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Sample records for reaction front contained

  1. Stability of reaction fronts in random walk simulations

    NARCIS (Netherlands)

    Nagy, Noemi; Izsak, F.

    A model of propagating reaction fronts is given for simple autocatalytic reactions and the stability of the propagating reaction fronts are studied in several numerical experiments. The corresponding random walk simulations - extending of a recent algorithm - make possible the simultaneous treatment

  2. Propagating fronts in reaction-transport systems with memory

    Energy Technology Data Exchange (ETDEWEB)

    Yadav, A. [Department of Chemistry, Southern Methodist University, Dallas, TX 75275-0314 (United States)], E-mail: ayadav1@lsu.edu; Fedotov, Sergei [School of Mathematics, University of Manchester, Manchester M60 1DQ (United Kingdom)], E-mail: sergei.fedotov@manchester.ac.uk; Mendez, Vicenc [Grup de Fisica Estadistica, Departament de Fisica, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain)], E-mail: vicenc.mendez@uab.es; Horsthemke, Werner [Department of Chemistry, Southern Methodist University, Dallas, TX 75275-0314 (United States)], E-mail: whorsthe@smu.edu

    2007-11-26

    In reaction-transport systems with non-standard diffusion, the memory of the transport causes a coupling of reactions and transport. We investigate the effect of this coupling for systems with Fisher-type kinetics and obtain a general analytical expression for the front speed. We apply our results to the specific case of subdiffusion.

  3. Multiple Scale Reaction-Diffusion-Advection Problems with Moving Fronts

    Science.gov (United States)

    Nefedov, Nikolay

    2016-06-01

    In this work we discuss the further development of the general scheme of the asymptotic method of differential inequalities to investigate stability and motion of sharp internal layers (fronts) for nonlinear singularly perturbed parabolic equations, which are called in applications reaction-diffusion-advection equations. Our approach is illustrated for some new important cases of initial boundary value problems. We present results on stability and on the motion of the fronts.

  4. Reaction-diffusion fronts with inhomogeneous initial conditions

    Energy Technology Data Exchange (ETDEWEB)

    Bena, I [Departement de Physique Theorique, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Droz, M [Departement de Physique Theorique, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Martens, K [Departement de Physique Theorique, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Racz, Z [Institute for Theoretical Physics, Eoetvoes University, 1117 Budapest (Hungary)

    2007-02-14

    Properties of reaction zones resulting from A+B {yields} C type reaction-diffusion processes are investigated by analytical and numerical methods. The reagents A and B are separated initially and, in addition, there is an initial macroscopic inhomogeneity in the distribution of the B species. For simple two-dimensional geometries, exact analytical results are presented for the time evolution of the geometric shape of the front. We also show using cellular automata simulations that the fluctuations can be neglected both in the shape and in the width of the front.

  5. Finite-time barriers to reaction front propagation

    Science.gov (United States)

    Locke, Rory; Mahoney, John; Mitchell, Kevin

    2015-11-01

    Front propagation in advection-reaction-diffusion systems gives rise to rich geometric patterns. It has been shown for time-independent and time-periodic fluid flows that invariant manifolds, termed burning invariant manifolds (BIMs), serve as one-sided dynamical barriers to the propagation of reaction front. More recently, theoretical work has suggested that one-sided barriers, termed burning Lagrangian Coherent structures (bLCSs), exist for fluid velocity data prescribed over a finite time interval, with no assumption on the time-dependence of the flow. In this presentation, we use a time-varying fluid ``wind'' in a double-vortex channel flow to demonstrate that bLCSs form the (locally) most attracting or repelling fronts.

  6. Field theory of propagating reaction-diffusion fronts

    International Nuclear Information System (INIS)

    Escudero, C.

    2004-01-01

    The problem of velocity selection of reaction-diffusion fronts has been widely investigated. While the mean-field limit results are well known theoretically, there is a lack of analytic progress in those cases in which fluctuations are to be taken into account. Here, we construct an analytic theory connecting the first principles of the reaction-diffusion process to an effective equation of motion via field-theoretic arguments, and we arrive at results already confirmed by numerical simulations

  7. Front propagation in Rayleigh-Taylor systems with reaction

    International Nuclear Information System (INIS)

    Scagliarini, A; Biferale, L; Sbragaglia, M; Mantovani, F; Pivanti, M; Schifano, S F; Tripiccione, R; Pozzati, F; Toschi, F

    2011-01-01

    A special feature of Rayleigh-Taylor systems with chemical reactions is the competition between turbulent mixing and the 'burning processes', which leads to a highly non-trivial dynamics. We studied the problem performing high resolution numerical simulations of a 2d system, using a thermal lattice Boltzmann (LB) model. We spanned the various regimes emerging at changing the relative chemical/turbulent time scales, from slow to fast reaction; in the former case we found numerical evidence of an enhancement of the front propagation speed (with respect to the laminar case), providing a phenomenological argument to explain the observed behaviour. When the reaction is very fast, instead, the formation of sharp fronts separating patches of pure phases, leads to an increase of intermittency in the small scale statistics of the temperature field.

  8. Reaction-Transport Systems Mesoscopic Foundations, Fronts, and Spatial Instabilities

    CERN Document Server

    Horsthemke, Werner; Mendez, Vicenc

    2010-01-01

    This book is an introduction to the dynamics of reaction-diffusion systems, with a focus on fronts and stationary spatial patterns. Emphasis is on systems that are non-standard in the sense that either the transport is not simply classical diffusion (Brownian motion) or the system is not homogeneous. A important feature is the derivation of the basic phenomenological equations from the mesoscopic system properties. Topics addressed include transport with inertia, described by persistent random walks and hyperbolic reaction-transport equations and transport by anomalous diffusion, in particular subdiffusion, where the mean square displacement grows sublinearly with time. In particular reaction-diffusion systems are studied where the medium is in turn either spatially inhomogeneous, compositionally heterogeneous or spatially discrete. Applications span a vast range of interdisciplinary fields and the systems considered can be as different as human or animal groups migrating under external influences, population...

  9. Fluid flow and reaction fronts: characterization of physical processes at the microscale using SEM analyses

    Science.gov (United States)

    Beaudoin, Nicolas; Koehn, Daniel; Toussaint, Renaud; Gomez-Rivas, Enrique; Bons, Paul; Chung, Peter; Martín-Martín, Juan Diego

    2014-05-01

    Fluid migrations are the principal agent for mineral replacement in the upper crust, leading to dramatic changes in the porosity and permeability of rocks over several kilometers. Consequently, a better understanding of the physical parameters leading to mineral replacement is required to better understand and model fluid flow and rock reservoir properties. Large-scale dolostone bodies are one of the best and most debated examples of such fluid-related mineral replacement. These formations received a lot of attention lately, and although genetic mechanics and implications for fluid volume are understood, the mechanisms controlling the formation and propagation of the dolomitization reaction front remain unclear. This contribution aims at an improvement of the knowledge about how this replacement front propagates over space and time. We study the front sharpness on hand specimen and thin section scale and what the influence of advection versus diffusion of material is on the front development. In addition, we demonstrate how preexisting heterogeneities in the host rock affect the propagation of the reaction front. The rock is normally not homogeneous but contains grain boundaries, fractures and stylolites, and such structures are important on the scale of the front width. Using Scanning Electron Microscopy and Raman Spectroscopy we characterized the reaction front chemistry and morphology in different context. Specimens of dolomitization fronts, collected from carbonate sequences of the southern Maestrat Basin, Spain and the Southwestern Scottish Highlands suggest that the front thickness is about several mm being relatively sharp. Fluid infiltrated grain boundaries and fractures forming mm-scale transition zone. We study the structure of the reaction zone in detail and discuss implications for fluid diffusion-advection models and mineral replacement. In addition we formulate a numerical model taking into account fluid flow, diffusion and advection of the mobile

  10. Reaction Front Evolution during Electrochemical Lithiation of Crystalline Silicon Nanopillars

    KAUST Repository

    Lee, Seok Woo

    2012-12-01

    The high theoretical specific capacity of Si as an anode material is attractive in lithium-ion batteries, although the issues caused by large volume changes during cycling have been a major challenge. Efforts have been devoted to understanding how diffusion-induced stresses cause fracture, but recent observations of anisotropic volume expansion in single-crystalline Si nanostructures require new theoretical considerations of expansion behavior during lithiation. Further experimental investigation is also necessary to better understand the anisotropy of the lithiation process. Here, we present a method to reveal the crystalline core of partially lithiated Si nanopillars with three different crystallographic orientations by using methanol to dissolve the Li atoms from the amorphous Li-Si alloy. The exposed crystalline cores have flat {110} surfaces at the pillar sidewalls; these surfaces represent the position of the reaction front between the crystalline core and the amorphous Li-Si alloy. It was also found that an amorphous Si structure remained on the flat surfaces of the crystalline core after dissolution of the Li, which was presumed to be caused by the accumulation of Si atoms left over from the removal of Li from the Li-Si alloy. © 2012 Wiley-VCH Verlag GmbH &Co. KGaA, Weinheim.

  11. Reaction Front Evolution during Electrochemical Lithiation of Crystalline Silicon Nanopillars

    KAUST Repository

    Lee, Seok Woo; Berla, Lucas A.; McDowell, Matthew T.; Nix, William D.; Cui, Yi

    2012-01-01

    The high theoretical specific capacity of Si as an anode material is attractive in lithium-ion batteries, although the issues caused by large volume changes during cycling have been a major challenge. Efforts have been devoted to understanding how diffusion-induced stresses cause fracture, but recent observations of anisotropic volume expansion in single-crystalline Si nanostructures require new theoretical considerations of expansion behavior during lithiation. Further experimental investigation is also necessary to better understand the anisotropy of the lithiation process. Here, we present a method to reveal the crystalline core of partially lithiated Si nanopillars with three different crystallographic orientations by using methanol to dissolve the Li atoms from the amorphous Li-Si alloy. The exposed crystalline cores have flat {110} surfaces at the pillar sidewalls; these surfaces represent the position of the reaction front between the crystalline core and the amorphous Li-Si alloy. It was also found that an amorphous Si structure remained on the flat surfaces of the crystalline core after dissolution of the Li, which was presumed to be caused by the accumulation of Si atoms left over from the removal of Li from the Li-Si alloy. © 2012 Wiley-VCH Verlag GmbH &Co. KGaA, Weinheim.

  12. Asymptotic analysis of reaction-diffusion-advection problems: Fronts with periodic motion and blow-up

    Science.gov (United States)

    Nefedov, Nikolay

    2017-02-01

    This is an extended variant of the paper presented at MURPHYS-HSFS 2016 conference in Barcelona. We discuss further development of the asymptotic method of differential inequalities to investigate existence and stability of sharp internal layers (fronts) for nonlinear singularly perturbed periodic parabolic problems and initial boundary value problems with blow-up of fronts for reaction-diffusion-advection equations. In particular, we consider periodic solutions with internal layer in the case of balanced reaction. For the initial boundary value problems we prove the existence of fronts and give their asymptotic approximation including the new case of blowing-up fronts. This case we illustrate by the generalised Burgers equation.

  13. Curved fronts in the Belousov-Zhabotinskii reaction-diffusion systems in R2

    Science.gov (United States)

    Niu, Hong-Tao; Wang, Zhi-Cheng; Bu, Zhen-Hui

    2018-05-01

    In this paper we consider a diffusion system with the Belousov-Zhabotinskii (BZ for short) chemical reaction. Following Brazhnik and Tyson [4] and Pérez-Muñuzuri et al. [45], who predicted V-shaped fronts theoretically and discovered V-shaped fronts by experiments respectively, we give a rigorous mathematical proof of their results. We establish the existence of V-shaped traveling fronts in R2 by constructing a proper supersolution and a subsolution. Furthermore, we establish the stability of the V-shaped front in R2.

  14. Coronal mass ejection shock fronts containing the two types of intermediate shocks

    International Nuclear Information System (INIS)

    Steinolfson, R.S.; Hundhausen, A.J.

    1990-01-01

    Numerical solutions of the time-dependent, magnetohydrodynamic (MHD) equations in two dimensions are used to demonstrate the formation of both types of intermediate shocks in a single shock front for physical conditions that are an idealization of those expected to occur in some observed coronal mass ejections. The key to producing such a shock configuration in the simulations is the use of an initial atmosphere containing a magnetic field representative of that in a coronal streamer with open field lines overlying a region of closed field lines. Previous attempts using just open field lines (perpendicular to the surface) produced shock configurations containing just one of the two intermediate shock types. A schematic of such a shock front containing both intermediate shock types has been constructed previously based solely on the known properties of MHD shocks from the Rankine-Hugoniot equations and specific requirements placed on the shock solution at points along the front where the shock normal and upstream magnetic field are aligned. The shock front also contains, at various locations along the front, a hydrodynamic (nonmagnetic) shock, a switch-on shock, and a fast shock in addition to the intermediate shocks. This particular configuration occurs when the shock front speed exceeds the upstream (preshock) intermediate wave speed but is less than a critical speed defined in the paper (equation 1) along at least some portion of the shock front. A distinctive feature of the front is that it is concave upward (away from the surface) near the region where the field in the preshock plasma is normal to the front of near the central portion of the shock front

  15. Frozen reaction fronts in steady flows: A burning-invariant-manifold perspective

    Science.gov (United States)

    Mahoney, John R.; Li, John; Boyer, Carleen; Solomon, Tom; Mitchell, Kevin A.

    2015-12-01

    The dynamics of fronts, such as chemical reaction fronts, propagating in two-dimensional fluid flows can be remarkably rich and varied. For time-invariant flows, the front dynamics may simplify, settling in to a steady state in which the reacted domain is static, and the front appears "frozen." Our central result is that these frozen fronts in the two-dimensional fluid are composed of segments of burning invariant manifolds, invariant manifolds of front-element dynamics in x y θ space, where θ is the front orientation. Burning invariant manifolds (BIMs) have been identified previously as important local barriers to front propagation in fluid flows. The relevance of BIMs for frozen fronts rests in their ability, under appropriate conditions, to form global barriers, separating reacted domains from nonreacted domains for all time. The second main result of this paper is an understanding of bifurcations that lead from a nonfrozen state to a frozen state, as well as bifurcations that change the topological structure of the frozen front. Although the primary results of this study apply to general fluid flows, our analysis focuses on a chain of vortices in a channel flow with an imposed wind. For this system, we present both experimental and numerical studies that support the theoretical analysis developed here.

  16. Simultaneous fingering, double-diffusive convection, and thermal plumes derived from autocatalytic exothermic reaction fronts

    Science.gov (United States)

    Eskew, Matthew W.; Harrison, Jason; Simoyi, Reuben H.

    2016-11-01

    Oxidation reactions of thiourea by chlorite in a Hele-Shaw cell are excitable, autocatalytic, exothermic, and generate a lateral instability upon being triggered by the autocatalyst. Reagent concentrations used to develop convective instabilities delivered a temperature jump at the wave front of 2.1 K. The reaction zone was 2 mm and due to normal cooling after the wave front, this generated a spike rather than the standard well-studied front propagation. The reaction front has solutal and thermal contributions to density changes that act in opposite directions due to the existence of a positive isothermal density change in the reaction. The competition between these effects generates thermal plumes. The fascinating feature of this system is the coexistence of plumes and fingering in the same solution which alternate in frequency as the front propagates, generating hot and cold spots within the Hele-Shaw cell, and subsequently spatiotemporal inhomogeneities. The small ΔT at the wave front generated thermocapillary convection which competed effectively with thermogravitational forces at low Eötvös Numbers. A simplified reaction-diffusion-convection model was derived for the system. Plume formation is heavily dependent on boundary effects from the cell dimensions. This work was supported by Grant No. CHE-1056366 from the NSF and a Research Professor Grant from the University of KwaZulu-Natal.

  17. Time behaviour of the reaction front in the catalytic A + B → B + C reaction-diffusion processes

    International Nuclear Information System (INIS)

    Nicolini, F.G.; Rodriguez, M.A.; Wio, H.S.

    1994-07-01

    The problem of the time evolution of the position and width of a reaction front between initially separated reactants for the catalytic reaction A + B → B + C (C inert) is treated within a recently introduced Galanin-like scheme. (author). 6 refs

  18. The influence of cricket fast bowlers' front leg technique on peak ground reaction forces.

    Science.gov (United States)

    Worthington, Peter; King, Mark; Ranson, Craig

    2013-01-01

    High ground reaction forces during the front foot contact phase of the bowling action are believed to be a major contributor to the high prevalence of lumbar stress fractures in fast bowlers. This study aimed to investigate the influence of front leg technique on peak ground reaction forces during the delivery stride. Three-dimensional kinematic data and ground reaction forces during the front foot contact phase were captured for 20 elite male fast bowlers. Eight kinematic parameters were determined for each performance, describing run-up speed and front leg technique, in addition to peak force and time to peak force in the vertical and horizontal directions. There were substantial variations between bowlers in both peak forces (vertical 6.7 ± 1.4 body weights; horizontal (braking) 4.5 ± 0.8 body weights) and times to peak force (vertical 0.03 ± 0.01 s; horizontal 0.03 ± 0.01 s). These differences were found to be linked to the orientation of the front leg at the instant of front foot contact. In particular, a larger plant angle and a heel strike technique were associated with lower peak forces and longer times to peak force during the front foot contact phase, which may help reduce the likelihood of lower back injuries.

  19. A simplified pyrolysis model of a biomass particle based on infinitesimally thin reaction front approximation

    NARCIS (Netherlands)

    Haseli, Y.; Oijen, van J.A.; Goey, de L.P.H.

    2012-01-01

    This paper presents a simplified model for prediction of pyrolysis of a biomass particle. The main assumptions include (1) decomposition of virgin material in an infinitesimal thin reaction front at a constant pyrolysis temperature, (2) constant thermo-physical properties throughout the process,

  20. Droplet heat transfer and chemical reactions during direct containment heating

    International Nuclear Information System (INIS)

    Baker, L. Jr.

    1986-01-01

    A simplified model of heat transfer and chemical reaction has been adapted to evaluate the expected behavior of droplets containing unreacted Zircaloy and stainless steel moving through the containment atmosphere during postulated accidents involving direct containment heating. The model includes internal and external diffusive resistances to reaction. The results indicate that reactions will be incomplete for many conditions characteristic of direct containment heating sequences

  1. The role of grain boundaries and transient porosity increase as fluid pathways for reaction front propagation

    Science.gov (United States)

    Jonas, Laura; John, Timm; Geisler, Thorsten; Putnis, Andrew

    2013-04-01

    The pseudomorphic replacement of Carrara marble by calcium phosphates was studied as a model system to examine the influence of different fluid pathways for reaction front propagation induced by fluid-rock interaction. In this model system, the grain boundaries present in the rock and the transient porosity structures developing throughout the replacement reaction enable the reaction front to progress further into the rock as well as to the center of each single grain until complete transformation. Hydrothermal treatment of the marble using phosphate bearing solutions at temperature levels of 150° C and 200° C for different durations lead to the formation of two product phases which were identified as hydroxyapatite [Ca5(PO4)3OH] as well as β-tricalcium phosphate [β-Ca3(PO4)2] (β-TCP). The formation of β-TCP was probably favored by the presence of ~0.6wt.% of Mg in the parent phase. Completely transformed single grains show a distinctive zoning, both in composition and texture. Whereas areas next to the grain boundary consist of nearly pure hydroxyapatite and show a coarse porosity, areas close to the center of the single grains show a high amount of β-TCP and a very fine porous microstructure. If F was added as an additional solution component, the formation of β-TCP was avoided and up to 3wt.% of F were incorporated into the product apatite. The use of the isotope 18O as a chronometer for the replacement reaction makes it possible to reconstruct the chronological development of the calcium phosphate reaction front. Raman analysis revealed that the incorporation of 18O in the PO4 tetrahedron of hydroxyapatite results in the development of distinct profiles in the calcium phosphate reaction front perpendicular to the grain boundaries of the marble. Through the use of the 18O chronometer, it is possible to estimate and compare the time effectiveness of the different fluid pathways in this model system. The results show that the grain boundaries serve as a

  2. Traveling and Pinned Fronts in Bistable Reaction-Diffusion Systems on Networks

    Science.gov (United States)

    Kouvaris, Nikos E.; Kori, Hiroshi; Mikhailov, Alexander S.

    2012-01-01

    Traveling fronts and stationary localized patterns in bistable reaction-diffusion systems have been broadly studied for classical continuous media and regular lattices. Analogs of such non-equilibrium patterns are also possible in networks. Here, we consider traveling and stationary patterns in bistable one-component systems on random Erdös-Rényi, scale-free and hierarchical tree networks. As revealed through numerical simulations, traveling fronts exist in network-organized systems. They represent waves of transition from one stable state into another, spreading over the entire network. The fronts can furthermore be pinned, thus forming stationary structures. While pinning of fronts has previously been considered for chains of diffusively coupled bistable elements, the network architecture brings about significant differences. An important role is played by the degree (the number of connections) of a node. For regular trees with a fixed branching factor, the pinning conditions are analytically determined. For large Erdös-Rényi and scale-free networks, the mean-field theory for stationary patterns is constructed. PMID:23028746

  3. Interface conditions for fast-reaction fronts in wet porous mineral materials: the case of concrete carbonation

    NARCIS (Netherlands)

    Muntean, A.; Böhm, M.

    2009-01-01

    Reaction–diffusion processes, where slow diffusion balances fast reaction, usually exhibit internal loci where the reactions are concentrated. Some modeling and simulation aspects of using kinetic free-boundary conditions to drive fast carbonation reaction fronts into unsaturated porous cement-based

  4. Dynamic transition in the structure of an energetic crystal during chemical reactions at shock front prior to detonation.

    Science.gov (United States)

    Nomura, Ken-Ichi; Kalia, Rajiv K; Nakano, Aiichiro; Vashishta, Priya; van Duin, Adri C T; Goddard, William A

    2007-10-05

    Mechanical stimuli in energetic materials initiate chemical reactions at shock fronts prior to detonation. Shock sensitivity measurements provide widely varying results, and quantum-mechanical calculations are unable to handle systems large enough to describe shock structure. Recent developments in reactive force-field molecular dynamics (ReaxFF-MD) combined with advances in parallel computing have paved the way to accurately simulate reaction pathways along with the structure of shock fronts. Our multimillion-atom ReaxFF-MD simulations of l,3,5-trinitro-l,3,5-triazine (RDX) reveal that detonation is preceded by a transition from a diffuse shock front with well-ordered molecular dipoles behind it to a disordered dipole distribution behind a sharp front.

  5. Correlation between discrete probability and reaction front propagation rate in heterogeneous mixtures

    Science.gov (United States)

    Naine, Tarun Bharath; Gundawar, Manoj Kumar

    2017-09-01

    We demonstrate a very powerful correlation between the discrete probability of distances of neighboring cells and thermal wave propagation rate, for a system of cells spread on a one-dimensional chain. A gamma distribution is employed to model the distances of neighboring cells. In the absence of an analytical solution and the differences in ignition times of adjacent reaction cells following non-Markovian statistics, invariably the solution for thermal wave propagation rate for a one-dimensional system with randomly distributed cells is obtained by numerical simulations. However, such simulations which are based on Monte-Carlo methods require several iterations of calculations for different realizations of distribution of adjacent cells. For several one-dimensional systems, differing in the value of shaping parameter of the gamma distribution, we show that the average reaction front propagation rates obtained by a discrete probability between two limits, shows excellent agreement with those obtained numerically. With the upper limit at 1.3, the lower limit depends on the non-dimensional ignition temperature. Additionally, this approach also facilitates the prediction of burning limits of heterogeneous thermal mixtures. The proposed method completely eliminates the need for laborious, time intensive numerical calculations where the thermal wave propagation rates can now be calculated based only on macroscopic entity of discrete probability.

  6. Global asymptotic stability of bistable traveling fronts in reaction-diffusion systems and their applications to biological models

    International Nuclear Information System (INIS)

    Wu Shiliang; Li Wantong

    2009-01-01

    This paper deals with the global asymptotic stability and uniqueness (up to translation) of bistable traveling fronts in a class of reaction-diffusion systems. The known results do not apply in solving these problems because the reaction terms do not satisfy the required monotone condition. To overcome the difficulty, a weak monotone condition is proposed for the reaction terms, which is called interval monotone condition. Under such a weak monotone condition, the existence and comparison theorem of solutions is first established for reaction-diffusion systems on R by appealing to the theory of abstract differential equations. The global asymptotic stability and uniqueness (up to translation) of bistable traveling fronts are then proved by the elementary super- and sub-solution comparison and squeezing methods for nonlinear evolution equations. Finally, these abstract results are applied to a two species competition-diffusion model and a system modeling man-environment-man epidemics.

  7. Lateral uniformity in chemical composition along a buried reaction front in polymers using off-specular reflectivity

    International Nuclear Information System (INIS)

    Lavery, Kristopher A; Prabhu, Vivek M; Wu Wenli; Satija, Sushil

    2010-01-01

    Off-specular neutron reflectometry was applied to characterize the form and amplitude of lateral compositional variations at a buried reaction-diffusion front. In this work, off-specular neutron measurements were first calibrated using off-specular x-ray reflectivity and atomic force microscopy via a roughened glass surface, both as a free surface and as a buried interface that was prepared by spin coating thin polymer films upon the glass surface. All three methods provided consistent roughness values despite the difference in their detection mechanism. Our neutron results demonstrated, for the first time, that the compositional heterogeneity at a buried reaction front can be measured; the model system used in this study mimics the deprotection reaction that occurs during the photolithographic process necessary for manufacturing integrated circuits.

  8. Lateral uniformity in chemical composition along a buried reaction front in polymers using off-specular reflectivity.

    Science.gov (United States)

    Lavery, Kristopher A; Prabhu, Vivek M; Satija, Sushil; Wu, Wen-Li

    2010-12-01

    Off-specular neutron reflectometry was applied to characterize the form and amplitude of lateral compositional variations at a buried reaction-diffusion front. In this work, off-specular neutron measurements were first calibrated using off-specular x-ray reflectivity and atomic force microscopy via a roughened glass surface, both as a free surface and as a buried interface that was prepared by spin coating thin polymer films upon the glass surface. All three methods provided consistent roughness values despite the difference in their detection mechanism. Our neutron results demonstrated, for the first time, that the compositional heterogeneity at a buried reaction front can be measured; the model system used in this study mimics the deprotection reaction that occurs during the photolithographic process necessary for manufacturing integrated circuits.

  9. Thermal ion-molecule reactions in oxygen-containing molecules

    International Nuclear Information System (INIS)

    Kumakura, Minoru

    1981-02-01

    The energetics of ions and the thermal ion-molecule reactions in oxygen-containing molecules have been studied with a modified time-of-flight mass spectrometer. It was found that the translational energy of ion can be easily obtained from analysis of the decay curve using the time-of-flight mass spectrometer. The condensation-elimination reactions proceeded via cross- and homo-elimination mechanism in which the nature of intermediate-complex could be correlated with the nature of reactant ion. It was elucidated that behavior of poly-atomic oxygen-containing ions on the condensation-elimination reactions is considerably influenced by their oxonium ion structures having functional groups. In addition, the rate constants of the condensation-elimination reactions have affected with the energy state of reactant ion and the dipole moment and/or the polarizability of neutral molecule. It was clarified that the rate constants of the ion-molecule clustering reactions in poly-atomic oxygen-containing molecules such as cyclic ether of six member rings are very large and the cluster ions are stable owing to the large number of vibrational degree of freedom in the cluster ions. (author)

  10. Redox fronts

    International Nuclear Information System (INIS)

    Chapman, N.; McKinley, I.; Shea, M.; Smellie, J.

    1993-01-01

    This article describes the investigations of redox fronts performed at the Osamu Utsumi mine. Results obtained by modelling groups on the rate of movement of the redox fronts and on the chemical reactions involved are discussed. Some of the most important rockwater interactions which occur at redox fronts can be modelled reasonably well but the complex redox chemistry of elements like sulphur is poorly simulated. The observed enrichment of many trace elements close to the redox fronts could be of significance for high-level waste repositories, but cannot be quantified by existing models. (author) 6 figs., 1 tab

  11. Gas phase reactions of organic iodine in containment conditions

    International Nuclear Information System (INIS)

    Kaerkalae, T.; Holm, J.; Auvinen, A.; Zilliacus, R.; Kajolinna, T.; Tapper, U.; Gaenneskog, H.; Ekberg, C.

    2010-01-01

    In case of a hypothetical severe accident it is very likely that iodine at least partly deposits on painted walls of a reactor containment building. Iodine may react with painted surfaces to form organic iodine species. These organic species are a possible source of volatile iodine, which may increase the fraction of releasable iodine. Therefore, it is important to study the transport of organic iodine in containment conditions. Another question is, in which form are the organic iodides transported as gaseous molecules or as aerosol particles resulting from organic iodides reacting with radiolysis products. To answer this last question methyl iodide was fed into the EXSI facility in an air mixture. In some experiments the flow contained also humidity. The reactions took place in a quartz tube heated either to 50 deg. C, 90 deg. C or 120 deg. C. UV-light was used as a source of radiation to produce ozone from oxygen. A separate generator was also applied to reach higher ozone concentrations. Nucleated aerosol particles were collected on plane filters and gaseous iodine species were trapped in trapping bottles. Aerosol mass flow rate and size distribution as well as speciation of gaseous reaction products were measured with several on-line instruments. Collected aerosol particles were analysed with SEM. It was found that the formation of aerosol particles was very fast when ozone and methyl iodide were present in the facility. Even a very low concentration of ozone produced high number concentration of particles. The measured aerosol mass concentration increased with increasing temperature and ozone concentration. Because the particle diameter was quite small (<180 nm), their settling velocity is low. Therefore, iodine containing aerosols may exist in containment atmosphere for a long period of time. Part of methyl iodide was always transported through the facility regardless of experimental conditions. All ozone was consumed in the reactions when only UV-light was

  12. Modes of reaction front propagation and end-gas combustion of hydrogen/air mixtures in a closed chamber

    KAUST Repository

    Shi, Xian

    2017-01-05

    Modes of reaction front propagation and end-gas combustion of hydrogen/air mixtures in a closed chamber are numerically investigated using an 1-D unsteady, shock-capturing, compressible and reacting flow solver. Different combinations of reaction front propagation and end-gas combustion modes are observed, i.e., 1) deflagration without end-gas combustion, 2) deflagration to end-gas autoignition, 3) deflagration to end-gas detonation, 4) developing or developed detonation, occurring in the sequence of increasing initial temperatures. Effects of ignition location and chamber size are evaluated: the asymmetric ignition is found to promote the reactivity of unburnt mixture compared to ignitions at center/wall, due to additional heating from asymmetric pressure waves. End-gas combustion occurs earlier in smaller chambers, where end-gas temperature rise due to compression heating from the deflagration is faster. According to the ξ−ε regime diagram based on Zeldovich theory, modes of reaction front propagation are primarily determined by reactivity gradients introduced by initial ignition, while modes of end-gas combustion are influenced by the total amount of unburnt mixture at the time when autoignition occurs. A transient reactivity gradient method is provided and able to capture the occurrence of detonation.

  13. Modes of reaction front propagation and end-gas combustion of hydrogen/air mixtures in a closed chamber

    KAUST Repository

    Shi, Xian; Ryu, Je Ir; Chen, Jyh-Yuan; Dibble, Robert W.

    2017-01-01

    Modes of reaction front propagation and end-gas combustion of hydrogen/air mixtures in a closed chamber are numerically investigated using an 1-D unsteady, shock-capturing, compressible and reacting flow solver. Different combinations of reaction front propagation and end-gas combustion modes are observed, i.e., 1) deflagration without end-gas combustion, 2) deflagration to end-gas autoignition, 3) deflagration to end-gas detonation, 4) developing or developed detonation, occurring in the sequence of increasing initial temperatures. Effects of ignition location and chamber size are evaluated: the asymmetric ignition is found to promote the reactivity of unburnt mixture compared to ignitions at center/wall, due to additional heating from asymmetric pressure waves. End-gas combustion occurs earlier in smaller chambers, where end-gas temperature rise due to compression heating from the deflagration is faster. According to the ξ−ε regime diagram based on Zeldovich theory, modes of reaction front propagation are primarily determined by reactivity gradients introduced by initial ignition, while modes of end-gas combustion are influenced by the total amount of unburnt mixture at the time when autoignition occurs. A transient reactivity gradient method is provided and able to capture the occurrence of detonation.

  14. Reactions of oxygen containing structures in coal pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Hodek, W.; Kirschstein, J.; Van Heek, K.-H. (DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany, F.R.))

    1991-03-01

    In coal pyrolysis O-containing structures such as ether bridges and phenolic groups play an important role. Their reactions were studied by non-isothermal pyrolysis of a high volatile bituminous coal and some model polymers with gas chromatographic detection of the gaseous pyrolysis products. The coal was separated into the maceral groups vitrinite, exinite and inertinite, which showed markedly different pyrolysis behaviour. The formation of CO, methane and benzene was measured versus temperature. By comparison with polyphenyleneoxide and phenol-formaldehyde resins, it was found that the main volatilization, during which most of the tar is evolved, is initiated by cleavage of alkyl-aryl-ethers. Rearrangements of the primarily formed radicals lead to the formation of CO and methane at higher temperatures. 5 refs., 8 figs., 1 tab.

  15. Reactions of diiron m-aminocarbyne complexes containing nitrile ligands

    Directory of Open Access Journals (Sweden)

    Busetto Luigi

    2003-01-01

    Full Text Available The acetonitrile ligand in the mu-aminocarbyne complexes [Fe2{mu-CN(MeR}(mu-CO(CO(NCMe(Cp2][SO 3CF3] (R = Me, 2a, CH2Ph, 2b, Xyl, 2c (Xyl = 2,6-Me2C6H3 is readily displaced by halides and cyanide anions affording the corresponding neutral species [Fe2{mu-CN(MeR}(mu-CO(CO(X(Cp2 ] (X = Br, I, CN. Complexes 2 undergo deprotonation and rearrangement of the coordinated MeCN upon treatment with organolithium reagents. Trimethylacetonitrile, that does not contain acidic alpha hydrogens has been used in place of MeCN to form the complexes [Fe2{mu-CN(MeR}(mu-CO(CO(NCCMe3 (Cp2][SO3CF3] (7a-c. Attempts to replace the nitrile ligand in 3 with carbon nucleophiles (by reaction with RLi failed, resulting in decomposition products. However the reaction of 7c with LiCºCTol (Tol = C6H4Me, followed by treatment with HSO3CF3, yielded the imino complex [Fe2{mu-CN(MeXyl}(mu-CO(CO {N(HC(CºCC6H4Me-4CMe3}(Cp 2][SO3CF3 ] (8, obtained via acetilyde addition at the coordinated NCCMe3.

  16. Effects of the starch indicator on the buoyantly unstable iodate-arsenous acid reaction front

    Czech Academy of Sciences Publication Activity Database

    Šebestíková, Lenka; Šimčík, Miroslav; Růžička, Marek

    2017-01-01

    Roč. 2, č. 24 (2017), s. 7141-7149 ISSN 2365-6549 R&D Projects: GA ČR GAP105/10/0919 Institutional support: RVO:67985874 ; RVO:67985858 Keywords : autocatalysis * exchange interaction * iodine * liquids * reaction mechanism Subject RIV: BK - Fluid Dynamics; CI - Industrial Chemistry, Chemical Engineering (UCHP-M) OBOR OECD: Fluids and plasma physics (including surface physics); Chemical process engineering (UCHP-M)

  17. Bimetallic Catalysts Containing Gold and Palladium for Environmentally Important Reactions

    Directory of Open Access Journals (Sweden)

    Ahmad Alshammari

    2016-07-01

    Full Text Available Supported bimetallic nanoparticles (SBN are extensively used as efficient redox catalysts. This kind of catalysis particularly using SBN has attracted immense research interest compared to their parent metals due to their unique physico-chemical properties. The primary objective of this contribution is to provide comprehensive overview about SBN and their application as promising catalysts. The present review contains four sections in total. Section 1 starts with a general introduction, recent progress, and brief summary of the application of SBN as promising catalysts for different applications. Section 2 reviews the preparation and characterization methods of SBN for a wide range of catalytic reactions. Section 3 concentrates on our own results related to the application of SBN in heterogeneous catalysis. In this section, the oxidation of cyclohexane to adipic acid (an eco-friendly and novel approach will be discussed. In addition, the application of bimetallic Pd catalysts for vapor phase toluene acetoxylation in a fixed bed reactor will also be highlighted. Acetoxylation of toluene to benzyl acetate is another green route to synthesize benzyl acetate in one step. Finally, Section 4 describes the summary of the main points and also presents an outlook on the application of SBN as promising catalysts for the production of valuable products.

  18. Continuous Dependence in Front Propagation for Convective Reaction-Diffusion Models with Aggregative Movements

    Directory of Open Access Journals (Sweden)

    Luisa Malaguti

    2011-01-01

    Full Text Available The paper deals with a degenerate reaction-diffusion equation, including aggregative movements and convective terms. The model also incorporates a real parameter causing the change from a purely diffusive to a diffusive-aggregative and to a purely aggregative regime. Existence and qualitative properties of traveling wave solutions are investigated, and estimates of their threshold speeds are furnished. Further, the continuous dependence of the threshold wave speed and of the wave profiles on a real parameter is studied, both when the process maintains its diffusion-aggregation nature and when it switches from it to another regime.

  19. Atomic-scale observation of lithiation reaction front in nanoscale SnO2 materials

    KAUST Repository

    Nie, Anmin; Gan, Liyong; Cheng, Yingchun; Asayesh-Ardakani, Hasti; Li, Qianqian; Dong, Cezhou; Tao, Runzhe; Mashayek, Farzad; Wang, Hongtao; Schwingenschlö gl, Udo; Klie, Robert F.; Yassar, Reza Shahbazian

    2013-01-01

    In the present work, taking advantage of aberration-corrected scanning transmission electron microscopy, we show that the dynamic lithiation process of anode materials can be revealed in an unprecedented resolution. Atomically resolved imaging of the lithiation process in SnO2 nanowires illustrated that the movement, reaction, and generation of b = [1Ì...1Ì...1] mixed dislocations leading the lithiated stripes effectively facilitated lithium-ion insertion into the crystalline interior. The geometric phase analysis and density functional theory simulations indicated that lithium ions initial preference to diffuse along the [001] direction in the {200} planes of SnO2 nanowires introduced the lattice expansion and such dislocation behaviors. At the later stages of lithiation, the Li-induced amorphization of rutile SnO2 and the formation of crystalline Sn and LixSn particles in the Li2O matrix were observed. © 2013 American Chemical Society.

  20. Atomic-scale observation of lithiation reaction front in nanoscale SnO2 materials

    KAUST Repository

    Nie, Anmin

    2013-07-23

    In the present work, taking advantage of aberration-corrected scanning transmission electron microscopy, we show that the dynamic lithiation process of anode materials can be revealed in an unprecedented resolution. Atomically resolved imaging of the lithiation process in SnO2 nanowires illustrated that the movement, reaction, and generation of b = [1Ì...1Ì...1] mixed dislocations leading the lithiated stripes effectively facilitated lithium-ion insertion into the crystalline interior. The geometric phase analysis and density functional theory simulations indicated that lithium ions initial preference to diffuse along the [001] direction in the {200} planes of SnO2 nanowires introduced the lattice expansion and such dislocation behaviors. At the later stages of lithiation, the Li-induced amorphization of rutile SnO2 and the formation of crystalline Sn and LixSn particles in the Li2O matrix were observed. © 2013 American Chemical Society.

  1. Development of fast reactor containment safety analysis code, CONTAIN-LMR. (3) Improvement of sodium-concrete reaction model

    International Nuclear Information System (INIS)

    Kawaguchi, Munemichi; Doi, Daisuke; Seino, Hiroshi; Miyahara, Shinya

    2015-01-01

    A computer code, CONTAIN-LMR, is an integrated analysis tool to predict the consequence of severe accident in a liquid metal fast reactor. Because a sodium-concrete reaction behavior is one of the most important phenomena in the accident, a Sodium-Limestone Concrete Ablation Model (SLAM) has been developed and installed into the original CONTAIN code at Sandia National Laboratories (SNL) in the U.S. The SLAM treats chemical reaction kinetics between the sodium and the concrete compositions mechanistically using a three-region model, containing a pool (sodium and reaction debris) region, a dry (boundary layer (B/L) and dehydrated concrete) region, and a wet (hydrated concrete) region, the application is limited to the reaction between sodium and limestone concrete. In order to apply SLAM to the reaction between sodium and siliceous concrete which is an ordinary structural concrete in Japan, the chemical reaction kinetics model has been improved to consider the new chemical reactions between sodium and silicon dioxide. The improved model was validated to analyze a series of sodium-concrete experiments which were conducted in Japan Atomic Energy Agency (JAEA). It has been found that relatively good agreement between calculation and experimental results is obtained and the CONTAIN-LMR code has been validated with regard to the sodium-concrete reaction phenomena. (author)

  2. [The general practitioners in front of reforms: the reactions of the sample group of liberal physicians of the region PACA].

    Science.gov (United States)

    Videau, Yann; Ventelou, Bruno; Combes, Jean-Baptiste; Verger, Pierre; Paraponaris, Alain

    2007-05-01

    The general practitioners in front of reforms: the reactions of the sample group of liberal physicians of the region PACA This article intends to analyse the opinion of general practioners (GPs) about the two laws of July 2004, relating to the health insurance reform and to public health planning. We used a panel data sample of 528 GPs practising in Provence Alpes Côte d'Azur in order to analyse the determinants of physicians' adherence to the reform, using multinomial logistic regression models. The results show that GPs do not seem to be fully convinced by this reform (45% agree with it, whereas 48% don't): this mistrustful opinion is more marked for young physicians and appears little correlated with their practices. 75% of the GPs are favourable to the Personal Medical File (Dossier Médical Personnel in french) and 76% estimate that they should draw a better attention to the public health dimension of their practice. Two barriers concerning GPs' adherence to the doctor > reform (réforme du ) seem relevant: the burden of administrative tasks and the disadvantage of young physicians who have not already fixed their own clientele.

  3. Computerized identification and classification of stance phases as made by front og hind feet of walking cows based on 3-dimensional ground reaction forces

    DEFF Research Database (Denmark)

    Skjøth, F; Thorup, Vivi Mørkøre; do Nascimento, Omar Feix

    2013-01-01

    Lameness is a frequent disorder in dairy cows and in large dairy herds manual lameness detection is a time-consuming task. This study describes a method for automatic identification of stance phases in walking cows, and their classification as made by a front or a hind foot based on ground reaction...... phases, of these 1146 (62%) were automatically identified as full stance phases and classified as made by a front or hind foot. As intended, the procedures did not favour identification of stance phases of healthy cows over lame cows. In addition, a human observer evaluated the stance phases by visual...... inspection, revealing a very low discrepancy (3.5%) between manual and automated approaches. Further, a sensitivity test indicated large robustness in the automatic procedures. In conclusion, the experimental setup combined with the computerized procedures described in the present study resulted in a high...

  4. Deamidation Reactions of Asparagine- and Glutamine-Containing Dipeptides Investigated by Ion Spectroscopy

    NARCIS (Netherlands)

    Kempkes, L.J.M.; Martens, J.; Grzetic, J.; Berden, G.; Oomens, J.

    2016-01-01

    Deamidation is a major fragmentation channel upon activation by collision induced dissociation (CID) for protonated peptides containing glutamine (Gln) and asparagine (Asn) residues. Here, we investigate these NH3-loss reactions for four Asn- and Gln-containing protonated peptides in terms of the

  5. Reaction of vanadocene and its monochloride with salts of nitrogen-containing heterocycles

    International Nuclear Information System (INIS)

    Gordetsov, A.S.; Pereshein, V.V.; Lyatyaeva, V.N.; Mar'in, V.P.; Rukevich, OS.; Zakharova, E.S.

    1985-01-01

    The reaction of bis(eta 5 -cyclopentadienyl) vanadium (Cp 2 V) and its monochloride with diallyl isocyanurates of Ag and alkali metals and with Ag salt of succinimide is used for preparing almost inaccessible Cp 2 V-substituted nitrogen-containing heterocycles. The reactions have been performed in toluene in an evacuated ampoule at room temperature and at 120-130 deg C in case of diallyl isocyanurates of alkali metals. Reaction yields element analysis data, DTA, IR spectra and ESR spectra. Cp 2 V easily reduces Ag from its salts with nitrogen-containing heterocycles oxidizing with production of V(3) sandwich derivatives In exchange reactions of Cp 2 VCl with diallyl isocyanurate salts of alkali metals and silver Cp 2 V-diallyl isocyanurate with an oxo-structure is prosduced as well. The produced AgCl subsequently oxidizers Cp 2 VCl up to Cp 2 VCl 2

  6. A case of anaphylactoid reaction to acetate in acetate-containing bicarbonate dialysate.

    Science.gov (United States)

    Misaki, Taro; Suzuki, Yumiko; Naito, Yoshitaka; Shiooka, Tempei; Isozaki, Taisuke

    2015-05-01

    A 35-year-old man with end-stage kidney disease due to chronic glomerulonephritis was admitted to our hospital to start maintenance hemodialysis (HD). One hour after starting the first session of HD, he experienced general pruritus, urticaria, and dyspnea. Signs and symptoms were resolved by discontinuing HD and administrating an antihistamine drug; HD-associated anaphylactoid reactions were therefore suspected. Over the next few HD sessions, we changed the dialysis membrane, anticoagulant, HD circuit and needle, in that order, but general pruritus and urticaria again appeared within 3 h after starting each session of HD. Finally, when we changed the dialysate from acetate-containing bicarbonate dialysate to acetate-free bicarbonate dialysate, urticaria was clearly less than that seen in previous HD sessions, and subsided after discontinuation of HD. Subsequently, 20 mg of oral prednisolone (PSL) was administered 1 h before starting HD, and the patient did not experience general pruritus, urticaria, or dyspnea after starting the session. When administered acetate-containing bicarbonate dialysate after oral PSL pretreatment, the patient again experienced general pruritus, urticaria and dyspnea. Few reports have been published on the occurrence of anaphylactoid reactions during HD using acetate dialysate. We report a rare case of anaphylactoid reactions with acetate in acetate-containing bicarbonate dialysate that were reduced with the use of acetate-free bicarbonate dialysate and oral PSL pretreatment.

  7. Formation of nitrogen-containing compounds during microwave pyrolysis of microalgae: Product distribution and reaction pathways.

    Science.gov (United States)

    Huang, Feng; Tahmasebi, Arash; Maliutina, Kristina; Yu, Jianglong

    2017-12-01

    The formation of nitrogen-containing compounds in bio-oil during microwave pyrolysis of Chlorella and Spirulina microalgae has been investigated in this study. Activated carbon (AC) and magnetite (Fe 3 O 4 ) were used as microwave receptors during microwave pyrolysis experiments. It has been found that the use of Fe 3 O 4 increased the total yield of bio-oil. The use of different microwave receptors did not seem to have affected the total yield of nitrogen-containing compounds in the bio-oil. However, Fe 3 O 4 promoted the formation of nitrogen-containing aliphatics, thereby reducing the formation of nitrogen-containing aromatics. The use of AC promoted the dehydration reactions during amino acid decomposition, thereby enhancing the formation of nitrogen-containing aromatics during pyrolysis. From the gas chromatography-mass spectrometry (GC-MS) analysis results, the major high-value nitrogen-containing compounds in the pyrolysis bio-oil of Chlorella and Spirulina were identified as indole and dodecamide. The formation mechanisms of nitrogen-containing compounds were proposed and discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Hyporheic exchange and fulvic acid redox reactions in an alpine stream/wetland ecosystem, Colorado front range

    Science.gov (United States)

    Miller, Matthew P.; McKnight, Diane M.; Cory, R.M.; Williams, Mark W.; Runkel, Robert L.

    2006-01-01

    The influence of hyporheic zone interactions on the redox state of fulvic acids and other redox active species was investigated in an alpine stream and adjacent wetland, which is a more reducing environment. A tracer injection experiment using bromide (Br-) was conducted in the stream system. Simulations with a transport model showed that rates of exchange between the stream and hyporheic zone were rapid (?? ??? 10-3 s -1). Parallel factor analysis of fluorescence spectra was used to quantify the redox state of dissolved fulvic acids. The rate coefficient for oxidation of reduced fulvic acids (?? = 6.5 ?? 10-3 s -1) in the stream indicates that electron-transfer reactions occur over short time scales. The rate coefficients for decay of ammonium (?? = 1.2 ?? 10-3 s-1) and production of nitrate (?? = -1.0 ?? 10-3 s-1) were opposite in sign but almost equal in magnitude. Our results suggest that fulvic acids are involved in rapid electron-transfer processes in and near the stream channel and may be important in determining ecological energy flow at the catchment scale. ?? 2006 American Chemical Society.

  9. Effects of iron-containing minerals on hydrothermal reactions of ketones

    Science.gov (United States)

    Yang, Ziming; Gould, Ian R.; Williams, Lynda B.; Hartnett, Hilairy E.; Shock, Everett L.

    2018-02-01

    Hydrothermal organic transformations occurring in geochemical processes are influenced by the surrounding environments including rocks and minerals. This work is focused on the effects of five common minerals on reactions of a model ketone substrate, dibenzylketone (DBK), in an experimental hydrothermal system. Ketones play a central role in many hydrothermal organic functional group transformations, such as those converting hydrocarbons to oxygenated compounds; however, how these minerals control the hydrothermal chemistry of ketones is poorly understood. Under the hydrothermal conditions of 300 °C and 70 MPa for up to 168 h, we observed that, while quartz (SiO2) and corundum (Al2O3) had no detectable effect on the hydrothermal reactions of DBK, iron-containing minerals, such as hematite (Fe2O3), magnetite (Fe3O4), and troilite (synthetic FeS), accelerated the reaction of DBK by up to an order of magnitude. We observed that fragmentation products, such as toluene and bibenzyl, dominated in the presence of hematite or magnetite, while use of troilite gave primarily the reduction products, e.g., 1, 3-diphenyl-propane and 1, 3-diphenyl-2-propanol. The roles of the three iron minerals in these transformations were further explored by (1) control experiments with various mineral surface areas, (2) measuring H2 in hydrothermal solutions, and (3) determining hydrogen balance among the organic products. These results suggest the reactions catalyzed by iron oxides (hematite and magnetite) are promoted mainly by the mineral surfaces, whereas the sulfide mineral (troilite) facilitated the reduction of ketone in the reaction solution. Therefore, this work not only provides a useful chemical approach to study and uncover complicated hydrothermal organic-mineral interactions, but also fosters a mechanistic understanding of ketone reactions in the deep carbon cycle.

  10. Stable and efficient nitrogen-containing-carbon based electrocatalysts for reactions in energy conversion systems.

    Science.gov (United States)

    Wang, Sicong; Teng, Zhenyuan; Wang, Chengyin; Wang, Guoxiu

    2018-05-17

    High activity and stability are crucial for practical electrocatalysts used for reactions in fuel cells, metal-air batteries and water electrolysis including ORR, HER, OER and oxidation reactions of formic acid and alcohols. N-C based electrocatalysts have shown promising prospects for catalyzing these reactions, however, there is no systematic review for strategies toward engineering active and stable N-C based electrocatalysts reported by far. Herein, a comprehensive comparison of recently reported N-C based electrocatalysts regarding both electrocatalytic activity and long-term stability is presented. In the first part of this review, relationships between electrocatalytic reactions and element selections for modifying N-C based materials are discussed. Afterwards, synthesis methods for N-C based electrocatalysts are summarized, and synthetic strategies for highly stable N-C based electrocatalysts are presented. Multiple tables containing data on crucial parameters for both electrocatalytic activity and stability are displayed in this review. Finally, constructing M-Nx moieties is proposed as the most promising engineering strategy for stable N-C based electrocatalysts. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Stable hydrogen production from ethanol through steam reforming reaction over nickel-containing smectite-derived catalyst.

    Science.gov (United States)

    Yoshida, Hiroshi; Yamaoka, Ryohei; Arai, Masahiko

    2014-12-25

    Hydrogen production through steam reforming of ethanol was investigated with conventional supported nickel catalysts and a Ni-containing smectite-derived catalyst. The former is initially active, but significant catalyst deactivation occurs during the reaction due to carbon deposition. Side reactions of the decomposition of CO and CH4 are the main reason for the catalyst deactivation, and these reactions can relatively be suppressed by the use of the Ni-containing smectite. The Ni-containing smectite-derived catalyst contains, after H2 reduction, stable and active Ni nanocrystallites, and as a result, it shows a stable and high catalytic performance for the steam reforming of ethanol, producing H2.

  12. Negative Ion Density Fronts

    International Nuclear Information System (INIS)

    Igor Kaganovich

    2000-01-01

    Negative ions tend to stratify in electronegative plasmas with hot electrons (electron temperature Te much larger than ion temperature Ti, Te > Ti ). The boundary separating a plasma containing negative ions, and a plasma, without negative ions, is usually thin, so that the negative ion density falls rapidly to zero-forming a negative ion density front. We review theoretical, experimental and numerical results giving the spatio-temporal evolution of negative ion density fronts during plasma ignition, the steady state, and extinction (afterglow). During plasma ignition, negative ion fronts are the result of the break of smooth plasma density profiles during nonlinear convection. In a steady-state plasma, the fronts are boundary layers with steepening of ion density profiles due to nonlinear convection also. But during plasma extinction, the ion fronts are of a completely different nature. Negative ions diffuse freely in the plasma core (no convection), whereas the negative ion front propagates towards the chamber walls with a nearly constant velocity. The concept of fronts turns out to be very effective in analysis of plasma density profile evolution in strongly non-isothermal plasmas

  13. Insights into the importance of oxygen functional groups in carbon reactions with oxygen containing gases

    International Nuclear Information System (INIS)

    John Zhu, Max Lu

    2005-01-01

    The role of pore structure of carbon in carbon-related adsorptions and reactions has been extensively investigated. However the studies on the role of surface chemistry of carbon are limited. In this paper, we present the importance of oxygen functional groups in carbon reactions with oxygen-containing gases. It is found that there is a good correlation between the electronic structures and reactivities of carbon edge sites. Zigzag sites are more active in oxygen adsorption because of the unpaired electrons and armchair sites are less active in oxygen adsorption due to the triple character. However, the desorption of semi-quinone oxygen from zigzag sites needs a bond energy ca. 30% higher than that of o-quinone oxygen from armchair edge sites. CO 2 and H 2 O adsorb on carbon surface much less favorably than O 2 . H 2 O is first physically adsorbed on the virgin graphite surface followed by chemisorption through oxygen atom approaching the carbon edge site and the movements of two hydrogen atoms to produce H 2 . The adsorption mechanism of H 2 O is different from that for CO 2 , but the final result is quite similar, i.e. producing only semi-quinone oxygen. Based upon the above studies, a new generalized mechanism, as shown in Fig. 1, is developed and can account for all the important kinetic phenomena of carbon-gas reactions. The key point is that in CO 2 /H 2 O-carbon reaction only semi-quinone formed; while, in O 2 -carbon reaction, semi-quinone, o-quinone (at lower pressure), and off-plane epoxy oxygen (at relatively higher pressure) can be formed. This is the main reason for the different reaction kinetics of O 2 -carbon reaction and CO 2 /H 2 O-carbon reactions as observed experimentally. The oxygen functional groups of carbon can be characterized by XPS, PZC (point of zero charge), IEP (isoelectric point) and TPD (temperature-programmed desorption), which were used in our previous studies. We treated the carbon surface with different acids, finding that HNO 3

  14. Activity of molybdenum-containing oxide catalysts in the reaction of ethane oxidation

    International Nuclear Information System (INIS)

    Konovalov, V.I.; Ehpova, T.I.; Shchukin, V.P.; Averbukh, A.Ya.

    1977-01-01

    Investigation results concerning the catalytic activity of molybdenum-containing catalysts in ethane oxidation reaction are presented. It has been found that the greatest activity in the temperature range from 450 to 600 deg C is exhibited by cobalt-molybdenum catalyst; at 600 deg C bismuth-molybdenum catalyst is the most active. Nickel-molybdenum catalyst is selective and active with respect to ethylene. Iron- and manganese-molybdenum catalysts do not show high ethane oxidation rates and their selectivity is insignificant

  15. Molybdenum blue reaction and determination of phosphorus in waters containing arsenic, silicon, and germanium

    Science.gov (United States)

    Levine, H.; Rowe, J.J.; Grimaldi, F.S.

    1955-01-01

    Microgram amounts of phosphate are usually determined by the molybdenum blue reaction, but this reaction is not specific for phosphorus. The research established the range of conditions under which phosphate, arsenate, silicate, and germanate give the molybdenum blue reaction for differentiating these elements, and developed a method for the determination of phosphate in waters containing up to 10 p.p.m. of the oxides of germanium, arsenic(V), and silicon. With stannous chloride or 1-amino-2-naphthol-4-sulfonic acid as the reducing agent no conditions were found for distinguishing silicate from germanate and phosphate from arsenate. In the recommended procedure the phosphate is concentrated by coprecipitation on aluminum hydroxide, and coprecipitated arsenic, germanium, and silicon are volatilized by a mixture of hydrofluoric, hydrochloric, and hydrobromic acids prior to the determination of phosphate. The authors are able to report that the total phosphorus content of several samples of sea water from the Gulf of Mexico ranged from 0.018 to 0.059 mg. of phosphorus pentoxide per liter of water.

  16. [Production of sugar syrup containing rare sugar using dual-enzyme coupled reaction system].

    Science.gov (United States)

    Han, Wenjia; Zhu, Yueming; Bai, Wei; Izumori, Ken; Zhang, Tongcun; Sun, Yuanxia

    2014-01-01

    Enzymatic conversion is very important to produce functional rare sugars, but the conversion rate of single enzymes is generally low. To increase the conversion rate, a dual-enzyme coupled reaction system was developed. Dual-enzyme coupled reaction system was constructed using D-psicose-3-epimerase (DPE) and L-rhamnose isomerase (L-RhI), and used to convert D-fructose to D-psicose and D-allose. The ratio of DPE and L-RhI was 1:10 (W/W), and the concentration of DPE was 0.05 mg/mL. The optimum temperature was 60 degrees C and pH was 9.0. When the concentration of D-fructose was 2%, the reaction reached its equilibrium after 10 h, and the yield of D-psicose and D-allose was 5.12 and 2.04 g/L, respectively. Using the dual-enzymes coupled system developed in the current study, we could obtain sugar syrup containing functional rare sugar from fructose-rich raw material, such as high fructose corn syrup.

  17. Development of clay characterization methods for use in repository design with application to a natural Ca bentonite clay containing a redox front

    International Nuclear Information System (INIS)

    Karnland, O.; Pusch, R.

    1990-12-01

    Natural smectite clays in the form of 'true' bentonites formed from volcanic ash, or resulting from in-situ weathering of rock, are suitable for a number of sealing options in repositories, both as tightening component of sand/clay backfills and as highly efficient buffer for embedment of canisters, as well as for fracture sealing. The price and quality, in terms of smectite content and type of smectite, vary considerably and an optimum choice of clay for use in repositories has to be based on quantitative quality data. This requires characterization of the clay material for which a test scheme has been worked out. It comprises determination of the granulometrical, chemical, and mineralogical compositions, as well as of certain physical properties. Recent research shows the importance of the type of smectite for the longevity of buffers in repository environment, beidellite being less favourable and saponite superior to montmorillonite, which is the most common smectite species. The test scheme hence includes means of distinguishing between various smectite minerals. The influence of accessory minerals on the chemical integrity of both the smectite and the canister material requires identification also of such minerals, for which the scheme is useful as well. The report summarizes the various test procedures and gives data from application of the scheme to samples from a natural Ca bentonite containing a redox front. This study suggests that a significant part of the iron in the clay fraction is in the form of Fe 2+ in octahedral positions of the montmorillonite of unoxidized natural clay and that it is converted to Fe 3+ on oxidation. Part of the iron is probably in the form of the Fe 2+ Fe 3+ hydroxy compounds that give the unoxidized clay its bluish colour, while they can be assumed to be transformed to yellowish FeOOH forms on oxidation. (author)

  18. Reaction kinetics and reaction heat on thermal decomposition of solvent containing unstable reactive hydrocarbons with nitric acid at Tomsk-7 reprocessing plant

    International Nuclear Information System (INIS)

    Nishio, Gunji; Watanabe, Kouji; Koike, Tadao; Miyato, Teijiro.

    1996-12-01

    For analyzing a cause of the Tomsk-7 accident at Russian reprocessing plant, it is necessary to determine reaction-rate constant and reaction heat for a thermal decomposition of TBP/kerosine containing unstable reactive hydrocarbons with nitric acid. In JAERI, the rate constant and reaction heat were obtained from data measured with a differential thermal analyzer (DTA) for unstable hydrocarbons such as n-butanol, n-butyl nitrate, aromatic hydrocarbons, and cyclic compounds. The safety evaluation of Tomsk tank ruptured by the reaction was carried out by heat balance calculations between heat generation and heat loss in the tank using these rate constants and reaction heats. Consequently, it is clear that the cause of the tank rupture would be due to an exothermic reaction of aromatic hydrocarbons in kerosine made by petroleum with the concentrated nitric acid of 14.2N. (author)

  19. Hydrolysis of Surfactants Containing Ester Bonds: Modulation of Reaction Kinetics and Important Aspects of Surfactant Self-Assembly

    Science.gov (United States)

    Lundberg, Dan; Stjerndahl, Maria

    2011-01-01

    The effects of self-assembly on the hydrolysis kinetics of surfactants that contain ester bonds are discussed. A number of examples on how reaction rates and apparent reaction orders can be modulated by changes in the conditions, including an instance of apparent zero-order kinetics, are presented. Furthermore, it is shown that the examples on…

  20. Zeolite synthesis from the pyrrolidine containing system and their catalytic properties in the methanol conversion reaction

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Kunio; Kiyozumi, Yoshimichi; Shin, Shigemitsu; Ogawa, Kiyoshi; Yamazaki, Yasuyoshi; Watanabe, Hideo

    1987-12-18

    Systhesis of zeolite from a system containing cheaper pyrrolidine as a crystallization regulator than quaternary ammonium ion was carried out and the methanol conversion reaction was studied over the systhesized zeolite to get C/sub 2/ and C/sub 3/ olefins. Hydrous gels were prepared by adding and agitating pyrrolidine, water glass and sulfuric acid to aluminum sulfate solution; and aluminum nitrate, colloidal silica and pyrrolidine to NaOH solution. Five zeolite, that is, ZSM-5, ZSM-35, ZSM-39, ZSM-48 and KZ-1 were synthesized by changing gel components. X-ray powder diffraction, BET specific surface areas, micropore diameters, micropore volumes, oxygen contents by scanning electron photomicrographs and infra-red spectra were examined. The organic base in hydrous gels influenced greatly on the zeolite composition and structure. The ZSM-5 zeolite exhibited the superior performance as to a high selectivity of light olefins over the target of development. (12 figs, 1 tab, 20 refs)

  1. Shock-induced hotspot formation and chemical reaction initiation in PETN containing a spherical void

    International Nuclear Information System (INIS)

    Shan, Tzu-Ray; Thompson, Aidan P

    2014-01-01

    We present results of reactive molecular dynamics simulations of hotspot formation and chemical reaction initiation in shock-induced compression of pentaerythritol tetranitrate (PETN) with the ReaxFF reactive force field. A supported shockwave is driven through a PETN crystal containing a 20 nm spherical void at a sub-threshold impact velocity of 2 km/s. Formation of a hotspot due to shock-induced void collapse is observed. During void collapse, NO 2 is the dominant species ejected from the upstream void surface. Once the ejecta collide with the downstream void surface and the hotspot develops, formation of final products such as N 2 and H 2 O is observed. The simulation provides a detailed picture of how void collapse and hotspot formation leads to initiation at sub-threshold impact velocities.

