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Sample records for quantum confinement effect

  1. THz quantum-confined Stark effect in semiconductor quantum dots

    DEFF Research Database (Denmark)

    Turchinovich, Dmitry; Monozon, Boris S.; Livshits, Daniil A.;

    2012-01-01

    We demonstrate an instantaneous all-optical manipulation of optical absorption at the ground state of InGaAs/GaAs quantum dots (QDs) via a quantum-confined Stark effect (QCSE) induced by the electric field of incident THz pulses with peak electric fields reaching 200 kV/cm in the free space...

  2. Quantum confined Stark effect in Gaussian quantum wells: A tight-binding study

    Energy Technology Data Exchange (ETDEWEB)

    Ramírez-Morales, A.; Martínez-Orozco, J. C.; Rodríguez-Vargas, I. [Unidad Académica de Física, Universidad Autónoma de Zacatecas, Calzada Solidaridad Esquina Con Paseo La Bufa S/N, 98060 Zacatecas, Zac. (Mexico)

    2014-05-15

    The main characteristics of the quantum confined Stark effect (QCSE) are studied theoretically in quantum wells of Gaussian profile. The semi-empirical tight-binding model and the Green function formalism are applied in the numerical calculations. A comparison of the QCSE in quantum wells with different kinds of confining potential is presented.

  3. Quantum confinement effects in low-dimensional systems

    Indian Academy of Sciences (India)

    D Topwal

    2015-06-01

    The confinement effects of electrons in ultrathin films and nanowires grown on metallic and semiconducting substrates investigated using band mapping of their electronic structures using angle-resolved photoemission spectroscopy is discussed here. It has been shown that finite electron reflectivity at the interface is sufficient to sustain the formation of quantum well states and weak quantum well resonance states even in closely matched metals. The expected parabolic dispersion of sp-derived quantum well states for free-standing layers undergoes deviations from parabolic behaviour and modifications due to the underlying substrate bands, suggesting the effects of strong hybridization between the quantum well states and the substrate bands. Electron confinement effects in low dimensions as observed from the dispersionless features in the band structures are also discussed.

  4. Growth mechanism and quantum confinement effect of silicon nanowires

    Institute of Scientific and Technical Information of China (English)

    冯孙齐; 俞大鹏; 张洪洲; 白志刚; 丁彧; 杭青岭; 邹英华; 王晶晶

    1999-01-01

    The methods for synthesizing one-dimensional Si nanowires with controlled diameter are introduced. The mechanism for the growth of Si nanowires and the growth model for different morphologies of Si nanowires are described, and the quantum confinement effect of the Si nanowires is presented.

  5. Strong quantum confinement effects in thin zinc selenide films

    Science.gov (United States)

    Baskoutas, S.; Poulopoulos, P.; Karoutsos, V.; Angelakeris, M.; Flevaris, N. K.

    2006-01-01

    Thin Zinc Selenide films in the thickness range 3-50 nm have been prepared on high quality glass substrates by e-beam evaporation under ultrahigh vacuum conditions. Optical absorption spectroscopy experiments reveal a systematically increasing blue shift of the effective bandgap energy as the film thickness decreases, reaching a maximum value of 0.32 eV for the thinner film. The experimental results, which indicate the presence of strong quantum confinement effects, are fairly well described by theoretical calculations based on the potential morphing method, using as a confining potential the finite square well potential with height of the barriers equal to 5 eV.

  6. Quark confinement and the fractional quantum Hall effect

    Institute of Scientific and Technical Information of China (English)

    WANG Hai-Jun; GENG Wen-Tong

    2008-01-01

    Working in the physics of Wilson factor and Aharonov-Bohm effect,we find in the fluxtubequark system the topology of a baryon consisting of three heavy flavor quarks resembles that of the fractional quantum Hall effect(FQHE)in condensed matter.This similarity yields the result that the constituent quarks of baryon have the"filling factor"1/3.thus the previous conjecture that quark confinement is a correlation effect is confirmed.Moreover,by deriving a Hamiltonian of the system analogous to that of FQHE,we predict an energy gap for the ground state of a heavy three-quark system.

  7. Quantum-confined Stark effect in band-inverted junctions

    Science.gov (United States)

    Díaz-Fernández, A.; Domínguez-Adame, F.

    2017-09-01

    Topological phases of matter are often characterized by interface states, which were already known to occur at the boundary of a band-inverted junction in semiconductor heterostructures. In IV-VI compounds such interface states are properly described by a two-band model, predicting the appearance of a Dirac cone in single junctions. We study the quantum-confined Stark effect of interface states due to an electric field perpendicular to a band-inverted junction. We find a closed expression to obtain the interface dispersion relation at any field strength and show that the Dirac cone widens under an applied bias. Thus, the Fermi velocity can be substantially lowered even at moderate fields, paving the way for tunable band-engineered devices based on band-inverted junctions.

  8. Quantum Confinement Effects in Strained SiGe/Si Multiple Quantum Wells

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Strained SiGe/Si multiple quantum wells (MQWs) were grown by cold-wall ultrahigh vacuum chemical vapor deposition (UHV/CVD). Photoluminescence measurement was performed to study the exciton energies of strained Si0.84 Ge0.16/Si MQWs with SiGe well widths ranging from 4.2nm to 25.4nm. The confinement energy of 43meV is found in the Si0.84Ge0.16/Si MQWs with well width of 4.2nm. The confinement energy was calculated by solving the problem of a particle confined in a single finite rectangular poteintial well using one band effect mass model. Experimental and theoretical confinement energies are in good agreement

  9. Investigation of confinement effects in ZnO quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Haranath, D; Sahai, Sonal; Joshi, Amish G; Gupta, Bipin K; Shanker, V, E-mail: haranath@nplindia.or [National Physical Laboratory, Council of Scientific and Industrial Research, Dr K S Krishnan Road, New Delhi-110 012 (India)

    2009-10-21

    We report a simple method for the synthesis of Na{sup +} doped and stable zinc oxide quantum dots, using the quantum confinement atom method. An intense broad green photoluminescence (PL) was observed with a maximum located at {approx}535 nm when excited by UV radiation of 332 nm. The PL peak intensity is found to be highly dependent on the size of the quantum dots (QDs). Electron microscopy observation revealed that the radius of the QD was {approx}1 nm, which clearly indicated that the QDs are in the strong quantum confinement region (exciton Bohr radius, r{sub B}, for bulk ZnO is 1.8 nm). Phase purity of ZnO and the presence of Na{sup +} was confirmed by x-ray diffraction (XRD) and atomic absorption spectroscopy (AAS), respectively. The results are well incremented by x-ray photoelectron spectroscopy (XPS) studies. Intentional ageing of QDs for several days under controlled experimental conditions such as temperature, relative humidity and pH etc, facilitated the formation of various nanostructures with a slight red shift in the PL peak position. Time resolved emission spectroscopy measurements indicated that PL decay time changes from 35 ns for QDs to 1660 {mu}s for nanocrystals. The observed high-intensity and stable green PL emissions have been analyzed and thoroughly discussed.

  10. Quantum-Confined Stark Effects in a Single GaN Quantum Dot

    Institute of Scientific and Technical Information of China (English)

    LIU Yong-Hui; WANG Xue-Feng; LI Shu-Shen

    2008-01-01

    Using analytical expressions for the polarization field in GaN quantum dot, and an approximation by separating the potential into a radial and an axial, we investigate theoretically the quantum-confined Stark effects. The electron and hole energy levels and optical transition energies are calculated in the presence of an electric field in different directions. The results show that the electron and hole energy levels and the optical transition energies can cause redshifts for the lateral electric field and blueshifts for the vertical field. The rotational direction of electric field can also change the energy shift.

  11. Quantum-Confined Stark Effect in Ensemble of Colloidal Semiconductor Quantum Dots

    Institute of Scientific and Technical Information of China (English)

    WANG Zhi-Bing; ZHANG Hui-Chao; ZHANG Jia-Yu; Huaipeng Su; Y.Andrew Wang

    2010-01-01

    @@ The presence of a strong,changing,randomly-oriented,local electric field,which is induced by the photo-ionization that occurs universally in colloidal semiconductor quantum dots(QDs),makes it difficult to observe the quantumconfined Stark effect in ensemble of colloidal QDs.We propose a way to inhibit such a random electric field,and a clear quantum-confined Stark shift is observed directly in close-packed colloidal QDs.Besides the applications in optical switches and modulators,our experimental results indicate how the oscillator strengths of the optical transitions are changed under external electric fields.

  12. Quantum-Confinement Effects on Binding Energies and Optical Properties of Excitons in Quantum Dots

    Institute of Scientific and Technical Information of China (English)

    潘晖

    2004-01-01

    Quantum-confinement effects on the binding energy and the linear optical susceptibility of excitons in quantum dots are studied. It is found that the binding energy and the linear optical susceptibility are sensitive to the barrier height and the dot size. For an infinite barrier, the binding energy of excitons decreases monotonically with the increasing dot radius, and the absorption intensity has almost the same amplitude with the increasing photon energy. For a finite barrier, the binding energy has a maximum value with the increasing dot radius, and the absorption intensity damps rapidly with the increasing photon energy. The effective mass ratio is also found to have an influence on the binding energy. The results could be confirmed by future experiments on excitons in quantum dots.

  13. Unusual quantum confined Stark effect and Aharonov-Bohm oscillations in semiconductor quantum rings with anisotropic effective masses

    Science.gov (United States)

    de Sousa, G. O.; da Costa, D. R.; Chaves, Andrey; Farias, G. A.; Peeters, F. M.

    2017-05-01

    The effects of external electric and magnetic fields on the energy spectrum of quantum rings made out of a bidimensional semiconductor material with anisotropic band structures are investigated within the effective-mass model. The interplay between the effective-mass anisotropy and the radial confinement leads to wave functions that are strongly localized at two diametrically opposite regions where the kinetic energy is lowest due to the highest effective mass. We show that this quantum phenomenon has clear consequences on the behavior of the energy states in the presence of applied in-plane electric fields and out-of-plane magnetic fields. In the former, the quantum confined Stark effect is observed with either linear or quadratic shifts, depending on the direction of the applied field. As for the latter, the usual Aharonov-Bohm oscillations are not observed for a circularly symmetric confining potential, however they can be reinstated if an elliptic ring with an appropriate aspect ratio is chosen.

  14. Bipolaron in different configuration of quantum confinement

    Institute of Scientific and Technical Information of China (English)

    阮永红; 陈庆虎; 焦正宽

    2004-01-01

    The authors used Landau-Pekar variational method to investigate a strong-coupling singlet optical bipolaron in different configuration of quantum confinement.Numerical and analytical results showed that when configuration changes from quantum dot and wire to well,confinement shows different effect on the formation of a bipolaron.In contrast to a bipolaron in a quantum dot or wire,the binding energy of a bipolaron in a quantum well increases with increasing confinement,indicating that confinement favors bipolaron formation in a quantum well.

  15. Bipolaron in different configuration of quantum confinement

    Institute of Scientific and Technical Information of China (English)

    阮永红; 陈庆虎; 焦正宽

    2004-01-01

    The authors used Landau-Pekar variational method to investigate a strong-coupling singlet optical bipolaron in different configuration of quantum confinement. Numerical and analytical results showed that when configuration changes from quantum dot and wire to well, confinement shows different effect on the formation of a bipolaron. In contrast to a bipolaron in a quantum dot or wire, the binding energy of a bipolaron in a quantum well increases with increasing con-finement, indicating that confinement favors bipolaron formation in a quantum well.

  16. Quantum Confinement in Hydrogen Bond

    CERN Document Server

    Santos, Carlos da Silva dos; Ricotta, Regina Maria

    2015-01-01

    In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

  17. CORRELATIONS IN CONFINED QUANTUM PLASMAS

    Energy Technology Data Exchange (ETDEWEB)

    DUFTY J W

    2012-01-11

    This is the final report for the project 'Correlations in Confined Quantum Plasmas', NSF-DOE Partnership Grant DE FG02 07ER54946, 8/1/2007 - 7/30/2010. The research was performed in collaboration with a group at Christian Albrechts University (CAU), Kiel, Germany. That collaboration, almost 15 years old, was formalized during the past four years under this NSF-DOE Partnership Grant to support graduate students at the two institutions and to facilitate frequent exchange visits. The research was focused on exploring the frontiers of charged particle physics evolving from new experimental access to unusual states associated with confinement. Particular attention was paid to combined effects of quantum mechanics and confinement. A suite of analytical and numerical tools tailored to the specific inquiry has been developed and employed

  18. Theoretical and Experimental Investigation of Quantum Confinement Effect on the Blue Shift in Semiconductor Quantum Dots

    Directory of Open Access Journals (Sweden)

    Changiz. Vatankhah

    2015-06-01

    Full Text Available Nano particles of zinc sulfide (ZnS of face centered cubic (fcc structures were synthesized using sulphur source of soium sulphide and mercaptoethanol respectively via Chemical Bath Deposition method. The synthesized quantum dots were characterized using X-ray diffraction (XRD, transmission electron microscopy (TEM and UV-visible spectrophotometry. The average crystallite size calculated from TEM and XRD pattern has been found to in the range 4.6 – 1.9 nm, the pariticles size decreases with the increase of the capping agent concentrations from 0. 001 to 0.7 Mol. The absorption coefficient in the range 325 - 250 nm decreases with increasing capping agent and the particles. ZnS nanoparticles were also derived from time independent Schrodinger equations for ZnS system and calculated the coefficient absorption using the density functional theory (DFT . It is shown that decreasing of ZnS nanosize lead to changes the optical properties and coefficient absorption in the visible region does not occur and the particles act like a transparent material. In this work, the blue shift was observed in absorption-wavelength both theoretical and experimental method due to the quantum confinement effects.

  19. The confinement effect in spherical inhomogeneous quantum dots and stability of excitons

    Directory of Open Access Journals (Sweden)

    F. Benhaddou

    2017-06-01

    Full Text Available We investigate in this work the quantum confinement effect of exciton in spherical inhomogeneous quantum dots IQDs. The spherical core is enveloped by two shells. The inner shell is a semiconductor characterized by a small band-gap. The core and the outer shell are the same semiconductor characterized by a large band-gap. So there is a significant gap-offset creating a deep potential well where the excitons are localized and strongly confined. We have adopted the Ritz variational method to calculate numerically the excitonic ground state energy and its binding energy in the strong, moderate and low confinement regimes. The results show that the Ritz variational method is in good agreement with the perturbation method in strong confinement. There is a double confinement effect and dual control. The calculation checks the effective Rydberg R* at the asymptotic limit of bulk semiconductor when the thickness takes very large values. The excitonic binding energy increases, Thus giving the excitons a high stability even at ambient temperature. These nanosystems are promising in several applications: lighting, detection, biological labeling and quantum computing.

  20. The confinement effect in spherical inhomogeneous quantum dots and stability of excitons

    Science.gov (United States)

    Benhaddou, F.; Zorkani, I.; Jorio, A.

    2017-06-01

    We investigate in this work the quantum confinement effect of exciton in spherical inhomogeneous quantum dots IQDs. The spherical core is enveloped by two shells. The inner shell is a semiconductor characterized by a small band-gap. The core and the outer shell are the same semiconductor characterized by a large band-gap. So there is a significant gap-offset creating a deep potential well where the excitons are localized and strongly confined. We have adopted the Ritz variational method to calculate numerically the excitonic ground state energy and its binding energy in the strong, moderate and low confinement regimes. The results show that the Ritz variational method is in good agreement with the perturbation method in strong confinement. There is a double confinement effect and dual control. The calculation checks the effective Rydberg R* at the asymptotic limit of bulk semiconductor when the thickness takes very large values. The excitonic binding energy increases, Thus giving the excitons a high stability even at ambient temperature. These nanosystems are promising in several applications: lighting, detection, biological labeling and quantum computing.

  1. Influence of the nanoparticles agglomeration state in the quantum-confinement effects: Experimental evidences

    Energy Technology Data Exchange (ETDEWEB)

    Lorite, I., E-mail: lorite@physik.uni-leipzig.de [Electroceramic Department, Instituto de Cerámica y Vidrio, CSIC, Kelsen 5, 28049, Madrid (Spain); Division of Superconductivity and Magnetism, Faculty of Physics and Earth Sciences, Linnestrasse 5, D-04103 Leipzig (Germany); Romero, J. J.; Fernandez, J. F. [Electroceramic Department, Instituto de Cerámica y Vidrio, CSIC, Kelsen 5, 28049, Madrid (Spain)

    2015-03-15

    The agglomeration state facilitates particle-particle interaction which produces important effects in the phonon confinement effects at the nanoscale. A partial phonon transmission between close nanoparticles yields a lower momentum conservation relaxation than in a single isolated nanoparticle. It means a larger red shift and broadening of the Raman modes than the expected ones for Raman quantum confinement effects. This particle-particle interaction can drive to error when Raman responses are used to estimate the size of the nanoscaled materials. In this work different corrections are suggested to overtake this source of error.

  2. Influence of the nanoparticles agglomeration state in the quantum-confinement effects: Experimental evidences

    Directory of Open Access Journals (Sweden)

    I. Lorite

    2015-03-01

    Full Text Available The agglomeration state facilitates particle-particle interaction which produces important effects in the phonon confinement effects at the nanoscale. A partial phonon transmission between close nanoparticles yields a lower momentum conservation relaxation than in a single isolated nanoparticle. It means a larger red shift and broadening of the Raman modes than the expected ones for Raman quantum confinement effects. This particle-particle interaction can drive to error when Raman responses are used to estimate the size of the nanoscaled materials. In this work different corrections are suggested to overtake this source of error.

  3. Quantum mechanical solver for confined heterostructure tunnel field-effect transistors

    Energy Technology Data Exchange (ETDEWEB)

    Verreck, Devin, E-mail: devin.verreck@imec.be; Groeseneken, Guido [imec, Kapeldreef 75, 3001 Leuven (Belgium); Department of Electrical Engineering, KU Leuven, 3001 Leuven (Belgium); Van de Put, Maarten; Sorée, Bart; Magnus, Wim [imec, Kapeldreef 75, 3001 Leuven (Belgium); Departement of Physics, Universiteit Antwerpen, 2020 Antwerpen (Belgium); Verhulst, Anne S.; Collaert, Nadine; Thean, Aaron [imec, Kapeldreef 75, 3001 Leuven (Belgium); Vandenberghe, William G. [Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080 (United States)

    2014-02-07

    Heterostructure tunnel field-effect transistors (HTFET) are promising candidates for low-power applications in future technology nodes, as they are predicted to offer high on-currents, combined with a sub-60 mV/dec subthreshold swing. However, the effects of important quantum mechanical phenomena like size confinement at the heterojunction are not well understood, due to the theoretical and computational difficulties in modeling realistic heterostructures. We therefore present a ballistic quantum transport formalism, combining a novel envelope function approach for semiconductor heterostructures with the multiband quantum transmitting boundary method, which we extend to 2D potentials. We demonstrate an implementation of a 2-band version of the formalism and apply it to study confinement in realistic heterostructure diodes and p-n-i-n HTFETs. For the diodes, both transmission probabilities and current densities are found to decrease with stronger confinement. For the p-n-i-n HTFETs, the improved gate control is found to counteract the deterioration due to confinement.

  4. Understanding and tuning the quantum-confinement effect and edge magnetism in zigzag graphene nanoribbon.

    Science.gov (United States)

    Huang, Liang Feng; Zhang, Guo Ren; Zheng, Xiao Hong; Gong, Peng Lai; Cao, Teng Fei; Zeng, Zhi

    2013-02-06

    The electronic structure of zigzag graphene nanoribbon (ZGNR) is studied using density functional theory. The mechanisms underlying the quantum-confinement effect and edge magnetism in ZGNR are systematically investigated by combining the simulated results and some useful analytic models. The quantum-confinement effect and the inter-edge superexchange interaction can be tuned by varying the ribbon width, and the spin polarization and direct exchange splitting of the edge states can be tuned by varying their electronic occupations. The two edges of ZGNR can be equally or unequally tuned by charge doping or Li adsorption, respectively. The Li adatom has a site-selective adsorption on ZGNR, and it is a nondestructive and memorable approach to effectively modify the edge states in ZGNR. These systematic understanding and effective tuning of ZGNR electronics presented in this work are helpful for further investigation and application of ZGNR and other magnetic graphene systems.

  5. Confinement effect in a quantum well dot induced by an InP stressor

    Science.gov (United States)

    Tulkki, J.; Heinämäki, A.

    1995-09-01

    We have calculated the confinement effect in an In1-xGaxAs/GaAs quantum well dot induced by a dislocation-free InP stressor island. The energy levels were calculated by including the strain interaction and the band-edge confinement in the Luttinger-Kohn Hamiltonian. The maximum level spacing for the dipole-allowed interband E1-->HH1 line spectrum was 20 meV. Our calculation also gives excellent agreement with recent measurements [H. Lipsanen, M. Sopanen, and J. Ahopelto, Phys. Rev. B 51, 13 868 (1995)] and provides indirect evidence of screened Coulomb interaction, tentatively addressed to slow carrier relaxation.

  6. Effect of extended confinement on the structure of edge channels in the quantum anomalous Hall effect

    Science.gov (United States)

    Yue, Z.; Raikh, M. E.

    2016-09-01

    The Quantum anomalous Hall (QAH) effect in the films with nontrivial band structure accompanies the ferromagnetic transition in the system of magnetic dopants. Experimentally, the QAH transition manifests itself as a jump in the dependence of longitudinal resistivity on a weak external magnetic field. Microscopically, this jump originates from the emergence of a chiral edge mode on one side of the ferromagnetic transition. We study analytically the effect of an extended confinement on the structure of the edge modes. We employ the simplest model of the extended confinement in the form of a potential step next to the hard wall. It is shown that, unlike the conventional quantum Hall effect, where all edge channels are chiral, in the QAH effect, a complex structure of the boundary leads to nonchiral edge modes which are present on both sides of the ferromagnetic transition. Wave functions of nonchiral modes are different above and below the transition: on the "topological" side, where the chiral edge mode is supported, nonchiral modes are "repelled" from the boundary; i.e., they are much less localized than on the "trivial" side. Thus, the disorder-induced scattering into these modes will boost the extension of the chiral edge mode. The prime experimental manifestation of nonchiral modes is that, by contributing to longitudinal resistance, they smear the QAH transition.

  7. Simulating compact quantum electrodynamics with ultracold atoms: probing confinement and nonperturbative effects.

    Science.gov (United States)

    Zohar, Erez; Cirac, J Ignacio; Reznik, Benni

    2012-09-21

    Recently, there has been much interest in simulating quantum field theory effects of matter and gauge fields. In a recent work, a method for simulating compact quantum electrodynamics (CQED) using Bose-Einstein condensates has been suggested. We suggest an alternative approach, which relies on single atoms in an optical lattice, carrying 2l + 1 internal levels, which converges rapidly to CQED as l increases. That enables the simulation of CQED in 2 + 1 dimensions in both the weak and the strong coupling regimes, hence, allowing us to probe confinement as well as other nonperturbative effects of the theory. We provide an explicit construction for the case l = 1 which is sufficient for simulating the effect of confinement between two external static charges.

  8. Quantum confinement effect in cheese like silicon nano structure fabricated by metal induced etching

    Energy Technology Data Exchange (ETDEWEB)

    Saxena, Shailendra K., E-mail: phd1211512@iiti.ac.in; Sahu, Gayatri; Sagdeo, Pankaj R.; Kumar, Rajesh [Material Research Laboratory, Discipline of Physics & MSEG, Indian Institute of Technology Indore, Madhya Pradesh-452017 (India)

    2015-08-28

    Quantum confinement effect has been studied in cheese like silicon nano-structures (Ch-SiNS) fabricated by metal induced chemical etching using different etching times. Scanning electron microscopy is used for the morphological study of these Ch-SiNS. A visible photoluminescence (PL) emission is observed from the samples under UV excitation at room temperature due to quantum confinement effect. The average size of Silicon Nanostructures (SiNS) present in the samples has been estimated by bond polarizability model using Raman Spectroscopy from the red-shift observed from SiNSs as compared to its bulk counterpart. The sizes of SiNS present in the samples decreases as etching time increase from 45 to 75 mintunes.

  9. Inclusion of Quantum Confinement Effects in Self-Consistent Monte Carlo Device Simulations

    Directory of Open Access Journals (Sweden)

    R. W. Kelsall

    1998-01-01

    Full Text Available The design of Monte Carlo FET simulations is discussed, with specific attention to the methods used to describe quantum confinement effects. A new model is presented, which employs self-consistent coupling of Schrodinger, Poisson and Monte Carlo algorithms, and explicit calculation of the scattering rates between confined and unconfined states. Comparisons between the new model and a standard semi-classical Monte Carlo model are presented for a 0.1 μm gate-length In0.52Al0.48As/In0.53 Ga0.47As/InP MODFET. Whilst the quantum model yields minor corrections in the predicted output characteristics, it is found that these results can be achieved without repeated iterations of the Schrodinger equation.

  10. Self-screening of the quantum confined Stark effect by the polarization induced bulk charges in the quantum barriers

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zi-Hui; Liu, Wei; Ju, Zhengang; Tiam Tan, Swee; Ji, Yun; Kyaw, Zabu; Zhang, Xueliang; Wang, Liancheng; Wei Sun, Xiao, E-mail: exwsun@ntu.edu.sg, E-mail: volkan@stanfordalumni.org [LUMINOUS Centre of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, School of Physical and Mathematical Sciences, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Volkan Demir, Hilmi, E-mail: exwsun@ntu.edu.sg, E-mail: volkan@stanfordalumni.org [LUMINOUS Centre of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, School of Physical and Mathematical Sciences, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Department of Electrical and Electronics, Department of Physics, and UNAM-Institute of Material Science and Nanotechnology, Bilkent University, TR-06800 Ankara (Turkey)

    2014-06-16

    InGaN/GaN light-emitting diodes (LEDs) grown along the polar orientations significantly suffer from the quantum confined Stark effect (QCSE) caused by the strong polarization induced electric field in the quantum wells, which is a fundamental problem intrinsic to the III-nitrides. Here, we show that the QCSE is self-screened by the polarization induced bulk charges enabled by designing quantum barriers. The InN composition of the InGaN quantum barrier graded along the growth orientation opportunely generates the polarization induced bulk charges in the quantum barrier, which well compensate the polarization induced interface charges, thus avoiding the electric field in the quantum wells. Consequently, the optical output power and the external quantum efficiency are substantially improved for the LEDs. The ability to self-screen the QCSE using polarization induced bulk charges opens up new possibilities for device engineering of III-nitrides not only in LEDs but also in other optoelectronic devices.

  11. The role of the interface in germanium quantum dots: when not only size matters for quantum confinement effects.

    Science.gov (United States)

    Cosentino, S; Mio, A M; Barbagiovanni, E G; Raciti, R; Bahariqushchi, R; Miritello, M; Nicotra, G; Aydinli, A; Spinella, C; Terrasi, A; Mirabella, S

    2015-07-14

    Quantum confinement (QC) typically assumes a sharp interface between a nanostructure and its environment, leading to an abrupt change in the potential for confined electrons and holes. When the interface is not ideally sharp and clean, significant deviations from the QC rule appear and other parameters beyond the nanostructure size play a considerable role. In this work we elucidate the role of the interface on QC in Ge quantum dots (QDs) synthesized by rf-magnetron sputtering or plasma enhanced chemical vapor deposition (PECVD). Through a detailed electron energy loss spectroscopy (EELS) analysis we investigated the structural and chemical properties of QD interfaces. PECVD QDs exhibit a sharper interface compared to sputter ones, which also evidences a larger contribution of mixed Ge-oxide states. Such a difference strongly modifies the QC strength, as experimentally verified by light absorption spectroscopy. A large size-tuning of the optical bandgap and an increase in the oscillator strength occur when the interface is sharp. A spatially dependent effective mass (SPDEM) model is employed to account for the interface difference between Ge QDs, pointing out a larger reduction in the exciton effective mass in the sharper interface case. These results add new insights into the role of interfaces on confined systems, and open the route for reliable exploitation of QC effects.

  12. Design of Ge/SiGe quantum-confined Stark effect modulators for CMOS compatible photonics

    Science.gov (United States)

    Lever, Leon; Ikonić, Zoran; Valavanis, Alex; Kelsall, Robert W.

    2010-02-01

    A simulation technique for modeling optical absorption in Ge/SiGe multiple quantum well (MQW) heterostructures is described, based on a combined 6 × 6 k • p hole wave-function a one-band effective mass electron wavefunction calculation. Using this model, we employ strain engineering to target a specific applications-oriented wavelength, namely 1310 nm, and arrive at a design for a MQW structure to modulate light at this wavelength. The modal confinement in a proposed device is then found using finite-element modeling, and we estimate the performance of a proposed waveguide-integrated electroabsorption modulator.

  13. First-principle study of quantum confinement effect on small sized silicon quantum dots using density-functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Anas, M. M.; Othman, A. P.; Gopir, G. [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor (Malaysia)

    2014-09-03

    Density functional theory (DFT), as a first-principle approach has successfully been implemented to study nanoscale material. Here, DFT by numerical basis-set was used to study the quantum confinement effect as well as electronic properties of silicon quantum dots (Si-QDs) in ground state condition. Selection of quantum dot models were studied intensively before choosing the right structure for simulation. Next, the computational result were used to examine and deduce the electronic properties and its density of state (DOS) for 14 spherical Si-QDs ranging in size up to ∼ 2 nm in diameter. The energy gap was also deduced from the HOMO-LUMO results. The atomistic model of each silicon QDs was constructed by repeating its crystal unit cell of face-centered cubic (FCC) structure, and reconstructed until the spherical shape obtained. The core structure shows tetrahedral (T{sub d}) symmetry structure. It was found that the model need to be passivated, and hence it was noticed that the confinement effect was more pronounced. The model was optimized using Quasi-Newton method for each size of Si-QDs to get relaxed structure before it was simulated. In this model the exchange-correlation potential (V{sub xc}) of the electrons was treated by Local Density Approximation (LDA) functional and Perdew-Zunger (PZ) functional.

  14. Distributed Reflector Laser Integrated with Active and Passive Grating Sections Using Lateral Quantum Confinement Effect

    Science.gov (United States)

    Ohira, Kazuya; Murayama, Tomonori; Yagi, Hideki; Tamura, Shigeo; Arai, Shigehisa

    2003-08-01

    A new type of distributed reflector (DR) laser, monolithically integrated with wirelike active section and passive distributed Bragg reflector (DBR) section, was realized for the first time by using the lateral quantum confinement effect in quantum-wire structure. As a result, a threshold current density as low as 320 A/cm2 and a strong asymmetric output ratio of the front to the rear facet of 28 were obtained for a 20 μm wide stripe structure. For lower threshold and single-mode operation, a narrow stripe DR laser was fabricated. Threshold current of 7.4 mA and submode suppression ratio (SMSR) of 40 dB at a bias current of 1.2 times the threshold were obtained for a stripe width of 3 μm under room-temperature continuous-wave (RT-CW) condition.

  15. Enhanced Quantum Confined Stark Effect in a mesoporous hybrid multifunctional system

    Science.gov (United States)

    Gogoi, M.; Deb, P.; Sen, D.; Mazumder, S.; Kostka, A.

    2014-06-01

    Quantum Confined Stark Effect in hybrid of CdTe quantum dot with superparamagnetic iron oxide nanoparticles in both nonporous and mesoporous silica matrix has been realized. The observed QCSE is due to the local electric field induced by charge dispersion at SiO2/polar solvent interface. Enhanced Stark shift of 89.5 meV is observed in case of mesoporous hybrid structure and the corresponding local electric field has been evaluated as 4.38×104 V/cm. The enhancement is assumed to be caused by greater density of charge in the mesoporous hybrid. The conjugation of superparamagnetic nanoparticles in this tailored hybrid microstructure has not imparted any alteration to the Stark shift, but has added multifunctional attribute. The present study on the local electric field induced enhanced QCSE with wavelength modulation towards red end paves the way of developing magneto-fluorescent hybrid systems for biomedical imaging application.

  16. The surface termination effect on the quantum confinement and electron affinities of 3C-SiC quantum dots: a first-principles study.

    Science.gov (United States)

    Zhang, Zhenkui; Dai, Ying; Yu, Lin; Guo, Meng; Huang, Baibiao; Whangbo, Myung-Hwan

    2012-03-07

    In light of the established differences between the quantum confinement effect and the electron affinities between hydrogen-passivated C and Si quantum dots, we carried out theoretical investigations on SiC quantum dots, with surfaces uniformly terminated by C-H or Si-H bonds, to explore the role of surface terminations on these two aspects. Surprisingly, it was found that the quantum confinement effect is present (or absent) in the highest occupied (or lowest unoccupied) molecular orbital of the SiC quantum dots regardless of their surface terminations. Thus, the quantum confinement effect related to the energy gap observed experimentally (Phys. Rev. Lett., 2005, 94, 026102) is contributed to by the size-dependence of the highest occupied states; the absence of quantum confinement in the lowest unoccupied states is in contrary to the usual belief based on hydrogen-passivated C quantum dots. However, the cause of the absence of the quantum confinement in C nanodots is not transferable to SiC. We propose a model that provides a clear explanation for all findings on the basis of the nearest-neighbor and next-nearest-neighbor interactions between the valence atomic p-orbital in the frontier occupied/unoccupied states. We also found that the electron affinities of the SiC quantum dots, which closely depend on the surface environments, are negative for the C-H termination and positive for the Si-H termination. The prediction of negative electron affinities in SiC quantum dots by simple C-H termination indicates a promising application for these materials in electron-emitter devices. Our model predicts that GeC quantum dots with hydrogen passivation exhibit similar features to SiC quantum dots and our study confirms the crucial role that the surface environment plays in these nanoscale systems.

  17. Effect of confinement potential geometry on entanglement in quantum dot-based nanostructures

    CERN Document Server

    Abdullah, S; D'Amico, I

    2009-01-01

    We calculate the spatial entanglement between two electrons trapped in a nanostructure for a broad class of confinement potentials, including single and double quantum dots, and core-shell quantum dot structures. By using a parametrized confinement potential, we are able to switch from one structure to the others with continuity and to analyze how the entanglement is influenced by the changes in the confinement geometry. We calculate the many-body wave function by `exact' diagonalization of the time independent Schr\\"odinger equation. We discuss the relationship between the entanglement and specific cuts of the wave function, and show that the wave function at a single highly symmetric point could be a good indicator for the entanglement content of the system. We analyze the counterintuitive relationship between spatial entanglement and Coulomb interaction, which connects maxima (minima) of the first to minima (maxima) of the latter. We introduce a potential quantum phase transition which relates quantum stat...

  18. Segregation, quantum confinement effect and band offset for [110] SiGe NWs

    Energy Technology Data Exchange (ETDEWEB)

    Amato, Michele [CNR-Istituto di Nanoscienze, Modena (Italy); Dipartimento di Fisica, Universita' di Modena e Reggio Emilia, Modena (Italy); Palummo, Maurizia [European Theoretical Spectroscopy Facility (ETSF), CNR-INFM-SMC, Roma (Italy); Dipartimento di Fisica, Universita di Roma, ' Tor Vergata' , Roma (Italy); Ossicini, Stefano [European Theoretical Spectroscopy Facility (ETSF), CNR-Istituto di Nanoscienze ' ' Centro S3' ' , Reggio Emilia (Italy); Dipartimento di Scienze e Metodi dell' Ingegneria, e Centro Interdipartimentale ' ' En and Tech' ' , Universita di Modena e Reggio Emilia, Reggio Emilia (Italy)

    2010-08-15

    Results of first-principles DFT simulations provide strong evidence that, at zero temperature, for [110] oriented SiGe nanowires (NWs), the segregated structure is favoured with respect to the mixed ones; for this observation two different schemes of calculations are presented and discussed. Moreover the segregation strongly influences the NWs electronic properties, inducing a reduced quantum confined effect (RQCE). We show here that it depends on the effect of strain in the plane normal to the direction of growth and not on the choice of lattice parameter in the direction of growth. A qualitative evaluation of the band offset between Si and Ge for SiGe NWs is also presented. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  19. Electronic Quantum Confinement in Cylindrical Potential Well

    CERN Document Server

    Baltenkov, A S

    2016-01-01

    The effects of quantum confinement on the momentum distribution of electrons confined within a cylindrical potential well have been analyzed. The motivation is to understand specific features of the momentum distribution of electrons when the electron behavior is completely controlled by the parameters of a non-isotropic potential cavity. It is shown that studying the solutions of the wave equation for an electron confined in a cylindrical potential well offers the possibility to analyze the confinement behavior of an electron executing one- or two-dimensional motion in the three-dimensional space within the framework of the same mathematical model. Some low-lying electronic states with different symmetries have been considered and the corresponding wave functions have been calculated; the behavior of their nodes and their peak positions with respect to the parameters of the cylindrical well has been analyzed. Additionally, the momentum distributions of electrons in these states have been calculated. The limi...

  20. Ge/SiGe quantum confined Stark effect electro-absorption modulation with low voltage swing at λ = 1550 nm.

    Science.gov (United States)

    Dumas, D C S; Gallacher, K; Rhead, S; Myronov, M; Leadley, D R; Paul, D J

    2014-08-11

    Low-voltage swing (≤1.0 V) high-contrast ratio (6 dB) electro-absorption modulation covering 1460 to 1560 nm wavelength has been demonstrated using Ge/SiGe quantum confined Stark effect (QCSE) diodes grown on a silicon substrate. The heterolayers for the devices were designed using an 8-band k.p Poisson-Schrödinger solver which demonstrated excellent agreement with the experimental results. Modelling and experimental results demonstrate that by changing the quantum well width of the device, low power Ge/SiGe QCSE modulators can be designed to cover the S- and C-telecommunications bands.

  1. Extra-dimensional confinement of quantum particles

    CERN Document Server

    Hedin, Eric R

    2016-01-01

    A basic theoretical framework is developed in which elementary particles have a component of their wave function extending into higher spatial dimensions. This model postulates an extension of the Schrodinger equation to include a 4th and 5th spatial component. A higher-dimensional simple harmonic oscillator confining potential localizes particles into 3-d space, characterizing the brane tension which confines Standard Model particles to the sub-manifold. Quantum effects allow a non-zero probability for a particle's evanescent existence in the higher dimensions, and suggest an experimental test for the validity of this model via particles being temporarily excited into the first excited state of the extra-dimensional potential well, in which their probability of existing in 3-d space transiently drops to zero. Several consistency checks of the outcomes of this extra-dimensional model are included in this paper. Among the outcomes of this model are: a match with the quantum phenomenon of zitterbewegung; the pr...

  2. Quantum Confined Semiconductors for High Efficiency Photovoltaics

    Science.gov (United States)

    Beard, Matthew

    2014-03-01

    Semiconductor nanostructures, where at least one dimension is small enough to produce quantum confinement effects, provide new pathways for controlling energy flow and therefore have the potential to increase the efficiency of the primary photon-to-free energy conversion step. In this discussion, I will present the current status of research efforts towards utilizing the unique properties of colloidal quantum dots (NCs confined in three dimensions) in prototype solar cells and demonstrate that these unique systems have the potential to bypass the Shockley-Queisser single-junction limit for solar photon conversion. The solar cells are constructed using a low temperature solution based deposition of PbS or PbSe QDs as the absorber layer. Different chemical treatments of the QD layer are employed in order to obtain good electrical communication while maintaining the quantum-confined properties of the QDs. We have characterized the transport and carrier dynamics using a transient absorption, time-resolved THz, and temperature-dependent photoluminescence. I will discuss the interplay between carrier generation, recombination, and mobility within the QD layers. A unique aspect of our devices is that the QDs exhibit multiple exciton generation with an efficiency that is ~ 2 to 3 times greater than the parental bulk semiconductor.

  3. Self-assembly of a novel beta-In2S3 nanostructure exhibiting strong quantum confinement effects.

    Science.gov (United States)

    Zhang, Wu; Ma, Dekun; Huang, Zhen; Tang, Qun; Xie, Qin; Qian, Yitai

    2005-05-01

    The 3D beta-In2S3 flowerlike architecture assembled from nanoflakes was prepared via a novel complex-precursor assisted (CPA) solvothermal route. The as-prepared beta-In2S3 powder was characterized by X-ray diffraction pattern (XRD), X-ray photoelectron spectra (XPS), transition electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), ultraviolet-visible light (UV-vis) spectra, and photoluminescence spectrum. The novel 3D beta-In2S3 nanostructure exhibit a strong quantum confinement effect. FT-IR spectra were used to investigate the coordinative chemical effect in the complex. A possible mechanism was discussed.

  4. Optical investigation of the one-dimensional confinement effects in narrow GaAs/GaAlAs quantum wires

    Science.gov (United States)

    Birotheau, L.; Izrael, A.; Marzin, J. Y.; Azoulay, R.; Thierry-Mieg, V.; Ladan, F. R.

    1992-12-01

    We show optical data obtained at 8 K on narrow GaAs/GaAlAs quantum wires, with width down to 15 nm, fabricated by reactive ion etching and metal organic chemical vapor deposition overgrowth. Lateral confinement energies (up to 23 meV) and polarization effects are evidenced in the photoluminescence excitation spectra. These experimental results are in good agreement with calculated absorption spectra, which include the effects of wire width fluctuations, yielding, for our fabrication technique, a value of ±5 nm for these size fluctuations.

  5. Theory of Confined Quantum Time of Arrivals

    CERN Document Server

    Galapon, E A

    2005-01-01

    We extend the concept of confined quantum time of arrival operators, first developed for the free particle [E.A. Galapon, R. Caballar, R. Bahague {\\it Phys. Rev. Let.} {\\bf 93} 180406 (2004)], to arbitrary potentials.

  6. Fast Tuneable InGaAsP DBR Laser Using Quantum-Confined Stark-Effect-Induced Refractive Index Change

    OpenAIRE

    Pantouvaki, M.; Renaud, C. C.; Cannard, P; Robertson, M. J.; Gwilliam, R; Seeds, A. J.

    2007-01-01

    We report a monolithically integrated InGaAsP DBR ridge waveguide laser that uses the quantum-confined Stark effect (QCSE) to achieve fast tuning response. The laser incorporates three sections: a forward-biased gain section, a reverse-biased phase section, and a reverse-biased DBR tuning section. The laser behavior is modeled using transmission matrix equations and tuning over similar to 8 nm is predicted. Devices were fabricated using post-growth shallow ion implantation to reduce the loss ...

  7. Relativistic quantum effects of confining potentials on the Klein-Gordon oscillator

    Science.gov (United States)

    Vitória, R. L. L.; Bakke, K.

    2016-02-01

    The behaviour of the Klein-Gordon oscillator under the influence of linear and Coulomb-type potentials is investigated. The introduction of the scalar potentials is made by modifying the mass term of the Klein-Gordon equation, then, by searching for relativistic bound states, a particular quantum effect can be observed: a dependence of the angular frequency of the Klein-Gordon oscillator on the quantum numbers associated with the radial modes and the angular momentum. As an example, we analyse the angular frequency and the energy level associated with the ground state of the relativistic system.

  8. Quantum confinement and its related effects on the critical size of GeO2 nanoparticles anodes for lithium batteries.

    Science.gov (United States)

    Son, Yoonkook; Park, Mihee; Son, Yeonguk; Lee, Jung-Soo; Jang, Ji-Hyun; Kim, Youngsik; Cho, Jaephil

    2014-02-12

    This work has been performed to determine the critical size of the GeO2 nanoparticle for lithium battery anode applications and identify its quantum confinement and its related effects on the electrochemical performance. GeO2 nanoparticles with different sizes of ∼ 2, ∼ 6, ∼ 10, and ∼ 35 nm were prepared by adjusting the reaction rate, controlling the reaction temperature and reactant concentration, and using different solvents. Among the different sizes of the GeO2 nanoparticles, the ∼ 6 nm sized GeO2 showed the best electrochemical performance. Unexpectedly smaller particles of the ∼ 2 nm sized GeO2 showed the inferior electrochemical performances compared to those of the ∼ 6 nm sized one. This was due to the low electrical conductivity of the ∼ 2 nm sized GeO2 caused by its quantum confinement effect, which is also related to the increase in the charge transfer resistance. Those characteristics of the smaller nanoparticles led to poor electrochemical performances, and their relationships were discussed.

  9. Strong quantum confinement effect in Cu{sub 4}SnS{sub 4} quantum dots synthesized via an improved hydrothermal approach

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yuehui; Ma, Ligang; Yin, Yan; Qian, Xu; Zhou, Guotai; Gu, Xiaomin [National Laboratory of Solid State Microstructures and Photovoltaic Engineering Center, Department of Physics, Nanjing University, Nanjing (China); Liu, Wenchao, E-mail: wcliu@nju.edu.cn [National Laboratory of Solid State Microstructures and Photovoltaic Engineering Center, Department of Physics, Nanjing University, Nanjing (China); Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials - SICAM, Nanjing Tech University - NanjingTech, Nanjing (China); Wu, Xiaoshan, E-mail: xswu@nju.edu.cn [National Laboratory of Solid State Microstructures and Photovoltaic Engineering Center, Department of Physics, Nanjing University, Nanjing (China); Zhang, Fengming [National Laboratory of Solid State Microstructures and Photovoltaic Engineering Center, Department of Physics, Nanjing University, Nanjing (China)

    2016-07-05

    We developed an improved hydrothermal method with water-oil two-phase reaction system to synthesize size-controllable and oil-soluble Cu{sub 4}SnS{sub 4} (CTS) quantum dots (QDs). The water-oil interface played an important role in controlling nuclei process, growth speed, crystal size and size-distribution of CTS QDs. X-ray diffraction, Raman scattering and transmission electron microscopy studies suggested that the formation and growth mechanism of CTS QDs was revealed to involve three steps. The crystallographic orientation of the CTS nanoprism was analyzed in detail. The blue-shift of absorption edge and broadening of Raman bands were observed due to the quantum confinement effect. The exciton Bohr radius of CTS QDs was calculated to be 3.3–5.8 nm by using the first principle calculation. The size dependence of band-gaps of CTS QDs follows the particle-in-a-box effective-mass model. The ability to fabricate high-quality CTS QDs certainly facilitates the solar cell applications. - Highlights: • We develop an improved hydrothermal method to synthesize monodisperse CTS QDs. • The size can be controlled through controlling the oil/water ratio. • The quantum confinement effect is confirmed by experiments and calculation.

  10. Einstein's Photoemission from Quantum Confined Superlattices.

    Science.gov (United States)

    Debbarma, S; Ghatak, K P

    2016-01-01

    This paper is dedicated to the 83th Birthday of Late Professor B. R. Nag, D.Sc., formerly Head of the Departments of Radio Physics and Electronics and Electronic Science of the University of Calcutta, a firm believer of the concept of theoretical minimum of Landau and an internationally well known semiconductor physicist, to whom the second author remains ever grateful as a student and research worker from 1974-2004. In this paper, an attempt is made to study, the Einstein's photoemission (EP) from III-V, II-VI, IV-VI, HgTe/CdTe and strained layer quantum well heavily doped superlattices (QWHDSLs) with graded interfaces in the presence of quantizing magnetic field on the basis of newly formulated electron dispersion relations within the frame work of k · p formalism. The EP from III-V, II-VI, IV-VI, HgTe/CdTe and strained layer quantum wells of heavily doped effective mass superlattices respectively has been presented under magnetic quantization. Besides the said emissions, from the quantum dots of the aforementioned heavily doped SLs have further investigated for the purpose of comparison and complete investigation in the context of EP from quantum confined superlattices. Using appropriate SLs, it appears that the EP increases with increasing surface electron concentration and decreasing film thickness in spiky manners, which are the characteristic features of such quantized hetero structures. Under magnetic quantization, the EP oscillates with inverse quantizing magnetic field due to Shuvnikov-de Haas effect. The EP increases with increasing photo energy in a step-like manner and the numerical values of EP with all the physical variables are totally band structure dependent for all the cases. The most striking features are that the presence of poles in the dispersion relation of the materials in the absence of band tails create the complex energy spectra in the corresponding HD constituent materials of such quantum confined superlattices and effective electron

  11. Singlet-Triplet Transition in Quantum Dots Confined by Triangular and Bowl-Like Potentials: the Effect of Electric Fields

    Institute of Scientific and Technical Information of China (English)

    SUN Lian-Liang; LI Shu-Shen

    2005-01-01

    @@ We theoretically investigate the energy spectra of two-electron two-dimensional (2e 2D) quantum dots (QDs)confined by triangular potentials and bowl-like potentials in a magnetic field by exact diagonalization in the framework of effective mass theory. An in-plane electric field is found to contribute to the singlet-triplet transition of the ground state of the 2e 2D QDs confined by triangular or bowl-like potentials in a perpendicular magnetic field. The stronger the in-plane electric field, the smaller the magnetic field for the total spin of the ground states in the dot systems to change from S = 0 to S = 1. However, the influence of anin-plane electric field on the singlettriplet transition of the ground state of two electrons in a triangular QD modulated by a perpendicular magnetic field is quite small because the triangular potential just deviates from the harmonic potential well slightly. We find that the strength of the perpendicular magnetic field needed for the spin singlet-triplet transition of the ground state of the QD confined by a bowl-like potential is reduced drastically by applying an in-plane electric field.

  12. Electronic structure and lattice relaxations in quantum confined Pb films

    NARCIS (Netherlands)

    Mans, A.

    2005-01-01

    Epitaxial films that are only several atoms layers thick exhibit interesting properties associated with quantum confinement. The electrons form standing waves, just like a violin string, clamped at both ends. In ultrathin lead films, this so-called `quantum size effect' (QSE) alters the physical pro

  13. Confinement Physics in Quantum Chromodynamics

    CERN Document Server

    Suganuma, H; Amemiya, K; Tanaka, A; Suganuma, Hideo; Ichie, Hiroko; Amemiya, Kazuhisa; Tanaka, Atsunori

    1998-01-01

    We study the confinement physics in QCD in the maximally abelian (MA) gauge using the SU(2) lattice QCD, based on the dual-superconductor picture. In the MA gauge, off-diagonal gluon components are forced to be small, and the off-diagonal angle variable $\\chi_\\mu(s)$ tends to be random. Within the random-variable approximation for $\\chi_\\mu(s)$, we analytically prove the perimeter law of the off-diagonal gluon contribution to the Wilson loop in the MA gauge, which leads to abelian dominance on the string tension. To clarify the origin of abelian dominance for the long-range physics, we study the charged-gluon propagator in the MA gauge using the lattice QCD, and find that the effective mass $m_{ch} \\simeq 0.9 {\\rm GeV}$ of the charged gluon is induced by the MA gauge fixing. In the MA gauge, there appears the macroscopic network of the monopole world-line covering the whole system, which would be identified as monopole condensation at a large scale. To prove monopole condensation in the field-theoretical mann...

  14. Effect of magnetic field on quantum state energies of an electron confined in the core of a double walled carbon nanotube

    Science.gov (United States)

    Shah, Khurshed A.; Bhat, Bashir Mohi Ud Din

    2016-10-01

    In this paper we report the effect of external magnetic field and core radius on the excited quantum state energies of an electron confined in the core of a double walled carbon nanotube. The goal is accomplished by using Wentzel-Kramers-Brillioun (WKB) approximation method within the effective mass approximation and confinement potential. All numerical analysis were carried out in a strong confinement regime. The results show that the electron energy increases with the increase in external magnetic field at a given core radii. The electron energy is also found to increase as the core radius of the CNT decreases and for core radius a > 5 nm the energy becomes almost zero. The effect of magnetic field on the excited state energies of the confined electron is more evident for smaller core radius acarbon nanotube quantum dot devices [1].

  15. Influence of quantum-confined Stark effect on optical properties within trench defects in InGaN quantum wells with different indium content

    Energy Technology Data Exchange (ETDEWEB)

    Vaitkevičius, A., E-mail: augustas.vaitkevicius@gmail.com; Mickevičius, J.; Dobrovolskas, D.; Tamulaitis, G. [Semiconductor Physics Department and Institute of Applied Research, Vilnius University, Sauletekio 9-III, LT-10222 Vilnius (Lithuania); Tuna, Ö.; Giesen, C.; Heuken, M. [AIXTRON SE, Kaiserstr. 98, 52134 Herzogenrath (Germany)

    2014-06-07

    The trench defects in InGaN/GaN multiple quantum well structures are studied using confocal photoluminescence (PL) spectroscopy and atomic force microscopy. A strong blueshift (up to ∼280 meV) and an intensity increase (by up to a factor of 700) of the emission are demonstrated for regions enclosed by trench loops. The influence of the difference in the well width inside and outside the trench loops observed by transmission electron microscopy, the compositional pulling effect, the strain relaxation inside the loop, and corresponding reduction in the built-in field on the PL band peak position and intensity were estimated. The competition of these effects is mainly governed by the width of the quantum wells in the structure. It is shown that the PL band blueshift observed within the trench defect loops in the InGaN structures with wide quantum wells is mainly caused by the reduction in efficiency of the quantum-confined Stark effect due to strain relaxation.

  16. Confined Quantum Time of Arrivals

    CERN Document Server

    Galapon, E A; Galapon, Eric A.; Bahague, Ricardo T.

    2003-01-01

    We show that the non-self-adjoint free time of arrival operator in free space defines a class of compact, self-adjoint, and canonical operators for a spatially confined particle. We analytically and numerically study the qualitative behaviors of these operators, and demonstrate that their eigenfunctions and eigenvalues are consistent with the interpretation that they are time of arrival operators.

  17. Simple theoretical analysis of the photoemission from quantum confined effective mass superlattices of optoelectronic materials

    Directory of Open Access Journals (Sweden)

    Debashis De

    2011-07-01

    Full Text Available The photoemission from quantum wires and dots of effective mass superlattices of optoelectronic materials was investigated on the basis of newly formulated electron energy spectra, in the presence of external light waves, which controls the transport properties of ultra-small electronic devices under intense radiation. The effect of magnetic quantization on the photoemission from the aforementioned superlattices, together with quantum well superlattices under magnetic quantization, has also been investigated in this regard. It appears, taking HgTe/Hg1−xCdxTe and InxGa1−xAs/InP effective mass superlattices, that the photoemission from these quantized structures is enhanced with increasing photon energy in quantized steps and shows oscillatory dependences with the increasing carrier concentration. In addition, the photoemission decreases with increasing light intensity and wavelength as well as with increasing thickness exhibiting oscillatory spikes. The strong dependence of the photoemission on the light intensity reflects the direct signature of light waves on the carrier energy spectra. The content of this paper finds six different applications in the fields of low dimensional systems in general.

  18. The pinning effect in a polar semiconductor quantum dot with Gaussian confinement: A study using the improved Wigner–Brillouin perturbation theory

    Energy Technology Data Exchange (ETDEWEB)

    P J, Monisha, E-mail: pjmonisha@gmail.com [School of Physics, University of Hyderabad, Hyderabad 500046 (India); Mukhopadhyay, Soma [Department of Physics, D V R college of Engineering and Technology, Hyderabad 502285 (India)

    2015-05-01

    The effect of electron–phonon interaction on a few low-lying energy levels in a polar semiconductor quantum dot with Gaussian confinement is studied by using an improved Wigner–Brillouin perturbation theory (IWBPT). In the absence of the electron–phonon interaction, the electronic ground state plus one phonon state is degenerate with the first excited electronic state plus the zero-phonon state at some value of the confinement length. Similarly, the electronic ground state plus one phonon state is also degenerate with the second excited electronic state plus the zero-phonon state at a larger value of the confinement length. It is shown that the electron–phonon interaction lifts these degeneracies and as a result, the excited state energy levels bend downward and get pinned to the ground state plus one phonon state as the confinement frequency is increased. Our calculations are finally applied to GaAs and InSb quantum dots.

  19. Valence band offset, strain and shape effects on confined states in self-assembled InAs/InP and InAs/GaAs quantum dots

    Science.gov (United States)

    >M Zieliński,

    2013-11-01

    I present a systematic study of self-assembled InAs/InP and InAs/GaAs quantum dot single-particle and many-body properties as a function of the quantum dot-surrounding matrix valence band offset. I use an atomistic, empirical tight-binding approach and perform numerically demanding calculations for half-million-atom nanosystems. I demonstrate that the overall confinement in quantum dots is a non-trivial interplay of two key factors: strain effects and the valence band offset. I show that strain effects determine both the peculiar structure of confined hole states of lens type InAs/GaAs quantum dots and the characteristic ‘shell-like’ structure of confined hole states in the commonly considered ‘low-strain’ lens type InAs/InP quantum dot. I also demonstrate that strain leads to single-band-like behavior of hole states of disk type (‘indium flushed’) InAs/GaAs and InAs/InP quantum dots. I show how strain and valence band offset affect quantum dot many-body properties: the excitonic fine structure, an important factor for efficient entangled photon pair generation, and the biexciton and charged exciton binding energies.

  20. Quantum confinement effects on optical transitions in nanodiamonds containing nitrogen vacancies

    Science.gov (United States)

    Petrone, Alessio; Goings, Joshua J.; Li, Xiaosong

    2016-10-01

    Colored nitrogen-vacancy (NV) centers in nanosize diamonds (d ˜5 nm) are promising probe materials because their optical transitions are sensitive to mechanical, vibrational, and spin changes in the surroundings. Here, a linear response time-dependent density functional theory approach is used to describe the optical transitions in several NV-doped diamond quantum dots (QDs) in order to investigate size effects on the absorption spectra. By computing the full optical spectrum up to band-to-band transitions, we analyze both the localized "pinned" midgap and the charge-transfer excitations for an isolated reduced NV center. Subband charge-transfer excitations are shown to be size dependent, involving the excitation of the dopant s p3 electrons to the diamond conduction band. Additionally, the NV-doped systems exhibit characteristic s p3-s p3 excitations whose experimental energies are reproduced well and do not depend on QD size. However, the NV position and global cluster symmetry can affect the amount of the energy splitting of the vertical excitation energies of the midgap transitions.

  1. Quantum confinement effect in Si/Ge core-shell nanowires: First-principles calculations

    Science.gov (United States)

    Yang, Li; Musin, Ryza N.; Wang, Xiao-Qian; Chou, M. Y.

    2008-05-01

    The electronic structure of Si/Ge core-shell nanowires along the [110] and [111] directions are studied with first-principles calculations. We identify the near-gap electronic states that are spatially separated within the core or the shell region, making it possible for a dopant to generate carriers in a different region. The confinement energies of these core and shell states provide an operational definition of the “band offset,” which is not only size dependent but also component dependent. The optimal doping strategy in Si/Ge core-shell nanowires is proposed based on these energy results.

  2. Storage of energy in confined quantum systems

    OpenAIRE

    Malbouisson, A. P. C.

    2002-01-01

    Using the non-perturbative method of {\\it dressed} states introduced in previous publications [N.P.Andion, A.P.C. Malbouisson and A. Mattos Neto, J.Phys.{\\bf A34}, 3735, (2001); G. Flores-Hidalgo, A.P.C. Malbouisson, Y.W. Milla, Phys. Rev. A, {\\bf 65}, 063314 (2002)], we study the evolution of a confined quantum mechanical system embedded in a {\\it ohmic} environment. Our approach furnishes a theoretical mechanism to control inhibition of the decay of excited quantum systems in cavities, in b...

  3. Interplay between quantum confinement and dielectric mismatch for ultrashallow dopants

    NARCIS (Netherlands)

    Mol, J.A.; Salfi, J.; Miwa, J.A.; Simmons, M.Y.; Rogge, S.

    2013-01-01

    Understanding the electronic properties of dopants near an interface is a critical challenge for nanoscale devices. We have determined the effect of dielectric mismatch and quantum confinement on the ionization energy of individual acceptors beneath a hydrogen passivated silicon (100) surface. While

  4. Observation of the Quantum-Confined Stark Effect in a GaAs/AlGaAs P-I-N Diode by Room Temperature Photocurrent Spectroscopy

    Directory of Open Access Journals (Sweden)

    C. S. Ison

    2003-06-01

    Full Text Available Room temperature photocurrent spectroscopy is performed on an MBE-grown GaAs/AlGaAs MQWp-i-n device. An observed shift to longer wavelengths is seen with increasing reverse bias voltages. Thisbehavior is explained through a mechanism called the Quantum-Confined Stark Effect. Applied electricfields are estimated using second-order correction for infinite quantum wells. The estimated built-inelectric field is 20 kV/cm corresponding to a 9-meV shift from the flatband energy transition. An observedshift to shorter wavelengths is seen under an optically applied field for both biased and unbiased conditions.

  5. Quantum confinement and Coulomb blockade in isolated nanodiamond crystallites

    Science.gov (United States)

    Bolker, Asaf; Saguy, Cecile; Tordjman, Moshe; Kalish, Rafi

    2013-07-01

    We present direct experimental evidence of quantum confinement effects in single isolated nanodiamonds by scanning tunneling spectroscopy. For grains smaller than 4.5 nm, the band gap was found to increase with decreasing nanodiamond size and a well-defined, evenly spaced, 12-peak structure was observed on the conduction band side of the conductance curves. We attribute these peaks to the Coulomb blockade effect, reflecting the 12-fold degeneracy of the first electron-energy level in the confined nanodiamond. The present results shed light on the size dependence of the electronic properties of single nanodiamonds and are of major importance for future nanodiamond-based applications.

  6. Nanometer-scale monitoring of quantum-confined Stark effect and emission efficiency droop in multiple GaN/AlN quantum disks in nanowires

    Science.gov (United States)

    Zagonel, L. F.; Tizei, L. H. G.; Vitiello, G. Z.; Jacopin, G.; Rigutti, L.; Tchernycheva, M.; Julien, F. H.; Songmuang, R.; Ostasevicius, T.; de la Peña, F.; Ducati, C.; Midgley, P. A.; Kociak, M.

    2016-05-01

    We report on a detailed study of the intensity dependent optical properties of individual GaN/AlN quantum disks (QDisks) embedded into GaN nanowires (NW). The structural and optical properties of the QDisks were probed by high spatial resolution cathodoluminescence (CL) in a scanning transmission electron microscope (STEM). By exciting the QDisks with a nanometric electron beam at currents spanning over three orders of magnitude, strong nonlinearities (energy shifts) in the light emission are observed. In particular, we find that the amount of energy shift depends on the emission rate and on the QDisk morphology (size, position along the NW and shell thickness). For thick QDisks (>4 nm), the QDisk emission energy is observed to blueshift with the increase of the emission intensity. This is interpreted as a consequence of the increase of carriers density excited by the incident electron beam inside the QDisks, which screens the internal electric field and thus reduces the quantum confined Stark effect (QCSE) present in these QDisks. For thinner QDisks (current threshold above which the energy shifts, marking the transition from unscreened to partially screened QCSE. From the threshold value we estimate the lifetime in the unscreened regime. These observations suggest that, counterintuitively, electrons of high energy can behave ultimately as single electron-hole pair generators. In addition, when we increase the current from 1 to 10 pA the light emission efficiency drops by more than one order of magnitude. This reduction of the emission efficiency is a manifestation of the "efficiency droop" as observed in nitride-based 2D light emitting diodes, a phenomenon tentatively attributed to the Auger effect.

  7. Theoretical study of quantum confined Stark shift in InAs/GaAs quantum dots

    Institute of Scientific and Technical Information of China (English)

    Guo Ru-Hai; Shi Hong-Yan; Sun Xiu-Dong

    2004-01-01

    The quantum confined Stark effect (QCSE) of the self-assembled InAs/GaAs quantum dots has been investigated theoretically. The ground-state transition energies for quantum dots in the shape of a cube, pyramid or "truncated pyramid" are calculated and analysed. We use a method based on the Green function technique for calculating the strain in quantum dots and an efficient plane-wave envelope-function technique to determine the ground-state electronic structure of them with different shapes. The symmetry of quantum dots is broken by the effect of strain. So the properties of carriers show different behaviours from the traditional quantum device. Based on these results, we also calculate permanent built-in dipole moments and compare them with recent experimental data. Our results demonstrate that the measured Stark effect in self-assembled InAs/GaAs quantum dot structures can be explained by including linear grading.

  8. Quantum Chromodynamics and Color Confinement (confinement 2000) - Proceedings of the International Symposium

    Science.gov (United States)

    Suganuma, H.; Fukushima, M.; Toki, H.

