Sample records for pumice

  1. Pumice aggregates for internal water curing

    DEFF Research Database (Denmark)

    Pietro, Lura; Bentz, Dale P.; Lange, David A.


    without pumice and mixes with 4% and 8% pumice by volume of mortar. By addition of pumice, mortars with improved strength, enhanced degree of hydration and reduced autogenous shrinkage were obtained. An important obstacle to the application of this kind of pumice for actual concrete production......A novel concept in internal curing of High Performance Concrete is based on dispersing very small, saturated lightweight aggregates (LWA) in the concrete, containing sufficient water to counteract self-desiccation. With this approach, the amount of water in the LWA can be minimized, thus...... water absorption, but they release a greater percentage of their absorbed water at the equilibrium relative humidity of practical interest in early-age concrete, above 90%. Additionally, early-age properties of mortars with different contents of saturated pumice were investigated: a reference mix...

  2. Classification of archaeologically stratified pumice by INAA

    International Nuclear Information System (INIS)

    Peltz, C.; Bichler, M.


    In the framework of the research program 'Synchronization of Civilization in the Eastern Mediterranean Region in the 2nd Millenium B.C.' instrumental neutron activation analysis (INAA) was used to determine 30 elements in pumice from archaeological excavations to reveal their specific volcanic origin. The widespread pumiceous products of several eruptions in the Aegean region were used as abrasive tools and were therefore popular trade objects. A remarkable quantity of pumice and pumiceous tephra (several km 3 ) was produced by the 'Minoan eruption' of Thera (Santorini), which is assumed to have happened between 1450 and 1650 B.C. Thus the discovery of the primary fallout of 'Minoan' tephra in archaeologically stratified locations can be used as a relative time mark. Additionally, pumice lumps used as abrasive can serve for dating by first appearance. Essential to an identification of the primary volcanic source is the knowledge that pumices from the Aegean region can easily be distinguished by their trace element distribution patterns, as previous work has shown. The elements Al, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Tb, Th, Ti, U, V, Yb, Zn and Zr were determined in 16 samples of pumice lumps from excavations in Tell-el-Dab'a and Tell-el-Herr (Egypt). Two irradiation cycles and five measurement runs were applied. A reliable identification of the samples is achieved by comparing these results to the database compiled in previous studies. (author)


    Directory of Open Access Journals (Sweden)

    Güngör TUNCER


    Full Text Available Within this paper, pumice is investigated in general and its importance is emphasized for our county's economy. Pumice which has a hardness of 5-6 with a specific gravity of 1-2 g/cm 3 owns many pores from micro to microscale. Its heat and sound insulation is extremely high whereas its permeability is too low due to its pore's independence from each other. It has got wide use areas in industry today due to those vital physical properties. Pumice which is produced by very simple mining and processing methods, has been used in many different fields, such as construction, textile, chemical and agricultural industries. This work aims to reveal scientific, technical and statistical information about pumice whose importance has been increasing day by day for our country's economy as an industrial mineral and try to raise the common interests of both industrialists and scientists about its mining and processing.

  4. Cadmium removal from aqueous solutions by pumice and nano-pumice

    Energy Technology Data Exchange (ETDEWEB)

    Khorzughy, Sara Haddadi; Eslamkish, Teymur [Amirkabir University of Technology, Tehran (Iran, Islamic Republic of); Ardejani, Faramarz Doulati [University of Tehran, Tehran (Iran, Islamic Republic of); Heydartaemeh, Mohammad Reza [Shahrood University of Technology, Shahrood (Iran, Islamic Republic of)


    Use of low-cost minerals to eliminate mining and industrial pollutants is the main goal of this study. We investigated the ability of pumice and nano-pumice to remove cadmium from a synthetic aqueous solution. Batch experiments were performed to investigate adsorption characteristic; therefore, the effective factors influencing the adsorption process including solution pH, contact time and initial concentration have been considered. Equilibrium data were attempted by Langmuir and Freundlich isotherm models to realize the interaction between adsorbent and adsorbate. The results show that cadmium adsorption on Pumice follows the Langmuir isotherm model with a R{sup 2} of 0.9996 and shows a homogeneous and mono-layer adsorption. Whereas, cadmium adsorption on nano-Pumice follows a Freundlich model (R{sup 2}=0.9939) and exhibits a multi-layer adsorption. The maximum mono-layer capacity (q{sub max}) of cadmium for pumice and nano-pumice was calculated 26 and 200mg/g, respectively. Two different kinetics models including pseudo first-order and pseudo second-order were studied to evaluate the rate and mechanism of cadmium adsorption by pumice and nano-pumice. The kinetics data indicate that a pseudo second-order model provides the best correlation of the experimental data.

  5. Drift pumice in the central Indian Ocean Basin: Geochemical evidence

    Digital Repository Service at National Institute of Oceanography (India)

    Pattan, J.N.; Mudholkar, A.V.; JaiSankar, S.; Ilangovan, D.

    Abundant white to light grey-coloured pumice without ferromanganese oxide coating occurs within the Quaternary sediments of the Central Indian Ocean Basin (CIOB). Two distinct groups of pumice are identified from their geochemical composition, which...

  6. Suitability of Moshi Pumice for Phosphorus Sorption in Constructed ...

    African Journals Online (AJOL)

    The study of Moshi Pumice's phosphorus sorption behaviours and properties was carried out in laboratory scale where by 1-2 mm, 2-4 mm and 4-8 mm grains were tested using batch experiments. The results show that Moshi Pumice has high phosphorus sorption capacity. The sorption capacity for the Moshi Pumice was ...

  7. The structure of pumice by neutron diffraction

    International Nuclear Information System (INIS)

    Floriano, M.A.; Venezia, A.M.; Deganello, G.; Svensson, E.C.; Root, J.H.


    Small-angle neutron scattering (SANS) and wide-angle neutron scattering (WANS) measurements on pumice, an amorphous natural aluminosilicate used as support for metals in the preparation of catalysts, are reported. The SANS spectrum indicates the presence of a broad size distribution of pores and the absence of volume fractality. Surface fractality, however, cannot be ruled out. The structure of pumice, suggested by the pair-correlation function derived from the WANS spectrum and simulated by a random-network structure model, is very similar to that of vitreous silica, consisting mainly of SiO 4- 4 tetrahedra interconnected by bridging O atoms with additional local disorder generated by the replacement, on average, of one in ten Si atoms by aluminium. (orig.)

  8. Characteristics of drift pumice from New Caledonia beaches (United States)

    Nicholson, Kirsten Ngaire; Stewart, Ariel


    Siliceous drift pumice was collected from a total of 40 beaches around the main island of New Caledonia, Southwest Pacific, in order to determine its provenance. New Caledonia is enclosed by a barrier reef lagoon whose 2008 designation as a UNESCO World Heritage Site brought attention to the environmental degradation caused by a century of open cast nickel mining. The frequent, voluminous pumice eruptions in the Southwest Pacific provide ample source material that is somewhat durable, highly transportable in water, and easy to collect and analyze. Geochemical and mineralogical analyses were used to identify the source of the pumice in order to map the transport vector across the open ocean and into the lagoon. Drift pumice was sampled during 2008 and 2010. The mineral assemblage of the pumice was consistently calcic plagioclase, clinopyroxene, orthopyroxene, and opaque minerals. All of the pumice was of fairly uniform geochemistry: low in mafic elements, low in alkalis, with LILE enriched compared to HFSE, and negative Eu, Ti, and Zr anomalies. The pumice is predominately dacitic and tholeiitic. This geochemical signature was consistent with published data from the Tonga arc, which is further supported by the mineralogy. With the exception of two samples (which probably came from either the Kermadec arc or Vanuatu) all of the pumice comes from the Tonga arc. The samples from 2008 are consistent with pumice erupted from Metis Shoal in 2006, and the majority of 2010 samples are consistent with pumice erupted from an unnamed volcano (0403-091) that erupted in 2001.

  9. Mineral resource of the month: pumice and pumicite (United States)



    The article offers information on pumice, an important commodity for the construction, horticulture and abrasives industries. The commodity is described as an extremely light, highly porous extrusive volcanic rock which was formed due to the rapid cooling of air-pocketed lava. It is noted that the characteristics of pumice make it as an ideal aggregate material in lightweight building blocks in the U.S. and abroad. The leading countries in terms of pumice production are Greece and the U.S.

  10. Effects of pumice mining on soil quality (United States)

    Cruz-Ruíz, A.; Cruz-Ruíz, E.; Vaca, R.; Del Aguila, P.; Lugo, J.


    México is the worl's fourth most important maize producer; hence, there is a need to maintain soil quality for a sustainable production in the upcoming years. Pumice mining, a superficial operation, modifies large areas in Central Mexico. The main aim was to assess the present state of agricultural soils differing in elapsed-time since pumice mining (0-15 years), in a representative area of the Calimaya region in the State of Mexico. The study sites in 0, 1, 4, 10 and 15 year-old reclaimed soils were compared with adjacent undisturbed site. Our results indicate that soil organic carbon, total nitrogen, microbial biomass carbon and microbial quotients were greatly impacted by disturbance. A general trend of recovery towards the undisturbed condition with reclamation age was found after disturbance. Recovery of soil total nitrogen was faster than soil organic carbon. Principal components analysis was applied. The first three components together explain 71.72 % of the total variability. First factor reveals strong associations between total nitrogen, microbial biomass carbon and pH. The second factor reveals high loading of urease and catalase. The obtained results revealed that the most appropriate indicators to diagnose the quality of the soils were: total nitrogen, microbial biomass carbon and soil organic carbon.

  11. The origin of pumice at Balmoral Beach aboriginal shell midden

    International Nuclear Information System (INIS)

    Attenbrow, V.; Sutherland, L.; Hashimoto, R.; Barron, J.


    Full text: Pumice occurs in varying amounts throughout the 2 m depth of deposits of Balmoral Beach shell midden. In one area a distinct layer of concentrated pumice occurs between 85 cm to 95 cm below present ground level. A radiocarbon date indicates that this layer was deposited around 3300 BP. Petrographic analysis of the pumice from selected levels indicates that pumice in the concentrated layer is distinct and may come from a different source from pumice in levels above and below. It contains sporadic crystals of olivine, pyroxene, feldspar, plagioclase and opaque iron oxides set in a highly vesicular rhyolite glass. Analyses of major and trace elements support such a conclusion. Geomorphological investigations indicate that Balmoral Beach formed progressively between 6000 and 2500 years ago. We hypothesize that the main pumice layer was brought in by wave action along the shoreline and derives from a raft of pumice which formed after a volcanic eruption in an as-yet unknown location. This may be local or from known drift sources, such as New Zealand, Tonga, Indonesia, the Solomon Islands or Southern Ocean sources. Results of the petrographic and major and trace element analyses suggest a potential source in the Tongan-Kermadec region. The mode of deposition of the pumice is also being investigated and will include the possibility of tsunami action

  12. Flexural behavior of reinforced concrete beam with polymer coated pumice (United States)

    Nainggolan, Christin Remayanti; Wijatmiko, Indradi; Wibowo, Ari


    Sustainable development has become an important issue due to the increasing consideration of preserving the nature. Many alternative for coarse aggregate replacement have been investigated ranging from natural and fabricated aggregates. In this study, natural aggregate pumice was investigated since it offers lower density that give paramount benefit in reducing total building weight and hence reducing the earthquake excitation effect and optimizing the structural dimension. However, the characteristic of porous surfaces of pumice causes excessive water absorption during concrete mixing process. Therefore, to reduce the additional water, the pumice aggregates were coated with polymer. The tested specimens consisted of normal concrete beams (NCB), uncoated pumice aggregate concrete beam (UPA) and polymer coated pumice aggregate concrete beam (PCP). The objective of the research was to obtain the effect of coating on the pumice aggregate to the flexural behavior of concrete beams. The lateral load-displacement behavior, ductility and collapse mechanism were studied. The results showed that there were only marginal drop on the load-carrying capacity of the pumice aggregate beam compared to those of normal beam. Additionally, the ductility coefficient of specimens UPA and PCP decreased of 11,97% and 14,03% respectively compared to NCB, and the ultimate load capacity decreased less than 1%. Overall, the pumice aggregate showed good characteristic for replacing normal coarse aggregate.

  13. Usage of pumice as bulking agent in sewage sludge composting. (United States)

    Wu, Chuandong; Li, Weiguang; Wang, Ke; Li, Yunbei


    In this study, the impacts of reused and sucrose-decorated pumice as bulking agents on the composting of sewage sludge were evaluated in the lab-scale reactor. The variations of temperature, pH, NH3 and CO2 emission rate, moisture content (MC), volatile solid, dissolved organic carbon, C/N and the water absorption characteristics of pumice were detected during the 25days composting. The MC of pumice achieved 65.23% of the 24h water absorptivity within the first 2h at the mass ratio of 0.6:1 (pumice:sewage sludge). Reused pumice increased 23.68% of CO2 production and reduced 21.25% of NH3 emission. The sucrose-decorated pumice reduced 43.37% of nitrogen loss. These results suggested that adding pumice and sucrose-decorated pumice in sludge composting matrix could not only adjust the MC of materials, but also improve the degradation of organic matters and reduce nitrogen loss. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Effect of physical, chemical and electro-kinetic properties of pumice samples on radiation shielding properties of pumice material

    International Nuclear Information System (INIS)

    Tapan, Mücip; Yalçın, Zeynel; İçelli, Orhan; Kara, Hüsnü; Orak, Salim; Özvan, Ali; Depci, Tolga


    Highlights: • Radiation shielding properties of pumice materials are studied. • The relationship between physical, chemical and electro-kinetic properties pumice samples is identified. • The photon atomic parameters are important for the absorber peculiarity of the pumices. - Abstract: Pumice has been used in cement, concrete, brick, and ceramic industries as an additive and aggregate material. In this study, some gamma-ray photon absorption parameters such as the total mass attenuation coefficients, effective atomic number and electronic density have been investigated for six different pumice samples. Numerous values of energy related parameters from low energy (1 keV) to high energy (100 MeV) were calculated using WinXCom programme. The relationship between radiation shielding properties of the pumice samples and their physical, chemical and electro-kinetic properties was evaluated using simple regression analysis. Simple regression analysis indicated a strong correlation between photon energy absorption parameters and density and SiO 2 , Fe 2 O 3 , CaO, MgO, TiO 2 content of pumice samples in this study. It is found that photon energy absorption parameters are not related to electro-kinetic properties of pumice samples

  15. NAA of the 'Minoan pumice' at Thera and comparison to alluvial pumice deposits in the Eastern Mediterranean region

    International Nuclear Information System (INIS)

    Bichler, M.; Egger, H.; Preisinger, A.; Ritter, D.; Stastny, P.


    Neutron activation analysis was used to determine up to 30 elements in the pumice layers from the 'Minoan eruption' at Thera (Santorini, Greece). Mt Pilato (Lipari, Italy) and in alluvial pumice from coasts of the Eastern Mediterranean region. The morphologically well distinguishable layers of the 'Minoan pumice' were found to be of nearly similar composition in respect to the elements determined and their distribution patterns could therefore be used to identify a sample as Santorinian or not. Additionally, this method was applied to pumice lumps found during archaeological excavations in the Nile delta, Egypt. The results showed that two of the three Egyptian samples are products of the Minoan eruption at Thera and therefore chronologically useful. A second group of pumices collected at Antalya (Turkey), Crete (Greece) and also in Egypt was found to have a distinctly different composition and is therefore related to another volcanic event. (author)

  16. The Study of Cr3+ Adsorption Wukirsari Pumice

    International Nuclear Information System (INIS)

    Samin; Susanna TS


    As an alternative to solve an environmental problem of Cr 3+ , the use of Wukirsari pumice has been studied. Before used as an adsorbent. 100-200 mesh of Wukirsari pumice was washed and calcinate. The elements composition of adsorbent was analyzed using Atomic Adsorption Spectrophotometer (AAS) method and presented as their oxides. After calcination, the pumice was saturated by NaCI and then converted to its ceramic. The mineral composition of pumice and its ceramic was determined using XRD method. Experimental results show optimum temperature for calcination was 500 o C and 5 hours duration of contact time was found from adsorption of Na + , with the value of 505 mg/g pumice. The other results show that pH of the solution influence the adsorption. The ion exchange between Na + and Cr 3+ did not follow ideal solution, and one ion Cr 3+ could replace only one ion Na + hence optimum adsorption of Cr 3+ was 1141.47 mg/g pumice. The data XRD shows that mineral composition of the pumice was magnetite, anorthite, and montmorilonite, while composition of its ceramic was feldspar and cristobalite. (author)

  17. Pumice stones as potential in-situ burning enhancer

    DEFF Research Database (Denmark)

    Rojas Alva, U.; Andersen, Bjørn Skjønning; Jomaas, Grunde


    Small-scale and mid-scale experiments were conducted in order to evaluate pumice stones as a potential enhancement for in-situ burning (ISB). Four oil types, several emulsification degrees of one crude oil were studied. In general, it was observed that the pumice stones did not improve the burning...... and after the burn, thus bringing the oil into the water column. Finally, the species production of CO and CO2 was not reduced. Based on the presented results, pumice stones have a negative impact on the efficiency of ISB, and they are ruled out as an ISB enhancer and should not be used in relation to ISB....

  18. The recent pumice eruptions of Mt. Pelée volcano, Martinique. Part I: Depositional sequences, description of pumiceous deposits (United States)

    Traineau, Hervé; Westercamp, Denis; Bardintzeff, Jacques-Marie; Miskovsky, Jean-Claude


    Mount Pelée is one of the most active volcanoes of the Lesser Antilles arc, with more than twenty eruptions over the last 5000 years. Both nuée ardente-type eruptions, which are well known, and pumice eruptions, although little known, are very common in the stratigraphic record. The four younger pumice eruptions, P4 (2440 y.B.P.), P3 (2010 y.B.P.), P2 (1670 y.B.P.) and P1 (650 y.B.P.) can be used to reconstruct the eruption sequences. The various pumiceous deposits can be described as fine lithic ash layer, Plinian fall deposits, pumice and ash flow deposits with associated ash cloud fall deposits, and pumice surge deposits. Three kinds of depositional sequences have been defined. The distinctions between them are based on the occurrence of an initial Plinian phase and the generation of intraflow pyroclastic surges. The pumice eruptions of Mt. Pelée are small in intensity and magnitude, as expressed by the dispersal of their products and by the total mass of erupted material which is estimated to be less than 1 km 3 in each case. The pumice fall deposits have dispersal characteristics of small Plinian eruptions, close to the sub-Plinian type. Nevertheless, the probability of an occurrence of a new pumice eruption at Mt. Pelée is high, and the widespread distribution of pumice deposits around the volcano suggests that such an eruption is a major volcanic risk during the present stage of activity.

  19. Rapid, long-distance dispersal by pumice rafting.

    Directory of Open Access Journals (Sweden)

    Scott E Bryan

    Full Text Available Pumice is an extremely effective rafting agent that can dramatically increase the dispersal range of a variety of marine organisms and connect isolated shallow marine and coastal ecosystems. Here we report on a significant recent pumice rafting and long-distance dispersal event that occurred across the southwest Pacific following the 2006 explosive eruption of Home Reef Volcano in Tonga. We have constrained the trajectory, and rate, biomass and biodiversity of transfer, discovering more than 80 species and a substantial biomass underwent a >5000 km journey in 7-8 months. Differing microenvironmental conditions on the pumice, caused by relative stability of clasts at the sea surface, promoted diversity in biotic recruitment. Our findings emphasise pumice rafting as an important process facilitating the distribution of marine life, which have implications for colonisation processes and success, the management of sensitive marine environments, and invasive pest species.

  20. Drift pumice in the Indian and South Atlantic oceans

    International Nuclear Information System (INIS)

    Frick, C.; Kent, L.E.


    Sixty-three samples of drift pumice, collected at the coasts of South Africa, East Africa, Madagascar, Mauritius, the Cocos Islands, Australia, Indonesia, Brazil, Marion Island and Bouvet Island, were investigated petrographically and geochemically with a view to establishing the possible source areas. Geochemically five distinct groups could be distinguished and some could be liked to specific eruptions in the Indian, Atlantic and Pacific oceans. Group A pumice originated from a submarine eruption off Zavodovski Island in the South Sandwich Island Group in 1962. The pumice in Group B occurs mainly on the beaches bordering the Atlantic Ocean, and was found on the west coast of South Africa, on the sea floor south-west of South Africa, and in Brazil. The source of this group is unknown, but all the evidence indicates that it must have been from the Mid-Atlantic Ridge in the South Atlantic Ocean. The Group C pumice was found in the southern Indian Ocean, probably from the Mid-Indian Ridge. The fourth group originated from a submarine eruption along the Tonga Trench in the Pacific Ocean. Group E, which is by far the most homogeneous, includes samples from Australia, the Indian Ocean islands, East and South Africa and samples of the undisputed Krakatoan origin. Specimens from the Krakatoan eruption are still the most abundant type of drift pumice that can be found

  1. A note on an occurrence of pseudo-pumice along the beaches of Goa and Karnataka

    Digital Repository Service at National Institute of Oceanography (India)

    Jumaila, C.P.U.; Pattan, J.N.; Mascarenhas, A.; Parthiban, G.; Moraes, C.; Khedekar, V.D.

    -anomaly These light weight fragments do not correspond with natural pumice, but rather appear to be similar to the chemical composition of foam glass/ artificial pumice available in the market Therefore, it is concluded that these pumice clasts are a waste product...

  2. Nature and composition of interbedded marine basaltic pumice in ...

    Indian Academy of Sciences (India)

    (core) of several samples were obtained by drilling, along with ... Ba, V, Ni, Zn) for five pumice samples were deter- mined by XRF ..... may also take place in the shallow water environ- ..... In: Soils and Sediments (eds) Paquet H and Clauer N,.

  3. Nature and composition of interbedded marine basaltic pumice in the

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 126; Issue 2. Nature and composition of interbedded marine basaltic pumice in the ~52–50 Ma Vastan lignite sequence, western India: Implication for Early Eocene MORB volcanism offshore Arabian Sea. Sarajit Sensarma Hukam Singh R S Rana Debajyoti Paul ...

  4. Fluoride removal from aqueous solution by pumice: case study on ...

    African Journals Online (AJOL)

    The fluoride removal from synthetic water by pumice was studied at batch experiments in this study. The effect of pH, contact time, fluoride concentration and adsorbent dose on the fluoride sequestration was investigated. The optimum conditions were studied on Kuhbonan water as a case study. The results showed that ...

  5. Eruptive shearing of tube pumice: pure and simple


    Dingwell, Donald B.; Lavallée, Yan; Hess, Kai-Uwe; Flaws, Asher; Marti, Joan; Nichols, Alexander R. L.; Gilg, H. Albert; Schillinger, Burkhard


    Understanding the physicochemical conditions extant and mechanisms operative during explosive volcanism is essential for reliable forecasting and mitigation of volcanic events. Rhyolitic pumices reflect highly vesiculated magma whose bubbles can serve as a strain indicator for inferring the state of stress operative immediately prior to eruptive fragmentation. Obtaining the full kinematic picture reflected in bubble population geometry has been extremely difficult, involving dissection of a s...

  6. INAA of Aegaean pumices for the classification of archaeological findings

    International Nuclear Information System (INIS)

    Peltz, C.; Schmid, P.; Bichler, M.


    Instrumental neutron activation analysis (INAA) was used to determine 29 elements in pumice from several volcanic sources (Milos, Nisyros, Yali, Kos and Thera) in the Aegean Sea, Greece, to establish a data basis for the identification of pumice and tephra layers found in archaeological context. The widespread products of the 'Minoan Eruption' of the Thera volcano can now be distinguished clearly from all other sources and will be used to establish a datumline in the Eastern Mediterranean Region in the second millenium B.C. The elements Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Ti, Th, U, V, Yb and Zr were determined in 14 samples from Milos, 25 samples from Nisyros, 7 samples from Kos and 17 samples from Thera. Two cycles of irradiation and four measurement runs were applied. The results were compared and suitable groups, typical for each island, were classified. Due to insufficiently comparable data sets, the criteria for distinguishing the different sources have not been revealed by previous studies. This basic knowledge was used to relate pumice from excavations in Tell-el-Dab'a (Egypt) and Bronze Age Knossos to their specific volcanic origin. (author)

  7. Characterization and stability studies of emulsion systems containing pumice

    Directory of Open Access Journals (Sweden)

    Marilene Estanqueiro


    Full Text Available Emulsions are the most common form of skin care products. However, these systems may exhibit some instability. Therefore, when developing emulsions for topical application it is interesting to verify whether they have suitable physical and mechanical characteristics and further assess their stability. The aim of this work was to study the stability of emulsion systems, which varied in the proportion of the emulsifying agent cetearyl alcohol (and sodium lauryl sulfate (and sodium cetearyl sulfate (LSX, the nature of the oily phase (decyl oleate, cyclomethicone or dimethicone and the presence or absence of pumice (5% w/w. While maintaining the samples at room temperature, rheology studies, texture analysis and microscopic observation of formulations with and without pumice were performed. Samples were also submitted to an accelerated stability study by centrifugation and to a thermal stress test. Through the testing, it was found that the amount of emulsifying agent affects the consistency and textural properties such as firmness and adhesiveness. So, formulations containing LSX (5% w/w and decyl oleate or dimethicone as oily phase had a better consistency and remained stable with time, so exhibited the best features to be used for skin care products.

  8. 14C age of the Satsunai pumice bed, Noboribetsu City, SW Hokkaido, Japan

    International Nuclear Information System (INIS)

    Kawachi, Shinpei; Matsui, Masaru; Miyasaka, Shogo; Akamatsu, Morio; Kasugai, Akira.


    A sample of carbonized fallen tree piece (Picea or Pinus; diameter 5 cm and length 15 cm) was discovered in a crop in the Noboribetsu pumice flow deposit, where fossil-rootless fumaroles had been found recently. It existed in the loam layer immediately above the Satsunai pumice bed covering the Noboribetsu formation and the fumaroles below it. Its 14 C age was determined to be 11,330 +- 320 Y.B.P. Though the distribution and eruption source of Satsunai pumice bed are still unknown, the 14 C age has significance as follows in the Quaternary chronology. (1) The Satsunai pumice bed is important as a pumice bed indicating the boundary between the pleistocene and the Recent epoch. (2) By means of the Satsunai pumice bed, the age of upper Noboribetsu formation is given. (3) As there is no high bench deposit on the Noboribetsu pumice flow deposit, the time gap may be small between the Satsunai pumice bed and the Noboribetsu formation below it. (J.P.N.)

  9. Possible Use of Diatomite and Pumice-Amended Mortar and Plaster in Agricultural Structures

    Directory of Open Access Journals (Sweden)

    Serkan Yazarel


    Full Text Available This study was conducted to investigate the potential use of diatomite (a natural pozzolana and pumice in plasters and mortars to be used in agricultural buildings. Compacted and loose unit weights, specific weight, water absorption, organic matter content, abrasion resistance of aggregate (sand and pumice and pozzolana were investigated and materials were found to comply with the relevant standards. Test results on fresh (unit weight and slum test and hardened (unit weight, capillary water absorption, total water absorption, bending and compressive strength, vapor diffusion test mortar samples revealed that pumice and diatomite could be used in agricultural structures. Diatomite and pumice should be heat-treated and grounded before to use in mortars. In plasters to be made with abundant pumice and diatomite sources, high water holding capacity of the materials should be taken into consideration and further researches should be carried out about their compliance with the other materials.

  10. Morphology and petrography of pumice from the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.; Karisiddaiah, S.M.

    Majority of pumice are equant with high Corey's shape factor values. Petrographic studies indicate flow bands of isotropic nature, with varied vesicle shape and size, and the diffractograms show them to be mainly composed of amorphous silica...

  11. The origin of ferro-manganese oxide coated pumice from the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Pattan, J.N.; Pearce, N.J.G.; Parthiban, G.; Smith, V.C.; Mudholkar, A.V.; Rao, N.R

    Pumice clasts, partially and fully coated with ferro-manganese oxide from the Central Indian Ocean Basin (CIOB) were analysed for major, trace and rare earth elements; and glass and mineral grain chemistry to assess their possible source...

  12. Hydrothermal signature in ferromanganese oxide coatings on pumice from the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Kalangutkar, N.G.; Iyer, S.D.; Mascarenhas-Pereira, M.B.L.; Nath, B.N.

    Mineralogical and elemental analyses of 20 ferromanganese (FeMn)-coated pumice samples from the Central Indian Ocean Basin (CIOB) indicate that todorokite is the major mineral phase, whereas vernadite occurs only rarely. Based on major, trace...

  13. Heterogeneous vesiculation of 2011 El Hierro xeno-pumice revealed by X-ray computed microtomography (United States)

    Berg, S. E.; Troll, V. R.; Deegan, F. M.; Burchardt, S.; Krumbholz, M.; Mancini, L.; Polacci, M.; Carracedo, J. C.; Soler, V.; Arzilli, F.; Brun, F.


    During the first week of the 2011 El Hierro submarine eruption, abundant light-coloured pumiceous, high-silica volcanic bombs coated in dark basanite were found floating on the sea. The composition of the light-coloured frothy material (`xeno-pumice') is akin to that of sedimentary rocks from the region, but the textures resemble felsic magmatic pumice, leaving their exact mode of formation unclear. To help decipher their origin, we investigated representative El Hierro xeno-pumice samples using X-ray computed microtomography for their internal vesicle shapes, volumes, and bulk porosity, as well as for the spatial arrangement and size distributions of vesicles in three dimensions (3D). We find a wide range of vesicle morphologies, which are especially variable around small fragments of rock contained in the xeno-pumice samples. Notably, these rock fragments are almost exclusively of sedimentary origin, and we therefore interpret them as relicts an the original sedimentary ocean crust protolith(s). The irregular vesiculation textures observed probably resulted from pulsatory release of volatiles from multiple sources during xeno-pumice formation, most likely by successive release of pore water and mineral water during incremental heating and decompression of the sedimentary protoliths.

  14. 'Chemical fingerprints' of pumice from Cappadocia (Turkey) and Kos (Greece) for archaeological applications

    International Nuclear Information System (INIS)

    Steinhauser, Georg; Sterba, Johannes H.; Bichler, Max


    Pumice has been used as a serviceable abrasive or religious artefact since antiquity and has therefore been an object of trade. It can be found in excavations of ancient workshops all over the Mediterranean. Pumice lumps from the major pumice-bearing rhyolitic tephra units in Cappadocia-the Central Anatolian Volcanic Province, Turkey (in particular the ignimbrites Kavak, Cemilkoey, Tahar, Goerdeles, and the volcanic complexes of Acigoel and Hasan Dagi), were sampled and analyzed for major and trace element concentrations using instrumental neutron activation analysis (INAA). Elements determined were Na, K, Sc, Cr, Fe, Co, Zn, As, Rb, Zr, Sb, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, Lu, Hf, Ta, Th, and U. Since the distribution of those elements is characteristic of the products of a certain eruption, this 'chemical fingerprint' can be used to establish the origin of an unknown pumice sample by comparison with samples of known origin. In the course of this study, it could be shown that one pumice finding from the excavation in Miletos (Turkey) probably originates from the Hasan Dagi volcanic complex in Cappadocia. Since it is known that the population in Miletos focused their trade connections on the Mediterranean, this result is somewhat surprising. Two other samples from Miletos show a very high similarity to the chemical fingerprint of pumice from the Kos Plateau Tuff (KPT; Greece): In one case, the identification is doubtless, in the other case identification as KPT seems quite probable

  15. The durability of fired brick incorporating textile factory waste ash and basaltic pumice

    Energy Technology Data Exchange (ETDEWEB)

    Binici, Hanifi [Kahramanmaras Sutcu Imam Univ., Kahramanmaras (Turkey). Dept. of Civil Engineering; Yardim, Yavuz [Epoka Univ., Tirana (Albania). Dept. of Civil Engineering


    This study investigates the durability of fired brick produced with additives of textile factories' waste ash and basaltic pumice. The effects of incorporating waste ash and basaltic pumice on durability and mechanical properties of the clay bricks were studied. Samples were produced with different ratios of the textile factories' waste ash and basaltic pumice added and at different fire temperatures of 700, 900, and 1 050 C for 8 h. The bricks with additives were produced by adding equal amounts of textile factories' waste ash and basaltic pumice, separately and together, with rates of 5, 10 and 20 wt.%. The produced samples were kept one year in sodium sulphate and sodium nitrate and tested under freezing - unfreezing and drying - wetting conditions. Then compression strength and mass loss of the samples with and without additives were investigated. The test results were compared with standards and results obtained from control specimens. The results showed that incorporations up to 10 wt.% of textile factories' waste ash and basaltic pumice is beneficial to the fired brick. Both textile factories' waste ash and basaltic pumice were suitable additives and could be used for more durable clay brick production at 900 C fire temperature. (orig.)

  16. Pyrolysis of plastic waste using alumina-pumice as catalyst

    International Nuclear Information System (INIS)

    Warnijati, S.; Agra, I.B.; Wibowo, W.


    Efforts to convert plastic waste to liquid fuel have been carried out, but the yield was not so promising yet. Various catalysts have been studied to drive the product more to the liquid fuel. In this study, alumina-pumice produced from cheap local materials, was used as catalyst. Solid polyethylene plastic waste was melted in a feed compartment surrounding the tube reactor, and the vapor flowed downward through the catalyst bed which was supported by small glass marbles. Air and water coolers were used to cool and condense the product. Liquid and uncondensable gas were collected in receivers and bottle filled with brine, respectively. The physical properties of a specific liquid product were tested according to the ASTM methods. Liquid and gas products increased with time and temperature, and the rate of liquid and gas formations followed first order reaction. Using 100 g of plastic waste and 40 g of catalyst, the favorable time and temperature of pyrolysis were 105 minutes and 653-673 K, respectively. Under this condition, 86 - 87 % of liquid, 45 - 53 mL/g of gas, and 1% of solid residue were obtained. The quantity of liquid product was higher than the previous work (which was just 70-75 %) and its physical properties were between those of kerosene and diesel oil. The gross heating value of the liquid was 49 796.03 J/g, and the gas burnt with yellow flame and some soot. (Author)

  17. Fabrication of naturel pumice/hydroxyapatite composite for biomedical engineering. (United States)

    Komur, Baran; Lohse, Tim; Can, Hatice Merve; Khalilova, Gulnar; Geçimli, Zeynep Nur; Aydoğdu, Mehmet Onur; Kalkandelen, Cevriye; Stan, George E; Sahin, Yesim Muge; Sengil, Ahmed Zeki; Suleymanoglu, Mediha; Kuruca, Serap Erdem; Oktar, Faik Nuzhet; Salman, Serdar; Ekren, Nazmi; Ficai, Anton; Gunduz, Oguzhan


    We evaluated the Bovine hydroxyapatite (BHA) structure. BHA powder was admixed with 5 and 10 wt% natural pumice (NP). Compression strength, Vickers micro hardness, Fourier transform infrared spectroscopy, scanning electron microscopy (SEM) and X-ray diffraction studies were performed on the final NP-BHA composite products. The cells proliferation was investigated by MTT assay and SEM. Furthermore, the antimicrobial activity of NP-BHA samples was interrogated. Variances in the sintering temperature (for 5 wt% NP composites) between 1000 and 1300 °C, reveal about 700 % increase in the microhardness (~100 and 775 HV, respectively). Composites prepared at 1300 °C demonstrate the greatest compression strength with comparable result for 5 wt% NP content (87 MPa), which are significantly better than those for 10 wt% and those that do not include any NP (below 60 MPa, respectively). The results suggested the optimal parameters for the preparation of NP-BHA composites with increased mechanical properties and biocompatibility. Changes in micro-hardness and compression strength can be tailored by the tuning the NP concentration and sintering temperature. NP-BHA composites have demonstrated a remarkable potential for biomedical engineering applications such as bone graft and implant.

  18. Origin and significance of the 2011 El Hierro xeno-pumice (United States)

    Zaczek-Pedroza, Kirsten; Troll, Valentin R.; Deegan, Frances M.; Meade, Fiona C.; Burchardt, Steffi; Carracedo, Juan C.; Klügel, Andreas; Harris, Chris; Wiesmaier, Sebastian; Berg, Sylvia E.; Barker, Abigail K.


    During the first week of the 2011/2012 submarine eruption off El Hierro (Canary Islands), peculiar light-coloured pumiceous rocks (xeno-pumice) were found floating on the sea. The appearance of these rocks led to a potentially inappropriate response from the authorities, because the rocks were viewed as likely indicators of high-silica magma and possible explosive eruptive behaviour. However, the eruption remained a relatively minor and dominantly effusive event and the origin and significance of these peculiar xeno-pumice rocks for volcanic monitoring remains unresolved. Three contrasting models have been put forward, describing them as: a) recycled hydrothermally altered felsic magmatic rocks (Meletlidis et al., 2012, Geophys. Res. Lett., 39:L17302), b) sediment-contaminated high-silica magma (Sigmarsson et al., 2013, Contrib. Mineral. Petrol., 165:601-622) or c) frothy xenoliths from pre-island sedimentary strata that were melted while immersed in magma (Troll et al., 2012, Solid Earth, 3:97-110). Here, we combine the three available datasets to assess the origin of El Hierro xeno-pumice in the light of texture, mineralogy, major and trace element composition, and oxygen isotope characteristics in order to discuss their significance. We note that: 1) Sedimentary relicts occur frequently in xeno-pumice samples with occasionally observed relict bedding. 2) Vesicle sizes are extremely variable, which documents multiple degassing events. The vesicles are biggest especially close to sedimentary relicts, likely the result of a complex mix of minerals and porewaters originally present. 3) The mineral assemblage of xeno-pumice includes quartz, smectite, illite, wollastonite, jasper and mica (XRD) and is akin to marine sedimentary rocks in the region (Hoernle, 1998, J. Petrol.,39:859-880; Robertson & Stillman, 1979, J. Geol. Soc., 136:47 -60; Aparicio et al., 2006, Geol. Mag. 143:181 -193). 4) CIPW norms calculated from xeno-pumice major element compositions show the

  19. Age and area predict patterns of species richness in pumice rafts contingent on oceanic climatic zone encountered. (United States)

    Velasquez, Eleanor; Bryan, Scott E; Ekins, Merrick; Cook, Alex G; Hurrey, Lucy; Firn, Jennifer


    The theory of island biogeography predicts that area and age explain species richness patterns (or alpha diversity) in insular habitats. Using a unique natural phenomenon, pumice rafting, we measured the influence of area, age, and oceanic climate on patterns of species richness. Pumice rafts are formed simultaneously when submarine volcanoes erupt, the pumice clasts breakup irregularly, forming irregularly shaped pumice stones which while floating through the ocean are colonized by marine biota. We analyze two eruption events and more than 5,000 pumice clasts collected from 29 sites and three climatic zones. Overall, the older and larger pumice clasts held more species. Pumice clasts arriving in tropical and subtropical climates showed this same trend, where in temperate locations species richness (alpha diversity) increased with area but decreased with age. Beta diversity analysis of the communities forming on pumice clasts that arrived in different climatic zones showed that tropical and subtropical clasts transported similar communities, while species composition on temperate clasts differed significantly from both tropical and subtropical arrivals. Using these thousands of insular habitats, we find strong evidence that area and age but also climatic conditions predict the fundamental dynamics of species richness colonizing pumice clasts.

  20. Fission-track dating of pumice from the KBS Tuff, East Rudolf, Kenya (United States)

    Hurford, A.J.; Gleadow, A.J.W.; Naeser, C.W.


    Fission-track dating of zircon separated from two pumice samples from the KBS Tuff in the Koobi Fora Formation, in Area 131, East Rudolf, Kenya, gives an age of 2.44??0.08 Myr for the eruption of the pumice. This result is compatible with the previously published K-Ar and 40Ar/ 39Ar age spectrum estimate of 2.61??0.26 Myr for the KBS Tuff in Area 105, but differs from the more recently published K-Ar date of 1.82??0.04 Myr for the KBS Tuff in Area 131. This study does not support the suggestion that pumice cobbles of different ages occur in the KBS Tuff. ?? 1976 Nature Publishing Group.

  1. Neutron activation analysis of pumice from Lipari, Italy, and the identification of a pumice find from the excavation at Tel Megadim, Israel

    International Nuclear Information System (INIS)

    Steinhauser, G.; Bichler, M.; Eigelsreiter, G.; Tischner, A.


    Sixteen pumice samples produced by the youngest eruption sequences of Mt. Pelato (Island of Lipari, Italy) were analyzed with instrumental neutron activation analysis (INAA) for their major and trace element contents, in particular Al, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sm, Ta, Tb, Th, Ti, U, V, Yb, Zn, and Zr. A pumice from the archaeological excavation in Tel Megadim, Israel, could be correlated to this volcanic source, using its chemical fingerprint. This result, together with the background information about the well dated eruption cycles of this volcano, lead to the assumption that trade connections existed between cultures in Palestine and the Tyrrhenian region during the Persian Period (approx. between the 6th and 3rd century B.C.), in spite of the long distance of over 2000 km. (author)

  2. 76 FR 69700 - Klamath National Forest; California; Pumice Vegetation Management Project (United States)


    ... Management Project AGENCY: Forest Service, USDA. ACTION: Notice of intent to prepare an environmental impact.... Grantham, Forest Supervisor, Attn: Ben Haupt, Pumice Vegetation Management Project Team Leader, Goosenest... Management Project will recommend implementation of one of the following: (1) The proposed action; (2) an...

  3. Physical properties, morphology and petrological characteristics of pumices from the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Kalangutkar, N.G.; Iyer, S.D.; Ilangovan, D.

    About 400 pumice clasts collected from the Central Indian Ocean Basin (CIOB) were studied for their morphology and classified based on their shape and size. A majority of the samples range between less than 1 cm and 36 cm and in the Zinggs shape...

  4. Wet Oxidation of Maleic Acid by a Pumice Supported Copper (II ...

    African Journals Online (AJOL)

    Pumice supported Cu (II) Schiff base catalysts were prepared by surface chemical modification followed by complexation with Cu (II) acetate. The resulting materials were characterised by Diffuse Reflectance Fourier Transform Spectroscopy (DRIFTS) to confirm the modification. The materials were tested in a wet oxidation ...

  5. Measurement of water transport from saturated pumice aggregates to hardening cement paste

    DEFF Research Database (Denmark)

    Lura, Pietro; Bentz, Dale; Lange, David A.


    In internal water curing of High Performance Concrete, it is fundamental to know how and when the water contained in the internal curing agent is released into the hydrating cement paste. In this study, X-ray absorption measurements showed that considerable transport of water from saturated pumice...... the crucial factor to avoid self-desiccation shrinkage at early-age....

  6. Microleakage assessment of fissure sealant following fissurotomy bur or pumice prophylaxis use before etching

    Directory of Open Access Journals (Sweden)

    Ali Bagherian


    The aim of this investigation was to compare the microleakage level of fissure sealants prepared by a fissurotomy bur or pumice prophylaxis prior to acid etching. Materials and Methods: Ninety freshly extracted healthy maxillary premolar teeth were randomly selected for this investigation. Teeth were then divided into three fissure sealant preparatory groups of A: Fissurotomy bur + acid etch; B: Pumice prophylaxis + acid etch and C: Acid etch alone. Sealant was applied to the occlusal fissures of all specimens using a plastic instrument. This was to avoid any air trap under the sealant. Sample teeth were first thermocycled (1000 cycles, 20 s dwell time and then coated with two layers of nail varnish leaving 2 mm around the sealant. This was then followed by immersion in basic fuchsin 3%. Processed teeth were sectioned longitudinally and examined under a stereomicroscope for microleakage assessment using a score of 0-3. Collected data was then subjected to Kruskall-Wallis Analysis of Variance and Mann-Whitney U-test. P < 0.05 was considered as significant. Results: Teeth in fissurotomy bur and pumice prophylaxis groups had significantly reduced level of microleakage than those in acid etch alone (P = 0.005 and P = 0.003, respectively. Conclusion: Use of fissurotomy bur and pumice prophylaxis accompanied with acid etching appears to have a more successful reduction of microleakage than acid etch alone.

  7. Pesticide behaviour in pumice and rockwool growth media; adsorption and transformation of metalaxyl, oxamyl and carbendazim

    NARCIS (Netherlands)

    Matser, A.M.; Leistra, M.


    Interactions of pesticides with substrates were studied. The adsorption of metalaxyl, oxamyl and carbendazim on unused pumice and rock-wool is much weaker than that on soils. The transformation rate of the pesticides in nutrient solution in contact with unused substrates is low. Metalaxyl is

  8. The pumice raft-forming 2012 Havre submarine eruption was effusive (United States)

    Manga, Michael; Fauria, Kristen E.; Lin, Christina; Mitchell, Samuel J.; Jones, Meghan; Conway, Chris E.; Degruyter, Wim; Hosseini, Behnaz; Carey, Rebecca; Cahalan, Ryan; Houghton, Bruce F.; White, James D. L.; Jutzeler, Martin; Soule, S. Adam; Tani, Kenichiro


    A long-standing conceptual model for deep submarine eruptions is that high hydrostatic pressure hinders degassing and acceleration, and suppresses magma fragmentation. The 2012 submarine rhyolite eruption of Havre volcano in the Kermadec arc provided constraints on critical parameters to quantitatively test these concepts. This eruption produced a >1 km3 raft of floating pumice and a 0.1 km3 field of giant (>1 m) pumice clasts distributed down-current from the vent. We address the mechanism of creating these clasts using a model for magma ascent in a conduit. We use water ingestion experiments to address why some clasts float and others sink. We show that at the eruption depth of 900 m, the melt retained enough dissolved water, and hence had a low enough viscosity, that strain-rates were too low to cause brittle fragmentation in the conduit, despite mass discharge rates similar to Plinian eruptions on land. There was still, however, enough exsolved vapor at the vent depth to make the magma buoyant relative to seawater. Buoyant magma was thus extruded into the ocean where it rose, quenched, and fragmented to produce clasts up to several meters in diameter. We show that these large clasts would have floated to the sea surface within minutes, where air could enter pore space, and the fate of clasts is then controlled by the ability to trap gas within their pore space. We show that clasts from the raft retain enough gas to remain afloat whereas fragments from giant pumice collected from the seafloor ingest more water and sink. The pumice raft and the giant pumice seafloor deposit were thus produced during a clast-generating effusive submarine eruption, where fragmentation occurred above the vent, and the subsequent fate of clasts was controlled by their ability to ingest water.

  9. Retention of phosphorous ions on natural and engineered waste pumice: Characterization, equilibrium, competing ions, regeneration, kinetic, equilibrium and thermodynamic study

    Energy Technology Data Exchange (ETDEWEB)

    Karimaian, Kamal Aldin [Department of Environmental Health Engineering, Faculty of Health, Kurdistan University of Medical Sciences, Sannandaj (Iran, Islamic Republic of); Amrane, Abdeltif [Ecole Nationale Supérieure de Chimie de Rennes, Université Rennes 1, CNRS, UMR 6226, Avenue du Général Leclerc, CS 50837, 35708 Rennes Cedex 7 (France); Kazemian, Hossein [Department of Chemical and Biochemical Engineering, Western University, London, ON, Canada N6A 5B9 (Canada); Panahi, Reza [Department of Biotechnology, Faculty of Chemical Engineering, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Zarrabi, Mansur, E-mail: [Department of Environmental Health Engineering, Faculty of Health, Alborz University of Medical Sciences, Karaj (Iran, Islamic Republic of)


    Natural and Mg{sup 2+} modified pumice were used for the removal of phosphorous. The adsorbents were characterized using XRF, XRD, SEM and FTIR instrumental techniques. In the optimal conditions, namely at equilibrium time (30 min), for a phosphorus concentration of 15 mg/L and pH 6, 69 and 97% phosphorus removals were achieved using 10 g/L of natural and modified pumice adsorbents, respectively. Maximum adsorption capacities were 11.88 and 17.71 mg/g by natural and modified pumice, respectively. Pseudo-second order kinetic model was the most relevant to describe the kinetic of phosphorus adsorption. External mass transfer coefficient decreased for increasing phosphorous concentration and film diffusion was found to be the rate-controlling step. Only a very low dissolution of the adsorbent was observed, leading to a low increase in conductivity and turbidity. Removal efficiency decreased for increasing ionic strength. It also decreased in the presence of competing ions; however modified pumice remained effective, since 67% of phosphorus was removed, versus only 17% for the natural pumice. The efficiency of the modified pumice was confirmed during the regeneration tests, since 96% regeneration yield was obtained after 510 min experiment, while only 22% was observed for the raw pumice.

  10. Spectroscopic analysis of Ahlat stone (ignimbrite) and pumice formed by volcanic activity. (United States)

    Aygun, Z; Aygun, M


    Natural materials such as ignimbrites are preferred commonly not only in historical places but also in houses or in different kind of buildings all over the world especially around Ahlat in Bitlis-Turkey. Durability, lightness and good-insulation are the significative properties of these stones. Also, pumice is an another preferred material because of its advantages in construction industry. In this paper, four kinds of ignimbrite (light-yellow, yellow, black and white) and pumice from Ahlat region have been investigated by EPR method to determine magnetic properties of them. The results obtained by EPR, EDS and XRD methods are evaluated together. SEM technique is also used to understand the surface morphology of the samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  11. Evaluation and comparison of aluminum-coated pumice and zeolite in arsenic removal from water resources

    Directory of Open Access Journals (Sweden)

    Heidari Masoumeh


    Full Text Available Abstract In this research the potential of aluminum-coated pumice and zeolite in arsenic, As (V removal was investigated and compared. Scanning Electron Microscopy (SEM, X-Ray Diffraction (XRD and X-Ray Flaorescence Spectrometry (XRF were carried out to determine the properties of the adsorbents. Several parameters including adsorbent dosage] pH, contact time, and initial As(V concentration were studied. The optimum pH obtained for both adsorbents was pH = 7. As(V adsorption by both adsorbents followed the Freundlich isotherm (for aluminum-coated pumice and zeolite respectively with R2 > 0.98 and R2 > 0.99. The obtained data from kinetics showed that the pseudo-second order model could better explain As(V adsorption for both aluminum-coated pumice and zeolite (R2 > 0.98 and R2 > 0.99 respectively. Because of low cost, both adsorbents may be economically used, but aluminum-coated zeolite showed high efficiency of, due to its porosity and surface area. More than 96% of As(V with initial concentration of 250 μg/L was removed by 10 g/L aluminum-coated zeolite at pH = 7 and in 60 minutes to achieve As(V concentration of 10 μg/L, while only 71% of As(V could be removed by aluminum-coated pumice.

  12. Natural radioactivity measurement in pumice samples used raw materials in Turkey

    International Nuclear Information System (INIS)

    Turhan, S.; Yuecel, H.; Guenduez, L.; Sahin, S.; Vural, M.; Parmaksiz, A.; Demircioglu, B.


    The activity concentrations of 232 Th, 226 Ra, and 4 K in different pumice samples have been determined by high-resolution γ-ray spectrometry using a 110% HpGe detector. The radium equivalent activities (Ra eq ), external hazard index (H ex ), and internal hazard index (H in ) associated with the natural radionuclides and representative level index (I γ r ) are calculated to assess the radiation hazard of the natural radioactivity in the pumice samples. The mean values of the measured radioactivity concentrations of 232 Th, 226 Ra, and 4 K for pumice samples from the region of lakes (ROL) are 232.4±8.0, 196.9±7.8, and 1325.8±20.4 Bq kg -1 and for pumice samples from Cukurova region (CR) 16.3±4.0, 16.1±4.9, and 479.7±170.4 Bq kg -1 , respectively. The calculated Ra eq values vary from 435.9±12.5 to 883.6±41.5 Bq kg -1 with a mean of 630.9±20.2 Bq kg -1 for the ROL samples and from 49.7±3.3 to 101.9±7.2 Bq kg -1 with a mean of 76.3±23.7 Bq kg -1 for the CR samples. For the ROL samples, Ra eq are above the limit of 370 Bq kg -1 , equivalent to external γ dose of 1.5 mSv yr -1 , recommended for the safe use of construction materials by NEA-OECD, while for the CR samples, Ra eq values are lower than the limit

  13. Isotopic Characteristics and Age Dating of the Pumice in Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    陈丽蓉; 翟世奎; 申顺喜


    The data on the isotope compositions of rubidium,strontium and oxygen in the pumice ofOkinawa Trough are reported for the first time.The ages of the pumice were successfully dated with themethod of U-series disequilibrium.Then,the material source,crystallization evolution of magma and activi-ty cycles of volcanos are explored.Isotopic data show that pumice magma was originally from the mantle,but had undergone a full crystal-lization differentiation and had been contaminated to a fair extent by crust-derived materials before the mag-ma was erupted out of the sea floor.According to the dating results available so far,the earliest volcaniceruption in Okinawa Trough occurred about 70,000 a ago and the latest eruption was about 10,000 a B.P.During this period,there were three volcanic eruption cycles which were respectively corresponding to themiddle Late Pleistocene,the late Late Pleistocene and the Early Holocene.

  14. Comparison of Different Methods of Denim Stone Washing by Pumice Stone, Acid Cellulases and Neutral Cellulases

    Directory of Open Access Journals (Sweden)

    M. Montazer


    Full Text Available Denim is a casual garment normally used by young people and extremely influential in shaping the fashion industry. Among various garments, these garments are subjected to innovations. This work is an attempt to compare the different methods of stone washing using pumice stones, acid cellulases and neutral cellulases or in combination of these methods. The effects of different processing conditions on the garment are compared and reported. Color differences of samples are probed by reflective colorimeter on the front side as well as the backside and also the white pocket of the garment.The abrasion resistance, tensile strength and crease recovery angle of samples are also reported. The XRD spectra are used to calculate the crystalline degrees of the selected samples. Moreover, fiber surfaces of some treated samples have been observed by SEM. The results indicate that treatment of denim with pumice stone with equal weight of garment causes a small color differences. The addition of cellulases to the washing, however, accelerates the color fading. Also, lower staining observed on the white pocket when the garment was treated with cellulases. However, the neutralcellulases increase the garment fading and decrease the staining on the white pocket. It is also observed that pumice stone with cellulases damages the fabric surface, although it is of a minimal damage.

  15. Crystallization Stages of the Bishop Tuff Magma Body Recorded in Crystal Textures in Pumice Clasts

    Energy Technology Data Exchange (ETDEWEB)

    Pamukcu, Ayla; Gualda, Guilherme A.R.; Anderson, Jr. , Alfred T. (Vanderbilt); (UC)


    The Bishop Tuff is a giant silicic ignimbrite erupted at 0.76 Ma in eastern California, USA. Five pumice clasts from the late-erupted Bishop Tuff (Aeolian Buttes) were studied in an effort to better understand the pre- and syn-eruptive history of the Bishop magma body and place constraints on the timescales of its existence. This study complements and expands on a previous study that focused on early-erupted Bishop Tuff pumice clasts. Bulk densities of pumice clasts were measured using an immersion method, and phenocryst crystal contents were determined using a sieving and winnowing procedure. X-ray tomography was used to obtain qualitative and quantitative textural information, particularly crystal size distributions (CSDs). We have determined CSDs for crystals ranging in size from {approx}10 to {approx}1000 {micro}m for three groups of mineral phases: magnetite ({+-}ilmenite), pyroxene + biotite, quartz + feldspar. Similar to early-erupted pumice, late-erupted pumice bulk density and crystal contents are positively correlated, and comparison of crystal fraction vs size trends suggests that the proportion of large crystals is the primary control on crystallinity. Porosity is negatively correlated with crystal content, which is difficult to reconcile with closed-system crystallization. Magnetite and pyroxene + biotite size distributions are fractal in nature, often attributed to fragmentation; however, crystals are mostly whole and euhedral, such that an alternative mechanism is necessary to explain these distributions. Quartz + feldspar size distributions are kinked, with a shallow-sloped log-linear section describing large crystals (> 140 {micro}m) and a steep-sloped log-linear section describing small crystals (< 140 {micro}m). We interpret these two crystal populations as resulting from a shift in crystallization regime. We suggest that the shallow-sloped section describes a pre-eruptive quartz + feldspar growth-dominated regime, whereas the steep

  16. Adsorption and transport of cadmium and rhodamine WT in pumice sand columns

    International Nuclear Information System (INIS)

    Pang, L.; Close, M.; Greenfield, H.; Stanton, G.


    The transport and attenuation of cadmium (Cd) and rhodamine WT (RWT) in a pumice sand aquifer media was investigated using column experiments to study a scenario of point-source contamination. A pore-water velocity of 1.7-1.8 m/day, which is a typical field groundwater velocity in a pumice sand aquifer system, was applied to triplicate columns. A pulse of a solution containing Cd and RWT, together with the conservative tracer tritiated water ( 3 H 2 O) at pH = 7, was introduced into the columns. Experimental results showed that concentration breakthrough curves (BTCs) of 3 H 2 O were symmetrical and fitted well into an equilibrium model. In contrast, BTCs of Cd and RWT were asymmetrical with significant tailings and fitted well with a two-site adsorption/desorption model. The symmetric 3 H 2 O BTCs suggest that physical non-equilibrium was absent in the experimental system, therefore the asymmetrical BTCs of Cd and RWT were attributed to chemical non-equilibrium. Modelling results showed that, in comparison with 3 H 2 O, Cd was apparently retarded by 101-108 times in pumice sand aquifer media (apparent adsorption coefficient 7.33-9.24 ml/g) and underwent a mass loss of 20-30% that was probably because of precipitation of CdCO 3 . As CdCO 3 is extremely insoluble, Cd precipitation would be irreversible and therefore it would not contribute to the tailing of the Cd BTCs. The experimental results suggest that the adsorption and desorption of Cd in pumice sand aquifer media in hydrodynamic conditions was a kinetic process. Cd desorption rates were two orders-of-magnitude slower than its adsorption rates. This resulted in a prolonged mean residence time for Cd in pumice sand aquifer media, which was 10-12 days in the 18-cm-long columns under a flow velocity of 1.7-1.8 m/day. Since the mean residence time is only indicative for the arrival of the central of mass in a contaminant BTC, the time required for the total disappearance of Cd will be much longer than the mean

  17. Evaluation of Iron and Manganese-Coated Pumice Application for the Removal of as(v from Aqueous Solutions

    Directory of Open Access Journals (Sweden)

    Leila Babaie Far


    Full Text Available Arsenic contamination of water has been recognized as a serious environmental issue and there are reports on its epidemiological problems to human health. The objective of this study was to evaluate the performances of iron-coated pumice and manganese-coated pumice as the adsorbents for removing arsenate from aqueous solutions. The effect of various parameters such as adsorbent dose, contact time, pH and initial concentration on removal efficiency of arsenate were evaluated in batch mode. The data obtained from the kinetic studies were analyzed using kinetic models of pseudo-first-order and pseudo-second-order. In addition, two isotherm models of Freundlich and Langmuir were used to fit the experimental data. The results showed that the optimum dosage of iron-coated pumice and manganese-coated pumice for arsenate removal were 40 and 80 g/L whereas the adsorption process reached equilibrium after 80 and 100 min, respectively. The maximum removal efficiency of arsenate using the two adsorbents were both recorded in pH=3 as the removal efficiency gradually declinedfollowing every increase in pH values of the solution. Iron-coated pumice also showed to have high removal efficiency when the initial concentration of arsenate was high while the low concentration of arsenate was efficiently removed by manganese-coated pumice. Moreover, it was depicted that the adsorption kinetics by bothadsorbents followed pseudo-second order equation and the uptake data of arsenate were well fitted with Langmuir isotherm model. Therefore, it could be concluded that iron and manganese-coated pumice could beconsidered as suitable adsorbents for arsenate removal from aqueous solutions.

  18. Long-term operational studies of lab-scale pumice-woodchip packed stormwater biofilters. (United States)

    Cheng, Jing; Yuan, Qingke; Kim, Youngchul


    The performance of three pumice-woodchip packed stormwater biofilter (PWSWBF) systems with three packing volume ratios of pumice to woodchip (1:2, 1:1 and 2:1) were compared. The results show that the PWSWBF system packed with a lower percentage of woodchip attained a higher removal efficiency of TCOD, TN, NH 4 -N and TP, whereas all three systems completely removed nitrate. The highest removal efficiencies for TCOD, TN, NH 4 -N, NO 3 -N and TP were 95%, 70%, 86%, 100% and 100%, respectively. In the biofilter with a lower percentage of woodchip, the pollutants that get removed through aerobic biological processes were removed more significantly, which is attributed to less oxygen depletion via woodchip decomposition, which is common under wet conditions. Nitrate was significantly removed via denitrification in all three systems, indicating that the woodchip that occupied one-third of the main media was sufficient for denitrification, and also that the oxygen condition inside the column was proper for denitrification to proceed. A smaller amount of woodchip as the packing material also mitigated the adverse effect of the release of organics from the media during the initial period. In addition, the system showed very good buffering capacity, in that the outflow pH was constant within the optimal range for microorganism growth.

  19. Tube pumices as strain markers of the ductile-brittle transition during magma fragmentation (United States)

    Martí, J.; Soriano, C.; Dingwell, D. B.


    Magma fragmentation-the process by which relatively slow-moving magma transforms into a violent gas flow carrying fragments of magma-is the defining feature of explosive volcanism. Yet of all the processes involved in explosively erupting systems, fragmentation is possibly the least understood. Several theoretical and laboratory studies on magma degassing and fragmentation have produced a general picture of the sequence of events leading to the fragmentation of silicic magma. But there remains a debate over whether magma fragmentation is a consequence of the textural evolution of magma to a foamed state where disintegration of walls separating bubbles becomes inevitable due to a foam-collapse criterion, or whether magma is fragmented purely by stresses that exceed its tensile strength. Here we show that tube pumice-where extreme bubble elongation is observed-is a well-preserved magmatic `strain marker' of the stress state immediately before and during fragmentation. Structural elements in the pumice record the evolution of the magma's mechanical response from viscous behaviour (foaming and foam elongation) through the plastic or viscoelastic stage, and finally to brittle behaviour. These observations directly support the hypothesis that fragmentation occurs when magma undergoes a ductile-brittle transition and stresses exceed the magma's tensile strength.

  20. Dye Removal From Textile Waste Water Through The Adsorption By Pumice Used In Stone Washing

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    Körlü Aysegül Ekmekçi


    Full Text Available Because the waste production is inevitable in almost all industries, the elimination of these wastes is a requirement in terms of environmental regulations and welfare of all the creatures in the future. In this study, the use of the waste pumice stones of a denim washing mill is intended to eliminate the pollutant by a waste material and obtain economic benefits by converting it to the adsorbent. The pollutants in the effluents obtained from three different localisations of waste water treatment system of the same factory were removed through the adsorption. The experimental studies were carried out in three different steps; characterisation of adsorbent before and after adsorption; adsorption isotherm studies and biological oxygen demand (BOD, chemical oxygen demand (COD measurements. Characterisation studies showed that the waste pumice has almost the same structural properties with unused one except the existence of some organic residues coming from washing process. The results of adsorption studies conducted at the adsorbent concentrations changing from 5 to 35 g/l revealed that the decolourisation was initial dye-concentration dependent. According to the BOD and COD measurements, the supernatants obtained at the end of adsorption could be assumed as somewhat polluted and this result indicates that the organic impurities other than indigo were also removed through the adsorption.

  1. The Synthesis and Characterization of Low-cost Mesoporous Silica SiO2 from Local Pumice Rock

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    Asmaa Mourhly


    removal of water molecules and the OH of silanol groups contained in the material. The investigations performed in this work have indicated that there is great scope for pumice exploitation as a raw material in the production of amorphous silica nanopowder on large scale.

  2. The 12.1 ka Middle Toluca Pumice: A dacitic Plinian subplinian eruption of Nevado de Toluca in Central Mexico (United States)

    Arce, J. L.; Cervantes, K. E.; Macías, J. L.; Mora, J. C.


    The Nevado de Toluca volcano erupted explosively approximately 12.1 ka ago, producing a Plinian-subplinian eruption that deposited the Middle Toluca Pumice (MTP). The MTP consists of white and gray juvenile pumice, gray dense juvenile lapilli, and red altered lithic lapilli. The pumice is dacitic (63.54-65.06 wt.% SiO 2) with phenocrysts of plagioclase > orthopyroxene > hornblende ± ilmenite and titanomagnetite, and biotite xenocrysts set in a groundmass of rhyolitic glass (70-71 wt.% SiO 2). The MTP has a dispersal axis to the ESE covering an area of 92 km 2, with a minimum volume of 1.8 km 3 (DRE). Stratigraphic relations, grain size, componentry, and vesicularity analyses suggest that the eruption occurred in five major phases: (1) an opening magmatic phase that generated a 20-km-high Plinian column dispersed to the SE; (2) a hydromagmatic explosion followed with the establishment of a subplinian eruptive column (18-19 km high) dispersed tephra to the SE and gradually waned; (3) hydromagmatic explosions emplaced dilute pyroclastic density currents followed by the formation of an eruptive column of unknown height; (4) immediately after, a new magmatic explosion established another eruptive column; and (5) the collapse of the latter column generated two pumiceous pyroclastic density currents that were fully dilute proximally, but transformed into two granular-fluid pyroclastic currents that traveled 19 km from the source.

  3. Tetrachloroethylene Removal Rate from Aqueous Solutions by Pumice Doped with Copper: An Evaluation of the Effect of pH

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    Ali Almasi


    Full Text Available Tetrachloroethylene (TCE is a chlorinated aliphatic hydrocarbon, used in many industries. Effective and efficient treatment of industrial wastewater, containing TCE, is one of the environmental requirements. The purpose of this study was to determine the role of alkaline environments in TCE removal rate from aqueous solutions, using copper-doped pumice. This experimental study was performed, using granulated pumice stones with a mesh 4 (8.4 mm in alkaline conditions; the samples were coated with copper. Copper-doped pumice was prepared as a bed at doses of 1, 2, and 3 g/L; the study was performed at pH ranges of 3, 7, and 11. Based on the results, copper-doped pumice showed good efficacy in TCE removal; in addition, its performance increased in alkaline conditions. Therefore, use of this stone for the treatment of wastewater, containing TCE, is effective due to its availability and low cost. Besides, it can be considered a good option, given its high efficiency in the absorption process.

  4. Opal-A in glassy pumice, acid alteration, and the 1817 phreatomagmatic eruption at Kawah Ijen (Java), Indonesia (United States)

    Lowenstern, Jacob B.; van Hinsberg, Vincent; Berlo, Kim; Liesegang, Moritz; Iacovino, Kayla D.; Bindeman, Ilya N.; Wright, Heather M.


    At Kawah Ijen (Indonesia), vigorous SO2 and HCl degassing sustains a hyperacid lake (pH ~0) and intensely alters the subsurface, producing widespread residual silica and advanced argillic alteration products. In 1817, a VEI 2 phreatomagmatic eruption evacuated the lake, depositing a widespread layer of muddy ash fall, and sending lahars down river drainages. We discovered multiple types of opaline silica in juvenile low-silica dacite pumice and in particles within co-erupted laharic sediments. Most spectacular are opal-replaced phenocrysts of plagioclase and pyroxene adjacent to pristine matrix glass and melt inclusions. Opal-bearing pumice has been found at numerous sites, including where post-eruption infiltration of acid water is unlikely. Through detailed analyses of an initial sampling of 1817 eruption products, we find evidence for multiple origins of opaline materials in pumice and laharic sediments. Evidently, magma encountered acid-altered materials in the subsurface and triggered phreatomagmatic eruptions. Syn-eruptive incorporation of opal-alunite clasts, layered opal, and fragment-filled vesicles of opal and glass, all suggest magma-rock interactions in concert with vesiculation, followed by cooling within minutes. Our experiments at magmatic temperature confirm that the opaline materials would show noticeable degradation in time periods longer than a few tens of minutes. Some glassy laharic sedimentary grains are more andesitic than the main pumice type and may represent older volcanic materials that were altered beneath the lake bottom and were forcefully ejected during the 1817 eruption. A post-eruptive origin remains likely for most of the opal-replaced phenocrysts in pumice. Experiments at 25°C and 100°C reveal that when fresh pumice is bathed in Kawah Ijen hyperacid fluid for 6 weeks, plagioclase is replaced without altering either matrix glass or melt inclusions. Moreover, lack of evidence for high-temperature annealing of the opal suggests

  5. Opal-A in Glassy Pumice, Acid Alteration, and the 1817 Phreatomagmatic Eruption at Kawah Ijen (Java), Indonesia (United States)

    Lowenstern, Jacob B.; van Hinsberg, Vincent; Berlo, Kim; Liesegang, Moritz; Iacovino, Kayla; Bindeman, Ilya N.; Wright, Heather M.


    At Kawah Ijen (Indonesia), vigorous SO2 and HCl degassing sustains a hyperacid lake (pH 0) and intensely alters the subsurface, producing widespread residual silica and advanced argillic alteration products. In 1817, a VEI 2 phreatomagmatic eruption evacuated the lake, depositing a widespread layer of muddy ash fall, and sending lahars down river drainages. We discovered multiple types of opaline silica in juvenile low-silica dacite pumice and in particles within co-erupted laharic sediments. Most spectacular are opal-replaced phenocrysts of plagioclase and pyroxene adjacent to pristine matrix glass and melt inclusions. Opal-bearing pumice has been found at numerous sites, including where post-eruption infiltration of acid water is unlikely. Through detailed analyses of an initial sampling of 1817 eruption products, we find evidence for multiple origins of opaline materials in pumice and laharic sediments. Evidently, magma encountered acid-altered materials in the subsurface and triggered phreatomagmatic eruptions. Syn-eruptive incorporation of opal-alunite clasts, layered opal, and fragment-filled vesicles of opal and glass, all suggest magma-rock interactions in concert with vesiculation, followed by cooling within minutes. Our experiments at magmatic temperature confirm that the opaline materials would show noticeable degradation in time periods longer than a few tens of minutes. Some glassy laharic sedimentary grains are more andesitic than the main pumice type and may represent older volcanic materials that were altered beneath the lake bottom and were forcefully ejected during the 1817 eruption. A post-eruptive origin remains likely for most of the opal-replaced phenocrysts in pumice. Experiments at 25°C and 100°C reveal that when fresh pumice is bathed in Kawah Ijen hyperacid fluid for six weeks, plagioclase is replaced without altering either matrix glass or melt inclusions. Moreover, lack of evidence for high-temperature annealing of the opal suggests

  6. Inclusion of geopolymers derivate from fly ash and pumice in reinforced concrete (United States)

    Montaño, A. M.; González, C. P.; Castro, D.; Gualdron, G.; Atencio, R.


    This paper presents results of a research project related to the development of alkali-activated geopolymers, synthesized from alumina-silicate minerals (fly ash and pumice) which are added to concrete. Alkali sources used in geopolymer synthesis were sodium hydroxide and sodium silicate solution. New materials were structurally characterized by Infra-Red spectroscopy (IR) and X-Ray Diffraction (XRD). Concretes obtained after geopolymers addition as Portland cement substitutes at 10%, 20% and 30%, were mechanically analysed by compression resistance at 7, 14, 28 and 90 drying days. Results were referred to standard (concrete of Portland cement) allows to know cementitious characteristics of geopolymers are lower than those for standard, but it keeps growing at longer drying time than Portland cement. By Electrochemical Impedance Spectroscopy (EIS) it is found that this new material shows high electrical resistance and have been proved as a protection agent against corrosion in reinforced concrete exhibiting anticorrosive properties higher than those showed by the conventional concrete mixture.

  7. Catalytic Ozonation by Iron Coated Pumice for the Degradation of Natural Organic Matters

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    Alper Alver


    Full Text Available The use of iron-coated pumice (ICP in heterogeneous catalytic ozonation significantly enhanced the removal efficiency of natural organic matters (NOMs in water, due to the synergistic effect of hybrid processes when compared to sole ozonation and adsorption. Multiple characterization analyses (BET, TEM, XRD, DLS, FT-IR, and pHPZC were employed for a systematic investigation of the catalyst surface properties. This analysis indicated that the ICP crystal structure was α-FeOOH, the surface hydroxyl group of ICP was significantly increased after coating, the particle size of ICP was about 200–250 nm, the BET surface area of ICP was about 10.56 m2 g−1, the pHPZC value of ICP was about 7.13, and that enhancement by iron loading was observed in the FT-IR spectra. The contribution of surface adsorption, hydroxyl radicals, and sole ozonation to catalytic ozonation was determined as 21.29%, 66.22%, and 12.49%, respectively. The reaction kinetic analysis with tert-Butyl alcohol (TBA was used as a radical scavenger, confirming that surface ferrous iron loading promoted the role of the hydroxyl radicals. The phosphate was used as an inorganic probe, and significantly inhibited the removal efficiency of catalytic NOM ozonation. This is an indication that the reactions which occur are more dominant in the solution phase.

  8. Anomalously high porosity in subduction inputs to the Nankai Trough (SW Japan) potentially caused by volcanic ash and pumice (United States)

    Huepers, A.; Ikari, M.; Underwood, M.; Kopf, A.


    At convergent margins, the sedimentary section seaward of the trench on the subducting oceanic lithosphere provides the source material for accretionary prisms and eventually becomes the host rock of the plate boundary megathrust. The mechanical properties of the sediments seaward of the subduction zone have therefore a first order control on subduction zone forearc mechanics and hydrogeology. At the Nankai Trough (SW Japan) the majority of sediment approaching the subduction zone is clay-rich. Scientific drilling expeditions in the framework of the Ocean Drilling Program (ODP) and the Integrated Ocean Drilling Program (IODP) have revealed an anomalous zone of high porosity in a major lithologic unit known as the Upper Shikoku Basin facies (USB), which is associated with elevated volcanic ash content and high amounts of silica in the interstitial water. The existence of the high porosity zone has previously been associated with advanced silica cementation, driven by the dual diagenetic transition of opal-A to opal-CT, and opal-CT to quartz. However, temperature estimates from recent drilling expeditions offshore the Kii peninsula reveal different in situ temperatures at the proposed diagenetic boundary in the Shikoku Basin. Furthermore, laboratory measurements using core samples from the USB show that cohesive strength is not elevated in the high porosity zone, suggesting that a process other than cementation may be responsible. The USB sediment is characterized by abundant volcanic ash and pumice, therefore the high porosity zone in the USB may be closely linked to the mechanical behavior of this phase. We conducted consolidation tests in the range 0.1 to 8 MPa effective vertical stress on artificial ash-smectite and pumice-smectite mixtures, as well as intact and remolded natural samples from the IODP Sites C0011 and C0012 to investigate the role of the volcanic constituent on porosity loss with progressive burial. Our results show that both remolded and intact

  9. Juvenile pumice and pyroclastic obsidian reveal the eruptive conditions necessary for the stability of Plinian eruption of rhyolitic magma (United States)

    Giachetti, T.; Shea, T.; Gonnermann, H. M.; McCann, K. A.; Hoxsie, E. C.


    Significant explosive activity generally precedes or coexists with the large effusion of rhyolitic lava (e.g., Mono Craters; Medicine Lake Volcano; Newberry; Chaitén; Cordón Caulle). Such explosive-to-effusive transitions and, ultimately, cessation of activity are commonly explained by the overall waning magma chamber pressure accompanying magma withdrawal, albeit modulated by magma outgassing. The tephra deposits of such explosive-to-effusive eruptions record the character of the transition - abrupt or gradual - as well as potential changes in eruptive conditions, such as magma composition, volatiles content, mass discharge rate, conduit size, magma outgassing. Results will be presented from a detailed study of both the gas-rich (pumice) and gas-poor (obsidian) juvenile pyroclasts produced during the Plinian phase of the 1060 CE Glass Mountain eruption of Medicine Lake Volcano, California. In the proximal deposits, a multitude of pumice-rich sections separated by layers rich in dense clasts suggests a pulsatory behavior of the explosive phase. Density measurements on 2,600 pumices show that the intermediate, most voluminous deposits have a near constant median porosity of 65%. However, rapid increase in porosity to 75-80% is observed at both the bottom and the top of the fallout deposits, suggestive of rapid variations in magma degassing. In contrast, a water content of pyroclastic obsidians of approximately 0.6 wt% does remain constant throughout the eruption, suggesting that the pyroclastic obsidians degassed up to a constant pressure of a few megapascals. Numerical modeling of eruptive magma ascent and degassing is used to provide constraints on eruption conditions.

  10. Effect of the use nickeliferous laterite and pumice as additives in the performance and durability of the Portland cement


    Rueda-Gualdrón, María Carolina; Vega-Nuñez, Karen Milena; Ríos-Reyes, Carlos Alberto


    This work evaluated the pozzolanic behavior of the niqueliferous laterite of Cerromatoso (Córdoba) and the pumice of Cemex (Boyacá), based on the NTC standards for fine aggregates. The mortars were prepared with additions of 2.5%, 5% and 10% as substitutes of type I Portland cement, which tested to extreme environments (high temperatures and chemical attacks with H2SO4 y MgSO4). Results demonstrates how these alternative materials increase or decrease their puzolanic degree, as well as the ef...

  11. Water in melt inclusions from phenocrysts of dacite pumice of the Vetrovoy Isthmus (Iturup Island, Southern Kuriles) (United States)

    Kotov, A. A.; Smirnov, S. Z.; Maksimovich, I. A.; Plechov, P. Yu; Chertkova, N. V.; Befus, A. I.


    This work is devoted to the study of one of the largest caldera eruptions of the Kurile-Kamchatka island-arc system that occurred on the island of Iturup. The object of investigation of this work are phenocrysts of quartz and plagioclase from dacite pumice of the Isthmus of the Isthmus, which is located on the island of Iturup. The purpose of this work is to determine the water content in the melts that participated in the caldera eruption of the Vetrovoy Isthmus and the patterns of their changes during the crystallization of magma. In the course of the work, the following were carried out: 1) adaptation and calibration of the Raman spectroscopy method for determining water in rhyolite melt’s inclusions glasses in quartz and plagioclase from pumice stone; 2) determination of composition and estimation of water content in melt inclusions in quartz and plagioclase according to x-ray spectral analysis; 3) establishment of the regularities of the change in the water content during the evolution of the magmatic melt; 4) evaluation of fluid pressure by comparison with experimental data

  12. Removal of Arsenic (V) from Aqueous Solutions Using Chitosan-Red Scoria and Chitosan-Pumice Blends. (United States)

    Asere, Tsegaye Girma; Mincke, Stein; De Clercq, Jeriffa; Verbeken, Kim; Tessema, Dejene A; Fufa, Fekadu; Stevens, Christian V; Du Laing, Gijs


    In different regions across the globe, elevated arsenic contents in the groundwater constitute a major health problem. In this work, a biopolymer chitosan has been blended with volcanic rocks (red scoria and pumice) for arsenic (V) removal. The effect of three blending ratios of chitosan and volcanic rocks (1:2, 1:5 and 1:10) on arsenic removal has been studied. The optimal blending ratio was 1:5 (chitosan: volcanic rocks) with maximum adsorption capacity of 0.72 mg/g and 0.71 mg/g for chitosan: red scoria (Ch-Rs) and chitosan: pumice (Ch-Pu), respectively. The experimental adsorption data fitted well a Langmuir isotherm ( R ² > 0.99) and followed pseudo-second-order kinetics. The high stability of the materials and their high arsenic (V) removal efficiency (~93%) in a wide pH range (4 to 10) are useful for real field applications. Moreover, the blends could be regenerated using 0.05 M NaOH and used for several cycles without losing their original arsenic removal efficiency. The results of the study demonstrate that chitosan-volcanic rock blends should be further explored as a potential sustainable solution for removal of arsenic (V) from water.

  13. Nuclear magnetic resonance analysis of freeze-thaw damage in natural pumice concrete

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    Wang, Xiaoxiao


    Full Text Available This paper presents an analysis of the damage propagation features of the pore structure of natural pumice lightweight aggregate concrete (LWC under freeze-thaw cyclic action. After freeze-thaw cycling, we conducted nuclear magnetic resonance (NMR tests on the concrete and acquired the porosity, distribution of transverse relaxation time T2, and magnetic resonance imaging (MRI results. The results showed the following. The T2 distribution of the LWC prior to freeze-thaw cycling presented four peaks representative of a preponderance of small pores. After 50, 100, 150, and 200 freeze-thaw cycles, the total area of the T2 spectrum and the porosity increased significantly. The MRI presented the changing spatial distribution of pores within the LWC during freeze-thaw cycling. Ultrasonic testing technology was applied simultaneously to analyze the NMR results, which verified that the new NMR technology demonstrated high accuracy and practicability for research regarding freeze-thaw concrete damage.En este trabajo se analiza la propagación de los daños que se producen en la estructura porosa de hormigón aligerado a base de piedra pómez natural sometido a la acción cíclica de hielo-deshielo. Después de realizarse los ensayos de hielo-deshielo, el hormigón se analizó mediante resonancia magnética nuclear (RMN, determinándose la porosidad y la distribución del tiempo de relajación transversal, T2, y registrándose las imágenes captadas por resonancia magnética. De acuerdo con los resultados obtenidos, antes de los ciclos de hielo-deshielo la distribución de T2 del hormigón aligerado presentaba cuatro picos, indicativos de un predominio de poros pequeños. Después de que se sometiera a 50, 100, 150, y 200 ciclos, se observó un aumento importante tanto de la porosidad como de la superficie total del espectro de T2. Las imágenes captadas por resonancia magnética evidenciaron la modificación de la distribución espacial de los poros del

  14. Glucoamylase biosynthesis by cells of Aspergillus niger C sub 58-III immobilized in sintered glass and pumice stones

    Energy Technology Data Exchange (ETDEWEB)

    Fiedurek, J.; Lobarzewski, J. (Uniwersytet Marii Curie-Sklodowskiej, Lublin (Poland). Inst. Mikrobiologii i Biochemii)


    A simple method of A. niger C{sub 58-III} cell immobilization is described. This strain produces extracellular glucoamylase. According to the proposed method A. niger spores were first immobilized by adsorption in sintered glass Rasching rings (RR) or pumice stones (PS). Growing out from spores, A. niger cells produced extracellular glucoamylase. This technique facilitates the culture growth in a filamentous spongy structure of the supports with a continuous accumulation of biomass. After every 24 h it was possible to obtain culture liquid rich in glucoamylase. This procedure can be repeated 30 times using the same sample of immobilized A. niger culture without any loss of glucoamylase activity in the liquid medium. In a 96 h period immobilized A. niger cells produced 300 units . ml{sup -1} whereas a shake culture of this fungus produced only 186 units . ml{sup -1}. (orig.).

