Whistler waves with electron temperature anisotropy and non-Maxwellian distribution functions

Directory of Open Access Journals (Sweden)

M. Usman Malik

2018-05-01

Full Text Available The previous works on whistler waves with electron temperature anisotropy narrated the dependence on plasma parameters, however, they did not explore the reasons behind the observed differences. A comparative analysis of the whistler waves with different electron distributions has not been made to date. This paper attempts to address both these issues in detail by making a detailed comparison of the dispersion relations and growth rates of whistler waves with electron temperature anisotropy for Maxwellian, Cairns, kappa and generalized (r, q distributions by varying the key plasma parameters for the problem under consideration. It has been found that the growth rate of whistler instability is maximum for flat-topped distribution whereas it is minimum for the Maxwellian distribution. This work not only summarizes and complements the previous work done on the whistler waves with electron temperature anisotropy but also provides a general framework to understand the linear propagation of whistler waves with electron temperature anisotropy that is applicable in all regions of space plasmas where the satellite missions have indicated their presence.

A quasilinear kinetic model for solar wind electrons and protons instabilities

Science.gov (United States)

Sarfraz, M.; Yoon, P. H.

2017-12-01

In situ measurements confirm the anisotropic behavior in temperatures of solar wind species. These anisotropies associated with charge particles are observed to be relaxed. In collionless limit, kinetic instabilities play a significant role to reshape particles distribution. The linear analysis results are encapsulated in inverse relationship between anisotropy and plasma beta based observations fittings techniques, simulations methods, or solution of linearized Vlasov equation. Here amacroscopic quasilinear technique is adopted to confirm inverse relationship through solutions of set of self-consistent kinetic equations. Firstly, for a homogeneous and non-collisional medium, quasilinear kinetic model is employed to display asymptotic variations of core and halo electrons temperatures and saturations of wave energy densities for electromagnetic electron cyclotron (EMEC) instability sourced by, T⊥}>T{∥ . It is shown that, in (β ∥ , T⊥}/T{∥ ) phase space, the saturations stages of anisotropies associated with core and halo electrons lined up on their respective marginal stability curves. Secondly, for case of electrons firehose instability ignited by excessive parallel temperature i.e T⊥}>T{∥ , both electrons and protons are allowed to dynamically evolve in time. It is also observed that, the trajectories of protons and electrons at saturation stages in phase space of anisotropy and plasma beta correspond to proton cyclotron and firehose marginal stability curves, respectively. Next, the outstanding issue that most of observed proton data resides in nearly isotropic state in phase space is interpreted. Here, in quasilinear frame-work of inhomogeneous solar wind system, a set of self-consistent quasilinear equations is formulated to show a dynamical variations of temperatures with spatial distributions. On choice of different initial parameters, it is shown that, interplay of electron and proton instabilities provides an counter-balancing force to slow

The BEAN experiment - An EISCAT study of ion temperature anisotropies

Directory of Open Access Journals (Sweden)

I. W. McCrea

Full Text Available Results are presented from a novel EISCAT special programme, SP-UK-BEAN, intended for the direct measurement of the ion temperature anisotropy during ion frictional heating events in the high-latitude F-region. The experiment employs a geometry which provides three simultaneous estimates of the ion temperature in a single F-region observing volume at a range of aspect angles from 0° to 36°. In contrast to most previous EISCAT experiments to study ion temperature anisotropies, field-aligned observations are made using the Sodankylä radar, while the Kiruna radar measures at an aspect angle of the order of 30°. Anisotropic effects can thus be studied within a small common volume whose size and altitude range is limited by the radar beamwidth, rather than in volumes which overlap but cover different altitudes. The derivation of line-of-sight ion temperature is made more complex by the presence of an unknown percentage of atomic and molecular ions at the observing altitude and the possibility of non-Maxwellian distortion of the ion thermal velocity distribution. The first problem has been partly accounted for by insisting that a constant value of electron temperature be maintained. This enables an estimate of the ion composition to be made, and facilitates the derivation of more realistic line-of-sight ion temperatures and temperature anisotropies. The latter problem has been addressed by assuming that the thermal velocity distribution remains bi-Maxwellian. The limitations of these approaches are discussed. The ion temperature anisotropies and temperature partition coefficients during two ion heating events give values intermediate between those expected for atomic and for molecular species. This result is consistent with an analysis which indicates that significant proportions of molecular ions (up to 50% were present at the times of greatest heating.

Theoretical analysis of low-energy proton and helium anisotropies in the outer heliosphere

International Nuclear Information System (INIS)

Forman, M.A.; McDonald, F.B.

1982-01-01

Analysis of the anisotropies of low-energy protons and helium near the ecliptic plane at 12 AU in 1977 reported by McDonald and Forman, in terms of the standard convection-diffusion and drift expressions, and using the observed gradients and spectral indices, shows that their mean free paths are approximately 10 AU parallel to the mean magnetic field, that k perpendicular may be substantially larger than k transverse 2 /k parallel and that these particles may be flowing radially

Anisotropy function for proton-proton elastic scattering

International Nuclear Information System (INIS)

Saleem, Mohammad; Fazal-e-Aleem; Azhar, I.A.

1990-01-01

By using the generalized Chou-Yang model and the experimental data on pp elastic scattering at 53 GeV, the anisotropy function which reflects the non-isotropic nature of elastic scattering is computed for the reaction pp→pp. (author)

Anisotropy function for proton-proton elastic scattering

Energy Technology Data Exchange (ETDEWEB)

Saleem, Mohammad; Fazal-e-Aleem; Azhar, I.A. (Punjab Univ., Lahore (Pakistan). Centre for High Energy Physics)

1990-07-01

By using the generalized Chou-Yang model and the experimental data on pp elastic scattering at 53 GeV, the anisotropy function which reflects the non-isotropic nature of elastic scattering is computed for the reaction pp{yields}pp. (author).

Variation in the strain anisotropy of Zircaloy with temperature and strain

International Nuclear Information System (INIS)

Hindle, E.D.; Worswick, D.

1984-04-01

Strain anisotropy was investigated at temperatures in the range 293 to 1117K in circular tensile specimens prepared from rolled Zircaloy-2 plate so that their tensile axes were parallel to and transverse to the rolling direction. The strain anisotropy factor for both types of specimen increased markedly in the high alpha phase region above 923K reaching a maximum at circa 1070K. Above this temperature in the alpha-plus-beta phase region the strain anisotropy decreased rapidly as the proportion of beta phase increased and was almost non-existent at 1173K. The strain anisotropy was markedly strain dependent, particularly in the high alpha phase region. The study was extended to Zircaloy-4 pressurized water reactor (PWR) 17 x 17 type fuel rod tubing specimens which were strained under biaxial conditions using cooling conditions which promoted uniform diametral strain over most of their lengths (circa 250 mm). In these circumstances the strain anisotropy is manifest by a reduction in length. Measurement of this change along with that in diameter and wall thickness produced data from which the strain anisotropy factor was calculated. The results, although influenced by additional factors discussed in the paper, were similar to those observed in the uniaxial Zircaloy-2 tensile tests. (author)

Effect of temperature on anisotropy in forming simulations of aluminum alloys

NARCIS (Netherlands)

Kurukuri, S.; Miroux, A.; Ghosh, M.; van den Boogaard, Antonius H.

2009-01-01

A combined experimental and numerical study of the effect of temperature on anisotropy in warm forming of AA 6016-T4 aluminum was performed. The anisotropy coefficients of the Vegter yield function were calculated from crystal plasticity models with an adequate combination of extra slip systems.

The time and spatial behavior of solar flare proton anisotropies observed in deep space on Pioneers 10 and 11

Science.gov (United States)

Mccarthy, J.; Ogallagher, J. J.

1975-01-01

The anisotropy of solar flare protons from the direction of the 'garden hose' magnetic field line has been analyzed for 24 events observed by the University of Chicago experiment on Pioneers 10 and 11 in 1972 and 1973. The anisotropy versus time profiles during individual events are in general consistent with diffusive propagation, but several cases are observed where the decay is better described by an exponential time decay. The anisotropy amplitude evaluated at the time of maximum intensity for each event shows evidence for a gradual decrease with increasing distance from the sun which is qualitatively consistent with diffusive propagation and suggests that the effective interplanetary diffusion coefficient parallel to the magnetic field increases slowly with heliocentric distance.

Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers

Energy Technology Data Exchange (ETDEWEB)

Pappas, S. D.; Trachylis, D.; Velgakis, M. J. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process Engineering Research Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Poulopoulos, P. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Materials Science Department, University of Patras, 26504 Patras (Greece); Fumagalli, P. [Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Politis, C. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States)

2012-09-01

Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

Reconstruction of CMB temperature anisotropies with primordial CMB induced polarization in galaxy clusters

Science.gov (United States)

Liu, Guo-Chin; Ichiki, Kiyotomo; Tashiro, Hiroyuki; Sugiyama, Naoshi

2016-07-01

Scattering of cosmic microwave background (CMB) radiation in galaxy clusters induces polarization signals determined by the quadrupole anisotropy in the photon distribution at the location of clusters. This `remote quadrupole' derived from the measurements of the induced polarization in galaxy clusters provides an opportunity to reconstruct local CMB temperature anisotropies. In this Letter, we develop an algorithm of the reconstruction through the estimation of the underlying primordial gravitational potential, which is the origin of the CMB temperature and polarization fluctuations and CMB induced polarization in galaxy clusters. We found a nice reconstruction for the quadrupole and octopole components of the CMB temperature anisotropies with the assistance of the CMB induced polarization signals. The reconstruction can be an important consistency test on the puzzles of CMB anomalies, especially for the low-quadrupole and axis-of-evil problems reported in Wilkinson Microwave Anisotropy Probe and Planck data.

Relationship between Magnetic Anisotropy below Pseudogap Temperature and Short-Range Antiferromagnetic Order in High-Temperature Cuprate Superconductor

Science.gov (United States)

Morinari, Takao

2018-06-01

The central issue in high-temperature cuprate superconductors is the pseudogap state appearing below the pseudogap temperature T*, which is well above the superconducting transition temperature. In this study, we theoretically investigate the rapid increase of the magnetic anisotropy below the pseudogap temperature detected by the recent torque-magnetometry measurements on YBa2Cu3Oy [Y. Sato et al., 10.1038/nphys4205" xlink:type="simple">Nat. Phys. 13, 1074 (2017)]. Applying the spin Green's function formalism including the Dzyaloshinskii-Moriya interaction arising from the buckling of the CuO2 plane, we obtain results that are in good agreement with the experiment and find a scaling relationship. Our analysis suggests that the characteristic temperature associated with the magnetic anisotropy, which coincides with T*, is not a phase transition temperature but a crossover temperature associated with the short-range antiferromagnetic order.

Limits on the ions temperature anisotropy in turbulent intracluster medium

Energy Technology Data Exchange (ETDEWEB)

Santos-Lima, R. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Potsdam Univ. (Germany). Inst. fuer Physik und Astronomie; Univ. de Sao Paulo (Brazil). Inst. de Astronomia, Geofisica e Ciencias Atmosfericas; Yan, H. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Potsdam Univ. (Germany). Inst. fuer Physik und Astronomie; Gouveia Dal Pino, E.M. de [Univ. de Sao Paulo (Brazil). Inst. de Astronomia, Geofisica e Ciencias Atmosfericas; Lazarian, A. [Wisconsin Univ., Madison, WI (United States). Dept. of Astronomy

2016-05-15

Turbulence in the weakly collisional intracluster medium of galaxies (ICM) is able to generate strong thermal velocity anisotropies in the ions (with respect to the local magnetic field direction), if the magnetic moment of the particles is conserved in the absence of Coulomb collisions. In this scenario, the anisotropic pressure magnetohydrodynamic (AMHD) turbulence shows a very different statistical behaviour from the standard MHD one and is unable to amplify seed magnetic fields, in disagreement with previous cosmological MHD simulations which are successful to explain the observed magnetic fields in the ICM. On the other hand, temperature anisotropies can also drive plasma instabilities which can relax the anisotropy. This work aims to compare the relaxation rate with the growth rate of the anisotropies driven by the turbulence. We employ quasilinear theory to estimate the ions scattering rate due to the parallel firehose, mirror, and ion-cyclotron instabilities, for a set of plasma parameters resulting from AMHD simulations of the turbulent ICM. We show that the ICM turbulence can sustain only anisotropy levels very close to the instabilities thresholds. We argue that the AMHD model which bounds the anisotropies at the marginal stability levels can describe the Alfvenic turbulence cascade in the ICM.

Cross-correlation studies between CMB temperature anisotropies and 21 cm fluctuations

International Nuclear Information System (INIS)

Cooray, Asantha

2004-01-01

During the transition from a neutral to a fully reionized universe, scattering of cosmic microwave background (CMB) photons via free electrons leads to a new anisotropy contribution to the temperature distribution. If the reionization process is inhomogeneous and patchy, the era of reionization is also visible via brightness temperature fluctuations in the redshifted 21 cm line emission from neutral hydrogen. Since regions containing electrons and neutral hydrogen are expected to trace the same underlying density field, the two are (anti)correlated and this is expected to be reflected in the anisotropy maps via a correlation between arcminute-scale CMB temperature and the 21 cm background. In terms of the angular cross-power spectrum, unfortunately, this correlation is insignificant due to a geometric cancellation associated with second-order CMB anisotropies. The same cross correlation between ionized and neutral regions, however, can be studied using a bispectrum involving large-scale velocity field of ionized regions from the Doppler effect, arcminute-scale CMB anisotropies during reionization, and the 21 cm background. While the geometric cancellation is partly avoided, the signal-to-noise ratio related to this bispectrum is reduced due to the large cosmic variance related to velocity fluctuations traced by the Doppler effect. Unless the velocity field during reionization can be independently established, it is unlikely that the correlation information related to the relative distribution of ionized electrons and regions containing neutral hydrogen can be obtained with a combined study involving CMB and 21 cm fluctuations

Temperature and carrier density dependence of anisotropy in supercurrent density in layered cuprate superconductors

International Nuclear Information System (INIS)

Singh, M.P.; Tewari, B.S.; Ajay

2006-01-01

In the present work, we have studied the effect of temperature and carrier density on anisotropy in supercurrent density in bilayer cuprate superconductors. Here, we have considered a tight binding bilayered Hubbard Hamiltonian containing intra and interlayer attractive interactions. The situation considered here is similar to a SIS junction. We have got the expressions for the superconducting order parameters, carrier density and anisotropy in superconducting density (I ab /I c ) for such SIS junction. The numerical analysis show that the anisotropy in the supercurrent density depends on temperature and carrier density in layered high T c cuprates. (author)

Temperature anisotropy in a cyclotron resonance heated tokamak plasma and the generation of poloidal electric field

International Nuclear Information System (INIS)

Choe, W.; Ono, M.; Chang, C.S.

1994-11-01

The temperature anisotropy generated by cyclotron resonance heating of tokamak plasmas is calculated and the poloidal equilibrium electric field due to the anisotropy is studied. For the calculation of anisotropic temperatures, bounce-averaged Fokker-Planck equation with a bi-Maxwellian distribution function of heated particles is solved, assuming a moderate wave power and a constant quasilinear cyclotron resonance diffusion coefficient. The poloidal electrostatic potential variation is found to be proportional to the particle density and the degree of temperature anisotropy of warm species created by cyclotron resonance heating

Stereochemistry-Dependent Proton Conduction in Proton Exchange Membrane Fuel Cells.

Science.gov (United States)

Thimmappa, Ravikumar; Devendrachari, Mruthyunjayachari Chattanahalli; Kottaichamy, Alagar Raja; Tiwari, Omshanker; Gaikwad, Pramod; Paswan, Bhuneshwar; Thotiyl, Musthafa Ottakam

2016-01-12

Graphene oxide (GO) is impermeable to H2 and O2 fuels while permitting H(+) shuttling, making it a potential candidate for proton exchange membrane fuel cells (PEMFC), albeit with a large anisotropy in their proton transport having a dominant in plane (σIP) contribution over the through plane (σTP). If GO-based membranes are ever to succeed in PEMFC, it inevitably should have a dominant through-plane proton shuttling capability (σTP), as it is the direction in which proton gets transported in a real fuel-cell configuration. Here we show that anisotropy in proton conduction in GO-based fuel cell membranes can be brought down by selectively tuning the geometric arrangement of functional groups around the dopant molecules. The results show that cis isomer causes a selective amplification of through-plane proton transport, σTP, pointing to a very strong geometry angle in ionic conduction. Intercalation of cis isomer causes significant expansion of GO (001) planes involved in σTP transport due to their mutual H-bonding interaction and efficient bridging of individual GO planes, bringing down the activation energy required for σTP, suggesting the dominance of a Grotthuss-type mechanism. This isomer-governed amplification of through-plane proton shuttling resulted in the overall boosting of fuel-cell performance, and it underlines that geometrical factors should be given prime consideration while selecting dopant molecules for bringing down the anisotropy in proton conduction and enhancing the fuel-cell performance in GO-based PEMFC.

Kinetic instabilities in the solar wind driven by temperature anisotropies

Science.gov (United States)

Yoon, Peter H.

2017-12-01

The present paper comprises a review of kinetic instabilities that may be operative in the solar wind, and how they influence the dynamics thereof. The review is limited to collective plasma instabilities driven by the temperature anisotropies. To limit the scope even further, the discussion is restricted to the temperature anisotropy-driven instabilities within the model of bi-Maxwellian plasma velocity distribution function. The effects of multiple particle species or the influence of field-aligned drift will not be included. The field-aligned drift or beam is particularly prominent for the solar wind electrons, and thus ignoring its effect leaves out a vast portion of important physics. Nevertheless, for the sake of limiting the scope, this effect will not be discussed. The exposition is within the context of linear and quasilinear Vlasov kinetic theories. The discussion does not cover either computer simulations or data analyses of observations, in any systematic manner, although references will be made to published works pertaining to these methods. The scientific rationale for the present analysis is that the anisotropic temperatures associated with charged particles are pervasively detected in the solar wind, and it is one of the key contemporary scientific research topics to correctly characterize how such anisotropies are generated, maintained, and regulated in the solar wind. The present article aims to provide an up-to-date theoretical development on this research topic, largely based on the author's own work.

Electron temperature anisotropy constraints in the solar wind

Czech Academy of Sciences Publication Activity Database

Štverák, Štěpán; Trávníček, Pavel M.; Maksimovic, M.; Marsch, E.; Fazakerley, A.; Scime, E. E.

2008-01-01

Roč. 113, A3 /2008/ (2008), A03103/1-A03103/10 ISSN 0148-0227 R&D Projects: GA AV ČR IAA300420602 Grant - others:EU(XE) ESA-PECS project No. 98024 Institutional research plan: CEZ:AV0Z10030501; CEZ:AV0Z30420517 Keywords : solar wind electrons * temperature anisotropy * radial Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 3.147, year: 2008

Amide proton temperature coefficients as hydrogen bond indicators in proteins

International Nuclear Information System (INIS)

Cierpicki, Tomasz; Otlewski, Jacek

2001-01-01

Correlations between amide proton temperature coefficients (Δσ HN /ΔT) and hydrogen bonds were investigated for a data set of 793 amides derived from 14 proteins. For amide protons showing temperature gradients more positive than -4.6 ppb/K there is a hydrogen bond predictivity value exceeding 85%. It increases to over 93% for amides within the range between -4 and -1 ppb/K. Detailed analysis shows an inverse proportionality between amide proton temperature coefficients and hydrogen bond lengths. Furthermore, for hydrogen bonds of similar bond lengths, values of temperature gradients in α-helices are on average 1 ppb/K more negative than in β-sheets. In consequence, a number of amide protons in α-helices involved in hydrogen bonds shorter than 2 A show Δσ HN /ΔT 10 helices and 98% in β-turns have temperature coefficients more positive than -4.6ppb/K. Ring current effect also significantly influences temperature coefficients of amide protons. In seven out of eight cases non-hydrogen bonded amides strongly deshielded by neighboring aromatic rings show temperature coefficients more positive than -2 ppb/K. In general, amide proton temperature gradients do not change with pH unless they correspond to conformational changes. Three examples of pH dependent equilibrium showing hydrogen bond formation at higher pH were found. In conclusion, amide proton temperature coefficients offer an attractive and simple way to confirm existence of hydrogen bonds in NMR determined structures

Temperature dependence of exchange anisotropy in monodisperse cobalt nanoparticles with a cobalt oxide shell

International Nuclear Information System (INIS)

Spasova, M.; Wiedwald, U.; Farle, M.; Radetic, T.; Dahmen, U.; Hilgendorff, M.; Giersig, M.

2004-01-01

Exchange anisotropy was studied by SQUID magnetometry on an array of monodisperse colloidal nanoparticles consisting of a 7-8 nm diameter FCC Co core covered with a 2-2.5 nm thick FCC CoO shell. Temperature-dependent measurements of the exchange bias field show that the exchange anisotropy vanishes when a magnetic field was applied during cooling below 150 K. The suppression of exchange anisotropy is due to uncompensated interfacial antiferromagnetic spins

Exploring thermal anisotropy of cortical bone using temperature measurements in drilling.

Science.gov (United States)

Alam, Khurshid

2016-05-12

Bone drilling is widely used in orthopaedics for fracture treatment, reconstructive surgery and bone biopsy. Heat generation in bone drilling can cause rise in bone temperature resulting in prolonged healing time or loosening of fixation. The purpose of this study was to investigate thermal anisotropy of bone by measuring the level of temperature in bone drilling with and without cooling conditions in two anatomical directions. Drilling tests were performed on bovine cortical bone. A total of fifteen specimens were used to obtain data for statistical analysis. Temperature near the cutting zone was measured in two anatomical directions. i.e. along the longitudinal and circumferential direction. Temperature distribution was also found in the two prescribed directions. Analysis of variance (ANOVA) was used to identify significant drilling parameter affecting bone temperature. Drilling speed, feed rate and drill size were found influential parameters affecting bone temperature. Higher drilling speed, feed rate, and large drill size were found to cause elevated temperature in bone. Much lower temperature was measured in bone when cooling fluid was supplied to the drilling region. Experimental results revealed lower temperatures in the circumferential direction compared to the longitudinal direction. Thermal anisotropy for heat transport was found in the bone. This study recommends lower drilling speed and feed rate and cooling for controlling rise in bone temperature.

Properties of Localized Protons in Neutron Star Matter at Finite Temperatures

Science.gov (United States)

Szmaglinski, A.; Kubis, S.; Wójcik, W.

2014-02-01

We study properties of the proton component of neutron star matter for realistic nuclear models. Vanishing of the nuclear symmetry energy implies proton-neutron separation in dense nuclear matter. Protons which form admixture tend to be localized in potential wells. Here, we extend the description of proton localization to finite temperatures. It appears that the protons are still localized at temperatures typical for hot neutron stars. That fact has important astrophysical consequences. Moreover, the temperature inclusion leads to unexpected results for the behavior of the proton localized state.

TEMPERATURE ANISOTROPY IN THE PRESENCE OF ULTRA LOW FREQUENCY WAVES IN THE TERRESTRIAL FORESHOCK

International Nuclear Information System (INIS)

Selzer, L. A.; Hnat, B.; Osman, K. T.; Nakariakov, V. M.; Eastwood, J. P.; Burgess, D.

2014-01-01

We report the first study of the correlation between elevated solar wind core plasma temperatures and temperature anisotropy in the terrestrial foreshock. Plasma temperature is enhanced near the fire hose marginal stability threshold in the presence of ultra low frequency (ULF) large amplitude magnetic perturbations, which are intrinsically right-hand circularly polarized. Direct comparison of contemporaneous anisotropic temperatures in the upstream solar wind and the foreshock suggests that the net heating of plasma is mediated via increase of the parallel temperature in the foreshock region where the ULF waves are present. We consider the possibility that a mechanism based on Landau damping, where solar wind plasma temperature parallel to the background magnetic field is increased by interaction with oblique compressible fast magneto-acoustic ULF waves, influences temperature anisotropy

TEMPERATURE ANISOTROPY IN THE PRESENCE OF ULTRA LOW FREQUENCY WAVES IN THE TERRESTRIAL FORESHOCK

Energy Technology Data Exchange (ETDEWEB)

Selzer, L. A.; Hnat, B.; Osman, K. T.; Nakariakov, V. M. [Centre for Fusion, Space and Astrophysics, University of Warwick, Coventry CV4 7AL (United Kingdom); Eastwood, J. P. [Space and Atmospheric Physics, The Blackett Laboratory, Imperial College London, London (United Kingdom); Burgess, D., E-mail: L.A.Selzer@warwick.ac.uk [School of Physics and Astronomy, Queen Mary University of London (United Kingdom)

2014-06-10

We report the first study of the correlation between elevated solar wind core plasma temperatures and temperature anisotropy in the terrestrial foreshock. Plasma temperature is enhanced near the fire hose marginal stability threshold in the presence of ultra low frequency (ULF) large amplitude magnetic perturbations, which are intrinsically right-hand circularly polarized. Direct comparison of contemporaneous anisotropic temperatures in the upstream solar wind and the foreshock suggests that the net heating of plasma is mediated via increase of the parallel temperature in the foreshock region where the ULF waves are present. We consider the possibility that a mechanism based on Landau damping, where solar wind plasma temperature parallel to the background magnetic field is increased by interaction with oblique compressible fast magneto-acoustic ULF waves, influences temperature anisotropy.

Strength and Anisotropy in Tournemire Shale: Temperature, Pressure and Time Dependences

Science.gov (United States)

Bonnelye, A.; Schubnel, A.; Zhi, G.; David, C.; Dick, P.

2017-12-01

Time and temperature dependent rock deformation has both scientific and socio-economic implications for natural hazards, the oil and gas industry and nuclear waste disposal. During the past decades, most studies on brittle creep have focused on igneous rocks and porous sedimentary rocks. To our knowledge, only few studies have been carried out on the brittle creep behavior of shale. We conducted a series of creep experiments on shale specimens coming from the French Institute for Nuclear Safety (IRSN) underground research laboratory located in Tournemire, France, under two different temperatures (26°C, 75°C) and confining pressures (10 MPa, 80 MPa), for three orientations (σ1along, perpendicular and 45° to bedding). In these long-term experiments (approximately 10 days), stress and strains were recorded continuously, while ultrasonic acoustic velocities were recorded every 1 15 minutes. The brittle creep failure stress of our Tournemire shale samples was systematically observed 50% higher than its short-term peak strength, with larger final axial strain accumulated. During creep, ultrasonic wave velocities first decreased, and then increased gradually. The magnitude of elastic wave velocity variations showed an important orientation and temperature dependence: velocities measured perpendicular to bedding showed increased variation, variation that was enhanced at higher temperature and higher pressure. The case of complete elastic anisotropy reversal was observed for sample deformed perpendicular to bedding, with amount of axial strain needed to reach anisotropy reversal reduced at higher temperature. SEM observations highlight the competition between crack growth, sealing/healing, and possibly mineral rotation, pressure solution or anisotropic compaction during creep defromation. Our study highlights that the short-term peak strength has little meaning in shale material, which can over-consolidate importantly by `plastic' flow. In addition, we show that elastic

High temperature proton exchange membranes prepared from epoxycyclohexylethyltrimethoxysilane and amino trimethylene phosphonic acid as anhydrous proton conductors

International Nuclear Information System (INIS)

Chen, Cheng; Shen, Chunhui; Kong, Gengjin; Gao, Shanjun

2013-01-01

High temperature anhydrous proton exchange membranes based on phosphonic acid were prepared from epoxycyclohexylethyltrimethoxysilane (EHTMS) and amino trimethylene phosphonic acid (ATMP) by sol–gel process. The structures and properties of membranes with different phosphonic acid content were extensively characterized by FTIR, TG-DSC and XRD. Their proton conductivity under dry condition was also investigated under different temperature. The results show that the proton conductivity of the prepared membranes strongly depends on temperature, and the proton conductivity ranges from 8.81 × 10 −5 S cm −1 at 20 °C to 4.65 × 10 −2 S cm −1 at 140 °C under anhydrous condition. It indicates that the increasing temperature is favorable for congregating of the grafted–PO 3 H 2 and increasing of the proton mobility. In addition, from the results of AFM images, it was confirmed that the continuous distribution of phosphonic acid groups is favorable for the formation of the proton transport channel, which can significantly enhance the proton conductivity of the membranes. Highlights: ► Hybrid membranes of Epoxycyclohexylethyltrimethoxysilane and Amino trimethylene phosphonic acid. ► The proton conductivity is 4.65 × 10 −2 S cm −1 at 140 °C under anhydrous condition. ► Continuous uniform distributions of phosphonic acid groups can be observed by AFM. ► There could be hydrogen bond network within high temperature membranes

High temperature proton exchange membranes prepared from epoxycyclohexylethyltrimethoxysilane and amino trimethylene phosphonic acid as anhydrous proton conductors

Energy Technology Data Exchange (ETDEWEB)

Chen, Cheng [Department of Polymer Materials and Engineering, School of Material Science and Engineering, Wuhan University of Technology, No. 122 Luoshi Road, Wuhan 430070 (China); Shen, Chunhui, E-mail: shenchunhui@whut.edu.cn [Department of Polymer Materials and Engineering, School of Material Science and Engineering, Wuhan University of Technology, No. 122 Luoshi Road, Wuhan 430070 (China); Kong, Gengjin; Gao, Shanjun [Department of Polymer Materials and Engineering, School of Material Science and Engineering, Wuhan University of Technology, No. 122 Luoshi Road, Wuhan 430070 (China)

2013-06-15

High temperature anhydrous proton exchange membranes based on phosphonic acid were prepared from epoxycyclohexylethyltrimethoxysilane (EHTMS) and amino trimethylene phosphonic acid (ATMP) by sol–gel process. The structures and properties of membranes with different phosphonic acid content were extensively characterized by FTIR, TG-DSC and XRD. Their proton conductivity under dry condition was also investigated under different temperature. The results show that the proton conductivity of the prepared membranes strongly depends on temperature, and the proton conductivity ranges from 8.81 × 10{sup −5} S cm{sup −1} at 20 °C to 4.65 × 10{sup −2} S cm{sup −1} at 140 °C under anhydrous condition. It indicates that the increasing temperature is favorable for congregating of the grafted–PO{sub 3}H{sub 2} and increasing of the proton mobility. In addition, from the results of AFM images, it was confirmed that the continuous distribution of phosphonic acid groups is favorable for the formation of the proton transport channel, which can significantly enhance the proton conductivity of the membranes. Highlights: ► Hybrid membranes of Epoxycyclohexylethyltrimethoxysilane and Amino trimethylene phosphonic acid. ► The proton conductivity is 4.65 × 10{sup −2} S cm{sup −1} at 140 °C under anhydrous condition. ► Continuous uniform distributions of phosphonic acid groups can be observed by AFM. ► There could be hydrogen bond network within high temperature membranes.

Temperature-Dependent Three-Dimensional Anisotropy of the Magnetoresistance in WTe_{2}.

Science.gov (United States)

Thoutam, L R; Wang, Y L; Xiao, Z L; Das, S; Luican-Mayer, A; Divan, R; Crabtree, G W; Kwok, W K

2015-07-24

Extremely large magnetoresistance (XMR) was recently discovered in WTe_{2}, triggering extensive research on this material regarding the XMR origin. Since WTe_{2} is a layered compound with metal layers sandwiched between adjacent insulating chalcogenide layers, this material has been considered to be electronically two-dimensional (2D). Here we report two new findings on WTe_{2}: (1) WTe_{2} is electronically 3D with a mass anisotropy as low as 2, as revealed by the 3D scaling behavior of the resistance R(H,θ)=R(ϵ_{θ}H) with ϵ_{θ}=(cos^{2}θ+γ^{-2}sin^{2}θ)^{1/2}, θ being the magnetic field angle with respect to the c axis of the crystal and γ being the mass anisotropy and (2) the mass anisotropy γ varies with temperature and follows the magnetoresistance behavior of the Fermi liquid state. Our results not only provide a general scaling approach for the anisotropic magnetoresistance but also are crucial for correctly understanding the electronic properties of WTe_{2}, including the origin of the remarkable "turn-on" behavior in the resistance versus temperature curve, which has been widely observed in many materials and assumed to be a metal-insulator transition.

In-plane magnetic anisotropy and temperature dependence of switching field in (Ga, Mn) as ferromagnetic semiconductors.

Science.gov (United States)

Kamara, S; Terki, F; Dumas, R; Dehbaoui, M; Sadowski, J; Galéra, R M; Tran, Q-H; Charar, S

2012-06-01

We explore the magnetic anisotropy of GaMnAs ferromagnetic semiconductor by Planar Hall Effect (PHE) measurements. Using low magnitude of applied magnetic field (i.e., when the magnitude H is smaller than both cubic Hc and uniaxial Hu anisotropy field), we have observed various shapes of applied magnetic field direction dependence of Planar Hall Resistance (PHR). In particular, in two regions of temperature. At T Tc/2 the "zigzag-shape" signal of PHR. They reflect different magnetic anisotropy and provide information about magnetization reversal process in GaMnAs ferromagnetic semiconductor. The theoretical model calculation of PHR based on the free energy density reproduces well the experimental data. We report also the temperature dependence of anisotropy constants and magnetization orientations. The transition of easy axis from biaxial to uniaxiale axes has been observed and confirmed by SQUID measurements.

Temperature anisotropy instabilities in a plasma containing cold and hot species in the magnetosphere

International Nuclear Information System (INIS)

Renuka, G.; Viswanathan, K.S.

1980-01-01

The nature of convective instability has been investigated for an electromagnetic wave, either right circularly polarised or left circularly polarised, propagating along a magnetic line of force in a plasma whose distribution function exhibits a temperature anisotropy in the hot species, a loss cone structure and a beam of cold electrons or ions travelling along the line of force with velocity V 1 . Detailed numerical calculations have been made using a computer for the growth and decay of the wave for different values of the anisotropy ratio Tsub(perpendicular to)/Tsub(parallel to) delta of the perpendicular and parallel temperatures, the McIlwain parameter L, the loss cone index j, velocity V 1 of the streaming particle and the particle density ratio epsilon. The ranges of the values of epsilon and delta for which the waves becomes unstable have been studied in detail. It is found that wave propagation shows no dependence on the loss cone index but shows very strong dependence on the temperature anisotropy delta. (author)

Shaping the solar wind electron temperature anisotropy by the interplay of core and suprathermal populations

Science.gov (United States)

Shaaban Hamd, S. M.; Lazar, M.; Poedts, S.; Pierrard, V.; Štverák

2017-12-01

We present the results of an advanced parametrization of the temperature anisotropy of electrons in the slow solar wind and the electromagnetic instabilities resulting from the interplay of their thermal core and suprathermal halo populations. A large set of observational data (from the Ulysses, Helios and Cluster missions) is used to parametrize these components and establish their correlations. Comparative analysis demonstrates for the first time a particular implication of the suprathermal electrons which are less dense but hotter than thermal electrons. The instabilities are significantly stimulated by the interplay of the core and halo populations, leading to lower thresholds which shape the observed limits of the temperature anisotropy for both the core and halo populations. This double agreement strongly suggests that the selfgenerated instabilities play the major role in constraining the electron anisotropy.

Magnetic anisotropy and pressure dependence of the order temperature in the Gd3(FeTi)29 compound

International Nuclear Information System (INIS)

Morellon, L.; Arnold, Z.; Pareti, L.; Albertini, F.; Paoluzi, A.

1995-01-01

In this work we report ac initial magnetic susceptibility under pressure, singular point detection (SPD) and linear thermal expansion measurements in the Gd 3 (FeTi) 29 intermetallic compound. From these measurements we have determined the anisotropy field, the order temperature and its pressure dependence. The thermal expansion measurement shows an Invar-like anomaly at the order temperature, T C =520 K, which decreases under increasing pressure with a slope of dT C /dp=-2.7 K/kbar. As the Gd 3+ ion is isotropic, no contribution to the anisotropy from the 4f sublattice is expected and low values of the anisotropy fields have been observed. (orig.)

Modelling temporal variance of component temperatures and directional anisotropy over vegetated canopy

Science.gov (United States)

Bian, Zunjian; du, yongming; li, hua

2016-04-01

Land surface temperature (LST) as a key variable plays an important role on hydrological, meteorology and climatological study. Thermal infrared directional anisotropy is one of essential factors to LST retrieval and application on longwave radiance estimation. Many approaches have been proposed to estimate directional brightness temperatures (DBT) over natural and urban surfaces. While less efforts focus on 3-D scene and the surface component temperatures used in DBT models are quiet difficult to acquire. Therefor a combined 3-D model of TRGM (Thermal-region Radiosity-Graphics combined Model) and energy balance method is proposed in the paper for the attempt of synchronously simulation of component temperatures and DBT in the row planted canopy. The surface thermodynamic equilibrium can be final determined by the iteration strategy of TRGM and energy balance method. The combined model was validated by the top-of-canopy DBTs using airborne observations. The results indicated that the proposed model performs well on the simulation of directional anisotropy, especially the hotspot effect. Though we find that the model overestimate the DBT with Bias of 1.2K, it can be an option as a data reference to study temporal variance of component temperatures and DBTs when field measurement is inaccessible

Anisotropy function for pion-proton elastic scattering

Energy Technology Data Exchange (ETDEWEB)

Saleem, Mohammad; Fazal-e-Aleem; Rashid, Haris

1988-09-01

By using the generalised Chou-Yang model and the experimental data on ..pi../sup -/p elastic scattering at 200 GeV/c, the anisotropy function which reflects the non-isotropic nature of elastic scattering is computed for the reaction ..pi../sup -/p -> ..pi../sup -/p.

Anisotropy function for pion-proton elastic scattering

International Nuclear Information System (INIS)

Saleem, Mohammad; Fazal-e-Aleem; Rashid, Haris

1988-01-01

By using the generalised Chou-Yang model and the experimental data on π - p elastic scattering at 200 GeV/c, the anisotropy function which reflects the non-isotropic nature of elastic scattering is computed for the reaction π - p → π - p. (author)

Temperature dependence of the magnetic anisotropy of metallic Y-Ba-Cu-O single crystals in the normal phase

International Nuclear Information System (INIS)

Miljak, M.; Zlatic, V.; Kos, I.; Aviani, I.; Hamzic, A.; Collin, G.

1990-01-01

The magnetic anisotropy measurements of metallic Y-Ba-Cu-O compounds in the normal phase reveal a temperature-dependent diamagnetic component of the susceptibility that increases with decreasing temperature. The temperature variation of the susceptibility anisotropy and its total change do not seem to be much affected by the presence of the superconductivity at some lower temperature and could not be accounted for by superconducting fluctuations. Rather, the data remind one of the behavior of some quasi-two-dimensional metals with anisotropic Fermi surfaces, reflecting the properties of the low-energy excitations in the normal phase. The anisotropy measurements above the bulk superconducting transition temperature T c reveal the nonlinear effects, which are due to the onset of superconductivity in disconnected grains. The existence of a two-step transition, typical for granular superconductors, should be taken into consideration if the normal-phase susceptibility data are compared with the theoretical predictions in the vicinity of T c

Effect of Temperature on the Protonation of the TALSPEAK Ligands: Lactic and Diethylenetrinitropentaacetic Acids

International Nuclear Information System (INIS)

Tian, Guoxin; Rao, Linfeng

2009-01-01

The protonation reactions of two ligands that play important roles in the TALSPEAK process for the separation of trivalent actinides from lanthanides, lactic acid and diethylenetrinitropentaacetic acid (DTPA), have been studied at variable temperatures. The protonation constants at 10-70 C were determined by titration potentiometry and the protonation enthalpies were determined at 25 C by titration microcalorimetry. The protonation constants remain essentially unchanged (25-70 C) within the experimental uncertainties, indicating that the effect of temperature on the protonation of lactate is insignificant. In contrast, the protonation constants of DTPA (log βH's) generally decrease as the temperature is increased. Results from this study indicate that the effect of temperature on the protonation of DTPA could alter the speciation of metal ions (actinides and lanthanides) in the TALSPEAK system, since lower values of logβH at higher temperatures suggest that the hydrogen ions would compete less strongly with the metal ions for the complexation of DTPA at higher temperatures.

Proton core-beam system in the expanding solar wind: Hybrid simulations

Czech Academy of Sciences Publication Activity Database

Hellinger, Petr; Trávníček, Pavel M.

2011-01-01

Roč. 116, A11 (2011), A11101/1-A11101/13 ISSN 0148-0227 R&D Projects: GA AV ČR IAA300420702 Grant - others:European Space Agency(XE) PECS contract No. 98068; European Commissions(XE) SWIFF (project 263340) Institutional research plan: CEZ:AV0Z30420517; CEZ:AV0Z10030501 Keywords : ELECTROMAGNETIC PROTON/PROTON INSTABILITIES * VELOCITY SPACE DIFFUSION * WAVE-WAVE SCATTERING * TEMPERATURE ANISOTROPY * PLASMA * DRIFT * DISTRIBUTIONS Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 3.021, year: 2011 http://www.agu.org/pubs/crossref/2011/2011JA016940.shtml

Ion temperature anisotropy effects on threshold conditions of a shear-modified current driven electrostatic ion-acoustic instability in the topside auroral ionosphere

Directory of Open Access Journals (Sweden)

P. J. G. Perron

2013-03-01

Full Text Available Temperature anisotropies may be encountered in space plasmas when there is a preferred direction, for instance, a strong magnetic or electric field. In this paper, we study how ion temperature anisotropy can affect the threshold conditions of a shear-modified current driven electrostatic ion-acoustic (CDEIA instability. In particular, this communication focuses on instabilities in the context of topside auroral F-region situations and in the limit where finite Larmor radius corrections are small. We derived a new fluid-like expression for the critical drift which depends explicitly on ion anisotropy. More importantly, for ion to electron temperature ratios typical of F-region, solutions of the kinetic dispersion relation show that ion temperature anisotropy may significantly lower the drift threshold required for instability. In some cases, a perpendicular to parallel ion temperature ratio of 2 and may reduce the relative drift required for the onset of instability by a factor of approximately 30, assuming the ion-acoustic speed of the medium remains constant. Therefore, the ion temperature anisotropy should be considered in future studies of ion-acoustic waves and instabilities in the high-latitude ionospheric F-region.

Effects of ion temperature anisotropy on the interhemispheric plasma transport during plasmaspheric refilling

International Nuclear Information System (INIS)

Singh, N.; Torr, D.G.

1990-01-01

Effects of temperature anisotropies on the early stage refilling of the outer plasmasphere are studied by solving an appropriate set of hydrodynamic equations. The anisotropies result from the supersonic outflows from the conjugate ionospheres and from the perpendicular ion heating in the equatorial region. The equatorial ion heating affected by wave-particle interaction is included phenomenologically. Even for the equatorial heating associated with moderate wave levels, the mirror force on the flows severely limits the interhemispheric plasma exchange. The temporal evolution of the flow developing in an empty flux tube is characterized by: (1) supersonic plasma outflows from the conjugate ionospheres, (2) reflections of the flows by the mirror force as they begin to penetrate into the opposite hemispheres, (3) formation of shocks in the reflection region and (4) propagations of the shocks to the ionospheres of the origins of the flows. In the quasi-steady state when flow completely subsides, the density distribution in the flux tube shows distinctive large-scale features, determined by the balance between electric, pressure and anisotropy forces. The latter force becomes significant in a broad equatorial region where T t >> T p and also at relatively high geomagnetic latitudes where T t p ; T t and T p are the perpendicular and parallel ion temperatures, respectively

Effects of trapped proton flux anisotropy on dose rates in low Earth orbit

International Nuclear Information System (INIS)

Badhwar, G.D.; Kushin, V.V.; Akatov, Yu A.; Myltseva, V.A.

1999-01-01

Trapped protons in the South Atlantic Anomaly (SAA) have a rather narrow pitch angle distribution and exhibit east-west anisotropy. In low Earth orbits, the E-W effect results in different amounts of radiation dose received by different sections of the spacecraft. This effect is best studied on missions in which the spacecraft flies in a fixed orientation. The magnitude of the effect depends on the particle energy and altitude through the SAA. In this paper, we describe a clear example of this effect from measurements of radiation dose rates and linear energy transfer spectra made on Space Shuttle flight STS-94 (28.5 deg. inclination x 296 km altitude). The ratio of dose rates from the two directions at this location in the mid-deck was 2.7. As expected from model calculations, the spectra from the two directions are different, that is the ratio is energy dependent. The data can be used to distinguish the anisotropy models. The flight carried an active tissue equivalent proportional counter (TEPC), and passive thermoluminscent detectors (TLDs), and two types of nuclear emulsions. Using nuclear emulsions, charged particles and secondary neutron energy spectra were measured. The combined galactic cosmic radiation+trapped charged particle lineal energy spectra measured by the TEPC and the linear energy transfer spectrum measured by nuclear emulsions are in good agreement. The charged particle absorbed dose rates varied from 112 to 175 μGy/day, and dose equivalent rates from 264.3 to 413 μSv/day. Neutrons in the 1-10 MeV contributed a dose rate of 3.7 μGy/day and dose equivalent rate of 30.8 μSv/day, respectively

Effects of trapped proton flux anisotropy on dose rates in low Earth orbit.

Science.gov (United States)

Badhwar, G D; Kushin, V V; Akatov YuA; Myltseva, V A

1999-06-01

Trapped protons in the South Atlantic Anomaly (SAA) have a rather narrow pitch angle distribution and exhibit east-west anisotropy. In low Earth orbits, the E-W effect results in different amounts of radiation dose received by different sections of the spacecraft. This effect is best studied on missions in which the spacecraft flies in a fixed orientation. The magnitude of the effect depends on the particle energy and altitude through the SAA. In this paper, we describe a clear example of this effect from measurements of radiation dose rates and linear energy transfer spectra made on Space Shuttle flight STS-94 (28.5 degree inclination x 296 km altitude). The ratio of dose rates from the two directions at this location in the mid-deck was 2.7. As expected from model calculations, the spectra from the two directions are different, that is the ratio is energy dependent. The data can be used to distinguish the anisotropy models. The flight carried an active tissue equivalent proportional counter (TEPC), and passive thermoluminscent detectors (TLDs), and two types of nuclear emulsions. Using nuclear emulsions, charged particles and secondary neutron energy spectra were measured. The combined galactic cosmic radiation+trapped charged particle lineal energy spectra measured by the TEPC and the linear energy transfer spectrum measured by nuclear emulsions are in good agreement. The charged particle absorbed dose rates varied from 112 to 175 microGy/day, and dose equivalent rates from 264.3 to 413 microSv/day. Neutrons in the 1-10 MeV contributed a dose rate of 3.7 microGy/day and dose equivalent rate of 30.8 microSv/day, respectively.

Metal Phosphates as Intermediate Temperature Proton Conducting Electrolytes

DEFF Research Database (Denmark)

Huang, Yunjie; Li, Q.F.; Pan, Chao

2012-01-01

A series of metal phosphates were synthesized and screened as potential proton conductor electrolytes for fuel cells and electrolysers operational at intermediate temperatures. Among the selected, niobium and bismuth phosphates exhibited a proton conductivity of 10-2 and 10-7 S cm-1, respectively......, under the anhydrous atmosphere at 250 °C, showing close correlation with the presence of hydroxyl groups in the phosphate phases. At the water partial pressure of above 0.6 atm, both phosphates possessed a proton conductivity to a level of above 3 x 10-2 S cm-1. Reasonable stability of the proton...... conductivity was observed under either a constant low water partial pressure or under a humidity cycling test within a period of more than 80 hours....

Detection of zero anisotropy at 5.2 AU during the November 1998 solar particle event: Ulysses Anisotropy Telescopes observations

Directory of Open Access Journals (Sweden)

S. Dalla

Full Text Available For the first time during the mission, the Anisotropy Telescopes instrument on board the Ulysses spacecraft measured constant zero anisotropy of protons in the 1.3-2.2 MeV energy range, for a period lasting more than three days. This measurement was made during the energetic particle event taking place at Ulysses between 25 November and 15 December 1998, an event characterised by constant high proton fluxes within a region delimited by two interplanetary forward shocks, at a distance of 5.2 AU from the Sun and heliographic latitude of 17°S. We present the ATs results for this event and discuss their possible interpretation and their relevance to the issue of intercalibration of the two telescopes.

Key words: Interplanetary physics (energetic particles - Solar physics, astrophysics and astronomy (energetic particles - Space plasma physics (instruments and techniques

Three-dimensional spin mapping of antiferromagnetic nanopyramids having spatially alternating surface anisotropy at room temperature.

Science.gov (United States)

Wang, Kangkang; Smith, Arthur R

2012-11-14

Antiferromagnets play a key role in modern spintronic devices owing to their ability to modify the switching behavior of adjacent ferromagnets via the exchange bias effect. Consequently, detailed measurements of the spin structure at antiferromagnetic interfaces and surfaces are highly desirable, not only for advancing technologies but also for enabling new insights into the underlying physics. Here using spin-polarized scanning tunneling microscopy at room-temperature, we reveal in three-dimensions an orthogonal spin structure on antiferromagnetic compound nanopyramids. Contrary to expected uniaxial anisotropy based on bulk properties, the atomic terraces are found to have alternating in-plane and out-of-plane magnetic anisotropies. The observed layer-wise alternation in anisotropy could have strong influences on future nanoscale spintronic applications.

Daytime Thermal Anisotropy of Urban Neighbourhoods: Morphological Causation

Directory of Open Access Journals (Sweden)

E. Scott Krayenhoff

2016-01-01

Full Text Available Surface temperature is a key variable in boundary-layer meteorology and is typically acquired by remote observation of emitted thermal radiation. However, the three-dimensional structure of cities complicates matters: uneven solar heating of urban facets produces an “effective anisotropy” of surface thermal emission at the neighbourhood scale. Remotely-sensed urban surface temperature varies with sensor view angle as a consequence. The authors combine a microscale urban surface temperature model with a thermal remote sensing model to predict the effective anisotropy of simplified neighbourhood configurations. The former model provides detailed surface temperature distributions for a range of “urban” forms, and the remote sensing model computes aggregate temperatures for multiple view angles. The combined model’s ability to reproduce observed anisotropy is evaluated against measurements from a neighbourhood in Vancouver, Canada. As in previous modeling studies, anisotropy is underestimated. Addition of moderate coverages of small (sub-facet scale structure can account for much of the missing anisotropy. Subsequently, over 1900 sensitivity simulations are performed with the model combination, and the dependence of daytime effective thermal anisotropy on diurnal solar path (i.e., latitude and time of day and blunt neighbourhood form is assessed. The range of effective anisotropy, as well as the maximum difference from nadir-observed brightness temperature, peak for moderate building-height-to-spacing ratios (H/W, and scale with canyon (between-building area; dispersed high-rise urban forms generate maximum anisotropy. Maximum anisotropy increases with solar elevation and scales with shortwave irradiance. Moreover, it depends linearly on H/W for H/W < 1.25, with a slope that depends on maximum off-nadir sensor angle. Decreasing minimum brightness temperature is primarily responsible for this linear growth of maximum anisotropy. These

Thermodynamics of protonation of amines in aqueous solutions at elevated temperatures

Energy Technology Data Exchange (ETDEWEB)

Kim, Inna, E-mail: inna.kim@sintef.no [SINTEF Materials and Chemistry, N-7465 Trondheim (Norway); Jens, Christian M., E-mail: chrijens@stud.ntnu.no [Norwegian University of Science and Technology (NTNU), N-7491 Trondheim (Norway); Grimstvedt, Andreas, E-mail: andreas.grimstvedt@sintef.no [SINTEF Materials and Chemistry, N-7465 Trondheim (Norway); Svendsen, Hallvard F., E-mail: hallvard.svendsen@chemeng.ntnu.no [Norwegian University of Science and Technology (NTNU), N-7491 Trondheim (Norway)

2011-11-15

Highlights: > Effect of ionic strength and temperature on dissociation constants of amines. > Effect of ionic strength of temperature on enthalpies of protonation of amines. > Measured dissociation constants and enthalpies of protonation used for fitting. > Coefficients for thermodynamically consistent correlations given for 5 amines. - Abstract: The dissociation constants, pK{sub a}, of monoethanolamine (MEA), N-methyldiethanolamine (MDEA), 2-amino-2-methyl-1-propanol (AMP), 2(2-aminoethyl)etanolamine (AEEA), and piperazine (Pz) were measured by potentiometric titration over the temperature range (298.15 to 363.15) K. Enthalpies of protonation, {Delta}H{sub p}, were measured calorimetrically at temperatures from (298.15 to 393.15) K for MEA, MDEA, and AMP, and from (298.15 to 353.15) K for AEEA and Pz. In addition, the effect of the ionic strength of the solutions on the protonation of MDEA was studied using NaCl as background salt {l_brace}(0 to 5.5) mol/kg-H{sub 2}O){r_brace}. Correlations for the reaction equilibrium constants for proton dissociation are proposed for the studied amines based on the experimental data from literature and from this work. Both experimental enthalpy data and dissociation constants were used for fitting. The results from this work may be used for thermodynamic modeling of CO{sub 2} capture processes using amines.

Large diffusion anisotropy and orientation sorting of phosphorene nanoflakes under a temperature gradient.

Science.gov (United States)

Cheng, Yuan; Zhang, Gang; Zhang, Yingyan; Chang, Tienchong; Pei, Qing-Xiang; Cai, Yongqing; Zhang, Yong-Wei

2018-01-25

We perform molecular dynamics simulations to investigate the motion of phosphorene nanoflakes on a large graphene substrate under a thermal gradient. It is found that the atomic interaction between the graphene substrate and the phosphorene nanoflake generates distinct rates of motion for phosphorene nanoflakes with different orientations. Remarkably, for square phosphorene nanoflakes, the motion of zigzag-oriented nanoflakes is 2-fold faster than those of armchair-oriented and randomly-oriented nanoflakes. This large diffusion anisotropy suggests that sorting of phosphorene nanoflakes into specific orientations can be realized by a temperature gradient. The findings here provide interesting insights into strong molecular diffusion anisotropy and offer a novel route for manipulating two-dimensional materials.

A Bayesian approach to infer the radial distribution of temperature and anisotropy in the transition zone from seismic data

Science.gov (United States)

Drilleau, M.; Beucler, E.; Mocquet, A.; Verhoeven, O.; Moebs, G.; Burgos, G.; Montagner, J.

2013-12-01

Mineralogical transformations and matter transfers within the Earth's mantle make the 350-1000 km depth range (considered here as the mantle transition zone) highly heterogeneous and anisotropic. Most of the 3-D global tomographic models are anchored on small perturbations from 1-D models such as PREM, and are secondly interpreted in terms of temperature and composition distributions. However, the degree of heterogeneity in the transition zone can be strong enough so that the concept of a 1-D reference seismic model may be addressed. To avoid the use of any seismic reference model, we developed a Markov chain Monte Carlo algorithm to directly interpret surface wave dispersion curves in terms of temperature and radial anisotropy distributions, considering a given composition of the mantle. These interpretations are based on laboratory measurements of elastic moduli and Birch-Murnaghan equation of state. An originality of the algorithm is its ability to explore both smoothly varying models and first-order discontinuities, using C1-Bézier curves, which interpolate the randomly chosen values for depth, temperature and radial anisotropy. This parameterization is able to generate a self-adapting parameter space exploration while reducing the computing time. Using a Bayesian exploration, the probability distributions on temperature and anisotropy are governed by uncertainties on the data set. The method was successfully applied to both synthetic data and real dispersion curves. Surface wave measurements along the Vanuatu- California path suggest a strong anisotropy above 400 km depth which decreases below, and a monotonous temperature distribution between 350 and 1000 km depth. On the contrary, a negative shear wave anisotropy of about 2 % is found at the top of the transition zone below Eurasia. Considering compositions ranging from piclogite to pyrolite, the overall temperature profile and temperature gradient are higher for the continental path than for the oceanic

The temperature dependence of magnetic anisotropy of Nd-Fe-B thin films

Science.gov (United States)

Sato, Takuya; Hashimoto, Ryuji; Tanaka, Yoshitomo; Suzuki, Kenichi; Enokido, Yasushi; Choi, Kyung-Ku; Suzuki, Takao

2018-05-01

The magnetic properties of Nd-Fe-B thin films with the three different compositions (#1: Nd12.6Fe81.5B5.9, #2: Nd14.6Fe78.1B7.4 and #3: Nd22.6Fe66.2B11.2) are discussed. With increasing Nd content, the c-axis orientation along the film normal is enhanced. It is found that sample #2 possesses the saturation magnetization Ms very close to that for Nd2Fe14B over a temperature range from 100 to about 300K. The magnetic anisotropy constant Ku2 for sample #2 is the highest among those samples, but smaller by about 20%, as compared to that for Nd2Fe14B. It is of interest to note that the temperature TR at which Ku1 changes its sign is lower by about 30K as compared to that previously reported for Nd2Fe14B. The reason for this discrepancy is not clear, but could be due to the presence of the minority phases of Nd-rich compounds and also a possible contribution of the magneto-elastic effect to the net magnetic anisotropy.

Finite-temperature dynamic structure factor of the spin-1 XXZ chain with single-ion anisotropy

Science.gov (United States)

Lange, Florian; Ejima, Satoshi; Fehske, Holger

2018-02-01

Improving matrix-product state techniques based on the purification of the density matrix, we are able to accurately calculate the finite-temperature dynamic response of the infinite spin-1 XXZ chain with single-ion anisotropy in the Haldane, large-D , and antiferromagnetic phases. Distinct thermally activated scattering processes make a significant contribution to the spectral weight in all cases. In the Haldane phase, intraband magnon scattering is prominent, and the on-site anisotropy causes the magnon to split into singlet and doublet branches. In the large-D phase response, the intraband signal is separated from an exciton-antiexciton continuum. In the antiferromagnetic phase, holons are the lowest-lying excitations, with a gap that closes at the transition to the Haldane state. At finite temperatures, scattering between domain-wall excitations becomes especially important and strongly enhances the spectral weight for momentum transfer π .

Intermolecular hydrogen bonds: From temperature-driven proton ...

Indian Academy of Sciences (India)

Abstract. We have combined neutron scattering and a range of numerical simulations to study hydrogen bonds in condensed matter. Two examples from a recent thesis will be presented. The first concerns proton transfer with increasing temperature in short inter- molecular hydrogen bonds [1,2]. These bonds have unique ...