    The Table of Contents for the book is as follows: * Preface * Opening Address * Monopole Condensation and Quark Confinement * Dual QCD, Effective String Theory, and Regge Trajectories * Abelian Dominance and Monopole Condensation * Non-Abelian Stokes Theorem and Quark Confinement in QCD * Infrared Region of QCD and Confining Configurations * BRS Quartet Mechanism for Color Confinement * Color Confinement and Quartet Mechanism * Numerical Tests of the Kugo-Ojima Color Confinement Criterion * Monopoles and Confinement in Lattice QCD * SU(2) Lattice Gauge Theory at T > 0 in a Finite Box with Fixed Holonomy * Confining and Dirac Strings in Gluodynamics * Cooling, Monopoles, and Vortices in SU(2) Lattice Gauge Theory * Quark Confinement Physics from Lattice QCD * An (Almost) Perfect Lattice Action for SU(2) and SU(3) Gluodynamics * Vortices and Confinement in Lattice QCD * P-Vortices, Nexuses and Effects of Gribov Copies in the Center Gauges * Laplacian Center Vortices * Center Vortices at Strong Couplings and All Couplings * Simulations in SO(3) × Z(2) Lattice Gauge Theory * Exciting a Vortex - the Cost of Confinement * Instantons in QCD * Deformation of Instanton in External Color Fields * Field Strength Correlators in the Instanton Liquid * Instanton and Meron Physics in Lattice QCD * The Dual Ginzburg-Landau Theory for Confinement and the Role of Instantons * Lattice QCD for Quarks, Gluons and Hadrons * Hadronic Spectral Functions in QCD * Universality and Chaos in Quantum Field Theories * Lattice QCD Study of Three Quark Potential * Probing the QCD Vacuum with Flavour Singlet Objects : η' on the Lattice * Lattice Studies of Quarks and Gluons * Quarks and Hadrons in QCD * Supersymmetric Nonlinear Sigma Models * Chiral Transition and Baryon-number Susceptibility * Light Quark Masses in QCD * Chiral Symmetry of Baryons and Baryon Resonances * Confinement and Bound States in QCD * Parallel Session * Off-diagonal Gluon Mass Generation and Strong Randomness of Off

  9. Quantum-Confined Stark Effect Analysis of GeSn/SiGeSn Quantum Wells for Mid-Infrared Si-Based Electroabsorption Devices Based on Many-Body Theory

    OpenAIRE

    Fujisawa, Takeshi; Saitoh, Kunimasa

    2015-01-01

    Quantum-confined Stark effect (QCSE) of group IV Ge(Sn)/SiGe(Sn) quantum wells (QWs) on Si substrate is analyzed by microscopic many-body theory for mid-infrared (mid-IR) Si-based electroabsorption devices. To show the validity of the theory, QCSE of Ge/SiGe QW is investigated and very good agreement between theory and reported measured results is obtained. Next, the QCSE of GeSn/SiGeSn QWs is analyzed and the QW design for electroabsorption modulators to obtain large extinction ratio in mid-...

  10. Combining ligand-induced quantum-confined stark effect with type II heterojunction bilayer structure in CdTe and CdSe nanocrystal-based solar cells.

    Science.gov (United States)

    Yaacobi-Gross, Nir; Garphunkin, Natalia; Solomeshch, Olga; Vaneski, Aleksandar; Susha, Andrei S; Rogach, Andrey L; Tessler, Nir

    2012-04-24

    We show that it is possible to combine several charge generation strategies in a single device structure, the performance of which benefits from all methods used. Exploiting the inherent type II heterojunction between layered structures of CdSe and CdTe colloidal quantum dots, we systematically study different ways of combining such nanocrystals of different size and surface chemistry and with different linking agents in a bilayer solar cell configuration. We demonstrate the beneficial use of two distinctly different sizes of NCs not only to improve the solar spectrum matching but also to reduce exciton binding energy, allowing their efficient dissociation at the interface. We further make use of the ligand-induced quantum-confined Stark effect in order to enhance charge generation and, hence, overall efficiency of nanocrystal-based solar cells.

  11. Quantum Confinement and Negative Heat Capacity

    OpenAIRE

    Serra, Pablo; Carignano, Marcelo; Alharbi, Fahhad; Kais, Sabre

    2013-01-01

    Thermodynamics dictates that the specific heat of a system is strictly non-negative. However, in finite classical systems there are well known theoretical and experimental cases where this rule is violated, in particular finite atomic clusters. Here, we show for the first time that negative heat capacity can also occur in finite quantum systems. The physical scenario on which this effect might be experimentally observed is discussed. Observing such an effect might lead to the design of new li...

  12. Quantum confinement in GaP nanoclusters

    Energy Technology Data Exchange (ETDEWEB)

    Laurich, B.K.; Smith, D.C.; Healy, M.D.

    1994-06-01

    We have prepared GaP and GaAs nanoclusters from organometallic condensation reactions of E[Si(ChH{sub 3})3]3 (E = P, As) and GaCl{sub 3}. The size of the as synthesized clusters is 10 {Angstrom} to 15 {Angstrom}. Larger clusters of 20 {Angstrom} to 30 {Angstrom} size were obtained by thermal annealing of the as grown material. X-ray diffraction and transmission electron microscopy confirm the high crystalline quality. A lattice contraction of 6.7% could be seen for 10 {Angstrom} sized GaAs clusters. The clusters are nearly spherical in shape. Optical absorption spectra show a distinct line which can be assigned to the fundamental transition of the quantum confined electronic state. The measured blue shift, with respect to the GaP bulk absorption edge is 0.53 eV. As the cluster is smaller than the exciton radius, we can calculate the cluster size from this blue shift and obtain 20.2 {Angstrom}, consistent with the results from X-ray diffraction of 19.5 {Angstrom} for the same sample.

  13. Confined-but-Connected Quantum Solids via Controlled Ligand Displacement

    KAUST Repository

    Baumgardner, William J.

    2013-07-10

    Confined-but-connected quantum dot solids (QDS) combine the advantages of tunable, quantum-confined energy levels with efficient charge transport through enhanced electronic interdot coupling. We report the fabrication of QDS by treating self-assembled films of colloidal PbSe quantum dots with polar nonsolvents. Treatment with dimethylformamide balances the rates of self-assembly and ligand displacement to yield confined-but-connected QDS structures with cubic ordering and quasi-epitaxial interdot connections through facets of neighboring dots. The QDS structure was analyzed by a combination of transmission electron microscopy and wide-angle and small-angle X-ray scattering. Excitonic absorption signatures in optical spectroscopy confirm that quantum confinement is preserved. Transport measurements show significantly enhanced conductivity in treated films. © 2013 American Chemical Society.

  14. Effects of quantum confinement on excited state properties of SrTiO3 from ab initio many-body perturbation theory

    Science.gov (United States)

    Reyes-Lillo, Sebastian E.; Rangel, Tonatiuh; Bruneval, Fabien; Neaton, Jeffrey B.

    2016-07-01

    The Ruddlesden-Popper (RP) homologous series Srn +1TinO3 n +1 provides a useful template for the study and control of the effects of dimensionality and quantum confinement on the excited state properties of the complex oxide SrTiO3. We use ab initio many-body perturbation theory within the G W approximation and the Bethe-Salpeter equation approach to calculate quasiparticle energies and absorption spectra of Srn +1TinO3 n +1 for n =1 -5 and ∞ . Our computed direct and indirect optical gaps are in excellent agreement with spectroscopic measurements. The calculated optical spectra reproduce the main experimental features and reveal excitonic structure near the gap edge. We find that electron-hole interactions are important across the series, leading to significant exciton binding energies that increase for small n and reach a value of 330 meV for n =1 , a trend attributed to increased quantum confinement. We find that the lowest-energy singlet exciton of Sr2TiO4 (n =1 ) localizes in the two-dimensional plane defined by the TiO2 layer, and we explain the origin of its localization.

  15. Quantum Confinement in Hydrogen Bond of DNA and RNA

    CERN Document Server

    Santos, da Silva dos; Ricotta, Regina Maria

    2015-01-01

    The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

  16. Quantum Hall effect in a bulk antiferromagnet EuMnBi2 with magnetically confined two-dimensional Dirac fermions.

    Science.gov (United States)

    Masuda, Hidetoshi; Sakai, Hideaki; Tokunaga, Masashi; Yamasaki, Yuichi; Miyake, Atsushi; Shiogai, Junichi; Nakamura, Shintaro; Awaji, Satoshi; Tsukazaki, Atsushi; Nakao, Hironori; Murakami, Youichi; Arima, Taka-hisa; Tokura, Yoshinori; Ishiwata, Shintaro

    2016-01-01

    For the innovation of spintronic technologies, Dirac materials, in which low-energy excitation is described as relativistic Dirac fermions, are one of the most promising systems because of the fascinating magnetotransport associated with extremely high mobility. To incorporate Dirac fermions into spintronic applications, their quantum transport phenomena are desired to be manipulated to a large extent by magnetic order in a solid. We report a bulk half-integer quantum Hall effect in a layered antiferromagnet EuMnBi2, in which field-controllable Eu magnetic order significantly suppresses the interlayer coupling between the Bi layers with Dirac fermions. In addition to the high mobility of more than 10,000 cm(2)/V s, Landau level splittings presumably due to the lifting of spin and valley degeneracy are noticeable even in a bulk magnet. These results will pave a route to the engineering of magnetically functionalized Dirac materials.

  17. Optical phonons in nanostructured thin films composed by zincblende zinc selenide quantum dots in strong size-quantization regime: Competition between phonon confinement and strain-related effects

    Energy Technology Data Exchange (ETDEWEB)

    Pejova, Biljana, E-mail: biljana@pmf.ukim.mk

    2014-05-01

    Raman scattering in combination with optical spectroscopy and structural studies by X-ray diffraction was employed to investigate the phonon confinement and strain-induced effects in 3D assemblies of variable-size zincblende ZnSe quantum dots close packed in thin film form. Nanostructured thin films were synthesized by colloidal chemical approach, while tuning of the nanocrystal size was enabled by post-deposition thermal annealing treatment. In-depth insights into the factors governing the observed trends of the position and half-width of the 1LO band as a function of the average QD size were gained. The overall shifts in the position of 1LO band were found to result from an intricate compromise between the influence of phonon confinement and lattice strain-induced effects. Both contributions were quantitatively and exactly modeled. Accurate assignments of the bands due to surface optical (SO) modes as well as of the theoretically forbidden transverse optical (TO) modes were provided, on the basis of reliable physical models (such as the dielectric continuum model of Ruppin and Englman). The size-dependence of the ratio of intensities of the TO and LO modes was studied and discussed as well. Relaxation time characterizing the phonon decay processes in as-deposited samples was found to be approximately 0.38 ps, while upon post-deposition annealing already at 200 °C it increases to about 0.50 ps. Both of these values are, however, significantly smaller than those characteristic for a macrocrystalline ZnSe sample. - Graphical abstract: Optical phonons in nanostructured thin films composed by zincblende zinc selenide quantum dots in strong size-quantization regime: competition between phonon confinement and strain-related effects. - Highlights: • Phonon confinement vs. strain-induced effects in ZnSe 3D QD assemblies were studied. • Shifts of the 1LO band result from an intricate compromise between the two effects. • SO and theoretically forbidden TO modes were

  18. Electron-hole confinement symmetry in silicon quantum dots

    NARCIS (Netherlands)

    Müller, F.; Mueller, Filipp; Konstantaras, Georgios; Spruijtenburg, P.C.; van der Wiel, Wilfred Gerard; Zwanenburg, Floris Arnoud

    2015-01-01

    We report electrical transport measurements on a gate-defined ambipolar quantum dot in intrinsic silicon. The ambipolarity allows its operation as either an electron or a hole quantum dot of which we change the dot occupancy by 20 charge carriers in each regime. Electron−hole confinement symmetry is

  19. Si quantum dots in silicon nitride: Quantum confinement and defects

    Science.gov (United States)

    Goncharova, L. V.; Nguyen, P. H.; Karner, V. L.; D'Ortenzio, R.; Chaudhary, S.; Mokry, C. R.; Simpson, P. J.

    2015-12-01

    Luminescence of amorphous Si quantum dots (Si QDs) in a hydrogenated silicon nitride (SiNx:H) matrix was examined over a broad range of stoichiometries from Si3N2.08 to Si3N4.14, to optimize light emission. Plasma-enhanced chemical vapor deposition was used to deposit hydrogenated SiNx films with excess Si on Si (001) substrates, with stoichiometry controlled by variation of the gas flow rates of SiH4 and NH3 gases. The compositional and optical properties were analyzed by Rutherford backscattering spectroscopy, elastic recoil detection, spectroscopic ellipsometry, photoluminescence (PL), time-resolved PL, and energy-filtered transmission electron microscopy. Ultraviolet-laser-excited PL spectra show multiple emission bands from 400 nm (3.1 eV) to 850 nm (1.45 eV) for different Si3Nx compositions. There is a red-shift of the measured peaks from ˜2.3 eV to ˜1.45 eV as Si content increases, which provides evidence for quantum confinement. Higher N content samples show additional peaks in their PL spectra at higher energies, which we attribute to defects. We observed three different ranges of composition where Tauc band gaps, PL, and PL lifetimes change systematically. There is an interesting interplay of defect luminescence and, possibly, small Si QD luminescence observed in the intermediate range of compositions (˜Si3N3.15) in which the maximum of light emission is observed.

  20. Si quantum dots in silicon nitride: Quantum confinement and defects

    Energy Technology Data Exchange (ETDEWEB)

    Goncharova, L. V., E-mail: lgonchar@uwo.ca; Karner, V. L.; D' Ortenzio, R.; Chaudhary, S.; Mokry, C. R.; Simpson, P. J. [Department of Physics and Astronomy, The University of Western Ontario, London, Ontario N6A 3K7 (Canada); Nguyen, P. H. [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2E1 (Canada)

    2015-12-14

    Luminescence of amorphous Si quantum dots (Si QDs) in a hydrogenated silicon nitride (SiN{sub x}:H) matrix was examined over a broad range of stoichiometries from Si{sub 3}N{sub 2.08} to Si{sub 3}N{sub 4.14}, to optimize light emission. Plasma-enhanced chemical vapor deposition was used to deposit hydrogenated SiN{sub x} films with excess Si on Si (001) substrates, with stoichiometry controlled by variation of the gas flow rates of SiH{sub 4} and NH{sub 3} gases. The compositional and optical properties were analyzed by Rutherford backscattering spectroscopy, elastic recoil detection, spectroscopic ellipsometry, photoluminescence (PL), time-resolved PL, and energy-filtered transmission electron microscopy. Ultraviolet-laser-excited PL spectra show multiple emission bands from 400 nm (3.1 eV) to 850 nm (1.45 eV) for different Si{sub 3}N{sub x} compositions. There is a red-shift of the measured peaks from ∼2.3 eV to ∼1.45 eV as Si content increases, which provides evidence for quantum confinement. Higher N content samples show additional peaks in their PL spectra at higher energies, which we attribute to defects. We observed three different ranges of composition where Tauc band gaps, PL, and PL lifetimes change systematically. There is an interesting interplay of defect luminescence and, possibly, small Si QD luminescence observed in the intermediate range of compositions (∼Si{sub 3}N{sub 3.15}) in which the maximum of light emission is observed.

  1. Confined excitons in a semiconductor quantum dot in a magnetic field

    Science.gov (United States)

    Nomura, Shintaro; Segawa, Yusaburo; Kobayashi, Takayoshi

    1994-05-01

    Magnetic field effects in a semiconductor quantum dot (QD) are studied theoretically. Magneto-optical effects originating from electron-hole pairs in the lowest and the higher excited states are discussed. The theory is based on the effective-mass approximation with the following effects taken into account: the direct Coulomb interaction, the electron-hole exchange interaction, and the valence-band mixing effect. A calculation is performed with a numerical diagonalization method. The transition from the quantum confined Zeeman effect for a weak magnetic field to the quantum confined Paschen-Back effect for a strong magnetic field is discussed. Special attention is paid to a magnetic field dependence of the optical transition probabilities which is found to be a pronounced effect for a CdSe QD, where the confinement by a potential and a magnetic field have competing contributions.

  2. Imaging electrostatically confined Dirac fermions in graphene quantum dots

    Science.gov (United States)

    Lee, Juwon; Wong, Dillon; Velasco, Jairo, Jr.; Rodriguez-Nieva, Joaquin F.; Kahn, Salman; Tsai, Hsin-Zon; Taniguchi, Takashi; Watanabe, Kenji; Zettl, Alex; Wang, Feng; Levitov, Leonid S.; Crommie, Michael F.

    2016-11-01

    Electrostatic confinement of charge carriers in graphene is governed by Klein tunnelling, a relativistic quantum process in which particle-hole transmutation leads to unusual anisotropic transmission at p-n junction boundaries. Reflection and transmission at these boundaries affect the quantum interference of electronic waves, enabling the formation of novel quasi-bound states. Here we report the use of scanning tunnelling microscopy to map the electronic structure of Dirac fermions confined in quantum dots defined by circular graphene p-n junctions. The quantum dots were fabricated using a technique involving local manipulation of defect charge within the insulating substrate beneath a graphene monolayer. Inside such graphene quantum dots we observe resonances due to quasi-bound states and directly visualize the quantum interference patterns arising from these states. Outside the quantum dots Dirac fermions exhibit Friedel oscillation-like behaviour. Bolstered by a theoretical model describing relativistic particles in a harmonic oscillator potential, our findings yield insights into the spatial behaviour of electrostatically confined Dirac fermions.

  3. Confined optical-phonon-assisted cyclotron resonance in quantum wells via two-photon absorption process

    Science.gov (United States)

    Phuc, Huynh Vinh; Hien, Nguyen Dinh; Dinh, Le; Phong, Tran Cong

    2016-06-01

    The effect of confined phonons on the phonon-assisted cyclotron resonance (PACR) via both one and two photon absorption processes in a quantum well is theoretically studied. We consider cases when electrons are scattered by confined optical phonons described by the Fuchs-Kliewer slab, Ridley's guided, and Huang-Zhu models. The analytical expression of the magneto-optical absorption coefficient (MOAC) is obtained by relating it to the transition probability for the absorption of photons. It predicts resonant peaks caused by transitions between Landau levels and electric subband accompanied by confined phonons emission in the absorption spectrum. The MOAC and the full-width at half-maximum (FWHM) for the intra- and inter-subband transitions are given as functions of the magnetic field, temperature, and quantum well width. In narrow quantum wells, the phonon confinement becomes more important and should be taken into account in studying FWHM.

  4. Duality, Confinement and Supersymmetry in Restricted Quantum Chromodynamics (rcd)

    Science.gov (United States)

    Rana, J. M. S.

    Electromagnetic duality has been utilized to study the isocolor charge-dyon interactions in Restricted Quantum Chromodynamics (RCD),in terms of current-current correlation (in magnetic gauge)using dielectric and permeability parameters of the associated vacuum. In the state of dyonic superconductivity, it has been shown that the dual propagators behave as 1/k4 (for small k2), which in analogy with superconductivity (dual superconductivity) leads to the confinement of colored fluxes associated with dyonic quarks vide generalized Meissner effect. Based on semi-quantitative analysis of vortex solutions of RCD and by calculating the masses for the massive collective modes of the condensed vacuum, the expressions for the London penetration depth, coherence length and the associated flux energy functions for the type I and type II superconducting media have been obtained. It has further been demonstrated that in the type I medium, vortices tend to coalesce and hence are attractive, while the energy function supports repulsive forces between vortices in the type II superconducting medium. The RCD has been supersymmetrized in N=1 limit and the supersymmetric dyonic solutions have been obtained. In the dyonic background gauge one-loop quantum corrections to the dyonic mass have been calculated and it has been shown that the one-loop quantum corrections lead no change in classical mass of the dyon.

  5. Quantum distillation and confinement of vacancies in a doublon sea

    Science.gov (United States)

    Xia, Lin; Zundel, Laura A.; Carrasquilla, Juan; Reinhard, Aaron; Wilson, Joshua M.; Rigol, Marcos; Weiss, David S.

    2015-04-01

    Ultracold atomic gases have revolutionized the study of non-equilibrium dynamics in quantum many-body systems. Many counterintuitive non-equilibrium effects have been observed, such as suppressed thermalization in a one-dimensional (1D) gas, the formation of repulsive self-bound dimers, and identical behaviours for attractive and repulsive interactions. Here, we observe the expansion of a bundle of ultracold 1D Bose gases in a flat-bottomed optical lattice potential. By combining in situ measurements with photoassociation, we follow the spatial dynamics of singly, doubly and triply occupied lattice sites. The system sheds interaction energy by dissolving some doublons and triplons. Some singlons quantum distil out of the doublon centre, whereas others remain confined. Our Gutzwiller mean-field model captures these experimental features in a physically clear way. These experiments might be used to study thermalization in systems with particle losses, the evolution of quantum entanglement or, if applied to fermions, to prepare very low entropy states.

  6. Hydrogenic Donor in a Spherical Quantum Dot with Different Confinements

    Institute of Scientific and Technical Information of China (English)

    A. John Peter; K. Navaneethakrishnan

    2009-01-01

    Binding energies of a hydrogenic donor in a spherical GaAs quantum dot surrounded by Ga1-xAlxAs matrix are calculated. The results are presented for realistic barrier heights corresponding to different values of x (x < 0.4). The calculations are performed under two different conditions: (i) a spherical dot with square well confinement and (ii) a dot with parabolic potential well confinement. The results show that (i) the donor ionization energies are always higher under parabolic confinement as compared to a dot of the same radius under square well confinement and (ii) the oscillator strengths coupling ground state with excited states are two orders larger under parabolic confinement. Our results are in agreement with the results of other researchers.

  7. Statistical mechanics of confined quantum particles

    CERN Document Server

    Bannur, V M; Bannur, Vishnu M.

    2006-01-01

    We develop statistical mechanics and thermodynamics of Bose and Fermi systems in relativistic harmonic oscillator (RHO) confining potential, which may be applicable in quark gluon plasma (QGP), astrophysics, Bose-Einstein condensation (BEC), condensed matter physics etc. Detailed study of QGP system is carried out and compared with lattice results. Further, as an application, our equation of state (EoS) of QGP is used to study compact stars like quark star.

  8. Statistical Mechanics of Confined Quantum Particles

    Science.gov (United States)

    Bannur, Vishnu M.; Udayanandan, K. M.

    We develop statistical mechanics and thermodynamics of Bose and Fermi systems in relativistic harmonic oscillator (RHO) confining potential, which is applicable in quark gluon plasma (QGP), astrophysics, Bose-Einstein condensation (BEC) etc. Detailed study of QGP system is carried out and compared with lattice results. Furthermore, as an application, our equation of state (EoS) of QGP is used to study compact stars like quark star.

  9. Diamagnetic susceptibility of a confined donor in inhomogeneous quantum dots

    Science.gov (United States)

    Rahmani, K.; Zorkani, I.; Jorio, A.

    2011-03-01

    The binding energy and diamagnetic susceptibility χdia are estimated for a shallow donor confined to move in GaAs-GaAlAs inhomogeneous quantum dots. The calculation was performed within the effective mass approximation and using the variational method. The results show that the binding energy and the diamagnetic susceptibility χdia depend strongly on the core radius and the shell radius. We have demonstrated that there is a critical value of the ratio of the inner radius to the outer radius which may be important for nanofabrication techniques. The binding energy Eb shows a minimum for a critical value of this ratio depending on the value of the outer radius and shows a maximum when the donor is placed at the center of the spherical layer. The diamagnetic susceptibility is more sensitive to variations of the radius for a large spherical layer. The binding energy and diamagnetic susceptibility depend strongly on the donor position.

  10. Manipulating topological-insulator properties using quantum confinement

    Science.gov (United States)

    Kotulla, M.; Zülicke, U.

    2017-07-01

    Recent discoveries have spurred the theoretical prediction and experimental realization of novel materials that have topological properties arising from band inversion. Such topological insulators are insulating in the bulk but have conductive surface or edge states. Topological materials show various unusual physical properties and are surmised to enable the creation of exotic Majorana-fermion quasiparticles. How the signatures of topological behavior evolve when the system size is reduced is interesting from both a fundamental and an application-oriented point of view, as such understanding may form the basis for tailoring systems to be in specific topological phases. This work considers the specific case of quantum-well confinement defining two-dimensional layers. Based on the effective-Hamiltonian description of bulk topological insulators, and using a harmonic-oscillator potential as an example for a softer-than-hard-wall confinement, we have studied the interplay of band inversion and size quantization. Our model system provides a useful platform for systematic study of the transition between the normal and topological phases, including the development of band inversion and the formation of massless-Dirac-fermion surface states. The effects of bare size quantization, two-dimensional-subband mixing, and electron-hole asymmetry are disentangled and their respective physical consequences elucidated.

  11. Development of polaron-transformed explicitly correlated full configuration interaction method for investigation of quantum-confined Stark effect in GaAs quantum dots

    CERN Document Server

    Blanton, Christopher J; Chakraborty, Arindam

    2012-01-01

    The effect of external electric field on electron-hole correlation in GaAs quantum dots is investigated. The electron-hole Schrodinger equation in the presence of external electric field is solved using explicitly correlated full configuration interaction (XCFCI) method and accurate exciton binding energy and electron-hole recombination probability are obtained. The effect of the electric field was included in the 1-particle single component basis functions by performing variational polaron transformation. The quality of the wavefunction at small inter-particle distances was improved by using Gaussian-type geminal function that depended explicitly on the electron-hole separation distance. The parameters of the explicitly correlated function were determined variationally at each field strength. The scaling of total exciton energy, exciton binding energy, and electron-hole recombination probability with respect to the strength of the electric field was investigated. It was found that a 500 kV/cm change in elect...

  12. Optical phonons in nanostructured thin films composed by zincblende zinc selenide quantum dots in strong size-quantization regime: Competition between phonon confinement and strain-related effects

    Science.gov (United States)

    Pejova, Biljana

    2014-05-01

    Raman scattering in combination with optical spectroscopy and structural studies by X-ray diffraction was employed to investigate the phonon confinement and strain-induced effects in 3D assemblies of variable-size zincblende ZnSe quantum dots close packed in thin film form. Nanostructured thin films were synthesized by colloidal chemical approach, while tuning of the nanocrystal size was enabled by post-deposition thermal annealing treatment. In-depth insights into the factors governing the observed trends of the position and half-width of the 1LO band as a function of the average QD size were gained. The overall shifts in the position of 1LO band were found to result from an intricate compromise between the influence of phonon confinement and lattice strain-induced effects. Both contributions were quantitatively and exactly modeled. Accurate assignments of the bands due to surface optical (SO) modes as well as of the theoretically forbidden transverse optical (TO) modes were provided, on the basis of reliable physical models (such as the dielectric continuum model of Ruppin and Englman). The size-dependence of the ratio of intensities of the TO and LO modes was studied and discussed as well. Relaxation time characterizing the phonon decay processes in as-deposited samples was found to be approximately 0.38 ps, while upon post-deposition annealing already at 200 °C it increases to about 0.50 ps. Both of these values are, however, significantly smaller than those characteristic for a macrocrystalline ZnSe sample.

  13. Quark Confinement Physics from Quantum Chromodynamics

    CERN Document Server

    Suganuma, H; Tanaka, A; Ichie, H

    2016-01-01

    We show the construction of the dual superconducting theory for the confinement mechanism from QCD in the maximally abelian (MA) gauge using the lattice QCD Monte Carlo simulation. We find that essence of infrared abelian dominance is naturally understood with the off-diagonal gluon mass $m_{\\rm off} \\simeq 1.2 {\\rm GeV}$ induced by the MA gauge fixing. In the MA gauge, the off-diagonal gluon amplitude is forced to be small, and the off-diagonal gluon phase tends to be random. As the mathematical origin of abelian dominance for confinement, we demonstrate that the strong randomness of the off-diagonal gluon phase leads to abelian dominance for the string tension. In the MA gauge, there appears the macroscopic network of the monopole world-line covering the whole system. We investigate the monopole-current system in the MA gauge by analyzing the dual gluon field $B_\\mu$. We evaluate the dual gluon mass as $m_B = 0.4 \\sim$ 0.5GeV in the infrared region, which is the lattice-QCD evidence of the dual Higgs mechan...

  14. Effective viscosity of confined hydrocarbons

    DEFF Research Database (Denmark)

    Sivebæk, Ion Marius; Samoilov, V.N.; Persson, B.N.J.

    2012-01-01

    We present molecular dynamics friction calculations for confined hydrocarbon films with molecular lengths from 20 to 1400 carbon atoms. We find that the logarithm of the effective viscosity ηeff for nanometer-thin films depends linearly on the logarithm of the shear rate: log ηeff=C-nlog γ̇, where...

  15. The nonlinear optical rectification of a confined exciton in a quantum dot

    Energy Technology Data Exchange (ETDEWEB)

    Xie Wenfang, E-mail: xiewf@gzhu.edu.c [School of Physics and Electronic Engineering, Guangzhou University, Guangzhou 510006 (China)

    2011-05-15

    An exciton in a disc-like quantum dot (QD) with the parabolic confinement, under applied electric field, is studied within the framework of the effective-mass approximation. The nonlinear optical rectification between the ground and the first-excited states has been examined through the computed energies and wave functions in details for the excitons. The results show that the optical rectification susceptibility obtained in a disc-like QD reach the magnitude of 10{sup -2} m/V, which is 3-4 orders of magnitude higher than in one-dimensional QDs. It is found that the second-order nonlinear optical properties of exciton states in a QD are strongly affected by the confinement strength and the electric field. - Research highlights: {yields} The magnitude of the nonlinear optical rectification of the excitons confined in a disc-like quantum dot may reach 10{sup -2} m/V. It is much higher than that of the other low-dimensional semiconductors, e.g., quantum wells, and one-dimensional semiparabolic quantum dots. {yields} The nonlinear optical rectification of the excitons confined in a disc-like quantum dot is strongly dependent on the confinement frequency. In order to obtain the larger optical rectification coefficients in quantum dots, we can change the confinement frequency. {yields} The calculated results also reveal that an applied electric field has a great influence on the nonlinear optical rectification susceptibility. In order to obtain the larger optical rectification coefficients in quantum dots we can induce the electric field.

  16. Nanocrystalline-Si-dot multi-layers fabrication by chemical vapor deposition with H-plasma surface treatment and evaluation of structure and quantum confinement effects

    Directory of Open Access Journals (Sweden)

    Daisuke Kosemura

    2014-01-01

    Full Text Available 100-nm-thick nanocrystalline silicon (nano-Si-dot multi-layers on a Si substrate were fabricated by the sequential repetition of H-plasma surface treatment, chemical vapor deposition, and surface oxidation, for over 120 times. The diameter of the nano-Si dots was 5–6 nm, as confirmed by both the transmission electron microscopy and X-ray diffraction analysis. The annealing process was important to improve the crystallinity of the nano-Si dot. We investigated quantum confinement effects by Raman spectroscopy and photoluminescence (PL measurements. Based on the experimental results, we simulated the Raman spectrum using a phenomenological model. Consequently, the strain induced in the nano-Si dots was estimated by comparing the experimental and simulated results. Taking the estimated strain value into consideration, the band gap modulation was measured, and the diameter of the nano-Si dots was calculated to be 5.6 nm by using PL. The relaxation of the q ∼ 0 selection rule model for the nano-Si dots is believed to be important to explain both the phenomena of peak broadening on the low-wavenumber side observed in Raman spectra and the blue shift observed in PL measurements.

  17. Proving Nontrivial Topology of Pure Bismuth by Quantum Confinement

    Science.gov (United States)

    Ito, S.; Feng, B.; Arita, M.; Takayama, A.; Liu, R.-Y.; Someya, T.; Chen, W.-C.; Iimori, T.; Namatame, H.; Taniguchi, M.; Cheng, C.-M.; Tang, S.-J.; Komori, F.; Kobayashi, K.; Chiang, T.-C.; Matsuda, I.

    2016-12-01

    The topology of pure Bi is controversial because of its very small (˜10 meV ) band gap. Here we perform high-resolution angle-resolved photoelectron spectroscopy measurements systematically on 14-202 bilayer Bi films. Using high-quality films, we succeed in observing quantized bulk bands with energy separations down to ˜10 meV . Detailed analyses on the phase shift of the confined wave functions precisely determine the surface and bulk electronic structures, which unambiguously show nontrivial topology. The present results not only prove the fundamental property of Bi but also introduce a capability of the quantum-confinement approach.

  18. Proving Nontrivial Topology of Pure Bismuth by Quantum Confinement.

    Science.gov (United States)

    Ito, S; Feng, B; Arita, M; Takayama, A; Liu, R-Y; Someya, T; Chen, W-C; Iimori, T; Namatame, H; Taniguchi, M; Cheng, C-M; Tang, S-J; Komori, F; Kobayashi, K; Chiang, T-C; Matsuda, I

    2016-12-02

    The topology of pure Bi is controversial because of its very small (∼10  meV) band gap. Here we perform high-resolution angle-resolved photoelectron spectroscopy measurements systematically on 14-202 bilayer Bi films. Using high-quality films, we succeed in observing quantized bulk bands with energy separations down to ∼10  meV. Detailed analyses on the phase shift of the confined wave functions precisely determine the surface and bulk electronic structures, which unambiguously show nontrivial topology. The present results not only prove the fundamental property of Bi but also introduce a capability of the quantum-confinement approach.

  19. Role of confinements on the melting of Wigner molecules in quantum dots

    Science.gov (United States)

    Bhattacharya, Dyuti; Filinov, Alexei V.; Ghosal, Amit; Bonitz, Michael

    2016-03-01

    We explore the stability of a Wigner molecule (WM) formed in confinements with different geometries emulating the role of disorder and analyze the melting (or crossover) of such a system. Building on a recent calculation [D. Bhattacharya, A. Ghosal, Eur. Phys. J. B 86, 499 (2013)] that discussed the effects of irregularities on the thermal crossover in classical systems, we expand our studies in the untested territory by including both the effects of quantum fluctuations and of disorder. Our results, using classical and quantum (path integral) Monte Carlo techniques, unfold complementary mechanisms that drive the quantum and thermal crossovers in a WM and show that the symmetry of the confinement plays no significant role in determining the quantum crossover scale n X . This is because the zero-point motion screens the boundary effects within short distances. The phase diagram as a function of thermal and quantum fluctuations determined from independent criteria is unique, and shows "melting" from the WM to both the classical and quantum "liquids". An intriguing signature of weakening liquidity with increasing temperature, T, is found in the extreme quantum regime. The crossover is associated with production of defects. However, these defects appear to play distinct roles in driving the quantum and thermal "melting". Our analyses carry serious implications for a variety of experiments on many-particle systems - semiconductor heterostructure quantum dots, trapped ions, nanoclusters, colloids and complex plasma.

  20. Confined Quantum Time of Arrival for Vanishing Potential

    OpenAIRE

    2005-01-01

    We give full account of our recent report in [E.A. Galapon, R. Caballar, R. Bahague {\\it Phys. Rev. Let.} {\\bf 93} 180406 (2004)] where it is shown that formulating the free quantum time of arrival problem in a segment of the real line suggests rephrasing the quantum time of arrival problem to finding a complete set of states that evolve to unitarily arrive at a given point at a definite time. For a spatially confined particle, here it is shown explicitly that the problem admits a solution in...

  1. Controlling Carrier Dynamics using Quantum-Confined Semiconductor Nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Beard, Matthew C.; Klimov, Victor I.

    2016-06-01

    The articles included in this special issue of Chemical Physics explore the use of quantum-confined semiconductor nanocrystals to control the flow of energy and/or charge. Colloidal quantum-confined semiconductor nanostructures are an emerging class of functional materials being developed for novel opto-electronic applications. In the last few years numerous examples in the literature have emerged where novel nanostructures have been tailored such as to achieve a specific function thus moving the field from the stage of discovery of novel behaviors to that of control of nanostructure properties. In addition to the internal structure of the NCs their assemblies can be tailored to achieve emergent properties and add additional control parameters that determine the final opto-electronic properties. These principles are explored via variations in shape, size, surface ligands, heterostructuring, morphology, composition, and assemblies and are demonstrated through measurements of excited state processes, such as Auger recombination; photoluminescence; charge separation and charge transport.

  2. Diamagnetic susceptibility of a confined donor in inhomogeneous quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Rahmani, K; Zorkani, I; Jorio, A, E-mail: izorkani@hotmail.com [LPS, Faculte des sciences, Dhar Mehraz Fes, Fes, BP 1796 (Morocco)

    2011-03-15

    The binding energy and diamagnetic susceptibility {chi}{sub dia} are estimated for a shallow donor confined to move in GaAs-GaAlAs inhomogeneous quantum dots. The calculation was performed within the effective mass approximation and using the variational method. The results show that the binding energy and the diamagnetic susceptibility {chi}{sub dia} depend strongly on the core radius and the shell radius. We have demonstrated that there is a critical value of the ratio of the inner radius to the outer radius which may be important for nanofabrication techniques. The binding energy E{sub b} shows a minimum for a critical value of this ratio depending on the value of the outer radius and shows a maximum when the donor is placed at the center of the spherical layer. The diamagnetic susceptibility is more sensitive to variations of the radius for a large spherical layer. The binding energy and diamagnetic susceptibility depend strongly on the donor position.

  3. Effect of carrier confinement on effective mass of excitons and estimation of ultralow disorder in Al x Ga1-x As/GaAs quantum wells by magneto-photoluminescence.

    Science.gov (United States)

    Haldar, S; Dixit, V K; Vashisht, Geetanjali; Khamari, Shailesh Kumar; Porwal, S; Sharma, T K; Oak, S M

    2017-07-07

    Effect of charge carrier confinement and ultra-low disorder acquainted in AlGaAs/GaAs multi-quantum well system is investigated via Magneto-photoluminescence spectroscopy. Significant increase of effective mass is observed for the confined exciton in narrow QWs. The foremost reason behind such an observation is due to the induced non-parabolicity in bands. Moreover, as the thickness of the QW are reduced, confined excitons in QW experience atomic irregularities at the hetero-junctions and their effects are prominent in the photoluminescence linewidth. Amount of photoluminescence line-broadening caused by the atomic irregularities at the hetero-junctions is correlated with average fluctuation (δ 1) in QW thickness. The estimated δ 1 for Al0.3Ga0.7As/GaAs QWs are found to be ±(0.14 - 1.6)× 'one monolayer thickness of GaAs layer'. Further, the strong perturbations due to magnetic field in a system helps in realizing optical properties of exciton in QWs, where magnetic field is used as a probe to detect ultralow defects in the QW. Additionally, the influence of magnetic field on the free and bound exciton luminescence is explained by a simple model. The proposed approach for measuring the interface and volume defects in an ultra-low disordered system by Magneto-PL spectroscopy technique will be highly beneficial in high mobility devices for advanced applications.

  4. Vortex anomaly in low-dimensional fermionic condensates: Quantum confinement breaks chirality

    Science.gov (United States)

    Chen, Yajiang; Shanenko, A. A.; Peeters, F. M.

    2014-02-01

    Chiral fermions are responsible for low-temperature properties of vortices in fermionic condensates, both superconducting (charged) and superfluid (neutral). One of the most striking consequences of this fact is that the core of a single-quantum vortex collapses at low temperatures, T →0 (i.e., the Kramer-Pesch effect for superconductors), due to the presence of chiral quasiparticles in the vortex-core region. We show that the situation changes drastically for fermionic condensates confined in quasi-one-dimensional and quasi-two-dimensional geometries. Here quantum confinement breaks the chirality of in-core fermions. As a result, instead of the ultimate shrinking, the core of a single-quantum vortex extends at low temperatures, and the condensate profile surprisingly mimics the multiquantum vortex behavior. Our findings are relevant for nanoscale superconductors, such as recent metallic nanoislands on silicon, and also for ultracold superfluid Fermi gases in cigar-shaped and pancake-shaped atomic traps.

  5. PARISI-SOURLAS CONFINEMENT MECHANISM OF QUANTUM CHROMODYNAMICS

    Institute of Scientific and Technical Information of China (English)

    KOU SU-PENG

    2001-01-01

    Using Parisi and Sourlas dimensional reduction, four-dimensional quantum chromodynamics is reduced to a twodimensional principal chiral model by suitable superspace embedding. The frame Ta cannot be regarded as a fixed one and the frame connection field wμ (x) becomes a dynamical gauge field in two dimensions, giving rise to a confining potential. As a result of the original SU(3) Yang-Mills field obtains another SU(3) local symmetry and turns into SU(3)× SU(3) local symmetry-one group element as exp(iδφaTa) with fixed frame Ta, the other gauging the frame Ta.

  6. Confined Quantum Time of Arrival for Vanishing Potential

    CERN Document Server

    Galapon, E A; Caballar, R F; Bahague, Ricardo; Caballar, Roland F.; Galapon, Eric A.

    2005-01-01

    We give full account of our recent report in [E.A. Galapon, R. Caballar, R. Bahague {\\it Phys. Rev. Let.} {\\bf 93} 180406 (2004)] where it is shown that formulating the free quantum time of arrival problem in a segment of the real line suggests rephrasing the quantum time of arrival problem to finding a complete set of states that evolve to unitarily arrive at a given point at a definite time. For a spatially confined particle, here it is shown explicitly that the problem admits a solution in the form of an eigenvalue problem of a class of compact and self-adjoint time of arrival operators derived by a quantization of the classical time of arrival. The eigenfunctions of these operators are numerically demonstrated to unitarilly arrive at the origin at their respective eigenvalues.

  7. Absence of quantum confinement effects in the photoluminescence of Si{sub 3}N{sub 4}–embedded Si nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Hiller, D., E-mail: daniel.hiller@imtek.uni-freiburg.de; Zelenina, A.; Gutsch, S.; Zacharias, M. [Faculty of Engineering, IMTEK, Albert-Ludwigs-University Freiburg, Georges-Köhler-Allee 103, 79110 Freiburg (Germany); Dyakov, S. A. [Department of Electronic and Electrical Engineering, Trinity College Dublin, Dublin 2 (Ireland); Optics and Photonics, School of Information and Communication Technology, Royal Institute of Technology (KTH), Electrum 229, Kista SE-16440 (Sweden); López-Conesa, L.; López-Vidrier, J.; Peiró, F.; Garrido, B. [MIND-IN2UB, Departament d' Electrònica, Universitat de Barcelona, C. Martí i Franquès, 1, 08028 Barcelona (Spain); Estradé, S. [MIND-IN2UB, Departament d' Electrònica, Universitat de Barcelona, C. Martí i Franquès, 1, 08028 Barcelona (Spain); CCiT, Scientific and Technical Centers, Universitat de Barcelona, C/Lluís Solé i Sabaris 1, 08028 Barcelona (Spain); Valenta, J.; Kořínek, M.; Trojánek, F.; Malý, P. [Faculty of Mathematics and Physics, Department of Chemical Physics and Optics, Charles University in Prague, Ke Karlovu 3, CZ-12116 Prague 2 (Czech Republic); Schnabel, M.; Weiss, C.; Janz, S. [Fraunhofer-Institut für Solare Energiesysteme ISE, Heidenhofstr. 2, 79110 Freiburg (Germany)

    2014-05-28

    Superlattices of Si-rich silicon nitride and Si{sub 3}N{sub 4} are prepared by plasma-enhanced chemical vapor deposition and, subsequently, annealed at 1150 °C to form size-controlled Si nanocrystals (Si NCs) embedded in amorphous Si{sub 3}N{sub 4}. Despite well defined structural properties, photoluminescence spectroscopy (PL) reveals inconsistencies with the typically applied model of quantum confined excitons in nitride-embedded Si NCs. Time-resolved PL measurements demonstrate 10{sup 5} times faster time-constants than typical for the indirect band structure of Si NCs. Furthermore, a pure Si{sub 3}N{sub 4} reference sample exhibits a similar PL peak as the Si NC samples. The origin of this luminescence is discussed in detail on the basis of radiative defects and Si{sub 3}N{sub 4} band tail states in combination with optical absorption measurements. The apparent absence of PL from the Si NCs is explained conclusively using electron spin resonance data from the Si/Si{sub 3}N{sub 4} interface defect literature. In addition, the role of Si{sub 3}N{sub 4} valence band tail states as potential hole traps is discussed. Most strikingly, the PL peak blueshift with decreasing NC size, which is often observed in literature and typically attributed to quantum confinement (QC), is identified as optical artifact by transfer matrix method simulations of the PL spectra. Finally, criteria for a critical examination of a potential QC-related origin of the PL from Si{sub 3}N{sub 4}-embedded Si NCs are suggested.

  8. Quantum-Confined and Enhanced Optical Absorption of Colloidal PbS Quantum Dots at Wavelengths with Expected Bulk Behavior.

    Science.gov (United States)

    Debellis, Doriana; Gigli, Giuseppe; Ten Brinck, Stephanie; Infante, Ivan; Giansante, Carlo

    2017-02-08

    Nowadays it is well-accepted to attribute bulk-like optical absorption properties to colloidal PbS quantum dots (QDs) at wavelengths above 400 nm. This assumption permits to describe PbS QD light absorption by using bulk optical constants and to determine QD concentration in colloidal solutions from simple spectrophotometric measurements. Here we demonstrate that PbS QDs experience the quantum confinement regime across the entire near UV-vis-NIR spectral range, therefore also between 350 and 400 nm already proposed to be sufficiently far above the band gap to suppress quantum confinement. This effect is particularly relevant for small PbS QDs (with diameter of ≤4 nm) leading to absorption coefficients that largely differ from bulk values (up to ∼40% less). As a result of the broadband quantum confinement and of the high surface-to-volume ratio peculiar of nanocrystals, suitable surface chemical modification of PbS QDs is exploited to achieve a marked, size-dependent enhancement of the absorption coefficients compared to bulk values (up to ∼250%). We provide empirical relations to determine the absorption coefficients at 400 nm of as-synthesized and ligand-exchanged PbS QDs, accounting for the broadband quantum confinement and suggesting a heuristic approach to qualitatively predict the ligand effects on the optical absorption properties of PbS QDs. Our findings go beyond formalisms derived from Maxwell Garnett effective medium theory to describe QD optical properties and permit to spectrophotometrically calculate the concentration of PbS QD solutions avoiding underestimation due to deviations from the bulk. In perspective, we envisage the use of extended π-conjugated ligands bearing electronically active substituents to enhance light-harvesting in QD solids and suggest the inadequacy of the representation of ligands at the QD surface as mere electric dipoles.

  9. Quantum statistics of ideal gases in confined space

    OpenAIRE

    Dai, Wu-Sheng; Xie, Mi

    2002-01-01

    In this paper, the effects of boundary and connectivity on ideal gases in two-dimensional confined space and three-dimensional tubes are discussed in detail based on the analytical result. The implication of such effects on the mesoscopic system is also revealed.

  10. Two- versus three-dimensional quantum confinement in indium phosphide wires and dots.

    Science.gov (United States)

    Yu, Heng; Li, Jingbo; Loomis, Richard A; Wang, Lin-Wang; Buhro, William E

    2003-08-01

    The size dependence of the bandgap is the most identifiable aspect of quantum confinement in semiconductors; the bandgap increases as the nanostructure size decreases. The bandgaps in one-dimensional (1D)-confined wells, 2D-confined wires, and 3D-confined dots should evolve differently with size as a result of the differing dimensionality of confinement. However, no systematic experimental comparisons of analogous 1D, 2D or 3D confinement systems have been made. Here we report growth of indium phosphide (InP) quantum wires having diameters in the strong-confinement regime, and a comparison of their bandgaps with those previously reported for InP quantum dots. We provide theoretical evidence to establish that the quantum confinement observed in the InP wires is weakened to the expected extent, relative to that in InP dots, by the loss of one confinement dimension. Quantum wires sometimes behave as strings of quantum dots, and we propose an analysis to generally distinguish quantum-wire from quantum-dot behaviour.

  11. Generalized Bogoliubov Transformation for Confined Fields Applications in Casimir Effect

    CERN Document Server

    Silva, J C; Neto, A M; Santana, A E

    2002-01-01

    The Bogoliubov transformation in thermofield dynamics, an operator formalism for the finite-temperature quantum-field theory, is generalized to describe a field in arbitrary confined regions of space and time. Starting with the scalar field, the approach is extended to the electromagnetic field and the energy-momentum tensor is written via the Bogoliubov transformation. In this context, the Casimir effect is calculated for zero and non-zero temperature, and therefore it can be considered as a vacuum condensation effect of the electromagnetic field. This aspect opens an interesting perspective for using this procedure as an effective scheme for calculations in the studies of confined fields, including the interacting fields.

  12. Computer simulation of liquid-vapor coexistence of confined quantum fluids.

    Science.gov (United States)

    Trejos, Víctor M; Gil-Villegas, Alejandro; Martinez, Alejandro

    2013-11-14

    The liquid-vapor coexistence (LV) of bulk and confined quantum fluids has been studied by Monte Carlo computer simulation for particles interacting via a semiclassical effective pair potential Veff(r) = VLJ + VQ, where VLJ is the Lennard-Jones 12-6 potential (LJ) and VQ is the first-order Wigner-Kirkwood (WK-1) quantum potential, that depends on β = 1∕kT and de Boer's quantumness parameter Λ=h/σ√mε, where k and h are the Boltzmann's and Planck's constants, respectively, m is the particle's mass, T is the temperature of the system, and σ and ε are the LJ potential parameters. The non-conformal properties of the system of particles interacting via the effective pair potential Veff(r) are due to Λ, since the LV phase diagram is modified by varying Λ. We found that the WK-1 system gives an accurate description of the LV coexistence for bulk phases of several quantum fluids, obtained by the Gibbs Ensemble Monte Carlo method (GEMC). Confinement effects were introduced using the Canonical Ensemble (NVT) to simulate quantum fluids contained within parallel hard walls separated by a distance Lp, within the range 2σ ≤ Lp ≤ 6σ. The critical temperature of the system is reduced by decreasing Lp and increasing Λ, and the liquid-vapor transition is not longer observed for Lp∕σ < 2, in contrast to what has been observed for the classical system.

  13. Ground State of a Two-Electron Quantum Dot with a Gaussian Confining Potential

    Institute of Scientific and Technical Information of China (English)

    XIE Wen-Fang

    2006-01-01

    We investigate the ground-state properties of a two-dimensional two-electron quantum dot with a Gaussian confining potential under the influence of perpendicular homogeneous magnetic field. Calculations are carried out by using the method of numerical diagonalization of Hamiltonian matrix within the effective-mass approximation. A ground-state behaviour (singlet→triplet state transitions) as a function of the strength of a magnetic field has been found. It is found that the dot radius R of the Gaussian potential is important for the ground-state transition and the feature of ground-state for the Gaussian potential quantum dot (QD), and the parabolic potential QDs are similar when R is larger. The larger the quantum dot radius, the smaller the magnetic field for the singlet-triplet transition of the ground-state of two interacting electrons in the Gaussian quantum dot.

  14. Quantum and classical confinement of resonant states in a trilayer graphene Fabry-Pérot interferometer.

    Science.gov (United States)

    Campos, L C; Young, A F; Surakitbovorn, K; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P

    2012-01-01

    The advent of few-layer graphene has given rise to a new family of two-dimensional systems with emergent electronic properties governed by relativistic quantum mechanics. The multiple carbon sublattices endow the electronic wavefunctions with pseudospin, a lattice analogue of the relativistic electron spin, whereas the multilayer structure leads to electric-field-effect tunable electronic bands. Here we use these properties to realize giant conductance oscillations in ballistic trilayer graphene Fabry-Pérot interferometers, which result from phase coherent transport through resonant bound states beneath an electrostatic barrier. We confine these states by selectively decoupling them from the leads, resulting in transport via non-resonant states and suppression of the giant oscillations. The confinement is achieved both classically, by manipulating quasiparticle momenta with a magnetic field, and quantum mechanically, by locally varying the pseudospin character of the carrier wavefunctions. Our results illustrate the unique potential of trilayer graphene as a versatile platform for electron optics and pseudospintronics.

  15. Energies and densities of electrons confined in elliptical and ellipsoidal quantum dots

    Science.gov (United States)

    Halder, Avik; Kresin, Vitaly V.

    2016-10-01

    We consider a droplet of electrons confined within an external harmonic potential well of elliptical or ellipsoidal shape, a geometry commonly encountered in work with semiconductor quantum dots and other nanoscale or mesoscale structures. For droplet sizes exceeding the effective Bohr radius, the dominant contribution to average system parameters in the Thomas-Fermi approximation comes from the potential energy terms, which allows us to derive expressions describing the electron droplet’s shape and dimensions, its density, total and capacitive energy, and chemical potential. The analytical results are in very good agreement with experimental data and numerical calculations, and make it possible to follow the dependence of the properties of the system on its parameters (the total number of electrons, the axial ratios and curvatures of the confinement potential, and the dielectric constant of the material). An interesting feature is that the eccentricity of the electron droplet is not the same as that of its confining potential well.

  16. A hybrid classical-quantum approach for ultra-scaled confined nanostructures : modeling and simulation*

    Directory of Open Access Journals (Sweden)

    Pietra Paola

    2012-04-01

    Full Text Available We propose a hybrid classical-quantum model to study the motion of electrons in ultra-scaled confined nanostructures. The transport of charged particles, considered as one dimensional, is described by a quantum effective mass model in the active zone coupled directly to a drift-diffusion problem in the rest of the device. We explain how this hybrid model takes into account the peculiarities due to the strong confinement and we present numerical simulations for a simplified carbon nanotube. Nous proposons un modèle hybride classique-quantique pour décrire le mouvement des électrons dans des nanostructures très fortement confinées. Le transport des particules, consideré unidimensionel, est décrit par un modèle quantique avec masse effective dans la zone active couplé à un problème de dérive-diffusion dans le reste du domaine. Nous expliquons comment ce modèle hybride prend en compte les spécificités de ce très fort confinement et nous présentons des résultats numériques pour un nanotube de carbone simplifié.

  17. Confinement-Driven Phase Separation of Quantum Liquid Mixtures

    Science.gov (United States)

    Prisk, T. R.; Pantalei, C.; Kaiser, H.; Sokol, P. E.

    2012-08-01

    We report small-angle neutron scattering studies of liquid helium mixtures confined in Mobil Crystalline Material-41 (MCM-41), a porous silica glass with narrow cylindrical nanopores (d=3.4nm). MCM-41 is an ideal model adsorbent for fundamental studies of gas sorption in porous media because its monodisperse pores are arranged in a 2D triangular lattice. The small-angle scattering consists of a series of diffraction peaks whose intensities are determined by how the imbibed liquid fills the pores. Pure He4 adsorbed in the pores show classic, layer-by-layer film growth as a function of pore filling, leaving the long range symmetry of the system intact. In contrast, the adsorption of He3-He4 mixtures produces a structure incommensurate with the pore lattice. Neither capillary condensation nor preferential adsorption of one helium isotope to the pore walls can provide the symmetry-breaking mechanism. The scattering is consistent with the formation of randomly distributed liquid-liquid microdomains ˜2.3nm in size, providing evidence that confinement in a nanometer scale capillary can drive local phase separation in quantum liquid mixtures.

  18. Stochastic quantum confinement in nanocrystalline silicon layers: The role of quantum dots, quantum wires and localized states

    Energy Technology Data Exchange (ETDEWEB)

    Ramírez-Porras, A., E-mail: aramirez@fisica.ucr.ac.cr [Centro de Investigación en Ciencia e Ingeniería de Materiales (CICIMA), Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica); Escuela de Física, Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica); García, O. [Escuela de Física, Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica); Escuela de Química, Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica); Vargas, C. [Escuela de Física, Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica); Corrales, A. [Escuela de Física, Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica); Escuela de Química, Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica); Solís, J.D. [Escuela de Física, Universidad de Costa Rica, San Pedro de Montes de Oca 11501 (Costa Rica)

    2015-08-30

    Highlights: • PL spectra of porous silicon samples have been studied using a stochastic model. • This model can deconvolute PL spectra into three components. • Quantum dots, quantum wires and localized states have been identified. • Nanostructure diameters are in the range from 2.2 nm to 4.0 nm. • Contributions from quantum wires are small compared to the others. - Abstract: Nanocrystallites of Silicon have been produced by electrochemical etching of crystal wafers. The obtained samples show photoluminescence in the red band of the visible spectrum when illuminated by ultraviolet light. The photoluminescence spectra can be deconvolved into three components according to a stochastic quantum confinement model: one band coming from Nanocrystalline dots, or quantum dots, one from Nanocrystalline wires, or quantum wires, and one from the presence of localized surface states related to silicon oxide. The results fit well within other published models.

  19. Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method

    Directory of Open Access Journals (Sweden)

    M. Melvin David Kumar

    2012-06-01

    Full Text Available Nanocrystals of CdSe have been produced in SiOx matrix layer and in ZnSe heterostructure layer by thermal evaporation method. Structural studies were done by X-ray diffractometer. Quantum confinement effect of CdSe nanocrystals was analyzed from optical studies. Bulk CdSe has band-gap energy of 1.756 eV that can be shifted to larger values by reducing the crystal size to dimensions smaller than the Bohr radius of the exciton. Experimentally measured band-gap shifts with respect to the bulk value for quantum dot thin films are compared with the predictions of the effective mass approximation model (i.e., Brus model and Quantum mechanical model. Sizes of the crystallites calculated from both models were coincident with each other.

  20. Third generation photovoltaics based on multiple exciton generation in quantum confined semiconductors.

    Science.gov (United States)

    Beard, Matthew C; Luther, Joseph M; Semonin, Octavi E; Nozik, Arthur J

    2013-06-18

    Improving the primary photoconversion process in a photovoltaiccell by utilizing the excess energy that is otherwise lost as heat can lead to an increase in the overall power conversion efficiency (PCE). Semiconductor nanocrystals (NCs) with at least one dimension small enough to produce quantum confinement effects provide new ways of controlling energy flow not achievable in thin film or bulk semiconductors. Researchers have developed various strategies to incorporate these novel structures into suitable solar conversion systems. Some of these methods could increase the PCE past the Shockley-Queisser (SQ) limit of ∼33%, making them viable "third generation photovoltaic" (TGPV) cell architectures. Surpassing the SQ limit for single junction solar cells presents both a scientific and a technological challenge, and the use of semiconductor NCs to enhance the primary photoconversion process offers a promising potential solution. The NCs are synthesized via solution phase chemical reactions producing stable colloidal solutions, where the reaction conditions can be modified to produce a variety of shapes, compositions, and structures. The confinement of the semiconductor NC in one dimension produces quantum films, wells, or discs. Two-dimensional confinement leads to quantum wires or rods (QRs), and quantum dots (QDs) are three-dimensionally confined NCs. The process of multiple exciton generation (MEG) converts a high-energy photon into multiple electron-hole pairs. Although many studies have demonstrated that MEG is enhanced in QDs compared with bulk semiconductors, these studies have either used ultrafast spectroscopy to measure the photon-to-exciton quantum yields (QYs) or theoretical calculations. Implementing MEG in a working solar cell has been an ongoing challenge. In this Account, we discuss the status of MEG research and strategies towards implementing MEG in working solar cells. Recently we showed an external quantum efficiency for photocurrent of greater

  1. Raman scattering from confined phonons in GaAs/AlGaAs quantum wires

    Science.gov (United States)

    Bairamov, B. H.; Aydinli, A.; Tanatar, B.; Güven, K.; Gurevich, S.; Mel'tser, B. Ya.; Ivanov, S. V.; Kop'ev, P. S.; Smirnitskii, V. B.; Timofeev, F. N.

    1998-10-01

    We report on photoluminescence and Raman scattering performed at low temperature (T = 10 K) on GaAs/Al0.3Ga0.7As quantum-well wires with effective wire widths ofL = 100.0 and 10.9 nm prepared by molecular beam epitaxial growth followed by holographic patterning, reactive ion etching, and anodic thinning. We find evidence for the existence of longitudinal optical phonon modes confined to the GaAs quantum wire. The observed frequency at οL10 = 285.6 cm-1forL = 11.0 nm is in good agreement with that calculated on the basis of the dispersive dielectric continuum theory of Enderleinas applied to the GaAs/Al0.3Ga0.7As system. Our results indicate the high crystalline quality of the quantum-well wires fabricated using these techniques.

  2. Effects of free electrons and quantum confinement in ultrathin ZnO films: a comparison between undoped and Al-doped ZnO.

    Science.gov (United States)

    Li, X D; Chen, T P; Liu, P; Liu, Y; Leong, K C

    2013-06-17

    Band gaps and exciton binding energies of undoped and Al-doped ZnO thin films were determined from optical absorption measurement based on the Elliott's exciton absorption theory. As compared to the undoped films, the doped films exhibit a band gap expansion and a reduction in the exciton binding energies due to the free electron screening effect, which suppresses the excitonic absorption and results in a blue shift of the absorption edge. The undoped and doped films show the same quantum size dependence, i.e. both the exciton binding energies and band gap energies increase with decreasing grain size of the oxides.

  3. The confined hydrogenoid ion in non-relativistic quantum electrodynamics

    CERN Document Server

    Amour, L

    2006-01-01

    We consider a system of a nucleus with an electron together with the quantized electromagnetic field. Instead of fixing the nucleus, the system is confined by its center of mass. This model is used in theoretical physics to explain the Lamb-Dicke and the M\\"ossbauer effects (see [CTDRG]). When an ultraviolet cut-off is imposed we initiate the spectral analysis of the Hamiltonian describing the system and we derive the existence of a ground state. This is achieved without conditions on the fine structure constant. [CTDRG] C. Cohen-Tannoudji, J. Dupont-Roc and G. Grynberg. Processus d'interaction entre photons et atomes. Edition du CNRS, 2001.

  4. Computer simulation of liquid-vapor coexistence of confined quantum fluids

    Energy Technology Data Exchange (ETDEWEB)

    Trejos, Víctor M.; Gil-Villegas, Alejandro, E-mail: gil@fisica.ugto.mx; Martinez, Alejandro [División de Ciencias e Ingenierías, Campus León, Universidad de Guanajuato, Loma del Bosque 103, Lomas del Campestre, 37150 León, Guanajuato (Mexico)

    2013-11-14

    The liquid-vapor coexistence (LV) of bulk and confined quantum fluids has been studied by Monte Carlo computer simulation for particles interacting via a semiclassical effective pair potential V{sub eff}(r) = V{sub LJ} + V{sub Q}, where V{sub LJ} is the Lennard-Jones 12-6 potential (LJ) and V{sub Q} is the first-order Wigner-Kirkwood (WK-1) quantum potential, that depends on β = 1/kT and de Boer's quantumness parameter Λ=h/σ√(mε), where k and h are the Boltzmann's and Planck's constants, respectively, m is the particle's mass, T is the temperature of the system, and σ and ε are the LJ potential parameters. The non-conformal properties of the system of particles interacting via the effective pair potential V{sub eff}(r) are due to Λ, since the LV phase diagram is modified by varying Λ. We found that the WK-1 system gives an accurate description of the LV coexistence for bulk phases of several quantum fluids, obtained by the Gibbs Ensemble Monte Carlo method (GEMC). Confinement effects were introduced using the Canonical Ensemble (NVT) to simulate quantum fluids contained within parallel hard walls separated by a distance L{sub p}, within the range 2σ ⩽ L{sub p} ⩽ 6σ. The critical temperature of the system is reduced by decreasing L{sub p} and increasing Λ, and the liquid-vapor transition is not longer observed for L{sub p}/σ < 2, in contrast to what has been observed for the classical system.

  5. Efficient Blue Electroluminescence Using Quantum-Confined Two-Dimensional Perovskites.

    Science.gov (United States)

    Kumar, Sudhir; Jagielski, Jakub; Yakunin, Sergii; Rice, Peter; Chiu, Yu-Cheng; Wang, Mingchao; Nedelcu, Georgian; Kim, Yeongin; Lin, Shangchao; Santos, Elton J G; Kovalenko, Maksym V; Shih, Chih-Jen

    2016-10-03

    Solution-processed hybrid organic-inorganic lead halide perovskites are emerging as one of the most promising candidates for low-cost light-emitting diodes (LEDs). However, due to a small exciton binding energy, it is not yet possible to achieve an efficient electroluminescence within the blue wavelength region at room temperature, as is necessary for full-spectrum light sources. Here, we demonstrate efficient blue LEDs based on the colloidal, quantum-confined 2D perovskites, with precisely controlled stacking down to one-unit-cell thickness (n = 1). A variety of low-k organic host compounds are used to disperse the 2D perovskites, effectively creating a matrix of the dielectric quantum wells, which significantly boosts the exciton binding energy by the dielectric confinement effect. Through the Förster resonance energy transfer, the excitons down-convert and recombine radiatively in the 2D perovskites. We report room-temperature pure green (n = 7-10), sky blue (n = 5), pure blue (n = 3), and deep blue (n = 1) electroluminescence, with record-high external quantum efficiencies in the green-to-blue wavelength region.

