WorldWideScience

Sample records for polarized infrared reflectivity

  1. Broadband infrared reflective surfaces using doped and stacked polar dielectric layers

    Science.gov (United States)

    Janipour, Mohsen; Sendur, Kursat

    2018-02-01

    Polar dielectrics, such as SiC, are excellent candidates for operation in extreme environments due to their excellent mechanical and thermal properties. In addition, they can achieve good IR reflection in the Reststrahlen band. However, these materials have relatively narrow spectral bandwidth for reflection, especially considering that the broadband illumination sources in extreme environments. In this study, we investigated the broadband reflection properties of polar dielectrics by engineering the Reststrahlen band through doping and stacked layers. Our results indicate that by doping polar dielectrics, spectral reflection bandwidth can be significantly broadened. In addition, we demonstrate that by stacking different polar dielectric layers, the reflection spectrum of different materials can be overlapped, and thereby, significantly broader spectrum is obtained.

  2. Increasing detectivity of polarization modulation infrared reflection-absorption spectroscopy for the study of ultrathin films deposited on various substrates.

    Science.gov (United States)

    Saccani, J; Buffeteau, T; Desbat, B; Blaudez, D

    2003-10-01

    In this paper, we present a simple way to increase the sensitivity of polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS) for the study of ultrathin films deposited on dielectric and semiconductor substrates. The enhancement of the absorption band intensity is obtained by reducing the signal arising from the substrate. This is achieved by adding a polarizer after the sample in order to balance the polarized reflectivities of the sample. As a consequence, the contribution of the film to the PM-IRRAS signal is increased relative to that of the substrate. An enhancement factor of about 10 has been obtained for ultrathin organic films deposited on glass and spread at the air-water interface. This method has also allowed the study of the very thin native oxide layer present on silicon without the need for the reference spectrum of bare silicon.

  3. Detecting Canopy Water Status Using Shortwave Infrared Reflectance Data From Polar Orbiting and Geostationary Platforms

    DEFF Research Database (Denmark)

    Fensholt, Rasmus; Huber Gharib, Silvia; Proud, Simon Richard

    2010-01-01

    analyses performed on SEVIRI SIWSI during a dry period within the growing season support these findings. These results suggest that the combined advantage of an improved temporal resolution and a fixed viewing angle potentially makes the SEVIRI sensor an interesting complementary data source to POES data......-based canopy water status detection from geostationary Meteosat Second Generation (MSG) Spinning Enhanced Visible and Infrared Imager (SEVIRI) data as compared to polar orbiting environmental satellite (POES)-based moderate resolution imaging spectroradiometer (MODIS) data. The EO-based SWIR water stress index...

  4. Selective Removal of Demineralization Using Near Infrared Cross Polarization Reflectance and a Carbon Dioxide Laser.

    Science.gov (United States)

    Chan, Kenneth H; Fried, Daniel

    2012-02-09

    Lasers can ablate/remove tissue in a non-contact mode of operation and a pulsed laser beam does not interfere with the ability to image the tooth surface, therefore lasers are ideally suited for integration with imaging devices for image-guided ablation. Laser energy can be rapidly and efficiently delivered to tooth surfaces using a digitally controlled laser beam scanning system for precise and selective laser ablation with minimal loss of healthy tissues. Under the appropriate irradiation conditions such laser energy can induce beneficial chemical and morphological changes in the walls of the drilled cavity that can increase resistance to further dental decay and produce surfaces with enhanced adhesive properties to restorative materials. Previous studies have shown that images acquired using near-IR transillumination, optical coherence tomography and fluorescence can be used to guide the laser for selective removal of demineralized enamel. Recent studies have shown that NIR reflectance measurements at 1470-nm can be used to obtain images of enamel demineralization with very high contrast. The purpose of this study was to demonstrate that image guided ablation of occlusal lesions can be successfully carried out using a NIR reflectance imaging system coupled with a carbon dioxide laser operating at 9.3-μm with high pulse repetition rates.

  5. In Situ Nondestructive Analysis of Kalanchoe pinnata Leaf Surface Structure by Polarization-Modulation Infrared Reflection-Absorption Spectroscopy.

    Science.gov (United States)

    Hama, Tetsuya; Kouchi, Akira; Watanabe, Naoki; Enami, Shinichi; Shimoaka, Takafumi; Hasegawa, Takeshi

    2017-12-14

    The outermost surface of the leaves of land plants is covered with a lipid membrane called the cuticle that protects against various stress factors. Probing the molecular-level structure of the intact cuticle is highly desirable for understanding its multifunctional properties. We report the in situ characterization of the surface structure of Kalanchoe pinnata leaves using polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS). Without sample pretreatment, PM-IRRAS measures the IR spectra of the leaf cuticle of a potted K. pinnata plant. The peak position of the CH 2 -related modes shows that the cuticular waxes on the leaf surface are mainly crystalline, and the alkyl chains are highly packed in an all-trans zigzag conformation. The surface selection rule of PM-IRRAS revealed the average orientation of the cuticular molecules, as indicated by the positive and negative signals of the IR peaks. This unique property of PM-IRRAS revealed that the alkyl chains of the waxes and the main chains of polysaccharides are oriented almost perpendicular to the leaf surface. The nondestructive, background-free, and environmental gas-free nature of PM-IRRAS allows the structure and chemistry of the leaf cuticle to be studied directly in its native environment.

  6. Layered magnets: polarized neutron reflection studies

    Energy Technology Data Exchange (ETDEWEB)

    Zabel, H.; Schreyer, A. [Ruhr-Univ. Bochum, Lehrstuhl fuer Experimentalphysik/Festkoerperphysik, Bochum (Germany)

    1996-11-01

    Neutron reflectivity measurements from extended surfaces, thin films and superlattices provide information on the chemical profile parallel to the film normal, including film thicknesses, average composition and interfacial roughness parameters. Reflectivity measurements with polarized neutrons are particularly powerful for analyzing the magnetic density profiles in thin films and superlattices in addition to chemical profiles. The basic theory of polarized neutron reflectivity is provided, followed by some examples and more recent applications concerning polarized neutron reflectivity studies from exchange coupled Fe/Cr superlattices. (author) 5 figs., 13 refs.

  7. Suomi National Polar-Orbiting Partnership Visible Infrared Imaging Radiometer Suite Polarization Sensitivity Analysis

    Science.gov (United States)

    Sun, Junqiang; Xiong, Xiaoxiong; Waluschka, Eugene; Wang, Menghua

    2016-01-01

    The Visible Infrared Imaging Radiometer Suite (VIIRS) is one of five instruments onboard the Suomi National Polar-Orbiting Partnership (SNPP) satellite that launched from Vandenberg Air Force Base, California, on October 28, 2011. It is a whiskbroom radiometer that provides +/-56.28deg scans of the Earth view. It has 22 bands, among which 14 are reflective solar bands (RSBs). The RSBs cover a wavelength range from 410 to 2250 nm. The RSBs of a remote sensor are usually sensitive to the polarization of incident light. For VIIRS, it is specified that the polarization factor should be smaller than 3% for 410 and 862 nm bands and 2.5% for other RSBs for the scan angle within +/-45deg. Several polarization sensitivity tests were performed prelaunch for SNPP VIIRS. The first few tests either had large uncertainty or were less reliable, while the last one was believed to provide the more accurate information about the polarization property of the instrument. In this paper, the measured data in the last polarization sensitivity test are analyzed, and the polarization factors and phase angles are derived from the measurements for all the RSBs. The derived polarization factors and phase angles are band, detector, and scan angle dependent. For near-infrared bands, they also depend on the half-angle mirror side. Nevertheless, the derived polarization factors are all within the specification, although the strong detector dependence of the polarization parameters was not expected. Compared to the Moderate Resolution Imaging Spectroradiometer on both Aqua and Terra satellites, the polarization effect on VIIRS RSB is much smaller.

  8. CVD molybdenum films of high infrared reflectance

    Energy Technology Data Exchange (ETDEWEB)

    Carver, G. E.

    1979-01-01

    Molybdenum thin films of high infrared reflectance have been deposited by pyrolytic decomposition of molybdenum carbonyl (Mo(CO)/sub 6/), and by hydrogen reduction of molybdenum pentachloride (MoCl/sub 5/). Reflectance values within 0.7% of the reflectance of supersmooth bulk molybdenum have been attained by annealing films of lower reflectance in both reducing and non-reducing atmospheres. All depositions and anneals proceed at atmospheric pressure, facilitating a continuous, flow-through fabrication. These reflectors combine the high temperature stability of molybdenum thin films with the infrared reflectance of a material such as aluminum. Deposition from Mo(CO)/sub 6/ under oxidizing conditions, and subsequent anneal in a reducing atmosphere, results in films that combine high solar absorptance with low thermal emittance. If anti-reflected, black molybdenum films can serve as highly selective single layer photothermal converters. Structural, compositional, and crystallographic properties have been measured after both deposition and anneal.

  9. Polarization modulation infrared reflection absorption spectroscopy investigations of thin silica films deposited on gold. 2. Structural analysis of a 1,2-dimyristoyl-sn-glycero-3-phosphocholine bilayer.

    Science.gov (United States)

    Zawisza, Izabella; Wittstock, Gunther; Boukherroub, Rabah; Szunerits, Sabine

    2008-04-15

    In this paper we report on the structural analysis of bilayers of 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) using polarization modulation infrared reflection absorption spectroscopy (PM IRRAS). The lipid bilayers were formed on SiO2|Au and Au surfaces using the Langmuir-Blodgett and Langmuir-Schaeffer techniques. As we showed in part 1 (Zawisza, I.; Wittstock, G.; Boukherroub, R.; Szunertis, S. Langmuir 2007, 23, 9303-9309), SiO2 layers of 7 nm thickness, synthesized by plasma-enhanced chemical vapor deposition on 200 nm thick gold covered glass slides, allow PM IRRAS investigations. Only minor changes in the order and structure of the lipid bilayer are observed when deposited on SiO2|Au and Au surfaces. The choline moiety in the leaflet directed toward the SiO2 surface exists in trans conformation and shows a tilt of 28 degrees with the surface normal of the CN bond. On the silica surface in the second leaflet directed toward air and in two layers deposited on the Au surface, trans and gauche isomers of the choline moiety are present and the tilt of the CN bond increases to 55 degrees with respect to the surface normal. The order and molecular orientation in the DMPC bilayers on SiO2 and Au surfaces are not affected by time. The analysis of the phosphate stretching mode on the Au surface shows slight dehydration of this group and reorientation of the phosphate moiety.

  10. Studies of dust grain properties in infrared reflection nebulae.

    Science.gov (United States)

    Pendleton, Y J; Tielens, A G; Werner, M W

    1990-01-20

    We have developed a model for reflection nebulae around luminous infrared sources embedded in dense dust clouds. The aim of this study is to determine the sizes of the scattering grains. In our analysis, we have adopted an MRN-like power-law size distribution (Mathis, Rumpl, and Nordsieck) of graphite and silicate grains, but other current dust models would give results which were substantially the same. In the optically thin limit, the intensity of the scattered light is proportional to the dust column density, while in the optically thick limit, it reflects the grain albedo. The results show that the shape of the infrared spectrum is the result of a combination of the scattering properties of the dust, the spectrum of the illuminating source, and foreground extinction, while geometry plays a minor role. Comparison of our model results with infrared observations of the reflection nebula surrounding OMC-2/IRS 1 shows that either a grain size distribution like that found in the diffuse interstellar medium, or one consisting of larger grains, can explain the observed shape of the spectrum. However, the absolute intensity level of the scattered light, as well as the observed polarization, requires large grains (approximately 5000 angstroms). By adding water ice mantles to the silicate and graphite cores, we have modeled the 3.08 micrometers ice band feature, which has been observed in the spectra of several infrared reflection nebulae. We show that this ice band arises naturally in optically thick reflection nebulae containing ice-coated grains. We show that the shape of the ice band is diagnostic of the presence of large grains, as previously suggested by Knacke and McCorkle. Comparison with observations of the BN/KL reflection nebula in the OMC-1 cloud shows that large ice grains (approximately 5000 angstroms) contribute substantially to the scattered light.

  11. Pigments which reflect infrared radiation from fire

    Science.gov (United States)

    Berdahl, Paul H.

    1998-01-01

    Conventional paints transmit or absorb most of the intense infrared (IR) radiation emitted by fire, causing them to contribute to the spread of fire. The present invention comprises a fire retardant paint additive that reflects the thermal IR radiation emitted by fire in the 1 to 20 micrometer (.mu.m) wavelength range. The important spectral ranges for fire control are typically about 1 to about 8 .mu.m or, for cool smoky fires, about 2 .mu.m to about 16 .mu.m. The improved inventive coatings reflect adverse electromagnetic energy and slow the spread of fire. Specific IR reflective pigments include titanium dioxide (rutile) and red iron oxide pigments with diameters of about 1 .mu.m to about 2 .mu.m and thin leafing aluminum flake pigments.

  12. CHROMOSPHERIC POLARIZATION IN THE PHOTOSPHERIC SOLAR OXYGEN INFRARED TRIPLET

    Energy Technology Data Exchange (ETDEWEB)

    Del Pino Alemán, Tanausú; Trujillo Bueno, Javier [Instituto de Astrofísica de Canarias, E-38205 La Laguna, Tenerife (Spain)

    2015-07-20

    We present multilevel radiative transfer modeling of the scattering polarization observed in the solar O i infrared triplet around 777 nm. We demonstrate that the scattering polarization pattern observed on the solar disk forms in the chromosphere, far above the photospheric region where the bulk of the emergent intensity profiles originate. We investigate the sensitivity of the polarization pattern to the thermal structure of the solar atmosphere and to the presence of weak magnetic fields (10{sup −2}–100 G) through the Hanle effect, showing that the scattering polarization signals of the oxygen infrared triplet encode information on the magnetism of the solar chromosphere.

  13. Light polarization management via reflection from arrays of sub-wavelength metallic twisted bands

    Science.gov (United States)

    Nawrot, M.; Haberko, J.; Zinkiewicz, Ł.; Wasylczyk, P.

    2017-12-01

    With constant progress of nano- and microfabrication technologies, photolithography in particular, a number of sub-wavelength metallic structures have been demonstrated that can be used to manipulate light polarization. Numerical simulations of light propagation hint that helical twisted bands can have interesting polarization properties. We use three-dimensional two-photon photolithography (direct laser writing) to fabricate a few-micrometer-thick arrays of twisted bands and coat them uniformly with metal. We demonstrate that circular polarization can be generated from linear polarization upon reflection from such structures over a broad range of frequencies in the mid infrared.

  14. Topological insulator infrared pseudo-bolometer with polarization sensitivity

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Peter Anand

    2017-10-25

    Topological insulators can be utilized in a new type of infrared photodetector that is intrinsically sensitive to the polarization of incident light and static magnetic fields. The detector isolates single topological insulator surfaces and allows light collection and exposure to static magnetic fields. The wavelength range of interest is between 750 nm and about 100 microns. This detector eliminates the need for external polarization selective optics. Polarization sensitive infrared photodetectors are useful for optoelectronics applications, such as light detection in environments with low visibility in the visible wavelength regime.

  15. [Research on the Thermal Infrared Polarization Properties of Fresh Snow].

    Science.gov (United States)

    Wang, Ting-ting; Li, Zhao-liang; Tang, Bo-hui; Sun, Wei-qi; Zhao, Yun-sheng

    2015-07-01

    Snow can directly affect the surface energy balance and climate change and has a significant impact on human life and production. It is therefore of great significance to study the fresh snow emission spectroscopy properties by using the thermal infrared Polarization technique. This can provide a basis for quantitative thermal infrared remote sensing monitoring of snow as well as a deeper understanding of global warming and appropriate countermeasures. This paper focuses on the investigation of the thermal infrared polarization properties of the fresh snow. The results show that the thermal emissive polarization properties of fresh snow depend significantly on the wavelengths (channels) and view angles used to measure them. Four channels are considered in this study, their spectral response ranges are 8-14 microm for channel 1 (CH1), 11.5-12.5 microm for channel 2 (CH2), 10.3-11.5 microm for channel 3 (CH) and 8.2-9.2 microm for channel 4 (CH4). The snow polarized radiance (L) and its polarized brightness temperature (T) manifest as L(CH1) >L(CH3) > L(CH4) > L(CH2) and T(CH4) > T(CH1) > T(CH2) > TCH3, respectively, while the degree of polarization (P) manifests as P0 > P30 > P40 > P20 > P0 > P50 where the subscript of P denotes the view angle. The maximum of both L and T occurs at the view angle of 50 degree and polarization angle of 90 degree while their minimum appears at the view angle of 30 degree and polarization angle of 75 degree for each channel. In addition, the results show that: CH3 is more appropriate for better investigation of the emissive polarization properties of snow. Linear relationship is found between the fresh snow polarized T and the polarization angle with the coefficient of determination larger than 0.77 for all four channels. The polarized brightness temperature of the fresh snow is found to be increased about 0.003 K per polarization angle within 0-135 degree. The degree of polarization of snow is almost independent of the channels we

  16. Soil classification using mid-infrared off-normal active differential reflectance characteristics

    International Nuclear Information System (INIS)

    Narayanan, R.M.; Green, S.E.; Alexander, D.R.

    1992-01-01

    Active mid-infrared laser reflectance characteristics of 18 different bench-mark soil samples were measured at various angles of incidence between 0° and 80° at 9.283-, 10/247-, and 10.633-μm wavelengths for both copolarized and cross-polarized conditions. Calibration was performed for each measurement using a Labsphere Infragold diffuse reflectance standard of 94 percent reflectance. One hundred independent reflectivity measurements were averaged for each combination to yield a mean reflectance value. The soil samples were characterized in terms of the soil taxonomy, mineralogy, geographic location, soil texture, and organic carbon content. Selected samples represented wide variability in soil properties

  17. [The research of the relationship between snow properties and the bidirectional polarized reflectance from snow surface].

    Science.gov (United States)

    Sun, Zhong-Qiu; Wu, Zheng-Fang; Zhao, Yun-Sheng

    2014-10-01

    In the context of remote sensing, the reflectance of snow is a key factor for accurate inversion for snow properties, such as snow grain size, albedo, because of it is influenced by the change of snow properties. The polarized reflectance is a general phenomenon during the reflected progress in natural incident light In this paper, based on the correct measurements for the multiple-angle reflected property of snow field in visible and near infrared wavelength (from 350 to 2,500 nm), the influence of snow grain size and wet snow on the bidirectional polarized property of snow was measured and analyzed. Combining the results measured in the field and previous conclusions confirms that the relation between polarization and snow grain size is obvious in infrared wavelength (at about 1,500 nm), which means the degree of polarization increasing with an increase of snow grain size in the forward scattering direction, it is because the strong absorption of ice near 1,500 nm leads to the single scattering light contributes to the reflection information obtained by the sensor; in other word, the larger grain size, the more absorption accompanying the larger polarization in forward scattering direction; we can illustrate that the change from dry snow to wet snow also influences the polarization property of snow, because of the water on the surface of snow particle adheres the adjacent particles, that means the wet snow grain size is larger than the dry snow grain size. Therefore, combining the multiple-angle polarization with reflectance will provide solid method and theoretical basis for inversion of snow properties.

  18. Grazing incidence polarized neutron scattering in reflection ...

    Indian Academy of Sciences (India)

    During the year 1980, polarized neutron scattering technique came into being as an ana- lytic tool to measure the ... The discovery of antiferromagnetic coupling was critical to the discovery of GMR, pro- viding as it did ..... Here we consider the incident wave vector ki making an angle αi in the x–z plane while the scattered ...

  19. Geomagnetic excursions reflect an aborted polarity state

    Science.gov (United States)

    Valet, Jean-Pierre; Plenier, Guillaume; Herrero-Bervera, E.

    2008-10-01

    Geomagnetic excursions represent short episodes of a few thousand years at most during which the field considerably exceeds its normal range of variability during a polarity state. Paleomagnetic records have now been obtained with extremely high temporal resolution which have improved our knowledge of these short events. We have compiled the most detailed records of excursions that had occurred during the Brunhes and Matuyama chrons. We show that virtual geomagnetic poles (VGPs) of at least one record of each event are able to reach the opposite polarity. In the next step, we have computed different simulations of excursions during which the dipole progressively vanishes before growing back without reversing. This scenario produces very few reversed directions which are only visible at some latitudes. We infer that it is impossible to reach the ratio of reversed to intermediate VGPs present in the paleomagnetic records if the excursions were not associated with a short period of reversed dipole field. Therefore, excursions should be regarded as two successive reversals bracketing an aborted polarity interval. We propose that the same underlying mechanisms prevail in both situations (excursions or reversals) and that below a certain strength the field reaches an unstable position which preludes either the achievement of a reversal or its return to the former polarity.

  20. Do cephalopods communicate using polarized light reflections from their skin?

    Science.gov (United States)

    Mäthger, Lydia M; Shashar, Nadav; Hanlon, Roger T

    2009-07-01

    Cephalopods (squid, cuttlefish and octopus) are probably best known for their ability to change color and pattern for camouflage and communication. This is made possible by their complex skin, which contains pigmented chromatophore organs and structural light reflectors (iridophores and leucophores). Iridophores create colorful and linearly polarized reflective patterns. Equally interesting, the photoreceptors of cephalopod eyes are arranged in a way to give these animals the ability to detect the linear polarization of incoming light. The capacity to detect polarized light may have a variety of functions, such as prey detection, navigation, orientation and contrast enhancement. Because the skin of cephalopods can produce polarized reflective patterns, it has been postulated that cephalopods could communicate intraspecifically through this visual system. The term 'hidden' or 'private' communication channel has been given to this concept because many cephalopod predators may not be able to see their polarized reflective patterns. We review the evidence for polarization vision as well as polarization signaling in some cephalopod species and provide examples that tend to support the notion--currently unproven--that some cephalopods communicate using polarized light signals.

  1. Adaptive infrared-reflecting systems inspired by cephalopods

    Science.gov (United States)

    Xu, Chengyi; Stiubianu, George T.; Gorodetsky, Alon A.

    2018-03-01

    Materials and systems that statically reflect radiation in the infrared region of the electromagnetic spectrum underpin the performance of many entrenched technologies, including building insulation, energy-conserving windows, spacecraft components, electronics shielding, container packaging, protective clothing, and camouflage platforms. The development of their adaptive variants, in which the infrared-reflecting properties dynamically change in response to external stimuli, has emerged as an important unmet scientific challenge. By drawing inspiration from cephalopod skin, we developed adaptive infrared-reflecting platforms that feature a simple actuation mechanism, low working temperature, tunable spectral range, weak angular dependence, fast response, stability to repeated cycling, amenability to patterning and multiplexing, autonomous operation, robust mechanical properties, and straightforward manufacturability. Our findings may open opportunities for infrared camouflage and other technologies that regulate infrared radiation.

  2. Infrared spectral reflectances of asteroid surfaces

    Science.gov (United States)

    Larson, H. P.; Veeder, G. J.

    1979-01-01

    This review compares the types of compositional information produced by three complementary techniques used in infrared observations of asteroid surfaces: broadband JHKL photometry, narrow band photometry, and multiplex spectroscopy. The high information content of these infrared observations permits definitive interpretations of asteroid surface compositions in terms of the major meteoritic minerals (olivine, pyroxene, plagioclase feldspar, hydrous silicates, and metallic Ni-Fe). These studies emphasize the individuality of asteroid surface compositions, the inadequacy of simple comparisons with spectra of meteorites, and the need to coordinate spectral measurements of all types to optimize diagnostic capabilities.

  3. NEAR-INFRARED LINEAR POLARIZATION OF ULTRACOOL DWARFS

    International Nuclear Information System (INIS)

    Zapatero Osorio, M. R.; Bejar, V. J. S.; Rebolo, R.; Acosta-Pulido, J. A.; Manchado, A.; Pena Ramirez, K.; Goldman, B.; Caballero, J. A.

    2011-01-01

    We report on near-infrared J- and H-band linear polarimetric photometry of eight ultracool dwarfs (two late-M, five L0-L7.5, and one T2.5) with known evidence for photometric variability due to dust clouds, anomalous red infrared colors, or low-gravity atmospheres. The polarimetric data were acquired with the LIRIS instrument on the William Herschel Telescope. We also provide mid-infrared photometry in the interval 3.4-24 μm for some targets obtained with Spitzer and WISE, which has allowed us to confirm the peculiar red colors of five sources in the sample. We can impose modest upper limits of 0.9% and 1.8% on the linear polarization degree for seven targets with a confidence of 99%. Only one source, 2MASS J02411151-0326587 (L0), appears to be strongly polarized (P ∼ 3%) in the J band with a significance level of P/σ P ∼ 10. The likely origin of its linearly polarized light and rather red infrared colors may reside in a surrounding disk with an asymmetric distribution of grains. Given its proximity (66 ± 8 pc), this object becomes an excellent target for the direct detection of the disk.

  4. Prediction of pork quality attributes from near infrared reflectance spectra

    NARCIS (Netherlands)

    Geesink, G.H.; Schreutelkamp, F.H.; Frankhuizen, R.; Vedder, H.W.; Faber, N.M.; Kranen, R.W.; Gerritzen, M.A.

    2003-01-01

    Near infrared spectroscopy (NIRS) is one of the most promising techniques for large-scale meat quality evaluation. We investigated the potential of NIRS-based models to predict drip loss and shear force of pork samples. Near infrared reflectance spectra (1000¿2500 nm), water-holding capacity, shear

  5. Mid infrared upconversion spectroscopy using diffuse reflectance

    DEFF Research Database (Denmark)

    Sanders, Nicolai Højer; Kehlet, Louis M.; Dam, Jeppe Seidelin

    2014-01-01

    specifically that upconversion methods can be deployed using a diffuse reflectance setup where the test sample is irradiated by a thermal light source, i.e. a globar. The diffuse reflectance geometry is particularly well suited when a transmission setup cannot be used. This situation may happen for highly...

  6. [Analysis of influencing factors of snow hyperspectral polarized reflections].

    Science.gov (United States)

    Sun, Zhong-Qiu; Zhao, Yun-Sheng; Yan, Guo-Qian; Ning, Yan-Ling; Zhong, Gui-Xin

    2010-02-01

    Due to the need of snow monitoring and the impact of the global change on the snow, on the basis of the traditional research on snow, starting from the perspective of multi-angle polarized reflectance, we analyzed the influencing factors of snow from the incidence zenith angles, the detection zenith angles, the detection azimuth angles, polarized angles, the density of snow, the degree of pollution, and the background of the undersurface. It was found that these factors affected the spectral reflectance values of the snow, and the effect of some factors on the polarization hyperspectral reflectance observation is more evident than in the vertical observation. Among these influencing factors, the pollution of snow leads to an obvious change in the snow reflectance spectrum curve, while other factors have little effect on the shape of the snow reflectance spectrum curve and mainly impact the reflection ratio of the snow. Snow reflectance polarization information has not only important theoretical significance, but also wide application prospect, and provides new ideas and methods for the quantitative research on snow using the remote sensing technology.

  7. Tunable infrared reflectance by phonon modulation

    Energy Technology Data Exchange (ETDEWEB)

    Ihlefeld, Jon F.; Sinclair, Michael B.; Beechem, III, Thomas E.

    2018-03-06

    The present invention pertains to the use of mobile coherent interfaces in a ferroelectric material to interact with optical phonons and, ultimately, to affect the material's optical properties. In altering the optical phonon properties, the optical properties of the ferroelectric material in the spectral range near-to the phonon mode frequency can dramatically change. This can result in a facile means to change to the optical response of the ferroelectric material in the infrared.

  8. Tunable infrared reflectance by phonon modulation

    Science.gov (United States)

    Ihlefeld, Jon F.; Sinclair, Michael B.; Beechem, III, Thomas E.

    2018-03-06

    The present invention pertains to the use of mobile coherent interfaces in a ferroelectric material to interact with optical phonons and, ultimately, to affect the material's optical properties. In altering the optical phonon properties, the optical properties of the ferroelectric material in the spectral range near-to the phonon mode frequency can dramatically change. This can result in a facile means to change to the optical response of the ferroelectric material in the infrared.

  9. Forensic applications of microscopical infrared internal reflection spectroscopy

    Science.gov (United States)

    Tungol, Mary W.; Bartick, Edward G.; Reffner, John A.

    1994-01-01

    Applications of microscopical infrared internal reflection spectroscopy in forensic science are discussed. Internal reflection spectra of single fibers, hairs, paint chips, vehicle rubber bumpers, photocopy toners, carbon copies, writing ink on paper, lipstick on tissue, black electrical tape, and other types of forensic evidence have been obtained. The technique is convenient, non-destructive, and may permit smeared materials to be analyzed in situ.

  10. NEAR-INFRARED IMAGING POLARIMETRY OF GGD 27: CIRCULAR POLARIZATION AND MAGNETIC FIELD STRUCTURES

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Jungmi; Tamura, Motohide [Department of Astronomy, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Hough, James H. [University of Hertfordshire, Hatfield, Herts AL10 9AB (United Kingdom); Nagata, Tetsuya [Kyoto University, Sakyo-ku, Kyoto 606-8502 (Japan); Kusakabe, Nobuhiko [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Saito, Hiro, E-mail: jungmi.kwon@astron.s.u-tokyo.ac.jp [Department of Astronomy and Earth Sciences, Tokyo Gakugei University, Koganei, Tokyo 184-8501 (Japan)

    2016-06-20

    Near-infrared imaging polarimetry in the J , H , and K{sub s} bands was carried out for GGD 27 in the dark cloud Lynds 291. Details of an infrared reflection nebula associated with the optical nebulosity GGD 27 and the infrared nebula GGD 27 IRS are presented. Aperture photometry of 1263 point-like sources, detected in all three bands, was used to classify them based on a color–color diagram, and the linear polarization of several hundred sources was determined, with the latter used to map the magnetic field structure around GGD 27. This field, around GGD 27 IRS, appears to be associated with the extended CO outflow of IRAS 18162–2048; however, there are partly distorted or bent components in the field. The Chandrasekhar–Fermi method gives an estimate of the magnetic field strength as ∼90 μ G. A region associated with GGD 27 IRS is discovered to have a circular polarization in the range of ∼2%–11% in the K{sub s} band. The circular polarization has an asymmetric positive/negative pattern and extends out to ∼ 120″ or 1.0 pc. The circular and linear polarization patterns are explained as resulting from a combination of dense inner and fainter outer lobes, suggesting episodic outflow.

  11. Polarization-controlled luminaires utilizing multiple Fresnel reflections

    Science.gov (United States)

    Falicoff, Waqidi; Minano, Juan C.; Caulfield, H. John; Alvarez, Roberto

    2003-11-01

    A novel luminaire utilizes repeated Fresnel reflections by angled surfaces to transform a small collimated input beam into a controlled output pattern with a high degree of polarization, either linear or radial. Applications to backlighting, front-lighting, optical communications and automotive lighting will be discussed.

  12. THE MAGNETIC FIELD IN TAURUS PROBED BY INFRARED POLARIZATION

    International Nuclear Information System (INIS)

    Chapman, Nicholas L.; Goldsmith, Paul F.; Pineda, Jorge L.; Li Di; Clemens, D. P.; Krco, Marko

    2011-01-01

    We present maps of the plane-of-sky magnetic field within two regions of the Taurus molecular cloud: one in the dense core L1495/B213 filament and the other in a diffuse region to the west. The field is measured from the polarization of background starlight seen through the cloud. In total, we measured 287 high-quality near-infrared polarization vectors in these regions. In L1495/B213, the percent polarization increases with column density up to A V ∼ 9 mag, the limits of our data. The radiative torques model for grain alignment can explain this behavior, but models that invoke turbulence are inconsistent with the data. We also combine our data with published optical and near-infrared polarization measurements in Taurus. Using this large sample, we estimate the strength of the plane-of-sky component of the magnetic field in nine subregions. This estimation is done with two different techniques that use the observed dispersion in polarization angles. Our values range from 5 to 82 μG and tend to be higher in denser regions. In all subregions, the critical index of the mass-to-magnetic flux ratio is sub-unity, implying that Taurus is magnetically supported on large scales (∼2 pc). Within the region observed, the B213 filament takes a sharp turn to the north and the direction of the magnetic field also takes a sharp turn, switching from being perpendicular to the filament to becoming parallel. This behavior can be understood if we are observing the rim of a bubble. We argue that it has resulted from a supernova remnant associated with a recently discovered nearby gamma-ray pulsar.

  13. Development of paints with infrared radiation reflective properties

    Directory of Open Access Journals (Sweden)

    Eliane Coser

    2015-06-01

    Full Text Available AbstractLarge buildings situated in hot regions of the Globe need to be agreeable to their residents. Air conditioning is extensively used to make these buildings comfortable, with consequent energy consumption. Absorption of solar visible and infrared radiations are responsible for heating objects on the surface of the Earth, including houses and buildings. To avoid excessive energy consumption, it is possible to use coatings formulated with special pigments that are able to reflect the radiation in the near- infrared, NIR, spectrum. To evaluate this phenomenon an experimental study about the reflectivity of paints containing infrared-reflective pigments has been made. By irradiating with an IR source and by measuring the surface temperatures of the samples we evaluated: color according to ASTM D 2244-14, UV/VIS/NIR reflectance according to ASTM E 903-12 and thermal performance. Additionally, the spectral reflectance and the IR emittance were measured and the solar reflectance of the samples were calculated. The results showed that plates coated with paints containing IR-reflecting pigments displayed lower air temperature on the opposite side as compared to conventional coatings, indicating that they can be effective to reflect NIR and decrease the temperature of buildings when used in roofs and walls.

  14. Infrared reflectance as a diagnostic adjunct for subclinical commotio retinae

    Directory of Open Access Journals (Sweden)

    Nicholas H Andrew

    2014-01-01

    Full Text Available Commotio retinae (CR is an outer retinal disorder following blunt trauma to the eye. Histologically it is characterized by disruption of the photoreceptor outer segments (OS, typically without injury to other retinal layers. Using spectral-domain optical coherence tomography (OCT the condition is visible as hyper-reflectivity of the OS. Most cases of CR are associated with transient grey-white discoloration of the retina and are easily diagnosed clinically, but there have been reports of OCT-confirmed CR without retinal discoloration. It is likely that this subclinical variant of CR is under-recognized as the OCT features of CR are subtle. Here, we report a case of OCT-confirmed subclinical CR that demonstrated prominent infrared hypo-reflectance, using the infrared protocol of the SPECTRALIS® OCT, Heidelberg Engineering. This case suggests that infrared reflectance may have a role in diagnosing cases of subclinical CR.

  15. Mid-Infrared Reflectance Imaging of Thermal-Barrier Coatings

    Science.gov (United States)

    Edlridge, Jeffrey I.; Martin, Richard E.

    2009-01-01

    An apparatus for mid-infrared reflectance imaging has been developed as means of inspecting for subsurface damage in thermal-barrier coatings (TBCs). The apparatus is designed, more specifically, for imaging the progression of buried delamination cracks in plasma-sprayed yttria-stabilized zirconia coatings on turbine-engine components. Progression of TBC delamination occurs by the formation of buried cracks that grow and then link together to produce eventual TBC spallation. The mid-infrared reflectance imaging system described here makes it possible to see delamination progression that is invisible to the unaided eye, and therefore give sufficiently advanced warning before delamination progression adversely affects engine performance and safety. The apparatus (see figure) includes a commercial mid-infrared camera that contains a liquid-nitrogen-cooled focal plane indium antimonide photodetector array, and imaging is restricted by a narrow bandpass centered at wavelength of 4 microns. This narrow wavelength range centered at 4 microns was chosen because (1) it enables avoidance of interfering absorptions by atmospheric OH and CO2 at 3 and 4.25 microns, respectively; and (2) the coating material exhibits maximum transparency in this wavelength range. Delamination contrast is produced in the midinfrared reflectance images because the introduction of cracks into the TBC creates an internal TBC/air-gap interface with a high diffuse reflectivity of 0.81, resulting in substantially higher reflectance of mid-infrared radiation in regions that contain buried delamination cracks. The camera is positioned a short distance (.12 cm) from the specimen. The mid-infrared illumination is generated by a 50-watt silicon carbide source positioned to the side of the mid-infrared camera, and the illumination is collimated and reflected onto the specimen by a 6.35-cm-diameter off-axis paraboloidal mirror. Because the collected images are of a steady-state reflected intensity (in

  16. Robust reflective ghost imaging against different partially polarized thermal light

    Science.gov (United States)

    Li, Hong-Guo; Wang, Yan; Zhang, Rui-Xue; Zhang, De-Jian; Liu, Hong-Chao; Li, Zong-Guo; Xiong, Jun

    2018-03-01

    We theoretically study the influence of degree of polarization (DOP) of thermal light on the contrast-to-noise ratio (CNR) of the reflective ghost imaging (RGI), which is a novel and indirect imaging modality. An expression for the CNR of RGI with partially polarized thermal light is carefully derived, which suggests a weak dependence of CNR on the DOP, especially when the ratio of the object size to the speckle size of thermal light has a large value. Different from conventional imaging approaches, our work reveals that RGI is much more robust against the DOP of the light source, which thereby has advantages in practical applications, such as remote sensing.

  17. Improved Spatial Resolution For Reflection Mode Infrared Spectromicroscopy

    International Nuclear Information System (INIS)

    Bechtel, Hans A.; Martin, Michael C.; May, T.E.; Lerch, Philippe

    2009-01-01

    Standard commercial infrared microscopes operating in reflection mode use a mirror to direct the reflected light from the sample to the detector. This mirror blocks about half of the incident light, however, and thus degrades the spatial resolution by reducing the numerical aperture of the objective. Here, we replace the mirror with a 50% beamsplitter to allow full illumination of the objective and retain a way to direct the reflected light to the detector. The improved spatial resolution is demonstrated using a microscope coupled to a synchrotron source.

  18. Improved Spatial Resolution For Reflection Mode Infrared Spectromicroscopy

    International Nuclear Information System (INIS)

    Bechtel, Hans A.; Martin, Michael C.; May, T. E.; Lerch, Philippe

    2010-01-01

    Standard commercial infrared microscopes operating in reflection mode use a mirror to direct the reflected light from the sample to the detector. This mirror blocks about half of the incident light, however, and thus degrades the spatial resolution by reducing the numerical aperture of the objective. Here, we replace the mirror with a 50% beamsplitter to allow full illumination of the objective and retain a way to direct the reflected light to the detector. The improved spatial resolution is demonstrated using a microscope coupled to a synchrotron source.

  19. Infrared reflectance spectra: effects of particle size, provenance and preparation

    Science.gov (United States)

    Su, Yin-Fong; Myers, Tanya L.; Brauer, Carolyn S.; Blake, Thomas A.; Forland, Brenda M.; Szecsody, J. E.; Johnson, Timothy J.

    2014-10-01

    We have recently developed methods for making more accurate infrared total and diffuse directional - hemispherical reflectance measurements using an integrating sphere. We have found that reflectance spectra of solids, especially powders, are influenced by a number of factors including the sample preparation method, the particle size and morphology, as well as the sample origin. On a quantitative basis we have investigated some of these parameters and the effects they have on reflectance spectra, particularly in the longwave infrared. In the IR the spectral features may be observed as either maxima or minima: In general, upward-going peaks in the reflectance spectrum result from strong surface scattering, i.e. rays that are reflected from the surface without bulk penetration, whereas downward-going peaks are due to either absorption or volume scattering, i.e. rays that have penetrated or refracted into the sample interior and are not reflected. The light signals reflected from solids usually encompass all such effects, but with strong dependencies on particle size and preparation. This paper measures the reflectance spectra in the 1.3 - 16 micron range for various bulk materials that have a combination of strong and weak absorption bands in order to observe the effects on the spectral features: Bulk materials were ground with a mortar and pestle and sieved to separate the samples into various size fractions between 5 and 500 microns. The median particle size is demonstrated to have large effects on the reflectance spectra. For certain minerals we also observe significant spectral change depending on the geologic origin of the sample. All three such effects (particle size, preparation and provenance) result in substantial change in the reflectance spectra for solid materials; successful identification algorithms will require sufficient flexibility to account for these parameters.

  20. The influence of particle size on infrared reflectance spectra

    Science.gov (United States)

    Myers, Tanya L.; Brauer, Carolyn S.; Su, Yin-Fong; Blake, Thomas A.; Johnson, Timothy J.; Richardson, Robert L.

    2014-06-01

    Reflectance spectra of solids are influenced by the absorption coefficient and index of refraction as well as particle size and morphology. In the infrared, spectral features may be observed as either maxima or minima: in general, the upwardgoing peaks in the reflectance spectrum result from surface scattering, which are rays that have reflected from the surface without penetration, whereas downward-going peaks result from either absorption or volume scattering, i.e. rays that have penetrated into the sample to be absorbed or refracted into the sample interior and are not reflected. The light signal reflected from solids usually encompasses all these effects which include dependencies on particle size, morphology and sample density. This paper measures the reflectance spectra in the 1.3 - 16 micron range for various bulk materials that have a combination of strong and weak absorption bands in order to understand the effects on the spectral features as a function of the mean grain size of the sample. The bulk materials were ground and sieved to separate the samples into various size fractions: 0-45, 45-90, 90-180, 180-250, 250-500, and >500 microns. The directional-hemispherical spectra were recorded using a Fourier transform infrared spectrometer equipped with an integrating sphere to measure the reflectance for all of the particle-size fractions. We have studied both organic and inorganic materials, but this paper focuses on inorganic salts, NaNO3, in particular. Our studies clearly show that particle size has an enormous influence on the measured reflectance spectra for bulk materials and that successful identification requires sufficient representative reflectance data so as to include the particle size(s) of interest. Origins of the effects are discussed.

  1. The Effect of Incident Light Polarization on Vegetation Bidirectional Reflectance Factor

    Science.gov (United States)

    Georgiev, Georgi T.; Thome, Kurt; Ranson, Kurtis J.; King, Michael D.; Butler, James J.

    2010-01-01

    The Laboratory-based Bidirectional Reflectance Factor (BRF) polarization study of vegetation is presented in this paper. The BRF was measured using a short-arc Xenon lamp/monochromator assembly producing an incoherent, tunable light source with a well-defined spectral bandpass at visible and near-infrared wavelengths of interest at 470 nm and 870 nm and coherent light source at 1.656 microns. All vegetation samples were measured using P and S linearly polarized incident light over a range of incident and scatter angles. By comparing these results, we quantitatively examine how the BRF of the samples depends on the polarization of the incident light. The differences are significant, depend strongly on the incident and scatter angles, and can be as high as 120% at 67 deg incident and 470nm. The global nature of Earth's processes requires consistent long-term calibration of all instruments involved in data retrieval. The BRF defines the reflection characteristics of Earth surface. It provides the reflectance of a target in a specific direction as a function of illumination and viewing geometry. The BRF is a function of wavelength and reflects the structural and optical properties of the surface. Various space and airborne radiometric and imaging remote sensing instruments are used in the remote sensing characterization of vegetation canopies and soils, oceans, or especially large pollution sources. The satellite data is validated through comparison with airborne, ground-based and laboratory-based data in an effort to fully understand the vegetation canopy reflectance, The Sun's light is assumed to be unpolarized at the top of the atmosphere; however it becomes polarized to some degree due to atmospheric effects by the time it reaches the vegetation canopy. Although there are numerous atmospheric correction models, laboratory data is needed for model verification and improvement.

  2. Temperature-dependent infrared reflectivity studies of multiferroic ...

    Indian Academy of Sciences (India)

    Abstract. We have measured near normal incidence far-infrared (FIR) reflectivity spec- tra of a single crystal of TbMnO3 from 10 K to 300 K in the spectral range of 50 cm−1–700 cm−1. Fifteen transverse optic (TO) and longitudinal optic (LO) modes are identified in the imaginary part of the dielectric function ε2(ω) and energy ...

  3. Efective infrared reflectivity and dielectric function of polycrystalline alumina ceramics

    Czech Academy of Sciences Publication Activity Database

    Nuzhnyy, Dmitry; Petzelt, Jan; Borodavka, Fedir; Vaněk, Přemysl; Šimek, Daniel; Trunec, D.; Maca, K.

    2017-01-01

    Roč. 254, č. 5 (2017), s. 1-8, č. článku 1600607. ISSN 0370-1972 R&D Projects: GA ČR GA15-08389S Institutional support: RVO:68378271 Keywords : alumina * ceramics * effective dielectric function * effective medium approximation * geometrical resonances * infrared reflectivity Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 1.674, year: 2016

  4. Thermal consequences of colour and near-infrared reflectance.

    Science.gov (United States)

    Stuart-Fox, Devi; Newton, Elizabeth; Clusella-Trullas, Susana

    2017-07-05

    The importance of colour for temperature regulation in animals remains controversial. Colour can affect an animal's temperature because all else being equal, dark surfaces absorb more solar energy than do light surfaces, and that energy is converted into heat. However, in reality, the relationship between colour and thermoregulation is complex and varied because it depends on environmental conditions and the physical properties, behaviour and physiology of the animal. Furthermore, the thermal effects of colour depend as much on absorptance of near-infrared ((NIR), 700-2500 nm) as visible (300-700 nm) wavelengths of direct sunlight; yet the NIR is very rarely considered or measured. The few available data on NIR reflectance in animals indicate that the visible reflectance is often a poor predictor of NIR reflectance. Adaptive variation in animal coloration (visible reflectance) reflects a compromise between multiple competing functions such as camouflage, signalling and thermoregulation. By contrast, adaptive variation in NIR reflectance should primarily reflect thermoregulatory requirements because animal visual systems are generally insensitive to NIR wavelengths. Here, we assess evidence and identify key research questions regarding the thermoregulatory function of animal coloration, and specifically consider evidence for adaptive variation in NIR reflectance.This article is part of the themed issue 'Animal coloration: production, perception, function and application'. © 2017 The Author(s).

  5. Polarized neutron reflectivity and scattering studies of magnetic heterostructures

    Science.gov (United States)

    Zabel, H.; Theis-Bröhl, K.

    2003-02-01

    The current interest in the magnetism of ultrathin films and multilayers is driven by their manifold applications in the magneto-and spin-electronic areas, for instance as magnetic field sensors or as information storage devices. In this regard, there is a large interest in exploring spin structures and spin disorder at the interface of magnetic heterostructures, to investigate magnetic domains in thin films and superlattices, and to understand remagnetization processes of various laterally shaped magnetic nanostructures. Traditionally neutron scattering has played a dominant role in the determination of spin structures, phase transitions and magnetic excitations in bulk materials. Today, its potential for the investigation of thin magnetic films has to be redefined. Polarized neutron reflectivity (PNR) at small wavevectors can provide precise information on the magnetic field distribution parallel to the film plane and on layer resolved magnetization vectors. In addition, PNR is not only sensitive to structural interface roughness but also to the magnetic roughness. Furthermore, magnetic hysteresis measurements from polarized small angle Bragg reflections allows us to filter out correlation effects during magnetization reversals of magnetic stripes and islands. An overview is provided on most recent PNR investigations of magnetic heterostructures.