  2. Lessons Learned Following the Successful Decommissioning of a Reaction Vessel Containing Lime Sludge and Technetium-99

    International Nuclear Information System (INIS)

    Dawson, P. M.; Watson, D. D.; Hylko, J. M.

    2002-01-01

    This paper documents how WESKEM, LLC utilized available source term information, integrated safety management, and associated project controls to safely decommission a reaction vessel and repackage sludge containing various Resource Conservation and Recovery Act constituents and technetium-99 (Tc-99). The decommissioning activities were segmented into five separate stages, allowing the project team to control work related decisions based on their knowledge, experience, expertise, and field observations. The information and experience gained from each previous stage and rehearsals contributed to modifying subsequent entries, further emphasizing the importance of developing hold points and incorporating lessons learned. The hold points and lessons learned, such as performing detailed personal protective equipment (PPE) inspections during sizing and repackaging operations, and using foam-type piping insulation to prevent workers from cutting or puncturing their PPE on sharp edge s or small shards generated during sizing operations, minimized direct contact with the Tc-99. To prevent the spread of contamination, the decommissioning activities were performed inside a containment enclosure connected to negative air machines. After performing over 235 individual entries totaling over 285 project hours, only one first aid was recorded during this five-stage project

  3. Dynamics of curved fronts

    CERN Document Server

    Pelce, Pierre

    1989-01-01

    In recent years, much progress has been made in the understanding of interface dynamics of various systems: hydrodynamics, crystal growth, chemical reactions, and combustion. Dynamics of Curved Fronts is an important contribution to this field and will be an indispensable reference work for researchers and graduate students in physics, applied mathematics, and chemical engineering. The book consist of a 100 page introduction by the editor and 33 seminal articles from various disciplines.

  4. Redox front penetration in the fractured Toki Granite, central Japan: An analogue for redox reactions and redox buffering in fractured crystalline host rocks for repositories of long-lived radioactive waste

    International Nuclear Information System (INIS)

    Yamamoto, Koshi; Yoshida, Hidekazu; Akagawa, Fuminori; Nishimoto, Shoji; Metcalfe, Richard

    2013-01-01

    reactions with rock forming minerals, in particular feldspar dissolution. These observations give important insights into the processes that control the rates of redox front penetration in fractured crystalline rock. The findings of the study can be used to help build confidence among stakeholders that radioactive waste would be emplaced in such rocks at greater depth than that to which oxidizing water is likely to penetrate in future

  5. Kinetics of Several Oxygen-Containing Carbon-Centered Free Radical Reactions with Nitric Oxide.

    Science.gov (United States)

    Rissanen, Matti P; Ihlenborg, Marvin; Pekkanen, Timo T; Timonen, Raimo S

    2015-07-16

    Kinetics of four carbon-centered, oxygen-containing free radical reactions with nitric oxide (NO) were investigated as a function of temperature at a few Torr pressure of helium, employing flow tube reactors coupled to a laser-photolysis/resonance-gas-discharge-lamp photoionization mass spectrometer (LP-RPIMS). Rate coefficients were directly determined from radical (R) decay signals under pseudo-first-order conditions ([R]0 ≪ [NO]). The obtained rate coefficients showed negative temperature dependences, typical for a radical-radical association process, and can be represented by the following parametrizations (all in units of cm(3) molecule(-1) s(-1)): k(CH2OH + NO) = (4.76 × 10(-21)) × (T/300 K)(15.92) × exp[50700/(RT)] (T = 266-363 K, p = 0.79-3.44 Torr); k(CH3CHOH + NO) = (1.27 × 10(-16)) × (T/300 K)(6.81) × exp[28700/(RT)] (T = 241-363 K, p = 0.52-3.43 Torr); k(CH3OCH2 + NO) = (3.58 ± 0.12) × 10(-12) × (T/300 K)(-3.17±0.14) (T = 221-363 K, p = 0.50-0.80 Torr); k(T)3 = 9.62 × 10(-11) × (T/300 K)(-5.99) × exp[-7100/(RT)] (T = 221-473 K, p = 1.41-2.95 Torr), with the uncertainties given as standard errors of the fits and the overall uncertainties estimated as ±20%. The rate of CH3OCH2 + NO reaction was measured in two density ranges due to its observed considerable pressure dependence, which was not found in the studied hydroxyalkyl reactions. In addition, the CH3CO + NO rate coefficient was determined at two temperatures resulting in k298K(CH3CO + NO) = (5.6 ± 2.8) × 10(-13) cm(3) molecule(-1) s(-1). No products were found during these experiments, reasons for which are briefly discussed.

  6. REACTION PRODUCTS AND CORROSION OF MOLYBDENUM ELECTRODE IN GLASS MELT CONTAINING ANTIMONY OXIDES AND SODIUM SULFATE

    Directory of Open Access Journals (Sweden)

    JIŘÍ MATĚJ

    2012-09-01

    Full Text Available The products on the interface of a molybdenum electrode and glass melt were investigated primarily at 1400°C in three model glass melts without ingredients, with 1 % Sb2O3 and with 1 % Sb2O3 and 0.5 % SO3 (wt. %, both under and without load by alternating current. Corrosion of the molybdenum electrode in glass melt without AC load is higher by one order of magnitude if antimony oxides are present. The corrosion continues to increase if sulfate is present in addition to antimony oxides. Isolated antimony droplets largely occur on the electrode-glass melt interface, and numerous droplets are also dissipated in the surrounding glass if only antimony oxides are present in the glass melt. A comparatively continuous layer of antimony occurs on the interface if SO3 is also present, antimony being always in contact with molybdenum sulfide. Almost no antimony droplets are dissipated in the glass melt. The total amount of precipitated antimony also increases. The presence of sulfide on the interface likely facilitates antimony precipitation. The reaction of molybdenum with antimony oxides is inhibited in sites covered by an antimony layer. The composition of sulfide layers formed at 1400°C approximates that of Mo2S3. At 1100°C, the sulfide composition approximates that of MoS4. Corrosion multiplies in the glass melt without additions through the effect of AC current, most molybdenum being separated in the form of metallic particles. Corrosion also increases in the glass melt containing antimony oxides. This is due to increased corrosion in the neighborhood of the separated antimony droplets. This mechanism also results in the loosening of molybdenum particles. The amount of precipitated antimony also increases through the effect of the AC current. AC exerts no appreciable effect on either corrosion, the character of the electrode-glass interface, or antimony precipitation in the glass melt containing SO3.

  7. Containment

    International Nuclear Information System (INIS)

    Anon.

    1987-01-01

    The primary mission of the Containment Group is to ensure that underground nuclear tests are satisfactorily contained. The main goal is the development of sound technical bases for containment-related methodology. Major areas of activity include siting, geologic description, emplacement hole stemming, and phenomenological predictions. Performance results of sanded gypsum concrete plugs on the Jefferson, Panamint, Cornucopia, Labquark, and Bodie events are given. Activities are also described in the following areas: computational capabilities site description, predictive modeling, and cavity-pressure measurement. Containment publications are listed. 8 references

  8. Kinetic study of the reaction of uranium with various carbon-containing gases

    International Nuclear Information System (INIS)

    Feron, G.

    1963-09-01

    The kinetic study of the reaction U + CO 2 and U + CO has been performed by a thermogravimetric method on a spherical uranium powder, in temperature ranges respectively from 460 to 690 deg. C and from 570 to 850 deg. C. The reaction with carbon dioxide leads to uranium dioxide. A carbon deposition takes place at the same time. The global reactions is the result of two reactions: U + 2 CO 2 → UO 2 + 2 CO U + CO 2 → UO 2 + C The reaction with carbon monoxide leads to a mixture of dioxide UO 2 , dicarbide UC 2 and free carbon. The main reaction can be written. U + CO → 1/2 UO 2 + 1/2 UC 2 The free carbon results of the disproportionation of the carbon monoxide. A remarkable separation of the two phases UO 2 and UC 2 can be observed. A mechanism accounting for the phenomenon has been proposed. The two reactions U + CO 2 and U + CO begin with a long germination period, after which, the reaction velocity seems to be limited in both cases by the ionic diffusion of oxygen through the uranium dioxide. (author) [fr

  9. Effect of micro-stirring on enzymatic reaction kinetics inside a biomimetic container

    Science.gov (United States)

    Gozen, Irep; Horowitz, Viva; Chambers, Zachary; Manoharan, Vinothan

    The intracellular environment is dynamic, influenced by the motion of active machinery such as cytoskeleton filaments and molecular motors. To understand whether and how such activity affects the rates of diffusion-limited reactions, we construct a model system consisting of a phospholipid vesicle encapsulating a small number of micro- or nanoparticles, the active motion of which can be induced by chemical or magnetic cues. We aim to determine a relation between active motion of particles and rates of enzymatic reactions in the confined volume. Our findings might illuminate how active motion influences cytoplasmic reaction dynamics, or may have played a role in protocell genetics.

  10. A miniature CSTR cascade for continuous flow of reactions containing solids

    OpenAIRE

    Mo, Yiming; Jensen, Klavs F

    2016-01-01

    Continuous handling of solids creates challenges for realizing continuous production of pharmaceuticals and fine chemicals. We present a new miniature continuous stirred-tank reactor (CSTR) cascade to handle solid-forming reactions in flow. Single-phase residence time distribution (RTD) measurements of the CSTR cascade reveal nearly ideal CSTR mixing behavior of the individual units. Consistency of experimental and predicted conversions of a Diels–Alder reaction further confirms the CSTR perf...

  11. Reaction sintering of a clay-containing silicon nitride bonded silicon carbide refractory

    International Nuclear Information System (INIS)

    Swenser, S.P.; Cheng, Y.B.

    1998-01-01

    Aspects of the reaction sequence for the reaction bonding of a cast refractory, which in the green state was composed of 79 wt-% SiC grit, 16 wt-% Si powder and 5 wt-% clay were established. As it was fired up to 1600 deg C in flowing N 2 (g), weight gains were noted and phase evolution was monitored by X-ray diffraction. However, details of the reaction sequence were not determined directly from this material because several reaction-bonding processes occurred simultaneously. Reaction features were ascertained by contrasting the weight changes and phase evolution in the refractory with those observed during reaction-bonding of (a) Si and clay without the SiC and (b) SiC and clay without the Si. In addition to silicon nitridation and the development of sialon phases by silicothermal and carbothermal reduction-nitridation processes, indirect evidence suggested that α-Si 3 N 4 formed by the carbothermal reduction-nitridation (CRN) of SiO(g). Copyright (1998) Australasian Ceramic Society

  12. Controlling the reaction between boron-containing sealing glass and a lanthanum-containing cathode by adding Nb2O5

    Science.gov (United States)

    Zhao, Dandan; Fang, Lihua; Tang, Dian; Zhang, Teng

    2016-09-01

    In solid oxide fuel cell (SOFC) stacks, the volatile boron species present in the sealing glass often react with the lanthanum-containing cathode, degrading the activity of the cathode (this phenomenon is known as boron poisoning). In this work, we report that this detrimental reaction can be effectively reduced by doping bismuth-containing borosilicate sealing glass-ceramic with a niobium dopant. The addition of Nb2O5 not only condenses the [SiO4] structural units in the glass network, but also promotes the conversion of [BO3] to [BO4]. Moreover, the Nb2O5 dopant enhances the formation of boron-containing phases (Ca3B2O6 and CaB2Si2O8), which significantly reduces the volatility of boron compounds in the sealing glass, suppressing the formation of LaBO3 in the reaction couple between the glass and the cathode. The reported results provide a new approach to solve the problem of boron poisoning.

  13. Geochemistry of Natural Redox Fronts

    International Nuclear Information System (INIS)

    Hofmann, B.A.

    1999-05-01

    Redox fronts are important geochemical boundaries which need to be considered in safety assessment of deep repositories for radioactive waste. In most cases, selected host-rock formations will be reducing due to the presence of ferrous minerals, sulphides, etc. During construction and operation of the repository, air will be introduced into the formation. After repository closure, oxidising conditions may persist locally until all oxygen is consumed. In the case of high-level waste, radiolysis of water may provide an additional source of oxidants. Oxidising conditions within a repository are thus possible and potentially have a strong influence on the mobility of many elements. The rate of movement of redox fronts, the boundary between oxidising and reducing environments, and their influence on migrating radionuclides are thus important factors influencing repository performance. The present report is a review of elemental behaviour at natural redox fronts, based on published information and work of the author. Redox fronts are geochemically and geometrically variable manifestations of a global interface between generally oxidising geochemical milieux in contact with the atmosphere and generally reducing milieux in contact with rocks containing ferrous iron, sulphide and/or organic carbon. A classification of redox fronts based on a subdivision into continental near-surface, marine near-surface, and deep environments is proposed. The global redox interface is often located close to the surface of rocks and sediments and, sometimes, within bodies of water. Temperature conditions are close to ambient. A deeper penetration of the global redox front to depths of several kilometres is found in basins containing oxidised sediments (red beds) and in some hydrothermal circulation systems. Temperatures at such deep redox fronts may reach 200 o C. Both near-surface and deep redox fronts are sites of formation of economic deposits of redox-sensitive elements, particularly of

  14. Copolymers containing meta-pyridylvinylene and para-arylenevinylene fragments: synthesis, quaternization reaction, and photophysical properties

    Science.gov (United States)

    Barashkov, Nikolay N.; Olivos, Hernando J.; Ferraris, John P.

    1997-12-01

    We report the Wittig reaction of the diphosphonium salt of 2,6-bis(chloromethyl)pyridine with terephthaldehyde, 2.5- dioctyloxyterephthaldehyde, or 9,10-anthracenedicarbaldehyde to form conjugated copolymers with fragments of 2,6 - pyridylene and para-arylenevinylene. The protonation reaction of poly(para-arylenevinylene)-co-(meta- pyridylvinylene) with hydrochloric acid and the quaternization reaction of poly(2,5-dioctyloxy-1,4- phenylenevinylene)-co-(2,6-pyridylvinylene) with methyl triflate have been investigated by spectrophotometric and fluorescent methods. The absorption, excitation and fluorescence spectra of these copolymers as well as their corresponding model compounds were studied and compared. The photophysical properties of the investigated polymers suggest that these materials could be good candidates for the fabrication of efficient blue and green light-emitting diodes.

  15. Comparative study of reactions between µ-nitrido- or µ-oxo-bridged iron tetrasulfophthalocyanines and sulfur-containing reductants

    Directory of Open Access Journals (Sweden)

    Dereven’kov Ilia A.

    2013-01-01

    Full Text Available A comparative study of reactivity of μ-nitrido- and μ-oxo-dimers of iron tetrasulfophthalocyanine has been performed in aqueous solutions of various acidity. The substantially higher stability of nitrido-bridged structure under both strongly acidic and strongly alkaline environments was demonstrated. Reactions of the complexes with sulfur-containing reductants (sodium dithionite, thiourea dioxide, sodium hydroxymethanesulfinate, L-cysteine has been studied. Differences in reduction processes were explained.

  16. Redox reactions of [FeFe]-hydrogenase models containing an internal amine and a pendant phosphine.

    Science.gov (United States)

    Zheng, Dehua; Wang, Mei; Chen, Lin; Wang, Ning; Sun, Licheng

    2014-02-03

    A diiron dithiolate complex with a pendant phosphine coordinated to one of the iron centers, [(μ-SCH2)2N(CH2C6H4-o-PPh2){Fe2(CO)5}] (1), was prepared and structurally characterized. The pendant phosphine is dissociated together with a CO ligand in the presence of excess PMe3, to afford [(μ-SCH2)2N(CH2C6H4-o-PPh2){Fe(CO)2(PMe3)}2] (2). Redox reactions of 2 and related complexes were studied in detail by in situ IR spectroscopy. A series of new Fe(II)Fe(I) ([3](+) and [6](+)), Fe(II)Fe(II) ([4](2+)), and Fe(I)Fe(I) (5) complexes relevant to Hox, Hox(CO), and Hred states of the [FeFe]-hydrogenase active site were detected. Among these complexes, the molecular structures of the diferrous complex [4](2+) with the internal amine and the pendant phosphine co-coordinated to the same iron center and the triphosphine diiron complex 5 were determined by X-ray crystallography. To make a comparison, the redox reactions of an analogous complex, [(μ-SCH2)2N(CH2C6H5){Fe(CO)2(PMe3)}2] (7), were also investigated by in situ IR spectroscopy in the absence or presence of extrinsic PPh3, which has no influence on the oxidation reaction of 7. The pendant phosphine in the second coordination sphere makes the redox reaction of 2 different from that of its analogue 7.

  17. Cold fusion reaction ignition at cavitation effect on deuterium-containing media

    International Nuclear Information System (INIS)

    Lipson, A.G.; Deryagin, B.V.; Klyuev, V.A.

    1992-01-01

    A possibility to induce 'cold' nuclear fusion reactions in the process of ultrasound cavitation in heavy water is studied. Nonstationary neutron emission is detected under cavitation in D 2 O on titanium vibrator which has the tracks of cavitation erosion (the vibrator ran in D 2 O to 20 hours). Maximum excess over background (12σ) was recorded under cavitation impact on the suspension of LaNi 5 D x dispersed particle in D 2 O

  18. Concentration-Discharge Relationships, Nested Reaction Fronts, and the Balance of Oxidative and Acid-Base Weathering Fluxes in an Alpine Catchment, East River, Colorado

    Science.gov (United States)

    Winnick, M.; Carroll, R. W. H.; Williams, K. H.; Maxwell, R. M.; Maher, K.

    2016-12-01

    Although important for solute production and transport, the varied interactions between biogeochemical processes and subsurface hydrology remain poorly characterized. We investigate these couplings in the headwaters of the East River, CO, a high-elevation shale-dominated catchment system in the Rocky Mountains, using concentration-discharge (C-Q) relationships for major cations, anions, and organic carbon. Dissolved organic carbon (DOC) displays a positive C-Q relationship with well-defined clockwise hysteresis, indicating the mobilization and depletion of DOC in the upper soil horizons and highlighting the importance of shallow flowpaths through the snowmelt period. Cation and anion concentrations demonstrate that carbonate weathering, which dominates solute fluxes, is promoted by both carbonic acid and sulfuric acid derived from oxidation of pyrite in the shale bedrock. Sulfuric acid weathering in the deep subsurface dominates during base flow conditions when waters have infiltrated below the hypothesized pyrite oxidation front, whereas carbonic acid weathering plays a dominant role during the snowmelt period as a result of shallow flowpaths. Differential C-Q relationships between solutes suggest that infiltrating waters approach calcite saturation before reaching the pyrite oxidation front, after which sulfuric acid reduces carbonate alkalinity. This increase in CO2(aq) at the expense of HCO3- results in outgassing of CO2 when waters equilibrate to surface conditions, and reduces the export of carbon and alkalinity from the East River by roughly 33% annually. Future changes in snowmelt dynamics that control the balance of carbonic and sulfuric acid weathering therefore have the capacity to substantially alter the cycling of carbon in the East River catchment. Ultimately, we demonstrate that differential C-Q relationships between major solutes can provide unique insights into the complex subsurface flow and biogeochemical dynamics that operate at catchment scales.

  19. Mechanism of NH{sub 3} desorption during the reaction of H{sub 2} with nitrogen containing carbonaceous materials

    Energy Technology Data Exchange (ETDEWEB)

    Juan F. Espinal; Thanh N. Truong; Fanor Mondragon [University of Antioquia, Medellin (Colombia). Institute of Chemistry

    2005-07-01

    The continued increase in demand for natural gas has stimulated the interest in coal conversion to methane as synthetic natural gas by hydropyrolysis of coal (pyrolysis in a H{sub 2} atmosphere). Because the produced raw gas contains considerable amounts of gaseous N-containing products that have to be removed before delivering to final users, the information on distribution of coal-N is important for designing purification processes. It has been reported in the literature that NH{sub 3} is the main nitrogen containing gas that is released during the hydropyrolysis process. Other gases such as HCN and N{sub 2} are also released but in a much smaller amount. To the best of our knowledge, the mechanism for NH{sub 3} desorption during hydrogen reaction with carbonaceous materials has not been studied. We carried out a molecular modeling study using Density Functional Theory in order to get an insight of the mechanism and thermodynamics for NH{sub 3} evolution using pyridinic nitrogen as a model of N-containing carbonaceous material. We propose a mechanism that involves consecutive hydrogenation steps that lead to C-N bond breakage and NH{sub 3} desorption to the gas phase. It was found that the first hydrogenation reaction is highly exothermic. However, further hydrogenations are endothermic. Several pathways for NH{sub 3} evolution were proposed and most of them show high exothermicity. 17 refs., 2 figs.

  20. Unsteady aspects of sodium-water reaction. Water clearing of sodium containing equipments

    International Nuclear Information System (INIS)

    Carnevali, Sofia

    2012-01-01

    Sodium fast Reactor (FSR) is one of the most promising nuclear reactor concepts in the frame of Generation IV Systems to be commercialised in the next decades. One important safety issue about this technology is the highly exothermal chemical reaction of sodium when brought in contact with liquid water. This situation is likely, in particular during decommissioning, when sodium needs to be firstly converted ('destroyed') into non-reactive species. This is achieved by water washing: the major products are then gaseous hydrogen and corrosive soda. Today, such operations are performed in confined chambers to mitigate the consequences of any possible abnormal conditions. It has for long been believed that the main safety problem was the combustion of hydrogen in the surrounding air despite some pioneering works suggested that even without air the reaction could be explosive. It is extremely important to clarify the phenomenology of sodium-water interactions since available knowledge does not allow a robust extrapolation of existing data/model to full scale plants. The primary objective of this work is to identify and assess the details of the phenomenology, especially at the sodium/water interface, to isolate the leading mechanisms and to propose a robust and innovative modelling approach. A large body of yet unreleased experimental data extracted from the files of the French Commissariat a l'Energie Atomique (CEA) was collated and analysed on the basis of 'explosion' physics. Some additional experiments were also performed to fill some gaps, especially about the kinetics of the reaction. The results strongly suggest that the fast expansion of gas producing a blast wave in certain conditions is a kind of vapour explosion. It also appears that any potential hydrogen-air explosion should be strongly mitigated by the large quantity of water vapour emanating also from the reaction zone. The limitations of existing modelling approaches are clearly

  1. Switching wormlike micelles of selenium-containing surfactant using redox reaction.

    Science.gov (United States)

    Zhang, Yongmin; Kong, Weiwei; Wang, Cheng; An, Pengyun; Fang, Yun; Feng, Yujun; Qin, Zhirong; Liu, Xuefeng

    2015-10-14

    A novel redox-switchable wormlike micellar system was developed based on a mixture of selenium-containing zwitterionic surfactant and commercially available anionic surfactant sodium dodecyl sulfate, which reversibly and quickly responds to H2O2 and vitamin C, and shows circulatory gel/sol transition, reflecting changes in aggregate morphology from entangled worms to vesicles.

  2. Coal chemistry. 8. Reactions of tetralin with coal and with some carbon-14-containing model compounds

    International Nuclear Information System (INIS)

    Collins, C.J.; Raaen, V.F.; Benjamin, B.M.; Maupin, P.H.; Roark, W.H.

    1979-01-01

    When coal was treated with tetralin-l- 14 C at 400 0 C, small yields of α- and β-methylnaphthalenes- 14 C were observed. In order to determine the mechanism of the reaction, tetralin was heated with 14 C-labeled 1,3-diphenylpropanes (1), with 1,3-diphenylpropene (2), and with 14 C-labeled phenetoles (3). In each case methylnaphthalenes were observed, and the origins of the methyl groups were determined with carbon-14. In addition to the methylnaphthalenes, 1 and 2 also yielded toluene and ethylbenzene (after 19 h), whereas phenetole-β- 14 C (3-β- 14 C) yielded toluene (unlabeled) plus ethyl- 14 C-benzene, benzene, phenol, and a mixture of α- and β-ethyl- 14 C-naphthalenes. Crossover experiments with labeled phenetole and unlabeled ethyl p-tolyl ether proved the intramolecularity of the reaction phenetole → toluene + ethylbenzene, thus illustrating a 1,2-phenyl shift from oxygen to carbon

  3. On the detection of chemical reactions in the systems containing tritium and luminescent labels

    International Nuclear Information System (INIS)

    Krasnyanskij, A.V.

    1997-01-01

    Features of detecting chemical processes in scintillation systems containing tritium, are considered on the base of a model, connecting the counting rate with the mass of cenverted substance. It is shown that the character of the cunting rate dependence on the mass of the converted phase is determined by the spatial distribution of scintillating and radioactive phases in microheterogeneous systems. Calculation results can be used for designing sensor elements, based on radionuclide luminescent probe

  4. Effect of electron injection on defect reactions in irradiated silicon containing boron, carbon, and oxygen

    Science.gov (United States)

    Makarenko, L. F.; Lastovskii, S. B.; Yakushevich, H. S.; Moll, M.; Pintilie, I.

    2018-04-01

    Comparative studies employing Deep Level Transient Spectroscopy and C-V measurements have been performed on recombination-enhanced reactions between defects of interstitial type in boron doped silicon diodes irradiated with alpha-particles. It has been shown that self-interstitial related defects which are immobile even at room temperatures can be activated by very low forward currents at liquid nitrogen temperatures. Their activation is accompanied by the appearance of interstitial carbon atoms. It has been found that at rather high forward current densities which enhance BiOi complex disappearance, a retardation of Ci annealing takes place. Contrary to conventional thermal annealing of the interstitial boron-interstitial oxygen complex, the use of forward current injection helps to recover an essential part of charge carriers removed due to irradiation.

  5. Alumina plate containing photosystem I reaction center complex oriented inside plate-penetrating silica nanopores.

    Science.gov (United States)

    Kamidaki, Chihiro; Kondo, Toru; Noji, Tomoyasu; Itoh, Tetsuji; Yamaguchi, Akira; Itoh, Shigeru

    2013-08-22

    The photosynthetic photosystem I reaction center complex (PSI-RC), which has a molecular diameter of 21 nm with 100 pigments, was incorporated into silica nanopores with a 100-nm diameter that penetrates an alumina plate of 60-μm thickness to make up an inorganic-biological hybrid photocell. PSI-RCs, purified from a thermophilic cyanobacterium, were stable inside the nanopores and rapidly photoreduced a mediator dye methyl viologen. The reduced dye was more stable inside nanopores suggesting the decrease of dissolved oxygen. The analysis by a cryogenic electron spin paramagnetic resonance indicated the oriented arrangement of RCs inside the 100-nm nanopores, with their surface parallel to the silica wall and perpendicular to the plane of the alumina plate. PSI RC complex in the semicrystalline orientation inside silica nanopores can be a new type of light energy conversion unit to supply strong reducing power selectively to other molecules inside or outside nanopores.

  6. Reaction

    African Journals Online (AJOL)

    abp

    19 oct. 2017 ... Reaction to Mohamed Said Nakhli et al. concerning the article: "When the axillary block remains the only alternative in a 5 year old child". .... Bertini L1, Savoia G, De Nicola A, Ivani G, Gravino E, Albani A et al ... 2010;7(2):101-.

  7. Kinetics of reaction of peroxynitrite with selenium- and sulfur-containing compounds

    DEFF Research Database (Denmark)

    Storkey, Corin; Pattison, David I.; Ignasiak, Marta T.

    2015-01-01

    with peroxynitrite with high rate constants. Low molecular mass selenols react particularly rapidly with peroxynitrite, with second order rate constants k2 in the range 5.1×105-1.9×106 M-1 s-1, and 250-830 fold faster than the corresponding thiols (RSH) and many other endogenous biological targets. Reactions......Peroxynitrite (the physiological mixture of ONOOH and its anion, ONOO-) is a powerful biologically-relevant oxidant capable of oxidizing and damaging a range of important targets including sulfides, thiols, lipids, proteins, carbohydrates and nucleic acids. Excessive production of peroxynitrite...... of peroxynitrite with selenides, including selenosugars are approximately 15-fold faster than their sulfur homologs with k2 approximately 2.5×103 M-1 s-1. The rate constants for diselenides and sulfides were slower with k2 0.72-1.3×103 M-1 s-1 and approximately 2.1×102 M-1 s-1 respectively. These studies...

  8. Front line of cement technolgy and control. Part 5. ; Baking process and chemical reactions. Cement saisentan sono gijutsu to kanri 5. ; Shosei katei to kagaku hanno

    Energy Technology Data Exchange (ETDEWEB)

    Hirai, M. (Ube Industries, Ltd., Yamaguchi (Japan))

    1990-06-01

    The baking process in cement production means the process that the raw materials which were mixed and pulverized in the raw material preparation process are charged into a reaction furnace which is called kiln, and clinders (intermediate product of cement) are generated. It is the process which affects quality as well as production cost of cement more significantly than anything else. In this article, an outline of the above baking facilities, how the raw materials change and clinkers are generated therein, and how they are controlled are introduced. Clinkers are composed of such products as alite, belite, aluminate and ferrite, etc. which were generated after decomposition reactions of such raw materials as lime stone, clay, silica rock and iron oxide in the above kiln. The essential ponts of the process control which makes the generation reactions of clinker compounds efficiently are such two points as well balanced raw materials to be charged into the baking facilities and stable operation of such facilities. The quality of cement which is required as finished goods is achieved by the quality control at each intermediate process and the quality tests of cement. 5 refs., 10 figs., 2 tabs.

  9. Nitroso Diels-Alder (NDA) Reaction as an Efficient Tool for the Functionalization of Diene-Containing Natural Products

    Science.gov (United States)

    Carosso, Serena; Miller, Marvin J.

    2014-01-01

    This review describes the use of nitroso Diels-Alder reactions for the functionalization of complex diene-containing natural products in order to generate libraries of compounds with potential biological activity. The application of this methodology to the structural modification of a series of natural products (thebaine, steroidal dienes, rapamycin, leucomycin, colchicine, isocolchicine and piperine) is discussed using relevant examples from the literature from 1973 onwards. The biological activity of the resulting compounds is also discussed. Additional comments are provided that evaluate the methodology as a useful tool in organic, bioorganic and medicinal chemistry. PMID:25119424

  10. Features of E-Z-photoisomerization reversible reaction of 4-styrylpyridine crown-containing complexes with different cations

    International Nuclear Information System (INIS)

    Fedorov, Yu.V.; Shepel', N.Eh.; Chernikova, E.Yu.; Fedorova, O.A.; Gulakova, E.N.; Avakyan, V.G.; Jonushauskas, G.

    2008-01-01

    E-Z-Photoisomerization reversible reaction of crown-containing 4-styrylpyridine in the presence of alkali metal perchlorates (Ca 2+ , Mg 2+ , Ba 2+ ) gifted in the formation of complexes with crown-ether fragments, as well as heavy metal perchlorates (Hg 2+ , Cd 2+ ) gifted in the coordination with nitrogen atom of heterocyclic residuum has been studied. Effect of complexing on the photoisomerization is determined by electron spectroscopy and NMR 1 H, structures of the formed Z-isomers are established. The possibility of the E-Z-isomerization control with the use of supramolecular complexing is confirmed by the investigations [ru

  11. Laser-induced photochemical reaction of aqueous maleic acid solutions containing H2O2

    International Nuclear Information System (INIS)

    Shimizu, Yuichi; Kawanishi, Shunichi; Suzuki, Nobutake

    1995-01-01

    Hydroxy acid such as glycolic, tartaric and malic acids was directly produced by XeF-laser irradiation of the N 2 -saturated maleic acid aqueous solution containing H 2 O 2 . The selectivities of these products at the maximum of tartaric acid were 71, 4, and 2% at H 2 O 2 feeding rate of 3.2 ml h -1 , respectively. On the other hand, the irradiation of maleates such as dipotassium, calcium, and disodium greatly enhanced the selectivities of tartaric acid formation to 19%, and of malic acid formation to 13%, respectively, for dipotassium maleate. It may be considered from these results that the stability of the hydroxylated intermediate radical plays an important role for the efficient formations of tartaric and malic acids. (author)

  12. Effect of the container in the synthesis of the combustion reaction of ZnAl2O4

    International Nuclear Information System (INIS)

    Silva, D.A.R.; Cavalcanti, L.R.C.; Moura, A.L.S.; Rocha, M.L.; Neto, O.L.A.; Cabral, I.C.; Viana, K.M.S.; Costa, A.C.F.M.

    2012-01-01

    In the present work is a study on the influence of the container in the synthesis of the combustion reaction ZnAl 2 O 4 . Products of combustion obtained for both synthesis routes, were broken and sieved in 325 mesh (44μm). The powders resulting from two types of synthesis were characterized by X-ray diffraction and scanning electron microscopy. By means of XRD analysis showed the formation of the main phase of zinc aluminate spinel (Z) as phase the mineral guanine in the two procedures synthesis. By means of SEM analysis showed that in the procedure used the crucible metal zinc aluminate is introduced in the form of smaller agglomerates. Therefore, the container used in the synthesis of combustion influences the microstructure of the material synthesized. (author)

  13. l-Tyrosine Contained in Dietary Supplement by Chemiluminescence Reaction of an Iron-Phthalocyanine Complex

    Directory of Open Access Journals (Sweden)

    Takao Ohtomo

    2012-01-01

    Full Text Available The chemiluminescence (CL signal immediately appeared when a hydrogen peroxide solution was injected into an iron-phthalocyanine tetrasulfonic acid (Fe-PTS aqueous solution. Moreover, the CL intensity of Fe-PTS decreased by adding L-tyrosine. Based on these results, the determination of trace amounts of L-tyrosine was developed using the quenching-chemiluminescence. The calibration curve of L-tyrosine was obtained in the concentration range of 2.0×10−7 M to 2.0×10−5 M. Moreover, the relative standard deviation (RSD was 1.63 % (=5 for 2.0×10−6 M L-tyrosine, and its detection limits (3σ were 1.81×10−7 M. The spike and recovery experiments for L-tyrosine were performed using a soft drink. Furthermore, the determination of L-tyrosine was applied to supplements containing various kinds of amino acids. Each satisfactory relative recovery was obtained at 98 to 102%.

  14. Synthesis, reactions and biological activity of some new bis-heterocyclic ring compounds containing sulphur atom

    Science.gov (United States)

    2013-01-01

    Background The derivatives of thieno[2,3-b]thiophene belong to a significant category of heterocyclic compounds, which have shown a wide spectrum of medical and industrial application. Results A new building block with two electrophilic center of thieno[2,3-b]thiophene derivatives 2 has been reported by one-pot reaction of diketone derivative 1 with Br2/AcOH in excellent yield. A variety of heteroaromatics having bis(1H-imidazo[1,2a] benzimidazole), bis(1H-imidazo[1,2-b][1,2,4]triazole)-3-methyl-4-phenylthieno[2,3-b]thiophene derivatives, dioxazolo-, dithiazolo-, and 1H-imidazolo-3-methyl-4-phenylthieno[2,3-b]thiophene derivatives as well pyrrolo, thiazolo -3-methyl-4-phenylthieno[2,3-b]thiophene derivatives have been designed, synthesized, characterized, and evaluated for their biological activity. Compounds 3–9 showed good bioassay result. These new derivatives were evaluated for anti-cancer activity against PC-3 cell lines, in vitro antioxidant potential and β-glucuronidase and α-glucosidase inhibitory activities. Compound 3 (IC50 = 56.26 ± 3.18 μM) showed a potent DPPH radical scavenging antioxidant activity and found to be more active than standard N-acetylcystein (IC50 = 105.9 ± 1.1 μM). Compounds 8a (IC50 = 13.2 ± 0.34 μM) and 8b (IC50 = 14.1 ± 0.28 μM) found as potent inhibitor of α-glucusidase several fold more active than the standard acarbose (IC50 = 841 ± 1.73 μM). Most promising results were obtained in β-glucuronidase enzyme inhibition assay. Compounds 5 (IC50 = 0.13 ± 0.019 μM), 6 (IC50 = 19.9 ± 0.285 μM), 8a (IC50 = 1.2 ± 0.0785 μM) and 9 (IC50 = 0.003 ± 0.09 μM) showed a potent inhibition of β-glucuronidase. Compound 9 was found to be several hundred fold more active than standard D-Saccharic acid 1,4-lactone (IC50 = 45.75 ± 2.16 μM). Conclusions Synthesis, characterization, and in vitro biological activity of a series of

  15. The first experimental confirmation of the fractional kinetics containing the complex-power-law exponents: Dielectric measurements of polymerization reactions

    Science.gov (United States)

    Nigmatullin, R. R.; Arbuzov, A. A.; Salehli, F.; Giz, A.; Bayrak, I.; Catalgil-Giz, H.

    2007-01-01

    For the first time we achieved incontestable evidence that the real process of dielectric relaxation during the polymerization reaction of polyvinylpyrrolidone (PVP) is described in terms of the fractional kinetic equations containing complex-power-law exponents. The possibility of the existence of the fractional kinetics containing non-integer complex-power-law exponents follows from the general theory of dielectric relaxation that has been suggested recently by one of the authors (R.R.N). Based on the physical/geometrical meaning of the fractional integral with complex exponents there is a possibility to develop a general theory of dielectric relaxation based on the self-similar (fractal) character of the reduced (averaged) microprocesses that take place in the mesoscale region. This theory contains some essential predictions related to existence of the non-integer power-law kinetics and the results of this paper can be considered as the first confirmation of existence of the kinetic phenomena that are described by fractional derivatives with complex-power-law exponents. We want to stress here that with the help of a new complex fitting function for the complex permittivity it becomes possible to describe the whole process for real and imaginary parts simultaneously throughout the admissible frequency range (30 Hz-13 MHz). The fitting parameters obtained for the complex permittivity function for three temperatures (70, 90 and 110 °C) confirm in general the picture of reaction that was known qualitatively before. They also reveal some new features, which improve the interpretation of the whole polymerization process. We hope that these first results obtained in the paper will serve as a good stimulus for other researches to find the traces of the existence of new fractional kinetics in other relaxation processes unrelated to the dielectric relaxation. These results should lead to the reconsideration and generalization of irreversibility and kinetic phenomena that

  16. Systematic front distortion and presence of consecutive fronts in a precipitation system

    NARCIS (Netherlands)

    Volford, A.; Izsak, F.; Ripszam, M.; Lagzi, I.

    2006-01-01

    A new simple reaction-diffusion system is presented focusing on pattern formation phenomena as consecutive precipitation fronts and distortion of the precipitation front.The chemical system investigated here is based on the amphoteric property of aluminum hydroxide and exhibits two unique phenomena.

  17. Ab-initio structure determination of novel strontium-containing layered silicate AES-18 synthesized using mechanochemical reaction

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, Takuji [AIST Tohoku, Sendai (Japan). Research Center for Compact Chemical System; Ideta, Chiaki; Yamamoto, Katsutoshi [Kitakyushu Univ. (Japan). Faculty of Environmental Engineering

    2013-07-01

    A new strontium-containing layered silicate, alkaline earth-containing silicate (AES)-18 [chemical composition: Si{sub 16}O{sub 24}(OH){sub 16} . {Sr(OH)_2}{sub 8} . (KOH){sub 2}], was synthesized utilizing a mechanochemical reaction in which an admixture of strontium hydroxide, which unfavorably precipitates in conventional syntheses, and a fumed silica (Aerosil) was allowed to react in the solid phase. The crystal structure of AES-18 was elucidated by the charge-flipping method using powder X-ray diffraction data, and the obtained structure was refined by a combination with the Rietveld method and the maximum entropy method (MEM). The structure analyses showed a tetragonal symmetry with a = 0.912738(3) nm, c = 1.628120(8) nm, and the space group P4{sub 2}/mnc. Two silicate layers composed of Q{sup 3} local structure [(-SiO){sub 3}Si-OH], 7-coordinated Sr{sup 2+} cations, and K{sup +} cations were included in a unit cell, and a Sr{sub 4}(OH){sub 17} cluster was formed between adjacent silicate layers. The framework topology of AES-18 containing 4- and 8-Si-membered rings was similar to that of paracelsian.

  18. Comparison of the effect of caffeine containing energy drink and Glucon D on auditory and visual reaction time

    Directory of Open Access Journals (Sweden)

    Viswanathan Shanti

    2016-07-01

    Full Text Available There has been an increase in the consumption of energy drinks in the last decade which raises a concern regarding its safety. Glucose improves information processing and cognition. But research on only glucose containing drink is lacking. In the present study, we evaluated the effect of Red Bull,a caffeine containing energy drink and Glucon D on visual and auditory reaction time in medical students. A total of 30 students,15 boys and 15 girls, in the age group 18 to 22 yrs were recruited for the study after taking approval from the Institutional Ethical Committee. At the beginning, a baseline record of pulse, blood pressure, ART and VRT were taken for all students. The students were given Red Bull and readings were taken after 30 minutes. After an interval of five days the same procedure was repeated with Glucon D. All readings were taken between 10-12 a.m. On comparing the effect of Red Bull on either sex, there was no significant difference. On comparing the effect of the two energy drinks, the p value between the effect of Red Bull and Glucon D on ART was 0.457 and on VRT was 0.314.Both were not statistically significant. There was a significant increase in pulse rate with Red Bull (P=0.036. The mean DBP increased marginally with Red Bull which was not significant (P=0.496.

  19. Electrocatalytic Performance of Carbon Supported WO3-Containing Pd–W Nanoalloys for Oxygen Reduction Reaction in Alkaline Media

    Directory of Open Access Journals (Sweden)

    Nan Cui

    2018-05-01

    Full Text Available In this paper, we report that WOx containing nanoalloys exhibit stable electrocatalytic performance in alkaline media, though bulk WO3 is easy to dissolve in NaOH solution. Carbon supported oxide-rich Pd–W alloy nanoparticles (PdW/C with different Pd:W atom ratios were prepared by the reduction–oxidation method. Among the catalysts, the oxide-rich Pd0.8W0.2/C (Pd/W = 8:2, atom ratio exhibits the highest catalytic activity for the oxygen reduction reaction. The X-ray photoelectron spectroscopy data shows that ~40% of Pd atoms and ~60% of the W atoms are in their oxide form. The Pd 3d5/2 binding energy of the oxide-rich Pd–W nanoalloys is higher than that of Pd/C, indicating the electronic structure of Pd is affected by the strong interaction between Pd and W/WO3. Compare to Pd/C, the onset potential of the oxygen reduction reaction at the oxide-rich Pd0.8W0.2/C shifts to a higher potential. The current density (mA·mg Pd−1 at the oxide-rich Pd0.8W0.2/C is ~1.6 times of that at Pd/C. The oxide-rich Pd0.8W0.2/C also exhibits higher catalytic stability than Pd/C, which demonstrates that it is a prospective candidate for the cathode of fuel cells operating with alkaline electrolyte.

  20. Study of the violation of the T and CP symmetries in the reactions Λb0 → Λ0 + a vector meson. Validation of the Front-end electronics for the PreShower detector of the LHCb experiment

    International Nuclear Information System (INIS)

    Conte, E.

    2007-11-01

    This thesis probes the beauty baryon physics in the framework of the LHCb experiment. The present study deals with the Λ b 0 → Λ 0 V decays where V is a vector meson such as J/Ψ(μ + μ - ), φ(K + K - ), ω(π + π - π0) or the ρ 0 - ω 0 (π + π - ) mixing. These processes allow to test independently the CP symmetry, which violation has not been observed yet in the baryonic sector, and the T symmetry, which experimental proofs are limited. Among the possible perspectives, a precise measurement of the Λ b 0 lifetime could contribute to the resolution of the raising theoretical-experimental puzzle. A phenomenological model of the Λ b 0 → Λ 0 V decays has been performed, from which branching ratios and angular distributions have been estimated. An advanced study of the reconstruction and the selection of these reactions by the LHCb apparatus shows that the channel Λ b 0 → Λ 0 J/Ψ is the dominant channel on both statistics and purity aspects. The Λ b 0 lifetime measure is the most imminent result; the constrains on asymmetries due to CP and T violation require several data taking years. Besides, an instrumental work has been achieved on the read-out electronics, called Front-End, of the experiment pre-shower. This contribution takes into account the validation of the prototype boards and the development of tools required by the qualification of the 100 production boards. (author)

  1. EFFECTS OF THE LITHIUM – CONTAINING SORBENT ON TERMS OF BEHAVIORAL REACTIONS UNDER CHRONIC ALCOHOL INTOXICATION MODEL

    Directory of Open Access Journals (Sweden)

    A. A. Kotlyarova

    2016-01-01

    Full Text Available Lithium preparations are widely used for stabilize mood in case of bipolar affective disorder. Currently neuroprotective and neuroregenerative effects of lithium are of interest as in case of acute brain injury, also in chronic neurodegenerative diseases such as dementia, alcoholism, Alzheimer disease, etc. [1–5]. In clinical practice use of lithium preparations is limited due to difficult adjustment of drug dosage, necessity of monitoring its concentration in blood, side effects development as a result of accumulation of lithium in a body. For the purpose of improvement of pharmacologic properties lithium is combined with other agents (for example modifying sorbent thus it can produce longer-term and more harmless (less side reactions effect in the long view. Lithium immobilization on sorption basis will allow to use sorbent as detoxicant and carrying agent of drugs to body. The purpose of the work is studying the effect of the lithium – containing sorbent on terms of behavioral reactions under chronic alcohol intoxication model.Materials and methods. During the work we used nonlinear mice – males, which weight 25–30 g (180 animals. Chronic alcohol intoxication was precipitated via 40% proof spirit injections (oral supplementation in quantity of 3 g/kg during 2 weeks, additionally mice drunk 5% proof spirit from drinking bowl. Each experimental group consisted of 10 animals. Study drugs were inserted inside while ethanol injecting. Control animals were inserted 0,9% salin solution. Emotional state of animals was assessed through forced swim test, short – term memory assessment was performed through conditioned passive avoidance reflex. Effect of chronic alcohol intoxication on the parameters of conditioned reflex activity was measured every 7 days.Results. It was found that the investigated lithium-containing sorbent increases: the number of mice are trained passive avoidance reflex, remembering percent of electric shock

  2. Recent Advances in the Synthesis of N-Containing Heteroaromatics via Heterogeneously Transition Metal Catalysed Cross-Coupling Reactions

    Directory of Open Access Journals (Sweden)

    Laurent Djakovitch

    2011-06-01

    Full Text Available N-containing heteroaromatics are important substructures found in numerous natural or synthetic alkaloids. The diversity of the structures encountered, as well as their biological and pharmaceutical relevance, have motivated research aimed at the development of new economical, efficient and selective synthetic strategies to access these compounds. Over more than 100 years of research, this hot topic has resulted in numerous so-called “classical synthetic methods” that have really contributed to this important area. However, when the selective synthesis of highly functional heteroaromatics like indoles, quinolones, indoxyls, etc. is considered these methods remain limited. Recently transition metal-catalysed (TM-catalysed procedures for the synthesis of such compounds and further transformations, have been developed providing increased tolerance toward functional groups and leading generally to higher reaction yields. Many of these methods have proven to be the most powerful and are currently applied in target- or diversity-oriented syntheses. This review article aims at reporting the recent developments devoted to this important area, focusing on the use of heterogeneous catalysed procedures that include either the formation of the heterocyclic ring towards the nuclei or their transformations to highly substituted compounds.

  3. Polymersomes containing iron sulfide (FeS) as primordial cell model : for the investigation of energy providing redox reactions.

    Science.gov (United States)

    Alpermann, Theodor; Rüdel, Kristin; Rüger, Ronny; Steiniger, Frank; Nietzsche, Sandor; Filiz, Volkan; Förster, Stephan; Fahr, Alfred; Weigand, Wolfgang

    2011-04-01

    According to Wächtershäuser's "Iron-Sulfur-World" one major requirement for the development of life on the prebiotic Earth is compartmentalization. Vesicles spontaneously formed from amphiphilic components containing a specific set of molecules including sulfide minerals may have lead to the first autotrophic prebiotic units. The iron sulfide minerals may have been formed by geological conversions in the environment of deep-sea volcanos (black smokers), which can be observed even today. Wächtershäuser postulated the evolution of chemical pathways as fundamentals of the origin of life on earth. In contrast to the classical Miller-Urey experiment, depending on external energy sources, the "Iron-Sulfur-World" is based on the catalytic and energy reproducing redox system FeS+H2S-->FeS2+H2. The energy release out of this redox reaction (∆RG°=-38 kJ/mol, pH 0) could be the cause for the subsequent synthesis of complex organic molecules and the precondition for the development of more complex units similar to cells known today. Here we show the possibility for precipitating iron sulfide inside vesicles composed of amphiphilic block-copolymers as a model system for a first prebiotic unit. Our findings could be an indication for a chemoautotrophic FeS based origin of life.

  4. Kinetic study of the reaction of uranium with various carbon-containing gases; Etude cinetique de la reaction sur l'uranium de differents gaz carbones

    Energy Technology Data Exchange (ETDEWEB)

    Feron, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1963-09-15

    The kinetic study of the reaction U + CO{sub 2} and U + CO has been performed by a thermogravimetric method on a spherical uranium powder, in temperature ranges respectively from 460 to 690 deg. C and from 570 to 850 deg. C. The reaction with carbon dioxide leads to uranium dioxide. A carbon deposition takes place at the same time. The global reactions is the result of two reactions: U + 2 CO{sub 2} {yields} UO{sub 2} + 2 CO U + CO{sub 2} {yields} UO{sub 2} + C The reaction with carbon monoxide leads to a mixture of dioxide UO{sub 2}, dicarbide UC{sub 2} and free carbon. The main reaction can be written. U + CO {yields} 1/2 UO{sub 2} + 1/2 UC{sub 2} The free carbon results of the disproportionation of the carbon monoxide. A remarkable separation of the two phases UO{sub 2} and UC{sub 2} can be observed. A mechanism accounting for the phenomenon has been proposed. The two reactions U + CO{sub 2} and U + CO begin with a long germination period, after which, the reaction velocity seems to be limited in both cases by the ionic diffusion of oxygen through the uranium dioxide. (author) [French] L'etude cinetique des reactions U sol + CO{sub 2} gaz et U sol + CO gaz a ete effectuee par thermogravirnetrie sur une poudre d'uranium a grains spheriques, les domaines de temperature etudies s'etendant respectivement de 460 a 690 deg. C et de 570 a 850 deg. C. L'action du dioxyde de carbone conduit au dioxyde d'uranium UO{sub 2}; il se produit en meme temps un depot de carbone. La reaction globale resulte des deux reactions: U + 2 CO{sub 2} {yields} UO{sub 2} + 2 CO U + CO{sub 2} {yields} UO{sub 2} + C Le mono-oxyde de carbone conduit a un melange de dioxyde UO{sub 2}, de dicarbure UC{sub 2} et de carbone libre. La reaction principale s'ecrit: U + CO {yields} 1/2 UO{sub 2} + 1/2 UC{sub 2} Le carbone libre provient de la dismutation du mono-oxyde de carbone. On observe une separation remarquable des deux phases UO{sub 2} et UC{sub 2}; un mecanisme rendant compte de ce phenomene a

  5. Product ion distributions for the reactions of NO+ with some N-containing and O-containing heterocyclic compounds obtained using SRI-TOF-MS

    Czech Academy of Sciences Publication Activity Database

    Mochalski, P.; Unterkofler, K.; Španěl, Patrik; Smith, D.; Amann, A.

    2015-01-01

    Roč. 386, JUL 2015 (2015), s. 42-46 ISSN 1387-3806 Institutional support: RVO:61388955 Keywords : heterocyclic compounds * SRI-TOF-MS * NO+ reactions Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.183, year: 2015

  6. Heating-induced inner-sphere substitution and reduction-oxidation reactions of the solid phenanthroline containing cobalt (2) and cobalt (3) complexes

    International Nuclear Information System (INIS)

    Palade, D.M.

    1996-01-01

    The results of the differential thermal and thermogravimetric analyses of solid phenanthroline-containing complexes of cobalt (2) and cobalt (3) in the atmosphere of the air have been analyzed. Mechanism of redox reactions occurring when cobalt (3) complexes are heated has been discussed. It is shown that some of gaseous products of the redox processes appear as a result of secondary reactions and not the processes of the ligands oxidation by Co 3+ . The influence of certain inner-sphere and coordinated anions (of I, inclusively) on cobalt (3) complexes behaviour during heating has been considered

  7. Light-Front QCD

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, S.

    2004-11-30

    In these lectures, I survey a number of applications of light-front methods to hadron and nuclear physics phenomenology and dynamics, including light-front statistical physics. Light-front Fock-state wavefunctions provide a frame-independent representation of hadrons in terms of their fundamental quark and gluon degrees of freedom. Nonperturbative methods for computing LFWFs in QCD are discussed, including string/gauge duality which predicts the power-law fall-off at high momentum transfer of light-front Fock-state hadronic wavefunctions with an arbitrary number of constituents and orbital angular momentum. The AdS/CFT correspondence has important implications for hadron phenomenology in the conformal limit, including an all-orders derivation of counting rules for exclusive processes. One can also compute the hadronic spectrum of near-conformal QCD assuming a truncated AdS/CFT space. Given the LFWFs, one can compute form factors, heavy hadron decay amplitudes, hadron distribution amplitudes, and the generalized parton distributions underlying deeply virtual Compton scattering. The quantum fluctuations represented by the light-front Fock expansion leads to novel QCD phenomena such as color transparency, intrinsic heavy quark distributions, diffractive dissociation, and hidden-color components of nuclear wavefunctions. A new test of hidden color in deuteron photodisintegration is proposed. The origin of leading-twist phenomena such as the diffractive component of deep inelastic scattering, single-spin asymmetries, nuclear shadowing and antishadowing is also discussed; these phenomena cannot be described by light-front wavefunctions of the target computed in isolation. Part of the anomalous NuTeV results for the weak mixing angle {theta}{sub W} could be due to the non-universality of nuclear antishadowing for charged and neutral currents.

  8. A plug flow model for chemical reactions and aerosol nucleation and growth in an alkali-containing flue gas

    DEFF Research Database (Denmark)

    Christensen, K. A.; Livbjerg, Hans

    2000-01-01

    multicomponent growth models are treated. The local gas phase composition is determined from a gas phase chemical equilibrium calculation combined with finite reaction rate kinetics for slower reactions. The model is useful in the analysis of boiler operation with respect to the formation of particles, HCl, SO2......The paper presents a numerical model for the simulation of gas to particle conversion and the chemical changes during cooling of a flue gas from the combustion of fuels rich in volatile alkali species. For the homogeneous nucleation of alkali species the model uses the classical theory modified...

  9. Beam front accelerators

    International Nuclear Information System (INIS)

    Reiser, M.

    1982-01-01

    An intense relativistic electron beam cannot propagate in a metal drift tube when the current exceeds the space charge limit. Very high charge density and electric field gradients (10 2 to 10 3 MV/m) develop at the beam front and the electrons are reflected. When a neutral gas or a plasma is present, collective acceleration of positive ions occur, and the resulting charge neutralization enables the beam to propagate. Experimental results, theoretical understanding, and schemes to achieve high ion energies by external control of the beam front velocity will be reviewed

  10. Moving carbonation fronts in concrete: a moving-sharp-interface approach

    NARCIS (Netherlands)

    Muntean, A.; Böhm, M.; Kropp, J.

    2011-01-01

    We present a new modeling strategy for predicting the penetration of carbonation reaction fronts in concrete. The approach relies on the assumption that carbonation reaction concentrates macroscopically on an a priori unknown narrow strip (called reaction front) moving into concrete gradually

  11. Synthesis and reactions of imines of α,β-ethylenic silicon-containing aldehydes with complex metal hydrides

    International Nuclear Information System (INIS)

    Surnin, V.A.; Stadnichuk, M.D.

    1986-01-01

    Imines of 3-trimethylsilyl-2-propenal or its hydrocarbon analog are reduced chemoselectively at the C=N double bond by sodium borohydride. The direction of lithium aluminum hydride reduction of these imines is not influenced by the nature of the element attached to the C=C bond silicon versus carbon, but rather is determined by the nature of the radical group attached to the nitrogen atom; N-arylimines undergo addition with lithium aluminum hydride at the C=N bond exclusively, whereas for N-alkylimines the addition reactions occur either partially or in full in the 1,4-position, depending on the reaction conditions, to give imines of saturated aldehydes after demetallation

  12. The fate of aniline after a photo-fenton reaction in an aqueous system containing iron(III), humic acid, and hydrogen peroxide

    Energy Technology Data Exchange (ETDEWEB)

    Fukushima, Masami; Tatsumi, Kenji; Morimoto, Kengo

    2000-05-15

    The degradation of aniline (ArNH{sub 2}) was facilitated by light irradiation ({lambda} > 370 nm) of an aqueous solution, which contained Fe(III), humic acid(HA), and H{sub 2}O{sub 2}. The consumption of H{sub 2}O{sub 2} and the reduction of Fe(III) to Fe(II) was consistent with the degradation of ArNH{sub 2} via the photo-Fenton reaction, accompanied by the generation of hydroxyl radicals (HO{sm_bullet}). HPLC analysis of the reaction mixture indicated the presence of p-aminophenol, p-hydroquinone, and maleic and fumaric acids and the simultaneous release of NH{sub 4}{sup +} ion. However, the sum of the product concentrations, as determined by HPLC after the reaction, was much smaller than the ArNH{sub 2} concentration added initially. This can be attributed to the majority of the ArNH{sub 2} being incorporated into the polymeric structure in the HA after the reaction. The {sup 15}N NMR and pyrolysis-GC/MS studies indicated that, after the reaction, ArNH{sub 2} formed covalent bonds with quinone and the vinyl carbons in the HA, to form anilino-compounds, such as anilinoquinone and enaminone.

  13. Light-Front Quantization of Gauge Theories

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.

    2003-03-25

    Light-front wavefunctions provide a frame-independent representation of hadrons in terms of their physical quark and gluon degrees of freedom. The light-front Hamiltonian formalism provides new nonperturbative methods for obtaining the QCD spectrum and eigensolutions, including resolvant methods, variational techniques, and discretized light-front quantization. A new method for quantizing gauge theories in light-cone gauge using Dirac brackets to implement constraints is presented. In the case of the electroweak theory, this method of light-front quantization leads to a unitary and renormalizable theory of massive gauge particles, automatically incorporating the Lorentz and 't Hooft conditions as well as the Goldstone boson equivalence theorem. Spontaneous symmetry breaking is represented by the appearance of zero modes of the Higgs field leaving the light-front vacuum equal to the perturbative vacuum. I also discuss an ''event amplitude generator'' for automatically computing renormalized amplitudes in perturbation theory. The importance of final-state interactions for the interpretation of diffraction, shadowing, and single-spin asymmetries in inclusive reactions such as deep inelastic lepton-hadron scattering is emphasized.

  14. Light-Front Quantization of Gauge Theories

    Energy Technology Data Exchange (ETDEWEB)

    Brodskey, Stanley

    2002-12-01

    Light-front wavefunctions provide a frame-independent representation of hadrons in terms of their physical quark and gluon degrees of freedom. The light-front Hamiltonian formalism provides new nonperturbative methods for obtaining the QCD spectrum and eigensolutions, including resolvant methods, variational techniques, and discretized light-front quantization. A new method for quantizing gauge theories in light-cone gauge using Dirac brackets to implement constraints is presented. In the case of the electroweak theory, this method of light-front quantization leads to a unitary and renormalizable theory of massive gauge particles, automatically incorporating the Lorentz and 't Hooft conditions as well as the Goldstone boson equivalence theorem. Spontaneous symmetry breaking is represented by the appearance of zero modes of the Higgs field leaving the light-front vacuum equal to the perturbative vacuum. I also discuss an ''event amplitude generator'' for automatically computing renormalized amplitudes in perturbation theory. The importance of final-state interactions for the interpretation of diffraction, shadowing, and single-spin asymmetries in inclusive reactions such as deep inelastic lepton-hadron scattering is emphasized.

  15. Sharp fronts within geochemical transport problems

    International Nuclear Information System (INIS)

    Grindrod, P.

    1995-01-01

    The authors consider some reactive geochemical transport problems in groundwater systems. When incoming fluid is in disequilibrium with the mineralogy sharp transition fronts may develop. They show that this is a generic property for a class of systems where the timescales associated with reaction and diffusion phenomena are much shorter than those associated with advective transport. Such multiple timescale problems are relevant to a variety of processes in natural systems: mathematically methods of singular perturbation theory reduce the dimension of the problems to be solved locally. Furthermore, they consider how spatial heterogeneous mineralogy can impact upon the propagation of sharp geochemical fronts. The authors developed an asymptotic approach in which they solve equations for the evolving geometry of the front and indicate how the non-smooth perturbations due to natural heterogeneity of the mineralogy on underlying ground water flow field are balanced against the smoothing effect of diffusion/dispersive processes. Fronts are curvature damped, and the results here indicate the generic nature of separate front propagation within both model (idealized) and natural (heterogeneous) geochemical systems

  16. QCD Phenomenology and Light-Front Wavefunctions

    International Nuclear Information System (INIS)

    Brodsky, Stanley J.

    2001-01-01

    A natural calculus for describing the bound-state structure of relativistic composite systems in quantum field theory is the light-front Fock expansion which encodes the properties of a hadrons in terms of a set of frame-independent n-particle wavefunctions. Light-front quantization in the doubly-transverse light-cone gauge has a number of remarkable advantages, including explicit unitarity, a physical Fock expansion, the absence of ghost degrees of freedom, and the decoupling properties needed to prove factorization theorems in high momentum transfer inclusive and exclusive reactions. A number of applications are discussed in these lectures, including semileptonic B decays, two-photon exclusive reactions, diffractive dissociation into jets, and deeply virtual Compton scattering. The relation of the intrinsic sea to the light-front wavefunctions is discussed. Light-front quantization can also be used in the Hamiltonian form to construct an event generator for high energy physics reactions at the amplitude level. The light-cone partition function, summed over exponentially weighted light-cone energies, has simple boost properties which may be useful for studies in heavy ion collisions. I also review recent work which shows that the structure functions measured in deep inelastic lepton scattering are affected by final-state rescattering, thus modifying their connection to light-front probability distributions. In particular, the shadowing of nuclear structure functions is due to destructive interference effects from leading-twist diffraction of the virtual photon, physics not included in the nuclear light-cone wavefunctions

  17. Radiative thermal conduction fronts

    International Nuclear Information System (INIS)

    Borkowski, K.J.; Balbus, S.A.; Fristrom, C.C.