  15. Experimental analysis of energy absorption behaviour of Al-tube filled with pumice lightweight concrete under axial loading condition (United States)

    Rajak, D. K.; Deshpande, P. G.; Kumaraswamidhas, L. A.


    This Paper aimed at experimental investigation of compressive behaviour of square tube filled with pumice lightweight concrete (PLC). Square section of 20×20×30 mm is investigated, which is the backbone structure. The compression deformation result shows the better folding mechanism, displacement value, and energy absorption. PLC concrete filled with aluminium thin-wall tubes has been revealed superior energy absorption capacity (EAC) under low strain rate at room temperature. Superior EAC resulted as a result of mutual deformation benefit between aluminium section and PLC is also analysed. PLC was characterised by Fourier Transform Infrared (FTIR) and Field Emission Scanning Electron Microscopy (FESEM), and Energy Dispersive X-ray Spectrometry (EDX) analysis for better understanding of material behaviour. Individual and comparative load bearing graphs is logged for better prospective of analysing. Novel approach aimed at validation of porous lightweight concrete for better lightweight EA filler material.

  16. CT patterns of pleuro-pulmonary damage caused by inhalation of pumice as a model of pneumoconiosis from non-fibrous amorphous silicates. (United States)

    Costa, Chiara; Ascenti, Giorgio; Scribano, Emanuele; D'Angelo, Tommaso; Gaeta, Michele; Fenga, Concettina; Blandino, Alfredo; Mazziotti, Silvio


    The aim of this article is to correlate the radiological features of pleuro-pulmonary damage caused by inhalation of pumice (an extrusive volcanic rock classified as a non-fibrous, amorphous, complex silicate) with exposure conditions. 36 subjects employed in the pumice quarries were evaluated for annual follow-up in a preventive medical surveillance program including spirometry, chest CT lasting from 1999 to 2014. They were only male subjects, mean age 56.92 ± 16.45 years. Subjects had worked in the quarries for an average of 25.03 ± 9.39 years. Domestic or occupational exposure to asbestos or other mineral dusts other than pumice was excluded. Subjects were also classified as smokers, former smokers and nonsmokers. Among the 36 workers examined, we identified four CT patterns which resulted to be dependent on exposure duration and intensity, FVC, FEV1 and FEF25-75, but not on cigarette smoking. The most common symptoms reported by clinical examination were dyspnoea, cough and asthenia. In no case it was proven an evolution of CT findings during follow-up for 10 years. Liparitosis, caused by pumice inhalation, can be considered a representative example of pneumoconiosis derived by amorphous silica compounds, which are extremely widespread for industrial manufacturing as well as for applicative uses, such as nano-materials. Moreover, being pumice free of quartz contamination, it can represent a disease model for exposure to pure non-fibrous silicates.

  17. Stratigraphy, distribution, and evidence for mafic triggering of the ca. 8.5 ka Driftwood Pumice eruption, Makushin Volcano, Alaska, U.S.A (United States)

    Lerner, Allan H.; Crowley, Peter D.; Nicolaysen, Kirsten P.; Hazlett, Richard W.


    Makushin Volcano on Unalaska Island, Alaska, threatens the Aleutian's largest population centers (Unalaska and Dutch Harbor), yet its eruption mechanisms are poorly known. This study presents a detailed stratigraphic and geochemical investigation of Makushin's most recent highly explosive event: the ca. 8.5 ka Driftwood Pumice eruption. The Driftwood Pumice has measured thicknesses of over 2.5 m, and isopach reconstructions estimate a total deposit volume of 0.3 to 1.6 km3, indicating a VEI 4-5 eruption. Proximal deposits consist of normally-graded, tan, dacitic to andesitic pumice, capped by a thinner dark layer of lower-silica andesitic scoria mixed with abundant lithic fragments. This stratigraphy is interpreted as an initial vent-clearing eruption that strengthened into a climactic ejection of pumice and ash and concluded with vent destabilization and the eruption of somewhat more mafic, gas-poor magma. Within the pumice, geochemical trends, disequilibrium mineral populations, and mineral zonation patterns show evidence of magma mixing between a bulk silicic magma and a mafic melt. Euhedral high-Ca plagioclase (An68-91) and high-Mg olivine (Fo69-77) phenocrysts are in disequilibrium with trachydacitic glass (65-68 wt% SiO2) and more abundant sodic plagioclase (An34-55), indicating the former originally crystallized in a more mafic melt. Tephra whole rock compositions become more mafic upwards through the deposit, ranging from a basal low-silica dacite to an andesite (total range: 60.8-63.3 wt% SiO2). Collectively, these compositional variations suggest magma mixing in the Driftwood Pumice (DWP) magma reservoir, with a systematic increase in the amount of a mafic component (up to 25%) upward through the deposit. Olivine-liquid and liquid-only thermometry indicate the mafic magma intruded at temperatures 140-200 °C hotter than the silicic magma. Diffusion rates calculated for 5-7 μm thick, lower-Mg rims on the olivine phenocrysts (Fo60 rim vs Fo76 bulk) suggest

  18. The Evidence from Inclusions in Pumices for the Direct Degassing of Volatiles from the Magma to the Hydrothermal Fluids in the Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    YU Zenghui; ZHAI Shikui; ZHAO Guangtao


    This article presents the evidence in support of the direct magma degassing as the principal mechanism of volatilesreleasing into the hydrothermal fluids in the Okinawa Trough, as contrasted to the argument for the hydrothermal strippingof volatiles from the volcanic rocks.Laser Raman microprobe and stepped-heating techniques are employed to determine the compositions and contents of thevolatiles in pumices in the middle Okinawa Trough. The results show that the volatiles are similar to the gases in the hy-drothermal fluids and hydrothermal minerals in composition, the mean percent content of each component and variationtrend. This indicates the direct influence of magma degassing on the hydrothermal fluids. In addition, the contents ofvolatiles in pumices are rather low and do not support the hydrothermal stripping as the main mechanism to enrich the fluidswith gases. The results are consistent with the idea that the direct magma degassing is more important than hydrothermalstripping in supplying gases to the hydrothermal fluids in the Okinawa Trough.

  19. AMS radiocarbon dating of wood trunks in the pumiceous deposits of the Kikai-Akahoya eruption in Yakushima Island, SW Japan (United States)

    Okuno, Mitsuru; Nakamura, Toshio; Geshi, Nobuo; Kimura, Katsuhiko; Saito-Kokubu, Yoko; Kobayashi, Tetsuo


    Radiocarbon dating using accelerator mass spectrometry (AMS) was performed on numerous wood trunks from pumiceous deposits along the Nagata, Isso and Miyanoura rivers on the northern side of Yakushima Island, 60 km south of Kyushu Island. The obtained 14C dates were around 6.5 ka BP, which, in combination with the geological characteristics of the pumiceous deposits indicates that these specimens were buried during the Kikai-Akahoya (K-Ah) eruption from the Kikai caldera. However, the fact that they are not charred suggests that the origin of these deposits are not pyroclastic flows. Fourteen taxa (Pinus subgen. Diploxylon, Tsuga, Cryptomeria, Chamaecyparis, Myrica, Castanea, Castanopsis, Quercus subgen. Cyclobalanopsis, Trochodendron, Phellodendron, Lagerstroemia, Rhododendron, Myrsine and Symplocos) were identified through anatomical characteristics. This is the first discovery of forest species on the Yakushima Island before the devastating eruption.

  20. AMS radiocarbon dating of wood trunks in the pumiceous deposits of the Kikai-Akahoya eruption in Yakushima Island, SW Japan

    Energy Technology Data Exchange (ETDEWEB)

    Okuno, Mitsuru, E-mail: [Department of Earth System Science, Faculty of Science, Fukuoka University, 814-0180 Fukuoka (Japan); AIG Collaborative Research Institute for International Study on Eruptive History and Informatics, Fukuoka University, 814-0180 Fukuoka (Japan); Nakamura, Toshio [Center for Chronological Research, Nagoya University, 464-8602 Nagoya (Japan); Geshi, Nobuo [Geological Survey of Japan, National Institute of Advanced Science and Technology, 305-8567 Tsukuba (Japan); Kimura, Katsuhiko [Division of Environment System Management, Faculty of Symbiotic System Science, Fukushima University, 960-1296 Fukushima (Japan); Saito-Kokubu, Yoko [Tono Geoscience Center, Japan Atomic Energy Agency (JAEA), 959-31 Jorinji, Toki, Gifu 509-5102 (Japan); Kobayashi, Tetsuo [Department of Earth and Environmental Sciences, Graduate School of Science and Engineering, Kagoshima University, 890-0065 Kagoshima (Japan)


    Radiocarbon dating using accelerator mass spectrometry (AMS) was performed on numerous wood trunks from pumiceous deposits along the Nagata, Isso and Miyanoura rivers on the northern side of Yakushima Island, 60 km south of Kyushu Island. The obtained {sup 14}C dates were around 6.5 ka BP, which, in combination with the geological characteristics of the pumiceous deposits indicates that these specimens were buried during the Kikai-Akahoya (K-Ah) eruption from the Kikai caldera. However, the fact that they are not charred suggests that the origin of these deposits are not pyroclastic flows. Fourteen taxa (Pinus subgen. Diploxylon, Tsuga, Cryptomeria, Chamaecyparis, Myrica, Castanea, Castanopsis, Quercus subgen. Cyclobalanopsis, Trochodendron, Phellodendron, Lagerstroemia, Rhododendron, Myrsine and Symplocos) were identified through anatomical characteristics. This is the first discovery of forest species on the Yakushima Island before the devastating eruption.

  1. The 21,700 yr b.p. Lower Toluca Pumice Plinian Eruption of Nevado de Toluca Volcano (Mexico): Evidences of Magma Mixing Process as Triggering Mechanism. (United States)

    Capra, L.; Arce, J.; Macias, J.


    Approximately 21,700 yr B.P., after a period of quiescence of 4800 yr, Nevado de Toluca volcano erupted, producing the Lower Toluca Pumice deposit. The activity generated a 24-km-high Plinian column that lasted ~11 h and dispersed 2.3 km3 (0.8 km3 dense rock equivalent) of tephra toward the NE, blanketing the Lerma basin, an area occupied today by the city of Toluca, with up to 5 cm of ash. Subsequent eruptive pulses were sub-Plinian in style, accompanied by phreatomagmatic explosions that emplaced surge deposits. Finally, the column collapsed toward the NE with the emplacement of a pumice flow deposit. The high vesicularity of the pumice from the basal Plinian layer, up to 83% by volume, indicates that exsolution was dominantly magmatic, and that pressurization of the magma chamber was probably due to a magma mixing process. Evidence for this includes the compositional range of juvenile products (from 55 to 65 wt% SiO2), as well as the presence of two types of plagioclase, one in equilibrium and the other one with disequilibrium textures and reverse zoning. This suggests input of an andesitic liquid into the dacitic magma chamber. Based on the eruptive record, the most likely future eruptive activity at Nevado de Toluca volcano will be Plinian. Although quiet for more than 3250 yr, Plinian activity could occur after a long period of quiescence, and it could represent a hazard for the entire Toluca basin, where more than one million people live today.

  2. The Upper Toluca Pumice (10.5 kyr): Product of the last major Plinian eruption of Nevado de Toluca volcano, Central Mexico (United States)

    Arce, J. L.; Macias, J. L.


    The last Plinian eruption at Nevado de Toluca volcano occurred 10.5 kyr ago producing the Upper Toluca Pumice (UTP). The UTP consists of four widespread fallout layers, interbedded with pyroclastic flow and surge deposits. The UTP event occurred under open vent conditions starting with hydromagmatic explosions that emplaced a hot pyroclastic flow (F0) on the east and northern flanks of the volcano. This explosion decompressed the magmatic system allowing almost immediately the formation of a 21 km high Plinian column that was dispersed by predominant winds 5o to the NE (PC0), which waned after some time. The eruption recommenced with the establishment of three Plinian columns that were dispersed in a NE-E direction, reaching heights of 39, 42, and 28 km, and deposited fall layers (PC1, PC2, and PC3) respectively. These Plinian columns were interrupted several times by phreatomagmatic and collapse events that emplaced pyroclastic flows (F1, F2, and F3) and surges (S1, and S2), mainly on the eastern and northern flanks of the volcano. The juvenile components of the UTP sequence are white, gray and banded pumice and gray juvenile lithic clasts both of dacitic composition (63-66wt% SiO2), and minor accidental lithics. The fallout deposits (PC1 and PC2) covered a minimum area of 2000 km2 with a total volume of 14 km3 (ca. 6 km3 D.R.E.); a mass eruption rate ranging from 3\\times107 to 5\\times108 kg/s and a total mass of 1.2\\times1013 kg. The UTP emplaced 1.5 m of gravel-sized pumice in the modern City of Toluca region and ca. 20 cm of fine sand in the Mexico City region. A future event of this magnitude might represent a major catastrophe to the 30 million people living in these cities and their surroundings.

  3. Application of acidic treated pumice as an adsorbent for the removal of azo dye from aqueous solutions: kinetic, equilibrium and thermodynamic studies

    Directory of Open Access Journals (Sweden)

    Samarghandi Mohammad


    Full Text Available Abstract Colored effluents are one of the important environment pollution sources since they contain unused dye compounds which are toxic and less-biodegradable. In this work removal of Acid Red 14 and Acid Red 18 azo dyes was investigated by acidic treated pumice stone as an efficient adsorbent at various experimental conditions. Removal of dye increased with increase in contact time and initial dye concentration, while decreased for increment in solution temperature and pH. Results of the equilibrium study showed that the removal of AR14 and AR18 followed Freundlich (r2>0.99 and Langmuir (r2>0.99 isotherm models. Maximum sorption capacities were 3.1 and 29.7 mg/g for AR 14 and AR18, namely significantly higher than those reported in the literature, even for activated carbon. Fitting of experimental data onto kinetic models showed the relevance of the pseudo-second order (r2>0.99 and intra-particle diffusion (r2>0.98 models for AR14 and AR18, respectively. For both dyes, the values of external mass transfer coefficient decreased for increasing initial dye concentrations, showing increasing external mass transfer resistance at solid/liquid layer. Desorption experiments confirmed the relevance of pumice stone for dye removal, since the pH regeneration method showed 86% and 89% regeneration for AR14 and AR18, respectively.

  4. Application of Acidic Treated Pumice as an Adsorbent for the Removal of Azo Dye from Aqueous Solutions:kinetic, Equilibrium and Thermodynamic Studies

    Directory of Open Access Journals (Sweden)

    Saied Bashiri


    Full Text Available Colored effluents are one of the important environment pollution sources since they contain unused dye compounds which are toxic and less-biodegradable. In this work removal of Acid Red 14 and Acid Red 18 azo dyes was investigated by acidic treated pumice stone as anefficient adsorbent at various experimental conditions. Removal of dye increased with increase in contact time and initial dye concentration, while decreased for increment in solution temperature and pH. Results of the equilibrium study showed that the removal ofAR14 and AR18 followed Freundlich (r2>0.99 and Langmuir (r2>0.99 isotherm models.Maximum sorption capacities were 3.1 and 29.7 mg/g for AR 14 and AR18, namely significantly higher than those reported in the literature, even for activated carbon. Fitting of experimental data onto kinetic models showed the relevance of the pseudo-second order (r2>0.99 and intra-particle diffusion (r2>0.98 models for AR14 and AR18, respectively. For both dyes, the values of external mass transfer coefficient decreased for increasing initial dye concentrations, showing increasing external mass transfer resistance at solid/liquid layer.Desorption experiments confirmed the relevance of pumice stone for dye removal, since the pH regeneration method showed 86% and 89 % regeneration for AR14 and AR18,respectively.

  5. Autotrophic denitrification of synthetic nitrate-contaminated groundwater in up-flow fixed-bed bioreactor by pumice as porous media

    Directory of Open Access Journals (Sweden)

    Masoud Tourang1


    Full Text Available Background: Background: Increasing nitrate concentrations in groundwater resources is considered a common environmental and public health problem worldwide. In this research, an autotrophic up-flow bioreactor with pumice as media was used to study the effects of the sulfur-to-nitrogen (S/N ratio and empty bed contact time (EBCT on nitrate removal efficiency and byproducts. Methods: Experiments were carried out in a 3.47 L up-flow, fixed-bed reactor with 3 sampling ports. To evaluate the overall impact of S/N ratio and EBCT on the performance of the bioreactor, several phases with different S/N ratios and EBCTs were applied. Results: At a constant S/N ratio of 3.85 g/g, as EBCT decreased from 24 hours to 2 hours, the nitrate removal efficiency decreased from 98% to 64%. On the other hand, at the desired EBCT of 4 hr, as S/N ratio decreased from 3.85 to 1.51 g/g, nitrate removal efficiency was reduced from 85% to 32%. Changing the EBCT and S/N ratio also affected the effluent nitrite and sulfate concentrations as byproducts. At the S/N ratio of 3.85 g/g and EBCT of 24 hours, effluent nitrite and sulfate concentrations were 0.1 mg NO2--N/L and 463 mg SO4 2-/L, respectively. Decreasing the S/N ratio to 1.51 g/g and the EBCT to 4 hours caused drastic changes in effluent nitrite and sulfate concentrations. Conclusion: The results indicated that the autotrophic denitrification with thiosulfate as electron donor and pumice as media was feasible and applicable for nitrate contaminated groundwater.

  6. Penicillium digitatum immobilized on pumice stone as a new solid phase extractor for preconcentration and/or separation of trace metals in environmental samples

    Energy Technology Data Exchange (ETDEWEB)

    Baytak, Sitki [Department of Chemistry, Faculty of Science and Arts, Harran University, 63100 Sanliurfa (Turkey); Kenduezler, Erdal [Department of Primary Education, Faculty of Education, Ahi Evran University, 40100 Kirsehir (Turkey); Tuerker, Ali Rehber [Department of Chemistry, Faculty of Science and Arts, Gazi University, 06500 Ankara (Turkey)], E-mail:; Goek, Nuray [Department of Environmental Engineering, Faculty of Engineering, Harran University, 63000 Sanliurfa (Turkey)


    This study presents a column solid phase extraction procedure based on column biosorption of Cu(II), Zn(II) and Pb(II) ions on Penicillium digitatum immobilized on pumice stone. The analytes were determined by flame atomic absorption spectrometry (FAAS). The optimum conditions such as: pH values, amount of solid phase, elution solution and flow rate of sample solution were evaluated for the quantitative recovery of the analytes. The effect of interfering ions on the recovery of the analytes has also been investigated. The recoveries of copper, zinc and lead under the optimum conditions were found to be 97 {+-} 2, 98 {+-} 2 and 98 {+-} 2%, respectively, at 95% confidence level. For the analytes, 50-fold preconcentration was obtained. The analytical detection limits for Cu(II), Zn(II) and Pb(II) were 1.8, 1.3 and 5.8 ng mL{sup -1}, respectively. The proposed procedure was applied for the determination of copper, zinc and lead in dam water, waste water, spring water, parsley and carrot. The accuracy of the procedure was checked by determining copper, zinc and lead in standard reference tea samples (GBW-07605)

  7. Penicillium digitatum immobilized on pumice stone as a new solid phase extractor for preconcentration and/or separation of trace metals in environmental samples

    International Nuclear Information System (INIS)

    Baytak, Sitki; Kenduezler, Erdal; Tuerker, Ali Rehber; Goek, Nuray


    This study presents a column solid phase extraction procedure based on column biosorption of Cu(II), Zn(II) and Pb(II) ions on Penicillium digitatum immobilized on pumice stone. The analytes were determined by flame atomic absorption spectrometry (FAAS). The optimum conditions such as: pH values, amount of solid phase, elution solution and flow rate of sample solution were evaluated for the quantitative recovery of the analytes. The effect of interfering ions on the recovery of the analytes has also been investigated. The recoveries of copper, zinc and lead under the optimum conditions were found to be 97 ± 2, 98 ± 2 and 98 ± 2%, respectively, at 95% confidence level. For the analytes, 50-fold preconcentration was obtained. The analytical detection limits for Cu(II), Zn(II) and Pb(II) were 1.8, 1.3 and 5.8 ng mL -1 , respectively. The proposed procedure was applied for the determination of copper, zinc and lead in dam water, waste water, spring water, parsley and carrot. The accuracy of the procedure was checked by determining copper, zinc and lead in standard reference tea samples (GBW-07605)

  8. The 23,500 y 14C BP White Pumice Plinian eruption and associated debris avalanche and Tochimilco lava flow of Popocatépetl volcano, México (United States)

    Siebe, Claus; Salinas, Sergio; Arana-Salinas, Lilia; Macías, José Luis; Gardner, James; Bonasia, Rosanna


    The White Pumice (WP) is one of the thickest and most voluminous Plinian fallouts produced by Popocatépetl volcano in central Mexico during the Late Pleistocene-Holocene. Its eruption 23,500 14C y BP (27,800 cal BP) was triggered by the catastrophic failure of the SW flank of the volcano. The resulting debris avalanche was highly mobile reaching 72 km from the cone with an apparent coefficient of friction (L/H) of 0.06. The deposit covers an area of 1200 km2, and has a volume of 10.4 km3. This gigantic landslide, characterized by exceptionally large proximal hummocks (> 400 m) provoked the sudden decompression of the hydrothermal and magmatic systems, which produced an initial blast followed by the rise of a Plinian column that reached an altitude of 33 km. The isopach map allows the recognition of a dispersal axis pointing toward the south, where an area of 2490 km2 was covered by > 10 cm of pumice and ash. The total volume of the pumice fallout was estimated at 1.9 km3 DRE (Dense Rock Equivalent). Pumice clasts are dacitic (62-66 wt.% SiO2, anhydrous basis), highly vesicular (55-88 vol.%) and display a seriate texture with phenocrysts of plagioclase + hornblende + augite + hypersthene + oxides (Ti-magnetite and ilmenite) + apatite. As the eruption advanced, discharge rates became more intermittent and the height of the column fluctuated and finally collapsed, generating pumice-and-ash flows that were emplaced around the volcano. This short but intense activity was followed during subsequent years by rain-induced lahars that reached great distances from the volcano. At the same time, more degassed andesitic-dacitic (61-65 wt.% SiO2) magma was erupted effusively (4.4 km3, DRE) in the new horseshoe-shaped 5 km-wide crater from which the Tochimilco lava flow descended toward the SSE, where it inundated an area of 68 km2 and reached as far as 22 km from its source. Since then, multiple eruptions have reconstructed the summit cone, almost completely obliterating the

  9. Pumices from the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.

    A better understanding of submarine volcanisms that result in pyroclastics is of universal importance for paleotectonic reconstruction, crustal growth estimates and location of volcanisms throughout the earth's history. Of the volcanogenic...

  10. Fluoride removal from aqueous solution by pumice: case study on ...

    African Journals Online (AJOL)


    conditions, the fluoride removal efficiency from Kuhbonan water by 2.8 mg/L fluoride was 74.64%. Eventually ... industrial wastewater containing fluoride is a key ..... solution using silica ceramic: Adsorption kinetics and equilibrium studies.

  11. Ectomycorrhizal communities of ponderosa pine and lodgepole pine in the south-central Oregon pumice zone (United States)

    Maria O. Garcia; Jane E. Smith; Daniel L. Luoma; Melanie D. Jones


    Forest ecosystems of the Pacific Northwest of the USA are changing as a result of climate change. Specifically, rise of global temperatures, decline of winter precipitation, earlier loss of snowpack, and increased summer drought are altering the range of Pinus contorta. Simultaneously, flux in environmental conditions within the historic ...

  12. Fresh pumice from the Central Indian Basin: A Krakatau 1883 signature

    Digital Repository Service at National Institute of Oceanography (India)

    Mudholkar, A.V.; Fujii, T.

    of different sizes and shapes were collected from the surficial sediments of the CIB from an average depth of about 5000 m (12 degrees S, 76 degrees E). Glass is the main phase comprising about 95% (volume) and resembles the matrix glass in Krakatau 1883...

  13. Post-depositional fracturing and subsidence of pumice flow deposits: Lascar Volcano, Chile. (United States)

    Whelley, Patrick L; Jay, J; Calder, E S; Pritchard, M E; Cassidy, N J; Alcaraz, S; Pavez, A

    Unconsolidated pyroclastic flow deposits of the 1993 eruption of Lascar Volcano, Chile, have, with time, become increasingly dissected by a network of deeply penetrating fractures. The fracture network comprises orthogonal sets of decimeter-wide linear voids that form a pseudo-polygonal grid visible on the deposit surface. In this work, we combine shallow surface geophysical imaging tools with remote sensing observations and direct field measurements of the deposit to investigate these fractures and their underlying causal mechanisms. Based on ground penetrating radar images, the fractures are observed to have propagated to depths of up to 10 m. In addition, orbiting radar interferometry shows that deposit subsidence of up to 1 cm/year -1 occurred between 1993 and 1996 with continued subsidence occurring at a slower rate thereafter. In situ measurements show that 1 m below the surface, the 1993 deposits remain 5°C to 15°C hotter, 18 years after emplacement, than adjacent deposits. Based on the observed subsidence as well as estimated cooling rates, the fractures are inferred to be the combined result of deaeration, thermal contraction, and sedimentary compaction in the months to years following deposition. Significant environmental factors, including regional earthquakes in 1995 and 2007, accelerated settling at punctuated moments in time. The spatially variable fracture pattern relates to surface slope and lithofacies variations as well as substrate lithology. Similar fractures have been reported in other ignimbrites but are generally exposed only in cross section and are often attributed to formation by external forces. Here we suggest that such interpretations should be invoked with caution, and deformation including post-emplacement subsidence and fracturing of loosely packed ash-rich deposits in the months to years post-emplacement is a process inherent in the settling of pyroclastic material.

  14. The effect of fly ash to self-compactability of pumice aggregate ...

    Indian Academy of Sciences (India)

    This paper presents the results of an experimental study on the effects .... There has been an increase in using self-compacting concrete (SCC) in recent years and a .... of SCLC and the ability for SCLC to change its path and to pass through.

  15. Ectomycorrhizal communities of ponderosa pine and lodgepole pine in the south-central Oregon pumice zone. (United States)

    Garcia, Maria O; Smith, Jane E; Luoma, Daniel L; Jones, Melanie D


    Forest ecosystems of the Pacific Northwest of the USA are changing as a result of climate change. Specifically, rise of global temperatures, decline of winter precipitation, earlier loss of snowpack, and increased summer drought are altering the range of Pinus contorta. Simultaneously, flux in environmental conditions within the historic P. contorta range may facilitate the encroachment of P. ponderosa into P. contorta territory. Furthermore, successful pine species migration may be constrained by the distribution or co-migration of ectomycorrhizal fungi (EMF). Knowledge of the linkages among soil fungal diversity, community structure, and environmental factors is critical to understanding the organization and stability of pine ecosystems. The objectives of this study were to establish a foundational knowledge of the EMF communities of P. ponderosa and P. contorta in the Deschutes National Forest, OR, USA, and to examine soil characteristics associated with community composition. We examined EMF root tips of P. ponderosa and P. contorta in soil cores and conducted soil chemistry analysis for P. ponderosa cores. Results indicate that Cenococcum geophilum, Rhizopogon salebrosus, and Inocybe flocculosa were dominant in both P. contorta and P. ponderosa soil cores. Rhizopogon spp. were ubiquitous in P. ponderosa cores. There was no significant difference in the species composition of EMF communities of P. ponderosa and P. contorta. Ordination analysis of P. ponderosa soils suggested that soil pH, plant-available phosphorus (Bray), total phosphorus (P), carbon (C), mineralizable nitrogen (N), ammonium (NH4), and nitrate (NO3) are driving EMF community composition in P. ponderosa stands. We found a significant linear relationship between EMF species richness and mineralizable N. In conclusion, P. ponderosa and P. contorta, within the Deschutes National Forest, share the same dominant EMF species, which implies that P. ponderosa may be able to successfully establish within the historic P. contorta range and dominant EMF assemblages may be conserved.

  16. The effect of blast furnace slag on the self-compactability of pumice ...

    Indian Academy of Sciences (India)


    Apr 2, 2018 ... and it has been used as the aggregate in the production of lightweight ... gravity factor (SGF) incorporates compensation for absorp- tion of free water ...... (vii) When the humidity control of aggregate was neglected and was not ...

  17. Coexistence of pumice and manganese nodule fields-evidence for submarine silicic volcanism in the Central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.; Sudhakar, M.

    Volcanologlst Association, Napoh, 128 pp. PAUTOT G and M HOFFERT (1984) Les nodules du Pactfique Central darts leur environment geologtque Campagne CopantT--1979 Publication du CNEXO, 26, 202 pp PATRIAT P and J SECOUFIN (1988) Reconstruction of the Central...

  18. Effect of the use nickeliferous laterite and pumice as additives in the performance and durability of the Portland cement

    Directory of Open Access Journals (Sweden)

    María Carolina Rueda-Gualdrón


    Full Text Available En este trabajo se evalúa el comportamiento puzolánico de la laterita niquelífera de Cerromatoso (Córdoba y la pumita de Cemex (Boyacá en la preparación de morteros según normas NTC para agregados finos. Los morteros se prepararon con adiciones de 2,5%, 5% y 10% como sustitutos del cemento Portland tipo I, los cuales fueron sometidos a ensayos de resistencia mecánica antes y después de ser sometidos a ambientes extremos (altas temperaturas y ataques químicos como H2 SO4 y MgSO4 . Los resultados demuestran cómo estos materiales alternativos incrementan o disminuyen su grado de puzolanidad, así como el efecto de estos aditivos al interior de las mezclas de mortero en el tiempo, demostrando propiedades similares con relación a los morteros preparados con cemento Portland tipo I. Por lo tanto, los morteros tienen una respuesta aceptable ante las condiciones evaluadas, aunque es posible mejorar su desempeño y durabilidad, colaborando no solo con el ahorro energético en la producción del cemento Portland tipo I sino también en el uso de aditivos alternativos que permitan mitigar el impacto ambiental provocado por la industria cementera.

  19. Effect of the use nickeliferous laterite and pumice as additives in the performance and durability of the Portland cement


    María Carolina Rueda-Gualdrón; Karen Milena Vega-Nuñez; Carlos Alberto Ríos-Reyes


    En este trabajo se evalúa el comportamiento puzolánico de la laterita niquelífera de Cerromatoso (Córdoba) y la pumita de Cemex (Boyacá) en la preparación de morteros según normas NTC para agregados finos. Los morteros se prepararon con adiciones de 2,5%, 5% y 10% como sustitutos del cemento Portland tipo I, los cuales fueron sometidos a ensayos de resistencia mecánica antes y después de ser sometidos a ambientes extremos (altas temperaturas y ataques químicos como H2 SO4 y MgSO4 ). Los resu...

  20. Comparison of shear bond strength of self-etching fluoride releasing adhesives with and without pumice prophylaxis

    Directory of Open Access Journals (Sweden)

    V R Shobbana Devi


    Conclusions: Fluoride releasing adhesives combined with antibacterial monomer can play a vital role in reducing white spot lesions by enhancing the cariostatic effect especially in noncompliant\\medically compromised patients.

  1. Petrology and geochemistry of Late Holocene felsic magmas from Rungwe volcano (Tanzania), with implications for trachytic Rungwe Pumice eruption dynamics

    NARCIS (Netherlands)

    Fontijn, K.; Elburg, M.A.; Nikogosian, I.K.; van Bergen, M.J.; Ernst, G.G.J.


    Rungwe in southern Tanzania is an active volcanic centre in the East African Rift System, characterised by Plinian-style explosive eruptions of metaluminous to slightly peralkaline trachytic silica-undersaturated magmas during its late Holocene history. Variations in whole-rock major and trace

  2. A note on chemical composition and origin of ferromanganese oxide coated and uncoated pumice samples from central Indian Ocean basin

    Digital Repository Service at National Institute of Oceanography (India)

    Pattan, J.N.; Parthiban, G.; Moraes, C.; Rajalakshmi, R.; Lekshmi, S.; Athira, S.; JaiSankar, S.

    other suggesting a same source. Tectonomagmatic discrimination diagrams (Nb vs Y: Yb vs. Ta), triangular plot (TiO2-Y) and High Field Strength Element ratios (La/Ta-25; Ta/Hf-0.2; Nb/Ta-9; Zr/Nb-22 and Ba/Ta-1084) indicate volcanic arc origin...

  3. Soil heating during the complete combustion of mega-logs and broadcast burning in central Oregon USA pumice soils (United States)

    Jane E. Smith; Ariel D. Cowan; Stephen A. Fitzgerald


    The environmental effect of extreme soil heating, such as occurs with the complete combustion of large downed wood during wildfires, is a post-fire management concern to forest managers. To address this knowledge gap, we stacked logs to create ‘mega-log’ burning conditions and compared the temperature, duration and penetration of the soil heat pulse in nine high...

  4. Time scales of magma recharge and crystal growth rate determined from Mg and Ti zoning in plagioclase phenocrysts from the Upper Toluca Pumice, Mexico (United States)

    Dohmen, Ralf; Smith, Victoria C.; Arce, Jose Luis; Blundy, Jonathan D.


    Major and trace element zoning in plagioclase phenocrysts has the potential to stores information on the temporal evolution of the chemical environment during crystal growth, i.e. the surrounding melt composition as well as the intensive parameters temperature (T) and pressure (P), provided that equilibrium partitioning accompanies growth. However, the problem is complicated by the fact that diffusion of mobile elements changes their initial concentrations due to re-equilibration with the surrounding melt at later stages, making estimation of the pre-diffusive element profiles fraught with uncertainty. Here we present a new approach that combines the information from immobile (e.g., Ca, Ti) and mobile (e.g., Mg) elements in plagioclase to unravel the growth history and time scales of magma recharge events from the 10.5 ka Upper Toluca plinian eruption of Nevado de Toluca volcano, Mexico. Since trace elements are less sensitive to intensive parameters their variations in plagioclase phenocrysts have been used to identify open-system processes in silicic systems [1]. These phenocrysts preserve complex element patterns, such as oscillatory zoning and overgrowths, indicating multiple magma recharging events. Based on available diffusion data major elements and, for example, the trace element Ba, are effectively unchanged since crystallization, but the mobility of Mg [2] is large enough to alter the initial concentration at later growth stages. We made attempts to model the Mg zoning using two endmember cases for the growth history of the plagioclase. In the model the growth rate can either be constant until the final crystal diameter is reached or involve various short growth stages with diffusion relaxation breaks in-between. The corresponding moving boundary problem of the diffusion equation was solved numerically using the method of finite differences and a front-tracking method [3]. A particular challenge of the modelling is to estimate the initial Mg concentration after an incremental growth step since the melt composition is unknown during each growth stage. We have tried two different approaches: In each case three calculation steps are involved, which are based on the assumption that Ti and the anorthite (An) content were not affected by diffusion and both correlated linearly with Mg in the plagioclase during growth. Both methods give a very similar result for the initial Mg profile, provided that the plagioclase-melt Mg partition coefficient is constant (independent of T and An) and of the order of 0.03 +/-0.01, which is consistent with the data of Bindeman et al. (1998) [4] and unpublished data of Blundy & Wood [5], and with the fact that the predicted MgO contents in the melt are consistent with observed melt inclusions in UTP rocks [1]. Our first modelling results are, in general, able to simulate the final observed Mg concentration profiles, but the time scale obtained is actually less sensitive to the choice for the growth history (constant or one-step growth). The time scales are on the order of hundred years to several thousand years subject to the assumption of Costa et al (2003) [6] that the diffusion coefficient of Mg has the same dependence on An as Sr, which has to be experimentally validated. Temperature was taken from two-oxide thermometry (830 °C). Other factors of uncertainty for the modelling are less significant (e.g., anisotropy) and lower than an order of magnitude. Our estimated magma residence times are consistent with steady refilling of the Toluca magma chamber since the previous eruption ~12 kyr at a rate of ≥ 6.e6 m3/yr. [1] Smith et al. (2009), J. Petrol. 50, 405. [2] LaTourette & Wasserburg (1998) Earth Plant. Sci. Let. 158, 91. [3] Crank (1975) Oxford Sci. Publ. 414p. [4] Bindeman et al. (1998), Geochim. Cosmochim. Acta 62, 1175. [5] Blundy & Wood, Nature, 372, 452. [6] Costa et al. , (2003), Geochim. Cosmochim. Acta 67, 2189.

  5. Chronology, morphology and stratigraphy of pumiceous pyroclastic-flow (ignimbrite) deposits from the eruption of Mount St. Helens on 18 May 1983 (United States)

    Criswell, C. W.; Elston, W. E.


    Between 1217 and 1620 hours (PDT), on May 18, 1980, the magmatic eruption column of Mount St. Helens formed an ash fountain and pyroclastic flows dominated the eruption process over tephra ejection. Eurption-rate pulsations generally increased to a maximum at 1600 to 1700 hrs. After 1620 hrs, the eruption assumed an open-vent discharge with strong, vertical ejection of tephra. Relative eruption rates (relative mass flux rates) of the pyroclastic flows were determined by correlating sequential photographs and SLAR images, obtained during the eruption, with stratigraphy and surface morphology of the deposits.

  6. 2018-04-29T21:07:23Z oai:ojs ...

    African Journals Online (AJOL)

    This paper assesses the properties of pumice materials on its particle sizes and the water absorption capacity. It also assesses the strengths of pumice blocks and wall units as compared with cement sand blocks and its walling units. The aim was to seek wider alternative choices of building materials. Samples of pumice ...

  7. A comprehensive view of manganese nodules and volcanics of the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Jauhari, P.; Iyer, S.D.

    the seafloor. Various theories have been proposed to explain the enigma of heavier nodules resting on lighter sediments especially when the rate of sediment accumu- lation is higher than the growth of the nodules. Glasby and Read (1976) observed that due... silicic erup- tion and pumice formation. Moreover, it has been reported that hot pumice sinks faster, due to a greater capacity to absorb water and being nearer to the source as compared to colder pumice (Whitham and Sparks, 1986). We presume...

  8. Characterization of juvenile pyroclasts from the Kos Plateau Tuff (Aegean Arc): insights into the eruptive dynamics of a large rhyolitic eruption (United States)

    Bouvet de Maisonneuve, Caroline; Bachmann, Olivier; Burgisser, Alain


    Silicic pumices formed during explosive volcanic eruptions are faithful recorders of the state of the magma in the conduit, close to or at the fragmentation level. We have characterized four types of pumices from the non-welded rhyolitic Kos Plateau Tuff, which erupted 161,000 years ago in the East Aegean Arc, Greece. The dominant type of pumice (>90 vol.%) shows highly elongated tubular vesicles. These tube pumices occur throughout the eruption. Less common pumice types include: (1) “frothy” pumice (highly porous with large, sub-rounded vesicles), which form 5-10 vol.% of the coarsest pyroclastic flow deposits, (2) dominantly “microvesicular” and systematically crystal-poor pumices, which are found in early erupted, fine-grained pyroclastic flow units, and are characterized by many small (<50 μm in diameter) vesicles and few mm-sized, irregular voids, (3) grey or banded pumices, indicating the interaction between the rhyolite and a more mafic magma, which are found throughout the eruption sequence and display highly irregular bubble shapes. Except for the grey-banded pumices, all three other types are compositionally identical and were generated synchronously as they are found in the same pyroclastic units. They, therefore, record different conditions in the volcanic conduit leading to variable bubble nucleation, growth and coalescence. A total of 74 pumice samples have been characterized using thin section observation, SEM imagery, porosimetry, and permeametry. We show that the four pumice types have distinct total and connected porosity, tortuosity and permeability. Grey-banded pumices show large variations in petrophysical characteristics as a response to mingling of two different magmas. The microvesicular, crystal-poor, pumices have a bimodal bubble size distribution, interpreted as reflecting an early heterogeneous bubble nucleation event followed by homogeneous bubble nucleation close to fragmentation. Finally, the significant differences in

  9. Evaluation of the surface roughness of three heat-cured acrylic denture base resins with different conventional lathe polishing techniques: A comparative study

    Directory of Open Access Journals (Sweden)

    Duggineni Chalapathi Rao


    Results: Among the materials tested, better results were obtained with Trevalon Hi followed by Meliodent and DPI. Among the polishing methods used, superior results were obtained with universal polishing paste followed by polishing cake; Pumice and Gold rouge. Although Pumice and Gold rouge values produced greater roughness value, they were well within the threshold value of 0.2 mm.

  10. Unusual pleural involvement after exposure to amorphous silicates (Liparitosis): report of two cases

    International Nuclear Information System (INIS)

    Mazziotti, S.; Ascenti, G.; Lamberto, S.; Scribano, E.; Costa, C.


    Liparitosis is a rare pneumoconiosis determined by inhalation of pumice, an amorphous complex silicate extracted in the quarries of Lipari (Aeolian Archipelago, Italy). We describe two cases of subjects occupationally exposed to pumice dust in which high-resolution computed tomography (HRCT) revealed the presence of pleural lesions without parenchymal involvement. (orig.)

  11. Unusual pleural involvement after exposure to amorphous silicates (Liparitosis): report of two cases

    Energy Technology Data Exchange (ETDEWEB)

    Mazziotti, S.; Ascenti, G.; Lamberto, S.; Scribano, E. [Institute of Radiological Sciences, Policlinico ' ' G. Martino' ' , University of Messina (Italy); Costa, C. [Social Health Department, Messina (Italy)


    Liparitosis is a rare pneumoconiosis determined by inhalation of pumice, an amorphous complex silicate extracted in the quarries of Lipari (Aeolian Archipelago, Italy). We describe two cases of subjects occupationally exposed to pumice dust in which high-resolution computed tomography (HRCT) revealed the presence of pleural lesions without parenchymal involvement. (orig.)

  12. Controls on magma permeability in the volcanic conduit during the climactic phase of the Kos Plateau Tuff eruption (Aegean Arc) (United States)

    Degruyter, W.; Bachmann, O.; Burgisser, A.


    X-ray computed microtomography (µCT) was applied to pumices from the largest Quaternary explosive eruption of the active South Aegean Arc (the Kos Plateau Tuff; KPT) in order to better understand magma permeability within volcanic conduits. Two different types of pumices (one with highly elongated bubbles, tube pumice; and the other with near spherical bubbles, frothy pumice) produced synchronously and with identical chemical composition were selected for µCT imaging to obtain porosity, tortuosity, bubble size and throat size distributions. Tortuosity drops on average from 2.2 in frothy pumice to 1.5 in tube pumice. Bubble size and throat size distributions provide estimates for mean bubble size (~93-98 μm) and mean throat size (~23-29 μm). Using a modified Kozeny-Carman equation, variations in porosity, tortuosity, and throat size observed in KPT pumices explain the spread found in laboratory measurements of the Darcian permeability. Measured difference in inertial permeability between tube and frothy pumices can also be partly explained by the same variables but require an additional parameter related to the internal roughness of the porous medium (friction factor f 0 ). Constitutive equations for both types of permeability allow the quantification of laminar and turbulent gas escape during ascent of rhyolitic magma in volcanic conduits.

  13. Influence of calcium and silicon supplementation into Pleurotus ostreatus substrates on quality of fresh and canned mushrooms. (United States)

    Thongsook, T; Kongbangkerd, T


    Supplements of gypsum (calcium source), pumice (silicon source) and pumice sulfate (silicon and calcium source) into substrates for oyster mushrooms (Pleurotus ostreatus) were searched for their effects on production as well as qualities of fresh and canned mushrooms. The addition of pumice up to 30% had no effect on total yield, size distribution and cap diameters. The supplementation of gypsum at 10% decreased the total yield; and although gypsum at 5% did not affect total yield, the treatment increased the proportion of large-sized caps. High content (>10%) of pumice sulfate resulted in the lower yield. Calcium and silicon contents in the fruit bodies were not influenced by supplementations. The centrifugal drip loss values and solid content of fresh mushrooms, and the percentage of weight gained and firmness of canned mushrooms, cultivated in substrates supplemented with gypsum, pumice and pumice sulfate were significantly (p≤0.05) higher than those of the control. Scanning electron micrographs revealed the more compacted hyphae of mushroom stalks supplemented with silicon and/or calcium after heat treatment, compared to the control. Supplementation of P. ostreatus substrates with 20% pumice was the most practical treatment because it showed no effect on yield and the most cost-effective.

  14. 36 CFR 228.42 - Definitions. (United States)


    ... and posted on the ground from which nonexclusive disposals of mineral materials may be made to low..., stone, pumice, pumicite, cinders, clay, and other similar materials. Common varieties do not include...

  15. Nature, source and composition of volcanic ash in sediments from a fracture zone trace of Rodriguez Triple Junction in the Central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Mascarenhas-Pereira, M.B.L.; Nath, B.N.; Borole, D.V.; Gupta, S.M.

    Volcanic glasses associated with pumice, micro nodules and palagonite like lithic fragments were recovered from a volcanic terrain in a fracture zone defined as Rodriguez Triple Junction trace in the Central Indian Basin. Morphologically, the tephra...

  16. Effectiveness of clean-up procedures on stain susceptibility of different orthodontic adhesives

    Directory of Open Access Journals (Sweden)

    Swati Pundlik Mane


    Conclusion: Chemical-cure adhesive showed higher stain susceptibility than light-cure adhesive in all clean-up procedures. Both adhesives would show less stain susceptibility with polishing step with rubber cup and pumice.

  17. Evidences for a volcanic province in the Central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.; Sudhakar, M.

    Based on various lines of evidence such as the widespread occurrence of basalts, pumice, volcanic glass shards and their transformational products (zeolites, palagonites, and smectite-rich sediments), we suggest the presence of a volcanic province...

  18. Submarine silicic volcanism: Processes and products

    Digital Repository Service at National Institute of Oceanography (India)

    Kalangutkar, N.G.; Iyer, S.D.

    hawaiite, mugearite, benmorite and trachyte to rhyolite (Prestvik et al., 2001). A plinian eruption produced rhyolitic ash and pumice while an initial phreatomagmatic explosion gave rise to lithic fragments characterised by bomb-like pumice blocks... blocks and bombs Selbekk and Tronnes (2007) Granophyres, rhyolites obsidian O’nions and Gronvold (1973) Rhyolite Sigvaldason (1974) Ascension and the Azores Quartz saturated residue Clague (1987) 14 Azores and the Canaries Silica oversaturated...

  19. Eruption dynamics and explosive-effusive transitions during the 1400 cal BP eruption of Opala volcano, Kamchatka, Russia (United States)

    Andrews, Benjamin J.; Dufek, Josef; Ponomareva, Vera


    Deposits and pumice from the 1400 cal BP eruption of Opala volcano record activity that occurred at the explosive-effusive transition, resulting in intermittent, or stop-start, behavior, where explosive activity resumed following a pause. The eruption deposited distinctive, biotite-bearing rhyolite tephra across much of Kamchatka, and its stratigraphy consists of a lithic-rich pumice fall, overlain by pumice falls and pyroclastic density deposits, with the proportion of the latter increasing with height. This sequence repeats such that the middle of the total deposit is marked by a lithic-rich fall with abundant obsidian clasts. Notably, the eruptive pumice are poorly vesiculated, with vesicle textures that record fragmentation of a partially collapsed magmatic foam. The eruption vent, Baranii Amphitheater is filled with obsidian lavas of the same composition as the rhyolite tephra. Based upon the stratigraphic and compositional relations, we divide the eruption into four phases. Phase I initiated with eruption of a lithic-rich pumice fall, followed by eruption of Plinian falls and pyroclastic density currents. During Phase II, the eruption paused for at least 5-6 h; in this time, microlites nucleated and began to grow in the magma. Phase III essentially repeated the Phase I sequence. Obsidian lavas were emplaced during Phase IV. The pumice textures suggest that the magma ascended very near the threshold decompression rate for the transition between explosive (fast) and effusive (slow) behavior. The pause during Phase II likely occurred as decompression slowed enough for the magma to develop sufficient permeability for gas to escape resulting in collapse of the magmatic foam, stopping the eruption and temporarily sealing the conduit. After about 5-6 h, eruption resumed with, once again, magma decompressing very near the explosive-effusive transition. Phase III ended when the decompression rate slowed and lava dome emplacement began. Distributions of pumice and

  20. Preliminary surface analysis of etched, bleached, and normal bovine enamel

    International Nuclear Information System (INIS)

    Ruse, N.D.; Smith, D.C.; Torneck, C.D.; Titley, K.C.


    X-ray photoelectron spectroscopic (XPS) and secondary ion-mass spectroscopic (SIMS) analyses were performed on unground un-pumiced, unground pumiced, and ground labial enamel surfaces of young bovine incisors exposed to four different treatments: (1) immersion in 35% H2O2 for 60 min; (2) immersion in 37% H3PO4 for 60 s; (3) immersion in 35% H2O2 for 60 min, in distilled water for two min, and in 37% H3PO4 for 60 s; (4) immersion in 37% H3PO4 for 60 s, in distilled water for two min, and in 35% H2O2 for 60 min. Untreated unground un-pumiced, unground pumiced, and ground enamel surfaces, as well as synthetic hydroxyapatite surfaces, served as controls for intra-tooth evaluations of the effects of different treatments. The analyses indicated that exposure to 35% H2O2 alone, besides increasing the nitrogen content, produced no other significant change in the elemental composition of any of the enamel surfaces investigated. Exposure to 37% H3PO4, however, produced a marked decrease in calcium (Ca) and phosphorus (P) concentrations and an increase in carbon (C) and nitrogen (N) concentrations in unground un-pumiced specimens only, and a decrease in C concentration in ground specimens. These results suggest that the reported decrease in the adhesive bond strength of resin to 35% H2O2-treated enamel is not caused by a change in the elemental composition of treated enamel surfaces. They also suggest that an organic-rich layer, unaffected by acid-etching, may be present on the unground un-pumiced surface of young bovine incisors. This layer can be removed by thorough pumicing or by grinding. An awareness of its presence is important when young bovine teeth are used in a model system for evaluation of resin adhesiveness

  1. Precursory activity of the 161 ka Kos Plateau Tuff eruption, Aegean Sea (Greece) (United States)

    Piper, David J. W.; Pe-Piper, Georgia; Lefort, Darren


    The Kos Plateau Tuff (KPT) eruption of 161 ka was the largest explosive Quaternary eruption in the eastern Mediterranean. We have discovered an uplifted beach deposit of abraded pumice cobbles, directly overlain by the KPT. The pumice cobbles resemble pumice from the KPT in petrography and composition and differ from Plio-Pleistocene rhyolites on the nearby Kefalos Peninsula. The pumice contains enclaves of basaltic andesite showing chilled lobate margins, suggesting co-existence of two magmas. The deposit provides evidence that the precursory phase of the KPT eruption produced pumice rafts, and defines the paleoshoreline for the KPT, which elsewhere was deposited on land. The beach deposit has been uplifted about 120 m since the KPT eruption, whereas the present marine area south of Kos has subsided several hundred metres, as a result of regional neotectonics. The basaltic andesite is more primitive than other mafic rocks known from the Kos-Nisyros volcanic centre and contains phenocrysts of Fo89 olivine, bytownite, enstatite and diopside. Groundmass amphibole suggests availability of water in the final stages of magma evolution. Geochemical and mineralogical variation in the mafic products of the KPT eruption indicate that fractionation of basaltic magma in a base-of-crust magma chamber was followed by mixing with rhyolitic magma during eruption. Low eruption rates during the precursory activity may have minimised the extent of mixing and preserved the end-member magma types.

  2. Structural and mechanical study of concrete made from cementitious materials of low environmental impact (United States)

    González, A. K.; Montaño, A. M.; González, C. P.; Santos, A.


    This work shows the results obtained by replacing Type I Portland®, by cementitious geopolymers materials, derived from minerals, in concrete mixtures. Synthesis of both geopolymers through alkaline activation of two alluminosilicates: Bentonite and Pumice with sodium silicate (Na2SiO3). XRD, SEM and XRDE are used to structural study of new geopolymers. Concrete mixtures with replacement of Portland have 10% and 30% of geopolymer. Finally, concrete mortars formed were mechanically analysed according to ICONTEC 220 at 7, 14, 28, 41, 90 and 120 days of cure. Results shows that compressive strength of concrete from Bentonite and Pumice are almost the same for the standard concrete at 28 days of cure. At 90 days of cure, compression resistance of concrete from Pumice at 10% is even higher than those that standard concrete shows.

  3. The largest deep-ocean silicic volcanic eruption of the past century. (United States)

    Carey, Rebecca; Soule, S Adam; Manga, Michael; White, James; McPhie, Jocelyn; Wysoczanski, Richard; Jutzeler, Martin; Tani, Kenichiro; Yoerger, Dana; Fornari, Daniel; Caratori-Tontini, Fabio; Houghton, Bruce; Mitchell, Samuel; Ikegami, Fumihiko; Conway, Chris; Murch, Arran; Fauria, Kristen; Jones, Meghan; Cahalan, Ryan; McKenzie, Warren


    The 2012 submarine eruption of Havre volcano in the Kermadec arc, New Zealand, is the largest deep-ocean eruption in history and one of very few recorded submarine eruptions involving rhyolite magma. It was recognized from a gigantic 400-km 2 pumice raft seen in satellite imagery, but the complexity of this event was concealed beneath the sea surface. Mapping, observations, and sampling by submersibles have provided an exceptionally high fidelity record of the seafloor products, which included lava sourced from 14 vents at water depths of 900 to 1220 m, and fragmental deposits including giant pumice clasts up to 9 m in diameter. Most (>75%) of the total erupted volume was partitioned into the pumice raft and transported far from the volcano. The geological record on submarine volcanic edifices in volcanic arcs does not faithfully archive eruption size or magma production.

  4. Clinical evaluation of the effect of a herbal compound made for treatment of discolorations caused by dental fluorosis

    Directory of Open Access Journals (Sweden)

    Mahshid Mohammdi Basir


    Full Text Available   Background and Aims: The purpose of this study was research on a new herbal compound (Seidlitzia Rosmarinus made by Traditional Medicine Research Group, University of shahed to find a safer alternative to HCL-Pumice compound technique.   Materials and Methods: In this randomized clinical trial seventy two anterior teeth from 9 patients were divided in to three groups according to fluorosis severity: mild (34 teeth, moderate (14 teeth, and sever (24 teeth. In each patient, half of the teeth were treated with “Shahed” compound and other half treated with HCL-Pumice compound. Before and after treatment, photographs were taken in both groups. HCL-Pumice treatment compound was applied for 30 seconds periods and continued for 10 minutes if necessary. In case of herbal Shahed compound the time was determined by clinical symptoms or when labial contour was dismissed, If the result was not esthetistically acceptabale for the patient, HCL-Pumice compound was applied on teeth. NaF was applied after mouth washing. The photographs of the teeth before and after treatment were reviewed by two experienced observer unaware of the treatment modality. The results were analyzed using willcoxon’s, kruskal-wallis and scheffe test.   Results: There was over 81.3% acceptance between two observers and no significant differences in intraobservers evaluation (P>0.05. Improvement in beauty indexes were observed in all degrees of dental fluorosis by 18% with HCL-Pumice compound application, but “Shahed” herbal compound induced significant reduction in the amount of white spots in mild fluorosis and stain intensity of moderate fluorosis (P<0.05 , while the reduction in the severity of discoloration in group 2, these two techniques were statistically equivalent but in the remainder, HCL-Pumice compound was more significantly effective (P<0.05 .   Conclusion: HCL-Pumice compound reduces the severity of the discoloration of the teeth. Shahed herbal compound

  5. Relationship between natural radioactivity and rock type in the Van lake basin - Turkey

    International Nuclear Information System (INIS)

    Tolluoglu, A. U.; Eral, M.; Aytas, S.


    The Van Lake basin located at eastern part of Turkey. The Van lake basin essentially comprises two province, these are namely Van and Bitlis. The former geochemistry research indicated that the uranium concentrations of Van lake water and deep sediments are 78-116 ppb and 0.1-0.5 ppm respectively. Uranium was transported to Van Lake by rivers and streams, flow through to outcrops of Paleozoic Bitlis Massive, and young Pleistocene alkaline/calkalkaline volcanic rocks. This study focused on the revealing natural radioactivity and secondary dispersion of radioactivity related to rock types surface environments in the Van Lake Basin. The Van Lake Basin essentially subdivided into three different parts; the Eastern parts characterized by Mesozoic basic and ultra basic rocks, southern parts dominated by metamorphic rocks of Bitlis Massive, Western and Northwestern parts covered by volcanic rocks of Pleistocene. Volcanic rocks can be subdivided into two different types. The first type is mafic rocks mainly composed of basalts. The second type is felsic rocks represented by rhyolites, dacites and pumice tuff. Surface gamma measurements (cps) and dose rate measurements (μR/h) show different values according to rock type. Surface gamma measurement and surface dose rate values in the basaltic rocks are slightly higher than the average values (130 cps, 11 μR/h). In the felsic volcanic rocks such as rhyolites and dacites surface gamma measurement values and surface dose rate values, occasionally exceed the background. Highest values were obtained in the pumice tuffs. Rhyolitic eruptions related to Quaternary volcanic activity formed thick pumice (natural glassy froth related to felsic volcanic rocks and exhibit spongy texture) sequences Northern and Western part of Van Lake basin. The dose rate of pumice rocks was measured mean 15 μR/h. The highest value for surface gamma measurements was recorded as 200 cps. The pumice has very big water capacity, due to porous texture of

  6. Destrucción de tierras en el flanco oriental del Nevado de Toluca, el caso de la cuenca del arroyo El Zaguán

    Directory of Open Access Journals (Sweden)

    José Luis Palacio-Prieto


    Full Text Available Changes in landuse and the presence of an erodible lithology (pumice lapilli are the main factors controlling the accelerated erosion in the eastern slope of the Nevado de Toluca volcano, state of Mexico. A detailed geomorphological study of a small catchment allowed the recognition of several unstable sectors along the catchment, requiring prior attention in order to avoid problems due to silting in dams, roads and towns. Among the uns­table sectors, first order streams and external portions in mean­ders developed in pumice lahars and tephra ace included.

  7. 75 FR 36023 - Approval and Promulgation of Implementation Plans; Designation of Areas for Air Quality Planning... (United States)


    ... and Coso mountain ranges. The China Lake Naval Air Weapons Station (China Lake NAWS) covers most of... Stationary Sources: --California Lightweight Pumice 167 --China Lake Naval Air Weapons Station 84 [[Page... emissions. The largest stationary source contributor is Coso Operating Company, a geothermal, wind and solar...

  8. Explosive eruptive history of Pantelleria, Italy: Repeated caldera collapse and ignimbrite emplacement at a peralkaline volcano (United States)

    Jordan, Nina J.; Rotolo, Silvio G.; Williams, Rebecca; Speranza, Fabio; McIntosh, William C.; Branney, Michael J.; Scaillet, Stéphane


    A new, pre-Green Tuff (46 ka) volcanic stratigraphy is presented for the peralkaline Pantelleria Volcano, Italy. New 40Ar/39Ar and paleomagnetic data are combined with detailed field studies to develop a comprehensive stratigraphic reconstruction of the island. We find that the pre-46 ka succession is characterised by eight silica-rich peralkaline (trachyte to pantellerite) ignimbrites, many of which blanketed the entire island. The ignimbrites are typically welded to rheomorphic, and are commonly associated with lithic breccias and/or pumice deposits. They record sustained radial pyroclastic density currents fed by low pyroclastic fountains. The onset of ignimbrite emplacement is typically preceded (more rarely followed) by pumice fallout with limited dispersal, and some eruptions lack any associated pumice fall deposit, suggesting the absence of tall eruption columns. Particular attention is given to the correlation of well-developed lithic breccias in the ignimbrites, interpreted as probable tracers of caldera collapses. They record as many as five caldera collapse events, in contrast to the two events reported to date. Inter-ignimbrite periods are characterised by explosive and effusive eruptions with limited dispersal, such as small pumice cones, as well as pedogenesis. These periods have similar characteristics as the current post-Green Tuff activity on the island, and, while not imminent, it is reasonable to postulate the occurrence of another ignimbrite-forming eruption sometime in the future.


    African Journals Online (AJOL)

    perlite and pumice, road metal and building stones. - g. Quaternary sediments and sedimentary rocks. Principal mineral and industrial rock occurrences are potash, sulphur, lignite, limestone, gypsum, diatomite, salt and clay. Figs 2 and 3 show the distribution of the main deposits of the principal minerals and industrial.

  10. Material and elastic properties of Al-tobermorite in ancient roman seawater concrete

    KAUST Repository

    Jackson, Marie D.; Moon, Juhyuk; Gotti, Emanuele; Taylor, Rae; Chae, Sejungrosie; Kunz, Martin; Emwas, Abdul-Hamid M.; Meral, Cagla; Guttmann, Peter; Levitz, Pierre E.; Wenk, Hans Rudolf; Monteiro, Paulo José Meleragno


    . Even so, K0, is substantially higher than calcium-aluminum-silicate-hydrate binder (C-A-S-H) in slag concrete. Based on nanoscale tomographic study, the crystal clusters form a well connected solid, despite having about 52% porosity. In the pumiceous

  11. Should ponderosa pine be planted on lodgepole pine sites? (United States)

    P.H. Cochran


    Repeated radiation frosts caused no apparent harm to the majority of lodgepole pine (Pinus contorta Dougl.) seedlings planted on a pumice flat in south-central Oregon. For most but not all of the ponderosa pine (Pinus ponderosa Dougl.) seedlings planted with the lodgepole pine, however, damage from radiation frost resulted in...

  12. Manganese nodule morphology as indicators for oceanic processes in the Central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Vineesh, T.C; Nath, B.N.; Banerjee, R.; Jaisankar, S.; Lekshmi, V.

    are found in the CIB with spheroidal, oblong, triangular, rounded, sub-rounded or irregular shapes, with irregular nodules being most common. The most common nucleus is altered basalt, while pumice, shark teeth, clay and older nodule nuclei are also present...

  13. Assessment of Current Cross-Infection Control Practices Among ...

    African Journals Online (AJOL)

    Twenty-eight respondents (34.6%) regularly wear gloves while handling dental impression. Only 20 respondents (24.7%) wear eyeglasses and face masks regularly. Most of the respondents always or often change pumice slurry, curing bath water and most rarely disinfect pliers. Most of the respondents (59.3%) had not ...

  14. Sadhana | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Effects of the different atmospheric steam curing processes on the properties of self-compacting-concrete containing microsilica · Abdulkadir Cüneyt Aydin Ali Öz Riza Polat ... Volume 41 Issue 2 February 2016 pp 253-264. The effect of blast furnace slag on the self-compactability of pumice aggregate lightweight concrete.

  15. 49 CFR 1039.11 - Miscellaneous commodities exemptions. (United States)


    ..., etc. 26 214 Wrapping paper, wrappers or coarse paper. 26 218 Sanitary tissue stock. 26 471 Sanitary... 30 111 Rubber pneumatic tires or parts. 31 Leather or leather products. 32 Clay... 32 952 15 Cinders, clay, shale expanded shale), slate or volcanic (not pumice stone), or haydrite. 33...

  16. Author Details

    African Journals Online (AJOL)

    Abebayehu, D. Vol 18 (2001) - Articles Properties Of Concrete And Masonry Blocks Made Of Locally Available Scoria And Pumice Aggregates Abstract. ISSN: 0514-6216. AJOL African Journals Online. HOW TO USE AJOL... for Researchers · for Librarians · for Authors · FAQ's · More about AJOL · AJOL's Partners · Terms ...

  17. Author Details

    African Journals Online (AJOL)

    ... proposal for structural concrete using messobo ordinary portland cement. Abstract PDF · Vol 18 (2001) - Articles Properties Of Concrete And Masonry Blocks Made Of Locally Available Scoria And Pumice Aggregates Abstract · Vol 17 (2000) - Articles Insurance requirements and practices of Ethiopia's construction sector

  18. The effects of different warm stratification periods on the seed ...

    African Journals Online (AJOL)



    Sep 11, 2009 ... the climate chamber for 10, 11 and 12 weeks, seeds were transferred in plastic bags including pumice medium and left at 5°C. After complete dormancy, seeds were transferred to climate room at 22°C for germination. Statistical analysis. The data were analyzed using two-way (factorial) ANOVA. Signifi-.

  19. The Te Rere and Okareka eruptive episodes : Okataina Volcanic Centre, Taupo Volcanic Zone, New Zealand

    International Nuclear Information System (INIS)

    Nairn, I.A.


    The Te Rere and Okareka eruptive episodes occurred within the Okataina Volcanic Centre at c. 21 000 and 18 000 yr B.P., respectively. The widespread rhyolitic pumice fall deposits of Te Rere Ash (volume 5 km 3 ) and Okareka Ash (6 km 3 ) are only rarely exposed in near-source areas, and locations of their vent areas have been uncertain. New exposures and petrographic and chemical analyses show that the Te Rere episode eruptions occurred from multiple vents, up to 20 km apart, on the Haroharo linear vent zone. The Okareka episode eruptions occurred from vents since buried beneath the Tarawera volcanic massif. Eruption of the rhyolitic Okareka pumice fall was immediately preceded by a small basaltic scoria eruption, apparently from vents close to those for the following rhyolite eruptions. Dacitic mixed pumices scattered within the rhyolite pumice layers immediately overlying the scoria were formed by mixing of the basalt and rhyolite magmas. The Te Rere and Okareka pyroclastic eruptions were both followed by extrusion of voluminous rhyolite lavas. These eruptive episodes mark the commencement of growth of the present-day Haroharo and Tarawera volcanic complexes. (author). 27 refs., 14 figs., 6 tabs

  20. Distribution of biomass and nutrients in lodgepole pine/bitterbrush ecosystems in central Oregon. (United States)

    Susan N. Little; Laurl J. Shainsky


    We investigated the distribution of biomass and nutrients in lodgepole pine (Pinus contorta var. murryana Dougl.) ecosystems on pumice soils in south-central Oregon. Sixty-three trees were sampled to develop equations for estimating dry weights of tree crowns, boles, bark, and coarse roots from diameter at breast height and...

  1. Synthesis of morphotectonics and volcanics of the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Mukherjee, A.D.; Iyer, S.D.

    to the hydrothermal effect on the pre-existing subalkaline basalts. Besides these rocks, there is a wide occurrence of pumice of probably in situ origin. A distinct relation occurs between the morpho-tectonic forms and the volcanics. For example, in and around...

  2. 25 years of ecological change at Mount St. Helens. (United States)

    V.H. Dale; C.M. Crisafulli; F.J. Swanson


    18 May 2005 marks the 25th anniversary of the massive eruption of Mount St. Helens. This eruption involved diverse geological processes (1) that disturbed forests, meadows, lakes, an drivers (2) (see the figure). A huge landslide and searing flows of hot gases and pumic framents (pyroclastic flows) inundated 60 km2 of land, obliterating...

  3. Clast comminution during pyroclastic density current transport: Mt St Helens (United States)

    Dawson, B.; Brand, B. D.; Dufek, J.


    Volcanic clasts within pyroclastic density currents (PDCs) tend to be more rounded than those in fall deposits. This rounding reflects degrees of comminution during transport, which produces an increase in fine-grained ash with distance from source (Manga, M., Patel, A., Dufek., J. 2011. Bull Volcanol 73: 321-333). The amount of ash produced due to comminution can potentially affect runout distance, deposit sorting, the volume of ash lofted into the upper atmosphere, and increase internal pore pressure (e.g., Wohletz, K., Sheridan, M. F., Brown, W.K. 1989. J Geophy Res, 94, 15703-15721). For example, increased pore pressure has been shown to produce longer runout distances than non-comminuted PDC flows (e.g., Dufek, J., and M. Manga, 2008. J. Geophy Res, 113). We build on the work of Manga et al., (2011) by completing a pumice abrasion study for two well-exposed flow units from the May 18th, 1980 eruption of Mt St Helens (MSH). To quantify differences in comminution from source, sampling and the image analysis technique developed in Manga et al., 2010 was completed at distances proximal, medial, and distal from source. Within the units observed, data was taken from the base, middle, and pumice lobes within the outcrops. Our study is unique in that in addition to quantifying the degree of pumice rounding with distance from source, we also determine the possible range of ash sizes produced during comminution by analyzing bubble wall thickness of the pumice through petrographic and SEM analysis. The proportion of this ash size is then measured relative to the grain size of larger ash with distance from source. This allows us to correlate ash production with degree of rounding with distance from source, and determine the fraction of the fine ash produced due to comminution versus vent-fragmentation mechanisms. In addition we test the error in 2D analysis by completing a 3D image analysis of selected pumice samples using a Camsizer. We find that the roundness of PDC

  4. Waduk Parangjoho dan Songputri: Alternatif Sumber Erupsi Formasi Semilir di daerah Eromoko, Kabupaten Wonogiri, Jawa Tengah

    Directory of Open Access Journals (Sweden)

    Sutikno Bronto


    Full Text Available Semilir Formation was typically originated from products of a very explosive volcanic activity, i.e. breccias, lapillistones, and tuffs containing abundant pumice. It has a light grey to white colour and high silica andesite to dacite in composition, mainly rich in volcanic glass and quartz. Sedimentary structures of these volcanic rocks are massive, grading, planar bedding, and cross-bedding to antidunes, with grain size varies from ash (≤ 2 mm to lapilli (2 – 64 mm to bomb and block (> 64 mm. The formation is widely distributed from the west side (Pleret and Piyungan areas, Bantul Regency, Special Province of Yogyakarta until Eromoko area in the east (Wonogiri Regency, Jawa Tengah Province. Stratigraphically, the Semilir Formation underlies the Nglanggeran Formation, and overlies the Mandalika Formation in the eastern part and Kebo-Butak Formation in the western part. Geomorphological- and lithological analyses of the Semilir Formation in areas of Parangjoho and Song- putri Dams, Eromoko Sub-regency, Wonogiri Regency indicate that the two depressions were alternatively volcanic sources of the Semilir Formation in the Eromoko area. This is proved by the presence of co-ignimbrite breccias(co-ignimbrite lag fall deposits, that descriptively they are polymict breccias. This rock is characterized by a mixing of pumice and various hard rock fragments that primarily are juvenile materials (volcanic blocks, bombs, accessory-, and accidental rock fragments set in pumice-rich volcanic ash and lapilli sizes. The accessory materials came from older volcanic rocks, whereas the accidental ones were originated from basement rocks. During a caldera forming event or a destruction period of an older composite volcanic cone(s, all older rocks resting above the magma chamber were ejected to the surface by a very high magmatic pressure. Since they were heavier than the juvenile material, most accessory and

  5. Abrasive supply for ancient Egypt revealed

    International Nuclear Information System (INIS)

    Peltz, C.; Bichler, M.


    In the framework of the major research scheme 'Synchronization of Civilizations in the Eastern Mediterranean Region in the 2nd Millennium B.C' instrumental neutron activation analysis (INAA) was used to determine 30 elements in pumice from archaeological excavations to reveal their specific volcanic origin. In ancient time, the widespread pumiceous products of several eruptions in the Aegean region have been used as abrasive tools and were therefore popular trade objects. The correlation of such archaeological findings to a specific eruption of known age would therefore allow to certify a maximum age of the respective stratum ('dating by first appearance'). Pumices from the Aegean region can easily be distinguished by their trace element distribution patterns. This has been shown by previous studies of the group. The elements Al, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Tb, Th, Ti, U, V, Yb, Zr and Zn were determined in 16 samples of pumice lumps from excavations in Tell-el-Dab'a and Tell-el-Herr (Egypt). Two irradiation cycles and five measurement runs were applied. To show the accuracy of the results obtained, typical samples of the most important pumice sources in the Aegean region, particularly from Milos, Nisyros, Kos and Thera were analyzed together with the Egyptian samples of unknown origin. A reliable identification of the samples is achieved by comparing these results to the database compiled in previous studies. The geographical positions of these islands are shown. Within the error range, most of the elements determined in typical representatives of Milos, Nisyros, Kos and Santorini were in perfect agreement with values from the literature. On the basis of the Cluster graphics presented, it is possible to relate unknown pumice to its primary source, just by comparing the relation of a few elements, like Ta-Eu and Th-Hf. One concludes that all samples except one can be related to the Minoan eruption of Thera

  6. On magma fragmentation by conduit shear stress: Evidence from the Kos Plateau Tuff, Aegean Volcanic Arc (United States)

    Palladino, Danilo M.; Simei, Silvia; Kyriakopoulos, Konstantinos


    Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas-pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones

  7. Investigation of alteration zones in Garandake and Kurokawa

    Energy Technology Data Exchange (ETDEWEB)

    Kinbara, K [Geological Survey of Japan, Kawasaki; Sudo, S


    The eastern part of the Garan area contains both the Myoban and Tsukahara hot springs. The springs are associated with the Sanin Formation, and an alteration zone is present which strikes easterly. Throughout the altered area, a clear zonation of the alteration is present. The zonation runs: silicified - alunitized - kaolin/argillized - montmorillonite/zeolite. In the Kurokawa area, a total of 0.96 km/sup 2/ of altered zones were observed near Suzumejigoku and throughout Yoshikawa and Tawara. The most heavily altered areas were at Kurokawa hot springs and Yoshikawa, where alunite and kaolinite are abundant. The time of alteration is believed to be prior to the deposition of the Hisazumi pumice. Around the Kurokawa hot springs, where the water temperature is 98/sup 0/C, the alteration extends as far as the pumice.

  8. Glass inclusions in volcanic rocks in the Okinawa Trough back-arc basin: constraints on magma genesis and evolution

    Institute of Scientific and Technical Information of China (English)


    The major elemnt compositions of glass inclusions in plagioclase and pyroxene phenocrysts of basalt and pumice in the Okinawa Trough back-arc basin are determined by electron microprobe. The results indicate that basalt and pumice are cognate and respectively represent the proluots at early stages of mgmtism and at late stage of crystal fractionation. The initial magrma in the trough is rich in H2O. The variation of H2O content in magma may play an important role in the magma evolution. Plagioclase is the mineral crystallized throughout the whole magrmatic process and accumulates in the zoned magma chamber. From these features it can he inferred that the initial magma in the Okinawa Trough, whose opening began in recent years, is serious ly affected by fluid or other materials carried by subducting slab and the geocbemical feature of volcanic rocks is in some degree similar to that of lavas in island-arc environments.

  9. Study of the mineralogical transformations of granite by underground nuclear explosions

    International Nuclear Information System (INIS)

    Faure, Jean


    The object of the following communication is to prove new data about the petrographic effects of the underground nuclear explosions. It is founded on the results of trench tests in granite rock. The samples are collected by drilling and the temperature of the rock was measured in the hole. Four types of melted rocks can be sorted, grey-green glass and pumices, beige to red-brown pumices, dark lavas, dark veinlets and crushed granite. The distribution of these rocks is studied. Optical microscopy, X-rays and chemical analysis, study by electron probe, are made. The results complete previously published data. They are interesting as far as the use of nuclear explosions for industrial applications is concerned. (author)


    Directory of Open Access Journals (Sweden)

    Hanifi BİNİCİ


    Full Text Available The population in the rural area of Turkey has increased due to KKP (in Turkish Köy-Kent Proje. Most of the buildings in the area are made out of limestone and adobe. But this material does not have sufficient resistance to earthquakes. The research in the field of construction at The University of Cukurova elaborates on the mechanical properties and workability of raw materials such as fibre, wheat stem, strafor, basaltic pumice and clay. The production of bricks using a significant fraction of mixed waste from wheat and different ratios of clay mixed with fibre, strafor, cement, gypsum, lime and basaltic pumice was investigated. This paper presents the use of waste in the construction of soft bricks at the KKP. The results of this study suggests that using these materials have many advantages such as energy savings, low cost and improvements in the final properties of products.

  11. The role of mycorrhizal fungi and microsites in primary succession on Mount St. Helens. (United States)

    Titus, J; Del Moral, R


    This study was designed to examine the role of vesicular-arbuscular mycorrhizae (VAM) and microsites on the growth of pioneer species. Flat, rill, near-rock, and dead lupine microsites were created in plots in barren areas of the Pumice Plain of Mount St. Helens. VAM propagules were added to the soil in half of the plots. Six pioneer species were planted into both VAM and non-VAM inoculated microsites. Plants in dead lupine microsites were greater in biomass than those in flat, rill, and near-rock microsites. Significant effects of VAM on plant biomass did not occur. Microsites continue to be important to plant colonization on the Pumice Plain, but VAM do not yet appear to play an important role. This may be due to limited nutrient availability and the facultatively mycotrophic nature of the colonizing plant species. It is unlikely that VAM play an important role in successional processes in newly emplaced nutrient-poor surfaces.

  12. Late Holocene history of Chaitén Volcano: new evidence for a 17th century eruption (United States)

    Lara, Luis E.; Moreno, Rodrigo; Amigo, Álvaro; Hoblitt, Richard P.; Pierson, Thomas C.


    Prior to May 2008, it was thought that the last eruption of Chaitén Volcano occurred more than 5,000 years ago, a rather long quiescent period for a volcano in such an active arc segment. However, increasingly more Holocene eruptions are being identified. This article presents both geological and historical evidence for late Holocene eruptive activity in the 17th century (AD 1625-1658), which included an explosive rhyolitic eruption that produced pumice ash fallout east of the volcano and caused channel aggradation in the Chaitén River. The extents of tephra fall and channel aggradation were similar to those of May 2008. Fine ash, pumice and obsidian fragments in the pre-2008 deposits are unequivocally derived from Chaitén Volcano. This finding has important implications for hazards assessment in the area and suggests the eruptive frequency and magnitude should be more thoroughly studied.

  13. Study of the mineralogical transformations of granite by underground nuclear explosions

    Energy Technology Data Exchange (ETDEWEB)

    Faure, Jean [Commissariat a I' Energie Atomique, Centre d' Etudes de Bruyeres-le-Chatel (France)


    The object of the following communication is to prove new data about the petrographic effects of the underground nuclear explosions. It is founded on the results of trench tests in granite rock. The samples are collected by drilling and the temperature of the rock was measured in the hole. Four types of melted rocks can be sorted, grey-green glass and pumices, beige to red-brown pumices, dark lavas, dark veinlets and crushed granite. The distribution of these rocks is studied. Optical microscopy, X-rays and chemical analysis, study by electron probe, are made. The results complete previously published data. They are interesting as far as the use of nuclear explosions for industrial applications is concerned. (author)

  14. Environmental Assessment for the Joint Red Flag 󈧉 ADA Activities Nellis Air Force Base (United States)


    occur in Lincoln County include: perlite, clay, soils additives, pumice, cinder, diatomite , fluorspar, gypsum, and zeolite. Additionally, sand and...capabilities of any given species may be exceeded, which could lead to thermal distress or even irreversible thermal damage. The effects of RF... effects to soils and geology would be site specific, the proposed ADA activities would not contribute to cumulative impacts in the region. 5.2.5 Land

  15. Sadhana | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Home; Journals; Sadhana. Türkay Kotan. Articles written in Sadhana. Volume 40 Issue 4 June 2015 pp 1343-1359 Mechanical Sciences. The effect of fly ash to self-compactability of pumice aggregate lightweight concrete · Murat Kurt Abdulkadir Cüneyt Aydin Muhammed Said Gül Rüstem Gül Türkay Kotan · More Details ...

  16. Removal of selenium species from waters using various surface-modified natural particles and waste materials

    Energy Technology Data Exchange (ETDEWEB)

    Yigit, Nevzat O.; Tozum, Seda [Department of Environmental Engineering, Suleyman Demirel University, Isparta (Turkey)


    Waste red mud and natural pumice/volcanic slag particles were surface modified and their selenium adsorption from waters was investigated. Acid activation/heat treatment of original red mud (ORM) particles significantly increased their micropore and external surface area and cumulative volume of pores. Iron oxide coating of pumice/slags and acid activation of ORM decreased their pH{sub pzc} values and increased surface acidity. Selenite/selenate adsorption on iron oxide surfaces and acid activated red mud (AARM) was very fast with approximately first-order adsorption kinetics. Iron oxide coating of pumice/slag and acid activation of ORM particles significantly enhanced their selenite and selenate uptakes. Maximum Se adsorption capacities as high as 6.3 (mg Se/g adsorbent) were obtained by AARM. The extent of selenate uptakes by the surface modified particles was generally lower than those of selenite. Due to competition among Se species and other background water matrix for iron oxide adsorption sites, reduced selenite/selenate uptakes were found in natural water compared to single solute tests. Higher Se uptakes by iron oxide surfaces were found at pH 7.5 compared to pH 8.9, due to increased electrostatic repulsion among iron oxides and Se species at higher pH. The most effective adsorbents among the tested 17 different particles for Se uptake were AARM and iron oxide coated pumice. Se concentrations less than drinking water standards (5-10 {mu}g/L) can be achieved by these particles. These low-cost, natural, or recyclable waste particles appear to be promising adsorbents for Se removal after their surface modification. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  17. [Comparative studies on fissure sealing: composite versus Cermet cement]. (United States)

    Hickel, R; Voss, A


    Fifty two molars sealed with either composite or Cermet cement were compared. The composite sealant was applied after enamel etching using a rubber dam. Before sealing with Cermet cement the enamel was only cleaned with pumice powder and sodium hypochlorie and the material was applied without enamel etching. After an average follow-up of 1.6 years composite sealants proved to be significantly more reliable. Cermet cement sealings showed defects more frequently.

  18. Estimation of the radon dose in buildings by measuring the exhalation rate from building materials

    International Nuclear Information System (INIS)

    Steiner, V.; Kovler, K.; Perevalov, A.; Kelm, H.