  6. Polarized neutron reflectivity and scattering studies of magnetic heterostructures

    International Nuclear Information System (INIS)

    Zabel, H; Theis-Broehl, K

    2003-01-01

    The current interest in the magnetism of ultrathin films and multilayers is driven by their manifold applications in the magneto-and spin-electronic areas, for instance as magnetic field sensors or as information storage devices. In this regard, there is a large interest in exploring spin structures and spin disorder at the interface of magnetic heterostructures, to investigate magnetic domains in thin films and superlattices, and to understand remagnetization processes of various laterally shaped magnetic nanostructures. Traditionally neutron scattering has played a dominant role in the determination of spin structures, phase transitions and magnetic excitations in bulk materials. Today, its potential for the investigation of thin magnetic films has to be redefined. Polarized neutron reflectivity (PNR) at small wavevectors can provide precise information on the magnetic field distribution parallel to the film plane and on layer resolved magnetization vectors. In addition, PNR is not only sensitive to structural interface roughness but also to the magnetic roughness. Furthermore, magnetic hysteresis measurements from polarized small angle Bragg reflections allows us to filter out correlation effects during magnetization reversals of magnetic stripes and islands. An overview is provided on most recent PNR investigations of magnetic heterostructures

  7. The infrared imaging spectrograph (IRIS) for TMT: reflective ruled diffraction grating performance testing and discussion

    Science.gov (United States)

    Meyer, Elliot; Chen, Shaojie; Wright, Shelley A.; Moore, Anna M.; Larkin, James E.; Simard, Luc; Marie, Jerome; Mieda, Etsuko; Gordon, Jacob

    2014-07-01

    We present the efficiency of near-infrared reflective ruled diffraction gratings designed for the InfraRed Imaging Spectrograph (IRIS). IRIS is a first light, integral field spectrograph and imager for the Thirty Meter Telescope (TMT) and narrow field infrared adaptive optics system (NFIRAOS). IRIS will operate across the near-infrared encompassing the ZYJHK bands (~0.84 - 2.4μm) with multiple spectral resolutions. We present our experimental setup and analysis of the efficiency of selected reflective diffraction gratings. These measurements are used as a comparison sample against selected candidate Volume Phase Holographic (VPH) gratings (see Chen et al., this conference). We investigate the efficiencies of five ruled gratings designed for IRIS from two separate vendors. Three of the gratings accept a bandpass of 1.19-1.37μm (J band) with ideal spectral resolutions of R=4000 and R=8000, groove densities of 249 and 516 lines/mm, and blaze angles of 9.86° and 20.54° respectively. The other two gratings accept a bandpass of 1.51-1.82μm (H Band) with an ideal spectral resolution of R=4000, groove density of 141 lines/mm, and blaze angle of 9.86°. The fraction of flux in each diffraction mode was compared to both a pure reflection mirror as well as the sum of the flux measured in all observable modes. We measure the efficiencies off blaze angle for all gratings and the efficiencies between the polarization transverse magnetic (TM) and transverse electric (TE) states. The peak reflective efficiencies are 98.90 +/- 3.36% (TM) and 84.99 +/- 2.74% (TM) for the H-band R=4000 and J-band R=4000 respectively. The peak reflective efficiency for the J-band R=8000 grating is 78.78 +/- 2.54% (TE). We find that these ruled gratings do not exhibit a wide dependency on incident angle within +/-3°. Our best-manufactured gratings were found to exhibit a dependency on the polarization state of the incident beam with a ~10-20% deviation, consistent with the theoretical efficiency

  8. Near infrared imager for spectral and polarization analysis of planetary surfaces

    Science.gov (United States)

    Belyaev, D. A.; Yushkov, K. B.; Anikin, S. P.; Evdokimova, N. A.; Potanin, S. A.; Dobrolenskiy, Y. S.; Korablev, O. I.; Molchanov, V. Ya; Mantsevich, S. N.

    2017-09-01

    We propose a concept of an imaging near-IR spectrometer for sensing of planetary surfaces. This instrument is intended to analyze mineralogical and, in some cases, petrographic composition of the upper surface layer in the planetary regolith; to identify and monitor OH/H2O bearing minerals and water adsorption in this layer. The scheme of the spectrometer was designed on a basis of an acousto-optic tunable filter (AOTF) that allows imaging of samples in two orthogonal polarization planes simultaneously. Images are registered as a light (e.g. solar one) reflected and scattered from an observed target in the near infrared spectral range. The AOTF's electrical tuning provides fast and flexible spectral scanning of an image through whole the range analyzed - potentially, ten microseconds per a spectral point. Thus, it is possible to explore reflectance spectra of specified areas on a sample and to detect its minerals composition and microstructure variations. In parallel, one can estimate polarization contrast at different wavelengths thanks to the AOTF's birefringence properties. In this paper we report design and performance of a laboratory prototype for the near-IR spectro-polarimeteric imaging AOTF system operating in the spectral range from 0.8 to 1.75 μm. Reflectance spectra of some minerals were measured with the spectral resolution of 100 cm-1 (passband 10 nm at 1 μm). When imaging samples the spatial resolution as high as 0.5 mm was reached at the target distance of one meter. It corresponds to 100 by 100 resolving elements on the CCD matrix for each of two polarizations of the reflected light. Such a concept is also being designed for the spectral range from 1.7 to 3.5 μm.

  9. Infrared reflectance measurement for InN thin film characterization

    International Nuclear Information System (INIS)

    Fukui, K.; Kugumiya, Y.; Nakagawa, N.; Yamamoto, A.

    2006-01-01

    Infrared reflectance measurements of a series of InN thin films have been performed and attempt to derive carrier concentration and other physical constants for InN thin film characterization. Fitting calculations are performed by use of the dielectric function equation based on phonon-plasmon coupling model. Longitudinal and transverse optical phonon frequencies, plasma frequency and their damping parameters can be derived from fitting. From those results, electrical and phonon properties of InN and characterization of films are discussed. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  10. Asymmetric bistable reflection and polarization switching in a magnetic nonlinear multilayer structure

    DEFF Research Database (Denmark)

    Tuz, Vladimir R.; Novitsky, Denis V.; Prosvirnin, Sergey L.

    2014-01-01

    , while light reflected from the other side has its polarization unchanged. Using the nonlinear transfer matrix calculations in the frequency domain, it is demonstrated that defect resonances in the nonlinear reflection spectra undergo bending, resulting in polarization bistability of reflected light....... This bistability is shown to result in abrupt switching between linear polarization of the output reflected light when the input intensity is varied. This switching is confirmed in finite-difference time-domain simulations, and its hysteresis character is established....

  11. Final Technical Report - Polymeric Multilayer Infrared Reflecting Mirrors

    Energy Technology Data Exchange (ETDEWEB)

    Reed, John [3M Company, St. Paul, MN (United States)

    2016-09-16

    The goal of this project was to develop a clear, polymeric, multilayer film with an expanded infrared (IR) reflection band which would allow improved rejection of incident IR energy. The IR reflection band is covering the region from about 850 nm to 1830 nm. This film is essentially clear and colorless in the visible portion of the electromagnetic spectra (visible light transmission of about 89%) while reflecting 90-95% of the IR energy over the portion of the spectra indicated above. This film has a nominal thickness of 3 mils, is polymeric in nature (contains no metals, metal oxides, or other material types) and is essentially clear in appearance This film can then be used as a component of other products such as a solar window film, an IR reflecting interlayer for laminated glass, a heat rejecting skylight film, a base film for daylight redirecting products, a greenhouse film, and many more applications. One of the main strengths of this product is that because it is a standalone IR rejecting film, it can be incorporated and retrofitted into many applications that desire or require the transmission of visible light, but want to block other portions of the solar spectra, especially the IR portion. Many of the applications exist in the window glazing product area where this film can provide for substantial energy improvements in applications where visible light is desired.

  12. Quantitative infrared spectroscopy of lipids in solution: II. Novel polar solvent systems.

    Science.gov (United States)

    Schmid, P; Steiner, R N

    1975-01-01

    In the second part of this series, previous solvent limitations in infrared studies are discussed and novel polar solvent systems for the analysis of nonpolar and polar lipids described. Limitation of potassium bromide windows for infrared cells are discussed. The use of calcium fluoride cells with crude lipids is discussed. Problems related to hydrogen bonding of lipid solutes in various solvent systems are discussed as well as hydrogen-deuterium exchange in biologically important lipids.

  13. Vitrified chiral-nematic liquid crystalline films for selective reflection and circular polarization

    Energy Technology Data Exchange (ETDEWEB)

    Katsis, D.; Chen, P.H.M.; Mastrangelo, J.C.; Chen, S.H. [Univ. of Rochester, NY (United States); Blanton, T.N. [Eastman Kodak Co., Rochester, NY (United States)

    1999-06-01

    Nematic and left-handed chiral-nematic liquid crystals comprising methoxybiphenylbenzoate and (S)-(-)-1-phenylethylamine pendants to a cyclohexane core were synthesized and characterized. Although pristine samples were found to be polycrystalline, thermal quenching following heating to and annealing at elevated temperatures permitted the molecular orders characteristic of liquid crystalline mesomorphism to be frozen in the glassy state. Left at room temperature for 6 months, the vitrified liquid crystalline films showed no evidence of recrystallization. An orientational order parameter of 0.65 was determined with linear dichroism of a vitrified nematic film doped with Exalite 428 at a mole fraction of 0.0025. Birefringence dispersion of a blank vitrified nematic film was determined using a phase-difference method complemented by Abbe refractometry. A series of vitrified chiral-nematic films were prepared to demonstrate selective reflection and circular polarization with a spectral region tunable from blue to the infrared region by varying the chemical composition. The experimentally measured circular polarization spectra were found to agree with the Good-Karali theory in which all four system parameters were determined a priori: optical birefringence, average refractive index, selective reflection wavelength, and film thickness.

  14. Electrically controlled infrared optical transmission and reflection through metallic grating using NEMS technology

    Science.gov (United States)

    Yamaguchi, Kenzo; Fujii, Masamitsu

    2015-12-01

    The enhanced optical properties of metallic subwavelength gratings with very narrow slits have recently been extensively studied in the field of plasmonics. The optical transmission and reflection of such nanostructures, which act as nano-electro-mechanical systems (NEMS) actuators, can be electrically controlled by varying their geometrical parameters, giving them great flexibility for numerous applications in photonics, opto-electronics, and sensing. The previous challenges in controlling the optical properties were overcome by forming a metallic subwavelength grating with an NEMS actuator in mid-air, allowing the grating to be physically moved with the bias voltage. The device can shift the plasmon resonance wavelength with an electrical signal. The resonance wavelength for Wood's anomaly at the infrared region is predicted through simulations to shift by approximately 150 nm. We discuss the effect of polarization on the optical properties and grating mechanism. The reported effect may be used to achieve active spectral tuning and switching in a wide range of applications.

  15. NPP Visible Infrared Imager-Radiometer Suite (VIIRS) Remote-Sensing Reflectance (RRS) Global Mapped Data

    Data.gov (United States)

    National Aeronautics and Space Administration — The Visible and Infrared Imager/Radiometer Suite (VIIRS) is a multi-disciplinary instrument that is being flown on the Joint Polar Satellite System (JPSS) series of...

  16. In situ study by polarization modulated Fourier transform infrared spectroscopy of the structure and orientation of lipids and amphipathic peptides at the air-water interface

    OpenAIRE

    Cornut, I.; Desbat, B.; Turlet, J.M.; Dufourcq, J.

    1996-01-01

    Free amphipathic peptides and peptides bound to dimyristoylphosphatidylcholine (DMPC) were studied directly at the air/water interface using polarization modulation infrared reflection absorption spectroscopy (PMIRRAS). Such differential reflectivity measurements proved to be a sensitive and efficient technique to investigate in situ the respective conformations and orientations of lipid and peptide molecules in pure and mixed films. Data obtained for melittin, a natural hemolytic peptide, ar...

  17. Fusion of infrared polarization and intensity images based on improved toggle operator

    Science.gov (United States)

    Zhu, Pan; Ding, Lei; Ma, Xiaoqing; Huang, Zhanhua

    2018-01-01

    Integration of infrared polarization and intensity images has been a new topic in infrared image understanding and interpretation. The abundant infrared details and target from infrared image and the salient edge and shape information from polarization image should be preserved or even enhanced in the fused result. In this paper, a new fusion method is proposed for infrared polarization and intensity images based on the improved multi-scale toggle operator with spatial scale, which can effectively extract the feature information of source images and heavily reduce redundancy among different scale. Firstly, the multi-scale image features of infrared polarization and intensity images are respectively extracted at different scale levels by the improved multi-scale toggle operator. Secondly, the redundancy of the features among different scales is reduced by using spatial scale. Thirdly, the final image features are combined by simply adding all scales of feature images together, and a base image is calculated by performing mean value weighted method on smoothed source images. Finally, the fusion image is obtained by importing the combined image features into the base image with a suitable strategy. Both objective assessment and subjective vision of the experimental results indicate that the proposed method obtains better performance in preserving the details and edge information as well as improving the image contrast.

  18. DUST AND INFRARED IMAGING OF POLAR RING GALAXIES

    NARCIS (Netherlands)

    ARNABOLDI, M; FREEMAN, KC; SACKETT, PD; SPARKE, LS; CAPACCIOLI, M

    1995-01-01

    We have derived surface photometry for a sample of five polar ring(PR) galaxies in the optical (B and R bands) and in the near-IR (K band). Our preliminary results show that the morphology of these objects is heavily perturbed by dust, which sometimes completely hides the real distribution of the

  19. AUTHENTICATION OF WILD AND REARED SEA BASS BY INFRARED SPECTROSCOPY NIRs (NEAR INFRARED REFLECTANCE SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    E. Novelli

    2009-09-01

    Full Text Available The aim of this study was to evaluate NIRs (Near Infrared Reflectance Spectroscopy performances in the prediction of Farmed vs.Wild production method in European sea bass. Samples collected (n=39 were submitted to analysis in order to assess chemical composition and fatty acids profile of fillets. Aliquots of wet and ground freeze-dried minced samples were scanned in duplicates (1100 to 2498 nm; 2 nm intervals in reflectance mode using a monochromator NIRsystem 5000. NIRs technique showed a satisfactory accurateness in predicting Protein, Lipids and Fatty acids profile in raw samples. Sample lyophilisation increased some predicting values (r2: coefficient of determination on cross-validation range from 0,671 to 0,992; SECV: standard error of cross-validation range from 0,864 to 2,981. Results showed that NIRs technique was able to discriminate between Wild (94,7% samples recognized and Farmed (100% samples recognized using wet muscles, and 100% for both classes on ground freeze-dried fillet.

  20. Polarization and Strong Infra-Red Activity in Compressed Solid Hydrogen

    OpenAIRE

    Souza, Ivo; Martin, Richard M.

    1998-01-01

    Under a pressure of ~150 GPa solid molecular hydrogen undergoes a phase transition accompanied by a dramatic rise in infra-red absorption in the vibron frequency range. We use the Berry's phase approach to calculate the electric polarization in several candidate structures finding large, anisotropic dynamic charges and strongly IR-active vibron modes. The polarization is shown to be greatly affected by the overlap between the molecules in the crystal, so that the commonly used Clausius-Mossot...

  1. Infrared reflective coatings for building and automobile glass windows for heat protection

    Science.gov (United States)

    Butt, M. A.; Fomchenkov, S. A.; Kazanskiy, N. L.; Ullah, A.; Ali, R. Z.; Habib, M.

    2017-04-01

    Sunlight can be used a source of light in buildings and automobiles, however infrared wavelengths in sunlight result in heating. In this work, Infrared Reflective Coatings are designed using thin films to transmit visible wavelengths 400 700 nm while reflecting infrared wavelengths above 700 nm. Three different design approaches have been used, namely single layer of metal, sandwich structure and multilayer design. Four metals (Ag, Au, Al and Cu) and two dielectrics (TiO2 and SiO2) are used in this study. Designs with Ag show maximum reflection of Infrared wavelengths in all designs. Sandwich structures of TiO2-Ag-TiO2 on substrate with 22 nm of thickness for each layer show the maximum transmission of 87% in the visible region and maximum reflection of Infrared wavelengths.

  2. [The application of near-infrared reflectance spectroscopy in seeds quality certification].

    Science.gov (United States)

    Ren, Wei-Bo; Han, Jian-Guo; Zhang, Yun-Wei; Guo, Hui-Qin

    2008-03-01

    Near infrared reflectance spectroscopy is a newly developed method capable of analyzing the content of specific compound in the detected sample quickly and efficiently. Near infrared reflectance spectroscopy has been wildly used in many fields such as agriculture science, food industry, medical industry, chemical engineering and protection of environment and so on. In the present paper firstly the principle, technique method and merits of near infrared reflectance spectroscopy were described. Then the application of near infrared reflectance spectroscopy to the seeds of many crops, i.e. wheat, rice, rape and apple, was reviewed and discussed in brief. Based on this introduction, the potential value of the application of near infrared reflectance spectroscopy to the grass seeds quality certification was discussed in the four areas, i.e. the grass seed variety discrimination, the standard percentage rate of grass seed germination testing, the scale of the content of grass seed moisture, and the evaluation of the grass seed vigor and the purity of grass seed. Finally, it was concluded that the application of near infrared reflectance spectroscopy to the grass seed quality certification is significant both in the academic and the technical areas because near infrared reflectance spectroscopy will not only improve the efficiency of grass seed certification, saving manual work and testing time, but also help expand the extent and application of routine quality certification of grass seeds.

  3. Determination of plant silicon content with near infrared reflectance spectroscopy

    Directory of Open Access Journals (Sweden)

    Adriaan eSmis

    2014-09-01

    Full Text Available Silicon (Si is one of the most common elements in the earth bedrock, and its continental cycle is strongly biologically controlled. Yet, research on the biogeochemical cycle of Si in ecosystems is hampered by the time and cost associated with the currently used chemical analysis methods. Here, we assessed the suitability of Near Infrared Reflectance Spectroscopy (NIRS for measuring Si content in plant tissues. NIR spectra depend on the characteristics of the present bonds between H and N, C and O, which can be calibrated against concentrations of various compounds. Because Si in plants always occurs as hydrated condensates of orthosilicic acid (Si(OH4, linked to organic biomolecules, we hypothesized that NIRS is suitable for measuring Si content in plants across a range of plant species.We based our testing on 442 samples of 29 plant species belonging to a range of growth forms. We calibrated the NIRS method against a well-established plant Si analysis method by using partial least-squares regression. Si concentrations ranged from detection limit (0.24 ppmSi to 7.8% Si on dry weight and were well predicted by NIRS. The model fit with validation data was good across all plant species (n=141, R2=0.90, RMSEP=0.24, but improved when only graminoids were modeled (n=66, R2=0.95, RMSEP=0.10. A species specific model for the grass Deschampsia cespitosa showed even slightly better results than the model for all graminoids (n=16, R2=0.93, RMSEP=0.015.We show for the first time that NIRS is applicable for determining plant Si concentration across a range of plant species and growth forms, and represents a time- and cost-effective alternative to the chemical Si analysis methods. As NIRS can be applied concurrently to a range of plant organic constituents, it opens up unprecedented research possibilities for studying interrelations between Si and other plant compounds in vegetation, and for addressing the role of Si in ecosystems across a range of Si

  4. Comparison of PARASOL Observations with Polarized Reflectances Simulated Using Different Ice Habit Mixtures

    Science.gov (United States)

    Cole, Benjamin H.; Yang, Ping; Baum, Bryan A.; Riedi, Jerome; Labonnote, Laurent C.; Thieuleux, Francois; Platnick, Steven

    2012-01-01

    Insufficient knowledge of the habit distribution and the degree of surface roughness of ice crystals within ice clouds is a source of uncertainty in the forward light scattering and radiative transfer simulations required in downstream applications involving these clouds. The widely used MODerate Resolution Imaging Spectroradiometer (MODIS) Collection 5 ice microphysical model assumes a mixture of various ice crystal shapes with smooth-facets except aggregates of columns for which a moderately rough condition is assumed. When compared with PARASOL (Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar) polarized reflection data, simulations of polarized reflectance using smooth particles show a poor fit to the measurements, whereas very rough-faceted particles provide an improved fit to the polarized reflectance. In this study a new microphysical model based on a mixture of 9 different ice crystal habits with severely roughened facets is developed. Simulated polarized reflectance using the new ice habit distribution is calculated using a vector adding-doubling radiative transfer model, and the simulations closely agree with the polarized reflectance observed by PARASOL. The new general habit mixture is also tested using a spherical albedo differences analysis, and surface roughening is found to improve the consistency of multi-angular observations. It is suggested that an ice model incorporating an ensemble of different habits with severely roughened surfaces would potentially be an adequate choice for global ice cloud retrievals.

  5. Mid-infrared imaging system based on polarizers for detecting marine targets covered in sun glint.

    Science.gov (United States)

    Zhao, Huijie; Ji, Zheng; Zhang, Ying; Sun, Xiaofeng; Song, Pengfei; Li, Yansong

    2016-07-25

    When a marine target is detected by a mid-infrared detector on a sunny day, the target's information could be lost if it is located in sun glint. Therefore, we developed a new mid-infrared imaging system capable of effectively detecting marine targets in regions of strong sun glint, which is presented in this report. Firstly, the theory of the analysis methods employed in different detection scenarios is briefly described to establish whether one or two polarizers should be utilized to suppress further the p-polarized component of sun glint. Secondly, for the case in which a second polarizer is employed, the formula for the optimum angle between the two polarizers is given. Then, the results of our field experiment are presented, demonstrating that the developed system can significantly reduce sun glint and can enhance the contrast of target images. A commonly used image processing algorithm proved capable of identifying a target in sun glint, confirming the effectiveness of our proposed mid-infrared polarization imaging system.

  6. Polarization-independent gain in mid-infrared interband cascade lasers

    Directory of Open Access Journals (Sweden)

    K. Ryczko

    2016-11-01

    Full Text Available We have calculated the gain function of a type-II W-design AlSb/InAs/GaAsSb/InAs/AlSb quantum wells to be used in an active region of interband cascade lasers, for two linear polarizations of in-plane propagating light: transverse-electric and transverse-magnetic. The effect of external electric field, imitating the conditions in a working device, has also been taken into account. We have proposed an active region design suitable for practical realization of mid-infrared lasing devices with controllable polarization properties. We have also demonstrated a way to achieve polarization-independent gain in mid-infrared emitters, which has not been reported so far.

  7. Variation in the circularly polarized light reflection of Lomaptera (Scarabaeidae) beetles.

    Science.gov (United States)

    Carter, I E; Weir, K; McCall, M W; Parker, A R

    2016-07-01

    An extended spectroscopic study on the left-through-left circularly polarized reflection spectra of a large number of beetles from the Australasian Scrabaeidae:Cetoniinae of the Lomaptera genus was undertaken. We have obtained a five-category spectral classification. The principal spectral features, which even within the genus range from blue to infrared, are related to structural chirality in the beetle shells. The detailed features of each spectral classification are related to different structural perturbations of the helix, including various pitch values and abrupt twist defects. These spectral characteristics and associated shell structures are confirmed on the basis of simple modelling. An important conclusion from our study is that the simple helical structure resulting in a single symmetric Bragg peak is not the dominant spectral type. Rather the reality is a rich tapestry of spectral types. One intriguing specimen is identified via a scanning electron micrograph to consist of a double interstitial helix leading to a particular double-peak spectrum. © 2016 The Authors.

  8. Highly doped semiconductor plasmonic nanoantenna arrays for polarization selective broadband surface-enhanced infrared absorption spectroscopy of vanillin

    Science.gov (United States)

    Barho, Franziska B.; Gonzalez-Posada, Fernando; Milla, Maria-Jose; Bomers, Mario; Cerutti, Laurent; Tournié, Eric; Taliercio, Thierry

    2017-11-01

    Tailored plasmonic nanoantennas are needed for diverse applications, among those sensing. Surface-enhanced infrared absorption (SEIRA) spectroscopy using adapted nanoantenna substrates is an efficient technique for the selective detection of molecules by their vibrational spectra, even in small quantity. Highly doped semiconductors have been proposed as innovative materials for plasmonics, especially for more flexibility concerning the targeted spectral range. Here, we report on rectangular-shaped, highly Si-doped InAsSb nanoantennas sustaining polarization switchable longitudinal and transverse plasmonic resonances in the mid-infrared. For small array periodicities, the highest reflectance intensity is obtained. Large periodicities can be used to combine localized surface plasmon resonances (SPR) with array resonances, as shown in electromagnetic calculations. The nanoantenna arrays can be efficiently used for broadband SEIRA spectroscopy, exploiting the spectral overlap between the large longitudinal or transverse plasmonic resonances and narrow infrared active absorption features of an analyte molecule. We demonstrate an increase of the vibrational line intensity up to a factor of 5.7 of infrared-active absorption features of vanillin in the fingerprint spectral region, yielding enhancement factors of three to four orders of magnitude. Moreover, an optimized readout for SPR sensing is proposed based on slightly overlapping longitudinal and transverse localized SPR.

  9. Highly doped semiconductor plasmonic nanoantenna arrays for polarization selective broadband surface-enhanced infrared absorption spectroscopy of vanillin

    Directory of Open Access Journals (Sweden)

    Barho Franziska B.

    2017-11-01

    Full Text Available Tailored plasmonic nanoantennas are needed for diverse applications, among those sensing. Surface-enhanced infrared absorption (SEIRA spectroscopy using adapted nanoantenna substrates is an efficient technique for the selective detection of molecules by their vibrational spectra, even in small quantity. Highly doped semiconductors have been proposed as innovative materials for plasmonics, especially for more flexibility concerning the targeted spectral range. Here, we report on rectangular-shaped, highly Si-doped InAsSb nanoantennas sustaining polarization switchable longitudinal and transverse plasmonic resonances in the mid-infrared. For small array periodicities, the highest reflectance intensity is obtained. Large periodicities can be used to combine localized surface plasmon resonances (SPR with array resonances, as shown in electromagnetic calculations. The nanoantenna arrays can be efficiently used for broadband SEIRA spectroscopy, exploiting the spectral overlap between the large longitudinal or transverse plasmonic resonances and narrow infrared active absorption features of an analyte molecule. We demonstrate an increase of the vibrational line intensity up to a factor of 5.7 of infrared-active absorption features of vanillin in the fingerprint spectral region, yielding enhancement factors of three to four orders of magnitude. Moreover, an optimized readout for SPR sensing is proposed based on slightly overlapping longitudinal and transverse localized SPR.

  10. Infrared polar brightenings on Jupiter. V - A thermal equilibrium model for the north polar hot spot

    Science.gov (United States)

    Halthore, Rangasayi; Burrows, Adam; Caldwell, John

    1988-01-01

    Voyager IRIS instrument records of the IR hydrocarbon emissions from Jupiter's north polar region are presently studied to determine the spatial and other characteristics of the north polar hot spot. Attention is given to a thermal equilibrium model that exploits the asymmetry found in 7.8-micron emission of stratospheric methane with respect to system III longitude in order to estimate stratospheric zonal wind velocity. This model accurately predicts the observed asymmetry in acetylene's 13.6-micron emission; this requires, however, enhanced acetylene abundance in the hot spot, as well as ethane depletion. Energetic charged particles are suggested to be the most probable cause of these effects.

  11. Testing models of low-excitation photodissociation regions with far-infrared observations of reflection nebulae

    NARCIS (Netherlands)

    Owl, RCY; Meixner, MM; Fong, D; Haas, MR; Rudolph, AL; Tielens, AGGM

    2002-01-01

    This paper presents Kuiper Airborne Observatory observations of the photodissociation regions ( PDRs) in nine reflection nebulae. These observations include the far-infrared atomic fine-structure lines of [O I] 63 and 145 mum, [C II] 158 mum, and [Si II] 35 mum and the adjacent far-infrared

  12. Carbon dioxide adsorption on a ZnO(101[combining macron]0) substrate studied by infrared reflection absorption spectroscopy.

    Science.gov (United States)

    Buchholz, Maria; Weidler, Peter G; Bebensee, Fabian; Nefedov, Alexei; Wöll, Christof

    2014-01-28

    The adsorption of carbon dioxide on the mixed-terminated ZnO(101[combining macron]0) surface of a bulk single crystal was studied by UHV Infrared Reflection Absorption Spectroscopy (IRRAS). In contrast to metals, the classic surface selection rule for IRRAS does not apply to bulk oxide crystals, and hence vibrational bands can also be observed for s-polarized light. Although this fact substantially complicates data interpretation, a careful analysis allows for a direct determination of the adsorbate geometry. Here, we demonstrate the huge potential of IR-spectroscopy for investigations on oxide single crystal surfaces by considering all three components of the incident polarized light separately. We find that the tridentate (surface) carbonate is aligned along the [0001] direction. A comparison to data reported previously for CO2 adsorbed on the surfaces of ZnO nanoparticles provides important insight into the role of defects in the surface chemistry of powder particles.

  13. Polarization contrast in fluorescence scanning near-field optical microscopy in reflection

    NARCIS (Netherlands)

    Jalocha, A.; Jalocha, A.; van Hulst, N.F.

    1995-01-01

    Polarization contrast is presented in fluorescence images of a Langmuir-Blodgett monolayer obtained with a scanning near-field optical microscope operated in reflection. A tapered optical fiber is used both to excite and to collect the fluorescence. The lateral resolution in the reflection

  14. Polarization and infrared imaging of regions of star formation

    International Nuclear Information System (INIS)

    Moneti, A.

    1985-01-01

    Observational studies of two regions of star formation, the Taurus cloud and the BN-KL region of Orion, are presented. The magnetic field structure in the Taurus cloud was studied in order to investigate its possible role in the evolution of the cloud. It was found that the magnetic field is generally perpendicular to the elongated structures that make up the cloud, and it is deduced that the observed structure could be due to the effects of the magnetic field during the early stages of collapse. In addition, it was found that the magnetic field may have prevented the formation of massive stars by inhibiting the collapse of large cores, while not affecting the collapse of the small ones. Using a new near-infrared array camera, high resolution (1'') images of several young stars embedded in the cloud were obtained. Most of these sources have extended, spatially resolved circumstellar shells. High resolution images of the BN-KL region of Orion at four wavelengths between 1.65 and 4.7 μm were also obtained. At 1.65 μm a large trough is seen in the overall nebulosity; it is suggested that the observed trough is due to the doughnut of material around IRc2 as it obscures the background nebulosity

  15. Angular Scattering Reflectance and Polarization Measurements of Candidate Regolith Materials Measured in the Laboratory

    Science.gov (United States)

    Nelson, Robert M.; Boryta, Mark D.; Hapke, Bruce W.; Shkuratov, Yuriy; Vandervoort, Kurt; Vides, Christina L.

    2016-10-01

    The reflectance and polarization of light reflected from a solar system object indicates the chemical and textural state of the regolith. Remote sensing data are compared to laboratory angular scattering measurements and surface properties are determined.We use a Goniometric Photopolarimeter (GPP) to make angular reflectance and polarization measurements of particulate materials that simulate planetary regoliths. The GPP employs the Helmholtz Reciprocity Principle ( 2, 1) - the incident light is linearly polarized - the intensity of the reflected component is measured. The light encounters fewer optical surfaces improving signal to noise. The lab data are physically equivalent to the astronomical data.Our reflectance and polarization phase curves of highly reflective, fine grained, media simulate the regolith of Jupiter's satellite Europa. Our lab data exhibit polarization phase curves that are very similar to reports by experienced astronomers (4). Our previous reflectance phase curve data of the same materials agree with the same astronomical observers (5). We find these materials exhibit an increase in circular polarization ratio with decreasing phase angle (3). This suggests coherent backscattering (CB) of photons in the regolith (3). Shkuratov et al.(3) report that the polarization properties of these particulate media are also consistent with the CB enhancement process (5). Our results replicate the astronomical data indicating Europa's regolith is fine-grained, high porous with void space exceeding 90%.1. Hapke, B. W. (2012). ISBN 978-0-521-88349-82. Minnaert, M. (1941).Asrophys. J., 93, 403-410.3. Nelson, R. M. et al. (1998). Icarus, 131, 223-230.4. Rosenbush, V. et al. (2015). ISBN 978-1-107-04390-9, pp 340-359.5. Shkuratov, Yu. et al. (2002) Icarus 159, 396-416.

  16. Terahertz reflection spectroscopy of Debye relaxation in polar liquids

    DEFF Research Database (Denmark)

    Møller, Uffe; Cooke, David; Tanaka, Koichiro

    2009-01-01

    Terahertz (THz) radiation interacts strongly with the intermolecular hydrogen-bond network in aqueous liquids. The dielectric properties of liquid water and aqueous solutions in the THz spectral region are closely linked to the microscopic dynamics of the liquid solution, and hence THz spectroscopy...... for remote detection of some of the properties of bottled liquids. Here we present a review of THz spectroscopy and modeling of water-ethanol mixtures, and establish a link between the dielectric function of water-ethanol mixtures and some of their thermodynamic properties. We then review how the knowledge...... offers an important insight into fundamental intermolecular interactions in polar liquids. At the same time, the strong and characteristic interaction between THz radiation and liquids offers a methodology for the classification of liquids inside containers, and hence the THz region is suitable...

  17. Direct visualization of polarization reversal of organic ferroelectric memory transistor by using charge modulated reflectance imaging

    Science.gov (United States)

    Otsuka, Takako; Taguchi, Dai; Manaka, Takaaki; Iwamoto, Mitsumasa

    2017-11-01

    By using the charge modulated reflectance (CMR) imaging technique, charge distribution in the pentacene organic field-effect transistor (OFET) with a ferroelectric gate insulator [P(VDF-TrFE)] was investigated in terms of polarization reversal of the P(VDF-TrFE) layer. We studied the polarization reversal process and the carrier spreading process in the OFET channel. The I-V measurement showed a hysteresis behavior caused by the spontaneous polarization of P(VDF-TrFE), but the hysteresis I-V curve changes depending on the applied drain bias, possibly due to the gradual shift of the polarization reversal position in the OFET channel. CMR imaging visualized the gradual shift of the polarization reversal position and showed that the electrostatic field formed by the polarization of P(VDF-TrFE) contributes to hole and electron injection into the pentacene layer and the carrier distribution is significantly dependent on the direction of the polarization. The polarization reversal position in the channel region is governed by the electrostatic potential, and it happens where the potential reaches the coercive voltage of P(VDF-TrFE). The transmission line model developed on the basis of the Maxwell-Wagner effect element analysis well accounts for this polarization reversal process in the OFET channel.

  18. Depth enhancement of multi-layer light field display using polarization dependent internal reflection.

    Science.gov (United States)

    Jo, Na-Young; Lim, Hong-Gi; Lee, Sung-Keun; Kim, Yong-Soo; Park, Jae-Hyeung

    2013-12-02

    A technique to enhance the depth range of the multi-layer light field three-dimensional display is proposed. A set of the optical plates are stacked in front of the conventional multi-layer light field display, creating additional internal reflection for one polarization state. By switching between two orthogonal polarization states in synchronization with the displayed three-dimensional images, the depth range of the display can be doubled. The proposed method is verified experimentally, confirming its feasibility.

  19. A C/X Dual-band Wide-angle Reflective Polarization Rotation Metasurface

    Directory of Open Access Journals (Sweden)

    Y. Zhou

    2017-09-01

    Full Text Available In this paper, a C/X dual-band wide-angle re¬flective polarization rotation metasurface (PRMS with high rotation efficiency is proposed and realized. Aiming to miniaturize the size of the unit cell, a metallic flower-like shape ring is selected to extend the current path and the 45 degree slanting stitch along diagonal direction is used to form the asymmetric structure. The simulated results show that the proposed PRMS achieves polarization rotation at 4.61 GHz and 8.67 GHz with high efficiency, at which the linear polarization incident wave is converted into its orthogonal polarization after reflection. Furthermore, the high polarization rotation efficiency of the proposed PRMS is maintained under an oblique incident direction from 0° to 60°. To verify the simulated results, the proposed PRMS is fabricated and measured. The measured results are in good accordance with the simulated ones.

  20. Infrared reflection properties and modelling of in situ reflection measurements on plasma-facing materials in Tore Supra

    International Nuclear Information System (INIS)

    Reichle, R; Desgranges, C; Faisse, F; Pocheau, C; Lasserre, J-P; Oelhoffen, F; Eupherte, L; Todeschini, M

    2009-01-01

    Tore Supra has-like ITER-reflecting internal surfaces, which can perturb the machine protection systems based on infrared (IR) thermography. To ameliorate this situation, we have measured and modelled in the 3-5 μm wavelength range the bi-directional reflection distribution function (BRDF) of wall material samples from Tore Supra and conducted in situ reflection measurements and simulated them with the CEA COSMOS code. BRDF results are presented for B 4 C and carbon fibre composite (CFC) tiles. The hemispherical integrated reflection ranges from 0.12 for the B 4 C sample to 0.39 for a CFC tile from the limiter erosion zone. In situ measurements of the IR reflection of a blackbody source off an ICRH and an LHCD antenna of Tore Supra are well reproduced by the simulation.

  1. Prediction of tablets disintegration times using near-infrared diffuse reflectance spectroscopy as a nondestructive method.

    Science.gov (United States)

    Donoso, M; Ghaly, Evone S

    2005-01-01

    The goals of this study are to user near-infrared reflectance (NIR) spectroscopy to measure the disintegration time of a series of tablets compacted at different compressional forces, calibrate NIR data vs. laboratory equipment data, develop a model equation, validate the model, and test the model's predictive ability. Seven theophylline tablet formulations of the same composition but with different disintegration time values (0.224, 1.141, 2.797, 5.492, 9.397, 16.8, and 30.092 min) were prepared along with five placebo tablet formulations with different disintegration times. Laboratory disintegration time was compared to near-infrared diffuse reflectance data. Linear regression, quadratic, cubic, and partial least square techniques were used to determine the relationship between disintegration time and near-infrared spectra. The results demonstrated that an increase in disintegration time produced an increase in near-infrared absorbance. Series of model equations, which depended on the mathematical technique used for regression, were developed from the calibration of disintegration time using laboratory equipment vs. the near-infrared diffuse reflectance for each formulation. The results of NIR disintegration time were similar to laboratory tests. The near-infrared diffuse reflectance spectroscopy method is an alternative nondestructive method for measurement of disintegration time of tablets.

  2. Infrared wire-grid polarizer with sol-gel antireflection films on both sides

    Science.gov (United States)

    Yamada, Itsunari; Ishihara, Yoshiro

    2017-12-01

    We fabricated an infrared wire-grid polarizer with the high transverse magnetic (TM) polarization transmittance and high extinction ratio by soft imprint lithography, sol-gel method, and Al shadow coating processes. A zilconia film was coated on Si substrate by using sol-gel method and spin coating method. Then, sol-gel zirconia grating was formed on the back side using imprinting using a silicone mold. The polarizer was produced by depositing Al obliquely on the grating. The TM transmittance of the fabricated element was greater than 80% at a wavelength of 4.8 μm. The sol-gel zilconia films acted as antireflection films. The extinction ratio exceeded 26 dB at its wavelength.

  3. Position Detection Based on Intensities of Reflected Infrared Light

    DEFF Research Database (Denmark)

    Christensen, Henrik Vie

    measurements of reflected light intensities, and includes easy calibration. The method for reconstructing 3D positions has been implemented in a prototype of a “non-Touch Screen” for a computer, so that the user can control a cursor in three dimensions by moving his/hers hand in front of the computer screen....... The 2D position reconstruction method is mplemented in a prototype of a human-machine interface (HMI) for an electrically powered wheelchair, such that the wheelchair user can control the movement of the wheelchair by head movements. Both “non-Touch Screen” prototype and wheelchair HMI has been tested...

  4. Diffuse reflectance infrared Fourier-Transform spectra of selected organic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Harmon, S.H.; Caton, J.E.

    1982-05-01

    Diffuse reflectance infrared spectra of a variety of different organic compounds have been determined. Profiles of the spectra along with the location and relative intensity of the principal bands have been included for each compound studied. In addition both diffuse reflectance and transmittance infrared spectra were obtained for the same samples, and the spectral results were compared. Although some minor variations are observed between a diffuse reflectance spectrum and the corresponding transmittance spectrum, the diffuse reflectance is quite useful and may be a superior technique for the study of many samples because it possesses an inherently higher signal-to-noise response, requires less sample preparation and allows a very wide range of samples (solids, liquids of low volatility, neat sample, or sample diluted in a reflecting medium) to be studied under very similar conditions.

  5. Investigation of Latent Traces Using Infrared Reflectance Hyperspectral Imaging

    Science.gov (United States)

    Schubert, Till; Wenzel, Susanne; Roscher, Ribana; Stachniss, Cyrill

    2016-06-01

    The detection of traces is a main task of forensics. Hyperspectral imaging is a potential method from which we expect to capture more fluorescence effects than with common forensic light sources. This paper shows that the use of hyperspectral imaging is suited for the analysis of latent traces and extends the classical concept to the conservation of the crime scene for retrospective laboratory analysis. We examine specimen of blood, semen and saliva traces in several dilution steps, prepared on cardboard substrate. As our key result we successfully make latent traces visible up to dilution factor of 1:8000. We can attribute most of the detectability to interference of electromagnetic light with the water content of the traces in the shortwave infrared region of the spectrum. In a classification task we use several dimensionality reduction methods (PCA and LDA) in combination with a Maximum Likelihood classifier, assuming normally distributed data. Further, we use Random Forest as a competitive approach. The classifiers retrieve the exact positions of labelled trace preparation up to highest dilution and determine posterior probabilities. By modelling the classification task with a Markov Random Field we are able to integrate prior information about the spatial relation of neighboured pixel labels.

  6. Ghost maculopathy: an artifact on near-infrared reflectance and multicolor imaging masquerading as chorioretinal pathology.

    Science.gov (United States)

    Pang, Claudine E; Freund, K Bailey

    2014-07-01

    To describe the features of an artifact on near-infrared reflectance and MultiColor imaging, termed "ghost maculopathy," and to illustrate how it may masquerade as true chorioretinal pathology. This was a retrospective, observational case series. The authors studied 144 eyes of 72 consecutive patients in a vitreoretinal clinical practice, reviewing multimodal imaging including color and red-free fundus photography, fundus autofluorescence (FAF), near-infrared reflectance, MultiColor imaging, and spectral-domain optical coherence tomography (SD OCT). In 36 of 144 eyes (25%), there was an appearance of a hyper-reflective spot on near-infrared reflectance and MultiColor imaging, located at the macula, nasal or superonasal to the fovea, which did not correspond to any apparent lesion on color and red-free fundus photography, FAF, or SD OCT. This spot was termed the "ghost image" in this phenomenon of "ghost maculopathy." The ghost image was present consistently on near-infrared reflectance and MultiColor imaging in all 36 eyes at every imaging encounter, showing minimal and subtle variability in its shape and location within each eye; however, it showed large interindividual variability in size, shape, location, and reflectivity between different eyes. Nine eyes were found to have a similar hyper-reflective spot resembling that in ghost maculopathy, but corresponding SD OCT images were consistent with diagnoses of choroidal nevus, age-related macular degeneration, and multifocal choroiditis. All eyes with ghost maculopathy were found to be pseudophakic with a posterior chamber intraocular lens. Ghost maculopathy is the phenomenon of an imaging artifact appearing at the macula on near-infrared reflectance and MultiColor imaging that occurs predominantly in pseudophakic patients and may be mistaken for true chorioretinal pathology. Awareness of this artifact is prudent to avoid misinterpretation of clinical findings and possible unnecessary over-investigation. Copyright

  7. Near-infrared reflectance analysis by Gauss-Jordan linear algebra

    International Nuclear Information System (INIS)

    Honigs, D.E.; Freelin, J.M.; Hieftje, G.M.; Hirschfeld, T.B.

    1983-01-01

    Near-infrared reflectance analysis is an analytical technique that uses the near-infrared diffuse reflectance of a sample at several discrete wavelengths to predict the concentration of one or more of the chemical species in that sample. However, because near-infrared bands from solid samples are both abundant and broad, the reflectance at a given wavelength usually contains contributions from several sample components, requiring extensive calculations on overlapped bands. In the present study, these calculations have been performed using an approach similar to that employed in multi-component spectrophotometry, but with Gauss-Jordan linear algebra serving as the computational vehicle. Using this approach, correlations for percent protein in wheat flour and percent benzene in hydrocarbons have been obtained and are evaluated. The advantages of a linear-algebra approach over the common one employing stepwise regression are explored

  8. Polarization resolved imaging with a reflection near-field optical microscope

    DEFF Research Database (Denmark)

    Bozhevolnyi, Sergey I.; Xiao, Mufei; Hvam, Jørn Märcher

    1999-01-01

    Using a rigorous microscopic point-dipole description of probe-sample interactions, we study imaging with a reflection scanning near-field optical microscope. Optical content, topographical artifacts, sensitivity window-i.e., the scale on which near-field optical images represent mainly optical...... contrast-and symmetry properties are considered for optical images obtained in constant-distance mode for different polarization configurations. We demonstrate that images obtained in cross-polarized detection mode are free of background and topographical artifacts and that the cross-circular polarization...... configuration is preferable to the cross-linear one, since it ensures more isotropic (in the surface plane) near-field imaging of surface features. The numerical results are supported with experimental near-field images obtained by using a reflection microscope with an uncoated fiber tip....

  9. A Study of Bi-Directional Reflectance Distribution Functions and Their Effect on Infrared Signature Models

    Science.gov (United States)

    2007-03-01

    emission is in the IR spectrum. V is ib le Infrared Microwaves Radio waves UVX -Rays Gamma Rays 10-8 10-4 10-2 1µm 103 106 Figure 1.1: The infrared...spectrum is a subset of the electro- magnetic spectrum. Wavelength is in units of microns (µm). Adapted from [4, Figure 1.1]. 1 (a) (b) Figure 1.2: The...properties are independent of the azimuthal incidence angle, φi; most com- mon surface types fit this definition. Two exceptions to this assumption are polar

  10. Origin of Infrared Light Modulation in Reflectance-Mode Photoplethysmography.

    Directory of Open Access Journals (Sweden)

    Igor S Sidorov

    Full Text Available We recently pointed out the important role of dermis deformation by pulsating arterial pressure in the formation of a photoplethysmographic signal at green light. The aim of this study was to explore the role of this novel finding in near-infrared (NIR light. A light-emitting diode (LED-based imaging photoplethysmography (IPPG system was used to detect spatial distribution of blood pulsations under frame-to-frame switching green and NIR illumination in the palms of 34 healthy individuals. We observed a significant increase of light-intensity modulation at the heartbeat frequency for both illuminating wavelengths after a palm was contacted with a glass plate. Strong positive correlation between data measured at green and NIR light was found, suggesting that the same signal was read independently from the depth of penetration. Analysis of the data shows that an essential part of remitted NIR light is modulated in time as a result of elastic deformations of dermis caused by variable blood pressure in the arteries. Our observations suggest that in contrast with the classical model, photoplethysmographic waveform originates from the modulation of the density of capillaries caused by the variable pressure applied to the skin from large blood vessels. Particularly, beat-to-beat transmural pressure in arteries compresses/decompresses the dermis and deforms its connective-tissue components, thus affecting the distance between the capillaries, which results in the modulation of absorption and scattering coefficients of both green and NIR light. These findings are important for the correct interpretation of this widely used medical technique, which may have novel applications in diagnosis and treatment monitoring of aging and skin diseases.

  11. [Application of near-infrared diffuse reflectance spectroscopy to the detection and identification of transgenic corn].

    Science.gov (United States)

    Rui, Yu-kui; Luo, Yun-bo; Huang, Kun-lun; Wang, Wei-min; Zhang, Lu-da

    2005-10-01

    With the rapid development of the GMO, more and more GMO food has been pouring into the market. Much attention has been paid to GMO labeling under the controversy of GMO safety. Transgenic corns and their parents were scanned by continuous wave of near infrared diffuse reflectance spectroscopy range of 12000-4000 cm(-1); the resolution was 4 cm(-1); scanning was carried out for 64 times; BP algorithm was applied for data processing. The GMO food was easily resolved. Near-infrared diffuse reflectance spectroscopy is unpolluted and inexpensive compared with PCR and ELISA, so it is a very promising detection method for GMO food.

