, Marlboro Snus (Philip Morris, USA), Camel Snus (RJ Reynolds, Winston-Salem, North Carolina, USA), Commit nicotine lozenge (GlaxoSmithKline; 2 mg), own brand cigarettes, Quest cigarettes (Vector Tobacco; delivers very low levels of nicotine) and sham smoking (ie, puffing on an unlit cigarette). In each session, the product was administered twice (separated by 60 min), and plasma nicotine levels, expired air CO and subjective effects were assessed regularly. Non-combustible products delivered less nicotine than own brand cigarettes, did not expose smokers to CO and failed to suppress tobacco abstinence symptoms as effectively as combustible products. While decreased toxicant exposure is a potential indicator of harm reduction potential, a failure to suppress abstinence symptoms suggests that currently marketed non-combustible PREPs may not be a viable harm reduction strategy for US smokers. This study demonstrates how clinical laboratory methods can be used to evaluate the short-term effects of non-combustible PREPs for smokers.

Combustion and emission characteristics of a diesel engine with DME as port premixing fuel under different injection timing

International Nuclear Information System (INIS)

Wang, Ying; Zhao, Yuwei; Xiao, Fan; Li, Dongchang

2014-01-01

Highlights: • Combustion and emission of diesel engine with DME as premixing fuel were examined. • Injection timing has profound effect on HRR of diffusive combustion in PCCI engine. • DME introduction drastically influenced HRR of PCCI combustion, especially for HTR. • Effect of injection timing on emission of PCCI engine is similar to that of DICI engine. - Abstract: This work dealt with the combustion and exhaust performance of a DME premixed charge compression ignition diesel engine. With the port premixing DME, the heat-release process was made up of the premixed charge homogeneous charge compression ignition combustion and diffusion combustion. The in-cylinder fuel injection timing and port premixing DME quantity played the important roles in combustion and emission control. They had little impact on the peak position of heat-release rate (HRR) during LTR phase. However, they had great effects on the peak values and the crank-angle positions corresponding to the HRR peaks during HTR and diffusion combustion phase. The peak value of HRR increased and the crank-angle corresponding to the HRR peak advanced with an incremental DME quantity or an early injection during HTR phase. However, the peak value of HRR dropped with an incremental DME quantity or a late injection during the diffusion combustion phase. p max and T max increased with an incremental DME quantity or an early injection. At the fixed direct-injection timing, BSFC decreased slightly with a rise of DME quantity due to CA50 closer to TDC. At a fixed DME quantity, BSFC was lowest when diesel was injected into cylinder at 7°CA BTDC. Moreover, as more DME was aspirated from port, NO x emissions decreased firstly but this decreasing trend ceased later. Smoke reduced, but CO and HC increased with a rise of DME quantity. Meanwhile, like the conventional DICI operation, NO x increased, but smoke, CO and HC declined with an early direct-injection

Effects of various intake valve timings and spark timings on combustion, cyclic THC and NOX emissions during cold start phase with idle operation in CVVT engine

International Nuclear Information System (INIS)

Choi, Kwan Hee; Lee, Hyung Min; Hwang, In Goo; Myung, Cha Lee; Park, Sim Soo

2008-01-01

In a gasoline SI engine, valve events and spark timings put forth a major influence on overall efficiency, fuel economy, and exhaust emissions. Residual gases controlled by the valve overlap can be used to reduce NOx emissions and the spark retardation technique can be used to improve raw THC emissions and catalyst light-off performance during the cold start phase. This paper investigated the behaviors of the engine and its combustion characteristics with various intake valve timings and spark timings during the fast idle condition and cold start. And cyclic THC and NOx emissions were measured at the exhaust port and their formation mechanisms were examined with fast response gas analyzers. As a result, THCs and NOx were reduced by 35% and 23% with optimizing valve overlap and spark advance during the cold transient start phase. Consequently, the valve events and ignition timings were found to significantly affect combustion phenomena and cold-start emissions

Wastes disposal on board a ship. Crushing and volume reducing apparatus for combustible and non-combustible refuses; Senjo no haikibutsu shori. Kanen funen gomi no hasai gen`yo shori sochi

Energy Technology Data Exchange (ETDEWEB)

Kishida, Y. [Hitachi Zosen Corp., Osaka (Japan)

1996-07-25

This paper introduces a refuse crushing apparatus to reduce for storage the volume of refuses produced on board a ship by crushing. Refuses to be crushed are solid wastes including solid combustible refuses such as paper, wood pieces, and cloths, non-combustible refuses such as empty cans, metals and glass, and refuses unsuitable for combustion, such as plastics and stylofoam. Crushing methods include impact system, compression system and shearing system. The shearing system shears and crushes refuses by using blades rotating at a low speed. The system has a wide range of crush ability and excellent versatility, generates low levels of dust, noise and vibration, and is suitable as a marine use refuse disposing apparatus. However, empty cans and PET bottles are more difficult of getting into cutting blades requiring a large amount of time for crushing. Therefore, it is more suitable to reduce volume of refuses by using a compressor or the like apparatuses, and then crush them by using a double-axial shearing crusher. Stylofoam causes its crushed pieces to be electrically charged and deposited onto the apparatus, hence it is more suitable to reduce the volume of refuses and make them brittle by heating, and then crush them by using the double-axial crusher. 2 figs.

Assessing Spontaneous Combustion Instability with Nonlinear Time Series Analysis

Science.gov (United States)

Eberhart, C. J.; Casiano, M. J.

2015-01-01

Considerable interest lies in the ability to characterize the onset of spontaneous instabilities within liquid propellant rocket engine (LPRE) combustion devices. Linear techniques, such as fast Fourier transforms, various correlation parameters, and critical damping parameters, have been used at great length for over fifty years. Recently, nonlinear time series methods have been applied to deduce information pertaining to instability incipiency hidden in seemingly stochastic combustion noise. A technique commonly used in biological sciences known as the Multifractal Detrended Fluctuation Analysis has been extended to the combustion dynamics field, and is introduced here as a data analysis approach complementary to linear ones. Advancing, a modified technique is leveraged to extract artifacts of impending combustion instability that present themselves a priori growth to limit cycle amplitudes. Analysis is demonstrated on data from J-2X gas generator testing during which a distinct spontaneous instability was observed. Comparisons are made to previous work wherein the data were characterized using linear approaches. Verification of the technique is performed by examining idealized signals and comparing two separate, independently developed tools.

Numerical analysis for controlling mixture heterogeneity to reduce abrupt combustion in diesel PCCI combustion

Energy Technology Data Exchange (ETDEWEB)

Nishiwaki, Kazuie [Ritsumeikan University (Japan); Kojima, Takafumi [Takamatsu National College of Technology (Japan)

2010-07-01

In the energy sector, stringent regulations have been implemented on combustion emissions in order to address health and environmental concerns and help improve air quality. A novel combustion mode, premixed charge compression ignition (PCCI), can improve the emissions performance of an engine over that of conventional diesel. The aim of this research is to develop a model to analyze the mixture formation in the PCCI combustion mode. A numerical model was developed and was applied to an engine and the results were compared to experimental results. It was found that the model results are in agreement with the experimental results. This paper presented a novel LES computer model and demonstrated that it is efficient in predicting the mixture formation in the PCCI combustion mode.

[Real time diagnostics of instantaneous temperature of combustion and explosion process by modern spectroscopy].

Science.gov (United States)

Zhou, Xue-tie; Wang, Jun-de; Li, Yan; Liu, Da-bing

2003-04-01

The combustion temperature is one of the important parameters to express flame combustion and explosion characteristics. It will effectively guide the design and manufacture of new model explosives, industrial explosive materials, and weapons. The recent developments and applications of real time diagnostics of instantaneous temperature of combustion and explosion processes by modern spectroscopic methods, such as atomic absorption-emission method, atomic emission two-line spectroscopy, atomic emission multiline spectroscopy, molecular rotation-vibration spectroscopy, coherent anti-stokes Raman scattering (CARS) and plane laser-induced fluorescence (PLIF), were reviewed in this paper. The maximum time resolution of atomic absorption-emission method is 25 microseconds. The time resolution of atomic emission two-line spectroscopy can reach 0.1 microsecond. These two methods can completely suit the need of real time and instantaneous temperature diagnostics of violent explosion and flame combustion. Other methods will also provide new effective research methods for the processes and characteristics of combustion, flame and explosion.

Strategies to reduce gaseous KCl and chlorine in deposits during combustion of biomass in fluidised bed boilers

Energy Technology Data Exchange (ETDEWEB)

Kassman, Haakan

2012-11-01

Combustion of a biomass with an enhanced content of alkali and chlorine (Cl) can result in operational problems including deposit formation and superheater corrosion. The strategies applied to reduce such problems include co-combustion and the use of additives. In this work, measures were investigated in order to decrease the risk of superheater corrosion by reducing gaseous KCl and the content of chlorine in deposits. The strategies applied were sulphation of KCl by sulphur/sulphate containing additives (i.e. elemental sulphur (S) and ammonium sulphate (AS)) and co-combustion with peat. Both sulphation of KCl and capture of potassium (K) in ash components can be of importance when peat is used. The experiments were mainly performed in a 12 MW circulation fluidised bed (CFB) boiler equipped for research purposes but also in a full-scale CFB boiler. The results were evaluated by means of IACM (on-line measurements of gaseous KCl), conventional gas analysis, deposit and corrosion probe measurements and ash analysis. Ammonium sulphate performed significantly better than elemental sulphur. Thus the presence of SO{sub 3} (i.e. AS) is of greater importance than that of SO{sub 2} (i.e. S) for sulphation of gaseous KCl and reduction of chlorine in deposits. Only a minor reduction of gaseous KCl was obtained during co-combustion with peat although chlorine in the deposits was greatly reduced. This reduction was supposedly due to capture of K by reactive components from the peat ash in parallel to sulphation of KCl. These compounds remained unidentified. The effect of volatile combustibles on the sulphation of gaseous KCl was investigated. The poorest sulphation was attained during injection of ammonium sulphate in the upper part of the combustion chamber during the lowest air excess ratio. The explanation for this is that SO{sub 3} was partly consumed by side reactions due to the presence of combustibles. These experimental results were supported by modelling, although the

In-cylinder pressure-based direct techniques and time frequency analysis for combustion diagnostics in IC engines

International Nuclear Information System (INIS)

D’Ambrosio, S.; Ferrari, A.; Galleani, L.

2015-01-01

Highlights: • Direct pressure-based techniques have been applied successfully to spark-ignition engines. • The burned mass fraction of pressure-based techniques has been compared with that of 2- and 3-zone combustion models. • The time frequency analysis has been employed to simulate complex diesel combustion events. - Abstract: In-cylinder pressure measurement and analysis has historically been a key tool for off-line combustion diagnosis in internal combustion engines, but online applications for real-time condition monitoring and combustion management have recently become popular. The present investigation presents and compares different low computing-cost in-cylinder pressure based methods for the analyses of the main features of combustion, that is, the start of combustion, the end of combustion and the crankshaft angle that responds to half of the overall burned mass. The instantaneous pressure in the combustion chamber has been used as an input datum for the described analytical procedures and it has been measured by means of a standard piezoelectric transducer. Traditional pressure-based techniques have been shown to be able to predict the burned mass fraction time history more accurately in spark ignition engines than in diesel engines. The most suitable pressure-based techniques for both spark ignition and compression ignition engines have been chosen on the basis of the available experimental data. Time–frequency analysis has also been applied to the analysis of diesel combustion, which is richer in events than spark ignited combustion. Time frequency algorithms for the calculation of the mean instantaneous frequency are computationally efficient, allow the main events of the diesel combustion to be identified and provide the greatest benefits in the presence of multiple injection events. These algorithms can be optimized and applied to onboard diagnostics tools designed for real control, but can also be used as an advanced validation tool for

Influence of Torrefaction on Single Particle Combustion of Wood

DEFF Research Database (Denmark)

Lu, Zhimin; Jian, Jie; Jensen, Peter Arendt

2016-01-01

This study focuses on the influence of torrefaction on the char reactivity, char yield, and combustion time of 3-5 mm spherical wood particles in a single particle combustion reactor (SPC) operating at a nominal temperature of 1231 °C. The devolatilization times were reduced and the char burnout...

Gradual combustion - method for nitrogen oxide suppression during brown coal combustion

Energy Technology Data Exchange (ETDEWEB)

Kotler, V.P.; Verzakov, V.N.; Lobov, T.V.

1990-10-01

Discusses combustion of brown coal in BKZ-500-140-1 boilers and factors that influence emission of nitrogen oxides. Temperature distribution in the furnace was evaluated. Effects of burner position, burner number and burner type as well as air excess ratio on chemical reactions during brown coal combustion, formation of nitrogen oxides and their emission were comparatively evaluated. Analyses showed that by optimum arrangement of burners and selecting the optimum air excess ratio a part of nitrogen oxides formed during the initial phase of combustion was reduced to molecular nitrogen in the second phase. On the basis of evaluations the following recommendations for furnace design are made: use of straight-flow burners characterized by a reduced mixing ratio with secondary air, parallel arrangement of burners which guarantees mixing of the combustion products from the burners with stable and unstable combustion (products of incomplete coal combustion), reducing the air excess ratio to below 1.0. 5 refs.

Development of a new reduced hydrogen combustion mechanism with NO_x and parametric study of hydrogen HCCI combustion using stochastic reactor model

International Nuclear Information System (INIS)

Maurya, Rakesh Kumar; Akhil, Nekkanti

2017-01-01

Highlights: • PDF based stochastic reactor model used for study of hydrogen HCCI engine. • New reduced hydrogen combustion mechanism with NOx developed (30 species and 253 reactions). • Mechanism predicts cylinder pressure and captures NO_x emission trend with sufficient accuracy. • Parametric study of hydrogen HCCI engine over wide range of speed and load conditions. • Hydrogen HCCI operating range increases with compression ratio & decreases with engine speed. - Abstract: Hydrogen is a potential alternative and renewable fuel for homogenous charge compression ignition (HCCI) engine to achieve higher efficiency and zero emissions of CO, unburned hydrocarbons as well as other greenhouse gases such as CO_2 and CH_4. In this study, a detailed hydrogen oxidation mechanism with NO_x was developed by incorporating additional species and NO_x reactions to the existing hydrogen combustion mechanism (10 species and 40 reactions). The detailed hydrogen combustion mechanism used in this study consists of 39 species and 311 reactions. A reduced mechanism consisting 30 species and 253 reactions was also developed by using directed relation graph (DRG) method from detailed mechanism. Developed mechanisms were validated with experimental data by HCCI engine simulation using stochastic reactor model. Sensitivity analysis was performed to identify the most important reactions in hydrogen combustion and NO_x formation in HCCI engine. Pathway analysis was also performed to analyze the important reaction pathways at different temperatures. Results revealed that H2 + HO2 [=] H + H2O2 and O2 + NNH [=] N2 + HO2 are the most significant reactions in the hydrogen HCCI combustion and NO_x formation respectively. Detailed parametric study of HCCI combustion was conducted using developed chemical kinetic model. Numerical simulations are performed at different engine operating condition by varying engine speed (1000–3000 rpm), intake air temperature (380–460 K), and compression

Maximizing Power Output in Homogeneous Charge Compression Ignition (HCCI) Engines and Enabling Effective Control of Combustion Timing

Science.gov (United States)

Saxena, Samveg

Homogeneous Charge Compression Ignition (HCCI) engines are one of the most promising engine technologies for the future of energy conversion from clean, efficient combustion. HCCI engines allow high efficiency and lower CO2 emission through the use of high compression ratios and the removal of intake throttle valves (like Diesel), and allow very low levels of urban pollutants like nitric oxide and soot (like Otto). These engines, however, are not without their challenges, such as low power density compared with other engine technologies, and a difficulty in controlling combustion timing. This dissertation first addresses the power output limits. The particular strategies for enabling high power output investigated in this dissertation focus on avoiding five critical limits that either damage an engine, drastically reduce efficiency, or drastically increase emissions: (1) ringing limits, (2) peak in-cylinder pressure limits, (3) misfire limits, (4) low intake temperature limits, and (5) excessive emissions limits. The research shows that the key factors that enable high power output, sufficient for passenger vehicles, while simultaneously avoiding the five limits defined above are the use of: (1) high intake air pressures allowing improved power output, (2) highly delayed combustion timing to avoid ringing limits, and (3) using the highest possible equivalence ratio before encountering ringing limits. These results are revealed by conducting extensive experiments spanning a wide range of operating conditions on a multi-cylinder HCCI engine. Second, this dissertation discusses strategies for effectively sensing combustion characteristics on a HCCI engine. For effective feedback control of HCCI combustion timing, a sensor is required to quantify when combustion occurs. Many laboratory engines use in-cylinder pressure sensors but these sensors are currently prohibitively expensive for wide-scale commercialization. Instead, ion sensors made from inexpensive sparkplugs

Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

Energy Technology Data Exchange (ETDEWEB)

Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

2011-12-22

The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting

Measures for a quality combustion (combustion chamber exit and downstream); Mesures pour une combustion de qualite (sortie de chambre de combustion et en aval)

Energy Technology Data Exchange (ETDEWEB)

Epinat, G. [APAVE Lyonnaise, 69 (France)

1996-12-31

After a review of the different pollutants related to the various types of stationary and mobile combustion processes (stoichiometric, reducing and oxidizing combustion), measures and analyses than may be used to ensure the quality and efficiency of combustion processes are reviewed: opacimeters, UV analyzers, etc. The regulation and control equipment for combustion systems are then listed, according to the generator capacity level

Experimental study of the effects of natural gas injection timing on the combustion performance and emissions of a turbocharged common rail dual-fuel engine

International Nuclear Information System (INIS)

Yang, Bo; Wei, Xing; Xi, Chengxun; Liu, Yifu; Zeng, Ke; Lai, Ming-Chia

2014-01-01

Highlights: • Natural gas injection timing has obvious effects on combustion of dual-fuel engine. • Combustion performance is improved with optimized natural gas injection timing. • BSHC and BSCO decreased with retarded natural gas injection timing at low load. • BSNO x increased at part load while reduced at high load with delay N.G. injection. • PM is very low and insensitive to the variation of natural gas injection timing. - Abstract: Natural gas combustion with pilot ignition has been considered to be one of the most promising ways to utilize natural gas in existing diesel engine without serious engine modification and it has been widely researched all over the world. In this study, three experiments of different loads (BMEP 0.240 MPa, 0.480 MPa and 0.767 MPa) were performed on a 2.8 L four-cylinder, natural gas manifold injection dual-fuel engine to investigate the effects of natural gas injection timing on engine combustion performance and emissions. The pilot injection parameters (pilot injection timing and pressure) and natural gas injection pressure remain constant at a speed of 1600 rpm in the experiment. The cylinder pressure, HRR, CoV imep , flame development duration, CA50 and brake thermal efficiency were analyzed. The results indicated that under low and part engine loads, the flame development duration and CA50 can be reduced by properly retarding natural gas injection timing, while the CoV imep increased with retarded natural gas injection timing. As a result, the brake thermal efficiency is increased and the combustion stability slightly deteriorates. Meanwhile, under low and part engine loads, PM emissions in the dual-fuel engine is much lower than that in conventional diesel engines, furthermore, at high load, the PM emissions are near zero. CO and HC emissions are reduced with retarded natural gas injection timing under low and part loads, however, NO x emissions are slightly increased. Under high load, the flame development duration

Study of combustion properties of a solid propellant by highly time-resolved passive FTIR

Energy Technology Data Exchange (ETDEWEB)

Zhang, Liming; Zhang, Lin; Li, Yan; Liu, Bingping; Wang, Junde [Laboratory of Advanced Spectroscopy, Nanjing University of Science and Technology, Nanjing 210014 (China)

2006-10-15

With a time resolution of 0.125 s and a spectral resolution of 4 cm{sup -1}, emission spectra of the combustion process of a solid propellant were recorded by highly time-resolved passive FTIR. Some gaseous combustion products, such as H{sub 2}O, CO, CO{sub 2}, NO and HCl, were distinguished by the characteristic emission band of each molecule. The equation for flame temperature calculation based on the diatomic molecule emission fine structure theory was improved through judicious utilization of the spectral running number 'm' which makes the temperature measurement simpler and faster. Some combustion information of the solid propellant had been given including the characteristic spectral profile, the distribution of the absolute spectral energy, the distribution of the combustion flame temperature, and the concentration distributions of HCl and NO versus burning time. The results will provide theoretical and experimental bases for improving the formula and raising combustion efficiency of solid propellant, and developing the design of rocket motor, infrared guidance and antiguidance systems. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

Combustion characteristics of crude jatropha oil droplets using rhodium liquid as a homogeneous combustion catalyst

Science.gov (United States)

Nanlohy, Hendry Y.; Wardana, I. N. G.; Hamidi, N.; Yuliati, L.

2018-01-01

Combustion characteristics of crude jatropha oil droplet at room temperature with and without catalyst have been studied experimentally. Its combustion characteristics have been observed by igniting the oil droplet on a junction of a thermocouple, and the combustion characteristics of oil droplets are observed using a high-speed camera. The results show that the uniqueness of crude jatropha oil as alternative fuel is evidenced by the different stages of combustion caused by thermal cracking in burning droplets. The results also show that the role of the catalyst is not only an accelerator agent, but there are other unique functions and roles as a stabilizer. Moreover, the results also found that the catalyst was able to shorten the ignition timing and burnout time. This phenomenon proves that the presence of catalysts alters and weakens the structure of the triglyceride geometry so that the viscosity and flash point is reduced, the fuel absorbs heat well and flammable.

Mechanisms and kinetics of granulated sewage sludge combustion.

Science.gov (United States)

Kijo-Kleczkowska, Agnieszka; Środa, Katarzyna; Kosowska-Golachowska, Monika; Musiał, Tomasz; Wolski, Krzysztof

2015-12-01

This paper investigates sewage sludge disposal methods with particular emphasis on combustion as the priority disposal method. Sewage sludge incineration is an attractive option because it minimizes odour, significantly reduces the volume of the starting material and thermally destroys organic and toxic components of the off pads. Additionally, it is possible that ashes could be used. Currently, as many as 11 plants use sewage sludge as fuel in Poland; thus, this technology must be further developed in Poland while considering the benefits of co-combustion with other fuels. This paper presents the results of experimental studies aimed at determining the mechanisms (defining the fuel combustion region by studying the effects of process parameters, including the size of the fuel sample, temperature in the combustion chamber and air velocity, on combustion) and kinetics (measurement of fuel temperature and mass changes) of fuel combustion in an air stream under different thermal conditions and flow rates. The combustion of the sludge samples during air flow between temperatures of 800 and 900°C is a kinetic-diffusion process. This process determines the sample size, temperature of its environment, and air velocity. The adopted process parameters, the time and ignition temperature of the fuel by volatiles, combustion time of the volatiles, time to reach the maximum temperature of the fuel surface, maximum temperature of the fuel surface, char combustion time, and the total process time, had significant impacts. Copyright © 2015 Elsevier Ltd. All rights reserved.

Simultaneous determination of devolatilization and char burnout times during fluidized bed combustion of coal

International Nuclear Information System (INIS)

Christofiedes, N.; Brown, R.C.

1992-01-01

In this paper, the authors investigate a method for simultaneous determination of devolatilization and char burnout times based on the analysis of CO 2 emissions from a fluidized bed combustor. The technique is non-intrusive and can be performed under realistic combustion conditions. The authors' method involves batching single-size coal samples in a fluidized bed combustor that is heated with propane gas or other fuel. Carbon dioxide profiles versus time for the batch tests are analyzed with a linear model to obtain characteristic time constants for coal devolatilization and char combustion which can be related to total devolatilization time and burnout time for a coal sample. The authors' approach does not require special sample preparation, can be performed in actual combustion equipment and employs standard boiler instrumentation

A reduced fidelity model for the rotary chemical looping combustion reactor

KAUST Repository

Iloeje, Chukwunwike O.

2017-01-11

The rotary chemical looping combustion reactor has great potential for efficient integration with CO capture-enabled energy conversion systems. In earlier studies, we described a one-dimensional rotary reactor model, and used it to demonstrate the feasibility of continuous reactor operation. Though this detailed model provides a high resolution representation of the rotary reactor performance, it is too computationally expensive for studies that require multiple model evaluations. Specifically, it is not ideal for system-level studies where the reactor is a single component in an energy conversion system. In this study, we present a reduced fidelity model (RFM) of the rotary reactor that reduces computational cost and determines an optimal combination of variables that satisfy reactor design requirements. Simulation results for copper, nickel and iron-based oxygen carriers show a four-order of magnitude reduction in simulation time, and reasonable prediction accuracy. Deviations from the detailed reference model predictions range from 3% to 20%, depending on oxygen carrier type and operating conditions. This study also demonstrates how the reduced model can be modified to deal with both optimization and design oriented problems. A parametric study using the reduced model is then applied to analyze the sensitivity of the optimal reactor design to changes in selected operating and kinetic parameters. These studies show that temperature and activation energy have a greater impact on optimal geometry than parameters like pressure or feed fuel fraction for the selected oxygen carrier materials.

System and method for reducing combustion dynamics and NO.sub.x in a combustor

Science.gov (United States)

Uhm, Jong H.; Johnson, Thomas Edward

2015-11-20

A system for reducing combustion dynamics and NO.sub.x in a combustor includes a tube bundle that extends radially across at least a portion of the combustor, wherein the tube bundle comprises an upstream surface axially separated from a downstream surface. A shroud circumferentially surrounds the upstream and downstream surfaces. A plurality of tubes extends through the tube bundle from the upstream surface through the downstream surface, wherein the downstream surface is stepped to produce tubes having different lengths through the tube bundle. A method for reducing combustion dynamics and NO.sub.x in a combustor includes flowing a working fluid through a plurality of tubes radially arranged between an upstream surface and a downstream surface of an end cap that extends radially across at least a portion of the combustor, wherein the downstream surface is stepped.

Low NOx combustion technologies for high-temperature natural gas combustion

International Nuclear Information System (INIS)

Flamme, Michael

1999-01-01

Because of the high process temperature which is required for some processes like glass melting and the high temperature to which the combustion air is preheated, NOx emission are extremely high. Even at these high temperatures, NOx emissions could be reduced drastically by using advanced combustion techniques such as staged combustion or flame-less oxidation, as experimental work has shown. In the case of oxy-fuel combustion, the NOx emission are also very high if conventional burners are used. The new combustion techniques achieve similar NOx reductions. (author)

Decrease of noxious emissions in the residual fuel oil combustion; Disminucion de emisiones nocivas en la combustion de aceite combustible residual

Energy Technology Data Exchange (ETDEWEB)

Mandoki W, Jorge [Econergia S. de R. L. de C. V. Mexico, D. F. (Mexico)

1994-12-31

The residual fuel oil combustion emits noxious substances such as carbonaceous particulate, nitrogen oxides, and sulfur trioxide at unacceptable levels. Water emulsified in the fuel substantially reduces such emissions, achieving besides, in most of the cases, a net saving in the fuel consumption. The beneficial effects are shown in burning the residual fuel oil as a water emulsion, as well as the method to produce an adequate emulsion. The emulsified fuel technology offers a low cost option to reduce air pollution. The fuel oil quality has been declining during the last decades due to: 1. Increase in the production of crude heavy oils, generally with higher content of asphaltens and sulfur. 2. Less availability of vacuum distillation residues due to its conversion into greater value products. 3. More intensive conversion processes such as catalytic cracking, visbreaking, etc. that increase the asphaltenes concentration in the bottoms, causing instability problems. 4. The increase in the vanadium and other metals content as the concentration of asphaltenes increases. The use of emulsified fuel oil provides an efficient and economical method to substantially reduce the noxious emissions to the atmosphere. The emulsion contains water particles in a diameter between 2 and 20 microns, uniformly distributed in the fuel oil, generally in a proportion generally of 5 to 10%; besides, it contains a tensioactive agent to assure a stable emulsion capable of withstanding the shearing forces of the pumping and distribution systems. When the atomized oil drops get into the combustion chamber, the emulsified water flashes into high pressure steam, originating a violent secondary atomization. The effect of this secondary atomization is the rupture of the oil drops of various hundred microns, producing drops of 5 to 15 microns in diameter. Since the necessary time for combustion is an exponential function of the drop diameter, a very substantial improvement in the combustion is

Technological methods of reducing the emissions of nitrogen oxides during the combustion of solid fuel

Energy Technology Data Exchange (ETDEWEB)

Kotler, V.R.

1981-01-01

For protecting the atmosphere from emissions of toxic NO /SUB x/ during combustion of fuel in boilers the amount of NO /SUB x/ can be reduced in the process of combustion, or the flue gases (FG) from the boiler can be cleaned. The latter method is bound up with the necessity for treatment of a large quantity of FG with a comparatively low concentration in them of nitrogen oxides, chemically stable and poorly soluble in water. The problem is complicated by the presence in the FG of SO /SUB x/, O/sub 2/, and solid particles. The method of purifying the FG is complicated and requires large capital investment and operating expenses. By laboratory studies in the All-Union Institute of Heat Engineering im. F.E. Dzerzhinskiy (VTI) it was established that thermal NO /SUB x/ is formed at a combustion temperature greater than or equal to 1550 /sup 0/C and that the 0/sub 2/ concentration and considerably less the temperature strongly affect NO /SUB x/ formation. On the basis of laboratory studies and industrial tests in the VTI, methods of reducing NO /SUB x/ emissions by large-scale boilers are recommended.

Possibility of reducing CO2 emissions from internal combustion engines

Science.gov (United States)

Drabik, Dawid; Mamala, Jarosław; Śmieja, Michał; Prażnowski, Krzysztof

2017-10-01

Article defines on the possibility of reduction CO2 of the internal combustion engine and presents the analysis based on originally conducted studies. The increase in overall engine efficiency is sought after by all engineers dealing with engine construction, one of the major ways to reduce CO2 emissions is to increase the compression ratio. The application of the compression ratio that has been increased constructional in the engine will, on one hand, bring about the increase in the theoretical efficiency, but, on the other hand, require a system for pressure control at a higher engine load in order to prevent engine knocking. For the purposes of the article there was carried out a number of studies and compiled results, and on their basis determined what have a major impact on the reducing CO2.

Combustion Characterization of Bio-derived Fuels and Additives

DEFF Research Database (Denmark)

Hashemi, Hamid

Climate change has become a serious concern nowadays. The main reason is believed to be the high emission of greenhouse gases, namely CO2 which is mainly produced from the combustion of fossil fuels. At the same time, energy demand has increased exponentially while the energy supply mainly depends...... on fossil fuels, especially for transportation. The practical strategy to address such problems in medium term is to increase the efficiency of combustion-propelled energy-production systems, as well as to reduce the net release of CO2 and other harmful pollutants, likely by using nonconventional fuels....... Modern internal combustion engines such as Homogeneous Charge Compression Ignition (HCCI) engines are more efficient and fuel-flexible compared to the conventional engines, making opportunities to reduce the release of greenhouse and other polluting gases to the environment. Combustion temperature...

Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

KAUST Repository

An, Yanzhao

2017-09-23

In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

KAUST Repository

An, Yanzhao; Jaasim, Mohammed; Vallinayagam, R.; Vedharaj, S.; Im, Hong G.; Johansson, Bengt.

2017-01-01

In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

A reduced fidelity model for the rotary chemical looping combustion reactor

International Nuclear Information System (INIS)

Iloeje, Chukwunwike O.; Zhao, Zhenlong; Ghoniem, Ahmed F.

2017-01-01

Highlights: • Methodology for developing a reduced fidelity rotary CLC reactor model is presented. • The reduced model determines optimal reactor configuration that meets design and operating requirements. • A 4-order of magnitude reduction in computational cost is achieved with good prediction accuracy. • Sensitivity studies demonstrate importance of accurate kinetic parameters for reactor optimization. - Abstract: The rotary chemical looping combustion reactor has great potential for efficient integration with CO_2 capture-enabled energy conversion systems. In earlier studies, we described a one-dimensional rotary reactor model, and used it to demonstrate the feasibility of continuous reactor operation. Though this detailed model provides a high resolution representation of the rotary reactor performance, it is too computationally expensive for studies that require multiple model evaluations. Specifically, it is not ideal for system-level studies where the reactor is a single component in an energy conversion system. In this study, we present a reduced fidelity model (RFM) of the rotary reactor that reduces computational cost and determines an optimal combination of variables that satisfy reactor design requirements. Simulation results for copper, nickel and iron-based oxygen carriers show a four-order of magnitude reduction in simulation time, and reasonable prediction accuracy. Deviations from the detailed reference model predictions range from 3% to 20%, depending on oxygen carrier type and operating conditions. This study also demonstrates how the reduced model can be modified to deal with both optimization and design oriented problems. A parametric study using the reduced model is then applied to analyze the sensitivity of the optimal reactor design to changes in selected operating and kinetic parameters. These studies show that temperature and activation energy have a greater impact on optimal geometry than parameters like pressure or feed fuel

The ChlorOut concept. A method to reduce alkali-related problems during combustion

Energy Technology Data Exchange (ETDEWEB)

Kassman, Haakan [ChlorOut AB c/o Vattenfall AB, Nykoeping (Sweden); Wollner, Lothar [Boehringer Ingelheim Pharma GmbH und Co. KG, Ingelheim am Rhein (Germany); Berg, Magnus [ChlorOut AB c/o Vattenfall AB, Stockholm (Sweden)

2013-06-01

Combustion of biomass with a high content of alkali and chlorine (Cl) can result in operational problems including deposit formation and superheater corrosion. The strategies applied to reduce such problems include co-combustion and the use of additives. Ammonium sulphate is a part of the ChlorOut concept which is applied in a range of commercial boilers. This concept is based on dosing of sulphate-containing additives to the flue gases and a unique measurement device for on-line measurement of gaseous alkali chlorides called IACM (in-situ alkali chloride monitor). The focus of the present paper is on evaluation of long-term experiences from two full-scale boilers. The operational problems with deposit formation and superheater corrosion decreased in these boilers after installing the ChlorOut concept. (orig.)

Pulsating combustion - Combustion characteristics and reduction of emissions

Energy Technology Data Exchange (ETDEWEB)

Lindholm, Annika

1999-11-01

In the search for high efficiency combustion systems pulsating combustion has been identified as one of the technologies that potentially can meet the objectives of clean combustion and good fuel economy. Pulsating combustion offers low emissions of pollutants, high heat transfer and efficient combustion. Although it is an old technology, the interest in pulsating combustion has been renewed in recent years, due to its unique features. Various applications of pulsating combustion can be found, mainly as drying and heating devices, of which the latter also have had commercial success. It is, however, in the design process of a pulse combustor, difficult to predict the operating frequency, the heat release etc., due to the lack of a well founded theory of the phenomenon. Research concerning control over the combustion process is essential for developing high efficiency pulse combustors with low emissions. Natural gas fired Helmholtz type pulse combustors have been the experimental objects of this study. In order to investigate the interaction between the fluid dynamics and the chemistry in pulse combustors, laser based measuring techniques as well as other conventional measuring techniques have been used. The experimental results shows the possibilities to control the combustion characteristics of pulsating combustion. It is shown that the time scales in the large vortices created at the inlet to the combustion chamber are very important for the operation of the pulse combustor. By increasing/decreasing the time scale for the large scale mixing the timing of the heat release is changed and the operating characteristics of the pulse combustor changes. Three different means for NO{sub x} reduction in Helmholtz type pulse combustors have been investigated. These include exhaust gas recirculation, alteration of air/fuel ratio and changed inlet geometry in the combustion chamber. All used methods achieved less than 10 ppm NO{sub x} emitted (referred to stoichiometric

Numerical Investigation Into Effect of Fuel Injection Timing on CAI/HCCI Combustion in a Four-Stroke GDI Engine

Science.gov (United States)

Cao, Li; Zhao, Hua; Jiang, Xi; Kalian, Navin

2006-02-01

The Controlled Auto-Ignition (CAI) combustion, also known as Homogeneous Charge Compression Ignition (HCCI), was achieved by trapping residuals with early exhaust valve closure in conjunction with direct injection. Multi-cycle 3D engine simulations have been carried out for parametric study on four different injection timings in order to better understand the effects of injection timings on in-cylinder mixing and CAI combustion. The full engine cycle simulation including complete gas exchange and combustion processes was carried out over several cycles in order to obtain the stable cycle for analysis. The combustion models used in the present study are the Shell auto-ignition model and the characteristic-time combustion model, which were modified to take the high level of EGR into consideration. A liquid sheet breakup spray model was used for the droplet breakup processes. The analyses show that the injection timing plays an important role in affecting the in-cylinder air/fuel mixing and mixture temperature, which in turn affects the CAI combustion and engine performance.

Understanding Combustion Processes Through Microgravity Research

Science.gov (United States)

Ronney, Paul D.

1998-01-01

A review of research on the effects of gravity on combustion processes is presented, with an emphasis on a discussion of the ways in which reduced-gravity experiments and modeling has led to new understanding. Comparison of time scales shows that the removal of buoyancy-induced convection leads to manifestations of other transport mechanisms, notably radiative heat transfer and diffusional processes such as Lewis number effects. Examples from premixed-gas combustion, non-premixed gas-jet flames, droplet combustion, flame spread over solid and liquid fuels, and other fields are presented. Promising directions for new research are outlined, the most important of which is suggested to be radiative reabsorption effects in weakly burning flames.

Development of rapid mixing fuel nozzle for premixed combustion

International Nuclear Information System (INIS)

Katsuki, Masashi; Chung, Jin Do; Kim, Jang Woo; Hwang, Seung Min; Kim, Seung Mo; Ahn, Chul Ju

2009-01-01

Combustion in high-preheat and low oxygen concentration atmosphere is one of the attractive measures to reduce nitric oxide emission as well as greenhouse gases from combustion devices, and it is expected to be a key technology for the industrial applications in heating devices and furnaces. Before proceeding to the practical applications, we need to elucidate combustion characteristics of non-premixed and premixed flames in high-preheat and low oxygen concentration conditions from scientific point of view. For the purpose, we have developed a special mixing nozzle to create a homogeneous mixture of fuel and air by rapid mixing, and applied this rapidmixing nozzle to a Bunsen-type burner to observe combustion characteristics of the rapid-mixture. As a result, the combustion of rapid-mixture exhibited the same flame structure and combustion characteristics as the perfectly prepared premixed flame, even though the mixing time of the rapid-mixing nozzle was extremely short as a few milliseconds. Therefore, the rapid-mixing nozzle in this paper can be used to create preheated premixed flames as far as the mixing time is shorter than the ignition delay time of the fuel

Reduced combustion mechanism for C1-C4 hydrocarbons and its application in computational fluid dynamics flare modeling.

Science.gov (United States)

Damodara, Vijaya; Chen, Daniel H; Lou, Helen H; Rasel, Kader M A; Richmond, Peyton; Wang, Anan; Li, Xianchang

2017-05-01

Emissions from flares constitute unburned hydrocarbons, carbon monoxide (CO), soot, and other partially burned and altered hydrocarbons along with carbon dioxide (CO 2 ) and water. Soot or visible smoke is of particular concern for flare operators/regulatory agencies. The goal of the study is to develop a computational fluid dynamics (CFD) model capable of predicting flare combustion efficiency (CE) and soot emission. Since detailed combustion mechanisms are too complicated for (CFD) application, a 50-species reduced mechanism, LU 3.0.1, was developed. LU 3.0.1 is capable of handling C 4 hydrocarbons and soot precursor species (C 2 H 2 , C 2 H 4 , C 6 H 6 ). The new reduced mechanism LU 3.0.1 was first validated against experimental performance indicators: laminar flame speed, adiabatic flame temperature, and ignition delay. Further, CFD simulations using LU 3.0.1 were run to predict soot emission and CE of air-assisted flare tests conducted in 2010 in Tulsa, Oklahoma, using ANSYS Fluent software. Results of non-premixed probability density function (PDF) model and eddy dissipation concept (EDC) model are discussed. It is also noteworthy that when used in conjunction with the EDC turbulence-chemistry model, LU 3.0.1 can reasonably predict volatile organic compound (VOC) emissions as well. A reduced combustion mechanism containing 50 C 1 -C 4 species and soot precursors has been developed and validated against experimental data. The combustion mechanism is then employed in the computational fluid dynamics (CFD) of modeling of soot emission and combustion efficiency (CE) of controlled flares for which experimental soot and CE data are available. The validated CFD modeling tools are useful for oil, gas, and chemical industries to comply with U.S. Environmental Protection Agency's (EPA) mandate to achieve smokeless flaring with a high CE.

Time-resolved analysis of particle emissions from residential biomass combustion - Emissions of refractory black carbon, PAHs and organic tracers

Science.gov (United States)

Nielsen, Ingeborg E.; Eriksson, Axel C.; Lindgren, Robert; Martinsson, Johan; Nyström, Robin; Nordin, Erik Z.; Sadiktsis, Ioannis; Boman, Christoffer; Nøjgaard, Jacob K.; Pagels, Joakim

2017-09-01

Time-resolved particle emissions from a conventional wood stove were investigated with aerosol mass spectrometry to provide links between combustion conditions, emission factors, mixing state of refractory black carbon and implications for organic tracer methods. The addition of a new batch of fuel results in low temperature pyrolysis as the fuel heats up, resulting in strong, short-lived, variable emission peaks of organic aerosol-containing markers of anhydrous sugars, such as levoglucosan (fragment at m/z 60). Flaming combustion results in emissions dominated by refractory black carbon co-emitted with minor fractions of organic aerosol and markers of anhydrous sugars. Full cycle emissions are an external mixture of larger organic aerosol-dominated and smaller thinly coated refractory black carbon particles. A very high burn rate results in increased full cycle mass emission factors of 66, 2.7, 2.8 and 1.3 for particulate polycyclic aromatic hydrocarbons, refractory black carbon, total organic aerosol and m/z 60, respectively, compared to nominal burn rate. Polycyclic aromatic hydrocarbons are primarily associated with refractory black carbon-containing particles. We hypothesize that at very high burn rates, the central parts of the combustion zone become air starved, leading to a locally reduced combustion temperature that reduces the conversion rates from polycyclic aromatic hydrocarbons to refractory black carbon. This facilitates a strong increase of polycyclic aromatic hydrocarbons emissions. At nominal burn rates, full cycle emissions based on m/z 60 correlate well with organic aerosol, refractory black carbon and particulate matter. However, at higher burn rates, m/z 60 does not correlate with increased emissions of polycyclic aromatic hydrocarbons, refractory black carbon and organic aerosol in the flaming phase. The new knowledge can be used to advance source apportionment studies, reduce emissions of genotoxic compounds and model the climate impacts of

A reduced mechanism for predicting the ignition timing of a fuel blend of natural-gas and n-heptane in HCCI engine

International Nuclear Information System (INIS)

Bahlouli, Keyvan; Atikol, Ugur; Khoshbakhti Saray, R.; Mohammadi, Vahid

2014-01-01

Highlights: • A two-stage reduction process is used to produce two reduced mechanisms. • The mechanisms are combined to develop a reaction mechanism for a fuel blend. • The genetic algorithm is used for optimization of reaction constants. • The developed reduced mechanism can be used to predict the ignition timing in HCCI engine for a fuel blend. - Abstract: One of the main challenges associated with homogeneous charge compression ignition (HCCI) combustion engine application is the lack of direct control on ignition timing. One of the solutions to this problem is mixing two fuels with various properties at a variety of ratios on a cycle-by-cycle basis. In the current study, a reduced mechanism for a fuel blend of natural-gas and n-heptane is proposed. The approach is validated for the prediction of ignition timing in the HCCI combustion engine. A single-zone combustion model is used to simulate the HCCI engine. A two-stage reduction process is used to produce two reduced mechanisms of existing semi-detailed GRI-Mech. 3.0 mechanism that contains 53 species and 325 reactions and Golovichev’s mechanism consisting of 57 species and 290 reactions for natural gas and n-heptane fuels, respectively. Firstly, the unimportant species and related reactions are identified by employing the directed relation graph with error propagation (DRGEP) reduction method and then, to extend reduction, the principal component analysis (PCA) method is utilized. To evaluate the validity of the reduced mechanism, representative engine combustion parameters such as peak pressure, maximum heat release, and CA50 are used. The reduced mechanism of GRI-Mech. 3.0 mechanism, containing 19 species and 39 reactions, and the reduced mechanism of Golovichev’s mechanism, consisting of 40 species and 95 reactions, provide good prediction for the mentioned parameters in comparison with those of detailed mechanisms. The combination of the generated reduced mechanisms is used to develop a

Real-time combustion control and diagnostics sensor-pressure oscillation monitor

Science.gov (United States)

Chorpening, Benjamin T [Morgantown, WV; Thornton, Jimmy [Morgantown, WV; Huckaby, E David [Morgantown, WV; Richards, George A [Morgantown, WV

2009-07-14

An apparatus and method for monitoring and controlling the combustion process in a combustion system to determine the amplitude and/or frequencies of dynamic pressure oscillations during combustion. An electrode in communication with the combustion system senses hydrocarbon ions and/or electrons produced by the combustion process and calibration apparatus calibrates the relationship between the standard deviation of the current in the electrode and the amplitudes of the dynamic pressure oscillations by applying a substantially constant voltage between the electrode and ground resulting in a current in the electrode and by varying one or more of (1) the flow rate of the fuel, (2) the flow rate of the oxidant, (3) the equivalence ratio, (4) the acoustic tuning of the combustion system, and (5) the fuel distribution in the combustion chamber such that the amplitudes of the dynamic pressure oscillations in the combustion chamber are calculated as a function of the standard deviation of the electrode current. Thereafter, the supply of fuel and/or oxidant is varied to modify the dynamic pressure oscillations.

Reducing NOx Emissions for a 600 MWe Down-Fired Pulverized-Coal Utility Boiler by Applying a Novel Combustion System.

Science.gov (United States)

Ma, Lun; Fang, Qingyan; Lv, Dangzhen; Zhang, Cheng; Chen, Yiping; Chen, Gang; Duan, Xuenong; Wang, Xihuan

2015-11-03

A novel combustion system was applied to a 600 MWe Foster Wheeler (FW) down-fired pulverized-coal utility boiler to solve high NOx emissions, without causing an obvious increase in the carbon content of fly ash. The unit included moving fuel-lean nozzles from the arches to the front/rear walls and rearranging staged air as well as introducing separated overfire air (SOFA). Numerical simulations were carried out under the original and novel combustion systems to evaluate the performance of combustion and NOx emissions in the furnace. The simulated results were found to be in good agreement with the in situ measurements. The novel combustion system enlarged the recirculation zones below the arches, thereby strengthening the combustion stability considerably. The coal/air downward penetration depth was markedly extended, and the pulverized-coal travel path in the lower furnace significantly increased, which contributed to the burnout degree. The introduction of SOFA resulted in a low-oxygen and strong-reducing atmosphere in the lower furnace region to reduce NOx emissions evidently. The industrial measurements showed that NOx emissions at full load decreased significantly by 50%, from 1501 mg/m3 (O2 at 6%) to 751 mg/m3 (O2 at 6%). The carbon content in the fly ash increased only slightly, from 4.13 to 4.30%.

Uncertainties in hydrogen combustion

International Nuclear Information System (INIS)

Stamps, D.W.; Wong, C.C.; Nelson, L.S.

1988-01-01

Three important areas of hydrogen combustion with uncertainties are identified: high-temperature combustion, flame acceleration and deflagration-to-detonation transition, and aerosol resuspension during hydrogen combustion. The uncertainties associated with high-temperature combustion may affect at least three different accident scenarios: the in-cavity oxidation of combustible gases produced by core-concrete interactions, the direct containment heating hydrogen problem, and the possibility of local detonations. How these uncertainties may affect the sequence of various accident scenarios is discussed and recommendations are made to reduce these uncertainties. 40 references

The effect of fan-induced turbulence on the combustion of hydrogen-air mixtures

International Nuclear Information System (INIS)

Kumar, R.K.; Tamm, H.

1984-01-01

The effect of fan-induced turbulence on the combustion of hydrogen-air mixtures has been studied in a 2.3-m diameter sphere over a hydrogen concentration range of 4 to 42% (by volume). Two fans were used to produce the turbulence, which was measured at various lacations by hot-wire anemometry. For low hydrogen concentrations (< 7%), turbulence increases the rate and extent of combustion; for large turbulence intensities the extent of combustion approaches 100%, and combustion times are reduced by factors of 8 to 10 from those observed under quiescent conditions. At high hydrogen concentrations, the effect of turbulence on combustion time is less pronounced than at low hydrogen concentrations. Flame-generated turbulence has a significant effect on the combustion rate. (orig.)

Effect of laser induced plasma ignition timing and location on Diesel spray combustion

International Nuclear Information System (INIS)

Pastor, José V.; García-Oliver, José M.; García, Antonio; Pinotti, Mattia

2017-01-01

Highlights: • Laser plasma ignition is applied to a direct injection Diesel spray, compared with auto-ignition. • Critical local fuel/air ratio for LIP provoked ignition is obtained. • The LIP system is able to stabilize Diesel combustion compared to auto-ignition cases. • Varying LIP position along spray axis directly affects Ignition-delay. • Premixed combustion is reduced both by varying position and delay of the LIP ignition system. - Abstract: An experimental study about the influence of the local conditions at the ignition location on combustion development of a direct injection spray is carried out in an optical engine. A laser induced plasma ignition system has been used to force the spray ignition, allowing comparison of combustion’s evolution and stability with the case of conventional autoignition on the Diesel fuel in terms of ignition delay, rate of heat release, spray penetration and soot location evolution. The local equivalence ratio variation along the spray axis during the injection process was determined with a 1D spray model, previously calibrated and validated. Upper equivalence ratios limits for the ignition event of a direct injected Diesel spray, both in terms of ignition success possibilities and stability of the phenomena, could been determined thanks to application of the laser plasma ignition system. In all laser plasma induced ignition cases, heat release was found to be higher than for the autoignition reference cases, and it was found to be linked to a decrease of ignition delay, with the premixed peak in the rate of heat release curve progressively disappearing as the ignition delay time gets shorter. Ignition delay has been analyzed as a function of the laser position, too. It was found that ignition delay increases for plasma positions closer to the nozzle, indicating that the amount of energy introduced by the laser induced plasma is not the only parameter affecting combustion initiation, but local equivalence ratio

SO2 emission reducing by Ca(OH)2 using at combustion of coal from East-Maritsa basin

International Nuclear Information System (INIS)

Batov, S.; Gadzhanov, P.; Popov, D.; Panchev, T.; Mikhajlov, Ya.; Shushulov, D.; Grozev, A.

1997-01-01

The 'Maritsa-Iztok' coal field contains about 65% of the lignite and 57% of the Bulgarian coal resources.The 'Maritsa-Iztok' lignite coal have a low combustion temperature and high concentration of ashes, moisture and sulfur. The concentration of sulphur oxides emitted is about 800 000 t per year, which is among the highest concentrations for Europe. In order to reduce the sulphur concentration, theoretical and experimental studies have been performed. A determination of the efficiency of some new methods for SO 2 reduction has been done. In this paper the results from experiments using Ca(OH) 2 as reagent, are presented. The experimental facility is a non-cooled combustion chamber which provides the same conditions as in the lignite coal boilers. In the experiments ground and dried lignite coal have been used. The controlled values are O 2 , CO, NO x , SO 2 , as well as the temperature of the hot and cold air and the combustion products after the cooler and absorber. Four different technologies have been performed. The first is adding of Ca(OH) 2 which give about 30% maximal SO 2 reducing for grain size 45μm and Ca/S=1.6. The obtaining of this small size is now difficult. The second technology is introduction of Ca(OH) 2 in the combustion chamber at a temperature 900-1050 o C. The cleaning efficiency is about 48.5% for the optimal concentration of the additive. As a washing of the combustion product with water in the absorber after the desulfurization. The second phase give 20% additional cleaning. Thus the total cleaning effect is 65-70%. The third method used lime washing of the combustion products. For the Bulgarian coal with a great S content it is the most suitable method. It gives a SO 2 cleaning up to 95%. Lime wash with pH=12.3 has been used with various amounts of the reagent. Experiments with different amounts of lime wash and different quality of the coal are performed and the specific reagent consumption has been determined

Reducing automotive emissions—The potentials of combustion engine technologies and the power of policy

International Nuclear Information System (INIS)

Berggren, Christian; Magnusson, Thomas

2012-01-01

Reducing transport emissions, in particular vehicular emissions, is a key element for mitigating the risks of climate change. In much of the academic and public discourse the focus has been on alternative vehicle technologies and fuels (e.g. electric cars, fuel cells and hydrogen), whereas vehicles based on internal combustion engines have been perceived as close to their development limits. This paper offers a different perspective by demonstrating the accelerated improvement processes taking place in established combustion technologies as a result of a new competition between manufacturers and technologies, encouraged both by more stringent EU legislation and new CAFE levels in the US. The short-term perspective is complemented by an analysis of future improvement potentials in internal combustion technologies, which may be realized if efficient regulation is in place. Based on a comparison of four different regulatory approaches, the paper identifies the need for a long-term technology-neutral framework with stepwise increasing stringencies, arguing that this will encourage continual innovation and diffusion in the most effective way. - Highlights: ► From 1990 to 2008, CO 2 emissions from road transportation in the EU increased by 21%. ► Alternative vehicles are important, but internal combustion engines (ICE) will remain dominant. ► The paper shows how competition and new regulation accelerate the improvement of ICE-vehicles. ► The key factor for long-term emissions reduction is appropriate regulation, not technology. ► Most effective is a technology-neutral framework with stepwise increasing stringencies.

Experimental validation for combustion analysis of GOTHIC code in 2-dimensional combustion chamber

International Nuclear Information System (INIS)

Lee, J. W.; Yang, S. Y.; Park, K. C.; Jung, S. H.