Mixed conduction protonic/electronic ceramic for high temperature electrolysis anode

International Nuclear Information System (INIS)

Goupil, Gregory

2011-01-01

This thesis validates the concept of mixed electron/proton ceramic conductors to be used as anode materials for intermediate temperature steam electrolyzer. The materials developed are based on cobaltites of alkaline-earth metals and rare earth elements commonly used for their high electronic conductivity in the temperature range of 300-600 C. The stability of each material has been assessed during 350 h in air and moist air. After checking the chemical compatibility with the BaZr 0.9 Y 0.1 O 3 electrolyte material, eight compositions have been selected: BaCoO 3 , LaCoO 3 , Sr 0.5 La 0.5 CoO 3 , Ba 0.5 La 0.5 CoO 3 , GdBaCo 2 O 5 , NdBaCo 2 O 5 , SmBaCo 2 O 5 and PrBaCo 2 O 5 . The thermal evolution of the oxygen stoichiometry of each material was determined by coupling iodo-metric titration and TGA in dry air. TGA in moist air has allowed determining the optimum temperature range for which proton incorporation is possible and maximized. Proton incorporation profiles have been determined on two cobaltites using SIMS and nuclear microanalysis in the ERDA configuration. Deuterium diffusion coefficients have been determined confirming the proton mobility in these materials. Under moist air, NdBaCo 2 O 5 is shown to incorporate rapidly a significant number of protons that spread homogeneously within the material bulk. Anode microstructure optimization has allowed reaching at 450 C and 600 C total resistance values on symmetrical cell highly promising. (author) [fr

Proton polarization in photo-excited aromatic molecule at room temperature enhanced by intense optical source and temperature control

Energy Technology Data Exchange (ETDEWEB)

Sakaguchi, S., E-mail: sakaguchi@phys.kyushu-u.ac.jp [Department of Physics, Kyushu University, Fukuoka 812-8581 (Japan); Uesaka, T. [RIKEN Nishina Center, Saitama 351-0198 (Japan); Kawahara, T. [Department of Physics, Toho University, Chiba 274-8510 (Japan); Ogawa, T. [RIKEN Advanced Science Institute, Saitama 351-0198 (Japan); Tang, L. [Center for Nuclear Study, University of Tokyo, Tokyo 113-0001 (Japan); Teranishi, T. [Department of Physics, Kyushu University, Fukuoka 812-8581 (Japan); Urata, Y.; Wada, S. [RIKEN Advanced Science Institute, Saitama 351-0198 (Japan); Wakui, T. [Cyclotron and Radioisotope Center (CYRIC), Tohoku University, Miyagi 980-8578 (Japan)

2013-12-15

Highlights: • Proton polarization in p-terphenyl at room-temperature is enhanced by a factor of 3. • Intense laser and temperature control are critically important for high polarization. • Optimization of time structure of laser pulse is effective for further improvement. -- Abstract: Proton polarization at room temperature, produced in a p-terphenyl crystal by using electron population difference in a photo-excited triplet state of pentacene, was enhanced by utilizing an intense laser with an average power of 1.5 W. It was shown that keeping the sample temperature below 300 K is critically important to prevent the rise of the spin–lattice relaxation rate caused by the laser heating. It is also reported that the magnitude of proton polarization strongly depends on the time structure of the laser pulse such as its width and the time interval between them.

Odd azimuthal anisotropy of the Glasma for pA scattering

Energy Technology Data Exchange (ETDEWEB)

McLerran, Larry [Institute for Nuclear Theory, University of Washington, Box 351550, Seattle, WA 98195 (United States); China Central Normal University, Wuhan (China); Skokov, Vladimir, E-mail: v.skokov@gsi.de [RIKEN/BNL, Brookhaven National Laboratory, Upton, NY 11973 (United States)

2017-03-15

In this paper we analytically extract the odd azimuthal anisotropy in the Classical Yang–Mills equations for the Glasma for pA collisions. We compute the first non-trivial term in the expansion of the proton sources of color charge. The computation is valid in the limit of a large nucleus when the produced particle momenta are larger than the saturation momentum of the proton.

High field magnetic anisotropy in praseodymium gallium garnet at low temperatures

International Nuclear Information System (INIS)

Wang Wei; Yue Yuan; Liu Gongqiang

2011-01-01

Research highlights: → A detailed analysis of crystal field effect is presented, and a set of new crystal field parameters is given to study the magnetic behaviors of the paramagnetic praseodymium gallium garnet (PrGaG). → The contribution of the exchange interaction between the praseodymium ions to the magnetic properties of PrGaG is further explored. Meanwhile, some characteristics of exchange interaction are revealed. → With the consideration of crystal field and exchange interaction, the available experiments are successfully fitted by our theoretical model. → Our theory suggests that PrGaG is ferromagnetic ordering at low temperatures, and the exchange interaction is anisotropic. - Abstract: In this paper, with the consideration of crystal field and exchange interaction between the rare-earth Pr 3+ ions, the magnetic anisotropy in praseodymium gallium garnet (PrGaG) in high magnetic fields and at low temperatures is theoretically analyzed. A set of relatively suitable CF parameters is obtained by studying the influence of the variations of nine CF parameters on the magnetization. However, only taking crystal field effect into account, theoretical calculations indicate that the experiments cannot be excellently interpreted. Then, the exchange interaction between Pr 3+ ion, which can be described as an effective exchange field H v = vM = vχH e = ηH e , is further considered. On the other hand, by evaluating the variation of the parameter η with the magnetic fields, our theory implies that PrGaG exhibits ferrimagnetic ordering at low temperatures, and the exchange interaction in PrGaG displays obvious anisotropy. Also, the theoretical data show better agreements with the experimental results.

Voyager observations of solar wind proton temperature - 1-10 AU

Science.gov (United States)

Gazis, P. R.; Lazarus, A. J.

1982-01-01

Simultaneous measurements are made of the solar wind proton temperatures by the Voyager 1 and 2 spacecraft, far from earth, and the IMP 8 spacecraft in earth orbit. This technique permits a separation of radial and temporal variations of solar wind parameters. The average value of the proton temperature between 1 and 9 AU is observed to decrease as r (the heliocentric radius) to the -(0.7 + or - 0.2). This is slower than would be expected for adiabatic expansion. A detailed examination of the solar wind stream structure shows that considerable heating occurs at the interface between high and low speed streams.

Surface energy anisotropy of tungsten

Energy Technology Data Exchange (ETDEWEB)

Kumar, R; Grenga, H E [Georgia Inst. of Tech., Atlanta (USA). School of Chemical Engineering

1976-10-01

Field-ion microscopy was used to study the faceting behavior and/or surface energy anisotropy of tungsten in vacuum and in hydrogen. In vacuum below 1700 K the activation energy for (110) facet growth agreed with values previously reported for surface diffusion on tungsten. The observed anisotropy values at 0.5 Tsub(m), where Tsub(m) is the absolute melting temperature of tungsten (approximately 3680 K), were different from those previously reported at higher temperatures and more nearly agreed with broken bond calculations based on Mie potential using m=5, n=8, and a 1.5% lattice expansion. Hydrogen appeared to have a negligible effect on surface energy anisotropy, but did preferentially increase surface diffusion rates on (310) regions.

Anisotropy and temperature dependence of structural, thermodynamic, and elastic properties of crystalline cellulose Iβ: a first-principles investigation

Science.gov (United States)

ShunLi Shang; Louis G. Hector Jr.; Paul Saxe; Zi-Kui Liu; Robert J. Moon; Pablo D. Zavattieri

2014-01-01

Anisotropy and temperature dependence of structural, thermodynamic and elastic properties of crystalline cellulose Iβ were computed with first-principles density functional theory (DFT) and a semi-empirical correction for van der Waals interactions. Specifically, we report the computed temperature variation (up to 500...

Thermodynamics for proton binding of phytate in KNO3(aq) at different temperatures and ionic strengths

International Nuclear Information System (INIS)

Bretti, Clemente; De Stefano, Concetta; Lando, Gabriele; Sammartano, Silvio

2013-01-01

Highlights: • Protonation data were modeled in a wide range of temperatures and ionic strengths. • Protonation values decrease with increasing ionic strength and temperature. • In KNO 3 proton binding process is slightly exothermic, but less than in NaCl. • The major contribution for the proton association is entropic in nature. • Results are in agreement with previous findings for KCl and NaCl. - Abstract: Potentiometric measurements were performed in KNO 3(aq) , to determine the apparent protonation constants of phytate at different temperatures (278.15 ≤ T (K) ≤ 323.15) and ionic strengths (0.25 ≤ I (mol) dm −3 ≤ 3.0) values. In general, the protonation constants decrease with increasing both temperature and ionic strength. The data reported were critically compared with previous results obtained in KCl and the values are in a good agreement, considering the experimental errors and slight differences between the activity coefficients of the various species in KCl and KNO 3 . Experimental data were then modeled as a function of temperature and ionic strength using, with comparable results, two approaches: the extended Debye–Hückel equation and the specific ion interaction theory (SIT). The single specific ion interaction coefficients, ε, were also determined. The corresponding values are higher than those in Na + media. The protonation constants were also analyzed considering a simplified weak interaction model using an empirical equation that contains an additional term which takes into account the formation of weak complexes. The results obtained for the modeling of the protonation constants are in agreement with the literature findings. Thermodynamic protonation parameters were also obtained at different temperatures and ionic strengths. The proton association process is slightly exothermic and the enthalpic contribution is less negative than that in NaCl solution. As observed in other cases for phytate anion, the major contribution for

Temperature dependent infrared spectroscopy of proton conducting alkali thio-hydroxogermanates

Energy Technology Data Exchange (ETDEWEB)

Karlsson, Maths; Matic, Aleksandar; Boerjesson, Lars [Department of Applied Physics, Chalmers University of Technology, SE-412 96 Goeteborg (Sweden); Nelson, Carly R.; Martindale, Chad A.; Martin, Steve W. [Department of Material Science and Engineering, 2220 Hoover Hall, Iowa State University of Science and Technology, Ames, IA 50011 (United States)

2006-04-15

We have investigated the thermal stability and reversibility upon dehydration and re-hydration of a novel class of proton conducting alkali thio-hydroxogermanates. The results indicate that no phase transitions or structural degradation occur in the temperature range 25 to 300C, and that repeated dehydration and subsequent re-hydration is a reversible process. The dehydration occurs gradually with increasing temperature, starting at about 80C. For temperatures above 180C the materials are dry, as all molecular water has been dried off. The dehydration process is shown to be reversible and the material can be rehydrated by exposure to air. The thermal stability and reversibility of the dehydration-rehydration process are attractive properties of functional materials, making the proton conducting alkali thio-hydroxogermanates to potential fuel cell electrolytes. (author)

Dynamic Model of the High Temperature Proton Exchange Membrane Fuel Cell Stack Temperature

DEFF Research Database (Denmark)

Andreasen, Søren Juhl; Kær, Søren Knudsen

2009-01-01

The present work involves the development of a model for predicting the dynamic temperature of a high temperature proton exchange membrane (HTPEM) fuel cell stack. The model is developed to test different thermal control strategies before implementing them in the actual system. The test system co...... elements for start-up, heat conduction through stack insulation, cathode air convection, and heating of the inlet gases in the manifold. Various measurements are presented to validate the model predictions of the stack temperatures....

Intermediate Temperature Proton Conductors – Why and How

OpenAIRE

Li, Qingfeng; Aili, David; Jensen, Jens Oluf; Cleemann, Lars Nilausen

2016-01-01

The current technologies of fuel cells and electrolzers are based on ionic conducting electrolyte materials exclusively operational either in the low (20 - 200ºC) or high (600 - 1000ºC) temperature ranges. The intermediate temperature window, especially between 200 and 400 ºC, is still only represented by early fundamental material research for ionic electrolytes. Such materials, most likely based on proton conductors, are expected to bring a new generation of the technologies: fuel cells by ...

Influence of temperature on the Zircaloy-4 plastic anisotropy; Influence de la temperature sur l`anisotropie plastique du Zircaloy-4

Energy Technology Data Exchange (ETDEWEB)

Limon, R.; Bechade, J.L.; Lehmann, S.; Maury, R.; Soniak, A. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Direction des Technologies Avancees; Mardon, J.P. [Societe Franco-Americaine de Constructions Atomiques (FRAMATOME), 92 - Paris-La-Defense (France)

1995-12-31

In order to improve the comportment modelling of PWR fuel pin, and more precisely their canning tubes, Framatome and the CEA have undertake an important study program of Zircaloy-4 mechanical properties. It includes in particular the study of the plasticity between 20 and 400 degree Celsius. This material being not isotropic because of the zirconium hexagonal crystal network and the texture presented by the canning tubes, its plastic anisotropy has been measured. The obtained results for the canning in *slack* and recrystallized before irradiation Zircaloy-4 are presented and the deformation systems able to explain the observed anisotropy is researched. (O.L.). 6 refs., 4 figs., 1 tab.

Measuring proton shift tensors with ultrafast MAS NMR.

Science.gov (United States)

Miah, Habeeba K; Bennett, David A; Iuga, Dinu; Titman, Jeremy J

2013-10-01

A new proton anisotropic-isotropic shift correlation experiment is described which operates with ultrafast MAS, resulting in good resolution of isotropic proton shifts in the detection dimension. The new experiment makes use of a recoupling sequence designed using symmetry principles which reintroduces the proton chemical shift anisotropy in the indirect dimension. The experiment has been used to measure the proton shift tensor parameters for the OH hydrogen-bonded protons in tyrosine·HCl and citric acid at Larmor frequencies of up to 850 MHz. Copyright © 2013 Elsevier Inc. All rights reserved.

Thermodynamics of strong coupling superconductors including the effect of anisotropy

Science.gov (United States)

Daams, J. M.; Carbotte, J. P.

1981-05-01

The thermodynamics of several elemental superconductors is computed from isotropic Eliashberg theory formulated on the imaginary frequency axis. A symmary of the available experimental literature is presented and a comparison with theory is given. The small disagreements that are found are all in the direction expected from anisotropy effects. We calculate the effect of a small amount of model anisotropy on the critical temperature, critical field, and high-temperature specific heat from an exact solution of the anisotropic Eliashberg equations. These are the first such results below the critical temperature; unlike previous analytical work, we include retardation, anisotropy in the mass enhancement, and the effect of the Coulomb repulsion in enhancing anisotropy, all of which are significant. We derive a new formula independent of any model anisotropy for the rate of decrease with impurity lifetime of the critical temperature. Finally we demonstrate how the commonly used formulas of Markowitz and Kadanoff and of Clem may give entirely misleading estimates of the gap anisotropy when used to interpret certain experiments.

Proton transfer and complex formation of angiotensin I ions with gaseous molecules at various temperature

International Nuclear Information System (INIS)

Nonose, Shinji; Yamashita, Kazuki; Sudo, Ayako; Kawashima, Minami

2013-01-01

Highlights: • Proton transfer from angiotensin I ions (z = 2, 3) to gaseous molecules was studied. • Temperature dependence of absolute reaction rate constants was measured. • Remarkable changes were obtained for distribution of product ions and reaction rate constants. • Proton transfer reaction was enhanced and reduced by complex formation. • Conformation changes are induced by complex formation and or by thermal collision with He. - Abstract: Proton transfer reactions of angiotensin I ions for +2 charge state, [M + 2H] 2+ , to primary, secondary and aromatic amines were examined in the gas phase. Absolute reaction rate constants for proton transfer were determined from intensities of parent and product ions in the mass spectra. Temperature dependence of the reaction rate constants was measured. Remarkable change was observed for distribution of product ions and reaction rate constants. Proton transfer reaction was enhanced or reduced by complex formation of [M + 2H] 2+ with gaseous molecules. The results relate to conformation changes of [M + 2H] 2+ with change of temperature, which are induced by complex formation and or by thermal collision with He. Proton transfer reactions of angiotensin I ions for +3 charge state, [M + 3H] 3+ , were also studied. The reaction rates did not depend on temperature so definitely

The Electron Temperature and Anisotropy in the Solar Wind. Comparison of the Core and Halo Populations

Czech Academy of Sciences Publication Activity Database

Pierrard, V.; Lazar, M.; Poedts, S.; Štverák, Štěpán; Maksimovic, M.; Trávníček, Pavel M.

2016-01-01

Roč. 291, č. 7 (2016), s. 2165-2179 ISSN 0038-0938 R&D Projects: GA ČR GA15-17490S Institutional support: RVO:67985815 Keywords : solar wind * electron velocity distributions * temperature anisotropy Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 2.682, year: 2016

Determination of the out-of-plane anisotropy contributions (first and second anisotropy terms) in amorphous Nd-Co thin films by micromagnetic numerical simulations

Science.gov (United States)

Alvarez-Prado, L. M.; Cid, R.; Morales, R.; Diaz, J.; Vélez, M.; Rubio, H.; Hierro-Rodriguez, A.; Alameda, J. M.

2018-06-01

Amorphous Nd-Co thin films exhibit stripe shaped periodic magnetic domains with local out-of-plane magnetization components due to their perpendicular magnetic anisotropy. This anisotropy has been quantified in a fairly simple way by reproducing the experimental magnetization curves by means of micromagnetic numerical simulations. The simulations show that the first (K1) and second (K2) anisotropy constants must be used to properly describe the variation of the stripe domains with the in plane applied magnetic field. A strong temperature dependence of both K1 and K2 has been obtained between 10 K and room temperature. This anisotropy behavior is characteristic of two magnetically coupled 3d-4f sublattices with competing anisotropies.

Niobium phosphates as an intermediate temperature proton conducting electrolyte for fuel cells

DEFF Research Database (Denmark)

Huang, Yunjie; Li, Qingfeng; Jensen, Annemette Hindhede

2012-01-01

A new proton conductor based on niobium phosphates was synthesized using niobium pentoxide and phosphoric acid as precursors. The existence of hydroxyl groups in the phosphates was confirmed and found to be preserved after heat treatment at 500 °C or higher, contributing to an anhydrous proton co...... are of high interest as potential proton conducting electrolytes for fuel cells operational in an intermediate temperature range....... conductivity of 1.6 × 10−2 S cm−1 at 250 °C. The conductivity increased with water content in the atmosphere and reached 5.8 × 10−2 S cm−1 under pure water vapour at the same temperature. The conductivity showed good stability in the low water partial pressure range of up to 0.05 atm. The metal phosphates...

The electron temperature and anisotropy in the solar wind. Comparison of the core and halo populations

Czech Academy of Sciences Publication Activity Database

Pierrard, V.; Lazar, M.; Poedts, S.; Štverák, Štěpán; Maksimovic, M.; Trávníček, Pavel M.

2016-01-01

Roč. 291, č. 7 (2016), s. 2165-2179 ISSN 0038-0938 Institutional support: RVO:68378289 Keywords : solar wind * electron velocity distributions * temperature anisotropy Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.682, year: 2016 http://link.springer.com/article/10.1007/s11207-016-0961-7

Nanostructure-based proton exchange membrane for fuel cell applications at high temperature.

Science.gov (United States)

Li, Junsheng; Wang, Zhengbang; Li, Junrui; Pan, Mu; Tang, Haolin

2014-02-01

As a clean and highly efficient energy source, the proton exchange membrane fuel cell (PEMFC) has been considered an ideal alternative to traditional fossil energy sources. Great efforts have been devoted to realizing the commercialization of the PEMFC in the past decade. To eliminate some technical problems that are associated with the low-temperature operation (such as catalyst poisoning and poor water management), PEMFCs are usually operated at elevated temperatures (e.g., > 100 degrees C). However, traditional proton exchange membrane (PEM) shows poor performance at elevated temperature. To achieve a high-performance PEM for high temperature fuel cell applications, novel PEMs, which are based on nanostructures, have been developed recently. In this review, we discuss and summarize the methods for fabricating the nanostructure-based PEMs for PEMFC operated at elevated temperatures and the high temperature performance of these PEMs. We also give an outlook on the rational design and development of the nanostructure-based PEMs.

Effects of a Guide Field on the Larmor Electric Field and Upstream Electron Temperature Anisotropy in Collisionless Asymmetric Magnetic Reconnection

Energy Technology Data Exchange (ETDEWEB)

Ek-In, Surapat; Ruffolo, David [Department of Physics, Faculty of Science, Mahidol University, Bangkok (Thailand); Malakit, Kittipat [Department of Physics, Faculty of Science and Techonology, Thammasat University, Pathum Thani (Thailand); Shay, Michael A. [Department of Physics and Astronomy, University of Delaware, Newark, DE (United States); Cassak, Paul A., E-mail: kmalakit@gmail.com [Department of Physics and Astronomy, West Virginia University, Morgantown, WV (United States)

2017-08-20

We perform the first study of the properties of the Larmor electric field (LEF) in collisionless asymmetric magnetic reconnection in the presence of an out-of-plane (guide) magnetic field for different sets of representative upstream parameters at Earth’s dayside magnetopause with an ion temperature greater than the electron temperature (the ion-to-electron temperature ratio fixed at 2) using two-dimensional particle-in-cell simulations. We show that the LEF does persist in the presence of a guide field. We study how the LEF thickness and strength change as a function of guide field and the magnetospheric temperature and reconnecting magnetic field strength. We find that the thickness of the LEF structure decreases, while its magnitude increases when a guide field is added to the reconnecting magnetic field. The added guide field makes the Larmor radius smaller, so the scaling with the magnetospheric ion Larmor radius is similar to that reported for the case without a guide field. Note, however, that the physics causing the LEF is not well understood, so future work in other parameter regimes is needed to fully predict the LEF for arbitrary conditions. We also find that a previously reported upstream electron temperature anisotropy arises in the vicinity of the LEF region both with and without a guide field. We argue that the generation of the anisotropy is linked to the existence of the LEF. The LEF can be used in combination with the electron temperature anisotropy as a signature to effectively identify dayside reconnection sites in observations.

Effects of a Guide Field on the Larmor Electric Field and Upstream Electron Temperature Anisotropy in Collisionless Asymmetric Magnetic Reconnection

International Nuclear Information System (INIS)

Ek-In, Surapat; Ruffolo, David; Malakit, Kittipat; Shay, Michael A.; Cassak, Paul A.

2017-01-01

We perform the first study of the properties of the Larmor electric field (LEF) in collisionless asymmetric magnetic reconnection in the presence of an out-of-plane (guide) magnetic field for different sets of representative upstream parameters at Earth’s dayside magnetopause with an ion temperature greater than the electron temperature (the ion-to-electron temperature ratio fixed at 2) using two-dimensional particle-in-cell simulations. We show that the LEF does persist in the presence of a guide field. We study how the LEF thickness and strength change as a function of guide field and the magnetospheric temperature and reconnecting magnetic field strength. We find that the thickness of the LEF structure decreases, while its magnitude increases when a guide field is added to the reconnecting magnetic field. The added guide field makes the Larmor radius smaller, so the scaling with the magnetospheric ion Larmor radius is similar to that reported for the case without a guide field. Note, however, that the physics causing the LEF is not well understood, so future work in other parameter regimes is needed to fully predict the LEF for arbitrary conditions. We also find that a previously reported upstream electron temperature anisotropy arises in the vicinity of the LEF region both with and without a guide field. We argue that the generation of the anisotropy is linked to the existence of the LEF. The LEF can be used in combination with the electron temperature anisotropy as a signature to effectively identify dayside reconnection sites in observations.

Quarkonium dissociation by anisotropy

Science.gov (United States)

Chernicoff, Mariano; Fernández, Daniel; Mateos, David; Trancanelli, Diego

2013-01-01

We compute the screening length for quarkonium mesons moving through an anisotropic, strongly coupled mathcal{N} = 4 super Yang-Mills plasma by means of its gravity dual. We present the results for arbitrary velocities and orientations of the mesons, as well as for arbitrary values of the anisotropy. The anisotropic screening length can be larger or smaller than the isotropic one, and this depends on whether the comparison is made at equal temperatures or at equal entropy densities. For generic motion we find that: (i) mesons dissociate above a certain critical value of the anisotropy, even at zero temperature; (ii) there is a limiting velocity for mesons in the plasma, even at zero temperature; (iii) in the ultra-relativistic limit the screening length scales as (1 - v 2)ɛ with ɛ = 1 /2, in contrast with the isotropic result ɛ = 1 /4.

Temperature dependence of magnetic anisotropy and magnetostriction: Beyond the mean-field theory

International Nuclear Information System (INIS)

Millev, Y.; Faehnle, M.

1994-05-01

The first nonvanishing magnetic anisotropy coefficient is calculated as a function of temperature for any spin quantum number and all temperatures below the Curie temperature for the case of face-centred cubic symmetry within the random-phase approximation (RPA). A detailed and instructive comparison between the mean-field and the RPA predictions is carried out. The RPA magnetization curves are also given for the first time for spins S>1/2. Most of the theoretical considerations are quite general as regard lattice type and even decoupling scheme and can thus be applied straightforwardly to other cases of interest. The progress reported here has been attained with the help of a new simplified and improved parametric approach and of a recent calculation of the average occupation number of magnons within the RPA. In particular, the new approach makes unnecessary the solving of integral equations so that the proposed procedure is especially simple and practically versatile in applications to any particular anisotropic material. (author). Refs, 6 figs

Nonlinear Evolution of Observed Fast Streams in the Solar Wind - Micro-instabilities and Energy Exchange between Protons and Alpha Particles

Science.gov (United States)

Maneva, Y. G.; Poedts, S.

2017-12-01

Non-thermal kinetic components such as deformed velocity distributions, temperature anisotropies and relative drifts between the multiple ion populations are frequently observed features in the collisionless fast solar wind streams near the Earth whose origin is still to be better understood. Some of the traditional models consider the formation of the temperature anisotropies through the effect of the solar wind expansion, while others assume in situ heating and particle acceleration by local fluctuations, such as plasma waves, or by spacial structures, such as advected or locally generated current sheets. In this study we consider the evolution of initial ion temperature anisotropies and relative drifts in the presence of plasma oscillations, such as ion-cyclotron and kinetic Alfven waves. We perform 2.5D hybrid simulations to study the evolution of observed fast solar wind plasma parcels, including the development of the plasma micro-instabilities, the field-particle correlations and the energy transfer between the multiple ion species. We consider two distinct cases of highly anisotropic and quickly drifting protons which excite ion-cyclotron waves and of moderately anisotropic slower protons, which co-exist with kinetic Alfven waves. The alpha particles for both cases are slightly anisotropic in the beginning and remain anisotropic throughout the simulation time. Both the imposed magnetic fluctuations and the initial differential streaming decrease in time for both cases, while the minor ions are getting heated. Finally we study the effects of the solar wind expansion and discuss its implications for the nonlinear evolution of the system.

Low-temperature structural phase transition in deuterated and protonated lithium acetate dihydrate

Energy Technology Data Exchange (ETDEWEB)

Schroeder, F., E-mail: schroeder@kristall.uni-frankfurt.d [Goethe-Universitaet Frankfurt am Main, Institut fuer Geowissenschaften, Abt. Kristallographie, Altenhoeferallee 1, 60438 Frankfurt am Main (Germany); Winkler, B.; Haussuehl, E. [Goethe-Universitaet Frankfurt am Main, Institut fuer Geowissenschaften, Abt. Kristallographie, Altenhoeferallee 1, 60438 Frankfurt am Main (Germany); Cong, P.T.; Wolf, B. [Goethe-Universitaet Frankfurt am Main, Physikalisches Institut, Max-von-Laue-Strasse 1, 60438 Frankfurt am Main (Germany); Avalos-Borja, M. [Instituto Potosino de Investigacion Cientifica y Tecnologica, A.C. Camino a la Presa San Jose 2055, Col. Lomas 4 seccion CP 78216, San Luis Potosi (Mexico); Quilichini, M.; Hennion, B. [Laboratoire Leon Brillouin, CEN Saclay, 91191 Gif-sur-Yvette (France)

2010-08-15

Heat capacity measurements of protonated lithium acetate dihydrate show a structural phase transition at T = 12 K. This finding is in contrast to earlier work, where it was thought that only the deuterated compound undergoes a low temperature structural phase transition. This finding is confirmed by low temperature ultrasound spectroscopy, where the structural phase transition is associated with a velocity decrease of the ultrasonic waves, i.e. with an elastic softening. We compare the thermodynamic properties of the protonated and deuterated compounds and discuss two alternatives for the mechanism of the phase transition based on the thermal expansion measurements.

Proton and temperature-induced competitive segregation of iron on surface and volume sinks of silica

International Nuclear Information System (INIS)

Shilobreeva, S.N.; Kashkarov, L.L.; Barabanenkov, M.Yu.; Pustovit, A.N.; Zinenko, V.I.; Agafonov, Yu.A.

2007-01-01

Experimental results are delivered on iron redistribution in silica for proton irradiation followed by thermal annealing. Iron ions are initially implanted into silica at room temperature. Proton irradiation is performed at different temperatures. It is demonstrated, in particular, that radiation-induced migration of iron is more efficient at low temperature. Iron surface segregation and capture of iron by sinks in silica subsurface region during thermal annealing are speculated in terms of diffusion-alternative-sinks problem

Proton and temperature-induced competitive segregation of iron on surface and volume sinks of silica

Energy Technology Data Exchange (ETDEWEB)

Shilobreeva, S.N. [Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow 117975 (Russian Federation); Kashkarov, L.L. [Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow 117975 (Russian Federation); Barabanenkov, M.Yu. [Institute of Microelectronics Technology and Superpure Materials, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region (Russian Federation)]. E-mail: barab@ipmt-hpm.ac.ru; Pustovit, A.N. [Institute of Microelectronics Technology and Superpure Materials, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region (Russian Federation); Zinenko, V.I. [Institute of Microelectronics Technology and Superpure Materials, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region (Russian Federation); Agafonov, Yu.A. [Institute of Microelectronics Technology and Superpure Materials, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region (Russian Federation)

2007-03-15

Experimental results are delivered on iron redistribution in silica for proton irradiation followed by thermal annealing. Iron ions are initially implanted into silica at room temperature. Proton irradiation is performed at different temperatures. It is demonstrated, in particular, that radiation-induced migration of iron is more efficient at low temperature. Iron surface segregation and capture of iron by sinks in silica subsurface region during thermal annealing are speculated in terms of diffusion-alternative-sinks problem.

Large Magnetic Anisotropy in HfMnP

Science.gov (United States)

Parker, David; Lamichhane, Tej; Taufour, Valentin; Masters, Morgan; Thimmaiah, Srinivasa; Bud'Ko, Ser'gey; Canfield, Paul

We present a theoretical and experimental study of two little-studied manganese phosphide ferromagnets, HfMnP and ZrMnP, with Curie temperatures above room temperature. We find an anisotropy field in HfMnP approaching 10 T - larger than that of the permanent magnet workhorse NdFeB magnets. From theory we determine the source of this anisotropy. Our results show the potential of 3d-element-based magnetic materials for magnetic applications.

H/D isotope effects in high temperature proton conductors

DEFF Research Database (Denmark)

Bonanos, Nikolaos; Huijser, A.; Poulsen, Finn Willy

2015-01-01

The atomic mass ratio of ca. 2 between deuterium and hydrogen is the highest for any pair of stable isotopes and results in significant and measurable H/D isotope effects in high temperature proton conductors containing these species. This paper discusses H/D isotope effects manifested in O-H/O-D...

Anisotropy influence on the failure of Ti6Al4V sheets deformed at room and elevated temperature

Science.gov (United States)

Wang, Q. L.; Ghiotti, A.; Bruschi, S.

2018-05-01

Ti6Al4V sheets are usually difficult-to-form at room temperature as a consequence of their strong basal texture and hcp crystal lattice. The heating of the alloy below the beta transus temperature is recognized to enhance its formability, reducing the flow stress and increasing the ductility. However, the influence of the sheet anisotropy on the material failure hasn't been studied yet. To this aim, the paper presents the anisotropy influence on the failure characteristics of Ti6Al4V titanium alloy sheets making use of tensile tests carried out at room temperature and 600°C on smooth, notched and shear samples in order to have various stress states. The fracture strain is measured and the effect of the sample orientation and stress state is identified. To determine the actual stress state for each sample geometry, a numerical model is set up and calibrated using elasto-plastic data from uni-axial tensile tests on smooth samples. Finally, the fracture surfaces are observed through SEM analysis to explain the failure characteristics.

Protic Salt Polymer Membranes: High-Temperature Water-Free Proton-Conducting Membranes

Energy Technology Data Exchange (ETDEWEB)

Gervasio, Dominic Francis [Univ. of Arizona, Tucson, AZ (United States)

2010-09-30

This research on proton-containing (protic) salts directly addresses proton conduction at high and low temperatures. This research is unique, because no water is used for proton ionization nor conduction, so the properties of water do not limit proton fuel cells. A protic salt is all that is needed to give rise to ionized proton and to support proton mobility. A protic salt forms when proton transfers from an acid to a base. Protic salts were found to have proton conductivities that are as high as or higher than the best aqueous electrolytes at ambient pressures and comparable temperatures without or with water present. Proton conductivity of the protic salts occurs providing two conditions exist: i) the energy difference is about 0.8 eV between the protic-salt state versus the state in which the acid and base are separated and 2) the chemical constituents rotate freely. The physical state of these proton-conducting salts can be liquid, plastic crystal as well as solid organic and inorganic polymer membranes and their mixtures. Many acids and bases can be used to make a protic salt which allows tailoring of proton conductivity, as well as other properties that affect their use as electrolytes in fuel cells, such as, stability, adsorption on catalysts, environmental impact, etc. During this project, highly proton conducting (~ 0.1S/cm) protic salts were made that are stable under fuel-cell operating conditions and that gave highly efficient fuel cells. The high efficiency is attributed to an improved oxygen electroreduction process on Pt which was found to be virtually reversible in a number of liquid protic salts with low water activity (< 1% water). Solid flexible non-porous composite membranes, made from inorganic polymer (e.g., 10%indium 90%tin pyrophosphate, ITP) and organic polymer (e.g., polyvinyl pyridinium phosphate, PVPP), were found that give conductivity and fuel cell performances similar to phosphoric acid electrolyte with no need for hydration at

Search for positron anisotropies in cosmic rays with AMS

Energy Technology Data Exchange (ETDEWEB)

Machate, Fabian [1. Physikalisches Institut B, RWTH Aachen University (Germany)

2016-07-01

The Alpha Magnetic Spectrometer (AMS-02) on the International Space Station has observed a significant excess of cosmic ray positrons over the background expected from secondary production at energies above 10 GeV. Nearby pulsars and annihilating dark matter particles as a primary source of electrons and positrons have been discussed as an explanation. A possible way of distinguishing between pulsar and dark matter origin is the measurement of dipole anisotropies in the positron flux or the positron to electron ratio. Any anisotropy will be reduced by diffusion in galactic magnetic fields to below the percent level. AMS-02 is the leading space-based experiment for cosmic ray detection and well suited for this search. A new analysis procedure for anisotropies using an event sample with large acceptance is presented. It relies on the ability of the Transition Radiation Detector (TRD) to separate positrons from the proton background.

Composite electrolyte with proton conductivity for low-temperature solid oxide fuel cell

Energy Technology Data Exchange (ETDEWEB)

Raza, Rizwan, E-mail: razahussaini786@gmail.com [Department of Physics, COMSATS Institute of Information Technology, Lahore 54000 (Pakistan); Department of Energy Technology, Royal Institute of Technology, KTH, Stockholm 10044 (Sweden); Ahmed, Akhlaq; Akram, Nadeem; Saleem, Muhammad; Niaz Akhtar, Majid; Ajmal Khan, M.; Abbas, Ghazanfar; Alvi, Farah; Yasir Rafique, M. [Department of Physics, COMSATS Institute of Information Technology, Lahore 54000 (Pakistan); Sherazi, Tauqir A. [Department of Chemistry, COMSATS Institute of Information Technology, Abbotabad 22060 (Pakistan); Shakir, Imran [Sustainable Energy Technologies (SET) center, College of Engineering, King Saud University, PO-BOX 800, Riyadh 11421 (Saudi Arabia); Mohsin, Munazza [Department of Physics, Lahore College for Women University, Lahore, 54000 (Pakistan); Javed, Muhammad Sufyan [Department of Physics, COMSATS Institute of Information Technology, Lahore 54000 (Pakistan); Department of Applied Physics, Chongqing University, Chongqing 400044 (China); Zhu, Bin, E-mail: binzhu@kth.se, E-mail: zhubin@hubu.edu.cn [Department of Energy Technology, Royal Institute of Technology, KTH, Stockholm 10044 (Sweden); Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Physics and Electronic Science/Faculty of Computer and Information, Hubei University, Wuhan, Hubei 430062 (China)

2015-11-02

In the present work, cost-effective nanocomposite electrolyte (Ba-SDC) oxide is developed for efficient low-temperature solid oxide fuel cells (LTSOFCs). Analysis has shown that dual phase conduction of O{sup −2} (oxygen ions) and H{sup +} (protons) plays a significant role in the development of advanced LTSOFCs. Comparatively high proton ion conductivity (0.19 s/cm) for LTSOFCs was achieved at low temperature (460 °C). In this article, the ionic conduction behaviour of LTSOFCs is explained by carrying out electrochemical impedance spectroscopy measurements. Further, the phase and structure analysis are investigated by X-ray diffraction and scanning electron microscopy techniques. Finally, we achieved an ionic transport number of the composite electrolyte for LTSOFCs as high as 0.95 and energy and power density of 90% and 550 mW/cm{sup 2}, respectively, after sintering the composite electrolyte at 800 °C for 4 h, which is promising. Our current effort toward the development of an efficient, green, low-temperature solid oxide fuel cell with the incorporation of high proton conductivity composite electrolyte may open frontiers in the fields of energy and fuel cell technology.

Composite electrolyte with proton conductivity for low-temperature solid oxide fuel cell

Science.gov (United States)

Raza, Rizwan; Ahmed, Akhlaq; Akram, Nadeem; Saleem, Muhammad; Niaz Akhtar, Majid; Sherazi, Tauqir A.; Ajmal Khan, M.; Abbas, Ghazanfar; Shakir, Imran; Mohsin, Munazza; Alvi, Farah; Javed, Muhammad Sufyan; Yasir Rafique, M.; Zhu, Bin

2015-11-01

In the present work, cost-effective nanocomposite electrolyte (Ba-SDC) oxide is developed for efficient low-temperature solid oxide fuel cells (LTSOFCs). Analysis has shown that dual phase conduction of O-2 (oxygen ions) and H+ (protons) plays a significant role in the development of advanced LTSOFCs. Comparatively high proton ion conductivity (0.19 s/cm) for LTSOFCs was achieved at low temperature (460 °C). In this article, the ionic conduction behaviour of LTSOFCs is explained by carrying out electrochemical impedance spectroscopy measurements. Further, the phase and structure analysis are investigated by X-ray diffraction and scanning electron microscopy techniques. Finally, we achieved an ionic transport number of the composite electrolyte for LTSOFCs as high as 0.95 and energy and power density of 90% and 550 mW/cm2, respectively, after sintering the composite electrolyte at 800 °C for 4 h, which is promising. Our current effort toward the development of an efficient, green, low-temperature solid oxide fuel cell with the incorporation of high proton conductivity composite electrolyte may open frontiers in the fields of energy and fuel cell technology.

Nonlinear δf Simulation Studies of Intense Charged Particle Beams with Large Temperature Anisotropy

International Nuclear Information System (INIS)

Startsev, Edward A.; Davidson, Ronald C.; Qin, Hong

2002-01-01

In this paper, a 3-D nonlinear perturbative particle simulation code (BEST) [H. Qin, R.C. Davidson and W.W. Lee, Physical Review Special Topics on Accelerators and Beams 3 (2000) 084401] is used to systematically study the stability properties of intense nonneutral charged particle beams with large temperature anisotropy (T perpendicularb >> T parallelb ). The most unstable modes are identified, and their eigenfrequencies, radial mode structure, and nonlinear dynamics are determined for axisymmetric perturbations with ∂/∂θ = 0

The Effects of Plastic Anisotropy in Warm and Hot Forming of Magnesium Sheet Materials

Science.gov (United States)

Taleff, Eric M.; Antoniswamy, Aravindha R.; Carpenter, Alexander J.; Yavuz, Emre

Mg alloy sheet materials often exhibit plastic anisotropy at room temperature as a result of the limited slip systems available in the HCP lattice combined with a commonly strong basal texture. Less well studied is plastic anisotropy developed at the elevated temperatures associated with warm and hot forming. At these elevated temperatures, particularly above 200°C, the activation of additional slip systems significantly increases ductility. However, plastic anisotropy is also induced at elevated temperatures by a strong crystallographic texture, and it can require an accounting in material constitutive models to achieve accurate forming simulations. The type and degree of anisotropy under these conditions depend on both texture and deformation mechanism. The current understanding of plastic anisotropy in Mg AZ31B and ZEK100 sheet materials at elevated temperatures is reviewed in this article. The recent construction of material forming cases is also reviewed with strategies to account for plastic anisotropy in forming simulations.

Role of the magnetic anisotropy in organic spin valves

Directory of Open Access Journals (Sweden)

V. Kalappattil

2017-09-01

Full Text Available Magnetic anisotropy plays an important role in determining the magnetic functionality of thin film based electronic devices. We present here, the first systematic study of the correlation between magnetoresistance (MR response in organic spin valves (OSVs and magnetic anisotropy of the bottom ferromagnetic electrode over a wide temperature range (10 K–350 K. The magnetic anisotropy of a La0.67Sr0.33MnO3 (LSMO film epitaxially grown on a SrTiO3 (STO substrate was manipulated by reducing film thickness from 200 nm to 20 nm. Substrate-induced compressive strain was shown to drastically increase the bulk in-plane magnetic anisotropy when the LSMO became thinner. In contrast, the MR response of LSMO/OSC/Co OSVs for many organic semiconductors (OSCs does not depend on either the in-plane magnetic anisotropy of the LSMO electrodes or their bulk magnetization. All the studied OSV devices show a similar temperature dependence of MR, indicating a similar temperature-dependent spinterface effect irrespective of LSMO thickness, resulting from the orbital hybridization of carriers at the OSC/LSMO interface.

Influence of temperature on the Zircaloy-4 plastic anisotropy

International Nuclear Information System (INIS)

Limon, R.; Bechade, J.L.; Lehmann, S.; Maury, R.; Soniak, A.

1995-01-01

In order to improve the comportment modelling of PWR fuel pin, and more precisely their canning tubes, Framatome and the CEA have undertake an important study program of Zircaloy-4 mechanical properties. It includes in particular the study of the plasticity between 20 and 400 degree Celsius. This material being not isotropic because of the zirconium hexagonal crystal network and the texture presented by the canning tubes, its plastic anisotropy has been measured. The obtained results for the canning in *slack* and recrystallized before irradiation Zircaloy-4 are presented and the deformation systems able to explain the observed anisotropy is researched. (O.L.). 6 refs., 4 figs., 1 tab

Suprathermal protons in the interplanetary solar wind

Science.gov (United States)

Goodrich, C. C.; Lazarus, A. J.

1976-01-01

Using the Mariner 5 solar wind plasma and magnetic field data, we present observations of field-aligned suprathermal proton velocity distributions having pronounced high-energy shoulders. These observations, similar to the interpenetrating stream observations of Feldman et al. (1974), are clear evidence that such proton distributions are interplanetary rather than bow shock associated phenomena. Large Alfven speed is found to be a requirement for the occurrence of suprathermal proton distribution; further, we find the proportion of particles in the shoulder to be limited by the magnitude of the Alfven speed. It is suggested that this last result could indicate that the proton thermal anisotropy is limited at times by wave-particle interactions

Monte Carlo studies of two-dimensional random-anisotropy magnets

Science.gov (United States)

Denholm, D. R.; Sluckin, T. J.

1993-07-01

We have carried out a systematic set of Monte Carlo simulations of the Harris-Plischke-Zuckermann lattice model of random magnetic anisotropy on a two-dimensional square lattice, using the classical Metropolis algorithm. We have considered varying temperature T, external magnetic field H (both in the reproducible and irreproducible limits), time scale of the simulation τ in Monte Carlo steps and anisotropy ratio D/J. In the absence of randomness this model reduces to the XY model in two dimensions, which possesses the familiar Kosterlitz-Thouless low-temperature phase with algebraic but no long-range order. In the presence of random anisotropy we find evidence of a low-temperature phase with some disordered features, which might be identified with a spin-glass phase. The low-temperature Kosterlitz-Thouless phase survives at intermediate temperatures for low randomness, but is no longer present for large D/J. We have also studied the high-H approach to perfect order, for which there are theoretical predictions due to Chudnovsky.

CMB anisotropies at all orders: the non-linear Sachs-Wolfe formula

OpenAIRE

Roldan, Omar

2017-01-01

We obtain the non-linear generalization of the Sachs-Wolfe + integrated Sachs-Wolfe (ISW) formula describing the CMB temperature anisotropies. Our formula is valid at all orders in perturbation theory, is also valid in all gauges and includes scalar, vector and tensor modes. A direct consequence of our results is that the maps of the logarithmic temperature anisotropies are much cleaner than the usual CMB maps, because they automatically remove many secondary anisotropies. This can for instan...

Anisotropy evidence for the K-shell ionization probability in the use of Ag(p,p)Ag reaction

International Nuclear Information System (INIS)

Andriamonje, S.

1976-01-01

The ionization probability of silver by 1MeV protons has been measured at large angles up to 110 0 C. The experimental results have been obtained using the coincidence between scattered protons and KX rays. The angular dependence in the ionization probability at small impact parameters indicates an anisotropy as expected by Ciochetti and Molinari in their theoretical study of K-shell ionization probability associated with nuclear reactions. The results have been compared to the predictions of the BEA (Binary Exchange Approximation) method, including relativistic corrections of deflection and binding energy. The anisotropy coefficient deduced from the comparison of experimental and theoretical results is in good agreement with expected values [fr

Measurement of the North-South asymmetry in the solar proton albedo neutron flux

International Nuclear Information System (INIS)

Ifedili, S.O.

1979-01-01

The solar proton albedo neutron flux in the range 10 -2 --10 7 eV measured by a neutron detector on board the Ogo 6 satellite was examined for north-south asymmetry. For the solar proton event of December 19, 1969, the S/N ratio of the solar proton albedo neutron rate at geomagnetic latitude lambda>70 0 was 1.61 +- 0.27 during the event, while for the November 2, 1969, event at 40 0 0 and altitudes ranging from 700 km to 800 km the solar proton albedo neutron rate was 0.40 +- 0.10 count/s in the north and 0.00 +- 0.10 count/s in the south. During the solar proton event of December 18, 1969, the N/S ratio of the solar proton albedo neutron rate at lambda>70 0 was 1.00 +- 0.26. The results are consistent with the expected N-S asymmetry in the solar proton flux. An interplanetary proton anisotropy with the interplanetary magnetic field polarity away from the sun corresponded to larger fluxes of solar proton albedo neutrons at the north polar cap than at the south, while an interplanetary proton anisotropy with the interplanetary magnetic field polarity toward the sun corresponded to larger fluxes of solar proton albedo neutrons at the south polar cap than at the north. This evidence favors the direct access of solar protons to the earth's polar caps via the merged interplanetary and geomagnetic field lines

Measurements of magnetic anisotropy in sickle cells

International Nuclear Information System (INIS)

Salvo Souza, L.H. de.

1982-03-01

Room temperature magnetic measurements in deoxigenated sickle cells showed the existence of magnetic anisotropy, Δchi=1,29 x 10 -3 . This effect was supposed paramagnetic and considered to be due to the iron atoms of the hemoglobin molecules which are one over the other, forming ordered chains inside the erythrocytes. Low temperature (liquid He - 4,2K) measurements of the magnetic anisotropy of sickle cells and normal red blood cells diluted in a cryoprotector was made to confirm the paramagnetic origin of the fenomena. For that purpose it was used a superconductor magnetometer coupled to a SQUID, developed in the 'Laboratorio do Estado Solido do Departamento de Fisica da PUC-RJ'. The results obtained seem to confirm the expected paramagnetic anisotropy and, furthermore, suggest the presence of magnetic interactions among the iron atoms in the sickle cells samples. (Author) [pt

Anisotropy of self-diffusion and α-zirconium radiation growth problems

International Nuclear Information System (INIS)

Smirnov, E.A.; Subbotin, A.V.

1996-01-01

Temperature dependence of α-zirconium seft-diffusion anisotropy coefficients is obtained within the framework of linear extrapolation of self-diffusion anisotropy characteristics for metal HCP with c/a ration of [ru

Effects of temperature anisotropy on neoclassical transport in the plateau and banana-plateau regimes

International Nuclear Information System (INIS)

Taguchi, Masayoshi

1999-01-01

The neoclassical transport theory in a presence of temperature anisotropy is investigated in the low to the intermediate collision frequency regimes for a large aspect-ratio tokamak plasma. The standard procedure for an isotropic plasma in the plateau regime is extended to an anisotropic plasma, and the neoclassical transport coefficients in this regime are explicitly calculated. By interpolating the results in the plateau regime and the previously obtained ones in the banana regime, the expressions for the neoclassical transport coefficients which are continuously valid from the banana to the plateau regimes are presented. (author)

Calculation of the magnetic anisotropy energy and finite-temperature magnetic properties of transition-metal films

International Nuclear Information System (INIS)

Garibay-Alonso, R; Villasenor-Gonzalez, P; Dorantes-Davila, J; Pastor, G M

2004-01-01

The magnetic anisotropy energy at the interface (IMAE) of Co films deposited on the Pd(111) surface are determined in the framework of a self-consistent, real-space tight-binding method at zero temperature. Significant spin moments are induced at the Pd atoms at the interface which have an important influence on the observed reorientation transitions as a function of Co film thickness. Film-substrate hybridizations are therefore crucial for the magneto-anisotropic behaviour of thin transition-metal films deposited on metallic non-magnetic substrates. Furthermore, using a real-space recursive expansion of the local Green function and within the virtual-crystal approximation we calculate the magnetization curves and the Curie temperature T C for free-standing Fe films

Room temperature synthesis of protonated layered titanate sheets using peroxo titanium carbonate complex solution.

Science.gov (United States)

Sutradhar, Narottam; Sinhamahapatra, Apurba; Pahari, Sandip Kumar; Bajaj, Hari C; Panda, Asit Baran

2011-07-21

We report the synthesis of peroxo titanium carbonate complex solution as a novel water-soluble precursor for the direct synthesis of layered protonated titanate at room temperature. The synthesized titanates showed excellent removal capacity for Pb(2+) and methylene blue. Based on experimental observations, a probable mechanism for the formation of protonated layered dititanate sheets is also discussed.

Temperature dependence of the magnetostriction and the induced anisotropy in nanocrystalline FeCuNbSiB alloys, and their fluxgate properties

DEFF Research Database (Denmark)

Nielsen, Otto V; Petersen, Jan Raagaard

1994-01-01

Making use of the stress induced magnetic anisotropy in some iron-rich FeCuNbSiB nanocrystalline materials we studied the thermal dependence of their magnetostriction which becomes zero below the Curie temperature. The choice of a suitable composition and annealing temperature results in materials...... with zero magnetostriction at room temperature. Due to the low magnetostriction these materials have very promising fluxgate properties which were studied as well...

Site-specific magnetic anisotropies in R2Fe14B systems

Science.gov (United States)

Yoshioka, T.; Tsuchiura, H.

2018-04-01

The local magnetic anisotropy of R ions in R2Fe14B (R = Dy, Ho) systems is studied based on a microscopic effective spin model constructed from the information obtained by using first-principles calculations. By taking into account up to 6-th order crystal electric field parameters, the model satisfactory describes the observed magnetization curves and the temperature dependence of anisotropy constants. We found that at low temperatures, the noncollinear structure appears in the Ho2Fe14B system reflecting the local magnetic anisotropy.

Direct Observation of Field and Temperature Induced Domain Replication in Dipolar Coupled Perpendicular Anisotropy Films

Energy Technology Data Exchange (ETDEWEB)

Hauet, T.; Gunther, C.M.; Pfau, B.; Eisebitt, S.; Fischer, P.; Rick, R. L.; Thiele, J.-U.; Hellwig, O.; Schabes, M.E.

2007-07-01

Dipolar interactions in a soft/Pd/hard [CoNi/Pd]{sub 30}/Pd/[Co/Pd]{sub 20} multilayer system, where a thick Pd layer between two ferromagnetic units prevents direct exchange coupling, are directly revealed by combining magnetometry and state-of-the-art layer resolving soft x-ray imaging techniques with sub-100-nm spatial resolution. The domains forming in the soft layer during external magnetic field reversal are found to match the domains previously trapped in the hard layer. The low Curie temperature of the soft layer allows varying its intrinsic parameters via temperature and thus studying the competition with dipolar fields due to the domains in the hard layer. Micromagnetic simulations elucidate the role of [CoNi/Pd] magnetization, exchange, and anisotropy in the duplication process. Finally, thermally driven domain replication in remanence during temperature cycling is demonstrated.

Solar energetic particle anisotropies and insights into particle transport

Energy Technology Data Exchange (ETDEWEB)

Leske, R. A., E-mail: ral@srl.caltech.edu; Cummings, A. C.; Cohen, C. M. S.; Mewaldt, R. A.; Labrador, A. W.; Stone, E. C. [California Institute of Technology, Pasadena, CA 91125 (United States); Wiedenbeck, M. E. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Christian, E. R.; Rosenvinge, T. T. von [NASA/Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2016-03-25

As solar energetic particles (SEPs) travel through interplanetary space, their pitch-angle distributions are shaped by the competing effects of magnetic focusing and scattering. Measurements of SEP anisotropies can therefore reveal information about interplanetary conditions such as magnetic field strength, topology, and turbulence levels at remote locations from the observer. Onboard each of the two STEREO spacecraft, the Low Energy Telescope (LET) measures pitch-angle distributions for protons and heavier ions up to iron at energies of about 2-12 MeV/nucleon. Anisotropies observed using LET include bidirectional flows within interplanetary coronal mass ejections, sunward-flowing particles when STEREO was magnetically connected to the back side of a shock, and loss-cone distributions in which particles with large pitch angles underwent magnetic mirroring at an interplanetary field enhancement that was too weak to reflect particles with the smallest pitch angles. Unusual oscillations in the width of a beamed distribution at the onset of the 23 July 2012 SEP event were also observed and remain puzzling. We report LET anisotropy observations at both STEREO spacecraft and discuss their implications for SEP transport, focusing exclusively on the extreme event of 23 July 2012 in which a large variety of anisotropies were present at various times during the event.

Solar energetic particle anisotropies and insights into particle transport

Science.gov (United States)

Leske, R. A.; Cummings, A. C.; Cohen, C. M. S.; Mewaldt, R. A.; Labrador, A. W.; Stone, E. C.; Wiedenbeck, M. E.; Christian, E. R.; Rosenvinge, T. T. von

2016-03-01

As solar energetic particles (SEPs) travel through interplanetary space, their pitch-angle distributions are shaped by the competing effects of magnetic focusing and scattering. Measurements of SEP anisotropies can therefore reveal information about interplanetary conditions such as magnetic field strength, topology, and turbulence levels at remote locations from the observer. Onboard each of the two STEREO spacecraft, the Low Energy Telescope (LET) measures pitch-angle distributions for protons and heavier ions up to iron at energies of about 2-12 MeV/nucleon. Anisotropies observed using LET include bidirectional flows within interplanetary coronal mass ejections, sunward-flowing particles when STEREO was magnetically connected to the back side of a shock, and loss-cone distributions in which particles with large pitch angles underwent magnetic mirroring at an interplanetary field enhancement that was too weak to reflect particles with the smallest pitch angles. Unusual oscillations in the width of a beamed distribution at the onset of the 23 July 2012 SEP event were also observed and remain puzzling. We report LET anisotropy observations at both STEREO spacecraft and discuss their implications for SEP transport, focusing exclusively on the extreme event of 23 July 2012 in which a large variety of anisotropies were present at various times during the event.

Low-temperature properties of orientationally degenerated (OH)- centers in proton-conducting oxides

International Nuclear Information System (INIS)

Ivanov, M.A.; Fishman, A.Ya.; Tsidil'kovsky, V.I.

2007-01-01

It is shown that the proton-associated dipole centers (OH) - can provide glasslike low-temperature properties of ABO 3-y oxides doped with cations of lower valence. These properties result from the splitting of the orientationally degenerated states of the (OH) - centers by proton tunnelling and random crystal fields. It is found that the substitution of hydrogen by deuterium or tritium leads to large and abnormal isotope effects for the contributions of degenerated centers to thermodynamic properties and absorption of elastic and electromagnetic waves

Proton irradiation of a swept charge device at cryogenic temperature and the subsequent annealing

International Nuclear Information System (INIS)

Gow, J P D; Smith, P H; Hall, D J; Holland, A D; Murray, N J; Pool, P

2015-01-01

A number of studies have demonstrated that a room temperature proton irradiation may not be sufficient to provide an accurate estimation of the impact of the space radiation environment on detector performance. This is a result of the relationship between defect mobility and temperature, causing the performance to vary subject to the temperature history of the device from the point at which it was irradiated. Results measured using Charge Coupled Devices (CCD) irradiated at room temperature therefore tend to differ from those taken when the device was irradiated at a cryogenic temperature, more appropriate considering the operating conditions in space, impacting the prediction of in-flight performance. This paper describes the cryogenic irradiation, and subsequent annealing of an e2v technologies Swept Charge Device (SCD) CCD236 irradiated at −35.4°C with a 10 MeV equivalent proton fluence of 5.0 × 10 8 protons · cm −2 . The CCD236 is a large area (4.4 cm 2 ) X-ray detector that will be flown on-board the Chandrayaan-2 and Hard X-ray Modulation Telescope spacecraft, in the Chandrayaan-2 Large Area Soft X-ray Spectrometer and the Soft X-ray Detector respectively. The SCD is readout continually in order to benefit from intrinsic dither mode clocking, leading to suppression of the surface component of the dark current and allowing the detector to be operated at warmer temperatures than a conventional CCD. The SCD is therefore an excellent choice to test and demonstrate the variation in the impact of irradiation at cryogenic temperatures in comparison to a more typical room temperature irradiation

Temperature dependence of the anisotropy of fluorescence in ring molecular systems

International Nuclear Information System (INIS)

Herman, Pavel; Barvik, Ivan

2007-01-01

The time dependence of the anisotropy of fluorescence after an impulsive excitation in the molecular ring (resembling the B850 ring of the purple bacterium Rhodopseudomonas acidophila) is calculated. Fast fluctuations of the environment are simulated by dynamic disorder and slow fluctuations by uncorrelated static disorder. Without dynamic disorder modest degrees of static disorder are sufficient to cause the experimentally found initial drop of the anisotropy on a sub-100 fs time scale. In the present investigation we are comparing results for the time-dependent optical anisotropy of the molecular ring for four models of the uncorrelated static disorder: Gaussian disorder in the local energies (model A), Gaussian disorder in the transfer integrals (model B), Gaussian disorder in radial positions of molecules (model C) and Gaussian disorder in angular positions of molecules (model D). Both types of disorder-static and dynamic-are taken into account simultaneously

Temperature dependence of relaxation times in proton components of fatty acids

International Nuclear Information System (INIS)

Kuroda, Kagayaki; Iwabuchi, Taku; Saito, Kensuke; Obara, Makoto; Honda, Masatoshi; Imai, Yutaka

2011-01-01

We examined the temperature dependence of relaxation times in proton components of fatty acids in various samples in vitro at 11 tesla as a standard calibration data for quantitative temperature imaging of fat. The spin-lattice relaxation time, T 1 , of both the methylene (CH 2 ) chain and terminal methyl (CH 3 ) was linearly related to temperature (r>0.98, P 2 signal for calibration and observed the signal with 18% of CH 3 to estimate temperature. These findings suggested that separating the fatty acid components would significantly improve accuracy in quantitative thermometry for fat. Use of the T 1 of CH 2 seems promising in terms of reliability and reproducibility in measuring temperature of fat. (author)

High-temperature annealing of proton irradiated beryllium – A dilatometry-based study

Energy Technology Data Exchange (ETDEWEB)

Simos, Nikolaos, E-mail: simos@bnl.gov [Brookhaven National Laboratory, Upton, NY, 11973 (United States); Elbakhshwan, Mohamed; Zhong, Zhong; Ghose, Sanjit [Brookhaven National Laboratory, Upton, NY, 11973 (United States); Savkliyildiz, Ilyas [Rutgers University (United States)

2016-08-15

S−200 F grade beryllium has been irradiated with 160 MeV protons up to 1.2 10{sup 20} cm{sup −2} peak fluence and irradiation temperatures in the range of 100–200 °C. To address the effect of proton irradiation on dimensional stability, an important parameter in its consideration in fusion reactor applications, and to simulate high temperature irradiation conditions, multi-stage annealing using high precision dilatometry to temperatures up to 740 °C were conducted in air. X-ray diffraction studies were also performed to compliment the macroscopic thermal study and offer a microscopic view of the irradiation effects on the crystal lattice. The primary objective was to qualify the competing dimensional change processes occurring at elevated temperatures namely manufacturing defect annealing, lattice parameter recovery, transmutation {sup 4}He and {sup 3}H diffusion and swelling and oxidation kinetics. Further, quantification of the effect of irradiation dose and annealing temperature and duration on dimensional changes is sought. The study revealed the presence of manufacturing porosity in the beryllium grade, the oxidation acceleration effect of irradiation including the discontinuous character of oxidation advancement, the effect of annealing duration on the recovery of lattice parameters recovery and the triggering temperature for transmutation gas diffusion leading to swelling.