  12. Using remote sensing to detect the polarized sunglint reflected from oil slicks beyond the critical angle

    Science.gov (United States)

    Lu, Yingcheng; Zhou, Yang; Liu, Yongxue; Mao, Zhihua; Qian, Weixian; Wang, Mengqiu; Zhang, Minwei; Xu, Jiang; Sun, Shaojie; Du, Peijun

    2017-08-01

    The critical angle at which the brightness of oil slicks and oil-free seawater is reversed occurs under sunglint and is often shown as an area of uncertainty due to different roughness and surface Fresnel reflection parameters. Consequently, differentiating oil slicks from the seawater in these areas using optical sensors is a challenge. Polarized optical remote sensing techniques provide complementary information for intensity imagery with different physical properties and, thus, possess the ability to resolve this difficult problem. In the polarized reflectance model, the degree of linear polarization (DOLP) of sunglint depends on accurately knowing the Stokes parameter for the reflected light, and varies with the refractive index of the surface layer and viewing angles. For the polarized detection of oil slicks, the highest sensitivity of the DOLP to the refractive index is located within the specular reflection direction where the sum of the solar and sensor zenith angles is 82.6°. The modeled results clearly indicate that the DOLP of oil slicks is weaker in comparison with oil-free seawater under sunglint. Using measurements from the space-borne Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar (PARASOL) over the Deepwater Horizon oil spill in the Gulf of Mexico, we illustrate that the PARASOL-derived DOLP difference between the oil spill and seawater is obvious and is in accordance with the modeled results. These preliminary results suggest that the potential of multiangle measurement and feasibility of deriving refractive index of ocean surface from space-borne sensors need further researches.

  13. Mid-infrared reflectance of silicone resin coating on metal substrates: Effect of polymeric binders' absorption

    Science.gov (United States)

    Ho, Wen-Dar; Ma, Chen-Chi M.

    1997-04-01

    This study examines the infrared reflectance of polymeric coatings of silicone resin, silicone modified alkyd resin, and alkyd resin on aluminum substrates. The Kubelka-Munk's two constants theory is applied to calculate the reflectance while considering the surface reflection. An integrating sphere, infrared spectroradiometer and blackbody source are utilized as the measurement systems. The extinction coefficients are determined and used to calculate the reflectances of coatings on aluminum. Coefficients in the mid-infrared region display the quantitative difference between the polymers' structure. Silicone content enhances the absorptance of the coating in the mid-IR region. The coefficients of miscible silicone resin/alkyd resin blends are determined as well. Comparing the measured and calculated reflectances reveals that the discrepancies in thinner coatings or at the IR transparent wavelength are higher and around 0.1. Such a discrepancy is owing to the polymers' non-scattering with absorption properties which affect the validity of the values involving internal reflectances considered in the model. The internal reflectance can be assigned a negligible value in the high absorption region and is also a variable depending on thickness and transparency.

  14. Attenuated total internal reflection infrared microscopy of multilayer plastic packaging foils.

    Science.gov (United States)

    van Dalen, Gerard; Heussen, Patricia C M; den Adel, Ruud; Hoeve, Robert B J

    2007-06-01

    Multilayer plastic foils are important packaging materials that are used to extend the shelf life of food products and drinks. Fourier transform infrared (FT-IR) spectroscopic imaging using attenuated total internal reflection (ATR) can be used for the identification and localization of different layers in multilayer foils. A new type of ATR crystal was used in combination with a linear array detector through which large sample areas (400 x 400 microm(2)) could be imaged with a pixel size of 1.6 microm. The method was tested on laminated plastic packing materials containing 5 to 12 layers. The results of the identification of the different materials using ATR-FT-IR were compared with differential scanning calorimetry (DSC) and the layer thickness of the individual layers measured by ATR-FT-IR was compared with polarized light microscopy (LM) and scanning electron microscopy (SEM). It has been demonstrated that individual layers with a thickness of about 3 microm could be identified in multilayer foils with a total thickness ranging from 100 to 150 microm. The results show a spatial resolution of about 4 microm (measured at wavenumbers ranging from 1000 to 1730 cm(-1)), which is about a factor of two better than can be obtained using transmission FT-IR imaging. An additional advantage of ATR is the ease of sample preparation. A good correspondence was found between visible and FT-IR images. The results of ATR-FT-IR imaging were in agreement with those obtained by LM, SEM, and DSC. ATR-FT-IR is superior to the combination of these techniques because it delivers both spatial and chemical information.

  15. Full Polarization Analysis of Resonant Superlattice and Forbidden x-ray Reflections in Magnetite

    International Nuclear Information System (INIS)

    Wilkins, S.B.; Bland, S.R.; Detlefs, B.; Beale, T.A.W.; Mazzoli, C.; Joly, Y.; Hatton, P.D.; Lorenzo, J.E.; Brabers, V.A.M.

    2009-01-01

    Despite being one of the oldest known magnetic materials, and the classic mixed valence compound, thought to be charge ordered, the structure of magnetite below the Verwey transition is complex and the presence and role of charge order is still being debated. Here, we present resonant x-ray diffraction data at the iron K-edge on forbidden (0, 0, 2n+1) C and superlattice (0, 0, 2n+1/2)C reflections. Full linear polarization analysis of the incident and scattered light was conducted in order to explore the origins of the reflections. Through simulation of the resonant spectra we have confirmed that a degree of charge ordering takes place, while the anisotropic tensor of susceptibility scattering is responsible for the superlattice reflections below the Verwey transition. We also report the surprising result of the conversion of a significant proportion of the scattered light from linear to nonlinear polarization.

  16. Catheter based mid-infrared reflectance and reflectance generated absorption spectroscopy

    Science.gov (United States)

    Holman, Hoi-Ying N

    2013-10-29

    A method of characterizing conditions in a tissue, by (a) providing a catheter that has a light source that emits light in selected wavenumbers within the range of mid-IR spectrum; (b) directing the light from the catheter to an area of tissue at a location inside a blood vessel of a subject; (c) collecting light reflected from the location and generating a reflectance spectra; and (d) comparing the reflectance spectra to a reference spectra of normal tissue, whereby a location having an increased number of absorbance peaks at said selected wavenumbers indicates a tissue inside the blood vessel containing a physiological marker for atherosclerosis.

  17. How Can Polarization States of Reflected Light from Snow Surfaces Inform Us on Surface Normals and Ultimately Snow Grain Size Measurements?

    Science.gov (United States)

    Schneider, A. M.; Flanner, M.; Yang, P.; Yi, B.; Huang, X.; Feldman, D.

    2016-12-01

    The Snow Grain Size and Pollution (SGSP) algorithm is a method applied to Moderate Resolution Imaging Spectroradiometer data to estimate snow grain size from space-borne measurements. Previous studies validate and quantify potential sources of error in this method, but because it assumes flat snow surfaces, however, large scale variations in surface normals can cause biases in its estimates due to its dependence on solar and observation zenith angles. To address these variations, we apply the Monte Carlo method for photon transport using data containing the single scattering properties of different ice crystals to calculate polarization states of reflected monochromatic light at 1500nm from modeled snow surfaces. We evaluate the dependence of these polarization states on solar and observation geometry at 1500nm because multiple scattering is generally a mechanism for depolarization and the ice crystals are relatively absorptive at this wavelength. Using 1500nm thus results in a higher number of reflected photons undergoing fewer scattering events, increasing the likelihood of reflected light having higher degrees of polarization. In evaluating the validity of the model, we find agreement with previous studies pertaining to near-infrared spectral directional hemispherical reflectance (i.e. black-sky albedo) and similarities in measured bidirectional reflectance factors, but few studies exist modeling polarization states of reflected light from snow surfaces. Here, we present novel results pertaining to calculated polarization states and compare dependences on solar and observation geometry for different idealized snow surfaces. If these dependencies are consistent across different ice particle shapes and sizes, then these findings could inform the SGSP algorithm by providing useful relationships between measurable physical quantities and solar and observation geometry to better understand variations in snow surface normals from remote sensing observations.

  18. Spectral and spatial properties of polarized light reflections from the arms of squid (Loligo pealeii) and cuttlefish (Sepia officinalis L.).

    Science.gov (United States)

    Chiou, Tsyr-Huei; Mäthger, Lydia M; Hanlon, Roger T; Cronin, Thomas W

    2007-10-01

    On every arm of cuttlefish and squid there is a stripe of high-reflectance iridophores that reflects highly polarized light. Since cephalopods possess polarization vision, it has been hypothesized that these polarized stripes could serve an intraspecific communication function. We determined how polarization changes when these boneless arms move. By measuring the spectral and polarizing properties of the reflected light from samples at various angles of tilt and rotation, we found that the actual posture of the arm has little or no effect on partial polarization or the e-vector angle of the reflected light. However, when the illumination angle changed, the partial polarization of the reflected light also changed. The spectral reflections of the signals were also affected by the angle of illumination but not by the orientation of the sample. Electron microscope samples showed that these stripes are composed of several groups of multilayer platelets within the iridophores. The surface normal to each group is oriented at a different angle, which produces essentially constant reflection of polarized light over a range of viewing angles. These results demonstrate that cuttlefish and squid could send out reliable polarization signals to a receiver regardless of arm orientation.

  19. Simple Unbiased Hot-Electron Polarization-Sensitive Near-Infrared Photodetector.

    Science.gov (United States)

    Mirzaee, Somayeh M A; Lebel, Olivier; Nunzi, Jean-Michel

    2018-03-27

    Plasmonic nanostructures can generate energetic "hot" electrons from light in a broad band fashion depending on their shape, size, and arrangement. Such structures have a promising use in photodetectors, allowing high speed, broad band, and multicolor photodetection. Because they function without a band gap absorption, photon detection at any energy would be possible through engineering of the plasmonic nanostructure. Herein, a compact hot-electron-based photodetector that combines polarization sensitivity and circularly polarized light detection in the near-infrared region was fabricated using an indium tin oxide (ITO)-Au hybrid layer. Furthermore, the sensitivity of the device was significantly increased by adding a poled Azo molecular glass film in a capacitor configuration. The resulting device is capable of detecting light below the ITO band gap at ambient temperature without any bias voltage. This photodetector, which is amenable to large-area fabrication, can be integrated with other nanophotonic and nanoplasmonic structures for operation at telecom wavelengths.

  20. Polarization contrast in reflection near-field optical microscopy with uncoated fibre tips

    DEFF Research Database (Denmark)

    Bozhevolnyi, Sergey I.; Langbein, Wolfgang; Hvam, Jørn Märcher

    1999-01-01

    Using cross-hatched, patterned semiconductor surfaces and round 20-nm-thick gold pads on semiconductor wafers, we investigate the imaging characteristics of a reflection near-field optical microscope with an uncoated fibre tip for different polarization configurations and light wavelengths....... Is is shown that cross-polarized detection allows one to effectively suppress far-field components in the detected signal and to realise imaging of optical contrast on the sub-wavelength scale. The sensitivity window of our microscope, i.e. the scale on which near-field optical images represent mainly optical...

  1. Near-infrared reflectance imaging of neovascular age-related macular degeneration.

    NARCIS (Netherlands)

    Theelen, T.; Berendschot, T.T.; Hoyng, C.B.; Boon, C.J.F.; Klevering, B.J.

    2009-01-01

    PURPOSE: To evaluate various types of neovascular age-related macular degeneration (AMD) by near-infrared fundus reflectance (NIR) as compared to fundus fluorescein angiography (FFA) and to test NIR for assessment of leakage due to choroidal neovascularization (CNV). PATIENTS AND METHODS:

  2. Thermal inertia and radar reflectivity of the Martian north polar ERG: Low-density aggregates

    Science.gov (United States)

    Herkenhoff, K. E.

    1993-01-01

    The north polar layered deposits on Mars appear to be the source of the dark material that comprises the north polar erg. The physical properties and chemical composition of the erg material therefore have important implications for the origin and evolution of the Martian layered deposits. Viking bistatic radar and infrared thermal mapping (IRTM) data indicate that the bulk density of the erg material is lower than that of the average Martian surface. These data are consistent with hypotheses involving formation of filamentary sublimation residue (FSR) particles from erosion of the layered deposits. The color and albedo of the erg and of the layered deposits, and the presence of magnetic material on Mars, suggest that the dark material is composed of low-density aggregates of magnetic dust grains, perhaps similar to FSR particles created in laboratory experiments.

  3. Durable silver mirror with ultra-violet thru far infra-red reflection

    Science.gov (United States)

    Wolfe, Jesse D.

    2010-11-23

    A durable highly reflective silver mirror characterized by high reflectance in a broad spectral range of about 300 nm in the UV to the far infrared (.about.10000 nm), as well as exceptional environmental durability. A high absorptivity metal underlayer is used which prevents the formation of a galvanic cell with a silver layer while increasing the reflectance of the silver layer. Environmentally durable overcoat layers are provided to enhance mechanical and chemical durability and protect the silver layer from corrosion and tarnishing, for use in a wide variety of surroundings or climates, including harsh or extreme environments.

  4. Wideband and High-Efficiency Reflective Polarization Conversion Metasurface Based on Anisotropic Metamaterials

    Science.gov (United States)

    Zheng, Qi; Guo, Chenjiang; Yuan, Pengliang; Ren, Yu-Hui; Ding, Jun

    2018-02-01

    In this paper, we propose a wideband and high-efficiency reflective polarization conversion metasurface (PCM) based on anisotropic metamaterials. The PCM has a period of sub-wavelength and simple design with a double-meander-line-shaped resonator printed on a metallic copper plate backed dielectric substrate. Owing to strong anisotropic properties and multiple plasmon resonances at neighboring frequencies, the PCM has a simulated fractional bandwidth of 82.3% from 8.40 GHz to 20.15 GHz with a polarization conversion ratio over 0.9. Numerical analysis and experimental validation are carried out to study the polarization conversion characteristics of the PCM. In addition, the mechanisms are analyzed in detail on the basis of multiple plasmon resonances and surface magnetic field distributions, respectively. The measured and simulated results obtained are in good agreement, which validates the effectiveness of the simulations and analysis.

  5. Polarization control of high transmission/reflection switching by all-dielectric metasurfaces

    Science.gov (United States)

    Shibanuma, Toshihiko; Maier, Stefan A.; Albella, Pablo

    2018-02-01

    Metasurfaces built of high refractive dielectric nanostructures could play a key role in controlling the electromagnetic wave propagation, due to their low energy losses and their ability to excite not only electric but also magnetic resonances. In this study, we theoretically and experimentally demonstrate that an array of high-index dielectric nanodimers can perform as tuneable metasurfaces that can be switched from a high transmitter to a high reflector, by just changing the linear polarization of excitation. The incident polarization alters the hybridization mode of the excited electric and magnetic dipoles in the dimer, and this leads to either spectral overlap or separation of the two dipoles. The hybridization of the electric and magnetic modes modifies the effective permittivity and permeability of the tuneable dielectric metasurface, exhibiting the high transmission and reflection that can be easily switched by simply changing the linear polarization.

  6. Analysis of bacteria on steel surfaces using reflectance micro-Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Ojeda, Jesús J; Romero-González, María E; Banwart, Steven A

    2009-08-01

    Reflectance micro-Fourier transform infrared (FT-IR) analysis has been applied to characterize biofilm formation of Aquabacterium commune, a common microorganism present on drinking water distribution systems, onto the increasingly popular pipe material stainless steel EN1.4307. The applicability of the reflectance micro-FT-IR technique for analyzing the bacterial functional groups is discussed, and the results are compared to spectra obtained using more conventional FT-IR techniques: transmission micro-FT-IR, attenuated transmitted reflectance (ATR), and KBr pellets. The differences between the infrared spectra of wet and dried bacteria, as well as free versus attached bacteria, are also discussed. The spectra obtained using reflectance micro-FT-IR spectroscopy were comparable to those obtained using other FT-IR techniques. The absence of sample preparation, the potential to analyze intact samples, and the ability to characterize opaque and thick samples without the need to transfer the bacterial samples to an infrared transparent medium or produce a pure culture were the main advantages of reflectance micro-FT-IR spectroscopy.

  7. Intersubband absorption in annealed InAs/GaAs quantum dots: a case for polarization-sensitive infrared detection

    International Nuclear Information System (INIS)

    Chakrabarti, S; Bhattacharya, P; Stiff-Roberts, A D; Lin, Y Y; Singh, J; Lei, Y; Browning, N

    2003-01-01

    We have studied the characteristics of intersubband absorption of polarized infrared (IR) radiation in as-grown and annealed self-organized InAs/GaAs quantum dots. It is observed that with the increase of annealing time and temperature, the dots tend to flatten and behave more like quantum wells. As a result, their sensitivity to TE (in-plane)-polarized light decreases and that to TM (out-of-plane)-polarized light increases. The effect could be utilized for the realization of polarization-sensitive IR detectors

  8. [The research progress in determining lignocellulosic content by near infrared reflectance spectroscopy technology].

    Science.gov (United States)

    Du, Juan; An, Dong; Xia, Tian; Huang, Yan-Hua; Li, Hong-Chao; Zhang, Yun-Wei

    2013-12-01

    Near infrared reflectance spectroscopy technology, as a new analytic method, can be used to determine the content of lignin, cellulose and hemi-cellulose which is faster, effective, easier to operate, and more accurate than the traditional wet chemical methods. Nowadays it has been widely used in measuring the composition of lignocelluloses in woody plant and herbaceous plant. The domestic and foreign research progress in determining the lignin, cellulose and hemi-cellulose content in woody plant ( wood and bamboo used as papermaking raw materials and wood served as potential biomass energy) and herbaceous plant (forage grass and energy grass) by near infrared reflectance spectroscopy technology is comprehensively summarized and the advances in method studies of measuring the composition of lignocelluloses by near infrared reflectance spectroscopy technology are summed up in three aspects, sample preparation, spectral data pretreatment and wavelength selection methods, and chemometric analysis respectively. Four outlooks are proposed combining the development statues of wood, forage grass and energy grass industry. First of all, the authors need to establish more feasible and applicable models for a variety of uses which can be used for more species from different areas, periods and anatomical parts. Secondly, comprehensive near infrared reflectance spectroscopy data base of grass products quality index needs to be improved to realize on-line quality and process control in grassproducts industry, which can guarantee the quality of the grass product. Thirdly, the near infrared reflectance spectroscopy quality index model of energy plant need to be built which can not only contribute to breed screening, but also improve the development of biomass industry. Besides, modeling approaches are required to be explored and perfected any further. Finally, the authors need to try our best to boost the advancement in the determination method of lignin, cellulose and hemi

  9. Generation of neutron standing waves at total reflection of polarized neutrons

    International Nuclear Information System (INIS)

    Aksenov, V.L.; Nikitenko, Yu.V.; Kozhevnikov, S.V.; Radu, F.; Kruijs, R.; Rekveldt, M.Th.

    1999-01-01

    The regime of neutron standing waves at reflection of polarized thermal neutrons from the structure glass/Cu (1000 A Angstrom)/Ti (2000 A Angstrom)/Co (60 A Angstrom)/Ti (300 A Angstrom) in a magnetic field directed at an angle to the sample plane is realized. The intensity of neutrons with a particular spin projection on the external magnetic field direction appears to be a periodic function of the neutron wavelength and the glancing angle of the reflected beam. It is shown that the neutron standing wave regime can be a very sensitive method for the determination of changes in the spatial position of magnetic noncollinear layers. (author)

  10. Reflecting metallic metasurfaces designed with stochastic optimization as waveplates for manipulating light polarization

    Science.gov (United States)

    Haberko, Jakub; Wasylczyk, Piotr

    2018-03-01

    We demonstrate that a stochastic optimization algorithm with a properly chosen, weighted fitness function, following a global variation of parameters upon each step can be used to effectively design reflective polarizing optical elements. Two sub-wavelength metallic metasurfaces, corresponding to broadband half- and quarter-waveplates are demonstrated with simple structure topology, a uniform metallic coating and with the design suited for the currently available microfabrication techniques, such as ion milling or 3D printing.

  11. Characterization of process-induced damage in Cu/low-k interconnect structure by microscopic infrared spectroscopy with polarized infrared light

    Energy Technology Data Exchange (ETDEWEB)

    Seki, Hirofumi, E-mail: Hirofumi-Seki@trc.toray.co.jp; Hashimoto, Hideki [Toray Research Center, Inc., 3-3-7 Sonoyama, Otsu, Shiga 520-8567 (Japan); Ozaki, Yukihiro [Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1, Gakuen, Sanda, Hyogo 669-1337 (Japan)

    2016-09-07

    Microscopic Fourier-transform infrared (FT-IR) spectra are measured for a Cu/low-k interconnect structure using polarized IR light for different widths of low-k spaces and Cu lines, and for different heights of Cu lines, on Si substrates. Although the widths of the Cu line and the low-k space are 70 nm each, considerably smaller than the wavelength of the IR light, the FT-IR spectra of the low-k film were obtained for the Cu/low-k interconnect structure. A suitable method was established for measuring the process-induced damage in a low-k film that was not detected by the TEM-EELS (Transmission Electron Microscope-Electron Energy-Loss Spectroscopy) using microscopic IR polarized light. Based on the IR results, it was presumed that the FT-IR spectra mainly reflect the structural changes in the sidewalls of the low-k films for Cu/low-k interconnect structures, and the mechanism of generating process-induced damage involves the generation of Si-OH groups in the low-k film when the Si-CH{sub 3} bonds break during the fabrication processes. The Si-OH groups attract moisture and the OH peak intensity increases. It was concluded that the increase in the OH groups in the low-k film is a sensitive indicator of low-k damage. We achieved the characterization of the process-induced damage that was not detected by the TEM-EELS and speculated that the proposed method is applicable to interconnects with line and space widths of 70 nm/70 nm and on shorter scales of leading edge devices. The location of process-induced damage and its mechanism for the Cu/low-k interconnect structure were revealed via the measurement method.

  12. Polarization resolved classification of winter road condition in the near-infrared region.

    Science.gov (United States)

    Casselgren, Johan; Sjödahl, Mikael

    2012-05-20

    Three different configurations utilizing polarized short-wave infrared light to classify winter road conditions have been investigated. In the first configuration, polarized broadband light was detected in the specular and backward directions, and the quotient between the detected intensities was used as the classification parameter. Best results were obtained for the SS-configuration. This sensor was shown to be able to distinguish between the smooth road conditions of water and ice from the diffuse road conditions of snow and dry asphalt with a probability of wrong classification as low as 7%. The second sensor configuration was a pure backward architecture utilizing polarized light with two distinct wavelengths. This configuration was shown to be effective for the important problem of distinguishing water from ice with a probability of wrong classification of only 1.5%. The third configuration was a combination of the two previous ones. This combined sensor utilizing bispectral illumination and bidirectional detection resulted in a probability of wrong classification as low as 2% among all four surfaces.

  13. Infrared wire-grid polarizer with sol-gel zirconia grating

    Science.gov (United States)

    Yamada, Itsunari; Ishihara, Yoshiro

    2017-05-01

    The infrared wire-grid polarizer consisting of an Al grating, Si, and sol-gel derived zirconia grating film was fabricated by soft imprint process and Al shadow coating processes. A silicone mold was used because of its low surface energy, flexibility, and capability of transferring submicrosized patterns. As a result, the Al grating with a pitch of 400 nm and a depth of 100 nm was obtained on the zirconia grating film. The fabricated polarizer exhibited a polarization function with the TM transmittance greater than that of the Si substrate in the specific wavelength range of 3.6-8.5 μm, because the zirconia film acted as an antireflection film. The maximum value was 63% at a wavelength of 5.2 μm. This increment of the TM transmission spectrum results in interference within the zirconia film. Also, the extinction ratio exceeded almost 20 dB in the 3-8.8 μm wavelength range.

  14. On interstellar light polarization by diamagnetic silicate and carbon dust in the infrared

    Science.gov (United States)

    Papoular, R.

    2018-04-01

    The motion of diamagnetic dust particles in interstellar magnetic fields is studied numerically with several different sets of parameters. Two types of behaviour are observed, depending on the value of the critical number R, which is a function of the grain inertia, the magnetic susceptibility of the material and of the strength of rotation braking. If R ≤ 10, the grain ends up in a static state and perfectly aligned with the magnetic field, after a few braking times. If not, it goes on precessing and nutating about the field vector for a much longer time. Usual parameters are such that the first situation can hardly be observed. Fortunately, in the second and more likely situation, there remains a persistent partial alignment that is far from negligible, although it decreases as the field decreases and as R increases. The solution of the complete equations of motion of grains in a field helps understanding the details of this behaviour. One particular case of an ellipsoidal forsterite silicate grain is studied in detail and shown to polarize light in agreement with astronomical measurements of absolute polarization in the infrared. Phonons are shown to contribute to the progressive flattening of extinction and polarization towards long wavelengths. The measured dielectric properties of forsterite qualitatively fit the Serkowski peak in the visible.

  15. Atomic polarizations necessary for coherent infrared intensity modeling with theoretical calculations.

    Science.gov (United States)

    Richter, Wagner E; Silva, Arnaldo F; Bruns, Roy E

    2017-04-07

    The inclusion of atomic polarizations for describing molecular electronic structure changes on vibration is shown to be necessary for coherent infrared intensity modeling. Atomic charges from the ChelpG partition scheme and atomic charges and dipoles from Quantum Theory of Atoms in Molecules (QTAIM) were employed within two different models to describe the stretching and bending vibrational intensities of the C-H, C-F, and C=O groups. The model employing the QTAIM parameters was the Charge-Charge Transfer and Dipolar Polarization model (QTAIM/CCTDP), and the model employing the ChelpG charges was the Equilibrium Charge-Charge Flux (ChelpG/ECCF). The QTAIM/CCTDP models result in characteristic proportions of the charge-charge transfer-dipolar polarization contributions even though their sums giving the total intensities do not discriminate between these vibrations. According to the QTAIM/CCTDP model, the carbon monoxide intensity has electronic structure changes similar to those of the carbonyl stretches whereas they resemble those of the CH stretches for the ChelpG/ECCF model.

  16. A partial least squares model for non-volatile residue quantification using diffuse reflectance infrared reflectance spectroscopy

    Science.gov (United States)

    Chen, Amylynn; Moision, Robert M.

    2016-09-01

    Traditionally, quantification of non-volatile residue (NVR) on surfaces relevant to space systems has been performed using solvent wipes for NVR removal followed by gravimetric analysis. In this approach the detectable levels of NVR are ultimately determined by the mass sensitivity of the analytical balance employed. Unfortunately, for routine samples, gravimetric measurement requires large sampling areas, on the order of a square foot, in order to clearly distinguish sample and background levels. Diffuse Reflectance Infrared Reflectance Spectroscopy (DRIFTS) is one possible alternative to gravimetric analysis for NVR measurement. DRIFTS is an analytical technique used for the identification and quantification of organic compounds that has two primary advantages relative to gravimetric based methods: increased sensitivity and the ability to identify classes of organic species present. However, the use of DRIFTS is not without drawbacks, most notably repeatability of sample preparation and the additive quantification uncertainty arising from overlapping infrared signatures. This can result in traditional calibration methods greatly overestimating the concentration of species in mixtures. In this work, a partial least squares (PLS) regression model is shown to be an effective method for removing the over prediction error of a three component mixture of common contaminant species.

  17. Study of Surface Wettability Change of Unconsolidated Sand Using Diffuse Reflectance Infrared Fourier Transform Spectroscopy and Thermogravimetric Analysis.

    Science.gov (United States)

    Gómora-Herrera, Diana; Navarrete Bolaños, Juan; Lijanova, Irina V; Olivares-Xometl, Octavio; Likhanova, Natalya V

    2018-04-01

    The effects exerted by the adsorption of vapors of a non-polar compound (deuterated benzene) and a polar compound (water) on the surface of Ottawa sand and a sample of reservoir sand (Channel), which was previously impregnated with silicon oil or two kinds of surfactants, (2-hydroxyethyl) trimethylammonium oleate (HETAO) and (2-hydroxyethyl)trimethylammonium azelate (HETAA), were studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The surface chemistry of the sandstone rocks was elucidated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDX). Terminal surface groups such as hydroxyls can strongly adsorb molecules that interact with these surface groups (surfactants), resulting in a wettability change. The wettability change effect suffered by the surface after treating it with surfactants was possible to be detected by the DRIFTS technique, wherein it was observed that the surface became more hydrophobic after being treated with silicon oil and HETAO; the surface became more hydrophilic after treating it with HETAA.

  18. Circularly polarized reflection from the scarab beetle Chalcothea smaragdina: light scattering by a dual photonic structure.

    Science.gov (United States)

    McDonald, Luke T; Finlayson, Ewan D; Wilts, Bodo D; Vukusic, Pete

    2017-08-06

    Helicoidal architectures comprising various polysaccharides, such as chitin and cellulose, have been reported in biological systems. In some cases, these architectures exhibit stunning optical properties analogous to ordered cholesteric liquid crystal phases. In this work, we characterize the circularly polarized reflectance and optical scattering from the cuticle of the beetle Chalcothea smaragdina (Coleoptera: Scarabaeidae: Cetoniinae) using optical experiments, simulations and structural analysis. The selective reflection of left-handed circularly polarized light is attributed to a Bouligand-type helicoidal morphology within the beetle's exocuticle. Using electron microscopy to inform electromagnetic simulations of this anisotropic stratified medium, the inextricable connection between the colour appearance of C. smaragdina and the periodicity of its helicoidal rotation is shown. A close agreement between the model and the measured reflectance spectra is obtained. In addition, the elytral surface of C. smaragdina possesses a blazed diffraction grating-like surface structure, which affects the diffuse appearance of the beetle's reflected colour, and therefore potentially enhances crypsis among the dense foliage of its rainforest habitat.

  19. [Rapid determination of fatty acids in soybean oils by transmission reflection-near infrared spectroscopy].

    Science.gov (United States)

    Song, Tao; Zhang, Feng-ping; Liu, Yao-min; Wu, Zong-wen; Suo, You-rui

    2012-08-01

    In the present research, a novel method was established for determination of five fatty acids in soybean oil by transmission reflection-near infrared spectroscopy. The optimum conditions of mathematics model of five components (C16:0, C18:0, C18:1, C18:2 and C18:3) were studied, including the sample set selection, chemical value analysis, the detection methods and condition. Chemical value was analyzed by gas chromatography. One hundred fifty eight samples were selected, 138 for modeling set, 10 for testing set and 10 for unknown sample set. All samples were placed in sample pools and scanned by transmission reflection-near infrared spectrum after sonicleaning for 10 minute. The 1100-2500 nm spectral region was analyzed. The acquisition interval was 2 nm. Modified partial least square method was chosen for calibration mode creating. Result demonstrated that the 1-VR of five fatty acids between the reference value of the modeling sample set and the near infrared spectrum predictive value were 0.8839, 0.5830, 0.9001, 0.9776 and 0.9596, respectively. And the SECV of five fatty acids between the reference value of the modeling sample set and the near infrared spectrum predictive value were 0.42, 0.29, 0.83, 0.46 and 0.21, respectively. The standard error of the calibration (SECV) of five fatty acids between the reference value of testing sample set and the near infrared spectrum predictive value were 0.891, 0.790, 0.900, 0.976 and 0.942, respectively. It was proved that the near infrared spectrum predictive value was linear with chemical value and the mathematical model established for fatty acids of soybean oil was feasible. For validation, 10 unknown samples were selected for analysis by near infrared spectrum. The result demonstrated that the relative standard deviation between predict value and chemical value was less than 5.50%. That was to say that transmission reflection-near infrared spectroscopy had a good veracity in analysis of fatty acids of soybean oil.

  20. Quantification of SOC and Clay Content Using Visible Near-Infrared Reflectance–Mid-Infrared Reflectance Spectroscopy With Jack-Knifing Partial Least Squares Regression

    DEFF Research Database (Denmark)

    Peng, Yi; Knadel, Maria; Gislum, René

    2014-01-01

    A total of 125 soil samples were collected from a Danish field varying in soil texture from sandy to loamy. Visible near-infrared reflectance (Vis-NIR) and mid-infrared reflectance (MIR) spectroscopy combined with chemometric methods were used to predict soil organic carbon (SOC) and clay contents...... of error. Partial least squares regression with JK simplified and enhanced the interpretation of the developed models because of a reduction in the number of variables used in the models...

  1. Light-directing omnidirectional circularly polarized reflection from liquid-crystal droplets.

    Science.gov (United States)

    Fan, Jing; Li, Yannian; Bisoyi, Hari Krishna; Zola, Rafael S; Yang, Deng-Ke; Bunning, Timothy J; Weitz, David A; Li, Quan

    2015-02-09

    Constructing and tuning self-organized three-dimensional (3D) superstructures with tailored functionality is crucial in the nanofabrication of smart molecular devices. Herein we fabricate a self-organized, phototunable 3D photonic superstructure from monodisperse droplets of one-dimensional cholesteric liquid crystal (CLC) containing a photosensitive chiral molecular switch with high helical twisting power. The droplets are obtained by a glass capillary microfluidic technique by dispersing into PVA solution that facilitates planar anchoring of the liquid-crystal molecules at the droplet surface, as confirmed by the observation of normal incidence selective circular polarized reflection in all directions from the core of individual droplet. Photoirradiation of the droplets furnishes dynamic reflection colors without thermal relaxation, whose wavelength can be tuned reversibly by variation of the irradiation time. The results provided clear evidence on the phototunable reflection in all directions. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Prepreg cure monitoring using diffuse reflectance-FTIR. [Fourier Transform Infrared Technique

    Science.gov (United States)

    Young, P. R.; Chang, A. C.

    1984-01-01

    An in situ diffuse reflectance-Fourier transform infrared technique was developed to determine infrared spectra of graphite fiber prepregs as they were being cured. A bismaleimide, an epoxy, and addition polyimide matrix resin prepregs were studied. An experimental polyimide adhesive was also examined. Samples were positioned on a small heater at the focal point of diffuse reflectance optics and programmed at 15 F/min while FTIR spectra were being scanned, averaged, and stored. An analysis of the resulting spectra provided basic insights into changes in matrix resin molecular structure which accompanied reactions such as imidization and crosslinking. An endo-exothermal isomerization involving reactive end-caps was confirmed for the addition polyimide prepregs. The results of this study contribute to a fundamental understanding of the processing of composites and adhesives. Such understanding will promote the development of more efficient cure cycles.

  3. A Study on Infrared Emissivity Measurement of Material Surface by Reflection Method

    International Nuclear Information System (INIS)

    Kang, Byung Chul; Kim, Sang Myoung; Choi, Joung Yoon; Kim, Gun Ok

    2010-01-01

    Infrared emissivity is one of the most important factors for the temperature measurement by infrared thermography. Although the infrared emissivity of an object can be measured from the ratio of blackbody and the object, at room temperature it is practically difficult to measure the value due to the background effects. Hence, quantitative reflectance of bare steel plate and the surface of coating was measured by FT-IR spectroscopy and emissivity was calculated from this. The emissivity of polished bare steel surface was from 0.06 to 0.10 and the value for the unpolished bare steel can not be achieved because optical characteristics changes of surface roughness induces erroneous results. Emissivity of transparent paint coated steel was from 0.50 to 0.84. Depends on the IR absorption regions, which is a characteristic value of the coating, emissivity changes. This study suggests surface condition of material, thickness, roughness etcetra are important factor for IR optical characteristics. Emissivity measurement by reflection method is useful technique to be applied for metal and it with coating applied on the surface. The range of experimental errors of temperature can be narrowed by the application of infrared thermography from the measured thermal emissivity

  4. Electrically tunable selective reflection of light from ultraviolet to visible and infrared by heliconical cholesterics.

    Science.gov (United States)

    Xiang, Jie; Li, Yannian; Li, Quan; Paterson, Daniel A; Storey, John M D; Imrie, Corrie T; Lavrentovich, Oleg D

    2015-05-20

    Electrical tuning of selective reflection of light is achieved in a very broad spectral range from ultraviolet to visible and infrared by an oblique helicoidal state of a cholesteric liquid crystal in a wide temperature range (including room temperature). The phenomenon offers potential applications in tunable smart windows, lasers, optical filters and limiters, as well as in displays. © 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Far-infrared and submillimeter observations and physical models of the reflection nebula Cederblad 201

    NARCIS (Netherlands)

    Kemper, C; Spaans, M; Jansen, DJ; Hogerheijde, MR; van Dishoeck, EF; Tielens, AGGM

    1999-01-01

    Infrared Space Observatory (ISO) CC nl 158 mu m, [O I] 63 mu m, and H-2 9 and 17 mu m observations are presented of the reflection nebula Ced 201, which is a photon-dominated region (PDR) illuminated by a B9.5 star with a color temperature of 10,000 K (a cool PDR). In combination with ground-based

  6. Near infrared reflectance spectroscopy for the determination of free gossypol in cottonseed meal

    OpenAIRE

    Lordelo, M.M.; Shaaban, S.A.; Dale, N.M.; Calhoun, M.C.; Vendrel, P.F.; Davis, A.J.

    2008-01-01

    Gossypol is a toxic polyphenolic compound produced by the pigment glands of the cotton plant. The free gossypol content of cottonseed meal (CSM) is commonly determined by the American Oil Chemists’ Society (AOCS) wet chemistry method. The AOCS method, however, laboratory-intensive, time-consuming, and therefore, not practical for quick field analyses. To determine if the free gossypol content of CSM could be predicted by near infrared reflectance spectroscopy (NIRS), CSM sample...

  7. IRAS surface brightness maps of visible reflection nebulae: evidence for non-equilibrium infrared emission

    International Nuclear Information System (INIS)

    Castelaz, M.W.; Werner, M.W.; Sellgren, K.

    1986-01-01

    Surface brightness maps at 12, 25, 60, and 100 microns of 16 visible reflection nebulae were extracted from the Infrared Astronomy Satellite (IRAS) database. The maps were produced by coadding IRAS survey scans over areas centered on the illuminating stars, and have spatial resolutions of 0.9' x 4' at 12 and 25 microns, 1.8' x 4.5' at 60 microns, and 3.6' x 5' at 100 microns. Extended emission in the four IRAS bandpasses was detected in fourteen of the reflection nebulae. The IRAS data were used to measure the flux of the infrared emission associated with each source. The energy distributions show that the 12 micron flux is greater than the 25 micron flux in 11 of the nebulae, and the peak flux occurs in the 60 or 100 micron bandpass in all 16 nebular. The 60 and 100 micron flux can be approximated by blackbodies with temperatures between 30 and 50 K, consistent with temperatures expected from extrapolation of greybody fits to the 60 and 100 micron data. The excess 12 and 25 micron emission is attributed to a nonequilibrium process such as emission from thermal fluctuations of very small grains excited by single ultraviolet photons, or emission from polycyclic aromatic hydrocarbons (PAHs) excited by ultraviolet radiation. The common features of the energy distributions of the 16 reflection nebulae, also seen in the reflection nebulae associated with the Pleiades, suggest that PAHs or very small grains may be found in most reflection nebulae

  8. Multipitched Diffraction Gratings for Surface Plasmon Resonance-Enhanced Infrared Reflection Absorption Spectroscopy.

    Science.gov (United States)

    Petefish, Joseph W; Hillier, Andrew C

    2015-11-03

    We demonstrate the application of metal-coated diffraction gratings possessing multiple simultaneous pitch values for surface enhanced infrared absorption (SEIRA) spectroscopy. SEIRA increases the magnitude of vibrational signals in infrared measurements by one of several mechanisms, most frequently involving the enhanced electric field associated with surface plasmon resonance (SPR). While the majority of SEIRA applications to date have employed nanoparticle-based plasmonic systems, recent advances have shown how various metals and structures lead to similar signal enhancement. Recently, diffraction grating couplers have been demonstrated as a highly tunable platform for SEIRA. Indeed, gratings are an experimentally advantageous platform due to the inherently tunable nature of surface plasmon excitation at these surfaces since both the grating pitch and incident angle can be used to modify the spectral location of the plasmon resonance. In this work, we use laser interference lithography (LIL) to fabricate gratings possessing multiple pitch values by subjecting photoresist-coated glass slides to repetitive exposures at varying orientations. After metal coating, these gratings produced multiple, simultaneous plasmon peaks associated with the multipitched surface, as identified by infrared reflectance measurements. These plasmon peaks could then be coupled to vibrational modes in thin films to provide localized enhancement of infrared signals. We demonstrate the flexibility and tunability of this platform for signal enhancement. It is anticipated that, with further refinement, this approach might be used as a general platform for broadband enhancement of infrared spectroscopy.

  9. Characterizations of an infrared polarization-insensitive metamaterial perfect absorber and its potential in sensing applications

    Science.gov (United States)

    Tung, Nguyen Thanh; Tanaka, Takuo

    2018-02-01

    An increasing interest has been paid for metamaterial perfect absorbers, which offer attractive platforms for electromagnetic radiation based sensing applications. In this paper, we systematically characterize an infrared polarization-insensitive metamaterial absorbers by means of finite integration simulations and spectroscopic experiments. The metamaterial absorber is composed of symmetric disk-type metal-dielectric-metal structure, which shows a near-unity absorption peak at about 70 THz. It is found that the absorption frequency can be well predicted using the magnetic resonance theory while the dielectric-thickness dependent absorptivity can only be explained by the destructive interference theory. Spectral analysis reveals the possibility of using the proposed absorber as a high-performance refractive-index and thickness sensor for novel sensitive IR inspection technologies.

  10. Polarized dependence of nonlinear susceptibility in a single layer graphene system in infrared region

    Energy Technology Data Exchange (ETDEWEB)

    Solookinejad, G., E-mail: ghsolooki@gmail.com

    2016-09-15

    In this study, the linear and nonlinear susceptibility of a single-layer graphene nanostructure driven by a weak probe light and an elliptical polarized coupling field is discussed theoretically. The Landau levels of graphene can be separated in infrared or terahertz regions under the strong magnetic field. Therefore, by using the density matrix formalism in quantum optic, the linear and nonlinear susceptibility of the medium can be derived. It is demonstrated that by adjusting the elliptical parameter, one can manipulate the linear and nonlinear absorption as well as Kerr nonlinearity of the medium. It is realized that the enhanced Kerr nonlinearity can be possible with zero linear absorption and nonlinear amplification at some values of elliptical parameter. Our results may be having potential applications in quantum information science based on Nano scales devices.

  11. Reflection performance research of grating with polarization independence based on a sandwiched structure

    Science.gov (United States)

    Pei, Hao; Wang, Bo; Zhu, Wenhua; Yin, Sufang; Chen, Li; Lei, Liang; Zhou, Jinyun

    2018-02-01

    The novel reflective grating was studied under Littrow incidence as one sort of high-efficiency optical element. A covering layer and a dielectric layer are employed in this structure to achieve higher efficiency and wider bandwidth. For the given wavelength of 1550 nm, by using two-beam-interference theory of modal method, duty cycle and period of grating can be calculated, where the physical essence of high efficiency in the first-order is well explained by the modal method. The other grating parameters are optimized by using rigorous coupled-wave analysis. The optimized grating has an appropriate aspect ratio and shows that diffraction efficiencies of TE and TM polarizations in the first-order are greater than 97%. Compared with the reported surface-relief high-efficiency grating, the diffraction efficiencies of the proposed grating for TE and TM polarizations can be greatly improved.

  12. Discrimination between immature and mature green coffees by attenuated total reflectance and diffuse reflectance Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Craig, Ana Paula; Franca, Adriana S; Oliveira, Leandro S

    2011-10-01

    The objective of this work was to evaluate the potential of Fourier transform infrared spectroscopy (FTIR) in the characterization and discrimination between immature and mature or ripe coffee beans. Arabica coffee beans were submitted to FTIR analysis by reflectance readings employing attenuated total reflectance (ATR) and diffuse reflectance (DR) accessories. The obtained spectra were similar, but in general higher absorbance values were observed for nondefective beans in comparison to immature ones. Multivariate statistical analysis (principal component analysis, PCA, and agglomerative hierarchical clustering, AHC) was performed in order to verify the possibility of discrimination between immature and mature coffee samples. A clear separation between immature and mature coffees was observed based on AHC and PCA analyses of the normalized spectra obtained by employing both ATR and DR accessories. Linear discriminant analysis was employed for developing classification models, with recognition and prediction abilities of 100%. Such results showed that FTIR analysis presents potential for the development of a simple routine methodology for separation of immature and mature coffee beans. Practical Application: The ultimate goal of this research is to be able to propose improvements in the way immature coffee beans are separated from graded mature beans in coffee facilities (cooperatives and other coffee producer's associations). The results obtained herein point toward FTIR as a potential tool for the aimed improvements. © 2011 Institute of Food Technologists®

  13. Identification of Uranium Minerals in Natural U-Bearing Rocks Using Infrared Reflectance Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Beiswenger, Toya N. [Pacific Northwest National Laboratory, Richland, WA, USA; Gallagher, Neal B. [Eigenvector Research, Inc., Manson, WA, USA; Myers, Tanya L. [Pacific Northwest National Laboratory, Richland, WA, USA; Szecsody, James E. [Pacific Northwest National Laboratory, Richland, WA, USA; Tonkyn, Russell G. [Pacific Northwest National Laboratory, Richland, WA, USA; Su, Yin-Fong [Pacific Northwest National Laboratory, Richland, WA, USA; Sweet, Lucas E. [Pacific Northwest National Laboratory, Richland, WA, USA; Lewallen, Tricia A. [Pacific Northwest National Laboratory, Richland, WA, USA; Johnson, Timothy J. [Pacific Northwest National Laboratory, Richland, WA, USA

    2017-10-24

    The identification of minerals, including uranium-bearing minerals, is traditionally a labor-intensive-process using x-ray diffraction (XRD), fluorescence, or other solid-phase and wet chemical techniques. While handheld XRD and fluorescence instruments can aid in field identification, handheld infrared reflectance spectrometers can also be used in industrial or field environments, with rapid, non-destructive identification possible via spectral analysis of the solid’s reflectance spectrum. We have recently developed standard laboratory measurement methods for the infrared (IR) reflectance of solids and have investigated using these techniques for the identification of uranium-bearing minerals, using XRD methods for ground-truth. Due to the rich colors of such species, including distinctive spectroscopic signatures in the infrared, identification is facile and specific, both for samples that are pure or are partially composed of uranium (e.g. boltwoodite, schoepite, tyuyamunite, carnotite, etc.) or non-uranium minerals. The method can be used to detect not only pure and partial minerals, but is quite sensitive to chemical change such as hydration (e.g. schoepite). We have further applied statistical methods, in particular classical least squares (CLS) and multivariate curve resolution (MCR) for discrimination of such uranium minerals and two uranium pure chemicals (U3O8 and UO2) against common background materials (e.g. silica sand, asphalt, calcite, K-feldspar) with good success. Each mineral contains unique infrared spectral features; some of the IR features are similar or common to entire classes of minerals, typically arising from similar chemical moieties or functional groups in the minerals: phosphates, sulfates, carbonates, etc. These characteristic 2 infrared bands generate the unique (or class-specific) bands that distinguish the mineral from the interferents or backgrounds. We have observed several cases where the chemical moieties that provide the

  14. Self-assembled iron oxide nanoparticle multilayer: x-ray and polarized neutron reflectivity.

    Science.gov (United States)

    Mishra, D; Benitez, M J; Petracic, O; Badini Confalonieri, G A; Szary, P; Brüssing, F; Theis-Bröhl, K; Devishvili, A; Vorobiev, A; Konovalov, O; Paulus, M; Sternemann, C; Toperverg, B P; Zabel, H

    2012-02-10

    We have investigated the structure and magnetism of self-assembled, 20 nm diameter iron oxide nanoparticles covered by an oleic acid shell for scrutinizing their structural and magnetic correlations. The nanoparticles were spin-coated on an Si substrate as a single monolayer and as a stack of 5 ML forming a multilayer. X-ray scattering (reflectivity and grazing incidence small-angle scattering) confirms high in-plane hexagonal correlation and a good layering property of the nanoparticles. Using polarized neutron reflectivity we have also determined the long range magnetic correlations parallel and perpendicular to the layers in addition to the structural ones. In a field of 5 kOe we determine a magnetization value of about 80% of the saturation value. At remanence the global magnetization is close to zero. However, polarized neutron reflectivity reveals the existence of regions in which magnetic moments of nanoparticles are well aligned, while losing order over longer distances. These findings confirm that in the nanoparticle assembly the magnetic dipole-dipole interaction is rather strong, dominating the collective magnetic properties at room temperature.