  6. Spectroscopy and dynamics of charge transfer excitons in type-II band aligned quantum confined heterostructures

    Science.gov (United States)

    Kushavah, Dushyant; Mohapatra, P. K.; Rustagi, K. C.; Bahadur, D.; Vasa, P.; Singh, B. P.

    2015-05-01

    We illustrate effect of charge transfer (CT) in type-II quantum confined heterostructure by comparing CdSe quantum dots (QDs), CdSe/CdTe heterostructure quantum dots (HQDs) and CdSe/CdTe/CdSe quantum well-quantum dots (QWQDs) heterostructures. CdSe core QDs were synthesized using a kinetic growth method where QD size depends on reaction time. For shell coating we used modified version of successive ionic layer adsorption and reaction (SILAR). Size of different QDs ˜5 to 7 nm were measured by transmission electron microscopy (TEM). Strong red shift from ˜597 to ˜746 nm in photoluminescence (PL) spectra from QDs to QWQDs shows high tunability which is not possible with single constituent semiconductor QDs. PL spectra have been recorded at different temperatures (10K-300K). Room temperature time correlated single photon counting (TCSPC) measurements for QDs to QWQDs show three exponential radiative decay. The slowest component decay constant in QWQDs comes around eight fold to ˜51 ns as compared to ˜6.5 ns in HQD suggesting new opportunities to tailor the radiative carrier recombination rate of CT excitons.

  7. Spectroscopy and dynamics of charge transfer excitons in type-II band aligned quantum confined heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Kushavah, Dushyant [Centre for Research in Nanotechnology and Science, IIT Bombay-400076, Mumbai (India); Mohapatra, P. K.; Vasa, P.; Singh, B. P., E-mail: bhanups@iitb.ac.in [Department of physics, IIT Bombay, Mumbai-400076 (India); Rustagi, K. C. [Indian Institute of Science Education and Research Bhopal-462066, Bhopal (India); Bahadur, D. [Department of Metallurgical Engineering and Materials Science, IIT Bombay, Mumbai-400076 (India)

    2015-05-15

    We illustrate effect of charge transfer (CT) in type-II quantum confined heterostructure by comparing CdSe quantum dots (QDs), CdSe/CdTe heterostructure quantum dots (HQDs) and CdSe/CdTe/CdSe quantum well-quantum dots (QWQDs) heterostructures. CdSe core QDs were synthesized using a kinetic growth method where QD size depends on reaction time. For shell coating we used modified version of successive ionic layer adsorption and reaction (SILAR). Size of different QDs ∼5 to 7 nm were measured by transmission electron microscopy (TEM). Strong red shift from ∼597 to ∼746 nm in photoluminescence (PL) spectra from QDs to QWQDs shows high tunability which is not possible with single constituent semiconductor QDs. PL spectra have been recorded at different temperatures (10K-300K). Room temperature time correlated single photon counting (TCSPC) measurements for QDs to QWQDs show three exponential radiative decay. The slowest component decay constant in QWQDs comes around eight fold to ∼51 ns as compared to ∼6.5 ns in HQD suggesting new opportunities to tailor the radiative carrier recombination rate of CT excitons.

  8. Molecule-induced quantum confinement in single-walled carbon nanotube

    Science.gov (United States)

    Hida, Akira; Ishibashi, Koji

    2015-04-01

    A method of fabricating quantum-confined structures with single-walled carbon nanotubes (SWNTs) has been developed. Scanning tunneling spectroscopy revealed that a parabolic confinement potential appeared when collagen model peptides were attached to both ends of an individual SWNT via the formation of carboxylic anhydrides. On the other hand, the confinement potential was markedly changed by yielding the peptide bonds between the SWNT and the collagen model peptides. Photoluminescence spectroscopy measurements showed that a type-II quantum dot was produced in the obtained heterostructure.

  9. Maximal Wavelength of Confined Quarks and Gluons and Properties of Quantum Chromodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, Stanley J.; /SLAC /YITP, Stony Brook /Durham U.; Shrock, Robert; /YITP, Stony Brook

    2008-08-01

    Because quarks and gluons are confined within hadrons, they have a maximum wavelength of order the confinement scale. Propagators, normally calculated for free quarks and gluons using Dyson-Schwinger equations, are modified by bound-state effects in close analogy to the calculation of the Lamb shift in atomic physics. Because of confinement, the effective quantum chromodynamic coupling stays finite in the infrared. The quark condensate which arises from spontaneous chiral symmetry breaking in the bound state Dyson-Schwinger equation is the expectation value of the operator {bar q}q evaluated in the background of the fields of the other hadronic constituents, in contrast to a true vacuum expectation value. Thus quark and gluon condensates reside within hadrons. The effects of instantons are also modified. We discuss the implications of the maximum quark and gluon wavelength for phenomena such as deep inelastic scattering and annihilation, the decay of heavy quarkonia, jets, and dimensional counting rules for exclusive reactions. We also discuss implications for the zero-temperature phase structure of a vectorial SU(N) gauge theory with a variable number N{sub f} of massless fermions.

  10. Engineered valley-orbit splittings in quantum-confined nanostructures in silicon

    NARCIS (Netherlands)

    Rahman, R.; Verduijn, J.; Kharche, N.; Lansbergen, G.P.; Klimeck, G.; Hollenberg, L.C.L.; Rogge, S.

    2011-01-01

    An important challenge in silicon quantum electronics in the few electron regime is the potentially small energy gap between the ground and excited orbital states in 3D quantum confined nanostructures due to the multiple valley degeneracies of the conduction band present in silicon. Understanding th

  11. Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction

    Science.gov (United States)

    Lei, Fengcai; Liu, Wei; Sun, Yongfu; Xu, Jiaqi; Liu, Katong; Liang, Liang; Yao, Tao; Pan, Bicai; Wei, Shiqiang; Xie, Yi

    2016-09-01

    Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin-tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis.

  12. Carrier confinement in Ge/Si quantum dots grown with an intermediate ultrathin oxide layer

    Science.gov (United States)

    Kuryliuk, V.; Korotchenkov, O.; Cantarero, A.

    2012-02-01

    We present computational results for strain effects on charge carrier confinement in GexSi1-x quantum dots (QDs) grown on an oxidized Si surface. The strain and free carrier probability density distributions are obtained using the continuum elasticity theory and the effective-mass approximation implemented by a finite-element modeling scheme. Using realistic parameters and conditions for hemisphere and pyramid QDs, it is pointed out that an uncapped hemisphere dot deposited on the Si surface with an intermediate ultrathin oxide layer offers advantageous electron-hole separation distances with respect to a square-based pyramid grown directly on Si. The enhanced separation is associated with a larger electron localization depth in the Si substrate for uncapped hemisphere dots. Thus, for dot diameters smaller than 15-20 nm and surface density of the dots (nQD) ranging from about 1010 to 1012 cm-2, the localization depth may be enhanced from about 8 nm for a pyramid to 38 nm for a hemisphere dot. We find that the effect in a hemisphere dot is very sensitive to the dot density and size, whereas the localization depth is not significantly affected by the variation of the Ge fraction x in GexSi1-x and the aspect ratio of the dot. We also calculate the effect of the fixed oxide charge (Qox) with densities ranging from 10-9 to 10-7 C/cm2 for 10-Ωcm p-type Si wafers on the carrier confinement. Although the confinement potential can be strongly perturbed by the charge at nQD less than ≈4×1011 cm-2, it is not very sensitive to the value of Qox at higher nQD. Since, to our knowledge, there are no data on carrier confinement for Ge QDs deposited on oxidized Si surfaces, these results might be applicable to functional devices utilizing separated electrons and holes such as photovoltaic devices, spin transistors, and quantum computing components. The use of hemisphere QDs placed on oxidized Si rather than pyramid dots grown on bare Si may help to confine charge carriers deeper

  13. Enhancement of Hole Confinement by Monolayer Insertion in Asymmetric Quantum-Barrier UVB Light Emitting Diodes

    KAUST Repository

    Janjua, Bilal

    2014-04-01

    We study the enhanced hole confinement by having a large bandgap AlGaN monolayer insertion (MLI) between the quantum well (QW) and the quantum barrier (QB). The numerical analysis examines the energy band alignment diagrams, using a self-consistent 6 × 6 k ·p method and, considering carrier distribution, recombination rates (Shockley-Reed-Hall, Auger, and radiative recombination rates), under equilibrium and forward bias conditions. The active region is based on AlaGa1-aN (barrier)/AlbGa1-bN (MLI)/AlcGa1-cN (well)/AldGa1-dN (barrier), where b > d > a > c. A large bandgap AlbGa1-bN mono layer, inserted between the QW and QB, was found to be effective in providing stronger hole confinement. With the proposed band engineering scheme, an increase of more than 30% in spatial overlap of carrier wavefunction was obtained, with a considerable increase in carrier density and direct radiative recombination rates. The single-QW-based UV-LED was designed to emit at 280 nm, which is an effective wavelength for water disinfection.

  14. Confinement in the Bulk, Deconfinement on the Wall: Infrared Equivalence between Compactified QCD and Quantum Magnets

    Science.gov (United States)

    Sulejmanpasic, Tin; Shao, Hui; Sandvik, Anders W.; Ünsal, Mithat

    2017-09-01

    In a spontaneously dimerized quantum antiferromagnet, spin-1 /2 excitations (spinons) are confined in pairs by strings akin to those confining quarks in non-Abelian gauge theories. The system has multiple degenerate ground states (vacua) and domain walls between regions of different vacua. For two vacua, we demonstrate that spinons on a domain wall are liberated, in a mechanism strikingly similar to domain-wall deconfinement of quarks in variants of quantum chromodynamics. This observation not only establishes a novel phenomenon in quantum magnetism, but also provides a new direct link between particle physics and condensed-matter physics. The analogy opens doors to improving our understanding of particle confinement and deconfinement by computational and experimental studies in quantum magnetism.

  15. Elucidating Quantum Confinement in Graphene Oxide Dots Based On Excitation-Wavelength-Independent Photoluminescence.

    Science.gov (United States)

    Yeh, Te-Fu; Huang, Wei-Lun; Chung, Chung-Jen; Chiang, I-Ting; Chen, Liang-Che; Chang, Hsin-Yu; Su, Wu-Chou; Cheng, Ching; Chen, Shean-Jen; Teng, Hsisheng

    2016-06-02

    Investigating quantum confinement in graphene under ambient conditions remains a challenge. In this study, we present graphene oxide quantum dots (GOQDs) that show excitation-wavelength-independent photoluminescence. The luminescence color varies from orange-red to blue as the GOQD size is reduced from 8 to 1 nm. The photoluminescence of each GOQD specimen is associated with electron transitions from the antibonding π (π*) to oxygen nonbonding (n-state) orbitals. The observed quantum confinement is ascribed to a size change in the sp(2) domains, which leads to a change in the π*-π gap; the n-state levels remain unaffected by the size change. The electronic properties and mechanisms involved in quantum-confined photoluminescence can serve as the foundation for the application of oxygenated graphene in electronics, photonics, and biology.

  16. Quantum confinement in amorphous TiO(2) films studied via atomic layer deposition.

    Science.gov (United States)

    King, David M; Du, Xiaohua; Cavanagh, Andrew S; Weimer, Alan W

    2008-11-05

    Despite the significant recent increase in quantum-based optoelectronics device research, few deposition techniques can reliably create the required functional nanoscale systems. Atomic layer deposition (ALD) was used here to study the quantum effects attainable through the use of this ångström-level controlled growth process. Size-dependent quantum confinement has been demonstrated using TiO(2) layers of nanoscale thickness applied to the surfaces of silicon wafers. TiO(2) films were deposited at 100 °C using TiCl(4) and H(2)O(2) in a viscous flow ALD reactor, at a rate of 0.61 Å/cycle. The low-temperature process was utilized to guarantee the amorphous deposition of TiO(2) layers and post-deposition thermal annealing was employed to promote crystallite-size modification. Hydrogen peroxide significantly reduced the residual chlorine that remained from a typical TiCl(4)-H(2)O ALD process at this temperature, down to 1.6%. Spectroscopic ellipsometry was used to quantify the optical properties both below and above the bandgap energy. A central composite design was employed to map the surface response of the film thickness-dependent bandgap shift for the as-deposited case and up to a thermal annealing temperature of 550 °C. The Brus model was used to develop a correlation between the amorphous TiO(2) film thickness and the quantum length to promote equivalent bandgap shifts.

  17. Field enhancement at metallic interfaces due to quantum confinement

    DEFF Research Database (Denmark)

    Öztürk, Fatih; Xiao, Sanshui; Yan, Min

    2011-01-01

    triangular nanoislands via numerical solutions of the appropriate Maxwell equations, and show that the field enhancement is several orders of magnitude larger than what the conventional theory predicts. (C) 2011 Society of Photo-Optical Instrumentation Engineers (SPIE). [DOI: 10.1117/1.3574159]......We point out an apparently overlooked consequence of the boundary conditions obeyed by the electric displacement vector at air-metal interfaces: the continuity of the normal component combined with the quantum mechanical penetration of the electron gas in the air implies the existence of a surface...... on which the dielectric function vanishes. This, in turn, leads to an enhancement of the normal component of the total electric field. We study this effect for a planar metal surface, with the inhomogeneous electron density accounted for by a Jellium model. We also illustrate the effect for equilateral...

  18. Free standing luminescent silicon quantum dots: evidence of quantum confinement and defect related transitions

    Energy Technology Data Exchange (ETDEWEB)

    Ray, Mallar [School of Materials Science and Engineering, Bengal Engineering and Science University, Shibpur, Howrah: 711103, West Bengal (India); Hossain, Syed Minhaz [Department of Physics, Bengal Engineering and Science University, Shibpur, Howrah: 711103, West Bengal (India); Klie, Robert F [Department of Physics, University of Illinois at Chicago, Chicago, IL 60607 (United States); Banerjee, Koushik; Ghosh, Siddhartha, E-mail: mray@matsc.becs.ac.in [Department of Electrical and Computer Engineering, University of Illinois at Chicago, Chicago, 60607 (United States)

    2010-12-17

    We report the synthesis of luminescent, free standing silicon quantum dots by dry and wet etching of silicon and silicon oxide core/shell nanostructures, which are synthesized by controlled oxidation of mechanically milled silicon. Dry and wet etching performed with CF{sub 4} plasma and aqueous HF, respectively, result in the removal of the thick oxide shell of the core/shell nanostructures and affect an additional step of size reduction. HF etch is capable of producing isolated, spherical quantum dots of silicon with dimensions {approx} 2 nm. However, the etching processes introduce unsaturated bonds at the surface of the nanocrystals which are subsequently passivated by oxygen on exposure to ambient atmosphere. The photoluminescence spectra of the colloidal suspensions of these nanocrystals are characterized by double peaks and excitation dependent shift of emission energy. Comparison of the structural, absorption and luminescence characteristics of the samples provides evidence for two competing transition processes-quantum confinement induced widened band gap related transitions and oxide associated interface state mediated transitions. The results enable us to experimentally distinguish between the contributions of the two different transition mechanisms, which has hitherto been a challenging problem.

  19. Quantum engineering. Confining the state of light to a quantum manifold by engineered two-photon loss.

    Science.gov (United States)

    Leghtas, Z; Touzard, S; Pop, I M; Kou, A; Vlastakis, B; Petrenko, A; Sliwa, K M; Narla, A; Shankar, S; Hatridge, M J; Reagor, M; Frunzio, L; Schoelkopf, R J; Mirrahimi, M; Devoret, M H

    2015-02-20

    Physical systems usually exhibit quantum behavior, such as superpositions and entanglement, only when they are sufficiently decoupled from a lossy environment. Paradoxically, a specially engineered interaction with the environment can become a resource for the generation and protection of quantum states. This notion can be generalized to the confinement of a system into a manifold of quantum states, consisting of all coherent superpositions of multiple stable steady states. We have confined the state of a superconducting resonator to the quantum manifold spanned by two coherent states of opposite phases and have observed a Schrödinger cat state spontaneously squeeze out of vacuum before decaying into a classical mixture. This experiment points toward robustly encoding quantum information in multidimensional steady-state manifolds.

  20. Elementary framework for cold field emission from quantum-confined, non-planar emitters

    Energy Technology Data Exchange (ETDEWEB)

    Patterson, A. A., E-mail: apatters@mit.edu; Akinwande, A. I. [Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA and Microsystems Technology Laboratories, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2015-05-07

    For suitably small field emitters, the effects of quantum confinement at the emitter tip may have a significant impact on the emitter performance and total emitted current density (ECD). Since the geometry of a quantum system uniquely determines the magnitude and distribution of its energy levels, a framework for deriving ECD equations from cold field electron emitters of arbitrary geometry and dimensionality is developed. In the interest of obtaining semi-analytical ECD equations, the framework is recast in terms of plane wave solutions to the Schrödinger equation via the use of the Jeffreys-Wentzel-Kramers-Brillouin approximation. To demonstrate the framework's consistency with our previous work and its capabilities in treating emitters with non-planar geometries, ECD equations were derived for the normally unconfined cylindrical nanowire (CNW) and normally confined (NC) CNW emitter geometries. As a function of the emitter radius, the NC CNW emitter ECD profile displayed a strong dependence on the Fermi energy and had an average ECD that exceeded the Fowler-Nordheim equation for typical values of the Fermi energy due to closely spaced, singly degenerate energy levels (excluding electron spin), comparatively large electron supply values, and the lack of a transverse, zero-point energy. Such characteristics suggest that emitters with non-planar geometries may be ideal for emission from both an electron supply and electrostatics perspective.

  1. Heat capacity and entropy of a GaAs quantum dot with Gaussian confinement.

    Science.gov (United States)

    Boyacioglu, B; Chatterjee, A

    2012-10-15

    The heat capacity and entropy effects in a GaAs quantum dot with Gaussian confinement are calculated in the presence of a magnetic field and its interaction with the electron spin using the canonical ensemble approach. It is shown that the heat capacity shows a Schottky-like anomaly at a low temperature, while it approaches a saturation value 2k(B) as the temperature increases. As a function of the magnetic field, the heat capacity shows a maximum and then reduces to zero. Also the width of the maximum becomes wider with temperature. It is also shown that the heat capacity remains constant up to a certain value of the confinement length beyond which it displays a monotonic increase. However as a function of the confinement strength, though the heat capacity initially shows a significant drop, it remains constant thereafter. At low temperatures like T = 10 and 20 K, the entropy is found to decrease with increasing magnetic field, but at higher temperatures, it remains almost independent of the magnetic field. At high temperatures, entropy shows a monotonic increase with temperature, but at a sufficiently low temperature as the magnetic field decreases, the entropy is found to develop a shoulder which becomes more and more pronounced with decreasing magnetic field.

  2. Chiral effects in the confining QCD vacuum

    CERN Document Server

    Simonov, Yu A

    1994-01-01

    Configurations are introduced into the standard instanton vacuum model. This drastically improves theoretical properties of the vacuum: instanton size density $d(\\rho)$ stabilizes at $\\rho\\sim 0.2 fm$, all chiral effects are formulated in a gauge-invariant way and quarks are confined. An interesting interplay of chiral and confining dynamics is observed; for the realistic values of parameters the Georgi-Manohar picture emerges with chiral radius $R_{ch}\\sim \\rho\\sim 0.2 fm$ much less than confining radius $R_c\\sim$ hadron radius $\\sim 1 fm$. In the limit $R_{ch}\\ll R_c$ the chiral mass $M_{ch}(p)$ is unaffected by confinement and can be taken in the local limit $M_{ch}(p=0)$. Different types of effective chiral Lagrangians (ECL) are obtained, containing all or a part of gluon, quark and Nambu--Goldstone--meson fields. The ECL are manifestly gauge--invariant and in the limit of no gluon fields coincide with those found previously. The problem of the double role of the pion -- as a Goldstone meson or as a $q\\ba...

  3. Confinement orientation effects in S/D tunneling

    Science.gov (United States)

    Medina-Bailon, C.; Sampedro, C.; Gámiz, F.; Godoy, A.; Donetti, L.

    2017-02-01

    The most extensive research of scaled electronic devices involves the inclusion of quantum effects in the transport direction as transistor dimensions approach nanometer scales. Moreover, it is necessary to study how these mechanisms affect different transistor architectures to determine which one can be the best candidate to implement future nodes. This work implements Source-to-Drain Tunneling mechanism (S/D tunneling) in a Multi-Subband Ensemble Monte Carlo (MS-EMC) simulator showing the modification in the distribution of the electrons in the subbands, and, consequently, in the potential profile due to different confinement direction between DGSOIs and FinFETs.

  4. Quantum behavior of water nano-confined in beryl

    Science.gov (United States)

    Finkelstein, Y.; Moreh, R.; Shang, S. L.; Wang, Y.; Liu, Z. K.

    2017-03-01

    The proton mean kinetic energy, Ke(H), of water confined in nanocavities of beryl (Be3Al2Si6O18) at 5 K was obtained by simulating the partial vibrational density of states from density functional theory based first-principles calculations. The result, Ke(H) = 104.4 meV, is in remarkable agreement with the 5 K deep inelastic neutron scattering (DINS) measured value of 105 meV. This is in fact the first successful calculation that reproduces an anomalous DINS value regarding Ke(H) in nano-confined water. The calculation indicates that the vibrational states of the proton of the nano-confined water molecule distribute much differently than in ordinary H2O phases, most probably due to coupling with lattice modes of the hosting beryl nano-cage. These findings may be viewed as a promising step towards the resolution of the DINS controversial measurements on other H2O nano-confining systems, e.g., H2O confined in single and double walled carbon nanotubes.

  5. Optical absorption and refraction index change of a confined exciton in a spherical quantum dot nanostructure

    Science.gov (United States)

    Mathan Kumar, K.; John Peter, A.; Lee, C. W.

    2011-12-01

    Electronic energies of an exciton confined in a strained Zn1- x Cd x Se/ZnSe quantum dot have been computed as a function of dot radius with various Cd content. Calculations have been performed using Bessel function as an orthonormal basis for different confinement potentials of barrier height considering the internal electric field induced by the spontaneous and piezoelectric polarizations. The optical absorption coefficients and the refractive index changes between the ground state ( L = 0) and the first excited state ( L = 1) are investigated. It is found that the optical properties in the strained ZnCdSe/ZnSe quantum dot are strongly affected by the confinement potentials and the dot radii. The intensity of the total absorption spectra increases for the transition between higher levels. The obtained optical nonlinearity brings out the fact that it should be considered in calculating the optical properties in low dimensional semiconductors especially in quantum dots.

  6. Spectral properties of a confined nonlinear quantum oscillator in one and three dimensions

    Energy Technology Data Exchange (ETDEWEB)

    Schulze-Halberg, Axel; Gordon, Christopher R. [Department of Mathematics and Actuarial Science, Indiana University Northwest, 3400 Broadway, Gary, Indiana 46408 (United States)

    2013-04-15

    We analyze the spectral behaviour of a nonlinear quantum oscillator model under confinement. The underlying potential is given by a harmonic oscillator interaction plus a nonlinear term that can be weakened or strengthened through a parameter. Numerical eigenvalues of the model in one and three dimensions are presented. The asymptotic behaviour of the eigenvalues for confinement relaxation and for vanishing nonlinear term in the potential is investigated. Our findings are compared with existing results.

  7. Exact diagonalization of the D-dimensional spatially confined quantum harmonic oscillator

    Directory of Open Access Journals (Sweden)

    Kunle Adegoke

    2016-01-01

    Full Text Available In the existing literature various numerical techniques have been developed to quantize the confined harmonic oscillator in higher dimensions. In obtaining the energy eigenvalues, such methods often involve indirect approaches such as searching for the roots of hypergeometric functions or numerically solving a differential equation. In this paper, however, we derive an explicit matrix representation for the Hamiltonian of a confined quantum harmonic oscillator in higher dimensions, thus facilitating direct diagonalization.

  8. Transversal confined polar optical phonons in spherical quantum-dot/quantum-well nanostructures

    Science.gov (United States)

    Comas, F.; Trallero-Giner, C.; Prado, S. J.; Marques, G. E.; Roca, E.

    2006-02-01

    Confined polar optical phonons are studied in a spherical quantum-dot/quantum-well (QD/QW) nanostructure by using an approach that takes into account the coupling of electromechanical oscillations and is valid in the long-wave limit. This approach was developed a few years ago and provides results beyond the usually applied dielectric continuum approach (DCA), where just the electric aspect of the oscillations is considered. In the present paper we limit ourselves to the study of the so-called uncoupled modes, having a purely transversal character and not involving an electric potential. We display the dispersion curves for the frequencies considering three possible nanostructures, which show different bulk phonon curvatures near the Brillouin zone -point and have been actually grown: ZnS/CdSe, CdSe/CdS and CdS/HgS. A detailed discussion of the results obtained is made, emphasizing the novelties provided by our treatment and the relevance of infrared spectroscopy in the characterization of the geometrical features of the QD/QW nanostructure.

  9. Optimization of the confinement energy of quantum-wire states in T-shaped GaAs/AlxGa1-xAs structures

    DEFF Research Database (Denmark)

    Langbein, Wolfgang Werner; Gislason, Hannes; Hvam, Jørn Märcher

    1996-01-01

    We report on an optimization of the wire confinement energies of the confined electronic states at the T-shaped intersection of GaAs and AlxGa1-xAs quantum wells. These structures can be produced by the cleaved edge overgrowth technique. We present an analytical model for the confinement to give......-shaped intersection due to the large and anisotropic hole effective masses. Employing optimized sample parameters, confinement energies for the free-electron-hole pairs are nearly doubled compared to symmetric structures, and 34 meV are predicted for a 3-nm overgrown GaAs well. This is expected to be further enhanced...

  10. Quantum confined laser devices optical gain and recombination in semiconductors

    CERN Document Server

    Blood, Peter

    2015-01-01

    The semiconductor laser, invented over 50 years ago, has had an enormous impact on the digital technologies that now dominate so many applications in business, commerce and the home. The laser is used in all types of optical fibre communication networks that enable the operation of the internet, e-mail, voice and skype transmission. Approximately one billion are produced each year for a market valued at around $5 billion. Nearly all semiconductor lasers now use extremely thin layers of light emitting materials (quantum well lasers). Increasingly smaller nanostructures are used in the form of quantum dots. The impact of the semiconductor laser is surprising in the light of the complexity of the physical processes that determine the operation of every device. This text takes the reader from the fundamental optical gain and carrier recombination processes in quantum wells and quantum dots, through descriptions of common device structures to an understanding of their operating characteristics. It has a consistent...

  11. Anisotropic carrier and exciton confinement in T-shaped quantum wires revealed by magneto-photoluminescence

    DEFF Research Database (Denmark)

    Langbein, Wolfgang Werner; Gislason, Hannes; Hvam, Jørn Märcher

    1998-01-01

    The realization of one-dimensional (1D) semiconductor nanostructures with large confinement energies is of importance for device applications. Different techniques such as growth on tilted substrates (Serpentine superlattices) or prepatterned substrates (V-groove quantum wires) and the cleaved-ed...... was revealed by magneto-photoluminescence. We determine here the extension of the T-shaped quantum wire (T-QWR) state in both confining directions [110] and [001] to verify its 1D character, as shown for crescent-shaped wires...

  12. Two Interacting Electrons in a Spherical Gaussian Confining Potential Quantum Well

    Institute of Scientific and Technical Information of China (English)

    XIE Wen-Fang

    2004-01-01

    Two-electron states of a three-dimensional spherical GaAs quantum dot (QD) with a Gaussian confining potential confinement are studied. Calculations are made by using the method of few-body physics within the effectivemass approximation. We have calculated the energy levels of single and triplet states as functions of the range and depth of the confining potential well in the spherical QDs. The same calculations performed with the parabolic approximation of the Gaussian potential lead to the results, which are qualitatively and quantitatively different.

  13. Canonical pairs, Spatially Confined Motion and the Quantum Time of Arrival Problem

    CERN Document Server

    Galapon, E A

    2000-01-01

    It has always been believed that no self-adjoint and canonical time of arrival operator can be constructed within the confines of standard quantum mechanics. In this Letter we demonstrate the otherwise. We do so by pointing out that there is no a priori reason in demanding that canonical pairs form a system of imprimitivities. We then proceed to show that a class of self-adjoint and canonical time of arrival (TOA) operators can be constructed for a spatially confined free particle. And then discuss the relatiobship between the non-self-adjointess of the TOA operator for the unconfined particle and the self-adjointness of the confined one.

  14. Charge Carrier Dynamics of Quantum Confined Semiconductor Nanoparticles Analyzed via Transient Absorption Spectroscopy

    Science.gov (United States)

    Thibert, Arthur Joseph, III

    Semiconductor nanoparticles are tiny crystalline structures (typically range from 1 - 100 nm) whose shape in many cases can be dictated through tailored chemical synthesis with atomic scale precision. The small size of these nanoparticles often results in quantum confinement (spatial confinement of wave functions), which imparts the ability to manipulate band-gap energies thus allowing them to be optimally engineered for different applications (i.e., photovoltaics, photocatalysis, imaging). However, charge carriers excited within these nanoparticles are often involved in many different processes: trapping, trap migration, Auger recombination, non-radiative relaxation, radiative relaxation, oxidation / reduction, or multiple exciton generation. Broadband ultrafast transient absorption laser spectroscopy is used to spectrally resolve the fate of excited charge carriers in both wavelength and time, providing insight as to what synthetic developments or operating conditions will be necessary to optimize their efficiency for certain applications. This thesis outlines the effort of resolving the dynamics of excited charge carriers for several Cd and Si based nanoparticle systems using this experimental technique. The thesis is organized into five chapters and two appendices as indicated below. Chapter 1 provides a brief introduction to the photophysics of semiconductor nanoparticles. It begins by defining what nanoparticles, semiconductors, charge carriers, and quantum confinement are. From there it details how the study of charge carrier dynamics within nanoparticles can lead to increased efficiency in applications such as photocatalysis. Finally, the experimental methodology associated with ultrafast transient absorption spectroscopy is introduced and its power in mapping charge carrier dynamics is established. Chapter 2 (JPCC, 19647, 2011) introduces the first of the studied samples: water-solubilized 2D CdSe nanoribbons (NRs), which were synthesized in the Osterloh

  15. Orbital magnetism of graphene nanostructures: Bulk and confinement effects

    Science.gov (United States)

    Heße, Lisa; Richter, Klaus

    2014-11-01

    We consider the orbital magnetic properties of noninteracting charge carriers in graphene-based nanostructures in the low-energy regime. The magnetic response of such systems results both from bulk contributions and from confinement effects that can be particularly strong in ballistic quantum dots. First we provide a comprehensive study of the magnetic susceptibility χ of bulk graphene in a magnetic field for the different regimes arising from the relative magnitudes of the energy scales involved, i.e., temperature, Landau-level spacing, and chemical potential. We show that for finite temperature or chemical potential, χ is not divergent although the diamagnetic contribution χ0 from the filled valance band exhibits the well-known -B-1 /2 dependence. We further derive oscillatory modulations of χ , corresponding to de Haas-van Alphen oscillations of conventional two-dimensional electron gases. These oscillations can be large in graphene, thereby compensating the diamagnetic contribution χ0 and yielding a net paramagnetic susceptibility for certain energy and magnetic field regimes. Second, we predict and analyze corresponding strong, confinement-induced susceptibility oscillations in graphene-based quantum dots with amplitudes distinctly exceeding the corresponding bulk susceptibility. Within a semiclassical approach we derive generic expressions for orbital magnetism of graphene quantum dots with regular classical dynamics. Graphene-specific features can be traced back to pseudospin interference along the underlying periodic orbits. We demonstrate the quality of the semiclassical approximation by comparison with quantum-mechanical results for two exemplary mesoscopic systems, a graphene disk with infinite mass-type edges, and a rectangular graphene structure with armchair and zigzag edges, using numerical tight-binding calculations in the latter case.

  16. Quantum confinement of excitons in wurtzite InP nanowires

    Science.gov (United States)

    Pemasiri, K.; Jackson, H. E.; Smith, L. M.; Wong, B. M.; Paiman, S.; Gao, Q.; Tan, H. H.; Jagadish, C.

    2015-05-01

    Exciton resonances are observed in photocurrent spectra of 80 nm wurtzite InP nanowire devices at low temperatures, which correspond to transitions between the A, B, and C valence bands and the lower conduction band. Photocurrent spectra for 30 nm WZ nanowires exhibit shifts of the exciton resonances to higher energy, which are consistent with finite element calculations of wavefunctions of the confined electrons and holes for the various bands.

  17. Energy spectrum of an electron confined in the hexagon-shaped quantum well

    Institute of Scientific and Technical Information of China (English)

    Yu.; V.; VOROBIEV; V.; R.; VIEIRA; P.; P.; HORLEY; P.; N.; GORLEY; J.; GONZLEZ-HERNNDEZ

    2009-01-01

    Considering the hexagonal-shaped quantum-scale formations on the surface of thin semiconductor films, a methodology was developed to obtain the analytical solution of the Schrdinger equation when impenetrable walls of a quantum well are treated as mirrors. The results obtained allowed the calculation of the space probability distributions and the energy spectrum of the particle confined in a hex-agonal-shaped well.

  18. Energy spectrum of an electron confined in the hexagon-shaped quantum well

    Institute of Scientific and Technical Information of China (English)

    Yu.V.VOROBIEV; V.R.VlEIRA; P.P.HORLEY; P.N.GORLEY; J.GONZ(A)LEZ-HERN(A)NDEZ

    2009-01-01

    Considering the hexagonal-shaped quantum-scale formations on the surface of thin semiconductor films, a methodology was developed to obtain the analytical solution of the Schr(o)dinger equation when impenetrable walls of a quantum well are treated as mirrors. The results obtained allowed the calcula-tion of the space probability distributions and the energy spectrum of the particle confined in a hex-agonal-shaped well.

  19. Quantum confinement induced performance enhancement in sub-5-nm lithographic Si nanowire transistors.

    Science.gov (United States)

    Trivedi, Krutarth; Yuk, Hyungsang; Floresca, Herman Carlo; Kim, Moon J; Hu, Walter

    2011-04-13

    We demonstrate lithographically fabricated Si nanowire field effect transistors (FETs) with long Si nanowires of tiny cross sectional size (∼3-5 nm) exhibiting high performance without employing complementarily doped junctions or high channel doping. These nanowire FETs show high peak hole mobility (as high as over 1200 cm(2)/(V s)), current density, and drive current as well as low drain leakage current and high on/off ratio. Comparison of nanowire FETs with nanobelt FETs shows enhanced performance is a result of significant quantum confinement in these 3-5 nm wires. This study suggests simple (no additional doping) FETs using tiny top-down nanowires can deliver high performance for potential impact on both CMOS scaling and emerging applications such as biosensing.

  20. Electronic states in crystals of finite size quantum confinement of bloch waves

    CERN Document Server

    Ren, Shang Yuan

    2017-01-01

    This book presents an analytical theory of the electronic states in ideal low dimensional systems and finite crystals based on a differential equation theory approach. It provides precise and fundamental understandings on the electronic states in ideal low-dimensional systems and finite crystals, and offers new insights into some of the basic problems in low-dimensional systems, such as the surface states and quantum confinement effects, etc., some of which are quite different from what is traditionally believed in the solid state physics community. Many previous predictions have been confirmed in subsequent investigations by other authors on various relevant problems. In this new edition, the theory is further extended to one-dimensional photonic crystals and phononic crystals, and a general theoretical formalism for investigating the existence and properties of surface states/modes in semi-infinite one-dimensional crystals is developed. In addition, there are various revisions and improvements, including us...

  1. Quantum-Carnot engine for particle confined to cubic potential

    Science.gov (United States)

    Sutantyo, Trengginas Eka P.; Belfaqih, Idrus H.; Prayitno, T. B.

    2015-09-01

    Carnot cycle consists of isothermal and adiabatic processes which are reversible. Using analogy in quantum mechanics, these processes can be well explained by replacing variables in classical process with a quantum system. Quantum system which is shown in this paper is a particle that moves under the influence of a cubic potential which is restricted only to the state of the two energy levels. At the end, the efficiency of the system is shown as a function of the width ratio between the initial conditions and the farthest wall while expanding. Furthermore, the system efficiency will be considered 1D and 2D cases. The providing efficiencies are different due to the influence of the degeneration of energy and the degrees of freedom of the system.

  2. Quantum-Carnot engine for particle confined to cubic potential

    Energy Technology Data Exchange (ETDEWEB)

    Sutantyo, Trengginas Eka P., E-mail: trengginas.eka@gmail.com; Belfaqih, Idrus H., E-mail: idrushusin21@gmail.com; Prayitno, T. B., E-mail: teguh-budi@unj.ac.id [Department of Physics, State University of Jakarta, Jl. Pemuda No.10, Rawamangun, Jakarta Timur 13220 (Indonesia)

    2015-09-30

    Carnot cycle consists of isothermal and adiabatic processes which are reversible. Using analogy in quantum mechanics, these processes can be well explained by replacing variables in classical process with a quantum system. Quantum system which is shown in this paper is a particle that moves under the influence of a cubic potential which is restricted only to the state of the two energy levels. At the end, the efficiency of the system is shown as a function of the width ratio between the initial conditions and the farthest wall while expanding. Furthermore, the system efficiency will be considered 1D and 2D cases. The providing efficiencies are different due to the influence of the degeneration of energy and the degrees of freedom of the system.

  3. Demonstration of Quantum Entanglement between a Single Electron Spin Confined to an InAs Quantum Dot and a Photon

    Science.gov (United States)

    2013-04-16

    AUTHOR(S) J. Schaibley, A. Burgers, G. McCracken , L. Duan, P. Berman, D. Steel, A. Bracker, D. Gammon, and I. Sham 5d. PROJECT NUMBER QEST 5e...TERMS quantum entanglement, electron spin, photon, quantum dot, laser J. R. Schaibley, A. P. Burgers, G. A. McCracken , L.-M. Duan, P. R. Berman, D...Single Electron Spin Confined to an InAs Quantum Dot and a Photon J. R. Schaibley, A. P. Burgers, G.A. McCracken , L.-M. Duan, P. R. Berman, and D.G

  4. Effective diffusion of confined active Brownian swimmers

    Science.gov (United States)

    Sandoval, Mario; Dagdug, Leonardo

    2014-11-01

    We find theoretically the effect of confinement and thermal fluctuations, on the diffusivity of a spherical active swimmer moving inside a two-dimensional narrow cavity of general shape. The explicit formulas for the effective diffusion coefficient of a swimmer moving inside two particular cavities are presented. We also compare our analytical results with Brownian Dynamics simulations and we obtain excellent agreement. L.D. thanks Consejo Nacional de Ciencia y Tecnologia (CONACyT) Mexico, for partial support by Grant No. 176452. M. S. thanks CONACyT and Programa de Mejoramiento de Profesorado (PROMEP) for partially funding this work under Grant No. 103.5/13/6732.

  5. Quantum Hamlet Effect

    CERN Document Server

    Panković, Vladan

    2009-01-01

    In this work, by use of a formalism similar to formalism of the quantum Zeno effect (decrease of the decay probability of an unstable quantum system by frequent measurements) and quantum anti-Zeno effect (increase of the decay probability of an unstable quantum system by frequent measurements), we introduce so-called quantum Hamlet effect. It represents a complete destruction of the quantum predictions on the decay probability of an unstable quantum system by frequent measurement. Precisely, by means of some especial, correctly defined, frequent measurements, decay probability of an unstable quantum system can behave as a divergent series without any definite value. In this way there is quantum mechanically completely unsolvable ``Hamlet dilemma'', to decay or not to decay.

  6. Charge injection and transport in quantum confined and disordered systems

    NARCIS (Netherlands)

    Houtepen, A.J.

    2007-01-01

    Quantum dots and conducting polymers are modern semiconductors with a high potential for applications such as lasers, LEDs, displays, solar cells etc. These applications require the controlled addition of charge carriers into the material and knowledge of the details of charge transport. This thesis

  7. Charge injection and transport in quantum confined and disordered systems

    NARCIS (Netherlands)

    Houtepen, A.J.

    2007-01-01

    Quantum dots and conducting polymers are modern semiconductors with a high potential for applications such as lasers, LEDs, displays, solar cells etc. These applications require the controlled addition of charge carriers into the material and knowledge of the details of charge transport. This thesis

  8. Wet chemical synthesis of quantum confined nanostructured tin oxide thin films by successive ionic layer adsorption and reaction technique

    Energy Technology Data Exchange (ETDEWEB)

    Murali, K.V., E-mail: kvmuralikv@gmail.com [School of Pure and Applied Physics, Department of Physics, Kannur University, Kerala 670327 (India); Department of Physics, Nehru Arts and Science College, Kanhangad, Kerala 671314 (India); Ragina, A.J. [School of Pure and Applied Physics, Department of Physics, Kannur University, Kerala 670327 (India); Department of Physics, Nehru Arts and Science College, Kanhangad, Kerala 671314 (India); Preetha, K.C. [School of Pure and Applied Physics, Department of Physics, Kannur University, Kerala 670327 (India); Department of Physics, Sree Narayana College, Kannur, Kerala 670007 (India); Deepa, K.; Remadevi, T.L. [School of Pure and Applied Physics, Department of Physics, Kannur University, Kerala 670327 (India); Department of Physics, Pazhassi Raja N.S.S. College, Mattannur, Kerala 670702 (India)

    2013-09-01

    Graphical abstract: - Highlights: • Quantum confined SnO{sub 2} thin films were synthesized at 80 °C by SILAR technique. • Film formation mechanism is discussed. • Films with snow like crystallite morphology offer high specific surface area. • The blue-shifted value of band gap confirmed the quantum confinement effect. • Present synthesis has advantages – low cost, low temperature and green friendly. - Abstract: Quantum confined nanostructured SnO{sub 2} thin films were synthesized at 353 K using ammonium chloride (NH{sub 4}Cl) and other chemicals by successive ionic layer adsorption and reaction technique. Film formation mechanism is discussed. Structural, morphological, optical and electrical properties were investigated and compared with the as-grown and annealed films fabricated without NH{sub 4}Cl solution. SnO{sub 2} films were polycrystalline with crystallites of tetragonal structure with grain sizes lie in the 5–8 nm range. Films with snow like crystallite morphology offer high specific surface area. The blue-shifted value of band gap of as-grown films confirmed the quantum confinement effect of grains. Refractive index of the films lies in the 2.1–2.3 range. Films prepared with NH{sub 4}Cl exhibit relatively lower resistivity of the order of 10{sup 0}–10{sup −1} Ω cm. The present synthesis has advantages such as low cost, low temperature and green friendly, which yields small particle size, large surface–volume ratio, and high crystallinity SnO{sub 2} films.

  9. Demonstration of quantum entanglement between a single electron spin confined to an InAs quantum dot and a photon.

    Science.gov (United States)

    Schaibley, J R; Burgers, A P; McCracken, G A; Duan, L-M; Berman, P R; Steel, D G; Bracker, A S; Gammon, D; Sham, L J

    2013-04-19

    The electron spin state of a singly charged semiconductor quantum dot has been shown to form a suitable single qubit for quantum computing architectures with fast gate times. A key challenge in realizing a useful quantum dot quantum computing architecture lies in demonstrating the ability to scale the system to many qubits. In this Letter, we report an all optical experimental demonstration of quantum entanglement between a single electron spin confined to a single charged semiconductor quantum dot and the polarization state of a photon spontaneously emitted from the quantum dot's excited state. We obtain a lower bound on the fidelity of entanglement of 0.59±0.04, which is 84% of the maximum achievable given the timing resolution of available single photon detectors. In future applications, such as measurement-based spin-spin entanglement which does not require sub-nanosecond timing resolution, we estimate that this system would enable near ideal performance. The inferred (usable) entanglement generation rate is 3×10(3) s(-1). This spin-photon entanglement is the first step to a scalable quantum dot quantum computing architecture relying on photon (flying) qubits to mediate entanglement between distant nodes of a quantum dot network.

  10. Investigation of Confinement Induced Resonance in Atomic Waveguides with Different Geometries by Quantum Monte Carlo Methods

    CERN Document Server

    Azizi, Sajad

    2016-01-01

    We have investigated the quantum dynamics of two ultracold bosons inside an atomic waveguide for two different confinement geometries (cigar-shaped and toroidal waveguides) by quantum Monte Carlo methods. For quasi-1D gases, the confining potential of the waveguide leads to the so-called confinement induced resonance (CIR), results in the phase transition of the gas to the impenetrable bosonic regime (known as TG gas). In this regime the bosons repel each other strongly and behave like fermions. We reproduce CIR for a cigar-shaped waveguide and analyze the behavior of the system for different conditions. Moreover, our analysis demonstrates appearance of CIR for a toroidal waveguide. Particularly, we show that the resonance position is dependent on the size of the waveguide, which is in contrast to the cigar shaped waveguides for which it is universal.

  11. Competing ν = 5/2 fractional quantum Hall states in confined geometry

    Science.gov (United States)

    Fu, Hailong; Wang, Pengjie; Shan, Pujia; Xiong, Lin; Pfeiffer, Loren N.; West, Ken; Kastner, Marc A.; Lin, Xi

    2016-11-01

    Some theories predict that the filling factor 5/2 fractional quantum Hall state can exhibit non-Abelian statistics, which makes it a candidate for fault-tolerant topological quantum computation. Although the non-Abelian Pfaffian state and its particle-hole conjugate, the anti-Pfaffian state, are the most plausible wave functions for the 5/2 state, there are a number of alternatives with either Abelian or non-Abelian statistics. Recent experiments suggest that the tunneling exponents are more consistent with an Abelian state rather than a non-Abelian state. Here, we present edge-current-tunneling experiments in geometrically confined quantum point contacts, which indicate that Abelian and non-Abelian states compete at filling factor 5/2. Our results are consistent with a transition from an Abelian state to a non-Abelian state in a single quantum point contact when the confinement is tuned. Our observation suggests that there is an intrinsic non-Abelian 5/2 ground state but that the appropriate confinement is necessary to maintain it. This observation is important not only for understanding the physics of the 5/2 state but also for the design of future topological quantum computation devices.

  12. Competing ν = 5/2 fractional quantum Hall states in confined geometry.

    Science.gov (United States)

    Fu, Hailong; Wang, Pengjie; Shan, Pujia; Xiong, Lin; Pfeiffer, Loren N; West, Ken; Kastner, Marc A; Lin, Xi

    2016-11-01

    Some theories predict that the filling factor 5/2 fractional quantum Hall state can exhibit non-Abelian statistics, which makes it a candidate for fault-tolerant topological quantum computation. Although the non-Abelian Pfaffian state and its particle-hole conjugate, the anti-Pfaffian state, are the most plausible wave functions for the 5/2 state, there are a number of alternatives with either Abelian or non-Abelian statistics. Recent experiments suggest that the tunneling exponents are more consistent with an Abelian state rather than a non-Abelian state. Here, we present edge-current-tunneling experiments in geometrically confined quantum point contacts, which indicate that Abelian and non-Abelian states compete at filling factor 5/2. Our results are consistent with a transition from an Abelian state to a non-Abelian state in a single quantum point contact when the confinement is tuned. Our observation suggests that there is an intrinsic non-Abelian 5/2 ground state but that the appropriate confinement is necessary to maintain it. This observation is important not only for understanding the physics of the 5/2 state but also for the design of future topological quantum computation devices.

  13. Design and Synthesis of Antiblinking and Antibleaching Quantum Dots in Multiple Colors via Wave Function Confinement.

    Science.gov (United States)

    Cao, Hujia; Ma, Junliang; Huang, Lin; Qin, Haiyan; Meng, Renyang; Li, Yang; Peng, Xiaogang

    2016-12-07

    Single-molecular spectroscopy reveals that photoluminescence (PL) of a single quantum dot blinks, randomly switching between bright and dim/dark states under constant photoexcitation, and quantum dots photobleach readily. These facts cast great doubts on potential applications of these promising emitters. After ∼20 years of efforts, synthesis of nonblinking quantum dots is still challenging, with nonblinking quantum dots only available in red-emitting window. Here we report synthesis of nonblinking quantum dots covering most part of the visible window using a new synthetic strategy, i.e., confining the excited-state wave functions of the core/shell quantum dots within the core quantum dot and its inner shells (≤ ∼5 monolayers). For the red-emitting ones, the new synthetic strategy yields nonblinking quantum dots with small sizes (∼8 nm in diameter) and improved nonblinking properties. These new nonblinking quantum dots are found to be antibleaching. Results further imply that the PL blinking and photobleaching of quantum dots are likely related to each other.

  14. Optical absorption, photoluminescence and structural analysis of CdS quantum dots in weak confinement

    Science.gov (United States)

    Mishra, Rakesh K.; Vedeshwar, A. G.; Tandon, R. P.

    2014-02-01

    The diffusion-controlled growth of CdS quantum dots (QDs) dispersed in a silicate glass matrix was investigated. It was found that the size of CdS QDs can be controlled by either heat treatment at various temperatures for a fixed duration or varying times at a constant temperature. Pastel yellow colored glass samples were obtained due to the presence of CdS petite crystals. X-ray diffraction (XRD) was used for determining the average dot size which varied from 3.8 to 30 nm. The typical quantum confinement effect was clearly observed from the blue shift measured in the optical absorption edge with decreasing dot size in the absorption spectroscopy. The band gap of CdS QDs ranges from 2.41 to 2.82 eV. Measured photoluminescence (PL) at an excitation wavelength of 350 nm showed the red shift of emission wavelength with increasing thermal treatment time and temperature in agreement with the increasing dot sizes. The half-width of PL spectra seems to indicate qualitatively the size distribution of dots and is consistent with the treatment parameters.

  15. Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction

    Science.gov (United States)

    Lei, Fengcai; Liu, Wei; Sun, Yongfu; Xu, Jiaqi; Liu, Katong; Liang, Liang; Yao, Tao; Pan, Bicai; Wei, Shiqiang; Xie, Yi

    2016-01-01

    Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin–tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis. PMID:27585984

  16. Enhanced memory effect via quantum confinement in 16 nm InN nanoparticles embedded in ZnO charge trapping layer

    Energy Technology Data Exchange (ETDEWEB)

    El-Atab, Nazek; Nayfeh, Ammar [Institute Center for Microsystems-iMicro, Department of Electrical Engineering and Computer Science (EECS), Masdar Institute of Science and Technology, Abu Dhabi (United Arab Emirates); Cimen, Furkan [Department of Electrical and Electronics Engineering, Bilkent University, 06800 Ankara (Turkey); UNAM-National Nanotechnology Research Center, Bilkent University, 06800 Ankara (Turkey); Alkis, Sabri; Ortaç, Bülend [UNAM-National Nanotechnology Research Center, Bilkent University, 06800 Ankara (Turkey); Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara (Turkey); Alevli, Mustafa [Department of Physics, Marmara University, 34722 Istanbul (Turkey); Dietz, Nikolaus [Department of Physics, Georgia State University, Atlanta, Georgia 30303 (United States); Okyay, Ali K. [Department of Electrical and Electronics Engineering, Bilkent University, 06800 Ankara (Turkey); UNAM-National Nanotechnology Research Center, Bilkent University, 06800 Ankara (Turkey); Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara (Turkey)

    2014-06-23

    In this work, the fabrication of charge trapping memory cells with laser-synthesized indium-nitride nanoparticles (InN-NPs) embedded in ZnO charge trapping layer is demonstrated. Atomic layer deposited Al{sub 2}O{sub 3} layers are used as tunnel and blocking oxides. The gate contacts are sputtered using a shadow mask which eliminates the need for any lithography steps. High frequency C-V{sub gate} measurements show that a memory effect is observed, due to the charging of the InN-NPs. With a low operating voltage of 4 V, the memory shows a noticeable threshold voltage (V{sub t}) shift of 2 V, which indicates that InN-NPs act as charge trapping centers. Without InN-NPs, the observed memory hysteresis is negligible. At higher programming voltages of 10 V, a memory window of 5 V is achieved and the V{sub t} shift direction indicates that electrons tunnel from channel to charge storage layer.

  17. Casimir effects for classical and quantum liquids in slab geometry: A brief review

    Energy Technology Data Exchange (ETDEWEB)

    Biswas, Shyamal, E-mail: sbsp@uohyd.ac.in [School of Physics, University of Hyderabad, C.R. Rao Road, Gachibowli, Hyderabad-500046 (India)

    2015-05-15

    We analytically explore Casimir effects for confinement of classical and quantum fluctuations in slab (film) geometry (i) for classical (critical) fluctuations over {sup 4}He liquid around the λ point, and (ii) for quantum (phonon) fluctuations of Bogoliubov excitations over an interacting Bose-Einstein condensate. We also briefly review Casimir effects for confinement of quantum vacuum fluctuations confined to two plates of different geometries.

  18. 3D versus 1D quantum confinement in coherently strained CdS/ZnS quantum structures

    DEFF Research Database (Denmark)

    Woggon, U.; Gindele, F.; Petri, W.

    1998-01-01

    Monolayer fluctuations in ultrathin, coherently strained CdS/ZnS quantum structures result in a very strong localization of excitons. The deepest localized excitons can be considered as individual, decoupled and three-dimensionally confined. Consequently, fingerprints of zero-dimensionality are f......Monolayer fluctuations in ultrathin, coherently strained CdS/ZnS quantum structures result in a very strong localization of excitons. The deepest localized excitons can be considered as individual, decoupled and three-dimensionally confined. Consequently, fingerprints of zero......-dimensionality are found in the optical spectra like single, ultranarrow luminescence lines in micro-photoluminescence and spectrally broad optical gain in the deep blue spectral range. The exchange splitting is proven and a strong enhancement over the bulk value is observed....

  19. Photoinduced Single- and Multiple- Electron Dynamics Processes Enhanced by Quantum Confinement in Lead Halide Perovskite Quantum Dots.

    Science.gov (United States)

    Vogel, Dayton Jon; Kryjevski, Andrei; Inerbaev, Talgat M; Kilin, Dmitri S

    2017-03-21

    Methyl-ammonium lead iodide perovskite (MAPbI3) is a promising material for photovoltaic devices. A modification of the MAPbI3 into confined nanostructures is expected to further increase efficiency of solar energy conversion. Photo-excited dynamic processes in a MAPbI3 quantum dot (QD) have been modeled by many-body perturbation theory and nonadiabatic dynamics. A photoexcitation is followed by either exciton cooling (EC), its radiative (RR) or non-radiative recombination (NRR), or multi-exciton generation (MEG) processes. Computed times of these processes fall in the order of MEG < EC < RR < NRR, where MEG is in the order of a few femtoseconds, EC at the picosecond range while RR and NRR are in the order of nanoseconds. Computed timescales indicate which electronic transition pathways can contribute to increase in charge collection efficiency. Simulated mechanism relaxation rates show that quantum confinement promotes MEG in MAPbI3 QDs.

  20. Engineering the hole confinement for CdTe-based quantum dot molecules

    Science.gov (United States)

    Kłopotowski, Ł.; Wojnar, P.; Kret, S.; Parlińska-Wojtan, M.; Fronc, K.; Wojtowicz, T.; Karczewski, G.

    2015-06-01

    We demonstrate an efficient method to engineer the quantum confinement in a system of two quantum dots grown in a vertical stack. We achieve this by using materials with a different lattice constant for the growth of the outer and inner barriers. We monitor the resulting dot morphology with transmission electron microscopy studies and correlate the results with ensemble quantum dot photoluminescence. Furthermore, we embed the double quantum dots into diode structures and study photoluminescence as a function of bias voltage. We show that in properly engineered structures, it is possible to achieve a resonance of the hole states by tuning the energy levels with electric field. At the resonance, we observe signatures of a formation of a molecular state, hybridized over the two dots.

  1. Engineering the hole confinement for CdTe-based quantum dot molecules

    Energy Technology Data Exchange (ETDEWEB)

    Kłopotowski, Ł., E-mail: lukasz.klopotowski@ifpan.edu.pl; Wojnar, P.; Kret, S.; Fronc, K.; Wojtowicz, T.; Karczewski, G. [Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warsaw (Poland); Parlińska-Wojtan, M. [Facility for Electron Microscopy and Sample Preparation, Center for Microelectronics and Nanotechnology, Faculty of Mathematics and Natural Sciences, University of Rzeszów, ul. Pigonia 1, 35-959 Rzeszów (Poland)

    2015-06-14

    We demonstrate an efficient method to engineer the quantum confinement in a system of two quantum dots grown in a vertical stack. We achieve this by using materials with a different lattice constant for the growth of the outer and inner barriers. We monitor the resulting dot morphology with transmission electron microscopy studies and correlate the results with ensemble quantum dot photoluminescence. Furthermore, we embed the double quantum dots into diode structures and study photoluminescence as a function of bias voltage. We show that in properly engineered structures, it is possible to achieve a resonance of the hole states by tuning the energy levels with electric field. At the resonance, we observe signatures of a formation of a molecular state, hybridized over the two dots.

  2. Effects of confinement in meso-porous silica and carbon nano-structures; Etude des effets de confinement dans la silice mesoporeuse et dans certaines nanostructures carbonees

    Energy Technology Data Exchange (ETDEWEB)

    Leon, V

    2006-07-15

    Physico-chemical properties of materials can be strongly modified by confinement because of the quantum effects that appear at such small length scales and also because of the effects of the confinement itself. The aim of this thesis is to show that both the nature of the confining material and the size of the pores and cavities have a strong impact on the confined material. We first show the effect of the pore size of the host meso-porous silica on the temperature of the solid-solid phase transition of silver selenide, a semiconducting material with enhanced magnetoresistive properties under non-stoichiometric conditions. Narrowing the pores from 20 nm to 2 nm raises the phase transition temperature from 139 C to 146 C. This result can be explained by considering the interaction between the confining and confined materials as a driving force. The effects of confinement are also studied in the case of hydrogen and deuterium inside cavities of organized carbon nano-structures. The effects that appear in the adsorption/desorption cycles are much stronger with carbon nano-horns as the host material than with C60 pea-pods and single-walled carbon nano-tubes. (author)

  3. Dynamical Mass Generation and Confinement in Maxwell-Chern-Simons Planar Quantum Electrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez Madrigal, S; Raya, A [Instituto de Fisica y Matematicas, Universidad Michoacana de San Nicolas de Hidalgo, Edificio C-3, Ciudad Universitaria, Morelia, Michoacan 58040 (Mexico); Hofmann, C P, E-mail: saul@ifm.umicri.mx, E-mail: christoph@ucol.mx, E-mail: raya@ifm.umich.mx [Facultad de Ciencias, Universidad de Colima, Bernal Diaz del Castillo 340, Colima, Colima 28045 (Mexico)

    2011-04-01

    We study the non-perturbative phenomena of Dynamical Mass Generation and Confinement by truncating at the non-perturbative level the Schwinger-Dyson equations in Maxwell-Chern-Simons planar quantum electrodynamics. We obtain numerical solutions for the fermion propagator in Landau gauge within the so-called rainbow approximation. A comparison with the ordinary theory without the Chern-Simons term is presented.

  4. Quantum-Mechanical Particle Confined to Surfaces of Revolution - Truncated Cone and Elliptic Torus Case Studies

    DEFF Research Database (Denmark)

    Gravesen, Jens; Willatzen, Morten; Voon, L.C. Lew Yan

    2005-01-01

    The theory of a quantum-mechanical particle confined to a surface of revolution is described using differential geometry methods including the derivation of a general set of three ordinary differential equations in curved coordinates. The problem is shown to be completely separable with the prese...... hard-wall boundary conditions. Two case studies of recent experimental interest. the nanocone and torus-shaped nanoring structures. are analyzed in terms of eigenstates, energies. and symmetry characteristics based on the theory presented....

  5. Bandgap and Carrier Transport Engineering of Quantum Confined Mixed Phase Nanocrystalline/Amorphous Silicon

    Energy Technology Data Exchange (ETDEWEB)

    Guan, Tianyuan; Klafehn, Grant; Kendrick, Chito; Theingi, San; Airuoyo, Idemudia; Lusk, Mark T.; Stradins, Paul; Taylor, Craig; Collins, Reuben T.

    2016-11-21

    Mixed phase nanocrystalline/amorphous-silicon (nc/a-Si:H) thin films with band-gap higher than bulk silicon are prepared by depositing silicon nanoparticles (SiNPs), prepared in a separate deposition zone, and hydrogenated amorphous silicon (a-Si:H), simultaneously. Since the two deposition phases are well decoupled, optimized parameters for each component can apply to the growth process. Photoluminescence spectroscopy (PL) shows that the embedded SiNPs are small enough to exhibit quantum confinement effects. The low temperature PL measurements on the mixed phase reveal a dominant emission feature, which is associated with SiNPs surrounded by a-Si:H. In addition, we compare time dependent low temperature PL measurements for both a-Si:H and mixed phase material under intensive laser exposure for various times up to two hours. The PL intensity of a-Si:H with embedded SiNPs degrades much less than that of pure a-Si:H. We propose this improvement of photostability occurs because carriers generated in the a-Si:H matrix quickly transfer into SiNPs and recombine there instead of recombining in a-Si:H and creating defect states (Staebler-Wronski Effect).

  6. Quantum Cosmology: Effective Theory

    CERN Document Server

    Bojowald, Martin

    2012-01-01

    Quantum cosmology has traditionally been studied at the level of symmetry-reduced minisuperspace models, analyzing the behavior of wave functions. However, in the absence of a complete full setting of quantum gravity and detailed knowledge of specific properties of quantum states, it remained difficult to make testable predictions. For quantum cosmology to be part of empirical science, it must allow for a systematic framework in which corrections to well-tested classical equations can be derived, with any ambiguities and ignorance sufficiently parameterized. As in particle and condensed-matter physics, a successful viewpoint is one of effective theories, adapted to specific issues one encounters in quantum cosmology. This review presents such an effective framework of quantum cosmology, taking into account, among other things, space-time structures, covariance, the problem of time and the anomaly issue.

  7. Field enhancement at metallic interfaces due to quantum confinement

    DEFF Research Database (Denmark)

    Öztürk, Fatih; Xiao, Sanshui; Yan, Min;

    2011-01-01

    on which the dielectric function vanishes. This, in turn, leads to an enhancement of the normal component of the total electric field. We study this effect for a planar metal surface, with the inhomogeneous electron density accounted for by a Jellium model. We also illustrate the effect for equilateral...... triangular nanoislands via numerical solutions of the appropriate Maxwell equations, and show that the field enhancement is several orders of magnitude larger than what the conventional theory predicts. (C) 2011 Society of Photo-Optical Instrumentation Engineers (SPIE). [DOI: 10.1117/1.3574159]...

  8. The Effect of Confined Hindrance in Polyphenylbenzenes.

    Science.gov (United States)

    Lima, Carlos F R A C; Rodrigues, Ana S M C; Santos, Luis M N B F

    2017-03-07

    A comprehensive thermodynamic study of the whole ortho-polyphenylbenzenes series, from biphenyl (n=1) to hexaphenylbenzene (n=6), is presented. Combustion calorimetry and phase equilibria measurements for 1,2,3,4-tetraphenylbenzene (n=4) and pentaphenylbenzene (n=5), together with literature data, were used to understand and quantify the constraint effect of ortho- substitution on the molecular energetics and phase stability of polyaromatic compounds. All the derived thermodynamic properties (enthalpy of sublimation, entropy of sublimation, and gas phase molecular energetics) show a marked trend shift at n=4 to n=5, which is related with the change of the degree of molecular flexibility after 1,2,3,4-tetraphenylbenzene (n=4). The greater intramolecular constraint in the more crowded members of the series (n=5 and n=6) leads to a significant change in the molecular properties and cohesive energy. The trend shift in the molecular properties is related with the decrease of molecular flexibility, which leads to lower molecular entropy and destabilization of the intramolecular interaction potential due to the increased hindrance in a confined molecular space.

  9. Strong coupling of two interacting excitons confined in a nanocavity-quantum dot system

    Energy Technology Data Exchange (ETDEWEB)

    Cardenas, Paulo C; RodrIguez, Boris A [Instituto de Fisica, Universidad de Antioquia, AA 1226 MedellIn (Colombia); Quesada, Nicolas [McLennan Physical Laboratories, University of Toronto, 60 St George Street, Toronto, ON, M5S 1A7 (Canada); Vinck-Posada, Herbert, E-mail: pcardenas@fisica.udea.edu.co [Departamento de Fisica, Universidad Nacional de Colombia, Ciudad Universitaria, Bogota (Colombia)

    2011-07-06

    We present a study of the strong coupling between radiation and matter, considering a system of two quantum dots, which are in mutual interaction and interact with a single mode of light confined in a semiconductor nanocavity. We take into account dissipative mechanisms such as the escape of the cavity photons, decay of the quantum dot excitons by spontaneous emission, and independent exciton pumping. It is shown that the mutual interaction between the dots can be measured off-resonance only if the strong coupling condition is reached. Using the quantum regression theorem, a reasonable definition of the dynamical coupling regimes is introduced in terms of the complex Rabi frequency. Finally, the emission spectrum for relevant conditions is presented and compared with the above definition, demonstrating that the interaction between the excitons does not affect the strong coupling.