2002-01-01

In this study, the prediction capability of GOTHIC code for hydrogen combustion phenomena was validated with the results of two-dimensional premixed hydrogen combustion experiment executed by Seoul National University. The experimental chamber has about 24 liter free volume (1x0.024x1 m 3 ) and 2-dimensional rectangular shape. The test were preformed with 10% hydrogen/air gas mixture and conducted with combination of two igniter positions (top center, top corner) and two boundary conditions (bottom full open, bottom right half open). Using the lumped parameter and mechanistic combustion model in GOTHIC code, the SNU experiments were simulated under the same conditions. The GOTHIC code prediction of the hydrogen combustion phenomena did not compare well with the experimental results. In case of lumped parameter simulation, the combustion time was predicted appropriately. But any other local information related combustion phenomena could not be obtained. In case of mechanistic combustion analysis, the physical combustion phenomena of gas mixture were not matched experimental ones. In boundary open cases, the GOTHIC predicted very long combustion time and the flame front propagation could not simulate appropriately. Though GOTHIC showed flame propagation phenomenon in adiabatic calculation, the induction time of combustion was still very long compare with experimental results. Also, it was found that the combustion model of GOTHIC code had some weak points in low concentration of hydrogen combustion simulation

NOx Emission Reduction by Oscillating Combustion

Energy Technology Data Exchange (ETDEWEB)

John C. Wagner

2004-03-31

High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

NOx Emission Reduction by Oscillating combustion

Energy Technology Data Exchange (ETDEWEB)

Institute of Gas Technology

2004-01-30

High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

Rapid tomographic reconstruction based on machine learning for time-resolved combustion diagnostics

Science.gov (United States)

Yu, Tao; Cai, Weiwei; Liu, Yingzheng

2018-04-01

Optical tomography has attracted surged research efforts recently due to the progress in both the imaging concepts and the sensor and laser technologies. The high spatial and temporal resolutions achievable by these methods provide unprecedented opportunity for diagnosis of complicated turbulent combustion. However, due to the high data throughput and the inefficiency of the prevailing iterative methods, the tomographic reconstructions which are typically conducted off-line are computationally formidable. In this work, we propose an efficient inversion method based on a machine learning algorithm, which can extract useful information from the previous reconstructions and build efficient neural networks to serve as a surrogate model to rapidly predict the reconstructions. Extreme learning machine is cited here as an example for demonstrative purpose simply due to its ease of implementation, fast learning speed, and good generalization performance. Extensive numerical studies were performed, and the results show that the new method can dramatically reduce the computational time compared with the classical iterative methods. This technique is expected to be an alternative to existing methods when sufficient training data are available. Although this work is discussed under the context of tomographic absorption spectroscopy, we expect it to be useful also to other high speed tomographic modalities such as volumetric laser-induced fluorescence and tomographic laser-induced incandescence which have been demonstrated for combustion diagnostics.

Effects of Noise and Time Delay Upon Active Control of Combustion Instabilities

National Research Council Canada - National Science Library

Zinn, Ben

2001-01-01

To improve the performance of practical active control system (ACS) for unstable combustors, the effects of system noise and ACS time delay upon combustion instabilities and the ACS performance were studied...

Volatiles and char combustion rates of demineralised lignite and wood blends

International Nuclear Information System (INIS)

Yilgin, Melek; Pehlivan, Dursun

2009-01-01

Today, much interest is given to the utilisation of materials of plant origin as substitutions of fossil fuels in meeting energy needs to reduce the level of atmospheric pollutant emissions and global warming threat, and emphasis has been placed on the co-combustion of coal and biomass. In this study, volatiles and char combustion behaviour of the fuel pellets composed from demineralised lignite and poplar wood sawdust, were investigated in a cylindrical wire mesh basket placed in a preheated tube furnace. The results have shown that ignition times of the pellets decreased with the burning temperature and shortened further due to demineralisation of lignite. Volatiles combustion rates of the samples did not correlate well with combustion times. However, they can be correlated with their respective proximate volatile matter contents. Char burnout times decreased with increasing combustion rates and correlated well with the respective proximate fixed carbon contents of the samples. Deviations were more considerable in the case of rate data. (author)

Reduced Order Modeling of Combustion Instability in a Gas Turbine Model Combustor

Science.gov (United States)

Arnold-Medabalimi, Nicholas; Huang, Cheng; Duraisamy, Karthik

2017-11-01

Hydrocarbon fuel based propulsion systems are expected to remain relevant in aerospace vehicles for the foreseeable future. Design of these devices is complicated by combustion instabilities. The capability to model and predict these effects at reduced computational cost is a requirement for both design and control of these devices. This work focuses on computational studies on a dual swirl model gas turbine combustor in the context of reduced order model development. Full fidelity simulations are performed utilizing URANS and Hybrid RANS-LES with finite rate chemistry. Following this, data decomposition techniques are used to extract a reduced basis representation of the unsteady flow field. These bases are first used to identify sensor locations to guide experimental interrogations and controller feedback. Following this, initial results on developing a control-oriented reduced order model (ROM) will be presented. The capability of the ROM will be further assessed based on different operating conditions and geometric configurations.

Effect of Variant End of Injection Period on Combustion Process of Biodiesel Combustion

Directory of Open Access Journals (Sweden)

Khalid Amir

2016-01-01

Full Text Available Biodiesel is an alternative fuel as a replacement to the standard diesel fuel in combustion diesel engine. The biodiesel fuel has a significantly influences throughout the combustion process and exhaust emission. The purpose of this research is to investigate the combustion process behavior during the End of Injection (EOI period and operates under variant conditions using Rapid Compression Machine (RCM. Experimental of RCM is used to simulate a combustion process and combustion characteristics of diesel engine combustion. Three types of biodiesel blend which are B5, B10 and B15 were tested at several injection pressures of 80 MPa, 90 MPa and 130 MPa under different ambient temperatures, 750 K to 1100 K. The results of this study showed that the ignition delay slightly reduced with increasing the content of biodiesel blends from B5, B10 and B15 and became more shorten as the injection pressure been enhanced. As the injection pressure increased, the behavior of combustion pressure at end of injection is reduced, radically increased the NOX emission. It is noted that the process of combustion at the end of injection increased as the ambient temperature is rising. In fact, higher initial ambient temperature improved the fuel atomization and mixing process. Under the biodiesel combustion with higher ambient temperature condition, the exhaust emission of CO, O2, and HC became less but increased in NOX emission. Besides, increased in blends of biodiesel ratio are found to enhance the combustion process, resulted a decreased in HC emissions.

Effects of Pilot Injection Timing and EGR on Combustion, Performance and Exhaust Emissions in a Common Rail Diesel Engine Fueled with a Canola Oil Biodiesel-Diesel Blend

Directory of Open Access Journals (Sweden)

Jun Cong Ge

2015-07-01

Full Text Available Biodiesel as a clean energy source could reduce environmental pollution compared to fossil fuel, so it is becoming increasingly important. In this study, we investigated the effects of different pilot injection timings from before top dead center (BTDC and exhaust gas recirculation (EGR on combustion, engine performance, and exhaust emission characteristics in a common rail diesel engine fueled with canola oil biodiesel-diesel (BD blend. The pilot injection timing and EGR rate were changed at an engine speed of 2000 rpm fueled with BD20 (20 vol % canola oil and 80 vol % diesel fuel blend. As the injection timing advanced, the combustion pressure, brake specific fuel consumption (BSFC, and peak combustion pressure (Pmax changed slightly. Carbon monoxide (CO and particulate matter (PM emissions clearly decreased at BTDC 20° compared with BTDC 5°, but nitrogen oxide (NOx emissions increased slightly. With an increasing EGR rate, the combustion pressure and indicated mean effective pressure (IMEP decreased slightly at BTDC 20° compared to other injection timings. However, the Pmax showed a remarkable decrease. The BSFC and PM emissions increased slightly, but the NOx emission decreased considerably.

Effect of main injection timing for controlling the combustion phasing of a homogeneous charge compression ignition engine using a new dual injection strategy

International Nuclear Information System (INIS)

Das, Pranab; Subbarao, P.M.V.; Subrahmanyam, J.P.

2015-01-01

Highlights: • A new dual injection concept is developed by minimum geometry modification. • The occurrence of combustion parameters strongly depend on main injection timing. • At higher load, premixed equivalence ratio dominates over main injection timing. • Retarded of main injection timing tends to retard combustion phasing. • Slightly retarded main injection timing is recommended to avoid intense knocking. - Abstract: Homogeneous charge compression ignition combustion of diesel fuel is implemented using a novel dual injection strategy. A new experimental technique is developed to modify a single cylinder direct injection diesel engine to run on homogeneous combustion mode. Effect of main injection timing is investigated covering a range from 26 to 8 crank angle degrees before top dead center with an interval of 3°. Retarded main injection timing is identified as a control strategy for delaying combustion phasing and a means of controlled combustion phasing of direct injection homogeneous charge compression ignition combustion. Two load conditions were investigated and it was observed that at higher load, start of combustion depends more on fuel air equivalence ratio than main injection timing, whereas at low load, it significantly varies with varying main injection timing. Significant improvements in smoke and oxides of nitrogen emissions are observed when compared with the baseline conventional combustion. By studying different combustion parameters, it is observed that there is an improvement in performance and emissions with marginal loss in thermal efficiency when the main injection timing is 20° before top dead center. This is identified as the optimum main injection timing for such homogeneous combustion under the same operating condition

Combustion Stratification for Naphtha from CI Combustion to PPC

KAUST Repository

Vallinayagam, R.

2017-03-28

This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON = 46). The motored pressure at TDC is maintained at 35 bar and fuelMEP is kept constant at 5.1 bar to account for the difference in fuel properties between naphtha and diesel. Single injection strategy is employed and the fuel is injected at a pressure of 800 bar. Photron FASTCAM SA4 that captures in-cylinder combustion at the rate of 10000 frames per second is employed. The captured high speed video is processed to study the combustion homogeneity based on an algorithm reported in previous studies. Starting from late fuel injection timings, combustion stratification is investigated by advancing the fuel injection timings. For late start of injection (SOI), a direct link between SOI and combustion phasing is noticed. At early SOI, combustion phasing depends on both intake air temperature and SOI. In order to match the combustion phasing (CA50) of diesel, the intake air temperature is increased to 90°C for naphtha. The combustion stratification from CI to PPC is also investigated for various level of dilution by displacing oxygen with nitrogen in the intake. The start of combustion (SOC) was delayed with the increase in dilution and to compensate for this, the intake air temperature is increased. The mixture homogeneity is enhanced for higher dilution due to longer ignition delay. The results show that high speed image is initially blue and then turned yellow, indicating soot formation and oxidation. The luminosity of combustion images decreases with early SOI and increased dilution. The images are processed to generate the level of stratification based on the image intensity. The level of stratification is same for diesel and naphtha at various SOI. When O concentration in the intake is decreased to 17.7% and 14

Catalytic Combustion of Gasified Waste

Energy Technology Data Exchange (ETDEWEB)

Kusar, Henrik

2003-09-01

This thesis concerns catalytic combustion for gas turbine application using a low heating-value (LHV) gas, derived from gasified waste. The main research in catalytic combustion focuses on methane as fuel, but an increasing interest is directed towards catalytic combustion of LHV fuels. This thesis shows that it is possible to catalytically combust a LHV gas and to oxidize fuel-bound nitrogen (NH{sub 3}) directly into N{sub 2} without forming NO{sub x} The first part of the thesis gives a background to the system. It defines waste, shortly describes gasification and more thoroughly catalytic combustion. The second part of the present thesis, paper I, concerns the development and testing of potential catalysts for catalytic combustion of LHV gases. The objective of this work was to investigate the possibility to use a stable metal oxide instead of noble metals as ignition catalyst and at the same time reduce the formation of NO{sub x} In paper II pilot-scale tests were carried out to prove the potential of catalytic combustion using real gasified waste and to compare with the results obtained in laboratory scale using a synthetic gas simulating gasified waste. In paper III, selective catalytic oxidation for decreasing the NO{sub x} formation from fuel-bound nitrogen was examined using two different approaches: fuel-lean and fuel-rich conditions. Finally, the last part of the thesis deals with deactivation of catalysts. The various deactivation processes which may affect high-temperature catalytic combustion are reviewed in paper IV. In paper V the poisoning effect of low amounts of sulfur was studied; various metal oxides as well as supported palladium and platinum catalysts were used as catalysts for combustion of a synthetic gas. In conclusion, with the results obtained in this thesis it would be possible to compose a working catalytic system for gas turbine application using a LHV gas.

Experimental and numerical studies on two-stage combustion of biomass

Energy Technology Data Exchange (ETDEWEB)

Houshfar, Eshan

2012-07-01

In this thesis, two-stage combustion of biomass was experimentally/numerically investigated in a multifuel reactor. The following emissions issues have been the main focus of the work: 1- NOx and N2O 2- Unburnt species (CO and CxHy) 3- Corrosion related emissions.The study had a focus on two-stage combustion in order to reduce pollutant emissions (primarily NOx emissions). It is well known that pollutant emissions are very dependent on the process conditions such as temperature, reactant concentrations and residence times. On the other hand, emissions are also dependent on the fuel properties (moisture content, volatiles, alkali content, etc.). A detailed study of the important parameters with suitable biomass fuels in order to optimize the various process conditions was performed. Different experimental studies were carried out on biomass fuels in order to study the effect of fuel properties and combustion parameters on pollutant emissions. Process conditions typical for biomass combustion processes were studied. Advanced experimental equipment was used in these studies. The experiments showed the effects of staged air combustion, compared to non-staged combustion, on the emission levels clearly. A NOx reduction of up to 85% was reached with staged air combustion using demolition wood as fuel. An optimum primary excess air ratio of 0.8-0.95 was found as a minimizing parameter for the NOx emissions for staged air combustion. Air staging had, however, a negative effect on N2O emissions. Even though the trends showed a very small reduction in the NOx level as temperature increased for non-staged combustion, the effect of temperature was not significant for NOx and CxHy, neither in staged air combustion or non-staged combustion, while it had a great influence on the N2O and CO emissions, with decreasing levels with increasing temperature. Furthermore, flue gas recirculation (FGR) was used in combination with staged combustion to obtain an enhanced NOx reduction. The

Combustion of Jordanian oil shale using circulating fluidized bed

International Nuclear Information System (INIS)

Hamdan, M.; Al-Azzam, S.

1998-11-01

this study re[resents design and manufacturing of a lab-scale circulating fluidized bed (C.F.B) to burn low grade fuel such as Jordanian oil shale. Hydrodynamic properties of C.F.B. were studied like minimum fluidization velocity, circulation flux and carryover rate. a hot run was firstly conducted by the combustion of L.P.G. to start up the combustion process. It proceeds until reaching the minimum burning temperature of oil shale particles, at which time the LPG supply was gradually reduced and oil shale feeding started. soon after reaching a self sustainable condition of oil shale particles, the LPG supply was cut off. The main combustion variables were investigated such as air to fuel ratios, temperature profiles across the bed, exhaust gas analysis and combustion efficiency. a combustion intensity of 859 kg/hr.m 2 and combustion efficiency of 96% were achieved. (authors). 19 refs., 9 tab., 18 fig

Development of flameless combustion; Desarrollo de la combustion sin flama

Energy Technology Data Exchange (ETDEWEB)

Flores Sauceda, M. Leonardo; Cervantes de Gortari, Jaime Gonzalo [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)]. E-mail: 8344afc@prodigy.net.mx; jgonzalo@servidor.unam.mx

2010-11-15

The paper intends contribute to global warming mitigation joint effort that develops technologies to capture the CO{sub 2} produced by fossil fuels combustion and to reduce emission of other greenhouse gases like the NO{sub x}. After reviewing existing combustion bibliography is pointed out that (a) touches only partial aspects of the collective system composed by Combustion-Heat transfer process-Environment, whose interactions are our primary interest and (b) most specialists think there is not yet a clearly winning technology for CO{sub 2} capture and storage. In this paper the study of combustion is focused as integrated in the aforementioned collective system where application of flameless combustion, using oxidant preheated in heat regenerators and fluent gas recirculation into combustion chamber plus appropriated heat and mass balances, simultaneously results in energy saving and environmental impact reduction. [Spanish] El trabajo pretende contribuir al esfuerzo conjunto de mitigacion del calentamiento global que aporta tecnologias para capturar el CO{sub 2} producido por la combustion de combustibles fosiles y para disminuir la emision de otros gases invernadero como NOx. De revision bibliografica sobre combustion se concluye que (a) trata aspectos parciales del sistema compuesto por combustion-proceso de trasferencia de calor-ambiente, cuyas interacciones son nuestro principal interes (b) la mayoria de especialistas considera no hay todavia una tecnologia claramente superior a las demas para captura y almacenaje de CO{sub 2}. Se estudia la combustion como parte integrante del mencionado sistema conjunto, donde la aplicacion de combustion sin flama, empleando oxidante precalentado mediante regeneradores de calor y recirculacion de gases efluentes ademas de los balances de masa y energia adecuados, permite tener simultaneamente ahorros energeticos e impacto ambiental reducido.

Controlling the heat release in HCCI combustion of DME with methanol and EGR

DEFF Research Database (Denmark)

Pedersen, Troels Dyhr; Schramm, Jesper; Yanai, Tadanori

2010-01-01

quantity required was determined. The added methanol increased the BMEP by increasing the total heat release and retarding the combustion to after TDC. Engine knock was reduced with increasing quantities of methanol. The highest BMEP was achieved when the equivalence ratio of methanol was around 0.......12 at 1000 RPM, and around 0.76 at 1800 RPM. EGR was also used to retarding the timing. With a moderate amount of EGR the effect on the combustion was not notable, but as the equivalence ratio approached unity the combustion was increasingly delayed and the rate of reaction reduced. Engine knock seized...

Effects of Injection Timing on Fluid Flow Characteristics of Partially Premixed Combustion Based on High-Speed Particle Image Velocimetry

KAUST Repository

Izadi Najafabadi, Mohammad

2017-03-28

Partially Premixed Combustion (PPC) is a promising combustion concept ,based on judicious tuning of the charge stratification, to meet the increasing demands of emission legislation and to improve fuel efficiency. Longer ignition delays of PPC in comparison with conventional diesel combustion provide better fuel/air mixture which decreases soot and NO emissions. Moreover, a proper injection timing and strategy for PPC can improve the combustion stability as a result of a higher level of fuel stratification in comparison with the Homogeneous Charge Compression Ignition (HCCI) concept. Injection timing is the major parameter with which to affect the level of fuel and combustion stratification and to control the combustion phasing and the heat release behavior. The scope of the present study is to investigate the fluid flow characteristics of PPC at different injection timings. To this end, high-speed Particle Image Velocimetry (PIV) is implemented in a light-duty optical engine to measure fluid flow characteristics, including the flow fields, mean velocity and cycle-resolved turbulence, inside the piston bowl as well as the squish region with a temporal resolution of 1 crank angle degree at 800 rpm. Two injectors, having 5 and 7 holes, were compared to see their effects on fluid flow and heat release behavior for different injection timings. Reactive and non-reactive measurements were performed to distinguish injection-driven and combustion-driven turbulence. Formation of vortices and higher turbulence levels enhance the air/fuel interaction, changing the level of fuel stratification and combustion duration. Results demonstrate clearly how turbulence level correlates with heat release behavior, and provide a quantitative dataset for validation of numerical simulations.

Experimental evaluation of main emissions during coal processing waste combustion.

Science.gov (United States)

Dmitrienko, Margarita A; Legros, Jean C; Strizhak, Pavel A

2018-02-01

The total volume of the coal processing wastes (filter cakes) produced by Russia, China, and India is as high as dozens of millions of tons per year. The concentrations of CO and CO 2 in the emissions from the combustion of filter cakes have been measured directly for the first time. They are the biggest volume of coal processing wastes. There have been many discussions about using these wastes as primary or secondary components of coal-water slurries (CWS) and coal-water slurries containing petrochemicals (CWSP). Boilers have already been operationally tested in Russia for the combustion of CWSP based on filter cakes. In this work, the concentrations of hazardous emissions have been measured at temperatures ranging from 500 to 1000°С. The produced CO and CO 2 concentrations are shown to be practically constant at high temperatures (over 900°С) for all the coal processing wastes under study. Experiments have shown the feasibility to lowering the combustion temperatures of coal processing wastes down to 750-850°С. This provides sustainable combustion and reduces the CO and CO 2 emissions 1.2-1.7 times. These relatively low temperatures ensure satisfactory environmental and energy performance of combustion. Using CWS and CWSP instead of conventional solid fuels significantly reduces NO x and SO x emissions but leaves CO and CO 2 emissions practically at the same level as coal powder combustion. Therefore, the environmentally friendly future (in terms of all the main atmospheric emissions: CO, CO 2 , NO x , and SO x ) of both CWS and CWSP technologies relies on low-temperature combustion. Copyright © 2017 Elsevier Ltd. All rights reserved.

Fuel spray and combustion characteristics of butanol blends in a constant volume combustion chamber

International Nuclear Information System (INIS)

Liu, Yu; Li, Jun; Jin, Chao

2015-01-01

Highlights: • A sudden drop is observed in spray penetration for B10S10D80 fuel at 800 and 900 K. • With increasing of temperature, auto-ignition timings of fuels become unperceivable. • Low n-butanol addition has little effect on autoignition timings from 800 to 1200 K. • n-Butanol additive can reduce soot emissions at the near-wall regions. • Larger soot reduction is seen at higher ambient temperatures for n-butanol addition. - Abstract: The processes of spray penetrations, flame propagation and soot formation and oxidation fueling n-butanol/biodiesel/diesel blends were experimentally investigated in a constant volume combustion chamber with an optical access. B0S20D80 (0% n-butanol, 20% soybean biodiesel, and 80% diesel in volume) was prepared as the base fuel. n-Butanol was added into the base fuel by volumetric percent of 5% and 10%, denoted as B5S15D80 (5% n-butanol/15% soybean biodiesel/80% diesel) and B10S10D80 (10% n-butanol/10% soybean biodiesel/80% diesel). The ambient temperatures at the time of fuel injection were set to 800 K, 900 K, 1000 K, and 1200 K. Results indicate that the penetration length reduces with the increase of n-butanol volumes in blending fuels and ambient temperatures. The spray penetration presents a sudden drop as fueling B10S10D80 at 800 K and 900 K, which might be caused by micro-explosion. A larger premixed combustion process is observed at low ambient temperatures, while the heat release rate of high ambient temperatures presents mixing controlled diffusion combustion. With a lower ambient temperature, the auto-ignition delay becomes longer with increasing of n-butanol volume in blends. However, with increasing of ambient temperatures, the auto-ignition timing between three fuels becomes unperceivable. Generally, low n-butanol addition has a limited or no effect on the auto-ignition timing in the current conditions. Compared with the base fuel of B0S20D80, n-butanol additive with 5% or 10% in volume can reduce soot

The effect of insulated combustion chamber surfaces on direct-injected diesel engine performance, emissions, and combustion

Science.gov (United States)

Dickey, Daniel W.; Vinyard, Shannon; Keribar, Rifat

1988-01-01

The combustion chamber of a single-cylinder, direct-injected diesel engine was insulated with ceramic coatings to determine the effect of low heat rejection (LHR) operation on engine performance, emissions, and combustion. In comparison to the baseline cooled engine, the LHR engine had lower thermal efficiency, with higher smoke, particulate, and full load carbon monoxide emissions. The unburned hydrocarbon emissions were reduced across the load range. The nitrous oxide emissions increased at some part-load conditions and were reduced slightly at full loads. The poor LHR engine performance was attributed to degraded combustion characterized by less premixed burning, lower heat release rates, and longer combustion duration compared to the baseline cooled engine.

Combustion of Waste Wood. Second phase of the collaboration project on waste wood combustion

International Nuclear Information System (INIS)

Andersson, Annika; Andersson, Christer; Eriksson, Jan; Hemstroem, Bengt; Jungstedt, Jenny; Kling, Aasa; Bahr, Bo von; Ekvall, Annika; Eskilsson, David; Tullin, Claes; Harnevie, Henrik; Sieurin, Jan; Keihaes, Juha; Mueller, Christian; Berg, Magnus; Wikman, Karin

2003-08-01

Combustion of waste wood has during the last decade increased dramatically and this has resulted in a number of Swedish plants using this fuel, e.g. Handeloe P11 (Norrkoeping) and ldbaecken P3 (Nykoeping), and yet other plants that are under construction (e.g. Nynaeshamn). The experience from these plants are that waste wood combustion results in a number of operational problems. To some extent these problems are different compared with the problems related to combustion of other biofuels but the situation is not directly comparable to waste incinerators. The problems are mainly related to slagging and fouling of heat exchanger surfaces and accelerated corrosion at relatively low temperature compared to the situation for ordinary biofuels. In some cases an increase in the emissions of specific substances can also result in difficulties to fulfil the EC-directive on waste combustion. Within previous projects the main problems related to combustion of waste wood have been identified and to some extent the cause of these problems has been clarified. One result of this reported investigation is a deeper understanding of the actual causes of these problems. However, the most important result is a number of recommendations for different measures on how to achieve disturbance-free combustion of waste wood. These recommendations actually summarises the most important possible solutions on how to achieve a disturbance-free operation and a lower maintenance cost for boilers combusting waste wood and can thereby be regarded as a short summery of the whole project: 1) Improving fuel quality by Improved sorting at the source and Sieving of the fuel -> Reducing the amount of metals and chlorine and Separation of fines and thereby reducing the amount of metals. 2) Combustion modifications by Avoiding reducing conditions at the heat exchanger surfaces -> Minimising slagging, fouling and corrosion. 3) Additives or co-combustion by Addition of sulphur with the fuel; Injection of

Frame-Transfer Gating Raman Spectroscopy for Time-Resolved Multiscalar Combustion Diagnostics

Science.gov (United States)

Nguyen, Quang-Viet; Fischer, David G.; Kojima, Jun

2011-01-01

Accurate experimental measurement of spatially and temporally resolved variations in chemical composition (species concentrations) and temperature in turbulent flames is vital for characterizing the complex phenomena occurring in most practical combustion systems. These diagnostic measurements are called multiscalar because they are capable of acquiring multiple scalar quantities simultaneously. Multiscalar diagnostics also play a critical role in the area of computational code validation. In order to improve the design of combustion devices, computational codes for modeling turbulent combustion are often used to speed up and optimize the development process. The experimental validation of these codes is a critical step in accepting their predictions for engine performance in the absence of cost-prohibitive testing. One of the most critical aspects of setting up a time-resolved stimulated Raman scattering (SRS) diagnostic system is the temporal optical gating scheme. A short optical gate is necessary in order for weak SRS signals to be detected with a good signal- to-noise ratio (SNR) in the presence of strong background optical emissions. This time-synchronized optical gating is a classical problem even to other spectroscopic techniques such as laser-induced fluorescence (LIF) or laser-induced breakdown spectroscopy (LIBS). Traditionally, experimenters have had basically two options for gating: (1) an electronic means of gating using an image intensifier before the charge-coupled-device (CCD), or (2) a mechanical optical shutter (a rotary chopper/mechanical shutter combination). A new diagnostic technology has been developed at the NASA Glenn Research Center that utilizes a frame-transfer CCD sensor, in conjunction with a pulsed laser and multiplex optical fiber collection, to realize time-resolved Raman spectroscopy of turbulent flames that is free from optical background noise (interference). The technology permits not only shorter temporal optical gating (down

Combustion physics

Science.gov (United States)

Jones, A. R.

1985-11-01

Over 90% of our energy comes from combustion. By the year 2000 the figure will still be 80%, even allowing for nuclear and alternative energy sources. There are many familiar examples of combustion use, both domestic and industrial. These range from the Bunsen burner to large flares, from small combustion chambers, such as those in car engines, to industrial furnaces for steel manufacture or the generation of megawatts of electricity. There are also fires and explosions. The bountiful energy release from combustion, however, brings its problems, prominent among which are diminishing fuel resources and pollution. Combustion science is directed towards finding ways of improving efficiency and reducing pollution. One may ask, since combustion is a chemical reaction, why physics is involved: the answer is in three parts. First, chemicals cannot react unless they come together. In most flames the fuel and air are initially separate. The chemical reaction in the gas phase is very fast compared with the rate of mixing. Thus, once the fuel and air are mixed the reaction can be considered to occur instantaneously and fluid mechanics limits the rate of burning. Secondly, thermodynamics and heat transfer determine the thermal properties of the combustion products. Heat transfer also plays a role by preheating the reactants and is essential to extracting useful work. Fluid mechanics is relevant if work is to be performed directly, as in a turbine. Finally, physical methods, including electric probes, acoustics, optics, spectroscopy and pyrometry, are used to examine flames. The article is concerned mainly with how physics is used to improve the efficiency of combustion.

Impact of higher n-butanol addition on combustion and performance of GDI engine in stoichiometric combustion

International Nuclear Information System (INIS)

Chen, Zheng; Yang, Feng; Xue, Shuo; Wu, Zhenkuo; Liu, Jingping

2015-01-01

Highlights: • Effects of 0–50% n-butanol addition on GDI engine are experimentally studied. • Higher n-butanol fractions increase combustion pressure and fasten burning rate. • Higher n-butanol fractions increase BSFC but improve BTE. • Higher n-butanol fractions enhance combustion stability but increase knock intensity. • Higher n-butanol fractions reduce exhaust temperature and NOx emissions. - Abstract: An experimental study was carried out on a turbocharged gasoline direct injection (GDI) engine fueled by n-butanol/gasoline blends. Effects of n-butanol percents (15%, 30%, and 50%) on combustion and performance of the engine operating on stoichiometric combustion condition were discussed and also compared with pure gasoline in this paper. The results indicate that n-butanol/gasoline blends increase combustion pressure and pressure rise rate, fasten burning rate, and shorten ignition delay and combustion duration, as compared to pure gasoline. Moreover, these trends are impacted more evidently with increased n-butanol fraction in the blends. In addition, higher n-butanol percent of gasoline blends increase combustion temperature but decrease the temperature in the later stage of expansion stroke, which contributes to the control of exhaust temperature at high-load. With regards to engine performance, higher n-butanol percent in the blends results in increased brake specific fuel consumption (BSFC) and higher brake thermal efficiency (BTE). However, higher n-butanol addition helps to improve combustion stability but shows slightly higher knock possibility in high-load. In that case, the knock trend could be weakened by retarding ignition timing. Moreover, higher n-butanol addition significantly decreases NOx emissions, but it increases CO emissions obviously.

Co-combustion of anthracite coal and wood pellets: Thermodynamic analysis, combustion efficiency, pollutant emissions and ash slagging.

Science.gov (United States)

Guo, Feihong; Zhong, Zhaoping

2018-08-01

This work presents studies on the co-combustion of anthracite coal and wood pellets in fluidized bed. Prior to the fluidized bed combustion, thermogravimetric analysis are performed to investigate the thermodynamic behavior of coal and wood pellets. The results show that the thermal decomposition of blends is divided into four stages. The co-firing of coal and wood pellets can promote the combustion reaction and reduce the emission of gaseous pollutants, such as SO 2 and NO. It is important to choose the proportion of wood pellets during co-combustion due to the low combustion efficiency caused by large pellets with poor fluidization. Wood pellets can inhibit the volatilization of trace elements, especially for Cr, Ni and V. In addition, the slagging ratio of wood pellets ash is reduced by co-firing with coal. The research on combustion of coal and wood pellets is of great significance in engineering. Copyright © 2018 Elsevier Ltd. All rights reserved.

Combustion characteristics and air pollutant formation during oxy-fuel co-combustion of microalgae and lignite.

Science.gov (United States)

Gao, Yuan; Tahmasebi, Arash; Dou, Jinxiao; Yu, Jianglong

2016-05-01

Oxy-fuel combustion of solid fuels is seen as one of the key technologies for carbon capture to reduce greenhouse gas emissions. The combustion characteristics of lignite coal, Chlorella vulgaris microalgae, and their blends under O2/N2 and O2/CO2 conditions were studied using a Thermogravimetric Analyzer-Mass Spectroscopy (TG-MS). During co-combustion of blends, three distinct peaks were observed and were attributed to C. vulgaris volatiles combustion, combustion of lignite, and combustion of microalgae char. Activation energy during combustion was calculated using iso-conventional method. Increasing the microalgae content in the blend resulted in an increase in activation energy for the blends combustion. The emissions of S- and N-species during blend fuel combustion were also investigated. The addition of microalgae to lignite during air combustion resulted in lower CO2, CO, and NO2 yields but enhanced NO, COS, and SO2 formation. During oxy-fuel co-combustion, the addition of microalgae to lignite enhanced the formation of gaseous species. Copyright © 2016 Elsevier Ltd. All rights reserved.

Effect of additives in reducing ash sintering and slagging in biomass combustion applications

Energy Technology Data Exchange (ETDEWEB)

Wang, Liang

2012-07-01

formation of low temperature melting potassium rich silicates and phosphates, causing severe sintering of the WCob ash at elevated temperatures. In contrast, both the Pioneer corn cob (PCob) and Surcin corn cob (SCob) contained high contents of Cl, Ca and Mg that promote K release from the ashes to a certain extent and inhibit formation of low temperature melting K rich silicates and phosphates. In addition, abundance of Ca and Mg in the PCob and SCob facilitated formation of high temperature melting Ca/Mg-K-silicates and Ca/Mg-K-phosphates, reducing sintering degrees of ashes derived from these two corn cobs. Utilizing additives is an efficient way to mitigate ash related operational problems in biomass combustion applications. The useful additives can be proximately categorized into Al-Si-based, S-based, calcium-based and phosphorus-based, according to the major chemical composition in the additives. After fed into biomass combustion systems with different approaches, the additives can decrease amounts of problematic ash species through five possible mechanisms, which prevent and/or abate ash related problems consequently. It is interesting to exploit additives from waste materials, which are normally characterized with rather high chemical reactivity, physical adsorption capacity, abundance of refractory compounds themselves and low costs. More detailed studies are needed to clarify effects of these additives on ash transformation during biomass combustion processes. Sintering characteristics of biomass ashes and effects of additives were investigated. The work revealed that severe fusion of wheat straw ash was associated with intensive formation and melting of potassium silicates under heating. Whereas, sintering of wood waste ash was caused by generation of low temperature melting potassium/sodium aluminum silicates and potassium/sodium calcium silicates. The best anti-sintering effect was achieved by using the marble sludge as additive. The dilution effect from the

Combustion optimization and HCCI modeling for ultra low emission

Energy Technology Data Exchange (ETDEWEB)

Koten, Hasan; Yilmaz, Mustafa; Zafer Gul, M. [Marmara University Mechanical Engineering Department (Turkey)], E-mail: hasan.koten@marmara.edu.tr

2011-07-01

With the coming shortage of fossil fuels and the rising concerns over the environment it is important to develop new technologies both to reduce energy consumption and pollution at the same time. In the transportation sector, new combustion processes are under development to provide clean diesel combustion with no particulate or NOx emissions. However, these processes have issues such as limited power output, high levels of unburned hydrocarbons, and carbon monoxide emissions. The aim of this paper is to present a methodology for optimizing combustion performance. The methodology consists of the use of a multi-objective genetic algorithm optimization tool; homogeneous charge compression ignition engine cases were studied with the ECFM-3Z combustion model. Results showed that injected fuel mass led to a decrease in power output, a finding which is in keeping with previous research. This paper presented on optimization tool which can be useful in improving the combustion process.

Hydrogen assisted diesel combustion

Energy Technology Data Exchange (ETDEWEB)

Lilik, Gregory K.; Boehman, Andre L. [The EMS Energy Institute, The Pennsylvania State University, University Park, PA 16802 (United States); Zhang, Hedan; Haworth, Daniel C. [Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, PA 16802 (United States); Herreros, Jose Martin [Escuela Tecnica Superior de Ingenieros Industriales, Universidad de Castilla La-Mancha, Avda. Camilo Jose Cela s/n, 13071 Ciudad Real (Spain)

2010-05-15

Hydrogen assisted diesel combustion was investigated on a DDC/VM Motori 2.5L, 4-cylinder, turbocharged, common rail, direct injection light-duty diesel engine, with a focus on exhaust emissions. Hydrogen was substituted for diesel fuel on an energy basis of 0%, 2.5%, 5%, 7.5%, 10% and 15% by aspiration of hydrogen into the engine's intake air. Four speed and load conditions were investigated (1800 rpm at 25% and 75% of maximum output and 3600 rpm at 25% and 75% of maximum output). A significant retarding of injection timing by the engine's electronic control unit (ECU) was observed during the increased aspiration of hydrogen. The retarding of injection timing resulted in significant NO{sub X} emission reductions, however, the same emission reductions were achieved without aspirated hydrogen by manually retarding the injection timing. Subsequently, hydrogen assisted diesel combustion was examined, with the pilot and main injection timings locked, to study the effects caused directly by hydrogen addition. Hydrogen assisted diesel combustion resulted in a modest increase of NO{sub X} emissions and a shift in NO/NO{sub 2} ratio in which NO emissions decreased and NO{sub 2} emissions increased, with NO{sub 2} becoming the dominant NO{sub X} component in some combustion modes. Computational fluid dynamics analysis (CFD) of the hydrogen assisted diesel combustion process captured this trend and reproduced the experimentally observed trends of hydrogen's effect on the composition of NO{sub X} for some operating conditions. A model that explicitly accounts for turbulence-chemistry interactions using a transported probability density function (PDF) method was better able to reproduce the experimental trends, compared to a model that ignores the influence of turbulent fluctuations on mean chemical production rates, although the importance of the fluctuations is not as strong as has been reported in some other recent modeling studies. The CFD results confirm

Influence of injector technology on injection and combustion development - Part 2: Combustion analysis

Energy Technology Data Exchange (ETDEWEB)

Payri, R.; Salvador, F.J.; Gimeno, J.; Morena, J. de la [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, E-46022 (Spain)

2011-04-15

The influence of injection technology on the fuel-air mixing process and the combustion development are analyzed by means of visualization techniques. For this purpose, two injectors (one solenoid and one piezoelectric) are characterized using an optical accessible two stroke engine. Visualization of liquid penetration has allowed the measurement of the stabilized liquid length, which is related with the efficiency of fuel-air mixing process. A theoretical derivation is used in order to relate this liquid length with chamber conditions, as well as to make a temporal analysis of these phenomena. After this, natural flame emission and chemiluminescence techniques are carried out. These results indicate that the piezoelectric system has a more efficient fuel-air mixing and combustion, reducing the characteristic times as well as soot formation. Finally, a correlation for the ignition delay of the two systems is obtained. (author)

TOPICAL REVIEW: Plasma assisted ignition and combustion

Science.gov (United States)

Starikovskaia, S. M.

2006-08-01

In recent decades particular interest in applications of nonequilibrium plasma for the problems of plasma-assisted ignition and plasma-assisted combustion has been observed. A great amount of experimental data has been accumulated during this period which provided the grounds for using low temperature plasma of nonequilibrium gas discharges for a number of applications at conditions of high speed flows and also at conditions similar to automotive engines. The paper is aimed at reviewing the data obtained and discusses their treatment. Basic possibilities of low temperature plasma to ignite gas mixtures are evaluated and historical references highlighting pioneering works in the area are presented. The first part of the review discusses plasmas applied to plasma-assisted ignition and combustion. The paper pays special attention to experimental and theoretical analysis of some plasma parameters, such as reduced electric field, electron density and energy branching for different gas discharges. Streamers, pulsed nanosecond discharges, dielectric barrier discharges, radio frequency discharges and atmospheric pressure glow discharges are considered. The second part depicts applications of discharges to reduce the ignition delay time of combustible mixtures, to ignite transonic and supersonic flows, to intensify ignition and to sustain combustion of lean mixtures. The results obtained by different authors are cited, and ways of numerical modelling are discussed. Finally, the paper draws some conclusions on the main achievements and prospects of future investigations in the field.

Evaluation of different water-washing treatments effects on wheat straw combustion properties.

Science.gov (United States)

Ma, Qiulin; Han, Lujia; Huang, Guangqun

2017-12-01

A series of experiments was conducted to explore the effects of various water-washing solid-liquid ratios (1:50 and 1:10) and the stirring on wheat straw (WS) combustion properties. Comparing different solid-liquid ratio groups, a 16% increment in the higher heating value was obtained for 1:50 groups and only 5% for 1:10 groups relative to the raw material. Moreover, energy was lost 4-26 times greater in 1:10 groups than 1:50 groups. While water-washing reduced the comprehensive combustibility index by 14.89%-32.09%, the index values of washed WS were all higher than 2, indicating good combustion performance. The combustion activation energy of four washed WS were 175, 172, 186, and 176kJ/mol, which were all higher than the 160kJ/mol of WS. The fouling/slagging propensity of washed WS reduced to a lower possibility compared to medium of untreated WS. Overall, the recommended condition for washing WS before combustion is 1:50 ratio without stirring. Copyright © 2017. Published by Elsevier Ltd.

COMBUSTION OPTIMIZATION IN SPARK IGNITION ENGINES

OpenAIRE

Barhm Mohamad; Gabor Szebesi; Betti Bollo

2017-01-01

The blending technique used in internal combustion engines can reduce emission of toxic exhaust components and noises, enhance overall energy efficiency and reduce fuel costs. The aim of the study was to compare the effects of dual alcohols (methanol and ethanol) blended in gasoline fuel (GF) against performance, combustion and emission characteristics. Problems arise in the fuel delivery system when using the highly volatile methanol - gasoline blends. This problem is reduced by using specia...

Preliminary assessment of combustion modes for internal combustion wave rotors

Science.gov (United States)

Nalim, M. Razi

1995-01-01

Combustion within the channels of a wave rotor is examined as a means of obtaining pressure gain during heat addition in a gas turbine engine. Several modes of combustion are considered and the factors that determine the applicability of three modes are evaluated in detail; premixed autoignition/detonation, premixed deflagration, and non-premixed compression ignition. The last two will require strong turbulence for completion of combustion in a reasonable time in the wave rotor. The compression/autoignition modes will require inlet temperatures in excess of 1500 R for reliable ignition with most hydrocarbon fuels; otherwise, a supplementary ignition method must be provided. Examples of combustion mode selection are presented for two core engine applications that had been previously designed with equivalent 4-port wave rotor topping cycles using external combustion.

Research into three-component biodiesel fuels combustion process using a single droplet technique

Directory of Open Access Journals (Sweden)

L. Raslavičius

2007-12-01

Full Text Available In order to reduce the engine emission while at same time improving engine efficiency, it is very important to clarify the combustion mechanism. Even if, there are many researches into investigating the mechanism of engine combustion, so that to clarify the relationship between complicated phenomena, it is very difficult to investigate due to the complicated process of both physical and chemical reaction from the start of fuel injection to the end of combustion event. The numerical simulations are based on a detailed vaporization model and detailed chemical kinetics. The influence of different physical parameters like droplet temperature, gas phase temperature, ambient gas pressure and droplet burning velocity on the ignition delay process is investigated using fuel droplet combustion stand. Experimental results about their influence on ignition delay time were presented.

Investigation of bluff-body micro-flameless combustion

International Nuclear Information System (INIS)

Hosseini, Seyed Ehsan; Wahid, Mazlan Abdul

2014-01-01

Highlights: • The temperature uniformity of the micro-flameless combustion increases when a triangular bluff-body is applied. • The velocity and temperature of exhaust gases are higher in micro-flameless combustion compared to the conventional mode. • The rate of fuel–oxidizer consumption in micro-flameless mode is lower than conventional micro-combustion. - Abstract: Characteristics of lean premixed conventional micro-combustion and lean non-premixed flameless regime of methane/air are investigated in this paper by solving three-dimensional governing equations. At moderate equivalence ratio (∅ = 0.5), standard k–ε and the eddy-dissipation concept are employed to simulate temperature distribution and combustion stability of these models. The effect of bluff-body on the temperature distribution of both conventional and flameless mode is developed. The results show that in the premixed conventional micro-combustion the stability of the flame is increased when a triangular bluff-body is applied. Moreover, micro-flameless combustion is more stable when bluff-body is used. Micro-flameless mode with bluff-body and 7% O 2 concentration (when N 2 is used as diluent) illustrated better performance than other cases. The maximum temperature in premixed conventional micro-combustion and micro-flameless combustion was recorded 2200 K and 1520 K respectively. Indeed, the flue gas temperature of conventional mode and flameless combustion was 1300 K and 1500 K respectively. The fluctuation of temperature in the conventional micro-combustor wall has negative effects on the combustor and reduces the lifetime of micro-combustor. However, in the micro-flameless mode, the wall temperature is moderate and uniform. The rate of fuel–oxidizer consumption in micro-flameless mode takes longer time and the period of cylinders recharging is prolonged

A study of fluid flow and combustion with variable valve timing

Energy Technology Data Exchange (ETDEWEB)

Soederberg, F

1998-10-01

The effects of variable valve timing (VVT) were examined by in-cylinder Laser Doppler Velocimetry flow measurements and heat-release calculations. A single-cylinder Volvo B5254 engine was used for all experiments and the valve timing was altered by phasing or exchanging the camshaft. Special cam lobes were developed for simulation of throttle-less operation. With the standard double camshaft, a tumbling flow was generated and with valve deactivation, a swirling flow was generated. The turbulence was increased with valve deactivation. This increased the combustion rate making lean burn possible. The standard camshaft with inlet valve deactivation and late cam phasing had a faster combustion at {lambda} = 1.8 than the standard camshaft with normal cam phasing at {lambda} = 1.0. Early and late inlet valve closing was used for enabling throttle-less operation. Early inlet valve closing (EIVC) generated a very slow tumble with low turbulence. Late inlet valve closing generated both very high and low turbulence. The net indicated efficiency was improved with up to 10%. Some reduction was observed for the gross indicated efficiency, due to a too large reduction in effective compression ratio. A very stable combustion was obtained for EIVC with gasoline, possibly due to a sheering flow over the inlet valves resulting in improved fuel-air preparation. Wavelet analysis was used for dividing LDV flow measurements into time and frequency resolved information. The technique rendered the same flow results as the moving window technique, but with a separation of the turbulence into different frequencies. The choice of wavelet was shown not to be crucial. The frequency resolved turbulence was studied for tumble and swirl. A tumbling flow had a larger transfer of energy from low frequency turbulence into high frequency turbulence than a swirling flow. This is caused by the tumble breakdown. A correlation against heat-release indicated that high frequency turbulence have a larger

Comparison of different chemical kinetic mechanisms of methane combustion in an internal combustion engine configuration

OpenAIRE

Ennetta Ridha; Hamdi Mohamed; Said Rachid

2008-01-01

Three chemical kinetic mechanisms of methane combustion were tested and compared using the internal combustion engine model of Chemkin 4.02 [1]: one-step global reaction mechanism, four-step mechanism, and the standard detailed scheme GRIMECH 3.0. This study shows good concordances, especially between the four-step and the detailed mechanisms in the prediction of temperature and main species profiles. But reduced schemes were incapables to predict pollutant emissions in an internal combustion...

Production of nanocrystalline metal powders via combustion reaction synthesis

Science.gov (United States)

Frye, John G.; Weil, Kenneth Scott; Lavender, Curt A.; Kim, Jin Yong

2017-10-31

Nanocrystalline metal powders comprising tungsten, molybdenum, rhenium and/or niobium can be synthesized using a combustion reaction. Methods for synthesizing the nanocrystalline metal powders are characterized by forming a combustion synthesis solution by dissolving in water an oxidizer, a fuel, and a base-soluble, ammonium precursor of tungsten, molybdenum, rhenium, or niobium in amounts that yield a stoichiometric burn when combusted. The combustion synthesis solution is then heated to a temperature sufficient to substantially remove water and to initiate a self-sustaining combustion reaction. The resulting powder can be subsequently reduced to metal form by heating in a reducing gas environment.

Emissions from carpet combustion in a pilot-scale rotary kiln: comparison with coal and particle-board combustion

Energy Technology Data Exchange (ETDEWEB)

Stephanie Lucero Konopa; James A. Mulholland; Matthew J. Realff; Paul M. Lemieux [Georgia Institute of Technology, Atlanta, GA (United States). School of Civil and Environmental Engineering

2008-08-15

The use of post-consumer carpet as a potential fuel substitute in cement kilns and other high-temperature processes is being considered to address the problem of huge volumes of carpet waste and the opportunity of waste-to-energy recovery. Carpet represents a high volume waste stream, provides high energy value, and contains other recoverable materials for the production of cement. This research studied the emission characteristics of burning 0.46-kg charges of chopped nylon carpet squares, pulverized coal, and particle-board pellets in a pilot-scale natural gas-fired rotary kiln. Carpet was tested with different amounts of water added. Emissions of oxygen, carbon dioxide, nitric oxide (NO), sulfur dioxide (SO{sub 2}), carbon monoxide (CO), and total hydrocarbons and temperatures were continuously monitored. It was found that carpet burned faster and more completely than coal and particle board, with a rapid volatile release that resulted in large and variable transient emission peaks. NO emissions from carpet combustion ranged from 0.06 to 0.15 g/MJ and were inversely related to CO emissions. Carpet combustion yielded higher NO emissions than coal and particleboard combustion, consistent with its higher nitrogen content. S{sub 2} emissions were highest for coal combustion, consistent with its higher sulfur content than carpet or particle board. Adding water to carpet slowed its burn time and reduced variability in the emission transients, reducing the CO peak but increasing NO emissions. Results of this study indicate that carpet waste can be used as an effective alternative fuel, with the caveats that it might be necessary to wet carpet or chop it finely to avoid excessive transient puff emissions due to its high volatility compared with other solid fuels, and that controlled mixing of combustion air might be used to control NO emissions from nylon carpet. 13 refs., 5 figs., 1 tab.

Two-stage combustion for reducing pollutant emissions from gas turbine combustors

Science.gov (United States)

Clayton, R. M.; Lewis, D. H.

1981-01-01

Combustion and emission results are presented for a premix combustor fueled with admixtures of JP5 with neat H2 and of JP5 with simulated partial-oxidation product gas. The combustor was operated with inlet-air state conditions typical of cruise power for high performance aviation engines. Ultralow NOx, CO and HC emissions and extended lean burning limits were achieved simultaneously. Laboratory scale studies of the non-catalyzed rich-burning characteristics of several paraffin-series hydrocarbon fuels and of JP5 showed sooting limits at equivalence ratios of about 2.0 and that in order to achieve very rich sootless burning it is necessary to premix the reactants thoroughly and to use high levels of air preheat. The application of two-stage combustion for the reduction of fuel NOx was reviewed. An experimental combustor designed and constructed for two-stage combustion experiments is described.

Real-Time Identification of Smoldering and Flaming Combustion Phases in Forest Using a Wireless Sensor Network-Based Multi-Sensor System and Artificial Neural Network.

Science.gov (United States)

Yan, Xiaofei; Cheng, Hong; Zhao, Yandong; Yu, Wenhua; Huang, Huan; Zheng, Xiaoliang

2016-08-04

Diverse sensing techniques have been developed and combined with machine learning method for forest fire detection, but none of them referred to identifying smoldering and flaming combustion phases. This study attempts to real-time identify different combustion phases using a developed wireless sensor network (WSN)-based multi-sensor system and artificial neural network (ANN). Sensors (CO, CO₂, smoke, air temperature and relative humidity) were integrated into one node of WSN. An experiment was conducted using burning materials from residual of forest to test responses of each node under no, smoldering-dominated and flaming-dominated combustion conditions. The results showed that the five sensors have reasonable responses to artificial forest fire. To reduce cost of the nodes, smoke, CO₂ and temperature sensors were chiefly selected through correlation analysis. For achieving higher identification rate, an ANN model was built and trained with inputs of four sensor groups: smoke; smoke and CO₂; smoke and temperature; smoke, CO₂ and temperature. The model test results showed that multi-sensor input yielded higher predicting accuracy (≥82.5%) than single-sensor input (50.9%-92.5%). Based on these, it is possible to reduce the cost with a relatively high fire identification rate and potential application of the system can be tested in future under real forest condition.

Combustion of Metals in Reduced-Gravity and Extraterrestrial Environment

Science.gov (United States)

Abbud-Madrid, A.; Omaly, P.; Branch, M. C.; Daily, J. W.

1999-01-01

As a result of the ongoing exploration of Mars and the several unmanned and manned missions planned for the future, increased attention has been given to the use of the natural resources of the planet for rocket propellant production and energy generation. Since the atmosphere of Mars consists of approximately 95% carbon dioxide (CO2), this gas is the resource of choice to be employed for these purposes. Unfortunately, CO2 is also a final product in most combustion reactions, requiring further processing to extract useful reactants such as carbon monoxide (CO), oxygen (O2), and hydrocarbons. An exception is the use Of CO2 as an oxidizer reacting directly with metal fuel. Since many metals burn vigorously with CO2, these may be used as an energy source and as propellants for an ascent/descent vehicle in sample-collection missions on Mars. In response to NASA's Human Exploration and Development of Space (HEDS) Enterprise to search for appropriate in-situ resource utilization techniques, this investigation will study the burning characteristics of promising metal/CO2 combinations. The use of reduced gravity is essential to eliminate the intrusive buoyant flows that plague the high-temperature metal reactions, to remove the destructive effect of gravity on the shape of molten metal samples, and to study the influence of radiative heat transfer from solid oxides undisturbed by natural convection. In studies with large metal specimens, the burning process is invariably influenced by strong convective currents that accelerate the reaction and shorten the burning times. Although these currents are nearly absent from small burning particles, the high emissivity of the flames, rapid reaction, small length scales, and intermittent explosions make the gathering of any useful information on burning rates and flame structure very difficult. This investigation has the ultimate goal of providing a careful probing of flame structure and dynamics by taking advantage of large, free

COMBUSTION SIMULATION IN A SPARK IGNITION ENGINE CYLINDER: EFFECTS OF AIR-FUEL RATIO ON THE COMBUSTION DURATION

Directory of Open Access Journals (Sweden)

Nureddin Dinler

2010-01-01

Full Text Available Combustion is an important subject of internal combustion engine studies. To reduce the air pollution from internal combustion engines and to increase the engine performance, it is required to increase combustion efficiency. In this study, effects of air/fuel ratio were investigated numerically. An axisymmetrical internal combustion engine was modeled in order to simulate in-cylinder engine flow and combustion. Two dimensional transient continuity, momentum, turbulence, energy, and combustion equations were solved. The k-e turbulence model was employed. The fuel mass fraction transport equation was used for modeling of the combustion. For this purpose a computational fluid dynamics code was developed by using the finite volume method with FORTRAN programming code. The moving mesh was utilized to simulate the piston motion. The developed code simulates four strokes of engine continuously. In the case of laminar flow combustion, Arrhenius type combustion equations were employed. In the case of turbulent flow combustion, eddy break-up model was employed. Results were given for rich, stoichiometric, and lean mixtures in contour graphs. Contour graphs showed that lean mixture (l = 1.1 has longer combustion duration.