  15. All dielectric reflective metasurface for controlling phase and polarization by using silicon nanoblocks

    Science.gov (United States)

    Kim, Youngsoo; Lee, Young Jin; Hong, Seokhyeun; Moon, Kihwan; Kwon, Soon-Hong

    2017-09-01

    We suggest all dielectric metasurfaces composed of silicon (Si) nanoblock array. We can control the phase and polarization of light reflected the metasurface by changing Mie scattering of each Si block. The Mie scattering is easily adjusted by changing structure parameters of Si block width and height. In single Si nanoblock, the magnetic dipole resonance mode was diminished when decreasing its height. In this study, for making 2-dimensional metasurface, we analyze the scattering cross-section by changing width and height of Si nanoblock with finite-difference time-domain method.

  16. Polarization sensitive subcutaneous and muscular imaging based on common path optical coherence tomography using near infrared source.

    Science.gov (United States)

    Han, Jae-Ho; Kang, Jin U; Song, Chul Gyu

    2011-08-01

    In this paper, we describe a polarization sensitive (PS) subcutaneous and muscular imaging system based on common path optical coherence tomography (CP-OCT) using a near infrared source. The axial and lateral resolutions of the PS-OCT system are 9 and 6 μm, respectively. The main goal of this work is to build a high-resolution and minimally invasive optical imager for examining various kinds of cutaneous substructures with intrinsic or form birefringence. The internal structural information is extracted by the real-time signal analysis (Fourier Transform) of the modulated spectral intensity depending on the beam and tissue birefringence. The preliminary results using fresh beef longissimus muscle and in vivo Rattus norvegicus (rat) show that it is possible to visualize the birefringence effect of the tissue collagen fibers in the samples in order to achieve superior image contrast and sensitivity for the detection of hidden dermal structures. Compared to conventional CP-OCT, the proposed PS-OCT system provides depth-resolved images, which reflect the tissue birefringence.

  17. HAWC+/SOFIA observations of Rho Oph A: far-infrared polarization spectrum

    Science.gov (United States)

    Santos, Fabio; Dowell, Charles D.; Houde, Martin; Looney, Leslie; Lopez-Rodriguez, Enrique; Novak, Giles; Ward-Thompson, Derek; HAWC+ Science Team

    2018-01-01

    In this work, we present preliminary results from the HAWC+ far-infrared polarimeter that operates on the SOFIA airborne observatory. The densest portions of the Rho Ophiuchi molecular complex, known as Rho Oph A, have been mapped using HAWC+ bands C (89 microns) and D (155 microns). Rho Oph A is a well known nearby star forming region. At the target's distance of approximately 130 pc, our observations provide excellent spatial resolution (~5 mpc in band C).The magnetic field map suggests a compressed and distorted field morphology around Oph S1, a massive B3 star that is the main heat source of Rho Oph A. We compute the ratio p(D)/p(C), where p(C) and p(D) are the polarization degree maps at bands C and D, respectively. This ratio estimates the slope of the polarization spectrum in the far-infrared. Although the slope is predicted to be positive by dust grain models, previous observations of other molecular clouds have revealed that negative slopes are common. In Rho Oph A, we find that there is a smooth gradient of p(D)/p(C) across the mapped field. The change in p(D)/p(C) is well correlated with the integrated NH3 (1,1) emission. A positive slope dominates the lower density and well illuminated portions of the cloud, whereas a transition to a negative slope is observed at the denser and less evenly illuminated cloud core.We interpret the positive to negative slope transition as being consistent with the radiative torques (RATs) grain alignment theory. For the sight lines of higher column density, polarized emission from the warmer outer cloud layers is added to emission from the colder inner well-shielded layers lying along the same line-of-sight. Given that the outer layers receive more radiation from Oph S1, their grain alignment efficiency is expected to be higher according to RATs. The combination of warmer, well aligned grains with cooler, poorly aligned grains is what causes the negative slope. This effect is not present in the sight lines of lower column

  18. [The evaluation of hydrocarbon potential generation for source rocks by near-infrared diffuse reflection spectra].

    Science.gov (United States)

    Zhang, Yu-Jia; Xu, Xiao-Xuan; Song, Ning; Wu, Zhong-Chen; Zhou, Xiang; Chen, Jin; Cao, Xue-Wei; Wang, Bin

    2011-04-01

    Near-infrared (NIR) and mid-infrared (MIR) diffuse reflection spectra were compared and evaluated for hydrocarbon potential generation of source rocks. Near-infrared diffuse reflectance often exhibits significant differences in the spectra due to the non-homogeneous distribution of the particles, so the signal-to-noise ratio of NIR is much lower than MIR It is too difficult to get accurate results by NIR without using a strong spectral preprocessing method to remove systematic noise such as base-line variation and multiplicative scatter effects. In the present paper, orthogonal signal correction (OSC) and an improved algorithm of it, i.e. direct orthogonal signal correction (DOSC), are used as different methods to preprocess both the NIR and MIR spectra of the hydrocarbon source rocks. Another algorithm, wavelet multi-scale direct orthogonal signal correction (WMDOSC), which is a combination of discrete wavelet transform (DWT) and DOSC, is also used as a preprocessing method. Then, the calibration model of hydrocarbon source rocks before and after pretreatment was established by interval partial least square (iPLS). The experimental results show that WMDOSC is more successfully applied to preprocess the NIR spectra data of the hydrocarbon source rocks than other two algorithms, and NIR performed as good as MIR in the analysis of hydrocarbon potential generation of source rocks with WMDOSC-iPLS pretreatment calibration model.

  19. Influence of InAlN Nanospiral Structures on the Behavior of Reflected Light Polarization

    Directory of Open Access Journals (Sweden)

    Yu-Hung Kuo

    2018-03-01

    Full Text Available The influence of structural configurations of indium aluminum nitride (InAlN nanospirals, grown by reactive magnetron sputter epitaxy, on the transformation of light polarization are investigated in terms of varying structural chirality, growth temperatures, titanium nitride (TiN seed (buffer layer thickness, nanospiral thickness, and pitch. The handedness of reflected circularly polarized light in the ultraviolet–visible region corresponding to the chirality of nanospirals is demonstrated. A high degree of circular polarization (Pc value of 0.75 is obtained from a sample consisting of 1.2 μm InAlN nanospirals grown at 650 °C. A film-like structure is formed at temperatures lower than 450 °C. At growth temperatures higher than 750 °C, less than 0.1 In-content is incorporated into the InAlN nanospirals. Both cases reveal very low Pc. A red shift of wavelength at Pc peak is found with increasing nanospiral pitch in the range of 200–300 nm. The Pc decreases to 0.37 for two-turn nanospirals with total length of 0.7 μm, attributed to insufficient constructive interference. A branch-like structure appears on the surface when the nanospirals are grown longer than 1.2 μm, which yields a low Pc around 0.5, caused by the excessive scattering of incident light.

  20. Optically ambidextrous circularly polarized reflection from the chiral cuticle of the scarab beetle Chrysina resplendens.

    Science.gov (United States)

    Finlayson, Ewan D; McDonald, Luke T; Vukusic, Pete

    2017-06-01

    The evolution of structural colour mechanisms in biological systems has given rise to many interesting optical effects in animals and plants. The instance of the scarab beetle Chrysina resplendens is particularly distinctive. Its exoskeleton has a bright, golden appearance and reflects both right-handed and left-handed circularly polarized light concurrently. The chiral nanostructure responsible for these properties is a helicoid, in which birefringent dielectric planes are assembled with an incremental rotation. This study correlates details of the beetle's circularly polarized reflectance spectra directly with physical aspects of its structural morphology. Electron micrography is used to identify and measure the physical dimensions of the key constituent components. These include a chiral multilayer configuration comprising two chirped, left-handed helicoids that are separated by a birefringent retarder. A scattering matrix technique is used to simulate the system's optical behaviour in which the roles of each component of the morphological substructure are elucidated by calculation of the fields throughout its depth. © 2017 The Author(s).

  1. Attenuated total reflectance Fourier transform infrared spectroscopy analysis of red seal inks on questioned document.

    Science.gov (United States)

    Nam, Yun Sik; Park, Jin Sook; Kim, Nak-Kyoon; Lee, Yeonhee; Lee, Kang-Bong

    2014-07-01

    Seals are traditionally used in the Far East Asia to stamp an impression on a document in place of a signature. In this study, an accuser claimed that a personal contract regarding mining development rights acquired by a defendant was devolved to the accuser because the defendant stamped the devolvement contract in the presence of the accuser and a witness. The accuser further stated that the seal ink stamped on the devolvement contract was the same as that stamped on the development rights application document. To verify this, the seals used in two documents were analyzed using micro-attenuated total reflectance Fourier transform infrared spectroscopy and infrared spectra. The findings revealed that the seals originated from different manufacturers. Thus, the accuser's claim on the existence of a devolvement contract was proved to be false. © 2014 American Academy of Forensic Sciences.

  2. [Applications of near infrared reflectance spectroscopy technique (NIRS) to soil attributes research].

    Science.gov (United States)

    Liu, Yan-De; Xiong, Song-Sheng; Liu, De-Li

    2014-10-01

    Soil is a much complicated substance, because animals, plants and microbes live together, organic and inorganic exist together. So soil contains a large amount of information. The traditional method in laboratory is a time-consuming effort. But the technology of near infrared reflectance spectroscopy (NIRS) has been widely used in many areas, owing to its rapidness, high efficiency, no pollution and low cost, NIRS has become the most important method to detect the composition of soil. This paper mainly introduce some traditional methods in laboratory, the basic processes of soil detection by NIRS, some algorithms for data preprocessing and modeling. Besides, the present paper illustrates the latest research progress and the development of portable near infrared instruments of the soil. According to this paper, the authors also hope to promote the application conditions of NIRS in the grassland ecology research in China, and accelerate the modernization of research measures in this area.

  3. In situ probing of surface hydrides on hydrogenated amorphous silicon using attenuated total reflection infrared spectroscopy

    CERN Document Server

    Kessels, W M M; Sanden, M C M; Aydil, E S

    2002-01-01

    An in situ method based on attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) is presented for detecting surface silicon hydrides on plasma deposited hydrogenated amorphous silicon (a-Si:H) films and for determining their surface concentrations. Surface silicon hydrides are desorbed by exposing the a-Si:H films to low energy ions from a low density Ar plasma and by comparing the infrared spectrum before and after this low energy ion bombardment, the absorptions by surface hydrides can sensitively be separated from absorptions by bulk hydrides incorporated into the film. An experimental comparison with other methods that utilize isotope exchange of the surface hydrogen with deuterium showed good agreement and the advantages and disadvantages of the different methods are discussed. Furthermore, the determination of the composition of the surface hydrogen bondings on the basis of the literature data on hydrogenated crystalline silicon surfaces is presented, and quantification of the h...

  4. The polarized neutron reflectivity and X-ray reflectivity studies of the magnetic profiles of epitaxial Ni80Fe20/Ru multilayers

    International Nuclear Information System (INIS)

    Su, H.-C.; Peir, J.-J.; Lee, C.-H.; Lin, M.-Z.; Wu, P.-T.; Huang, J.C.A.; Tun Zin

    2005-01-01

    The depth profiles of the epitaxial Ni 80 Fe 20 (1 1 1)/Ru(0 0 0 1) multilayers were studied by polarized neutron reflectivity and X-ray reflectivity. At the Ru thickness that the anti-ferromagnetic coupling was found, the magnetic moments between two Ni 80 Fe 20 interlayers show a biquadratic coupling effect with a double unit cell at low applied fields. A magnetic dead layer of about 0.3 nm was also found at the interface boundaries. The maximal polarization effect applied to the Ru layer is less than 0.03μ B

  5. The Bone Black Pigment Identification by Noninvasive, In Situ Infrared Reflection Spectroscopy

    Directory of Open Access Journals (Sweden)

    Alessia Daveri

    2018-01-01

    Full Text Available Two real case studies, an oil painting on woven paper and a cycle of mural paintings, have been presented to validate the use of infrared reflection spectroscopy as suitable technique for the identification of bone black pigment. By the use of the sharp weak band at 2013 cm−1, it has been possible to distinguish animal carbon-based blacks by a noninvasive method. Finally, an attempt for an eventual assignment for the widely used sharp band at 2013 cm−1 is discussed.

  6. Rapid biochemical methane potential prediction of urban organic waste with near-infrared reflectance spectroscopy

    DEFF Research Database (Denmark)

    Fitamo, Temesgen Mathewos; Triolo, Jin Mi; Boldrin, Alessio

    2017-01-01

    The anaerobic digestibility of various biomass feedstocks in biogas plants is determined with biochemical methane potential (BMP) assays. However, experimental BMP analysis is time-consuming, costly and challenging to optimise stock management and feeding to achieve improved biogas production....... The aim of the present study is to develop a fast and reliable model based on near-infrared reflectance spectroscopy (NIRS) for the BMP prediction of urban organic waste (UOW). The model comprised 87 UOW samples. Additionally, 88 plant biomass samples were included, to develop a combined model predicting...

  7. Determination of Moisture Content in 5-Fluorouracil using Diffuse Reflectance Infrared Spectroscopy

    Science.gov (United States)

    Singh, Parul; Jangir, Deepak Kumar; Mehrotra, Ranjana; Kandpal, H. C.

    2008-11-01

    Determination of moisture content in pharmaceuticals is very important, as moisture is mainly responsible for the degradation of drugs. The degraded drug has not only reduced efficacy but is also hazardous for health. The objective of the present work is to replace the Karl Fischer (KF) titration method used for moisture analysis with a method that is rapid, involves no toxic materials and is more effective. Diffuse reflectance infrared spectroscopy, which is explored as a potential alternate for various applications, is investigated for moisture analysis in 5-Fluorouracil, an anticancer drug.

  8. Methods for Thickness Determination of SiC Homoepilayers by Using Infrared Reflectance Spectroscopy

    International Nuclear Information System (INIS)

    Zhi-Yun, Li; Ji-Wei, Sun; Yu-Ming, Zhang; Yi-Men, Zhang; Xiao-Yan, Tang

    2010-01-01

    Infrared reflectance spectra have been widely used to measure layer thickness based either on calculation or on curve fitting, and two traditional methods for thickness determination have been studied. Considering the disadvantages of those two methods, we propose a new fitting model based on the fitting of the fringe order difference. In comparison with the measured results, the new fitting model shows its superiority not only for its stable and accurate results which have great agreement with the results from SEM, but also for its simple and quick fitting process. (cross-disciplinary physics and related areas of science and technology)

  9. A far-infrared polarized view of active galactic nuclei with SOFIA/HAWC+

    Science.gov (United States)

    Lopez Rodriguez, Enrique; HAWC+ Science Team

    2018-01-01

    Near- to mid-infrared (NIR, MIR; 1-13 μm) total and polarized flux observations from the ground have been key to advance our understanding about the dust distribution and emission in the central few parsecs of the active galactic nucleus (AGN), i.e. jets and dusty torus, as well as in their central few hundred parsecs, i.e. narrow line regions. Our previous studies provided insights about 1) a potential cut-off wavelength at > 40 μm of the synchrotron emission from the pc-scale jet close to the core of Cygnus A, 2) the peak emission of the dusty torus occurs at wavelengths > 32 μm in a sample of nearby and bright AGN, and 3) thermal emission from magnetic galactic winds in M82. However, the atmosphere is opaque to the far-IR (FIR) range and observations are impossible from ground-based telescopes and also polarimetric capabilities have been very limited in this wavelength range, which it makes difficult to observationally constraint our previous findings. HAWC+ has open a new window to explore AGN and starburst galaxies, providing the best angular resolution and the solely polarimetric capability within the 50-220 μm range of the current suite of instruments.We here present preliminary results of AGN and starburst galaxies observed with the FIR polarimeter HAWC+ onboard the Stratospheric Observatory for Infrared Astronomy (SOFIA). Specifically, our total flux observations of NGC 1068 at 53 μm have shown for the first time the turn-over emission of the dusty torus in the range of 30-40 μm, which it allows us to put tight constraints on the clumpy torus model parameters such as the torus size, ˜6 pc, number and distribution of clouds. Our polarized flux observations of M82, in combination with previously published NIR polarimetric observations, have shown evidences of a galactic magnetic wind at scales of few hundred parsecs.

  10. Pluto-Charon: Infrared Reflectance from 3.6 to 8.0 Micrometers

    Science.gov (United States)

    Cruikshank, Dale P.; Emery, Joshua P.; Stansberry, John A.; VanCleve, Jeffrey E.

    2004-01-01

    We have measured the spectral reflectance of the Pluto-Charon pair at 3.6, 4.5, 5.8, and 8.0 micrometers with the Infrared Array Camera (IRAC) (G. G. Fazzio et al. Ap.J.Supp. 154, 10-17, 2004) on the Spitzer Space Telescope (STS), at eight different longitudes that cover a full rotation of the planet. STS does not have sufficient resolution to separate the light from the planet and the satellite. The image of the Pluto-Charon pair is clearly visible at each of the four wavelengths. We will discuss the spectral reflectance in terms of models that include the known components of Pluto and Charon s surfaces, and evidence for diurnal variations.

  11. Sediment mineralogy based on visible and near-infrared reflectance spectroscopy

    Science.gov (United States)

    Jarrard, R.D.; Vanden Berg, M.D.; ,

    2006-01-01

    Visible and near-infrared spectroscopy (VNIS) can be used to measure reflectance spectra (wavelength 350-2500 nm) for sediment cores and samples. A local ground-truth calibration of spectral features to mineral percentages is calculated by measuring reflectance spectra for a suite of samples of known mineralogy. This approach has been tested on powders, core plugs and split cores, and we conclude that it works well on all three, unless pore water is present. Initial VNIS studies have concentrated on determination of relative proportions of carbonate, opal, smectite and illite in equatorial Pacific sediments. Shipboard VNIS-based determination of these four components was demonstrated on Ocean Drilling Program Leg 199. ?? The Geological Society of London 2006.

  12. High-accuracy infra-red thermography method using reflective marker arrays

    Science.gov (United States)

    Kirollos, Benjamin; Povey, Thomas

    2017-09-01

    In this paper, we describe a new method for high-accuracy infra-red (IR) thermography measurements in situations with significant spatial variation in reflected radiation from the surroundings, or significant spatial variation in surface emissivity due to viewing angle non-uniformity across the field of view. The method employs a reflective marker array (RMA) on the target surface—typically, high emissivity circular dots—and an integrated image analysis algorithm designed to require minimal human input. The new technique has two particular advantages which make it suited to high-accuracy measurements in demanding environments: (i) it allows the reflected radiation component to be calculated directly, in situ, and as a function of position, overcoming a key problem in measurement environments with non-uniform and unsteady stray radiation from the surroundings; (ii) using image analysis of the marker array (via apparent aspect ratio of the circular reflective markers), the local viewing angle of the target surface can be estimated, allowing corrections for angular variation of local emissivity to be performed without prior knowledge of the geometry. A third advantage of the technique is that allows for simple focus-stacking algorithms due to increased image entropy. The reflective marker array method is demonstrated for an isothermal, hemispherical object exposed to an external IR source arranged to give a significant non-uniform reflected radiation term. This is an example of a challenging environment, both because of the significant non-uniform reflected radiation term, and also the significant variation in target emissivity due to surface angle variation. We demonstrate that the new RMA IR technique leads to significantly lower error in evaluated surface temperature than conventional IR techniques. The method is applicable to any complex radiative environment.

  13. Reflecting and Polarizing Properties of Conductive Fabrics in Ultra-High Frequency Range

    Directory of Open Access Journals (Sweden)

    Oleg Kiprijanovič

    2015-09-01

    Full Text Available The system based on ultra-wide band (UWB signals was employed for qualitative estimation of attenuating, reflecting and polarizing properties of conductive fabrics, capable to prevent local static charge accumulation. Pulsed excitation of triangle monopole antenna of 6.5 cm height by rectangular electric pulses induced radiation of UWB signals with spectral density of power having maximum in ultra-high frequency (UHF range. The same antenna was used for the radiated signal receiving. Filters and amplifiers of different passband were employed to divide UHF range into subranges of 0.3-0.55 GHz, 0.55-1 GHz, 1-2 GHz and 2-4 GHz bands. The free space method, when conductive fabric samples of 50x50 cm2 were placed between transmitting and receiving antennas, was used to imitate a practical application. Received wideband signals corresponding to the defined range were detected by unbiased detectors. The fabrics made of two types of warps, containing different threads with conductive yarns, were investigated. It was estimated attenuation and reflective properties of the fabrics when electric field is collinear or perpendicular to thread direction. In the UHF range it was revealed good reflecting properties of the fabrics containing metallic component in the threads. The system has advantages but not without a certain shortcoming. Adapting it for specific tasks should lead to more effective usage, including yet unused properties of the UWB signals.

  14. Study of magnetic thin films by polarized neutron reflectivity. Off-specular diffusion on periodical structures

    International Nuclear Information System (INIS)

    Ott, F.

    1998-01-01

    Theoretical (Zeeman energy effects) and experimental (beam polarisation problems) progress have been made in the understanding of polarized neutron reflectivity with polarisation analysis. It has been shown that modelization and numerical simulations makes it possible to avoid to have to systematically measure a full set of reflectivity curves for each field and temperature condition. It has been possible to determine a magnetic profile as a function of the field in a magnetic bilayer system by using only a few points in the reciprocal space. This technique allows to considerable reduce the experiment time. In single nickel layer systems, we have shown that it is possible to induce magnetic rotation inhomogeneities when these systems are subjects to deformation strains. The effect are related to magneto-elastic constants gradients. In trilayer systems, with a ME constant modulation, we have been able to induce large magnetic rotation gradients. A new magneto-optic technique to measure the magnetization direction without rotating the magnetic field has been developed. The field of neutron reflectivity has been extended to off-specular studies. It has been possible to account quantitatively of the off-specular diffusion on 2-D model systems (prepared by optical lithography). This new technique should make it possible in the future to determine magnetic structures with a in-depth as well as lateral resolution. (author)

  15. Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

    Science.gov (United States)

    Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

    2012-12-01

    The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

  16. Polarization-selective infrared bandpass filter based on a two-layer subwavelength metallic grating

    Science.gov (United States)

    Hohne, Andrew J.; Moon, Benjamin; Baumbauer, Carol L.; Gray, Tristan; Dilts, James; Shaw, Joseph A.; Dickensheets, David L.; Nakagawa, Wataru

    2017-08-01

    We present the design, fabrication, and characterization of a polarization-selective infrared bandpass filter based on a two-layer subwavelength metallic grating for use in polarimetric imaging. Gold nanowires were deposited via physical vapor deposition (PVD) onto a silicon surface relief grating that was patterned using electron beam lithography (EBL) and fabricated using standard silicon processing techniques. Optical characterization with a broad-spectrum tungsten halogen light source and a grating spectrometer showed normalized peak TM transmission of 53% with a full-width at half-maximum (FWHM) of 122 nm, which was consistent with rigorous coupled-wave analysis (RCWA) simulations. Simulation results suggested that device operation relied on suppression of the TM transmission caused by surface plasmon polariton (SPP) excitation at the gold-silicon interface and an increase in TM transmission caused by a Fabry-Perot (FP) resonance in the cavity between the gratings. TE rejection occurred at the initial air/gold interface. We also present simulation results of an improved design based on a two-dielectric grating where two different SPP resonances allowed us to improve the shape of the passband by suppressing the side lobes. This newer design resulted in improved side-band performance and increased peak TM transmission.

  17. Effects of Linear-Polarized Near-Infrared Light Irradiation on Chronic Pain

    Directory of Open Access Journals (Sweden)

    Dong Huang

    2012-01-01

    Full Text Available In order to study the efficacy of linear-polarized near-infrared light irradiation (LPNIR on relieving chronic pain in conjunction with nerve block (NB or local block (LB, a 3-week prospective, randomized, double-blind, controlled study was conducted to evaluate the pre- and post-therapy pain intensity. Visual analogue scales (VASs were measured in all patients before and 6 months after therapy visiting the pain clinic during the period of August 2007 to January 2008. A total of 52 patients with either shoulder periarthritis or myofascial pain syndrome or lateral epicondylitis were randomly assigned into two groups by drawing lots. Patients in Group I were treated with NB or LB plus LPNIR; Group II patients, for their part, were treated with the same procedures as in Group I, but not using LPNIR. In both groups, the pain intensity (VAS score decreased significantly immediately after therapy as compared to therapy. There was a significant difference between the test and control groups immediately after therapy (P<0.05, while no effect 6 months later. No side effects were observed. It is concluded that LPNIR is an effective and safe modality to treat various chronic pains, which has synergic effects with NB or LB.

  18. Determination of soil content in chlordecone (organochlorine pesticide) using near infrared reflectance spectroscopy (NIRS)

    Energy Technology Data Exchange (ETDEWEB)

    Brunet, Didier, E-mail: didier.brunet@ird.f [IRD - Institut de Recherche pour le Developpement, UMR Eco and Sols (Ecologie Fonctionnelle et Biogeochimie des Sols), Montpellier SupAgro, Batiment 12, 2 place Viala, 34060 Montpellier Cedex 1 (France); Woignier, Thierry [IRD, UMR Eco and Sols, PRAM (Pole de Recherche Agronomique de la Martinique), BP 213, Petit Morne, 97232 Le Lamentin, Martinique (French West Indies) (France); CNRS - Centre National de la Recherche Scientifique, Universite Montpellier 2, place Eugene Bataillon, 34095 Montpellier Cedex 5 (France); Lesueur-Jannoyer, Magalie; Achard, Raphael [CIRAD (Centre de Cooperation Internationale en Recherche Agronomique pour le Developpement), PRAM, BP 213, Petit Morne, 97232 Le Lamentin, Martinique (French West Indies) (France); Rangon, Luc [IRD, UMR Eco and Sols, PRAM (Pole de Recherche Agronomique de la Martinique), BP 213, Petit Morne, 97232 Le Lamentin, Martinique (French West Indies) (France); Barthes, Bernard G. [IRD - Institut de Recherche pour le Developpement, UMR Eco and Sols (Ecologie Fonctionnelle et Biogeochimie des Sols), Montpellier SupAgro, Batiment 12, 2 place Viala, 34060 Montpellier Cedex 1 (France)

    2009-11-15

    Chlordecone is a toxic organochlorine insecticide that was used in banana plantations until 1993 in the French West Indies. This study aimed at assessing the potential of near infrared reflectance spectroscopy (NIRS) for determining chlordecone content in Andosols, Nitisols and Ferralsols from Martinique. Using partial least square regression, chlordecone content conventionally determined through gas chromatography-mass spectrometry could be correctly predicted by NIRS (Q{sup 2} = 0.75, R{sup 2} = 0.82 for the total set), especially for samples with chlordecone content <12 mg kg{sup -1} or when the sample set was rather homogeneous (Q{sup 2} = 0.91, R{sup 2} = 0.82 for the Andosols). Conventional measures and NIRS predictions were poorly correlated for chlordecone content >12 mg kg{sup -1}, nevertheless ca. 80% samples were correctly predicted when the set was divided into three or four classes of chlordecone content. Thus NIRS could be considered a time- and cost-effective method for characterising soil contamination by chlordecone. - Soil content in chlordecone, an organochlorine insecticide, can be determined time- and cost-effectively using near infrared reflectance spectroscopy (NIRS).

  19. Hemispherical Reflectance and Emittance Properties of Carbon Nanotubes Coatings at Far-Infrared Wavelengths

    Science.gov (United States)

    Quijada, Manuel A.; Hagopian, John G.; Getty, Stephanie; Kinzer, Raymond (Robin) E., Jr.; Wollack, Edward

    2011-01-01

    Recent visible wavelength observations of Multiwalled Carbon Nanotubes (MWCNT) coatings have revealed that they represent the blackest materials known in nature with a Total Hemispherical Reflectance (THR) less than .25%. This makes them as exceptionally good absorbers, with the potential to provide order-of-magnitude improvement in stray-light suppression over current black surface treatments when used in an optical system. Here we extend the characterization of this class of materials into the infrared spectral region to further evaluate their potential for use on instrument baffles for stray-light suppression and to manage spacecraft thermal properties to dissipate heat through radiant heat transfer process. These characterizations will include the wavelength-dependent Total Hemispherical Reflectance properties in the mid-IR and far-infrared spectral regions (2-100 micrometers). Determination of the temperature-dependent emittance will be investigated in the temperature range of 20 to 300 K. These results will be compared against other more conventional black coatings such as Acktar Fractal Black or Z-306 coatings among others.

  20. Combination of infrared thermography and reflectance spectroscopy for precise classification of hair follicle stage

    Science.gov (United States)

    Wang, Jianru; Guan, Yue; Liu, Caihua; Zhu, Dan

    2015-03-01

    Hair follicles enjoy continual cycle of anagen, catagen and telogen all life. They not only provide a unique opportunity to study the physiological mechanism of organ regeneration, but also benefit to guide the treatment of organ repair in regenerative medicine. Usually, the histological examination as a gold standard has been applied to determine the stage of hair follicle cycle, but noninvasive classification of hair cycle in vivo remains unsolved. In this study, the thermal infrared imager was applied to measure the temperature change of mouse dorsal skin with hair follicle cycle, and the change of diffuse reflectance was monitored by the optical fiber spectrometer. Histological examination was used to verify the hair follicle stages. The results indicated that the skin temperature increased at the beginning of anagen. After having stayed a high value for several days, the temperature began to decrease. At the same time, the skin diffuse reflectance decreased until the end of this period. Then the temperature increased gradually after slightly decreased when the hair follicle entered into catagen stage, and the diffuse reflectance increased at this time. In telogen, both the temperature and the diffuse reflectance went back to a steady state all the time. Sub-stages of hair follicle cycle could be distinguished based on the joint curves. This study provided a new method to noninvasively recognize the hair follicle stage, and should be valuable for the basic and therapeutic investigations on hair regeneration.

  1. Polarization-dependent in-line quasi-Michelson interferometer based on PM-PCF reflection.

    Science.gov (United States)

    Du, Yanying; Qiao, Xueguang; Rong, Qiangzhou; Zhang, Jing; Feng, Dingyi; Wang, Ruohui; Sun, Hao; Hu, Manli; Feng, Zhongyao

    2013-05-20

    An in-line fiber quasi-Michelson interferometer (IFQMI) working on reflection is proposed and experimentally demonstrated. The sensing head is fabricated by splicing a section of polarization-maintaining photonic crystal fiber (PM-PCF) with a lead-in single mode fiber (SMF). Some cladding modes are excited into the PM-PCF via the mismatch-core splicing interface between PM-PCF and SMF. Besides, two orthogonal polarized-modes are formed due to the inherent multiholes cladding structure of the PM-PCF. A well-defined interference pattern is obtained as the result of cladding-orthogonal modes interference. The IFQMI with 20 cm long PM-PCF is proposed for strain and torsion measurements. A strain sensitivity of -1.3 pm/με and a torsion sensitivity of -19.17 pm/deg are obtained, respectively. The proposed device with 10 cm long PM-PCF exhibits a considered temperature sensitivity of 9.9 pm/°C. The IFQMI has a compact structure and small size, making it a good candidate for multiparameter measurements.

  2. Classification of the waxy condition of durum wheat by near infrared reflectance spectroscopy using wavelets and a genetic algorithm

    Science.gov (United States)

    Near infrared (NIR) reflectance spectroscopy has been applied to the problem of differentiating four genotypes of durum wheat: ‘waxy’, wx-A1 null, wx-B1 null and wild type. The test data consisted of 95 NIR reflectance spectra of wheat samples obtained from a USDA-ARS wheat breeding program. A two...

  3. CO Adsorption and Oxidation at the Catalyst-Water Interface: An Investigation by Attenuated Total Reflection Infrared Spectroscopy.

    NARCIS (Netherlands)

    Ebbesen, S.D.; Mojet, Barbara; Lefferts, Leonardus

    2006-01-01

    Adsorption of carbon monoxide and oxidation of preadsorbed carbon monoxide from gas and aqueous phases were studied on a platinum catalyst deposited on a ZnSe internal reflection element (IRE) using attenuated total reflection infrared (ATR-IR) spectroscopy. The results of this study convincingly

  4. Polarized photomodulated reflectivity and photoluminescence studies of ordered InGaP2 under pressure

    International Nuclear Information System (INIS)

    Thomas, R.J.; Chandrasekhar, H.R.; Chandrasekhar, M.; Jones, E.D.; Schneider, R.P. Jr.

    1994-01-01

    Spontaneous ordering of ternary alloys grown on misoriented substrates has been of recent interest. Ordering induced band gap reduction, and valence band splittings exhibiting novel polarization properties have been investigated by theory and experiment. This paper discusses polarized photomodulated reflectivity (PR) and photoluminescence (PL) studies of MOCVD grown InGaP 2 epilayers lattice-matched to a GaAs substrate. These structures were grown on a (001) face with a niisorientation of two degrees along . The high degree of ordering has enabled us to accurately measure the crystal field splitting and additional structure not reported in the PR spectra. For the electric field E parallel to [110] two features in the PR spectra are seen; for E parallel[110], however, additional features are observed. Comparison with spectra of disordered samples of the same alloy composition has enabled a determination of the band gap reduction due to ordering. Linewidths of the PR peaks are approximately 5--10 meV which has enabled us to study them in detail as a function of hydrostatic pressure at cryogenic temperatures. The pressure dependence is slightly sublinear with the first order term of 8--9 meV/kbar for pressures well below the l-X crossover. Also observed is the indirect level crossing which occurs under pressure at about 40-kbar. A comparison of PR lineshapes at 1-bar is also presented at several commonly used experimental temperatures. Data indicate a substantial change in PR lineshapes, showing that interpretation of reflectivity data for these samples must be handled carefully

  5. Flexible Holographic Fabrication of 3D Photonic Crystal Templates with Polarization Control through a 3D Printed Reflective Optical Element

    Directory of Open Access Journals (Sweden)

    David Lowell

    2016-07-01

    Full Text Available In this paper, we have systematically studied the holographic fabrication of three-dimensional (3D structures using a single 3D printed reflective optical element (ROE, taking advantage of the ease of design and 3D printing of the ROE. The reflective surface was setup at non-Brewster angles to reflect both s- and p-polarized beams for the interference. The wide selection of reflective surface materials and interference angles allow control of the ratio of s- and p-polarizations, and intensity ratio of side-beam to central beam for interference lithography. Photonic bandgap simulations have also indicated that both s and p-polarized waves are sometimes needed in the reflected side beams for maximum photonic bandgap size and certain filling fractions of dielectric inside the photonic crystals. The flexibility of single ROE and single exposure based holographic fabrication of 3D structures was demonstrated with reflective surfaces of ROEs at non-Brewster angles, highlighting the capability of the ROE technique of producing umbrella configurations of side beams with arbitrary angles and polarizations and paving the way for the rapid throughput of various photonic crystal templates.

  6. Polarized Raman and Infrared Spectroscopy and ab Initio Calculation of Palmitic and Stearic Acids in the Bm and C Forms.

    Science.gov (United States)

    L da Silva, L F; Andrade-Filho, T; Freire, P T C; Filho, J Mendes; da Silva Filho, J G; Saraiva, G D; Moreira, S G C; de Sousa, F F

    2017-06-29

    A complete experimental study on the vibrational properties of palmitic and stearic acids crystallized in the B m and C forms, both belonging to the monoclinic system with the P2 1 /a (C 2h 5 ) space group, through polarized Raman and infrared spectroscopy, is reported in this paper. Density functional theory calculations were also performed to assign the normal modes and to help in the interpretation of the experimental data. The different polarizations were compared and their influence on the spectral profiles, in both the lattice and the internal mode regions, was discussed. In general, the Raman and infrared spectra exhibit accentuated differences among the polymorphic forms, which are associated with the different molecular modifications, defined as gauche and all-trans conformations. Insights about interaction among different groups are also furnished.

  7. Infrared renormalons and the relations between the Gross-Llewellyn Smith and the Bjorken polarized and unpolarized sum rules

    International Nuclear Information System (INIS)

    Kataev, A.L.

    2005-01-01

    It is demonstrated that the infrared renormalon calculus indicates that the QCD theoretical expressions for the Gross-Llewellyn Smith sum rule and for the Bjorken polarized and unpolarized ones contain an identical negative twist-4 1/Q 2 correction. This observation is supported by the consideration of the results of calculations of the corresponding twist-4 matrix elements. Together with the indication of the similarity of perturbative QCD contributions to these three sum rules, this observation leads to simple new theoretical relations between the Gross-Llewellyn Smith and Bjorken polarized and unpolarized sum rules in the energy region Q 2 ≥ 1 GeV 2 . The validity of this relation is checked using concrete experimental data for the Gross-Llewellyn Smith and Bjorken polarized sum rules [ru

  8. NOAA JPSS Visible Infrared Imaging Radiometer Suite (VIIRS) Polar Winds from NDE

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains the Level 3 Polar Winds Northern and Southern Hemisphere datasets. The Level 3 Polar Winds data from VIIRS for the Arctic and Antarctic from 65...

  9. Potential applications of near infrared auto-fluorescence spectral polarized imaging for assessment of food quality

    Science.gov (United States)

    Zhou, Kenneth J.; Chen, Jun

    2016-03-01

    The current growing of food industry for low production costs and high efficiency needs for maintenance of high-quality standards and assurance of food safety while avoiding liability issues. Quality and safety of food depend on physical (texture, color, tenderness etc.), chemical (fat content, moisture, protein content, pH, etc.), and biological (total bacterial count etc.) features. There is a need for a rapid (less than a few minutes) and accurate detection system in order to optimize quality and assure safety of food. However, the fluorescence ranges for known fluorophores are limited to ultraviolet emission bands, which are not in the tissue near infrared (NIR) "optical window". Biological tissues excited by far-red or NIR light would exhibit strong emission in spectral range of 650-1,100 nm although no characteristic peaks show the emission from which known fluorophores. The characteristics of the auto-fluorescence emission of different types of tissues were found to be different between different tissue components such as fat, high quality muscle food. In this paper, NIR auto-fluorescence emission from different types of muscle food and fat was measured. The differences of fluorescence intensities of the different types of muscle food and fat emissions were observed. These can be explained by the change of the microscopic structure of physical, chemical, and biological features in meat. The difference of emission intensities of fat and lean meat tissues was applied to monitor food quality and safety using spectral polarized imaging, which can be detect deep depth fat under the muscle food up to several centimeter.

  10. Infrared

    Science.gov (United States)

    Vollmer, M.

    2013-11-01

    techniques such as attenuated total reflectance [6]. The two final papers deal with what seem to be wholly different scientific fields [7, 8]. One paper describes SOFIA, an aeroplane-based astronomical observatory covering the whole IR range [7], while the other represents a small review of the quite new topic of terahertz physics at the upper end of the IR spectral range, from around 30 µm to 3 mm wavelength, and its many applications in science and industry [8]. Although artificially separated, all these fields use similar kinds of detectors, similar kinds of IR sources and similar technologies, while the instruments use the same physical principles. We are convinced that the field of infrared physics will develop over the next decade in the same dynamic way as during the last, and this special issue may serve as starting point for regular submissions on the topic. At any rate, it shines a light on this fascinating and many-faceted subject, which started more than 200 years ago. References [1] Mangold K, Shaw J A and Vollmer M 2013 The physics of near-infrared photography Eur. J. Phys. 34 S51-71 [2] Vollmer M and Möllmann K-P 2013 Characterization of IR cameras in student labs Eur. J. Phys. 34 S73-90 [3] Ibarra-Castanedo C, Tarpani J R and Maldague X P V 2013 Nondestructive testing with thermography Eur. J. Phys. 34 S91-109 [4] Shaw J A and Nugent P W 2013 Physics principles in radiometric infrared imaging of clouds in the atmosphere Eur. J. Phys. 34 S111-21 [5] Möllmann K-P and Vollmer M 2013 Fourier transform infrared spectroscopy in physics laboratory courses Eur. J. Phys. 34 S123-37 [6] Heise H M, Fritzsche J, Tkatsch H, Waag F, Karch K, Henze K, Delbeck S and Budde J 2013 Recent advances in mid- and near-infrared spectroscopy with applications for research and teaching, focusing on petrochemistry and biotechnology relevant products Eur. J. Phys. 34 S139-59 [7] Krabbe A, Mehlert D, Röser H-P and Scorza C 2013 SOFIA, an airborne observatory for infrared astronomy

  11. [Testing of germination rate of hybrid rice seeds based on near-infrared reflectance spectroscopy].

    Science.gov (United States)

    Li, Yi-nian; Jiang, Dan; Liu, Ying-ying; Ding, Wei-min; Ding, Qi-shuo; Zha, Liang-yu

    2014-06-01

    Germination rate of rice seeds was measured according to technical stipulation of germination testing for agricultural crop seeds at present. There existed many faults for this technical stipulation such as long experimental period, more costing and higher professional requirement. A rapid and non-invasive method was put forward to measure the germination rate of hybrid rice seeds based on near-infrared reflectance spectroscopy. Two varieties of hybrid rice seeds were aged artificially at temperature 45 degrees C and humidity 100% condition for 0, 24, 48, 72, 96, 120 and 144 h. Spectral data of 280 samples for 2 varieties of hybrid rice seeds with different aging time were acquired individually by near-infrared spectra analyzer. Spectral data of 280 samples for 2 varieties of hybrid rice seeds were randomly divided into calibration set (168 samples) and prediction set (112 samples). Gormination rate of rice seed with different aging time was tested. Regression model was established by using partial least squares (PLS). The effect of the different spectral bands on the accuracy of models was analyzed and the effect of the different spectral preprocessing methods on the accuracy of models was also compared. Optimal model was achieved under the whole bands and by using standardization and orthogonal signal correction (OSC) preprocessing algorithms with CM2000 software for spectral data of 2 varieties of hybrid rice seeds, the coefficient of determination of the calibration set (Rc) and that of the prediction set (Rp) were 0.965 and 0.931 individually, standard error of calibration set (SEC) and that of prediction set (SEP) were 1.929 and 2.899 respectively. Relative error between tested value and predicted value for prediction set of rice seeds is below 4.2%. The experimental results show that it is feasible that rice germination rate is detected rapidly and nondestructively by using the near-infrared spectroscopy analysis technology.

  12. Diffuse reflectance near infrared-chemometric methods development and validation of amoxicillin capsule formulations

    Directory of Open Access Journals (Sweden)

    Ahmed Nawaz Khan

    2016-01-01

    Full Text Available Objective: The aim of present study was to establish near infrared-chemometric methods that could be effectively used for quality profiling through identification and quantification of amoxicillin (AMOX in formulated capsule which were similar to commercial products. In order to evaluate a large number of market products easily and quickly, these methods were modeled. Materials and Methods: Thermo Scientific Antaris II near infrared analyzer with TQ Analyst Chemometric Software were used for the development and validation of the identification and quantification models. Several AMOX formulations were composed with four excipients microcrystalline cellulose, magnesium stearate, croscarmellose sodium and colloidal silicon dioxide. Development includes quadratic mixture formulation design, near infrared spectrum acquisition, spectral pretreatment and outlier detection. According to prescribed guidelines by International Conference on Harmonization (ICH and European Medicine Agency (EMA developed methods were validated in terms of specificity, accuracy, precision, linearity, and robustness. Results: On diffuse reflectance mode, an identification model based on discriminant analysis was successfully processed with 76 formulations; and same samples were also used for quantitative analysis using partial least square algorithm with four latent variables and 0.9937 correlation of coefficient followed by 2.17% root mean square error of calibration (RMSEC, 2.38% root mean square error of prediction (RMSEP, 2.43% root mean square error of cross-validation (RMSECV. Conclusion: Proposed model established a good relationship between the spectral information and AMOX identity as well as content. Resulted values show the performance of the proposed models which offers alternate choice for AMOX capsule evaluation, relative to that of well-established high-performance liquid chromatography method. Ultimately three commercial products were successfully evaluated

  13. Cluster analysis of near-infrared reflectance spectra of asteroid Itokawa

    Science.gov (United States)

    Inasawa, Tomoki; Kitazato, Kohei; Hirata, Naru; Demura, Hirohide

    2017-10-01

    The data from the analysis of samples returned by Hayabusa spacecraft have provided conclusive evidence regarding mineral composition and space weathering of near-Earth S-type asteroid Itokawa. To apply these information to the Hayabusa remote sensing data towards revealing the formation history of Itokawa, we made a more precise near-infrared spectral map of Itokawa than the previous ones from the Hayabusa NIRS data and performed its cluster analysis. The NIRS instrument had acquired more than 80,000 spatially resolved 0.75 to 2.20 microns reflectance spectra from the surface of Itokawa. We used PCA and k-means clustering for cluster analysis and found that at least three different types of surface areas would exist on Itokawa.

  14. Correcting attenuated total reflection-fourier transform infrared spectra for water vapor and carbon dioxide

    DEFF Research Database (Denmark)

    Bruun, Susanne Wrang; Kohler, Achim; Adt, Isabelle

    2006-01-01

    Fourier transform infrared (FT-IR) spectroscopy is a valuable technique for characterization of biological samples, providing a detailed fingerprint of the major chemical constituents. However, water vapor and CO(2) in the beam path often cause interferences in the spectra, which can hamper...... the data analysis and interpretation of results. In this paper we present a new method for removal of the spectral contributions due to atmospheric water and CO(2) from attenuated total reflection (ATR)-FT-IR spectra. In the IR spectrum, four separate wavenumber regions were defined, each containing...... of the growing yeast biofilm, the gas correction revealed otherwise hidden variations of relevance for modeling the growth dynamics. As the presented method improved the interpretation of the principle component analysis (PCA) models, it has proven to be a valuable tool for filtering atmospheric variation in ATR...

  15. Recent Developments in Solid-Phase Extraction for Near and Attenuated Total Reflection Infrared Spectroscopic Analysis

    Directory of Open Access Journals (Sweden)

    Christian W. Huck

    2016-05-01

    Full Text Available A review with more than 100 references on the principles and recent developments in the solid-phase extraction (SPE prior and for in situ near and attenuated total reflection (ATR infrared spectroscopic analysis is presented. New materials, chromatographic modalities, experimental setups and configurations are described. Their advantages for fast sample preparation for distinct classes of compounds containing different functional groups in order to enhance selectivity and sensitivity are discussed and compared. This is the first review highlighting both the fundamentals of SPE, near and ATR spectroscopy with a view to real sample applicability and routine analysis. Most of real sample analyses examples are found in environmental research, followed by food- and bioanalysis. In this contribution a comprehensive overview of the most potent SPE-NIR and SPE-ATR approaches is summarized and provided.

  16. [Use of visible and near infrared reflectance spectroscopy to identify the cashmere and wool].

    Science.gov (United States)

    Liu, Xin-Ru; Zhang, Li-Ping; Wang, Jian-Fu; Wu, Jian-Ping; Wang, Xin-Rong

    2013-08-01

    The wool and cashmere samples (n = 130) from different areas of Gansu province were identified by visible and near-infrared reflectance spectroscopy (Vis/NIRs). The result shows that principal component-mahalanobis distance pattern can identify the wool and cashmere, and the boundary between two categories was clear; The calibration set samples were used to establish calibration qualitative model using PCR combined with the best pretreatment of the spectra and math, including multivariate scattering correction (MSC), first derivative, eight for the best principal component factor, one for uncertainty factor, this calibration model of the predicted was the best, and the result of the external validation was correct completely. Results from this experiment indicate that Vis/NIRs can be utilized to identify the wool and cashmere.