    1990-01-01

    The discovery of the O VI interstellar absorption lines in our Galaxy by the Copernicus observatory was a turning point in our understanding of the Interstellar Medium (ISM). It implied the presence of widespread hot (approx. 10 to the 6th power K) gas in disk galaxies. The detection of highly ionized species in quasi-stellar objects' absorption spectra may be the first indirect observation of this hot phase in external disk galaxies. Previous efforts to understand extensive O VI absorption line data from our Galaxy were not very successful in locating the regions where this absorption originates. The location at interfaces between evaporating ISM clouds and hot gas was favored, but recent studies of steady-state conduction fronts in spherical clouds by Ballet, Arnaud, and Rothenflug (1986) and Bohringer and Hartquist (1987) rejected evaporative fronts as the absorption sites. Researchers report here on time-dependent nonequilibrium calculations of planar conductive fronts whose properties match well with observations, and suggest reasons for the difference between the researchers' results and the above. They included magnetic fields in additional models, not reported here, and the conclusions are not affected by their presence

  18. Total cross-sections assessment of neutron reaction with stainless steel SUS-310 contained in various nuclear data files

    International Nuclear Information System (INIS)

    Suwoto

    2002-01-01

    The integral testing of neutron cross-sections for Stainless Steel SUS-310 contained in various nuclear data files have been performed. The shielding benchmark calculations for Stainless Steel SUS-310 has been analysed through ORNL-Broomstick Experiment calculation which performed by MAERKER, R.E. at ORNL - USA ( 1) . Assessment with JENDL-3.1, JENDL-3.2, ENDF/B-IV, ENDF/B-VI nuclear data files and data from GEEL have also been carried out. The overall calculation results SUS-310 show in a good agreement with the experimental data, although, underestimate results appear below 3 MeV for all nuclear data files. These underestimation tendencies clearly caused by presented of iron nuclide which more than half in Stainless Steel compound. The total neutron cross-sections of iron nuclide contained in various nuclear data files relatively lower on that energy ranges

  19. Probing Metal Carbonation Reactions of CO2 in a Model System Containing Forsterite and H2O Using Si-29, C-13 Magic Angle Sample Spinning NMR Spectroscopy

    Science.gov (United States)

    Hu, J.; Kwak, J.; Hoyt, D. W.; Sears, J. A.; Rosso, K. M.; Felmy, A. R.

    2009-12-01

    Ex situ solid state NMR have been used for the first time to study fundamental mineral carbonation processes and reaction extent relevant to geologic carbon sequestration using a model silicate mineral forsterite (Mg2SiO4)+scCO2 with and without H2O. Run conditions were 80C and 96 bar. Si-29 NMR clearly shows that in the absence of CO2, the role of H2O is to hydrolyze surface Mg-O-Si bonds to produce Mg2+, and mono- and oligomeric hydroxylated silica species. The surface hydrolysis products contain only Q0 (Si(OH)4) and Q1 (Si(OH)3OSi) species. An equilibrium between Q0, Q1 and Mg2+ with a saturated concentration equivalent to less than 3.2% of the Mg2SiO4 conversion is obtained at a reaction time of up to 7 days. Using scCO2 without H2O, no reaction is observed within 7 days. Using both scCO2 and H2O, the surface reaction products for silica are mainly Q3 (SiOH(OSi)3) species accompanied by a lesser amount of Q2 (Si(OH)2(OSi)2) and Q4 (Si(OSi)4). However, no Q0 and Q1 were detected, indicating the carbonic acid formation/deprotonation and magnesite (MgCO3) precipitation reactions are faster than the forsterite hydrolysis process. Thus it can be concluded that the Mg2SiO4 hydrolysis process is the rate limiting step of the overall mineral carbonation process. Si-29 NMR combined with XRD, TEM, SAED and EDX further reveal that the reaction is a surface reaction with the Mg2SiO4 crystallite in the core and with condensed Q2-Q4 species forming amorphous surface layers. C-13 MAS NMR identified a possible reaction intermediates as (MgCO3)4*Mg(OH)2*5H2O. However, at long reaction times only crystallite magnesite MgCO3 products are observed. This research is part of a broader effort at PNNL to develop experimental tools and fundamental insights into chemical transformations affecting subsurface CO2 reactive transport. Si-29 (left) and C-13 (right) MAS NMR spectra of Mg2SiO4 under various reaction conditions. Si-29 NMR reveals that in scCO2 without H2O, no reaction is

  20. Synthesis of some fenchyl-substituted alkenes and enol-ethers containing 3-oxyphenyl substituents by the Barton-Kellogg reaction

    International Nuclear Information System (INIS)

    Ciscato, Luiz Francisco M.L.; Bartoloni, Fernando H.; Baader, Wilhelm Josef; Bastos, Erick L.; Guenther, Wolfgang; Weiss, Dieter; Beckert, Rainer

    2010-01-01

    The synthesis of one fenchyl-substituted alkene and two enol-ethers, containing 3-oxyphenyl substituents by the Barton-Kellogg reaction is described. The tri-substituted aromatic fenchylalkene 1a was prepared in 53% yield from thiofenchone and a diazoanisole; whereas enol-ethers 1b and 1c were obtained (95 and 75% yield, respectively) using an inverse approach based on diazofenchone and aromatic thionoesters. A mixture of Z and E isomers was obtained in all cases; isomer attribution and quantification has been carried out by analysis of NMR spectroscopic data assisted by theoretical calculations (E/Z ratio: 1a = 0.72, 1b = 2.2, 1c = 1.8). Reaction proceeds with low stereoselectivity leading to the preferential formation of diastereoisomeric olefins and enol-ethers where the aromatic substituent resides at the side of the two fenchyl methyl groups. (author)

  1. Synthesis of some fenchyl-substituted alkenes and enol-ethers containing 3-oxyphenyl substituents by the Barton-Kellogg reaction

    Energy Technology Data Exchange (ETDEWEB)

    Ciscato, Luiz Francisco M.L.; Bartoloni, Fernando H.; Baader, Wilhelm Josef, E-mail: wjbaader@iq.usp.b [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Quimica. Dept. de Quimica Fundamental; Bastos, Erick L. [Universidade Federal do ABC (UFABC), Santo Andre, SP (Brazil). Centro de Ciencias Naturais e Humanas; Guenther, Wolfgang; Weiss, Dieter; Beckert, Rainer [Friedrich-Schiller Universitaet Jena (Germany). Institut fuer Organische Chemie und Makromolekulare Chemie

    2010-07-01

    The synthesis of one fenchyl-substituted alkene and two enol-ethers, containing 3-oxyphenyl substituents by the Barton-Kellogg reaction is described. The tri-substituted aromatic fenchylalkene 1a was prepared in 53% yield from thiofenchone and a diazoanisole; whereas enol-ethers 1b and 1c were obtained (95 and 75% yield, respectively) using an inverse approach based on diazofenchone and aromatic thionoesters. A mixture of Z and E isomers was obtained in all cases; isomer attribution and quantification has been carried out by analysis of NMR spectroscopic data assisted by theoretical calculations (E/Z ratio: 1a = 0.72, 1b = 2.2, 1c = 1.8). Reaction proceeds with low stereoselectivity leading to the preferential formation of diastereoisomeric olefins and enol-ethers where the aromatic substituent resides at the side of the two fenchyl methyl groups. (author)

  2. Polymer-modified copper catalysts on carbon-containing support for reactions of H2O2 decomposition and cyclohexane oxidation

    Directory of Open Access Journals (Sweden)

    S. Auezkhanova

    2012-12-01

    Full Text Available Polymer-copper catalysts supported on a carbon-containing sorbent(CS, obtained by rice husk pyrolysis have been studied in the reactions of hydrogen peroxide decomposition and cyclohexane oxidation by hydrogen peroxide at 40°C and atmospheric pressure. The effect of the polymer nature on the activity of the developed catalysts have been shown. Polyhexamethyleneguanidine (PHMG was an optimal modifier for the developed catalysts. The calculated number of catalytic cycles (TON for 7% Cu-PGMG/CS was 450.

  3. Chemical reactions during sintering of Fe-Cr-Mn-Si-Ni-Mo-C-steels with special reference to processing in semi-closed containers

    Directory of Open Access Journals (Sweden)

    Cias A.

    2015-01-01

    Full Text Available Sintering of Cr, Mn and Si bearing steels has recently attracted both experimental and theoretical attention and processing in semiclosed containers has been reproposed. This paper brings together relevant thermodynamic data and considers the kinetics of some relevant chemical reactions. These involve iron and carbon, water vapour, carbon monoxide and dioxide, hydrogen and nitrogen of the sintering atmospheres and the alloying elements Cr, Mn, Mo and Si. The paper concludes by presenting mechanical properties data for three steels sintered in local microatmosphere with nitrogen, hydrogen, nitrogen-5% hydrogen and air as the furnace gas.

  4. Ceramic containers for spent nuclear fuel. II. Reactions between TiO2 and the steel canning during hot isostatic processing

    International Nuclear Information System (INIS)

    Bergman, B.; Forberg, S.

    1984-01-01

    Rutile was selected for some practical studies of processing and properties of ceramic containers. Hot isostatic pressing at 1280 0 C has resulted in reaction zones between the TiO 2 powder and the steel canning. The phases ilmenite, pseudobrookite, rutile, and iron have been identified by x-ray diffraction and by microprobe analysis. The microstructures have been interpreted by classical metallographic methods, and some microstructures obtained by hot pressing and rapid cooling have also been examined for purposes of comparison. Some implications of the microstructures have been discussed in terms of microcracking and slow crack growth. 13 refs., 7 figs

  5. Stationary flow near fronts

    Directory of Open Access Journals (Sweden)

    Reinhold Steinacker

    2016-12-01

    Full Text Available In 1906, the Austrian scientist Max Margules published a paper on temperature stratification in resting and non-accelerated moving air. The paper derives conditions for stationary slopes of air mass boundaries and was an important forerunner of frontal theories. Its formulation of relations between changes in density and geostrophic wind across the front is basically a discrete version of the thermal wind balance equation. The paper was highly influential and is still being cited to the present day. This paper accompanies an English translation of Margules’ seminal paper. We conclude here our “Classic Papers” series of the Meteorologische Zeitschrift.

  6. A colorimetric assay of 1-aminocyclopropane-1-carboxylate (ACC) based on ninhydrin reaction for rapid screening of bacteria containing ACC deaminase.

    Science.gov (United States)

    Li, Z; Chang, S; Lin, L; Li, Y; An, Q

    2011-08-01

    1-Aminocyclopropane-1-carboxylate (ACC) deaminase activity is an efficient marker for bacteria to promote plant growth by lowering ethylene levels in plants. We aim to develop a method for rapidly screening bacteria containing ACC deaminase, based on a colorimetric ninhydrin assay of ACC. A reliable colorimetric ninhydrin assay was developed to quantify ACC using heat-resistant polypropylene chimney-top 96-well PCR plates, having the wells evenly heated in boiling water, preventing accidental contamination from boiling water and limiting evaporation. With this method to measure bacterial consumption of ACC, 44 ACC-utilizing bacterial isolates were rapidly screened out from 311 bacterial isolates that were able to grow on minimal media containing ACC as the sole nitrogen source. The 44 ACC-utilizing bacterial isolates showed ACC deaminase activities and belonged to the genus Burkholderia, Pseudomonas or Herbaspirillum. Determination of bacterial ACC consumption by the PCR-plate ninhydrin-ACC assay is a rapid and efficient method for screening bacteria containing ACC deaminase from a large number of bacterial isolates. The PCR-plate ninhydrin-ACC assay extends the utility of the ninhydrin reaction and enables a rapid screening of bacteria containing ACC deaminase from large numbers of bacterial isolates. © 2011 The Authors. Letters in Applied Microbiology © 2011 The Society for Applied Microbiology.

  7. Preparation, characterization of Mo catalysts supported on Ni- containing calcium deficient hydroxyapatite and reactivity for the thiophene HDS reaction

    Directory of Open Access Journals (Sweden)

    Cherif A.

    2013-09-01

    Full Text Available Ni-containing Calcium Hydroxyapatite (NiCaHAp; 3.31 wt.% Ni was synthesized by coprecipitation and used as catalyst support. Molybdenum was supported on NiCaHAp by impregnation using ammonium heptamolybdate. The prepared catalysts Mo(x/NiCaHAp (x: 2 to 8 wt % in Mo were characterized by elemental analysis, XRD, FT-IR, N2 adsorption-desorption and TEM-EDX. The catalysts were sulfided in-situ at 673 K under flowing H2S/H2 (15 Vol.% H2S and tested in hydrodesulfurization (HDS of thiophene at 673 K. The main XRD peaks of hydroxyapatite CaHAp phase were observed in all samples and a peak due probably to crystalline MoO3 phase was also identified from the results. However, no crystalline phase of NiO was found for the catalysts, which showed its Ni species were highly dispersed. The sulfided catalysts Mo(x/NiCaHAp presented are active in HDS of thiophene, despite the presence of some large MoO3 crystallites and incomplete sulfidation. This activity may be due to interaction of NiO and MoO3 on CaHAp resulting in the formation of Ni-Mo-S phase under flowing H2S/H2. When the molybdenum content increased the HDS activity increasead slightly, which was caused by the agglomeration of MoO3. The Mo(8/NiCaHAp catalyst is about two times less active for thiophene HDS than the commercial NiMoP/Al2O3.

  8. Adverse reactions from essential oil-containing natural flea products exempted from Environmental Protection Agency regulations in dogs and cats.

    Science.gov (United States)

    Genovese, Allison G; McLean, Mary Kay; Khan, Safdar A

    2012-08-01

    To describe adverse effects in dogs and cats exposed to Environmental Protection Agency exempted plant-derived flea preventatives containing mixtures of essential oils. Retrospective study from 2006 to 2008. Records of dog and cat cases were reviewed from the American Society for the Prevention of Cruelty to Animals, Animal Poison Control Center database. Thirty-nine cats and 9 dogs with history of exposure to natural flea preventatives. The following information was retrieved from each incident: number of animals, species involved, frequency, types, onset time, duration of clinical signs, exposure appropriateness, final outcome, and treatment information. Ninety-two percent of animals (n = 44) showed presence of one or more adverse effects. The frequency of adverse effects in dogs (n = 8; 89%) and cats (n = 36; 92%) was similar. Onset time of adverse effects in 39 of 44 animals occurred within 24 hours. The duration of signs in 24 animals ranged from 30 minutes to 149 hours. The products were used as per label in 77% animals (n = 37). Of 28 animals with known outcome, 50% (n = 14) recovered with bathing alone while others received intravenous fluids, muscle relaxants, and anticonvulsive medications. Death (1 cat; n = 1/28; 4%) or euthanasia (1 cat and 1 dog; n = 2/28; 7%) was reported in 3 animals. Dogs and cats can experience significant adverse effects when exposed to plant-derived flea preventatives even when used according to label directions. The number of reports of exposure in cats was higher than dogs, but the frequency of reported adverse effects was similar between the 2 species. Agitation and hypersalivation were common in cats, whereas lethargy and vomiting were common in dogs. © Veterinary Emergency and Critical Care Society 2012.

  9. Self-Propagating Reactive Fronts in Compacts of Multilayered Particles

    International Nuclear Information System (INIS)

    Sraj, I.; Vohra, M.; Alawieh, L.; Weihs, T.P.; Knio, O.M.

    2013-01-01

    Reactive multilayered foils in the form of thin films have gained interest in various applications such as joining, welding, and ignition. Typically, thin film multilayers support self-propagating reaction fronts with speeds ranging from 1 to 20 m/s. In some applications, however, reaction fronts with much smaller velocities are required. This recently motivated Fritz et al. (2011) to fabricate compacts of regular sized/shaped multilayered particles and demonstrate self-sustained reaction fronts having much smaller velocities than thin films with similar layering. In this work, we develop a simplified numerical model to simulate the self-propagation of reactive fronts in an idealized compact, comprising identical Ni/Al multilayered particles in thermal contact. The evolution of the reaction in the compact is simulated using a two-dimensional transient model, based on a reduced description of mixing, heat release, and thermal transport. Computed results reveal that an advancing reaction front can be substantially delayed as it crosses from one particle to a neighboring particle, which results in a reduced mean propagation velocity. A quantitative analysis is thus conducted on the dependence of these phenomena on the contact area between the particles, the thermal contact resistance, and the arrangement of the multilayered particles.

  10. Self-Propagating Reactive Fronts in Compacts of Multilayered Particles

    Directory of Open Access Journals (Sweden)

    Ihab Sraj

    2013-01-01

    Full Text Available Reactive multilayered foils in the form of thin films have gained interest in various applications such as joining, welding, and ignition. Typically, thin film multilayers support self-propagating reaction fronts with speeds ranging from 1 to 20 m/s. In some applications, however, reaction fronts with much smaller velocities are required. This recently motivated Fritz et al. (2011 to fabricate compacts of regular sized/shaped multilayered particles and demonstrate self-sustained reaction fronts having much smaller velocities than thin films with similar layering. In this work, we develop a simplified numerical model to simulate the self-propagation of reactive fronts in an idealized compact, comprising identical Ni/Al multilayered particles in thermal contact. The evolution of the reaction in the compact is simulated using a two-dimensional transient model, based on a reduced description of mixing, heat release, and thermal transport. Computed results reveal that an advancing reaction front can be substantially delayed as it crosses from one particle to a neighboring particle, which results in a reduced mean propagation velocity. A quantitative analysis is thus conducted on the dependence of these phenomena on the contact area between the particles, the thermal contact resistance, and the arrangement of the multilayered particles.

  11. A novel arctigenin-containing latex glove prevents latex allergy by inhibiting type I/IV allergic reactions.

    Science.gov (United States)

    Wang, Yong-Xin; Xue, Dan-Ting; Liu, Meng; Zhou, Zheng-Min; Shang, Jing

    2016-03-01

    The present study aimed at developing a natural compound with anti-allergic effect and stability under latex glove manufacturing conditions and investigating whether its anti-allergic effect is maintained after its addition into the latex. The effects of nine natural compounds on growth of the RBL-2H3 cells and mouse primary spleen lymphocytes were determined using MTT assay. The compounds included glycyrrhizin, osthole, tetrandrine, tea polyphenol, catechin, arctigenin, oleanolic acid, baicalin and oxymatrine. An ELISA assay was used for the in vitro anti-type I/IV allergy screening; in this process β-hexosaminidase, histamine, and IL-4 released from RBL-2H3 cell lines and IFN-γ and IL-2 released from mouse primary spleen lymphocytes were taken as screening indices. The physical stability of eight natural compounds and the dissolubility of arctigenin, selected based on the in vitro pharnacodynamaic screening and the stability evaluation, were detected by HPLC. The in vivo pharmacodynamic confirmation of arctigenin and final latex product was evaluated with a passive cutaneous anaphylaxis (PCA) model and an allergen-specific skin response model. Nine natural compounds showed minor growth inhibition on RBL-2H3 cells and mouse primary spleen lymphocytes. Baicalin and arctigenin had the best anti-type I and IV allergic effects among the natural compounds based on the in vitro pharmacodynamic screening. Arctigenin and catechin had the best physical stability under different manufacturing conditions. Arctigenin was the selected for further evaluation and proven to have anti-type I and IV allergic effects in vivo in a dose-dependent manner. The final product of the arctigenin-containing latex glove had anti-type I and IV allergic effects in vivo which were mainly attributed to arctigenin as proved from the dissolubility results. Arctigenin showed anti-type I and IV allergic effects in vitro and in vivo, with a good stability under latex glove manufacturing conditions

  12. Time-delayed fronts from biased random walks

    International Nuclear Information System (INIS)

    Fort, Joaquim; Pujol, Toni

    2007-01-01

    We generalize a previous model of time-delayed reaction-diffusion fronts (Fort and Mendez 1999 Phys. Rev. Lett. 82 867) to allow for a bias in the microscopic random walk of particles or individuals. We also present a second model which takes the time order of events (diffusion and reproduction) into account. As an example, we apply them to the human invasion front across the USA in the 19th century. The corrections relative to the previous model are substantial. Our results are relevant to physical and biological systems with anisotropic fronts, including particle diffusion in disordered lattices, population invasions, the spread of epidemics, etc

  13. Partial oxidation of jet fuels over Rh/Al_2O_3. Design and reaction kinetics of sulfur-containing surrogates

    International Nuclear Information System (INIS)

    Baer, Julian Nicolaas

    2016-01-01

    The conversion of logistic fuels via catalytic partial oxidation (CPOX) on Rh/Al_2O_3 at short contact times is an efficient method for generating hydrogen-rich synthesis gas. Depending on the inlet conditions, fuel, and catalyst, high syngas yields, low by-product formation, and rates of high fuel conversion can be achieved. CPOX is relevant for mobile hydrogen generation, e.g., on board of airplanes in order to increase the fuel efficiency via fuel cell-based auxiliary power units. Jet fuels contain hundreds of different hydrocarbons and a significant amount of sulfur. The hydrocarbon composition and sulfur content of a jet fuel vary depending on distributor, origin, and refinement of the crude oil. Little is known about the influence of the various compounds on the synthesis-gas yield and the impact of sulfur on the product yield. In this work, the influence of three main chemical compounds of a jet fuel (aromatics, alkanes, and sulfur compounds) on syngas selectivity, the catalyst deactivation process, and reaction sequence is unraveled. As representative components of alkanes and aromatics, n-dodecane and 1,2,4-trimethylbenzene were chosen for ex-situ and in-situ investigations on the CPOX over Rh/Al_2O_3, respectively. Additionally, for a fixed paraffin-to-aromatics ratio, benzothiophene or dibenzothiophene were added as a sulfur component in three different concentrations. The knowledge gained about the catalytic partial oxidation of jet fuels and their surrogates is used to identify requirements for jet fuels in mobile applications based on CPOX and to optimize the overall system efficiency. The results show an influence of the surrogate composition on syngas selectivity. The tendency for syngas formation increases with higher paraffin contents. A growing tendency for by-product formation can be observed with increasing aromatics contents in the fuel. The impact of sulfur on the reaction system shows an immediate change in the product distribution. An

  14. Partial oxidation of jet fuels over Rh/Al{sub 2}O{sub 3}. Design and reaction kinetics of sulfur-containing surrogates

    Energy Technology Data Exchange (ETDEWEB)

    Baer, Julian Nicolaas

    2016-07-01

    The conversion of logistic fuels via catalytic partial oxidation (CPOX) on Rh/Al{sub 2}O{sub 3} at short contact times is an efficient method for generating hydrogen-rich synthesis gas. Depending on the inlet conditions, fuel, and catalyst, high syngas yields, low by-product formation, and rates of high fuel conversion can be achieved. CPOX is relevant for mobile hydrogen generation, e.g., on board of airplanes in order to increase the fuel efficiency via fuel cell-based auxiliary power units. Jet fuels contain hundreds of different hydrocarbons and a significant amount of sulfur. The hydrocarbon composition and sulfur content of a jet fuel vary depending on distributor, origin, and refinement of the crude oil. Little is known about the influence of the various compounds on the synthesis-gas yield and the impact of sulfur on the product yield. In this work, the influence of three main chemical compounds of a jet fuel (aromatics, alkanes, and sulfur compounds) on syngas selectivity, the catalyst deactivation process, and reaction sequence is unraveled. As representative components of alkanes and aromatics, n-dodecane and 1,2,4-trimethylbenzene were chosen for ex-situ and in-situ investigations on the CPOX over Rh/Al{sub 2}O{sub 3}, respectively. Additionally, for a fixed paraffin-to-aromatics ratio, benzothiophene or dibenzothiophene were added as a sulfur component in three different concentrations. The knowledge gained about the catalytic partial oxidation of jet fuels and their surrogates is used to identify requirements for jet fuels in mobile applications based on CPOX and to optimize the overall system efficiency. The results show an influence of the surrogate composition on syngas selectivity. The tendency for syngas formation increases with higher paraffin contents. A growing tendency for by-product formation can be observed with increasing aromatics contents in the fuel. The impact of sulfur on the reaction system shows an immediate change in the product

  15. Front propagation in flipping processes

    International Nuclear Information System (INIS)

    Antal, T; Ben-Avraham, D; Ben-Naim, E; Krapivsky, P L

    2008-01-01

    We study a directed flipping process that underlies the performance of the random edge simplex algorithm. In this stochastic process, which takes place on a one-dimensional lattice whose sites may be either occupied or vacant, occupied sites become vacant at a constant rate and simultaneously cause all sites to the right to change their state. This random process exhibits rich phenomenology. First, there is a front, defined by the position of the leftmost occupied site, that propagates at a nontrivial velocity. Second, the front involves a depletion zone with an excess of vacant sites. The total excess Δ k increases logarithmically, Δ k ≅ ln k, with the distance k from the front. Third, the front exhibits ageing-young fronts are vigorous but old fronts are sluggish. We investigate these phenomena using a quasi-static approximation, direct solutions of small systems and numerical simulations

  16. Oxidative treatment of bromide-containing waters: formation of bromine and its reactions with inorganic and organic compounds--a critical review.

    Science.gov (United States)

    Heeb, Michèle B; Criquet, Justine; Zimmermann-Steffens, Saskia G; von Gunten, Urs

    2014-01-01

    Bromide (Br(-)) is present in all water sources at concentrations ranging from ≈ 10 to >1000 μg L(-1) in fresh waters and about 67 mg L(-1) in seawater. During oxidative water treatment bromide is oxidized to hypobromous acid/hypobromite (HOBr/OBr(-)) and other bromine species. A systematic and critical literature review has been conducted on the reactivity of HOBr/OBr(-) and other bromine species with inorganic and organic compounds, including micropollutants. The speciation of bromine in the absence and presence of chloride and chlorine has been calculated and it could be shown that HOBr/OBr(-) are the dominant species in fresh waters. In ocean waters, other bromine species such as Br2, BrCl, and Br2O gain importance and may have to be considered under certain conditions. HOBr reacts fast with many inorganic compounds such as ammonia, iodide, sulfite, nitrite, cyanide and thiocyanide with apparent second-order rate constants in the order of 10(4)-10(9)M(-1)s(-1) at pH 7. No rate constants for the reactions with Fe(II) and As(III) are available. Mn(II) oxidation by bromine is controlled by a Mn(III,IV) oxide-catalyzed process involving Br2O and BrCl. Bromine shows a very high reactivity toward phenolic groups (apparent second-order rate constants kapp ≈ 10(3)-10(5)M(-1)s(-1) at pH 7), amines and sulfamides (kapp ≈ 10(5)-10(6)M(-1)s(-1) at pH 7) and S-containing compounds (kapp ≈ 10(5)-10(7)M(-1)s(-1) at pH 7). For phenolic moieties, it is possible to derive second-order rate constants with a Hammett-σ-based QSAR approach with [Formula in text]. A negative slope is typical for electrophilic substitution reactions. In general, kapp of bromine reactions at pH 7 are up to three orders of magnitude greater than for chlorine. In the case of amines, these rate constants are even higher than for ozone. Model calculations show that depending on the bromide concentration and the pH, the high reactivity of bromine may outweigh the reactions of chlorine during

  17. Photoionization effects in ionization fronts

    International Nuclear Information System (INIS)

    Arrayas, Manuel; Fontelos, Marco A; Trueba, Jose L

    2006-01-01

    In this paper we study the effects of photoionization processes on the propagation of both negative and positive ionization fronts in streamer discharge. We show that negative fronts accelerate in the presence of photoionization events. The appearance and propagation of positive ionization fronts travelling with constant velocity is explained as the result of the combined effects of photoionization and electron diffusion. The photoionization range plays an important role in the selection of the velocity of the ionization front as we show in this work

  18. Photoionization effects in ionization fronts

    Energy Technology Data Exchange (ETDEWEB)

    Arrayas, Manuel [Departamento de Electromagnetismo, Universidad Rey Juan Carlos, Tulipan s/n, 28933 Mostoles, Madrid (Spain); Fontelos, Marco A [Departamento de Matematicas, Instituto de Matematicas y Fisica Fundamental, Consejo Superior de Investigaciones CientIficas, C/Serrano 123, 28006 Madrid (Spain); Trueba, Jose L [Departamento de Electromagnetismo, Universidad Rey Juan Carlos, Tulipan s/n, 28933 Mostoles, Madrid (Spain)

    2006-12-21

    In this paper we study the effects of photoionization processes on the propagation of both negative and positive ionization fronts in streamer discharge. We show that negative fronts accelerate in the presence of photoionization events. The appearance and propagation of positive ionization fronts travelling with constant velocity is explained as the result of the combined effects of photoionization and electron diffusion. The photoionization range plays an important role in the selection of the velocity of the ionization front as we show in this work.

  19. New results in light-front phenomenology

    International Nuclear Information System (INIS)

    Brodsky, S.J.

    2005-01-01

    The light-front quantization of gauge theories in light-cone gauge provides a frame-independent wavefunction representation of relativistic bound states, simple forms for current matrix elements, explicit unitarity, and a trivial vacuum. In this talk I review the theoretical methods and constraints which can be used to determine these central elements of QCD phenomenology. The freedom to choose the light-like quantization four-vector provides an explicitly covariant formulation of light-front quantization and can be used to determine the analytic structure of light-front wave functions and define a kinematical definition of angular momentum. The AdS/CFT correspondence of large N c supergravity theory in higher-dimensional anti-de Sitter space with supersymmetric QCD in four-dimensional space-time has interesting implications for hadron phenomenology in the conformal limit, including an all-orders demonstration of counting rules for exclusive processes. String/gauge duality also predicts the QCD power-law behavior of light-front Fock-state hadronic wavefunctions with arbitrary orbital angular momentum at high momentum transfer. The form of these near-conformal wavefunctions can be used as an initial ansatz for a variational treatment of the light-front QCD Hamiltonian. The light-front Fock-state wavefunctions encode the bound state properties of hadrons in terms of their quark and gluon degrees of freedom at the amplitude level. The nonperturbative Fock-state wavefunctions contain intrinsic gluons, and sea quarks at any scale Q with asymmetries such as s(x) ≠ s-bar(x), u-bar(x) ≠ d-bar(x). Intrinsic charm and bottom quarks appear at large x in the light-front wavefunctions since this minimizes the invariant mass and off-shellness of the higher Fock state. In the case of nuclei, the Fock state expansion contains 'hidden color' states which cannot be classified in terms of of nucleonic degrees of freedom. I also briefly review recent analyses which show that some

  20. EFFECT OF CONTINUOUS CRYSTALLIZER PERFORMANCE ON STRUVITE CRYSTALS PRODUCED IN REACTION CRYSTALLIZATION FROM SOLUTIONS CONTAINING PHOSPHATE(V AND ZINC(II IONS

    Directory of Open Access Journals (Sweden)

    N. Hutnik

    Full Text Available Abstract Continuous reaction crystallization of struvite from aqueous solutions containing phosphate(V (1.0 mass % and zinc(II ions (from 0.1 to 2.0 mg kg-1 in a continuous DT MSMPR crystallizer was investigated. The influence of pH (9 - 11 and mean residence time (900 - 3600 s on the product characteristics and its chemical composition was tested. Struvite crystals of mean size 22-41 µm were produced. An increase in Zn2+ concentration decreased the mean crystal size and homogeneity. An elevation of the pH also decreased the struvite crystal size. Augmenting the mean residence time influenced product quality advantageously. Coexistence of struvite and Zn(OH2 in the product was confirmed analytically.

  1. Uric acid-derived Fe3C-containing mesoporous Fe/N/C composite with high activity for oxygen reduction reaction in alkaline medium

    Science.gov (United States)

    Ma, Jun; Xiao, Dejian; Chen, Chang Li; Luo, Qiaomei; Yu, Yue; Zhou, Junhao; Guo, Changding; Li, Kai; Ma, Jie; Zheng, Lirong; Zuo, Xia

    2018-02-01

    In this work, a category of Fe3C-containing Fe/N/C mesoporous material has been fabricated by carbonizing the mixture of uric acid, Iron (Ⅲ) chloride anhydrous and carbon support (XC-72) under different pyrolysis temperature. Of all these samples, pyrolysis temperature (800 °C) becomes the most crucial factor in forming Fe3C active sites which synergizes with high content of graphitic N to catalyze oxygen reduction reaction (ORR). X-ray absorption fine structure spectroscopy (XAFS) is used to exhibit that the space structure around Fe atoms in the catalyst. This kind of catalyst possesses comparable ORR properties with commercial 20% Pt/C (onset potential is 0 V vs. Ag/AgCl in 0.1 M KOH), the average transfer electron number is 3.84 reflecting the 4-electron process. Moreover, superior stability and methanol tolerance deserve to be mentioned.

  2. Formation of iodo-trihalomethanes, iodo-acetic acids, and iodo-acetamides during chloramination of iodide-containing waters: Factors influencing formation and reaction pathways

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Shaogang [Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 18 Shuang-qing Road, Beijing, 100085 (China); Guangxi Colleges and Universities Key Laboratory of Food Safety and Pharmaceutical Analytical Chemistry, Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530006, Guangxi (China); Li, Zhenlin [Guangxi Colleges and Universities Key Laboratory of Food Safety and Pharmaceutical Analytical Chemistry, Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530006, Guangxi (China); Dong, Huiyu [Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 18 Shuang-qing Road, Beijing, 100085 (China); Goodman, Bernard A. [College of Physical Science and Engineering, State Key Laboratory for Conservation and Utilization of Subtropical Agro-Bioresources, Guangxi University, Nanning, 520004, Guangxi (China); Qiang, Zhimin, E-mail: qiangz@rcees.ac.cn [Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 18 Shuang-qing Road, Beijing, 100085 (China)

    2017-01-05

    This study investigated systematically the factors influencing the formation of iodinated disinfection by-products (I-DBPs) during chloramination of I{sup −}-containing waters, including reaction time, NH{sub 2}Cl dose, I{sup −} concentration, pH, natural organic matter (NOM) concentration, Br{sup −}/I{sup −} molar ratio, and water matrix. Among the I-DBPs detected, iodoform (CHI{sub 3}), iodoacetic acid (IAA), diiodoacetic acid (DIAA), triiodoacetic acid (TIAA), and diiodoacetamide (DIAcAm) were the major species produced from reactions between reactive iodine species (HOI/I{sub 2}) and NOM. A kinetic model involving the reactions of NH{sub 2}Cl auto-decomposition, iodine species transformation and NOM consumption was developed, which could well describe NH{sub 2}Cl decay and HOI/I{sub 2} evolution. Higher concentrations of CHI{sub 3}, IAA, DIAA, TIAA, and DIAcAm were observed in chloramination than in chlorination, whereas IO{sub 3}{sup −} was only formed significantly in chlorination. Maximum formation of I-DBPs occurred at pH 8.0, but acidic conditions favored the formation of iodinated haloacetic acids and DIAcAm. Increasing Br{sup −}/I{sup −} molar ratio from 1 to 10 did not increase the total amount of I-DBPs, but produced more bromine-substituting species. In addition, chloramination of 18 model compounds indicated that low-SUVA{sub 254} (specific ultraviolet absorbance at 254 nm) NOM generally favored the formation of I-DBPs compared to high-SUVA{sub 254} NOM. Finally, potential pathways for I-DBPs formation from chloramination of NOM were proposed.

  3. Experimental and theoretical investigation of the production of cations containing C-N bonds in the reaction of benzene with atomic nitrogen ions

    International Nuclear Information System (INIS)

    Di Stefano, Marco; Rosi, Marzio; Sgamellotti, Antonio; Ascenzi, Daniela; Bassi, Davide; Franceschi, Pietro; Tosi, Paolo

    2003-01-01

    In the last few years, astronomical spectra have revealed the presence of aromatic and polyaromatic molecules in extraterrestrial environments, near carbon stars, in molecular clouds and meteorites. Moreover, the recent observation of benzene in interstellar space has noticeably increased the interest in the entire class of molecules and in their chemical behavior. In this work, we have investigated the reaction between the benzene molecule and the atomic nitrogen cation and, in particular, the mechanisms by which the reactants are converted into cationic products containing at least one C-N bond, according to the general scheme C 6 H 6 +N + →H m C n N + +C x H y . We have measured the energy dependence of the cross section in a guided ion beam tandem mass spectrometer. Relevant stationary points of the potential energy surface have been studied by using the density functional theory hybrid functional B3LYP with the 6-31G* basis set. Thermochemical calculations, and the comparison with experimental results, allow us to distinguish between exoergic and endoergic processes and to obtain a detailed description of the reaction mechanisms. We show that aromatic hydrocarbons may be converted into organic-nitrogen compounds via the insertion of N + into the benzene ring and the formation of C-N bonds from C-C ring reactants

  4. Kinetics of Reactive Fronts in Porous Media: quantification through a laboratory experiment

    Science.gov (United States)

    De Anna, P.; Jimenez-Martinez, J.; Turuban, R.; Tabuteau, H.; Derrien, M.; Le Borgne, T.; Meheust, Y.

    2013-12-01

    The kinetics of reaction fronts in heterogeneous flows is tightly linked to the mixing dynamics governed by the combined action of stretching, diffusion and dispersion. Focusing on porous media flows, with a new experimental setup we show that the invading solute is organized into stretched lamellae, whose deformation and coalescence control the effective reaction kinetics of the mixing limited bimolecular reaction A + B --> C. While the classic advection-dispersion theory predicts a scaling of the cumulative product mass of C as t^(0.5), we observe two distinct kinetics regimes, one characterized by the stretching and the other by the coalescence of the invading lamellae, in which the mass of C scales faster than t^(0.5). The proposed experimental set up allows for direct quantification of mixing and reactive transport in porous media with a high spatial resolution, at the pore scale. The analogous two dimensional porous medium consists in a Hele-Shaw cell containing a single layer of cylindrical solid grains built by soft lithography. On the one hand, the measurement of the local, intra-pore, conservative concentration field is done using a fluorescent tracer. On the other hand, considering a fast bimolecular advection-dispersion reaction A + B --> C occurring as A displaces B, we quantify the reaction kinetics from the spatially-resolved measurement of the pore scale reaction rate, using a chemiluminescent reaction.

  5. Active learning of Pareto fronts.

    Science.gov (United States)

    Campigotto, Paolo; Passerini, Andrea; Battiti, Roberto

    2014-03-01

    This paper introduces the active learning of Pareto fronts (ALP) algorithm, a novel approach to recover the Pareto front of a multiobjective optimization problem. ALP casts the identification of the Pareto front into a supervised machine learning task. This approach enables an analytical model of the Pareto front to be built. The computational effort in generating the supervised information is reduced by an active learning strategy. In particular, the model is learned from a set of informative training objective vectors. The training objective vectors are approximated Pareto-optimal vectors obtained by solving different scalarized problem instances. The experimental results show that ALP achieves an accurate Pareto front approximation with a lower computational effort than state-of-the-art estimation of distribution algorithms and widely known genetic techniques.

  6. Medicago truncatula DNF2 is a PI-PLC-XD-containing protein required for bacteroid persistence and prevention of nodule early senescence and defense-like reactions.

    Science.gov (United States)

    Bourcy, Marie; Brocard, Lysiane; Pislariu, Catalina I; Cosson, Viviane; Mergaert, Peter; Tadege, Millon; Mysore, Kirankumar S; Udvardi, Michael K; Gourion, Benjamin; Ratet, Pascal

    2013-03-01

    Medicago truncatula and Sinorhizobium meliloti form a symbiotic association resulting in the formation of nitrogen-fixing nodules. Nodule cells contain large numbers of bacteroids which are differentiated, nitrogen-fixing forms of the symbiotic bacteria. In the nodules, symbiotic plant cells home and maintain hundreds of viable bacteria. In order to better understand the molecular mechanism sustaining the phenomenon, we searched for new plant genes required for effective symbiosis. We used a combination of forward and reverse genetics approaches to identify a gene required for nitrogen fixation, and we used cell and molecular biology to characterize the mutant phenotype and to gain an insight into gene function. The symbiotic gene DNF2 encodes a putative phosphatidylinositol phospholipase C-like protein. Nodules formed by the mutant contain a zone of infected cells reduced to a few cell layers. In this zone, bacteria do not differentiate properly into bacteroids. Furthermore, mutant nodules senesce rapidly and exhibit defense-like reactions. This atypical phenotype amongst Fix(-) mutants unravels dnf2 as a new actor of bacteroid persistence inside symbiotic plant cells. © 2012 CNRS. New Phytologist © 2012 New Phytologist Trust.

  7. "Front" hotshet izvinitsja / Aleksandr Ikonnikov

    Index Scriptorium Estoniae

    Ikonnikov, Aleksandr

    2003-01-01

    Põhiliselt vene rahvusest noori ühendava liikumise "Front" esindajad kavatsevad kohtuda USA suursaadikuga Eestis ja vabandada kevadel suursaatkonna ees vägivallatsemisega lõppenud meeleavalduse pärast

  8. Energy conversion at dipolarization fronts

    Science.gov (United States)

    Khotyaintsev, Yu. V.; Divin, A.; Vaivads, A.; André, M.; Markidis, S.

    2017-02-01

    We use multispacecraft observations by Cluster in the Earth's magnetotail and 3-D particle-in-cell simulations to investigate conversion of electromagnetic energy at the front of a fast plasma jet. We find that the major energy conversion is happening in the Earth (laboratory) frame, where the electromagnetic energy is being transferred from the electromagnetic field to particles. This process operates in a region with size of the order several ion inertial lengths across the jet front, and the primary contribution to E·j is coming from the motional electric field and the ion current. In the frame of the front we find fluctuating energy conversion with localized loads and generators at sub-ion scales which are primarily related to the lower hybrid drift instability excited at the front; however, these provide relatively small net energy conversion.

  9. Evaluation of Front Morphological Development of Reactive Solute Transport Using Behavior Diagrams

    Directory of Open Access Journals (Sweden)

    Jui-Sheng Chen

    2009-01-01

    Full Text Available While flowing through porous medium, ground water flow dissolves minerals thereby in creasing medium porosity and ultimately permeability. Reactive fluid flows preferentially into highly permeable zones, which are therefore dissolved most rapidly, producing a further preferential permeability enhancement. Accordingly, slight non-uniformities present in porous medium can be amplified and lead to fingering reaction fronts. The objective of this study is to investigate dissolution-induced porosity changes on reaction front morphology in homogeneous porous medium with two non-uniformities. Four controlling parameters, including up stream pressure gradient, reaction rate constant, non-uniformities spacing and non-uniformity strength ratio are comprehensively considered. By using a modified version of the numerical code, NSPCRT, to conduct a series of numerical simulations, front behavior diagrams are constructed to illustrate the morphologies of reaction fronts under various combinations of these four factors. Simulation results indicate that the two non-uniformities are inhibited into a planar front under low up stream pressure gradient, merge into a single-fingering front under inter mediate up stream pressure gradient, or grow into a double-fingers front under high up stream pressure gradient. More over, the two non-uniformities tend to develop intoadouble-fingering front as the non-uniformity strength ratio in creases from 0.2 to 1.0, and merge into a single-fingering front while the non-uniformity strength ratio in creases from 1.0 to 1.8. When the reaction rate constant is small, the two non-uniformities merge into a single front. Reaction rate constant significantly affects front advancing velocity. The front advancing velocity decreases with the reaction rate constant. Based on these results, front behavior diagrams which de fine the morphologies of the reaction fronts for these four parameters are constructed. Moreover, non

  10. General Solvent-dependent Strategy toward Enhanced Oxygen Reduction Reaction in Graphene/Metal Oxide Nanohybrids: Effects of Nitrogen-containing Solvent

    Science.gov (United States)

    Kao, Wei-Yao; Chen, Wei-Quan; Chiu, Yu-Hsiang; Ho, Yu-Hsuan; Chen, Chun-Hu

    2016-11-01

    A general solvent-dependent protocol directly influencing the oxygen reduction reaction (ORR) in metal oxide/graphene nanohybrids has been demonstrated. We conducted the two-step synthesis of cobalt oxide/N-doped graphene nanohybrids (CNG) with solvents of water, ethanol, and dimethylformamide (DMF), representing tree typical categories of aqueous, polar organic, and organic N-containing solvents commonly adopted for graphene nanocomposites preparation. The superior ORR performance of the DMF-hybrids can be attributed to the high nitrogen-doping, aggregation-free hybridization, and unique graphene porous structures. As DMF is the more effective N-source, the spectroscopic results support a catalytic nitrogenation potentially mediated by cobalt-DMF coordination complexes. The wide-distribution of porosity (covering micro-, meso-, to macro-pore) and micron-void assembly of graphene may further enhance the diffusion kinetics for ORR. As the results, CNG by DMF-synthesis exhibits the high ORR activities close to Pt/C (i.e. only 8 mV difference of half-wave potential with electron transfer number of 3.96) with the better durability in the alkaline condition. Additional graphene hybrids comprised of iron and manganese oxides also show the superior ORR activities by DMF-synthesis, confirming the general solvent-dependent protocol to achieve enhanced ORR activities.

  11. Effects of fluorine-containing usnic acid and fungus Beauveria bassiana on the survival and immune-physiological reactions of Colorado potato beetle larvae.

    Science.gov (United States)

    Kryukov, Vadim Yu; Tomilova, Oksana G; Luzina, Olga A; Yaroslavtseva, Olga N; Akhanaev, Yuriy B; Tyurin, Maksim V; Duisembekov, Bahytzhan A; Salakhutdinov, Nariman F; Glupov, Viktor V

    2018-03-01

    The search for compounds that interact synergistically with entomopathogenic fungi is aimed at enhancing the efficacy and stability of biological products against pest insects, for example, against the Colorado potato beetle (CPB). We hypothesized that fluorine-containing derivatives of usnic acid (FUA) might be candidates for the development of multicomponent bio-insecticides. The aim of this study was to analyze the co-influence of FUA and Beauveria bassiana on the survival and immune-physiological reactions of CPB larvae. Synergy between FUA and B. bassiana was observed after treatment of second, third and fourth larvae instars under laboratory conditions. Furthermore, synergy was observed in field trials in continental climate conditions in southeastern Kazakhstan. In a field experiment, the median lethal time was shortened three-fold, and cumulative mortality for 15 days increased by 36% in the combined treatment compared with a fungal infection alone. FUA treatment delayed larval development, decreased the total hemocyte count, and increased both the phenoloxidase activity in integuments and the detoxification enzyme rate in hemolymph. A combined treatment with fungus and FUA led to increases in the aforementioned changes. Toxicosis caused by FUA provides a stable synergistic effect between FUA and B. bassiana. The combination can be promising for the development of highly efficient products against CPB. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  12. Electrochemical reductive dehalogenation of iodine-containing contrast agent pharmaceuticals: Examination of reactions of diatrizoate and iopamidol using the method of rotating ring-disc electrode (RRDE).

    Science.gov (United States)

    Yan, Mingquan; Chen, Zhanghao; Li, Na; Zhou, Yuxuan; Zhang, Chenyang; Korshin, Gregory

    2018-06-01

    This study examined the electrochemical (EC) reduction of iodinated contrast media (ICM) exemplified by iopamidol and diatrizoate. The method of rotating ring-disc electrode (RRDE) was used to elucidate rates and mechanisms of the EC reactions of the selected ICMs. Experiments were carried at varying hydrodynamic conditions, concentrations of iopamidol, diatrizoate, natural organic matter (NOM) and model compounds (resorcinol, catechol, guaiacol) which were used to examine interactions between products of the EC reduction of ICMs and halogenation-active species. The data showed that iopamidol and diatrizoate were EC-reduced at potentials < -0.45 V vs. s.c.e. In the range of potentials -0.65 to -0.85 V their reduction was mass transfer-controlled. The presence of NOM and model compounds did not affect the EC reduction of iopamidol and diatrizoate but active iodine species formed as a result of the EC-induced transformations of these ICMs reacted readily with NOM and model compounds. These data provide more insight into the nature of generation of iodine-containing by-products in the case of reductive degradation of ICMs. Copyright © 2018 Elsevier Ltd. All rights reserved.

  13. Study of ignition possibility, development and properties of self-sustaining nuclear chain reaction in the fuel-containing masses of the object “Ukryttya”

    Directory of Open Access Journals (Sweden)

    V. A. Babenko

    2017-12-01

    Full Text Available Main characteristic properties of ignition and development of self-sustaining nuclear chain reaction (SCR in the fuel-containing masses (FCM of the object “Ukryttya”, and also the main properties of SCR for a number of its typical essentially possible modes were studied. System of differential equations for the main physical quantities describing FCM was formulated. Numerical analysis and calculations according to this system show that the main possible modes of SCR are exponential growth of the neutron flux, mode of the solitary neutron flux burst of differing strength, and also mode of the neutron flux oscillations. Mode of the flux oscillations is of great interest and exhibits various properties. According to calculations, the neutron flux burst of extremely high strength appears to be possible under some likely and reasonable physical conditions in presence of the sufficient accumulation of fissile materials. But the most realistic and close to the experiment mode of SCR appears to be the mode of slow growth of the neutron flux progressively, as the system is flooded by water, and further subsequent transition into the mode of the neutron flux oscillations in the neighbourhood of the critical state.

  14. Reaction products from N-methyl-N-nitrosourea and deoxyribonucleic acid containing thymidine residues. Synthesis and identification of a new methylation product, O4-methyl-thymidine

    Science.gov (United States)

    Lawley, P. D.; Orr, D. J.; Shah, S. A.; Farmer, P. B.; Jarman, M.

    1973-01-01

    1. DNA was treated with N-methyl-N-nitrosourea at pH7–8, 37°C, degraded to yield 3- and 7-methylpurines and deoxyribonucleosides and the reaction products were separated by chromatography on ion-exchange resins. The following methods for identification and determination of products were used: with unlabelled N-methyl-N-nitrosourea, u.v. absorption; use of methyl-14C-labelled N-methyl-N-nitrosourea and use of [14C]thymine-labelled DNA. 2. The synthesis of O4-methylthymidine and its identification by u.v. and mass spectroscopy are reported. 3. 3-Methylthymidine and O4-methylthymidine were found as methylation products from N-methyl-N-nitrosourea with thymidine and with DNA, in relatively small yields. Unidentified products containing thymine were found in enzymic digests of N-methyl-N-nitrosourea-treated DNA, which may be phosphotriesters. 4. The possible role of formation of methylthymines in mutagenesis by N-methyl-N-nitrosourea is discussed. PMID:4798180

  15. Attitude and vibration control of a satellite containing flexible solar arrays by using reaction wheels, and piezoelectric transducers as sensors and actuators

    Science.gov (United States)

    da Fonseca, Ijar M.; Rade, Domingos A.; Goes, Luiz C. S.; de Paula Sales, Thiago

    2017-10-01

    The primary purpose of this paper is to provide insight into control-structure interaction for satellites comprising flexible appendages and internal moving components. The physical model considered herein aiming to attend such purpose is a rigid-flexible satellite consisting of a rigid platform containing two rotating flexible solar panels. The solar panels rotation is assumed to be in a sun-synchronous configuration mode. The panels contain surface-bonded piezoelectric patches that can be used either as sensors for the elastic displacements or as actuators to counteract the vibration motion. It is assumed that in the normal mode operation the satellite platform points towards the Earth while the solar arrays rotate so as to follow the Sun. The vehicle moves in a low Earth polar orbit. The technique used to obtain the mathematical model combines the Lagrangian formulation with the Finite Elements Method used to describe the dynamics of the solar panel. The gravity-gradient torque as well as the torque due to the interaction of the Earth magnetic field and the satellite internal residual magnetic moment is included as environmental perturbations. The actuators are three reaction wheels for attitude control and piezoelectric actuators to control the flexible motion of the solar arrays. Computer simulations are performed using the MATLAB® software package. The following on-orbit satellite operating configurations are object of analysis: i) Satellite pointing towards the Earth (Earth acquisition maneuver) by considering the initial conditions in the elastic displacement equal to zero, aiming the assessment of the flexible modes excitation by the referred maneuver; ii) the satellite pointing towards the Earth with the assumption of an initial condition different from zero for the flexible motion such that the attitude alterations are checked against the elastic motion disturbance; and iii) attitude acquisition accomplished by taking into account initial conditions

  16. Characteristic wave fronts in magnetohydrodynamics

    International Nuclear Information System (INIS)

    Menon, V.V.; Sharma, V.D.

    1981-01-01

    The influence of magnetic field on the process of steepening or flattening of the characteristic wave fronts in a plane and cylindrically symmetric motion of an ideal plasma is investigated. This aspect of the problem has not been considered until now. Remarkable differences between plane, cylindrical diverging, and cylindrical converging waves are discovered. The discontinuity in the velocity gradient at the wave front is shown to satisfy a Bernoulli-type equation. The discussion of the solutions of such equations reported in the literature is shown to be incomplete, and three general theorems are established. 18 refs

  17. The LHCb front-end electronics and data acquisition system

    CERN Document Server

    Jost, B

    2000-01-01

    The LHCb experiment is the most recently approved of the four experiments under construction at CERN's LHC accelerator. It is a special purpose experiment designed to precisely measure the CP violation parameters in the B-B system and to study rare B-decays. Triggering poses special problems since the interesting events containing B-mesons are immersed in a large background of inelastic p-p reactions. We therefore decided to implement a four-level triggering scheme. The LHCb data acquisition (DAQ) system will have to cope with an average trigger rate of 40 kHz, after two levels of hardware triggers, and an average event size of 100 kB. Thus, an event-building network which can sustain an average bandwidth of 4 GB /s is required. A powerful software trigger farm will have to be installed to reduce the rate from 40 kHz to 100 Hz of events written for permanent storage. In this paper we will outline the general architectures of the front-end electronics and of the trigger and DAQ system and the readout protocols...

  18. Traveling interface modulations and anisotropic front propagation in ammonia oxidation over Rh(110)

    Energy Technology Data Exchange (ETDEWEB)

    Rafti, Matías [Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Fac. Cs. Exactas, Universidad Nacional de La Plata, 64 y Diag. 113 (1900), La Plata (Argentina); Institut für Physikalische Chemie und Elektrochemie, Leibniz-Universität Hannover, Callinstr. 3-3a, D-30167 Hannover (Germany); Borkenhagen, Benjamin; Lilienkamp, Gerhard [Institut für Energieforschung und Physikalische Technologien, Technische Universität Clausthal, Leibnizstr. 4, 38678 Clausthal-Zellerfeld (Germany); Lovis, Florian; Smolinsky, Tim; Imbihl, Ronald, E-mail: imbihl@pci.uni-hannvover.de [Institut für Physikalische Chemie und Elektrochemie, Leibniz-Universität Hannover, Callinstr. 3-3a, D-30167 Hannover (Germany)

    2015-11-14

    The bistable NH{sub 3} + O{sub 2} reaction over a Rh(110) surface was explored in the pressure range 10{sup −6}–10{sup −3} mbar and in the temperature range 300–900 K using photoemission electron microscopy and low energy electron microscopy as spatially resolving methods. We observed a history dependent anisotropy in front propagation, traveling interface modulations, transitions with secondary reaction fronts, and stationary island structures.

  19. Align the Front End First.

    Science.gov (United States)

    Perry, Jim

    1995-01-01

    Discussion of management styles and front-end analysis focuses on a review of Douglas McGregor's theories. Topics include Theories X, Y, and Z; leadership skills; motivational needs of employees; intrinsic and extrinsic rewards; and faulty implementation of instructional systems design processes. (LRW)

  20. Immobilization of chitosan film containing semaphorin 3A onto a microarc oxidized titanium implant surface via silane reaction to improve MG63 osteogenic differentiation

    Directory of Open Access Journals (Sweden)

    Fang K

    2014-10-01

    Full Text Available Kaixiu Fang,1,* Wen Song,2,* Lifeng Wang,1 Sen Jia,3 Hongbo Wei,1 Shuai Ren,1 Xiaoru Xu,1 Yingliang Song1 1State Key Laboratory of Military Stomatology, Department of Implant Dentistry, School of Stomatology, Fourth Military Medical University, Xi’an, People’s Republic of China; 2State Key Laboratory of Military Stomatology, Department of Prosthetic Dentistry, School of Stomatology, Fourth Military Medical University, Xi’an, People’s Republic of China; 3State Key Laboratory of Military Stomatology, Department of Oral and Maxillofacial Surgery, School of Stomatology, Fourth Military Medical University, Xi’an, People’s Republic of China *These authors contributed equally to this work Abstract: Improving osseointegration of extensively used titanium (Ti implants still remains a main theme in implantology. Recently, grafting biomolecules onto a Ti surface has attracted more attention due to their direct participation in the osseointegration process around the implant. Semaphorin 3A (Sema3A is a new proven osteoprotection molecule and is considered to be a promising therapeutic agent in bone diseases, but how to immobilize the protein onto a Ti surface to acquire a long-term effect is poorly defined. In our study, we tried to use chitosan to wrap Sema3A (CS/Sema and connect to the microarc oxidized Ti surface via silane glutaraldehyde coupling. The microarc oxidization could formulate porous topography on a Ti surface, and the covalently bonded coating was homogeneously covered on the ridges between the pores without significant influence on the original topography. A burst release of Sema3A was observed in the first few days in phosphate-buffered saline and could be maintained for >2 weeks. Coating in phosphate-buffered saline containing lysozyme was similar, but the release rate was much more rapid. The coating did not significantly affect cellular adhesion, viability, or cytoskeleton arrangement, but the osteogenic-related gene

  1. Reactor container

    International Nuclear Information System (INIS)

    Kojima, Yoshihiro; Hosomi, Kenji; Otonari, Jun-ichiro.

    1997-01-01

    In the present invention, a catalyst for oxidizing hydrogen to be disposed in a reactor container upon rupture of pipelines of a reactor primary coolant system is prevented from deposition of water droplets formed from a reactor container spray to suppress elevation of hydrogen concentration in the reactor container. Namely, a catalytic combustion gas concentration control system comprises a catalyst for oxidizing hydrogen and a support thereof. In addition, there is also disposed a water droplet deposition-preventing means for preventing deposition of water droplets in a reactor pressure vessel on the catalyst. Then, the effect of the catalyst upon catalytic oxidation reaction of hydrogen can be kept high. The local elevation of hydrogen concentration can be prevented even upon occurrence of such a phenomenon that various kinds of mobile forces in the container such as dry well cooling system are lost. (I.S.)

  2. Confinement contains condensates

    DEFF Research Database (Denmark)

    Brodsky, S. J.; Roberts, C. D.; Shrock, R.

    2012-01-01

    been viewed as constant empirical mass scales that fill all space-time, are instead wholly contained within hadrons; i.e., they are a property of hadrons themselves and expressed, e.g., in their Bethe-Salpeter or light-front wave functions. We explain that this paradigm is consistent with empirical...

  3. Light front field theory: an advanced primer

    International Nuclear Information System (INIS)

    Martinovic, L.

    2007-01-01

    We present an elementary introduction to quantum field theory formulated in terms of Dirac's light front variables. In addition to general principles and methods, a few more specific topics and approaches based on the author's work will be discussed. Most of the discussion deals with massive two-dimensional models formulated in a finite spatial volume starting with a detailed comparison between quantization of massive free fields in the usual field theory and the light front (LF) quantization. We discuss basic properties such as relativistic invariance and causality. After the LF treatment of the soluble Federbush model, a LF approach to spontaneous symmetry breaking is explained and a simple gauge theory - the massive Schwinger model in various gauges is studied. A LF version of bosonization and the massive Thirring model are also discussed. A special chapter is devoted to the method of discretized light cone quantization and its application to calculations of the properties of quantum solitons. The problem of LF zero modes is illustrated with the example of the two/dimensional Yukawa model. Hamiltonian perturbation theory in the LF formulation is derived and applied to a few simple processes to demonstrate its advantages. As a byproduct, it is shown that the LF theory cannot be obtained as a 'light-like' limit of the usual field theory quantized on a initial space-like surface. A simple LF formulation of the Higgs mechanism is then given Since our intention was to provide a treatment of the light front quantization accessible to postgradual students, an effort was made to discuss most of the topics pedagogically and number of technical details and derivations are contained in the appendices (Author)

  4. Functional description of APS beamline front ends

    International Nuclear Information System (INIS)

    Kuzay, T.

    1993-02-01

    Traditional synchrotron sources were designed to produce bending magnet radiation and have proven to be an essential scientific tool. Currently, a new generation of synchrotron sources is being built that will be able to accommodate a large number of insertion device (ID) and high quality bending magnet (BM) sources. One example is the 7-GeV Advanced Photon Source (APS) now under construction at Argonne National Laboratory. The research and development effort at the APS is designed to fully develop the potential of this new generation of synchrotron sources. Of the 40 straight sections in the APS storage ring, 34 will be available for IDs. The remaining six sections are reserved for the storage ring hardware and diagnostics. Although the ring incorporates 80 BMs, only 40 of them can be used to extract radiation. The accelerator hardware shadows five of these 40 bending magnets, so the maximum number of BM sources on the lattice is 35. Generally, a photon beamline consists of four functional sections. The first section is the ID or the BM, which provides the radiation source. The second section, which is immediately outside the storage ring but inside a concrete shielding tunnel, is the front end, which is designed to control, define, and/or confine the x-ray beam. In the case of the APS, the front ends are designed to confine the photon beam. The third section, just outside the concrete shielding tunnel and on the experimental floor, is the first optics enclosure, which contains optics to filter and monochromatize the photon beam. The fourth section of a beamline consists of beam transports, additional optics, and experiment stations to do the scientific investigations. This document describes only the front ends of the APS beamlines

  5. QCD Phenomenology and Light-Front Wave Functions

    International Nuclear Information System (INIS)

    Brodsky, St.J.

    2001-01-01

    A natural calculus for describing the bound-state structure of relativistic composite systems in quantum field theory is the light-front Fock expansion which encodes the properties of a hadrons in terms of a set of frame-independent n-particle wave functions. Light-front quantization in the doubly-transverse light-cone gauge has a number of remarkable advantages, including explicit unitarity, a physical Fock expansion, the absence of ghost degrees of freedom, and the decoupling properties needed to prove factorization theorems in high momentum transfer inclusive and exclusive reactions. A number of applications are discussed in these lectures, including semileptonic B decays, two-photon exclusive reactions, diffractive dissociation into jets, and deeply virtual Compton scattering. The relation of the intrinsic sea to the light-front wave functions is discussed. Light-front quantization can also be used in the Hamiltonian form to construct an event generator for high energy physics reactions at the amplitude level. The light-cone partition function, summed over exponentially-weighted light-cone energies, has simple boost properties which may be useful for studies in heavy ion collisions. I also review recent work which shows that the structure functions measured in deep inelastic lepton scattering are affected by final-state rescattering, thus modifying their connection to light-front probability distributions. In particular, the shadowing of nuclear structure functions is due to destructive interference effects from leading-twist diffraction of the virtual photon, physics not included in the nuclear light-cone wave functions. (author)

  6. The ALICE TPC front end electronics

    CERN Document Server

    Musa, L; Bialas, N; Bramm, R; Campagnolo, R; Engster, Claude; Formenti, F; Bonnes, U; Esteve-Bosch, R; Frankenfeld, Ulrich; Glässel, P; Gonzales, C; Gustafsson, Hans Åke; Jiménez, A; Junique, A; Lien, J; Lindenstruth, V; Mota, B; Braun-Munzinger, P; Oeschler, H; Österman, L; Renfordt, R E; Ruschmann, G; Röhrich, D; Schmidt, H R; Stachel, J; Soltveit, A K; Ullaland, K

    2004-01-01

    In this paper we present the front end electronics for the time projection chamber (TPC) of the ALICE experiment. The system, which consists of about 570000 channels, is based on two basic units: (a) an analogue ASIC (PASA) that incorporates the shaping-amplifier circuits for 16 channels; (b) a mixed-signal ASIC (ALTRO) that integrates 16 channels, each consisting of a 10-bit 25-MSPS ADC, the baseline subtraction, tail cancellation filter, zero suppression and multi-event buffer. The complete readout chain is contained in front end cards (FEC), with 128 channels each, connected to the detector by means of capton cables. A number of FECs (up to 25) are controlled by a readout control unit (RCU), which interfaces the FECs to the data acquisition (DAQ), the trigger, and the detector control system (DCS) . A function of the final electronics (1024 channels) has been characterized in a test that incorporates a prototype of the ALICE TPC as well as many other components of the final set-up. The tests show that the ...