Catalytic combustion in small wood burning appliances

Energy Technology Data Exchange (ETDEWEB)

Oravainen, H [VTT Energy, Jyvaeskylae (Finland)

1997-12-31

There is over a million hand fired small heating appliances in Finland where about 5,4 million cubic meters of wood fuel is used. Combustion in such heating appliances is a batch-type process. In early stages of combustion when volatiles are burned, the formation of carbon monoxide (CO) and other combustible gases are difficult to avoid when using fuels that have high volatile matter content. Harmful emissions are formed mostly after each fuel adding but also during char burnout period. When the CO-content in flue gases is, say over 0.5 %, also other harmful emissions will be formed. Methane (CH{sub 4}) and other hydrocarbons are released and the amount of polycyclic aromatic hydrocarbons (PAH)-compounds can be remarkable. Some PAH-compounds are very carcinogenic. It has been estimated that in Finland even more than 90 % of hydrocarbon and PAH emissions are due to small scale wood combustion. Emissions from transportation is excluded from these figures. That is why wood combustion has a net effect on greenhouse gas phenomena. For example carbon monoxide emissions from small scale wood combustion are two fold compared to that of energy production in power plants. Methane emission is of the same order as emission from transportation and seven fold compared with those of energy production. Emissions from small heating appliances can be reduced by developing the combustion techniques, but also by using other means, for example catalytic converters. In certain stages of the batch combustion, temperature is not high enough, gas mixing is not good enough and residence time is too short for complete combustion. When placed to a suitable place inside a heating appliance, a catalytic converter can oxidize unburned gases in the flue gas into compounds that are not harmful to the environment. (3 refs.)

Catalytic combustion in small wood burning appliances

Energy Technology Data Exchange (ETDEWEB)

Oravainen, H. [VTT Energy, Jyvaeskylae (Finland)

1996-12-31

There is over a million hand fired small heating appliances in Finland where about 5,4 million cubic meters of wood fuel is used. Combustion in such heating appliances is a batch-type process. In early stages of combustion when volatiles are burned, the formation of carbon monoxide (CO) and other combustible gases are difficult to avoid when using fuels that have high volatile matter content. Harmful emissions are formed mostly after each fuel adding but also during char burnout period. When the CO-content in flue gases is, say over 0.5 %, also other harmful emissions will be formed. Methane (CH{sub 4}) and other hydrocarbons are released and the amount of polycyclic aromatic hydrocarbons (PAH)-compounds can be remarkable. Some PAH-compounds are very carcinogenic. It has been estimated that in Finland even more than 90 % of hydrocarbon and PAH emissions are due to small scale wood combustion. Emissions from transportation is excluded from these figures. That is why wood combustion has a net effect on greenhouse gas phenomena. For example carbon monoxide emissions from small scale wood combustion are two fold compared to that of energy production in power plants. Methane emission is of the same order as emission from transportation and seven fold compared with those of energy production. Emissions from small heating appliances can be reduced by developing the combustion techniques, but also by using other means, for example catalytic converters. In certain stages of the batch combustion, temperature is not high enough, gas mixing is not good enough and residence time is too short for complete combustion. When placed to a suitable place inside a heating appliance, a catalytic converter can oxidize unburned gases in the flue gas into compounds that are not harmful to the environment. (3 refs.)

Experimental research on combustion fluorine retention using calcium-based sorbents during coal combustion (II)

Energy Technology Data Exchange (ETDEWEB)

Qi, Q.; Ma, X.; Liu, J.; Wu, X.; Zhou, J.; Cen, K. [Liaoning Technical University, Fuxin (China). College of Resource and Environment Engineering

2008-12-15

Fluoride pollution produced by coal burning can be controlled with the calcium-based sorbent combustion fluorine technique in which calcium-based sorbents are mixed with the coal or sprayed into the combustion chamber. In a fixed bed tube furnace combustion experiment using one calcium-based natural mineral, limestone and one calcium-based building material, it was shown that the calcium-based sorbent particle grain size and pore structure have a big influence on the combustion fluorine retention effect. Reducing the calcium-based sorbent particle grain size and improving the calcium sorbent structure characteristics at very high temperature to enhance the fluorine retention effect is the important approach to the fluorine retention agent development. 8 refs., 1 fig., 5 tabs.

Ignition and combustion of bulk metals under elevated, normal and reduced gravity conditions

Science.gov (United States)

Abbud-Madrid, Angel; Branch, Melvyn C.; Daily, John W.

1995-01-01

This research effort is aimed at providing further insight into this multi-variable dependent phenomena by looking at the effects of gravity on the ignition and combustion behavior of metals. Since spacecraft are subjected to higher-than-1g gravity loads during launch and reentry and to zero-gravity environments while in orbit, the study of ignition and combustion of bulk metals at different gravitational potentials is of great practical concern. From the scientific standpoint, studies conducted under microgravity conditions provide simplified boundary conditions since buoyancy is removed, and make possible the identification of fundamental ignition mechanisms. The effect of microgravity on the combustion of bulk metals has been investigated by Steinberg, et al. on a drop tower simulator. However, no detailed quantitative work has been done on ignition phenomena of bulk metals at lower or higher-than-normal gravitational fields or on the combustion characteristics of metals at elevated gravity. The primary objective of this investigation is the development of an experimental system capable of providing fundamental physical and chemical information on the ignition of bulk metals under different gravity levels. The metals used in the study, iron (Fe), titanium (Ti), zirconium (Zr), magnesium (Mg), zinc (Zn), and copper (Cu) were selected because of their importance as elements of structural metals and their simple chemical composition (pure metals instead of multi-component alloys to avoid complication in morphology and spectroscopic studies). These samples were also chosen to study the two different combustion modes experienced by metals: heterogeneous or surface oxidation, and homogeneous or gas-phase reaction. The experimental approach provides surface temperature profiles, spectroscopic measurements, surface morphology, x-ray spectrometry of metals specimens and their combustion products, and high-speed cinematography of the heating, ignition and combustion

A novel approach to predict the stability limits of combustion chambers with large eddy simulation

Science.gov (United States)

Pritz, B.; Magagnato, F.; Gabi, M.

2010-06-01

Lean premixed combustion, which allows for reducing the production of thermal NOx, is prone to combustion instabilities. There is an extensive research to develop a reduced physical model, which allows — without time-consuming measurements — to calculate the resonance characteristics of a combustion system consisting of Helmholtz resonator type components (burner plenum, combustion chamber). For the formulation of this model numerical investigations by means of compressible Large Eddy Simulation (LES) were carried out. In these investigations the flow in the combustion chamber is isotherm, non-reacting and excited with a sinusoidal mass flow rate. Firstly a combustion chamber as a single resonator subsequently a coupled system of a burner plenum and a combustion chamber were investigated. In this paper the results of additional investigations of the single resonator are presented. The flow in the combustion chamber was investigated without excitation at the inlet. It was detected, that the mass flow rate at the outlet cross section is pulsating once the flow in the chamber is turbulent. The fast Fourier transform of the signal showed that the dominant mode is at the resonance frequency of the combustion chamber. This result sheds light on a very important source of self-excited combustion instabilities. Furthermore the LES can provide not only the damping ratio for the analytical model but the eigenfrequency of the resonator also.

High resolution real time capable combustion chamber simulation; Zeitlich hochaufloesende echtzeitfaehige Brennraumsimulation

Energy Technology Data Exchange (ETDEWEB)

Piewek, J. [Volkswagen AG, Wolfsburg (Germany)

2008-07-01

The article describes a zero-dimensional model for the real time capable combustion chamber pressure calculation with analogue pressure sensor output. The closed-loop-operation of an Engine Control Unit is shown at the hardware-in-the-loop-simulator (HiL simulator) for a 4-cylinder common rail diesel engine. The presentation of the model focuses on the simulation of the load variation which does not depend on the injection system and thus the simulated heat release rate. Particular attention is paid to the simulation and the resulting test possibilities regarding to full-variable valve gears. It is shown that black box models consisting in the HiL mean value model for the aspirated gas mass, the exhaust gas temperature after the outlet valve and the mean indicated pressure can be replaced by calculations from the high-resolution combustion chamber model. (orig.)

Low cost combustion tuning and fuel nozzles modification to reduce NOx emission in large coal-fired boilers

Energy Technology Data Exchange (ETDEWEB)

B. Chudnovsky; L. Levin; A. Talanker; E. Bar-Ziv; A. Vikhansky; A.F. Sarofim [Israel Electric Corporation (IEC), Haifa (Israel)

2003-07-01

This work focuses on low-cost combustion tuning to reduce NOx emission in coal-fired tangential boilers, testing the furnace in various operation modes. We have also experimented different coal nozzle types. The measurements were accompanied by computer simulations of the combustion process. We also used an on-line supervision system. The data obtained from 575 MW boilers show that with tuning and modified nozzles NOx was considerably reduced. The emission of NOx was reduced from 1200 to 570 mg/dNm{sup 3} at 6% O{sub 2} for South African coal at full load. At partial load NOx emission dropped from 1400 to 750-850 mg/dNm{sup 3} at 6% O{sub 2}. High volatile coal firing led to additional NOx reduction. A series of tests were performed with Colombian and Indonesian coals as well, dropping NOx emission to 400-450 mg/dNm{sup 3} at6% O{sub 2} at full load. Sootblowing optimization using the supervision system enabled us to further reduce NOx emission by approximately 10%. The boiler and unit performance was not influenced by any of the techniques used for NOx reduction. In such a manner, the results presented in this work clearly show that technological methods for reduction NOx are available and capable of obtaining the required NOx emission. We believe that the conclusions of the present study are general and may be applied to other utility boilers as well. 13 refs., 12 figs., 7 tabs.

Low Temperature Combustion in a Heavy Duty Diesel Engine

Energy Technology Data Exchange (ETDEWEB)

Ehleskog, Malin

2012-07-01

In recent years, there have been major efforts to reduce engine emissions and fuel consumption. The studies described in this thesis were conducted with the aim of identifying methods for reducing harmful engine-out emissions of soot and nitrogen oxides (NOx) under high load without increasing fuel consumption. The first part of the project focused on low temperature combustion using very high levels of EGR. It was found that very low soot and NOx emissions could be achieved at low loads. Unfortunately, these conditions resulted in high fuel consumption as well as high emissions of HC and CO. The increased emissions could be mitigated by optimising the timing of the SOI and increasing the injection pressure, but the high fuel consumption remained problematic. Intermediate levels of EGR can be used to increase the ignition delay and thereby achieve partially premixed combustion. When soot and NOx emissions are plotted against the amount of EGR, there is an intersection point at which the soot emissions are just beginning to increase but the recirculated exhaust gas has greatly reduced the NOx emissions. At this point, the HC and CO emissions and the fuel consumption remain acceptably low. If the onset of the increased soot emissions could be shifted to a higher EGR level or if the peak soot emissions could be reduced in magnitude, the tradeoff between soot and NOx emissions at intermediate EGR levels could be improved. By increasing the charge air pressure, the size of the soot bump is reduced and the point of intersection between the soot and NOx curves is shifted to a higher EGR percentage. The soot-NOx tradeoff can also be improved by increasing the injection pressure to reduce the soot peak while using EGR levels that are high enough to suppress NOx formation. To further investigate the potential of partially premixed combustion, the effects of varying the timing of late inlet valve closure were investigated. The results show that reducing the effective

Emission and combustion characteristics of multiple stage diesel combustion; Nidan nensho ni yoru diesel kikan no nensho to haishutsubutsu tokusei

Energy Technology Data Exchange (ETDEWEB)

Hashizume, T; Miyamoto, T; Tsujimura, K [New A.C.E. Institute Co. Ltd., Tokyo (Japan); Kobayashi, S; Shimizu, K [Japan Automobile Research Institute, Tsukuba (Japan)

1997-10-01

A new concept of multiple stage diesel combustion was studied by means of engine test, combustion observation and numerical simulation, in order to reduce NOx emissions at high load conditions. With this concept, the premixed combustion occurs under the fuel lean conditions and the diffusion combustion occurs under the high temperature conditions. As seen in the result of combustion observation, a first stage combustion occurs with no luminous flame. A second stage combustion occurs with a luminous flame after very short ignition delay period. However the luminous flame is disappeared immediately. Because cylinder temperature is high, and hence soot oxidizes immediately. 5 refs., 11 figs., 1 tab.

Transient flow combustion

Science.gov (United States)

Tacina, R. R.

1984-01-01

Non-steady combustion problems can result from engine sources such as accelerations, decelerations, nozzle adjustments, augmentor ignition, and air perturbations into and out of the compressor. Also non-steady combustion can be generated internally from combustion instability or self-induced oscillations. A premixed-prevaporized combustor would be particularly sensitive to flow transients because of its susceptability to flashback-autoignition and blowout. An experimental program, the Transient Flow Combustion Study is in progress to study the effects of air and fuel flow transients on a premixed-prevaporized combustor. Preliminary tests performed at an inlet air temperature of 600 K, a reference velocity of 30 m/s, and a pressure of 700 kPa. The airflow was reduced to 1/3 of its original value in a 40 ms ramp before flashback occurred. Ramping the airflow up has shown that blowout is more sensitive than flashback to flow transients. Blowout occurred with a 25 percent increase in airflow (at a constant fuel-air ratio) in a 20 ms ramp. Combustion resonance was found at some conditions and may be important in determining the effects of flow transients.

Effect of Pilot Injection Timings on the Combustion Temperature Distribution in a Single-Cylinder CI Engine Fueled with DME and ULSD

Directory of Open Access Journals (Sweden)

Jeon Joonho

2016-01-01

Full Text Available Many studies of DiMethyl Ether (DME as an alternative fuel in Compression-Ignition (CI engines have been performed. Although diverse DME engine research has been conducted, the investigation of combustion behavior and temperature distribution in the combustion engine has not progressed due to the fact that there is no sooting flame in DME combustion. In order to investigate the combustion characteristics in this study, the KIVA-3 V code was implemented to research various pilot injection strategies on a single-cylinder CI engines with DME and Ultra-Low-Sulfur Diesel (ULSD fuels. The combustion distribution results obtained from the numerical investigation were validated when compared with the measurement of flame temperature behaviors in the experimental approach. This study showed that long intervals between two injection timings enhanced pilot combustion by increasing the ambient pressure and temperature before the start of the main combustion. Different atomization properties between DME and ULSD fuels contributed to the formation of a fuel-air mixture at the nozzle tip and piston lip regions, separately, which strongly affected the temperature distribution of the two fuels. In addition, the pilot injection timing played a vital role in regard to ignition delay and peak combustion temperatures. Exhaust emissions, such as NOx and soot, are related to the local equivalence ratio and temperature in the combustion chamber, also illustrated by the contrary result on a Φ (equivalence ratio – T (temperature map.

Superheated fuel injection for combustion of liquid-solid slurries

Science.gov (United States)

Robben, F.A.

1984-10-19

A method and device are claimed for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal. 2 figs., 2 tabs.

Techniques de combustion Combustin Techniques

Directory of Open Access Journals (Sweden)

Perthuis E.

2006-11-01

Full Text Available L'efficacité d'un processus de chauffage par flamme est étroitement liée à la maîtrise des techniques de combustion. Le brûleur, organe essentiel de l'équipement de chauffe, doit d'une part assurer une combustion complète pour utiliser au mieux l'énergie potentielle du combustible et, d'autre part, provoquer dans le foyer les conditions aérodynamiques les plus propices oux transferts de chaleur. En s'appuyant sur les études expérimentales effectuées à la Fondation de Recherches Internationales sur les Flammes (FRIF, au Groupe d'Étude des Flammes de Gaz Naturel (GEFGN et à l'Institut Français du Pétrole (IFP et sur des réalisations industrielles, on présente les propriétés essentielles des flammes de diffusion aux combustibles liquides et gazeux obtenues avec ou sans mise en rotation des fluides, et leurs répercussions sur les transferts thermiques. La recherche des températures de combustion élevées conduit à envisager la marche à excès d'air réduit, le réchauffage de l'air ou son enrichissement à l'oxygène. Par quelques exemples, on évoque l'influence de ces paramètres d'exploitation sur l'économie possible en combustible. The efficiency of a flame heating process is closely linked ta the mastery of, combustion techniques. The burner, an essential element in any heating equipment, must provide complete combustion sa as to make optimum use of the potential energy in the fuel while, at the same time, creating the most suitable conditions for heat transfers in the combustion chamber. On the basis of experimental research performed by FRIF, GEFGN and IFP and of industrial achievements, this article describesthe essential properties of diffusion flames fed by liquid and gaseous fuels and produced with or without fluid swirling, and the effects of such flames on heat transfers. The search for high combustion temperatures means that consideration must be given to operating with reduced excess air, heating the air or

Multi-stage combustion using nitrogen-enriched air

Science.gov (United States)

Fischer, Larry E.; Anderson, Brian L.

2004-09-14

Multi-stage combustion technology combined with nitrogen-enriched air technology for controlling the combustion temperature and products to extend the maintenance and lifetime cycles of materials in contact with combustion products and to reduce pollutants while maintaining relatively high combustion and thermal cycle efficiencies. The first stage of combustion operates fuel rich where most of the heat of combustion is released by burning it with nitrogen-enriched air. Part of the energy in the combustion gases is used to perform work or to provide heat. The cooled combustion gases are reheated by additional stages of combustion until the last stage is at or near stoichiometric conditions. Additional energy is extracted from each stage to result in relatively high thermal cycle efficiency. The air is enriched with nitrogen using air separation technologies such as diffusion, permeable membrane, absorption, and cryogenics. The combustion method is applicable to many types of combustion equipment, including: boilers, burners, turbines, internal combustion engines, and many types of fuel including hydrogen and carbon-based fuels including methane and coal.

Molten salt combustion of radioactive wastes

International Nuclear Information System (INIS)

Grantham, L.F.; McKenzie, D.E.; Richards, W.L.; Oldenkamp, R.D.

1976-01-01

The Atomics International Molten Salt Combustion Process reduces the weight and volume of combustible β-γ contaminated transuranic waste by utilizing air in a molten salt medium to combust organic materials, to trap particulates, and to react chemically with any acidic gases produced during combustion. Typically, incomplete combustion products such as hydrocarbons and carbon monoxide are below detection limits (i.e., 3 ) is directly related to the sodium chloride vapor pressure of the melt; >80% of the particulate is sodium chloride. Essentially all metal oxides (combustion ash) are retained in the melt, e.g., >99.9% of the plutonium, >99.6% of the europium, and >99.9% of the ruthenium are retained in the melt. Both bench-scale radioactive and pilot scale (50 kg/hr) nonradioactive combustion tests have been completed with essentially the same results. Design of three combustors for industrial applications are underway

LES and RANS modeling of pulverized coal combustion in swirl burner for air and oxy-combustion technologies

International Nuclear Information System (INIS)

Warzecha, Piotr; Boguslawski, Andrzej

2014-01-01

Combustion of pulverized coal in oxy-combustion technology is one of the effective ways to reduce the emission of greenhouse gases into the atmosphere. The process of transition from conventional combustion in air to the oxy-combustion technology, however, requires a thorough investigations of the phenomena occurring during the combustion process, that can be greatly supported by numerical modeling. The paper presents the results of numerical simulations of pulverized coal combustion process in swirl burner using RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) methods for turbulent flow. Numerical simulations have been performed for the oxyfuel test facility located at the Institute of Heat and Mass Transfer at RWTH Aachen University. Detailed analysis of the flow field inside the combustion chamber for cold flow and for the flow with combustion using different numerical methods for turbulent flows have been done. Comparison of the air and oxy-coal combustion process for pulverized coal shows significant differences in temperature, especially close to the burner exit. Additionally the influence of the combustion model on the results has been shown for oxy-combustion test case. - Highlights: • Oxy-coal combustion has been modeled for test facility operating at low oxygen ratio. • Coal combustion process has been modeled with simplified combustion models. • Comparison of oxy and air combustion process of pulverized coal has been done. • RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) results for pulverized coal combustion process have been compared

Effect of fuel injection pressure and injection timing of Karanja biodiesel blends on fuel spray, engine performance, emissions and combustion characteristics

International Nuclear Information System (INIS)

Agarwal, Avinash Kumar; Dhar, Atul; Gupta, Jai Gopal; Kim, Woong Il; Choi, Kibong; Lee, Chang Sik; Park, Sungwook

2015-01-01

Highlights: • Effect of FIP on microscopic spray characteristics. • Effect of FIP and SOI timing on CRDI engine performance, emissions and combustion. • Fuel injection duration shortened, peak injection rate increased with increasing FIP. • SMD (D 32 ) and AMD (D 10 ) of fuel droplets decreased for lower biodiesel blends. • Increase in biodiesel blend ratio and FIP, fuel injection duration decreased. - Abstract: In this investigation, effect of 10%, 20% and 50% Karanja biodiesel blends on injection rate, atomization, engine performance, emissions and combustion characteristics of common rail direct injection (CRDI) type fuel injection system were evaluated in a single cylinder research engine at 300, 500, 750 and 1000 bar fuel injection pressures at different start of injection timings and constant engine speed of 1500 rpm. The duration of fuel injection slightly decreased with increasing blend ratio of biodiesel (Karanja Oil Methyl Ester: KOME) and significantly decreased with increasing fuel injection pressure. The injection rate profile and Sauter mean diameter (D 32 ) of the fuel droplets are influenced by the injection pressure. Increasing fuel injection pressure generally improves the thermal efficiency of the test fuels. Sauter mean diameter (D 32 ) and arithmetic mean diameter (D 10 ) decreased with decreasing Karanja biodiesel content in the blend and significantly increased for higher blends due to relatively higher fuel density and viscosity. Maximum thermal efficiency was observed at the same injection timing for biodiesel blends and mineral diesel. Lower Karanja biodiesel blends (up to 20%) showed lower brake specific hydrocarbon (BSHC) and carbon monoxide (BSCO) emissions in comparison to mineral diesel. For lower Karanja biodiesel blends, combustion duration was shorter than mineral diesel however at higher fuel injection pressures, combustion duration of 50% blend was longer than mineral diesel. Up to 10% Karanja biodiesel blends in a CRDI

Development of High Efficiency Clean Combustion Engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines

Energy Technology Data Exchange (ETDEWEB)

Marriott, Craig; Gonzalez, Manual; Russell, Durrett

2011-06-30

This report summarizes activities related to the revised STATEMENT OF PROJECT OBJECTIVES (SOPO) dated June 2010 for the Development of High-Efficiency Clean Combustion engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines (COOPERATIVE AGREEMENT NUMBER DE-FC26-05NT42415) project. In both the spark- (SI) and compression-ignition (CI) development activities covered in this program, the goal was to develop potential production-viable internal combustion engine system technologies that both reduce fuel consumption and simultaneously met exhaust emission targets. To be production-viable, engine technologies were also evaluated to determine if they would meet customer expectations of refinement in terms of noise, vibration, performance, driveability, etc. in addition to having an attractive business case and value. Prior to this activity, only proprietary theoretical / laboratory knowledge existed on the combustion technologies explored The research reported here expands and develops this knowledge to determine series-production viability. Significant SI and CI engine development occurred during this program within General Motors, LLC over more than five years. In the SI program, several engines were designed and developed that used both a relatively simple multi-lift valve train system and a Fully Flexible Valve Actuation (FFVA) system to enable a Homogeneous Charge Compression Ignition (HCCI) combustion process. Many technical challenges, which were unknown at the start of this program, were identified and systematically resolved through analysis, test and development. This report documents the challenges and solutions for each SOPO deliverable. As a result of the project activities, the production viability of the developed clean combustion technologies has been determined. At this time, HCCI combustion for SI engines is not considered production-viable for several reasons. HCCI combustion is excessively sensitive to control variables

ANALYSIS OF INTERNAL COMBUSTION ENGINE WITH A NEW CONCEPT OF POROUS MEDIUM COMBUSTION FOR THE FUTURE CLEAN ENGINE

Directory of Open Access Journals (Sweden)

Ashok A Dhale

2010-01-01

Full Text Available At present, the emissions of internal combustion engine can only be improved by catalytic treatments of the exhaust gases. Such treatments, however, result in high costs and relatively low conversion efficiency. This suggests that a new combustion technique should be developed to yield improved primary combustion processes inside the engine with drastically reduced exhaust gas emissions. To fulfill all requirements, Dr. Franz Drust has proposed a new combustion concept to perform homogenous combustion in internal combustion engines. This concept used the porous medium combustion technique and is called "PM-engine". It is shown that the PM combustion technique can be applied to internal combustion engines. Theoretical considerations are presented for internal combustion engines, indicating that an overall improvement in thermal efficiency can be achieved for the PM-engine. This is explained and general performance of the new PM-engines is demonstrated for a single cylinder, water cooled, direct injection diesel engine. Verification of experiments at primary stage is described that were carried out as a part of the present study.

The combustion behavior of diesel/CNG mixtures in a constant volume combustion chamber

Science.gov (United States)

Firmansyah; Aziz, A. R. A.; Heikal, M. R.

2015-12-01

The stringent emissions and needs to increase fuel efficiency makes controlled auto-ignition (CAI) based combustion an attractive alternative for the new combustion system. However, the combustion control is the main obstacles in its development. Reactivity controlled compression ignition (RCCI) that employs two fuels with significantly different in reactivity proven to be able to control the combustion. The RCCI concept applied in a constant volume chamber fuelled with direct injected diesel and compressed natural gas (CNG) was tested. The mixture composition is varied from 0 - 100% diesel/CNG at lambda 1 with main data collection are pressure profile and combustion images. The results show that diesel-CNG mixture significantly shows better combustion compared to diesel only. It is found that CNG is delaying the diesel combustion and at the same time assisting in diesel distribution inside the chamber. This combination creates a multipoint ignition of diesel throughout the chamber that generate very fast heat release rate and higher maximum pressure. Furthermore, lighter yellow color of the flame indicates lower soot production in compared with diesel combustion.

Advanced Combustion Numerics and Modeling - FY18 First Quarter Report

Energy Technology Data Exchange (ETDEWEB)

Whitesides, R. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Killingsworth, N. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); McNenly, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Petitpas, G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2018-01-05

This project is focused on early stage research and development of numerical methods and models to improve advanced engine combustion concepts and systems. The current focus is on development of new mathematics and algorithms to reduce the time to solution for advanced combustion engine design using detailed fuel chemistry. The research is prioritized towards the most time-consuming workflow bottlenecks (computer and human) and accuracy gaps that slow ACS program members. Zero-RK, the fast and accurate chemical kinetics solver software developed in this project, is central to the research efforts and continues to be developed to address the current and emerging needs of the engine designers, engine modelers and fuel mechanism developers.

Simulation of lean premixed turbulent combustion

International Nuclear Information System (INIS)

Bell, J; Day, M; Almgren, A; Lijewski, M; Rendleman, C; Cheng, R; Shepherd, I

2006-01-01

There is considerable technological interest in developing new fuel-flexible combustion systems that can burn fuels such as hydrogen or syngas. Lean premixed systems have the potential to burn these types of fuels with high efficiency and low NOx emissions due to reduced burnt gas temperatures. Although traditional Scientific approaches based on theory and laboratory experiment have played essential roles in developing our current understanding of premixed combustion, they are unable to meet the challenges of designing fuel-flexible lean premixed combustion devices. Computation, with its ability to deal with complexity and its unlimited access to data, has the potential for addressing these challenges. Realizing this potential requires the ability to perform high fidelity simulations of turbulent lean premixed flames under realistic conditions. In this paper, we examine the specialized mathematical structure of these combustion problems and discuss simulation approaches that exploit this structure. Using these ideas we can dramatically reduce computational cost, making it possible to perform high-fidelity simulations of realistic flames. We illustrate this methodology by considering ultra-lean hydrogen flames and discuss how this type of simulation is changing the way researchers study combustion

Method of estimating time management of safety control of combustion. Nensho anzen seigyo no tame no jikan kanri No hyoka hoho

Energy Technology Data Exchange (ETDEWEB)

Moroboshi, M. (Yamatake-Honeywell Co. Ltd., Tokyo (Japan))

1993-12-01

The results of investigating time management (permissible value of ignition time and prepurge time) for safety control of combustion relating to a combustor is reported. It is shown that the heating value of hydrocarbon-based fuel is determined by molecular weight irrespective of molecular structure and constant (11200kcal/kg) per unit weight; the heating value of mixture gas of theoretical mixture ratio is constant (1000kcal/m[sup 3]) indifferently of the kind of fuel; and that the product of the heating value of a fuel and the lower limit of its explosion limit is approximately constant (400-600kcal/m[sup 3]). Succeedingly it is shown based on these values that allowable ignition time is determined by the combustion chamber load (ratio of the maximum amount, 10[sup 4]kcal/h, of combustion to the volume of combustion chamber); the effect of dilution by exhaust lengthens it by only about 50%; and that the conventional criterion that the frequency of ventilation of prepurge should be 4-5 or that the minimum time of prepurge should be 30 seconds is appropriate. 6 refs., 4 figs., 1 tab.

Computation and Analysis of EGR Mixing in Internal Combustion Engine Manifolds

OpenAIRE

Sakowitz, Alexander

2013-01-01

This thesis deals with turbulent mixing processes occurring in internal combustion engines, when applying exhaust gas recirculation (EGR). EGR is a very efficient way to reduce emissions of nitrogen oxides (NOx) in internal combustion engines. Exhaust gases are recirculated and mixed with the fresh intake air, reducing the oxygen con- centration of the combustion gas and thus the peak combustion temperatures. This temperature decrease results in a reduction of NOx emissions. When applying EGR...

Effect of Electric Field in the Stabilized Premixed Flame on Combustion Process Emissions

Science.gov (United States)

Otto, Krickis

2017-10-01

The effect of the AC and DC electrical field on combustion processes has been investigated by various researchers. The results of these experiments do not always correlate, due to different experiment conditions and experiment equipment variations. The observed effects of the electrical field impact on the combustion process depends on the applied voltage polarity, flame speed and combustion physics. During the experiment was defined that starting from 1000 V the ionic wind takes the effect on emissions in flue gases, flame shape and combustion instabilities. Simulation combustion process in hermetically sealed chamber with excess oxygen amount 3 % in flue gases showed that the positive effect of electrical field on emissions lies in region from 30 to 400 V. In aforementioned voltage range carbon monoxide emissions were reduced by 6 % and at the same time the nitrogen oxide emissions were increased by 3.5 %.

Combustion distribution control using the extremum seeking algorithm

International Nuclear Information System (INIS)

Marjanovic, A; Djurovic, Z; Kvascev, G; Papic, V; Krstic, M

2014-01-01

Quality regulation of the combustion process inside the furnace is the basis of high demands for increasing robustness, safety and efficiency of thermal power plants. The paper considers the possibility of spatial temperature distribution control inside the boiler, based on the correction of distribution of coal over the mills. Such control system ensures the maintenance of the flame focus away from the walls of the boiler, and thus preserves the equipment and reduces the possibility of ash slugging. At the same time, uniform heat dissipation over mills enhances the energy efficiency of the boiler, while reducing the pollution of the system. A constrained multivariable extremum seeking algorithm is proposed as a tool for combustion process optimization with the main objective of centralizing the flame in the furnace. Simulations are conducted on a model corresponding to the 350MW boiler of the Nikola Tesla Power Plant, in Obrenovac, Serbia

Combustion distribution control using the extremum seeking algorithm

Science.gov (United States)

Marjanovic, A.; Krstic, M.; Djurovic, Z.; Kvascev, G.; Papic, V.

2014-12-01

Quality regulation of the combustion process inside the furnace is the basis of high demands for increasing robustness, safety and efficiency of thermal power plants. The paper considers the possibility of spatial temperature distribution control inside the boiler, based on the correction of distribution of coal over the mills. Such control system ensures the maintenance of the flame focus away from the walls of the boiler, and thus preserves the equipment and reduces the possibility of ash slugging. At the same time, uniform heat dissipation over mills enhances the energy efficiency of the boiler, while reducing the pollution of the system. A constrained multivariable extremum seeking algorithm is proposed as a tool for combustion process optimization with the main objective of centralizing the flame in the furnace. Simulations are conducted on a model corresponding to the 350MW boiler of the Nikola Tesla Power Plant, in Obrenovac, Serbia.

Jet plume injection and combustion system for internal combustion engines

Science.gov (United States)

Oppenheim, Antoni K.; Maxson, James A.; Hensinger, David M.

1993-01-01

An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

Emission characteristics of multiple stage diesel combustion. Effect of exhaust gas recirculation; Nidan nensho diesel kikan no haishutsubutsu tokusei. EGR no eikyo

Energy Technology Data Exchange (ETDEWEB)

Hashizume, T.; Miyamoto, T.; Akagawa, H.; Tsujimura, K. [New A.C.E. Institute Co. Ltd., Tokyo (Japan)

1998-05-01

For an aim to reduce NOx emission from diesel engines, it has become possible to realize it with smoke emission maintained at low levels by taking the following steps: initial combustion is carried out as lean pre-mixed combustion by adopting early fuel injection; the fuel is injected again after completion of this combustion; and EGR is combined with two-stage combustion which performs diffusion combustion under high temperature atmosphere. When a large quantity of EGR is used, cylinder temperature drops to have ignition timing delayed in the first stage, serving for improving fuel consumption. The problem of increase in smoke generation is solved by optimizing the injection timing at the second stage to suppress smoke generation increase, resulting in realization of lower NOx emission. By completing the second-stage fuel injection before ignition of the first-stage injection, it was possible to realize further lower NOx emission. Smoke increase due to higher EGR ratio was suppressed by pre-mixing both fuels injected in the first and second stages, although this is a high load operation. In addition, oxygen concentration and cylinder temperature were reduced, the gas pre-mixture was homogenized, and combustion velocity was suppressed by delaying the angle of ignition timing. This made low smoke combustion at {lambda} = 1 possible even in compressed ignition combustion. 8 refs., 12 figs., 1 tab.

Dynamics of Al/Fe{sub 2}O{sub 3} MIC combustion from short single-pulse photothermal initiation and time-resolved spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Stiegman, Albert E.; Park, Chi-Dong; Mileham, Melissa; Van de Burgt, Lambertus J. [Department of Chemistry and Biochemistry, Florida State University Tallahassee, FL (United States); Kramer, Michael P. [AFRL/MNME Eglin AFB, FL (United States)

2009-08-15

Time-resolved spectroscopy was used to study the dynamics of the photothermal ignition of Al/Fe{sub 2}O{sub 3} metastable intermolecular composites after single short-pulse laser initiation. The dynamics were recorded in several time domains from nanosecond to microsecond to quantify the dynamics from initial laser excitation to combustion. Time-averaged spectral data were also collected for the overall emission occurring during combustion. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

Turbulence-combustion interaction in direct injection diesel engine

Directory of Open Access Journals (Sweden)

Bencherif Mohamed

2014-01-01

Full Text Available The experimental measures of chemical species and turbulence intensity during the closed part of the engine combustion cycle are today unattainable exactly. This paper deals with numerical investigations of an experimental direct injection Diesel engine and a commercial turbocharged heavy duty direct injection one. Simulations are carried out with the kiva3v2 code using the RNG (k-ε model. A reduced mechanism for n-heptane was adopted for predicting auto-ignition and combustion processes. From the calibrated code based on experimental in-cylinder pressures, the study focuses on the turbulence parameters and combustion species evolution in the attempt to improve understanding of turbulence-chemistry interaction during the engine cycle. The turbulent kinetic energy and its dissipation rate are taken as representative parameters of turbulence. The results indicate that chemistry reactions of fuel oxidation during the auto-ignition delay improve the turbulence levels. The peak position of turbulent kinetic energy coincides systematically with the auto-ignition timing. This position seems to be governed by the viscous effects generated by the high pressure level reached at the auto-ignition timing. The hot regime flame decreases rapidly the turbulence intensity successively by the viscous effects during the fast premixed combustion and heat transfer during other periods. It is showed that instable species such as CO are due to deficiency of local mixture preparation during the strong decrease of turbulence energy. Also, an attempt to build an innovative relationship between self-ignition and maximum turbulence level is proposed. This work justifies the suggestion to determine otherwise the self-ignition timing.

Real time NO emissions measurement during cold start in LPG SI engine

International Nuclear Information System (INIS)

Li, Gong; Liu, Zhimin; Li, Zhilong; Qiu, Dongping; Li, Liguang

2007-01-01

To identify combustion occurrence is very important. Traditionally, cylinder pressure has been used as a criterion of combustion occurrence, but it can be unreliable when identifying lean mixture combustion (there is little difference in the cylinder pressure trace between the firing cycle and motoring cycles at the lean combustion limit). This is particularly important for fuels like LPG, which have a good capacity for lean combustion. In this study, a fast response NO detector, CambustionfNOx400, based on the chemiluminescence method, was used to measure real time NO emissions in order to evaluate the technique as a criterion for establishing combustion occurrence. At the same time, this paper presents an investigation of the characteristics of real time NO emissions of the first firing cycle during cold start in a LPG SI engine to determine the optimal excess air factor of the first firing cycle, and the cylinder pressure and crank shaft speed of the engine were measured and recorded. Test results show that the excess air ratio directly influences the cylinder pressure, engine speed and NO emissions of the first firing cycle. As the excess air coefficient is reduced from the lean misfiring limit, NO emissions increase quickly, then reduce quickly and then reduce slowly. NO emissions generally increase with peak cylinder pressure, even at constant excess air coefficient. Real time NO emissions can be used to identify cylinder combustion and misfire occurrence during engine cranking, even at the dilute combustion limit, and real time NO emission can be used to understand the combustion and misfire occurrence. (author)

DIAGNOSIS OF FAILURE OF COMBUSTION IN THE COMBUSTION CHAMBER WITH A THERMOVISION EQUIPMENT

Directory of Open Access Journals (Sweden)

S. V. Vorobiev

2014-01-01

Full Text Available The use of thermovision technology to diagnose failure of the combustion flame test tube of the main combustion chamber gas turbine engine is deal with in the article. Join the thermal radiation of the jet of combustion products and the internal elements was carried out using short-wave thermovision system AGA-782 with spectral spectral filters in several ranges from 3.2 to 5.6 microns. Thermovision is mounted on the axis of the flame tube. The output signal was recorded and processed on a computer in real time, allowing monitor the combustion process and the thermal state of the object during the experiment.

Staged combustion with piston engine and turbine engine supercharger

Science.gov (United States)

Fischer, Larry E [Los Gatos, CA; Anderson, Brian L [Lodi, CA; O'Brien, Kevin C [San Ramon, CA

2011-11-01

A combustion engine method and system provides increased fuel efficiency and reduces polluting exhaust emissions by burning fuel in a two-stage combustion system. Fuel is combusted in a piston engine in a first stage producing piston engine exhaust gases. Fuel contained in the piston engine exhaust gases is combusted in a second stage turbine engine. Turbine engine exhaust gases are used to supercharge the piston engine.

Combustion modeling in waste tanks

International Nuclear Information System (INIS)

Mueller, C.; Unal, C.; Travis, J.R.; Forschungszentrum Karlsruhe

1997-01-01

This paper has two objectives. The first one is to repeat previous simulations of release and combustion of flammable gases in tank SY-101 at the Hanford reservation with the recently developed code GASFLOW-II. The GASFLOW-II results are compared with the results obtained with the HMS/TRAC code and show good agreement, especially for non-combustion cases. For combustion GASFLOW-II predicts a steeper pressure rise than HMS/TRAC. The second objective is to describe a so-called induction parameter model which was developed and implemented into GASFLOW-II and reassess previous calculations of Bureau of Mines experiments for hydrogen-air combustion. The pressure time history improves compared with the one-step model, and the time rate of pressure change is much closer to the experimental data

Effect of W/O Emulsion Fuel Properties on Spray Combustion

Science.gov (United States)

Ida, Tamio; Fuchihata, Manabu; Takeda, Shuuco

This study proposes a realizable technology for an emulsion combustion method that can reduce environmental loading. This paper discusses the effect on spray combustion for W/O emulsion fuel properties with an added agent, and the ratio between water and emulsifier added to a liquid fuel. The addition of water or emulsifier to a liquid fuel affected the spray combustion by causing micro-explosions in the flame due to geometric changes in the sprayed flame and changes to the temperature distribution. Experimental results revealed that the flame length shortened by almost 40% upon the addition of the water. Furthermore, it was found that water was effective in enhancing combustion due to its promoting micro-explosions. Results also showed that when the emulsifier was added to the spray flame, the additive burned in the flame's wake, producing a bright red flame. The flame length was observed to be long as a result. The micro-explosion phenomenon, caused by emulsifier dosage differences, was observed using time-dependent images at a generated frequency and an explosion scale with a high-speed photography method. Results indicated that the micro-explosion phenomenon in the W/O emulsion combustion method effectively promoted the combustion reaction and suppressed soot formation.

Control device for combustible gas concentration

International Nuclear Information System (INIS)

Osawa, Yasuo.

1988-01-01

Purpose: To control the concentration of combustible gases such as hydrogen evolved in a reactor container upon loss-of-coolant accidents. Constitution: Combustible gases evolved from the lower area of a drywell in which a combustible atmosphere is liable to be formed locally are taken out through a take-out pipeway to the outside of a reactor container and processed by a hydrogen-oxygen recombiner. Combustible gases in other areas of the drywell are also introduced to the lower area of the drywell and then taken-out externally for procession. Further, combustible gases in the suppression chamber are introduced by the opening of a vacuum breaking valve through a gas supply pipe to the lower area of the drywell and fluids in the drywell are stirred and diluted with fluids exhausted from the gas supply pipe. Disposition of such take-out pipeway and gas supply pipe can reduce the possibility of forming local combustible atmosphere to improve the integrity of the reactor container. (Kamimura, M.)

Sulfur equilibrium desulfurization of sulfur containing products of combustion

International Nuclear Information System (INIS)

Woodroffe, J.A.; Abichandani, J.S.

1990-01-01

This patent describes the method for the combustion of a carbon- and sulfur-containing fuel for substantially reducing emission of gaseous sulfur compounds formed during combustion of the fuel in a combustion zone. The zone having one or more fuel inlets and one or more oxidizer inlets, and having a combustion products outlet spaced therefrom, and having one or more inorganic sorbent inlets downstream of the fuel inlet(s) and oxidizer inlet(s) and upstream of the combustion products outlet

Reduced nicotine product standards for combustible tobacco: building an empirical basis for effective regulation.

Science.gov (United States)

Donny, Eric C; Hatsukami, Dorothy K; Benowitz, Neal L; Sved, Alan F; Tidey, Jennifer W; Cassidy, Rachel N

2014-11-01

Both the Tobacco Control Act in the U.S. and Article 9 of the Framework Convention on Tobacco Control enable governments to directly address the addictiveness of combustible tobacco by reducing nicotine through product standards. Although nicotine may have some harmful effects, the detrimental health effects of smoked tobacco are primarily due to non-nicotine constituents. Hence, the health effects of nicotine reduction would likely be determined by changes in behavior that result in changes in smoke exposure. Herein, we review the current evidence on nicotine reduction and discuss some of the challenges in establishing the empirical basis for regulatory decisions. To date, research suggests that very low nicotine content cigarettes produce a desirable set of outcomes, including reduced exposure to nicotine, reduced smoking, and reduced dependence, without significant safety concerns. However, much is still unknown, including the effects of gradual versus abrupt changes in nicotine content, effects in vulnerable populations, and impact on youth. A coordinated effort must be made to provide the best possible scientific basis for regulatory decisions. The outcome of this effort may provide the foundation for a novel approach to tobacco control that dramatically reduces the devastating health consequences of smoked tobacco. Copyright © 2014 Elsevier Inc. All rights reserved.

Effects of pilot injection parameters on low temperature combustion diesel engines equipped with solenoid injectors featuring conventional and rate-shaped main injection

International Nuclear Information System (INIS)

D’Ambrosio, S.; Ferrari, A.

2016-01-01

Highlights: • The influence of the principal pilot injection parameters is discussed for low-temperature combustion systems. • Swirl-sweep and dwell-time sweep results are combined to analyze soot emissions. • The pilot injection effects are investigated in injection profiles featuring rate-shaped main injections. - Abstract: The potential of pilot injection has been assessed on a low-temperature combustion diesel engine for automotive applications, which was characterized by a reduced compression-ratio, high EGR rates and postponed main injection timings. Dwell time sweeps have been carried out for pilot injections with distinct energizing times under different representative steady-state working conditions of the medium load and speed area of the New European Driving Cycle. The results of in-cylinder analyses of the pressure, heat-release rate, temperature and emissions are presented. Combustion noise has been shown to decrease significantly when the pilot injected mass increases, while it is scarcely affected by the dwell time between the pilot and main injections. The HC, CO and fuel consumption trends, with respect to both the pilot injection dwell time and mass, are in line with those of conventional combustion systems, and in particular decreasing trends occur as the pilot injection energizing time is increased. Furthermore, a reduced sensitivity of NO_x emissions to both dwell time and pilot injected mass has been found, compared to conventional combustion systems. Finally, it has been observed that soot emissions diminish as the energizing time is shortened, and their dependence on dwell time is influenced to a great extent by the presence of local zones with reduced air-to-fuel ratios within the cylinder. A combined analysis of the results of swirl sweeps and dwell time sweeps is here proposed as a methodology for the detection of any possible interference between pilot combustion burned gases and the main injected fuel. The effect of pilot

Two-stage combustion, a new concept in reducing alkali related operational problem; Tvaastegsfoerbraenning, ett nytt koncept att minska alkalirelaterad driftproblematik

Energy Technology Data Exchange (ETDEWEB)

Hjoernhede, Anders; Hermansson, Sven; Seemann, Martin; Alamia, Alberto; Larsson, Anton; Davidsson, Kent; Niklasson, Fredrik; Atongka Tchoffor, Placid; Jones, Frida

2012-07-01

A possible way to reduce alkali related problems during thermal conversion of fuels into heat and power is to thermally split the fuel into a relatively alkali-lean gas stream and a relatively alkali-rich char stream. The alkali-lean gas stream could then be combusted and used for high-temperature purpose, e.g. superheating of steam. The char residue could be combusted for heating of e.g. steam tubes at inferior temperatures. The purpose of this project has been to study and demonstrate such two-stage combustion, with separation of the early devolatilization from alkali-rich fuels for steam superheating. Within the project, it has been investigated if this type of thermal conversion is thermo-economically feasible. Furthermore, it has been investigated in laboratory and pilot scale trials, which kinds of fuels, temperature levels and fuel residence times that are required to achieve a flue gas with significantly lower concentrations of alkaloids, compared to single-stage conversion. The results from the thermo-economical simulations show that it is possible to arrange the heat exchanger surfaces in a power plant for thermal two-stage conversion. Compared to traditional one-stage combustion, the electricity efficiency could be increased from 35 % to more than 38 %. However, the results from combustion, gasification and pyrolysis in lab, together with gasification trials in the Chalmers pilot plant, show that the investigated woody fuels (bark and wood pellets) do not seem to be feasible for two-stage conversion. These fuels emit alkaloids exclusively in conjunction with the devolatilization in opposite to the desired effect. On the other hand, straw is a potential fuel candidate for two-stage conversion, since straw emits alkaloids during both devolatilization and char conversion. Furthermore, the results show that increased temperature generally causes increased alkali release. From the results it is suggested that the propensity of a fuel to release alkali during

The effects of key parameters on the transition from SI combustion to HCCI combustion in a two-stroke free piston linear engine

International Nuclear Information System (INIS)

Hung, Nguyen Ba; Lim, Ocktaeck; Iida, Norimasa

2015-01-01

Highlights: • A free piston engine is modeled and simulated by three mathematical models. • The models include dynamic model, linear alternator model and thermodynamic model. • The SI-HCCI transition is successful if the key parameters are adjusted suitably. • Spring stiffness has a strong influence on reducing peak temperature in HCCI mode. • Adjusting spark timing helps the SI-HCCI transition to be more convenient. - Abstract: An investigation was conducted to examine the effects of key parameters such as intake temperature, equivalence ratio, engine load, intake pressure, spark timing and spring stiffness on the transition from SI combustion to HCCI combustion in a two-stroke free piston linear engine. Operation of the free piston engine was simulated based on the combination of three mathematical models including a dynamic model, a linear alternator model and a thermodynamic model. These mathematical models were combined and solved by a program written in Fortran. To validate the mathematical models, the simulation results were compared with experimental data in the SI mode. For the transition from SI combustion to HCCI combustion, the simulation results show that if the equivalence ratio is decreased, the intake temperature and engine load should be increased to get a successful SI-HCCI transition. However, the simulation results also show that the in-cylinder pressure is decreased, while the peak in-cylinder temperature in HCCI mode is increased significantly if the intake temperature is increased so much. Beside the successful SI-HCCI transition, the increase of intake pressure from P in = 1.1 bar to P in = 1.6 bar is one of solutions to reduce peak in-cylinder temperature in HCCI mode. However, the simulation results also indicate that if the intake pressure is increased so much (P in = 1.6 bar), the engine knocking problem is occurred. Adjusting spring stiffness from k = 2.9 N/mm to k = 14.7 N/mm is also considered one of useful solutions for

NOx reduction and NO2 emission characteristics in rich-lean combustion of hydrogen

OpenAIRE

Shudo, Toshio; Omori, Kento; Hiyama, Osamu

2008-01-01

Hydrogen is a clean alternative to conventional hydrocarbon fuels, but it is very important to reduce the nitrogen oxides (NOx) emissions generated by hydrogen combustion. The rich-lean combustion or staged combustion is known to reduce NOx emissions from continuous combustion burners such as gas turbines and boilers, and NOx reduction effects have been demonstrated for hydrocarbon fuels. The authors applied rich-lean combustion to a hydrogen gas turbine and showed its NOx reduction effect in...

Combustion and agglomeration of aluminized high-energy compositions

International Nuclear Information System (INIS)

Korotkikh, A G; Slyusarskiy, K V; Arkhipov, V A; Glotov, O G

2015-01-01

The results of combustion study for high-energy compositions (HECs) based on ammonium perchlorate (AP), butadiene rubber and ultrafine powder (UFP) aluminum Alex, and agglomeration of metal particles on the burning surface and composition of condensed combustion products (CCPs) are presented. It was found that partial replacement 2 wt. % of Alex by iron UFP in HEC increases the burning rate 1.3—1.4 times at the range of nitrogen pressure 2.0-7.5 MPa and reduces the mean diameter of CCPs particles d 43 from 37.4 μm to 33.5 μm at pressure ∼ 4 MPa. Upon partial replacement 2 wt. % of Alex by boron UFP in HEC the recoil force of gasification products outflow from burning surface is increased by 9 % and the burning rate of HEC does not change in the above pressure range, while the mean diameter of CCPs particles is reduced to 32.6 μm at p ∼ 4 MPa. (paper)

Large eddy simulation and combustion instabilities; Simulation des grandes echelles et instabilites de combustion

Energy Technology Data Exchange (ETDEWEB)

Lartigue, G.

2004-11-15

The new european laws on pollutants emission impose more and more constraints to motorists. This is particularly true for gas turbines manufacturers, that must design motors operating with very fuel-lean mixtures. Doing so, pollutants formation is significantly reduced but the problem of combustion stability arises. Actually, combustion regimes that have a large excess of air are naturally more sensitive to combustion instabilities. Numerical predictions of these instabilities is thus a key issue for many industrial involved in energy production. This thesis work tries to show that recent numerical tools are now able to predict these combustion instabilities. Particularly, the Large Eddy Simulation method, when implemented in a compressible CFD code, is able to take into account the main processes involved in combustion instabilities, such as acoustics and flame/vortex interaction. This work describes a new formulation of a Large Eddy Simulation numerical code that enables to take into account very precisely thermodynamics and chemistry, that are essential in combustion phenomena. A validation of this work will be presented in a complex geometry (the PRECCINSTA burner). Our numerical results will be successfully compared with experimental data gathered at DLR Stuttgart (Germany). Moreover, a detailed analysis of the acoustics in this configuration will be presented, as well as its interaction with the combustion. For this acoustics analysis, another CERFACS code has been extensively used, the Helmholtz solver AVSP. (author)

Experimental and theoretical analysis of the combustion process at low loads of a diesel natural gas dual-fuel engine

International Nuclear Information System (INIS)

Li, Weifeng; Liu, Zhongchang; Wang, Zhongshu

2016-01-01

To construct an effective method to analyze the combustion process of dual fuel engines at low loads, effects of combustion boundaries on the combustion process of an electronically controlled diesel natural gas dual-fuel engine at low loads were investigated. Three typical combustion modes, including h, m and n, appeared under different combustion boundaries. In addition, the time-sequenced characteristic and the heat release rate-imbalanced characteristic were found in the dual fuel engine combustion process. To quantify these characteristics, two quantitative indicators, including the TSC (time-sequenced coefficient) and the HBC (HRR-balanced coefficient) were defined. The results show that increasing TSC and HBC can decrease HC (hydrocarbon) emissions and improve the BTE (brake thermal efficiency) significantly. The engine with the n combustion mode can obtain the highest BTE and the lowest HC emissions, followed by m, and then h. However, the combustion process of the engine will deteriorate sharply if boundary conditions are not strictly controlled in the n combustion mode. Based on the n combustion mode, advancing the start of diesel injection significantly, using large EGR (exhaust gas recirculation) rate and appropriately intake throttling can effectively reduce HC emissions and improve the BTE of dual fuel engines at low loads with relatively high natural gas PES (percentage energy substitution). - Highlights: • We reported three typical combustion modes of a dual-fuel engine at low loads. • Time-sequenced characteristic was put forward and qualified. • HRR-imbalanced characteristic was put forward and qualified. • Three combustion modes appeared as equivalence ratio/diesel injection timing varied. • The engine performance varied significantly with different combustion mode.