  17. Infrared reflectivity of Tl1.94Mn2O6.96

    Science.gov (United States)

    Massa, Néstor E.; Alonso, José Antonio; Martínez-Lope, María Jesús; Casais, María Teresa; Salva, Horacio

    1999-09-01

    We report temperature dependent infrared reflectivity of Tl1.94Mn2O6.96 in the 30 to 10 000 cm-1 frequency range. We found that between room temperature and the Curie temperature (TC≅TIM) in which the insulator-ferromagnetic metal phase transition takes place, Tl1.94Mn2O6.96 behaves as an insulator with antiresonances near the longitudinal optical modes indicating distinctive electron-phonon interactions. Below TC the band envelope assigned to breathing oxygen phonons undergoes broadening and frequency hardening and the sample becomes a poor metal oxide in which small trapped polaron electrons are released with decreasing temperature. We support this conclusion pointing to the agreement between the experimental and the calculated; using Reik's small polaron theory, optical conductivity strongly suggests that conductivity be achieved by phonon assisted electron hopping.

  18. Preliminary method for direct quantification of colistin methanesulfonate by attenuated total reflectance Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Niece, Krista L; Akers, Kevin S

    2015-09-01

    Colistin use has increased in response to the advent of infections caused by multidrug-resistant organisms. It is administered parenterally as an inactive prodrug, colistin methanesulfonate (CMS). Various formulations of CMS and labeling conventions can lead to confusion about colistin dosing, and questions remain about the pharmacokinetics of CMS. Since CMS does not have strong UV absorbance, current methods employ a laborious process of chemical conversion to colistin followed by precolumn derivatization to detect formed colistin by high-performance liquid chromatography. Here, we report a method for direct quantification of colistin methanesulfonate by attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR). Copyright © 2015, American Society for Microbiology. All Rights Reserved.

  19. Detection of citrus Huanglongbing by Fourier transform infrared-attenuated total reflection spectroscopy.

    Science.gov (United States)

    Hawkins, Samantha A; Park, Bosoon; Poole, Gavin H; Gottwald, Timothy; Windham, William R; Lawrence, Kurt C

    2010-01-01

    Citrus Huanglongbing (HLB, also known as citrus greening disease) was discovered in Florida in 2005 and is spreading rapidly amongst the citrus growing regions of the state. Detection via visual symptoms of the disease is not a long-term viable option. New techniques are being developed to test for the disease in its earlier presymptomatic stages. Fourier transform infrared-attenuated total reflection (FT-IR-ATR) spectroscopy is a candidate for rapid, inexpensive, early detection of the disease. The mid-infrared region of the spectrum reveals dramatic changes that take place in the infected leaves when compared to healthy non-infected leaves. The carbohydrates that give rise to peaks in the 900-1180 cm(-1) range are reliable in distinguishing leaves from infected plants versus non-infected plants. A model based on chemometrics was developed using the spectra from 179 plants of known disease status. This model then correctly predicted the status of >95% of the plants tested.

  20. Attenuated total reflectance Fourier-transform infrared spectroscopy of carboxylic acids adsorbed onto mineral surfaces

    Science.gov (United States)

    Kubicki, J. D.; Schroeter, L. M.; Itoh, M. J.; Nguyen, B. N.; Apitz, S. E.

    1999-09-01

    A suite of naturally-occurring carboxylic acids (acetic, oxalic, citric, benzoic, salicylic and phthalic) and their corresponding sodium salts were adsorbed onto a set of common mineral substrates (quartz, albite, illite, kaolinite and montmorillonite) in batch slurry experiments. Solution pH's of approximately 3 and 6 were used to examine the effects of pH on sorption mechanisms. Attenuated total reflectance Fourier-transform infrared (ATR FTIR) spectroscopy was employed to obtain vibrational frequencies of the organic ligands on the mineral surfaces and in solution. UV/visible spectroscopy on supernatant solutions was also employed to confirm that adsorption from solution had taken place for benzoic, salicylic and phthalic acids. Molecular orbital calculations were used to model possible surface complexes and interpret the experimental spectra. In general, the tectosilicates, quartz and albite feldspar, did not chemisorb (i.e., strong, inner-sphere adsorption) the carboxylate anions in sufficient amounts to produce infrared spectra of the organics after rinsing in distilled water. The clays (illite, kaolinite and montmorillonite) each exhibited similar ATR FTIR spectra. However, the illite sample used in this study reacted to form strong surface and aqueous complexes with salicylic acid before being treated to remove free Fe-hydroxides. Chemisorption of carboxylic acids onto clays is shown to be limited without the presence of Fe-hydroxides within the clay matrix.

  1. Attenuated total internal reflection Fourier transform infrared spectroscopy: a quantitative approach for kidney stone analysis.

    Science.gov (United States)

    Gulley-Stahl, Heather J; Haas, Jennifer A; Schmidt, Katherine A; Evan, Andrew P; Sommer, André J

    2009-07-01

    The impact of kidney stone disease is significant worldwide, yet methods for quantifying stone components remain limited. A new approach requiring minimal sample preparation for the quantitative analysis of kidney stone components has been investigated utilizing attenuated total internal reflection Fourier transform infrared spectroscopy (ATR-FT-IR). Calcium oxalate monohydrate (COM) and hydroxylapatite (HAP), two of the most common constituents of urinary stones, were used for quantitative analysis. Calibration curves were constructed using integrated band intensities of four infrared absorptions versus concentration (weight %). The correlation coefficients of the calibration curves range from 0.997 to 0.93. The limits of detection range from 0.07 +/- 0.02% COM/HAP where COM is the analyte and HAP is the matrix, to 0.26 +/- 0.07% HAP/COM where HAP is the analyte and COM is the matrix. This study shows that linear calibration curves can be generated for the quantitative analysis of stone mixtures provided the system is well understood especially with respect to particle size.

  2. Quality Control of Valerianae Radix by Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR) Spectroscopy.

    Science.gov (United States)

    Nikzad-Langerodi, Ramin; Arth, Katharina; Klatte-Asselmeyer, Valerie; Bressler, Sabine; Saukel, Johannes; Reznicek, Gottfried; Dobeš, Christoph

    2017-11-09

    (Acetoxy-)valerenic acid and total essential oil content are important quality attributes of pharmacy grade valerian root (Valerianae radix). Traditional analysis of these quantities is time-consuming and necessitates (harmful) solvents. Here we investigated an application of attenuated total reflection Fourier transform infrared spectroscopy for extractionless analysis of these quality attributes on a representative sample comprising 260 wild-crafted individuals covering the Central European taxonomic diversity of the Valeriana officinalis L. s. l. species aggregate with its three major ploidy cytotypes (i.e., di-, tetra- and octoploid). Calibration models were built by orthogonal partial least squares regression for quantitative analysis of (acetoxy-)valerenic acid and total essential oil content. For the latter, we propose a simplistic protocol involving apolar extraction followed by gas chromatography as a reference method for multivariate calibration in order to handle the analysis of samples taken from individual plants. We found good predictive ability of chemometric models for quantification of valerenic acid, acetoxyvalerenic acid, total sesquiterpenoid acid, and essential oil content with a root mean squared error of cross-validation of 0.064, 0.043, and 0.09 and root mean squared error of prediction of 0.066, 0.057, and 0.09 (% content), respectively. Orthogonal partial least squares discriminant analysis revealed good discriminability between the most productive phenotype (i.e., the octoploid cytotype) in terms of sesquiterpenoid acids, and the less productive ones (i.e., di- and tetraploid). All in all, our results demonstrate the application of attenuated total reflection Fourier transform infrared spectroscopy for rapid, extractionless estimation of the most important quality attributes of valerian root and minimally invasive identification of the most productive phenotype in terms of sesquiterpenoid acids. Georg Thieme Verlag KG Stuttgart · New

  3. Identification of Uranium Minerals in Natural U-Bearing Rocks Using Infrared Reflectance Spectroscopy.

    Science.gov (United States)

    Beiswenger, Toya N; Gallagher, Neal B; Myers, Tanya L; Szecsody, James E; Tonkyn, Russell G; Su, Yin-Fong; Sweet, Lucas E; Lewallen, Tricia A; Johnson, Timothy J

    2018-02-01

    The identification of minerals, including uranium-bearing species, is often a labor-intensive process using X-ray diffraction (XRD), fluorescence, or other solid-phase or wet chemical techniques. While handheld XRD and fluorescence instruments can aid in field applications, handheld infrared (IR) reflectance spectrometers can now also be used in industrial or field environments, with rapid, nondestructive identification possible via analysis of the solid's reflectance spectrum providing information not found in other techniques. In this paper, we report the use of laboratory methods that measure the IR hemispherical reflectance of solids using an integrating sphere and have applied it to the identification of mineral mixtures (i.e., rocks), with widely varying percentages of uranium mineral content. We then apply classical least squares (CLS) and multivariate curve resolution (MCR) methods to better discriminate the minerals (along with two pure uranium chemicals U 3 O 8 and UO 2 ) against many common natural and anthropogenic background materials (e.g., silica sand, asphalt, calcite, K-feldspar) with good success. Ground truth as to mineral content was attained primarily by XRD. Identification is facile and specific, both for samples that are pure or are partially composed of uranium (e.g., boltwoodite, tyuyamunite, etc.) or non-uranium minerals. The characteristic IR bands generate unique (or class-specific) bands, typically arising from similar chemical moieties or functional groups in the minerals: uranyls, phosphates, silicates, etc. In some cases, the chemical groups that provide spectral discrimination in the longwave IR reflectance by generating upward-going (reststrahlen) bands can provide discrimination in the midwave and shortwave IR via downward-going absorption features, i.e., weaker overtone or combination bands arising from the same chemical moieties.

  4. Far-infrared reflection-absorption spectroscopy of amorphous and polycrystalline gallium arsenide films

    International Nuclear Information System (INIS)

    Gregory, J.R.

    1992-01-01

    We have reported far-infrared reflection absorption spectra (30-320CM -1 ) at 30 and 310K for nine films of non-stoichiometric GaAs. The FIRRAS measurements were performed using the grazing incidence FIR double-modulation spectroscopy technique first described by DaCosta and Coleman. The films were fabricated by molecular beam deposition on metallized substrates for two As/Ga molecular beam flux ratios. The films were characterized by depth profilometry, IRAS, XRD, and x-ray microprobe analysis. Film thicknesses ranged from 800 to 5800 angstrom and compositions were 45-50% As for a MB flux ratio of 0.29 and 60-70% As for a ratio of 1.12. FIRRAS measurements were made and characterizations performed for as-deposited films and for 5 hour anneals at 473, 573, 673 and 723 degrees C. Vibrational spectra of the crystallized films were interpreted in terms of the exact reflectivity of a thin dielectric film on a conducting substrate, using a classical Lorentzian dielectric function for the response of the film. Resonances appearing in the open-quote forbidden close-quote region between the TO and LO frequencies were modelled with an effective medium approximation and are interpreted as arising from small-scale surface roughness. The behavior of the amorphous film spectra were examined within two models. The effective force constant model describes the variation of the reflection-absorption maxima with measured crystallite size in terms of the effective vibration frequency of 1-D atomic chains having force constants distributed according to the parameters of the crystalline-to-amorphous relaxation length and the crystalline to amorphous force constant ratio. The dielectric function continuum model uses the relaxation of the crystal momentum selection rule to calculate the reflection-absorption spectrum based on a dielectric function in which the oscillator strength is the normalized product of a constant dipole strength and the smoothed vibrational density of states

  5. Reflectance and Polarization Characteristics of Various Vegetation Types: an Advanced Experimental Approach using the FIGIFIGO Goniospectrometer

    Science.gov (United States)

    Gritsevich, M.; Peltoniemi, J.; Zubko, N.; Pisek, J.

    2016-12-01

    To reduce data acquired by Earth Observation projects and for collecting more accurate knowledge on the Earth, universe, and environment one needs to provide a set of reliable references carefully gathered by measuring various known, well characterized targets. We present an overview of the Finnish Geodetic Institute's field goniospectrometer, FIGIFIGO, and highlight its capabilities for spectropolarimetric measurements of various samples, both under actual field conditions and in the laboratory. The design concept of this custom made instrument has proven to have a number of advantages, such as a well designed, user friendly interface, a high level of automation, and an excellent adaptability to a wide range of weather conditions during field measurements. The instrument communicates via a control computer which has a simple user-friendly interface. It is battery powered and very portable, making it feasible to transport it by plane, car, boat, or sledge. The system includes a sky camera to detect the orientation of the goniometer and a pyranometer to monitor the synchronous illumination conditions. The instrument's mirror can be finely adjusted to apply small spatial corrections to the optical chain. The foreoptics is connected to an ASD FieldSpec Pro FR 350-2500 nm spectroradiometer by an optical fiber. A calcite Glan-Thompson prism is used as a polarizer, covering the full spectral range with better than 1% accuracy.FIGIFIGO has been used to measure the reflectance properties of hundreds of different targets, including various vegetation types. In particular, it has been shown that directional and polarization signals vary largely between different species, and provide information about the leaf surface and orientation. The measurement data are stored in the FGI's Reflectance Library and new specific measurements are made upon request. The potential use of the results from these measurements are diverse; including their use as ground truth references for Earth

  6. Modifying Earth's Insolation with Aerosols: Reflectance and Polarization Properties of Candidate Particulate Materials

    Science.gov (United States)

    Nelson, R. M.; Boryta, M. D.; Hapke, B. W.; Manatt, K. S.; Shkuratov, Y.; Vandervoort, K.; Vides, C.; Quinones, J.

    2017-12-01

    We report reflectance phase curves of selected materials, including several that, if distributed as particulate aerosols, might regulate solar insolation and hence reduce Earth's surface temperature. (See e.g. Teller et al., 1997). We have identified several materials that have phase functions that are remarkably backscattering at very small phase angles (Nelson et al., 2017). When these materials are of appropriately small particle size and in the form of dispersed discrete random media, they are highly reflective at ultraviolet and visual wavelengths. Particles of less than 0.5 microns in diameter are transparent in the infrared. The most promising of these is the mineral halite (NaCl). NaCl and its sister materials exhibit this property due to their simple cubic crystal structure. In crystalline form they are `corner cube' reflectors similar to those on bicycle reflectors used throughout the world, and in arrays deployed by astronauts on the Moon for precise distance determination. As aerosols distributed in relatively small quantities, NaCl might reduce the solar forcing function by several W/m2, the amount estimated by the IPCC to be the anthropogenic contribution to global warming. Furthermore, NaCl is environmentally benign and, as a particulate aerosol, it would have short residence time in the atmosphere. With great trepidation, we suggest potential use in these areas: Temporary regional application to mitigate short-term, life-threatening conditions in areas where extreme temperature events are expected on timescales of days, and Global application for immediate relief during a near-term transition period to an atmosphere that is generally free of anthropogenic greenhouse gas. We offer this as a temporary relief measure and not a solution, somewhat analogous to the application of morphine in a medical situation. This work partially supported by NASA's Cassini Orbiter Program

  7. Assessment of Various Organic Matter Properties by Infrared Reflectance Spectroscopy of Sediments and Filters

    Science.gov (United States)

    Alaoui, G.; Leger, M.; Gagne, J.; Tremblay, L.

    2009-05-01

    The goal of this work was to evaluate the capability of infrared reflectance spectroscopy for a fast quantification of the elemental and molecular compositions of sedimentary and particulate organic matter (OM). A partial least-squares (PLS) regression model was used for analysis and values were compared to those obtained by traditional methods (i.e., elemental, humic and HPLC analyses). PLS tools are readily accessible from software such as GRAMS (Thermo-Fisher) used in spectroscopy. This spectroscopic-chemometric approach has several advantages including its rapidity and use of whole unaltered samples. To predict properties, a set of infrared spectra from representative samples must first be fitted to form a PLS calibration model. In this study, a large set (180) of sediments and particles on GFF filters from the St. Lawrence estuarine system were used. These samples are very heterogenous (e.g., various tributaries, terrigenous vs. marine, events such as landslides and floods) and thus represent a challenging test for PLS prediction. For sediments, the infrared spectra were obtained with a diffuse reflectance, or DRIFT, accessory. Sedimentary carbon, nitrogen, humic substance contents as well as humic substance proportions in OM and N:C ratios were predicted by PLS. The relative root mean square error of prediction (%RMSEP) for these properties were between 5.7% (humin content) and 14.1% (total humic substance yield) using the cross-validation, or leave-one out, approach. The %RMSEP calculated by PLS for carbon content was lower with the PLS model (7.6%) than with an external calibration method (11.7%) (Tremblay and Gagné, 2002, Anal. Chem., 74, 2985). Moreover, the PLS approach does not require the extraction of POM needed in external calibration. Results highlighted the importance of using a PLS calibration set representative of the unknown samples (e.g., same area). For filtered particles, the infrared spectra were obtained using a novel approach based on

  8. Degrees of polarization of reflected light eliciting polarotaxis in dragonflies (Odonata), mayflies (Ephemeroptera) and tabanid flies (Tabanidae).

    Science.gov (United States)

    Kriska, György; Bernáth, Balázs; Farkas, Róbert; Horváth, Gábor

    2009-12-01

    With few exceptions insects whose larvae develop in freshwater possess positive polarotaxis, i.e., are attracted to sources of horizontally polarized light, because they detect water by means of the horizontal polarization of light reflected from the water surface. These insects can be deceived by artificial surfaces (e.g. oil lakes, asphalt roads, black plastic sheets, dark-coloured cars, black gravestones, dark glass surfaces, solar panels) reflecting highly and horizontally polarized light. Apart from the surface characteristics, the extent of such a 'polarized light pollution' depends on the illumination conditions, direction of view, and the threshold p* of polarization sensitivity of a given aquatic insect species. p* means the minimum degree of linear polarization p of reflected light that can elicit positive polarotaxis from a given insect species. Earlier there were no quantitative data on p* in aquatic insects. The aim of this work is to provide such data. Using imaging polarimetry in the red, green and blue parts of the spectrum, in multiple-choice field experiments we measured the threshold p* of ventral polarization sensitivity in mayflies, dragonflies and tabanid flies, the positive polarotaxis of which has been shown earlier. In the blue (450nm) spectral range, for example, we obtained the following thresholds: dragonflies: Enallagma cyathigerum (0%

  9. Moisture assay of an antifungal by near-infrared diffuse reflectance spectroscopy.

    Science.gov (United States)

    Dunko, Adam; Dovletoglou, Angelos

    2002-04-01

    Near-infrared (NIR) diffuse reflectance spectroscopy was employed in the method development and validation of a moisture assay for the novel antifungal caspofungin acetate. Spectra were obtained over the entire spectral region available (950-1650 nm) using an InGaAs photodiode array detector equipped with a diffuse reflectance probe. No sample pre-treatment was required and the analysis time was less than 1 min. Primary reference data were obtained using a Karl Fischer (KF) titration (coulometric, volumetric or both). The investigated range of water content was 2.6-9.9% (w/w) with a standard error of prediction (SEP) of 0.2%. The predictive capabilities of the partial least-squares (PLS) regression calibration model used in the moisture assay were verified using independent test sets. The NIR predicted values of the developed method were equivalent to the reference method sets and the prediction error was equivalent to the reference method error. These results reveal that the predictive model constructed by means of a PLS regression is valid, rugged and could be used to determine moisture levels on-line in caspofungin acetate drug substance.

  10. Simulation of attenuated total reflection infrared absorbance spectra: applications to automotive clear coat forensic analysis.

    Science.gov (United States)

    Lavine, Barry K; Fasasi, Ayuba; Mirjankar, Nikhil; Nishikida, Koichi; Campbell, Jay

    2014-01-01

    Attenuated total reflection (ATR) is a widely used sampling technique in infrared (IR) spectroscopy because minimal sample preparation is required. Since the penetration depth of the ATR analysis beam is quite shallow, the outer layers of a laminate or multilayered paint sample can be preferentially analyzed with the entire sample intact. For this reason, forensic laboratories are taking advantage of ATR to collect IR spectra of automotive paint systems that may consist of three or more layers. However, the IR spectrum of a paint sample obtained by ATR will exhibit distortions, e.g., band broadening and lower relative intensities at higher wavenumbers, compared with its transmission counterpart. This hinders library searching because most library spectra are measured in transmission mode. Furthermore, the angle of incidence for the internal reflection element, the refractive index of the clear coat, and surface contamination due to inorganic contaminants can profoundly influence the quality of the ATR spectrum obtained for automotive paints. A correction algorithm to allow ATR spectra to be searched using IR transmission spectra of the paint data query (PDQ) automotive database is presented. The proposed correction algorithm to convert transmission spectra from the PDQ library to ATR spectra is able to address distortion issues such as the relative intensities and broadening of the bands, and the introduction of wavelength shifts at lower frequencies, which prevent library searching of ATR spectra using archived IR transmission data.

  11. Comparison of visible and near infrared reflectance spectroscopy on fat to authenticate dietary history of lambs.

    Science.gov (United States)

    Huang, Y; Andueza, D; de Oliveira, L; Zawadzki, F; Prache, S

    2015-11-01

    Since consumers are showing increased interest in the origin and method of production of their food, it is important to be able to authenticate dietary history of animals by rapid and robust methods used in the ruminant products. Promising breakthroughs have been made in the use of spectroscopic methods on fat to discriminate pasture-fed and concentrate-fed lambs. However, questions remained on their discriminatory ability in more complex feeding conditions, such as concentrate-finishing after pasture-feeding. We compared the ability of visible reflectance spectroscopy (Vis RS, wavelength range: 400 to 700 nm) with that of visible-near-infrared reflectance spectroscopy (Vis-NIR RS, wavelength range: 400 to 2500 nm) to differentiate between carcasses of lambs reared with three feeding regimes, using partial least square discriminant analysis (PLS-DA) as a classification method. The sample set comprised perirenal fat of Romane male lambs fattened at pasture (P, n = 69), stall-fattened indoors on commercial concentrate and straw (S, n = 55) and finished indoors with concentrate and straw for 28 days after pasture-feeding (PS, n = 65). The overall correct classification rate was better for Vis-NIR RS than for Vis RS (99.0% v. 95.1%, P visible part of the Vis-NIR spectra (possibly fatty acids), together with carotenoid and haem pigments, in the discrimination of the three feeding regimes.

  12. Development of an in situ polarization-dependent total-reflection fluorescence XAFS measurement system.

    Science.gov (United States)

    Chun, W J; Tanizawa, Y; Shido, T; Iwasawa, Y; Nomura, M; Asakura, K

    2001-03-01

    An in situ polarization-dependent total-reflection fluorescence X-ray absorption fine structure (PTRF-XAFS) spectroscopy system has been developed, which enables PTRF-XAFS experiments to be performed in three different orientations at various temperatures (273-600 K) and pressures (10(-10) approximately 760 torr). The system consists of a measurement chamber and a preparation chamber. The measurement chamber has a high-precision six-axis goniometer and a multielement solid-state detector. Using a transfer chamber, also operated under ultra-high-vacuum conditions, the sample can be transferred to the measurement chamber from the preparation chamber, which possesses low-energy electron diffraction, Auger electron spectroscopy and X-ray photoelectron spectroscopy facilities, as well as a sputtering gun and an annealing system. The in situ PTRF-EXAFS for Cu species on TiO2 (110) has been measured in three different orientations, revealing anisotropic growth of Cu under the influence of the TiO2 (110) surface.

  13. Assessing Zones of Low Radar Reflectivity Across the South Polar Cap of Mars

    Science.gov (United States)

    Putzig, N. E.; Smith, I. B.; Whitten, J. L.; Campbell, B. A.

    2017-12-01

    The Mars Reconnaissance Orbiter Shallow Radar (SHARAD) revealed near-surface zones of low radar reflectivity (reflection-free zones, RFZs) in many areas of Planum Australe (Phillips et al., 2011, Science 332). The most poleward, RFZ3, corresponds geographically to geologic unit AA3 (Tanaka et al., 2007, 7th Int'l Mars Conf. abs. 3276) that exhibits sublimation features. Geometric considerations demonstrated that RFZ3 consists of three distinct layers of CO2 ice, preserved from earlier periods of atmospheric collapse (Bierson et al., 2016, GRL 43). However, the nature of other RFZs at lower latitudes remains undetermined, with none of the SHARAD observations examined to date providing definitive geometric constraints on their composition. While CO2-ice composition has not been ruled out, these RFZs differ in important ways from RFZ3. Surface imagery in the vicinity of the outlying RFZs does not generally exhibit sublimation features similar to those seen in AA3, SHARAD reflectivity exhibits a lower contrast with surrounding materials relative to RFZ3, and there are no indications of distinct layering within the outlying RFZs as there are in RFZ3. In addition, climate modeling of atmospheric collapse episodes (Wood et al., 2016, LPSC abs. 3074) suggests that CO2 accumulation is highly concentrated at the highest latitudes. An alternative explanation for the outlying RFZs is that they consist of nearly pure water ice deposited during times when atmospheric dust was nearly absent. Such conditions may occur coeval with eras of CO2 accumulation at the higher latitudes. To test these possibilities, we are working to constrain the composition of the outlying RFZs, using the recently produced 3-D SHARAD data volume that encompasses the entire Martian south polar ice cap (Foss et al., 2017, The Leading Edge, 36). Work is ongoing, but we expect that the geometric corrections and improvements to the overall signal-to-noise ratio provided by the 3-D radar imaging processing may

  14. Baseline Correction of Diffuse Reflection Near-Infrared Spectra Using Searching Region Standard Normal Variate (SRSNV).

    Science.gov (United States)

    Genkawa, Takuma; Shinzawa, Hideyuki; Kato, Hideaki; Ishikawa, Daitaro; Murayama, Kodai; Komiyama, Makoto; Ozaki, Yukihiro

    2015-12-01

    An alternative baseline correction method for diffuse reflection near-infrared (NIR) spectra, searching region standard normal variate (SRSNV), was proposed. Standard normal variate (SNV) is an effective pretreatment method for baseline correction of diffuse reflection NIR spectra of powder and granular samples; however, its baseline correction performance depends on the NIR region used for SNV calculation. To search for an optimal NIR region for baseline correction using SNV, SRSNV employs moving window partial least squares regression (MWPLSR), and an optimal NIR region is identified based on the root mean square error (RMSE) of cross-validation of the partial least squares regression (PLSR) models with the first latent variable (LV). The performance of SRSNV was evaluated using diffuse reflection NIR spectra of mixture samples consisting of wheat flour and granular glucose (0-100% glucose at 5% intervals). From the obtained NIR spectra of the mixture in the 10 000-4000 cm(-1) region at 4 cm intervals (1501 spectral channels), a series of spectral windows consisting of 80 spectral channels was constructed, and then SNV spectra were calculated for each spectral window. Using these SNV spectra, a series of PLSR models with the first LV for glucose concentration was built. A plot of RMSE versus the spectral window position obtained using the PLSR models revealed that the 8680–8364 cm(-1) region was optimal for baseline correction using SNV. In the SNV spectra calculated using the 8680–8364 cm(-1) region (SRSNV spectra), a remarkable relative intensity change between a band due to wheat flour at 8500 cm(-1) and that due to glucose at 8364 cm(-1) was observed owing to successful baseline correction using SNV. A PLSR model with the first LV based on the SRSNV spectra yielded a determination coefficient (R2) of 0.999 and an RMSE of 0.70%, while a PLSR model with three LVs based on SNV spectra calculated in the full spectral region gave an R2 of 0.995 and an RMSE of

  15. Non-invasive identification of organic materials in historical stringed musical instruments by reflection infrared spectroscopy: a methodological approach.

    Science.gov (United States)

    Invernizzi, Claudia; Daveri, Alessia; Vagnini, Manuela; Malagodi, Marco

    2017-05-01

    The analysis of historical musical instruments is becoming more relevant and the interest is increasingly moving toward the non-invasive reflection FTIR spectroscopy, especially for the analysis of varnishes. In this work, a specific infrared reflectance spectral library of organic compounds was created with the aim of identifying musical instrument materials in a totally non-invasive way. The analyses were carried out on pure organic compounds, as bulk samples and laboratory wooden models, to evaluate the diagnostic reflection mid-infrared (MIR) bands of proteins, polysaccharides, lipids, and resins by comparing reflection spectra before and after the KK correction. This methodological approach was applied to real case studies represented by four Stradivari violins and a Neapolitan mandolin.

  16. Classification of Fusarium-Infected Korean Hulled Barley Using Near-Infrared Reflectance Spectroscopy and Partial Least Squares Discriminant Analysis

    OpenAIRE

    Jongguk Lim; Giyoung Kim; Changyeun Mo; Kyoungmin Oh; Hyeonchae Yoo; Hyeonheui Ham; Moon S. Kim

    2017-01-01

    The purpose of this study is to use near-infrared reflectance (NIR) spectroscopy equipment to nondestructively and rapidly discriminate Fusarium-infected hulled barley. Both normal hulled barley and Fusarium-infected hulled barley were scanned by using a NIR spectrometer with a wavelength range of 1175 to 2170 nm. Multiple mathematical pretreatments were applied to the reflectance spectra obtained for Fusarium discrimination and the multivariate analysis method of partial least squares discri...

  17. Secondary cell wall development in cotton fibers as examined with attenuated total reflection Fourier transform infrared spectroscopy

    Science.gov (United States)

    Cotton fibers harvested at 18, 20, 24, 28, 32, 36 and 40 days after flowering were examined using attenuated total reflection Fourier transform-infrared (ATR FT-IR) spectroscopy. The selected harvesting points coincide with secondary cell wall (SCW) development in the fibers. Progressive but moderat...

  18. Characterization of southern yellow pine bark layers by Attenuated Total Reflectance (ATR) and Fourier Transform Infrared (FT-IR) Spectroscopy

    Science.gov (United States)

    Thomas L. Eberhardt

    2009-01-01

    The outer bark (rhytidome) of the southern yellow pines is a complex structure comprised of alternating layers of obliterated phloem and periderm tissues, with the latter comprised of three layers, those being phellem, phellogen, and phelloderm. An attenuated total reflectance (ATR) sampling accessory, coupled with a Fourier transform infrared (FTIR) spectrometer,...

  19. Diffuse-reflectance fourier-transform mid-infrared spectroscopy as a method of characterizing changes in soil organic matter

    Science.gov (United States)

    Diffuse-Reflectance Fourier-Transform Mid-Infrared Spectroscopy (MidIR) can identify the presence of important organic functional groups in soil organic matter (SOM). Soils contain myriad organic and inorganic components that absorb in the MidIR so spectral interpretation needs to be validated in or...

  20. Quantification of betaglucans, lipid and protein contents in whole oat groats (Avena sativa L.) using near infrared reflectance spectroscopy

    Science.gov (United States)

    Whole oat has been described as an important healthy food for humans due to its beneficial nutritional components. Near infrared reflectance spectroscopy (NIRS) is a powerful, fast, accurate and non-destructive analytical tool that can be substituted for some traditional chemical analysis. A total o...

  1. Effective rumen degradation of dry matter, crude protein and neutral detergent fibre in forage determined by near infrared reflectance spectroscopy

    DEFF Research Database (Denmark)

    Ohlsson, C; Houmøller, L P; Weisbjerg, Martin Riis

    2007-01-01

    The objective of the present study was to examine if near infrared reflectance spectroscopy (NIRS) could be used to predict degradation parameters and effective degradation from scans of original forage samples. Degradability of dry matter (DM), crude protein (CP) and neutral detergent fibre (NDF...

  2. Characterization of polar stratospheric cloud (PSC using ground-based Fourier-transform infrared spectrometer (FTIR at Syowa Station, Antarctica

    Directory of Open Access Journals (Sweden)

    Hideaki Nakajima

    2010-12-01

    Full Text Available Polar stratospheric clouds (PSCs play an important role in ozone destruction via the occurrence of heterogeneous reactions on their surface that convert reservoir species of active chlorine and bromine (e.g., HCl, ClONO_2, HBr, or BrONO_2 into active Cl_2 or Br_2. However, a lack of direct measurements means that uncertainty remains regarding the characteristics, types, mixtures, and nature of PSCs. To address this problem, we conducted, for the first time, ground-based measurements of the features of PSCs using a low-resolution Fourier-transform infrared (FTIR spectrometer at Syowa Station, Antarctica, in 2007. Many PSCs were observed between July and August 2007. We succeeded in identifying the features of Ice (Type-II, NAD and or β-NAT (Type-Ia, and STS (Type-Ib PSCs in the zenith sky infrared spectra measured by FTIR.

  3. Illuminating the Capabilities of the Suomi National Polar-Orbiting Partnership (NPP Visible Infrared Imaging Radiometer Suite (VIIRS Day/Night Band

    Directory of Open Access Journals (Sweden)

    Steven D. Miller

    2013-12-01

    Full Text Available Daytime measurements of reflected sunlight in the visible spectrum have been a staple of Earth-viewing radiometers since the advent of the environmental satellite platform. At night, these same optical-spectrum sensors have traditionally been limited to thermal infrared emission, which contains relatively poor information content for many important weather and climate parameters. These deficiencies have limited our ability to characterize the full diurnal behavior and processes of parameters relevant to improved monitoring, understanding and modeling of weather and climate processes. Visible-spectrum light information does exist during the nighttime hours, originating from a wide variety of sources, but its detection requires specialized technology. Such measurements have existed, in a limited way, on USA Department of Defense satellites, but the Suomi National Polar-orbiting Partnership (NPP satellite, which carries a new Day/Night Band (DNB radiometer, offers the first quantitative measurements of nocturnal visible and near-infrared light. Here, we demonstrate the expanded potential for nocturnal low-light visible applications enabled by the DNB. Via a combination of terrestrial and extraterrestrial light sources, such observations are always available—expanding many current existing applications while enabling entirely new capabilities. These novel low-light measurements open doors to a wealth of new interdisciplinary research topics while lighting a pathway toward the optimized design of follow-on satellite based low light visible sensors.

  4. Exploration of a Polarized Surface Bidirectional Reflectance Model Using the Ground-Based Multiangle SpectroPolarimetric Imager

    Directory of Open Access Journals (Sweden)

    David J. Diner

    2012-12-01

    Full Text Available Accurate characterization of surface reflection is essential for retrieval of aerosols using downward-looking remote sensors. In this paper, observations from the Ground-based Multiangle SpectroPolarimetric Imager (GroundMSPI are used to evaluate a surface polarized bidirectional reflectance distribution function (PBRDF model. GroundMSPI is an eight-band spectropolarimetric camera mounted on a rotating gimbal to acquire pushbroom imagery of outdoor landscapes. The camera uses a very accurate photoelastic-modulator-based polarimetric imaging technique to acquire Stokes vector measurements in three of the instrument’s bands (470, 660, and 865 nm. A description of the instrument is presented, and observations of selected targets within a scene acquired on 6 January 2010 are analyzed. Data collected during the course of the day as the Sun moved across the sky provided a range of illumination geometries that facilitated evaluation of the surface model, which is comprised of a volumetric reflection term represented by the modified Rahman-Pinty-Verstraete function plus a specular reflection term generated by a randomly oriented array of Fresnel-reflecting microfacets. While the model is fairly successful in predicting the polarized reflection from two grass targets in the scene, it does a poorer job for two manmade targets (a parking lot and a truck roof, possibly due to their greater degree of geometric organization. Several empirical adjustments to the model are explored and lead to improved fits to the data. For all targets, the data support the notion of spectral invariance in the angular shape of the unpolarized and polarized surface reflection. As noted by others, this behavior provides valuable constraints on the aerosol retrieval problem, and highlights the importance of multiangle observations.

  5. Analysis of total oil and fatty acids composition by near infrared reflectance spectroscopy in edible nuts

    Science.gov (United States)

    Kandala, Chari V.; Sundaram, Jaya

    2014-10-01

    Near Infrared (NIR) Reflectance spectroscopy has established itself as an important tool in quantifying water and oil present in various food materials. It is rapid and nondestructive, easier to use, and does not require processing the samples with corrosive chemicals that would render them non-edible. Earlier, the samples had to be ground into powder form before making any measurements. With the development of new soft ware packages, NIR techniques could now be used in the analysis of intact grain and nuts. While most of the commercial instruments presently available work well with small grain size materials such as wheat and corn, the method present here is suitable for large kernel size products such as shelled or in-shell peanuts. Absorbance spectra were collected from 400 nm to 2500 nm using a NIR instrument. Average values of total oil contents (TOC) of peanut samples were determined by standard extraction methods, and fatty acids were determined using gas chromatography. Partial least square (PLS) analysis was performed on the calibration set of absorption spectra, and models were developed for prediction of total oil and fatty acids. The best model was selected based on the coefficient of determination (R2), Standard error of prediction (SEP) and residual percent deviation (RPD) values. Peanut samples analyzed showed RPD values greater than 5.0 for both absorbance and reflectance models and thus could be used for quality control and analysis. Ability to rapidly and nondestructively measure the TOC, and analyze the fatty acid composition, will be immensely useful in peanut varietal improvement as well as in the grading process of grain and nuts.

  6. Analysis of multiple soybean phytonutrients by near-infrared reflectance spectroscopy.

    Science.gov (United States)

    Zhang, Gaoyang; Li, Penghui; Zhang, Wenfei; Zhao, Jian

    2017-05-01

    Improvement of the nutritional quality of soybean is usually facilitated by a vast range of soybean germplasm with enough information about their multiple phytonutrients. In order to acquire this essential information from a huge number of soybean samples, a rapid analytic method is urgently required. Here, a nondestructive near-infrared reflectance spectroscopy (NIRS) method was developed for rapid and accurate measurement of 25 nutritional components in soybean simultaneously, including fatty acids palmitic acid, stearic acid, oleic acid, linoleic acid, and linolenic acid, vitamin E (VE), α-VE, γ-VE, δ-VE, saponins, isoflavonoids, and flavonoids. Modified partial least squares regression and first, second, third, and fourth derivative transformation was applied for the model development. The 1 minus variance ratio (1-VR) value of the optimal model can reach between the highest 0.95 and lowest 0.64. The predicted values of phytonutrients in soybean using NIRS technology are comparable to those obtained from using the traditional spectrum or chemical methods. A robust NIRS can be adopted as a reliable method to evaluate complex plant constituents for screening large-scale samples of soybean germplasm resources or genetic populations for improvement of nutritional qualities. Graphical Abstract ᅟ.

  7. [Maize Hybrid Seed Purity Identification Based on Near Infrared Reflectance (NIR) and Transmittance (NIT) Spectra].

    Science.gov (United States)

    Li, Tian-xin; Jia, Shi-qiang; Liu, Xu; Zhao, Sheng-yi; Ran, Hang; Yan, Yan-lu; An, Dong

    2015-12-01

    This article explore the feasibility of using Near Infrared Reflectance (NIR) and Transmittance (NIT) Spectroscopy (908.1-1677.2 nm wavelength range) to identify maize hybrid purity, and compare the performance of NIR and NIT spectroscopy. Principle Component Analysis (PCA) and Orthogonal Linear Discriminant Analysis (OLDA) were used to reduce the dimension of spectra which have been pretreated by first derivative and vector normalization. The hybrid purity identification model of Nonghua101 and Jingyu16 were built by SVM. Models based on NIR spectra obtained correct identification rate as 100% and 90% for Nonghua101 and Jingyu16 respectively. But NIR spectra were greatly influenced by the placement of seeds, and there existed significant difference between NIR spectra of embryo and non-embryo side. Models based on NIT spectroscopy yielded correct identification rate as 98% both for Nonghua101 and Jingyu16. NIT spectra of embryo and non-embryo side were highly similar. The results indicate that it is feasible to identify maize hybrid purity based on NIR and NIT spectroscopy, and NIT spectroscopy is more suitable to analyze single seed kernel than NIR spectroscopy.

  8. Attenuated total reflectance fourier transform infrared analysis of fly ash geopolymer gel aging.

    Science.gov (United States)

    Rees, Catherine A; Provis, John L; Lukey, Grant C; van Deventer, Jannie S J

    2007-07-17

    Structural changes in fly ash geopolymers activated with different sodium hydroxide and silicate concentrations are investigated using attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy over a period of 200 days. A strong correlation is found between the concentration of silicate monomer in the activating solution and the position of the main Si-O-T stretching band in the FTIR spectrum, which gives an indication of the relative changes in the gel Si/Al ratio. The FTIR spectra of geopolymer samples with activating solution concentrations of up to 1.2 M SiO2 indicate that an Al-rich gel forms before the final gel composition is reached. The time required for the system to reach a steady gel composition depends on the silicate activating solution concentration and speciation. Geopolymers activated with solutions containing predominantly high-order silicate species rapidly reach a steady gel composition without first forming an Al-rich gel. A minimum silicate monomer concentration of approximately 0.6 M is required to shift the geopolymer synthesis mechanism from hydroxide activation to silicate activation. Silicate speciation in the activating solutions also affects zeolite formation and geopolymer microstructures, with a more homogeneous microstructure and less zeolite formation observed at a higher SiO2 content.

  9. Near-infrared reflectance spectroscopy as a process analytical technology tool in Ginkgo biloba extract qualification.

    Science.gov (United States)

    Rosa, Sílvia S; Barata, Pedro A; Martins, José M; Menezes, José C

    2008-06-09

    Here, we describe the use of near-infrared diffuse reflectance spectroscopy for qualification of Ginkgo biloba extract as raw material for use in pharmaceutical products. G. biloba extract shows unpredicted and uncontrolled variability in some of its quality specifications, intrinsic to its natural origin, which have influence on the manufacturing process of solid dosage forms (viz. granulation and compression). Some of these properties could not be determined by conventional quality control tests, so we investigated the use of NIR to qualify the batches of Ginkgo extract accordingly to its different features and establish a relationship with some of the manufacturing steps behaviour based on their qualification. Several approaches were evaluated, and the NIR method developed demonstrated to be sensitive to changes in important quality specifications and therefore adequate to qualify incoming batches of G. biloba extract. This could be considered a process analytical technology (PAT) application since it: (1) establishes the source of variability in a qualitative way, (2) explains its propagation to the final product quality attributes and (3) lays the basis for a control strategy to be applied in the manufacturing process.

  10. Detection of sibutramine in adulterated dietary supplements using attenuated total reflectance-infrared spectroscopy.

    Science.gov (United States)

    Deconinck, E; Cauwenbergh, T; Bothy, J L; Custers, D; Courselle, P; De Beer, J O

    2014-11-01

    Sibutramine is one of the most occurring adulterants encountered in dietary supplements with slimming as indication. These adulterated dietary supplements often contain a herbal matrix. When customs intercept these kind of supplements it is almost impossible to discriminate between the legal products and the adulterated ones, due to misleading packaging. Therefore in most cases these products are confiscated and send to laboratories for analysis. This results inherently in the confiscation of legal, non-adulterated products. Therefore there is a need for easy to use equipment and techniques to perform an initial screening of samples. Attenuated total reflectance-infrared (ATR-IR) spectroscopy was evaluated for the detection of sibutramine in adulterated dietary supplements. Data interpretation was performed using different basic chemometric techniques. It was found that the use of ATR-IR combined with the k-Nearest Neighbours (k-NN) was able to detect all adulterated dietary supplements in an external test set and this with a minimum of false positive results. This means that a small amount of legal products will still be confiscated and analyzed in a laboratory to be found negative, but no adulterated samples will pass the initial ATR-IR screening. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Infrared reflectance of GaN films grown on Si(001) substrates

    International Nuclear Information System (INIS)

    Zhang, Xiong; Hou, Yong-Tian; Feng, Zhe-Chuan; Chen, Jin-Li

    2001-01-01

    GaN thin films on Si(001) substrates are studied by infrared reflectance (IRR) spectroscopy at room temperature (RT). Variations in the IRR spectral line shape with the microstructure of GaN/Si(011) film are quantitatively explained in terms of a three-component effective medium model. In this model, the nominally undoped GaN film is considered to consist of three elementary components, i.e., single crystalline GaN grains, pores (voids), and inter-granulated materials (amorphous GaN clusters). Such a polycrystalline nature of the GaN/Si(001) films was confirmed by scanning electron microscopy measurements. It was demonstrated that based on the proposed three-component effective medium model, excellent overall simulation of the RT-IRR spectra can be achieved, and the fine structures of the GaN reststrahlen band in the measured RT-IRR spectra can also be interpreted very well. Furthermore, the volume fraction for each component in the GaN/Si(001) film was accurately determined by fitting the experimental RT-IRR spectra with the theoretical simulation. These results indicate that IRR spectroscopy can offer a sensitive and convenient tool to probe the microstructure of GaN films grown on silicon. [copyright] 2001 American Institute of Physics

  12. Rapid biochemical methane potential prediction of urban organic waste with near-infrared reflectance spectroscopy.

    Science.gov (United States)

    Fitamo, T; Triolo, J M; Boldrin, A; Scheutz, C

    2017-08-01

    The anaerobic digestibility of various biomass feedstocks in biogas plants is determined with biochemical methane potential (BMP) assays. However, experimental BMP analysis is time-consuming, costly and challenging to optimise stock management and feeding to achieve improved biogas production. The aim of the present study is to develop a fast and reliable model based on near-infrared reflectance spectroscopy (NIRS) for the BMP prediction of urban organic waste (UOW). The model comprised 87 UOW samples. Additionally, 88 plant biomass samples were included, to develop a combined model predicting BMP. The coefficient of determination (R 2 ) and root mean square error in prediction (RMSE P ) of the UOW model were 0.88 and 44 mL CH 4 /g VS, while the combined model was 0.89 and 50 mL CH 4 /g VS. Improved model performance was obtained for the two individual models compared to the combined version. The BMP prediction with NIRS was satisfactory and moderately successful. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. [Progress in application of near infrared reflectance spectroscopy to the study of ruminant nutrition].

    Science.gov (United States)

    Guo, Xu-Sheng; Shang, Zhan-Huan; Fang, Xiang-Wen; Long, Rui-Jun

    2009-03-01

    The near infrared reflectance spectroscopy (NIRS) technique has been widely used in the study of ruminant nutrition with many of its operational merits such as facility, shortcut and accuracy, etc. Study suggested that the standard error of cross-validation (SECV) ranges from 1.6% to 2.8% in predicting organic matter digestion of ruminant diet by using the NIRS technique; the chemical and biological compositions and the microbial protein proportion in the duodenal digesta can be predicted accurately using the NIRS. However, the kinetic parameters of degradation are not well predicted; The prediction of intake of stall feeding animals by using NIRS is similar to the determination of in vivo method, but the standard error of prediction is about 14% when using the NIRS to predict intake of grazing animals. All of the studies suggest that big progress has been made in using NIRS technique to predict feed digestion and evaluate the diet quality and intake of ruminant animals, which also suggest that the NIRS technique has a wide prospect in the study of ruminant nutrition.

  14. Phase transitions of amorphous solid acetone in confined geometry investigated by reflection absorption infrared spectroscopy.

    Science.gov (United States)

    Shin, Sunghwan; Kang, Hani; Kim, Jun Soo; Kang, Heon

    2014-11-26

    We investigated the phase transformations of amorphous solid acetone under confined geometry by preparing acetone films trapped in amorphous solid water (ASW) or CCl4. Reflection absorption infrared spectroscopy (RAIRS) and temperature-programmed desorption (TPD) were used to monitor the phase changes of the acetone sample with increasing temperature. An acetone film trapped in ASW shows an abrupt change in the RAIRS features of the acetone vibrational bands during heating from 80 to 100 K, which indicates the transformation of amorphous solid acetone to a molecularly aligned crystalline phase. Further heating of the sample to 140 K produces an isotropic solid phase, and eventually a fluid phase near 157 K, at which the acetone sample is probably trapped in a pressurized, superheated condition inside the ASW matrix. Inside a CCl4 matrix, amorphous solid acetone crystallizes into a different, isotropic structure at ca. 90 K. We propose that the molecularly aligned crystalline phase formed in ASW is created by heterogeneous nucleation at the acetone-water interface, with resultant crystal growth, whereas the isotropic crystalline phase in CCl4 is formed by homogeneous crystal growth starting from the bulk region of the acetone sample.