  7. HINS Linac front end focusing system R&D

    Energy Technology Data Exchange (ETDEWEB)

    Apollinari, G.; Carcagno, R.H.; Dimarco, J.; Huang, Y.; Kashikhin, V.V.; Orris, D.F.; Page, T.M.; Rabehl, R.; Sylvester, C.; Tartaglia, M.A.; Terechkine, I.; /Fermilab /Argonne

    2008-08-01

    This report summarizes current status of an R&D program to develop a focusing system for the front end of a superconducting RF linac. Superconducting solenoids will be used as focusing lenses in the low energy accelerating sections of the front end. The development of focusing lenses for the first accelerating section is in the production stage, and lens certification activities are in preparation at FNAL. The report contains information about the focusing lens design and performance, including solenoid, dipole corrector, and power leads, and about cryogenic system design and performance. It also describes the lens magnetic axis position measurement technique and discusses scope of an acceptance/certification process.

  8. HINS Linac front end focusing system R and D

    International Nuclear Information System (INIS)

    Apollinari, G.; Carcagno, R.H.; Dimarco, J.; Huang, Y.; Kashikhin, V.V.; Orris, D.F.; Page, T.M.; Rabehl, R.; Sylvester, C.; Tartaglia, M.A.; Terechkine, I.; Fermilab; Argonne

    2008-01-01

    This report summarizes current status of an R and D program to develop a focusing system for the front end of a superconducting RF linac. Superconducting solenoids will be used as focusing lenses in the low energy accelerating sections of the front end. The development of focusing lenses for the first accelerating section is in the production stage, and lens certification activities are in preparation at FNAL. The report contains information about the focusing lens design and performance, including solenoid, dipole corrector, and power leads, and about cryogenic system design and performance. It also describes the lens magnetic axis position measurement technique and discusses scope of an acceptance/certification process

  9. Light front quantum chromodynamics: Towards phenomenology

    Indian Academy of Sciences (India)

    Light front dynamics; quantum chromodynamics; deep inelastic scattering. PACS Nos 11.10. ... What makes light front dynamics appealing from high energy phenomenology point of view? .... given in terms of Poincarй generators by. MВ = W P ...

  10. Front Propagation in Stochastic Neural Fields

    KAUST Repository

    Bressloff, Paul C.; Webber, Matthew A.

    2012-01-01

    We analyze the effects of extrinsic multiplicative noise on front propagation in a scalar neural field with excitatory connections. Using a separation of time scales, we represent the fluctuating front in terms of a diffusive-like displacement

  11. Seabirds and fronts: a brief overview

    OpenAIRE

    Schneider, David C.

    1990-01-01

    Oceanographic fronts are the sites of enhanced physical and biological activity, including locally concentrated feeding by marine birds. Two general hypotheses relating marine birds to fronts have been developed. The first is that enhanced primary production at fronts increases prey supply through increased animal growth, reproduction, or immigration. The second is that prey patches develop at fronts either through behavioural responses of prey to thermal or salinity gradients, or through int...

  12. Novel UTP derivative with diene-containing spacer arm for Diels-Alder reaction: potential tool for radioactive or fluorescent detection upon its incorporation into ribonucleic acid

    Czech Academy of Sciences Publication Activity Database

    Točík, Zdeněk; Krásný, Libor; Kovačková, Soňa; Rejman, Dominik; Rosenberg, Ivan

    2007-01-01

    Roč. 6, č. 5 (2007), s. 357 ISSN 1535-3508. [International Conference of the European Society for Molecular Imaging /2./. 14.06.2007-15.06.2007, Naples] Institutional research plan: CEZ:AV0Z40550506; CEZ:AV0Z50520701 Keywords : UTP derivative * Diels - Alder reaction * diene * spacer arm Subject RIV: CC - Organic Chemistry

  13. Fluctuation charge effects in ionization fronts

    International Nuclear Information System (INIS)

    Arrayas, Manuel; Trueba, Jose L; Baltanas, J P

    2008-01-01

    In this paper, we study the effects of charge fluctuations on the propagation of both negative and positive ionization fronts in streamer discharges. We show that fronts accelerate when random charge creation events are present. This effect might play a similar role to photoionization in order to make the front move faster

  14. Fluctuation charge effects in ionization fronts

    Energy Technology Data Exchange (ETDEWEB)

    Arrayas, Manuel; Trueba, Jose L [Area de Electromagnetismo, Universidad Rey Juan Carlos, Camino del Molino s/n, 28943 Fuenlabrada, Madrid (Spain); Baltanas, J P [Departamento de Fisica Aplicada II, Universidad de Sevilla, Av. Reina Mercedes 2, 41012 Sevilla (Spain)

    2008-05-21

    In this paper, we study the effects of charge fluctuations on the propagation of both negative and positive ionization fronts in streamer discharges. We show that fronts accelerate when random charge creation events are present. This effect might play a similar role to photoionization in order to make the front move faster.

  15. A novel high performance stopped-flow apparatus equipped with a special constructed mixing chamber containing a plunger under inert condition with a very short dead-time to investigate very rapid reactions

    Directory of Open Access Journals (Sweden)

    Sayyed Mostafa Habibi Khorassani

    2015-11-01

    Full Text Available The present work set out to establish a novel stopped-flow instrument equipped with a special constructed mixing chamber containing a plunger to enable a kinetic study of the very rapid reactions under a dry inert atmosphere glove bag, in particular, for the reactions are sensitive to moisture or air. A stopped-flow spectrophotometer is essentially a conventional spectrophotometer with the addition of a system for rapid mixing of solutions. The purpose of this work is to describe the fabrication and evaluation of specially constructed and in-expensive stopped-flow system. The evaluation includes determination of the dead-time, relative mixing efficiency, and the measurement of known rate constants. Herein, a dead-time of about 3.4 ms was determined in the final modified construction of the stopped-flow apparatus in order to investigate the rapid initial during which some form of reaction intermediate is presented to be formed.

  16. Adaptive two-regime method: Application to front propagation

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, Martin, E-mail: martin.robinson@maths.ox.ac.uk; Erban, Radek, E-mail: erban@maths.ox.ac.uk [Mathematical Institute, University of Oxford, Andrew Wiles Building, Radcliffe Observatory Quarter, Woodstock Road, Oxford OX2 6GG (United Kingdom); Flegg, Mark, E-mail: mark.flegg@monash.edu [School of Mathematical Sciences, Faculty of Science, Monash University Wellington Road, Clayton, Victoria 3800 (Australia)

    2014-03-28

    The Adaptive Two-Regime Method (ATRM) is developed for hybrid (multiscale) stochastic simulation of reaction-diffusion problems. It efficiently couples detailed Brownian dynamics simulations with coarser lattice-based models. The ATRM is a generalization of the previously developed Two-Regime Method [Flegg et al., J. R. Soc., Interface 9, 859 (2012)] to multiscale problems which require a dynamic selection of regions where detailed Brownian dynamics simulation is used. Typical applications include a front propagation or spatio-temporal oscillations. In this paper, the ATRM is used for an in-depth study of front propagation in a stochastic reaction-diffusion system which has its mean-field model given in terms of the Fisher equation [R. Fisher, Ann. Eugen. 7, 355 (1937)]. It exhibits a travelling reaction front which is sensitive to stochastic fluctuations at the leading edge of the wavefront. Previous studies into stochastic effects on the Fisher wave propagation speed have focused on lattice-based models, but there has been limited progress using off-lattice (Brownian dynamics) models, which suffer due to their high computational cost, particularly at the high molecular numbers that are necessary to approach the Fisher mean-field model. By modelling only the wavefront itself with the off-lattice model, it is shown that the ATRM leads to the same Fisher wave results as purely off-lattice models, but at a fraction of the computational cost. The error analysis of the ATRM is also presented for a morphogen gradient model.

  17. Synthesis of imine bond containing insoluble polymeric ligand and its transition metal complexes, structural characterization and catalytic activity on esterification reaction.

    Science.gov (United States)

    Gönül, İlyas; Ay, Burak; Karaca, Serkan; Saribiyik, Oguz Yunus; Yildiz, Emel; Serin, Selahattin

    2017-01-01

    In this study, synthesis of insoluble polymeric ligand (L) and its transition metal complexes [Cu(L)Cl 2 ]·2H 2 O (1) , [Co(L)Cl 2 (H 2 O) 2 ] (2) and [Ni(L)Cl 2 (H 2 O) 2 ] (3) , having the azomethine groups, were synthesized by the condensation reactions of the diamines and dialdehydes. The structural properties were characterized by the analytical and spectroscopic methods using by elemental analysis, Fourier Transform Infrared, Thermo Gravimetric Analysis, Powder X-ray Diffraction, magnetic susceptibility and Inductively Coupled Plasma. The solubilities of the synthesized polymeric materials were also investigated and found as insoluble some organic and inorganic solvents. Additionally, their catalytic performance was carried out for the esterification reaction of acetic acid and butyl acetate. The highest conversion rate is 75.75% by using catalyst 1 . The esterification of butanol gave butyl acetate with 100% selectivity.

  18. Stereoselective reactions. XXXII. Enantioselective deprotonation of 4-tert-butylcyclohexanone by fluorine-containing chiral lithium amides derived from 1-phenylethylamine and 1-(1-naphthyl)ethylamine.

    Science.gov (United States)

    Aoki, K; Koga, K

    2000-04-01

    Enantioselective deprotonation of 4-tert-butylcyclohexanone was examined using 1-phenylethylamine- and 1-(1-naphthyl)ethylamine-derived chiral lithium amides having an alkyl or a fluoroalkyl substituent at the amide nitrogen. The lithium amides having a 2,2,2-trifluoroethyl group on the amide nitrogen are easily accessible in both enantiomeric forms, and were found to induce good enantioselectivity in the present reaction.

  19. Hydrodynamic instabilities in an ablation front

    International Nuclear Information System (INIS)

    Piriz, A R; Portugues, R F

    2004-01-01

    The hydrodynamic stability of an ablation front is studied for situations in which the wavelength of the perturbations is larger than the distance to the critical surface where the driving radiation is absorbed. An analytical model is presented, and it shows that under conditions in which the thermal flux is limited within the supercritical region of the ablative corona, the front may behave like a flame or like an ablation front, depending on the perturbation wavelength. For relatively long wavelengths the critical and ablation surfaces practically lump together into a unique surface and the front behaves like a flame, whereas for the shortest wavelengths the ablation front substructure is resolved

  20. Hydrodynamic instabilities in an ablation front

    Energy Technology Data Exchange (ETDEWEB)

    Piriz, A R; Portugues, R F [E.T.S.I. Industriales, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain)

    2004-06-01

    The hydrodynamic stability of an ablation front is studied for situations in which the wavelength of the perturbations is larger than the distance to the critical surface where the driving radiation is absorbed. An analytical model is presented, and it shows that under conditions in which the thermal flux is limited within the supercritical region of the ablative corona, the front may behave like a flame or like an ablation front, depending on the perturbation wavelength. For relatively long wavelengths the critical and ablation surfaces practically lump together into a unique surface and the front behaves like a flame, whereas for the shortest wavelengths the ablation front substructure is resolved.

  1. Polymer reaction engineering, an integrated approach

    NARCIS (Netherlands)

    Meyer, T.; Keurentjes, J.T.F.; Meyer, T.; Keurentjes, J.T.F.

    2005-01-01

    Summary This chapter contains sections titled: Polymer Materials A Short History of Polymer Reaction Engineering The Position of Polymer Reaction Engineering Toward Integrated Polymer Reaction Engineering The Disciplines in Polymer Reaction Engineering The Future: Product-inspired Polymer Reaction

  2. Dipolarization Fronts from Reconnection Onset

    Science.gov (United States)

    Sitnov, M. I.; Swisdak, M. M.; Merkin, V. G.; Buzulukova, N.; Moore, T. E.

    2012-12-01

    Dipolarization fronts observed in the magnetotail are often viewed as signatures of bursty magnetic reconnection. However, until recently spontaneous reconnection was considered to be fully prohibited in the magnetotail geometry because of the linear stability of the ion tearing mode. Recent theoretical studies showed that spontaneous reconnection could be possible in the magnetotail geometries with the accumulation of magnetic flux at the tailward end of the thin current sheet, a distinctive feature of the magnetotail prior to substorm onset. That result was confirmed by open-boundary full-particle simulations of 2D current sheet equilibria, where two magnetotails were separated by an equilibrium X-line and weak external electric field was imposed to nudge the system toward the instability threshold. To investigate the roles of the equilibrium X-line, driving electric field and other parameters in the reconnection onset process we performed a set of 2D PIC runs with different initial settings. The investigated parameter space includes the critical current sheet thickness, flux tube volume per unit magnetic flux and the north-south component of the magnetic field. Such an investigation is critically important for the implementation of kinetic reconnection onset criteria into global MHD codes. The results are compared with Geotail visualization of the magnetotail during substorms, as well as Cluster and THEMIS observations of dipolarization fronts.

  3. Simultaneous regioselective synthesis of trifluoromethyl-containing 1,7-phenanthrolines and quinolines from cyclocondensation reaction of N,N'-bis(oxotrifluoroalkenyl)-1,3-phenylenediamines

    Energy Technology Data Exchange (ETDEWEB)

    Bonacorso, Helio G.; Andrighetto, Rosalia; Krueger, Nicolas; Martins, Marcos A.P.; Zanatta, Nilo [Universidade Federal de Santa Maria (NUQUIMHE/UFSM), RS (Brazil). Dept. de Quimica. Nucleo de Quimica de Heterociclos

    2011-08-15

    This paper reports interesting results of the conventional synthesis of a new series of 2,10-dialkyl(aryl)-4,8-bis(trifluoromethyl)-1,7-phenanthrolines, in 22-40% yields, from cyclization reactions of N,N'-bis(oxotrifluoroalkenyl)-1,3-phenylenediamines [1,3-C{sub 6}H{sub 4}-(NHCR=CHC(O)CF{sub 3}){sub 2}] in a strongly acidic medium and absence of solvent. The synthetic route also allowed the isolation of a new series of 2-alkyl(aryl/heteroaryl)-4-trifluoromethyl-7-aminoquinolines, in 20-73% yields, simultaneously. The enaminone precursors were obtained from the reaction of 4-alkoxy-1,1,1-trifluoroalk-3-en-2-ones [CF{sub 3}C(O)CH=C(R)OR1, where R = H, Me, Ph, 4-MePh, 4-OMePh, 4-ClPh, 4-FPh, 4-BrPh, 4-NO{sub 2}Ph, 2-furyl and R1 = Me, Et] with 1,3-phenylenediamine under mild conditions, in 47-91% yields. (author)

  4. Dinuclear NHC-palladium complexes containing phosphine spacers: synthesis, X-ray structures and their catalytic activities towards the Hiyama coupling reaction.

    Science.gov (United States)

    Yang, Jin; Li, Pinhua; Zhang, Yicheng; Wang, Lei

    2014-05-21

    Six dinuclear N-heterocyclic carbene (NHC) palladium complexes, [PdCl2(IMes)]2(μ-dppe) (1), [PdCl2(IPr)]2(μ-dppe) (2), [PdCl2(IMes)]2(μ-dppb) (3), [PdCl2(IPr)]2(μ-dppb) (4), [PdCl2(IMes)]2(μ-dpph) (5), and [PdCl2(IPr)]2(μ-dpph) (6) [IMes = N,N'-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene; IPr = N,N'-bis-(2,6-di(iso-propyl)phenyl)imidazol-2-ylidene; dppe = 1,2-bis(diphenylphosphino)ethane, dppb = 1,4-bis(diphenylphosphino)butane; and dpph = 1,6-bis(diphenylphosphino)hexane], have been synthesized through bridge-cleavage reactions of chloro-bridged dimeric compounds, [Pd(μ-Cl)(Cl)(NHC)]2, with the corresponding diphosphine ligands. The obtained compounds were fully characterized by (1)H NMR, (13)C NMR and (31)P NMR spectroscopy, FT-IR, elemental analysis and single-crystal X-ray crystallography. Moreover, further explorations of the catalytic potential of the dinuclear carbene palladium complexes as catalysts for the Pd-catalyzed transformations have been performed under microwave irradiation conditions, and the complexes exhibited moderate to good catalytic activity in the Hiyama coupling reaction of trimethoxyphenylsilane with aryl chlorides.

  5. Front Propagation in Stochastic Neural Fields

    KAUST Repository

    Bressloff, Paul C.

    2012-01-01

    We analyze the effects of extrinsic multiplicative noise on front propagation in a scalar neural field with excitatory connections. Using a separation of time scales, we represent the fluctuating front in terms of a diffusive-like displacement (wandering) of the front from its uniformly translating position at long time scales, and fluctuations in the front profile around its instantaneous position at short time scales. One major result of our analysis is a comparison between freely propagating fronts and fronts locked to an externally moving stimulus. We show that the latter are much more robust to noise, since the stochastic wandering of the mean front profile is described by an Ornstein-Uhlenbeck process rather than a Wiener process, so that the variance in front position saturates in the long time limit rather than increasing linearly with time. Finally, we consider a stochastic neural field that supports a pulled front in the deterministic limit, and show that the wandering of such a front is now subdiffusive. © 2012 Society for Industrial and Applied Mathematics.

  6. Bare quantifier fronting as contrastive topicalization

    Directory of Open Access Journals (Sweden)

    Ion Giurgea

    2015-11-01

    Full Text Available I argue that indefinites (in particular bare quantifiers such as ‘something’, ‘somebody’, etc. which are neither existentially presupposed nor in the restriction of a quantifier over situations, can undergo topicalization in a number of Romance languages (Catalan, Italian, Romanian, Spanish, but only if the sentence contains “verum” focus, i.e. focus on a high degree of certainty of the sentence. I analyze these indefinites as contrastive topics, using Büring’s (1999 theory (where the term ‘S-topic’ is used for what I call ‘contrastive topic’. I propose that the topic is evaluated in relation to a scalar set including generalized quantifiers such as {lP $x P(x, lP MANYx P(x, lP MOSTx P(x, lP “xP(x} or {lP $xP(x, lP P(a, lP P(b …}, and that the contrastive topic is the weakest generalized quantifier in this set. The verum focus, which is part of the “comment” that co-occurs with the “Topic”, introduces a set of alternatives including degrees of certainty of the assertion. The speaker asserts that his claim is certainly true or highly probable, contrasting it with stronger claims for which the degree of probability is unknown. This explains the observation that in downward entailing contexts, the fronted quantified DPs are headed by ‘all’ or ‘many’, whereas ‘some’, small numbers or ‘at least n’ appear in upward entailing contexts. Unlike other cases of non-specific topics, which are property topics, these are quantifier topics: the topic part is a generalized quantifier, the comment is a property of generalized quantifiers. This explains the narrow scope of the fronted quantified DP.

  7. Synthesis of Chitin Oligosaccharides Using Dried Stenotrophomonas maltophilia Cells Containing a Transglycosylation Reaction-Catalyzing β-N-Acetylhexosaminidase as a Whole-Cell Catalyst.

    Science.gov (United States)

    Uehara, Asaki; Takahashi, Narumi; Moriyama, Mei; Hirano, Takako; Hakamata, Wataru; Nishio, Toshiyuki

    2018-02-01

    Bacterial strain NYT501, which we previously isolated from soil, was identified as Stenotrophomonas maltophilia, and it was confirmed that this strain produces an intracellular β-N-acetylhexosaminidase exhibiting transglycosylation activity. Several properties of this enzyme were characterized using a partially purified enzyme preparation. Using N,N'-diacetylchitobiose (GlcNAc) 2 and N,N',N″-triacetylchitotriose (GlcNAc) 3 as substrates and dried cells of this bacterium as a whole-cell catalyst, chitin oligosaccharides of higher degrees of polymerization were synthesized. (GlcNAc) 3 was generated from (GlcNAc) 2 as the major transglycosylation product, and a certain amount of purified sample of the trisaccharide was obtained. By contrast, in the case of the reaction using (GlcNAc) 3 as a substrate, the yield of higher-degree polymerization oligosaccharides was comparatively low.

  8. Carbon-14 studies on the role of oxygen-containing compounds in the reaction mechanism of the Fischer-Tropsch synthesis

    International Nuclear Information System (INIS)

    Aksoy, H.A.

    1975-01-01

    In this work the behaviour of organic oxygen compounds has been studied in the reaction mechanism of Fischer-Tropsch synthesis using the tracer method. As an oxygen carrying tracer materials i-propanole (2- 14 C), acetone (2- 14 C) and ethanole (1- 14 C) have been added to the synthesis gas. The synthesis experiments are performed under standard conditions: The synthesis products are separated in suitable fractions and then studied by gas- and radio-gaschromatography. As a result the C-number distributions of the synthesis products are obtained as a function of concentration (weight %, mol %) and radioactivity (activity %). On this basis the relative molar activities have been calculated for certain compounds and fractions. Adding i-propanole- 14 C a great part of the tracer compound is transformed to acetone- 14 C, however adding acetone- 14 C to the synthesis gas a large amount of i-propanole- 14 C is produced. The main hydrocarbon reaction product from i-propanol and acetone is propane. Besides propane also propene is produced with equal molar radioactivity. This indicates that the formation of adsorbed oxygen compounds, as they may also be produced by chemisorption from alcohols or carbonyle compounds, is the first step in the formation of hydrocarbons by hydrogenolytic separation of oxygen. Comparing the results obtained with ethanole- 14 C and i-propanole- 14 C as a tacer material, for ethane an essentially lower molar activity is obtained when adding ethanole- 14 C compared with propane when adding i-propanole- 14 C. This corresponds with a particularly low desorption probability at the C 2 -hydrocarbon level. (orig./HK) [de

  9. The upgraded Tevatron front end

    International Nuclear Information System (INIS)

    Glass, M.; Zagel, J.; Smith, P.; Marsh, W.; Smolucha, J.

    1990-01-01

    We are replacing the computers which support the CAMAC crates in the Fermilab accelerator control system. We want a significant performance increase, but we still want to be able to service scores of different varieties of CAMAC cards in a manner essentially transparent to console applications software. Our new architecture is based on symmetric multiprocessing. Several processors on the same bus, each running identical software, work simultaneously at satisfying different pieces of a console's request for data. We dynamically adjust the load between the processors. We can obtain more processing power by simply plugging in more processor cards and rebooting. We describe in this paper what we believe to be the interesting architectural features of the new front-end computers. We also note how we use some of the advanced features of the Multibus TM II bus and the Intel 80386 processor design to achieve reliability and expandability of both hardware and software. (orig.)

  10. Speed ot travelling waves in reaction-diffusion equations

    International Nuclear Information System (INIS)

    Benguria, R.D.; Depassier, M.C.; Mendez, V.

    2002-01-01

    Reaction diffusion equations arise in several problems of population dynamics, flame propagation and others. In one dimensional cases the systems may evolve into travelling fronts. Here we concentrate on a reaction diffusion equation which arises as a simple model for chemotaxis and present results for the speed of the travelling fronts. (Author)

  11. Le front oriental de Lille

    Directory of Open Access Journals (Sweden)

    Étienne Poncelet

    2011-06-01

    Full Text Available De la porte d’eau de la Basse Deûle jusqu’au fort Saint-Sauveur, le front oriental de Lille, fortifié à l’époque espagnole, glisse ses courtines dans les entrelacs du périphérique et des gares. L’enjeu urbain actuel consiste à s’appuyer sur ces murs historiques pour « passer malgré tout » à travers cet écheveau urbain et retisser les fils de la continuité des promenades au cœur de la ville. Moins connus que le front occidental de la reine des citadelles, ces anciens espaces militaires sont une chance pour l’urbanisme de demain dont les opérations en cours de la Porte de Gand et de la Basse Deûle témoignent déjà.The east wall, at Lille, fortified during the period of Spanish occupation, extends from the Porte d'Eau de la Basse-Deûle to the Saint-Sauveur fort. Its curtain walls emerge today in a landscape of ring roads and railway territories. The issue today is to profit from these historic walls in order to make some sense of the urban chaos and to reinstate some urban continuity in the city-centre walkways. Although they are not as well known as the western wall of this major fortified city, these former military properties are an exciting opportunity for tomorrow's town-planners, as the operations already underway at the Porte de Gand et de la Basse Deûle suggest.

  12. MDT-ASD, CMOS front-end for ATLAS MDT

    CERN Document Server

    Posch, C; Oliver, J

    2007-01-01

    This document serves as the main reference and user`s manual for the read-out chip of the Monitored Drift Tubes in the ATLAS Muon Spectrometer. The eight-channel front-end ASIC is referred to as MDT-ASD. The document contains the requirements and complete specifications, a detailed description of the design with characteristics of all sub-circuits and building blocks, a comprehensive section on functionality and performance test results, and a complete bibliography.

  13. Muon front end for the neutrino factory

    Directory of Open Access Journals (Sweden)

    C. T. Rogers

    2013-04-01

    Full Text Available In the neutrino factory, muons are produced by firing high-energy protons onto a target to produce pions. The pions decay to muons and pass through a capture channel known as the muon front end, before acceleration to 12.6 GeV. The muon front end comprises a variable frequency rf system for longitudinal capture and an ionization cooling channel. In this paper we detail recent improvements in the design of the muon front end.

  14. Muon front end for the neutrino factory

    CERN Document Server

    Rogers, C T; Prior, G; Gilardoni, S; Neuffer, D; Snopok, P; Alekou, A; Pasternak, J

    2013-01-01

    In the neutrino factory, muons are produced by firing high-energy protons onto a target to produce pions. The pions decay to muons and pass through a capture channel known as the muon front end, before acceleration to 12.6 GeV. The muon front end comprises a variable frequency rf system for longitudinal capture and an ionization cooling channel. In this paper we detail recent improvements in the design of the muon front end.

  15. Recoil Reactions in Neutron-Activation Analysis. The Szilard-Chalmers Effect Applied in the Analysis of Biological Samples; II. Transfer of Activities from Container Material to Sample

    Energy Technology Data Exchange (ETDEWEB)

    Brune, D

    1965-01-15

    The present investigation consists of two parts. The one part concerns the application of the Szilard-Chalmers effect in the separation of activities from neutron-irradiated biological material. The nuclides As-76, Au-198, Br-82, Ca-47, Cd-115, Cl-38, Co-60, Cr-51, Cs-134, Cu-64, Fe-59, Mg-27, Mo-99, Na-24, P-32, Rb-86, Se-75 and Zn-65 were extracted from either liver tissue, whole blood or muscle tissue. The extractions were made in water, 0.1 N HCl, 1 N HCl or conc. HCl respectively. The nuclides belonging to the alkali metals together with Br and Cl, were found present in the water and hydrochloric extracts to 96 per cent or more. In the conc. HCl extracts, the greater part of the nuclides were recovered to 90 per cent or more. The enrichment of the different nuclides obtained in the Szilard-Chalmers process was investigated as follows. After extraction of the nuclides from the irradiated material the solution obtained was divided into two parts, one of which was reactivated. The specific activities of the nuclides in the two solutions were then compared, thus giving the enrichment factor In one case, the residue of organic material after extraction was reactivated and the activity compared to the initial one. The effect of dilution together with the application of short irradiation periods favouring higher yield was investigated in the separation of Fe-59 from whole blood samples irradiated in frozen conditions. The other part of the investigation concerns an estimation of the amounts of the activities originating from polyethylene and quartz containers transferred to container surface due to the recoil effect in the thermal neutron-capture process, thus causing contamination of the sample. The universal range-energy relationship given by Lindhard and Scharff has been applied in these calculations. As regards containers with impurities in the ppm region, the amounts of activities transferred owing to this effect were found to be quite negligible. However, when

  16. Discovery of core-structurally novel PTP1B inhibitors with specific selectivity containing oxindole-fused spirotetrahydrofurochroman by one-pot reaction.

    Science.gov (United States)

    Dong, Suzhen; Lei, Yubing; Jia, Shikun; Gao, Lixin; Li, Jia; Zhu, Tong; Liu, Shunying; Hu, Wenhao

    2017-02-15

    Protein tyrosine phosphatase 1B (PTP1B) has been proposed to be an ideal target for treatment of type II diabetes and obesity. However, no druggable PTP1B inhibitor has been established and there is still an urgent demand for the development of structurally novel PTPIB inhibitor. Herein, we reported core-structurally novel PTP1B inhibitors with low micromole-ranged inhibitory activity by one-pot reaction from simple starting materials. Further studies demonstrated some of these active compounds had a specific selectivity over other PTPs. The structure and activity relationship was also described. The best active and selective compound 5e inhibited PTP1B activity with an IC 50 of 4.53μM. Molecular docking analysis further demonstrated that compound 5e bound to the active pocket of PTP1B. The results might provide some insights for further development of new drugs for type II diabetes and obesity. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. ESI-MS studies of the reactions of novel platinum(II) complexes containing O,O'-chelated acetylacetonate and sulfur ligands with selected model proteins.

    Science.gov (United States)

    Marzo, Tiziano; De Pascali, Sandra A; Gabbiani, Chiara; Fanizzi, Francesco P; Messori, Luigi; Pratesi, Alessandro

    2017-08-01

    A group of mixed-ligand Pt(II) complexes bearing acetylacetonate and sulphur ligands were recently developed in the University of Lecce as a new class of prospective anticancer agents that manifested promising pharma-cological properties in preliminary in vitro and in vivo tests. Though modelled on the basis of cisplatin, these Pt(II) complexes turned out to exhibit a profoundly distinct mode of action as they were found to act mainly on non-genomic targets rather than on DNA. Accordingly, we have explored here their reactions with two representative model proteins through an established ESI-MS procedure with the aim to describe their general interaction mechanism with protein targets. A pronounced reactivity with the tested proteins was indeed documented; the nature of the resulting metallodrug-protein interactions could be characterised in depth in the various cases. Preferential binding to protein targets compared to DNA is supported by independent ICP-OES measurements. The implications of these findings are discussed.

  18. Adsorption and reaction mechanism of arsenic vapors over γ-Al2O3 in the simulated flue gas containing acid gases.

    Science.gov (United States)

    Hu, Hongyun; Chen, Dunkui; Liu, Huan; Yang, Yuhan; Cai, Hexun; Shen, Junhao; Yao, Hong

    2017-08-01

    Arsenic emission from fuel combustion and metal smelting flue gas causes serious pollution. Addition of sorbents is a promising way for the arsenic capture from high temperature flue gas. However, it is difficult to remove arsenic from SO 2 /HCl-rich flue gas due to the competitive reaction of the sorbents with arsenic and these acid gases. To solve this problem, arsenic adsorption over γ-Al 2 O 3 was studied in this work to evaluate its adsorption mechanism, resistance to acid gases as well as regeneration behavior. The results show that γ-Al 2 O 3 had good resistance to acid gases and the arsenic adsorption by γ-Al 2 O 3 could be effectively carried out at a wide temperature range between 573 and 1023 K. Nevertheless, adsorption at higher-temperature (like 1173 K) leaded to the decrease of surface area and the rearrangement of crystal structure of γ-Al 2 O 3 , reducing the active sites for arsenic adsorption. The adsorption of arsenic was confirmed to occur at different active sites in γ-Al 2 O 3 by forming various adsorbed species. Increasing temperature facilitated arsenic transformation into more stable chemisorbed As 3+ and As 5+ which were difficult to remove through thermal treatment regeneration. Fortunately, the regeneration of spent γ-Al 2 O 3 could be well performed using NaOH solution. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. A Metal Stable Isotope Approach to Understanding Uranium Mobility Across Roll Front Redox Boundaries

    Science.gov (United States)

    Brown, S. T.; Basu, A.; Christensen, J. N.; DePaolo, D. J.; Heikoop, J. M.; Reimus, P. W.; Maher, K.; Weaver, K. L.

    2015-12-01

    Sedimentary roll-front uranium (U) ore deposits are the principal source of U for nuclear fuel in the USA and an important part of the current all-of-the-above energy strategy. Mining of roll-front U ore in the USA is primarily by in situ alkaline oxidative dissolution of U minerals. There are significant environmental benefits to in situ mining including no mine tailings or radioactive dust, however, the long-term immobilization of U in the aquifer after the completion of mining remains uncertain. We have utilized the metal stable isotopes U, Se and Mo in groundwater from roll-front mines in Texas and Wyoming to quantify the aquifer redox conditions and predict the onset of U reduction after post mining aquifer restoration. Supporting information from the geochemistry of groundwater and aquifer sediments are used to understand the transport of U prior to and after in situ mining. Groundwater was collected across 4 mining units at the Rosita mine in the Texas coastal plain and 2 mining units at the Smith Ranch mine in the Powder River Basin, Wyoming. In general, the sampled waters are moderately reducing and ore zone wells contain the highest aqueous U concentrations. The lowest U concentrations occur in monitoring wells downgradient of the ore zone. 238U/235U is lowest in downgradient wells and is correlated with aqueous U concentrations. Rayleigh distillation models of the 238U/235U are consistent with U isotope fractionation factors of 1.0004-1.001, similar to lab-based studies. Based on these results we conclude that redox reactions continue to affect U distribution in the ore zone and downgradient regions. We also measured aqueous selenium isotope (δ82Se) and molybdenum isotope (δ98Mo) compositions in the Rosita groundwater. Se(VI) primarily occurs in the upgradient wells and is absent in most ore zone and downgradient wells. Rayleigh distillation models suggest reduction of Se(VI) along the groundwater flow path and when superimposed on the U isotope data

  20. Stability of cosmological deflagration fronts

    Science.gov (United States)

    Mégevand, Ariel; Membiela, Federico Agustín

    2014-05-01

    In a cosmological first-order phase transition, bubbles of the stable phase nucleate and expand in the supercooled metastable phase. In many cases, the growth of bubbles reaches a stationary state, with bubble walls propagating as detonations or deflagrations. However, these hydrodynamical solutions may be unstable under corrugation of the interface. Such instability may drastically alter some of the cosmological consequences of the phase transition. Here, we study the hydrodynamical stability of deflagration fronts. We improve upon previous studies by making a more careful and detailed analysis. In particular, we take into account the fact that the equation of motion for the phase interface depends separately on the temperature and fluid velocity on each side of the wall. Fluid variables on each side of the wall are similar for weakly first-order phase transitions, but differ significantly for stronger phase transitions. As a consequence, we find that, for large enough supercooling, any subsonic wall velocity becomes unstable. Moreover, as the velocity approaches the speed of sound, perturbations become unstable on all wavelengths. For smaller supercooling and small wall velocities, our results agree with those of previous works. Essentially, perturbations on large wavelengths are unstable, unless the wall velocity is higher than a critical value. We also find a previously unobserved range of marginally unstable wavelengths. We analyze the dynamical relevance of the instabilities, and we estimate the characteristic time and length scales associated with their growth. We discuss the implications for the electroweak phase transition and its cosmological consequences.

  1. Stability of cosmological detonation fronts

    Science.gov (United States)

    Mégevand, Ariel; Membiela, Federico Agustín

    2014-05-01

    The steady-state propagation of a phase-transition front is classified, according to hydrodynamics, as a deflagration or a detonation, depending on its velocity with respect to the fluid. These propagation modes are further divided into three types, namely, weak, Jouguet, and strong solutions, according to their disturbance of the fluid. However, some of these hydrodynamic modes will not be realized in a phase transition. One particular cause is the presence of instabilities. In this work we study the linear stability of weak detonations, which are generally believed to be stable. After discussing in detail the weak detonation solution, we consider small perturbations of the interface and the fluid configuration. When the balance between the driving and friction forces is taken into account, it turns out that there are actually two different kinds of weak detonations, which behave very differently as functions of the parameters. We show that the branch of stronger weak detonations are unstable, except very close to the Jouguet point, where our approach breaks down.

  2. Up front in the CIS

    International Nuclear Information System (INIS)

    Grey, C.A.

    1994-01-01

    A picture is drawn of the current supply side of the front-end fuel cycle production capacities in the CIS. Uranium production has been steadily declining, as in the West. Market realities have been reflected in local costs of production since the break-up of the former Soviet Union and some uneconomic mines have been closed. In terms of actual production, Kazakhstan, Russia and Uzbekistan, remain among the top five uranium producers in the world. Western government action has been taken to restrict the market access for natural uranium from the CIS. Reactors in the CIS continue to be supplied with fabricated fuel solely by Russian, though Western fuel fabricators have reduced Russian supplies to Eastern Europe. Russia's current dominance in conversion and enrichment services in both the CIS and Eastern Europe is likely to continue as long as the present surplus low enriched uranium stocks last and surplus production capacity exists. Market penetration in the West has been limited by government action but Russia in 1993 still held about 20% of the world's conversion market and nearly 19% of the enrichment market. (6 figures, 2 tables, 4 references) (UK)

  3. Application of up-front licensing

    International Nuclear Information System (INIS)

    Grant, S.D.; Snell, V.G.

    1995-01-01

    AECL has been pioneering 'up-front' licensing of new reactor designs. The CANDU 3 design has been formally reviewed by AECB staff for a number of years. The CANDU 9 design has just started the up-front licensing process. The process gives designers, regulators and potential customers early confidence in the licensability of future plants. (author). 4 refs., 2 tabs

  4. Application of up-front licensing

    Energy Technology Data Exchange (ETDEWEB)

    Grant, S D [Atomic Energy of Canada Ltd., Saskatoon, SK (Canada); Snell, V G [Atomic Energy of Canada Ltd., Mississauga, ON (Canada)

    1996-12-31

    AECL has been pioneering `up-front` licensing of new reactor designs. The CANDU 3 design has been formally reviewed by AECB staff for a number of years. The CANDU 9 design has just started the up-front licensing process. The process gives designers, regulators and potential customers early confidence in the licensability of future plants. (author). 4 refs., 2 tabs.

  5. RPC performance vs. front-end electronics

    International Nuclear Information System (INIS)

    Cardarelli, R.; Aielli, G.; Camarri, P.; Di Ciaccio, A.; Di Stante, L.; Liberti, B.; Pastori, E.; Santonico, R.; Zerbini, A.

    2012-01-01

    Moving the amplification from the gas to the front-end electronics was a milestone in the development of Resistive Plate Chambers. Here we discuss the historical evolution of RPCs and we show the results obtained with newly developed front-end electronics with threshold in the fC range.

  6. Through the EU's Back and Front Doors

    DEFF Research Database (Denmark)

    Adler-Nissen, Rebecca

    2015-01-01

    Through the EU's front- and backdoors: The selective Danish and Norwegian approaches in the Area of Freedom, Security and Justice Rebecca Adler-Nissen......Through the EU's front- and backdoors: The selective Danish and Norwegian approaches in the Area of Freedom, Security and Justice Rebecca Adler-Nissen...

  7. Control of a laser front wave

    International Nuclear Information System (INIS)

    Akaoka, K.; Wakaida, I.

    1996-01-01

    We controlled the laser wave front through a laser beam simulation experiment propagating through medium. Thus, we confirmed that the RMS, defined as the quadratic mean of the laser beam wave front, dropped to the 1/3 - 1/6 of the pre-control value

  8. Nuclear Physics on the Light Front

    OpenAIRE

    Miller, Gerald A.

    1999-01-01

    High energy scattering experiments involving nuclei are typically analyzed in terms of light front variables. The desire to provide realistic, relativistic wave functions expressed in terms of these variables led me to try to use light front dynamics to compute nuclear wave functions. The progress is summarized here.

  9. Wave fronts of electromagnetic cyclotron harmonic waves

    International Nuclear Information System (INIS)

    Ohnuma, T.; Watanabe, T.

    1982-01-01

    In an inhomogeneous high-density magnetized plasma, the spatial properties of the wave fronts and ray trajectories of electromagnetic ordinary and extraordinary cyclotron harmonic waves are investigated. Those waves which are radiated from a local source are found to have wave fronts which are almost parallel to the magnetic field. Also, the reflective properties of the electromagnetic cyclotron harmonic waves are confirmed

  10. End-Users, Front Ends and Librarians.

    Science.gov (United States)

    Bourne, Donna E.

    1989-01-01

    The increase in end-user searching, the advantages and limitations of front ends, and the role of the librarian in end-user searching are discussed. It is argued that librarians need to recognize that front ends can be of benefit to themselves and patrons, and to assume the role of advisors and educators for end-users. (37 references) (CLB)

  11. The PHENIX Drift Chamber Front End Electroncs

    Science.gov (United States)

    Pancake, C.; Velkovska, J.; Pantuev, V.; Fong, D.; Hemmick, T.

    1998-04-01

    The PHENIX Drift Chamber (DC) is designed to operate in the high particle flux environment of the Relativistic Heavy Ion Collider and provide high resolution track measurements. It is segmented into 80 keystones with 160 readout channels each. The Front End Electronics (FEE) developed to meet the demanding operating conditions and the large number of readout channels of the DC will be discussed. It is based on two application specific integrated circuits: the ASD8 and the TMC-PHX1. The ASD8 chip contains 8 channels of bipolar amplifier-shaper-discriminator with 6 ns shaping time and ≈ 20 ns pulse width, which satisfies the two track resolution requirements. The TMC-PHX1 chip is a high-resolution multi-hit Time-to-Digital Converter. The outputs from the ASD8 are digitized in the Time Memory Cell (TMC) every (clock period)/32 or 0.78 ns (at 40 MHz), which gives the intrinsic time resolution of the system. A 256 words deep dual port memory keeps 6.4 μs time history of data at 40 MHz clock. Each DC keystone is supplied with 4 ASD8/TMC boards and one FEM board, which performs the readout of the TMC-PHX1's, buffers and formats the data to be transmitted over the Glink. The slow speed control communication between the FEM and the system is carried out over ARCNET. The full readout chain and the data aquisition system are being tested.

  12. Front tracking for hyperbolic conservation laws

    CERN Document Server

    Holden, Helge

    2015-01-01

    This is the second edition of a well-received book providing the fundamentals of the theory hyperbolic conservation laws. Several chapters have been rewritten, new material has been added, in particular, a chapter on space dependent flux functions, and the detailed solution of the Riemann problem for the Euler equations. Hyperbolic conservation laws are central in the theory of nonlinear partial differential equations and in science and technology. The reader is given a self-contained presentation using front tracking, which is also a numerical method. The multidimensional scalar case and the case of systems on the line are treated in detail. A chapter on finite differences is included. From the reviews of the first edition: "It is already one of the few best digests on this topic. The present book is an excellent compromise between theory and practice. Students will appreciate the lively and accurate style." D. Serre, MathSciNet  "I have read the book with great pleasure, and I can recommend it to experts ...

  13. Front tracking for hyperbolic conservation laws

    CERN Document Server

    Holden, Helge

    2002-01-01

    Hyperbolic conservation laws are central in the theory of nonlinear partial differential equations and in science and technology. The reader is given a self-contained presentation using front tracking, which is also a numerical method. The multidimensional scalar case and the case of systems on the line are treated in detail. A chapter on finite differences is included. "It is already one of the few best digests on this topic. The present book is an excellent compromise between theory and practice. Students will appreciate the lively and accurate style." D. Serre, MathSciNet "I have read the book with great pleasure, and I can recommend it to experts as well as students. It can also be used for reliable and very exciting basis for a one-semester graduate course." S. Noelle, Book review, German Math. Soc. "Making it an ideal first book for the theory of nonlinear partial differential equations...an excellent reference for a graduate course on nonlinear conservation laws." M. Laforest, Comp. Phys. Comm.

  14. Flexible Frequency Discrimination Subsystems for Reconfigurable Radio Front Ends

    Directory of Open Access Journals (Sweden)

    Carey-Smith Bruce E

    2005-01-01

    Full Text Available The required flexibility of the software-defined radio front end may currently be met with better overall performance by employing tunable narrowband circuits rather than pursuing a truly wideband approach. A key component of narrowband transceivers is appropriate filtering to reduce spurious spectral content in the transmitter and limit out-of-band interference in the receiver. In this paper, recent advances in flexible, frequency-selective, circuit components applicable to reconfigurable SDR front ends are reviewed. The paper contains discussion regarding the filtering requirements in the SDR context and the use of intelligent, adaptive control to provide environment-aware frequency discrimination. Wide tuning-range frequency-selective circuit elements are surveyed including bandpass and bandstop filters and narrowband tunable antennas. The suitability of these elements to the mobile wireless SDR environment is discussed.

  15. Nucleon parton distributions in a light-front quark model

    International Nuclear Information System (INIS)

    Gutsche, Thomas; Lyubovitskij, Valery E.; Schmidt, Ivan

    2017-01-01

    Continuing our analysis of parton distributions in the nucleon, we extend our light-front quark model in order to obtain both the helicity-independent and the helicity-dependent parton distributions, analytically matching the results of global fits at the initial scale μ∝ 1 GeV; they also contain the correct Dokshitzer-Gribov-Lipatov-Altarelli-Parisi evolution. We also calculate the transverse parton, Wigner and Husimi distributions from a unified point of view, using our light-front wave functions and expressing them in terms of the parton distributions q_v(x) and δq_v(x). Our results are very relevant for the current and future program of the COMPASS experiment at SPS (CERN). (orig.)

  16. Nucleon parton distributions in a light-front quark model

    Energy Technology Data Exchange (ETDEWEB)

    Gutsche, Thomas [Universitaet Tuebingen, Institut fuer Theoretische Physik, Kepler Center for Astro and Particle Physics, Tuebingen (Germany); Lyubovitskij, Valery E. [Universitaet Tuebingen, Institut fuer Theoretische Physik, Kepler Center for Astro and Particle Physics, Tuebingen (Germany); Tomsk State University, Department of Physics, Tomsk (Russian Federation); Tomsk Polytechnic University, Laboratory of Particle Physics, Mathematical Physics Department, Tomsk (Russian Federation); Universidad Tecnica Federico Santa Maria, Departamento de Fisica y Centro Cientifico Tecnologico de Valparaiso (CCTVal), Valparaiso (Chile); Schmidt, Ivan [Universidad Tecnica Federico Santa Maria, Departamento de Fisica y Centro Cientifico Tecnologico de Valparaiso (CCTVal), Valparaiso (Chile)

    2017-02-15

    Continuing our analysis of parton distributions in the nucleon, we extend our light-front quark model in order to obtain both the helicity-independent and the helicity-dependent parton distributions, analytically matching the results of global fits at the initial scale μ∝ 1 GeV; they also contain the correct Dokshitzer-Gribov-Lipatov-Altarelli-Parisi evolution. We also calculate the transverse parton, Wigner and Husimi distributions from a unified point of view, using our light-front wave functions and expressing them in terms of the parton distributions q{sub v}(x) and δq{sub v}(x). Our results are very relevant for the current and future program of the COMPASS experiment at SPS (CERN). (orig.)

  17. The hybridized front end electronics of the Central Drift Chamber in the Stanford Linear Collider Detector

    International Nuclear Information System (INIS)

    Lo, C.C.; Kirsten, F.A.; Nakamura, M.

    1987-10-01

    In order to accommodate the high packaging density requirements for the front end electronics of the Central Drift Chamber (CDC) in the SLAC Linear Collider Detector (SLD), the CDC front end electronics has been hybridized. The hybrid package contains eight channels of amplifiers together with all the associated circuits for calibration, event recognition and power economy switching functions. A total of 1280 such hybrids are used in the CDC

  18. Blocking-resistant communication through domain fronting

    Directory of Open Access Journals (Sweden)

    Fifield David

    2015-06-01

    Full Text Available We describe “domain fronting,” a versatile censorship circumvention technique that hides the remote endpoint of a communication. Domain fronting works at the application layer, using HTTPS, to communicate with a forbidden host while appearing to communicate with some other host, permitted by the censor. The key idea is the use of different domain names at different layers of communication. One domain appears on the “outside” of an HTTPS request—in the DNS request and TLS Server Name Indication—while another domain appears on the “inside”—in the HTTP Host header, invisible to the censor under HTTPS encryption. A censor, unable to distinguish fronted and nonfronted traffic to a domain, must choose between allowing circumvention traffic and blocking the domain entirely, which results in expensive collateral damage. Domain fronting is easy to deploy and use and does not require special cooperation by network intermediaries. We identify a number of hard-to-block web services, such as content delivery networks, that support domain-fronted connections and are useful for censorship circumvention. Domain fronting, in various forms, is now a circumvention workhorse. We describe several months of deployment experience in the Tor, Lantern, and Psiphon circumvention systems, whose domain-fronting transports now connect thousands of users daily and transfer many terabytes per month.

  19. Characterizing Ion Flows Across a Dipolarization Front

    Science.gov (United States)

    Arnold, H.; Drake, J. F.; Swisdak, M.

    2017-12-01

    In light of the Magnetospheric Multiscale Mission (MMS) moving to study predominately symmetric magnetic reconnection in the Earth's magnetotail, it is of interest to investigate various methods for determining the relative location of the satellites with respect to the x line or a dipolarization front. We use a 2.5 dimensional PIC simulation to explore the dependence of various characteristics of a front, or flux bundle, on the width of the front in the dawn-dusk direction. In particular, we characterize the ion flow in the x-GSM direction across the front. We find a linear relationship between the width of a front, w, and the maximum velocity of the ion flow in the x-GSM direction, Vxi, for small widths: Vxi/VA=w/di*1/2*(mVA2)/Ti*Bz/Bxwhere m, VA, di, Ti, Bz, and Bx are the ion mass, upstream Alfven speed, ion inertial length, ion temperature, and magnetic fields in the z-GSM and x-GSM directions respectively. However, once the width reaches around 5 di, the relationship gradually approaches the well-known theoretical limit for ion flows, the upstream Alfven speed. Furthermore, we note that there is a reversal in the Hall magnetic field near the current sheet on the positive y-GSM side of the front. This reversal is most likely due to conservation of momentum in the y-GSM direction as the ions accelerate towards the x-GSM direction. This indicates that while the ions are primarily energized in the x-GSM direction by the front, they transfer energy to the electromagnetic fields in the y-GSM direction. The former energy transfer is greater than the latter, but the reversal of the Hall magnetic field drags the frozen-in electrons along with it outside of the front. These simulations should better able researchers to determine the relative location of a satellite crossing a dipolarization front.

  20. Managing Controversies in the Fuzzy Front End

    DEFF Research Database (Denmark)

    Christiansen, John K.; Gasparin, Marta

    2016-01-01

    This research investigates the controversies that emerge in the fuzzy front end (FFE) and how they are closed so the innovation process can move on. The fuzzy front has been characterized in the literature as a very critical phase, but controversies in the FFE have not been studied before....... The analysis investigates the microprocesses around the controversies that emerge during the fuzzy front end of four products. Five different types of controversies are identified: profit, production, design, brand and customers/market. Each controversy represents a threat, but also an opportunity to search...

  1. SPD very front end electronics

    International Nuclear Information System (INIS)

    Luengo, S.; Gascon, D.; Comerma, A.; Garrido, L.; Riera, J.; Tortella, S.; Vilasis, X.

    2006-01-01

    The Scintillator Pad Detector (SPD) is part of the LHCb calorimetry system [D. Breton, The front-end electronics for LHCb calorimeters, Tenth International Conference on Calorimetry in Particle Physics, CALOR, Pasadena, 2002] that provides high-energy hadron, electron and photon candidates for the first level trigger. The SPD is designed to distinguish electrons from photons. It consists of a plastic scintillator layer, divided into about 6000 cells of different size to obtain better granularity near the beam [S. Amato, et al., LHCb technical design report, CERN/LHCC/2000-0036, 2000]. Charged particles will produce, and photons will not, ionization in the scintillator. This ionization generates a light pulse that is collected by a WaveLength Shifting (WLS) fiber that is coiled inside the scintillator cell. The light is transmitted through a clear fiber to the readout system that is placed at the periphery of the detector. Due to space constraints, and in order to reduce costs, these 6000 cells are divided in groups using a MAPMT [Z. Ajaltouni, et al., Nucl. Instr. and Meth. A 504 (2003) 9] of 64 channels that provides information to the VFE readout electronics. The SPD signal has rather large statistical fluctuations because of the low number (20-30) of photoelectrons per MIP. Therefore the signal is integrated over the whole bunch crossing length of 25 ns in order to have the maximum value. Since in average about 85% of the SPD signal is within 25 ns, 15% of a sample is subtracted from the following one using an operational amplifier. The SPD VFE readout system that will be presented consists of the following components. A specific ASIC [D. Gascon, et al., Discriminator ASIC for the VFE SPD of the LHCb Calorimeter, LHCB Technical Note, LHCB 2004-xx] integrates the signal, makes the signal-tail subtraction, and compares the level obtained to a programmable threshold (to distinguish electrons from photons). A FPGA programmes the ASIC threshold and the value for

  2. Geostatistical ore reserve estimation for a roll-front type uranium deposit (practitioner's guide)

    International Nuclear Information System (INIS)

    Kim, Y.C.; Knudsen, H.P.

    1977-01-01

    This report comprises two parts. Part I contains illustrative examples of each phase of a geostatistical study using a roll-front type uranium deposit. Part II contains five computer programs and comprehensive users' manuals for these programs which are necessary to make a practical geostatistical study

  3. Localized structures and front propagation in the Lengyel-Epstein model

    DEFF Research Database (Denmark)

    Jensen, O.; Pannbacker, Viggo Ole; Mosekilde, Erik

    1994-01-01

    Pattern selection, localized structure formation, and front propagation are analyzed within the framework of a model for the chlorine dioxide-iodine-malonic acid reaction that represents a key to understanding recently obtained Turing structures. This model is distinguished from previously studied......, simple reaction-diffusion models by producing a strongly subcritical transition to stripes. The wave number for the modes of maximum linear gain is calculated and compared with the dominant wave number for the finally selected, stationary structures grown from the homogeneous steady state or developed...... bifurcation. In the subcritical regime there is an interval where the front velocity vanishes as a result of a pinning of the front to the underlying structure. In 2D, two different nucleation mechanisms for hexagonal structures are illustrated on the Lengyel-Epstein and the Brusselator model. Finally...

  4. On Front Slope Stability of Berm Breakwaters

    DEFF Research Database (Denmark)

    Burcharth, Hans F.

    2013-01-01

    The short communication presents application of the conventional Van der Meer stability formula for low-crested breakwaters for the prediction of front slope erosion of statically stable berm breakwaters with relatively high berms. The method is verified (Burcharth, 2008) by comparison...... with the reshaping of a large Norwegian breakwater exposed to the North Sea waves. As a motivation for applying the Van der Meer formula a discussion of design parameters related to berm breakwater stability formulae is given. Comparisons of front erosion predicted by the use of the Van der Meer formula with model...... test results including tests presented in Sigurdarson and Van der Meer (2011) are discussed. A proposal is presented for performance of new model tests with the purpose of developing more accurate formulae for the prediction of front slope erosion as a function of front slope, relative berm height...

  5. Study of the properties of self-sustaining nuclear chain reaction in the fuel-containing masses of the "Ukryttya" object for the case of varying velocity of water inflow

    Directory of Open Access Journals (Sweden)

    V. A. Babenko

    2018-03-01

    Full Text Available The main peculiarities of ignition and development of self-sustaining nuclear chain reaction (SCR in fuel-containing masses (FCM of Chernobyl "Ukryttya" were studied for the case of varying velocity of water incoming into the system or its outcoming. On the basis of analysis and numerical solution of the corresponding system of differential equations for the main characteristics of the system, it was shown that the variations of water inflow could lead to very sufficient and various changes in SCR development comparing to possible modes at constant velocities of water inflow. In particular, the calculations show that the neutron bursts with great amplitude could take place in the system under definite sufficiently reasonable physical conditions. It was also shown that the increase of velocity of water inflow into the FCM in the mode of constant oscillations can lead to transition into "beyond critical" state which is the subcritical state with big quantity of water.

  6. A geometric classification of traveling front propagation in the Nagumo equation with cut-off

    International Nuclear Information System (INIS)

    Popovic, N

    2011-01-01

    An important category of solutions to reaction-diffusion systems of partial differential equations is given by traveling fronts, which provide a monotonic connection between rest states and maintain a fixed profile when considered in a co-moving frame. Reaction-diffusion equations are frequently employed in the mean-field (continuum) approximation of discrete (many-particle) models; however, the quality of this approximation deteriorates when the number of particles is not sufficiently large. The (stochastic) effects of this discreteness have been modeled via the introduction of (deterministic) 'cut-offs' that effectively deactivate the reaction terms at points where the particle concentration is below a certain threshold. In this article, we present an overview of the effects of such a cut-off on the front propagation dynamics in a prototypical reaction-diffusion system, the classical Nagumo equation. Our analysis is based on the method of geometric desingularization ('blow-up'), in combination with dynamical systems techniques such as invariant manifolds and normal forms. Using these techniques, we categorize front propagation in the cut-off Nagumo equation in dependence of a control parameter, and we classify the corresponding propagation regimes ('pulled,' 'pushed,' and 'bistable') in terms of the bifurcation structure of a projectivized system of equations that is obtained from the original traveling front problem, after blow-up. In particular, our approach allows us to determine rigorously the asymptotics (in the cut-off parameter) of the correction to the front propagation speed in the Nagumo equation that is due to a cut-off. Moreover, it explains the structure of that asymptotics (logarithmic, superlinear, or sublinear) in dependence of the front propagation regime. Finally, it enables us to calculate the corresponding leading-order coefficients in the resulting expansions in closed form.

  7. Life on the front lines.

    Science.gov (United States)

    Hern, W M

    1993-01-01

    honor those who advanced the cause of women's rights. They honored the physician who had to shout over hecklers to make his remarks heard. After a year of operation, the physician encountered differences with the Board of Directors of the clinic. Soon after that, he resigned and opened his own clinic with a bank loan of $7000. Within 4 years, his clinic had expanded, and he purchased its building. The harassment from antiabortion protesters continued, with broken windows, pickets, and, in February 1988, bullets fired through the front windows of the waiting room. This necessitated the installation of bullet-proof glass and a security system which cost $17,000. As of March 1, 1993, there had been 1285 acts of violence towards abortion clinics, which led to the destruction of more than 100. On March 10 of that year, a physician who performed abortions in Florida was gunned down by an anti-abortion protestor. People who provide abortions hope for legal protection and respect for their civil liberties, but they will continue to provide this service even if conditions do not improve.

  8. Kinematics and thermodynamics across a propagating non-stoichiometric oxidation phase front in spent fuel grains

    International Nuclear Information System (INIS)

    Stout, R.B.; Kansa, E.J.; Wijesinghe, A.M.

    1993-09-01

    Spent fuel contains mixtures, alloy and compound, but are dominated by U and O except for some UO 2 fuels with burnable poisons (gadolinia in BWR rods), the other elements evolve during reactor operation from neutron reaction and fission + fission decay events. Due to decay, chemical composition and activity of spent fuel will continue to evolve after removal from reactors. During the time interval with significant radioactivity levels relevant for a geological repository, it is important to develop models for potential chemical responses in spent fuel and potential degradation of repository. One such potential impact is the oxidation of spent fuel, which results in initial phase change of UO 2 lattice to U 4 O 9 and the next phase change is probably to U 3 O 8 although it has not been observed yet below 200C. The U 4 O 9 lattice is nonstoichiometric with a O/U weight ratio at 2.4. Preliminary indications are that the UO 2 has a O/U of 2. 4 at the time just before it transforms into the U 4 O 9 phase. In the oxygen weight gain versus time response, a plateau appears as the O/U approaches 2.4. Part of this plateau is due to geometrical effects of a U 4 O 9 phase change front propagating into UO 2 grain volumes; however, this may indicate a metastable phase change delay kinetics or a diffusional related delay time until the oxygen density can satisfy stoichiometry and energy conditions for phase changes. Experimental data show a front of U 4 O 9 lattice structure propagating into grains of the UO 2 lattice. To describe this spatially inhomogenous oxidation phase transition, as well as the expected U 3 O 8 phase transition from the U 4 O 9 lattice, lattice models are developed and spatially discontinuous kinematic and energetic expressions are derived. 9 refs

  9. Study of deuterons induced nuclear reactions on light elements (N, Al and Si): Application to containment materials of radioactive wastes; Etude des reactions nucleaires induites par des deuterons sur des elements legers (N, Al, Si): application aux materiaux de confinement des dechets radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Pellegrino, St

    2004-03-01

    Nuclear reaction analysis is well adapted to the quantification of light element. Profiles of concentration in order to follow elements migration into materials can be undertaken. This technique is used to study the behavior of the future matrices for nuclear waste containment. This technique is isotopic, characterized by a good signal-to-background ratio and a very low detection limit. The probability of a nuclear reaction is linked to a parameter called 'cross section' we have to know in order to carry out quantitative analysis. We have determined excitation curves for nitrogen, aluminium and silicon. These experiments were done with deuterons from 0.5 to 2 MeV. Two methods for the cross section characterization are presented and are in agreement with each other. The second one reduces uncertainty. Data are incorporated in the simulation software SIMNRA. We have compared the results obtained on different samples when we use data in literature or data of the study. We have noticed a great fit improvement with the data of this study. The new cross sections of this work will be integrated in the general data base SIGMABASE. Applications on materials such as Si{sub 3}N{sub 4}, nano-metric powders, WCN and nuclear glass YLaMgSiAlON studied for radioactive waste containment are also presented. (author)

  10. PENETRATION OF A SHOCK WAVE IN A FLAME FRONT

    Directory of Open Access Journals (Sweden)

    Dan PANTAZOPOL

    2009-09-01

    Full Text Available The present paper deals with the interactions between a fully supersonic flame front, situated in a supersonic two-dimensional flow of an ideal homogeneous combustible gas mixture, and an incident shock wawe, which is penetrating in the space of the hot burnt gases. A possible configuration, which was named ,,simple penetration” is examined. For the anlysis of the interference phenomena, shock polar and shock-combustion polar are used. At the same time, the paper shows the possibility to produce similar but more complicated configurations, which may contain expansion fans and reflected shock waves.

  11. PMF: the front end electronic of the ALFA detector

    CERN Document Server

    Barrillon, P; Cheikali, C; Cuisy, D; Gaspard, M; Fournier, D; Heller, M; Iwanski, W; Lavigne, B; de La Taille, C; Puzo, P; Socha, J-L

    2008-01-01

    The front end electronic (PMF) of the future ATLAS luminometer is described here. It is composed by a MAPMT and a compact stack of three PCBs which deliver the high voltage, route and readout the output signals. The third board contains a FPGA and MAROC, a 64 channels ASIC which can correct the non uniformity of the MAPMT channels gain thanks to a variable gain preamplifier. Its main role is to shape and discriminate the input signals at 1/3 photo-electron and produce 64 trigger outputs. Laboratory tests performed on prototype and pre-series PMFs have showed performances in good agreement with the requirements.