Controlling cyclic combustion timing variations using a symbol-statistics predictive approach in an HCCI engine

International Nuclear Information System (INIS)

Ghazimirsaied, Ahmad; Koch, Charles Robert

2012-01-01

Highlights: ► Misfire reduction in a combustion engine based on chaotic theory methods. ► Chaotic theory analysis of cyclic variation of a HCCI engine near misfire. ► Symbol sequence approach is used to predict ignition timing one cycle-ahead. ► Prediction is combined with feedback control to lower HCCI combustion variation. ► Feedback control extends the HCCI operating range into the misfire region. -- Abstract: Cyclic variation of a Homogeneous Charge Compression Ignition (HCCI) engine near misfire is analyzed using chaotic theory methods and feedback control is used to stabilize high cyclic variations. Variation of consecutive cycles of θ Pmax (the crank angle of maximum cylinder pressure over an engine cycle) for a Primary Reference Fuel engine is analyzed near misfire operation for five test points with similar conditions but different octane numbers. The return map of the time series of θ Pmax at each combustion cycle reveals the deterministic and random portions of the dynamics near misfire for this HCCI engine. A symbol-statistic approach is used to predict θ Pmax one cycle-ahead. Predicted θ Pmax has similar dynamical behavior to the experimental measurements. Based on this cycle ahead prediction, and using fuel octane as the input, feedback control is used to stabilize the instability of θ Pmax variations at this engine condition near misfire.

Combustion characteristics and influential factors of isooctane active-thermal atmosphere combustion assisted by two-stage reaction of n-heptane

Energy Technology Data Exchange (ETDEWEB)

Lu, Xingcai; Ji, Libin; Ma, Junjun; Zhou, Xiaoxin; Huang, Zhen [Key Lab. for Power Machinery and Engineering of MOE, Shanghai Jiao Tong University, 200240 Shanghai (China)

2011-02-15

This paper presents an experimental study on the isooctane active-thermal atmosphere combustion (ATAC) which is assisted by two-stage reaction of n-heptane. The active-thermal atmosphere is created by low- and high-temperature reactions of n-heptane which is injected at intake port, and isooctane is directly injected into combustion chamber near the top dead center. The effects of isooctane injection timing, active-thermal atmosphere intensity, overall equivalence ratio, and premixed ratio on combustion characteristics and emissions are investigated. The experimental results reveal that, the isooctane ignition and combustion can be classified to thermal atmosphere combustion, active atmosphere combustion, and active-thermal atmosphere combustion respectively according to the extent of n-heptane oxidation as well as effects of isooctane quenching and charge cooling. n-Heptane equivalence ratio, isooctane equivalence ratio and isooctane delivery advance angle are major control parameters. In one combustion cycle, the isooctane ignited and burned after those of n-heptane, and then this combustion phenomenon can also be named as dual-fuel sequential combustion (DFSC). The ignition timing of the overall combustion event is mainly determined by n-heptane equivalence ratio and can be controlled in flexibility by simultaneously adjusting isooctane equivalence ratio. The isooctane ignition regime, overall thermal efficiency, and NO{sub x} emissions show strong sensitivity to the fuel delivery advance angle between 20 CA BTDC and 25 CA BTDC. (author)

OxyFuel combustion of Coal and Biomass

DEFF Research Database (Denmark)

Toftegaard, Maja Bøg

The power and heat producing sector is facing a continuously increasing demand to reduce its emissions of CO2. Oxyfuel combustion combined with CO2 storage is suggested as one of the possible, promising technologies which will enable the continuous use of the existing fleet of suspension-fired po......The power and heat producing sector is facing a continuously increasing demand to reduce its emissions of CO2. Oxyfuel combustion combined with CO2 storage is suggested as one of the possible, promising technologies which will enable the continuous use of the existing fleet of suspension......-fired power plants burning coal or other fuels during the period of transition to renewable energy sources. The oxyfuel combustion process introduces several changes to the power plant configuration. Most important, the main part of the flue gas is recirculated to the boiler and mixed with pure oxygen....... The oxidant thus contains little or no nitrogen and a near-pure CO2 stream can be produced by cooling the flue gas to remove water. The change to the oxidant composition compared to combustion in air will induce significant changes to the combustion process. This Ph.D. thesis presents experimental...

Construction of a power plant with prototype DLN combustion turbines

Energy Technology Data Exchange (ETDEWEB)

Wilkinson, M.L. [CSW Energy, Dallas, TX (United States); Drummond, L.J. [Zurn NEPCO, Redmond, WA (United States)

1996-12-31

Design and construction of a power plant is always a difficult process and this is especially true when the main keystone, the combustion turbine engine, is being modified by the manufacturer resulting in numerous changes in the design interfaces. The development of the design and construction of the Orange Cogeneration Facility has been in parallel with major modification of the LM6000 to DLE technology (a Dry Low NO{sub x} combustion system). The Dry Low NO{sub x} Combustion System for a combustion turbine offered a means to reduce water usage, lower Zero Liquid Discharge System operating costs and reduce emissions to meet Florida Department of Environmental Protection requirements. This development was successfully accomplished by Owner, EPC contractor and Combustion Turbine Manufacturer by maintaining flexibility in the design and construction while the design interfaces and performance of the combustion turbines were being finalized.

Experimental validation for combustion analysis of GOTHIC 6.1b code in 2-dimensional premixed combustion experiments

International Nuclear Information System (INIS)

Lee, J. Y.; Lee, J. J.; Park, K. C.

2003-01-01

In this study, the prediction capability of GOTHIC code for hydrogen combustion phenomena was validated with the results of two-dimensional premixed hydrogen combustion experiment executed by Seoul National University. In the experimental results, we could confirm the propagation characteristics of hydrogen flame such as buoyancy effect, flame front shape etc.. The combustion time of the tests was about 0.1 sec.. In the GOTHIC analyses results, the GOTHIC code could predict the overall hydrogen flame propagation characteristics but the buoyancy effect and flame shape did not compare well with the experimental results. Especially, in case of the flame propagate to the dead-end, GOTHIC predicted the flame did not affected by the flow and this cause quite different results in flame propagation from experimental results. Moreover the combustion time of the analyses was about 1 sec. which is ten times longer than the experimental result. To obtain more reasonable analysis results, it is necessary that combustion model parameters in GOTHIC code apply appropriately and hydrogen flame characteristics be reflected in solving governing equations

Application of macro-cellular SiC reactor to diesel engine-like injection and combustion conditions

Science.gov (United States)

Cypris, Weclas, M.; Greil, P.; Schlier, L. M.; Travitzky, N.; Zhang, W.

2012-05-01

One of novel combustion technologies for low emissions and highly efficient internal combustion engines is combustion in porous reactors (PM). The heat release process inside combustion reactor is homogeneous and flameless resulting in a nearly zero emissions level. Such combustion process, however is non-stationary, is performed under high pressure with requirement of mixture formation directly inside the combustion reactor (high pressure fuel injection). Reactor heat capacity resulting in lowering of combustion temperature as well as internal heat recuperation during the engine cycle changes the thermodynamic conditions of the process as compared to conventional engine. For the present investigations a macro-cellular lattice structure based on silicon carbide (non-foam structure) with 600 vertical cylindrical struts was fabricated and applied to engine-like combustion conditions (combustion chamber). The lattice design with a high porosity > 80% was shaped by indirect three-dimensional printing of a SiC powder mixed with a dextrin binder which also serves as a carbon precursor. In order to perform detailed investigations on low-and high-temperature oxidation processes in porous reactors under engine-like conditions, a special combustion chamber has been built and equipped with a Diesel common-rail injection system. This system simulates the thermodynamic conditions at the time instance of injection onset (corresponding to the nearly TDC of compression in a real engine). Overall analysis of oxidation processes (for variable initial pressure, temperature and air excess ratio) for free Diesel spray combustion and for combustion in porous reactor allows selection of three regions representing different characteristics of the oxidation process represented by a single-step and multi-step reactions Another characteristic feature of investigated processes is reaction delay time. There are five characteristic regions to be selected according to the delay time (t) duration

Effect of Metal Additives on the Combustion Characteristics of High-Energy Materials

Directory of Open Access Journals (Sweden)

Korotkikh Alexander

2016-01-01

Full Text Available Thermodynamic calculation of combustion parameters and equilibrium composition of HEMs combustion products showed, that at the increase of aluminum powder dispersity the specific impulse and combustion temperature of solid propellants are reduced due to the decrease of the mass fraction of active aluminum in particles. Partial or complete replacement of aluminum by metal powder (B, Mg, AlB2, Al\\Mg alloy, Fe, Ti and Zr in HEMs composition leads to the reduce of the specific impulse and combustion temperature. Replacement of aluminum powder by boron and magnesium in HEM reduces the mass fraction of condensed products in the combustion chamber of solid rocket motor. So, for compositions HEMs with boron and aluminum boride the mass fraction in chamber is reduced by 24 and 36 %, respectively, with respect to the composition HEMs with Al powder. But the mass fraction of CCPs in the nozzle exit increases by 13 % for HEMs with aluminum boride due to the formation of boron oxide in the condensed combustion products. Partial replacement of 2 wt. % aluminum powder by iron and copper additives in HEM leads to the reduce of CCPs mass fraction in chamber by 4–10 % depending on the aluminum powder dispersity duo to these metals are not formed condensed products at the HEMs combustion in chamber.

Oxyfuel combustion for below zero CO{sub 2} emissions

Energy Technology Data Exchange (ETDEWEB)

Boeg Toftegaard, M; Hansen, Kim G; Fisker, D [DONG Energy Power, Hvidovre (Denmark); Brix, J; Brun Hansen, B; Putluru, S S.R.; Jensen, Peter Arendt; Glarborg, Peter; Degn Jensen, A [Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark); Montgomery, M [Technical Univ. of Denmark. DTU Mechanical Engineering, Kgs. Lyngby (Denmark)

2011-07-01

The reduction of CO{sub 2} emissions is of highest concern in relation to limiting the anthropogenic impacts on the environment. Primary focus has gathered on the large point sources of CO{sub 2} emissions constituted by large heat and power stations and other heavy, energy-consuming industry. Solutions are sought which will enable a significant reduction of the anthropogenic CO{sub 2} emissions during the transformation period from the use of fossil fuels to renewable sources of energy. Carbon capture and storage (CCS) has the potential to significantly reduce CO{sub 2} emissions from power stations while allowing for the continuous utilisation of the existing energy producing system in the transformation period. Oxyfuel combustion is one of the possible CCS technologies which show promising perspectives for implementation in industrial scale within a relatively short period of time. Oxyfuel combustion deviates from conventional combustion in air by using a mixture of pure oxygen and recirculated flue gas as the combustion medium thereby creating a flue gas highly concentrated in CO{sub 2} making the capture process economically more feasible compared to technologies with capture from more dilute CO{sub 2} streams. This project has investigated a number of the fundamental and practical issues of the oxyfuel combustion process by experimental, theoretical, and modelling investigations in order to improve the knowledge of the technology. The subjects investigated cover: general combustion characteristics of coal and biomass (straw) and mixtures thereof, formation and emission of pollutants, ash characteristics, flue gas cleaning for SO{sub 2} by wet scrubbing with limestone and for NO{sub x} by selective catalytic reduction (SCR), corrosion of boiler heat transfer surfaces, operation and control of large suspension-fired boilers, and the perspectives for the implementation of oxyfuel combustion s a CO{sub 2} sequestration solution in the Danish power production

Modelling of fuel spray and combustion in diesel engines

Energy Technology Data Exchange (ETDEWEB)

Huttunen, M T; Kaario, O T [VTT Energy, Espoo (Finland)

1998-12-31

Fuel spray and air motion characteristics and combustion in direct injection (DI) diesel engines was studied using computational models of the commercial CFD-code FIRE. Physical subprocesses modelled included Lagrangian spray droplet movement and behaviour (atomisation, evaporation and interaction of spray droplets) and combustion of evaporated liquid spray in the gas phase. Fuel vapour combustion rate was described by the model of Magnussen and Hjertager. The standard k,{epsilon}-model was used for turbulence. In order to be able to predict combustion accurately, the fuel spray penetration should be predicted with reasonable accuracy. In this study, the standard drag coefficient had to be reduced in order to match the computed penetration to the measured one. In addition, the constants in the submodel describing droplet breakup also needed to be adjusted for closer agreement with the measurements. The characteristic time scale of fuel consumption rate k/C{sub R} {epsilon} strongly influenced the heat release and in-cylinder pressure. With a value around 2.0 to 5.0 for C{sub R}, the computed in-cylinder pressure during the compression stroke agreed quite well with the measurements. On the other hand, the in-cylinder pressure was underpredicted during the expansion stroke. This is partly due to the fact that hydrocarbon fuel combustion was modelled as a one-step reaction reading to CO{sub 2} and H{sub 2}O and inadequate description of the mixing of reactants and combustion products. (author) 16 refs.

Modelling of fuel spray and combustion in diesel engines

Energy Technology Data Exchange (ETDEWEB)

Huttunen, M.T.; Kaario, O.T. [VTT Energy, Espoo (Finland)

1997-12-31

Fuel spray and air motion characteristics and combustion in direct injection (DI) diesel engines was studied using computational models of the commercial CFD-code FIRE. Physical subprocesses modelled included Lagrangian spray droplet movement and behaviour (atomisation, evaporation and interaction of spray droplets) and combustion of evaporated liquid spray in the gas phase. Fuel vapour combustion rate was described by the model of Magnussen and Hjertager. The standard k,{epsilon}-model was used for turbulence. In order to be able to predict combustion accurately, the fuel spray penetration should be predicted with reasonable accuracy. In this study, the standard drag coefficient had to be reduced in order to match the computed penetration to the measured one. In addition, the constants in the submodel describing droplet breakup also needed to be adjusted for closer agreement with the measurements. The characteristic time scale of fuel consumption rate k/C{sub R} {epsilon} strongly influenced the heat release and in-cylinder pressure. With a value around 2.0 to 5.0 for C{sub R}, the computed in-cylinder pressure during the compression stroke agreed quite well with the measurements. On the other hand, the in-cylinder pressure was underpredicted during the expansion stroke. This is partly due to the fact that hydrocarbon fuel combustion was modelled as a one-step reaction reading to CO{sub 2} and H{sub 2}O and inadequate description of the mixing of reactants and combustion products. (author) 16 refs.

Environmental optimisation of waste combustion

Energy Technology Data Exchange (ETDEWEB)

Schuster, Robert [AaF Energikonsult, Stockholm (Sweden); Berge, Niclas; Stroemberg, Birgitta [TPS Termiska Processer AB, Nykoeping (Sweden)

2000-12-01

The regulations concerning waste combustion evolve through R and D and a strive to get better and common regulations for the European countries. This study discusses if these rules of today concerning oxygen concentration, minimum temperature and residence time in the furnace and the use of stand-by burners are needed, are possible to monitor, are the optimum from an environmental point of view or could be improved. No evidence from well controlled laboratory experiments validate that 850 deg C in 6 % oxygen content in general is the best lower limit. A lower excess air level increase the temperature, which has a significant effect on the destruction of hydrocarbons, favourably increases the residence time, increases the thermal efficiency and the efficiency of the precipitators. Low oxygen content is also necessary to achieve low NO{sub x}-emissions. The conclusion is that the demands on the accuracy of the measurement devices and methods are too high, if they are to be used inside the furnace to control the combustion process. The big problem is however to find representative locations to measure temperature, oxygen content and residence time in the furnace. Another major problem is that the monitoring of the operation conditions today do not secure a good combustion. It can lead to a false security. The reason is that it is very hard to find boilers without stratifications. These stratifications (stream lines) has each a different history of residence time, mixing time, oxygen and combustible gas levels and temperature, when they reach the convection area. The combustion result is the sum of all these different histories. The hydrocarbons emission is in general not produced at a steady level. Small clouds of unburnt hydrocarbons travels along the stream lines showing up as peaks on a THC measurement device. High amplitude peaks has a tendency to contain higher ratio of heavy hydrocarbons than lower peaks. The good correlation between some easily detected

Analyzing a low NO[sub x] concentric combustion system

Energy Technology Data Exchange (ETDEWEB)

Kotler, V.R.; Eremeev, A.V.

1992-05-01

Discusses concentric combustion technology developed by Combustion Engineering, Inc. (USA) to reduce NO[sub x] emissions from pulverized coal-fired boilers. The major innovation consists in arranging existing independent secondary air burners into three pairs of concentric combustion burners. Using high-deflection angle concentric combustion burners, higher oxygen concentration near the boiler walls, reduced erosion and lower probability of slag deposition on the heat shield are achieved. The technology was tested at the 165 MW Valmont power plant and 350 MW Cherokee power plant. Reduction of 55.7% (to 0.294 kg/GJ) in NO[sub x] emissions with a boiler efficiency of 86.35% was achieved. Highest NO[sub x] reduction efficiency was observed at full load (highest tertiary air supply). Burner design, performance, relations of NO[sub x] emissions and tertiary air blast as well as fuel entrainment prior to and after upgrading are given. Methods of reducing slag deposition in boilers are considered. 2 refs.

Evaporation and Ignition Characteristics of Water Emulsified Diesel under Conventional and Low Temperature Combustion Conditions

Directory of Open Access Journals (Sweden)

Zhaowen Wang

2017-07-01

Full Text Available The combination of emulsified diesel and low temperature combustion (LTC technology has great potential in reducing engine emissions. A visualization study on the spray and combustion characteristics of water emulsified diesel was conducted experimentally in a constant volume chamber under conventional and LTC conditions. The effects of ambient temperature on the evaporation, ignition and combustion characteristics of water emulsified diesel were studied under cold, evaporating and combustion conditions. Experimental results showed that the ambient temperature had little effect on the spray structures, in terms of the liquid core length, the spray shape and the spray area. However, higher ambient temperature slightly reduced the Sauter Mean Diameter (SMD of the spray droplets. The auto-ignition delay time increased significantly with the decrease of the ambient temperature. The ignition process always occurred at the entrainment region near the front periphery of the liquid core. This entrainment region was evolved from the early injected fuel droplets which were heated and mixed by the continuous entrainment until the local temperature and equivalence ratio reached the ignition condition. The maximum value of integrated natural flame luminosity (INFL reduced by 60% when the ambient temperature dropped from 1000 to 800 K, indicating a significant decrease of the soot emissions could be achieved by LTC combustion mode than the conventional diesel engines.

A synthesis of carbon dioxide emissions from fossil-fuel combustion

DEFF Research Database (Denmark)

Andres, R.J.; Boden, T.A.; Bréon, F.-M.

2012-01-01

This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores our knowledge of these emissions in terms......; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions......, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossilfuel carbon dioxide emissions are known to within 10% uncertainty (95% confidence interval). Uncertainty on individual national total fossil-fuel carbon...

Establishment of Combustion Model for Isooctane HCCI Marine Diesel Engine and Research on the Combustion Characteristic

Directory of Open Access Journals (Sweden)

Li Biao

2016-01-01

Full Text Available The homogeneous charge compression ignition (HCCI combustion mode applied in marine diesel engine is expected to be one of alternative technologies to decrease nitrogen oxide (NOX emission and improve energy utilization rate. Applying the chemical-looping combustion (CLC mechanism inside the cylinder, a numerical study on the HCCI combustion process is performed taking a marine diesel engine as application object. The characteristic feature of combustion process is displayed. On this basis, the formation and emission of NOX are analyzed and discussed. The results indicate that the HCCI combustion mode always exhibit two combustion releasing heats: low-temperature reaction and high-temperature reaction. The combustion phase is divided into low-temperature reaction zone, high-temperature reaction zone and negative temperature coefficient (NTC zone. The operating conditions of the high compression ratio, high intake air temperature, low inlet pressure and small excess air coefficient would cause the high in-cylinder pressure which often leads engine detonation. The low compression ratio, low intake air temperature and big excess air coefficient would cause the low combustor temperature which is conducive to reduce NOX emissions. These technological means and operating conditions are expected to meet the NOX emissions limits in MARPOL73/78 Convention-Annex VI Amendment.

Hydrogen enrichment of an internal combustion engine via closed loop thermochemical recuperation

NARCIS (Netherlands)

Zwitserlood, J.G.; Hofman, T.; Erickson, P.A.

2013-01-01

Hydrogen enrichment in an internal combustion engine can greatly improve efficiency and at the same time reduce emissions without the need for extensive engine modifications. One option for a hydrogen source for the enrichment is actively producing hydrogen on-board the vehicle through steam

Reburning technology - a means to reduce NOx emissions

International Nuclear Information System (INIS)

Kremer, H.; Lorra, M.

1999-01-01

Nitrogen oxide emission control technologies can be classified as either combustion modifications to minimize the NO production or post-combustion flue gas treatment to reduce the NO concentration afterwards. The techniques for minimizing NOx Production includes the use of low-NOx burners, overfire air (staged combustion) and boiler combustion optimization. Procedures for flue gas treatment can be subdivided into selective catalytic reduction (SCR) or selective non-catalytic reduction (SNCR). The re burning process is a selective non-catalytic technology which is applicable to a wide variety of boilers and can be implemented within a relatively short period of time. The NOx reduction potential of this technique is in the range of 50 % up to 70 %. (author)

Boiler for combustion fuel in a fluidized bed

Directory of Open Access Journals (Sweden)

Laković Mirjana S.

2015-01-01

Full Text Available Fuel combustion in fluidized bed combustion is a process that is current and which every day gives more attention and there are many studies that have been closely associated with this technology. This combustion technology is widespread and constantly improving the range of benefits it provides primarily due to reduced emissions. This paper presents the boilers for combustion in a fluidized bed, whit characteristics and advantages. Also is shown the development of this type of boilers in Republic of Serbia. In this paper is explained the concept of fluidized bed combustion. Boilers for this type of combustion can be improved and thereby increase their efficiency level. More detailed characteristics are given for boilers with bubbling and circulating fluidized bed as well as their mutual comparison.

Enhancement of exergy efficiency in combustion systems using flameless mode

International Nuclear Information System (INIS)

Hosseini, Seyed Ehsan; Wahid, Mazlan Abdul

2014-01-01

Highlights: • Exergy efficiency in flameless combustion mode is 13% more than conventional combustion. • The maximum exergy efficiency in flameless combustion mode is achieved when oxidizer contains 10% oxygen. • Exergy destruction of flameless combustion is maximized when CO 2 is used for dilution of oxidizer. - Abstract: An exergitic-based analysis of methane (CH 4 ) conventional and flameless combustion in a lab-scale furnace is performed to determine the rate of pollutant formation and the effective potential of a given amount of fuel in the various combustion modes. The effects of inlet air temperature on exergy efficiency and pollutant formation of conventional combustion in various equivalence ratios are analyzed. The rate of exergy destruction in different conditions of flameless combustion (various equivalence ratios, oxygen concentration in the oxidizer and the effects of diluent) are computed using three-dimensional (3D) computational fluid dynamic (CFD). Fuel consumption reduction and exergy efficiency augmentation are the main positive consequences of using preheated air temperature in conventional combustion, however pollutants especially NO x formation increases dramatically. Low and moderate temperature inside the chamber conducts the flameless combustion system to low level pollutant formation. Fuel consumption and exergy destruction reduce drastically in flameless mode in comparison with conventional combustion. Exergy efficiency of conventional and flameless mode is 75% and 88% respectively in stoichiometric combustion. When CO 2 is used for dilution of oxidizer, chemical exergy increases due to high CO 2 concentration in the combustion products and exergy efficiency reduces around 2% compared to dilution with nitrogen (N 2 ). Since the rate of irreversibilities in combustion systems is very high in combined heat and power (CHP) generation and other industries, application of flameless combustion could be effective in terms of pollutant

Study of experimental validation for combustion analysis of GOTHIC code

International Nuclear Information System (INIS)

Lee, J. Y.; Yang, S. Y.; Park, K. C.; Jeong, S. H.

2001-01-01

In this study, present lumped and subdivided GOTHIC6 code analyses of the premixed hydrogen combustion experiment at the Seoul National University and comparison with the experiment results. The experimental facility has 16367 cc free volume and rectangular shape. And the test was performed with unit equivalence ratio of the hydrogen and air, and with various location of igniter position. Using the lumped and mechanistic combustion model in GOTHIC6 code, the experiments were simulated with the same conditions. In the comparison between experiment and calculated results, the GOTHIC6 prediction of the combustion response does not compare well with the experiment results. In the point of combustion time, the lumped combustion model of GOTHIC6 code does not simulate the physical phenomena of combustion appropriately. In the case of mechanistic combustion model, the combustion time is predicted well, but the induction time of calculation data is longer than the experiment data remarkably. Also, the laminar combustion model of GOTHIC6 has deficiency to simulate combustion phenomena unless control the user defined value appropriately. And the pressure is not a proper variable that characterize the three dimensional effect of combustion

A reduced fidelity model for the rotary chemical looping combustion reactor

KAUST Repository

Iloeje, Chukwunwike O.; Zhao, Zhenlong; Ghoniem, Ahmed F.

2017-01-01

The rotary chemical looping combustion reactor has great potential for efficient integration with CO capture-enabled energy conversion systems. In earlier studies, we described a one-dimensional rotary reactor model, and used it to demonstrate

Application of Pareto-efficient combustion modeling framework to large eddy simulations of turbulent reacting flows

Science.gov (United States)

Wu, Hao; Ihme, Matthias

2017-11-01

The modeling of turbulent combustion requires the consideration of different physico-chemical processes, involving a vast range of time and length scales as well as a large number of scalar quantities. To reduce the computational complexity, various combustion models are developed. Many of them can be abstracted using a lower-dimensional manifold representation. A key issue in using such lower-dimensional combustion models is the assessment as to whether a particular combustion model is adequate in representing a certain flame configuration. The Pareto-efficient combustion (PEC) modeling framework was developed to perform dynamic combustion model adaptation based on various existing manifold models. In this work, the PEC model is applied to a turbulent flame simulation, in which a computationally efficient flamelet-based combustion model is used in together with a high-fidelity finite-rate chemistry model. The combination of these two models achieves high accuracy in predicting pollutant species at a relatively low computational cost. The relevant numerical methods and parallelization techniques are also discussed in this work.

Mechanism of influence water vapor on combustion characteristics of propane-air mixture

Science.gov (United States)

Larionov, V. M.; Mitrofanov, G. A.; Sachovskii, A. V.; Kozar, N. K.

2016-01-01

The article discusses the results of an experimental study of the effect of water vapor at the flame temperature. Propane-butane mixture with air is burning on a modified Bunsen burner. Steam temperature was varied from 180 to 260 degrees. Combustion parameters changed by steam temperature and its proportion in the mixture with the fuel. The fuel-air mixture is burned in the excess air ratio of 0.1. It has been established that the injection of steam changes the characteristics of combustion fuel-air mixture and increase the combustion temperature. The concentration of CO in the combustion products is substantially reduced. Raising the temperature in the combustion zone is associated with increased enthalpy of the fuel by the added steam enthalpy. Reducing the concentration of CO is caused by decrease in the average temperature in the combustion zone by applying steam. Concentration of active hydrogen radicals and oxygen increases in the combustion zone. That has a positive effect on the process of combustion.

Effects of Temperature and Residence Time on the Emissions of PIC and Fine Particles during Fixed Bed Combustion of Conifer Stemwood Pellets

Energy Technology Data Exchange (ETDEWEB)

Boman, Christoffer; Lindmark, Fredrik; Oehman, Marcus; Nordin, Anders [Umeaa Univ. (Sweden). Energy Technology and Thermal Process Chemistry; Pettersson, Esbjoern [Energy Technology Centre, Piteaa (Sweden); Westerholm, Roger [Stockholm Univ., Arrhenius Laboratory (Sweden). Dept. of Analytical Chemistry

2006-07-15

The use of wood fuel Pellets has proved to be well suited for the small-scale market enabling controlled and efficient combustion with low emission of products of incomplete combustion (PIC). Still a potential for further emission reduction exists and a thorough understanding of the influence of combustion conditions on the emission characteristics of air pollutants like PAH and particulate matter (PM) is important. The objective was to determine the effects of temperature and residence time on the emission performance and characteristics with focus on hydrocarbons and PM during combustion of conifer stemwood Pellets in a laboratory fixed bed reactor (<5 kW). Temperature and residence time after the bed section were varied according to statistical experimental designs (650-970 deg C and 0.5-3.5 s) with the emission responses; CO, organic gaseous carbon, NO, 20 VOC compounds, 43 PAH compounds, PM{sub tot}, fine particle mass/count median diameter (MMD and CMD) and number concentration. Temperature was negatively correlated with the emissions of all studied PIC with limited effects of residence time. The PM{sub tot} emissions of 15-20 mg/MJ was in all cases dominated by fine (<1 {mu}m) particles of K, Na, S, Cl, C, O and Zn. Increased residence time resulted in increased fine particle sizes (i.e. MMD and CMD) and decreased number concentrations. The importance of high temperature (>850 deg C) in the bed zone with intensive, air rich and well mixed isothermal conditions for 0.5-1.0 s in the post combustion zone was illustrated for wood Pellets combustion with almost a total depletion of all studied PIC. The results emphasize the need for further verification studies and technology development work.

Application of Fly Ash from Solid Fuel Combustion in Concrete

DEFF Research Database (Denmark)

Pedersen, Kim Hougaard

2008-01-01

with implementation of low-NOx combustion technologies. The present thesis concerns three areas of importance within this field: 1) testing of fly ash adsorption behavior; 2) the influence of fuel type and combustion conditions on the ash adsorption behaviour including full-scale experiments at the power plant...... has a low sensitivity toward small variations in AEA adsorption between different fly ashes and it requires further work before a finished procedure is accomplished. Finally, it was shown that changes in temperature affect both test methods. Pulverized fuel has been combusted in an entrained flow...... formation. It was found that the AEA adsorption of the fly ash was reduced up to five times compared to reference operation, when the plant was operated with minimum furnace air staging, three levels of burners instead of four and without recycled flue gas. The lower AEA requirements of the fly ash...

Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies

Energy Technology Data Exchange (ETDEWEB)

Chia-fon F. Lee; Alan C. Hansen

2010-09-30

In accordance with meeting DOE technical targets this research was aimed at developing and optimizing new fuel injection technologies and strategies for the combustion of clean burning renewable fuels in diesel engines. In addition a simultaneous minimum 20% improvement in fuel economy was targeted with the aid of this novel advanced combustion system. Biodiesel and other renewable fuels have unique properties that can be leveraged to reduce emissions and increase engine efficiency. This research is an investigation into the combustion characteristics of biodiesel and its impacts on the performance of a Low Temperature Combustion (LTC) engine, which is a novel engine configuration that incorporates technologies and strategies for simultaneously reducing NOx and particulate emissions while increasing engine efficiency. Generating fundamental knowledge about the properties of biodiesel and blends with petroleum-derived diesel and their impact on in-cylinder fuel atomization and combustion processes was an important initial step to being able to optimize fuel injection strategies as well as introduce new technologies. With the benefit of this knowledge experiments were performed on both optical and metal LTC engines in which combustion and emissions could be observed and measured under realistic conditions. With the aid these experiments and detailed combustion models strategies were identified and applied in order to improve fuel economy and simultaneously reduce emissions.

Multi-User Hardware Solutions to Combustion Science ISS Research

Science.gov (United States)

Otero, Angel M.

2001-01-01

In response to the budget environment and to expand on the International Space Station (ISS) Fluids and Combustion Facility (FCF) Combustion Integrated Rack (CIR), common hardware approach, the NASA Combustion Science Program shifted focus in 1999 from single investigator PI (Principal Investigator)-specific hardware to multi-user 'Minifacilities'. These mini-facilities would take the CIR common hardware philosophy to the next level. The approach that was developed re-arranged all the investigations in the program into sub-fields of research. Then common requirements within these subfields were used to develop a common system that would then be complemented by a few PI-specific components. The sub-fields of research selected were droplet combustion, solids and fire safety, and gaseous fuels. From these research areas three mini-facilities have sprung: the Multi-user Droplet Combustion Apparatus (MDCA) for droplet research, Flow Enclosure for Novel Investigations in Combustion of Solids (FEANICS) for solids and fire safety, and the Multi-user Gaseous Fuels Apparatus (MGFA) for gaseous fuels. These mini-facilities will develop common Chamber Insert Assemblies (CIA) and diagnostics for the respective investigators complementing the capability provided by CIR. Presently there are four investigators for MDCA, six for FEANICS, and four for MGFA. The goal of these multi-user facilities is to drive the cost per PI down after the initial development investment is made. Each of these mini-facilities will become a fixture of future Combustion Science NASA Research Announcements (NRAs), enabling investigators to propose against an existing capability. Additionally, an investigation is provided the opportunity to enhance the existing capability to bridge the gap between the capability and their specific science requirements. This multi-user development approach will enable the Combustion Science Program to drive cost per investigation down while drastically reducing the time

Combustion

CERN Document Server

Glassman, Irvin

2008-01-01

Combustion Engineering, a topic generally taught at the upper undergraduate and graduate level in most mechanical engineering programs, and many chemical engineering programs, is the study of rapid energy and mass transfer usually through the common physical phenomena of flame oxidation. It covers the physics and chemistry of this process and the engineering applications-from the generation of power such as the internal combustion automobile engine to the gas turbine engine. Renewed concerns about energy efficiency and fuel costs, along with continued concerns over toxic and particulate emissions have kept the interest in this vital area of engineering high and brought about new developments in both fundamental knowledge of flame and combustion physics as well as new technologies for flame and fuel control. *New chapter on new combustion concepts and technologies, including discussion on nanotechnology as related to combustion, as well as microgravity combustion, microcombustion, and catalytic combustion-all ...

Internal combustion engine

Science.gov (United States)

Baker, Quentin A.; Mecredy, Henry E.; O'Neal, Glenn B.

1991-01-01

An improved engine is provided that more efficiently consumes difficult fuels such as coal slurries or powdered coal. The engine includes a precombustion chamber having a portion thereof formed by an ignition plug. The precombustion chamber is arranged so that when the piston is proximate the head, the precombustion chamber is sealed from the main cylinder or the main combustion chamber and when the piston is remote from the head, the precombustion chamber and main combustion chamber are in communication. The time for burning of fuel in the precombustion chamber can be regulated by the distance required to move the piston from the top dead center position to the position wherein the precombustion chamber and main combustion chamber are in communication.

Unraveling advanced compression ignition combustion using optical diagnostics

OpenAIRE

Zegers, R.P.C.

2012-01-01

Despite the expected upsurge of hybrid and electric cars in the coming decades, internal combustion will remain the main power supply for (long-distance) transport. Buses, trucks, ships and airplanes will still rely on combustion engines. Nevertheless, emission legislation is becoming more stringent and the oil price continues to rise. Consequently, there still exists a serious interest in new developments that may improve combustion efficiency and fuel flexibility, and reduce emissions; both...

Combustion and smoke formation following exposure of actinide metals to explosions

International Nuclear Information System (INIS)

Luna, R.E.; Church, H.W.; Elrick, R.M.; Parker, D.R.; Nelson, L.S.

1976-01-01

Results from the plutonium aerosol generation experiment (PAGE) program studies indicate that: (1) Significant quantities of metal-bearing aerosols are likely to be formed in an accidental high explosive detonation of a nuclear weapon. Although the explosive charge-to-metal ratio has been reduced in modern weapons, considerable inhalation hazard is still expected due to increased shrapnel formation and streamer combustion. (2) Close-in shrapnel particle sizes and velocities can be estimated by impact sampling techniques. (3) Uranium droplets are a very accurate simulant of plutonium droplets from the standpoint of combustion-related phenomena but do not seem to simulate either the total quantity of aerosol formed from plutonium droplets or its time-dependent generation pattern very well. This is due primarily to the large effect of the explosion of the burning uranium droplets on total aerosol formation which is not observed in the case of plutonium, even though more aerosol is produced per unit time during the actual combustion itself. (4) The formation of chain-like plutonium aerosols from the droplets produced during streamer combustion is expected to produce an unusually active material from the standpoint of inhalation into the lung and ultimate translocation in the body. 16 figures

Combustion

CERN Document Server

Glassman, Irvin

1997-01-01

This Third Edition of Glassman's classic text clearly defines the role of chemistry, physics, and fluid mechanics as applied to the complex topic of combustion. Glassman's insightful introductory text emphasizes underlying physical and chemical principles, and encompasses engine technology, fire safety, materials synthesis, detonation phenomena, hydrocarbon fuel oxidation mechanisms, and environmental considerations. Combustion has been rewritten to integrate the text, figures, and appendixes, detailing available combustion codes, making it not only an excellent introductory text but also an important reference source for professionals in the field. Key Features * Explains complex combustion phenomena with physical insight rather than extensive mathematics * Clarifies postulates in the text using extensive computational results in figures * Lists modern combustion programs indicating usage and availability * Relates combustion concepts to practical applications.

Development of reduced kinetic schemes for the description of pollutants formation in combustion; Mise au point de schemas cinetiques reduits pour decrire la formation des polluants dans la combustion

Energy Technology Data Exchange (ETDEWEB)

Ferrendier, M.

1998-12-17

The typical dimensions of details chemical-kinetic mechanisms proposed to describe combustion systems are too large for multi-dimensional computations applications. The objective of reduction methods is to construct low-dimensional schemes that can be incorporated in industrial codes. We consider here a new class of methods based on a mathematical analysis of the detailed chemical-kinetic mechanisms, and the identification of a low-dimensional manifold that describes the slow dynamics of the chemical system. The mathematical reduction methods considered in this work are the Intrinsic Low Dimensional Manifold (ILDM) method proposed by Maas and Pope (1992), and the Singular Perturbation (PS) method proposed by Duchene and Rouchon (1996). The domain of validity of the ILDM or PS reduced schemes is limited to a high temperature domain T {>=} T{sub c}. This result suggests that ignition is out of the domain of application of reduced mechanisms. In the case of a CO/H{sub 2}/N{sub 2}-air combustion system, and using a two-dimensional slow manifold, we find T{sub c} {approx} 750 K. We also find that for that particular system, 2 progress variables are sufficient for an accurate description of the structure and the velocity of a laminar premixed flame. In the case of a CH{sub 4}-air combustion system, and using a two-dimensional slow manifold, we find T{sub c}{approx}1500 K. We also find that 2 progress variables are insufficient for an accurate description of the structure and the velocity of a laminar premixed flame. The study of the different NO formation mechanisms show that the thermal NO mechanism (the Zeldovich mechanism) is dominant for premixed configurations with lean or stoichiometric conditions ({phi}){>=}1.2), and for non-premixed configurations at high temperatures and high pressures (T{sub air}{>=}1000 K, P {>=} 10 bars). Under these conditions, the MPKIVA sub model used to describe NO formation in the IFP version of the KIVA code performs reasonably well. An

Pulsed atmospheric fluidized bed combustion

Energy Technology Data Exchange (ETDEWEB)

1989-11-01

In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

Possibility of Coal Combustion Product Conditioning

Science.gov (United States)

Błaszczyński, Tomasz Z.; Król, Maciej R.

2018-03-01

This paper is focused on properties of materials known as green binders. They can be used to produce aluminium-siliceous concrete and binders known also as geopolymers. Comparing new ecological binders to ordinary cements we can see huge possibility of reducing amount of main greenhouse gas which is emitted to atmosphere by 3 to even 10 times depending of substrate type used to new green material production. Main ecological source of new materials obtaining possibility is to use already available products which are created in coal combustion and steel smelting process. Most of them are already used in many branches of industry. They are mostly civil engineering, chemistry or agriculture. Conducted research was based on less popular in civil engineering fly ash based on lignite combustion. Materials were examine in order to verify possibility of obtaining hardened mortars based of different factors connected with process of geopolymerization, which are temperature, amount of reaction reagent and time of heat treatment. After systematizing the matrices for the basic parameters affecting the strength of the hardened mortars, the influence of the fly ash treatment for increasing the strength was tested.

COMBUSTION OF BIOMASS AND CHARCOAL MADE FROM BABASSU NUTSHELL

Directory of Open Access Journals (Sweden)

Thiago de Paula Protásio

2017-03-01

Full Text Available In recent years, studies have examined the use of lignocellulosic wastes for energy generation. However, there is a lack of information on the combustibility of the residual biomass, especially the bark and charcoal of babassu nut. In this study, thermogravimetric analysis (TGA, differential thermal analysis (DTA and differential scanning calorimetry (DSC were used to achieve the following objectives: to evaluate the combustion of the residual biomass from the babassu nut; to evaluate the combustion of charcoal produced from this biomass, considering different final carbonization temperatures; and to determine the effect of the final carbonization temperature on the thermal stability of charcoal and on its performance in combustion. Thermal analyses were performed in synthetic air. In order to evaluate the characteristics of charcoal combustion and fresh biomass, the ignition temperature (Ti, the burnout temperature (Tf, characteristic combustion index (S, ignition index (Di, time corresponding to the maximum combustion rate (tp, and ignition time (tig were considered. The combustion of the babassu nutshell occurred in three phases and it was observed that this lignocellulosic material is suitable for the direct generation of heat. The increase in the final carbonization temperature caused an increase in the ignition temperature, as well as in the burnout temperature, the ignition time and the time corresponding to the maximum combustion rate. The results indicate that the increase in the carbonization temperature causes a decrease in combustion reactivity and, consequently, the charcoals produced at lower temperatures are easier to ignite and exhibit better performance in ignition.

Fuel properties to enable lifted-flame combustion

Energy Technology Data Exchange (ETDEWEB)

Kurtz, Eric [Ford Motor Company, Dearborn, MI (United States)

2015-03-15

The Fuel Properties to Enable Lifted-Flame Combustion project responded directly to solicitation DE-FOA-0000239 AOI 1A, Fuels and Lubricants for Advanced Combustion Regimes. This subtopic was intended to encompass clean and highly-efficient, liquid-fueled combustion engines to achieve extremely low engine-out nitrogen oxides (NOx) and particulate matter (PM) as a target and similar efficiency as state-of-the-art direct injection diesel engines. The intent of this project was to identify how fuel properties can be used to achieve controllable Leaner Lifted Flame Combustion (LLFC) with low NOx and PM emissions. Specifically, this project was expected to identify and test key fuel properties to enable LLFC and their compatibility with current fuel systems and to enhance combustion models to capture the effect of fuel properties on advanced combustion. Successful demonstration of LLFC may reduce the need for after treatment devices, thereby reducing costs and improving thermal efficiency. The project team consisted of key technical personnel from Ford Motor Company (FMC), the University of Wisconsin-Madison (UW), Sandia National Laboratories (SNL) and Lawrence Livermore National Laboratories (LLNL). Each partner had key roles in achieving project objectives. FMC investigated fuel properties relating to LLFC and sooting tendency. Together, FMC and UW developed and integrated 3D combustion models to capture fuel property combustion effects. FMC used these modeling results to develop a combustion system and define fuel properties to support a single-cylinder demonstration of fuel-enabled LLFC. UW investigated modeling the flame characteristics and emissions behavior of different fuels, including those with different cetane number and oxygen content. SNL led spray combustion experiments to quantify the effect of key fuel properties on combustion characteristics critical for LLFC, as well as single cylinder optical engine experiments to improve fundamental

An Assessment of Combustion Dynamics in a Low-Nox, Second-Generation Swirl-Venturi Lean Direct Injection Combustion Concept

Science.gov (United States)

Tacina, K. M.; Chang, C. T.; Lee, P.; Mongia, H.; Podboy, D. P.; Dam, B.

2015-01-01

Dynamic pressure measurements were taken during flame-tube emissions testing of three second-generation swirl-venturi lean direct injection (SV-LDI) combustor configurations. These measurements show that combustion dynamics were typically small. However, a small number of points showed high combustion dynamics, with peak-to-peak dynamic pressure fluctuations above 0.5 psi. High combustion dynamics occurred at low inlet temperatures in all three SV-LDI configurations, so combustion dynamics were explored further at low temperature conditions. A point with greater than 1.5 psi peak-to-peak dynamic pressure fluctuations was identified at an inlet temperature of 450!F, a pressure of 100 psia, an air pressure drop of 3%, and an overall equivalence ratio of 0.35. This is an off design condition: the temperature and pressure are typical of 7% power conditions, but the equivalence ratio is high. At this condition, the combustion dynamics depended strongly on the fuel staging. Combustion dynamics could be reduced significantly without changing the overall equivalence ratio by shifting the fuel distribution between stages. Shifting the fuel distribution also decreased NOx emissions.

Effects of stepwise gas combustion on NOx generation

International Nuclear Information System (INIS)

Woperane Seredi, A.; Szepesi, E.

1999-01-01

To decrease NO x emission from gas boilers, the combustion process of gas has been modified from continuous combustion to step-wise combustion. In this process the combustion temperature, the temperature peaks in the flame, the residence time of combustion products in the high-temperature zone and the oxygen partial pressure are changed advantageously. Experiments were performed using multistage burners, and the NO x emission was recorded. It was found that the air factor of the primary combustion space has a determining effect on the NO x reduction. (R.P.)

Periodic equivalence ratio modulation method and apparatus for controlling combustion instability

Science.gov (United States)

Richards, George A.; Janus, Michael C.; Griffith, Richard A.

2000-01-01

The periodic equivalence ratio modulation (PERM) method and apparatus significantly reduces and/or eliminates unstable conditions within a combustion chamber. The method involves modulating the equivalence ratio for the combustion device, such that the combustion device periodically operates outside of an identified unstable oscillation region. The equivalence ratio is modulated between preselected reference points, according to the shape of the oscillation region and operating parameters of the system. Preferably, the equivalence ratio is modulated from a first stable condition to a second stable condition, and, alternatively, the equivalence ratio is modulated from a stable condition to an unstable condition. The method is further applicable to multi-nozzle combustor designs, whereby individual nozzles are alternately modulated from stable to unstable conditions. Periodic equivalence ratio modulation (PERM) is accomplished by active control involving periodic, low frequency fuel modulation, whereby low frequency fuel pulses are injected into the main fuel delivery. Importantly, the fuel pulses are injected at a rate so as not to affect the desired time-average equivalence ratio for the combustion device.

Gasdynamic modeling and parametric study of mesoscale internal combustion swing engine/generator systems

Science.gov (United States)

Gu, Yongxian

The demand of portable power generation systems for both domestic and military applications has driven the advances of mesoscale internal combustion engine systems. This dissertation was devoted to the gasdynamic modeling and parametric study of the mesoscale internal combustion swing engine/generator systems. First, the system-level thermodynamic modeling for the swing engine/generator systems has been developed. The system performance as well as the potentials of both two- and four-stroke swing engine systems has been investigated based on this model. Then through parameterc studies, the parameters that have significant impacts on the system performance have been identified, among which, the burn time and spark advance time are the critical factors related to combustion process. It is found that the shorter burn time leads to higher system efficiency and power output and the optimal spark advance time is about half of the burn time. Secondly, the turbulent combustion modeling based on levelset method (G-equation) has been implemented into the commercial software FLUENT. Thereafter, the turbulent flame propagation in a generic mesoscale combustion chamber and realistic swing engine chambers has been studied. It is found that, in mesoscale combustion engines, the burn time is dominated by the mean turbulent kinetic energy in the chamber. It is also shown that in a generic mesoscale combustion chamber, the burn time depends on the longest distance between the initial ignition kernel to its walls and by changing the ignition and injection locations, the burn time can be reduced by a factor of two. Furthermore, the studies of turbulent flame propagation in real swing engine chambers show that the combustion can be enhanced through in-chamber turbulence augmentation and with higher engine frequency, the burn time is shorter, which indicates that the in-chamber turbulence can be induced by the motion of moving components as well as the intake gas jet flow. The burn time

Combustion engineering

CERN Document Server

Ragland, Kenneth W

2011-01-01

Introduction to Combustion Engineering The Nature of Combustion Combustion Emissions Global Climate Change Sustainability World Energy Production Structure of the Book   Section I: Basic Concepts Fuels Gaseous Fuels Liquid Fuels Solid Fuels Problems Thermodynamics of Combustion Review of First Law Concepts Properties of Mixtures Combustion StoichiometryChemical EnergyChemical EquilibriumAdiabatic Flame TemperatureChemical Kinetics of CombustionElementary ReactionsChain ReactionsGlobal ReactionsNitric Oxide KineticsReactions at a Solid SurfaceProblemsReferences  Section II: Combustion of Gaseous and Vaporized FuelsFlamesLaminar Premixed FlamesLaminar Flame TheoryTurbulent Premixed FlamesExplosion LimitsDiffusion FlamesGas-Fired Furnaces and BoilersEnergy Balance and EfficiencyFuel SubstitutionResidential Gas BurnersIndustrial Gas BurnersUtility Gas BurnersLow Swirl Gas BurnersPremixed-Charge Engine CombustionIntroduction to the Spark Ignition EngineEngine EfficiencyOne-Zone Model of Combustion in a Piston-...

Numerical analysis on the combustion and emission characteristics of forced swirl combustion system for DI diesel engines

International Nuclear Information System (INIS)

Su, LiWang; Li, XiangRong; Zhang, Zheng; Liu, FuShui

2014-01-01

Highlights: • A new combustion system named FSCS for DI diesel engines was proposed. • Fuel/air mixture formation was improved for the application of FSCS. • The FSCS showed a good performance on emission characteristics. - Abstract: To optimize the fuel/air mixture formation and improve the environmental effect of direct injection (DI) diesel engines, a new forced swirl combustion system (FSCS) was proposed concerned on unique design of the geometric shape of the combustion chamber. Numerical simulation was conducted to verify the combustion and emission characteristics of the engines with FSCS. The fuel/air diffusion, in-cylinder velocity distribution, turbulent kinetic energy and in-cylinder temperature distribution were analyzed and the results shown that the FSCS can increase the area of fuel/air diffusion and improve the combustion. The diesel engine with FSCS also shown excellent performance on emission. At full load condition, the soot emission was significantly reduced for the improved fuel/air mixture formation. There are slightly difference for the soot and NO emission between the FSCS and the traditional omega combustion system at lower load for the short penetration of the fuel spray

On hydrogen addition effects in turbulent combustion using the Flamelet Generated Manifold technique

NARCIS (Netherlands)

Fancello, A.; Bastiaans, R.J.M.; de Goey, L.P.H.

2014-01-01

The idea of reducing emissions and pollution in turbo-machinery technology is growing significantly in the last decades. In order to reach these standards and to guarantee, at the same time, efficient combustion systems, new configurations for burners are required. Classical approaches such as

A method for generating reduced-order combustion mechanisms that satisfy the differential entropy inequality

Science.gov (United States)

Ream, Allen E.; Slattery, John C.; Cizmas, Paul G. A.

2018-04-01

This paper presents a new method for determining the Arrhenius parameters of a reduced chemical mechanism such that it satisfies the second law of thermodynamics. The strategy is to approximate the progress of each reaction in the reduced mechanism from the species production rates of a detailed mechanism by using a linear least squares method. A series of non-linear least squares curve fittings are then carried out to find the optimal Arrhenius parameters for each reaction. At this step, the molar rates of production are written such that they comply with a theorem that provides the sufficient conditions for satisfying the second law of thermodynamics. This methodology was used to modify the Arrhenius parameters for the Westbrook and Dryer two-step mechanism and the Peters and Williams three-step mechanism for methane combustion. Both optimized mechanisms showed good agreement with the detailed mechanism for species mole fractions and production rates of most major species. Both optimized mechanisms showed significant improvement over previous mechanisms in minor species production rate prediction. Both optimized mechanisms produced no violations of the second law of thermodynamics.

The rheodynamics and combustion of coal-water mixtures

Energy Technology Data Exchange (ETDEWEB)

Burdukov, A.P.; Popov, V.I.; Tomilov, V.G.; Fedosenko, V.D. [Russian Academy of Science, Novosibirsk (Russian Federation). Inst. of Thermophysics (Siberian Branch, Russian Academy of Science)

2002-05-01

Investigation methods for characteristics of movement along the tubes, combustion dynamics and gasification of separate drops were developed for the coal-water mixtures (CWM). The following parameters were determined on the basis of laser heating: thermometric, pyrometric and concentration dynamics of single-drop combustion, complete combustion times, duration of temperature phases of combustion, as well as the moment and temperature of ignition. Information on the combustion mass velocity and gasification products was also obtained using laser heating. 6 refs., 13 figs., 1 tab.

Combustion characteristics of the mustard methyl esters

International Nuclear Information System (INIS)

Bannikov, M.G.; Vasilev, I.P.