  10. Classical And Quantum Chaos: Strongly Interacting Particles In A Confined Geometry

    CERN Document Server

    Ivanushkin, P S

    2003-01-01

    This dissertation details the classical and quantum dynamics of two mechanical systems. The first one represents a charged particle confined inside a square elastic boundary acted on by a uniform magnetic field—the Square Magnetic Billiard. The second system, called the Circular Coulomb Billiard, consists of two particles, interacting by virtue of the Coulomb potential, and enclosed inside a circular boundary. One of the particles is considered to be massive and remains stationary. The first two chapters give a brief history of classical and quantum chaos, and review the major theoretical concepts. The third chapter analyzes the classical dynamics of the Square Magnetic Billiard. A number of approaches were used for numerical experiments: which shows that the system's classical behavior ranges from completely integrable to fully chaotic, but then the system restores it's integrability as the magnetic field continues to grow. The fourth chapter examines the Square Magnetic Billiard quantum mechanical...

  11. Quantum confinement induced band gaps in MgB2 nanosheets

    Science.gov (United States)

    Xu, Bo Z.; Beckman, Scott P.

    2016-09-01

    The discovery of two-dimensional semiconducting materials, a decade ago, spawned an entire sub-field within solid-state physics that is focused on the development of nanoelectronics. Here we present a new class of semiconducting two-dimensional material based on hexagonal MgB2. Although MgB2 is a semimetal, similar to the other well-studied transition metal diborides, we demonstrate that, unlike the transition metal diborides, thinning MgB2, to create nanosheets, opens a band gap in the density of states. We predict that a 7 Å thick MgB2 nanosheet will have a band gap of 0.51 eV. MgB2 nanosheets differ from other two-dimensional semiconductors in that the band gap is introduced by (001) surfaces and is opened by the quantum confinement effect. The implications of these findings are that nanostructured MgB2 is not merely a new composition, but also has intrinsic mechanisms for tuning its electronic properties, which may facilitate the development of nanoelectronics.

  12. Optical response of confined excitons in GaInAsSb/GaSb Quantum Dots heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Cano, R [Departamento de Fisica, Universidad Autonoma de Occidente, A.A. 2790, Cali (Colombia); Tirado-Mejia, L; Fonthal, G; Ariza-Calderon, H [Laboratorio de Optoelectronica, Universidad del Quindio, A.A. 4603 Armenia (Colombia); Porras-Montenegro, N, E-mail: rsanchez40@gmail.co [Departamento de Fisica, Universidad del Valle, A.A. 25360, Cali (Colombia)

    2009-05-01

    The narrow-gap Ga{sub 1-x}In{sub x}As{sub y}Sb{sub 1-y} compounds are suitable materials for heterostructure devices operating in the infrared wavelength range. In these compounds grown by liquid phase epitaxy over GaSb single crystals, for x and y values in the range of 0.10 to 0.14 for both variables, the photoluminescence optical response at 12K is blue-shifted by 20 meV related to the photoreflectance response. We believe this behavior is due to possible higher electronic confinement in some places of the heterostructure, possibly formed in the interface during the growth process. In order to explain this behavior, in this work we study the exciton recombination energy in spherical Quantum Dots (QDs) on Ga{sub 1-x}In{sub x}As{sub y}Sb{sub 1-y}/GaSb, using the variational procedure within the effective-mass approximation and considering an electron in a Type I band alignment formed by two semiconductors with similar parabolic conduction bands. Our results are in good agreement with recent experimental results.

  13. Investigation of quantum confinement within the tunneling-percolation transition for ultrathin bismuth films

    Energy Technology Data Exchange (ETDEWEB)

    Oller, Declan, E-mail: declan_oller@brown.edu; Fernandes, Gustavo E.; Kim, Jin Ho; Xu, Jimmy

    2015-10-15

    We investigate conduction phenomena in ultrathin bismuth (Bi) films that are thermally evaporated onto flat quartz. Critical points in the conductance as a function of deposition time are identified and used to scale the data from time dependence to coverage dependence. The resulting nonlinear coverage scaling equation is verified independently via analysis done on transmission electron microscope images of the evaporated films. The scaled data yields critical exponents in very good agreement with classical percolation theory, and clearly shows the transition from the tunneling regime into percolation. Surprisingly, no noticeable signatures of size-quantization effects in the nucleation sites as a function of deposition time is observed in either regime. We discuss our findings in light of Boltzmann transport modeling of 1D conduction as an approximation to the narrow percolative paths that form at the onset of percolation. Our results suggest that lack of a preferred crystallite orientation in the nucleation process may indeed cause quantum-confinement to be too smeared out to be observable in the tunneling to percolation transition.

  14. Quantum confinement, carrier dynamics and interfacial processes in nanostructured direct/indirect-gap semiconductor-glass composites

    Energy Technology Data Exchange (ETDEWEB)

    Joseph H. Simmons

    2002-08-13

    The behavior of semiconductor clusters precipitated in an insulated matrix was investigated. Semiconductor compositions of CdTe, Si and Ge were studies and the insulating matrix was amorphous SiO2. As a function of size, quantum confinement effects were observed in all three composite systems. However significant differences were observed between the direct-gap column 2-6 semiconductors and the indirect-gap column 4 semiconductors. As observed by others, the direct-gap 2-6 semiconductors showed a distinct saturation in the energy-gap blue shift with decreasing size. Theoretical studies using a 20-band k dot p calculation of the electronic and valence bands for a 3-dimensionally confined CdTe semiconductor showed that mixing of the conduction band states leads to a flattening of the central valley. This increases the electron mass drastically and saturates the size dependent blue shift in the bandgap. In contrast, the blue shift in the Si and Ge nanocrystals showed no sign of saturation and increased drastically with decreasing size. In fact, Si and Ge crystals were formed with blue shift values that moved the bandgap to the near UV region. We examined the absorption curves to determine whether the bandgap was direct or indirect in the quantum dots. The results are that the absorption shows an indirect gap for all but the smallest Si crystals and an indirect gap for all Ge crystals. Raman studies showed negligible size dependence due to a lack of phonon confinement in the matrix embedded clusters. Exciton saturation and recovery times were found to be very short (of the order of 400fs) and are the fastest reported for any quantum dot system. Work to examine the type of confinement obtained in a matrix that consists of a transparent conductor is under way. Studies of the photoinduced absorption change in GeSe glasses showed a significant effect of photodarkening, regardless of composition. The photodarkening effect appears to be composed of permanent and transient

  15. Improved energy confinement with nonlinear isotope effects in magnetically confined plasmas

    CERN Document Server

    Garcia, J; Jenko, F

    2016-01-01

    The efficient production of electricity from nuclear fusion in magnetically confined plasmas relies on a good confinement of the thermal energy. For more than thirty years, the observation that such confinement depends on the mass of the plasma isotope and its interaction with apparently unrelated plasma conditions has remained largely unexplained and it has become one of the main unsolved issues. By means of numerical studies based on the gyrokinetic theory, we quantitatively show how the plasma microturbulence depends on the isotope mass through nonlinear multiscale microturbulence effects involving the interplay between zonal flows, electromagnetic effects and the torque applied. This finding has crucial consequences for the design of future reactors since, in spite of the fact that they will be composed by multiple ion species, their extrapolation from present day experiments heavily relies on the knowledge obtained from a long experimental tradition based in single isotope plasmas.

  16. Electrostatically Confined Monolayer Graphene Quantum Dots with Orbital and Valley Splittings.

    Science.gov (United States)

    Freitag, Nils M; Chizhova, Larisa A; Nemes-Incze, Peter; Woods, Colin R; Gorbachev, Roman V; Cao, Yang; Geim, Andre K; Novoselov, Kostya S; Burgdörfer, Joachim; Libisch, Florian; Morgenstern, Markus

    2016-09-14

    The electrostatic confinement of massless charge carriers is hampered by Klein tunneling. Circumventing this problem in graphene mainly relies on carving out nanostructures or applying electric displacement fields to open a band gap in bilayer graphene. So far, these approaches suffer from edge disorder or insufficiently controlled localization of electrons. Here we realize an alternative strategy in monolayer graphene, by combining a homogeneous magnetic field and electrostatic confinement. Using the tip of a scanning tunneling microscope, we induce a confining potential in the Landau gaps of bulk graphene without the need for physical edges. Gating the localized states toward the Fermi energy leads to regular charging sequences with more than 40 Coulomb peaks exhibiting typical addition energies of 7-20 meV. Orbital splittings of 4-10 meV and a valley splitting of about 3 meV for the first orbital state can be deduced. These experimental observations are quantitatively reproduced by tight binding calculations, which include the interactions of the graphene with the aligned hexagonal boron nitride substrate. The demonstrated confinement approach appears suitable to create quantum dots with well-defined wave function properties beyond the reach of traditional techniques.

  17. Effects of Confinement on Conventional Spin Problems

    DEFF Research Database (Denmark)

    Marchukov, Oleksandr

    2015-01-01

    In recent years quantum simulations in cold-atom set-ups has attracted a lot of interest both from experimental and theoretical research groups around the world. Unprecedented level of control over physical systems allowed one to investigate rather peculiar models, such as artificial gauge fields...... to the quantum signa- tures of chaos are discussed. The second part of the dissertation is concerned with quantum state transfer in one-dimensional spin chains. The properties required to achieve conditional state transfer, i.e. “allowing” or “blocking” of state transfer depending on the parameters of the spin...... chain, are discussed....

  18. Theory of the vortex-clustering transition in a confined two-dimensional quantum fluid

    CERN Document Server

    Yu, Xiaoquan; Nian, Jun; Reeves, Matthew T; Bradley, Ashton S

    2016-01-01

    Clustering of like-sign vortices in a planar bounded domain is known to occur at negative temperature, a phenomenon that Onsager demonstrated to be a consequence of bounded phase space. In a confined superfluid, quantized vortices can support such an ordered phase, provided they evolve as an almost isolated subsystem containing sufficient energy. A detailed theoretical understanding of the statistical mechanics of such states thus requires a microcanonical approach. Here we develop an analytical theory of the vortex clustering transition in a neutral system of quantum vortices confined to a two-dimensional disk geometry, within the microcanonical ensemble. As the system energy increases above a critical value, the system develops global order via the emergence of a macroscopic dipole structure from the homogeneous phase of vortices, spontaneously breaking the Z2 symmetry associated with invariance under vortex circulation exchange, and the rotational SO(2) symmetry due to the disk geometry. The dipole structu...

  19. Quantum Effects in Biology

    Science.gov (United States)

    Mohseni, Masoud; Omar, Yasser; Engel, Gregory S.; Plenio, Martin B.

    2014-08-01

    List of contributors; Preface; Part I. Introduction: 1. Quantum biology: introduction Graham R. Fleming and Gregory D. Scholes; 2. Open quantum system approaches to biological systems Alireza Shabani, Masoud Mohseni, Seogjoo Jang, Akihito Ishizaki, Martin Plenio, Patrick Rebentrost, Alàn Aspuru-Guzik, Jianshu Cao, Seth Lloyd and Robert Silbey; 3. Generalized Förster resonance energy transfer Seogjoo Jang, Hoda Hossein-Nejad and Gregory D. Scholes; 4. Multidimensional electronic spectroscopy Tomáš Mančal; Part II. Quantum Effects in Bacterial Photosynthetic Energy Transfer: 5. Structure, function, and quantum dynamics of pigment protein complexes Ioan Kosztin and Klaus Schulten; 6. Direct observation of quantum coherence Gregory S. Engel; 7. Environment-assisted quantum transport Masoud Mohseni, Alàn Aspuru-Guzik, Patrick Rebentrost, Alireza Shabani, Seth Lloyd, Susana F. Huelga and Martin B. Plenio; Part III. Quantum Effects in Higher Organisms and Applications: 8. Excitation energy transfer in higher plants Elisabet Romero, Vladimir I. Novoderezhkin and Rienk van Grondelle; 9. Electron transfer in proteins Spiros S. Skourtis; 10. A chemical compass for bird navigation Ilia A. Solov'yov, Thorsten Ritz, Klaus Schulten and Peter J. Hore; 11. Quantum biology of retinal Klaus Schulten and Shigehiko Hayashi; 12. Quantum vibrational effects on sense of smell A. M. Stoneham, L. Turin, J. C. Brookes and A. P. Horsfield; 13. A perspective on possible manifestations of entanglement in biological systems Hans J. Briegel and Sandu Popescu; 14. Design and applications of bio-inspired quantum materials Mohan Sarovar, Dörthe M. Eisele and K. Birgitta Whaley; 15. Coherent excitons in carbon nanotubes Leonas Valkunas and Darius Abramavicius; Glossary; References; Index.

  20. Quantum confinement in MOVPE-grown structures with self-assembled InAs/GaAs quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Kuldova, K; Vyborny, Z; Pangrac, J; Oswald, J [Institute of Physics of the AS CR, v. v. i., Cukrovarnicka 10, CZ-162 00 Praha 6 (Czech Republic); Molas, M; Borysiuk, J; Babinski, A, E-mail: kuldova@fzu.c [Institute of Experimental Physics, University of Warsaw, Ho z-dot a 69, PL-00-681 Warszawa (Poland)

    2010-09-01

    In this communication we report on low-temperature, micro-photoluminescence study of quantum confinement in MOVPE-grown structures with InAs/GaAs quantum dots (QDs) with GaAs and/or strain reducing InGaAs/GaAs capping. We focus our attention on sharp emission lines, which appear in both structures at energies up to 80 meV below the wetting line emission. Power-dependent measurements confirmed their attribution to single excitons as well as biexcitons. Negative binding energy of biexcitons with systematic dependence on their energy was observed. It has been proposed that the investigated emission lines result from radiative recombination in flat non-fully developed QDs in the investigated structure. The attribution is confirmed by transmission electron microscopic analysis of investigated structures.

  1. Effect of Rashba spin-orbit coupling on the electronic, thermodynamic, magnetic and transport properties of GaAs, InAs and InSb quantum dots with Gaussian confinement

    Science.gov (United States)

    Boda, Aalu; Boyacioglu, Bahadir; Erkaslan, Ugur; Chatterjee, Ashok

    2016-10-01

    The effect of Rashba spin-orbit interaction on the electronic, thermodynamic, magnetic and transport properties of a one-electron Gaussian quantum dot is investigated in the presence of a magnetic field and its interaction with the electron spin using the canonical ensemble approach. The temperature-dependent energy, magnetization, susceptibility, specific heat and the persistent current are calculated as a function of the spin-orbit coupling parameter. The results are applied to GaAs, InAs and InSb quantum dots.

  2. Effect of Rashba spin–orbit coupling on the electronic, thermodynamic, magnetic and transport properties of GaAs, InAs and InSb quantum dots with Gaussian confinement

    Energy Technology Data Exchange (ETDEWEB)

    Boda, Aalu [School of Physics, University of Hyderabad, Hyderabad 500046 (India); Boyacioglu, Bahadir [Vocational School of Health Services, University of Ankara, 06290 Ankara (Turkey); Erkaslan, Ugur [Department of Physics, Faculty of Science, Mugla Sitki Kocman University, 48170 Kotekli-Mugla (Turkey); Chatterjee, Ashok, E-mail: acsp@uohyd.ernet.in [School of Physics, University of Hyderabad, Hyderabad 500046 (India)

    2016-10-01

    The effect of Rashba spin–orbit interaction on the electronic, thermodynamic, magnetic and transport properties of a one-electron Gaussian quantum dot is investigated in the presence of a magnetic field and its interaction with the electron spin using the canonical ensemble approach. The temperature-dependent energy, magnetization, susceptibility, specific heat and the persistent current are calculated as a function of the spin–orbit coupling parameter. The results are applied to GaAs, InAs and InSb quantum dots.

  3. Quantum Spin Hall Effect

    Energy Technology Data Exchange (ETDEWEB)

    Bernevig, B.Andrei; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

    2010-01-15

    The quantum Hall liquid is a novel state of matter with profound emergent properties such as fractional charge and statistics. Existence of the quantum Hall effect requires breaking of the time reversal symmetry caused by an external magnetic field. In this work, we predict a quantized spin Hall effect in the absence of any magnetic field, where the intrinsic spin Hall conductance is quantized in units of 2 e/4{pi}. The degenerate quantum Landau levels are created by the spin-orbit coupling in conventional semiconductors in the presence of a strain gradient. This new state of matter has many profound correlated properties described by a topological field theory.

  4. Quantum-Carnot engine for particle confined to 2D symmetric potential well

    Science.gov (United States)

    Belfaqih, Idrus Husin; Sutantyo, Trengginas Eka Putra; Prayitno, T. B.; Sulaksono, Anto

    2015-09-01

    Carnot model of heat engine is the most efficient cycle consisting of isothermal and adiabatic processes which are reversible. Although ideal gas usually used as a working fluid in the Carnot engine, Bender used quantum particle confined in 1D potential well as a working fluid. In this paper, by following Bender we generalize the situation to 2D symmetric potential well. The efficiency is express as the ratio of the initial length of the system to the final length of the compressed system. The result then is shown that for the same ratio, 2D potential well is more efficient than 1D potential well.

  5. Quantum-Carnot engine for particle confined to 2D symmetric potential well

    Energy Technology Data Exchange (ETDEWEB)

    Belfaqih, Idrus Husin, E-mail: idrushusin21@gmail.com; Sutantyo, Trengginas Eka Putra, E-mail: trengginas.eka@gmail.com; Prayitno, T. B., E-mail: teguh-budi@unj.ac.id [Department of Physics, Universitas Negeri Jakarta, Jl. Pemuda Rawamangun, Jakarta Timur, 13220 (Indonesia); Sulaksono, Anto, E-mail: anto.sulaksono@sci.ui.ac.id [Department of Physics, Universitas Indonesia, Depok, Jawa Barat, 164242 (Indonesia)

    2015-09-30

    Carnot model of heat engine is the most efficient cycle consisting of isothermal and adiabatic processes which are reversible. Although ideal gas usually used as a working fluid in the Carnot engine, Bender used quantum particle confined in 1D potential well as a working fluid. In this paper, by following Bender we generalize the situation to 2D symmetric potential well. The efficiency is express as the ratio of the initial length of the system to the final length of the compressed system. The result then is shown that for the same ratio, 2D potential well is more efficient than 1D potential well.

  6. Role of quantum heat bath and confinement in the low-temperature thermodynamics of cyclotron motion.

    Science.gov (United States)

    Bandyopadhyay, Malay; Dattagupta, Sushanta

    2010-04-01

    In this Brief Report we show how the low-temperature thermodynamics of the dissipative motion of an electron in a magnetic field is sensitive to the nature of the spectral density function, J(omega), of the quantum heat bath. In all cases of couplings considered here the free energy and the entropy of the cyclotron motion of the electron fall off to zero as power law in conformity with the third law of thermodynamics. The power of the power law however depends on the nature of J(omega). We also separately discuss the influence of confinement.

  7. Confluent hypergeometric orthogonal polynomials related to the rational quantum Calogero system with harmonic confinement

    CERN Document Server

    Van Diejen, J F

    1997-01-01

    Two families (type $A$ and type $B$) of confluent hypergeometric polynomials in several variables are studied. We describe the orthogonality properties, differential equations, and Pieri type recurrence formulas for these families. In the one-variable case, the polynomials in question reduce to the Hermite polynomials (type $A$) and the Laguerre polynomials (type $B$), respectively. The multivariable confluent hypergeometric families considered here may be used to diagonalize the rational quantum Calogero models with harmonic confinement (for the classical root systems) and are closely connected to the (symmetric) generalized spherical harmonics investigated by Dunkl.

  8. Investigation of the confinement potential within GaNAs/GaAs multiple quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Goshima, Keishiro; Kittaka, Akinobu; Fujii, Kensuke; Shiraga, Masahiro; Tsurumachi, Noriaki; Nakanishi, Shunsuke; Koshiba, Shyun; Itoh, Hiroshi [Engineering, Kagawa University, 2217-20, Takamatsu, Kagawa 761-0396 (Japan); Akiyama, Hidefumi [Institute of Solid State Physics, University of Tokyo, Chiba 277-8581 (Japan)

    2011-02-15

    We conducted a detailed investigation of the potential structure within GaNAs/GaAs multiple quantum wells (MQWs) using three independent experimental techniques: the temperature dependence of Photo-luminescence (PL) spectroscopy, time-resolved PL spectroscopy, and degenerate four-wave mixing (DFWM) measurements. We observed a very long lifetime (T{sub 1} = 12 ns) and dephasing time (T{sub 2} = 130 ps) of excitons in the GaNAs/GaAs MQWs. We suggested that the GaNAs/GaAs MQWs have a strong and deep confinement structure that is comparable to that of quantum dots (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  9. Light-Front Holography and Superconformal Quantum Mechanics: A New Approach to Hadron Structure and Color Confinement

    CERN Document Server

    Brodsky, S J; de Teramond, G F; Dosch, H G

    2015-01-01

    A primary question in hadron physics is how the mass scale for hadrons consisting of light quarks, such as the proton, emerges from the QCD Lagrangian even in the limit of zero quark mass. If one requires the effective action which underlies the QCD Lagrangian to remain conformally invariant and extends the formalism of de Alfaro, Fubini and Furlan to light-front Hamiltonian theory, then a unique, color-confining potential with a mass parameter $\\kappa$ emerges. The actual value of the parameter $\\kappa$ is not set by the model - only ratios of hadron masses and other hadronic mass scales are predicted. The result is a nonperturbative, relativistic light-front quantum mechanical wave equation, the Light-Front Schr\\"odinger Equation which incorporates color confinement and other essential spectroscopic and dynamical features of hadron physics, including a massless pion for zero quark mass and linear Regge trajectories with the identical slope in the radial quantum number $n$ and orbital angular momentum $L$. T...

  10. Spontaneous Coherence Effects in Quantum Dots and Quantum Wells Placed in Microcavities

    Directory of Open Access Journals (Sweden)

    Kaputkina N.E.

    2016-01-01

    Full Text Available The Bose-Einstein condensation temperature Tc for a system of coupled quantum dots in a microcavity was estimated in function of the confining potential steepness, the external magnetic field strength, and the barrier layer width for indirect excitons. The effect of the magnetic field on Tc was found to be nonmonotonic over a certain range of the control parameters. The reason is the presence of two competing mechanisms accompanying the increase of the magnetic field: (a increase of the magnetoexciton effective mass and (b increase of the effective confining potential steepness for quantum dots.

  11. Effectively Emergent Quantum Mechanics

    CERN Document Server

    Exirifard, Qasem

    2008-01-01

    We consider non minimal coupling between matters and gravity in modified theories of gravity. In contrary to the current common sense, we report that quantum mechanics can effectively emerge when the space-time geometry is sufficiently flat. In other words, quantum mechanics might play no role when and where the space-time geometry is highly curved. We study the first two simple models of Effectively Emergent Quantum Mechanics(EEQM): R-dependent EEQM and G-dependent EEQM where R is the Ricci scalar and G is the Gauss-Bonnet Lagrangian density. We discuss that these EEQM theories might be fine tuned to remain consistent with all the implemented experiments and performed observations. In particular, we observe that G-dependent EEQM softens the problem of quantum gravity.

  12. Ion-mediated RNA structural collapse: effect of spatial confinement

    CERN Document Server

    Tan, Zhi-Jie

    2013-01-01

    RNAs are negatively charged molecules residing in macromolecular crowding cellular environments. Macromolecular confinement can influence the ion effects in RNA folding. In this work, using the recently developed tightly bound ion model for ion fluctuation and correlation, we investigate the confinement effect on the ion-mediated RNA structural collapse for a simple model system. We found that, for both Na$^+$ and Mg$^{2+}$, ion efficiencies in mediating structural collapse/folding are significantly enhanced by the structural confinement. Such an enhancement in the ion efficiency is attributed to the decreased electrostatic free energy difference between the compact conformation ensemble and the (restricted) extended conformation ensemble due to the spatial restriction.

  13. The pinning effect in quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Monisha, P. J., E-mail: pjmonisha@gmail.com [School of Physics, University of Hyderabad, Hyderabad-500046 (India); Mukhopadhyay, Soma [Department of Physics, D V R College of Engineering and Technology, Hyderabad-502285 (India)

    2014-04-24

    The pinning effect is studied in a Gaussian quantum dot using the improved Wigner-Brillouin perturbation theory (IWBPT) in the presence of electron-phonon interaction. The electron ground state plus one phonon state is degenerate with the electron in the first excited state. The electron-phonon interaction lifts the degeneracy and the first excited states get pinned to the ground state plus one phonon state as we increase the confinement frequency.

  14. Effectively calculable quantum mechanics

    OpenAIRE

    Bolotin, Arkady

    2015-01-01

    According to mathematical constructivism, a mathematical object can exist only if there is a way to compute (or "construct") it; so, what is non-computable is non-constructive. In the example of the quantum model, whose Fock states are associated with Fibonacci numbers, this paper shows that the mathematical formalism of quantum mechanics is non-constructive since it permits an undecidable (or effectively impossible) subset of Hilbert space. On the other hand, as it is argued in the paper, if...

  15. Quantum mechanical effects analysis of nanostructured solar cell models

    Directory of Open Access Journals (Sweden)

    Badea Andrei

    2016-01-01

    Full Text Available The quantum mechanical effects resulted from the inclusion of nanostructures, represented by quantum wells and quantum dots, in the i-layer of an intermediate band solar cell will be analyzed. We will discuss the role of these specific nanostructures in the increasing of the solar cells efficiency. InAs quantum wells being placed in the i-layer of a gallium arsenide (GaAs p-i-n cell, we will analyze the quantum confined regions and determine the properties of the eigenstates located therein. Also, we simulate the electroluminescence that occurs due to the nanostructured regions.

  16. Boundary Effects in Quantum Physics

    CERN Document Server

    Asorey, M

    2013-01-01

    We analyze the role of boundaries in the infrared behavior of quantum field theories. By means of a novel method we calculate the vacuum energy for a massless scalar field confined between two homogeneous parallel plates with the most general type of boundary properties. This allows the discrimination between boundary conditions which generate attractive or repulsive Casimir forces between the plates. In the interface between both regimes we find a very interesting family of boundary conditions which do not induce any type of Casimir force. We analyze the effect of the renormalization group flow on these boundary conditions. Even if the Casimirless conformal invariant conditions are physically unstable under renormalization group flow they emerge as a new set of conformally invariant boundary conditions which are anomaly free.

  17. 5 CFR 890.605 - Persons confined on effective date.

    Science.gov (United States)

    2010-01-01

    ... REGULATIONS (CONTINUED) FEDERAL EMPLOYEES HEALTH BENEFITS PROGRAM Transfers From Retired Federal Employees... persons who, on the effective date of an enrollment under § 890.602, are confined in a hospital or...

  18. The effect of confinement on water structure

    Energy Technology Data Exchange (ETDEWEB)

    Mancinelli, R, E-mail: mancinelli@fis.uniroma3.i [CNR Istituto Sistemi Complessi, via Madonna del Piano 10, I-50019 Sesto Fiorentino (Italy); Dipartimento di Fisica ' Amaldi' , University of Roma Tre, via della Vasca Navale 84, I-00146 Roma (Italy)

    2010-10-13

    Neutron diffraction experiments with hydrogen isotope substitution on water confined in MCM41-S15 have been performed at temperatures of 300 and 210 K. Data are analyzed at a microscopic level using a revised version of the empirical potential structure refinement technique. It is found that the influence of the substrate on the water structure is not negligible and depends on the temperature: owing to the geometrical constraints and the symmetry breaking induced by the wall, comparison with the corresponding bulk phases is not straightforward and standard analysis should be replaced by a more suitable one.

  19. Crystalline Confinement

    CERN Document Server

    Banerjee, D; Jiang, F -J; Wiese, U -J

    2013-01-01

    We show that exotic phases arise in generalized lattice gauge theories known as quantum link models in which classical gauge fields are replaced by quantum operators. While these quantum models with discrete variables have a finite-dimensional Hilbert space per link, the continuous gauge symmetry is still exact. An efficient cluster algorithm is used to study these exotic phases. The $(2+1)$-d system is confining at zero temperature with a spontaneously broken translation symmetry. A crystalline phase exhibits confinement via multi-stranded strings between charge-anti-charge pairs. A phase transition between two distinct confined phases is weakly first order and has an emergent spontaneously broken approximate $SO(2)$ global symmetry. The low-energy physics is described by a $(2+1)$-d $\\mathbb{R}P(1)$ effective field theory, perturbed by a dangerously irrelevant $SO(2)$ breaking operator, which prevents the interpretation of the emergent pseudo-Goldstone boson as a dual photon. This model is an ideal candidat...

  20. Magneto-optical absorption in semiconducting spherical quantum dots: Influence of the dot-size, confining potential, and magnetic field

    Directory of Open Access Journals (Sweden)

    Manvir S. Kushwaha

    2014-12-01

    Full Text Available Semiconducting quantum dots – more fancifully dubbed artificial atoms – are quasi-zero dimensional, tiny, man-made systems with charge carriers completely confined in all three dimensions. The scientific quest behind the synthesis of quantum dots is to create and control future electronic and optical nanostructures engineered through tailoring size, shape, and composition. The complete confinement – or the lack of any degree of freedom for the electrons (and/or holes – in quantum dots limits the exploration of spatially localized elementary excitations such as plasmons to direct rather than reciprocal space. Here we embark on a thorough investigation of the magneto-optical absorption in semiconducting spherical quantum dots characterized by a confining harmonic potential and an applied magnetic field in the symmetric gauge. This is done within the framework of Bohm-Pines’ random-phase approximation that enables us to derive and discuss the full Dyson equation that takes proper account of the Coulomb interactions. As an application of our theoretical strategy, we compute various single-particle and many-particle phenomena such as the Fock-Darwin spectrum; Fermi energy; magneto-optical transitions; probability distribution; and the magneto-optical absorption in the quantum dots. It is observed that the role of an applied magnetic field on the absorption spectrum is comparable to that of a confining potential. Increasing (decreasing the strength of the magnetic field or the confining potential is found to be analogous to shrinking (expanding the size of the quantum dots: resulting into a blue (red shift in the absorption spectrum. The Fermi energy diminishes with both increasing magnetic-field and dot-size; and exhibits saw-tooth-like oscillations at large values of field or dot-size. Unlike laterally confined quantum dots, both (upper and lower magneto-optical transitions survive even in the extreme instances. However, the intra

  1. Magneto-optical absorption in semiconducting spherical quantum dots: Influence of the dot-size, confining potential, and magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Kushwaha, Manvir S. [Department of Physics and Astronomy, Rice University, P.O. Box 1892, Houston, TX 77251 (United States)

    2014-12-15

    Semiconducting quantum dots – more fancifully dubbed artificial atoms – are quasi-zero dimensional, tiny, man-made systems with charge carriers completely confined in all three dimensions. The scientific quest behind the synthesis of quantum dots is to create and control future electronic and optical nanostructures engineered through tailoring size, shape, and composition. The complete confinement – or the lack of any degree of freedom for the electrons (and/or holes) – in quantum dots limits the exploration of spatially localized elementary excitations such as plasmons to direct rather than reciprocal space. Here we embark on a thorough investigation of the magneto-optical absorption in semiconducting spherical quantum dots characterized by a confining harmonic potential and an applied magnetic field in the symmetric gauge. This is done within the framework of Bohm-Pines’ random-phase approximation that enables us to derive and discuss the full Dyson equation that takes proper account of the Coulomb interactions. As an application of our theoretical strategy, we compute various single-particle and many-particle phenomena such as the Fock-Darwin spectrum; Fermi energy; magneto-optical transitions; probability distribution; and the magneto-optical absorption in the quantum dots. It is observed that the role of an applied magnetic field on the absorption spectrum is comparable to that of a confining potential. Increasing (decreasing) the strength of the magnetic field or the confining potential is found to be analogous to shrinking (expanding) the size of the quantum dots: resulting into a blue (red) shift in the absorption spectrum. The Fermi energy diminishes with both increasing magnetic-field and dot-size; and exhibits saw-tooth-like oscillations at large values of field or dot-size. Unlike laterally confined quantum dots, both (upper and lower) magneto-optical transitions survive even in the extreme instances. However, the intra-Landau level

  2. Confinement and sleep deprivation effects on propensity to take risks.

    Science.gov (United States)

    Chaumet, Guillaume; Taillard, Jacques; Sagaspe, Patricia; Pagani, Massimo; Dinges, David F; Pavy-Le-Traon, Anne; Bareille, Marie-Pierre; Rascol, Olivier; Philip, Pierre

    2009-02-01

    The impact of confinement and sleep deprivation on risk-taking propensity is a key issue in crew management. We investigated both confinement and gender effects on risk propensity and performance during up to 36 h of extended wakefulness. We studied 4 groups of 3 men and 3 women [N = 24, mean age (+/- SD) = 32.9 +/- 5.8 yr] for 10 consecutive days: a 7-d confined period (CONF) or a 7-d baseline (BASE) condition preceding one control night of normal sleep, one night of sleep deprivation, and one recovery night in the laboratory. Risk propensity (EVAR scale) and simple reaction time task (SRTT) performances were monitored every 2.25 h (0930-1945) during CONF and every 2.11 h (0930-0745) during the sleep deprivation condition. Overall risk propensity during extended wakefulness showed a variation in both conditions with two diurnal peaks separated by a nocturnal minima. After the confinement period, no second peak was found. Number of lapses (reaction time > 500 ms) on the SRTT varied daily in both conditions. In the normal sleep schedule, subjects increased their level of impulsiveness between the first day and the end of confinement (P risk-taking propensity decreases and remains stable the following day in the confinement condition while it increases after the baseline period. In a confined environment under a normal sleep-wake schedule, impulsiveness increases in men and women.

  3. Confinement of gold quantum dot arrays inside ordered mesoporous silica thin film

    Institute of Scientific and Technical Information of China (English)

    Chi Yaqing; Zhong Haiqin; Zhang Xueao; Fang Liang; Chang Shengli

    2009-01-01

    Periodic disposed quantum dot arrays are very useful for the large scale integration of single electron devices. Gold quantum dot arrays were self-assembled inside pore channels of ordered amino-functionalized mesoporous silica thin films, employing the neutralization reaction between chloroauric acid and amino groups. The diameters of quantum dots are controlled via changing the aperture of pore channels from 2.3 to 8.3 nm, which are characterized by HRTEM, SEM and FT-IR. UV-vis absorption spectra of gold nanoparticle/mesoporous silica composite thin films exhibit a blue shift and intensity drop of the absorption peak as the aperture of mesopores decreases,which represents the energy level change of quantum dot arrays due to the quantum size effect.

  4. The quantum sweeper effect

    Science.gov (United States)

    Grössing, G.; Fussy, S.; Mesa Pascasio, J.; Schwabl, H.

    2015-07-01

    We show that during stochastic beam attenuation in double slit experiments, there appear unexpected new effects for transmission factors below a ≤ 10-4, which can eventually be observed with the aid of weak measurement techniques. These are denoted as quantum sweeper effects, which are characterized by the bunching together of low counting rate particles within very narrow spatial domains. We employ a “superclassical” modeling procedure which we have previously shown to produce predictions identical with those of standard quantum theory. Thus it is demonstrated that in reaching down to ever weaker channel intensities, the nonlinear nature of the probability density currents becomes ever more important. We finally show that the resulting unexpected effects nevertheless implicitly also exist in standard quantum mechanics.

  5. Thickness-Induced Metal-Insulator Transition in Sb-doped SnO2 Ultrathin Films: The Role of Quantum Confinement.

    Science.gov (United States)

    Ke, Chang; Zhu, Weiguang; Zhang, Zheng; Tok, Eng Soon; Ling, Bo; Pan, Jisheng

    2015-11-30

    A thickness induced metal-insulator transition (MIT) was firstly observed in Sb-doped SnO2 (SnO2:Sb) epitaxial ultrathin films deposited on sapphire substrates by pulsed laser deposition. Both electrical and spectroscopic studies provide clear evidence of a critical thickness for the metallic conductivity in SnO2:Sb thin films and the oxidation state transition of the impurity element Sb. With the shrinkage of film thickness, the broadening of the energy band gap as well as the enhancement of the impurity activation energy was studied and attributed to the quantum confinement effect. Based on the scenario of impurity level pinning and band gap broadening in quantum confined nanostructures, we proposed a generalized energy diagram to understand the thickness induced MIT in the SnO2:Sb system.

  6. Quantum propagation and confinement in 1D systems using the transfer-matrix method

    Science.gov (United States)

    Pujol, Olivier; Carles, Robert; Pérez, José-Philippe

    2014-05-01

    The aim of this article is to provide some Matlab scripts to the teaching community in quantum physics. The scripts are based on the transfer-matrix formalism and offer a very efficient and versatile tool to solve problems of a physical object (electron, proton, neutron, etc) with one-dimensional (1D) stationary potential energy. Resonant tunnelling through a multiple-barrier or confinement in wells of various shapes is particularly analysed. The results are quantitatively discussed with semiconductor heterostructures, harmonic and anharmonic molecular vibrations, or neutrons in a gravity field. Scripts and other examples (hydrogen-like ions and transmission by a smooth variation of potential energy) are available freely at http://www-loa.univ-lille1.fr/˜pujol in three languages: English, French and Spanish.

  7. Band-gap engineering of functional perovskites through quantum confinement and tunneling

    DEFF Research Database (Denmark)

    Castelli, Ivano Eligio; Pandey, Mohnish; Thygesen, Kristian Sommer

    2015-01-01

    An optimal band gap that allows for a high solar-to-fuel energy conversion efficiency is one of the key factors to achieve sustainability. We investigate computationally the band gaps and optical spectra of functional perovskites composed of layers of the two cubic perovskite semiconductors BaSnO3...... and BaTaO2N. Starting from an indirect gap of around 3.3 eV for BaSnO3 and a direct gap of 1.8 eV for BaTaO2N, different layerings can be used to design a direct gap of the functional perovskite between 2.3 and 1.2 eV. The variations of the band gap can be understood in terms of quantum confinement...

  8. Quantum Magellan Effect

    CERN Document Server

    Pankovic, Vladan

    2009-01-01

    In this work we consider remarkable experiment of the quantum dynamical interaction between a photon and fixed beam splitter with additional two optical fibers. Given fibers, having "circular", almost completely closed loop forms, admit that both superposition terms, corresponding to reflecting and passing photon, interact unlimitedly periodically with splitter. For increasing number of given interactions final state of the photon tends to superposition of reflecting and passing photon with equivalent superposition coefficients quite independently of their initial values. So, many time repeated unitary quantum dynamical evolution implies an unexpected degeneration. Feynman ingeniously observed that a time of the degeneration of the ideas will come, known to any great geographer-explorer (e.g. Magellan that first circumnavigate Earth), when he thinks about the army of the tourists that will come after him. For this reason mentioned dynamical degeneration will be called quantum Magellan effect. Also, we conside...

  9. Room temperature low-threshold InAs/InP quantum dot single mode photonic crystal microlasers at 1.5 microm using cavity-confined slow light.

    Science.gov (United States)

    Bordas, Frédéric; Seassal, Christian; Dupuy, Emmanuel; Regreny, Philippe; Gendry, Michel; Viktorovitch, Pierre; Steel, M J; Rahmani, Adel

    2009-03-30

    We have designed, fabricated, and characterized an InP photonic crystal slab structure that supports a cavity-confined slow-light mode, i.e. a bandgap-confined valence band-edge mode. Three dimensional finite difference in time domain calculations predict that this type of structure can support electromagnetic modes with large quality factors and small mode volumes. Moreover these modes are robust with respect to fabrication imperfections. In this paper, we demonstrate room-temperature laser operation at 1.5 mum of a cavity-confined slow-light mode under pulsed excitation. The gain medium is a single layer of InAs/InP quantum dots. An effective peak pump power threshold of 80 microW is reported.

  10. A Confined Fabrication of Perovskite Quantum Dots in Oriented MOF Thin Film.

    Science.gov (United States)

    Chen, Zheng; Gu, Zhi-Gang; Fu, Wen-Qiang; Wang, Fei; Zhang, Jian

    2016-10-10

    Organic-inorganic hybrid lead organohalide perovskites are inexpensive materials for high-efficiency photovoltaic solar cells, optical properties and superior electrical conductivity. However, the fabrication of their quantum dots (QDs) with uniform ultra-small particles is still a challenge. Here we use oriented microporous metal-organic framework (MOF) thin film prepared by liquid phase epitaxy approach as a template for CH3NH3PbI2X (X = Cl, Br and I) perovskite QDs fabrication. By introducing the PbI2 and CH3NH3X (MAX) precursors into MOF HKUST-1 (Cu3(BTC)2, BTC = 1,3,5-benzene tricarboxylate) thin film in a stepwise approach, the resulted perovskite MAPbI2X (X = Cl, Br and I) QDs with uniform diameters of 1.5~2 nm match to the pore size of HKUST-1. Furthermore, the photoluminescent properties and stability in the moist air of the perovskite QDs loaded HKUST-1 thin film were studied. This confined fabrication strategy demonstrates that the perovskite QDs loaded MOF thin film will be insensitive to air exposure and offers a novel means of confining the uniform size of the similar perovskite QDs according to the oriented porous MOF materials.

  11. Confinement-Higgs transition in a disordered gauge theory and the accuracy threshold for quantum memory

    CERN Document Server

    Wang, C; Wang, Chenyang; Preskill, John

    2003-01-01

    We study the +/- J random-plaquette Z_2 gauge model (RPGM) in three spatial dimensions, a three-dimensional analog of the two-dimensional +/- J random-bond Ising model (RBIM). The model is a pure Z_2 gauge theory in which randomly chosen plaquettes (occuring with concentration p) have couplings with the ``wrong sign'' so that magnetic flux is energetically favored on these plaquettes. Excitations of the model are one-dimensional ``flux tubes'' that terminate at ``magnetic monopoles.'' Electric confinement can be driven by thermal fluctuations of the flux tubes, by the quenched background of magnetic monopoles, or by a combination of the two. Like the RBIM, the RPGM has enhanced symmetry along a ``Nishimori'' line in the p-T plane (where T is the temperature). The critical concentration p_c of wrong-sign plaquettes at the confinement-Higgs phase transition along the Nishimori line can be identified with the accuracy threshold for robust storage of quantum information using topological error-correcting codes: i...

  12. Effects of adsorption and confinement on nanoporous electrochemistry.

    Science.gov (United States)

    Bae, Je Hyun; Han, Ji-Hyung; Han, Donghyeop; Chung, Taek Dong

    2013-01-01

    Characteristic molecular dynamics of reactant molecules confined in the space of the nanometer scale augments the frequency of collisions with the electrified surface so that a given faradaic reaction can be enhanced at nanoporous electrodes, the so-called nano-confinement effect. Since this effect is grounded on diffusion inside nanopores, it is predicted that adsorption onto the surface will seriously affect the enhancement by nano-confinement. We experimentally explored the correlation between adsorption and the confinement effect by examining the oxidation of butanol isomers at platinum and gold nanoporous electrodes. The results showed that electrooxidation of 2-butanol, which is a non-adsorption reaction, was enhanced more than that of 1-butanol, which is an adsorption reaction, at nanoporous platinum in acidic media. In contrast, the nanoporous gold electrode, on which 1-butanol is less adsorptive than it is on platinum, enhanced the electrooxidation of 1-butanol greatly. Furthermore, the electrocatalytic activity of nanoporous gold for oxygen reduction reaction was improved so much as to be comparable with that of flat Pt. These findings show that the nano-confinement effect can be appreciable for electrocatalytic oxygen reduction as well as alcohol oxidation unless the adsorption is extensive, and suggests a new strategy in terms of material design for innovative non-noble metal electrocatalysts.

  13. Simple theoretical analysis of the Einstein’s photoemission from quantum confined superlattices

    Science.gov (United States)

    Pahari, S.; Bhattacharya, S.; Roy, S.; Saha, A.; De, D.; Ghatak, K. P.

    2009-11-01

    In this paper, we study the Einstein's photoemission from III-V, II-VI, IV-VI and HgTe/CdTe quantum well superlattices (QWSLs) with graded interfaces and quantum well effective mass superlattices in the presence of a quantizing magnetic field on the basis of newly formulated dispersion relations in the respective cases. Besides, the same has been studied from the afore-mentioned quantum dot superlattices and it appears that the photoemission oscillates with increasing carrier degeneracy and quantizing magnetic field in different manners. In addition, the photoemission oscillates with film thickness and increasing photon energy in quantum steps together with the fact that the solution of the Boltzmann transport equation will introduce new physical ideas and new experimental findings under different external conditions. The influence of band structure is apparent from all the figures and we have suggested three applications of the analyses of this paper in the fields of superlattices and microstructures.

  14. Colloidal Synthesis of Strongly Fluorescent CsPbBr3 Nanowires with Width Tunable down to the Quantum Confinement Regime

    CERN Document Server

    Imran, Muhammad; Dang, Zhiya; Canale, Claudio; Khan, Ali Hossain; Shamsi, Javad; Brescia, Rosaria; Prato, Mirko; Manna, Liberato

    2016-01-01

    We report the colloidal synthesis of strongly fluorescent CsPbBr3 perovskite nanowires (NWs) with rectangular section and with tuneable width, from 20 nm (exhibiting no quantum confinement, hence emitting in the green) down to around 3 nm (in the strong quan-tum-confinement regime, emitting in the blue), by introducing in the synthesis a short acid (octanoic acid or hexanoic acid) together with alkyl amines (octylamine and oleylamine). Temperatures below 70 {\\deg}C promoted the formation of monodisperse, few unit cell thick NWs that were free from byproducts. The photoluminescence quantum yield of the NW samples went from 12% for non-confined NWs emitting at 524 nm to a maximum of 77% for the 5 nm diameter NWs emitting at 497 nm, down to 30% for the thinnest NWs (diameter ~ 3nm), in the latter sample most likely due to aggregation occurring in solution.

  15. Nitride-based Quantum-Confined Structures for Ultraviolet-Visible Optical Devices on Silicon Substrates

    KAUST Repository

    Janjua, Bilal

    2017-04-01

    III–V nitride quantum-confined structures embedded in nanowires (NWs), also known as quantum-disks-in-nanowires (Qdisks-in-NWs), have recently emerged as a new class of nanoscale materials exhibiting outstanding properties for optoelectronic devices and systems. It is promising for circumventing the technology limitation of existing planar epitaxy devices, which are bounded by the lattice-, crystal-structure-, and thermal- matching conditions. This work presents significant advances in the growth of good quality GaN, InGaN and AlGaN Qdisks-in-NWs based on careful optimization of the growth parameters, coupled with a meticulous layer structure and active region design. The NWs were grown, catalyst-free, using plasma assisted molecular beam epitaxy (PAMBE) on silicon (Si) substrates. A 2-step growth scheme was developed to achieve high areal density, dislocation free and vertically aligned NWs on Ti/Si substrates. Numerical modeling of the NWs structures, using the nextnano3 software, showed reduced polarization fields, and, in the presence of Qdisks, exhibited improved quantum-confinement; thus contributing to high carrier radiative-recombination rates. As a result, based on the growth and device structure optimization, the technologically challenging orange and yellow NWs light emitting devices (LEDs) targeting the ‘green-yellow’ gap were demonstrated on scalable, foundry compatible, and low-cost Ti coated Si substrates. The NWs work was also extended to LEDs emitting in the ultraviolet (UV) range with niche applications in environmental cleaning, UV-curing, medicine, and lighting. In this work, we used a Ti (100 nm) interlayer and Qdisks to achieve good quality AlGaN based UV-A (320 - 400 nm) device. To address the issue of UV-absorbing polymer, used in the planarization process, we developed a pendeo-epitaxy technique, for achieving an ultra-thin coalescence of the top p-GaN contact layer, for a self-planarized Qdisks-in-NWs UV-B (280 – 320 nm) LED grown

  16. Exploiting Confinement Effects to Tune Selectivity in Cyclooctane Metathesis

    KAUST Repository

    Pump, Eva

    2017-08-24

    The mechanism of cyclooctane metathesis using confinement effect strategies in mesoporous silica nanoparticles (MSNs) is discussed by catalytic experiments and density functional theory (DFT) calculations. WMe6 was immobilized inside the pores of a series of MSNs having the same structure but different pore diameters (60, 30 and 25 Å). Experiments in cyclooctane metathesis suggest that confinement effects observed in smaller pores (30 and 25 Å) improve selectivity towards the dimeric cyclohexadecane. In contrast, in larger pores (60 Å) a broad product distribution dominated by ring contracted cycloalkanes was found. The catalytic cycle and potential side reactions occurring at [(≡SiO-)WMe5] were examined with DFT calculations. Analysis of the geometries for the key reaction intermediates allowed to rationalize the impact of a confined environment on the enhanced selectivity towards the dimeric product in smaller pores, while in large pores the ring contracted products are favored.

  17. The effect of quantum noise on the restricted quantum game

    Institute of Scientific and Technical Information of China (English)

    Cao Shuai; Fang Mao-Fa

    2006-01-01

    It has recently been established that quantum strategies have great advantage over classical ones in quantum games. However, quantum states are easily affected by the quantum noise resulting in decoherence. In this paper, we investigate the effect of quantum noise on the restricted quantum game in which one player is restricted in classical strategic space, another in quantum strategic space and only the quantum player is affected by the quantum noise. Our results show that in the maximally entangled state, no Nash equilibria exist in the range of 0< p≤0.422 (p is the quantum noise parameter), while two special Nash equilibria appear in the range of 0.422 < p< 1. The advantage that the quantum player diminished only in the limit of maximum quantum noise. Increasing the amount of quantum noise leads to the increase of the classical player's payoff and the reduction of the quantum player's payoff, but is helpful in forming two Nash equilibria.

  18. Photoinduced band filling in strongly confined colloidal PbS quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Ullrich, B., E-mail: bruno@fis.unam.mx [Instituto de Ciencias Físicas, Universidad Nacional Autónoma de México, Cuernavaca, Morelos 62210 (Mexico); Ullrich Photonics LLC, Wayne, Ohio 43466 (United States); Xi, H. [Department of Physics and Astronomy, Bowling Green State University, Bowling Green, Ohio 43403-0209 (United States); Wang, J. S. [Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright Patterson AFB, Ohio 45433-7707 (United States)

    2014-06-21

    Increase in continuous wave laser excitation (6 W/cm{sup 2} to 120 W/cm{sup 2}) of colloidal PbS quantum dots in the strongly quantized regime (diameters 2.0 nm and 4.7 nm) deposited on semi-insulating GaAs and glass causes a clear blue shift (0.019 eV and 0.080 eV) of the emission spectra. Proof of the applicability of a dynamic three-dimensional band filling model is the significance of the presented results and demonstrates the effective electronic coupling in quantum dot arrays similar to superlattices. The work also reveals the influence of quantum dot sizes on photo-doping effects.

  19. Photoinduced band filling in strongly confined colloidal PbS quantum dots

    Science.gov (United States)

    Ullrich, B.; Xi, H.; Wang, J. S.

    2014-06-01

    Increase in continuous wave laser excitation (6 W/cm2 to 120 W/cm2) of colloidal PbS quantum dots in the strongly quantized regime (diameters 2.0 nm and 4.7 nm) deposited on semi-insulating GaAs and glass causes a clear blue shift (0.019 eV and 0.080 eV) of the emission spectra. Proof of the applicability of a dynamic three-dimensional band filling model is the significance of the presented results and demonstrates the effective electronic coupling in quantum dot arrays similar to superlattices. The work also reveals the influence of quantum dot sizes on photo-doping effects.

  20. Effects of spatial confinement on conduction electrons in semiconductor nanostructures

    NARCIS (Netherlands)

    Germeau, Alexander

    2003-01-01

    Semiconductor nanostructures show electrical and optical properties which can be very different from bulk semiconductors. The various effects that occur due to the spatial confinement of electrons in such structures are of scientific importance. In addition, semiconductor nanostructures are very pro

  1. Non-monotonic effect of confinement on the glass transition

    Science.gov (United States)

    Varnik, Fathollah; Franosch, Thomas

    2016-04-01

    The relaxation dynamics of glass forming liquids and their structure are influenced in the vicinity of confining walls. This effect has mostly been observed to be a monotonic function of the slit width. Recently, a qualitatively new behaviour has been uncovered by Mittal and coworkers, who reported that the single particle dynamics in a hard-sphere fluid confined in a planar slit varies in a non-monotonic way as the slit width is decreased from five to roughly two particle diametres (Mittal et al 2008 Phys. Rev. Lett. 100 145901). In view of the great potential of this effect for applications in those fields of science and industry, where liquids occur under strong confinement (e.g. nano-technology), the number of researchers studying various aspects and consequences of this non-monotonic behaviour has been rapidly growing. This review aims at providing an overview of the research activity in this newly emerging field. We first briefly discuss how competing mechanisms such as packing effects and short-range attraction may lead to a non-monotonic glass transition scenario in the bulk. We then analyse confinement effects on the dynamics of fluids using a thermodynamic route which relates the single particle dynamics to the excess entropy. Moreover, relating the diffusive dynamics to the Widom’s insertion probability, the oscillations of the local dynamics with density at moderate densities are fairly well described. At high densities belonging to the supercooled regime, however, this approach breaks down signaling the onset of strongly collective effects. Indeed, confinement introduces a new length scale which in the limit of high densities and small pore sizes competes with the short-range local order of the fluid. This gives rise to a non-monotonic dependence of the packing structure on confinement, with a corresponding effect on the dynamics of structural relaxation. This non-monotonic effect occurs also in the case of a cone-plate type channel, where the degree

  2. Electronic confinement in graphene quantum rings due to substrate-induced mass radial kink

    Science.gov (United States)

    Xavier, L. J. P.; da Costa, D. R.; Chaves, A.; Pereira, J. M., Jr.; Farias, G. A.

    2016-12-01

    We investigate localized states of a quantum ring confinement in monolayer graphene defined by a circular mass-related potential, which can be induced e.g. by interaction with a substrate that breaks the sublattice symmetry, where a circular line defect provides a change in the sign of the induced mass term along the radial direction. Electronic properties are calculated analytically within the Dirac-Weyl approximation in the presence of an external magnetic field. Analytical results are also compared with those obtained by the tight-binding approach. Regardless of its sign, a mass term Δ is expected to open a gap for low-energy electrons in Dirac cones in graphene. Both approaches confirm the existence of confined states with energies inside the gap, even when the width of the kink modelling the mass sign transition is infinitely thin. We observe that such energy levels are inversely proportional to the defect line ring radius and independent on the mass kink height. An external magnetic field is demonstrated to lift the valley degeneracy in this system and easily tune the valley index of the ground state in this system, which can be polarized on either K or {{K}\\prime} valleys of the Brillouin zone, depending on the magnetic field intensity. Geometrical changes in the defect line shape are considered by assuming an elliptic line with different eccentricities. Our results suggest that any defect line that is closed in a loop, with any geometry, would produce the same qualitative results as the circular ones, as a manifestation of the topologically protected nature of the ring-like states investigated here.

  3. Theory of the vortex-clustering transition in a confined two-dimensional quantum fluid

    Science.gov (United States)

    Yu, Xiaoquan; Billam, Thomas P.; Nian, Jun; Reeves, Matthew T.; Bradley, Ashton S.

    2016-08-01

    Clustering of like-sign vortices in a planar bounded domain is known to occur at negative temperature, a phenomenon that Onsager demonstrated to be a consequence of bounded phase space. In a confined superfluid, quantized vortices can support such an ordered phase, provided they evolve as an almost isolated subsystem containing sufficient energy. A detailed theoretical understanding of the statistical mechanics of such states thus requires a microcanonical approach. Here we develop an analytical theory of the vortex clustering transition in a neutral system of quantum vortices confined to a two-dimensional disk geometry, within the microcanonical ensemble. The choice of ensemble is essential for identifying the correct thermodynamic limit of the system, enabling a rigorous description of clustering in the language of critical phenomena. As the system energy increases above a critical value, the system develops global order via the emergence of a macroscopic dipole structure from the homogeneous phase of vortices, spontaneously breaking the Z2 symmetry associated with invariance under vortex circulation exchange, and the rotational SO (2 ) symmetry due to the disk geometry. The dipole structure emerges characterized by the continuous growth of the macroscopic dipole moment which serves as a global order parameter, resembling a continuous phase transition. The critical temperature of the transition, and the critical exponent associated with the dipole moment, are obtained exactly within mean-field theory. The clustering transition is shown to be distinct from the final state reached at high energy, known as supercondensation. The dipole moment develops via two macroscopic vortex clusters and the cluster locations are found analytically, both near the clustering transition and in the supercondensation limit. The microcanonical theory shows excellent agreement with Monte Carlo simulations, and signatures of the transition are apparent even for a modest system of 100

  4. Optical properties and quantum confinement of nanocrystalline II-IV semiconductor particles

    NARCIS (Netherlands)

    Dijken, Albert van

    2001-01-01

    In this thesis, experiments are described that were performed on suspensions of nanocrystalline II-IV semiconductor particles.The object of this research is to study quantum size effects in relation to the luminescence properties of these particles. A pre-requisite for performing studies of size-

  5. Confinement Effects for Lithium Borohydride: Comparing Silica and Carbon Scaffolds.

    Science.gov (United States)

    Suwarno; Ngene, Peter; Nale, Angeloclaudio; Eggenhuisen, Tamara M; Oschatz, Martin; Embs, Jan Peter; Remhof, Arndt; de Jongh, Petra E

    2017-03-02

    LiBH4 is a promising material for hydrogen storage and as a solid-state electrolyte for Li ion batteries. Confining LiBH4 in porous scaffolds improves its hydrogen desorption kinetics, reversibility, and Li(+) conductivity, but little is known about the influence of the chemical nature of the scaffold. Here, quasielastic neutron scattering and calorimetric measurements were used to study support effects for LiBH4 confined in nanoporous silica and carbon scaffolds. Pore radii were varied from 8 Å to 20 nm, with increasing confinement effects observed with decreasing pore size. For similar pore sizes, the confinement effects were more pronounced for silica than for carbon scaffolds. The shift in the solid-solid phase transition temperature is much larger in silica than in carbon scaffolds with similar pore sizes. A LiBH4 layer near the pore walls shows profoundly different phase behavior than crystalline LiBH4. This layer thickness was 1.94 ± 0.13 nm for the silica and 1.41 ± 0.16 nm for the carbon scaffolds. Quasi-elastic neutron scattering confirmed that the fraction of LiBH4 with high hydrogen mobility is larger for the silica than for the carbon nanoscaffold. These results clearly show that in addition to the pore size the chemical nature of the scaffold also plays a significant role in determining the hydrogen mobility and interfacial layer thickness in nanoconfined metal hydrides.

  6. Confinement Effects for Lithium Borohydride: Comparing Silica and Carbon Scaffolds

    Science.gov (United States)

    2017-01-01

    LiBH4 is a promising material for hydrogen storage and as a solid-state electrolyte for Li ion batteries. Confining LiBH4 in porous scaffolds improves its hydrogen desorption kinetics, reversibility, and Li+ conductivity, but little is known about the influence of the chemical nature of the scaffold. Here, quasielastic neutron scattering and calorimetric measurements were used to study support effects for LiBH4 confined in nanoporous silica and carbon scaffolds. Pore radii were varied from 8 Å to 20 nm, with increasing confinement effects observed with decreasing pore size. For similar pore sizes, the confinement effects were more pronounced for silica than for carbon scaffolds. The shift in the solid–solid phase transition temperature is much larger in silica than in carbon scaffolds with similar pore sizes. A LiBH4 layer near the pore walls shows profoundly different phase behavior than crystalline LiBH4. This layer thickness was 1.94 ± 0.13 nm for the silica and 1.41 ± 0.16 nm for the carbon scaffolds. Quasi-elastic neutron scattering confirmed that the fraction of LiBH4 with high hydrogen mobility is larger for the silica than for the carbon nanoscaffold. These results clearly show that in addition to the pore size the chemical nature of the scaffold also plays a significant role in determining the hydrogen mobility and interfacial layer thickness in nanoconfined metal hydrides. PMID:28286596

  7. Collective behavior of interwell excitons laterally confined in GaAs/AlGaAs double quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Timofeev, V.B.; Gorbunov, A.V. [Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka 142432 (Russian Federation)

    2005-02-01

    The luminescence of interwell excitons laterally confined by long range potential fluctuations and with the use of inhomogeneous electric field in n-i-n GaAs/AlGaAs heterostructures double quantum wells has been investigated under variation of excitation power and temperature. Above mobility threshold very narrow interwell exciton line has been observed and its intensity decrease is linearly dependent on temperature growth. The observed phenomena, which were critical to exciton density and temperature, are attributed to the Bose-condensation in laterally confined quasi-two dimensional system of interwell excitons. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  8. Bound state energies and wave functions of spherical quantum dots in presence of a confining potential model

    CERN Document Server

    Ikhdair, Sameer M

    2011-01-01

    We obtain the exact energy spectra and corresponding wave functions of the radial Schr\\"odinger equation (RSE) for any (n,l) state in the presence of a combination of psudoharmonic, Coulomb and linear confining potential terms using an exact analytical iteration method. The interaction potential model under consideration is Cornell-modified plus harmonic (CMpH) type which is a correction form to the harmonic, Coulomb and linear confining potential terms. It is used to investigates the energy of electron in spherical quantum dot and the heavy quarkonia (QQ-onia).

  9. Effects of confinement on a rotating sphere

    Science.gov (United States)

    Liu, Qianlong; Prosperetti, Andrea

    2009-11-01

    The hydrodynamic force and couple acting on a rotating sphere in a quiescent fluid are modified by nearby boundaries with possible consequences on spin-up and spin-down times of particles uspended in a fluid, their wall deposition, entraiment and others. Up to now, the vast majority of papers dealing with these problems have considered the low-Reynolds-number regime. This paper focuses on the effect of inertia on the hydrodynamic interaction of a spinning sphere with nearby boundaries. Rotation axes parallel and perpendicular to a plane boundary as well as other situations are studied. Several steady and transient numerical results are presented and interptreted in terms of physical scaling arguments. The Navier-Stokes equations for an incompressible, constant-property Newtonian fluid are solved by the finite-difference PHYSALIS method. Among the noteworthy features of this method are the fact that the no-slip condition at the particle surface is satisfied exactly and that the force and torque on the sphere are obtained directly as a by-product of the computation. This feature avoids the need to integrate the stress over the particle surface, which with other methods is a step prone to numerical inaccuracies. A locally refined mesh surrounding the particle is used to enhance the resolution of boundary layers maintaining a manageable overall computational cost.

  10. Quantum Effects in Biological Systems

    Science.gov (United States)

    Roy, Sisir

    2014-07-01

    The debates about the trivial and non-trivial effects in biological systems have drawn much attention during the last decade or so. What might these non-trivial sorts of quantum effects be? There is no consensus so far among the physicists and biologists regarding the meaning of "non-trivial quantum effects". However, there is no doubt about the implications of the challenging research into quantum effects relevant to biology such as coherent excitations of biomolecules and photosynthesis, quantum tunneling of protons, van der Waals forces, ultrafast dynamics through conical intersections, and phonon-assisted electron tunneling as the basis for our sense of smell, environment assisted transport of ions and entanglement in ion channels, role of quantum vacuum in consciousness. Several authors have discussed the non-trivial quantum effects and classified them into four broad categories: (a) Quantum life principle; (b) Quantum computing in the brain; (c) Quantum computing in genetics; and (d) Quantum consciousness. First, I will review the above developments. I will then discuss in detail the ion transport in the ion channel and the relevance of quantum theory in brain function. The ion transport in the ion channel plays a key role in information processing by the brain.