  12. New RPC front-end electronics for hades

    CERN Document Server

    Gil, Alejandro; Cabanelas, P; Díaz, J; Garzón, J A; González-Díaz, D; König, W; Lange, J S; Marín, J; Montes, N; Skott, P; Traxler, M

    2007-01-01

    Time-of-flight (TOF) detectors are mainly used for both particle identification and triggering. Resistive Plate Chamber (RPC) detectors are becoming widely used because of their excellent TOF capabilities and reduced cost. The new ESTRELA* RPC wall, which is being installed in the HADES detector at Darmstadt GSI, will contain 1024 RPC modules, covering an active area of around 7 m2. It has excellent TOF and good charge resolutions. Its Front-End electronics is based on a 8-layer Mother-Board providing impedance matched paths for the output signals of each of the eight 4-channel Daughter-Boards to the TDC.

  13. Front-end electronics for the CMS preshower detector

    CERN Document Server

    Go, A; Barney, D; Bloch, P; Peisert, Anna; Löfstedt, B; Reynaud, S; Borkar, S; Lalwani, S

    2002-01-01

    The front-end readout system PACE2 for the CMS preshower detector consists of two chips: Delta is a 32 channel preamplifier and shaper that provides low noise, charge to voltage readout for large capacitive silicon sensors over a large dynamic range (up to 400 MIPs); PACE-AM contains a 32-channel wide, 160-cell deep, analog memory with a 32 to 1 multiplexer for serial readout. These chips are designed in .8 mu m BiCMOS DMILL radiation tolerant technology. The performance in terms of dynamic range, linearity, noise, peaking time and memory uniformity are presented. (4 refs).

  14. Electromagnetic form factors in the light-front dynamics

    International Nuclear Information System (INIS)

    Karmanov, V.A.; Smirnov, A.V.

    1992-01-01

    It is shown that the electromagnetic vertex of a nucleus (and of any bound system), expressed through the wave function in the light-front dynamics at relativistic values of momentum transfer, contains a contribution of nonphysical form factors which increases the total number of invariant form factors (for the deuteron from 3 up to 11). This fact explains an ambiguity in the form factors calculated previously. The physical and nonphysical form factors are covariantly separated. Explicit expressions for physical form factors of systems with spin 0, 1/2 and 1 through the vertex functions are obtained. (orig.)

  15. Constraints and Hamiltonian in light-front quantized field theory

    International Nuclear Information System (INIS)

    Srivastava, P.P.

    1993-01-01

    Self-consistent hamiltonian formulation of scalar theory on the null plane is constructed and quantized following the Dirac procedure. The theory contains also constraint equations which would give, if solved, to a nonlocal Hamiltonian. In contrast to the equal-time formulation we obtain a different description of the spontaneous symmetry breaking in the continuum and the symmetry generators are found to annihilate the light-front vacuum. Two examples are given where the procedure cannot be applied self-consistently. The corresponding theories are known to be ill-defined from the equal-time quantization. (author)

  16. QCD and Light-Front Dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; de Teramond, Guy F.; /SLAC /Southern Denmark U., CP3-Origins /Costa Rica U.

    2011-01-10

    AdS/QCD, the correspondence between theories in a dilaton-modified five-dimensional anti-de Sitter space and confining field theories in physical space-time, provides a remarkable semiclassical model for hadron physics. Light-front holography allows hadronic amplitudes in the AdS fifth dimension to be mapped to frame-independent light-front wavefunctions of hadrons in physical space-time. The result is a single-variable light-front Schroedinger equation which determines the eigenspectrum and the light-front wavefunctions of hadrons for general spin and orbital angular momentum. The coordinate z in AdS space is uniquely identified with a Lorentz-invariant coordinate {zeta} which measures the separation of the constituents within a hadron at equal light-front time and determines the off-shell dynamics of the bound state wavefunctions as a function of the invariant mass of the constituents. The hadron eigenstates generally have components with different orbital angular momentum; e.g., the proton eigenstate in AdS/QCD with massless quarks has L = 0 and L = 1 light-front Fock components with equal probability. Higher Fock states with extra quark-anti quark pairs also arise. The soft-wall model also predicts the form of the nonperturbative effective coupling and its {beta}-function. The AdS/QCD model can be systematically improved by using its complete orthonormal solutions to diagonalize the full QCD light-front Hamiltonian or by applying the Lippmann-Schwinger method to systematically include QCD interaction terms. Some novel features of QCD are discussed, including the consequences of confinement for quark and gluon condensates. A method for computing the hadronization of quark and gluon jets at the amplitude level is outlined.

  17. QCD and Light-Front Dynamics

    International Nuclear Information System (INIS)

    Brodsky, Stanley J.; de Teramond, Guy F.

    2011-01-01

    AdS/QCD, the correspondence between theories in a dilaton-modified five-dimensional anti-de Sitter space and confining field theories in physical space-time, provides a remarkable semiclassical model for hadron physics. Light-front holography allows hadronic amplitudes in the AdS fifth dimension to be mapped to frame-independent light-front wavefunctions of hadrons in physical space-time. The result is a single-variable light-front Schroedinger equation which determines the eigenspectrum and the light-front wavefunctions of hadrons for general spin and orbital angular momentum. The coordinate z in AdS space is uniquely identified with a Lorentz-invariant coordinate ζ which measures the separation of the constituents within a hadron at equal light-front time and determines the off-shell dynamics of the bound state wavefunctions as a function of the invariant mass of the constituents. The hadron eigenstates generally have components with different orbital angular momentum; e.g., the proton eigenstate in AdS/QCD with massless quarks has L = 0 and L = 1 light-front Fock components with equal probability. Higher Fock states with extra quark-anti quark pairs also arise. The soft-wall model also predicts the form of the nonperturbative effective coupling and its β-function. The AdS/QCD model can be systematically improved by using its complete orthonormal solutions to diagonalize the full QCD light-front Hamiltonian or by applying the Lippmann-Schwinger method to systematically include QCD interaction terms. Some novel features of QCD are discussed, including the consequences of confinement for quark and gluon condensates. A method for computing the hadronization of quark and gluon jets at the amplitude level is outlined.

  18. Pareto fronts in clinical practice for pinnacle.

    Science.gov (United States)

    Janssen, Tomas; van Kesteren, Zdenko; Franssen, Gijs; Damen, Eugène; van Vliet, Corine

    2013-03-01

    Our aim was to develop a framework to objectively perform treatment planning studies using Pareto fronts. The Pareto front represents all optimal possible tradeoffs among several conflicting criteria and is an ideal tool with which to study the possibilities of a given treatment technique. The framework should require minimal user interaction and should resemble and be applicable to daily clinical practice. To generate the Pareto fronts, we used the native scripting language of Pinnacle(3) (Philips Healthcare, Andover, MA). The framework generates thousands of plans automatically from which the Pareto front is generated. As an example, the framework is applied to compare intensity modulated radiation therapy (IMRT) with volumetric modulated arc therapy (VMAT) for prostate cancer patients. For each patient and each technique, 3000 plans are generated, resulting in a total of 60,000 plans. The comparison is based on 5-dimensional Pareto fronts. Generating 3000 plans for 10 patients in parallel requires on average 96 h for IMRT and 483 hours for VMAT. Using VMAT, compared to IMRT, the maximum dose of the boost PTV was reduced by 0.4 Gy (P=.074), the mean dose in the anal sphincter by 1.6 Gy (P=.055), the conformity index of the 95% isodose (CI(95%)) by 0.02 (P=.005), and the rectal wall V(65 Gy) by 1.1% (P=.008). We showed the feasibility of automatically generating Pareto fronts with Pinnacle(3). Pareto fronts provide a valuable tool for performing objective comparative treatment planning studies. We compared VMAT with IMRT in prostate patients and found VMAT had a dosimetric advantage over IMRT. Copyright © 2013 Elsevier Inc. All rights reserved.

  19. Pareto Fronts in Clinical Practice for Pinnacle

    International Nuclear Information System (INIS)

    Janssen, Tomas; Kesteren, Zdenko van; Franssen, Gijs; Damen, Eugène; Vliet, Corine van

    2013-01-01

    Purpose: Our aim was to develop a framework to objectively perform treatment planning studies using Pareto fronts. The Pareto front represents all optimal possible tradeoffs among several conflicting criteria and is an ideal tool with which to study the possibilities of a given treatment technique. The framework should require minimal user interaction and should resemble and be applicable to daily clinical practice. Methods and Materials: To generate the Pareto fronts, we used the native scripting language of Pinnacle 3 (Philips Healthcare, Andover, MA). The framework generates thousands of plans automatically from which the Pareto front is generated. As an example, the framework is applied to compare intensity modulated radiation therapy (IMRT) with volumetric modulated arc therapy (VMAT) for prostate cancer patients. For each patient and each technique, 3000 plans are generated, resulting in a total of 60,000 plans. The comparison is based on 5-dimensional Pareto fronts. Results: Generating 3000 plans for 10 patients in parallel requires on average 96 h for IMRT and 483 hours for VMAT. Using VMAT, compared to IMRT, the maximum dose of the boost PTV was reduced by 0.4 Gy (P=.074), the mean dose in the anal sphincter by 1.6 Gy (P=.055), the conformity index of the 95% isodose (CI 95% ) by 0.02 (P=.005), and the rectal wall V 65 Gy by 1.1% (P=.008). Conclusions: We showed the feasibility of automatically generating Pareto fronts with Pinnacle 3 . Pareto fronts provide a valuable tool for performing objective comparative treatment planning studies. We compared VMAT with IMRT in prostate patients and found VMAT had a dosimetric advantage over IMRT

  20. Natural Oil-Based Emulsion Containing Allantoin Versus Aqueous Cream for Managing Radiation-Induced Skin Reactions in Patients With Cancer: A Phase 3, Double-Blind, Randomized, Controlled Trial

    Energy Technology Data Exchange (ETDEWEB)

    Chan, Raymond Javan, E-mail: email.rchan@gmail.com [Cancer Care Services, Royal Brisbane and Women' s Hospital, Herston, Queensland (Australia); School of Nursing, Queensland University of Technology, Kelvin Grove (Australia); Institute of Health and Biomedical Innovation, Queensland University of Technology, Kelvin Grove (Australia); Mann, Jennifer; Tripcony, Lee; Keller, Jacqui; Cheuk, Robyn; Blades, Rae [Cancer Care Services, Royal Brisbane and Women' s Hospital, Herston, Queensland (Australia); Keogh, Samantha [National Health and Medical Research Council Centre for Research Excellence in Nursing, Centre for Health Practice Innovation–Griffith Health Institute, Griffith University, Nathan (Australia); Poole, Christopher [Cancer Care Services, Royal Brisbane and Women' s Hospital, Herston, Queensland (Australia); Science and Engineering Faculty, Queensland University of Technology, Brisbane (Australia); Walsh, Christopher [Cancer Care Services, Royal Brisbane and Women' s Hospital, Herston, Queensland (Australia)

    2014-11-15

    Purpose: To investigate the effects of a natural oil-based emulsion containing allantoin versus aqueous cream for preventing and managing radiation-induced skin reactions. Methods and Materials: A total of 174 patients were randomized and participated in the study. Patients received either cream 1 (the natural oil-based emulsion containing allantoin) or cream 2 (aqueous cream). Skin toxicity, pain, itching, and skin-related quality of life scores were collected for up to 4 weeks after radiation treatment. Results: Patients who received cream 1 had a significantly lower average level of Common Terminology Criteria for Adverse Events at week 3 (P<.05) but had statistically higher average levels of skin toxicity at weeks 7, 8, and 9 (all P<.001). Similar results were observed when skin toxicity was analyzed by grades. With regards to pain, patients in the cream 2 group had a significantly higher average level of worst pain (P<.05) and itching (P=.046) compared with the cream 1 group at week 3; however, these differences were not observed at other weeks. In addition, there was a strong trend for cream 2 to reduce the incidence of grade 2 or more skin toxicity in comparison with cream 1 (P=.056). Overall, more participants in the cream 1 group were required to use another topical treatment at weeks 8 (P=.049) and 9 (P=.01). Conclusion: The natural oil-based emulsion containing allantoin seems to have similar effects for managing skin toxicity compared with aqueous cream up to week 5; however, it becomes significantly less effective at later weeks into the radiation treatment and beyond treatment completion (week 6 and beyond). There were no major differences in pain, itching, and skin-related quality of life. In light of these results, clinicians and patients can base their decision on costs and preferences. Overall, aqueous cream seems to be a more preferred option.

  1. Natural Oil-Based Emulsion Containing Allantoin Versus Aqueous Cream for Managing Radiation-Induced Skin Reactions in Patients With Cancer: A Phase 3, Double-Blind, Randomized, Controlled Trial

    International Nuclear Information System (INIS)

    Chan, Raymond Javan; Mann, Jennifer; Tripcony, Lee; Keller, Jacqui; Cheuk, Robyn; Blades, Rae; Keogh, Samantha; Poole, Christopher; Walsh, Christopher

    2014-01-01

    Purpose: To investigate the effects of a natural oil-based emulsion containing allantoin versus aqueous cream for preventing and managing radiation-induced skin reactions. Methods and Materials: A total of 174 patients were randomized and participated in the study. Patients received either cream 1 (the natural oil-based emulsion containing allantoin) or cream 2 (aqueous cream). Skin toxicity, pain, itching, and skin-related quality of life scores were collected for up to 4 weeks after radiation treatment. Results: Patients who received cream 1 had a significantly lower average level of Common Terminology Criteria for Adverse Events at week 3 (P<.05) but had statistically higher average levels of skin toxicity at weeks 7, 8, and 9 (all P<.001). Similar results were observed when skin toxicity was analyzed by grades. With regards to pain, patients in the cream 2 group had a significantly higher average level of worst pain (P<.05) and itching (P=.046) compared with the cream 1 group at week 3; however, these differences were not observed at other weeks. In addition, there was a strong trend for cream 2 to reduce the incidence of grade 2 or more skin toxicity in comparison with cream 1 (P=.056). Overall, more participants in the cream 1 group were required to use another topical treatment at weeks 8 (P=.049) and 9 (P=.01). Conclusion: The natural oil-based emulsion containing allantoin seems to have similar effects for managing skin toxicity compared with aqueous cream up to week 5; however, it becomes significantly less effective at later weeks into the radiation treatment and beyond treatment completion (week 6 and beyond). There were no major differences in pain, itching, and skin-related quality of life. In light of these results, clinicians and patients can base their decision on costs and preferences. Overall, aqueous cream seems to be a more preferred option

  2. Nucleon induced reactions

    International Nuclear Information System (INIS)

    Gmuca, S.; Antalik, R.; Kristiak, J.

    1988-01-01

    The collection contains full texts of 37 contributions; all fall within the INIS Subject Scope. The topics treated include some unsolved problems of nuclear reactions and relevant problems of nuclear structure at low and intermediate energies. (Z.S.)

  3. Light-Front Holography and the Light-Front Schrodinger Equation

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; de Teramond, Guy

    2012-08-15

    One of the most important nonperturbative methods for solving QCD is quantization at fixed light-front time {tau} = t+z=c - Dirac's 'Front Form'. The eigenvalues of the light-front QCD Hamiltonian predict the hadron spectrum and the eigensolutions provide the light-front wavefunctions which describe hadron structure. More generally, we show that the valence Fock-state wavefunctions of the light-front QCD Hamiltonian satisfy a single-variable relativistic equation of motion, analogous to the nonrelativistic radial Schrodinger equation, with an effective confining potential U which systematically incorporates the effects of higher quark and gluon Fock states. We outline a method for computing the required potential from first principles in QCD. The holographic mapping of gravity in AdS space to QCD, quantized at fixed light-front time, yields the same light front Schrodinger equation; in fact, the soft-wall AdS/QCD approach provides a model for the light-front potential which is color-confining and reproduces well the light-hadron spectrum. One also derives via light-front holography a precise relation between the bound-state amplitudes in the fifth dimension of AdS space and the boost-invariant light-front wavefunctions describing the internal structure of hadrons in physical space-time. The elastic and transition form factors of the pion and the nucleons are found to be well described in this framework. The light-front AdS/QCD holographic approach thus gives a frame-independent first approximation of the color-confining dynamics, spectroscopy, and excitation spectra of relativistic light-quark bound states in QCD.

  4. Statistical Physics and Light-Front Quantization

    Energy Technology Data Exchange (ETDEWEB)

    Raufeisen, J

    2004-08-12

    Light-front quantization has important advantages for describing relativistic statistical systems, particularly systems for which boost invariance is essential, such as the fireball created in a heavy ion collisions. In this paper the authors develop light-front field theory at finite temperature and density with special attention to quantum chromodynamics. They construct the most general form of the statistical operator allowed by the Poincare algebra and show that there are no zero-mode related problems when describing phase transitions. They then demonstrate a direct connection between densities in light-front thermal field theory and the parton distributions measured in hard scattering experiments. The approach thus generalizes the concept of a parton distribution to finite temperature. In light-front quantization, the gauge-invariant Green's functions of a quark in a medium can be defined in terms of just 2-component spinors and have a much simpler spinor structure than the equal-time fermion propagator. From the Green's function, the authors introduce the new concept of a light-front density matrix, whose matrix elements are related to forward and to off-diagonal parton distributions. Furthermore, they explain how thermodynamic quantities can be calculated in discretized light-cone quantization, which is applicable at high chemical potential and is not plagued by the fermion-doubling problems.

  5. Optimal back-to-front airplane boarding

    Science.gov (United States)

    Bachmat, Eitan; Khachaturov, Vassilii; Kuperman, Ran

    2013-06-01

    The problem of finding an optimal back-to-front airplane boarding policy is explored, using a mathematical model that is related to the 1+1 polynuclear growth model with concave boundary conditions and to causal sets in gravity. We study all airplane configurations and boarding group sizes. Optimal boarding policies for various airplane configurations are presented. Detailed calculations are provided along with simulations that support the main conclusions of the theory. We show that the effectiveness of back-to-front policies undergoes a phase transition when passing from lightly congested airplanes to heavily congested airplanes. The phase transition also affects the nature of the optimal or near-optimal policies. Under what we consider to be realistic conditions, optimal back-to-front policies lead to a modest 8-12% improvement in boarding time over random (no policy) boarding, using two boarding groups. Having more than two groups is not effective.

  6. Friction forces on phase transition fronts

    International Nuclear Information System (INIS)

    Mégevand, Ariel

    2013-01-01

    In cosmological first-order phase transitions, the microscopic interaction of the phase transition fronts with non-equilibrium plasma particles manifests itself macroscopically as friction forces. In general, it is a nontrivial problem to compute these forces, and only two limits have been studied, namely, that of very slow walls and, more recently, ultra-relativistic walls which run away. In this paper we consider ultra-relativistic velocities and show that stationary solutions still exist when the parameters allow the existence of runaway walls. Hence, we discuss the necessary and sufficient conditions for the fronts to actually run away. We also propose a phenomenological model for the friction, which interpolates between the non-relativistic and ultra-relativistic values. Thus, the friction depends on two friction coefficients which can be calculated for specific models. We then study the velocity of phase transition fronts as a function of the friction parameters, the thermodynamic parameters, and the amount of supercooling

  7. Optimal back-to-front airplane boarding.

    Science.gov (United States)

    Bachmat, Eitan; Khachaturov, Vassilii; Kuperman, Ran

    2013-06-01

    The problem of finding an optimal back-to-front airplane boarding policy is explored, using a mathematical model that is related to the 1+1 polynuclear growth model with concave boundary conditions and to causal sets in gravity. We study all airplane configurations and boarding group sizes. Optimal boarding policies for various airplane configurations are presented. Detailed calculations are provided along with simulations that support the main conclusions of the theory. We show that the effectiveness of back-to-front policies undergoes a phase transition when passing from lightly congested airplanes to heavily congested airplanes. The phase transition also affects the nature of the optimal or near-optimal policies. Under what we consider to be realistic conditions, optimal back-to-front policies lead to a modest 8-12% improvement in boarding time over random (no policy) boarding, using two boarding groups. Having more than two groups is not effective.

  8. Two RNAs or DNAs May Artificially Fuse Together at a Short Homologous Sequence (SHS) during Reverse Transcription or Polymerase Chain Reactions, and Thus Reporting an SHS-Containing Chimeric RNA Requires Extra Caution

    Science.gov (United States)

    Xie, Bingkun; Yang, Wei; Ouyang, Yongchang; Chen, Lichan; Jiang, Hesheng; Liao, Yuying; Liao, D. Joshua

    2016-01-01

    Tens of thousands of chimeric RNAs have been reported. Most of them contain a short homologous sequence (SHS) at the joining site of the two partner genes but are not associated with a fusion gene. We hypothesize that many of these chimeras may be technical artifacts derived from SHS-caused mis-priming in reverse transcription (RT) or polymerase chain reactions (PCR). We cloned six chimeric complementary DNAs (cDNAs) formed by human mitochondrial (mt) 16S rRNA sequences at an SHS, which were similar to several expression sequence tags (ESTs).These chimeras, which could not be detected with cDNA protection assay, were likely formed because some regions of the 16S rRNA are reversely complementary to another region to form an SHS, which allows the downstream sequence to loop back and anneal at the SHS to prime the synthesis of its complementary strand, yielding a palindromic sequence that can form a hairpin-like structure.We identified a 16S rRNA that ended at the 4th nucleotide(nt) of the mt-tRNA-leu was dominant and thus should be the wild type. We also cloned a mouse Bcl2-Nek9 chimeric cDNA that contained a 5-nt unmatchable sequence between the two partners, contained two copies of the reverse primer in the same direction but did not contain the forward primer, making it unclear how this Bcl2-Nek9 was formed and amplified. Moreover, a cDNA was amplified because one primer has 4 nts matched to the template, suggesting that there may be many more artificial cDNAs than we have realized, because the nuclear and mt genomes have many more 4-nt than 5-nt or longer homologues. Altogether, the chimeric cDNAs we cloned are good examples suggesting that many cDNAs may be artifacts due to SHS-caused mis-priming and thus greater caution should be taken when new sequence is obtained from a technique involving DNA polymerization. PMID:27148738

  9. PIV tracer behavior on propagating shock fronts

    International Nuclear Information System (INIS)

    Glazyrin, Fyodor N; Mursenkova, Irina V; Znamenskaya, Irina A

    2016-01-01

    The present work was aimed at the quantitative particle image velocimetry (PIV) measurement of a velocity field near the front of a propagating shock wave and the study of the dynamics of liquid tracers crossing the shock front. For this goal, a shock tube with a rectangular cross-section (48  ×  24 mm) was used. The flat shock wave with Mach numbers M  =  1.4–2.0 propagating inside the tube channel was studied as well as an expanding shock wave propagating outside the channel with M  =  1.2–1.8 at its main axis. The PIV imaging of the shock fronts was carried out with an aerosol of dioctyl sebacate (DEHS) as tracer particles. The pressures of the gas in front of the shock waves studied ranged from 0.013 Mpa to 0.1 MPa in the series of experiments. The processed PIV data, compared to the 1D normal shock theory, yielded consistent values of wake velocity immediately behind the plain shock wave. Special attention was paid to the blurring of the velocity jump on the shock front due to the inertial particle lag and peculiarities of the PIV technique. A numerical algorithm was developed for analysis and correction of the PIV data on the shock fronts, based on equations of particle-flow interaction. By application of this algorithm, the effective particle diameter of the DEHS aerosol tracers was estimated as 1.03  ±  0.12 μm. A number of different formulations for particle drag were tested with this algorithm, with varying success. The results show consistency with previously reported experimental data obtained for cases of stationary shock waves. (paper)

  10. Instability of an infiltration-driven dissolution-precipitation front with a nonmonotonic porosity profile

    Science.gov (United States)

    Kondratiuk, Paweł; Dutka, Filip; Szymczak, Piotr

    2016-04-01

    Infiltration of a rock by an external fluid very often drives it out of chemical equilibrium. As a result, alteration of the rock mineral composition occurs. It does not however proceed uniformly in the entire rock volume. Instead, one or more reaction fronts are formed, which are zones of increased chemical activity, separating the altered (product) rock from the yet unaltered (primary) one. The reaction fronts propagate with velocities which are usually much smaller than those of the infiltrating fluid. One of the simplest examples of such alteration is the dissolution of some of the minerals building the primary rock. For instance, calcium carbonate minerals in the rock matrix can be dissolved by infiltrating acidic fluids. In such a case the product rock has higher porosity and permeability than the primary one. Due to positive feedbacks between the reactant transport, fluid flow, and porosity generation, the reaction fronts in porosity-generating replacement systems are inherently unstable. An arbitrarily small protrusion of the front gets magnified and develops into a highly porous finger-like or funnel-like structure. This feature of dissolution fronts, dubbed the "reactive-infiltration instability" [1], is responsible for the formation of a number of geological patterns, such as solution pipes or various karst forms. It is also of practical importance, since spontaneous front breakup and development of localized highly porous flow paths (a.k.a. "wormholes") is favourable by petroleum engineers, who apply acidization to oil-bearing reservoirs in order to increase their permeability. However, more complex chemical reactions might occur during infiltration of a rock by a fluid. In principle, the products of dissolution might react with other species present either in the fluid or in the rock and reprecipitate [2]. The dissolution and precipitation fronts develop and and begin to propagate with equal velocities, forming a single dissolution-precipitation front

  11. RF front-end world class designs

    CERN Document Server

    Love, Janine

    2009-01-01

    All the design and development inspiration and direction a harware engineer needs in one blockbuster book! Janine Love site editor for RF Design Line,columnist, and author has selected the very best RF design material from the Newnes portfolio and has compiled it into this volume. The result is a book covering the gamut of RF front end design from antenna and filter design fundamentals to optimized layout techniques with a strong pragmatic emphasis. In addition to specific design techniques and practices, this book also discusses various approaches to solving RF front end design problems and h

  12. THREE PERSPECTIVES ON MANAGING FRONT END INNOVATION

    DEFF Research Database (Denmark)

    Jensen, Anna Rose Vagn; Clausen, Christian; Gish, Liv

    2018-01-01

    as a complementary perspective. The paper combines a literature review with an empirical examination of the application of these multiple perspectives across three cases of front end of innovation (FEI) management in mature product developing companies. While the process models represent the dominant, albeit rather...... to represent an emergent approach in managing FEI where process models, knowledge strategies and objects become integrated elements in more advanced navigational strategies for key players.......This paper presents three complementary perspectives on the management of front end innovation: A process model perspective, a knowledge perspective and a translational perspective. While the first two perspectives are well established in literature, we offer the translation perspective...

  13. TopN-Pareto Front Search

    Energy Technology Data Exchange (ETDEWEB)

    2016-12-21

    The JMP Add-In TopN-PFS provides an automated tool for finding layered Pareto front to identify the top N solutions from an enumerated list of candidates subject to optimizing multiple criteria. The approach constructs the N layers of Pareto fronts, and then provides a suite of graphical tools to explore the alternatives based on different prioritizations of the criteria. The tool is designed to provide a set of alternatives from which the decision-maker can select the best option for their study goals.

  14. Discretionary Power on the Front-line

    DEFF Research Database (Denmark)

    Sanden, Guro Refsum; Lønsmann, Dorte

    This article investigates the communication practices used by front-line employees to cross language boundaries in the context of English language policies implemented by the management of three multinational corporations (MNCs) headquartered in Scandinavia. Based on an analysis of interview...... and document data, our findings show that employees face a number of different language boundaries in their everyday work, and that ad hoc and informal solutions in many cases are vital for successful cross-language communication. We introduce the concept of ‘discretionary power’ to explain how and why front...

  15. Coping on the Front-line

    DEFF Research Database (Denmark)

    Sanden, Guro Refsum; Lønsmann, Dorte

    language boundaries in their everyday work. Despite official English language policies in the three companies, our findings show that employees face a number of different language boundaries, and that ad hoc and informal solutions in many cases are vital for successful cross-language communication. Drawing......This article investigates how front-line employees respond to English language policies implemented by the management of three multinational corporations (MNCs) headquartered in Scandinavia. Based on interview and document data the article examines the ways in which front-line employees cross...

  16. Discretionary power on the front-line

    DEFF Research Database (Denmark)

    Sanden, Guro Refsum; Lønsmann, Dorte

    2018-01-01

    This article investigates the communication practices used by front-line employees to cross language boundaries in the context of English language policies implemented by the management of three multinational corporations headquartered in Scandinavia. Based on an analysis of interview and document...... data, our findings show that employees face a number of different language boundaries in their everyday work, and that ad hoc and informal solutions in many cases are vital for successful cross-language communication. We introduce the concept of discretionary power to explain how and why front...

  17. Discretionary Power on the Front Line

    DEFF Research Database (Denmark)

    Sanden, Guro Refsum; Lønsmann, Dorte

    2018-01-01

    This paper investigates the communication practices used by front-line employees to cross language boundaries in the context of English language policies implemented by the management of three multinational corporations (MNCs) headquartered in Scandinavia. Based on an analysis of interview...... and document data, our findings show that employees face a number of different language boundaries in their everyday work, and that ad hoc and informal solutions in many cases are vital for successful cross-language communication. We introduce the concept of 'discretionary power' to explain how and why front...

  18. Pole solutions for flame front propagation

    CERN Document Server

    Kupervasser, Oleg

    2015-01-01

    This book deals with solving mathematically the unsteady flame propagation equations. New original mathematical methods for solving complex non-linear equations and investigating their properties are presented. Pole solutions for flame front propagation are developed. Premixed flames and filtration combustion have remarkable properties: the complex nonlinear integro-differential equations for these problems have exact analytical solutions described by the motion of poles in a complex plane. Instead of complex equations, a finite set of ordinary differential equations is applied. These solutions help to investigate analytically and numerically properties of the flame front propagation equations.

  19. Light-front nuclear shell-model

    International Nuclear Information System (INIS)

    Johnson, M.B.

    1990-01-01

    I examine the effects of nuclear structure on high-energy, high-momentum transfer processes, specifically the EMC effect. For pedagogical reasons, a fictitious but simple two-body system consisting of two equal-mass particles interacting in a harmonic oscillator potential has been chosen. For this toy nucleus, I utilize a widely-used link between instant-form and light-front dynamics, formulating nuclear structure and deep-inelastic scattering consistently in the laboratory system. Binding effects are compared within conventional instant-form and light-front dynamical frameworks, with appreciable differences being found in the two cases. 20 refs

  20. Deep reduced PEDOT films support electrochemical applications: Biomimetic color front.

    Directory of Open Access Journals (Sweden)

    Toribio Fernandez OTERO

    2015-02-01

    Full Text Available Most of the literature accepts, despite many controversial results, that during oxidation/reduction films of conducting polymers move from electronic conductors to insulators. Thus, engineers and device’s designers are forced to use metallic supports to reoxidize the material for reversible device work. Electrochromic front experiments appear as main visual support of the claimed insulating nature of reduced conducting polymers. Here we present a different design of the biomimetic electrochromic front that corroborates the electronic and ionic conducting nature of deep reduced films. The direct contact PEDOT metal/electrolyte and film/electrolyte was prevented from electrolyte contact until 1cm far from the metal contact with protecting Parafilm®. The deep reduced PEDOT film supports the flow of high currents promoting reaction induced electrochromic color changes beginning 1 cm far from the metal-polymer electrical contact and advancing, through the reduced film, towards the metal contact. Reverse color changes during oxidation/reduction always are initiated at the film/electrolyte contact advancing, under the protecting film, towards the film/metal contact. Both reduced and oxidized states of the film demonstrate electronic and ionic conductivities high enough to be used for electronic applications or, as self-supported electrodes, for electrochemical devices. The electrochemically stimulated conformational relaxation (ESCR model explains those results.

  1. A double-blind randomised controlled trial of a natural oil-based emulsion (Moogoo Udder Cream®) containing allantoin versus aqueous cream for managing radiation-induced skin reactions in patients with cancer.

    Science.gov (United States)

    Chan, Raymond Javan; Keller, Jacqui; Cheuk, Robyn; Blades, Rae; Tripcony, Lee; Keogh, Samantha

    2012-07-31

    Radiation-induced skin reaction (RISR) is one of the most common and distressing side effects of radiotherapy in patients with cancer. It is featured with swelling, redness, itching, pain, breaks in skin, discomfort, and a burning sensation. There is a lack of convincing evidence supporting any single practice in the prevention or management of RISR. This double-blinded randomised controlled trial aims to investigate the effects of a natural oil-based emulsion containing allantoin (as known as Moogoo Udder Cream®) versus aqueous cream in reducing RISR, improving pain, itching and quality of life in this patient group. One group will receive Moogoo Udder Cream®. Another group will receive aqueous cream. Outcome measures will be collected using patient self-administered questionnaire, interviewer administered questionnaire and clinician assessment at commencement of radiotherapy, weekly during radiotherapy, and four weeks after the completion of radiotherapy. Despite advances of radiologic advances and supportive care, RISR are still not well managed. There is a lack of efficacious interventions in managing RISR. While anecdotal evidence suggests that Moogoo Udder Cream® may be effective in managing RISR, research is needed to substantiate this claim. This paper presents the design of a double blind randomised controlled trial that will evaluate the effects of Moogoo Udder Cream® versus aqueous cream for managing in RISR in patients with cancer. ACTRN 12612000568819.

  2. A double-blind randomised controlled trial of a natural oil-based emulsion (Moogoo Udder Cream® containing allantoin versus aqueous cream for managing radiation-induced skin reactions in patients with cancer

    Directory of Open Access Journals (Sweden)

    Chan Raymond

    2012-07-01

    Full Text Available Abstract Background Radiation-induced skin reaction (RISR is one of the most common and distressing side effects of radiotherapy in patients with cancer. It is featured with swelling, redness, itching, pain, breaks in skin, discomfort, and a burning sensation. There is a lack of convincing evidence supporting any single practice in the prevention or management of RISR. Methods/Designs This double-blinded randomised controlled trial aims to investigate the effects of a natural oil-based emulsion containing allantoin (as known as Moogoo Udder Cream® versus aqueous cream in reducing RISR, improving pain, itching and quality of life in this patient group. One group will receive Moogoo Udder Cream®. Another group will receive aqueous cream. Outcome measures will be collected using patient self-administered questionnaire, interviewer administered questionnaire and clinician assessment at commencement of radiotherapy, weekly during radiotherapy, and four weeks after the completion of radiotherapy. Discussion Despite advances of radiologic advances and supportive care, RISR are still not well managed. There is a lack of efficacious interventions in managing RISR. While anecdotal evidence suggests that Moogoo Udder Cream® may be effective in managing RISR, research is needed to substantiate this claim. This paper presents the design of a double blind randomised controlled trial that will evaluate the effects of Moogoo Udder Cream® versus aqueous cream for managing in RISR in patients with cancer. Trial registration ACTRN 12612000568819

  3. A double-blind randomised controlled trial of a natural oil-based emulsion (Moogoo Udder Cream®) containing allantoin versus aqueous cream for managing radiation-induced skin reactions in patients with cancer

    International Nuclear Information System (INIS)

    Chan, Raymond Javan; Keller, Jacqui; Cheuk, Robyn; Blades, Rae; Tripcony, Lee; Keogh, Samantha

    2012-01-01

    Radiation-induced skin reaction (RISR) is one of the most common and distressing side effects of radiotherapy in patients with cancer. It is featured with swelling, redness, itching, pain, breaks in skin, discomfort, and a burning sensation. There is a lack of convincing evidence supporting any single practice in the prevention or management of RISR. This double-blinded randomised controlled trial aims to investigate the effects of a natural oil-based emulsion containing allantoin (as known as Moogoo Udder Cream®) versus aqueous cream in reducing RISR, improving pain, itching and quality of life in this patient group. One group will receive Moogoo Udder Cream®. Another group will receive aqueous cream. Outcome measures will be collected using patient self-administered questionnaire, interviewer administered questionnaire and clinician assessment at commencement of radiotherapy, weekly during radiotherapy, and four weeks after the completion of radiotherapy. Despite advances of radiologic advances and supportive care, RISR are still not well managed. There is a lack of efficacious interventions in managing RISR. While anecdotal evidence suggests that Moogoo Udder Cream® may be effective in managing RISR, research is needed to substantiate this claim. This paper presents the design of a double blind randomised controlled trial that will evaluate the effects of Moogoo Udder Cream® versus aqueous cream for managing in RISR in patients with cancer. ACTRN 12612000568819

  4. Diversity comparison of Pareto front approximations in many-objective optimization.

    Science.gov (United States)

    Li, Miqing; Yang, Shengxiang; Liu, Xiaohui

    2014-12-01

    Diversity assessment of Pareto front approximations is an important issue in the stochastic multiobjective optimization community. Most of the diversity indicators in the literature were designed to work for any number of objectives of Pareto front approximations in principle, but in practice many of these indicators are infeasible or not workable when the number of objectives is large. In this paper, we propose a diversity comparison indicator (DCI) to assess the diversity of Pareto front approximations in many-objective optimization. DCI evaluates relative quality of different Pareto front approximations rather than provides an absolute measure of distribution for a single approximation. In DCI, all the concerned approximations are put into a grid environment so that there are some hyperboxes containing one or more solutions. The proposed indicator only considers the contribution of different approximations to nonempty hyperboxes. Therefore, the computational cost does not increase exponentially with the number of objectives. In fact, the implementation of DCI is of quadratic time complexity, which is fully independent of the number of divisions used in grid. Systematic experiments are conducted using three groups of artificial Pareto front approximations and seven groups of real Pareto front approximations with different numbers of objectives to verify the effectiveness of DCI. Moreover, a comparison with two diversity indicators used widely in many-objective optimization is made analytically and empirically. Finally, a parametric investigation reveals interesting insights of the division number in grid and also offers some suggested settings to the users with different preferences.

  5. Light-Front Dynamics in Hadron Physics

    NARCIS (Netherlands)

    Ji, C.R.; Bakker, B.L.G.; Choi, H.M.

    2013-01-01

    Light-front dynamics(LFD) plays an important role in the analyses of relativistic few-body systems. As evidenced from the recent studies of generalized parton distributions (GPDs) in hadron physics, a natural framework for a detailed study of hadron structures is LFD due to its direct application in

  6. Positional Velar Fronting: An Updated Articulatory Account

    Science.gov (United States)

    Byun, Tara McAllister

    2012-01-01

    This study develops the hypothesis that the child-specific phenomenon of positional velar fronting can be modeled as the product of phonologically encoded articulatory limitations unique to immature speakers. Children have difficulty executing discrete tongue movements, preferring to move the tongue and jaw as a single unit. This predisposes the…

  7. QCD and Light-Front Holography

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; /SLAC /Southern Denmark U., CP3-Origins; de Teramond, Guy F.; /Costa Rica U.

    2010-10-27

    The soft-wall AdS/QCD model, modified by a positive-sign dilaton metric, leads to a remarkable one-parameter description of nonperturbative hadron dynamics. The model predicts a zero-mass pion for zero-mass quarks and a Regge spectrum of linear trajectories with the same slope in the leading orbital angular momentum L of hadrons and the radial quantum number N. Light-Front Holography maps the amplitudes which are functions of the fifth dimension variable z of anti-de Sitter space to a corresponding hadron theory quantized on the light front. The resulting Lorentz-invariant relativistic light-front wave equations are functions of an invariant impact variable {zeta} which measures the separation of the quark and gluonic constituents within the hadron at equal light-front time. The result is to a semi-classical frame-independent first approximation to the spectra and light-front wavefunctions of meson and baryon light-quark bound states, which in turn predict the behavior of the pion and nucleon form factors. The theory implements chiral symmetry in a novel way: the effects of chiral symmetry breaking increase as one goes toward large interquark separation, consistent with spectroscopic data, and the the hadron eigenstates generally have components with different orbital angular momentum; e.g., the proton eigenstate in AdS/QCD with massless quarks has L = 0 and L = 1 light-front Fock components with equal probability. The soft-wall model also predicts the form of the non-perturbative effective coupling {alpha}{sub s}{sup AdS} (Q) and its {beta}-function which agrees with the effective coupling {alpha}{sub g1} extracted from the Bjorken sum rule. The AdS/QCD model can be systematically improved by using its complete orthonormal solutions to diagonalize the full QCD light-front Hamiltonian or by applying the Lippmann-Schwinger method in order to systematically include the QCD interaction terms. A new perspective on quark and gluon condensates is also reviewed.

  8. Experimental investigation on depression mechanism of fly ash on progression of leaching alteration front

    International Nuclear Information System (INIS)

    Yamamoto, Takeshi; Hironaga, Michihiko

    2008-01-01

    An objective of this experimental study is to clarify the depression mechanism of fly ash on leaching alteration in hardened cementitious material. There are two major effects that derived from fly ash, firstly, compacting capillary pore among hydration phase with progression of pozzolanic reaction, secondly, lessen the crystal size and dispersing the location of CH crystal. Progression rate of CH alteration front depends on chain dissolution of CH crystal, so the depression on progressing rate of CH alteration front would be derived from the effects of fly ash as mentioned above. The influences of difference in amount of mixing water and sand on progression rate of CH alteration front in mortar would also be depressed by mixing fly ash. (author)

  9. Effects of ice melting and redox front migration in fractured rocks of low permeability

    Energy Technology Data Exchange (ETDEWEB)

    Guimera, J.; Duro, L.; Jordana, S.; Bruno, J. [QuantiSci, Barcelona (Spain)

    1999-09-01

    The geochemical stability of a KBS-3 type repository could be adversely affected by oxygenated water inflow during glaciation-deglaciation periods. We have assessed on a quantitative basis the extent and depth of such an oxidising front. This has been done by using limited regional groundwater flow schemes in combination with heterogeneous geochemical models. We consider that the consumption of oxidants under the soil cover will be governed by the reactions between groundwater and redox buffering minerals. The ability of the media to buffer an oxidant intrusion will be dominated by the presence of iron(II) bearing minerals such as chlorite, biotite and pyrite. We approach the problem under two perspectives: the equilibrium approach, where groundwater reaches equilibrium with Fe(II) containing minerals; and the kinetic approach, where the interaction between oxidants and the minerals is governed by kinetic rate laws. The results show that, while the equilibrium approach is applicable to groundwater systems with sufficiently long residence times, the kinetically controlled reactive transport gives more accurate results, provided that characteristic reaction times are longer than groundwater residence time. Multicomponent reactive transport results show that despite the input of melt waters from glacial origin, the ground-water system remains anoxic after periods of thousands of years for most of the scenarios and conceptual models considered. The redox state is governed by the presence of iron(II) in the system. We have performed a sensitivity analysis of the effects of varying the groundwater flow velocity, the available reactive surface and the presence of different Fe(H) minerals. The majority of the simulations indicate that the resulting geochemical composition of the system would not jeopardise the geochemical stability of the spent fuel, at repository depths. Consequently, the intrusion of melting ice water does not pose any threat to the chemical stability of

  10. Effects of ice melting and redox front migration in fractured rocks of low permeability

    International Nuclear Information System (INIS)

    Guimera, J.; Duro, L.; Jordana, S.; Bruno, J.

    1999-09-01

    The geochemical stability of a KBS-3 type repository could be adversely affected by oxygenated water inflow during glaciation-deglaciation periods. We have assessed on a quantitative basis the extent and depth of such an oxidising front. This has been done by using limited regional groundwater flow schemes in combination with heterogeneous geochemical models. We consider that the consumption of oxidants under the soil cover will be governed by the reactions between groundwater and redox buffering minerals. The ability of the media to buffer an oxidant intrusion will be dominated by the presence of iron(II) bearing minerals such as chlorite, biotite and pyrite. We approach the problem under two perspectives: the equilibrium approach, where groundwater reaches equilibrium with Fe(II) containing minerals; and the kinetic approach, where the interaction between oxidants and the minerals is governed by kinetic rate laws. The results show that, while the equilibrium approach is applicable to groundwater systems with sufficiently long residence times, the kinetically controlled reactive transport gives more accurate results, provided that characteristic reaction times are longer than groundwater residence time. Multicomponent reactive transport results show that despite the input of melt waters from glacial origin, the ground-water system remains anoxic after periods of thousands of years for most of the scenarios and conceptual models considered. The redox state is governed by the presence of iron(II) in the system. We have performed a sensitivity analysis of the effects of varying the groundwater flow velocity, the available reactive surface and the presence of different Fe(H) minerals. The majority of the simulations indicate that the resulting geochemical composition of the system would not jeopardise the geochemical stability of the spent fuel, at repository depths. Consequently, the intrusion of melting ice water does not pose any threat to the chemical stability of

  11. Effects of ice melting and redox front migration in low permeability media

    International Nuclear Information System (INIS)

    Guimera, J.; Duro, L.; Jordana, S.; Bruno, J.

    1998-01-01

    Migration of oxidising groundwater could adversely affect the ability of deep repository systems to limit radioelements releases to acceptable levels. Glaciation-deglaciation periods enhance the presence of deep oxidising water, thus jeopardizing stable chemical conditions of the repository over a long period. We assess in a quantitative basis the possibility of such oxidising front to happen, by using limited regional groundwater flow schemes with heterogenous models. We consider that the consumption of oxidants under the soil cover will be governed by the reactions between groundwater and redox buffering minerals. The ability of the media to buffer an oxidant intrusion will be dominated by the presence of iron(II) bearing minerals such as chlorite, biotite and pyrite. The ability of clays containing Fe(II) to act as oxidant sinks has been pointed out by several authors. Our study approaches the problem under two perspectives: equilibrium approach, where groundwater reaches equilibrium with minerals able to release Fe(II), and kinetic approach, where the interaction between oxidants and the minerals is not instantaneous, but governed by kinetic rate laws. Results show that, while the equilibrium approach is applicable whenever groundwater residence times are sufficiently long, kinetically controlled reactive transport gives more accurate results, provided that characteristic reaction times are longer than groundwater residence time. Multicomponent reactive transport results show that despite the glacial origin, groundwater remains anoxic after periods of thousands of years and the redox state is governed by the presence of iron in the system. We have performed a sensitivity analysis of the effects of varying the groundwater flow velocity, the available reactive surface and the presence of minerals. The majority of the simulations indicate that the resulting geochemical composition of the system would not jeopardize the stability of the spent fuel, at repository

  12. Performance of the front-end electronics of the ANTARES neutrino telescope

    NARCIS (Netherlands)

    Aguilar, J. A.; Al Samarai, I.; Albert, A.; Anghinolfi, M.; Anton, G.; Anvar, S.; Ardid, M.; Jesus, A. C. Assis; Astraatmadja, T.; Aubert, J-J; Auer, R.; Baret, B.; Basa, S.; Bazzotti, M.; Bertin, V.; Biagi, S.; Bigongiari, C.; Bou-Cabo, M.; Bouwhuis, M. C.; Brown, A.; Brunner, J.; Busto, J.; Camarena, F.; Capone, A.; Caponetto, L.; Carloganu, C.; Carminati, G.; Carr, J.; Castorina, E.; Cavasinni, V.; Cecchini, S.; Chaleil, Th; Charvis, [No Value; Chiarusi, T.; Sen, N. Chon; Circella, M.; Costantini, H.; Cottini, N.; Coyle, P.; Curtil, C.; De Bonis, G.; de Botton, N.; Dekeyser, I.; Delagnes, E.; Deschamps, A.; Distefano, C.; Donzaud, C.; Dornic, D.; Drouhin, D.; Druillole, F.; Eberl, T.; Emanuele, U.; Ernenwein, J-P; Escoffier, S.; Falchini, E.; Fehr, F.; Feinstein, F.; Flaminio, V.; Fopma, J.; Fratini, K.; Fritsch, U.; Fuda, J-L; Gay, P.; Giacomelli, G.; Gomez-Gonzalez, J. P.; Graf, K.; Guillard, G.; Halladjian, G.; Hallewell, G.; Hoffmann, C.; van Haren, H.; Heijboer, A. J.; Hello, Y.; Hernandez-Rey, J. J.; Herold, B.; Hoessl, J.; de Jong, M.; Kalantar-Nayestanaki, N.; Kalekin, O.; Kappes, A.; Katz, U.; Kooijman, P.; Kopper, C.; Kouchner, A.; Kretschmer, W.; Lachartre, D.; Lafoux, H.; Lahmann, R.; Lamare, P.; Lambard, G.; Larosa, G.; Laschinsky, H.; Le Provost, H.; Le Van Suu, A.; Lefevre, D.; Legou, T.; Lelaizant, G.; Lim, G.; Lo Presti, D.; Loehner, H.; Loucatos, S.; Lucarelli, F.; Mangano, S.; Marcelin, M.; Margiotta, A.; Martinez-Mora, J. A.; Mazure, A.; Monmarthe, E.; Montaruli, T.; Morganti, M.; Moscoso, L.; Motz, H.; Naumann, C.; Neff, M.; Olivetto, Ch; Ostasch, R.; Palioselitis, D.; Pavala, G. E.; Payre, P.; Petrovic, J.; Piattelli, P.; Picot-Clemente, N.; Picq, C.; Pineau, J-P; Poinsignon, J.; Popa, V.; Pradier, T.; Presani, E.; Racca, C.; Radu, A.; Reed, C.; Rethore, F.; Riccobene, G.; Richardt, C.; Rujoiu, M.; Russo, G. V.; Salesa, F.; Sapienza, P.; Schoeck, F.; Schuller, J. P.; Shanidze, R.; Simeone, F.; Spurio, M.; Steijger, J. J. M.; Stolarczyk, Th.; Tamburini, C.; Tasca, L.; Toscano, S.; Vallage, B.; Van Elewyck, V.; Vannoni, G.; Vecchi, M.; Vernin, P.; Wijnker, G.; de Wolf, E.; Yepes, H.; Zaborov, D.; Zornoza, J. D.; Zuniga, J.

    2010-01-01

    ANTARES is a high-energy neutrino telescope installed in the Mediterranean Sea at a depth of 2475 m. It consists of a three-dimensional array of optical modules, each containing a large photomultiplier tube. A total of 2700 front-end ASICs named analogue ring samplers (ARS) process the phototube

  13. Noncanonical Reactions of Flavoenzymes

    Directory of Open Access Journals (Sweden)

    Pablo Sobrado

    2012-11-01

    Full Text Available Enzymes containing flavin cofactors are predominantly involved in redox reactions in numerous cellular processes where the protein environment modulates the chemical reactivity of the flavin to either transfer one or two electrons. Some flavoenzymes catalyze reactions with no net redox change. In these reactions, the protein environment modulates the reactivity of the flavin to perform novel chemistries. Recent mechanistic and structural data supporting novel flavin functionalities in reactions catalyzed by chorismate synthase, type II isopentenyl diphosphate isomerase, UDP-galactopyranose mutase, and alkyl-dihydroxyacetonephosphate synthase are presented in this review. In these enzymes, the flavin plays either a direct role in acid/base reactions or as a nucleophile or electrophile. In addition, the flavin cofactor is proposed to function as a “molecular scaffold” in the formation of UDP-galactofuranose and alkyl-dihydroxyacetonephosphate by forming a covalent adduct with reaction intermediates.

  14. Meson Transition Form Factors in Light-Front Holographic QCD

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; /SLAC; Cao, Fu-Guang; /Massey U.; de Teramond, Guy F.; /Costa Rica U.

    2011-06-22

    We study the photon-to-meson transition form factors (TFFs) F{sub M{gamma}}(Q{sup 2}) for {gamma}{gamma}* {yields} M using light-front holographic methods. The Chern-Simons action, which is a natural form in 5-dimensional anti-de Sitter (AdS) space, leads directly to an expression for the photon-to-pion TFF for a class of confining models. Remarkably, the predicted pion TFF is identical to the leading order QCD result where the distribution amplitude has asymptotic form. The Chern-Simons form is local in AdS space and is thus somewhat limited in its predictability. It only retains the q{bar q} component of the pion wavefunction, and further, it projects out only the asymptotic form of the meson distribution amplitude. It is found that in order to describe simultaneously the decay process {pi}{sup 0} {yields} {gamma}{gamma} and the pion TFF at the asymptotic limit, a probability for the q{bar q} component of the pion wavefunction P{sub q{bar q}} = 0.5 is required; thus giving indication that the contributions from higher Fock states in the pion light-front wavefunction need to be included in the analysis. The probability for the Fock state containing four quarks (anti-quarks) which follows from analyzing the hadron matrix elements, P{sub q{bar q}q{bar q}} {approx} 10%, agrees with the analysis of the pion elastic form factor using light-front holography including higher Fock components in the pion wavefunction. The results for the TFFs for the {eta} and {eta}{prime} mesons are also presented. The rapid growth of the pion TFF exhibited by the BABAR data at high Q{sup 2} is not compatible with the models discussed in this article, whereas the theoretical calculations are in agreement with the experimental data for the {eta} and {eta}{prime} TFFs.

  15. Shielding container

    International Nuclear Information System (INIS)

    Darling, K.A.M.

    1981-01-01

    A shielding container incorporates a dense shield, for example of depleted uranium, cast around a tubular member of curvilinear configuration for accommodating a radiation source capsule. A lining for the tubular member, in the form of a close-coiled flexible guide, provides easy replaceability to counter wear while the container is in service. Container life is extended, and maintenance costs are reduced. (author)

  16. Propagating gene expression fronts in a one-dimensional coupled system of artificial cells

    Science.gov (United States)

    Tayar, Alexandra M.; Karzbrun, Eyal; Noireaux, Vincent; Bar-Ziv, Roy H.

    2015-12-01

    Living systems employ front propagation and spatiotemporal patterns encoded in biochemical reactions for communication, self-organization and computation. Emulating such dynamics in minimal systems is important for understanding physical principles in living cells and in vitro. Here, we report a one-dimensional array of DNA compartments in a silicon chip as a coupled system of artificial cells, offering the means to implement reaction-diffusion dynamics by integrated genetic circuits and chip geometry. Using a bistable circuit we programmed a front of protein synthesis propagating in the array as a cascade of signal amplification and short-range diffusion. The front velocity is maximal at a saddle-node bifurcation from a bistable regime with travelling fronts to a monostable regime that is spatially homogeneous. Near the bifurcation the system exhibits large variability between compartments, providing a possible mechanism for population diversity. This demonstrates that on-chip integrated gene circuits are dynamical systems driving spatiotemporal patterns, cellular variability and symmetry breaking.

  17. Reactor container

    International Nuclear Information System (INIS)

    Ichiki, Tadaharu; Saba, Kazuhisa.

    1979-01-01

    Purpose: To improve the earthquake resistance as well as reduce the size of a container for a nuclear reactor with no adverse effects on the decrease of impact shock to the container and shortening of construction step. Constitution: Reinforcing profile steel materials are welded longitudinally and transversely to the inner surface of a container, and inner steel plates are secured to the above profile steel materials while keeping a gap between the materials and the container. Reactor shielding wall planted to the base concrete of the container is mounted to the pressure vessel, and main steam pipeways secured by the transverse beams and led to the outside of container is connected. This can improve the rigidity earthquake strength and the safetiness against the increase in the inside pressure upon failures of the container. (Yoshino, Y.)

  18. Study of the violation of the T and CP symmetries in the reactions {lambda}{sub b}{sup 0} {yields} {lambda}{sup 0} + a vector meson. Validation of the Front-end electronics for the PreShower detector of the LHCb experiment; Recherche de la violation des symetries CP et T dans les reactions {lambda}{sub b}{sup 0} {yields} {lambda}{sup 0} + un meson vecteur. Validation de l'architecture de lecteur des canaux du detecteur de pied de gerbe de l'experience LHCb

    Energy Technology Data Exchange (ETDEWEB)

    Conte, E

    2007-11-15

    This thesis probes the beauty baryon physics in the framework of the LHCb experiment. The present study deals with the {lambda}{sub b}{sup 0} {yields} {lambda}{sup 0}V decays where V is a vector meson such as J/{psi}({mu}{sup +}{mu}{sup -}), {phi}(K{sup +}K{sup -}), {omega}({pi}{sup +}{pi}{sup -}{pi}0) or the {rho}{sup 0} - {omega}{sup 0}({pi}{sup +}{pi}{sup -}) mixing. These processes allow to test independently the CP symmetry, which violation has not been observed yet in the baryonic sector, and the T symmetry, which experimental proofs are limited. Among the possible perspectives, a precise measurement of the {lambda}{sub b}{sup 0} lifetime could contribute to the resolution of the raising theoretical-experimental puzzle. A phenomenological model of the {lambda}{sub b}{sup 0} {yields} {lambda}{sup 0}V decays has been performed, from which branching ratios and angular distributions have been estimated. An advanced study of the reconstruction and the selection of these reactions by the LHCb apparatus shows that the channel {lambda}{sub b}{sup 0} {yields} {lambda}{sup 0}J/{psi} is the dominant channel on both statistics and purity aspects. The {lambda}{sub b}{sup 0} lifetime measure is the most imminent result; the constrains on asymmetries due to CP and T violation require several data taking years. Besides, an instrumental work has been achieved on the read-out electronics, called Front-End, of the experiment pre-shower. This contribution takes into account the validation of the prototype boards and the development of tools required by the qualification of the 100 production boards. (author)

  19. Managing Controversies in the Fuzzy Front End

    DEFF Research Database (Denmark)

    Christiansen, John K.; Gasparin, Marta

    2016-01-01

    . The analysis investigates the microprocesses around the controversies that emerge during the fuzzy front end of four products. Five different types of controversies are identified: profit, production, design, brand and customers/market. Each controversy represents a threat, but also an opportunity to search...... for new solutions in the unpredictable non-linear processes. The study uses an ethnographic approach using qualitative data from interviews, company documents, external communication and marketing material, minutes of meetings, informal conversations and observations. The analysis of four FFE processes...... demonstrates how the fuzzy front requires managers to deal with controversies that emerge from many different places and involve both human and non-human actors. Closing the controversies requires managers to take account of the situation, identify the problem that needs to be addressed, and initiate a search...

  20. Multiclass gene selection using Pareto-fronts.

    Science.gov (United States)

    Rajapakse, Jagath C; Mundra, Piyushkumar A

    2013-01-01

    Filter methods are often used for selection of genes in multiclass sample classification by using microarray data. Such techniques usually tend to bias toward a few classes that are easily distinguishable from other classes due to imbalances of strong features and sample sizes of different classes. It could therefore lead to selection of redundant genes while missing the relevant genes, leading to poor classification of tissue samples. In this manuscript, we propose to decompose multiclass ranking statistics into class-specific statistics and then use Pareto-front analysis for selection of genes. This alleviates the bias induced by class intrinsic characteristics of dominating classes. The use of Pareto-front analysis is demonstrated on two filter criteria commonly used for gene selection: F-score and KW-score. A significant improvement in classification performance and reduction in redundancy among top-ranked genes were achieved in experiments with both synthetic and real-benchmark data sets.

  1. Trace metal fronts in European shelf waters

    International Nuclear Information System (INIS)

    Kremling, K.

    1983-01-01

    The Hebrides shelf edge area is characterized by strong horizontal salinity gradients (fronts) which mark the boundary between Scottish coastal and oceanic waters. The results presented here, obtained in summer 1981 on a transect between the open north Atlantic and the German Bight, confirm that the hydrographical front is accompanied by dramatic increases in inorganic nutrients (phosphate, silicate) and dissolved trace elements such as Cd, Cu, Mn, and 226 Ra. These data (together with measurements from North Sea regions) suggest that the trace metals are mobilized from partly reduced (organic-rich) sediments and vertically mixed into the surface waters. The regional variations evident from the transect are interpreted as being the result of the hydrography prevailing in waters around the British Isles. (author)

  2. Hybrid circuit prototypes for the CMS Tracker upgrade front-end electronics

    International Nuclear Information System (INIS)

    Blanchot, G; Honma, A; Kovacs, M; Braga, D; Raymond, M

    2013-01-01

    New high-density interconnect hybrid circuits are under development for the CMS tracker modules at the HL-LHC. These hybrids will provide module connectivity between flip-chip front-end ASICs, strip sensors and a service board for the data transmission and powering. Rigid organic-based substrate prototypes and also a flexible hybrid design have been built, containing up to eight front-end flip chip ASICs. A description of the function of the hybrid circuit in the tracker, the first prototype designs, results of some electrical and mechanical properties from the prototypes, and examples of the integration of the hybrids into detector modules are presented

  3. Prototype ALICE front-end card

    CERN Multimedia

    Maximilien Brice

    2004-01-01

    This circuit board is a prototype 48-channel front end digitizer card for the ALICE time projection chamber (TPC), which takes electrical signals from the wire sensors in the TPC and shapes the data before converting the analogue signal to digital data. A total of 4356 cards will be required to process the data from the ALICE TPC, the largest of this type of detector in the world.

  4. Front Cover Photograph & Interview for FREEYE Magazine

    OpenAIRE

    Murray, Matthew

    2003-01-01

    Matthew Murray Front Cover Photograph & Interview for FREEYE Magazine - Dutch Quarterly For Exceptional International Photography, Holland.\\ud The article focuses on Murray's practice, his personal work, commissioned work, advertising, gallery and exhibition work along with his methodology. Looking at Murray's inspirations and how they feed into his personal projects and how this personal work feeds into shooting above the line advertising campaigns. Murray's work blurs the lines between pers...

  5. Wave Front Sensor for Solar Concentrator Control

    Science.gov (United States)

    2009-10-01

    terrestrial-based and space-based. Both types of concentrator can be either imaging or nonimaging and they can be rigid or inflatable. Other...and T is the temperature of the absorber and propellant. In (5), Iin is input intensity with effects of the optical path through the concentrator acting...Hartmann in 1900 and was used for checking optical telescopes for aberrations. It was an array of holes in a plate placed in front of the mirror of

  6. Fronting and exhaustive exclusion in Biblical Hebrew

    African Journals Online (AJOL)

    Kate H

    48, 2017, 219-222 doi: 10.5774/48-0-292. Fronting and exhaustive exclusion in Biblical Hebrew. Christo H. J. van der Merwe. Department of Ancient Studies, University of Stellenbosch, South ... Merwe, Naudé and Kroeze 2017: 491-493). .... “And I will give him to the Lord all the days of his life, and no razor shall touch his.

  7. Kinetics of a plasma streamer ionization front

    Science.gov (United States)

    Taccogna, Francesco; Pellegrini, Fabrizio

    2018-02-01

    A streamer is a non-linear and non-local gas breakdown mode. Its large-scale coherent structures, such as the ionization front, are the final results of a hierarchical cascade starting from the single particle dynamics. Therefore, this phenomenon covers, by definition, different space and time scales. In this study, we have reproduced the ionization front formation and development by means of a particle-based numerical methodology. The physical system investigated concerns of a high-voltage ns-pulsed surface dielectric barrier discharge. Different reduced electric field regimes ranging from 50 to 500 Td have been considered for two gases: pure atomic Ar and molecular N2. Results have shown the detailed structure of the negative streamer: the leading edge, the head, the interior and the tail. Its dynamical evolution and the front propagation velocity have been calculated for the different cases. Finally, the deviation of the electron energy distribution function from equilibrium behavior has been pointed out as a result of a fast and very localized phenomenon.

  8. Reactor container

    International Nuclear Information System (INIS)

    Naruse, Yoshihiro.