2011-01-01

Mustard Methyl Esters (further bio diesel) and regular diesel fuel were tested in direct injection diesel engine. Analysis of experimental data was supported by an analysis of fuel injection and combustion characteristics. Engine fuelled with bio diesel had increased brake specific fuel consumption, reduced nitrogen oxides emission and smoke opacity, moderate increase in carbon monoxide emission with essentially unchanged unburned hydrocarbons emission. Increase in fuel consumption was attributed to lesser heating value of bio diesel and partially to decreased fuel conversion efficiency. Analysis of combustion characteristics revealed earlier start of injection and shorter ignition delay period of bio diesel. Resulting decrease in maximum rate of heat release and cylinder pressure was the most probable reason for reduced emission of nitrogen oxides. Analysis of combustion characteristics also showed that cetane index determined by ASTM Method D976 is not a proper measure of ignition quality of bio diesel. Conclusion was made on applicability of mustard oil as a source for commercial production of bio diesel in Pakistan. Potentialities of on improving combustion and emissions characteristics of diesel engine by reformulating bio diesel were discussed. (author)

Combustion

CERN Document Server

Glassman, Irvin

1987-01-01

Combustion, Second Edition focuses on the underlying principles of combustion and covers topics ranging from chemical thermodynamics and flame temperatures to chemical kinetics, detonation, ignition, and oxidation characteristics of fuels. Diffusion flames, flame phenomena in premixed combustible gases, and combustion of nonvolatile fuels are also discussed. This book consists of nine chapters and begins by introducing the reader to heats of reaction and formation, free energy and the equilibrium constants, and flame temperature calculations. The next chapter explores the rates of reactio

Effect of Metal Additives on the Combustion Characteristics of High-Energy Materials

OpenAIRE

Korotkikh, Aleksandr Gennadievich; Glotov, Oleg; Sorokin, Ivan

2016-01-01

Thermodynamic calculation of combustion parameters and equilibrium composition of HEMs combustion products showed, that at the increase of aluminum powder dispersity the specific impulse and combustion temperature of solid propellants are reduced due to the decrease of the mass fraction of active aluminum in particles. Partial or complete replacement of aluminum by metal powder (B, Mg, AlB[2], Al\\Mg alloy, Fe, Ti and Zr) in HEMs composition leads to the reduce of the specific impulse and comb...

Effect of combustion characteristics on wall radiative heat flux in a 100 MWe oxy-coal combustion plant

Energy Technology Data Exchange (ETDEWEB)

Park, S.; Ryu, C. [Sungkyunkwan Univ., Suwon (Korea, Republic of). School of Mechanical Engineering; Chae, T.Y. [Sungkyunkwan Univ., Suwon (Korea, Republic of). School of Mechanical Engineering; Korea Institute of Industrial Technology, Cheonan (Korea, Republic of). Energy System R and D Group; Yang, W. [Korea Institute of Industrial Technology, Cheonan (Korea, Republic of). Energy System R and D Group; Kim, Y.; Lee, S.; Seo, S. [Korea Electric Power Research Institute (KEPRI), Daejeon (Korea, Republic of). Power Generation Lab.

2013-07-01

Oxy-coal combustion exhibits different reaction, flow and heat transfer characteristics from air-coal combustion due to different properties of oxidizer and flue gas composition. This study investigated the wall radiative heat flux (WRHF) of air- and oxy-coal combustion in a simple hexahedral furnace and in a 100 MWe single-wall-fired boiler using computational modeling. The hexahedral furnace had similar operation conditions with the boiler, but the coal combustion was ignored by prescribing the gas properties after complete combustion at the inlet. The concentrations of O{sub 2} in the oxidizers ranging between 26 and 30% and different flue gas recirculation (FGR) methods were considered in the furnace. In the hexahedral furnace, the oxy-coal case with 28% of O{sub 2} and wet FGR had a similar value of T{sub af} with the air-coal combustion case, but its WRHF was 12% higher. The mixed FGR case with about 27% O{sub 2} in the oxidizer exhibited the WRHF similar to the air-coal case. During the actual combustion in the 100 MWe boiler using mixed FGR, the reduced volumetric flow rates in the oxy-coal cases lowered the swirl strength of the burners. This stretched the flames and moved the high temperature region farther to the downstream. Due to this reason, the case with 30% O{sub 2} in the oxidizers achieved a WRHF close to that of air-coal combustion, although its adiabatic flame temperature (T{sub af}) and WHRF predicted in the simplified hexahedral furnace was 103 K and 10% higher, respectively. Therefore, the combustion characteristics and temperature distribution significantly influences the WRHF, which should be assessed to determine the ideal operating conditions of oxy- coal combustion. The choice of the weighted sum of gray gases model (WSGGM) was not critical in the large coal-fired boiler.

Comparative sinterability of combustion synthesized and commercial titanium carbides

International Nuclear Information System (INIS)

Manley, B.W.

1984-11-01

The influence of various parameters on the sinterability of combustion synthesized titanium carbide was investigaged. Titanium carbide powders, prepared by the combustion synthesis process, were sintered in the temperature range 1150 to 1600 0 C. Incomplete combustion and high oxygen contents were found to be the cause of reduced shrinkage during sintering of the combustion syntheized powders when compared to the shrinkage of commercial TiC. Free carbon was shown to inhibit shrinkage. The activation energy for sintering was found to depend on stoichiometry (C/Ti). With decreasing C/Ti, the rate of sintering increased. 29 references, 16 figures, 13 tables

Combustion control and sensors: a review

International Nuclear Information System (INIS)

Docquier, N.; Candel, S.

2002-01-01

There is an increased interest in the application of control to combustion. The objective is to optimize combustor operation, monitor the process and alleviate instabilities and their severe consequences. One wishes to improve the system performance, for example by reducing the levels of pollutant emissions or by smoothing the pattern factor at the combustor exhaust. In other cases, the aim is to extend the stability domain by reducing the level of oscillation induced by coupling between resonance modes and combustion. As combustion systems have to meet increasingly more demanding air pollution standards, their design and operation becomes more complex. The trend towards reduced NO x levels has led to new developments in different fields. Automotive engines and gas turbine combustors are considered in this article. In the first case, complex exhaust aftertreatment is being applied and dedicated engine control systems are required to ensure and maintain high pollutant conversion efficiency. For gas turbines, premixed combustors, which operate at lower local temperatures than conventional systems have been designed. In both cases, monitoring and control of the operating point of the process have to be achieved with great precision to obtain the full benefits of the NO x reduction scheme. For premixed combustors operating near the lean stability limit, the flame is more susceptible to blowout, oscillation or flashback. Research is now carried out to reduce these dynamical problems with passive and active control methods. In addition to a broad range of fundamental problems raised by Active Combustion Control (ACC) and Operating Point Control (OPC), there are important technological issues. This paper contains a review of some facets of combustion control and focuses on the sensors that take or could take part to combustion control solutions. The current status of ACC and OPC is presented together with the associated control concepts. The state of the art in sensors is

The changing nicotine products landscape: time to outlaw sales of combustible tobacco products?

Science.gov (United States)

Hefler, Marita

2018-01-01

Combustible tobacco products are unique both for the extraordinary harm they cause, and the fact that more than 50 years after these harms became known, they continue to be widely and legally available globally. However, the rapid evolution of the nicotine product marketplace in recent years warrants a re-assessment of the viability of phasing out commercial sales of combustible tobacco, and presents an opportunity to end the exceptionalism of combustible tobacco being permitted for sale. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

Gasoline Engine HCCI Combustion - Extending the high load limit

Energy Technology Data Exchange (ETDEWEB)

Dahl, Daniel

2012-07-01

There is an increasing global focus on reducing emissions of greenhouse gases. For the automotive industry this means reducing CO2 emissions of the vehicles manufactured, which is synonymous with reducing their fuel consumption or adapting them for using renewable fuels. This thesis is based on a project aimed at improving the efficiency of gasoline engines in the lower load/speed region. The focus was mainly on a combustion strategy called homogeneous charge compression ignition (HCCI), but also on homogeneous lean and stratified lean spark-ignited combustion. In contrast to traditional stoichiometric spark-ignited combustion, HCCI can operate with diluted mixtures, which leads to better cycle efficiency, smaller pumping losses and smaller heat losses. However, at relatively high loads, HCCI combustion becomes excessively rapid, generating in-cylinder pressure oscillations (ringing), which are perceived as noise by the human ear. The main objective of the project was to identify ways to avoid this ringing behaviour in order to increase the upper load limit of HCCI. This is vital to avoid the need for mode switches to spark-ignited combustion at higher loads and to operate the engine as much as possible in the more effective HCCI mode. The strategy for reducing ringing investigated most extensively in the project was charge stratification, achieved by injecting part of the fuel late in the compression stroke. Available literature on effects of this strategy gave conflicting indications, both positive and negative effects have been reported, depending on the type of fuel and engine used. It was soon found that the strategy is effective for reducing ringing, but with resulting increases of NOX emissions. Further, in order for the strategy to be effective, global air/fuel ratios must not be much leaner than stoichiometric. The increases in NOX emissions were countered by shifting the ratio towards stoichiometric using exhaust gas recirculation (EGR), allowing a three

Combustion of drops of Mexican fuel oils with high asphaltenes content; Combustion de gotas de combustoleos mexicanos con alto contenido de asfaltenos

Energy Technology Data Exchange (ETDEWEB)

Garcia Rodriguez, Jose Francisco [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1998-09-01

In this work the combustion of fuel drops with a content of 18% of asphaltenes has been studied . The results obtained for this fuel were compared with the ones obtained for another with a content of 12% asphaltenes. The drops were suspended in a platinum filament and burned in an spherical radiant furnace. The drop size varied between 600 and 800 microns. The fuel drops with 12% asphaltenes showed shorter combustion times, a smaller diameter increment of the smaller diameter during the combustion stages and also a shorter burning time of the carbonaceous residue than the fuel drops with a content of 18% asphaltenes. [Espanol] En el presente trabajo se ha estudiado la combustion de gotas de combustible con 18% de contenido de asfaltenos. Los resultados obtenidos para este combustible se compararon con los obtenidos para otro con 12% de contenido de asfaltenos. Las gotas fueron suspendidas en un filamento de platino y quemadas en un horno radiante esferico. El tamano de las gotas vario entre 600 y 800 micras. Las gotas de combustible con 12% de asfaltenos mostraron tiempos de combustion mas cortos, un incremento del diametro menor durante las etapas de combustion y un tiempo de quemado del residuo carbonoso tambien mas corto que las gotas del combustible con 18% de contenido de asfaltenos.

Accelerated Electromechanical Modeling of a Distributed Internal Combustion Engine Generator Unit

Directory of Open Access Journals (Sweden)

Serhiy V. Bozhko

2012-07-01

Full Text Available Distributed generation with a combustion engine prime mover is still widely used to supply electric power in a variety of applications. These applications range from backup power supply systems and combined wind-diesel generation to providing power in places where grid connection is either technically impractical or financially uneconomic. Modelling of such systems as a whole is extremely difficult due to the long-time load profiles needed and the computational difficulty of including small time-constant electrical dynamics with large time-constant mechanical dynamics. This paper presents the development of accelerated, reduced-order models of a distributed internal combustions engine generator unit. Overall these models are shown to achieve a massive improvement in the computational time required for long-time simulations while also achieving an extremely high level of dynamic accuracy. It is demonstrated how these models are derived, used and verified against benchmark models created using established techniques. Throughout the paper the modelling set as a whole, including multi level detail, is presented, detailed and finally summarised into a crucial tool for general system investigation and multiple target optimisation.

Control issues in oxy-fuel combustion

Energy Technology Data Exchange (ETDEWEB)

Snarheim, Dagfinn

2009-08-15

Combustion of fossil fuels is the major energy source in todays society. While the use of fossil fuels is a necessity for our society to function, there has been an increasing concern on the emissions of CO{sub 2} resulting from human activities. Emissions of CO{sub 2} are considered to be the main cause for the global warming and climate changes we have experienced in recent years. To fight the climate changes, the emissions of CO{sub 2} must be reduced in a timely fashion. Strategies to achieve this include switching to less carbon intensive fuels, renewable energy sources, nuclear energy and combustion with CO{sub 2} capture. The use of oxy-fuel combustion is among the alternative post- and pre combustion capture concepts, a strategy to achieve power production from fossil fuels with CO{sub 2} capture. In an oxy-fuel process, the fuel is burned in a mixture of oxygen and CO{sub 2} (or steam), leaving the exhaust consisting mainly of CO{sub 2} and steam. The steam can be removed by use of a condenser, leaving (almost) pure CO{sub 2} ready to be captured. The downside to CO{sub 2} capture is that it is expensive, both in capital cost of extra equipment, and in operation as it costs energy to capture the CO{sub 2}. Thus it is important to maximize the efficiency in such plants. One attractive concept to achieve CO{sub 2} capture by use of oxy-fuel, is a semi-closed oxy-fuel gas turbine cycle. The dynamics of such a plant are highly integrated, involving energy and mass recycle, and optimizing efficiency might lead to operational (control) challenges. In these thesis we investigate how such a power cycle should be controlled. By looking at control at such an early stage in the design phase, it is possible to find control solutions otherwise not feasible, that leads to better overall performance. Optimization is used on a nonlinear model based on first principles, to compare different control structures. Then, closed loop simulations using MPC, are used to validate

Consumption of Combustible and Smokeless Tobacco - United States, 2000-2015.

Science.gov (United States)

Wang, Teresa W; Kenemer, Brandon; Tynan, Michael A; Singh, Tushar; King, Brian

2016-12-09

Combustible and smokeless tobacco use causes adverse health outcomes, including cardiovascular disease and multiple types of cancer (1,2). Standard approaches for measuring tobacco use include self-reported surveys of use and consumption estimates based on tobacco excise tax data (3,4). To provide the most recently available tobacco consumption estimates in the United States, CDC used federal excise tax data to estimate total and per capita consumption during 2000-2015 for combustible tobacco (cigarettes, roll-your-own tobacco, pipe tobacco, small cigars, and large cigars) and smokeless tobacco (chewing tobacco and dry snuff). During this period, total combustible tobacco consumption decreased 33.5%, or 43.7% per capita. Although total cigarette consumption decreased 38.7%, cigarettes remained the most commonly used combustible tobacco product. Total noncigarette combustible tobacco (i.e., cigars, roll-your-own, and pipe tobacco) consumption increased 117.1%, or 83.8% per capita during 2000-2015. Total consumption of smokeless tobacco increased 23.1%, or 4.2% per capita. Notably, total cigarette consumption was 267.0 billion cigarettes in 2015 compared with 262.7 billion in 2014. These findings indicate that although cigarette smoking declined overall during 2000-2015, and each year from 2000 to 2014, the number of cigarettes consumed in 2015 was higher than in 2014, and the first time annual cigarette consumption was higher than the previous year since 1973. Moreover, the consumption of other combustible and smokeless tobacco products remains substantial. Implementation of proven tobacco prevention interventions (5) is warranted to further reduce tobacco use in the United States.

Technology for emission control in internal combustion engines; Kakushu nainen kikan ni okeru hai gas joka gijutsu

Energy Technology Data Exchange (ETDEWEB)

Shioji, M. [Kyoto University, Kyoto (Japan)

1998-09-01

Described herein are emission control technology and exhaust gas cleaning measures for internal combustion engines. Gas turbines burn relatively high-quality fuels, such as natural gas, kerosene, diesel oil and gas oil, where the major concerns are to reduce NOx and dust emissions. The NOx abatement techniques fall into two general categories; wet processes which inject water or steam, and dry processes which depend on improved combustion. Power generation and cogeneration which burn natural gas adopt lean, premixed combustion and two-stage combustion as the major approaches. Low-speed, large-size diesel engines, which realize very high thermal efficiency, discharge high concentrations of NOx. Delayed fuel injection timing is the most easy NOx abatement technique to meet the related regulations, but is accompanied by decreased fuel economy. Use of water-emulsified fuel, water layer injection and multi-port injection can reduce NOx emissions without decreasing fuel economy, depending on optimization methods adopted. Automobile gasoline engines are required to further clean exhaust gases by catalystic systems. 9 refs., 10 figs., 6 tabs.

Spectroscoping analysis of ignition in a spark ignition engine with jet-controlled combustion; Spektroskopische Untersuchung der Entflammung an einem Ottomotor mit strahlgefuehrtem Brennverfahren

Energy Technology Data Exchange (ETDEWEB)

Palaveev, S. [MOT Forschungs- und Entwicklungsgesellschaft fuer Motorentechnik, Optik und Thermodynamik GmbH, Karlsruhe (Germany); Buri, S.; Xander, B.; Spicher, U. [Karlsruhe Univ. (T.H.) (Germany). Inst. fuer Kolbenmaschinen

2007-07-01

The gasoline direct injection engine is one of the most promising strategies today to reduce the fuel consumption and CO{sub 2}-emissions of spark-ignition engines. The commercial launch of that combustion system was possible only through the development of new optical measurement techniques, which have been a major contribution for understanding the basics of the combustion in a stratified mode. In terms of space and time, compared to the homogeneous approach, the air-fuel-ratio for a stratified mode may vary significantly. This fluctuation affects in a critical way the process of ignition and combustion. The knowledge of the air-fuel-ratio in the spark plug area both at time of ignition and in during the combustion is therefore critical for the development of this combustion system and it components. This paper presents the spark-emission spectroscopy as a non invasive optical technique for measuring the air-fuel-ratio {lambda} in the spark gap at time of ignition. (orig.)

An investigation of partially premixed compression ignition combustion using gasoline and spark assistance

OpenAIRE

Benajes Calvo, Jesus Vicente; García Martínez, Antonio; Doménech Llopis, Vicente; Durret, Russell

2013-01-01

Nowadays the automotive scientific community and companies are focusing part of their efforts on the investigation of new combustion modes in Compression Ignition (Cl) engines, mainly based on the use of locally lean air fuel mixtures. This characteristic, combined with exhaust gas recirculation, provides low combustion temperatures that reduce pollutant formation. However these combustion concepts have some shortcomings, related to combustion phasing control and combustion stability under th...

Low emission turbulent technology for fuel combustion

International Nuclear Information System (INIS)

Finker, F. Z.; Kubyshkin, I. B.; Zakharov, B. Yu.; Akhmedov, D. B.; Sobchuk, Ch.

1997-01-01

The company 'POLITEKHENERGO' in co-operation and the Russian-Poland firm 'EnergoVIR' have performed investigations for modernization of the current existing boilers. A low emission turbulent technology has been used for the modernization of 10 industrial boilers. The reduction of NO x emissions is based on the following processes: 1) multistage combustion assured by two counter-deviated fluxes; 2) Some of the combustion facilities have an abrupt slope and a reduced air supply which leads to an intense separation of the fuel in the bottom part and a creation of a low-temperature combustion zone where the active restoration of the NO x takes part; 3) The influence of the top high-temperature zone on the NO x formation is small. Thus the 'sandwich' consisting of 'cold' and'hot' combustion layers provides a full rate combustion. This technique permits to: decrease of the NO x and CO x down to the European standard values;increase of the efficiency in 1-2%; obtain a stable coal combustion up to 97-98%; assure the large loading range (30 -100%); modernize and use the old boilers

Rapid computation of chemical equilibrium composition - An application to hydrocarbon combustion

Science.gov (United States)

Erickson, W. D.; Prabhu, R. K.

1986-01-01

A scheme for rapidly computing the chemical equilibrium composition of hydrocarbon combustion products is derived. A set of ten governing equations is reduced to a single equation that is solved by the Newton iteration method. Computation speeds are approximately 80 times faster than the often used free-energy minimization method. The general approach also has application to many other chemical systems.

Emission Modeling of an Interturbine Burner Based on Flameless Combustion

NARCIS (Netherlands)

Perpignan, A.A.V.; Talboom, M.G.; Levy, Yeshayahou; Gangoli Rao, A.

2018-01-01

Since its discovery, the flameless combustion (FC) regime has been a promising alternative to reduce pollutant emissions of gas turbine engines. This combustion mode is characterized by well-distributed reaction zones, which potentially decreases temperature gradients, acoustic oscillations, and

Predictive piston motion control in a free-piston internal combustion engine

Energy Technology Data Exchange (ETDEWEB)

Mikalsen, R.; Jones, E.; Roskilly, A.P. [Sir Joseph Swan Institute for Energy Research, Newcastle University, Newcastle upon Tyne, NE1 7RU England (United Kingdom)

2010-05-15

A piston motion controller for a free-piston internal combustion engine is presented. To improve dynamic performance in the control of the piston motion and engine compression ratio, the controller response is determined from a prediction of engine top dead centre error rather than the measured value from the previous cycle. The proposed control approach showed superior performance compared with that of standard PI feedback control known from the literature due to a reduced control action time delay. The manipulation of fuel injection timing to reduce in-cylinder pressure peaks and cycle-to-cycle variations was also studied, indicating that with the piston motion estimation, the injection timing is a powerful control variable for this purpose. (author)

Real-time modelling of the diesel engine combustion process; Echtzeitfaehige Modellierung des dieselmotorischen Verbrennungsprozesses

Energy Technology Data Exchange (ETDEWEB)

Merz, B.

2008-07-01

The publication investigates single-zone models of diesel engine combustion which are capable, in addition to pre-injection and main injection, to represent post-injection processes on a physical basis. These must function in real time as they are used in ''hardware-in-the-loop'' test stands. Methods to adapt the models to other engine types are explained. Validation is made across the whole characteristic field on the basis of measured data provided by two serial engines. For assessing pollutant production, models are integrated that are capable of calculating NOx and soot formation. These, too, are calculated in real time using appropriate hardware systems. A runtime analysis compares the computing times of the models. (orig.)

Ethanol-fueled low temperature combustion: A pathway to clean and efficient diesel engine cycles

International Nuclear Information System (INIS)

Asad, Usman; Kumar, Raj; Zheng, Ming; Tjong, Jimi

2015-01-01

Highlights: • Concept of ethanol–diesel fueled Premixed Pilot Assisted Combustion (PPAC). • Ultra-low NOx and soot with diesel-like thermal efficiency across the load range. • Close to TDC pilot injection timing for direct combustion phasing control. • Minimum pilot quantity (15% of total energy input) for clean, stable operation. • Defined heat release profile distribution (HRPD) to optimize pilot-ethanol ratio. - Abstract: Low temperature combustion (LTC) in diesel engines offers the benefits of ultra-low NOx and smoke emissions but suffers from lowered energy efficiency due to the high reactivity and low volatility of diesel fuel. Ethanol from renewable biomass provides a viable alternate to the petroleum based transportation fuels. The high resistance to auto-ignition (low reactivity) and its high volatility make ethanol a suitable fuel for low temperature combustion (LTC) in compression-ignition engines. In this work, a Premixed Pilot Assisted Combustion (PPAC) strategy comprising of the port fuel injection of ethanol, ignited with a single diesel pilot injection near the top dead centre has been investigated on a single-cylinder high compression ratio diesel engine. The impact of the diesel pilot injection timing, ethanol to diesel quantity ratio and exhaust gas recirculation on the emissions and efficiency are studied at 10 bar IMEP. With the lessons learnt, successful ethanol–diesel PPAC has been demonstrated up to a load of 18 bar IMEP with ultra-low NOx and soot emissions across the full load range. The main challenge of PPAC is the reduced combustion efficiency especially at low loads; therefore, the authors have presented a combustion control strategy to allow high efficiency, clean combustion across the load range. This work entails to provide a detailed framework for the ethanol-fueled PPAC to be successfully implemented.

Internal and Surface Phenomena in Heterogenous Metal Combustion

Science.gov (United States)

Dreizin, Edward L.

1997-01-01

The phenomenon of gas dissolution in burning metals was observed in recent metal combustion studies, but it could not be adequately explained by the traditional metal combustion models. The research reported here addresses heterogeneous metal combustion with emphasis on the processes of oxygen penetration inside burning metal and its influence on the metal combustion rate, temperature history, and disruptive burning. The unique feature of this work is the combination of the microgravity environment with a novel micro-arc generator of monodispersed metal droplets, ensuring repeatable formation and ignition of uniform metal droplets with a controllable initial temperature and velocity. Burning droplet temperature is measured in real time with a three wavelength pyrometer. In addition, particles are rapidly quenched at different combustion times, cross-sectioned, and examined using SEM-based techniques to retrieve the internal composition history of burning metal particles. When the initial velocity of a spherical particle is nearly zero, the microgravity environment makes it possible to study the flame structure, the development of flame nonsymmetry, and correlation of the flame shape with the heterogeneous combustion processes.

Ultra-High Efficiency and Low-Emissions Combustion Technology for Manufacturing Industries

Energy Technology Data Exchange (ETDEWEB)

Atreya, Arvind

2013-04-15

The purpose of this research was to develop and test a transformational combustion technology for high temperature furnaces to reduce the energy intensity and carbon footprint of U.S. manufacturing industries such as steel, aluminum, glass, metal casting, and petroleum refining. A new technology based on internal and/or external Flue Gas Recirculation (FGR) along with significant enhancement in flame radiation was developed. It produces "Radiative Flameless Combustion (RFC)" and offers tremendous energy efficiency and pollutant reduction benefits over and above the now popular "flameless combustion." It will reduce the energy intensity (or fuel consumption per unit system output) by more than 50% and double the furnace productivity while significantly reducing pollutants and greenhouse gas emissions (10^3 times reduction in NOx and 10 times reduction in CO & hydrocarbons and 3 times reduction in CO2). Product quality improvements are also expected due to uniform radiation, as well as, reduction in scale/dross formation is expected because of non-oxidative atmosphere. RFC is inexpensive, easy to implement, and it was successfully tested in a laboratory-scale furnace at the University of Michigan during the course of this work. A first-ever theory with gas and particulate radiation was also developed. Numerical programs were also written to design an industrial-scale furnace. Nine papers were published (or are in the process of publication). We believe that this early stage research adequately proves the concept through laboratory experiments, modeling and computational models. All this work is presented in the published papers. Important conclusions of this work are: (1) It was proved through experimental measurements that RFC is not only feasible but a very beneficial technology. (2) Theoretical analysis of RFC was done in (a) spatially uniform strain field and (b) a planar momentum jet where the strain rate is neither prescribed nor uniform. Four important non

Combustible structural composites and methods of forming combustible structural composites

Science.gov (United States)

Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

2013-04-02

Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

The John Zink Hamworthy combustion handbook

CERN Document Server

Baukal, Charles E

2013-01-01

Despite the length of time it has been around, its importance, and vast amounts of research, combustion is still far from being completely understood. Issues regarding the environment, cost, and fuel consumption add further complexity, particularly in the process and power generation industries. Dedicated to advancing the art and science of industrial combustion, The John Zink Hamworthy Combustion Handbook, Second Edition: Volume 3 - Applications offers comprehensive, up-to-date coverage of equipment used in the process and power generation industries. Under the leadership of Charles E. Baukal

Chaotic combustion in spark ignition engines

International Nuclear Information System (INIS)

Wendeker, Miroslaw; Czarnigowski, Jacek; Litak, Grzegorz; Szabelski, Kazimierz

2003-01-01

We analyse the combustion process in a spark ignition engine using the experimental data of an internal pressure during the combustion process and show that the system can be driven to chaotic behaviour. Our conclusion is based on the observation of unperiodicity in the time series, suitable stroboscopic maps and a complex structure of a reconstructed strange attractor. This analysis can explain that in some circumstances the level of noise in spark ignition engines increases considerably due to nonlinear dynamics of a combustion process

Proceedings of IEA combustion 2009 : IEA 31. task leaders meeting on energy conservation and emissions reduction in combustion

International Nuclear Information System (INIS)

2009-01-01

The International Energy Agency (IEA) supports research and development in energy technology. This meeting provided a forum to discuss combustion processes, which is fundamental to achieving further improvements in fuel use efficiency, reducing the production of pollutants such as nitrogen oxides, and facilitating the transition to alternative fuels. The presentations demonstrated recent studies in improving the efficiency and fuel flexibility of automotive engines; improving the performance of industrial furnaces; emissions formation and control mechanisms; and fuel injection and fuel/air mixing. The conference also highlighted studies involving hydrogen combustion, alternative fuels, particulate diagnostics, fuel sprays, gas turbines, and advanced combustion processes such as homogeneous charge compression ignition (HCCI). The sessions were entitled: HCCI fuels; sprays; nanoparticle diagnostics; alternative fuels; hydrogen internal combustion engines; turbines; energy security; and collaborative task planning. All 45 presentations from the conference have been catalogued separately for inclusion in this database. refs., tabs., figs.

Combustion instability modeling and analysis

Energy Technology Data Exchange (ETDEWEB)

Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States); Sheppard, E.J. [Tuskeggee Univ., Tuskegee, AL (United States). Dept. of Aerospace Engineering

1995-12-31

It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors. The present study represents a coordinated effort between industry, government and academia to investigate gas turbine combustion dynamics. Specific study areas include development of advanced diagnostics, definition of controlling phenomena, advancement of analytical and numerical modeling capabilities, and assessment of the current status of our ability to apply these tools to practical gas turbine combustors. The present work involves four tasks which address, respectively, (1) the development of a fiber-optic probe for fuel-air ratio measurements, (2) the study of combustion instability using laser-based diagnostics in a high pressure, high temperature flow reactor, (3) the development of analytical and numerical modeling capabilities for describing combustion instability which will be validated against experimental data, and (4) the preparation of a literature survey and establishment of a data base on practical experience with combustion instability.

Aerosols from biomass combustion

Energy Technology Data Exchange (ETDEWEB)

Nussbaumer, T

2001-07-01

This report is the proceedings of a seminar on biomass combustion and aerosol production organised jointly by the International Energy Agency's (IEA) Task 32 on bio energy and the Swiss Federal Office of Energy (SFOE). This collection of 16 papers discusses the production of aerosols and fine particles by the burning of biomass and their effects. Expert knowledge on the environmental impact of aerosols, formation mechanisms, measurement technologies, methods of analysis and measures to be taken to reduce such emissions is presented. The seminar, visited by 50 participants from 11 countries, shows, according to the authors, that the reduction of aerosol emissions resulting from biomass combustion will remain a challenge for the future.

Aerosols from biomass combustion

Energy Technology Data Exchange (ETDEWEB)

Nussbaumer, T.

2001-07-01

This report is the proceedings of a seminar on biomass combustion and aerosol production organised jointly by the International Energy Agency's (IEA) Task 32 on bio energy and the Swiss Federal Office of Energy (SFOE). This collection of 16 papers discusses the production of aerosols and fine particles by the burning of biomass and their effects. Expert knowledge on the environmental impact of aerosols, formation mechanisms, measurement technologies, methods of analysis and measures to be taken to reduce such emissions is presented. The seminar, visited by 50 participants from 11 countries, shows, according to the authors, that the reduction of aerosol emissions resulting from biomass combustion will remain a challenge for the future.

Improvement of fuel combustion technologies

Energy Technology Data Exchange (ETDEWEB)

Tumanovskii, A.G.; Babii, V.I.; Enyakin, Y.P.; Kotler, V.R.; Ryabov, G.V.; Verbovetskii, E.K.; Nadyrov, I.I. [All-Russian Thermal Engineering Institute, Moscow (Russian Federation)

1996-07-01

The main problems encountered in the further development of fuel combustion technologies at thermal power stations in Russia are considered. Experience is generalized and results are presented on the efficiency with which nitrogen oxide emissions are reduced by means of technological methods when burning natural gas, fuel oil, and coal. The problems that arise in the introduction of new combustion technologies and in using more promising grades of coal are considered. The results studies are presented that show that low grade Russian coals can be burnt in circulating fluidized bed boilers. 14 refs., 5 figs., 4 tabs.

Dynamics of Water Absorption and Evaporation During Methanol Droplet Combustion in Microgravity

Science.gov (United States)

Hicks, Michael C.; Dietrich, Daniel L.; Nayagam, Vedha; Williams, Forman A.

2012-01-01

The combustion of methanol droplets is profoundly influenced by the absorption and evaporation of water, generated in the gas phase as a part of the combustion products. Initially there is a water-absorption period of combustion during which the latent heat of condensation of water vapor, released into the droplet, enhances its burning rate, whereas later there is a water-evaporation period, during which the water vapor reduces the flame temperature suffciently to extinguish the flame. Recent methanol droplet-combustion experiments in ambient environments diluted with carbon dioxide, conducted in the Combustion Integrated Rack on the International Space Station (ISS), as a part of the FLEX project, provided a method to delineate the water-absorption period from the water-evaporation period using video images of flame intensity. These were obtained using an ultra-violet camera that captures the OH* radical emission at 310 nm wavelength and a color camera that captures visible flame emission. These results are compared with results of ground-based tests in the Zero Gravity Facility at the NASA Glenn Research Center which employed smaller droplets in argon-diluted environments. A simplified theoretical model developed earlier correlates the transition time at which water absorption ends and evaporation starts. The model results are shown to agree reasonably well with experiment.

LES SOFTWARE FOR THE DESIGN OF LOW EMISSION COMBUSTION SYSTEMS FOR VISION 21 PLANTS

Energy Technology Data Exchange (ETDEWEB)

Clifford E. Smith; Steven M. Cannon; Virgil Adumitroaie; David L. Black; Karl V. Meredith

2005-01-01

In this project, an advanced computational software tool was developed for the design of low emission combustion systems required for Vision 21 clean energy plants. Vision 21 combustion systems, such as combustors for gas turbines, combustors for indirect fired cycles, furnaces and sequestrian-ready combustion systems, will require innovative low emission designs and low development costs if Vision 21 goals are to be realized. The simulation tool will greatly reduce the number of experimental tests; this is especially desirable for gas turbine combustor design since the cost of the high pressure testing is extremely costly. In addition, the software will stimulate new ideas, will provide the capability of assessing and adapting low-emission combustors to alternate fuels, and will greatly reduce the development time cycle of combustion systems. The revolutionary combustion simulation software is able to accurately simulate the highly transient nature of gaseous-fueled (e.g. natural gas, low BTU syngas, hydrogen, biogas etc.) turbulent combustion and assess innovative concepts needed for Vision 21 plants. In addition, the software is capable of analyzing liquid-fueled combustion systems since that capability was developed under a concurrent Air Force Small Business Innovative Research (SBIR) program. The complex physics of the reacting flow field are captured using 3D Large Eddy Simulation (LES) methods, in which large scale transient motion is resolved by time-accurate numerics, while the small scale motion is modeled using advanced subgrid turbulence and chemistry closures. In this way, LES combustion simulations can model many physical aspects that, until now, were impossible to predict with 3D steady-state Reynolds Averaged Navier-Stokes (RANS) analysis, i.e. very low NOx emissions, combustion instability (coupling of unsteady heat and acoustics), lean blowout, flashback, autoignition, etc. LES methods are becoming more and more practical by linking together tens

Proceedings of the 2006 Combustion Institute Canadian Section spring technical meeting

International Nuclear Information System (INIS)

Devaud, C.; Weckman, E.; Lam, C.; Spike, E.

2006-01-01

This conference provided a networking opportunity for academic, government and industrial combustion researchers from across Canada. All aspects of combustion were discussed, particularly those related to new engine technologies that reduce exhaust gas emissions while maintaining performance. Major engine operating and fuelling control parameters that improve combustion efficiency were identified. The conference was divided into several sessions dealing with combustion emissions and pollutants such as soot and particulates; alternative fuels including biofuels and fuel cells; chemical kinetics; droplet and spray combustion; combustion synthesis of materials; detonations, explosions, fires, flammability, flares and incineration; environmental issues and hazard analysis; and, numerical modeling and simulation. The conference featured 61 presentations, of which 39 have been catalogued separately for inclusion in this database

Novel approaches in advanced combustion characterization of fuels for advanced pressurized combustion

Energy Technology Data Exchange (ETDEWEB)

Aho, M.; Haemaelaeinen, J. [VTT Energy (Finland); Joutsenoja, T. [Tampere Univ. of Technology (Finland)

1996-12-01

This project is a part of the EU Joule 2 (extension) programme. The objective of the research of Technical Research Centre of Finland (VTT) is to produce experimental results of the effects of pressure and other important parameters on the combustion of pulverized coals and their char derivates. The results can be utilized in modelling of pressurized combustion and in planning pilot-scale reactors. The coals to be studied are Polish hvb coal, French lignite (Gardanne), German anthracite (Niederberg) and German (Goettelbom) hvb coal. The samples are combusted in an electrically heated, pressurized entrained flow reactor (PEFR), where the experimental conditions are controlled with a high precision. The particle size of the fuel can vary between 100 and 300 {mu}m. The studied things are combustion rates, temperatures and sizes of burning single coal and char particles. The latter measurements are performed with a method developed by Tampere University of Technology, Finland. In some of the experiments, mass loss and elemental composition of the char residue are studied in more details as the function of time to find out the combustion mechanism. Combustion rate of pulverized (140-180 {mu}m) Gardanne lignite and Niederberg anthracite were measured and compared with the data obtained earlier with Polish hvb coal at various pressures, gas temperatures, oxygen partial pressures and partial pressures of carbon dioxide in the second working period. In addition, particle temperatures were measured with anthracite. The experimental results were treated with multivariable partial least squares (PLS) method to find regression equation between the measured things and the experimental variables. (author)

CFD analysis of premixed hydrogen/air combustion in an upright, rectangular shaped combustion chamber

International Nuclear Information System (INIS)

Gera, B.; Singh, R.K.; Vaze, K.K.

2014-01-01

Premixed hydrogen/air combustion in an upright, rectangular shaped combustion chamber has been performed numerically using commercial CFD code CFD-ACE+. The combustion chamber had dimensions 1 m X 0.024 m X 1 m. Simulations were carried out for 10% (v/v) hydrogen concentration for which experimental results were available. Effect of different boundary condition and ignition position on flame propagation was studied. Time dependent flame propagation in the chamber was predicted by CFD code. The computed transient flame propagation in the chamber was in good agreement with experimental results. The present work demonstrated that the available commercial CFD codes are capable of modeling hydrogen deflagration in a realistic manner. (author)

Experimental and CFD investigation of gas phase freeboard combustion

DEFF Research Database (Denmark)

Andersen, Jimmy

Reliable and accurate modeling capabilities for combustion systems are valuable tools for optimization of the combustion process. This work concerns primary precautions for reducing NO emissions, thereby abating the detrimental effects known as “acid rain”, and minimizing cost for flue gas...... treatment. The aim of this project is to provide validation data for Computational Fluid Dynamic (CFD) models relevant for grate firing combustion conditions. CFD modeling is a mathematical tool capable of predicting fluid flow, mixing and chemical reaction with thermal conversion and transport. Prediction......, but under well-defined conditions. Comprehensive experimental data for velocity field, temperatures, and gas composition are obtained from a 50 kW axisymmetric non-swirling natural gas fired combustion setup under two different settings. Ammonia is added to the combustion setup in order to simulate fuel...

Using biofuel tracers to study alternative combustion regimes

International Nuclear Information System (INIS)

Mack, J.H.; Flowers, D.L.; Buchholz, B.A.; Dibble, R.W.

2007-01-01

Interest in the use of alternative fuels and engines is increasing as the price of petroleum climbs. The inherently higher efficiency of Diesel engines has led to increased adoption of Diesels in Europe, capturing approximately 40% of the new passenger car market. Unfortunately, lower CO 2 emissions are countered with higher nitrogen oxides (NO x ) and particulate matter (PM) emissions and higher noise. Adding oxygenated compounds to the fuel helps reduce PM emissions. However, relying on fuel alone to reduce PM is unrealistic due to economic constraints and difficult due to the emerging PM standards. Keeping peak combustion temperature below 1700 K inhibits NO x formation. Altering the combustion regime to burn at temperatures below the NO x threshold and accept a wide variety of fuels seems like a promising alternative for future engines. Homogeneous charge compression ignition (HCCI) is a possible solution. Fuel and air are well mixed prior to intake into a cylinder (homogeneous charge) and ignition occurs by compression of the fuel-air mixture by the piston. HCCI is rapid and relatively cool, producing little NO x and PM. Unfortunately, it is hard to control since HCCI is initiated by temperature and pressure instead of a spark or direct fuel injection. We investigate biofuel HCCI combustion, and use intrinsically labeled biofuels as tracers of HCCI combustion. Data from tracer experiments are used to improve our combustion modeling

Combustion technology developments in power generation in response to environmental challenges

Energy Technology Data Exchange (ETDEWEB)

BeerBeer, J.M. [Massachusetts Inst. of Technology, Dept. of Chemical Engineering, Cambridge, MA (United States)

2000-07-01

Combustion system development in power generation is discussed ranging from the pre-environmental era in which the objectives were complete combustion with a minimum of excess air and the capability of scale up to increased boiler unit performances, through the environmental era (1970-), in which reduction of combustion generated pollution was gaining increasing importance, to the present and near future in which a combination of clean combustion and high thermodynamic efficiency is considered to be necessary to satisfy demands for CO{sub 2} emissions mitigation. From the 1970's on, attention has increasingly turned towards emission control technologies for the reduction of oxides of nitrogen and sulfur, the so-called acid rain precursors. By a better understanding of the NO{sub x} formation and destruction mechanisms in flames, it has become possible to reduce significantly their emissions via combustion process modifications, e.g. by maintaining sequentially fuel-rich and fuel-lean combustion zones in a burner flame or in the combustion chamber, or by injecting a hydrocarbon rich fuel into the NO{sub x} bearing combustion products of a primary fuel such as coal. Sulfur capture in the combustion process proved to be more difficult because calcium sulfate, the reaction product of SO{sub 2} and additive lime, is unstable at the high temperature of pulverised coal combustion. It is possible to retain sulfur by the application of fluidised combustion in which coal burns at much reduced combustion temperatures. Fluidised bed combustion is, however, primarily intended for the utilisation of low grade, low volatile coals in smaller capacity units, which leaves the task of sulfur capture for the majority of coal fired boilers to flue gas desulfurisation. During the last decade, several new factors emerged which influenced the development of combustion for power generation. CO{sub 2} emission control is gaining increasing acceptance as a result of the international

Modelling of Non-Premixed Turbulent Combustion of Hydrogen using Conditional Moment Closure Method

International Nuclear Information System (INIS)

Noor, M M; Hairuddin, A Aziz; Wandel, Andrew P; Yusaf, T F

2012-01-01

Most of the electricity generation and energy for transport is still generated by the conversion of chemical to mechanical energy by burning the fuels in the combustion chamber. Regulation for pollution and the demand for more fuel economy had driven worldwide researcher to focus on combustion efficiency. In order to reduce experimental cost, accurate modelling and simulation is very critical step. Taylor series expansion was utilised to reduce the error term for the discretization. FORTRAN code was used to execute the discretized partial differential equation. Hydrogen combustion was simulated using Conditional Moment Closure (CMC) model. Combustion of hydrogen with oxygen was successfully simulated and reported in this paper.

Combustion in a High-Speed Compression-Ignition Engine

Science.gov (United States)

Rothrock, A M

1933-01-01

An investigation conducted to determine the factors which control the combustion in a high-speed compression-ignition engine is presented. Indicator cards were taken with the Farnboro indicator and analyzed according to the tangent method devised by Schweitzer. The analysis show that in a quiescent combustion chamber increasing the time lag of auto-ignition increases the maximum rate of combustion. Increasing the maximum rate of combustion increases the tendency for detonation to occur. The results show that by increasing the air temperature during injection the start of combustion can be forced to take place during injection and so prevent detonation from occurring. It is shown that the rate of fuel injection does not in itself control the rate of combustion.

Combustion stratification study of partially premixed combustion using Fourier transform analysis of OH* chemiluminescence images

KAUST Repository

Izadi Najafabadi, Mohammad

2017-11-06

A relatively high level of stratification (qualitatively: lack of homogeneity) is one of the main advantages of partially premixed combustion over the homogeneous charge compression ignition concept. Stratification can smooth the heat release rate and improve the controllability of combustion. In order to compare stratification levels of different partially premixed combustion strategies or other combustion concepts, an objective and meaningful definition of “stratification level” is required. Such a definition is currently lacking; qualitative/quantitative definitions in the literature cannot properly distinguish various levels of stratification. The main purpose of this study is to objectively define combustion stratification (not to be confused with fuel stratification) based on high-speed OH* chemiluminescence imaging, which is assumed to provide spatial information regarding heat release. Stratification essentially being equivalent to spatial structure, we base our definition on two-dimensional Fourier transforms of photographs of OH* chemiluminescence. A light-duty optical diesel engine has been used to perform the OH* bandpass imaging on. Four experimental points are evaluated, with injection timings in the homogeneous regime as well as in the stratified partially premixed combustion regime. Two-dimensional Fourier transforms translate these chemiluminescence images into a range of spatial frequencies. The frequency information is used to define combustion stratification, using a novel normalization procedure. The results indicate that this new definition, based on Fourier analysis of OH* bandpass images, overcomes the drawbacks of previous definitions used in the literature and is a promising method to compare the level of combustion stratification between different experiments.

1998 annual report of advanced combustion science utilizing microgravity

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

For the purpose of stabilizing energy supply, diversifying energy supply sources and reducing the worsening of global environment caused by combustion exhaust gases, advanced combustion technology was studied and the FY 1998 results were summarized. Following the previous year, the following were conducted: international research jointly with NASA, experiments using microgravity test facilities of Japan Space Utilization Promotion Center (JSUP), evaluation studies made by universities/national research institutes/private companies, etc. In the FY 1998 joint study, a total of 52 drop experiments were carried out on 4 themes using test facilities of Japan Microgravity Center (JAMIC), and 100 experiments were conducted on one theme using test facilities of NASA. In the study using microgravity test facilities, the following were carried out: study of combustion and evaporation of fuel droplets, study of ignition/combustion of fuel droplets in the suspending state, study of combustion of spherical/cylinder state liquid fuels, study of high pressure combustion of binary fuel spray, study of interaction combustion of fuel droplets in the microgravity field, etc. (NEDO)

Characterization of biomass combustion at high temperatures based on an upgraded single particle model

International Nuclear Information System (INIS)

Li, Jun; Paul, Manosh C.; Younger, Paul L.; Watson, Ian; Hossain, Mamdud; Welch, Stephen

2015-01-01

Highlights: • High temperature rapid biomass combustion is studied based on single particle model. • Particle size changes in devolatilization and char oxidation models are addressed. • Time scales of various thermal sub-processes are compared and discussed. • Potential solutions are suggested to achieve better biomass co-firing performances. - Abstract: Biomass co-firing is becoming a promising solution to reduce CO 2 emissions, due to its renewability and carbon neutrality. Biomass normally has high moisture and volatile contents, complicating its combustion behavior, which is significantly different from that of coal. A computational fluid dynamics (CFD) combustion model of a single biomass particle is employed to study high-temperature rapid biomass combustion. The two-competing-rate model and kinetics/diffusion model are used to model biomass devolatilization reaction and char burnout process, respectively, in which the apparent kinetics used for those two models were from high temperatures and high heating rates tests. The particle size changes during the devolatilization and char burnout are also considered. The mass loss properties and temperature profile during the biomass devolatilization and combustion processes are predicted; and the timescales of particle heating up, drying, devolatilization, and char burnout are compared and discussed. Finally, the results shed light on the effects of particle size on the combustion behavior of biomass particle

Engine combustion control via fuel reactivity stratification

Science.gov (United States)

Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

2013-12-31

A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choose the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

Modeling of microgravity combustion experiments

Science.gov (United States)

Buckmaster, John

1995-01-01

This program started in February 1991, and is designed to improve our understanding of basic combustion phenomena by the modeling of various configurations undergoing experimental study by others. Results through 1992 were reported in the second workshop. Work since that time has examined the following topics: Flame-balls; Intrinsic and acoustic instabilities in multiphase mixtures; Radiation effects in premixed combustion; Smouldering, both forward and reverse, as well as two dimensional smoulder.

Co-combustion: A summary of technology

Directory of Open Access Journals (Sweden)

Leckner Bo

2007-01-01

Full Text Available Co-combustion of biomass or waste together with a base fuel in a boiler is a simple and economically suitable way to replace fossil fuels by biomass and to utilize waste. Co-combustion in a high-efficiency power station means utilization of biomass and waste with a higher thermal efficiency than what otherwise had been possible. Due to transport limitations, the additional fuel will only supply a minor part (less than a few hundreds MW fuel of the energy in a plant. There are several options: co-combustion with coal in pulverized or fluidized bed boilers, combustion on added grates inserted in pulverized coal boilers, combustors for added fuel coupled in parallel to the steam circuit of a power plant, external gas producers delivering its gas to replace an oil, gas or pulverized fuel burner. Furthermore biomass can be used for reburning in order to reduce NO emissions or for afterburning to reduce N2O emissions in fluidized bed boilers. Combination of fuels can give rise to positive or negative synergy effects, of which the best known are the interactions between S, Cl, K, Al, and Si that may give rise to or prevent deposits on tubes or on catalyst surfaces, or that may have an influence on the formation of dioxins. With better knowledge of these effects the positive ones can be utilized and the negative ones can be avoided.

Ignition delays, heats of combustion, and reaction rates of aluminum alkyl derivatives used as ignition and combustion enhancers for supersonic combustion

Science.gov (United States)

Ryan, Thomas W., III; Schwab, S. T.; Harlowe, W. W.

1992-01-01

The subject of this paper is the design of supersonic combustors which will be required in order to achieve the needed reaction rates in a reasonable sized combustor. A fuel additive approach, which is the focus of this research, is the use of pyrophorics to shorten the ignition delay time and to increase the energy density of the fuel. Pyrophoric organometallic compounds may also provide an ignition source and flame stabilization mechanism within the combustor, thus permitting use of hydrocarbon fuels in supersonic combustion systems. Triethylaluminum (TEA) and trimethylaluminum (TMA) were suggested for this application due to their high energy density and reactivity. The objective here is to provide comparative data for the ignition quality, the energy content, and the reaction rates of several different adducts of both TEA and TMA. The results of the experiments indicate the aluminum alkyls and their more stable derivatives reduce the ignition delay and total reaction time to JP-10 jet fuel. Furthermore, the temperature dependence of ignition delay and total reaction time of the blends of the adducts are significantly lower than in neat JP-10.

Annual Report: DOE Advanced Combustion Systems & Fuels R&D; Light-Duty Diesel Combustion

Energy Technology Data Exchange (ETDEWEB)

Busch, Stephen [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2017-11-01

Despite compliance issues in previous years, automakers have demonstrated that the newest generation of diesel power trains are capable of meeting all federal and state regulations (EPA, 2016). Diesels continue to be a cost-effective, efficient, powerful propulsion source for many light- and medium-duty vehicle applications (Martec, 2016). Even modest reductions in the fuel consumption of light- and medium duty diesel vehicles in the U.S. will eliminate millions of tons of CO2 emissions per year. Continued improvement of diesel combustion systems will play an important role in reducing fleet fuel consumption, but these improvements will require an unprecedented scientific understanding of how changes in engine design and calibration affect the mixture preparation, combustion, and pollutant formation processes that take place inside the cylinder. The focus of this year’s research is to provide insight into the physical mechanisms responsible for improved thermal efficiency observed with a stepped-lip piston. Understanding how piston design can influence efficiency will help engineers develop and optimize new diesel combustion systems.

Mitigating the effect of siloxanes on internal combustion engines using landfill gasses

Science.gov (United States)

Besmann, Theodore M

2014-01-21

A waste gas combustion method that includes providing a combustible fuel source, in which the combustible fuel source is composed of at least methane and siloxane gas. A sodium source or magnesium source is mixed with the combustible fuel source. Combustion of the siloxane gas of the combustible fuel source produces a silicon containing product. The sodium source or magnesium source reacts with the silicon containing product to provide a sodium containing glass or sodium containing silicate, or a magnesium containing silicate. By producing the sodium containing glass or sodium containing silicate, or the magnesium containing silicate, or magnesium source for precipitating particulate silica instead of hard coating, the method may reduce or eliminate the formation of silica deposits within the combustion chamber and the exhaust components of the internal combustion engine.

IEA combustion agreement : a collaborative task on alternative fuels in combustion

International Nuclear Information System (INIS)

Larmi, M.

2009-01-01

The focus of the alternative fuels in combustion task of the International Energy Agency is on high efficiency engine combustion, furnace combustion, and combustion chemistry. The objectives of the task are to develop optimum combustion for dedicated fuels by fully utilizing the physical and chemical properties of synthetic and renewable fuels; a significant reduction in carbon dioxide, NOx and particulate matter emissions; determine the minimum emission levels for dedicated fuels; and meet future emission standards of engines without or with minimum after-treatment. This presentation discussed the alternative fuels task and addressed issues such as synthetic fuel properties and benefits. The anticipated future roadmap was presented along with a list of the synthetic and renewable engine fuels to be studied, such as neat oxygenates like alcohols and ethers, biogas/methane and gas combustion, fuel blends, dual fuel combustion, high cetane number diesel fuels like synthetic Fischer-Tropsch diesel fuel and hydrogenated vegetable oil, and low CN number fuels. Implementation examples were also discussed, such as fuel spray studies in optical spray bombs; combustion research in optical engines and combustion chambers; studies on reaction kinetics of combustion and emission formation; studies on fuel properties and ignition behaviour; combustion studies on research engines; combustion optimization; implementing the optimum combustion in research engines; and emission measurements. Overall milestone examples and the overall schedule of participating countries were also presented. figs.