General kinetic solution for the Biermann battery with an associated pressure anisotropy generation

Science.gov (United States)

Schoeffler, K. M.; Silva, L. O.

2018-01-01

Fully kinetic analytic calculations of an initially Maxwellian distribution with arbitrary density and temperature gradients exhibit the development of temperature anisotropies and magnetic field growth associated with the Biermann battery. The calculation, performed by taking a small order expansion of the ratio of the Debye length to the gradient scale, predicts anisotropies and magnetic fields as a function of space given an arbitrary temperature and density profile. These predictions are shown to qualitatively match the values measured from particle-in-cell simulations, where the development of the Weibel instability occurs at the same location and with a wavenumber aligned with the predicted temperature anisotropy.

Giant anisotropy of magnetocaloric effect in TbMnO3 single crystals

Science.gov (United States)

Jin, Jin-Ling; Zhang, Xiang-Qun; Li, Guo-Ke; Cheng, Zhao-Hua; Zheng, Lin; Lu, Yi

2011-05-01

The magnetocaloric effect (MCE) in TbMnO3 single crystals was investigated by isothermal magnetization curves for the ab plane at low temperatures. Large magnetic entropy change, ΔSM = -18.0 J/kg K, and the refrigerant capacity, RC = 390.7 J/kg, are achieved near the ordering temperature of Tb3+ moment (TNTb) under 70 kOe along the a axis. Furthermore, the TbMnO3 single crystal exhibits a giant MCE anisotropy. The difference of ΔSMand RC between the a and b axes is field and temperature dependent, which reaches maximum values of 11.4 J/kg K and 304.1 J/kg, respectively. By taking magnetocrystalline anisotropy into account, the rotating ΔSMwithin the ab plane can be well simulated, indicating that the anisotropy of ΔSMis directly contributed from the magnetocrystalline anisotropy. Our finding for giant MCE anisotropy in TbMnO3 single crystals explores the possibility of using this material for magnetic refrigerators by rotating its magnetization vector rather than moving it in and out of the magnet.

Momentum anisotropy at freeze out

International Nuclear Information System (INIS)

Feld, S.; Borghini, N.; Lang, C.

2017-01-01

The transition from a hydrodynamical modeling to a particle-based approach is a crucial element of the description of high-energy heavy-ion collisions. Assuming this “freeze out” happens instantaneously at each point of the expanding medium, we show that the local phase-space distribution of the emitted particles is asymmetric in momentum space. This suggests the use of anisotropic hydrodynamics for the last stages of the fluid evolution. We discuss how observables depend on the amount of momentum-space anisotropy at freeze out and how smaller or larger anisotropies allow for different values of the freeze-out temperature. (paper)

Ginzburg-Landau theory of the superheating field anisotropy of layered superconductors

Science.gov (United States)

Liarte, Danilo B.; Transtrum, Mark K.; Sethna, James P.

2016-10-01

We investigate the effects of material anisotropy on the superheating field of layered superconductors. We provide an intuitive argument both for the existence of a superheating field, and its dependence on anisotropy, for κ =λ /ξ (the ratio of magnetic to superconducting healing lengths) both large and small. On the one hand, the combination of our estimates with published results using a two-gap model for MgB2 suggests high anisotropy of the superheating field near zero temperature. On the other hand, within Ginzburg-Landau theory for a single gap, we see that the superheating field shows significant anisotropy only when the crystal anisotropy is large and the Ginzburg-Landau parameter κ is small. We then conclude that only small anisotropies in the superheating field are expected for typical unconventional superconductors near the critical temperature. Using a generalized form of Ginzburg Landau theory, we do a quantitative calculation for the anisotropic superheating field by mapping the problem to the isotropic case, and present a phase diagram in terms of anisotropy and κ , showing type I, type II, or mixed behavior (within Ginzburg-Landau theory), and regions where each asymptotic solution is expected. We estimate anisotropies for a number of different materials, and discuss the importance of these results for radio-frequency cavities for particle accelerators.

Influences of Structure Disorder and Temperature on Properties of Proton Conductivity in Hydrogen-Bond Molecular Systems

Institute of Scientific and Technical Information of China (English)

PANG Xiao-Feng; YU Jia-Feng

2007-01-01

The dynamic properties of proton conductivity along hydrogen-bonded molecular systems,for example,ice crystal,with structure disorder or damping and finite temperatures exposed in an externally applied electric-field have been numerically studied by Runge-Kutta way in our Soliton model.The results obtained show that the proton-soliton is very robust against the structure disorder including the fluctuation of the force constant and disorder in the sequence of masses and thermal perturbation and damping of medium,the velocity of its conductivity increases with increasing of the externally applied electric-field and decreasing of the damping coefficient of medium,but the proton-soliton disperses for quite great fluctuation of the force constant and damping coefficient.In the numerical simulation we find that the proton-soliton in our model is thermally stable in a large region of temperature of T ≤ 273 K under influences of damping and externally applied electric-field in ice crystal.This shows that our model is available and appropriate to ice.

Influences of Structure Disorder and Temperature on Properties of Proton Conductivity in Hydrogen-Bond Molecular Systems

International Nuclear Information System (INIS)

Pang Xiaofeng; Yu Jiafeng

2007-01-01

The dynamic properties of proton conductivity along hydrogen-bonded molecular systems, for example, ice crystal, with structure disorder or damping and finite temperatures exposed in an externally applied electric-field have been numerically studied by Runge-Kutta way in our soliton model. The results obtained show that the proton-soliton is very robust against the structure disorder including the fluctuation of the force constant and disorder in the sequence of masses and thermal perturbation and damping of medium, the velocity of its conductivity increases with increasing of the externally applied electric-field and decreasing of the damping coefficient of medium, but the proton-soliton disperses for quite great fluctuation of the force constant and damping coefficient. In the numerical simulation we find that the proton-soliton in our model is thermally stable in a large region of temperature of T≤273 K under influences of damping and externally applied electric-field in ice crystal. This shows that our model is available and appropriate to ice.

Magnetic anisotropies in SmCo thin films

International Nuclear Information System (INIS)

Chen, K.

1993-01-01

A systemic study of the deposition processes and magnetic properties for the Sm-Co film system has been carried out. Films of Sm-Co system with various magnetic anisotropies have been synthesized through sputter deposition in both crystalline and amorphous phases. The origins of various anisotropies have been studied. Thermalized sputter deposition process control was used to synthesize Fe enriched Sm-Co films with rhombohedral Th 2 Zn 17 type structure. The film exhibited unusually strong textures with the crystallographic c axes of the crystallites aligned in the film plane. A large anisotropy was resulted with easy axis in the film plane. A well defined and large in-the-film-plane anisotropy of exceptionally high value of 3.3 x 10 6 erg/cm 3 has been obtained in the amorphous SmCo films by applying a magnetic field in the film plane during deposition. It was found that the in-the-film-plane anisotropy depended essentially on the applied field and Sm concentration. For films not synthesized through thermallized sputtering, the easy axis of the film could reoriented. A perpendicular anisotropy was also presented in the film synthesized through thermallized sputtering deposition. A large in-plane anisotropy was obtained in films deposited above ambient temperatures. It was concluded that the surface induced short range ordering was the origin of the in-the-film-phase anisotropy observed in amorphous film deposited in the presence of a magnetic field. The formation mechanism was different from that of the short range ordering induced by field annealing. The perpendicular anisotropy was shown to be growth induced. Large in-plane anisotropy in amorphous films was resulted form partial crystallization in the film. Both the formation of growth induced structure and partial crystallization in the film prevented the formation of the pair ordering and decreased in-the-film-plane anisotropy

Quantum Monte Carlo simulation for S=1 Heisenberg model with uniaxial anisotropy

International Nuclear Information System (INIS)

Tsukamoto, Mitsuaki; Batista, Cristian; Kawashima, Naoki

2007-01-01

We perform quantum Monte Carlo simulations for S=1 Heisenberg model with an uniaxial anisotropy. The system exhibits a phase transition as we vary the anisotropy and a long range order appears at a finite temperature when the exchange interaction J is comparable to the uniaxial anisotropy D. We investigate quantum critical phenomena of this model and obtain the line of the phase transition which approaches a power-law with logarithmic corrections at low temperature. We derive the form of logarithmic corrections analytically and compare it to our simulation results

1H NMR spectra. Part 30(+): 1H chemical shifts in amides and the magnetic anisotropy, electric field and steric effects of the amide group.

Science.gov (United States)

Abraham, Raymond J; Griffiths, Lee; Perez, Manuel

2013-03-01

The (1)H spectra of 37 amides in CDCl(3) solvent were analysed and the chemical shifts obtained. The molecular geometries and conformational analysis of these amides were considered in detail. The NMR spectral assignments are of interest, e.g. the assignments of the formamide NH(2) protons reverse in going from CDCl(3) to more polar solvents. The substituent chemical shifts of the amide group in both aliphatic and aromatic amides were analysed using an approach based on neural network data for near (≤3 bonds removed) protons and the electric field, magnetic anisotropy, steric and for aromatic systems π effects of the amide group for more distant protons. The electric field is calculated from the partial atomic charges on the N.C═O atoms of the amide group. The magnetic anisotropy of the carbonyl group was reproduced with the asymmetric magnetic anisotropy acting at the midpoint of the carbonyl bond. The values of the anisotropies Δχ(parl) and Δχ(perp) were for the aliphatic amides 10.53 and -23.67 (×10(-6) Å(3)/molecule) and for the aromatic amides 2.12 and -10.43 (×10(-6) Å(3)/molecule). The nitrogen anisotropy was 7.62 (×10(-6) Å(3)/molecule). These values are compared with previous literature values. The (1)H chemical shifts were calculated from the semi-empirical approach and also by gauge-independent atomic orbital calculations with the density functional theory method and B3LYP/6-31G(++) (d,p) basis set. The semi-empirical approach gave good agreement with root mean square error of 0.081 ppm for the data set of 280 entries. The gauge-independent atomic orbital approach was generally acceptable, but significant errors (ca. 1 ppm) were found for the NH and CHO protons and also for some other protons. Copyright © 2013 John Wiley & Sons, Ltd.

Metal Phosphates as Proton Conducting Materials for Intermediate Temperature Fuel Cell and Electrolyser Applications

DEFF Research Database (Denmark)

Anfimova, Tatiana

The present thesis presents the results achieved during my ph.d. project on a subject of intermediate temperature proton conducting metal phosphates as electrolyte materials for fuel cells and electrolysers. Fuel cells and electrolysers are electrochemical devices with high energy conversion...... with a proton conductivity of above 10-2S cm-1. Chapter 1 of the thesis is an introduction to basics of fuel cell and electrolyser technologies as well as proton conducting materials. Extended discussion on the proton conducting materials, a particularly phosphates is made in Chapter 2. Three major types...... starts with synthesis and investigation of three rare earth metal phosphate hydrates, which is first presented in Chapter 5. Structural and surface water as well as its stability has been investigated using thermogravimetric and differential thermal analyses combined with structural modeling calculations...

Thermal conductivity of carbon felts, insulating materials with a high anisotropy; Conductivite thermique des feutres de carbone, isolants a forte anisotropie

Energy Technology Data Exchange (ETDEWEB)

Danes, F.E.; Bardon, J.P. [Centre National de la Recherche Scientifique, 44 - Nantes (France). Lab. de Thermocinetique

1996-12-31

Because of their high temperature resistance, carbon felts are used as thermal insulating materials for high temperature applications. The aim of this paper is to present a model that allows to calculate the thermal conductivity of felt fibers taking into account their high anisotropy and the contact resistance of fibers generated by the 3-D constriction phenomena which develop in fibers around each contact point. The study is divided in two parts: the first part concerns the bibliographic study of the different anisotropies of fibers and felts, while the second part presents the proposed conductivity model. (J.S.) 12 refs.

Flexibl Pavement Analysis Considering Temperature Profile and Anisotropy Behavior in Hot Mix Asphalt Layer

Directory of Open Access Journals (Sweden)

Choi Joonho

2011-12-01

Full Text Available A three Dimensional finite element model (FEM incorporating the anisotropic properties and temperature profile of hot mix asphalt (HMA pavement was developed to predict the structural responses of HMA pavement subject to heavy loads typically encountered in the field. In this study, ABAQUS was adopted to model the stress and strain relationships within the pavement structure. The results of the model were verified using data collected from the Korean Highway Corporation Test Road (KHCTR. The results demonstrated that both the base course and surface course layers follow the anisotropic behavior and the incorporation of the temperature profile throughout the pavement has a substantial effect on the pavement response predictions that impact pavement design. The results also showed that the anisotropy level of HMA and base material can be reduced to as low as 80% and 15% as a result of repeated loading, respectively.

Electromagnetic waves near the proton cyclotron frequency: Stereo observations

Energy Technology Data Exchange (ETDEWEB)

Jian, L. K. [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Wei, H. Y.; Russell, C. T. [Institute of Geophysics and Planetary Physics, University of California, Los Angeles, CA 90095 (United States); Luhmann, J. G. [Space Science Laboratory, University of California, Berkeley, CA 94720 (United States); Klecker, B. [Max-Planck-Institut für Extraterrestrische Physik, D-85741 Garching (Germany); Omidi, N. [Solana Scientific Inc., Solana Beach, CA 92075 (United States); Isenberg, P. A. [Institute for the Study of Earth, Oceans, and Space, University of New Hampshire, Durham, NH 03824 (United States); Goldstein, M. L.; Figueroa-Viñas, A. [Heliophysics Science Division, NASA Goddard Space Flight Center, MD 20771 (United States); Blanco-Cano, X., E-mail: lan.jian@nasa.gov [Instituto de Geofisica, Universidad Nacional Autónoma de México, Coyoacán D.F. (Mexico)

2014-05-10

Transverse, near-circularly polarized, parallel-propagating electromagnetic waves around the proton cyclotron frequency were found sporadically in the solar wind throughout the inner heliosphere. They could play an important role in heating and accelerating the solar wind. These low-frequency waves (LFWs) are intermittent but often occur in prolonged bursts lasting over 10 minutes, named 'LFW storms'. Through a comprehensive survey of them from Solar Terrestrial Relations Observatory A using dynamic spectral wave analysis, we have identified 241 LFW storms in 2008, present 0.9% of the time. They are left-hand (LH) or right-hand (RH) polarized in the spacecraft frame with similar characteristics, probably due to Doppler shift of the same type of waves or waves of intrinsically different polarities. In rare cases, the opposite polarities are observed closely in time or even simultaneously. Having ruled out interplanetary coronal mass ejections, shocks, energetic particles, comets, planets, and interstellar ions as LFW sources, we discuss the remaining generation scenarios: LH ion cyclotron instability driven by greater perpendicular temperature than parallel temperature or by ring-beam distribution, and RH ion fire hose instability driven by inverse temperature anisotropy or by cool ion beams. The investigation of solar wind conditions is compromised by the bias of the one-dimensional Maxwellian fit used for plasma data calibration. However, the LFW storms are preferentially detected in rarefaction regions following fast winds and when the magnetic field is radial. This preference may be related to the ion cyclotron anisotropy instability in fast wind and the minimum in damping along the radial field.

Measurement of proton and nitrogen polarization in ammonia and a test of equal spin temperature

CERN Document Server

AUTHOR|(CDS)2067425; Arvidson, A; Badelek, B; Baum, G; Berglund, P; Betev, L; De Botton, N R; Bradamante, Franco; Bradtke, C; Bravar, A; Bültmann, S; Crabb, D; Cranshaw, J; Çuhadar-Dönszelmann, T; Dalla Torre, S; Van Dantzig, R; Derro, B R; Dreshpande, A; Dhawan, S K; Dulya, C M; Dutz, H; Eichblatt, S; Fasching, D; Feinstein, F; Fernández, C; Forthmann, S; Frois, Bernard; Gallas, A; Garzón, J A; Gehring, R; Gilly, H; Giorgi, M A; Görtz, S; Gracia, G; De Groot, N; Grosse-Perdekamp, M; Haft, K; Harmsen, J; Von Harrach, D; Hasegawa, T; Hautle, P; Hayashi, N; Heusch, C A; Horikawa, N; Hughes, V W; Igo, G; Ishimoto, S; Iwata, T; Kabuss, E M; Kageya, T; Karev, A G; Ketel, T; Kiryluk, J; Kiselev, Yu F; Kok, E; Krämer, Dietrich; Kröger, W; Kurek, K; Kyynäräinen, J; Lamanna, M; Landgraf, U; Le Goff, J M; Lehár, F; de Lesquen, A; Lichtenstadt, J; Litmaath, M; Magnon, A; Mallot, G K; Martin, A; Matsuda, T; Mayes, B W; McCarthy, J S; Medved, K S; Meyer, W T; Van Middelkoop, G; Miller, D; Miyachi, Y; Mori, K; Nassalski, J P; Niinikoski, T O; Oberski, J; Ogawa, A; Parks, D P; Pereira da Costa, H D; Perrot-Kunne, F; Peshekhonov, V D; Pinsky, L; Platchkov, S K; Pló, M; Plückthun, M; Polec, J; Pose, D; Postma, H; Pretz, J; Puntaferro, R; Rädel, G; Reicherz, G; Rijllart, A; Rodríguez, M; Rondio, Ewa; Sandacz, A; Savin, I A; Schiavon, R P; Schiller, A; Sichtermann, E P; Simeoni, F; Smirnov, G I; Staude, A; Steinmetz, A; Stiegler, U; Stuhrmann, H B; Tessarotto, F; Tlaczala, W; Tripet, A; Ünel, G; Velasco, M; Vogt, J; Voss, Rüdiger; Whitten, C; Windmolders, R; Wislicki, W; Witzmann, A; Ylöstalo, J; Zanetti, A M; Zaremba, K

1998-01-01

The 1996 data taking of the SMC experiment used polarized protons to measure the spin dependent structure function $g_1$ of the proton. Three liters of solid granular ammonia were irradiated at the Bonn electron linac in order to create the paramagnetic radicals which are needed for polarizing the protons. Proton polarizations of $\\pm(90\\pm2.5)\\,\\%$ were routinely reached. An analysis based on a theoretical line-shape for spin-1 systems with large quadrupolar broadening was developed which allowed the nitrogen polarization in the ammonia to be determined with a 10% relative error. The measured quadrupolar coupling constant of $^{14}$N agrees well with earlier extrapolated values. The polarization of the nitrogen nuclei was measured as a function of the proton polarization in order to provide a test of the equal spin temperature (EST) hypothesis. It was found to be closely valid under the dynamic nuclear polarization conditions with which the protons are polarized. Large deviations from EST could be induced by...

H3PO4 imbibed polyacrylamide-graft-chitosan frameworks for high-temperature proton exchange membranes

Science.gov (United States)

Yuan, Shuangshuang; Tang, Qunwei; He, Benlin; Chen, Haiyan; Li, Qinghua; Ma, Chunqing; Jin, Suyue; Liu, Zhichao

2014-03-01

Proton exchange membrane (PEM), transferring protons from anode to cathode, is a key component in a PEM fuel cell. In the current work, a new class of PEMs are synthesized benefiting from the imbibition behavior of three-dimensional (3D) polyacrylamide-graft-chitosan (PAAm-graft-chitosan) frameworks to H3PO4 aqueous solution. Interconnected 3D framework of PAAm-graft-chitosan provides tremendous space for holding proton-conducting H3PO4. The highest anhydrous proton conductivity of 0.13 S cm-1 at 165 °C is obtained. A fuel cell using a thick membrane as a PEM showed a peak power density of 405 mW cm-2 with O2 and H2 as the oxidant and fuel, respectively. Results indicate that the interconnected 3D framework provides superhighway for proton conduction. The valued merits on anhydrous proton conductivity, huge H3PO4 loading, and easy synthesis promise the new membranes to be good alternatives as high-temperature PEMs.

Magnetic anisotropies of (Ga,Mn)As films and nanostructures

Energy Technology Data Exchange (ETDEWEB)

Hoffmann, Frank

2011-02-02

In this work the magnetic anisotropies of the diluted magnetic semiconductor (Ga,Mn)As were investigated experimentally. (Ga,Mn)As films show a superposition of various magnetic anisotropies which depend sensitively on various parameters such as temperature, carrier concentration or lattice strain. However, the anisotropies of lithographically prepared (Ga,Mn)As elements differ significantly from an unpatterned (Ga,Mn)As film. In stripe-shaped structures this behaviour is caused by anisotropic relaxation of the compressive lattice strain. In order to determine the magnetic anisotropies of individual (Ga,Mn)As nanostructures a combination of ferromagnetic resonance and time-resolved scanning Kerr microscopy was employed in this thesis. In addition, local changes of the magnetic anisotropy in circular and rectangular structures were visualized by making use of spatially resolved measurements. Finally, also the influence of the laterally inhomogeneous magnetic anisotropies on the static magnetic properties, such as coercive fields, was investigated employing spatially resolved static MOKE measurements on individual (Ga,Mn)As elements. (orig.)

Growth anisotropy effect of bulk high temperature superconductors on the levitation performance in the applied magnetic field

Science.gov (United States)

Zheng, J.; Liao, X. L.; Jing, H. L.; Deng, Z. G.; Yen, F.; Wang, S. Y.; Wang, J. S.

2013-10-01

Growth anisotropies of bulk high temperature superconductors (HTSCs) fabricated by a top-seeded melt texture growth process, that is, different pinning effect in the growth sectors (GSs) and growth sector boundaries (GSBs), possess effect on the macro flux trapping and levitation performance of bulk HTSCs. Previous work (Physics Procedia, 36 (2012) 1043) has found that the bulk HTSC array with aligned GSB pattern (AGSBP) exhibits better capability for levitation and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP). In this paper, we further examine this growth anisotropy effect on the maglev performance of a double-layer bulk HTSC. In contrast to reported trapped flux cases (Supercond. Sci. Technol. 19 (2006) S466), the two superposed bulk HTSCs with same AGSBP with PMG are found to show better maglev performance. These series of results are helpful and support a new way for the performance optimization of present HTS maglev systems.

Thermal Fluctuations in the Magnetic Ground State of the Molecular Cluster Mn12O12 Acetate from μSR and Proton NMR Relaxation

International Nuclear Information System (INIS)

Lascialfari, A.; Borsa, F.; Carretta, P.; Jang, Z.H.; Borsa, F.; Gatteschi, D.

1998-01-01

Measurements of the spin-lattice relaxation rate are reported for muons and protons as a function of temperature for different values of the applied magnetic field in the Mn 12 O 12 molecular cluster. Strongly field dependent maxima in the relaxation rate versus temperature are observed below 50thinspthinspK. The results are explained in terms of thermal fluctuations of the total magnetization of the cluster among the different orientations with respect to the anisotropy axis. The lifetimes of the different m components of the total spin, S T =10 , of the molecule are obtained from the experiment and shown to be consistent with the ones expected from a spin-phonon coupling mechanism. No clear evidence for macroscopic quantum tunneling was observed in the field dependence of the proton relaxation rate at low T . copyright 1998 The American Physical Society

A proton-recoil neutron spectrometer for time-dependent ion temperatures on the National Ignition Facility

International Nuclear Information System (INIS)

Murphy, T.J.

1995-01-01

Ion temperatures from inertial confinement fusion targets are usually determined by measuring the Doppler broadening of the neutron spectrum using the time-of-flight method. Measurement systems are generally designed so that the contribution of the duration of neutron production (∼100 ps) to the width of the neutron signal is negligible. This precludes the possibility of time-dependent ion temperature. If, however, one could measure the neutron energy and arrival time at a detector independently, then time-dependent neutron spectra could be obtained, and ion temperature information deduced. A concept utilizing a proton-recoil neutron spectrometer has been developed in which recoil protons from a small plastic foil are measured. From the energy, arrival time, and recoil angle of the recoil proton, the birth time and energy of the incident neutron can be deduced. The sensitivity of the system is low, but the higher anticipated neutron yields from the proposed National Ignition Facility may make the technique feasible. Large scintillator arrays currently in use on the Nova facility for neutron spectral measurements consist of ∼1,000 channels and detect between 50 and 500 counts for typical time-integrated data. Time-dependent results would then require about an order of magnitude larger system. Key issues for making this system feasible will be keeping the cost per channel low while allowing adequately time (∼ 50 ps), energy (20 keV), and angular resolution (2 mrad) for each of the proton detectors

Influence of carbonization conditions on the development of different types of optical anisotropy in cokes

Energy Technology Data Exchange (ETDEWEB)

Patrick, J W; Reynolds, M J; Shaw, F H

1975-01-01

The vitrain components of a series of coal samples were carbonized at temperatures from 400 to 1000/sup 0/C at different rates of heating ranging from 0.5 to 10/sup 0/K/min and utilizing soaking times up to 24 hr. Polished specimens prepared from the carbonized products were examined microscopically under polarized light in order to determine the proportions of the various types of optical anisotropy present in them. The variations in heating rate and soaking time were found to exert little significant influence on the anisotropy developed in high-temperature cokes. But in semicokes produced at carbonization temperatures within the plastic range the influence of the carbonization conditions was much more pronounced with the effects being interrelated. Decreasing the heating rate or increasing the soaking time led to the optical anisotropy generally becoming detectable at lower carbonization temperatures. Fast heating rates caused an increase in the rate of transformation of the fine-grain mosaic anisotropy into coarser-grained types of anisotropy and increased soaking time led to enhanced anisotropic development in the semicokes produced at temperatures within the plastic range. The type of anisotropy developed in cokes is closely related to the release of volatile matter and the plasticity developed during carbonization and the conclusion is drawn that the balance between these factors controls the extent of the anisotropic development.

CMB anisotropies at all orders: the non-linear Sachs-Wolfe formula

International Nuclear Information System (INIS)

Roldan, Omar

2017-01-01

We obtain the non-linear generalization of the Sachs-Wolfe + integrated Sachs-Wolfe (ISW) formula describing the CMB temperature anisotropies. Our formula is valid at all orders in perturbation theory, is also valid in all gauges and includes scalar, vector and tensor modes. A direct consequence of our results is that the maps of the logarithmic temperature anisotropies are much cleaner than the usual CMB maps, because they automatically remove many secondary anisotropies. This can for instance, facilitate the search for primordial non-Gaussianity in future works. It also disentangles the non-linear ISW from other effects. Finally, we provide a method which can iteratively be used to obtain the lensing solution at the desired order.

CMB anisotropies at all orders: the non-linear Sachs-Wolfe formula

Energy Technology Data Exchange (ETDEWEB)

Roldan, Omar, E-mail: oaroldan@if.ufrj.br [Instituto de Física, Universidade Federal do Rio de Janeiro, 21941-972, Rio de Janeiro, RJ (Brazil)

2017-08-01

We obtain the non-linear generalization of the Sachs-Wolfe + integrated Sachs-Wolfe (ISW) formula describing the CMB temperature anisotropies. Our formula is valid at all orders in perturbation theory, is also valid in all gauges and includes scalar, vector and tensor modes. A direct consequence of our results is that the maps of the logarithmic temperature anisotropies are much cleaner than the usual CMB maps, because they automatically remove many secondary anisotropies. This can for instance, facilitate the search for primordial non-Gaussianity in future works. It also disentangles the non-linear ISW from other effects. Finally, we provide a method which can iteratively be used to obtain the lensing solution at the desired order.

Plasma focus neutron anisotropy measurements and influence of a deuteron beam obstacle

Energy Technology Data Exchange (ETDEWEB)

Talebitaher, A. [Physics Department, University of Regina, Saskatchewan, Canada S4S 0A2 (Canada); Springham, S.V., E-mail: stuart.springham@nie.edu.sg [Natural Sciences and Science Education, National Institute of Education, 637616 (Singapore); Rawat, R.S.; Lee, P. [Natural Sciences and Science Education, National Institute of Education, 637616 (Singapore)

2017-03-11

The deuterium-deuterium (DD) fusion neutron yield and anisotropy were measured on a shot-to-shot basis for the NX2 plasma focus (PF) device using two beryllium fast-neutron activation detectors at 0° and 90° to the PF axis. Measurements were performed for deuterium gas pressures in the range 6–16 mbar, and positive correlations between neutron yield and anisotropy were observed at all pressures. Subsequently, at one deuterium gas pressure (13 mbar), the contribution to the fusion yield produced by the forwardly-directed D{sup +} ion beam, emitted from the plasma pinch, was investigated by using a circular Pyrex plate to obstruct the beam and suppress its fusion contribution. Neutron measurements were performed with the obstacle positioned at two distances from the anode tip, and also without the obstacle. It was found that ~ 80% of the neutron yield originates in the plasma pinch column and just above that. In addition, proton pinhole imaging was performed from the 0° and 90° directions to the pinch. The obtained proton images are consistent with the conclusion that DD fusion is concentrated (~ 80%) in the pinch column region.

Flow stress anisotropy in aluminium

DEFF Research Database (Denmark)

Juul Jensen, D.; Hansen, N.

1990-01-01

The plastic anisotropy of cold-rolled high purity aluminum (99.996%) and commercially pure aluminum (99.6%) has been investigated. Sample parameters were the initial grain size and the degree of plastic strain (ϵ < 3.00). Flow stresses (0.2% offset) were measured at room temperature by uniaxial t...

Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

International Nuclear Information System (INIS)

Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

2013-01-01

A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

Elevated Temperature Effects on the Plastic Anisotropy of an Extruded Mg-4 Wt Pct Li Alloy: Experiments and Polycrystal Modeling

Science.gov (United States)

Risse, Marcel; Lentz, Martin; Fahrenson, Christoph; Reimers, Walter; Knezevic, Marko; Beyerlein, Irene J.

2017-01-01

In this work, we study the deformation behavior of Mg-4 wt pct Li in uniaxial tension as a function of temperature and loading direction. Standard tensile tests were performed at temperatures in the range of 293 K (20 °C) ≤ T ≤ 473 K (200 °C) and in two in-plane directions: the extrusion and the transverse. We find that while the in-plane plastic anisotropy (PA) decreases with temperature, the anisotropy in failure strain and texture development increases. To uncover the temperature dependence in the critical stresses for slip and in the amounts of slip and twinning systems mediating deformation, we employ the elastic-plastic self-consistent polycrystal plasticity model with a thermally activated dislocation density based hardening law for activating slip with individual crystals. We demonstrate that the model, with a single set of intrinsic material parameters, achieves good agreement with the stress-strain curves, deformation textures, and intragranular misorientation axis analysis for all test directions and temperatures. With the model, we show that at all temperatures the in-plane tensile behavior is driven primarily by analysis explains that the in-plane PA decreases and failure strains increase with temperature as a result of a significant reduction in the activation stress for pyramidal multiple types of < a rangle and < {c + a} rangle slip. The results also show that because of the strong initial texture, in-plane texture development is anisotropic since prismatic slip dominates the deformation in one test, although it is not the easiest slip mode, and basal slip in the other. These findings reveal the relationship between the temperature-sensitive thresholds needed to activate crystallographic slip and the development of texture and macroscopic PA.

Epoxides cross-linked hexafluoropropylidene polybenzimidazole membranes for application as high temperature proton exchange membranes

International Nuclear Information System (INIS)

Yang, Jingshuai; Xu, Yixin; Liu, Peipei; Gao, Liping; Che, Quantong; He, Ronghuan

2015-01-01

Covalently cross-linked hexafluoropropylidene polybenzimidazole (F 6 PBI) was prepared and used to fabricate high temperature proton exchange membranes with enhanced mechanical strength against thermoplastic distortion. Three different epoxides, i.e. bisphenol A diglycidyl ether (R 1 ), bisphenol A propoxylate diglycidyl ether (R 2 ) and poly(ethylene glycol) diglycidyl ether (R 3 ), were chosen as the cross-linkers to investigate the influence of their structures on the properties of the cross-linked F 6 PBI membranes. All the cross-linked F 6 PBI membranes displayed excellent stability towards the radical oxidation. Comparing with the pure F 6 PBI membrane, the cross-linked F 6 PBI membranes showed high acid doping level but less swelling after doping phosphoric acid at elevated temperatures. The mechanical strength at 130 °C was improved from 0.4 MPa for F 6 PBI membrane to a range of 0.8–2.0 MPa for the cross-linked F 6 PBI membranes with an acid doping level as high as around 14, especially for that crosslinking with the epoxide (R 3 ), which has a long linear structure of alkyl ether. The proton conductivity of the cross-linked membranes was increased accordingly due to the high acid doping levels. Fuel cell tests demonstrated the technical feasibility of the acid doped cross-linked F 6 PBI membranes for high temperature proton exchange membrane fuel cells

Proton Transfer in Perfluorosulfonic Acid Fuel Cell Membranes with Differing Pendant Chains and Equivalent Weights.

Science.gov (United States)

Thomaz, Joseph E; Lawler, Christian M; Fayer, Michael D

2017-05-04

Proton transfer in the nanoscopic water channels of polyelectrolyte fuel cell membranes was studied using a photoacid, 8-hydroxypyrene-1,3,6-trisulfonic acid sodium salt (HPTS), in the channels. The local environment of the probe was determined using 8-methoxypyrene-1,3,6-trisulfonic acid sodium salt (MPTS), which is not a photoacid. Three fully hydrated membranes, Nafion (DuPont) and two 3M membranes, were studied to determine the impact of different pendant chains and equivalent weights on proton transfer. Fluorescence anisotropy and excited state population decay data that characterize the local environment of the fluorescent probes and proton transfer dynamics were measured. The MPTS lifetime and anisotropy results show that most of the fluorescent probes have a bulk-like water environment with a relatively small fraction interacting with the channel wall. Measurements of the HPTS protonated and deprotonated fluorescent bands' population decays provided information on the proton transport dynamics. The decay of the protonated band from ∼0.5 ns to tens of nanoseconds is in part determined by dissociation and recombination with the HPTS, providing information on the ability of protons to move in the channels. The dissociation and recombination is manifested as a power law component in the protonated band fluorescence decay. The results show that equivalent weight differences between two 3M membranes resulted in a small difference in proton transfer. However, differences in pendant chain structure did significantly influence the proton transfer ability, with the 3M membranes displaying more facile transfer than Nafion.

Proton conducting hydrocarbon membranes: Performance evaluation for room temperature direct methanol fuel cells

International Nuclear Information System (INIS)

Krivobokov, Ivan M.; Gribov, Evgeniy N.; Okunev, Alexey G.

2011-01-01

The methanol permeability, proton conductivity, water uptake and power densities of direct methanol fuel cells (DMFCs) at room temperature are reported for sulfonated hydrocarbon (sHC) and perfluorinated (PFSA) membranes from Fumatech, and compared to Nafion membranes. The sHC membranes exhibit lower proton conductivity (25-40 mS cm -1 vs. ∼95-40 mS cm -1 for Nafion) as well as lower methanol permeability (1.8-3.9 x 10 -7 cm 2 s -1 vs. 2.4-3.4 x 10 -6 cm 2 s -1 for Nafion). Water uptake was similar for all membranes (18-25 wt%), except for the PFSA membrane (14 wt%). Methanol uptake varied from 67 wt% for Nafion to 17 wt% for PFSA. The power density of Nafion in DMFCs at room temperature decreases with membrane thickness from 26 mW cm -2 for Nafion 117 to 12.5 mW cm -2 for Nafion 112. The maximum power density of the Fumatech membranes ranges from 4 to 13 mW cm -1 . Conventional transport parameters such as membrane selectivity fail to predict membrane performance in DMFCs. Reliable and easily interpretable results are obtained when the power density is plotted as a function of the transport factor (TF), which is the product of proton concentration in the swollen membrane and the methanol flux. At low TF values, cell performance is limited by low proton conductivity, whereas at high TF values it decreases due to methanol crossover. The highest maximum power density corresponds to intermediate values of TF.

Anisotropy of domain wall resistance

Science.gov (United States)

Viret; Samson; Warin; Marty; Ott; Sondergard; Klein; Fermon

2000-10-30

The resistive effect of domain walls in FePd films with perpendicular anisotropy was studied experimentally as a function of field and temperature. The films were grown directly on MgO substrates, which induces an unusual virgin magnetic configuration composed of 60 nm wide parallel stripe domains. This allowed us to carry out the first measurements of the anisotropy of domain wall resistivity in the two configurations of current perpendicular and parallel to the walls. At 18 K, we find 8.2% and 1.3% for the domain wall magnetoresistance normalized to the wall width (8 nm) in these two respective configurations. These values are consistent with the predictions of Levy and Zhang.

Perpendicular magnetic anisotropy of non-epitaxial hexagonal Co{sub 50}Pt{sub 50} thin films prepared at room temperature

Energy Technology Data Exchange (ETDEWEB)

Yuan, F.T., E-mail: ftyuan@gmail.com [iSentek Ltd., Advanced Sensor Laboratory, New Taipei City 22101, Taiwan (China); Chang, H.W., E-mail: wei0208@gmail.com [Department of Applied Physics, Tunghai University, Taichung 40704, Taiwan (China); Lee, P.Y.; Chang, C.Y. [Department of Applied Physics, Tunghai University, Taichung 40704, Taiwan (China); Chi, C.C. [Department of Materials Sciences and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Ouyang, H., E-mail: houyang@mx.nthu.edu.tw [Department of Materials Sciences and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan (China)

2015-04-15

Highlights: • In this paper, we propose a non-epitaxially grown PMA thin film of disorder hexagonal Co{sub 50}Pt{sub 50} which can satisfy all the requirements at once. • Although the preparation temperature is at room temperature and no post annealing is required, the film also shows good thermal stability up to 400 °C. • Moreover, the easy-controlling single layer deposition process of the film largely enhances the feasibility of practical production. • Significant PMA is achieved in a wide range of film thickness from 2 nm to 20 nm, which expands the usage form a GMR or TMR magnetic junctions to perpendicular spin polarizer for spin current related engineering. • The presented results may open new opportunities for advanced spintronic devices. - Abstract: Non-epitaxially induced perpendicular magnetic anisotropy (PMA) of Co{sub 50}Pt{sub 50} thin films at room temperature (RT) is reported. The CoPt film having a disordered hcp structure shows a magnetocrystalline anisotropy (K{sub u}{sup RT}) of 1–2 × 10{sup 6} erg/cm{sup 3} in a wide range of layer thickness from 2 to 20 nm. K{sub u}{sup RT} of about 1 × 10{sup 6} erg/cm{sup 3} can be preserved after a 400 °C-thermal cycle in the 5-nm-thick sample. Moderate PMA, large thickness range, simple preparation process, low formation temperature but good thermal stability make presented hcp CoPt become a remarkable option for advanced spintronic devices.

Anisotropy analysis of low cement concrete by ultrasonic measurements and image analysis

Directory of Open Access Journals (Sweden)

Martinović Sanja P.

2016-01-01

Full Text Available The analized material was high alumina low cement castable sintered at three different temperatures. Influence of initial material anisotropy on the thermal shock resistance as well as changes of anisotropy level during the thermal shock were studied. Water quench test was used as an experimental method for the thermal stability testing. Surface anisotropy was analysed by image analysis and structural anisotropy using ultrasonic measurements. The results pointed out that the highest homogeinity and the lowest surface and structural anisotropy was for the samples sintered at 1600ºC. Surface anistoropy had prevailing infuence on behavior of material during the thermal shock, but the structural anisotropy should not be neglected. [Projekat Ministarstva nauke Republike Srbije, br. TR 33007

Analysis of the magnetic anisotropy in SmCo5 and GdCo5

International Nuclear Information System (INIS)

Zhao, T.; Jin, H.; Groessinger, R.; Kou, X.; Kirchmayr, H.R.

1991-01-01

The temperature dependence of the magnetic anisotropy constant K 1 for SmCo 5 and GdCo 5 is well reproduced by calculations based on a single-ion model taking into account the anisotropies of the R--Co exchange interaction and the Co-sublattice magnetic moment. The anisotropy of the R--Co exchange interaction plays an important role in reproducing the experimental K 1 (T) for SmCo 5 and GdCo 5 . It is found that the absolute value of the second order crystalline electric field parameter A 0 2 in SmCo 5 decreases monotonically with increasing temperature

Effect of anisotropy on anomalous Hall effect in Tb-Fe thin films

International Nuclear Information System (INIS)

Babu, V. Hari; Markandeyulu, G.; Subrahmanyam, A.

2009-01-01

The electrical and Hall resistivities of Tb x Fe 100-x thin films in the temperature range 13-300 K were investigated. The sign of Hall resistivity at 300 K is found to change from positive for x=28 film to negative for x=30 film, in accordance with the compensation of Tb and Fe moments. All the films are seen to have planar magnetic anisotropy at 13 K. The temperature coefficients of electrical resistivities of the amorphous films with 19≤x≤51 are seen to be negative. The temperature dependence of Hall resistivity of these films is explained on the basis of random magnetic anisotropy model. The temperature dependences of Hall resistivities of the x=22 and 41 films are seen to exhibit a nonmonotonous behavior due to change in anisotropy from perpendicular to planar. The same behavior is considered for the explanation regarding the probable formation of Berry phase curvature in these films.

Thermal behavior for a nanoscale two ferromagnetic phase system based on random anisotropy model

International Nuclear Information System (INIS)

Muraca, D.; Sanchez, F.H.; Pampillo, L.G.; Saccone, F.D.

2010-01-01

Advances in theory that explain the magnetic behavior as function of temperature for two phase nanocrystalline soft magnetic materials are presented. The theory developed is based on the well known random anisotropy model, which includes the crystalline exchange stiffness and anisotropy energies in both amorphous and crystalline phases. The phenomenological behavior of the coercivity was obtained in the temperature range between the amorphous phase Curie temperature and the crystalline phase one.

Phosphoric acid doped imidazolium polysulfone membranes for high temperature proton exchange membrane fuel cells

DEFF Research Database (Denmark)

Yang, Jingshuai; Li, Qingfeng; Jensen, Jens Oluf

2012-01-01

A novel acid–base polymer membrane is prepared by doping of imidazolium polysulfone with phosphoric acid for high temperature proton exchange membrane fuel cells. Polysulfone is first chloromethylated, followed by functionalization of the chloromethylated polysulfone with alkyl imidazoles i.e. me...

On the in-plane uniaxial anisotropy formation by using Fe–Co–Zr–N films: A theoretical and experimental investigation

Energy Technology Data Exchange (ETDEWEB)

Seemann, K., E-mail: klaus.seemann@kit.edu; Beirle, S.; Leiste, H.

2016-09-01

In the present paper a simple theoretical approach for the in-plane uniaxial anisotropy evolution in thin films is introduced. In order to show, what are the conditions for a uniaxial anisotropy formation during annealing a ferromagnetic film in an external static magnetic field, a Hamiltonian, i.e., mean energy balances were established with introducing their annealing temperature dependence. At this point, a 1-dimesional chain-like arrangement of Fe and Co elements for an “isotropic” and uniaxial anisotropy state for the numerical computation was assumed. It was shown that a critical energy and annealing temperature (temperature threshold) can be attained from which a uniaxial anisotropy arises. Comparatively, calculations according to the Neél theory delivered the activation energy for inducing a uniaxial anisotropy. The experimental verification of the calculations, by using Fe{sub 40}Co{sub 37}Zr{sub 11}N{sub 12} films which were produced by reactive magnetron sputtering, yielded the activation energy of about 250 meV. Annealing temperatures above 473 K (200 °C) enabled marked uniaxial anisotropies. This correlated with the numerical quantum mechanical estimations which yielded a critical annealing temperature of approximately 449 K (176 °C). The calculated critical energy of 243 meV was in a good agreement with the verified experiments if one assumes a short range order of at least 10 ferromagnetic atoms in line (5Fe+5Co) for computation. - Highlights: • Model and theoretical description of the uniaxial anisotropy in ferromagnetic films. • Critical energy and a critical temperature for inducing the uniaxial anisotropy. • Investigation of the activation energy for inducing the uniaxial anisotropy. • Comparison with the model and according to the Neél theory.

TIMTEM - a digital program for the calculation of two-dimensional, non-linear temperature fields of reactor components of complex structure taking into account inhomogeneity and anisotropy

International Nuclear Information System (INIS)

Simon-Weidner, J.

1975-05-01

The digital program TIMTEM calculates twodimensional, nonlinear temperature fields of reactor components of complex structure; inhomogeneity and anisotropy are taken into account. Systems consisting of different materials and therefore having different temperature- and/or time-dependent material characteristics are allowed. Various local, time- and/or temperature-dependent boundary conditions can be considered, too, which may be locally different from each other or can be interconnected. (orig.) [de

Shape anisotropy: tensor distance to anisotropy measure

Science.gov (United States)

Weldeselassie, Yonas T.; El-Hilo, Saba; Atkins, M. S.

2011-03-01

Fractional anisotropy, defined as the distance of a diffusion tensor from its closest isotropic tensor, has been extensively studied as quantitative anisotropy measure for diffusion tensor magnetic resonance images (DT-MRI). It has been used to reveal the white matter profile of brain images, as guiding feature for seeding and stopping in fiber tractography and for the diagnosis and assessment of degenerative brain diseases. Despite its extensive use in DT-MRI community, however, not much attention has been given to the mathematical correctness of its derivation from diffusion tensors which is achieved using Euclidean dot product in 9D space. But, recent progress in DT-MRI has shown that the space of diffusion tensors does not form a Euclidean vector space and thus Euclidean dot product is not appropriate for tensors. In this paper, we propose a novel and robust rotationally invariant diffusion anisotropy measure derived using the recently proposed Log-Euclidean and J-divergence tensor distance measures. An interesting finding of our work is that given a diffusion tensor, its closest isotropic tensor is different for different tensor distance metrics used. We demonstrate qualitatively that our new anisotropy measure reveals superior white matter profile of DT-MR brain images and analytically show that it has a higher signal to noise ratio than fractional anisotropy.

Phenomenological description of anisotropy effects in some ferromagnetic superconductors

Energy Technology Data Exchange (ETDEWEB)

Shopova, Diana V., E-mail: sho@issp.bas.bg [TCCM Research Group, Institute of Solid State Physics, Bulgarian Academy of Sciences, BG-1784 Sofia (Bulgaria); Todorov, Michail D. [Department of Applied Mathematics and Computer Science, Technical University of Sofia, 1000 Sofia (Bulgaria)

2015-07-03

We study phenomenologically the role of anisotropy in ferromagnetic superconductors UGe{sub 2}, URhGe, and UCoGe for the description of their phase diagrams. We use the Ginzburg–Landau free energy in its uniform form as we will consider only spatially independent solutions. This is an expansion of previously derived results where the effect of Cooper-pair and crystal anisotropies is not taken into account. The three compounds are separately discussed with the special stress on UGe{sub 2}. The main effect comes from the strong uniaxial anisotropy of magnetization while the anisotropy of Cooper pairs and crystal anisotropy only slightly change the phase diagram in the vicinity of Curie temperature. The limitations of this approach are also discussed. - Highlights: • Anisotropic Landau energy for description of ferromagnetic superconductors is proposed. • Meissner phases are described with their existence and stability conditions. • The application of the model to UGe{sub 2} is discussed. • The limitations to apply the model for description of experimental data are explained.

Elastic anisotropy of crystals

Directory of Open Access Journals (Sweden)

Christopher M. Kube

2016-09-01

Full Text Available An anisotropy index seeks to quantify how directionally dependent the properties of a system are. In this article, the focus is on quantifying the elastic anisotropy of crystalline materials. Previous elastic anisotropy indices are reviewed and their shortcomings discussed. A new scalar log-Euclidean anisotropy measure AL is proposed, which overcomes these deficiencies. It is based on a distance measure in a log-Euclidean space applied to fourth-rank elastic tensors. AL is an absolute measure of anisotropy where the limiting case of perfect isotropy yields zero. It is a universal measure of anisotropy applicable to all crystalline materials. Specific examples of strong anisotropy are highlighted. A supplementary material provides an anisotropy table giving the values of AL for 2,176 crystallite compounds.

Temperature dependence of partial conductivities of the BaZr0.7Ce0.2Y0.1O3-δ proton conductor

Science.gov (United States)

Heras-Juaristi, Gemma; Pérez-Coll, Domingo; Mather, Glenn C.

2017-10-01

Partial conductivities are presented for BaZr0.7Ce0.2Y0.1O3-δ, an important proton conductor for protonic-ceramic fuel cells and membrane reactors. Atmospheric dependencies of impedance performed in humidified and dry O2, air, N2 and H2(10%)/N2(90%) in the temperature range 300-900 °C, supported by the modified emf method, confirm significant electron-hole and protonic contributions to transport. For very reducing and wet atmospheres, the conductivity is predominantly ionic, with a higher participation of protons with decreasing temperature and increasing water-vapour partial pressure (pH2O). From moderately reducing conditions of wet N2 to wet O2, however, the conductivity is considerably influenced by electron holes as revealed by a significant dependence of total conductivity on oxygen partial pressure (pO2). With higher pH2O, proton transport increases, with a concomitant decrease of holes and oxygen vacancies. However, the effect of pH2O is also influenced by temperature, with a greater protonic contribution at both lower temperature and pO2. Values of proton transport number tH ≈ 0.63 and electronic transport number th ≈ 0.37 are obtained at 600 °C for pH2O = 0.022 atm and pO2 = 0.2 atm, whereas tH ≈ 0.95 and th ≈ 0.05 for pO2 = 10-5 atm. A hydration enthalpy of -109 kJ mol-1 is obtained in the range 600-900 °C.

Geodynamic Constraints on the Sources of Seismic Anisotropy Beneath Madagascar

Science.gov (United States)

Rajaonarison, T. A.; Stamps, D. S.; Fishwick, S.

2017-12-01

The rheological structure of the lithosphere-asthenosphere system controls the degree in which the mantle drives surface motions. Seismic anisotropy is a proxy to infer information about previous tectonic events imprinted in lithospheric structures and/or asthenospheric flow pattern in regions absent of active volcanism, however, distinguishing between the shallow and deeper sources, respectively, remains ambiguous. Madagascar is an ideal natural laboratory to study the sources of anisotropy and the rheological implications for lithosphere-asthenosphere system because 1) active volcanism is minimal or absent, 2) there are well-exposed tectonic fabrics for comparison, and 3) numerous geological and geophysical observations provides evidence of present-day tectonic activities. Recent studies suggest new seismic anisotropy observations in southern Madagascar are sourced from both fossilized lithospheric structure and asthenospheric flow driven by rigid lithospheric plate motion. In this work we compare geodynamic simulations of the lithosphere-asthenosphere system with seismic anisotropy data set that includes all of Madagascar. We use the numerical code Advanced Solver for Problems in Earth's ConvecTion (ASPECT) to calculate instantaneous deformation in the lithosphere and edge-driven convective flow in the asthenosphere accounting for variations in buoyancy forces and temperature dependent viscosity. The initial temperature conditions are based on interpretations from high resolution regional surface wave tomography. We assume visco-plastic rheology for a uniform crust, dislocation creep for a laterally varying mantle lithospheric structure, and diffusion creep for the asthenosphere. To test for the source of anisotropy we compare our velocity solution azimuths with azimuths of anisotropy at 25 km depth intervals. Calculated asthenospheric flow aligns with measured seismic anisotropy with a 15° WRMS at 175 km depth and possibly down to 250 km suggesting the

Mechanical properties of low temperature proton irradiated single crystal copper

International Nuclear Information System (INIS)

Schildcrout, M.

1975-01-01

Single crystal copper samples, of varying degrees of cold work, were irradiated near either liquid helium or liquid nitrogen temperature by 10.1-MeV protons. The internal friction and dynamic Young's modulus were observed as a function of either temperature or integrated proton flux. The primary effect of irradiation was to produce dislocation pinning. The initial pinning rate was found to be very sensitive to cold work. During irradiation it was found that heavily cold worked samples (25 percent compression) exhibited, almost exclusively, exponential pinning given by Y = e/sup --lambda phi/. This is attributed to the immobilization, rather than shortening, of loop lengths and is characterized by the pinning constant lambda. Exponential pinning was also found, to a smaller degree, in less heavily cold worked samples. Cold work appears to reduce the ''effective volume'' within which the defect clusters produced by irradiation, can immobilize dislocation segments. The bulk effect was observed after dislocation pinning was completed. Expressed in terms of the fractional change in Young's modulus per unit concentration of irradiation induced defects, it was measured at liquid helium temperature to be --18.5 +- 3. An anelastic process occurring near 10 0 K for low kHz frequencies and due to stress-induced ordering of point defects produced by irradiation has also been studied. The peak height per unit fluence was found to decrease with increasing cold work. The peak was not observed in samples compressed 25 percent. For the most carefully handled sample the activation energy was (1.28 +- 0.05) x 10 -2 eV, the attempt frequency was 10/sup 11.6 +- .8/ s -1 , the shape factor was 0.20, and the half width of the peak was 11 percent larger than the theoretical value calculated from the Debye equation for a single relaxation process

Anisotropy of the proton spin--lattice relaxation time in the superconducting intercalation complex TaS2(NH3): Structural and bonding implications

International Nuclear Information System (INIS)

Gamble, F.R.; Silbernagel, B.G.

1975-01-01

The nature of the interaction responsible for the formation of molecular intercalation complexes between Lewis bases and layered transition metal dichalcogenides is not well understood. To some extent this is due to a lack of structural information. A prototype of these complexes is TaS 2 (NH 3 ), in which monolayers of ammonia are inserted between the metallic, superconducting layers of TaS 2 . The compound is crystalline and stoichiometric. Measurement of the anisotropy of the proton spin--lattice relaxation time at 300 degreeK indicates that the molecular threefold symmetry axis is not perpendicular to the disulfide layers as suggested by other workers, but is parallel to the layers. This orientation precludes direct interaction between the molecular lone pair orbital and the transition metal atoms. The interactions governing the structure of this complex may be similar to those obtaining in the intercalation complexes between TaS 2 and a number of substituted pyridines, in which complexes the axis of the lone pair orbital is also parallel to the layers

Model of coordination melting of crystals and anisotropy of physical and chemical properties of the surface

Science.gov (United States)

Bokarev, Valery P.; Krasnikov, Gennady Ya

2018-02-01

Based on the evaluation of the properties of crystals, such as surface energy and its anisotropy, the surface melting temperature, the anisotropy of the work function of the electron, and the anisotropy of adsorption, were shown the advantages of the model of coordination melting (MCM) in calculating the surface properties of crystals. The model of coordination melting makes it possible to calculate with an acceptable accuracy the specific surface energy of the crystals, the anisotropy of the surface energy, the habit of the natural crystals, the temperature of surface melting of the crystal, the anisotropy of the electron work function and the anisotropy of the adhesive properties of single-crystal surfaces. The advantage of our model is the simplicity of evaluating the surface properties of the crystal based on the data given in the reference literature. In this case, there is no need for a complex mathematical tool, which is used in calculations using quantum chemistry or modeling by molecular dynamics.

Influence of anisotropy effect and internal stresses upon the superconductive critical temperature of plastically deformed tin

International Nuclear Information System (INIS)

Wagner, D.; Stangler, F.

1976-01-01

The influence of plastic deformation on the superconductive critical temperature of tin single crystals has been investigated experimentally. It was shown by measurements that the lattice defects produced by plastic deformation lead to an anisotropy effect (according to the theory of Markowitz and Kadanoff), as do impurities in alloyed material. The decrease in T/sub c/ due to this effect can be measured, however, only with samples of certain special orientations. Samples with other orientations show an increase in T/sub c/, which can be explained by the assumption of internal stresses from dislocation pileups. A model is discussed which accounts for the measured rise in T/sub c/

Thermal effects and in-plane magnetic anisotropy in thin-film recording media

International Nuclear Information System (INIS)

Ajan, Antony; Abarra, E.N.; Acharya, B.R.; Inomata, A.; Okamoto, I.; Shinohara, M.

2003-01-01

The effect of thermal activation on the in-plane magnetic anisotropy [measured as orientation ratio (OR)] of granular longitudinal magnetic recording media is investigated. Temperature and time dependent studies were made on media with different magnetic layer thicknesses. We find that OR is independent of temperature for a stable medium but shows a large increase with temperature for thermally unstable media. At low temperatures and high field sweep rates, the OR values are found to be the same, independent of the magnetic layer thickness. The unique value when thermal activation is reduced is consistent with the high population of the cobalt c axes along the texturing direction as the origin of anisotropy

Magnetic anisotropy of nonmodulated Ni-Mn-Ga martensite revisited

Czech Academy of Sciences Publication Activity Database

Heczko, Oleg; Straka, L.; Novák, Václav; Fähler, S.

2010-01-01

Roč. 107, č. 9 (2010), 09A914/1-09A914/3 ISSN 0021-8979 Grant - others:AV ČR(CZ) M100100913 Institutional research plan: CEZ:AV0Z10100520 Keywords : magnetic anisotropy of non-modulated martensite * temperature dependence of anisotropy * Ni-Mn-Ga * adaptive martensite Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.064, year: 2010 http://jap.aip.org/resource/1/japiau/v107/i9/p09A914_s1

In Situ Solid-State Reactions Monitored by X-ray Absorption Spectroscopy: Temperature-Induced Proton Transfer Leads to Chemical Shifts.

Science.gov (United States)

Stevens, Joanna S; Walczak, Monika; Jaye, Cherno; Fischer, Daniel A

2016-10-24

The dramatic colour and phase alteration with the solid-state, temperature-dependent reaction between squaric acid and 4,4'-bipyridine has been probed in situ with X-ray absorption spectroscopy. The electronic and chemical sensitivity to the local atomic environment through chemical shifts in the near-edge X-ray absorption fine structure (NEXAFS) revealed proton transfer from the acid to the bipyridine base through the change in nitrogen protonation state in the high-temperature form. Direct detection of proton transfer coupled with structural analysis elucidates the nature of the solid-state process, with intermolecular proton transfer occurring along an acid-base chain followed by a domino effect to the subsequent acid-base chains, leading to the rapid migration along the length of the crystal. NEXAFS thereby conveys the ability to monitor the nature of solid-state chemical reactions in situ, without the need for a priori information or long-range order. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Fluxes of energetic protons and electrons measured on board the Oersted satellite

Directory of Open Access Journals (Sweden)

J. Cabrera

2005-11-01

Full Text Available The Charged Particle Detector (CPD on board the Oersted satellite (649 km perigee, 865 km apogee and 96.48° inclination currently measures energetic protons and electrons. The measured peak fluxes of E>1 MeV electrons are found to confirm the predictions of AE8-MAX, though they occur at a geographical position relatively shifted in the SAA. The fluxes of protons are one order of magnitude higher than the predictions of AP8-MAX in the energy range 20-500 MeV. This huge discrepancy between AP8 and recent measurements in LEO was already noticed and modelled in SAMPEX/PSB97 and TPM-1 models. Nevertheless some other LEO measurements such as PROBA and CORONA-F result in flux values in good agreement with AP8 within a factor 2. The anisotropy of the low-altitude proton flux, combined with measurement performed on board three-axis stabilised satellites, has been suspected to be one possible source of the important discrepancies observed by different missions. In this paper, we evaluate the effect of anisotropy on flux measurements conducted using the CPD instruments. On the basis of the available data, we confirm the inaccuracy of AP8 at LEO and suggest methods to improve the analysis of data in future flux measurements of energetic protons at low altitudes.