    1990-01-01

    The thickness of steel shell plates in a reactor container embedded in sand cussions is monitored to recognize the corrosion of the steel shell plates. That is, the reactor pressure vessel is contained in a reactor container shell and the sand cussions are disposed on the lower outside of the reactor container shell to elastically support the shell. A pit is disposed at a position opposing to the sand cussions for measuring the thickness of the reactor container shell plates. The pit is usually closed by a closing member. In the reactor container thus constituted, the closing member can be removed upon periodical inspection to measure the thickness of the shell plates. Accordingly, the corrosion of the steel shell plates can be recognized by the change of the plate thickness. (I.S.)

  9. A container

    DEFF Research Database (Denmark)

    2012-01-01

    A container assembly for the containment of fluids or solids under a pressure different from the ambient pressure comprising a container (2) comprising an opening and an annular sealing, a lid (3) comprising a central portion (5) and engagement means (7) for engaging the annular flange, and sealing...... means (10) wherein the engagement means (7) is adapted, via the sealing means, to seal the opening when the pressure of the container assembly differs from the ambient pressure in such a way that the central portion (5) flexes in the axial direction which leads to a radial tightening of the engagement...... means (7) to the container, wherein the container further comprises locking means (12) that can be positioned so that the central portion is hindered from flexing in at least one direction....

  10. Shielded container

    International Nuclear Information System (INIS)

    Fries, B.A.

    1978-01-01

    A shielded container for transportation of radioactive materials is disclosed in which leakage from the container is minimized due to constructional features including, inter alia, forming the container of a series of telescoping members having sliding fits between adjacent side walls and having at least two of the members including machine sealed lids and at least two of the elements including hand-tightenable caps

  11. Wintertime sea surface temperature fronts in the Taiwan Strait

    Science.gov (United States)

    Chang, Yi; Shimada, Teruhisa; Lee, Ming-An; Lu, Hsueh-Jung; Sakaida, Futoki; Kawamura, Hiroshi

    2006-12-01

    We present wintertime variations and distributions of sea surface temperature (SST) fronts in the Taiwan Strait by applying an entropy-based edge detection method to 10-year (1996-2005) satellite SST images with grid size of 0.01°. From climatological monthly mean maps of SST gradient magnitude in winter, we identify four significant SST fronts in the Taiwan Strait. The Mainland China Coastal Front is a long frontal band along the 50-m isobath near the Chinese coast. The sharp Peng-Chang Front appears along the Peng-Hu Channel and extends northward around the Chang-Yuen Ridge. The Taiwan Bank Front evolves in early winter. As the winter progresses, the front becomes broad and moves toward the Chinese coast, connecting to the Mainland China Coastal Front. The Kuroshio Front extends northeastward from the northeastern tip of Taiwan with a semicircle-shape curving along the 100-m isobath.

  12. Bibliometric analysis of acupuncture research fronts and their ...

    African Journals Online (AJOL)

    Bibliometric analysis of acupuncture research fronts and their worldwide ... This study chronologically examined the changing features and research fronts of ... from the Science Citation Index Expanded and Social Science Citation Index.

  13. Experimental determination of primary and intermediate ions in a flame front

    Energy Technology Data Exchange (ETDEWEB)

    Fialkov, A.B.; Fialkov, B.S.

    1988-10-01

    A procedure is described for determining the primary and intermediate ions in the front of a flame rarefied using mass spectrometry. By using the method proposed here, primary CHO(+) and CHO2(+) ions as well as a series of short-lived intermediate ions have been identified. The possibility of using this method for obtaining quantitative data on the characteristic lifetimes of ions and rate constants of ion-molecular reactions in flames is demonstrated. 16 references.

  14. PMF: The front end electronic of the ALFA detector

    Energy Technology Data Exchange (ETDEWEB)

    Barrillon, P., E-mail: barrillo@lal.in2p3.f [Laboratoire de l' Accelerateur Lineaire, 91898 Orsay (France); Blin, S.; Cheikali, C.; Cuisy, D.; Gaspard, M.; Fournier, D.; Heller, M. [Laboratoire de l' Accelerateur Lineaire, 91898 Orsay (France); Iwanski, W. [Institute of Nuclear Physics PAN, Radzikowskiego 152, 31-342 Cracow (Poland); Lavigne, B.; De la Taille, C.; Puzo, P.; Socha, J-L. [Laboratoire de l' Accelerateur Lineaire, 91898 Orsay (France)

    2010-11-01

    The front end electronic (PMF) of the future ATLAS luminometer is described here. It is composed of a MAPMT and a compact stack of three PCBs, which deliver high voltage, route and read out of the output signals. The third board contains an FPGA and MAROC, a 64-channel ASIC, which can correct the non-uniformity of the MAPMT channels gain, thanks to a variable gain preamplifier. Its main role is to shape and discriminate the input signals at 1/3 photo-electron and produce 64 trigger outputs. Laboratory tests performed on prototype and pre-series PMFs have showed performances in good agreement with the requirements and have fulfilled the approval criteria for the final production of all elements.

  15. PMF: the front end electronic of the ALFA detector

    CERN Document Server

    Barrillon, P; Cheikali, C; Cuisy, D; Gaspard, M; Fournier, D; Heller, M; Iwanski, W; Lavigne, B; de La Taille, C; Puzo, P; Socha, J-L

    2010-01-01

    The front end electronic (PMF) of the future ATLAS luminometer is described here. It is composed of a MAPMT and a compact stack of three PCBs, which deliver high voltage, route and read out of the output signals. The third board contains an FPGA and MAROC, a 64-channel ASIC, which can correct the non-uniformity of the MAPMT channels gain, thanks to a variable gain preamplifier. Its main role is to shape and discriminate the input signals at 1/3 photo-electron and produce 64 trigger outputs. Laboratory tests performed on prototype and pre-series PMFs have showed performances in good agreement with the requirements and have fulfilled the approval criteria for the final production of all elements.

  16. Interstellar material in front of chi ophiuchi. I. Optical observations

    International Nuclear Information System (INIS)

    Frisch, P.C.

    1979-01-01

    Optical observations of the interstellar material in front of chi Oph are discussed. The main interstellar cloud is made up of several regions with velocities between -6 and -12 km s -1 (heliocentric). Both CH and CH + are found within this feature, but with central velocities which differ by 2 km s -1 . Another cloud, with a velocity of -26 km s -1 , contains relatively strong Ca + lines. It has a ratio between Ca + and Na 0 column densities that is appropriate for ''high-velocity'' clouds. Calcium, iron, and sodium column densities are used to estimate an average electron density for the line of sight as well as for each cloud. The abundances of CH and CH + , and the absence of CN, are analyzed in terms of current theories about their origin

  17. Measurement of Design Process Front-End – Radical Innovation Approach

    DEFF Research Database (Denmark)

    Berg, Pekka; Pihlajamaa, Jussi; Hansen, Poul H. Kyvsgård

    2014-01-01

    The overall structure and the main characteristics of the future product are all decided in the front-end phase, which then strongly affects subsequent new product development activities. Recent studies indicate that these early front-end activities represent the most troublesome phase...... of the innovation process, and at the same time one of the greatest opportunities to improve the overall innovation capability of a company. In this paper dealing with the criteria we concentrate only for the objectives viewpoint and leave the attributes discussion to the future research. Two most crucial questions...... the innovation activities front end contains five assessment viewpoints as follows; input, process, output (including impacts), social environment and structural environment. Based on the results from our first managerial implications in three Finnish manufacturing companies we argue, that the developed model...

  18. Nuclear reactions

    International Nuclear Information System (INIS)

    Lane, A.M.

    1980-01-01

    In reviewing work at Harwell over the past 25 years on nuclear reactions it is stated that a balance has to be struck in both experiment and theory between work on cross-sections of direct practical relevance to reactors and on those relevant to an overall understanding of reaction processes. The compound nucleus and direct process reactions are described. Having listed the contributions from AERE, Harwell to developments in nuclear reaction research in the period, work on the optical model, neutron capture theory, reactions at doorway states with fine structure, and sum-rules for spectroscopic factors are considered in more detail. (UK)

  19. Sleeve reaction chamber system

    Science.gov (United States)

    Northrup, M Allen [Berkeley, CA; Beeman, Barton V [San Mateo, CA; Benett, William J [Livermore, CA; Hadley, Dean R [Manteca, CA; Landre, Phoebe [Livermore, CA; Lehew, Stacy L [Livermore, CA; Krulevitch, Peter A [Pleasanton, CA

    2009-08-25

    A chemical reaction chamber system that combines devices such as doped polysilicon for heating, bulk silicon for convective cooling, and thermoelectric (TE) coolers to augment the heating and cooling rates of the reaction chamber or chambers. In addition the system includes non-silicon-based reaction chambers such as any high thermal conductivity material used in combination with a thermoelectric cooling mechanism (i.e., Peltier device). The heat contained in the thermally conductive part of the system can be used/reused to heat the device, thereby conserving energy and expediting the heating/cooling rates. The system combines a micromachined silicon reaction chamber, for example, with an additional module/device for augmented heating/cooling using the Peltier effect. This additional module is particularly useful in extreme environments (very hot or extremely cold) where augmented heating/cooling would be useful to speed up the thermal cycling rates. The chemical reaction chamber system has various applications for synthesis or processing of organic, inorganic, or biochemical reactions, including the polymerase chain reaction (PCR) and/or other DNA reactions, such as the ligase chain reaction.

  20. Topology optimization of front metallization patterns for solar cells

    NARCIS (Netherlands)

    Gupta, D.K.; Langelaar, M.; Barink, M.; Keulen, F. van

    2015-01-01

    This paper presents the application of topology optimization (TO) for designing the front electrode patterns for solar cells. Improving the front electrode design is one of the approaches to improve the performance of the solar cells. It serves to produce the voltage distribution for the front

  1. Reactor container

    International Nuclear Information System (INIS)

    Fukazawa, Masanori.

    1991-01-01

    A system for controlling combustible gases, it has been constituted at present such that the combustible gases are controlled by exhausting them to the wet well of a reactor container. In this system, however, there has been a problem, in a reactor container having plenums in addition to the wet well and the dry well, that the combustible gases in such plenums can not be controlled. In view of the above, in the present invention, suction ports or exhaust ports of the combustible gas control system are disposed to the wet well, the dry well and the plenums to control the combustible gases in the reactor container. Since this can control the combustible gases in the entire reactor container, the integrity of the reactor container can be ensured. (T.M.)

  2. Reactor containment

    International Nuclear Information System (INIS)

    Kawabe, Ryuhei; Yamaki, Rika.

    1990-01-01

    A water vessel is disposed and the gas phase portion of the water vessel is connected to a reactor container by a pipeline having a valve disposed at the midway thereof. A pipe in communication with external air is extended upwardly from the liquid phase portion to a considerable height so as to resist against the back pressure by a waterhead in the pipeline. Accordingly, when the pressure in the container is reduced to a negative level, air passes through the pipeline and uprises through the liquid phase portion in the water vessel in the form of bubbles and then flows into the reactor container. When the pressure inside of the reactor goes higher, since the liquid surface in the water vessel is forced down, water is pushed up into the pipeline. Since the waterhead pressure of a column of water in the pipeline and the pressure of the reactor container are well-balanced, gases in the reactor container are not leaked to the outside. Further, in a case if a great positive pressure is formed in the reactor container, the inner pressure overcomes the waterhead of the column of water, so that the gases containing radioactive aerosol uprise in the pipeline. Since water and the gases flow being in contact with each other, this can provide the effect of removing aerosol. (T.M.)

  3. Sharps container

    Science.gov (United States)

    Lee, Angelene M. (Inventor)

    1992-01-01

    This invention relates to a system for use in disposing of potentially hazardous items and more particularly a Sharps receptacle for used hypodermic needles and the like. A Sharps container is constructed from lightweight alodined nonmagnetic metal material with a cup member having an elongated tapered shape and length greater than its transverse dimensions. A magnet in the cup member provides for metal retention in the container. A nonmagnetic lid member has an opening and spring biased closure flap member. The flap member is constructed from stainless steel. A Velcro patch on the container permits selective attachment at desired locations.

  4. Novel Perspectives from Light-Front QCD, Super-Conformal Algebra, and Light-Front Holography

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-12-01

    Light-Front Quantization – Dirac’s “Front Form” – provides a physical, frame-independent formalism for hadron dynamics and structure. Observables such as structure functions, transverse momentum distributions, and distribution amplitudes are defined from the hadronic LFWFs. One obtains new insights into the hadronic mass scale, the hadronic spectrum, and the functional form of the QCD running coupling in the nonperturbative domain using light-front holography. In addition, superconformal algebra leads to remarkable supersymmetric relations between mesons and baryons. I also discuss evidence that the antishadowing of nuclear structure functions is nonuniversal; i.e., flavor dependent, and why shadowing and antishadowing phenomena may be incompatible with the momentum and other sum rules for the nuclear parton distribution functions.

  5. Front panel human interface for FASTBUS

    International Nuclear Information System (INIS)

    Gustavson, D.B.; Holmes, T.L.; Paffrath, L.; Steffani, J.P.

    1980-01-01

    A human interface based on the Snoop diagnostic module has been designed to facilitate checkout of FASTBUS devices, diagnosis of system faults, and monitoring of system performance. This system, which is a generalization of the usual computer front panel or control console, includes logic analyzer functions, display and manual-control access to other modules, a microprocessor which allows the user to create and execute diagnostic programs and store them on a minifloppy disk, and a diagnostic network which allows remote console operation and coordination of information from multiple segments' Snoops

  6. Vinyl ethers, containing isothiocyanate group. 12. Reaction of 2-vinyloxyethylisothiocyanate with metallated ethoxyethene, methoxyalline and 2-alkynes: 2,3-disubstituted N-(2-vinyloxyethyl) pyrroles and 6-(vinyloxymethyl)-5,6-dihydropyridines

    International Nuclear Information System (INIS)

    Nedolya, N.A.; Brandsma, L.; Zinov'eva, V.P.; Trofimov, B.A.

    1997-01-01

    New route of synthesis of 1,2,3-trisubstituted pyrroles and 2,3,6-trisubstituted 5,6-dyhydropyridines by the reaction of lithiated alkoxyallenes and 2-alkynes with 2-vinyloxyethylisothiocyanate is found. It is shown that key intermediates are 1,3,4-azatrienes. Reaction of metallized ethoxyethene with 2-vinyloxyethyisothiocyanate (after intermediate alkylation) results in 1-(2-vinyloxyethyl)-1,3-azadiene

  7. Light-Front Holography, Light-Front Wavefunctions, and Novel QCD Phenomena

    DEFF Research Database (Denmark)

    Brodsky, S. J.; de Teramond, G. F.

    2012-01-01

    Light-front holography is one of the most remarkable features of the AdS/CFT correspondence. In spite of its present limitations, it provides important physical insights into the non-perturbative regime of QCD and its transition to the perturbative domain. This novel framework allows hadronic...... projected on the free Fock basis provides the complete set of valence and non-valence light-front Fock state wavefunctions Psi(n)/H(x(i), k(perpendicular to i), lambda(i)) which describe the hadron's momentum and spin distributions needed to compute the direct measures of hadron structure at the quark...

  8. Lightweight flywheel containment

    Science.gov (United States)

    Smith, James R.

    2004-06-29

    A lightweight flywheel containment composed of a combination of layers of various material which absorb the energy of a flywheel structural failure. The various layers of material act as a vacuum barrier, momentum spreader, energy absorber, and reaction plate. The flywheel containment structure has been experimentally demonstrated to contain carbon fiber fragments with a velocity of 1,000 m/s and has an aerial density of less than 6.5 g/square centimeters. The flywheel containment, may for example, be composed of an inner high toughness structural layer, and energy absorbing layer, and an outer support layer. Optionally, a layer of impedance matching material may be utilized intermediate the flywheel rotor and the inner high toughness layer.

  9. Syntactic and FSP Aspects of Fronting as a Style Marker

    Directory of Open Access Journals (Sweden)

    Libuše Dušková

    2017-07-01

    Full Text Available The paper examines contextual and emphatic fronting in academic prose, fiction narrative and fiction dialogue in order to ascertain whether the types of fronting can serve as a style marker. The differences in the distribution and their effect on style are assumed to be connected with the respective FSP structures: in emphatic fronting the fronted element is the rheme, whereas in contextual fronting it is the diatheme. Hence emphatic fronting displays a prominent deviation from the basic distribution of communicative dynamism, whereas contextual fronting achieves agreement with it. As compared with the unmarked postverbal ordering, emphatic fronting intensifies the emphatic/emotional character of the content being expressed, which is a feature of speech, while contextual fronting serves as a direct link with what precedes, hence contributes to textual cohesion, which is a characteristic of academic prose, with fiction narrative presumably occupying an intermediate position. The results of the study show more types of fronting with diversified structures and less clear-cut relations between the types of frontings and the examined text sorts.

  10. Reaction mechanisms of metal complexes

    CERN Document Server

    Hay, R W

    2000-01-01

    This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanis...

  11. Automated Detection of Fronts using a Deep Learning Convolutional Neural Network

    Science.gov (United States)

    Biard, J. C.; Kunkel, K.; Racah, E.

    2017-12-01

    A deeper understanding of climate model simulations and the future effects of global warming on extreme weather can be attained through direct analyses of the phenomena that produce weather. Such analyses require these phenomena to be identified in automatic, unbiased, and comprehensive ways. Atmospheric fronts are centrally important weather phenomena because of the variety of significant weather events, such as thunderstorms, directly associated with them. In current operational meteorology, fronts are identified and drawn visually based on the approximate spatial coincidence of a number of quasi-linear localized features - a trough (relative minimum) in air pressure in combination with gradients in air temperature and/or humidity and a shift in wind, and are categorized as cold, warm, stationary, or occluded, with each type exhibiting somewhat different characteristics. Fronts are extended in space with one dimension much larger than the other (often represented by complex curved lines), which poses a significant challenge for automated approaches. We addressed this challenge by using a Deep Learning Convolutional Neural Network (CNN) to automatically identify and classify fronts. The CNN was trained using a "truth" dataset of front locations identified by National Weather Service meteorologists as part of operational 3-hourly surface analyses. The input to the CNN is a set of 5 gridded fields of surface atmospheric variables, including 2m temperature, 2m specific humidity, surface pressure, and the two components of the 10m horizontal wind velocity vector at 3-hr resolution. The output is a set of feature maps containing the per - grid cell probabilities for the presence of the 4 front types. The CNN was trained on a subset of the data and then used to produce front probabilities for each 3-hr time snapshot over a 14-year period covering the continental United States and some adjacent areas. The total frequencies of fronts derived from the CNN outputs matches

  12. Internal waves and temperature fronts on slopes

    Directory of Open Access Journals (Sweden)

    S. A. Thorpe

    Full Text Available Time series measurements from an array of temperature miniloggers in a line at constant depth along the sloping boundary of a lake are used to describe the `internal surf zone' where internal waves interact with the sloping boundary. More small positive temperature time derivatives are recorded than negative, but there are more large negative values than positive, giving the overall distribution of temperature time derivatives a small negative skewness. This is consistent with the internal wave dynamics; fronts form during the up-slope phase of the motion, bringing cold water up the slope, and the return flow may become unstable, leading to small advecting billows and weak warm fronts. The data are analysed to detect `events', periods in which the temperature derivatives exceed a set threshold. The speed and distance travelled by `events' are described. The motion along the slope may be a consequence of (a instabilities advected by the flow (b internal waves propagating along-slope or (c internal waves approaching the slope from oblique directions. The propagation of several of the observed 'events' can only be explained by (c, evidence that the internal surf zone has some, but possibly not all, the characteristics of the conventional 'surface wave' surf zone, with waves steepening as they approach the slope at oblique angles.

    Key words. Oceanography: general (benthic boundary layers; limnology, Oceanography: physical (internal and inertial waves

  13. Biomechanics of front and back squat exercises

    International Nuclear Information System (INIS)

    Braidot, A A; Brusa, M H; Lestussi, F E; Parera, G P

    2007-01-01

    Squat constitutes one of the most popular exercises to strengthen the muscles of the lower limbs. It is considered one of the most widely spread exercises for muscle sport training and is part of the competition movements comprised within olympic weight-lifting. In physical rehabilitation, squats are used for muscular recovery after different injuries of the lower limbs, especially the knee. In previous anterior cruciate ligament injuries, the mini-squats are generally used, in a knee flexion motion range from 0 deg. to 50 deg. because in this range the shear forces, the tibiofemoral and patellofemoral compression forces decrease related to greater flexion angles. The aim of this work is to make a comparative bidimensional study of the kinematic and dynamic variables of the excecution of the parallel squat exercise with the front and back bar. It is observed in the knee a better development of energy with the front bar, allowing a better muscular exercise with the same load. The mean power absorbed by the hip with the back bar is considerably greater, associated to the speed of the gesture

  14. Travelling fronts in stochastic Stokes’ drifts

    KAUST Repository

    Blanchet, Adrien

    2008-10-01

    By analytical methods we study the large time properties of the solution of a simple one-dimensional model of stochastic Stokes\\' drift. Semi-explicit formulae allow us to characterize the behaviour of the solutions and compute global quantities such as the asymptotic speed of the center of mass or the effective diffusion coefficient. Using an equivalent tilted ratchet model, we observe that the speed of the center of mass converges exponentially to its limiting value. A diffuse, oscillating front attached to the center of mass appears. The description of the front is given using an asymptotic expansion. The asymptotic solution attracts all solutions at an algebraic rate which is determined by the effective diffusion coefficient. The proof relies on an entropy estimate based on homogenized logarithmic Sobolev inequalities. In the travelling frame, the macroscopic profile obeys to an isotropic diffusion. Compared with the original diffusion, diffusion is enhanced or reduced, depending on the regime. At least in the limit cases, the rate of convergence to the effective profile is always decreased. All these considerations allow us to define a notion of efficiency for coherent transport, characterized by a dimensionless number, which is illustrated on two simple examples of travelling potentials with a sinusoidal shape in the first case, and a sawtooth shape in the second case. © 2008 Elsevier B.V. All rights reserved.

  15. Biomechanics of front and back squat exercises

    Energy Technology Data Exchange (ETDEWEB)

    Braidot, A A [Laboratorio de Biomecanica FI-UNER. Ruta 11 Km 10 Oro Verde Entre Rios (Argentina); Brusa, M H [Laboratorio de Biomecanica FI-UNER. Ruta 11 Km 10 Oro Verde Entre Rios (Argentina); Lestussi, F E [Laboratorio de Biomecanica FI-UNER. Ruta 11 Km 10 Oro Verde Entre Rios (Argentina); Parera, G P [Licenciatura en KinesiologIa y FisiatrIa Universidad Abierta Interamericana. Sede Regional Rosario (Argentina)

    2007-11-15

    Squat constitutes one of the most popular exercises to strengthen the muscles of the lower limbs. It is considered one of the most widely spread exercises for muscle sport training and is part of the competition movements comprised within olympic weight-lifting. In physical rehabilitation, squats are used for muscular recovery after different injuries of the lower limbs, especially the knee. In previous anterior cruciate ligament injuries, the mini-squats are generally used, in a knee flexion motion range from 0 deg. to 50 deg. because in this range the shear forces, the tibiofemoral and patellofemoral compression forces decrease related to greater flexion angles. The aim of this work is to make a comparative bidimensional study of the kinematic and dynamic variables of the excecution of the parallel squat exercise with the front and back bar. It is observed in the knee a better development of energy with the front bar, allowing a better muscular exercise with the same load. The mean power absorbed by the hip with the back bar is considerably greater, associated to the speed of the gesture.

  16. Biomechanics of front and back squat exercises

    Science.gov (United States)

    Braidot, A. A.; Brusa, M. H.; Lestussi, F. E.; Parera, G. P.

    2007-11-01

    Squat constitutes one of the most popular exercises to strengthen the muscles of the lower limbs. It is considered one of the most widely spread exercises for muscle sport training and is part of the competition movements comprised within olympic weight-lifting. In physical rehabilitation, squats are used for muscular recovery after different injuries of the lower limbs, especially the knee. In previous anterior cruciate ligament injuries, the mini-squats are generally used, in a knee flexion motion range from 0° to 50° because in this range the shear forces, the tibiofemoral and patellofemoral compression forces decrease related to greater flexion angles. The aim of this work is to make a comparative bidimensional study of the kinematic and dynamic variables of the excecution of the parallel squat exercise with the front and back bar. It is observed in the knee a better development of energy with the front bar, allowing a better muscular exercise with the same load. The mean power absorbed by the hip with the back bar is considerably greater, associated to the speed of the gesture.

  17. Tracer filamentation at an unstable ocean front

    Science.gov (United States)

    Feng, Yen Chia; Mahadevan, Amala; Thiffeault, Jean-Luc; Yecko, Philip

    2017-11-01

    A front, where two bodies of ocean water with different physical properties meet, can become unstable and lead to a flow with high strain rate and vorticity. Phytoplankton and other oceanic tracers are stirred into filaments by such flow fields, as can often be seen in satellite imagery. The stretching and folding of a tracer by a two-dimensional flow field has been well studied. In the ocean, however, the vertical shear of horizontal velocity is typically two orders of magnitude larger than the horizontal velocity gradient. Theoretical calculations show that vertical shear alters the way in which horizontal strain affects the tracer, resulting in thin, sloping structures in the tracer field. Using a non-hydrostatic ocean model of an unstable ocean front, we simulate tracer filamentation to identify the effect of vertical shear on the deformation of the tracer. In a complementary laboratory experiment, we generate a simple, vertically sheared strain flow and use dye and particle image velocimetry to quantify the filamentary structures in terms of the strain and shear. We identify how vertical shear alters the tracer filaments and infer how the evolution of tracers in the ocean will differ from the idealized two-dimensional paradigm. Support of NSF DMS-1418956 is acknowledged.

  18. Analytically solvable models of reaction-diffusion systems

    Energy Technology Data Exchange (ETDEWEB)

    Zemskov, E P; Kassner, K [Institut fuer Theoretische Physik, Otto-von-Guericke-Universitaet, Universitaetsplatz 2, 39106 Magdeburg (Germany)

    2004-05-01

    We consider a class of analytically solvable models of reaction-diffusion systems. An analytical treatment is possible because the nonlinear reaction term is approximated by a piecewise linear function. As particular examples we choose front and pulse solutions to illustrate the matching procedure in the one-dimensional case.

  19. Spatially hybrid computations for streamer discharges with generic features of pulled fronts: I. Planar fronts

    International Nuclear Information System (INIS)

    Li Chao; Ebert, Ute; Hundsdorfer, Willem

    2010-01-01

    Streamers are the first stage of sparks and lightning; they grow due to a strongly enhanced electric field at their tips; this field is created by a thin curved space charge layer. These multiple scales are already challenging when the electrons are approximated by densities. However, electron density fluctuations in the leading edge of the front and non-thermal stretched tails of the electron energy distribution (as a cause of X-ray emissions) require a particle model to follow the electron motion. But present computers cannot deal with all electrons in a fully developed streamer. Therefore, super-particle have to be introduced, which leads to wrong statistics and numerical artifacts. The method of choice is a hybrid computation in space where individual electrons are followed in the region of high electric field and low density while the bulk of the electrons is approximated by densities (or fluids). We here develop the hybrid coupling for planar fronts. First, to obtain a consistent flux at the interface between particle and fluid model in the hybrid computation, the widely used classical fluid model is replaced by an extended fluid model. Then the coupling algorithm and the numerical implementation of the spatially hybrid model are presented in detail, in particular, the position of the model interface and the construction of the buffer region. The method carries generic features of pulled fronts that can be applied to similar problems like large deviations in the leading edge of population fronts, etc.

  20. The International intraval project. Phase 1, case 7. The Pocos de Caldas natural analogue: studies of redox front movement

    International Nuclear Information System (INIS)

    Chapman, N.

    1992-01-01

    The study of natural analogues is an important means of validating models of the geochemical processes affecting radionuclide behaviour. This test case, which is one aspect taken from the much broader geochemical studies carried out in the Pocos de Caldas Project, concerns the nature and behaviour of redox fronts, such as might be generated in the near-field of a spent-fuel repository. A redox front is potentially important in terms of the movements and speciation of certain radionuclides close to the waste package. The natural redox fronts in Osamu Utsumi uranium mine display many of the features which may occur in a repository, and influence the movement of natural series radionuclides, and other elements, through the rock/groundwater system. This report, describes the geological, hydrogeological and geochemical nature of the site, and of the redox fronts. Emphasis is placed on the mineralogy of the fronts, and the concentration profiles of various elements across them. The project involved a number of different modelling approaches which attempted to describe the generation and movement of the fronts through the rock. These included mass balance, reaction-diffusion models, fissure flow models, thermodynamic models, and kinetic models. 21 refs., 36 figs., 1 tab

  1. Impact of Added Sugar Information of Front-of-Pack Labels on Consumers’ Beverage Health Perception Changes

    OpenAIRE

    Kim, Hyeyoung; House, Lisa

    2012-01-01

    This study examined the effect of Front-of-package (FOP) labels with voluntary and mandatory disclosure of added sugar levels for beverages on consumer perceptions of how healthy the beverages are. Three groups of beverages were investigated: 1) 100% fruit juice (containing sugar but no added sugar); 2) sugar-sweetened beverages (containing sugar and added sugar); and 3) diet soft drink (containing no sugar). In general, added sugar information seems to play an important role in perception of...

  2. Front-end electronics for the Muon Portal project

    Energy Technology Data Exchange (ETDEWEB)

    Garozzo, S.; Marano, D.; Bonanno, G.; Grillo, A.; Romeo, G.; Timpanaro, M.C. [INAF, Osservatorio Astrofisico di Catania, Via S. Sofia 78, I-95123 Catania (Italy); Lo Presti, D.; Riggi, F.; Russo, V.; Bonanno, D.; La Rocca, P.; Longhitano, F.; Bongiovanni, D.G. [Università di Catania, Dipartimento di Fisica e Astronomia, and INFN, Sezione di Catania, Via S. Sofia 64, I-95123 Catania (Italy); Fallica, G.; Valvo, G. [ST-Microelectronics, Stradale V Primosole 50, Catania (Italy)

    2016-10-11

    The Muon Portal Project was born as a joint initiative between Italian research and industrial partners, aimed at the construction of a real-size working detector prototype to inspect the content of traveling containers by means of secondary cosmic-ray muon radiation and recognize potentially dangerous hidden materials. The tomographic image is obtained by reconstructing the incoming and outgoing muon trajectories when crossing the inspected volume, employing two tracker planes located above and below the container under inspection. In this paper, the design and development of the front-end electronics of the Muon Portal detector is presented, with particular emphasis being devoted to the photo-sensor devices detecting the scintillation light and to the read-out circuitry which is in charge of processing and digitizing the analog pulse signals. In addition, the remote control system, mechanical housing, and thermal cooling system of all structural blocks of the Muon Portal tracker are also discussed, demonstrating the effectiveness and functionality of the adopted design.

  3. Vector mesons on the light front

    International Nuclear Information System (INIS)

    Naito, K.; Maedan, S.; Itakura, K.

    2004-01-01

    We apply the light-front quantization to the Nambu-Jona-Lasinio model with the vector interaction, and compute vector meson's mass and light-cone wavefunction in the large N limit. Following the same procedure as in the previous analyses for scalar and pseudo-scalar mesons, we derive the bound-state equations of a qq-bar system in the vector channel. We include the lowest order effects of the vector interaction. The resulting transverse and longitudinal components of the bound-state equation look different from each other. But eventually after imposing an appropriate cutoff, one finds these two are identical, giving the same mass and the same (spin-independent) light-cone wavefunction. Mass of the vector meson decreases as one increases the strength of the vector interaction

  4. Light-front quantization of field theory

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, Prem P. [Universidade do Estado, Rio de Janeiro, RJ (Brazil). Inst. de Fisica]|[Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil)

    1996-07-01

    Some basic topics in Light-Front (LF) quantized field theory are reviewed. Poincare algebra and the LF spin operator are discussed. The local scalar field theory of the conventional framework is shown to correspond to a non-local Hamiltonian theory on the LF in view of the constraint equations on the phase space, which relate the bosonic condensates to the non-zero modes. This new ingredient is useful to describe the spontaneous symmetry breaking on the LF. The instability of the symmetric phase in two dimensional scalar theory when the coupling constant grows is shown in the LF theory renormalized to one loop order. Chern-Simons gauge theory, regarded to describe excitations with fractional statistics, is quantized in the light-cone gauge and a simple LF Hamiltonian obtained which may allow us to construct renormalized theory of anyons. (author). 20 refs.

  5. Light-front quantization of field theory

    International Nuclear Information System (INIS)

    Srivastava, Prem P.

    1996-07-01

    Some basic topics in Light-Front (LF) quantized field theory are reviewed. Poincare algebra and the LF spin operator are discussed. The local scalar field theory of the conventional framework is shown to correspond to a non-local Hamiltonian theory on the LF in view of the constraint equations on the phase space, which relate the bosonic condensates to the non-zero modes. This new ingredient is useful to describe the spontaneous symmetry breaking on the LF. The instability of the symmetric phase in two dimensional scalar theory when the coupling constant grows is shown in the LF theory renormalized to one loop order. Chern-Simons gauge theory, regarded to describe excitations with fractional statistics, is quantized in the light-cone gauge and a simple LF Hamiltonian obtained which may allow us to construct renormalized theory of anyons. (author). 20 refs

  6. The CMS Tracker Readout Front End Driver

    CERN Document Server

    Foudas, C.; Ballard, D.; Church, I.; Corrin, E.; Coughlan, J.A.; Day, C.P.; Freeman, E.J.; Fulcher, J.; Gannon, W.J.F.; Hall, G.; Halsall, R.N.J.; Iles, G.; Jones, J.; Leaver, J.; Noy, M.; Pearson, M.; Raymond, M.; Reid, I.; Rogers, G.; Salisbury, J.; Taghavi, S.; Tomalin, I.R.; Zorba, O.

    2004-01-01

    The Front End Driver, FED, is a 9U 400mm VME64x card designed for reading out the Compact Muon Solenoid, CMS, silicon tracker signals transmitted by the APV25 analogue pipeline Application Specific Integrated Circuits. The FED receives the signals via 96 optical fibers at a total input rate of 3.4 GB/sec. The signals are digitized and processed by applying algorithms for pedestal and common mode noise subtraction. Algorithms that search for clusters of hits are used to further reduce the input rate. Only the cluster data along with trigger information of the event are transmitted to the CMS data acquisition system using the S-LINK64 protocol at a maximum rate of 400 MB/sec. All data processing algorithms on the FED are executed in large on-board Field Programmable Gate Arrays. Results on the design, performance, testing and quality control of the FED are presented and discussed.

  7. Light-Front Holography, Light-Front Wavefunctions, and Novel QCD Phenomena

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; /SLAC /Southern Denmark U., CP3-Origins; de Teramond, Guy F.; /Costa Rica U.

    2012-02-16

    Light-Front Holography is one of the most remarkable features of the AdS/CFT correspondence. In spite of its present limitations it provides important physical insights into the nonperturbative regime of QCD and its transition to the perturbative domain. This novel framework allows hadronic amplitudes in a higher dimensional anti-de Sitter (AdS) space to be mapped to frame-independent light-front wavefunctions of hadrons in physical space-time. The model leads to an effective confining light-front QCD Hamiltonian and a single-variable light-front Schroedinger equation which determines the eigenspectrum and the light-front wavefunctions of hadrons for general spin and orbital angular momentum. The coordinate z in AdS space is uniquely identified with a Lorentz-invariant coordinate {zeta} which measures the separation of the constituents within a hadron at equal light-front time and determines the off-shell dynamics of the bound-state wavefunctions, and thus the fall-off as a function of the invariant mass of the constituents. The soft-wall holographic model modified by a positive-sign dilaton metric, leads to a remarkable one-parameter description of nonperturbative hadron dynamics - a semi-classical frame-independent first approximation to the spectra and light-front wavefunctions of meson and baryons. The model predicts a Regge spectrum of linear trajectories with the same slope in the leading orbital angular momentum L of hadrons and the radial quantum number n. The hadron eigensolutions projected on the free Fock basis provides the complete set of valence and non-valence light-front Fock state wavefunctions {Psi}{sub n/H} (x{sub i}, k{sub {perpendicular}i}, {lambda}{sub i}) which describe the hadron's momentum and spin distributions needed to compute the direct measures of hadron structure at the quark and gluon level, such as elastic and transition form factors, distribution amplitudes, structure functions, generalized parton distributions and transverse

  8. Quasielastic reactions

    International Nuclear Information System (INIS)

    Henning, W.

    1979-01-01

    Quasielastic reaction studies, because of their capability to microscopically probe nuclear structure, are still of considerable interest in heavy-ion reactions. The recent progress in understanding various aspects of the reaction mechanism make this aim appear closer. The relation between microscopic and macroscopic behavior, as suggested, for example, by the single proton transfer data to individual final states or averaged excitation energy intervals, needs to be explored. It seems particularly useful to extend measurements to higher incident energies, to explore and understand nuclear structure aspects up to the limit of the energy range where they are important

  9. Salinity fronts in the tropical Pacific Ocean.

    Science.gov (United States)

    Kao, Hsun-Ying; Lagerloef, Gary S E

    2015-02-01

    This study delineates the salinity fronts (SF) across the tropical Pacific, and describes their variability and regional dynamical significance using Aquarius satellite observations. From the monthly maps of the SF, we find that the SF in the tropical Pacific are (1) usually observed around the boundaries of the fresh pool under the intertropical convergence zone (ITCZ), (2) stronger in boreal autumn than in other seasons, and (3) usually stronger in the eastern Pacific than in the western Pacific. The relationship between the SF and the precipitation and the surface velocity are also discussed. We further present detailed analysis of the SF in three key tropical Pacific regions. Extending zonally around the ITCZ, where the temperature is nearly homogeneous, we find the strong SF of 1.2 psu from 7° to 11°N to be the main contributor of the horizontal density difference of 0.8 kg/m 3 . In the eastern Pacific, we observe a southward extension of the SF in the boreal spring that could be driven by both precipitation and horizontal advection. In the western Pacific, the importance of these newly resolved SF associated with the western Pacific warm/fresh pool and El Niño southern oscillations are also discussed in the context of prior literature. The main conclusions of this study are that (a) Aquarius satellite salinity measurements reveal the heretofore unknown proliferation, structure, and variability of surface salinity fronts, and that (b) the fine-scale structures of the SF in the tropical Pacific yield important new information on the regional air-sea interaction and the upper ocean dynamics.

  10. Uranium fixation by mineralization at the redox front

    International Nuclear Information System (INIS)

    Isobe, Hiroshi

    1998-01-01

    The behavior of actinide elements including uranium in geomedia is controlled by redox conditions. Under the oxidized conditions, uranium forms uranyl ion (UO 2 2+ ) and its complexes, and dissolves in ground water. Under the reduced conditions, U(IV) has much lower solubility than uranyl ion. In the Koongarra uranium deposit, Australia, lead-bearing uraninite, uranyl lead oxide and uranyl silicate minerals occur in the unweathered, primary ore zone, and uranyl phosphate minerals occur in the weathered, secondary ore zone. Between unweathered and weathered zones, the transition zone exists as a redox front. In the transition zone, graphite and sulfide minerals react as reducing agents for species dissolved in ground water. By SEM, spherical grains of uraninite were observed in veins with graphite. Pyrite had coffinite rim with crystals of uraninite. Calculation based on the ground water chemistry and hydrology at Koongarra shows that the uranium in the transition zone may be fixed from the ground water. In the Koongarra transition zone, recent mineralization of uranium by reduction takes place. Mineralization is much stronger fixation mechanism than adsorption on clay minerals. Pyrite in the buffer materials of possible radioactive waste repositories can fix radionuclides in oxidized ground water by mineralization with reducing reactions. (author)

  11. On microscopic simulations of systems with model chemical reactions

    International Nuclear Information System (INIS)

    Gorecki, J.; Gorecka, J.N.

    1998-01-01

    Large scale computer simulations of model chemical systems play the role of idealized experiments in which theories may be tested. In this paper we present two applications of microscopic simulations based on the reactive hard sphere model. We investigate the influence of internal fluctuations on an oscillating chemical system and observe how they modify the phase portrait of it. Another application, we consider, is concerned with the propagation of a chemical wave front associated with a thermally activated reaction. It is shown that the nonequilibrium effects increase the front velocity if compared with the velocity of the front generated by a nonactivated process characterized by the same rate constant. (author)

  12. Reactor container

    International Nuclear Information System (INIS)

    Furukawa, Hideyasu; Oyamada, Osamu; Uozumi, Hiroto.

    1976-01-01

    Purpose: To provide a container for a reactor provided with a pressure suppressing chamber pool which can prevent bubble vibrating load, particularly negative pressure generated at the time of starting to release exhaust from a main steam escape-safety valve from being transmitted to a lower liner plate of the container. Constitution: This arrangement is characterized in that a safety valve exhaust pool for main steam escape, in which a pressure suppressing chamber pool is separated and intercepted from pool water in the pressure suppressing chamber pool, a safety valve exhaust pipe is open into said safety valve exhaust pool, and an isolator member, which isolates the bottom liner plate in the pressure suppressing chamber pool from the pool water, is disposed on the bottom of the safety valve exhaust pool. (Nakamura, S.)

  13. Rabbit System. Low cost, high reliability front end electronics featuring 16 bit dynamic range

    International Nuclear Information System (INIS)

    Drake, G.; Droege, T.F.; Nelson, C.A. Jr.; Turner, K.J.; Ohska, T.K.

    1985-10-01

    A new crate-based front end system has been built which features low cost, compact packaging, command capability, 16 bit dynamic range digitization, and a high degree of redundancy. The crate can contain a variety of instrumentation modules, and is designed to be situated close to the detector. The system is suitable for readout of a large number of channels via parallel multiprocessor data acquisition

  14. CONTAIN calculations

    International Nuclear Information System (INIS)

    Scholtyssek, W.

    1995-01-01

    In the first phase of a benchmark comparison, the CONTAIN code was used to calculate an assumed EPR accident 'medium-sized leak in the cold leg', especially for the first two days after initiation of the accident. The results for global characteristics compare well with those of FIPLOC, MELCOR and WAVCO calculations, if the same materials data are used as input. However, significant differences show up for local quantities such as flows through leakages. (orig.)

  15. MMIC front-ends for optical communication systems

    DEFF Research Database (Denmark)

    Petersen, Anders Kongstad

    1993-01-01

    Two different types of optical front-end MMIC amplifiers for a 2.5-Gb/s coherent heterodyne optical receiver are presented. A bandwidth of 6-12 GHz has been obtained for a tuned front-end and 3-13 GHz for a distributed front-end. An input noise current density of 5-15 pA/√Hz has been obtained for...

  16. The upgraded CDF front end electronics for calorimetry

    Energy Technology Data Exchange (ETDEWEB)

    Drake, G.; Frei, D.; Hahn, S.R.; Nelson, C.A.; Segler, S.L.; Stuermer, W.

    1991-11-01

    The front end electronics used in the calorimetry of the CDF detector has been upgraded to meet system requirements for higher expected luminosity. A fast digitizer utilizing a 2 {mu}Sec, 16 bit ADC has been designed and built. Improvements to the front end trigger circuitry have been implemented, including the production of 900 new front end modules. Operational experience with the previous system is presented, with discussion of the problems and performance goals.

  17. The upgraded CDF front end electronics for calorimetry

    International Nuclear Information System (INIS)

    Drake, G.; Frei, D.; Hahn, S.R.; Nelson, C.A.; Segler, S.L.; Stuermer, W.

    1991-11-01

    The front end electronics used in the calorimetry of the CDF detector has been upgraded to meet system requirements for higher expected luminosity. A fast digitizer utilizing a 2 μSec, 16 bit ADC has been designed and built. Improvements to the front end trigger circuitry have been implemented, including the production of 900 new front end modules. Operational experience with the previous system is presented, with discussion of the problems and performance goals

  18. Reactor container

    International Nuclear Information System (INIS)

    Kato, Masami; Nishio, Masahide.

    1987-01-01

    Purpose: To prevent the rupture of the dry well even when the melted reactor core drops into a reactor pedestal cavity. Constitution: In a reactor container in which a dry well disposed above the reactor pedestal cavity for containing the reactor pressure vessel and a torus type suppression chamber for containing pressure suppression water are connected with each other, the pedestal cavity and the suppression chamber are disposed such that the flow level of the pedestal cavity is lower than the level of the pressure suppression water. Further, a pressure suppression water introduction pipeway for introducing the pressure suppression water into the reactor pedestal cavity is disposed by way of an ON-OFF valve. In case if the melted reactor core should fall into the pedestal cavity, the ON-OFF valve for the pressure suppression water introduction pipeway is opened to introduce the pressure suppression water in the suppression chamber into the pedestal cavity to cool the melted reactor core. (Ikeda, J.)

  19. Plasma container

    International Nuclear Information System (INIS)

    Ebisawa, Katsuyuki.

    1985-01-01

    Purpose: To enable to easily detect that the thickness of material to be abraded is reduced to an allowable limit from the outerside of the plasma container even during usual operation in a plasma vessel for a thermonuclear device. Constitution: A labelled material is disposed to the inside or rear face of constituent members of a plasma container undergoing the irradiation of plasma particles. A limiter plate to be abraded in the plasma container is composed of an armour member and heat removing plate, in which the armour member is made of graphite and heat-removing plate is made of copper. If the armour member is continuously abraded under the effect of sputtering due to plasma particles, silicon nitride embedded so far in the graphite at last appears on the surface of the limiter plate to undergo the impact shocks of the plasma particles. Accordingly, abrasion of the limiter material can be detected by a detector comprising gas chromatography and it can easily be detected from the outside of the plasma content even during normal operation. (Horiuchi, T.)

  20. Reactor container

    International Nuclear Information System (INIS)

    Shibata, Satoru; Kawashima, Hiroaki

    1984-01-01

    Purpose: To optimize the temperature distribution of the reactor container so as to moderate the thermal stress distribution on the reactor wall of LMFBR type reactor. Constitution: A good heat conductor (made of Al or Cu) is appended on the outer side of the reactor container wall from below the liquid level to the lower face of a deck plate. Further, heat insulators are disposed to the outside of the good heat conductor. Furthermore, a gas-cooling duct is circumferentially disposed at the contact portion between the good heat conductor and the deck plate around the reactor container. This enables to flow the cold heat from the liquid metal rapidly through the good heat conductor to the cooling duct and allows to maintain the temperature distribution on the reactor wall substantially linear even with the abrupt temperature change in the liquid metal. Further, by appending the good heat conductor covered with inactive metals not only on the outer side but also on the inside of the reactor wall to introduce the heat near the liquid level to the upper portion and escape the same to the cooling layer below the roof slab, the effect can be improved further. (Ikeda, J.)

  1. cycloaddition reactions

    Indian Academy of Sciences (India)

    Unknown

    Molecular Modeling Group, Organic Chemical Sciences, Indian Institute of Chemical Technology,. Hyderabad ... thus obtained are helpful to model the regioselectivity ... compromise to model Diels–Alder reactions involving ...... acceptance.

  2. Application of deep convolutional neural networks for ocean front recognition

    Science.gov (United States)

    Lima, Estanislau; Sun, Xin; Yang, Yuting; Dong, Junyu

    2017-10-01

    Ocean fronts have been a subject of study for many years, a variety of methods and algorithms have been proposed to address the problem of ocean fronts. However, all these existing ocean front recognition methods are built upon human expertise in defining the front based on subjective thresholds of relevant physical variables. This paper proposes a deep learning approach for ocean front recognition that is able to automatically recognize the front. We first investigated four existing deep architectures, i.e., AlexNet, CaffeNet, GoogLeNet, and VGGNet, for the ocean front recognition task using remote sensing (RS) data. We then propose a deep network with fewer layers compared to existing architecture for the front recognition task. This network has a total of five learnable layers. In addition, we extended the proposed network to recognize and classify the front into strong and weak ones. We evaluated and analyzed the proposed network with two strategies of exploiting the deep model: full-training and fine-tuning. Experiments are conducted on three different RS image datasets, which have different properties. Experimental results show that our model can produce accurate recognition results.

  3. Propagation of Reactions in Thermally-damaged PBX-9501

    Energy Technology Data Exchange (ETDEWEB)

    Tringe, J W; Glascoe, E A; Kercher, J R; Willey, T M; Springer, H K; Greenwood, D W; Molitoris, J D; Smilowitz, L; Henson, B F; Maienschein, J L

    2010-03-05

    A thermally-initiated explosion in PBX-9501 (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) is observed in situ by flash x-ray imaging, and modeled with the LLNL multi-physics arbitrary-Lagrangian-Eulerian code ALE3D. The containment vessel deformation provides a useful estimate of the reaction pressure at the time of the explosion, which we calculate to be in the range 0.8-1.4 GPa. Closely-coupled ALE3D simulations of these experiments, utilizing the multi-phase convective burn model, provide detailed predictions of the reacted mass fraction and deflagration front acceleration. During the preinitiation heating phase of these experiments, the solid HMX portion of the PBX-9501 undergoes a {beta}-phase to {delta}-phase transition which damages the explosive and induces porosity. The multi-phase convective burn model results demonstrate that damaged particle size and pressure are critical for predicting reaction speed and violence. In the model, energetic parameters are taken from LLNL's thermochemical-kinetics code Cheetah and burn rate parameters from Son et al. (2000). Model predictions of an accelerating deflagration front are in qualitative agreement with the experimental images assuming a mode particle diameter in the range 300-400 {micro}m. There is uncertainty in the initial porosity caused by thermal damage of PBX-9501 and, thus, the effective surface area for burning. To better understand these structures, we employ x-ray computed tomography (XRCT) to examine the microstructure of PBX-9501 before and after thermal damage. Although lack of contrast between grains and binder prevents the determination of full grain size distribution in this material, there are many domains visible in thermally damaged PBX-9501 with diameters in the 300-400 {micro}m range.

  4. Bifurcating fronts for the Taylor-Couette problem in infinite cylinders

    Science.gov (United States)

    Hărăguş-Courcelle, M.; Schneider, G.

    We show the existence of bifurcating fronts for the weakly unstable Taylor-Couette problem in an infinite cylinder. These fronts connect a stationary bifurcating pattern, here the Taylor vortices, with the trivial ground state, here the Couette flow. In order to show the existence result we improve a method which was already used in establishing the existence of bifurcating fronts for the Swift-Hohenberg equation by Collet and Eckmann, 1986, and by Eckmann and Wayne, 1991. The existence proof is based on spatial dynamics and center manifold theory. One of the difficulties in applying center manifold theory comes from an infinite number of eigenvalues on the imaginary axis for vanishing bifurcation parameter. But nevertheless, a finite dimensional reduction is possible, since the eigenvalues leave the imaginary axis with different velocities, if the bifurcation parameter is increased. In contrast to previous work we have to use normalform methods and a non-standard cut-off function to obtain a center manifold which is large enough to contain the bifurcating fronts.

  5. Development of Novel Front Contract Pastes for Crystalline Silicon Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Duty, C.; Jellison, D. G.E. P.; Joshi, P.

    2012-04-05

    In order to improve the efficiencies of silicon solar cells, paste to silicon contact formation mechanisms must be more thoroughly understood as a function of paste chemistry, wafer properties and firing conditions. Ferro Corporation has been involved in paste development for over 30 years and has extensive expertise in glass and paste formulations. This project has focused on the characterization of the interface between the top contact material (silver paste) and the underlying silicon wafer. It is believed that the interface between the front contact silver and the silicon wafer plays a dominant role in the electrical performance of the solar cell. Development of an improved front contact microstructure depends on the paste chemistry, paste interaction with the SiNx, and silicon (“Si”) substrate, silicon sheet resistivity, and the firing profile. Typical front contact ink contains silver metal powders and flakes, glass powder and other inorganic additives suspended in an organic medium of resin and solvent. During fast firing cycles glass melts, wets, corrodes the SiNx layer, and then interacts with underlying Si. Glass chemistry is also a critical factor in the development of an optimum front contact microstructure. Over the course of this project, several fundamental characteristics of the Ag/Si interface were documented, including a higher-than-expected distribution of voids along the interface, which could significantly impact electrical conductivity. Several techniques were also investigated for the interfacial analysis, including STEM, EDS, FIB, EBSD, and ellipsometry.

  6. Ingesting a pre-workout supplement containing caffeine, B-vitamins, amino acids, creatine, and beta-alanine before exercise delays fatigue while improving reaction time and muscular endurance

    Directory of Open Access Journals (Sweden)

    Spradley Brandon D

    2012-03-01

    Full Text Available Abstract Background The purpose of this study was to determine the effects of the pre-workout supplement Assault™ (MusclePharm, Denver, CO, USA on upper and lower body muscular endurance, aerobic and anaerobic capacity, and choice reaction time in recreationally-trained males. Subjective feelings of energy, fatigue, alertness, and focus were measured to examine associations between psychological factors and human performance. Methods Twelve recreationally-trained males participated in a 3-week investigation (mean +/- SD, age: 28 +/- 5 y, height: 178 +/- 9 cm, weight: 79.2 +/- 15.7 kg, VO2max: 45.7 +/- 7.6 ml/kg/min. Subjects reported to the human performance laboratory on three separate occasions. All participants completed a baseline/familiarization day of testing that included a maximal graded exercise test for the determination of aerobic capacity (VO2max, one-rep maximum (1-RM for bench and leg press to determine 75% of 1-RM, choice reaction tests, and intermittent critical velocity familiarization. Choice reaction tests included the following: single-step audio and visual, one-tower stationary protocol, two-tower lateral protocol, three-tower multi-directional protocol, and three-tower multi-directional protocol with martial arts sticks. Subjects were randomly assigned to ingest either the supplement (SUP or the placebo (PL during Visit 2. Subjects were provided with the cross-over treatment on the last testing visit. Testing occurred 20 min following ingestion of both treatments. Results Significant (p Conclusions Ingesting the SUP before exercise significantly improved agility choice reaction performance and lower body muscular endurance, while increasing perceived energy and reducing subjective fatigue. These findings suggest that the SUP may delay fatigue during strenuous exercise.

  7. CONTAIN calculations; CONTAIN-Rechnungen

    Energy Technology Data Exchange (ETDEWEB)

    Scholtyssek, W.

    1995-08-01

    In the first phase of a benchmark comparison, the CONTAIN code was used to calculate an assumed EPR accident `medium-sized leak in the cold leg`, especially for the first two days after initiation of the accident. The results for global characteristics compare well with those of FIPLOC, MELCOR and WAVCO calculations, if the same materials data are used as input. However, significant differences show up for local quantities such as flows through leakages. (orig.)

  8. Reactor container

    International Nuclear Information System (INIS)

    Hidaka, Masataka; Hatamiya, Shigeo; Kawasaki, Terufumi; Fukui, Toru; Suzuki, Hiroaki; Kataoka, Yoshiyuki; Kawabe, Ryuhei; Murase, Michio; Naito, Masanori.

    1990-01-01

    In order to suppress the pressure elevation in a reactor container due to high temperature and high pressure steams jetted out upon pipeway rupture accidents in the reactor container, the steams are introduced to a pressure suppression chamber for condensating them in stored coolants. However, the ability for suppressing the pressure elevation and steam coagulation are deteriorated due to the presence of inactive incondensible gases. Then, there are disposed a vent channel for introducing the steams in a dry well to a pressure suppression chamber in the reactor pressure vessel, a closed space disposed at the position lower than a usual liquid level, a first channel having an inlet in the pressure suppression chamber and an exit in the closed space and a second means connected by way of a backflow checking means for preventing the flow directing to the closed space. The first paths are present by plurality, a portion of which constitutes a syphon. The incondensible gases and the steams are discharged to the dry well at high pressure by using the difference of the water head for a long cooling time after the pipeway rupture accident. Then, safety can be improved without using dynamic equipments as driving source. (N.H.)

  9. Direct Reactions

    Energy Technology Data Exchange (ETDEWEB)

    Austern, N. [University of Pittsburgh, Pittsburgh, PA (United States)

    1963-01-15

    In order to give a unified presentation of one point of view, these lectures are devoted only to a detailed development of the standard theories of direct reactions, starting from basic principles. Discussion is given of the present status of the theories, of the techniques used for practical calculation, and of possible future developments. The direct interaction (DI) aspects of a reaction are those which involve only a few of the many degrees of freedom of a nucleus. In fact the minimum number of degrees of freedom which must be involved in a reaction are those required to describe the initial and final channels, and DI studies typically consider these degrees of freedom and no others. Because of this simplicity DI theories may be worked out in painstaking detail. DI processes concern only part of the wave function for a problem. The other part involves complicated excitations of many degrees of freedom, and gives the compound nucleus (CN) effects. While it is extremely interesting to learn how to separate DI and CN effects in an orderly manner, if they are both present in a reaction, no suitable method has yet been found. Instead, current work stresses the kinds of reactions and the kinds of final states in which DI effects dominate and in which CN effects may almost be forgotten. The DI cross-sections which are studied are often extremely large, comparable to elastic scattering cross-sections. (author)

  10. Reactor container

    International Nuclear Information System (INIS)

    Oyamada, Osamu; Furukawa, Hideyasu; Uozumi, Hiroto.

    1979-01-01

    Purpose: To lower the position of an intermediate slab within a reactor container and fitting a heat insulating material to the inner wall of said intermediate slab, whereby a space for a control rod exchanging device and thermal stresses of the inner peripheral wall are lowered. Constitution: In the pedestal at the lower part of a reactor pressure vessel there is formed an intermediate slab at a position lower than diaphragm floor slab of the outer periphery of the pedestal thereby to secure a space for providing automatic exchanging device of a control rod driving device. Futhermore, a heat insulating material is fitted to the inner peripheral wall at the upper side of the intermediate slab part, and the temperature gradient in the wall thickness direction at the time of a piping rupture trouble is made gentle, and thermal stresses at the inner peripheral wall are lowered. (Sekiya, K.)

  11. Containment vessel

    International Nuclear Information System (INIS)

    Zbirohowski-Koscia, K.F.; Roberts, A.C.

    1980-01-01

    A concrete containment vessel for nuclear reactors is disclosed that is spherical and that has prestressing tendons disposed in first, second and third sets, the tendons of each set being all substantially concentric and centred around a respective one of the three orthogonal axes of the sphere; the tendons of the first set being anchored at each end at a first anchor rib running around a circumference of the vessel, the tendons of the second set being anchored at each end at a second anchor rib running around a circumference of the sphere and disposed at 90 0 to the first rib, and the tendons of the third set being anchored some to the first rib and the remainder to the second rib. (author)

  12. Thermodynamics of Enzyme-Catalyzed Reactions Database

    Science.gov (United States)

    SRD 74 Thermodynamics of Enzyme-Catalyzed Reactions Database (Web, free access)   The Thermodynamics of Enzyme-Catalyzed Reactions Database contains thermodynamic data on enzyme-catalyzed reactions that have been recently published in the Journal of Physical and Chemical Reference Data (JPCRD). For each reaction the following information is provided: the reference for the data, the reaction studied, the name of the enzyme used and its Enzyme Commission number, the method of measurement, the data and an evaluation thereof.

  13. How I treat CLL up front.

    Science.gov (United States)

    Gribben, John G

    2010-01-14

    Although chronic lymphocytic leukemia (CLL) remains incurable, over the past decade there have been major advances in understanding the pathophysiology of CLL and in the treatment of this disease. This has led to greatly increased response rates and durations of response but not yet improved survival. Advances in the use of prognostic factors that identify patients at high risk for progression have led us to the question whether there is still a role for a "watch and wait" approach in asymptomatic high-risk patients or whether they should be treated earlier in their disease course. Questions remain, including, what is the optimal first-line treatment and its timing and is there any role of maintenance therapy or stem cell transplantation in this disease? CLL is a disease of the elderly and not all patients are eligible for aggressive up-front chemoimmunotherapy regimens, so what is the optimal treatment approach for more frail elderly patients? It is highly likely that our treatment approaches will continue to evolve as the results of ongoing clinical trials are released and that further improvements in the outcome of this disease will result from identification of therapies that target the underlying pathophysiology of CLL.

  14. Front lighted optical tooling method and apparatus

    International Nuclear Information System (INIS)

    Stone, W. J.

    1985-01-01

    An optical tooling method and apparatus uses a front lighted shadowgraphic technique to enhance visual contrast of reflected light. The apparatus includes an optical assembly including a fiducial mark, such as cross hairs, reflecting polarized light with a first polarization, a polarizing element backing the fiducial mark and a reflective surface backing the polarizing element for reflecting polarized light bypassing the fiducial mark and traveling through the polarizing element. The light reflected by the reflecting surface is directed through a second pass of the polarizing element toward the frontal direction with a polarization differing from the polarization of the light reflected by the fiducial mark. When used as a tooling target, the optical assembly may be mounted directly to a reference surface or may be secured in a mounting, such as a magnetic mounting. The optical assembly may also be mounted in a plane defining structure and used as a spherometer in conjunction with an optical depth measuring instrument. A method of measuring a radius of curvature of an unknown surface includes positioning the spherometer on a surface between the surface and a depth measuring optical instrument. As the spherometer is frontally illuminated, the distance from the depth measuring instrument to the fiducial mark and the underlying surface are alternately measured and the difference in these measurements is used as the sagittal height to calculate a radius of curvature

  15. Light-Front Dynamics in Hadron Physics

    International Nuclear Information System (INIS)

    Ji, C.-R.; Bakker, B.L.G.; Choi, H.-M.

    2013-01-01

    Light-front dynamics(LFD) plays an important role in the analyses of relativistic few-body systems. As evidenced from the recent studies of generalized parton distributions (GPDs) in hadron physics, a natural framework for a detailed study of hadron structures is LFD due to its direct application in Minkowski space as well as its distinct feature of accounting for the vacuum fluctuations in quantum field theories. In the last few years, however, it has been emphasized that treacherous points such as LF singularities and zero-modes should be taken into account for successful LFD applications to hadron phenomenology. In this paper, we discuss a typical example of the contemporary relativistic hadron physics in which the fundamental issues should be taken into account for the successful application of LFD. In particular, we focus on the kinematic issue of GPDs in deeply virtual Compton scattering (DVCS). Although this fundamental issue has been glossed over in the literature, it must be taken care of for the correct analysis of DVCS data. (author)

  16. The Front Line of Genomic Translation

    International Nuclear Information System (INIS)

    O'Neill, C. S.; McBride, C. M.; Koehly, L. M.; Bryan, A. D.; Wideroff, L.

    2012-01-01

    Cancer prevention, detection, and treatment represent the front line of genomic translation. Increasingly, new genomic knowledge is being used to inform personalized cancer prevention recommendations and treatment [1-3]. Genomic applications proposed and realized span the full cancer continuum, from cancer prevention and early detection vis a vis genomic risk profiles to motivate behavioral risk reduction and adherence [4] to screening and prophylactic prevention recommendations for high-risk families [5-7], to enhancing cancer survivorship by using genomic tumor profiles to inform treatment decisions and targeted cancer therapies [8, 9]. Yet the utility for many of these applications is as yet unclear and will be influenced heavily by the public’s, patients’, and health care providers’ responses and in numerous other factors, such as health care delivery models [3]. The contributors to this special issue consider various target groups’ responses and contextual factors. To reflect the cancer continuum, the special issue is divided into three broad, overlapping themes-primary prevention, high risk families and family communication and clinical translation.