  15. Detection of canine skin and subcutaneous tumors by visible and near-infrared diffuse reflectance spectroscopy

    Science.gov (United States)

    Cugmas, Blaž; Plavec, Tanja; Bregar, Maksimilijan; Naglič, Peter; Pernuš, Franjo; Likar, Boštjan; Bürmen, Miran

    2015-03-01

    Cancer is the main cause of canine morbidity and mortality. The existing evaluation of tumors requires an experienced veterinarian and usually includes invasive procedures (e.g., fine-needle aspiration) that can be unpleasant for the dog and the owner. We investigate visible and near-infrared diffuse reflectance spectroscopy (DRS) as a noninvasive optical technique for evaluation and detection of canine skin and subcutaneous tumors ex vivo and in vivo. The optical properties of tumors and skin were calculated in a spectrally constrained manner, using a lookup table-based inverse model. The obtained optical properties were analyzed and compared among different tumor groups. The calculated parameters of the absorption and reduced scattering coefficients were subsequently used for detection of malignant skin and subcutaneous tumors. The detection sensitivity and specificity of malignant tumors ex vivo were 90.0% and 73.5%, respectively, while corresponding detection sensitivity and specificity of malignant tumors in vivo were 88.4% and 54.6%, respectively. The obtained results show that the DRS is a promising noninvasive optical technique for detection and classification of malignant and benign canine skin and subcutaneous tumors. The method should be further investigated on tumors with common origin.

  16. Rapid assessment of soluble solids content in navel orange by near-infrared diffuse reflectance spectra

    Science.gov (United States)

    Liu, Yande; Luo, Ji; Chen, Xingmiao; Ying, Yibin

    2006-10-01

    The potential of using Near Infrared diffuse reflectance spectroscopy to assess soluble solids content (SSC) of intact navel orange was examined. A total 40 samples were used to develop the calibration and prediction models. NIR spectral data were collected in the spectral region between 350 nm and 2500 nm and its second derivative spectra was used for this study. Different scattering correction algorithms (no preprocessing and multiplicative scattering correction (MSC) were compared. Calibration models based on different spectral ranges, different derivatives and different kinds of statistical models including partial least square (PLS) and principle component regression (PCR) were also compared in this research. The best results of PLS models with the second derivative spectra are r=0.929, RMSEC=0.517 and RMSEP=0.592, in the wavelength range of 361-2488 nm. The segment length used to derivate the spectra influences the calibration model and the results are better when the segment lengths and gap sizes are lower in Norris derivate filter. The results show that this method is feasible for rapid assessing SSC of the navel orange.

  17. Quality evaluation of regional forage resources by means of near infrared reflectance spectroscopy

    Directory of Open Access Journals (Sweden)

    Bruno Ronchi

    2010-01-01

    Full Text Available Quality parameters of grassland and pasture samples collected during a three-year period at two environmentally andgeographically different areas were analysed by Near Infrared Reflectance Spectroscopy (NIRS. Chemical analysis forcrude protein (CP, crude fibre (CF, neutral detergent fibre (NDF, acid detergent fibre (ADF, acid detergent lignin (ADLand crude ash (ASH carried out on two-thirds of the samples were used in calibration processes. The remaining onethirdof the data was used to validate the best calibrations obtained. Samples selection is discussed. Different math pretreatments(derivative, gap, primary smoothing and secondary smoothing, light scattering correction methods and calibrationalgorithms were tested to achieve the better predictive performances. We obtained the best results using differentregression algorithms to correlate spectral information to chemical data. For CP (R2 = 0.94, SEP=1.3, NDF (R2 =0.95, SEP = 2.14 and ADF (R2 = 0.92, SEP=2.06 Multiple Linear Regression (MLR models fit chemical data better thanMean Partial Least Square (MPLS regression. A molecular basis explanation of wavelengths selected was carried out.MPLS models worked well for CF (R2 = 0.93, SEP=1.57, and ASH (R2 = 0.95, SEP=1.17 while poor calibrations wereobtained for ADL using both algorithms. To confirm the reliability of the models developed, uncertainties of predictionswere compared with findings on nutritional variations and animal performances.

  18. Changes in Attenuated Total Reflection Fourier Transform Infrared Spectra as Blood Dries Out.

    Science.gov (United States)

    Zhang, Yinming; Wang, Qi; Li, Bing; Wang, Zhijun; Li, Chengzhi; Yao, Yao; Huang, Ping; Wang, Zhenyuan

    2017-05-01

    The time since deposition (TSD) of a bloodstain is a valuable piece of evidence for forensic scientists to determine the time at which a crime took place. The objective of this study was to determine whether attenuated total reflection (ATR) Fourier transform infrared (FTIR) spectroscopy could be used to estimate the TSD of a bloodstain in a relatively early period (from 0 min to the time required for the bloodstain to dry out). For this purpose, we used ATR-FTIR to study the variation in absorbance at certain wavelengths as rat and human blood sample dried out. The absorbance at 3308/cm (A3308) was found to have a close correlation with the TSD during this time period, and the changes in A3308 during the drying of rat and human blood drops under the same controlled conditions showed similar results. The current study indicates that ATR-FTIR spectroscopy has potential as a tool for estimating TSD at early time periods of blood deposition. © 2016 American Academy of Forensic Sciences.

  19. Histological validation of near-infrared reflectance multispectral imaging technique for caries detection and quantification.

    Science.gov (United States)

    Salsone, Silvia; Taylor, Andrew; Gomez, Juliana; Pretty, Iain; Ellwood, Roger; Dickinson, Mark; Lombardo, Giuseppe; Zakian, Christian

    2012-07-01

    Near infrared (NIR) multispectral imaging is a novel noninvasive technique that maps and quantifies dental caries. The technique has the ability to reduce the confounding effect of stain present on teeth. The aim of this study was to develop and validate a quantitative NIR multispectral imaging system for caries detection and assessment against a histological reference standard. The proposed technique is based on spectral imaging at specific wavelengths in the range from 1000 to 1700 nm. A total of 112 extracted teeth (molars and premolars) were used and images of occlusal surfaces at different wavelengths were acquired. Three spectral reflectance images were combined to generate a quantitative lesion map of the tooth. The maximum value of the map at the corresponding histological section was used as the NIR caries score. The NIR caries score significantly correlated with the histological reference standard (Spearman's Coefficient=0.774, p<0.01). Caries detection sensitivities and specificities of 72% and 91% for sound areas, 36% and 79% for lesions on the enamel, and 82% and 69% for lesions in dentin were found. These results suggest that NIR spectral imaging is a novel and promising method for the detection, quantification, and mapping of dental caries.

  20. Near infrared reflectance spectroscopy as a process signature in uranium oxides

    International Nuclear Information System (INIS)

    Plaue, J.W.; Klunder, G.L.; Hutcheon, I.D.; Czerwinski, K.R.

    2013-01-01

    Near-infrared (NIR) reflectance spectroscopy was examined as a potential tool for the determination of forensic signatures indicative of the chemical process history of uranium oxides. The ability to determine the process history of nuclear materials is a desired, but underdeveloped, area of technical nuclear forensics. Application of the NIR technique potentially offers a quick and non-destructive tool to serve this need; however, few data have been published on the compounds of interest. The viability of NIR was investigated through the analysis of a combination of laboratory-derived and real-world uranium precipitates and oxides. A set of reference uranium materials was synthesized in the laboratory using the commonly encountered aqueous precipitation reactions for uranium ore concentration and chemical separation processes (ammonia, hydrogen peroxide, sodium hydroxide, ammonium carbonate, and magnesia). NIR spectra were taken on a range of samples heat treated in air between 85 and 750 deg C. X-ray diffraction patterns were also obtained to complement the NIR analysis with crystal phase information. Similar analyses were performed using a set of real-world samples, with process information obtained from the literature, to provide a comparison between materials synthesized in the laboratory and samples representative of industrial processes. (author)

  1. Forensic Hair Differentiation Using Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy.

    Science.gov (United States)

    Manheim, Jeremy; Doty, Kyle C; McLaughlin, Gregory; Lednev, Igor K

    2016-07-01

    Hair and fibers are common forms of trace evidence found at crime scenes. The current methodology of microscopic examination of potential hair evidence is absent of statistical measures of performance, and examiner results for identification can be subjective. Here, attenuated total reflection (ATR) Fourier transform-infrared (FT-IR) spectroscopy was used to analyze synthetic fibers and natural hairs of human, cat, and dog origin. Chemometric analysis was used to differentiate hair spectra from the three different species, and to predict unknown hairs to their proper species class, with a high degree of certainty. A species-specific partial least squares discriminant analysis (PLSDA) model was constructed to discriminate human hair from cat and dog hairs. This model was successful in distinguishing between the three classes and, more importantly, all human samples were correctly predicted as human. An external validation resulted in zero false positive and false negative assignments for the human class. From a forensic perspective, this technique would be complementary to microscopic hair examination, and in no way replace it. As such, this methodology is able to provide a statistical measure of confidence to the identification of a sample of human, cat, and dog hair, which was called for in the 2009 National Academy of Sciences report. More importantly, this approach is non-destructive, rapid, can provide reliable results, and requires no sample preparation, making it of ample importance to the field of forensic science. © The Author(s) 2016.

  2. Noninvasive method for the assessment of dermal uptake of pesticides using attenuated total reflectance infrared spectroscopy.

    Science.gov (United States)

    Carden, Angela; Yost, Michael G; Fenske, Richard A

    2005-03-01

    Dermal absorption of pesticides is a primary exposure route for agricultural workers, but is not well characterized. Current measurement techniques are either invasive, such as tape-stripping, or require extensive sample preparation or analysis time, such as urinary metabolite monitoring or wipe sampling followed by gas chromatography analysis. We present the application of a noninvasive, spectroscopic approach for the measurement of pesticide absorption into skin. Attenuated total reflectance infrared spectroscopy (ATR-IR) was used to monitor directly the absorption of two pesticides--captan and azinphos-methyl--in ten volunteers over 20 min under occlusive conditions. We found substantial variability in absorption across subjects. Our results were comparable to those measured by the more traditional method of wipe-sampling followed by extraction and gas chromatography analysis. Multivariate data analysis, in the form of multivariate curve resolution (MCR), is a novel addition to this type of experiment, yielding time-resolved information unachievable by standard methods. These data are potentially more informative than the monitoring of blood or urinary metabolites because they can be acquired in essentially real-time, allowing observations of pesticide absorption on a rapid timescale rather than over hours or days.

  3. Investigation of the internal reflectance and prediction of infrared diffuse reflectance of the polymeric coating on aluminum substrate

    Science.gov (United States)

    Ho, Wen-Dar; Ma, Chen-Chi M.

    1998-02-01

    This study employs the ray tracing method to develop and analyze mathematical formulae for the IR diffuse reflectance of the polymeric coating on a metal substrate. The effects of the thickness and the absorption property of the polymer film on the internal reflectance are also investigated. In addition, the diffuse reflectance of the coating/substrate system which is irradiated with a perfect diffuse source is formulated as well. Analysis results indicate that the internal reflectance of the internal front surface (polymer/air interface) is not a constant which depends on the film thickness and absorption property. Closely examining the internal multiple reflections between the front and the substrate surface reveals that the diffuse reflectance of the coating/substrate system can be obtained by summing the fractions of rays emerging from the front surface. By knowing the refractive index and the extinction coefficient of the polymer, the diffuse reflectance of the coating/substrate system can be calculated by the formulae presented here. In addition an alkyd resin coating/aluminum substrate system is also implemented to compare the experimental reflectances with the calculated ones. According to the comparisons the analysis and developed formulae are quite effective.

  4. Near-infrared Reflectance Spectra Of 135 Hertha, 224 Oceana, 516 Amherstia, And 872 Holda

    Science.gov (United States)

    Hardersen, Paul S.; Gaffey, M. J.; Abell, P. A.

    2006-09-01

    Near-infrared reflectance spectra of M-asteroids 135 Hertha, 224 Oceana, 516 Amherstia, and 872 Holda display spectral and mineralogical diversity that is becoming the norm for the M-asteroid taxonomic group. 224 Oceana exhibits a traditionally featureless M-asteroid spectrum, moderately reddish slope, and an IRAS albedo of 17%. Canonical interpretations include a NiFe metal-rich surface or a surface similar to that of the enstatite chondrites. 516 Amherstia, with an IRAS albedo of 16%, displays absorption features centered at 0.93- and 1.92-microns superimposed on an overall reddish slope. This suggests a surface with a single mafic silicate (i.e., pyroxene, Wo10±4Fs31±5) and NiFe metal. The Band I and II absorptions are 5% and 2% deep, respectively. Amherstia's features are similar to, but somewhat more intense and Fe-rich than, other M-asteroid spectra as discussed in Hardersen et al. (2005). 872 Holda displays a generally featureless NIR reflectance spectrum with the exception of a very broad and weak ( 2% depth) absorption that ranges from 0.5 to 1.2-microns. 872 Holda's overall spectrum is similar to that of synthetic troilite, but differs from spectra of meteoritic troilite as discussed in Cloutis and Burbine (1999). If troilite is present on Holda's surface, then a potential interpretation is a mixture of NiFe metal and troilite as seen in iron meteorites. The NIR reflectance spectrum for 135 Hertha will also be discussed and compared to this asteroid's 52-color survey spectrum, which indicates the presence of a weak 0.9-micron absorption feature. Of the 20 M-asteroid spectra that have been examined by this team thus far, 10 M-asteroids display the presence of low-Fe pyroxene absorption features at 0.9 microns, 3 suggest the presence of spinel, 2 indicate the presence of olivine, one suggests the possible presence of troilite, and 4 display featureless spectra that suggest a variety of potential interpretations.

  5. Non-invasive identification of metal-oxalate complexes on polychrome artwork surfaces by reflection mid-infrared spectroscopy.

    Science.gov (United States)

    Monico, Letizia; Rosi, Francesca; Miliani, Costanza; Daveri, Alessia; Brunetti, Brunetto G

    2013-12-01

    In this work a reflection mid-infrared spectroscopy study of twelve metal-oxalate complexes, of interest in art conservation science as alteration compounds, was performed. Spectra of the reference materials highlighted the presence of derivative-like and/or inverted features for the fundamental vibrational modes as result of the main contribution from the surface component of the reflected light. In order to provide insights in the interpretation of theses spectral distortions, reflection spectra were compared with conventional transmission ones. The Kramers-Kronig (KK) algorithm, employed to correct for the surface reflection distortions, worked properly only for the derivative-like bands. Therefore, to pay attention to the use of this algorithm when interpreting the reflection spectra is recommended. The outcome of this investigation was exploited to discriminate among different oxalates on thirteen polychrome artworks analyzed in situ by reflection mid-infrared spectroscopy. The visualization of the νs(CO) modes (1400-1200 cm(-1)) and low wavenumber bands (below 900 cm(-1)) in the raw reflection profiles allowed Ca, Cu and Zn oxalates to be identified. Further information about the speciation of different hydration forms of calcium oxalates were obtained by using the KK transform. The work proves reflection mid-infrared spectroscopy to be a reliable and sensitive spectro-analytical method for identifying and mapping different metal-oxalate alteration compounds on the surface of artworks, thus providing conservation scientists with a non-invasive tool to obtain information on the state of conservation and causes of alteration of artworks. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Detection of Polarized Infrared Emission by Polycyclic Aromatic Hydrocarbons in the MWC 1080 Nebula

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Han; Telesco, Charles M.; Pantin, Eric; Barnes, Peter [Department of Astronomy, University of Florida, Gainesville, FL 32611 (United States); Hoang, Thiem [Korea Astronomy and Space Science Institute 776, Daedeokdae-ro, Yuseong-gu, Daejeon 34055 (Korea, Republic of); Li, Aigen [Department of Physics and Astronomy, University of Missouri, Columbia, MO 65211 (United States); Wright, Christopher M. [School of Physical, Environmental and Mathematical Sciences, UNSW Canberra, P.O. Box 7916, Canberra BC 2610 (Australia); Li, Dan, E-mail: hanzh0420@ufl.edu [Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, PA 19104 (United States)

    2017-07-20

    Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in astrophysical environments, as revealed by their pronounced emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 μ m commonly ascribed to the C–H and C–C vibrational modes. Although these features have long been predicted to be polarized, previous searches for PAH polarization led to null or, at best, tentative detections. Here we report the definite detection of polarized PAH emission at 11.3 μ m in the nebula associated with the Herbig Be star MWC 1080. We measure a polarization degree of 1.9% ± 0.2%, which is unexpectedly high compared to models. This poses a challenge in the current understanding of the alignment of PAHs, which is required to polarize the PAH emission but thought to be substantially suppressed. PAH alignment with a magnetic field via a resonance paramagnetic relaxation process may account for such a high level of polarization.

  7. Detection of Polarized Infrared Emission by Polycyclic Aromatic Hydrocarbons in the MWC 1080 Nebula

    International Nuclear Information System (INIS)

    Zhang, Han; Telesco, Charles M.; Pantin, Eric; Barnes, Peter; Hoang, Thiem; Li, Aigen; Wright, Christopher M.; Li, Dan

    2017-01-01

    Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in astrophysical environments, as revealed by their pronounced emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 μ m commonly ascribed to the C–H and C–C vibrational modes. Although these features have long been predicted to be polarized, previous searches for PAH polarization led to null or, at best, tentative detections. Here we report the definite detection of polarized PAH emission at 11.3 μ m in the nebula associated with the Herbig Be star MWC 1080. We measure a polarization degree of 1.9% ± 0.2%, which is unexpectedly high compared to models. This poses a challenge in the current understanding of the alignment of PAHs, which is required to polarize the PAH emission but thought to be substantially suppressed. PAH alignment with a magnetic field via a resonance paramagnetic relaxation process may account for such a high level of polarization.

  8. Methods for quantitative infrared directional-hemispherical and diffuse reflectance measurements using an FTIR and a commercial integrating sphere

    Energy Technology Data Exchange (ETDEWEB)

    Blake, Thomas A.; Johnson, Timothy J.; Tonkyn, Russell G.; Forland, Brenda M.; Myers, Tanya L.; Brauer, Carolyn S.; Su, Yin-Fong; Bernacki, Bruce E.; Hanssen, Leonard; Gonzalez, Gerardo

    2018-01-01

    Infrared integrating sphere measurements of solid samples are important in providing reference data for contact, standoff and remote sensing applications. At the Pacific Northwest National Laboratory (PNNL) we have developed protocols to measure both the directional-hemispherical ( and diffuse (d) reflectances of powders, liquids, and disks of powders and solid materials using a commercially available, matte gold-coated integrating sphere and Fourier transform infrared spectrometer. Detailed descriptions of the sphere alignment and its use for making these reflectance measurements are given. Diffuse reflectance values were found to be dependent on the bidirectional reflection distribution function (BRDF) of the sample and the solid angle intercepted by the sphere’s specular exclusion port. To determine how well the sphere and protocols produce quantitative reflectance data, measurements were made of three diffuse and two specular standards prepared by the National institute of Standards and Technology (NIST, USA), LabSphere Infragold and Spectralon standards, hand-loaded sulfur and talc powder samples, and water. The five NIST standards behaved as expected: the three diffuse standards had a high degree of “diffuseness,” d/ = D > 0.9, whereas the two specular standards had D ≤ 0.03. The average absolute differences between the NIST and PNNL measurements of the NIST standards for both directional-hemispherical and diffuse reflectances are on the order of 0.01 reflectance units. Other quantitative differences between the PNNL-measured and calibration (where available) or literature reflectance values for these standards and materials are given and the possible origins of discrepancies are discussed. Random uncertainties and estimates of systematic uncertainties are presented. Corrections necessary to provide better agreement between the PNNL reflectance values as measured for the NIST standards and the NIST reflectance values for these same standards are also

  9. Removal of Chromophore-proximal Polar Atoms Decreases Water Content and Increases Fluorescence in a Near Infrared Phytofluor

    Directory of Open Access Journals (Sweden)

    Heli eLehtivuori

    2015-11-01

    Full Text Available Genetically encoded fluorescent markers have revolutionized cell and molecular biology due to their biological compatibility, controllable spatiotemporal expression, and photostability. To achieve in vivo imaging in whole animals, longer excitation wavelength probes are needed due to the superior ability of near infrared light to penetrate tissues unimpeded by absorbance from biomolecules or autofluorescence of water. Derived from near infrared-absorbing bacteriophytochromes, phytofluors are engineered to fluoresce in this region of the electromagnetic spectrum, although high quantum yield remains an elusive goal. An invariant aspartate residue is of utmost importance for photoconversion in native phytochromes, presumably due to the proximity of its backbone carbonyl to the pyrrole ring nitrogens of the biliverdin (BV chromophore as well as the size and charge of the side chain. We hypothesized that the polar interaction network formed by the charged side chain may contribute to the decay of the excited state via proton transfer. Thus, we chose to further probe the role of this amino acid by removing all possibility for polar interactions with its carboxylate side chain by incorporating leucine instead. The resultant fluorescent protein, WiPhy2, maintains BV binding, monomeric status, and long maximum excitation wavelength while minimizing undesirable protoporphyrin IXα binding in cells. A crystal structure and time-resolved fluorescence spectroscopy reveal that water near the BV chromophore is excluded and thus validate our hypothesis that removal of polar interactions leads to enhanced fluorescence by increasing the lifetime of the excited state. This new phytofluor maintains its fluorescent properties over a broad pH range and does not suffer from photobleaching. WiPhy2 achieves the best compromise to date between high fluorescence quantum yield and long illumination wavelength in this class of fluorescent proteins.

  10. Evaluation of various polyethylene as potential dosimeters by attenuated total reflectance-Fourier-transform infrared spectroscopy

    International Nuclear Information System (INIS)

    Halperin, Fred; Collins, Greta; DiCicco, Michael; Logar, John

    2014-01-01

    Various types of polyethylene (PE) have been evaluated in the past for use as a potential dosimeter, chiefly via the formation of an unsaturated transvinylene (TV) double-bond resulting from exposure to ionizing radiation. The utilization of attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy in characterizing TV formation in irradiated PE for a potential dosimeter has yet to be fully developed. In this initial investigation, various PE films/sheets were exposed to ionizing radiation in a high-energy 5 megaelectron volt (MeV) electron beam accelerator in the 10–500 kilogray (kGy) dose range, followed by ATR-FTIR analysis of TV peak formation at the 965 cm −1 wavenumber. There was an upward trend in TV formation for low-density polyethylene (LDPE) films and high-density polyethylene (HDPE) sheets as a function of absorbed dose in the 10–50 kGy dose range, however, the TV response could not be equated to a specific absorbed dose. LDPE film displayed a downward trend from 50 kGy to 250 kGy and then scattering up to 500 kGy; HDPE sheets demonstrated an upward trend in TV formation up to 500 kGy. For ultra-high molecular weight polyethylene (UHMWPE) sheets irradiated up to 150 kGy, TV response was equivalent to non-irradiated UHMWPE, and a minimal upward trend was observed for 200 kGy to 500 kGy. The scatter of the data for the irradiated PE films/sheets is such that the TV response could not be equated to a specific absorbed dose. A better correlation of the post-irradiation TV response to absorbed dose may be attained through a better understanding of variables. - Highlights: • Various types of PE films/sheets have been evaluated for use as a potential dosimeter. • Attenuated total reflectance FTIR spectroscopy was utilized to analyze transvinylene formation in irradiated PE films/sheets. • PE films/sheets were exposed to ionizing radiation using a 5 MeV high-energy electron beam accelerator. • Analysis of TV peak formation at

  11. Near infrared reflectance spectroscopy for the fast identification of PVC-based films.

    Science.gov (United States)

    Laasonen, M; Rantanen, J; Harmia-Pulkkinen, T; Michiels, E; Hiltunen, R; Räsänen, M; Vuorela, H

    2001-07-01

    Near infrared (NIR) reflectance spectroscopy was used to develop a non-destructive and rapid qualitative method for the analysis of plastic films used by the pharmaceutical industry for blistering. Three types of films were investigated: 250 microm PVC [poly(vinyl chloride)] films, 250 microm PVC films coated with 40 g m(-2) of PVDC [poly(vinylidene dichloride)] and 250 microm PVC films coated with 5 g m(-2) of TE (Thermoelast) and 90 g m(-2) of PVDC. Three analyses were carried out using different pre-treatment options and a PLS (partial least squares) algorithm. Each analysis was aimed at identifying one type of film and rejecting all types of false sample (different thickness, colour or layer). True and false samples from four plastics manufacturers were included in the calibration sets in order to obtain robust methods that were suitable regardless of the supplier. Specificity was demonstrated by testing validation sets against the methods. The tests showed 0% of type I (false negative identification) and 1% of type II errors (false positive identification) for the PVC method, 13 and 3%, respectively, for the PVC-PVDC method and no error for the PVC-TE-PVDC method. Type II errors, mostly due to the slight sensitivity of the methods to film thickness, are easily corrected by simple thickness measurements. This study demonstrates that NIR spectroscopy is an excellent tool for the identification of PVC-based films. The three methods can be used by the pharmaceutical industry or plastics manufacturers for the quality control of films used in blister packaging.

  12. Determining the mineral composition in Cucurbita pepo fruit using near infrared reflectance spectroscopy.

    Science.gov (United States)

    Martínez-Valdivieso, Damián; Font, Rafael; Gómez, Pedro; Blanco-Díaz, Teresa; Del Río-Celestino, Mercedes

    2014-12-01

    Efforts through conventional breeding to improve the mineral content in horticultural crops have not always been successful mainly due to the fact that standard analytical methods are both costly and time-consuming. We investigated the feasibility of applying near infrared reflectance spectroscopy (NIRS) to the estimation of essential mineral composition in the skin and flesh of summer squash fruits (Cucurbita pepo subsp. pepo) using a 200-sample set from diverse morphotypes. The coefficients of determination in the external validation (R(2) VAL) obtained for the skin and flesh of the fruit were: total mineral content, 0.84 and 0.70; P, 0.74 and 0.62; K, 0.83 and 0.67; Ca, 0.57 and 0.60; Mg, 0.78 and 0.45; Fe, 0.78 and 0.65; Cu, 0.67 and 0.66; Mn, 0.67 and 0.64; Zn, 0.80 and 0.79 and Na, 0.33 and 0.33; respectively. NIRS combined with different spectral transformations by modified partial least-squares (MPLS) regression has shown to be useful in determining the mineral composition of summer squash fruit, being a fast and low-cost analytical technique. Components such as chlorophyll, starch and lipids were used by MPLS for modelling the predicting equations. The promotion of micronutrient-rich summer squash varieties could have a significant long-term beneficial impact on the health of mineral deficient human populations. © 2014 Society of Chemical Industry.

  13. Centrifugal ultrafiltration of human serum for improving immunoglobulin A quantification using attenuated total reflectance infrared spectroscopy.

    Science.gov (United States)

    Elsohaby, Ibrahim; McClure, J Trenton; Riley, Christopher B; Bryanton, Janet; Bigsby, Kathryn; Shaw, R Anthony

    2018-02-20

    Attenuated total reflectance infrared (ATR-IR) spectroscopy is a simple, rapid and cost-effective method for the analysis of serum. However, the complex nature of serum remains a limiting factor to the reliability of this method. We investigated the benefits of coupling the centrifugal ultrafiltration with ATR-IR spectroscopy for quantification of human serum IgA concentration. Human serum samples (n = 196) were analyzed for IgA using an immunoturbidimetric assay. ATR-IR spectra were acquired for whole serum samples and for the retentate (residue) reconstituted with saline following 300 kDa centrifugal ultrafiltration. IR-based analytical methods were developed for each of the two spectroscopic datasets, and the accuracy of each of the two methods compared. Analytical methods were based upon partial least squares regression (PLSR) calibration models - one with 5-PLS factors (for whole serum) and the second with 9-PLS factors (for the reconstituted retentate). Comparison of the two sets of IR-based analytical results to reference IgA values revealed improvements in the Pearson correlation coefficient (from 0.66 to 0.76), and the root mean squared error of prediction in IR-based IgA concentrations (from 102 to 79 mg/dL) for the ultrafiltration retentate-based method as compared to the method built upon whole serum spectra. Depleting human serum low molecular weight proteins using a 300 kDa centrifugal filter thus enhances the accuracy IgA quantification by ATR-IR spectroscopy. Further evaluation and optimization of this general approach may ultimately lead to routine analysis of a range of high molecular-weight analytical targets that are otherwise unsuitable for IR-based analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. Characterization and quantitation of aprepitant drug substance polymorphs by attenuated total reflectance fourier transform infrared spectroscopy.

    Science.gov (United States)

    Helmy, Roy; Zhou, George X; Chen, Yadan W; Crocker, Louis; Wang, Tao; Wenslow, Robert M; Vailaya, Anant

    2003-02-01

    In this study, we report the use of attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FT-IR) for the identification and quantitation of two polymorphs of Aprepitant, a substance P antagonist for chemotherapy-induced emesis. Mixtures of the polymorph pair were prepared by weight and ATR-FT-IR spectra of the powdered samples were obtained over the wavelength range of 700-1500 cm(-1). Significant spectral differences between the two polymorphs at 1140 cm(-1) show that ATR-FT-IR can provide definitive identification of the polymorphs. To investigate the feasibility of ATR-FT-IR for quantitation of polymorphic forms of Aprepitant, a calibration plot was constructed with known mixtures of the two polymorphs by plotting the peak ratio of the second derivative of absorbance spectra against the weight percent of form II in the polymorphic mixture. Using this novel approach, 3 wt % of one crystal form could be detected in mixtures of the two polymorphs. The accuracy of ATR-FT-IR in determining polymorph purity of the drug substance was tested by comparing the results with those obtained by X-ray powder diffractometry (XRPD). Indeed, polymorphic purity results obtained by ATR-FT-IR were found to be in good agreement with the predictions made by XRPD and compared favorably with actual values in the known mixtures. The present study clearly demonstrates the potential of ATR-FT-IR as a quick, easy, and inexpensive alternative to XRPD for the determination of polymorphic identity and purity of solid drug substances. The technique is ideally suited for polymorph analysis, because it is precise, accurate, and requires minimal sample preparation.

  15. The O2 A-Band in the Fluxes and Polarization of Starlight Reflected by Earth-Like Exoplanets

    Science.gov (United States)

    Fauchez, Thomas; Rossi, Loic; Stam, Daphne M.

    2017-06-01

    Earth-like, potentially habitable exoplanets are prime targets in the search for extraterrestrial life. Information about their atmospheres and surfaces can be derived by analyzing the light of the parent star reflected by the planet. We investigate the influence of the surface albedo A s, the optical thickness b cloud, the altitude of water clouds, and the mixing ratio of biosignature O2 on the strength of the O2 A-band (around 760 nm) in the flux and polarization spectra of starlight reflected by Earth-like exoplanets. Our computations for horizontally homogeneous planets show that small mixing ratios (η < 0.4) will yield moderately deep bands in flux and moderate-to-small band strengths in polarization, and that clouds will usually decrease the band depth in flux and the band strength in polarization. However, cloud influence will be strongly dependent on properties such as optical thickness, top altitude, particle phase, coverage fraction, and horizontal distribution. Depending on the surface albedo and cloud properties, different O2 mixing ratios η can give similar absorption-band depths in flux and band strengths in polarization, especially if the clouds have moderate-to-high optical thicknesses. Measuring both the flux and the polarization is essential to reduce the degeneracies, although it will not solve them, especially not for horizontally inhomogeneous planets. Observations at a wide range of phase angles and with a high temporal resolution could help to derive cloud properties and, once those are known, the mixing ratio of O2 or any other absorbing gas.

  16. Relationship between infrared and Raman intensities in molecules with polarized π electrons

    Science.gov (United States)

    Tommasini, M.; Castiglioni, C.; Del Zoppo, M.; Zerbi, G.

    1999-05-01

    A model is presented which allows to obtain a linear relationship between infrared and Raman intensity parameters of the strongest vibrational bands of push-pull conjugated molecules. The results obtained clarify the origin of the exceptionally large values of the vibrational first hyperpolarizability shown by these molecules.

  17. Assessment of polarization correction impact on the calibration of Terra MODIS reflective solar bands

    Science.gov (United States)

    Wu, Aisheng; Angal, Amit; Geng, Xu; Xiong, Xiaoxiong

    2017-09-01

    The Moderate-Resolution Imaging Spectroradiometer (MODIS), launched in 1999 on Terra and 2002 on Aqua spacecraft respectively, is a scanning radiometer that covers a wavelength range from 0.4 μm to 14.4 μm and scans the Earth over an angular range from -55° to +55°. After a few years in the Terra mission, it became extremely challenging to characterize the changes in the sensor gain and response versus scan angle (RVS) at short wavelengths due to significant degradation and increased polarization sensitivity. To better characterize the system-level degradation, the MODIS Characterization Support Team (MCST) developed an enhanced approach in Collection-6 (C6) L1B algorithm by supplementing the on-board calibration data with the Earth-scene response trends at various scan angles obtained from the pseudo-invariant desert sites. However, the trends at short wavelengths experienced significant impact due to the increased polarization sensitivity, especially at the end of scan. In this study, a polarization correction algorithm developed by MCST is applied to the Terra MODIS RSB response trends obtained from the desert sites. The trends after polarization correction are used to derive the gain and RVS based on the existing MODIS C6 calibration algorithm. Impact of the polarization correction is examined for gain, RVS and their fitting uncertainties over the entire mission. The results of this study provide useful information on how to further improve accuracy and stability of the calibrated L1B product.

  18. Solid polymer films exhibiting handedness-switchable, full-color-tunable selective reflection of circularly polarized light.

    Science.gov (United States)

    Nagata, Yuuya; Takagi, Keisuke; Suginome, Michinori

    2014-07-16

    Poly(quinoxaline-2,3-diyl)s bearing (S)-2-methylbutyl, n-butyl, and 8-chlorooctyl groups as side chains were synthesized to fabricate dry solid polymer thin films. These films exhibited selective reflection of right-handed circular polarized light (CPL) in the visible region after annealing in CHCl3 vapor at room temperature. The handedness of reflected CPL was inverted to the left after annealing in 1,2-dichloroethane vapor. It was also found that the color of a particular single film along with the handedness of reflected CPL were fully tuned reversibly, upon exposure of the film to the vapor of various mixtures of chloroform and 1,2-dichloroethane in different ratios.

  19. Transient Reactivity of Solid Silver Acetate in Hydrogen and Oxygen by In Situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy*

    OpenAIRE

    Tohru, KANNO; Masayoshi, KOBAYASHI

    1985-01-01

    The reactivity of solid silver acetate in hydrogen and oxygen has been studied by using the transient response method and the in situ diffuse reflectance infrared fourier transform spectroscopic (DKIFTS) technique to compare its nature to that of the reaction intermediates in ethylene oxidation. 0n the analysis of the transient response curves, solid silver acetate produced acetic acid and a small amount of carbon dioxide in a hydrogen stream, and produced CO_2 and a small amount of CH_3COOH ...

  20. The application of Near Infrared Reflectance Spectroscopy (NIRS) for the quantitative analysis of hydrocortisone in primary materials

    OpenAIRE

    A. PITTAS; C. SERGIDES; K. NIKOLICH

    2001-01-01

    Near Infrared Reflectance Spectroscopy (NIRS), coupled with fiber optic probes, has been shown to be a quick and reliable analytical tool for quality assurance and quality control in the pharmaceutical industry, both for verifications of raw materials and quantification of the active ingredients in final products. In this paper, a typical pharmaceutical product, hydrocortisone sodium succinate, is used as an example for the application of NIR spectroscopy for quality control. In order to deve...

  1. Processing of phase pure and dense bulk EuTiO.sub.3./sub. ceramics and their infrared reflectivity spectra

    Czech Academy of Sciences Publication Activity Database

    Kachlik, M.; Máca, K.; Goian, Veronica; Kamba, Stanislav

    2012-01-01

    Roč. 74, MAY (2012), s. 16-18 ISSN 0167-577X R&D Projects: GA ČR GD202/09/H041; GA ČR(CZ) GA202/09/0682 Grant - others:GAUK(CZ) SVV-2011-263303 Institutional research plan: CEZ:AV0Z10100520 Keywords : functional ceramics, * europium titanate * sintering * infrared reflectivity Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.224, year: 2012

  2. The Advantages of an Attenuated Total Internal Reflection Infrared Microspectroscopic Imaging Technique for the Analysis of Polymer Laminates.

    Science.gov (United States)

    Ling, Chen; Sommer, André J

    2015-06-01

    Until recently, the analysis of polymer laminates using infrared microspectroscopy involved the painstaking separation of individual layers by dissection or by obtaining micrometer thin cross-sections. The latter usually requires the expertise of an individual trained in microtomy and even then, the very structure of the laminate could affect the outcome of the spectral results. The recent development of attenuated total internal reflection (ATR) infrared microspectroscopy imaging has provided a new avenue for the analysis of these multilayer structures. This report compares ATR infrared microspectroscopy imaging with conventional transmission infrared microspectroscopy imaging. The results demonstrate that the ATR method offers improved spatial resolution, eliminates a variety of competing optical processes, and requires minimal sample preparation relative to transmission measurements. These advantages were illustrated using a polymer laminate consisting of 11 different layers whose thickness ranged in size from 4-20 μm. The spatial resolution achieved by using an ATR-FTIR (Fourier transform infrared spectroscopy) imaging technique was diffraction limited. Contrast in the ATR images was enhanced by principal component analysis.

  3. Phototaxis and polarotaxis hand in hand: night dispersal flight of aquatic insects distracted synergistically by light intensity and reflection polarization.

    Science.gov (United States)

    Boda, Pál; Horváth, Gábor; Kriska, György; Blahó, Miklós; Csabai, Zoltán

    2014-05-01

    Based on an earlier observation in the field, we hypothesized that light intensity and horizontally polarized reflected light may strongly influence the flight behaviour of night-active aquatic insects. We assumed that phototaxis and polarotaxis together have a more harmful effect on the dispersal flight of these insects than they would have separately. We tested this hypothesis in a multiple-choice field experiment using horizontal test surfaces laid on the ground. We offered simultaneously the following visual stimuli for aerial aquatic insects: (1) lamplit matte black canvas inducing phototaxis alone, (2) unlit shiny black plastic sheet eliciting polarotaxis alone, (3) lamplit shiny black plastic sheet inducing simultaneously phototaxis and polarotaxis, and (4) unlit matte black canvas as a visually unattractive control. The unlit matte black canvas trapped only a negligible number (13) of water insects. The sum (16,432) of the total numbers of water beetles and bugs captured on the lamplit matte black canvas (7,922) and the unlit shiny black plastic sheet (8,510) was much smaller than the total catch (29,682) caught on the lamplit shiny black plastic sheet. This provides experimental evidence for the synergistic interaction of phototaxis (elicited by the unpolarized direct lamplight) and polarotaxis (induced by the strongly and horizontally polarized plastic-reflected light) in the investigated aquatic insects. Thus, horizontally polarizing artificial lamplit surfaces can function as an effective ecological trap due to this synergism of optical cues, especially in the urban environment.

  4. Organic-inorganic hybrid optical foils with strong visible reflection, excellent near infrared-shielding ability and high transparency.

    Science.gov (United States)

    Zhou, Yijie; Huang, Aibin; Zhou, Huaijuan; Ji, Shidong; Jin, Ping

    2018-03-02

    Research on functional flexible films has recently been attracting widespread attention especially with regards to foils, which can be designed artificially on the basis of the practical requirements. In this work, a foil with high visible reflection and a strong near infrared shielding efficiency was prepared by a simple wet chemical method. In the process of making this kind of optical foil, emulsion polymerization was first introduced to synthesize polymer opals, which were further compressed between two pieces of polyethylene terephthalate (PET) foil under polymer melting temperature to obtain a photonic crystal film with a strong reflection in the visible region to block blue rays. The following step was to coat a layer of the inorganic nano paint, which was synthesized by dispersing Cs-doped WO 3 (CWO) nanoparticles homogenously into organic resin on the surface of the PET to achieve a high near infrared shielding ability. The final composite foil exhibited unique optical properties such as high visible reflectance (23.9%) to block blue rays, and excellent near infrared shielding efficiency (98.0%), meanwhile it still maintained a high transparency meaning that this foil could potentially be applied in energy-saving window films. To sum up, this study provides new insight into devising flexible hybrid films with novel optical properties, which could be further extended to prepare other optical films for potential use in automobile, architectural and other decorative fields.

  5. Reflectance infrared spectroscopy for in-line monitoring of nicotine during a coating process for an oral thin film.

    Science.gov (United States)

    Hammes, Florian; Hille, Thomas; Kissel, Thomas

    2014-02-01

    A process analytical method using reflectance infrared spectrometry was developed for the in-line monitoring of the amount of the active pharmaceutical ingredient (API) nicotine during a coating process for an oral thin film (OTF). In-line measurements were made using a reflectance infrared (RI) sensor positioned after the last drying zone of the coating line. Real-time spectra from the coating process were used for modelling the nicotine content. Partial least squares (PLS1) calibration models with different data pre-treatments were generated. The calibration model with the most comparable standard error of calibration (SEC) and the standard error of cross validation (SECV) was selected for an external validation run on the production coating line with an independent laminate. Good correlations could be obtained between values estimated from the reflectance infrared data and the reference HPLC test method, respectively. With in-line measurements it was possible to allow real-time adjustments during the production process to keep product specifications within predefined limits hence avoiding loss of material and batch. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Organic-inorganic hybrid optical foils with strong visible reflection, excellent near infrared-shielding ability and high transparency

    Science.gov (United States)

    Zhou, Yijie; Huang, Aibin; Zhou, Huaijuan; Ji, Shidong; Jin, Ping

    2018-03-01

    Research on functional flexible films has recently been attracting widespread attention especially with regards to foils, which can be designed artificially on the basis of the practical requirements. In this work, a foil with high visible reflection and a strong near infrared shielding efficiency was prepared by a simple wet chemical method. In the process of making this kind of optical foil, emulsion polymerization was first introduced to synthesize polymer opals, which were further compressed between two pieces of polyethylene terephthalate (PET) foil under polymer melting temperature to obtain a photonic crystal film with a strong reflection in the visible region to block blue rays. The following step was to coat a layer of the inorganic nano paint, which was synthesized by dispersing Cs-doped WO3 (CWO) nanoparticles homogenously into organic resin on the surface of the PET to achieve a high near infrared shielding ability. The final composite foil exhibited unique optical properties such as high visible reflectance (23.9%) to block blue rays, and excellent near infrared shielding efficiency (98.0%), meanwhile it still maintained a high transparency meaning that this foil could potentially be applied in energy-saving window films. To sum up, this study provides new insight into devising flexible hybrid films with novel optical properties, which could be further extended to prepare other optical films for potential use in automobile, architectural and other decorative fields.

  7. Predicting ambient aerosol thermal-optical reflectance measurements from infrared spectra: elemental carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-10-01

    Elemental carbon (EC) is an important constituent of atmospheric particulate matter because it absorbs solar radiation influencing climate and visibility and it adversely affects human health. The EC measured by thermal methods such as thermal-optical reflectance (TOR) is operationally defined as the carbon that volatilizes from quartz filter samples at elevated temperatures in the presence of oxygen. Here, methods are presented to accurately predict TOR EC using Fourier transform infrared (FT-IR) absorbance spectra from atmospheric particulate matter collected on polytetrafluoroethylene (PTFE or Teflon) filters. This method is similar to the procedure developed for OC in prior work (Dillner and Takahama, 2015). Transmittance FT-IR analysis is rapid, inexpensive and nondestructive to the PTFE filter samples which are routinely collected for mass and elemental analysis in monitoring networks. FT-IR absorbance spectra are obtained from 794 filter samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to collocated TOR EC measurements. The FT-IR spectra are divided into calibration and test sets. Two calibrations are developed: one developed from uniform distribution of samples across the EC mass range (Uniform EC) and one developed from a uniform distribution of Low EC mass samples (EC normalized error (21 %). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision and accuracy to collocated TOR measurements. Only the normalized error is higher for the FT-IR EC measurements than for collocated TOR. FT-IR spectra are also divided into calibration and test sets by the ratios OC/EC and ammonium/EC to determine the impact of OC and ammonium on EC prediction. We conclude that FT-IR analysis with

  8. RETRACTED: Modeling and imprint fabrication of an infrared wire-grid polarizer with an antireflection grating structure

    Science.gov (United States)

    Yamada, Itsunari; Yamashita, Naoto; Einishi, Toshihiko; Saito, Mitsunori; Fukumi, Kouhei; Nishii, Junji

    2014-05-01

    This article has been retracted: please see Elsevier Policy on Article Withdrawal (http://www.elsevier.com/locate/withdrawalpolicy). This article has been retracted at the request of the Editor and the authors as they/the authors acknowledged extensive overlap between an earlier published article of Applied Physics Express1 and the current article. The authors would like to apologize to the Editors and readers for this situation. 1Itsunari Yamada, Naoto Yamashita, Kunihiko Tani, Toshihiko Einishi, Mitsunori Saito, Kouhei Fukumi and Junji Nishii, Infrared Wire-Grid Polarizer with Antireflection Structure by Imprinting on Both Sides. Appl. Phys. Express (2012). http://dx.doi.org/10.1143/APEX.5.082502

  9. Use of infrared thermography to detect thermal segregation in asphalt overlay and reflective cracking potential.

    Science.gov (United States)

    2015-03-01

    The objectives of this study were to assess whether temperature differentials measured using Infrared : Thermography (IRT) occur in an overlay built on top of discontinuities such as joints and cracks and to : study the horizontal and vertical therma...

  10. Co-adsorption of oxygen and formic acid on rutile TiO2 (110) studied by infrared reflection-absorption spectroscopy

    Science.gov (United States)

    Mattsson, Andreas; Österlund, Lars

    2017-09-01

    Adsorption of formic acid and co-adsorption with oxygen have been investigated on the rutile TiO2(110) surface using p- and s-polarized infrared reflection-absorption spectroscopy (IRRAS) at O2 exposures between 45 L to 8100 L and at temperatures between 273 K and 343 K. On the clean surface formic acid dissociates into a formate ion (formate) and a proton. Formate binds to two five-fold coordinated Ti atoms in the troughs along the [001] direction, and the proton binds to neighboring bridging O atoms. Exposure of adsorbed formate to O2 leads to a decrease in the asymmetric νas(OCO) band at 1532 cm-1 and to the concomitant formation of a new vibration band at 1516 cm-1. From the s-and p-polarized IRRAS measurements performed at different O2 exposures, surface pre-treatments and substrate temperatures, and by comparisons with previous reports, we conclude that the new species is a bidentate surface hydrogen carbonate, which is formed by reaction between formate and oxygen adatoms on the surface. The σv reflection plane of the surface hydrogen carbonate molecule is oriented along the [001] direction, i.e. the same direction as the adsorbed formate molecule. On the clean TiO2(110) surface exposed to O2 prior to formic acid adsorption, similar results are obtained. The reaction rate to form surface hydrogen carbonate from formate is found to follow first-order kinetics, with an apparent activation energy of Er=0.25 eV.

  11. Electromagnetic radiation energy arrangement. [coatings for solar energy absorption and infrared reflection

    Science.gov (United States)

    Lipkis, R. R.; Vehrencamp, J. E. (Inventor)

    1965-01-01

    A solar energy collector and infrared energy reflector is described which comprises a vacuum deposited layer of aluminum of approximately 200 to 400 Angstroms thick on one side of a substrate. An adherent layer of titanium with a thickness of between 800 and 1000 Angstroms is vacuum deposited on the aluminum substrate and is substantially opaque to solar energy and substantially transparent to infrared energy.

  12. Polarized light for horizontal incidence and reflection by plane-parallel atmospheres

    NARCIS (Netherlands)

    Hovenier, J.W.; Stam, D.M.

    2007-01-01

    We show that the intensity vector of light reflected by a plane-parallel atmosphere is discontinuous if the directions of incidence and reflection are both horizontal. An exact expression describing the discontinuity is presented. This expression shows that the discontinuity is only due to first

  13. Influence of the tilting reflection mirror on the temperature and wind velocity retrieved by a polarizing atmospheric Michelson interferometer.