    We review the accumulator technique using active (CRM) and passive detectors (activated charcoal and electret). We describe the ERS2 detector, an electrostatic radon sampler followed by alpha spectrometry, with improved algorithm and adapted to measure the exhalation rate from walls. The technique produces accurate results over a broad range of materials: concrete, Pumice, ceramics, tiles, granite, etc. The measured exhalation rate is the same, within errors, as measured by the standard detectors

  19. Inner structure of La Fossa di Vulcano (Vulcano Island, southern Tyrrhenian Sea, Italy) revealed by high-resolution electric resistivity tomography coupled with self-potential, temperature, and CO2 diffuse degassing measurements


    Revil , A.; Finizola , Anthony; Piscitelli , A.; Rizzo , E.; Ricci , T.; Crespy , A.; Angeletti , B.; Balasco , M.; Barde-Cabusson , Stéphanie; Bennati , L.; Boleve , A.; Byrdina , S.; Carzaniga , N.; Di Gangi , F.; Morin , Julie


    International audience; La Fossa cone is an active stratovolcano located on Vulcano Island in the Aeolian Archipelago (southern Italy). Its activity is characterized by explosive phreatic and phreatomagmatic eruptions producing wet and dry pyroclastic surges, pumice fall deposits, and highly viscous lava flows. Nine 2-D electrical resistivity tomograms (ERTs; electrode spacing 20 m, with a depth of investigation >200 m) were obtained to image the edifice. In addition, we also measured the sel...

  20. High Strength Lightweight Concrete Made with Ternary Mixtures of Cement-Fly Ash-Silica Fume and Scoria as Aggregate


    YAŞAR, Ergül; ATIŞ, Cengiz Duran; KILIÇ, Alaettin


    This paper presents part of the results of an ongoing laboratory study carried out to design a structural lightweight high strength concrete (SLWHSC) made with and without ternary mixtures of cement-fly ash-silica fume. In the mixtures, lightweight basaltic-pumice (scoria) aggregate was used. A concrete mixture made with lightweight scoria, and another lightweight scoria concrete mixture incorporating 20% fly ash and 10% silica fume as a cement replacement, were prepared. Two normal...

  1. Microabrasion as treatment of enamel fluorosis

    Directory of Open Access Journals (Sweden)

    Ana Caroline Brito


    Full Text Available There is currently a trend in favor of using fluoride as a coadjuvant in reducing caries indexes, as much in underdeveloped as in developedcountries. However, simultaneously the indexes of dental fluorosis seem to grow in an inverse proportion. This is brought about by chronic ingestion of fluoride for a prolonged length of time or in high concentration. Enamel microabrasion is an effective method to remove superficial stains caused by this condition, which affects esthetics of that tissue. The use of 18% hydrochloric acid in association with pumice, despite being a simple and low cost method, has been gradually replaced due to its potential of causing damage to periodontal tissues. Thus, this article reports the treatment of a fluorosis clinical case solved with microabrasion using phosphoric acid 37%, because its costbenefit is supposedly better than with chloridric acid. The deliberate ingestion of toothpaste was the probable cause of the tooth stains. Due to the location of the teeth and to the patient’s smile, only the six upper anterior teeth were selected to receive the proposed treatment. Four clinical sessions, with a seven days interval between each other, were carried out using 37% phosphoric acid and pumice. Under rubber dam isolation, the two first sessions consisted of rubbing the acid-pumice mix on enamel surface using a rubber cup on slow speed, and abrasive paper strips on the interproximal tooth surfaces. On the two final sessions, only finishing touches were performed using a wooden spatula to manually rub the acid-pumice paste.

  2. Production of high anti-knock gasoline

    Energy Technology Data Exchange (ETDEWEB)


    A process is described for producing gasoline of high antiknock value by separating from the gasoline of low antiknock value by treating the gasoline in the vapor phase under pressure equal to or slightly above atmospheric and at a temperature at which it does not form essentially hydrocarbons gaseous at the operating temperature and in contact with catalysts, the process being characterized by the utilization of catalysts of silicates or phosphates except pumice stone and fullers earth.

  3. Isogloss: language and legacy on Mount St. Helens (United States)

    E. Dodd


    Nothing standing aboveground today was here thirty years ago. The ground itself wasn't here. Oh, there was ground, but much of it lay below the surface where my boot soles slip a little in the loose pebbles of pumice. Rolling on loose rock and big ideas, for a moment I lose my sense of balance, glancing first at the sky above, then at the nearby peak of Mount St...

  4. Effect of different provisional cement remnant cleaning procedures including Er:YAG laser on shear bond strength of ceramics


    Zortuk, Mustafa; Gumus, Hasan Onder; Kilinc, Halil Ibrahim; Tuncdemir, Ali Riza


    PURPOSE The purpose of this study was to evaluate the effect of provisional cement removal by different dentin cleaning protocols (dental explorer, pumice, cleaning bur, Er:YAG laser) on the shear bond strength between ceramic and dentin. MATERIALS AND METHODS In total, 36 caries-free unrestored human third molars were selected as tooth specimens. Provisional restorations were fabricated and cemented with eugenol-free provisional cement. Then, disc-shaped ceramic specimens were fabricated and...

  5. Mineral resource of the month: perlite (United States)



    The article talks about perlite, which is a mineral used as an aggregate for lightweight construction products, filler for paints and horticultural soil blends. Perlite comes from viscous lava, mined and processed to produce lightweight material that competes with pumice, exfoliated vermiculite and expanded clay and shale. It is mined in about 35 countries that include Greece, Japan and the U.S. Other uses include insulation, concrete and plaster aggregate, and stonewashing.

  6. H2O Contents of Submarine and Subaerial Silicic Pyroclasts from Oomurodashi Volcano, Northern Izu-Bonin Arc (United States)

    McIntosh, I. M.; Tani, K.; Nichols, A. R.


    Oomurodashi volcano is an active shallow submarine silicic volcano in the northern Izu-Bonin Arc, located ~20 km south of the inhabited active volcanic island of Izu-Oshima. Oomurodashi has a large (~20km diameter) flat-topped summit located at 100 - 150 metres below sea level (mbsl), with a small central crater, Oomuro Hole, located at ~200 mbsl. Surveys conducted during cruise NT12-19 of R/V Natsushima in 2012 using the remotely-operated vehicle (ROV) Hyper-Dolphin revealed that Oomuro Hole contains numerous active hydrothermal vents and that the summit of Oomurodashi is covered by extensive fresh rhyolitic lava and pumice clasts with little biogenetic or manganese cover, suggesting recent eruption(s) from Oomuro Hole. Given the shallow depth of the volcano summit, such eruptions are likely to have generated subaerial eruption columns. A ~10ka pumiceous subaerial tephra layer on the neighbouring island of Izu-Oshima has a similar chemical composition to the submarine Oomurodashi rocks collected during the NT12-19 cruise and is thought to have originated from Oomurodashi. Here we present FTIR measurements of the H2O contents of rhyolitic pumice from both the submarine deposits sampled during ROV dives and the subaerial tephra deposit on Izu-Oshima, in order to assess magma degassing and eruption processes occurring during shallow submarine eruptions.

  7. Evaluation of the surface roughness of three heat-cured acrylic denture base resins with different conventional lathe polishing techniques: A comparative study. (United States)

    Rao, Duggineni Chalapathi; Kalavathy, N; Mohammad, H S; Hariprasad, A; Kumar, C Ravi


    Surface roughness promotes adhesion and colonization of denture plaque. Therefore, it is important to know the effects of polishing and finishing on the surface roughness of various acrylic resin materials. To evaluate and compare the effects of different conventional lathe polishing techniques on heat cured acrylic resins in producing surface roughness. Three different commercially available heat-cured acrylic resin materials namely DPI, Meliodent and Trevalon Hi were selected. 30 Specimens of each acrylic material (30 x 3 = 90, 10 x 60 x 2mm) were prepared and divided into 5 groups, each group consisted of 6 Nos. of specimens per material(6x3=18) and were grouped as Group A(unfinished), Group B (finished), Group C (Polishing Paste), Group D (Polishing Cake) and Group E (Pumice and Gold rouge). The resulted surface roughness (μm) was measured using Perthometer and observed under Scanning Electron Microscope. The values obtained were subjected statistical analyses. Among the materials tested, better results were obtained with Trevalon Hi followed by Meliodent and DPI. Among the polishing methods used, superior results were obtained with universal polishing paste followed by polishing cake; Pumice and Gold rouge. Although Pumice and Gold rouge values produced greater roughness value, they were well within the threshold value of 0.2 mm.

  8. Pre-eruptive conditions of the ~31 ka rhyolitic magma of Tlaloc volcano, Sierra Nevada Volcanic Range, Central Mexico (United States)

    Macias, J.; Arce, J.; Rueda, H.; Gardner, J.


    Tlaloc volcano is located at the northern tip of the Sierra Nevada Volcanic Range in Central Mexico. This Pleistocene to Recent volcanic range consists from north to south of Tlaloc-Telapón-Teyotl-Iztaccíhuatl-and- Popocatépetl volcanoes. While andesitic to barely dacitic volcanism dominates the southern part of the range (i.e. Popocatépetl and Iztaccíhuatl); dacitic and rare rhyolithic volcanism (i.e. Telapón, Tlaloc) dominates the northern end. The known locus of rhyolitic magmatism took place at Tlaloc volcano with a Plinian-Subplinian eruption that occurred 31 ka ago. The eruption emplaced the so-called multilayered fallout and pumiceous pyroclastic flows (~2 km3 DRE). The deposit consists of 95% vol. of juvenile particles (pumice + crystals) and minor altered lithics 5% vol. The mineral association of the pumice fragments (74-76 % wt. SiO2) consists of quartz + plagioclase + sanidine + biotite and rare oxides set in a glassy groundmass with voids. Melt inclusions in quartz phenocrysts suggest that prior to the eruption the rhyolitic contain ~7% of H2O and Nevado de Toluca volcano (~6 km) some 50 km to the southwest.

  9. The Ottaviano eruption of Somma-Vesuvio (8000 y B.P.): a magmatic alternating fall and flow-forming eruption (United States)

    Rolandi, G.; Maraffi, S.; Petrosino, P.; Lirer, L.


    The Ottaviano eruption occurred in the late neolithic (8000 y B.P.). 2.40 km 3 of phonolitic pyroclastic material (0.61 km 3 DRE) were emplaced as pyroclastic flow, surge and fall deposits. The eruption began with a fall phase, with a model column height of 14 km, producing a pumice fall deposit (LA). This phase ended with short-lived weak explosive activity, giving rise to a fine-grained deposit (L1), passing to pumice fall deposits as the result of an increasing column height and mass discharge rate. The subsequent two fall phases (producing LB and LC deposits), had model column heights of 20 and 22 km with eruption rates of 2.5 × 10 7 and 2.81 × 10 7 kg/s, respectively. These phases ended with the deposition of ash layers (L2 and L3), related to a decreasing, pulsing explosive activity. The values of dynamic parameters calculated for the eruption classify it as a sub-plinian event. Each fall phase was characterized by variations in the eruptive intensity, and several pyroclastic flows were emplaced (F1 to F3). Alternating pumice and ash fall beds record the waning of the eruption. Finally, owing to the collapse of a eruptive column of low gas content, the last pyroclastic flow (F4) was emplaced.

  10. Designing metallic iron based water filters: Light from methylene blue discoloration. (United States)

    Btatkeu-K, B D; Tchatchueng, J B; Noubactep, C; Caré, S


    Available water filtration systems containing metallic iron (Fe(0) filters) are pragmatically designed. There is a lack of sound design criteria to exploit the full potential of Fe(0) filters. A science-based design relies on valuable information on processes within a Fe(0) filter, including chemical reactions, hydrodynamics and their relation to the performance of the filter. The aim of this study was to establish a simple method to evaluate the initial performance of Fe(0) filters. The differential adsorptive affinity of methylene blue (MB) onto sand and iron oxide is exploited to characterize the evolution of a Fe(0)/sand system using the pure sand system as operational reference. Five systems were investigated for more than 70 days: pure sand, pure Fe(0), Fe(0)/sand, Fe(0)/pumice and Fe(0)/sand/pumice. Individual systems were characterized by the extent of changes in pH value, iron breakthrough, MB breakthrough and hydraulic conductivity. Results showed that for MB discoloration (i) pure sand was the most efficient system, (ii) hybrid systems were more sustainable than the pure Fe(0) system, and (iii) the pores of used pumice are poorly interconnected. Characterizing the initial reactivity of Fe(0) filters using MB discoloration has introduced a powerful tool for the exploration of various aspects of filter design. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Natural microbial populations in a water-based biowaste management system for space life support (United States)

    Bornemann, Gerhild; Waßer, Kai; Tonat, Tim; Moeller, Ralf; Bohmeier, Maria; Hauslage, Jens


    The reutilization of wastewater is a key issue with regard to long-term space missions and planetary habitation. This study reports the design, test runs and microbiological analyses of a fixed bed biofiltration system which applies pumice grain (16-25 mm grain size, 90 m2 /m3 active surface) as matrix and calcium carbonate as buffer. For activation, the pumice was inoculated with garden soil known to contain a diverse community of microorganisms, thus enabling the filtration system to potentially degrade all kinds of organic matter. Current experiments over 194 days with diluted synthetic urine (7% and 20%) showed that the 7% filter units produced nitrate slowly but steadily (max. 2191 mg NO3-N/day). In the 20% units nitrate production was slower and less stable (max. 1411 mg NO3-N/day). 84% and 76% of the contained nitrogen was converted into nitrate. The low conversion rate is assumed to be due to the high flow rate, which keeps the biofilm on the pumice thin. At the same time the thin biofilm seems to prevent the activity of denitrifiers implicating the existence of a trade off between rate and the amount of nitrogen loss. Microbiological analyses identified a comparatively low number of species (26 in the filter material, 12 in the filtrate) indicating that urine serves as a strongly selective medium and filter units for the degradation of mixed feedstock have to be pre-conditioned on the intended substrates from the beginning.

  12. Tephrostratigraphy of the late Quaternary record from Lake Chalco, central México (United States)

    Ortega-Guerrero, Beatriz; Caballero García, Lizeth; Linares-López, Carlos


    Lacustrine sequences in active volcanic settings preserve the record of fall-out products (tephras) from explosive volcanic activity from both proximal and distal sources. Sediments of Lake Chalco, located in the western part of the Trans Mexican Volcanic Belt, offer the opportunity to develop a detailed tephrostratigraphy of proximal and distal sources, and to provide stratigraphic marker horizons for the correlation of paleoclimate records. Here, we present major oxide glass and pumice data from 18 tephra layers interbedded in the lacustrine sediments of Chalco, from 11.5 to 31.3 cal ka BP. Tephra glass compositions range from basaltic trachyandesitic to rhyolitic. Two tephras were successfully correlated with the Tutti Frutti Plinian Eruption of Popocatépetl volcano; and two tephra layers from the Nevado de Toluca Plinian activity: the Upper Toluca Pumice and the Lower Toluca Pumice. Although the source of most of the tephras analyzed is unknown, their geochemical characterization, coupled with a robust chronology, contributes to establish a detailed tephrostratigraphy for the region. This tephra record also contributes to improving the estimated frequency of explosive volcanic activity for future hazards in the Basin of México and surrounding areas, where more than 29 million people live. Our findings estimate a recurrence interval of volcanic activity of ca. 1100 years in the interval between ca. 32 and 11.5 cal ka BP, shorter than previously estimated.

  13. Effect of different provisional cement remnant cleaning procedures including Er:YAG laser on shear bond strength of ceramics. (United States)

    Zortuk, Mustafa; Gumus, Hasan Onder; Kilinc, Halil Ibrahim; Tuncdemir, Ali Riza


    The purpose of this study was to evaluate the effect of provisional cement removal by different dentin cleaning protocols (dental explorer, pumice, cleaning bur, Er:YAG laser) on the shear bond strength between ceramic and dentin. In total, 36 caries-free unrestored human third molars were selected as tooth specimens. Provisional restorations were fabricated and cemented with eugenol-free provisional cement. Then, disc-shaped ceramic specimens were fabricated and randomly assigned to four groups of dentin cleaning protocols (n = 9). Group 1 (control): Provisional cements were mechanically removed with a dental explorer. Group 2: The dentin surfaces were treated with a cleaning brush with pumice Group 3: The dentin surfaces were treated with a cleaning bur. Group 4: The provisional cements were removed by an Er:YAG laser. Self-adhesive luting cement was used to bond ceramic discs to dentin surfaces. Shear bond strength (SBS) was measured using a universal testing machine at a 0.05 mm/min crosshead speed. The data were analyzed using a Kolmogorov Smirnov, One-way ANOVA and Tukey HSD tests to perform multiple comparisons (α=0.05). THE DENTIN CLEANING METHODS DID NOT SIGNIFICANTLY AFFECT THE SBS OF CERAMIC DISCS TO DENTIN AS FOLLOWS: dental explorer, pumice, cleaning bur, and Er:YAG laser. The use of different cleaning protocols did not affect the SBS between dentin and ceramic surfaces.

  14. Stratigraphic, Granulometric and Geochemical Studies of a Major Plinian Eruption on Dominica, Lesser Antilles (United States)

    Smith, A. L.; Daly, G.; Killingsworth, N.; Deuerling, K.; Schneider, S.; Fryxell, J. E.


    The island of Dominica, located in the center of the Lesser Antilles island arc has witnessed, probably within the last 100,000 years, three large volume Plinian eruptions. One of these, associated with the Morne Diablotins center, forms the Grande Savane pyroclastic flow fan, that extends off shore as a distinctive submarine feature for a distance of at least 14 km. Stratigraphical studies of road cuts and well-exposed sea cliffs indicate the fan is composed of an older unit composed of reworked deposits at the base followed by at least four sequences, based on the presence of paleosols, of block and ash flow deposits. The upper unit of block and ash flows is overlain, with no evidence of an intervening paleosol, by a sequence of ignimbrites and pumiceous surges (representing the Plinian eruption). There is no evidence of an initial Plinian fall deposit, so the lowest bed in the succession is an ignimbrite with a highly irregular base that cuts into the underlying block and ash flow deposits, the upper parts of which are colored red due to thermal effects. This lowest ignimbrite is welded (minimum porosity of 15%) throughout its thickness (maximum thickness of greater than 21 m), although a few outcrops near the margins show a thin (20-30 cm) non-welded but lithified zone beneath the welded zone. The remainder of the sequence is composed of lithified ignimbrite that can be subdivided into three units separated by pumiceous surge layers. The ignimbrite succession is overlain, with no obvious break, by a thin fall deposit containing accretionary lapilli and gas cavities, followed by three pumiceous surge deposits (lower and upper show planar stratification and the middle surge shows massive bedding); towards the north the upper two surge deposits are separated by thin pumiceous lapilli fall and ash fall deposits. This surge sequence extends laterally outside of the main area of ignimbrite deposition. The pumice clasts from the ignimbrites are andesitic in

  15. The evaluation of the growth and nutrition conditions of the garden nursery material Prunus and Thuja according to the use of various cultivating substrates and systems of fertilization

    Directory of Open Access Journals (Sweden)

    Tomáš Meisl


    Full Text Available The influence of different peat-based cultivating substrates and the system of fertilization on the nutrition conditions and growth characteristics of garden nursery material Prunus kurilensis ‘Brillant’ and Thuja occidentalis ‘Smaragd’ were observed during a three-year experiment. Three kinds of substrates were tested: peat + pumice (pemza proportioned 8:2, fermented bark + peat + clay proportioned 4:4:2, fermented bark + peat + clay proportioned 4:4:2. Two fertilizers were used: granular controlled-release fertilizer – Osmocote, and watersoluble with irrigation – Kristalon.A higher content of macroelements was observed in the leaves of Prunus. The only exception was potassium, the quantity of which was demonstrably higher in the assimilative organs of Thuja. On the contrary, Thuja had a higher content of trace elements except for copper and iron. The highest contents of nitrogen, potassium, and iron were statistically proved in leaves of woods grown in the substrate of peat and pumice due to its higher sorption capability. A better nutrition conditions in almost all nutrients were observed at plants where the gradually effective Osmocote was applied. The exceptions were calcium, molybdenum and iron, the content of which was, on the contrary, higher where Kristalon with irrigation were used. Physical characteristics of the growing substrates that contained bark were significantly worse at the end of the experiment. This was even intensified by clay. The substrate containing peat and pumice were less stable. The best growth was observed in woods grown in the substrate of peat and pumice, ie where peat was not substituted by bark, and, at the same time, expanded clay was used instead of classic clay. Higher values of growth characteristics were demonstratively observed after the Osmocote fertilizer was applied.The results of the experiment reveal that pumice should be recommended, pemza with a high sorption capability and the

  16. Titanium zoning and diffusion chronometry reveal dynamic and late-stage quartz growth in the Youngest Toba Tuff, Indonesia (United States)

    Tierney, C. R.; Reid, M. R.; Burns, D. H.; Costa Rodriguez, F.; Chesner, C. A.


    The enormous 74 ka Youngest Toba Tuff (YTT) ejected 2800 km3 of compositionally zoned (68-77 wt.% SiO2) ignimbrite and co-ignimbrite ash. Titanium zoning within YTT quartz records a dynamic growth history, and sometimes concludes with a final growth stage under different conditions. We investigated the timescales of quartz growth using diffusion chronometry, and determined whether the last stage of crystallization was the result of a discrete and chamber-wide magmatic event. This work offers insight into the dynamics and timescales of storage and remobilization of voluminous silicic magmas - an important consideration for hazards assessment. High-resolution (1 µm steps) hyperspectral CL was mapped from 5-20 quartz crystals from each of five pumices spanning the YTT compositional spectrum. CL intensity was calibrated to Ti concentration via EPMA, and numerically modeled time-dependent diffusional relaxation curves where fit to concentration profiles across zone boundaries. CL-bright/high-Ti rims are found in quartz from all samples, but become less common and have lower Ti concentrations with increasing host pumice silica content (e.g., 70 ppm vs 50 ppm). Some large crystals contain distinct CL-bright interior zones with similar Ti concentration to the rims. Onset of growth of CL-bright rims commenced between 15 and 100 years before eruption, and interior bands between 30 and 1500 years. Neither rim nor interior ages correlate significantly with host pumice silica. Rim growth on quartz evidently occurred closer to eruption than a previous estimate of several decades to centuries for quartz from a single YTT pumice (Matthews et al., 2012). The similar timing for the onset of high-Ti quartz rim growth across all samples suggests a marked and temporally discrete magmatic event in the years to decades prior to eruption and may be recording the chamber-wide influence of magmatic recharge or remobilization. High-Ti interior zones likely record older recharge events that

  17. Geochemical characterization of mid-distal Nisyros tephra on Datça peninsula (southwestern Anatolia) (United States)

    Gençalioğlu-Kuşcu, Gonca; Uslular, Göksu


    We present new distal records of tephra deposits that overly the Kos ignimbrite in seven locations of Datça peninsula. Tephra in one of these locations were previously associated with Nisyros Kyra sub-unit based only on the field characteristics. We use different proxies such as field observations, petrography, mineral, glass, and whole-rock chemistry in order to characterize and correlate the previously and recently identified pumice fall deposits on Datça. The total thickness of the fall deposit reaches to 3.5 m. The size of the pumice clasts is generally within the range of lapilli, and they have vitrophyric texture consisting mainly of plagioclase (andesine to labradorite) with scarce clinopyroxene (diopside to augite), olivine (Fo48-50), amphibole (magnesio-hastingsite), and biotite crystals. Amphibole is a ubiquitous phenocryst in all Datça tephra units and used as a criterion for the correlation. Glass major element analyses by EMPA reveal two different groups with andesitic and dacitic compositions. Difference in silica content (up to ca. 4 wt%) detected in the same specimen also designates the heterogeneity in pumice glass. This heterogeneity in glass composition is also supported by the frequent occurrence of banded pumice clasts in Datça tephra. Whole-rock composition of the pumice is mainly andesitic with calc-alkaline affinity. Multi-element patterns on primitive-mantle normalized diagram display typical arc-magmatism signature (i.e. depletion in Nb, Ta, Ti, and P). In order to check and eliminate the potential alternatives, we compared the distal deposits on Datça not only with Kyra, but also with other Nisyros tephra units. Yet, Kyra is the only unit that has comparable depositional characteristics, calcic amphibole crystals, andesitic-dacitic glass and whole-rock chemistry, and distal tephra deposits on neighboring islands (Tilos and Chalki). Therefore, we associate Datça tephra deposits with some proximal Kyra subunits of intermediate

  18. Perhitungan Volume dan Karakterisasi Material Endapan Erupsi Gunungapi Kelud Tahun 2014, di Sungai Bladak Bagian Hulu Dengan Metode Geofisika

    Directory of Open Access Journals (Sweden)

    Anastasia Neni Candra Purnamasari


    Full Text Available ABSTRAK Erupsi Gunungapi Kelud pada 13 Februari 2014 menghasilkan material endapan di hulu Sungai Bladak dalam jumlah yang sangat besar.Endapan hasil erupsi yang terdapat di hulu sungai berpotensi sebagai material lahar bagi wilayah di hilir.Upaya mitigasi untuk mengurangi bencana banjir lahar memerlukan informasi volume material endapan. Selain itu, informasi karakteristik fisik material endapan juga penting untuk pemanfaatannya bagi masyarakat. Penelitian untuk mengetahui volume material endapan dilakukan dengan menggunakan metode geofisika pada pengukuran ketebalan dari material endapan.Metode geofisika yang digunakan adalah metode mikroseismik dan metode seismik refraksi.Hasil yang didapatkan dari pengolahan data lapangan mikroseismik adalah nilai frekuensi natural (f0 dari setiap titik pengukuran mikroseismik. Hasil yang didapatkan dari pengolahan data lapangan seismik refraksi adalah kecepatan gelombang P dari material endapan, dimana kecepatan gelombang P akan diturunkan sehingga didapatkan kecepatan gelombang S. Kecepatan gelombang S akan digunakan untuk penghitungan ketebalan material endapan yang digabungkan dengan nilai frekuensi natural dengan rumus h=Vs/4f0. Berdasarkan ketebalan material endapan yang didapatkan dari hasil penghitungan setiap titik mikroseismik, kemudian dibuat kontur ketebalan material endapan dan dilakukan penghitungan volume material endapan. Karakterisasi material endapan dilakukan dengan cara menghitung persentase pumice dan nonpumice secara fisual menggunakan foto lapangan. Ketebalan endapan pumice di permukaan lahan dianalisis persebarannya menurut satuan-satuan lereng. Volume material endapan yang didapatkan dari hasil penelitian sebesar 27,6 juta m3. Hasil karakterisasi material diketahui bahwa pumice pada material endapan yang ada di hulu Sungai Bladak 91,82 % dan sisanya 7,18 % adalah nonpumice. Jumlah pumice yang sangat banyak tersebut merupakan sumberdaya alam yang bernilai ekonomi tinggi. Pumice dapat

  19. The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska (United States)

    Hildreth, W.


    On June 6-8, 1912, ??? 15 km3 of magma erupted from the Novarupta caldera at the head of the Valley of Ten Thousand Smokes (VTTS), producing ??? 20 km3 of air-fall tephra and 11-15 km3 of ash-flow tuff within ??? 60 hours. Three discrete periods of ash-fall at Kodiak correlate, respectively, with Plinian tephra layers designated A, CD, and FG by Curtis (1968) in the VTTS. The ash-flow sequence overlapped with but outlasted pumice fall A, terminating within 20 hours of the initial outbreak and prior to pumice fall C. Layers E and H consist mostly of vitric dust that settled during lulls, and Layer B is the feather edge of the ash flow. The fall units filled and obscured the caldera, but arcuate and radial fissures outline a 6-km2 depression. The Novarupta lava dome and its ejecta ring were emplaced later within the depression. At Mt. Katmai, 10 km east of the 1912 vent, a 600-m-deep caldera of similar area also collapsed at about this time, probably owing to hydraulic connection with the venting magma system; but all known ejecta are thought to have erupted at Novarupta. Mingling of three distinctive magmas during the eruption produced an abundance of banded pumice, and mechanical mixing of chilled ejecta resulted in deposits with a wide range of bulk composition. Pumice in the initial fall unit (A) is 100% rhyolite, but fall units atop the ash flow are > 98% dacite; black andesitic scoria is common only in the ash flows and in near-vent air-fall tephra. Pumice counts show the first half of the ash-flow deposit to be 91-98% rhyolite, but progressive increases of dacite and andesite eventually reduced the rhyolitic component to 20 km to the lowermost VTTS, and deposited 1-8 m of debris there. Rhyolitic ejecta contain only 1-2% phenocrysts but andesite and dacite have 30-45%. Quartz is present and augite absent only in the rhyolite, but all ejecta contain plagioclase, orthopyroxene, titanomagnetite, ilmenite, apatite, and pyrrhotite; rare olivine occurs in the

  20. Testing to expand the rotary-mode core sampling system operating envelope

    International Nuclear Information System (INIS)

    Witwer, K.S.


    Rotary sampling using the Rotary Mode Core Sampling System (RMCSS) is constrained by what is referred to as the ''Operating Envelope''. The Operating Envelop defines the maximum downward force, maximum rotational speed and minimum purge gas flow allowed during operation of the RMCSS. The original values of 1170 lb. down force, 55 RPM rotational speed, and 30 SCFM nitrogen purge gas were determined during original envelope testing. This envelope was determined by observing the temperature rise on the bitface while drilling into waste simulants. The maximum temperature in single-shell tanks (SSTS) is considered to be approximately 9O C and the critical drill bit temperature, which is the temperature at which an exothermic reaction could be initiated in the tank waste, was previously determined to be 150 C. Thus, the drill bit temperature increase was limited to 60 C. Thermal properties of these simulants approximated typical properties of waste tank saltcake. Later, more detailed envelope testing which used a pumice block simulant, showed a notably higher temperature rise while drilling. This pumice material, which simulated a ''worst case'' foreign object embedded in the waste, has lower thermal conductivity and lower thermal diffusivity than earlier simulants. These properties caused a slower heat transfer in the pumice than in the previous simulants and consequently a higher temperature rise. The maximum downward force was subsequently reduced to 750 lb (at a maximum 55 RPM and minimum 30 SCFM purge gas flow) which was the maximum value at which the drill bit could be operated and still remain below the 60 C temperature rise

  1. Comparison of six different methods of cleaning and preparing occlusal fissure surface before placement of pit and fissure sealant: An in vitro study

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    A Agrawal


    Full Text Available Aim & Objectives : The purpose of this in vitro study was to evaluate and compare the microleakage of pit and fissure sealants after using six different preparation techniques: (a brush, (b pumice slurry application, (c bur, (d air polishing, (e air abrasion, and (f longer etching time. Material & Method : The study was conducted on 60 caries-free first premolars extracted for orthodontic purpose. These teeth were randomly assigned to six groups of 10 teeth each. Teeth were prepared using one of six occlusal surface treatments prior to placement of Clinpro" 3M ESPE light-cured sealant. The teeth were thermocycled for 500 cycles and stored in 0.9% normal saline. Teeth were sealed apically and coated with nail varnish 1 mm from the margin and stained in 1% methylene blue for 24 hours. Each tooth was divided buccolingually parallel to the long axis of the tooth, yielding two sections per tooth for analysis. The surfaces were scored from 0 to 2 for the extent of microleakage. Statistical Analysis : Results obtained for microleakage were analyzed by using t-tests at sectional level and chi-square test and analysis of variance (ANOVA at the group level. Results : The results of round bur group were significantly superior when compared to all other groups. The application of air polishing and air abrasion showed better results than pumice slurry, bristle brush, and longer etching time. Round bur group was the most successful cleaning and preparing technique. Air polishing and air abrasion produced significantly less microleakage than traditional pumice slurry, bristle brush, and longer etching time.

  2. South Aegean volcanic glass. Separation and analysis by INAA and EPMA

    International Nuclear Information System (INIS)

    Saminger, S.; Peltz, C.; Bichler, M.


    Pumice from the major volcanic sources (Milos, Nisyros, Yali, Kos and Santorini) in the South Aegean region was investigated to reveal the differences between the composition of the bulk material, which contains a certain percentage of crystallites, and the pure glass phase, which is the main constituent. The knowledge of these differences is important for the identification of vitric tephra layers found in the Eastern Mediterranean region in archaeological context, in deep sea drilling cores and lake sediments. Eruption products, deposited at some distance, show not only a decrease in their grain size, but also have usually lost their crystalline fraction due to gravity separation and consist only of glass shards. Major element distributions in such layers and in pumiceous glass are not sufficient for a reliable identification of the volcanic source, as several eruptions are known to have produced chemically very similar tephra layers in this region. Trace element data, especially of the rather immobile rare earth elements (REEs), can provide greater information on tephra originating from different volcanic eruptions. Therefore, a technique has been developed to separate the glass phase from different primary pumices to reveal differences in their trace element distributions. The concentrations of the major constituents, in particular Al, Ca, Fe, Mg, Mn, Na, Si, and Ti were determined by electron probe microanalysis (EPMA), those of Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Th, Ti, U, V, Yb and Zr by instrumental neutron activation analysis. Subtle differences between the compositions of the glass phase and the bulk material are explained by differentiation during partial crystallization. Their applicability to the classification of tephra layers is demonstrated. (author)

  3. Ignimbrite Analyses of Batur Caldera, Bali, based on 14C Dating

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    Igan S. Sutawidjaja


    Full Text Available Batur Caldera, in the northeastern part of Bali Island, is an elliptical collapse structure 13.8 by 10 km in size and another circular composite collapse structure with a diameter of 7.5 km in its centre. Two stages of the collapse were interrupted by silicic andesite lavas and domes. The first collapse was initiated by the eruption of about 84 km3 of the dacitic "Ubud Ignimbrite", about 29,300 years B.P., which caused a steep-walled depression about 1 km deep. The second ignimbrite was erupted from a large crater about the present lake, and it  produced about 19 km3 of a similar voluminous dacitic ignimbrite, called the "Gunungkawi Ignimbrite" about 20,150 years B.P. This second eruption trig- gered a second collapse, which created the central circular caldera, and formed a basin structure. Both the Ubud and Gunungkawi Ignimbrites consist of a similar dacitic composition, white to red (the most abundant nearly 90 % and dark grey to black dacitic pumice clasts. The large clasts, up to 20 cm in diameter, are in the non-welded ignimbrite, particularly in the upper part of the Gunungkawi Ignimbrite. The intracaldera ignimbrite, called the "Batur Ignimbrite" about 5 km3  in volume is a densely welded ignimbrite and generally shows typical welded features. The ignimbrite comprises at least five different flow units, separated by thin (15 - 40 cm welded pumiceous airfall deposits, with flattened pumice clasts. Another large eruption occurred about 5,500 years B.P., producing around 0.09 km3  andesitic ignimbrite. This was initiated by phreatomagmatic eruptions, indicated by thick phreatomagmatic and surge deposits, underlying the ignimbrite. The caldera and its vicinity are partly filled, and variably mantled by later eruptive products of dacitic and andesitic phreatomagmatic and airfall deposits.  

  4. Surface morphology of caldera-forming eruption deposits revealed by lidar mapping of Crater Lake National Park, Oregon- Implications for emplacement and surface modification (United States)

    Robinson, Joel E.; Bacon, Charles R.; Major, Jon J.; Wright, Heather M.; Vallance, James W.


    Large explosive eruptions of silicic magma can produce widespread pumice fall, extensive ignimbrite sheets, and collapse calderas. The surfaces of voluminous ignimbrites are rarely preserved or documented because most terrestrial examples are heavily vegetated, or severely modified by post-depositional processes. Much research addresses the internal sedimentary characteristics, flow processes, and depositional mechanisms of ignimbrites, however, surface features of ignimbrites are less well documented and understood, except for comparatively small-volume deposits of historical eruptions. The ~7,700 calendar year B.P. climactic eruption of Mount Mazama, USA vented ~50 km3 of magma, deposited first as rhyodacite pumice fall and then as a zoned rhyodacite-to-andesite ignimbrite as Crater Lake caldera collapsed. Lidar collected during summer 2010 reveals the remarkably well-preserved surface of the Mazama ignimbrite and related deposits surrounding Crater Lake caldera in unprecedented detail despite forest cover. The ±1 m lateral and ±4 cm vertical resolution lidar allows surface morphologies to be classified. Surface morphologies are created by internal depositional processes and can point to the processes at work when pyroclastic flows come to rest. We describe nine surface features including furrow-ridge sets and wedge-shaped mounds in pumice fall eroded by high-energy pyroclastic surges, flow- parallel ridges that record the passage of multiple pyroclastic flows, perched benches of marginal deposits stranded by more-mobile pyroclastic-flow cores, hummocks of dense clasts interpreted as lag deposit, transverse ridges that mark the compression and imbrication of flows as they came to rest, scarps indicating ignimbrite remobilization, fields of pit craters caused by phreatic explosions, fractures and cracks caused by extensional processes resulting from ignimbrite volume loss, and stream channels eroded in the newly formed surface. The nine morphologies presented

  5. Correlation and stratigraphic eruption age of the pyroclastic flow deposits and wide spread volcanic ashes intercalated in the Pliocene-Pleistocene strata, central Japan

    International Nuclear Information System (INIS)

    Nagahashi, Yoshitaka; Satoguchi, Yasufumi; Yoshikawa, Shusaku


    Three pyroclastic flow deposits in the Takayama and Omine area, central Honshu, are correlated to the distal widespread volcanic ashes intercalated in the Plio-Pleistocene boundary strata in central Japan. The correlation is based on these stratigraphic relationships, facies, magnetostratigraphy, petrographic properties such as mineral assemblage, refractive index and chemical composition of the volcanic glasses and orthopyroxene. As the result of these correlation, the eruption age of the proximal pyroclastic flow deposits have become clear. And precise correlation between proximal eruption units and distal depositional units is now possible. Ho-Kd 39 Tephra erupted at about 1.76 Ma, forming a co-ignimbrite ash, which deposited in the Kanto sedimentary basin. Eb-Fukuda Tephra erupted at about 1.75 Ma, and distal volcaniclastic deposit sedimented in the Kinki, Niigata and Kanto sedimentary basins. The eruptional and depositional phase are divided into the stage 1, stage 2 (early), stage 2 (late) and stage 3. Stage 1 is phreato-plinian type eruption phase, forming distal ash fall deposit. Stage 2 (early) is plinian pumice fall, intra-plinian pyroclastic flow and plinian pumice fall eruption phase, forming distal ash fall. Stage 2 (late) is final eruptional phase of the biggest pyroclastic flow of the Eb-Fukuda Tephra, forming a co-ignimbrite ash fall. Stage 3 is resedimented stage after the end of the explosive eruption. It is notable that resedimented volcaniclastic deposit reached Osaka sedimentary basin 300 km away from the eruption center. Om-SK110 Tephra erupted at about 1.65 Ma, divided into the stage 1, stage 2 and stage 3. Stage 1 is eruption phase of the plinian pumice fall and first pyroclastic flow. Stage 2 is pauses in eruption activity. Stage 3 is second pyroclastic flow phase, it is inferred that the pyroclastic flow of the stage 3 directly entered the Niigata sedimentary basin and simultaneously formed a co-ignimbrite ash. (author)

  6. Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy (United States)

    Doherty, Angela L.; Bodnar, Robert J.; De Vivo, Benedetto; Bohrson, Wendy A.; Belkin, Harvey E.; Messina, Antonia; Tracy, Robert J.


    The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo72−84) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo57−78). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO2 of 49.8 wt %) in the pumices and basaltic-andesite (average SiO2 of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.

  7. Vertical Structural Variation and Their Development of the Sanukayama Rhyolite Lava in Kozushima Island, Japan (United States)

    Furukawa, K.; Uno, K.; Kanamaru, T.; Nakai, K.


    We revealed structural development of the Pleistocene Sanukayama rhyolite lava of Kozushima Island, Japan. The good exposure, with about 130 m thick, provides valuable opportunity to understand the vertical structural variation. This exposure corresponds to the upper half of the lava. The paleomagnetic results show that the lava emplaced in subaerial condition at least in the exposed part. The vertical lithofacies are divided into the pumiceous (25-40 m thick), obsidian (40-60 m), spherulitic (30-50 m) layers from top to base. The pumiceous layer is characterized by massive foliated pumice. The foliation dips are gradually changed from gentle (10-30°) in lower part to steep (around 90°) in upper part. This shows the balloon-like morphology. The massive pumiceous layer would be generated from late stage diapiric inflation of the lava (Fink and Manley, 1987). The obsidian layer is composed of massive and welded-brecciated parts. The ductile-deformed light-colored veins, with a few mm thick, are frequently developed. In the microscopic observation, the veins are composed of broken crystals and obsidian clasts indicating fracturing of the lava followed by ductile deformation such as the RFH process (Tuffen et al., 2003). In this layer, extensive vesiculation and microlite development must have been prevented by higher load pressure and faster cooling, respectively. Consequently, they resulted in formation of the obsidian. The spherulitic layer is characterized by development of the ductile-deformed flow banding. The microscopic observation shows that the bands are formed by the spherulite trail. Furthermore, the microlites are aligned within the spherulites. In the heat-retained inner part of the lava, microlites would be developed around the healed fractures. The microlites acted as nucleation site of spherulite. In transition layer between obsidian and spherulitic layers (obsidian layer. This would be caused by high flow-induced shear arising from their rheological

  8. Pyroclast textural variation as an indicator of eruption column steadiness in andesitic Plinian eruptions at Mt. Ruapehu (United States)

    Pardo, Natalia; Cronin, Shane J.; Wright, Heather M.N.; Schipper, C. Ian; Smith, Ian; Stewart, Bob


    Between 27 and 11 cal. ka BP, a transition is observed in Plinian eruptions at Mt. Ruapehu, indicating evolution from non-collapsing (steady and oscillatory) eruption columns to partially collapsing columns (both wet and dry). To determine the causes of these variations over this eruptive interval, we examined lapilli fall deposits from four eruptions representing the climactic phases of each column type. All eruptions involve andesite to basaltic andesite magmas containing plagioclase, clinopyroxene, orthopyroxene and magnetite phenocrysts. Differences occur in the dominant pumice texture, the degree of bulk chemistry and textural variability, the average microcrystallinity and the composition of groundmass glass. In order to investigate the role of ascent and degassing processes on column stability, vesicle textures were quantified by gas volume pycnometry (porosity), X-ray synchrotron and computed microtomography (μ-CT) imagery from representative clasts from each eruption. These data were linked to groundmass crystallinity and glass geochemistry. Pumice textures were classified into six types (foamy, sheared, fibrous, microvesicular, microsheared and dense) according to the vesicle content, size and shape and microlite content. Bulk porosities vary from 19 to 95 % among all textural types. Melt-referenced vesicle number density ranges between 1.8 × 102 and 8.9 × 102 mm−3, except in fibrous textures, where it spans from 0.3 × 102 to 53 × 102 mm−3. Vesicle-free magnetite number density varies within an order of magnitude from 0.4 × 102 to 4.5 × 102 mm−3 in samples with dacitic groundmass glass and between 0.0 and 2.3 × 102 mm−3 in samples with rhyolitic groundmass. The data indicate that columns that collapsed to produce pyroclastic flows contained pumice with the greatest variation in bulk composition (which overlaps with but extends to slightly more silicic compositions than other eruptive products); textures

  9. Biomethanation of salty cheese whey using multichamber anaerobic bioreactor

    Energy Technology Data Exchange (ETDEWEB)

    Patel, Chirag; Madamwar, Datta [Sardar Patel Univ., Gujarat (India)


    To obtain enriched methane content and improve anaerobic digestion of salty cheese whey after diluting with total dairy waste water, a multichamber anaerobic bioreactor has been developed using different combination of bedding materials in different chambers. Best performance has been obtained at 37''oC under the combination of polystyrene chips, pumice stones and PVC beads as supporting materials, and operating at 2 day hydraulic retention time. Maximum gas production of 3.2 litre/litre of digester/day with methane content of 68% and 83% reduction in COD have been noticed. (Author)

  10. The Riscos Bayos Ignimbrites of the Caviahue-Copahue volcanic caldera complex, southern Andes, Argentina (United States)

    Colvin, A.; Merrill, M.; Demoor, M.; Goss, A.; Varekamp, J. C.


    The Caviahue-Copahue volcanic complex (38 S, 70 W) is located on the eastern margin of the active arc in the southern Andes, Argentina. Volcán Copahue, an active stratovolcano which hosts an active hydrothermal system, sits on the southwestern rim of the elliptical Caviahue megacaldera (17 x 15 km). The caldera wall sequences are up to 0.6 km thick and consist of lavas with 51 -69 percent SiO2 and 0.2 - 5 percent MgO as well as breccias, dikes, sills, domes and minor ignimbrites. Andesitic lava flows also occur within the caldera, and are overlain by a chaotic complex of silicic lava and intracaldera pyroclastic flow deposits. The eastern wall sequence is capped by several extracaldera ignimbrites (Riscos Bayos formation) of about 50 m maximum thickness which extend 30 km east-southeast of the caldera. Young back-arc alkali basalt scoria cones occur east of the Caviahue-Copahue volcanic complex. The eruption of the Riscos Bayos formation at about 1.1 Ma (12 km cubed) may be related to the Caviahue caldera formation, though the Riscos Bayos account for only about 7 percent of the caldera volume. The Riscos Bayos consists of three lithic-bearing flow units: a grey basal flow, a tan middle flow and a bright-white, highly indurated uppermost flow. The basal unit consists of white and grey pumice fragments, black scoria clasts, black obsidian clasts (which give it the grey color), and accidental volcanic lithics set in a matrix of ash and crystals. The middle unit is composed of large mauve pumice fragments and accidental lithics set in a fine tan ash groundmass. The uppermost unit is composed of small pink and white pumice fragments set in a matrix of fine white ash. These pumices carry quartz and biotite crystals, whereas the lower two units are orthopyroxene-bearing trachy-dacites. The Caviahue-Copahue magmas all bear arc signatures, but possibly some magma mixing between the andesitic arc magmas and basaltic back-arc magmas may have occurred. The evolved top layer

  11. 40Ar/39Ar age spectra from the KBS Tuff, Koobi Fora Formation

    International Nuclear Information System (INIS)

    McDougall, I.


    40 Ar/ 39 Ar age spectra on anorthoclase phenocrysts from three pumice clasts in the KBS Tuff yield nearly ideal flat patterns, providing good evidence that the samples have remained undisturbed since crystallization. The ages are concordant at 1.88 = 0.02 Myr, and confirm that the KBS Tuff, a key marker bed in the Koobi Fora Formation, northern Kenya, is now very well dated. These results resolve the conflict between earlier 40 Ar/ 39 Ar and conventional K-Ar dating measurements on the KBS Tuff. (author)

  12. 40Ar/39Ar age spectra from the KBS Tuff, Koobi Fora Formation. (United States)

    McDougall, Ian


    40 Ar/ 39 Ar age spectra on anorthoclase phenocrysts from three pumice clasts in the KBS Tuff yield nearly ideal flat patterns, providing good evidence that the samples have remained undisturbed since crystallization. The ages are concordant at 1.88±0.02 Myr, and confirm that the KBS Tuff, a key marker bed in the Koobi Fora Formation, northern Kenya, is now very well dated. These results resolve the conflict between earlier 40 Ar/ 39 Ar and conventional K-Ar dating measurements on the KBS Tuff.

  13. Impact of the AD 79 explosive eruption on Pompeii, II. Causes of death of the inhabitants inferred by stratigraphic analysis and areal distribution of the human casualties (United States)

    Luongo, Giuseppe; Perrotta, Annamaria; Scarpati, Claudio; De Carolis, Ernesto; Patricelli, Giovanni; Ciarallo, Annamaria


    Detailed descriptions of the effects of explosive eruptions on urban settlements available to volcanologists are relatively rare. Apart from disease and starvation, the largest number of human deaths caused by explosive eruptions in the twentieth century are due to pyroclastic flows. The relationship between the number of victims related to a specific hazard and the presence of urban settlements in the area covered by the eruption has been shown. However, pyroclastic falls are also extremely dangerous under certain conditions. These conclusions are based on archaeological and volcanological studies carried out on the victims of the well-known AD 79 eruption of Vesuvius that destroyed and buried the Roman city of Pompeii. The stratigraphic level in the pyroclastic deposit and the location of all the casualties found are described and discussed. The total number of victims recovered during the archaeological excavations amounts to 1150. Of these, 1044 well recognisable bodies plus an additional group of 100 individuals were identified based on the analysis of several groups of scattered bones. Of the former, 394 were found in the lower pumice lapilli fall deposit and 650 in the upper stratified ash and pumice lapilli pyroclastic density currents (PDCs) deposits. In addition, a tentative evaluation suggests that 464 corpses may still be buried in the unexcavated part of the city. According to the reconstruction presented in this paper, during the first phase of the eruption (August 24, AD 79) a huge quantity of pumice lapilli fell on Pompeii burying the city under 3 m of pyroclastic material. During this eruptive phase, most of the inhabitants managed to leave the city. However, 38% of the known victims were killed during this phase mainly as a consequence of roofs and walls collapsing under the increasing weight of the pumice lapilli deposit. During the second phase of the eruption (August 25, AD 79) 49% of the total victims were on the roadways and 51% inside

  14. Coarse fraction components in a red-clay sedimemt core, Central Indian Ocean Basin: Their occurrence and significance

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.; Fernandes, G.Q.; Mahender, K.

    -spherical shapes while some grains are irregular or blocky. Iron-rich fragments are nearly triangular or blocky and are 224 to 735 µm long (Fig. 8 A,B). Pumices of different shapes are 183 to 850 µm in size (Fig. 8 C-F) and sometimes have FeMn oxides.... 7 C,D). The former are 227 to 411 µm long and are either platy or bubble or Y-shaped morphology while the translucent shards are 46 to 190 µm long and are blocky or flat and stubby (Fig. 7 E,F). Coloured glass is also present of spherical to sub...

  15. Long term storage of explosively erupted magma at Nevado de Toluca volcano, Mexico (United States)

    Arce, J. L.; Gardner, J.; Macias, J. L.


    Dacitic magmas production is common in subduction-related volcanoes, occurring in those with a long period of activity as a result of the magmatic evolution. However, in this evolution many factors (i.e. crystal fractionation, assimilation, magma mixing) can interact to produce dacites. Nevado de Toluca volcano (4,680 masl; 19°09'N; 99°45'W) Central Mexico has recorded a long period of time producing dacites explosively, at least during 42 ka of activity, involving several km3 of magma, with two important Plinian-type eruptions occurred at ~21.7 ka (Lower Toluca Pumice) and ~10.5 ka (Upper Toluca Pumice). Questions like, what was the mechanism responsible to produce voluminous dacitic magma and how the volatiles and pressure changed in the Nevado de Toluca system, remain without answers. Dacites from the Lower Toluca Pumice (LTP) contain plagioclase, amphibole, iron-titanium oxides, and minor resorbed biotite, set in a glassy-vesicular matrix and the Upper Toluca Pumice (UTP) dacites contain the same mineral phases plus orthopyroxene. Ilmenite- ulvospinel geothermometry yielded a temperature of ~860°C for the LTP dacite, a little hotter than the UTP (~ 840°C). Based on hydrothermal experiments data, amphibole is stable above 100 MPa under 900°C, while plagioclase crystallizes up to 250-100 MPa at temperatures of 850-900°C. Pyroxene occurs only at pressures of 200-100 MPa with its respective temperatures of 825-900°C. Water contents in the LTP magma (2-3.5 wt %) are similar to that calculated for the UTP magma (1.3-3.6 wt %). So, there are only small changes in temperature and pressure from ~21.7 ka to 10.5 ka. It is noteworthy that orthopyroxene is absent in the LTP, however reaction-rimmed biotite (probably xenocrystic) is commonly observed in all dacites. Hence, almost all dacitic magmas seem to be stored at relatively similar pressures, water contents, and temperatures. All of these data could suggest repetitive basic magma injections producing the

  16. Volcanic activity in the Acambay Graben: a < 25 Ka subplinian eruption from the Temascalcingo volcano and implications for volcanic hazard. (United States)

    Pedrazzi, Dario; Aguirre Díaz, Gerardo; Sunyé Puchol, Ivan; Bartolini, Stefania; Geyer, Adelina


    The Trans-Mexican Volcanic Belt (TMVB) contains a large number of stratovolcanoes, some well-known, as Popocatepetl, Iztaccihuatl, Nevado de Toluca, or Colima and many others of more modest dimensions that are not well known but constitute the majority in the TMVB. Such volcanoes are, for example, Tequila, San Juan, Sangangüey, Cerro Culiacán, Cerro Grande, El Zamorano, La Joya, Palo Huerfano, Jocotitlán, Altamirano and Temascalcingo, among many others. The Temascalcingo volcano (TV) is an andesitic-dacitic stratovolcano located in the Trans-Mexican Volcanic Belt (TMVB) at the eastern part of the Acambay Graben (northwest portion of Estado de México). The TV is composed mainly by dacitic, porphyritic lavas, block and ash deposits and subordinate pumice fall deposits and ignimbrites (Roldán-Quintana et al., 2011). The volcanic structure includes a summit caldera that has a rectangular shape, 2.5×3.5 km, with the largest side oriented E-W, parallel to major normal faults affecting the edifice. The San Mateo Pumice eruption is one of the greatest paroxysmal episodes of this volcano with pumice deposits mainly exposed at the scarp of the Acambay-Tixmadeje fault and at the northern and northeastern flanks of TV. It overlies a paleosol dated at 25 Ka. A NE-trending dispersion was obtained from field data covering an area of at least 80 km2. These deposits overlie older lava flows and mud flows and are discontinuously covered and eroded by younger reworked deposits of Temascalcingo volcano. This event represents a highly explosive phase that generated a relatively thick and widespread pumice fallout deposit that may occur again in future eruptions. A similar eruption today would have a significantly impact in the region, overall due to the fact that there has been no systematic assessment of the volcanic hazard in any of the studies that have been conducted so far in the area. So, this is a pending and urgent subject that must be tackled without delay. Financed by

  17. Floating stones off El Hierro, Canary Islands: xenoliths of pre-island sedimentary origin in the early products of the October 2011 eruption (United States)

    Troll, V. R.; Klügel, A.; Longpré, M.-A.; Burchardt, S.; Deegan, F. M.; Carracedo, J. C.; Wiesmaier, S.; Kueppers, U.; Dahren, B.; Blythe, L. S.; Hansteen, T. H.; Freda, C.; Budd, D. A.; Jolis, E. M.; Jonsson, E.; Meade, F. C.; Harris, C.; Berg, S. E.; Mancini, L.; Polacci, M.; Pedroza, K.


    A submarine eruption started off the south coast of El Hierro, Canary Islands, on 10 October 2011 and continues at the time of this writing (February 2012). In the first days of the event, peculiar eruption products were found floating on the sea surface, drifting for long distances from the eruption site. These specimens, which have in the meantime been termed "restingolites" (after the close-by village of La Restinga), appeared as black volcanic "bombs" that exhibit cores of white and porous pumice-like material. Since their brief appearance, the nature and origin of these "floating stones" has been vigorously debated among researchers, with important implications for the interpretation of the hazard potential of the ongoing eruption. The "restingolites" have been proposed to be either (i) juvenile high-silica magma (e.g. rhyolite), (ii) remelted magmatic material (trachyte), (iii) altered volcanic rock, or (iv) reheated hyaloclastites or zeolite from the submarine slopes of El Hierro. Here, we provide evidence that supports yet a different conclusion. We have analysed the textures and compositions of representative "restingolites" and compared the results to previous work on similar rocks found in the Canary Islands. Based on their high-silica content, the lack of igneous trace element signatures, the presence of remnant quartz crystals, jasper fragments and carbonate as well as wollastonite (derived from thermal overprint of carbonate) and their relatively high oxygen isotope values, we conclude that "restingolites" are in fact xenoliths from pre-island sedimentary layers that were picked up and heated by the ascending magma, causing them to partially melt and vesiculate. As they are closely resembling pumice in appearance, but are xenolithic in origin, we refer to these rocks as "xeno-pumice". The El Hierro xeno-pumices hence represent messengers from depth that help us to understand the interaction between ascending magma and crustal lithologies beneath the

  18. Enhancement of eruption explosivity by heterogeneous bubble nucleation triggered by magma mingling. (United States)

    Paredes-Mariño, Joali; Dobson, Katherine J; Ortenzi, Gianluigi; Kueppers, Ulrich; Morgavi, Daniele; Petrelli, Maurizio; Hess, Kai-Uwe; Laeger, Kathrin; Porreca, Massimiliano; Pimentel, Adriano; Perugini, Diego


    We present new evidence that shows magma mingling can be a key process during highly explosive eruptions. Using fractal analysis of the size distribution of trachybasaltic fragments found on the inner walls of bubbles in trachytic pumices, we show that the more mafic component underwent fracturing during quenching against the trachyte. We propose a new mechanism for how this magmatic interaction at depth triggered rapid heterogeneous bubble nucleation and growth and could have enhanced eruption explosivity. We argue that the data support a further, and hitherto unreported contribution of magma mingling to highly explosive eruptions. This has implications for hazard assessment for those volcanoes in which evidence of magma mingling exists.

  19. K-Ar age estimate for the KBS Tuff, East Turkana, Kenya

    International Nuclear Information System (INIS)

    McDougall, I.; Maier, R.; Sutherland-Hawkes, P.; Gleadow, A.J.W.


    Stone tools and numerous vertebrate fossils including hominids, have been found in close stratigraphic proximity to the KBS Tuff, whose age has been the subject of much debate. Concordant K-Ar ages, averaging 1.89 +- 0.01 Myr, are reported on anorthoclase phenocrysts from 13 pumice clasts collected from within the KBS Tuff or its correlatives. It is believed that this age is the best estimate currently available for the time of formation of this important marker horizon within the East Turkana Basin. (author)

  20. Field-trip guide for exploring pyroclastic density current deposits from the May 18, 1980, eruption of Mount St. Helens, Washington (United States)

    Brand, Brittany D.; Pollock, Nicholas; Sarocchi, Damiano; Dufek, Josef; Clynne, Michael A.


    Pyroclastic density currents (PDCs) are one of the most dangerous phenomena associated with explosive volcanism. To help constrain damage potential, a combination of field studies, laboratory experiments, and numerical modeling are used to establish conditions that influence PDC dynamics and depositional processes, including runout distance. The objective of this field trip is to explore field relations that may constrain PDCs at the time of emplacement.The PDC deposits from the May 18, 1980, eruption of Mount St. Helens are well exposed along the steep flanks (10–30° slopes) and across the pumice plain (5–12° slopes) as far as 8 km north of the volcano. The pumice plain deposits represent deposition from a series of concentrated PDCs and are primarily thick (3–12 m), massive, and poorly sorted. In contrast, the steep east-flank deposits are stratified to cross-stratified, suggesting deposition from PDCs where turbulence strongly influenced transport and depositional processes.The PDCs that descended the west flank were largely nondepositional; they maintained a higher flow energy and carrying capacity than PDCs funneled through the main breach, as evidenced by the higher concentration of large blocks in their deposits. The PDC from the west flank collided with PDCs funneled through the breach at various points along the pumice plain. Evidence for flow collision will be explored and debated throughout the field trip.Evidence for substrate erosion and entrainment is found (1) along the steep eastern flank of the volcano, which has a higher degree of rough, irregular topography relative to the west flanks where PDCs were likely nonerosive, (2) where PDCs encountered debris-avalanche hummocks across the pumice plain, and (3) where PDCs eroded and entrained material deposited by PDCs produced during earlier phases of the eruption. Two features interpreted as large-scale (tens of meters wide) levees and a large (~200 m wide) channel scour-and-fill feature

  1. Floating stones off El Hierro, Canary Islands: xenoliths of pre-island sedimentary origin in the early products of the October 2011 eruption

    Directory of Open Access Journals (Sweden)

    V. R. Troll


    Full Text Available A submarine eruption started off the south coast of El Hierro, Canary Islands, on 10 October 2011 and continues at the time of this writing (February 2012. In the first days of the event, peculiar eruption products were found floating on the sea surface, drifting for long distances from the eruption site. These specimens, which have in the meantime been termed "restingolites" (after the close-by village of La Restinga, appeared as black volcanic "bombs" that exhibit cores of white and porous pumice-like material. Since their brief appearance, the nature and origin of these "floating stones" has been vigorously debated among researchers, with important implications for the interpretation of the hazard potential of the ongoing eruption. The "restingolites" have been proposed to be either (i juvenile high-silica magma (e.g. rhyolite, (ii remelted magmatic material (trachyte, (iii altered volcanic rock, or (iv reheated hyaloclastites or zeolite from the submarine slopes of El Hierro. Here, we provide evidence that supports yet a different conclusion. We have analysed the textures and compositions of representative "restingolites" and compared the results to previous work on similar rocks found in the Canary Islands. Based on their high-silica content, the lack of igneous trace element signatures, the presence of remnant quartz crystals, jasper fragments and carbonate as well as wollastonite (derived from thermal overprint of carbonate and their relatively high oxygen isotope values, we conclude that "restingolites" are in fact xenoliths from pre-island sedimentary layers that were picked up and heated by the ascending magma, causing them to partially melt and vesiculate. As they are closely resembling pumice in appearance, but are xenolithic in origin, we refer to these rocks as "xeno-pumice". The El Hierro xeno-pumices hence represent messengers from depth that help us to understand the interaction between ascending magma and crustal lithologies

  2. Rhyolitic calderas and centers clustered within the active andesitic belt of Ecuador's Eastern Cordillera

    Energy Technology Data Exchange (ETDEWEB)

    Mothes, Patricia A; Hall, Minard L [Instituto Geofisico, Escuela Politecnica Nacional, Quito (Ecuador)], E-mail:


    In the Ecuadorian volcanic arc a cluster of scattered rhyolitic and dacitic centers within the mainly andesitic Eastern Cordillera includes large caldera structures (Chalupas, Chacana, Cosanga) as well as smaller edifices, built upon the Paleozoic-Mesozoic metamorphic basement. At the Chacana caldera magmatism dates from 2.7 Ma to historic times. These centers erupted enormous ash flows and thick pumice lapilli falls that covered the InterAndean Valley near Quito. The role of the 50-70 km-thick crust with a notable negative gravity anomaly appears to be related to the generation of this highly silicic magmatism occurring along the crest of the Andes in the NVZ.

  3. Accessing the application of in situ cosmogenic 14C to surface exposure dating of amorphous SiO2 (United States)

    Cesta, J. M.; Goehring, B. M.; Ward, D. J.


    We assess the feasibility and utility of in situ cosmogenic 14C as a geochronometer for landforms composed of amorphous SiO2 through the comparison of 14C surface exposure ages to independently determined eruption ages on Obsidian Dome, California. Landforms composed of amorphous SiO2 phases are difficult to date by conventional cosmogenic nuclide methods due to several complications that may arise (e.g., inability to remove meteoric contamination). The onset of an increased understanding of production rates and analytical measurement of in situ 14C in SiO2 provides an opportunity to address this limitation. Obsidian Dome is a 600-year-old phreatomagmatic dome of the Mono-Inyo Craters located in Inyo County, California, and consists of vesicular pumice, obsidian, and rhyolite. Exposure ages from eight obsidian and banded pumice and obsidian surface samples range from 3947 ± 678 to 914 ± 134 years, all significantly older than the accepted radiocarbon age of 650-550 years. δ13C values for the samples range between +2.65‰ and +1.34‰ and show a negative correlation with CO2 yield. The `too old' exposure ages coupled with this negative correlation between δ13C and CO2 yield suggests the incorporation of an atmospheric component of 14C. Measurement of 14C concentrations in shielded, subsurface samples will assist in isolating the atmospheric 14C component and aid in correcting the surface exposure ages.

  4. Effect of two prophylaxis methods on marginal gap of Cl Vresin-modified glass-ionomer restorations. (United States)

    Kimyai, Soodabeh; Pournaghi-Azar, Fatemeh; Daneshpooy, Mehdi; Abed Kahnamoii, Mehdi; Davoodi, Farnaz


    Background. This study evaluated the effect of two prophylaxis techniques on the marginal gap of CI V resin-modified glass-ionomer restorations. Methods. Standard Cl V cavities were prepared on the buccal surfaces of 48 sound bovine mandibular incisors in this in vitro study. After restoration of the cavities with GC Fuji II LC resin-modified glass-ionomer, the samples were randomly assigned to 3 groups of 16. In group 1, the prophylactic procedures were carried out with rubber cup and pumice powder and in group 2 with air-powder polishing device (APD). In group 3 (control), the samples did not undergo any prophylactic procedures. Then the marginal gaps were measured. Two-way ANOVA was used to compare marginal gaps at the occlusal and gingival margins between the groups. Post hoc Tukey test was used for two-by-two comparisons. Statistical significance was set at P marginal gaps in terms of prophylactic techniques (P marginal gaps in the APD group compared to the pumice and rubber cup group, which in turn exhibited significantly larger marginal gaps compared to the control group (P marginal gaps were significant in terms of the margin type (P margins compared to the occlusal margins (P marginal gaps of Cl V resin-modified glass-ionomer restorations.

  5. Geological research for hot spring resources in the Kanno-kawa area, Tsukui-machi, Tanzawa mountains

    Energy Technology Data Exchange (ETDEWEB)


    The Kanno-kawa area is mainly composed of the following geological units: miocene submarine pyroclastic formation and its associated augite dolerite sheets, quartz diorite intrusive, and hornblende andesite dykes. The Miocene pyroclastic rocks mainly consist of tuff, tuff breccia, and agglomerate of basaltic, andestic, and dacitic composition intercalated with subordinate amounts of conglomerate, sandstone, and siltstone beds. These rocks were divided into two lithological facies: basaltic and andestic tuff and tuff breccia facies and a facies of dacitic pumice tuff with characteristic white or gray spots of siliceous pumice (2 to 35 mm in diameter). These pyroclastic rocks suffered metamorphism mainly related to the intrusion of quartz diorite. The metamorphic rocks can be divided into the following four zones: amphibolite, actinolite hornfels, pumpellyite-prehnite, and zeolite. Probably during the late stage of the metamorphism, hornblende andesite intruded along sheared zones running from NE or NNE toward SW or SSW. Above noted Miocene pyroclastic rocks, quartz diorite, and hornblende andesite also suffered a hydrothermal alteration by which many zeolite bearing veins or networks were formed. Mineral waters of the Tanzawa mountains are believed to be related to the intrusion of quartz diorite, hornblende andesite, and formation of zeolite veins. In this respect, mineral water of highly alkaline nature can be expected by deep drilling of 600 to 1,000 m at some places such as Choja-goya and Hikage-zawa of the Kanno-kawa area.

  6. Advanced treatment of biologically pretreated coal chemical industry wastewater using the catalytic ozonation process combined with a gas-liquid-solid internal circulating fluidized bed reactor. (United States)

    Li, Zhipeng; Liu, Feng; You, Hong; Ding, Yi; Yao, Jie; Jin, Chao


    This paper investigated the performance of the combined system of catalytic ozonation and the gas-liquid-solid internal circulating fluidized bed reactor for the advanced treatment of biologically pretreated coal chemical industry wastewater (CCIW). The results indicated that with ozonation alone for 60min, the removal efficiency of chemical oxygen demand (COD) could reach 34%. The introduction of activated carbon, pumice, γ-Al 2 O 3 carriers improved the removal performance of COD, and the removal efficiency was increased by 8.6%, 4.2%, 2%, respectively. Supported with Mn, the catalytic performance of activated carbon and γ-Al 2 O 3 were improved significantly with COD removal efficiencies of 46.5% and 41.3%, respectively; however, the promotion effect of pumice supported with Mn was insignificant. Activated carbon supported with Mn had the best catalytic performance. The catalytic ozonation combined system of MnO X /activated carbon could keep ozone concentration at a lower level in the liquid phase, and promote the transfer of ozone from the gas phase to the liquid phase to improve ozonation efficiency.

  7. La phase explosive précédant l'extrusion des dômes volcaniques : exemple du dôme rhyodacitique de Dikkartin Dag, Erciyes, Anatolie centrale, TurquieInitial explosive phases during extrusion of volcanic lava domes: example from rhyodacitic dome of Dikkartin Dag, Erciyes stratovolcano, Central Anatolia, Turkey (United States)

    Sen, Erdal; Aydar, Erkan; Gourgaud, Alain; Kurkcuoglu, Biltan


    The Erciyes stratovolcano, in Central Anatolia, exhibits rhyodacitic domes on its flanks that emplaced after important eruptive pyroclastic events. The changes in eruption dynamics are well defined. Measurements of density and porosity of pumices have been carried out. Initial gas content of erupted magma decreased during the first Plinian phase (units 1 to 3) and then the gas content progressively increased in U4 and in pumiceous ash flow. The latter two deposits contain bread crust bombs that become very abundant in following phreatomagmatic products. The Last Plinian phase, rich in vitreous fragments, where porosity is minimum while density is maximal, preceded the dome extrusion. Although mineralogical and chemical compositions, further thermodynamical conditions of erupted magmas did not change during the eruptive sequence, the eruption mode changed. These changes in eruption mode are the results of the degassing of magma and the meteoric water contribution to the eruption. The transition observed is as follows: Plinian, pyroclastic flow, phreatomagmatism, Plinian and extrusion. To cite this article: E. Sen et al., C. R. Geoscience 334 (2002) 27-33

  8. Hydrological performance of dual-substrate-layer green roofs using porous inert substrates with high sorption capacities. (United States)

    Wang, Xiaoou; Tian, Yimei; Zhao, Xinhua; Peng, Chenrui


    Given that the common medium in existing green roofs is a single layer composed of organic and inorganic substrates, seven pilot-scale dual-substrate-layer extensive green roofs (G1-G7), which include nutrition and adsorption substrate layers, were constructed in this study. The effectiveness of porous inert substrates (activated charcoal, zeolite, pumice, lava, vermiculite and expanded perlite) used as the adsorption substrate for stormwater retention was investigated. A single-substrate-layer green roof (G8) was built for comparison with G1-G7. Despite the larger total rainfall depth (mm) of six types of simulated rains (43.2, 54.6, 76.2, 87.0, 85.2 and 86.4, respectively), the total percent retention of G1-G7 varied between 14% and 82% with an average of 43%, exhibiting better runoff-retaining capacity than G8 based on the maximum potential rainfall storage depth per unit height of adsorption substrate. Regression analysis showed that there was a logarithmic relationship between cumulative rainfall depth with non-zero runoff and stormwater retention for G1-G4 and a linear relationship for G5-G8. To enhance the water retention capacity and extend the service life of dual-substrate-layer extensive green roofs, the mixture of activated charcoal and/or pumice with expanded perlite and/or vermiculite is more suitable as the adsorption substrate than the mixture containing lava and/or zeolite.

  9. BAHAN PENYERAP KMnO4 DAN ASAM L-ASKORBAT DALAM PENGEMASAN AKTIF (ACTIVE PACKAGING UNTUK MEMPERPANJANG MASA SIMPAN DAN MEMPERTAHANKAN MUTU BUAH DUKU (Lansium domesticum Corr. [Adsorbers for KMnO4 and L-Ascorbic Acid in the Active Packaging to Prolong the Shelve-Life and Maintain the Quality of Lanzone (Lansium domesticum Corr. Fruits

    Directory of Open Access Journals (Sweden)

    Soesiladi E Widodo


    Full Text Available To develop an active packaging of lanzone (Lansium domisticum Corr. Fruits, KmnO4 as an ethylene scavenger and L-ascorbic acid as an oxygent scavenger were inserted into packaging. As direct contact of KmnO4 with agricultural product was not recommended and due to the liquid characteristic of both scavenger was carried out. This research was aimed at finding out the best adsorbers for KmnO4, L-ascorbic acid, and their combination in an active packaging to prolog the shelve-life and to maintain the quality of lanzone fruits. The result showed that 1 among the four adsorbers tested, pumice could was the best alternative as a KmnO4 or L-ascorbic acid adsorbers, and 2 spon and pumice were the best alternative adsorber for the combination of KmnO4 or L-ascorbic acid. Both adsorber were effective in prolonging the shelve-live (8-11 days longer than with out packaging and as good as using silica gel and vermiculite and maintaining the quality of lanzone fruits.

  10. Effect of Different Prophylaxis Methods on Microleakage of Microfilled Composite Restorations

    Directory of Open Access Journals (Sweden)

    Soodabeh Kimyai


    Full Text Available Background and aims. This study was aimed at evaluating the effect of different prophylaxis methods on microleakage of microfilled composite restorations. Materials and methods. In this in vitro study, class V cavities were prepared on buccal surfaces of 84 bovine teeth. The teeth were restored with Tetric N-Bond adhesive and Heliomolar composite resin. Subsequent to a thermocycling procedure and three months of storage in distilled water, the teeth were randomly assigned to four groups (n=21: (1 prophylaxis with a rubber cup and pumice; (2 prophylaxis with a brush and pumice; (3 prophylaxis with air/powder polishing device; and (4 no prophylaxis (the control group. Then the teeth were immersed in 2% basic fuchsin for 24 hours and sectioned for microleakage evaluation under a stereomicroscope. Data were analyzed using Kruskal-Wallis and Wilcoxon Signed Ranks tests. Statistical significance was defined at p<0.05. Results. There were no statistically significant differences in occlusal and gingival microleakage between the groups (p=0.996 and p=0.860, respectively. In all the groups gingival margins exhibited significantly higher microleakage values compared to occlusal margins (p<0.0005. Conclusion. Prophylaxis methods had no adverse effect on marginal leakage of microfilled composite resin restorations.

  11. Les grandes étapes d'évolution d'un volcan andésitique composite: Exemple du Nevado de Toluca (Méxique) (United States)

    Cantagrel, J. M.; Robin, C.; Vincent, P.


    The Nevado de Toluca, in the middle of the Mexican volcanic belt, has been built by two very dissimilar phases. The first one that lasted more than one million years is mainly andesitic. Numerous massive and autobrecciated lava flows of this phase pass outwards into thick conglomeratic formations. The volume of this primitive volcano represents the essential part of the Nevado. After an intense periode of erosion, the second phase is of very short duration (about 100.000 years) and is dacitic in nature. Three main episode can be distinguished: 1. Eruption of important ash and pumice pyroclastic flows related to caldera collapse above a shallow magmatic reservoir. 2. Extrusions of several dacitic domes within and outside the caldera with numerous associated «nuées ardentes» surrounding the volcano. 3. Plinian eruption leading to widespread pumiceous air-fall and to the opening of the present crater inside the caldera. Extrusion of a new small dacitic dome and late phreatic explosions. This second sequence of events can be interpreted as the progressive emptying of the crustal magmatic chamber without refilling by a new magma supply. The most recent activity in the area is represented by monogenic cones and flows of basic andesites outside the central vent system of the Nevado.

  12. Study on Soil Mobility of Two Neonicotinoid Insecticides

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    Mária Mörtl


    Full Text Available Movement of two neonicotinoid insecticide active ingredients, clothianidin (CLO and thiamethoxam (TMX, was investigated in different soil types (sand, clay, or loam and in pumice. Elution profiles were determined to explore differences in binding capacity. Soil characterized by high organic matter content retained the ingredients, whereas high clay content resulted in long release of compounds. Decrease in concentration was strongly influenced by soil types: both CLO and TMX were retained in loam and clay soils and showed ready elution through sandy soil and pumice. Elution capability of the active ingredients in sandy soil correlated with their water solubility, indicating approximately 30% higher rapidity for TMX than for CLO. Soil organic carbon-water partitioning coefficients (Koc determined were in good agreement with literature values with somewhat lower value for CLO in sandy soil and substantially higher values for TMX in clay soil. High mobility of these neonicotinoid active ingredients in given soil types urges stronger precautionary approach taken during their application.

  13. Surface morphology changes of acrylic resins during finishing and polishing phases

    Directory of Open Access Journals (Sweden)

    Glaucio Serra


    Full Text Available INTRODUCTION: The finishing and polishing phases are essential to improve smoothness and shining on the surface of acrylic resins used to make removable orthodontic appliances. A good surface finishing reduces roughness, which facilitates hygiene, prevents staining and provides greater comfort to the patients. OBJECTIVE: The aim of this paper was to analyze the changes on surface morphology of acrylic resins during finishing and polishing phases. METHODS: Thirty discs (10 mm in diameter and 5 mm in length were made with acrylic resin and randomly divided into ten groups. The control group did not receive any treatment while the other groups received gradual finishing and polishing. The last group received the entire finishing and polishing procedures. Surface morphology was qualitatively analyzed through scanning electron microscopy and quantitatively analyzed through a laser profilometer test. RESULTS: The acrylic resin surfaces without treatment showed bubbles which were not observed in the subsequent phases. Wearing out with multilaminated burs, finishing with wood sandpaper and finishing with water sandpaper resulted in surfaces with decreasing irregularities. The surfaces that were polished with pumice and with low abrasive liquids showed high superficial smoothness. CONCLUSION: Highly smooth acrylic resin surfaces can be obtained after mechanical finishing and polishing performed with multilaminated burs, wood sandpaper, water sandpaper, pumice and low abrasive liquids.

  14. Qualitative and quantitative evaluation of human dental enamel after bracket debonding: a noncontact three-dimensional optical profilometry analysis. (United States)

    Ferreira, Fabiano G; Nouer, Darcy F; Silva, Nelson P; Garbui, Ivana U; Correr-Sobrinho, Lourenço; Nouer, Paulo R A


    The aim of this study was to undertake a qualitative and quantitative evaluation of changes on enamel surfaces after debonding of brackets followed by finishing procedures, using a high-resolution three-dimensional optical profiler and to investigate the accuracy of the technique. The labial surfaces of 36 extracted upper central incisors were examined. Before bonding, the enamel surfaces were subjected to profilometry, recording four amplitude parameters. Brackets were then bonded using two types of light-cured orthodontic adhesive: composite resin and resin-modified glass ionomer cement. Finishing was performed by three different methods: pumice on a rubber cup, fine and ultrafine aluminum oxide discs, and microfine diamond cups followed by silicon carbide brushes. The samples were subsequently re-analyzed by profilometry. Wilcoxon signed-rank test, Kruskal-Wallis test (p enamel roughness when diamond cups followed by silicon carbide brushes were used to finish surfaces that had remnants of resin-modified glass ionomer adhesive and when pumice was used to finish surfaces that had traces of composite resin. Enamel loss was minimal. The 3D optical profilometry technique was able to provide accurate qualitative and quantitative assessment of changes on the enamel surface after debonding. Morphological changes in the topography of dental surfaces, especially if related to enamel loss and roughness, are of considerable clinical importance. The quantitative evaluation method used herein enables a more comprehensive understanding of the effects of orthodontic bonding on teeth.

  15. The mechanisms of fine particle generation and electrification during Mount St. Helens volcanic eruption (United States)

    Cheng, R. J.


    Microscopical investigation of volcanic ash collected from ground stations during Mount St. Helens eruptions reveal a distinctive bimodel size distribution with high concentrations of particle ranges at (1) 200-100 microns and (2) 20-0.1 microns. Close examination of individual particles shows that most larger ones are solidified magma particles of porous pumice with numerous gas bubbles in the interior and the smaller ones are all glassy fragments without any detectable gas bubbles. Elemental analysis demonstrates that the fine fragments all have a composition similar to that of the larger pumice particles. Laboratory experiments suggest that the formation of the fine fragments is by bursting of glassy bubbles from a partially solidified surface of a crystallizing molten magma particle. The production of gas bubbles is due to the release of absorbed gases in molten magma particles when solubility decreases during phase transition. Diffusion cloud chamber experiments strongly indicate that sub-micron volcanic fragments are highly hygroscopic and extremely active as cloud condensation nuclei. Ice crystals also are evidently formed on those fragments in a supercooled (-20 C) cloud chamber. It has been reported that charge generation from ocean volcanic eruptions is due to contact of molten lava with sea water. This seems to be insufficient to explain the observed rapid and intense lightning activities over Mount St. Helens eruptions. Therefore, a hypothesis is presented here that highly electrically charged fine solid fragments are ejected by bursting of gas bubbles from the surface of a crystallizing molten magma particles.

  16. LA-ICP-MS Pb-U Dating of Young Zircons from the Kos-Nisyros Volcanic Centre, SE Aegean Arc (Greece) (United States)

    Guillong, M.; Von Quadt, A.; Peytcheva, I.; Bachmann, O.


    Zircon Pb-U dating has become a key technique for answering many important questions in geosciences. This paper describes a new LA-ICP-MS approach. We show, using previously dated samples of a large quaternary rhyolitic eruption in the Kos-Nisyros volcanic centre (the 161 ka Kos Plateau Tuff), that the precision of our LA-ICP-MS method is as good as via SHRIMP, while ID-TIMS measurements confirm the accuracy. Gradational age distribution over >140 ka of the Kos zircons and the near-absence of inherited cores indicate near-continuous crystallisation in a growing magma reservoir with little input from wall rocks. Previously undated silicic eruptions from Nisyros volcano (Lower Pumice, Nikia Flow, Upper Pumice), which are stratigraphically constrained to have happened after the Kos Plateau Tuff, are dated to be younger than respectively 124 ± 35 ka, 111 ± 42 ka and 70 ± 24 ka. Samples younger than 1 Ma were corrected for initial thorium disequilibrium using a new formula that also accounts for disequilibrium in 230Th decay. Guillong, M. et al., 2014, JAAS, 29, p. 963-967; doi: 10.1039/c4ja00009a.

  17. Fragmentation, nucleation and migration of crystals and bubbles in the Bishop Tuff rhyolitic magma

    Energy Technology Data Exchange (ETDEWEB)

    Gualda, G.; Cook, D.L.; Chopra, R.; Qin, L.; Anderson, A.T.; Rivers, M. (UC)


    The Bishop Tuff (USA) is a large-volume, high-silica pyroclastic rhyolite. Five pumice clasts from three early stratigraphic units were studied. Size distributions were obtained using three approaches: (1) crushing, sieving and winnowing (reliable for crystals >100 {micro}m); (2) microscopy of 1 mm{sup 3} fragments (preferable for crystals <100 {micro}m); and (3) computerised X-ray microtomography of {approx}1 cm{sup 3} pumice pieces. Phenocryst fragments coated with glass are common, and the size distributions for all crystals are concave-upward, indicating that crystal fragmentation is an important magmatic process. Three groups are recognised, characterised by: (1) high-density (0.759-0.902 g cm{sup -3}), high-crystal content (14.4-15.3 wt.%) and abundant large crystals (>800 {micro}m); concave-downward size distributions for whole crystals indicate late-stage growth with limited nucleation, compatible with the slow cooling of a large, gas-saturated, stably stratified magma body; (2) low-density (0.499 g cm{sup -3}), low-crystal content (6.63 wt.%) and few large crystals; the approximately linear size distribution reveals that nucleation was locally important, perhaps close to the walls; and (3) intermediate characteristics in all respects. The volumetric fraction of bubbles inversely correlates with the number of large crystals. This is incompatible with isobaric closed-system crystallisation, but can be explained by sinking of large crystals and rise of bubbles in the magma.