  11. The Joule-Thomson effect in confined fluids

    Science.gov (United States)

    Schoen, Martin

    1999-08-01

    The Joule-Thomson effect is discussed for a fluid composed of spherically symmetric Lennard-Jones(12,6) molecules (of “diameter” σ) confined between two planar, rigid, structureless solid substrates separated by sz=10 and 20 σ. The effect of “strong” and “weak” of the substrate is studied by employing fluid-substrate potentials with and without attractive interactions, respectively. The focal point of this study is the confinement-induced depression of the inversion temperature Tinv with respect to the bulk value. It is defined such that during a Joule-Thomson expansion the temperature of a (confined or bulk) gas remains constant. In the limit of vanishing gas density, Tinv is computed from the second virial coefficient defined through a density expansion of the transverse stress T∥ in the gas. For higher densities Tinv is computed from the (transverse) expansion coefficient α∥ which is accessible through density and enthalpy fluctuations in mixed stress-strain ensemble Monte Carlo simulations. Results of these simulations are analyzed in terms of a mean-field theory which provides a qualitatively correct description of the Joule-Thomson effect in confined fluids. The smaller sz the more depressed (with respect to the bulk) is Tinv. The density dependence of Tinv is different for “strong” and “weak” substrates. Without attractive fluid-fluid interactions Tinv does not exist and the confined gas is always heated during a Joule-Thomson expansion. In this case α∥ is independent of the substrate material.

  12. Persistent Spin Current in a Hard-Wall Confining Quantum Wire with Weak Dresselhaus Spin-Orbit Coupling

    Institute of Scientific and Technical Information of China (English)

    FU Xi; ZHOU Guang-Hui

    2009-01-01

    We investigate theoretically the spin current in a quantum wire with weak Dresselhaus spin-orbit coupling connected to two normal conductors.Both the quantum wire and conductors are described by a hard-wall confining potential.Using the electron wave-functions in the quantum wire and a new definition of spin current, we have calculated the elements of linear spin current density jTs,xi and jTs,yi(I = x, y, z).We lind that the elements jTs,xx and jTs,yy have a antisymmetrical relation and the element jTs,yz has the same amount level jTs,xx and jTs,yy.We also find a net linear spin current density, which has peaks at the center of quantum wire.The net linear spin current can induce a linear electric field, which may imply a way of spin current detection.

  13. Self-assembly of lamella-forming diblock copolymers confined in nanochannels: Effect of confinement geometry

    Science.gov (United States)

    Yu, Bin; Deng, Jian-Hua; Wang, Zheng; Li, Bao-Hui; Shi, An-Chang

    2015-04-01

    The self-assembly of symmetric diblock copolymers confined in the channels of variously shaped cross sections (regular triangles, squares, and ellipses) is investigated using a simulated annealing technique. In the bulk, the studied symmetric diblock copolymers form a lamellar structure with period LL. The geometry and surface property of the confining channels have a large effect on the self-assembled structures and the orientation of the lamellar structures. Stacked perpendicular lamellae with period LL are observed for neutral surfaces regardless of the channel shape and size, but each lamella is in the shape of the corresponding channel's cross section. In the case of triangle-shaped cross sections, stacked parallel lamellae are the majority morphologies for weakly selective surfaces, while morphologies including a triangular-prism-shaped B-cylinder and multiple tridentate lamellae are obtained for strongly selective surfaces. In the cases of square-shaped and ellipse-shaped cross sections, concentric lamellae are the signature morphology for strongly selective surfaces, whereas for weakly selective surfaces, stacked parallel lamellae, and several types of folding lamellae are obtained in the case of square-shaped cross sections, and stacked parallel lamellae are the majority morphologies in the case of ellipse-shaped cross sections when the length of the minor axis is commensurate with the bulk lamellar period. The mean-square end-to-end distance, the average contact number between different species and the surface concentration of the A-monomers are computed to elucidate the mechanisms of the formation of the different morphologies. It is found that the resulting morphology is a consequence of competition among the chain stretching, interfacial energy, and surface energy. Our results suggest that the self-assembled morphology and the orientation of lamellae can be manipulated by the shape, the size, and the surface property of the confining channels. Project

  14. Quantum Effects in Biological Systems

    CERN Document Server

    2016-01-01

    Since the last decade the study of quantum mechanical phenomena in biological systems has become a vibrant field of research. Initially sparked by evidence of quantum effects in energy transport that is instrumental for photosynthesis, quantum biology asks the question of how methods and models from quantum theory can help us to understand fundamental mechanisms in living organisms. This approach entails a paradigm change challenging the related disciplines: The successful framework of quantum theory is taken out of its low-temperature, microscopic regimes and applied to hot and dense macroscopic environments, thereby extending the toolbox of biology and biochemistry at the same time. The Quantum Effects in Biological Systems conference is a platform for researchers from biology, chemistry and physics to present and discuss the latest developments in the field of quantum biology. After meetings in Lisbon (2009), Harvard (2010), Ulm (2011), Berkeley (2012), Vienna (2013), Singapore (2014) and Florence (2015),...

  15. Solid Confinement of Quantum Dots in ZIF-8 for Efficient and Stable Color-Conversion White LEDs.

    Science.gov (United States)

    Ying, Wen; Mao, Yiyin; Wang, Xiaobing; Guo, Yi; He, Haiping; Ye, Zhizhen; Lee, Shuit-Tong; Peng, Xinsheng

    2017-03-13

    The powder form and low photoluminescence quantum yield (PLQY) of fluorescent metal-organic frameworks (MOFs) present a serious obstacle to fabricating high-efficiency film-like lighting devices. Here, we present a facile way to produce thin films of CdSex S1-x /ZnS quantum dots (QDs)@ZIF-8 with high PLQY by encapsulating red, green, and blue CdSex S1-x /ZnS QDs in ZIF-8 through a one-pot solid-confinement conversion process. The QDs@ZIF-8 thin film emits warm white light with good color quality and presents good thermal stability and long-term durability.

  16. Binding Energy of D- and D0 Centers Confined by Spherical Quantum Dots

    Institute of Scientific and Technical Information of China (English)

    BAO Yuan-Peng; XIE Wen-Fang

    2008-01-01

    We study a negative donor center, a neutral donor in a spherical Gaussian potential quantum dot by using the matrix diagonalization of Hamiltonian within the effective-mass approximation. We calculate the energy E(D-) as functions of Gaussian potential size and depth, the same calculations as performed with the parabolic approximation. The dependence of the ground state of the neutral shallow donor and the negatively charged donor on the dot size and the potential depth is investigated.

  17. Connectivity of Confined Dense Networks: Boundary Effects and Scaling Laws

    CERN Document Server

    Coon, Justin P; Georgiou, Orestis

    2012-01-01

    In this paper, we study the probability that a dense network confined within a given geometry is fully connected. We employ a cluster expansion approach often used in statistical physics to analyze the effects that the boundaries of the geometry have on connectivity. To maximize practicality and applicability, we adopt four important point-to-point link models based on outage probability in our analysis: single-input single-output (SISO), single-input multiple-output (SIMO), multiple-input single-output (MISO), and multiple-input multiple-output (MIMO). Furthermore, we derive diversity and power scaling laws that dictate how boundary effects can be mitigated (to leading order) in confined dense networks for each of these models. Finally, in order to demonstrate the versatility of our theory, we analyze boundary effects for dense networks comprising MIMO point-to-point links confined within a right prism, a polyhedron that accurately models many geometries that can be found in practice. We provide numerical re...

  18. Nonlocal effects in a hybrid plasmonic waveguide for nanoscale confinement.

    Science.gov (United States)

    Huang, Qiangsheng; Bao, Fanglin; He, Sailing

    2013-01-28

    The effect of nonlocal optical response is studied for a novel silicon hybrid plasmonic waveguide (HPW). Finite element method is used to implement the hydrodynamic model and the propagation mode is analyzed for a hybrid plasmonic waveguide of arbitrary cross section. The waveguide has an inverted metal nano-rib over a silicon-on-insulator (SOI) structure. An extremely small mode area of~10⁻⁶λ² is achieved together with several microns long propagation distance at the telecom wavelength of 1.55 μm. The figure of merit (FoM) is also improved in the same time, compared to the pervious hybrid plasmonic waveguide. We demonstrate the validity of our method by comparing our simulating results with some analytical results for a metal cylindrical waveguide and a metal slab waveguide in a wide wavelength range. For the HPW, we find that the nonlocal effects can give less loss and better confinement. In particular, we explore the influence of the radius of the rib's tip on the loss and the confinement. We show that the nonlocal effects give some new fundamental limitation on the confinement, leaving the mode area finite even for geometries with infinitely sharp tips.

  19. Field-effect transistor self-electrooptic effect device integrated photodiode, quantum well modulator and transistor

    Energy Technology Data Exchange (ETDEWEB)

    Miller, D.A.B.; Feuer, M.D.; Chang, T.Y.; Shunk, S.C.; Henry, J.E.; Burrows, D.J.; Chemla, D.S.

    1989-03-01

    The authors propose and demonstrate the integration of a photodiode, a quantum-confined Stark effect quantum well optical modulator and a metal-semiconductor field-effect transistor (MESFET), to make a field-effect transistor self-electrooptic effect device. This integration allows optical inputs and outputs on the surface of a GaAs-integrated circuit chip, compatible with standard MESFET processing. As an illustration of feasibility, the authors demonstrate optical signal amplification with a single MESFET.

  20. Effective equations for the quantum pendulum from momentous quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez, Hector H.; Chacon-Acosta, Guillermo [Universidad Autonoma de Chihuahua, Facultad de Ingenieria, Nuevo Campus Universitario, Chihuahua 31125 (Mexico); Departamento de Matematicas Aplicadas y Sistemas, Universidad Autonoma Metropolitana-Cuajimalpa, Artificios 40, Mexico D. F. 01120 (Mexico)

    2012-08-24

    In this work we study the quantum pendulum within the framework of momentous quantum mechanics. This description replaces the Schroedinger equation for the quantum evolution of the system with an infinite set of classical equations for expectation values of configuration variables, and quantum dispersions. We solve numerically the effective equations up to the second order, and describe its evolution.

  1. Effect of the Electron-LO-Phonon Coupling on an Exciton Quantum Dot

    Institute of Scientific and Technical Information of China (English)

    XIE Wen-Fang; ZHU Wu

    2002-01-01

    The influence of the electron-LO-phonon coupling on energy spectrum of the low-lying states ofan exciton inparabolic quantum dots is investigated as a function of dot size. Calculations are made by using the method of few-bodyphysics within the effective-mass approximation. A considerable decrease of the energy in the stronger confinement rangeis found for the low-lying states of an exciton in quantum dots, which results from the confinement of electron-phononcoupling.

  2. Confinement of an electron in a non-homogeneous magnetic field: Integrable vs superintegrable quantum systems

    Energy Technology Data Exchange (ETDEWEB)

    Contreras-Astorga, A., E-mail: alonso.contreras.astorga@gmail.com [Department of Mathematics and Actuarial Science, Indiana University Northwest, 3400 Broadway, Gary, IN 46408 (United States); Departamento de Física, Cinvestav, A.P. 14-740, 07000 México D.F. (Mexico); Negro, J., E-mail: jnegro@fta.uva.es [Departamento de Física Teórica, Atómica y Óptica and IMUVA, Universidad de Valladolid, E-47011 Valladolid (Spain); Tristao, S., E-mail: hetsudoyaguiu@gmail.com [Departamento de Física Teórica, Atómica y Óptica and IMUVA, Universidad de Valladolid, E-47011 Valladolid (Spain)

    2016-01-08

    This paper deals with the problem of an electron in a non-homogeneous magnetic field perpendicular to a plane. From the classical point of view this is an integrable, but not superintegrable, solvable system. In the quantum framework of the Dirac equation this integrable system is solvable too; the energy levels and wavefunctions of bound states, for its reduction to the plane, are computed. The effective one-dimensional matrix Hamiltonian is shown to belong to a shape-invariant hierarchy. Through this example we will shed some light on the specific properties of a quantum integrable system with respect to those characteristic of superintegrable systems. - Highlights: • The system: an electron in a non-homogeneous magnetic field. • This is a solvable integrable but not superintegrable system. • Solutions to the discrete Dirac spectrum are found. • The shape-invariance of Dirac matrix Hamiltonians is characterized. • Specific properties of integrable, not superintegrable, systems are analyzed.

  3. Raman spectrum of Si nanowires: temperature and phonon confinement effects

    Science.gov (United States)

    Anaya, J.; Torres, A.; Hortelano, V.; Jiménez, J.; Prieto, A. C.; Rodríguez, A.; Rodríguez, T.; Rogel, R.; Pichon, L.

    2014-03-01

    The Raman spectrum of Si nanowires (NWs) is a matter of controversy. Usually, the one-phonon band appears broadened and shifted. This behaviour is interpreted in terms of phonon confinement; however, similar effects are observed for NWs with dimensions for which phonon confinement does not play any relevant role. In this context, the temperature increase induced by the laser beam is recognized to play a capital role in the shape of the spectrum. The analysis of the Raman spectrum, under the influence of the heating induced by the laser beam, is strongly dependent on the excitation conditions and the properties of the NWs. We present herein an analysis of the Raman spectrum of Si NWs based on a study of the interaction between the laser beam and the NWs, for both ensembles of NWs and individual NWs, taking account of the temperature increase in the NWs under the focused laser beam and the dimensions of the NWs.

  4. Energy-loss rate of hot electrons due to confined acoustic phonon modes in a semiconductor quantum wire under transverse electric field

    Science.gov (United States)

    Stepanyan, A.; Yeranosyan, M.; Vardanyan, L.; Asatryan, A.; Kirakosyan, A.; Vartanian, A.

    2017-08-01

    The hot-electron energy-loss rate via the acoustic-phonons in an embedded semiconductor quantum wire of circular cross section in the presence of external electric field has been investigated using deformation potential theory. Dimensional confinement effect on modifying acoustic-phonon modes are taken into account. The energy-loss rate as a function of electric field strength, electron density and electron temperature is obtained. Our calculations show that the electric field applied perpendicularly to the wire axis can be used as an important tool for the control of the energy-loss processes in nanowires.

  5. Light-front holography and superconformal quantum mechanics: A new approach to hadron structure and color confinement

    Science.gov (United States)

    Brodsky, Stanley J.; Deur, Alexandre; de Téramond, Guy F.; Dosch, Hans Günter

    2015-11-01

    A primary question in hadron physics is how the mass scale for hadrons consisting of light quarks, such as the proton, emerges from the QCD Lagrangian even in the limit of zero quark mass. If one requires the effective action which underlies the QCD Lagrangian to remain conformally invariant and extends the formalism of de Alfaro, Fubini and Furlan to light-front Hamiltonian theory, then a unique, color-confining potential with a mass parameter κ emerges. The actual value of the parameter κ is not set by the model - only ratios of hadron masses and other hadronic mass scales are predicted. The result is a nonperturbative, relativistic light-front quantum mechanical wave equation, the Light-Front Schrödinger Equation which incorporates color confinement and other essential spectroscopic and dynamical features of hadron physics, including a massless pion for zero quark mass and linear Regge trajectories with the identical slope in the radial quantum number n and orbital angular momentum L. The same light-front equations for mesons with spin J also can be derived from the holographic mapping to QCD (3+1) at fixed light-front time from the soft-wall model modification of AdS5 space with a specific dilaton profile. Light-front holography thus provides a precise relation between the bound-state amplitudes in the fifth dimension of AdS space and the boost-invariant light-front wavefunctions describing the internal structure of hadrons in physical space-time. One can also extend the analysis to baryons using superconformal algebra - 2 × 2 supersymmetric representations of the conformal group. The resulting fermionic LF bound-state equations predict striking similarities between the meson and baryon spectra. In fact, the holographic QCD light-front Hamiltonians for the states on the meson and baryon trajectories are identical if one shifts the internal angular momenta of the meson (LM) and baryon (LB) by one unit: LM = LB + 1. We also show how the mass scale κ

  6. Fermion confinement via quantum walks in (2+1)-dimensional and (3+1)-dimensional space-time

    Science.gov (United States)

    Márquez-Martín, I.; Di Molfetta, G.; Pérez, A.

    2017-04-01

    We analyze the properties of a two- and three-dimensional quantum walk that are inspired by the idea of a brane-world model put forward by Rubakov and Shaposhnikov [Phys. Lett. B 125, 136 (1983), 10.1016/0370-2693(83)91253-4]. In that model, particles are dynamically confined on the brane due to the interaction with a scalar field. We translated this model into an alternate quantum walk with a coin that depends on the external field, with a dependence which mimics a domain wall solution. As in the original model, fermions (in our case, the walker) become localized in one of the dimensions, not from the action of a random noise on the lattice (as in the case of Anderson localization) but from a regular dependence in space. On the other hand, the resulting quantum walk can move freely along the "ordinary" dimensions.

  7. Strong confinement-induced engineering of the g factor and lifetime of conduction electron spins in Ge quantum wells

    Science.gov (United States)

    Giorgioni, Anna; Paleari, Stefano; Cecchi, Stefano; Vitiello, Elisa; Grilli, Emanuele; Isella, Giovanni; Jantsch, Wolfgang; Fanciulli, Marco; Pezzoli, Fabio

    2016-12-01

    Control of electron spin coherence via external fields is fundamental in spintronics. Its implementation demands a host material that accommodates the desirable but contrasting requirements of spin robustness against relaxation mechanisms and sizeable coupling between spin and orbital motion of the carriers. Here, we focus on Ge, which is a prominent candidate for shuttling spin quantum bits into the mainstream Si electronics. So far, however, the intrinsic spin-dependent phenomena of free electrons in conventional Ge/Si heterojunctions have proved to be elusive because of epitaxy constraints and an unfavourable band alignment. We overcome these fundamental limitations by investigating a two-dimensional electron gas in quantum wells of pure Ge grown on Si. These epitaxial systems demonstrate exceptionally long spin lifetimes. In particular, by fine-tuning quantum confinement we demonstrate that the electron Landé g factor can be engineered in our CMOS-compatible architecture over a range previously inaccessible for Si spintronics.

  8. Nickel on porous silicon MSM photo-detector and quantum confinement in nanocrystallites structure as methods to reduce dark current

    Science.gov (United States)

    Zerdali, Mokhtar; Bechiri, F.; Rahmoun, I.; Adnane, M.; Sahraoui, T.; Hamzaoui, S.

    2013-03-01

    We propose in this work, contact Schottky Nickel/porous silicon (PSi) system, coupled to nanocrystallites size variation of material for a possible technique to reduce dark current. The device consists of metal- semiconductor-metal photodiode (MSM-PD). Higher barrier ΦΒ enhances the performance of MSM-PD through reduction in dark current (Is), and benefits to resolve noise from signal detection of the devices. In order to reduce much more Is, we proposed different anodization times (5-7-10 min) as method to tune the size of nanocrystallites. As result Is value was reduced to almost two orders of magnitude for 10 min etching time, and the value of Is ≈ 10-10 A. ΦΒ reached the value of 0.882 eV. Among the hypothesis suggested in the reduction of Is was the quantum confinement effects. According to Rhoderick model, the Schottky barrier height is explicitly linked to the band gap energy due to the presence of interface states. The existence of narrow nanocrystallites increased energy band gap of PSi and the Schottky barrier height, which in turn reduces Is. The photoluminescence measurements confirmed our hypothesis. Photosensitivity of the device was established by adopting the MSM configuration, and strong absorption was detected in visible range.

  9. Tamping effects and confinement time in NIF experiments

    Science.gov (United States)

    Wang, Y. M.; Cheng, B.; Kwan, T. J. T.; Merrill, F.; Cerjan, C.; Batha, S. H.

    2015-11-01

    Tamper is expected to play an important role in inertial confinement fusion capsule experiments performed at the National Ignition Facility (NIF). It is expected to increase the confinement time of thermonuclear burning (TN) in the hot spot. In this work, we study the dependence of the capsule performance with respect to the density ratio of the pusher to the hot fuel at the cold-hot interface numerically through LASNEX simulations in one-dimension. Our study shows that the dependence of the capsule performance (neutron yield) with respect to the square root of the density ratio is not linear: the sharper the interface, the higher the tamping effect and neutron yields. Our analysis indicates that the tamping factor in both NIC and NIF experiments has not been appreciable and the tamping factor on yield is less than 1.1. Thus, the tamping factor has not yet played a significant role in the current NIF ignition design. Furthermore, the confinement time in NIF experiments will be discussed. (LA-UR-15-25596).

  10. Crystallization in Micellar Cores: confinement effects and dynamics

    Science.gov (United States)

    Lund, Reidar; Zinn, Thomas; Willner, Lutz; Department of Chemistry, University of Oslo Team; Forschungszentrum Jülich Collaboration

    It is well known that liquids confined to small nanoscopic pores and droplets exhibit thermal behavior very different from bulk samples. Here we demonstrate that n-alkanes forming 2-3 nm small micellar cores are considerably affected by confinement in analogue with hard confined systems. We study micelles form by self-assembly of a series of well-defined n-Alkyl-PEO polymers in aqueous solutions. By using small-angle X-ray scattering (SAXS), densiometry and differential scanning calorimetry (DSC), we show that n-alkane exhibit a first-order phase transition i.e. melting. Correlating the structural and thermodynamic data, we find that a melting depression can be accurately described by the Gibbs-Thomson equation. ∖f1 The effect of core crystallinity on the molecular exchange kinetics is investigated using time-resolved small-angle neutron scattering (TR-SANS). We show that there are considerable entropic and enthalpic contributions from the chain packing that affect the kinetic stability of micelles. ∖pard

  11. Tunneling into a quantum confinement created by a single-step nanolithography of conducting oxide interfaces

    Science.gov (United States)

    Maniv, E.; Ron, A.; Goldstein, M.; Palevski, A.; Dagan, Y.

    2016-07-01

    A unique nanolithography technique compatible with conducting oxide interfaces, which requires a single lithographic step with no additional amorphous deposition or etching, is presented. It is demonstrated on a SrTiO3/LaAlO3 interface where a constriction is patterned in the electron liquid. We find that an additional backgating can further confine the electron liquid into an isolated island. Conductance and differential conductance measurements show resonant tunneling through the island. The data at various temperatures and magnetic fields are analyzed and the effective island size is found to be of the order of 10 nm. The magnetic field dependence suggests the absence of spin degeneracy in the island. Our method is suitable for creating superconducting and oxide-interface-based electronic devices.

  12. Effects of Confined Laser Ablation on Laser Plasma Propulsion

    Institute of Scientific and Technical Information of China (English)

    ZHENG Zhi-Yuan; ZHANG Jie; LU Xin; HAO Zuo-Qiang; XU Miao-Hua; WANG Zhao-Hua; WEI Zhi-Yi

    2005-01-01

    @@ We investigate the effects of confined laser ablation on laser plasma propulsion. Compared with planar ablation,the cavity ablation provides an effective way to obtain a large target momentum and a high coupling coefficient.When laser pukes are focused into a cavity with 1 mm diameter and 2mm depth, a high coupling coefficient is obtained. By using a glass layer to cover the cavity, the coupling coefficient is enhanced by 10 times. Meanwhile,it is found that with the increase of the target surface size, the target momentum presents a linear increase.

  13. Dielectric confinement on exciton binding energy and nonlinear optical properties in a strained Zn1-xinMgxinSe/Zn1-xoutMgxoutSe quantum well

    Institute of Scientific and Technical Information of China (English)

    J. Abraham Hudson Mark; A. John Peter

    2012-01-01

    The band offsets for a Zn1-xinMgxin Se/Zn1-xoutMgxout Se quantum well heterostructure are determined using the model solid theory.The heavy hole exciton binding energies are investigated with various Mg alloy contents.The effect of mismatch between the dielectric constants between the well and the barrier is taken into account.The dependence of the excitonic transition energies on the geometrical confinement and the Mg alloy is discussed.Non-linear optical properties are determined using the compact density matrix approach.The linear,third order non-linear optical absorption coefficient values and the refractive index changes of the exciton are calculated for different concentrations of magnesium.The results show that the occurred blue shifts of the resonant peak due to the Mg incorporation give the information about the variation of two energy levels in the quantum well width.

  14. The effect of quantum noise on multiplayer quantum game

    Institute of Scientific and Technical Information of China (English)

    Cao Shuai; Fang Mao-Fa; Zheng Xiao-Juan

    2007-01-01

    It has recently been realized that quantum strategies have a great advantage over classical ones in quantum games.However, quantum states are easily affected by the quantum noise, resulting in decoherence. In this paper, we investigate the effect of quantum noise on a multiplayer quantum game with a certain strategic space, with all players affected by the same quantum noise at the same time. Our results show that in a maximally entangled state, a special Nash equilibrium appears in the range of 0 (≤) p (≤) 0.622 (p is the quantum noise parameter), and then disappears in the range of 0.622 < p (≤) 1. Increasing the amount of quantum noise leads to the reduction of the quantum player's payoff.

  15. Shear behavior of squalane and tetracosane under extreme confinement. III. Effect of confinement on viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, S.A.; Cochran, H.D.; Cummings, P.T. [Department of Chemical Engineering, University of Tennessee, Knoxville, Tennessee 37996-2200 (United States)]|[Chemical Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6268 (United States)

    1997-12-01

    This study uses nonequilibrium molecular dynamics simulation to explore the rheology of confined liquid alkanes. Two alkanes that differ in molecular structural complexity are examined: tetracosane (C{sub 24}H{sub 50}), which is a linear alkane, and squalane (C{sub 30}H{sub 62}), which has six symmetrically placed methyl branches along a 24 carbon backbone. These model lubricants are confined between model walls that have short chains tethered to them, thus screening the wall details. This paper, the third of a three part series, compares the viscosities of the confined fluids to those of the bulk fluids. The alkanes are described by a well-documented potential model that has been shown to reproduce bulk experimental viscosity and phase equilibria measurements. Details of the simulation method, and structural information can be found in the preceding two papers of this series. The measured strain rates in these simulations range between 10{sup 8} and 10{sup 11} s{sup {minus}1}, which is typical of a number of practical applications. The confined fluids undergo extensive shear thinning, showing a power-law behavior. Comparison of results for the confined fluid to those for the bulk fluid reveal that, for the conditions examined, there is no difference between the bulk and confined viscosities for these alkanes. This observation is in contrast to experimental results at much lower strain rates (10{endash}10{sup 5} s{sup {minus}1}), which indicate the viscosities of the confined fluid to be much larger than the bulk viscosities. In making the comparison, we have carefully accounted for slip at the wall and have performed simulations of the bulk fluid at the same conditions of strain rate, temperature, and pressure as for the corresponding confined fluid. The viscosity is found to be independent of the wall spacing. The calculated power-law exponents are similar to experimentally observed values. We also note that the exponent increases with increasing density of the

  16. Observable Effects of Quantum Gravity

    CERN Document Server

    Chang, Lay Nam; Sun, Chen; Takeuchi, Tatsu

    2016-01-01

    We discuss the generic phenomenology of quantum gravity and, in particular, argue that the observable effects of quantum gravity, associated with new, extended, non-local, non-particle-like quanta, and accompanied by a dynamical energy-momentum space, are not necessarily Planckian and that they could be observed at much lower and experimentally accessible energy scales.

  17. Luminescent tunable polydots: Charge effects in confined geometry

    Science.gov (United States)

    Wijesinghe, Sidath; Maskey, Sabina; Perahia, Dvora; Grest, Gary S.

    2017-06-01

    Long-lived soft nanoparticles, formed by conjugated polymers, constitute a new class of far-from-equilibrium responsive structures for nano-medicine. Tethering ionizable groups to the polymers enables functionality. However concurrently, the ionic groups perturb the delicate balance of interactions that governs these particles. Using fully atomistic molecular dynamics simulations, this study probed the effects of charged groups tethered to poly para phenylene ethynylene substituted by alkyl groups on the polymer conformation and dynamics in confined geometry. We find that the ionizable groups affect the entire shape of the polydots and impact the conformation and dynamics of the polymer.

  18. Quantum gravitational effects on boundary

    CERN Document Server

    Park, I Y

    2016-01-01

    Quantum gravitational effects may hold the key to some of the outstanding problems in theoretical physics. In this work we analyze the perturbative quantum effects on the boundary of a gravitational system and Dirichlet boundary condtion imposed at the classical level. Our analysis reveals that for a black hole solution there exists a clash between the quantum effects and Dirichlet boundary condition: the solution of the one-particle-irreducible (1PI) action no longer obeys the Dirichlet boundary condition. The analysis also suggests that the violation of the Dirichlet boundary condition should be tied with a certain mechanism of information storage on the boundary.

  19. Quantum confinement of Bi2S3 in glass with magnetic behavior

    Directory of Open Access Journals (Sweden)

    Rajendra P. Panmand

    2013-02-01

    Full Text Available The novel Bi2S3 quantum dots (QDs glass nanosystems with unique magnetic properties have been investigated. The monodispersed QDs of size in the range of 3 to 15 nm were grown in the glass matrix. The optical study of these nanosystems clearly demonstrated the size quantization effect resulting in a pronounced band gap variation with QD size. The magnetic properties of the pristine glass and the Bi2S3 QD glass nanosystems were investigated by VSM and SQUID magnetometer. The pristine glass did not show any ferromagnetism while the Bi2S3 glass nanosystems showed significant and reproducible ferromagnetism. We also investigated the effect of the size of Bi2S3 QDs on the magnetic properties. The saturation magnetization for the 15 nm QD glass-nanosystem (124 memu/g was observed to be higher as compared to the 3nm QD glass nanosystem (58.2 memu/g. The SQUID measurement gave the excellent hysteresis up to 300K. Surprisingly, the bulk Bi2S3 powder is diamagnetic in nature but Bi2S3 quantum dots glass nanosystem showed the ferromagnetic behavior for the first time. The investigated novel QD glass-nanosystem may have a potential application in spintronic devices and most importantly, this nanosystem can be fabricated in any usable shape as per the device requirement.

  20. Modeling direct band-to-band tunneling: From bulk to quantum-confined semiconductor devices

    Energy Technology Data Exchange (ETDEWEB)

    Carrillo-Nuñez, H.; Ziegler, A.; Luisier, M.; Schenk, A. [Integrated Systems Laboratory ETH Zürich, Gloriastrasse 35, 8092 Zürich (Switzerland)

    2015-06-21

    A rigorous framework to study direct band-to-band tunneling (BTBT) in homo- and hetero-junction semiconductor nanodevices is introduced. An interaction Hamiltonian coupling conduction and valence bands (CVBs) is derived using a multiband envelope method. A general form of the BTBT probability is then obtained from the linear response to the “CVBs interaction” that drives the system out of equilibrium. Simple expressions in terms of the one-electron spectral function are developed to compute the BTBT current in two- and three-dimensional semiconductor structures. Additionally, a two-band envelope equation based on the Flietner model of imaginary dispersion is proposed for the same purpose. In order to characterize their accuracy and differences, both approaches are compared with full-band, atomistic quantum transport simulations of Ge, InAs, and InAs-Si Esaki diodes. As another numerical application, the BTBT current in InAs-Si nanowire tunnel field-effect transistors is computed. It is found that both approaches agree with high accuracy. The first one is considerably easier to conceive and could be implemented straightforwardly in existing quantum transport tools based on the effective mass approximation to account for BTBT in nanodevices.

  1. Generalized quantitative approach to nanoscale Raman spectroscopy: Scaled quantum-mechanical treatment of three-dimensional phonon confinement

    CERN Document Server

    Korepanov, Vitaly I

    2016-01-01

    Raman spectroscopy provides a well-established tool for studying crystalline/molecular systems with well-defined selection rules based on crystalline/molecular symmetries. However, its application to nanoscale matter is hindered by the lack of such well-defined selection rules. Here, we couple the phonon confinement model with a scaled quantum-chemical calculation to construct a universal and physically consistent basis for nanoscale Raman spectroscopy. Unlike the commonly used one-dimensional dispersion approach, we take into account the confinement along all three dimensions of the k-space. We apply it to diamond nanoparticles of sub-50nm size, a system with pronounced anisotropy of dispersion for which three-dimensional dispersion approach is requisite. The approach excellently reproduces size-sensitive spectral features, including the peak position, bandwidth and asymmetry of the sp3 C-C Raman band. This fundamental approach can be easily generalized to other nanocrystalline solids to hopefully contribute...

  2. Influence of Ge content and annealing conditions on the PL properties of nc-Si{sub 1−x}Ge{sub x} embedded in SiO{sub 2} matrix in weak quantum confined regime

    Energy Technology Data Exchange (ETDEWEB)

    Tuğay, Evrin, E-mail: evrin.tugay@erdogan.edu.tr [Department of Mechanical Engineering, Faculty of Engineering, Recep Tayyip Erdogan University, Rize 53100 (Turkey); Ilday, Serim [Department of Micro and Nanotechnology, Middle East Technical University, Ankara (Turkey); Center of Solar Energy Research and Application (GÜNAM), Middle East Technical University (METU), 06531 Ankara (Turkey); Turan, Raşit [Center of Solar Energy Research and Application (GÜNAM), Middle East Technical University (METU), 06531 Ankara (Turkey); Department of Physics, Middle East Technical University, Ankara (Turkey); Finstad, Treje G. [Department of Physics, University of Oslo, Oslo (Norway)

    2014-11-15

    Fabrication of Si (nc-Si), Ge (nc-Ge), and Si{sub 1−x}Ge{sub x} (nc-Si{sub 1−x}Ge{sub x}) nanocrystals embedded in SiO{sub 2} matrix is achieved by thermal annealing of magnetron-sputtered thin films. Effects of annealing conditions, namely duration and temperature, as well as Ge content on the photoluminescence properties are investigated. Origin and evolution of the photoluminescence signal in the weak quantum confinement regime are discussed. It is found that photoluminescence signals can be decomposed into four Gaussian peaks originating from Ge-related radiative defects located at the sub-oxide (GeO{sub x}), either inside the matrix or at the interface region (peak M), nc-Si{sub 1−x}Ge{sub x}/SiO{sub 2} interface-related localized states (peak I), localized states in the amorphous Si{sub 1−x}Ge{sub x} bandgap (peak A) and quantum confinement of excitons in small nanocrystals (peak Q). The role of small and large nanocrystals in the photoluminescence mechanism is investigated by varying the mean nanocrystal size from 3 nm to 23 nm (from strong to weak quantum confined regime). Our results demonstrate that the quantum confinement effect in Ge nanocrystals manifests though spectral blueshift due to increase in Ge content. We also propose that the decreasing photoluminescence signal intensity with an increase in Ge content may originate from Ge-related nonradiative P{sub b} centers. - Highlights: • Origin and evolution of PL in weak quantum confinement regime are investigated. • It is necessary to distinguish between the role of smaller and larger nanocrystals. • Blueshift and PL quenching by incorporation of more Ge atoms has been observed.

  3. Synergetic effects of interfacial and spatial confinement in polymer nanocomposites

    Science.gov (United States)

    Zhao, Weiwei; Su, Yunlan; Wang, Dujin

    2017-08-01

    Dispersing three-dimensional (3D) nanoparticles as the filler into a polymeric component is known to significantly improve the physicochemical properties of the materials and makes them attractive for industrial applications. There are two main contributions to the underlying enhancement mechanism of polymer nanocomposites (PNCs). The first contribution is linked to the interfacial effect, originating from the interaction between polymer and nanoparticles. The packing density, conformation and orientation of adsorbed chains are significantly altered, which results in an interfacial region with different properties from the bulk. The second contribution is attributed to the spatial effect, introduced by confining polymer chains in a restricted space between/among nanoparticles. These two effects are often correlated. The characteristic behavior of polymer chains confined by nanoparticles has already shown to be quite complicated and hence interesting as compared with that of pure polymers. The broad range of influencing factors including the size, content and surface chemistry of nanoparticles as well as the molecular weight and chain ends of polymers were discussed in this review. The controversial issues such as the segmental dynamics at interface, interfacial architecture and the extent of its impact on the bulk phase were summarized, wishing to produce further understanding of PNCs.

  4. Effects of external fields, dimension and polarization on the resonance fluorescence of quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Vaseghi, B., E-mail: vaseghi@mail.yu.ac.ir; Razavi, S.M.

    2017-02-01

    In this paper simultaneous effects of external electric and magnetic fields, dimension and polarization on the resonance fluorescence spectrum and photon statistics of a spherical quantum dot with parabolic confinement are investigated. With special attention to the optical scattering processes resonance fluorescence spectrum and second-order correlation function are calculated and plotted for different external parameters. Our results show the occurrence of resonance fluorescence similar to atomic systems and considerable effects of external fields, quantum confinement and light polarization on the resonance fluorescence spectrum and second-order correlation function in the quantum dot systems. The existence of Mollow triplets and photon antibunching are strongly depend on these external agents.

  5. Effects of external fields, dimension and polarization on the resonance fluorescence of quantum dots

    Science.gov (United States)

    Vaseghi, B.; Razavi, S. M.

    2017-02-01

    In this paper simultaneous effects of external electric and magnetic fields, dimension and polarization on the resonance fluorescence spectrum and photon statistics of a spherical quantum dot with parabolic confinement are investigated. With special attention to the optical scattering processes resonance fluorescence spectrum and second-order correlation function are calculated and plotted for different external parameters. Our results show the occurrence of resonance fluorescence similar to atomic systems and considerable effects of external fields, quantum confinement and light polarization on the resonance fluorescence spectrum and second-order correlation function in the quantum dot systems. The existence of Mollow triplets and photon antibunching are strongly depend on these external agents.

  6. Quantum Effects in Cosmology

    Science.gov (United States)

    Saharian, A. A.

    2016-09-01

    We investigate the vacuum expectation value of the current density for a charged scalar field on a slice of anti-de Sitter (AdS) space with toroidally compact dimensions. Along the compact dimensions periodicity conditions are imposed on the field operator with general phases and the presence of a constant gauge field is assumed. The latter gives rise to Aharonov-Bohm-like effects on the vacuum currents. The current density along compact dimensions is a periodic function of the gauge field flux with the period equal to the flux quantum. It vanishes on the AdS boundary and, near the horizon, to the leading order, it is conformally related to the corresponding quantity in Minkowski bulk for a massless field. For large values of the length of the compact dimension compared with the AdS curvature radius, the vacuum current decays as power-law for both massless and massive fields. This behavior is essentially different from the corresponding one in Minkowski background, where the currents for a massive field are suppressed exponentially.

  7. Screening effects on structure and diffusion in confined charged colloids.

    Science.gov (United States)

    Kittner, Madeleine; Klapp, Sabine H L

    2007-04-21

    Using molecular dynamics computer simulations we investigate structural and dynamic (diffusion) properties of charged colloidal suspension confined to narrow slit pores with structureless, uncharged walls. The system is modeled on an effective level involving only the macroions, which interact via a combination of a soft-sphere and a screened Coulomb potential. The aim of our study is to identify the role of the range of the macroion-macroion interaction controlled by the inverse Debye screening length, kappa. We also compare to bulk properties at the same chemical potential as determined in parallel grand canonical Monte Carlo simulations. Our results reveal a significant influence of the interaction range which competes, however, with the influence of density. At liquidlike densities a decrease of range yields a decreasing mobility (and a corresponding enhancement of local structure) in the bulk system, whereas the reverse effect occurs in narrow slits with thickness of a few particle diameter. These differences can be traced back to the confinement-induced, and kappa-dependent, reduction of overall density compared to the bulk reservoir. We also show that an increase of kappa softens the oscillations in the normal pressure as function of the wall separation, which is consistent with experimental observations concerning the influence of addition of salt.

  8. Piezo-Phototronic Effect in a Quantum Well Structure.

    Science.gov (United States)

    Huang, Xin; Du, Chunhua; Zhou, Yongli; Jiang, Chunyan; Pu, Xiong; Liu, Wei; Hu, Weiguo; Chen, Hong; Wang, Zhong Lin

    2016-05-24

    With enhancements in the performance of optoelectronic devices, the field of piezo-phototronics has attracted much attention, and several theoretical works have been reported based on semiclassical models. At present, the feature size of optoelectronic devices are rapidly shrinking toward several tens of nanometers, which results in the quantum confinement effect. Starting from the basic piezoelectricity equation, Schrödinger equation, Poisson equation, and Fermi's golden rule, a self-consistent theoretical model is proposed to study the piezo-phototronic effect in the framework of perturbation theory in quantum mechanics. The validity and universality of this model are well-proven with photoluminescence measurements in a single GaN/InGaN quantum well and multiple GaN/InGaN quantum wells. This study provides important insight into the working principle of nanoscale piezo-phototronic devices as well as guidance for the future device design.

  9. Evaluation of confinement effects in zeolites under Henry's adsorption regime

    Science.gov (United States)

    Pera-Titus, Marc; Llorens, Joan

    2010-06-01

    This paper provides a detailed thermodynamic analysis of gas/vapour adsorption in zeolites at low pressures. At these conditions, we show first that Henry's isotherm can be conveniently rewritten using the thermodynamic isotherm model developed in a previous study [J. Llorens, M. Pera-Titus, Description of gas adsorption on microporous materials: evaluation of energy heterogeneity, J. Colloid Interface Sci. 331, 2009, 302-311], linking the integral free energy of adsorption relative to saturation, Ψ/ RT, expressed as a Kiselev integral, with the variable Z = 1/-ln( Π), being Π the relative pressure. Relevant information about sorbate confinement effects in zeolites can be inferred using strong sorbates under Henry's adsorption regime using the thermodynamic formulation provided here. The confining level of zeolites can be characterized by a parameter ( m1), whose value depends on the zeolite framework, but remains essentially unchanged with the sorbate probe molecule and temperature. We illustrate the application of these concepts using a collection of MFI and MTW-type zeolites as model systems.

  10. Schwinger Effect and Entanglement Entropy in Confining Geometries

    CERN Document Server

    Ghodrati, Mahdis

    2015-01-01

    Using AdS/CFT, we study the critical electric field, the rate of Schwinger pair creation and the phase diagram of the total potential versus the distance between the quark and anti quark in four confining supergravity backgrounds which are the Witten QCD, the Maldacena-Nunez, the Klebanov-Tseytlin and the Klebanov-Strassler models. We find the three phases in each geometry and we show the differences and similarities of the phase diagram for these models. For comparing the results with the conformal case, we also study the Klebanov-Witten geometry. We then study the phase diagram of the entanglement entropy of a strip in these specific confining geometries and find the predicted butterfly shape in the diagram of the entanglement entropy. Then by using the imaginary part of the Euler-Heisenberg effective Lagrangian, we study the rate of pair creation in the presence of a magnetic field. We show that in all of these geometries, increasing the parallel magnetic field would increase the pair creation rate and inc...

  11. Hydrodynamic Boundary Effects on Thermophoresis of Confined Colloids

    Science.gov (United States)

    Würger, Alois

    2016-04-01

    We study hydrodynamic slowing down of a particle moving in a temperature gradient perpendicular to a wall. At distances much smaller than the particle radius, h ≪a , the lubrication approximation leads to the reduced velocity u /u0=3 (h /a )[ln (a /h )-9/4 ] , where u0 is the velocity in the bulk. With Brenner's result for confined diffusion, we find that the trapping efficiency, or effective Soret coefficient, increases logarithmically as the particle gets very close to the wall. Our results provide a quantitative explanation for the recently observed enhancement of thermophoretic trapping at short distances. Our discussion of parallel and perpendicular thermophoresis in a capillary reveals a good agreement with experiments on charged polystyrene particles, and sheds some light on a controversy concerning the size dependence and the nonequilibrium nature of the Soret effect.

  12. Effective boson-spin model for nuclei ensemble based universal quantum memory

    CERN Document Server

    Song, Z; Shi, T; Sun, C P

    2004-01-01

    We study the collective excitation of a macroscopic ensemble of polarized nuclei fixed in a quantum dot. Under the approximately homogeneous condition that we explicitly present in this paper, this many-particle system behaves as a single mode boson interacting with the spin of a single conduction band electron confined in this quantum dot. Within this effective spin-boson system, the quantum information carried by the electronic spin can be coherently transferred into the collective bosonic mode of excitation in the ensemble of nuclei. In this sense, the collective bosonic excitation can serve as a stable quantum memory to store the quantum information of spin state of electron.

  13. Influence of Aging and Environment on Nanoparticle Chemistry: Implication to Confinement Effects in Nanoceria

    Energy Technology Data Exchange (ETDEWEB)

    Kuchibhatla, Satyanarayana V N T; Karakoti, Ajay S.; Baer, Donald R.; Samudrala, Saritha; Engelhard, Mark H.; Amonette, James E.; Thevuthasan, Suntharampillai; Seal, Sudipta

    2012-07-05

    The oxidation state switching of cerium in cerium oxide nanoparticles is studied in detail. The influence of synthesis medium, aging time and local environment on the oxidation state switching, between +3 and + 4, is analyzed by tracking the absorption edge using UV-Visible spectroscopy. It is observed that by tuning the local environment, the chemistry of the nanoparticles could be altered. These time dependent, environmentally induced changes likely contribute to inconsistencies in the literature regarding quantum-confinement effects for ceria nanoparticles. The results in this article indicate that there is a need to carry out comprehensive analysis of nanoparticles while considering the influence of synthesis and processing conditions, aging time and local environment.

  14. High-temperature quantum kinetic effect in silicon nanosandwiches

    Science.gov (United States)

    Bagraev, N. T.; Grigoryev, V. Yu.; Klyachkin, L. E.; Malyarenko, A. M.; Mashkov, V. A.; Romanov, V. V.; Rul, N. I.

    2017-01-01

    The negative-U impurity stripes confining the edge channels of semiconductor quantum wells are shown to allow the effective cooling inside in the process of the spin-dependent transport, with the reduction of the electron-electron interaction. The aforesaid promotes also the creation of composite bosons and fermions by the capture of single magnetic flux quanta on the edge channels under the conditions of low sheet density of carriers, thus opening new opportunities for the registration of the quantum kinetic phenomena in weak magnetic fields at high-temperatures up to the room temperature. As a certain version noted above we present the first findings of the high temperature de Haas-van Alphen, 300 K, quantum Hall, 77 K, effects as well as quantum conductance staircase in the silicon sandwich structure that represents the ultra-narrow, 2 nm, p-type quantum well (Si-QW) confined by the delta barriers heavily doped with boron on the n-type Si (100) surface.

  15. Effect of density changes on tokamak plasma confinement

    CERN Document Server

    Spineanu, F

    2015-01-01

    A change of the particle density (by gas puff, pellets or impurity seeding) during the plasma discharge in tokamak produces a radial current and implicitly a torque and rotation that can modify the state of confinement. After ionization the newly born ions will evolve toward the periodic neoclassical orbits (trapped or circulating) but the first part of their excursion, which precedes the periodicity, is an effective radial current. It is short, spatially finite and unique for each new ion, but multiplied by the rate of ionization and it can produce a substantial total radial current. The associated torque induces rotation which modify the transport processes. We derive the magnitude of the radial current induced by ionization by three methods: the analysis of a simple physical picture, a numerical model and the neoclassical drift-kinetic treatment. The results of the three approaches are in agreement and show that the current can indeed be substantial. Many well known experimental observations can be reconsi...

  16. Lorentz-covariant quantum 4-potential and orbital angular momentum for the transverse confinement of matter waves

    Science.gov (United States)

    Ducharme, R.; da Paz, I. G.

    2016-08-01

    In two recent papers exact Hermite-Gaussian solutions to relativistic wave equations were obtained for both electromagnetic and particle beams. The solutions for particle beams correspond to those of the Schrödinger equation in the nonrelativistic limit. Here, it will be shown that each beam particle has additional 4-momentum resulting from transverse localization compared to a free particle traveling in the same direction as the beam with the same speed. This will be referred to as the quantum 4-potential term since it will be shown to play an analogous role in relativistic Hamiltonian quantum mechanics as the Bohm potential in the nonrelativistic quantum Hamilton-Jacobi equation. Low-order localization effects include orbital angular momentum, Gouy phase, and beam spreading. Toward a more systematic approach for calculating localization effects at all orders, it will be shown that both the electromagnetic and quantum 4-potentials couple into the canonical 4-momentum of a particle in a similar way. This offers the prospect that traditional methods used to calculate the affect of an electromagnetic field on a particle can now be adapted to take localization effects into account. The prospects for measuring higher order quantum 4-potential related effects experimentally are also discussed alongside some questions to challenge the quantum information and quantum field theorists.

  17. Low-Energy Charge and Spin Dynamics in Quantum Confined Systems

    Science.gov (United States)

    Rice, William D.

    Condensed matter systems exhibit a variety of dynamical phenomena at low energy scales, from gigahertz (GHz) to terahertz (THz) frequencies in particular, arising from complex interplay between charge, spin, and lattice. A large number of collective and elementary excitations in solids occur in this frequency range, which are further modified and enriched by scattering, interactions, and disorder. Recent advancements in spectroscopic methods for probing low-energy dynamics allow us to investigate novel aspects of charge and spin dynamics in solids. In this dissertation work, we used direct current (DC) conductivity, GHz, THz, and mid-infrared (MIR) techniques to provide significant new insights into interaction and disorder effects in low-dimensional systems. Specifically, we have studied temperature-dependent magnetoresistance (MR) and electron spin resonance (ESR) in single-wall carbon nanotubes (SWCNTs), intra-exciton scattering in InGaAs quantum wells, and high-field MIR-induced band gaps in graphene. Temperature-dependent resistance and MR were measured in an ensemble of SWCNTs from 0.3 to 350 K. The resistance temperature behavior followed a 3D variable range hopping (VRH) behavior from 0.3 to ˜100 K. A positive MR was observed at temperatures above 25 K and could be fit with a spin-dependent VRH model; negative MR was seen at low temperatures. In the GHz regime, the ESR linewidth for SWCNTs was observed to narrow by as much as 50% as the temperature was increased from 3 to 300 K, a phenomenon known as motional narrowing, suggesting that we are detecting the ESR of hopping spins. From the linewidth change versus temperature, we find the hopping frequency to be 285 GHz. For excitons in InGaAs quantum wells, we demonstrate the manipulation of intra-excitonic populations using intense, narrow-band THz pulses. The THz radiation temporarily quenches the 1s emission, which is then followed by an enhancement and subsequent decay of 2s emission. After the quenching

  18. Sandwiched confinement of quantum dots in graphene matrix for efficient electron transfer and photocurrent production.

    Science.gov (United States)

    Zhu, Nan; Zheng, Kaibo; Karki, Khadga J; Abdellah, Mohamed; Zhu, Qiushi; Carlson, Stefan; Haase, Dörthe; Žídek, Karel; Ulstrup, Jens; Canton, Sophie E; Pullerits, Tõnu; Chi, Qijin

    2015-05-21

    Quantum dots (QDs) and graphene are both promising materials for the development of new-generation optoelectronic devices. Towards this end, synergic assembly of these two building blocks is a key step but remains a challenge. Here, we show a one-step strategy for organizing QDs in a graphene matrix via interfacial self-assembly, leading to the formation of sandwiched hybrid QD-graphene nanofilms. We have explored structural features, electron transfer kinetics and photocurrent generation capacity of such hybrid nanofilms using a wide variety of advanced techniques. Graphene nanosheets interlink QDs and significantly improve electronic coupling, resulting in fast electron transfer from photoexcited QDs to graphene with a rate constant of 1.3 × 10(9) s(-1). Efficient electron transfer dramatically enhances photocurrent generation in a liquid-junction QD-sensitized solar cell where the hybrid nanofilm acts as a photoanode. We thereby demonstrate a cost-effective method to construct large-area QD-graphene hybrid nanofilms with straightforward scale-up potential for optoelectronic applications.

  19. Sandwiched confinement of quantum dots in graphene matrix for efficient electron transfer and photocurrent production

    Science.gov (United States)

    Zhu, Nan; Zheng, Kaibo; Karki, Khadga J.; Abdellah, Mohamed; Zhu, Qiushi; Carlson, Stefan; Haase, Dörthe; Žídek, Karel; Ulstrup, Jens; Canton, Sophie E.; Pullerits, Tõnu; Chi, Qijin

    2015-05-01

    Quantum dots (QDs) and graphene are both promising materials for the development of new-generation optoelectronic devices. Towards this end, synergic assembly of these two building blocks is a key step but remains a challenge. Here, we show a one-step strategy for organizing QDs in a graphene matrix via interfacial self-assembly, leading to the formation of sandwiched hybrid QD-graphene nanofilms. We have explored structural features, electron transfer kinetics and photocurrent generation capacity of such hybrid nanofilms using a wide variety of advanced techniques. Graphene nanosheets interlink QDs and significantly improve electronic coupling, resulting in fast electron transfer from photoexcited QDs to graphene with a rate constant of 1.3 × 109 s-1. Efficient electron transfer dramatically enhances photocurrent generation in a liquid-junction QD-sensitized solar cell where the hybrid nanofilm acts as a photoanode. We thereby demonstrate a cost-effective method to construct large-area QD-graphene hybrid nanofilms with straightforward scale-up potential for optoelectronic applications.

  20. Quantum effects near future singularities

    CERN Document Server

    Barrow, John D; Dito, Giuseppe; Fabris, Julio C; Houndjo, Mahouton J S

    2012-01-01

    General relativity allows a variety of future singularities to occur in the evolution of the universe. At these future singularities, the universe will end in a singular state after a finite proper time and geometrical invariants of the space time will diverge. One question that naturally arises with respect to these cosmological scenarios is the following: can quantum effects lead to the avoidance of these future singularities? We analyze this problem considering massless and conformally coupled scalar fields in an isotropic and homogeneous background leading to future singularities. It is shown that near strong, big rip-type singularities, with violation of the energy conditions, the quantum effects are very important, while near some milder classes of singularity like the sudden singularity, which preserve the energy conditions, quantum effects are irrelevant.

  1. CONFINING PRESSURE EFFECT ON ACOUSTIC EMISSIONS IN ROCK FAILURE

    Institute of Scientific and Technical Information of China (English)

    陈忠辉; 唐春安; 傅宇方

    1998-01-01

    Based on the phenomenon that acoustic emissions (AE) generated by rock massincreas uddenly because of underground excavation, time sequence of AE rate in rock failurehas been discussed by using statistical damage theory. It has been demonstrated that how theinfluence of confining pressure on the deformation behavior and AE characteristics in rocks can beinferred from a simple mechanics model. The results show that loading confining pressure sharplybrings out increasing of AE. On the other hand, few AE emits when confining pressure is loadedsharply, and AE occurs again when axial pressure keeps on increasing. These results have beenwell simulated with computer and show close correspondence with directly measured curves" inexperiments.

  2. Long-wavelength oxide-confined VCSEL using InGaAsN quantum wells

    Science.gov (United States)

    Lai, H. C.; Pan, J. S.; Li, Alice C. F.; Tang, M. C.; Wu, C. C.; Lee, Tsin-Dong; Huang, K. F.

    2004-05-01

    Characteristics of oxide-confined vertical-cavity surface emitting laser emitting at 1289nm will be presented in this paper. The wafer is monolithically grown using InGaAsN/GaAs QWs as active layer and GaAs/AlGaAs conventional DBRs. In the structure, the laser employs 39 pairs N-GaAs/Al0.9GaAs and 23 pairs P-GaAs/Al0.9GaAs with a selectively oxide layer located at first DBR close to active region, providing the current and optical confinement. The device processing is similar to the fabrication for current 850nm oxVCSELs. Mesa etching is used to expose the Al-rich AlGaAs layer and followed by oxidation to form the current confinement. The maximum light output power is around 950uW at room temperature under CW operation with a threshold current around 6mA for 10um aperture size devices. The device can still lase at 1000C with a maximum power of 0.14mW. Slope efficiency is 0.133(W/A) and side mode suppression ratio (SMSR) is around 20dB at 10mA operation. The aging data and speed transmission experimental data will also be presented.

  3. Confinement and Sleep Deprivation Effects on Propensity to Take Risks

    National Research Council Canada - National Science Library

    Chaumet, Guillaume; Taillard, Jacques; Sagaspe, Patricia; Pagani, Massimo; Dinges, David F; Pavy-Le-Traon, Anne; Bareille, Marie-Pierre; Rascol, Olivier; Philip, Pierre

    2009-01-01

    ...: a 7-d confined period (CONF) or a 7-d baseline (BASE) condition preceding one control night of normal sleep, one night of sleep deprivation, and one recovery night in the laboratory. Risk propensity (EVAR scale...

  4. Schwinger effect and entanglement entropy in confining geometries

    Science.gov (United States)

    Ghodrati, Mahdis

    2015-09-01

    By using AdS /CFT , we study the critical electric field, the Schwinger pair creation rate and the potential phase diagram for the quark and antiquark in four confining supergravity backgrounds which are the Witten QCD (WQCD), the Maldacena-Nunez (MN), the Klebanov-Tseytlin (KT) and the Klebanov-Strassler (KS) models. We compare the rate of phase transition in these models and compare it also with the conformal case. We then present the phase diagrams of the entanglement entropy of a strip in these geometries and find the predicted butterfly shape in the diagrams. We found that the phase transitions have a higher rate in WQCD and KT relative to MN and KS. Finally we show the effect of turning on an additional magnetic field on the rate of pair creation by using the imaginary part of the Euler-Heisenberg effective Lagrangian. The result is increasing the parallel magnetic field would increase the pair creation rate and increasing the perpendicular magnetic field would decrease the rate.

  5. Efficient, High-Speed, Monolithic Optoelectronic Circuits Using Quantum- Confined Structures

    Science.gov (United States)

    1991-07-25

    made to optimize the ridge-waveguide laser fabrication process by working on GaAs and In0.2Ga0.sAs single quantum- laser monitoring and polyimidc...with and without a SSL active layer. Because the SSL laser samples are precious, a special effort has been made to optimize the ridge-waveguide laser ... fabrication process by working on GaAs and Ino.2Ga0.sAs single quantum- 20 well SCH structures. It is found that the choice among SiQz, SixNy and

  6. Photonic transistor and router using a single quantum-dot-confined spin in a single-sided optical microcavity.

    Science.gov (United States)

    Hu, C Y

    2017-03-28

    The future Internet is very likely the mixture of all-optical Internet with low power consumption and quantum Internet with absolute security guaranteed by the laws of quantum mechanics. Photons would be used for processing, routing and com-munication of data, and photonic transistor using a weak light to control a strong light is the core component as an optical analogue to the electronic transistor that forms the basis of modern electronics. In sharp contrast to previous all-optical tran-sistors which are all based on optical nonlinearities, here I introduce a novel design for a high-gain and high-speed (up to terahertz) photonic transistor and its counterpart in the quantum limit, i.e., single-photon transistor based on a linear optical effect: giant Faraday rotation induced by a single electronic spin in a single-sided optical microcavity. A single-photon or classical optical pulse as the gate sets the spin state via projective measurement and controls the polarization of a strong light to open/block the photonic channel. Due to the duality as quantum gate for quantum information processing and transistor for optical information processing, this versatile spin-cavity quantum transistor provides a solid-state platform ideal for all-optical networks and quantum networks.

  7. Photonic transistor and router using a single quantum-dot-confined spin in a single-sided optical microcavity

    Science.gov (United States)

    Hu, C. Y.

    2017-01-01

    The future Internet is very likely the mixture of all-optical Internet with low power consumption and quantum Internet with absolute security guaranteed by the laws of quantum mechanics. Photons would be used for processing, routing and com-munication of data, and photonic transistor using a weak light to control a strong light is the core component as an optical analogue to the electronic transistor that forms the basis of modern electronics. In sharp contrast to previous all-optical tran-sistors which are all based on optical nonlinearities, here I introduce a novel design for a high-gain and high-speed (up to terahertz) photonic transistor and its counterpart in the quantum limit, i.e., single-photon transistor based on a linear optical effect: giant Faraday rotation induced by a single electronic spin in a single-sided optical microcavity. A single-photon or classical optical pulse as the gate sets the spin state via projective measurement and controls the polarization of a strong light to open/block the photonic channel. Due to the duality as quantum gate for quantum information processing and transistor for optical information processing, this versatile spin-cavity quantum transistor provides a solid-state platform ideal for all-optical networks and quantum networks. PMID:28349960

  8. Temperature independent Seebeck coefficient through quantum confinement modulation in amorphous Nb-O/Ni-Ta-O multilayers

    Science.gov (United States)

    Music, Denis; Hunold, Oliver; Coultas, Sarah; Roberts, Adam

    2017-05-01

    Employing a correlative experimental and theoretical methodology, we have investigated amorphous monoxide Nb-O/Ni-Ta-O multilayers. It is feasible to obtain a temperature independent Seebeck coefficient up to 500 °C for these metallic-like conductors, attaining -25 μV K-1. While Nb and Ta strongly interact with O, Ni experiences the metallic and monoxide-like bonding. We observe a 3 eV wide region below the Fermi level convoluted through several first nearest neighbor Ni - Ni and second nearest neighbor Nb - Nb interactions resulting in many confined states. It can be proposed that by increasing temperature these modulated quantum states gradually become thermally accessible eradicating the temperature dependence of the Seebeck coefficient.

  9. Density matrix for an electron confined in quantum dots under uniform magnetic field and static electrical field

    Institute of Scientific and Technical Information of China (English)

    Pang Qian-Jun

    2007-01-01

    Using unitary transformations, this paper obtains the eigenvalues and the common eigenvector of Hamiltonian and a new-defined generalized angular momentum (Lz) for an electron confined in quantum dots under a uniform magnetic field (UMF) and a static electric field (SEF). It finds that the eigenvalue of Lz just stands for the expectation value of a usual angular momentum lz in the eigen-state. It first obtains the matrix density for this system via directly calculating a transfer matrix element of operator exp(-βH) in some representations with the technique of integral within an ordered products (IWOP) of operators, rather than via solving a Bloch equation. Because the quadratic homogeneity of potential energy is broken due to the existence of SEF, the virial theorem in statistical physics is not satisfactory for this system, which is confirmed through the calculation of thermal averages of physical quantities.

  10. Effective Constraints for Quantum Systems

    CERN Document Server

    Bojowald, Martin; Skirzewski, Aureliano; Tsobanjan, Artur

    2008-01-01

    An effective formalism for quantum constrained systems is presented which allows manageable derivations of solutions and observables, including a treatment of physical reality conditions without requiring full knowledge of the physical inner product. Instead of a state equation from a constraint operator, an infinite system of constraint functions on the quantum phase space of expectation values and moments of states is used. The examples of linear constraints as well as the free non-relativistic particle in parameterized form illustrate how standard problems of constrained systems can be dealt with in this framework.

  11. Hole confinement and dynamics in delta-doped Ge quantum dots

    NARCIS (Netherlands)

    Halsall, M. P.; Dunbar, A. D. F.; Shiraki, Y.; Miura, M.; Wells, J. P. R.

    2004-01-01

    We report picosecond pump-probe studies of the dynamics of inter-level transitions in p-type Ge quantum dot structures using a free electron laser as a source of intense mid-infrared pulses. The wavelength-independent lifetime of around 210 ps is much longer than have been recently reported in SiGe/

  12. Intrinsic optical confinement for ultrathin InAsN quantum well superlattices

    Energy Technology Data Exchange (ETDEWEB)

    Sakri, A.; Robert, C.; Pedesseau, L.; Cornet, C.; Durand, O.; Even, J.; Jancu, J.-M. [Université Europeenne de Bretagne, INSA Rennes,France and CNRS, UMR 6082, Foton, 20 avenues des Buttes de Coësmes, 35708 Rennes (France)

    2013-12-04

    We study energy-band engineering with InAsN monolayer in GaAs/GaP quantum well structure. A tight-binding calculation indicates that both type I alignment along with direct band-gap behavior can be obtained. We show that the optical transitions are less sensitive to the position of the probe.

  13. Quantum effects in warp drives

    Directory of Open Access Journals (Sweden)

    Finazzi Stefano

    2013-09-01

    Full Text Available Warp drives are interesting configurations that, at least theoretically, provide a way to travel at superluminal speed. Unfortunately, several issues seem to forbid their realization. First, a huge amount of exotic matter is required to build them. Second, the presence of quantum fields propagating in superluminal warp-drive geometries makes them semiclassically unstable. Indeed, a Hawking-like high-temperature flux of particles is generated inside the warp-drive bubble, which causes an exponential growth of the energy density measured at the front wall of the bubble by freely falling observers. Moreover, superluminal warp drives remain unstable even if the Lorentz symmetry is broken by the introduction of regulating higher order terms in the Lagrangian of the quantum field. If the dispersion relation of the quantum field is subluminal, a black-hole laser phenomenon yields an exponential amplification of the emitted flux. If it is superluminal, infrared effects cause a linear growth of this flux.