Measurement of the anisotropy ratios in MgB2 single crystals

International Nuclear Information System (INIS)

Kim, Heon-Jung; Kang, Byeongwon; Lee, Hyun-Sook; Lee, Sung-Ik

2006-01-01

We present our recent measurements on the anisotropy ratios of MgB 2 single crystals. Our measurements indicate that the anisotropy ratios of the penetration depth and of the upper critical field have different magnitudes and temperature dependences, as predicted by theoretical calculations. These results imply that the two-gap nature can strongly influence the superconducting properties of MgB 2

Regulation of ion drifts and anisotropies by parametrically unstable finite-amplitude Alfvén-cyclotron waves in the fast solar wind

Energy Technology Data Exchange (ETDEWEB)

Maneva, Y. G. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Araneda, J. A. [Departamento de Física, Universidad de Concepción, 4070386 (Chile); Marsch, E., E-mail: yana.g.maneva@nasa.gov [Institute for Experimental and Applied Physics, Christian Albrechts University at Kiel, D-24118 Kiel (Germany)

2014-03-10

We study the preferential heating and differential acceleration of minor ions by dissipation of ion-acoustic waves (IAWs) generated by parametric instabilities of a finite-amplitude monochromatic Alfvén-cyclotron pump wave. We consider the associated kinetic effects of Landau damping and nonlinear pitch-angle scattering of protons and α particles in the tenuous plasma of coronal holes and the fast solar wind. Various data collected by Wind spacecraft show signatures for a local transverse heating of the minor ions, presumably by Alfvén-cyclotron wave dissipation, and an unexpected parallel heating by a so far unknown mechanism. Here, we present the results from a set of 1.5 dimensional hybrid simulations in search for a plausible explanation for the observed field-aligned kinetic features in the fast solar wind minor ions. We investigate the origin and regulation of ion relative drifts and temperature anisotropies in low plasma β, fast solar wind conditions. Depending on their initial drifts, both ion species can heat up not only transversely through cyclotron resonance and non-resonant wave-particle interactions, but also strongly in the parallel direction by Landau damping of the daughter IAWs. We discuss the dependence of the relative ion drifts and temperature anisotropies on the plasma β of the individual species and we describe the effect of the pump wave amplitude on the ion heating and acceleration.

Magnetic anisotropy of ultrafine 316L stainless steel fibers

Energy Technology Data Exchange (ETDEWEB)

Shyr, Tien-Wei, E-mail: twshyr@fcu.edu.tw [Department of Fiber and Composite Materials, Feng Chia University, No. 100, Wenhwa Road, Seatwen, Taichung 40724, Taiwan, ROC (China); Huang, Shih-Ju [Department of Fiber and Composite Materials, Feng Chia University, No. 100, Wenhwa Road, Seatwen, Taichung 40724, Taiwan, ROC (China); Wur, Ching-Shuei [Department of Physics, National Cheng Kung University, No. 1, University Road, Tainan 70101, Taiwan, ROC (China)

2016-12-01

An as-received 316L stainless steel fiber with a diameter of 20 μm was drawn using a bundle drawing process at room temperature to form ultrafine stainless steel fibers with diameters of 12, 8, and 6 μm. The crystalline phases of the fibers were analyzed using the X-ray diffraction (XRD) profile fitting technique. The grain sizes of γ-austenite and α′-martensite were reduced to nanoscale sizes after the drawing process. XRD analysis and focused ion beam-scanning electron microscope observations showed that the newly formed α′-martensitic grains were closely arrayed in the drawing direction. The magnetic property was measured using a superconducting quantum interference device vibrating sample magnetometer. The magnetic anisotropy of the fibers was observed by applying a magnetic field parallel and perpendicular to the fiber axis. The results showed that the microstructure anisotropy including the shape anisotropy, magnetocrystalline anisotropy, and the orientation of the crystalline phases strongly contributed to the magnetic anisotropy. - Highlights: • The martensitic transformation of the 316L SS fiber occurred during the cold drawn. • The grain sizes of γ-austenite and α′-martensite were reduced to the nanoscale. • The newly formed martensitic grains were closely arrayed in the drawing direction. • The drawing process caused the magnetic easy axis to be aligned with the fiber axis. • The microstructure anisotropy strongly contributed to the magnetic anisotropy.

Spin-reorientation and anisotropy of the magnetization in single crystalline Ho2Co15Si2

International Nuclear Information System (INIS)

Tegus, O.

2000-01-01

We have studied the magnetic properties of a Ho 2 Co 15 Si 2 single crystal. The easy magnetization direction is parallel to the c-axis in an extended temperature region below the Curie temperature. A spin-reorientation transition takes place at 323 K, leading to an easy magnetization direction perpendicular to the c-axis below this temperature. We have compared the present results with those obtained previously on various R 2 Co 17 single crystals and found that Si substitution not only leads to a sign reversal in the Co sublattice anisotropy but also leads to a substantial anisotropy of the saturation magnetization. Sign and magnitude of the magnetization anisotropy are conserved during the spin-reorientation transition. (orig.)

Why do proton conducting polybenzimidazole phosphoric acid membranes perform well in high-temperature PEM fuel cells?

Science.gov (United States)

Melchior, Jan-Patrick; Majer, Günter; Kreuer, Klaus-Dieter

2016-12-21

Transport properties and hydration behavior of phosphoric acid/(benz)imidazole mixtures are investigated by diverse NMR techniques, thermogravimetric analysis (TGA) and conductivity measurements. The monomeric systems can serve as models for phosphoric acid/poly-benzimidazole membranes which are known for their exceptional performance in high temperature PEM fuel cells. 1 H- and 31 P-NMR data show benzimidazole acting as a strong Brønsted base with respect to neat phosphoric acid. Since benzimidazole's nitrogens are fully protonated with a low rate for proton exchange with phosphate species, proton diffusion and conduction processes must take place within the hydrogen bond network of phosphoric acid only. The proton exchange dynamics between phosphate and benzimidazole species pass through the intermediate exchange regime (with respect to NMR line separations) with exchange times being close to typical diffusion times chosen in PFG-NMR diffusion measurements (ms regime). The resulting effects, as described by the Kärger equation, are included into the evaluation of PFG-NMR data for obtaining precise proton diffusion coefficients. The highly reduced proton diffusion coefficient within the phosphoric acid part of the model systems compared to neat phosphoric acid is suggested to be the immediate consequence of proton subtraction from phosphoric acid. This reduces hydrogen bond network frustration (imbalance of the number of proton donors and acceptors) and therefore also the rate of structural proton diffusion, phosphoric acid's acidity and hygroscopicity. Reduced water uptake, shown by TGA, goes along with reduced electroosmotic water drag which is suggested to be the reason for PBI-phosphoric acid membranes performing better in fuel cells than other phosphoric-acid-containing electrolytes with higher protonic conductivity.

Anisotropy of the Mechanical Properties of TbF3 Crystals

Science.gov (United States)

Karimov, D. N.; Lisovenko, D. S.; Sizova, N. L.; Sobolev, B. P.

2018-01-01

TbF3 (sp. gr. Pnma) crystals up to 40 mm in diameter have been grown from melt by a Bridgman technique. The anisotropy of their mechanical properties is studied for the first time. the technical elasticity constants are calculated, and room-temperature values of Vickers microhardness for the (010) and (100) planes are measured. The shape of indentation impressions is found to correlate with Young's modulus anisotropy for TbF3 crystals.

Creep-induced anisotropy in covalent adaptable network polymers.

Science.gov (United States)

Hanzon, Drew W; He, Xu; Yang, Hua; Shi, Qian; Yu, Kai

2017-10-11

Anisotropic polymers with aligned macromolecule chains exhibit directional strengthening of mechanical and physical properties. However, manipulating the orientation of polymer chains in a fully cured thermoset is almost impossible due to its permanently crosslinked nature. In this paper, we demonstrate that rearrangeable networks with bond exchange reactions (BERs) can be utilized to tailor the anisotropic mechanical properties of thermosetting polymers. When a constant force is maintained at BER activated temperatures, the malleable thermoset creeps in the direction of stress, and macromolecule chains align themselves in the same direction. The aligned polymer chains result in an anisotropic network with a stiffer mechanical behavior in the direction of creep, while with a more compliant behavior in the transverse direction. The degree of network anisotropy is proportional to the amount of creep strain. A multi-length scale constitutive model is developed to study the creep-induced anisotropy of thermosetting polymers. The model connects the micro-scale BER kinetics, orientation of polymer chains, and directional mechanical properties of network polymers. Without any fitting parameters, it is able to predict the evolution of creep strain at different temperatures and anisotropic stress-strain behaviors of CANs after creep. Predictions on the chain orientation are verified by molecular dynamics (MD) simulation. Based on parametric studies, it is shown that the influences of creep time and temperature on the network anisotropy can be generalized into a single parameter, and the evolution of directional modulus follows an Arrhenius type time-temperature superposition principle (TTSP). The presented work provides a facile approach to transform isotropic thermosets into anisotropic ones using simple heating, and their directional properties can be readily tailored by the processing conditions.

Extracting foreground-obscured μ-distortion anisotropies to constrain primordial non-Gaussianity

Science.gov (United States)

Remazeilles, M.; Chluba, J.

2018-04-01

Correlations between cosmic microwave background (CMB) temperature, polarization and spectral distortion anisotropies can be used as a probe of primordial non-Gaussianity. Here, we perform a reconstruction of μ-distortion anisotropies in the presence of Galactic and extragalactic foregrounds, applying the so-called Constrained ILC component separation method to simulations of proposed CMB space missions (PIXIE, LiteBIRD, CORE, PICO). Our sky simulations include Galactic dust, Galactic synchrotron, Galactic free-free, thermal Sunyaev-Zeldovich effect, as well as primary CMB temperature and μ-distortion anisotropies, the latter being added as correlated field. The Constrained ILC method allows us to null the CMB temperature anisotropies in the reconstructed μ-map (and vice versa), in addition to mitigating the contaminations from astrophysical foregrounds and instrumental noise. We compute the cross-power spectrum between the reconstructed (CMB-free) μ-distortion map and the (μ-free) CMB temperature map, after foreground removal and component separation. Since the cross-power spectrum is proportional to the primordial non-Gaussianity parameter, fNL, on scales k˜eq 740 Mpc^{-1}, this allows us to derive fNL-detection limits for the aforementioned future CMB experiments. Our analysis shows that foregrounds degrade the theoretical detection limits (based mostly on instrumental noise) by more than one order of magnitude, with PICO standing the best chance at placing upper limits on scale-dependent non-Gaussianity. We also discuss the dependence of the constraints on the channel sensitivities and chosen bands. Like for B-mode polarization measurements, extended coverage at frequencies ν ≲ 40 GHz and ν ≳ 400 GHz provides more leverage than increased channel sensitivity.

Local Equation of State for Protons, and Implications for Proton Heating in the Solar Wind.

Science.gov (United States)

Zaslavsky, A.; Maksimovic, M.; Kasper, J. C.

2017-12-01

The solar wind protons temperature is observed to decrease with distance to the Sun at a slower rate than expected from an adiabatic expansion law: the protons are therefore said to be heated. This observation raises the question of the evaluation of the heating rate, and the question of the heat source.These questions have been investigated by previous authors by gathering proton data on various distances to the Sun, using spacecraft as Helios or Ulysses, and then computing the radial derivative of the proton temperature in order to obtain a heating rate from the internal energy equation. The problem of such an approach is the computation of the radial derivative of the temperature profile, for which uncertainties are very large, given the dispersion of the temperatures measured at a given distance.An alternative approach, that we develop in this paper, consists in looking for an equation of state that links locally the pressure (or temperature) to the mass density. If such a relation exists then one can evaluate the proton heating rate on a local basis, without having any space derivative to compute.Here we use several years of STEREO and WIND proton data to search for polytropic equation of state. We show that such relationships are indeed a good approximation in given solar wind's velocity intervals and deduce the associated protons heating rates as a function of solar wind's speed. The obtained heating rates are shown to scale from around 1 kW/kg in the slow wind to around 10 kW/kg in the fast wind, in remarkable agreement with the rate of energy observed by previous authors to cascade in solar wind's MHD turbulence at 1 AU. These results therefore support the idea of proton turbulent heating in the solar wind.

On the molecular anisotropy of liquid crystalline and flexible polymer systems

Science.gov (United States)

van Horn, Brett L.

The demand for products of ever increasing quality or for novel applications has required increasing attention to or manipulation of the anisotropy of manufactured parts. Oriented plastics are used everywhere from recording film to automotive body parts to monofilament fishing line. Liquid crystals are also used in a wide array of applications including their dominance in the flat panel display industry, color changing temperature sensors, and woven bullet resistant fabrics. Anisotropy can also be detrimental, for instance sometimes leading to poor fracture resistance or low yield stress along specific directions. Controlling and measuring anisotropy of materials has become increasingly important, but doing so is wrought with challenges. Measuring physical properties of isotropic liquids, such as water or most oils can be done in a straightforward fashion. Their viscosities and densities, for example, have unique values under a given set of conditions. With anisotropic fluids, like liquid crystals, the viscosity, for instance, will not only depend upon temperature, concentration, etc. but also upon the direction of observation, degree of anisotropy, source of anisotropy, and so forth. This added degree of complexity complicates our ability to define the state of the material at which the measurements are made and generally necessitates the use of more sophisticated measurement strategies or techniques. This work presents techniques and tools for investigating anisotropy in liquid crystalline and stretched polymeric systems. Included are the use of conoscopy for the determination of birefringence and orientation of nematic liquid crystals and stretched polymers, the shear response of flow aligning nematic liquid crystal monodomains, and the design of a novel linear rheometer that allows for in situ optical or scattering investigations.

On the Origin of the Large Magnetic Anisotropy of Rare Earth-Cobalt Compounds

DEFF Research Database (Denmark)

Szpunar, B.; Lindgård, Per-Anker

1979-01-01

Experimental data on the magnetocrystalline anisotropy in Co, YCo5, GdCo5, SmCo5 and Y2Co17 is analysed using a single-ion crystal field and isotropic exchange interaction. The large magnetic anisotropy at high temperatures in the alloys is due to significant deviations in the alloy lattices...

High-temperature and low-stress creep anisotropy of single-crystal superalloys

Czech Academy of Sciences Publication Activity Database

Jacome, L. A.; Nortershauser, P.; Heyer, J. K.; Lahni, A.; Frenzel, J.; Dlouhý, Antonín; Somsen, C.; Eggeler, G.

2013-01-01

Roč. 61, č. 8 (2013), s. 2926-2943 ISSN 1359-6454 R&D Projects: GA ČR(CZ) GA202/09/2073 Institutional support: RVO:68081723 Keywords : superalloy single crystals * creep anisotropy * rafting * dislocations * deformation mechanisms Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.940, year: 2013

Anisotropy-Driven Instability in Intense Charged Particle Beams

CERN Document Server

Startsev, Edward; Qin, Hong

2005-01-01

In electrically neutral plasmas with strongly anisotropic distribution functions, free energy is available to drive different collective instabilities such as the electrostatic Harris instability and the transverse electromagnetic Weibel instability. Such anisotropies develop naturally in particle accelerators and may lead to a detoriation of beam quality. We have generalized the analysis of the classical Harris and Weibel instabilities to the case of a one-component intense charged particle beam with anisotropic temperature including the important effects of finite transverse geometry and beam space-charge. For a long costing beam, the delta-f particle-in-cell code BEST and the eighenmode code bEASt have been used to determine detailed 3D stability properties over a wide range of temperature anisotropy and beam intensity. A theoretical model is developed which describes the essential features of the linear stage of these instabilities. Both, the simulations and analytical theory, clearly show that moderately...

Reorientational Dynamics of Enzymes Adsorbed on Quartz: A Temperature-Dependent Time-Resolved TIRF Anisotropy Study

Science.gov (United States)

Czeslik, C.; Royer, C.; Hazlett, T.; Mantulin, W.

2003-01-01

The preservation of enzyme activity and protein binding capacity upon protein adsorption at solid interfaces is important for biotechnological and medical applications. Because these properties are partly related to the protein flexibility and mobility, we have studied the internal dynamics and the whole-body reorientational rates of two enzymes, staphylococcal nuclease (SNase) and hen egg white lysozyme, over the temperature range of 20–80°C when the proteins are adsorbed at the silica/water interface and, for comparison, when they are dissolved in buffer. The data were obtained using a combination of two experimental techniques, total internal reflection fluorescence spectroscopy and time-resolved fluorescence anisotropy measurements in the frequency domain, with the protein Trp residues as intrinsic fluorescence probes. It has been found that the internal dynamics and the whole-body rotation of SNase and lysozyme are markedly reduced upon adsorption over large temperature ranges. At elevated temperatures, both protein molecules appear completely immobilized and the fractional amplitudes for the whole-body rotation, which are related to the order parameter for the local rotational freedom of the Trp residues, remain constant and do not approach zero. This behavior indicates that the angular range of the Trp reorientation within the adsorbed proteins is largely restricted even at high temperatures, in contrast to that of the dissolved proteins. The results of this study thus provide a deeper understanding of protein activity at solid surfaces. PMID:12668461

Synergy and destructive interferences between local magnetic anisotropies in binuclear complexes

Energy Technology Data Exchange (ETDEWEB)

Guihéry, Nathalie; Ruamps, Renaud [Laboratoire de Chimie et Physique Quantiques, UMR5625, University of Toulouse 3, Paul Sabatier, 118 route de Narbonne, 31062 Toulouse (France); Maurice, Rémi [SUBATECH, IN2P3/EMN Nantes/University of Nantes, 4 rue Alfred Kastler, BP 20722 44307, Nantes, Cedex 3 (France); Graaf, Coen de [University Rovira i Virgili, Marcelli Domingo s/n, 43007 Tarragona (Spain)

2015-12-31

Magnetic anisotropy is responsible for the single molecule magnet behavior of transition metal complexes. This behavior is characterized by a slow relaxation of the magnetization for low enough temperatures, and thus for a possible blocking of the magnetization. This bistable behavior can lead to possible technological applications in the domain of data storage or quantum computing. Therefore, the understanding of the microscopic origin of magnetic anisotropy has received a considerable interest during the last two decades. The presentation focuses on the determination of the anisotropy parameters of both mono-nuclear and bi-nuclear types of complexes and on the control and optimization of the anisotropic properties. The validity of the model Hamiltonians commonly used to characterize such complexes has been questioned and it is shown that neither the standard multispin Hamiltonian nor the giant spin Hamiltonian are appropriate for weakly coupled ions. Alternative models have been proposed and used to properly extract the relevant parameters. Rationalizations of the magnitude and nature of both local anisotropies of single ions and the molecular anisotropy of polynuclear complexes are provided. The synergy and interference effects between local magnetic anisotropies are studied in a series of binuclear complexes.

Tailoring of magnetic anisotropy of Fe-rich microwires by stress induced anisotropy

International Nuclear Information System (INIS)

Zhukov, A.; Zhukova, V.; Larin, V.; Gonzalez, J.

2006-01-01

We report on tailoring of magnetic properties and GMI of Fe 69 B 12 Si 14 C 5 glass-coated microwires by stress annealing. The induced magnetic anisotropy field depend on temperature and time of annealing and applied stress. At certain conditions considerable GMI effect (up to 65%) has been achieved. Application of the tensile stress drastically affects the shape of the hysteresis loop of stress-annealed sample and its GMI effect. In this way the shape of the hysteresis loop and GMI effect can by tailored by controllable way

Stress induced anisotropy in CoFeMn soft magnetic nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Leary, A. M., E-mail: leary@cmu.edu; Keylin, V.; McHenry, M. E. [Materials Science and Engineering Department, Carnegie Mellon University, 5000 Forbes Ave., Pittsburgh, Pennsylvania 15213 (United States); Ohodnicki, P. R. [Functional Materials Development Division, National Energy Technology Laboratory (NETL), 626 Cochrans Mill Road, Pittsburgh, Pennsylvania 15236 (United States)

2015-05-07

The use of processing techniques to create magnetic anisotropy in soft magnetic materials is a well-known method to control permeability and losses. In nanocomposite materials, field annealing below the Curie temperature results in uniaxial anisotropy energies up to ∼2 kJ/m{sup 3}. Higher anisotropies up to ∼10 kJ/m{sup 3} result after annealing Fe-Si compositions under stress due to residual stress in the amorphous matrix acting on body centered cubic crystals. This work describes near zero magnetostriction Co{sub 80−x−y}Fe{sub x}Mn{sub y}Nb{sub 4}B{sub 14}Si{sub 2} soft magnetic nanocomposites, where x and y < 8 at.% with close packed crystalline grains that show stress induced anisotropies up to ∼50 kJ/m{sup 3} and improved mechanical properties with respect to Fe-Si compositions. Difference patterns measured using transmission X-ray diffraction show evidence of affine strain with respect to the stress axis.

Temperature behavior and annealing of insulated gate transistors subjected to localized lifetime control by proton implantation

International Nuclear Information System (INIS)

Mogro-Campero, A.; Love, R.P.; Chang, M.F.; Dyer, R.F.

1987-01-01

Localized lifetime control by proton implantation can result in a considerable improvement (as much as an order of magnitude or more) in the trade-off between device turn-off time and forward voltage when compared with the unlocalized method of electron irradiation. The physical mechanisms responsible for the qualitative temperature dependences are identified: MOS channel resistance for forward voltage, carrier capture cross-section for turn-off time, and generation and diffusion components of leakage current. Since no catastrophic or unrecoverable behavior is observed, normal device operation within the tested temperature range is possible. Isothermal annealing curves of turn-off time measured after annealing, and corresponding to a few hours annealing time, reveal that a constant turn-off time is reached after about an hour. The constant value increases with temperature, but is still below the unimplanted value after 4 h at 525 0 C. The turn-off time was verified to be constant even after 24 h of annealing at 200 0 C. Lifetime control by proton implantation seems to be more thermally stable than that caused by electron irradiation. (author)

Analytical theory and nonlinear δf perturbative simulations of temperature anisotropy instability in intense charged particle beams

Directory of Open Access Journals (Sweden)

Edward A. Startsev

2003-08-01

Full Text Available In plasmas with strongly anisotropic distribution functions (T_{∥b}/T_{⊥b}≪1 a Harris-like collective instability may develop if there is sufficient coupling between the transverse and longitudinal degrees of freedom. Such anisotropies develop naturally in accelerators and may lead to a deterioration of beam quality. This paper extends previous numerical studies [E. A. Startsev, R. C. Davidson, and H. Qin, Phys. Plasmas 9, 3138 (2002] of the stability properties of intense non-neutral charged particle beams with large temperature anisotropy (T_{⊥b}≫T_{∥b} to allow for nonaxisymmetric perturbations with ∂/∂θ≠0. The most unstable modes are identified, and their eigenfrequencies, radial mode structure, and nonlinear dynamics are determined. The simulation results clearly show that moderately intense beams with s_{b}=ω[over ^]_{pb}^{2}/2γ_{b}^{2}ω_{β⊥}^{2}≳0.5 are linearly unstable to short-wavelength perturbations with k_{z}^{2}r_{b}^{2}≳1, provided the ratio of longitudinal and transverse temperatures is smaller than some threshold value. Here, ω[over ^]_{pb}^{2}=4πn[over ^]_{b}e_{b}^{2}/γ_{b}m_{b} is the relativistic plasma frequency squared, and ω_{β⊥} is the betatron frequency associated with the applied smooth-focusing field. A theoretical model is developed based on the Vlasov-Maxwell equations which describes the essential features of the linear stages of instability. Both the simulations and the analytical theory predict that the dipole mode (azimuthal mode number m=1 is the most unstable mode. In the nonlinear stage, tails develop in the longitudinal momentum distribution function, and the kinetic instability saturates due to resonant wave-particle interactions.

Anisotropies in the cosmic neutrino background after Wilkinson Microwave Anisotropy Probe five-year data

International Nuclear Information System (INIS)

De Bernardis, Francesco; Pagano, Luca; Melchiorri, Alessandro; Serra, Paolo; Cooray, Asantha

2008-01-01

We search for the presence of cosmological neutrino background (CNB) anisotropies in recent Wilkinson Microwave Anisotropy Probe (WMAP) five-year data using their signature imprinted on modifications to the cosmic microwave background (CMB) anisotropy power spectrum. By parameterizing the neutrino background anisotropies with the speed viscosity parameter c vis , we find that the WMAP five-year data alone provide only a weak indication for CNB anisotropies with c vis 2 >0.06 at the 95% confidence level. When we combine CMB anisotropy data with measurements of galaxy clustering, the SN-Ia Hubble diagram, and other cosmological information, the detection increases to c vis 2 >0.16 at the same 95% confidence level. Future data from Planck, combined with a weak lensing survey such as the one expected with DUNE from space, will be able to measure the CNB anisotropy parameter at about 10% accuracy. We discuss the degeneracy between neutrino background anisotropies and other cosmological parameters such as the number of effective neutrinos species and the dark energy equation of state

Structural and elastic anisotropy of crystals at high pressures and temperatures from quantum mechanical methods: The case of Mg{sub 2}SiO{sub 4} forsterite

Energy Technology Data Exchange (ETDEWEB)

Erba, A., E-mail: alessandro.erba@unito.it; Dovesi, R. [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy); Maul, J. [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy); Laboratório de Combustíveis e Materiais, INCTMN-UFPB, Universidade Federal da Paraíba, CEP 58051-900 João Pessoa, PB (Brazil); De La Pierre, M. [Nanochemistry Research Institute, Curtin Institute for Computation, Department of Chemistry, Curtin University, GPO Box U1987, Perth, WA 6845 (Australia)

2015-05-28

We report accurate ab initio theoretical predictions of the elastic, seismic, and structural anisotropy of the orthorhombic Mg{sub 2}SiO{sub 4} forsterite crystal at high pressures (up to 20 GPa) and temperatures (up to its melting point, 2163 K), which constitute earth’s upper mantle conditions. Single-crystal elastic stiffness constants are evaluated up to 20 GPa and their first- and second-order pressure derivatives reported. Christoffel’s equation is solved at several pressures: directional seismic wave velocities and related properties (azimuthal and polarization seismic anisotropies) discussed. Thermal structural and average elastic properties, as computed within the quasi-harmonic approximation of the lattice potential, are predicted at high pressures and temperatures: directional thermal expansion coefficients, first- and second-order pressure derivatives of the isothermal bulk modulus, and P-V-T equation-of-state. The effect on computed properties of five different functionals, belonging to three different classes of approximations, of the density functional theory is explicitly investigated.

Higher-order anisotropies in the blast-wave model: Disentangling flow and density field anisotropies

Energy Technology Data Exchange (ETDEWEB)

Cimerman, Jakub [Czech Technical University in Prague, FNSPE, Prague (Czech Republic); Comenius University, FMPI, Bratislava (Slovakia); Tomasik, Boris [Czech Technical University in Prague, FNSPE, Prague (Czech Republic); Univerzita Mateja Bela, FPV, Banska Bystrica (Slovakia); Csanad, Mate; Loekoes, Sandor [Eoetvoes Lorand University, Budapest (Hungary)

2017-08-15

We formulate a generalisation of the blast-wave model which is suitable for the description of higher-order azimuthal anisotropies of the hadron production. The model includes anisotropy in the density profile as well as an anisotropy in the transverse expansion velocity field. We then study how these two kinds of anisotropies influence the single-particle distributions and the correlation radii of two-particle correlation functions. Particularly we focus on the third-order anisotropy and consideration is given averaging over different orientations of the event plane. (orig.)

In Situ Neutron Diffraction of Rare-Earth Phosphate Proton Conductors Sr/Ca-doped LaPO4 at Elevated Temperatures

Science.gov (United States)

Al-Wahish, Amal; Al-Binni, Usama; Bridges, C. A.; Huq, A.; Bi, Z.; Paranthaman, M. P.; Tang, S.; Kaiser, H.; Mandrus, D.

Acceptor-doped lanthanum orthophosphates are potential candidate electrolytes for proton ceramic fuel cells. We combined neutron powder diffraction (NPD) at elevated temperatures up to 800° C , X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) to investigate the crystal structure, defect structure, thermal stability and surface topography. NPD shows an average bond length distortion in the hydrated samples. We employed Quasi-Elastic Neutron Scattering (QENS) and electrochemical impedance spectroscopy (EIS) to study the proton dynamics of the rare-earth phosphate proton conductors 4.2% Sr/Ca-doped LaPO4. We determined the bulk diffusion and the self-diffusion coefficients. Our results show that QENS and EIS are probing fundamentally different proton diffusion processes. Supported by the U.S. Department of Energy.

Spin waves in terbium. III. Magnetic anisotropy at zero wave vector

DEFF Research Database (Denmark)

Houmann, Jens Christian Gylden; Jensen, J.; Touborg, P.

1975-01-01

The energy gap at zero wave vector in the spin-wave dispersion relation of ferromagnetic. Tb has been studied by inelastic neutron scattering. The energy was measured as a function of temperature and applied magnetic field, and the dynamic anisotropy parameters were deduced from the results...... the effects of zero-point deviations from the fully aligned ground state, and we tentatively propose polarization-dependent two-ion couplings as their origin........ The axial anisotropy is found to depend sensitively on the orientation of the magnetic moments in the basal plane. This behavior is shown to be a convincing indication of considerable two-ion contributions to the magnetic anisotropy at zero wave vector. With the exception of the sixfold basal...

Coasting characteristic of the flywheel system under anisotropy effect of bulk high temperature superconductors

Science.gov (United States)

Wu, J. F.; Li, Y.

2014-10-01

High-temperature superconductors (HTSCs) array with aligned growth section boundary (GSB) pattern (AGSBP) exhibits larger levitation force and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP) has been studied in maglev train application (Zheng et al., 2013). This result maybe helpful and support a new way for the HTS bearing design for flywheel systems. So, in this paper, we further examine this growth anisotropy effect on the maglev performance of flywheel system. Levitation force and coasting time were investigated from the point-view of HTS flywheel applications. The GS/GSB alignment of AGSBP bulk HTSCs produces larger levitation force than that of MGSBP, but the coasting time is shorter than that of MGSBP, that is to say, the electric magnetic drag force with AGSBP is larger than that of MGSBP. This result may also exist in the maglev guideline when the maglev train stops freely.

Growth anisotropy effect of bulk high temperature superconductors on the levitation performance in the applied magnetic field

International Nuclear Information System (INIS)

Zheng, J.; Liao, X.L.; Jing, H.L.; Deng, Z.G.; Yen, F.; Wang, S.Y.; Wang, J.S.

2013-01-01

Highlights: • The single-layer bulk HTSC with AGSBP obtains better levitation performance than that of MGSBP. • The double-layer bulk with AGSBP obtains better levitation performance than that of MGSBP too. • The double-layer bulk finding is contrast to MGSBP if pursuing high trapped field. • The optimization is highlighted by simple and easy operation, thus economical in the practice. -- Abstract: Growth anisotropies of bulk high temperature superconductors (HTSCs) fabricated by a top-seeded melt texture growth process, that is, different pinning effect in the growth sectors (GSs) and growth sector boundaries (GSBs), possess effect on the macro flux trapping and levitation performance of bulk HTSCs. Previous work (Physics Procedia, 36 (2012) 1043) has found that the bulk HTSC array with aligned GSB pattern (AGSBP) exhibits better capability for levitation and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP). In this paper, we further examine this growth anisotropy effect on the maglev performance of a double-layer bulk HTSC. In contrast to reported trapped flux cases (Supercond. Sci. Technol. 19 (2006) S466), the two superposed bulk HTSCs with same AGSBP with PMG are found to show better maglev performance. These series of results are helpful and support a new way for the performance optimization of present HTS maglev systems

Room-temperature superparamagnetism due to giant magnetic anisotropy in Mo S defected single-layer MoS2

Science.gov (United States)

Khan, M. A.; Leuenberger, Michael N.

2018-04-01

Room-temperature superparamagnetism due to a large magnetic anisotropy energy (MAE) of a single atom magnet has always been a prerequisite for nanoscale magnetic devices. Realization of two dimensional (2D) materials such as single-layer (SL) MoS2, has provided new platforms for exploring magnetic effects, which is important for both fundamental research and for industrial applications. Here, we use density functional theory (DFT) to show that the antisite defect (Mo S ) in SL MoS2 is magnetic in nature with a magnetic moment μ of  ∼2 μB and, remarkably, exhibits an exceptionally large atomic scale MAE =\\varepsilon\\parallel-\\varepsilon\\perp of  ∼500 meV. Our calculations reveal that this giant anisotropy is the joint effect of strong crystal field and significant spin–orbit coupling (SOC). In addition, the magnetic moment μ can be tuned between 1 μB and 3 μB by varying the Fermi energy \\varepsilonF , which can be achieved either by changing the gate voltage or by chemical doping. We also show that MAE can be raised to  ∼1 eV with n-type doping of the MoS2:Mo S sample. Our systematic investigations deepen our understanding of spin-related phenomena in SL MoS2 and could provide a route to nanoscale spintronic devices.

Growth anisotropy effect of bulk high temperature superconductors on the levitation performance in the applied magnetic field

Energy Technology Data Exchange (ETDEWEB)

Zheng, J., E-mail: jzheng@swjtu.edu.cn; Liao, X.L.; Jing, H.L.; Deng, Z.G.; Yen, F.; Wang, S.Y.; Wang, J.S.

2013-10-15

Highlights: • The single-layer bulk HTSC with AGSBP obtains better levitation performance than that of MGSBP. • The double-layer bulk with AGSBP obtains better levitation performance than that of MGSBP too. • The double-layer bulk finding is contrast to MGSBP if pursuing high trapped field. • The optimization is highlighted by simple and easy operation, thus economical in the practice. -- Abstract: Growth anisotropies of bulk high temperature superconductors (HTSCs) fabricated by a top-seeded melt texture growth process, that is, different pinning effect in the growth sectors (GSs) and growth sector boundaries (GSBs), possess effect on the macro flux trapping and levitation performance of bulk HTSCs. Previous work (Physics Procedia, 36 (2012) 1043) has found that the bulk HTSC array with aligned GSB pattern (AGSBP) exhibits better capability for levitation and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP). In this paper, we further examine this growth anisotropy effect on the maglev performance of a double-layer bulk HTSC. In contrast to reported trapped flux cases (Supercond. Sci. Technol. 19 (2006) S466), the two superposed bulk HTSCs with same AGSBP with PMG are found to show better maglev performance. These series of results are helpful and support a new way for the performance optimization of present HTS maglev systems.

Anisotropy in highly charged ion induced molecule fragmentation

International Nuclear Information System (INIS)

Juhasz, Z.; Sulik, B.; Fremont, F.; Chesnel, J.Y.; Hajaji, A.

2006-01-01

Complete text of publication follows. Studying fragmentation processes of biologically relevant molecules due to highly charged ion impact is important to understand radiation damage in biological tissues. Energy spectra of the charged molecule fragments may reveal the different fragmentation patterns meanwhile the angular distributions of the fragments characterize the dependence of fragmentation probability on the initial orientation of the molecule. The research to explore the angular distribution of the molecule fragments has only recently been started[1]. In 2006 we performed measurements at ARIBE facility at GANIL, Caen (France), in order to investigate orientation effects in molecule fragmentation. Fragmentation of H 2 O, C 6 H 6 and CH 4 , which represent different level of symmetry, have been studied by 60 keV N 6+ ion impact. Energy spectra of the charged fragments at different observation angles have been taken. As our example spectra show the different protonic peaks can be attributed to different fragmentation processes. Significant anisotropy can be seen in the different processes. The strongest evidence for the anisotropy can be seen in the spectra of C 6 H 6 , where the spectra appear isotropic in almost the whole observed energy range except one peak, which has a strong angular dependence and is maximal around 90 deg. (author)

Influence of anisotropy and pinning centers on critical current properties in Bi-2212 superconductors

International Nuclear Information System (INIS)

Haraguchi, T.; Takayama, S.; Kiuchi, M.; Otabe, E.S.; Matsushita, T.; Yasuda, T.; Okayasu, S.; Uchida, S.; Shimoyama, J.; Kishio, K.

2006-01-01

The critical current density in Bi-2212 superconductors with various anisotropies irradiated by heavy ions was investigated in the medium temperature region to understand the effects of defect size and the anisotropy of the superconductor. It was found that the critical current density and the irreversibility field were larger for the specimen with larger defect and/or with smaller anisotropy. Introduction of stronger pinning centers and the optimization of the doping condition to improve the dimensionality are desired for further improvement of the critical current properties

T=0 phase diagram and nature of domains in ultrathin ferromagnetic films with perpendicular anisotropy

International Nuclear Information System (INIS)

Pighin, Santiago A.; Billoni, Orlando V.; Stariolo, Daniel A.; Cannas, Sergio A.

2010-01-01

We present the complete zero temperature phase diagram of a model for ultrathin films with perpendicular anisotropy. The whole parameter space of relevant coupling constants is studied in first order anisotropy approximation. Because the ground state is known to be formed by perpendicular stripes separated by Bloch walls, a standard variational approach is used, complemented with specially designed Monte Carlo simulations. We can distinguish four regimes according to the different nature of striped domains: a high anisotropy Ising regime with sharp domain walls, a saturated stripe regime with thicker walls inside which an in-plane component of the magnetization develops, a narrow canted-like regime, characterized by a sinusoidal variation of both the in-plane and the out of plane magnetization components, which upon further decrease of the anisotropy leads to an in-plane ferromagnetic state via a spin reorientation transition (SRT). The nature of domains and walls are described in some detail together with the variation of domain width with anisotropy, for any value of exchange and dipolar interactions. Our results, although strictly valid at T=0, can be valuable for interpreting data on the evolution of domain width at finite temperature, a still largely open problem.

Evolution of anisotropy in bcc Fe distorted by interstitial boron

Science.gov (United States)

Gölden, Dominik; Zhang, Hongbin; Radulov, Iliya; Dirba, Imants; Komissinskiy, Philipp; Hildebrandt, Erwin; Alff, Lambert

2018-01-01

The evolution of magnetic anisotropy in bcc Fe as a function of interstitial boron atoms was investigated in thin films grown by molecular beam epitaxy. The thermodynamic nonequilibrium conditions during film growth allowed one to stabilize an interstitial boron content of about 14 at .% accompanied by lattice tetragonalization. The c /a ratio scaled linearly with the boron content up to a maximum value of 1.05 at 300 °C substrate growth temperature, with a room-temperature magnetization of. In contrast to nitrogen interstitials, the magnetic easy axis remained in-plane with an anisotropy of approximately -5.1 ×106erg /cm3 . Density functional theory calculations using the measured lattice parameters confirm this value and show that boron local ordering indeed favors in-plane magnetization. Given the increased temperature stability of boron interstitials as compared to nitrogen interstitials, this study will help to find possible ways to manipulate boron interstitials into a more favorable local order.

Wave and particle evolution downstream of quasi-perpendicular shocks

Science.gov (United States)

Mckean, M. E.; Omidi, N.; Krauss-Varban, D.; Karimabadi, H.

1995-01-01

Distributions of ions heated in quasi-perpendicular bow shocks have large perpendicular temperature anisotropies that provide free energy for the growth of Alfven ion cyclotron (AIC) and mirror waves. These modes are often obsreved in the Earth's magnetosheath. Using two-dimensional hybrid simulations, we show that these waves are produced near the shock front and convected downstream rather than being produced locally downstream. The wave activity reduces the proton anisotropy to magnetosheath levels within a few tens of gyroradii of the shock but takes significantly longer to reduce the anisotropy of He(++) ions. The waves are primarily driven by proton anisotropy and the dynamics of the helium ions is controlled by the proton waves. Downstream of high Mach number shocks, mirror waves compete effectively with AIC waves. Downstream of low Mach number shocks, AIC waves dominate.

Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells

International Nuclear Information System (INIS)

Kim, Jintae; Kim, Minjin; Kang, Taegon; Sohn, Young-Jun; Song, Taewon; Choi, Kyoung Hwan

2014-01-01

High-temperature PEMFCs (proton exchange membrane fuel cells) using PA (phosphoric acid)-doped PBI (polybenzimidazole) membranes have received attention as a potential solution to several of the issues with traditional low-temperature PEMFCs. However, the durability of high-temperature PEMFCs deteriorates rapidly with increasing temperature, although its performance improves. This characteristic makes it difficult to select the proper operating temperature to achieve its target lifetime. In this paper, to resolve this problem, models were developed to predict the performance and durability of the high-temperature PEMFC as a function of operating temperature. The optimal operating temperature was then determined for a variety of lifetimes. Theoretical model to estimate cell performance and empirical model to predict the degradation rate of cell performance were constructed, respectively. The prediction results of the developed models agreed well with the experimental data. From the simulation, we could obtain higher average cell performances by optimizing the operating temperature for the given target lifetime compared to the cell performance at some temperatures determined using an existing rule of thumb. It is expected that the proposed methodologies will lead to the more rapid commercialization of this technology in such applications as stationary and automotive fuel cell systems. - Highlights: • High-temperature PEMFCs (proton exchange membrane fuel cells). • Operational optimization for improving the lifetime. • Development of the degradation modeling for high-temperature PEMFCs

An estimator for statistical anisotropy from the CMB bispectrum

International Nuclear Information System (INIS)

Bartolo, N.; Dimastrogiovanni, E.; Matarrese, S.; Liguori, M.; Riotto, A.

2012-01-01

Various data analyses of the Cosmic Microwave Background (CMB) provide observational hints of statistical isotropy breaking. Some of these features can be studied within the framework of primordial vector fields in inflationary theories which generally display some level of statistical anisotropy both in the power spectrum and in higher-order correlation functions. Motivated by these observations and the recent theoretical developments in the study of primordial vector fields, we develop the formalism necessary to extract statistical anisotropy information from the three-point function of the CMB temperature anisotropy. We employ a simplified vector field model and parametrize the bispectrum of curvature fluctuations in such a way that all the information about statistical anisotropy is encoded in some parameters λ LM (which measure the anisotropic to the isotropic bispectrum amplitudes). For such a template bispectrum, we compute an optimal estimator for λ LM and the expected signal-to-noise ratio. We estimate that, for f NL ≅ 30, an experiment like Planck can be sensitive to a ratio of the anisotropic to the isotropic amplitudes of the bispectrum as small as 10%. Our results are complementary to the information coming from a power spectrum analysis and particularly relevant for those models where statistical anisotropy turns out to be suppressed in the power spectrum but not negligible in the bispectrum

Manipulating magnetic anisotropy of the ultrathin Co2FeAl full-Heusler alloy film via growth orientation of the Pt buffer layer

International Nuclear Information System (INIS)

Wen, F.S.; Xiang, J.Y.; Hao, C.X.; Zhang, F.; Lv, Y.F.; Wang, W.H.; Hu, W.T.; Liu, Z.Y.

2013-01-01

The ultrathin films of Co 2 FeAl (CFA) full-Heusler alloy were prepared between two Pt layers on MgO single crystals by magnetron sputtering. By controlling the substrate temperature, different growth orientations of the Pt underlayers were realized, and their effects were investigated on the magnetic anisotropy of the ultrathin CFA film. It was revealed that different Pt orientations lead to distinctly different magnetic anisotropy for the sandwiched ultrathin CFA films. The Pt (111) orientation favors the perpendicular anisotropy, while the appearance of partial Pt (001) orientation leads to the quick decrease of perpendicular anisotropy and the complete Pt (001) orientation gives rise to the in-plane anisotropy. With the Pt (111) orientation, the temperature and thickness-induced spin reorientation transitions were investigated in the sandwiched ultrathin CFA films. - Highlights: • Different Pt orientations lead to different magnetic anisotropy for sandwiched ultrathin CFA films. • The Pt (111) orientation favors the perpendicular anisotropy for CFA layer. • Temperature and thickness-induced spin reorientation transitions were investigated in sandwiched ultrathin CFA films. • 0.8 nm CFA film is good candidate as electrode in magnetic tunnel junctions

A SEARCH FOR CONCENTRIC CIRCLES IN THE 7 YEAR WILKINSON MICROWAVE ANISOTROPY PROBE TEMPERATURE SKY MAPS

International Nuclear Information System (INIS)

Wehus, I. K.; Eriksen, H. K.

2011-01-01

In this Letter, we search for concentric circles with low variance in cosmic microwave background sky maps. The detection of such circles would hint at new physics beyond the current cosmological concordance model, which states that the universe is isotropic and homogeneous, and filled with Gaussian fluctuations. We first describe a set of methods designed to detect such circles, based on matched filters and χ 2 statistics, and then apply these methods to the best current publicly available data, the 7 year Wilkinson Microwave Anisotropy Probe (WMAP) temperature sky maps. We compare the observations with an ensemble of 1000 Gaussian ΛCDM simulations. Based on these tests, we conclude that the WMAP sky maps are fully compatible with the Gaussian and isotropic hypothesis as measured by low-variance ring statistics.

Optical and mechanical anisotropy of oxide glass fibers

DEFF Research Database (Denmark)

Deubener, J.; Yue, Yuanzheng

2012-01-01

products [1], whereas stretching (frozen-in strain) results in optical and mechanical anisotropy of glass fibers, which is quantified inter alia by the specific birefringence [2]. The paper will stress the later effects by combining previous results on the structural origins of birefringence...... and anisotropic shrinkage in silica and phosphate fibers with recent studies on relaxation of optical anisotropy in E-glass fibers [3,4].......Upon fiber drawing, glass forming oxide melts are thermally quenched and mechanically stretched. High cooling rates (up to 106 K/min) of quenched glass fibres lead to higher enthalpy state of liquids, thereby, to higher fictive temperature than regular quenching (e.g. 20 K/min) of bulk glass...

Relaxation dynamics and transformation kinetics of deeply supercooled water: Temperature, pressure, doping, and proton/deuteron isotope effects.

Science.gov (United States)

Lemke, Sonja; Handle, Philip H; Plaga, Lucie J; Stern, Josef N; Seidl, Markus; Fuentes-Landete, Violeta; Amann-Winkel, Katrin; Köster, Karsten W; Gainaru, Catalin; Loerting, Thomas; Böhmer, Roland

2017-07-21

Above its glass transition, the equilibrated high-density amorphous ice (HDA) transforms to the low-density pendant (LDA). The temperature dependence of the transformation is monitored at ambient pressure using dielectric spectroscopy and at elevated pressures using dilatometry. It is found that near the glass transition temperature of deuterated samples, the transformation kinetics is 300 times slower than the structural relaxation, while for protonated samples, the time scale separation is at least 30 000 and insensitive to doping. The kinetics of the HDA to LDA transformation lacks a proton/deuteron isotope effect, revealing that this process is dominated by the restructuring of the oxygen network. The x-ray diffraction experiments performed on samples at intermediate transition stages reflect a linear combination of the LDA and HDA patterns implying a macroscopic phase separation, instead of a local intermixing of the two amorphous states.

Relaxation dynamics and transformation kinetics of deeply supercooled water: Temperature, pressure, doping, and proton/deuteron isotope effects

Science.gov (United States)

Lemke, Sonja; Handle, Philip H.; Plaga, Lucie J.; Stern, Josef N.; Seidl, Markus; Fuentes-Landete, Violeta; Amann-Winkel, Katrin; Köster, Karsten W.; Gainaru, Catalin; Loerting, Thomas; Böhmer, Roland

2017-07-01

Above its glass transition, the equilibrated high-density amorphous ice (HDA) transforms to the low-density pendant (LDA). The temperature dependence of the transformation is monitored at ambient pressure using dielectric spectroscopy and at elevated pressures using dilatometry. It is found that near the glass transition temperature of deuterated samples, the transformation kinetics is 300 times slower than the structural relaxation, while for protonated samples, the time scale separation is at least 30 000 and insensitive to doping. The kinetics of the HDA to LDA transformation lacks a proton/deuteron isotope effect, revealing that this process is dominated by the restructuring of the oxygen network. The x-ray diffraction experiments performed on samples at intermediate transition stages reflect a linear combination of the LDA and HDA patterns implying a macroscopic phase separation, instead of a local intermixing of the two amorphous states.

Investigations of the temperature distribution in proton exchange membrane fuel cells

International Nuclear Information System (INIS)

Jung, Chi-Young; Shim, Hyo-Sub; Koo, Sang-Man; Lee, Sang-Hwan; Yi, Sung-Chul

2012-01-01

A two-dimensional, non-isothermal model of a proton exchange membrane fuel cell was implemented to elucidate heat balance through the membrane electrode assembly (MEA). To take local utilization of platinum catalyst into account, the model was presented by considering the formation of agglomerated catalyst structure in the electrodes. To estimate energy balance through the MEA, various modes of heat generation and depletion by reversible/irreversible heat release, ohmic heating and phase change of water were included in the present model. In addition, dual-pathway kinetics, that is a combination of Heyrovsky–Volmer and Tafel–Volmer kinetics, were employed to precisely describe the hydrogen oxidation reaction. The proposed model was validated with experimental cell polarization, resulting in excellent fit. The temperature distribution inside the MEA was analyzed by the model. Consequently, a thorough investigation was made of the relation between membrane thickness and the temperature distribution inside the MEA.

Effects of proton irradiation and temperature on 1 ohm-cm and 10 ohm-cm silicon solar cells

Science.gov (United States)

Nicoletta, C. A.

1973-01-01

The 1 ohm-cm and 10 ohm-cm silicon solar cells were exposed to 1.0 MeV protons at a fixed flux of 10 to the 9th power P/sq cm-sec and fluences of 10 to the 10th power, 10 to the 11th power, 10 to the 12th power and 3 X 10 to the 12th power P/sq cm. I-V curves of the cells were made at room temperature, 65 C and 165 C after each irradiation. A value of 139.5 mw/sq cm was taken as AMO incident energy rate per unit area. Degradation occurred for both uncovered 1 ohm-cm and 10 ohm-cm cells. Efficiencies are generally higher than those of comparable U.S. cells tested earlier. Damage (loss in maximum power efficiency) with proton fluence is somewhat higher for 10 ohm-cm cells, measured at the three temperatures, for fluences above 2 X 10 to the 11th power P/sq cm. Cell efficiency, as expected, changes drastically with temperature.

Size-dependent magnetic anisotropy of PEG coated Fe3O4 nanoparticles; comparing two magnetization methods

Science.gov (United States)

Nayek, C.; Manna, K.; Imam, A. A.; Alqasrawi, A. Y.; Obaidat, I. M.

2018-02-01

Understanding the size dependent magnetic anisotropy of iron oxide nanoparticles is essential for the successful application of these nanoparticles in several technological and medical fields. PEG-coated iron oxide (Fe3O4) nanoparticles with core diameters of 12 nm, 15 nm, and 16 nm were synthesized by the usual co-precipitation method. The morphology and structure of the nanoparticles were investigated using transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), and X-ray diffraction (XRD). Magnetic measurements were conducted using a SQUID. The effective magnetic anisotropy was calculated using two methods from the magnetization measurements. In the first method the zero-field-cooled magnetization versus temperature measurements were used at several applied magnetic fields. In the second method we used the temperature-dependent coercivity curves obtained from the zero-field-cooled magnetization versus magnetic field hysteresis loops. The role of the applied magnetic field on the effective magnetic anisotropy, calculated form the zero-field-cooled magnetization versus temperature measurements, was revealed. The size dependence of the effective magnetic anisotropy constant Keff obtained by the two methods are compared and discussed.

Influence of the interface on the magnetic properties of NiZn ferrite thin films treated by proton irradiation

Energy Technology Data Exchange (ETDEWEB)

Jiang, X.D. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000 (China); Guo, D.W. [Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000 (China); Zhang, C.H., E-mail: c.h.zhang@impcas.ac.cn [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Fan, X.L.; Chai, G.Z. [Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000 (China); Xue, D.S., E-mail: xueds@lzu.edu.cn [Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000 (China)

2015-09-01

In order to systematically investigate the influence of the interface on the magnetic properties, polycrystalline NiZn ferrite thin films were irradiated with 60 keV proton in the dose range from 5 × 10{sup 12} to 5 × 10{sup 16} ions/cm{sup 2}. A non-destructive approach by proton irradiation was found to finely adjust the magnetic properties of polycrystalline NiZn ferrite thin films such as coercivity, perpendicular magnetic anisotropy as well as the effective g value. The coercivity is about 725 Oe for high proton dose ferrite, which is twice larger than the unirradiated one. The ferromagnetic resonance measurements indicated that perpendicular magnetic anisotropy and the effective g value increase with the irradiation dose. Our finding indicates that all modifications of these magnetic properties were associated with the change of interface due to the diffusion and the stress induced by proton irradiation. The change of the effective g value is a result of lattice expansion and the decrease of the magnetic dipole interaction between the columnar grains. This work provides a feasible way to tailor the magnetic properties of thin films by ion irradiation and promotes investigations for the stability of magnetic thin film devices in space or unclear radiation environments.

Tamper temperature and compression from simultaneous proton and alpha-particle measurements in laser fusion experiments

International Nuclear Information System (INIS)

Cover, R.A.; Kubis, J.J.; Mayer, F.J.; Slater, D.C.

1978-01-01

The energy loss per unit path length for a charged particle incident on a spatially uniform isothermal Maxwellian plasma is a function of the temperature and density of the medium. Within this model the temperature and compression rhoΔr of the tamper of a laser-driven microshell target can be accurately determined, in the absence of electrostatic acceleration, by the simultaneous measurement of the energy loss from 3.52-MeV α particles from D-T reactions and 3.02-MeV protons from D-D reactions

Manipulating magnetic anisotropy of the ultrathin Co{sub 2}FeAl full-Heusler alloy film via growth orientation of the Pt buffer layer

Energy Technology Data Exchange (ETDEWEB)

Wen, F.S., E-mail: wenfsh03@126.com [State Key Lab of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Xiang, J.Y.; Hao, C.X.; Zhang, F.; Lv, Y.F. [State Key Lab of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Wang, W.H. [Institute of Physics, Chinese Academy of Science, Beijing 100080 (China); Hu, W.T.; Liu, Z.Y. [State Key Lab of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China)

2013-12-15

The ultrathin films of Co{sub 2}FeAl (CFA) full-Heusler alloy were prepared between two Pt layers on MgO single crystals by magnetron sputtering. By controlling the substrate temperature, different growth orientations of the Pt underlayers were realized, and their effects were investigated on the magnetic anisotropy of the ultrathin CFA film. It was revealed that different Pt orientations lead to distinctly different magnetic anisotropy for the sandwiched ultrathin CFA films. The Pt (111) orientation favors the perpendicular anisotropy, while the appearance of partial Pt (001) orientation leads to the quick decrease of perpendicular anisotropy and the complete Pt (001) orientation gives rise to the in-plane anisotropy. With the Pt (111) orientation, the temperature and thickness-induced spin reorientation transitions were investigated in the sandwiched ultrathin CFA films. - Highlights: • Different Pt orientations lead to different magnetic anisotropy for sandwiched ultrathin CFA films. • The Pt (111) orientation favors the perpendicular anisotropy for CFA layer. • Temperature and thickness-induced spin reorientation transitions were investigated in sandwiched ultrathin CFA films. • 0.8 nm CFA film is good candidate as electrode in magnetic tunnel junctions.

Electrical resistivity anisotropy of osmium single crystals in the range 4,2 to 300 K

International Nuclear Information System (INIS)

Volkenshtejn, N.V.; Dyakina, V.P.; Dyakin, V.V.; Startsev, V.E.; Cherepanov, V.I.; Azhazha, V.M.; Kovtun, G.P.; Elenskij, V.A.; AN Ukrainskoj SSR, Kharkov. Fiziko-Tekhnicheskij Inst.)

1981-01-01

Electrical resistivity and size effect anisotropies of pure osmium single crystals with rhosub(273.2/rhosub(4.2)2600 were investigated in the temperature range 4.2 to 300 K. It is found that the electrical resistivity anisotropy (αT)=rhosub( )/rhosub( ) is less than unit and has a maximum at T approximately 50 K; the size effect anisotropy (rho1)sub( )/(rho1)sub( ) is 0.39+-0.07 at T=4.2 K; at liquid helium temperature, the dependence of thin samples is controlled by the scattering of conduction electrons by the surface of the sample. The results are discussed for the specific shape of the Fermi surface geometry of osmium with an account for the scattering processes of conduction electrons by phonons and by surface of the sample

Magnetic anisotropy in (Ga,Mn)As: Influence of epitaxial strain and hole concentration

Science.gov (United States)

Glunk, M.; Daeubler, J.; Dreher, L.; Schwaiger, S.; Schoch, W.; Sauer, R.; Limmer, W.; Brandlmaier, A.; Goennenwein, S. T. B.; Bihler, C.; Brandt, M. S.

2009-05-01

We present a systematic study on the influence of epitaxial strain and hole concentration on the magnetic anisotropy in (Ga,Mn)As at 4.2 K. The strain was gradually varied over a wide range from tensile to compressive by growing a series of (Ga,Mn)As layers with 5% Mn on relaxed graded (In,Ga)As/GaAs templates with different In concentration. The hole density, the Curie temperature, and the relaxed lattice constant of the as-grown and annealed (Ga,Mn)As layers turned out to be essentially unaffected by the strain. Angle-dependent magnetotransport measurements performed at different magnetic-field strengths were used to probe the magnetic anisotropy. The measurements reveal a pronounced linear dependence of the uniaxial out-of-plane anisotropy on both strain and hole density. Whereas the uniaxial and cubic in-plane anisotropies are nearly constant, the cubic out-of-plane anisotropy changes sign when the magnetic easy axis flips from in-plane to out-of-plane. The experimental results for the magnetic anisotropy are quantitatively compared with calculations of the free energy based on a mean-field Zener model. Almost perfect agreement between experiment and theory is found for the uniaxial out-of-plane and cubic in-plane anisotropy parameters of the as-grown samples. In addition, magnetostriction constants are derived from the anisotropy data.

Proton conductance at elevated temperature:Formulation and investigation of poly(4-styrenesulfonic acid / 4-aminobenzylamine / phosphoric acid membranes

Directory of Open Access Journals (Sweden)

Jalal eJalili

2014-07-01

Full Text Available 4-aminobenzylamine and phosphoric acid were blended in various proportions with poly (4-styrenesulfonic acid to form a new group of membranes exhibiting proton conductance under water-free conditions. The 4-aminobenzylamine molecule, possessing an aniline-like and benzylamine-like functional group, can interact both with the phosphoric acid and the poly(4-styrenesulfonic acid via nucleophilic interaction, thereby allowing proton jumping in the structure. Physico-chemical and thermal characteristics of the prepared solid membranes were investigated by IR spectroscopy and thermo-gravimetric analysis, respectively. Electrochemical impedance spectroscopy was employed to investigate their proton-conductance properties. Transparent composite membranes were prepared. However, the membranes are opaque for relatively high content of phosphoric acid. These membranes are thermally stable up to 300°C. The proton conductivity increases with temperature and also with content of phosphoric acid. Values as high as 1.8×10–3 S cm–1 were measured at 190°C in fully anhydrous condition.

Research on anisotropy of fusion-produced protons and neutrons emission from high-current plasma-focus discharges

Energy Technology Data Exchange (ETDEWEB)

Malinowski, K., E-mail: karol.malinowski@ncbj.gov.pl; Sadowski, M. J.; Szydlowski, A. [National Centre for Nuclear Research (NCBJ), 05-400 Otwock (Poland); Institute of Plasma Physics and Laser Microfusion (IFPiLM), 01-497 Warsaw (Poland); Skladnik-Sadowska, E.; Czaus, K.; Kwiatkowski, R.; Zaloga, D. [National Centre for Nuclear Research (NCBJ), 05-400 Otwock (Poland); Paduch, M.; Zielinska, E. [Institute of Plasma Physics and Laser Microfusion (IFPiLM), 01-497 Warsaw (Poland)

2015-01-15

The paper concerns fast protons and neutrons from D-D fusion reactions in a Plasma-Focus-1000U facility. Measurements were performed with nuclear-track detectors arranged in “sandwiches” of an Al-foil and two PM-355 detectors separated by a polyethylene-plate. The Al-foil eliminated all primary deuterons, but was penetrable for fast fusion protons. The foil and first PM-355 detector were penetrable for fast neutrons, which were converted into recoil-protons in the polyethylene and recorded in the second PM-355 detector. The “sandwiches” were irradiated by discharges of comparable neutron-yields. Analyses of etched tracks and computer simulations of the fusion-products behavior in the detectors were performed.

Mechanical-property changes of structural composite materials after low-temperature proton irradiation: Implications for use in SSC magnet systems

International Nuclear Information System (INIS)

Morena, J.; Snead, C.L. Jr.; Czajkowski, C.; Skaritka, J.