  18. Geology of the region of Guadalajara, Mexico, and its relationships with processes of subsidence (United States)

    Suarez-Plascencia, C.; Delgado-Argote, L. A.; Nuñez-Cornu, F. J.; Sanchez, J. J.


    The city of Guadalajara, Mexico, began an accelerated urban growth in early 1950. During a span of 25 years a large number of gullies were artificially filled, with the aim of incorporating new areas for urbanization, particularly in the areas north and west of the city. These gullies originally formed a complex dendritic-type system, whose evolution may be associated with faults or fracture zones whose current identification are only possible based on escarpments along the Canyon of the Rio Grande de Santiago (CRGS), north of Guadalajara. Reports of affectations documented in the 80's described subsidence in buildings and infrastructure, a process that has been continued during 2008. We present the results of work done in the CRGS, which is a tectonic erosive-depression with an average depth of 500 m and exhibits a sequence of volcanic and sedimentary deposits with rapid lateral facies changes. The stratigraphic column spans a 15 km-long section along the Matatlán-Arcediano road, and, from top to bottom contains: 1) Unconsolidated pumice and tuffs with an average thickness of 12 m; 2) basaltic lavas with average thickness of 60 m; 3) the San Gaspar ignimbrite; 4) fluvial- sedimentary deposits with a thickness of approximately 20 meters that include both sub-rounded and angular volcanic clasts, with sizes up to 0.15 m; 5) a thick sequence of ignimbrites and dacitic lavas. At a depth of 1200 m.a.s.l. in the town of Arcediano, the basal sequence is composed of dacites and andesites with interbedded pumice-rich ignimbrites with 10-20 m thickness. The Rio Grande de Santiago talweg to 1018 m.a.s.l. (apparently the base of the sequence) is formed by andesite lava. In the area of San Gaspar we identified oblique-normal left-lateral faults in lavas, with a strike 191° and a dip 89°. In the Colimilla dam, 1297 m.a.s.l., we observed normal faulting (strike 267° and dip 81°), with 20-30 m jumps with reference to a unit of tephra of 3-10 m thickness. The lavas in this

  19. A closer look at the pyroclastic density current deposits of the May 18, 1980 eruption of Mt St Helens (United States)

    Mackaman-Lofland, C. A.; Brand, B. D.; Dufek, J.


    Pyroclastic Density Currents (PDCs) are the most dangerous hazard associated with explosive volcanic eruptions. Due to the danger associated with observing these ground-hugging currents of searing hot gas, ash, and rock in real time, their processes are poorly understood. In order to understand flow dynamics, including what controls how far PDCs travel and how they interact with topography, it is necessary to study their deposits. The May 18th, 1980 eruption of Mt. St. Helens produced multiple PDCs, burying the area north of the volcano under 10s of meters of PDC deposits. Because the eruption is one of the best observed on record, individual flow units can be correlated to changes in eruptive intensity throughout the day (e.g., Criswell, 1987). Deep drainage erosion over the past 30 years has exposed the three-dimensional structure of the PDC deposits, making this intensive study possible. Up to six flow units have been identified along the large western drainage of the pumice plain. Each flow unit has intricate vertical and lateral facies changes and complex cross-cutting relationships away from source. The most proximal PDC deposits associated with the afternoon flows on May 18 are exposed 4 km from source in tributaries of the large drainage on the western side of the pumice plain. Hummocks from the debris avalanche are also exposed above and within these proximal drainages. It is apparent that the PDCs were often erosional, entraining large blocks from the hummocks and depositing them in close proximity downstream. The currents were also depositional, as thick sequences of PDC deposits are found in areas between hummocks, which thin to veneers above them. This indicates that the currents were interacting with complex topography early in their propagation, and is reflected by spatially variable bed conditions including rapid changes in bedding and granulometry characteristics within individual flow units. For example, within 20 lateral meters of a given flow

  20. The 2012 Copahue eruption: magnitude of gas fluxes and time scale of degassing (United States)

    Varekamp, J. C.; Camfield, L.


    Copahue volcano (Argentina, 37.5 S, 71.5 W) erupted in 2000 and 2012 with initial phreato-magmatic blasts, violent Strombolian eruptions of several hours duration, followed by open conduit activity for days to months. The 2012 basal deposits 10 km S of Copahue are mm-sized ashes with hydrothermally altered debris, followed by up to 10cm pancake pumices, while denser cinders fell near the crater in the waning stages. The strombolian plume was ~ 6 km high and satellite images show its trajectory up to 200 km S. The pumices have finely porous rims (0.3mm vesicles) that were probably quenched by hydrothermal fluids and coarse interiors (several mm vesicles) that inflated during eruption. All the products have identical chemical composition and mineralogy, and only vary in degree of vesiculation. The 2012 products are the most mafic of the whole volcanic history of Copahue, with MgO ~ 4.5 %. The quench rim pumice glass contains 1160 ppm Cl while glass inclusions have up to 1800 ppm Cl. Water concentrations are 0.5-2.0 % (by difference with EMPA) and plagioclase hygrometry. Pre-eruptive conditions were 1080 oC and 1-2.5 kb pressure. The magmato-hydrothermal system is leaking fluids into the overlying crater lake and into a river. The hot springs have pH <1 and these fluids are up to 60% magmatic in origin. Annual river flux measurements and non-steady state modeling between 1997 and 2013 constrain the mean hydrothermal Cl flux at 1170 tonnes/month. The 2012 erupted magma mass is about 1012 gr, and from the measured total Cl loss between 2000 and 2012 and mean degassed Cl in the magma the volume of degassing magma is estimated at 1014-1015 grams. Much more magma was degassing than was erupted. Analyses of 226Ra-210Pb constrained the maximum degassing time at 8-10 years prior to the 2012 eruption. Almost all rock samples have 210Pb deficits, and so most gas escaped from the magma into the hydrothermal system. Nonetheless, the top of the magma reservoir accumulated bubbles

  1. Eruption Depths, Magma Storage and Magma Degassing at Sumisu Caldera, Izu-Bonin Arc: Evidence from Glasses and Melt Inclusions (United States)

    Johnson, E. R.


    Island arc volcanoes can become submarine during cataclysmal caldera collapse. The passage of a volcanic vent from atmospheric to under water environment involves complex modifications of the eruption style and subsequent transport of the pyroclasts. Here, we use FTIR measurements of the volatile contents of glass and melt inclusions in the juvenile pumice clasts in the Sumisu basin and its surroundings (Izu-Bonin arc) to investigate changes in eruption depths, magma storage and degassing over time. This study is based on legacy cores from ODP 126, where numerous unconsolidated (250 m), massive to normally graded pumice lapilli-tuffs were recovered over four cores (788C, 790A, 790B and 791A). Glass and clast geochemistry indicate the submarine Sumisu caldera as the source of several of these pumice lapilli-tuffs. Glass chips and melt inclusions from these samples were analyzed using FTIR for H2O and CO2 contents. Glass chips record variable H2O contents; most chips contain 0.6-1.6 wt% H2O, corresponding to eruption depths of 320-2100 mbsl. Variations in glass H2O and pressure estimates suggest that edifice collapse occurred prior-to or during eruption of the oldest of these samples, and that the edifice may have subsequently grown over time. Sanidine-hosted melt inclusions from two units record variably degassed but H2O-rich melts (1.1-5.6 wt% H2O). The lowest H2O contents overlap with glass chips, consistent with degassing and crystallization of melts until eruption, and the highest H2O contents suggest that large amounts of degassing accompanied likely explosive eruptions. Most inclusions, from both units, contain 2-4 wt% H2O, which further indicates that the magmas crystallized at pressures of ~50-100 MPa, or depths ~400-2800 m below the seafloor. Further glass and melt inclusion analyses, including major element compositions, will elucidate changes in magma storage, degassing and evolution over time.

  2. Stratigraphy and landsnail faunas of Late Holocene coastal dunes, Tokerau Beach, northern New Zealand

    International Nuclear Information System (INIS)

    Brook, F.J.


    At least four depositional episodes, each involving cycles of dune instability and sand accumulation followed by stabilisation and soil formation, are represented in a Holocene dune sequence at Tokerau Beach. The first depositional episode followed the maximum post-glacial sea level rise at 6500 years BP, probably with formation of a narrow dune belt landward of the present coastline. The second depositional episode resulted in extensive progradation of the dune belt to about the present coastline from c. 3000-2000 years BP, followed by dune stabilisation and soil formation from c. 2000-900 years BP. The third depositional episode involved vertical dune accretion at c. 900-600 years BP, followed by stabilisation and soil formation after c. 600 years BP. The fourth depositional episode, after 240 years BP, resulted in further vertical dune accretion and localised extensive erosion and reworking of pre-existing dune deposits. Fossil landsnail faunas indicate that there was patchy sandfield and shrubland vegetation of the dune belt from c. 3000-2000 years BP, followed by a mosaic of shrubland and forest from c. 2000-900 years BP. After 900 years BP there was a progressive reversion to patchy shrubland vegetation, but an extensive shrubland cover again became established at c. 600 years BP and persisted until c. 450 years BP, when it was replaced by patchy shrubland and sandfield vegetation. Dune progradational phases in the first two depositional episodes correlate with and probably developed primarily in response to changes in sea level, whereas subsequent alternating phases of dune stabilisation and build-up are inferred to have resulted in part from the influence of long term cyclical variation in prevailing local wind and wave regimes in Doubtless Bay. Two stratigraphically distinct, exotic, sea-rafted pumice units are represented in the Tokerau dune sequence: Tokerau pumice (new), which has a primary depositional age of c. 3000 years BP, and Loisels pumice, which

  3. Hydrologic Tests at Characterization Well R-14

    Energy Technology Data Exchange (ETDEWEB)

    S. McLin; W. Stone


    Well R-14 is located in Ten Site Canyon and was completed at a depth of 1316 ft below ground surface (bgs) in August 2002 within unassigned pumiceous deposits located below the Puye Formation (fanglomerate). The well was constructed with two screens positioned below the regional water table. Individual static depths measured for each isolated screen after the Westbay{trademark} transducer monitoring system was installed in mid-December 2002 were nearly identical at 1177 ft bgs, suggesting only horizontal subsurface flow at this time, location, and depth. Screen 1 straddles the geologic contact between the Puye fanglomerate and unassigned pumiceous deposits. Screen 2 is located about 50 ft deeper than screen 1 and is only within the unassigned pumiceous deposits. Constant-rate, straddle-packer, injection tests were conducted at screen 2, including two short tests and one long test. The short tests were 1 minute each but at different injection rates. These short tests were used to select an appropriate injection rate for the long test. We analyzed both injection and recovery data from the long test using the Theis, Theis recovery, Theis residual-recovery, and specific capacity techniques. The Theis injection, Theis recovery, and specific capacity methods correct for partial screen penetration; however, the Theis residual-recovery method does not. The long test at screen 2 involved injection at a rate of 10.1 gallons per minute (gpm) for 68 minutes and recovery for the next 85 minutes. The Theis analysis for screen 2 gave the best fit to residual recovery data. These results suggest that the 158-ft thick deposits opposite screen 2 have a transmissivity (T) equal to or greater than 143 ft{sup 2}/day, and correspond to a horizontal hydraulic conductivity (K) of at least 0.9 ft/day. The specific capacity method yielded a T value equal to or greater than 177 ft{sup 2}/day, and a horizontal K of at least 1.1 ft/day. Results from the injection and recovery phases of the

  4. Hydrothermal alteration of a rhyolitic hyaloclastite from Ponza Island, Italy (United States)

    Ylagan, Robert F.; Altaner, Stephen P.; Pozzuoli, Antonio


    A rhyolitic hyaloclastite from Ponza island, Italy, has been hydrothermally altered producing four distinct alteration zones based on XRD and field textures: (1) non-pervasive argillic zone; (2) propylitic zone; (3) silicic zone; and (4) sericitic zone. The unaltered hyaloclastite is a volcanic breccia with clasts of vesiculated obsidian in a matrix of predominantly pumice lapilli. Incomplete alteration of the hyaloclastite resulted in the non pervasive argillic zone, characterized by smectite and disordered opal-CT. Obsidian clasts, some pumice lapilli, and pyrogenic plagioclase and biotite are unaltered. Smectite has an irregular flakey morphology, although euhedral particles are occasionally observed. The propylitic zone is characterized by mixed-layer illite/smectite (I/S) with 10 to 85% illite (I), mordenite, opal-C and authigenic K-feldspar (akspar). The matrix of the hyaloclastite is completely altered and obsidian clasts are silicified; however, plagioclase and biotite phenocrysts remain unaltered. Flakey I/S replaces pumice, and mordenite, akspar and silica line and fill pores. I/S particles are composed predominantly of subequant plates and euhedral laths. The silicic zone is characterized by highly illitic I/S with ≥ 90% I, quartz, akspar and occasional albite. In this zone the matrix and clasts are completely altered, and pyrogenic plagioclase shows significant alteration. Illitic I/S has a euhedral lath-like morphology. In the sericitic zone the hyaloclastite altered primarily to illitic I/S with ≥ 66% I, quartz, and minor akspar and pyrite. Clay minerals completely replace pyrogenic feldspars and little evidence remains of the original hyaloclastite texture. Unlike other zones, illitic I/S is fibrous and pure illite samples are composed of euhedral laths and hexagonal plates. The temperatures of hydrothermal alteration likely ranged from 30 to 90 °C for the argillic zone, from 110 to 160 °C for the propylitic zone, from 160 to 270 °C for the

  5. Assembling an ignimbrite: Compositionally defined eruptive packages in the 1912 Valley of Ten Thousand Smokes ignimbrite, Alaska (United States)

    Fierstein, J.; Wilson, C.J.N.


    The 1912 Valley of Ten Thousand Smokes (VTTS) ignimbrite was constructed from 9 compositionally distinct, sequentially emplaced packages, each with distinct proportions of rhyolite (R), dacite (D), and andesite (A) pumices that permit us to map package boundaries and flow paths from vent to distal extents. Changing pumice proportions and interbedding relationships link ignimbrite formation to coeval fall deposition during the first ???16 h (Episode I) of the eruption. Pumice compositional proportions in the ignimbrite were estimated by counts on ???100 lapilli at multiple levels in vertical sections wherever accessible and more widely over most of the ignimbrite surface in the VTTS. The initial, 100% rhyolite ignimbrite package (equivalent to regional fall Layer A and occupying ???3.5 h) was followed by packages with increasing proportions of andesite, then dacite, emplaced over ???12.5 h and equivalent to regional fall Layers B1-B3. Coeval fall deposits are locally intercalated with the ignimbrite and show parallel changes in R:D (rhyolite:dacite) proportions, but lack significant amounts of andesite. Andesite was thus dominantly a low-fountaining component in the eruption column and is preferentially represented in packages filling the VTTS north of the vent. The most extensive packages (3 and 4) occur in B1 and early B2 times where flow mobility and volume were optimized; earlier all-rhyolite flows (Package 1) were highly energetic but less voluminous, while later packages (5-9) were both less voluminous and emplaced at lower velocities. Package boundaries are expressed as one or more of the following: sharp color changes corresponding to compositional variations; persistent finer-grained basal parts of flow units; compaction swales filled by later packages; erosional channels cut by the flows that fill them; lobate accumulations of one package; and (mostly south of the vent) intercalated fall deposit layers. Clear flow-unit boundaries are best developed between

  6. Remarkably preserved tephra from the 3430 Ma Strelley Pool Formation, Western Australia: Implications for the interpretation of Precambrian microfossils (United States)

    Wacey, David; Saunders, Martin; Kong, Charlie


    The ∼3430 Ma Strelley Pool Formation (SPF), Pilbara, Western Australia contains some of the most diverse microfossil evidence for early life on Earth. Here we report an assemblage of tephra (scoria, tubular pumice, plus vesicular and non-vesicular volcanic glass shards) from two stratigraphic levels in the SPF, including morphotypes that closely resemble previously described microfossils from this unit and elsewhere. Clasts of scoria are characterised by numerous spheroidal vesicles, with subordinate eye- and lens-shaped morphotypes, commonly lined with anatase (TiO2) and small amounts of organic material. Their diameters range from 5-180 μm with 80% in the 10-50 μm range. Fragments of tubular pumice are also lined with anatase + / - carbon and have tube diameters of 5-15 μm. Other volcanic ejecta particles include a multitude of sub-angular shard particles with or without vesicles, plus more rounded vase-shaped, eye-shaped, and hair-like morphologies; once again, most of these are coated by anatase + / - carbon and are several tens of micrometres in size. Many of the tephra fragments are now entirely silicified with no compositional difference between the former volcanic glass, the vesicle infill and the clast matrix. However, some examples retain a partial aluminosilicate composition, either as a vesicle infilling phase or as isolated lath-like grains within the formerly glassy groundmass. Isolated occurrences of some of these tephra morphotypes strongly resemble simple microbial morphologies including pairs and clusters of cells (cf. scoria), filamentous microbes (cf. tubular pumice) and larger sheaths/cysts (cf. sub-rounded glass shards). Furthermore, some tephra-containing clasts occur in a SPF sandstone unit that hosts previously described microfossils, while others are interbedded with chert layers from which microfossils have also been described. In light of our new volcanogenic data, we evaluate the robustness of previous microfossil evidence from the

  7. Culture-Independent Identification of Manganese-Oxidizing Genes from Deep-Sea Hydrothermal Vent Chemoautotrophic Ferromanganese Microbial Communities Using a Metagenomic Approach (United States)

    Davis, R.; Tebo, B. M.


    Microbial activity has long been recognized as being important to the fate of manganese (Mn) in hydrothermal systems, yet we know very little about the organisms that catalyze Mn oxidation, the mechanisms by which Mn is oxidized or the physiological function that Mn oxidation serves in these hydrothermal systems. Hydrothermal vents with thick ferromanganese microbial mats and Mn oxide-coated rocks observed throughout the Pacific Ring of Fire are ideal models to study the mechanisms of microbial Mn oxidation, as well as primary productivity in these metal-cycling ecosystems. We sampled ferromanganese microbial mats from Vai Lili Vent Field (Tmax=43°C) located on the Eastern Lau Spreading Center and Mn oxide-encrusted rhyolytic pumice (4°C) from Niua South Seamount on the Tonga Volcanic Arc. Metagenomic libraries were constructed and assembled from these samples and key genes known to be involved in Mn oxidation and carbon fixation pathways were identified in the reconstructed genomes. The Vai Lili metagenome assembled to form 121,157 contiguous sequences (contigs) greater than 1000bp in length, with an N50 of 8,261bp and a total metagenome size of 593 Mbp. Contigs were binned using an emergent self-organizing map of tetranucleotide frequencies. Putative homologs of the multicopper Mn-oxidase MnxG were found in the metagenome that were related to both the Pseudomonas-like and Bacillus-like forms of the enzyme. The bins containing the Pseudomonas-like mnxG genes are most closely related to uncultured Deltaproteobacteria and Chloroflexi. The Deltaproteobacteria bin appears to be an obligate anaerobe with possible chemoautotrophic metabolisms, while the Chloroflexi appears to be a heterotrophic organism. The metagenome from the Mn-stained pumice was assembled into 122,092 contigs greater than 1000bp in length with an N50 of 7635 and a metagenome size of 385 Mbp. Both forms of mnxG genes are present in this metagenome as well as the genes encoding the putative Mn

  8. Surface deformation on the west portion of the Chapala lake basin: uncertainties and facts

    Directory of Open Access Journals (Sweden)

    M. Hernandez-Marin


    Full Text Available In this study we investigate different aspects of land subsidence and ground failures occurring in the west portion of Chapala lake basin. Currently, surface discontinuities seem to be associated with subsiding bowls. In an effort to understand some of the conditioning factors to surface deformation, two sounding cores from the upper sequence (11 m depth were extracted for analyzing physical and mechanical properties. The upper subsoil showed a predominant silty composition and several lenses of pumice pyroclastic sand. Despite the relative predominance of fine soil, the subsoil shows mechanical properties with low clay content, variable water content, low plasticity and variable compressibility index, amongst some others. Some of these properties seem to be influenced by the sandy pyroclastic lenses, therefore, a potential source of the ground failure could be heterogeneities in the upper soil.

  9. Isotopic feature and uranium dating of the volcanic rocks in the Okinawa Trough

    Institute of Scientific and Technical Information of China (English)


    Volcanic rocks from the northern and middle Okinawa Trough were dated by uranium-series dating method. Differential fractions using magnetic procedure were designed to separate samples. New report on the ages and isotopic data of rocks in the northern trough (especially black pumice) was discussed. Based on the uranium dates and Sr-Nd isotopic ratio, magmatic evolution process of the Okinawa Trough was noted. Firstly, there have been wide silicic volcanic activities in the Okinawa Trough from late Pleistocene to present, and the volcanic rocks can be divided into three subgroups. Secondly, magma generally came from PREMA source area under the Okinawa Trough. Magmatic evolution in the northern trough was similar to the middle, but different to the south. Finally, volcanic activities indicated that opening of the southern Okinawa Trough did not happen due to the collision between Luson Arc and Eurasian Plate until the early Pleistocene.

  10. How Did Ca. 300 Years of Explosive Activity at Kilauea End? (United States)

    Swanson, D. A.


    Kilauea experienced ~300 years of frequent explosive eruptions following caldera collapse in about 1500 CE, producing the Keanakāko';i Tephra. The first 200 years were dominated by juvenile-rich phreatomagmatic eruptions, and the next 100 years by lithic-rich phreatomagmatic and phreatic explosive events. For most of this time, the caldera was deep enough (≥600 m) to allow magma and hot rock to interact with external water at and below the water table. This situation changed after the deadly 1790 eruption. The first eruption was magmatic, involving high fountaining that deposited pumice across >25 km2 south of the caldera. The pumice is hard to find today; it was mostly eroded away soon after deposition and is found only in protected areas along drainages and next to obstacles. The deposit has a consistent internal stratigraphy regardless of its thickness (maximum of 12 cm): lower third mostly achneliths (Pele's hair and tears), upper two- thirds pumice bombs and lapilli. The fountaining, the first purely magmatic event since reticulite erupted in ca. 1500, probably signifies a rising magma column and early filling of the caldera. The next eruption was phreatic, depositing fine lithic ash a few millimeters thick across >45 km2 south of the caldera. It may record withdrawal of the magma column and collapse of part of the caldera floor to or below the water table. The magma column rose soon thereafter, and its free surface was above the water table for some time. This event is recorded by Pele's hair deposited on the lithic ash across >30 km2 south of the caldera. The hair forms a jackstraw mat Pele's hair that blows kilometers downwind, forming a paper-thin deposit that glistens in the sun like golden grain. Phreatic activity followed, depositing small lapilli now embedded in the hair and lithic ash. This was perhaps a vent-opening event for a dominantly phreatomagmatic eruption. The deposit of this eruption, mostly lithic but with scattered fluidal lapilli, is 0

  11. Role of complex utilization of mineral raw materials In geological research

    Energy Technology Data Exchange (ETDEWEB)

    Takacs, P.; Varju, G.


    Presents Hungarian research efforts on ways of utilizing the secondary raw materials alunite, pumice and slate coal from various mines. The slate coal is separated from brown coal and disposed of at spoil banks of brown coal mines, due to its high ash content (up to 56.8% under dry conditions), silicate content up to 58.2% and low calorific value between 1500 and 2780 kcal/kg. The research proposal for utilizing slate coal is directed at partial separation of the mineral and coal content by comminution, peptization and hydrocentrifugal separation. The larger part of the silicate content is held in the colloid suspension, which could be used for conditioning drilling mud or foundry sand. The produced coal concentrate has a reduced ash content and higher calorific value (between 500 and 800 kcal/kg) and could be employed in soil amelioration or combustion. (10 refs.) (In German)

  12. On the geochemistry of the Kyra eruption sequence of Nisyros volcano on Nisyros and Tilos, Greece

    International Nuclear Information System (INIS)

    Sterba, Johannes H.; Steinhauser, Georg; Bichler, Max


    The Kyra sequence is a volcanic eruption sequence originating from the eastern flank of Nisyros volcano, Greece. Its eruptions products can be found not only on Nisyros itself but also on the nearby non-volcanic island of Tilos. In an extensive sampling campaign, outcrops of the Kyra eruption products on Nisyros were sampled and corresponding samples on Tilos were taken. The clear stratigraphical relationship between the different units within in the individual outcrops, combined with the chemical information gained by the application of instrumental neutron activation analysis (INAA) to the samples, made a detailed chemo-stratigraphy of the complete eruption sequence possible. It can be shown that the sequence is separated into eight distinguishable eruptions. Furthermore, no eruption products of the caldera-forming eruptions from Nisyros (Lower- and Upper Caldera Pumice) or from Santorin were found on Tilos.

  13. Carbon 11 labelled phosgene: a new synthesis - medical interest

    International Nuclear Information System (INIS)

    Landais, P.


    This thesis describes a new synthesis of high specific radioactivity carbon-11 labelled phosgene. The latter is an important precursor for the labelling of radiopharmaceuticals used in Positron Emission Tomography. The synthesis is carried out in 10 minutes. First, the carbon-11 labelled methane ( 11 CH 4 ) is chlorinated into carbon tetrachloride on pumice impregnated with copper (II) chloride. A photochemical process had previously been studied but this reaction was strongly inhibited. Then the 11 C-carbon tetrachloride is oxidized into 11 C-phosgene on hot stainless. The 11 C-CGP 12177 has been labelled from this new 11 C-Phosgene synthesis for receptor studies which require high specific radioactivity. (author) [fr

  14. Carbon-11 labelled phosgene new synthesis - medical interest

    International Nuclear Information System (INIS)

    Landais, P.


    This thesis describes a new synthesis of high specific radioactivity carbon-11 labelled phosgene. The latter is an important precursor for the labelling of radiopharmaceuticals used in Positron Emission Tomography. The synthesis is carried out in 10 minutes. First, the carbon-11 labelled methane ( 11 CH 4 ) is chlorinated into carbon tetrachloride on pumice impregnated with copper (II) chloride. A photochemical process had previously been studied but this reaction was strongly inhibited. Then the 11 C-carbon tetrachloride is oxidized into 11 C-phosgene on hot stainless. The 11 C-CGP 12177 has been labelled from this new 11 C-Phosgene synthesis for receptor studies which require high specific radioactivity [fr

  15. Caracterización morfoscópica de los materiales piroclásticos sálicos del sur de Tenerife (Islas Canarias

    Directory of Open Access Journals (Sweden)

    Alonso, J. J.


    Full Text Available In this work, several morphological aspects of volcanic ash grains from southern Tenerife are studied by S.E.M. Important variations in vesiculation, fracture and wheathering of pyroclasts are observed. It's possible to characterize diferent types of deposits (pyroclastic falIs, pyroclastic flow, surges, etc. in function of the pumice fragments surface.En este trabajo se estudian mediante M.E.B. (Microscopio Electrónico de Barrido diversos aspectos morfológicos de granos de cenizas volcánicas del sur de Tenerife. Son observadas importantes variaciones en la vesiculación, fracturación y alteraciones de los piroclastos. Es posible caracterizar distintos tipos de depósitos (piroclastos de caída, coladas piroclásticas, surges, etc. en función de las características superficiales de los fragmentos pumíticos.

  16. Evidence for a welded tuff in the Rhyolite of Calico Hills

    International Nuclear Information System (INIS)

    Dickerson, R.P.; Hunter, W.C.


    A welded pyroclastic deposit has been identified in the Rhyolite of Calico Hills near Yucca Mountain, Nevada, where only lava flows and nonwelded pyroclastic deposits were previously described. Field data from Fortymile Wash show that nonwelded, bedded tuff grades upward into partially welded massive ruff, and thence into densely welded vitrophyre. Petrographic data show a progressive decrease in inter- and intragranular porosity and amount of vapor-phase minerals, with increasing welding. Pumice fragments are first deformed, then develop diffuse boundaries which become increasingly obscure with progressive welding. The most densely welded rock is a perlitic vitrophyre. The origin of this welded tuff is not clear, as it could represent an ignimbrite or a tuff fused beneath a thick lava flow

  17. Santorini eruption radiocarbon dated to 1627-1600 B.C. (United States)

    Friedrich, Walter L; Kromer, Bernd; Friedrich, Michael; Heinemeier, Jan; Pfeiffer, Tom; Talamo, Sahra


    Precise and direct dating of the Minoan eruption of Santorini (Thera) in Greece, a global Bronze Age time marker, has been made possible by the unique find of an olive tree, buried alive in life position by the tephra (pumice and ashes) on Santorini. We applied so-called radiocarbon wiggle-matching to a carbon-14 sequence of tree-ring segments to constrain the eruption date to the range 1627-1600 B.C. with 95.4% probability. Our result is in the range of previous, less precise, and less direct results of several scientific dating methods, but it is a century earlier than the date derived from traditional Egyptian chronologies.


    Witkind, Irving J.; Ridenour, James


    A mineral survey conducted within the Centennial Mountains Wilderness study area in Montana and Idaho showed large areas of probable and substantiated resource potential for phosphate. Byproducts that may be derived from processing the phosphate include vanadium, chromium, uranium, silver, fluorine, and the rare earths, lanthanum and yttrium. Results of a geochemical sampling program suggest that there is little promise for the occurrence of base and precious metals in the area. Although the area contains other nonmetallic deposits, such as coal, building stone, and pumiceous ash they are not considered as mineral resources. There is a probable resource potential for oil and gas and significant amounts may underlie the area around the Peet Creek and Odell Creek anticlines.

  19. Volcanic Ash fall Impact on Vegetation, Colima 2005 (United States)

    Garcia, M. G.; Martin, A.; Fonseca, R.; Nieto, A.; Radillo, R.; Armienta, M.


    An ash sampling network was established arround Colima Volcano in 2005. Ash fall was sampled on the North, Northeast, East, Southeast, South, Southwest and West of the volcano. Samples were analyzed for ash components, geochemistry and leachates. Ash fall ocurred on April (12), May (10, 23), June (2, 6, 9, 10, 12, 14), July (27), September (27), October (23) and November (24). Most of the ash is made of andesitic dome-lithics but shows diferences in crystal, juvenile material and lithic content. In May, some samples contained grey and dark pumice (scoria). Texture varies from phi >4 to phi 0. Leachate concentration were low: SO4 (7.33-54.19) Cl- (2.29-4.97) and F- (0.16-0.37). During 2005, Colima Volcano's ash fall rotted some of the guava and peach fruits and had a drying effect on spearment and epazote plants. Even these small ash amounts could have hindered sugar cane and agave growth.

  20. Mobility of pyroclastic flows and surges at the Soufriere Hills Volcano, Montserrat (United States)

    Calder, E.S.; Cole, P.D.; Dade, W.B.; Druitt, T.H.; Hoblitt, R.P.; Huppert, H.E.; Ritchie, L.; Sparks, R.S.J.; Young, S.R.


    The Soufriere Hills Volcano on Montserrat has produced avalanche-like pyroclastic flows formed by collapse of the unstable lava dome or explosive activity. Pyroclastic flows associated with dome collapse generate overlying dilute surges which detach from and travel beyond their parent flows. The largest surges partially transform by rapid sedimentation into dense secondary pyroclastic flows that pose significant hazards to distal areas. Different kinds of pyroclastic density currents display contrasting mobilities indicated by ratios of total height of fall H, run-out distance L, area inundated A and volume transported V. Dome-collapse flow mobilities (characterised by either L/H or A/V 2/3) resemble those of terrestrial and extraterrestrial cold-rockfalls (Dade and Huppert, 1998). In contrast, fountain-fed pumice flows and fine-grained, secondary pyroclastic flows travel slower but, for comparable initial volumes and heights, can inundate greater areas.

  1. Economic Drivers of Strategic & Critical Materials (United States)


    Calla<la. r>eru, cnre ZINC 7J ----i, Peru, Mexico, l relaniJ TIT .. .Nll.JM (&p1111ge) ’i">9 -----j K azaUI&tan. Japan. ~ R~a ~.0:!\\JM Ml N...G YPS’Uloil PHOSPI1AT E ROCK IRON and STEEL IRON and STE EL SlAG OEME:NT PUMICE DIIL\\IO.N !> (na:lr.ll t1du&trtal s!Oile) U:ME STO.N E (Ct...PLATINUM ZINC TU.NGSTE.N mA.~w.l ($f10nge) HICK EL PEAT MAGNESIUM METAL SltVER S t’UCON BERYLUUM MAGNESIUM COMPOU l>S ALUMI NUM PUMICIE

  2. Immobilized glucose oxidase--catalase and their deactivation in a differential-bed loop reactor. (United States)

    Prenosil, J E


    Glucose oxidase containing catalase was immobilized with a copolymer of phenylenediamine and glutaraldehyde on pumice and titania carrier to study the enzymatic oxidation of glucose in a differential-bed loop reactor. The reaction rate was found to be first order with respect to the concentration of limiting oxygen substrate, suggesting a strong external mass-transfer resistance for all the flow rates used. The partial pressure of oxygen was varied from 21.3 up to 202.6 kPa. The use of a differential-bed loop reactor for the determination of the active enzyme concentration in the catalyst with negligible internal pore diffusion resistance is shown. Catalyst deactivation was studied, especially with respect to the presence of catalase. It is believed that the hydrogen peroxide formed in the oxidation reaction deactivates catalase first; if an excess of catalase is present, the deactivation of glucose oxidase remains small. The mathematical model subsequently developed adequately describes the experimental results.

  3. Interpreting compositional zonation of the Zaragoza ignimbrite from Los Humeros caldera, Central Mexico

    International Nuclear Information System (INIS)

    Carrasco-Nunez, Gerardo; McCurry, Michael; Branney, Michael J


    Compositional zonation in ignimbrites is relatively common, and is often inferred to record gradual withdrawal by an eruption of a density-stratified magma chamber (with silicic magma towards the top and more dense, mafic magma at the bottom). We show that this model does not match observations at the ca. 0.1 Ma Zaragoza ignimbrite from Los Humeros caldera in central Mexico. Detailed petrologic studies reveal a more complex scenario: the ignimbrite exhibits a 'double' vertical zonation based on the compositions of pumice lapilli. We present evidence for mingling and limited mixing occurred during or immediately before the caldera-forming eruption. One possibility to explain the observations is that the ignimbrite eruption occurred in response to intrusion of a hybridized andesitic magma into a rhyodacitic magma chamber.

  4. Effect of prophylactic treatments on the superficial roughness of dental tissues and of two esthetic restorative materials Efeito de tratamentos profiláticos na rugosidade superficial de tecidos dentais e de dois materiais restauradores estéticos

    Directory of Open Access Journals (Sweden)

    Daniele Salami


    Full Text Available Dental prophylaxis is a common way to remove dental plaque and stain, both undesirable factors in most dentistry procedures. However, besides cleaning the tooth surface, prophylactic techniques may increase the surface roughness of restorations and dental tissues, which, in turn, may result in plaque accumulation, superficial staining and superficial degradation. This study evaluated the effect of three prophylactic techniques - sodium bicarbonate jet, pumice paste and whiting paste - on the superficial roughness of two restorative materials - a composite resin and a compomer - and on the superficial roughness of two dental surfaces - enamel and cementum/dentin - through rugosimetric and scanning electron microscopy (SEM analysis. Statistical analysis of the rugosimetric data showed that the use of pumice paste on enamel produced a significantly smoother surface than the natural surface. However, comparing the effect of the three techniques, prophylaxis with the pumice paste produced a rougher surface than did the other techniques as regards enamel and cementum/dentin probably due to its abrasiveness. On composite resin, the pumice paste only produced a rougher surface than did the whiting paste. On compomer, all of the applied treatments produced similar results. Based on rugosimetric and SEM analysis, we could conclude that the prophylactic treatments employed did not improve roughness of the studied surfaces. As to the effects of the techniques, they were different depending on the surfaces on which the prophylactic treatments were applied.A profilaxia dental é uma prática comum para a remoção de placa bacteriana e outros indutos que dificultam a realização dos procedimentos restauradores. Entretanto, como efeito secundário à limpeza, pode-se ter uma superfície mais rugosa e sujeita a manchamentos e degradações. O presente estudo avaliou os efeitos de três técnicas de profilaxia - jato de bicarbonato de sódio, pasta de pedra

  5. Potassium-argon dating in archaeology

    Energy Technology Data Exchange (ETDEWEB)

    McDougall, I. (Australian National Univ., Canberra (Australia). Research School of Earth Sciences)


    The potassium-argon (K-Ar) isotopic dating method can provide precise and accurate numerical ages on suitable rocks, especially igneous rocks, over a wide range of age from less than 100,000 years old, with no older limit. Together with its variants, the {sup 40}Ar/{sup 39}Ar technique, the K-Ar method is very useful for the numerical age calibration of stratigraphic sequences, including those containing archaeological or fossil material, in cases where appropriate rocks for dating are present. This brief review of the basis of the K-Ar dating method and the underlying assumptions, concludes with an example of its application to the Plio-Pleistocene stratigraphic sequence in the Turkana Basin, northern Kenya. By dating alkali feldspars separated from pumice blocks in tuffaceous beds, excellent age control has been obtained for the wealth of vertebrate fossils, including hominids, as well as archaeological materials that has been found in the sequence. (author).

  6. The Laramide Mesa formation and the Ojo de Agua caldera, southeast of the Cananea copper mining district, Sonora, Mexico (United States)

    Cox, Dennis P.; Miller, Robert J.; Woodbourne, Keith L.


    The Mesa Formation extends from Cananea, Mexico, southeast to the Sonora River and is the main host rock of Laramide porphyry copper deposits in the Cananea District and at the Alacran porphyry prospect to the east. The Mesa consists of two members-a lower andesite and an upper dacite. The lowest part of the dacite member is a crystal tuff about 100 m thick. This tuff is the outfall of a caldera centered near the village of Ojo de Agua, dated by 40Ar/39Ar at 65.8 Ma ?0.4. The Ojo de Agua Caldera is about 9 km in diameter and is filled by a light gray biotite dacite tuff with abundant flattened pumice fragments. The volume of the caldera is estimated to be 24 km3.

  7. Constructing a reference tephrochronology for Augustine Volcano, Alaska (United States)

    Wallace, Kristi; Coombs, Michelle L.


    Augustine Volcano is the most historically active volcano in Alaska's populous Cook Inlet region. Past on-island work on pre-historic tephra deposits mainly focused on using tephra layers as markers to help distinguish among prevalent debris-avalanche deposits on the island (Waitt and Beget, 2009, USGS Prof Paper 1762), or as source material for petrogenetic studies. No comprehensive reference study of tephra fall from Augustine Volcano previously existed. Numerous workers have identified Holocene-age tephra layers in the region surrounding Augustine Island, but without well-characterized reference deposits, correlation back to the source volcano is difficult. The purpose of this detailed tephra study is to provide a record of eruption frequency and magnitude, as well as to elucidate physical and chemical characteristics for use as reference standards for comparison with regionally distributed Augustine tephra layers. Whole rock major- and trace-element geochemistry, deposit componentry, and field context are used to correlate tephra units on the island where deposits are coarse grained. Major-element glass geochemistry was collected for use in correlating to unknown regional tephra. Due to the small size of the volcanic island (9 by 11 km in diameter) and frequent eruptive activity, on-island exposures of tephra deposits older than a couple thousand years are sparse, and the lettered Tephras B, M, C, H, I, and G of Waitt and Beget (2009) range in age from 370-2200 yrs B.P. There are, however, a few exposures on the south side of the volcano, within about 2 km of the vent, where stratigraphic sections that extend back to the late Pleistocene glaciation include coarse pumice-fall deposits. We have linked the letter-named tephras from the coast to these higher exposures on the south side using physical and chemical characteristics of the deposits. In addition, these exposures preserve at least 5 older major post-glacial eruptions of Augustine. These ultra

  8. Historical tephra-stratigraphy of the Cosiguina Volcano (Western Nicaragua)

    International Nuclear Information System (INIS)

    Hradecky, Petr; Rapprich, Vladislav


    New detailed geological field studies and 14 C dating of the Cosiguina Volcano (westernmost Nicaragua) have allowed to reconstruct a geological map of the volcano and to establish a recent stratigraphy, including three historical eruptions. Five major sequences are represented. I: pyroclastic flows around 1500 AD, II: pyroclastic flows, scoria and pumice flows and surges, III: pyroclastic deposits related to a littoral crater, IV: pyroclastic flows related to 1709 AD eruption, and finally, V: pyroclastic deposits corresponding to the cataclysmic 1835 AD phreatic, phreatomagmatic and subplinian eruption, which seems to be relatively small-scale in comparison with the preceding historical eruptions. The pulsating geochemical character of the pyroclastic rocks in the last five centuries has been documented. The beginning of every eruption is marked by increasing contents of silica and Zr. Based on that, regardless of present-day volcanic repose, the entire Cosiguina Peninsula should be considered as a very hazardous volcanic area. (author)

  9. Chronology and pyroclastic stratigraphy of the May 18, 1980, eruption of Mount St. Helens, Washington (United States)

    Criswell, C. William


    The eruption of Mount St. Helens on May 18, 1980 can be subdivided into six phases: the paroxysmal phase I, the early Plinian phase II, the early ash flow phase III, the climactic phase IV, the late ash flow phase V, and phase VI, the activity of which consisted of a low-energy ash plume. These phases are correlated with stratigraphic subunits of ash-fall tephra and pyroclastic flow deposits. Sustained vertical discharge of phase II produced evolved dacite with high S/Cl ratios. Ash flow activity of phase III is attributed to decreases in gas content, indicated by reduced S/Cl ratios and increased clast density of the less evolved gray pumice. Climactic events are attributed to vent clearing and exhaustion of the evolved dacite.

  10. An evaluation of the geothermal potential of the Tecuamburro Volcano area of Guatemala

    Energy Technology Data Exchange (ETDEWEB)

    Heiken, G.; Duffield, W. (eds.)


    Radiometric ages indicate that the Tecuamburro Volcano and three adjacent lava domes grew during the last 38,300 years, and that a 360-m-wide phreatic crater, Laguna Ixpaco, was formed near the base of these domes about 2900 years ago. Laguna Ixpaco is located within the Chupadero crater, from which pyroxene pumice deposits were erupted 38,300 years ago. Thus, the likelihood is great for a partly molten or solid-but-still-hot near-surface intrusion beneath the area. Fumaroles and hot springs issue locally from the Tecuamburro volcanic complex and near Laguna Ixpaco. Analyses of gas and fluid samples from these and other nearby thermal manifestations yield chemical-geothermometer temperatures of about 150{degree} to 300{degree}C, with the highest temperatures at Ixpaco. The existence of a commercial-grade geothermal reservoir beneath the Ixpaco area seems likely. 84 refs., 70 figs., 12 tabs.

  11. Hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)


    Coal tar, mineral oils, bitumens, coal extraction products, hydrogenation products of coal, oil schists can be atomized and heated with steam to decompose pyrogenetically and form gases rich in olefins which may be heated with or without pressure and with or without catalysts to produce liquid hydrocarbons of low boiling point, some of which may be aromatic. The apparatus should be lined with copper, silica, or ferrosilicon to prevent contact of the bases with iron which causes deposition of soot. Catalysts used may be metal oxides, silica, graphite, active charcoal, mica, pumice, porcelain, barium carbonate, copper, silver, gold, chromium, boron, or their compounds. At temperatures from 300 to 400/sup 0/C, olefins are produced. At higher temperatures, naphthenes and benzene hydrocarbons are produced.

  12. Functional characteristics and influence factors of microbial community in sewage sludge composting with inorganic bulking agent. (United States)

    Wang, Ke; Mao, Hailong; Li, Xiangkun


    The metabolic function of microbial community dominated organics and nutrients transformation in aerobic composting process. In this study, the metabolic characteristics of bacterial and fungal communities were evaluated in 60 days composting of sludge and pumice by using FUNGuild and PICRUSt, respectively. The results showed that microbial community structure and metabolic characteristics were distinctively different at four composting periods. Bacterial genes related to carbohydrate metabolisms decreased during the first 30 days, but bacterial sequences associated with oxidative phosphorylation and fatty acids synthesis were enhanced in curing phase. Most of fungal animal pathogen and plant pathogen disappeared after treatment, and the abundance of saprotroph fungi increased from 44.3% to 97.8%. Oxidation reduction potential (ORP) significantly increased from -28 to 175 mV through incubation. RDA analysis showed that ORP was a crucial factor on the succession of both bacterial and fungal communities in sludge composting system. Copyright © 2017. Published by Elsevier Ltd.

  13. On the geochemistry of the Kyra eruption sequence of Nisyros volcano on Nisyros and Tilos, Greece

    Energy Technology Data Exchange (ETDEWEB)

    Sterba, Johannes H., E-mail: [Atominstitut der oesterreichischen Universitaeten, Vienna University of Technology (Austria); Steinhauser, Georg; Bichler, Max [Atominstitut der oesterreichischen Universitaeten, Vienna University of Technology (Austria)


    The Kyra sequence is a volcanic eruption sequence originating from the eastern flank of Nisyros volcano, Greece. Its eruptions products can be found not only on Nisyros itself but also on the nearby non-volcanic island of Tilos. In an extensive sampling campaign, outcrops of the Kyra eruption products on Nisyros were sampled and corresponding samples on Tilos were taken. The clear stratigraphical relationship between the different units within in the individual outcrops, combined with the chemical information gained by the application of instrumental neutron activation analysis (INAA) to the samples, made a detailed chemo-stratigraphy of the complete eruption sequence possible. It can be shown that the sequence is separated into eight distinguishable eruptions. Furthermore, no eruption products of the caldera-forming eruptions from Nisyros (Lower- and Upper Caldera Pumice) or from Santorin were found on Tilos.

  14. Non-destructive material investigation with thermal neutrons at the TRIGA Mark II reactor in Vienna

    International Nuclear Information System (INIS)

    Bastuerk, M.; Boeck, H.; Zamani, B.; Zawisky, M.; Rauch, H.


    Neutron tomography providing 3D information about interior of an object is a very efficient tool to visualize inner defects of the materials, non-destructively. In this study, some applications of neutron tomography in different fields such as geology, aerospace, civil engineering and archaeology were presented. Distribution of minerals in pumice and rock samples, visualization of inner defects within a new developed titan aluminum turbine blade, and distribution of silica gel as an important impregnating agent in construction and restoration of buildings were investigated. The measurements of tomography projections taken in the 0 to 180 o angle were performed with a thermal neutron flux of 10 5 at the TRIGA Mark II research reactor in Vienna, and the common filtered back projection method was used for the 3D image reconstruction. (author)

  15. Upper pliocene-lower pleistocene 40Ar/39Ar ages of Pudahuel ignimbrite (Diamante-Maipo volcanic complex), Central Chile (33.50S)

    International Nuclear Information System (INIS)

    Wall, R.M.; Lara, L.E.; Perez de Arce, C


    The Pudahuel Ignimbrite (Wall et al., 1996) is a characteristic pyroclastic flow deposit placed in the Central Depression, within the Maipo, Mapocho and Cachapoal valleys and, in the eastern side of the Andes, at Yaucha and Papagayos rivers as well (Harrington, 1989; Guerstein, 1993). Close to Santiago, Pudahuel Ignimbrite reaches 40 m in thickness (Dragicevic, 1962) which decreces up to 5 m 60 km to the west. The deposit is compounded by ash and lapilli size pumice within a cineritic matrix with shards, crystals and pumice fragments. Facies of both, laminar and turbulent flow regime can be distinguished, the latter prevailing near topographic barriers and on river plain floors. There, traction structures like cross-bedding and important amount of litic clasts are characteristic. Pumices are rhyolitic in composition (ca. 75% SiO 2 ; Stern et al., 1984; Guerstein, 1993) and have few 0.5-2 mm long biotite crystals. Two 40 Ar/ 39 Ar step-heating experiments on biotite from pumices of two localities, Maipu (Santiago) and Bollenar (Melipilla), show plateau ages of 2.3±0.3 Ma (RW-371) and 2.2±0.3 Ma (RW-1009). In both cases, the first step of the experiment indicates loss of Ar from the cristal rims wich was removed for the plateau calculus only in the second case. For the RW-371 sample an inverse isocrone age of 1.4±0.8 Ma (MSWD: 0.98) was obtained. Previously, the Pudahuel Ignimbrite was dated by Stern et al. (1984) in ca. 450 ka using zircon fission-tracks. Although inconsistent with our new ages, these pleistocene age seemed coherent with the discovery of an Antifer (deer) bone by Tavera (1978) within the ignimbrite close to Santiago. Nevertheless, as was apointed by Tavera (1978) himself, the Antifer genus is recognized in Argentina in the Pliocene-Quaternary interval and make possible a review of the well known 'pleistocene' mammal vertebrate associations in Chile. Another consequence of the new possible pliocene ages is that, since the ignimbrite does not show

  16. Timescales and conditions of crystallization in the Pokai and Chimpanzee Ignimbrites, Taupo Volcanic Zone, New Zealand (United States)

    Connor, M.; Gualda, G. A.; Gravley, D. M.


    Silicic magmas give rise to explosive eruptions that are both of scientific and societal interest. The central Taupo Volcanic Zone in New Zealand has been volcanically active for 2 Ma and represents the most active volcanic area in the world today. Particularly intense volcanic activity took place as part of a flare-up event that occurred from ~340 to ~240 ka, when 7 large ignimbrite eruptions took place, as well as many smaller eruptions, which erupted a total of at least 3000 km3 of magma. This project seeks to identify the conditions and timescales over which magma bodies that gave rise to these ignimbrite eruptions evolved. We aim to understand how much of the tens of thousands of years between successive eruptions were characterized by the presence of large bodies of silicic magma within the crust, as well the magma distribution within the crust during those times. We focus on the Chimpanzee and Pokai ignimbrites, which together erupted ~150 km3 of magma. The Pokai ignimbrite erupted at ~275 ka, while the Chimpanzee ignimbrite (undated) erupted between ~320 and 275 ka. Pumice clasts from the Chimpanzee and Pokai ignimbrite were collected in the field. Pumice bulk densities were measured using a submersion technique. Quartz and plagioclase crystals were extracted through a crushing, sieving, and winnowing procedure. Whole crystals were hand-picked under a conventional microscope, mounted on epoxy, and polished to expose grain interiors. Grain mounts were analyzed under an SEM using back-scattered electron, cathodoluminescence (CL), and energy-dispersive x-ray (EDX) imaging. Bulk-densities vary from 0.42 to 0.81 g/cm3 for Pokai and between 0.52 and 0.64 g/cm3 for Chimpanzee pumice clasts. Plagioclase is the dominant crystal phase in both units. Several plagioclase crystals have inclusions of orthopyroxene, ilmenite, magnetite, and zircon, which in some cases form clusters. Quartz is rare but is present in pumice from both deposits. Both plagioclase and quartz

  17. Interpreting compositional zonation of the Zaragoza ignimbrite from Los Humeros caldera, Central Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Carrasco-Nunez, Gerardo [Centro de Geociencias, UNAM, Campus Juriquilla, Queretaro, Qro. (Mexico); McCurry, Michael [Department of Geology, Idaho State University, Pocatello, ID (United States); Branney, Michael J [Department of Geology, University of Leicester, Leicester (United Kingdom)


    Compositional zonation in ignimbrites is relatively common, and is often inferred to record gradual withdrawal by an eruption of a density-stratified magma chamber (with silicic magma towards the top and more dense, mafic magma at the bottom). We show that this model does not match observations at the ca. 0.1 Ma Zaragoza ignimbrite from Los Humeros caldera in central Mexico. Detailed petrologic studies reveal a more complex scenario: the ignimbrite exhibits a 'double' vertical zonation based on the compositions of pumice lapilli. We present evidence for mingling and limited mixing occurred during or immediately before the caldera-forming eruption. One possibility to explain the observations is that the ignimbrite eruption occurred in response to intrusion of a hybridized andesitic magma into a rhyodacitic magma chamber.

  18. Formation of a spatter-rich pyroclastic density current deposit in a Neogene sequence of trachytic-mafic igneous rocks at Mason Spur, Erebus volcanic province, Antarctica (United States)

    Martin, A. P.; Smellie, J. L.; Cooper, A. F.; Townsend, D. B.


    Erosion has revealed a remarkable section through the heart of a volcanic island, Mason Spur, in the southwestern Ross Sea, Antarctica, including an unusually well-exposed section of caldera fill. The near-continuous exposure, 10 km laterally and > 1 km vertically, cuts through Cenozoic alkalic volcanic rocks of the Erebus volcanic province (McMurdo Volcanic Group) and permits the study of an ancient volcanic succession that is rarely available due to subsequent burial or erosion. The caldera filling sequence includes an unusual trachytic spatter-rich lapilli tuff (ignimbrite) facies that is particularly striking because of the presence of abundant black fluidal, dense juvenile spatter clasts of trachytic obsidian up to 2 m long supported in a pale cream-coloured pumiceous lapilli tuff matrix. Field mapping indicates that the deposit is an ignimbrite and, together with petrological considerations, it is suggested that mixing of dense spatter and pumiceous lapilli tuff in the investigated deposit occurred during emplacement, not necessarily in the same vent, with the mixed fragmental material emplaced as a pyroclastic density current. Liquid water was not initially present but a steam phase was probably generated during transport and may represent water ingested during passage of the current as it passed over either wet ground, stream, shallow lake or (possibly) snow. Well-exposed caldera interiors are uncommon and that at Mason Spur is helping understand eruption dynamics associated with a complex large island volcano. The results of our study should help to elucidate interpretations of other, less well exposed, pyroclastic density current deposits elsewhere in Antarctica and globally.

  19. Composite Calderas: The Long and Short of it (United States)

    Gravley, D. M.; Hasegawa, T.; Nakagawa, M.; Wilson, C. J.


    Calderas formed in supereruptions are normally linked to a single magma body. However, caldera formation, regional tectonics, and multiple magma bodies may interact to form composite structures with complex geometries. The term composite caldera is often used without reference as to whether the `composite' is in time or space. Three examples of composite caldera styles from New Zealand and Japan show field, geophysical, geochemical and isotopic evidence to suggest that current models for the size, shape and evolution of calderas may be too simplistic. In our examples, multiple separate magma bodies distributed in either space or time, or both, may play a significant role in composite caldera formation. Multiple, clustered collapse events incremental in time: Akan caldera in Hokkaido appears to be a single, rectangular shaped caldera. However, the identification of 17 eruptive units spanning >1 Myr suggests that the caldera evolved incrementally over time and space. New gravity data shows that the caldera is actually a daisy-chain of 3 distinct collapse structures that can be correlated, using lithic componentry, to 3 major geochemical groups in the eruptive products. Multiple, clustered collapse events in a single eruption sequence: Shikotsu caldera in Hokkaido was originally thought to have formed following the eruption of a single large zoned magma chamber. However, the caldera-related deposits are characterized by several geochemically distinct pumice types that can not have been accommodated in a single magma system. Our studies suggest that the variations in pumice compositions are consistent with multiple distinct magma bodies feeding coeval eruptions from several vent sources within an area that collapsed to form a single caldera. Paired calderas with linking eruption-related regional faulting: Rotorua and Ohakuri calderas in New Zealand are 30 km apart and formed in close succession during a complex but virtually continuous eruption sequence at ca. 240 ka

  20. The organic selenium identification on the cattle feedstuffs in Sumedang region

    International Nuclear Information System (INIS)

    Endang Yuni Setyowati; Ujang Hidayat Tanuwiria; Muhayatun Santoso


    Selenium is an essential micro mineral which has an important role in cattle growth. Feeding cattle with this mineral increase feed efficiency and decrease oxidative stress that results in lengthening cattle product shelf live. Se deficiency reduce cattle resistance to infection disease and growth rate. Feeding cattle with variety feedstuffs is necessary in order to balance its nutrient requirement. Se content within feedstuffs is varying and depends on the Se content and the condition of soil. Sumedang is a potential region for cattle production as it has variety plants for cattle feed. However, there is no information on the Se content of feedstuffs since it has not been identified yet. This research was aim to identify Se content of several feedstuffs, that were grass, cassava pumice and chips, coconut meal, soya sauce waste, rice brand and wheat pollard. Samples were identified by Neutron Activation Analysis (NAA). There was no Se detection on the grass and rice brand. Se on soya sauce waste is vary from 0.25-0.45 mg/kg; on coconut meat is vary between 0.23-0.44 mg/kg; on cassava chips is 0.18 mg/kg; on cassava pumice is between 0.32-0.40 mg/kg and that on wheat pollard is between 0.18-0.35 mg/kg. Se content on the ration that mixed from all feedstuffs is 0.279 mg/kg. Supplementation organic Se 0.3 ppm on the ration increases the Se content to 0.608 mg/kg. It could expect that Se supplementation to the ration would result in rising cattle production. (author)

  1. Stratigraphy of the Grande Savane Ignimbrite Sequence, Dominica, Lesser Antilles (United States)

    Schneider, S.; Smith, A. L.; Deuerling, K.; Killingsworth, N.; Daly, G.


    The island of Dominica, located in the central part of the Lesser Antilles island arc has eight potentially active volcanoes. One of these, Morne Diablotins, is a composite stratovolcano with several superimposed stratigraphic sequences ranging in age from Pliocene (4-2 Ma) to "Younger" Pleistocene (22,000 and >40,000 years B.P. The ignimbrite sequences form four flow fans that reached both the east and west coasts of the island. One of these flow fans, the Grande Savane, on the west coast of the island, also extends off-shore for a distance of at least 14 km as a distinctive submarine fan. Stratigraphical studies of the on- shore deposits that make up this fan indicate an older sequence of block and ash flow deposits, within which occurs a distinctive vulcanian fall deposit. These are overlain, with no evidence of an intervening paleosol, by a sequence of ignimbrites containing welded horizons (ranging in thickness from around 4 m to 16m). The lack of fall deposits beneath the ignimbrites suggest they may have been formed by instantaneous continuous collapse of the eruption column. This whole succession is overlain by a series of planar and dune bedded pumiceous surge deposits with interbedded pumiceous lapilli fall and ash fall deposits, that extend laterally outside of the main area of ignimbrite deposition. Beds within this upper sequence often contain accretionary lapilli and gas cavities suggesting magma-water interaction. The youngest deposits from Morne Diablotins appear to be valley- fill deposits of both ignimbrite and block and ash flow. A comparison of the of the Grande Savane pyroclastic sequence with the Pointe Ronde (west coast) and Londonderry (east coast) pyroclastic flow fans will provide information on the eruptive history of this major Plinian episode.

  2. Multiple Magma Batches Recorded in Tephra Deposits from the Toba Complex, Sumatra. (United States)

    Pearce, N. J. G.; Westgate, J.; Gatti, E.


    The Toba Caldera Complex is the largest Quaternary caldera on Earth, and has generated three voluminous and compositionally similar rhyolitic tuffs, viz. the Oldest (OTT, 800 ka), Middle (MTT, ~500 ka) and Youngest Toba Tuffs (YTT, 75 ka). These tephra deposits are widespread across Indonesia, Malaysia, South China Sea, Sea of Bengal, India and Indian Ocean and provide useful stratigraphic markers in oceanic, lacustrine and terrestrial environments. Single shard trace element analysis of these deposits reveals the changing availability of different batches of magma through time, with Sr, Ba and Y contents defining 5 discrete magma populations in YTT, 4 populations in MTT and only a single, low Ba population in OTT. Within an individual eruption these populations are clearly distinct, but between eruptions (e.g. MTT and YTT) some of these populations overlap while others do not, indicating both the longevity (and/or continuous supply of fresh material) and evolution of these magma batches in the Toba Complex. Major element compositions of the different groups show equilibration at different pressures (based on Q'-Ab'-Or'), with the equilibration of low Ba populations at ~160 MPa, increasing to depths of ~210 MPa for the highest Ba population. The proportions of different populations of glass in distal YTT shows that relatively little of the high Ba population makes it into the distal record across India, and that this population appears to be over-represented in the proximal free glass and pumice from the caldera walls. This data may shed light on magma availability and tephra dispersal during the YTT eruption. Similarly, the glass composition of individual pumices from proximal deposits record regional, compositional and temporal differences in the erupted products. These show, for example, the apparent mingling of some of the magma batches and also that the high Ba population appears early (i.e. stratigraphically lower) in the northern caldera wall.

  3. Volcanic Hazards Associated with the NE Sector of Tacaná Volcano, Guatemala. (United States)

    Hughes, S. R.; Saucedo, R.; Macias, J.; Arce, J.; Garcia-Palomo, A.; Mora, J.; Scolamacchia, T.


    Tacaná volcano, with a height of 4,030 m above sea level, straddles the southern Mexico/Guatemala border. Last active in 1986, when there was a small phreatic event with a duration of a few days, this volcano presents an impending hazard to over 250,000 people. The NE sector of the volcano reveals the violent volcanic history of Tacaná that may be indicative of a serious potential risk to the area. Its earliest pyroclastic history appears to consist of fall, flow, and surge deposits, together with lavas, that have formed megablocks within a series of old debris avalanche deposits. This sector collapse event is overlain by a sequence of pumice fall and ash flow deposits, of which the youngest, less-altered pumice fall deposit shows a minimum thickness of > 4 m, with a dispersal axis trending toward the NE. A second debris avalanche deposit, separated from the above deposits by a paleosoil, is dominated by megablocks of lava and scoriaceous dome material. The current topography around the northeastern flank of the volcano is determined by a third, and most recent debris avalanche deposit, a thick (> 20 m) sequence of six block and ash flows dated at around 16,000 years BP, each separated by 1-10 cm thick ash cloud surge deposit, together with secondary lahar deposits. These are followed by a at least 4 lava flows that extend 2 km down the flank of the volcano. It appears that the most recent pyroclastic event at Tacaná is also recorded in this sector of the volcano: above the block and ash flows occurs a > 1 m thick ash flow unit that can be seen at least 5 km from the vent. Lastly, the Santa Maria Ash fall deposit, produced in 1902, has capped most of the deposits at Tacaná.

  4. Analisis stratigrafi awal kegiatan Gunung Api Gajahdangak di daerah Bulu, Sukoharjo; Implikasinya terhadap stratigrafi batuan gunung api di Pegunungan Selatan, Jawa Tengah

    Directory of Open Access Journals (Sweden)

    Hill Gendoet Hartono


    Full Text Available, Tertiary volcanisms in the Southern Mountains, Central Jawa were started with the formation of pillow lavas having basalt to basaltic andesite in composition. This initial stage volcanism developed into a  construction period of composite volcanoes that consist of alternating basaltic to andesitic lava flows, breccias, and tuffs. The construction period could be followed by a destructive phase, producing pumice-rich pyroclastic breccias, lapillistones, and tuffs of high silica andesite to dacite, or even rhyolite in composition. A stratigraphic measuring section at Bulu area, Sukoharjo Regency, presents an alternat- ing fine-grained andesitic volcaniclastic material and some limestones, with the total thickness is 143.33 m. The thickness of bedded volcaniclastic material tends to be thickening upward from 35 m until 90 m. The grain size of the volcaniclastic material also tends to be coarsening upward from clay size through silt and fine sand to coarse sand and granules. Paleontological analysis on fossils contained in the lime- stone gives an age of Early Miocene (N7 - N9. The volcaniclastic rocks is conformably overlain by the Mandalika Formation, comprising alternating andesitic breccias, lavas, and tuffs. These data imply that the fine-grained volcaniclastic material is an initial product of the construction period of Gajahdangak Volcano in the area, that formed the Mandalika Formation. This Formation is overlain by the Semilir Formation, composed of pumice-rich pyroclastic breccias and tuffs with dacitic composition. This as- sociated volcanic rock reflects a product of a caldera explosion or a destructive phase. Based on the characteristics of lithology of volcanic products from the initial stage, to a construction and destruction period, and compiled age data, the Southern Mountains represent formal volcanic rock units that are able to be divided into many formations.  

  5. Direct seeding of Sitka spruce (Picea sitchensis (Bong.) Carr.), lodgepole pine (Pinus Contorta Dougl. v. contorta) and Siberian larch (Larix sibirica Ledeb.), on scarified seed spots in southern Iceland, using various methods

    Energy Technology Data Exchange (ETDEWEB)

    Petursson, J.G. [The Icelandic Forestry Association, Reykjavik (Iceland)


    Field experiments were established to study the potential of direct seeding of Sitka spruce, lodgepole pine and Siberian larch in southern Iceland. Five seeding methods were tried; control, covered with gravel, covered with pumice, pyramidal indentations and plastic cone. Spring- and autumn planting of one year old planting stock was also carried out for comparison. The results after two growing seasons are presented. Overall germination was 11,3% the first summer and 19,0% the second summer. Lodgepole pine had significantly highest germination or 41,3%. Sitka spruce, having 26.8% germination, and Siberian larch having 22,6% germination did not differ significantly from each other. The seeding method plastic cone gave the highest germination for all the species used, or 50,3%. Seedling mortality was high after the first winter, except in the plastic cone where more than 80% of the seedlings survived. The number of spots having at least one living seedling after two growth seasons was high in all seeding methods for lodgepole pine or 76,3-95,0% and for Sitka spruce or 71,3-86,3%. This result was however mainly explained by seedlings that germinated in the current growing season. For Siberian larch the number of the spots having one or more living seedlings was low for other seeding methods than plastic cone which gave 68,8%. No difference was found in seedling height between the methods control, covered with gravel, covered with pumice and pyramidal indentations. Survival of planted seedlings differed between planting times. Spring planting (28/6) was found more advantageous for Sitka spruce and lodgepole pine, but autumn planting (3/10) for Siberian larch. When the seeding methods were compared with planting after two growth seasons, it can be concluded that the method plastic cone was the only method tried which was compatible with planting. 45 refs, 9 figs, 14 tabs

  6. Protection of biofilms against toxic shocks by the adsorption and desorption capacity of carriers in anaerobic fluidized bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Petrozzi, S. (Biological Reaction Engineering Group, Chemical Engineering Dept., ETH, Zurich (Switzerland)); Kut, O.M. (Biological Reaction Engineering Group, Chemical Engineering Dept., ETH, Zurich (Switzerland)); Dunn, I.J. (Biological Reaction Engineering Group, Chemical Engineering Dept., ETH, Zurich (Switzerland))


    The aim of this study was to select a support medium for an anaerobic biofilm fluidized bed reactor (AFBR) for waste water treatment. Six materials, shale, pumice, porous glass, quartz sand, activated carbon and anthracite were used as carriers for the biofilm. The reactors were operated in parallel for several months with vapour condensate from a sulfite cellulose process as feed. The criteria used for the evaluation were: (a) Reproducibility of the reactor performance, (b) performance of the different carriers under various loading rates, (c) stability against toxic shock loadings using 2,4,6-trichlorophenol (TCP) as toxicant, (d) recovery capacity after intoxication and starvation, (e) adsorption/desorption behavior of the carriers. A comparison between four runs showed good reproducibility of the steady state removal rates. The performance of the reactors and the stability of the degradation rates were tested for a range of loading conditions. Unbuffered, buffered and pH controlled conditions were compared. The pumice carrier was best with respect to the degradation rate achieved per carrier mass. The response of the reactors to massive TCP step loadings was tested. Loadings less than 1.5 kg TCP/m[sup 3]d resulted in initially normal gas production rates for all the systems, except the activated carbon, whose gas production was partially inhibited from the start. After increasing the load to 1.5 kg TCP/m[sup 3]d the gas production rates of all the other reactors fell abruptly to zero. Restarting after 2 months, all reactors showed methanogenic activity without requiring new inoculum. (orig.)

  7. Microbial colonisation in diverse surface soil types in Surtsey and diversity analysis of its subsurface microbiota (United States)

    Marteinsson, V.; Klonowski, A.; Reynisson, E.; Vannier, P.; Sigurdsson, B. D.; Ólafsson, M.


    Colonisation of life on Surtsey has been observed systematically since the formation of the island 50 years ago. Although the first colonisers were prokaryotes, such as bacteria and blue-green algae, most studies have been focusing on settlement of plants and animals but less on microbial succession. To explore microbial colonization in diverse soils and the influence of associate vegetation and birds on numbers of environmental bacteria, we collected 45 samples from different soils types on the surface of the island. Total viable bacterial counts were performed with plate count at 22, 30 and 37 °C for all soils samples and the amount of organic matter and nitrogen (N) was measured. Selected samples were also tested for coliforms, faecal coliforms aerobic and anaerobic bacteria. The deep subsurface biosphere was investigated by collecting liquid subsurface samples from a 182 m borehole with a special sampler. Diversity analysis of uncultivated biota in samples was performed by 16S rRNA gene sequences analysis and cultivation. Correlation was observed between N deficits and the number of microorganisms in surface soils samples. The lowest number of bacteria (1 × 104-1 × 105 g-1) was detected in almost pure pumice but the count was significant higher (1 × 106-1 × 109 g-1) in vegetated soil or pumice with bird droppings. The number of faecal bacteria correlated also to the total number of bacteria and type of soil. Bacteria belonging to Enterobacteriaceae were only detected in vegetated and samples containing bird droppings. The human pathogens Salmonella, Campylobacter and Listeria were not in any sample. Both thermophilic bacteria and archaea 16S rDNA sequences were found in the subsurface samples collected at 145 m and 172 m depth at 80 °C and 54 °C, respectively, but no growth was observed in enrichments. The microbiota sequences generally showed low affiliation to any known 16S rRNA gene sequences.

  8. Microbial colonization in diverse surface soil types in Surtsey and diversity analysis of its subsurface microbiota (United States)

    Marteinsson, V.; Klonowski, A.; Reynisson, E.; Vannier, P.; Sigurdsson, B. D.; Ólafsson, M.


    Colonization of life on Surtsey has been observed systematically since the formation of the island 50 years ago. Although the first colonisers were prokaryotes, such as bacteria and blue-green algae, most studies have been focused on the settlement of plants and animals but less on microbial succession. To explore microbial colonization in diverse soils and the influence of associated vegetation and birds on numbers of environmental bacteria, we collected 45 samples from different soil types on the surface of the island. Total viable bacterial counts were performed with the plate count method at 22, 30 and 37 °C for all soil samples, and the amount of organic matter and nitrogen (N) was measured. Selected samples were also tested for coliforms, faecal coliforms and aerobic and anaerobic bacteria. The subsurface biosphere was investigated by collecting liquid subsurface samples from a 181 m borehole with a special sampler. Diversity analysis of uncultivated biota in samples was performed by 16S rRNA gene sequences analysis and cultivation. Correlation was observed between nutrient deficits and the number of microorganisms in surface soil samples. The lowest number of bacteria (1 × 104-1 × 105 cells g-1) was detected in almost pure pumice but the count was significantly higher (1 × 106-1 × 109 cells g-1) in vegetated soil or pumice with bird droppings. The number of faecal bacteria correlated also to the total number of bacteria and type of soil. Bacteria belonging to Enterobacteriaceae were only detected in vegetated samples and samples containing bird droppings. The human pathogens Salmonella, Campylobacter and Listeria were not in any sample. Both thermophilic bacteria and archaea 16S rDNA sequences were found in the subsurface samples collected at 145 and 172 m depth at 80 and 54 °C, respectively, but no growth was observed in enrichments. The microbiota sequences generally showed low affiliation to any known 16S rRNA gene sequences.

  9. Late Miocene ignimbrites at the southern Puna-northern Sierras Pampeanas border (˜27°S): Stratigraphic correlation (United States)

    Montero-López, Carolina; Guzmán, Silvina; Barrios, Fabiola


    New field observations and petrographic and geochemical data of pyroclastic deposits exposed along the Las Papas valley (border between southern Puna and northern Sierras Pampeanas, Argentina) and further north, lead us to propose a new stratigraphic correlation and classification of the late Miocene volcanism in this area. We redefine the Las Papas, Las Juntas, Aguada Alumbrera and Rosada ignimbrites and define the Agua Caliente and Del Medio ignimbrites. The whole set of ignimbrites are rhyolites and less frequently dacites of calc-alkaline affinity. In the present contribution we divide ignimbrites into the Agua Negra and Rincón groups, based mainly on their geochemical signature. The Agua Negra Group is formed by the Las Papas and Las Juntas ignimbrites, indurated and welded, lithic-rich, with crystal-poor pumices and crystal-rich matrix. The Rincón Group comprises the Agua Caliente, Aguada Alumbrera, Rosada and Del Medio ignimbrites, with variable welding degrees, lithic and crystal content. The greater enrichment of crystals in the matrix in comparison with the crystal content in pumices indicates significant elutriation during flow transport and thus volume estimations are to be considered lower bounds for the actual erupted volume. The total minimum estimated volume for the ignimbrites of the Agua Negra and Rincón groups is 2.8 km3 (2.3 km3 DRE). Field relationships and new analytical data indicate that the different acid ignimbrites that crop out in this small area are related to at least two different magma chambers. The widespread Quaternary volcanism in this area covers the older deposits, thus making it difficult to recognize the volcanic centers that produced these late Miocene ignimbrites.

  10. Estimation of septic tank setback distances based on transport of E. coli and F-RNA phages. (United States)

    Pang, Liping; Close, Murray; Goltz, Mark; Sinton, Lester; Davies, Helen; Hall, Carollyn; Stanton, Greg


    Setback distances between septic tank systems and the shorelines of Lake Okareka, New Zealand were determined from model simulations for a worst-case scenario, using the highest hydraulic conductivity and gradient measured in the field, removal rates of the microbial indicators (Escherichia coli and F-RNA phages) determined from a column experiment, and maximum values of the design criteria for the disposal system, and assuming an absence of an unsaturated zone, a continuous discharge of the raw effluent from a failed or non-complying treatment system (both indicators at concentrations of 1x10(7) counts/100 ml) into the groundwater and no sorption of pathogens in the aquifer. Modelling results suggest that the minimal setback distances were 16 m to satisfy the New Zealand Recreational Water Quality Guidelines for E. coli <126 per 100 ml (Ministry for the Environment, 1999) and 48 m to meet the Drinking-Water Standards for New Zealand 2000 for enteric virus <1 per 100 l (Ministry of Health, 2000). These distances may be applicable for other lakeshores in pumice sand aquifers with groundwater velocities <7 m/day. Findings of laboratory column and batch experiments provided an insight into the microbial attenuation and transport processes in pumice sand aquifers. Bacterial removal was predominately through filtration (87-88%) and partially by die-off (12-13%), while viral removal was by both die-off (45%) and filtration (55%). In addition, microbial die-off in groundwater without aquifer material (i.e., free microbes) was much lower than die-off in groundwater with aquifer material (i.e., sorbed microbes) and contributed only 2-6% to the total removal. This implies that the setback distances estimated from die-off rates for the free microbes, determined in the laboratory without considering aquifer media and other removal processes, which are often reported in the literature, could be larger than necessary.

  11. Pre-eruptive conditions of dacitic magma erupted during the 21.7 ka Plinian event at Nevado de Toluca volcano, Central Mexico (United States)

    Arce, J. L.; Gardner, J. E.; Macías, J. L.


    The Nevado de Toluca volcano in Central Mexico has been active over the last ca. 42 ka, during which tens of km3 of pyroclastic material were erupted and two important Plinian-type eruptions occurred at ca. 21.7 ka (Lower Toluca Pumice: LTP) and ca. 10.5 ka (Upper Toluca Pumice: UTP). Samples from both the LTP and UTP contain plagioclase, amphibole, iron-titanium oxides, and minor anhedral biotite, set in a vesicular, rhyolitic, glassy matrix. In addition, UTP dacites contain orthopyroxene. Analysis of melt inclusions in plagioclase phenocrysts yields H2O contents of 2-3.5 wt.% for LTP and 1.3-3.6 wt.% for UTP samples. Ilmenite-ulvospinel geothermometry yields an average temperature of ~ 868 °C for the LTP magma (hotter than the UTP magma, ~ 842 °C; Arce et al., 2006), whereas amphibole-plagioclase geothermometry yields a temperature of 825-859 °C for the LTP magma. Water-saturated experiments using LTP dacite suggest that: (i) amphibole is stable above 100 MPa and below 900 °C; (ii) plagioclase crystallizes below 250-100 MPa at temperatures of 850-900 °C; and (iii) pyroxene is stable only below pressures of 200-100 MPa and temperatures of 825-900 °C. Comparison of natural and experimental data suggests that the LTP dacitic magma was stored at 150-200 MPa (5.8-7.7 km below the volcano summit). No differences in pressure found between 21.7 ka and 10.5 ka suggest that these two magmas were stored at similar depths. Orthopyroxene produced in lower temperature LTP experiments is compositionally different to those found in UTP natural samples, suggesting that they originated in two different magma batches. Whole-rock chemistry, petrographic features, and mineral compositions suggest that magma mixing was responsible for the generation of the dacitic Plinian LTP eruption.

  12. Primary and secondary fragmentation of crystal-bearing intermediate magma (United States)

    Jones, Thomas J.; McNamara, Keri; Eychenne, Julia; Rust, Alison C.; Cashman, Katharine V.; Scheu, Bettina; Edwards, Robyn


    Crystal-rich intermediate magmas are subjected to both primary and secondary fragmentation processes, each of which may produce texturally distinct tephra. Of particular interest for volcanic hazards is the extent to which each process contributes ash to volcanic plumes. One way to address this question is by fragmenting pyroclasts under controlled conditions. We fragmented pumice samples from Soufriere Hills Volcano (SHV), Montserrat, by three methods: rapid decompression in a shock tube-like apparatus, impact by a falling piston, and milling in a ball mill. Grain size distributions of the products reveal that all three mechanisms produce fractal breakage patterns, and that the fractal dimension increases from a minimum of 2.1 for decompression fragmentation (primary fragmentation) to a maximum of 2.7 by repeated impact (secondary fragmentation). To assess the details of the fragmentation process, we quantified the shape, texture and components of constituent ash particles. Ash shape analysis shows that the axial ratio increases during milling and that particle convexity increases with repeated impacts. We also quantify the extent to which the matrix is separated from the crystals, which shows that secondary processes efficiently remove adhering matrix from crystals, particularly during milling (abrasion). Furthermore, measurements of crystal size distributions before (using x-ray computed tomography) and after (by componentry of individual grain size classes) decompression-driven fragmentation show not only that crystals influence particular size fractions across the total grain size distribution, but also that free crystals are smaller in the fragmented material than in the original pumice clast. Taken together, our results confirm previous work showing both the control of initial texture on the primary fragmentation process and the contributions of secondary processes to ash formation. Critically, however, our extension of previous analyses to characterisation

  13. Lichen Persistence and Recovery in Response to Varied Volcanic Disturbances (United States)

    Nelson, P.; Wheeler, T. B.


    Volcanic eruptions produce many ecological disturbances that structure vegetation. While lichens are sensitive to disturbances, little is known about their responses to volcanic disturbances, except for colonization of lava. We examined lichen community responses through time to different disturbances produced by the May 1, 2008 eruption of Volcan Chaiten in south-central Chile. Pre-eruption vegetation near the volcano was old-growth Valdivian temperate rainforest dominated by closed-canopy Nothofagus sp... In 2012, we installed thirteen 1-acre plots across volcanic disturbance zones on which a time-constrained search was done for all macrolichen species, each of which was assigned an approximate log10 categorical abundance. We also installed a 0.2 m2 quadrat on two representative trees per plot for repeat photography of lichen cover. We remeasured at least one plot per disturbance zone in 2014 and re-photographed tree quadrats in 2013 and 2014. We then analyzed species composition and abundance differences among disturbance zones. In 2012, the blast (pyroclastic density flow), scorch (standing scorched forest at the edge of the blast) and deep tephra (>10 cm) zones had the lowest lichen species richness (5-13 species), followed by reference (unimpacted) and shallow (lichen species since 2012 while the light tephra and reference were essentially unchanged. Gravel rain, gravel rain + pumice and flooded forest plots all had about the same number of species in 2014 as 2012. Lichen colonization and growth in tree quadrats varied widely, from very little colonization in the blast to prolific colonization in the gravel rain + pumice zone. Lichen's varied responses to different volcanic disturbances were attributable to varying degrees of mortality and subsequent availability of substrate, quantity of light and removal of competitors. While sensitive to disturbance, lichens are apparently resilient to and can quickly recolonize after a variety of large, violent volcanic

  14. Kaguyak dome field and its Holocene caldera, Alaska Peninsula (United States)

    Fierstein, J.; Hildreth, W.


    Kaguyak Caldera lies in a remote corner of Katmai National Park, 375??km SW of Anchorage, Alaska. The 2.5-by-3-km caldera collapsed ~ 5.8 ?? 0.2??ka (14C age) during emplacement of a radial apron of poorly pumiceous crystal-rich dacitic pyroclastic flows (61-67% SiO2). Proximal pumice-fall deposits are thin and sparsely preserved, but an oxidized coignimbrite ash is found as far as the Valley of Ten Thousand Smokes, 80??km southwest. Postcaldera events include filling the 150-m-deep caldera lake, emplacement of two intracaldera domes (61.5-64.5% SiO2), and phreatic ejection of lakefloor sediments onto the caldera rim. CO2 and H2S bubble up through the lake, weakly but widely. Geochemical analyses (n = 148), including pre-and post-caldera lavas (53-74% SiO2), define one of the lowest-K arc suites in Alaska. The precaldera edifice was not a stratocone but was, instead, nine contiguous but discrete clusters of lava domes, themselves stacks of rhyolite to basalt exogenous lobes and flows. Four extracaldera clusters are mid-to-late Pleistocene, but the other five are younger than 60??ka, were truncated by the collapse, and now make up the steep inner walls. The climactic ignimbrite was preceded by ~ 200??years by radial emplacement of a 100-m-thick sheet of block-rich glassy lava breccia (62-65.5% SiO2). Filling the notches between the truncated dome clusters, the breccia now makes up three segments of the steep caldera wall, which beheads gullies incised into the breccia deposit prior to caldera formation. They were probably shed by a large lava dome extruding where the lake is today.

  15. Hazard assessment of long-range tephra dispersal for a Plinian eruptive scenario at Popocatépetl volcano (Mexico). Inplications on civil aviation (United States)

    Bonasia, R.; Scaini, C.; Capra, L.; Nathenson, M.; Siebe, C.; Arana-Salinas, L.; Folch, A.