    Science.gov (United States)

    Zhang, Chunmin; Li, Ying

    2012-09-20

    The principles of a polarizing atmospheric Michelson interferometer are outlined. The tilt of its reflection mirror results in deflection of the reflected beam and affects the intensities of the observed inteferogram. This effect is systematically analyzed. Both rectangular and circular apertures are considered. The theoretical expression of the modulation depth and phase of the interferogram are derived. These parameters vary with the inclination angle of the mirror and the distance between the deflection center and the optical axis and significantly influence the retrieved temperature and wind speed. If the wind and temperature errors are required to be less than 3 m/s and 5 K, the deflection angle must be less than 0.5°. The errors are also dependent on the shape of aperture. If the reflection mirror is deflected in one direction, the temperature error is smaller for a circular aperture (1.3 K) than for a rectangular one (2.6 K), but the wind velocity errors are almost the same (less than 3 m/s). If the deflection center and incident light beam are coincident, the temperature errors are 3 × 10(-4) K and 0.45 K for circular and rectangular apertures, respectively. The wind velocity errors are 1.2 × 10(-3) m/s and 0.06 m/s. Both are small. The result would be helpful for theoretical research and development of the static polarization wind imaging interferometer.

  14. Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: organic carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-03-01

    Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, organic carbon is measured from a quartz fiber filter that has been exposed to a volume of ambient air and analyzed using thermal methods such as thermal-optical reflectance (TOR). Here, methods are presented that show the feasibility of using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters to accurately predict TOR OC. This work marks an initial step in proposing a method that can reduce the operating costs of large air quality monitoring networks with an inexpensive, non-destructive analysis technique using routinely collected PTFE filter samples which, in addition to OC concentrations, can concurrently provide information regarding the composition of organic aerosol. This feasibility study suggests that the minimum detection limit and errors (or uncertainty) of FT-IR predictions are on par with TOR OC such that evaluation of long-term trends and epidemiological studies would not be significantly impacted. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least-squares regression is used to calibrate sample FT-IR absorbance spectra to TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date. The calibration produces precise and accurate TOR OC predictions of the test set samples by FT-IR as indicated by high coefficient of variation (R2; 0.96), low bias (0.02 μg m-3, the nominal IMPROVE sample volume is 32.8 m3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision to collocated TOR measurements. FT-IR spectra are also

  15. Comparison of Attenuated Total Reflectance Mid-Infrared, Near Infrared, and 1H-Nuclear Magnetic Resonance Spectroscopies for the Determination of Coffee’s Geographical Origin

    Directory of Open Access Journals (Sweden)

    Jessica Medina

    2017-01-01

    Full Text Available The sensorial properties of Colombian coffee are renowned worldwide, which is reflected in its market value. This raises the threat of fraud by adulteration using coffee grains from other countries, thus creating a demand for robust and cost-effective methods for the determination of geographical origin of coffee samples. Spectroscopic techniques such as Nuclear Magnetic Resonance (NMR, near infrared (NIR, and mid-infrared (mIR have arisen as strong candidates for the task. Although a body of work exists that reports on their individual performances, a faithful comparison has not been established yet. We evaluated the performance of 1H-NMR, Attenuated Total Reflectance mIR (ATR-mIR, and NIR applied to fraud detection in Colombian coffee. For each technique, we built classification models for discrimination by species (C. arabica versus C. canephora (or robusta and by origin (Colombia versus other C. arabica using a common set of coffee samples. All techniques successfully discriminated samples by species, as expected. Regarding origin determination, ATR-mIR and 1H-NMR showed comparable capacity to discriminate Colombian coffee samples, while NIR fell short by comparison. In conclusion, ATR-mIR, a less common technique in the field of coffee adulteration and fraud detection, emerges as a strong candidate, faster and with lower cost compared to 1H-NMR and more discriminating compared to NIR.

  16. Invited Article: An active terahertz polarization converter employing vanadium dioxide and a metal wire grating in total internal reflection geometry

    Science.gov (United States)

    Liu, Xudong; Chen, Xuequan; Parrott, Edward P. J.; Han, Chunrui; Humbert, Georges; Crunteanu, Aurelian; Pickwell-MacPherson, Emma

    2018-05-01

    Active broadband terahertz (THz) polarization manipulation devices are challenging to realize, but also of great demand in broadband terahertz systems. Vanadium dioxide (VO2) shows a promising phase transition for active control of THz waves and provides broadband polarization characteristics when integrated within grating-type structures. We creatively combine a VO2-based grating structure with a total internal reflection (TIR) geometry providing a novel interaction mechanism between the electromagnetic waves and the device, to realize a powerful active broadband THz polarization-controlling device. The device is based on a Si-substrate coated with a VO2 layer and a metal grating structure on top, attached to a prism for generating the TIR condition on the Si-VO2-grating interface. The grating is connected to electrodes for electrically switching the VO2 between its insulating and conducting phases. By properly selecting the incident angle of the THz waves, the grating direction, and the incident polarization state, we first achieved a broadband intensity modulator under a fused silica prism with an average modulation depth of 99.75% in the 0.2-1.1 THz region. Additionally, we realized an active ultra-broadband quarter-wave converter under a Si prism that can be switched between a 45° linear rotator and a quarter wave converter in the 0.8-1.5 THz region. This is the first demonstration of an active quarter-wave converter with ultra-broad bandwidth performance. Our work shows a highly flexible and multifunctional polarization-controlling device for broadband THz applications.

  17. Analysis of peripheral thermal damage after laser irradiation of dentin using polarized light microscopy and synchrotron radiation infrared spectromicroscopy

    Science.gov (United States)

    Dela Rosa, Alfredo; Sarma, Anupama V.; Le, Charles Q.; Jones, Robert S.; Fried, Daniel

    2004-05-01

    It is necessary to minimize peripheral thermal damage during laser irradiation, since thermal damage to collagen and mineral compromises the bond strength to restorative materials in dentin and inhibits healing and osteointegration in bone. The overall objective of this study was to test the hypothesis that lasers resonant to the specific absorption of water, collagen, and hydroxyapatite with pulse durations less than the thermal relaxation times at each respective laser wavelength will efficiently remove dentin with minimal peripheral thermal damage. Precise incisions were produced in 3 x 3 mm2 blocks of human dentin using CO2 (9.6 μm), Er:YSGG (2.79 μm), and Nd:YAG (355 nm) lasers with and without a computer controlled water spray. Polarization-sensitive optical coherence tomography was used to obtain optical cross-sections of each incision to determine the rate and efficiency of ablation. The peripheral thermal damage zone around each incision was analyzed using polarized light microscopy (PLM) and Synchrotron-Radiation Fourier Transform Infrared Spectro-microscopy (SR-FTIR). Thermally induced chemical changes to both mineral and the collagen matrix was observed with SR-FTIR with a 10-μm spatial resolution and those changes were correlated with optical changes observed with PLM. Minimal (alveolar bone.

  18. Dual-band and polarization-independent infrared absorber based on two-dimensional black phosphorus metamaterials.

    Science.gov (United States)

    Wang, Jiao; Jiang, Yannan; Hu, Zhirun

    2017-09-04

    Two-dimensional (2D) black phosphorus (BP) with direct band gap, bridges the characteristics of graphene with a zero or near-zero band gap and transition metal dichalcogenides with a wide band gap. In the infrared (IR) regime, 2D BP materials can attenuate electromagnetic energy due to losses derived from its surface conductivity. This paper proposes an IR absorber based on 2D BP metamaterials. It consists of multi-layer BP-based nano-ribbon pairs, each formed by two orthogonally stacked nano-ribbons. The multi-layer BP metamaterials and bottom gold mirror together form a Fabry-Perot resonator that could completely inhibit light transmission to create strong absorption through the BP metamaterials. Unlike previously reported BP metamaterial absorbers, this new structure can operate at two frequency bands with absorption > 90% in each owning to the first-order and second-order Fabry-Perot resonant frequencies. It is also polarization independent due to the fourfold rotational structural symmetry. To our best knowledge, this is the first report on using BP metamaterials in an absorber that operates independent of polarization and in dual bands.

  19. Lateral refraction and reflection of light polarized lenses principle. Coplanar lens systems

    International Nuclear Information System (INIS)

    Miranda, L.

    2012-01-01

    Studying the behavior of the linearly polarized light to impact a lens and in the lens itself, resulted in the discovery of a physical principle of optics, not mentioned or used so far. This phenomenon is very useful in practice. Perhaps the manifestation of the phenomenon occurs in the plane perpendicular to the road or optical axis, is due the reason that was not seen before, but it has always been there when polarized light passes through a lens. Known and mastered the principle has been manipulated for better research results, using for the first time a planar lens system, which according to the placement of the lens allows for accurate lags between the light beams ar the exits the system. (Author)

  20. Classification of Fusarium-Infected Korean Hulled Barley Using Near-Infrared Reflectance Spectroscopy and Partial Least Squares Discriminant Analysis.

    Science.gov (United States)

    Lim, Jongguk; Kim, Giyoung; Mo, Changyeun; Oh, Kyoungmin; Yoo, Hyeonchae; Ham, Hyeonheui; Kim, Moon S

    2017-09-30

    The purpose of this study is to use near-infrared reflectance (NIR) spectroscopy equipment to nondestructively and rapidly discriminate Fusarium -infected hulled barley. Both normal hulled barley and Fusarium -infected hulled barley were scanned by using a NIR spectrometer with a wavelength range of 1175 to 2170 nm. Multiple mathematical pretreatments were applied to the reflectance spectra obtained for Fusarium discrimination and the multivariate analysis method of partial least squares discriminant analysis (PLS-DA) was used for discriminant prediction. The PLS-DA prediction model developed by applying the second-order derivative pretreatment to the reflectance spectra obtained from the side of hulled barley without crease achieved 100% accuracy in discriminating the normal hulled barley and the Fusarium -infected hulled barley. These results demonstrated the feasibility of rapid discrimination of the Fusarium -infected hulled barley by combining multivariate analysis with the NIR spectroscopic technique, which is utilized as a nondestructive detection method.

  1. Blood glucose measurement in vivo using hollow-fiber based, mid-infrared ATR probe with multi-reflection prism

    Science.gov (United States)

    Kino, Saiko; Omori, Suguru; Matsuura, Yuji

    2016-03-01

    An attenuated-total-reflection (ATR), mid-infrared spectroscopy system that consists of hollow optical fibers, a trapezoidal multi-reflection ATR prism, and a conventional FT-IR spectrometer has been developed to measure blood glucose levels. Owing to the low transmission loss and high flexibility of the hollow-optical fiber, the system can measure any sites of the human body where blood capillaries are close to the surface of mucosa, such as inner lips. Using a multi-reflection prism brought about higher sensitivity, and the flat and wide contact surface of the prism resulted in higher measurement reproducibility. The results of in-vivo measurement of human inner lips showed the feasibility of the proposed system, and the measurement errors were within 20%.

  2. The Performance of Reflecting Multichannel Collimators as a Neutron Beam Filter and Polarizer

    DEFF Research Database (Denmark)

    Bjerrum Møller, Hans; Passell, L.; Stecher-Rasmussen, F.

    1963-01-01

    Summarizes the results obtained to date from a study of the properties of reflecting multi-channel collimators. The measurements have not yet been completed but enough information is available to give an indication of the capabilities of the system.......Summarizes the results obtained to date from a study of the properties of reflecting multi-channel collimators. The measurements have not yet been completed but enough information is available to give an indication of the capabilities of the system....

  3. Application of infrared reflection and Raman spectroscopy for quantitative determination of fat in potato chips

    Science.gov (United States)

    Mazurek, Sylwester; Szostak, Roman; Kita, Agnieszka

    2016-12-01

    Potato chips are important products in the snack industry. The most significant parameter monitored during their quality control process is fat content. The Soxhlet method, which is applied for this purpose, is time consuming and expensive. We demonstrate that both infrared and Raman spectroscopy can effectively replace the extraction method. Raman, mid-infrared (MIR) and near-infrared (NIR) spectra of the homogenised laboratory-prepared chips were recorded. On the basis of obtained spectra, partial least squares (PLS) calibration models were constructed. They were characterised by the values of relative standard errors of prediction (RSEP) in the 1.0-1.9% range for both calibration and validation data sets. Using the developed models, six commercial products were successfully quantified with recovery in the 98.5-102.3% range against the AOAC extraction method. The proposed method for fat quantification in potato chips based on Raman spectroscopy can be easily adopted for on-line product analysis.

  4. Predicting ambient aerosol Thermal Optical Reflectance (TOR) measurements from infrared spectra: elemental carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-06-01

    Elemental carbon (EC) is an important constituent of atmospheric particulate matter because it absorbs solar radiation influencing climate and visibility and it adversely affects human health. The EC measured by thermal methods such as Thermal-Optical Reflectance (TOR) is operationally defined as the carbon that volatilizes from quartz filter samples at elevated temperatures in the presence of oxygen. Here, methods are presented to accurately predict TOR EC using Fourier Transform Infrared (FT-IR) absorbance spectra from atmospheric particulate matter collected on polytetrafluoroethylene (PTFE or Teflon) filters. This method is similar to the procedure tested and developed for OC in prior work (Dillner and Takahama, 2015). Transmittance FT-IR analysis is rapid, inexpensive, and non-destructive to the PTFE filter samples which are routinely collected for mass and elemental analysis in monitoring networks. FT-IR absorbance spectra are obtained from 794 filter samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to collocated TOR EC measurements. The FTIR spectra are divided into calibration and test sets. Two calibrations are developed, one which is developed from uniform distribution of samples across the EC mass range (Uniform EC) and one developed from a~uniform distribution of low EC mass samples (EC TOR EC samples in the same mass range and an estimate of the minimum detection limit (MDL) that is on par with TOR EC MDL. For all samples, this hybrid approach leads to precise and accurate TOR EC predictions by FT-IR as indicated by high coefficient of variation (R2; 0.96), no bias (0.00 μg m-3, concentration value based on the nominal IMPROVE sample volume of 32.8 m-3), low error (0.03 μg m-3) and reasonable normalized error (21 %). These performance metrics can be achieved with various degrees of spectral pretreatment

  5. CO adsorption on Pd(100) studied by multimodal ambient pressure X-ray photoelectron and infrared reflection absorption spectroscopies

    Science.gov (United States)

    Head, Ashley R.; Karslıoǧlu, Osman; Gerber, Timm; Yu, Yi; Trotochaud, Lena; Raso, Joseph; Kerger, Philipp; Bluhm, Hendrik

    2017-11-01

    The adsorption of CO on Pd(100) was investigated using simultaneous ambient pressure X-ray photoelectron spectroscopy (APXPS) and infrared reflection absorption infrared spectroscopy (IRRAS). The measurements were performed as a function of CO partial pressures from ultra-high vacuum to 0.5 Torr. Total CO coverages estimated from the complementary APXPS and IRRAS measurements are in good agreement. A signal for atop CO, which is uncommon for Pd(100), was observed in the IRRAS data and was used to identify the C 1 s binding energy of this species. Discerning this binding configuration of CO on the Pd(100) surface at elevated pressures has significance for catalytic reactions involving CO, where bridging CO is often the only configuration considered. We also detail the combined APXPS/IRRAS instrumentation and discuss ways to improve these multimodal measurements, which should have wide applicability across many areas of surface and interface science.

  6. Ultraviolet, optical, and infrared observations of the intermediate polar TV Columbae

    Science.gov (United States)

    Mateo, M.; Szkody, P.; Hutchings, J.

    1985-01-01

    Forty-three IUE spectra of the X-ray discovered, triply periodic cataclysmic variable, TV Col are examined. The results show that the UV flux varies with the four-day period discovered by Motch in 1981. By fitting continuum models to the UV and optical fluxes, it is inferred that this modulation corresponds to the periodic heating of a normally 9000 K source within the binary system due to reprocessing of beamed X-ray and (possibly) EUV radiation from the vicinity of the degenerate star. The observed flux from this heated source is consistent with its origin at either the disk hot spot or the secondary star. Phasing arguments, however, favor the identification of the latter as the primary reprocessing site in the system. The infrared observations are not consistent with the model proposed by Watts et al. in 1982 and imply that the four-day period does not correspond to the orbital period of the binary.

  7. Temporal and spectral studies of high-order harmonics generated by polarization-modulated infrared fields

    International Nuclear Information System (INIS)

    Sola, I. J.; Zaier, A.; Cormier, E.; Mevel, E.; Constant, E.; Lopez-Martens, R.; Johnsson, P.; Varju, K.; Mauritsson, J.; L'Huillier, A.; Strelkov, V.

    2006-01-01

    The temporal confinement of high harmonic generation (HHG) via modulation of the polarization of the fundamental pulse is studied in both temporal and spectral domains. In the temporal domain, a collinear cross-correlation setup using a 40 fs IR pump for the HHG and a 9 fs IR pulse to probe the generated emission is used to measure the XUV pulse duration. The observed temporal confinement is found to be consistent with theoretical predictions. An increased confinement is observed when a 9 fs pulse is used to generate the harmonics. An important spectral broadening, including a continuum background, is also measured. Theoretical calculations show that with 10 fs driving pulses, either one or two main attosecond pulses are created depending on the value of the carrier envelope phase

  8. Measurements of size and composition of particles in polar stratospheric clouds from infrared solar absorption spectra

    International Nuclear Information System (INIS)

    Kinne, S.; Toon, O.B.; Toon, G.C.; Farmer, C.B.; Browell, E.V.; McCormick, M.P.

    1989-01-01

    The attenuation of solar radiation between 1.8- and 15-μm wavelength was measured with the airborne Jet Propulsion Laboratory Mark IV interferometer during the Airborne Antarctic Ozone Expedition in 1987. The measurements not only provide information about the abundance of stratospheric gases, but also about the optical depths of polar stratospheric clouds (PSCs) at wavelengths of negligible gas absorption. The spectral dependence of the PSC optical depth contains information about PSC particle size and particle composition. Thirty-three PSC cases were analyzed and categorized into two types. Type I clouds contain particles with radii of about 0.5 μm and nitric acid concentrations greater than 40%. Type II clouds contain particles composed of water ice with radii of 6 μm and larger. Cloud altitudes were determined from 1.064-μm backscattering observations of the airborne Langley DIAL lidar system. Based on the PSC geometrical thickness, both mass and particle density were estimated. Type I clouds typically had visible wavelength optical depths of about 0.008, mass densities of about 20 ppb, and about 2 particles/cm 3 . The observed type II clouds had optical depths of about 0.03, mass densities of about 400 ppb mass, and about 0.03 particles/cm 3 . The detected PSC type I clouds extended to altitudes of 21 km and were nearly in the ozone-depleted region of the polar stratosphere. The observed type II cases during September were predominantly found at altitudes below 15 km

  9. Measurement of anchoring coefficient of homeotropically aligned nematic liquid crystal using a polarizing optical microscope in reflective mode

    Directory of Open Access Journals (Sweden)

    Sang-In Baek

    2015-09-01

    Full Text Available Although the homeotropic alignment of liquid crystals is widely used in LCD TVs, no easy method exists to measure its anchoring coefficient. In this study, we propose an easy and convenient measurement technique in which a polarizing optical microscope is used in the reflective mode with an objective lens having a low depth of focus. All measurements focus on the reflection of light near the interface between the liquid crystal and alignment layer. The change in the reflected light is measured by applying an electric field. We model the response of the director of the liquid crystal to the electric field and, thus, the change in reflectance. By adjusting the extrapolation length in the calculation, we match the experimental and calculated results and obtain the anchoring coefficient. In our experiment, the extrapolation lengths were 0.31 ± 0.04 μm, 0.32 ± 0.08 μm, and 0.23 ± 0.05 μm for lecithin, AL-64168, and SE-5662, respectively.

  10. Infrared analysis of urinary calculi by a single reflection accessory and a neural network interpretation algorithm

    NARCIS (Netherlands)

    Volmer, M; de Vries, JCM; Goldschmidt, HMJ

    Background: Preparation of KBr tablets, used for Fourier transform infrared (FT-IR) analysis of urinary calculus composition, is time-consuming and often hampered by pellet breakage. We developed a new F:T-IR method for urinary calculus analysis. This method makes use of a Golden Gate Single

  11. ITER-like wide-angle infrared thermography and visible observation diagnostic using reflective optics

    NARCIS (Netherlands)

    Gauthier, E.; Roche, H.; Thomas, E.; Droineau, S.; Bertrand, B.; Migozzi, J.B.; Vliegenthart, W.A.; Dague, L.; Andrew, P.; Tiscornia, T.; Sands, D.

    2007-01-01

    Control of the plasma-wall interaction during transient events will be a critical issue in ITER. A new ITER-like wide-angle infrared and visible diagnostic, allowing to observe plasma wall interaction in the main chamber, has been installed on JET. The design and the manufacture of the diagnostic

  12. Quantitative structural analysis of lignin by diffuse reflectance fourier transform infrared spectrometry

    International Nuclear Information System (INIS)

    Schultz, T.P.; Glasser, W.G.

    1986-01-01

    Empirical quantitative relationships were established between infrared (IR) spectral information and several structural features in lignins as determined by conventional methods. The structural composition of average phenylpropane (C g ) units which significantly correlated (0.01 level) with IR peak intensities included methoxy content, aromatic hydrogen content, phenolic hydroxy content, guaiacyl/syringyl ratio, and ''hydrolysis'' and ''condensation'' ratios

  13. The use of near infra-red reflectance spectroscopy for the ...

    African Journals Online (AJOL)

    The applicability of the NIRS ryegrass calibration to other species was briefly examined by estimating the N content of Kikuyu (Penisetum clandestinum) (r = 0, 97 and SEP = 0, 277). Keywords: italian ryegrass; kikuyu; lolium multiflorum; near infra-red spectroscopy; nitrogen; plant physiology; protein; regression analysis; ...

  14. Hyperspectral near-infrared reflectance imaging for detection of defect tomatoes

    Science.gov (United States)

    Cuticle cracks on tomatoes are potential sites of pathogenic infection that may cause deleterious consequences both to consumer health and to fresh and fresh-cut produce markets. The feasibility of a hyperspectral near-infrared imaging technique in the spectral range of 1000 nm to 1700 nm was inves...

  15. Diffuse Reflectance Spectroscopy of Hidden Objects, Part I: Interpretation of the Reflection-Absorption-Scattering Fractions in Near-Infrared (NIR) Spectra of Polyethylene Films.

    Science.gov (United States)

    Pomerantsev, Alexey L; Rodionova, Oxana Ye; Skvortsov, Alexej N

    2017-08-01

    Investigation of a sample covered by an interfering layer is required in many fields, e.g., for process control, biochemical analysis, and many other applications. This study is based on the analysis of spectra collected by near-infrared (NIR) diffuse reflectance spectroscopy. Each spectrum is a composition of a useful, target spectrum and a spectrum of an interfering layer. To recover the target spectrum, we suggest using a new phenomenological approach, which employs the multivariate curve resolution (MCR) method. In general terms, the problem is very complex. We start with a specific problem of analyzing a system, which consists of several layers of polyethylene (PE) film and underlayer samples with known spectral properties. To separate information originating from PE layers and the target, we modify the system versus both the number of the PE layers as well as the reflectance properties of the target sample. We consider that the interfering spectrum of the layer can be modeled using three components, which can be tentatively called transmission, absorption, and scattering contributions. The novelty of our approach is that we do not remove the reflectance and scattering effects from the spectra, but study them in detail aiming to use this information to recover the target spectrum.

  16. Polarization resolved imaging with a reflection near-field optical microscope

    DEFF Research Database (Denmark)

    Bozhevolnyi, Sergey I.; Xiao, Mufei; Hvam, Jørn Märcher

    1999-01-01

    Using a rigorous microscopic point-dipole description of probe-sample interactions, we study imaging with a reflection scanning near-field optical microscope. Optical content, topographical artifacts, sensitivity window-i.e., the scale on which near-field optical images represent mainly optical c...

  17. Infrared reflection spectra of multilayer epitaxial heterostructures with embedded InAs and GaAs layers

    International Nuclear Information System (INIS)

    Seredin, P. V.; Domashevskaya, E. P.; Lukin, A. N.; Arsent'ev, I. N.; Vinokurov, D. A.; Tarasov, I. S.

    2008-01-01

    The effect of the thickness of embedded InAs and GaAs layers on the infrared reflection spectra of lattice vibrations for AlInAs/InAs/AlInAs, InGaAs/GaAs/InGaAs, and AlInAs/InGaAs/GaAs/InGaAs/AlInAs multilayer epitaxial heterostructures grown by MOC hydride epitaxy on InP (100) substrates is studied. Relative stresses emerging in the layers surrounding the embedded layers with variation in the number of monolayers from which the quantum dots are formed and with variation the thickness of the layers themselves surrounding the embedded layers are evaluated.

  18. Surface temperatures in the polar regions from Nimbus 7 temperature humidity infrared radiometer

    Science.gov (United States)

    Comiso, Josefino C.

    1994-01-01

    Monthly surface temperatures in the Arctic and Antarctic regions have been derived from the 11.5 micrometer thermal infrared channel of the Nimbus 7 temperature humidity infrared radiometer (THIR) for a whole year in 1979 and for a winter and a summer month from 1980 through 1985. The data set shows interannual variability and provides spatial details that allow identification of temperature patterns over sea ice and ice sheet surfaces. For example, the coldest spot in the southern hemisphere is observed to be consistently in the Antarctic plateau in the southern hemisphere, while that in the northern hemisphere is usually located in Greenland, or one of three other general areas: Siberia, the central Arctic, or the Canadian Archipelago. Also, in the southern hemisphere, the amplitude of the seasonal fluctuation of ice sheet temperatures is about 3 times that of sea ice, while in the northern hemisphere, the corresponding fluctuations for the two surfaces are about the same. The main sources of error in the retrieval are cloud and other atmospheric effects. These were minimized by first choosing the highest radiance value from the set of measurements during the day taken within a 30 km by 30 km grid of each daily map. Then the difference of daily maps was taken and where the difference is greater than a certain threshold (which in this case is 12 C), the data element is deleted. Overall, the monthly maps derived from the resulting daily maps are spatially and temporally consistent, are coherent with the topograph y of the Antarctic continent and the location of the sea ice edge, and are in qualitative agreement with climatological data. Quantitatively, THIR data are in good agreement with Antarctic ice sheet surface air temperature station data with a correlation coefficient of 0.997 and a standard deviation of 2.0 C. The absolute values are not as good over the sea ice edges, but a comparison with Russian 2-m drift station temperatures shows very high correlation

  19. Attenuated total reflection infrared difference spectroscopy (ATR-IRDS) for quantitative reaction monitoring.

    Science.gov (United States)

    Kiefer, Johannes; Cöngevel, Melek A; Roth, Daniel; Obert, Katharina; Wasserscheid, Peter; Leipertz, Alfred

    2012-06-01

    Monitoring of chemical reactors is key to optimizing yield and efficiency of chemical transformation processes. Aside from tracking pressure and temperature, the measurement of the chemical composition is essential in this context. We present an infrared difference spectroscopy approach for determining the reactant (cyclooctene) and product (cyclooctane) concentrations during a catalytic hydrogenation reaction in the solvent cyclohexane, which is present in large excess. Subtracting the spectrum of the pure solvent from the reactor mixture spectra yields infrared (IR) spectra, which can ultimately be evaluated using a curve-fitting procedure based on spectral soft modeling. An important feature of our evaluation approach is that the calibration only requires recording the pure component spectra of the reactants, products, and solvent. Hence, no time-consuming preparation of mixtures for calibration is necessary. The IR concentration results are in good agreement with gas chromatography measurements.

  20. Application of attenuated total reflection infrared spectroscopy in the study of Peruphasma schultei defensive secretion

    OpenAIRE

    Mcleod, Michael P.; Dossey, Aaron T.; Ahmed, M. Khalique

    2007-01-01

    In this short communication, we present the first Fourier Transform Infrared Absorbance (FT-IR) study of peruphasmal; a defensive secretion from Peruphasma schultei. The spectral data collected are representative of the natural product structure proposed by Dossey et al. This study demonstrates the viability of FT-IR as another tool in the physical and biological chemist's repertoire for use in determining important structural characteristics from minute amounts of available sample.

  1. Polarization contrast linear spectroscopies for cubic semiconductors under stress: macro- and micro-reflectance difference spectroscopies

    Energy Technology Data Exchange (ETDEWEB)

    Lastras-Martinez, L.F.; Balderas-Navarro, R.E.; Castro-Garcia, R.; Herrera-Jasso, R.; Lastras-Martinez, A. [Instituto de Investigacion en Comunicacion Optica, Universidad Autonoma de San Luis Potosi, Alvaro Obregon 64, 78000 San Luis Potosi, S.L.P. (Mexico); Chavira-Rodriguez, M. [Departamento de Fisico Matematicas, Universidad Autonoma de San Luis Potosi, Alvaro Obregon 64, 78000 San Luis Potosi, S.L.P. (Mexico)

    2011-01-15

    The technique to measure optical anisotropies (OA) in cubic semiconductors is termed either reflectance difference spectroscopy (RDS) or reflectance anisotropy spectroscopy (RAS). In this paper we report on the application of RDS/RAS to a number of cubic semiconductors. We discuss RD spectra of GaAs, Si, CdTe, GaP, InP and GaSb (001) surfaces, induced by an uniaxial stress applied along [110] crystal directions. We show that all RD spectra can be explained in terms of a phenomenological model based on a perturbative Hamiltonian. We further report on measurements of spatial-resolved RDS measurements of GaAs employing a newly developed micro-RD spectrometer with a spatial resolution of 5 {mu}m. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  2. Determination of oxygen content and carbonate impurity in YBa2Cu3O7-x by diffuse reflectance infrared spectroscopy

    International Nuclear Information System (INIS)

    Merzbacher, C.I.; Bonner, B.P.

    1991-01-01

    Samples of YBa 2 Cu 3 O 7-x with x ranging from ∼0 to 0.65 have been analyzed by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) in the midinfrared region (400--6000 cm -1 ). Spectral line shapes vary gradually as a function of oxygen stoichiometry, and the reflectance at 400 and 1000 cm -1 decreases linearly with decreasing oxygen content. Spectra of samples that were incompletely synthesized or exposed to a 4% CO 2 atmosphere at 650 degree C clearly indicated the presence of carbonate. DRIFTS is therefore a quick, nondestructive method for determining oxygen content in YBa 2 Cu 3 O 7-x powders, and for detecting carbonate species due to synthesis error or reaction with CO 2 -bearing atmosphere

  3. Visible and Near-Infrared Leaf Reflectance Spectra, 1992-1993 (ACCP)

    Data.gov (United States)

    National Aeronautics and Space Administration — Visible/NIR reflectance spectra data for both fresh and dry leaf samples were collected to determine the relationship of foliar chemical concentrations with...

  4. Polarized matrix infrared spectra of cyclopentadienone: observations, calculations, and assignment for an important intermediate in combustion and biomass pyrolysis.

    Science.gov (United States)

    Ormond, Thomas K; Scheer, Adam M; Nimlos, Mark R; Robichaud, David J; Daily, John W; Stanton, John F; Ellison, G Barney

    2014-01-30

    A detailed vibrational analysis of the infrared spectra of cyclopentadienone (C5H4═O) in rare gas matrices has been carried out. Ab initio coupled-cluster anharmonic force field calculations were used to guide the assignments. Flash pyrolysis of o-phenylene sulfite (C6H4O2SO) was used to provide a molecular beam of C5H4═O entrained in a rare gas carrier. The beam was interrogated with time-of-flight photoionization mass spectrometry (PIMS), confirming the clean, intense production of C5H4═O. Matrix isolation infrared spectroscopy coupled with 355 nm polarized UV for photoorientation and linear dichroism experiments was used to determine the symmetries of the vibrations. Cyclopentadienone has 24 fundamental vibrational modes, Γvib = 9a1 ⊕ 3a2 ⊕ 4b1 ⊕ 8b2. Using vibrational perturbation theory and a deperturbation-diagonalization method, we report assignments of the following fundamental modes (cm(-1)) in a 4 K neon matrix: the a1 modes of X̃ (1)A1 C5H4═O are found to be ν1 = 3107, ν2 = (3100, 3099), ν3 = 1735, ν5 = 1333, ν7 = 952, ν8 = 843, and ν9 = 651; the inferred a2 modes are ν10 = 933, and ν11 = 722; the b1 modes are ν13 = 932, ν14 = 822, and ν15 = 629; the b2 fundamentals are ν17 = 3143, ν18 = (3078, 3076) ν19 = (1601 or 1595), ν20 = 1283, ν21 = 1138, ν22 = 1066, ν23 = 738, and ν24 = 458. The modes ν4 and ν6 were too weak to be detected, ν12 is dipole-forbidden and its position cannot be inferred from combination and overtone bands, and ν16 is below our detection range (calculations, assigned as two quantum transitions, and used to assign some of the weak and infrared inactive fundamental vibrations.

  5. Predicting Clear-Sky Reflectance Over Snow/Ice in Polar Regions

    Science.gov (United States)

    Chen, Yan; Sun-Mack, Sunny; Arduini, Robert F.; Hong, Gang; Minnis, Patrick

    2015-01-01

    Satellite remote sensing of clouds requires an accurate estimate of the clear-sky radiances for a given scene to detect clouds and aerosols and to retrieve their microphysical properties. Knowing the spatial and angular variability of clear-sky albedo is essential for predicting clear-sky radiance at solar wavelengths. The Clouds and the Earth's Radiant Energy System (CERES) Project uses the nearinfrared (NIR; 1.24, 1.6 or 2.13 micrometers), visible (VIS; 0.63 micrometers) and vegetation (VEG; 0.86 micrometers) channels available on the Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) to help identify clouds and retrieve their properties in both snow-free and snow-covered conditions. Thus, it is critical to have reliable distributions of clear-sky albedo for all of these channels. In CERES Edition 4 (Ed4), the 1.24-micrometer channel is used to retrieve cloud optical depth over snow/ice-covered surfaces. Thus, it is especially critical to accurately predict the 1.24-micrometer clear-sky albedo alpha and reflectance rho for a given location and time. Snow albedo and reflectance patterns are very complex due to surface texture, particle shapes and sizes, melt water, and vegetation protrusions from the snow surface. To minimize those effects, this study focuses on the permanent snow cover of Antarctica where vegetation is absent and melt water is minimal. Clear-sky albedos are determined as a function of solar zenith angle (SZA) from observations over all scenes determined to be cloud-free to produce a normalized directional albedo model (DRM). The DRM is used to develop alpha(SZA=0 degrees) on 10 foot grid for each season. These values provide the basis for predicting r at any location and set of viewing & illumination conditions. This paper examines the accuracy of this approach for two theoretical snow surface reflectance models.

  6. Reflectance and Thermal Infrared Spectroscopy of Mars: Relationship Between ISM and TES for Compositional Determinations

    Science.gov (United States)

    Boyce, Joseph (Technical Monitor); Mustard, John

    2004-01-01

    Reflectance spectroscopy has demonstrated that high albedo surfaces on Mars contain heavily altered materials with some component of hematite, poorly crystalline ferric oxides, and an undefined silicate matrix. The spectral properties of many low albedo regions indicate crystalline basalts containing both low and high calcium pyroxene, a mineralogy consistent with the basaltic SNC meteorites. The Thermal Emission Spectrometer (TES) experiment on the Mars Geochemical Surveyor has acquired critical new data relevant to surface composition and mineralogy, but in a wavelength region that is complementary to reflectance spectroscopy. The essence of the completed research was to analyze TES data in the context of reflectance data obtained by the French ISM imaging spectrometer experiment in 1989. This approach increased our understanding of the complementary nature of these wavelength regions for mineralogic determinations using actual observations of the martian surface. The research effort focused on three regions of scientific importance: Syrtis Major-Isidis Basin, Oxia Palus-Arabia, and Valles Marineris. In each region distinct spatial variations related to reflectance, and in derived mineralogic information and interpreted compositional units were analyzed. In addition, specific science questions related to the composition of volcanics and crustal evolution, soil compositions and pedogenic processes, and the relationship between pristine lithologies and weathering provided an overall science-driven framework for the work. The detailed work plan involved colocation of TES and ISM data, extraction of reflectance and emissivity spectra from areas of known reflectance variability, and quantitative analysis using factor analysis and statistical techniques to determine the degree of correspondence between these different wavelength regions. Identified coherent variations in TES spectroscopy were assessed against known atmospheric effects to validate that the variations

  7. Detection of Earth-rotation Doppler shift from Suomi National Polar-Orbiting Partnership Cross-Track Infrared Sounder.

    Science.gov (United States)

    Chen, Yong; Han, Yong; Weng, Fuzhong

    2013-09-01

    The Cross-Track Infrared Sounder (CrIS) on the Suomi National Polar-Orbiting Partnership Satellite is a Fourier transform spectrometer and provides a total of 1305 channels for sounding the atmosphere. Quantifying the CrIS spectral accuracy, which is directly related to radiometric accuracy, is crucial for improving its data assimilation in numerical weather prediction. In this study, a cross-correlation method is used for detecting the effect of Earth-rotation Doppler shift (ERDS) on CrIS observations. Based on a theoretical calculation, the ERDS can be as large as about 1.3 parts in 10(6) (ppm) near Earth's equator and at the satellite scan edge for a field of regard (FOR) of 1 or 30. The CrIS observations exhibit a relative Doppler shift as large as 2.6 ppm for a FOR pair of 1 and 30 near the equator. The variation of the ERDS with latitude and scan position detected from CrIS observations is similar to that derived theoretically, which indicates that the spectral stability of the CrIS instrument is very high. To accurately calibrate CrIS spectral accuracy, the ERDS effect should be removed. Since the ERDS is easily predictable, the Doppler shift is correctable in the CrIS spectra.

  8. To See the World in a Grain of Sand: Recognizing the Origin of Sand Specimens by Diffuse Reflectance Infrared Fourier Transform Spectroscopy and Multivariate Exploratory Data Analysis

    Science.gov (United States)

    Pezzolo, Alessandra De Lorenzi

    2011-01-01

    The diffuse reflectance infrared Fourier transform (DRIFT) spectra of sand samples exhibit features reflecting their composition. Basic multivariate analysis (MVA) can be used to effectively sort subsets of homogeneous specimens collected from nearby locations, as well as pointing out similarities in composition among sands of different origins.…

  9. Effect of near-infrared-radiation reflective screen materials on ventilation requirement, crop transpiration and water use efficiency of a greenhouse rose crop

    NARCIS (Netherlands)

    Stanghellini, C.; Jianfeng, D.; Kempkes, F.L.K.

    2011-01-01

    The effect of Near Infrared (NIR)-reflective screen material on ventilation requirement, crop transpiration and water use efficiency of a greenhouse rose crop was investigated in an experiment whereby identical climate was ensured in greenhouse compartments installed with either NIR-reflective or

  10. Deposition of nanocrystalline diamond films on temperature sensitive substrates for infrared reflectance spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Babchenko, Oleg; Remeš, Zdeněk; Ižák, Tibor; Rezek, Bohuslav; Kromka, Alexander

    2011-01-01

    Roč. 248, č. 11 (2011), s. 2736-2739 ISSN 0370-1972 R&D Projects: GA ČR(CZ) GAP108/11/0794; GA AV ČR KAN400100701; GA MŠk LC510; GA AV ČR(CZ) IAAX00100902; GA AV ČR(CZ) KAN400480701 Institutional research plan: CEZ:AV0Z10100521 Keywords : focused plasma * glass substrate * infrared spectroscopy * nanocrystalline diamond * surface wave plasma Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.316, year: 2011

  11. Attenuated total internal reflection infrared microspectroscopic imaging using a large-radius germanium internal reflection element and a linear array detector.

    Science.gov (United States)

    Patterson, Brian M; Havrilla, George J

    2006-11-01

    The number of techniques and instruments available for Fourier transform infrared (FT-IR) microspectroscopic imaging has grown significantly over the past few years. Attenuated total internal reflectance (ATR) FT-IR microspectroscopy reduces sample preparation time and has simplified the analysis of many difficult samples. FT-IR imaging has become a powerful analytical tool using either a focal plane array or a linear array detector, especially when coupled with a chemometric analysis package. The field of view of the ATR-IR microspectroscopic imaging area can be greatly increased from 300 x 300 microm to 2500 x 2500 microm using a larger internal reflection element of 12.5 mm radius instead of the typical 1.5 mm radius. This gives an area increase of 70x before aberrant effects become too great. Parameters evaluated include the change in penetration depth as a function of beam displacement, measurements of the active area, magnification factor, and change in spatial resolution over the imaging area. Drawbacks such as large file size will also be discussed. This technique has been successfully applied to the FT-IR imaging of polydimethylsiloxane foam cross-sections, latent human fingerprints, and a model inorganic mixture, which demonstrates the usefulness of the method for pharmaceuticals.

  12. One-dimensional photonic crystals with highly Bi-substituted iron garnet defect in reflection polar geometry

    International Nuclear Information System (INIS)

    Mikhailova, T V; Berzhansky, V N; Karavainikov, A V; Shaposhnikov, A N; Prokopov, A R; Lyashko, S D

    2016-01-01

    It is represented the results of modelling of magnetooptical properties in reflection polar geometry of one-dimensional photonic crystal, in which highly Bi-substituted iron garnet defect of composition Bi 1.0 Y 0.5 Gd 1.5 Fe 4.2 A l0.8 O 12 / Bi 2.8 Y 0.2 Fe 5 Oi 2 is located between the dielectric Bragg mirrors (SiO 2 / TiO 2 ) m (were m is number of layer pairs) and buffer SiO 2 and gold top layers of different thicknesses is placed on structure. The modification of spectral line- shapes of microcavity and Tamm plasmon-polariton modes depending on m is found. (paper)

  13. Detection of precancerous lesions in the oral cavity using oblique polarized reflectance spectroscopy: a clinical feasibility study

    Science.gov (United States)

    Bailey, Maria J.; Verma, Nishant; Fradkin, Leonid; Lam, Sylvia; MacAulay, Calum; Poh, Catherine; Markey, Mia K.; Sokolov, Konstantin

    2017-06-01

    We developed a multifiber optical probe for oblique polarized reflectance spectroscopy (OPRS) in vivo and evaluated its performance in detection of dysplasia in the oral cavity. The probe design allows the implementation of a number of methods to enable depth resolved spectroscopic measurements including polarization gating, source-detector separation, and differential spectroscopy; this combination was evaluated in carrying out binary classification tasks between four major diagnostic categories: normal, benign, mild dysplasia (MD), and severe dysplasia (SD). Multifiber OPRS showed excellent performance in the discrimination of normal from benign, MD, SD, and MD plus SD yielding sensitivity/specificity values of 100%/93%, 96%/95%, 100%/98%, and 100%/100%, respectively. The classification of benign versus dysplastic lesions was more challenging with sensitivity and specificity values of 80%/93%, 71%/93%, and 74%/80% in discriminating benign from SD, MD, and SD plus MD categories, respectively; this challenge is most likely associated with a strong and highly variable scattering from a keratin layer that was found in these sites. Classification based on multiple fibers was significantly better than that based on any single detection pair for tasks dealing with benign versus dysplastic sites. This result indicates that the multifiber probe can perform better in the detection of dysplasia in keratinized tissues.

  14. A Framework for Estimating the 30 m Thermal-Infrared Broadband Emissivity From Landsat Surface Reflectance Data

    Science.gov (United States)

    Cheng, Jie; Liu, Hao; Liang, Shunlin; Nie, Aixiu; Liu, Qiang; Guo, Yamin

    2017-11-01

    The land surface thermal-infrared broadband emissivity (BBE) is a vital variable for estimating land surface radiation budgets (SRBs). We develop a framework for retrieving the 30 m BBE from Landsat surface reflectance data to estimate SRBs at finer scales and validate coarse resolution data. In the developed framework, the land surface is classified as bare soils and vegetated surfaces to allow different algorithms to be used for the BBE estimation. We propose a downscaling algorithm that uses the empirical relationship between the Advanced Spaceborne Thermal Emission and Reflectance Radiometer (ASTER) BBE and Landsat surface reflectance at 90 m to retrieve the 30 m BBE over bare soils. A look-up table (LUT)-based algorithm is proposed for vegetated surfaces. The BBE is interpolated from a LUT that is constructed from the 4SAIL radiative transfer model with inputs of the leaf BBE, the soil background BBE, and the leaf area index (LAI). Ground measurements that were collected at 11 relatively homogeneous sandy sites during three independent field campaigns are used to validate the proposed algorithm over bare soils. The average difference between the retrieved and field-measured BBEs is 0.012. We produce the land surface BBE of China in 2008 by using the developed framework and composited winter and summer seasonal BBE maps. The composited seasonal BBE maps are compared to the seasonal BBE maps derived from the ASTER emissivity product. The bias is within ±0.005 over bare soils and ranges from 0.012 to 0.019 over vegetated surfaces. Combined with the validated results in this study and published references, the comparison results demonstrate the good performance of the developed framework. This study provides a new perspective on estimating BBEs from sensors with only a thermal-infrared channel.

  15. Improving the performance of infrared reflective night curtains for warming field plots

    DEFF Research Database (Denmark)

    Bruhn, Dan; Larsen, Klaus S.; de Dato, Giovanbattista D.

    2013-01-01

    the curtains and (iii) reducing the lateral wind speed. We provide experimentally based replies to the major concerns raised in the literature about the passive nighttime warming method. We show (a) that using IR-reflective curtains during night does in fact not result in nighttime warming only...

  16. Optical phonon features of triclinic montebrasite : dispersion analysis and non-polar Raman modes.

    OpenAIRE

    Almeida, Rafael M.; Höfer, Sonja; Mayerhöfer, Thomas G.; Popp, Jürgen; Krambrock, Klaus; Lobo, Ricardo P. S. M.; Dias, Anderson; Moreira, Roberto Luiz

    2015-01-01

    Polarized infrared and Raman spectra of triclinic LiAl(PO4)(OH) [montebrasite] single crystal were recorded for appropriate optical configurations. Dispersion analysis was applied on the infrared reflectivity spectra taken at low incidence angle (11 ) to determine the oscillator parameters and the dipole directions of the polar phonons. In particular, all the 27 polar phonons, predicted by group theory for triclinic P1 structure,were determined. The obtained dielectric tensor para...