1993-01-01

Longterm physical, mechanical, electrical, and other properties of advanced composites, plastics, and other polymer materials are greatly affected by high-energy proton, neutron, electron, and gamma radiation. The effects of high-energy particles on materials is a critical design parameter to consider when choosing polymeric structural, nonstructural, and elastomeric matrix resin systems. Polymer materials used for filled resins, laminates, seals, gaskets, coatings, insulation and other nonmetallic components must be chosen carefully, and reference data viewed with caution. Most reference data collected in the high-energy physics community to date reflects material property degradation using other than proton irradiations. In most instances, the data were collected for room-temperature irradiations, not 4.2 K or other cryogenic temperatures, and at doses less than 10 8 --10 9 Rad. Energetic proton (and the accompanying spallation-product particles) provide good simulation fidelity to the expected radiation fields predicted for the cold-mass regions of the SSC magnets, especially the corrector magnets. The authors present here results for some structural composite materials which were part of a larger irradiation-characterization of polymeric materials for SSC applications

Magnetic anisotropy of some R2CO17 compounds

International Nuclear Information System (INIS)

Khan, W.I.; Melville, D.

1978-01-01

The singular-point detection technique, in which the second derivative of the magnetization with respect to field is examined, has been used to determine the anisotropy field Bsub(A) = (2/Msub(s)) (K 1 + 2K 2 ) for Sm 2 Co 17 , Er 2 Co 17 , and Tm 2 Co 17 over the temperature range 77 - 300 K. Exrapolation of the initial part of the hard-direction magnetization curve for aligned powders enables K 1 and K 2 to be estimated. For Er 2 Co 17 and Tm 2 Co 17 the rare-earth (R) and cobalt sublattices are oppositely aligned, so that the onset of ordering of the R sublattice leads to a decrease in saturation magnetization as the temperature is lowered. This is in sharp contrast to the rapid increase in K 1 at low temperatures. By subtracting the corresponding Msub(s) values from that of Y 2 Co 17 the temperature dependence of the R sublattice can be determined. It is found that K 1 is directly proportional to the cube of this quantity, indicating the dominance of the rare-earth sublattice in determining the anisotropic properties of these compounds. For Sm 2 Co 17 the anisotropy constant varies very strongly with the reduced magnetization. (author)

Late time CMB anisotropies constrain mini-charged particles

Energy Technology Data Exchange (ETDEWEB)

Burrage, C.; Redondo, J.; Ringwald, A. [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Jaeckel, J. [Univ. of Durham, Inst. for Particle Physics Phenomenology (United Kingdom)

2009-09-15

Observations of the temperature anisotropies induced as light from the CMB passes through large scale structures in the late universe are a sensitive probe of the interactions of photons in such environments. In extensions of the Standard Model which give rise to mini-charged particles, photons propagating through transverse magnetic fields can be lost to pair production of such particles. Such a decrement in the photon flux would occur as photons from the CMB traverse the magnetic fields of galaxy clusters. Therefore late time CMB anisotropies can be used to constrain the properties of mini- charged particles. We outline how this test is constructed, and present new constraints on mini-charged particles from observations of the Sunyaev-Zel'dovich effect in the Coma cluster. (orig.)

Polarimetric study of the optical anisotropy of polymers

International Nuclear Information System (INIS)

Sinyavsky, N; Korneva, I

2017-01-01

This paper presents the results of an optical anisotropy study of a polymer film and the effect of temperature on birefringence. A method using a polariscope for the quantitative determination of the optical path difference is offered. The research findings are useful to students of physical and engineering specialities studying electromagnetic theory and optics. The described experiments and theoretical approaches are based on prominent aspects of modern optics. This work can be used to teach students the methods of polarimetry, the method of measuring optical anisotropy, and the basics of colorimetry. Students will learn a color description system to demonstrate the interference of polarized light, as well as being able to make a comparison between the numerical simulation and experiment of the interference pattern. (paper)

Search for anisotropy in the Debye-Waller factor of HCP solid 4He

Science.gov (United States)

Barnes, Ashleigh L.; Hinde, Robert J.

2016-02-01

The properties of hexagonal close packed (hcp) solid 4He are dominated by large atomic zero point motions. An accurate description of these motions is therefore necessary in order to accurately calculate the properties of the system, such as the Debye-Waller (DW) factors. A recent neutron scattering experiment reported significant anisotropy in the in-plane and out-of-plane DW factors for hcp solid 4He at low temperatures, where thermal effects are negligible and only zero-point motions are expected to contribute. By contrast, no such anisotropy was observed either in earlier experiments or in path integral Monte Carlo (PIMC) simulations of solid hcp 4He. However, the earlier experiments and the PIMC simulations were both carried out at higher temperatures where thermal effects could be substantial. We seek to understand the cause of this discrepancy through variational quantum Monte Carlo simulations utilizing an accurate pair potential and a modified trial wavefunction which allows for anisotropy. Near the melting density, we find no anisotropy in an ideal hcp 4He crystal. A theoretical equation of state is derived from the calculated energies of the ideal crystal over a range of molar volumes from 7.88 to 21.3 cm3, and is found to be in good qualitative agreement with experimental data.

Relative thermoluminescent efficiencies proton/gamma and helium/gamma of peaks of high temperature in TLD-100 dosemeters

International Nuclear Information System (INIS)

Flores M, E.

2007-01-01

The increase of the applications of ion beams in radiotherapy treatments has generated interest in the study of the thermoluminescent materials (TL) that allow to determine the applied doses. A way to quantify the TL response from these materials to ions is by means of the relative thermoluminescent efficiency. In the group of Thermoluminescent dosimetry of the Institute of Physics of the UNAM (IFUNAM) the thermoluminescent response of the TLD-100 dosemeters has been studied, which present a glow curve characteristic with several peaks that correspond to traps and luminescent centers in the material. The stable peaks know each other as 4, 5, 6a, 6b, 7, 8, 9 and 10. The efficiencies should be measured using the response so much to the radiation of interest (in this case protons and helium ions) as the response to gamma radiation. In previous works with ions of low energy taken place in the Pelletron accelerator of the IFUNAM was only measured the TL efficiency for the peak 5 and the total signal. It had not been possible to measure the efficiency of the peaks of high temperature (6a-10) because, for the gamma radiation, the peaks of high temperature show very small signals; however, recently Massillon carries out measures of efficiency TL of peaks of high temperature for ions of intermediate energy using a protocol special of reading and of deconvolution that allows to measure the signals coming from the peaks of high temperature. In this work is implemented this same protocol to complete the study of TL efficiencies at low energy of protons and helium and to determine if the values of efficiency depend on the used reading protocol. For it is reported it measures of the relative efficiency of the peaks of high temperature from the TLD-100 exposed to protons of 1.5 MeV and nuclei of helium of 3 and 7.5 MeV. (Author)

Hc2 of anisotropy two-band superconductors by Ginzburg-Landau approach

International Nuclear Information System (INIS)

Udomsamuthirun, P.; Changjan, A.; Kumvongsa, C.; Yoksan, S.

2006-01-01

The purpose of this research is to study the upper critical field H c2 of two-band superconductors by two-band Ginzburg-Landau approach. The analytical formula of H c2 included anisotropy of order parameter and anisotropy of effective-mass are found. The parameters of the upper critical field in ab-plane (H c2 - bar ab ) and c-axis (H c2 - bar c ) can be found by fitting to the experimental data. Finally, we can find the ratio of upper critical field that temperature dependent in the range of experimental result

Magnetic anisotropy of (Sm, Y)2Fe17Ny compounds

International Nuclear Information System (INIS)

Lu, Y.; Tegus, O.; Li, Q.A.; Tang, N.; Yu, M.J.; Zhao, R.W.; Kuang, J.P.; Yang, F.M.; Zhou, G.F.; Li, X.; Boer, F.R. de

1992-01-01

A study of the crystal structure and the magnetic properties, especially the magnetocrystalline anisotropy of (Sm 1-x Y x ) 2 Fe 17 N y compounds (x = 0, 0.2, 0.4, 0.6, 0.8, and 1.0, 2 2 Zn 17 - or Th 2 Ni 17 -type structure as the original compounds. The Curie temperatures decrease from 750 to 700 K as x increases from 0 to 1. The anisotropy field decreases linearly with increasing yttrium content. The spin reorientation has been investigated by means of high field magnetization measurements, AC-susceptibility measurements and thermomagnetic analysis, combined with X-ray diffraction. The anisotropy constants K 1 , K 2 and K 3 were derived by a phenomenological analysis, using magnetization curves measured in high fields, applied perpendicular to the alignment direction of the powder samples. A tentative spin phase diagram of the series is presented. (orig.)

Temperature dependence of (+)-catechin pyran ring proton coupling constants as measured by NMR and modeled using GMMX search methodology

Science.gov (United States)

Fred L. Tobiason; Stephen S. Kelley; M. Mark Midland; Richard W. Hemingway

1997-01-01

The pyran ring proton coupling constants for (+)-catechin have been experimentally determined in deuterated methanol over a temperature range of 213 K to 313 K. The experimental coupling constants were simulated to 0.04 Hz on the average at a 90 percent confidence limit using a LAOCOON method. The temperature dependence of the coupling constants was reproduced from the...

Study of the energetic proton production in relativistic heavy ions Ne + nuclei collisions, using Diogene detector. Hadronic matter temperature

International Nuclear Information System (INIS)

Rahmani, A.

1988-12-01

The study of the proton's production differential cross sections, in the collision of relativistic heavy ions, allows to obtain the nuclear-matter temperature and gives information about the nucleons large burst pulses in the nucleus. The chosen thermodynamic model is a generalized approach of the R. Hagedorn model, applied to heavy ions collisions: the nuclear matter is divided in volume elements δV assumed to be in thermal and chemical equilibrium and emitting particles and fragments isotropically, inside their own system. The applied nuclear-matter velocity distribution depended only on the impact parameter and on the relationship between the chemical potential and the temperature. The predictions of this thermodynamic model were compared to the Saturne experimental results, using Diogene detector. The obtained temperature values are similar to those given by D. Hahn and H. Stoker. The proton production cross sections were measured for backward emitting angles. A relationship between the cross sections and the burst pulse distribution in the nuclei was settled [fr

Influence of magnetic anisotropy on the superferromagnetic ordering in nanocomposites

DEFF Research Database (Denmark)

Mørup, Steen; Christiansen, Gunnar Dan

1993-01-01

Magnetic interaction between ultrafine particles may result in superferromagnetism, i.e., ordering of the magnetic moments of particles which would be superparamagnetic if they were noninteracting. In this article we discuss the influence of the magnetic anisotropy on the temperature dependence o...

High proton polarization at high temperature with single crystals of aromatic molecules

International Nuclear Information System (INIS)

Iinuma, M.; Takahashi, Y.; Shake, I.; Oda, M.; Masaike, A.; Yabuzaki, T.; Shimizu, H.M.

2004-01-01

Protons in single crystals of naphthalene doped with pentacene and p-terphenyl doped with pentacene have been polarized up to 32% and 18%, respectively. Such polarization has been achieved at liquid nitrogen temperature in a magnetic field of 3 kG by means of microwave-induced optical nuclear polarization. We also measured the polarization by the neutron transmission method. The relaxation time at 77 K in 7 G was found to be about 3 h and the enhancement of the obtained polarization compared with thermal polarization reached 8x10 4 . This method is applicable to neutron experiments

Determination of anisotropy constants of protein encapsulated iron oxide nanoparticles by electron magnetic resonance

International Nuclear Information System (INIS)

Li Hongyan; Klem, Michael T.; Sebby, Karl B.; Singel, David J.; Young, Mark; Douglas, Trevor; Idzerda, Yves U.

2009-01-01

Angle-dependent electron magnetic resonance was performed on 4.9, 8.0, and 19 nm iron oxide nanoparticles encapsulated within protein capsids and suspended in water. Measurements were taken at liquid nitrogen temperature after cooling in a 1 T field to partially align the particles. The angle dependence of the shifts in the resonance field for the iron oxide nanoparticles (synthesized within Listeria-Dps, horse spleen ferritin, and cowpea chlorotic mottle virus) all show evidence of a uniaxial anisotropy. Using a Boltzmann distribution for the particles' easy-axis direction, we are able to use the resonance field shifts to extract a value for the anisotropy energy, showing that the anisotropy energy density increases with decreasing particle size. This suggests that surface anisotropy plays a significant role in magnetic nanoparticles of this size

Determination of anisotropy constants of protein encapsulated iron oxide nanoparticles by electron magnetic resonance

Energy Technology Data Exchange (ETDEWEB)

Li Hongyan [Department of Physics, Montana State University, Bozeman, MT 59717 (United States); Center for Bio-Inspired Nanomaterials, Montana State University, Bozeman, MT 59717 (United States); Klem, Michael T.; Sebby, Karl B.; Singel, David J. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States); Center for Bio-Inspired Nanomaterials, Montana State University, Bozeman, MT 59717 (United States); Young, Mark [Department of Plant Sciences and Plant Pathology, Montana State University, Bozeman, MT 59717 (United States); Center for Bio-Inspired Nanomaterials, Montana State University, Bozeman, MT 59717 (United States); Douglas, Trevor [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States); Center for Bio-Inspired Nanomaterials, Montana State University, Bozeman, MT 59717 (United States); Idzerda, Yves U. [Department of Physics, Montana State University, Bozeman, MT 59717 (United States); Center for Bio-Inspired Nanomaterials, Montana State University, Bozeman, MT 59717 (United States)], E-mail: Idzerda@montana.edu

2009-02-15

Angle-dependent electron magnetic resonance was performed on 4.9, 8.0, and 19 nm iron oxide nanoparticles encapsulated within protein capsids and suspended in water. Measurements were taken at liquid nitrogen temperature after cooling in a 1 T field to partially align the particles. The angle dependence of the shifts in the resonance field for the iron oxide nanoparticles (synthesized within Listeria-Dps, horse spleen ferritin, and cowpea chlorotic mottle virus) all show evidence of a uniaxial anisotropy. Using a Boltzmann distribution for the particles' easy-axis direction, we are able to use the resonance field shifts to extract a value for the anisotropy energy, showing that the anisotropy energy density increases with decreasing particle size. This suggests that surface anisotropy plays a significant role in magnetic nanoparticles of this size.

Solid state protonic conductors II for fuel cells and sensors. Proceedings of the European workshop on solid state materials for low to medium temperature fuel cells and monitors, with special emphasis on proton conductors

Energy Technology Data Exchange (ETDEWEB)

Goodenough, J B; Jensen, J; Kleitz, M [eds.

1983-01-01

Solid electrolytes for chemical sensing, energy storage and conversion have been actively researched and developed since the early sixties. The zirconia fuel-cell electrolyser, the sodium-sulphur rechargeable battery, the oxygen sensor and lithium batteries can all be cited as significant developments from the field. Although of great potential the solid protonic conductors have somehow been ignored by comparison to the great interest that has been shown in, e.g., the lithium conductors. The long absence of any good, stable protonic conductors could easily explain this. The presence of water in the protonic conductors eliminates the possibility of high-temperature preparation and hence of conventional ceramic processing. Since solid electrolytes are used as dense ceramic membranes, difficulties with the fabrication of protonic electrilytes has been a strong disincentive. However, techniques have been developed for fabricating dense composite membranes; these contain free, but immobilized water that is lost at relatively low temperatures. Framework hydrates hold their water to higher temperatures. Although low-temperature ion-exchange preparations are possible, they yield weak ceramics. Nevertheless, their support on strong substrates, as reported in this conference, may provide an alternate way forward. A second workshop was organised on this theme at Hindsgavl Castle, Denmark, 1982. The aim was to compare the progress made in laboratories in Denmark, France and U.K. and also to review present and and future applications of fuel cells in a broader sense. Thirty scientists and representatives from the Commission of the European Communities, European Space Agency and the Daish Ministry of Energy participated. The proceedings cover all the papers of the workshop and the main comments and suggestions proposed during the discussions.

Measuring the cosmological lepton asymmetry through the CMB anisotropy

CERN Document Server

Kinney, W H; Kinney, William H.; Riotto, Antonio

1999-01-01

A large lepton asymmetry in the Universe is still a viable possibility and leads to many interesting phenomena such as gauge symmetry nonrestoration at high temperature. We show that a large lepton asymmetry changes the predicted cosmic microwave background (CMB) anisotropy and that any degeneracy in the relic neutrino sea will be measured to a precision of 1% or better when the CMB anisotropy is measured at the accuracy expected to result from the planned satellite missions MAP and Planck. In fact, the current measurements already put an upper limit on the lepton asymmetry of the Universe which is stronger than the one coming from considerations of primordial nucleosynthesis and structure formation.

Protonation of pyridine. Vol. 2

Energy Technology Data Exchange (ETDEWEB)

Zahran, N F; Ghoniem, H; Helal, A I [Physics Dept., Nuclear Research Center, AEA., Cairo, (Egypt); Rasheed, N [Nuclear Material Authority, Cairo, (Egypt)

1996-03-01

Field ionization mass spectra of pyridine is measured using 10{mu}m activated wire. protonation of pyridine, is observed as an intense peak in the mass spectra. Charge distribution of pyridine molecule is calculated using the modified neglect of diatomic overlap (MNDO) technique, and consequently proton attachment is proposed to be on the nitrogen atom. Temperature dependence of (M+H){sup +} ion is investigated and discussed. MNDO calculations of the protonated species are done, and the proton affinity of pyridine molecule is estimated. Time dependence of the field ionization process of pyridine and protonated ions are observed and discussed. 5 figs.

Doping phosphoric acid in polybenzimidazole membranes for high temperature proton exchange membrane fuel cells

DEFF Research Database (Denmark)

He, Ronghuan; Li, Qingfeng; Jensen, Jens Oluf

2007-01-01

Polybenzimidazole (PBI) membranes were doped in phosphoric acid solutions of different concentrations at room temperature. The doping chemistry was studied using the Scatchard method. The energy distribution of the acid complexation in polymer membranes is heterogeneous, that is, there are two...... different types of sites in PBI for the acid doping. The protonation constants of PBI by phosphoric acid are found to be 12.7 L mol(-1) (K-1) for acid complexing sites with higher affinity, and 0.19 L mol(-1) (K-2) for the sites with lower affinity. The dissociation constants for the complexing acid onto...... these two types of PBI sites are found to be 5.4 X 10(-4) and 3.6 X 10(-2), respectively, that is, about 10 times smaller than that of aqueous phosphoric acid in the first case but 5 times higher in the second. The proton conducting mechanism is also discussed....

Effect of microstructural anisotropy on the mechanical properties of K-doped tungsten rods for plasma facing components

Energy Technology Data Exchange (ETDEWEB)

Nogami, Shuhei, E-mail: shuhei.nogami@qse.tohoku.ac.jp; Guan, Wenhai, E-mail: wenhai.guan@jupiter.qse.tohoku.ac.jp; Fukuda, Makoto, E-mail: fukuda@jupiter.qse.tohoku.ac.jp; Hasegawa, Akira, E-mail: akira.hasegawa@qse.tohoku.ac.jp

2016-11-01

Highlights: • K-doping led to improve the tensile strength regardless of the test direction and temperature. • K-doping did not alter the elongation regardless of the test direction in the ductile fracture temperature range. • The ductility at lower temperature range was improved by the K-doping. • The lowest temperature of ductile fracture along both axial and radial directions decreased because of K-doping. • K-doping could suppress the influence of microstructural anisotropy on tensile properties, especially ductility, in large diameter W rods. - Abstract: The effect of microstructural anisotropy in pure tungsten (W) and potassium (K) doped W rods (20 mm in diameter) on their mechanical properties was investigated by tensile tests along the axial and radial directions at temperatures from 473 K to 1573 K and fracture analysis. K-doping led to improved tensile strength regardless of the test direction and temperature. K-doping did not alter the elongation regardless of the test direction in the temperature range showing ductile fracture. The ductility at lower temperature range was improved by the K-doping, especially in tensile tests along the radial direction. The lowest temperature of ductile fracture along both axial and radial directions decreased from 1373 K to 973 K because of K-doping. Thus, K-doping could suppress the influence of microstructural anisotropy on tensile properties, especially ductility, in large diameter W rods.

Higher-order anisotropies in the Buda-Lund model: Disentangling flow and density field anisotropies

Energy Technology Data Exchange (ETDEWEB)

Loekoes, Sandor [Eoetvoes Lorand University, Budapest (Hungary); Csanad, Mate [Eoetvoes Lorand University, Budapest (Hungary); Stony Brook University, Stony Brook, NY (United States); Tomasik, Boris [Univerzita Mateja Bela, Banska Bystrica (Slovakia); Czech Technical University in Prague, FNSPE, Prague (Czech Republic); Csoergo, Tamas [Wigner RCP, Budapest (Hungary); KRF, Gyoengyoes (Hungary)

2016-10-15

The Buda-Lund hydro model describes an expanding ellipsoidal fireball, and fits the observed elliptic flow and oscillating HBT radii successfully. Due to fluctuations in energy depositions, the fireball shape however fluctuates on an event-by-event basis. The transverse plane asymmetry can be translated into a series of multipole anisotropy coefficients. These anisotropies then result in measurable momentum-space anisotropies, to be measured with respect to their respective symmetry planes. In this paper we detail an extension of the Buda-Lund model to multipole anisotropies and investigate the resulting flow coefficients and oscillations of HBT radii. (orig.)

Influence of process variables on permeability and anisotropy of Biso-coated HTGR fuel particles

International Nuclear Information System (INIS)

Stinton, D.P.; Lackey, W.J.; Thiele, B.A.

1977-11-01

The effect of several important process variables on the fraction of defective particles and anisotropy of the low-temperature isotropic (LTI) coating layer was determined for Biso-coated HTGR fuel particles. Process variables considered are deposition temperature, hydrocarbon type, diluent type, and percent diluent. The effect of several other variables such as coating rate and density that depend on the process variables were also considered in this analysis. The fraction of defective particles was controlled by the dependent variables coating rate and LTI density. Coating rate was also the variable controlling the anisotropy of the LTI layer. Diluent type and diluent concentration had only a small influence on the deposition rate of the LTI layer. High-quality particles in terms of anisotropy and permeability can be produced by use of a porous plate gas distributor if the coating rate is between 3 and 5 μm/min and the coating density is between about 1.75 and 1.95 g/cm 3

A phenomenological approach to study the effect of uniaxial anisotropy on the magnetization of ferromagnetic nanoparticles

Science.gov (United States)

Sánchez-Marín, N.; Cuchillo, A.; Knobel, M.; Vargas, P.

2018-04-01

We study the effect of the uniaxial anisotropy in a system of ideal, noninteracting ferromagnetic nanoparticles by means of a thermodynamical model. We show that the effect of the anisotropy can be easily assimilated in a temperature shift Ta∗, in analogy to what was proposed by Allia et al. (2001) in the case of interacting nanomagnets. The phenomenological anisotropic Ta∗ parameter can be negative, indicating an antiferromagnetic-like behavior, or positive, indicating a ferromagnetic-like character as seen in the inverse susceptibility behavior as a function of temperature. The study is done considering an easy axis distribution to take into account the anisotropy axis dispersion in real samples (texture). In the case of a volumetric uniform distribution of anisotropy axes, the net effect makes Ta∗ to vanish, and the magnetic susceptibility behaves like a conventional superparamagnetic system, whereas in the others a finite value is obtained for Ta∗ . When magnetic moment distribution is considered, the effect is to enhance the Ta∗ parameter, when the dispersion of the magnetic moments becomes wider.

Moving protons with pendant amines: proton mobility in a nickel catalyst for oxidation of hydrogen.

Science.gov (United States)

O'Hagan, Molly; Shaw, Wendy J; Raugei, Simone; Chen, Shentan; Yang, Jenny Y; Kilgore, Uriah J; DuBois, Daniel L; Bullock, R Morris

2011-09-14

Proton transport is ubiquitous in chemical and biological processes, including the reduction of dioxygen to water, the reduction of CO(2) to formate, and the production/oxidation of hydrogen. In this work we describe intramolecular proton transfer between Ni and positioned pendant amines for the hydrogen oxidation electrocatalyst [Ni(P(Cy)(2)N(Bn)(2)H)(2)](2+) (P(Cy)(2)N(Bn)(2) = 1,5-dibenzyl-3,7-dicyclohexyl-1,5-diaza-3,7-diphosphacyclooctane). Rate constants are determined by variable-temperature one-dimensional NMR techniques and two-dimensional EXSY experiments. Computational studies provide insight into the details of the proton movement and energetics of these complexes. Intramolecular proton exchange processes are observed for two of the three experimentally observable isomers of the doubly protonated Ni(0) complex, [Ni(P(Cy)(2)N(Bn)(2)H)(2)](2+), which have N-H bonds but no Ni-H bonds. For these two isomers, with pendant amines positioned endo to the Ni, the rate constants for proton exchange range from 10(4) to 10(5) s(-1) at 25 °C, depending on isomer and solvent. No exchange is observed for protons on pendant amines positioned exo to the Ni. Analysis of the exchange as a function of temperature provides a barrier for proton exchange of ΔG(‡) = 11-12 kcal/mol for both isomers, with little dependence on solvent. Density functional theory calculations and molecular dynamics simulations support the experimental observations, suggesting metal-mediated intramolecular proton transfers between nitrogen atoms, with chair-to-boat isomerizations as the rate-limiting steps. Because of the fast rate of proton movement, this catalyst may be considered a metal center surrounded by a cloud of exchanging protons. The high intramolecular proton mobility provides information directly pertinent to the ability of pendant amines to accelerate proton transfers during catalysis of hydrogen oxidation. These results may also have broader implications for proton movement in

Indium doped niobium phosphates as intermediate temperature proton conductors

DEFF Research Database (Denmark)

Huang, Yunjie; Li, Qingfeng; Anfimova, Tatiana

2013-01-01

contributed to the anhydrous proton conductivity. The Nb0.9In0.1 phosphate exhibited a proton conductivity of five times higher than that of the un-doped analog at 250 °C. The conductivity was stabilized at a level of above 0.02 S cm−1 under dry atmosphere at 250 °C during the stability evaluation for 3 days....

Uniaxial anisotropy in magnetite thin film-Magnetization studies

International Nuclear Information System (INIS)

Wiechec, A.; Korecki, J.; Handke, B.; Kakol, Z.; Owoc, D.; Antolak, D.A.; Kozlowski, A.

2006-01-01

Magnetization and electrical resistivity measurements have been performed on a stoichiometric single crystalline magnetite Fe 3 O 4 thin film (thickness of ca. 500 nm) MBE deposited on MgO (1 0 0) substrate. The aim of these studies was to check the influence of preparation method and sample form (bulk vs. thin film) on magnetic anisotropy properties in magnetite. The film magnetization along versus applied magnetic field has been determined both in the direction parallel and perpendicular to the film surface, and at temperatures above and below the Verwey transition. We have found, in agreement with published results, that the in-plane field of 10 kOe was not sufficient to saturate the sample. This can be understood if some additional factor, on top of the bulk magnetocrystalline anisotropy, is taken into account

Discovery of ferromagnetism with large magnetic anisotropy in ZrMnP and HfMnP

Energy Technology Data Exchange (ETDEWEB)

Lamichhane, Tej N.; Taufour, Valentin; Kaluarachchi, Udhara S.; Bud' ko, Sergey L.; Canfield, Paul C. [Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); The Ames Laboratory, US Department of Energy, Iowa State University, Ames, Iowa 50011 (United States); Masters, Morgan W. [Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Parker, David S. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Thimmaiah, Srinivasa [The Ames Laboratory, US Department of Energy, Iowa State University, Ames, Iowa 50011 (United States)

2016-08-29

ZrMnP and HfMnP single crystals are grown by a self-flux growth technique, and structural as well as temperature dependent magnetic and transport properties are studied. Both compounds have an orthorhombic crystal structure. ZrMnP and HfMnP are ferromagnetic with Curie temperatures around 370 K and 320 K, respectively. The spontaneous magnetizations of ZrMnP and HfMnP are determined to be 1.9 μ{sub B}/f.u. and 2.1 μ{sub B}/f.u., respectively, at 50 K. The magnetocaloric effect of ZrMnP in terms of entropy change (ΔS) is estimated to be −6.7 kJ m{sup −3} K{sup −1} around 369 K. The easy axis of magnetization is [100] for both compounds, with a small anisotropy relative to the [010] axis. At 50 K, the anisotropy field along the [001] axis is ∼4.6 T for ZrMnP and ∼10 T for HfMnP. Such large magnetic anisotropy is remarkable considering the absence of rare-earth elements in these compounds. The first principle calculation correctly predicts the magnetization and hard axis orientation for both compounds, and predicts the experimental HfMnP anisotropy field within 25%. More importantly, our calculations suggest that the large magnetic anisotropy comes primarily from the Mn atoms, suggesting that similarly large anisotropies may be found in other 3d transition metal compounds.

Discovery of ferromagnetism with large magnetic anisotropy in ZrMnP and HfMnP

International Nuclear Information System (INIS)

Lamichhane, Tej N.; Taufour, Valentin; Kaluarachchi, Udhara S.; Bud'ko, Sergey L.; Canfield, Paul C.; Masters, Morgan W.; Parker, David S.; Thimmaiah, Srinivasa

2016-01-01

ZrMnP and HfMnP single crystals are grown by a self-flux growth technique, and structural as well as temperature dependent magnetic and transport properties are studied. Both compounds have an orthorhombic crystal structure. ZrMnP and HfMnP are ferromagnetic with Curie temperatures around 370 K and 320 K, respectively. The spontaneous magnetizations of ZrMnP and HfMnP are determined to be 1.9 μ_B/f.u. and 2.1 μ_B/f.u., respectively, at 50 K. The magnetocaloric effect of ZrMnP in terms of entropy change (ΔS) is estimated to be −6.7 kJ m"−"3 K"−"1 around 369 K. The easy axis of magnetization is [100] for both compounds, with a small anisotropy relative to the [010] axis. At 50 K, the anisotropy field along the [001] axis is ∼4.6 T for ZrMnP and ∼10 T for HfMnP. Such large magnetic anisotropy is remarkable considering the absence of rare-earth elements in these compounds. The first principle calculation correctly predicts the magnetization and hard axis orientation for both compounds, and predicts the experimental HfMnP anisotropy field within 25%. More importantly, our calculations suggest that the large magnetic anisotropy comes primarily from the Mn atoms, suggesting that similarly large anisotropies may be found in other 3d transition metal compounds.

The single-ion anisotropy effects in the mixed-spin ternary-alloy

Science.gov (United States)

Albayrak, Erhan

2018-04-01

The effect of single-ion anisotropy on the thermal properties of the ternary-alloy in the form of ABpC1-p is investigated on the Bethe lattice (BL) in terms of exact recursion relations. The simulation on the BL consists of placing A atoms (spin-1/2) on the odd shells and randomly placing B (spin-3/2) or C (spin-5/2) atoms with concentrations p and 1 - p, respectively, on the even shells. The phase diagrams are calculated in possible planes spanned by the system parameters: temperature, single-ion anisotropy, concentration and ratio of the bilinear interaction parameters for z = 3 corresponding to the honeycomb lattice. It is found that the crystal field drives the system to the lowest possible state therefore reducing the temperatures of the critical lines in agreement with the literature.

Observation of Various and Spontaneous Magnetic Skyrmionic Bubbles at Room Temperature in a Frustrated Kagome Magnet with Uniaxial Magnetic Anisotropy

KAUST Repository

Hou, Zhipeng

2017-06-07

The quest for materials hosting topologically protected skyrmionic spin textures continues to be fueled by the promise of novel devices. Although many materials have demonstrated the existence of such spin textures, major challenges remain to be addressed before devices based on magnetic skyrmions can be realized. For example, being able to create and manipulate skyrmionic spin textures at room temperature is of great importance for further technological applications because they can adapt to various external stimuli acting as information carriers in spintronic devices. Here, the first observation of skyrmionic magnetic bubbles with variable topological spin textures formed at room temperature in a frustrated kagome Fe3 Sn2 magnet with uniaxial magnetic anisotropy is reported. The magnetization dynamics are investigated using in situ Lorentz transmission electron microscopy, revealing that the transformation between different magnetic bubbles and domains is via the motion of Bloch lines driven by an applied external magnetic field. These results demonstrate that Fe3 Sn2 facilitates a unique magnetic control of topological spin textures at room temperature, making it a promising candidate for further skyrmion-based spintronic devices.

Electromagnetic Weible Instability in Intense Charged Particle Beams with Large Energy Anisotropy

International Nuclear Information System (INIS)

Startsev, Edward A.; Davidson, Ronald C.

2003-01-01

In plasmas with strongly anisotropic distribution functions, collective instabilities may develop if there is sufficient coupling between the transverse and longitudinal degrees of freedom. Our previous numerical and theoretical studies of intense charged particle beams with large temperature anisotropy [E. A. Startsev, R. C. Davidson and H. Qin, PRSTAB, 6, 084401 (2003); Phys. Plasmas 9, 3138 (2002)] demonstrated that a fast, electrostatic, Harris-like instability develops, and saturates nonlinearly, for sufficiently large temperature anisotropy (T perpendi c ular b /T parallelb >> 1). The total distribution function after saturation, however, is still far from equipartitioned. In this paper the linearized Vlasov-Maxwell equations are used to investigate detailed properties of the transverse electromagnetic Weibel-type instability for a long charge bunch propagating through a cylindrical pipe of radius r w . The kinetic stability analysis is carried out for azimuthally symmetric perturbations about a two-temperature thermal equilibrium distribution in the smooth-focusing approximation. The most unstable modes are identified, and their eigenfrequencies, radial mode structure and instability thresholds are determined. The stability analysis shows that, although there is free energy available to drive the electromagnetic Weibel instability, the finite transverse geometry of the charged particle beam introduces a large threshold value for the temperature anisotropy ((T perpendi c ularb /T parallelb ) Weibel >> (T perpendi c ularb /T parallelb ) Harris ) below which the instability is absent. Hence, unlike the case of an electrically neutral plasma, the Weibel instability is not expected to play as significant a role in the process of energy isotropization of intense unneutralized charged particle beams as the electrostatic Harris-type instability

Spin reorientation and magnetic anisotropy in Y2Co17-xCr x (x 1.17-3.0) compounds

International Nuclear Information System (INIS)

Fuquan, B.; Tegus, O.; Dagula, W.; Brueck, E.; Boer, F.R. de; Buschow, K.H.J.

2005-01-01

Spin reorientation transitions and magnetic anisotropy in Y 2 Co 17-x Cr x (x = 1.17-3.0) compounds have been investigated by means of X-ray diffraction and magnetization measurements. The powder X-ray diffraction patterns show that most samples crystallize as a single phase with the rhombohedral Th 2 Zn 17 -type structure. However, in the compound Y 2 Co 14 Cr 3 the Th 2 Zn 17 phase coexist with the hexagonal Th 2 Ni 17 -type phase. The lattice parameters a and c hardly change and the unit cell volume V increases slightly with increasing Cr content. The X-ray diffraction patterns of the aligned powder of the samples have confirmed that at room temperature the compound with x = 1.17 has planar anisotropy, but the compounds with x = 1.76, 2.34 and 3.00 have uniaxial anisotropy. Spin reorientation phenomena occur in all of the compounds. With increasing Cr content, the Curie temperature, the spin reorientation temperature, the spontaneous magnetization, and the anisotropy constant K 2 of the Y 2 Co 17-x Cr x (x = 1.17-3.0) compounds decrease strongly while the anisotropy constant K 1 increases in the range of x from 1.17 to 2.34 and then decreases in the range of x from 2.34 to 3.00

Excited state Intramolecular Proton Transfer in Anthralin

DEFF Research Database (Denmark)

Møller, Søren; Andersen, Kristine B.; Spanget-Larsen, Jens

1998-01-01

Quantum chemical calculations performed on anthralin (1,8-dihydroxy-9(10H)-anthracenone) predict the possibility of an excited-state intramolecular proton transfer process. Fluorescence excitation and emission spectra of the compound dissolved in n-hexane at ambient temperature results in an unus......Quantum chemical calculations performed on anthralin (1,8-dihydroxy-9(10H)-anthracenone) predict the possibility of an excited-state intramolecular proton transfer process. Fluorescence excitation and emission spectra of the compound dissolved in n-hexane at ambient temperature results......, associated with an excited-state intramolecular proton transfer process....

Numerical simulation of proton exchange membrane fuel cells at high operating temperature

Science.gov (United States)

Peng, Jie; Lee, Seung Jae

A three-dimensional, single-phase, non-isothermal numerical model for proton exchange membrane (PEM) fuel cell at high operating temperature (T ≥ 393 K) was developed and implemented into a computational fluid dynamic (CFD) code. The model accounts for convective and diffusive transport and allows predicting the concentration of species. The heat generated from electrochemical reactions, entropic heat and ohmic heat arising from the electrolyte ionic resistance were considered. The heat transport model was coupled with the electrochemical and mass transport models. The product water was assumed to be vaporous and treated as ideal gas. Water transportation across the membrane was ignored because of its low water electro-osmosis drag force in the polymer polybenzimidazole (PBI) membrane. The results show that the thermal effects strongly affect the fuel cell performance. The current density increases with the increasing of operating temperature. In addition, numerical prediction reveals that the width and distribution of gas channel and current collector land area are key optimization parameters for the cell performance improvement.

Numerical simulation of proton exchange membrane fuel cells at high operating temperature

Energy Technology Data Exchange (ETDEWEB)

Peng, Jie; Lee, Seung Jae [Energy Lab, Samsung Advanced Institute of Technology, Mt. 14-1 Nongseo-Dong, Giheung-Gu, Yongin-Si, Gyeonggi-Do 446-712 (Korea, Republic of)

2006-11-22

A three-dimensional, single-phase, non-isothermal numerical model for proton exchange membrane (PEM) fuel cell at high operating temperature (T>=393K) was developed and implemented into a computational fluid dynamic (CFD) code. The model accounts for convective and diffusive transport and allows predicting the concentration of species. The heat generated from electrochemical reactions, entropic heat and ohmic heat arising from the electrolyte ionic resistance were considered. The heat transport model was coupled with the electrochemical and mass transport models. The product water was assumed to be vaporous and treated as ideal gas. Water transportation across the membrane was ignored because of its low water electro-osmosis drag force in the polymer polybenzimidazole (PBI) membrane. The results show that the thermal effects strongly affect the fuel cell performance. The current density increases with the increasing of operating temperature. In addition, numerical prediction reveals that the width and distribution of gas channel and current collector land area are key optimization parameters for the cell performance improvement. (author)

On the single-ion Magnetic Anisotropy of the Rare-Earth Metals

DEFF Research Database (Denmark)

Kolmakova, N.P.; Tishin, A.M.; Bohr, Jakob

1996-01-01

The temperature dependences of the single-ion magnetic anisotropy constants for Tb and Dy metals are calculated in terms of the multipole moments of the rare-earth ions utilizing the available crystal-field parameters. The results are compared with the existing experimental data....

Covalent magnetism, exchange interactions and anisotropy of the high temperature layered antiferromagnet MnB₂.

Science.gov (United States)

Khmelevskyi, S; Mohn, P

2012-01-11

The investigation of the electronic structure and magnetism for the compound MnB(2) with crystal structure type AlB(2) has been revisited to resolve contradictions between various experimental and theoretical results present in the literature. We find that MnB(2) exhibits an interesting example of a Kübler's covalent magnetism (Williams et al 1981 J. Appl. Phys. 52 2069). The covalent magnetism also appears to be the source of some disagreement between the calculated values of the magnetic moments and those given by neutron diffraction experiments. We show that this shortcoming is due to the atomic sphere approximation applied in earlier calculations. The application of the disordered local moment approach and the calculation of the inter-atomic exchange interactions within the Liechtenstein formalism reveal strong local moment antiferromagnetism with a high Néel temperature predicted from Monte Carlo simulations. A fully relativistic band structure calculation and then the application of the torque method yields a strong in-plane anisotropy of the Mn magnetic moments. The agreement of these results with neutron diffraction studies rules out any possible weak itinerant electron magnetism scenarios as proposed earlier for MnB(2).

Time resolved infrared spectroscopy of femtosecond proton dynamics in the liquid phase

International Nuclear Information System (INIS)

Amir, W.

2003-12-01

This work of thesis aims to understand the strong mobility of protons in water. Water is fundamental to life and mediates many chemical and biological processes. However this liquid is poorly understood at the molecular level. The richness of interdisciplinary sciences allows us to study the properties which make it so unique. The technique used for this study was the femtosecond time resolved vibrational spectroscopy. Several experiments were carried out to characterize the femtosecond proton dynamics in water. The visualization of the rotation of water molecules obtained by anisotropy measurements will be presented. This experiment is carried out in isotopic water HDO/D 2 O for reasons of experimental and theoretical suitability. However this is not water. Pure water H 2 O was also studied without thermal effects across vibrations modes. An intermolecular energy resonant transfer was observed. Finally the localized structure of the proton in water (called Eigen form) was clearly experimentally observed. This molecule is implicated in the abnormal mobility of the proton in water (Grotthuss mechanism). (author)

Measurements of impurity migration in graphite at high temperatures using a proton microprobe

International Nuclear Information System (INIS)

Shroy, R.E.; Soo, P.; Sastre, C.A.; Schweiter, D.G.; Kraner, H.W.; Jones, K.W.

1978-01-01

The migration of fission products and other impurities through the graphite core of a High Temperature Gas Cooled Reactor is of prime importance in studies of reactor safety. Work in this area is being carried out in which graphite specimens are heated to temperatures up to 3800 0 C to induce migration of trace elements whose local concentrations are then measured with a proton microprobe. This instrument is a powerful device for such work because of its ability to determine concentrations at a part per million (ppm) level in a circular area as small as 10 μm while operating in an air environment. Studies show that Si, Ca, Cl, and Fe impurities in graphite migrate from hotter to cooler regions. Also Si, S, Cl, Ca, Fe, Mn, and Cr are observed to escape from the graphite and be deposited on cooler surfaces

Primordial anisotropies in gauged hybrid inflation

Science.gov (United States)

Akbar Abolhasani, Ali; Emami, Razieh; Firouzjahi, Hassan

2014-05-01

We study primordial anisotropies generated in the model of gauged hybrid inflation in which the complex waterfall field is charged under a U(1)gauge field. Primordial anisotropies are generated either actively during inflation or from inhomogeneities modulating the surface of end of inflation during waterfall transition. We present a consistent δN mechanism to calculate the anisotropic power spectrum and bispectrum. We show that the primordial anisotropies generated at the surface of end of inflation do not depend on the number of e-folds and therefore do not produce dangerously large anisotropies associated with the IR modes. Furthermore, one can find the parameter space that the anisotropies generated from the surface of end of inflation cancel the anisotropies generated during inflation, therefore relaxing the constrains on model parameters imposed from IR anisotropies. We also show that the gauge field fluctuations induce a red-tilted power spectrum so the averaged power spectrum from the gauge field can change the total power spectrum from blue to red. Therefore, hybrid inflation, once gauged under a U(1) field, can be consistent with the cosmological observations.

Primordial anisotropies in gauged hybrid inflation

International Nuclear Information System (INIS)

Abolhasani, Ali Akbar; Emami, Razieh; Firouzjahi, Hassan

2014-01-01

We study primordial anisotropies generated in the model of gauged hybrid inflation in which the complex waterfall field is charged under a U(1)gauge field. Primordial anisotropies are generated either actively during inflation or from inhomogeneities modulating the surface of end of inflation during waterfall transition. We present a consistent δN mechanism to calculate the anisotropic power spectrum and bispectrum. We show that the primordial anisotropies generated at the surface of end of inflation do not depend on the number of e-folds and therefore do not produce dangerously large anisotropies associated with the IR modes. Furthermore, one can find the parameter space that the anisotropies generated from the surface of end of inflation cancel the anisotropies generated during inflation, therefore relaxing the constrains on model parameters imposed from IR anisotropies. We also show that the gauge field fluctuations induce a red-tilted power spectrum so the averaged power spectrum from the gauge field can change the total power spectrum from blue to red. Therefore, hybrid inflation, once gauged under a U(1) field, can be consistent with the cosmological observations

Inorganic-based proton conductive composite membranes for elevated temperature and reduced relative humidity PEM fuel cells

Science.gov (United States)

Wang, Chunmei

Proton exchange membrane (PEM) fuel cells are regarded as highly promising energy conversion systems for future transportation and stationary power generation and have been under intensive investigations for the last decade. Unfortunately, cutting edge PEM fuel cell design and components still do not allow economically commercial implementation of this technology. The main obstacles are high cost of proton conductive membranes, low-proton conductivity at low relative humidity (RH), and dehydration and degradation of polymer membranes at high temperatures. The objective of this study was to develop a systematic approach to design a high proton conductive composite membrane that can provide a conductivity of approximately 100 mS cm-1 under hot and dry conditions (120°C and 50% RH). The approach was based on fundamental and experimental studies of the proton conductivity of inorganic additives and composite membranes. We synthesized and investigated a variety of organic-inorganic Nafion-based composite membranes. In particular, we analyzed their fundamental properties, which included thermal stability, morphology, the interaction between inorganic network and Nafion clusters, and the effect of inorganic phase on the membrane conductivity. A wide range of inorganic materials was studied in advance in order to select the proton conductive inorganic additives for composite membranes. We developed a conductivity measurement method, with which the proton conductivity characteristics of solid acid materials, zirconium phosphates, sulfated zirconia (S-ZrO2), phosphosilicate gels, and Santa Barbara Amorphous silica (SBA-15) were discussed in detail. Composite membranes containing Nafion and different amounts of functionalized inorganic additives (sulfated inorganics such as S-ZrO2, SBA-15, Mobil Composition of Matter MCM-41, and S-SiO2, and phosphonated inorganic P-SiO2) were synthesized with different methods. We incorporated inorganic particles within Nafion clusters

The dew point temperature as a criterion for optimizing the operating conditions of proton exchange membrane fuel cells

DEFF Research Database (Denmark)

Berning, Torsten

2012-01-01

In this article an analytical method to calculate the dew point temperatures of the anode and cathode exit gas streams of a proton exchange membrane fuel cell is developed. The results of these calculations are used to create diagrams that show the dew point temperatures as function of the operat...... for conventional flow field plates. The diagrams presented here are created for completely dry inlet gases, but they can be easily corrected for a nonzero inlet relative humidity....

Anisotropy in the deep Earth

Science.gov (United States)

Romanowicz, Barbara; Wenk, Hans-Rudolf

2017-08-01

Seismic anisotropy has been found in many regions of the Earth's interior. Its presence in the Earth's crust has been known since the 19th century, and is due in part to the alignment of anisotropic crystals in rocks, and in part to patterns in the distribution of fractures and pores. In the upper mantle, seismic anisotropy was discovered 50 years ago, and can be attributed for the most part, to the alignment of intrinsically anisotropic olivine crystals during large scale deformation associated with convection. There is some indication for anisotropy in the transition zone, particularly in the vicinity of subducted slabs. Here we focus on the deep Earth - the lower mantle and core, where anisotropy is not yet mapped in detail, nor is there consensus on its origin. Most of the lower mantle appears largely isotropic, except in the last 200-300 km, in the D″ region, where evidence for seismic anisotropy has been accumulating since the late 1980s, mostly from shear wave splitting measurements. Recently, a picture has been emerging, where strong anisotropy is associated with high shear velocities at the edges of the large low shear velocity provinces (LLSVPs) in the central Pacific and under Africa. These observations are consistent with being due to the presence of highly anisotropic MgSiO3 post-perovskite crystals, aligned during the deformation of slabs impinging on the core-mantle boundary, and upwelling flow within the LLSVPs. We also discuss mineral physics aspects such as ultrahigh pressure deformation experiments, first principles calculations to obtain information about elastic properties, and derivation of dislocation activity based on bonding characteristics. Polycrystal plasticity simulations can predict anisotropy but models are still highly idealized and neglect the complex microstructure of polyphase aggregates with strong and weak components. A promising direction for future progress in understanding the origin of seismic anisotropy in the deep mantle

Cosmic ray anisotropy searches with AMS-02

Energy Technology Data Exchange (ETDEWEB)

Zeissler, Stefan; Gebauer, Iris; Trumpf, Ricarda [Karlsruher Institut fuer Technologie (KIT) (Germany)

2016-07-01

The Alpha Magnetic Spectrometer (AMS-02) is a state-of-the-art particle detector designed to operate as an external module on the International Space Station (ISS). In this unique space environment cosmic particles can be measured with high precision over an energy range from GeV up to TeV. The AMS collaboration provided precise measurements of the electron and positron fluxes, which indicate an additional source of positrons among the various cosmic particles. Possible candidates for this source are local pulsars, a local source of positrons produced in proton-gas interactions or dark matter annihilation. In the first two cases a possible anisotropy in the electrons and positrons incoming direction at Earth might be detectable. To determine the level of isotropy the measured data is compared to reference maps, which simulate the measurement of an isotropic sky. A common choice of reference maps are proton count maps or shuffled maps, which redistribute measured incoming directions over the whole measuring time. Both choices lead to difficulties in the reconstruction of a marginal signal with a big expansion over the galactic sky as it would be the case for charged cosmic particles. We developed a method to construct reference maps based on fundamental detector characteristics such as the lifetime and the geometric acceptance. Using this we are able to reconstruct the isotropic sky as it would be seen by the detector. We demonstrate the performance of the method using AMS-02 data.

Seismic anisotropies of the Songshugou peridotites (Qinling orogen, central China) and their seismic implications

Science.gov (United States)

Cao, Yi; Jung, Haemyeong; Song, Shuguang

2018-01-01

Though extensively studied, the roles of olivine crystal preferred orientations (CPOs or fabrics) in affecting the seismic anisotropies in the Earth's upper mantle are rather complicated and still not fully known. In this study, we attempted to address this issue by analyzing the seismic anisotropies [e.g., P-wave anisotropy (AVp), S-wave polarization anisotropy (AVs), radial anisotropy (ξ), and Rayleigh wave anisotropy (G)] of the Songshugou peridotites (dunite dominated) in the Qinling orogen in central China, based on our previously reported olivine CPOs. The seismic anisotropy patterns of olivine aggregates in our studied samples are well consistent with the prediction for their olivine CPO types; and the magnitude of seismic anisotropies shows a striking positive correlation with equilibrium pressure and temperature (P-T) conditions. Significant reductions of seismic anisotropies (AVp, max. AVs, and G) are observed in porphyroclastic dunite compared to coarse- and fine-grained dunites, as the results of olivine CPO transition (from A-/D-type in coarse-grained dunite, through AG-type-like in porphyroclastic dunite, to B-type-like in fine-grained dunite) and strength variation (weakening: A-/D-type → AG-type-like; strengthening: AG-type-like → B-type-like) during dynamic recrystallization. The transition of olivine CPOs from A-/D-type to B-/AG-type-like in the forearc mantle may weaken the seismic anisotropies and deviate the fast velocity direction and the fast S-wave polarization direction from trench-perpendicular to trench-oblique direction with the cooling and aging of forearc mantle. Depending on the size and distribution of the peridotite body such as the Songshugou peridotites, B- and AG-type-like olivine CPOs can be an additional (despite minor) local contributor to the orogen-parallel fast velocity direction and fast shear-wave polarization direction in the orogenic crust such as in the Songshugou area in Qinling orogen.

Measurement of the distribution of anisotropy constants in magnetic nanoparticles for hyperthermia applications

Science.gov (United States)

McGhie, A. A.; Marquina, C.; O'Grady, K.; Vallejo-Fernandez, G.

2017-11-01

In this work, we have applied theoretical calculations to new experimental measurements of the effect of the anisotropy distribution in magnetite nanoparticles, which in turn controls hysteresis heating for hyperthermia applications. Good agreement between theory and experiment is reported where the theoretical calculation is based upon the detailed measurement of the particle elongation generally observed in the nanoparticles. The elongation has been measured from studies via transmission electron microscopy. We find that particle elongation is responsible for the anisotropy dispersion, which can be obtained by analysis and fitting to a measurement of the temperature decay of remanence. A median value of the anisotropy constant of 1.5  ×  105 erg/cc was obtained. A very wide distribution of anisotropy constants is present with a Gaussian standard deviation of 1.5  ×  105 erg/cc. From our measurements, deviations in the value of the saturation magnetisation from particle to particle are most likely the main factor giving rise to this large distribution, with 33% arising from the error in the measured elongation. The lower limit to the anisotropy constant of the nanoparticles is determined by the magnetocrystalline anisotropy of the material, 1.1  ×  105 erg/cc for magnetite, which was studied in this work.

Thermal and water management of low temperature Proton Exchange Membrane Fuel Cell in fork-lift truck power system

International Nuclear Information System (INIS)

Hosseinzadeh, Elham; Rokni, Masoud; Rabbani, Abid; Mortensen, Henrik Hilleke

2013-01-01

Highlights: ► Developing a general zero dimensional Proton Exchange Membrane Fuel Cell (PEMFC) model for a forklift. ► System performance with different cooling fluids. ► Water and thermal management of fuel cell system. ► Effect of inlet temperature, outlet temperature and temperature gradient on system performance. - Abstract: A general zero-dimensional Proton Exchange Membrane Fuel Cell (PEMFC) model has been developed for forklift truck application. The balance of plant (BOP) comprises of a compressor, an air humidifier, a set of heat exchangers and a recirculation pump. Water and thermal management of the fuel cell stack and BOP has been investigated in this study. The results show that humidification of the inlet air is of great importance. By decreasing the relative humidity of inlet air from 95% to 25%, the voltage can drop by 29%. In addition, elevated stack temperature can lead to a higher average cell voltage when membrane is fully hydrated otherwise it causes a drastic voltage drop in the stack. Furthermore, by substituting liquid water with water–ethylene glycol mixture of 50%, the mass flow of coolant increases by about 32–33% in the inner loop and 60–65% in the outer loop for all ranges of current. The system can then be started up at about −25 °C with negligible change in the efficiency

Thin film thermocouples for in situ membrane electrode assembly temperature measurements in a polybenzimidazole-based high temperature proton exchange membrane unit cell

DEFF Research Database (Denmark)

Ali, Syed Talat; Lebæk, Jesper; Nielsen, Lars Pleth

2010-01-01

m thick layer of TFTCs on 75 mu m thick Kapton foil. The Kapton foil was treated with in situ argon plasma etching to improve the adhesion between TFTCs and the Kapton substrate. The TFTCs were covered with a 7 mu m liquid Kapton layer using spin coating technique to protect them from environmental......This paper presents Type-T thin film thermocouples (TFTCs) fabricated on Kapton (polyimide) substrate for measuring the internal temperature of PBI(polybenzimidazole)-based high temperature proton exchange membrane fuel cell (HT-PEMFC). Magnetron sputtering technique was employed to deposit a 2 mu...... degradation. This Kapton foil with deposited TFTCs was used as sealing inside a PBI (polybenzimidazole)-based single cell test rig, which enabled measurements of in situ temperature variations of the working fuel cell MEA. The performance of the TFTCs was promising with minimal interference to the operation...

Transfer anisotropy in a turbulent plasma

International Nuclear Information System (INIS)

Bychenkov, V.Y.; Gradov, O.M.; Silin, V.P.

1982-01-01

We formulate a theory for transfer phenomena in a plasma with developed ion-sound turbulence. A transfer anisotropy effect caused by a temperature gradient is revealed. The corresponding fluxes transverse to the effective force vector (1) which generates the turbulence turn out to be considerably larger than the longitudinal fluxes in a plasma with a relatively small degree of nonisothermality. For a strongly nonisothermal plasma a suppression of the transverse fluxes takes place and corresponds to a growth of the thermal insulation of the current-carrying plasma filaments

Time resolved infrared spectroscopy of femtosecond proton dynamics in the liquid phase; Spectroscopie infrarouge resolue en temps pour l'etude de la dynamique femtoseconde du proton en phase liquide

Energy Technology Data Exchange (ETDEWEB)

Amir, W

2003-12-15

This work of thesis aims to understand the strong mobility of protons in water. Water is fundamental to life and mediates many chemical and biological processes. However this liquid is poorly understood at the molecular level. The richness of interdisciplinary sciences allows us to study the properties which make it so unique. The technique used for this study was the femtosecond time resolved vibrational spectroscopy. Several experiments were carried out to characterize the femtosecond proton dynamics in water. The visualization of the rotation of water molecules obtained by anisotropy measurements will be presented. This experiment is carried out in isotopic water HDO/D{sub 2}O for reasons of experimental and theoretical suitability. However this is not water. Pure water H{sub 2}O was also studied without thermal effects across vibrations modes. An intermolecular energy resonant transfer was observed. Finally the localized structure of the proton in water (called Eigen form) was clearly experimentally observed. This molecule is implicated in the abnormal mobility of the proton in water (Grotthuss mechanism). (author)

Evidence for a tyrosine protonation change during the primary phototransition of bacteriorhodopsin at low temperature.

OpenAIRE

Rothschild, K J; Roepe, P; Ahl, P L; Earnest, T N; Bogomolni, R A; Das Gupta, S K; Mulliken, C M; Herzfeld, J

1986-01-01

Isotopically labeled tyrosines have been selectively incorporated into bacteriorhodopsin (bR). A comparison of the low-temperature bR570 to K Fourier transform infrared-difference spectra of these samples and normal bR provides information about the role of tyrosine in the primary phototransition. Several tyrosine contributions to the difference spectrum are found. These results and comparison with the spectra of model compounds suggest that a tyrosinate group protonates during the bR570 to K...

Solar diurnal anisotropy measured using muons in GRAPES-3 ...

Indian Academy of Sciences (India)

The mean energy of muons at sea level is ∼4 GeV with a rel- .... of decays of mesons and muons work against each other resulting in temperature coef- ..... The mean muon rate of 16 modules measured every 15 min for one week interval from .... 4. 8. 12. 16. 20. 24. Hours. Figure 12. Solar diurnal anisotropy measured in ...

Experimental study of pyrolytic boron nitride at high temperature with and without proton and VUV irradiations

International Nuclear Information System (INIS)

Balat-Pichelin, M.; Eck, J.; Heurtault, S.; Glénat, H.

2014-01-01

Highlights: • New results for the high temperature study of pBN in high vacuum for the heat shield of solar probes. • Physico-chemical behavior of pBN studied up to 1700 K with proton and VUV irradiations. • Rather low effect of synergistic aggressions on the microstructure of pBN material. • The α/ε ratio of pBN coating on C/C measured up to 2200 K is 20% lower than for the C/C itself. - Abstract: In the frame of future exploration missions such as Solar Probe Plus (NASA) and PHOIBOS (ESA), research was carried out to study pyrolytic BN material envisaged as coating for their heat shields. The physico-chemical behavior of CVD pBN at very high temperature with or without hydrogen ions and VUV (Vacuum Ultra-Violet) irradiations was studied in high vacuum together with the in situ measurement of the thermal radiative properties conditioning the thermal equilibrium of the heat shield. Experimental results obtained on massive pBN samples are presented through in situ mass spectrometry and mass loss rate, and post-test microstructural characterization by XRD, SEM, AFM and nano-indentation techniques, some of them leading to mechanical properties. It could be concluded that synergistic effect of high temperature, protons and VUV radiation has an impact on the emission of gaseous species, the mass loss rate and the mechanical properties of the material

Analysis of the austenitic stainless steel's r-value behavior at elevated temperatures

Directory of Open Access Journals (Sweden)

Dušan Arsić

2015-05-01

Full Text Available An analysis of the anisotropy properties of austenitic steel AISI 304 (X5CrNi18-10 at elevated temperatures is presented in this paper. Considerations of the anisotropy problems are presented in the theoretical part of the paper, as well as the procedure for determination of the normal anisotropy coefficient. The experimental part of the paper describes the plan, methodology and equipment for testing of material's normal anisotropy and mechanical characteristics. The objective of conducting the experiments was to investigate influence of temperature on normal anisotropy, as well as on the mechanical properties of the considered material. The normal anisotropy was monitored by the coefficient – the so-called "r-value". Besides that, the tensile strength, yield stress and elongation at break were monitored, also. The tests were done on the 0.7 mm thick sheet metal within the temperature range 20 to 700°C.