    Popocatépetl is one of the most active volcanoes in Mexico threatening a densely populated area that includes Mexico City with more than 20 million inhabitants. The destructive potential of this volcano is demonstrated by its Late Pleistocene-Holocene eruptive activity, which has been characterized by recurrent Plinian eruptions of large magnitude. The current volcanic hazards map, reconstructed after the crisis occurred in 1994, considers the potential occurrence of different volcanic phenomena, including pyroclastic density currents and lahars. However, no quantitative assessment of the tephra dispersal hazard, especially related to atmospheric dispersal, has been performed. Given the high number of important airports in the surroundings of Popocatépetl volcano and considering the potential threat posed to civil aviation in Mexico and adjacent regions in case of a Plinian eruption, a hazard assessment for tephra dispersal is strongly required. In this work we present the first probabilistic tephra dispersal hazard assessment for Popocatépetl volcano. We compute probabilistic hazard maps for critical thresholds of airborne ash concentrations at different flight levels. Tephra dispersal modelling is performed using the FALL3D numerical model. Probabilistic hazard maps are built for a Plinian eruptive scenario defined on the basis of geological field data for the 'Ochre Pumice' Plinian eruption (4965 14C yrBP). FALL3D model input eruptive parameters are constrained through an inversion method carried out with the semi-analytical HAZMAP model and are varied sampling them on the base of a Probability Density Function. We analyze the influence of seasonal variations on ash dispersal and estimate the average persistence of critical ash concentrations at relevant locations and airports. This study assesses the impact that a Plinian eruption similar to the Ochre Pumice eruption would have on the main airports of Mexico and adjacent areas. The hazard maps presented here

  16. Petrogenesis and depositional history of felsic pyroclastic rocks from the Melka Wakena archaeological site-complex in South central Ethiopia (United States)

    Resom, Angesom; Asrat, Asfawossen; Gossa, Tegenu; Hovers, Erella


    The Melka Wakena archaeological site-complex is located at the eastern rift margin of the central sector of the Main Ethiopian Rift (MER), in south central Ethiopia. This wide, gently sloping rift shoulder, locally called the "Gadeb plain" is underlain by a succession of primary pyroclastic deposits and intercalated fluvial sediments as well as reworked volcaniclastic rocks, the top part of which is exposed by the Wabe River in the Melka Wakena area. Recent archaeological survey and excavations at this site revealed important paleoanthropological records. An integrated stratigraphic, petrological, and major and trace element geochemical study has been conducted to constrain the petrogenesis of the primary pyroclastic deposits and the depositional history of the sequence. The results revealed that the Melka Wakena pyroclastic deposits are a suite of mildly alkaline, rhyolitic pantellerites (ash falls, pumiceous ash falls and ignimbrites) and slightly dacitic ash flows. These rocks were deposited by episodic volcanic eruptions during early to middle Pleistocene from large calderas along the Wonji Fault Belt (WFB) in the central sector of the MER and from large silicic volcanic centers at the eastern rift shoulder. The rhyolitic ash falls, pumiceous ash falls and ignimbrites have been generated by fractional crystallization of a differentiating basaltic magma while the petrogenesis of the slightly dacitic ash flows involved some crustal contamination and assimilation during fractionation. Contemporaneous fluvial activities in the geomorphologically active Gadeb plain deposited overbank sedimentary sequences (archaeology bearing conglomerates and sands) along meandering river courses while a dense network of channels and streams have subsequently down-cut through the older volcanic and sedimentary sequences, redepositing the reworked volcaniclastic sediments further downstream.

  17. Character, mass, distribution, and origin of tephra-fall deposits of the 1989-1990 eruption of redoubt volcano, south-central Alaska (United States)

    Scott, W.E.; McGimsey, R.G.


    The 1989-1990 eruption of Redoubt Volcano spawned about 20 areally significant tephra-fall deposits between December 14, 1989 and April 26, 1990. Tephra plumes rose to altitudes of 7 to more than 10 km and were carried mainly northward and eastward by prevailing winds, where they substantially impacted air travel, commerce, and other activities. In comparison to notable eruptions of the recent past, the Redoubt events produced a modest amount of tephra-fall deposits - 6 ?? 107 to 5 ?? 1010 kg for individual events and a total volume (dense-rock equivalent) of about 3-5 ?? 107 m3 of andesite and dacite. Two contrasting tephra types were generated by these events. Pumiceous tephra-fall deposits of December 14 and 15 were followed on December 16 and all later events by fine-grained lithic-crystal tephra deposits, much of which fell as particle aggregates. The change in the character of the tephra-fall deposits reflects their fundamentally different modes of origin. The pumiceous deposits were produced by magmatically driven explosions. The finegrained lithic-crystal deposits were generated by two processes. Hydrovolcanic vent explosions generated tephrafall deposits of December 16 and 19. Such explosions continued as a tephra source, but apparently with diminishing importance, during events of January and February. Ash clouds of lithic pyroclastic flows generated by collapse of actively growing lava domes probably contributed to tephra-fall deposits of all events from January 2 to April 26, and were the sole source of tephra fall for at least the last 4 deposits. ?? 1994.

  18. The eruption history of the quaternary Eifel volcanic fields: Implications from the ELSA - Tephra - Stack (United States)

    Förster, Michael; Sirocko, Frank


    Numerous tephra layers occur in maar sediments in the quaternary Eifel volcanic fields. The sediments were systematically drilled and cored since 1998 by the Eifel Laminated Sediment Archive project (ELSA) (Sirocko et al. 2013). These maar sediments are laminated and the tephra is easily recognizeable by a coarser grain size. Additionaly, tephra layers appear dark grey to black in color. The ashes were sieved to a fraction of 250 - 100 µm and sorted into grains of: reddish and greyish sandstone, quartz, amphibole, pyroxene, scoria and pumice, sanidine, leucite and biotite. A minimum of 100 grains for each tephra layer were used for a sediment petrographic tephra characterisation (SPTC). The grain counts resemble the vol. -% of each grain species. Three types of tephra could be identified by their distinctive grain pattern: (1) phreatomagmatic tephra, rich in basement rocks like greyish/reddish sandstone and quartz. (2) Strombolian tephra, rich in scoria and mafic minerals like pyroxene. (3) evolved tephra, rich in sanidine and pumice. 16 drill-cores, covering the last 500 000 years have been examined. Younger cores were dated by 14C ages and older cores by optical stimulated luminescence. Independently from this datings, the drill-cores were cross-correlated by pollen and the occurences of specific marker-tephra layers, comprising characteristic grain-types. These marker-tephra layers are especially thick and of evolved composition with a significant abundance of sanidine and pumice. The most prominent tephra layers of this type are the Laacher See tephra, dated to 12 900 b2k by Zolitschka (1998), the 40Ar/39Ar dated tephra layers of Dümpelmaar, Glees and Hüttenberg, dated to 116 000 b2k, 151 000 b2k and 215 000 b2k by van den Bogaard & Schmincke (1990), van den Bogaard et al. (1989). These datings set the time-frame for the eruption-phases of the quaternary Eifel Volcanic Fields. Our study refines these findings and shows that phases of activity are very

  19. Shallow conduit processes of the 1991 Hekla eruption, Iceland (United States)

    Gudnason, J.; Thordarson, T.; Houghton, B. F.


    On January 17, 1991 at 17:00 hrs, the 17th eruption of Hekla since 1104AD began. Lasting for almost two months, it produced 0.02 km3 of icelandite tephra and ~0.15km3 of icelandite lava. This eruption was the third of four eruptions since 1980 with a recurrence period of approximately 10 years, as opposed to a recurrence interval of c. 55 years for the eruptions in the period 1104AD to 1947AD. [1] The last four Hekla eruptions are typified by a 0.5-2 hour-long initial phase of subplinian intensity and discharge ranging from 2900-6700 m3/s [2]. In all 4 events the inital phase was followed by a sustained and relatively low-discharge(sorted tephra fall covering >20,000 km2. Here we examine the first phase of the Hekla 1991 eruption with focus on vesiculation and fragmentation processes in the shallow conduit and ash production. Samples of the tephra fall were collected on snow immediately after the initial phase at multiple sites providing a representative spatial coverage within the 0.1mm isopach [3]. This set was augmented by samples collected in 2012 to provide tighter coverage of near vent region. Grain size of all samples has been measured down to 1 micron. Density measurements have been conducted on 4 near-vent pumice samples (100 clasts each) and the pumice vesicle size distribution has been determined in a selected subset of clasts. The reconstructed whole deposit grain size distribution exhibits a unimodal, log-normal distribution peaking at -3 phi, typical of dry, magmatic fragmentation. Pumice densities range from 520-880 kg/m3 and exhibit a tight unimodal and log-normal distribution indicating a mean vesicularity of 77% to 79% for the magma erupted during the initial phase. Along with preliminary results for bubble number density and vesicle size distribution this implies a single late-stage homogeneous bubble nucleation and very uniform conditions of magma fragmentation during this short-lived initial phase of the Hekla 1991 eruption. 1. Gudmundsson, A

  20. Long-term changes in explosive and effusive behaviour at andesitic arc volcanoes: Chronostratigraphy of the Centre Hills Volcano, Montserrat (United States)

    Coussens, Maya; Cassidy, Michael; Watt, Sebastian F. L.; Jutzeler, Martin; Talling, Peter J.; Barfod, Dan; Gernon, Thomas M.; Taylor, Rex; Hatter, Stuart J.; Palmer, Martin R.; Montserrat Volcano Observatory


    Volcanism on Montserrat (Lesser Antilles arc) has migrated southwards since the formation of the Silver Hills 2.5 Ma, and has formed three successively active volcanic centres. The Centre Hills volcano was the focus of volcanism from 1-0.4 Ma, before activity commenced at the currently active Soufrière Hills volcano. The history of activity at these two volcanoes provides an opportunity to investigate the pattern of volcano behaviour on an andesitic arc island over the lifetime of individual volcanoes. Here, we describe the pyroclastic stratigraphy of subaerial exposures around central Montserrat; identifying 11 thick (> 1 m) pumiceous units derived from sustained explosive eruptions of Centre Hills from 0.8-0.4 Ma. Over 10 other, less well- exposed pumiceous units have also been identified. The pumice-rich units are interbedded with andesite lava breccias derived from effusive, dome-forming eruptions of Centre Hills. The stratigraphy indicates that large (up to magnitude 5) explosive eruptions occurred throughout the history of Centre Hills, alongside effusive activity. This behaviour at Centre Hills contrasts with Soufrière Hills, where deposits from sustained explosive eruptions are much less common and restricted to early stages of activity at the volcano, from 175-130 ka. Subsequent eruptions at Soufriere Hills have been dominated by andesitic effusive eruptions. The bulk composition, petrography and mineral chemistry of volcanic rocks from Centre Hills and Soufrière Hills are similar throughout the history of both volcanoes, except for occasional, transient departures to different magma compositions, which mark shifts in vent location or dominant eruption style. For example, the final recorded eruption of Centre Hills, before the initiation of activity at Soufrière Hills, was more silicic than any other identified eruption on Montserrat; and the basaltic South Soufrière Hills episode marked the transition to the current stage of predominantly effusive


    Suarez-Plascencia, C.; Delgado-Argote, L. A.; Nunez-Cornu, F. J.


    The Metropolitan Area of Guadalajara (MAG) was built over pumice deposits generated during Quaternary activity in the Sierra la Primavera, that covered a thick sequence of basaltic, dacitic, rhyolitic lava flows, ignimbrites and fluvial-lacustrine deposits. The most complete stratigraphic section is observed in different sections of the Rio Grande de Santiago cliff, located north of the city. Five distinctive geoforms were identified: 1) the cliff of the Rio Grande de Santiago (CRGS) is a tectonic erosive depression with average depth of 500 m and 3.5 km width. Structurally, in the San Gaspar zone, south of the union of Verde river with Santiago river, we identified normal faults with left-lateral motion and oriented 191°/89° on basaltic lavas. In the Colimilla dam, 1297 meters above sea level, we observed lateral faulting with normal component (267°/81°) where jumps as high as 30 m were observed. Lava flows are sheared parallel to the Verde river. In the Puente Arcediano zone, where the base of the sequence is apparent, faults have a dominant orientation of 188°/75° on andesitic flows, whereas on pumice ignimbrites they show a shearing with a direction of 92°/84° parallel to the Verde river. 2) The Sierra la Primavera, to the southwest of MAG is a caldera formed by a series of domes, flows, and pyroclastic deposits with rhyolitic composition. 3) The southern Guadalajara volcanic chain system, which is formed by several volcanic cones and flows of basaltic-andesitic composition and Plio-Pleistocene age, oriented NW-SE, developed over the San Gaspar ignimbrite (4.8 m.a.). 4) Los Colomos and Alcalde-Barranquitas cliff system, which form dendrite networks developed on pumice deposits, where most of the cliffs were deep and narrow. The origin of the cliffs might be associated with observed faults or fracture zones in the CRGS. 5) Wavy plains of Atemajac and Tesistán valleys, which are characterized by hills and wide plains. The system of cliffs controlled the

  2. 3D imaging of vesicles in hyaloclastic fragments - clues to syn-eruptive shear conditions (United States)

    Helo, C.; Flaws, A.; Hess, K.; Franz, A.; Clague, D. A.; Dingwell, D. B.


    3D imaging of stretched vesicles in hyaloclastic fragments has been used to investigate the shear environment of mild pyroclastic eruptions at mid-ocean ridges. X-ray computed tomography offers an attractive non-invasive method to investigate geomaterials at a high resolution for the geometry of the different phases. In this study, we have imaged vesicles within two types of basaltic glass fragments. Stretched, ellipsoid-shaped vesicles in thin limu o Pele and tubular vesicles in a pumiceous fragment. Both types originate from pyroclastic activity on Axial Seamount, Juan de Fuca ridge. Rapid quenching of the glass has prevented extensive bubble relaxation and information about syn-eruptive shear and differential stress conditions is stored, as the dimensions of a stretched bubble directly relates to the extent and mode of shearing. The X-ray tomography data was processed using a set of codes based on edge detection and ellipsoid fitting to acquire quantitative information on the shape of the stretched vesicles. Preliminary results demonstrate, that the geometry of the stretched vesicles, e.g., the elongation of the vesicle with respect to the calculated undeformed radius, is in accordance with simple shear scenarios. Stored differential stress ranges from 5 kPa to 90 kPa with shear rates between 3.2x102 s-1 and 5.7x3 s-1 within a single limu o Pele fragment. This range may be explained by either variable time available for relaxation as the cooling front proceeds through the fragment, complex interplay in space and time between fragmentation and quenching, bubble clusters mutually inhibiting each others extend of deformation, or any combination of these. Bubble relaxation time scales are less then 0.005 s providing constraints on the timeframe for cooling to the glass transition. Qualitative analyses of the tube pumice indicates that the tubular structures grow in length by coalescence of vertically aligned ellipsoid-shaped vesicles, and in width by coalescence of

  3. Emplacement processes of tuffaceous sandstones at IODP Site C0011B, Nankai Trough, derived from modal analysis (United States)

    Schindlbeck, J. C.; Kutterolf, S.; Freundt, A.


    Tuffaceous sandstones are characterized by their high amount (25 to 75%) of pyroclasts in their modal composition. During IODP Expedition 322 three interbeds of tuffaceous sandstones have been found within a moderately lithified and bioturbated silty claystone sequence in the late Miocene (>7.07 to ~9.0 Ma) upper part of the middle Shikoku Basin facies. Of the three sandstones, units 1 and 2 are single beds whereas unit 3 is composed of three beds. Modal analyses of 29 sandstone thin sections reveal systematic vertical changes within each bed. Generally low-density pyroclasts are enriched at the top (50-60 vol%) of each sandstone bed whereas dense lithic components (25-30 vol%) and minerals (25-30 vol%) are enriched at the bottom. The vertically varying abundance of various types of lithic fragments (sedimentary, volcanoclastic and metamorphic) suggests that these have also been segregated according to their respective densities. The highest amount of fine-grained matrix glass is found in the middle of each bed. Pumice and lithic fragments in the middle and upper parts of the sandstone beds carry ash coatings. For sandstone package 3, in contrast to 1 and 2, core pictures and thin section analyses indicate a subdivision in three units showing the same significant variations in top to bottom enrichment. This suggests three sedimentation events following each other in short time intervals. Glass and mineral chemistry of each sandstone bed show no significant vertical variations. Specifically the matrix glass-shard major element compositions are identical to the pumice clast composition in each tuffaceous sandstone bed. The compositions of amphibole and pyroxene crystals differ only slightly between the sandstone packages. Application of the Ridolfi et al. (2009) thermobarometric calculations to amphiboles of sandstone packages 1 and 2 suggests that each of these was derived from a volcanic system comprising both a deep and a shallow magma reservoir. Thickness and

  4. Surficial Geology of Mount Rainier National Park, Washington (United States)

    Crandell, Dwight Raymond


    Much of the ground surface around Mount Rainier volcano is directly underlain by loose geologic deposits that veneer the hard rock formations. Examples of these deposits are sand and gravel bars along the rivers, ridges of loose rock debris beside the glaciers, and sloping aprons of rock fragments beneath almost every cliff. Even though they are generally thin and inconspicuous when compared with the rock formations, these surficial deposits are clues to geologic events that have profoundly influenced the shape of the park's landscape. Thus, from the character and extent of glacial deposits one can judge the age and size of former glaciers that carved the cirques and deep canyons of the park; from the mudflows which streamed down nearly every valley one can infer the age and size of huge landslides of the past that helped determine Mount Rainier's present shape; and from the pumice deposits some of the volcano's recent eruptive activity can be reconstructed. The map (plate 1, in pocket) that accompanies this description of the surficial deposits of Mount Rainier National Park shows the location of the various geologic formations, and the explanation shows the formations arranged in order of their relative age, with the oldest at the bottom. The text describes the surficial deposits in sequence from older to younger. A discussion of the pumice deposits of the park, which were not mapped, is followed by a description of the formations shown on the geologic map. Inspection of the geologic map may lead the viewer to question why the surficial deposits are shown in more detail in a zone several miles wide around the base of the volcano than elsewhere. This is partly because the zone is largely near or above timberline, relatively accessible, and the surficial deposits there can be readily recognized, differentiated, and mapped. In contrast, access is more difficult in the heavily timbered parts of the park, and surficial deposits there are generally blanketed by a dense

  5. Dynamics of an unusual cone-building trachyte eruption at Pu`u Wa`awa`a, Hualālai volcano, Hawai`i (United States)

    Shea, Thomas; Leonhardi, Tanis; Giachetti, Thomas; Lindoo, Amanda; Larsen, Jessica; Sinton, John; Parsons, Elliott


    The Pu`u Wa`awa`a pyroclastic cone and Pu`u Anahulu lava flow are two prominent monogenetic eruptive features assumed to result from a single eruption during the trachyte-dominated early post-shield stage of Hualālai volcano (Hawaíi). Púu Wa`awa`a is composed of complex repetitions of crudely cross-stratified units rich in dark dense clasts, which reversely grade into coarser pumice-rich units. Pyroclasts from the cone are extremely diverse texturally, ranging from glassy obsidian to vesicular scoria or pumice, in addition to fully crystalline end-members. The >100-m thick Pu`u Anahulu flow is, in contrast, entirely holocrystalline. Using field observations coupled with whole rock analyses, this study aimed to test whether the Pu`u Wa`awa`a tephra and Pu`u Anahulu lava flows originated from the same eruption, as had been previously assumed. Crystal and vesicle textures are characterized along with the volatile contents of interstitial glasses to determine the origin of textural variability within Pu`u Wáawáa trachytes (e.g., magma mixing vs. degassing origin). We find that (1) the two eruptions likely originated from distinct vents and magma reservoirs, despite their proximity and similar age, (2) the textural diversity of pyroclasts forming Pu`u Wa`awa`a can be fully explained by variable magma degassing and outgassing within the conduit, (3) the Pu`u Wa`awa`a cone was constructed during explosions transitional in style between violent Strombolian and Vulcanian, involving the formation of a large cone and with repeated disruption of conduit plugs, but without production of large pyroclastic density currents (PDCs), and (4) the contrasting eruption styles of Hawaiian trachytes (flow-, cone-, and PDC-forming) are probably related to differences in the outgassing capacity of the magmas prior to reaching the surface and not in intrinsic compositional or temperature properties. These results further highlight that trachytes are "kinetically faster" magmas compared

  6. Assessing New and Old Methods in Paleomagnetic Paleothermometry: A Test Case at Mt. St. Helens, USA (United States)

    Bowles, J. A.; Gerzich, D.; Jackson, M. J.


    Paleomagnetic data can be used to estimate deposit temperatures (Tdep) of pyroclastic density currents (PDCs). The typical method is to thermally demagnetize oriented lithic clasts incorporated into the PDC. If Tdep is less than the maximum Curie temperature (Tc), the clast is partially remagnetized in the PDC, and the unblocking temperature (Tub) at which this remagnetization is removed is an estimate of Tdep. In principle, juvenile clasts can also be used, and Tub-max is taken as the minimum Tdep. This all assumes blocking (Tb) and unblocking temperatures are equivalent and that the blocking spectrum remains constant through time. Recent evidence shows that Tc in many titanomagnetites is a strong function of thermal history due to a crystal-chemical reordering process. We therefore undertake a study designed to test some of these assumptions and to assess the extent to which the method may be biased by a Tb spectrum that shifts to higher T during cooling. We also explore a new magnetic technique that relies only on stratigraphic variations in Tc. Samples are from the May 18, 1980 PDCs at Mt. St. Helens, USA. Direct temperature measurements of the deposits were 297 - 367°C. At sites with oriented lithics, standard methods provide a Tdep range that overlaps with measured temperatures, but is systematically higher by a few 10s of °C. By contrast, pumice clasts all give Tdep_min estimates that greatly exceed lithic estimates and measured temperatures. We attribute this overestimate to two causes: 1) Tc and Tub systematically increase with depth as a result of the reordering process. This results in Tdep_min estimates that vary by 50°C and increase with depth. 2) MSH pumice is multi-domain, where Tub > Tb, resulting in a large overestimate in Tdep. At 5 sites, stratigraphic variations in Tc were conservatively interpreted in terms of Tdep as 300°C. More sophisticated modeling of the time-temperature-depth evolution of Tc allows us to place tighter constraints on

  7. Somma-Vesuvius Plinian Eruptions fed by mafic magma: insights from bubbles in melt inclusions (United States)

    Esposito, R.; Redi, D.; Cannatelli, C.; Danyushevsky, L. V.; Lima, A.; Bodnar, R. J.; De Vivo, B.


    Mt. Somma-Vesuvius Plinian eruptions were first described by Pliny the younger in 79 AD during the infamous eruption that destroyed Pompeii. Today, such eruptions are still a concern to the nearly 3 million people living in the Naples metropolitan area. Understanding the source for Mt. Somma-Vesuvius magma and the coexisting volatile phase is vital to better constrain the long-term eruptive behavior of this volcano. In the present study, ~ 50 olivine phenocrysts were selected from lavas and pumices produced during mild effusive events referred to as inter-Plinian eruptions, and from highly explosive Plinian eruptions that occurred at Mt. Somma-Vesuvius between 33000 ka and 1631 AD. Selected olivine phenocrysts containing MI were examined petrographically and analyzed for Fo content. Fo varies from 69 to 73 mole% for inter-Plinian olivine crystals and from 84 to 90 mole% with one zoned olivine containing 76-81 mole% Fo, for Plinian olivine crystals. Investigated MI vary from slightly crystallized to highly crystallized. Selected crystallized MI were reheated using the Vernadsky stage, and quenched to a homogeneous glass (Group 1) or glass plus a vapor bubble (Group 2). On one hand, MI of Group 1 are hosted in olivine ranging from Fo72 to Fo76 and were all erupted from the Pompeii eruption (white pumice deposit). On the other hand, MI of Group 2 are trapped in olivine ranging from Fo69 to Fo81 and from Fo84 to Fo90, and the hosts are representative of both Plinian and inter-Plinian events. The only eruption where Group-1 and Group-2 MI coexist is the Pompeii eruption. Group 2 MIs were further analyzed by Raman to test for the presence of volatiles (CO2 or H2O) in the vapor bubbles. CO2 was detected in all MI analyzed. CO2 density was determined using the distance between the two Fermi-diad peaks, and ranges between 0.14 and 0.55 g/cm3. Six MI also showed evidence for H2O in the vapor bubble. In addition, carbonates were detected at the glass-vapor interface of five

  8. Topographic controls on pyroclastic density current dynamics: Insight from 18 May 1980 deposits at Mount St. Helens, Washington (USA) (United States)

    Brand, Brittany D.; Bendaña, Sylvana; Self, Stephen; Pollock, Nicholas


    Our ability to interpret the deposits of pyroclastic density currents (PDCs) is critical for understanding the transport and depositional processes that control PDC dynamics. This paper focuses on the influence of slope on flow dynamics and criticality as recorded in PDC deposits from the 18 May 1980 eruption of Mt. St. Helens (USA). PDC deposits are found along the steep flanks (10°-30°) and across the pumice plain ( 5°) up to 8 km north of the volcano. Granulometry, componentry and descriptions of depositional characteristics (e.g., bedform morphology) are recorded with distance from source. The pumice plain deposits are primarily thick (3-12 m), massive and poorly-sorted, and represent deposition from a series of concentrated PDCs. By contrast, the steep flank deposits are stratified to cross-stratified, suggesting deposition from PDCs where turbulence strongly influenced transport and depositional processes. We propose that acceleration of the concentrated PDCs along the steep flanks resulted in thinning of the concentrated, basal region of the current(s). Enhanced entrainment of ambient air, and autofluidization from upward fluxes of air from substrate interstices and plunging breakers across rugged, irregular topography further inflated the currents to the point that the overriding turbulent region strongly influenced transport and depositional mechanisms. Acceleration in combination with partial confinement in slot canyons and high surface roughness would also increase basal shear stress, further promoting shear and traction transport in the basal region of the current. Conditions along the steep flank resulted in supercritical flow, as recorded by regressive bedforms, which gradually transitioned to subcritical flow downstream as the concentrated basal region thickness increased as a function of decreasing slope and flow energy. We also find that (1) PDCs were erosive into the underlying granular substrate along high slopes (> 25°) where currents were

  9. Integrating field, textural, and geochemical monitoring to track eruption triggers and dynamics: a case study from Piton de la Fournaise (United States)

    Gurioli, Lucia; Di Muro, Andrea; Vlastélic, Ivan; Moune, Séverine; Thivet, Simon; Valer, Marina; Villeneuve, Nicolas; Boudoire, Guillaume; Peltier, Aline; Bachèlery, Patrick; Ferrazzini, Valérie; Métrich, Nicole; Benbakkar, Mhammed; Cluzel, Nicolas; Constantin, Christophe; Devidal, Jean-Luc; Fonquernie, Claire; Hénot, Jean-Marc


    The 2014 eruption at Piton de la Fournaise (PdF), La Réunion, which occurred after 41 months of quiescence, began with surprisingly little precursory activity and was one of the smallest so far observed at PdF in terms of duration (less than 2 days) and volume (less than 0.4 × 106 m3). The pyroclastic material was composed of golden basaltic pumice along with fluidal, spiny iridescent and spiny opaque basaltic scoria. Density analyses performed on 200 lapilli reveal that while the spiny opaque clasts are the densest (1600 kg m-3) and most crystalline (55 vol. %), the golden pumices are the least dense (400 kg m-3) and crystalline (8 vol. %). The connectivity data indicate that the fluidal and golden (Hawaiian-like) clasts have more isolated vesicles (up to 40 vol. %) than the spiny (Strombolian-like) clasts (0-5 vol. %). These textural variations are linked to primary pre-eruptive magma storage conditions. The golden and fluidal fragments track the hotter portion of the melt, in contrast to the spiny fragments and lava that mirror the cooler portion of the shallow reservoir. Exponential decay of the magma ascent and output rates through time revealed depressurization of the source during which a stratified storage system was progressively tapped. Increasing syn-eruptive degassing and melt-gas decoupling led to a decrease in the explosive intensity from early fountaining to Strombolian activity. The geochemical results confirm the absence of new input of hot magma into the 2014 reservoir and confirm the emission of a single shallow, differentiated magma source, possibly related to residual magma from the November 2009 eruption. Fast volatile exsolution and crystal-melt separation (second boiling) were triggered by deep pre-eruptive magma transfer and stress field change. Our study highlights the possibility that shallow magma pockets can be quickly reactivated by deep processes without mass or energy (heat) transfer and produce hazardous eruptions with only short

  10. Magma Chamber Model of Batur Caldera, Bali, Indonesia: Compositional Variation of Two Facies, Large-Volume Dacitic Ignimbrites

    Directory of Open Access Journals (Sweden)

    Igan S. Sutawidjaja


    Full Text Available DOI:10.17014/ijog.2.2.111-124Batur is one of the finest known calderas on Earth, and is the source of at least two major ignimbrite eruptions with a combined volume of some 84 km3 and 19 km3. These ignimbrites have a similar compositions, raising the question of whether they are geneticaly related. The Batur Ignimbrite-1 (BI-1 is crystal poor, containing rhyodacitic (68 - 70wt % SiO2, white to grey pumices and partly welded and unwelded. The overlying Batur Ignimbrite-2 (BI-2 is a homogeneous grey to black dacitic pumices (64 - 66 wt % SiO2, unwelded and densely welded (40 - 60% vesicularity, crystal and lithic rich. Phase equilibria indicate that the Batur magma equilibrated at temperatures of 1100 - 1300oC with melt water contents of 3 - 6 wt%. The post-eruptive Batur magma was cooler (<1100oC and it is melt more water rich (> 6 wt % H2O. A pressure of 20 kbar is infered from mineral barometry for the Batur magma chamber. Magmatic chamber model is one in which crystals and melt separate from a convecting Batur magma by density differences, resulting in a stratified magma chamber with a homogeneous central zone, a crystal-rich accumulation zone near the walls or base, and a buoyant, melt-rich zone near the top. This is consistent with the estimated magma temperatures and densities: the pre-eruptive BI-1 magma was hoter (1300oC and more volatile rich (6 wt % H2O with density 2.25 g/cm3 than the BI-2 magma (1200oC; 4 wt % H2O in density was higher (2.50 g/cm3. Batur melt characteristics and intensive parameters are consistent with a volatile oversaturation-driven eruption. However, the higher H2O content, high viscosity and low crystal content of the BI-1 magma imply an external eruption trigger.

  11. The VEI-7 Millennium eruption, Changbaishan-Tianchi volcano, China/DPRK: New field, petrological, and chemical constraints on stratigraphy, volcanology, and magma dynamics (United States)

    Pan, Bo; de Silva, Shanaka L.; Xu, Jiandong; Chen, Zhengquan; Miggins, Daniel P.; Wei, Haiquan


    Field relations, petrography, bulk and micro-scale chemistry reveal that the most recent history of hazardous Changbaishan-Tianchi volcano should be revised with important implications for volcanic hazard in NE Asia. Currently, the two most recent large eruptions are identified separately as a VEI 5 trachytic Baguamiao eruption (BGM) and the much heralded VEI 7, late 946 CE (Common Era) "Millennium" eruption (ME) of comendite. However, we find that the former is part of the latter based on the following evidence: (1) trachytic fallout of the BGM lies directly on the comendite tephra of the ME without any indication of depositional hiatus; (2) abundant mingled trachyte-comendite pumice in the tephra deposits; (3) similar chemistry of mingled pumice and its components to those in the BGM and ME products; (4) correlation of bimodal glass shard compositions in the distal 'B-Tm' ash from the Japan Sea with comendite and trachyte glass from the BGM and ME products. Based on the above evidence, we suggest that the great Millennium eruption of 946 CE should be revised finally to include the BGM trachyte as its final stage. Furthermore, deposits attributed to two other trachytic eruptions in 1668 and/or 1702 CE (also called Baguamiao by some authors), and 1903 CE referred to in historic accounts were also examined. Our field observations, petrography, bulk and micro-scale chemistry combined with previously published Ra/Th ages indicate that all these trachytes are either primary deposits of the ME or its reworked deposits. Thus our findings do not support two separate post-ME eruptions and require that volcanic hazard assessment at Changbaishan volcano include this new interpretation. Recently published geochronological data integrated with our new petrochemical and volcanological framework informs the magma dynamics leading to the ME. The ME comendite, derived from a parental trachyte similar to the BGM started accumulating at shallow levels around 12 ka to 8 ka. Around 4

  12. Complex proximal deposition during the Plinian eruptions of 1912 at Novarupta, Alaska (United States)

    Houghton, Bruce F.; Wilson, C.J.N.; Fierstein, J.; Hildreth, W.


    Proximal (Smokes ignimbrite. The proximal products include alternations and mixtures of both locally and regionally dispersed fall ejecta, and numerous thin complex deposits of pyroclastic density currents (PDCs) with no regional analogs. The locally dispersed component of the fall deposits forms sector-confined wedges of material whose thicknesses halve radially from and concentrically about the vent over distances of 100-300 m (cf. several kilometers for the medial-distal fall deposits). This locally dispersed fall material (and many of the associated PDC deposits) is rich in andesitic and banded pumices and richer in shallow-derived wall-rock lithics in comparison with the coeval medial fall units of almost entirely dacitic composition. There are no marked contrasts in grain size in the near-vent deposits, however, between locally and widely dispersed beds, and all samples of the proximal fall deposits plot as a simple continuation of grain size trends for medial-distal samples. Associated PDC deposits form a spectrum of facies from fines-poor, avalanched beds through thin-bedded, landscape-mantling beds to channelized lobes of pumice-block-rich ignimbrite. The origins of the Novarupta near-vent deposits are considered within a spectrum of four transport regimes: (1) sustained buoyant plume, (2) fountaining with co-current flow, (3) fountaining with counter-current flow, and (4) direct lateral ejection. The Novarupta deposits suggest a model where buoyant, stable, regime-1 plumes characterized most of episodes II and III, but were accompanied by transient and variable partitioning of clasts into the other three regimes. Only one short period of vent blockage and cessation of the Plinian plume occurred, separating episodes II and III, which was followed by a single PDC interpreted as an overpressured "blast" involving direct lateral ejection. In contrast, regimes 2 and 3 were reflected by spasmodic sedimentation from the margins of the jet and perhaps lower plume

  13. Minimal alterations on the enamel surface by micro-abrasion: in vitro roughness and wear assessments

    Directory of Open Access Journals (Sweden)

    Marcela Charantola Rodrigues


    Full Text Available Objective: To evaluate the in vitro changes on the enamel surface after a micro-abrasion treatment promoted by different products. Material and Methods: Fifty (50 fragments of bovine enamel (15 mm × 5 mm were randomly assigned to five groups (n=10 according to the product utilized: G1 (control= silicone polisher (TDV, G2= 37% phosphoric acid (3M/ESPE + pumice stone (SS White, G3= Micropol (DMC Equipment, G4= Opalustre (Ultradent and G5= Whiteness RM (FGM Dental Products. Roughness and wear were the responsible variables used to analyze these surfaces in four stages: baseline, 60 s and 120 s after the micro-abrasion and after polishing, using a Hommel Tester T1000 device. After the tests, a normal distribution of data was verified, with repeated ANOVA analyses (p≤0.05 which were used to compare each product in different stages. One-way ANOVA and Tukey tests were applied for individual comparisons between the products in each stage (p≤0.05. Results: Means and standard deviations of roughness and wear (µm after all the promoted stages were: G1=7.26(1.81/13.16(2.67, G2=2.02(0.62/37.44(3.33, G3=1.81(0.91/34.93(6.92, G4=1.92(0.29/38.42(0.65 and G5=1.98(0.53/33.45(2.66. At 60 seconds, all products tended to produce less surface roughness with a variable gradual decrease over time. After polishing, there were no statistically significant differences between the groups, except for G1. Independent of the product utilized, the enamel wear occurred after the micro-abrasion. Conclusions: In this in vitro study, enamel micro-abrasion presented itself as a conservative approach, regardless of the type of the paste compound utilized. These products promoted minor roughness alterations and minimal wear. The use of phosphoric acid and pumice stone showed similar results to commercial products for the micro-abrasion with regard to the surface roughness and wear.

  14. Proximal stratigraphy and event sequence of the c. 5600 cal. yr BP Whakatane rhyolite eruption episode from Haroharo volcano, Okataina Volcanic Centre, New Zealand

    International Nuclear Information System (INIS)

    Kobayashi, T.; Nairn, I.; Smith, V.; Shane, P.


    The c. 5600 cal. yr BP Whakatane eruption episode consisted of a sequence of intracaldera rhyolite eruptions from at least five vents spread over 11 km of the Haroharo linear vent zone within Okataina Volcanic Centre. Initial vent-opening eruptions from the Haroharo vent produced coarse lithic clast 'blast beds' and pyroclastic density currents surges). These were immediately followed by eruption of very mobile pumiceous pyroclastic surges from the Makatiti vent 6 km to the southwest. Major plinian eruptions from the Makatiti vent then dispersed Whakatane Tephra pumice fall deposits (bulk volume c. 6 km 3 ) across the northeastern North Island while smaller explosive eruptions produced pyroclastic flows and falls from the Haroharo-Rotokohu vents and at the Pararoa vent on the caldera rim 11 km northeast from Makatiti. The pyroclastic eruptions at all vents were followed by the extrusion of lava flows and domes; extruded lava volumes ranged from 0.03 km 3 for the Pararoa dome to 7.5 km 3 for the Makatiti-Tapahoro lava flows and domes. Minor variations in whole rock and glass chemistry show that the three main vent areas each tapped a slightly different high-silica rhyolite magma. About 10 km 3 of M-type magma was erupted from the Makatiti-Tapahoro vents; c. 1.3 km 3 of H-type magma from the Haroharo-Rotokohu vents, and 0.04 km 3 of P-type magma from the Pararoa vent. There are no significant weathering or erosional breaks within the Whakatane eruptive sequence, which suggests that all Whakatane eruptions occurred within a short time interval. However, extrusion of the Haroharo dome within the Makatiti pyroclastic eruption sequence suggests a duration of c. 2 yr for the main pyroclastic eruption phase. Emplacement of the following voluminous (7.5 km 3 ) lavas from the Makatiti-Tapahoro vents would have occurred over >10 yr at the c. 10-20 m 3 /s inferred extrusion rates. (author). 19 refs., 16 figs., 7 tabs

  15. Permeability of porour rhyolite (United States)

    Cashman, K.; Rust, A.; Wright, H.; Roberge, J.


    The development of permeability in bubble-bearing magmas determines the efficiency of volatile escape during their ascent through volcanic conduits, which, in turn, controls their explosive potential. As permeability requires bubble connectivity, relationships between permeability and porosity in silicic magmas must be controlled by the formation, growth, deformation and coalescence of their constituent bubbles. Although permeability data on porous volcanic pyroclasts are limited, the database can be greatly extended by including data for ceramic and metallic foams1. Several studies indicate that a single number does not adequately describe the permeability of a foam because inertial effects, which predominate at high flow rates, cause deviations from Darcy's law. These studies suggest that permeability is best modeled using the Forschheimer equation to determine both the Darcy permeability (k1) and the non-Darcian (k2) permeability. Importantly, at the high porosities of ceramic foams (75-95%), both k1 and k2 are strongly dependent on pore size and geometry, suggesting that measurement of these parameters provides important information on foam structure. We determined both the connected porosity (by He-pycnometry) and the permeability (k1 and k2) of rhyolitic samples having a wide range in porosity (22-85%) and vesicle textures. In general, these data support previous observations of a power law relationship between connected porosity and Darcy permeability2. In detail, variations in k1 increase at higher porosities. Similarly, k2 generally increases in both mean and standard deviation with increasing porosity. Measurements made on three mutually perpendicular cores from individual pumice clasts suggest that some of the variability can be explained by anisotropy in the vesicle structure. By comparison with ceramic foams, we suggest that the remaining variability results from differences either in average vesicle size or, more likely, in the size of apertures

  16. Long-range hazard assessment of volcanic ash dispersal for a Plinian eruptive scenario at Popocatépetl volcano (Mexico): implications for civil aviation safety (United States)

    Bonasia, Rosanna; Scaini, Chiara; Capra, Lucia; Nathenson, Manuel; Siebe, Claus; Arana-Salinas, Lilia; Folch, Arnau


    Popocatépetl is one of Mexico's most active volcanoes threatening a densely populated area that includes Mexico City with more than 20 million inhabitants. The destructive potential of this volcano is demonstrated by its Late Pleistocene-Holocene eruptive activity, which has been characterized by recurrent Plinian eruptions of large magnitude, the last two of which destroyed human settlements in pre-Hispanic times. Popocatépetl's reawakening in 1994 produced a crisis that culminated with the evacuation of two villages on the northeastern flank of the volcano. Shortly after, a monitoring system and a civil protection contingency plan based on a hazard zone map were implemented. The current volcanic hazards map considers the potential occurrence of different volcanic phenomena, including pyroclastic density currents and lahars. However, no quantitative assessment of the tephra hazard, especially related to atmospheric dispersal, has been performed. The presence of airborne volcanic ash at low and jet-cruise atmospheric levels compromises the safety of aircraft operations and forces re-routing of aircraft to prevent encounters with volcanic ash clouds. Given the high number of important airports in the surroundings of Popocatépetl volcano and considering the potential threat posed to civil aviation in Mexico and adjacent regions in case of a Plinian eruption, a hazard assessment for tephra dispersal is required. In this work, we present the first probabilistic tephra dispersal hazard assessment for Popocatépetl volcano. We compute probabilistic hazard maps for critical thresholds of airborne ash concentrations at different flight levels, corresponding to the situation defined in Europe during 2010, and still under discussion. Tephra dispersal mode is performed using the FALL3D numerical model. Probabilistic hazard maps are built for a Plinian eruptive scenario defined on the basis of geological field data for the "Ochre Pumice" Plinian eruption (4965 14C yr BP

  17. Geology of proximal, small-volume trachyte-trachyandesite pyroclastic flows and associated surge deposits, Roccamonfina volcano, Italy (United States)

    Giannetti, Bernardino


    This paper describes the 232 ka B.P. MTTT trachyte-trachyandesite pyroclastic succession of Roccamonfina volcano. This small-volume, proximal sequence crops out along Mulino di Sotto, Paratone, and Pisciariello ravines in the southwest sector of the central caldera, and covers a minimum extent of 3.5 km 2 area. It is made up of seven pyroclastic flows and pyroclastic surge units consisting of trachytic ash matrix containing juvenile trachyandesitic scoria and dense lava fragments, pumice clasts of uncertain trachyandesite, and a foreign trachyandesitic lithic facies. Two stratigraphic markers allow correlation of the units. No paleosoils and Plinian fallout have been observed at the base and within the succession. Some lateral grading of scoria and lithic clasts suggests that MTTT derived from three distinct source vents. The sequence consists of a basal ash flow passing laterally to laminated surge deposits (Unit A). This is overlain by a reversely graded scoria and pumice lapilli flow (Unit B) which is in turn overlain by a thinly cross-stratified scoria lapilli surge (Unit C). Unit C is capped by a prominent ash-and-scoria flow (Unit D). A ground layer (Marker MK1) divides Unit D from a massive ignimbrite which grades upcurrent to sand-wave surge deposits (Unit E). Another ground layer (Marker MK2) separates Unit E from Unit F. This unit consists of a basal ignimbrite passing laterally to bedded surge deposits with convolute structures (subunit Fl), and grading upcurrent to a subhorizontally plane-laminated ash cloud (subunit F2) containing near the top a layer of millimetric lithic clasts embedded in fine ash. The succession is closed by the pyroclastic flow Unit G. Surge Unit C can be interpreted in terms of vertical gradients in turbulence, particle concentration, and velocity during flowage, whereas the bedded surge parts present in the massive deposits of Units A and E-F1 can be related to abrupt changes of velocity down the steep slopes of ravines. Reverse


    Directory of Open Access Journals (Sweden)

    Catur Wasonowati


    Full Text Available Tomato is vegetable that has high economic and nutritional value. Hydroponics is the cultivation of plants without soil but using rice husk charcoal, rockwool, pumice, sand, gravel, perlite water and air media. This research aims to study the effect of nutrients and polybag size on growth and yield of hydroponic tomatoes. The experiment was conducted in Kassa House of Agroekoteknologi Departement Faculty of Agriculture Trunojoyo University. Fertilizers used were Hidrogroup and Greentonik while polybag size are 30x30 cm, 30x40 cm and 40x40 cm. The design of this study using Complete Randomized Design (CRD with 3 replications. The result showed that this research affect to the vegetative phase. No interaction between type of nutrition and polybag size on plant height, leaf number, stem diameter, number of flowers, flowering time of tomato. Type of nutrition significantly affect plant height, leaf number, stem diameter, flower number and wet and dry weight of stems and leaves, whereas the size of polybags significantly affects in the number of leaves, wet and dry weight of stems and leaves of tomato.

  19. Recent ground subsidence at Crown Road, Tauhara and its probable causes

    International Nuclear Information System (INIS)

    Bromley, Chris J.; Manville, Vern R.; Rosenberg, Michael D.; Currie, Steve


    A localised ground subsidence anomaly at Crown Road, Taupo, within the Tauhara field of the Wairakei-Tauhara geothermal system, has been subjected to intense scrutiny because of its relatively recent onset and proximity to urban areas. Over a period of 20 years a maximum of 0.63 m of subsidence has accumulated. Uncertainties regarding its cause remain, but the evidence now strongly favours a relatively shallow (about 50 m depth) origin, compared with other geothermal subsidence bowls at Wairakei, Tauhara and Ohaaki. Declining water levels in a shallow boiling aquifer are considered to be the principal driving mechanism at Crown Road. The source of the subsidence is an anomalously compressible formation of intensely altered ignimbrite found at the base of a buried hydrothermal eruption deposit. This formation is dominated by soft kaolinite and smectite-illite clays of high plasticity and water content, resulting from alteration of highly vesiculated pumice, and is capped by a thin hardpan of silicified pyroclastic material, characterised by vuggy macro-porosity, at about 33 m depth. During initiation of the subsidence event, this hardpan may have failed in shear mode around the edges of a buried eruption crater, allowing the overburden to fully load the underlying compressible clays. (author)

  20. Thermal modeling of core sampling in flammable gas waste tanks. Part 2: Rotary-mode sampling

    International Nuclear Information System (INIS)

    Unal, C.; Poston, D.; Pasamehmetoglu, K.O.; Witwer, K.S.


    The radioactive waste stored in underground storage tanks at Hanford site includes mixtures of sodium nitrate and sodium nitrite with organic compounds. The waste can produce undesired violent exothermic reactions when heated locally during the rotary-mode sampling. Experiments are performed varying the downward force at a maximum rotational speed of 55 rpm and minimum nitrogen purge flow of 30 scfm. The rotary drill bit teeth-face temperatures are measured. The waste is simulated with a low thermal conductivity hard material, pumice blocks. A torque meter is used to determine the energy provided to the drill string. The exhaust air-chip temperature as well as drill string and drill bit temperatures and other key operating parameters were recorded. A two-dimensional thermal model is developed. The safe operating conditions were determined for normal operating conditions. A downward force of 750 at 55 rpm and 30 scfm nitrogen purge flow was found to yield acceptable substrate temperatures. The model predicted experimental results reasonably well. Therefore, it could be used to simulate abnormal conditions to develop procedures for safe operations

  1. Material and elastic properties of Al-tobermorite in ancient roman seawater concrete

    KAUST Repository

    Jackson, Marie D.


    The material characteristics and elastic properties of aluminum-substituted 11 Å tobermorite in the relict lime clasts of 2000-year-old Roman seawater harbor concrete are described with TG-DSC and 29Si MAS NMR studies, along with nanoscale tomography, X-ray microdiffraction, and high-pressure X-ray diffraction synchrotron radiation applications. The crystals have aluminum substitution for silicon in tetrahedral bridging and branching sites and 11.49(3) Å interlayer (002) spacing. With prolonged heating to 350°C, the crystals exhibit normal behavior. The experimentally measured isothermal bulk modulus at zero pressure, K0, 55 ±5 GPa, is less than ab initio and molecular dynamics models for ideal tobermorite with a double-silicate chain structure. Even so, K0, is substantially higher than calcium-aluminum-silicate-hydrate binder (C-A-S-H) in slag concrete. Based on nanoscale tomographic study, the crystal clusters form a well connected solid, despite having about 52% porosity. In the pumiceous cementitious matrix, Al-tobermorite with 11.27 Å interlayer spacing is locally associated with phillipsite, similar to geologic occurrences in basaltic tephra. The ancient concretes provide a sustainable prototype for producing Al-tobermorite in high-performance concretes with natural volcanic pozzolans. © 2013 The American Ceramic Society.

  2. Geological Consideration for the Site Selection of Radioactive Waste at the PPTN Serpong Area

    International Nuclear Information System (INIS)



    Geological consideration is a main aspect in the exploration or selection of site for radioactive waste repository, because, really that repository site must be surrounded by geological system (geosphere). The objective of the site selection is to obtain a site which geologically capable to prevent the escape of waste pollution from repository to biosphere. Beside that the site must be free from geological processes which harmfull to longterm stability of the site. Descriptive analysis method was applied in this research and combined with evaluation by scoring methods. From the analysis result could be identified that PPTN Serpong morphologically consist of undulatory plains (elevation 80-100 m above msl), the lithology are alluvial deposits. Quarternary tuffs, pumiceous tuffs, clayey tuffs. sandy tuffs and limestone. The geological structure was supposed a horst and graben which buried more than 15 m since Pleistocene. Hydrological condition are moderately run-off, and the distance to the river is about 160 m. The depth of groundwater is 8.3 m, with parallel drainage system. Geological resources found in the site are land and groundwater. The most potential of geological hazard is supposed a rock mass movement. By the land evaluation could be concluded that PPTN Serpong area have moderate suitability for NSD site. (author)

  3. Data Qualification and Data Summary Report: Intact Rock Properties Data on Poisson's Ratio and Young's Modulus

    International Nuclear Information System (INIS)

    Cikanek, E.M.; Safley, L.E.; Grant, T.A.


    This report reviews all potentially available Yucca Mountain Project (YMP) data in the Technical Data Management System and compiles all relevant qualified data, including data qualified by this report, on elastic properties, Poisson's ratio and Young's modulus, into a single summary Data Tracking Number (DTN) MO0304DQRIRPPR.002. Since DTN MO0304DQRIRPPR.002 was compiled from both qualified and unqualified sources, this report qualifies the DTN in accordance with AP-SIII.2Q. This report also summarizes the individual test results in MO0304DQRIRPPR.002 and provides summary values using descriptive statistics for Poisson's ratio and Young's modulus in a Reference Information Base Data Item. This report found that test conditions such as temperature, saturation, and sample size could influence test results. The largest influence, however, is the lithologic variation within the tuffs themselves. Even though the summary DTN divided the results by lithostratigrahic units within each formation, there was still substantial variation in elastic properties within individual units. This variation was attributed primarily to the presence or absence of lithophysae, fractures, alteration, pumice fragments, and other lithic clasts within the test specimens as well as changes in porosity within the units. As a secondary cause, substantial variations can also be attributed to test conditions such as the type of test (static or dynamic), size of the test specimen, degree of saturation, temperature, and strain rate conditions. This variation is characteristic of the tuffs and the testing methods, and should be considered when using the data summarized in this report

  4. Mantle wedge infiltrated with saline fluids from dehydration and decarbonation of subducting slab. (United States)

    Kawamoto, Tatsuhiko; Yoshikawa, Masako; Kumagai, Yoshitaka; Mirabueno, Ma Hannah T; Okuno, Mitsuru; Kobayashi, Tetsuo


    Slab-derived fluids play an important role in heat and material transfer in subduction zones. Dehydration and decarbonation reactions of minerals in the subducting slab have been investigated using phase equilibria and modeling of fluid flow. Nevertheless, direct observations of the fluid chemistry and pressure-temperature conditions of fluids are few. This report describes CO2-bearing saline fluid inclusions in spinel-harzburgite xenoliths collected from the 1991 Pinatubo pumice deposits. The fluid inclusions are filled with saline solutions with 5.1 ± 1.0% (wt) NaCl-equivalent magnesite crystals, CO2-bearing vapor bubbles, and a talc and/or chrysotile layer on the walls. The xenoliths contain tremolite amphibole, which is stable in temperatures lower than 830 °C at the uppermost mantle. The Pinatubo volcano is located at the volcanic front of the Luzon arc associated with subduction of warm oceanic plate. The present observation suggests hydration of forearc mantle and the uppermost mantle by slab-derived CO2-bearing saline fluids. Dehydration and decarbonation take place, and seawater-like saline fluids migrate from the subducting slab to the mantle wedge. The presence of saline fluids is important because they can dissolve more metals than pure H2O and affect the chemical evolution of the mantle wedge.

  5. Durability of heavyweight concrete containing barite

    International Nuclear Information System (INIS)

    Binici, Hanifi


    The supplementary waste barite aggregates deposit in Osmaniye, southern Turkey, has been estimated at around 500 000 000 tons based on 2007 records. The aim of the present study is to investigate the durability of concrete incorporating waste barite as coarse and river sand (RS), granule blast furnace slag (GBFS), granule basaltic pumice (GBP) and ≤ 4 mm granule barite (B) as fine aggregates. The properties of the fresh concrete determined included the air content, slump, slump loss and setting time. They also included the compressive strength, flexural and splitting tensile strengths and Young's modulus of elasticity, resistance to abrasion and sulphate resistance of hardened concrete. Besides these, control mortars were prepared with crushed limestone aggregates. The influence of waste barite as coarse aggregates and RS, GBFS, GBP and B as fine aggregates on the durability of the concretes was evaluated. The mass attenuation coefficients were calculated at photon energies of 1 keV to 100 GeV using XCOM and the obtained results were compared with the measurements at 0.66 and 1.25 MeV. The results showed the possibility of using these waste barite aggregates in the production of heavy concretes. In several cases, some of these properties have been improved. Durability of the concrete made with these waste aggregates was improved. Thus, these materials should be preferably used as aggregates in heavyweight concrete production. (orig.)

  6. Textural evidence for high-grade ignimbrites formed by low-explosivity eruptions, Paraná Magmatic Province, southern Brazil (United States)

    Luchetti, Ana Carolina F.; Gravley, Darren M.; Gualda, Guilherme A. R.; Nardy, Antonio J. R.


    The Paraná-Etendeka Province is a Lower Cretaceous huge bimodal tholeiitic volcanic province (1 million·km3) that predated the Gondwana breakup. Its silicic portion makes up a total volume of at least 20,000 km3 and in southern Brazil it comprises the Chapecó porphyritic high-Ti trachydacites-dacites and the Palmas microporphyritic-aphyric low-Ti dacites-rhyolites. The widespread silicic sheets are debated in the literature because they bear similarities between lavas and high grade ignimbrites. Here we provide new observations and interpretations for flow units with large, dark, and vesicle-poor lens-shaped blobs surrounded by a light-colored matrix. The textural features (macro- to micro-scale) of these blobs are different from typical pumice and/or fiamme and support a low explosivity pyroclastic origin, possibly low-column fountain eruptions with discharge rates high enough to produce laterally extensive high-grade ignimbrites. Such an interpretation, combined with a conspicuous absence of lithic fragments in the deposits, is aligned with a lack of identified calderas in the Paraná-Etendeka Province. Maximum timescales of crystallization associated with the juvenile blobs and estimated from CSD slopes are on the order of millennia for phenocryst populations and on the order of decades for microphenocryst populations.


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    Full Text Available A number of geopolymer cement mixes were designed and produced by alkali-activation of a pumice-type natural pozzolan. Effects of blast-furnace slag on basic engineering properties of the mixes were studied. Different engineering properties of the mixes such as setting times and 28-day compressive strength were studied at different amounts of blast-furnace slag, sodium oxide content, and water-to-cement ratio. The mix comprising of 5 wt.% blast-furnace slag and 8 wt.% Na2O with a water-to-dry binder ratio of 0.30 exhibits the highest 28-day compressive strength, i.e. 36 MPa. Mixes containing 5 wt.% of ground granulated blast furnace slag showed the least efflorescence or best soundness. Laboratory techniques of X-ray diffractometry (XRD, fourier transform infrared spectroscopy (FTIR, and scanning electron microscopy (SEM were utilized for characterizing a number of mixes and studying their molecular and micro-structure. Investigations done by scanning electron microscopy confirm that smaller blast-furnace slag particles react totally while the larger ones react partially with alkaline activators and contribute to the formation of a composite microstructure.

  8. Plaque, gingival bleeding and calculus formation after supragingival scaling with and without polishing: a randomised clinical trial. (United States)

    Zanatta, Fabricio Batistin; Pinto, Tatiana Militz; Kantorski, Karla Zanini; Rösing, Cassiano Kuchenbecker


    The aim of this study was to compare the effect of polishing after scaling and root planing on supragingival plaque, calculus formation, and gingival bleeding. The study was designed as a split-mouth randomised clinical trial. Seventy-six patients were submitted to supragingival scaling on the six mandibular anterior teeth with manual curettes until a smooth surface was achieved. Subsequently, quadrants were randomly selected to be polished (test) or not (control) with a rubber cup and pumice. One, two and three weeks following treatment, a blinded examiner evaluated the visible plaque index, gingival bleeding index and the presence of supragingival calculus on the lingual tooth surfaces. The results showed that unpolished surfaces exhibited higher mean percentages of visible plaque in the third week. No statistically significant differences were observed between unpolished and polished sites related to gingival bleeding. Calculus formation was higher on unpolished sites than on polished sites at 2 and 3 weeks. Dental polishing after supragingival scaling contributed to reducing plaque and calculus formation. Polishing exerts an inhibitory effect on plaque and calculus formation.

  9. Age of the earliest known hominids in Java, Indonesia. (United States)

    Swisher, C C; Curtis, G H; Jacob, T; Getty, A G; Suprijo, A; Widiasmoro


    40Ar/39Ar laser-incremental heating of hornblende separated from pumice recovered at two hominid sites in Java, Indonesia, has yielded well-defined plateaus with weighted mean ages of 1.81 +/- 0.04 and 1.66 +/- 0.04 million years ago (Ma). The hominid fossils, a juvenile calvaria of Pithecanthropus and a partial face and cranial fragments of Meganthropus, commonly considered part of the Asian Homo erectus hypodigm, are at least 0.6 million years older than fossils referred to as Homo erectus (OH-9) from Olduvai Gorge, Tanzania, and comparable in age with the oldest Koobi Fora Homo cf. erectus (Homo ergaster) in Kenya. These ages lend further credence to the view that Homo erectus may have evolved outside of Africa. If the ancestor of Homo erectus ventured out of Africa before 1.8 Ma, the dispersal would have predated the advent of the Acheulean culture at 1.4 Ma, possibly explaining the absence of these characteristic stone cleavers and hand axes in East Asia.

  10. Soil and Crop management: Lessons from the laboratory biosphere 2002-2004 (United States)

    Silverstone, S.; Nelson, M.; Alling, A.; Allen, J.

    During the years 2002 and 2003, three closed system experiments were carried out in the "Laboratory Biosphere" facility located in Santa Fe, New Mexico. The program involved experimentation with "Hoyt" Soy Beans, USU Apogee Wheat and TU-82-155 sweet potato using a 5.37 m2 soil planting bed which was 30 cm deep. The soil texture, 40% clay, 31% sand and 28% silt (a clay loam), was collected from an organic farm in New Mexico to avoid chemical residues. Soil management practices involved minimal tillage, mulching and returning crop residues to the soil after each experiment. Between experiment #2 and #3, the top 15 cm of the soil was amended using a mix of peat moss, green sand, humates and pumice to improve soil texture, lower soil pH and increase nutrient availability. Soil analyses for all three experiments are presented to show how the soils have changed with time and how the changes relate to crop selection and rotation, soil selection and management, water management and pest control. The experience and information gained from these experiments are being applied to the future design of the Mars On Earth facility.

  11. Fluctuations of the Vestfonna ice margin at Brageneset, Nordaustlandet, Svalbard, after the last glacial maximum

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    Donner, J.J.


    Full Text Available Four radiocarbon datings of shells of Mya truncata and Saxicava arctica from the till of the end-moraine of the advance of Vestfonna against Brageneset, Nordaustlandet, between AD 1861 and 1899, gave ages between 8300 BP and 8700 BP. These are from the time when the ice margin had retreated from Brageneset after the last glaciation. An additional age of 7900 BP obtained for Astarteelliptica, also from the end-moraine, shows that the shells in the till represent a mixed death assemblage, as also shown by the composition of the molluscan fauna in general. By comparing the altitudes of the two pumice levels with their altitudes in other areas of Svalbard a curve for the relative uplift of Brageneset could be constructed. According to this curve the highest point of Brageneset at 46.5 m emerged at about 9200 BP, which gives a minimum age for the general deglaciation, an age in agreement with dates obtained from other parts of Nordaustlandet.

  12. Evidence for water influx from a caldera lake during the explosive hydromagmatic eruption of 1790, Kilauea volcano, Hawaii (United States)

    Mastin, L.G.


    In 1790 a major hydromagmatic eruption at the summit of Kilauea volcano, Hawaii, deposited up to 10 m of pyroclastic fall and surge deposits and killed several dozen Hawaiian natives who were crossing the island. Previous studies have hypothesized that the explosivity of this eruption was due to the influx of groundwater into the conduit and mixing of the groundwater with ascending magma. This study proposes that surface water, not groundwater, was the agent responsible for the explosiveness of the eruption. That is, a lake or pond may have existed in the caldera in 1790 and explosions may have taken place when magma ascended into the lake from below. That assertion is based on two lines of evidence: (1) high vesicularity (averaging 73% of more than 3000 lapilli) and high vesicle number density (105-107 cm-3 melt) of pumice clasts suggest that some phases of the eruption involved vigorous, sustained magma ascent; and (2) numerical calculations suggest that under most circumstances, hydrostatic pressure would not be sufficient to drive water into the eruptive conduit during vigorous magma ascent unless the water table were above the ground surface. These results are supported by historical data on the rate of infilling of the caldera floor during the early 1800s. When extrapolated back to 1790, they suggest that the caldera floor was below the water table.

  13. Tsunamis Observed on the Coasts of Greece from Antiquity to Present Time

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    Full Text Available In comparison with the great number of disastrous earthquakes
    which have occurred from antiquity to the present time in Greece, large
    tsunamis are very rare on the coasts of Greece. A really great tsunami
    may have started in the Aegean Sea after the tremendous explosion of
    Santorin volcano, which occurred 3370 ± 100 years ago (13. After the
    deposit of a layer of pumice 20-30 m thick and the emptying of the
    volcanic focus, the roof of the cavern thus formed collapsed. The
    centrai part, consisting of an area of 83 sq km, of the former island
    Stronghyb tlius became a gigantic caldera 300-400 m deep.
    Tliere is no evidence indicating whether the cobapse took place
    graduaby or ab at once. In the second case a huge tsunami should have
    started greater by far than that generated by the explosion of Krakatoa,
    on August 27, 1883. At that time depths of 200-300 m were formed by
    the sinking (24 of 2/3 of the former island of an area of 33 1/2 sq km.
    Thus the cavity formed by the explosion of Santorin is about 4 times
    greater than that of the Krakatoa.

  14. Abrasion of 6 dentifrices measured by vertical scanning interference microscopy. (United States)

    Pascaretti-Grizon, Florence; Mabilleau, Guillaume; Chappard, Daniel


    The abrasion of dentifrices is well recognized to eliminate the dental plaque. The aims of this study were to characterize the abrasive powders of 6 dentifrices (3 toothpastes and 3 toothpowders) and to measure the abrasion on a test surface by Vertical Scanning Interference microscopy (VSI). Bright field and polarization microscopy were used to identify the abrasive particles on the crude dentifrices and after prolonged washes. Scanning electron microscopy and microanalysis characterized the shape and nature of the particles. Standardized and polished blocks of poly(methylmethacrylate) were brushed with a commercial electric toothbrush with the dentifrices. VSI quantified the mean roughness (Ra) and illustrated in 3D the abraded areas. Toothpastes induced a limited abrasion. Toothpowders induced a significantly higher roughness linked to the size of the abrasive particles. One powder (Gencix® produced a high abrasion when used with a standard testing weight. However, the powder is based on pumice particles covered by a plant homogenate that readily dissolves in water. When used in the same volume, or after dispersion in water, Ra was markedly reduced. Light and electron microscopy characterize the abrasive particles and VSI is a new tool allowing the analysis of large surface of abraded materials.

  15. Effect of temporary cements on the microtensile bond strength of self-etching and self-adhesive resin cement. (United States)

    Carvalho, Edilausson Moreno; Carvalho, Ceci Nunes; Loguercio, Alessandro Dourado; Lima, Darlon Martins; Bauer, José


    The aim of this study was to evaluate the microtensile bond strength (µTBS) of self-etching and self-adhesive resin cement systems to dentin affected by the presence of remnants of either eugenol-containing or eugenol-free temporary cements. Thirty extracted teeth were obtained and a flat dentin surface was exposed on each tooth. Acrylic blocks were fabricated and cemented either with one of two temporary cements, one zinc oxide eugenol (ZOE) and one eugenol free (ZOE-free), or without cement (control). After cementation, specimens were stored in water at 37°C for 1 week. The restorations and remnants of temporary cements were removed and dentin surfaces were cleaned with pumice. Resin composite blocks were cemented to the bonded dentin surfaces with one of two resin cements, either self-etching (Panavia F 2.0) or self-adhesive (RelyX U-100). After 24 h, the specimens were sectioned to obtain beams for submission to µTBS. The fracture mode was evaluated under a stereoscopic loupe and a scanning electron microscope (SEM). Data from µTBS were submitted to two-way repeated-measure ANOVA and the Tukey test (alpha = 0.05). The cross-product interaction was statistically significant (p cements reduced the bond strength to Panavia self-etching resin cements only (p cements did not interfere in the bond strength to dentin of self-adhesive resin cements.

  16. Effects of a non-rinse conditioner on the enamel of primary teeth

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    Fava Marcelo


    Full Text Available The aim of this in vitro study was to evaluate by scanning electron microscopy the morphological aspects of the enamel of primary teeth after etching with 36% phosphoric acid or a non-rinse conditioner. Ten naturally exfoliated anterior primary teeth were selected. The samples were subjected to prophylaxis with pumice paste and water using a low-speed hand piece. Etching was done on the buccal surface. Specimens were divided into 2 groups: G1 (n=10: etching with 36% phosphoric acid gel - Conditioner 36 (Dentsply for 20 s, followed by water rinse for 15 s; G2 (n=10: etching with NRC - Non Rinse Conditioner (Dentsply for 20 s, followed by air drying for 15 s. The samples were dehydrated, mounted on metal stubs, coated with gold and observed with Jeol JSM-6100 scanning electron microscope. Electron-micrographic analysis showed that both etching agents were effective for etching the enamel of primary teeth causing the formation of microporosities on the enamel surface, although the etching pattern was more effective with the use of 36% phosphoric acid gel.

  17. Glass produced by underground nuclear explosions

    International Nuclear Information System (INIS)

    Schwartz, L.; Piwinskii, A.; Ryerson, F.; Tewes, H.; Beiriger, W.


    Detonation of an underground nuclear explosive produces a strong shock wave which propagates spherically outward, vaporizing the explosive and nearby rock and melting, the surrounding rock. The vaporized material expands adiabatically, forming a cavity. As the energy is dissipated during the cavity formation process, the explosive and rock debris condense and mix with the melted rock. The melt flows to the bottom of the cavity where it is quenched by fractured rock fragments falling from above as the cavity collapses. Measurements indicate that about 740 tonnes of rock and/or soil are melted for every kiloton (10 12 calories) of explosive energy, or about 25% of the explosive energy goes to melting rock. The resulting glass composition reflects the composition of the unaltered rock with explosive debris. The appearance ranges from white pumice to dense, dark lava. The bulk composition and color vary with the amount of explosive iron incorporated into the glass. The refractory explosion products are mixed with the solidified melt, although the degree of mixing is variable. Electron microprobe studies of glasses produced by Rainier in welded tuff have produced the following results: glasses are dehydrated relative to the host media, glasses are extremely heterogeneous on a 20 μm scale, a ubiquitous feature is the presence of dark marble-cake regions in the glass, which were locally enriched in iron and may be related to the debris, optically amorphous regions provide evidence of shock melting, only limited major element redistribution and homogenization occur within the cavity

  18. 14C age of the ash found in the peat bed of upland dog, Nakagawa-Gun, Hokkaido

    International Nuclear Information System (INIS)

    Igarashi, Yaeko; Kondo, Tsutomu; Fujiwara, Koichiro.


    The determination of the 14 C age of volcanic ash forming thin layer, which was found in a peat bed, was carried out. The samples were collected from the peat bed which distributes on the flat top of upland about 450m above sea level. The moor spread in the experimental plantation of the agricultural department of Hokkaido University. The thin layer of volcanic ash was found 20 cm deep in the peat bed and with about 1-3 cm thickness. The determination of 14 C age was made on the peat directly beneath the volcanic ash layer, along with the mineralogical studies. The obtained 14 C age was 480 480 +- 100 Y.B.P. (A.D. 1470), and this is presumed to be the age of eruption of the volcanic ash. The color of the ash was greenish yellow or orange in wet state, and grayish white in dry state. The volcanic ash was fine grained pumiceous, and round or nearly round grains predominate. By macroscopic observation, the grains were found to be composed of fibrous volcanic glass. The volcanic ash was well sorted, and the central grain size was 0.11 mm. Heavy liquid method was applied for the determination of heavy minerals. The weight percentage of heavy minerals was 1.59, and the characteristic of this ash was the entire absence of amphibole. Further investigation is necessary for clarifying the distribution of volcanic ash and the source of eruption. (Ishimitsu, A.)

  19. The effect of traditional architecture elements on architectureal and planning forming develop and raise the efficency of using the traditional energy (study case Crater/Aden, Yemen)

    International Nuclear Information System (INIS)

    Ghanem, Wadee Ahmed


    This paper discuss the role of architecture in Center city-Aden, Republic of Yemen which has a historical traditional architecture which is a unique sample with many elements that make the building of this city as an effective helper in keeping the sources traditional energy. This architecture could be meritoriously described as courtyards, high ceiling for suitable air circling are used as well as the main building material used are local and environmental such as stones, wood and lime stone (Pumic). The research aim at studying and analyzing the planning forming and architectural specification of this city through studying some examples of its buildings to recognize the traditional building role in saving the traditional energy by studying the building material, ventilation system, orientation and opening, for using these elements to raise the efficiency of using the resources of traditional sources. The research is abbreviated to several results such as: 1. Urbanization planning side: a. Elements of urban planning represented in the mass and opening their environmental role. b. Method of forming the urban planning. c. Series in arrangement of elements of urban planning. 2. Architectural side: a. Ratio between solid and void. b. opening shapes. c. internal courtyards. d. Unique architectural elements (Mashrabiyas (Oriels), sky lines, opening covering...etc). e. Building material used . f. building construction methods. g. Kind of walls.(Author)

  20. Lithostratigraphy of the Calico Hills Formation and Prow Pass Tuff (Crater Flat Group) at Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    Moyer, T.C.; Geslin, J.K.


    Lithostratigraphic relations within the Calico Hills Formation and Prow Pass Tuff (Crater Flat Group) were reconstructed from analysis of core samples and observation of outcrop exposures. The Calico Hills Formation is composed of five nonwelded pyroclastic units (each formed of one or more pyroclastic-flow deposits) that overlie an interval of bedded tuff and a basal volcaniclastic sandstone unit. The Prow Pass Tuff is divided into four pyroclastic units and an underlying interval of bedded tuff. The pyroclastic units of the Prow Pass Tuff are distinguished by the sizes and amounts of their pumice and lithic clasts and their degree of welding. Pyroclastic units of the Prow Pass Tuff are distinguished from those of the Calico Hills Formation by their phenocryst assemblage, chemical composition, and ubiquitous siltstone lithic clasts. Downhole resistivity tends to mirror the content of authigenic minerals, primarily zeolites, in both for-mations and may be useful for recognizing the vitric-zeolite boundary in the study area. Maps of zeolite distribution illustrate that the bedded tuff and basal sandstone units of the Calico Hills Formation are altered over a wider area than the pyroclastic units of both the Calico Hills Formation and the upper Prow Pass Tuff

  1. 14C ages for the ejecta from Kutcharo and Mashu calderas, eastern Hokkaido, Japan

    International Nuclear Information System (INIS)

    Yamamoto, Takahiro; Ito, Jun-ichi; Nakagawa, Mitsuhiro; Hasegawa, Takeshi; Kishimoto, Hiroshi


    Eruption ages of the ejecta from Kutcharo and Mashu calderas were systematically determined by 14 C dating. 16 charred samples were newly obtained from the Mashu and Nakashumbetsu Tephra Formations around the calderas and dated by AMS and β-counting methods. Examined units are Ma-d, Ma-e, Ma-f, Ma-j, Ma-k, Ma-l and Ml-a in the Mashu ejecta and 6 Nakashumbetsu tephra layers including Kutcharo Pumice Flow Deposit I (KpI), which is the youngest caldera-forming product from Kutcharo caldera. Results of the 14 C dating range from 3,660 ±40 yBP to 36,080±1,300 yBP, and are consistent with the tephrostratigraphy. Calendar age for KpI was newly calculated at almost 40 ka and this age shows there was about 70,000 years recurrence interval between KpI and KpIV caldera-forming eruptions. Mashu caldera has appeared on the eastern part of Kutcharo caldera immediately after the KpI eruption, and calendar age for its main caldera-forming eruption were determined at ca. BC 5,600. (author)

  2. [Combination of phosphorus solubilizing and mobilizing fungi with phosphate rocks and volcanic materials to promote plant growth of lettuce (Lactuca sativa L.)]. (United States)

    Velázquez, María S; Cabello, Marta N; Elíades, Lorena A; Russo, María L; Allegrucci, Natalia; Schalamuk, Santiago

    Arbuscular mycorrhizal fungi (AMF) increase the uptake of soluble phosphates, while phosphorus solubilizing fungi (S) promote solubilization of insoluble phosphates complexes, favoring plant nutrition. Another alternative to maintaining crop productivity is to combine minerals and rocks that provide nutrients and other desirable properties. The aim of this work was to combine AMF and S with pyroclastic materials (ashes and pumices) from Puyehue volcano and phosphate rocks (PR) from Rio Chico Group (Chubut) - to formulate a substrate for the production of potted Lactuca sativa. A mixture of Terrafertil®:ashes was used as substrate. Penicillium thomii was the solubilizing fungus and Rhizophagus intraradices spores (AMF) was the P mobilizer (AEGIS® Irriga). The treatments were: 1) Substrate; 2) Substrate+AMF; 3) Substrate+S; 4) Substrate+AMF+S; 5) Substrate: PR; 6) Substrate: PR+AMF; 7) Substrate: PR+S and 8) Substrate: PR+AMF+S. Three replicates were performed per treatment. All parameters evaluated (total and assimilable P content in substrate, P in plant tissue and plant dry biomass) were significantly higher in plants grown in substrate containing PR and inoculas with S and AMF. This work confirms that the combination of S/AMF with Puyehue volcanic ashes, PR from the Río Chico Group and a commercial substrate promote the growth of L. sativa, thus increasing the added value of national geomaterials. Copyright © 2017 Asociación Argentina de Microbiología. Publicado por Elsevier España, S.L.U. All rights reserved.

  3. The Novarupta-Katmai eruption of 1912 - largest eruption of the twentieth century; centennial perspectives (United States)

    Hildreth, Wes; Fierstein, Judy


    The explosive outburst at Novarupta (Alaska) in June 1912 was the 20th century's most voluminous volcanic eruption. Marking its centennial, we illustrate and document the complex eruptive sequence, which was long misattributed to nearby Mount Katmai, and how its deposits have provided key insights about volcanic and magmatic processes. It was one of the few historical eruptions to produce a collapsed caldera, voluminous high-silica rhyolite, wide compositional zonation (51-78 percent SiO2), banded pumice, welded tuff, and an aerosol/dust veil that depressed global temperature measurably. It emplaced a series of ash flows that filled what became the Valley of Ten Thousand Smokes, sustaining high-temperature metal-transporting fumaroles for a decade. Three explosive episodes spanned ~60 hours, depositing ~17 km3 of fallout and 11±2 km3 of ignimbrite, together representing ~13.5 km3 of zoned magma. No observers were nearby and no aircraft were in Alaska, and so the eruption narrative was assembled from scattered villages and ship reports. Because volcanology was in its infancy and the early investigations (1915-23) were conducted under arduous expeditionary conditions, many provocative misapprehensions attended reports based on those studies. Fieldwork at Katmai was not resumed until 1953, but, since then, global advances in physical volcanology and chemical petrology have gone hand in hand with studies of the 1912 deposits, clarifying the sequence of events and processes and turning the eruption into one of the best studied in the world. To provide perspective on this century-long evolution, we describe the geologic and geographic setting of the eruption - in a remote, sparsely inhabited wilderness; we review the cultural and scientific contexts at the time of the eruption and early expeditions; and we compile a chronology of the many Katmai investigations since 1912. Products of the eruption are described in detail, including eight layers of regionwide fallout

  4. Ca-Lignosulphonate and sclerotial viability of Sclerotinia sclerotiorum

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    Full Text Available Lignosulphonates, low cost by-products of the pulping process, have shown suppressive effects against some diseases caused by soil-borne pathogens. In this study, the effect of 1.5% v/v calcium lignosulphonate (Ca-Ls amendment to two commercial potting mixes (peat + coconut fibres; PC; and municipal compost + peat + pumice; MCPP on the viability of Sclerotinia sclerotiorum sclerotia was investigated. Sclerotia were buried in the Ca-Ls amended substrates for 30 days. Non-amended PC and MCPP, sterile sand and sterile PC with and without Ca-Ls were used as controls. The viability of sclerotia recovered from PC and MCPP amended with Ca-Ls was reduced by 50 and 42% respectively compared to control treatments. Ca-Ls amendment decreased sclerotial viability by enhancing the activity of the indigenous mycoparasitic fungi, Fusarium oxysporum, Mucor spp. and Trichoderma spp. The biocontrol ability of Ca-Ls against sclerotia was due to the stimulation of microbial activity and is, therefore, strictly dependent on the microbial composition of the substrate.

  5. Spatial distribution of damage around faults in the Joe Lott Tuff Member of the Mount Belknap Volcanics, Utah: A mechanical analog for faulting in pyroclastic deposits on Mars (United States)

    Okubo, Chris H.


    Volcanic ash is thought to comprise a large fraction of the Martian equatorial layered deposits and much new insight into the process of faulting and related fluid flow in these deposits can be gained through the study of analogous terrestrial tuffs. This study identifies a set of fault-related processes that are pertinent to understanding the evolution of fault systems in fine-grained, poorly indurated volcanic ash by investigating exposures of faults in the Miocene-aged Joe Lott Tuff Member of the Mount Belknap Volcanics, Utah. The porosity and granularity of the host rock are found to control the style of localized strain that occurs prior to and contemporaneous with faulting. Deformation bands occur in tuff that was porous and granular at the time of deformation, while fractures formed where the tuff lost its porous and granular nature due to silicic alteration. Non-localized deformation of the host rock is also prominent and occurs through compaction of void space, including crushing of pumice clasts. Significant off-fault damage of the host rock, resembling fault pulverization, is recognized adjacent to one analog fault and may reflect the strain rate dependence of the resulting fault zone architecture. These findings provide important new guidelines for future structural analyses and numerical modeling of faulting and subsurface fluid flow through volcanic ash deposits on Mars.

  6. Lithostratigraphy of the Calico Hills Formation and Prow Pass Tuff (Crater Flat Group) at Yucca Mountain, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Moyer, T.C.; Geslin, J.K. [Science Applications International Corp., Las Vegas, NV (United States)


    Lithostratigraphic relations within the Calico Hills Formation and Prow Pass Tuff (Crater Flat Group) were reconstructed from analysis of core samples and observation of outcrop exposures. The Calico Hills Formation is composed of five nonwelded pyroclastic units (each formed of one or more pyroclastic-flow deposits) that overlie an interval of bedded tuff and a basal volcaniclastic sandstone unit. The Prow Pass Tuff is divided into four pyroclastic units and an underlying interval of bedded tuff. The pyroclastic units of the Prow Pass Tuff are distinguished by the sizes and amounts of their pumice and lithic clasts and their degree of welding. Pyroclastic units of the Prow Pass Tuff are distinguished from those of the Calico Hills Formation by their phenocryst assemblage, chemical composition, and ubiquitous siltstone lithic clasts. Downhole resistivity tends to mirror the content of authigenic minerals, primarily zeolites, in both for-mations and may be useful for recognizing the vitric-zeolite boundary in the study area. Maps of zeolite distribution illustrate that the bedded tuff and basal sandstone units of the Calico Hills Formation are altered over a wider area than the pyroclastic units of both the Calico Hills Formation and the upper Prow Pass Tuff.

  7. Proposed stratigraphic nomenclature and macroscopic identification of lithostratigraphic units of the Paintbrush Group exposed at Yucca Mountain, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Buesch, D.C.; Spengler, R.W.; Moyer, T.C.; Geslin, J.K.


    This paper describes the formations of the Paintbrush Group exposed at Yucca Mountain, Nevada, presents a detailed stratigraphic nomenclature for the Tiva Canyon and Topopah spring Tuffs, and discusses the criteria that define lithostratigraphic units. The Tiva Canyon and Topopah Spring Tuffs are divided into zones, subzones, and intervals on the basis of macroscopic features observed in surface exposures and borehole samples. Primary divisions reflect depositional and compositional zoning that is expressed by variations in crystal content, phenocryst assemblage, pumice content and composition, and lithic content. Secondary divisions define welding and crystlalization zones, depositional features, or fracture characteristics. Both formations are divided into crystal-rich and crystal-poor members that have an identical sequency of zones, although subzone designations vary slightly between the two units. The identified lithostratigraphic divisions can be used to approximate thermal-mechanical and hydrogeologic boundaries in the field. Linking these three systems of nomenclature provides a framework within which to correlate these properties through regions of sparse data.

  8. Volcanic Processes and Geology of Augustine Volcano, Alaska (United States)

    Waitt, Richard B.; Beget, James E.