  17. FACILITATING RADICAL FRONT-END INNOVATION THROUGH TARGETED HR PRACTICES

    DEFF Research Database (Denmark)

    Aagaard, Annabeth

    2017-01-01

    This study examines how radical front end innovation can be actively facilitated through selected and targeted HR practices and bundles of HR practices. The empirical field is an explorative case study of front end innovation and HR practices in the pharmaceutical industry, with an in-depth case ...

  18. An improved front tracking method for the Euler equations

    NARCIS (Netherlands)

    Witteveen, J.A.S.; Koren, B.; Bakker, P.G.

    2007-01-01

    An improved front tracking method for hyperbolic conservation laws is presented. The improved method accurately resolves discontinuities as well as continuous phenomena. The method is based on an improved front interaction model for a physically more accurate modeling of the Euler equations, as

  19. MMIC tuned front-end for a coherent optical receiver

    DEFF Research Database (Denmark)

    Petersen, Anders Kongstad; Jagd, A. M.; Ebskamp, F.

    1993-01-01

    A low-noise transformer tuned optical front-end for a coherent optical receiver is described. The front-end is based on a GaInAs/InP p-i-n photodiode and a full custom designed GaAs monolithic microwave integrated circuit (MMIC). The measured equivalent input noise current density is between 5-16 p...

  20. Desirable forest structures for a restored Front Range

    Science.gov (United States)

    Yvette L. Dickinson; Rob Addington; Greg Aplet; Mike Babler; Mike Battaglia; Peter Brown; Tony Cheng; Casey Cooley; Dick Edwards; Jonas Feinstein; Paula Fornwalt; Hal Gibbs; Megan Matonis; Kristen Pelz; Claudia Regan

    2014-01-01

    As part of the federal Collaborative Forest Landscape Restoration Program administered by the US Forest Service, the Colorado Front Range Collaborative Forest Landscape Restoration Project (FR-CFLRP, a collaborative effort of the Front Range Roundtable1 and the US Forest Service) is required to define desired conditions for lower montane ponderosa pine (Pinus ponderosa...

  1. Reaction mechanisms

    International Nuclear Information System (INIS)

    Nguyen Trong Anh

    1988-01-01

    The 1988 progress report of the Reaction Mechanisms laboratory (Polytechnic School, France), is presented. The research topics are: the valence bond methods, the radical chemistry, the modelling of the transition states by applying geometric constraints, the long range interactions (ion - molecule) in gaseous phase, the reaction sites in gaseous phase and the mass spectroscopy applications. The points of convergence between the investigations of the mass spectroscopy and the theoretical chemistry teams, as well as the purposes guiding the research programs, are discussed. The published papers, the conferences, the congress communications and the thesis, are also reported [fr

  2. Dilution of boar ejaculates with BTS containing HEPES in place of bicarbonate immediately after ejaculation can reduce the increased inducibility of the acrosome reaction by treatment with calcium and calcium ionophore A23187, which is potentially associated with boar subfertility.

    Science.gov (United States)

    Murase, Tetsuma; Imaeda, Noriaki; Yamada, Hiroto; Takasu, Masaki; Taguchi, Kazuo; Katoh, Tsutomu

    2010-06-01

    The present study investigated whether substitution of HEPES for bicarbonate in BTS (BTS-H) used to dilute boar ejaculates immediately after ejaculation could reduce the increased inducibility of the acrosome reaction by calcium and calcium ionophore A23187. When an ejaculate was split, diluted 5-fold with regular BTS (BTS-B) and BTS-H and stored at 17 C for 12 h or 60 h, the extender or storage time had no significant influence on sperm motility or viability measured by the eosin-nigrosin method. When spermatozoa diluted serially with BTS-B and stored (36 h) were stimulated with Ca2+ (3 mM) and A23187 (0.3 microM), the proportion of spermatozoa that underwent the acrosome reaction (% acrosome reactions) significantly increased as the magnifications of dilution increased (bicarbonate content almost unchanged by dilution). By contrast, the % acrosome reactions in spermatozoa similarly diluted and stored with BTS-H decreased with the increasing magnifications of dilution (bicarbonate decreased). Sperm motility immediately after the end of incubation without A23178 tended to be lower for BTS-H than BTS-B, and the ejaculates for BTS-H had a tendency to have a lower total protein in seminal plasma than those for BTS-B. These results implied that the samples for BTS-H could be used as a model for ejaculates possibly collected during summer and showing subfertility. When an ejaculate was split, diluted serially with BTS-B and BTS-H and stored, viability measured by staining with propidium iodide was extremely similar between the 2 extenders and among the different dilution magnifications, regardless of whether spermatozoa were washed (stored for 36-66 h) or not (stored for 66-72 h). These results suggest that boar ejaculate can be stored with BTS-H at least according to the results for sperm motility and viability and that hypersensitivity of spermatozoa to Ca2+ and A23187 potentially associated with boar subfertility could be lessened by diluting ejaculates with BTS-H.

  3. Protein requirements for Blue-fronted Amazon (Amazona aestiva) growth.

    Science.gov (United States)

    Carciofi, A C; Sanfilippo, L F; de-Oliveira, L D; do Amaral, P P; Prada, F

    2008-06-01

    The objective of this study was to evaluate the protein requirements for hand-rearing Blue-fronted Amazon parrots (Amazona aestiva). Forty hatchlings were fed semi-purified diets containing one of four (as-fed basis) protein levels: 13%, 18%, 23% and 28%. The experiment was carried out in a randomized block design with the initial weight of the nestling as the blocking factor and 10 parrots per protein level. Regression analysis was used to determine relationships between protein level and biometric measurements. The data indicated that 13% crude protein supported nestling growth with 18% being the minimum tested level required for maximum development. The optimal protein concentration for maximum weight gain was 24.4% (p = 0.08; r(2) = 0.25), tail length 23.7% (p = 0.09; r(2) = 0.19), wing length 23.0% (p = 0.07; r(2) = 0.17), tarsus length 21.3% (p = 0.06; r(2) = 0.10) and tarsus width 21.4% (p = 0.07; r(2) = 0.09). Tarsus measurements were larger in males (p < 0.05), indicating that sex must be considered when studying developing psittacines. These results were obtained using a highly digestible protein and a diet with moderate metabolizable energy levels.

  4. Pediatric Burns from Glass-Fronted Fireplaces in Canada: A Growing Issue Over the Past 20 Years.

    Science.gov (United States)

    Toor, Jay; Crain, Jennifer; Kelly, Charis; Verchere, Cindy; Fish, Joel

    2016-01-01

    There is an alarming lack of public awareness surrounding the safety of glass-fronted fireplaces. This has resulted in an active campaign from the American Burn Association Prevention Committee. One issue encountered while advocating for prevention among manufacturers is the lack of corroborating and accurate data. The purpose of this study was to examine the annual trends and epidemiology of glass-fronted fireplace-related burn injuries to children less than 15 years old, who presented to Canadian emergency departments between 1990 and 2010. Records of pediatric burn injuries related to glass-fronted fireplaces were extracted from the Canadian Hospitals Injury Reporting and Prevention Program database for the study period (1990-2010). Cases were analyzed in terms of anatomic area affected, demographics, seasonality, safety device use, and injury severity. A total of 616 cases of burns from glass-fronted fireplaces were identified. The incidence increased at an average of 2.7 cases per year. This is a greater than 20-fold increase over 20 years. Seventy-five percentage of the cases occurred in children less than 2 years, and 95% occurred in children less than 5 years. The study demonstrated a growing risk from glass-fronted fireplace burns, likely due to the increasing popularity of household gas fireplace units. These units are a particular risk to children less than 2 years, attributable to their developing mobility and reduced reaction time. This is a preventable injury that should be addressed through changes to legislation and manufacturing.

  5. Study of the activation of targets containing Mo for the production of 99Mo by the 98Mo(n,γ)99Mo nuclear reaction and the behaviour of the radionuclidic impurities of the process

    International Nuclear Information System (INIS)

    Nieto, Renata Correa

    1998-01-01

    The most used radioisotope in Nuclear Medicine is 99m Tc, in the 99 Mo- 99m Tc generator form. 99 Mo can be produced by several nuclear reactions in reactors and cyclotrons. The cyclotron production is not technically and economically viable. The production in the reactor can be done in two different ways: by the fission of 235 U and by 98 Mo(n,γ) 99 Mo reaction. A project for the production of 99 Mo by the activation of Mo and the preparation of gel type generators is under development at the 'Instituto de Pesquisas Energeticas e Nucleares'. In the present work, the radionuclidic impurities produced in the activation of MOO 3 and MoZr gel were evaluated, and these represent the two possible ways of preparing the gel of MoZr. A target of metallic Mo was also studied. The radionuclidic purity of 99m Tc eluted from generators prepared in these ways was also measured and compared with the generators prepared with fission 99 Mo. The results showed that, by all the parameters analysed, the best way of preparing the generator of 99 Mo - 99m Tc is the irradiation of MOO 3 and further preparation of the gel and the generators. (author)

  6. Nonlinear waves in reaction-diffusion systems: The effect of transport memory

    International Nuclear Information System (INIS)

    Manne, K. K.; Hurd, A. J.; Kenkre, V. M.

    2000-01-01

    Motivated by the problem of determining stress distributions in granular materials, we study the effect of finite transport correlation times on the propagation of nonlinear wave fronts in reaction-diffusion systems. We obtain results such as the possibility of spatial oscillations in the wave-front shape for certain values of the system parameters and high enough wave-front speeds. We also generalize earlier known results concerning the minimum wave-front speed and shape-speed relationships stemming from the finiteness of the correlation times. Analytic investigations are made possible by a piecewise linear representation of the nonlinearity. (c) 2000 The American Physical Society

  7. Nonlinear waves in reaction-diffusion systems: The effect of transport memory

    Science.gov (United States)

    Manne, K. K.; Hurd, A. J.; Kenkre, V. M.

    2000-04-01

    Motivated by the problem of determining stress distributions in granular materials, we study the effect of finite transport correlation times on the propagation of nonlinear wave fronts in reaction-diffusion systems. We obtain results such as the possibility of spatial oscillations in the wave-front shape for certain values of the system parameters and high enough wave-front speeds. We also generalize earlier known results concerning the minimum wave-front speed and shape-speed relationships stemming from the finiteness of the correlation times. Analytic investigations are made possible by a piecewise linear representation of the nonlinearity.

  8. Allergic reactions

    Science.gov (United States)

    ... that don't bother most people (such as venom from bee stings and certain foods, medicines, and pollens) can ... person. If the allergic reaction is from a bee sting, scrape the ... more venom. If the person has emergency allergy medicine on ...

  9. Combining Stereo SECCHI COR2 and HI1 Images for Automatic CME Front Edge Tracking

    Science.gov (United States)

    Kirnosov, Vladimir; Chang, Lin-Ching; Pulkkinen, Antti

    2016-01-01

    COR2 coronagraph images are the most commonly used data for coronal mass ejection (CME) analysis among the various types of data provided by the STEREO (Solar Terrestrial Relations Observatory) SECCHI (Sun-Earth Connection Coronal and Heliospheric Investigation) suite of instruments. The field of view (FOV) in COR2 images covers 215 solar radii (Rs) that allow for tracking the front edge of a CME in its initial stage to forecast the lead-time of a CME and its chances of reaching the Earth. However, estimating the lead-time of a CME using COR2 images gives a larger lead-time, which may be associated with greater uncertainty. To reduce this uncertainty, CME front edge tracking should be continued beyond the FOV of COR2 images. Therefore, heliospheric imager (HI1) data that covers 1590 Rs FOV must be included. In this paper, we propose a novel automatic method that takes both COR2 and HI1 images into account and combine the results to track the front edges of a CME continuously. The method consists of two modules: pre-processing and tracking. The pre-processing module produces a set of segmented images, which contain the signature of a CME, for both COR2 and HI1 separately. In addition, the HI1 images are resized and padded, so that the center of the Sun is the central coordinate of the resized HI1 images. The resulting COR2 andHI1 image set is then fed into the tracking module to estimate the position angle (PA) and track the front edge of a CME. The detected front edge is then used to produce a height-time profile that is used to estimate the speed of a CME. The method was validated using 15 CME events observed in the period from January 1, 2008 to August 31, 2009. The results demonstrate that the proposed method is effective for CME front edge tracking in both COR2 and HI1 images. Using this method, the CME front edge can now be tracked automatically and continuously in a much larger range, i.e., from 2 to 90 Rs, for the first time. These improvement scan greatly

  10. A water soluble fraction capable of regulating the immunity reactions of a host against allogenic cells or tissues, the pharmaceutical preparations which contain this fraction and a procedure for the preparation of the latter

    International Nuclear Information System (INIS)

    1980-01-01

    The preparation is described of non-toxic bone marrow cell suspensions containing a marrow-regulating factor, which are suitable for intravenous injection in patients with serious hematopoietic disturbances or radiation syndrome. The marrow-regulating factor conditions the bone marrow in a manner which enhances the success of bone marrow transplantation in donor-incompatible or semicompatible hosts. The extensive testing of this pharmaceutical preparation in irradiated mice is described and a toxicity study reported. (Auth.)

  11. Cluster Observations of Multiple Dipolarization Fronts

    Science.gov (United States)

    Hwang, Kyoung-Joo; Goldstein, Melvyn L.; Lee, Ensang; Pickett, Jolene S.

    2011-01-01

    We present Cluster observations of a series of dipolarization fronts (DF 1 to 6) at the central current sheet in Earth's magnetotail. The velocities of fast earthward flow following behind each DF 1-3, are comparable to the Alfven velocity, indicating that the flow bursts might have been generated by bursty reconnection that occurred tailward of the spacecraft. Based on multi-spacecraft timing analysis, DF normals are found to propagate mainly earthward at $160-335$ km/s with a thickness of 900-1500 km, which corresponds to the ion inertial length or gyroradius scale. Each DF is followed by significant fluctuations in the $x$ and $y$ components of the magnetic field whose peaks are found 1-2 minutes after the DF passage. These $(B_{x},B_{y} )$-fluctuations propagate dawnward (mainly) and earthward. Strongly enhanced field-aligned beams are observed coincidently with $(B_{x},B_{y})$ fluctuations, while an enhancement of cross-tail currents is associated with the DFs. From the observed pressure imbalance and flux-tube entropy changes between the two regions separated by the DF, we speculate that interchange instability destabilizes the DFs and causes the deformation of the mid-tail magnetic topology. This process generates significant field-aligned currents, and might power the auroral brightening in the ionosphere. However, this event is neither associated with the main substorm auroral breakup nor the poleward expansion, which might indicate that the observed multiple DFs have been dissipated before they reach the inner plasma sheet boundary.

  12. Iu. Ushakov & A. Stukalov, Front voennykh prokurorov [The Military Procurators’ Front], Moskva, Viatka, 2000, 223 pages.

    Directory of Open Access Journals (Sweden)

    Vanessa Voisin

    2008-07-01

    Full Text Available Front voennykh prokurorov is a collection of essays written by two writers who are not known as specialists of military history, but obviously have access to archives, as proves the reprint, in the middle of the book, of several pages from the personal files of Afanas’ev, former Main Military Prosecutor of Soviet Armed Forces.The first part of the book is devoted to Nikolai Porfir’evich Afanas’ev’s memoirs, written, according to the editors, after his retirement in 1950. Afanas’ev, though les...

  13. Heterocyclization of compounds containing diazo and cyano groups. 4. Reactions of 2-diazo-2-cyanoacetic acid amides with P4S10 and the Lawesson reagent. Synthesis and recyclization of 5-amino-1,2,3-thiadiazole-4-carbothioamides

    International Nuclear Information System (INIS)

    Bakulev, V.A.; Dankova, E.F.; Mokrushin, V.S.; Sidorov, E.O.; Lebedev, A.T.

    1987-01-01

    5-Amino-1,2,3-thiadiazole-4-carbothioamides were obtained in the reaction of carbonyl derivatives of diazoacetonitrile with P 4 S 10 and the Lawesson reagent. A novel recyclization of 1,2,3-thiadiazole-4-carbothioamides was observed. The PMR spectra of solutions in d 6 -DMSO were obtained with a Perkin-Elmer R-12B spectrometer (60 MHz) with tetramethylsilane (TMS) as the internal standard. The 13 C NMR spectra of solutions in d 6 -DMSO were obtained with a Bruker WP-80 spectrometer (60 MHz) with TMS as the internal standard. The mass spectra were recorded with MAT-311A (ionizing voltage 70 V) and MKh-1303 (50 V) mass spectrometers

  14. Adaptive moving mesh methods for simulating one-dimensional groundwater problems with sharp moving fronts

    Science.gov (United States)

    Huang, W.; Zheng, Lingyun; Zhan, X.

    2002-01-01

    Accurate modelling of groundwater flow and transport with sharp moving fronts often involves high computational cost, when a fixed/uniform mesh is used. In this paper, we investigate the modelling of groundwater problems using a particular adaptive mesh method called the moving mesh partial differential equation approach. With this approach, the mesh is dynamically relocated through a partial differential equation to capture the evolving sharp fronts with a relatively small number of grid points. The mesh movement and physical system modelling are realized by solving the mesh movement and physical partial differential equations alternately. The method is applied to the modelling of a range of groundwater problems, including advection dominated chemical transport and reaction, non-linear infiltration in soil, and the coupling of density dependent flow and transport. Numerical results demonstrate that sharp moving fronts can be accurately and efficiently captured by the moving mesh approach. Also addressed are important implementation strategies, e.g. the construction of the monitor function based on the interpolation error, control of mesh concentration, and two-layer mesh movement. Copyright ?? 2002 John Wiley and Sons, Ltd.

  15. Exploration and exploitation of homologous series of bis(acrylamidoalkanes containing pyridyl and phenyl groups: β-sheet versus two-dimensional layers in solid-state photochemical [2 + 2] reactions

    Directory of Open Access Journals (Sweden)

    Mousumi Garai

    2015-09-01

    Full Text Available The homologous series of phenyl and pyridyl substituted bis(acrylamidoalkanes have been synthesized with the aim of systematic analysis of their crystal structures and their solid-state [2 + 2] reactivities. The changes in the crystal structures with respect to a small change in the molecular structure, that is by varying alkyl spacers between acrylamides and/or by varying the end groups (phenyl, 2-pyridyl, 3-pyridyl, 4-pyridyl on the C-terminal of the amide, were analyzed in terms of hydrogen-bonding interference (N—H...Npy versus N—H...O=C and network geometries. In this series, a greater tendency towards the formation of N—H...O hydrogen bonds (β-sheets and two-dimensional networks over N—H...N hydrogen bonds was observed. Among all the structures seven structures were found to have the required alignments of double bonds for the [2 + 2] reaction such that the formations of single dimer, double dimer and polymer are facilitated. However, only four structures were found to exhibit such a solid-state [2 + 2] reaction to form a single dimer and polymers. The two-dimensional hydrogen-bonding layer via N—H...O hydrogen bonds was found to promote solid-state [2 + 2] photo-polymerization in a single-crystal-to-single-crystal manner. Such two-dimensional layers were encountered only when the spacer between acryl amide moieties is butyl. Only four out of the 16 derivatives were found to form hydrates, two each from 2-pyridyl and 4-pyridyl derivatives. The water molecules in these structures govern the hydrogen-bonding networks by the formation of an octameric water cluster and one-dimensional zigzag water chains. The trends in the melting points and densities were also analyzed.

  16. Dynamics of one- and two-dimensional fronts in a bistable equation with time-delayed global feedback: Propagation failure and control mechanisms

    International Nuclear Information System (INIS)

    Boubendir, Yassine; Mendez, Vicenc; Rotstein, Horacio G.

    2010-01-01

    We study the evolution of fronts in a bistable equation with time-delayed global feedback in the fast reaction and slow diffusion regime. This equation generalizes the Hodgkin-Grafstein and Allen-Cahn equations. We derive a nonlinear equation governing the motion of fronts, which includes a term with delay. In the one-dimensional case this equation is linear. We study the motion of one- and two-dimensional fronts, finding a much richer dynamics than for the previously studied cases (without time-delayed global feedback). We explain the mechanism by which localized fronts created by inhibitory global coupling loose stability in a Hopf bifurcation as the delay time increases. We show that for certain delay times, the prevailing phase is different from that corresponding to the system in the absence of global coupling. Numerical simulations of the partial differential equation are in agreement with the analytical predictions.

  17. System for inspection of stacked cargo containers

    Science.gov (United States)

    Derenzo, Stephen [Pinole, CA

    2011-08-16

    The present invention relates to a system for inspection of stacked cargo containers. One embodiment of the invention generally comprises a plurality of stacked cargo containers arranged in rows or tiers, each container having a top, a bottom a first side, a second side, a front end, and a back end; a plurality of spacers arranged in rows or tiers; one or more mobile inspection devices for inspecting the cargo containers, wherein the one or more inspection devices are removeably disposed within the spacers, the inspection means configured to move through the spacers to detect radiation within the containers. The invented system can also be configured to inspect the cargo containers for a variety of other potentially hazardous materials including but not limited to explosive and chemical threats.

  18. Simulating the Evolving Behavior of Secondary Slow Slip Fronts

    Science.gov (United States)

    Peng, Y.; Rubin, A. M.

    2017-12-01

    High-resolution tremor catalogs of slow slip events reveal secondary slow slip fronts behind the main front that repetitively occupy the same source area during a single episode. These repetitive fronts are most often observed in regions with high tremor density. Their recurrence intervals gradually increase from being too short to be tidally modulated (tens of minutes) to being close to tidal periods (about 12 or 24 hours). This could be explained by a decreasing loading rate from creep in the surrounding regions (with few or no observable tremor events) as the main front passes by. As the recurrence intervals of the fronts increase, eventually they lock in on the tidal periods. We attempt to simulate this numerically using a rate-and-state friction law that transitions from velocity-weakening at low slip speeds to velocity strengthening at high slip speeds. Many small circular patches with a cutoff velocity an order of magnitude higher than that of the background are randomly placed on the fault, in order to simulate the average properties of the high-density tremor zone. Preliminary results show that given reasonable parameters, this model produces similar propagation speeds of the forward-migrating main front inside and outside the high-density tremor zone, consistent with observations. We will explore the behavior of the secondary fronts that arise in this model, in relation to the local density of the small tremor-analog patches, the overall geometry of the tremor zone and the tides.

  19. Hindrances to bistable front propagation: application to Wolbachia invasion.

    Science.gov (United States)

    Nadin, Grégoire; Strugarek, Martin; Vauchelet, Nicolas

    2018-05-01

    We study the biological situation when an invading population propagates and replaces an existing population with different characteristics. For instance, this may occur in the presence of a vertically transmitted infection causing a cytoplasmic effect similar to the Allee effect (e.g. Wolbachia in Aedes mosquitoes): the invading dynamics we model is bistable. We aim at quantifying the propagules (what does it take for an invasion to start?) and the invasive power (how far can an invading front go, and what can stop it?). We rigorously show that a heterogeneous environment inducing a strong enough population gradient can stop an invading front, which will converge in this case to a stable front. We characterize the critical population jump, and also prove the existence of unstable fronts above the stable (blocking) fronts. Being above the maximal unstable front enables an invading front to clear the obstacle and propagate further. We are particularly interested in the case of artificial Wolbachia infection, used as a tool to fight arboviruses.

  20. A differential low-voltage high gain current-mode integrated RF receiver front-end

    Energy Technology Data Exchange (ETDEWEB)

    Wang Chunhua; Ma Minglin; Sun Jingru; Du Sichun; Guo Xiaorong; He Haizhen, E-mail: wch1227164@sina.com [School of Information Science and Technology, Hunan University, Changsha 410082 (China)

    2011-02-15

    A differential low-voltage high gain current-mode integrated RF front end for an 802.11b WLAN is proposed. It contains a differential transconductance low noise amplifier (G{sub m}-LNA) and a differential current-mode down converted mixer. The single terminal of the G{sub m}-LNA contains just one MOS transistor, two capacitors and two inductors. The gate-source shunt capacitors, C{sub x1} and C{sub x2}, can not only reduce the effects of gate-source C{sub gs} on resonance frequency and input-matching impedance, but they also enable the gate inductance L{sub g1,2} to be selected at a very small value. The current-mode mixer is composed of four switched current mirrors. Adjusting the ratio of the drain channel sizes of the switched current mirrors can increase the gain of the mixer and accordingly increase the gain of RF receiver front-end. The RF front-end operates under 1 V supply voltage. The receiver RFIC was fabricated using a chartered 0.18 {mu}m CMOS process. The integrated RF receiver front-end has a measured power conversion gain of 17.48 dB and an input referred third-order intercept point (IIP3) of -7.02 dBm. The total noise figure is 4.5 dB and the power is only 14 mW by post-simulations. (semiconductor integrated circuits)

  1. Direct containment heating models in the CONTAIN code

    International Nuclear Information System (INIS)

    Washington, K.E.; Williams, D.C.

    1995-08-01

    The potential exists in a nuclear reactor core melt severe accident for molten core debris to be dispersed under high pressure into the containment building. If this occurs, the set of phenomena that result in the transfer of energy to the containment atmosphere and its surroundings is referred to as direct containment heating (DCH). Because of the potential for DCH to lead to early containment failure, the U.S. Nuclear Regulatory Commission (USNRC) has sponsored an extensive research program consisting of experimental, analytical, and risk integration components. An important element of the analytical research has been the development and assessment of direct containment heating models in the CONTAIN code. This report documents the DCH models in the CONTAIN code. DCH models in CONTAIN for representing debris transport, trapping, chemical reactions, and heat transfer from debris to the containment atmosphere and surroundings are described. The descriptions include the governing equations and input instructions in CONTAIN unique to performing DCH calculations. Modifications made to the combustion models in CONTAIN for representing the combustion of DCH-produced and pre-existing hydrogen under DCH conditions are also described. Input table options for representing the discharge of debris from the RPV and the entrainment phase of the DCH process are also described. A sample calculation is presented to demonstrate the functionality of the models. The results show that reasonable behavior is obtained when the models are used to predict the sixth Zion geometry integral effects test at 1/10th scale

  2. Direct containment heating models in the CONTAIN code

    Energy Technology Data Exchange (ETDEWEB)

    Washington, K.E.; Williams, D.C.

    1995-08-01

    The potential exists in a nuclear reactor core melt severe accident for molten core debris to be dispersed under high pressure into the containment building. If this occurs, the set of phenomena that result in the transfer of energy to the containment atmosphere and its surroundings is referred to as direct containment heating (DCH). Because of the potential for DCH to lead to early containment failure, the U.S. Nuclear Regulatory Commission (USNRC) has sponsored an extensive research program consisting of experimental, analytical, and risk integration components. An important element of the analytical research has been the development and assessment of direct containment heating models in the CONTAIN code. This report documents the DCH models in the CONTAIN code. DCH models in CONTAIN for representing debris transport, trapping, chemical reactions, and heat transfer from debris to the containment atmosphere and surroundings are described. The descriptions include the governing equations and input instructions in CONTAIN unique to performing DCH calculations. Modifications made to the combustion models in CONTAIN for representing the combustion of DCH-produced and pre-existing hydrogen under DCH conditions are also described. Input table options for representing the discharge of debris from the RPV and the entrainment phase of the DCH process are also described. A sample calculation is presented to demonstrate the functionality of the models. The results show that reasonable behavior is obtained when the models are used to predict the sixth Zion geometry integral effects test at 1/10th scale.

  3. Spin-1 particles with light-front approach

    Directory of Open Access Journals (Sweden)

    de Melo J.P.B.C.

    2014-06-01

    Full Text Available For the vector sector, i.e, mesons with spin-1, the electromagnetic form factors and anothers observables are calculated with the light-front approach. However, the light-front quantum field theory have some problems, for example, the rotational symmetry breaking. We solve that problem added the zero modes contribuition to the matrix elements of the electromagnetic current, besides the valence contribuition. We found that among the four independent matrix elements of the plus component in the light-front helicity basis only the 0 → 0 one carries zero mode contributions.

  4. Determination of cut front position in laser cutting

    International Nuclear Information System (INIS)

    Pereira, M; Thombansen, U

    2016-01-01

    Laser cutting has a huge importance to manufacturing industry. Laser cutting machines operate with fixed technological parameters and this does not guarantee the best productivity. The adjustment of the cutting parameters during operation can improve the machine performance. Based on a coaxial measuring device it is possible to identify the cut front position during the cutting process. This paper describes the data analysis approach used to determine the cut front position for different feed rates. The cut front position was determined with good resolution, but improvements are needed to make the whole process more stable. (paper)

  5. Adaptive RF front-ends for hand-held applications

    CERN Document Server

    van Bezooijen, Andre; van Roermund, Arthur

    2010-01-01

    The RF front-end - antenna combination is a vital part of a mobile phone because its performance is very relevant to the link quality between hand-set and cellular network base-stations. The RF front-end performance suffers from changes in operating environment, like hand-effects, that are often unpredictable. ""Adaptive RF Front-Ends for Hand-Held Applications"" presents an analysis on the impact of fluctuating environmental parameters. In order to overcome undesired behavior two different adaptive control methods are treated that make RF frond-ends more resilient: adaptive impedance control,

  6. Light-front field theory in the description of hadrons

    Science.gov (United States)

    Ji, Chueng-Ryong

    2017-03-01

    We discuss the use of light-front field theory in the descriptions of hadrons. In particular, we clarify the confusion in the prevailing notion of the equivalence between the infinite momentum frame and the light-front dynamics and the advantage of the light-front dynamics in hadron physics. As an application, we present our recent work on the flavor asymmetry in the proton sea and identify the presence of the delta-function contributions associated with end-point singularities arising from the chiral effective theory calculation. The results pave the way for phenomenological applications of pion cloud models that are manifestly consistent with the chiral symmetry properties of QCD.

  7. Chaos of radiative heat-loss-induced flame front instability.

    Science.gov (United States)

    Kinugawa, Hikaru; Ueda, Kazuhiro; Gotoda, Hiroshi

    2016-03-01

    We are intensively studying the chaos via the period-doubling bifurcation cascade in radiative heat-loss-induced flame front instability by analytical methods based on dynamical systems theory and complex networks. Significant changes in flame front dynamics in the chaotic region, which cannot be seen in the bifurcation diagrams, were successfully extracted from recurrence quantification analysis and nonlinear forecasting and from the network entropy. The temporal dynamics of the fuel concentration in the well-developed chaotic region is much more complicated than that of the flame front temperature. It exhibits self-affinity as a result of the scale-free structure in the constructed visibility graph.

  8. Gluon cascades and amplitudes in light-front perturbation theory

    International Nuclear Information System (INIS)

    Cruz-Santiago, C.A.; Staśto, A.M.

    2013-01-01

    We construct the gluon wave functions, fragmentation functions and scattering amplitudes within the light-front perturbation theory. Recursion relations on the light-front are constructed for the wave functions and fragmentation functions, which in the latter case are the light-front analogs of the Berends–Giele recursion relations. Using general relations between wave functions and scattering amplitudes it is demonstrated how to obtain the maximally-helicity violating amplitudes, and explicit verification of the results is based on simple examples.

  9. Determination of cut front position in laser cutting

    Science.gov (United States)

    Pereira, M.; Thombansen, U.

    2016-07-01

    Laser cutting has a huge importance to manufacturing industry. Laser cutting machines operate with fixed technological parameters and this does not guarantee the best productivity. The adjustment of the cutting parameters during operation can improve the machine performance. Based on a coaxial measuring device it is possible to identify the cut front position during the cutting process. This paper describes the data analysis approach used to determine the cut front position for different feed rates. The cut front position was determined with good resolution, but improvements are needed to make the whole process more stable.

  10. Secondary Containers and Service Containers for Pesticides

    Science.gov (United States)

    Secondary containers and service containers are used by pesticide applicators in the process of applying a pesticide. EPA does not require secondary containers or service containers to be labeled or to meet particular construction standards. Learn more.

  11. Reactions of a 16-electron Cp*Co half-sandwich complex containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand with alkynones HC≡C-C(O)R (R=OMe,Me,Ph)

    Institute of Scientific and Technical Information of China (English)

    GUOYIQIBAYI; Gulnisa

    2010-01-01

    The reaction of the 16e half-sandwich complex Cp*Co(S2C2B10H10) (1) (Cp* = pentamethylcyclopentadienyl) with excess methyl acetylene monocarboxylate, HC≡C-CO2Me, affords the 18e complexes 2-6. Compound 2 bears a B-CH2 unit in which B-substitution occurs in the B(3)/B(6) position of the ortho-carborane cage. Complexes 3-6 are geometrical isomers, in which the alkyne is twofold inserted into one of the Co-S bonds in all the four possible ways. Treatment of 1 with excess 3-butyn-2-one or phenyl ethynyl ketone, HC≡C-C(O)R (R = Me, Ph), at ambient temperature leads to the 18e complexes 7-10, respectively, with two alkynes inserted into one of the Co-S bonds. All the new complexes were fully characterized by spectroscopic techniques and elemental analysis. The solid-state structures of 2, 3, 5, 7, 8, 9 and 10 were further characterized by X-ray structural analysis.

  12. A Case of a Generalized Lichenoid Tattoo Reaction

    Science.gov (United States)

    Zirwas, Matthew J.; Mosser, Joy L.

    2014-01-01

    Cutaneous reactions to tattoos have been increasing in conjunction with the rise in popularity of tattoos. While localized lichenoid reactions to tattoo inks are fairly common, generalized lichenoid reactions are relatively rare. Herein the authors present a case of a generalized lichenoid reaction to a tattoo containing only black ink. They also present a brief discussion of tattoo reactions and treatment options. PMID:25161761

  13. Endothermic decompositions of inorganic monocrystalline thin plates. II. Displacement rate modulation of the reaction front

    Science.gov (United States)

    Bertrand, G.; Comperat, M.; Lallemant, M.

    1980-09-01

    Copper sulfate pentahydrate dehydration into trihydrate was investigated using monocrystalline platelets with (110) crystallographic orientation. Temperature and pressure conditions were selected so as to obtain elliptical trihydrate domains. The study deals with the evolution, vs time, of elliptical domain dimensions and the evolution, vs water vapor pressure, of the {D}/{d} ratio of ellipse axes and on the other hand of the interface displacement rate along a given direction. The phenomena observed are not basically different from those yielded by the overall kinetic study of the solid sample. Their magnitude, however, is modulated depending on displacement direction. The results are analyzed within the scope of our study of endothermic decomposition of solids.

  14. Nano-Aluminum Reaction with Nitrogen in the Burn Front of Oxygen-Free Energetic Materials

    International Nuclear Information System (INIS)

    Tappan, B. C.; Son, S. F.; Moore, D. S.

    2006-01-01

    Nano-particulate aluminum metal was added to the high nitrogen energetic material triaminoguanidium azotetrazolate (TAGzT) in order to determine the effects on decomposition behavior. Standard safety testing (sensitivity to impact, spark and friction) are reported and show that the addition of nano-Al actually decreases the sensitivity of the pure TAGzT. Thermo-equilibrium calculations (Cheetah) indicate that the all of the Al reacts to form AlN in TAGzT decomposition, and the calculated specific impulses are reported. T-Jump/FTIR spectroscopy was performed on the neat TAGzT. Emission spectra were collected to determine the temperature of AlN formation in combustion. Burning rates were also collected, and the effects of nano-Al on rates are discussed

  15. Relvakogujad sõjaajalooklubist Front Line vahistati / Kadri Ratt

    Index Scriptorium Estoniae

    Ratt, Kadri

    2009-01-01

    Kaitsepolitsei võttis vahi alla 9 meest, keda kahtlustatakse suures koguses lõhkeainete, lõhkekehade ja tulirelvade ebaseaduslikus käitlemises. 6 meest neist kuuluvad sõjaajalooklubisse Front Line

  16. Your employees: the front line in cyber security

    OpenAIRE

    Ashenden, D

    2016-01-01

    First published in The Chemical Engineer and reproduced by Crest - Centre for Research and Evidence on Security Threats, 26/01/2016 (https://crestresearch.ac.uk/comment/employees-front-line-cyber-security/)

  17. Light-front quantization of the sine-Gordon model

    International Nuclear Information System (INIS)

    Burkardt, M.

    1993-01-01

    It is shown how to modify the canonical light-front quantization of the (1+1)-dimensional sine-Gordon model such that the zero-mode problem of light-front quantization is avoided. The canonical sine-Gordon Lagrangian is replaced by an effective Lagrangian which does not lead to divergences as k + =(k 0 +k 1 )/ √2 →0. After canonically quantizing the effective Lagrangian, one obtains the effective light-front Hamiltonian which agrees with the naive light-front (LF) Hamiltonian, up to one additional renormalization. The spectrum of the effective LF Hamiltonian is determined using discrete light-cone quantization and agrees with results from equal-time quantization

  18. Temperature in subsonic and supersonic radiation fronts measured at OMEGA

    Science.gov (United States)

    Johns, Heather; Kline, John; Lanier, Nick; Perry, Ted; Fontes, Chris; Fryer, Chris; Brown, Colin; Morton, John

    2017-10-01

    Propagation of heat fronts relevant to astrophysical plasmas is challenging in the supersonic regime. Plasma Te changes affect opacity and equation of state without hydrodynamic change. In the subsonic phase density perturbations form at material interfaces as the plasma responds to radiation pressure of the front. Recent experiments at OMEGA studied this transition in aerogel foams driven by a hohlraum. In COAX, two orthogonal backlighters drive x-ray radiography and K-shell absorption spectroscopy to diagnose the subsonic shape of the front and supersonic Te profiles. Past experiments used absorption spectroscopy in chlorinated foams to measure the heat front; however, Cl dopant is not suitable for higher material temperatures at NIF. COAX has developed use of Sc and Ti dopants to diagnose Te between 60-100eV and 100-180eV. Analysis with PrismSPECT using OPLIB tabular opacity data will evaluate the platform's ability to advance radiation transport in this regime.

  19. Idea management in support of pharmaceutical front end innovation

    DEFF Research Database (Denmark)

    Aagaard, Annabeth

    2012-01-01

    The pharmaceutical industry faces continuing pressures from rising R&D costs and depreciating value of patents, as patent lives is eroded by testing procedures and pressures from public authorities to cut health care costs. These challenges have increased the focus on shortening development times......, which again put pressure on the efficiency of front end innovation (FEI). In the attempt to overcome these various challenges pharmaceutical companies are looking for new models to support FEI. This paper explores in what way idea management can be applied as a tool in facilitation of front end...... innovation in practice. First I show through a literature study, how idea management and front end innovation are related and may support each other. Hereafter I apply an exploratory case study of front end innovation in eight medium to large pharmaceutical companies in examination of how idea management...

  20. Fast front-end electronics for COMPASS MWPCs

    CERN Document Server

    Colantoni, M L; Ferrero, A; Frolov, V; Grasso, A; Heinz, S; Maggiora, A; Maggiora, M G; Panzieri, D; Popov, A; Tchalyshev, V

    2000-01-01

    In the COMPASS experiment, under construction at CERN, about 23000 channels of MWPCs will be used. The very high rate of the muon and hadron beams, and the consequently high trigger rate, require front- end electronics with innovative conceptual design. A new MWPC front- end electronics that fulfills the main COMPASS requirement to have a fast DAQ with a minimum dead-time has been designed. The general concept of the front-end cards is described; the comparative tests of two front-end chips, and different fast gas mixtures, are also shown. The commissioning of the experiment will start in the summer 2000, and production running, using the muon beam, is foreseen for the year 2001. (8 refs).

  1. Quasielastic reactions

    International Nuclear Information System (INIS)

    Hansen, O.

    1983-01-01

    A brief review is presented of the experimental and theoretical situation regarding transfer reactions and inelastic scattering. In the first category there is little (very little) precision data for heavy projectiles and consequently almost no experience with quantitative theoretical analysis. For the inelastic scattering the rather extensive data strongly supports the coupled channels models with collective formfactors. At the most back angles, at intensities about 10 -5 of Rutherford scattering, a second, compound-like mechanism becomes dominant. The description of the interplay of these two opposite mechanisms provides a new challenge for our understanding

  2. Front-end electronics development for the SSC

    International Nuclear Information System (INIS)

    Levi, M.

    1990-12-01

    This is a status report on electronics development undertaken by the Front-End Electronics Collaboration. The overall goal of the collaboration remains the development by 1992 of complete, architecturally compatible, front end electronic systems for calorimeter, wire drift chamber, and silicon strip readout. We report here a few highlights to give a brief overview of the work underway. Performance requirements and capabilities, selected architectures, circuit designs and test results are presented. 13 refs., 21 figs., 1 tab

  3. Flow structure in front of the broad-crested weir

    Directory of Open Access Journals (Sweden)

    Zachoval Zbyněk

    2015-01-01

    Full Text Available The paper deals with research focused on description of flow structure in front of broad-crested weir. Based on experimental measurement, the flow structure in front of the weir (the recirculation zone of flow and tornado vortices and flow structure on the weir crest has been described. The determined flow character has been simulated using numerical model and based on comparing results the suitable model of turbulence has been recommended.

  4. Landau-Darrieus instability in an ablation front

    International Nuclear Information System (INIS)

    Piriz, A.R.; Portugues, R.F.

    2003-01-01

    An analytical model that shows the conditions for the existence of the Landau-Darrieus instability of an ablation front is presented. The model seems to agree with recently claimed simulation results [L. Masse et al., Proceedings of the 1st International Conference on Inertial Fusion Sciences and Applications (Elsevier, Paris, 2000), p. 220]. The model shows that the ablation front can be unstable in absence of gravity when the thermal flux is inhibited within the supercritical region of the corona

  5. An Alternative Front End Analysis Strategy for Complex Systems

    Science.gov (United States)

    2014-12-01

    missile ( ABM ) system . Patriot is employed in the field through a battalion echelon organizational structure. The line battery is the basic building...Research Report 1981 An Alternative Front End Analysis Strategy for Complex Systems M. Glenn Cobb U.S. Army Research Institute...NUMBER W5J9CQ11D0003 An Alternative Front End Analysis Strategy for Complex Systems 5b. PROGRAM ELEMENT NUMBER 633007 6

  6. Radiation hardness on very front-end for SPD

    International Nuclear Information System (INIS)

    Cano, Xavier; Graciani, Ricardo; Gascon, David; Garrido, Lluis; Bota, Sebastia; Herms, Atila; Comerma, Albert; Riera, Jordi

    2005-01-01

    The calorimeter front-end electronics of the LHCb experiment will be located in a region, which is not protected from radiation. Therefore, all the electronics must be qualified to stand some defined radiation levels. The procedure, measurements and results of an irradiation test for every component of the very front-end SPD detector, which is part of the LHCb calorimeter are presented here. All the tested components, except a custom made ASIC, are commercially available

  7. Are Hydrostatic Models Still Capable of Simulating Oceanic Fronts

    Science.gov (United States)

    2016-11-10

    Hydrostatic Models Still Capable of Simulating Oceanic Fronts Yalin Fan Zhitao Yu Ocean Dynamics and Prediction Branch Oceanography Division FengYan Shi...OF PAGES 17. LIMITATION OF ABSTRACT Are Hydrostatic Models Still Capable of Simulating Oceanic Fronts? Yalin Fan, Zhitao Yu, and, Fengyan Shi1 Naval...mixed layer and thermocline simulations as well as large scale circulations. Numerical experiments are conducted using hydrostatic (HY) and

  8. Poincare invariant algebra from instant to light-front quantization

    International Nuclear Information System (INIS)

    Ji, Chueng-Ryong; Mitchell, Chad

    2001-01-01

    We present the Poincare algebra interpolating between instant and light-front time quantizations. The angular momentum operators satisfying SU(2) algebra are constructed in an arbitrary interpolation angle and shown to be identical to the ordinary angular momentum and Leutwyler-Stern angular momentum in the instant and light-front quantization limits, respectively. The exchange of the dynamical role between the transverse angular mometum and the boost operators is manifest in our newly constructed algebra

  9. Indico front-end: From spaghetti to lasagna

    CERN Multimedia

    CERN. Geneva

    2017-01-01

    We will present how we transitioned from legacy spaghetti UI code to a more coherent, easier to understand and maintain ecosystem of front-end technologies and facilities with a strong emphasis in reusable components. In particular, we will share with you: 1) how we use Sass to maintain our home-baked CSS, 2) how we survive in 2017 without front-end Javascript frameworks, and 3) how we use template macros and WTForms for generating consistent HTML transparently.

  10. Traveling wave front solutions in lateral-excitatory neuronal networks

    Directory of Open Access Journals (Sweden)

    Sittipong Ruktamatakul

    2008-05-01

    Full Text Available In this paper, we discuss the shape of traveling wave front solutions to a neuronal model with the connection function to be of lateral excitation type. This means that close connecting cells have an inhibitory influence, while cells that aremore distant have an excitatory influence. We give results on the shape of the wave fronts solutions, which exhibit different shapes depend ing on the size of a threshold parameter.

  11. Hyper-X Vehicle Model - Front View

    Science.gov (United States)

    1996-01-01

    A front view of an early desk-top model of NASA's X-43A 'Hyper-X,' or Hypersonic Experimental Vehicle, which has been developed to flight test a dual-mode ramjet/scramjet propulsion system at speeds from Mach 7 up to Mach 10 (7 to 10 times the speed of sound, which varies with temperature and altitude). Hyper-X, the flight vehicle for which is designated as X-43A, is an experimental flight-research program seeking to demonstrate airframe-integrated, 'air-breathing' engine technologies that promise to increase payload capacity for future vehicles, including hypersonic aircraft (faster than Mach 5) and reusable space launchers. This multiyear program is currently underway at NASA Dryden Flight Research Center, Edwards, California. The Hyper-X schedule calls for its first flight later this year (2000). Hyper-X is a joint program, with Dryden sharing responsibility with NASA's Langley Research Center, Hampton, Virginia. Dryden's primary role is to fly three unpiloted X-43A research vehicles to validate engine technologies and hypersonic design tools as well as the hypersonic test facility at Langley. Langley manages the program and leads the technology development effort. The Hyper-X Program seeks to significantly expand the speed boundaries of air-breathing propulsion by being the first aircraft to demonstrate an airframe-integrated, scramjet-powered free flight. Scramjets (supersonic-combustion ramjets) are ramjet engines in which the airflow through the whole engine remains supersonic. Scramjet technology is challenging because only limited testing can be performed in ground facilities. Long duration, full-scale testing requires flight research. Scramjet engines are air-breathing, capturing their oxygen from the atmosphere. Current spacecraft, such as the Space Shuttle, are rocket powered, so they must carry both fuel and oxygen for propulsion. Scramjet technology-based vehicles need to carry only fuel. By eliminating the need to carry oxygen, future hypersonic

  12. Nuclear reactions

    International Nuclear Information System (INIS)

    Corner, J.; Richardson, K.; Fenton, N.

    1990-01-01

    Nuclear reactions' marks a new development in the study of television as an agency of public policy debate. During the Eighties, nuclear energy became a major international issue. The disasters at Three-mile Island and Chernobyl created a global anxiety about its risks and a new sensitivity to it among politicians and journalists. This book is a case-study into documentary depictions of nuclear energy in television and video programmes and into the interpretations and responses of viewers drawn from many different occupational groupings. How are the complex and specialist arguments about benefit, risk and proof conveyed through the different conventions of commentary, interview and film sequence? What symbolic associations does the visual language of television bring to portrayals of the issue? And how do viewers make sense of various and conflicting accounts, connecting what they see and hear on the screen with their pre-existing knowledge, experience and 'civic' expectations. The authors examine some of the contrasting forms and themes which have been used by programme makers to explain and persuade, and then give a sustained analysis of the nature and sources of viewers' own accounts. 'Nuclear Reactions' inquires into the public meanings surrounding energy and the environment, spelling out in its conclusion some of the implications for future media treatments of this issue. It is also a key contribution to the international literature on 'television knowledge' and the processes of active viewing. (author)

  13. Combustion waves and fronts in flows flames, shocks, detonations, ablation fronts and explosion of stars

    CERN Document Server

    Clavin, Paul

    2016-01-01

    Combustion is a fascinating phenomenon coupling complex chemistry to transport mechanisms and nonlinear fluid dynamics. This book provides an up-to-date and comprehensive presentation of the nonlinear dynamics of combustion waves and other non-equilibrium energetic systems. The major advances in this field have resulted from analytical studies of simplified models performed in close relation with carefully controlled laboratory experiments. The key to understanding the complex phenomena is a systematic reduction of the complexity of the basic equations. Focusing on this fundamental approach, the book is split into three parts. Part I provides physical insights for physics-oriented readers, Part II presents detailed technical analysis using perturbation methods for theoreticians, and Part III recalls the necessary background knowledge in physics, chemistry and fluid dynamics. This structure makes the content accessible to newcomers to the physics of unstable fronts in flows, whilst also offering advanced mater...

  14. Digital front-end module (DFEM) series; Digital front end module (DFEM) series

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The digital front-end module (DFEM) is a module in which the processes ranging from the reception of digitally modulated radiofrequencies to the output of digital IF (Intermediate Frequency) signals or data streams are integrated. Beginning with a module for the MCNS (Multimedia Cable Network System) cable modem which was the first module in this business field approved by the Cable Labs, U.S., Toshiba has developed a series of DFEMs for various digital media for satellites, ground waves, and CATV (Cable Television) systems. The series is characterized by (1) the serialization of DFEMs compatible with various digital modulation techniques such as 8 PSK (Phase Shift Keying), OFDM (Orthogonal Frequency Division Multiplexing), and 256 QAM (Quadrature Amplitude Modulation), (2) easy connection with digital circuits thanks to the high shielding effect, and (3) the achievement of smaller size, higher performance, and lower power consumption. (translated by NEDO)

  15. Zero modes in discretized light-front quantization

    International Nuclear Information System (INIS)

    Martinovic, E.

    1997-01-01

    The current understanding of the role of bosonic zero modes in field-theoretical models quantized at the equal light-front time is reviewed. After a brief discussion of the main features of the light-front field theories - in particular the simplicity of the physical vacuum - the light-front canonical formalism for the quantum electrodynamics and the Yukawa model is sketched. The zero mode of Maskawa and Yamawaki is reviewed. Reasons for the appearance of the constrained and/or dynamical zero modes are explained along with the subtleties of the gauge fixing in presence of boundary conditions. Perturbative treatment of the corresponding constraint equations in the Yukawa model and quantum electrodynamics (3+1) is outlined. The next topic is the manifestation of the symmetry breaking in the light-front field theory. A pattern of multiple solutions to the zero-mode constraint equations replacing physical picture of multiple vacua of the conventionally quantized field theories is illustrated on an example of 2-dimensional theory. The importance of a (regularized) constrained zero mode of the pion field for the consistency of the Nambu-Goldstone phase of the discretized light-front linear a/model is demonstrated. Finally, a non-trivial physical vacuum based on the dynamical zero mode is constructed for the two-dimensional light-front quantum electrodynamics. (authors)

  16. Light-Front Holography and AdS/QCD Correspondence

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; de Teramond, Guy F.

    2008-04-23

    Light-Front Holography is a remarkable consequence of the correspondence between string theory in AdS space and conformal field theories in physical-space time. It allows string modes {Phi}(z) in the AdS fifth dimension to be precisely mapped to the light-front wavefunctions of hadrons in terms of a specific light-front impact variable {zeta} which measures the separation of the quark and gluonic constituents within the hadron. This mapping was originally obtained by matching the exact expression for electromagnetic current matrix elements in AdS space with the corresponding exact expression for the current matrix element using light-front theory in physical space-time. More recently we have shown that one obtains the identical holographic mapping using matrix elements of the energy-momentum tensor, thus providing an important consistency test and verification of holographic mapping from AdS to physical observables defined on the light-front. The resulting light-front Schrodinger equations predicted from AdS/QCD give a good representation of the observed meson and baryon spectra and give excellent phenomenological predictions for amplitudes such as electromagnetic form factors and decay constants.

  17. Feedback from operational experience in front-end transportation

    International Nuclear Information System (INIS)

    Mondonel, J.L.; Parison, C.

    1998-01-01

    Transport forms an integral part of the nuclear fuel cycle, representing the strategic link between each stage of the cycle. In a way there is a transport cycle that parallels the nuclear fuel cycle. This concerns particularly the front-end of the cycle whose steps - mining conversion, enrichment and fuel fabrication - require numerous transports. Back-end shipments involve a handful of countries, but front-end transports involve all five continents, and many exotic countries. All over Europe such transports are routinely performed with an excellent safety track record. Transnucleaire dominates the French nuclear transportation market and carries out both front and back-end transports. For instance in 1996 more than 28,400 front-end packages were transported as well as more than 3,600 back-end packages. However front-end transport is now a business undergoing much change. A nuclear transportation company must now cope with an evolving picture including new technical requirements, new transportation schemes and new business conditions. This paper describes the latest evolutions in terms of front-end transportation and the way this activity is carried out by Transnucleaire, and goes on to discuss future prospects. (authors)

  18. Optimal Design of HGV Front Structure for Pedestrian Safety

    Science.gov (United States)

    Ramli, Faiz Redza; Yamazaki, Koetsu

    This paper addresses a pedestrian safety design of front structure of Heavy Goods Vehicle (HGV) by two concepts; firstly by equipping a lower bumper stiffener structure under the front bumper and secondly by putting an airbag in front of the HGV front panel. In this study, HGV-pedestrian collision accident was simulated by the crash analysis solver MADYMO environment, where the HGV model with the speed of 20 km/h was collided with an adult male and with an adult female pedestrian, respectively. The bumper and lower bumper stiffener were varied their positions, while the airbag was adjusted the vent hole size and the position of airbag in front of front panel vertically. The pedestrian injuries that can be sustained during the simulation impact were limited at the critical body parts of head, chest, upper leg; an injury criteria of Head Injury Criterion (HIC), Thorax Cumulative 3ms Acceleration (C3ms) and peak loads of femur, respectively. Because of various parameters and constraints of initial conditions and injury thresholds, a multi-objective optimization design problem considered these main injury criterion is solved in order to achieve the best solution for this study. The results of optimized design parameters for each cases and conditions were obtained and the possibilities of the proposed concept were discussed.

  19. Stratified Fronts in Well-Mixed Estuaries

    Science.gov (United States)

    2013-09-01

    absences, I owe you more than I will ever be able to repay. To my daughters, Maya and Matilda, you are my joy, my light, and my happiness. I love you. xx...than those at the energy- conserving toe region [Lowe et al., 2002; Gristenko and Chubarenko, 2010]. The toe is contained laterally to the width of... conservation equation, the plunge point will conform to a line of mutual realization for hp and bp, which is referred herein as the “plunge section

  20. Uranium mobility in the natural environment - evidence from sedimentary roll-front deposits

    International Nuclear Information System (INIS)

    Deutsch, W.J.; Serne, R.J.

    1983-04-01

    Roll-front deposits consist of naturally occurring ore-grade uranium in selected sandstone aquifers throughout the world. The geochemical environment of these roll-front deposits is analogous to the environment of a radioactive waste repository containing redox-sensitive elements during its post-thermal period. The ore deposits are formed by a combination of dissolution, complexation, sorption/precipitation, and mineral formation processes. The uranium, leached from the soil by percolating rainwater, complexes with dissolved carbonate and moves in the oxidizing ground water at very low concentration (parts per billion) levels. The uranium is extracted from the leaching solution by the chemical processes, over long periods of time, at the interfaces between oxidized and reduced sediments. The Eh of the ground water associated with the reduced sediments (Eh = -100 mv to +100 mv) is higher than the Eh expected for most waste repository environments (Eh = -100 mv to -300 mv); this suggests that uranium solids will not be very soluble in the repositories. Data from in-situ leach mining and restoration of roll-front uranium deposits also provide information on the potential mobility of the waste if oxidizing ground water should enter the repository. Uranium solids probably will be initially very soluble in carbonate ground water; however, as reducing conditions are re-estblished through water/rock interactions, the uranium will reprecipitate and the amount of uranium in solution will again equilibrate with the reduced uranium minerals

  1. Spallation reactions; Reactions de spallation

    Energy Technology Data Exchange (ETDEWEB)

    Cugon, J.

    1996-12-31

    Spallation reactions dominate the interactions of hadrons with nuclei in the GeV range (from {approx} 0.1 to {approx} 10 GeV). They correspond to a sometimes important ejection of light particles leaving most of the time a residue of mass commensurate with the target mass. The main features of the experimental data are briefly reviewed. The most successful theoretical model, namely the intranuclear cascade + evaporation model, is presented. Its physical content, results and possible improvements are critically discussed. Alternative approaches are shortly reviewed. (author). 84 refs.

  2. The movement of a redox front downstream from a repository for nuclear waste

    International Nuclear Information System (INIS)

    Neretnieks, I.

    1982-01-01

    In a final repository for nuclear waste it is envisaged that the waste will eventually come in contact with water. When this happens the α-radiation will radiolyse water. The main products will be hydrogen and hydrogen peroxide. The hydrogen is fairly nonreactive and will be transported away by diffusion and convection. The hydrogen peroxide is a strong oxidizing agent and will oxidize any ferrous iron it encounters to ferric iron. This will change the electrochemical potential of the water in the region, from reducing to oxidizing conditions. In oxidizing waters many of the potentially hazardeous radionuclides - actinides and technetium - will have a high solubility and low sorption compared to conditions. The movement of the redox front along the fissures downstream of a repository has been investigated theoretically. The rock is modelled as having parallel fissures where the water flows. The rock matrix has a connected porosity into which the hydrogen peroxide diffuses and quickly reacts with the minerals containing ferrous iron. The movements of the sharp boundary between oxidizing and reducing conditions in the fissures as well as in the matrix of the rock is described mathematically. A calculated example based on expected flowrate of water, rate of α-radiolysis, fissure spacing and measured values of matrix diffusivity and ferrous iron content of the bedrock is made. The results indicate that under some conditions the redox front may move tens of meters downstraem during 10 6 years in fairly good rock, poor in ferrous iron. It is conceivable that the extension of the redox front is larger as well as shorter because many of the importhat factors governing teh front movement may vary considerably. (Author)

  3. Catalytic Organometallic Reactions of Ammonia

    Science.gov (United States)

    Klinkenberg, Jessica L.

    2012-01-01

    Until recently, ammonia had rarely succumbed to catalytic transformations with homogeneous catalysts, and the development of such reactions that are selective for the formation of single products under mild conditions has encountered numerous challenges. However, recently developed catalysts have allowed several classes of reactions to create products with nitrogen-containing functional groups from ammonia. These reactions include hydroaminomethylation, reductive amination, alkylation, allylic substitution, hydroamination, and cross-coupling. This Minireview describes examples of these processes and the factors that control catalyst activity and selectivity. PMID:20857466

  4. LHCb: Test Station for the LHCb Muon Front-End Electronic

    CERN Multimedia

    Polycarpo, E

    2005-01-01

    The LHCb Muon Group has developed the CMOS ASIC CARIOCA to readout its Multiwire Proportional Chambers (MWPC) and GEM detectors, using a rad-hard IBM 0.25um process. Each ASIC holds 8 identical current-mode ASDB channels with individual input thresholds. The Muon detector contains around 120000 physical channels, requiring production of 20000 front-end chips, roughly. CARIOCA has been developed to process MWPC cathode and anode signals and two different versions have been implemented to overcome the requirement of MWP and GEM chambers operation. The test station has been devised to accomplish bipolar tests and to measure characteristics of both CARIOCA versions.

  5. Paleogene Sediment Character of Mountain Front Central Sumatra Basin

    Directory of Open Access Journals (Sweden)

    P. A. Suandhi

    2014-07-01

    Full Text Available DOI: 10.17014/ijog.v8i3.164The SE-NW trending Mountain Front of Central Sumatra Basin is located in the southern part of the basin. The Mountain Front is elongated parallel to the Bukit Barisan Mountain, extending from the Regencies of North Padang Lawas (Gunung Tua in the northwest, Rokan Hulu, Kampar, Kuantan Singingi, and Inderagiri Hulu Regency in the southeast. The Palaeogene sediments also represent potential exploration objectives in Central Sumatra Basin, especially in the mountain front area. Limited detailed Palaeogene sedimentology information cause difficulties in hydrocarbon exploration in this area. Latest age information and attractive sediment characters based on recent geological fieldwork (by chaining method infer Palaeogene sediment potential of the area. The Palaeogene sedimentary rock of the mountain front is elongated from northwest to southeast. Thickness of the sedimentary unit varies between 240 - 900 m. Palynology samples collected recently indicate that the oldest sedimentary unit is Middle Eocene and the youngest one is Late Oligocene. This latest age information will certainly cause significant changes to the existing surface geological map of the mountain front area. Generally, the Palaeogene sediments of the mountain front area are syn-rift sediments. The lower part of the Palaeogene deposit consists of fluvial facies of alluvial fan and braided river facies sediments. The middle part consists of fluvial meandering facies, lacustrine delta facies, and turbidity lacustrine facies sediments. The upper part consists of fluvial braided facies and transitional marine facies sediments. Volcanism in the area is detected from the occurrence of volcanic material as lithic material and spotted bentonite layers in the middle part of the mountain front area. Late rifting phase is indicated by the presence of transitional marine facies in the upper part of the Palaeogene sediments.

  6. Chain reaction

    International Nuclear Information System (INIS)

    Balogh, Brian.

    1991-01-01

    Chain Reaction is a work of recent American political history. It seeks to explain how and why America came to depend so heavily on its experts after World War II, how those experts translated that authority into political clout, and why that authority and political discretion declined in the 1970s. The author's research into the internal memoranda of the Atomic Energy Commission substantiates his argument in historical detail. It was not the ravages of American anti-intellectualism, as so many scholars have argued, that brought the experts back down to earth. Rather, their decline can be traced to the very roots of their success after World War II. The need to over-state anticipated results in order to garner public support, incessant professional and bureaucratic specialization, and the sheer proliferation of expertise pushed arcane and insulated debates between experts into public forums at the same time that a broad cross section of political participants found it easier to gain access to their own expertise. These tendencies ultimately undermined the political influence of all experts. (author)

  7. Virulence evolution at the front line of spreading epidemics.

    Science.gov (United States)

    Griette, Quentin; Raoul, Gaël; Gandon, Sylvain

    2015-11-01

    Understanding and predicting the spatial spread of emerging pathogens is a major challenge for the public health management of infectious diseases. Theoretical epidemiology shows that the speed of an epidemic is governed by the life-history characteristics of the pathogen and its ability to disperse. Rapid evolution of these traits during the invasion may thus affect the speed of epidemics. Here we study the influence of virulence evolution on the spatial spread of an epidemic. At the edge of the invasion front, we show that more virulent and transmissible genotypes are expected to win the competition with other pathogens. Behind the front line, however, more prudent exploitation strategies outcompete virulent pathogens. Crucially, even when the presence of the virulent mutant is limited to the edge of the front, the invasion speed can be dramatically altered by pathogen evolution. We support our analysis with individual-based simulations and we discuss the additional effects of demographic stochasticity taking place at the front line on virulence evolution. We confirm that an increase of virulence can occur at the front, but only if the carrying capacity of the invading pathogen is large enough. These results are discussed in the light of recent empirical studies examining virulence evolution at the edge of spreading epidemics. © 2015 The Author(s). Evolution © 2015 The Society for the Study of Evolution.