Relative thermoluminescent efficiencies proton/gamma and helium/gamma of high temperature peaks in TLD-100 dosemeters

International Nuclear Information System (INIS)

Flores M, E.; Avila, O.; Rodriguez V, M.; Massillon, J.L.G.; Buenfil A, E.; Ruiz T, C.; Brandan, M.E.; Gamboa De Buen, I.

2007-01-01

This work presents measures of relative thermoluminescent efficiency of those high temperature peaks of TLD-100 dosemeters exposed to protons of 1.5 MeV and to helium nuclei of 3 and 7.5 MeV. A rigorous reading and of deconvolution protocol was used for the calculation of the TL efficiencies. Additionally an Excel program that facilitated the deconvolution adjustment process of the glow curves was elaborated. (Author)

CνB Damping of Primordial Gravitational Waves and the Fine-Tuning of the CγB Temperature Anisotropy

Directory of Open Access Journals (Sweden)

A. E. Bernardini

2014-01-01

Full Text Available Damping of primordial gravitational waves due to the anisotropic stress contribution owing to the cosmological neutrino background (CνB is investigated in the context of a radiation-to-matter dominated universe. Besides its inherent effects on the gravitational wave propagation, the inclusion of the CνB anisotropic stress into the dynamical equations also affects the tensor mode contribution to the anisotropy of the cosmological microwave background (CγB temperature. The mutual effects on the gravitational waves and on the CγB are obtained through a unified prescription for a radiation-to-matter dominated scenario. The results are confronted with some preliminary results for the radiation dominated scenario. Both scenarios are supported by a simplified analytical framework, in terms of a scale independent dynamical variable, kη, that relates cosmological scales, k, and the conformal time, η. The background relativistic (hot dark matter essentially works as an effective dispersive medium for the gravitational waves such that the damping effect is intensified for the universe evolving to the matter dominated era. Changes on the temperature variance owing to the inclusion of neutrino collision terms into the dynamical equations result in spectral features that ratify that the multipole expansion coefficients ClT’s die out for l~100.

Transfer anisotropy effect in a turbulent plasma

International Nuclear Information System (INIS)

Bychenkov, V.Yu.; Gradov, O.M.; Silin, V.P.

1982-01-01

A theory is developed of transfer phenomena with pronounced ion-sound turbulence. A transfer anisotropy effect is observed which is due to the temperature gradient. The corresponding fluxes across the effective force vector generating the turbulence are found to be considerably greater than the longitudinal fluxes in a plasma with a comparatively low degree of nonisothermality. In a strongly nonisothermal plasma the suppression of transverse fluxes occurs, corresponding to the growth of thermal insulation of the current-carrying plasma filaments

Construction and test of a polarized proton target

International Nuclear Information System (INIS)

Aures, R.

1983-12-01

This work describes experiments in which for the first time a proton target has been constructed which is polarized by the ''brute-force'' method. This method requires very low temperatures and high magnetic fields. The low temperatures (down to 10 mK) are obtained by a 3 He/ 4 He dilution refrigerator, the magnetic field (up to 9 T) is produced by a superconducting split pair magnet. The proton target has a volume of about 18 cm 3 and consists of pressed titaniumhydride powder, which has a titanium/-hydrogen ratio of 1:1,96. The hydrogen content is 1,3 mol. Titaniumhydride has the advantage of sufficient heat conductivity at low temperatures and a very high proton density. The heat conductivity of the sample is measured, with and without the presence of a magnetic field. Thermodynamical measurements and adiabatic demagnetisation experiments proved quantitatively the polarization of the protons. The polarization of the proton has been measured in a transmission experiment using polarized neutrons of 1.2 MeV. The result shows a good agreement of theoretical and actual polarization. From the results it can be concluded, that this sample can be used successfully as a polarized proton target for neutron scattering experiments to measure spin-correlations. (orig.) [de

Flow-induced elastic anisotropy of metallic glasses

International Nuclear Information System (INIS)

Sun, Y.H.; Concustell, A.; Carpenter, M.A.; Qiao, J.C.; Rayment, A.W.; Greer, A.L.

2016-01-01

As-cast bulk metallic glasses are isotropic, but anisotropy can be induced by thermomechanical treatments. For example, the diffraction halo in the structure function S(Q) observed in transmission becomes elliptical (rather than circular) after creep in uniaxial tension or compression. Published studies associate this with frozen-in anelastic strain and bond-orientational anisotropy. Results so far are inconsistent on whether viscoplastic flow of metallic glasses can induce anisotropy. Preliminary diffraction data suggest that the anisotropy, if any, is very low, while measurements of the elastic properties suggest that there is induced anisotropy, opposite in sign to that due to anelastic strain. We study three bulk metallic glasses, Ce 65 Al 10 Cu 20 Co 5 , La 55 Ni 10 Al 35 , and Pd 40 Ni 30 Cu 10 P 20 . By using resonant ultrasound spectroscopy to determine the full elasticity tensor, the effects of relaxation and rejuvenation can be reliably separated from uniaxial anisotropy (of either sign). The effects of viscoplastic flow in tension are reported for the first time. We find that viscoplastic flow of bulk metallic glasses, particularly in tension, can induce significant anisotropy that is distinct from that associated with frozen-in anelastic strain. The conditions for inducing such anisotropy are explored in terms of the Weissenberg number (ratio of relaxation times for primary relaxation and for shear strain rate). There is a clear need for further work to characterize the structural origins of flow-induced anisotropy and to explore the prospects for improved mechanical and other properties through induced anisotropy.

In-situ monitoring of internal local temperature and voltage of proton exchange membrane fuel cells.

Science.gov (United States)

Lee, Chi-Yuan; Fan, Wei-Yuan; Hsieh, Wei-Jung

2010-01-01

The distribution of temperature and voltage of a fuel cell are key factors that influence performance. Conventional sensors are normally large, and are also useful only for making external measurements of fuel cells. Centimeter-scale sensors for making invasive measurements are frequently unable to accurately measure the interior changes of a fuel cell. This work focuses mainly on fabricating flexible multi-functional microsensors (for temperature and voltage) to measure variations in the local temperature and voltage of proton exchange membrane fuel cells (PEMFC) that are based on micro-electro-mechanical systems (MEMS). The power density at 0.5 V without a sensor is 450 mW/cm(2), and that with a sensor is 426 mW/cm(2). Since the reaction area of a fuel cell with a sensor is approximately 12% smaller than that without a sensor, but the performance of the former is only 5% worse.

Anisotropy of acoustic properties in paratellurite

International Nuclear Information System (INIS)

Parygin, Vladimir N.

1996-01-01

One of the peculiarities of the TeO 2 crystal consists of its strong acoustic anisotropy. This anisotropy demonstrates itself by acoustic energy walk-off and anisotropic distortion of an acoustic beam. Four constants completely characterise the acoustic anisotropy of the medium. In this paper these constants are calculated for various directions of the acoustic beam in crystal. (authors)

Strain-dependent magnetic anisotropy in GaMnAs on InGaAs templates

Energy Technology Data Exchange (ETDEWEB)

Daeubler, Joachim; Glunk, Michael; Schwaiger, Stephan; Dreher, Lukas; Schoch, Wladimir; Sauer, Rolf; Limmer, Wolfgang [Institut fuer Halbleiterphysik, Universitaet Ulm, 89069 Ulm (Germany)

2008-07-01

We have systematically studied the influence of strain on the magnetic anisotropy of GaMnAs by means of HRXRD reciprocal space mapping and angle-dependent magnetotransport. For this purpose, a series of GaMnAs layers with Mn contents of {proportional_to}5% was grown by low-temperature MBE on relaxed InGaAs/GaAs templates with different In concentrations, enabling us to vary the strain in the GaMnAs layers continuously from tensile to compressive, including the unstrained state. Considering both, as-grown and annealed samples, the anisotropy parameter describing the uniaxial out-of-plane magnetic anisotropy has been found to vary linearly with hole density and strain. As a consequence, the out-of-plane direction gradually undergoes a transition from a magnetic hard axis to a magnetic easy axis from compressive to tensile strain.

Thickness and angular dependent magnetic anisotropy of La0.67Sr0.33MnO3 thin films by Vectorial Magneto Optical Kerr Magnetometry

Science.gov (United States)

Chaluvadi, S. K.; Perna, P.; Ajejas, F.; Camarero, J.; Pautrat, A.; Flament, S.; Méchin, L.

2017-10-01

We investigate the in-plane magnetic anisotropy in La0.67Sr0.33MnO3 thin films grown on SrTiO3 (001) substrate using angular dependent room temperature Vectorial Magneto-Optical Kerr Magnetometry. The experimental data reveals that the magnetic anisotropy symmetry landscape significantly changes depending upon the strain and thickness. At low film thickness (12 and 25 nm) the dominant uniaxial anisotropy is due to interface effects, step edges due to mis-cut angle of SrTiO3 substrate. At intermediate thickness, the magnetic anisotropy presents a competition between magnetocrystalline (biaxial) and substrate step induced (uniaxial) anisotropy. Depending upon their relative strengths, a profound biaxial or uniaxial or mixed anisotropy is favoured. Above the critical thickness, magnetocrystalline anisotropy dominates all other effects and shows a biaxial anisotropy.

Controlling the induced anisotropy in soft magnetic films for high-frequency applications

NARCIS (Netherlands)

Chezan, A.R.; Craus, C.B.; Chechenin, N.G.; Vystavel, T.; Hosson, J.Th.M. De; Niesen, L.; Boerma, D.O.

Nanocrystalline soft magnetic Fe–Zr–N films were successfully deposited by dc magnetron reactive sputtering. The nitrogen content was controlled by varying the Ar/N2 ratio and/or the substrate temperature. The films have saturation magnetization and induced uniaxial anisotropy values in the range

Texture and Elastic Anisotropy of Mantle Olivine

Science.gov (United States)

Nikitin, A. N.; Ivankina, T. I.; Bourilitchev, D. E.; Klima, K.; Locajicek, T.; Pros, Z.

Eight olivine rock samples from different European regions were collected for neu- tron texture analyses and for P-wave velocity measurements by means of ultrasonic sounding at various confining pressures. The orientation distribution functions (ODFs) of olivine were determined and pole figures of the main crystallographic planes were calculated. The spatial P-wave velocity distributions were determined at confining pressures from 0.1 to 400 MPa and modelled from the olivine textures. In dependence upon the type of rock (xenolith or dunite) different behavior of both the P-wave veloc- ity distributions and the anisotropy coefficients with various confining pressures was observed. In order to explain the interdependence of elastic anisotropy and hydrostatic pressure, a model for polycrystalline olivine rocks was suggested, which considers the influence of the crystallographic and the mechanical textures on the elastic behaviour of the polycrystal. Since the olivine texture depends upon the active slip systems and the deformation temperature, neutron texture analyses enable us to estimate depth and thermodynamical conditions during texture formation.

Parton self-energies for general momentum-space anisotropy

Science.gov (United States)

Kasmaei, Babak S.; Strickland, Michael

2018-03-01

We introduce an efficient general method for calculating the self-energies, collective modes, and dispersion relations of quarks and gluons in a momentum-anisotropic high-temperature quark-gluon plasma. The method introduced is applicable to the most general classes of deformed anisotropic momentum distributions and the resulting self-energies are expressed in terms of a series of hypergeometric basis functions which are valid in the entire complex phase-velocity plane. Comparing to direct numerical integration of the self-energies, the proposed method is orders of magnitude faster and provides results with similar or better accuracy. To extend previous studies and demonstrate the application of the proposed method, we present numerical results for the parton self-energies and dispersion relations of partonic collective excitations for the case of an ellipsoidal momentum-space anisotropy. Finally, we also present, for the first time, the gluon unstable mode growth rate for the case of an ellipsoidal momentum-space anisotropy.

Effect of anisotropy on the magnon energy gap in a two-layer ferromagnetic superlattice

International Nuclear Information System (INIS)

Qiu Rongke; Liang Jing; Li Qingfeng; Zhang Zhidong; Song Panpan; Hong Xiaomin

2009-01-01

The magnon energy bands or spectra in a two-layer ferromagnetic superlattice are studied. It is found that a modulated energy gap exists in the magnon energy band along K x direction perpendicular to the superlattice plane, which is different from the optical magnon gap at K x =0. The anisotropy, the spin quantum numbers and the interlayer exchange couplings all affect the magnon energy gap. If the anisotropy exists, there will be no acoustic energy branch in the system. There is a competition effect of the anisotropy and the spin quantum number on the magnon energy gap. The competition achieves a balance at the zero energy gap, at which the symmetry of the system is higher. The two energy spectra of the two-layer ferromagnetic superlattice are lowered with increasing temperature.

Hysteresis, critical fields and superferromagnetism of the film with perpendicular anisotropy

International Nuclear Information System (INIS)

Kalita, V.M.; Kulyk, M.M.; Ryabchenko, S.M.

2016-01-01

This paper is focused on the analysis of hysteresis and critical phenomena of magnetization reversal of superferromagnetic (SFM) state in nanogranular (NG) Co/Al 2 O 3 film with perpendicular anisotropy. It was demonstrated that the transition from the multidomain SFM state to the homogeneous SFM state, during the magnetization process, occurs critically. The value of the field of critical transition to the homogeneous state depends on the demagnetization field, granular anisotropy and interparticle exchange anisotropy. It turned out that the temperature dependence of the coercive force of the film, despite its SFM state, accords with the Neel–Brown formula for anisotropic single-domain ferromagnetic particles, but has an anomalous angular dependence. It was concluded that domain wall motion affects these features of the coercive field. The domain wall movement may occur due to the overturn of magnetic moments of particles in the boundaries between the superdomains. At the same time, the main factors influencing the coercivity are the anisotropy of the particles, which blocks their magnetic moment reorientation, and demagnetizing factor of the film. Together they lead to the anomalous angular dependence of the coercive field. - Highlights: • The transition from the multidomain SFM to homogeneous SFM state occurs critically. • The value of the critical field depends on the direction of the magnetizing field. • Critical transition field depends on the anisotropy of the interparticle exchange. • Dependence of H c (θ H ) differs from expected one for an ensemble of the particles. • Magnetization reversal occurs by turning the particle's moments in domain borders.

Four-fold magnetic anisotropy in a Co film on MgO(0 0 1)

International Nuclear Information System (INIS)

Pires, M.J.M.; Cotta, A.A.C.; Martins, M.D.; Silva, A.M.A.; Macedo, W.A.A.

2011-01-01

The development of devices based on magnetic tunnel junctions has raised new interests on the structural and magnetic properties of the interface Co/MgO. In this context, we have grown ultrathin Co films (≤30 A) by molecular-beam epitaxy on MgO(0 0 1) substrates kept at different temperatures (T S ). Their structural and magnetic properties were correlated and discussed in the context of distinct magnetic anisotropies for Co phases reported in the literature. The sample characterization has been done by reflection high energy electron diffraction, magneto-optical Kerr effect and ferromagnetic resonance. The main focus of the work is on a sample deposited at T S =25 o C, as its particular way of growth has enabled a bct Co structure to settle on the substrate, where it is not normally obtained without specific seed layers. This sample presented the best crystallinity, softer magnetic properties and a four-fold in-plane magnetic anisotropy with Co easy directions. Concerning the samples prepared at T S =200 and 500 o C, they show fcc and polycrystalline structures, respectively and more intricate magnetic anisotropy patterns. - Research Highlights: →Results suggest the lattice is already after the Bain transformation for T S =25 o C, and the Co film has a bct structure instead of an fct one. →For deposition temperature of T S =25 o C, a four-fold in-plane magnetic anisotropy with Co easy directions has been obtained. →The growth mode of Co on MgO single crystals at different temperatures resulted in bct Co at T S =25 o C, fcc Co at T S =200 o C and polycrystalline Co at T S =500 o C.

Molecular anisotropy effects in carbon K-edge scattering: depolarized diffuse scattering and optical anisotropy

Energy Technology Data Exchange (ETDEWEB)

Stone, Kevin H.

2014-07-14

Some polymer properties, such as conductivity, are very sensitive to short- and intermediate-range orientational and positional ordering of anisotropic molecular functional groups, and yet means to characterize orientational order in disordered systems are very limited. We demonstrate that resonant scattering at the carbon K-edge is uniquely sensitive to short-range orientation correlations in polymers through depolarized scattering at high momentum transfers, using atactic polystyrene as a well-characterized test system. Depolarized scattering is found to coexist with unpolarized fluorescence, and to exhibit pronounced anisotropy. We also quantify the spatially averaged optical anisotropy from low-angle reflectivity measurements, finding anisotropy consistent with prior visible, x-ray absorption, and theoretical studies. The average anisotropy is much smaller than that in the depolarized scattering and the two have different character. Both measurements exhibit clear spectral signatures from the phenyl rings and the polyethylene-like backbone. Discussion focuses on analysis considerations and prospects for using this depolarized scattering for studies of disorder in soft condensed matter.

Magnetic anisotropy considerations in magnetic force microscopy studies of single superparamagnetic nanoparticles

International Nuclear Information System (INIS)

Nocera, Tanya M; Agarwal, Gunjan; Chen Jun; Murray, Christopher B

2012-01-01

In recent years, superparamagnetic nanoparticles (SPNs) have become increasingly important in applications ranging from solid state memory devices to biomedical diagnostic and therapeutic tools. However, detection and characterization of the small and unstable magnetic moment of an SPN at the single particle level remains a challenge. Further, depending on their physical shape, crystalline structure or orientation, SPNs may also possess magnetic anisotropy, which can govern the extent to which their magnetic moments can align with an externally applied magnetic field. Here, we demonstrate how we can exploit the magnetic anisotropy of SPNs to enable uniform, highly-sensitive detection of single SPNs using magnetic force microscopy (MFM) in ambient air. Superconducting quantum interference device magnetometry and analytical transmission electron microscopy techniques are utilized to characterize the collective magnetic behavior, morphology and composition of the SPNs. Our results show how the consideration of magnetic anisotropy can enhance the ability of MFM to detect single SPNs at ambient room temperature with high force sensitivity and spatial resolution. (paper)

Magnetic anisotropy and quantized spin waves in hematite nanoparticles

DEFF Research Database (Denmark)

Klausen, Stine Nyborg; Lefmann, Kim; Lindgård, Per-Anker

2004-01-01

We report on the observation of high-frequency collective magnetic excitations, (h) over bar omegaapproximate to1.1 meV, in hematite (alpha-Fe2O3) nanoparticles. The neutron scattering experiments include measurements at temperatures in the range 6-300 K and applied fields up to 7.5 T as well...... as polarization analysis. We give an explanation for the field- and temperature dependence of the excitations, which are found to have strongly elliptical out-of-plane precession. The frequency of the excitations gives information on the magnetic anisotropy constants in the system. We have in this way determined...

Proton-rich nuclear statistical equilibrium

International Nuclear Information System (INIS)

Seitenzahl, I.R.; Timmes, F.X.; Marin-Lafleche, A.; Brown, E.; Magkotsios, G.; Truran, J.

2008-01-01

Proton-rich material in a state of nuclear statistical equilibrium (NSE) is one of the least studied regimes of nucleosynthesis. One reason for this is that after hydrogen burning, stellar evolution proceeds at conditions of an equal number of neutrons and protons or at a slight degree of neutron-richness. Proton-rich nucleosynthesis in stars tends to occur only when hydrogen-rich material that accretes onto a white dwarf or a neutron star explodes, or when neutrino interactions in the winds from a nascent proto-neutron star or collapsar disk drive the matter proton-rich prior to or during the nucleosynthesis. In this Letter we solve the NSE equations for a range of proton-rich thermodynamic conditions. We show that cold proton-rich NSE is qualitatively different from neutron-rich NSE. Instead of being dominated by the Fe-peak nuclei with the largest binding energy per nucleon that have a proton-to-nucleon ratio close to the prescribed electron fraction, NSE for proton-rich material near freezeout temperature is mainly composed of 56Ni and free protons. Previous results of nuclear reaction network calculations rely on this nonintuitive high-proton abundance, which this Letter explains. We show how the differences and especially the large fraction of free protons arises from the minimization of the free energy as a result of a delicate competition between the entropy and nuclear binding energy.

Planck intermediate results: XLVIII. Disentangling Galactic dust emission and cosmic infrared background anisotropies

DEFF Research Database (Denmark)

Aghanim, N.; Ashdown, M.; Aumont, J.

2016-01-01

Using the Planck 2015 data release (PR2) temperature maps, we separate Galactic thermal dust emission from cosmic infrared background (CIB) anisotropies. For this purpose, we implement a specifically tailored component-separation method, the so-called generalized needlet internal linear combinati...

Magnetic anisotropy of Ni/Cr multilayers

International Nuclear Information System (INIS)

Kang, S.; Xia, H.

1997-01-01

The magnetic anisotropy of Ni/Cr multilayers has been investigated by using vibrating sample magnetometer (VSM) and ferromagnetic resonance techniques (FMR). The FMR spectra are obtained as a function of the orientation of the applied magnetic field from in-plane to out-of-plane. The results are fitted theoretically to determine the magnetic anisotropy. From VSM and FMR, a positive value for Ni/Cr interface anisotropy is obtained, which favours a perpendicular easy axis. The possible mechanism for the perpendicular anisotropy has been discussed and it may be attributed to the magnetostriction, caused by intrinsic stress due to lattice mismatch. (orig.). With 005 figs., 001 tabs

Influence of non-bi-maxwellian distribution function of solar wind protons on the ion cyclotron instability

International Nuclear Information System (INIS)

Leubner, M.P.

1978-01-01

Satellite measurements of the thermal anisotropy of solar wind protons have shown that the particle velocity distributions at 1 AU are not adequately described by a bi-Maxwellian distribution function. On the other hand, the stability criteria derived from a bi-Maxwellian distribution require T/sub perpendicular/>T/sub parallel/, which is, however, hardly ever observed. A modified axisymmetric distribution function for solar wind protons is used here to calculate the stability and growth rate of the iom cyclotron instability in a warm slow speed solar plasma at 1 AU. Cyclotron wave growth is found also in the case t/sub parallel/>T/sub perpendicular/

Study of the high energy Cosmic Rays large scale anisotropies with the ANTARES neutrino telescope

International Nuclear Information System (INIS)

Illuminati, Giulia

2016-01-01

We present the analysis method used to search for an anisotropy in the high energy Cosmic Rays arrival distribution using data collected by the ANTARES telescope. ANTARES is a neutrino detector, where the collected data are dominated by a large background of cosmic ray muons. Therefore, the background data are suitable for high-statistics studies of cosmic rays in the Northern sky. The main challenge for this analysis is accounting for those effects which can mimic an apparent anisotropy in the muon arrival direction: the detector exposure asymmetries, non-uniform time coverage, diurnal and seasonal variation of the atmospheric temperature. Once all these effects have been corrected, a study of the anisotropy profiles along the right ascension can be performed. (paper)

Magnetic properties of magnetic liquids with iron-oxide particles - the influence of anisotropy and interactions

DEFF Research Database (Denmark)

Johansson, C.; Hanson, M.; Pedersen, Michael Stanley

1997-01-01

Magnetic liquids containing iron-oxide particles were investigated by magnetization and Mossbauer measurements. The particles were shown to be maghemite with a spontanious saturation magentization Ms = 320 kA m-1 at 200 K and a normalized high-field susceptibility x/M0 = 5.1x10-6 mkA-1, practically...... independent of temperature. Ms increases with decreasing temperature according to an effective Bloch law with an exponent larger than 1.5, as expected for fine magnetic particles. The model of magnetic particles with uniaxial anisotropy and the actual size distribution gives a consistent description...... of independent measurements of the temperature dependence of the hyperfine field and the isothermal magnetization versus field. From this an effective anisotropy constant of about 4.5x10 4 J m-3 is estimated for a particle with diameter 7.5 nm. The magnetic relaxation, as observed in zero...

In-situ Monitoring of Internal Local Temperature and Voltage of Proton Exchange Membrane Fuel Cells

Directory of Open Access Journals (Sweden)

Chi-Yuan Lee

2010-06-01

Full Text Available The distribution of temperature and voltage of a fuel cell are key factors that influence performance. Conventional sensors are normally large, and are also useful only for making external measurements of fuel cells. Centimeter-scale sensors for making invasive measurements are frequently unable to accurately measure the interior changes of a fuel cell. This work focuses mainly on fabricating flexible multi-functional microsensors (for temperature and voltage to measure variations in the local temperature and voltage of proton exchange membrane fuel cells (PEMFC that are based on micro-electro-mechanical systems (MEMS. The power density at 0.5 V without a sensor is 450 mW/cm2, and that with a sensor is 426 mW/cm2. Since the reaction area of a fuel cell with a sensor is approximately 12% smaller than that without a sensor, but the performance of the former is only 5% worse.

Protonic conduction of hydrogen impurities in K2OsCl6

International Nuclear Information System (INIS)

Willemsen, H.W.; Armstrong, R.L.; Meincke, P.P.M.

1979-01-01

Dielectric measurements as a function of temperature and frequency in single crystal K 2 OsCl 6 with defects containing protons are reported. The results are consistent with a model which assumes the defect state to be a simple interstitial proton which is hydrogen bonded to the nearest neighbor chlorine ions. Temperatures greater than 180 K shows that proton diffusion is thermally activated with a mobility of 10 -2 cm 2 /V-sec whereas below this temperature it is determined by quantum tunneling between localized states

High temperature tensile testing of modified 9Cr-1Mo after irradiation with high energy protons

International Nuclear Information System (INIS)

Toloczko, M.B.; Hamilton, M.L.; Maloy, S.A.

2003-01-01

This study examines the effect of tensile test temperatures ranging from 50 to 600 deg. C on the tensile properties of a modified 9Cr-1Mo ferritic steel after high energy proton irradiation at about 35-67 deg. C to doses from 1 to 3 dpa and 9 dpa. For the specimens irradiated to doses between 1 and 3 dpa, it was observed that the yield strength and ultimate strength decreased monotonically as a function of tensile test temperature, whereas the uniform elongation (UE) remained at approximately 1% for tensile test temperatures up to 250 deg. C and then increased for tensile test temperatures up to and including 500 deg. C. At 600 deg. C, the UE was observed to be less than the values at 400 and 500 deg. C. UE of the irradiated material tensile tested at 400-600 deg. C was observed to be greater than the values for the unirradiated material at the same temperatures. Tensile tests on the 9 dpa specimens followed similar trends

Observations of Solar Energetic Particle Anisotropies at MeV Energies from STEREO/LET

Science.gov (United States)

Leske, R. A.; Cummings, A. C.; Cohen, C.; Mewaldt, R. A.; Labrador, A. W.; Stone, E. C.; Wiedenbeck, M. E.; Christian, E. R.; von Rosenvinge, T. T.

2016-12-01

During the transport of solar energetic particles (SEPs) through interplanetary space, their pitch-angle distributions are modified by the competing effects of scattering and magnetic focusing. Thus, measurements of SEP anisotropies can reveal conditions such as magnetic field strength, topology, and turbulence levels at heliospheric locations far removed from the observer. Onboard each of the two STEREO spacecraft, the Low Energy Telescope (LET) measures angular distributions in the ecliptic for SEP protons, helium, and heavier ions up to iron with energies of about 2-12 MeV/nucleon. Anisotropies observed with this instrument include unidirectional outward beams at the onset of magnetically well-connected SEP events when particles experienced little scattering, bidirectional flows within many interplanetary coronal mass ejections, sunward particle flows when the spacecraft was magnetically connected to the back side of a shock, and loss-cone distributions when particles with large pitch angles were magnetically mirrored at a remote field enhancement that was too weak to reflect particles with the smallest pitch angles. Observations at a 1-minute cadence also revealed peculiar oscillations in the width of a beamed distribution at the onset of the 23 July 2012 extreme SEP event. The shapes of the pitch angle distributions often vary with energy and differ for H, He, and heavier species, perhaps as a result of rigidity dependence of the pitch angle diffusion coefficient. We present a selection of the more interesting LET anisotropy observations made throughout solar cycle 24 and discuss the implications of these observations for SEP transport in the heliosphere.

CeCo5 thin films with perpendicular anisotropy grown by molecular beam epitaxy

Science.gov (United States)

Sharma, S.; Hildebrandt, E.; Major, M.; Komissinskiy, P.; Radulov, I.; Alff, L.

2018-04-01

Buffer-free, highly textured (0 0 1) oriented CeCo5 thin films showing perpendicular magnetic anisotropy were synthesized on (0 0 1) Al2O3 substrates by molecular beam epitaxy. Ce exists in a mixture of Ce3+ and Ce4+ valence states as shown by X-ray photoelectron spectroscopy. The first anisotropy constant, K1, as measured by torque magnetometry was 0.82 MJ/m3 (8.2 ×106erg /cm3) . A maximum coercivity of 5.16 kOe with a negative temperature coefficient of -0.304%K-1 and a magnetization of 527.30 emu/cm3 was measured perpendicular to the film plane at 5 K. In addition, a large anisotropy of the magnetic moment of 15.5% was observed. These magnetic parameters make CeCo5 a potential candidate material for spintronic and magnetic recording applications.

PREFACE: Transport phenomena in proton conducting media Transport phenomena in proton conducting media

Science.gov (United States)

Eikerling, Michael

2011-06-01

, charge-bearing species at interfaces and porous host materials on proton transport properties. As a common thread, articles in this special issue contribute to understanding the functionality provided by complex materials, beyond hydrogen bond fluctuations in water. The first group of articles (Smirnov et al, Henry et al, Medvedev and Stuchebrukhov) elucidates various aspects of the impact of local structural fluctuations, hydrogen bonding and long-range electrostatic forces on proton transfer across and at the surface of mitochondrial membranes. The second group of articles (Ilhan and Spohr, Allahyarov et al and Idupulapati et al) employ molecular dynamics simulations to rationalize vital dependencies of proton transport mechanisms in aqueous-based polymer electrolyte membranes on the nanoporous, phase-separated ionomer morphology, and on the level of hydration. The articles by Gebel et al, Boillat et al, and Aleksandrova et al employ small angle neutron scattering, neutron radiography, and electrochemical atomic force microscopy, respectively, to obtain detailed insights into the kinetics of water sorption, water distribution, water transport properties, as well as spatial maps of proton conductivity in fuel cell membranes. The contribution of Paschos et al provides a comprehensive review of phosphate-based solid state protonic conductors for intermediate temperature fuel cells. The topic of proton conductive materials for high-temperature, water-free operation of fuel cells is continued in the article of Verbraeken et al which addresses synthesis and characterization of a proton conducting perovskite. The guest editor wishes to acknowledge and thank all contributing authors for their commitment to this special issue. Moreover, I would like to thank the staff at IOP Publishing for coordinating submission and refereeing processes. Finally, for the readers, I hope that this special issue will be a valuable and stimulating source of insights into the versatile and

Improved Electrodes for High Temperature Proton Exchange Membrane Fuel Cells using Carbon Nanospheres.

Science.gov (United States)

Zamora, Héctor; Plaza, Jorge; Cañizares, Pablo; Lobato, Justo; Rodrigo, Manuel A

2016-05-23

This work evaluates the use of carbon nanospheres (CNS) in microporous layers (MPL) of high temperature proton exchange membrane fuel cell (HT-PEMFC) electrodes and compares the characteristics and performance with those obtained using conventional MPL based on carbon black. XRD, hydrophobicity, Brunauer-Emmett-Teller theory, and gas permeability of MPL prepared with CNS were the parameters evaluated. In addition, a short life test in a fuel cell was carried out to evaluate performance under accelerated stress conditions. The results demonstrate that CNS is a promising alternative to traditional carbonaceous materials because of its high electrochemical stability and good electrical conductivity, suitable to be used in this technology. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Upper critical field and superconducting anisotropy of BaFe2-xRuxAs2 (x=0.48 and 0.75) single crystals

International Nuclear Information System (INIS)

Jo, Youn Jung; Eom, Man Jin; Kim, Jun Sung; Kang, W.

2014-01-01

The upper critical field (H c 2 ) was determined by applying a magnetic field along the ab plane and c axis for two single crystals of BaFe 2-x Ru x As 2 (x=0.48 and 0.75). The anisotropy of the H c 2 (0), γ(0)=H c 2 ab (0)/H c 2 c (0), was ∼1.6 for x=0.48 and ∼2.3 for x=0.75. The angle-dependent resistance measured below T c allowed perfect scaling features based on anisotropic Ginzburg-Landau theory, leading to consistent anisotropy values. Because only one fitting parameter γ is used in the scaling for each temperature, the validity of the γ value was compared with that determined from γ=H c 2 ab /H c 2 c . The γ obtained at a temperature close to Tc was 3.0 and decreased to 2.0 at low temperatures. Comparing to the anisotropy determined for electron- or hole-doped BaFe 2 As 2 using the same method, the present results point to consistent anisotropy in Ru-doped BaFe 2 As 2 with other electron- or hole-doped BaFe 2 As 2 .

The Cosmic Microwave Background Anisotropy

Science.gov (United States)

Bennett, C. L.

1994-12-01

The properties of the cosmic microwave background radiation provide unique constraints on the history and evolution of the universe. The first detection of anisotropy of the microwave radiation was reported by the COBE Team in 1992, based on the first year of flight data. The latest analyses of the first two years of COBE data are reviewed in this talk, including the amplitude of the microwave anisotropy as a function of angular scale and the statistical nature of the fluctuations. The two-year results are generally consistent with the earlier first year results, but the additional data allow for a better determination of the key cosmological parameters. In this talk the COBE results are compared with other observational anisotropy results and directions for future cosmic microwave anisotropy observations will be discussed. The National Aeronautics and Space Administration/Goddard Space Flight Center (NASA/GSFC) is responsible for the design, development, and operation of the Cosmic Background Explorer (COBE). Scientific guidance is provided by the COBE Science Working Group.

Anisotropy of the cosmic background radiation

International Nuclear Information System (INIS)

Silk, J.

1988-01-01

The characteristics of the cosmic microwave background radiation (CBR) are reviewed, focusing on intrinsic anisotropies caused by primordial matter fluctuations. The basic elements of the CBR are outlined and the contributions to anisotropy at different angular scales are discussed. Possible fluctuation spectra that can generate the observed large-scale structure of the universe through gravitational instability and nonlinear evolution are examined and compared with observational searches for cosmic microwave anisotropies. 21 refs

Organic chemistry in ambient temperature chloroaluminate melts. I. Protonation of arenes

International Nuclear Information System (INIS)

Dworkin, A.S.; Smith, G.P.; ZIngg, S.P.; Pagni, R.M.

1987-01-01

Acidic chloroaluminates are the quintessential Friedel-Crafts catalysts. Many of the reactions that they activate are of the carbenium-ion-chain type. In the case of arene (ArH) substrates a key step is the partial protonation of ArH by a protic acid (HB) as shown in Eq. 1 , where B- is a generic base and ArH/sub 2//sup +/ is the protonated arene or arenium ion. The apparent role of the acidic chloroaluminate is the ArH + HB ↔ ArH/sub 2//sup +/ + B/sup -/. Enhancement of the protonating strength of HB through the reaction of acidic chloroaluminate species, such as Al/sub 2/Cl/sub 6/, Al/sub 3/Cl/sub 7/- or Al/sub 3/Cl/sub 10-/., with the base B/sub -/. The simplest example of HB is HCl for which the overall protonating reaction is given in Eq. 2, where ArH + HCl + Al/sub 2/Cl/sub 7/- ↔ ArH/sub 2/+ + 2AlCl/sub 4/- Al/sub 2/Cl/sub 7/- represents the acidic chloroalmuniate

Design of an optical thermal sensor for proton exchange membrane fuel cell temperature measurement using phosphor thermometry

Science.gov (United States)

Inman, Kristopher; Wang, Xia; Sangeorzan, Brian

Internal temperatures in a proton exchange membrane (PEM) fuel cell govern the ionic conductivities of the polymer electrolyte, influence the reaction rate at the electrodes, and control the water vapor pressure inside the cell. It is vital to fully understand thermal behavior in a PEM fuel cell if performance and durability are to be optimized. The objective of this research was to design, construct, and implement thermal sensors based on the principles of the lifetime-decay method of phosphor thermometry to measure temperatures inside a PEM fuel cell. Five sensors were designed and calibrated with a maximum uncertainty of ±0.6 °C. Using these sensors, surface temperatures were measured on the cathode gas diffusion layer of a 25 cm 2 PEM fuel cell. The test results demonstrate the utility of the optical temperature sensor design and provide insight into the thermal behavior found in a PEM fuel cell.

Transverse susceptibility as a probe of the magnetocrystalline anisotropy-driven phase transition in Pr0.5Sr0.5CoO3

Science.gov (United States)

Frey Huls, N. A.; Bingham, N. S.; Phan, M. H.; Srikanth, H.; Stauffer, D. D.; Leighton, C.

2011-01-01

Half-doped Pr1-xSrxCoO3 (x=0.5) displays anomalous magnetism, most notably manifest in the field-cooled magnetization versus temperature curves under different applied cooling fields. Recently, an explanation was advanced that a magnetocrystalline anisotropy transition driven by a structural transition at 120 K is the origin of this behavior. In this paper, we further elucidate the nature of the magnetic anisotropy across the low-temperature phase transition in this material by means of transverse susceptibility (TS) measurements performed using a self-resonant tunnel diode oscillator. TS probes magnetic materials by means of a small radio frequency oriented transverse to a dc field that sweeps from positive to negative saturation. TS scans as a function of field clearly reveal peaks associated with the anisotropy (HK) and switching fields (HS). When peak position is examined as a function of temperature, ˜120 K the signature of a ferromagnetic-to-ferromagnetic phase transition is evident as a sharp feature in HK and a corresponding cusp in HS. A third TS peak (not previously observed in other classes of magnetic oxides such as manganites and spinel ferrites) is found to be correlated with the crossover field (Hcr) in the unconventional magnetization versus temperature [M(T)] behavior. We observe a strong temperature dependence of Hcr at ˜120 K using this technique, which suggests the magnetic-field-influenced magnetocrystalline anisotropy transition. We show the switching between the high-field magnetization state and the low-field magnetization state associated with the magnetocrystalline anisotropy transition is irreversible when the magnetic field is recycled. Finally, we demonstrate that the TS peak magnitude indicates easy axis switching associated with this phase transition, even in these polycrystalline samples. Our results further confirm that TS provides new insights into the magnetic behavior of complex oxides.

Non-typical fluorescence studies of excited and ground state proton and hydrogen transfer

KAUST Repository

Gil, Michał; Kijak, Michał; Piwonski, Hubert Marek; Herbich, Jerzy; Waluk, Jacek

2017-01-01

Fluorescence studies of tautomerization have been carried out for various systems that exhibit single and double proton or hydrogen translocation in various environments, such as liquid and solid condensed phases, ultracold supersonic jets, and finally, polymer matrices with single emitters.We focus on less explored areas of application of fluorescence for tautomerization studies, using porphycene, a porphyrin isomer, as an example. Fluorescence anisotropy techniques allow investigations of self-exchange reactions, where the reactant and product are formally identical. Excitation with polarized light makes it possible to monitor tautomerization in single molecules and to detect their three-dimensional orientation. Analysis of fluorescence from single vibronic levels of jet-isolated porphycene not only demonstrates coherent tunneling of two internal protons, but also indicates that the process is vibrational mode-specific. Next, we present bifunctional proton donoracceptor systems, molecules that are able, depending on the environment, to undergo excited state single intramolecular or double intermolecular proton transfer. For molecules that have donor and acceptor groups located in separate moieties linked by a single bond, excited state tautomerization can be coupled to mutual twisting of the two subunits.

Non-typical fluorescence studies of excited and ground state proton and hydrogen transfer

KAUST Repository

Gil, Michał

2017-02-03

Fluorescence studies of tautomerization have been carried out for various systems that exhibit single and double proton or hydrogen translocation in various environments, such as liquid and solid condensed phases, ultracold supersonic jets, and finally, polymer matrices with single emitters.We focus on less explored areas of application of fluorescence for tautomerization studies, using porphycene, a porphyrin isomer, as an example. Fluorescence anisotropy techniques allow investigations of self-exchange reactions, where the reactant and product are formally identical. Excitation with polarized light makes it possible to monitor tautomerization in single molecules and to detect their three-dimensional orientation. Analysis of fluorescence from single vibronic levels of jet-isolated porphycene not only demonstrates coherent tunneling of two internal protons, but also indicates that the process is vibrational mode-specific. Next, we present bifunctional proton donoracceptor systems, molecules that are able, depending on the environment, to undergo excited state single intramolecular or double intermolecular proton transfer. For molecules that have donor and acceptor groups located in separate moieties linked by a single bond, excited state tautomerization can be coupled to mutual twisting of the two subunits.

Spin waves in two-dimensional ferromagnet with large easy-plane anisotropy

International Nuclear Information System (INIS)

Fridman, Yu.A.; Spirin, D.V.

2002-01-01

Spin waves in easy-plane two-dimensional ferromagnet when anisotropy is much stronger than exchange are investigated. The spectra of magnons, the spin-spin and quadrupolar correlation functions have been derived. It is shown that in such a system there exist spin waves at low temperatures. Some properties of the quadrupolar ordering in ferromagnets are discussed

Crosslinking of polybenzimidazolemembranes by divinylsulfone post-treatment for high-temperature proton exchange membrane fuel cell applications

DEFF Research Database (Denmark)

Aili, David; Li, Qingfeng; Christensen, Erik

2011-01-01

Phosphoric acid-doped polybenzimidazole (PBI) has been suggested as a promising electrolyte for proton exchangemembrane fuel cells operating at temperatures up to 200 ◦C. This paper describes the development of a crosslinking procedure for PBI membranes by post-treatment with divinylsulfone....... The crosslinking chemistry was studied and optimized on a low-molecularweight model system and the results were used to optimize the crosslinking conditions of PBI membranes. The crosslinked membraneswere characterized with respect to chemical and physiochemical properties, showing improved mechanical strength...

Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy.

Science.gov (United States)

Pavlov, Alexander A; Savkina, Svetlana A; Belov, Alexander S; Nelyubina, Yulia V; Efimov, Nikolay N; Voloshin, Yan Z; Novikov, Valentin V

2017-06-19

High magnetic anisotropy is a key property of paramagnetic shift tags, which are mostly studied by NMR spectroscopy, and of single molecule magnets, for which magnetometry is usually used. We successfully employed both these methods in analyzing magnetic properties of a series of transition metal complexes, the so-called clathrochelates. A cobalt complex was found to be both a promising paramagnetic shift tag and a single molecule magnet because of it having large axial magnetic susceptibility tensor anisotropy at room temperature (22.5 × 10 -32 m 3 mol -1 ) and a high effective barrier to magnetization reversal (up to 70.5 cm -1 ). The origin of this large magnetic anisotropy is a negative value of zero-field splitting energy that reaches -86 cm -1 according to magnetometry and NMR measurements.

Coasting characteristic of the flywheel system under anisotropy effect of bulk high temperature superconductors

International Nuclear Information System (INIS)

Wu, J.F.; Li, Y.

2014-01-01

Highlights: • Coasting time was investigated from the point-view of HTS flywheel applications. • The coasting time of aligned growth section boundary pattern (AGSBP) is shorter than that of MGSBP. • The electric magnetic drag force with AGSBP is larger than that of MGSBP. • This result may also exist in the maglev guideline when the maglev train stops freely. - Abstract: High-temperature superconductors (HTSCs) array with aligned growth section boundary (GSB) pattern (AGSBP) exhibits larger levitation force and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP) has been studied in maglev train application (Zheng et al., 2013). This result maybe helpful and support a new way for the HTS bearing design for flywheel systems. So, in this paper, we further examine this growth anisotropy effect on the maglev performance of flywheel system. Levitation force and coasting time were investigated from the point-view of HTS flywheel applications. The GS/GSB alignment of AGSBP bulk HTSCs produces larger levitation force than that of MGSBP, but the coasting time is shorter than that of MGSBP, that is to say, the electric magnetic drag force with AGSBP is larger than that of MGSBP. This result may also exist in the maglev guideline when the maglev train stops freely

Coasting characteristic of the flywheel system under anisotropy effect of bulk high temperature superconductors

Energy Technology Data Exchange (ETDEWEB)

Wu, J.F., E-mail: wujf@ciomp.ac.cn; Li, Y.

2014-10-15

Highlights: • Coasting time was investigated from the point-view of HTS flywheel applications. • The coasting time of aligned growth section boundary pattern (AGSBP) is shorter than that of MGSBP. • The electric magnetic drag force with AGSBP is larger than that of MGSBP. • This result may also exist in the maglev guideline when the maglev train stops freely. - Abstract: High-temperature superconductors (HTSCs) array with aligned growth section boundary (GSB) pattern (AGSBP) exhibits larger levitation force and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP) has been studied in maglev train application (Zheng et al., 2013). This result maybe helpful and support a new way for the HTS bearing design for flywheel systems. So, in this paper, we further examine this growth anisotropy effect on the maglev performance of flywheel system. Levitation force and coasting time were investigated from the point-view of HTS flywheel applications. The GS/GSB alignment of AGSBP bulk HTSCs produces larger levitation force than that of MGSBP, but the coasting time is shorter than that of MGSBP, that is to say, the electric magnetic drag force with AGSBP is larger than that of MGSBP. This result may also exist in the maglev guideline when the maglev train stops freely.

Evidence for nanoscale two-dimensional Co clusters in CoPt{sub 3} films with perpendicular magnetic anisotropy

Energy Technology Data Exchange (ETDEWEB)

Cross, J O [Department of Physics, University of Washington, Seattle, WA 98195 (United States); Newville, M [Consortium for Advanced Radiation Sources, University of Chicago, Chicago, IL 60637 (United States); Maranville, B B; Hellman, F [Department of Physics, University of California at San Diego, La Jolla, CA 92093 (United States); Bordel, C [Department of Physics, University of California at Berkeley, CA 94720 (United States); Harris, V G, E-mail: cbordel@berkeley.ed [Department of Electrical and Computer Engineering, Northeastern University, Boston, MA 02115 (United States)

2010-04-14

The length scale of the local chemical anisotropy responsible for the growth-temperature-induced perpendicular magnetic anisotropy of face-centered cubic CoPt{sub 3} alloy films was investigated using polarized extended x-ray absorption fine structure (EXAFS). These x-ray measurements were performed on a series of four (111) CoPt{sub 3} films epitaxially grown on (0001) sapphire substrates. The EXAFS data show a preference for Co-Co pairs parallel to the film plane when the film exhibits magnetic anisotropy, and random chemical order otherwise. Furthermore, atomic pair correlation anisotropy was evidenced only in the EXAFS signal from the next neighbors to the absorbing Co atoms and from multiple scattering paths focused through the next neighbors. This suggests that the Co clusters are no more than a few atoms in extent in the plane and one monolayer in extent out of the plane. Our EXAFS results confirm the correlation between perpendicular magnetic anisotropy and two-dimensional Co segregation in CoPt{sub 3} alloy films, and establish a length scale on the order of 10 A for the Co clusters.

Proton temperature-anisotropy-driven instabilities in weakly collisional plasmas: Hybrid simulations

Czech Academy of Sciences Publication Activity Database

Hellinger, Petr; Trávníček, Pavel M.

2015-01-01

Roč. 81, č. 1 (2015), 305810103/1-305810103/14 ISSN 0022-3778 R&D Projects: GA ČR GAP209/12/2023 Grant - others:EU(XE) SHOCK Project No. 284515 Institutional support: RVO:67985815 ; RVO:68378289 Keywords : magnetic field * solar wind * mirror instability Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics; BL - Plasma and Gas Discharge Physics (UFA-U) Impact factor: 0.981, year: 2015

Proton temperature-anisotropy-driven instabilities in weakly collisional plasmas: Hybrid simulations

Czech Academy of Sciences Publication Activity Database

Hellinger, Petr; Trávníček, Pavel M.

2015-01-01

Roč. 81, č. 1 (2015), s. 1-14 ISSN 0022-3778 Institutional support: RVO:68378289 Keywords : magnetic-field * solar- wind * mirror instability * Langevin representation * Coulomb collisions * nonlinear-theory * fluid model * evolution * turbulence * threshold Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 0.981, year: 2015 http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=9525437

Anisoft - Advanced Treatment of Magnetic Anisotropy Data

Science.gov (United States)

Chadima, M.

2017-12-01

Since its first release, Anisoft (Anisotropy Data Browser) has gained a wide popularity in magnetic fabric community mainly due to its simple and user-friendly interface enabling very fast visualization of magnetic anisotropy tensors. Here, a major Anisoft update is presented transforming a rather simple data viewer into a platform offering an advanced treatment of magnetic anisotropy data. The updated software introduces new enlarged binary data format which stores both in-phase and out-of-phase (if measured) susceptibility tensors (AMS) or tensors of anisotropy of magnetic remanence (AMR) together with their respective confidence ellipses and values of F-tests for anisotropy. In addition to the tensor data, a whole array of specimen orientation angles, orientation of mesoscopic foliation(s) and lineation(s) is stored for each record enabling later editing or corrections. The input data may be directly acquired by AGICO Kappabridges (AMS) or Spinner Magnetometers (AMR); imported from various data formats, including the long-time standard binary ran-format; or manually created. Multiple anisotropy files can be combined together or split into several files by manual data selection or data filtering according to their values. Anisotropy tensors are conventionally visualized as principal directions (eigenvectors) in equal-area projection (stereoplot) together with a wide array of quantitative anisotropy parameters presented in histograms or in color-coded scatter plots showing mutual relationship of up to three quantitative parameters. When dealing with AMS in variable low fields, field-independent and field-dependent components of anisotropy can be determined (Hrouda 2009). For a group of specimens, individual principal directions can be contoured, or a mean tensor and respective confidence ellipses of its principal directions can be calculated using either the Hext-Jelinek (Jelinek 1978) statistics or the Bootstrap method (Constable & Tauxe 1990). Each graphical

Proton nuclear magnetic resonance study of water + t-butyl alcohol ...

African Journals Online (AJOL)

The water proton resonance initially shifts to higher frequencies (low fields) as the cosolvent is added to water, and the shift to higher frequency is strongly temperature dependent, the effect being greatly enhanced at lower temperatures. As the proportion of cosolvent increases the hydroxyl proton signals in the water + ...

What does anisotropy measure? Insights from increased and decreased anisotropy in selective fiber tracts in schizophrenia.

Directory of Open Access Journals (Sweden)

Gabriel A De Erausquin

2013-03-01

Full Text Available Schizophrenia is a common, severe and chronically disabling mental illness of unknown cause. Recent MRI studies have focused attention on white matter abnormalities in schizophrenia using diffusion tensor imaging (DTI. Indices commonly derived from DTI include (a mean diffusivity, independent of direction, (b fractional anisotropy (FA or relative anisotropy (RA, (c axial diffusivity, and (d radial diffusivity. In cerebral white matter, contributions to these indices come from fiber arrangements, degree of myelination, and axonal integrity. Relatively pure deficits in myelin result in a modest increase in radial diffusivity, without affecting axial diffusivity and with preservation of anisotropy. Although schizophrenia is not characterized by gross abnormalities of white matter, it does involve a profound dysregulation of myelin-associated gene expression, reductions in oligodendrocyte numbers, and marked abnormalities in the ultrastructure of myelin sheaths. Since each oligodendrocyte myelinates as many as 40 axon segments, changes in the number of oligodendrocytes, and/or in the integrity of myelin sheaths, and/or axoglial contacts can have a profound impact on signal propagation and the integrity of neuronal circuits. Whereas a number of studies have revealed inconsistent decreases in anisotropy in schizophrenia, we and others have found increased fractional anisotropy in key subcortical tracts associated with the circuits underlying symptom generation in schizophrenia. We review data revealing increased anisotropy in dopaminergic tracts in the mesencephalon of schizophrenics and their unaffected relatives, and discuss the possible biological underpinnings and physiological significance of this finding.

Proton-bound cluster ions in ion mobility spectrometry

Science.gov (United States)

Ewing, R. G.; Eiceman, G. A.; Stone, J. A.

1999-01-01

Gaseous oxygen and nitrogen bases, both singly and as binary mixtures, have been introduced into ion mobility spectrometers to study the appearance of protonated molecules, and proton-bound dimers and trimers. At ambient temperature it was possible to simultaneously observe, following the introduction of molecule A, comparable intensities of peaks ascribable to the reactant ion (H2O)nH+, the protonated molecule AH+ and AH+ H2O, and the symmetrical proton bound dimer A2H+. Mass spectral identification confirmed the identifications and also showed that the majority of the protonated molecules were hydrated and that the proton-bound dimers were hydrated to a much lesser extent. No significant peaks ascribable to proton-bound trimers were obtained no matter how high the sample concentration. Binary mixtures containing molecules A and B, in some cases gave not only the peaks unique to the individual compounds but also peaks due to asymmetrical proton bound dimers AHB+. Such ions were always present in the spectra of mixtures of oxygen bases but were not observed for several mixtures of oxygen and nitrogen bases. The dimers, which were not observable, notable for their low hydrogen bond strengths, must have decomposed in their passage from the ion source to the detector, i.e. in a time less than approximately 5 ms. When the temperature was lowered to -20 degrees C, trimers, both homogeneous and mixed, were observed with mixtures of alcohols. The importance of hydrogen bond energy, and hence operating temperature, in determining the degree of solvation of the ions that will be observed in an ion mobility spectrometer is stressed. The possibility is discussed that a displacement reaction involving ambient water plays a role in the dissociation.

Intermediate Temperature Proton Conductors – Why and How

DEFF Research Database (Denmark)

Li, Qingfeng; Aili, David; Jensen, Jens Oluf

represented by early fundamental material research for ionic electrolytes. Such materials, most likely based on proton conductors, are expected to bring a new generation of the technologies: fuel cells by direct oxidation or internal splitting of biofuels such as methanol and ethanol, as well as efficient...

Anisotropy properties of the quartzite from Jegłowa, Poland

Science.gov (United States)

Marciniszyn, Tomasz; Sieradzki, Adam

2013-06-01

Marciniszyn, T. and Sieradzki, A. 2013. Anisotropy properties of the quartzite from Jegłowa, Poland. Acta Geologica Polonica, 63 (2), 265-269. Warszawa. Results of the dielectric spectroscopy, thermal and dilatometric measurements of the quartzite rock are presented. Based on the dielectric measurements performed in a wide range of the frequency (101 - 5 × 107 Hz) at temperature of 300K the piezoresonance in quartzite was found. A chemical composition of quartzite was examined by XRF. The anisotropy of the thermal conductivity was observed. The thermal conductivity coefficient changes from 13.2 [W/Km] to 5.6 [W/Km] for the [100] and [001] direction, respectively. Based on the thermal expansion measurement the thermal expansion coefficient of quartzite was estimated to be α Q = 8.0 × 10-6 [K-1 ] ±0.7 × 10-6 .

On the Relationship of Magnetocrystalline Anisotropy and Stoichiometry in Epitaxial L1{sub 0} CoPt(001) and FePt(001) Thin Films

Energy Technology Data Exchange (ETDEWEB)

Barmak, K

2004-08-10

Two series of epitaxial CoPt and FePt films, with nominal thicknesses of 42 or 50 nm, were prepared by sputtering onto single crystal MgO(001) substrates in order to investigate the chemical ordering and the resultant magnetic properties as a function of alloy composition. In the first series, the film composition was kept constant, while the substrate temperature was increased from 144 to 704 C. In the second series the substrate temperature was kept constant at 704 C for CoPt and 620 C for FePt, while the alloy stoichiometry was varied in the nominalrange of 40-60 at% Co(Fe). Film compositions and thicknesses were measured via Rutherford backscattering spectrometry. The lattice and long-range order parameter for the L1{sub 0} phase were obtained for both sets of films using x-ray diffraction. The room-temperature magnetocrystalline anisotropy constants were determined for a subset of the films using torque magnetometry. The order parameter was found to increase with increasing temperature, with ordering occurring more readily in FePt when compared with CoPt. A perpendicular anisotropy developed in CoPt for substrate temperatures above 534 C and in FePt above 321 C. The structure and width of the magnetic domains in CoPt and FePt, as seen by magnetic force microscopy, also demonstrated an increase in magnetic anisotropy with increasing temperature. For the films deposited at the highest temperatures (704 C for CoPt and 620 C for FePt), the order parameter reached a maximum near the equiatomic composition, whereas the magnetocrystalline anisotropy increased as the concentration of Co or Fe was increased from below to slightly above the equiatomic composition. It is concluded that non-stoichiometric L1{sub 0} CoPt and FePt, with a slight excess of Co or Fe, are preferable for applications requiring the highest anisotropies.

Modeling elastic anisotropy in strained heteroepitaxy.

Science.gov (United States)

Dixit, Gopal Krishna; Ranganathan, Madhav

2017-09-20

Using a continuum evolution equation, we model the growth and evolution of quantum dots in the heteroepitaxial Ge on Si(0 0 1) system in a molecular beam epitaxy unit. We formulate our model in terms of evolution due to deposition, and due to surface diffusion which is governed by a free energy. This free energy has contributions from surface energy, curvature, wetting effects and elastic energy due to lattice mismatch between the film and the substrate. In addition to anisotropy due to surface energy which favors facet formation, we also incorporate elastic anisotropy due to an underlying crystal lattice. The complicated elastic problem of the film-substrate system subjected to boundary conditions at the free surface, interface and the bulk substrate is solved by perturbation analysis using a small slope approximation. This permits an analysis of effects at different orders in the slope and sheds new light on the observed behavior. Linear stability analysis shows the early evolution of the instability towards dot formation. The elastic anisotropy causes a change in the alignment of dots in the linear regime, whereas the surface energy anisotropy changes the dot shapes at the nonlinear regime. Numerical simulation of the full nonlinear equations shows the evolution of the surface morphology. In particular, we show, for parameters of the [Formula: see text] [Formula: see text] on Si(0 0 1), the surface energy anisotropy dominates the shapes of the quantum dots, whereas their alignment is influenced by the elastic energy anisotropy. The anisotropy in elasticity causes a further elongation of the islands whose coarsening is interrupted due to [Formula: see text] facets on the surface.

Modeling elastic anisotropy in strained heteroepitaxy

Science.gov (United States)

Krishna Dixit, Gopal; Ranganathan, Madhav

2017-09-01

Using a continuum evolution equation, we model the growth and evolution of quantum dots in the heteroepitaxial Ge on Si(0 0 1) system in a molecular beam epitaxy unit. We formulate our model in terms of evolution due to deposition, and due to surface diffusion which is governed by a free energy. This free energy has contributions from surface energy, curvature, wetting effects and elastic energy due to lattice mismatch between the film and the substrate. In addition to anisotropy due to surface energy which favors facet formation, we also incorporate elastic anisotropy due to an underlying crystal lattice. The complicated elastic problem of the film-substrate system subjected to boundary conditions at the free surface, interface and the bulk substrate is solved by perturbation analysis using a small slope approximation. This permits an analysis of effects at different orders in the slope and sheds new light on the observed behavior. Linear stability analysis shows the early evolution of the instability towards dot formation. The elastic anisotropy causes a change in the alignment of dots in the linear regime, whereas the surface energy anisotropy changes the dot shapes at the nonlinear regime. Numerical simulation of the full nonlinear equations shows the evolution of the surface morphology. In particular, we show, for parameters of the Ge0.25 Si0.75 on Si(0 0 1), the surface energy anisotropy dominates the shapes of the quantum dots, whereas their alignment is influenced by the elastic energy anisotropy. The anisotropy in elasticity causes a further elongation of the islands whose coarsening is interrupted due to facets on the surface.