    Augustine Island (volcano) in lower Cook Inlet, Alaska, has erupted repeatedly in late-Holocene and historical times. Eruptions typically beget high-energy volcanic processes. Most notable are bouldery debris avalanches containing immense angular clasts shed from summit domes. Coarse deposits of these avalanches form much of Augustine's lower flanks. A new geologic map at 1:25,000 scale depicts these deposits, these processes. We correlate deposits by tephra layers calibrated by many radiocarbon dates. Augustine Volcano began erupting on the flank of a small island of Jurassic clastic-sedimentary rock before the late Wisconsin glaciation (late Pleistocene). The oldest known effusions ranged from olivine basalt explosively propelled by steam, to highly explosive magmatic eruptions of dacite or rhyodacite shed as pumice flows. Late Wisconsin piedmont glaciers issuing from the mountainous western mainland surrounded the island while dacitic eruptive debris swept down the south volcano flank. Evidence is scant for eruptions between the late Wisconsin and about 2,200 yr B.P. On a few south-flank inliers, thick stratigraphically low pumiceous pyroclastic-flow and fall deposits probably represent this period from which we have no radiocarbon dates on Augustine Island. Eruptions between about 5,350 and 2,200 yr B.P. we know with certainty by distal tephras. On Shuyak Island 100 km southeast of Augustine, two distal fall ashes of Augustinian chemical provenance (microprobe analysis of glass) date respectively between about 5,330 and 5,020 yr B.P. and between about 3,620 and 3,360 yr B.P. An Augustine ash along Kamishak Creek 70 km southwest of Augustine dates between about 3,850 and 3,660 yr B.P. A probably Augustinian ash lying within peat near Homer dates to about 2,275 yr B.P. From before 2,200 yr B.P. to the present, Augustine eruptive products abundantly mantle the island. During this period, numerous coarse debris avalanches swept beyond Augustine's coast, most

  9. Evaluating Complex Magma Mixing via Polytopic Vector Analysis (PVA in the Papagayo Tuff, Northern Costa Rica: Processes that Form Continental Crust

    Directory of Open Access Journals (Sweden)

    Guillermo E. Alvarado


    Full Text Available Over the last forty years, research has revealed the importance of magma mixing as a trigger for volcanic eruptions, as well as its role in creating the diversity of magma compositions in arcs. Sensitive isotopic and microchemical techniques can reveal subtle evidence of magma mixing in igneous rocks, but more robust statistical techniques for bulk chemical data can help evaluate complex mixing relationships. Polytopic vector analysis (PVA is a multivariate technique that can be used to evaluate suites of samples that are produced by mixing of two or more magma batches. The Papagayo Tuff of the Miocene-Pleistocene Bagaces Formation in northern Costa Rica is associated with a segment of the Central American Volcanic Arc. While this segment of the arc is located on oceanic plateau, recent (<8 Ma ignimbrites bear the chemical signatures of upper continental crust, marking the transition from oceanic to continental crust. The Papagayo Tuff contains banded pumice fragments consistent with one or more episodes of mixing/mingling to produce a single volcanic deposit. The PVA solution for the sample set is consistent with observations from bulk chemistry, microchemistry and petrographic data from the rocks. However, without PVA, the unequivocal identification of the three end-member solution would not have been possible.

  10. Effect of two bleaching agents on enamel morphology: a SEM study

    Directory of Open Access Journals (Sweden)

    Ghavam M.


    Full Text Available Statement of Problem: Bleaching materials are able to change the surface morphology as well as mineral and organic content of tooth structure. Considering that bleaching is done for aesthetic purpose, awareness of the possible effect of these materials on hard tissue is important, because it may affect the restorative treatments. Purpose: The aim of this study was comparing the effect of two bleaching materials, Kimia and Ultradent both containing 35% H2O2, on tooth enamel by SEM. Materials and Methods: Five intact central incisors were cut into three sections vertically and each part was randomly divided into three groups. Group 1 (control, without any bleaching. Group 2, bleached with Kimia 35% H2O2. Group 3, bleached with Ultradent 35% H2O2. Each tooth served as its own control. Then the samples were observed by SEM with 250 and 500 magnifications. Results: In the control group some scratches and small white grains were observed which seems to be the result of mastication trauma and pumice powder. In the other groups, morphologic changes like increased surface roughness, deepening of cracks, rod exposure and presence of new cracks were observed. The two experimental materials did not differ in these regards. Conclusion: It seems that both studied materials have limited destructive effects on tooth enamel which seems to be of no clinical importance.

  11. Attempt of groundwater dating using the drilled rock core. 1. Development of the rock sampling method for measurement of noble gases dissolved in interstitial water in rock

    International Nuclear Information System (INIS)

    Mahara, Yasunori


    Groundwater dating in low permeable rock is very difficult and impracticable, because we take a very long time to collect groundwater sample in a borehole and have to invest much fund in production of the in-situ groundwater sampler and in operation of it. If we can directly measure noble gases dissolved in interstitial groundwater in rock core, we have a big merit to estimate groundwater resident time easy. In this study, we designed and produced a high vacuum container to let dissolved noble gases diffuse until reaching in equilibrium, and we made a handling manual of the rock core into the container and a procedure to vacuum out air from the sealed container. We compared data sets of noble gas concentration obtained from rock cores and groundwater sample collected from boreholes in-situ. The measured rocks are pumice-tuff rock, mud rock and hornfels, which have their permeabilities of 10 -6 cm/s, 10 -9 cm/s and 10 -11 cm/s, respectively. Consequently, we evaluated the rock core method is better than the in-situ groundwater sampling method for low permeable rock. (author)

  12. Enamel microabrasion: An overview of clinical and scientific considerations (United States)

    Pini, Núbia Inocencya Pavesi; Sundfeld-Neto, Daniel; Aguiar, Flavio Henrique Baggio; Sundfeld, Renato Herman; Martins, Luis Roberto Marcondes; Lovadino, José Roberto; Lima, Débora Alves Nunes Leite


    Superficial stains and irregularities of the enamel are generally what prompt patients to seek dental intervention to improve their smile. These stains or defects may be due to hypoplasia, amelogenesis imperfecta, mineralized white spots, or fluorosis, for which enamel microabrasion is primarily indicated. Enamel microabrasion involves the use of acidic and abrasive agents, such as with 37% phosphoric acid and pumice or 6% hydrochloric acid and silica, applied to the altered enamel surface with mechanical pressure from a rubber cup coupled to a rotatory mandrel of a low-rotation micromotor. If necessary, this treatment can be safely combined with bleaching for better esthetic results. Recent studies show that microabrasion is a conservative treatment when the enamel wear is minimal and clinically imperceptible. The most important factor contributing to the success of enamel microabrasion is the depth of the defect, as deeper, opaque stains, such as those resulting from hypoplasia, cannot be resolved with microabrasion, and require a restorative approach. Surface enamel alterations that result from microabrasion, such as roughness and microhardness, are easily restored by saliva. Clinical studies support the efficacy and longevity of this safe and minimally invasive treatment. The present article presents the clinical and scientific aspects concerning the microabrasion technique, and discusses the indications for and effects of the treatment, including recent works describing microscopic and clinical evaluations. PMID:25610848

  13. Volcanic hazard zonation of the Nevado de Toluca volcano, México (United States)

    Capra, L.; Norini, G.; Groppelli, G.; Macías, J. L.; Arce, J. L.


    The Nevado de Toluca is a quiescent volcano located 20 km southwest of the City of Toluca and 70 km west of Mexico City. It has been quiescent since its last eruptive activity, dated at ˜ 3.3 ka BP. During the Pleistocene and Holocene, it experienced several eruptive phases, including five dome collapses with the emplacement of block-and-ash flows and four Plinian eruptions, including the 10.5 ka BP Plinian eruption that deposited more than 10 cm of sand-sized pumice in the area occupied today by Mexico City. A detailed geological map coupled with computer simulations (FLOW3D, TITAN2D, LAHARZ and HAZMAP softwares) were used to produce the volcanic hazard assessment. Based on the final hazard zonation the northern and eastern sectors of Nevado de Toluca would be affected by a greater number of phenomena in case of reappraisal activity. Block-and-ash flows will affect deep ravines up to a distance of 15 km and associated ash clouds could blanket the Toluca basin, whereas ash falls from Plinian events will have catastrophic effects for populated areas within a radius of 70 km, including the Mexico City Metropolitan area, inhabited by more than 20 million people. Independently of the activity of the volcano, lahars occur every year, affecting small villages settled down flow from main ravines.

  14. Simulation of water-rock interaction in the yellowstone geothermal system using TOUGHREACT

    International Nuclear Information System (INIS)

    Dobson, P.F.; Salah, S.; Spycher, N.; Sonnenthal, E.


    The Yellowstone geothermal system provides an ideal opportunity to test the ability of reactive transport models to accurately simulate water-rock interaction. Previous studies of the Yellowstone geothermal system have characterized water-rock interaction through analysis of rocks and fluids obtained from both surface and downhole samples. Fluid chemistry, rock mineralogy, permeability, porosity, and thermal data obtained from the Y-8 borehole in Upper Geyser Basin were used to constrain a series of reactive transport simulations of the Yellowstone geothermal system using TOUGHREACT. Three distinct stratigraphic units were encountered in the 153.4 m deep Y-8 drill core: volcaniclastic sandstone, perlitic rhyolitic lava, and nonwelded pumiceous tuff. The main alteration phases identified in the Y-8 core samples include clay minerals, zeolites, silica polymorphs, adularia, and calcite. Temperatures observed in the Y-8 borehole increase with depth from sub-boiling conditions at the surface to a maximum of 169.8 C at a depth of 104.1 m, with near-isothermal conditions persisting down to the well bottom. 1-D models of the Y-8 core hole were constructed to determine if TOUGHREACT could accurately predict the observed alteration mineral assemblage given the initial rock mineralogy and observed fluid chemistry and temperatures. Preliminary simulations involving the perlitic rhyolitic lava unit are consistent with the observed alteration of rhyolitic glass to form celadonite

  15. Inoculum development by using activated sludge to remove hydrogen sulphide (H2S through biofiltration*

    Directory of Open Access Journals (Sweden)

    Alejandra Mora


    Full Text Available Different activated sludges were used for developing an inoculum able to degrade hydrogen sulphide in a pilot scale biofiltration plant using two different support materials: sugarcane bagasse and this bagasse mixed with pumice stone. Adapting and selecting microbial species which degrade hydrogen sulphide (H2S was aided by adding nutrients plus a specific substrate to the activated sludge. Population variation was monitored within the different trophic groups in the biofiter medium during pilot scale plant operation, a general trend towards sulphur-oxidising bacteria (SOB growth being observed as was a decrease in heterotrophic bacteria, molds and yeasts. The activated sludge which showed the highest substrate degradation speed was selected for standardising inoculum preparation; the different nutritional mediums were evaluated during this process. Measuring some variables for controlling the process led to choosing the pH for determining the proper point of inoculum adaptation for this specific substrate. The inoculation procedure and support characteristics in terms of establishing and developing the microbial species increased biofilter removal efficiency by up to 99% from start-up. Key words: biofilter, activated sludge, adapted microorganisms, sulphur-oxidising bacteria, respirometry. Este artículo es el resultado de un proyecto cofinanciado por Colciencias y desarrollado por un grupo de investigadores vinculados al proyecto a través de las entidades Corporación

  16. Evaluation of the potential for debris and hyperconcentrated flows in Capulin Canyon as a result of the 1996 Dome fire, Bandelier National Monument, New Mexico (United States)

    Cannon, Susan H.


    The Dome fire of April 1996 burned 6684 ha in Bandelier National Monument and the adjacent Sante Fe National Forest. The potential for significant debris- and hyperconcentrated-flow activity in Capulin Canyon is evaluated through 1) a systematic consideration of geologic and geomorphic factors that characterize the condition of the hillslope materials and channels following the fire, 2) examination of sedimentologic evidence for past debris-flow activity in the canyon, and 3) evaluation of the response of the watershed through the 1996 summer monsoon season. The lack of accumulations of dry-ravel material on the hillslopes or in channels, the absence of a continuous hydrophobic layer, the relatively intact condition of the riparian vegetation and of the fibrous root mat on the hillslopes, and the lack of evidence of widespread past debris- and hyperconcentrated-flow activity, even with evidence of past fires, indicate a low potential for debris-flow activity in Capulin Canyon. In addition, thunderstorms during the summer monsoon of 1996 resulted in abundant surface overland flow on the hillslopes which transported low-density pumice, charcoal, ash and some mineral soil downslope as small-scale and non-erosive debris flows. In some places cobble- and boulder-sized material was moved short distances. A moderate potential for debris- and hyperconcentrated-flow activity is identified for the two major tributary canyons to Capulin Canyon based on evidence of both summer of 1996 and possible historic significant debris-flow activity.

  17. Major periods of erosion and alluvial sedimentation in New Zealand during the Late Holocene

    International Nuclear Information System (INIS)

    Grant, P.J.


    During the last 1,800 years there have been eight major periods of erosion and alluvial sedimentation in New Zealand. These and their probable times of occurrence are: Taupo (1,l764 years BP), Post-Taupo (1,600-1,500 years BP), Pre-Kaharoa (1,300-900 years BP), Waihirere (680-600 years BP), Matawhero (450-330 years BP), Wakarara (180-150 years BP), Tamaki (1870-1900 AD) and Waipawa (1950 to present). The Taupo period, which is identified only in North Island, possibly resulted from heavy rainfalls induced by the Taupo Pumice eruption. The other seven periods, which probably occurred universally in both main islands of New Zealand, were almost certainly caused by increased northerly airflow and atmospheric warming over New Zealand, and the associated increased magnitude of major rainstorms and floods, producing increased rates of erosion and channel sediment transport. Such changes were due primarily to a temporary strengthening of the meridional upper atmospheric circulation in the Southwest Pacific region

  18. The assessment of orthodontic bonding defects: optical coherence tomography followed by three-dimensional reconstruction (United States)

    Rominu, R.; Sinescu, C.; Rominu, M.; Negrutiu, M.; Petrescu, E.; Pop, D.; Podoleanu, A. Gh.


    Orthodontic bonding is a simple yet important procedure that can influence the outcome of treatment in case it is performed incorrectly. An orthodontic treatment shadowed by repeated bonding failures can become unduly long and will decrease patient trust and compliance. Optical coherence tomography has been widely used in ophtalmology but is relatively new to dentistry. Using OCT one can detect aerial inclusions within the orthodontic adhesive or even identify incongruence between the bracket base and the tooth surface. The aim of our study was to identify bonding defects and reconstruct them three-dimensionally in order to be able to characterize them more accurately. We bonded 30 sound human permanent teeth with ceramic orthodontic brackets using a no-mix self-curing orthodontic adhesive. Prior to bonding all teeth were stored in tap water at 4°C and then professionally cleaned with rotary brushes and pumice. The samples were processed by the same person and the rotary brushes were changed after every fifth tooth. All interfaces were investigated by means of OCT and 4 defects were found. Subsequently, the defects were reconstructed threedimensionally using an open-source program. By identifying and reconstructing bonding defects we could assess the quality of the bonding procedure. Since bonding tends to be more accurate in vitro where the environmental conditions are close to ideal, it is probable that defects found in vivo be even greater in number, which leads to the conclusion that this type of investigation is potentially valuable.

  19. Effect of adhesive remnant removal on enamel topography after bracket debonding

    Directory of Open Access Journals (Sweden)

    Larissa Adrian Meira Cardoso


    Full Text Available INTRODUCTION: At orthodontic treatment completion, knowledge about the effects of adhesive remnant removal on enamel is paramount.OBJECTIVE: This study aimed at assessing the effect of different adhesive remnant removal methods on enamel topography (ESI and surface roughness (Ra after bracket debonding and polishing.METHODS: A total of 50 human premolars were selected and divided into five groups according to the method used for adhesive remnant removal: high speed tungsten carbide bur (TCB, Sof-Lex discs (SL, adhesive removing plier (PL, ultrasound (US and Fiberglass burs (FB. Metal brackets were bonded with Transbond XT, stored at 37oC for 24 hours before debonding with adhesive removing plier. Subsequently, removal methods were carried out followed by polishing with pumice paste. Qualitative and quantitative analyses were conducted with pre-bonding, post-debonding and post-polishing analyses. Results were submitted to statistical analysis with F test (ANOVA and Tukey's (Ra as well as with Kruskal-Wallis and Bonferroni tests (ESI (P < 0.05.RESULTS: US Ra and ESI were significantly greater than TCB, SL, PL and FB. Polishing minimized Ra and ESI in the SL and FB groups.CONCLUSION: Adhesive remnant removal with SL and FB associated with polishing are recommended due to causing little damage to the enamel.

  20. Large eruption-triggered ocean-island landslide at Tenerife

    DEFF Research Database (Denmark)

    Harris, P; Branney, M; Storey, Michael


    An extensive debris-avalanche deposit has been discovered on Cañadas volcano, Tenerife (Canary Islands). The onshore component of the 733 ± 3 ka Abona landslide deposit exposes classic block facies and mixed facies across 90 km2. Three lines of evidence together show that the avalanche was trigge......An extensive debris-avalanche deposit has been discovered on Cañadas volcano, Tenerife (Canary Islands). The onshore component of the 733 ± 3 ka Abona landslide deposit exposes classic block facies and mixed facies across 90 km2. Three lines of evidence together show that the avalanche...... was triggered by an ignimbrite-forming explosive eruption: (1) the deposit is enclosed by phonolitic ignimbrites and is draped by a Plinian fallout layer, all within a single eruption unit; (2) it contains prismatic-jointed pumice blocks that were hot during landslide emplacement, indicated by chilled rims...... and breadcrust surfaces; (3) these blocks yield the same 40Ar/39Ar date as the associated ignimbrite and fall deposit. Landslide hummocks dammed surface water, forming ephemeral lakes perched on the volcano flank. Phonolite dome growth destabilized the southeast sector of a mid-Pleistocene Cañadas caldera wall...

  1. Preliminary confirmation of a surface faulting based on geological and earthquake data in the Puspiptek Serpong area

    International Nuclear Information System (INIS)

    Hadi Suntoko; Supartoyo


    BAPETEN regulation No. 8/2013 present the requirement that the site of the nuclear industry should not be a fault capable in a radius of 5 km. It is known that the RDE site composed of sandstones, clay stone, conglomerates and pumice rework the age of Pliocene, there straightness river valley hypothesized as a fault. Potential faults are identified using morphological observation, remote sensing using DEM rock outcrops, and seismic interpretation results that aims to confirm capable faults in a radius of 5 km. Traces defence surface is focused on the observation of the appearance of the terrain (land form), in the form of straightness morphology or valleys, fault scarp (fault scarp), shift or offset (river or hill), depression formed along fault zones, saddle, pressure ridge, and the shape of the river as well as earthquake monitoring. The results showed that there was no fault capable also a surface faulting that prove the presence in the RDE site radius of 5 km. (author)

  2. The volcaniclastic sequence of Aranzazu: Record of the impact of volcanism on Neogene fluvial system in the middle part of the Central Cordillera, Colombia

    International Nuclear Information System (INIS)

    Borrero Pena, Carlos Alberto; Rosero Cespedes, Juan Sebastian; Valencia M, Julian David; Pardo Trujillo, Andres


    The volcaniclastic sequence of Aranzazu (VSA, late Pliocene - early Pleistocene?) was sourced from the northernmost sector of the Machin - Cerro Bravo volcanic complex. The volcaniclastic accumulations filled the pre-existing fault-bend depressions in the surroundings of Aranzazu town (Caldas department, Colombia). A new classification of volcaniclastic deposits is proposed, in which the lahars are defined as volcaniclastic resedimented deposits, and differentiated from the primary volcaniclastic and epiclastic deposits. The updating the sedimentology and rheology of the deposits related with the laharic events is aimed. The VSA stratigraphy is based on the lithofacies identification and the definition of the architectural elements for syn- and inter-eruptive periods. The VSA lower member corresponds to the successive aggradation of syneruptive lahars (SV and SB elements) resulted from re-sedimentation of pumice-rich pyroclastic deposits and transported as debris and hyperconcentrated stream/flood flows. The VSA middle and upper members defined by coal contents were formed during the dominion of inter-eruptive (FF element) over the syn-eruptive (SV and SB elements) periods. They were formed during the reestablishment of the fluvial condition after the syn-eruptive laharic activity. Once the fluvial deposition was strengthened, the necessary conditions for the peat formation were propitious and the coal-bearing bed sets were developed.

  3. Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile Eruption: Preliminary Approach for the Application in the Arsenic Removal

    Directory of Open Access Journals (Sweden)

    Irma Lia Botto


    Full Text Available Volcanic ash from Puyehue Cordon Caulle Volcanic Complex (Chile, emitted on June 4, 2011, and deposited in Villa La Angostura at ~40 km of the source, was collected and analyzed by Raman spectroscopy, optical and scanning electron microscopy (SEM-EDS, X-ray diffraction (XRD, surface area (BET, and chemical analysis (ICP-AES-MS technique. The mineralogical and physicochemical study revealed that the pyroclastic mixture contains iron oxides in the form of magnetite and hematite as well as pyroxene and plagioclase mineral species and amorphous pumiceous shards. Carbonaceous material was also identified. Physicochemical techniques allow us to select two representative samples (average composition and Fe-rich materials which were used to analyze their performances in the adsorption process to remove arsenic from water. Additional iron activation by means of ferric salts was performed under original sample. Results showed that the low-cost feedstock exhibited a good adsorption capacity to remove the contaminant, depending on the iron content and the water pH.

  4. 40Ar/39Ar chronology of the McMurdo Volcanic Group at The Pleiades, Northern Victoria Land, Antarctica

    International Nuclear Information System (INIS)

    Esser, R.P.; Kyle, P.R.


    Fifteen samples from The Pleiades volcanic centre in northern Victoria Land, Antarctica, were dated using the 40 Ar/ 39 Ar furnace step-heating method. Ages range from 847 to 6 ka. Eight samples are <100 ka, showing that The Pleiades are very young. Three trachyte samples suggest eruptive activity started at c. 830 ka. An apparent increase in volcanic activity began at c. 100 ka, and at c. 65 ka a significant phase of cone building occurred at Mt Atlas, the largest volcanic cone at The Pleiades. At c. 45 ka, lava flows were erupted on the western flank of Mt Pleiones adjacent to Mt Atlas and near the summit of Alcyone Cone. The youngest activity (6 ± 6 ka) occurred at Taygete Cone, an endogenous dome of trachyte. The near-zero age for Taygete Cone is consistent with evidence of recent volcanism, including fresh hydrothermal activity and compositionally similar pumice lapilli scattered over parts of The Pleiades. (author). 6 refs., 3 figs., 1 tab

  5. Proposed stratigraphic nomenclature and macroscopic identification of lithostratigraphic units of the Paintbrush Group exposed at Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    Buesch, D.C.; Spengler, R.W.; Moyer, T.C.; Geslin, J.K.


    This paper describes the formations of the Paintbrush Group exposed at Yucca Mountain, Nevada, presents a detailed stratigraphic nomenclature for the Tiva Canyon and Topopah spring Tuffs, and discusses the criteria that define lithostratigraphic units. The Tiva Canyon and Topopah Spring Tuffs are divided into zones, subzones, and intervals on the basis of macroscopic features observed in surface exposures and borehole samples. Primary divisions reflect depositional and compositional zoning that is expressed by variations in crystal content, phenocryst assemblage, pumice content and composition, and lithic content. Secondary divisions define welding and crystlalization zones, depositional features, or fracture characteristics. Both formations are divided into crystal-rich and crystal-poor members that have an identical sequency of zones, although subzone designations vary slightly between the two units. The identified lithostratigraphic divisions can be used to approximate thermal-mechanical and hydrogeologic boundaries in the field. Linking these three systems of nomenclature provides a framework within which to correlate these properties through regions of sparse data

  6. The petrologic evolution and pre-eruptive conditions of the rhyolitic Kos Plateau Tuff (Aegean arc) (United States)

    Bachmann, Olivier


    The Kos Plateau Tuff is a large (>60 km3) and young (160 k.y.) calc-alkaline, high-SiO2 rhyolitic ignimbrite from the active Kos-Nisyros volcanic center in the Aegean arc (Greece). Combined textural, petrological and geochemical information suggest that (1) the system evolved dominantly by crystal fractionation from (mostly unerupted) more mafic parents, (2) the magma chamber grew over ≥ 250 000 years at shallow depth (˜1.5-2.5 kb) and was stored as a H2O-rich crystalline mush close to its solidus (˜670-750°C), (3) the eruption occurred after a reheating event triggered by the intrusion of hydrous mafic magma at the base of the rhyolitic mush. Rare banded pumices indicate that the mafic magma only mingled with a trivial portion of resident crystal-rich rhyolite; most of the mush was remobilized following partial melting of quartz and feldspars induced by advection of heat and volatiles from the underplated, hotter mafic influx.

  7. The melt inclusion record from the rhyolitic Kos Plateau Tuff (Aegean Arc) (United States)

    Bachmann, Olivier; Wallace, Paul J.; Bourquin, Julie


    The >60 km3 rhyolitic Kos Plateau Tuff provides an exceptional probe into the behavior of volatile components in highly evolved arc magmas: it is crystal-rich (30-40 vol% crystals), was rapidly quenched by the explosive eruptive process, and contains abundant homogeneous melt inclusions in large quartz crystals. Several methods for measuring major, trace and volatile element concentrations (SIMS, FTIR, Raman spectroscopy, electron microprobe, LA-ICPMS) were applied to these melt inclusions. We found a ~2 wt% range of H2O contents (4.5-6.5 wt% H2O, measured independently by SIMS, FTIR, and Raman spectroscopy) and relatively low CO2 concentrations (15-140 ppm measured by FTIR, with most analyses <100 ppm). No obvious correlations between H2O, CO2, major and trace elements are observed. These observations require a complex, protracted magma evolution in the upper crust that included: (1) vapor-saturated crystallization in a chamber located between 1.5 and 2.5 kb pressure, (2) closed-system degassing (with up to 10 vol% exsolved gas) as melts percolated upwards through a vertically extensive mush zone (2-4 km thick), and (3) periodic gas fluxing from subjacent, more mafic and more CO2-rich magma, which is preserved as andesite bands in pumices. These processes can account for the range of observed H2O and CO2 values and the lack of correlation between volatiles and trace elements in the melt inclusions.

  8. Fission-track ages of Neogene and Quaternary volcanic ashes in south of Osaka, Japan

    International Nuclear Information System (INIS)

    Yokoyama, Takuo; Nakagawa, Yonosuke; Danhara, Tohru.


    A calculation method is proposed for the fission-track ages of zircon crystals in volcanic material. In this method, it is checked whether the spontaneous fission-track number of respective zircon crystals follows the Poisson distribution. If it does, the age is calculated by population method with all crystals, and if not, only with those crystals following the Poisson distribution, eliminating abnormal crystals. Extraneous zircon crystals are thus excluded and crystals with spontaneous fission-track number zero are not ignored. The following ages were obtained: Tamateyama volcanic ash in the Nijo group, 14.0 +- 0.6 Ma; pink volcanic ash in the Osaka group, 1.0 +- 0.2 Ma; Matsuo volcanic ash in the Ko-Osaka group, 1.5 +- 0.4 Ma; pumice volcanic ash in the Ko-Osaka group, 2.3 +- 0.4 Ma; Asashiro volcanic ash in the Ko-Osaka group, 2.9 +- 0.6 Ma. (Mori, K.)

  9. In Vitro Comparison of Microleakage of Two Materials Used as Pit and Fissure Sealants

    Directory of Open Access Journals (Sweden)

    Zahra Bahrololoomi


    Full Text Available Background and aims. Marginal seal of the material is extremely important in fissure sealant therapy. The aim of this study was to investigate microleakage of flowable composite resins and conventional fissure sealants with or without dentin bonding agent. Materials and methods. The occlusal surface of 60 intact extracted human premolars, divided into four groups, were cleaned with pumice/slurry, etched with 37% phosphoric acid for 15 seconds, rinsed and dried. Groups were treated differently: Excite bonding agent followed by Helioseal F fissure sealant in group1; Helioseal F alone in group 2; Excite bonding agent followed by Tetric Flow in group 3; and Tetric Flow alone in group 4. Light-curing was done after each application. After thermocycling, the whole surface of each specimen was coated with nail varnish except for one millimeter around the fissure sealant. The teeth were immersed in 2% basic fuchsin for 24 hours and then sectioned buccolingually. The sections were analyzed for leakage under a stereomicroscope. Data was analyzed by Kruskal-Wallis and Mann-Whitney tests at a significance level of P 0.05, except for groups 2 and 4 (P = 0.002 and groups 3 and 4 (P = 0.033. Conclusion. Use of a flowable composite with bonding agent is a good alternative for sealing pits and fissures; however, further in vitro and in vivo studies are necessary.

  10. Moisture Transfer in Concrete: Numerical Determination of the Capillary Conductivity Coefficient

    Directory of Open Access Journals (Sweden)

    Simo Elie


    Full Text Available We numerically investigated moisture transfer in buildings made of concrete. We considered three types of concrete: normal concrete, pumice concrete and cellular concrete. We present the results of a 1-D liquid water flow in such materials. We evaluated the moisture distribution in building materials using the Runge-Kutta fourth-and-fifth-order method. The DOPRI5 code was used as an integrator. The model calculated the resulting moisture content and other moisture-dependent physical parameters. The moisture curves were plotted. The dampness data obtained was utilized for the numerical computation of the coefficient of the capillary conductivity of moisture. Different profiles of this coefficient are represented. Calculations were performed for four different values of the outdoor temperature: -5°C, 0°C, 5°C and 10°C. We determined that the curves corresponding to small time intervals of wetting are associated with great amplitudes of the capillary conductivity . The amplitudes of the coefficient of the capillary conductivity decrease as the time interval increases. High outdoor temperatures induce high amplitudes of the coefficient of the capillary conductivity.

  11. Comparative study of resin sealant and resin modified glass ionomer as pit and fissure sealant

    Directory of Open Access Journals (Sweden)

    Shirin Malek


    Full Text Available The purpose of the present study was to compare the marginal integrity of resin modified glass ionomer cement with that of resin sealant, in vitro. Forty artificial pit and fissure cavities were prepared in occlusal surface of extracted premolar teeth by using ¼ round carbide bur. Cavities were condensed with artificial organic debris followed by cleaning with prophylaxis pumice brush and paste and then separated into two treatment groups. In Group A, 15 fissure cavities were sealed by resin sealant and in Group B, 15 fissure cavities were sealed by resin modified glass ionomer sealant. These specimens were subjected to thermo-cycling followed by dye penetration test. The remaining 5 cavities from each group were analyzed for debris score by the SEM. The results of the microleakage test showed that the efficacy of preventing microleakage of samples sealed by resin modified glass ionomer sealant was higher than the samples sealed by resin sealant. However, no significant differences were found. It can be concluded that use of resin modified glass ionomer sealant is a good alternative for sealing pits and fissures.

  12. Dirt-binding particles consisting of hydrogenated castor oil beads constitute a nonirritating alternative for abrasive cleaning of recalcitrant oily skin contamination in a three-step programme of occupational skin protection. (United States)

    Mahler, V; Erfurt-Berge, C; Schiemann, S; Michael, S; Egloffstein, A; Kuss, O


    In occupational fields with exposure to grease, oil, metal particles, coal, black lead or soot, cleansing formulations containing abrasive bodies (e.g. refined walnut shell, corn, wood, plastic or pumice) are used. These may constitute an irritant per se. As an alternative, hydrogenated castor oil (also known as castor wax) beads have been developed as dirt-binding particles. A polar surface contributes to their mechanical cleaning effects in removal of oily grime. Standardized examination of the in vivo effects upon the skin barrier of castor wax beads in comparison with abrasive bodies and pure detergent. Three cleansing preparations - (i) detergent, (ii) detergent containing castor wax beads, (iii) detergent containing walnut shell powder - were each repetitively applied in vivo (four times daily for 3 weeks), mimicking workplace conditions, in 30 healthy volunteers (15 with and 15 without an atopic skin diathesis) and compared vs. (iv) no treatment. The treatment effects upon the skin barrier were monitored by repeated measurements of functional parameters [transepidermal water loss (TEWL), redness] and surface topography. After a 3-week treatment, a significant global treatment effect (P dirt and use of skin protection and skin care measures under real workplace conditions, this component may now be used and examined further in different occupations.

  13. Assessment of porous material anisotropy and its effect on gas permeability (United States)

    Wałowski, Grzegorz


    The results of experimental research upon the assessment of porous material anisotropy and its effect on gas permeability of porous materials with respect to the gas flow. The conducted research applied to natural materials with an anisotropic gap-porous structure and - for comparative purposes - to model materials such as coke, pumice and polyamide agglomerates. The research was conducted with the use of a special test stand that enables measuring the gas permeability with respect to three flow orientations compared with symmetric cubic-shaped samples. The research results show an explicit impact of the flow direction on the permeability of materials porous, which results from their anisotropic internal structures. The anisotropy coefficient and permeability effective coefficient of such materials was determined and an experimental evaluation of the value of this coefficient was conducted with respect to the gas stream and the total pressure drop across the porous deposit. The process of gas permeability was considered in the category of hydrodynamics of gas flow through porous deposits. It is important to broaden the knowledge of gas hydrodynamics assessment in porous media so far unrecognised for the development of a new generation of clean energy sources, especially in the context of biogas or raw gas production.

  14. Evaluation of surface physical properties of acrylic resins for provisional prosthesis

    Directory of Open Access Journals (Sweden)

    Sérgio Paulo Hilgenberg


    Full Text Available Acrylic resins used for provisional prostheses should have satisfactory superficial characteristics in order to ensure gingival health and low bacterial attachment. The purpose of the present study was to evaluate the superficial roughness and contact angle after two types of polishing and the Vickers hardness of three acrylic resins (Duralay - G1, Dencrilay - G2, and Dencor - G3, all shade 66, indicated for provisional fixed prostheses. Five 20 x 3 ± 1 mm diameter discoid specimens were obtained for each group. One side of the specimens was subjected to standard polishing (pumice and whiting slurry, and the opposite side was polished with special tips. The mean roughness and contact angles of the materials were measured. The specimens were subjected to the Vickers microhardness test, which indicated that standard polishing produced a surface roughness equivalent to that of the special tips. The contact angles obtained with the standard polishing were equivalent to those observed in the special tips group. The microhardness of G1 and G3 resins showed statistical differences.

  15. Tephrostratigraphy and the Acheulian to middle stone age transition in the Kapthurin Formation, Kenya. (United States)

    Tryon, Christian A; McBrearty, Sally


    Sites containing Acheulian, Sangoan, Fauresmith, and Middle Stone Age artefacts occur within and below the Bedded Tuff, a widespread volcaniclastic member of the Kapthurin Formation, Kenya. The Bedded Tuff eruptive complex consists of up to twelve tephra beds, intercalated sediments, and paleosols. Two pumiceous units, high in the Bedded Tuff sequence, have been dated by(40)Ar/(39)Ar, one to 235+/-2 ka (Deino & McBrearty, 2002, Journal of Human Evolution, 42, 185-210, cf. Tallon, 1978, Geological Background to Fossil Man, pp. 361-373, Scottish Academic Press), the other to 284+/-12 ka (Deino & McBrearty, 2001), the latter now providing a minimum age estimate for all underlying archaeological sites. Bedded Tuff outcrops are correlated through field stratigraphic and electron microprobe geochemical analyses of individual beds. Bedded Tuff units show increasingly evolved composition through the stratigraphic succession, indicating that the beds are the product of intermittent eruption of a single differentiating magma system, and the chemical signatures of these beds permit the chronological ordering of archaeological sites. Our results indicate that the transition to Middle Stone Age technology occurred prior to 285 ka in this region of East Africa. The interstratification of sites containing Acheulian, Sangoan, Fauresmith, and Middle Stone Age artefacts suggests that these technologies were contemporary in a single depositional basin over the duration of the transition. Copyright 2002 Academic Press.

  16. Volcanic stratigraphy and geochemistry of the Soufrière Volcanic Centre, Saint Lucia with implications for volcanic hazards (United States)

    Lindsay, Jan M.; Trumbull, Robert B.; Schmitt, Axel K.; Stockli, Daniel F.; Shane, Phil A.; Howe, Tracy M.


    The Soufrière Volcanic Complex (SVC), Saint Lucia, represents one of the largest silicic centres in the Lesser Antilles arc. It comprises extensive pumiceous pyroclastic flow deposits, lava flows as well as Peléan-style domes and dome collapse block-and-ash-flow deposits. These deposits occur within and around the Qualibou Depression, a ~ 10-km diameter wide sector collapse structure. To date, vent locations for SVC pyroclastic deposits and their relationship to the sector collapse have been unclear because of limited stratigraphic correlation and few radiometric ages. In this study we reconstruct the geologic history of the SVC in light of new and recently published (U-Th)/He, U-Th and U-Pb zircon chronostratigraphic data, aided by mineralogical and geochemical correlation. Compositionally, SVC deposits are monotonous medium-K, calc-alkaline rocks with 61.6 to 67.7 wt.% SiO2 and display similar trace element abundances. Combined U-Th and (U-Th)/He zircon dating together with 14C ages and mineral fingerprinting reveals significant explosive eruptions at 640, 515, 265, 104, 60 and 40 ka (producing deposits previously grouped together as the "Choiseul" unit) and at 20 ka (Belfond unit). The mineralogically and geochemically distinct Belfond unit is a large, valley-filling pumiceous pyroclastic flow deposit distributed to the north, northeast, south and southeast of the Qualibou Depression that was probably deposited during a single plinian eruption. The unit previously referred to as ‘Choiseul tuff' is much less well defined. The typical Choiseul unit comprises a series of yellowish-white, crystal-poor, non-welded pumiceous pyroclastic deposits cropping out to the north and southeast of the Qualibou depression; however its age is poorly constrained. A number of other units previously mapped as Choiseul can be distinguished based on age, and in some cases mineral and whole rock chemistry. Pyroclastic deposits at Micoud (640 ± 19 ka), Bellevue (264 ± 8 ka), Anse

  17. Aberrant thermoluminescence dates obtained from primary volcanic quartz

    International Nuclear Information System (INIS)

    Guerin, Gilles; Samper, Agnes


    This study deals with the dating by thermoluminescence (TL) of quartz from six volcanic formations of the Saint Lucia Island (Lesser Antilles Arc). Quartz microcrystals up to one millimetre in size were extracted from dacites and pumice flows and prepared in a way similar to the well-known inclusion technique. The TL properties of these quartz were used to estimate apparent palaeodoses using the multi-aliquot protocol. The quartz TL was studied in three different spectral domains: red, green and ultraviolet/blue. The calculated annual dose-rates yielded a set of 18 age-estimates. For some samples complementary dates were obtained using high temperature TL (HTTL) of plagioclase feldspars. These latter dates combined with previously determined radiocarbon and unspiked K-Ar dates were used to explore the validity of ages computed from the TL of quartz. Individual values for quartz appear to be scattered and do not match ages deduced from 14 C, unspiked K-Ar or HTTL on plagioclase dates. These results indicate that when conventional TL methodologies derived from the inclusion method are applied to volcanic quartz major dating problems are to be expected

  18. Aberrant thermoluminescence dates obtained from primary volcanic quartz

    Energy Technology Data Exchange (ETDEWEB)

    Guerin, Gilles [Laboratoire des Sciences du Climat et de l' Environnement, CEA-CNRS, avenue de la Terrasse, 91191 Gif-sur-Yvette (France)], E-mail:; Samper, Agnes [Laboratoire de geochronologie multitechnique (UPS-IPGP), Universite de Paris-Sud Orsay, 91405 Orsay Cedex (France)


    This study deals with the dating by thermoluminescence (TL) of quartz from six volcanic formations of the Saint Lucia Island (Lesser Antilles Arc). Quartz microcrystals up to one millimetre in size were extracted from dacites and pumice flows and prepared in a way similar to the well-known inclusion technique. The TL properties of these quartz were used to estimate apparent palaeodoses using the multi-aliquot protocol. The quartz TL was studied in three different spectral domains: red, green and ultraviolet/blue. The calculated annual dose-rates yielded a set of 18 age-estimates. For some samples complementary dates were obtained using high temperature TL (HTTL) of plagioclase feldspars. These latter dates combined with previously determined radiocarbon and unspiked K-Ar dates were used to explore the validity of ages computed from the TL of quartz. Individual values for quartz appear to be scattered and do not match ages deduced from {sup 14}C, unspiked K-Ar or HTTL on plagioclase dates. These results indicate that when conventional TL methodologies derived from the inclusion method are applied to volcanic quartz major dating problems are to be expected.

  19. Distilling bituminous materials

    Energy Technology Data Exchange (ETDEWEB)

    Forrest, C N; Hayden, H P


    Bituminous materials such as heavy asphaltic residues from petroleum distillation or natural bitumens such as gilsonite, grahamite, etc. are distilled in presence of a carrier consisting of pieces of inert refractory material and by the heat generated by combustion of the coke which remains on the carrier after distillation. A vertical cylindrical retort, in which a wood and coal fire is first made, is charged with an inert refractory substance such as pumice stone, broken firebrick, burnt fire clay, carborundum, ash, etc. mixed with a bituminous substance, which, if fusible, may be melted and added in a rotary drum. The mixture passes downwards through the retort, first through regions in which the hydrocarbons are distilled and cracked and then through a region in which the remaining carbon is burnt by a limited supply of air and steam admitted through a grate. The inert material is discharged through a water seal and used again. Vapors, withdrawn from the retort though an outlet, pass through a heat intercharger and separator and are treated with a spray of sulfuric acid to separate ammonia in a scrubber, with water sprays to condense oil in scrubbers, and with oil in a scrubber.

  20. Petrography of the Nimun and Baca pottery (Ware Celestun Roja): Canbalam Ceramic Sphere of the Yucatan Peninsula, Mexico

    International Nuclear Information System (INIS)

    Obando, Luis G.; Jimenez Alvarez, Socorro del Pilar


    The ware Celestun Red (of the Nimun and Baca ceramic typologies) is one of the most diagnosis ceramics of the northwestern coast of Mexico's Yucatan Peninsula and subject of ongoing debate regarding its distribution and origin. Although ceramics from coastal Campeche and Yucatan have been the focus of years of investigation, scholars still do not know if Celestun Red was manufactured locally during the Late Classic (A.D. 600-900) or was made and exchanged by the regional elite. The first petrographic description of Celestun Red are provide, and use to contribute to a formal definition of the Cambalan Ceramic Sphere. These petrographic observations show that the detrital components were rhyolite fragments, vitroclastic tuffs, pumice, shards of glass, quartzes, plagioclase, calcite, hematite, magnetite and other minor contributors. The clay matrix is phyllomorphic, with a parallel, rectilinear fabric of fine grains. granulometricaly, the detrital components have been characterized as fine to medium sands. The pastes pastes present evidence of diagenetic processes, most notably porosity in the primary ceramic matrix. These space are in some cases filled by secondary calcite deposits. Evidence of manufacturing was also observed, such as the fracture and bending of the paste that took place to produce the rims of these ceramic objects. (author) [es

  1. New 40Ar/39Ar age of the Bishop Tuff from multiple sites and sediment rate calibration for the Matuyama-Brunhes boundary (United States)

    Sarna-Wojcicki, A. M.; Pringle, M.S.; Wijbrans, J.


    Precise dating of sanidine from proximal ash flow Bishop Tuff and air fall Bishop pumice and ash, California, can be used to derive an absolute age of the Matuyama Reversed-Brunhes Normal (M-B) paleomagnetic transition, identified stratigraphically close beneath the Bishop Tuff and ash at many sites in the western United States. An average age of 758.9 ?? 1.8 ka, standard error of the mean (SEM), was obtained for individual sanidine crystals or groups of several crystals, determined from ???70 individual analyses of sanidine separates from 11 sample groups obtained at five localities. The basal air fall pumice (757.7 ?? 1.8 ka) and overlying ash flow tuff (762.2 ?? 4.7 ka) from near the source yield essentially the same dates within errors of analysis, suggesting that the two units were emplaced close in time. A date on distal Bishop air fall ash bed at Friant, California, ???100 km to the west of the source area, is younger, 750.1 ?? 4.3 ka, but not significantly different within analytical error (??1 standard deviation). Previous dates of the Bishop Tuff, obtained by others using conventional K-Ar and the fission track method on zircons, ranged from ???650 ka to ???1.0 Ma. The most recent, generally accepted date by the K-Ar method on sanidine was 738 ?? 3 ka. We infer, as others before, that many K-Ar dates on sanidine feldspar are too young owing to incomplete degassing of radiogenic Ar during fusion in the K-Ar technique and that many older K-Ar dates are too old owing to detrital or xenocrystic contamination in the larger samples that are necessary for the technique. The new dates are similar to recent 40Ar/39Ar ages of the Bishop Tuff determined on individual samples by others but are derived from a larger proximal sample population and from multiple analysis of each sample. The results provide a definitive and precise age calibration of this widespread chronostratigraphic marker in the western United States and northeastern Pacific Ocean. We calculated the

  2. Influence of magma fragmentation on the plume dynamics of Vulcanian explosions (United States)

    Scheu, B.; Alatorre-Ibarguengoitia, M.; Dingwell, D. B.


    Over the last 40 years analytical, numerical and experimental studies have provided insights into many aspects of volcanic eruptions, from the fragmentation behaviour of magma to the development of volcanic plumes, subsequent ash dispersal and pyroclastic density currents. Initially research on volcanic plumes was mainly focussed on Plinian-type eruptions with quasi-steady vent conditions. However, several studies have recently investigated the plume dynamics from short-lived, Vulcanian explosions highlighting the importance of conditions at the vent for the evolution of the plume and its transition from buoyant rise to gravitational collapse (Clarke et al. 2002, Odgen et al. 2008). Previous studies have revealed the complex nature of brittle magma fragmentation in discrete fracturing events, with the time interval between two fracturing events depending on pressure evolution over the fragmentation surface (Fowler et al. 2010, McGuinness et al. 2012). In this study we investigate the influence of magma fragmentation on the dynamics of the evolving plume. We conduct rapid decompression experiments (most closely mimicking Vulcanian-type explosions) using pumice samples from the February 2010 eruption period of Soufriere Hills volcano in Montserrat, West Indies. We compare experiments of solid cylindrical samples undergoing brittle fragmentation to experiments conducted with loose granular particles of the same material (previously fragmented). All experiments are conducted at room temperature and monitored with a series of pressure sensors along the experimental conduit. A transparent setup allows us to capture the entire process from pumice fragmentation, expansion in the conduit to the ejection into the atmosphere (low pressure tank) with a high-speed video camera. In both the fragmentation and granular case, at the initial phase of the experiment the vent pressure exceeds atmospheric pressure resulting in supersonic ejection of the gas phase and the formation of a

  3. Oxygen isotope study of the Long Valley magma system, California: isotope thermometry and convection in large silicic magma bodies (United States)

    Bindeman, Ilya; Valley, John


    Products of voluminous pyroclastic eruptions with eruptive draw-down of several kilometers provide a snap-shot view of batholith-scale magma chambers, and quench pre-eruptive isotopic fractionations (i.e., temperatures) between minerals. We report analyses of oxygen isotope ratio in individual quartz phenocrysts and concentrates of magnetite, pyroxene, and zircon from individual pumice clasts of ignimbrite and fall units of caldera-forming 0.76 Ma Bishop Tuff (BT), pre-caldera Glass Mountain (2.1-0.78 Ma), and post-caldera rhyolites (0.65-0.04 Ma) to characterize the long-lived, batholith-scale magma chamber beneath Long Valley Caldera in California. Values of δ18O show a subtle 1‰ decrease from the oldest Glass Mountain lavas to the youngest post-caldera rhyolites. Older Glass Mountain lavas exhibit larger ( 1‰) variability of δ18O(quartz). The youngest domes of Glass Mountain are similar to BT in δ18O(quartz) values and reflect convective homogenization during formation of BT magma chamber surrounded by extremely heterogeneous country rocks (ranging from 2 to +29‰). Oxygen isotope thermometry of BT confirms a temperature gradient between "Late" (815 °C) and "Early" (715 °C) BT. The δ18O(quartz) values of "Early" and "Late" BT are +8.33 and 8.21‰, consistent with a constant δ18O(melt)=7.8+/-0.1‰ and 100 °C temperature difference. Zircon-melt saturation equilibria gives a similar temperature range. Values of δ18O(quartz) for different stratigraphic units of BT, and in pumice clasts ranging in pre-eruptive depths from 6 to 11 km (based on melt inclusions), and document vertical and lateral homogeneity of δ18O(melt). Worldwide, five other large-volume rhyolites, Lava Creek, Lower Bandelier, Fish Canyon, Cerro Galan, and Toba, exhibit equal δ18O(melt) values of earlier and later erupted portions in each of the these climactic caldera-forming eruptions. We interpret the large-scale δ18O homogeneity of BT and other large magma chambers as evidence

  4. Pre-eruptive conditions of the Hideaway Park topaz rhyolite: Insights into metal source and evolution of magma parental to the Henderson porphyry molybdenum deposit, Colorado (United States)

    Mercer, Celestine N.; Hofstra, Albert H.; Todorov, Todor I.; Roberge, Julie; Burgisser, Alain; Adams, David T.; Cosca, Michael A.


    The Hideaway Park tuff is the only preserved extrusive volcanic unit related to the Red Mountain intrusive complex, which produced the world-class Henderson porphyry Mo deposit. Located within the Colorado Mineral Belt, USA, Henderson is the second largest Climax-type Mo deposit in the world, and is therefore an excellent location to investigate magmatic processes leading to Climax-type Mo mineralization. We combine an extensive dataset of major element, volatile, and trace element abundances in quartz-hosted melt inclusions and pumice matrix glass with major element geochemistry from phenocrysts to reconstruct the pre-eruptive conditions and the source and evolution of metals within the magma. Melt inclusions are slightly peraluminous topaz rhyolitic in composition and are volatile-charged (≤6 wt % H2O, ≤600 ppm CO2, ∼0·3–1·0 wt % F, ∼2300–3500 ppm Cl) and metal-rich (∼7–24 ppm Mo, ∼4–14 ppm W, ∼21–52 ppm Pb, ∼28–2700 ppm Zn, shallow ascent and eruption. Filter pressing, crystal settling, magma recharge and mixing of less evolved rhyolite melt, and volatile exsolution were important processes during magma evolution; the low estimated viscosities (∼105–1010 Pa s) of these H2O- and F-rich melts probably enhanced these processes. A noteworthy discrepancy between the metal contents in the pumice matrix glass and in the melt inclusions suggests that after quartz crystallization ceased upon shallow magma ascent and eruption, the Hideaway Park magma exsolved an aqueous fluid into which Mo, Bi, Ag, Zn, Mn, Cs, and Y strongly partitioned. Given that the Henderson deposit contains anomalous abundances of not only Mo, but also W, Pb, Zn, Cu, Bi, Ag, and Mn, we suggest that these metals were sourced from similar fluids exsolved from unerupted portions of the same magmatic system. Trace element ratios imply that Mo was sourced deep, from either the lower crust or metasomatized mantle. The origin of sulfur remains unresolved

  5. Dacitic ash-flow sheet near Superior and Globe, Arizona (United States)

    Peterson, Donald W.


    , and their relative proportions are fairly uniform. Almost three-fourths of the phenocrysts are plagioclase, one-tenth quartz, one-tenth biotite, and the remainder sanidine, magnetite, and hornblende, with accessory sphene, zircon, and appetite. Pumice fragments are nearly equidimensional near the top of the sheet, and downward they become progressively more flattened until they finally disappear. The zones and the pumice fragment flattening ration (ratio of length to height) provide means for recognizing several faults within the sheet. Twelve new chemical analyses are nearly uniform in composition. If named according to chemical composition, the rock would be a quartz latite, but when named according to phenocrysts, it is a dacite. From the field occurrence and the interpretation of relict textures, it is concluded that the deposit is an ash-flow sheet containing large amounts of welded tuff, and that it was emplaced by a type of nuee ardente instead of a lava flow or air-fall shower. The nature of zoning and trend of flattening ratios indicate a series of eruptions in rapid enough succession for the sheet to form a single cooling unit. Except in the lower part of the sheet, original textures were obscured by devitrification and crystallization during cooling. Nearly uniform mineralogy and chemistry suggest a single magnetic source. A nearly circular area, about 3? miles in diameter, of altered dacite and earlier volcanic rocks, bounded by intricately faulted and brecciated older rocks, may be the site of a caldera that represents the source of the eruptions.

  6. Two coarse pyroclastic flow deposits, northern Mono-Inyo Craters, CA (United States)

    Dennen, R. L.; Bursik, M. I.; Stokes, P. J.; Lagamba, M.; Fontanella, N.; Hintz, A. R.; Jayko, A. S.


    The ~1350 A.D., rhyolitic North Mono eruption, Mono-Inyo Craters, CA, included the extrusion and destruction of Panum Dome and associated clastic deposits. Overlying the tephras of the North Mono sequence, the Panum deposits include a block-and-ash flow (BAF) deposit, covering ~3.5 km2. Blocks within the deposit are typically lithic rhyolite and banded gray micro-vesicular glass, showing white, almost powdery marks ranging from circular to linear in shape. These marks are interpreted as friction marks resulting from collisions between clasts. The deposit also contains bread-crusted obsidians with pressed-in clasts as well as reticulite with a bread-crusted surface texture. Near the centerline of the deposit is a ridge-topping train of jigsaw fractured blocks, often with reddish-orange alteration. One house sized jigsaw block sits upstream of a long, thinning pile of reddish orange debris; this “flow shadow” indicates that the block remained relatively stationary while the block and ash flow continued to propagate around it. The bread-crusted reticulite is most common at proximal localities. It is proposed that the dome destruction included a debris avalanche emplacing the train of jigsaw fractured blocks and creating a topographic high, the block-and-ash flow (the farthest reaching deposit from this event) which flowed around the debris avalanche deposits, and a final “lateral expansion” of a magma foam, creating the reticulite seen concentrated at proximal locations. Another coarse pyroclastic flow (here termed the “lower blast deposit”) underlies the North Mono tephra. It is more obsidian rich and finer grained than the Panum BAF. The lower blast deposit may have originated from Pumice Pit vent, which is now capped with an older dome ~0.5 km southeast of Panum. The lower blast deposit extends farther from the Panum vent than does the Panum BAF deposit, and apparently was mistaken for the Panum BAF deposit by previous workers. Hence the run

  7. Ustica Island (Tyrrhenian Sea, Italy): from shoaling to emergent stage (United States)

    Marinoni, L. B.; Pasquaré, G.; Vezzoli, L.


    Ustica is a volcanic island located in the southern Tyrrhenian sea, ~60 km NW of Sicily. As usual for volcanic ocean islands, its exposed part (8.6 km2, 248 m max elevation, mostly of Pleistocene age), is a small fraction of the whole edifice which rises from ~2000 m depth. Its 5-pointed-star shape is slightly elongated in a NE direction. A new geological field survey was carried out at scale 1:10000 and locally at 1:2000, establishing informal stratigraphic units that on the whole fit a common scheme of evolution for volcanic ocean islands. In this framework, the whole pre-existing stratigraphy has been revised. Ustica has a variety of volcanic deposits from submarine (basaltic effusive to explosive) to subaereal (effusive, explosive and highly explosive -Plinian?). Moreover, Ustica is one of the few places in the world where a transition of deposits from shoaling to emergent stage crop out. In fact, its oldest deposits consist of: (a) a flank-facies association of submarine lavas (variably-shaped pillows, pillow breccias and hyaloclastites) with biocalcarenite-biocalcirudite lenses, dipping coastward in the E, S and W outer parts of the island; this association is arranged in steep foreset beds (lava deltas) and is capped by flat-lying transitional to subaereal massive lava flows and surf-shaped boulder conglomerates; the geometry of this association may suggest a progressive island uplift or sea lowering during this period; (b) shallow-water to emergent tuff cone deposits in the NW part of the island. In the centre of the island, subsequent activity built a pile, now deeply eroded, of subaereal basaltic lava flows capped by a scoria cone. A previously unknown outcrop where a pumice fall layer is exposed, allows a distinction into two members of a unit that was known as formed by pyroclastic surges only. Higher in the succession, the Ustica Pumice formation (for which 4 members are defined) is underlain by a palaeosoil, and is likely the remnant of a caldera

  8. The advance of Kos Plateau Tuff ignimbrite into the marine realm of the Kalymnos Basin, SE Aegean Sea. (United States)

    Markakis, Emmanouil; Anastasakis, George


    The 161 ka Kos Plateau Tuff (KPT) eruption is considered to be the largest explosive Quaternary event in the eastern Mediterranean. It produced pumice rafts followed by "non-welded ignimbrites" that are up to 30m thick, especially widespread on Kos island and covering an area of > 80 Km2 that includes mainly islands and present marine regions. Pyroclastic flows travelled from the proposed vent, that lies between and around Yali and Nisyros islands, across present land and sea, the total volume of the tuff has been estimated as at least 100km3. KPT products principally consist of rhyolitic ash and pumice. Post 2010 Athens University oceanographic missions have mapped the seafloor around the volcanic islands of the SE Aegean Sea. Here we present new data on seafloor morphology and Upper Quaternary seafloor stratigraphy of the Kalymnos basin that extends over an area over 70km2 and map the advance and deposition of the KPT that was previously unknown in this region. The Kalymnos basin is roughly triangular in shape and essentially consists of two sedimentation depocenters: a) a roughly elliptical 400 m deep northern segment that is developed sub-parallel to Kalymnos Island and its W-SW shelf; b) a rather physiographically complex western sector developed NE of Astipalea island and reaching depths of over 620m. High resolution sparker profiles from the west Kos-Kalymnos shelf reveal an outstanding seismic stratigraphy of stacked and prograded coastal clinoform packets capped by erosional transgressive surfaces that record Quaternary eustatic lowstands deposits of sea level with clinoforms developing during forced regression and the erosional surfaces during transgression. We show that a massive gravity flow deposit is intercalated with the shelf sediments. Above it low sea level MIS 6 and 2 sedimentary sequences are fully developed and below stage 8-10 sediments are erratically preserved over stages 12 and 16 sediments. This gravity flow deposit swept across the shelf

  9. Deposits from the 12 July Dome Collapse and Explosive Activity at Soufriere Hills Volcano, 12-15 July 2003 (United States)

    Edmonds, M.; Herd, R.; Strutt, M.; Mann, C.


    A large dome collapse took place on 12-13 July 2003 at Soufriere Hills Volcano. This event was the largest in magnitude during the 1995-2003 eruption and involved over 120 million m3 andesite dome and talus material. The collapse took place over 18 hours and culminated in an explosive phase that continued intermittently until 15 July 2003. Prior to the collapse, the total volume of the dome was 230 million m3 and was made up of remnants of lava erupted 1997-2001, talus material and fresh andesite dome lava erupted during the last two years. Talus made up around 50% of the total dome volume. This paper describes and interprets the pyroclastic flow and airfall deposits from this event, using other monitoring data and empirical evidence to reconstruct the dome collapse. The airfall and pyroclastic flow deposits were studied in detail over the weeks following the collapse. Airfall deposits were studied at 45 locations around the island and 75 samples were collected for analysis. The surge deposit stretched over 10 km2 on land and 35 pits were dug at intervals through it. The sections were described and sampled, yielding a further 60 samples for grain size analysis. Further sampling was carried out on the block and ash deposits in the Tar River Valley and on the Tar River Fan. Pumices from the post-collapse explosion sequence were collected and their densities measured and mass coverage estimated. Deposit maps for airfall, lithics and pumices were constructed for all of the individual events and a map to show the distribution of the main surge unit was generated. The collapse was monitored in real-time using the MVO seismic network and observations from the field. The sequence of events was as follows. From 09:00 to 18:00, low-energy pyroclastic flows took place, confined to the Tar River Valley, which reached the sea at the mouth of Tar River. These flows gradually increased in energy throughout the day but were not associated with energetic, large surges. By 18:00 the

  10. Hydrological modelling of a slope covered with shallow pyroclastic deposits from field monitoring data

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    R. Greco


    Full Text Available A one-dimensional hydrological model of a slope covered with pyroclastic materials is proposed. The soil cover is constituted by layers of loose volcanic ashes and pumices, with a total thickness between 1.8 m and 2.5 m, lying upon a fractured limestone bedrock. The mean inclination of the slope is around 40°, slightly larger than the friction angle of the ashes. Thus, the equilibrium of the slope, significantly affected by the cohesive contribution exerted by soil suction in unsaturated conditions, may be altered by rainfall infiltration. The model assumes a single homogeneous soil layer occupying the entire depth of the cover, and takes into account seasonally variable canopy interception of precipitation and root water uptake by vegetation, mainly constituted by deciduous chestnut woods with a dense underbrush growing during late spring and summer. The bottom boundary condition links water potential at the soil–bedrock interface with the fluctuations of the water table of the aquifer located in the fractured limestone, which is conceptually modelled as a linear reservoir. Most of the model parameters have been assigned according to literature indications or from experimental data. Soil suction and water content data measured between 1 January 2011 and 20 July 2011 at a monitoring station installed along the slope allowed the remaining parameters to be identified. The calibrated model, which reproduced very closely the data of the calibration set, has been applied to the simulation of the hydrological response of the slope to the hourly precipitation record of 1999, when a large flow-like landslide was triggered close to the monitored location. The simulation results show that the lowest soil suction ever attained occurred just at the time the landslide was triggered, indicating that the model is capable of predicting slope failure conditions.

  11. Impact of rhizobial inoculation and reduced N supply on biomass production and biological N2 fixation in common bean grown hydroponically. (United States)

    Kontopoulou, Charis-Konstantina; Liasis, Epifanios; Iannetta, Pietro Pm; Tampakaki, Anastasia; Savvas, Dimitrios


    Testing rhizobial inoculation of common bean (Phaseolus vulgaris L.) in hydroponics enables accurate quantification of biological N 2 fixation (BNF) and provides information about the potential of reducing inorganic N fertilizer use. In view of this background, common bean grown on pumice was inoculated with Rhizobium tropici CIAT899 (Rt) and supplied with either full-N (total nitrogen 11.2 mmol L -1 ), 1/3 of full-N or N-free nutrient solution (NS). BNF was quantified at the early pod-filling stage using the 15 N natural abundance method. Full-N supply to Rt-inoculated plants resulted in markedly smaller nodules than less- or zero-N supply, and no BNF. Rt inoculation of full-N-treated plants did not increase biomass and pod yield compared with non-inoculation. Restriction (1/3 of full-N) or omission of inorganic N resulted in successful nodulation and BNF (54.3 and 49.2 kg N ha -1 , corresponding to 58 and 100% of total plant N content respectively) but suppressed dry shoot biomass from 191.7 (full-N, +Rt) to 107.4 and 43.2 g per plant respectively. Nutrient cation uptake was reduced when inorganic N supply was less or omitted. Rt inoculation of hydroponic bean provides no advantage when full-N NS is supplied, while 1/3 of full-N or N-free NS suppresses plant biomass and yield, partly because the restricted NO 3 - supply impairs cation uptake. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  12. Storage conditions of the mafic and silicic magmas at Cotopaxi, Ecuador (United States)

    Martel, Caroline; Andújar, Joan; Mothes, Patricia; Scaillet, Bruno; Pichavant, Michel; Molina, Indira


    The 2015 reactivation of the Cotopaxi volcano urges us to understand the complex eruptive dynamics of Cotopaxi for better management of a potential major crisis in the near future. Cotopaxi has commonly transitioned from andesitic eruptions of strombolian style (lava flows and scoria ballistics) or nuées ardentes (pyroclastic flows and ash falls) to highly explosive rhyolitic ignimbrites (pumiceous pyroclastic flows), which entail drastically different risks. To better interpret geophysical and geochemical signals, Cotopaxi magma storage conditions were determined via existing phase-equilibrium experiments that used starting materials chemically close to the Cotopaxi andesites and rhyolites. The results suggest that Cotopaxi's most mafic andesites (last erupted products) can be stored over a large range of depth from 7 km to ≥16 km below the summit (pressure from 200 to ≥400 MPa), 1000 °C, NNO +2, and contain 4.5-6.0±0.7 wt% H2O dissolved in the melt in equilibrium with 30-40% phenocrysts of plagioclase, two pyroxenes, and Fe-Ti oxides. These mafic andesites sometimes evolve towards more silicic andesites by cooling to 950 °C. Rhyolitic magmas are stored at 200-300 MPa (i.e. 7-11 km below the summit), 750 °C, NNO +2, and contain 6-8 wt% H2O dissolved in a nearly aphyric melt (<5% phenocrysts of plagioclase, biotite, and Fe-Ti oxides). Although the andesites produce the rhyolitic magmas by fractional crystallization, the Cotopaxi eruptive history suggests reactivation of either reservoirs at distinct times, likely reflecting flux or time fluctuations during deep magma recharge.

  13. Characterization of volcanic deposits and geoarchaeological studies from the 1815 eruption of Tambora volcano

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    Igan Supriatman Sutawidjaja


    Full Text Available eruption of Tambora volcano on the island of Sumbawa in 1815 is generally considered as the largest and the most violent volcanic event in recorded history. The cataclysmic eruption occurred on 11 April 1815 was initiated by Plinian eruption type on 5 April and killed more than 90,000 people on Sumbawa and nearby Lombok. The type plinian eruptions occurred twice and ejected gray pumice and ash, to form stratified deposits as thick as 40-150 cm on the slopes and mostly distributed over the district west of the volcano. Following this, at about 7 pm, on 11 April the first pyroclastic surge was generated and progressively became greater extending to almost whole direction, mainly to the north, west, and south districts from the eruption center. The deadliest volcanic eruption buried ancient villages by pyroclastic surge and flow deposits in almost intact state, thus preserving important archaeological evidence for the period. High preservation in relatively stable conditions and known date of the eruptions provide approximate dating for the archaeological remains. Archaeological excavations on the site uncovered a variety of remains were relieved by ground penetrating radar (GPR to map structural remains of the ancient villages under the pyroclastic surge and flow deposits. These traverses showed that GPR could define structures as deep as 10 m (velocity 0.090 m/ns and could accurately map the thickness of the stratified volcanic deposits in the Tambora village area.    

  14. Combination of ozonation and photocatalysis for pharmaceutical wastewater treatment (United States)

    Ratnawati, Enjarlis, Slamet


    The chemical oxygen demand (COD) and phenol removal from pharmaceutical wastewater were investigated using configuration of two circulation batch reactors in a series with ozonation and photocatalytic processes. The ozonation is conducted with O3/granulated activated carbon (O3/GAC), whereas photocatalysis with TiO2 that immobilized on pumice stone (PS-TiO2). The effect of circulation flow rate (10; 12; 15 L/min) and the amount PS-TiO2 (200 g, 250 g, 300 g) were examined. Wastewater of 20 L was circulated pass through the pipe that injected with O3 by the ozone generator, and subsequently flow through two GAC columns, and finally, go through photoreactor that contains photocatalyst PS-TiO2 which equipped with mercury lamp as a photon source. At a time interval, COD and phenol concentration were measured to assess the performance of the process. FESEM imaging confirmed that TiO2 was successfully impregnated on PS, as corroborated by EDX spectra. Meanwhile, degradation process indicated that the combined ozonation and photocatalytic processes (O3/GAC-TiO2) is more efficient compared to the ozonation and photocatalysis alone. For combination process with the circulation flow rate of 10 L/min and 300 g of PS-TiO2,the influent COD of around 1000 ppm are effectively degraded to a final effluent COD of 290 ppm (71% removal) and initial phenol concentration of 4.75 ppm down to 0 ppm for 4 h which this condition fulfill the discharge standards quality. Therefore, this portable prototype reactor is effective that can be used in the pharmaceutical wastewater treatment. For the future, this process condition will be developed for orientation on the industrial applications (portable equipment) since pharmaceutical industries produce wastewater relatively in the small amount.

  15. The Effect of Fluid and Solid Properties on the Auxetic Behavior of Porous Materials Having Rock-like Microstructures (United States)

    Wollner, U.; Vanorio, T.; Kiss, A. M.


    Materials with a negative Poisson's Ratio (PR), known as auxetics, exhibit the counterintuitive behavior of becoming wider when uniaxially stretched and thinner when compressed. Though negative PR is characteristic of polymer foams or cellular solids, tight as well as highly porous rocks have also been reported to exhibit a negative Poisson's ratio, both from dynamic (PRd) and static measurements. We propose a novel auxetic structure based on pore-space configuration observed in rocks. First, we performed 2D and 3D imaging of a pumice and tight basalt to analyze their rock microstructure as well as similarities to natural structures of auxetic materials - e.g., cork. Based on these analyses, we developed a theoretical auxetic 3D model consisting of rotating rigid bodies having pore configurations similar to those observed in rocks. To alleviate the mechanical assumption of rotating bodies, the theoretical model was modified to include crack-like features being represented by intersecting, elliptic cylinders. We then used a 3D printer to create a physical version of the modified model, whose PRd was tested. We also numerically explored how the compressibility of fluids located in the pore-space of the modified model as well as how the elastic properties of the material from which the model is made of affect its auxetic behavior. We conclude that for a porous medium composed of a single material saturated with a single fluid (a) the more compliant the fluid is and (b) the lower the PR of the solid material, the lower the PR value of the composite material.

  16. Magmatic storage conditions, decompression rate, and incipient caldera collapse of the 1902 eruption of Santa Maria Volcano, Guatemala (United States)

    Andrews, Benjamin J.


    Phase equilibria experiments and analysis of natural pumice and phenocryst compositions indicate the 1902 Santa Maria dacite was stored at ~ 140-170 MPa and 840-850 °C prior to eruption. H2O-saturated, cold-seal experiments conducted in vessels with an intrinsic log fO2 of NNO + 1 ± 0.5 show that the natural phase assemblage (melt + plagioclase + amphibole + orthopyroxene + Fe-Ti oxides + apatite) is stable from approximately 115-140 MPa at temperatures below ~ 825 °C, to ~ 840-860 °C at 150 MPa, to > 850 and Ridolfi et al., 2010) applied to experimental samples suggest two populations of amphiboles, phenocrysts grown during the experiments and inherited xenocrysts, but the pressure-temperature conditions returned by the geothermobarometer are routinely > 50 MPa and > 50 °C greater than experimental run conditions; precise estimates of magmatic conditions based solely upon amphibole composition are likely inaccurate. The experimental results and analysis of natural crystals suggest that although the natural amphiboles likely record a broad range of magmatic conditions, only the lower bounds of that range reflect pre-eruptive storage conditions. Comparison of Santa Maria microlite abundances with decompression experiments examining other silicic systems from the literature suggests that the 1902 dacite decompressed at the rate of ~ 0.005 to 0.01 MPa/s during the eruption. Applying the decompression rate with the previously described eruption rate of approximately 2-3 × 108 kg/s (Williams and Self, 1983; Carey and Sparks, 1986) to the conduit model CONFLOW reveals that the eruption conduit was dike-like with an along-strike length > 1 km. Despite depositing ~ 20 km3 of dacite tephra (equivalent to ~ 8.5 km3 magma), the 1902 eruption did not form an obvious caldera. This work suggests that collapse of the dike-like conduit terminated the eruption, preventing full caldera collapse.

  17. Evaluation of Scotchbond Multipurpose and maleic acid as alternative methods of bonding orthodontic brackets. (United States)

    Olsen, M E; Bishara, S E; Damon, P; Jakobsen, J R


    Damage to the enamel surface during bonding and debonding of orthodontic brackets is a clinical concern. Alternative bonding methods that minimize enamel surface damage while maintaining a clinically useful bond strength is an aim of current research. The purpose of this study was to compare the effects on bond strength and bracket failure location of two adhesives (System 1+ and Scotchbond Multipurpose, 3M Dental Products Division) and two enamel conditioners (37% phosphoric acid and 10% maleic acid). Forty-eight freshly extracted human premolars were pumiced and divided into four groups of 12 teeth, and metal orthodontic brackets were attached to the enamel surface by one of four protocols: (1) System 1+ and phosphoric acid, (2) Scotchbond and phosphoric acid, (3) System 1+ and maleic acid, and (4) Scotchbond and maleic acid. After bracket attachment, the teeth were mounted in phenolic rings and stored in deionized water at 37 degrees C for 72 hours. A Zwick universal testing machine (Zwick GmbH & Co.) was used to determine shear bond strengths. The residual adhesive on the enamel surface was evaluated with the Adhesive Remnant Index. The analysis of variance was used to compare the four groups. Significance was predetermined at p adhesives on the enamel surfaces, revealed significant differences among the four groups (mean 2 = 0.005). A Duncan multiple range test revealed the difference occurred between the phosphoric acid and maleic acid groups, with maleic acid having bond failures at the enamel-adhesive interface. In conclusion, the use of Scotchbond Multipurpose and/or maleic acid does not significantly effect bond strength, however, the use of maleic acid resulted in an unfavorable bond failure location.

  18. Hydrological sensitivity of volcanically disturbed watersheds—a lesson reinforced at Pinatubo (United States)

    Major, J. J.; Janda, R. J.


    The climactic June 1991 eruption of Mount Pinatubo devastated many surrounding catchments with thick pyroclastic fall and flow deposits, and subsequent hydrogeomorphic responses were dramatic and persisted for years. But in the 24 hours preceding the climactic eruption there was less devastating eruptive activity that had more subtle, yet significant, impact on catchment hydrology. Stratigraphic relations show damaging lahars swept all major channels east of the volcano, starting late on June 14 and continuing through (and in some instances after) midday on June 15, before the climactic phase of the eruption began and before Typhoon Yunya struck the region. These early lahars were preceded by relatively small explosions and pyroclastic surges that emplaced fine-grained ash in the upper catchments, locally damaged or destroyed vegetation, reduced hillside infiltration capacity, and smoothed surface roughness. Thus the lahars, likely triggered by typical afternoon monsoon storms perhaps enhanced by local thermal influences of fresh volcanic deposits, did not result from extraordinary tropical rainfall or exceptional volcaniclastic deposition. Instead, direct rainfall-runoff volume increased substantially as a consequence of vegetation damage and moderate deposition of fine ash. Rapid runoff from hillsides to channels initiated hillside and bank erosion as well as channel scour, producing debris flows and hyperconcentrated flows. Timing of some lahars varied across catchments as well as downstream within catchments with respect to climactic pumice fall, demonstrating complex interplay among volcanic processes, variations in catchment disturbance, and rainfall timing and intensity. Occurrence of these early lahars supports the hypothesis that eruptions that deposit fine ash in volcanic catchments can instigate major hydrogeomorphic responses even when volcanic disturbances are modest—an effect that can be masked by later eruption impacts.

  19. IODP Expedition 351 Lithostratigraphy: Volcaniclastic Record of Izu-Bonin-Mariana (IBM) Arc Initiation (United States)

    Barth, A. P.; Brandl, P. A.; Li, H.; Hickey-Vargas, R.; Jiang, F.; Kanayama, K.; Kusano, Y.; Marsaglia, K. M.; McCarthy, A.; Meffre, S.; Savov, I. P.; Tepley, F. J., III; Yogodzinski, G. M.


    The destruction of lithospheric plates by subduction is a fundamentally important process leading to arc magmatism and the creation of continental crust, yet subduction initiation and early magmatic arc evolution remain poorly understood. For many arc systems, onset of arc volcanism and early evolution are obscured by metamorphism or the record is deeply buried; however, initial products of arc systems may be preserved in forearc and backarc sedimentary records. IODP Expedition 351 recovered this history from the dispersed ash and pyroclast record in the proximal rear-arc of the northern IBM system west of the Kyushu-Palau Ridge. Drilling at Site U1438 in the Amami Sankaku Basin recovered a thick volcaniclastic record of subduction initiation and the early evolution of the Izu-Bonin Arc. A 160-m thick section of Neogene sediment overlies 1.3 kilometers of Paleogene volcaniclastic rocks with andesitic average composition; this volcaniclastic section was deposited on mafic volcanic basement rocks. The thin upper sediment layer is primarily terrigenous, biogenic and volcaniclastic mud and ooze with interspersed ash layers. The underlying Eocene to Oligocene volcaniclastic rocks are 33% tuffaceous mudstone, 61% tuffaceous sandstone, and 6% conglomerate with volcanic and rare sedimentary clasts commonly up to pebble and rarely to cobble size. The clastic section is characterized by repetitive conglomerate and sandstone-dominated intervals with intervening mudstone-dominated intervals, reflecting waxing and waning of coarse arc-derived sediment inputs through time. Volcanic lithic clasts in sandstones and conglomerates range from basalt to rhyolite in composition and include well-preserved pumice, reflecting a lithologically diverse and compositionally variable arc volcanic source.

  20. The isotopic record of atmospheric lead fall-out on an Icelandic salt marsh since AD 50

    International Nuclear Information System (INIS)

    Marshall, William A.; Clough, Robert; Gehrels, W. Roland


    We report a record of atmospheric Pb deposition at a coastal site in western Iceland that spans the last two millennia. The elemental concentrations of Pb, Al, Li and Ti are determined using ICP-MS from a sediment monolith collected from a salt marsh. Multicollector (MC) ICP-MS analysis is used to obtain isotopic ratios of stable Pb. The Pb/Ti and Pb/Li ratios are used to separate natural Pb background concentrations from Pb derived from remote anthropogenic sources. The pollution record in western Iceland is subdued in comparison with Pb records from the European mainland, but the isotopic character, profile and timing of Pb deposition show good agreement with the atmospheric Pb fall-out reported from sites in Scandinavia and northwestern Europe. At the bottom of the sequence we isolate a low-level (0.1-0.4 mg kg -1 ) Pb enrichment signal dated to AD 50-150. The isotopic signature and timing of this signal suggest Roman metal working industries as the source. In the subsequent millennium there was no significant or very low (i.e. elemental concentrations -1 ) anthropogenic Pb deposition at the site up to, and including, the early Medieval period. Above a pumice layer, dated to AD 1226-1227, a small increase in Pb deposition is found. This trend is maintained until a more substantive and progressive increase is signalled during the late 1700s and early 1800s. This is followed by a substantial enrichment signal in the sediments (> 3.0 mg kg -1 ) that is interpreted as derived from industrial coal burning and metal working during the 19th and 20th centuries in northern Europe. During the late 20th century, significant fall-out from European fuel additives reached Iceland

  1. Effect of type of cavity preparation (bur,Er:YAG laser and restorative materials on prevention of caries lesion

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    Masumeh Hasani Tabatabaei


    Full Text Available Background and Aims: Despite the reduction of incidence of dental caries in recent years, this disease is common and many efforts were conducted to decrease the prevalence of dental caries. On the other hand secondary caries lesions are the main reason for replacement of direct restorations. Therefore, the aim of the current study was to evaluate suitable methods of preparation and restorative materials to reduce caries recurrence. Materials and Methods: In this experimental study, eighty human teeth were collected and stored in normal saline. The teeth were soft-tissue debrided and cleaned with water/pumice slurry and rubber cups in a low-speed handpiece. Speciments were randomly divided in two main groups. Cavities were prepared with diamond burs or Er:YAG laser (10 Hz, 300 mJ, 3W. Each group was divided into 4 sub-groups, and restored with a glass-ionomer cement (Fuji IX, resin modified glass-ionomer (Fuji II LC, total etch bonding + composite resin or self-etch bonding + composite resin. The specimens were submitted to pH cycling. Speciments were then sectioned, polished and Vickers microhardness measurements were performed on each specimen. Differences among the medians were analyzed using two way ANOVA test at a 95% confidence level and Tukey test. Results: Statistical analysis showed significant difference in the type of substrate (enamel, dentin in both main groups (P<0.0001 but no differences in the caries lesion development between the cavities restored with the same material and prepared with diamond burs or Er:YAG laser. Conclusion: The Er:YAG laser used for cavity preparation and different types of restorative materials used did not show the ability to guarantee significantly more acid-resistance tooth structure against demineralization.

  2. New 1.5 million-year-old Homo erectus maxilla from Sangiran (Central Java, Indonesia). (United States)

    Zaim, Yahdi; Ciochon, Russell L; Polanski, Joshua M; Grine, Frederick E; Bettis, E Arthur; Rizal, Yan; Franciscus, Robert G; Larick, Roy R; Heizler, Matthew; Aswan; Eaves, K Lindsay; Marsh, Hannah E


    Sangiran (Solo Basin, Central Java, Indonesia) is the singular Homo erectus fossil locale for Early Pleistocene Southeast Asia. Sangiran is the source for more than 80 specimens in deposits with (40)Ar/(39)Ar ages of 1.51-0.9 Ma. In April 2001, we recovered a H. erectus left maxilla fragment (preserving P(3)- M(2)) from the Sangiran site of Bapang. The find spot lies at the base of the Bapang Formation type section in cemented gravelly sands traditionally called the Grenzbank Zone. Two meters above the find spot, pumice hornblende has produced an (40)Ar/(39)Ar age of 1.51 ± 0.08 Ma. With the addition of Bpg 2001.04, Sangiran now has five H. erectus maxillae. We compare the new maxilla with homologs representing Sangiran H. erectus, Zhoukoudian H. erectus, Western H. erectus (pooled African and Georgian specimens), and Homo habilis. Greatest contrast is with the Zhoukoudian maxillae, which appear to exhibit a derived pattern of premolar-molar relationships compared to Western and Sangiran H. erectus. The dental patterns suggest distinct demic origins for the earlier H. erectus populations represented at Sangiran and the later population represented at Zhoukoudian. These two east Asian populations, separated by 5000 km and nearly 800 k.yr., may have had separate origins from different African/west Eurasian populations. Copyright © 2011 Elsevier Ltd. All rights reserved.

  3. Contrasting patterns of vesiculation in low, intermediate, and high Hawaiian fountains: A case study of the 1969 Mauna Ulu eruption (United States)

    Parcheta, Carolyn E.; Houghton, Bruce F.; Swanson, Donald A.