  8. Submesoscale CO2 variability across an upwelling front off Peru

    Science.gov (United States)

    Köhn, Eike E.; Thomsen, Sören; Arévalo-Martínez, Damian L.; Kanzow, Torsten

    2017-12-01

    As a major source for atmospheric CO2, the Peruvian upwelling region exhibits strong variability in surface fCO2 on short spatial and temporal scales. Understanding the physical processes driving the strong variability is of fundamental importance for constraining the effect of marine emissions from upwelling regions on the global CO2 budget. In this study, a frontal decay on length scales of 𝒪(10 km) was observed off the Peruvian coast following a pronounced decrease in down-frontal (equatorward) wind speed with a time lag of 9 h. Simultaneously, the sea-to-air flux of CO2 on the inshore (cold) side of the front dropped from up to 80 to 10 mmol m-2 day-1, while the offshore (warm) side of the front was constantly outgassing at a rate of 10-20 mmol m-2 day-1. Based on repeated ship transects the decay of the front was observed to occur in two phases. The first phase was characterized by a development of coherent surface temperature anomalies which gained in amplitude over 6-9 h. The second phase was characterized by a disappearance of the surface temperature front within 6 h. Submesoscale mixed-layer instabilities were present but seem too slow to completely remove the temperature gradient in this short time period. Dynamics such as a pressure-driven gravity current appear to be a likely mechanism behind the evolution of the front.

  9. Light-front QCD. II. Two-component theory

    International Nuclear Information System (INIS)

    Zhang, W.; Harindranath, A.

    1993-01-01

    The light-front gauge A a + =0 is known to be a convenient gauge in practical QCD calculations for short-distance behavior, but there are persistent concerns about its use because of its ''singular'' nature. The study of nonperturbative field theory quantizing on a light-front plane for hadronic bound states requires one to gain a priori systematic control of such gauge singularities. In the second paper of this series we study the two-component old-fashioned perturbation theory and various severe infrared divergences occurring in old-fashioned light-front Hamiltonian calculations for QCD. We also analyze the ultraviolet divergences associated with a large transverse momentum and examine three currently used regulators: an explicit transverse cutoff, transverse dimensional regularization, and a global cutoff. We discuss possible difficulties caused by the light-front gauge singularity in the applications of light-front QCD to both old-fashioned perturbative calculations for short-distance physics and upcoming nonperturbative investigations for hadronic bound states

  10. River networks and ecological corridors: Reactive transport on fractals, migration fronts, hydrochory

    Science.gov (United States)

    Bertuzzo, E.; Maritan, A.; Gatto, M.; Rodriguez-Iturbe, I.; Rinaldo, A.

    2007-04-01

    Moving from a recent quantitative model of the US colonization in the 19th century that relies on analytical and numerical results of reactive-diffusive transport on fractal river networks, this paper considers its generalization to include an embedded flow direction which biases transport. We explore the properties of biased reaction-dispersal models, in which the reaction rates are described by a logistic equation. The relevance of the work is related to the prediction of the role of hydrologic controls on invasion processes (of species, populations, propagules, or infective agents, depending on the specifics of reaction and transport) occurring in river basins. Exact solutions are obtained along with general numerical solutions, which are applied to fractal constructs like Peano basins and real rivers. We also explore similarities and departures from different one-dimensional invasion models where a bias is added to both the diffusion and the telegraph equations, considering their respective ecological insight. We find that the geometrical constraints imposed by the fractal networks imply strong corrections on the speed of traveling fronts that can be enhanced or smoothed by the bias. Applications to real river networks show that the chief morphological parameters affecting the front speed are those characterizing the node-to-node distances measured along the network structure. The spatial density and number of reactive sites thus prove to be a vital hydrologic control on invasions. We argue that our solutions, currently tied to the validity of the logistic growth, might be relevant to the general study of species' spreading along ecological corridors defined by the river network structure.

  11. Online monitoring of chemical reactions by polarization-induced electrospray ionization.

    Science.gov (United States)

    Meher, Anil Kumar; Chen, Yu-Chie

    2016-09-21

    Polarization-induced electrospray ionization (PI-ESI) is a simple technique for instant generation of gas-phase ions directly from a microliter-sized droplet for mass spectrometric analysis. A sample droplet was placed over a dielectric substrate and in proximity (2-3 mm) to the inlet of a mass spectrometer. Owing to the polarization effect induced by the high electric field provided by the mass spectrometer, the droplet was polarized and the electrospray was generated from the apex of the droplet. The polarization-induced electrospray could last for tens of seconds, which was sufficiently long to monitor fast reactions occurring within few seconds. Thus, we demonstrated the feasibility of using the droplet-based PI-ESI MS for the online monitoring of fast reactions by simply mixing two droplets (5-10 μL) containing reactants on a dielectric substrate placed in front of a mass spectrometer applied with a high voltage (-4500 V). Schiff base reactions and oxidation reactions that can generate intermediates/products within a few seconds were selected as the model reactions. The ionic reaction species generated from intermediates and products can be simultaneously monitored by PI-ESI MS in real time. We also used this approach to selectively detect acetone from a urine sample, in which acetone was derivatized in situ. In addition, the possibility of using this approach for quantitative analysis of acetone from urine samples was examined. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. Light-front field theory in the description of hadrons

    Directory of Open Access Journals (Sweden)

    Ji Chueng-Ryong

    2017-01-01

    Full Text Available We discuss the use of light-front field theory in the descriptions of hadrons. In particular, we clarify the confusion in the prevailing notion of the equivalence between the infinite momentum frame and the light-front dynamics and the advantage of the light-front dynamics in hadron physics. As an application, we present our recent work on the flavor asymmetry in the proton sea and identify the presence of the delta-function contributions associated with end-point singularities arising from the chiral effective theory calculation. The results pave the way for phenomenological applications of pion cloud models that are manifestly consistent with the chiral symmetry properties of QCD.

  13. Methods for enhancing mapping of thermal fronts in oil recovery

    Science.gov (United States)

    Lee, D.O.; Montoya, P.C.; Wayland, J.R. Jr.

    1984-03-30

    A method for enhancing the resistivity contrasts of a thermal front in an oil recovery production field as measured by the controlled source audio frequency magnetotelluric (CSAMT) technique is disclosed. This method includes the steps of: (1) preparing a CSAMT-determined topological resistivity map of the production field; (2) introducing a solution of a dopant material into the production field at a concentration effective to alter the resistivity associated with the thermal front; said dopant material having a high cation exchange capacity which might be selected from the group consisting of montmorillonite, illite, and chlorite clays; said material being soluble in the conate water of the production field; (3) preparing a CSAMT-determined topological resistivity map of the production field while said dopant material is moving therethrough; and (4) mathematically comparing the maps from step (1) and step (3) to determine the location of the thermal front. This method is effective with the steam flood, fire flood and water flood techniques.

  14. General motors front wheel drive 2-mode hybrid transmission

    Energy Technology Data Exchange (ETDEWEB)

    Hendrickson, James [General Motors Corp., Pontiac, MI (United States). New Transmission Products Group.; Holmes, Alan G. [General Motors Corp., Pontiac, MI (United States). Powertrain Hybrid Architecture

    2009-07-01

    General Motors now expands the application of two-mode hybrid technology to front wheel drive vehicles with the development of a hybrid electric transmission packaged into essentially the same space as a conventional automatic transmission for front wheel drive. This was accomplished using a space-efficient arrangement based on two planetary gear sets and electric motor-generators with large internal diameters. A combination of damper and hydraulically-controlled clutch allow comfortable shutdown and restarting of large-displacement engines in front wheel drive vehicles. The hybrid system delivers electric low-speed urban driving, two continuously variable ranges of transmission speed ratios, four fixed transmission speed ratios, electric acceleration boosting, and regenerative braking. In the first vehicle application, the two-mode hybrid helps to reduce vehicle fuel consumption by approximately one-third. (orig.)

  15. Concepts for a Muon Accelerator Front-End

    Energy Technology Data Exchange (ETDEWEB)

    Stratakis, Diktys [Fermilab; Berg, Scott [Brookhaven; Neuffer, David [Fermilab

    2017-03-16

    We present a muon capture front-end scheme for muon based applications. In this Front-End design, a proton bunch strikes a target and creates secondary pions that drift into a capture channel, decaying into muons. A series of rf cavities forms the resulting muon beams into a series of bunches of differerent energies, aligns the bunches to equal central energies, and initiates ionization cooling. We also discuss the design of a chicane system for the removal of unwanted secondary particles from the muon capture region and thus reduce activation of the machine. With the aid of numerical simulations we evaluate the performance of this Front-End scheme as well as study its sensitivity against key parameters such as the type of target, the number of rf cavities and the gas pressure of the channel.

  16. FRONT AXLE OF MERCEDES AMG GT. MODELLING IN AUTODESK INVENTOR

    Directory of Open Access Journals (Sweden)

    COROLENCU Eduard – Narcis

    2017-05-01

    Full Text Available This paper analyzes the front axle of the Mercedes AMG GT model, as so as the graphical representation of the axle and of the subassemblies of suspension system and steering system, using the AutoCAD and Autodesk Inventor software. The paper include the steps for made the 3D model of the front axle in order to highlight the advantages of suspension and steering system, the function of this systems and methods for manufacturing of these. The 3D model presents a suite of complex surfaces. This type of surfaces is often designed with non-analytical means. The main commands and options used in Autodesk Inventor software were presented and explained. All the component parts of the front axle were modelled and assembled according to their functional role. Finally, the models were rendered in order to have a realistic appearance.

  17. Selenium-containing indolyl compounds

    DEFF Research Database (Denmark)

    Casaril, Angela M; Ignasiak, Marta T; Chuang, Christine Y

    2017-01-01

    materials, including extracellular matrix (ECM) proteins, within the artery wall. Here we investigated the potential of selenium-containing indoles to afford protection against these oxidants, by determining rate constants (k) for their reaction, and quantifying the extent of damage on isolated ECM proteins......Tyr on HCAEC-ECM were also reduced. These data demonstrate that the novel selenium-containing compounds show high reactivity with oxidants and may modulate oxidative and nitrosative damage at sites of inflammation, contributing to a reduction in tissue dysfunction and atherogenesis....

  18. Light-front dynamics of Chern-Simons systems

    International Nuclear Information System (INIS)

    Srivastava, P.P.

    1994-10-01

    The Chern-Simons theory coupled to complex scalars is quantized on the light-front in the local light-cone gauge by constructing the self-consistent Hamiltonian theory. It is shown that no inconsistency arises on using two local gauge-fixing conditions in the Dirac procedure. The light-front Hamiltonian turns out to be simple and the framework may be useful to construct renormalized field theory of particles with fractional statistics (anyons). The theory is shown to be relativistic and the extra term in the transformation of the matter field under space rotations, interpreted in previous works as anomaly, is argued to be gauge artefact. (author). 20 refs

  19. Front Range Forest Health Partnership Phase 1 feasibility study

    Energy Technology Data Exchange (ETDEWEB)

    Volkin, P

    1998-09-01

    The Front Range Forest Health Partnership is an alliance of individuals, citizen groups, federal, state, private, and nonprofit organizations that formed to promote forest health restoration and reduce fire risks on Colorado's Front Range. The partnership promotes selective thinning to restore forest health and supports economically feasible end uses for wood waste materials. The Phase I study was initiated to determine the environmental and economic feasibility of using wood wastes from forested and urban areas for the production of fuel-grade ethanol.

  20. CMOS front-end electronics for radiation sensors

    CERN Document Server

    AUTHOR|(CDS)2071026

    2015-01-01

    This book offers a comprehensive treatment of front-end electronics for radiation detection. It discusses the fundamental principles of signal processing for radiation detectors and describes circuits at the level of functional building blocks, omitting transistor-level implementation. It also covers important system-level topics commonly found in the world of front-end electronics for radiation sensors. The book develops the topics in detail, with a constant focus on practical problems. It also provides real implementation examples that offer insights and stimuli for more experienced engineers already working in the field.

  1. Light-front view of the axial anomaly

    International Nuclear Information System (INIS)

    Ji, C.; Rey, S.

    1996-01-01

    Motivated by an apparent puzzle of the light-front vacua incompatible with the axial anomaly, we have considered the two-dimensional massless Schwinger model for an arbitrary interpolating angle of Hornbostel close-quote s interpolating quantization surface. By examining spectral deformation of the Dirac sea under an external electric field semiclassically, we have found that the axial anomaly is quantization angle independent. This indicates an intricate nontrivial vacuum structure present even in the light-front limit. copyright 1996 The American Physical Society

  2. Differential sensor in front photopyroelectric technique: II. Experimental

    International Nuclear Information System (INIS)

    Ivanov, R; Moreno, I; Araujo-Andrade, C; MarIn, E; Cruz-Orea, A; Pichardo-Molina, J L

    2009-01-01

    We describe the differential cell design and the experimental (optical and electronic) setup for the differential front photopyroelectric technique, whose theory has been developed in the first part of this paper (Ivanov et al 2008 J. Phys. D: Appl. Phys. 41 085106). We will show first how the direct (non-differential) front photopyroelectric theory described in our previous paper reproduces well the experimental results. The usefulness of the differential technique is demonstrated by means of experimental measurements of the thermal effusivity in binary ethanol-water and glycerol-water mixtures, based on a theoretical methodology that simplifies the measurement procedure and diminishes the experimental uncertainty.

  3. Differential sensor in front photopyroelectric technique: II. Experimental

    Energy Technology Data Exchange (ETDEWEB)

    Ivanov, R; Moreno, I; Araujo-Andrade, C [Facultad de Fisica, Universidad Autonoma de Zacatecas, Calz. Solidaridad Esquina Paseo de la Bufa s/n, CP 98060, Zacatecas, Zac. (Mexico); MarIn, E [Centro de Investigacion en Ciencia Aplicada y TecnologIa Avanzada-Instituto Politecnico Nacional, Legaria 694, Col. Irrigacion, CP 11500, Mexico D.F. (Mexico); Cruz-Orea, A [Departamento de Fisica, CINVESTAV-IPN, Av. IPN No. 2508, Col. San Pedro Zacatenco, CP 07360, Mexico D.F. (Mexico); Pichardo-Molina, J L, E-mail: rumen@fisica.uaz.edu.m [Centro de Investigaciones en Optica, Loma del Bosque 115, Loma del Campestre, CP 37150, Leon, Guanajuato (Mexico)

    2009-06-21

    We describe the differential cell design and the experimental (optical and electronic) setup for the differential front photopyroelectric technique, whose theory has been developed in the first part of this paper (Ivanov et al 2008 J. Phys. D: Appl. Phys. 41 085106). We will show first how the direct (non-differential) front photopyroelectric theory described in our previous paper reproduces well the experimental results. The usefulness of the differential technique is demonstrated by means of experimental measurements of the thermal effusivity in binary ethanol-water and glycerol-water mixtures, based on a theoretical methodology that simplifies the measurement procedure and diminishes the experimental uncertainty.

  4. Rotational covariance and light-front current matrix elements

    International Nuclear Information System (INIS)

    Keister, B.D.

    1994-01-01

    Light-front current matrix elements for elastic scattering from hadrons with spin 1 or greater must satisfy a nontrivial constraint associated with the requirement of rotational covariance for the current operator. Using a model ρ meson as a prototype for hadronic quark models, this constraint and its implications are studied at both low and high momentum transfers. In the kinematic region appropriate for asymptotic QCD, helicity rules, together with the rotational covariance condition, yield an additional relation between the light-front current matrix elements

  5. Overtopping of Rubble Mound Breakwaters with Front Reservoir

    DEFF Research Database (Denmark)

    Burcharth, Hans F.; Andersen, Thomas Lykke

    2007-01-01

    The design and performance of breakwaters with front reservoir are discussed on the basis of physical 2-D model tests with a number of cross sections, in which vertopping discharge and spatial distribution, wave forces on inner parapet walls, and stability of reservoir armour were studied....... The sensitivity of these quantities to the width of the reservoir is discussed. It is demonstrated that front reservoir solutions are more economical than conventional cross section solutions, such as bermed structures and mild slope structures, in cases where low crests and small overtopping discharges...

  6. REASONING IN THE FUZZY FRONT END OF INNOVATION:

    DEFF Research Database (Denmark)

    Haase, Louise Møller; Laursen, Linda Nhu

    2018-01-01

    in the fuzzy front end is the reasoning process: innovation teams are faced with open-ended, ill-defined problems, where they need to make decisions about an unknown future but have only incomplete, ambiguous and contradicting insights available. We study the reasoning of experts, how they frame to make sense...... of all the insights and create a basis for decision-making in relation to a new project. Based on case studies of five innovative products from various industries, we propose a Product DNA model for understanding the reasoning in the fuzzy front end of innovation. The Product DNA Model explains how...... experts reason and what direct their reasoning....

  7. Observations of the Ushant tidal front in September 2007

    OpenAIRE

    Le Boyer, A.; Cambon, Gildas; Daniault, N.; Herbette, Steven; Le Cann, B.; Marie, Louis; Morin, P.

    2009-01-01

    The Ushant tidal front is the dominant feature of the summer season hydrological structure of the Iroise Sea. It separates tidally mixed coastal waters from thermally stratified open Celtic Sea waters. This article reports on observations made in September 2007 during two short cruises that took place aboard R/V "Cotes de la Manche", and gives a general account of the physical structure of the front along one cross-frontal transect. The data set comprises data from a 4 month ADCP mooring, sho...

  8. Rippled shock front solutions for testing hydrodynamic stability simulations

    International Nuclear Information System (INIS)

    Munro, D.H.

    1989-01-01

    The response of a shock front to arbitrary small perturbations can be calculated analytically. Such rippled shock front solutions are useful for determining the accuracy of hydrodynamic simulation codes such as LASNEX [Comments Plasma Phys. Controlled Fusion 2, 51 (1977)], which are used to compute perturbation growth in inertial fusion targets. The LASNEX fractional errors are of order κ 2 L 2 , where κ is the transverse wavenumber of the perturbation, and L is the largest zone dimension. Numerical errors are about 25% for a calculation using 26 zones per transverse wavelength

  9. Stability of negative ionization fronts: Regularization by electric screening?

    International Nuclear Information System (INIS)

    Arrayas, Manuel; Ebert, Ute

    2004-01-01

    We recently have proposed that a reduced interfacial model for streamer propagation is able to explain spontaneous branching. Such models require regularization. In the present paper we investigate how transversal Fourier modes of a planar ionization front are regularized by the electric screening length. For a fixed value of the electric field ahead of the front we calculate the dispersion relation numerically. These results guide the derivation of analytical asymptotes for arbitrary fields: for small wave-vector k, the growth rate s(k) grows linearly with k, for large k, it saturates at some positive plateau value. We give a physical interpretation of these results

  10. Multiple stable isotope fronts during non-isothermal fluid flow

    Science.gov (United States)

    Fekete, Szandra; Weis, Philipp; Scott, Samuel; Driesner, Thomas

    2018-02-01

    Stable isotope signatures of oxygen, hydrogen and other elements in minerals from hydrothermal veins and metasomatized host rocks are widely used to investigate fluid sources and paths. Previous theoretical studies mostly focused on analyzing stable isotope fronts developing during single-phase, isothermal fluid flow. In this study, numerical simulations were performed to assess how temperature changes, transport phenomena, kinetic vs. equilibrium isotope exchange, and isotopic source signals determine mineral oxygen isotopic compositions during fluid-rock interaction. The simulations focus on one-dimensional scenarios, with non-isothermal single- and two-phase fluid flow, and include the effects of quartz precipitation and dissolution. If isotope exchange between fluid and mineral is fast, a previously unrecognized, significant enrichment in heavy oxygen isotopes of fluids and minerals occurs at the thermal front. The maximum enrichment depends on the initial isotopic composition of fluid and mineral, the fluid-rock ratio and the maximum change in temperature, but is independent of the isotopic composition of the incoming fluid. This thermally induced isotope front propagates faster than the signal related to the initial isotopic composition of the incoming fluid, which forms a trailing front behind the zone of transient heavy oxygen isotope enrichment. Temperature-dependent kinetic rates of isotope exchange between fluid and rock strongly influence the degree of enrichment at the thermal front. In systems where initial isotope values of fluids and rocks are far from equilibrium and isotope fractionation is controlled by kinetics, the temperature increase accelerates the approach of the fluid to equilibrium conditions with the host rock. Consequently, the increase at the thermal front can be less dominant and can even generate fluid values below the initial isotopic composition of the input fluid. As kinetics limit the degree of isotope exchange, a third front may

  11. Osteoma in a blue-fronted Amazon parrot (Amazona aestiva).

    Science.gov (United States)

    Cardoso, João Felipe Rito; Levy, Marcelo Guilherme Bezerra; Liparisi, Flavia; Romão, Mario Antonio Pinto

    2013-09-01

    Osteoma is an uncommon bone formation documented in avian species and other animals. A blue-fronted Amazon parrot (Amazona aestiva) with clinical respiratory symptoms was examined because of a hard mass present on the left nostril. Radiographs suggested a bone tumor, and the mass was surgically excised. Histopathologic examination revealed features of an osteoma. To our knowledge, this is the first description of an osteoma in a blue-fronted Amazon parrot. Osteoma should be considered as a differential diagnosis in birds with respiratory distress and swelling of the nostril.

  12. General characteristics of current in front of Port Said, Egypt

    Directory of Open Access Journals (Sweden)

    Mohamed S. Elsharkawy

    2017-06-01

    Full Text Available This paper is a preliminary investigation of the general characteristics of the current in front of the coastal Mediterranean city: Port Said, Egypt. The study of the current regime in front of Port Said helps environmental engineers to tackle problems as marine port sedimentation and shoreline changes. Surface and bottom current recordings at a single offshore station of depth 104 m located at 31° 34.90′ N, 32° 30.01′ E have been subject to statistical analysis. The measurements showed unexpectedly that bottom currents were relatively stronger than surface currents during May-99.

  13. 11. El avance del Front National en Francia

    OpenAIRE

    Ferrer Sánchez, Albert

    2016-01-01

    Este artículo tiene por objeto analizar las causas del ascenso electoral de la formación ultraderechista francesa Front National (FN). En primer lugar, estudia la evolución política de dicho partido a fin de mostrar los cambios y las continuidades de su estrategia, su programa y sus discursos. Una vez analizados el contenido, la oferta política del nuevo Front National y el contexto político y social de Francia, muestra las razones por las cuales la formación ultraderechista se ha convertido ...

  14. Front-end electronics for the upgraded GMRT

    International Nuclear Information System (INIS)

    Raut, Anil N; Bhalerao, Vilas; Kumar, A Praveen

    2013-01-01

    This paper first describes briefly the existing front-end receiver in use at the GMRT observatory and then details the ongoing development of next generation receiver systems for the upgraded GMRT. It covers the design of the new, two stage, room temperature, low noise amplifiers with better noise performance and matching, and improved dynamic range that are being implemented for the 130–260 MHz, 250–500 MHz and 550–900 MHz bands of the upgraded GMRT front-end systems.

  15. Reaction chemistry of nitrogen species in hydrothermal systems: Simple reactions, waste simulants, and actual wastes

    International Nuclear Information System (INIS)

    Dell'Orco, P.; Luan, L.; Proesmans, P.; Wilmanns, E.

    1995-01-01

    Results are presented from hydrothermal reaction systems containing organic components, nitrogen components, and an oxidant. Reaction chemistry observed in simple systems and in simple waste simulants is used to develop a model which presents global nitrogen chemistry in these reactive systems. The global reaction path suggested is then compared with results obtained for the treatment of an actual waste stream containing only C-N-0-H species

  16. Density-wave fronts on the brink of wet granular condensation

    Science.gov (United States)

    Huang, Kai; Zippelius, Andreas; Sand lab @ University of Bayreuth Team

    2017-11-01

    From sand dunes to Faraday heaping, driven granular matter, i.e., large agglomeration of macroscopic particles, is rich pattern forming system. When a granular material is partially wet (e.g., wet sand on the beach), a different pattern forming scenario arises due to the cohesive particle-particle interactions. Here, we focus on the formation of density-wave fronts in an oscillated wet granular layer undergoing a gas-liquid-like transition. The threshold of the instability is governed by the amplitude of the vertical vibrations. Fronts, which are curved into a spiral shape, propagate coherently along the circular rim of the container with leading edges. They are stable beyond a critical distance from the container center. Based on the measurement of the critical distance and the rotation frequency, we propose a model for the pattern formation by considering the competition between the time scale for the collapse of cohesive particles and that of the energy injection resisting this process. Deutsche Forschungsgemeinschaft (Grant No. HU1939 4-1).

  17. Behavior of fragmentation front in a porous viscoelastic material

    Science.gov (United States)

    Ichihara, M.; Takayama, K.

    2002-12-01

    We are developing laboratory experiments to investigate dynamics of magma fragmentation during explosive volcanic eruptions. Fragmentation of such a mixture as magma consisting of viscoelastic melt, bubbles and solid particles, is not known yet, and experiments are necessary to establish a mathematical model. It has been shown that viscoelastic silicone compound (Dow Corning 3179) is a useful analogous material to simulate magma fragmentation. In the previous work, a porous specimen made of the compound was rapidly decompressed and development of brittle fragmentation was observed. However, there were arguments that the experiment was different from actual processes which produce fragments as small as volcanic ash, because in the experiment the specimen was broken into only several pieces. This time, results of the improved experiments are presented. The experimental apparatus is a kind of a vertical shock tube, which mainly consists of a high pressure test section and low pressure chambers. The test section is made of acrylic tube of which inner diameter is 25 mm. The internal phenomenon is recorded by a high-speed video camera. Pressure is measured in the gas above and beneath the specimen by piezoelectric transducers. The specimen is prepared in the following way. First, an acrylic tube filled with the compound is put in a nitrogen tank and kept at 45 bar for more than 8 hours. The compound absorbs the gas and equilibrates with the nitrogen. Next, the tank is decompressed back to the atmospheric pressure slowly. Nitrogen exsolves and bubbles are formed in the compound quite uniformly. Finally, the expanded compound sticking out of both ends of the tube is cut down, and the tube containing the specimen is attached to the shock tube. The specimen is rapidly decompressed by 24, 16, and 8 bars. The high-speed video images demonstrate a sequence of the fragmentation process. We observe propagation of a clear fracture front at 50 m/s for 24 bar of decompression and at

  18. Catalyst Initiation in the Oscillatory Carbonylation Reaction

    Directory of Open Access Journals (Sweden)

    Katarina Novakovic

    2011-01-01

    Full Text Available Palladium(II iodide is used as a catalyst in the phenylacetylene oxidative carbonylation reaction that has demonstrated oscillatory behaviour in both pH and heat of reaction. In an attempt to extract the reaction network responsible for the oscillatory nature of this reaction, the system was divided into smaller parts and they were studied. This paper focuses on understanding the reaction network responsible for the initial reactions of palladium(II iodide within this oscillatory reaction. The species researched include methanol, palladium(II iodide, potassium iodide, and carbon monoxide. Several chemical reactions were considered and applied in a modelling study. The study revealed the significant role played by traces of water contained in the standard HPLC grade methanol used.

  19. Non-equilibrium dynamics due to moving deflagration front at RDX/HTPB interface

    Science.gov (United States)

    Chaudhuri, Santanu; Joshi, Kaushik; Lacevic, Naida

    Reactive dissipative particle dynamics (DPD-RX), a promising tool in characterizing the sensitivity and performance of heterogeneous solid propellants like polymer bonded explosives (PSXs), requires further testing for non-equilibrium dynamics. It is important to understand detailed atomistic chemistry for developing coarse grain reactive models needed for the DPD-RX. In order to obtain insights into combustion chemistry of RDX/HTPB binder, we used reactive molecular dynamics (RMD) to obtain energy up-pumping and reaction mechanisms at RDX/HTPB interface when exposed to a self-sustaining deflagration front. Hot spots are ignited near and away from the heterogeneous interface using the thermal pulse. The results show that the hot spot near interface significantly delays the transition from ignition to deflagration. We will present the mechanical response and the combustion chemistry of HTPB when the propagating deflagration front hits the polymer binder. We will discuss our efforts to incorporate this RMD based chemistry into the DPD-RX which will enable us to perform such non-equilibrium dynamics simulations on large-length scale with microstructural heterogeneities. Funding from DTRA Grant Number HDTRA1-15-1-0034 is acknowledged.

  20. Mechanism of formation of subnanosecond current front in high-voltage pulse open discharge

    Science.gov (United States)

    Schweigert, I. V.; Alexandrov, A. L.; Zakrevsky, Dm. E.; Bokhan, P. A.

    2014-11-01

    The mechanism of subnanosecond current front rise observed previously in the experiment in high-voltage pulse open discharge in helium is studied in kinetic particle-in-cell simulations. The Boltzmann equations for electrons, ions, and fast atoms are solved self-consistently with the Poisson equations for the electrical potential. The partial contributions to the secondary electron emission from the ions, fast atoms, photons, and electrons, bombarding the electrode, are calculated. In simulations, as in the experiment, the discharge glows between two symmetrical cathodes and the anode grid in the midplane at P =6 Torr and the applied voltage of 20 kV. The electron avalanche development is considered for two experimental situations during the last stage of breakdown: (i) with constant voltage and (ii) with decreasing voltage. For case (i), the subnanosecond current front rise is set by photons from the collisional excitation transfer reactions. For the case (ii), the energetic electrons swamp the cathode during voltage drop and provide the secondary electron emission for the subnanosecond current rise, observed in the experiment.

  1. Realization of a neural algorithm by means of front-propagation in a thyristor-based hybrid system

    CERN Document Server

    Niedernostheide, F J; Freyd, O; Bode, M; Gorbatyuk, A V

    2003-01-01

    Propagating fronts are generic structures in a bistable diffusion-driven system and can be used to realize neural algorithms, as e.g., the Kohonen or the neural-gas algorithm. We present an analog-digital hybrid system based on a thyristor-like structure with several gate terminals. This structure represents the continuous part in which a propagating front, separating a region of high current density from a region of low current density, is used to control the learning process of the neural algorithm. With a system containing five neurons and five gates in a quasi one-dimensional arrangement it is demonstrated that an efficient parallel operating learning process can be realized by using the winner-take-all principle and the front propagation, i.e. exploiting the intrinsic dynamics of the semiconductor device. Finally, numerical and analytical investigations of the dependency of the front velocity and its width on the load current have been performed since these are essential parameters for improving the netw...

  2. Design of ultralow power receiver front-ends for 2.4 GHz wireless sensor network applications

    International Nuclear Information System (INIS)

    Zhang Meng; Li Zhiqun; Wang Zengqi; Wu Chenjian; Chen Liang

    2014-01-01

    This paper presents the design of an ultralow power receiver front-end designed for a wireless sensor network (WSN) in a 0.18 μm CMOS process. The author designs two front-ends working in the saturation region and the subthreshold region respectively. The front-ends contain a two-stage cross-coupling cascaded common-gate (CG) LNA and a quadrature Gilbert IQ mixer. The measured conversion gain is variable with high gain at 24 dB and low gain at 7 dB for the saturation one, and high gain at 22 dB and low gain at 5 dB for the subthreshold one. The noise figure (NF) at high gain mode is 5.1 dB and 6.3 dB for each. The input 1 dB compression point (IP1dB) at low gain mode is about −6 dBm and −3 dBm for each. The front-ends consume about 2.1 mA current from 1.8 V power supply for the saturation one and 1.3 mA current for the subthreshold one. The measured results show that, comparing with the power consumption saving, it is worth making sacrifices on the performance for using the subthreshold technology. (semiconductor integrated circuits)

  3. Realization of a neural algorithm by means of front-propagation in a thyristor-based hybrid system

    International Nuclear Information System (INIS)

    Niedernostheide, F.-J.; Schulze, H.-J.; Freyd, O.; Bode, M.; Gorbatyuk, A.V.

    2003-01-01

    Propagating fronts are generic structures in a bistable diffusion-driven system and can be used to realize neural algorithms, as e.g., the Kohonen or the neural-gas algorithm. We present an analog-digital hybrid system based on a thyristor-like structure with several gate terminals. This structure represents the continuous part in which a propagating front, separating a region of high current density from a region of low current density, is used to control the learning process of the neural algorithm. With a system containing five neurons and five gates in a quasi one-dimensional arrangement it is demonstrated that an efficient parallel operating learning process can be realized by using the winner-take-all principle and the front propagation, i.e. exploiting the intrinsic dynamics of the semiconductor device. Finally, numerical and analytical investigations of the dependency of the front velocity and its width on the load current have been performed since these are essential parameters for improving the network performance

  4. Photochemical reactions of neptunium in nitric acid solution containing photocatalyst

    International Nuclear Information System (INIS)

    Fukasawa, Tetsuo; Kawamura, Fumio

    1991-01-01

    Photochemical oxidation and reduction behaviors of neptunium were preliminarily investigated in 3 mol/l nitric acid solution. Nitric acid of 3 mol/l simulated the high level waste solution from a spent fuel reprocessing process. Concentrations of Np(V), Np(VI) and nitrous acid were determined with a photospectrometer, and solution potential with an electrode. Without additives, Np(VI) was reduced to Np(V) by nitrous acid which was photolytically generated from nitric acid. With a scavenger for nitrous acid, Np(V) was oxidized to extractable Np(VI) by a photolytically generated oxidizing reagent which were predicted by the solution potential measurement. The reduction rate was higher than the oxidation rate because of the larger quantity and higher reactivity of nitrous acid than an oxidizing reagent. Photocatalyst was proved to be effective for the oxidation of Np(V) to Np(VI). (author)

  5. Elastoplastic reaction of a container to water freezing

    Czech Academy of Sciences Publication Activity Database

    Krejčí, Pavel

    2010-01-01

    Roč. 135, č. 4 (2010), s. 423-441 ISSN 0862-7959 R&D Projects: GA ČR GAP201/10/2315 Institutional research plan: CEZ:AV0Z10190503 Keywords : phase transition * water * ice * energy * entropy * elastoplastic boundary Subject RIV: BA - General Mathematics http://www.dml.cz/dmlcz/140833

  6. Spectroscopy and reaction dynamics of collision complexes containing hydroxyl radicals

    Energy Technology Data Exchange (ETDEWEB)

    Lester, M.I. [Univ. of Pennsylvania, Philadelphia (United States)

    1993-12-01

    The DOE supported work in this laboratory has focused on the spectroscopic characterization of the interaction potential between an argon atom and a hydroxyl radical in the ground X{sup 2}II and excited A {sup 2}{summation}{sup +} electronic states. The OH-Ar system has proven to be a test case for examining the interaction potential in an open-shell system since it is amenable to experimental investigation and theoretically tractable from first principles. Experimental identification of the bound states supported by the Ar + OH (X {sup 2}II) and Ar + OH(A {sup 2}{summation}{sup +}) potentials makes it feasible to derive realistic potential energy surfaces for these systems. The experimentally derived intermolecular potentials provide a rigorous test of ab initio theory and a basis for understanding the dramatically different collision dynamics taking place on the ground and excited electronic state surfaces.

  7. Determination of the internal exposure hazard from plutonium work in an open front hood

    Science.gov (United States)

    Olson, Cheryl Lynn

    Work with hazardous substances, such as radioactive material, can be done safely when engineered controls are used to maintain the worker effective dose below the International Commission on Radiological Protection ICRP 60 recommendation of 0.02 Sv/year and reduce the worker exposure to material to as low as reasonably achievable (ALARA). A primary engineered control used at a Los Alamos National Laboratory facility is the open-front hood. An open-front hood, also known as an open-front box, is a laboratory containment box that is fully enclosed except for a 15-cm opening along the front of the box. This research involved collection of the aerosol escaping an open-front hood while PuO2 sample digestion was simulated. Sodium chloride was used as a surrogate to mimic the behavior of PuO2. The NaCl aerosol was binned as a function of median aerodynamic diameter using a Micro-orifice Uniform Deposit Impactor (MOUDI, MSP Corporation, Shoreview, MN) cascade impactor. Using neutron activation analysis (NAA) to measure the mass of material in each of the nine bins of the MOUDI, the mass median diameter of the escaping aerosol was determined. Using the mass median diameter and the total mass of the particle distribution, dose was calculated using ICRP 60 methodology. Experimental conditions mimicked a stationary worker and a worker moving her hands in and out of the open front hood. Measurements were also done in the hood for comparison. The effect of the hands moving in and out of the box was modeled. Information necessary for Computational Fluid Dynamics (CFD) modeling is given, such as volumetric flow rates out of the open front hood and into the experimental room, detailed sketches of the experimental set-up, and energy provided by the hot plate and worker. This research is unique as it measures particle size distribution from routine working conditions. Current research uses tracer gases or describes non-routine conditions. It is important to have results that mimic

  8. Waste container and method for containing waste

    International Nuclear Information System (INIS)

    Ono, Akira; Matsushita, Mitsuhiro; Doi, Makoto; Nakatani, Seiichi.

    1990-01-01

    In a waste container, water-proof membranes and rare earth element layers are formed on the inner surface of a steel plate concrete container in which steel plates are embedded. Further, rear earth element detectors are disposed each from the inner side of the steel plate concrete container by way of a pressure pipe to the outer side of the container. As a method for actually containing wastes, when a plurality of vessels in which wastes are fixed are collectively enhoused to the waste container, cussioning materials are attached to the inner surface of the container and wastes fixing containers are stacked successively in a plurality of rows in a bag made of elastic materials. Subsequently, fixing materials are filled and tightly sealed in the waste container. When the waste container thus constituted is buried underground, even if it should be deformed to cause intrusion of rain water to the inside of the container, the rare earth elements in the container dissolved in the rain water can be detected by the detectors, the containers are exchanged before the rain water intruding to the inner side is leached to the surrounding ground, to previously prevent the leakage of radioactive nuclides. (K.M.)

  9. Chemical kinetics and reaction mechanism

    International Nuclear Information System (INIS)

    Jung, Ou Sik; Park, Youn Yeol

    1996-12-01

    This book is about chemical kinetics and reaction mechanism. It consists of eleven chapters, which deal with reaction and reaction speed on reaction mechanism, simple reaction by rate expression, reversible reaction and simultaneous reaction, successive reaction, complicated reaction mechanism, assumption for reaction mechanism, transition state theory, successive reaction and oscillating reaction, reaction by solution, research method high except kinetics on reaction mechanism, high reaction of kinetics like pulsed radiolysis.

  10. PACE3 - front-end chip for the CMS Preshower

    CERN Multimedia

    Aspel, Paul

    2003-01-01

    This is PACE3 which is the front-end chip for the CMS Preshower. In fact PACE3 is the combination of two ASICs called Delta3 and PACEAM3. Delta3 is on the left and PACEAM3 is on the right. The two ASICs are bonded together and then packaged within a single 196 pin fpBGA package.

  11. Iterative wave-front reconstruction in the Fourier domain.

    Science.gov (United States)

    Bond, Charlotte Z; Correia, Carlos M; Sauvage, Jean-François; Neichel, Benoit; Fusco, Thierry

    2017-05-15

    The use of Fourier methods in wave-front reconstruction can significantly reduce the computation time for large telescopes with a high number of degrees of freedom. However, Fourier algorithms for discrete data require a rectangular data set which conform to specific boundary requirements, whereas wave-front sensor data is typically defined over a circular domain (the telescope pupil). Here we present an iterative Gerchberg routine modified for the purposes of discrete wave-front reconstruction which adapts the measurement data (wave-front sensor slopes) for Fourier analysis, fulfilling the requirements of the fast Fourier transform (FFT) and providing accurate reconstruction. The routine is used in the adaptation step only and can be coupled to any other Wiener-like or least-squares method. We compare simulations using this method with previous Fourier methods and show an increase in performance in terms of Strehl ratio and a reduction in noise propagation for a 40×40 SPHERE-like adaptive optics system. For closed loop operation with minimal iterations the Gerchberg method provides an improvement in Strehl, from 95.4% to 96.9% in K-band. This corresponds to ~ 40 nm improvement in rms, and avoids the high spatial frequency errors present in other methods, providing an increase in contrast towards the edge of the correctable band.

  12. Radiation hydrodynamical instabilities in cosmological and galactic ionization fronts

    Science.gov (United States)

    Whalen, Daniel J.; Norman, Michael L.

    2011-11-01

    Ionization fronts, the sharp radiation fronts behind which H/He ionizing photons from massive stars and galaxies propagate through space, were ubiquitous in the universe from its earliest times. The cosmic dark ages ended with the formation of the first primeval stars and galaxies a few hundred Myr after the Big Bang. Numerical simulations suggest that stars in this era were very massive, 25-500 solar masses, with H(II) regions of up to 30,000 light-years in diameter. We present three-dimensional radiation hydrodynamical calculations that reveal that the I-fronts of the first stars and galaxies were prone to violent instabilities, enhancing the escape of UV photons into the early intergalactic medium (IGM) and forming clumpy media in which supernovae later exploded. The enrichment of such clumps with metals by the first supernovae may have led to the prompt formation of a second generation of low-mass stars, profoundly transforming the nature of the first protogalaxies. Cosmological radiation hydrodynamics is unique because ionizing photons coupled strongly to both gas flows and primordial chemistry at early epochs, introducing a hierarchy of disparate characteristic timescales whose relative magnitudes can vary greatly throughout a given calculation. We describe the adaptive multistep integration scheme we have developed for the self-consistent transport of both cosmological and galactic ionization fronts.

  13. Analytical Estimates of the Dispersion Curve in Planar Ionization Fronts

    International Nuclear Information System (INIS)

    Arrayas, Manuel; Trueba, Jose L.; Betelu, Santiago; Fontelos, Marco A.

    2009-01-01

    Fingers from ionization fronts for a hydrodynamic plasma model result from a balance between impact ionization and electron diffusion in a non-attaching gas. An analytical estimation of the size of the fingers and its dependence on both the electric field and electron diffusion coefficient can be done when the diffusion is low and the electric field is strong.

  14. Vacuum Polarization Tensor for QED in the Light Front Gauge

    International Nuclear Information System (INIS)

    Suzuki, A.T.; Soriano, L.A.; Bolzan, J.D.; Sales, J.H.O.

    2012-01-01

    The use of light front coordinates in quantum field theories (QFT) always brought some problems and controversies. In this work we explore some aspects of its formalism with respect to the employment of dimensional regularization in the computation of the photon's self-energy at the one-loop level and how the fermion propagator has an important role in the outcoming results. (author)

  15. On the propagation of a coupled saturation and pressure front

    Energy Technology Data Exchange (ETDEWEB)

    Vasco, D. W.

    2010-12-01

    Using an asymptotic technique, valid for a medium with smoothly varying heterogeneity, I derive an expression for the velocity of a propagating, coupled saturation and pressure front. Due to the nonlinearity of the governing equations, the velocity of the propagating front depends upon the magnitude of the saturation and pressure changes across the front in addition to the properties of the medium. Thus, the expression must be evaluated in conjunction with numerical reservoir simulation. The propagation of the two-phase front is governed by the background saturation distribution, the saturation-dependent component of the fluid mobility, the porosity, the permeability, the capillary pressure function, the medium compressibility, and the ratio of the slopes of the relative permeability curves. Numerical simulation of water injection into a porous layer saturated with a nonaqueous phase liquid indicates that two modes of propagation are important. The fastest mode of propagation is a pressure-dominated disturbance that travels through the saturated layer. This is followed, much later, by a coupled mode with a large saturation change. These two modes are also observed in a simulation using a heterogeneous porous layer. A comparison between the propagation times estimated from the results of the numerical simulation and predictions from the asymptotic expression indicates overall agreement.

  16. Front end readout electronics for the CMS hadron calorimeter

    CERN Document Server

    Shaw, Terri M

    2002-01-01

    The front-end electronics for the CMS Hadron Calorimeter provides digitized data at the beam interaction rate of 40 MHz. Analog signals provided by hybrid photodiodes (HPDs) or photomultiplier tubes (PMTs) are digitized and the data is sent off board through serialized fiber optic links running at 1600 Mbps. In order to maximize the input signal, the front-end electronics are housed on the detector in close proximity to the scintillating fibers or phototubes. To fit the electronics into available space, custom crates, backplanes and cooling methods have had to be developed. During the expected ten-year lifetime, the front-end readout electronics will exist in an environment where radiation levels approach 330 rads and the neutron fluence will be 1.3E11 n/cm sup 2. For this reason, the design approach relies heavily upon custom radiation tolerant ASICs. This paper will present the system architecture of the front-end readout crates and describe their results with early prototypes.

  17. Front End Loader Operator. Open Pit Mining Job Training Series.

    Science.gov (United States)

    Savilow, Bill

    This training outline for front end loader operators, one in a series of eight outlines, is designed primarily for company training foremen or supervisors and for trainers to use as an industry-wide guideline for heavy equipment operator training in open pit mining in British Columbia. Intended as a guide for preparation of lesson plans both for…

  18. Front-running of Mutual Fund Fire-sales

    NARCIS (Netherlands)

    Dyakov, T.C.; Verbeek, M.

    2013-01-01

    We show that a real-time trading strategy which front-runs the anticipated forced sales by mutual funds experiencing extreme capital outflows generates an alpha of 0.5% per month during the 1990-2010 period. The abnormal return stems from selling pressure among stocks that are below the NYSE mean

  19. Consumer preferences for front-of-pack calories labelling

    NARCIS (Netherlands)

    Kleef, van E.; Trijp, van J.C.M.; Paeps, F.; Fernández-Celemín, L.

    2008-01-01

    Objective In light of the emerging obesity pandemic, front-of-pack calories labels may be an important tool to assist consumers in making informed healthier food choices. However, there is little prior research to guide key decisions on whether caloric content should be expressed in absolute terms

  20. An operational map of the Polish Coastal Front 1970

    DEFF Research Database (Denmark)

    Nielsen, Thomas Theis; Svenningsen, Stig Roar; Tinning, Morten

    2016-01-01

    The map of the Operational Plan for the Coastal Front, from Poland 1970 forms the basis for this paper. The map portraits the blueprint of the combined operational war plans for the Polish military in the late 1960’s and 70’s. It details the offensive against NATO countries and their forces...

  1. A New Formula for Front Slope Recession of Berm Breakwaters

    DEFF Research Database (Denmark)

    Andersen, Thomas Lykke; Burcharth, Hans F.

    2010-01-01

    The front slope stability of breakwaters with a homogeneous berm was studied in a large number of two dimensional model tests at Aalborg University, Denmark. The results are presented together with a new formula for prediction of the berm recession which is the most important parameter...

  2. Front and backside processed thin film electronic devices

    Science.gov (United States)

    Yuan, Hao-Chih; Wang, Guogong; Eriksson, Mark A.; Evans, Paul G.; Lagally, Max G.; Ma, Zhenqiang

    2010-10-12

    This invention provides methods for fabricating thin film electronic devices with both front- and backside processing capabilities. Using these methods, high temperature processing steps may be carried out during both frontside and backside processing. The methods are well-suited for fabricating back-gate and double-gate field effect transistors, double-sided bipolar transistors and 3D integrated circuits.

  3. Variational formulation based analysis on growth of yield front in ...

    African Journals Online (AJOL)

    The present study investigates the growth of elastic-plastic front in rotating solid disks of non-uniform thickness having exponential and parabolic geometry variation. The problem is solved through an extension of a variational method in elastoplastic regime. The formulation is based on von-Mises yield criterion and linear ...

  4. Electric field measurements in moving ionization fronts during plasma breakdown

    NARCIS (Netherlands)

    Wagenaars, E.; Bowden, M.D.; Kroesen, G.M.W.

    2006-01-01

    We have performed time-resolved, direct measurements of electric field strengths in moving ionization fronts during the breakdown phase of a pulsed plasma. Plasma breakdown, or plasma ignition, is a highly transient process marking the transition from a gas to a plasma. Some aspects of plasma

  5. Morale among French colonial troops on the Western Front during ...

    African Journals Online (AJOL)

    The traditional images of the French Army in World War I on the Western Front from Cyril Falls's to Marc Ferro's surveys (both entitled The Great War 1914– 1918) have been that of the grizzled yet determined French peasant or worker – the poilu. It is clear from recent research that this is far from accurate and that the French ...

  6. Front end readout electronics for the CMS hadron calorimeter

    International Nuclear Information System (INIS)

    Terri M. Shaw et al.

    2002-01-01

    The front-end electronics for the CMS Hadron Calorimeter provides digitized data at the beam interaction rate of 40 MHz. Analog signals provided by hybrid photodiodes (HPDs) or photomultiplier tubes (PMTs) are digitized and the data is sent off board through serialized fiber optic links running at 1600 Mbps. In order to maximize the input signal, the front-end electronics are housed on the detector in close proximity to the scintillating fibers or phototubes. To fit the electronics into available space, custom crates, backplanes and cooling methods have had to be developed. During the expected ten-year lifetime, the front-end readout electronics will exist in an environment where radiation levels approach 330 rads and the neutron fluence will be 1.3E11 n/cm 2 . For this reason, the design approach relies heavily upon custom radiation tolerant ASICs. This paper will present the system architecture of the front-end readout crates and describe their results with early prototypes

  7. Calibration method for direct conversion receiver front-ends

    Directory of Open Access Journals (Sweden)

    R. Müller

    2008-05-01

    Full Text Available Technology induced process tolerances in analog circuits cause device characteristics different from specification. For direct conversion receiver front-ends a system level calibration method is presented. The malfunctions of the devices are compensated by tuning dominant circuit parameters. Thereto optimization techniques are applied which use measurement values and special evaluation functions.

  8. Modeling beam-front dynamics at low gas pressures

    International Nuclear Information System (INIS)

    Briggs, R.J.; Yu, S.

    1982-01-01

    The dynamics of space charge neutralization at the front of an intense self-focused electron beam pulse exhibits important differences in different gas pressure regimes. At very low pressures, the beam front is in the so-called ion-focused regime (IFR) where all secondary electrons are expelled from the beam region by the radial electric field without causing significant additional ionization. We estimate the upper pressure boundary of this regime by considering the distance scale length for cascade (avalanche) ionization. Data from the FX-25 diode experiments indicate a critical transition pressure (P/sub c/) that agrees with this estimate and with its scaling among various gas types. Normal mobility-limited treatments (local conductivity models) of the secondary electrons at the beam front are not justified until the gas pressure is 10 to 50 times higher than P/sub c/, due to runaway of these secondary electrons in the strong space-charge electric field at the lower pressures. The main conclusion of this study is that a non-local phase space (Boltzmann) treatment of the secondary electrons is required to accurately describe these different beam front regimes and the transitions between them; such a code model is currently under development

  9. A socio-internactive framework for the fuzzy front end

    NARCIS (Netherlands)

    Smulders, Frido E.; van den Broek, Egon; van der Voort, Mascha C.; Fernandes, A.; Teixeira, A.; Natal Jorge, R.

    2007-01-01

    This paper aims to illustrate that the dominating rational-analytic perspective on the Fuzzy Front End (FFE) of innovation could benefit by a complementary socio-interactive perspective that addresses the social processes during the FFE. We have developed a still fledgling socio-interactive

  10. Protecting front-line survey and rescue teams during emergencies

    International Nuclear Information System (INIS)

    Tresise, H.

    1980-01-01

    Means of protecting front-line survey and rescue teams during emergencies are described. The team composition, their apparatus, the selection of the incident control point, the use of guidelines and breathing apparatus and control point trolley and equipment are discussed. (H.K.)

  11. Spatially Localized Chemical Patterns around an A + B → Oscillator Front.

    Science.gov (United States)

    Budroni, M A; Lemaigre, L; Escala, D M; Muñuzuri, A P; De Wit, A

    2016-02-18

    When two gels, each loaded with a different set of reactants A and B of an oscillatory reaction, are brought into contact, reaction-diffusion patterns such as waves or Turing patterns can develop in the reactive contact zone. The initial condition which separates the reactants at the beginning leads to a localization in space of the different dynamical regimes accessible to the chemical oscillator. We study here both numerically and experimentally the composite traveling structures resulting from the interaction between chemical fronts and localized waves in the case in which the reactants of such an A + B → oscillator system are those of the canonical Belousov-Zhabotinsky (BZ) oscillating reaction. A transition between different dynamics is obtained by varying the initial concentration of the organic substrate of the BZ reactants, which is one of the parameters controlling the local excitability. We show that the dynamical regime (excitable or oscillatory) characterizing the BZ oscillator in the initial contact area is the key feature which determines the spatiotemporal evolution of the system. The experimental results are in qualitative agreement with the theoretical predictions.

  12. 5-D interpolation with wave-front attributes

    Science.gov (United States)

    Xie, Yujiang; Gajewski, Dirk

    2017-11-01

    Most 5-D interpolation and regularization techniques reconstruct the missing data in the frequency domain by using mathematical transforms. An alternative type of interpolation methods uses wave-front attributes, that is, quantities with a specific physical meaning like the angle of emergence and wave-front curvatures. In these attributes structural information of subsurface features like dip and strike of a reflector are included. These wave-front attributes work on 5-D data space (e.g. common-midpoint coordinates in x and y, offset, azimuth and time), leading to a 5-D interpolation technique. Since the process is based on stacking next to the interpolation a pre-stack data enhancement is achieved, improving the signal-to-noise ratio (S/N) of interpolated and recorded traces. The wave-front attributes are determined in a data-driven fashion, for example, with the Common Reflection Surface (CRS method). As one of the wave-front-attribute-based interpolation techniques, the 3-D partial CRS method was proposed to enhance the quality of 3-D pre-stack data with low S/N. In the past work on 3-D partial stacks, two potential problems were still unsolved. For high-quality wave-front attributes, we suggest a global optimization strategy instead of the so far used pragmatic search approach. In previous works, the interpolation of 3-D data was performed along a specific azimuth which is acceptable for narrow azimuth acquisition but does not exploit the potential of wide-, rich- or full-azimuth acquisitions. The conventional 3-D partial CRS method is improved in this work and we call it as a wave-front-attribute-based 5-D interpolation (5-D WABI) as the two problems mentioned above are addressed. Data examples demonstrate the improved performance by the 5-D WABI method when compared with the conventional 3-D partial CRS approach. A comparison of the rank-reduction-based 5-D seismic interpolation technique with the proposed 5-D WABI method is given. The comparison reveals that

  13. Silicon-based sleeve devices for chemical reactions

    Science.gov (United States)

    Northrup, M. Allen; Mariella, Jr., Raymond P.; Carrano, Anthony V.; Balch, Joseph W.

    1996-01-01

    A silicon-based sleeve type chemical reaction chamber that combines heaters, such as doped polysilicon for heating, and bulk silicon for convection cooling. The reaction chamber combines a critical ratio of silicon and silicon nitride to the volume of material to be heated (e.g., a liquid) in order to provide uniform heating, yet low power requirements. The reaction chamber will also allow the introduction of a secondary tube (e.g., plastic) into the reaction sleeve that contains the reaction mixture thereby alleviating any potential materials incompatibility issues. The reaction chamber may be utilized in any chemical reaction system for synthesis or processing of organic, inorganic, or biochemical reactions, such as the polymerase chain reaction (PCR) and/or other DNA reactions, such as the ligase chain reaction, which are examples of a synthetic, thermal-cycling-based reaction. The reaction chamber may also be used in synthesis instruments, particularly those for DNA amplification and synthesis.

  14. Modeling, simulation, and optimization of a front-end system for acetylene hydrogenation reactors

    Directory of Open Access Journals (Sweden)

    R. Gobbo

    2004-12-01

    Full Text Available The modeling, simulation, and dynamic optimization of an industrial reaction system for acetylene hydrogenation are discussed in the present work. The process consists of three adiabatic fixed-bed reactors, in series, with interstage cooling. These reactors are located after the compression and the caustic scrubbing sections of an ethylene plant, characterizing a front-end system; in contrast to the tail-end system where the reactors are placed after the de-ethanizer unit. The acetylene conversion and selectivity profiles for the reactors are optimized, taking into account catalyst deactivation and process constraints. A dynamic optimal temperature profile that maximizes ethylene production and meets product specifications is obtained by controlling the feed and intercoolers temperatures. An industrial acetylene hydrogenation system is used to provide the necessary data to adjust kinetics and transport parameters and to validate the approach.

  15. Reaction and devitrification of a prototype nuclear-waste-storage glass with hot magnesium-rich brine

    International Nuclear Information System (INIS)

    Komarneni, S.; Freeborn, W.P.; Scheetz, B.E.; White, W.B.; McCarthy, G.J.

    1982-10-01

    PNL 76-68, a prototype nuclear waste storage glass, was reacted under hydrothermal conditions at 100, 200, and 300 C with NBT-6a (Ca-Mg-K-Na-Cl) brine. Reaction products were identified, the state of the residual glass determined, and the concentrations of various elements remaining in the solutions analyzed. Solid products formed by reaction of the glass and brine talc (hydrated magnesium silicate), powellite (CaMoO 4 ), hematite (Fe 2 O 3 ) and rarely an unidentified uranium-containing phase. Glass fragments were leached to depths of 300 to 500 μm, depending on time and temperature. Most elements were extracted, but the silicate framework remained intact. Distinct diffusion fronts due to K/Na exchange and Mg/Zn exchange were identified. A complex compositional layering develops in the outer reaction rind. The concentration of silica in brine solution was lower by an order of magnitude than the concentration of silica in deionized water reacted under similar conditions. The concentration of cesium, strontium, uranium, rare earths, and other alkali and alkaline earth elements in solution increases exponentially with temperature of reaction. Behavior of the transition metals is more complex. In general the extraction of elements from the glass by hydrothermal brine leads to concentrations in solution that are from 10 to 100 times higher than the concentrations obtained by deionized water extraction under similar conditions of temperature and pressure

  16. Container crane for sea freight containers

    NARCIS (Netherlands)

    Luttekes, E.; Rijsenbrij, J.C.

    2001-01-01

    The invention relates to a container crane for loading and unloading seaborne containers. The container crane comprises a bridge girder (7), a jib (8), at least two crabs (11, 12) which can travel along the said bridge girder and/or jib and are provided with hoist means for lifting and lowering the

  17. Consumer preferences for front-of-pack calories labelling

    Science.gov (United States)

    van Kleef, Ellen; van Trijp, Hans; Paeps, Frederic; Fernández-Celemín, Laura

    2008-01-01

    Objective In light of the emerging obesity pandemic, front-of-pack calories labels may be an important tool to assist consumers in making informed healthier food choices. However, there is little prior research to guide key decisions on whether caloric content should be expressed in absolute terms or relative to recommended daily intake, whether it should be expressed in per serving or per 100 g and whether the information should be further brought alive for consumers in terms of what the extra calorie intake implies in relation to activity levels. The present study aimed at providing more insight into consumers’ appreciation of front-of-pack labelling of caloric content of food products and their specific preferences for alternative execution formats for such information in Europe. Design For this purpose, eight executions of front-of-pack calorie flags were designed and their appeal and information value were extensively discussed with consumers through qualitative research in four different countries (Germany, The Netherlands, France and the UK). Results The results show that calories are well-understood and that participants were generally positive about front-of-pack flags, particularly when flags are uniform across products. The most liked flags are the simpler flags depicting only the number of calories per serving or per 100 g, while more complex flags including references to daily needs or exercise and the flag including a phrase referring to balanced lifestyle were least preferred. Some relevant differences between countries were observed. Although participants seem to be familiar with the notion of calories, they do not seem to fully understand how to apply them. Conclusion From the results, managerial implications for the design and implementation of front-of-pack calorie labelling as well as important directions for future research are discussed. PMID:17601362

  18. Consumer preferences for front-of-pack calories labelling.

    Science.gov (United States)

    van Kleef, Ellen; van Trijp, Hans; Paeps, Frederic; Fernández-Celemín, Laura

    2008-02-01

    In light of the emerging obesity pandemic, front-of-pack calories labels may be an important tool to assist consumers in making informed healthier food choices. However, there is little prior research to guide key decisions on whether caloric content should be expressed in absolute terms or relative to recommended daily intake, whether it should be expressed in per serving or per 100 g and whether the information should be further brought alive for consumers in terms of what the extra calorie intake implies in relation to activity levels. The present study aimed at providing more insight into consumers' appreciation of front-of-pack labelling of caloric content of food products and their specific preferences for alternative execution formats for such information in Europe. For this purpose, eight executions of front-of-pack calorie flags were designed and their appeal and information value were extensively discussed with consumers through qualitative research in four different countries (Germany, The Netherlands, France and the UK). The results show that calories are well-understood and that participants were generally positive about front-of-pack flags, particularly when flags are uniform across products. The most liked flags are the simpler flags depicting only the number of calories per serving or per 100 g, while more complex flags including references to daily needs or exercise and the flag including a phrase referring to balanced lifestyle were least preferred. Some relevant differences between countries were observed. Although participants seem to be familiar with the notion of calories, they do not seem to fully understand how to apply them. From the results, managerial implications for the design and implementation of front-of-pack calorie labelling as well as important directions for future research are discussed.

  19. Wave front sensing for next generation earth observation telescope

    Science.gov (United States)

    Delvit, J.-M.; Thiebaut, C.; Latry, C.; Blanchet, G.

    2017-09-01

    High resolution observations systems are highly dependent on optics quality and are usually designed to be nearly diffraction limited. Such a performance allows to set a Nyquist frequency closer to the cut off frequency, or equivalently to minimize the pupil diameter for a given ground sampling distance target. Up to now, defocus is the only aberration that is allowed to evolve slowly and that may be inflight corrected, using an open loop correction based upon ground estimation and refocusing command upload. For instance, Pleiades satellites defocus is assessed from star acquisitions and refocusing is done with a thermal actuation of the M2 mirror. Next generation systems under study at CNES should include active optics in order to allow evolving aberrations not only limited to defocus, due for instance to in orbit thermal variable conditions. Active optics relies on aberration estimations through an onboard Wave Front Sensor (WFS). One option is using a Shack Hartmann. The Shack-Hartmann wave-front sensor could be used on extended scenes (unknown landscapes). A wave-front computation algorithm should then be implemented on-board the satellite to provide the control loop wave-front error measure. In the worst case scenario, this measure should be computed before each image acquisition. A robust and fast shift estimation algorithm between Shack-Hartmann images is then needed to fulfill this last requirement. A fast gradient-based algorithm using optical flows with a Lucas-Kanade method has been studied and implemented on an electronic device developed by CNES. Measurement accuracy depends on the Wave Front Error (WFE), the landscape frequency content, the number of searched aberrations, the a priori knowledge of high order aberrations and the characteristics of the sensor. CNES has realized a full scale sensitivity analysis on the whole parameter set with our internally developed algorithm.

  20. Hypersensitivity Reactions from Excipients in Systemic Glucocorticoid Formulations

    DEFF Research Database (Denmark)

    Calogiuri, Gianfranco; Garvey, Lene H; Romita, Paolo

    2016-01-01

    Glucocorticoids are the most widely used drugs for the treatment of hypersensitivity, however these drugs themselves and the excipients contained in commercial corticosteroid formulations are able to induce severe immediate-type hypersensitivity reactions. Reactions involving excipients have been...