Characteristic Study of Shenmu Bituminous Coal Combustion with Online TG-MS-FTIR

Science.gov (United States)

Pan, Guanfu

2018-01-01

The combustion characteristics of Shenmu bituminous pulverized coal (SBC) were comprehensively investigated with a combined TG-MS-FTIR system by considering the effect of particle size, heating rate and total flowrate. The combustion products were accurately quantified by normalization and numerical analysis of MS results. The results indicate that the decrease of the particle size, heating rate and total flowrate result in lower ignition and burnout temperatures. The activation energy tends to be lower with smaller particle size, lower heating rate and total flowrate. The MS and FTIR results demonstrate that lower concentrations of different products, such as NO, NO2, HCN, CH4 and SO2 were produced with smaller particle size, slower heating rate and lower total flowrate. The decrease of particle size would lead to more contact area with oxygen and slower heating rate could provide more sufficient time for the diffusion. High total flowrate would reduce the oxygen adsorbability on the coal particle surface and shorten the residence time of oxygen, which makes the ignition difficult to occur. This work will guide to understand the combustion kinetics of pulverized coals and be beneficial to control the formation of pollutants.

A synthesis of carbon dioxide emissions from fossil-fuel combustion

Directory of Open Access Journals (Sweden)

R. J. Andres

2012-05-01

Full Text Available This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e., maps; how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10 % uncertainty (95 % confidence interval. Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. This manuscript concludes that carbon dioxide emissions from fossil-fuel combustion continue to increase with time and that while much is known about the overall characteristics of these emissions, much is still to be learned about the detailed characteristics of these emissions.

Thermal Behavior of Coal Used in Rotary Kiln and Its Combustion Intensification

Directory of Open Access Journals (Sweden)

Qiang Zhong

2018-04-01

Full Text Available Pyrolysis and combustion behaviors of three coals (A, B, and C coals were investigated and their combustion kinetics were calculated by the Freeman–Carroll method to obtain quantitative insight into their combustion behaviors. Moreover, the effects of coal size, air flow, oxygen content, and heating rate on coal combustion behaviors were analyzed. Results showed that the three coals have a similar trend of pyrolysis that occurs at about 670 K and this process continuously proceeds along with their combustion. Combustion characteristics and kinetic parameters can be applied to analyze coal combustion behaviors. Three coals having combustion characteristics of suitable ignition temperature (745–761 K, DTGmax (14.20–15.72%/min, and burnout time (7.45–8.10 min were analyzed in a rotary kiln. Combustion kinetic parameters provide quantitative insights into coal combustion behavior. The suitable particle size for coal combustion in a kiln is that the content of less than 74 μm is 60% to 80%. Low activation energy and reaction order make coal, especially C coal, have a simple combustion mechanism, great reactivity, be easily ignited, and a low peak temperature in the combustion state. Oxygen-enrichment and high heating rates enhance coal combustion, increasing combustion intensity and peak value, thus shortening burnout time.

Internal combustion engine using premixed combustion of stratified charges

Science.gov (United States)

Marriott, Craig D [Rochester Hills, MI; Reitz, Rolf D [Madison, WI

2003-12-30

During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

Combustion of lean hydrogen-air mixtures in the connected compartments

International Nuclear Information System (INIS)

Fan Liu; Yoshio Yoshizawa; Akio Miyori; Kenya Kubota

1997-01-01

A study of combustion experiments with premixed lean hydrogen-air mixtures was conducted in a vessel consisting of two compartments connected by a diameter-variable vent. Effects of various parameters (hydrogen concentration, vent diameter and initial pressure) on mechanical loads of the combustion processes including mainly the peak pressures and the rates of pressure rise were investigated. Relation of flow and combustion was approached. Ignition-combustion processes were discussed, and the combustion types were classified into three patterns according to the pressure-time histories and the flow characteristics in main combustion compartment

Effect of fuel injection parameters on combustion stability and emissions of a mineral diesel fueled partially premixed charge compression ignition (PCCI) engine

International Nuclear Information System (INIS)

Jain, Ayush; Singh, Akhilendra Pratap; Agarwal, Avinash Kumar

2017-01-01

Highlights: • NOx and PM emissions were lowest at 700 bar fuel injection pressure (FIP). • PCCI showed lower knocking than compression ignition combustion mode. • Increasing FIP reduced emissions of nitrogen oxides and smoke opacity in PCCI mode. • Increasing FIP reduced nucleation mode particle concentration. • Increasing FIP with advanced main injection timings improved PCCI combustion. - Abstract: This experimental study focuses on developing new combustion concept for compression ignition (CI) engines by achieving partially homogeneous charge, leading to low temperature combustion (LTC). Partially premixed charge compression ignition (PCCI) combustion is a single-stage phenomenon, with combustion shifting towards increasingly premixed combustion phase, resulting in lower in-cylinder temperatures. PCCI leads to relatively lower emissions of oxides of nitrogen (NOx) and particulate matter (PM) simultaneously. To investigate combustion, performance and emission characteristics of the PCCI engine, experiments were performed in a mineral diesel fueled single cylinder research engine, which was equipped with flexible fuel injection equipment (FIE). Effects of fuel injection pressure (FIP) were investigated by changing the FIP from 400 bar to 1000 bar. Experiments were carried out by varying start of main injection (SoMI) timings (from 12° to 24° before top dead center (bTDC)), when using single pilot injection. This experimental study included detailed investigations of particulate characteristics such as particulate number-size distribution using engine exhaust particle sizer (EEPS), particulate bound trace metal analysis using inductively coupled plasma-optical emission spectrometer (ICP-OES), and soot morphology using transmission electron microscopy (TEM). PCCI combustion improved with increasing FIP (up to 700 bar) due to superior fuel atomization however further increasing FIP deteriorated PCCI combustion and engine performance due to intense

Science review of internal combustion engines

International Nuclear Information System (INIS)

Taylor, Alex M.K.P.

2008-01-01

Internal combustion engines used in transportation produce about 23% of the UK's carbon dioxide emission, up from 14% in 1980. The current science described in this paper suggests that there could be 6-15% improvements in internal combustion fuel efficiency in the coming decade, although filters to meet emission legislation reduce these gains. Using these engines as hybrids with electric motors produces a reduction in energy requirements in the order of 21-28%. Developments beyond the next decade are likely to be dominated by four topics: emission legislation and emission control, new fuels, improved combustion and a range of advanced concepts for energy saving. Emission control is important because current methods for limiting nitrogen oxides and particulate emissions imply extra energy consumption. Of the new fuels, non-conventional fossil-derived fuels are associated with larger greenhouse gas emissions than conventional petroleum-based fuels, while a vehicle propelled by fuel cells consuming non-renewable hydrogen does not necessarily offer an improvement in emissions over the best hybrid internal combustion engines. Improved combustion may be developed for both gasoline and diesel fuels and promises better efficiency as well as lower noxious emissions without the need for filtering. Finally, four advanced concepts are considered: new thermodynamic cycles, a Rankine bottoming cycle, electric turbo-compounding and the use of thermoelectric devices. The latter three all have the common theme of trying to extract energy from waste heat, which represents about 30% of the energy input to an internal combustion engine

Combustion Stratification for Naphtha from CI Combustion to PPC

KAUST Repository

Vallinayagam, R.; Vedharaj, S.; An, Yanzhao; Dawood, Alaaeldin; Izadi Najafabadi, Mohammad; Somers, Bart; Johansson, Bengt

2017-01-01

This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON

Fuel and combustion stratification study of Partially Premixed Combustion

OpenAIRE

Izadi Najafabadi, M.; Dam, N.; Somers, B.; Johansson, B.

2016-01-01

Relatively high levels of stratification is one of the main advantages of Partially Premixed Combustion (PPC) over the Homogeneous Charge Compression Ignition (HCCI) concept. Fuel stratification smoothens heat release and improves controllability of this kind of combustion. However, the lack of a clear definition of “fuel and combustion stratifications” is obvious in literature. Hence, it is difficult to compare stratification levels of different PPC strategies or other combustion concepts. T...

Effect of bed particles to combustion of gases in fluidized bed

Energy Technology Data Exchange (ETDEWEB)

Raiko, R.; Wallen, V.; Etelaeaho, R.; Correia, S. [Tampere Univ. of Technology (Finland). Energy and Process Engineering

1997-10-01

The objective of this project was to obtain experimental data on effects of sand particles to the combustion of gases. The effect of the surface area of the particles was tested using different sized particles. The fluidized bed reactor used in these experiments was a stainless-steel tube with an internal diameter of 42 mm surrounded by an electric heater. The test rig was built in the Laboratory of Energy and Process Engineering at Tampere University of Technology. In order to elucidate the possible changes of particle surface, microscopic and porosimetric studies were conducted with both fresh bed particles and used bed particles. These measurements indicate that carbon monoxide significantly reacts with oxygen in the particulate or emulsion phase of a fluidized bed, if the residence time is long enough. The reaction rate depends mainly on temperature, air coefficient, residence time and particle size of the solids. It seems that the combustion enhances if the average particle size increases. Whether this is caused by increased free path length or reduced specific surface area of the bed is yet unknown. The first might be more probable cause because the majority of reactions often took place in the freeboard right above the bed. It was clear that the bed hindered proper combustion in several cases. (orig.)

Pulsed atmospheric fluidized bed combustion. Final report

Energy Technology Data Exchange (ETDEWEB)

1989-11-01

In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

Experimental and numerical investigation of hetero-/homogeneous combustion-based HCCI of methane–air mixtures in free-piston micro-engines

International Nuclear Information System (INIS)

Chen, Junjie; Liu, Baofang; Gao, Xuhui; Xu, Deguang

2016-01-01

Highlights: • Single-shot experiments and a transient model of micro-engine were presented. • Coupled combustion can significantly improve in-cylinder temperatures. • Coupled combustion can reduce mass losses and compression ratios. • Heterogeneous reactions cause earlier ignition. • Heat losses result in higher mass losses. - Abstract: The hetero-/homogenous combustion-based HCCI (homogeneous charge compression ignition) of fuel–lean methane–air mixtures over alumina-supported platinum catalysts was investigated experimentally and numerically in free-piston micro-engines without ignition sources. Single-shot experiments were carried out in the purely homogeneous and coupled hetero-/homogeneous combustion modes, involved temperature measurements, capturing the visible combustion image sequences, exhaust gas analysis, and the physicochemical characterization of catalysts. Simulations were performed with a two-dimensional transient model that includes detailed hetero-/homogeneous chemistry and transport, leakage, and free-piston motion to gain physical insight and to explore the hetero-/homogeneous combustion characteristics. The micro-engine performance concerning combustion efficiency, mass loss, energy density, and free-piston dynamics was investigated. The results reveal that both purely homogeneous and coupled hetero-/homogeneous combustion of methane–air mixtures in a narrow cylinder with a diameter of 3 mm and a height of approximately 0.3 mm are possible. The coupled hetero-/homogeneous mode can not only significantly improve the combustion efficiency, in-cylinder temperature and pressure, output power and energy density, but also reduce the mass loss because of its lower compression ratio and less time spent around TDC (top dead center) and during the expansion stroke, indicating that this coupled mode is a promising combustion scheme for micro-engine. Heat losses result in higher mass losses. Heterogeneous reactions cause earlier ignition

Environmental considerations on the FBC combustion of dry sewage sludge

Energy Technology Data Exchange (ETDEWEB)

Lopes, M. Helena; Abelha, Pedro; Gulyurtlu, Ibrahim; Cabrita, Isabel [INETI/DEECA, Lisboa (Portugal)

2001-07-01

This paper presents results of on-going research on the incineration of pre-dried granular sewage sludges using a FBC system. Co-combustion is compared with mono-combustion of sludges leads to minor emissions and higher retention of Cd, Pb, Cu, and Zn in the bottom ashes, when compared to co-combustion with coal. The leachability of the sludge is reduced through combustion, as none of the metals, Cd, Cr, Ca Ni, Ph, Zn, Co and Mn were leached from the bottom ashes. These findings may contribute to an improvement in the incineration of sewage sludges and to the development of applications for the ashes in civil engineering activities.

Researches on direct injection in internal-combustion engines

Science.gov (United States)

Tuscher, Jean E

1941-01-01

These researches present a solution for reducing the fatigue of the Diesel engine by permitting the preservation of its components and, at the same time, raising its specific horsepower to a par with that of carburetor engines, while maintaining for the Diesel engine its perogative of burning heavy fuel under optimum economical conditions. The feeding of Diesel engines by injection pumps actuated by engine compression achieves the required high speeds of injection readily and permits rigorous control of the combustible charge introduced into each cylinder and of the peak pressure in the resultant cycle.

Modeling internal ballistics of gas combustion guns.

Science.gov (United States)

Schorge, Volker; Grossjohann, Rico; Schönekess, Holger C; Herbst, Jörg; Bockholdt, Britta; Ekkernkamp, Axel; Frank, Matthias

2016-05-01

Potato guns are popular homemade guns which work on the principle of gas combustion. They are usually constructed for recreational rather than criminal purposes. Yet some serious injuries and fatalities due to these guns are reported. As information on the internal ballistics of homemade gas combustion-powered guns is scarce, it is the aim of this work to provide an experimental model of the internal ballistics of these devices and to investigate their basic physical parameters. A gas combustion gun was constructed with a steel tube as the main component. Gas/air mixtures of acetylene, hydrogen, and ethylene were used as propellants for discharging a 46-mm caliber test projectile. Gas pressure in the combustion chamber was captured with a piezoelectric pressure sensor. Projectile velocity was measured with a ballistic speed measurement system. The maximum gas pressure, the maximum rate of pressure rise, the time parameters of the pressure curve, and the velocity and path of the projectile through the barrel as a function of time were determined according to the pressure-time curve. The maximum gas pressure was measured to be between 1.4 bar (ethylene) and 4.5 bar (acetylene). The highest maximum rate of pressure rise was determined for hydrogen at (dp/dt)max = 607 bar/s. The muzzle energy was calculated to be between 67 J (ethylene) and 204 J (acetylene). To conclude, this work provides basic information on the internal ballistics of homemade gas combustion guns. The risk of injury to the operator or bystanders is high, because accidental explosions of the gun due to the high-pressure rise during combustion of the gas/air mixture may occur.

Oxy combustion with CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-01-15

An update for oxyfuel-combustion carbon capture in the power industry is provided. The report was developed by the Electric Power Research Institute (EPRI) on behalf of the Global CCS Institute. In the oxyfuel-combustion processes, the bulk nitrogen is removed from the air before combustion. The resulting combustion products will have CO2 content up to about 90 per cent (dry basis). The flue gas impurities (predominantly O2, N2, and Ar) may be removed by reducing the flue gas (at moderate pressure) to a temperature at which the CO2 condenses and the impurities do not. Oxyfuel-combustion may be employed with solid fuels such as coal, petroleum coke, and biomass, as well as liquid and gaseous fuels. Some key points raised in the oxyfuel-combustion carbon capture report are: The oxyfuel-combustion/CO2 capture power plant designs being developed and deployed for service in the next four or five years are based on individual component technologies and arrangements which have demonstrated sufficient maturity, with the greatest remaining technical challenge being integrating the systems into a complete steam-electric power plant; By its nature, an oxyfuel-coal power plant is likely to be a 'near zero' emitter of all criteria pollutants; Existing air-fired power plants might be retrofitted with an air separation unit, oxyfuel-fired burners, flue gas recycle, and a CO2 processing unit, with the large fleet of air-fired power plants in service calling for more study of this option; and, Future efficiency improvements to the oxyfuel-combustion process for power generation point toward an oxyfuel-combustion plant with near zero emissions of conventional pollutants, up to 98 per cent CO2 capture, and efficiency comparable to the best power plants currently being built.

Steam-moderated oxy-fuel combustion

International Nuclear Information System (INIS)

Seepana, Sivaji; Jayanti, Sreenivas

2010-01-01

The objective of the present paper is to propose a new variant of the oxy-fuel combustion for carbondioxide (CO 2 ) sequestration in which steam is used to moderate the flame temperature. In this process, pure oxygen is mixed with steam and the resulting oxidant mixture is sent to the boiler for combustion with a fossil fuel. The advantage of this method is that flue gas recirculation is avoided and the volumetric flow rates through the boiler and auxiliary components is reduced by about 39% when compared to the conventional air-fired coal combustion power plant leading to a reduction in the size of the boiler. The flue gas, after condensation of steam, consists primarily of CO 2 and can be sent directly for compression and sequestration. Flame structure analysis has been carried out using a 325-step reaction mechanism of methane-oxidant combustion to determine the concentration of oxygen required to ensure a stable flame. Thermodynamic exergy analysis has also been carried out on SMOC-operated CO 2 sequestration power plant and air-fired power plant, which shows that though the gross efficiency increases the absolute power penalty of ∼8% for CO 2 sequestration when compared to air-fired power plant.

Steam-moderated oxy-fuel combustion

Energy Technology Data Exchange (ETDEWEB)

Seepana, Sivaji; Jayanti, Sreenivas [Department of Chemical Engineering, IIT Madras, Adyar, Chennai 600 036 (India)

2010-10-15

The objective of the present paper is to propose a new variant of the oxy-fuel combustion for carbondioxide (CO{sub 2}) sequestration in which steam is used to moderate the flame temperature. In this process, pure oxygen is mixed with steam and the resulting oxidant mixture is sent to the boiler for combustion with a fossil fuel. The advantage of this method is that flue gas recirculation is avoided and the volumetric flow rates through the boiler and auxiliary components is reduced by about 39% when compared to the conventional air-fired coal combustion power plant leading to a reduction in the size of the boiler. The flue gas, after condensation of steam, consists primarily of CO{sub 2} and can be sent directly for compression and sequestration. Flame structure analysis has been carried out using a 325-step reaction mechanism of methane-oxidant combustion to determine the concentration of oxygen required to ensure a stable flame. Thermodynamic exergy analysis has also been carried out on SMOC-operated CO{sub 2} sequestration power plant and air-fired power plant, which shows that though the gross efficiency increases the absolute power penalty of {proportional_to}8% for CO{sub 2} sequestration when compared to air-fired power plant. (author)

Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

Energy Technology Data Exchange (ETDEWEB)

Soloiu, Valentin A. [Georgia Southern Univ., Statesboro, GA (United States)

2012-03-31

The research advanced fundamental science and applied engineering for increasing the efficiency of internal combustion engines and meeting emissions regulations with biofuels. The project developed a laboratory with new experiments and allowed investigation of new fuels and their combustion and emissions. This project supports a sustainable domestic biofuels and automotive industry creating economic opportunities across the nation, reducing the dependence on foreign oil, and enhancing U.S. energy security. The one year period of research developed fundamental knowledge and applied technology in advanced combustion, emissions and biofuels formulation to increase vehicle's efficiency. Biofuels combustion was investigated in a Compression Ignition Direct Injection (DI) to develop idling strategies with biofuels and an Indirect Diesel Injection (IDI) intended for auxiliary power unit.

Spontaneous human combustion in the light of the 21st century.

Science.gov (United States)

Koljonen, Virve; Kluger, Nicolas

2012-01-01

The term "spontaneous human combustion" refers to a situation when a human body is found with significant portions of the middle parts of the body reduced to ashes, much less damage to the head and extremities, and minimal damage to the direct surroundings of the body. Typically, no observable source of ignition is found in the vicinity of the victim and a bad smelling oily substance is noted. In the past, such a situation was erroneously attributed to supernatural powers, as such phenomenon occurs in the absence of any witness. The purpose of this review article was to analyze articles published from January 1, 2000, on this unique type of burn injury. Further aims were to gather and present data on the causes and events leading to this situation. The literature was reviewed with PubMed interface using the key words spontaneous human combustion and preternatural combustion. Specific inclusion criteria resulted in 12 patients. A unique sequence of events takes place for the human body to incinerate to ashes. The flame burn victim has to die for the body fat to start melting. A tear in the skin has to occur for the melted fat to impregnate the charred clothes, igniting a wick effect that produces localized heat for extended period. A phenomenon called spontaneous human combustion is reality. The term "spontaneous human combustion" has nuances which are not applicable to this situation or to these modern times, therefore we suggest a new term "fat wick burns."

Two phase exhaust for internal combustion engine

Science.gov (United States)

Vuk, Carl T [Denver, IA

2011-11-29

An internal combustion engine having a reciprocating multi cylinder internal combustion engine with multiple valves. At least a pair of exhaust valves are provided and each supply a separate power extraction device. The first exhaust valves connect to a power turbine used to provide additional power to the engine either mechanically or electrically. The flow path from these exhaust valves is smaller in area and volume than a second flow path which is used to deliver products of combustion to a turbocharger turbine. The timing of the exhaust valve events is controlled to produce a higher grade of energy to the power turbine and enhance the ability to extract power from the combustion process.

Sound quality assessment of Diesel combustion noise using in-cylinder pressure components

Science.gov (United States)

Payri, F.; Broatch, A.; Margot, X.; Monelletta, L.

2009-01-01

The combustion process in direct injection (DI) Diesel engines is an important source of noise, and it is thus the main reason why end-users could be reluctant to drive vehicles powered with this type of engine. This means that the great potential of Diesel engines for environment preservation—due to their lower consumption and the subsequent reduction of CO2 emissions—may be lost. Moreover, the advanced combustion concepts—e.g. the HCCI (homogeneous charge compression ignition)—developed to comply with forthcoming emissions legislation, while maintaining the efficiency of current engines, are expected to be noisier because they are characterized by a higher amount of premixed combustion. For this reason many efforts have been dedicated by car manufacturers in recent years to reduce the overall level and improve the sound quality of engine noise. Evaluation procedures are required, both for noise levels and sound quality, that may be integrated in the global engine development process in a timely and cost-effective manner. In previous published work, the authors proposed a novel method for the assessment of engine noise level. A similar procedure is applied in this paper to demonstrate the suitability of combustion indicators for the evaluation of engine noise quality. These indicators, which are representative of the peak velocity of fuel burning and the resonance in the combustion chamber, are well correlated with the combustion noise mark obtained from jury testing. Quite good accuracy in the prediction of the engine noise quality has been obtained with the definition of a two-component regression, which also permits the identification of the combustion process features related to the resulting noise quality, so that corrective actions may be proposed.

Signal correlations in biomass combustion. An information theoretic analysis

Energy Technology Data Exchange (ETDEWEB)

Ruusunen, M.

2013-09-01

Increasing environmental and economic awareness are driving the development of combustion technologies to efficient biomass use and clean burning. To accomplish these goals, quantitative information about combustion variables is needed. However, for small-scale combustion units the existing monitoring methods are often expensive or complex. This study aimed to quantify correlations between flue gas temperatures and combustion variables, namely typical emission components, heat output, and efficiency. For this, data acquired from four small-scale combustion units and a large circulating fluidised bed boiler was studied. The fuel range varied from wood logs, wood chips, and wood pellets to biomass residue. Original signals and a defined set of their mathematical transformations were applied to data analysis. In order to evaluate the strength of the correlations, a multivariate distance measure based on information theory was derived. The analysis further assessed time-varying signal correlations and relative time delays. Ranking of the analysis results was based on the distance measure. The uniformity of the correlations in the different data sets was studied by comparing the 10-quantiles of the measured signal. The method was validated with two benchmark data sets. The flue gas temperatures and the combustion variables measured carried similar information. The strongest correlations were mainly linear with the transformed signal combinations and explicable by the combustion theory. Remarkably, the results showed uniformity of the correlations across the data sets with several signal transformations. This was also indicated by simulations using a linear model with constant structure to monitor carbon dioxide in flue gas. Acceptable performance was observed according to three validation criteria used to quantify modelling error in each data set. In general, the findings demonstrate that the presented signal transformations enable real-time approximation of the studied

Drying wood waste with a pulse combustion dryer

Energy Technology Data Exchange (ETDEWEB)

Buchkowski, A.G. [Spectrum Engineering Corp., Ltd., Peterborough, Ontario (Canada); Kitchen, J.A. [John A. Kitchen, Ltd., Hastings, Ontario (Canada)

1993-12-31

There is a vast amount of wood waste available to be used as an alternate fuel if its moisture could be reduced efficiently. Tests have been conducted to assess an industrial dryer using pulse combustion as a heating source for drying wood waste; specifically sawdust and pulverized wet hog fuel. Pulse combustion offers the advantage of high heat transfer, efficient combustion, and low NO{sub x} emissions. The material is injected into the exhaust gases in the tailpipe of the combustor which uses natural gas or propane as a fuel. The turbulence created by the pulsations enhance the drying process by reducing the boundary layer thicknesses. The materials is further dried in a rotary drum. The material has been dried without scorching or burning in tests where the inlet moisture content has been as high as 60% on a wet basis. The outlet moisture contents achieved have typically been 10%. Analysis of the test data and cost estimates of the equipment indicate that the pulse combustion drying system is at least comparable to existing systems in terms of operating costs, and offers very significant savings in capital costs. Testing with various other materials such as wood pulp, sludges and peat is continuing to further assess the equipment`s performance.

Experimental, theoretical, and numerical studies of small scale combustion

Science.gov (United States)

Xu, Bo

Recently, the demand increased for the development of microdevices such as microsatellites, microaerial vehicles, micro reactors, and micro power generators. To meet those demands the biggest challenge is obtaining stable and complete combustion at relatively small scale. To gain a fundamental understanding of small scale combustion in this thesis, thermal and kinetic coupling between the gas phase and the structure at meso and micro scales were theoretically, experimentally, and numerically studied; new stabilization and instability phenomena were identified; and new theories for the dynamic mechanisms of small scale combustion were developed. The reduction of thermal inertia at small scale significantly reduces the response time of the wall and leads to a strong flame-wall coupling and extension of burning limits. Mesoscale flame propagation and extinction in small quartz tubes were theoretically, experimentally and numerically studied. It was found that wall-flame interaction in mesoscale combustion led to two different flame regimes, a heat-loss dominant fast flame regime and a wall-flame coupling slow flame regime. The nonlinear transition between the two flame regimes was strongly dependent on the channel width and flow velocity. It is concluded that the existence of multiple flame regimes is an inherent phenomenon in mesoscale combustion. In addition, all practical combustors have variable channel width in the direction of flame propagation. Quasi-steady and unsteady propagations of methane and propane-air premixed flames in a mesoscale divergent channel were investigated experimentally and theoretically. The emphasis was the impact of variable cross-section area and the flame-wall coupling on the flame transition between different regimes and the onset of flame instability. For the first time, spinning flames were experimentally observed for both lean and rich methane and propane-air mixtures in a broad range of equivalence ratios. An effective Lewis number

Research Needs and Impacts in Predictive Simulation for Internal Combustion Engines (PreSICE)

Energy Technology Data Exchange (ETDEWEB)

Eckerle, Wayne [Cummins, Inc., Columbus, IN (United States); Rutland, Chris [Univ. of Wisconsin, Madison, WI (United States); Rohlfing, Eric [Dept. of Energy (DOE), Washington DC (United States). Office of Science; Singh, Gurpreet [Dept. of Energy (DOE), Washington DC (United States). Office of Energy Efficiency and Renewable Energy; McIlroy, Andrew [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2011-03-03

This report is based on a SC/EERE Workshop to Identify Research Needs and Impacts in Predictive Simulation for Internal Combustion Engines (PreSICE), held March 3, 2011, to determine strategic focus areas that will accelerate innovation in engine design to meet national goals in transportation efficiency. The U.S. has reached a pivotal moment when pressures of energy security, climate change, and economic competitiveness converge. Oil prices remain volatile and have exceeded $100 per barrel twice in five years. At these prices, the U.S. spends $1 billion per day on imported oil to meet our energy demands. Because the transportation sector accounts for two-thirds of our petroleum use, energy security is deeply entangled with our transportation needs. At the same time, transportation produces one-quarter of the nation’s carbon dioxide output. Increasing the efficiency of internal combustion engines is a technologically proven and cost-effective approach to dramatically improving the fuel economy of the nation’s fleet of vehicles in the near- to mid-term, with the corresponding benefits of reducing our dependence on foreign oil and reducing carbon emissions. Because of their relatively low cost, high performance, and ability to utilize renewable fuels, internal combustion engines—including those in hybrid vehicles—will continue to be critical to our transportation infrastructure for decades. Achievable advances in engine technology can improve the fuel economy of automobiles by over 50% and trucks by over 30%. Achieving these goals will require the transportation sector to compress its product development cycle for cleaner, more efficient engine technologies by 50% while simultaneously exploring innovative design space. Concurrently, fuels will also be evolving, adding another layer of complexity and further highlighting the need for efficient product development cycles. Current design processes, using “build and test” prototype engineering, will not

Combustion stratification for naphtha from CI combustion to PPC

NARCIS (Netherlands)

Vallinayagam, R.; Vedharaj, S.; An, Y.; Dawood, A.; Izadi Najafabadi, M.; Somers, L.M.T.; Johansson, B.H.

2017-01-01

This study demonstrated the change in combustion homogeneity from conventional diesel combustion via partially premixed combustion towards HCCI. Experiments are performed in an optical diesel engine at a speed of 1200 rpm with diesel fuel. Single injection strategy is employed and the fuel is

Synthesis of functional materials in combustion reactions

Science.gov (United States)

Zhuravlev, V. D.; Bamburov, V. G.; Ermakova, L. V.; Lobachevskaya, N. I.

2015-12-01

The conditions for obtaining oxide compounds in combustion reactions of nitrates of metals with organic chelating-reducing agents such as amino acids, urea, and polyvinyl alcohol are reviewed. Changing the nature of internal fuels and the reducing agent-to-oxidizing agent ratio makes possible to modify the thermal regime of the process, fractal dimensionality, morphology, and dispersion of synthesized functional materials. This method can be used to synthesize simple and complex oxides, composites, and metal powders, as well as ceramics and coatings. The possibilities of synthesis in combustion reactions are illustrated by examples of αand γ-Al2O3, YSZ composites, uranium oxides, nickel powder, NiO and NiO: YSZ composite, TiO2, and manganites, cobaltites, and aluminates of rare earth elements.

Combustion instability control in the model of combustion chamber

International Nuclear Information System (INIS)

Akhmadullin, A N; Ahmethanov, E N; Iovleva, O V; Mitrofanov, G A

2013-01-01

An experimental study of the influence of external periodic perturbations on the instability of the combustion chamber in a pulsating combustion. As an external periodic disturbances were used sound waves emitted by the electrodynamics. The purpose of the study was to determine the possibility of using the method of external periodic perturbation to control the combustion instability. The study was conducted on a specially created model of the combustion chamber with a swirl burner in the frequency range from 100 to 1400 Hz. The study found that the method of external periodic perturbations may be used to control combustion instability. Depending on the frequency of the external periodic perturbation is observed as an increase and decrease in the amplitude of the oscillations in the combustion chamber. These effects are due to the mechanisms of synchronous and asynchronous action. External periodic disturbance generated in the path feeding the gaseous fuel, showing the high efficiency of the method of management in terms of energy costs. Power required to initiate periodic disturbances (50 W) is significantly smaller than the thermal capacity of the combustion chamber (100 kW)

Numerical and Experimental Study on the Combustion and Emission Characteristics of a Dimethyl Ether (DME Fueled Compression Ignition Engine Études numériques et expérimentales sur les caractéristiques de combustion et d’émissions d’un éther diméthylique (EDM- moteur à auto-allumage rempli de combustible

Directory of Open Access Journals (Sweden)

Kim Hyung Jun

2012-05-01

Full Text Available A numerical investigation was carried out to study on the combustion and emission characteristics of dimethyl ether (DME with wide ranges of injection timings in compression ignition engines. In order to simulate DME combustion processes, a KIVA-3V code coupled with a chemistry solver was used to solve the detailed chemical kinetics model of DME oxidation. In addition, the Kelvin-Helmholtz-Rayleigh-Taylor (KH-RT hybrid breakup model and Renormalization Group (RNG k-ε  models were applied to analyze the spray characteristics and turbulent flow, respectively. To predict the NOx formation during DME combustion, a reduced Gas Research Institute (GRI NO mechanism was used. From these results on the combustion and emission, the calculated results were compared with experimental ones for the same operating conditions. In the combustion characteristics, the calculated combustion pressure and heat release rates agreed well with experimental results. The levels of experimental NOx emissions was reduced as the start of the injection timing retarded, and also these trends appeared in calculated emission characteristics. Additionally, the calculated CO and HC emissions show an increasing trend as the start of the injection is retarded. Dans cette étude, nous considérons la simulation de la combustion du dimethyl ether (DME dans un moteur à allumage par compression. Les caractéristiques de la combustion ainsi que les émissions polluantes sont analysées sur une large gamme d’avance à l’injection. Afin de simuler le processus de combustion du EDM, le code KIVA-3V couplé à un solveur chimique a été utilisé pour résoudre la cinétique détaillée de l’oxydation du EDM. Le modèle de rupture de Kelvin-Helmholtz-Rayleigh- Taylor (KH-RT ainsi que le modèle de turbulence k-ε  RNG ont été appliqués pour analyser respectivement les caractéristiques du jet et l’écoulement turbulent. Pour prévoir la formation de NOx pendant la combustion

Multi-Point Combustion System: Final Report

Science.gov (United States)

Goeke, Jerry; Pack, Spencer; Zink, Gregory; Ryon, Jason

2014-01-01

A low-NOx emission combustor concept has been developed for NASA's Environmentally Responsible Aircraft (ERA) program to meet N+2 emissions goals for a 70,000 lb thrust engine application. These goals include 75 percent reduction of LTO NOx from CAEP6 standards without increasing CO, UHC, or smoke from that of current state of the art. An additional key factor in this work is to improve lean combustion stability over that of previous work performed on similar technology in the early 2000s. The purpose of this paper is to present the final report for the NASA contract. This work included the design, analysis, and test of a multi-point combustion system. All design work was based on the results of Computational Fluid Dynamics modeling with the end results tested on a medium pressure combustion rig at the UC and a medium pressure combustion rig at GRC. The theories behind the designs, results of analysis, and experimental test data will be discussed in this report. The combustion system consists of five radially staged rows of injectors, where ten small scale injectors are used in place of a single traditional nozzle. Major accomplishments of the current work include the design of a Multipoint Lean Direct Injection (MLDI) array and associated air blast and pilot fuel injectors, which is expected to meet or exceed the goal of a 75 percent reduction in LTO NOx from CAEP6 standards. This design incorporates a reduced number of injectors over previous multipoint designs, simplified and lightweight components, and a very compact combustor section. Additional outcomes of the program are validation that the design of these combustion systems can be aided by the use of Computational Fluid Dynamics to predict and reduce emissions. Furthermore, the staging of fuel through the individually controlled radially staged injector rows successfully demonstrated improved low power operability as well as improvements in emissions over previous multipoint designs. Additional comparison

Reaction and diffusion in turbulent combustion

Energy Technology Data Exchange (ETDEWEB)

Pope, S.B. [Mechanical and Aerospace Engineering, Ithaca, NY (United States)

1993-12-01

The motivation for this project is the need to obtain a better quantitative understanding of the technologically-important phenomenon of turbulent combustion. In nearly all applications in which fuel is burned-for example, fossil-fuel power plants, furnaces, gas-turbines and internal-combustion engines-the combustion takes place in a turbulent flow. Designers continually demand more quantitative information about this phenomenon-in the form of turbulent combustion models-so that they can design equipment with increased efficiency and decreased environmental impact. For some time the PI has been developing a class of turbulent combustion models known as PDF methods. These methods have the important virtue that both convection and reaction can be treated without turbulence-modelling assumptions. However, a mixing model is required to account for the effects of molecular diffusion. Currently, the available mixing models are known to have some significant defects. The major motivation of the project is to seek a better understanding of molecular diffusion in turbulent reactive flows, and hence to develop a better mixing model.

Rotary combustion device

NARCIS (Netherlands)

2008-01-01

Rotary combustion device (1) with rotary combustion chamber (4). Specific measures are taken to provide ignition of a combustible mixture. It is proposed that a hollow tube be provided coaxially with the axis of rotation (6), so that a small part of the mixture is guided into the combustion chamber.

Combustive management of oil spills

International Nuclear Information System (INIS)

1992-01-01

Extensive experiments with in situ incineration were performed on a desert site at the University of Arizona with very striking results. The largest incinerator, 6 feet in diameter with a 30 foot chimney, developed combustion temperatures of 3000, F, and attendant soot production approximately 1000 times less than that produced by conventional in situ burning. This soot production, in fact, is approximately 30 times less than current allowable EPA standards for incinerators and internal combustion engines. Furthermore, as a consequence of the high temperature combustion, the bum rate was established at a very high 3400 gallons per hour for this particular 6 foot diameter structure. The rudimentary design studies we have carried out relative to a seagoing 8 foot diameter incinerator have predicted that a continuous burn rate of 7000 gallons per hour is realistic. This structure was taken as a basis for operational design because it is compatible with C130 flyability, and will be inexpensive enough ($120,000 per copy) to be stored at those seaside depots throughout the US coast line in which the requisite ancillary equipments (booms, service tugs, etc.) are already deployed. The LOX experiments verified our expectations with respect to combustion of debris and various highly weathered or emulsified oils. We have concluded, however, that the use of liquid oxygen in actual beach clean up is not promising because the very high temperatures associated with this combustion are almost certain to produce environmentally deleterious effects on the beach surface and its immediately sublying structures. However, the use of liquid oxygen augmentation for shore based and flyable incinerators may still play an important role in handing the problem of accumulated debris

Solid waste combustion for alpha waste incineration

International Nuclear Information System (INIS)

Orloff, D.I.

1981-02-01

Radioactive waste incinerator development at the Savannah River Laboratory has been augmented by fundamental combustion studies at the University of South Carolina. The objective was to measure and model pyrolysis and combustion rates of typical Savannah River Plant waste materials as a function of incinerator operating conditions. The analytical models developed in this work have been incorporated into a waste burning transient code. The code predicts maximum air requirement and heat energy release as a function of waste type, package size, combustion chamber size, and temperature. Historically, relationships have been determined by direct experiments that did not allow an engineering basis for predicting combustion rates in untested incinerators. The computed combustion rates and burning times agree with measured values in the Savannah River Laboratory pilot (1 lb/hr) and full-scale (12 lb/hr) alpha incinerators for a wide variety of typical waste materials

Combustion performance evaluation of air staging of palm oil blends.

Science.gov (United States)

Mohd Jaafar, Mohammad Nazri; Eldrainy, Yehia A; Mat Ali, Muhammad Faiser; Wan Omar, W Z; Mohd Hizam, Mohd Faizi Arif

2012-02-21

The problems of global warming and the unstable price of petroleum oils have led to a race to develop environmentally friendly biofuels, such as palm oil or ethanol derived from corn and sugar cane. Biofuels are a potential replacement for fossil fuel, since they are renewable and environmentally friendly. This paper evaluates the combustion performance and emission characteristics of Refined, Bleached, and Deodorized Palm Oil (RBDPO)/diesel blends B5, B10, B15, B20, and B25 by volume, using an industrial oil burner with and without secondary air. Wall temperature profiles along the combustion chamber axis were measured using a series of thermocouples fitted axially on the combustion chamber wall, and emissions released were measured using a gas analyzer. The results show that RBDPO blend B25 produced the maximum emission reduction of 56.9% of CO, 74.7% of NOx, 68.5% of SO(2), and 77.5% of UHC compared to petroleum diesel, while air staging (secondary air) in most cases reduces the emissions further. However, increasing concentrations of RBDPO in the blends also reduced the energy released from the combustion. The maximum wall temperature reduction was 62.7% for B25 at the exit of the combustion chamber.

Chemical-looping combustion - status of development

Energy Technology Data Exchange (ETDEWEB)

Lyngfelt, Anders; Johansson, Marcus; Mattisson, Tobias

2008-05-15

Chemical-looping combustion (CLC) is a combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The technique involves the use of a metal oxide as an oxygen carrier which transfers oxygen from combustion air to the fuel, and hence a direct contact between air and fuel is avoided. Two inter-connected fluidized beds, a fuel reactor and an air reactor, are used in the process. In the fuel reactor, the metal oxide is reduced by the reaction with the fuel and in the air reactor; the reduced metal oxide is oxidized with air. The outlet gas from the fuel reactor consists of CO{sub 2} and H{sub 2}O, and almost pure stream of CO{sub 2} is obtained when water is condensed. Considerable research has been conducted on CLC in the last years with respect to oxygen carrier development, reactor design, system efficiencies and prototype testing. In 2002 the process was a paper concept, albeit with some important but limited laboratory work on oxygen carrier particles. Today more than 600 materials have been tested and the technique has been successfully demonstrated in chemical-looping combustors in the size range 0.3 - 50 kW, using different types of oxygen carriers based on the metals Ni, Co, Fe, Cu and Mn. The total time of operational experience is more than a thousand hours. From these tests it can be established that almost complete conversion of the fuel can be obtained and 100% CO{sub 2} capture is possible. Most work so far has been focused on gaseous fuels, but the direct application to solid fuels is also being studied. Moreover, the same principle of oxygen transfer is used in chemical-looping reforming (CLR), which involves technologies to produce hydrogen with inherent CO{sub 2} capture. This paper presents an overview of the research performed on CLC and CLR highlights the current status of the technology

Homogeneous charge combustion of aqueous ethanol

Science.gov (United States)

2001-02-01

The goal of this research is to reduce nitrous oxide (NOx) and carbon monoxide (CO) emissions and to retain the performance characteristics of a diesel engine by modifying the in-cylinder combustion process. To accomplish this goal, a direct-injected...

Domestic wood combustion - practices, attitudes and regulation; Braendefyring i hjemmet - praksis, holdninger og regulering

Energy Technology Data Exchange (ETDEWEB)

Kjerulf Petersen, L.; Martinsen, L.

2008-06-15

Use of wood burning stoves for domestic heating is the subject of this report which is based on results from an interview study and a survey. The report is concerned with why people have and use stoves, how they use them and which functions the stoves serve in their homes. Of equal interest are the attitudes of users as well as non-users to environmental consequences of wood combustion and to different forms of regulation. There can be several reasons for having and using a wood burning stove for domestic heating. The main reason seems to be the sense of homeliness and cosiness and calm that it gives to the home, and the second most important reason is the economic advantages it implies in terms of reducing heating expenses. Enjoyment of the particular quality of warmth that stoves can provide and a desire to obtain higher indoor temperature are important additional motivations, while self determination in household heating supply runs through all these motivations as an underlying incentive. Potential environmental problems from domestic wood combustion depend on the properties of the stove, on the quality of the fuel, and on air intake and other aspects of the combustion process; and practices of stove users play an important role in all this. For stove users there are both sensuous experiences and social norms - e.g. regarding use of damp wood or any other type of fuel than pure wood - that support an environmentally appropriate practice. However, this study shows that even though users are inclined to follow environmentally sound practices for wood combustion other considerations in everyday life may be more important; considerations regarding what kind of effort one has time and energy for, what is practically feasible, what one can be bothered to consider, and what level of thermal comfort one wants. Almost half of the respondents, users and non-users alike, are to some extend - from slightly to extremely - bothered by smoke from wood combustion, and around

Improvement of a combustion model in MELCOR code

International Nuclear Information System (INIS)

Ogino, Masao; Hashimoto, Takashi

1999-01-01

NUPEC has been improving a hydrogen combustion model in MELCOR code for severe accident analysis. In the proposed combustion model, the flame velocity in a node was predicted using five different flame front shapes of fireball, prism, bubble, spherical jet, and plane jet. For validation of the proposed model, the results of the Battelle multi-compartment hydrogen combustion test were used. The selected test cases for the study were Hx-6, 13, 14, 20 and Ix-2 which had two, three or four compartments under homogeneous hydrogen concentration of 5 to 10 vol%. The proposed model could predict well the combustion behavior in multi-compartment containment geometry on the whole. MELCOR code, incorporating the present combustion model, can simulate combustion behavior during severe accident with acceptable computing time and some degree of accuracy. The applicability study of the improved MELCOR code to the actual reactor plants will be further continued. (author)

Combustion instability modeling and analysis

Energy Technology Data Exchange (ETDEWEB)

Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States)] [and others

1995-10-01

It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. Clearly, the key to successful gas turbine development is based on understanding the effects of geometry and operating conditions on combustion instability, emissions (including UHC, CO and NO{sub x}) and performance. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors.

The John Zink Hamworthy combustion handbook, v.1 fundamentals

CERN Document Server

Baukal, Charles E

2012-01-01

Despite the length of time it has been around, its importance, and vast amounts of research, combustion is still far from being completely understood. Environmental, cost, and fuel consumption issues add further complexity, particularly in the process and power generation industries. Dedicated to advancing the art and science of industrial combustion, The John Zink Hamworthy Combustion Handbook, Second Edition: Volume One - Fundamentals gives you a strong understanding of the basic concepts and theory. Under the leadership of Charles E. Baukal, Jr., top combustion engineers and technologists f

Engine combustion control at low loads via fuel reactivity stratification

Science.gov (United States)

Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

2014-10-07

A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

Engine combustion control at low loads via fuel reactivity stratification

Energy Technology Data Exchange (ETDEWEB)

Reitz, Rolf Deneys; Hanson, Reed M.; Splitter, Derek A.; Kokjohn, Sage

2017-12-26

A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

Effects of Catalysts on Emissions of Pollutants from Combustion Processes of Liquid Fuels

Directory of Open Access Journals (Sweden)

Bok Agnieszka

2014-12-01

Full Text Available The dynamic growth of the use of non-renewable fuels for energy purposes results in demand for catalysts to improve their combustion process. The paper describes catalysts used mainly in the processes of combustion of motor fuels and fuel oils. These catalysts make it possible to raise the efficiency of oxidation processes simultanously reducing the emission of pollutants. The key to success is the selection of catalyst compounds that will reduce harmful emissions of combustion products into the atmosphere. Catalysts are introduced into the combustion zone in form of solutions miscible with fuel or with air supplied to the combustion process. The following compounds soluble in fuel are inclused in the composition of the described catalysts: organometallic complexes, manganese compounds, salts originated from organic acids, ferrocen and its derivatives and sodium chloride and magnesium chloride responsible for burning the soot (chlorides. The priority is to minimize emissions of volatile organic compounds, nitrogen oxides, sulphur oxides, and carbon monoxide, as well as particulate matter.

Synthesis of Li2MO3 (M = Ti or Zr) by the combustion method

International Nuclear Information System (INIS)

Cruza, D.; Bulbuliana, S.; Cruza, D.; Pfeifferc, H.

2006-01-01

The advantages and disadvantages of the combustion method to prepare Li 2 TiO 3 and Li 2 ZrO 3 ceramics were studied. Firstly, the ceramic powders were prepared by the combustion process using LiOH, MO 2 (where M=Ti or Zr) and urea in different molar ratios (from 2:1:3 to 3:1:3) at different temperatures for 5 minutes. Li 2 TiO 3 and Li 2 ZrO 3 were also obtained by the solid-state method, and the results were compared with those obtained by the combustion process. The powders were characterized by X-ray diffraction and scanning electron microscopy. It was found that the combustion process reduces the synthesis time of Li 2 TiO 3 (1 minute at 750 C), but it does not have any advantage on producing Li 2 ZrO 3 , due to thermodynamic factors. On the other hand, the combustion process produces carbon contaminants in the solids. It was necessary to add excess of lithium hydroxide, in order to compensate the quantity of Li sublimated during the production of the ceramics. Finally, it seems that both reactions follow the same mechanism, which is determined by the lithium diffusion into the metal oxides. (authors)

Experimental Investigation into the Combustion Characteristics of Propane Hydrates in Porous Media

Directory of Open Access Journals (Sweden)

Xiang-Ru Chen

2015-02-01

Full Text Available The combustion characteristics of both pure propane hydrates and the mixtures of hydrates and quartz sands were investigated by combustion experiments. The flame propagation, flame appearance, burning time and temperature in different hydrate layers were studied. For pure propane hydrate combustion, the initial flame falls in the “premixed” category. The flame propagates very rapidly, mainly as a result of burnt gas expansion. The flame finally self-extinguishes with some proportion of hydrates remaining unburned. For the hydrate-sand mixture combustion, the flame takes the form of many tiny discontinuous flames appearing and disappearing at different locations. The burn lasts for a much shorter amount of time than pure hydrate combustion. High porosity and high hydrate saturation is beneficial to the combustion. The hydrate combustion is the combustion of propane gas resulting from the dissociation of the hydrates. In both combustion test scenarios, the hydrate-dissociated water plays a key role in the fire extinction, because it is the main resistance that restrains the heat transfer from the flame to the hydrates and that prevents the hydrate-dissociated gas from releasing into the combustion zone.

Fluidized-bed calciner with combustion nozzle and shroud

International Nuclear Information System (INIS)

Wielang, J.A.; Palmer, W.B.; Kerr, W.B.

1977-01-01

A nozzle employed as a burner within a fluidized bed is coaxially enclosed within a tubular shroud that extends beyond the nozzle length into the fluidized bed. The open-ended shroud portion beyond the nozzle end provides an antechamber for mixture and combustion of atomized fuel with an oxygen-containing gas. The arrangement provides improved combustion efficiency and excludes bed particles from the high-velocity, high-temperature portions of the flame to reduce particle attrition. 4 claims, 2 figures

Numerical analysis of the thermo-fluid-dynamic field in the combustion chamber of an incinerator plant

International Nuclear Information System (INIS)

Costa, M.; Dell'Isola, M.; Massarotti, N.

2009-01-01

As the interest for energy recovery from waste incineration has increased over the years, concern for the impact such processes have on the environment has also grown. To reduce such an impact, the legislation enforced in Italy and Europe imposes important restrictions on the temperature of the exhausts in the combustion chamber, which must be kept above certain values depending on the type of waste that is being incinerated, for a given period of time. Such conditions can be rather difficult and certainly very expensive to monitor with acceptable accuracy. In this work, a numerical approach is presented for modelling waste combustion in a full scale incineration plant. Both solid and gas phase reactions are considered. Various modes of heat and mass transfer between the waste bed, the air and the combustion products are taken into account, as well as radiation from the combustion chamber walls and the combustion products. The temperature distribution in the combustion chamber is obtained considering either forced or mixed convection. It is therefore shown that neglecting buoyancy effects may lead to appreciable errors. Verification of the code performance is based on comparison with the results of an experimental campaign at a full scale plant in Italy.

Study on Characteristics of Co-firing Ammonia/Methane Fuels under Oxygen Enriched Combustion Conditions

Science.gov (United States)

Xiao, Hua; Wang, Zhaolin; Valera-Medina, Agustin; Bowen, Philip J.

2018-06-01

Having a background of utilising ammonia as an alternative fuel for power generation, exploring the feasibility of co-firing ammonia with methane is proposed to use ammonia to substitute conventional natural gas. However, improvement of the combustion of such fuels can be achieved using conditions that enable an increase of oxygenation, thus fomenting the combustion process of a slower reactive molecule as ammonia. Therefore, the present study looks at oxygen enriched combustion technologies, a proposed concept to improve the performance of ammonia/methane combustion. To investigate the characteristics of ammonia/methane combustion under oxygen enriched conditions, adiabatic burning velocity and burner stabilized laminar flame emissions were studied. Simulation results show that the oxygen enriched method can help to significantly enhance the propagation of ammonia/methane combustion without changing the emission level, which would be quite promising for the design of systems using this fuel for practical applications. Furthermore, to produce low computational-cost flame chemistry for detailed numerical analyses for future combustion studies, three reduced combustion mechanisms of the well-known Konnov's mechanism were compared in ammonia/methane flame simulations under practical gas turbine combustor conditions. Results show that the reduced reaction mechanisms can provide good results for further analyses of oxygen enriched combustion of ammonia/methane. The results obtained in this study also allow gas turbine designers and modellers to choose the most suitable mechanism for further combustion studies and development.

Combustion synthesis and structural characterization of Li–Ti mixed

Indian Academy of Sciences (India)

Combustion synthesis and structural characterization of Li–Ti mixed nanoferrites ... were prepared by combustion method at lower temperatures compared to the ... first time at low temperatures, using PEG which acts as a new fuel and oxidant.

Modifying intake flow to increase EGR tolerance in an Internal Combustion Engine

Science.gov (United States)

Rubio, Daniel; Drabo, Mebougna; Puzinauskas, Paul

2010-11-01

The worldwide effort to reduce vehicle emissions and increase fuel efficiencies has continuously intensified as the need to improve air quality and reduce fuel consumption becomes more acute. Exhaust gas recirculation (EGR) is a method that has long been employed to reduce combustion temperatures and therefore reduce thermal NOx formation and accommodate higher compression ratios and more optimum combustion phasing for improved efficiency. Generally the effective EGR level as a percent of trapped charge is limited by its affect on combustion stability. Inducing flow structures such as swirl, squish and tumble in the trapped charge have proven to extend this EGR limit in homogeneous charge spark-ignited engines at part load, but this enhancement has not been significantly studied at full loads in such engines. This research explored modifying the intake flow into an engine to create tumble and evaluate its effect at high loads in such engines. This exploration included characterizing the flow on a steady flow bench and quantifying the results using engine dynamometer tests.

Determination of combustion parameters using engine crankshaft speed

Science.gov (United States)

Taglialatela, F.; Lavorgna, M.; Mancaruso, E.; Vaglieco, B. M.

2013-07-01

Electronic engine controls based on real time diagnosis of combustion process can significantly help in complying with the stricter and stricter regulations on pollutants emissions and fuel consumption. The most important parameter for the evaluation of combustion quality in internal combustion engines is the in-cylinder pressure, but its direct measurement is very expensive and involves an intrusive approach to the cylinder. Previous researches demonstrated the direct relationship existing between in-cylinder pressure and engine crankshaft speed and several authors tried to reconstruct the pressure cycle on the basis of the engine speed signal. In this paper we propose the use of a Multi-Layer Perceptron neural network to model the relationship between the engine crankshaft speed and some parameters derived from the in-cylinder pressure cycle. This allows to have a non-intrusive estimation of cylinder pressure and a real time evaluation of combustion quality. The structure of the model and the training procedure is outlined in the paper. A possible combustion controller using the information extracted from the crankshaft speed information is also proposed. The application of the neural network model is demonstrated on a single-cylinder spark ignition engine tested in a wide range of speeds and loads. Results confirm that a good estimation of some combustion pressure parameters can be obtained by means of a suitable processing of crankshaft speed signal.