    Hawaiian-style eruptions, or Hawaiian fountains, typically occur at basaltic volcanoes and are sustained, weakly explosive jets of gas and dominantly coarse, juvenile ejecta (dense spatter to delicate reticulite). Almost the entire range of styles and mass eruption rates within Hawaiian fountaining occurred during twelve fountaining episodes recorded at Mauna Ulu, Kīlauea between May and December 1969. Such diversity in intensity and style is controlled during magma ascent by many processes that can be constrained by the size and shape of vesicles in the 1969 pyroclasts. This paper describes pyroclast vesicularity from high, intermediate, and low fountaining episodes with eruption rates from 0.05 to 1.3 × 106 m3 h− 1. As each eruptive episode progressed, magma ascent slowed in and around the vent system, offering extended time for bubbles to grow and coalesce. Late ejected pyroclasts are thus characterized by populations of fewer and larger vesicles with relaxed shapes. This progression continued in the intervals between episodes after termination of fountain activity. The time scale for this process of shallow growth, coalescence and relaxation of bubbles is typically tens of hours. Rims and cores of pumiceous pyroclasts from moderate to high fountaining episodes record a second post-fragmentation form of vesicle maturation. Partially thermally insulated pyroclasts can have internal bubble populations evolve more dynamically with continued growth and coalescence, on a time scale of only minutes, during transport in the fountains. Reticulite, which formed in a short-lived fountain 540 m in height, underwent late, short-lived bubble nucleation followed by rapid growth of a uniform bubble population in a thermally insulated fountain, and quenched at the onset of permeability before significant coalescence. These contrasting patterns of shallow degassing and outgassing were the dominant controls in determining both the form and duration of fountaining

  4. Tulelake, California: The last 3 million years (United States)

    Adam, D.P.; Sarna-Wojcicki, A. M.; Rieck, Hugh J.; Bradbury, J.P.; Dean, W.E.; Forester, R.M.


    The Tulelake basin, formed by east-west extension and faulting during the past several million years, contains at least 550 m of lacustrine sediment. Interdisciplinary studies of a 334 m-long cored section from the town of Tulelake, California, near the center of the basin, document a 3-m.y. record of environmental changes. The core consists of a thick sequence of diatomaceous clayey, silty, and marly lacustrine sediments interbedded with numerous tephra layers. Paleomagnetic study puts the base of the core at about 3.0 Ma. Twelve widespread silicic tephra units provide correlations with other areas and complement age control provided by magnetostratigraphy; mafic and silicic tephra units erupted from local sources are also common in the core. Widespread tephra units include the Llao Rock pumice (=Tsoyawata, 7 ka), the Trego Hot Springs Bed (23 ka), and the Rockland (0.40 Ma), Lava Creek (0.62 Ma), and Rio Dell (1.5 Ma) ash beds, as well as several ash beds also found at Summer Lake, Oregon, and an ash bed originally recognized in DSDP hole 173 in the northeastern Pacific. Several tephra layers found in the core also occur in lacustrine beds exposed around the margins of the basin and elsewhere in the ancestral lacustrine system. Diatoms are present throughout the section. Pollen is present in most of the section, but some barren zones are found in the interval between 50 and 140 m; the greatest change in behavior of the pollen record takes place just above the top of the Olduvai Normal-Polarity Subchronozone. Ostracodes are present only in high-carbonate (>10% CaCO3) intervals. Evolutionary changes are found in the diatom and ostracode records. Bulk geochemical analyses show significant changes in elemental composition of the sediment through time. ?? 1989.

  5. Experimental interaction of magma and “dirty” coolants (United States)

    Schipper, C. Ian; White, James D. L.; Zimanowski, Bernd; Büttner, Ralf; Sonder, Ingo; Schmid, Andrea


    The presence of water at volcanic vents can have dramatic effects on fragmentation and eruption dynamics, but little is known about how the presence of particulate matter in external water will further alter eruptions. Volcanic edifices are inherently “dirty” places, where particulate matter of multiple origins and grainsizes typically abounds. We present the results of experiments designed to simulate non-explosive interactions between molten basalt and various “coolants,” ranging from homogeneous suspensions of 0 to 30 mass% bentonite clay in pure water, to heterogeneous and/or stratified suspensions including bentonite, sand, synthetic glass beads and/or naturally-sorted pumice. Four types of data are used to characterise the interactions: (1) visual/video observations; (2) grainsize and morphology of resulting particles; (3) heat-transfer data from a network of eight thermocouples; and (4) acoustic data from three force sensors. In homogeneous coolants with ~20% sediment, heat transfer is by forced convection and conduction, and thermal granulation is less efficient, resulting in fewer blocky particles, larger grainsizes, and weaker acoustic signals. Many particles are droplet-shaped or/and “vesicular,” containing bubbles filled with coolant. Both of these particle types indicate significant hydrodynamic magma-coolant mingling, and many of them are rewelded into compound particles. The addition of coarse material to heterogeneous suspensions further slows heat transfer thus reducing thermal granulation, and variable interlocking of large particles prevents efficient hydrodynamic mingling. This results primarily in rewelded melt piles and inefficient distribution of melt and heat throughout the coolant volume. Our results indicate that even modest concentrations of sediment in water will significantly limit heat transfer during non-explosive magma-water interactions. At high concentrations, the dramatic reduction in cooling efficiency and increase in

  6. Isotope geochemistry of recent magmatism in the Aegean arc: Sr, Nd, Hf, and O isotopic ratios in the lavas of Milos and Santorini-geodynamic implications (United States)

    Briqueu, L.; Javoy, M.; Lancelot, J.R.; Tatsumoto, M.


    In this comparative study of variations in the isotopic compositions (Sr, Nd, O and Hf) of the calc-alkaline magmas of the largest two volcanoes, Milos and Santorini, of the Aegean arc (eastern Mediterranean) we demonstrate the complexity of the processes governing the evolution of the magmas on the scale both of the arc and of each volcano. On Santorini, the crustal contamination processes have been limited, effecting the magma gradually during its differentiation. The most differentiated lavas (rhyodacite and pumice) are also the most contaminated. On Milos, by contrast, these processes are very extensive. They are expressed in the 143Nd/144Nd vs. 87Sr/86Sr diagram as a continuous mixing curve between a mantle and a crustal end member pole defined by schists and metavolcanic rocks outcropping on these volcanoes. In contrast with Santorini, the least differentiated lavas on Milos are the most contaminated. These isotopic singularities can be correlated with the geodynamic evolution of the Aegean subduction zone, consisting of alternating tectonic phases of distension and compression. The genesis of rhyolitic magmas can be linked to the two phases of distension, and the contamination of the calc-alkaline mantle-derived magmas with the intermediate compressive phase. The isotopic characteristics of uncontaminated calc-alkaline primitive magmas of Milos and Santorini are directly comparable to those of magmas generated in subduction zones for which a contribution of subducted sediments to partial melts from the mantle is suggested, such as in the Aleutian, Sunda, and lesser Antilles island arcs. However, in spite of the importance of the sediment pile in the eastern Mediterranen oceanic crust (6-10 km), the contribution of the subducted terrigenous materials remains of limited amplitude. ?? 1986.


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    Three wells, PB-1, PB-2, and PB-3, were drilled in 2003 at the Nopal I uranium deposit as part of a natural analogue study to evaluate radionuclide transport processes. The wells penetrate through the Tertiary volcanic section down to the Cretaceous limestone basement, and intersect the top of the regional aquifer system. The PB-1 well, drilled immediately adjacent to the Nopal I ore body, was cored to a depth of 250 m, thus providing an opportunity to document the local stratigraphy. The uppermost unit encountered in the PB-1 well is the Nopal Formation, a densely welded, crystal-rich rhyolitic ash-flow tuff. The cored section is highly altered and devitrified, with kaolinite, quartz, chlorite, and montmorillonite replacing feldspars and much of the groundmass. Breccia zones within the tuff contain fracture fillings of hematite, limonite, and goethite. A zone of intense clay alteration encountered in the depth interval 17.45-22.30 m was interpreted to represent the basal vitrophyre of this unit. Underlying the basal vitrophyre is the Coloradas Formation, which consists of a welded, lithic-rich rhyolitic ash-flow tuff. The cored section of this unit has undergone devitrification and oxidation, and has a similar alteration mineralogy to that observed in the Nopal tuff. The Nopal I ore body is restricted to a brecciated zone that intersects these two volcanic units. A sharp contact between the Coloradas tuff and the underlying Pozos Formation was observed at a depth of 136.38 m. The Pozos Formation in the PB-1 core consists of interbedded, poorly sorted sandstone and conglomerate layers. The conglomeratic clasts consist of subangular to subrounded fragments of volcanic rocks, limestone, and chert. Thin (2-6 m) intervals of intercalated pumiceous tuffs were observed within this unit. The contact between the Pozos Formation and the underlying Cretaceous limestone basement was observed at a depth of 244.4 m.

  8. Infection control knowledge and practice: A cross-sectional survey on dental laboratories in dental institutes of North India. (United States)

    Gupta, Sakshi; Rani, Sapna; Garg, Sandeep


    The aim of the study was to assess the knowledge of dental laboratory technicians regarding infection control and modes of infection control employed by them. A self-assessment questionnaire-based survey was carried out among dental technicians to assess the knowledge and practice of infection control in dental laboratories. Survey instrument containing 16 questions were randomly distributed to 70 dental colleges of North India regarding knowledge of infection control methods and infection control practised in laboratories. Data were collected and analyzed. The response showed that 30.76% of dental technicians receive 30-50 or more than 50 impressions in a week. About 96.15% of the technicians used a plastic bag to carry impressions. Twenty-five percent of the dental technicians were aware of infection control protocol. Fifty-five percent of the technicians received impressions while wearing gloves and 61.53% of the institutes had a separate receiving area. Nearly 71.15% of the technicians communicate with the doctor regarding the disinfection of impression received in the laboratory. Almost 30.76% of the dental technicians disinfect all the impressions and 67.30% technicians use immersion for disinfection of impressions. Only 38.46% responded that they immerse impressions for 10 min for disinfection. About 73.07% use gloves, 90.38% use mouth masks, 57.69% wear eye shields, and 88.46% wear aprons while working. Nearly 78.84% of the technicians received vaccination against hepatitis B virus. Almost 69.23% of the technicians change pumice slurry after regular intervals, and 75% do not add any disinfectant. Nearly 59.61% of technicians disinfect the prostheses before sending it to the clinic, and 42.30% disinfect them by immersion technique. About disposal of waste, 80.76% said that they dispose the waste properly. To summarize, most of the technicians were not aware of basic infection control protocols.

  9. Xenopumice erupted on 15 October 2011 offshore of El Hierro (Canary Islands): a subvolcanic snapshot of magmatic, hydrothermal and pyrometamorphic processes (United States)

    Del Moro, S.; Di Roberto, A.; Meletlidis, S.; Pompilio, M.; Bertagnini, A.; Agostini, S.; Ridolfi, F.; Renzulli, A.


    On 15 October 2011, a submarine eruption offshore of El Hierro Island gave rise to floating volcanic products, known as xenopumices, i.e., pumiceous xenoliths partly mingled and coated with the juvenile basanitic magma. Over the last few years, no consensus in the scientific community in explaining the origin of these products has been reached. In order to better understand the formation of xenopumice, we present a textural, mineralogical, and geochemical study of the possible magmatic, hydrothermal, and pyrometamorphic processes, which usually operate in the plumbing systems of active volcanoes. We carried out a comprehensive SEM investigation and Sr-Nd-Pb isotope analyses on some samples representative of three different xenopumice facies. All the data were compared with previous studies, new data for El Hierro extrusives and a literature dataset of Canary Islands igneous and sedimentary rocks. In the investigated xenopumices, we emphasize the presence of restitic magmatic phases as well as crystallization of minerals (mainly olivine + pyroxene + magnetite aggregates) as pseudomorphs after pre-existing mafic phenocrysts, providing evidence of pyrometamorphism induced by the high-T juvenile basanitic magma. In addition, we identify veins consisting of zircon + REE-oxides + mullite associated with Si-rich glass and hydrothermal quartz, which indicate the fundamental role played by hydrothermal fluid circulation in the xenopumice protolith. The petrological data agree with a pre-syneruptive formation of the xenopumice, when El Hierro basanite magma intruded hydrothermally altered trachyandesite to trachyte rocks and triggered local partial melting. Therefore, the El Hierro xenopumice represents a snapshot of the transient processes at the magma-wall rock interface, which normally occurs in the feeding system of active volcanoes.

  10. Habitat template approach for green roofs using a native rocky sea coast plant community in Japan. (United States)

    Nagase, Ayako; Tashiro-Ishii, Yurika


    The present study examined whether it is possible to simulate a local herbaceous coastal plant community on a roof, by studying the natural habitats of rocky sea coast plants and their propagation and performance on a green roof. After studying the natural habitat of coastal areas in Izu peninsula, a germination and cutting transplant study was carried out using herbaceous plants from the Jogasaki sea coast. Many plant species did not germinate at all and the use of cuttings was a better method than direct seeding. The green roof was installed in the spring of 2012 in Chiba city. Thirteen plant species from the Jogasaki sea coast, which were successfully propagated, were planted in three kinds of substrate (15 cm depth): pumice, roof tile and commercial green roof substrate. The water drainage was restricted and a reservoir with 5 cm depth of water underlaid the substrate to simulate a similar growing environment to the sea coast. Volcanic rocks were placed as mulch to create a landscape similar to that on the Jogasaki sea coast. Plant coverage on the green roof was measured every month from June 2012 to October 2014. All plants were harvested and their dry shoot weight was measured in December 2014. The type of substrate did not cause significant differences in plant survival and dry shoot weight. Sea coast plant species were divided into four categories: vigorous growth; seasonal change; disappearing after a few years; limited growth. Understanding the ecology of natural habitats was important to simulating a local landscape using native plant communities on the green roof. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Infection control practice in private dental laboratories in Riyadh

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    AlKheraif, Abdulaziz A; Mobarak, Fahmy A


    In view of the risk of infection of dental health care workers and patients, interruption of possible chains of infection is to be demanded. The objective of this study was to assess infection control practice in private dental laboratories in Riyadh City, Kingdom of Saudi Arabia. The study was conducted on thirty-two private dental laboratories in Riyadh City regarding infection control practiced by these laboratories. The instrument of the study consisted of ten open-ended questions that were asked from the laboratories directors. A large percentage of the surveyed laboratories (87.5 %) did not implement any infection control protocol during their practice. The mean number of impressions received per week was 16. Most of the surveyed laboratories (90.6 %) had no way of communication with the clinics regarding the disinfection procedures. The results indicated that 62.5 % of the laboratories reported that they were aware that they may get infection from non-disinfected items. Only a small percentage (6.2%) of the laboratories added disinfecting agent to pumice slurry. Wearing laboratory coats was reported by 75% of the laboratory workers. The use of gloves during work was reported by 59.3% of the laboratories while 56.2% reported the use protective eyewear. Only 21.8% of the laboratories use face masks during work. Construction of infection control manuals that contain updated and recommended guidelines to ensure aseptic practice in private dental laboratories is highly recommended. Also, a way of communication between dentists and dental technicians regarding disinfection of laboratory items should be strongly encouraged. (author)

  12. Resolving the age of Wilson Creek Formation tephras and the Mono Lake excursion using high-resolution SIMS dating of allanite and zircon rims (United States)

    Vazquez, J. A.; Lidzbarski, M. I.


    Sediments of the Wilson Creek Formation surrounding Mono Lake preserve a high-resolution archive of glacial and pluvial responses along the eastern Sierra Nevada due to late Pleistocene climate change. An absolute chronology for the Wilson Creek stratigraphy is critical for correlating the paleoclimate record to other archives in the western U.S. and the North Atlantic region. However, multiple attempts to date the Wilson Creek stratigraphy using carbonates and interbedded rhyolitic tephras yield discordant 14C and 40Ar/39Ar results due to open-system effects, carbon reservoir uncertainties, as well as abundant xenocrysts entrained during eruption. Ion microprobe (SIMS) 238U-230Th dating of the final increments of crystallization recorded by allanite and zircon autocrysts from juvenile pyroclasts yields ages that effectively date eruption of key tephra beds and resolve age uncertainties about the Wilson Creek stratigraphy. To date the final several micrometers of crystal growth, individual allanite and zircon crystals were embedded in soft indium to allow sampling of unpolished rims. Isochron ages derived from rims on coexisting allanite and zircon (± glass) from hand-selected pumiceous pyroclasts delimit the timing of Wilson Creek sedimentation between Ashes 7 and 19 (numbering of Lajoie, 1968) to the interval between ca. 27 to ca. 62 ka. The interiors of individual allanite and zircon crystals sectioned in standard SIMS mounts yield model 238U-230Th ages that are mostly hydrologic responses in the Sierra Nevada and Mono Basin to climate change, with intervals of lake filling and glacial-snowpack melting that are in phase with peaks in spring insolation. Moreover, the results demonstrate that high-spatial resolution SIMS dating of accessory mineral rims is an alternative and promising approach for resolving the depositional ages of silicic tephras containing minerals that crystallized over protracted intervals or that are plagued by incorporation of xenocrysts

  13. Neogene fallout tuffs from the Yellowstone hotspot in the Columbia Plateau region, Oregon, Washington and Idaho, USA.

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    Barbara P Nash

    Full Text Available Sedimentary sequences in the Columbia Plateau region of the Pacific Northwest ranging in age from 16-4 Ma contain fallout tuffs whose origins lie in volcanic centers of the Yellowstone hotspot in northwestern Nevada, eastern Oregon and the Snake River Plain in Idaho. Silicic volcanism began in the region contemporaneously with early eruptions of the Columbia River Basalt Group (CRBG, and the abundance of widespread fallout tuffs provides the opportunity to establish a tephrostratigrahic framework for the region. Sedimentary basins with volcaniclastic deposits also contain diverse assemblages of fauna and flora that were preserved during the Mid-Miocene Climatic Optimum, including Sucker Creek, Mascall, Latah, Virgin Valley and Trout Creek. Correlation of ashfall units establish that the lower Bully Creek Formation in eastern Oregon is contemporaneous with the Virgin Valley Formation, the Sucker Creek Formation, Oregon and Idaho, Trout Creek Formation, Oregon, and the Latah Formation in the Clearwater Embayment in Washington and Idaho. In addition, it can be established that the Trout Creek flora are younger than the Mascall and Latah flora. A tentative correlation of a fallout tuff from the Clarkia fossil beds, Idaho, with a pumice bed in the Bully Creek Formation places the remarkably well preserved Clarkia flora assemblage between the Mascall and Trout Creek flora. Large-volume supereruptions that originated between 11.8 and 10.1 Ma from the Bruneau-Jarbidge and Twin Falls volcanic centers of the Yellowstone hotspot in the central Snake River Plain deposited voluminous fallout tuffs in the Ellensberg Formation which forms sedimentary interbeds in the CRBG. These occurrences extend the known distribution of these fallout tuffs 500 km to the northwest of their source in the Snake River Plain. Heretofore, the distal products of these large eruptions had only been recognized to the east of their sources in the High Plains of Nebraska and Kansas.

  14. Numerical Simulations Of Catastrophic Disruption Of Porous Bodies: Application To Dark-type Asteroids And Kuiper-belt Family Formation (United States)

    Michel, Patrick; Jutzi, M.; Richardson, D. C.; Benz, W.


    Asteroids of dark (e.g. C, D) taxonomic classes as well as Kuiper Belt objects and comets are believed to have high porosity, not only in the form of large voids but also in the form of micro-pores. The presence of such microscale porosity introduces additional physics in the impact process. We have enhanced our 3D SPH hydrocode, used to simulate catastrophic breakups, with a model of porosity [1] and validated it at small scale by comparison with impact experiments on pumice targets [2]. Our model is now ready to be applied to a large range of problems. In particular, accounting for the gravitational phase of an impact, we can study the formation of dark-type asteroid families, such as Veritas, and Kuiper-Belt families, such as Haumea. Recently we characterized for the first time the catastrophic impact energy threshold, usually called Q*D, as a function of the target's diameter, porosity, material strength and impact speed [3]. Regarding the mentioned families, our preliminary results show that accounting for porosity leads to different outcomes that may better represent their properties and constrain their definition. In particular, for Veritas, we find that its membership may need some revision [4]. The parameter space is still large, many interesting families need to be investigated and our model will be applied to a large range of cases. PM, MJ and DCR acknowledge financial support from the French Programme National de Planétologie, NASA PG&G "Small Bodies and Planetary Collisions" and NASA under Grant No. NNX08AM39G issued through the Office of Space Science, respectively. [1] Jutzi et al. 2008. Icarus 198, 242-255; [2] Jutzi et al. 2009. Icarus 201, 802-813; [3] Jutzi et al. 2010. Fragment properties at the catastrophic disruption threshold: The effect of the parent body's internal structure, Icarus 207, 54-65; [4] Michel et al. 2010. Icarus, submitted.

  15. Paleointensity in ignimbrites and other volcaniclastic flows (United States)

    Bowles, J. A.; Gee, J. S.; Jackson, M. J.


    Ash flow tuffs (ignimbrites) are common worldwide, frequently contain fine-grained magnetite hosted in the glassy matrix, and often have high-quality 40Ar/39Ar ages. This makes them attractive candidates for paleointensity studies, potentially allowing for a substantial increase in the number of well-dated paleointensity estimates. However, the timing and nature of remanence acquisition in ignimbrites are not sufficiently understood to allow confident interpretation of paleointensity data from ash flows. The remanence acquisition may be a complex function of mineralogy and thermal history. Emplacement conditions and post-emplacement processes vary considerably between and within tuffs and may potentially affect the ability to recover ancient field intensity information. To better understand the relevant magnetic recording assemblage(s) and remanence acquisition processes we have collected samples from two well-documented historical ignimbrites, the 1980 ash flows at Mt. St. Helens (MSH), Washington, and the 1912 flows from Mt. Katmai in the Valley of Ten Thousand Smokes (VTTS), Alaska. Data from these relatively small, poorly- to non-welded historical flows are compared to the more extensive and more densely welded 0.76 Ma Bishop Tuff. This sample set enables us to better understand the geologic processes that destroy or preserve paleointensity information so that samples from ancient tuffs may be selected with care. Thellier-type paleointensity experiments carried out on pumice blocks sampled from the MSH flows resulted in a paleointensity of 55.8 μT +/- 0.8 (1 standard error). This compares favorably with the actual value of 56.0 μT. Excluded specimens of poor technical quality were dominantly from sites that were either emplaced at low temperature (600°C) temperatures does not corrupt the paleointensity signal, and additional data will be presented which explores this more fully.

  16. The Tala Tuff, La Primavera caldera Mexico. Pre-eruptive conditions and magma processes before eruption (United States)

    Sosa-Ceballos, G.


    La Primavera caldera, Jalisco Mexico, is a Pleistocenic volcanic structure formed by dome complexes and multiple pyroclastic flows and fall deposits. It is located at the intersection of the Chapala, Colima, and Tepic grabens in western Mexico. The first volcanic activity associated to La Primavera started ~0.1 Ma with the emission of pre-caldera lavas. The caldera collapse occurred 95 ka and is associated to the eruption of ~20 km3of pumice flows known as the Tala tuff (Mahood 1980). The border of the caldera was replaced by a series of domes dated in 75-30 ky, which partially filled the inner depression of the caldera with pyroclastic flows and falls. For more than a decade the Federal Commission of Electricity in Mexico (CFE) has prospected and evaluated the geothermal potential of the Cerritos Colorados project at La Primavera caldera. In order to better understand the plumbing system that tapped the Tala tuff and to investigate its relation with the potential geothermal field at La Primavera we performed a series of hydrothermal experiments and studied melt inclusions hosted in quartz phenocrysts by Fourier Infra red stectroscopy (FTIR). Although some post caldera products at La Primavera contain fayalite and quartz (suggesting QFM conditions) the Tala tuff does not contain fayalite and we ran experiments under NNO conditions. The absence of titanomagnetite does not allowed us to calculate pre-eruptive temperature. However, the stability of quartz and plagioclase, which are natural phases, suggest that temperature should be less than 750 °C at a pressure of 200 MPa. The analyses of H2O and CO2 dissolved in melt inclusions yielded concentrations of 2-5 wt.% and 50-100 ppm respectively. This data confirm that the pre-eruptive pressure of the Tala tuff is ~200 MPa and in addition to major elements compositions suggest that the Tala tuff is either, compositionally zoned or mixed with other magma just prior to eruption.

  17. Tocuila Mammoths, Basin of Mexico: Late Pleistocene-Early Holocene stratigraphy and the geological context of the bone accumulation (United States)

    Gonzalez, Silvia; Huddart, David; Israde-Alcántara, Isabel; Dominguez-Vazquez, Gabriela; Bischoff, James


    We report new stratigraphic, tephrochronology and dating results from the Tocuila Mammoth site in the Basin of Mexico. At the site there is evidence for a thin meteorite airburst layer dated between 10,878 and 10,707 cal BC at the onset of the Younger Dryas (YD) cool period. The Upper Toluca Pumice (UTP) tephra marker, caused by a Plinian eruption of the Nevado de Toluca volcano, dated from 10,666 to 10,612 cal BC, is above that layer. The eruption must have caused widespread environmental disruption in the region with evidence of extensive reworking and channelling by the Lake Texcoco shoreline and contributed to the widespread death and/or extinction of megafaunal populations, as suggested by earlier authors, but the new work reinforces the view that both catastrophic events must have caused large environmental disruption in a short time period of around two hundred years. There is no evidence for megafauna (mammoths, sabre toothed cats, camels, bison, glyptodonts) after the UTP volcanic event and subsequent lahars in the Basin of Mexico. At Tocuila, although there are some in situ tephra markers in nearshore lake sediments, such as the Great Basaltic Ash (GBA) and the UTP Ash, there is evidence of much reworking of several tephra populations in various combinations. The mammoth bone accumulation is reworked in a lahar sequence (volcanic mudflow) derived from several source sediments but associated with the major UTP Plinian eruption. Paleoindian populations were also present in the Basin of Mexico during the YD period, where several Paleoindian skeletons were found associated with the UTP ash deposits, e.g. Metro Man, Chimalhuacan Man and Tlapacoya Man.

  18. Geochemical Characterization of Late Pleistocene and Holocene Tephra Layers from the Basin of Mexico, Central Mexico (United States)

    Ortega-Guerrero, Beatriz; Newton, Anthony J.


    In order to aid palaeoenvironmental research of Late Pleistocene and Holocene deposits of central Mexico, tephra layers collected from the sediments of the Texcoco and Chalco sub-basins, in the southern part of the Basin of Mexico, are geochemically characterized and used as stratigraphic markers. The tephra layers range in composition from basaltic andesites to rhyolites and are calc-alkaline. The tephras range in age from >34,000 to ca. 2600 14C yr B.P. New names are used informally to designate correlated tephras. The Tlahuac tephra is present in Chalco, at a depth of 18 m; in the southeastern part of Texcoco, at a depth of around 10 m; and at the Tlapacoya archaeological site, where it had been mistakenly described as basaltic. This basalt-andesite tephra is dated to at least 34,000 14C yr B.P. The Tlapacoya 1 tephra is dated to between 15,020 ± 450 and 14,430 ± 190 yr B.P. and is present in all Chalco sections. The Tlapacoya 2 tephra corresponds to the previously described "pomez gruesa con fragmentos de andesita" (ca. 14,400 yr B.P.) and is present in all Chalco and Texcoco sections. The likely source of these three tephras is the volcano Popocatepetl. Tephra II at Chalco dates to 12,520 ± 135 yr B.P. and correlates with the Upper Toluca Pumice from Nevado de Toluca volcano. These represent the first geochemical glass-shard analysis of tephras from the Basin of Mexico, and so further research is necessary before a reliable tephrochronology can be established.

  19. Floating sandstones off El Hierro (Canary Islands, Spain): the peculiar case of the October 2011 eruption (United States)

    Troll, V. R.; Klügel, A.; Longpré, M.-A.; Burchardt, S.; Deegan, F. M.; Carracedo, J. C.; Wiesmaier, S.; Kueppers, U.; Dahren, B.; Blythe, L. S.; Hansteen, T.; Freda, C.; Budd, D. A.; Jolis, E. M.; Jonsson, E.; Meade, F.; Berg, S.; Mancini, L.; Polacci, M.


    The eruption that started off the south coast of El Hierro, Canary Islands, in October 2011 has emitted intriguing eruption products found floating in the sea. These specimens appeared as floating volcanic "bombs" that have in the meantime been termed "restingolites" (after the close-by village of La Restinga) and exhibit cores of white and porous pumice-like material. Currently the nature and origin of these "floating stones" is vigorously debated among researchers, with important implications for the interpretation of the hazard potential of the ongoing eruption. The "restingolites" have been proposed to be either (i) juvenile high-silica magma (e.g. rhyolite), (ii) remelted magmatic material (trachyte), (iii) altered volcanic rock, or (iv) reheated hyaloclastites or zeolite from the submarine slopes of El Hierro. Here, we provide evidence that supports yet a different conclusion. We have collected and analysed the structure and composition of samples and compared the results to previous work on similar rocks found in the archipelago. Based on their high silica content, the lack of igneous trace element signatures, and the presence of remnant quartz crystals, jasper fragments and carbonate relicts, we conclude that "restingolites" are in fact xenoliths from pre-island sedimentary rocks that were picked up and heated by the ascending magma causing them to partially melt and vesiculate. They hence represent messengers from depth that help us to understand the interaction between ascending magma and crustal lithologies in the Canary Islands as well as in similar Atlantic islands that rest on sediment/covered ocean crust (e.g. Cape Verdes, Azores). The occurrence of these "restingolites" does therefore not indicate the presence of an explosive high-silica magma that is involved in the ongoing eruption.

  20. Biodegradation of formaldehyde from contaminated air using a laboratory scale static-bed bioreactor

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    Yaghoub Hajizadeh


    Full Text Available Aims: The objective of the present study was to evaluate the performance of an aerobic fixed-bed bioreactor (FBR enriched with microorganisms of sewage sludge in biodegradation of formaldehyde in air stream with various retention times and airflow rates in laboratory scale. Materials and Methods: An aerobic biofilter 60 cm in height and 14 cm internal diameter made of steel was constructed and packed with a mixture of pumice and compost as a medium and utilized in this study. The microorganism′s growth, which is derived from the sludge of a municipal wastewater treatment plant, was initiated by adding nutrient. During the first few days of run, the airflow containing different concentrations of formaldehyde (from 24 ± 3 to 224 ± 5 mg/m 3 was introduced to the reactor to ensure biological adaptation. Sampling was performed through a series of two impingers containing adsorbent, and analyzed by chromotropic acid assay using DR-5000. Results: The maximum removal and elimination capacity of formaldehyde was yielded at 0.48 ± 0.06 g/m 3 /h inlet loading rate and 180 s of empty bed retention time (EBRT. These values for stabilized days were almost 88% and 0.42 g/m 3 /h, respectively. Conclusion: The results showed that by increasing the inlet concentration of formaldehyde and reducing the EBRT, the formaldehyde removal capacity of the system decreases. Aerobic bioreactor with appropriate bed volume and compatible with inlet pollutant mass flow rate in optimum retention time will admissibly degrade and reduce the formaldehyde concentration from contaminated gas phase, such as gases produced in municipal wastewater treatment facilities.

  1. The effectiveness of educational practice in diabetic foot: a view from Brazil

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    Anselmo Maria I


    Full Text Available Abstract Background The aim of the present study was to evaluate the prevention and self-inspection behavior of diabetic subjects with foot at ulcer risk, no previous episode, who participated in the routine visits and standardized education provided by the service and who received prescribed footwear. This evaluation was carried out using a questionnaire scoring from 0-10 (high scores reflect worse practice compliance. Results 60 patients were studied (30 of each sex; mean age was 62 years, mean duration of the disease was 17 years. As for compliance, 90% showed a total score ≤5, only 8.7% regularly wore the footwear supplied; self foot inspection 65%, 28,3% with additional familiar inspection; creaming 77%; proper washing and drying 88%; proper cutting of toe nails 83%; no cuticle cutting 83%; routine shoe inspection 77%; no use of pumice stones or similar abrasive 70%; no barefoot walking 95%. Conclusion the planned and multidisciplinary educational approach enabled high compliance of the ulcer prevention care needed in diabetic patients at risk for complications. In contrast, compliance observed for the use of footwear provided was extremely low, demonstrating that the issue of its acceptability should be further and carefully addressed. In countries of such vast dimensions as Brazil multidisciplinary educational approaches can and should be performed by the services providing care for patients with foot at risk for complications according to the reality of local scenarios. Furthermore, every educational program should assess the learning, results obtained and efficacy in the target population by use of an adequate evaluation system.

  2. Unsaturated Groundwater Flow Beneath Upper Mortandad Canyon, Los Alamos, New Mexico

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    Dander, David Carl [Univ. of Arizona, Tucson, AZ (United States)


    Mortandad Canyon is a discharge site for treated industrial effluents containing radionuclides and other chemicals at Los Alamos National Laboratory, New Mexico. This study was conducted to develop an understanding of the unsaturated hydrologic behavior below the canyon floor. The main goal of this study was to evaluate the hypothetical performance of the vadose zone above the water table. Numerical simulations of unsaturated groundwater flow at the site were conducted using the Finite Element Heat and Mass Transfer (FEHM) code. A two-dimensional cross-section along the canyon's axis was used to model flow between an alluvial groundwater system and the regional aquifer approximately 300 m below. Using recharge estimated from a water budget developed in 1967, the simulations showed waters from the perched water table reaching the regional aquifer in 13.8 years, much faster than previously thought. Additionally, simulations indicate that saturation is occurring in the Guaje pumice bed an d that the Tshirege Unit 1B is near saturation. Lithologic boundaries between the eight materials play an important role in flow and solute transport within the system. Horizontal flow is shown to occur in three thin zones above capillary barriers; however, vertical flow dominates the system. Other simulations were conducted to examine the effects of changing system parameters such as varying recharge inputs, varying the distribution of recharge, and bypassing fast-path fractured basalt of uncertain extent and properties. System sensitivity was also explored by changing model parameters with respect to size and types of grids and domains, and the presence of dipping stratigraphy.

  3. Stratigraphy and geologic age of the Neogene Shimajiri Group in Kumejima Island, Ryukyu Islands, southwestern Japan

    International Nuclear Information System (INIS)

    Nakamura, Yodai; Asahara, Yoshihiro; Ozawa, Tomowo; Kameo, Koji


    The Neogene Shimajiri Group is distributed sporadically in the Ryukyu islands. This study focuses on the Shimajiri Group in Kumejima Island, central Ryukyu, and clarifies its stratigraphy and geologic age on the basis of 1) lithostratigraphy, 2) calcareous nannofossil biostratigraphy, and 3) strontium isotope stratigraphy. The Shimajiri Group in Kumejima Island unconformably overlies the middle Miocene Aradake Formation, and is overlain by the Pleistocene Ryukyu Group. The group is divided into three formations, namely the Maja, the Aka and the Uegusukudake Formations in ascending order, and the first two are redefined in this paper based on the new geologic evidence. The Maja Formation consists mainly of fine-grained sandstone, sandy siltstone and alternating beds of them. The Aka Formation is mainly composed of cross-stratified sandstone, pumiceous sandstone and tuffaceous siltstone, and unconformably overlies the Maja Formation. The Uegusukudake Formation, conformably overlying the Aka Formation, consists of basaltic lava, tuff breccia and andesite. On the basis of calcareous nannofossil biostratigraphy, the Maja and Aka Formations can be assigned to Zone CN9 and Zone CN12b of Okada and Bukry (1980) respectively. Strontium isotope ages of the molluscan fossil specimens obtained from the Maja and Aka Formations revealed that the Maja Formation is assigned to the late Miocene (ca. 7.8-7.2 Ma) and the Aka Formation is assigned to the late Pliocene (ca. 3.2-3.1 Ma). These ages are concordant with the nannofossil biostratigraphy. The upper Miocene Maja Formation yields many molluscan fossils in which the characteristic species of the Kakegawa Fauna, such as Amussiopecten praesignis and Mimachlamys satoi are contained. The molluscan fauna of the Maja Formation is significant in understanding the origin of the Kakegawa Fauna, as the characteristic species of the Plio-Pleistocene Kakegawa Fauna already appeared in the Ryukyu Islands in the late Miocene. (author)

  4. The timing of compositionally-zoned magma reservoirs and mafic 'priming' weeks before the 1912 Novarupta-Katmai rhyolite eruption (United States)

    Singer, Brad S.; Costa, Fidel; Herrin, Jason S.; Hildreth, Wes; Fierstein, Judith


    The June 6, 1912 eruption of more than 13 km3 of dense rock equivalent (DRE) magma at Novarupta vent, Alaska was the largest of the 20th century. It ejected >7 km3 of rhyolite, ~1.3 km3 of andesite and ~4.6 km3 of dacite. Early ideas about the origin of pyroclastic flows and magmatic differentiation (e.g., compositional zonation of reservoirs) were shaped by this eruption. Despite being well studied, the timing of events that led to the chemically and mineralogically zoned magma reservoir remain poorly known. Here we provide new insights using the textures and chemical compositions of plagioclase and orthopyroxene crystals and by reevaluating previous U-Th isotope data. Compositional zoning of the magma reservoir likely developed a few thousand years before the eruption by several additions of mafic magma below an extant silicic reservoir. Melt compositions calculated from Sr contents in plagioclase fill the compositional gap between 68 and 76% SiO2 in whole pumice clasts, consistent with uninterrupted crystal growth from a continuum of liquids. Thus, our findings support a general model in which large volumes of crystal-poor rhyolite are related to intermediate magmas through gradual separation of melt from crystal-rich mush. The rhyolite is incubated by, but not mixed with, episodic recharge pulses of mafic magma that interact thermochemically with the mush and intermediate magmas. Hot, Mg-, Ca-, and Al-rich mafic magma intruded into, and mixed with, deeper parts of the reservoir (andesite and dacite) multiple times. Modeling the relaxation of the Fe-Mg concentrations in orthopyroxene and Mg in plagioclase rims indicates that the final recharge event occurred just weeks prior to the eruption. Rapid addition of mass, volatiles, and heat from the recharge magma, perhaps aided by partial melting of cumulate mush below the andesite and dacite, pressurized the reservoir and likely propelled a ~10 km lateral dike that allowed the overlying rhyolite to reach the surface.

  5. Fitful and protracted magma assembly leading to a giant eruption, Youngest Toba Tuff, Indonesia (United States)

    Reid, Mary R; Vazquez, Jorge A.


    The paroxysmal eruption of the 74 ka Youngest Toba Tuff (YTT) of northern Sumatra produced an extraordinary 2800 km3 of non-welded to densely welded ignimbrite and co-ignimbrite ash-fall. We report insights into the duration of YTT magma assembly obtained from ion microprobe U-Th and U-Pb dates, including continuous age spectra over >50% of final zircon growth, for pumices and a welded tuff spanning the compositional range of the YTT. A relatively large subpopulation of zircon crystals nucleated before the penultimate caldera-related eruption at 501 ka, but most zircons yielded interior dates 100-300 ka thereafter. Zircon nucleation and growth was likely episodic and from diverse conditions over protracted time intervals of >100 to >500 ka. Final zircon growth is evident as thin rim plateaus that are in Th/U chemical equilibrium with hosts, and that give crystallization ages within tens of ka of eruption. The longevity and chemical characteristics of the YTT zircons, as well as evidence for intermittent zircon isolation and remobilization associated with magma recharge, is especially favored at the cool and wet eutectoid conditions that characterize at least half of the YTT, wherein heat fluxes could dissolve major phases but have only a minor effect on larger zircon crystals. Repeated magma recharge may have contributed to the development of compositional zoning in the YTT but, considered together with limited allanite, quartz, and other mineral dating and geospeedometry, regular perturbations to the magma reservoir over >400 ka did not lead to eruption until 74 ka ago.

  6. Mio Pliocene volcaniclastic deposits in the Famatina Ranges, southern Central Andes: A case of volcanic controls on sedimentation in broken foreland basins (United States)

    Martina, Federico; Dávila, Federico M.; Astini, Ricardo A.


    A well-constrained record of Miocene-Pliocene explosive volcanism is preserved within the broken foreland of Western Argentina along the Famatina Ranges. This paper focuses on the volcaniclastic record known as the Río Blanco member of the El Durazno Formation. Three facies can be recognized in the study area: (1) massive tuffs; (2) volcaniclastic conglomerates and (3) pumiceous sandstones. These facies are interpreted as primary pyroclastic flow deposits (ignimbrites) and reworked volcanogenic deposits within interacting volcanic-fluvial depositional systems. Alternation between ignimbrites and volcanogenic sandstones and conglomerates suggest a recurrent pattern of sedimentation related to recurrent volcanic activity. Considering the facies mosaic and relative thicknesses of facies, short periods of syn-eruption sedimentation (volcaniclastic deposits) seem to have been separated by longer inter-eruption periods, where normal stream-flow processes were dominant. The volcaniclastic component decreases up-section, suggesting a gradual reduction in volcanic activity. The mean sedimentation rate of the Río Blanco member is higher (0.44 mm/year) than those obtained for the underlying and overlying units. This increase cannot be fully explained by foreland basement deformation and tectonic loading. Hence, we propose subsidence associated with volcanic activity as the causal mechanism. Volcanism would have triggered additional accommodation space through coeval pyroclastic deposition, modification of the stream equilibrium profile, flexural loading of volcanoes, and thermal processes. These mechanisms may have favored the preservation of volcaniclastic beds in the high-gradient foreland system of Famatina during the Mio-Pliocene. Thus, the Río Blanco member records the response of fluvial systems to large, volcanism-induced sediment loads.

  7. Ability of Hand Hygiene Interventions Using Alcohol-Based Hand Sanitizers and Soap To Reduce Microbial Load on Farmworker Hands Soiled during Harvest. (United States)

    de Aceituno, Anna Fabiszewski; Bartz, Faith E; Hodge, Domonique Watson; Shumaker, David J; Grubb, James E; Arbogast, James W; Dávila-Aviña, Jorgé; Venegas, Fabiola; Heredia, Norma; García, Santos; Leon, Juan S


    Effective hand hygiene is essential to prevent the spread of pathogens on produce farms and reduce foodborne illness. The U.S. Food and Drug Administration Food Safety Modernization Act Proposed Rule for Produce Safety recommends the use of soap and running water for hand hygiene of produce handlers. The use of alcohol-based hand sanitizer (ABHS) may be an effective alternative hygiene intervention where access to water is limited. There are no published data on the efficacy of either soap or ABHS-based interventions to reduce microbial contamination in agricultural settings. The goal of this study was to assess the ability of two soap-based (traditional or pumice) and two ABHS-based (label-use or two-step) hygiene interventions to reduce microbes (coliforms, Escherichia coli, and Enterococcus spp.) and soil (absorbance of hand rinsate at 600 nm [A600]) on farmworker hands after harvesting produce, compared with the results for a no-hand-hygiene control. With no hand hygiene, farmworker hands were soiled (median A600, 0.48) and had high concentrations of coliforms (geometric mean, 3.4 log CFU per hand) and Enterococcus spp. (geometric mean, 5.3 log CFU per hand) after 1 to 2 h of harvesting tomatoes. Differences in microbial loads in comparison to the loads in the control group varied by indicator organism and hygiene intervention (0 to 2.3 log CFU per hand). All interventions yielded lower concentrations of Enterococcus spp. and E. coli (P hands (P hand washing with soap at reducing indicator organisms on farmworker hands. Based on these results, ABHS is an efficacious hand hygiene solution for produce handlers, even on soiled hands.

  8. Cryophenomena in the Cold Desert of Atacama (United States)

    Buchroithner, Dr.; Trombotto, Dr.


    The study area of the Valle de Barrancas Blancas in the High Atacama Andes of Chile (68°39' W, 27°02' S), a kind of Patagonian "bajo sin salida", shows well preserved landforms resulting from a combination of slope, eolian, lacustrine/litoral, fluvial, glacial and periglacial regimes. They permit the reconstruction of geomorphological processes within this isolated catchment of approximately 160 km2. The mean annual air temperature varies between -2 and -4 °C and the precipitation is approximately 150 mm/a. Snowfall is frequent but the snow is quickly sublimated, redeposited and/or covered by cryosediments, i.e. mainly pumice pebbles. Water bodies present icings, even in summer. Regarding its climatic conditions the study area represents an extremely cold desertic region. Extremophile microfauna was also found. The area displays both in situ mountain permafrost and creeping permafrost. The active layer is 30 to 45 cm thick. It is a periglacial macro-environment where interdependent processes, and not only cryogenic processes but also erosion and eolian deposition and the action of fluvial washout mainly caused by precipitation, accumulation, retransportation/redeposition and melting of snow, play an important role. The cryogenic geomorphology of the Valle de Barrancas Blancas is varied and contains microforms such as patterned ground and microforms caused by cryoturbation, as well as mesoforms like rockglaciers and cryoplanation surfaces. Slopes are strongly affected by gelifluction. New cryoforms in South America and in the Southern Hemisphere like the Atacama Pingo (Pingo atacamensis) and Permafrosted Dunes ("Dunas heladas") were found. Intense niveo-eolian processes participate in the erosion of preexisting landforms, in the formation of subterraneous ice layers, and the retransportation/redeposition of snow and sediments. Studies of this periglacial environment are crucial for the understanding of Tundrean paleoenvironments and Martian conditions.

  9. Magma fracturing and degassing associated with obsidian formation: The explosive–effusive transition (United States)

    Cabrera, Agustin; Weinberg, Roberto; Wright, Heather M.


    This paper explores the role of melt fracturing in degassing rhyolitic volcanic systems. The Monte Pilato-Rocche Rosse eruptions in Italy evolved from explosive to effusive in style, and H2O content in quenched glasses changed over time from relatively H2O-rich (~ 0.90 wt.%) to H2O-poor dense obsidian (~ 0.10–0.20 wt.%). In addition, healed fractures have been recorded in all different eruptive materials, from the glass of early-erupted tube pumice and rinds of breadcrusted obsidian pyroclasts, to the glass of late-erupted dense obsidian pyroclasts, and throughout the final effusive Rocche Rosse lava flow. These rocks show multiple fault sets, some with crenulated fault planes indicating resumption of viscous flow after faulting, complex obsidian breccias with evidence for post-brecciation folding and stretching, and centimetre- to metre-thick tuffisite preserved in pyroclasts and lava, representing collapsed foam due to fracturing of vesicle walls. These microstructural observations indicate that multiple fracturing and healing events occurred during both explosive and effusive eruptions. H2O content in glass decreases by as much as 0.14 wt.% towards healed fractures/faults and decreases in stretched obsidian breccias towards regions of intense brecciation. A drop in pressure and/or increase in temperature along fractures caused diffusive H2O migration through melt towards fracture surfaces. Repetitive and pervasive fracturing and healing thereby create conditions for diffusive H2O loss into fractures and subsequent escape through permeable paths. This type of progressive magma degassing provides a potential mechanism to explain the formation of dense obsidian and the evolution from explosive to effusive eruption style.

  10. Melt fracturing and healing: A mechanism for degassing and origin of silicic obsidian (United States)

    Cabrera, A.; Weinberg, R.F.; Wright, H.M.N.; Zlotnik, S.; Cas, Ray A.F.


    We present water content transects across a healed fault in pyroclastic obsidian from Lami pumice cone, Lipari, Italy, using synchrotron Fourier transform infrared spectroscopy. Results indicate that rhyolite melt degassed through the fault surface. Transects define a trough of low water content coincident with the fault trace, surrounded on either side by high-water-content plateaus. Plateaus indicate that obsidian on either side of the fault equilibrated at different pressure-temperature (P-T) conditions before being juxtaposed. The curves into the troughs indicate disequilibrium and water loss through diffusion. If we assume constant T, melt equilibrated at pressures differing by 0.74 MPa before juxtaposition, and the fault acted as a low-P permeable path for H2O that diffused from the glass within time scales of 10 and 30 min. Assuming constant P instead, melt on either side could have equilibrated at temperatures differing by as much as 100 ??C, before being brought together. Water content on the fault trace is particularly sensitive to post-healing diffusion. Its preserved value indicates either higher temperature or lower pressure than the surroundings, indicative of shear heating and dynamic decompression. Our results reveal that water contents of obsidian on either side of the faults equilibrated under different P-T conditions and were out of equilibrium with each other when they were juxtaposed due to faulting immediately before the system was quenched. Degassing due to faulting could be linked to cyclical seismic activity and general degassing during silicic volcanic activity, and could be an efficient mechanism of producing low-water-content obsidian. ?? 2011 Geological Society of America.

  11. Effects of surface treatment and artificial aging on the shear bond strength of orthodontic brackets bonded to four different provisional restorations. (United States)

    Al Jabbari, Youssef S; Al Taweel, Sara M; Al Rifaiy, Mohammed; Alqahtani, Mohammed Q; Koutsoukis, Theodoros; Zinelis, Spiros


    To evaluate the combined effects of material type, surface treatment, and thermocycling on the bond strength of orthodontic brackets to materials used for the fabrication of provisional crowns. Four materials were included in this study (ProTemp, Trim Plus, Trim II, and Superpont C+B). Sixty cylindrical specimens (1 × 3 cm) were prepared from each material and equally divided into three groups. The first group was ground with silica carbide paper, the second was polished with pumice, and the last group was sandblasted with 50-µm aluminum oxide particles. Stainless-steel maxillary central incisor brackets (Victory Series, 3M) were bonded to the provisional material specimens with Transbond XT light-cured composite resin, and half of the specimens from each group were thermocycled 500 times in 5°C and 55°C water baths. Then the brackets were debonded with shear testing, and the results were statistically analyzed by three-way analysis of variance and Tukey's multiple-comparison tests at α  =  0.05. Adhesive Remnant Index (ARI) was also identified. Before and after thermocycling, ProTemp materials showed the highest shear bond strength with orthodontic brackets (10.3 and 13.1 MPa, respectively). The statistical analysis indicated an interaction among the three independent variables (P < .05) and statistically significant differences in bond strength among provisional materials (P < .001), surface treatments (P < .001), and thermocycling (P < .05). According to the ARI, most groups demonstrated adhesive failure. The provisional material type, surface treatment, and artificial aging have a significant effect on bond strength. Sandblasting treatment exerts a beneficial effect on shear bond strength.

  12. Effect of CO2 Laser and Fluoride Varnish Application on Microhardness of Enamel Surface Around Orthodontic Brackets. (United States)

    Mahmoudzadeh, Majid; Rezaei-Soufi, Loghman; Farhadian, Nasrin; Jamalian, Seyed Farzad; Akbarzadeh, Mahdi; Momeni, Mohammadali; Basamtabar, Masome


    Introduction: Orthodontic treatment has many advantages such as esthetic improvement and self-esteem enhancement; yet it has some disadvantages such as increasing the risk of formation of white spot lesions, because it makes oral hygiene more difficult. It is rational to implement procedures to prevent these lesions. The present study was aimed to assess the effect of CO 2 laser and fluoride varnish on the surface of the enamel surface microhardness around the orthodontic braces. Methods: Eighty extracted premolar teeth were selected, scaled, polished with nonfluoridated pumic and metal brackets were bonded to them. Then, they were randomly allocated to 5 groups: control (neither fluoride nor laser is used on enamel surfaces), fluoride (4 minutes fluoride varnish treatment of the enamel surfaces), CO 2 laser (10.6 µm CO 2 laser irradiation of the teeth), laserfluoride (fluoride application after laser irradiation) and fluoride-laser (fluoride was applied and then teeth were irradiated with laser). After surface treatment around brackets on enamel, the samples were stored in 0.1% thymol for less than 5 days and then they were exposed to a 10-day microbiological caries model. Microhardness values of enamel were evaluated with Vickers test. One sample of each group (5 teeth from 80 samples) was prepared for SEM (scanning electron microscopy) and the data from 75 remaining teeth were analyzed with analysis of variance (ANOVA) and chi-square tests (α =0.05). Results: Microhardness mean values from high to low were as follow: fluoride-laser, laser-fluoride, laser, fluoride and control. Microhardness in fluoride-laser group was significantly higher compared with that of the control group. Distribution adhesive remnant index (ARI) scores were significantly different between groups and most of bond failures occurred at the enamel-adhesive interface in groups 2 to 5 and at the adhesive-bracket interface in the control group. Conclusion: Combination of fluoride varnish and

  13. Emplacement of Holocene silicic lava flows and domes at Newberry, South Sister, and Medicine Lake volcanoes, California and Oregon (United States)

    Fink, Jonathan H.; Anderson, Steven W.


    This field guide for the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly 2017 focuses on Holocene glassy silicic lava flows and domes on three volcanoes in the Cascade Range in Oregon and California: Newberry, South Sister, and Medicine Lake volcanoes. Although obsidian-rich lava flows have been of interest to geologists, archaeologists, pumice miners, and rock hounds for more than a century, many of their emplacement characteristics had not been scientifically observed until two very recent eruptions in Chile. Even with the new observations, several eruptive processes discussed in this field trip guide can only be inferred from their final products. This makes for lively debates at outcrops, just as there have been in the literature for the past 30 years.Of the three volcanoes discussed in this field guide, one (South Sister) lies along the main axis defined by major peaks of the Cascade Range, whereas the other two lie in extensional tectonic settings east of the axis. These two tectonic environments influence volcano morphology and the magmatic and volcanic processes that form silicic lava flows and domes. The geomorphic and textural features of glass-rich extrusions provide many clues about their emplacement and the magma bodies that fed them.The scope of this field guide does not include a full geologic history or comprehensive explanation of hazards associated with a particular volcano or volcanic field. The geochemistry, petrology, tectonics, and eruption history of Newberry, South Sister, and Medicine Lake volcanic centers have been extensively studied and are discussed on other field excursions. Instead, we seek to explore the structural, textural, and geochemical evolution of well-preserved individual lava flows—the goal is to understand the geologic processes, rather than the development, of a specific volcano.

  14. Evaluation of the effect of different methods of microabrasion and polishing on surface roughness of dental enamel. (United States)

    Bertoldo, Carlos; Lima, Debora; Fragoso, Larissa; Ambrosano, Glaucia; Aguiar, Flavio; Lovadino, Jose


    The microabrasion technique of enamel consists of selectively abrading the discolored areas or causing superficial structural changes in a selective way. In microabrasion technique, abrasive products associated with acids are used, and the evaluation of enamel roughness after this treatment, as well as surface polishing, is necessary. This in-vitro study evaluated the enamel roughness after microabrasion, followed by different polishing techniques. Roughness analyses were performed before microabrasion (L1), after microabrasion (L2), and after polishing (L3).Thus, 60 bovine incisive teeth divided into two groups were selected (n=30): G1- 37% phosphoric acid (37%) (Dentsply) and pumice; G2- hydrochloric acid (6.6%) associated with silicon carbide (Opalustre - Ultradent). Thereafter, the groups were divided into three sub-groups (n=10), according to the system of polishing: A - Fine and superfine granulation aluminum oxide discs (SofLex 3M); B - Diamond Paste (FGM) associated with felt discs (FGM); C - Silicone tips (Enhance - Dentsply). A PROC MIXED procedure was applied after data exploratory analysis, as well as the Tukey-Kramer test (5%). No statistical differences were found between G1 and G2 groups. L2 differed statistically from L1 and showed superior amounts of roughness. Differences in the amounts of post-polishing roughness for specific groups (1A, 2B, and 1C) arose, which demonstrated less roughness in L3 and differed statistically from L2 in the polishing system. All products increased enamel roughness, and the effectiveness of the polishing systems was dependent upon the abrasive used.

  15. Microbial decontamination of uranium mine drainage

    International Nuclear Information System (INIS)

    Hard, B.C.; Babel, W.


    One of the problems one is faced with when uranium mines are closed is the decontamination of acid mine drainage (AMD) from tailings and flooding of the underground mines. The high concentrations of sulfates and metals in mining water make it impossible to dispose of the water into rivers without having to decontaminate it first. A bioremediation process is proposed in which sulfate-reducing bacteria are used to remove metals, neutralize the water and reduce the sulfate concentrations. Methylotrophic sulfate-reducing strains have been isolated which can be used in such a process. Lab scale experiments with different reactor types were carried out in order to find the optimum design for this bioremediation process. Comparisons were made between methanol and other electron donors with regards to their suitability as substrate for this process. Methanol was found to be most suited. Laboratory data suggest that immobilizing the bacteria on pumice particles increases the sulfate-reduction rate (SRR) up to three fold to 18 mg/l.h, compared to the rates of free flowing cells of between 3.7 and 6.8 mg/l.h. Preliminary experiments on a larger scale (15 l) using acid mine drainage pH 2.5 show SRR of 0.71 mg/l.h. In biosorption experiments up to 140 mg of aluminium per g biomass was removed from the water. One strain was found to reduce uranium VI, thus changing it from the soluble to the insoluble form. The application of the proposed process with regards to bioremediation of AMD are discussed. (orig.)


    International Nuclear Information System (INIS)


    Three wells, PB-1, PB-2, and PB-3, were drilled in 2003 at the Nopal I uranium deposit as part of a natural analogue study to evaluate radionuclide transport processes. The wells penetrate through the Tertiary volcanic section down to the Cretaceous limestone basement, and intersect the top of the regional aquifer system. The PB-1 well, drilled immediately adjacent to the Nopal I ore body, was cored to a depth of 250 m, thus providing an opportunity to document the local stratigraphy. The uppermost unit encountered in the PB-1 well is the Nopal Formation, a densely welded, crystal-rich rhyolitic ash-flow tuff. The cored section is highly altered and devitrified, with kaolinite, quartz, chlorite, and montmorillonite replacing feldspars and much of the groundmass. Breccia zones within the tuff contain fracture fillings of hematite, limonite, and goethite. A zone of intense clay alteration encountered in the depth interval 17.45-22.30 m was interpreted to represent the basal vitrophyre of this unit. Underlying the basal vitrophyre is the Coloradas Formation, which consists of a welded, lithic-rich rhyolitic ash-flow tuff. The cored section of this unit has undergone devitrification and oxidation, and has a similar alteration mineralogy to that observed in the Nopal tuff. The Nopal I ore body is restricted to a brecciated zone that intersects these two volcanic units. A sharp contact between the Coloradas tuff and the underlying Pozos Formation was observed at a depth of 136.38 m. The Pozos Formation in the PB-1 core consists of interbedded, poorly sorted sandstone and conglomerate layers. The conglomeratic clasts consist of subangular to subrounded fragments of volcanic rocks, limestone, and chert. Thin (2-6 m) intervals of intercalated pumiceous tuffs were observed within this unit. The contact between the Pozos Formation and the underlying Cretaceous limestone basement was observed at a depth of 244.4 m

  17. Orthodontic bracket bonding to glazed full-contour zirconia

    Directory of Open Access Journals (Sweden)

    Ji-Young Kwak


    Full Text Available Objectives This study evaluated the effects of different surface conditioning methods on the bond strength of orthodontic brackets to glazed full-zirconia surfaces. Materials and Methods Glazed zirconia (except for the control, Zirkonzahn Prettau disc surfaces were pre-treated: PO (control, polishing; BR, bur roughening; PP, cleaning with a prophy cup and pumice; HF, hydrofluoric acid etching; AA, air abrasion with aluminum oxide; CJ, CoJet-Sand. The surfaces were examined using profilometry, scanning electron microscopy, and electron dispersive spectroscopy. A zirconia primer (Z-Prime Plus, Z or a silane primer (Monobond-S, S was then applied to the surfaces, yielding 7 groups (PO-Z, BR-Z, PP-S, HF-S, AA-S, AA-Z, and CJ-S. Metal bracket-bonded specimens were stored in water for 24 hr at 37℃, and thermocycled for 1,000 cycles. Their bond strengths were measured using the wire loop method (n = 10. Results Except for BR, the surface pre-treatments failed to expose the zirconia substructure. A significant difference in bond strengths was found between AA-Z (4.60 ± 1.08 MPa and all other groups (13.38 ± 2.57 - 15.78 ± 2.39 MPa, p < 0.05. For AA-Z, most of the adhesive remained on the bracket. Conclusions For bracket bonding to glazed zirconia, a simple application of silane to the cleaned surface is recommended. A zirconia primer should be used only when the zirconia substructure is definitely exposed.

  18. Eruptive origins of a lacustrine pyroclastic succession: insights from the middle Huka Falls Formation, Taupo Volcanic Zone, New Zealand

    International Nuclear Information System (INIS)

    Cattell, H.J.; Cole, J.W.; Oze, C.; Allen, S.R.


    Current and ancestral lakes within the central Taupo Volcanic Zone (TVZ) provide depocentres for pyroclastic deposits, providing a reliable record of eruption history. These lakes can also be the source of explosive eruptions that directly feed pyroclast-rich density currents. The lithofacies characteristics of pyroclastic deposits allow discrimination between eruption-fed and resedimented facies. The most frequently recognised styles of subaqueous eruptions in the TVZ are shallow-water phreatomagmatic and phreatoplinian eruptions that form subaerial eruption columns. However, deeper source conditions (>150 m water depth) could generate subaqueous explosive eruptions that feed water-supported pyroclast-rich density currents, similar to neptunian eruptions. Such deep-water eruptions have not previously been recognised in the TVZ. Here we study a subsurface deposit, the middle Huka Falls Formation (MHFF), in the Wairakei-Tauhara geothermal fields (Wairakei-Tauhara), TVZ, which we interpret to be the product of a relatively deep-water pyroclastic eruption (150-250 m). The largely subsurface Huka Falls Formation records past sedimentary and volcaniclastic deposition in ancient Lake Huka. Deposits examined from eight drill cores reveal a lithic-rich lower unit, a middle volumetrically dominant pumice lapilli-tuff and an upper thinly bedded suspension-settled tuff unit. A coarse lithic lapilli-tuff within the lower unit is locally thick and coarse near well THM12, suggesting proximity to a source located beneath Lake Huka. This research provides an understanding of the origin of the MHFF deposit and offers insights for evaluating and interpreting the diversity of subaqueous volcanic lake deposits elsewhere. (author)

  19. Pseudoimpactites in anthropocenically overprinted quaternary sediments (United States)

    Huber, Robert; Darga, Robert; Lauterbach, Hans


    Whereas typical anthropogenic materials such as plastics can easily be identified in the anthropocene record, other materials such as building materials or industrial waste often closely resemble natural rocks or minerals. Especially transported and weathered anthropocenic matter is hard to distinguish from natural rocks. Whereas most rock samples may easily be distinguished by visual inspection, definite identification of exotic and small sized matter is not always an easy exercise which has been shown during the controversial discussion on the cosmic origin of carbon spherules found in Younger Dryas sediments. Similarly, a variety of exotic materials and lithological phenomena reported from quaternary sediments in Upper Bavaria have been associated to a cosmic impact in the area. Findings of carbonatic regmaglypts, glass coated and fragmented rocks, glassy carbon or pumice like carbon have been proposed to represent impact related rocks, an hypothesis which has further been supported by findings of iron silicides and the postulated detection of nanodiamonds and Carbine. Many of these findings have been strongly doubted within the geoscientific community, however a systematic, independent investigation of these phenomena has not yet been conducted. We present the results of our examinations which have been carried out to critically test the impact related origin of the mentioned strange materials and rocks. We could identify some key sites and independently collected samples of several of the materials and analysed these thoroughly. We found that the majority of these impact related materials is of anthropogenic or biogenic origin, thus they are pseudoimpactites partly originating from old fireplaces and waste pits. The claimed cosmic origin of this matter is an illusion caused by the anthropocene overprint of the original sedimentary record.

  20. Model Mineralisasi Pembentukan Opal Banten

    Directory of Open Access Journals (Sweden)

    Chusni Ansori


    Full Text Available DOI: 10.17014/ijog.v5i3.100Opal is a beautiful precious gemstone that is equal or more valuable than diamond. In Indonesia, precious opal is found at the Lebak Regency, Province of Banten. Banten’s opal widely has been recognized due to its beautiful opalescence. This paper is a review of the last research; preliminary study of Banten’s opal, characteristics of opal-CT and determining of opal type from geochemical data, added by new data to compile concept and to make mineralization model. In order to fulfill these targets, field geology research and analysis of mineralog/gemology, petrography, X-RD, and major and trace element geochemistry have been done. The Banten’s opal is opal-CT showing opalescence (play of colour, weathering, and leaching silica from volcanic glass by dark grey claystone hosted. Mineralization model is divided into three periods; at Early Pliocene volcanic clastic sediments rich in volcanic glass occured as fluvial sediments. Afterwards, at Late Pliocene - Pleistocene folding, weathering and leaching of silica took place. Intensive jointing, faulting, and folding quickened weathering and leaching processes to formed opal at limb of anticline through Holocene. The prospecting area of Banten’s opal is in tuff unit with intercalation of conglomerate or pumiceous breccia, at limb of anticline. The host rock of opal is dark grey claystone which underlies polimict conglomerate/pebbly sandstone sequence with cross stratification, imbricated, and erossional stucture; more than 8 m deep.

  1. Status of volcanic hazard studies for the Nevada Nuclear Waste Storage Investigations. Volume II

    International Nuclear Information System (INIS)

    Crowe, B.M.; Wohletz, K.H.; Vaniman, D.T.; Gladney, E.; Bower, N.


    Volcanic hazard investigations during FY 1984 focused on five topics: the emplacement mechanism of shallow basalt intrusions, geochemical trends through time for volcanic fields of the Death Valley-Pancake Range volcanic zone, the possibility of bimodal basalt-rhyolite volcanism, the age and process of enrichment for incompatible elements in young basalts of the Nevada Test Site (NTS) region, and the possibility of hydrovolcanic activity. The stress regime of Yucca Mountain may favor formation of shallow basalt intrusions. However, combined field and drill-hole studies suggest shallow basalt intrusions are rare in the geologic record of the southern Great Basin. The geochemical patterns of basaltic volcanism through time in the NTS region provide no evidence for evolution toward a large-volume volcanic field or increases in future rates of volcanism. Existing data are consistent with a declining volcanic system comparable to the late stages of the southern Death Valley volcanic field. The hazards of bimodal volcanism in this area are judged to be low. The source of a 6-Myr pumice discovered in alluvial deposits of Crater Flat has not been found. Geochemical studies show that the enrichment of trace elements in the younger rift basalts must be related to an enrichment of their mantle source rocks. This geochemical enrichment event, which may have been metasomatic alteration, predates the basalts of the silicic episode and is, therefore, not a young event. Studies of crater dimensions of hydrovolcanic landforms indicate that the worst case scenario (exhumation of a repository at Yucca Mountain by hydrovolcanic explosions) is unlikely. Theoretical models of melt-water vapor explosions, particularly the thermal detonation model, suggest hydrovolcanic explosion are possible at Yucca Mountain. 80 refs., 21 figs., 5 tabs

  2. Evaluation of methods for stain removal in acrylic resin denture teeth: in vitro study

    Directory of Open Access Journals (Sweden)

    Ana Flávia Balestrero CASSIANO

    Full Text Available Abstract Introduction The staining of artificial teeth can be related to the acrylic resin abrasion caused by brushing, resulting in higher deposition of dyes from the beverage, and consequently higher aesthetic damage. Objective The aim of this in vitro study was to evaluate methods for removal of stains from acrylic denture teeth using spectrophotometric analysis. Material and method Artificial teeth were divided into twelve groups (n=10 according to the type of treatment (re-polishing - Re or immersion in Corega Tabs - Sp, staining solutions, coffee (Cf and Coca-Cola® (Cc or water (W and with/without toothbrushing (B. The Sp specimens were submitted to seven immersion cycles (5 min each. The Re specimens were polished with pumice stone followed by Spain white paste. Color differences (ΔE were captured by a spectrophotometer: T0 (baseline, T1 (after brushing/immersion in solutions and T2 (after Re or Sp. Result Statistically significant color change between T1 and T2 (paired T-test; α =.05 was observed for the group CfSp (p=.032; and for the groups BWRe (p=.000, BCfRe (p=.049 and CcRe (p=.042. Higher color changes were observed for the specimens submitted to toothbrushing (ANOVA two way; p<.001. Conclusion It could be concluded that the immersion in sodium perborate (Corega Tabs can be used for removal of coffee stains from denture teeth, and re-polishing for removal of Coca-Cola® stains. Still, toothbrushing produced greater color changes on denture teeth, regardless of the immersion solution.

  3. Causes of fragmented crystals in ignimbrites: a case study of the Cardones ignimbrite, Northern Chile (United States)

    van Zalinge, M. E.; Cashman, K. V.; Sparks, R. S. J.


    Broken crystals have been documented in many large-volume caldera-forming ignimbrites and can help to understand the role of crystal fragmentation in both eruption and compaction processes, the latter generally overlooked in the literature. This study investigates the origin of fragmented crystals in the > 1260 km3, crystal-rich Cardones ignimbrites located in the Central Andes. Observations of fragmented crystals in non-welded pumice clasts indicate that primary fragmentation includes extensive crystal breakage and an associated ca. 5 vol% expansion of individual crystals while preserving their original shapes. These observations are consistent with the hypothesis that crystals fragment in a brittle response to rapid decompression associated with the eruption. Additionally, we observe that the extent of crystal fragmentation increases with increasing stratigraphic depth in the ignimbrite, recording secondary crystal fragmentation during welding and compaction. Secondary crystal fragmentation aids welding and compaction in two ways. First, enhanced crystal fragmentation at crystal-crystal contacts accommodates compaction along the principal axis of stress. Second, rotation and displacement of individual crystal fragments enhances lateral flow in the direction(s) of least principal stress. This process increases crystal aspect ratios and forms textures that resemble mantled porphyroclasts in shear zones, indicating lateral flow adds to processes of compaction and welding alongside bubble collapse. In the Cardones ignimbrite, secondary fragmentation commences at depths of 175-250 m (lithostatic pressures 4-6 MPa), and is modulated by both the overlying crystal load and the time spent above the glass transition temperature. Under these conditions, the existence of force-chains can produce stresses at crystal-crystal contacts of a few times the lithostatic pressure. We suggest that documenting crystal textures, in addition to conventional welding parameters, can

  4. In vitro color stability of provisional restorative materials

    Directory of Open Access Journals (Sweden)

    Hamid Jalali


    Aims: The purpose of this study was to investigate the effect of tea on provisional restorative materials. Setting and Design: This study was designed to measure the degree of color change of three acrylic resin provisional materials, before and after immersion in artificial saliva and artificial saliva-tea solution for 2 and 4 weeks. Materials and Methods : Three types of acrylic provisional materials (duralay, tempron, acropars TRP, were studied. Twenty disks (20±0.1 mm by 2±0.05 mm were fabricated from each material. Specimens were polished with acrylic bur using pumice and diamond polishing paste. Base line color was measured using a spectrophotometer. Ten disks were stored in artificial saliva and 10 were stored in a solution of artificial saliva and tea at room temperature. Color measurements were made after 2 and 4 weeks of immersion. Statistical analysis used: Differences in color changes were compared by two way ANOVA, across the six groups, followed by a Turkey-Kramer′s multiple comparison test. Results: For specimens immersed in artificial saliva, the color change of methyl methacrylate materials; duralay (ΔE=4.94 and tempron (ΔE=6.54, was significantly more than butyl methacrylate material; acropars (ΔE=4.10. After immersion in an artificial saliva- tea solution, tempron exhibited less color change (ΔE=8.50 compared to duralay (ΔE=10.93 and acropars (ΔE=15.64. Conclusion: Color stability of methyl methacrylate is higher than butyl methacrylates so if provisional materials are used for extended periods of time; tempron is preferred.

  5. In vitro color stability of provisional restorative materials. (United States)

    Jalali, Hamid; Dorriz, Hassan; Hoseinkhezri, Farzaneh; Emadian Razavi, S F


    Discoloration of provisional restorations can result in esthetic problems which are critically important in, for example, anterior areas and may compromise the acceptability of the restoration. The purpose of this study was to investigate the effect of tea on provisional restorative materials. This study was designed to measure the degree of color change of three acrylic resin provisional materials, before and after immersion in artificial saliva and artificial saliva-tea solution for 2 and 4 weeks. Three types of acrylic provisional materials (duralay, tempron, acropars TRP), were studied. Twenty disks (20 ± 0.1 mm by 2 ± 0.05 mm) were fabricated from each material. Specimens were polished with acrylic bur using pumice and diamond polishing paste. Base line color was measured using a spectrophotometer. Ten disks were stored in artificial saliva and 10 were stored in a solution of artificial saliva and tea at room temperature. Color measurements were made after 2 and 4 weeks of immersion. Differences in color changes were compared by two way ANOVA, across the six groups, followed by a Turkey-Kramer's multiple comparison test. For specimens immersed in artificial saliva, the color change of methyl methacrylate materials; duralay (ΔE=4.94) and tempron (ΔE=6.54), was significantly more than butyl methacrylate material; acropars (ΔE=4.10). After immersion in an artificial saliva- tea solution, tempron exhibited less color change (ΔE=8.50) compared to duralay (ΔE=10.93) and acropars (ΔE=15.64). Color stability of methyl methacrylate is higher than butyl methacrylates so if provisional materials are used for extended periods of time; tempron is preferred.

  6. Do Zircon age Spectra Record Magmatic Cyclicity at Soufrière (Saint Lucia, Lesser Antilles)? (United States)

    Schmitt, A. K.; Stockli, D. F.; Lindsay, J. M.


    The Soufrière Volcanic Center (Saint Lucia, Lesser Antilles) is a long-lived arc-volcanic system that evolved over the past 5 - 6 Ma. Its most recent volcanic activity between 20 and 40 ka was concentrated within the prominent Qualibou topographic depression and produced two voluminous pyroclastic deposits: Choiseul and the overlying Belfond. In addition, several dacitic lava domes exist within the Qualibou depression. Because evidence of earlier volcanic activity in long-lived magma systems is frequently obliterated by subsequent eruptive or volcano-tectonic events, high spatial resolution U-Th dating of zircon combined with (U-Th)/He dating is a powerful tool to identify magma crystallization episodes at depth and to link these to the eruptive record. U-Th model ages and disequilibrium corrected U-Pb ages for 56 individual zircons from Soufrière lavas (Morne Bonin, Belfond, Terre Blanche) and pumice (Choiseul, Belfond) were determined by secondary ionization mass spectrometry. The majority of results is on unpolished zircons where analysis pits integrate over the outermost ~10 μm of individual grains with a lateral spatial resolution of ~40 μm. Selected grains were subsequently analyzed by (U-Th)/He methods. Belfond and Terre Blanche (U-Th)/He zircon ages (~20 ka) agree with previous 14C charcoal ages, whereas Morne Bonin ages are much older (~250 ka). Overall, the U-Th zircon crystallization age spectrum reveals a remarkable range between ~20 and ~600 ka and displays multiple peaks, among which the most prominent are tentatively identified at ~40 ka, ~80 ka, ~130 ka, ~200 ka and ~500 ka. The distribution of rim ages indicates that most zircons lack overgrowth dating from just prior to the eruption, but the youngest ages for each sample overlap with the eruption ages. Soufrière zircons thus reveal magma intrusion, cooling, and crystallization cycles within the underlying plutonic system for which the volcanic stratigraphic record is sketchy.

  7. Episodic growth and homogenization of plutonic roots in arc volcanoes from combined U-Th and (U-Th)/He zircon dating (United States)

    Schmitt, Axel K.; Stockli, Daniel F.; Lindsay, Jan M.; Robertson, Richard; Lovera, Oscar M.; Kislitsyn, Roman


    Tracing the fate of unerupted magma is challenging because plutonic roots of young volcanoes are largely inaccessible. Here we develop the use of zircon age spectra to determine crystal provenance and source rocks for volcanic products, in analogy to detrital crystals in sediments. U-Th zircon crystallization ages for the Soufrière Volcanic Complex, Saint Lucia (Lesser Antilles) frequently predate their eruption as determined from combined U-Th and (U-Th)/He zircon dating. The oldest dated eruptions are 273 ± 15 ka and 264 ± 8 ka (1σ uncertainty) for Morne Bonin dacite and Bellevue pumice deposit, respectively. The most recent eruptions formed morphologically pristine domes in the center of the Qualibou depression (Belfond: 13.6 ± 0.4 ka; Terre Blanche: 15.3 ± 0.4 ka). U-Th (U-Pb) zircon crystallization ages determined for crystal rims and interiors range between near-eruption ages to ∼ 600 ka. Older xenocrysts are absent. Zircon crystallization age distributions are complex, yet systematic: crystal rim ages in the most recently erupted volcanic rocks match those of co-erupted plutonic inclusions, whereas crystal interiors are equivalent to the cumulative distribution of zircon ages from older eruptions. This is evidence that silicic lava domes and pyroclastic flows share a common source that is located underneath the Qualibou depression, where the intrusive roots of this long-lived arc volcanic system became homogenized through thermal and mechanical reprocessing of individual batches of unerupted magma from earlier volcanic episodes within timescales of < 100 ka.

  8. Microbial community stratification controlled by the subseafloor fluid flow and geothermal gradient at the Iheya North hydrothermal field in the Mid-Okinawa Trough (Integrated Ocean Drilling Program Expedition 331). (United States)

    Yanagawa, Katsunori; Breuker, Anja; Schippers, Axel; Nishizawa, Manabu; Ijiri, Akira; Hirai, Miho; Takaki, Yoshihiro; Sunamura, Michinari; Urabe, Tetsuro; Nunoura, Takuro; Takai, Ken


    The impacts of lithologic structure and geothermal gradient on subseafloor microbial communities were investigated at a marginal site of the Iheya North hydrothermal field in the Mid-Okinawa Trough. Subsurface marine sediments composed of hemipelagic muds and volcaniclastic deposits were recovered through a depth of 151 m below the seafloor at site C0017 during Integrated Ocean Drilling Program Expedition 331. Microbial communities inferred from 16S rRNA gene clone sequencing in low-temperature hemipelagic sediments were mainly composed of members of the Chloroflexi and deep-sea archaeal group. In contrast, 16S rRNA gene sequences of marine group I Thaumarchaeota dominated the microbial phylotype communities in the coarse-grained pumiceous gravels interbedded between the hemipelagic sediments. Based on the physical properties of sediments such as temperature and permeability, the porewater chemistry, and the microbial phylotype compositions, the shift in the physical properties of the sediments is suggested to induce a potential subseafloor recharging flow of oxygenated seawater in the permeable zone, leading to the generation of variable chemical environments and microbial communities in the subseafloor habitats. In addition, the deepest section of sediments under high-temperature conditions (∼90°C) harbored the sequences of an uncultivated archaeal lineage of hot water crenarchaeotic group IV that may be associated with the high-temperature hydrothermal fluid flow. These results indicate that the subseafloor microbial community compositions and functions at the marginal site of the hydrothermal field are highly affected by the complex fluid flow structure, such as recharging seawater and underlying hydrothermal fluids, coupled with the lithologic transition of sediments. Copyright © 2014, American Society for Microbiology. All Rights Reserved.

  9. Formation of obsidian pyroclasts by sintering of ash particles in the volcanic conduit (United States)

    Gardner, James E.; Llewellin, Edward W.; Watkins, James M.; Befus, Kenneth S.


    The ranges in intensity and style of volcanic eruptions, from highly explosive Plinian eruptions to quiescent lava extrusions, depend on the style and efficiency of gas loss from ascending magma. Obsidian pyroclasts - small, glassy pieces of quenched magma found in some volcanic tephra beds - may preserve valuable information about magma degassing in their vesicle textures and volatile contents. Accurate interpretation of their textures and volatiles, however, requires understanding the mechanism of formation of the pyroclasts. Obsidian pyroclasts from the ca. 1325-1350 C.E. North Mono eruption of Mono Craters (CA, USA) were analyzed and found to have H2O and CO2 contents indicating that they were formed at pressures in the approximate range of 3-40 MPa. Many also contain domains with differing vesicle textures, separated by boundaries containing xenocrystic material, indicating that they are composed of smaller fragments that have sutured together. More than half of the pyroclasts analyzed contained small (∼10 μm), highly distorted vesicles, with multi-cuspate morphology, interpreted as the remnants of interstitial gas trapped amongst sintered fragments of melt/glass. Rounded vesicles are also common and are interpreted to result from surface tension-driven relaxation of the distorted vesicles. Calculated timescales of sintering and relaxation are consistent with timescales for pyroclast formation indicated by H2O re-equilibration within the heterogeneous pyroclasts. This sintering model for the origin of obsidian pyroclasts is further supported by the observation that spherical vesicles are found mainly in H2O-rich pyroclasts, and distorted vesicles mainly in H2O-poor pyroclasts. We conclude that obsidian pyroclasts generated during the North Mono eruption were formed by cycles of fragmentation, sintering/suturing, and relaxation, over a very wide range of depths within the conduit; we find no evidence to support pumice (foam) collapse as the formation

  10. Structure Of Conduits Of The Acidic Volcanism And Related Deposits In The Paraná-Etendeka Magmatic Province, São Marcos Region, South Brazil (United States)

    Guimarães, L. F.; De Campos, C. P.; Lima, E. F. D.; Janasi, V. A.