Perpendicular magnetic anisotropy in granular multilayers of CoPd alloyed nanoparticles

Science.gov (United States)

Vivas, L. G.; Rubín, J.; Figueroa, A. I.; Bartolomé, F.; García, L. M.; Deranlot, C.; Petroff, F.; Ruiz, L.; González-Calbet, J. M.; Pascarelli, S.; Brookes, N. B.; Wilhelm, F.; Chorro, M.; Rogalev, A.; Bartolomé, J.

2016-05-01

Co-Pd multilayers obtained by Pd capping of pre-deposited Co nanoparticles on amorphous alumina are systematically studied by means of high-resolution transmission electron microscopy, x-ray diffraction, extended x-ray absorption fine structure, SQUID-based magnetometry, and x-ray magnetic circular dichroism. The films are formed by CoPd alloyed nanoparticles self-organized across the layers, with the interspace between the nanoparticles filled by the non-alloyed Pd metal. The nanoparticles show atomic arrangements compatible with short-range chemical order of L 10 strucure type. The collective magnetic behavior is that of ferromagnetically coupled particles with perpendicular magnetic anisotropy, irrespective of the amount of deposited Pd. For increasing temperature three magnetic phases are identified: hard ferromagnetic with strong coercive field, soft-ferromagnetic as in an amorphous asperomagnet, and superparamagnetic. Increasing the amount of Pd in the system leads to both magnetic hardness increment and higher transition temperatures. Magnetic total moments of 1.77(4) μB and 0.45(4) μB are found at Co and Pd sites, respectively, where the orbital moment of Co, 0.40(2) μB, is high, while that of Pd is negligible. The effective magnetic anisotropy is the largest in the capping metal series (Pd, Pt, W, Cu, Ag, Au), which is attributed to the interparticle interaction between de nanoparticles, in addition to the intraparticle anisotropy arising from hybridization between the 3 d -4 d bands associated to the Co and Pd chemical arrangement in a L 10 structure type.

Effect of composition on the degree of anisotropy of thermal expansion and electric resistance of cermet specimens of GeTe

International Nuclear Information System (INIS)

Barbakadze, K.G.; Vekua, T.S.; Ioseliani, M.I.; Kvitsiniya, K.M.

1988-01-01

A study was made on α temperature coefficient of thermal expansion and ρ specific electric resistance of cermet germanium telluride for alloys close to stoichiometric composition. It is shown that anisotropy of thermal expansion of cermet germanium telluride depends sufficiently on its composition. This dependence is clearly pronounced if tellurium content in alloys equals 50.4-51.2 at.%. The maximal anisotropy is observed in the alloy containing 50.8 at.% of tellurium. The temperature of extreme value of temperature coefficient of linear expansion decreases from 440 down to 373 deg.C for alloys with 49-50.8 at.% of tellurium, and grows from 373 up to 405 deg.C if tellurium content equals 50.8-52 at.%

Relative thermoluminescent efficiencies proton/gamma and helium/gamma of peaks of high temperature in TLD-100 dosemeters; Eficiencias termoluminiscentes relativas proton/gamma y helio/gamma de picos de alta temperatura en dosimetros TLD-100

Energy Technology Data Exchange (ETDEWEB)

Flores M, E. [UNAM, Facultad de Ciencias, 04510 Mexico D.F. (Mexico)

2007-07-01

The increase of the applications of ion beams in radiotherapy treatments has generated interest in the study of the thermoluminescent materials (TL) that allow to determine the applied doses. A way to quantify the TL response from these materials to ions is by means of the relative thermoluminescent efficiency. In the group of Thermoluminescent dosimetry of the Institute of Physics of the UNAM (IFUNAM) the thermoluminescent response of the TLD-100 dosemeters has been studied, which present a glow curve characteristic with several peaks that correspond to traps and luminescent centers in the material. The stable peaks know each other as 4, 5, 6a, 6b, 7, 8, 9 and 10. The efficiencies should be measured using the response so much to the radiation of interest (in this case protons and helium ions) as the response to gamma radiation. In previous works with ions of low energy taken place in the Pelletron accelerator of the IFUNAM was only measured the TL efficiency for the peak 5 and the total signal. It had not been possible to measure the efficiency of the peaks of high temperature (6a-10) because, for the gamma radiation, the peaks of high temperature show very small signals; however, recently Massillon carries out measures of efficiency TL of peaks of high temperature for ions of intermediate energy using a protocol special of reading and of deconvolution that allows to measure the signals coming from the peaks of high temperature. In this work is implemented this same protocol to complete the study of TL efficiencies at low energy of protons and helium and to determine if the values of efficiency depend on the used reading protocol. For it is reported it measures of the relative efficiency of the peaks of high temperature from the TLD-100 exposed to protons of 1.5 MeV and nuclei of helium of 3 and 7.5 MeV. (Author)

Present mantle flow in North China Craton constrained by seismic anisotropy and numerical modelling

Science.gov (United States)

Qu, W.; Guo, Z.; Zhang, H.; Chen, Y. J.

2017-12-01

North China Carton (NCC) has undergone complicated geodynamic processes during the Cenozoic, including the westward subduction of the Pacific plate to its east and the collision of the India-Eurasia plates to its southwest. Shear wave splitting measurements in NCC reveal distinct seismic anisotropy patterns at different tectonic blocks, that is, the predominantly NW-SE trending alignment of fast directions in the western NCC and eastern NCC, weak anisotropy within the Ordos block, and N-S fast polarization beneath the Trans-North China Orogen (TNCO). To better understand the origin of seismic anisotropy from SKS splitting in NCC, we obtain a high-resolution dynamic model that absorbs multi-geophysical observations and state-of-the-art numerical methods. We calculate the mantle flow using a most updated version of software ASPECT (Kronbichler et al., 2012) with high-resolution temperature and density structures from a recent 3-D thermal-chemical model by Guo et al. (2016). The thermal-chemical model is obtained by multi-observable probabilistic inversion using high-quality surface wave measurements, potential fields, topography, and surface heat flow (Guo et al., 2016). The viscosity is then estimated by combining the dislocation creep, diffusion creep, and plasticity, which is depended on temperature, pressure, and chemical composition. Then we calculate the seismic anisotropy from the shear deformation of mantle flow by DREX, and predict the fast direction and delay time of SKS splitting. We find that when complex boundary conditions are applied, including the far field effects of the deep subduction of Pacific plate and eastward escaping of Tibetan Plateau, our model can successfully predict the observed shear wave splitting patterns. Our model indicates that seismic anisotropy revealed by SKS is primarily resulting from the LPO of olivine due to the shear deformation from asthenospheric flow. We suggest that two branches of mantle flow may contribute to the

Preparation of ring-shaped composite bonded magnets with continuously controlled anisotropy distribution for internal space

International Nuclear Information System (INIS)

Yamashita, F; Yamada, O; Ohya, S; Kobayashi, O; Nakano, M; Fukunaga, H

2010-01-01

We have already reported an advanced method for producing a radially-anisotropic rare earth composite bonded magnet with continuously controlled direction of anisotropy. The magnet has been applied to an inner rotor as a practical usage. In this study, the outstanding preparation method was adopted into the preparation of a magnet applied for an outer rotor. An optimized condition of extrusion and compaction at an elevated temperature could be obtained. In addition, a low pressure configuration to the ring-shaped magnet from plural preformed magnets was carried out, which had specific distribution of magnetic anisotropy for internal space for a small motor, by using self recoverability based on the viscous deformation without an alignment field. No deterioration of magnetic properties was detected through the process even if those magnets were miniaturized. Resultantly, the (BH) max of a ring-shaped magnet with the continuously controlled direction of magnetic anisotropy attained the value of 186 kJ/m 3 , and we obtained sine-wave magnetic anisotropy distribution, even if those magnets were miniaturized.

Magnetic anisotropy in GaMnAs; Magnetische Anisotropie in GaMnAs

Energy Technology Data Exchange (ETDEWEB)

Daeubler, Joachim

2009-07-02

The goal of the present work was the detailed investigation of the impact of parameters like vertical strain, hole concentration, substrate orientation and patterning on the MA in GaMnAs. At first a method is introduced enabling us to determine the MA from angle-dependent magnetotransport measurements. This method was used to analyze the impact of vertical strain {epsilon}{sub zz} on the MA in a series of GaMnAs layers with a Mn content of 5% grown on relaxed InGaAs-templates. While hole concentration and Curie temperature were found to be unaffected by vertical strain, a significant dependence of the MA on {epsilon}{sub zz} was found. The most pronounced dependence was observed for the anisotropy parameter B{sub 2} {sub perpendicular} {sub to}, representing the intrinsic contribution to the MA perpendicular to the layer plane. For this parameter a linear dependence on {epsilon}{sub zz} was found, resulting in a strain-induced transition of the magnetic easy axis with increasing strain from in-plane to out-of-plane at {epsilon}{sub zz} {approx} -0.13%. Post-growth annealing of the samples leads to an outdiffusion and/or regrouping of the highly mobile Mn interstitial donor defects, resulting in an increase in both p and T{sub C}. For the annealed samples, the transition from in-plane to out-of-plane easy axis takes place at {epsilon}{sub zz} {approx} -0.07%. From a comparison of as-grown and annealed samples, B{sub 2} {sub perpendicular} {sub to} was found to be proportional to both p and {epsilon}{sub zz}, B{sub 2} {sub perpendicular} {sub to} {proportional_to} p .{epsilon}{sub zz}. To study the influence of substrate orientation on the magnetic properties of GaMnAs, a series of GaMnAs layers with Mn contents up to 5% was grown on (001)- and (113)A-oriented GaAs substrates. The hole densities and Curie temperatures, determined from magnetotransport measurements, are drastically reduced in the (113)A layers. The differences in the magnetic properties of (113)A- and

Influence of Sn on the optical anisotropy of single-domain Si(001)

International Nuclear Information System (INIS)

Astropekakis, A.; Power, J.R.; Fleischer, K.; Esser, N.; Richter, W.; Galata, S.; Papadimitriou, D.

2001-01-01

We apply reflectance anisotropy spectroscopy (RAS) and low-energy electron diffraction (LEED) to the study of Sn deposited on a single-domain vicinal Si(001) sample. Large variations in RAS are recorded when up to 5 monolayers (ML) of Sn is deposited on the Si substrate at room temperature. We observe (2x2) and (1x1) LEED patterns for the 0.5-ML and 1.0-ML Sn covered surfaces, respectively. The (1x1) LEED pattern exists beyond this coverage and up to 5.0-ML deposition. Even though a (1x1) LEED pattern is observed upon deposition of 1.5 ML, surprisingly, a significant optical anisotropy is observed. After annealing to 570 degree sign C for 2 min, we observe a progression of LEED pattern changes from c(4x4)→(6x2)→c(8x4)→(5x1) with increased Sn coverage up to 1.5 ML. Similar RAS line shapes are obtained for all reconstructions produced through annealing with the exception of the (5x1). For the (5x1) phase, a significant anisotropy appears in the region of 1.8 eV. Similarities in the RAS line shape for both the (5x1) phase and that obtained after deposition of 1.5 ML of Sn at room temperature may indicate a RAS sensitivity to Sn dimer orientation within the uppermost layer

Kinetics of proton transport in water

DEFF Research Database (Denmark)

Kornyshev, A.A.; Kuznetsov, A.M.; Spohr, E.

2003-01-01

for rationalizing the excess proton mobility, based on computer simulations, theory of proton transfer (PT) in condensed media, and analysis of classical proton conductivity experiments over broad temperature ranges. The mechanistic options involved are (i) classical hydrodynamic motion of the hydronium ion (H3O...... are brought into the framework of quantum mechanical PT theory in condensed media. Both the nature of the elementary act and the reaction coordinates are, however, different for the two types of PT clusters. The corresponding rate constants are calculated and compared with MD simulations. Within the framework...

Mapping the CMB with the Wilkinson Microwave Anisotropy Probe

Science.gov (United States)

Hinshaw, Gary F.

2007-01-01

The data from the Wilkinson Microwave Anisotropy Probe (WMAP) satellite provide detailed full-sky maps of the cosmic microwave background temperature anisotropy and new full-sky maps of the polarization. Together, the data provide a wealth of cosmological information, including the age of the universe, the epoch when the first stars formed, and the overall composition of baryonic matter, dark matter, and dark energy. The results also provide constraints on the period of inflationary expansion in the very first moments of time. These and other aspects of the mission results will be discussed and commented on. WMAP, part of NASA's Explorers program, was launched on June 30,200 1. The WMAP satellite was produced in a partnership between the Goddard Space Flight Center and Princeton University. The WMAP team also includes researchers at the Johns Hopkins University; the Canadian Institute of Theoretical Astrophysics; University of Texas; University of Chicago; Brown University; University of British Columbia; and University of California, Los Angeles.

Middle-energy electron anisotropies in the auroral region

Directory of Open Access Journals (Sweden)

P. Janhunen

2004-01-01

Full Text Available Field-aligned anisotropic electron distribution functions of T_∥ > T_⊥ type are observed on auroral field lines at both low and high altitudes. We show that typically the anisotropy is limited to a certain range of energies, often below 1keV, although sometimes extending to slightly higher energies as well. Almost always there is simultaneously an isotropic electron distribution at higher energies. Often the anisotropies are up/down symmetrical, although cases with net upward or downward electron flow also occur. For a statistical analysis of the anisotropies we divide the energy range into low (below 100eV, middle (100eV–1keV and high (above 1keV energies and develop a measure of anisotropy expressed in density units. The statistical magnetic local time and invariant latitude distribution of the middle-energy anisotropies obeys that of the average auroral oval, whereas the distributions of the low and high energy anisotropies are more irregular. This suggests that it is specifically the middle-energy anisotropies that have something to do with auroral processes. The anisotropy magnitude decreases monotonically with altitude, as one would expect, because electrons have high mobility along the magnetic field and thus, the anisotropy properties spread rapidly to different altitudes.

Key words. Magnetospheric physics (auroral phenomena. Space plasma physics (wave-particle interactions; changed particle motion and acceleration

Transference of Fermi Contour Anisotropy to Composite Fermions.

Science.gov (United States)

Jo, Insun; Rosales, K A Villegas; Mueed, M A; Pfeiffer, L N; West, K W; Baldwin, K W; Winkler, R; Padmanabhan, Medini; Shayegan, M

2017-07-07

There has been a surge of recent interest in the role of anisotropy in interaction-induced phenomena in two-dimensional (2D) charged carrier systems. A fundamental question is how an anisotropy in the energy-band structure of the carriers at zero magnetic field affects the properties of the interacting particles at high fields, in particular of the composite fermions (CFs) and the fractional quantum Hall states (FQHSs). We demonstrate here tunable anisotropy for holes and hole-flux CFs confined to GaAs quantum wells, via applying in situ in-plane strain and measuring their Fermi wave vector anisotropy through commensurability oscillations. For strains on the order of 10^{-4} we observe significant deformations of the shapes of the Fermi contours for both holes and CFs. The measured Fermi contour anisotropy for CFs at high magnetic field (α_{CF}) is less than the anisotropy of their low-field hole (fermion) counterparts (α_{F}), and closely follows the relation α_{CF}=sqrt[α_{F}]. The energy gap measured for the ν=2/3 FQHS, on the other hand, is nearly unaffected by the Fermi contour anisotropy up to α_{F}∼3.3, the highest anisotropy achieved in our experiments.

The development of MEMS device packaging technology using proton beam

International Nuclear Information System (INIS)

Hyeon, J. W.; Kong, Y. J.; Kim, E. H.; Kim, H. S.; No, S. J.

2006-05-01

Wafer-bonding techniques are key issues for the commercialization of MEMS(MicroElectroMechanical Systems) devices. The anodic bonding method and the wafer direct-bonding method are well-known major techniques for wafer bonding. Due to the anodic bonding method includes high voltage processes above 1.5 kV, the MEMS devices can be damaged during the bonding process or malfunctioned while long-term operation. On the other hand, since the wafer direct-bonding method includes a high temperature processes above 1000 .deg. C, temperature-sensitive materials and integrated circuits will be damaged or degraded during the bonding processes. Therefore, high-temperature bonding processes are not applicable for fabricating or packaging devices where temperature-sensitive materials exist. During the past few years, much effort has been undertaken to find a reliable bonding process that can be conducted at a low temperature. Unfortunately, these new bonding processes depend highly on the bonding material, surface treatment and surface flatness. In this research, a new packaging method using proton beam irradiation is proposed. While the energy loss caused in an irradiated material by X-rays or electron beams decreases with the surface distance, the energy loss caused by proton beams has a maximum value at the Bragg peak. Thus, the localized energy produced at the Bragg peak of the proton beams can be used to bond pyrex glass on a silicon wafer, so the MEMS damage is expected to be minimized. The localized heating caused by as well as the penetration depth, or the proton beam has been investigated. The energy absorbed in a stack of pyrex glass/silicon wafers due to proton-beam irradiation was numerically calculated for various proton energies by using the SRIM program. The energy loss was shown to be sufficiently localized at the interface between the pyrex glass and the silicon wafer. Proton beam irradiation was performed in the common environment of room temperature and

Proton Content and Nature in Perovskite Ceramic Membranes for Medium Temperature Fuel Cells and Electrolysers

Directory of Open Access Journals (Sweden)

Aneta Slodczyk

2012-07-01

Full Text Available Recent interest in environmentally friendly technology has promoted research on green house gas-free devices such as water steam electrolyzers, fuel cells and CO₂/syngas converters. In such applications, proton conducting perovskite ceramics appear especially promising as electrolyte membranes. Prior to a successful industrial application, it is necessary to determine/understand their complex physical and chemical behavior, especially that related to proton incorporation mechanism, content and nature of bulk protonic species. Based on the results of quasi-elastic neutron scattering (QNS, thermogravimetric analysis (TGA, Raman and IR measurements we will show the complexity of the protonation process and the importance of differentiation between the protonic species adsorbed on a membrane surface and the bulk protons. The bulk proton content is very low, with a doping limit (~1–5 × 10⁻³ mole/mole, but sufficient to guarantee proton conduction below 600 °C. The bulk protons posses an ionic, covalent bond free nature and may occupy an interstitial site in the host perovskite structure.

Structure of nanoparticles in transformer oil-based magnetic fluids, anisotropy of acoustic attenuation

International Nuclear Information System (INIS)

Kúdelčík, Jozef; Bury, Peter; Kopčanský, Peter; Timko, Milan

2015-01-01

The anisotropy of acoustic attenuation in transformer oil-based magnetic fluids upon the external magnetic field was studied to discover the structure of nanoparticles. When a magnetic field is increased, the interaction between the external magnetic field and the magnetic moments of the nanoparticles leads to the aggregation of magnetic nanoparticles and following clusters formation. However, the temperature of magnetic fluids and the concentration of nanoparticles also have very important influence on the structural changes. The measurement of the dependence of the acoustic attenuation on the angle between the magnetic field direction and acoustic wave vector (anisotropy) can give the useful information about the structure of magnetic nanoparticles formations. In the present, the results of anisotropy measurements of the transformer oil-based magnetic fluids are described and using appropriate theory the basic parameters of clusters are calculated. On the basis of the performed calculations, the proportion of the acoustic wave energy used for excitation of the translational and rotational degrees of freedom was also established. - Highlights: • Nanoparticles formation in transformer oil-based magnetic fluids was investigated. • The anisotropy acoustic spectroscopy as the method of investigation was used. • The external conditions on the structure of magnetic fluids were studied. • The structure parameters using suitable theoretical model were determined

Structure of nanoparticles in transformer oil-based magnetic fluids, anisotropy of acoustic attenuation

Energy Technology Data Exchange (ETDEWEB)

Kúdelčík, Jozef, E-mail: kudelcik@fyzika.uniza.sk [Department of Physics, University of Žilina, Univerzitná 1, 010 01 Žilina (Slovakia); Bury, Peter [Department of Physics, University of Žilina, Univerzitná 1, 010 01 Žilina (Slovakia); Kopčanský, Peter; Timko, Milan [Department of Magnetism, IEP SAS, Watsonova 47, 040 01 Košice (Slovakia)

2015-08-15

The anisotropy of acoustic attenuation in transformer oil-based magnetic fluids upon the external magnetic field was studied to discover the structure of nanoparticles. When a magnetic field is increased, the interaction between the external magnetic field and the magnetic moments of the nanoparticles leads to the aggregation of magnetic nanoparticles and following clusters formation. However, the temperature of magnetic fluids and the concentration of nanoparticles also have very important influence on the structural changes. The measurement of the dependence of the acoustic attenuation on the angle between the magnetic field direction and acoustic wave vector (anisotropy) can give the useful information about the structure of magnetic nanoparticles formations. In the present, the results of anisotropy measurements of the transformer oil-based magnetic fluids are described and using appropriate theory the basic parameters of clusters are calculated. On the basis of the performed calculations, the proportion of the acoustic wave energy used for excitation of the translational and rotational degrees of freedom was also established. - Highlights: • Nanoparticles formation in transformer oil-based magnetic fluids was investigated. • The anisotropy acoustic spectroscopy as the method of investigation was used. • The external conditions on the structure of magnetic fluids were studied. • The structure parameters using suitable theoretical model were determined.

A Bayesian method to quantify azimuthal anisotropy model uncertainties: application to global azimuthal anisotropy in the upper mantle and transition zone

Science.gov (United States)

Yuan, K.; Beghein, C.

2018-04-01

Seismic anisotropy is a powerful tool to constrain mantle deformation, but its existence in the deep upper mantle and topmost lower mantle is still uncertain. Recent results from higher mode Rayleigh waves have, however, revealed the presence of 1 per cent azimuthal anisotropy between 300 and 800 km depth, and changes in azimuthal anisotropy across the mantle transition zone boundaries. This has important consequences for our understanding of mantle convection patterns and deformation of deep mantle material. Here, we propose a Bayesian method to model depth variations in azimuthal anisotropy and to obtain quantitative uncertainties on the fast seismic direction and anisotropy amplitude from phase velocity dispersion maps. We applied this new method to existing global fundamental and higher mode Rayleigh wave phase velocity maps to assess the likelihood of azimuthal anisotropy in the deep upper mantle and to determine whether previously detected changes in anisotropy at the transition zone boundaries are robustly constrained by those data. Our results confirm that deep upper-mantle azimuthal anisotropy is favoured and well constrained by the higher mode data employed. The fast seismic directions are in agreement with our previously published model. The data favour a model characterized, on average, by changes in azimuthal anisotropy at the top and bottom of the transition zone. However, this change in fast axes is not a global feature as there are regions of the model where the azimuthal anisotropy direction is unlikely to change across depths in the deep upper mantle. We were, however, unable to detect any clear pattern or connection with surface tectonics. Future studies will be needed to further improve the lateral resolution of this type of model at transition zone depths.

A new anhydrous proton conductor based on polybenzimidazole and tridecyl phosphate

International Nuclear Information System (INIS)

Jiang Fengjing; Pu Hongting; Meyer, Wolfgang H.; Guan Yisi; Wan Decheng

2008-01-01

Most of the anhydrous proton conducting membranes are based on inorganic or partially inorganic materials, like SrCeO 3 membranes or polybenzimidazole (PBI)/H 3 PO 4 composite membranes. In present work, a new kind of anhydrous proton conducting membrane based on fully organic components of PBI and tridecyl phosphate (TP) was prepared. The interaction between PBI and TP is discussed. The temperature dependence of the proton conductivity of the composite membranes can be modeled by an Arrhenius relation. Thermogravimetric analysis (TGA) illustrates that these composite membranes are chemically stable up to 145 deg. C. The weight loss appearing at 145 deg. C is attributed to the selfcondensation of phosphate, which results in the proton conductivity drop of the membranes occurring at the same temperature. The DC conductivity of the composite membranes can reach ∼10 -4 S/cm for PBI/1.8TP at 140 deg. C and increases with increasing TP content. The proton conductivity of PBI/TP and PBI/H 3 PO 4 composite membranes is compared. The former have higher proton conductivity, however, the proton conductivity of the PBI/H 3 PO 4 membranes increases with temperature more significantly. Compared with PBI/H 3 PO 4 membranes, the migration stability of TP in PBI/TP membranes is improved significantly

Slow electron contribution to inelastic reflection anisotropy

International Nuclear Information System (INIS)

Podsvirov, O.A.; Kuznetsov, Yu.A.

1980-01-01

Investigated is electron contribution with low energy (up to 1 keV) to the anisotropy of electron inelastic reflection (IRE) from silicon monocrystal (111) within 12-50 keV energy range of primary electrons. Experimental data on IRE anisotropy are presented: delay curves for silicon monocrystal, permitting to separate electrons with the energy up to 1 keV, dependences of IRE anisotropy on the energy of primary electrons for the systems - monocrystalline silicon-amorphous silicon film and delay curves for such systems (film thickness varies from 20 to 2000 A). Suggested is a phenomenologic model, permitting to take into account the contribution of slow electrons to IRE anisotropy: it is supposed, that three groups of electrons take part in the formation of the latter: elastic and inelastic reflected electrons, slow electrons, excited by primary electrons and slow electrons, generated by the reverse flow of the scattered electrons. Contribution of electrons, different by origin, to IRE anisotropy is evaluated in accordance with the experimental data on the basis of this model. It is stated, that slow electrons constitute approximately one half of the IRE anisotropy value, the contribution of both groups of slow electrons being approximately equal

Thermal properties of the mixed spin-1 and spin-3/2 Ising ferrimagnetic system with two different random single-ion anisotropies

Science.gov (United States)

Pereira, J. R. V.; Tunes, T. M.; de Arruda, A. S.; Godoy, M.

2018-06-01

In this work, we have performed Monte Carlo simulations to study a mixed spin-1 and spin-3/2 Ising ferrimagnetic system on a square lattice with two different random single-ion anisotropies. This lattice is divided in two interpenetrating sublattices with spins SA = 1 in the sublattice A and SB = 3 / 2 in the sublattice B. The exchange interaction between the spins on the sublattices is antiferromagnetic (J single-ion anisotropies, DiA and DjB , on the sublattices A and B, respectively. We have determined the phase diagram of the model in the critical temperature Tc versus strength of the random single-ion anisotropy D plane and we shown that it exhibits only second-order phase transition lines. We also shown that this system displays compensation temperatures for some cases of the random single-ion distribution.

Oxygen sensor using proton-conductor thick-film operative at room temperature. Puroton dodentai atsumaku wo mochiita joon sadogata sanso sensor

Energy Technology Data Exchange (ETDEWEB)

Miura, Norio; Yoshida, Nobuaki; Matayoshi, Naoko; Shimizu, Yoichi; Yamazoe, Noboru; Kuwata, Shigeki [Kyushu Univ., Fukuoka, (Japan) Niihama National College of Tech., Ehime, (Japan)

1989-10-01

An amperometric solid-state oxygen sensor using a proton-conductor thick-film was examined as a miniaturized and intelligent oxygen sensor operative at room temperature. The good-conditioned proton-conductor film of about 10{mu}m in thickness without holes was formed on a porous alumina substrate by spin-coating the paste containing antimonic acid and a polyvinyl alcohol binder. Using this material, the thick-film oxygen sensor was made. A limiting current, controlled by oxygen permeation through the gas-diffusion layer, was observed when an external voltage was over 1.4V. The limiting current increased linearly with an increase in oxygen partial pressure up to 1.0 atm at an external voltage of 1.6V. The 90% response time for increasing oxygen partial pressure was about 40 seconds at 30 centigrade. Moreover, it was found that the sensor could also respond to dissolved oxygen in water at room temperature. With a sensor using a hydrophobic gas-diffusion layer containing a polystyrene binder, the limiting current was linear to the dissolved oxygen concentration up to 20ppm. 15 refs., 5 figs.

Giant magnetic anisotropy and tunnelling of the magnetization in Li2(Li1-xFex)N

Energy Technology Data Exchange (ETDEWEB)

Jesche, A.; McCallum, R. W.; Thimmaiah, S.; Jacobs, J. L.; Taufour, V.; Kreyssig, A.; Houk, R. S.; Bud’ko, S. L.; Canfield, P. C.

2014-02-25

Large magnetic anisotropy and coercivity are key properties of functional magnetic materials and are generally associated with rare earth elements. Here we show an extreme, uniaxial magnetic anisotropy and the emergence of magnetic hysteresis in Li2(Li_1-xFe_x)N. An extrapolated, magnetic anisotropy field of 220 T and a coercivity field of over 11 T at 2 K outperform all known hard ferromagnets and single-molecular magnets. Steps in the hysteresis loops and relaxation phenomena in striking similarity to single-molecular magnets are particularly pronounced for x<<1 and indicate the presence of nanoscale magnetic centres. Quantum tunnelling, in the form of temperature-independent relaxation and coercivity, deviation from Arrhenius behaviour and blocking of the relaxation, dominates the magnetic properties up to 10 K. The simple crystal structure, the availability of large single crystals and the ability to vary the Fe concentration make Li2(Li_1-xFe_x)N an ideal model system to study macroscopic quantum effects at elevated temperatures and also a basis for novel functional magnetic materials.

Magnetic loss, permeability, and anisotropy compensation in CoO-doped Mn-Zn ferrites

Science.gov (United States)

Beatrice, Cinzia; Dobák, Samuel; Tsakaloudi, Vasiliki; Ragusa, Carlo; Fiorillo, Fausto; Martino, Luca; Zaspalis, Vassilis

2018-04-01

Mn-Zn ferrite samples prepared by conventional solid state reaction method and sintering at 1325 °C were Co-enriched by addition of CoO up to 6000 ppm and characterized versus frequency (DC - 1GHz), peak polarization (2 mT - 200 mT), and temperature (23 °C - 120 °C). The magnetic losses at room temperature are observed to pass through a deep minimum value around 4000 ppm CoO at all polarizations values. This trend is smoothed out either by approaching the MHz range or by increasing the temperature. Conversely, the initial permeability attains its maximum value around the same CoO content, while showing moderate monotonical decrease with increasing CoO at the typical working temperatures of 80 - 100 °C. The energy losses, measured by a combination of fluxmetric and transmission line methods, are affected by the eddy currents, on the conventional 5 mm thick ring samples, only beyond a few MHz. Their assessment relies on the separation of rotational and domain wall processes, which can be done by analysis of the complex permeability and its frequency behavior. This permits one, in particular, to calculate the magnetic anisotropy and its dependence on CoO content and temperature and bring to light its decomposition into the host lattice and Co2+ temperature dependent contributions. The temperature and doping dependence of initial permeability and magnetic losses can in this way be qualitatively justified, without invoking the passage through zero value of the effective anisotropy constant upon doping.

Comparison of Theories of Anisotropy in Transformer Oil-Based Magnetic Fluids

Directory of Open Access Journals (Sweden)

Jozef Kudelcik

2013-01-01

Full Text Available The external magnetic field in transformer oil-based magnetic fluids leads to the aggregation of magnetic nanoparticles and formation of clusters. These aggregations are the result of the interaction between the external magnetic field and the magnetic moments of the nanoparticles occurs. However, the temperature of magnetic fluids has also very important influence on the structural changes because the mechanism of thermal motion acts against the cluster creation. The acoustic spectroscopy was used to study the anisotropy of transformer oil-based magnetic fluids upon the effect of an external magnetic field and temperature. In present the anisotropy of the magnetic fluids can be described by two theories. Taketomi theory assumes the existence of spherical clusters. These clusters form long chains, aligned in a magnetic field direction. Shliomis in his theory supposed that only nanoparticles formed chains. A comparison of the experimental results with the predictions of the Taketomi theory allowed a determination of the cluster radius and the number density of the colloidal particles. The proportions of the acoustic wave energy used for excitation of the translational and rotational motion were determined.

Porous polybenzimidazole membranes doped with phosphoric acid: Preparation and application in high-temperature proton-exchange-membrane fuel cells

International Nuclear Information System (INIS)

Li, Jin; Li, Xiaojin; Yu, Shuchun; Hao, Jinkai; Lu, Wangting; Shao, Zhigang; Yi, Baolian

2014-01-01

Highlights: • Porous polybenzimidazole membrane was prepared with glucose as porogen. • Phosphoric acid content was as high as 15.7 mol H 3 PO 4 per PBI repeat unit. • 200 h Constant current density test was carried out at 150 °C. • Degradation was due to the gap between membrane and catalyst layer. - Abstract: In this paper, the preparation and characterization of porous polybenzimidazole membranes doped with phosphoric acid were reported. For the preparation of porous polybenzimidazole membranes, glucose and saccharose were selected as porogen and added into PBI resin solution before solvent casting. The prepared porous PBI membranes had high proton conductivity and high content of acid doping at room temperature with 15.7 mol H 3 PO 4 per PBI repeat unit, much higher than pure PBI membrane at the same condition. Further, the performance and stability of the porous PBI membrane in high-temperature proton-exchange-membrane fuel cells was tested. It was found that the cell performance remained stable during 200 h stability test under a constant current discharge of 0.5 A cm −2 except for the last fifty hours. The decay in the last fifty hours was ascribed to the delamination between the catalyst layer and membrane increasing the charge-transfer resistance

Study of the out-of-plane emission of protons and light fragments in symmetric heavy-ion collisions

International Nuclear Information System (INIS)

Brill, D.; Beckerle, P.; Bormann, C.; Schwab, E.; Shin, Y.; Stock, R.; Stroebele, H.; Baltes, P.; Muentz, C.; Oeschler, H.; Sturm, C.; Wagner, A.; Barth, R.; Cieslak, M.; Debowski, M.; Grosse, E.; Koczon, P.; Mang, M.; Miskowiec, D.; Schicker, R.; Senger, P.; Kohlmeyer, B.; Puehlhofer, F.; Speer, J.; Voelkel, K.; Walus, W.

1996-01-01

Midrapidity protons from 209 Bi+ 209 Bi collisions were measured with the Kaon Spectrometer at SIS at incident energies of E Lab /A=400, 700 and 1000 MeV. Additionally, light fragments were analysed at 400 MeV. We have investigated the azimuthal emission pattern of the particles relative to the reaction plane as function of transverse momentum, bombarding energy and impact parameter. We observe an enhanced emission of particles perpendicular to the reaction plane at all bombarding energies. The ratio of the number of particles emitted out-of-plane/in-plane increases strongly with the particles transverse momentum. The anisotropy decreases with increasing beam energy. Composite particles show a much stronger effect than protons. (orig.)

Relationship between electrical conductivity anisotropy and fabric anisotropy in granular materials during drained triaxial compressive tests: a numerical approach

Science.gov (United States)

Niu, Qifei; Revil, André; Li, Zhaofeng; Wang, Yu-Hsing

2017-07-01

The anisotropy of granular media and its evolution during shearing are important aspects required in developing physics-based constitutive models in Earth sciences. The development of relationships between geoelectrical properties and the deformation of porous media has applications to the monitoring of faulting and landslides. However, such relationships are still poorly understood. In this study, we first investigate the definition of the electrical conductivity anisotropy tensor of granular materials in presence of surface conductivity of the grains. Fabric anisotropy is related to the components of the fabric tensor. We define an electrical anisotropy factor based on the Archie's exponent second-order symmetric tensor m of granular materials. We use numerical simulations to confirm a relationship between the evolution of electrical and fabric anisotropy factors during shearing. To realize the simulations, we build a virtual laboratory in which we can easily perform synthetic experiments. We first simulate drained compressive triaxial tests of loose and dense granular materials (porosity 0.45 and 0.38, respectively) using the discrete element method. Then, the electrical conductivity tensor of a set of deformed synthetic samples is computed using the finite-difference method. The numerical results show that shear strains are responsible for a measurable anisotropy in the bulk conductivity of granular media. The observed electrical anisotropy response, during shearing, is distinct for dense and loose synthetic samples. Electrical and fabric anisotropy factors exhibit however a unique linear correlation, regardless of the shear strain and the initial state (porosity) of the synthetic samples. The practical implication of this finding confirms the usefulness of the electrical conductivity method in studying the fabric tensor of granular media. This result opens the door in using time-lapse electrical resistivity to study non-intrusively the evolution of anisotropy

Origin of perpendicular magnetic anisotropy in Co/Ni multilayers

Science.gov (United States)

Arora, M.; Hübner, R.; Suess, D.; Heinrich, B.; Girt, E.

2017-07-01

We studied the variation in perpendicular magnetic anisotropy of (111) textured Au /N ×[Co /Ni ]/Au films as a function of the number of bilayer repeats N . The ferromagnetic resonance and superconducting quantum interference device magnetometer measurements show that the perpendicular magnetic anisotropy of Co/Ni multilayers first increases with N for N ≤10 and then moderately decreases for N >10 . The model we propose reveals that the decrease of the anisotropy for N reduction in the magnetoelastic and magnetocrystalline anisotropies. A moderate decrease in the perpendicular magnetic anisotropy for N >10 is due to the reduction in the magnetocrystalline and the surface anisotropies. To calculate the contribution of magnetoelastic anisotropy in the Co/Ni multilayers, in-plane and out-of-plane x-ray diffraction measurements are performed to determine the spacing between Co/Ni (111) and (220) planes. The magnetocrystalline bulk anisotropy is estimated from the difference in the perpendicular and parallel g factors of Co/Ni multilayers that are measured using the in-plane and out-of-plane ferromagnetic resonance measurements. Transmission electron microscopy has been used to estimate the multilayer film roughness. These values are used to calculate the roughness-induced surface and magnetocrystalline anisotropy coefficients as a function of N .

Proton Conductivity of Proton Exchange Membrane Synergistically Promoted by Different Functionalized Metal-Organic Frameworks.

Science.gov (United States)

Rao, Zhuang; Tang, Beibei; Wu, Peiyi

2017-07-12

In this study, two functionalized metal-organic frameworks (MOFs), UiO-66-SO 3 H and UiO-66-NH 2 , were synthesized. Then, different composite proton exchange membranes (PEMs) were prepared by single doping and codoping of these two MOFs, respectively. It was found that codoping of these two MOFs with suitable sizes was more conducive to the proton conductivity enhancement of the composite PEM. A synergistic effect between these two MOFs led to the the formation of more consecutive hydration channels in the composite PEM. It further greatly promoted the proton conductivity of the composite PEM. The proton conductivity of the codoped PEM reached up to 0.256 S/cm under 90 °C, 95% RH, which was ∼1.17 times higher than that of the recast Nafion (0.118 S/cm). Besides, the methanol permeability of the codoped PEM was prominently decreased owing to the methanol trapping effect of the pores of these two MOFs. Meanwhile, the high water and thermal stabilities of these two MOFs were beneficial to the high proton conductivity stability of the codoped PEM under high humidity and high temperature. The proton conductivity of the codoped PEM was almost unchanged throughout 3000 min of testing under 90 °C, 95% RH. This work provides a valuable reference for designing different functionalized MOFs to synergistically promote the proton conductivities of PEMs.

Effects of substrate anisotropy and edge diffusion on submonolayer growth during molecular beam epitaxy: A Kinetic Monte Carlo study

International Nuclear Information System (INIS)

Devkota, J.; Shrestha, S.P.

2007-12-01

We have performed Kinetic Monte Carlo simulation work to study the effect of diffusion anisotropy, bonding anisotropy and edge diffusion on island formation at different temperatures during the sub-monolayer film growth in Molecular Beam Epitaxy. We use simple cubic solid on solid model and event based Bortz, Kalos and Labowitch (BKL) algorithm on the Kinetic Monte Carlo method to simulate the physical phenomena. We have found that the island morphology and growth exponent are found to be influenced by substrate anisotropy as well as edge diffusion, however they do not play a significant role in island elongation. The growth exponent and island size distribution are observed to be influenced by substrate anisotropy but are negligibly influenced by edge diffusion. We have found fractal islands when edge diffusion is excluded and compact islands when edge diffusion is included. (author)

Enhancing the magnetic anisotropy of maghemite nanoparticles via the surface coordination of molecular complexes

Science.gov (United States)

Prado, Yoann; Daffé, Niéli; Michel, Aude; Georgelin, Thomas; Yaacoub, Nader; Grenèche, Jean-Marc; Choueikani, Fadi; Otero, Edwige; Ohresser, Philippe; Arrio, Marie-Anne; Cartier-dit-Moulin, Christophe; Sainctavit, Philippe; Fleury, Benoit; Dupuis, Vincent; Lisnard, Laurent; Fresnais, Jérôme

2015-01-01

Superparamagnetic nanoparticles are promising objects for data storage or medical applications. In the smallest—and more attractive—systems, the properties are governed by the magnetic anisotropy. Here we report a molecule-based synthetic strategy to enhance this anisotropy in sub-10-nm nanoparticles. It consists of the fabrication of composite materials where anisotropic molecular complexes are coordinated to the surface of the nanoparticles. Reacting 5 nm γ-Fe2O3 nanoparticles with the [CoII(TPMA)Cl2] complex (TPMA: tris(2-pyridylmethyl)amine) leads to the desired composite materials and the characterization of the functionalized nanoparticles evidences the successful coordination—without nanoparticle aggregation and without complex dissociation—of the molecular complexes to the nanoparticles surface. Magnetic measurements indicate the significant enhancement of the anisotropy in the final objects. Indeed, the functionalized nanoparticles show a threefold increase of the blocking temperature and a coercive field increased by one order of magnitude. PMID:26634987

Micromechanical properties of single crystals and polycrystals of pure α-titanium: anisotropy of microhardness, size effect, effect of the temperature (77-300 K)

Science.gov (United States)

Lubenets, S. V.; Rusakova, A. V.; Fomenko, L. S.; Moskalenko, V. A.

2018-01-01

The anisotropy of microhardness of pure α-Ti single crystals, indentation size effect in single-crystal, course grained (CG) pure and nanocrystalline (NC) VT1-0 titanium, as well as the temperature dependences of the microhardness of single-crystal and CG Ti in the temperature range 77-300 K were studied. The minimum value of hardness was obtained when indenting into the basal plane (0001). The indentation size effect (ISE) was clearly observed in the indentation of soft high-purity single-crystal iodide titanium while it was the least pronounced in a sample of nanocrystalline VT1-0 titanium. It has been demonstrated that the ISE can be described within the model of geometrically necessary dislocations (GND), which follows from the theory of strain gradient plasticity. The true hardness and others parameters of the GND model were determined for all materials. The temperature dependence of the microhardness is in agreement with the idea of the governing role of Peierls relief in the dislocation thermally-activated plastic deformation of pure titanium as has been earlier established and justified in macroscopic tensile investigations at low temperatures. The activation energy and activation volume of dislocation motion in the strained region under the indenter were estimated.

Seismic Anisotropy of Soft Sands, Offshore Western AUstralia

Science.gov (United States)

Urosevic, M.; Gurevich, B.

2007-05-01

Seismic anisotropy is commonly measured in sand shale environment. Intrinsic polar anisotropy of the shale and its effect on seismic data processing and analysis is well established and reasonably well understood. In sandstone, azimuthal anisotropy is often detected and is typically connected to an in situ stress regime and the brittleness of the rock. This type of anisotropy, commonly referred to as fractured induced anisotropy, has been widely and extensively studied as it directly affects both permeability and the strength of the rock. Hence fracture induced anisotropy is not only important for hydrocarbon exploration but also for geotechnical studies, underground mining, etc. Interestingly, in the last few years azimuthal anisotropy has also been detected in soft, poorly consolidated clean sands, mainly by cross-dipole sonic log measurements. This is somewhat surprising as in such soft, typically highly porous and permeable rocks stress induced fractures are unlikely to be abundant. In this study we analyse the anisotropy in such sand class using well-log measurements, three-component VSP data, as well as 2D and 3D surface seismic (reflection) data. High-quality cross-dipole sonic log measurements showed significant shear wave splitting over unconsolidated, highly porous and permeable sand interval. The shear wave anisotropy was computed to be around 10-15%. This is commonly seen as an indication that the rock is fractured and that the fractures are likely to be open. However, image log data over the same sand section suggested dilute most likely non-conductive fractures. Analysis of the shear wave splitting in VSP data also suggested low fracture density. The frequency content of the direct fast and slow shear waves on the VSP data was very similar, not supporting the presence of open fluid saturated fractures. Unfortunately, the evidence from the VSP data is not very compelling because the reservoir is thin compared to the wavelength and sampling interval of

Analysis of the system efficiency of an intermediate temperature proton exchange membrane fuel cell at elevated temperature and relative humidity conditions

International Nuclear Information System (INIS)

Jeon, Seung Won; Cha, Dowon; Kim, Hyung Soon; Kim, Yongchan

2016-01-01

Highlights: • System efficiency of PEMFC is evaluated at elevated temperature and humidity. • Operating parameters are optimized using response surface methodology. • The optimal operating parameters are T = 90.6 °C, RH = 100.0%, and ζ = 2.07. • The power output and system efficiency are 1.28 W and 15.8% at the optimum. • The system efficiency can be effectively improved by increasing relative humidity. - Abstract: Humidification of the membrane is very important in a proton exchange membrane fuel cell (PEMFC), to maintain high ionic conductivity. At an elevated temperature, a large amount of thermal energy is required for humidification because of the exponentially increased saturation vapor pressure. In this study, the system efficiency of a PEMFC was evaluated by considering the heat required for preheating/humidification and compression work. Three-dimensional steady-state simulations were conducted using Fluent 14 to simulate the electrochemical reactions. The operating conditions were optimized using response surface methodology by considering both the fuel cell output and system efficiency. In addition, the effects of operating parameters such as the temperature, relative humidity, and stoichiometric ratio were investigated. The system efficiency can be improved more effectively by increasing relative humidity rather than increasing operating temperature because the ionic conductivity of the membrane was strongly influenced by the relative humidity.

Experimental determination of monoethanolamine protonation constant and its temperature dependency

Directory of Open Access Journals (Sweden)

Ma’mun Sholeh

2017-01-01

Full Text Available Carbon dioxide as one of the major contributors to the global warming problem is produced in large quantities by many important industries and its emission seems to rise from year to year. Aminebased absorption is one of the methods to capture CO2 from its sources. As a reactive system, mass transfer and chemical reaction take place simultaneously. In a vapor-liquid equilibrium model for the CO2-amine-water system, some parameters such as mass transfer coefficients and chemical equilibrium constants need to be known. However, some parameters could be determined experimentally and the rests could be regressed from the model. The protonation constant (pKa, as one of the model parameters, could then be measured experimentally. The purpose of this study is to measure the pKa of monoethanolamine (MEA at a range of temperatures from 303 to 330K by a potentiometric titration method. The experimental data obtained were in a good agreement with the literature data. The pKa data from this work together with those from the literature were then correlated in an empirical correlation to be used for future research.

Proton-air and proton-proton cross sections

Directory of Open Access Journals (Sweden)

Ulrich Ralf

2013-06-01

Full Text Available Different attempts to measure hadronic cross sections with cosmic ray data are reviewed. The major results are compared to each other and the differences in the corresponding analyses are discussed. Besides some important differences, it is crucial to see that all analyses are based on the same fundamental relation of longitudinal air shower development to the observed fluctuation of experimental observables. Furthermore, the relation of the measured proton-air to the more fundamental proton-proton cross section is discussed. The current global picture combines hadronic proton-proton cross section data from accelerator and cosmic ray measurements and indicates a good consistency with predictions of models up to the highest energies.

Tensile anisotropy and creep properties of a Fe-14CrWTi ODS ferritic steel

Energy Technology Data Exchange (ETDEWEB)

Steckmeyer, A., E-mail: antonin.steckmeyer@cea.fr [CEA Saclay, DEN/DANS/DMN/SRMA, 91191 Gif-sur-Yvette (France); Rodrigo, Vargas Hideroa [CEA Saclay, DEN/DANS/DMN/SRMA, 91191 Gif-sur-Yvette (France); Gentzbittel, J.M. [CEA Grenoble, DRT/LITEN/DTBH/LCTA, 38054 Grenoble Cedex 9 (France); Rabeau, V.; Fournier, B. [CEA Saclay, DEN/DANS/DMN/SRMA, 91191 Gif-sur-Yvette (France)

2012-07-15

A Fe-14Cr oxide dispersion strengthened (ODS) ferritic steel is studied as a potential material for cladding tube application for the next generation of fast-breeder nuclear reactors. Tensile specimens machined out from a hot extruded round bar in three different orientations are used to evaluate the mechanical anisotropy of this steel for temperatures in the range 20-750 Degree-Sign C. Its anisotropy is discussed both in terms of mechanical strength and fracture mode. At high temperatures (HTs), above 500 Degree-Sign C, the longitudinal direction appears to be the most ductile and most resistant direction. Longitudinal creep tests between 650 Degree-Sign C and 900 Degree-Sign C were also carried out. They show this ODS steel has a high HT creep lifetime and a low creep failure strain. Intergranular cracks aligned along the loading axis were observed on fractured creep specimens. They reveal a particular weakness of prior particle boundaries and suggest to modify the elaboration process through mechanical alloying and hot extrusion.

Anisotropy effect of the clay soil masses on the stress-strain state of transport tunnels

Directory of Open Access Journals (Sweden)

Yushkov Boris Semenovich

2014-09-01

Full Text Available The article considers the kinds of clay soil mass anisotropy in the form of the spatial heterogeneity of properties of thawed and frozen soils, ambiguity of the frost heaving values and shrinkage in different directions. The questions of anisotropy of the clay soil properties at the positive temperatures are reported. The dependence of the heterogeneity of the physical and mechanical properties of frozen soils from the cryogenic texture, natural arrangement, different types of stratification and interbedding is considered. Indexes of the strength and strain anisotropy are noted. The accounting possibilities of the basic numerical indexes of heaving phenomena from the standpoint of anisotropy of the properties and processes inherent in the freezing through soil are analyzed by substitution in the heaving strain formula. The unevenness of thawed soil shrinkage in vertical and horizontal directions is noted during the freezing of the top layer. The unevenness of shrinkage in different directions is connected with kind of stress and cryogenic texture. Anisotropy of the frost heaving process is considered in the context of one-dimensional and non-one-dimensional problem depending on the amount of the freezing fronts and their direction. There is summarized the effect of anisotropy appearances on the stress-strain state of the transport tunnel. One can conclude that the resulting non-uniformity of heaving and shrinkage in conjunction with anisotropic properties of frozen soils, is a significant component in the complex of power factors determining the optimal design solution of a transport tunnel.

Strong out-of-plane magnetic anisotropy in ion irradiated anatase TiO2 thin films

Directory of Open Access Journals (Sweden)

M. Stiller

2016-12-01

Full Text Available The temperature and field dependence of the magnetization of epitaxial, undoped anatase TiO2 thin films on SrTiO3 substrates was investigated. Low-energy ion irradiation was used to modify the surface of the films within a few nanometers, yet with high enough energy to produce oxygen and titanium vacancies. The as-prepared thin film shows ferromagnetism which increases after irradiation with low-energy ions. An optimal and clear magnetic anisotropy was observed after the first irradiation, opposite to the expected form anisotropy. Taking into account the experimental parameters, titanium vacancies as di-Frenkel pairs appear to be responsible for the enhanced ferromagnetism and the strong anisotropy observed in our films. The magnetic impurities concentrations was measured by particle-induced X-ray emission with ppm resolution. They are ruled out as a source of the observed ferromagnetism before and after irradiation.

Recommended data on proton-ion collision rate coefficients for Fe X-Fe XV ions

International Nuclear Information System (INIS)

Skobelev, I.; Murakami, I.; Kato, T.

2006-01-01

The proton-ion collisions are important for excitation of some ion levels in a high-temperature low density plasma. In the present work evaluation of data obtained for proton-induced transitions in Fe X - Fe XV ions with the help of different theoretical methods is carried out. It is suggested a simple analytical formula with 7 parameters allowing to describe dependency of proton rate coefficient on proton temperature in an enough wide temperature range. The values of free parameters have been determined by fitting of approximation formula to numerical data and are presented for recommended data together with fitting accuracies. By comparing of proton collision rates with electron ones it is shown that proton impact excitation processes may be important for Fe X, XI, XIII-XV ions. The results obtained can be used for plasma kinetics calculations and for development of spectroscopy methods of plasma diagnostics. (author)

Relative sensitivity of formability to anisotropy

International Nuclear Information System (INIS)

Logan, R.W.; Maker, B.N.

1997-01-01

This work compares the relative importance of material anisotropy in sheet forming as compared to other material and process variables. The comparison is made quantitative by the use of normalized dependencies of depth to failure (forming limit is reached) on various measures of anisotropy, as well as strain and rate sensitivity, friction, and tooling. Comparisons are made for a variety of forming processes examined previously in the literature as well as two examples of complex stampings in this work. 7 The examples rover a range from nearly pure draw to nearly pure stretch situations, and show that for materials following a quadratic yield criterion, anisotropy is among the most sensitive parameters influencing formability. For materials following higher-exponent yield criteria, the dependency is milder but is still of the order of most other process parameters. However, depending on the particular forming operation, it is shown that in some cases anisotropy may be ignored, whereas in others its consideration is crucial to a good quality analysis

Island dynamics and anisotropy during vapor phase epitaxy of m-plane GaN

Energy Technology Data Exchange (ETDEWEB)

Perret, Edith [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA; University of Fribourg, Department of Physics and Fribourg Center for Nanomaterials, Chemin du Musée 3, CH-1700 Fribourg, Switzerland; Xu, Dongwei [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA; Highland, M. J. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA; Stephenson, G. B. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA; Zapol, P. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA; Fuoss, P. H. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA; Munkholm, A. [Munkholm Consulting, Mountain View, California 94043, USA; Thompson, Carol [Department of Physics, Northern Illinois University, DeKalb, Illinois 60115, USA

2017-12-04

Using in situ grazing-incidence x-ray scattering, we have measured the diffuse scattering from islands that form during layer-by-layer growth of GaN by metal-organic vapor phase epitaxy on the (1010) m-plane surface. The diffuse scattering is extended in the (0001) in-plane direction in reciprocal space, indicating a strong anisotropy with islands elongated along [1210] and closely spaced along [0001]. This is confirmed by atomic force microscopy of a quenched sample. Islands were characterized as a function of growth rate F and temperature. The island spacing along [0001] observed during the growth of the first monolayer obeys a power-law dependence on growth rate F-n, with an exponent n = 0:25 + 0.02. The results are in agreement with recent kinetic Monte Carlo simulations, indicating that elongated islands result from the dominant anisotropy in step edge energy and not from surface diffusion anisotropy. The observed power-law exponent can be explained using a simple steady-state model, which gives n = 1/4.

Anisotropy of transverse sound in the heavy Fermian supersonductor UPt3

International Nuclear Information System (INIS)

Shiveram, B.S.; Jeong, Y.H.; Rosenbaum, T.F.; Hinks, D.G.

1986-03-01

We report the first measurements of the attenuation of ultrasound in the basal plane of superconducting UPt 3 . Transverse sound propagating along the b-axis shows a marked anisotropy in its temperature dependence when the polarization is rotated in and out of the basal plane. For polarization in the basal plane the attenuation varies linearly with temperature down to 35 mK and the slope scales as the square of the frequency. Our results appear to indicate the presence of an additional attenuation mechanism when compared with recent theories of anisotropic superconductors in the dirty limit. 18 refs., 3 figs

Using reflectance anisotropy spectroscopy to characterize capped silver nanostructures grown on silicon

Energy Technology Data Exchange (ETDEWEB)

Fleischer, K.; Jacob, J.; McGilp, J.F. [School of Physics, Trinity College Dublin, Dublin 2 (Ireland); Chandola, S. [School of Physics, Trinity College Dublin, Dublin 2 (Ireland); ISAS - Institute for Analytical Sciences, Department Berlin, Albert-Einstein-Strasse 9, 12489 Berlin (Germany); Esser, N. [ISAS - Institute for Analytical Sciences, Department Berlin, Albert-Einstein-Strasse 9, 12489 Berlin (Germany)

2008-07-01

Using the single domain Si(111)-3 x 1-Ag surface as a template, room temperature deposition of two or more monolayers of Ag leads to the formation of metallic nanostructures. Reflectance anisotropy spectroscopy (RAS) in the infrared (IR) spectral region is used to analyse the anisotropic conductivity of the structures. The anisotropy is found to be influenced by the offcut angle of the substrate, and hence the terrace width. The Ag nanostructures were capped with Si to form a near-IR transparent protecting layer. The samples are stable to exposure to ambient conditions for significant periods. The RAS spectra are compared to model calculations, which support the conclusion that the buried metallic Ag nanostructures survive the capping process. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

CMB statistical anisotropy from noncommutative gravitational waves

Energy Technology Data Exchange (ETDEWEB)

Shiraishi, Maresuke; Ricciardone, Angelo [Dipartimento di Fisica e Astronomia ' ' G. Galilei' ' , Università degli Studi di Padova, via Marzolo 8, I-35131, Padova (Italy); Mota, David F. [Institute of Theoretical Astrophysics, University of Oslo, P.O. Box 1029 Blindern, N-0315 Oslo (Norway); Arroja, Frederico, E-mail: maresuke.shiraishi@pd.infn.it, E-mail: d.f.mota@astro.uio.no, E-mail: angelo.ricciardone@pd.infn.it, E-mail: arroja@pd.infn.it [INFN, Sezione di Padova, via Marzolo 8, I-35131, Padova (Italy)

2014-07-01

Primordial statistical anisotropy is a key indicator to investigate early Universe models and has been probed by the cosmic microwave background (CMB) anisotropies. In this paper, we examine tensor-mode CMB fluctuations generated from anisotropic gravitational waves, parametrised by P{sub h}(k) = P{sub h}{sup (0)}(k) [ 1 + ∑{sub LM} f{sub L}(k) g{sub LM} Y{sub LM} ( k-circumflex )], where P{sub h}{sup (0)}(k) is the usual scale-invariant power spectrum. Such anisotropic tensor fluctuations may arise from an inflationary model with noncommutativity of fields. It is verified that in this model, an isotropic component and a quadrupole asymmetry with f{sub 0}(k) = f{sub 2}(k) ∝ k{sup -2} are created and hence highly red-tilted off-diagonal components arise in the CMB power spectra, namely ℓ{sub 2} = ℓ{sub 1} ± 2 in TT, TE, EE and BB, and ℓ{sub 2} = ℓ{sub 1} ± 1 in TB and EB. We find that B-mode polarisation is more sensitive to such signals than temperature and E-mode polarisation due to the smallness of large-scale cosmic variance and we can potentially measure g{sub 00} = 30 and g{sub 2M} = 58 at 68% CL in a cosmic-variance-limited experiment. Such a level of signal may be measured in a PRISM like experiment, while the instrumental noise contaminates it in the Planck experiment. These results imply that it is impossible to measure the noncommutative parameter if it is small enough for the perturbative treatment to be valid. Our formalism and methodology for dealing with the CMB tensor statistical anisotropy are general and straightforwardly applicable to other early Universe models.

Proton dynamics in oxides: insight into the mechanics of proton conduction from quasielastic neutron scattering.

Science.gov (United States)

Karlsson, Maths

2015-01-07

This article is concerned with the use of quasielastic neutron scattering as a technique for investigation of the dynamical properties of proton conducting oxides. Currently, the main interest in these materials comes from their promise as electrolytes in future electrochemical devices and particularly through their use as electrolytes in next-generation, intermediate-temperature, fuel cells. However, the realization of such devices depends critically on the development of new, more highly proton conducting oxides. Such a development depends on increasing the current understanding of proton conduction in oxides and for this purpose quasielastic neutron scattering is an important mean. The aim of this article is to introduce the non-specialist reader to the basic principles of quasielastic neutron scattering, its advantages and disadvantages, to summarize the work that has been done on proton conducting oxides using this technique, as well as to discuss future opportunities within this field of research.

Anisotropy and multi-band effects in weak-coupling superconductors

International Nuclear Information System (INIS)

Berger, T.L.