Investigation of diesel engine for low exhaust emissions with different combustion chambers

Directory of Open Access Journals (Sweden)

Ghodke Pundlik R.

2015-01-01

Full Text Available Upcoming stringent Euro-6 emission regulations for passenger vehicle better fuel economy, low cost are the key challenges for engine development. In this paper, 2.2L, multi cylinder diesel engine have been tested for four different piston bowls designed for compression ratio of CR 15.5 to improve in cylinder performance and reduce emissions. These combustion chambers were verified in CFD at two full load points. 14 mode points have been derived using vehicle model run in AVL CRUISE software as per NEDC cycle based on time weightage factor. Base engine with compression ratio CR16.5 for full load performance and 14-mode points on Engine test bench was taken as reference for comparison. The bowl with flat face on bottom corner has shown reduction 25% and 12 % NOx emissions at 1500 and 3750 rpm full load points at same level of Soot emissions. Three piston bowls were tested for full load performance and 14 mode points on engine test bench and combustion chamber ‘C’ has shown improvement in thermal efficiency by 0.8%. Combinations of cooled EGR and combustion chamber ‘C’ with geometrical changes in engine have reduced exhaust NOx, soot and CO emissions by 22%, 9 % and 64 % as compared to base engine at 14 mode points on engine test bench.

Some Factors Affecting Combustion in an Internal-Combustion Engine

Science.gov (United States)

Rothrock, A M; Cohn, Mildred

1936-01-01

An investigation of the combustion of gasoline, safety, and diesel fuels was made in the NACA combustion apparatus under conditions of temperature that permitted ignition by spark with direct fuel injection, in spite of the compression ratio of 12.7 employed. The influence of such variables as injection advance angle, jacket temperature, engine speed, and spark position was studied. The most pronounced effect was that an increase in the injection advance angle (beyond a certain minimum value) caused a decrease in the extent and rate of combustion. In almost all cases combustion improved with increased temperature. The results show that at low air temperatures the rates of combustion vary with the volatility of the fuel, but that at high temperatures this relationship does not exist and the rates depend to a greater extent on the chemical nature of the fuel.

Cold flow simulation of an internal combustion engine with vertical valves using layering approach

Science.gov (United States)

Martinas, G.; Cupsa, O. S.; Stan, L. C.; Arsenie, A.

2015-11-01

Complying with emission requirements and fuel consumption efficiency are the points which drive any development of internal combustion engine. Refinement of the process of combustion and mixture formation, together with in-cylinder flow refinement, is a requirement, valves and piston bowl and intake exhaust port design optimization is essential. In order to reduce the time for design optimization cycle it is used Computational Fluid Dynamics (CFD). Being time consuming and highly costly caring out of experiment using flow bench testing this methods start to become less utilized. Air motion inside the intake manifold is one of the important factors, which govern the engine performance and emission of multi-cylinder diesel engines. Any cold flow study on IC is targeting the process of identifying and improving the fluid flow inside the ports and the combustion chamber. This is only the base for an optimization process targeting to increase the volume of air accessing the combustion space and to increase the turbulence of the air at the end of the compression stage. One of the first conclusions will be that the valve diameter is a fine tradeoff between the need for a bigger diameter involving a greater mass of air filling the cylinder, and the need of a smaller diameter in order to reduce the blind zone. Here there is room for optimization studies. The relative pressure indicates a suction effect coming from the moving piston. The more the shape of the inlet port is smoother and the diameter of the piston is bigger, the aerodynamic resistance of the geometry will be smaller so that the difference of inlet port pressure and the pressure near to piston face will be smaller. Here again there is enough room for more optimization studies.

Development of simultaneous hyperspectral coherent Raman imaging for advancing reduced emission combustion technology

NARCIS (Netherlands)

Bohlin, G.A.

2016-01-01

Overall aim and key objectives Advances in optical imaging techniques over the past decades have revolutionized our ability to study chemically reactive flows encountered in air-breathing combustion systems. Emerging technology for unravelling clean- and efficient

Combustion Gases And Heat Release Analysis During Flame And Flameless Combustion Of Wood Pellets

Directory of Open Access Journals (Sweden)

Horváth Jozef

2015-06-01

Full Text Available With the growing prices of fossil fuels, alternative fuels produced of biomass come to the fore. They are made of waste materials derived from the processing of wood and wood materials. The main objective of this study was to analyse the fire-technical characteristics of wood pellets. The study analysed three dust samples acquired from wood pellets made of various types of wood biomass. Wood pellet dust is produced when manipulating with pellets. During this process a potentially hazardous situations may occur. Biomass is chemically composed mostly of hemicellulose, cellulose and lignin. During straining of the biomass by heat flux, combustion initiation occurs. Also, there was a change in the composition of material throughout combustion gases production, and the amount of heat generated by a flame or flameless combustion. Measurement of fire characteristics was conducted according to ISO 5660-1 standard using a cone calorimeter. Two samples of wood pellet dust were tested under the heat flux of 35 kW.m−2 and 50 kW.m−2. The process of combustion, the time to ignition, the carbon monoxide concentration and the amount of released heat were observed.

Method and device for diagnosing and controlling combustion instabilities in internal combustion engines operating in or transitioning to homogeneous charge combustion ignition mode

Science.gov (United States)

Wagner, Robert M [Knoxville, TN; Daw, Charles S [Knoxville, TN; Green, Johney B [Knoxville, TN; Edwards, Kevin D [Knoxville, TN

2008-10-07

This invention is a method of achieving stable, optimal mixtures of HCCI and SI in practical gasoline internal combustion engines comprising the steps of: characterizing the combustion process based on combustion process measurements, determining the ratio of conventional and HCCI combustion, determining the trajectory (sequence) of states for consecutive combustion processes, and determining subsequent combustion process modifications using said information to steer the engine combustion toward desired behavior.

ERA-Net Evaluation of technology status for small-scale combustion of pellets from new ash rich biomasses - combustion tests in residential burners

Energy Technology Data Exchange (ETDEWEB)

Roennbaeck, Marie; Johansson, Mathias; Frida Claesson

2008-07-01

In this project, pellets with higher ash content compared to the wood pellets used today on the Swedish market were tested in three domestic-scale burners. The tests were carried out based on EN 303-5. In the flue gas, combustion parameters as carbon monoxide, carbon dioxide, oxygen and hydro carbons were measured, and also more fuel specific parameters such as nitrogen oxides, sulphur dioxide, hydrogen chloride, total dust and particle mass- and number concentration. The dust (fly ash) and bottom ash were characterized chemically. The implications of high ash content on combustion performance are discussed in the report. Altogether five pellets with 8 mm diameter were tested: oilseed straw pellet, reed canary grass pellet (RCG), barley straw pellet, bark pellet and wood pellet. All fuels were dry ranging from 6.5-12 % moisture. The ash content varied from 0.3 weight-% dm in wood to 7.9 % in RCG. Barley straw has a noticeable low ash melting temperature, < 980 deg C, and could not be combusted in any of the burners. The nitrogen content varied nine times and sulphur more than 10 times. The chlorine content was very low in wood and bark and more than 20 times higher in oilseed and barley. The composition of inorganic species in the fuel ash was dominated by calcium, potassium and silica in wood, bark and oilseed pellet, while RCG and barley straw were dominated by silica. The three burners used were commercial and known to fulfil high quality requirements. Burner A is a pellet burner where fuel is supplied on top of the grate with no mechanical mean for moving bottom ash on the grate during combustion. Bottom ash is blown away, and any slag remaining on the grate is removed with a scrape before ignition. Burner B is an upward burning pellet burner where fuel and ash is pushed upwards and the glow bed is exposed to the surrounding combustion department. Burner C is a forward burning grain burner that pushes fuel and ash forwards, inside a cylinder. From the

System analysis of environmental impacts of the combustion of waste paper

International Nuclear Information System (INIS)

Palanterae, R.

1996-01-01

Combustion alternatives of different waste paper grades that are unsuitable or difficult to recycle were studied. Environmental impacts of alternative methods of waste paper treatment - combustion, dump disposal and use for fibre raw material - were studied with the aid of system analysis. Use of waste paper for energy production is usually recommended when there is oversupply of waste paper or it is unsuitable for recycled pulp. On the basis of certain studies it has also been suggested that it would be most profitable to use all waste paper as fuel. Refused tight paper rolls, baled brown paper and a mixture of adhesive paper and crushed building waste wood were chosen for waste paper in the combustion tests. The tests were run in the fluidised-bed combustion boiler of Maentaen Energia Oy. The mass flow of paper was about 3 t/h and its proportion of the fuel efficiency on average 20%. Prior to each paper combustion test, a blank trial was run with pure peat. The combustion tests indicated that flue gas emissions are not reduced by using paper instead of peat for energy production, but their composition is changed slightly. When the environmental effects of the use of waste paper for energy were compared with those of landfill dumping, the most significant difference was a reduction in greenhouse gases. The amount of methane emitted from the landfill will reduce. Differences in other emissions, e.g., in acidification due to SO 2 and NO 2 emissions, were rather small. The amount of solid waste was significantly lower in the combustion alternative. (38 refs.)

Fundamental combustion characteristics of lean hydrogen mixtures; Suiso kihaku kongoki no kisoteki nensho tokusei

Energy Technology Data Exchange (ETDEWEB)

Barat, D; Kido, H; Nakahara, M; Hashimoto, J [Kyushu University, Fukuoka (Japan)

1997-10-01

One of the excellent combustion characteristics of hydrogen-air mixture is that its emission is free of CO2, but the problem of NOx remains, mainly caused by the high combustion temperature. Using leaner mixture and carrying out EGR are supposed to be effective methods to reduce NOx. In this study, to examine the effectiveness of the two methods, fundamental combustion characteristics of nitrogen added lean hydrogen mixtures were investigated by chemical equilibrium calculations and measurements of turbulent combustion characteristics. It is suggested that nitrogen added mixtures can achieve lower NOx combustion than lean mixtures, taking the combustion efficiency into consideration. 7 refs., 7 figs., 1 tab.

Modeling of Plasma Assisted Combustion

Science.gov (United States)

Akashi, Haruaki

2012-10-01

Recently, many experimental study of plasma-assisted combustion has been done. However, numerous complex reactions in combustion of hydrocarbons are preventing from theoritical study for clarifying inside the plasma-assisted combustion, and the effect of plasma-assist is still not understood. Shinohara and Sasaki [1,2] have reported that the shortening of flame length by irradiating microwave without increase of gas temperature. And they also reported that the same phenomena would occur when applying dielectric barrier discharges to the flame using simple hydrocarbon, methane. It is suggested that these phenomena may result by the electron heating. To clarify this phenomena, electron behavior under microwave and DBD was examined. For the first step of DBD plasma-assisted combustion simulation, electron Monte Carlo simulation in methane, oxygen and argon mixture gas(0.05:0.14:0.81) [2] has been done. Electron swarm parameters are sampled and electron energy distribution function (EEDF)s are also determined. In the combustion, gas temperature is higher(>1700K), so reduced electric field E/N becomes relatively high(>10V/cm/Torr). The electrons are accelerated to around 14 eV. This result agree with the optical emission from argon obtained by the experiment of reference [2]. Dissociation frequency of methane and oxygens are obtained in high. This might be one of the effect of plasma-assist. And it is suggested that the electrons should be high enough to dissociate methane, but plasma is not needed.[4pt] [1] K. Shinohara et al, J. Phys. D:Appl. Phys., 42, 182008 (1-7) (2009).[0pt] [2] K. Sasaki, 64th Annual Gaseous Electronic Conference, 56, 15 CT3.00001(2011).

Homogeneous Charge Compression Ignition Combustion of Dimethyl Ether

DEFF Research Database (Denmark)

Pedersen, Troels Dyhr

This thesis is based on experimental and numerical studies on the use of dimethyl ether (DME) in the homogeneous charge compression ignition (HCCI) combustion process. The first paper in this thesis was published in 2007 and describes HCCI combustion of pure DME in a small diesel engine. The tests...... were designed to investigate the effect of engine speed, compression ratio and equivalence ratio on the combustion timing and the engine performance. It was found that the required compression ratio depended on the equivalence ratio used. A lower equivalence ratio requires a higher compression ratio...... before the fuel is burned completely, due to lower in-cylinder temperatures and lower reaction rates. The study provided some insight in the importance of operating at the correct compression ratio, as well as the operational limitations and emission characteristics of HCCI combustion. HCCI combustion...

Numerical simulation of turbulent combustion: Scientific challenges

Science.gov (United States)

Ren, ZhuYin; Lu, Zhen; Hou, LingYun; Lu, LiuYan

2014-08-01

Predictive simulation of engine combustion is key to understanding the underlying complicated physicochemical processes, improving engine performance, and reducing pollutant emissions. Critical issues as turbulence modeling, turbulence-chemistry interaction, and accommodation of detailed chemical kinetics in complex flows remain challenging and essential for high-fidelity combustion simulation. This paper reviews the current status of the state-of-the-art large eddy simulation (LES)/prob-ability density function (PDF)/detailed chemistry approach that can address the three challenging modelling issues. PDF as a subgrid model for LES is formulated and the hybrid mesh-particle method for LES/PDF simulations is described. Then the development need in micro-mixing models for the PDF simulations of turbulent premixed combustion is identified. Finally the different acceleration methods for detailed chemistry are reviewed and a combined strategy is proposed for further development.

The Diesel Combustion Collaboratory: Combustion Researchers Collaborating over the Internet

Energy Technology Data Exchange (ETDEWEB)

C. M. Pancerella; L. A. Rahn; C. Yang

2000-02-01

The Diesel Combustion Collaborator (DCC) is a pilot project to develop and deploy collaborative technologies to combustion researchers distributed throughout the DOE national laboratories, academia, and industry. The result is a problem-solving environment for combustion research. Researchers collaborate over the Internet using DCC tools, which include: a distributed execution management system for running combustion models on widely distributed computers, including supercomputers; web-accessible data archiving capabilities for sharing graphical experimental or modeling data; electronic notebooks and shared workspaces for facilitating collaboration; visualization of combustion data; and video-conferencing and data-conferencing among researchers at remote sites. Security is a key aspect of the collaborative tools. In many cases, the authors have integrated these tools to allow data, including large combustion data sets, to flow seamlessly, for example, from modeling tools to data archives. In this paper the authors describe the work of a larger collaborative effort to design, implement and deploy the DCC.

Combustion/particle sizing experiments at the Naval Postgraduate School Combustion Research Laboratory

Science.gov (United States)

Powers, John; Netzer, David

1987-01-01

Particle behavior in combustion processes is an active research area at NPS. Currently, four research efforts are being conducted: (1) There is a long standing need to better understand the soot production and combustion processes in gas turbine combustors, both from a concern for improved engine life and to minimize exhaust particulates. Soot emissions are strongly effected by fuel composition and additives; (2) A more recent need for particle sizing/behavior measurements is in the combustor of a solid fuel ramjet which uses a metallized fuel. High speed motion pictures are being used to study rather large burning particles; (3) In solid propellant rocket motors, metals are used to improve specific impulse and/or to provide damping for combustion pressure oscillations. Particle sizing experiments are being conducted using diode arrays to measure the light intensity as a function of scattering angle; (4) Once a good quality hologram is attained, a need exists for obtaining the particle distributions from hologram in a short period of time. A Quantimet 720 Image Analyzer is being used to reconstruct images.

FY1996 annual report on the advanced combustion science in microgravity field

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-03-01

Research was implemented continuously from the previous year on combustion equipment enabling advanced combustion technologies, by studying combustion in a microgravity field, for the purpose of preventing environmental pollution caused by diversification of energy sources and exhaust gasses. In joint studies with NASA, the themes of the previous year were continued, for which tests were conducted 37 times using Japanese drop test equipment and 131 times using NASA's. The evaluation and analysis of the experiments and test data by the microgravity test equipment were, in addition to the themes of the previous year, such that micro observation for ignition/combustion mechanism of fuel spray droplets was made, as well as studies on fuel droplets combustion by a laser diagnostic device, concerning combustion of fuel droplets and vaporization process, that flame spread on solid substances was researched in relation to combustion characteristics of high density fuels, and that mixed gas combustion on a solid surface was studied in connection with the research on flammability limits. Furthermore, a study on combustion technology for gas turbines was added for the purpose of studying an advanced combustor. (NEDO)

Analysis of an Internal Combustion Engine Using Porous Foams for Thermal Energy Recovery

Directory of Open Access Journals (Sweden)

Mehdi Ali Ehyaei

2016-03-01

Full Text Available Homogeneous and complete combustion in internal combustion engines is advantageous. The use of a porous foam in the exhaust gas in an engine cylinder for heat recovery is examined here with the aim of reducing engine emissions. The internal combustion engine with a porous core regenerator is modeled using SOPHT software, which solved the differential equations for the thermal circuit in the engine. The engine thermal efficiency is observed to increase from 43% to 53% when the porous core regenerator is applied. Further, raising the compression ratio causes the peak pressure and thermal efficiency to increase, e.g., increasing the compression ratio from 13 to 15 causes the thermal efficiency and output work to increase from 53% to 55% and from 4.86 to 4.93 kJ, respectively. The regenerator can also be used as a catalytic converter for fine particles and some other emissions. The regenerator oxidizes unburned hydrocarbons. Meanwhile, heat recovered from the exhaust gases can reduce fuel consumption, further reducing pollutant emissions from the internal combustion engine.

Gaseous emissions during concurrent combustion of biomass and non-recyclable municipal solid waste.

Science.gov (United States)

Laryea-Goldsmith, René; Oakey, John; Simms, Nigel J

2011-02-01

Biomass and municipal solid waste offer sustainable sources of energy; for example to meet heat and electricity demand in the form of combined cooling, heat and power. Combustion of biomass has a lesser impact than solid fossil fuels (e.g. coal) upon gas pollutant emissions, whilst energy recovery from municipal solid waste is a beneficial component of an integrated, sustainable waste management programme. Concurrent combustion of these fuels using a fluidised bed combustor may be a successful method of overcoming some of the disadvantages of biomass (high fuel supply and distribution costs, combustion characteristics) and characteristics of municipal solid waste (heterogeneous content, conflict with materials recycling). It should be considered that combustion of municipal solid waste may be a financially attractive disposal route if a 'gate fee' value exists for accepting waste for combustion, which will reduce the net cost of utilising relatively more expensive biomass fuels. Emissions of nitrogen monoxide and sulphur dioxide for combustion of biomass are suppressed after substitution of biomass for municipal solid waste materials as the input fuel mixture. Interactions between these and other pollutants such as hydrogen chloride, nitrous oxide and carbon monoxide indicate complex, competing reactions occur between intermediates of these compounds to determine final resultant emissions. Fluidised bed concurrent combustion is an appropriate technique to exploit biomass and municipal solid waste resources, without the use of fossil fuels. The addition of municipal solid waste to biomass combustion has the effect of reducing emissions of some gaseous pollutants.

The combustion behavior of large scale lithium titanate battery

Science.gov (United States)

Huang, Peifeng; Wang, Qingsong; Li, Ke; Ping, Ping; Sun, Jinhua

2015-01-01

Safety problem is always a big obstacle for lithium battery marching to large scale application. However, the knowledge on the battery combustion behavior is limited. To investigate the combustion behavior of large scale lithium battery, three 50 Ah Li(NixCoyMnz)O2/Li4Ti5O12 batteries under different state of charge (SOC) were heated to fire. The flame size variation is depicted to analyze the combustion behavior directly. The mass loss rate, temperature and heat release rate are used to analyze the combustion behavior in reaction way deeply. Based on the phenomenon, the combustion process is divided into three basic stages, even more complicated at higher SOC with sudden smoke flow ejected. The reason is that a phase change occurs in Li(NixCoyMnz)O2 material from layer structure to spinel structure. The critical temperatures of ignition are at 112–121°C on anode tab and 139 to 147°C on upper surface for all cells. But the heating time and combustion time become shorter with the ascending of SOC. The results indicate that the battery fire hazard increases with the SOC. It is analyzed that the internal short and the Li+ distribution are the main causes that lead to the difference. PMID:25586064

Control of the low-load region in partially premixed combustion

Science.gov (United States)

Ingesson, Gabriel; Yin, Lianhao; Johansson, Rolf; Tunestal, Per

2016-09-01

Partially premixed combustion (PPC) is a low temperature, direct-injection combustion concept that has shown to give promising emission levels and efficiencies over a wide operating range. In this concept, high EGR ratios, high octane-number fuels and early injection timings are used to slow down the auto-ignition reactions and to enhance the fuel and are mixing before the start of combustion. A drawback with this concept is the combustion stability in the low-load region where a high octane-number fuel might cause misfire and low combustion efficiency. This paper investigates the problem of low-load PPC controller design for increased engine efficiency. First, low-load PPC data, obtained from a multi-cylinder heavy- duty engine is presented. The data shows that combustion efficiency could be increased by using a pilot injection and that there is a non-linearity in the relation between injection and combustion timing. Furthermore, intake conditions should be set in order to avoid operating points with unfavourable global equivalence ratio and in-cylinder temperature combinations. Model predictive control simulations were used together with a calibrated engine model to find a gas-system controller that fulfilled this task. The findings are then summarized in a suggested engine controller design. Finally, an experimental performance evaluation of the suggested controller is presented.

Construction of combustion models for rapeseed methyl ester bio-diesel fuel for internal combustion engine applications.

Science.gov (United States)

Golovitchev, Valeri I; Yang, Junfeng

2009-01-01

Bio-diesel fuels are non-petroleum-based diesel fuels consisting of long chain alkyl esters produced by the transesterification of vegetable oils, that are intended for use (neat or blended with conventional fuels) in unmodified diesel engines. There have been few reports of studies proposing theoretical models for bio-diesel combustion simulations. In this study, we developed combustion models based on ones developed previously. We compiled the liquid fuel properties, and the existing detailed mechanism of methyl butanoate ester (MB, C(5)H(10)O(2)) oxidation was supplemented by sub-mechanisms for two proposed fuel constituent components, C(7)H(16) and C(7)H(8)O (and then, by mp2d, C(4)H(6)O(2) and propyne, C(3)H(4)) to represent the combustion model for rapeseed methyl ester described by the chemical formula, C(19)H(34)O(2) (or C(19)H(36)O(2)). The main fuel vapor thermal properties were taken as those of methyl palmitate C(19)H(36)O(2) in the NASA polynomial form of the Burcat database. The special global reaction was introduced to "crack" the main fuel into its constituent components. This general reaction included 309 species and 1472 reactions, including soot and NO(x) formation processes. The detailed combustion mechanism was validated using shock-tube ignition-delay data under diesel engine conditions. For constant volume and diesel engine (Volvo D12C) combustion modeling, this mechanism could be reduced to 88 species participating in 363 reactions.

A Mechanistic Investigation of Nitrogen Evolution and Corrosion with Oxy-Combustion

Energy Technology Data Exchange (ETDEWEB)

Dale Tree; Andrew Mackrory; Thomas Fletcher

2008-12-31

A premixed, staged, down-fired, pulverized coal reactor and a flat flame burner were used to study the evolution of nitrogen in coal contrasting differences in air and oxy-combustion. In the premixed reactor, the oxidizer was staged to produce a fuel rich zone followed by a burnout zone. The initial nominal fuel rich zone stoichiometric ratio (S.R.) of 0.85 selected produced higher NO reductions in the fuel rich region under oxy-combustion conditions. Air was found to be capable of similar NO reductions when the fuel rich zone was at a much lower S.R. of 0.65. At a S.R. of 0.85, oxy-combustion was measured to have higher CO, unburned hydrocarbons, HCN and NH{sub 3} in the fuel rich region than air at the same S.R. There was no measured difference in the initial formation of NO. The data suggest devolatilization and initial NO formation is similar for the two oxidizers when flame temperatures are the same, but the higher CO{sub 2} leads to higher concentrations of CO and nitrogen reducing intermediates at a given equivalence ratio which increases the ability of the gas phase to reduce NO. These results are supported by flat flame burner experiments which show devolatilization of nitrogen from the coal and char to be similar for air and oxy-flame conditions at a given temperature. A model of premixed combustion containing devolatilization, char oxidation and detailed kinetics captures most of the trends seen in the data. The model suggests CO is high in oxy-combustion because of dissociation of CO{sub 2}. The model also predicts a fraction (up to 20%, dependent on S.R.) of NO in air combustion can be formed via thermal processes with the source being nitrogen from the air while in oxy-combustion equilibrium drives a reduction in NO of similar magnitude. The data confirm oxy-combustion is a superior oxidizer to air for NO control because NO reduction can be achieved at higher S.R. producing better char burnout in addition to NO from recirculated flue gas being reduced

Effect of automatic control technologies on emission reduction in small-scale combustion

Energy Technology Data Exchange (ETDEWEB)

Ruusunen, M. [Control Engineering Laboratory, University of Oulu (Finland)

2007-07-01

Automatic control can be regarded as a primary measure for preventing combustion emissions. In this view, the control technology covers broadly the control methods, sensors and actuators for monitoring and controlling combustion. In addition to direct control of combustion process, it can also give tools for condition monitoring and optimisation of total heat consumption by system integration thus reducing the need for excess conversion of energy. Automatic control has already shown its potential in small-scale combustion. The potential, but still unrealised advantages of automatic control in this scale are the adaptation to changes in combustion conditions (fuel, environment, device, user) and the continuous optimisation of the air/fuel ratio. Modem control technology also covers combustion condition monitoring, diagnostics, and the higher level optimisation of the energy consumption with system integration. In theory, these primary measures maximise the overall efficiency, enabling a significant reduction in fuel consumption and thus total emissions per small-scale combustion unit, specifically at the annual level.

New class of combustion processes

International Nuclear Information System (INIS)

Merzhanov, A.G.; Borovinskaya, I.P.

1975-01-01

A short review is given of the results of work carried out since 1967 on studying the combustion processes caused by the interaction of chemical elements in the condensed phase and leading to the formation of refractory compounds. New phenomena and processes are described which are revealed when investigating the combustion of the systems of this class, viz solid-phase combustion, fast combustion in the condensed phase, filtering combustion, combustion in liquid nitrogen, spinning combustion, self-oscillating combustion, and repeated combustion. A new direction in employment of combustion processes is discussed, viz. a self-propagating high-temperature synthesis of refractory nitrides, carbides, borides, silicides and other compounds

Conversion of sewage sludge to clean solid fuel using hydrothermal carbonization: Hydrochar fuel characteristics and combustion behavior

International Nuclear Information System (INIS)

He, Chao; Giannis, Apostolos; Wang, Jing-Yuan

2013-01-01

Highlights: • The hydrothermal carbonization of sewage sludge process is developed. • Hydrochars are solid fuels with less nitrogen and sulfur contents. • The first order combustion reaction of hydrochars is derived. • Main combustion decomposition of hydrochars is easier and more stable. • Formation pathways of hydrochars during hydrothermal carbonization are proposed. - Abstract: Conventional thermochemical treatment of sewage sludge (SS) is energy-intensive due to its high moisture content. To overcome this drawback, the hydrothermal carbonization (HTC) process was used to convert SS into clean solid fuel without prior drying. Different carbonization times were applied in order to produce hydrochars possessing better fuel properties. After the carbonization process, fuel characteristics and combustion behaviors of hydrochars were evaluated. Elemental analysis showed that 88% of carbon was recovered while 60% of nitrogen and sulfur was removed. Due to dehydration and decarboxylation reactions, hydrogen/carbon and oxygen/carbon atomic ratios reduced to 1.53 and 0.39, respectively. It was found that the fuel ratio increased to 0.18 by prolonging the carbonization process. Besides, longer carbonization time seemed to decrease oxygen containing functional groups while carbon aromaticity structure increased, thereby rendering hydrochars highly hydrophobic. The thermogravimetric analysis showed that the combustion decomposition was altered from a single stage for raw sludge to two stages for hydrochars. The combustion reaction was best fitted to the first order for both raw sludge and hydrochars. The combustion of hydrochars is expected to be easier and more stable than raw sludge because of lower activation energy and pre-exponential factor

Investigation of the effect of heated ethanol fuel on combustion and emissions of an ethanol direct injection plus gasoline port injection (EDI + GPI) engine

International Nuclear Information System (INIS)

Huang, Yuhan; Hong, Guang

2016-01-01

Highlights: • Effect of EDI heating on the EDI + GPI engine performance was investigated. • CO and HC were significantly reduced and NO was slightly increased by EDI heating. • IMEP and combustion speed were slightly reduced by EDI heating. • EDI heating is effective to address the evaporation and over-cooling issues of EDI + GPI engine. - Abstract: Ethanol direct injection plus gasoline port injection (EDI + GPI) is a new technology to utilise ethanol fuel more efficiently and flexibly in spark ignition engines. One issue needs to be addressed in the development of EDI + GPI is the ethanol fuel’s low vapour pressure and large latent heat which slow down the ethanol’s evaporation and result in the mixture unready for combustion by the time of spark ignition and the consequent increase of CO and HC emissions. Heating the ethanol fuel to be directly injected (EDI heating) has been proposed to address this issue. This paper reports the investigation of the effect of EDI heating on the combustion and emissions of a research engine equipped with EDI + GPI. The results showed that EDI heating effectively reduced the CO and HC emissions of the engine due to the increase of evaporation rate and reduced fuel impingement and local over-cooling. The reduction of CO and HC became more significant with the increase of ethanol ratio. When the temperature of the ethanol fuel was increased by 40 °C, the CO and HC were reduced by as much as 43% and 51% respectively in EDI only condition at the original spark timing of 15 CAD BTDC, and 15% and 47% respectively at the minimum spark advance for best torque (MBT) timing of 19 CAD BTDC. On the other hand, the NO emission was slightly increased, but still much smaller than that in GPI only condition due to the strong cooling effect and low combustion temperature of EDI. The IMEP and combustion speed were slightly reduced by EDI heating due to the decrease of injector fuel flow rate and spray collapse of flash-boiling. The

Modelling the effects of heat loss and fuel/air mixing on turbulent combustion in gas turbine combustion systems

NARCIS (Netherlands)

Gövert, S.

2016-01-01

The present study is concerned with the development and validation of a simulation framework for the accurate prediction of turbulent reacting flows at reduced computational costs. Therefore, a combustion model based on the tabulation of laminar premixed flamelets is employed. By compilation of

Availability analysis of a syngas fueled spark ignition engine using a multi-zone combustion model

International Nuclear Information System (INIS)

Rakopoulos, C.D.; Michos, C.N.; Giakoumis, E.G.

2008-01-01

A previously developed and validated zero-dimensional, multi-zone, thermodynamic combustion model for the prediction of spark ignition (SI) engine performance and nitric oxide (NO) emissions has been extended to include second-law analysis. The main characteristic of the model is the division of the burned gas into several distinct zones, in order to account for the temperature and chemical species stratification developed in the burned gas during combustion. Within the framework of the multi-zone model, the various availability components constituting the total availability of each of the multiple zones of the simulation are identified and calculated separately. The model is applied to a multi-cylinder, four-stroke, turbocharged and aftercooled, natural gas (NG) SI gas engine running on synthesis gas (syngas) fuel. The major part of the unburned mixture availability consists of the chemical contribution, ranging from 98% at the inlet valve closing (IVC) event to 83% at the ignition timing of the total availability for the 100% load case, which is due to the presence of the combustible fuel. On the contrary, the multiple burned zones possess mainly thermomechanical availability. Specifically, again for the 100% load case, the total availability of the first burned zone at the exhaust valve opening (EVO) event consists of thermomechanical availability approximately by 90%, with similar percentages for all other burned zones. Two definitions of the combustion exergetic efficiency are used to explore the degree of reversibility of the combustion process in each of the multiple burned zones. It is revealed that the crucial factor determining the thermodynamic perfection of combustion in each burned zone is the level of the temperatures at which combustion occurs in the zone, with minor influence of the whole temperature history of the zone during the complete combustion phase. The availability analysis is extended to various engine loads. The engine in question is

Influence of injection timing on performance, combustion and emission characteristics of Jatropha biodiesel engine

International Nuclear Information System (INIS)

Ganapathy, T.; Gakkhar, R.P.; Murugesan, K.

2011-01-01

Highlights: → The effect of injection timing, load and speed on BSFC, BTE, peak pressure, HRR, CO, HC, NO and smoke were investigated. → Advanced injection timing caused reduced BSFC, CO, HC, smoke and increased BTE, P max , HRR max and NO for Jatropha biodiesel. → At 15 N m, 1800 rpm and 340 CAD, reduction in BSFC, CO, HC and smoke were 5.1%, 2.5%, 1.2% and 1.5% for Jatropha biodiesel. → Increase in BTE, P max , HRR max and NO at 15 N m, 1800 rpm and 340 CAD were 5.3%, 1.8%, 26% and 20% for Jatropha biodiesel. → Optimal injection timing for Jatropha biodiesel with minimum BSFC, CO, HC, smoke and maximum BTE, P max , HRR is 340 CAD. -- Abstract: The study of effect of injection timing along with engine operating parameters in Jatropha biodiesel engine is important as they significantly affect its performance and emissions. The present paper focuses on the experimental investigation of the influence of injection timing, load torque and engine speed on the performance, combustion and emission characteristics of Jatropha biodiesel engine. For this purpose, the experiments were conducted using full factorial design consisting of (3 3 ) with 27 runs for each fuel, diesel and Jatropha biodiesel. The effect of variation of above three parameters on brake specific fuel consumption (BSFC), brake thermal efficiency (BTE), peak cylinder pressure (P max ), maximum heat release rate (HRR max ), CO, HC, NO emissions and smoke density were investigated. It has been observed that advance in injection timing from factory settings caused reduction in BSFC, CO, HC and smoke levels and increase in BTE, P max , HRR max and NO emission with Jatropha biodiesel operation. However, retarded injection timing caused effects in the other way. At 15 N m load torque, 1800 rpm engine speed and 340 crank angle degree (CAD) injection timing, the percentage reduction in BSFC, CO, HC and smoke levels were 5.1%, 2.5%, 1.2% and 1.5% respectively. Similarly the percentage increase in BTE, P

AKR1C1 as a Biomarker for Differentiating the Biological Effects of Combustible from Non-Combustible Tobacco Products.

Science.gov (United States)

Woo, Sangsoon; Gao, Hong; Henderson, David; Zacharias, Wolfgang; Liu, Gang; Tran, Quynh T; Prasad, G L

2017-05-03

Smoking has been established as a major risk factor for developing oral squamous cell carcinoma (OSCC), but less attention has been paid to the effects of smokeless tobacco products. Our objective is to identify potential biomarkers to distinguish the biological effects of combustible tobacco products from those of non-combustible ones using oral cell lines. Normal human gingival epithelial cells (HGEC), non-metastatic (101A) and metastatic (101B) OSCC cell lines were exposed to different tobacco product preparations (TPPs) including cigarette smoke total particulate matter (TPM), whole-smoke conditioned media (WS-CM), smokeless tobacco extract in complete artificial saliva (STE), or nicotine (NIC) alone. We performed microarray-based gene expression profiling and found 3456 probe sets from 101A, 1432 probe sets from 101B, and 2717 probe sets from HGEC to be differentially expressed. Gene Set Enrichment Analysis (GSEA) revealed xenobiotic metabolism and steroid biosynthesis were the top two pathways that were upregulated by combustible but not by non-combustible TPPs. Notably, aldo-keto reductase genes, AKR1C1 and AKR1C2 , were the core genes in the top enriched pathways and were statistically upregulated more than eight-fold by combustible TPPs. Quantitative real time polymerase chain reaction (qRT-PCR) results statistically support AKR1C1 as a potential biomarker for differentiating the biological effects of combustible from non-combustible tobacco products.

Effects of nano-TiO2 on combustion and desulfurization

International Nuclear Information System (INIS)

Zhao, Yi; Wang, Shuqin; Shen, Yanmei; Lu, Xiaojuan

2013-01-01

Nanosized titanium oxide powder was prepared via the sol–gel process and characterized by transmission electron microscope. The effects of nano-TiO 2 on combustion characteristics of lignite, desulfurization in combustion and the properties of ashes were investigated. The calorific value of coals and the fusion point of the coal ashes were measured by calorimeter and ash fusion point determination meter; the components of coal ashes and the contents of combustible matters in ash were determined by chemical methods; the pore-size distribution and specific surface area of the coal ash were analyzed by surface area analyzer. A thermogravimetric analyzer was used to investigate the effect of nano-TiO 2 on combustion. The results showed that the calorific value of the coal and the fusion temperature of the coal ash were lowered by adding CaO, while on the other hand adding nano-TiO 2 to coal increased the calorific value and the melting temperature effectively. Meanwhile, the coal combustion efficiency and desulfurization in combustion could be effectively improved by the co-action of TiO 2 . - Highlights: • The burn-off rate of coals was raised and the combustible contents were reduced by adding nano-TiO 2 . • The desulfurization in combustion can be achieved by adding CaO, but the combustion efficiency was inhibited. • Nano-TiO 2 can promote the transfer rate of oxygen from gas phase to the surface of char

Turbulent Combustion Modeling Advances, New Trends and Perspectives

CERN Document Server

Echekki, Tarek

2011-01-01

Turbulent combustion sits at the interface of two important nonlinear, multiscale phenomena: chemistry and turbulence. Its study is extremely timely in view of the need to develop new combustion technologies in order to address challenges associated with climate change, energy source uncertainty, and air pollution. Despite the fact that modeling of turbulent combustion is a subject that has been researched for a number of years, its complexity implies that key issues are still eluding, and a theoretical description that is accurate enough to make turbulent combustion models rigorous and quantitative for industrial use is still lacking. In this book, prominent experts review most of the available approaches in modeling turbulent combustion, with particular focus on the exploding increase in computational resources that has allowed the simulation of increasingly detailed phenomena. The relevant algorithms are presented, the theoretical methods are explained, and various application examples are given. The book ...

Gas Phase Sulfur, Chlorine and Potassium Chemistry in Biomass Combustion

DEFF Research Database (Denmark)

Løj, Lusi Hindiyarti

2007-01-01

Gas Phase Sulfur, Chlorine and Alkali Metal Chemistry in Biomass Combustion Concern about aerosols formation, deposits, corrosion, and gaseous emissions during biomass combustion, especially straw, continues to be a driving force for investigation on S, Cl, K-containing species under combustions...... conditions. These trace species contained in the biomass structure will be released to the gas phase during combustion and contribute to the problems generated during the process. The investigation during this PhD project is done to stepwise improve the understanding in the chemistry and reduce...... the uncertainties. In the present work, the detailed kinetic model for gas phase sulfur, chlorine, alkali metal, and their interaction has been updated. The K/O/H/Cl chemistry, S chemistry, and their interaction can reasonably predict a range of experimental data. In general, understanding of the interaction...

Global cloud condensation nuclei influenced by carbonaceous combustion aerosol

Directory of Open Access Journals (Sweden)

D. V. Spracklen

2011-09-01

Full Text Available Black carbon in carbonaceous combustion aerosol warms the climate by absorbing solar radiation, meaning reductions in black carbon emissions are often perceived as an attractive global warming mitigation option. However, carbonaceous combustion aerosol can also act as cloud condensation nuclei (CCN so they also cool the climate by increasing cloud albedo. The net radiative effect of carbonaceous combustion aerosol is uncertain because their contribution to CCN has not been evaluated on the global scale. By combining extensive observations of CCN concentrations with the GLOMAP global aerosol model, we find that the model is biased low (normalised mean bias = −77 % unless carbonaceous combustion aerosol act as CCN. We show that carbonaceous combustion aerosol accounts for more than half (52–64 % of global CCN with the range due to uncertainty in the emitted size distribution of carbonaceous combustion particles. The model predicts that wildfire and pollution (fossil fuel and biofuel carbonaceous combustion aerosol causes a global mean cloud albedo aerosol indirect effect of −0.34 W m⁻², with stronger cooling if we assume smaller particle emission size. We calculate that carbonaceous combustion aerosol from pollution sources cause a global mean aerosol indirect effect of −0.23 W m⁻². The small size of carbonaceous combustion particles from fossil fuel sources means that whilst pollution sources account for only one-third of the emitted mass they cause two-thirds of the cloud albedo aerosol indirect effect that is due to carbonaceous combustion aerosol. This cooling effect must be accounted for, along with other cloud effects not studied here, to ensure that black carbon emissions controls that reduce the high number concentrations of fossil fuel particles have the desired net effect on climate.

Numerical Modeling of MILD Combustion at High Pressure to Predict the Optimal Operating Conditions

KAUST Repository

Vanteru, Mahendra Reddy

2017-02-01

This Chapter presents numerical simulation on MILD combustion operating at high pressure. Influence of preheat and dilution of oxidizer and operating pressure on stabilization of MILD combustion are presented. Three different preheat temperatures (1100, 1300 and 1500 K) and three different dilution levels (3, 6 and 9% O2) are simulated over an operating pressure variation from 1 atm to 16 atm. A classical jet in hot coflow burner is considered for this study. Total of 45 cases are simulated and analyzed. Essential characteristics of MILD combustion, i.e., maximum temperature (Tmax), temperature rise (ΔT) and temperature distributions, are analyzed. The distribution of emissions OH and CO are also studied and presented. Well-stabilized MILD combustion is observed for all cases except for two cases with high preheated (1500 K). Peak temperature is observed to decrease with increasing operating pressure for a given level of preheat and dilution. OH mass faction is reduced with increasing pressure. The CO emissions show little sensitivity to operating pressure. However, CO mass fraction is slightly higher at 1 atm operating pressure as compared to 4 to 16 atm. Since the residence time of reactants increases as the operating pressure increases, well-stabilized MILD combustion is observed for all highly diluted and low temperature preheat cases (3% O2 and 1100 K).

Numerical Modeling of MILD Combustion at High Pressure to Predict the Optimal Operating Conditions

KAUST Repository

Vanteru, Mahendra Reddy; Roberts, William L.

2017-01-01

This Chapter presents numerical simulation on MILD combustion operating at high pressure. Influence of preheat and dilution of oxidizer and operating pressure on stabilization of MILD combustion are presented. Three different preheat temperatures (1100, 1300 and 1500 K) and three different dilution levels (3, 6 and 9% O2) are simulated over an operating pressure variation from 1 atm to 16 atm. A classical jet in hot coflow burner is considered for this study. Total of 45 cases are simulated and analyzed. Essential characteristics of MILD combustion, i.e., maximum temperature (Tmax), temperature rise (ΔT) and temperature distributions, are analyzed. The distribution of emissions OH and CO are also studied and presented. Well-stabilized MILD combustion is observed for all cases except for two cases with high preheated (1500 K). Peak temperature is observed to decrease with increasing operating pressure for a given level of preheat and dilution. OH mass faction is reduced with increasing pressure. The CO emissions show little sensitivity to operating pressure. However, CO mass fraction is slightly higher at 1 atm operating pressure as compared to 4 to 16 atm. Since the residence time of reactants increases as the operating pressure increases, well-stabilized MILD combustion is observed for all highly diluted and low temperature preheat cases (3% O2 and 1100 K).

Spray combustion of Jet-A and diesel fuels in a constant volume combustion chamber

KAUST Repository

Jing, Wei

2015-01-01

This work investigates the spray combustion of Jet-A fuel in an optical constant-volume combustion chamber under different ambient initial conditions. Ambient temperature was varied at 800 K, 1000 K, and 1200 K and five different ambient O2 concentrations were used, spanning 10-21%. These ambient conditions can be used to mimic practical diesel engine working conditions under different fuel injection timings and exhaust gas recirculation (EGR) levels. Both transient and quasi-steady state analyses were conducted. The transient analysis focused on the flame development from the beginning to the end of the combustion process, illustrating how the flame structure evolves with time. The quasi-steady state analysis concentrated on the stable flame structure and compared the flame emissions in terms of spatially integrated intensity, flame effective area, and intensity per pixel. The transient analysis was based on measurements using high-speed imaging of both OH∗ chemiluminescence and broadband natural luminosity (NL). For the quasi-steady state analysis, three flame narrow-band emissions (OH∗ at 310 nm, Band A at 430 nm and Band B at 470 nm) were captured using an ICCD camera. Based on the current Jet-A data and diesel data obtained from previous experiments, a comparison between Jet-A and diesel was made in terms of flame development during the transient state and spatially integrated intensity, flame effective area, and intensity per pixel during the quasi-steady state. For the transient results, Jet-A shares a similar flame development trend to diesel, but featuring a narrower region of NL and a wider region of OH∗ with the increase of ambient temperature and O2 concentration. The soot cloud is oxidized more quickly for Jet-A than diesel at the end of combustion, evident by comparing the area of NL, especially under high O2 concentration. The quasi-steady state results suggest that soot is oxidized effectively under high O2 concentration conditions by the

Catalytic combustion of gasified waste - Experimental part. Final report

Energy Technology Data Exchange (ETDEWEB)

Jaeraas, Sven; Kusar, Henrik [Royal Institute of Technology, Stockholm (Sweden). Chemical Engineering and Technology

2003-08-01

This final report covers the work that has been performed within the project P 10547-2, 'Catalytic combustion of gasified waste - system analysis ORWARE'. This project is part of the research programme 'Energy from Waste' financed by the Swedish National Energy Administration. The project has been carried out at the division of Industrial Ecology and at the division of Chemical Technology at Royal Inst. of Technology. The aim of the project has been to study the potentials for catalytic combustion of gasified waste. The supposed end user of the technique is a smaller community in Sweden with 15,000-20,000 inhabitants. The project contains of two sub projects: an experimental part carried out at Chemical Technology and a system analysis carried out at Industrial Ecology. This report covers the experimental part of the project carried out at Chemical Technology. The aim for the experimental part has been to develop and test catalysts with long life-time and a high performance, to reduce the thermal-NO{sub x} below 5 ppm and to significantly reduce NO{sub x} formed from fuel-bound nitrogen. Different experimental studies have been carried out within the project: a set-up of catalytic materials have been tested over a synthetic mixture of the gasified waste, the influence of sulfur present in the gas stream, NO{sub x} formation from fuel bound nitrogen, kinetic studies of CO and H{sub 2} with and without the presence of water and the effects of adding a co-metal to palladium catalysts Furthermore a novel annular reactor design has been used to carry out experiments for kinetic measurements. Real gasification tests of waste pellets directly coupled to catalytic combustion have successfully been performed. The results obtained from the experiments, both the catalytic combustion and from the gasification, have been possible to use in the system analysis. The aim of the system analysis of catalytic combustion of gasified waste takes into consideration

Combustion and direct energy conversion inside a micro-combustor

International Nuclear Information System (INIS)

Lei, Yafeng; Chen, Wei; Lei, Jiang

2016-01-01

Highlights: • The flammability range of micro-combustor was broadened with heat recirculation. • The quenching diameter decreased with heat recirculation compared to without recirculation. • The surface areas to volume ratio was the most important parameter affecting the energy conversion efficiency. • The maximum conversion efficiency (3.15%) was achieved with 1 mm inner diameter. - Abstract: Electrical energy can be generated by employing a micro-thermophotovoltaic (TPV) cell which absorbs thermal radiation from combustion taking place in a micro-combustor. The stability of combustion in a micro-combustor is essential for operating a micro-power system using hydrogen and hydrocarbon fuels as energy source. To understand the mechanism of sustaining combustion within the quenching distance of fuel, this study proposed an annular micro combustion tube with recirculation of exhaust heat. To explore the feasibility of combustion in the micro annular tube, the parameters influencing the combustion namely, quenching diameter, and flammability were studied through numerical simulation. The results indicated that combustion could be realized in micro- combustor using heat recirculation. Following results were obtained from simulation. The quenching diameter reduced from 1.3 mm to 0.9 mm for heat recirculation at equivalence ratio of 1; the lean flammability was 2.5%–5% lower than that of without heat recirculation for quenching diameters between 2 mm and 5 mm. The overall energy conversion efficiency varied at different inner diameters. A maximum efficiency of 3.15% was achieved at an inner diameter of 1 mm. The studies indicated that heat recirculation is an effective strategy to maintain combustion and to improve combustion limits in micro-scale system.

Control of surplus oxygen in the combustion zone reduces fuel costs and NO{sub x} emissions; Verringerung der Brennstoffkosten und NO{sub X}-Emissionen durch Regelung des Sauerstoffueberschusses in der Brennzone

Energy Technology Data Exchange (ETDEWEB)

Boltz, Eric S. [Marathon Sensors Inc. (Germany); Baumann, Jens [Process Electronic GmbH (Germany)

2009-06-15

Real time in-situ measurement of oxygen content and temperature in the combustion zone of a heating boiler or furnace permits monitoring of combustion conditions at source. Measurements of oxygen surplus and of temperature at strategic points supply us with instantaneous information for optimum control of the combustion process. Accurate and rapid measurement of oxygen surplus is vital in view of the cost explosion in the case of fuels, and also for reduction of NO{sub x} emissions. Locally available commercial high-temperature oxygen sensors make it possible to solve problems of combustion control and burner regulation with only short amortization periods and high annual financial benefits in power generating plant, petrochemicals, refinery and glassworks applications. (orig.)

Combustion modeling in internal combustion engines

Science.gov (United States)

Zeleznik, F. J.

1976-01-01

The fundamental assumptions of the Blizard and Keck combustion model for internal combustion engines are examined and a generalization of that model is derived. The most significant feature of the model is that it permits the occurrence of unburned hydrocarbons in the thermodynamic-kinetic modeling of exhaust gases. The general formulas are evaluated in two specific cases that are likely to be significant in the applications of the model.

Effect of ethanol/water blends addition on diesel fuel combustion in RCM and DI diesel engine

International Nuclear Information System (INIS)

Nour, Mohamed; Kosaka, Hidenori; Sato, Susumu; Bady, Mahmoud; Abdel-Rahman, Ali K.; Uchida, Kenta

2017-01-01

Highlights: • Effect of ethanol/water addition on diesel combustion studied using optical diagnostics. • The addition of water to ethanol improves engine combustion and soot oxidation. • Ethanol/water injection into exhaust manifold eliminates their endothermic effect. • Ethanol with high water content is recommended for better engine combustion. • Soot concentration reduced by 50% and NO x emissions reduced by 88%. - Abstract: The effect of ethanol/water blends addition on diesel fuel combustion and emissions is investigated experimentally in this study using optical diagnostics. Basic study is performed using rapid compression machine (RCM) under CI conditions. The tested ethanol energy fractions varied in the range of 10–40% of the total added fuel energy, while water volume ratios varied in the range of 10–40% of the injected ethanol. Ethanol and water were evaporated before entering the combustion chamber to eliminate their endothermic effect. Results reveal that addition of ethanol/water blends to diesel fuel results in longer ignition delay and promote the apparent heat release rate (AHRR) at the premixed combustion phase compared to absolute ethanol addition. Additionally, soot and NO x emissions are reduced with ethanol/water addition compared to absolute ethanol addition and neat diesel combustion. The basic study is then extended to investigate the effect ethanol/water blends addition on diesel fuel combustion using single cylinder diesel engine. Waste heat in exhaust manifold is utilized to vaporize ethanol/water blends before combustion. Results reveal that ethanol/water blends injection leads to increase in peak cylinder pressure, indicated mean effective pressure (IMEP), and AHRR at premixed combustion phase. Additionally, the ignition delay increased with ethanol/water addition. NO x emission is decreased up to 88% along with a reduction in soot by 50%. The lower ethanol to water volume ratios show better combustion efficiency, IMEP

Catalysts for cleaner combustion of coal, wood and briquettes sulfur dioxide reduction options for low emission sources

Energy Technology Data Exchange (ETDEWEB)

Smith, P.V. [Global Environmental Solutions, Inc., Morton Grove, IL (United States)

1995-12-31

Coal fired, low emission sources are a major factor in the air quality problems facing eastern European cities. These sources include: stoker-fired boilers which feed district heating systems and also meet local industrial steam demand, hand-fired boilers which provide heat for one building or a small group of buildings, and masonary tile stoves which heat individual rooms. Global Environmental Systems is marketing through Global Environmental Systems of Polane, Inc. catalysts to improve the combustion of coal, wood or fuel oils in these combustion systems. PCCL-II Combustion Catalysts promotes more complete combustion, reduces or eliminates slag formations, soot, corrosion and some air pollution emissions and is especially effective on high sulfur-high vanadium residual oils. Glo-Klen is a semi-dry powder continuous acting catalyst that is injected directly into the furnace of boilers by operating personnel. It is a multi-purpose catalyst that is a furnace combustion catalyst that saves fuel by increasing combustion efficiency, a cleaner of heat transfer surfaces that saves additional fuel by increasing the absorption of heat, a corrosion-inhibiting catalyst that reduces costly corrosion damage and an air pollution reducing catalyst that reduces air pollution type stack emissions. The reduction of sulfur dioxides from coal or oil-fired boilers of the hand fired stoker design and larger, can be controlled by the induction of the Glo-Klen combustion catalyst and either hydrated lime or pulverized limestone.

A predictive model of natural gas mixture combustion in internal combustion engines

Directory of Open Access Journals (Sweden)

Henry Espinoza

2007-05-01

Full Text Available This study shows the development of a predictive natural gas mixture combustion model for conventional com-bustion (ignition engines. The model was based on resolving two areas; one having unburned combustion mixture and another having combustion products. Energy and matter conservation equations were solved for each crankshaft turn angle for each area. Nonlinear differential equations for each phase’s energy (considering compression, combustion and expansion were solved by applying the fourth-order Runge-Kutta method. The model also enabled studying different natural gas components’ composition and evaluating combustion in the presence of dry and humid air. Validation results are shown with experimental data, demonstrating the software’s precision and accuracy in the results so produced. The results showed cylinder pressure, unburned and burned mixture temperature, burned mass fraction and combustion reaction heat for the engine being modelled using a natural gas mixture.

Boiler using combustible fluid

Science.gov (United States)

Baumgartner, H.; Meier, J.G.