    Voluminous acidic volcanics from the Paraná-Etendeka Magmatic Province crop out in the southern part of Brazil. The conduits responsible for the feeding of this intermediate/acid volcanism are preserved and well exposed in the São Marcos region (Lima et al. 2012; Geologia USP 12:49-64). Conduits are aligned along a NW-SE trend and have thicknesses up to 1 km. These structures are often characterized by mixing between dacitic and rhyodacitic magmas, with intercalation between two major zones: 1) reddish or grayish vitrophiricdacite/rhyodacite, sub-divided in massive or vesiculated; 2) reddish or grayish vitrophiric fragmented dacite/rhyodacite composed of bubble-rich angular to rounded blocks. Such fragments commonly deform coeval to the flow. A third zone dominated by filaments depicts a chaotic stretching-and-folding process from the mixture of the acid magmas. We used classical field measurements of flow structures and recognized main flow directions in these feeder-dikes. They follow two preferential directions: NW, ranging from N272° to N 355°, and NE, varying from N20° to N85°. These directions are indicative of a transtensive fissural system, which seems to be related to conjugated fractures. Evidence of an important fragmentation process in the conduits point towards the presence of related products in this region, thus rheomorphic deposits such as those observed elsewhere (e.g. Uruguay and Namibia) are expected to occur. Possible vestiges of these deposits could be represented by restricted outcrops of lens-shaped and banded hipohyaline, occasionally bubble-rich, dacites. The presence of continuous pseudotachylitic levels, tightly folded bands with horizontal axial planes together with local deformed bubble-rich pumice-like lens could be indicative of remelting and rheomorphism of previous vulcanoclastic material. Coulees and compound (lobed) dacitic lava flows, reaching up to 5-8 meters length, occur as the uppermost deposits and correspond to the

  11. Ash erupted during normal activity at Stromboli (Aeolian Islands, Italy) raises questions on how the feeding system works (United States)

    D'Oriano, Claudia; Bertagnini, Antonella; Pompilio, Massimo


    Normal activity at Stromboli consists of continuous, non-explosive degassing, punctuated by mild explosions at a frequency of about 13 events/h. Each burst, lasting for a few seconds, throws to heights of 100-300 m incandescent scoriae, ash and blocks made of high-porphyritic (HP) degassed magma. During a multidisciplinary experiments on September 2008, ash samples emitted from 18 distinct explosions were collected with the aim of investigating magmatic and volcanic processes occurring in the conduits during the normal Strombolian activity on the basis of ash characterization. The selected samples are representative of the activity of two different craters (SW and NE) during three distinct days. After sieving, about 30 juvenile fragments (from the 0.5-1 mm size interval) were randomly hand-picked from each sample, and then mounted on double-adhesive tape on a glass slide. Single clasts were examined and photographed at the Scanning Electron Microscope (SEM) for identification of clast types, external morphology description and identification of secondary minerals. The same clasts were embedded in epoxy, sectioned and polished for textural and compositional analysis of the groundmass. Preliminary results indicate that Pele's hairs and fluidal, glassy fragments represent the majority (>50 vol%) of the juvenile material together with dense clasts (<30 vol%) in all the analysed samples, while crystals and lithic clasts are less than 20 vol%. Within the juvenile fraction a minor but significant amount of highly vesicular fragments (< 3 vol%) shows glass composition typical of deep-seated, volatile-rich, low-porphyritic (LP) magma. Until now the emission of the LP magma, as highly vesicular pumice, was associated exclusively with high energy explosions (paroxysms) (Bertagnini et al. 1999, Schiavi et al. 2009). The comparison of the morphological and textural features of these LP ash fragments let exclude that they are clasts recycled after the last paroxysm (15 March

  12. Experimental and petrological constraints on long-term magma dynamics and post-climactic eruptions at the Cerro Galán caldera system, NW Argentina (United States)

    Grocke, Stephanie B.; Andrews, Benjamin J.; de Silva, Shanaka L.


    Cerro Galán in NW Argentina records > 3.5 Myr of magmatic evolution of a major resurgent caldera complex. Beginning at 5.72 Ma, nine rhyodacitic ignimbrites (68-71 wt% SiO2) with a combined minimum volume of > 1200 km3 (Dense Rock Equivalent; DRE) have been erupted. The youngest of those ignimbrites is the eponymous, geochemically homogenous, caldera-forming 2.08 ± 0.02 Ma Cerro Galán Ignimbrite (CGI; > 630 km3 DRE). Following this climactic supereruption, structural and magmatic resurgence led to the formation of a resurgent dome and post-climactic lava domes and their associated pyroclastic deposits. A clear transition from amphibole to sanidine-bearing magmas occurred during the evolution of Cerro Galán and is inferred to represent a shallowing of the magma system. We test this hypothesis here using experimental phase equilibria. We conducted a series of phase equilibria experiments on the post-climactic dome lithologies under H2O-saturated conditions using cold seal Waspaloy pressure vessels with an intrinsic log fO2 of NNO + 1 ± 0.5 across a temperature-pressure range of 750-900 °C and 50-200 MPa (PH2O = Ptotal), respectively. Petrologic and geochemical analysis of the post-climactic lithologies shows that the natural phase assemblage (plagioclase + quartz + biotite + sanidine + Fe-Ti oxides ± apatite ± zircon) is stable at history of Cerro Galán is informed through a detailed investigation of the textural differences among the post-climactic dome lithologies, and a comparison of those textures with previously published decompression experiments. These suggest that the highly vesiculated, pumiceous clasts with rare microlites represent magma stored within the core of the lava dome that decompressed relatively rapidly (0.003-0.0003 MPa s-1) and evolved via closed system degassing. Resulting over-pressure of the dome may have triggered superficial explosion. In contrast, dense clasts with abundant crystalline silica precipitates represent more typical

  13. Treatment of Athlete's Plantar Warts Using a Botanical Blend: A Case Report. (United States)

    Nelson, Erik O; Kozin, Adam F; Ruiz, Guillermo; Lasku, Arben; Langland, Jeffrey O


    Context • Viral plantar warts, or verruca plantaris, are a benign epithelial tumor caused by various strains of the human papilloma virus (HPV). Current treatments have had mixed degrees of success, are moderately invasive, and are often incompatible with participation in sports. Objective • The study intended to examine the benefits of treating plantar warts with a topical, botanical blend that has had clinical success treating herpes simplex virus cold sores. Methods • A synergistic botanical blend was applied topically. Setting • The case report was completed at the Southwest College of Naturopathic Medicine (Tempe, Arizona, USA). Participant • The participant was a 24-y-old male soccer player, 177.8 cm tall, and weighing 69 kg with previously diagnosed, viral mosaic warts. Intervention • The patient used a pumice stone during bathing for the first week to remove dead tissue and ensure sufficient contact and entry of the botanical gel into infected tissue. After drying the area, the patient applied the botanical gel blend 1 to 2 times daily postshower, spreading it evenly across the surface of the entire lesion. The patient discontinued the exfoliation technique after the first week. Results • Within the first week of treatment, the patient noted changes to the infected area of the hallux epidermal tissue. The combination of exfoliation and application of the gel caused marked, visible differences in presentation by the fifth day of treatment. At 1-mo postintervention, or day 90, the epidermal tissue was asymptomatic and devoid of petechiae, malformations, or visible infection. Conclusions • The results of the current case study directly contrast with the drawbacks of commonly accepted, first-line interventions in the treatment of viral plantar warts and, in many respects, demonstrate better efficacy and fewer side effects than the standard of care. The positive results also highlight the necessity for additional study in the fields of sports

  14. Top Soils Geochemical and Radioactivity Survey of Naples (Italy) Metropolitan. (United States)

    Somma, R.; De Vivo, B.; Cicchella, D.


    The metropolitan area of Naples due to intense human activities is an emblematic area affected by various environmental pollution of soils and waters in addition to hydrogeological volcanic, seismic and bradyseismic hazards. The geology of the area is prevailing represented by volcanics erupted, from the Upper Pleistocene to Recent by Mt. Somma-Vesuvius on the east and the Campi Flegrei fields on the west. The morphology of the metropolitan area of Naples city can be subdivided in flat areas, constituted by reworked pyroclastic terrains, and by hills originated by the overlapping of different welded pyroclastic flows (i.e.: Campanian Ignimbrite and Neapoletan Yellow Tuff) intercalated with pyroclastic deposits of different origins (i.e.: Campi Flegrei, Mt. Somma-Vesuvius, Ischia) and ages. In order to compile a multi-element baseline geochemical and radioactivity mapping of the metropolitan area of the Napoli we have sampled for this study, in situ top soil and imported filling material (mainly soil, volcanic ash, pumice and scoriae). The sampling and radioactivity survey has been carried out on about 200 sampling sites covering an area of about 150 Km2, with a grid of 0.5 x 0.5 km in the urbanised downtown and 1 km x 1 km in the sub urban areas. In each site has been determined a radioactivity by a Scintrex GRS-500 at different emission spectra as total radioactivity (> 0.08 MeV and > 0.40 MeV), 238U (at 1.76 MeV mostly from 214Bi), 232Th (at 2.6 MeV mostly from 208Tl) and 40K (at 1.46 MeV mostly for 40K). The range of values of in situ soils are as follow for the in situ soils (Total radioactivity: 1327- 360 and 114- 47; 238U: 2.6- 1.3; 40K: 8.1- 3.1; 232U: 0.5- 0.1). Analyses of major, metallic elements and pH of each soil sample are in progress, while Pb isotopes compositions, for a selected number of samples, will be determined to discriminate the natural (geogenic) from the anthropogenic components in the soils by versus the anthropogenetic origin. The data

  15. Tephrostratigraphy of Changbaishan volcano, northeast China, since the mid-Holocene (United States)

    Sun, Chunqing; Liu, Jiaqi; You, Haitao; Nemeth, Karoly


    A detailed tephrostratigraphy of an active volcano is essential for evaluating its eruptive history, forecasting future eruptions and correlation with distal tephra records. Changbaishan volcano is known for its Millennium eruption (ME, AD 940s; VEI 7) and the ME tephra has been detected in Greenland ice cores ∼9000 km from the vent. However, the pre-Millennium (pre-ME) and post-Millennium (post-ME) eruptions are still poorly characterized. In this study, we present a detailed late Holocene eruptive sequence of Changbaishan volcano based on single glass shard compositions from tephra samples collected from around the caldera rim and flanks. Tephra ages are constrained by optically stimulated luminescence (OSL) and AMS 14C dates. Tephra from the mid-Holocene pre-ME eruption can be divided into two pyroclastic fall subunits, and it cannot be correlated with any known Changbaishan-sourced tephra recorded in the Japan Sea based on major element composition of glass shards, such as the B-J (Baegdusan-Japan Basin) and B-V (Baegdusan-Vladivostok-oki) tephras. ME pyroclastic fall deposits from the caldera rims and volcanic flanks can be correlated to the juvenile pumice lapilli or blocks within the pyroclastic density current (PDC) deposits deposited in the valleys around the volcano based on glass shard compositions. Our results indicate that the glass shard compositions of proximal ME tephra are more varied than previously thought and can be correlated with distal ME tephra. In addition, widely-dispersed mafic scoria was ejected by the ME Plinian column and deposited on the western and southern summits and the eastern flank of the volcano. Data for glass from post-ME eruptions, such as the historically-documented AD 1403, AD 1668 and AD 1702 eruptions, are reported here for the first time. Except for the ME, other Holocene eruptions, including pre-ME and post-ME eruptions, had the potential to form widely-distributed tephra layers around northeast Asia, and our dataset

  16. Characteristics of Young Rhyolites at Taupo, New Zealand: Implications for the Sub-Surface Plutonic System (United States)

    Wilson, C. J.; Charlier, B. L.


    The young history of Taupo volcano captures the growth and destruction in the 26.5 ka ca. 530 km3 Oruanui eruption of a large rhyolitic magma body, together with the subsequent rejuvenation of magma sources below the volcano. Integration of field information with petrological and isotopic studies at the whole-pumice and single- crystal scales provide a picture of this history. Several important contrasts are inferred to exist between Taupo and comparably-sized, long-lived silicic foci such at Long Valley and in the Bishop Tuff. At Taupo the following are demonstrable. 1. Even in crystal-poor rhyolites like the Oruanui, many grains are inherited antecrysts or xenocrysts. The Oruanui crystal-poor rhyolite body was an open system, with influxes of crystals (plus melt) from remobilised older crystal mush, melted metasedimentary country rocks and plutonics, and crystal-poor basaltic to andesitic magmas. 2. All the Taupo rhyolites were well mixed prior to eruption, and there are no gradients in the eruption products to suggest that the holding chamber(s) were stratified to any extent. 3. Mafic magmas rose into, interacted with, and ponded on the floors of crystal-poor rhyolite in the Oruanui and Waimihia (3.5 ka) examples, again implying that the chamber floor was sharply defined, not a gradual progression down into a more crystal- rich root zone. 4. Pre-Oruanui activity involved contrasting magma types being generated simultaneously, but erupting from geographically separated vents. Post-Oruanui activity has seen (subtly) contrasting magma groups being erupted from vents in the same geographic area, but separated in time. The Oruanui and post-Oruanui magmas are different and do not appear to be related by consanguinity or by mixing - the Oruanui eruption effectively destroyed its magma body. These features are consistent with rhyolite magma generation at Taupo that is exceptionally fast, driven by high fluxes of mafic magmas into a highly heterogeneous crustal melange

  17. 'tomo_display' and 'vol_tools': IDL VM Packages for Tomography Data Reconstruction, Processing, and Visualization (United States)

    Rivers, M. L.; Gualda, G. A.


    One of the challenges in tomography is the availability of suitable software for image processing and analysis in 3D. We present here 'tomo_display' and 'vol_tools', two packages created in IDL that enable reconstruction, processing, and visualization of tomographic data. They complement in many ways the capabilities offered by Blob3D (Ketcham 2005 - Geosphere, 1: 32-41, DOI: 10.1130/GES00001.1) and, in combination, allow users without programming knowledge to perform all steps necessary to obtain qualitative and quantitative information using tomographic data. The package 'tomo_display' was created and is maintained by Mark Rivers. It allows the user to: (1) preprocess and reconstruct parallel beam tomographic data, including removal of anomalous pixels, ring artifact reduction, and automated determination of the rotation center, (2) visualization of both raw and reconstructed data, either as individual frames, or as a series of sequential frames. The package 'vol_tools' consists of a series of small programs created and maintained by Guilherme Gualda to perform specific tasks not included in other packages. Existing modules include simple tools for cropping volumes, generating histograms of intensity, sample volume measurement (useful for porous samples like pumice), and computation of volume differences (for differential absorption tomography). The module 'vol_animate' can be used to generate 3D animations using rendered isosurfaces around objects. Both packages use the same NetCDF format '.volume' files created using code written by Mark Rivers. Currently, only 16-bit integer volumes are created and read by the packages, but floating point and 8-bit data can easily be stored in the NetCDF format as well. A simple GUI to convert sequences of tiffs into '.volume' files is available within 'vol_tools'. Both 'tomo_display' and 'vol_tools' include options to (1) generate onscreen output that allows for dynamic visualization in 3D, (2) save sequences of tiffs to disk

  18. Tephrostratigraphic studies on a sediment core from Lake Prespa in the Balkans

    Directory of Open Access Journals (Sweden)

    M. Damaschke


    Full Text Available A detailed tephrostratigraphic record, which dates back to Marine Isotope Stage (MIS 5b (ca. 91 kyr, has been established from a 17.76 m long core (Co1215 from Lake Prespa (Macedonia, Albania and Greece. A total of eleven tephra and cryptotephra layers (PT0915-1 to PT0915-11 were identified, using XRF scanning, magnetic susceptibility measurements, and macro- and microscopic inspection of the sediments. The major element composition of glass shards and/or micro-pumice fragments indicates that the tephras and cryptotephras originate from the explosive volcanism of Italy. Eight tephra and cryptotephra layers were correlated with specific volcanic eruptions: the AD 512 eruption of Somma-Vesuvius (1438 cal yr BP, the Mercato eruption of Somma-Vesuvius (8890 ± 90 cal yr BP, the Tufi Biancastri/LN1-LN2 eruption of the Campi Flegrei (14 749 ± 523 cal yr BP and 15 551 ± 621 cal yr BP, the SMP1-e/Y-3 eruption of the Campi Flegrei (30 000–31 000 cal yr BP, the Campanian Ignimbrite/Y-5 eruption of the Campi Flegrei (39 280 ± 110 cal yr BP, the SMP1-a event of Ischia Island (around 44 000 cal yr BP and the Green Tuff/Y-6 eruption of Pantelleria Island (around 45 000 cal yr BP. One tephra could be attributed to the volcanic activity of Mount Etna, but probably represents an unknown eruption at ca. 60 000 cal yr BP. Cryptotephras PT0915-6 and PT0915-10 remain unclassified so far, but according to the presented age-depth model these would have been deposited around 35 000 and 48 500 cal yr BP, respectively. Some of the tephras and cryptotephras are recognised for the first time in the Balkan region. The tephrostratigraphic work provides important information about ash dispersal and explosion patterns of source volcanoes and can be used to correlate and date geographically distant paleoenvironmental and archaeological archives in the central Mediterranean region. Moreover, the tephrostratigraphic work in combination with radiocarbon and electron spin

  19. Pressure Changes before and after Explosive Rhyolitic Bomb Ejection at Chaiten, Chile Recorded By Water Diffusion Profiles Around Tuffisite Veins (United States)

    Tuffen, H.; McGowan, E.; Castro, J. M.; Berlo, K.; James, M. R.; Owen, J.; Schipper, C. I.; Wadsworth, F. B.; Saubin, E.; Wehbe, K.


    The recent rhyolitic eruptions at Chaitén and Cordón Caulle have provided valuable new insights into the relationship between explosive and effusive activity, and the gas escape mechanisms that permit rapid effusion of degassed lava[1,2]. Bombs ejected during mixed explosive-effusive activity host spectacular tuffisite veins cutting both dense obsidian (Fig 1a) and highly-expanded pumice. Tuffisite veins are ash-filled fracture networks that act as ephemeral permeable pathways for gas escape in shallow conduits and lava domes. Previous studies have revealed water depletion adjacent to tuffisite veins, leading to models of fracture-triggered pressure release[2] and estimates of gas escape timescales[2,3]. We have characterised water diffusion profiles from a new suite of tuffisite-bearing Chaitén bombs, using synchrotron-source FTIR at the Diamond Light Source, Oxford, UK. Unexpectedly, one exceptionally large tuffisite vein, which is 30 mm thick (Fig. 1a, b) is mantled by zones of strong water enrichment, which enclose the usual narrow depletion zones immediately adjacent to the vein (Fig. 1c). Consistent results from different branches of this vein (Fig. 1b) indicate a similar history. The plausible range of diffusion model solutions points towards ~2-4 hours of vein pressurisation, followed by a brief pre-quench period of lower pressure conditions. In our model the vein opened during a period of overpressure at the lava dome base, sustained by gas influx from a deeper catchment extending hundreds of metres into the upper conduit. Overpressure culminated in violent bomb ejection, after which vein pressure decreased due to gas leakage to the atmosphere through the incompletely welded vein, as observed in rhyolitic bombs from Cordón Caulle (Fig. 1d). Commonly-seen water depletion zones[2,3] may therefore merely record post-fragmentation degassing. However, the enrichment zone points towards the type of deep pressurisation associated with cycles of tilt and

  20. Experimental Determination of Bed Conditions in Concentrated Pyroclastic Density Currents (United States)

    Winner, A.; Ferrier, K.; Dufek, J.


    Pyroclastic density currents (PDCs) are ground-hugging mixtures of hot gas and rock that can reach temperatures > 800 oC and speeds of 200 m/s. These flows are capable of eroding and entraining the underlying bed material into the flow, which can strongly influence flow momentum, runout distance, and hazards associated with PDCs. However, the mechanism of erosion remains poorly constrained, with proposed mechanisms including under-pressure following the head of the fluidized current, force chain enhanced stresses at the bed, and discrete particle impacts and friction. The interactions between PDCs and the bed have been difficult to observe in the field, as their infrequent occurrence, opacity, and hostile environment make real-time measurement difficult. This study is aimed at obtaining a better understanding of the interactions between PDCs and the bed through a quantitative analysis of bed forces. Our experimental apparatus consists of a rotating cylindrical flume of radius 22 cm, within which gas-rich granular material flows along the interior of the cylinder as it rotates. By using a rotating cylinder, we are able to simulate long-duration flows, allowing us to observe impact forces at the bed over timescales comparable to the flow duration of natural PDCs. To measure the distribution and evolution of forces imparted by the flow on the bed, we constructed a cylindrical insert with a non-erodible bed in which we embedded force sensor arrays parallel and perpendicular to the direction of flow. To measure the forces felt by the particles in the flow, we added "smart particles" 25 to 50 mm in diameter to the flow. Each smart particle contains a three-axis accelerometer and a micro SD card enclosed in a spherical plastic casing, and possesses a density similar to that of the pumice in the experimental flow. Each smart particle also contains a three-axis magnetometer which permits its location to be tracked by means of a unique applied magnetic field. Ultimately

  1. Composite volcanoes in the south-eastern part of İzmir-Balıkesir Transfer Zone, Western Anatolia, Turkey (United States)

    Seghedi, Ioan; Helvacı, Cahit; Pécskay, Zoltan


    During the Early-Middle Miocene (Western Anatolia) several volcanic fields occur along a NE-SW-trending shear zone, known as İzmir-Balıkesir Transfer Zone. This is a deformed crustal-scale sinistral strike-slip fault zone crossing the Bornova flysch and extending along the NW-boundary of the Menderes Massif by accommodating the differential deformation between the Cycladic and Menderes core complexes within the Aegean extensional system. Here we discuss the volcanic activity in Yamanlar and Yuntdağı fields that is closely related to the extensional tectonics of the İzmir-Balıkesir Transfer Zone and in the same time with the episodic core complex denudation of the Menderes Massif. This study documents two composite volcanoes (Yamanlar and Yuntdağı), whose present vent area is strongly eroded and cut by a variety of strike-slip and normal fault systems, the transcurrent NW-SE being the dominant one. The erosional remnants of the vent areas, resembling a shallow crater intrusive complex, illustrate the presence of numerous dykes or variably sized neck-like intrusions and lava flows, typically associated with hydrothermal alteration processes (propylitic and argillic). Such vent areas were observed in both the examined volcanic fields, having ~ 6 km in diameter and being much more eroded toward the south, along the NW-SE fault system. Lava flows and lava domes are sometimes associated with proximal block and ash flow deposits. In the cone-building association part, besides lava flows and remnants of lava domes, rare block and ash and pumice-rich pyroclastic flow deposits, as well as a series of debris-flow deposits, have been observed. The rocks display a porphyritic texture and contain various proportions of plagioclase, clinopyroxene, orthopyroxene, amphibole, rare biotite and corroded quartz. The examined rocks fall at the limit between calc-alkaline to alkaline field, and plot predominantly in high-K andesite and dacite fields and one is rhyolite. The trace

  2. The grain-size distribution of pyroclasts: Primary fragmentation, conduit sorting or abrasion? (United States)

    Kueppers, U.; Schauroth, J.; Taddeucci, J.


    of magma fragmentation at or close to the fragmentation level. Given the high abrasiveness of pumice, hemispherical clasts should be observed if clast break-up followed efficient clast abrasion. As a consequence, finer grained pyroclastic fall deposits do not necessarily proof efficient secondary fragmentation in the conduit but may rather reveal the influence of conduit length on 'What size of pyroclasts can be erupted'?

  3. The three youngest Plinian eruptions of Mt Pelée, Martinique (P1, P2 and P3): Constraining the eruptive conditions from field and experimental studies. (United States)

    Kueppers, Ulrich; Uhlig, Joan; Carazzo, Guillaume; Kaminski, Edouard; Perugini, Diego; Tait, Steve; Clouard, Valérie


    Mt Pelée on Martinique, French Lesser Indies, is infamous for the last big Pelean (i.e., dome forming) eruption in 1902 AD that destroyed agricultural land and the city of Saint Pierre by pyroclastic density currents. Beside such mostly valley-confined deposits, the geological record shows thick fall deposits of at least three Plinian eruptions during the past 2000 years. In an attempt to describe and understand systematic eruptive behaviours as well as the associated variability of eruptive scenarios of Plinian eruptions in Martinique, we have investigated approx. 50 outcrops belonging to the P1 (1315 AD), P2 (345 AD) and P3 (4 AD) eruptions (Traineau et al., JVGR 1989) and collected bulk samples as well as >100 mm pumiceous clasts. All samples are andesitic, contain plagioclase and pyroxene in a glassy matrix and range in porosity between 55 and 69 vol.% with individual bubbles rarely larger than 1 mm. Our approach was two-fold: 1) Loose bulk samples have been subject to dry mechanical sieving in order to quantively describe the grain-size distribution and the fractal dimension. 2) From large clasts, 60*25 mm cylinders have been drilled for fragmentation experiments following the sudden decompression of gas in the sample's pore space. The used experimental set-up allowed for precisely controllable and repeatable conditions (5, 10 and 15 MPa, 25 °C) and the complete sampling of the generated pyroclasts. These experimentally generated clasts were analysed for their grain-size distribution and fractal dimension. For both natural samples and experimental populations, we find we find that the grain-size distribution follows a power-law, with an exponent between 2,5 and 3,7. Deciphering eruption conditions from deposits alone is challenging because of the complex interplay of dynamic volcanic processes and transport-related sorting. We use the quantified values of fractal dimension for a comparison of the power law exponents among the three eruptions and the

  4. Eruption and Degassing Processes in a Supervolcanic System: The Volatile Record Preserved in Melt Inclusions from the 3.49Ma Tara Ignimbrite in the Central Andes (United States)

    Grocke, S.; de Silva, S. L.; Schmitt, A. K.; Wallace, P. J.


    Analysis of H2O and CO2 in quartz and sanidine-hosted melt inclusions from one of the youngest supervolcanic eruptions in the Altiplano Puna Volcanic Complex (APVC) in the Central Andes provides information on crystallization depths and eruption and degassing processes. At least 740 km3 of high-K, metaluminous, rhyodacite to rhyolite magma erupted from the Guacha Caldera in southwest Bolivia, producing three phases of the 3.49 Ma Tara Ignimbrite: a Plinian fall-deposit, an extensive ignimbrite, and several post-caldera domes. Infrared spectroscopic analyses of quartz-hosted melt inclusions from Tara Plinian pumice have H2O contents of ~4.5 wt % and variable CO2 contents (110-300 ppm), corresponding to vapor saturation pressures up to 180 MPa. In contrast, sanidine-hosted melt inclusions from the Plinian-fall deposit contain bubbles, lower water contents (1.4-2.2 wt %) and lower CO2 (87-143 ppm). These vesiculated melt inclusions and low volatile contents suggest that the sanidine crystals leaked on their ascent to the surface and therefore do not record accurate pre-eruptive melt volatile contents. In contrast, quartz-hosted melt inclusions from post-caldera dome samples contain lower H2O contents of 2.5-3.5 wt % (average 2.9 wt %) and no detectable CO2, corresponding to vapor saturation pressures of 50-90 MPa. These data indicate that the preeruptive plinian stage Tara magma was vapor saturated at the time of melt inclusion entrapment and stored between 5-6 km, while those from the post-caldera domes were trapped at 2-3 km. Differences in CO2 between Plinian and dome melt inclusions require that the post-caldera dome quartzes represent a different generation of crystals that grew as the magma slowly rose and progressively degassed at 2-3 km. During this shallow crystallization, the magma evolved further and eventually fed the post-caldera domes, one of which is a high-Si rhyolite. Consistent with this interpretation, melt inclusions from post-caldera dome samples

  5. The origin of a coarse lithic breccia in the 34 ka caldera-forming Sounkyo eruption, Taisetsu volcano group, central Hokkaido, Japan (United States)

    Yasuda, Y.; Suzuki-Kamata, K.


    The 34 ka Sounkyo eruption produced 7.6 km3 of tephra ( 5 km3 DRE) as fallout, ignimbrite, and lithic breccia units, forming a small, 2-km-diameter summit caldera in the Taisetsu volcano group, Japan. The Sounkyo eruption products are made up of five eruptive units (SK-A to -E) in proximal regions, corresponding to the distal deposits, a 1- to 2-m-thick pumice fallout and the Px-type ignimbrite up to 220 m thick. The eruption began with a fallout phase, producing unstable low eruption columns during the earlier phase to form a 27-m-thick, unstratified and ungraded, coarse lithic breccia (SK-C). The failure in turn choked the conduit, and then the eruption stopped. After a short eruptive hiatus, the eruption resumed with a short-lived fall phase, establishing an eruption column up to 16 km high and producing a <6-m-thick scoria fallout (SK-D). Finally, the eruption ended with the generation of PDCs by eruption column collapse to form a 5- to 15-m-thick ignimbrite in the proximal area (SK-E). Volume relationships between the caldera, ejected magma, and ejected lithic fragments suggest that the caldera was not essentially formed by caldera collapse but, instead, by vent widening as a consequence of explosive erosion and failure of the shallow conduit. The dominance of shallow-origin volcanic rocks in the lithic fraction throughout the Sounkyo eruption products implies the development of a flaring funnel-shaped vent. Hence, the occurrence of lithic breccias within small caldera-forming eruption products does not necessarily reflect either the existence or the timing of caldera collapse, as commonly assumed in literature. Lithic breccias commonly overlie climactic ignimbrite/fallout deposits in small caldera-forming eruptions, and an alternative explanation is that this reflects the collapse of the shallow conduit after an eruption climax, whose walls had been highly fractured and had become unstable owing to progressive erosion.

  6. Soil and crop management experiments in the Laboratory Biosphere: An analogue system for the Mars on Earth ® facility (United States)

    Silverstone, S.; Nelson, M.; Alling, A.; Allen, J. P.

    During the years 2002 and 2003, three closed system experiments were carried out in the "Laboratory Biosphere" facility located in Santa Fe, New Mexico. The program involved experimentation of "Hoyt" Soy Beans, (experiment #1) USU Apogee Wheat (experiment #2) and TU-82-155 sweet potato (experiment #3) using a 5.37 m 2 soil planting bed which was 30 cm deep. The soil texture, 40% clay, 31% sand and 28% silt (a clay loam), was collected from an organic farm in New Mexico to avoid chemical residues. Soil management practices involved minimal tillage, mulching, returning crop residues to the soil after each experiment and increasing soil biota by introducing worms, soil bacteria and mycorrhizae fungi. High soil pH of the original soil appeared to be a factor affecting the first two experiments. Hence, between experiments #2 and #3, the top 15 cm of the soil was amended using a mix of peat moss, green sand, humates and pumice to improve soil texture, lower soil pH and increase nutrient availability. This resulted in lowering the initial pH of 8.0-6.7 at the start of experiment #3. At the end of the experiment, the pH was 7.6. Soil nitrogen and phosphorus has been adequate, but some chlorosis was evident in the first two experiments. Aphid infestation was the only crop pest problem during the three experiments and was handled using an introduction of Hyppodamia convergens. Experimentation showed there were environmental differences even in this 1200 cubic foot ecological system facility, such as temperature and humidity gradients because of ventilation and airflow patterns which resulted in consequent variations in plant growth and yield. Additional humidifiers were added to counteract low humidity and helped optimize conditions for the sweet potato experiment. The experience and information gained from these experiments are being applied to the future design of the Mars On Earth ® facility (Silverstone et al., Development and research program for a soil

  7. Volcanic geology and eruption frequency, São Miguel, Azores (United States)

    Moore, Richard B.


    Six volcanic zones comprise São Miguel, the largest island in the Azores. All are Quaternary in age except the last, which is partly Pliocene. From west to east the zones are (1) the trachyte stratovolcano of Sete Cidades, (2) a field of alkali-basalt cinder cones and lava flows with minor trachyte, (3) the trachyte stratovolcano of Agua de Pau, (4) a field of alkali-basalt cinder cones and lava flows with minor trachyte and tristanite, (5) the trachyte stratovolcano of Furnas, and (6) the Nordeste shield, which includes the Povoação caldera and consists of alkali basalt, tristanite, and trachyte. New radiocarbon and K-Ar ages augment stratigraphic data obtained during recent geologic mapping of the entire island and provide improved data to interpret eruption frequency. Average dormant intervals for the past approximately 3000 years in the areas active during that time are about 400 years for Sete Cidades, 145 for zone 2, 1150 for Agua de Pau, and 370 for Furnas. However, the average dormant interval at Sete Cidades increased from 400 to about 680 years before each of the past two eruptions, and the interval at Furnas decreased from 370 to about 195 years before each of the past four eruptions. Eruptions in zone 4 occurred about once every 1000 years during latest Pleistocene and early Holocene time; none has occurred for about 3000 years. The Povoação caldera truncates part of the Nordeste shield and probably formed during the middle to late Pleistocene. Calderas formed during latest Pleistocene time at the three younger stratovolcanoes in the sequence: outer Agua de Pau (between 46 and 26.5 ka), Sete Cidades (about 22 ka), inner Agua de Pau (15.2 ka), and Furnas (about 12 ka). Normal faults are common, but many are buried by Holocene trachyte pumice. Most faults trend northwest or west-northwest and are related to the Terceira rift, whose most active segment on São Miguel passes through Sete Cidades and zone 2. A major normal fault displaces Nordeste

  8. The Tephra Layer From the Plinian Eruption in ™r‘faj”kull 1362, Southeast Iceland (United States)

    Selbekk, R. S.


    Pyroclastic fallout from the 1362 eruption of ™r‘faj”kull forms one of the volcanic marker horizons of the North Atlantic. This contribution reports the mineralogical and geochemical characteristics of the ™r‘faj”kull 1362 fallout and its grain-size distribution. A non-rifting 120 km long volcanic lineament some 50 km east of the Eastern Rift-Zone of Iceland is defined by transitional and alkalic volcanic rocks resting unconformably on late Tertiary strata. ™r‘faj”kull which forms the southern termination of this off-rift liniment is an ice-covered stratovolcano (2200 masl) composed mostly of subglacially formed hyaloclastite ranging from basalts to rhyolites. The two historical (1100 yrs) eruptions of ™r‘faj”kull include a small explosive eruption in 1727 and a large devastating Plinian eruption associated with major lahars and a caldera collapse in 1362. Between 1 and 2 km3 dense rock equivalent or 5-10 km3 of rhyolitic pumice was erupted and the fallout was mainly towards ESE. Tentative modelling of the PT-conditions of the magma formation, based on glass/mineral equilibria, indicates that the source was a near-eutectic melt in equilibrium with fayalite, hedenbergite, oligoclase and hematite at some 0.2 GPa pressure. A profile through the fallout was sampled at elevation of about 1100 masl on the SE flank of the volcano. A deposit of 1.8 m thickness was collected in 14 units for examination of composition, mineralogy and grain-size distribution during the eruption. In the profile the fallout is fine grained vesicular glass (1-3% minerals, 3% lithic fragments) with bubble wall thickness in the low micron range. The high and even vesiculation of the glass indicates fast magma ascent and explains the extreme mechanical fragmentation within the eruptive column, yielding between 50 and 80 wt% of less than 0.25 mm grain size. A reconstruction of the Plinian phase, based on grain-size analysis and abundance of lithic fragments, reveals that the

  9. Temporal evolution of the Roccamonfina volcanic complex (Pleistocene), Central Italy (United States)

    Rouchon, V.; Gillot, P. Y.; Quidelleur, X.; Chiesa, S.; Floris, B.


    The Roccamonfina volcanic complex (RVC), in southern Italy, is an Early to Middle Pleistocene stratovolcano sharing temporal and morphological characteristics with the Somma-Vesuvius and the Alban Hills; both being associated with high volcanic hazard for the cities of Naples and Rome, respectively. The RVC is important for the understanding of volcanic evolution in the Roman and Campanian volcanic provinces. We report a comprehensive study of its evolution based on morphological, geochemical and K-Ar geochronological data. The RVC was active from c.a. 550 ka to 150 ka. Its evolution is divided into five stages, defining a volcanic pulse recurrence time of c.a. 90-100 kyr. The two initial stages, consisted in the construction of two successive stratovolcanoes of the tephrite-phonolite, namely "High-K series". The first stage was terminated by a major plinian eruption emplacing the trachytic Rio Rava pumices at 439 ± 9 ka. At the end of the second stage, the last High-K series stratovolcano was destroyed by a large sector collapse and the emplacement of the Brown Leucitic Tuff (BLT) at 353 ± 5 ka. The central caldera of the RVC is the result of the overlapping of the Rio Rava and of the BLT explosions. The plinian eruption of the BLT is related to the emptying of a stratified, deep-seated HKS magma chamber during the upwelling of K series (KS) magma, marking a major geochemical transition and plumbing system re-organization. The following stage was responsible for the emplacement of the Lower White Trachytic Tuff at 331 ± 2 ka, and of basaltic-trachytic effusive products erupted through the main vent. The subsequent activity was mainly restricted to the emplacement of basaltic-shoshonitic parasitic cones and lava flows, and of minor subplinian deposits of the Upper White Trachytic Tuff between 275 and 230 ka. The northern crater is most probably a maar that formed by the phreatomagmatic explosion of the Yellow Trachytic Tuff at 230 ka. The latest stage of

  10. Single-crystal 40Ar/39Ar incremental heating reveals bimodal sanidine ages in the Bishop Tuff (United States)

    Andersen, N. L.; Jicha, B. R.; Singer, B. S.


    The 650 km3 Bishop Tuff (BT) is among the most studied volcanic deposits because it is an extensive marker bed deposited just after the Matuyama-Brunhes boundary. Reconstructions of the vast BT magma reservoir from which high-silica rhyolite erupted have long influenced thinking about how large silicic magma systems are assembled, crystallized, and mixed. Yet, the longevity of the high silica rhyolitic melt and exact timing of the eruption remain controversial due to recent conflicting 40Ar/39Ar sanidine vs. SIMS and ID-TIMS U-Pb zircon dates. We have undertaken 21 40Ar/39Ar incremental heating ages on 2 mm BT sanidine crystals from pumice in 3 widely separated outcrops of early-erupted fall and flow units. Plateau ages yield a bimodal distribution: a younger group has a mean of 766 ka and an older group gives a range between 772 and 782 ka. The younger population is concordant with the youngest ID-TIMS and SIMS U-Pb zircon ages recently published, as well as the astronomical age of BT in marine sediment. Of 21 crystals, 17 yield older, non-plateau, steps likely affected by excess Ar that would bias traditional 40Ar/39Ar total crystal fusion ages. The small spread in older sanidine ages, together with 25+ kyr of pre-eruptive zircon growth, suggest that the older sanidines are not partially outgassed xenocrysts. A bimodal 40Ar/39Ar age distribution implies that some fraction of rhyolitic melt cooled below the Ar closure temperature at least 10 ky prior to eruption. We propose that rapid "thawing" of a crystalline mush layer released older crystals into rhyolitic melt from which sanidine also nucleated and grew immediately prior to the eruption. High precision 40Ar/39Ar dating can thus provide essential information on thermo-physical processes at the millenial time scale that are critical to interpreting U-Pb zircon age distributions that are complicated by large uncertainties associated with zircon-melt U-Th systematics.

  11. Centre of nuclear research experience in the control of personal exposition between 2002 - 2006

    International Nuclear Information System (INIS)

    Bayardo, Karina; Blanco, Daniel; Garcia, Fernando


    Full text: The control of the personal exposition in the public University is done by the Centre of Nuclear Research since 1999. A look at the last years permitted to note the increase in the Personal Dosimeter users. In this work we study the annual collective dose, the annual effective dose average and the different dose in each University area between 2002-2005. The annual effective dose limit for the Nuclear Regulatory Authority (Autoridad Reguladora Nuclear), are the suggested by the International Commission of Radiological Protection (ICRP). The actual application of the Basics Principles of Radiological Protection demand exposition levels as low as reasonable achievable (ALARA) considering economics and social factors. In this way we decrease the probability to induce illness in the expose personal and their descendants. The different dependences of the University where the service is given are: Faculty of Medicine (Radiology, Oncology, Clinical Oncology, Nuclear Medicine), Faculty of Chemistry (Radiochemistry), Faculty of Odontology (Radiology), Faculty of Veterinary (Radiology) and Faculty of Sciences (Centre of Nuclear Research). The number of users between 2002-2006 varied from 292 in year 2002 to 329 in the year 2006. We see a maximum of persons in the year 2004. The annual collective dose have been changing too, the lowest was 0.13 Sv.person in the year 2002 and the highest was 0.21 Sv.person in the year 2005. The annual collective dose permits the evaluation of the radiological impact of the radiation ionising manipulation in the University. In these 5 years the 96% of the annual effective dose average were under 4 mSv, and the 76% were smaller than the minimum detectable limit. This 76% were obtained in teach and researches areas. In the 4% higher than 4 mSv we can find areas where works with open radioactive sources like: Nuclear Medicine and Radiochemistry (Faulted de Pumice). In these places we detect annual effective doses of 15 mSv, these levels

  12. Geogenic fluoride and arsenic contamination in the groundwater environments in Tanzania (United States)

    Bhattacharya, Prosun; Lesafi, Fina; Filemon, Regina; Ligate, Fanuel; Ijumulana, Julian; Mtalo, Felix


    materials such as pumice, bauxite, ferralsols and bone char. Developing innovative technologies, pilot-scale implementation and scaling-up water purification based on the locally available adsorbents is thus necessary to safeguard the public health for communities exposed to high levels of fluoride and arsenic in drinking water.

  13. Uranium Exploration in Paipa and Iza Area, Colombia: A Preliminary Report of New Contributions

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Oviedo, L., E-mail: [Mineral Resources Area — INGEOMINAS, Bogotá (Colombia)


    This paper shows the preliminary results from uranium exploration of the Boyacá Department, for the first survey conducted by the Colombian state after 26 years. The exploration was carried out this year and the zone covers an area of 460 square kilometers divided into three sectors, located in the municipalities of Sogamoso Paipa, Iza, Tota and Pesca, Chivata and Tuta. The area is dominated by Cretaceous-Tertiary sedimentary rocks Quaternary sediments. Paipa and Iza exposes outcrops volcanic and sedimentary rocks; and the major structural features are Arcabuco anticline, Los Medios syncline and Boyaca and Soapaga faults. The sedimentary formations from the oldest to most recent in the area are: Tibasosa Formation; Une Formation, Conejo Formation; Plaeners Formation; Los Pinos Formation; Labor y Tierna Formation, Guaduas Formation Socha Formation; Picacho Formation an Concentration Formation; in the area outcrops also, volcanic rocks (rhyolites porphyrites and andesites); and explosive (pumices). In the Paipa Area, three anomalous sites (Durazno, Quebrada Honda and Casa Blanca) were found with values ranging between 440 and 7 500 counts/s, the highest values were reported in the Durazno area. The host rocks are volcanic rocks (tophus) and tectonic breccias with thin strips of coal from the Guaduas Formation. In 1979 the studies by ENUSA (Spain) reported values up to 3 800 counts/s. In Iza, five anomalous zones (El Crucero, San Miguel, Cuitiva — Iza, Erika and Tota — Pesca) was found with values ranging between 480 and 4 480 counts/s. Host rocks are igneous rocks in Erika sector; and phosphates in El Crucero sector with a maximum value of 2 100 counts/s. In shot holes made in Iza the values went up from 1 200 counts/s in surface to 4 480 counts/s in depth (1.60 m). In Paipa, the values incerased from 4 500 in surface to 7 500 counts/s at 1.50 meters. Chemical analysis, of samples from “El Durazno” records values between 200 and 5 345 ppm so that this year

  14. Violent Explosive Eruptions in the Ararat Valley, Armenia and Associated Volcanic Hazards (United States)

    Meliksetian, Khachatur; Savov, Ivan; Connor, Charles; Gevorgyan, Hripsime; Connor, Laura; Navasardyan, Gevorg; Manucharyan, Davit; Jrbashyan, Ruben; Ghukasyan, Yura


    The Anatolian-Armenian-Iranian volcanically active orogenic plateau is located in the collision zone between the Arabian and Eurasian plates. The majority of regional geodynamic and petrologic models of collision-related magmatism use the model proposed by Keskin (2003), where volcanism is driven by Neo-Tethyan slab break-off, however an updated model by Neill et al. (2015) and Skolbeltsyn et al.(2014) comprise break-off of two slabs. One of the significant (and understudied) features of the regionally extensive collision zone volcanism is the diversity of eruption styles and also the presence of large number of highly explosive (Plinian) eruptions with VEI≥5 during the Middle-Upper Pleistocene. Geological records of the Ararat depression include several generations of thick low aspect ratio Quaternary ignimbrites erupted from Aragats volcano, as well as up to 3 m thick ash and pumice fall deposit from the Holocene-historically active Ararat volcano. The Ararat tephra fall deposit is studied at 12 newly discovered outcrops covering an area ˜1000 km2. It is noteworthy, that the Ararat tephra deposits are loose and unwelded and observed only in cross-sections in small depressions or in areas where they were rapidly covered by younger, colluvium deposits, presumably of Holocene age. Therefore, the spatial extent of the explosive deposits of Ararat is much bigger but not well preserved due to rapid erosion. Whole rock elemental, isotope (Sr, Nd) and mineral chemistry data demonstrate significant difference in the magma sources of the large Aragats and Ararat stratovolcanoes. Lavas and pyroclastic products of Aragats are high K calc-alkaline, and nearly always deprived from H2O rich phases such as amphibole. In contrasts lavas and pyroclastic products from Ararat are medium K calc-alkaline and volatile-rich (>4.6 wt% H2O and amphibole bearing) magmas. Here we shall attempt to reveal possible geochemical triggers of explosive eruptions in these volcanoes and assess

  15. Paleoproterozoic volcanism in the southern Amazon Craton (Brazil): insight into its origin and deposit textures (United States)

    Roverato, Matteo; Juliani, Caetano


    The Brazilian Amazon craton hosts a primitive volcanic activity that took place in a region completely stable since 1.87 Ga. The current geotectonic context is very different from what caused the huge volcanism that we are presenting in this work. Volcanic rocks in several portions of the Amazon craton were grouped in the proterozoic Uatumã supergroup, a well-preserved magmatic region that covers an area with more than 1,200,000 km2. In this work one specific region is considered, the southwestern Tapajos Gold province (TGP) that is part of the Tapajós-Parina tectonic province (Tassinari and Macambri, 1999). TGP consists of metamorphic, igneous and sedimentary sequences resulted from a ca. 2.10-1.87 Ga ocean-continent orogeny. High-K andesites to felsic volcanic sequences and plutonic bodies, andesitic/rhyolitic epiclastic volcanic rocks and A-type granitic intrusions form part of this volcanism/plutonism. In this work we focus particularly our attention on welded, reomorphic and lava-like rhyolitic ignimbrites and co-ignimbrite brecchas. Fiamme texture of different welding intensity, stretched obsidian fragments, "glassy folds", relict pumices, lithics, rotated crystals of feldspars, bipiramidal quarz, and devetrification spherulites are the common features represented by our samples. Microscopical images are provided to characterize the deposits analyzed during this preliminary research. The lack of continuum outcrops in the field made more difficult the stratigraphic reconstruction, but the superb preservation of the deposits, apparently without any metamorphic evidences (not even low-grade), permits a clearly description of the textures and a differentiation between deposits. A detailed exploration of this ancient andesitic and rhyolitic volcanic activity could contribute greatly to the knowledge of the Amazon territory and in particular for the recognition of the various units that form the supergroup Uatumã, especially in relation to different eruptive

  16. Stratigraphy and Facies Analysis of a 122 M Long Lacustrine Sequence from Chalco Lake, Central Mexico (United States)

    Herrera, D. A.; Ortega, B.; Caballero, M.; Lozano, S.; Pi, T.; Brown, E. T.


    Chalco lake is located SE of the outskirts of Mexico City, at the central part of the Trans Mexican Volcanic Belt. Previous studies show the importance of this lacustrine sequence as an archive of paleoenvironmental and paleoclimatic changes. A set of five cores up to 122 m depth were drilled in the basin, in order to analyze the sedimentary record and to extent the previous knowledge of past environmental changes in central Mexico. As an initial step, in this work we present the identification and classification of sedimentary facies. Preliminary paleomagnetism analyses recognize the possible record of the Blake Event (ca. 120 kyr BP), and suggest that the sequence might span the last 240 kyr. In this case, variations in sedimentary facies could reflect the conditions of the MIS 1-7. The facies are mostly diatom ooze, carbonate mud, organic rich silt and volcaniclastic, both massive and laminated, and massive dark gray to reddish brown silt. From 1 to 8 m depth dominates the organic rich silt facies, which correlates with the MIS 1. Intercalations of reddish brown and grayish brown silt facies, between 8 to 60 m depth, indicate changes occurred during MIS 2 to 5d. Between 60-75 m depth the sequence is characterized by dark grayish silty clay facies, which possibly coincide with the MIS 5e. At 79 m depth (ca. 130 kyr BP) we found struvite (MgNH4PO4.6H2O), which may be related to dry conditions. The laminated diatom ooze facies dominates between 90 to 122 m depth and indicates rhythmic changes in the sediment deposition of the basin. The volcaniclastic facies is represented by lapilli and ash deposits in more than 100 individual tephra layers of both mafic and felsic composition. Some of them correspond to main volcanic eruptions, as the Upper Toluca Pumice (13,500 cal yr BP), from the Nevado de Toluca volcano and the Pómez con Andesita (17,700 cal yr BP) from the Popocatépetl volcano. The carbonate mud facies is composed of calcite and siderite, with frequent

  17. Extensive, water-rich magma reservoir beneath southern Montserrat (United States)

    Edmonds, M.; Kohn, S. C.; Hauri, E. H.; Humphreys, M. C. S.; Cassidy, M.


    South Soufrière Hills and Soufrière Hills volcanoes are 2 km apart at the southern end of the island of Montserrat, West Indies. Their magmas are distinct geochemically, despite these volcanoes having been active contemporaneously at 131-129 ka. We use the water content of pyroxenes and melt inclusion data to reconstruct the bulk water contents of magmas and their depth of storage prior to eruption. Pyroxenes contain up to 281 ppm H2O, with significant variability between crystals and from core to rim in individual crystals. The Al content of the enstatites from Soufrière Hills Volcano (SHV) is used to constrain melt-pyroxene partitioning for H2O. The SHV enstatite cores record melt water contents of 6-9 wt%. Pyroxene and melt inclusion water concentration pairs from South Soufriere Hills basalts independently constrain pyroxene-melt partitioning of water and produces a comparable range in melt water concentrations. Melt inclusions recorded in plagioclase and in pyroxene contain up to 6.3 wt% H2O. When combined with realistic melt CO2 contents, the depth of magma storage for both volcanoes ranges from 5 to 16 km. The data are consistent with a vertically protracted crystal mush in the upper crust beneath the southern part of Montserrat which contains heterogeneous bodies of eruptible magma. The high water contents of the magmas suggest that they contain a high proportion of exsolved fluids, which has implications for the rheology of the mush and timescales for mush reorganisation prior to eruption. A depletion in water in the outer 50-100 μm of a subset of pyroxenes from pumices from a Vulcanian explosion at Soufrière Hills in 2003 is consistent with diffusive loss of hydrogen during magma ascent over 5-13 h. These timescales are similar to the mean time periods between explosions in 1997 and in 2003, raising the possibility that the driving force for this repetitive explosive behaviour lies not in the shallow system, but in the deeper parts of a vertically

  18. Volcanism at 1.45 Ma within the Yellowstone Volcanic Field, United States (United States)

    Rivera, Tiffany A.; Furlong, Ryan; Vincent, Jaime; Gardiner, Stephanie; Jicha, Brian R.; Schmitz, Mark D.; Lippert, Peter C.


    Rhyolitic volcanism in the Yellowstone Volcanic Field has spanned over two million years and consisted of both explosive caldera-forming eruptions and smaller effusive flows and domes. Effusive eruptions have been documented preceding and following caldera-forming eruptions, however the temporal and petrogenetic relationships of these magmas to the caldera-forming eruptions are relatively unknown. Here we present new 40Ar/39Ar dates for four small-volume eruptions located on the western rim of the second-cycle caldera, the source of the 1.300 ± 0.001 Ma Mesa Falls Tuff. We supplement our new eruption ages with whole rock major and trace element chemistry, Pb isotopic ratios of feldspar, and paleomagnetic and rock magnetic analyses. Eruption ages for the effusive Green Canyon Flow (1.299 ± 0.002 Ma) and Moonshine Mountain Dome (1.302 ± 0.003 Ma) are in close temporal proximity to the eruption age of the Mesa Falls Tuff. In contrast, our results indicate a period of volcanism at ca 1.45 Ma within the Yellowstone Volcanic Field, including the eruption of the Bishop Mountain Flow (1.458 ± 0.002 Ma) and Tuff of Lyle Spring (1.450 ± 0.003 Ma). These high-silica rhyolites are chemically and isotopically distinct from the Mesa Falls Tuff and related 1.3 Ma effusive eruptions. The 40Ar/39Ar data from the Tuff of Lyle Spring demonstrate significant antecrystic inheritance, prevalent within the upper welded ash-flow tuff matrix, and minimal within individual pumice. Antecrysts are up to 20 kyr older than the eruption, with subpopulations of grains occurring every few thousand years. We interpret these results as an indicator for the timing of magmatic pulses into a growing magmatic system that would ultimately erupt the Tuff of Lyle Spring, and which we more broadly interpret as the tempo of crustal accumulation associated with bimodal magmatism. We propose a system whereby chemically, isotopically, and temporally distinct, isolated small-volume magma batches are

  19. Understanding the eruption mechanisms of the explosive Bellecombe Eruptions on Piton de la Fournaise, La Réunion (United States)

    Morgan, K.; Ort, M. H.; Di Muro, A.; Parnell, R. A.; Huff, W. D.


    Piton de la Fournaise (PdF) is an active basaltic volcano on La Réunion island. The Bellecombe Tephra was deposited from at least three unusually explosive eruptions between 3000-5000 ka. The Bellecombe eruptions were interpreted recently to have been due to rapid depressurization of the hydrothermal system when a deep fracture opened after lateral, seaward-directed sliding of the eastern flank, late in a large effusive eruption. This project tests this hypothesis by physically, mineralogically, and chemically characterizing the Bellecombe Tephra to look for evidence of the involvement of the PdF hydrothermal system in the eruptions and understand where the eruptions initiated. The Bellecombe tephra consists of three units separated by incipient soils. Both the Upper and Lower Bellecombe deposits are mostly medium to very fine ash. Lower Bellecombe deposits, from the first two eruptions, are mostly beds of glassy ash containing minor lithic grains and olivine crystals. Hydrothermal minerals, mostly smectite, are present in a few Lower Bellecombe beds. Since these minerals are only present in some beds, the smectite formed before deposition rather than as a product of surficial alteration. The Upper Bellecombe deposits record a third eruption and vary between clast-supported crystal- and lithic-rich lapilli beds and ash beds with abundant ash pellets. The crystals are mostly olivine, with lesser pyroxene and plagioclase and sparse hydrothermal quartz. Gabbro and oceanite clasts are abundant and trachytic pumice rare in these deposits. Hydrothermal minerals are common in most Upper Bellecombe beds. The presence of smectite in some of the Lower Bellecombe beds suggests these deposits came from a system below 200 ºC. Clays in the Upper Bellecombe beds - smectite and mixed layer R0 illite/smectite - imply a system at 40-140 ºC. The hydrothermal system was involved, but might not have been the primary impetus for these eruptions, since hydrothermal minerals are not

  20. The erosive potential of commercially available mouthrinses on enamel as measured by Quantitative Light-induced Fluorescence (QLF). (United States)

    Pretty, I A; Edgar, W M; Higham, S M


    Longitudinal in vitro. Previously extracted, caries free, human premolars were selected and prepared by gentle pumicing and coating in an acid-resistant nail-varnish save for an exposed enamel window on the buccal surface. Each was assigned to one of eight groups (six per group, 10 in positive control); positive control (citric acid, pH 2.7, F(-) 0 ppm), negative control (pH 7.0, F(-) 0 ppm) Listerine (pH 3.87, F(-) 0.021 ppm), Tesco Value (pH 6.05, F(-) 289.00 ppm), Tesco Total Care (pH 6.20, F(-) 313.84 ppm), Sainsbury's (pH 6.15, F(-) 365.75 ppm), Sensodyne (pH 6.12, F(-) 285.30 ppm) and Corsodyl (pH 5.65, F(-) 0 ppm). The titratable acid values (TAV) for each rinse were established using volume (ml) of 0.1 M NaOH to achieve pH 7. Fluoride values were obtained by ion selective electrode. The solutions were kept at 37 degrees C and gently agitated. Teeth were removed at hourly intervals for 15 h, air-dried and subjected to Quantitative Light-induced Fluorescence (QLF) examination by a blinded examiner and DeltaQ values recorded. At the conclusion of the study each of the positive control teeth and one from each other group were sectioned through the eroded lesion, ground and polished to 100 micrometers and subjected to transverse microradiography and DeltaZ recorded for validation. TAVs were: Listerine 2.45 L > Sainsbury's 0.35 ml >Tesco Total Care 0.14 ml > Tesco Value 0.08 ml > Corsodyl 0.10 ml >Sensodyne 0.9 ml. DeltaQ increased over time for the positive control, (0 h 0.2, 10 h 95.2, 15 h 152.3). Negative controls remained stable. The increase in DeltaQ for each rinse after 15 h was Listerine (9.3(+/-7.2)), Corsodyl (1.5(+/-1.2)), Tesco Value (1.8(+/-1.2)), Tesco Total Care (1.4(+/-1.1)), Sainsbury's (3.4(+/-2.2)), Sensodyne (0.9(+/-1.6)). TMR confirmed the presence/absence of erosive lesions. QLF effectively monitored erosion in the positive controls and lack of erosion in the NC. Only one mouthrinse (Listerine) caused any erosion compared to the negative

  1. In defense of Magnetite-Ilmenite Thermometry in the Bishop Tuff and its implication for gradients in silicic magma reservoirs (United States)

    Evans, Bernard W; Hildreth, Edward; Bachmann, Olivier; Scaillet, Bruno


    Despite claims to the contrary, the compositions of magnetite and ilmenite in the Bishop Tuff correctly record the changing conditions of T and fO2 in the magma reservoir. In relatively reduced (∆NNO magmas (e.g., Bishop Tuff, Taupo units), Ti behaves compatibly (DTi ≈ 2-3.5), leading to a decrease in TiO2 activity in the melt with cooling and fractionation. In contrast, FeTi-oxides are poorer in TiO2 in more oxidized magmas (∆NNO > 1, e.g., Fish Canyon Tuff, Pinatubo), and the d(aTiO2)/dT slope can be negative. Biotite, FeTi-oxides, liquid, and possibly plagioclase largely maintained equilibrium in the Bishop Tuff magma (unlike the pyroxenes, and cores of quartz, sanidine, and zircon) prior ro and during a mixing event triggered by a deeper recharge, which, based on elemental diffusion profiles in minerals, took place at least several decades before eruption. Equilibrating phases and pumice compositions show evolving chemical variations that correlate well with mutually consistent temperatures based on the FeTi-oxides, sanidine-plagioclase, and ∆18O quartz-magnetite pairs. Early Bishop Tuff (EBT) temperatures are lower (700 to ~780‎°C) than temperatures (780 to >820°C) registered in Late Bishop Tuff (LBT), the latter defined here not strictly stratigraphically, but by the presence of orthopyroxene and reverse-zoned rims on quartz and sanidine. The claimed similarity in compositions, Zr-saturation temperatures and thermodynamically calculated temperatures (730-740°C) between EBT and less evolved LBT reflect the use of glass inclusions in quartz cores in LBT that were inherited from the low temperature rhyolitic part of the reservoir characteristic of the EBT. LBT temperatures as high as 820°C, the preservation of orthopyroxene, and the presence of reverse-zoned minerals (quartz, sanidine, zircons) are consistent with magma recharge at the base of the zoned reservoir, heating the cooler rhyolitic melt, partly remelting cumulate mush, and introducing

  2. Chemical and biological characterisation of solvent extracts and essential oils from leaves and fruit of two Australian species of Pittosporum (Pittosporaceae) used in aboriginal medicinal practice. (United States)

    Sadgrove, Nicholas John; Jones, Graham Lloyd


    Although no known medicinal use for Pittosporum undulatum Vent. (Pittosporaceae) has been recorded, anecdotal evidence suggests that Australian Aboriginal people used Pittosporum angustifolium Lodd., G. Lodd. & W. Lodd. topically for eczema, pruritis or to induce lactation in mothers following child-birth and internally for coughs, colds or cramps. Essential oil composition and bioactivity as well as differential solvent extract antimicrobial activity from Pittosporum angustifolium are investigated here first, to partially describe the composition of volatiles released in traditional applications of Pittosporum angustifolium for colds or as a lactagogue, and second to investigate antibacterial activity related to topical applications. Essential oils were also investigated from Pittosporum undulatum Vent., first to enhance essential oil data produced in previous studies, and second as a comparison to Pittosporum angustifolium. Essential oils were hydrodistilled from fruit and leaves of both species using a modified approach to lessen the negative (frothing) effect of saponins. This was achieved by floating pumice or pearlite obsidian over the mixture to crush the suds formed while boiling. Essential oil extracts were analysed using GC-MS, quantified using GC-FID then screened for antimicrobial activity using a micro-titre plate broth dilution assay (MIC). Using dichloromethane, methanol, hexane and H(2)O as solvents, extracts were produced from leaves and fruit of Pittosporum angustifolium and screened for antimicrobial activity and qualitative phytochemical character. Although the essential oil from leaves and fruit of Pittosporum undulatum demonstrated some component variation, the essential oil from fruits of Pittosporum angustifolium had major constituents that strongly varied according to the geographical location of collection, suggesting the existence of at least two chemotypes; one with high abundance of acetic acid decyl ester. This chemotype had high

  3. Conditions and timescales for welding block-and-ash flow deposits (United States)

    Heap, M. J.; Kolzenburg, S.; Russell, J. K.; Campbell, M. E.; Welles, J.; Farquharson, J. I.; Ryan, A.


    Welding of pyroclastic deposits to reform a coherent rock mass is a common phenomenon, especially for pumiceous pyroclastic density current deposits (i.e., ignimbrites). However, and despite the pervasive abundance of block-and-ash flow (BAF) deposits in the geological and modern record, instances of strongly welded BAF deposits are few. Here, we present a series of high-temperature (800-900 °C) compaction experiments designed to map the conditions (deposit thickness/stress and temperature/viscosity) and timescales that permit or inhibit the welding of BAF deposits. Our experiments were performed on unconsolidated aggregates (containing an ash and lapilli component) derived from crushed and sieved lava blocks (containing 25% crystals) taken from the well-documented welded BAF deposit at Mount Meager volcano (British Columbia, Canada). The experiments demonstrate that welding efficiency increases with increasing time and temperature. Progressive welding is expressed by increasing axial strain, porosity loss, and bulk density. The rate of change of each of these physical properties reduces as welding progresses. Microstructural analysis of the experimental products shows that the loss of interclast porosity during welding results from the progressive sintering and amalgamation of vitric fragments, and that the pore shape changes from sub-equant pores to stretched lenses sandwiched between vitric and crystal fragments. The coincidence between the microstructure and rock physical properties of the natural and experimental samples highlight that we have successfully reproduced welded BAF in the laboratory. Furthermore, our permeability measurements highlight a hysteresis in the return journey of the "there-and-back-again" volcanic permeability cycle (expressed by an increase in permeability due to vesiculation and fragmentation followed by a decrease due to welding). This hysteresis cannot be described by a single porosity-permeability power law relationship and

  4. Field-trip guide to Mount St. Helens, Washington - An overview of the eruptive history and petrology, tephra deposits, 1980 pyroclastic density current deposits, and the crater (United States)

    Pallister, John S.; Clynne, Michael A.; Wright, Heather M.; Van Eaton, Alexa R.; Vallance, James W.; Sherrod, David R.; Kokelaar, B. Peter


    This field trip will provide an introduction to several fascinating features of Mount St. Helens. The trip begins with a rigorous hike of about 15 km from the Johnston Ridge Observatory (9 km north-northeast of the crater vent), across the 1980 Pumice Plain, to Windy Ridge (3.6 km northeast of the crater vent) to examine features that document the dynamics and progressive emplacement of pyroclastic flows. The next day, we examine classic tephra outcrops of the past 3,900 years and observe changes in thickness and character of these deposits as we traverse their respective lobes. We examine clasts in the deposits and discuss how the petrology and geochemistry of Mount St. Helens deposits reveal the evolution of the magmatic system through time. We also investigate the stratigraphy of the 1980 blast deposit and review the chronology of this iconic eruption as we travel through the remains of the blown-down forest. The third day is another rigorous hike, about 13 km round trip, climbing from the base of Windy Ridge (elevation 1,240 m) to the front of the Crater Glacier (elevation 1,700 m). En route we examine basaltic andesite and basalt lava flows emplaced between 1,800 and 1,700 years before present, a heterolithologic flow deposit produced as the 1980 blast and debris avalanche interacted, debris-avalanche hummocks that are stranded on the north flank and in the crater mouth, and shattered dacite lava domes that were emplaced between 3,900 and 2,600 years before present. These domes underlie the northern part of the volcano. In addition, within the crater we traverse well-preserved pyroclastic-flow deposits that were emplaced on the crater floor during the summer of 1980, and a beautiful natural section through the 1980 deposits in the upper canyon of the Loowit River.Before plunging into the field-trip log, we provide an overview of Mount St. Helens geology, geochemistry, petrology, and volcanology as background. The volcano has been referred to as a

  5. Geology and petrology of the Woods Mountains Volcanic Center, southeastern California: Implications for the genesis of peralkaline rhyolite ash flow tuffs (United States)

    McCurry, Michael


    The Woods Mountains Volcanic Center is a middle Miocene silicic caldera complex located at the transition from the northern to the southern Basin and Range provinces of the western United States. It consists of a trachyte-trachydacite-rhyolite-peralkaline rhyolite association of lava flows, domes, plugs, pyroclastic rocks, and epiclastic breccia. Volcanism began at about 16.4 Ma, near the end of a local resurgence of felsic to intermediate magmatism and associated crustal extension. Numerous metaluminous high-K trachyte, trachydacite, and rhyolite lava flows, domes, and pyroclastic deposits accumulated from vents scattered over an area of 200 km2 forming a broad volcanic field with an initial volume of about 10 km3. At 15.8 Ma, about 80 km3 of metaluminous to mildly peralkaline high-K rhyolite ash flows were erupted from vents in the western part of fhe field in three closely spaced pulses, resulting in the formation of a trap door caldera 10 km in diameter. The ash flows formed the Wild Horse Mesa Tuff, a compositionally zoned ash flow sheet that originally covered an area of about 600 km2 to a maximum thickness of at least 320 m. High-K trachyte pumice lapilli, some of which are intimately banded with rhyolite, were produced late in the two later eruptions, Intracaldera volcanism from widely distributed vents rapidly filled the caldera with about 10 km3 of high-K, mildly peralkaline, high-silica rhyolite lava flows and pyroclastic deposits. These are interlayered with breccia derived from the caldera scarp. They are intruded by numerous compositionally similar plugs, some of which structurally uplifted and fractured the center of the caldera. The center evolved above a high-K trachyte magma chamber about 10 km in diameter that had developed and differentiated within the upper crust at about 15.8 Ma. Petrological, geochemical, and geophysical data are consistent with the idea that a cap of peralkaline rhyolite magma formed within the trachyte chamber as a result

  6. Biological phosphorus removal during high-rate, low-temperature, anaerobic digestion of wastewater

    Directory of Open Access Journals (Sweden)

    Ciara eKeating


    Full Text Available We report, for the first time, extensive biologically-mediated phosphate removal from wastewater during high-rate anaerobic digestion (AD. A hybrid sludge bed/fixed-film (packed pumice stone reactor was employed for low-temperature (12°C anaerobic treatment of synthetic sewage wastewater. Successful phosphate removal from the wastewater (up to 78% of influent phosphate was observed, mediated by biofilms in the reactor. Scanning electron microscopy and energy dispersive X-ray analysis revealed the accumulation of elemental phosphorus (~2% within the sludge bed and fixed-film biofilms. 4’, 6-diamidino-2-phenylindole (DAPI staining indicated phosphorus accumulation was biological in nature and mediated through the formation of intracellular inorganic polyphosphate (polyP granules within these biofilms. DAPI staining further indicated that polyP accumulation was rarely associated with free cells. Efficient and consistent chemical oxygen demand (COD removal was recorded, throughout the 732-day trial, at applied organic loading rates between 0.4-1.5 kg COD m-3 d-1 and hydraulic retention times of 8-24 hours, while phosphate removal efficiency ranged from 28-78% on average per phase. Analysis of protein hydrolysis kinetics and the methanogenic activity profiles of the biomass revealed the development, at 12˚C, of active hydrolytic and methanogenic populations. Temporal microbial changes were monitored using Illumina Miseq analysis of bacterial and archaeal 16S rRNA gene sequences. The dominant bacterial phyla present in the biomass at the conclusion of the trial were the Proteobacteria and Firmicutes and the dominant archaeal genus was Methanosaeta. Trichococcus and Flavobacterium populations, previously associated with low temperature protein degradation, developed in the reactor biomass. The presence of previously characterised polyphosphate accumulating organisms (PAOs such as Rhodocyclus, Chromatiales, Actinobacter and Acinetobacter was

  7. El Hierro's floating stones as messengers of crust-magma interaction at depth (United States)

    Burchardt, S.; Troll, V. R.; Schmeling, H.; Koyi, H.; Blythe, L. S.; Longpré, M. A.; Deegan, F. M.


    During the early stages of the submarine eruption that started on October 10 2011 south of El Hierro, Canary Islands, Spain, peculiar eruption products were found floating on the sea surface. These centimetre- to decimetre-sized "bombs" have been termed "restingolites" after the nearby village La Restinga and consist of a basaltic rind and a white to light grey core that resembles pumice in texture. According to Troll et al. (2011; see also Troll et al. EGU 2012 Abstracts), this material consists of a glassy matrix hosting extensive vesicle networks, which results in extremely low densities allowing these rocks to float on sea water. Mineralogical and geochemical analyses reveal that the "restingolites" originate from the sedimentary rocks (sand-, silt-, and mudstones) that form layer 1 of the oceanic crust beneath El Hierro. During the onset and early stages of the eruption, magma ponded at the base of this sedimentary sequence, breaking its way through the sedimentary rocks to the ocean floor. The textures of the "restingolites" reveal that crust-magma interaction during fragmentation and transport of the xenoliths involved rapid partial melting and volatile exsolution. Xenoliths strikingly similar to those from El Hierro are known from eruptions on other Canary Islands (e.g. La Palma, Gran Canaria, and Lanzarote). In fact, they resemble in texture xenoliths of various protoliths from volcanic areas worldwide (e.g. Krakatao, Indonesia, Cerro Quemado, Guatemala, Laacher See, Germany). This indicates that the process of partial melting and volatile exsolution, which the "restingolites" bear witness of, is probably occurring frequently during shallow crustal magma emplacement. Thermomechanical numerical models of the effect of the density decrease associated with the formation of vesicle networks in partially molten xenoliths show that xenoliths of crustal rocks initially sink in a magma chamber, but may start to float to the chamber roof once they start to heat up

  8. Ground-based LiDAR application to characterize sea cliff instability processes along a densely populated coastline in Southern Italy (United States)

    Esposito, Giuseppe; Semaan, Fouad; Salvini, Riccardo; Troise, Claudia; Somma, Renato; Matano, Fabio; Sacchi, Marco


    Sea cliff retreatment along the coastline of the Campi Flegrei volcanic area (Southern Italy) is becoming a threat for public and private structures due to the massive urbanization occurred in the last few decades. In this area, geological features of the outcropping rocks represent one of the most important factors conditioning the sea cliff retreatment. In fact, pyroclastic deposits formed by pumices, scoria, ashes and lapilli are arranged in weakly to moderately welded layers of variable thicknesses, resulting very erodible and prone to landslide processes. Available methods to evaluate topographic changes and retreat rates of sea cliffs include a variety of geomatic techniques, like terrestrial and aerial photogrammetry and LiDAR (Light Detection And Ranging). By means of such techniques, it is in fact possible to obtain high resolution topography of sea cliffs and perform multi-temporal change detection analysis. In this contribution, we present an application of Terrestrial Laser Scanning (TLS or ground-based LiDAR) aimed to identify and quantify instability processes acting along the Torrefumo coastal cliff, in the Campi Flegrei area. Specifically, we acquired a series of 3D point clouds on the years 2013 and 2016, and compared them through a cloud-to-cloud distance computation. Furthermore, a statistical analysis was applied to the change detection results. In this way, an inventory of the cliff failures occurred along the Torrefumo cliff in the 2013-2016 time span was created, as well as the spatial and volumetric distribution of these failures was evaluated. The volumetric analysis shows that large collapses occurred rarely, whereas the spatial analysis shows that the majority of failures occurred in the middle and upper parts of the cliff face. Results also show that both rock fall and surficial erosion processes contribute to the cliff retreatment, acting in turn according to the geological properties of the involved pyroclastic deposits. The presented

  9. Las ignimbritas del complejo volcánico Coranzuli (Puna Argentina-Andes Centrales

    Directory of Open Access Journals (Sweden)

    Martí, J.


    Full Text Available The Coranzulí is a large Upper Miocene volcanic complex located on a NE-SW and NW-SE regional faults intersection, at 66º 15' W 23º S, in the Northwest of Argentina in Jujuy province. It corresponds to one of four large volcanic complexes which represent the end of Transversal Volcanic Chaines in La Puna Argentina in the Central Andes. The volcanic activity was characterized by at least four separate ignimbrite eruptions which produced four different ignimbrite sheets. These are well welded, very crystal-rich, lithie poor ignimbrites and have a moderate to high pumice content. The total volume of the Coranzuli ignimbrites exeededs 650 Km3. Preliminary data indicate that the eruption oeeurred from a homogeneous magmatic chamber without zoning. The emplacement characteristics of the ignimbrites and the lack of basal or interbedded plinian fall deposits suggest that the eruptions developed quickly to massive proportions.El Coranzuli es uno de los grandes complejos volcánicos que representan el remate final de las Cadenas Volcánicas Transversales de la Puna Argentina, en los Andes Centrales. Se trata de un complejo volcánico del Mioceno superior situado a los 66º 15' W 23º S en el NW de Argentina en la provincia de Jujuy, en la intersección entre dos fallas regionales de dirección NE-SW y NW-SE, respectivamente. La actividad eruptiva se caracterizó por la existencia de, al menos, cuatro erupciones ignimbríticas que produjeron cuatro diferentes mantos ignimbríticos. Se trata de ignimbritas bien soldadas, muy ricas en cristales, pobre en fragmentos líticos y que presentan un contenido en fragmentos pumíticos de moderado a alto. El volumen total que representan estas ignimbritas supera los 650 km3. Los datos preliminares indican que el magma juvenil deriva de una cámara magmática homogénea no zonada. Las características de emplazamiento de estas ignimbritas, así como la falta de depósitos plinianos de caída en la base o

  10. Effect of filler type on 3-body abrasion of dental composite

    Directory of Open Access Journals (Sweden)

    Yasini E.


    Full Text Available Statement of Problem: The relatively poor wear resistance of dental composite in stress bearing posterior situations has restricted wider clinical application of this restorative material. Purpose: The aim of this study was to evaluate the three body abrasive wear of a dental composite based on a new filler (leucite: KAl Si2O6 and to compare it with the wear resistance of a composite based on commonly used Aluminium – Barium Silicate filler. Materials and Methods: This research was an interventional study done in Iran polymer institute. Five specimens were considered in each group. All ceramic IPS Empress® (Ivoclar- Vivadent ingots based on leucite crystals were ball milled, passed through an 800 sieve and used as filler. Experimental composites were prepared by mixing the silane- treated fillers with monomers (BisGMA and TEGDMA. Camphorquinone and amine were used as photoinitiator system. Degree of conversion of the light-cured and post-cured composites was measured using FTIR spectroscopy. The prepared pastes were inserted into plexy-glass mold and light cured (700 mw/cm2, 40 s. Then for maximum degree of conversion specimens were post- cured (120ºC, 5 hours. Three body abrasion wear testing was performed using a wear machine with 50 rpm rotational movement. In this machine, pumice (150 meshes was used as the third body. Weight loss of specimens in each group was measured by balance after each 50 hours. After wear testing SEM examination was made specimens in each group. The data were analyzed and compared using ANOVA and Tukey HSD tests (P<0.05. Tetric Ceram was tested as commercial composite. Results: There were significantly differences between three body abrasive wear of composites. The ranking from lowest to highest was as follows: leucite composite (19% < Tetric Ceram (22% < glass composite (28%. leucite composite showed the highest wear resistance value, propably due to the crystalliniy and hardness of filler. Conclusion

  11. Update on subsidence at the Wairakei-Tauhara geothermal system, New Zealand

    International Nuclear Information System (INIS)

    Allis, Rick; Bromley, Chris; Currie, Steve


    The total subsidence at the Wairakei field as a result of 50 years of geothermal fluid extraction is 15 ± 0.5 m. Subsidence rates in the center of the subsidence bowl have decreased from over 450 mm/year during the 1970s to 80-90 mm/year during 2000-2007. The location of the bowl, adjacent to the original liquid outflow zone of the field, has not changed significantly. Subsidence at the Tauhara field due to Wairakei production was not as well documented in the early years but appeared later and has been less intense than at Wairakei. Total subsidence of 2.6 ± 0.5 m has also occurred close to the original liquid outflow zone of this field, and maximum subsidence rates in this area today are in the 80-100 mm/year range. In the western part of the Wairakei field, near the area of hot upflow, subsidence rates have approximately doubled during the last 20 years to 30-50 mm/year. This increase appears to be have been caused by declining pressure in the underlying steam zone in this area, which is tapped by some production wells. At Tauhara field, two areas of subsidence have developed since the 1990s with rates of 50-65 mm/year. Although less well-determined, this subsidence may also be caused by declining pressure in shallow steam zones. The cause of the main subsidence bowls in the Wairakei-Tauhara geothermal system is locally high-compressibility rocks within the Huka Falls Formation (HFF), which are predominantly lake sediments and an intervening layer of pumice breccia. At Wairakei, casing deformation suggests the greatest compaction is at 150-200 m depth. The cause of the large compressibility is inferred to be higher clay content in the HFF due to intense hydrothermal alteration close to the natural fluid discharge areas. Future subsidence is predicted to add an additional 2-4 m to the Wairakei bowl, and 1-2 m elsewhere, but these estimates depend on the assumed production-injection scenarios. (author)

  12. Spatial variability of damage around faults in the Joe Lott Tuff Member of the Mount Belknap Volcanics, southwestern Utah (United States)

    Okubo, C. H.


    In order to yield new insight into the process of faulting in fine-grained, poorly indurated volcanic ash, the distribution of strain around faults in the Miocene-aged Joe Lott Tuff Member of the Mount Belknap Volcanics, Utah, is investigated. Several distinct styles of inelastic strain are identified. Deformation bands are observed in tuff that is porous and granular in nature, or is inferred to have been so at the time of deformation. Where silicic alteration is pervasive, fractures are the dominant form of localized strain. Non-localized strain within the host rock is manifest as pore space compaction, including crushing of pumice clasts. Distinct differences in fault zone architecture are observed at different magnitudes of normal fault displacement, in the mode II orientation. A fault with cm-scale displacements is manifest as a single well-defined surface. Off-fault damage occurs as pore space compaction near the fault tips and formation of deformation band damage zones that are roughly symmetric about the fault. At a fault with larger meter-scale displacements, a fault core is present. A recognizable fault-related deformation band damage zone is not observed here, even though large areas of the host rock remain porous and granular and deformation bands had formed prior to faulting. The host rock is instead fractured in areas of pervasive alteration and shows possible textural evidence of fault pulverization. The zones of localized and distributed strain have notably different spatial extents around the causative fault. The region of distributed deformation, as indicated by changes in gas permeability of the macroscopically intact rock, extends up to four times farther from the fault than the highest densities of localized deformation (i.e., fractures and deformation bands). This study identifies a set of fault-related processes that are pertinent to understanding the evolution of fault systems in poorly indurated tuff. Not surprisingly, the type of

  13. Ash turbidites from Southern Italy help understanding the parent eruptions and contributing to geodynamic evolution cadre of the Tyrrhenian sea (United States)

    Doronzo, Domenico Maria


    Tephra layers intercalated in sedimentary successions are very interesting since they represent some instants of geodynamic evolution in a sedimentation basin. Furthermore, they can constitute deposits of explosive eruptions whose distal behaviour can be useful for studying the volcanoes activity, especially when pyroclastic deposits in proximal areas are absent. In the Craco area (Matera, Italy), thick ash turbidites intercalated in marine clays deposits have been recently recognized, which interest is related to the considerable cropping out thickness (1 to 5 m), freshness of the material and absence of sedimentary component. Petrography, sedimentology and chemistry of the deposits have been characterized with the aim of defining genesis and deposition of the material. The deposits are essentially made up of ashy pyroclasts, dominated by fresh acidic to intermediate glass, mostly in the form of shards, pumice fragments and groundmass fragments with vitrophyric texture. Rare crystals include Pl, Opx, Cpx, Hbl and Bt. 40Ar/39Ar geochronology on the amphibole dated one level to 2.24 ± 0.06 Ma, indicating the Late Pliocene. The grain size (fine ash) and textural features of the deposits are typical of pyroclastic fall deposits related to explosive eruptions with consequent upward projection of the fragmented material through Plinian columms. The columns turned eastward because of stratospheric winds and the material fell in a marine environment. It deposited on the slope of Pliocene basins in the frontal sector of the Southern Apennine chain. Structural features are the following: fining-upward gradation of the deposits with cross- and convolute laminations at the base and fine-grained massive beds at the top. They suggest that the primary pyroclastic fall deposits were mobilized as volcaniclastic turbidity currents towards a deeper environment. Glass and crystal compositions were investigated by SEM/EDS analysis. Petrographycal and chemical compositions of the

  14. Subaqueous non-vesicular to poorly-vesicular shards: hydroclastic fragmentation on seamounts and summit calderas (United States)

    Mueller, W. U.; Dingwell, D. B.; Downey, W. S.; Mastin, L. G.


    Recognizing pyroclastic deposits that originate directly from magmatic and phreatomagmatic explosions in a subaqueous setting is based upon sedimentary structures, such as massive, stratified, and graded beds as well as (pyro)clast size. Ideally such deposits form ordered fining-and thinning-upward sequences. Pumice, scoria, glass shards, euhedral and broken crystals, and lithic fragments are constituents that support an explosive heritage. Recent deep-sea ROV and submersible dives have retrieved non-vesicular to vesicle- poor, mm-scale, mafic shards in 5-15 cm-thick massive and/or graded (stratified) deposits, for which a subaqueous explosive origin has been inferred. These sheet hyaloclastites with variable shard shapes were first documented on Seamount 6 as deep-sea Limu O Pele at water depths > 1000 m. We identified in Seamount 6 samples equant to blocky shards with angular to subrounded terminations, but also subordinate hair-like and contorted glassy filaments, warped shards and irregular shards. Shards display internal laminations (flow-banding?) and have local perlitic fractures. Bubble wall shards derived from scoria burst were rare. In combination with all the above and a poor shard vesicularity (tubes and ponded magma in depths > 1000 m. We envision that hydrostatic pressure commensurate with water depth played a significant role. The deposits can be readily explained by a hydroclastic process whereby fragmentation occurred at the milli-second (Limu) to second scale (hyaloclastite). Hence, hyperquenched glass shards or thread-like gl