  14. Quantum channels and memory effects

    Science.gov (United States)

    Caruso, Filippo; Giovannetti, Vittorio; Lupo, Cosmo; Mancini, Stefano

    2014-10-01

    Any physical process can be represented as a quantum channel mapping an initial state to a final state. Hence it can be characterized from the point of view of communication theory, i.e., in terms of its ability to transfer information. Quantum information provides a theoretical framework and the proper mathematical tools to accomplish this. In this context the notion of codes and communication capacities have been introduced by generalizing them from the classical Shannon theory of information transmission and error correction. The underlying assumption of this approach is to consider the channel not as acting on a single system, but on sequences of systems, which, when properly initialized allow one to overcome the noisy effects induced by the physical process under consideration. While most of the work produced so far has been focused on the case in which a given channel transformation acts identically and independently on the various elements of the sequence (memoryless configuration in jargon), correlated error models appear to be a more realistic way to approach the problem. A slightly different, yet conceptually related, notion of correlated errors applies to a single quantum system which evolves continuously in time under the influence of an external disturbance which acts on it in a non-Markovian fashion. This leads to the study of memory effects in quantum channels: a fertile ground where interesting novel phenomena emerge at the intersection of quantum information theory and other branches of physics. A survey is taken of the field of quantum channels theory while also embracing these specific and complex settings.

  15. Making the Tg-Confinement Effect Disappear in Thin Polystyrene Films: Good Physics vs. Inappropriate Analysis

    Science.gov (United States)

    Torkelson, John; Chen, Lawrence

    2013-03-01

    The Tg-confinement effect in polymers was first characterized in supported polystyrene (PS) films by Keddie et al. in 1994. Since then, many researchers have shown that (pseudo-)thermodynamic Tg measurements of supported PS films taken on cooling consistently yield the same qualitative results, with a decrease from bulk Tg beginning at 40-60 nm thickness and becoming very strong below 20 nm thickness. Some quantitative differences have been noted between studies, which may be ascribed to measurement method or the analysis employed. In 2004, we showed that the Tg-confinement effect in PS may be suppressed by adding several wt% of small-molecule diluents such as dioctyl phthalate. Recently, Kremer and co-workers (Macromolecules 2010, 43, 9937) reported that there was no Tg-confinement in supported PS films based on an analysis of the second derivative of ellipsometry data and use of a ninth order polynomial fit. Here, we demonstrate a new method for suppressing the Tg-confinement effect. In particular, PS made by emulsion polymerization yields no Tg-confinement effect as measured by ellipsometry or fluorescence, while PS made by anionic or conventional free radical polymerization yield strong Tg-confinement effects. The difference is hypothesized to result from surfactant in the emulsion polymerized PS. We also show that the absence of the Tg-confinement effect reported by Kremer is due to inappropriate analysis of ellipsometry data and that correct analysis yields Tg-confinement effects.

  16. The optical gain and radiative current density of GaInNAs/GaAs/AlGaAs separate confinement heterostructure quantum well lasers

    Science.gov (United States)

    Wu, Shudong; Cao, Yongge; Tomić, Stanko; Ishikawa, Fumitaro

    2010-01-01

    The optical gain and radiative current density of GaInNAs/GaAs/AlGaAs separate confinement heterostructure quantum well (QW) lasers with an emission wavelength of 1.3 μm have been theoretically investigated. The effect of carrier leakage from the GaInNAs QW to the GaAs waveguide layer is studied, and its influence on the optical gain and radiative current density is identified. The hole filling caused by an injected carrier has a strong impact on the optical gain and radiative current density, while the effect of electron filling is negligible, reflecting the smaller band-gap discontinuity in the valence band than in the conduction band. Hole occupation in the waveguide layer decreases the optical gain, and increases the radiative and threshold current densities of the laser. Our calculated threshold current density (659.6 A/cm2) at T=300 K is in good agreement with the experimental value (650.9 A/cm2) reported in literature [R. Fehse et al., IEEE J. Sel. Top. Quantum Electron. 8, 801 (2002)].

  17. A new and effective method for thermostatting confined fluids

    Energy Technology Data Exchange (ETDEWEB)

    De Luca, Sergio; Todd, B. D., E-mail: btodd@swin.edu.au [Department of Mathematics, Faculty of Science, Engineering and Technology, and Centre for Molecular Simulation, Swinburne University of Technology, Melbourne, Victoria 3122 (Australia); Hansen, J. S. [DNRF Center “Glass and Time,” IMFUFA, Department of Science, Systems and Models, Roskilde University, DK-4000 Roskilde (Denmark); Daivis, Peter J. [School of Applied Sciences, RMIT University, Melbourne, Victoria 3001 (Australia)

    2014-02-07

    We present a simple thermostatting method suitable for nanoconfined fluid systems. Two conventional strategies involve thermostatting the fluid directly or employing a thermal wall that couples only the wall atoms with the thermostat. When only a thermal wall is implemented, the temperature control of the fluid is true to the actual experiment and the heat is transferred from the fluid to the walls. However, for large or complex systems it can often be computationally prohibitive to employ thermal walls. To overcome this limitation many researchers choose to freeze wall atoms and instead apply a synthetic thermostat to the fluid directly through the equations of motion. This, however, can have serious consequences for the mechanical, thermodynamic, and dynamical properties of the fluid by introducing unphysical behaviour into the system [Bernardi et al., J. Chem. Phys. 132, 244706 (2010)]. In this paper, we propose a simple scheme which enables working with both frozen walls and naturally thermostatted liquids. This is done by superimposing the walls with oscillating particles, which vibrate on the edge of the fluid control volume. These particles exchange energy with the fluid molecules, but do not interact with wall atoms or each other, thus behaving as virtual particles. Their displacements violate the Lindemann criterion for melting, in such a way that the net effect would not amount to an additional confining surface. One advantage over standard techniques is the reduced computational cost, particularly for large walls, since they can be kept rigid. Another advantage over accepted strategies is the opportunity to freeze complex charged walls such as β-cristobalite. The method furthermore overcomes the problem with polar fluids such as water, as thermalized charged surfaces require higher spring constants to preserve structural stability, due to the effects of strong Coulomb interactions, thus inevitably degrading the thermostatting efficiency.

  18. A new and effective method for thermostatting confined fluids

    Science.gov (United States)

    De Luca, Sergio; Todd, B. D.; Hansen, J. S.; Daivis, Peter J.

    2014-02-01

    We present a simple thermostatting method suitable for nanoconfined fluid systems. Two conventional strategies involve thermostatting the fluid directly or employing a thermal wall that couples only the wall atoms with the thermostat. When only a thermal wall is implemented, the temperature control of the fluid is true to the actual experiment and the heat is transferred from the fluid to the walls. However, for large or complex systems it can often be computationally prohibitive to employ thermal walls. To overcome this limitation many researchers choose to freeze wall atoms and instead apply a synthetic thermostat to the fluid directly through the equations of motion. This, however, can have serious consequences for the mechanical, thermodynamic, and dynamical properties of the fluid by introducing unphysical behaviour into the system [Bernardi et al., J. Chem. Phys. 132, 244706 (2010)]. In this paper, we propose a simple scheme which enables working with both frozen walls and naturally thermostatted liquids. This is done by superimposing the walls with oscillating particles, which vibrate on the edge of the fluid control volume. These particles exchange energy with the fluid molecules, but do not interact with wall atoms or each other, thus behaving as virtual particles. Their displacements violate the Lindemann criterion for melting, in such a way that the net effect would not amount to an additional confining surface. One advantage over standard techniques is the reduced computational cost, particularly for large walls, since they can be kept rigid. Another advantage over accepted strategies is the opportunity to freeze complex charged walls such as β-cristobalite. The method furthermore overcomes the problem with polar fluids such as water, as thermalized charged surfaces require higher spring constants to preserve structural stability, due to the effects of strong Coulomb interactions, thus inevitably degrading the thermostatting efficiency.

  19. Density-Gradient Theory: A Macroscopic Approach to Quantum Confinement and Tunneling in Semiconductor Devices

    Science.gov (United States)

    2011-01-01

    technological perspective, the most important quantum well is that that occurs in silicon MOSFETs ad- jacent to oxide interfaces. Because the barrier...harder to make. From the experimental (a) (b) Fig. 4.5.2 Energy band diagram and carrier profiles in the DGT ap- proximation for an n+-poly MOSFET ...device design using well-understood materials or predicting ultimate performance of some new material like graphene ). As a tactical choice for

  20. Quantum Computation with Neutral Atoms at Addressable Optical Lattice Sites and Atoms in Confined Geometries

    Science.gov (United States)

    2014-10-13

    Félix Riou, Aaron Reinhard, Laura A. Zundel, David S. Weiss. Spontaneous-emission- induced transition rates between atomic states in optical lattices...complementary technique to measure the hyperfine states at each lattice site. We developed a technique to cool atoms so that they are mostly in the vibrational ...28-Feb-2013 Approved for Public Release; Distribution Unlimited Final Report: Quantum Computation with Neutral Atoms at Addressable Optical Lattice

  1. Piezoelectric effect in InAs/InP quantum rod nanowires grown on silicon substrate

    Energy Technology Data Exchange (ETDEWEB)

    Anufriev, Roman; Chauvin, Nicolas, E-mail: nicolas.chauvin@insa-lyon.fr; Bru-Chevallier, Catherine [Université de Lyon, Institut des Nanotechnologies de Lyon (INL)-UMR5270-CNRS, INSA-Lyon, 7 avenue Jean Capelle, 69621 Villeurbanne (France); Khmissi, Hammadi [Université de Monastir, Laboratoire de Micro-Optoélectronique et Nanostructures (LMON), Faculté des Sciences, Avenue de l' environnement, 5019 Monastir (Tunisia); Naji, Khalid; Gendry, Michel [Université de Lyon, Institut des Nanotechnologies de Lyon (INL)-UMR5270-CNRS, Ecole Centrale de Lyon, 36 avenue Guy de Collongue, 69134 Ecully (France); Patriarche, Gilles [Laboratoire de Photonique et de Nanostructures (LPN), UPR20-CNRS, route de Nozay, 91460 Marcoussis (France)

    2014-05-05

    We report on the evidence of a strain-induced piezoelectric field in wurtzite InAs/InP quantum rod nanowires. This electric field, caused by the lattice mismatch between InAs and InP, results in the quantum confined Stark effect and, as a consequence, affects the optical properties of the nanowire heterostructure. It is shown that the piezoelectric field can be screened by photogenerated carriers or removed by increasing temperature. Moreover, a dependence of the piezoelectric field on the quantum rod diameter is observed in agreement with simulations of wurtzite InAs/InP quantum rod nanowire heterostructures.

  2. Piezoelectric effect in InAs/InP quantum rod nanowires grown on silicon substrate

    Science.gov (United States)

    Anufriev, Roman; Chauvin, Nicolas; Khmissi, Hammadi; Naji, Khalid; Patriarche, Gilles; Gendry, Michel; Bru-Chevallier, Catherine

    2014-05-01

    We report on the evidence of a strain-induced piezoelectric field in wurtzite InAs/InP quantum rod nanowires. This electric field, caused by the lattice mismatch between InAs and InP, results in the quantum confined Stark effect and, as a consequence, affects the optical properties of the nanowire heterostructure. It is shown that the piezoelectric field can be screened by photogenerated carriers or removed by increasing temperature. Moreover, a dependence of the piezoelectric field on the quantum rod diameter is observed in agreement with simulations of wurtzite InAs/InP quantum rod nanowire heterostructures.

  3. Nonlinear absorption coefficient and optically detected electrophonon resonance in cylindrical GaAs/AlAs quantum wires with different confined phonon models

    Science.gov (United States)

    Khoa, Doan Quoc; Phuong, Le Thi Thu; Hoi, Bui Dinh

    2017-03-01

    A quantum kinetic equation for electrons interacting with confined phonons is used to investigate the nonlinear absorption of an intense electromagnetic wave by electrons in cylindrical GaAs/AlAs quantum wires. The analytic expression for absorption coefficient is calculated for three models of confined optical phonons: the dielectric continuum (DC), hydrodynamic continuum (HC), and Huang-Zhu (HZ) models. The absorption coefficient depends on the square of the electromagnetic wave amplitude. The electrophonon resonance and optically detected electrophonon resonance (ODEPR) are observed through the absorption spectrum. The full width at half maximum (the line-width) of the ODEPR peaks is obtained by a computational method. The line-width is found to increase with increasing temperature and decrease with increasing the quantum wire radius. In particular, numerical results show that the DC and HZ models lead to a similar behaviour of electron - confined phonon interaction whereas the HC model results in a quite different one, especially at small quantum wire radius. For large quantum wire radii, above mentioned phonon models have equivalent contributions to the ODEPR line-width.

  4. Quest for Inexpensive Hydrogen Isotopic Fractionation: Do We Need 2D Quantum Confining in Porous Materials or Are Rough Surfaces Enough? The Case of Ammonia Nanoclusters.

    Science.gov (United States)

    Mella, Massimo; Curotto, E

    2016-10-05

    We study the adsorption energetics and quantum properties of the molecular hydrogen isotopes H2, D2, and T2 onto the surface of rigid ammonia nanoclusters with quantum simulations and accurate model potential energy surfaces (PES). A highly efficient diffusion Monte Carlo (DMC) algorithm for rigid rotors allowed us to accurately define zero-point adsorption energies for the three isotopes, as well as the degree of translational and rotational delocalization that each affords on the surface. From the data emerges that the quantum adsorption energy (Eads) of T2 can be up to twice the one of H2 at 0 K, suggesting the possibility of exploiting some form of solid ammonia to selectivity separate hydrogen isotopes at low temperatures (≃20 K). This is discussed by focusing on the structural motif that may be more effective for the task. The analysis of the contributions to Eads, however, surprisingly indicates that the average kinetic energy (E(kin)) and rotation energy (Erot(kin)) of T2 can also be, respectively, 2 times and 20 times higher than those of H2; this finding markedly deviates from what is predicted for hydrogen molecules inside carbon nanotubes (CNT) or metallic-organic frameworks (MOF), where E(kin) and Erot(kin) is higher for H2 due to the unavoidable effects of confinement and hindrance to its rotational motion. The rationale for these differences is provided by the geometrical distributions for the rigid rotors, which reveal an increasingly stronger coupling between rotational and translational degrees of freedom upon increasing the isotopic mass. This effect has never been observed before on adsorbing surfaces (e.g., graphite) and is induced by a strongly anisotropic and anharmonic bowl-like potential experienced by the rotors.

  5. Robust effective Zeeman energy in monolayer MoS2 quantum dots

    Science.gov (United States)

    Dias, A. C.; Fu, Jiyong; Villegas-Lelovsky, L.; Qu, Fanyao

    2016-09-01

    We report a theoretical investigation on the energy spectrum and the effective Zeeman energy (EZE) in monolayer MoS2 circular quantum dots, subjected to an out-of-plane magnetic field. Interestingly, we observe the emergence of energy-locked modes, depending on the competition between the dot confinement and the applied magnetic field, for either the highest K-valley valence band or the lowest {{K}\\prime} -valley conduction band. Moreover, an unusual dot-size-independent EZE behavior of the highest valence and the lowest conduction bands is found. Although the EZEs are insensitive to the variation of quantum confinement, both of them grow linearly with the magnetic field, similar to that in the monolayer MoS2 material. The EZEs along with their ‘robustness’ against dot confinements open opportunities of a universal magnetic control over the valley degree of freedom, for quantum dots of all sizes.

  6. Neutron confinement and the Aharonov-Casher effect

    Energy Technology Data Exchange (ETDEWEB)

    Bruce, S [Department of Physics, University of Concepcion, PO Box 160c, Concepcion (Chile)

    2005-08-05

    We determine the (bound) ground state of a spin-1/2 chargeless particle with anomalous magnetic moment in certain Aharonov-Casher configurations. We recast the description of the system in a supersymmetric form. Then the basic physical requirements for unbroken supersymmetry are established. We comment on the possibility of neutron confinement in these systems.

  7. N identical particles under quantum confinement: A many-body dimensional perturbation theory approach II, the lowest-order wave function II

    CERN Document Server

    Dunn, M; Loeser, J G

    2006-01-01

    In this paper, the second in a series of two, we complete the derivation of the lowest-order wave function of a dimensional perturbation theory (DPT) treatment for the N-body quantum-confined system. Taking advantage of the symmetry of the zeroth-order configuration, we use group theoretic techniques and the FG matrix method from quantum chemistry to obtain analytic results for frequencies and normal modes. This method directly accounts for each two-body interaction, rather than an average interaction so that even lowest-order results include beyond-mean-field effects. It is thus appropriate for the study of both weakly and strongly interacting systems and the transition between them. While previous work has focused on energies, lowest-order wave functions yield important information such as the nature of excitations and expectation values of physical observables at low orders including density profiles. Higher orders in DPT also require as input the zeroth-order wave functions. In the earlier paper we presen...

  8. Quantum confinement in perovskite oxide heterostructures: Tight binding instead of a nearly free electron picture

    OpenAIRE

    Zhong, Zhicheng; Zhang, Qinfang; Held, Karsten

    2013-01-01

    Most recently, orbital-selective quantum well states of $d$ electrons have been experimentally observed in SrVO$_3$ ultrathin films [K. Yoshimatsu et. al., Science 333, 319 (2011)] and SrTiO$_3$ surfaces [A. F. Santander-Syro et. al., Nature 469, 189 (2011)]. Hitherto, one tries to explain these experiments by a nearly free electron (NFE) model, an approach widely used for delocalized electrons in semiconductor heterostructures and simple metal films. We show that a tight binding (TB) model i...

  9. Effect of the Electron-LO-Phonon Coupling on an Exciton Quantum Dot

    Institute of Scientific and Technical Information of China (English)

    XIEWen-Fang; ZHUWu

    2002-01-01

    The influence of the electron-LO-phonon coupling on energy spectrum of the low -lying states of an exciton in parabolic quantum dots is investigated as a function of dot size.Calculations are made by using the method of few-body physics within the effective-mass approximation.A considerable decrease of the energy in the stronger confinement range is found for the low-lying states of an exction in quantum dots.Which results from the confinement of electron-phonon coupling.

  10. Self-assembly of lamella-forming diblock copolymers confined in nanochannels:Effect of confinement geometry

    Institute of Scientific and Technical Information of China (English)

    于彬; 邓建华; 王铮; 李宝会; 史安昌

    2015-01-01

    The self-assembly of symmetric diblock copolymers confined in the channels of variously shaped cross sections (regu-lar triangles, squares, and ellipses) is investigated using a simulated annealing technique. In the bulk, the studied symmetric diblock copolymers form a lamellar structure with period LL. The geometry and surface property of the confining channels have a large effect on the self-assembled structures and the orientation of the lamellar structures. Stacked perpendicular lamellae with period LL are observed for neutral surfaces regardless of the channel shape and size, but each lamella is in the shape of the corresponding channel’s cross section. In the case of triangle-shaped cross sections, stacked parallel lamel-lae are the majority morphologies for weakly selective surfaces, while morphologies including a triangular-prism-shaped B-cylinder and multiple tridentate lamellae are obtained for strongly selective surfaces. In the cases of square-shaped and ellipse-shaped cross sections, concentric lamellae are the signature morphology for strongly selective surfaces, whereas for weakly selective surfaces, stacked parallel lamellae, and several types of folding lamellae are obtained in the case of square-shaped cross sections, and stacked parallel lamellae are the majority morphologies in the case of ellipse-shaped cross sections when the length of the minor axis is commensurate with the bulk lamellar period. The mean-square end-to-end distance, the average contact number between different species and the surface concentration of the A-monomers are computed to elucidate the mechanisms of the formation of the different morphologies. It is found that the resulting morphology is a consequence of competition among the chain stretching, interfacial energy, and surface energy. Our results suggest that the self-assembled morphology and the orientation of lamellae can be manipulated by the shape, the size, and the surface property of the confining channels.

  11. Lectures on the Quantum Hall Effect

    CERN Document Server

    Tong, David

    2016-01-01

    The purpose of these lectures is to describe the basic theoretical structures underlying the rich and beautiful physics of the quantum Hall effect. The focus is on the interplay between microscopic wavefunctions, long-distance effective Chern-Simons theories, and the modes which live on the boundary. The notes are aimed at graduate students in any discipline where $\\hbar=1$. A working knowledge of quantum field theory is assumed. Contents: 1. The Basics (Landau levels and Berry phase). 2. The Integer Quantum Hall Effect. 3. The Fractional Quantum Hall Effect. 4. Non-Abelian Quantum Hall States. 5. Chern-Simons Theories. 6. Edge Modes.

  12. Effect of energetic ion loss on ICRF heating efficiency and energy confinement time in heliotrons

    Energy Technology Data Exchange (ETDEWEB)

    Murakami, S.; Nakajima, N.; Okamoto, M. [National Inst. for Fusion Science, Toki, Gifu (Japan); Nuehrenberg, J.

    1999-06-01

    ICRF heating efficiency and the global energy confinement time during ICRF heating are investigated including the effect of energetic ion loss in heliotrons. The approximate formula of ICRF heating efficiency is derived using the results based on Monte Carlo simulations. The global energy confinement time including energetic ion effect can be expressed in terms of ICRF heating power, plasma density, and magnetic field strength in heliotrons. Our results in the CHS plasma show the systematic decrement of the global energy confinement time due to the energetic ion loss from the assumed energy confinement scaling law, which is consistent with the experimental observations. Also we apply our model to the ICRF minority heating in the LHD plasma in two cases of typical magnetic configurations. The clear increment of the global energy confinement time due to the stored energy of energetic tail ions is obtained in the `orbit improved` configuration, while the decrement is observed in the `standard` configuration. (author)

  13. Effect of Electrical Field on Colloidal CdSe/ZnS Quantum Dots

    Institute of Scientific and Technical Information of China (English)

    WANG Zhi-Bing; ZHANG Jia-Yu; CUI Yi-Ping; YE Yong-Hong

    2008-01-01

    @@ We fabricate the hybrid films of colloidal CdSe/ZnS quantum dots (QDs) and poly(9-vinylcarbazole) (PVK) sandwiched between two electrodes.The voltage and temperature dependences of the electrolumineseence (EL) are measured.The quantum-confined Stark effect of colloidal QDs is clearly observed.To explore the mechanism in the QD EL, hybrid films are fabricated with different concentrations of colloidal QDs.Electrons and holes are proposed to be separately transported in QDs and PVK, respectively.

  14. Dynamical memory effects in correlated quantum channels

    Science.gov (United States)

    Addis, Carole; Karpat, Göktuǧ; Macchiavello, Chiara; Maniscalco, Sabrina

    2016-09-01

    Memory effects play a fundamental role in the study of the dynamics of open quantum systems. There exist two conceptually distinct notions of memory discussed for quantum channels in the literature. In quantum information theory quantum channels with memory are characterized by the existence of correlations between successive applications of the channel on a sequence of quantum systems. In open quantum systems theory memory effects arise dynamically during the time evolution of quantum systems and define non-Markovian dynamics. Here we relate and combine these two different concepts of memory. In particular, we study the interplay between correlations between multiple uses of quantum channels and non-Markovianity as nondivisibility of the t -parametrized family of channels defining the dynamical map.

  15. Vibrational properties of water under confinement: Electronic effects

    Energy Technology Data Exchange (ETDEWEB)

    Donadio, D; Cicero, G; Schwegler, E; Sharma, M; Galli, G

    2008-10-17

    We compare calculations of infrared (IR) spectra of water confined between non polar surfaces, carried out using ab initio and classical simulations. Ab-initio results show important differences between IR spectra and vibrational density of state, unlike classical simulations. These differences originate from electronic charge fluctuations at the interface, whose signature is present in IR spectra but not in the density of states. The implications of our findings for the interpretation of experimental data are discussed.

  16. Quantum coherence in the dynamical Casimir effect

    Science.gov (United States)

    Samos-Sáenz de Buruaga, D. N.; Sabín, Carlos

    2017-02-01

    We propose to use quantum coherence as the ultimate proof of the quantum nature of the radiation that appears by means of the dynamical Casimir effect in experiments with superconducting microwave waveguides. We show that, unlike previously considered measurements such as entanglement and discord, quantum coherence does not require a threshold value of the external pump amplitude and is highly robust to thermal noise.

  17. Nonlocal Quantum Effects in Cosmology

    CERN Document Server

    Dumin, Yurii V

    2014-01-01

    Since it is commonly believed that the observed large-scale structure of the Universe is an imprint of quantum fluctuations existing at the very early stage of its evolution, it is reasonable to pose the question: Do the effects of quantum nonlocality, which are well established now by the laboratory studies, manifest themselves also in the early Universe? We try to answer this question by utilizing the results of a few experiments, namely, with the superconducting multi-Josephson-junction loops and the ultracold gases in periodic potentials. Employing a close analogy between the above-mentioned setups and the simplest one-dimensional Friedmann-Robertson-Walker cosmological model, we show that the specific nonlocal correlations revealed in the laboratory studies might be of considerable importance also in treating the strongly-nonequilibrium phase transitions of Higgs fields in the early Universe. Particularly, they should substantially reduce the number of topological defects (e.g., domain walls) expected du...

  18. The effect of impurity on transition frequency of bound polaron in quantum rods

    Indian Academy of Sciences (India)

    Wei Xiao; Jing-Lin Xiao

    2012-12-01

    The Hamiltonian of a quantum rod with an ellipsoidal boundary is given after a coordinate transformation that changes the ellipsoidal boundary into a spherical one. The properties of the quantum rods constituting the bridge between two-dimensional quantum wells, zero-dimensional quantum dots and one-dimensional quantum wires are explored theoretically using linear combination operator method. The first internal excited state energy, the excitation energy and the transition frequency between the first internal excited and the ground states of the strong-coupled impurity-bound polaron in the rod with Coulomb-bound potential, the transverse effective confinement length, the ellipsoid aspect ratio and the electron–phonon coupling strength are studied. It is found that the first internal excited state energy, the excitation energy and the transition frequency are increasing functions of the Coulomb-bound potential and the electron–phonon coupling strength, whereas they are decreasing functions of the ellipsoid aspect ratio and the transverse effective confinement length. These results can be attributed to the interesting quantum size confining effects.

  19. Unified Drain Current Model of Armchair Graphene Nanoribbons with Uniaxial Strain and Quantum Effect

    Directory of Open Access Journals (Sweden)

    EngSiew Kang

    2014-01-01

    Full Text Available A unified current-voltage I-V model of uniaxial strained armchair graphene nanoribbons (AGNRs incorporating quantum confinement effects is presented in this paper. The I-V model is enhanced by integrating both linear and saturation regions into a unified and precise model of AGNRs. The derivation originates from energy dispersion throughout the entire Brillouin zone of uniaxial strained AGNRs based on the tight-binding approximation. Our results reveal the modification of the energy band gap, carrier density, and drain current upon strain. The effects of quantum confinement were investigated in terms of the quantum capacitance calculated from the broadening density of states. The results show that quantum effect is greatly dependent on the magnitude of applied strain, gate voltage, channel length, and oxide thickness. The discrepancies between the classical calculation and quantum calculation were also measured and it has been found to be as high as 19% drive current loss due to the quantum confinement. Our finding which is in good agreement with the published data provides significant insight into the device performance of uniaxial strained AGNRs in nanoelectronic applications.

  20. Confinement and surface effects on the physical properties of rhombohedral-shape hematite (α-Fe{sub 2}O{sub 3}) nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Luna, Carlos, E-mail: carlos.lunacd@uanl.edu.mx [Universidad Autónoma de Nuevo León (UANL), Av. Universidad S/N, San Nicolás de los Garza, Nuevo León 66455 (Mexico); Cuan-Guerra, Aída D. [Universidad Autónoma de Nuevo León (UANL), Av. Universidad S/N, San Nicolás de los Garza, Nuevo León 66455 (Mexico); Barriga-Castro, Enrique D. [Centro de Investigación en Química Aplicada (CIQA), Blvd. Enrique Reyna Hermosillo No. 140, Saltillo, 25294 Coahuila (Mexico); Núñez, Nuria O. [Instituto de Ciencia de Materiales de Sevilla (ICMS), CSIC-US, Avda. Americo Vespucio n° 49, Isla de la Cartuja, 41092 Sevilla (Spain); Mendoza-Reséndez, Raquel [Universidad Autónoma de Nuevo León (UANL), Av. Universidad S/N, San Nicolás de los Garza, Nuevo León 66455 (Mexico)

    2016-08-15

    Highlights: • Uniform rhombohedral hematite nanocrystals (RHNCs) have been obtained. • A detailed formation mechanism of these HNCS has been proposed. • Phonon confinement effects were revealed in the RHNCS vibrational bands. • Quantum confinement effects on the optical and electronic properties were found. - Abstract: Morphological, microstructural and vibrational properties of hematite (α-Fe{sub 2}O{sub 3}) nanocrystals with a rhombohedral shape and rounded edges, obtained by forced hydrolysis of iron(III) solutions under a fast nucleation, have been investigated in detail as a function of aging time. These studies allowed us to propose a detailed formation mechanism and revealed that these nanocrystals are composed of four {104} side facets, two {110} faces at the edges of the long diagonal of the nanocrystals and two {−441} facets as the top and bottom faces. Also, the presence of nanoscopic pores and fissures was evidenced. The vibrational bands of such nanocrystals were shifted to lower frequencies in comparison with bulk hematite ones as the nanocrystal size was reduced due to phonon confinement effects. Also, the indirect and direct transition band gaps displayed interesting dependences on the aging time arising from quantum confinement and surface effects.

  1. Anisotropic intrinsic spin Hall effect in quantum wires.

    Science.gov (United States)

    Cummings, A W; Akis, R; Ferry, D K

    2011-11-23

    We use numerical simulations to investigate the spin Hall effect in quantum wires in the presence of both Rashba and Dresselhaus spin-orbit coupling. We find that the intrinsic spin Hall effect is highly anisotropic with respect to the orientation of the wire, and that the nature of this anisotropy depends strongly on the electron density and the relative strengths of the Rashba and Dresselhaus spin-orbit couplings. In particular, at low densities, when only one subband of the quantum wire is occupied, the spin Hall effect is strongest for electron momentum along the [N110] axis, which is the opposite of what is expected for the purely 2D case. In addition, when more than one subband is occupied, the strength and anisotropy of the spin Hall effect can vary greatly over relatively small changes in electron density, which makes it difficult to predict which wire orientation will maximize the strength of the spin Hall effect. These results help to illuminate the role of quantum confinement in spin-orbit-coupled systems, and can serve as a guide for future experimental work on the use of quantum wires for spin-Hall-based spintronic applications.

  2. Effects of confinement on the dielectric response of water extends up to mesoscale dimensions

    DEFF Research Database (Denmark)

    De Luca, Sergio; Kannam, Sridhar Kumar; Todd, B.D.

    2016-01-01

    The extent of confinement effects on water is not clear in the literature. While some properties are affected only within a few nanometers from the wall surface, others are affected over long length scales, but the range is not clear. In this work, we have examined the dielectric response...... of confined water under the influence of external electric fields along with the dipolar fluctuations at equilibrium. The confinement induces a strong anisotropic effect which is evident up to 100 nm channel width, and may extend to macroscopic dimensions. The root-mean-square fluctuations of the total...

  3. Effects of quantum gravity on black holes

    CERN Document Server

    Chen, Deyou; Yang, Haitang; Yang, Shuzheng

    2014-01-01

    In this review, we discuss effects of quantum gravity on black hole physics. After a brief review of the origin of the minimal observable length from various quantum gravity theories, we present the tunneling method. To incorporate quantum gravity effects, we modify the Klein-Gordon equation and Dirac equation by the modified fundamental commutation relations. Then we use the modified equations to discuss the tunneling radiation of scalar particles and fermions. The corrected Hawking temperatures are related to the quantum numbers of the emitted particles. Quantum gravity corrections slow down the increase of the temperatures. The remnants are observed as $M_{\\hbox{Res}}\\gtrsim \\frac{M_p}{\\sqrt{\\beta_0}}$. The mass is quantized by the modified Wheeler-DeWitt equation and is proportional to $n$ in quantum gravity regime. The thermodynamical property of the black hole is studied by the influence of quantum gravity effects.

  4. Relaxation of Exciton Confinement in CdSe Quantum Dots by Modification with a Conjugated Dithiocarbamate Ligand

    Energy Technology Data Exchange (ETDEWEB)

    Frederick, Matthew T. [Northwestern Univ., Evanston, IL (United States); Weiss, Emily A. [Northwestern Univ., Evanston, IL (United States)

    2010-01-01

    Coordination of phenyldithiocarbamate (PTC) ligands to solution-phase colloidal CdSe quantum dots (QDs) decreases the optical band gap, Eg, of the QDs by up to 220 meV. These values of ΔEg are the largest shifts achieved by chemical modification of the surfaces of solution-phase CdSe QDs and are—by more than an order of magnitude in energy—the largest bathochromic shifts achieved for QDs in either the solution or solid phases. Measured values of ΔEg upon coordination to PTC correspond to an apparent increase in the excitonic radius of 0.26 ± 0.03 nm; this excitonic delocalization is independent of the size of the QD for radii, R = 1.1-1.9 nm. Density functional theory calculations indicate that the highest occupied molecular orbital of PTC is near resonant with that of the QD, and that the two have correct symmetry to exchange electron density (PTC is a π-donor, and the photoexcited QD is a π-acceptor). We therefore propose that the relaxation of exciton confinement occurs through delocalization of the photoexcited hole of the QD into the ligand shell.

  5. XPS Observations of Crystal Field Splitting in TiO2 Thin Films in Quantum Confinement Approach

    Science.gov (United States)

    Sushkova, Natalya

    2015-03-01

    Transition metal oxides attract increased interest due to amazing electrical and magnetic properties and their outstanding applications designated by relative d-band redistributions that are shifted in such a way that narrow bands arranged by localized electrons are situated in the vicinity of EF. Different kinds of lattice distortions caused by doping and/or quantum size confinement of TM oxides are assigned to remarkable phenomenon Mott metal-insulator transitions, when mutual metal-oxide orbital arrangement changes dramatically. There is a widespread consensus that strong electron correlations are responsible for that change and magnetic excitation is one of manifestations of these correlations. Here we are presenting XPS study of titanium dioxide nanocrystal formations on silicon substrate with native oxide. The dynamic changes in XPS spectra were used for analysis of TiO2 thin films with mass thicknesses up to 2 monolayers formed by redox reactions of sputtered Ti on Si(100) substrate with native oxide implemented in situ under UHV conditions. XPS spectra evolution, as a traditional source of information on phase composition, was complemented by the possibility to estimate the morphology and crystal field splitting of formed precipitates. Intensity fluctuations observed for O1s, Si 2p, Ti2p spectra were accompanied by crystal field splitting in Ti2p and on second derivatives of O1s. These fluctuations were followed by noticeable changes in the vicinity of band gap indicating possible Mott metal-insulator transitions.

  6. Laser Ignition of pyrotechnics - effects of wavelength, composition and confinement

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, Sheikh Rafi; Russell, David Anthony [Department of Environmental and Ordnance Systems, Cranfield University, Royal Military College of Science, Shrivenham, Swindon, Wiltshire SN6 8LA (United Kingdom)

    2005-04-01

    Ignition tests were carried out using three different laser systems and three different pyrotechnic compositions. Pyrotechnic materials investigated are: sulfur/charcoal/potassium nitrate based composition (gunpowder, GP), Shellac binder-based boron/potassium nitrate composition (SR 44) and acaroid resin binder based magnesium/potassium nitrate composition (SR 371C). The laser sources were the multimode output from an Ar-ion laser ({lambda}=500 nm average), a high-power commercial diode laser ({lambda}=784 nm) and a small laser diode operating at around the same wavelength but controlled by a customized electronic circuitry. Lasers operating in the visible wavelength range provided more reproducible and quicker ignition than the infrared output from the diode lasers. It was found that unconfined gunpowder exhibits more reproducible ignition for both the visible and the infrared wavelengths compared to the other two compositions. The composition based on magnesium, SR 371C appeared to be very sensitive to laser intensity variations and gave erratic and therefore, irreproducible ignition delay times. The threshold laser energies to initiate reproducible ignition for the different wavelengths were measured and ignition maps were constructed. From these maps, the required laser power density for any value of the ignition delay time, i.e. laser energy density was determined. Tests were also conducted on gunpowder samples, partially confined in a modified pyrogen igniter capsule and a small laser diode. The diode was operated in single pulse mode using a current surge, which was much higher than the recommended value for CW operation. This provided 1 W pulses at the end of a 1 mm diameter fiber optic cable and caused reproducible ignition in the semi-confined pyrotechnic bed within the capsule. The threshold ignition energy under semi-confined conditions was found to be substantially less than that required in the unconfined environment under similar experimental

  7. Effect of plasma shape on confinement and MHD behaviour in TCV

    Energy Technology Data Exchange (ETDEWEB)

    Weisen, H.; Alberti, S.; Barry, S. [Ecole Polytechnique Federale, Lausanne (Switzerland). Centre de Recherche en Physique des Plasma (CRPP)] [and others

    1997-06-01

    The TCV tokamak has produced a wide variety of plasma configurations, both diverted and limited, with elongations {kappa}{sub a} ranging from 0.9 to 2.58, triangularities {delta}{sub a} from -0.7 to 1 as well as discharges nearly rectangular cross sections. Plasma currents of 1 MA have been obtained in elongated discharges ({kappa}{sub a}{approx_equal}2.3). Ohmic discharges with {delta}{sub a} <0 have smaller sawteeth and higher levels of MHD mode activity than plasmas with {delta}>0. The main change in MHD behaviour when elongation is increased beyond 2 is an increase in the relative importance of modes with m,n>1 and a reduction of sawtooth amplitudes. Confinement is strongly dependent on plasma shape. In ohmic limiter L-modes energy confinement times improve typically by a factor of 2 as the plasma triangularity is reduced from 0.5 to 0 at constant q{sub a}. There also is an improvement of confinement as the elongation is increased. In most discharges the changes in confinement are explained by a combination of geometrical effects and power degradation. A global factor of merit H{sub s}(shape enhancement factor) has been introduced to quantify the effect of flux surface geometry. The introduction of H{sub s} into well known confinement scaling expressions such Neo-Alcator and Rebut-Lallia-Watkins scaling leads to improved descriptions of the effect of shape for a given confinement mode. In some cases with {kappa}{sub a}{>=}1.7 limited ohmic L-modes undergo a slow transition to a confinement regime with an energy confinement improved by a factor of up to 1.5 and higher particle confinement. First experiments to study the effect of shape in ECRH at a frequency of 83 GHz (second harmonic) have been undertaken with 500 kW of additional power. (author) 10 figs., refs.

  8. Ground state of a confined Yukawa plasma including correlation effects

    CERN Document Server

    Henning, C; Filinov, A; Piel, A; Bonitz, M

    2007-01-01

    The ground state of an externally confined one-component Yukawa plasma is derived analytically using the local density approximation (LDA). In particular, the radial density profile is computed. The results are compared with the recently obtained mean-field (MF) density profile \\cite{henning.pre06}. While the MF results are more accurate for weak screening, LDA with correlations included yields the proper description for large screening. By comparison with first-principle simulations for three-dimensional spherical Yukawa crystals we demonstrate that both approximations complement each other. Together they accurately describe the density profile in the full range of screening parameters.

  9. Electron interaction and spin effects in quantum wires, quantum dots and quantum point contacts: a first-principles mean-field approach

    Energy Technology Data Exchange (ETDEWEB)

    Zozoulenko, I V; Ihnatsenka, S [Solid State Electronics, Department of Science and Technology (ITN), Linkoeping University, 60174 Norrkoeping (Sweden)

    2008-04-23

    We have developed a mean-field first-principles approach for studying electronic and transport properties of low dimensional lateral structures in the integer quantum Hall regime. The electron interactions and spin effects are included within the spin density functional theory in the local density approximation where the conductance, the density, the effective potentials and the band structure are calculated on the basis of the Green's function technique. In this paper we present a systematic review of the major results obtained on the energetics, spin polarization, effective g factor, magnetosubband and edge state structure of split-gate and cleaved-edge overgrown quantum wires as well as on the conductance of quantum point contacts (QPCs) and open quantum dots. In particular, we discuss how the spin-resolved subband structure, the current densities, the confining potentials, as well as the spin polarization of the electron and current densities in quantum wires and antidots evolve when an applied magnetic field varies. We also discuss the role of the electron interaction and spin effects in the conductance of open systems focusing our attention on the 0.7 conductance anomaly in the QPCs. Special emphasis is given to the effect of the electron interaction on the conductance oscillations and their statistics in open quantum dots as well as to interpretation of the related experiments on the ultralow temperature saturation of the coherence time in open dots.

  10. An effective electrostatic-confinement based fusion approach

    CERN Document Server

    Paul, R K

    2013-01-01

    The paper reports a new electrostatic-confinement based fusion approach, where, a new non-equilibrium distribution function for an ion-beam, compressed by an external electric force, has been derived. This distribution function allows the system to possess appreciably low and insignificant thermal energy irrespective of the energy per particle. The spread in the energy among the particles is attributed to the collisions in presence of the external force, whereas; for equilibrium, the spreading in energy is due to the absence of the force. The reactivity for a deuterium-deuterium fusion, using the proposed distribution function, has been computed. It is shown that the fusion time is comparable to the energy confinement time, collision time and transit time of the ion for beam energy greater than 160 keV. The estimated energy gain Q (ratio of fusion power to the power consumed by the system) is around 10 for beam energy 160 keV and ion density 1018 cm-3. The energy loss due to particle scattering is estimated a...

  11. Effects of Spin Quantum Force in Magnetized Quantum Plasma

    Institute of Scientific and Technical Information of China (English)

    杨秀峰; 姜虹; 祁学宏; 段文山

    2011-01-01

    Starting from the governing equations for a quantum magnetoplasma including the electron spin -1/2 effects and quantum Bohm potential, we derive Korteweg-de Vries (KdV) equation of the system of quantum magneto- hydrodynamics (QMHD). The amplitude and width of magnetosonic soliton with different parameters in the system are studied. It is found that the normalized Zeeman energy E plays a crucial role, for E ≥ 1 the amplitude τmξ and the width we of solitary wave all decrease as E increases. That is, the introduction of spin quantum force modifies the shape of solitary magnetosonic waves and makes them more narrower and shallower.

  12. Effects of transverse mode coupling and optical confinement factor on gallium-nitride based laser diode

    Institute of Scientific and Technical Information of China (English)

    Jin Xiao-Ming; Zhang Bei; Dai Tao; Zhang Guo-Yi

    2008-01-01

    We have investigated the transverse mode pattern and the optical field confinement factor of gallium nitride (GaN) laser diodes (LDs) theoretically. For the particular LD structure, composed of approximate 4μm thick n-GaN substrate layer, the maximum optical confinement factor was found to be corresponding to the 5th order transverse mode, the so-called lasing mode. Moreover, the value of the maximum confinement factor varies periodically when increasing the n-side GaN layer thickness, which simultaneously changes and increases the oscillation mode order of the GaN LD caused by the effects of mode coupling. The effects of the thickness and the average composition of Al in the AlGaN/GaN superlattice on the optical confinement factor are also presented. Finally, the mode coupling and optimization of the layers in the GaN-based LD are discussed.

  13. Strong-coupling effects in a plasma of confining gluons

    CERN Document Server

    Florkowski, Wojciech; Su, Nan; Tywoniuk, Konrad

    2015-01-01

    The plasma consisting of confining gluons resulting from the Gribov quantization of the SU(3) Yang-Mills theory is studied using non-equilibrium fluid dynamical framework. Exploiting the Bjorken symmetry and using linear response theory a general analytic expressions for the bulk and shear viscosity coefficients are derived. It is found that the considered system exhibits a number of properties similar to the strongly-coupled theories, where the conformality is explicitly broken. In particular, it is shown that, in the large temperature limit, bulk to shear viscosity ratio, scales linearly with the difference $1/3 - c_s^2$, where $c_s$ is the speed of sound. Results obtained from the analysis are in line with the interpretation of the quark-gluon plasma as an almost perfect fluid.

  14. Nonlocal Quantum Effects in Cosmology

    Directory of Open Access Journals (Sweden)

    Yurii V. Dumin

    2014-01-01

    Full Text Available Since it is commonly believed that the observed large-scale structure of the universe is an imprint of quantum fluctuations existing at the very early stage of its evolution, it is reasonable to pose the question: do the effects of quantum nonlocality, which are well established now by the laboratory studies, manifest themselves also in the early universe? We try to answer this question by utilizing the results of a few experiments, namely, with the superconducting multi-Josephson-junction loops and the ultracold gases in periodic potentials. Employing a close analogy between the above-mentioned setups and the simplest one-dimensional Friedmann-Robertson-Walker cosmological model, we show that the specific nonlocal correlations revealed in the laboratory studies might be of considerable importance also in treating the strongly nonequilibrium phase transitions of Higgs fields in the early universe. Particularly, they should substantially reduce the number of topological defects (e.g., domain walls expected due to independent establishment of the new phases in the remote spatial regions. This gives us a hint on resolving a long-standing problem of the excessive concentration of topological defects, inconsistent with observational constraints. The same effect may be also relevant to the recent problem of the anomalous behavior of cosmic microwave background fluctuations at large angular scales.

  15. Quantum effects in beam-plasma instabilities

    CERN Document Server

    Bret, A

    2015-01-01

    Among the numerous works on quantum effects that have been published in recent years, streaming instabilities in plasma have also been revisited. Both the fluid quantum and the kinetic Wigner-Maxwell models have been used to explore quantum effects on the Weibel, Filamentation and Two-Stream instabilities. While quantum effects usually tend to reduce the instabilities, they can also spur new unstable branches. A number of theoretical results will be reviewed together with the implications to one physical setting, namely the electron driven fast ignition scenario.

  16. Counterion effects on nano-confined metal–drug–DNA complexes

    Directory of Open Access Journals (Sweden)

    Nupur Biswas

    2016-01-01

    Full Text Available We have explored morphology of DNA molecules bound with Cu complexes of piroxicam (a non-steroidal anti-inflammatory drug molecules under one-dimensional confinement of thin films and have studied the effect of counterions present in a buffer. X-ray reflectivity at and away from the Cu K absorption edge and atomic force microscopy studies reveal that confinement segregates the drug molecules preferentially in a top layer of the DNA film, and counterions enhance this segregation.

  17. Configurational effects on low collision plasma confinement in CHS Heliotron/Torsatron

    Energy Technology Data Exchange (ETDEWEB)

    Heyn, M.F.; Kernbichler, W. [Institut fuer Theoretische Physik, Technische Universitaet Graz, Graz (Austria); Kasilov, S.V.; Nemov, V.V.; Pavlichenko, O.S. [Institute of Plasma Physics, NSC KIPT, Kharkov (Ukraine); Matsuoka, K.; Okamura, S. [National Inst. for Fusion Science, Toki, Gifu (Japan)

    2001-01-01

    Multihelicity effects on low collisionality ({approx}1/v) regime of neoclassical transport has been analyzed for full range of magnetic field configurations of CHS Heliotron/Torsatron. Transport coefficients for this regime has been calculated according to an approach developed in the previous paper. It was shown that the drift-orbit-optimized configuration of CHS device investigated in the previous report has the best confinement properties for low collision plasma confinement. (author)

  18. Effect of cylindrical cavity height on laser-induced breakdown spectroscopy with spatial confinement

    Science.gov (United States)

    Junfeng, Shao; Tingfeng, Wang; Jin, Guo; Anmin, Chen; Mingxing, Jin

    2017-02-01

    In this paper, we present a study on the spatial confinement effect of laser-induced plasma with a cylindrical cavity in laser-induced breakdown spectroscopy (LIBS). The emission intensity with the spatial confinement is dependent on the height of the confinement cavity. It is found that, by selecting the appropriate height of cylindrical cavity, the signal enhancement can be significantly increased. At the cylindrical cavity (diameter = 2 mm) with a height of 6 mm, the enhancement ratio has the maximum value (approximately 8.3), and the value of the relative standard deviation (RSD) (7.6%) is at a minimum, the repeatability of LIBS signal is best. The results indicate that the height of confinement cavity is very important for LIBS technique to reduce the limit of detection and improve the precision.

  19. Effect of confinement on the collapsing mechanism of a flexible polymer chain.

    Science.gov (United States)

    Das, Siddhartha; Chakraborty, Suman

    2010-11-07

    In this paper, Brownian dynamics simulation (BDS) studies are executed to demonstrate the distinctive influences of the extent of confinement on the collapsing mechanism and kinetics of a flexible hydrophobic polymer chain in a poor solvent. The collapsing behavior is quantified by the time of collapse, which below a critical dimension of the confinement (h(c)), encounters a drastic reduction with a further strengthening in the degree of confinement. For dimensions greater than this critical one, the collapse occurs through the well-known hydrodynamic interaction (HI) controlled multiple-globule-mediated mechanisms. However, for channel dimensions less than this critical one, the collapse mechanism is drastically altered. Under such circumstances, the collapse gets predominantly controlled by the confinement effects (with negligible contribution of the HIs) and occurs via the formation of a single central globule. This central globule rapidly engulfs the noncondensed polymer segments, and in the process largely hastens up the collapsing event. Under such circumstances, the collapse time is found to decrease linearly with decrements in the channel height. On the contrary, for channel heights greater than h(c), the multiple-globule-mediated collapse is characterized by a collapse time that shows an exponential dependence on the channel height, rapidly attaining a state in which the confinement effect becomes inconsequential and HIs dictate the entire collapsing behavior. We further propose detailed arguments based on physical reasoning as well as free energy estimations to conclusively support the qualitative and quantitative nature of influences of the confinement on the polymer collapse.

  20. GeP3: A Small Indirect Band Gap 2D Crystal with High Carrier Mobility and Strong Interlayer Quantum Confinement.

    Science.gov (United States)

    Jing, Yu; Ma, Yandong; Li, Yafei; Heine, Thomas

    2017-03-08

    We propose a two-dimensional crystal that possesses low indirect band gaps of 0.55 eV (monolayer) and 0.43 eV (bilayer) and high carrier mobilities similar to those of phosphorene, GeP3. GeP3 has a stable three-dimensional layered bulk counterpart, which is metallic and known from experiment since 1970. GeP3 monolayer has a calculated cleavage energy of 1.14 J m(-2), which suggests exfoliation of bulk material as viable means for the preparation of mono- and few-layer materials. The material shows strong interlayer quantum confinement effects, resulting in a band gap reduction from mono- to bilayer, and then to a semiconductor-metal transition between bi- and triple layer. Under biaxial strain, the indirect band gap can be turned into a direct one. Pronounced light absorption in the spectral range from ∼600 to 1400 nm is predicted for monolayer and bilayer and promises applications in photovoltaics.

  1. Optical properties of ionized donor-bound excitons confined in strained wurtzite ZnO/MgxZn1-xO quantum dots

    Science.gov (United States)

    Dongmei, Zheng; Zongchi, Wang; Boqi, Xiao

    2015-03-01

    Within the framework of the effective-mass approximation and the dipole approximation, considering the three-dimensional confinement of the electron and hole and the strong built-in electric field (BEF) in strained wurtzite ZnO/Mg0.25Zn0.75O quantum dots (QDs), the optical properties of ionized donor-bound excitons (D+, X) are investigated theoretically using a variational method. The computations are performed in the case of finite band offset. Numerical results indicate that the optical properties of (D+, X) complexes sensitively depend on the donor position, the QD size and the BEF. The binding energy of (D+, X) complexes is larger when the donor is located in the vicinity of the left interface of the QDs, and it decreases with increasing QD size. The oscillator strength reduces with an increase in the dot height and increases with an increase in the dot radius. Furthermore, when the QD size decreases, the absorption peak intensity shows a marked increment, and the absorption coefficient peak has a blueshift. The strong BEF causes a redshift of the absorption coefficient peak and causes the absorption peak intensity to decrease remarkably. The physical reasons for these relationships have been analyzed in depth. Project supported by the National Natural Science Foundation for Young Scientists of China (No. 11102100), the Program for New Century Excellent Talents in Fujian Province University (No. JA14285) and the Program for Young Top-Notch Innovative Talents of Fujian Province of China.

  2. Electronic structure of a spherical quantum dot: Effects of the Kratzer potential, hydrogenic impurity, external electric and magnetic fields

    Science.gov (United States)

    Dehyar, A.; Rezaei, G.; Zamani, A.

    2016-10-01

    In the present work, we have investigated the simultaneous effects of external electric and magnetic fields on the energy spectrum of an electron bound to an impurity confined in a spherical quantum dot with Kratzer potential. To this end, energy eigenvalues are obtained using the asymptotic iteration method. The energy dependencies upon the confinement potential and external fields are reported. Our results indicate that the confinement potential, external electric and magnetic fields have a great influence on the energy eigenvalues of the system. We found that, an increase in the magnetic field increases the energy eigenvalues of the states with positive magnetic quantum number, m ≽ 0 . While, the states with negative m decrease, reaching to their minimum values and increase again, with increasing the magnetic field. Moreover, an increase in electric field strength leads to decrease the confinement effects and energy eigenvalues of the system.

  3. Electric field effect on the third-order nonlinear optical susceptibility in inverted core–shell nanodots with dielectric confinement

    Energy Technology Data Exchange (ETDEWEB)

    Cristea, M.; Radu, A., E-mail: radu@physics.pub.ro; Niculescu, E.C.

    2013-11-15

    Third-order nonlinear optical processes associated with the interlevel transitions in ZnS/CdSe core–shell quantum dots under electric fields are theoretically investigated. Taking into account the dielectric mismatch with the surrounding matrix, the electronic structure of the dots is obtained within the effective mass and parabolic band approximations. It is shown that large applied electric fields break the symmetry of the confinement potential and lead to a significant blue-shift of the peak positions in the nonlinear optical spectrum. The size effect is also discussed and it is proved that large nonlinear susceptibility can be obtained by increasing the thickness of the nanocrystal shell. Our results suggest that external factors such as the applied electric field and orientation of the incident light polarization can be used – in addition to spatial confinement – to improve the performances of the optical devices. -- Highlights: • Nonlinear optical processes in ZnS/CdSe QDs under electric field were studied. • The effective mass and parabolic band approximations were used. • The dielectric mismatch of the QDs with the surrounding matrix was considered. • Increasing the thickness of the shell could lead to large nonlinear susceptibility. • Incident light polarization with respect to the electric field was discussed.

  4. Two rods confined by positive plates: effective forces and charge distribution profiles

    Energy Technology Data Exchange (ETDEWEB)

    Odriozola, G; Jimenez-Angeles, F; Lozada-Cassou, M [Programa de IngenierIa Molecular, Instituto Mexicano del Petroleo, Lazaro Cardenas 152, 07730 Mexico, DF (Mexico)

    2006-09-13

    The effect of confinement on the interaction force between two negatively charged rods is studied through Monte Carlo simulations. Confinement is produced by two parallel, charged or uncharged plates. The system is immersed in a 0.1 M 1-1 restricted primitive model electrolyte. The effect on the rod-rod effective force by the plate charge distribution is analysed. A strong modification of the rod-rod effective force due to confinement is found, as compared to the bulk case. In particular, rod-rod attraction was found for plates having a charge equal to that of fully charged bilipid bilayers. In spite of the simplicity of the model, these results agree with some DNA-phospholipid experimental observations. On the other hand, for a model having the plate charges fixed on a grid, very long range, oscillatory rod-rod effective forces were obtained.

  5. Discrete quantum geometries and their effective dimension

    CERN Document Server

    Thürigen, Johannes

    2015-01-01

    In several approaches towards a quantum theory of gravity, such as group field theory and loop quantum gravity, quantum states and histories of the geometric degrees of freedom turn out to be based on discrete spacetime. The most pressing issue is then how the smooth geometries of general relativity, expressed in terms of suitable geometric observables, arise from such discrete quantum geometries in some semiclassical and continuum limit. In this thesis I tackle the question of suitable observables focusing on the effective dimension of discrete quantum geometries. For this purpose I give a purely combinatorial description of the discrete structures which these geometries have support on. As a side topic, this allows to present an extension of group field theory to cover the combinatorially larger kinematical state space of loop quantum gravity. Moreover, I introduce a discrete calculus for fields on such fundamentally discrete geometries with a particular focus on the Laplacian. This permits to define the ef...

  6. Quantum Confined Semiconductors

    Science.gov (United States)

    2015-02-01

    luminescence was measured from 5 K up to 300 K using a closed-cycle refrigeration cryostat with a diamond window. Figure 61 shows the PL spectra...degrade faster than the optical properties [18]. REFERENCES [1] Porter , V. J., Mentzel, T., Charpentier, S., Kastner, M. A. and Bawendi, M. G...Characterization of high performance PbS photodetectors,” J. Optoelectronics and Adv. Mater. 10 (2), 306–310 (2008). [5] Jarosz, M. V., Porter , V

  7. Intersubband optical transition energy in a CdTe/Zn{sub 0.2}Cd{sub 0.8}Te/ZnTe core/shell/shell spherical quantum dot with Smorodinsky–Winternitz confinement potential

    Energy Technology Data Exchange (ETDEWEB)

    Christina lily Jasmine, P. [Dept. of Physics, N.M.S. Sermathai Vasan College for Women, Madurai 625 012 (India); John Peter, A., E-mail: a.john.peter@gmail.com [P.G. and Research Dept. of Physics, Government Arts College, Melur, 625 106 Madurai (India); Lee, Chang Woo [Department of Chemical Engineering, College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Gihung, Yongin, Gyeonggi 446-701 (Korea, Republic of)

    2015-05-01

    Highlights: • Optical properties of a hydrogenic donor impurity in CdTe/Zn{sub 0.2}Cd{sub 0.8}Te/ZnTe core/shell/shell dot are discussed. • Two parametrical potential of Smorodinsky–Winternitz are considered in this problem. • The dielectric mismatch is included in the Hamiltonian. • The position dependent effective mass is applied. • The intersubband optical absorption, oscillator strength and radiative life time are studied. - Abstract: Electronic and optical properties of a hydrogenic donor impurity in a CdTe/Zn{sub 0.2}Cd{sub 0.8}Te/ZnTe core/shell/shell quantum dot are discussed taking into consideration of geometrical confinement effect. The confining potentials on both the sides of the barrier are different and a two parametrical potential of Smorodinsky–Winternitz is considered in this problem. The dielectric mismatch is included in the Hamiltonian. The position dependent effective mass is applied. The electronic properties are studied using variational method and the optical properties are investigated using the density matrix approach. The intersubband optical absorption, the oscillator strength and the radiative life time between ground and the excited states are studied based on the wave functions and the confined energies with and without the impurity with various dot radii. The results show that the absorption wavelength in type-II core and shell semiconducting nanomaterials can be tuned over a wider range of wavelengths by altering their size and the composition.

  8. Discrete quantum geometries and their effective dimension

    Energy Technology Data Exchange (ETDEWEB)

    Thuerigen, Johannes

    2015-07-02

    In several approaches towards a quantum theory of gravity, such as group field theory and loop quantum gravity, quantum states and histories of the geometric degrees of freedom turn out to be based on discrete spacetime. The most pressing issue is then how the smooth geometries of general relativity, expressed in terms of suitable geometric observables, arise from such discrete quantum geometries in some semiclassical and continuum limit. In this thesis I tackle the question of suitable observables focusing on the effective dimension of discrete quantum geometries. For this purpose I give a purely combinatorial description of the discrete structures which these geometries have support on. As a side topic, this allows to present an extension of group field theory to cover the combinatorially larger kinematical state space of loop quantum gravity. Moreover, I introduce a discrete calculus for fields on such fundamentally discrete geometries with a particular focus on the Laplacian. This permits to define the effective-dimension observables for quantum geometries. Analysing various classes of quantum geometries, I find as a general result that the spectral dimension is more sensitive to the underlying combinatorial structure than to the details of the additional geometric data thereon. Semiclassical states in loop quantum gravity approximate the classical geometries they are peaking on rather well and there are no indications for stronger quantum effects. On the other hand, in the context of a more general model of states which are superposition over a large number of complexes, based on analytic solutions, there is a flow of the spectral dimension from the topological dimension d on low energy scales to a real number between 0 and d on high energy scales. In the particular case of 1 these results allow to understand the quantum geometry as effectively fractal.

  9. The Quantum Zeno Effect -- Watched Pots in the Quantum World

    CERN Document Server

    Venugopalan, Anu

    2012-01-01

    In the 5th century B.C.,the philosopher and logician Zeno of Elea posed several paradoxes which remained unresolved for over two thousand five hundred years. The $20^{th}$ century saw some resolutions to Zeno's mind boggling problems. This long journey saw many significant milestones in the form of discoveries like the tools of converging series and theories on infinite sets in mathematics. In recent times, the Zeno effect made an intriguing appearance in a rather unlikely place - a situation involving the time evolution of a quantum system, which is subject to "observations" over a period of time. Leonid Khalfin working in the former USSR in the 1960s and ECG Sudarshan and B. Misra at the University of Texas, Austin, first drew attention to this problem. In 1977, ECG Sudarshan and B. Misra published a paper on the quantum Zeno effect, called "The Zeno's paradox in quantum theory". Their fascinating result revealed the bizarre workings of the quantum world. Misra and Sudarshan's 1977 paper activated over two ...

  10. Impact of quantum confinement on transport and the electrostatic driven performance of silicon nanowire transistors at the scaling limit

    Science.gov (United States)

    Al-Ameri, Talib; Georgiev, Vihar P.; Sadi, Toufik; Wang, Yijiao; Adamu-Lema, Fikru; Wang, Xingsheng; Amoroso, Salvatore M.; Towie, Ewan; Brown, Andrew; Asenov, Asen

    2017-03-01

    In this work we investigate the impact of quantum mechanical effects on the device performance of n-type silicon nanowire transistors (NWT) for possible future CMOS applications at the scaling limit. For the purpose of this paper, we created Si NWTs with two channel crystallographic orientations and and six different cross-section profiles. In the first part, we study the impact of quantum corrections on the gate capacitance and mobile charge in the channel. The mobile charge to gate capacitance ratio, which is an indicator of the intrinsic performance of the NWTs, is also investigated. The influence of the rotating of the NWTs cross-sectional geometry by 90° on charge distribution in the channel is also studied. We compare the correlation between the charge profile in the channel and cross-sectional dimension for circular transistor with four different cross-sections diameters: 5 nm, 6 nm, 7 nm and 8 nm. In the second part of this paper, we expand the computational study by including different gate lengths for some of the Si NWTs. As a result, we establish a correlation between the mobile charge distribution in the channel and the gate capacitance, drain-induced barrier lowering (DIBL) and the subthreshold slope (SS). All calculations are based on a quantum mechanical description of the mobile charge distribution in the channel. This description is based on the solution of the Schrödinger equation in NWT cross sections along the current path, which is mandatory for nanowires with such ultra-scale dimensions.

  11. Intersubband optical transition energy in a CdTe/Zn0.2Cd0.8Te/ZnTe core/shell/shell spherical quantum dot with Smorodinsky-Winternitz confinement potential

    Science.gov (United States)

    Christina lily Jasmine, P.; John Peter, A.; Lee, Chang Woo

    2015-05-01

    Electronic and optical properties of a hydrogenic donor impurity in a CdTe/Zn0.2Cd0.8Te/ZnTe core/shell/shell quantum dot are discussed taking into consideration of geometrical confinement effect. The confining potentials on both the sides of the barrier are different and a two parametrical potential of Smorodinsky-Winternitz is considered in this problem. The dielectric mismatch is included in the Hamiltonian. The position dependent effective mass is applied. The electronic properties are studied using variational method and the optical properties are investigated using the density matrix approach. The intersubband optical absorption, the oscillator strength and the radiative life time between ground and the excited states are studied based on the wave functions and the confined energies with and without the impurity with various dot radii. The results show that the absorption wavelength in type-II core and shell semiconducting nanomaterials can be tuned over a wider range of wavelengths by altering their size and the composition.

  12. Effects of Confinement on Interaction Diagrams of Square Reinforced Concrete Columns

    Directory of Open Access Journals (Sweden)

    Recky Tirtajaya

    2009-01-01

    Full Text Available To prevent brittle failure, the design of a structural column in a seismic-resistant building is of important consideration, particularly in terms of confinement. In the recent building code, the need of closely-spaced stirrups in a structural member, such as column becomes compulsory due to the ductility and strength considerations. However, the design is based on the simplified block stress of unconfined concrete, and does not account for the strength gain due to the presence of confinement. To investigate the effects of lateral confinement on the column capacity, an analytical study is carried out. Both the strength gain in concrete core and the loss of strength in the cover are considered in the analytical models to exhibit the remaining strength gain after the mobilization of strength gain in the core concrete to compensate the loss of strength in the concrete cover. There are six key parameters primarily influence the effectiveness of lateral confinement. The most influencing parameter is found to be the spacing of transverse steel. The presence of closely-spaced lateral confinement significantly increases the magnitude of stress-strain curve of concrete. This increase expands the interaction diagram of the column particularly when it is in the compression-controlled region (for lower-story columns when axial load dominates the behavior.