1974-07-03

A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

Severe Accident Analysis for Combustible Gas Risk Evaluation inside CFVS

International Nuclear Information System (INIS)

Lee, NaRae; Lee, JinYong; Bang, YoungSuk; Lee, DooYong; Kim, HyeongTaek

2015-01-01

The purpose of this study is to identify the composition of gases discharged into the containment filtered venting system by analyzing severe accidents. The accident scenarios which could be significant with respect to containment pressurization and hydrogen generation are derived and composition of containment atmosphere and possible discharged gas mixtures are estimated. In order to ensure the safety of the public and environment, the ventilation system should be designed properly by considering discharged gas flow rate, aerosol loads, radiation level, etc. One of considerations to be resolved is the risk due to combustible gas, especially hydrogen. Hydrogen can be generated largely by oxidation of cladding and decomposition of concrete. If the hydrogen concentration is high enough and other conditions like oxygen and steam concentration is met, the hydrogen can burn, deflagrate or detonate, which result in the damage the structural components. In particularly, after Fukushima accident, the hydrogen risk has been emphasized as an important contributor threatening the integrity of nuclear power plant during the severe accident. These results will be used to analyze the risk of hydrogen combustion inside the CFVS as boundary conditions. Severe accident simulation results are presented and discussed qualitatively with respect to hydrogen combustion. The hydrogen combustion risk inside of the CFVS has been examined qualitatively by investigating the discharge flow characteristics. Because the composition of the discharge flow to CFVS would be determined by the containment atmosphere, the severe accident progression and containment atmosphere composition have been investigated. Due to PAR operation, the hydrogen concentration in the containment would be decreased until the oxygen is depleted. After the oxygen is depleted, the hydrogen concentration would be increased. As a result, depending on the vent initiation timing (i.e. vent initiation pressure), the important

Severe Accident Analysis for Combustible Gas Risk Evaluation inside CFVS

Energy Technology Data Exchange (ETDEWEB)

Lee, NaRae; Lee, JinYong; Bang, YoungSuk; Lee, DooYong [FNC Technology Co. Ltd., Yongin (Korea, Republic of); Kim, HyeongTaek [KHNP-Central Research Institute, Daejeon (Korea, Republic of)

2015-10-15

The purpose of this study is to identify the composition of gases discharged into the containment filtered venting system by analyzing severe accidents. The accident scenarios which could be significant with respect to containment pressurization and hydrogen generation are derived and composition of containment atmosphere and possible discharged gas mixtures are estimated. In order to ensure the safety of the public and environment, the ventilation system should be designed properly by considering discharged gas flow rate, aerosol loads, radiation level, etc. One of considerations to be resolved is the risk due to combustible gas, especially hydrogen. Hydrogen can be generated largely by oxidation of cladding and decomposition of concrete. If the hydrogen concentration is high enough and other conditions like oxygen and steam concentration is met, the hydrogen can burn, deflagrate or detonate, which result in the damage the structural components. In particularly, after Fukushima accident, the hydrogen risk has been emphasized as an important contributor threatening the integrity of nuclear power plant during the severe accident. These results will be used to analyze the risk of hydrogen combustion inside the CFVS as boundary conditions. Severe accident simulation results are presented and discussed qualitatively with respect to hydrogen combustion. The hydrogen combustion risk inside of the CFVS has been examined qualitatively by investigating the discharge flow characteristics. Because the composition of the discharge flow to CFVS would be determined by the containment atmosphere, the severe accident progression and containment atmosphere composition have been investigated. Due to PAR operation, the hydrogen concentration in the containment would be decreased until the oxygen is depleted. After the oxygen is depleted, the hydrogen concentration would be increased. As a result, depending on the vent initiation timing (i.e. vent initiation pressure), the important

A Preliminary Study on Rock Bed Heat Storage from Biomass Combustion for Rice Drying

Science.gov (United States)

Nelwan, L. O.; Wulandani, D.; Subrata, I. D. M.

2018-05-01

One of the main constraints of biomass fuel utilization in a small scale rice drying system is the operating difficulties related to the adjustment of combustion/feeding rate. Use of thermal storage may reduce the problem since combustion operation can be accomplished in a much shorter time and then the use of heat can be regulated by simply adjusting the air flow. An integrated biomass furnace-rock bed thermal storage with a storage volume of 540 L was designed and tested. There were four experiments conducted in this study. Charging was performed within 1-2 hours with a combustion rate of 11.5-15.5 kg/h. In discharging process, the mixing of air passing through the rock bed and ambient air were regulated by valves. Without adjusting the valve during the discharging process, air temperature increased up to 80°C, which is not suitable for rice batch drying process. Charging with sufficiently high combustion rate (14 kg/h) within 1 hour continued by adjusting the valve during discharging process below 60°C increased the discharge-charge time ratio (DCTR) up to 5.33 at average air temperature of 49°C and ambient temperature of 33°C.The efficiency of heat discharging was ranged from 34.5 to 45.8%. From the simulation, as much as 156.8-268.8 kg of rice was able to be dried by the discharging conditions.

Computational combustion and emission analysis of hydrogen-diesel blends with experimental verification

International Nuclear Information System (INIS)

Masood, M.; Ishrat, M.M.; Reddy, A.S.

2007-01-01

The paper discusses the effect of blending hydrogen with diesel in different proportions on combustion and emissions. A comparative study was carried out to analyze the effect of direct injection of hydrogen into the combustion chamber with that of induction through the inlet manifold for dual fueling. Percentage of hydrogen substitution varied from 20% to 80%, simultaneously reducing the diesel percentages. CFD analysis of dual fuel combustion and emissions were carried out for both the said methods using the CFD software FLUENT, meshing the combustion chamber was carried out using GAMBIT. The standard combustion and emission models were used in the analysis. In the second part of the paper, the effect of angle of injection in both the methods of hydrogen admission, on performance, combustion and emissions were analyzed. The experimental results were compared with that of simulated values and a good agreement between them was noticed. (author)

Natural gas reburning technology for NOx reduction from MSW combustion systems

International Nuclear Information System (INIS)

Penterson, C.A.; Abbasi, H.; Khinkis, M.J.; Wakamura, Y.; Linz, D.G.

1990-01-01

A technology for reducing emissions from municipal solid waste combustion systems through advanced combustion techniques is being developed. Pilot testing of natural gas reburning was first performed in the Institute of Gas Technology's pilot-scale furnace under conditions simulating the firing of 1.7 x 10 6 Btu/hr (0.5 MWth) of MSW. Pilot testing then continued in Riley Stoker Corporation's 3 x 10 6 Btu/hr (0.88 MWth), 7 ton/day, pilot-scale MSW combustor using actual MSW in both test series, injection of up to 15% (HHV basis) natural gas reduced NO, by 50--70% while maintaining or improving combustion efficiency as measured by CO and hydrocarbon emissions and temperature stability. This paper will review the test results and discuss the status of the full-scale field demonstration testing that is planned for 1990

Investigation of a rotary valving system with variable valve timing for internal combustion engines

Science.gov (United States)

Cross, Paul C.; Hansen, Craig N.

1994-11-01

The objective of the program was to provide a functional demonstration of the Hansen Rotary Valving System with Variable Valve Timing (HRVS/VVT), capable of throttleless inlet charge control, as an alternative to conventional poppet-valves for use in spark ignited internal combustion engines. The goal of this new technology is to secure benefits in fuel economy, broadened torque band, vibration reduction, and overhaul accessibility. Additionally, use of the variable valve timing capability to vary the effective compression ratio is expected to improve multifuel tolerance and efficiency. Efforts directed at the design of HRVS components proved to be far more extensive than had been anticipated, ultimately requiring that proof-trial design/development work be performed. Although both time and funds were exhausted before optical or ion-probe types of in-cylinder investigation could be undertaken, a great deal of laboratory data was acquired during the course of the design/development work. This laboratory data is the basis for the information presented in this final report.

Combustion of Refuse Derived Fuels; Foerbraenning av utsorterade avfallsfraktioner

Energy Technology Data Exchange (ETDEWEB)

Berg, Magnus; Wikman, Karin [AaF-Energi och Miljoe, Stockholm (Sweden); Andersson, Christer; Myringer, Aase; Helgesson, Anna [Vattenfall Utveckling AB, Aelvkarleby (Sweden); Eskilsson, David; Ekvall, Annika [SP Swedish National Testing and Research Inst., Boraas (Sweden); Oehman, Marcus; Geyter, Sigrid de [Umeaa Univ. (Sweden). Energy Technology and Thermal Process Chemistry

2005-03-01

the different fuel mixtures shows that addition of PWP-fuel results in locally lower O{sub 2}-levels and higher CO-levels close to the front wall. This results in an increased risk for local corrosion on the furnace walls. The measurements in Johannes showed that co-combustion with PWP increased the alkali chloride concentration in the flue gas but an increase in the amount of deposits could not be measured. However, the deposits contained more chlorine during co-combustion of PWP, which should yield increased risk for corrosion. The increase can be correlated with the wood and paper fractions of the fuel. Injection of sulphate in the furnace resulted in increased SO{sub 2} concentration and reduced alkali chloride concentration, which resulted in reduced deposit formation. Addition of sulphate also reduced the chlorine concentration in the deposits thereby reducing the corrosion risk. The sub micron particles in the flue gas before gas cleaning mainly contain KCl and K2SO{sub 4} but with sulphate addition KCl to a large extent is converted to K{sub 2}SO{sub 4}. Altogether, this shows that this kind of fuel yields an increased risk for corrosion and deposits on superheaters and furnace walls. However, these problems can to a large extent be avoided by the addition of sulphur (concerning superheater corrosion) and adjustment of the air and fuel feed equipment (concerning furnace wall corrosion). Also in the tests in Hoegdalen the SO{sub 2} concentration increased and the alkali chloride concentration decreased in the flue gas when sulphur was added, resulting in decreased deposit formation. At the same time the chlorine concentration decreased and the sulphur concentration increased in the deposits. However, the chlorine concentration of the deposits was still high and did not decrease as much as in Johannes. Using elementary sulphur or sulphate as an additive had no noticeable influence on deposit growth or on the chemical composition of the deposits. Neither did the

Fuel oil-water emulsions combustion and application perspectives in Mexico; Combustion de emulsiones de agua en combustoleo y perspectivas de aplicacion en Mexico

Energy Technology Data Exchange (ETDEWEB)

Ocampo Barrera, Rene [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1998-09-01

Fuel drops with a content of 16% by weight were burned in three emulsions prepared with 5%, 15% and 25% water. The combustion of the drops was carried out in an spherical furnace utilizing the technique of a drop suspended in a filament. The combustion process was registered by a high velocity video system. It was found that the surface of the particles produced by the combustion of the emulsions, had larger holes than the ones of the fuel, therefore it is expected that emulsifying the fuel can help in reducing the unburned particles emission. [Espanol] Se quemaron gotas de un combustoleo, con un contenido de asfaltenos del 16% en peso, y de tres emulsiones preparadas con 5%, 15% y 25% de agua. La combustion de las gotas se llevo a cabo en un horno esferico empleando la tecnica de gota suspendida en un filamento. El proceso de combustion se registro mediante un sistema de video de alta velocidad. Se encontro que la superficie de las particulas de coque, producidas por la combustion de emulsiones, tuvo hoyos mas grandes que la del combustoleo, por lo que es de esperarse que emulsionar el combustoleo puede ayudar a reducir las emisiones de particulas inquemadas.

Gaseous emissions during concurrent combustion of biomass and non-recyclable municipal solid waste

Directory of Open Access Journals (Sweden)

Oakey John

2011-02-01

Full Text Available Abstract Background Biomass and municipal solid waste offer sustainable sources of energy; for example to meet heat and electricity demand in the form of combined cooling, heat and power. Combustion of biomass has a lesser impact than solid fossil fuels (e.g. coal upon gas pollutant emissions, whilst energy recovery from municipal solid waste is a beneficial component of an integrated, sustainable waste management programme. Concurrent combustion of these fuels using a fluidised bed combustor may be a successful method of overcoming some of the disadvantages of biomass (high fuel supply and distribution costs, combustion characteristics and characteristics of municipal solid waste (heterogeneous content, conflict with materials recycling. It should be considered that combustion of municipal solid waste may be a financially attractive disposal route if a 'gate fee' value exists for accepting waste for combustion, which will reduce the net cost of utilising relatively more expensive biomass fuels. Results Emissions of nitrogen monoxide and sulphur dioxide for combustion of biomass are suppressed after substitution of biomass for municipal solid waste materials as the input fuel mixture. Interactions between these and other pollutants such as hydrogen chloride, nitrous oxide and carbon monoxide indicate complex, competing reactions occur between intermediates of these compounds to determine final resultant emissions. Conclusions Fluidised bed concurrent combustion is an appropriate technique to exploit biomass and municipal solid waste resources, without the use of fossil fuels. The addition of municipal solid waste to biomass combustion has the effect of reducing emissions of some gaseous pollutants.

Analysis of Turbulent Combustion in Simplified Stratified Charge Conditions

Science.gov (United States)

Moriyoshi, Yasuo; Morikawa, Hideaki; Komatsu, Eiji

The stratified charge combustion system has been widely studied due to the significant potentials for low fuel consumption rate and low exhaust gas emissions. The fuel-air mixture formation process in a direct-injection stratified charge engine is influenced by various parameters, such as atomization, evaporation, and in-cylinder gas motion at high temperature and high pressure conditions. It is difficult to observe the in-cylinder phenomena in such conditions and also challenging to analyze the following stratified charge combustion. Therefore, the combustion phenomena in simplified stratified charge conditions aiming to analyze the fundamental stratified charge combustion are examined. That is, an experimental apparatus which can control the mixture distribution and the gas motion at ignition timing was developed, and the effects of turbulence intensity, mixture concentration distribution, and mixture composition on stratified charge combustion were examined. As a result, the effects of fuel, charge stratification, and turbulence on combustion characteristics were clarified.

Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up

Energy Technology Data Exchange (ETDEWEB)

Axelbaum, Richard [Washington Univ., St. Louis, MO (United States); Kumfer, Benjamin [Washington Univ., St. Louis, MO (United States); Gopan, Akshay [Washington Univ., St. Louis, MO (United States); Yang, Zhiwei [Washington Univ., St. Louis, MO (United States); Phillips, Jeff [Electric Power Research Inst. (EPRI), Palo Alto, CA (United States); Pint, Bruce [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2017-12-29

The immediate need for a high efficiency, low cost carbon capture process has prompted the recent development of pressurized oxy-combustion. With a greater combustion pressure the dew point of the flue gas is increased, allowing for effective integration of the latent heat of flue gas moisture into the Rankine cycle. This increases the net plant efficiency and reduces costs. A novel, transformational process, named Staged, Pressurized Oxy-Combustion (SPOC), achieves additional step changes in efficiency and cost reduction by significantly reducing the recycle of flue gas. The research and development activities conducted under Phases I and II of this project (FE0009702) include: SPOC power plant cost and performance modeling, CFD-assisted design of pressurized SPOC boilers, theoretical analysis of radiant heat transfer and ash deposition, boiler materials corrosion testing, construction of a 100 kWth POC test facility, and experimental testing. The results of this project have advanced the technology readiness level (TRL) of the SPOC technology from 1 to 5.

EMISSION AND COMBUSTION CHARACTERISTICS OF DIFFERENT FUELS IN A HCCI ENGINE

Directory of Open Access Journals (Sweden)

S. Sendilvelan

2011-06-01

Full Text Available Different intake valve timings and fuel injection amounts were tested in order to identify their effects on exhaust emissions and combustion characteristics using variable valve actuation (VVA in a Homogeneous Charge Compression Ignition (HCCI engine. The HCCI engine is a promising concept for future automobile engines and stationary power plants. The two-stage ignition process in a HCCI engine creates advanced ignition and stratified combustion, which makes the ignition timing and combustion rate controllable. Meanwhile, the periphery of the fuel-rich zone leads to fierce burning, which results in slightly high NOx emissions. The experiments were conducted in a modified single cylinder water-cooled diesel engine. In this experiment we use diesel, bio-diesel (Jatropha and gasoline as the fuel at different mixing ratios. HCCI has advantages in high thermal efficiency and low emissions and could possibly become a promising combustion method in internal combustion engines.

Development and validation of double and single Wiebe function for multi-injection mode Diesel engine combustion modelling for hardware-in-the-loop applications

International Nuclear Information System (INIS)

Maroteaux, Fadila; Saad, Charbel; Aubertin, Fabrice

2015-01-01

Highlights: • Modelling of Diesel engine combustion with multi-injection mode was conducted. • Double and single Wiebe correlations for pilot, main and post combustion processes were calibrated. • Ignition delay time correlations have been developed and calibrated using experimental data for each injection. • The complete in-cylinder model has been applied successfully to real time simulations on HiL test bed. - Abstract: The improvement of Diesel engine performances in terms of fuel consumption and pollutant emissions has a huge impact on management system and diagnostic procedure. Validation and testing of engine performances can benefit from the use of theoretical models, for the reduction of development time and costs. Hardware in the Loop (HiL) test bench is a suitable way to achieve these objectives. However, the increasing complexity of management systems rises challenges for the development of very reduced physical models able to run in real time applications. This paper presents an extension of a previously developed phenomenological Diesel combustion model suitable for real time applications on a HiL test bench. In the earlier study, the modelling efforts have been targeted at high engine speeds with a very short computational time window, and where the engine operates with single injection. In the present work, a modelling of in-cylinder processes at low and medium engine speeds with multi-injection is performed. In order to reach an adequate computational time, the combustion progress during the pilot and main injection periods has been treated through a double Wiebe function, while the post combustion period has required a single Wiebe function. This paper describes the basic system models and their calibration and validation against experimental data. The use of the developed correlations of Wiebe coefficients and ignition delay times for each combustion phase, included in the in-cylinder crank angle global model, is applied for the prediction

HERCULES Advanced Combustion Concepts Test Facility: Spray/Combustion Chamber

Energy Technology Data Exchange (ETDEWEB)

Herrmann, K. [Eidgenoessische Technische Hochschule (ETH), Labor fuer Aerothermochemie und Verbrennungssysteme, Zuerich (Switzerland)

2004-07-01

This yearly report for 2004 on behalf of the Swiss Federal Office of Energy (SFOE) at the Laboratory for Aero-thermochemistry and Combustion Systems at the Federal Institute of Technology ETH in Zurich, Switzerland, presents a review of work being done within the framework of HERCULES (High Efficiency R and D on Combustion with Ultra Low Emissions for Ships) - the international R and D project concerning new technologies for ships' diesels. The work involves the use and augmentation of simulation models. These are to be validated using experimental data. The report deals with the development of an experimental set-up that will simulate combustion in large two-stroke diesel engines and allow the generation of reference data. The main element of the test apparatus is a spray / combustion chamber with extensive possibilities for optical observation under variable flow conditions. The results of first simulations confirm concepts and shall help in further work on the project. The potential offered by high-speed camera systems was tested using the institute's existing HTDZ combustion chamber. Further work to be done is reviewed.

Quasi-dimensional modeling of a fast-burn combustion dual-plug spark-ignition engine with complex combustion chamber geometries

International Nuclear Information System (INIS)

Altın, İsmail; Bilgin, Atilla

2015-01-01

This study builds on a previous parametric investigation using a thermodynamic-based quasi-dimensional (QD) cycle simulation of a spark-ignition (SI) engine with dual-spark plugs. The previous work examined the effects of plug-number and location on some performance parameters considering an engine with a simple cylindrical disc-shaped combustion chamber. In order to provide QD thermodynamic models applicable to complex combustion chamber geometries, a novel approach is considered here: flame-maps, which utilizes a computer aided design (CAD) software (SolidWorks). Flame maps are produced by the CAD software, which comprise all the possible flame radiuses with an increment of one-mm between them, according to the spark plug positions, spark timing, and piston position near the top dead center. The data are tabulated and stored as matrices. Then, these tabulated data are adapted to the previously reported cycle simulation. After testing for simple disc-shaped chamber geometries, the simulation is applied to a real production automobile (Honda-Fit) engine to perform the parametric study. - Highlights: • QD model was applied in dual plug engine with complex realistic combustion chamber. • This method successfully modeled the combustion in the dual-plug Honda-Fit engine. • The same combustion chamber is tested for various spark plug(s) locations. • The centrally located single spark-plug results in the fastest combustion

The pyrolysis and combustion characteristics of five typical biomass from Tibet

Energy Technology Data Exchange (ETDEWEB)

Dong, C.Q.; Shan, L.; Yang, Y.P.; Zhang, J.J. [Ministry of Education, Beijing (China). Key Laboratory of Condition Monitoring and Control for Power Plant Equipment; North China Electric Power Univ., Beijing (China). Key Laboratory of Security and Clean Energy Technology

2008-07-01

Thermogravimetric (TG) and differential thermal gravimetric (DTG) methods were used to conduct pyrolysis and combustion tests of winter wheat, highland barley, sawdust, cattle manure, and sheep manure from Tibet. The aim of the study was to determine the combustion characteristics of biomass grown in regions with lower levels of atmospheric oxygen. A reaction kinetic model was used to determine kinetic parameters of the biomass samples. The study showed that oxygen concentrations did not influence activation energy. Combustion efficiency was influenced by the nitrogen dilute effect located in Tibet. The sawdust combustion analysis demonstrated that heat losses from flue gases were approximately 5 per cent higher when oxygen levels were 11 per cent, than when oxygen levels were 21 per cent. It was concluded that chemical looping processes can be used to improve efficiency and reduce the environmental impacts associated with biomass combustion in Tibet. 17 refs., 3 tabs., 6 figs.

Soot measurements for diesel and biodiesel spray combustion under high temperature highly diluted ambient conditions

KAUST Repository

Zhang, Ji

2014-11-01

This paper presents the soot temperature and KL factor for biodiesel, namely fatty acid methyl ester (FAME) and diesel fuel combustion in a constant volume chamber using a two-color technique. The KL factor is a parameter for soot concentration, where K is an absorption coefficient and proportional to the number density of soot particles, L is the geometric thickness of the flame along the optical detection axis, and KL factor is proportional to soot volume fraction. The main objective is to explore a combustion regime called high-temperature and highly-diluted combustion (HTHDC) and compare it with the conventional and low-temperature combustion (LTC) modes. The three different combustion regimes are implemented under different ambient temperatures (800 K, 1000 K, and 1400 K) and ambient oxygen concentrations (10%, 15%, and 21%). Results are presented in terms of soot temperature and KL factor images, time-resolved pixel-averaged soot temperature, KL factor, and spatially integrated KL factor over the soot area. The time-averaged results for these three regimes are compared for both diesel and biodiesel fuels. Results show complex combined effects of the ambient temperature and oxygen concentration, and that two-color temperature for the HTHDC mode at the 10% oxygen level can actually be lower than the conventional mode. Increasing ambient oxygen and temperature increases soot temperature. Diesel fuel results in higher soot temperature than biodiesel for all three regimes. Results also show that diesel and biodiesel fuels have very different burning and sooting behavior under the three different combustion regimes. For diesel fuel, the HTHDC regime offers better results in terms of lower soot than the conventional and LTC regimes, and the 10% O2, 1400 K ambient condition shows the lowest soot concentration while maintaining a moderate two-color temperature. For biodiesel, the 15% O2, 800 K ambient condition shows some advantages in terms of reducing soot

Effects of injection timing on fluid flow characteristics of partially premixed combustion based on high-speed particle image velocimetry

NARCIS (Netherlands)

Izadi Najafabadi, M.; Tanov, S.; Wang, H.; Somers, L.M.T.; Johansson, B.; Dam, N.J.

2017-01-01

Partially premixed combustion (PPC) is a promising combustion concept to meet the increasing demands of emission legislation and to improve fuel efficiency. Longer ignition delay of PPC in comparison with conventional diesel combustion provide better fuel/air mixture which decreases soot and NOx

Faecal-wood biomass co-combustion and ash composition analysis.

Science.gov (United States)

Somorin, Tosin Onabanjo; Kolios, Athanasios J; Parker, Alison; McAdam, Ewan; Williams, Leon; Tyrrel, Sean

2017-09-01

Fuel blending is a widely used approach in biomass combustion, particularly for feedstocks with low calorific value and high moisture content. In on-site sanitation technologies, fuel blending is proposed as a pre-treatment requirement to reduce moisture levels and improve the physiochemical properties of raw faeces prior to drying. This study investigates the co-combustion performance of wood dust: raw human faeces blends at varying air-to-fuel ratios in a bench-scale combustor test rig. It concludes with ash composition analyses and discusses their potential application and related problems. The study shows that a 50:50 wood dust (WD): raw human faeces (FC) can reduce moisture levels in raw human faeces by ∼40% prior to drying. The minimum acceptable blend for treating moist faeces without prior drying at a combustion air flow rate of 14-18 L/min is 30:70 WD: FC. For self-sustained ignition and flame propagation, the minimum combustion temperature required for conversion of the fuel to ash is ∼400 °C. The most abundant elements in faecal ash are potassium and calcium, while elements such as nickel, aluminium and iron are in trace quantities. This suggests the potential use of faecal ash as a soil conditioner, but increases the tendency for fly ash formation and sintering problems.

Modification of combustion aerosols in the atmosphere

Energy Technology Data Exchange (ETDEWEB)

Weingartner, E [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

1996-07-01

Combustion aerosols particles are released on large scale into the atmosphere in the industrialized regions as well as in the tropics (by wood fires). The particles are subjected to various aging processes which depend on the size, morphology, and chemical composition of the particles. The interaction of combustion particles with sunlight and humidity as well as adsorption and desorption of volatile material to or from the particles considerably changes their physical and chemical properties and thus their residence time in the atmosphere. This is of importance because combustion particles are known to have a variety of health effects on people. Moreover, atmospheric aerosol particles have an influence on climate, directly through the reflection and absorption of solar radiation and indirectly through modifying the optical properties and lifetime of clouds. In a first step, a field experiment was carried out to study the sources and characteristics of combustion aerosols that are emitted from vehicles in a road tunnel. It was found that most of the fine particles were tail pipe emissions of diesel powered vehicles. The calculation shows that on an average these vehicles emit about 300 mg fine particulate matter per driven kilometer. This emission factor is at least 100 times higher than the mean emission factor estimated for gasoline powered vehicles. Furthermore, it is found that during their residence time in the tunnel, the particles undergo significant changes: The particles change towards a more compact structure. The conclusion is reached that this is mainly due to adsorption of volatile material from the gas phase to the particle surface. In the atmosphere, the life cycle as well as the radiative and chemical properties of an aerosol particle is strongly dependent on its response to humidity. Therefore the hygroscopic behavior of combustion particles emitted from single sources (i.e. from a gasoline and a diesel engine) were studied in laboratory experiments.

Predictive modeling and reducing cyclic variability in autoignition engines

Science.gov (United States)

Hellstrom, Erik; Stefanopoulou, Anna; Jiang, Li; Larimore, Jacob

2016-08-30

Methods and systems are provided for controlling a vehicle engine to reduce cycle-to-cycle combustion variation. A predictive model is applied to predict cycle-to-cycle combustion behavior of an engine based on observed engine performance variables. Conditions are identified, based on the predicted cycle-to-cycle combustion behavior, that indicate high cycle-to-cycle combustion variation. Corrective measures are then applied to prevent the predicted high cycle-to-cycle combustion variation.

The application of zonal trademark combustion monitoring and tuning system to coal boilers for efficiency improvement and emissions reduction

Energy Technology Data Exchange (ETDEWEB)

Xu, Guang; Zhou, Wei; Widmer, Neil C.; Moyeda, David K. [GE Energy, Irvine, CA (United States)

2013-07-01

Coal-fired boilers equipped with Low NO{sub x} Burner (LNB) and Overfire Air (OFA) are challenged with maintaining good combustion conditions. In many cases, the significant increases in carbon monoxide (CO) and unburned carbon levels can be attributed to local poor combustion conditions as a result of poorly controlled fuel-air distribution within the furnace. The Zonal trademark combustion monitoring and tuning system developed by GE is available to detect and correct the furnace air-fuel distribution imbalance. The system monitors the boiler excess oxygen (O{sub 2}) and combustible gases, primarily carbon monoxide (CO), by using spatially distributed multipoint sensors located in the boiler's high temperature upper convective backpass region. At these locations, the furnace flow is still significantly stratified allowing tracing of poor combustion zones to specific burners and OFA ports. Using a model-based tuning system, operators can rapidly respond to poor combustion conditions by redistributing airflows to select burners and OFA ports. By improving combustion at every point within the furnace, the boiler can operate at reduced excess O{sub 2} and reduced furnace exit gas temperature (FEGT) while also reducing localized hot spots, corrosive gas conditions, slag formation, and carbon-in-ash. Benefits include improving efficiency, reducing NO{sub X} emissions, increasing output and maximizing availability. This chapter presents the results from implementing the Zonal combustion monitoring and tuning system on a 460 MW tangential-fired coal boiler in the Western United States.

Combustion, cofiring and emissions characteristics of torrefied biomass in a drop tube reactor

International Nuclear Information System (INIS)

Ndibe, Collins; Maier, Jörg; Scheffknecht, Günter

2015-01-01

The study investigates cofiring characteristics of torrefied biomass fuels at 50% thermal shares with coals and 100% combustion cases. Experiments were carried out in a 20 kW, electrically heated, drop-tube reactor. Fuels used include a range of torrefied biomass fuels, non-thermally treated white wood pellets, a high volatile bituminous coal and a lignite coal. The reactor was maintained at 1200 °C while the overall stoichiometric ratio was kept constant at 1.15 for all combustion cases. Measurements were performed to evaluate combustion reactivity, emissions and burn-out. Torrefied biomass fuels in comparison to non-thermally treated wood contain a lower amount of volatiles. For the tests performed at a similar particle size distribution, the reduced volatile content did not impact combustion reactivity significantly. Delay in combustion was only observed for test fuel with a lower amount of fine particles. The particle size distribution of the pulverised grinds therefore impacts combustion reactivity more. Sulphur and nitrogen contents of woody biomass fuels are low. Blending woody biomass with coal lowers the emissions of SO 2 mainly as a result of dilution. NO X emissions have a more complex dependency on the nitrogen content. Factors such as volatile content of the fuels, fuel type, furnace and burner configurations also impact the final NO X emissions. In comparison to unstaged combustion, the nitrogen conversion to NO X declined from 34% to 9% for air-staged co-combustion of torrefied biomass and hard coal. For the air-staged mono-combustion cases, nitrogen conversion to NO X declined from between 42% and 48% to about 10%–14%. - Highlights: • Impact of torrefaction on cofiring was studied at high heating rates in a drop tube. • Cofiring of torrefied biomasses at high thermal shares (50% and higher) is feasible. • Particle size impacts biomass combustion reactivity more than torrefaction. • In a drop tube reactor, torrefaction has no negative

Staged combustion - main method for suppressing nitrogen oxides in pulverized-coal fired boilers

Energy Technology Data Exchange (ETDEWEB)

Kotler, V.R. (Vsesoyuznyi Teplotekhnicheskii Institut (USSR))

1989-08-01

Describes principles behind staged combustion, which is based on organizing furnace operations so that only part of the air from the fuel is taken into the furnace. The remaining air, which is needed for combustion, is fed as a tertiary blast jet into the intermediate flame zone. Following inflammation and combustion of the volatile matter, the oxygen concentration in the flame drops sharply causing a retardation of the oxidation reactions forming NO and an intensification of the reactions causing the nitrogen-containing radicals NH{sub i} and CN to be converted into N{sub 2}. When the reducing agents CO, H{sub 2} and CH{sub 4} are present in certain flame zones, even the nitrogen oxide is reduced to N{sub 2}. The NO concentrations in the flame are reduced until the jet of tertiary air is introduced. Discusses with reference to practice in the USA and Western Europe how to achieve maximum effect of this method for different types of boiler and presents the results of observations of the introduction of staged combustion to the BKZ-210-140 boiler burning Kuznetsk gassy coal. 5 refs.

Effects of biomass on dynamics of combustion in circulating fluidized beds

Directory of Open Access Journals (Sweden)

Tourunen Antti

2004-01-01

Full Text Available Fluidized bed technology is very suitable for the combustion of biomass Nevertheless substitution of coal with biomass affects boiler operation and especially dynamics and controllability. Non-homogeneity of biomass and fuel feeding disturbances cause process instability, such as variations in temperatures and pressures, which reduce lifetime of equipment and structures. Because of process instability higher air coefficient must be used in order to avoid CO emissions, which is not economical. Combustion profiles for coal, wood and peat, measured at the VTT Processes Pilot circulating fluidized bed reactor, have been compared. Process stability and char inventories have been studied by the measurements and the model. Biofuel are usually very reactive and their combustion profiles are quite different compared to coals. Because of high reactivity and low char content combustion process with biofuel is very sensitive for fuel feeding. Also low char inventory effect on load changes combined with combustion profile that differs from coals. Because of different combustion profile heat transfer can be a limiting factor in load changes despite the high reactivity and fast oxygen response.

Effect of injection timing on combustion and performance of a direct injection diesel engine running on Jatropha methyl ester

Energy Technology Data Exchange (ETDEWEB)

Jindal, S. [Mechanical Engineering Department, College of Technology & Engineering, Maharana Pratap University of Agriculture and Technology, Udaipur 313001 (India)

2011-07-01

The present study aims at evaluation of effect of injection timing on the combustion, performance and emissions of a small power diesel engine, commonly used for agriculture purpose, running on pure biodiesel, prepared from Jatropha (Jatropha curcas) vegetable oil. The effect of varying injection timing was evaluated in terms of thermal efficiency, specific fuel consumption, power and mean effective pressure, exhaust temperature, cylinder pressure, rate of pressure rise and the heat release rate. It was found that retarding the injection timing by 3 degrees enhances the thermal efficiency by about 8 percent.

Impaired mitochondrial respiration and protein nitration in the rat hippocampus after acute inhalation of combustion smoke

International Nuclear Information System (INIS)

Lee, Heung M.; Reed, Jason; Greeley, George H.; Englander, Ella W.

2009-01-01

Survivors of massive inhalation of combustion smoke endure critical injuries, including lasting neurological complications. We have previously reported that acute inhalation of combustion smoke disrupts the nitric oxide homeostasis in the rat brain. In this study, we extend our findings and report that a 30-minute exposure of awake rats to ambient wood combustion smoke induces protein nitration in the rat hippocampus and that mitochondrial proteins are a sensitive nitration target in this setting. Mitochondria are central to energy metabolism and cellular signaling and are critical to proper cell function. Here, analyses of the mitochondrial proteome showed elevated protein nitration in the course of a 24-hour recovery following exposure to smoke. Mass spectrometry identification of several significantly nitrated mitochondrial proteins revealed diverse functions and involvement in central aspects of mitochondrial physiology. The nitrated proteins include the ubiquitous mitochondrial creatine kinase, F1-ATP synthase α subunit, dihydrolipoamide dehydrogenase (E3), succinate dehydrogenase Fp subunit, and voltage-dependent anion channel (VDAC1) protein. Furthermore, acute exposure to combustion smoke significantly compromised the respiratory capacity of hippocampal mitochondria. Importantly, elevated protein nitration and reduced mitochondrial respiration in the hippocampus persisted beyond the time required for restoration of normal oxygen and carboxyhemoglobin blood levels after the cessation of exposure to smoke. Thus, the time frame for intensification of the various smoke-induced effects differs between blood and brain tissues. Taken together, our findings suggest that nitration of essential mitochondrial proteins may contribute to the reduction in mitochondrial respiratory capacity and underlie, in part, the brain pathophysiology after acute inhalation of combustion smoke

The emissions of VOCs during co-combustion of coal with different waste materials in a fluidized bed

Energy Technology Data Exchange (ETDEWEB)

I. Gulyurtlu; P. Abelha; A. Gregorio; A. Garcia-Garcia; D. Boavida; A. Crujeira; I. Cabrita [DEECA-INETI, Lisbon (Portugal)

2004-06-01

The combustion of different fuels gives rise to the formation of small but appreciable amounts of volatile organic compounds (VOCs). They basically result from incomplete combustion and their emissions have negative repercussions on health and on the environment in general. As their measurement is difficult, costly, and very time-consuming, very little is reported on the emissions of VOCs from combustion installations. In this study, various blends of two different coals with several wastes were burned in a pilot-scale fluidized bed combustor and measurements of VOCs at several locations along the combustor height as well as just before the stack were carried out. The results demonstrate that the parameters important for the formation of VOCs are temperature, excess air levels, and the effectiveness of the mixing of air with fuel. Furthermore, it was observed that coal was the principal source of VOCs, but the combustion of volatiles from fuels such as biomass, occurring in the freeboard, was important in reducing the emissions of VOCs to almost zero. 8 refs., 6 figs., 6 tabs.

Chemical looping combustion: A new low-dioxin energy conversion technology.

Science.gov (United States)

Hua, Xiuning; Wang, Wei

2015-06-01

Dioxin production is a worldwide concern because of its persistence and carcinogenic, teratogenic, and mutagenic effects. The pyrolysis-chemical looping combustion process of disposing solid waste is an alternative to traditional solid waste incineration developed to reduce the dioxin production. Based on the equilibrium composition of the Deacon reaction, pyrolysis gas oxidized by seven common oxygen carriers, namely, CuO, NiO, CaSO4, CoO, Fe2O3, Mn3O4, and FeTiO3, is studied and compared with the pyrolysis gas directly combusted by air. The result shows that the activity of the Deacon reaction for oxygen carriers is lower than that for air. For four typical oxygen carriers (CuO, NiO, Fe2O3, and FeTiO3), the influences of temperature, pressure, gas composition, and tar on the Deacon reaction are discussed in detail. According to these simulation results, the dioxin production in China, Europe, the United States, and Japan is predicted for solid waste disposal by the pyrolysis-chemical looping combustion process. Thermodynamic analysis results in this paper show that chemical looping combustion can reduce dioxin production in the disposal of solid waste. Copyright © 2015. Published by Elsevier B.V.

Modeling the internal combustion engine

Science.gov (United States)

Zeleznik, F. J.; Mcbride, B. J.

1985-01-01

A flexible and computationally economical model of the internal combustion engine was developed for use on large digital computer systems. It is based on a system of ordinary differential equations for cylinder-averaged properties. The computer program is capable of multicycle calculations, with some parameters varying from cycle to cycle, and has restart capabilities. It can accommodate a broad spectrum of reactants, permits changes in physical properties, and offers a wide selection of alternative modeling functions without any reprogramming. It readily adapts to the amount of information available in a particular case because the model is in fact a hierarchy of five models. The models range from a simple model requiring only thermodynamic properties to a complex model demanding full combustion kinetics, transport properties, and poppet valve flow characteristics. Among its many features the model includes heat transfer, valve timing, supercharging, motoring, finite burning rates, cycle-to-cycle variations in air-fuel ratio, humid air, residual and recirculated exhaust gas, and full combustion kinetics.

Particle Emissions from Biomass Combustion

Energy Technology Data Exchange (ETDEWEB)

Szpila, Aneta; Bohgard, Mats [Lund Inst. of Technology (Sweden). Div. of Ergonomics and Aerosol Technology; Strand, Michael; Lillieblad, Lena; Sanati, Mehri [Vaexjoe Univ. (Sweden). Div. of Bioenergy Technology; Pagels, Joakim; Rissler, Jenny; Swietlicki, Erik; Gharibi, Arash [Lund Univ. (Sweden). Div. of Nuclear Physics

2003-05-01

We have shown that high concentrations of fine particles of the order of 2-7x10{sup -7} particles per cm{sup 3} are being formed in all the combustion units studied. There was a higher difference between the units in terms of particle mass concentrations. While the largest differences was found for gas-phase constituents (CO and THC) and polyaromatic hydrocarbons. In 5 out of 7 studied units, multi-cyclones were the only measure for flue-gas separation. The multicyclones had negligible effect on the particle number concentration and a small effect on the mass of particles smaller than 5 {mu}m. The separation efficiency was much higher for the electrostatic precipitators. The boiler load had a dramatic influence on the coarse mode concentration during combustion of forest residue. PM0.8-6 increased from below 5 mg/m{sup 3} to above 50 mg/m{sup 3} even at a moderate change in boiler load from medium to high. A similar but less pronounced trend was found during combustion of dry wood. PM0.8-PM6 increased from 12 to 23 mg/m{sup 3} when the load was changed from low to high. When increasing the load, the primary airflow taken through the grate is increased; this itself may lead to a higher potential of the air stream to carry coarse particles away from the combustion zone. Measurements with APS-instrument with higher time-resolution showed a corresponding increase in coarse mode number concentration with load. Additional factor influencing observed higher concentration of coarse mode during combustion of forest residues, could be relatively high ash content in this type of fuel (2.2 %) in comparison to dry wood (0.3 %) and pellets (0.5 %). With increasing load we also found a decrease in PM1 during combustion of forest residue. Whether this is caused by scavenging of volatilized material by the high coarse mode concentration or a result of a different amount of volatilized material available for formation of fine particles needs to be shown in future studies. The

Increase in efficiency and reduction of generation cost at hard coal-fired power plants. Post-combustion of combustion residues from co-firing of RDF and biomass during dry ash removal

Energy Technology Data Exchange (ETDEWEB)

Baur, Guenter [Magaldi Power GmbH, Esslingen (Germany); Spindeldreher, Olaf [RWE Generation SE, Werne (Germany); RWE Generation SE, Essen (Germany)

2013-09-01

Secondary as well as substitute fuels are being used in hard coal-fired power plants to improve efficiency and to enlarge fuel flexibility. However, grinding and firing systems of the existing coal-fired plants are not designed for those co-fuels. Any deterioration of the combustion performance would reduce the power output and increase ash disposal costs by increased content of combustion residues. The application of air-cooled ash removal, with simultaneous and controlled post-combustion of unburned residues on the conveyor belt, enlarges the furnace and maintains combustion efficiency even with different fuel qualities. Plant efficiency can also be increased through heat recovery. (orig.)

Energy efficiency impact of EGR on organizing clean combustion in diesel engines

International Nuclear Information System (INIS)

Divekar, Prasad S.; Chen, Xiang; Tjong, Jimi; Zheng, Ming

2016-01-01

Highlights: • Studied EGR impact on efficiency and emissions of diesel and dual-fuel combustion. • Quantified effectiveness of intake dilution for NOx reduction using EGR. • Identified suitable EGR ranges for mitigating emissions–efficiency trade-off. • Developed careful control of intake dilution and in-cylinder excess ratio. • Enabled ultra-low NOx in both diesel and dual-fuel combustion via EGR control. - Abstract: Exhaust gas recirculation (EGR) is a commonly recognized primary technique for reducing NOx emissions in IC engines. However, depending on the extent of its use, the application of EGR in diesel engines is associated with an increase in smoke emissions and a reduction in thermal efficiency. In this work, empirical investigations and parametric analyses are carried out to assess the impact of EGR in attaining ultra-low NOx emissions while minimizing the smoke and efficiency penalties. Two fuelling strategies are studied, namely diesel-only injection and dual-fuel injection. In the dual-fuel strategy, a high volatility liquid fuel is injected into the intake ports, and a diesel fuel is injected directly into the cylinder. The results suggest that the reduction in NOx can be directly correlated with the intake dilution caused by EGR and the correlation is largely independent of the fuelling strategy, the intake boost, and the engine load level. Simultaneously ultra-low NOx and smoke emissions can be achieved at high intake boost and intake dilution levels in the diesel-only combustion strategy and at high ethanol fractions in the dual-fuel strategy. The efficiency penalty associated with EGR is attributed to two primary factors; the combustion off-phasing and the reduction in combustion efficiency. The combustion off-phasing can be minimized by the closed loop control of the diesel injection timing in both the fuelling strategies, whereas the combustion efficiency can be improved by limiting the intake dilution to moderate levels. The

Modeling the effects of auxiliary gas injection and fuel injection rate shape on diesel engine combustion and emissions

Science.gov (United States)

Mather, Daniel Kelly

1998-11-01

The effect of auxiliary gas injection and fuel injection rate-shaping on diesel engine combustion and emissions was studied using KIVA a multidimensional computational fluid dynamics code. Auxiliary gas injection (AGI) is the injection of a gas, in addition to the fuel injection, directly into the combustion chamber of a diesel engine. The objective of AGI is to influence the diesel combustion via mixing to reduce emissions of pollutants (soot and NO x). In this study, the accuracy of modeling high speed gas jets on very coarse computational grids was addressed. KIVA was found to inaccurately resolve the jet flows near walls. The cause of this inaccuracy was traced to the RNG k - ɛ turbulence model with the law-of-the-wall boundary condition used by KIVA. By prescribing the lengthscale near the nozzle exit, excellent agreement between computed and theoretical jet penetration was attained for a transient gas jet into a quiescent chamber at various operating conditions. The effect of AGI on diesel engine combustion and emissions was studied by incorporating the coarse grid gas jet model into a detailed multidimensional simulation of a Caterpillar 3401 heavy-duty diesel engine. The effects of AGI timing, composition, amount, orientation, and location were investigated. The effects of AGI and split fuel injection were also investigated. AGI was found to be effective at reducing soot emissions by increasing mixing within the combustion chamber. AGI of inert gas was found to be effective at reducing emissions of NOx by depressing the peak combustion temperatures. Finally, comparison of AGI simulations with experiments were conducted for a TACOM-LABECO engine. The results showed that AGI improved soot oxidation throughout the engine cycle. Simulation of fuel injection rate-shaping investigated the effects of three injection velocity profiles typical of unit-injector type, high-pressure common-rail type, and accumulator-type fuel injectors in the Caterpillar 3401 heavy

Combustion of environmentally altered molybdenum trioxide nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Moore, Kevin; Pantoya, Michelle L. [Mechanical Engineering Department, Texas Tech University, 2500 Broadway, Lubbock, TX 79409 (United States)

2006-06-15

Nanocomposite thermite mixtures are currently under development for many primer applications due to their high energy densities, high ignition sensitivity, and low release of toxins into the environment. However, variability and inconsistencies in combustion performance have not been sufficiently investigated. Environmental interactions with the reactants are thought to be a contributing factor to these variabilities. Combustion velocity experiments were conducted on aluminum (Al) and molybdenum trioxide (MoO{sub 3}) mixtures to investigate the role of environmental interactions such as light exposure and humidity. While the Al particles were maintained in an ambient, constant environment, the MoO{sub 3} particles were exposed to UV or fluorescent light, and highly humid environments. Results show that UV and fluorescent lighting over a period of days does not significantly contribute to performance deterioration. However, a humid environment severely decreases combustion performance if the oxidizer particles are not heat-treated. Heat treatment of the MoO{sub 3} greatly increases the material's ability to resist water absorption, yielding more repeatable combustion performance. This work further quantifies the role of the environment in the decrease of combustion performance of nanocomposites over time. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

Testing fireproof materials in a combustion chamber

Directory of Open Access Journals (Sweden)

Kulhavy Petr

2017-01-01

Full Text Available This article deals with a prototype concept, real experiment and numerical simulation of a combustion chamber, designed for testing fire resistance some new insulating composite materials. This concept of a device used for testing various materials, providing possibility of monitoring temperatures during controlled gas combustion. As a fuel for the combustion process propane butane mixture has been used and also several kinds of burners with various conditions of inlet air (forced, free and fuel flows were tested. The tested samples were layered sandwich materials based on various materials or foams, used as fillers in fire shutters. The temperature distribution was measured by using thermocouples. A simulation of whole concept of experimental chamber has been carried out as the non-premixed combustion process in the commercial final volume sw Pyrosim. The result was to design chamber with a construction suitable, according to the international standards, achieve the required values (temperature in time. Model of the combustion based on a stoichiometric defined mixture of gas and the tested layered samples showed good conformity with experimental results – i.e. thermal distribution inside and heat release rate that has gone through the sample.

Reduced ash-related operational problems by co-combustion peat and agricultural fuels; Minskade askrelaterade driftsproblem genom inblandning av torv i aakerbraenslen

Energy Technology Data Exchange (ETDEWEB)

Oehman, Marcus; Bostroem, Dan; Skoglund, Nils; Grimm, Alejandro; Boman, Christoffer; Kofod-Hansen, Marie

2010-06-15

The objectives of the project were: To determine the admixing levels for different peat classes to various energy crops (straw, Salix and Reed canary grass) that are required to reach positive effects regarding slagging, deposit formation/(high temperature corrosion) and bed agglomeration; and, To demonstrate the possibilities to reduce the occurrence of ash related operational problems in combustion of energy crops upon admixing peat. Operational experiences and research of effects of co-firing peat and energy crops are scarce. Some previous tests in bench scale indicated though, on a strong reduction of the agglomeration tendency and lowering of the agglomeration temperature for straw and Salix at a peat admixing level corresponding to 15 - 20 weight% (on DS basis). A reduction in the amount of emitted fine particles was also observed in these experiments. However, care must be taken in the choice of peat. Some Carex dominated peats with high Si contents may cause problems with slagging. Another conclusion from the mentioned bench scale tests was that peats with relative high Ca/Si ratios should be selected to minimize the risk of slagging and bed agglomeration. Thermochemical modelling was performed to determine the effects of peat admixture, on slagging-, deposit formation- (corrosion)- and bed agglomeration tendencies during combustion of straw, willow and reed canary grass with high and low ash content. These results and previously conducted bench scale experiments were used as a basis for determining combinations of fuel and peat admixtures for the demonstration experiments. The calculations were performed with admixing levels of 0-, 5-, 15, 25-, and 40 weight% (on DS basis) of four peat samples to the investigated four crop fuels. The used peat samples were typical carex-containing Swedish peat with differences in e.g. silicon-, calcium- and sulfur contents. A number of the model calculations were qualitatively validated against previously conducted

Experimental study on fuel economies and emissions of direct-injection premixed combustion engine fueled with gasoline/diesel blends

International Nuclear Information System (INIS)

Du, Jiakun; Sun, Wanchen; Guo, Liang; Xiao, Senlin; Tan, Manzhi; Li, Guoliang; Fan, Luyan

2015-01-01

Highlights: • A compound combustion concept was proposed and investigated. • Premixed combustion near the top dead center was investigated using blended fuels. • Increasing gasoline blend ratio was found to enhance the mixture preparation. • Too much addition of gasoline decreases indicated thermal efficiency. • Gasoline/diesel blends may be a promising alternative for premixed combustion. - Abstract: The effects of gasoline/diesel blended fuel composed of diesel fuel with gasoline as additives in volume basis, on combustion, fuel economies and exhaust emissions were experimentally investigated. Tests were carried out based on a turbocharged Common-rail Direct Injection engine at a constant engine speed of 1800 r/min and different loads of 3.2 bar, 5.1 bar Indicated Mean Effective Pressure. Additionally, the effect of combustion phasing and Exhaust Gas Recirculation were evaluated experimentally for various fuels. The results indicated that with the fraction of gasoline increasing in blends, the ignition delay was prolonged and the combustion phasing was retarded with the common injection timing. This led to a significant increase of premixed burning phase, which was in favor of smoke reduction; although, too much gasoline might be adverse to fuel consumption. An optimum combustion phasing was identified, leading to a higher thermal efficiency and better premixed combustion with blended fuels. A combined application of Exhaust Gas Recirculation and blended fuel with a high gasoline fraction was confirmed effective in reducing the oxides of nitrogen and smoke emissions simultaneously at the optimum combustion phasing without giving significant penalty of fuel consumption. A compound combustion mode with its emission lower than the conventional Compression Ignition engines, and efficiency higher than the typical Spark Ignition engines, could be achieved with a cooperative control of Exhaust Gas Recirculation and combustion phasing of the gasoline

Effects of ethanol added fuel on exhaust emissions and combustion in a premixed charge compression ignition diesel engine

Directory of Open Access Journals (Sweden)

Kim Yungjin

2015-01-01

Full Text Available The use of diesel engines for vehicle has been increasing recently due to its higher thermal efficiency and lower CO2 emission level. However, in the case of diesel engine, NOx increases in a high temperature combustion region and particulate matter is generated in a fuel rich region. Therefore, the technique of PCCI (premixed charge compression ignition is often studied to get the peak combustion temperature down and to make a better air-fuel mixing. However it also has got a limited operating range and lower engine power produced by the wall wetting and the difficulty of the ignition timing control. In this research, the effect of injection strategies on the injected fuel behavior, combustion and emission characteristics in a PCCI engine were investigated to find out the optimal conditions for fuel injection, and then ethanol blended diesel fuel was used to control the ignition timing. As a result, the combustion pressures and ROHR (rate of heat release of the blended fuel became lower, however, IMEP showed fewer differences. Especially in the case of triple injection, smoke could be reduced a little and NOx emission decreased a lot by using the ethanol blended fuel simultaneously without much decreasing of IMEP compared to the result of 100% diesel fuel.

Advanced Diagnostics in Oxy-Fuel Combustion Processes

DEFF Research Database (Denmark)

Brix, Jacob; Toftegaard, Maja Bøg; Clausen, Sønnik

This report sums up the findings in PSO-project 010069, “Advanced Diagnostics in Oxy- Fuel Combustion Processes”. Three areas of optic diagnostics are covered in this work: - FTIR measurements in a 30 kW swirl burner. - IR measurements in a 30 kW swirl burner. - IR measurements in a laboratory...... technique was an invaluable tool in the discussion of data obtained by gas analysis, and it allowed for estimation of combustion times in O2/CO2 where the high CO2 concentration prevents the use of the carbon mass balance for that purpose. During the project the data have been presented at a conference......, formed the basis of a publication and it is part of two PhD dissertations. The name of the conference the journal and the dissertations are listed below. - Joint Meeting of the Scandinavian-Nordic and French Sections of the Combustion Institute, Combustion of Char Particles under Oxy-Fuel Conditions...