1977-01-01

The techniques of second quantization and thermodynamic Green functions are used to investigate energy gap anisotropy and multi-band effects in pure, single-crystal, weak-coupling superconductors. A generalized version of the standard Gorkov factorization is used to linearize the Green functions equations of motion. The effects of lattice periodicity and band structure are taken into account by means of Bloch wave expansions and Bloch transforms. A pairing selection rule is derived which indicates the possibility of pairing between single particle states belonging to different bands, as well as the usual Cooper pairing. It is shown that the interband gap parameter, which is coupled to the usual gap parameter by the Green functions equations of motion, can only contribute indirectly to the tunneling electric current and the thermodynamic potential. In the absence of interband pairing, the equations of motion lead to the usual BCS gap equation. Also, in the absence of interband pairing, the gap parameter is found to be equal to the diagonal matrix element of the superconductor pair potential between electronic Bloch states. An essentially temperature independent anisotropy function which contains all angular dependence of the gap is shown to evolve naturally from this formalism. The overall temperature dependence of the gap is investigated and it is found that with a change of temperature, the magnitude of the gap in different directions changes in the same ration. The ordinary Markowitz-Kadanoff model is shown to be inappropriate for the case of a multi-band superconductor and a generalized version of this model is introduced and discussed. A special case of this model is considered which leads to gap discontinuities at Brillouin zone boundaries

Cosmic-ray anisotropy studies with IceCube

Science.gov (United States)

McNally, Frank

2014-03-01

The IceCube neutrino observatory detects tens of billions of energetic muons per year produced by cosmic-ray interactions with the atmosphere. The size of this sample has allowed IceCube to observe a significant anisotropy in arrival direction for cosmic rays with median energies between 20 and 400 TeV. This anisotropy is characterized by a large scale structure of per-mille amplitude accompanied by structures with smaller amplitudes and with typical angular sizes between 10° and 20°. IceTop, the surface component of IceCube, has observed a similar anisotropy in the arrival direction distribution of cosmic rays, extending the study to PeV energies. The better energy resolution of IceTop allows for additional studies of the anisotropy, for example a comparison of the energy spectrum in regions of a cosmic-ray excess or deficit to the rest of the sky. We present an update on the cosmic-ray anisotropy observed with IceCube and IceTop and the results of first studies of the energy spectrum at locations of cosmic-ray excess or deficit.

Proton spin-lattice relaxation in a liquid crystal-Aerosil complex above the bulk isotropization temperature

Energy Technology Data Exchange (ETDEWEB)

Anoardo, E.; Grinberg, F.; Vilfan, M.; Kimmich, R

2004-02-16

We present a study of the molecular dynamics in an octylcyanobiphenyl (8CB)-Aerosil complex above the bulk isotropization temperature. Using proton nuclear magnetic relaxation experiments in the laboratory frame (T{sub 1}{sup -1}) and in the rotating-frame (T{sub 1{rho}}{sup -1}), we found a notable increase of the relaxation rates in the kHz frequency range as compared to the bulk 8CB liquid crystal at the same temperature. The field-cycling technique was used for the laboratory frame experiments while a conventional apparatus was used for the rotating frame method. The observed behavior is analyzed with the aid of Monte Carlo simulations on the basis of a two-phase fast-exchange model distinguishing surface-ordered and bulk phases. Two processes affecting the low frequency relaxation could be identified: reorientation mediated by translational displacements, accounting for molecular reorientations, and exchange losses of molecules from the surface to the bulk.

Solvent Exchange Rates of Side-chain Amide Protons in Proteins

International Nuclear Information System (INIS)

Rajagopal, Ponni; Jones, Bryan E.; Klevit, Rachel E.

1998-01-01

Solvent exchange rates and temperature coefficients for Asn/Gln side-chain amide protons have been measured in Escherichia coli HPr. The protons of the eight side-chain amide groups (two Asn and six Gln) exhibit varying exchange rates which are slower than some of the fast exchanging backbone amide protons. Differences in exchange rates of the E and Z protons of the same side-chain amide group are obtained by measuring exchange rates at pH values > 8. An NOE between a side-chain amide proton and a bound water molecule was also observed

Proton conductivity and relaxation properties of chitosan-acetate films

International Nuclear Information System (INIS)

Prokhorov, E.; Luna-Bárcenas, G.; González-Campos, J.B.; Kovalenko, Yu.; García-Carvajal, Z.Y.; Mota-Morales, J.

2016-01-01

Graphical abstract: Temperature dependence of conductivity, the number of density and proton mobility in chitosan-acetate film. - Highlights: • DD, conductivity, Vogel temperature dependent on the concentration of acetic acid. • Proton conductivity of CS-acetate films interpreted using two Grotthuss mechanisms. • Transformation between two mechanisms observed at the glass transition temperature. - Abstract: The effect of aqueous acetic acid solution concentration during the preparation of chitosan-acetate (CS-acetate) films on the conductivity and relaxation properties were studied by dielectric and FTIR spectroscopies, TGA measurements and X-Ray diffraction. Analyses of the experimental results on the degree of deacetylation, water absorption, conductivity, Vogel temperature and activation energy demonstrate a strong dependence of these parameters on the concentration of the acid acetic solutions from which the films have been obtained. The proton conductivity and relaxation properties of CS-acetate films have been interpreted using two Grotthuss “structural diffusion” and “pack-acid” mechanisms. The transformation between these two mechanisms observed at temperature higher than CS-acetate glass transition temperature is due to an increase in the thermal motion of CS chains, water evaporation, hydrogen bond between water molecules and side groups of CS breaking and formation of new bonds between NH 3 + and acetate ions. Additionally, application of the Rice and Roth model allowed estimating the temperature dependence of proton number and their mobility in CS-acetate films. A systematic interpretation on the appropriate conductivity mechanism will help trigger the design of smart materials used in flexible electronic, solid polymer electrolytes for fuel cells and solid polymer batteries based on CS-acetate films.

What does anisotropy measure? Insights from increased and decreased anisotropy in selective fiber tracts in schizophrenia.

Science.gov (United States)

Alba-Ferrara, L M; de Erausquin, Gabriel A

2013-01-01

Schizophrenia is a common, severe, and chronically disabling mental illness of unknown cause. Recent MRI studies have focused attention on white matter abnormalities in schizophrenia using diffusion tensor imaging (DTI). Indices commonly derived from DTI include (1) mean diffusivity, independent of direction, (2) fractional anisotropy (FA) or relative anisotropy (RA), (3) axial diffusivity, and (4) radial diffusivity. In cerebral white matter, contributions to these indices come from fiber arrangements, degree of myelination, and axonal integrity. Relatively pure deficits in myelin result in a modest increase in radial diffusivity, without affecting axial diffusivity and with preservation of anisotropy. Although schizophrenia is not characterized by gross abnormalities of white matter, it does involve a profound dysregulation of myelin-associated gene expression, reductions in oligodendrocyte numbers, and marked abnormalities in the ultrastructure of myelin sheaths. Since each oligodendrocyte myelinates as many as 40 axon segments, changes in the number of oligodendrocytes (OLG), and/or in the integrity of myelin sheaths, and/or axoglial contacts can have a profound impact on signal propagation and the integrity of neuronal circuits. Whereas a number of studies have revealed inconsistent decreases in anisotropy in schizophrenia, we and others have found increased FA in key subcortical tracts associated with the circuits underlying symptom generation in schizophrenia. We review data revealing increased anisotropy in dopaminergic tracts in the mesencephalon of schizophrenics and their unaffected relatives, and discuss the possible biological underpinnings and physiological significance of this finding.

Yttrium and Nickel Co-Doped BaZrO3 as a Proton-Conducting Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells

KAUST Repository

Shafi, S. P.

2015-07-17

High temperature proton conducting oxides, due to their lower activation energy for proton conduction, can achieve high conductivity at relatively low temperatures (500-700°C). Though BaZr0.8Y0.2O3-δ (BZY) perovskite exhibits good chemical stability and high bulk conductivity, high grain boundary resistance decreases its total conductivity. This work focuses on substitution of Zr4+ with Ni2+ in the perovskite B-site in a targeted fashion in order to promote the sinterability of BZY. Powder X-ray diffraction analysis showed the formation of single phases for Ba0.8-xY0.2NixO3-δ compositions up to x = 0.04. Scanning electron microscopy (SEM) image analysis demonstrated that densification is promoted by increasing the Ni-content, reaching a fully dense microstructure for Ba0.76Y0.2Ni0.04O3-δ (BZYNi04). An anode supported single cell based on BZYNi04 electrolyte showed superior power performance, achieving 240 and 428 mW cm-2 at 600 and 700°C, respectively. © The Electrochemical Society.

Yttrium and Nickel Co-Doped BaZrO3 as a Proton-Conducting Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells

KAUST Repository

Shafi, S. P.; Bi, Lei; Boulfrad, S.; Traversa, Enrico

2015-01-01

High temperature proton conducting oxides, due to their lower activation energy for proton conduction, can achieve high conductivity at relatively low temperatures (500-700°C). Though BaZr0.8Y0.2O3-δ (BZY) perovskite exhibits good chemical stability and high bulk conductivity, high grain boundary resistance decreases its total conductivity. This work focuses on substitution of Zr4+ with Ni2+ in the perovskite B-site in a targeted fashion in order to promote the sinterability of BZY. Powder X-ray diffraction analysis showed the formation of single phases for Ba0.8-xY0.2NixO3-δ compositions up to x = 0.04. Scanning electron microscopy (SEM) image analysis demonstrated that densification is promoted by increasing the Ni-content, reaching a fully dense microstructure for Ba0.76Y0.2Ni0.04O3-δ (BZYNi04). An anode supported single cell based on BZYNi04 electrolyte showed superior power performance, achieving 240 and 428 mW cm-2 at 600 and 700°C, respectively. © The Electrochemical Society.

COSMIC-RAY TRANSPORT AND ANISOTROPIES

Energy Technology Data Exchange (ETDEWEB)

Biermann, Peter L. [MPI for Radioastronomy, Auf dem Huegel 69, D-53121 Bonn (Germany); Becker Tjus, Julia; Mandelartz, Matthias [Ruhr-Universitaet Bochum, Fakultaet fuer Physik and Astronomie, Theoretische Physik I, D-44780 Bochum (Germany); Seo, Eun-Suk [Department of Physics, University of Maryland, College Park, MD 20742 (United States)

2013-05-10

We show that the large-scale cosmic-ray anisotropy at {approx}10 TeV can be explained by a modified Compton-Getting effect in the magnetized flow field of old supernova remnants. Cosmic rays arrive isotropically to the flow field and are then carried along with the flow to produce a large-scale anisotropy in the arrival direction. This approach suggests an optimum energy scale for detecting the anisotropy. Two key assumptions are that propagation is based on turbulence following a Kolmogorov law and that cosmic-ray interactions are dominated by transport via cosmic-ray-excited magnetic irregularities through the stellar wind of an exploding star and its shock shell. A prediction is that the amplitude is smaller at lower energies due to incomplete sampling of the velocity field and also smaller at larger energies due to smearing.

Shape-induced anisotropy in antiferromagnetic nanoparticles

International Nuclear Information System (INIS)

Gomonay, O.; Kondovych, S.; Loktev, V.

2014-01-01

High fraction of the surface atoms considerably enhances the influence of size and shape on the magnetic and electronic properties of nanoparticles. Shape effects in ferromagnetic nanoparticles are well understood and allow us to set and control the parameters of a sample that affect its magnetic anisotropy during production. In the present paper we study the shape effects in the other widely used magnetic materials – antiferromagnets, – which possess vanishingly small or zero macroscopic magnetization. We take into account the difference between the surface and bulk magnetic anisotropy of a nanoparticle and show that the effective magnetic anisotropy depends on the particle shape and crystallographic orientation of its faces. The corresponding shape-induced contribution to the magnetic anisotropy energy is proportional to the particle volume, depends on magnetostriction, and can cause formation of equilibrium domain structure. Crystallographic orientation of the nanoparticle surface determines the type of domain structure. The proposed model allows us to predict the magnetic properties of antiferromagnetic nanoparticles depending on their shape and treatment. - Highlights: • We demonstrate that the shape effects in antiferromagnetic nanoparticles stem from the difference of surface and bulk magnetic properties combined with strong magnetoelastic coupling. • We predict shape-induced anisotropy in antiferromagnetic particles with large aspect ratio. • We predict different types of domain structures depending on the orientation of the particle faces

Electrical resistivity characterization of anisotropy in the Biscayne Aquifer.

Science.gov (United States)

Yeboah-Forson, Albert; Whitman, Dean

2014-01-01

Electrical anisotropy occurs when electric current flow varies with azimuth. In porous media, this may correspond to anisotropy in the hydraulic conductivity resulting from sedimentary fabric, fractures, or dissolution. In this study, a 28-electrode resistivity imaging system was used to investigate electrical anisotropy at 13 sites in the Biscayne Aquifer of SE Florida using the rotated square array method. The measured coefficient of electrical anisotropy generally ranged from 1.01 to 1.12 with values as high as 1.36 found at one site. The observed electrical anisotropy was used to estimate hydraulic anisotropy (ratio of maximum to minimum hydraulic conductivity) which ranged from 1.18 to 2.83. The largest values generally were located on the Atlantic Coastal Ridge while the lowest values were in low elevation areas on the margin of the Everglades to the west. The higher values of anisotropy found on the ridge may be due to increased dissolution rates of the oolitic facies of the Miami formation limestone compared with the bryozoan facies to the west. The predominate trend of minimum resistivity and maximum hydraulic conductivity was E-W/SE-NW beneath the ridge and E-W/SW-NE farther west. The anisotropy directions are similar to the predevelopment groundwater flow direction as indicated in published studies. This suggests that the observed anisotropy is related to the paleo-groundwater flow in the Biscayne Aquifer. © 2013, National Ground Water Association.

Magnetoresistance anisotropy of ultrathin epitaxial La0.83Sr0.17MnO3 films

Science.gov (United States)

Balevičius, Saulius; Tornau, Evaldas E.; ŽurauskienÄ--, Nerija; Stankevič, Voitech; Šimkevičius, Česlovas; TolvaišienÄ--, Sonata; PlaušinaitienÄ--, Valentina; Abrutis, Adulfas

2017-12-01

We present the study of temperature dependence of resistivity (ρ), magnetoresistance (MR), and magnetoresistance anisotropy (AMR) of thin epitaxial La0.83Sr0.17MnO3 films. The films with thickness from 4 nm to 140 nm were grown on an NdGaO3 (001) substrate by a pulsed injection metal organic chemical vapor deposition technique. We demonstrate that the resistivity of these films significantly increases and the temperature Tm of the resistivity maximum in ρ(T) dependence decreases with the decrease of film thickness. The anisotropy of ρ(T) dependence with respect to the electrical current direction along the [100] or [010] crystallographic axis of the film is found for ultrathin films (4-8 nm) at temperatures close to Tm. Both MR and AMR, measured in magnetic fields up to 0.7 T applied in the film plane parallel and perpendicular to the current direction, have shown strong dependence on the film thickness. It was also found that the anisotropy of magnetoresistance could change its sign from positive (thicker films) to negative (ultrathin films) and obtain very small values at a certain intermediate thickness (20 nm) when the current is flowing perpendicular to the easy magnetization axis [010]. While the positive AMR effect was assigned to the conventional magnetic ordering of manganites, the AMR of ultrathin films was influenced by the pinning of magnetization to the easy axis. The temperature dependence and change of the AMR sign with film thickness is shown to be well described by the two-region model (more strained closer to the film substrate and more relaxed further from it) assuming that the relative concentration of both regions changes with the film thickness. The possibility to use the effect of the AMR compensation for the development of scalar in-plane magnetic field sensors is discussed.

Tuning the surface anisotropy in Fe-doped NiO nanoparticles.

Science.gov (United States)

Moura, K O; Lima, R J S; Coelho, A A; Souza-Junior, E A; Duque, J G S; Meneses, C T

2014-01-07

Ni(1-x)FexO nanoparticles have been obtained by the co-precipitation chemical route. X-ray diffraction analyses using Rietveld refinement have shown a slight decrease in the microstrain and mean particle size as a function of the Fe content. The zero-field-cooling (ZFC) and field-cooling (FC) magnetization curves show superparamagnetic behavior at high temperatures and a low temperature peak (at T = 11 K), which is enhanced with increasing Fe concentration. Unusual behavior of the coercive field in the low temperature region and an exchange bias behavior were also observed. A decrease in the Fe concentration induces an increase in the exchange bias field. We argue that these behaviors can be linked with the strengthening of surface anisotropy caused by the incorporation of Fe ions.

Non-Gaussianity and the Cosmic Microwave Background Anisotropies

Directory of Open Access Journals (Sweden)

N. Bartolo

2010-01-01

microwave background (CMB anisotropies. We first show how to set the initial conditions at second order for the CMB anisotropies when some primordial NG is present. However, there are many sources of NG in CMB anisotropies, beyond the primordial one, which can contaminate the primordial signal. We mainly focus on the NG generated from the post inflationary evolution of the CMB anisotropies at second order in perturbation theory at large and small angular scales, such as the ones generated at the recombination epoch. We show how to derive the equations to study the second-order CMB anisotropies and provide analytical computations to evaluate their contamination to primordial NG (complemented with numerical examples. We also offer a brief summary of other secondary effects. This paper requires basic knowledge of the theory of cosmological perturbations at the linear level.

Magnetisation switching in a ferromagnetic Heisenberg nanoparticle with uniaxial anisotropy: a Monte Carlo investigation

International Nuclear Information System (INIS)

Ledue, D.; Berche, P.E.; Patte, R.

2004-01-01

We investigate the thermal-activated magnetisation reversal in a single ferromagnetic nanoparticle with uniaxial anisotropy using Monte Carlo simulations. The aim of this work is to reproduce the reversal magnetisation by uniform rotation at very low temperature in the high-energy barrier hypothesis, that is to realize the Neel-Brown model. For this purpose we have considered a simple cubic nanoparticle where each site is occupied by a classical Heisenberg spin. The Hamiltonian is the sum of an exchange interaction term, a single-ion anisotropy term and a Zeeman interaction term. Our numerical data of the thermal variation of the switching field are compared to an approximated expression and previous experimental results on Co nanoparticles

Proton-proton bremsstrahlung

International Nuclear Information System (INIS)

Fearing, H.W.

1990-01-01

We summarize some of the information about the nucleon-nucleon force which has been obtained by comparing recent calculations of proton-proton bremsstrahlung with cross section and analyzing power data from the new TRIUMF bremsstrahlung experiment. Some comments are made as to how these results can be extended to neutron-proton bremsstrahlung. (Author) 17 refs., 6 figs

Time scales of bias voltage effects in FE/MgO-based magnetic tunnel junctions with voltage-dependent perpendicular anisotropy

International Nuclear Information System (INIS)

Lytvynenko, Ia.M.; Hauet, T.; Montaigne, F.; Bibyk, V.V.; Andrieu, S.

2015-01-01

Interplay between voltage-induced magnetic anisotropy transition and voltage-induced atomic diffusion is studied in epitaxial V/Fe (0.7 nm)/ MgO/ Fe(5 nm)/Co/Au magnetic tunnel junction where thin Fe soft electrode has in-plane or out-of-plane anisotropy depending on the sign of the bias voltage. We investigate the origin of the slow resistance variation occurring when switching bias voltage in opposite polarity. We demonstrate that the time to reach resistance stability after voltage switching is reduced when increasing the voltage amplitude or the temperature. A single energy barrier of about 0.2 eV height is deduced from temperature dependence. Finally, we demonstrate that the resistance change is not correlated to a change in soft electrode anisotropy. This conclusion contrasts with observations recently reported on analogous systems. - Highlights: • Voltage-induced time dependence of resistance is studied in epitaxial Fe/MgO/Fe. • Resistance change is not related to the bottom Fe/MgO interface. • The effect is thermally activated with an energy barrier of the order of 0.2 eV height

Elastic Anisotropy of Basalt

Science.gov (United States)

Becker, K.; Shapiro, S.; Stanchits, S.; Dresen, G.; Kaselow, A.; Vinciguerra, S.

2005-12-01

Elastic properties of rocks are sensitive to changes of the in-situ stress and damage state. In particular, seismic velocities are strongly affected by stress-induced formation and deformation of cracks or shear-enhanced pore collapse. The effect of stress on seismic velocities as a result of pore space deformation in isotropic rock at isostatic compression may be expressed by the equation: A+K*P-B*exp (-D*P) (1), where P=Pc-Pp is the effective pressure, the pure difference between confining pressure and pore pressure. The parameter A, K, B and D describe material constants determined using experimental data. The physical meaning of the parameters is given by Shapiro (2003, in Geophysics Vol.68(Nr.2)). Parameter D is related to the stress sensitivity of the rock. A similar relation was derived by Shapiro and Kaselow (2005, in Geophysics in press) for weak anisotropic rocks under arbitrary load. They describe the stress dependent anisotropy in terms of Thomson's (1986, in Geophysics, Vol. 51(Nr.10)) anisotropy parameters ɛ and γ as a function of stress in the case of an initially isotropic rock: ɛ ∝ E2-E3, γ ∝ E3-E2 (2) with Ei=exp (D*Pi). The exponential terms Ei are controlled by the effective stress components Pi. To test this relation, we have conducted a series of triaxial compression tests on dry samples of initially isotropic Etnean Basalt in a servo-controlled MTS loading frame equipped with a pressure cell. Confining pressure was 60, 40 and 20 MPa. Samples were 5 cm in diameter and 10 cm in length. Elastic anisotropy was induced by axial compression of the samples through opening and growth of microcracks predominantly oriented parallel to the sample axis. Ultrasonic P- and S- wave velocities were monitored parallel and normal to the sample axis by an array of 20 piezoceramic transducers glued to the surface. Preamplified full waveform signals were stored in two 12 channel transient recorders. According to equation 2 the anisotropy parameters are

Anhydrous proton conducting composite membranes containing Nafion and triazole modified POSS

International Nuclear Information System (INIS)

Lei, M.; Wang, Y.G.; Zhang, F.F.; Huang, C.; Xu, X.; Zhang, R.; Fan, D.Y.

2014-01-01

Development of membrane electrolytes having reasonable proton conductivity and mechanical strength under anhydrous conditions is of great importance for proton exchange membrane fuel cells operated at elevated temperature. With the introduction of triazole modified polyhedral oligomeric silsesquioxanes (Tz-POSS) into Nafion membrane, the formed composite electrolytes exhibit improved mechanical properties compared to pristine Nafion membrane due to the well distribution of Tz-POSS inside the membrane. The anhydrous proton conductivity of the formed composite membranes increases initially with the increase in temperature, reaching about 0.02 Scm −1 at 140 °C. With further increase in temperature to about 150 °C, the composite membrane reaches its glass transition point above which the proton conductivity decreases dramatically. The performance of assembled single cell from composite membrane is slightly dependent on humidification conditions at 95 °C, reaching 0.45 V at 600 mAcm −2 using hydrogen and oxygen as reaction gases

Large-angle cosmic microwave background anisotropies in an open universe

Science.gov (United States)

Kamionkowski, Marc; Spergel, David N.

1994-01-01

If the universe is open, scales larger than the curvature scale may be probed by observation of large-angle fluctuations in the cosmic microwave background (CMB). We consider primordial adiabatic perturbations and discuss power spectra that are power laws in volume, wavelength, and eigenvalue of the Laplace operator. Such spectra may have arisen if, for example, the universe underwent a period of `frustated' inflation. The resulting large-angle anisotropies of the CMB are computed. The amplitude generally increases as Omega is decreased but decreases as h is increased. Interestingly enough, for all three Ansaetze, anisotropies on angular scales larger than the curvature scale are suppressed relative to the anisotropies on scales smaller than the curvature scale, but cosmic variance makes discrimination between various models difficult. Models with 0.2 approximately less than Omega h approximately less than 0.3 appear compatible with CMB fluctuations detected by Cosmic Background Explorer Satellite (COBE) and the Tenerife experiment and with the amplitude and spectrum of fluctuations of galaxy counts in the APM, CfA, and 1.2 Jy IRAS surveys. COBE normalization for these models yields sigma(sub 8) approximately = 0.5 - 0.7. Models with smaller values of Omega h when normalized to COBE require bias factors in excess of 2 to be compatible with the observed galaxy counts on the 8/h Mpc scale. Requiring that the age of the universe exceed 10 Gyr implies that Omega approximately greater than 0.25, while requiring that from the last-scattering term in the Sachs-Wolfe formula, large-angle anisotropies come primarily from the decay of potential fluctuations at z approximately less than 1/Omega. Thus, if the universe is open, COBE has been detecting temperature fluctuations produced at moderate redshift rather than at z approximately 1300.

Performance evaluation of an air-breathing high-temperature proton exchange membrane fuel cell

International Nuclear Information System (INIS)

Wu, Qixing; Li, Haiyang; Yuan, Wenxiang; Luo, Zhongkuan; Wang, Fang; Sun, Hongyuan; Zhao, Xuxin; Fu, Huide

2015-01-01

Highlights: • An air-breathing HT-PEMFC was designed and evaluated experimentally. • The peak power density of the air-breathing HT-PEMFC was 220.5 mW cm"−"2 at 200 °C. • Break-in behavior and effects of temperature and anodic stoichiometry were studied. • The effect of cell orientations on the performance was investigated. • The degradation rate of the air-breathing HT-PEMFC was around 58.32 μV h"−"1. - Abstract: The air-breathing proton exchange membrane fuel cell (PEMFC) is of great interest in mobile power sources because of its simple system design and low parasitic power consumption. Different from previous low-temperature air-breathing PEMFCs, a high-temperature PEMFC with a phosphoric acid doped polybenzimidazole (PBI) membrane as the polymer electrolyte is designed and investigated under air-breathing conditions. The preliminary results show that a peak power density of 220.5 mW cm"−"2 at 200 °C can be achieved without employing any water managements, which is comparable to those with conventional Nafion® membranes operated at low temperatures. In addition, it is found that with the present cell design, the limiting current density arising from the oxygen transfer limitation is around 700 mA cm"−"2 even at 200 °C. The short-term durability test at 200 mA cm"−"2 and 180 °C reveals that all the cells exhibit a gradual decrease in the voltage along with a rise in the internal resistance. The degradation rate of continuous operation is around 58.32 μV h"−"1, which is much smaller than those of start/stop cycling operations.

Temperature mapping using proton phase shift on a 0.3 T permanent magnet open MRI system

International Nuclear Information System (INIS)

Komura, Kazumi; Takahashi, Tetsuhiko; Dohi, Michiko; Harada, Junta

2000-01-01

Temperature mapping using proton phase shift (PPS) was evaluated for ex vivo objects. The evaluation was done on a 0.3 T permanent magnet open magnetic resonance imaging (MRI) machine, like those widely used for clinical diagnosis. Temperature maps were acquired using a gradient echo sequence (TR/TE =80/30 ms, flip angle =60 degrees, field of view =200 x 200 mm, slice thickness =8 mm, matrix size =128 x 128, data acquisition number =1, and imaging time =10.2 s). Specific first order data correction was performed to eliminate calculated temperature fluctuation due to magnetic field instability. A ham, 10 cm in diameter, was heated with a Nd: YAG laser with a wavelength of 1064 nm. The laser fiber was inserted into the ham to a depth of 3 cm. The laser power was 5, 8, or 10 W. Magnetic resonance images were taken continually during and after irradiation. Temperature maps were taken every 15 s. The maps taken during laser ablation showed color changes for the heated areas. Temperatures measured by the MRI and thermocouple had a linear relationship of r 2 =0.80. The inter-image standard deviation of the temperature maps of a non-heated object was 2.07 degrees for a 4.68 x 4.68 x 8 mm volume. This value is negligible for a monitored laser heating process since temperature rise is typically larger than 30 degrees. These results show that temperature mapping based on PPS is feasible for a 0.3 T permanent magnet open MRI system. (author)

Magnetic moment and magnetocrystalline anisotropy of 3d-ion subsystem in R2T14B

International Nuclear Information System (INIS)

Bartashevich, M.I.; Kudrevatykh, N.V.; Andreev, A.V.; Rejmer, V.A.

1990-01-01

The effect of substituting cobalt for iron on the magnetic moment, magneto-crystalline anisotropy and thermal expansion of R 2 (Fe 1-x Co x ) 14 B single crystals (R=Y, Gd, 0≤x≤0.3) is investigated. The uniaxial magnetic anisotropy constant K 1 for the 3d-subsystem passes through a maximum at T=4.2 K with increasing Co concentration. For T c the temperature dependence of K 1 does not possess a positive slope. The magnetic moment of the 3d-subsystem at 4.2 K does not exhibit the maximum at intermediate concentrations observed for most R(Fe, Co)-intermetallics. An explanation is presented of the changes in the magnetic properties. It is shown that the variation of the interatomic distances on thermal expansion should not affect the magnitude of the anisotropy constant of the 3d- and R-subsystems

Better Proton-Conducting Polymers for Fuel-Cell Membranes

Science.gov (United States)

Narayan, Sri; Reddy, Prakash

2012-01-01

Polyoxyphenylene triazole sulfonic acid has been proposed as a basis for development of improved proton-conducting polymeric materials for solid-electrolyte membranes in hydrogen/air fuel cells. Heretofore, the proton-conducting membrane materials of choice have been exemplified by a family of perfluorosulfonic acid-based polymers (Nafion7 or equivalent). These materials are suitable for operation in the temperature of 75 to 85 C, but in order to reduce the sizes and/or increase the energy-conversion efficiencies of fuel-cell systems, it would be desirable to increase temperatures to as high as 120 C for transportation applications, and to as high as 180 C for stationary applications. However, at 120 C and at relative humidity values below 50 percent, the loss of water from perfluorosulfonic acid-based polymer membranes results in fuel-cell power densities too low to be of practical value. Therefore, membrane electrolyte materials that have usefully high proton conductivity in the temperature range of 180 C at low relative humidity and that do not rely on water for proton conduction at 180 C would be desirable. The proposed polyoxyphenylene triazole sulfonic acid-based materials have been conjectured to have these desirable properties. These materials would be free of volatile or mobile acid constituents. The generic molecular structure of these materials is intended to exploit the fact, demonstrated in previous research, that materials that contain ionizable acid and base groups covalently attached to thermally stable polymer backbones exhibit proton conduction even in the anhydrous state.

Polarized proton and deuteron targets for the usage in intensive proton beams

International Nuclear Information System (INIS)

Get'man, V.A.; Derkach, A.Ya.; Karnaukhov, I.M.; Lukhanin, A.A.; Razumnyj, A.A.; Sorokin, P.V.; Sporo, E.A.; Telegin, Yu.N.

1982-01-01

Polarized proton and deuteron targets are developed and tested for conducting investigations in intense photon beams. A flowsheet of polarization targets which includes: working agent of the target, superconducting magnet, cryostat of 3 He evaporation with 3 He pumping and recirculation systems, SHF system of 4 mm range for polarization pumping, measuring system of target polarization protons is presented. Working agent of the targets includes frozen balls with 1.5 mm diameter. Ethylene-glucol and 1.2-propylene-glycol were used as a working substance for proton targets. Completely deuterated ethylene-glycol was used for the deuteron target. Vertical magnetic field with 2.7 T intensity is produced by a superconducting magnetic system. Polarization pumping is exercised at 75 GHz frequency. Q-meter of direct current is used for determination of polarization. Working temperature of the cryostat is approximately 0.5 K. The lock device permits to exercise replacement of the target working agent during 30 minutes

A perturbative DFT approach for magnetic anisotropy

Energy Technology Data Exchange (ETDEWEB)

Khoo, Khoong Hong; Laskowski, Robert, E-mail: rolask@ihpc.a-star.edu.sg

2017-04-15

We develop a perturbative formalism for computing magnetocrystalline anisotropy within density functional theory and the magnetic force theorem. Instead of computing eigenvalues of the spin–orbit Hamiltonian for selected spin polarizations, as in the conventional “force theorem” approach, we show that the effect can be cast into a redefined form of the spin–orbit operator. This allows to separate the large eigenvalue shift due to spin-orbit interaction common for both polarizations from the much smaller magnetic anisotropy splitting. As a consequence the anisotropy splitting may by considered as a perturbation.

Analysis of the austenitic stainless steel's r-value behavior at elevated temperatures

OpenAIRE

Dušan Arsić; Milan Djordjević; Srbislav Aleksandrović; Vukić Lazić; Ruzica R. Nikolic; Branislav Hadzima

2015-01-01

An analysis of the anisotropy properties of austenitic steel AISI 304 (X5CrNi18-10) at elevated temperatures is presented in this paper. Considerations of the anisotropy problems are presented in the theoretical part of the paper, as well as the procedure for determination of the normal anisotropy coefficient. The experimental part of the paper describes the plan, methodology and equipment for testing of material's normal anisotropy and mechanical characteristics. The objective of conducting ...

Millimeter Wavelength Observations of Galactic Sources with the Mobile Anisotropy Telescope (MAT)

Science.gov (United States)

Cruz, K. L.; Caldwell, R.; Devlin, M. J.; Dorwart, W. B.; Herbig, T.; Miller, A. D.; Nolta, M. R.; Page, L. A.; Puchalla, J. L.; Torbet, E.; Tran, H. T.

1999-12-01

The Mobile Anisotropy Telescope (MAT) has completed two observing seasons (1997 and 1998) in Chile from the Cerro Toco site. Although the primary goal of MAT was to measure anisotropy in the Cosmic Microwave Background (CMB) radiation, the chosen observation scheme also allowed daily viewing of the Galactic Plane. We present filtered maps at 30, 40 and 144 GHz of a region of the Galactic Plane which contains several millimeter-bright regions including the Carinae nebula and IRAS 11097-6102. We report the best fit brightness temperatures as well as the total flux densities in the MAT beams (0.9, 0.6 and 0.2 degrees FWHM) . The data are calibrated with respect to Jupiter whose flux is known to better than 8% in all frequency bands. This work was funded by the National Science Foundation and the Packard Foundation.

Electron mass anisotropy of BaZrO3 doped YBCO thin films in pulsed magnetic fields up to 30 T

International Nuclear Information System (INIS)

Palonen, H; Huhtinen, H; Paturi, P; Shakhov, M A

2013-01-01

The high anisotropy of the critical current density in the high-temperature superconductor YBa 2 Cu 3 O 6+x can be compensated by changing the pinning landscape, for example, through doping with BaZrO 3 . We measure the change due to BaZrO 3 doping in the effective electron mass anisotropy, γ, by resistive measurements of the upper critical field in pulsed high magnetic fields. It is found that the angular dependence of the upper critical field follows the Blatter scaling up to 30 T but the irreversibility field does not. We also report a significant reduction in the effective electron mass anisotropy from 6.0 to 3.4 by BaZrO 3 doping. (paper)

Thermal conductivity anisotropy in holey silicon nanostructures and its impact on thermoelectric cooling

Science.gov (United States)

Ren, Zongqing; Lee, Jaeho

2018-01-01

Artificial nanostructures have improved prospects of thermoelectric systems by enabling selective scattering of phonons and demonstrating significant thermal conductivity reductions. While the low thermal conductivity provides necessary temperature gradients for thermoelectric conversion, the heat generation is detrimental to electronic systems where high thermal conductivity are preferred. The contrasting needs of thermal conductivity are evident in thermoelectric cooling systems, which call for a fundamental breakthrough. Here we show a silicon nanostructure with vertically etched holes, or holey silicon, uniquely combines the low thermal conductivity in the in-plane direction and the high thermal conductivity in the cross-plane direction, and that the anisotropy is ideal for lateral thermoelectric cooling. The low in-plane thermal conductivity due to substantial phonon boundary scattering in small necks sustains large temperature gradients for lateral Peltier junctions. The high cross-plane thermal conductivity due to persistent long-wavelength phonons effectively dissipates heat from a hot spot to the on-chip cooling system. Our scaling analysis based on spectral phonon properties captures the anisotropic size effects in holey silicon and predicts the thermal conductivity anisotropy ratio up to 20. Our numerical simulations demonstrate the thermoelectric cooling effectiveness of holey silicon is at least 30% greater than that of high-thermal-conductivity bulk silicon and 400% greater than that of low-thermal-conductivity chalcogenides; these results contrast with the conventional perception preferring either high or low thermal conductivity materials. The thermal conductivity anisotropy is even more favorable in laterally confined systems and will provide effective thermal management solutions for advanced electronics.

Thermal conductivity anisotropy in holey silicon nanostructures and its impact on thermoelectric cooling.

Science.gov (United States)

Ren, Zongqing; Lee, Jaeho

2018-01-26

Artificial nanostructures have improved prospects of thermoelectric systems by enabling selective scattering of phonons and demonstrating significant thermal conductivity reductions. While the low thermal conductivity provides necessary temperature gradients for thermoelectric conversion, the heat generation is detrimental to electronic systems where high thermal conductivity are preferred. The contrasting needs of thermal conductivity are evident in thermoelectric cooling systems, which call for a fundamental breakthrough. Here we show a silicon nanostructure with vertically etched holes, or holey silicon, uniquely combines the low thermal conductivity in the in-plane direction and the high thermal conductivity in the cross-plane direction, and that the anisotropy is ideal for lateral thermoelectric cooling. The low in-plane thermal conductivity due to substantial phonon boundary scattering in small necks sustains large temperature gradients for lateral Peltier junctions. The high cross-plane thermal conductivity due to persistent long-wavelength phonons effectively dissipates heat from a hot spot to the on-chip cooling system. Our scaling analysis based on spectral phonon properties captures the anisotropic size effects in holey silicon and predicts the thermal conductivity anisotropy ratio up to 20. Our numerical simulations demonstrate the thermoelectric cooling effectiveness of holey silicon is at least 30% greater than that of high-thermal-conductivity bulk silicon and 400% greater than that of low-thermal-conductivity chalcogenides; these results contrast with the conventional perception preferring either high or low thermal conductivity materials. The thermal conductivity anisotropy is even more favorable in laterally confined systems and will provide effective thermal management solutions for advanced electronics.

Perpendicular magnetic anisotropy in CoXPd100-X alloys for magnetic tunnel junctions

Science.gov (United States)

Clark, B. D.; Natarajarathinam, A.; Tadisina, Z. R.; Chen, P. J.; Shull, R. D.; Gupta, S.

2017-08-01

CoFeB/MgO-based perpendicular magnetic tunnel junctions (p-MTJ's) with high anisotropy and low damping are critical for spin-torque transfer random access memory (STT-RAM). Most schemes of making the pinned CoFeB fully perpendicular require ferrimagnets with high damping constants, a high temperature-grown L10 alloy, or an overly complex multilayered synthetic antiferromagnet (SyAF). We report a compositional study of perpendicular CoxPd alloy-pinned Co20Fe60B20/MgO based MTJ stacks, grown at moderate temperatures in a planetary deposition system. The perpendicular anisotropy of the CoxPd alloy films can be tuned based on the layer thickness and composition. The films were characterized by alternating gradient magnetometry (AGM), energy-dispersive X-rays (EDX), and X-ray diffraction (XRD). Current-in-plane tunneling (CIPT) measurements have also been performed on the compositionally varied CoxPd MTJ stacks. The CoxPd alloy becomes fully perpendicular at approximately x = 30% (atomic fraction) Co. Full-film MTJ stacks of Si/SiO2/MgO (13)/CoXPd100-x (50)/Ta (0.3)/CoFeB (1)/MgO (1.6)/CoFeB (1)/Ta (5)/Ru (10), with the numbers enclosed in parentheses being the layer thicknesses in nm, were sputtered onto thermally oxidized silicon substrates and in-situ lamp annealed at 400 °C for 5 min. CIPT measurements indicate that the highest TMR is observed for the CoPd composition with the highest perpendicular magnetic anisotropy.

Supernovae anisotropy power spectrum

Energy Technology Data Exchange (ETDEWEB)

Ghodsi, Hoda; Baghram, Shant [Department of Physics, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of); Habibi, Farhang, E-mail: h.ghodsi@mehr.sharif.ir, E-mail: baghram@sharif.edu, E-mail: habibi@lal.in2p3.fr [LAL-IN2P3/CNRS, BP 34, 91898 Orsay Cedex (France)

2017-10-01

We contribute another anisotropy study to this field of research using Type Ia supernovae (SNe Ia). In this work, we utilise the power spectrum calculation method and apply it to both the current SNe Ia data and simulation. Using the Union2.1 data set at all redshifts, we compare the spectrum of the residuals of the observed distance moduli to that expected from an isotropic universe affected by the Union2.1 observational uncertainties at low multipoles. Through this comparison we find a dipolar anisotropy with tension of less that 2σ towards l = 171° ± 21° and b = −26° ± 28° which is mainly induced by anisotropic spatial distribution of the SNe with z > 0.2 rather than being a cosmic effect. Furthermore, we find a tension of ∼ 4σ at ℓ = 4 between the two spectra. Our simulations are constructed with the characteristics of the upcoming surveys like the Large Synoptic Survey Telescope (LSST), which shall bring us the largest SNe Ia collection to date. We make predictions for the amplitude of a possible dipolar anisotropy that would be detectable by future SNe Ia surveys.

Effects of low temperature periodic annealing on the deep-level defects in 200 keV proton irradiated AlGaAs-GaAs solar cells

Science.gov (United States)

Li, S. S.; Chiu, T. T.; Loo, R. Y.

1981-01-01

The GaAs solar cell has shown good potential for space applications. However, degradation in performance occurred when the cells were irradiated by high energy electrons and protons in the space environment. The considered investigation is concerned with the effect of periodic thermal annealing on the deep-level defects induced by the 200 keV protons in the AlGaAs-GaAs solar cells. Protons at a fluence of 10 to the 11th P/sq cm were used in the irradiation cycle, while annealing temperatures of 200 C (for 24 hours), 300 C (six hours), and 400 C (six hours) were employed. The most likely candidate for the E(c) -0.71 eV electron trap observed in the 200 keV proton irradiated samples may be due to GaAs antisite, while the observed E(v) +0.18 eV hole trap has been attributed to the gallium vacancy related defect. The obtained results show that periodic annealing in the considered case does not offer any advantages over the one time annealing process.

Non-Gaussianity and the Cosmic Microwave Background Anisotropies

CERN Document Server

Bartolo, N; Riotto, A

2010-01-01

We review in a pedagogical way the present status of the impact of non-Gaussianity (NG) on the Cosmic Microwave Background (CMB) anisotropies. We first show how to set the initial conditions at second-order for the (gauge invariant) CMB anisotropies when some primordial NG is present. However, there are many sources of NG in CMB anisotropies, beyond the primordial one, which can contaminate the primordial signal. We mainly focus on the NG generated from the post-inflationary evolution of the CMB anisotropies at second-order in perturbation theory at large and small angular scales, such as the ones generated at the recombination epoch. We show how to derive the equations to study the second-order CMB anisotropies and provide analytical computations to evaluate their contamination to primordial NG (complemented with numerical examples). We also offer a brief summary of other secondary effects. This review requires basic knowledge of the theory of cosmological perturbations at the linear level.

Enhanced superconductivity and anisotropy of FeTe0.6Se0.4 single crystals with Li -NH3 intercalation

Science.gov (United States)

Li, Chenghe; Sun, Shanshan; Wang, Shaohua; Lei, Hechang

2017-10-01

We report a systematic study of anisotropy resistivity, magnetoresistance, and Hall effect of Li0.32(NH3)yFe2Te1.2Se0.8 single crystals. When compared to the parent compound FeTe0.6Se0.4 , the Li-NH3 intercalation not only increases the superconducting transition temperature but also enhances the electronic anisotropy in both normal and superconducting states. Moreover, in contrast to the parent compound, the Hall coefficient RH becomes negative at low temperature, indicating electron-type carriers are dominant due to Li doping. On the other hand, the sign reverse of RH at high temperature and the failure of scaling behavior of magnetoresistance imply that hole pockets may be still crossing or just below the Fermi energy level, leading to the multiband behavior in Li0.32(NH3)yFe2Te1.2Se0.8 .

Field dependence and anisotropy of the Meissner effect in sintered and dilute powders of YBa2Cu3O7

International Nuclear Information System (INIS)

Regnier, P.; Bontemps, N.; Monod, P.

1990-01-01

We report low temperature field-cooled susceptibility measurements on sintered and dilute YBa 2 Cu 3 O 7 powders in a 3-40 Oe field range. We find that the so-called Meissner fraction is field dependent, increasing as the field increases in ceramics and decreasing in powders. We also find a strong anisotropy, in both sets of samples: the Meissner fraction is larger when the field is applied parallel to the c axis. All these features are shown to emerge naturally if one assumes that the low temperature Meissner fraction: i) reflects the field dependence and the anisotropic properties of the equilibrium Meissner fraction which has been trapped at higher temperature. ii) is further reduced and its anisotropy is enhanced in sintered compounds with respect to powders, due to flux pinning at the grain boundaries

Protein proton-proton dynamics from amide proton spin flip rates

International Nuclear Information System (INIS)

Weaver, Daniel S.; Zuiderweg, Erik R. P.

2009-01-01

Residue-specific amide proton spin-flip rates K were measured for peptide-free and peptide-bound calmodulin. K approximates the sum of NOE build-up rates between the amide proton and all other protons. This work outlines the theory of multi-proton relaxation, cross relaxation and cross correlation, and how to approximate it with a simple model based on a variable number of equidistant protons. This model is used to extract the sums of K-rates from the experimental data. Error in K is estimated using bootstrap methodology. We define a parameter Q as the ratio of experimental K-rates to theoretical K-rates, where the theoretical K-rates are computed from atomic coordinates. Q is 1 in the case of no local motion, but decreases to values as low as 0.5 with increasing domination of sidechain protons of the same residue to the amide proton flips. This establishes Q as a monotonous measure of local dynamics of the proton network surrounding the amide protons. The method is applied to the study of proton dynamics in Ca 2+ -saturated calmodulin, both free in solution and bound to smMLCK peptide. The mean Q is 0.81 ± 0.02 for free calmodulin and 0.88 ± 0.02 for peptide-bound calmodulin. This novel methodology thus reveals the presence of significant interproton disorder in this protein, while the increase in Q indicates rigidification of the proton network upon peptide binding, confirming the known high entropic cost of this process

Thermoelectric anisotropy in the iron-based superconductor Ba (Fe1-xCox) 2As2

Science.gov (United States)

Matusiak, Marcin; Rogacki, Krzysztof; Wolf, Thomas

2018-06-01

We report on the in-plane anisotropy of the Seebeck and Nernst coefficients as well as of the electrical resistivity determined for a series of strain-detwinned single crystals of Ba (Fe1-xC ox) 2A s2 . Two underdoped samples (x =0.024 , 0.045) exhibiting a transition from the tetragonal paramagnetic phase to the orthorhombic spin density wave (SDW) phase (at Ttr=100 and 60 K, respectively) show an onset of Nernst anisotropy at temperatures above 200 K, which is significantly higher than Ttr. In the optimally doped sample (x =0.06 ) the transport properties also appear to be in-plane anisotropic below T ≈120 K, despite the fact that this particular composition does not show any evidence of long-range magnetic order. However, the anisotropy observed in the optimally doped crystal is rather small, and for the Seebeck and Nernst coefficients the difference between values measured along and across the uniaxial strain has an opposite sign to those observed for underdoped crystals with x =0.024 and 0.045. For these two samples, the insensitivity of the Nernst anisotropy to the SDW transition suggests that the origin of nematicity might be something other than magnetic.

Evaluation of electrical resistivity anisotropy in geological mapping ...

African Journals Online (AJOL)

user

Key words: Electrical resistivity anisotropy, radial vertical electrical sounding, anisotropy polygons. INTRODUCTION ... electrical resistivity survey in the geological interpretation ... resistivity and other electrical or electromagnetic based.

Anisotropy in wavelet-based phase field models

KAUST Repository

Korzec, Maciek; Mü nch, Andreas; Sü li, Endre; Wagner, Barbara

2016-01-01

When describing the anisotropic evolution of microstructures in solids using phase-field models, the anisotropy of the crystalline phases is usually introduced into the interfacial energy by directional dependencies of the gradient energy coefficients. We consider an alternative approach based on a wavelet analogue of the Laplace operator that is intrinsically anisotropic and linear. The paper focuses on the classical coupled temperature/Ginzburg--Landau type phase-field model for dendritic growth. For the model based on the wavelet analogue, existence, uniqueness and continuous dependence on initial data are proved for weak solutions. Numerical studies of the wavelet based phase-field model show dendritic growth similar to the results obtained for classical phase-field models.

Anisotropy in wavelet-based phase field models

KAUST Repository

Korzec, Maciek

2016-04-01

When describing the anisotropic evolution of microstructures in solids using phase-field models, the anisotropy of the crystalline phases is usually introduced into the interfacial energy by directional dependencies of the gradient energy coefficients. We consider an alternative approach based on a wavelet analogue of the Laplace operator that is intrinsically anisotropic and linear. The paper focuses on the classical coupled temperature/Ginzburg--Landau type phase-field model for dendritic growth. For the model based on the wavelet analogue, existence, uniqueness and continuous dependence on initial data are proved for weak solutions. Numerical studies of the wavelet based phase-field model show dendritic growth similar to the results obtained for classical phase-field models.

Determination of magnetic characteristics of nanoparticles by low-temperature calorimetry methods

Energy Technology Data Exchange (ETDEWEB)

Ugulava, A.; Toklikishvili, Z. [Department of Physics, I.Javakhishvili Tbilisi State University,I.Chavchavadze av. 3, 0179 Tbilisi, Georgia (United States); Chkhaidze, S., E-mail: simon.chkhaidze@tsu.ge [Department of Physics, I.Javakhishvili Tbilisi State University,I.Chavchavadze av. 3, 0179 Tbilisi, Georgia (United States); Kekutia, Sh. [V. Chavchanidze Institute of Cybernetics, at the Technical State University, S. Euli str. 5, 0186 Tbilisi, Georgia (United States)

2017-05-15

At low temperatures, the heat capacity of a superparamagnetic “ideal gas” determined by magnetic degrees of freedom can greatly exceed the lattice heat capacity. It is shown that in the presence of an external magnetic field, the temperature dependence of the magnetic part of the heat capacity has two maxima. The relations between the temperature at which these maxima are achieved, the magnetic moment of the nanoparticles and the magnetic anisotropy constant have been obtained. Measuring the heat capacity maxima temperatures by low-temperature calorimetry methods and using the obtained relations, we can obtain the numerical values both of the magnetic moment of nanoparticles and the magnetic anisotropy constants.

Proton Conductivity and Operational Features Of PBI-Based Membranes

DEFF Research Database (Denmark)

Qingfeng, Li; Jensen, Jens Oluf; Precht Noyé, Pernille

2005-01-01

As an approach to high temperature operation of PEMFCs, acid-doped PBI membranes are under active development. The membrane exhibits high proton conductivity under low water contents at temperatures up to 200°C. Mechanisms of proton conduction for the membranes have been proposed. Based on the me...... on the membranes fuel cell tests have been demonstrated. Operating features of the PBI cell include no humidification, high CO tolerance, better heat utilization and possible integration with fuel processing units. Issues for further development are also discussed....

Changes in the anisotropy of oriented membrane dynamics induced by myelin basic protein

Energy Technology Data Exchange (ETDEWEB)

Natali, F. [OGG-INFM, Grenoble (France); Gliozzi, A.; Rolandi, R.; Relini, A. [Dipartimento di Fisica and Istituto Nazionale per la Fisica della Materia, Universita di Genova (Italy); Cavatorta, P.; Deriu, A. [Dipartimento di Fisica and Istituto Nazionale per la Fisica della Materia, Universita di Parma (Italy); Fasano, A. [Dipartimento di Biochimica e Biologia Molecolare, Universita di Bari (Italy); Riccio, P. [Dipartimento di Biologia D.B.A.F., Universita della Basilicata, Potenza (Italy)

2002-07-01

We report recent results showing the evidence of the effect induced by physiological amounts of myelin basic protein (MBP) on the dynamics of dimyristoyl L-a-phosphatidic acid (DMPA) membranes. Incoherent elastic neutron scattering scans, performed over a wide temperature range, have shown that the anisotropy of motions in oriented membranes is significantly enhanced by the presence of MBP. (orig.)

Temperature effects on the mechanical properties of candidate SNS target container materials after proton and neutron irradiation

International Nuclear Information System (INIS)

Byun, T.S.; Farrell, K.; Lee, E.H.; Mansur, L.K.; Maloy, S.A.; James, M.R.; Johnson, W.R.

2002-01-01

This report presents the tensile properties of EC316LN austenitic stainless steel and 9Cr-2WVTa ferritic/martensitic steel after 800 MeV proton and spallation neutron irradiation to doses in the range 0.54-2.53 dpa at 30-100 deg. C. Tensile testing was performed at room temperature (20 deg. C) and 164 deg. C. The EC316LN stainless steel maintained notable strain-hardening capability after irradiation, while the 9Cr-2WVTa ferritic/martensitic steel posted negative hardening in the engineering stress-strain curves. In the EC316LN stainless steel, increasing the test temperature from 20 to 164 deg. C decreased the strength by 13-18% and the ductility by 8-36%. The effect of test temperature for the 9Cr-2WVTa ferritic/martensitic steel was less significant than for the EC316LN stainless steel. In addition, strain-hardening behaviors were analyzed for EC316LN and 316L stainless steels. The strain-hardening rate of the 316 stainless steels was largely dependent on test temperature. A calculation using reduction of area measurements and stress-strain data predicted positive strain hardening during plastic instability

Dielectron production in proton-proton collisions with ALICE

CERN Document Server

Koehler, Markus K

Ultrarelativistic hadron collisions, such as delivered since a couple of years at the Large Hadron Collider (LHC), provide new insights into the properties of strongly interacting matter at high temperatures and densities, which is expected to have existed a few of a millionth seconds after the big bang. Electromagnetic probes, such as leptons and photons, are emitted during the entire collision. Since they do not undergo strong interactions, they reflect the entire evolution of the collision.\\\\ Pairs of leptons, so called dileptons, have the advantage compared to real photons, that they do not only carry momentum, but also have a non-zero invariant mass. The invariant mass spectrum of dileptons is a superposition of several components and allows to address different characteristics of the medium.\\\\ To understand dielectron production in heavy-ion collisions, reference measurements in proton-proton (pp) collisions are necessary. pp collisions reflect the vacuum contribution of the particles produced in heavy-...

NMR studies of interfaces, strain and anisotropy in Co/Cu multilayers

International Nuclear Information System (INIS)

Thomson, T.; Riedi, P.C.

1999-01-01

59 Co NMR studies of multilayers are able to give three direct pieces of information: (i) the crystal phase of Co, fcc (217.4 MHz), hcp (220-228 MHz) and in exotic cases bcc (198 MHz) for films measured at T= 4.2 K, (ii) the nature of the interfaces from low frequency satellite lines, and (iii) the strain state deduced from small changes in the line positions. Extensive studies of Co/Cu multilayer interfacial structures as a function of deposition technique, layer thickness, substrate/buffer layer structure and annealing temperature have been undertaken. This work has shed new light on the relationship between interfacial structure and magnetoresistance and in particular has demonstrated that flat, atomic scale, interfaces lead to greater magnetoresistance. The difference between the Co and Cu lattice constant results in an extensive, tensile in-plane strain developing in Co layers provided that some epitaxial registry is present. Information on strain effects can be obtained from the position and width of the NMR lines. The magnetic anisotropy field can be determined by measuring the field dependence of the enhancement effect due to electronic magnetisation. This provides unique insight into the distribution of magnetic anisotropy within the Co layers, as the enhancement can be investigated independently for each NMR line and, hence, provides environment specific information on magnetic anisotropy at the interfaces and in the interior of the layers

Effect of heat treatment on the microstructure, texture and elastic anisotropy of the nickel-based superalloy CM247LC processed by selective laser melting

International Nuclear Information System (INIS)

Muñoz-Moreno, R.; Divya, V.D.; Driver, S.L.; Messé, O.M.D.M.; Illston, T.; Baker, S.; Carpenter, M.A.; Stone, H.J.

2016-01-01

Selective laser melting (SLM) of nickel-based superalloys is of great interest for the aerospace industry due to its capability for producing components with complex geometries. However, an improved understanding of the effect of SLM and subsequent post deposition heat treatments on the microstructure and mechanical properties is required to ensure that components with good structural integrity are produced. In this study, the microstructure, texture and elastic anisotropy of the nickel-based superalloy, CM247LC, in the as-SLM and heat-treated states have been analysed. The as-SLM microstructure showed fine elongated cells with a preferential alignment of <001> along the build direction and a significant intercellular misorientation. Heat treatments at temperatures below 1230 °C resulted in a progressive recovery of the microstructure, whilst heat treatments above this temperature gave rise to a recrystallised microstructure. The extent to which nucleation and growth of the γ′ precipitates and secondary particles were affected by increasing the heat treatment temperature was also characterised. The bulk elastic anisotropy of all samples was measured by resonant ultrasound spectroscopy (RUS) and was found to be consistent with the local textures obtained by electron backscatter diffraction (EBSD). It was observed that the initially strong elastic anisotropy exhibited by the as-SLM material was significantly reduced in the recrystallised samples, although some anisotropy was retained as a result of their elongated grain microstructures.

Effect of heat treatment on the microstructure, texture and elastic anisotropy of the nickel-based superalloy CM247LC processed by selective laser melting

Energy Technology Data Exchange (ETDEWEB)

Muñoz-Moreno, R., E-mail: rociomunozmoreno@gmail.com [Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS (United Kingdom); Divya, V.D. [Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS (United Kingdom); Driver, S.L. [Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS (United Kingdom); Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ (United Kingdom); Messé, O.M.D.M. [Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS (United Kingdom); Illston, T.; Baker, S. [Materials Solutions, Unit 8, Great Western Business Park, McKenzie Way, Worcester WR4 9GN (United Kingdom); Carpenter, M.A. [Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ (United Kingdom); Stone, H.J. [Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS (United Kingdom)

2016-09-30

Selective laser melting (SLM) of nickel-based superalloys is of great interest for the aerospace industry due to its capability for producing components with complex geometries. However, an improved understanding of the effect of SLM and subsequent post deposition heat treatments on the microstructure and mechanical properties is required to ensure that components with good structural integrity are produced. In this study, the microstructure, texture and elastic anisotropy of the nickel-based superalloy, CM247LC, in the as-SLM and heat-treated states have been analysed. The as-SLM microstructure showed fine elongated cells with a preferential alignment of <001> along the build direction and a significant intercellular misorientation. Heat treatments at temperatures below 1230 °C resulted in a progressive recovery of the microstructure, whilst heat treatments above this temperature gave rise to a recrystallised microstructure. The extent to which nucleation and growth of the γ′ precipitates and secondary particles were affected by increasing the heat treatment temperature was also characterised. The bulk elastic anisotropy of all samples was measured by resonant ultrasound spectroscopy (RUS) and was found to be consistent with the local textures obtained by electron backscatter diffraction (EBSD). It was observed that the initially strong elastic anisotropy exhibited by the as-SLM material was significantly reduced in the recrystallised samples, although some anisotropy was retained as a result of their elongated grain microstructures.

Motion induced second order temperature and y-type anisotropies after the subtraction of linear dipole in the CMB maps

International Nuclear Information System (INIS)

Sunyaev, Rashid A.; Khatri, Rishi

2013-01-01

y-type spectral distortions of the cosmic microwave background allow us to detect clusters and groups of galaxies, filaments of hot gas and the non-uniformities in the warm hot intergalactic medium. Several CMB experiments (on small areas of sky) and theoretical groups (for full sky) have recently published y-type distortion maps. We propose to search for two artificial hot spots in such y-type maps resulting from the incomplete subtraction of the effect of the motion induced dipole on the cosmic microwave background sky. This dipole introduces, at second order, additional temperature and y-distortion anisotropy on the sky of amplitude few μK which could potentially be measured by Planck HFI and Pixie experiments and can be used as a source of cross channel calibration by CMB experiments. This y-type distortion is present in every pixel and is not the result of averaging the whole sky. This distortion, calculated exactly from the known linear dipole, can be subtracted from the final y-type maps, if desired

Studies of anisotropy of iron based superconductors

Energy Technology Data Exchange (ETDEWEB)

Murphy, Jason A. [Iowa State Univ., Ames, IA (United States)

2013-01-01