  13. Effect of Fuelling Depth on the Fusion Performance and Particle Confinement of a Fusion Reactor

    Science.gov (United States)

    Wang, Shijia; Wang, Shaojie

    2016-12-01

    The fusion performance and particle confinement of an international thermonuclear experimental reactor (ITER)-like fusion device have been modeled by numerically solving the energy transport equation and the particle transport equation. The effect of fuelling depth has been investigated. The plasma is primarily heated by the fusion produced alpha particles and the loss process of particles and energy in the scrape-off layer has been taken into account. To study the effect of fuelling depth on fusion performance, the ITERH-98P(y,2) scaling law has been used to evaluate the transport coefficients. It is shown that the particle confinement and fusion performance are significantly dependent on the fuelling depth. Deviation of 10% of the minor radius on fuelling depth can make the particle confinement change by ∼ 61% and the fusion performance change by ∼ 108%. The enhancement of fusion performance is due to the better particle confinement induced by deeper particle fuelling. supported by National Natural Science Foundation of China (Nos. 11175178 and 11375196) and the National Magnetic Confinement Fusion Science Program of China (No. 2014GB113000)

  14. Chaos in effective classical and quantum dynamics

    CERN Document Server

    Casetti, L; Modugno, M; Casetti, Lapo; Gatto, Raoul; Modugno, Michele

    1998-01-01

    We investigate the dynamics of classical and quantum N-component phi^4 oscillators in presence of an external field. In the large N limit the effective dynamics is described by two-degree-of-freedom classical Hamiltonian systems. In the classical model we observe chaotic orbits for any value of the external field, while in the quantum case chaos is strongly suppressed. A simple explanation of this behaviour is found in the change in the structure of the orbits induced by quantum corrections. Consistently with Heisenberg's principle, quantum fluctuations are forced away from zero, removing in the effective quantum dynamics a hyperbolic fixed point that is a major source of chaos in the classical model.

  15. Computational study of the effect of dynamic wall confinement on ventricular filling

    Science.gov (United States)

    Zheng, Xudong; Xue, Qian

    2013-11-01

    Ventricular filling is a major cardiac phase in which the freshly oxygenated blood in the left atrium (LA) enters the left ventricle (LV). There is an increasing consensus that dynamics of transmitral blood flow during filling plays a critical role in dictating overall cardiac health and predicting early changes in cardiac function. The ventricular flow during filling is determined by the interplay of incoming mitral jet and myocardial wall confinement and manifested by a complex morphing pattern of an asymmetric vortex ring. In the current study, we employ computational simulations to explore the effects of dynamic wall confinement on ventricular flow in an idealized left ventricle model. The effects of radial and longitudinal confinement as well as wall motion will be investigated, with special interests on vortex dynamics, such as vortex ring tilting, pinch off and breakdown, intraventricular pressure drop, filling velocity, energy dissipation and blood mixing.

  16. The quantum Hall effects: Philosophical approach

    Science.gov (United States)

    Lederer, P.

    2015-05-01

    The Quantum Hall Effects offer a rich variety of theoretical and experimental advances. They provide interesting insights on such topics as gauge invariance, strong interactions in Condensed Matter physics, emergence of new paradigms. This paper focuses on some related philosophical questions. Various brands of positivism or agnosticism are confronted with the physics of the Quantum Hall Effects. Hacking's views on Scientific Realism, Chalmers' on Non-Figurative Realism are discussed. It is argued that the difficulties with those versions of realism may be resolved within a dialectical materialist approach. The latter is argued to provide a rational approach to the phenomena, theory and ontology of the Quantum Hall Effects.

  17. About empty waves, their effect, and the quantum theory

    CERN Document Server

    Wechsler, Sofia

    2010-01-01

    When a quantum object -- a particle as we call it in a non-rigorous way -- is described by a multi-branched wave- function, with the corresponding wave-packets occupying separated regions of the time-space, a frequently asked question is whether the quantum object is actually contained in only one of these wave-packets. If the answer is positive, then the other wave-packets are called in literature empty waves. The wave-packet containing the object is called a full wave, and is the only one that would produce a recording in a detector. A question immediately arising is whether the empty waves may also have an observable effect. Different works were dedicated to the elucidation of this question. None of them proved that the hypothesis of full/empty waves is correct - it may be that the Nature is indeed non-deterministic and the quantum object is not confined to one region of the space-time. All the works that proved that the empty waves have an effect, in fact, proved that if there exist full and empty waves, ...

  18. Y{sub 2}O{sub 2}S:Eu{sup 3+} nanocrystals, a strong quantum-confined luminescent system

    Energy Technology Data Exchange (ETDEWEB)

    Thirumalai, J. [Luminescence Group, Central Electro Chemical Research Institute, Karaikudi 630 006, Tamil Nadu (India); Jagannathan, R. [Luminescence Group, Central Electro Chemical Research Institute, Karaikudi 630 006, Tamil Nadu (India)]. E-mail: jags57_99@yahoo.com; Trivedi, D.C. [Luminescence Group, Central Electro Chemical Research Institute, Karaikudi 630 006, Tamil Nadu (India)

    2007-10-15

    Trivalent europium-doped yttrium oxysulfide nanocrystals synthesized using sol-gel thermolysis show significant blue shifts in the excitation bands corresponding to fundamental absorption, charge-transfer absorption. A significant blue shift observed in the fundamental absorption edge for the nanocrystals having an average crystallite size ({phi}) in the range 9-15 nm indicates a strong quantum confinement with a Bohr exciton radius of 5-13 nm. Also, the diffuse reflectance spectra and the corresponding Kubelka-Munk plot indicate the possibility of profound decrease in the absorption coefficient of Eu{sup 3+}-ligand charge-transfer species necessitating further studies in this wide-gap semiconductor nanocrystalline system.

  19. Universal Expression of Efficiency at Maximum Power: A Quantum-Mechanical Brayton Engine Working with a Single Particle Confined in a Power-Law Trap

    Science.gov (United States)

    Ye, Zhuo-Lin; Li, Wei-Sheng; Lai, Yi-Ming; He, Ji-Zhou; Wang, Jian-Hui

    2015-12-01

    We propose a quantum-mechanical Brayton engine model that works between two superposed states, employing a single particle confined in an arbitrary power-law trap as the working substance. Applying the superposition principle, we obtain the explicit expressions of the power and efficiency, and find that the efficiency at maximum power is bounded from above by the function: η+ = θ/(θ + 1), with θ being a potential-dependent exponent. Supported by the National Natural Science Foundation of China under Grant Nos. 11505091, 11265010, and 11365015, and the Jiangxi Provincial Natural Science Foundation under Grant No. 20132BAB212009

  20. Thermodynamics of the quantum butterfly effect

    CERN Document Server

    Campisi, Michele

    2016-01-01

    In this letter we consider the quantum analogue of the butterfly effect which is well known in the field of classical non-linear dynamics. Recently, it has been proposed to measure the effect using an out-of-time-order correlator (OTOC) between two local operators. Effectively measuring the degree of non-commutativity in time, this correlator describes the phenomenon of information scrambling in quantum information. Here we show that the butterfly effect can be recast as a two-measurement scheme inspired from the field of non-equilibrium quan- tum thermodynamics. Furthermore, we demonstrate how an OTOC can emerge as the characteristic function of the work distribution. Our realisation not only offers a physically intuitive thermodynamical interpretation of the quantum butterfly effect, it also inspires novel experimental schemes to study the problem of quantum information scrambling.

  1. Quantum Hall effect in momentum space

    Science.gov (United States)

    Ozawa, Tomoki; Price, Hannah M.; Carusotto, Iacopo

    2016-05-01

    We theoretically discuss a momentum-space analog of the quantum Hall effect, which could be observed in topologically nontrivial lattice models subject to an external harmonic trapping potential. In our proposal, the Niu-Thouless-Wu formulation of the quantum Hall effect on a torus is realized in the toroidally shaped Brillouin zone. In this analogy, the position of the trap center in real space controls the magnetic fluxes that are inserted through the holes of the torus in momentum space. We illustrate the momentum-space quantum Hall effect with the noninteracting trapped Harper-Hofstadter model, for which we numerically demonstrate how this effect manifests itself in experimental observables. Extension to the interacting trapped Harper-Hofstadter model is also briefly considered. We finally discuss possible experimental platforms where our proposal for the momentum-space quantum Hall effect could be realized.

  2. Effects of confinement on anomalies and phase transitions of core-softened fluids

    Energy Technology Data Exchange (ETDEWEB)

    Krott, Leandro B., E-mail: leandro.krott@ufrgs.br; Barbosa, Marcia C., E-mail: marciabarbosa@ufrgs.br [Instituto de Física, Universidade Federal do Rio Grande do Sul, Caixa Postal 15051, CEP 91501-970, Porto Alegre, RS (Brazil); Bordin, José Rafael, E-mail: josebordin@unipampa.edu.br [Campus Caçapava do Sul, Universidade Federal do Pampa, Av. Pedro Anunciação, s/n, CEP 96570-000, Caçapava do Sul, RS (Brazil); Barraz, Ney M., E-mail: ney.barraz@uffs.edu.br [Campus Cerro Largo, Universidade Federal da Fronteira Sul, Av. Jacob Reinaldo Haupenthal, 1580. CEP 97900-000, Cerro Largo, RS (Brazil)

    2015-04-07

    We use molecular dynamics simulations to study how the confinement affects the dynamic, thermodynamic, and structural properties of a confined anomalous fluid. The fluid is modeled using an effective pair potential derived from the ST4 atomistic model for water. This system exhibits density, structural, and dynamical anomalies, and the vapor-liquid and liquid-liquid critical points similar to the quantities observed in bulk water. The confinement is modeled both by smooth and structured walls. The temperatures of extreme density and diffusion for the confined fluid show a shift to lower values while the pressures move to higher amounts for both smooth and structured confinements. In the case of smooth walls, the critical points and the limit between fluid and amorphous phases show a non-monotonic change in the temperatures and pressures when the nanopore size is increase. In the case of structured walls, the pressures and temperatures of the critical points varies monotonically with the pore size. Our results are explained on basis of the competition between the different length scales of the fluid and the wall-fluid interaction.

  3. Effect of confinement on melting behavior of cadmium arachidate Langmuir-Blodgett multilayer.

    Science.gov (United States)

    Pandit, Pallavi; Gupta, Ajay; Kumar, Dileep; Banerjee, Mandira; Bernstorff, Sigrid

    2013-03-26

    The effect of confinement between two metallic layers on the melting behavior of a 13 monolayer cadmium arachidate (CdA) Langmuir-Blodgett (LB) multilayer has been studied. Temperature dependent diffraction measurements provide information about structural changes occurring in the film plane as well as in the out-of-plane direction. X-ray standing waves have been used to achieve depth selectivity in diffraction measurements. It is found that the difference in melting behavior of the surface and the bulk, which is observed in the film with free surface, disappears in the case of confined films; while the free surface transforms to hexaticlike phase via an intermediate smectic phase, confinement results in disappearance of this phase, and the sequence of transformations in the bulk and the interfacial regions becomes identical. Some anisotropy between (01 + 11¯) and (10) directions remains, with coherence along (10) direction decreasing at a faster rate. The confinement between metallic layers also significantly reduces the tilting of the chains observed at higher temperature. Further, both in the case of film with free surface and confined films, melting at the surface/interface occurs at a lower temperature as compared to the bulk.

  4. Effects of Thermal Damage and Confining Pressure on the Mechanical Properties of Coarse Marble

    Science.gov (United States)

    Yao, Mengdi; Rong, Guan; Zhou, Chuangbing; Peng, Jun

    2016-06-01

    Heating treatment generally causes thermal damage inside rocks, and the influence of thermal damage on mechanical properties of rocks is an important topic in rock mechanics. The coarse marble specimens drilled out from a rock block were first heated to a specific temperature level of 200, 400 and 600 °C except the control group left at 20 °C. A series of triaxial compression tests subjected to the confining pressure of 0, 5, 10, 15, 20, 25, 30, 35 and 40 MPa were conducted. Coupling effects of thermal damage and confining pressure on the mechanical properties of marbles including post-peak behaviors and failure modes, strength and deformation parameters, characteristic stresses in the progressive failure process had been investigated. Meanwhile, accompanied tests of physical properties were carried out to study the effect of thermal damage on microstructure, porosity and P-wave velocity. Finally, the degradation parameter was defined and a strength-degradation model to describe the peak strength was proposed. Physical investigations show that porosity increases slowly and P-wave velocity reduces dramatically, which could be re-demonstrated by the microscopy results. As for the post-peak behaviors and the failure modes, there is a brittle to ductile transition trend with increasing confining pressure and thermal effect reinforces the ductility to some degree. The comparative study on strength and deformation parameters concludes that heating causes damage and confining pressure inhibits the damage to develop. Furthermore, crack damage stress and crack initiation stress increase, while the ratios of crack damage stress to peak strength and crack initiation stress to peak strength show a decreasing trend with the increase of confining pressure; the magnitude of crack damage stress or crack initiation stress shows a tendency of decrease with the increasing heating temperature and the tendency vanishes subjected to high confinement.

  5. Gravitational and rotational effects in quantum interference

    Energy Technology Data Exchange (ETDEWEB)

    Anandan, J.

    1977-03-15

    The phase shift due to gravitation and rotation in the quantum interference of two coherent beams is obtained relativistically and compared with the recent experiment of Colella, Overhauser, and Werner. A general expression relating the quantum phase shift to the transverse acceleration of a classical particle in the plane of interference for an arbitrary interaction with any external field is given. This can serve as a correspondence principle between quantum physics and classical physics. The phase shift due to the coupling of spin to curvature of space-time is deduced and written explicitly for the special case of a Schwarzschild field. The last result implies that a massless spinning particle can have at most two helicity states and its world line in a gravitational field is a null geodesic. Finally, new experiments are proposed to test the effect of rotation on quantum interference and to obtain direct evidence of the equivalence principle in quantum mechanics.

  6. Rheology of red blood cells under flow in highly confined microchannels. II. Effect of focusing and confinement.

    Science.gov (United States)

    Lázaro, Guillermo R; Hernández-Machado, Aurora; Pagonabarraga, Ignacio

    2014-10-07

    We study the focusing of red blood cells and vesicles in pressure-driven flows in highly confined microchannels (10-30 μm), identifying the control parameters that dictate the cell distribution along the channel. Our results show that an increase in the flow velocity leads to a sharper cell distribution in a lateral position of the channel. This position depends on the channel width, with cells flowing at outer (closer to the walls) positions in thicker channels. We also study the relevance of the object shape, exploring the different behaviour of red blood cells and different vesicles. We also analyze the implications of these phenomena in the cell suspension rheology, highlighting the crucial role of the wall confinement in the rheological properties of the suspension.

  7. Small Scale Plasticity With Confinement and Interfacial Effects

    OpenAIRE

    Habibzadeh, Pouya

    2016-01-01

    The mechanical properties of crystalline metals are strongly affected when the sample size is limited to the micron or sub-micron scale. At these scales, the mechanical properties are enhanced far beyond classical predictions. Besides, the surface to volume ratio significantly increases. Therefore surfaces and interfaces play a big role in the mechanical properties of these micro-samples. The effect of different interfaces on the mechanical properties of micro-samples is not yet well understo...

  8. Effects of confinement & surface roughness in electrorheological flows

    Science.gov (United States)

    Helal, Ahmed; Telleria, Maria J.; Wang, Julie; Strauss, Marc; Murphy, Mike; McKinley, Gareth; Hosoi, A. E.

    2014-11-01

    Electrorheological (ER) fluids are dielectric suspensions that exhibit a fast, reversible change in rheological properties with the application of an external electric field. Upon the application of the electric field, the material develops a field-dependent yield stress that is typically modeled using a Bingham plastic model. ER fluids are promising for designing small, cheap and rapidly actuated hydraulic devices such as rapidly-switchable valves, where fluid flowing in a microchannel can be arrested by applying an external electric field. In the lubrication limit, for a Bingham plastic fluid, the maximum pressure the channel can hold, before yielding, is a function of the field-dependent yield stress, the length of the channel and the electrode gap. In practice, the finite width of the channel and the surface roughness of the electrodes could affect the maximum yield pressure but a quantitative understanding of these effects is currently lacking. In this study, we experimentally investigate the effects of the channel aspect ratio (width/height) and the effects of electrode roughness on the performance of ER valves. Based on this quantitative analysis, we formulate new performance metrics for ER valves as well as design rules for ER valves that will help guide and optimize future designs.

  9. Strategies for effective management of health and safety in confined site construction

    Directory of Open Access Journals (Sweden)

    John Spillane

    2013-12-01

    Full Text Available Purpose: The overall aim of this research is to identify and catalogue the numerous managerial strategies for effective management of health and safety on a confined, urban, construction site. Design/Methodology/Approach: This is achieved by utilising individual interviews, focus groups discussion on selected case studies of confined construction sites, coupled with a questionnaire survey. Findings: The top five key strategies include (1 Employ safe system of work plans to mitigate personnel health and safety issues; (2 Inform personnel, before starting on-site, of the potential issues using site inductions; (3 Effective communication among site personnel; (4 Draft and implement an effective design site layout prior to starting on-site; and (5 Use of banksman (traffic co-ordinator to segregate personnel from vehicular traffic. Practical Implication: The construction sector is one of the leading industries in accident causation and with the continued development and regeneration of our urban centres, confined site construction is quickly becoming the norm - an environment which only fuels accident creation within the construction sector. Originality/Value: This research aids on-site management that requires direction and assistance in the identification and implementation of key strategies for the management of health and safety, particularly in confined construction site environments.

  10. Strategies for effective management of health and safety in confined site construction

    Directory of Open Access Journals (Sweden)

    John Spillane

    2013-12-01

    Full Text Available Purpose: The overall aim of this research is to identify and catalogue the numerous managerial strategies for effective management of health and safety on a confined, urban, construction site. Design/Methodology/Approach: This is achieved by utilising individual interviews, focus groups discussion on selected case studies of confined construction sites, coupled with a questionnaire survey. Findings: The top five key strategies include (1 Employ safe system of work plans to mitigate personnel health and safety issues; (2 Inform personnel, before starting on-site, of the potential issues using site inductions; (3 Effective communication among site personnel; (4 Draft and implement an effective design site layout prior to starting on-site; and (5 Use of banksman (traffic co-ordinator to segregate personnel from vehicular traffic. Practical Implication: The construction sector is one of the leading industries in accident causation and with the continued development and regeneration of our urban centres, confined site construction is quickly becoming the norm - an environment which only fuels accident creation within the construction sector. Originality/Value: This research aids on-site management that requires direction and assistance in the identification and implementation of key strategies for the management of health and safety, particularly in confined construction site environments.

  11. Stark effect in a wedge-shaped quantum box

    CERN Document Server

    Reyes-Esqueda, J A; Castillo-Mussot, M; Vazquez, G J; Reyes-Esqueda, Jorge-Alejandro; Mendoza, Carlos I.; Castillo-Mussot, Marcelo del; Vazquez, Gerardo J.

    2005-01-01

    The effect of an external applied electric field on the electronic ground state energy of a quantum box with a geometry defined by a wedge is studied by carrying out a variational calculation. This geometry could be used as an approximation for a tip of a cantilever of an atomic force microscope. We study theoretically the Stark effect as function of the parameters of the wedge: its diameter, angular aperture and thickness; as well as function of the intensity of the external electric field applied along the axis of the wedge in both directions; pushing the carrier towards the wider or the narrower parts. A confining electronic effect, which is sharper as the wedge dimensions are smaller, is clearly observed for the first case. Besides, the sign of the Stark shift changes when the angular aperture is changed from small angles to angles theta>pi. For the opposite field, the electronic confinement for large diameters is very small and it is also observed that the Stark shift is almost independent with respect t...

  12. Turbulent transport of impurities and their effect on energy confinement

    CERN Document Server

    Pusztai, I; Fulop, T; Candy, J

    2012-01-01

    By presenting linear and nonlinear gyrokinetic similarity studies, based on a balanced neutral beam injection deuterium discharge from the DIII-D tokamak, we demonstrate that impurities alter the scaling of the transport on the charge and mass of the main species, and even more importantly, they can dramatically change the energy transport even in relatively small quantities. A poloidally varying equilibrium electrostatic potential can lead to a strong reduction or sign change of the impurity peaking factor due to the combined effect of the in-out impurity density asymmetry and the EXB drift of impurities. We present an approximate expression for the impurity peaking factor and demonstrate that impurity peaking is not significantly affected by impurity self-collisions.

  13. Size Effect of a Negatively Charged Exciton in a Two-Dimensional Quantum Dot

    Institute of Scientific and Technical Information of China (English)

    LIU Chao; XIE Wen-Fang

    2009-01-01

    In this paper we study a negatively charged exciton (NCE), which is trapped by a two-dimensional (2D) parabolic potential.By using matrix diagonalization techniques, the correlation energies of the low-lying states with L = O, 1, and 2 are calculated as a function of confinement strength.We find that the size effects of different states are different.This phenomenon can be explained as a hidden symmetry, which is originated purely from symmetry.Based on symmetry, the features of the low-lying states are discussed in the influence of the 2D parabolic potential well.It is found that the confinement may cause accidental degeneracies between levels with different low-excited states.It is shown that the effect of quantum confinement on the binding energy of the heavy hole is stronger than that of a light hole.

  14. Confined Crystal Growth in Space. Deterministic vs Stochastic Vibroconvective Effects

    Science.gov (United States)

    Ruiz, Xavier; Bitlloch, Pau; Ramirez-Piscina, Laureano; Casademunt, Jaume

    The analysis of the correlations between characteristics of the acceleration environment and the quality of the crystalline materials grown in microgravity remains an open and interesting question. Acceleration disturbances in space environments usually give rise to effective gravity pulses, gravity pulse trains of finite duration, quasi-steady accelerations or g-jitters. To quantify these disturbances, deterministic translational plane polarized signals have largely been used in the literature [1]. In the present work, we take an alternative approach which models g-jitters in terms of a stochastic process in the form of the so-called narrow-band noise, which is designed to capture the main statistical properties of realistic g-jitters. In particular we compare their effects so single-frequency disturbances. The crystalline quality has been characterized, following previous analyses, in terms of two parameters, the longitudinal and the radial segregation coefficients. The first one averages transversally the dopant distribution, providing continuous longitudinal information of the degree of segregation along the growth process. The radial segregation characterizes the degree of lateral non-uniformity of the dopant in the solid-liquid interface at each instant of growth. In order to complete the description, and because the heat flux fluctuations at the interface have a direct impact on the crystal growth quality -growth striations -the time dependence of a Nusselt number associated to the growing interface has also been monitored. For realistic g-jitters acting orthogonally to the thermal gradient, the longitudinal segregation remains practically unperturbed in all simulated cases. Also, the Nusselt number is not significantly affected by the noise. On the other hand, radial segregation, despite its low magnitude, exhibits a peculiar low-frequency response in all realizations. [1] X. Ruiz, "Modelling of the influence of residual gravity on the segregation in

  15. Effect of crack size on gas leakage characteristics in a confined space

    Energy Technology Data Exchange (ETDEWEB)

    Sung, Kun Hyuk; Ryou, Hong Sun; Yoon, Kee Bong; Lee, Hy Uk; Bang, Joo Won [Chung-Ang University, Seoul (Korea, Republic of); Li, Longnan; Choi, Jin Wook; Kim, Dae Joong [Sogang University, Seoul (Korea, Republic of)

    2016-07-15

    We numerically investigated the influence of crack size on gas leakage characteristics in a confined space. The real scale model of underground Combined cycle power plant (CCPP) was taken for simulating gas leakage characteristics for different crack sizes such as 10 mm, 15 mm and 20 mm. The commercial code of Fluent (v.16.1) was used for three-dimensional simulation. In particular, a risk region showing such a probability of ignition was newly suggested with the concept of Lower flammable limit (LFL) of methane gas used in the present study to characterize the gas propagation and the damage area in space. From the results, the longitudinal and transverse leakage distances were estimated and analyzed for quantitative evaluation of risk area. The crack size was found to have a great impact on the longitudinal leakage distance, showing an increasing tendency with the crack size. In case of a crack size of 20 mm, the longitudinal leakage distance suddenly increased after 180 s, whereas it remained constant after 2 s in the other cases. This is because a confinement effect, which is caused by circulation flows in the whole space, increased the gas concentration near the gas flow released from the crack. The confinement effect is thus closely associated with the released mass flow rate changing with the crack size. This result would be useful in designing the gas detector system for preventing accidents in the confined space as like CCPP.

  16. 1D versus 3D quantum confinement in 1-5 nm ZnO nanoparticle agglomerations for application in charge-trapping memory devices

    Science.gov (United States)

    El-Atab, Nazek; Nayfeh, Ammar

    2016-07-01

    ZnO nanoparticles (NPs) have attracted considerable interest from industry and researchers due to their excellent properties with applications in optoelectronic devices, sunscreens, photocatalysts, sensors, biomedical sciences, etc. However, the agglomeration of NPs is considered to be a limiting factor since it can affect the desirable physical and electronic properties of the NPs. In this work, 1-5 nm ZnO NPs deposited by spin- and dip-coating techniques are studied. The electronic and physical properties of the resulting agglomerations of NPs are studied using UV-vis-NIR spectroscopy, atomic force microscopy (AFM), and transmission electron microscopy (TEM), and their application in metal-oxide-semiconductor (MOS) memory devices is analyzed. The results show that both dip- and spin-coating techniques lead to agglomerations of the NPs mostly in the horizontal direction. However, the width of the ZnO clusters is larger with dip-coating which leads to 1D quantum confinement, while the smaller ZnO clusters obtained by spin-coating enable 3D quantum confinement in ZnO. The ZnO NPs are used as the charge-trapping layer of a MOS-memory structure and the analysis of the high-frequency C-V measurements allow further understanding of the electronic properties of the ZnO agglomerations. A large memory window is achieved in both devices which confirms that ZnO NPs provide large charge-trapping density. In addition, ZnO confined in 3D allows for a larger memory window at lower operating voltages due to the Poole-Frenkel charge-emission mechanism.

  17. On the Nature of Nonperturbative Effects in Stabilized 2D Quantum Gravity

    CERN Document Server

    Diego, O; Diego, Oscar; Gonzalez, Jose

    1994-01-01

    We remark that the weak coupling regime of the stochastic stabilization of 2D quantum gravity has a unique perturbative vacuum, which does not support instanton configurations. By means of Monte Carlo simulations we show that the nonperturbative vacuum is also confined in one potential well. Nonperturbative effects can be assessed in the loop equation. This can be derived from the Ward identities of the stabilized model and is shown to be modified by nonperturbative terms.

  18. Coherent quantum effects through dispersive bosonic media

    CERN Document Server

    Ye, Sai-Yun; Zheng, Shi-Biao; Serafini, Alessio

    2010-01-01

    The coherent evolution of two atomic qubits mediated by a set of bosonic field modes is investigated. By assuming a specific encoding of the quantum states in the internal levels of the two atoms we show that entangling quantum gates can be realised, with high fidelity, even when a large number of mediating modes is involved. The effect of losses and imperfections on the gates' operation is also considered in detail.

  19. Algorithmic quantum simulation of memory effects

    Science.gov (United States)

    Alvarez-Rodriguez, U.; Di Candia, R.; Casanova, J.; Sanz, M.; Solano, E.

    2017-02-01

    We propose a method for the algorithmic quantum simulation of memory effects described by integrodifferential evolution equations. It consists in the systematic use of perturbation theory techniques and a Markovian quantum simulator. Our method aims to efficiently simulate both completely positive and nonpositive dynamics without the requirement of engineering non-Markovian environments. Finally, we find that small error bounds can be reached with polynomially scaling resources, evaluated as the time required for the simulation.

  20. Confinement and correlation effects in the Xe@C60 generalized oscillator strengths

    CERN Document Server

    Amusia, M Ya; Dolmatov, V K

    2011-01-01

    The impact of both confinement and electron correlation on generalized oscillator strengths (GOS's) of endohedral atoms, A@C60, is theoretically studied choosing the Xe@C60 4d, 5s, and 5p fast electron impact ionization as the case study. Calculations are performed in the transferred to the atom energy region beyond the 4d threshold, omega = 75--175 eV. The calculation methodology combines the plane wave Born approximation, Hartree-Fock approximation, and random phase approximation with exchange in the presence of the C60 confinement. The confinement is modeled by a spherical delta-function-like potential as well as by a square well potential to evaluate the effect of the finite thickness of the C60 cage on the Xe@C60 GOS's. Dramatic distortion of the 4d, 5p, and 5s GOS's by the confinement is demonstrated, compared to the free atom. Considerable contributions of multipolar transitions beyond dipole transitions in the calculated GOS's is revealed, in some instances. The vitality of accounting for electron cor...

  1. Holographic Schwinger Effect in a Confining D3-Brane Background with Chemical Potential

    Directory of Open Access Journals (Sweden)

    Zi-qiang Zhang

    2016-01-01

    Full Text Available Using the AdS/CFT correspondence, we investigate the Schwinger effect in a confining D3-brane background with chemical potential. The potential between a test particle pair on the D3-brane in an external electric field is obtained. The critical field Ec in this case is calculated. Also, we apply numerical method to evaluate the production rate for various cases. The results imply that the presence of chemical potential tends to suppress the pair production effect.

  2. Effects of confinement duration and parity on stereotypic behavioral and physiological responses of pregnant sows.

    Science.gov (United States)

    Zhang, Ming-Yue; Li, Xiang; Zhang, Xiao-Hui; Liu, Hong-Gui; Li, Jian-Hong; Bao, Jun

    2017-10-01

    The aim of this study was to evaluate the effects of space restriction stress on the stereotypic behavioral and physiological responses of different parity sows, and it is necessary to understand such effects due to space restriction to improve the welfare of the sows in confined conditions. We selected fifty pregnant sows (Large White) at primiparity and first to fifth parity in a confined farm with the same body condition and due date (3±1.5days). Behavioral observations and physiological analysis were carried out during spatial confinement throughout pregnancy. The results showed that there were no significant changes in vacuum-chewing, bar-biting, trough-biting and the concentrations of serum IL-6 in primiparous sows during the initial confinement (0-8days). With the increase of the confinement duration, the serum cortisol, IgA, IL-6 concentrations and the vacuum-chewing frequency of sows in all groups increased significantly, and the serum concentrations of C-reactive protein and Pig-MAP increased significantly except for the sows in the first and second parity groups. The serum cortisol, IgA, IL-6 concentrations and the vacuum-chewing frequency of older sows were significantly higher than those of the young sows throughout the entire restricted feeding period, but the serum C-reactive protein concentrations of primiparous gilts was significantly higher than those of the other groups. The serum cortisol, IgA, IL-6 concentrations and bar-biting and trough-biting frequencies of all parity sows decreased significantly after entering the delivery bed. In conclusion, long-lasting and recurrent environmental constraints can significantly increase the frequency of stereotypical behavior and serious psychological and physical stress, seriously damaging sow welfare. Copyright © 2017 Elsevier Inc. All rights reserved.

  3. Quantum confinement-tunable ultrafast charge transfer at the PbS quantum dot and phenyl-C61-butyric acid methyl ester interface

    KAUST Repository

    El-Ballouli, AlA'A O.

    2014-05-14

    Quantum dot (QD) solar cells have emerged as promising low-cost alternatives to existing photovoltaic technologies. Here, we investigate charge transfer and separation at PbS QDs and phenyl-C61-butyric acid methyl ester (PCBM) interfaces using a combination of femtosecond broadband transient absorption (TA) spectroscopy and steady-state photoluminescence quenching measurements. We analyzed ultrafast electron injection and charge separation at PbS QD/PCBM interfaces for four different QD sizes and as a function of PCBM concentration. The results reveal that the energy band alignment, tuned by the quantum size effect, is the key element for efficient electron injection and charge separation processes. More specifically, the steady-state and time-resolved data demonstrate that only small-sized PbS QDs with a bandgap larger than 1 eV can transfer electrons to PCBM upon light absorption. We show that these trends result from the formation of a type-II interface band alignment, as a consequence of the size distribution of the QDs. Transient absorption data indicate that electron injection from photoexcited PbS QDs to PCBM occurs within our temporal resolution of 120 fs for QDs with bandgaps that achieve type-II alignment, while virtually all signals observed in smaller bandgap QD samples result from large bandgap outliers in the size distribution. Taken together, our results clearly demonstrate that charge transfer rates at QD interfaces can be tuned by several orders of magnitude by engineering the QD size distribution. The work presented here will advance both the design and the understanding of QD interfaces for solar energy conversion. © 2014 American Chemical Society.

  4. Effective pure states for bulk quantum computation

    Energy Technology Data Exchange (ETDEWEB)

    Knill, E.; Chuang, I.; Laflamme, R.

    1997-11-01

    In bulk quantum computation one can manipulate a large number of indistinguishable quantum computers by parallel unitary operations and measure expectation values of certain observables with limited sensitivity. The initial state of each computer in the ensemble is known but not pure. Methods for obtaining effective pure input states by a series of manipulations have been described by Gershenfeld and Chuang (logical labeling) and Corey et al. (spatial averaging) for the case of quantum computation with nuclear magnetic resonance. We give a different technique called temporal averaging. This method is based on classical randomization, requires no ancilla qubits and can be implemented in nuclear magnetic resonance without using gradient fields. We introduce several temporal averaging algorithms suitable for both high temperature and low temperature bulk quantum computing and analyze the signal to noise behavior of each.

  5. Effective operator formalism for open quantum systems

    DEFF Research Database (Denmark)

    Reiter, Florentin; Sørensen, Anders Søndberg

    2012-01-01

    We present an effective operator formalism for open quantum systems. Employing perturbation theory and adiabatic elimination of excited states for a weakly driven system, we derive an effective master equation which reduces the evolution to the ground-state dynamics. The effective evolution...

  6. Wide Effectiveness of a Sine Basis for Quantum-Mechanical Problems in d Dimensions

    Directory of Open Access Journals (Sweden)

    Richard L. Hall

    2013-01-01

    Full Text Available It is shown that the spanning set for L2([0,1] provided by the eigenfunctions {2sin(nπx}n=1∞ of the particle in a box in quantum mechanics provides a very effective variational basis for more general problems. The basis is scaled to [a,b], where a and b are then used as variational parameters. What is perhaps a natural basis for quantum systems confined to a spherical box in Rd turns out to be appropriate also for problems that are softly confined by U-shaped potentials, including those with strong singularities at r=0. Specific examples are discussed in detail, along with some bound N-boson systems.

  7. Effects of Electron-Phonon Interaction on Linear and Nonlinear Optical Absorption in Cylindrical Quantum Wires

    Institute of Scientific and Technical Information of China (English)

    YU You-Bin

    2008-01-01

    The electron-phonon interaction influences on linear and nonlinear optical absorption in cylindrical quantum wires (CQW) with an infinite confining potential are investigated. The optical absorption coefficients are obtained by using the compact-density-matrix approach and iterative method, and the numerical results are presented for GaAs CQW. The results show that the electron-phonon interaction makes a distinct influence on optical absorption in CQW. The electron-phonon interaction on the wave functions of electron dominates the values of absorption coefficients and the correction of the electron-phonon effect on the energies of the electron makes the absorption peaks blue shift and become wider. Moreover, the electron-phonon interaction influence on optical absorption with an infinite confining potential is different from that with a finite confining potential.

  8. Influence of boundary conditions and confinement on nonlocal effects in flows of wormlike micellar systems.

    Science.gov (United States)

    Masselon, Chloé; Colin, Annie; Olmsted, Peter D

    2010-02-01

    In this paper we report on the influence of different geometric and boundary constraints on nonlocal (spatially inhomogeneous) effects in wormlike micellar systems. In a previous paper, nonlocal effects were observable by measuring the local rheological flow curves of micelles flowing in a microchannel under different pressure drops, which appeared to differ from the flow curve measured using conventional rheometry. Here we show that both the confinement and the boundary conditions can influence those nonlocal effects. The role of the nature of the surface is analyzed in detail using a simple scalar model that incorporates inhomogeneities, which captures the flow behavior in both wide and confined geometries. This leads to an estimate for the nonlocal "diffusion" coefficient (i.e., the shear curvature viscosity) which corresponds to a characteristic length from 1 to 10 microm.

  9. Quantum Gravity signatures in the Unruh effect

    CERN Document Server

    Alkofer, Natalia; Saueressig, Frank; Versteegen, Fleur

    2016-01-01

    We study quantum gravity signatures emerging from phenomenologically motivated multiscale models, spectral actions, and Causal Set Theory within the detector approach to the Unruh effect. We show that while the Unruh temperature is unaffected, Lorentz-invariant corrections to the two-point function leave a characteristic fingerprint in the induced emission rate of the accelerated detector. Generically, quantum gravity models exhibiting dynamical dimensional reduction exhibit a suppression of the Unruh rate at high energy while the rate is enhanced in Kaluza-Klein theories with compact extra dimensions. We quantify this behavior by introducing the "Unruh dimension" as the effective spacetime dimension seen by the Unruh effect and show that it is related, though not identical, to the spectral dimension used to characterize spacetime in quantum gravity. We comment on the physical origins of these effects and their relevance for black hole evaporation.

  10. Quantum gravity signatures in the Unruh effect

    Science.gov (United States)

    Alkofer, Natalia; D'Odorico, Giulio; Saueressig, Frank; Versteegen, Fleur

    2016-11-01

    We study quantum gravity signatures emerging from phenomenologically motivated multiscale models, spectral actions, and causal set theory within the detector approach to the Unruh effect. We show that while the Unruh temperature is unaffected, Lorentz-invariant corrections to the two-point function leave a characteristic fingerprint in the induced emission rate of the accelerated detector. Generically, quantum gravity models exhibiting dynamical dimensional reduction exhibit a suppression of the Unruh rate at high energy while the rate is enhanced in Kaluza-Klein theories with compact extra dimensions. We quantify this behavior by introducing the "Unruh dimension" as the effective spacetime dimension seen by the Unruh effect and show that it is related, though not identical, to the spectral dimension used to characterize spacetime in quantum gravity. We comment on the physical origins of these effects and their relevance for black hole evaporation.

  11. High-power low-threshold graded-index separate confinement heterostructure AlGaAs single quantum well lasers on Si substrates

    Science.gov (United States)

    Kim, Jae-Hoon; Lang, Robert J.; Radhakrishnan, Gouri; Katz, Joseph; Narayanan, Authi A.

    1989-01-01

    A high-power low-threshold graded-index separate confinement heterostructure AlGaAs single quantum well laser on Si substrates has been demonstrated for the first time by a hybrid growth of migration-enhanced molecular beam epitaxy followed by metalorganic vapor phase epitaxy. The quantum well laser showed an output power of more than 400 mW per facet under pulsed conditions. A room-temperature threshold current of 300 mA was obtained with a differential quantum efficiency of 40 percent without facet coating. The threshold current density was 550 A/sq cm for a cavity length of 500 microns. These results show the highest peak power reported to date for low-threshold lasers on Si substrates. The full width at half maximum of the far-field pattern parallel to the junction was 6 deg. Threshold current densities as low as 250 A/sq cm were obtained for lasers on GaAs substrates.

  12. The effect of normobaric hypoxic confinement on metabolism, gut hormones and body composition

    Directory of Open Access Journals (Sweden)

    Igor B. Mekjavic

    2016-06-01

    Full Text Available To assess the effect of normobaric hypoxia on metabolism, gut hormones and body composition, eleven normal weight, aerobically trained ( O2peak: 60.6±9.5 ml·kg-1·min-1 men (73.0±7.7 kg; 23.7±4.0 yrs, BMI 22.2±2.4 kg·m-2 were confined to a normobaric (altitude⋍940m normoxic (NORMOXIA; PIO2⋍133.2 mmHg or normobaric hypoxic (HYPOXIA; PIO was reduced from 105.6 to 97.7 mmHg over 10 days environment for 10 days in a randomized cross-over design. The wash-out period between confinements was 3 weeks. During each 10-day period, subjects avoided strenuous physical activity and were under continuous nutritional control. Before, and at the end of each exposure, subjects completed a meal tolerance test, during which blood glucose, insulin, GLP-1, ghrelin, peptide-YY, adrenaline, noradrenaline, leptin, and gastro-intestinal blood flow and appetite sensations were measured. There was no significant change in body weight in either of the confinements (NORMOXIA: -0.7±0.2 kg; HYPOXIA: -0.9±0.2 kg, but a significant increase in fat mass in NORMOXIA (0.23±0.45 kg, but not in HYPOXIA (0.08±0.08 kg. HYPOXIA confinement increased fasting noradrenaline and decreased energy intake, the latter most likely associated with increased fasting leptin. The majority of all other measured variables/responses were similar in NORMOXIA and HYPOXIA. To conclude, normobaric hypoxic confinement without exercise training results in negative energy balance due to primarily reduced energy intake.

  13. Toward simulating complex systems with quantum effects

    Science.gov (United States)

    Kenion-Hanrath, Rachel Lynn

    Quantum effects like tunneling, coherence, and zero point energy often play a significant role in phenomena on the scales of atoms and molecules. However, the exact quantum treatment of a system scales exponentially with dimensionality, making it impractical for characterizing reaction rates and mechanisms in complex systems. An ongoing effort in the field of theoretical chemistry and physics is extending scalable, classical trajectory-based simulation methods capable of capturing quantum effects to describe dynamic processes in many-body systems; in the work presented here we explore two such techniques. First, we detail an explicit electron, path integral (PI)-based simulation protocol for predicting the rate of electron transfer in condensed-phase transition metal complex systems. Using a PI representation of the transferring electron and a classical representation of the transition metal complex and solvent atoms, we compute the outer sphere free energy barrier and dynamical recrossing factor of the electron transfer rate while accounting for quantum tunneling and zero point energy effects. We are able to achieve this employing only a single set of force field parameters to describe the system rather than parameterizing along the reaction coordinate. Following our success in describing a simple model system, we discuss our next steps in extending our protocol to technologically relevant materials systems. The latter half focuses on the Mixed Quantum-Classical Initial Value Representation (MQC-IVR) of real-time correlation functions, a semiclassical method which has demonstrated its ability to "tune'' between quantum- and classical-limit correlation functions while maintaining dynamic consistency. Specifically, this is achieved through a parameter that determines the quantumness of individual degrees of freedom. Here, we derive a semiclassical correction term for the MQC-IVR to systematically characterize the error introduced by different choices of simulation

  14. The quantum Hall's effect:A quantum electrodynamic phenomenon

    Institute of Scientific and Technical Information of China (English)

    A.I. Arbab

    2012-01-01

    We have applied Maxwell's equations to study the physics of quantum Hall's effect.The electromagnetic properties of this system are obtained.The Hall's voltage,VH =2πh2ns/e rn,where ns is the electron number density,for a 2-dimensional system,and h =2πh is the Planck's constant,is found to coincide with the voltage drop across the quantum capacitor.Consideration of the cyclotronic motion of electrons is found to give rise to Hall's resistance.Ohmic resistances in the horizontal and vertical directions have been found to exist before equilibrium state is reached.At a fundamental level,the Hall's effect is found to be equivalent to a resonant LCR circuit with LH =2π m/e2ns and CH =me2/2πh2ns satisfying the resonance condition with resonant frequency equal to the inverse of the scattering (relaxation) time,Ts.The Hall's resistance is found to be RH =√LH/CH.The Hall's resistance may be connected with the impedance that the electron wave experiences when it propagates in the 2-dimeasional gas.

  15. Quantum metrology and estimation of Unruh effect.

    Science.gov (United States)

    Wang, Jieci; Tian, Zehua; Jing, Jiliang; Fan, Heng

    2014-11-26

    We study the quantum metrology for a pair of entangled Unruh-Dewitt detectors when one of them is accelerated and coupled to a massless scalar field. Comparing with previous schemes, our model requires only local interaction and avoids the use of cavities in the probe state preparation process. We show that the probe state preparation and the interaction between the accelerated detector and the external field have significant effects on the value of quantum Fisher information, correspondingly pose variable ultimate limit of precision in the estimation of Unruh effect. We find that the precision of the estimation can be improved by a larger effective coupling strength and a longer interaction time. Alternatively, the energy gap of the detector has a range that can provide us a better precision. Thus we may adjust those parameters and attain a higher precision in the estimation. We also find that an extremely high acceleration is not required in the quantum metrology process.

  16. Effect of morphology on spectral properties of magneto-trion X{sup +} in vertically coupled type II quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Horta-Piñeres, Sindi, E-mail: sdhorta@yahoo.es [Group of Investigation in Condensed Matter Theory, Universidad del Magdalena, Santa Marta (Colombia); Universidad de Sucre, Sincelejo (Colombia); Elizabeth Escorcia-Salas, G., E-mail: elizabethescorcia@gmail.com [Group of Investigation in Condensed Matter Theory, Universidad del Magdalena, Santa Marta (Colombia); Mikhailov, I.D., E-mail: mikhail2811@gmail.com [Universidad Industrial de Santander, Apartado Aereo 678, Bucaramanga (Colombia); Sierra-Ortega, J., E-mail: jsierraortega@gmail.com [Group of Investigation in Condensed Matter Theory, Universidad del Magdalena, Santa Marta (Colombia)

    2014-11-15

    The energy spectrum of a positively charged exciton confined in vertically coupled type II quantum dots with different morphologies in the presence of the external magnetic field is studied. The effect of the quantum dot morphology on the curves of the lowest energy levels as functions of the magnetic field is analyzed. It is shown that a strong correlation presented in this system generates the Aharonov–Bohm oscillations of the lower energy levels similar to those in wide quantum ring. The novel curves of the trion energies dependences on the external magnetic field for the disk-like, lens-like, and cone-like structures are presented.

  17. Generalized Sturmians in the time-dependent frame: effect of a fullerene confining potential

    Science.gov (United States)

    Frapiccini, Ana Laura; Gasaneo, Gustavo; Mitnik, Dario M.

    2017-02-01

    In this work we present a novel implementation of the Generalized Sturmian Functions in the time-dependent frame to numerically solve the time-dependent Schrödinger equation. We study the effect of the confinement of H atom in a fullerene cage for the 1s → 2p resonant transition of the atom interacting with a finite laser pulse, calculating the population of bound states and spectral density.

  18. Quantum anomalous Hall effect in real materials

    Science.gov (United States)

    Zhang, Jiayong; Zhao, Bao; Zhou, Tong; Yang, Zhongqin

    2016-11-01

    Under a strong magnetic field, the quantum Hall (QH) effect can be observed in two-dimensional electronic gas systems. If the quantized Hall conductivity is acquired in a system without the need of an external magnetic field, then it will give rise to a new quantum state, the quantum anomalous Hall (QAH) state. The QAH state is a novel quantum state that is insulating in the bulk but exhibits unique conducting edge states topologically protected from backscattering and holds great potential for applications in low-power-consumption electronics. The realization of the QAH effect in real materials is of great significance. In this paper, we systematically review the theoretical proposals that have been brought forward to realize the QAH effect in various real material systems or structures, including magnetically doped topological insulators, graphene-based systems, silicene-based systems, two-dimensional organometallic frameworks, quantum wells, and functionalized Sb(111) monolayers, etc. Our paper can help our readers to quickly grasp the recent developments in this field. Project supported by the National Basic Research Program of China (Grant No. 2011CB921803), the National Natural Science Foundation of China (Grant No. 11574051), the Natural Science Foundation of Shanghai, China (Grant No. 14ZR1403400), and Fudan High-end Computing Center, China.

  19. Quantum gravity, effective fields and string theory

    CERN Document Server

    Bjerrum-Bohr, N E J

    2004-01-01

    We look at the various aspects of treating general relativity as a quantum theory. It is briefly studied how to consistently quantize general relativity as an effective field theory. A key achievement here is the long-range low-energy leading quantum corrections to both the Schwarzschild and Kerr metrics. The leading quantum corrections to the pure gravitational potential between two sources are also calculated, both in the mixed theory of scalar QED and quantum gravity and in the pure gravitational theory. The (Kawai-Lewellen-Tye) string theory gauge/gravity relations is next dealt with. We investigate if the KLT-operator mapping extends to the case of higher derivative effective operators. The KLT-relations are generalized, taking the effective field theory viewpoint, and remarkable tree-level amplitude relations between the field theory operators are derived. Quantum gravity is finally looked at from the the perspective of taking the limit of infinitely many spatial dimensions. It is verified that only a c...

  20. Ion-specific effects under confinement: the role of interfacial water.

    Science.gov (United States)

    Argyris, Dimitrios; Cole, David R; Striolo, Alberto

    2010-04-27

    All-atom molecular dynamics simulations were employed for the study of the structure and dynamics of aqueous electrolyte solutions within slit-shaped silica nanopores with a width of 10.67 A at ambient temperature. All simulations were conducted for 250 ns to capture the dynamics of ion adsorption and to obtain the equilibrium distribution of multiple ionic species (Na+, Cs+, and Cl(-)) within the pores. The results clearly support the existence of ion-specific effects under confinement, which can be explained by the properties of interfacial water. Cl(-) strongly adsorbs onto the silica surface. Although neither Na+ nor Cs+ is in contact with the solid surface, they show ion-specific behavior. The differences between the density distributions of cations within the pore are primarily due to size effects through their interaction with confined water molecules. The majority of Na+ ions appear within one water layer in close proximity to the silica surface, whereas Cs+ is excluded from well-defined water layers. As a consequence of this preferential distribution, we observe enhanced in-plane mobility for Cs+ ions, found near the center of the pore, compared to that for Na+ ions, closer to the solid substrate. These observations illustrate the key role of interfacial water in determining ion-specific effects under confinement and have practical importance in several fields, from geology to biology.

  1. Gravitational Waves in Effective Quantum Gravity

    Energy Technology Data Exchange (ETDEWEB)

    Calmet, Xavier; Kuntz, Ibere; Mohapatra, Sonali [University of Sussex, Physics and Astronomy, Brighton (United Kingdom)

    2016-08-15

    In this short paper we investigate quantum gravitational effects on Einstein's equations using Effective Field Theory techniques. We consider the leading order quantum gravitational correction to the wave equation. Besides the usual massless mode, we find a pair of modes with complex masses. These massive particles have a width and could thus lead to a damping of gravitational waves if excited in violent astrophysical processes producing gravitational waves such as e.g. black hole mergers. We discuss the consequences for gravitational wave events such as GW 150914 recently observed by the Advanced LIGO collaboration. (orig.)

  2. Effective constraints of loop quantum gravity

    CERN Document Server

    Bojowald, M; Kagan, M; Skirzewski, A; Bojowald, Martin; Hernandez, Hector; Kagan, Mikhail; Skirzewski, Aureliano

    2006-01-01

    Within a perturbative cosmological regime of loop quantum gravity corrections to effective constraints are computed. This takes into account all inhomogeneous degrees of freedom relevant for scalar metric modes around flat space and results in explicit expressions for modified coefficients and of higher order terms. It also illustrates the role of different scales determining the relative magnitude of corrections. Our results demonstrate that loop quantum gravity has the correct classical limit, at least in its sector of cosmological perturbations around flat space, in the sense of perturbative effective theory.

  3. The kinetic magnetoelectric effect in laterally boundary-confined ballistic two-dimensional hole gases

    Institute of Scientific and Technical Information of China (English)

    Huang Hai-Tao; Hu Liang-Bin; Zhang Xin-Ding; Zhu Shi-Liang

    2009-01-01

    A theoretical investigation is presented on the characteristics of the kinetic magnetoelectric effect in laterally boundary-confined ballistic two-dimensional hole gases.It was shown that,though the momentum-dependent effective magnetic fields felt by charge carriers due to the spin-orbit interaction are in-plane orientated in such systems,both in-plane polarized and normal polarized nonequilibrium spin polarization densities could be electrically induced by the kinetic magnetoelectric effect,and the induced nonequilibrium spin polarizations exhibit some interesting characteristics.The characteristics we found indicate that there may be some possible relation between this effect and some recent experimental findings.

  4. Quantum and isotope effects in lithium metal

    Science.gov (United States)

    Ackland, Graeme J.; Dunuwille, Mihindra; Martinez-Canales, Miguel; Loa, Ingo; Zhang, Rong; Sinogeikin, Stanislav; Cai, Weizhao; Deemyad, Shanti

    2017-06-01

    The crystal structure of elements at zero pressure and temperature is the most fundamental information in condensed matter physics. For decades it has been believed that lithium, the simplest metallic element, has a complicated ground-state crystal structure. Using synchrotron x-ray diffraction in diamond anvil cells and multiscale simulations with density functional theory and molecular dynamics, we show that the previously accepted martensitic ground state is metastable. The actual ground state is face-centered cubic (fcc). We find that isotopes of lithium, under similar thermal paths, exhibit a considerable difference in martensitic transition temperature. Lithium exhibits nuclear quantum mechanical effects, serving as a metallic intermediate between helium, with its quantum effect-dominated structures, and the higher-mass elements. By disentangling the quantum kinetic complexities, we prove that fcc lithium is the ground state, and we synthesize it by decompression.

  5. Mesoscopic effects in the quantum Hall regime

    Indian Academy of Sciences (India)

    R N Bhatt; Xin Wan

    2002-02-01

    We report results of a study of (integer) quantum Hall transitions in a single or multiple Landau levels for non-interacting electrons in disordered two-dimensional systems, obtained by projecting a tight-binding Hamiltonian to the corresponding magnetic subbands. In finite-size systems, we find that mesoscopic effects often dominate, leading to apparent non-universal scaling behavior in higher Landau levels. This is because localization length, which grows exponentially with Landau level index, exceeds the system sizes amenable to the numerical study at present. When band mixing between multiple Landau levels is present, mesoscopic effects cause a crossover from a sequence of quantum Hall transitions for weak disorder to classical behavior for strong disorder. This behavior may be of relevance to experimentally observed transitions between quantum Hall states and the insulating phase at low magnetic fields.

  6. Loop quantum gravity as an effective theory

    CERN Document Server

    Bojowald, Martin

    2012-01-01

    As a canonical and generally covariant gauge theory, loop quantum gravity requires special techniques to derive effective actions or equations. If the proper constructions are taken into account, the theory, in spite of considerable ambiguities at the dynamical level, allows for a meaningful phenomenology to be developed, by which it becomes falsifiable. The tradiational problems plaguing canonical quantum-gravity theories, such as the anomaly issue or the problem of time, can be overcome or are irrelevant at the effective level, resulting in consistent means of physical evaluations. This contribution presents aspects of canonical equations and related notions of (deformed) space-time structures and discusses implications in loop quantum gravity, such as signature change at high density from holonomy corrections, and falsifiability thanks to inverse-triad corrections.

  7. SiO{sub {ital x}} luminescence from light-emitting porous silicon: Support for the quantum confinement/luminescence center model

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, D.W.; Bennett, B.L.; Farnum, E.H.; Hults, W.L.; Sickafus, K.E.; Smith, J.F.; Smith, J.L.; Taylor, T.N.; Tiwari, P. [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Portis, A.M. [Department of Physics, University of California, Berkeley, California 94720 (United States)

    1996-03-01

    Measurements of hydrogen loss and luminescence as a function of annealing temperature in porous silicon suggest that luminescence is attributable to electron-hole recombination in SiO{sub {ital x}} surface layers with an intensity that is dependent upon the surface hydrogen content. The luminescence is composed of three Gaussian bands similar to those found in amorphous SiO{sub 2}. X-ray photoelectron spectroscopy and scanning electron microscopy show porous silicon has SiO{sub {ital x}} on the surface, which is comprised of many particles of about 10 nm size. Collectively, the data strongly support the previously proposed quantum confinement/luminescence center model. {copyright} {ital 1996 American Institute of Physics.}

  8. Polarization-induced confinement of continuous hole-states in highly pumped, industrial-grade, green InGaN quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Nippert, Felix, E-mail: felix@physik.tu-berlin.de; Callsen, Gordon; Westerkamp, Steffen; Kure, Thomas; Nenstiel, Christian; Hoffmann, Axel [Institut für Festkörperphysik, Technische Universität Berlin, Hardenbergstraße 36, 10623 Berlin (Germany); Nirschl, Anna; Pietzonka, Ines; Strassburg, Martin [OSRAM Opto Semiconductors GmbH, Leibnizstraße 4, 93055 Regensburg (Germany); Schulz, Tobias; Albrecht, Martin [Leibniz-Institut für Kristallzüchtung, Max-Born-Straße 2, 12489 Berlin (Germany)

    2016-06-07

    We investigate industrial-grade InGaN/GaN quantum wells (QWs) emitting in the green spectral region under high, resonant pumping conditions. Consequently, an ubiquitous high energy luminescence is observed that we assign to a polarization field Confined Hole Continuum (CHC). Our finding is supported by a unique combination of experimental techniques, including transmission electron microscopy, (time-resolved) photoluminescence under various excitation conditions, and electroluminescence, which confirm an extended out-of-plane localization of the CHC-states. The larger width of this localization volume surpasses the QW thickness, yielding enhanced non-radiative losses due to point defects and interfaces, whereas the energetic proximity to the bulk valence band states promotes carrier leakage.

  9. Dynamic gluon confinement in high energy processes within effective QCD field theory

    CERN Document Server

    Kinder-Geiger, Klaus

    1994-01-01

    An effective Lagrangian approach to describe the dynamics of confinement and symmetry breaking in the process of quark-gluon to hadron conversion is proposed. The deconfined quark and gluon degrees of freedom of the perturbative QCD vacuum are coupled to color neutral condensate fields representing the non-perturbative vacuum with broken scale and chiral symmetry. As a first application the evolution of gluons emitted by a fragmenting high energy q\\bar q pair from the perturbative to the non-perturbative regime with confinement is studied. For reasonable parameter choice the solution of the equations of motion leads to flux tube configurations with a string tension t \\simeq 1 GeV/fm.

  10. Weak Anchoring and Surface Elasticity Effects in Electroosmotic Flow of Nematic Liquid Crystals Through Narrow Confinements

    CERN Document Server

    Poddar, Antarip; Chakraborty, Suman

    2016-01-01

    Advent of nematic liquid crystals flows have attracted renewed attention in view of microfluidic transport phenomena. Among various transport processes, electroosmosis stands as one of the efficient flow actuation method through narrow confinement. In the present study, we explore the electrically actuated flow of a nematic fluid with ionic inclusions taking into account the influences from surface induced elastic and electrical double layer phenomena. Influence of surface effects on the flow characteristics is known to get augmented in micro-confined environment and must be properly addressed. Towards this, we devise the coupled flow governing equations from fundamental free energy analysis considering the contributions from first and second-order elastic, dielectric, flexoelectric, ionic and entropic energies. We have further considered weak anchoring surface conditions with second order elasticity which helps us to more accurately capture the director deformations along the boundaries. The present study fo...

  11. Effect of external fields on the energies of hydrogenic donor with the anharmonic confinement potential

    Energy Technology Data Exchange (ETDEWEB)

    Aciksoz, E.; Bayrak, O. [Department of Physics, Akdeniz University, 07058 Antalya (Turkey); Soylu, A., E-mail: asimsoylu@gmail.com [Department of Physics, Nigde University, 51240 Nigde (Turkey)

    2015-01-01

    The impurity binding energy in the GaAs−Ga{sub 1−x}Al{sub x}As system is studied with an anharmonic type confinement potential by taking into account the influence of the external electric and magnetic fields within the framework of the effective mass approximation and asymptotic iteration method (AIM). The influence of the external electromagnetic fields and anharmonicity on a donor binding energy is examined systematically. It is shown that the donor binding energy is highly dependent on the external electric and magnetic fields and the confinement potential shapes. Both the electric and magnetic fields are increased, the binding energies increase for each of them. However, the behaviors of increase in the weak and strong fields’ regimes have different character a bit. Furthermore, when the more anharmonicity is considered, the binding energy of donor slightly increases as well.

  12. A Quantitative Study of the Effect of Cladding Thickness on Modal Confinement Loss in Photonic Waveguides

    CERN Document Server

    Jiang, Shidong

    2016-01-01

    There has been increasing interest in making the photonic devices more and more compact in the integrated photonics industry, and one of the important questions for manufacturers and design engineers is how to quantify the effect of the finite cladding thickness on the modal confinement loss of photonic waveguides. This requires at least six to seven digits accuracy for the computation of propagation constant $\\beta$ since the modal confinement loss is proportional to the imaginary part of $\\beta$ that is six to seven orders of magnitude smaller than its real part by the industrial standard. In this paper, we present an accurate and efficient method to compute the propagation constant of electromagnetic modes of photonic waveguides with arbitrary number of (nonsmooth) inclusions in a layered media. The method combines a well-conditioned boundary integral equation formulation for photonic waveguides which requires the discretization of the material interface only, and efficient Sommerfeld integral representati...

  13. Modeling the interaction of microbubbles: Effects of proximity, confinement, and excitation amplitude

    Science.gov (United States)

    Wiedemair, W.; Tukovic, Z.; Jasak, H.; Poulikakos, D.; Kurtcuoglu, V.

    2014-06-01

    The interaction of closely spaced microbubbles (MBs) exposed to a transient external pressure field is relevant for a variety of industrial and medical applications. We present a computational framework employing an interface tracking approach to model the transient dynamics of multiple, interacting, insonated MBs in arbitrary settings. In particular, this technique allows studying the effects of mutual proximity, confinement, and variations in excitation amplitude on the translatory motion of pairs of differently sized MBs. Domains of mutual repulsion or attraction are observed for closely spaced MBs in the investigated range of excitation frequencies. The repulsion domain widens and shifts to lower frequencies with increasing excitation pressure amplitude. When the MBs are confined in rigid tubes of decreasing diameters, we observe a shift of the translatory patterns towards lower frequencies, accompanied by a change in relative strength of the two translation modes. This effect is correlated to a decrease of the resonance frequency due to confinement which causes changes in oscillation amplitude and phase shift between the bubble vibrations. Coupling to the viscous host liquid gives rise to phenomena such as collective MB drift, non-symmetric attraction or repulsion, and reversal of translation direction. A system comprising six MBs inside a narrow tube highlights the potential of the computational framework to treat complex setups with multiple bubbles.

  14. On the harmonic-type and linear-type confinement of a relativistic scalar particle yielded by Lorentz symmetry breaking effects

    Energy Technology Data Exchange (ETDEWEB)

    Bakke, K., E-mail: kbakke@fisica.ufpb.br [Departamento de Física, Universidade Federal da Paraíba, Caixa Postal 5008, 58051-900, João Pessoa-PB (Brazil); Belich, H., E-mail: belichjr@gmail.com [Departamento de Física e Química, Universidade Federal do Espírito Santo, Av. Fernando Ferrari, 514, Goiabeiras, 29060-900, Vitória, ES (Brazil)

    2016-10-15

    Based on the Standard Model Extension, we investigate relativistic quantum effects on a scalar particle in backgrounds of the Lorentz symmetry violation defined by a tensor field. We show that harmonic-type and linear-type confining potentials can stem from Lorentz symmetry breaking effects, and thus, relativistic bound state solutions can be achieved. We first analyse a possible scenario of the violation of the Lorentz symmetry that gives rise to a harmonic-type potential. In the following, we analyse another possible scenario of the breaking of the Lorentz symmetry that induces both harmonic-type and linear-type confining potentials. In this second case, we also show that not all values of the parameter associated with the intensity of the electric field are permitted in the search for polynomial solutions to the radial equation, where the possible values of this parameter are determined by the quantum numbers of the system and the parameters associated with the violation of the Lorentz symmetry.

  15. Effects of quantum gravity on the inflationary parameters and thermodynamics of the early universe

    CERN Document Server

    Tawfik, A; Ali, A Farag

    2014-01-01

    The effects of generalized uncertainty principle (GUP) on the inflationary dynamics and the thermodynamics of the early universe are studied. Using the GUP approach, the tensorial and scalar density fluctuations in the inflation era are evaluated and compared with the standard case. We find a good agreement with the Wilkinson Microwave Anisotropy Probe data. Assuming that a quantum gas of scalar particles is confined within a thin layer near the apparent horizon of the Friedmann-Lemaitre-Robertson-Walker universe which satisfies the boundary condition, the number and entropy densities and the free energy arising form the quantum states are calculated using the GUP approach. A qualitative estimation for effects of the quantum gravity on all these thermodynamic quantities is introduced.

  16. Effects of quantum gravity on the inflationary parameters and thermodynamics of the early universe

    Science.gov (United States)

    Tawfik, A.; Magdy, H.; Farag Ali, Ahmed

    2013-06-01

    The effects of generalized uncertainty principle (GUP) on the inflationary dynamics and the thermodynamics of the early universe are studied. Using the GUP approach, the tensorial and scalar density fluctuations in the inflation era are evaluated and compared with the standard case. We find a good agreement with the Wilkinson Microwave Anisotropy Probe data. Assuming that a quantum gas of scalar particles is confined within a thin layer near the apparent horizon of the Friedmann-Lemaitre-Robertson-Walker universe which satisfies the boundary condition, the number and entropy densities and the free energy arising form the quantum states are calculated using the GUP approach. A qualitative estimation for effects of the quantum gravity on all these thermodynamic quantities is introduced.

  17. Observation of Distinct Two-Photon Transition Channels in CdTe Quantum Dots in a Regime of Very Strong Confinement

    Directory of Open Access Journals (Sweden)

    Marcelo Gonçalves Vivas

    2017-03-01

    Full Text Available We report here on the direct observation of distinct two-photon transition channels in glutathione-capped (GSH CdTe quantum dots (QDs in a very strong confinement regime. CdTe-GSH QDs with different average diameters (2.5, 3.0, and 3.3 nm were synthesized through the one-pot method and their two-photon absorption (2PA spectrum determined by a femtosecond wavelength-tunable Z-scan. Our results show that the two lower-energy one-photon-allowed excitonic transitions, 1S3/2(h → 1S(e and 2S3/2(h → 1S(e, are also accessed via 2PA. These results were ascribed to the relaxation of the parity selection rules due to the noncentrosymmetric structure of the CdTe QDs (zinc-blended structure, whose magnitude are determined by surface defects and structural irregularities present in CdTe-GSH QDs, in the strong confinement regime.

  18. Quantum Hall Effect in Higher Dimensions

    CERN Document Server

    Karabali, Dimitra; Karabali, Dimitra

    2002-01-01

    Following recent work on the quantum Hall effect on $S^4$, we solve the Landau problem on the complex projective spaces ${\\bf C}P^k$ and discuss quantum Hall states for such spaces. Unlike the case of $S^4$, a finite spatial density can be obtained with a finite number of internal states for each particle. We treat the case of ${\\bf C}P^2$ in some detail considering both Abelian and nonabelian background fields. The wavefunctions are obtained and incompressibility of the Hall states is shown. The case of ${\\bf C}P^3$ is related to the case of $S^4$.

  19. Confinement effects upon the separation of structural transitions in linear systems with restricted bond fluctuation ranges.

    Science.gov (United States)

    Koci, Tomas; Bachmann, Michael

    2015-10-01

    By means of advanced parallel replica-exchange Monte Carlo methods we examine the influence of elasticity and confinement on the structural transitions of linear systems with restricted bonded interaction. For this purpose, we adopt a model for coarse-grained flexible polymers of finite length in the dilute regime. Hyperphase diagrams are constructed using energy-dependent canonical quantities to demonstrate the effects of the changes in the range of the confined interaction on the liquid and solid structural phases. With increasing bonded interaction range we observe the disappearance of the liquid phase and the fusion of the gas-liquid (or Θ) and the liquid-solid transitions. One of the most remarkable features, the liquid-gas transition, changes from second to first order if the confined interaction range exceeds a threshold that separates polymeric from nonpolymeric systems. The notoriously difficult sampling of the entropically suppressed conformations in the region of very strong first-order transitions is improved by using multiple Gaussian modified ensembles.

  20. Electrical charging effects on the sliding friction of a model nano-confined ionic liquid

    Energy Technology Data Exchange (ETDEWEB)

    Capozza, R.; Vanossi, A. [International School for Advanced Studies (SISSA), Via Bonomea 265, 34136 Trieste (Italy); CNR-IOM Democritos National Simulation Center, Via Bonomea 265, 34136 Trieste (Italy); Benassi, A. [CNR-IOM Democritos National Simulation Center, Via Bonomea 265, 34136 Trieste (Italy); Institute for Materials Science and Max Bergmann Center of Biomaterials, TU Dresden, 01062 Dresden (Germany); Tosatti, E. [International School for Advanced Studies (SISSA), Via Bonomea 265, 34136 Trieste (Italy); CNR-IOM Democritos National Simulation Center, Via Bonomea 265, 34136 Trieste (Italy); International Centre for Theoretical Physics (ICTP), Strada Costiera 11, 34014 Trieste (Italy)

    2015-10-14

    Recent measurements suggest the possibility to exploit ionic liquids (ILs) as smart lubricants for nano-contacts, tuning their tribological and rheological properties by charging the sliding interfaces. Following our earlier theoretical study of charging effects on nanoscale confinement and squeezout of a model IL, we present here molecular dynamics simulations of the frictional and lubrication properties of that model under charging conditions. First, we describe the case when two equally charged plates slide while being held together to a confinement distance of a few molecular layers. The shear sliding stress is found to rise strongly and discontinuously as the number of IL layers decreases stepwise. However, the shear stress shows, within each given number of layers, only a weak dependence upon the precise value of the normal load, a result in agreement with data extracted from recent experiments. We subsequently describe the case of opposite charging of the sliding plates and follow the shear stress when the charging is slowly and adiabatically reversed in the course of time, under fixed load. Despite the fixed load, the number and structure of the confined IL layers change with changing charge, and that in turn drives strong friction variations. The latter involves first of all charging-induced freezing of the IL film, followed by a discharging-induced melting, both made possible by the nanoscale confinement. Another mechanism for charging-induced frictional changes is a shift of the plane of maximum shear from mid-film to the plate-film interface, and vice versa. While these occurrences and results invariably depend upon the parameters of the model IL and upon its specific interaction with the plates, the present study helps identifying a variety of possible behavior, obtained under very simple assumptions, while connecting it to an underlying equilibrium thermodynamics picture.

  1. Electrical charging effects on the sliding friction of a model nano-confined ionic liquid

    Science.gov (United States)

    Capozza, R.; Benassi, A.; Vanossi, A.; Tosatti, E.

    2015-10-01

    Recent measurements suggest the possibility to exploit ionic liquids (ILs) as smart lubricants for nano-contacts, tuning their tribological and rheological properties by charging the sliding interfaces. Following our earlier theoretical study of charging effects on nanoscale confinement and squeezout of a model IL, we present here molecular dynamics simulations of the frictional and lubrication properties of that model under charging conditions. First, we describe the case when two equally charged plates slide while being held together to a confinement distance of a few molecular layers. The shear sliding stress is found to rise strongly and discontinuously as the number of IL layers decreases stepwise. However, the shear stress shows, within each given number of layers, only a weak dependence upon the precise value of the normal load, a result in agreement with data extracted from recent experiments. We subsequently describe the case of opposite charging of the sliding plates and follow the shear stress when the charging is slowly and adiabatically reversed in the course of time, under fixed load. Despite the fixed load, the number and structure of the confined IL layers change with changing charge, and that in turn drives strong friction variations. The latter involves first of all charging-induced freezing of the IL film, followed by a discharging-induced melting, both made possible by the nanoscale confinement. Another mechanism for charging-induced frictional changes is a shift of the plane of maximum shear from mid-film to the plate-film interface, and vice versa. While these occurrences and results invariably depend upon the parameters of the model IL and upon its specific interaction with the plates, the present study helps identifying a variety of possible behavior, obtained under very simple assumptions, while connecting it to an underlying equilibrium thermodynamics picture.

  2. Holographic Butterfly Effect at Quantum Critical Points

    CERN Document Server

    Ling, Yi; Wu, Jian-Pin

    2016-01-01

    When the Lyapunov exponent $\\lambda_L$ in a quantum chaotic system saturates the bound $\\lambda_L\\leqslant 2\\pi k_BT$, it is proposed that this system has a holographic dual described by a gravity theory. In particular, the butterfly effect as a prominent phenomenon of chaos can ubiquitously exist in a black hole system characterized by a shockwave solution near the horizon. In this letter we propose that the butterfly velocity $v_B$ can be used to diagnose quantum phase transition (QPT) in holographic theories. We provide evidences for this proposal with two holographic models exhibiting metal-insulator transitions (MIT), in which the second derivative of $v_B$ with respect to system parameters characterizes quantum critical points (QCP) with local extremes. We also point out that this proposal can be tested by experiments in the light of recent progress on the measurement of out-of-time-order correlation function (OTOC).

  3. Finding quantum effects in strong classical potentials

    Science.gov (United States)

    Hegelich, B. Manuel; Labun, Lance; Labun, Ou Z.

    2017-06-01

    The long-standing challenge to describing charged particle dynamics in strong classical electromagnetic fields is how to incorporate classical radiation, classical radiation reaction and quantized photon emission into a consistent unified framework. The current, semiclassical methods to describe the dynamics of quantum particles in strong classical fields also provide the theoretical framework for fundamental questions in gravity and hadron-hadron collisions, including Hawking radiation, cosmological particle production and thermalization of particles created in heavy-ion collisions. However, as we show, these methods break down for highly relativistic particles propagating in strong fields. They must therefore be improved and adapted for the description of laser-plasma experiments that typically involve the acceleration of electrons. Theory developed from quantum electrodynamics, together with dedicated experimental efforts, offer the best controllable context to establish a robust, experimentally validated foundation for the fundamental theory of quantum effects in strong classical potentials.

  4. Nonlinear peltier effect in quantum point contacts

    Science.gov (United States)

    Bogachek, E. N.; Scherbakov, A. G.; Landman, Uzi

    1998-11-01

    A theoretical analysis of the Peltier effect in two-dimensional quantum point contacts, in field-free conditions and under the influence of applied magnetic fields, is presented. It is shown that in the nonlinear regime (finite applied voltage) new peaks in the Peltier coefficient appear leading to violation of Onsager's relation. Oscillations of the Peltier coefficient in a magnetic field are demonstrated.

  5. Relativistic bounds states for a neutral particle confined to a parabolic potential induced by noninertial effects

    Science.gov (United States)

    Bakke, K.

    2010-10-01

    We obtain the solutions of the Dirac equation when the noninertial effects of the Fermi-Walker reference frame break the relativistic Landau-Aharonov-Casher quantization, but they provide bound states in an analogous way to a Dirac neutral particle subject to Tan-Inkson quantum dot potential [W.-C. Tan, J.C. Inkson, Semicond. Sci. Technol. 11 (1996) 1635].

  6. NON-LINEAR ANALYSIS OF EFFECT OF CONFINEMENT REGIONS ON MOMENT CURVATURE BEHAVIOR OF SHEAR WALL (THEORETICAL STUDY

    Directory of Open Access Journals (Sweden)

    Şevket Murat ŞENEL

    2002-02-01

    Full Text Available Computer program which investigates the effectiveness of confinement regions of shear walls was developed.Specimens which have unique web reinforcement and different confinement regions were analyzed by using this computer program. Data needed for theoratical computations were obtained by tensile testing of steel rods and by concrete specimen tests. Mander Method was applied to reflect confined concrete behavior. Strain hardening behavior of steel was included in computations. Effect of stirrup spacing and hook reinforcement was introduced together and seperately to understand the moment-curvature response of specimens.

  7. ac electrokinetic micropumps: The effect of geometrical confinement, Faradaic current injection, and nonlinear surface capacitance

    DEFF Research Database (Denmark)

    Olesen, Laurits Højgaard; Bruus, Henrik; Ajdari, A.

    2006-01-01

    Recent experiments have demonstrated that ac electrokinetic micropumps permit integrable, local, and fast pumping (velocities similar to mm/s) with low driving voltage of a few volts only. However, they also displayed many quantitative and qualitative discrepancies with existing theories. We...... therefore extend the latter theories to account for three experimentally relevant effects: (i) vertical confinement of the pumping channel, (ii) Faradaic currents from electrochemical reactions at the electrodes, and (iii) nonlinear surface capacitance of the Debye layer. We report here that these effects...... indeed affect the pump performance in a way that we can rationalize by physical arguments....

  8. Effects of confinement (110 and 240 days) on neuroendocrine stress response and changes of immune cells in men.

    Science.gov (United States)

    Choukèr, A; Smith, L; Christ, F; Larina, I; Nichiporuk, I; Baranov, V; Bobrovnik, E; Pastushkova, L; Messmer, K; Peter, K; Thiel, M

    2002-04-01

    The aim of the study was to evaluate the effects of long-term confinement on stress-permissive neuroendocrine and immune responses in humans. Two groups of four male subjects were confined 240 days (group 240) or 110 days (group 110) in two space modules of 100 or 200 m3, respectively. During confinement, none of the volunteers developed psychic stress as could be examined and verified by a current stress test. However, in group 240 but not in group 110, the diurnal rhythm of cortisol secretion was slightly depressed and the urine excretion of norepinephrine significantly increased. The innate part of the immune system became activated as seen by a rise in the number of circulating granulocytes and the enhanced expression of beta2-integrins. In contrast, the ratio of T-helper to T-suppressor cells decreased. All these effects, observed during confinement, were even more pronounced in both groups when values of endocrinological and immunological parameters were compared between before and 1 wk after the end of the confinement period. Hence, return to normal life exerts pronounced effects to a much higher degree, irrespective of how long or under which conditions individuals were confined. Because the delayed-type hypersensitivity skin reaction against recall antigens remained unaffected, it is to be presumed that confinement appears to induce distinct sympathoadrenergic activation and immunological changes but no clinically relevant immunosuppression.

  9. Quantum Mechanical Effects in Gravitational Collapse

    CERN Document Server

    Greenwood, Eric

    2010-01-01

    In this thesis we investigate quantum mechanical effects to various aspects of gravitational collapse. These quantum mechanical effects are implemented in the context of the Functional Schr\\"odinger formalism. The Functional Schr\\"odinger formalism allows us to investigate the time-dependent evolutions of the quantum mechanical effects, which is beyond the scope of the usual methods used to investigate the quantum mechanical corrections of gravitational collapse. Utilizing the time-dependent nature of the Functional Schr\\"odinger formalism, we study the quantization of a spherically symmetric domain wall from the view point of an asymptotic and infalling observer, in the absence of radiation. To build a more realistic picture, we then study the time-dependent nature of the induced radiation during the collapse using a semi-classical approach. Using the domain wall and the induced radiation, we then study the time-dependent evolution of the entropy of the domain wall. Finally we make some remarks about the pos...

  10. Stochasticity effects in quantum radiation reaction

    CERN Document Server

    Neitz, N

    2013-01-01

    When an ultrarelativistic electron beam collides with a sufficiently intense laser pulse, radiation-reaction effects can strongly alter the beam dynamics. In the realm of classical electrodynamics, radiation reaction has a beneficial effect on the electron beam as it tends to reduce its energy spread. Here, we show that when quantum effects become important, radiation reaction induces the opposite effect, i.e., the electron beam spreads out after interacting with the laser pulse. We identify the physical origin of this opposite tendency in the intrinsic stochasticity of photon emission, which becomes substantial in the full quantum regime. Our numerical simulations indicated that the predicted effects of the stochasticity can be measured already with presently available lasers and electron accelerators.

  11. Stochasticity effects in quantum radiation reaction.

    Science.gov (United States)

    Neitz, N; Di Piazza, A

    2013-08-02

    When an ultrarelativistic electron beam collides with a sufficiently intense laser pulse, radiation-reaction effects can strongly alter the beam dynamics. In the realm of classical electrodynamics, radiation reaction has a beneficial effect on the electron beam as it tends to reduce its energy spread. Here we show that when quantum effects become important, radiation reaction induces the opposite effect; i.e., the energy distribution of the electron beam spreads out after interacting with the laser pulse. We identify the physical origin of this opposite tendency in the intrinsic stochasticity of photon emission, which becomes substantial in the quantum regime. Our numerical simulations indicate that the predicted effects of the stochasticity can be measured already with presently available lasers and electron accelerators.

  12. Regions of Different Confinement in Low-Dimensional AlyInxGa1−x−yN Quantum Structures

    Directory of Open Access Journals (Sweden)

    A. Gröning

    2007-01-01

    Full Text Available The optical properties of metal-organic vapor phase epitaxy grown AlyInxGa1−x−yN quantum dot structures have been studied by time-resolved photoluminescence experiments. We investigated the recombination dynamics of the photo-exited carriers in dependence of the growth parameters such as aluminium flow and the duration of the growth interruption after the dot deposition. Our results confirm the presence of localized states, where the degree of localization is strongly dependent on the growth conditions. To describe this behavior, we propose a band structure with coupled potentials for these nanostructures. Finally, we demonstrate state filling to prove the zero-dimensional character of the strongly localized states in our quaternary quantum dots.

  13. Effective operator formalism for open quantum systems

    DEFF Research Database (Denmark)

    Reiter, Florentin; Sørensen, Anders Søndberg

    2012-01-01

    We present an effective operator formalism for open quantum systems. Employing perturbation theory and adiabatic elimination of excited states for a weakly driven system, we derive an effective master equation which reduces the evolution to the ground-state dynamics. The effective evolution...... involves a single effective Hamiltonian and one effective Lindblad operator for each naturally occurring decay process. Simple expressions are derived for the effective operators which can be directly applied to reach effective equations of motion for the ground states. We compare our method...

  14. The scaling of the effective band gaps in indium-arsenide quantum dots and wires.

    Science.gov (United States)

    Wang, Fudong; Yu, Heng; Jeong, Sohee; Pietryga, Jeffrey M; Hollingsworth, Jennifer A; Gibbons, Patrick C; Buhro, William E

    2008-09-23

    Colloidal InAs quantum wires having diameters in the range of 5-57 nm and narrow diameter distributions are grown from Bi nanoparticles by the solution-liquid-solid (SLS) mechanism. The diameter dependence of the effective band gaps (DeltaE(g)s) in the wires is determined from photoluminescence spectra and compared to the experimental results for InAs quantum dots and rods and to the predictions of various theoretical models. The DeltaE(g) values for InAs quantum dots and wires are found to scale linearly with inverse diameter (d(-1)), whereas the simplest confinement models predict that DeltaE(g) should scale with inverse-square diameter (d(-2)). The difference in the observed and predicted scaling dimension is attributed to conduction-band nonparabolicity induced by strong valence-band-conduction-band coupling in the narrow-gap InAs semiconductor.

  15. Spin-orbit effects in carbon-nanotube double quantum dots

    DEFF Research Database (Denmark)

    Weiss, S; Rashba, E I; Kuemmeth, Ferdinand;

    2010-01-01

    We study the energy spectrum of symmetric double quantum dots in narrow-gap carbon nanotubes with one and two electrostatically confined electrons in the presence of spin-orbit and Coulomb interactions. Compared to GaAs quantum dots, the spectrum exhibits a much richer structure because of the spin...... between the dots. For the two-electron regime, the detailed structure of the spin-orbit split energy spectrum is investigated as a function of detuning between the quantum dots in a 22-dimensional Hilbert space within the framework of a single-longitudinal-mode model. We find a competing effect......-orbit interaction that couples the electron's isospin to its real spin through two independent coupling constants. In a single dot, both constants combine to split the spectrum into two Kramers doublets while the antisymmetric constant solely controls the difference in the tunneling rates of the Kramers doublets...

  16. Non-monotonicity in the quantum-classical transition: Chaos induced by quantum effects

    CERN Document Server

    Kapulkin, A; Kapulkin, Arie; Pattanayak, Arjendu K.

    2007-01-01

    The transition from classical to quantum behavior for chaotic systems is understood to be accompanied by the suppression of chaotic effects as the relative size of $\\hbar$ is increased. We show evidence to the contrary in the behavior of the quantum trajectory dynamics of a dissipative quantum chaotic system, the double-well Duffing oscillator. The classical limit in the case considered has regular behavior, but as the effective $\\hbar$ is increased we see chaotic behavior. This chaos then disappears deeper into the quantum regime, which means that the quantum-classical transition in this case is non-monotonic in $\\hbar$.

  17. Quantum Information Processing using Nonlinear Optical Effects

    DEFF Research Database (Denmark)

    Andersen, Lasse Mejling

    of the converted idler depends on the other pump. This allows for temporal-mode-multiplexing. When the effects of nonlinear phase modulation (NPM) are included, the phases of the natural input and output modes are changed, reducing the separability. These effects are to some degree mediated by pre......This PhD thesis treats applications of nonlinear optical effects for quantum information processing. The two main applications are four-wave mixing in the form of Bragg scattering (BS) for quantum-state-preserving frequency conversion, and sum-frequency generation (SFG) in second-order nonlinear...... to obtain a 100 % conversion efficiency is to use multiple stages of frequency conversion, but this setup suffers from the combined effects of NPM. This problem is circumvented by using asymmetrically pumped BS, where one pump is continuous wave. For this setup, NPM is found to only lead to linear phase...

  18. Synchronization effect for uncertain quantum networks

    Science.gov (United States)

    Li, Wenlin; Gebremariam, Tesfay; Li, Chong; Song, Heshan

    2017-01-01

    We propose a novel technique for investigating the synchronization effect for uncertain networks with quantum chaotic behaviors in this paper. Through designing a special function to construct Lyapunov function of network and the adaptive laws of uncertain parameters, the synchronization between the uncertain network and the synchronization target can be realized, and the uncertain parameters in state equations of the network nodes are perfectly identified. All the theoretical results are verified by numerical simulations to demonstrate the effectiveness of the proposed synchronization technique.

  19. Confinement effects in π-bonded chains at group IV semiconductor (111) surfaces.

    Science.gov (United States)

    Bonanni, B; Bussetti, G; Violante, A; Chiaradia, P; Goletti, C

    2013-12-04

    The degree of 1D character of surface chains at group IV (111)-2 × 1 reconstructed surfaces is established by surface sensitive optical spectroscopy. Optical experiments on a diamond C(111)-2 × 1 surface show that the absorption peak related to dangling-bond transitions exhibits a marked blueshift upon oxygen exposure of the clean surface. Such behaviour is analogous to that observed on a clean Si(111)-2 × 1 surface. For both surfaces the experimental finding is interpreted in terms of quantum confinement of surface electrons in quasi-one-dimensional π-bonded chains, whose length decreases with oxygen uptake. A different behaviour is observed in Ge(111)-2 × 1, where only a very slight blueshift of the surface-state optical transition is detected upon oxidation. The almost negligible blueshift in Ge(111)-2 × 1 is consistent with a significant coupling between the π-bonded chains resulting in a much less pronounced one-dimensional character of Ge(111)-2 × 1 surface electrons compared to diamond and silicon reconstructed surfaces.

  20. Self-adjointness and the Casimir effect with confined quantized spinor matter

    CERN Document Server

    Sitenko, Yurii A

    2015-01-01

    A generalization of the MIT bag boundary condition for spinor matter is proposed basing on the requirement that the Dirac hamiltonian operator be self-adjoint. An influence of a background magnetic field on the vacuum of charged spinor matter confined between two parallel material plates is studied. Employing the most general set of boundary conditions at the plates in the case of the uniform magnetic field directed orthogonally to the plates, we find the pressure from the vacuum onto the plates. In physically plausible situations, the Casimir effect is shown to be repulsive, independently of a choice of boundary conditions and of a distance between the plates.

  1. Diffusion in a soft confining environment: Dynamic effects of thermal fluctuations

    Science.gov (United States)

    Palmieri, Benoit; Safran, Samuel

    2013-03-01

    A dynamical model of a soft, thermally fluctuating two-dimensional tube is used to study the effect of thermal fluctuations of a confining environment on diffusive transport. The tube fluctuations in both space and time are driven by Brownian motion and suppressed by surface tension and the rigidity of the surrounding environment. The dynamical fluctuations modify the concentration profile boundary condition at the tube surface. They decrease the diffusive transport rate through the tube for two important cases: uniform tube fluctuations (wave vector, q = 0 mode) for finite tube lengths and fluctuations of any wave vector for infinitely long tubes.

  2. ARTICLES: Effect of Interaction upon Translocation of Confined Polymer Chain Through Nanopore

    Science.gov (United States)

    Wang, Yao; Xie, Yong-jun; Yang, Hai-yang; Zhang, Xing-yuan

    2010-06-01

    The effect of the interaction between nanopore and chain monomer on the translocation of a single polymer chain confined in a finite size square through an interacting nanopore to a large space has been studied by two-dimensional bond fluctuation model with Monte Carlo simulation. Results indicate that the free energy barrier before the successful translocation of the chain depends linearly on the chain length as well as the nanopore length for different pore-polymer interaction, and the attractive interaction reduces the free energy barrier, leading to the reduction of the average trapping time.

  3. Effects of Confinement on Microstructure and Charge Transport in High Performance Semicrystalline Polymer Semiconductors

    KAUST Repository

    Himmelberger, Scott

    2012-11-23

    The film thickness of one of the most crystalline and highest performing polymer semiconductors, poly(2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b] thiophene) (PBTTT), is varied in order to determine the effects of interfaces and confinement on the microstructure and performance in organic field effect transistors (OFETs). Crystalline texture and overall film crystallinity are found to depend strongly on film thickness and thermal processing. The angular distribution of crystallites narrows upon both a decrease in film thickness and thermal annealing. These changes in the film microstructure are paired with thin-film transistor characterization and shown to be directly correlated with variations in charge carrier mobility. Charge transport is shown to be governed by film crystallinity in films below 20 nm and by crystalline orientation for thicker films. An optimal thickness is found for PBTTT at which the mobility is maximized in unannealed films and where mobility reaches a plateau at its highest value for annealed films. The effects of confinement on the morphology and charge transport properties of poly(2,5-bis(3-tetradecylthiophen-2-yl) thieno[3,2-b]thiophene) (PBTTT) are studied using quantitative X-ray diffraction and field-effect transistor measurements. Polymer crystallinity is found to limit charge transport in the thinnest films while crystalline texture and intergrain connectivity modulate carrier mobility in thicker films. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Quantum and field effects of oxide heterostructures

    DEFF Research Database (Denmark)

    Trier, Felix

    , these interfaces are the ones between CaZrO3/SrTiO3 and amorphous-LaAlO3/(La, Sr)MnO3/SrTiO3. The sample preparation section is ended by outlininga patterning strategy for the high-electron mobility interface at amorphous-LaAlO3/(La, Sr)MnO3/SrTiO3. Subsequently, the effects of electrostatic gating is studied...... with a gradual tuning of the interface conductivity. Finally, the so-called quantum Hall effect is demonstrated at the interface between amorphous-LaAlO3/(La, Sr)MnO3/SrTiO3. The manifestation of the quantum Hall effect reveals that the interface conductivity is comprised of several subbands conducting...

  5. Spatially dependent Kondo effect in Quantum Corrals

    Science.gov (United States)

    Rossi, Enrico; Morr, Dirk K.

    2007-03-01

    We study the Kondo screening of a single magnetic impurity placed inside a quantum corral consisting of non-magnetic impurities on the surface of a metallic host system. We show that the spatial structure of the corral's eigenmodes leads to a spatially dependent Kondo effect whose signatures are experimentally measurable spatial variations of the Kondo temperature, TK, and of the critical Kondo coupling, Jcr. Moreover we find that the screening of the magnetic impurity is accompanied by the formation of multiple Kondo resonances with characteristic spatial patterns that provide further experimental signatures of the spatially dependent Kondo effect. Our results demonstrate that quantum corrals provide new possibilities to manipulate and explore the Kondo effect.

  6. Quantum confinement-tunable intersystem crossing and the triplet state lifetime of cationic porphyrin–CdTe quantum dot nano-assemblies

    KAUST Repository

    Ahmed, Ghada H.

    2015-03-27

    Here, we report a ground-state interaction between the positively charged cationic porphyrin and the negatively charged carboxylate groups of the thiol ligands on the surface of CdTe quantum dots (QDs), leading to the formation of a stable nanoassembly between the two components. Our time-resolved data clearly demonstrate that we can dramatically tune the intersystem crossing (ISC) and the triplet state lifetime of porphyrin by changing the size of the QDs in the nanoassembly.

  7. Quantum dissipative effects in graphene-like mirrors

    CERN Document Server

    Fosco, C D; Mazzitelli, F D; Remaggi, M L

    2013-01-01

    We study quantum dissipative effects due to the accelerated motion of a single, imperfect, zero-width mirror. It is assumed that the microscopic degrees of freedom on the mirror are confined to it, like in plasma or graphene sheets. Therefore, the mirror is described by a vacuum polarization tensor $\\Pi_{\\alpha\\beta}$ concentrated on a time-dependent surface. Under certain assumptions about the microscopic model for the mirror, we obtain a rather general expression for the Euclidean effective action, a functional of the time-dependent mirror's position, in terms of two invariants that characterize the tensor $\\Pi_{\\alpha\\beta}$. The final result can be written in terms of the TE and TM reflection coefficients of the mirror, with qualitatively different contributions coming from them. We apply that general expression to derive the imaginary part of the `in-out' effective action, which measures dissipative effects induced by the mirror's motion, in different models, in particular for an accelerated graphene she...

  8. Quantum Zeno effects with "pulsed" and "continuous" measurements

    OpenAIRE

    Facchi, P.; Pascazio, S.

    2001-01-01

    The dynamics of a quantum system undergoing measurements is investigated. Depending on the features of the interaction Hamiltonian, the decay can be slowed (quantum Zeno effect) or accelerated (inverse quantum Zeno effect), by changing the time interval between successive (pulsed) measurements or, alternatively, by varying the "strength" of the (continuous) measurement.

  9. Effective Hamiltonian approach to periodically perturbed quantum optical systems

    Energy Technology Data Exchange (ETDEWEB)

    Sainz, I. [Centro Universitario de los Lagos, Universidad de Guadalajara, Enrique Diaz de Leon, 47460 Lagos de Moreno, Jal. (Mexico)]. E-mail: isa@culagos.udg.mx; Klimov, A.B. [Departamento de Fisica, Universidad de Guadalajara, Revolucion 1500, 44410 Guadalajara, Jal. (Mexico)]. E-mail: klimov@cencar.udg.mx; Saavedra, C. [Center for Quantum Optics and Quantum Information, Departamento de Fisica, Universidad de Concepcion, Casilla 160-C, Concepcion (Chile)]. E-mail: csaaved@udec.cl

    2006-02-20

    We apply the method of Lie-type transformations to Floquet Hamiltonians for periodically perturbed quantum systems. Some typical examples of driven quantum systems are considered in the framework of this approach and corresponding effective time dependent Hamiltonians are found.

  10. Effects of Quantum Noise on Quantum Clock Synchronization

    Institute of Scientific and Technical Information of China (English)

    谢端; 彭进业

    2012-01-01

    In laboratory environment, the channel apparatus will generate particular dominant quantum noise. The noise then will give rise to some errors during synchronization. In this work, the accuracies of one qubit transport protocol and entangled states transport protocol in the presence of noise have been studied. With the help of three important and familiar noise models, the quantum noise will degrade the accuracy has been proved. Due to the influence of quantum noise, the accuracy of entangled qubits decrease faster than that of one qubit. The entangled states will improve the accuracy in noise-free channel, and will degrade the accuracy in noise channel.

  11. Negative activation energy and dielectric signatures of excitons and excitonic Mott transitions in quantum confined laser structures

    Science.gov (United States)

    Bhunia, Amit; Bansal, Kanika; Henini, Mohamed; Alshammari, Marzook S.; Datta, Shouvik

    2016-10-01

    Mostly, optical spectroscopies are used to investigate the physics of excitons, whereas their electrical evidences are hardly explored. Here, we examined a forward bias activated differential capacitance response of GaInP/AlGaInP based multi-quantum well laser diodes to trace the presence of excitons using electrical measurements. Occurrence of "negative activation energy" after light emission is understood as thermodynamical signature of steady state excitonic population under intermediate range of carrier injections. Similar corroborative results are also observed in an InGaAs/GaAs quantum dot laser structure grown by molecular beam epitaxy. With increasing biases, the measured differential capacitance response slowly vanishes. This represents gradual Mott transition of an excitonic phase into an electron-hole plasma in a GaInP/AlGaInP laser diode. This is further substantiated by more and more exponentially looking shapes of high energy tails in electroluminescence spectra with increasing forward bias, which originates from a growing non-degenerate population of free electrons and holes. Such an experimental correlation between electrical and optical properties of excitons can be used to advance the next generation excitonic devices.

  12. Confinement effects on the crystalline features of poly(9,9-dioctylfluorene)

    KAUST Repository

    Martin, Jaime

    2016-01-01

    Typical device architectures in polymer-based optoelectronic devices, such as field effect transistors organic light emitting diodes and photovoltaic cells include sub-100 nm semiconducting polymer thin-film active layers, whose microstructure is likely to be subject to finite-size effects. The aim of this study was to investigate effect of the two-dimensional spatial confinement on the internal structure of the semiconducting polymer poly(9,9-dioctylfluorene) (PFO). PFO melts were confined inside the cylindrical nanopores of anodic aluminium oxide (AAO) templates and crystallized via two crystallization strategies, namely, in the presence or in the absence of a surface bulk reservoir located at the template surface. We show that highly textured semiconducting nanowires with tuneable crystal orientation can be thus produced. The results presented here demonstrate the simple fabrication and crystal engineering of ordered arrays of PFO nanowires; a system with potential applications in devices where anisotropic optical properties are required, such as polarized electroluminescence, waveguiding, optical switching and lasing.

  13. Quantum Effects in Higher-Order Correlators of a Quantum-Dot Spin Qubit

    Science.gov (United States)

    Bechtold, A.; Li, F.; Müller, K.; Simmet, T.; Ardelt, P.-L.; Finley, J. J.; Sinitsyn, N. A.

    2016-07-01

    We measure time correlators of a spin qubit in an optically active quantum dot beyond the second order. Such higher-order correlators are shown to be directly sensitive to pure quantum effects that cannot be explained within the classical framework. They allow direct determination of ensemble and quantum dephasing times, T2* and T2, using only repeated projective measurements and without the need for coherent spin control. Our method enables studies of purely quantum behavior in solid state systems, including tests of the Leggett-Garg type of inequalities that rule out local hidden variable interpretation of the quantum-dot spin dynamics.

  14. Spin–orbit interaction effect on nonlinear optical rectification of quantum wire in the presence of electric and magnetic fields

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Manoj [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Lahon, Siddhartha, E-mail: sid.lahon@gmail.com [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Department of Physics, Kirori Mal College, University of Delhi, Delhi 110007 (India); Jha, Pradip Kumar [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Department of Physics, DDU College, University of Delhi, Delhi 110007 (India); Gumber, Sukirti; Mohan, Man [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India)

    2014-04-01

    Here we have investigated the influence of external electric field and magnetic field on the nonlinear optical rectification of a parabolic confinement wire in the presence of Rashba spin–orbit interaction. We have used density matrix formulation for obtaining optical properties within the effective mass approximation. The results are presented as a function of quantum wire radius, electric field, magnetic field, Rashba spin–orbit interaction strength and photon energy. Our results indicate an increase of electric field gives the red-shift of the peak positions of nonlinear optical rectification. The role of confinement strength and spin–orbit interaction strength as control parameters on this nonlinear property have been demonstrated.

  15. Theoretical study on effect of confinement on flexural ductility of normal and high-strength concrete beams

    OpenAIRE

    Kwan, AKH; Au, FTK; Chau, SL

    2004-01-01

    Compared with normal concrete, high-strength concrete has higher strength but is generally more brittle. Its use in a reinforced concrete structure, if not properly controlled, could lead to an unsustainable reduction in ductility. However, confinement could be provided to improve the ductility of the structure. In this study, the effects of concrete strength and confinement on the flexural ductility of reinforced concrete beams have been evaluated by means of complete moment-curvature analys...

  16. Hypocycloid-shaped hollow-core photonic crystal fiber Part II: cladding effect on confinement and bend loss.

    Science.gov (United States)

    Alharbi, M; Bradley, T; Debord, B; Fourcade-Dutin, C; Ghosh, D; Vincetti, L; Gérôme, F; Benabid, F

    2013-11-18

    We report on numerical and experimental studies on the influence of cladding ring-number on the confinement and bend loss in hypocycloid-shaped Kagome hollow core photonic crystal fiber. The results show that beyond the second ring, the ring number has a minor effect on confinement loss whereas the bend loss is strongly reduced with the ring-number increase. Finally, the results show that the increase in the cladding ring-number improves the modal content of the fiber.

  17. Many electron effects in semiconductor quantum dots

    Indian Academy of Sciences (India)

    R K Pandey; Manoj K Harbola; V Ranjan; Vijay A Singh

    2003-01-01

    Semiconductor quantum dots (QDs) exhibit shell structures, very similar to atoms. Termed as ‘artificial atoms’ by some, they are much larger (1 100 nm) than real atoms. One can study a variety of manyelectron effects in them, which are otherwise difficult to observe in a real atom. We have treated these effects within the local density approximation (LDA) and the Harbola–Sahni (HS) scheme. HS is free of the selfinteraction error of the LDA. Our calculations have been performed in a three-dimensional quantum dot. We have carried out a study of the size and shape dependence of the level spacing. Scaling laws for the Hubbard ‘’ are established.

  18. Effects of gravity on structure and entropy generation of confined laminar diffusion flames

    Energy Technology Data Exchange (ETDEWEB)

    Datta, A. [Department of Power Engineering, Jadvapur University, Salt Lake Campus, Kolkata 700098 (India)

    2005-05-01

    A numerical prediction of a confined, co-flowing, laminar jet diffusion flame has been made to find the flow and scalar variables under steady state condition. These variables are used for the description of the flame structure and the evaluation of entropy generation rate and the rate of exergy loss. The exergy loss is compared against the exergy coming in, to evaluate the second law efficiency of the combustion process. The model is applied for diffusion flames in a confined geometry at various gravity levels to find the effect of gravity on the rate of entropy generation and second law efficiency. In general, the flame becomes wider in shape at reduced gravity. A correlation of the flame width against Froude number over a wide gravity range has been proposed. It is observed from the local volumetric entropy generation rate that a diffusion flame is more intense at its base than at the tip. The intensity of the flame becomes less at reduced gravity because of the lower rate of entrainment of oxygen. The entropy generation rate due to heat transfer increases considerably at normal gravity compared to that at zero gravity, because of the thermal stratification of the flow under the influence of buoyant acceleration. The rate of entropy generation due to chemical reaction and mass transfer remain almost unaltered at all gravity levels. The lowering of the total entropy generation rate and the corresponding exergy destruction increases the second law efficiency of a confined diffusion flame at reduced gravity compared to that at normal gravity. (authors)

  19. Highly efficient visual detection of trace copper(II) and protein by the quantum photoelectric effect.

    Science.gov (United States)

    Wang, Peng; Lei, Jianping; Su, Mengqi; Liu, Yueting; Hao, Qing; Ju, Huangxian

    2013-09-17

    This work presented a photocurrent response mechanism of quantum dots (QDs) under illumination with the concept of a quantum photoelectric effect. Upon irradiation, the photoelectron could directly escape from QDs. By using nitro blue tetrazolium (NBT) to capture the photoelectron, a new visual system was proposed due to the formation of an insoluble reduction product, purple formazan, which could be used to visualize the quantum photoelectric effect. The interaction of copper(II) with QDs could form trapping sites to interfere with the quantum confinement and thus blocked the escape of photoelectron, leading to a "signal off" visual method for sensitive copper(II) detection. Meanwhile, by using QDs as a signal tag to label antibody, a "signal on" visual method was also proposed for immunoassay of corresponding protein. With meso-2,3-dimercaptosuccinic-capped CdTe QDs and carcino-embryonic antigen as models, the proposed visual detection methods showed high sensitivity, low detection limit, and wide detectable concentration ranges. The visualization of quantum photoelectric effect could be simply extended for the detection of other targets. This work opens a new visual detection way and provides a highly efficient tool for bioanalysis.

  20. Effective Dynamics of Disordered Quantum Systems

    Science.gov (United States)

    Kropf, Chahan M.; Gneiting, Clemens; Buchleitner, Andreas

    2016-07-01

    We derive general evolution equations describing the ensemble-average quantum dynamics generated by disordered Hamiltonians. The disorder average affects the coherence of the evolution and can be accounted for by suitably tailored effective coupling agents and associated rates that encode the specific statistical properties of the Hamiltonian's eigenvectors and eigenvalues, respectively. Spectral disorder and isotropically disordered eigenvector distributions are considered as paradigmatic test cases.

  1. Effects of isolation and confinement on humans-implications for manned space explorations.

    Science.gov (United States)

    Pagel, J I; Choukèr, A

    2016-06-15

    Human psychology and physiology are significantly altered by isolation and confinement. In light of planned exploration class interplanetary missions, the related adverse effects on the human body need to be explored and defined as they have a large impact on a mission's success. Terrestrial space analogs offer an excellent controlled environment to study some of these stressors during a space mission in isolation without the complex environment of the International Space Station. Participants subjected to these space analog conditions can encounter typical symptoms ranging from neurocognitive changes, fatigue, misaligned circadian rhythm, sleep disorders, altered stress hormone levels, and immune modulatory changes. This review focuses on both the psychological and the physiological responses observed in participants of long-duration spaceflight analog studies, such as Mars500 or Antarctic winter-over. They provide important insight into similarities and differences encountered in each simulated setting. The identification of adverse effects from confinement allows not only the crew to better prepare for but also to design feasible countermeasures that will help support space travelers during exploration class missions in the future. Copyright © 2016 the American Physiological Society.

  2. Effects of strain rate and confining pressure on the deformation and failure of shale

    Energy Technology Data Exchange (ETDEWEB)

    Cook, J.M. (Schlumberger Cambridge Research (GB)); Sheppard, M.C. (Anadrill/Schlumberger (US)); Houwen, O.H. (Sedco Forex (FR))

    1991-06-01

    Previous work on shale mechanical properties has focused on the slow deformation rates appropriate to wellbore deformation. Deformation of shale under a drill bit occurs at a very high rate, and the failure properties of the rock under these conditions are crucial in determining bit performance and in extracting lithology and pore-pressure information from drilling parameters. Triaxial tests were performed on two nonswelling shales under a wide range of strain rates and confining and pore pressures. At low strain rates, when fluid is relatively free to move within the shale, shale deformation and failure are governed by effective stress or pressure (i.e., total confining pressure minus pore pressure), as is the case for ordinary rock. If the pore pressure in the shale is high, increasing the strain rate beyond about 0.1%/sec causes large increases in the strength and ductility of the shale. Total pressure begins to influence the strength. At high stain rates, the influence of effective pressure decreases, except when it is very low (i.e., when pore pressure is very high); ductility then rises rapidly. This behavior is opposite that expected in ordinary rocks. This paper briefly discusses the reasons for these phenomena and their impact on wellbore and drilling problems.

  3. Effects of surface morphology on the anchoring and electrooptical dynamics of confined nanoscale liquid crystalline films.

    Science.gov (United States)

    Noble, Alison R; Kwon, Hye J; Nuzzo, Ralph G

    2002-12-18

    The orientation and dynamics of two 40-nm thick films of 4-n-pentyl-4'-cyanobiphenyl (5CB), a nematic liquid crystal, have been studied using step-scan Fourier transform infrared spectroscopy (FTIR). The films are confined in nanocavities bounded by an interdigitated electrode array (IDA) patterned on a zinc selenide (ZnSe) substrate. The effects of the ZnSe surface morphology (specifically, two variations of nanometer-scale corrugations obtained by mechanical polishing) on the initial ordering and reorientation dynamics of the electric-field-induced Freedericksz transition are presented here. The interaction of the 5CB with ZnSe surfaces bearing a spicular corrugation induces a homeotropic (surface normal) alignment of the film confined in the cavity. Alternately, when ZnSe is polished to generate fine grooves along the surface, a planar alignment is promoted in the liquid crystalline film. Time-resolved FTIR studies that enable the direct measurement of the rate constants for the electric-field-induced orientation and thermal relaxation reveal that the dynamic transitions of the two film structures are significantly different. These measurements quantitatively demonstrate the strong effects of surface morphology on the anchoring, order, and dynamics of liquid crystalline thin films.

  4. Gravitational Effects of a Crystalline Quantum Foam

    Science.gov (United States)

    Crouse, David

    2017-01-01

    In this work, concepts in quantum mechanics and general relativity are used to derive the quantums of space and time. After showing that space and time, at the Planck scale, must be discrete and not continuous, various anomalous gravitational effects are described. It is discussed how discrete space necessarily imposes order upon Wheeler's quantum foam, changing the foam into a crystal. The forces in this crystal are gravitational forces due to the ordered array of electrically neutral Planck masses, and with a lattice constant on the order of the Planck length. Thus the crystal is a gravity crystal rather than the more common crystals (e.g., silicon) that rely on electromagnetic forces. It is shown that similar solid-state physics techniques can be applied to this universe-wide gravity crystal to calculate particles' dispersion curves. It is shown that the crystal produces typical crystalline effects, namely bandgaps, Brillouin zones, and effective inertial masses that may differ from the gravitational masses with possible values even being near zero or negative. It is shown that the gravity crystal can affect the motion of black holes in dramatic ways, imbuing them with a negative inertial mass such that they are pushed by the pull of gravity.

  5. Stimulated visible light emission from ultrathin GaAs single and multiple quantum wells sandwiched between indirect-gap (Al sub 0. 49 Ga sub 0. 51 As) confining layers

    Energy Technology Data Exchange (ETDEWEB)

    Lee, J.H.; Hsieh, K.Y.; Hwang, Y.L.; Kolbas, R.M. (Department of Electrical and Computer Engineering, North Carolina State University, Raleigh, North Carolina 27695-7911 (USA))

    1990-05-14

    Spontaneous and stimulated emission from a series of Al{sub 0.7}Ga{sub 0.3}As -Al{sub 0.49}Ga{sub 0.51}As-GaAs ultrathin single (1,2, and 3 monolayer (ML), 1 ML=2.83 A) and multiple (2 ML) quantum well separate confinement heterostructures are demonstrated and compared to a control sample (0 ML). Spectra from sample to sample are very different and depend on the alignment of the {ital n}=1, {Gamma} electron bound state in the quantum well with the {ital X}{sub minima} (lowest band edge) in the indirect-gap (Al{sub 0.49}Ga{sub 0.51}As) confining layers. Some samples (3 ML single and 2 ML multiple quantum well) can support stimulated emission despite the fact that the quantum well is undoped, unstrained, and very thin ({ital L}{sub {ital z}} {much lt}scattering path length) and that most of the wave function is in the indirect-gap confining layers. These experimental results can be explained using a simple model based on the spatial extent of the wave function (rather than the well width) under the special condition of band alignment between the {Gamma} and {ital X} states.

  6. Extremely confined quantum-well states for (2×2)-K and (3×3)-K on graphite: First-principles calculations

    Science.gov (United States)

    Chis, V.; Walldén, L.

    2011-10-01

    We report on the atomic and electronic structure obtained by first-principles density functional theory calculations for a (2×2)-K monolayer as well as a (3×3)-K monolayer on graphite represented by an 11-layer carbon slab. In both cases, the calculations predict that the K atoms reside above hollows [2.93 Å above the surface atomic layers for (2×2)-K]. The electronic structure is characterized by a partially occupied, free-electron-like overlayer quantum-well (QW)-state band (EF-0.76 eV at Γ¯, 1.14me) and one empty QW band (EF+1.7 eV, 1.0me), for (2×2)-K. The partially filled QW band, which has an energy and dispersion close to that which has been experimentally observed, provides examples of extremely confined states with nearly all charge (93%) deposited in the overlayer. In the substrate, the layer-confined σ bands are rigidly downshifted, by 0.6 eV for the outermost carbon-atom layer and by 0.14 eV for the second layer. For the π electrons, downshifted bands are split off from the ladder of closely spaced band energies, which approximate the continuum of states in a thick graphite sample. The splitting off can be regarded as the formation of a QW state, since the electrons are found mainly in the outermost layer of carbon atoms. The split-off band is not obtained via a downshift of the band with the lowest energy among the closely spaced states, since the band-edge states of the bare substrate have only a small amplitude in the outermost layer of carbon atoms. The high degree of confinement for both the K overlayer states and the C underlayer π states should make the system of interest for studies of the excitations of two near-two-dimensional electron gases at short distance.

  7. Fano Effect and Quantum Entanglement in Hybrid Semiconductor Quantum Dot-Metal Nanoparticle System

    Directory of Open Access Journals (Sweden)

    Yong He

    2017-06-01

    Full Text Available In this paper, we review the investigation for the light-matter interaction between surface plasmon field in metal nanoparticle (MNP and the excitons in semiconductor quantum dots (SQDs in hybrid SQD-MNP system under the full quantum description. The exciton-plasmon interaction gives rise to the modified decay rate and the exciton energy shift which are related to the exciton energy by using a quantum transformation method. We illustrate the responses of the hybrid SQD-MNP system to external field, and reveal Fano effect shown in the absorption spectrum. We demonstrate quantum entanglement between two SQD mediated by surface plasmon field. In the absence of a laser field, concurrence of quantum entanglement will disappear after a few ns. If the laser field is present, the steady states appear, so that quantum entanglement produced will reach a steady-state entanglement. Because one of all optical pathways to induce Fano effect refers to the generation of quantum entangled states, It is shown that the concurrence of quantum entanglement can be obtained by observation for Fano effect. In a hybrid system including two MNP and a SQD, because the two Fano quantum interference processes share a segment of all optical pathways, there is correlation between the Fano effects of the two MNP. The investigations for the light-matter interaction in hybrid SQD-MNP system can pave the way for the development of the optical processing devices and quantum information based on the exciton-plasmon interaction.

  8. Fano Effect and Quantum Entanglement in Hybrid Semiconductor Quantum Dot-Metal Nanoparticle System

    Science.gov (United States)

    He, Yong; Zhu, Ka-Di

    2017-01-01

    In this paper, we review the investigation for the light-matter interaction between surface plasmon field in metal nanoparticle (MNP) and the excitons in semiconductor quantum dots (SQDs) in hybrid SQD-MNP system under the full quantum description. The exciton-plasmon interaction gives rise to the modified decay rate and the exciton energy shift which are related to the exciton energy by using a quantum transformation method. We illustrate the responses of the hybrid SQD-MNP system to external field, and reveal Fano effect shown in the absorption spectrum. We demonstrate quantum entanglement between two SQD mediated by surface plasmon field. In the absence of a laser field, concurrence of quantum entanglement will disappear after a few ns. If the laser field is present, the steady states appear, so that quantum entanglement produced will reach a steady-state entanglement. Because one of all optical pathways to induce Fano effect refers to the generation of quantum entangled states, It is shown that the concurrence of quantum entanglement can be obtained by observation for Fano effect. In a hybrid system including two MNP and a SQD, because the two Fano quantum interference processes share a segment of all optical pathways, there is correlation between the Fano effects of the two MNP. The investigations for the light-matter interaction in hybrid SQD-MNP system can pave the way for the development of the optical processing devices and quantum information based on the exciton-plasmon interaction. PMID:28632165

  9. Fano Effect and Quantum Entanglement in Hybrid Semiconductor Quantum Dot-Metal Nanoparticle System.

    Science.gov (United States)

    He, Yong; Zhu, Ka-Di

    2017-06-20

    In this paper, we review the investigation for the light-matter interaction between surface plasmon field in metal nanoparticle (MNP) and the excitons in semiconductor quantum dots (SQDs) in hybrid SQD-MNP system under the full quantum description. The exciton-plasmon interaction gives rise to the modified decay rate and the exciton energy shift which are related to the exciton energy by using a quantum transformation method. We illustrate the responses of the hybrid SQD-MNP system to external field, and reveal Fano effect shown in the absorption spectrum. We demonstrate quantum entanglement between two SQD mediated by surface plasmon field. In the absence of a laser field, concurrence of quantum entanglement will disappear after a few ns. If the laser field is present, the steady states appear, so that quantum entanglement produced will reach a steady-state entanglement. Because one of all optical pathways to induce Fano effect refers to the generation of quantum entangled states, It is shown that the concurrence of quantum entanglement can be obtained by observation for Fano effect. In a hybrid system including two MNP and a SQD, because the two Fano quantum interference processes share a segment of all optical pathways, there is correlation between the Fano effects of the two MNP. The investigations for the light-matter interaction in hybrid SQD-MNP system can pave the way for the development of the optical processing devices and quantum information based on the exciton-plasmon interaction.

  10. Quantum confinement-tunable intersystem crossing and the triplet state lifetime of cationic porphyrin-CdTe quantum dot nano-assemblies

    KAUST Repository

    Ahmed, Ghada H.

    2015-01-01

    Here, we report a ground-state interaction between the positively charged cationic porphyrin and the negatively charged carboxylate groups of the thiol ligands on the surface of CdTe quantum dots (QDs), leading to the formation of a stable nanoassembly between the two components. Our time-resolved data clearly demonstrate that we can dramatically tune the intersystem crossing (ISC) and the triplet state lifetime of porphyrin by changing the size of the QDs in the nanoassembly. © 2015 The Royal Society of Chemistry.

  11. Effect of quantum corrections on Rayleigh-Taylor instability and internal waves in strongly coupled magnetized viscoelastic fluid

    Science.gov (United States)

    Prajapati, Ramprasad

    2016-07-01

    The Rayleigh-Taylor (R-T) instability is recently investigated is strongly coupled plasma looking to its importance in dense stellar systems and Inertial Confinement Fusion [1-3]. In the present work, the effect of quantum corrections are studied on Rayleigh-Taylor (R-T) instability and internal wave propagation in a strongly coupled, magnetized, viscoelastic fluid. The modified generalized hydrodynamic model is used to derive the analytical dispersion relation. The internal wave mode and dispersion relation are modified due to the presence of quantum corrections and viscoelastic effects. We observe that strong coupling effects and quantum corrections significantly modifies the dispersion characteristics. The dispersion relation is also discussed in weakly coupled (hydrodynamic) and strongly coupled (kinetic) limits. The explicit expression of R-T instability criterion is derived which is influenced by shear velocity and quantum corrections. Numerical calculations are performed in astrophysical and experimental relevance and it is examined that both the shear and quantum effects suppresses the growth rate of R-T instability. The possible application of the work is discussed in Inertial Confinement Fusion (ICF) to discuss the suppression of R-T instability under considered situation. References: [1] R. P. Prajapati, Phys. Plasmas 23, 022106 (2016). [2] K. Avinash and A. Sen, Phys. Plasmas 22, 083707 (2015). [3] A. Das and P. Kaw, Phys. Plasmas 21 (2014) 062102.

  12. Effect of Rasbha spin-orbit interaction on the ground state energy of a hydrogenic D{sup 0} complex in a Gaussian quantum dot

    Energy Technology Data Exchange (ETDEWEB)

    Boda, Aalu, E-mail: aaluphd@gmail.com; Kumar, D. Sanjeev; Chatterjee, Ashok [School of Physics, University of Hyderabad, Hyderabad-500046, Telangana (India); Mukhopadhyay, Soma [Department of Physics, DVR College of Engineering and Technology, Sangareddy Mandal, Hyderabad 502285 (India)

    2015-06-24

    The ground state energy of a hydrogenic D{sup 0} complex trapped in a three-dimensional GaAs quantum dot with Gaussian confinement is calculated variationally incorporating the effect of Rashba spin-orbit interaction. The results are obtained as a function of the quantum dot size and the Rashba spin-orbit interaction. The results show that the Rashba interaction reduces the ground state energy of the system.

  13. Insertion and confinement of hydrophobic metallic powder in water: The bubble-marble effect

    Science.gov (United States)

    Meir, Yehuda; Jerby, Eli

    2014-09-01

    Metallic powders such as thermite are known as efficient fuels also applicable in oxygen-free environments. However, due to their hydrophobicity, they hardly penetrate into water. This paper presents an effect that enables the insertion and confinement of hydrophobic metallic powders in water, based on encapsulating an air bubble surrounded by a hydrophobic metallic shell. This effect, regarded as an inverse of the known liquid-marble effect, is named here "bubble marble" (BM). The sole BM is demonstrated experimentally as a stable, maneuverable, and controllable soft-solid-like structure, in a slightly deformed hollow spherical shape of ˜1-cm diameter. In addition to experimental and theoretical BM aspects, this paper also demonstrates its potential for underwater applications, such as transportation of solid objects within BM and underwater combustion of thermite BM by localized microwaves. Hence, the BM phenomena may open new possibilities for heat and thrust generation, as well as material processing and mass transfer underwater.

  14. Quantum optical effective-medium theory and transformation quantum optics for metamaterials

    DEFF Research Database (Denmark)

    Wubs, Martijn; Amooghorban, Ehsan; Zhang, Jingjing

    2016-01-01

    While typically designed to manipulate classical light, metamaterials have many potential applications for quantum optics as well. We argue why a quantum optical effective-medium theory is needed. We present such a theory for layered metamaterials that is valid for light propagation in all spatial...... directions, thereby generalizing earlier work for one-dimensional propagation. In contrast to classical effective-medium theory there is an additional effective parameter that describes quantum noise. Our results for metamaterials are based on a rather general Lagrangian theory for the quantum...

  15. Quantum Dot Photovoltaics in the Extreme Quantum Confinement Regime: The Surface-Chemical Origins of Exceptional Air- and Light-Stability

    KAUST Repository

    Tang, Jiang

    2010-02-23

    We report colloidal quantum dot (CQDs) photovoltaics having a ∼930 nm bandgap. The devices exhibit AM1.5G power conversion efficiencies in excess of 2%. Remarkably, the devices are stable in air under many tens of hours of solar illumination without the need for encapsulation. We explore herein the origins of this ordersof-magnitude improvement in air stability compared to larger PbS dots. We find that small and large dots form dramatically different oxidation products, with small dots forming lead sulfite primarily and large dots, lead sulfate. The lead sulfite produced on small dots results in shallow electron traps that are compatible with excellent device performance; whereas the sulfates formed on large dots lead to deep traps, midgap recombination, and consequent catastrophic loss of performance. We propose and offer evidence in support of an explanation based on the high rate of oxidation of sulfur-rich surfaces preponderant in highly faceted large-diameter PbS colloidal quantum dots. © 2010 American Chemical Society.

  16. Effective evolution equations from quantum dynamics

    CERN Document Server

    Benedikter, Niels; Schlein, Benjamin

    2016-01-01

    These notes investigate the time evolution of quantum systems, and in particular the rigorous derivation of effective equations approximating the many-body Schrödinger dynamics in certain physically interesting regimes. The focus is primarily on the derivation of time-dependent effective theories (non-equilibrium question) approximating many-body quantum dynamics. The book is divided into seven sections, the first of which briefly reviews the main properties of many-body quantum systems and their time evolution. Section 2 introduces the mean-field regime for bosonic systems and explains how the many-body dynamics can be approximated in this limit using the Hartree equation. Section 3 presents a method, based on the use of coherent states, for rigorously proving the convergence towards the Hartree dynamics, while the fluctuations around the Hartree equation are considered in Section 4. Section 5 focuses on a discussion of a more subtle regime, in which the many-body evolution can be approximated by means of t...

  17. Effects of magnetic ripple on 3D equilibrium and alpha particle confinement in the European DEMO

    Science.gov (United States)

    Pfefferlé, D.; Cooper, W. A.; Fasoli, A.; Graves, J. P.

    2016-11-01

    An assessment of alpha particle confinement is performed in the European DEMO reference design. 3D MHD equilibria with nested flux-surfaces and single magnetic axis are obtained with the VMEC free-boundary code, thereby including the plasma response to the magnetic ripple created by the finite number of TF coils. Populations of fusion alphas that are consistent with the equilibrium profiles are evolved until slowing-down with the VENUS-LEVIS orbit code in the guiding-centre approximation. Fast ion losses through the last-closed flux-surface are numerically evaluated with two ripple models: (1) using the 3D equilibrium and (2) algebraically adding the non-axisymmetric ripple perturbation to the 2D equilibrium. By virtue of the small ripple field and its non-resonant nature, both models quantitatively agree. Differences are however noted in the toroidal location of particles losses on the last-closed flux-surface, which in the first case is 3D and in the second not. Superbanana transport, i.e. ripple-well trapping and separatrix crossing, is expected to be the dominant loss mechanism, the strongest effect on alphas being between 100-200 KeV. Above this, stochastic ripple diffusion is responsible for a rather weak loss rate, as the stochastisation threshold is observed numerically to be higher than analytic estimates. The level of ripple in the current 18 TF coil design of the European DEMO is not found to be detrimental to fusion alpha confinement.

  18. Scale Effect of Premixed Methane-Air Combustion in Confined Space Using LES Model

    Directory of Open Access Journals (Sweden)

    Liang Wang

    2015-12-01

    Full Text Available Gas explosion is the most hazardous incident occurring in underground airways. Computational Fluid Dynamics (CFD techniques are sophisticated in simulating explosions in confined spaces; specifically, when testing large-scale gaseous explosions, such as methane explosions in underground mines. The dimensions of a confined space where explosions could occur vary significantly. Thus, the scale effect on explosion parameters is worth investigating. In this paper, the impact of scaling on explosion overpressures is investigated by employing two scaling factors: The Gas-fill Length Scaling Factor (FLSF and the Hydraulic Diameter Scaling Factor (HDSF. The combinations of eight FLSFs and five HDSFs will cover a wide range of space dimensions where flammable gas could accumulate. Experiments were also conducted to evaluate the selected numerical models. The Large Eddy Simulation turbulence model was selected because it shows accuracy compared to the widely used Reynolds’ averaged models for the scenarios investigated in the experiments. Three major conclusions can be drawn: (1 The overpressure increases with both FLSF and HDSF within the deflagration regime; (2 In an explosion duct with a length to diameter ratio greater than 54, detonation is more likely to be triggered for a stoichiometric methane/air mixture; (3 Overpressure increases as an increment hydraulic diameter of a geometry within deflagration regime. A relative error of 7% is found when predicting blast peak overpressure for the base case compared to the experiment; a good agreement for the wave arrival time is also achieved.

  19. Evaluation of confinement effects in zeolites under Henry's adsorption regime

    Energy Technology Data Exchange (ETDEWEB)

    Pera-Titus, Marc, E-mail: marc.pera-titus@ircelyon.univ-lyon1.fr [Universite de Lyon, Institut de Recherches sur la Catalyse et l' Environnement de Lyon (IRCELYON), UMR 5256 CNRS, Universite Lyon 1, 2, Av. A. Einstein, 69626 Villeurbanne Cedex (France); Llorens, Joan [Chemical Engineering Department, Faculty of Chemistry, University of Barcelona, Marti i Franques, 1, 08028 Barcelona (Spain)

    2010-06-15

    This paper provides a detailed thermodynamic analysis of gas/vapour adsorption in zeolites at low pressures. At these conditions, we show first that Henry's isotherm can be conveniently rewritten using the thermodynamic isotherm model developed in a previous study [J. Llorens, M. Pera-Titus, Description of gas adsorption on microporous materials: evaluation of energy heterogeneity, J. Colloid Interface Sci. 331, 2009, 302-311], linking the integral free energy of adsorption relative to saturation, {Psi}/RT, expressed as a Kiselev integral, with the variable Z = 1/-ln({Pi}), being {Pi} the relative pressure. Relevant information about sorbate confinement effects in zeolites can be inferred using strong sorbates under Henry's adsorption regime using the thermodynamic formulation provided here. The confining level of zeolites can be characterized by a parameter (m{sub 1}), whose value depends on the zeolite framework, but remains essentially unchanged with the sorbate probe molecule and temperature. We illustrate the application of these concepts using a collection of MFI and MTW-type zeolites as model systems.

  20. Effect of crowding and confinement on first-passage times: A model study

    Science.gov (United States)

    Antoine, C.; Talbot, J.

    2016-06-01

    We study the "color dynamics" of a hard-disk fluid confined in an annulus, as well as the corresponding hard-sphere system in three dimensions, using event-driven simulation in order to explore the effect of confinement and self-crowding on the search for targets. We compute the mean first-passage times (MFPTs) of red particles transiting from the outer to the inner boundary as well as those of blue particles passing from the inner to the outer boundary for different packing fractions and geometries. In the steady state the reaction rate, defined as the rate of collision of red particles with the inner boundary, is inversely proportional to the sum of the MFPTs. The reaction rate is wall mediated (ballistic) at low densities and diffusion controlled at higher densities and displays a maximum at intermediate densities. At moderate to high densities, the presence of layering has a strong influence on the search process. The numerical results for the reaction rate and MFPTs are compared with a ballistic model at low densities and a Smoluchowski approach with uniform diffusivities at higher densities. We discuss the reasons for the limited validity of the theoretical approaches. The maximum in the reaction rate is qualitatively well rendered by a Bosanquet-like approach that interpolates between the two regimes. Finally, we compute the position-dependent diffusivity from the MFPTs and observe that it is out of phase with the radial density.