  17. DUST IN THE POLAR REGION AS A MAJOR CONTRIBUTOR TO THE INFRARED EMISSION OF ACTIVE GALACTIC NUCLEI

    Energy Technology Data Exchange (ETDEWEB)

    Hoenig, S. F.; Antonucci, R. [Department of Physics, University of California in Santa Barbara, Broida Hall, Santa Barbara, CA 93109 (United States); Kishimoto, M.; Tristram, K. R. W.; Asmus, D.; Weigelt, G. [Max-Planck-Institut fuer Radioastronomie, Auf dem Huegel 69, D-53121 Bonn (Germany); Prieto, M. A. [Instituto de Astrofisica de Canarias, E-38200 La Laguna, Tenerife (Spain); Gandhi, P. [Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Burtscher, L. [Max-Planck-Institut fuer extraterrestrische Physik, Giessenbachstrae, D-85748 Garching (Germany); Duschl, W. J., E-mail: shoenig@physics.ucsb.edu [Institut fuer Theoretische Physik und Astrophysik, Christian-Albrechts-Universitaet zu Kiel, Leibnizstr. 15, D-24098, Kiel (Germany)

    2013-07-10

    Dust around active galactic nuclei (AGNs) is distributed over a wide range of spatial scales and can be observed in the infrared (IR). It is generally assumed that the distribution on parsec scales forms a geometrically and optically thick entity in the equatorial plane around the accretion disk and broad-line region-dubbed {sup d}ust torus{sup -}that emits the bulk of the subarcsecond-scale IR emission and gives rise to orientation-dependent obscuration. However, recent IR interferometry studies with unprecedented position angle (P.A.) and baseline coverage on these small scales in two obscured (type 2) AGNs have revealed that the majority of the mid-IR emission in these objects is elongated in the polar direction. These observations are difficult to reconcile with the standard interpretation that most of the parsec-scale mid-IR emission in AGNs originate from the torus and challenges the justification of using simple torus models to model the broadband IR emission. Here, we report detailed interferometry observations of the unobscured (type 1) AGN in NGC 3783 that allow us to constrain the size, elongation, and direction of the mid-IR emission with high accuracy. The mid-IR emission is characterized by a strong elongation toward position angle P.A. -52 Degree-Sign , closely aligned with the polar axis (P.A. -45 Degree-Sign ). We determine half-light radii along the major and minor axes at 12.5 {mu}m of (20.0 {+-} 3.0) mas Multiplication-Sign (6.7 {+-} 1.0) mas or (4.23 {+-} 0.63) pc Multiplication-Sign (1.42 {+-} 0.21) pc, which corresponds to intrinsically scaled sizes of (69.4 {+-} 10.8) r{sub in} Multiplication-Sign (23.3 {+-} 3.5) r{sub in} for the inner dust radius of r{sub in} = 0.061 pc as inferred from near-IR reverberation mapping. This implies an axis ratio of 3:1, with about 60%-90% of the 8-13 {mu}m emission associated with the polar-elongated component. It is quite likely that the hot-dust emission as recently resolved by near-IR interferometry is

  18. Near-infrared reflectance spectroscopy for predicting amino acids content in intact processed animal proteins.

    Science.gov (United States)

    De la Haba, Maria José; Garrido-Varo, Ana; Guerrero-Ginel, José Emilio; Pérez-Marín, Dolores C

    2006-10-04

    Near-infrared calibrations were developed for the instantaneous prediction of amino acids composition of processed animal proteins (PAPs). Two sample presentation modes were compared (ground vs intact) for demonstrating the viability of the analysis in the intact form, avoiding the need for milling. Modified partial least-squares (MPLS) equations for the prediction of amino acids in PAPs were developed using the same set of samples (N = 92 PAPs) analyzed in ground and intact form and in three cups differing in the optical window size. The standard error for cross validation (SECV) and the coefficient of determination (1-VR) values yielded with the calibrations developed using the samples analyzed in the intact form showed similar or even better accuracy than those obtained with finely ground samples. The excellent predictive ability (1-VR > 0.90; CV marketing of these important protein feed ingredients, alleviating the costs and time associated with the routine quality controls.

  19. [Near infrared reflectance spectroscopy (NIRS): a novel approach to reconstructing historical changes of primary productivity in Antarctic lake].

    Science.gov (United States)

    Chen, Qian-Qian; Liu, Xiao-Dong; Liu, Wen-Qi; Jiang, Shan

    2011-10-01

    Compared with traditional chemical analysis methods, reflectance spectroscopy has the advantages of speed, minimal or no sample preparation, non-destruction, and low cost. In order to explore the potential application of spectroscopy technology in the paleolimnological study on Antarctic lakes, we took a lake sediment core in Mochou Lake at Zhongshan Station of Antarctic, and analyzed the near infrared reflectance spectroscopy (NIRS) data in the sedimentary samples. The results showed that the factor loadings of principal component analysis (PCA) displayed very similar depth-profile change pattern with the S2 index, a reliable proxy for the change in historical lake primary productivity. The correlation analysis showed that the values of PCA factor loading and S2 were correlated significantly, suggesting that it is feasible to infer paleoproductivity changes recorded in Antarctic lakes using NIRS technology. Compared to the traditional method of the trough area between 650 and 700 nm, the authors found that the PCA statistical approach was more accurate for reconstructing the change in historical lake primary productivity. The results reported here demonstrate that reflectance spectroscopy can provide a rapid method for the reconstruction of lake palaeoenviro nmental change in the remote Antarctic regions.

  20. Measurement of sugar content of watermelon using near-infrared reflectance spectroscopy in comparison with dielectric property

    Science.gov (United States)

    Tao, Xuemei; Bao, Yidan

    2006-09-01

    The sugar content of watermelon is important to its taste thus influences the market. It's difficult to know whether the melon is sweet or not for consumers. We tried to develop a convenient meter to determine the sugar of watermelon. The first objective of this paper was to demonstrate the feasibility of using a near-infrared reflectance spectrometer (NIRS) to investigate the relationship between sugar content of watermelon and absorption spectra. The NIRS reflectance of nondestructive watermelon was measured with a Visible/NIR spectrophotometer in 325-1075nm range. The sugar content of watermelon was obtained with a handhold sugar content meter. The second objective was to measure the watermelon's dielectric property, such as dielectric resistance, capacitance, quality factor and dielectric loss. A digital electric bridge instrument was used to get the dielectric property. The experimental results show that they were related to watermelon's sugar content. A comparison between the two methods was made in the paper. The model derived from NIRS reflection is useful for class identification of Zaochun Hongyu watermelon though it's not quite accurate in sweetness prediction (the max. deviation is 0.7). Electric property bears little relation to sugar content of watermelon at this experiment and it couldn't be used as non-destructive inspection method.

  1. Discrimination of the hard keratins animal horn and chelonian shell using attenuated total reflection-infrared spectroscopy.

    Science.gov (United States)

    Biscardi, Brianna; Welsh, Wendy; Kennedy, Anthony

    2012-05-01

    The ability to discriminate between objects manufactured from animal horn and chelonian (turtle, tortoise, or terrapin) shell is important from a cultural and archeological perspective such that it may allow conservators to determine the appropriate treatment and long-term care solution. It would also aid curators in identifying and cataloging items manufactured from these materials. Discrimination and classification is also a valuable tool for those involved in tracking the illegal trade in restricted materials of this nature. Attenuated total reflection infrared (ATR-IR) spectroscopy, using a single reflection diamond internal reflection element (IRE), coupled with discrimination analysis was used to analyze a total of thirty-nine samples (29 calibration samples, 10 validation samples). A discrimination analysis model was constructed using Mahalanobis distances to classify spectra into one of two classes. The model was then subsequently used to successfully classify all validation samples and correctly identify them as animal horn or chelonian shell based on second-derivative spectra of the amide I and II regions. This technique requires minimal to no sample preparation and may be used to nondestructively identify very small samples successfully without performing detailed secondary structural curve-fitting routines. This model should be a valuable resource to museums, conservators, and wildlife management programs for rapidly and reliably discriminating between animal horn and chelonian shell.

  2. Visible near infrared diffuse reflectance spectroscopy (VisNIR DRS) for rapid measurement of organic matter in compost.

    Science.gov (United States)

    McWhirt, Amanda L; Weindorf, David C; Chakraborty, Somsubhra; Li, Bin

    2012-10-01

    Commercial compost is the inherently variable organic product of a controlled decomposition process. In the USA, assessment of compost's physicochemical parameters presently relies on standard laboratory analyses set forth in Test Methods for the Examination of Composting and Compost (TMECC). A rapid, field-portable means of assessing the organic matter (OM) content of compost products would be useful to help producers ensure optimal uniformity in their compost products. Visible near infrared diffuse reflectance spectroscopy (VisNIR DRS) is a rapid, proximal-sensing technology proven effective at quantifying organic matter levels in soils. As such, VisNIR DRS was evaluated to assess its applicability to compost. Thirty-six compost samples representing a wide variety of source materials and moisture content were collected and scanned with VisNIR DRS under moist and oven-dry conditions. Partial least squares (PLS) regression and principal component regression (PCR) were used to relate the VisNIR DRS spectra with laboratory-measured OM to build compost OM prediction models. Raw reflectance, and first- and second-derivatives of the reflectance spectra were considered. In general, PLS regression outperformed PCR and the oven-dried first-derivative PLS model produced an r(2) value of 0.82 along with a residual prediction deviation value of 1.72. As such, VisNIR DRS shows promise as a suitable technique for the analysis of compost OM content for dried samples.

  3. Trasmission and Reflection (ATR)Far-Infrared Spectroscopy Applied in the Analysis of Cultural Heritage Materials

    OpenAIRE

    Kendix, Elsebeth Langholz

    2009-01-01

    FIR spectroscopy is an alternative way of collecting spectra of many inorganic pigments and corrosion products found on art objects, which is not normally observed in the MIR region. Most FIR spectra are traditionally collected in transmission mode but as a real novelty it is now also possible to record FIR spectra in ATR (Attenuated Total Reflectance) mode. In FIR transmission we employ polyethylene (PE) for preparation of pellets by embedding the sample in PE. Unfortunately, ...

  4. Evidence for surface water ice in the lunar polar regions using reflectance measurements from the Lunar Orbiter Laser Altimeter and temperature measurements from the Diviner Lunar Radiometer Experiment

    Science.gov (United States)

    Fisher, Elizabeth A.; Lucey, Paul G.; Lemelin, Myriam; Greenhagen, Benjamin T.; Siegler, Matthew A.; Mazarico, Erwan; Aharonson, Oded; Williams, Jean-Pierre; Hayne, Paul O.; Neumann, Gregory A.; Paige, David A.; Smith, David E.; Zuber, Maria T.

    2017-08-01

    We find that the reflectance of the lunar surface within 5° of latitude of the South Pole increases rapidly with decreasing temperature, near ∼110 K, behavior consistent with the presence of surface water ice. The North polar region does not show this behavior, nor do South polar surfaces at latitudes more than 5° from the pole. This South pole reflectance anomaly persists when analysis is limited to surfaces with slopes less than 10° to eliminate false detection due to the brightening effect of mass wasting, and also when the very bright south polar crater Shackleton is excluded from the analysis. We also find that south polar regions of permanent shadow that have been reported to be generally brighter at 1064 nm do not show anomalous reflectance when their annual maximum surface temperatures are too high to preserve water ice. This distinction is not observed at the North Pole. The reflectance excursion on surfaces with maximum temperatures below 110 K is superimposed on a general trend of increasing reflectance with decreasing maximum temperature that is present throughout the polar regions in the north and south; we attribute this trend to a temperature or illumination-dependent space weathering effect (e.g. Hemingway et al., 2015). We also find a sudden increase in reflectance with decreasing temperature superimposed on the general trend at 200 K and possibly at 300 K. This may indicate the presence of other volatiles such as sulfur or organics. We identified and mapped surfaces with reflectances so high as to be unlikely to be part of an ice-free population. In this south we find a similar distribution found by Hayne et al. (2015) based on UV properties. In the north a cluster of pixels near that pole may represent a limited frost exposure.

  5. Rapid determination of the fat, moisture, and protein contents in homogenized chicken eggs based on near-infrared reflectance spectroscopy.

    Science.gov (United States)

    Zhao, Qingna; Lv, Xueze; Jia, Yaxiong; Chen, Yu; Xu, Guiyun; Qu, Lujiang

    2018-03-19

    Current analytical methods used for composition analysis of egg products are time consuming and laborious. We developed a near-infrared reflectance spectroscopy (NIRS)-based method to determine the fat, moisture, and protein contents in homogenized egg yolk and the moisture and protein contents in homogenized egg albumen to substitute for conventional methods. The coefficients of determination in the external validation set (R2P) were over 0.8 for all chemical compositions. The ratios of performance to standard deviation (RPD) were 4.38, 2.25, 2.28, 2.31, and 3.03 for fat, moisture, protein and moisture in the egg yolk, and protein in the egg albumen, respectively. Thus, NIR spectroscopy could be an efficient tool for quantitative analysis of the nutrients in chicken eggs.

  6. Soil profile organic carbon prediction with Visible Near Infrared Reflec-tance spectroscopy based on a national database

    DEFF Research Database (Denmark)

    Deng, Fan; Knadel, Maria; Peng, Yi

    This study focuses on the application of the Danish national soil Visible Near Infrared Re-flectance spectroscopy (NIRs) database for predicting SOC in a field. The Conditioned Latin hypercube sam-pling (cLHS) method was used for the selection of 120 soil profiles based on DualEM21s and DEM data...... (ele-vation, slope, profile curvature). All the soil profile cores were taken by a 1 m long hydraulic auger with plastic liners inside. A Labspec 5100 equipped with a contact probe was used to acquire spectra at (350-2500 nm) in each 5 cm depth interval. The results show that after the removal...... of moisture effect using an external parameter orthogonalisation algorithm, most of the spectra collected at field moisture content can be projected in the National spectra library. Moreover, the prediction of SOC improved compared to the model based on absorbance spectra....

  7. Direct determination of lycopene content in tomatoes (Lycopersicon esculentum) by attenuated total reflectance infrared spectroscopy and multivariate analysis.

    Science.gov (United States)

    Halim, Yuwana; Schwartz, Steven J; Francis, David; Baldauf, Nathan A; Rodriguez-Saona, Luis E

    2006-01-01

    Lycopene is a potent antioxidant that has been shown to play critical roles in disease prevention. Efficient assays for detection and quantification of lycopene are desirable as alternatives to time- and labor-intensive methods. Attenuated total reflectance infrared (ATR-IR) spectroscopy was used for quantification of lycopene in tomato varieties. Calibration models were developed by partial least-squares regression (PLSR) using quantitative measures of lycopene concentration from liquid chromatography as reference method. IR spectra showed a distinct marker band at 957 cm(-1) for trans Carbon-Hydrogen (CH) deformation vibration of lycopene. PLSR models predicted the lycopene content accurately and reproducibly with a correlation coefficient (sigma) of 0.96 and standard error of cross-validation ATR-IR spectroscopy allowed for rapid, simple, and accurate determination of lycopene in tomatoes with minimal sample preparation. Results suggest that the ATR-IR method is applicable for high-throughput quantitative analysis and screening for lycopene in tomatoes.

  8. Modeling and Forecasting of Depletion of Additives in Car Engine Oils Using Attenuated Total Reflectance Fast Transform Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Ronald Nguele

    2014-11-01

    Full Text Available On average, additives make up to 7% of a typical lubricant base. Commonly, they are blended with lube oils to enhance specific features thereby improving their qualities. Ultimately, additives participate in the performance of car engine oils. Using an analytical tool, attenuated total reflectance fast transform infrared spectroscopy, various grades of car engine oils, at different mileages, were analyzed. Sulfate oxidation and wear were found to trigger chemical processes which, in the long run, cause lubricant degradation while carbonyl oxidation was observed to occur only at a slow rate. Based upon data obtained from infrared spectra and using a curve fitting technique, mathematical equations predicting the theoretical rates of chemical change due to the aforementioned processes were examined. Additive depletions were found to obey exponential regression rather than polynomial. Moreover, breakpoint (breakpoint is used here to denote the initiation of deterioration of additives and critical mileage (critical mileage defines the distance at which the lubricant is chemically unusable of both samples were determined.

  9. The effect of grain size and phosphorous-doping of polycrystalline 3C-SiC on infrared reflectance spectra

    Energy Technology Data Exchange (ETDEWEB)

    Rooyen, I.J. van, E-mail: Isabella.vanRooyen@inl.gov [Fuel Performance and Design Department, Idaho National Laboratory, Idaho Falls, ID 83415-6188 (United States); Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Engelbrecht, J.A.A. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Henry, A.; Janzen, E. [Department of Physics, Chemistry and Biology, Semiconductor Materials, Linkoeping University, Linkoeping 58183 (Sweden); Neethling, J.H. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Rooyen, P.M. van [Philip M van Rooyen Network Consultants, Midlands Estates (South Africa)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer IR is investigated as a technique to measure grain size and P-doping of polycrystalline SiC. Black-Right-Pointing-Pointer Infrared plasma minima can be used to determine doping levels in 3C-SiC for doping levels greater than 5 Multiplication-Sign 10{sup 17} cm{sup -3}. Black-Right-Pointing-Pointer A linear relationship is found between FWHM and the inverse of grain size of 3C-SiC irrespective of P-doping level. Black-Right-Pointing-Pointer It is further found that {omega}{sub p} is not influenced by the grain size. Black-Right-Pointing-Pointer P-doping level has no significant effect on the linear relationship between grain size and surface roughness. - Abstract: The effect of P-doping and grain size of polycrystalline 3C-SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behavior of the 3C-SiC with the highest phosphorous doping level (of 1.2 Multiplication-Sign 10{sup 19} at. cm{sup -3}) is different from those with lower doping levels (<6.6 Multiplication-Sign 10{sup 18} at. cm{sup -3}). It is also further demonstrated that the plasma resonance frequency ({omega}{sub p}) is not influenced by the grain size.

  10. The effect of grain size and phosphorous-doping of polycrystalline 3C–SiC on infrared reflectance spectra

    International Nuclear Information System (INIS)

    Rooyen, I.J. van; Engelbrecht, J.A.A.; Henry, A.; Janzén, E.; Neethling, J.H.; Rooyen, P.M. van

    2012-01-01

    Highlights: ► IR is investigated as a technique to measure grain size and P-doping of polycrystalline SiC. ► Infrared plasma minima can be used to determine doping levels in 3C–SiC for doping levels greater than 5 × 10 17 cm −3 . ► A linear relationship is found between FWHM and the inverse of grain size of 3C–SiC irrespective of P-doping level. ► It is further found that ω p is not influenced by the grain size. ► P-doping level has no significant effect on the linear relationship between grain size and surface roughness. - Abstract: The effect of P-doping and grain size of polycrystalline 3C–SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behavior of the 3C–SiC with the highest phosphorous doping level (of 1.2 × 10 19 at. cm −3 ) is different from those with lower doping levels ( 18 at. cm −3 ). It is also further demonstrated that the plasma resonance frequency (ω p ) is not influenced by the grain size.

  11. Rapid Quantification of Methamphetamine: Using Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Chemometrics

    Science.gov (United States)

    Hughes, Juanita; Ayoko, Godwin; Collett, Simon; Golding, Gary

    2013-01-01

    In Australia and increasingly worldwide, methamphetamine is one of the most commonly seized drugs analysed by forensic chemists. The current well-established GC/MS methods used to identify and quantify methamphetamine are lengthy, expensive processes, but often rapid analysis is requested by undercover police leading to an interest in developing this new analytical technique. Ninety six illicit drug seizures containing methamphetamine (0.1%–78.6%) were analysed using Fourier Transform Infrared Spectroscopy with an Attenuated Total Reflectance attachment and Chemometrics. Two Partial Least Squares models were developed, one using the principal Infrared Spectroscopy peaks of methamphetamine and the other a Hierarchical Partial Least Squares model. Both of these models were refined to choose the variables that were most closely associated with the methamphetamine % vector. Both of the models were excellent, with the principal peaks in the Partial Least Squares model having Root Mean Square Error of Prediction 3.8, R2 0.9779 and lower limit of quantification 7% methamphetamine. The Hierarchical Partial Least Squares model had lower limit of quantification 0.3% methamphetamine, Root Mean Square Error of Prediction 5.2 and R2 0.9637. Such models offer rapid and effective methods for screening illicit drug samples to determine the percentage of methamphetamine they contain. PMID:23936058

  12. Exploring Planetary Analogs With an Ultracompact Near-Infrared Reflectance Instrument

    Science.gov (United States)

    Sobron, P.; Wang, A.

    2017-12-01

    Orbital reflectance spectrometers provide unique measurements of mineralogical features globally and repeatedly on planets and moons of our solar system. Mounted on landed spacecraft, reflectance sensors enable fine-scale investigations and can provide ground truth analyses to assess the validity of spectral remote sensing. We have developed a miniaturized, field-ready, active source NIR (1.14-4.76 μm) reflectance spectrometer (WIR) WIR enables in-situ, near real-time identification of water (structural or adsorbed), carbonates, sulfates, hydrated silicates, as well as C-H & N-H bonds in organic species. WIR is suited for lander/rover deployment in two modes: 1) In Traverse Survey Mode WIR is integrated into a rover wheel and performs nonstop synchronized data collection with every revolution of the wheel; large amounts of data points can be collected during a rover traverse that inform the spatial distribution of mineral phases; 2) In Point-Check Mode WIR is mounted on a robotic arm of a rover/lander and deployed on selected targets at planetary surfaces, or installed inside an analytical lab where samples from a drill/scoop are delivered for detailed analysis. Over the past 10 years we have deployed WIR in planetary analog settings, including hydrothermal springs in Svalbard (Norway) and High Andes (Chile); Arctic volcanoes in Svalbard; Arctic springs and permafrost in Axel Heiberg (Canada); Antarctic ice-covered lakes; saline playas in hyperarid deserts in the Tibetan Plateau (China) and the Atacama; high elevation ore deposits in the Andes and the Abitibi gold belt region (Canada); lava tubes in California; and acidic waters in Rio Tinto (Spain). We have recorded in-situ NIR reflectance spectra from these analogues and used improved spectral unmixing algorithms to determine the mineralogical composition at these sites. We have observed minerals consistent with sedimentary, mineralogical, morphological, and geochemical processes, some of which have been

  13. Prediction of leaf chemistry by the use of visible and near infrared reflectance spectroscopy

    Science.gov (United States)

    Card, Don H.; Peterson, David L.; Matson, Pamela A.; Aber, John D.

    1988-01-01

    The chemical content of dry, ground leaf material sampled from deciduous and conifer tree species from sites in Alaska, Wisconsin, and California was estimated using visible and shortwave IR spectroscopy. Seven chemical components - sugar, starch, protein, cellulose, total chlorophyll, lignin, and total nitrogen - were analyzed by wet chemical methods and their concentrations regressed against log 1/rho and first and second differences of log 1/rho (where rho is measured reflectance) at wavelengths selected by stepwise regression. Predictions of chemical concentrations based on cross validation suggest that this technique may be useful for extracting vegetation canopy biochemical information by remote sensing.

  14. Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy and chemometric techniques for the determination of adulteration in petrodiesel/biodiesel blends

    OpenAIRE

    Armando Guerrero Peña; Francisco Anguebes Franseschi; Mepivoseth Castelán Estrada; Victorino Morales Ramos; Reyes García Zarracino; José C. Zavala Loría; Atl V. Córdova Quiroz

    2014-01-01

    We propose an analytical method based on fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy to detect the adulteration of petrodiesel and petrodiesel/palm biodiesel blends with African crude palm oil. The infrared spectral fingerprints from the sample analysis were used to perform principal components analysis (PCA) and to construct a prediction model using partial least squares (PLS) regression. The PCA results separated the samples into three groups, allowing id...

  15. Characterizing and Authenticating Montilla-Moriles PDO Vinegars Using Near Infrared Reflectance Spectroscopy (NIRS Technology

    Directory of Open Access Journals (Sweden)

    María-José De la Haba

    2014-02-01

    Full Text Available This study assessed the potential of near infrared (NIR spectroscopy as a non-destructive method for characterizing Protected Designation of Origin (PDO “Vinagres de Montilla-Moriles” wine vinegars and for classifying them as a function of the manufacturing process used. Three spectrophotometers were evaluated for this purpose: two monochromator instruments (Foss NIRSystems 6500 SY-I and Foss NIRSystems 6500 SY-II; spectral range 400–2,500 nm in both cases and a diode-array instrument (Corona 45 VIS/NIR; spectral range 380–1,700 nm. A total of 70 samples were used to predict major chemical quality parameters (total acidity, fixed acidity, volatile acidity, pH, dry extract, ash, acetoin, methanol, total polyphenols, color (tonality and intensity, and alcohol content, and to construct models for the classification of vinegars as a function of the manufacturing method used. The results obtained indicate that this non-invasive technology can be used successfully by the vinegar industry and by PDO regulators for the routine analysis of vinegars in order to authenticate them and to detect potential fraud. Slightly better results were achieved with the two monochromator instruments. The findings also highlight the potential of these NIR instruments for predicting the manufacturing process used, this being of particular value for the industrial authentication of traditional wine vinegars.

  16. Use of the near-infrared reflectance method for measurement of moisture content during granulation.

    Science.gov (United States)

    Rantanen, J; Antikainen, O; Mannermaa, J P; Yliruusi, J

    2000-01-01

    The purpose of this study was to demonstrate the use of a near-infrared (NIR) method for in-process control of a placebo formulation. An NIR setup with a multichannel detector was applied in the measurement of water during fluidized bed granulation. The effects of two critical granulation parameters were studied using the central composite design. The present NIR setup with three wavelengths proved applicable for in-line moisture measurement. The 1990 nm signal was used for measurement of water and the 1745 and 2145 nm signals were used to correct the change in spectra baseline during granulation. Variations in inlet air conditions proved to be critical factors, explaining differences in the granule size distributions. Differences in granule moistening and drying rates resulting from varying inlet air conditions could be measured with the NIR setup. The moisture content of granules at the end of the spraying phase explained part of the differences in granule size distributions. The moisture content of granules at the end of the drying phase affected the tableting behavior of granules. The results suggested that direct measurement of granule moisture content facilitates the in-process control of the granulation.

  17. Characterizing and authenticating Montilla-Moriles PDO vinegars using near infrared reflectance spectroscopy (NIRS) technology.

    Science.gov (United States)

    De la Haba, María-José; Arias, Mar; Ramírez, Pilar; López, María-Isabel; Sánchez, María-Teresa

    2014-02-20

    This study assessed the potential of near infrared (NIR) spectroscopy as a non-destructive method for characterizing Protected Designation of Origin (PDO) "Vinagres de Montilla-Moriles" wine vinegars and for classifying them as a function of the manufacturing process used. Three spectrophotometers were evaluated for this purpose: two monochromator instruments (Foss NIRSystems 6500 SY-I and Foss NIRSystems 6500 SY-II; spectral range 400-2,500 nm in both cases) and a diode-array instrument (Corona 45 VIS/NIR; spectral range 380-1,700 nm). A total of 70 samples were used to predict major chemical quality parameters (total acidity, fixed acidity, volatile acidity, pH, dry extract, ash, acetoin, methanol, total polyphenols, color (tonality and intensity), and alcohol content), and to construct models for the classification of vinegars as a function of the manufacturing method used. The results obtained indicate that this non-invasive technology can be used successfully by the vinegar industry and by PDO regulators for the routine analysis of vinegars in order to authenticate them and to detect potential fraud. Slightly better results were achieved with the two monochromator instruments. The findings also highlight the potential of these NIR instruments for predicting the manufacturing process used, this being of particular value for the industrial authentication of traditional wine vinegars.

  18. On-line prediction of fresh pork quality using visible/near-infrared reflectance spectroscopy.

    Science.gov (United States)

    Liao, Yi-Tao; Fan, Yu-Xia; Cheng, Fang

    2010-12-01

    Visible/near-infrared (Vis/NIR) spectroscopy was tested to predict the quality attributes of fresh pork (content of intramuscular fat, protein and water, pH and shear force value) on-line. Vis/NIR spectra (350-1100 nm) were obtained from 211 samples using a prototype. Partial least-squares regression (PLSR) models were developed by external validation with wavelet de-noising and several pre-processing methods. The 6th order Daubechies wavelet with 6 decomposition levels (db6-6) showed high de-noising ability with good information preservation. The first derivative of db6-6 de-noised spectra combined with multiplicative scatter correction yielded the prediction models with the highest coefficient of determination (R(2)) for all traits in both calibration and validation periods, which were all above 0.757 except for the prediction of shear force value. The results indicate that Vis/NIR spectroscopy is a promising technique to roughly predict the quality attributes of intact fresh pork on-line. Copyright © 2010 The American Meat Science Association. Published by Elsevier Ltd. All rights reserved.

  19. [Prediction of minced pork quality attributes using visible and near infrared reflectance spectroscopy].

    Science.gov (United States)

    Fan, Yu-Xia; Liao, Yi-Tao; Cheng, Fang

    2011-10-01

    The objective of the present study was to estimate minced pork meat quality using visible and near infrared (Vis-NIR) spectroscopy. Two hundred twenty five carcasses samples from longissimus dorsi muscle were scanned over the Vis-NIR spectral range from 350 to 1 015 nm and analysed for intramuscular fat (IMF), protein and moisture according to the official methods. Wavelet transform was employed to eliminate the spectra noise. Partial least square regression (PLSR) and support vector machine (SVM) were used to develop Vis-NIR spectroscopy models for chemical composition detection. According to calibration statistics, the best model to predict intramuscular fat content was developed by SVM with the denoised spectra, the correlation coefficient was 0.889 for calibration and 0.888 for validation. For protein and moisture, the best model was achieved with the PLS method with the correlation coefficient of 0.869 and 0.881 for protein calibration and validation sets and 0.877 and 0.848 for moisture calibration and validation sets, respectively. And all the ratios of standard deviation of validation set to root mean square error of prediction (RPD) were not more than 3.0. Results indicated that it was possible to predict chemical composition in minced pork meat. As a fast predictor of meat quality using Vis-NIR spectroscopy, it is necessary to improve the precision and the robustness of the model for practice.

  20. Validation of MODIS-derived bidirectional reflectivity retrieval algorithm in mid-infrared channel with field measurements.

    Science.gov (United States)

    Tang, Bo-Hui; Wu, Hua-; Li, Zhao-Liang; Nerry, Françoise

    2012-07-30

    This work addressed the validation of the MODIS-derived bidirectional reflectivity retrieval algorithm in mid-infrared (MIR) channel, proposed by Tang and Li [Int. J. Remote Sens. 29, 4907 (2008)], with ground-measured data, which were collected from a field campaign that took place in June 2004 at the ONERA (Office National d'Etudes et de Recherches Aérospatiales) center of Fauga-Mauzac, on the PIRRENE (Programme Interdisciplinaire de Recherche sur la Radiométrie en Environnement Extérieur) experiment site [Opt. Express 15, 12464 (2007)]. The leaving-surface spectral radiances measured by a BOMEM (MR250 Series) Fourier transform interferometer were used to calculate the ground brightness temperatures with the combination of the inversion of the Planck function and the spectral response functions of MODIS channels 22 and 23, and then to estimate the ground brightness temperature without the contribution of the solar direct beam and the bidirectional reflectivity by using Tang and Li's proposed algorithm. On the other hand, the simultaneously measured atmospheric profiles were used to obtain the atmospheric parameters and then to calculate the ground brightness temperature without the contribution of the solar direct beam, based on the atmospheric radiative transfer equation in the MIR region. Comparison of those two kinds of brightness temperature obtained by two different methods indicated that the Root Mean Square Error (RMSE) between the brightness temperatures estimated respectively using Tang and Li's algorithm and the atmospheric radiative transfer equation is 1.94 K. In addition, comparison of the hemispherical-directional reflectances derived by Tang and Li's algorithm with those obtained from the field measurements showed that the RMSE is 0.011, which indicates that Tang and Li's algorithm is feasible to retrieve the bidirectional reflectivity in MIR channel from MODIS data.

  1. Exploring the Role of the Spatial Characteristics of Visible and Near-Infrared Reflectance in Predicting Soil Organic Carbon Density

    Directory of Open Access Journals (Sweden)

    Long Guo

    2017-10-01

    Full Text Available Soil organic carbon stock plays a key role in the global carbon cycle and the precision agriculture. Visible and near-infrared reflectance spectroscopy (VNIRS can directly reflect the internal physical construction and chemical substances of soil. The partial least squares regression (PLSR is a classical and highly commonly used model in constructing soil spectral models and predicting soil properties. Nevertheless, using PLSR alone may not consider soil as characterized by strong spatial heterogeneity and dependence. However, considering the spatial characteristics of soil can offer valuable spatial information to guarantee the prediction accuracy of soil spectral models. Thus, this study aims to construct a rapid and accurate soil spectral model in predicting soil organic carbon density (SOCD with the aid of the spatial autocorrelation of soil spectral reflectance. A total of 231 topsoil samples (0–30 cm were collected from the Jianghan Plain, Wuhan, China. The spectral reflectance (350–2500 nm was used as auxiliary variable. A geographically-weighted regression (GWR model was used to evaluate the potential improvement of SOCD prediction when the spatial information of the spectral features was considered. Results showed that: (1 The principal components extracted from PLSR have a strong relationship with the regression coefficients at the average sampling distance (300 m based on the Moran’s I values. (2 The eigenvectors of the principal components exhibited strong relationships with the absorption spectral features, and the regression coefficients of GWR varied with the geographical locations. (3 GWR displayed a higher accuracy than that of PLSR in predicting the SOCD by VNIRS. This study aimed to help people realize the importance of the spatial characteristics of soil properties and their spectra. This work also introduced guidelines for the application of GWR in predicting soil properties by VNIRS.

  2. The effects of atmospheric pressure on infrared reflectance spectra of Martian analogs

    Science.gov (United States)

    Bishop, Janice L.; Pieters, Carle M.; Pratt, Stephen F.; Patterson, William

    1993-01-01

    The use of terrestrial samples as analogs of Mars soils are complicated by the Martian atmosphere. Spectral features due to the Martian atmosphere can be removed from telescopic spectra of Mars and ISM spectra of Mars, but this does not account for any spectral differences resulting from atmospheric pressure or any interactions between the atmosphere and the surface. We are examining the effects of atmospheric pressure on reflectance spectra of powdered samples in the laboratory. Contrary to a previous experiment with granite, no significant changes in albedo or the Christiansen feature were observed from 1 bar pressure down to a pressure of 8 micrometers Hg. However, reducing the atmospheric pressure does have a pronounced affect on the hydration features, even for samples retained in a dry environment for years.

  3. Evaluation of transmission and reflection modalities for measuring content uniformity of pharmaceutical tablets with near-infrared spectroscopy.

    Science.gov (United States)

    Xiang, Dong; LoBrutto, Rosario; Cheney, James; Wabuyele, Busolo Wa; Berry, Joseph; Lyon, Robbe; Wu, Huiquan; Khan, Mansoor A; Hussain, Ajaz S

    2009-01-01

    This paper examines how one may assess spectral changes with instrument configuration (or composition), in combination with the spectral changes in the measurement that are caused by experimental effects, and subsequently select an appropriate measurement modality for tablet content uniformity determination with near-infrared (NIR) spectroscopy. Two NIR spectrometers furnished with three configurations in the sample measurement interface were evaluated. One spectrometer, Bruker MPA (multiple purpose analyzer), was equipped with two measurement modalities, diffuse transmission (DT) and diffuse reflection based on integrating sphere optics (DR/IS). The other spectrometer, Bruker StepOne, was equipped only with diffuse reflection mode based on a fiber-optic probe (DR/FO). The data were collected with each of the configurations for the tablets associated with two dosage strengths differing significantly in diameter and thickness. Spectral diagnosis was performed in terms of sensitivity and selectivity. The signal-to-noise ratio computed for the data collected with the DT and DR/IS spectrometers was approximately an order of magnitude greater than that computed for the DR/FO spectrometer. The net-analyte-signal-based selectivity analysis of NIR spectra associated with the sample tablet and the placebo tablet indicated that both transmission and reflection mode provided similar selectivity when the optimal spectral range was chosen. A partial least squares (PLS) calibration model was developed for each data set. The overall standard error of calibration for each DT and DR/IS measurement was approximately 0.3% in weight for each strength, significantly better than the value of 1.0% in weight produced by the DR/FO measurement. This result was consistent with the sensitivity analysis based on spectral noise characterization. The poor analytical performance of the DR/FO spectrometer was attributed to the small illumination spot size of the reflection probe and thus the

  4. Hygrothermal degradation of (3-glycidoxypropyl)trimethoxysilane films studied by neutron and X-ray reflectivity and attenuated total reflection infrared spectroscopy

    International Nuclear Information System (INIS)

    Tallant, David Robert; Garcia, Manuel Joseph; Majewski, Jaroslaw; Kent, Michael Stuart; Yim, Hyun

    2005-01-01

    Thin films of organosilanes have great technological importance in the areas of adhesion promotion, durability, and corrosion resistance. However, it is well-known that water can degrade organosilane films, particularly at elevated temperatures. In this work, X-ray and neutron reflectivity (XR and NR) were combined with attenuated total reflection infrared (ATR-IR) spectroscopy to study the chemical and structural changes within thin films of (3-glycidoxypropyl)trimethoxysilane (GPS) after exposure for various periods of time to air saturated with either D 2 O or H 2 O at 80 C. For NR and XR, ultrathin (∼100 (angstrom)) films were prepared by spin-coating. Both D 2 O and H 2 O provide neutron scattering contrast with GPS. Variations in the neutron scattering length density (SLD) profiles (a function of mass density and atomic composition) with conditioning time were measured after drying the samples out and also swelled with H 2 O or D 2 O vapor at room temperature. For samples that were dried out prior to measurement, little or no change was observed for H 2 O conditioning up to 3.5 days, but large changes were observed after 30 days of conditioning. The range of conditioning time for this structural change was narrowed to between 4 and 10 days with XR. The SLD profiles indicated that the top portion of the GPS film was transformed into a thick low-density layer after conditioning, but the bottom portion showed little structural change. A previous NR study of as-prepared GPS films involving swelling with deuterated nitrobenzene showed that the central portion of the film has much lower cross-link density than the region nearest the substrate. The present data show that the central portion also swells to a much greater extent with water and hydrolyzes more rapidly. The chemical degradation mechanism was identified by IR as hydrolysis of siloxane bonds. For ATR-IR, GPS films were prepared by dip-coating, which resulted in a greater and more variable thickness than

  5. Reflections

    Directory of Open Access Journals (Sweden)

    Joanne Embree

    2001-01-01

    Full Text Available Ideally, editorials are written one to two months before publication in the Journal. It was my turn to write this one. I had planned to write the first draft the evening after my clinic on Tuesday, September 11. It didn't get done that night or during the next week. Somehow, the topic that I had originally chosen just didn't seem that important anymore as I, along my friends and colleagues, reflected on the changes that the events of that day were likely to have on our lives.

  6. Rapid Erosion Modeling in a Western Kenya Watershed using Visible Near Infrared Reflectance, Classification Tree Analysis and 137Cesium.

    Science.gov (United States)

    deGraffenried, Jeff B; Shepherd, Keith D

    2009-12-15

    Human induced soil erosion has severe economic and environmental impacts throughout the world. It is more severe in the tropics than elsewhere and results in diminished food production and security. Kenya has limited arable land and 30 percent of the country experiences severe to very severe human induced soil degradation. The purpose of this research was to test visible near infrared diffuse reflectance spectroscopy (VNIR) as a tool for rapid assessment and benchmarking of soil condition and erosion severity class. The study was conducted in the Saiwa River watershed in the northern Rift Valley Province of western Kenya, a tropical highland area. Soil 137 Cs concentration was measured to validate spectrally derived erosion classes and establish the background levels for difference land use types. Results indicate VNIR could be used to accurately evaluate a large and diverse soil data set and predict soil erosion characteristics. Soil condition was spectrally assessed and modeled. Analysis of mean raw spectra indicated significant reflectance differences between soil erosion classes. The largest differences occurred between 1,350 and 1,950 nm with the largest separation occurring at 1,920 nm. Classification and Regression Tree (CART) analysis indicated that the spectral model had practical predictive success (72%) with Receiver Operating Characteristic (ROC) of 0.74. The change in 137 Cs concentrations supported the premise that VNIR is an effective tool for rapid screening of soil erosion condition.

  7. Reversible near-infrared light directed reflection in a self-organized helical superstructure loaded with upconversion nanoparticles.

    Science.gov (United States)

    Wang, Ling; Dong, Hao; Li, Yannian; Xue, Chenming; Sun, Ling-Dong; Yan, Chun-Hua; Li, Quan

    2014-03-26

    Adding external, dynamic control to self-organized superstructures with desired functionalities is an important leap necessary in leveraging the fascinating molecular systems for applications. Here, the new light-driven chiral molecular switch and upconversion nanoparticles, doped in a liquid crystal media, were able to self-organize into an optically tunable helical superstructure. The resulting nanoparticle impregnated helical superstructure was found to exhibit unprecedented reversible near-infrared (NIR) light-guided tunable behavior only by modulating the excitation power density of a continuous-wave NIR laser (980 nm). Upon irradiation by the NIR laser at the high power density, the reflection wavelength of the photonic superstructure red-shifted, whereas its reverse process occurred upon irradiation by the same laser but with the lower power density. Furthermore, reversible dynamic NIR-light-driven red, green, and blue reflections in a single thin film, achieved only by varying the power density of the NIR light, were for the first time demonstrated.

  8. Micro transflection on a metallic stick: an innovative approach of reflection infrared spectroscopy for minimally invasive investigation of painting varnishes.

    Science.gov (United States)

    Rosi, Francesca; Legan, Lea; Miliani, Costanza; Ropret, Polonca

    2017-05-01

    A new analytical approach, based on micro-transflection measurements from a diamond-coated metal sampling stick, is presented for the analysis of painting varnishes. Minimally invasive sampling is performed from the varnished surface using the stick, which is directly used as a transflection substrate for micro Fourier transform infrared (FTIR) measurements. With use of a series of varnished model paints, the micro-transflection method has been proved to be a valuable tool for the identification of surface components thanks to the selectivity of the sampling, the enhancement of the absorbance signal, and the easier spectral interpretation because the profiles are similar to transmission mode ones. Driven by these positive outcomes, the method was then tested as tool supporting noninvasive reflection FTIR spectroscopy during the assessment of varnish removal by solvent cleaning on paint models. Finally, the integrated analytical approach based on the two reflection methods was successfully applied for the monitoring of the cleaning of the sixteenth century painting Presentation in the Temple by Vittore Carpaccio. Graphical Abstract Micro-transflection FTIR on a metallic stick for the identification of varnishes during painting cleanings.

  9. Preliminary evaluation of optical glucose sensing in red cell concentrations using near-infrared diffuse-reflectance spectroscopy

    Science.gov (United States)

    Suzuki, Yusuke; Maruo, Katsuhiko; Zhang, Alice W.; Shimogaki, Kazushige; Ogawa, Hideto; Hirayama, Fumiya

    2012-01-01

    Bacterial contamination of blood products is one of the most frequent infectious complications of transfusion. Since glucose levels in blood supplies decrease as bacteria proliferate, it should be possible to detect the presence of bacterial contamination by measuring the glucose concentrations in the blood components. Hence this study is aimed to serve as a preliminary study for the nondestructive measurement of glucose level in transfusion blood. The glucose concentrations in red blood cell (RBC) samples were predicted using near-infrared diffuse-reflectance spectroscopy in the 1350 to 1850 nm wavelength region. Furthermore, the effects of donor, hematocrit level, and temperature variations among the RBC samples were observed. Results showed that the prediction performance of a dataset which contained samples that differed in all three parameters had a standard error of 29.3 mg/dL. Multiplicative scatter correction (MSC) preprocessing method was also found to be effective in minimizing the variations in scattering patterns created by various sample properties. The results suggest that the diffuse-reflectance spectroscopy may provide another avenue for the detection of bacterial contamination in red cell concentrations (RCC) products.

  10. Real time and non-destructive analysis of tablet coating thickness using acoustic microscopy and infrared diffuse reflectance spectroscopy.

    Science.gov (United States)

    Bikiaris, D; Koutri, I; Alexiadis, D; Damtsios, A; Karagiannis, G

    2012-11-15

    Tablet coating thicknesses were estimated using several techniques such as weight gain and scanning electron microscopy (SEM), in comparison with acoustic microscopy and diffuse reflectance spectroscopy. Acoustic microscopy, used for the first time in such an application, is based on the physical phenomenon of ultrasound propagation through the materials and the echoes generated by their interfaces. Based on the time of flights (TOFs) of the echoes from the coating surface and the tablet, it is possible to calculate the coating thickness. In order to evaluate the accuracy and robustness of these methods, drug tablets were coated with Kollicoat SR polymer for several times, so that to prepare tablets with different coating thicknesses. Tablets with 3, 6 and 9 wt% coating material have been prepared and based on SEM micrographs it was found that the tablet coating thickness is 71.99 ± 1.2 μm, 92.5 ± 1.7 μm and 132.3 ± 2.1 μm, respectively (SEM analysis). The tablet coating thicknesses measured with acoustic microscopy and infrared diffuse reflectance spectroscopy, were in agreement with those obtained using SEM. This verifies that both techniques can be successfully applied for real time and non-destructive thickness measurements of tablet coating. Furthermore, both techniques, compared with SEM and weight gained measurements, are fast and fully automated. Copyright © 2012 Elsevier B.V. All rights reserved.

  11. Structural changes in the cells of some bacteria during population growth: a Fourier transform infrared-attenuated total reflectance study.

    Science.gov (United States)

    Ede, Sarah M; Hafner, Louise M; Fredericks, Peter M

    2004-03-01

    Structural changes occurring in the cells of several bacteria during their growth curves have been investigated by Fourier transform infrared (FT-IR) spectroscopy using the sampling technique of attenuated total reflectance (ATR). Spectra reflect all of the components of the cells, including the cell walls, cell membranes, internal structures, and the cytoplasm. The bacteria studied were Bacillus stearothermophilus, Halobacterium salinarum, Halococcus morrhuae, and Acetobacter aceti. All species showed significant spectral changes during their growth curves, indicating structural changes in the cells during increases in cell numbers. The major change for B. stearothermophilus was in the lipid content, which was at a maximum during the exponential phase of the growth curve. For the halophiles H. salinarum and H. morrhuae, the major change was that the concentration of sulfate ion in the cells varied during the growth curve and was at a maximum during the mid-part of the exponential phase of the growth curve. A. aceti cells showed increasing polysaccharide content during the growth curve as well as maximum lipid content during the exponential phase of growth.

  12. Non-destructive evaluation of degradation in EB-PVD thermal barrier coatings by infrared reflectance spectroscopy

    International Nuclear Information System (INIS)

    Flattum, Richard Y.; Cooney, Adam T.

    2013-01-01

    At room temperature and atmospheric conditions infrared reflectance spectroscopy and X-ray diffraction were employed for the detection of the phase transformation and residual stress within thermal barrier coatings (TBC). The TBC's samples initially consisted of the porous ceramic topcoat deposited by electron beam plasma vapor deposition, a bond coat and a superalloy substrate. Reflectance spectroscopy scans were performed from 7497 cm −1 to 68 cm −1 to analysis the fingerprint region as well as the chemical bonding region. These regions should indicate if a detectable change within the TBC response is a result of thermal degradation of the microstructure and the changes in yttrium dispersion throughout the yttrium stabilized zirconium. The thermal degradation was induced by thermal cycling the samples to 1100° C and then cooling them in an atmospheric environment. X-ray diffraction was also used to detect the phase composition within the TBC samples and see if either would clearly identify failure prior to actual spallation. The eventual measurability and quantify-ability of the phase changes within the TBC's may be used as an effective non-destructive evaluation (NDE) technique that would allow personnel in the field to know when servicing of the turbine blade was necessary.

  13. Difference between the Brewster angle and angle of minimum reflectance for incident unpolarized or circularly polarized light at interfaces between transparent media.

    Science.gov (United States)

    Azzam, R M A

    2015-06-01

    For reflection at interfaces between transparent optically isotropic media, the difference between the Brewster angle ϕB of zero reflectance for incident p-polarized light and the angle ϕu min of minimum reflectance for incident unpolarized or circularly polarized light is considered as function of the relative refractive n in external and internal reflection. We determine the following. (i) ϕu min reflection (n > 1), the maximum difference (ϕB - ϕu min)max = 75° at n = 2 + √3. (iii) In internal reflection and 0 reflectance R0 at normal incidence is in the range 0 ≤ R0 ≤ 1/3, ϕu min = 0, and ϕB - ϕu min = ϕB. (v) For internal reflection and 0 < n < 2 - √3, ϕu min exhibits an unexpected maximum (= 12.30°) at n = 0.24265. Finally, (vi) for 1/3 ≤ R0 < 1, Ru min at ϕu min is limited to the range 1/3 ≤ Ru min < 1/2.

  14. Determination of the pigments present in a wallpaper of the middle nineteenth century: the combination of mid-diffuse reflectance and far infrared spectroscopies.

    Science.gov (United States)

    Arrizabalaga, Iker; Gómez-Laserna, Olivia; Aramendia, Julene; Arana, Gorka; Madariaga, Juan Manuel

    2014-04-24

    In this work the determination of the pigments present in a decorative wallpaper of the middle nineteenth century from the Santa Isabel factory (Vitoria-Gasteiz, Basque Country, Spain) has been performed by a combination of mid-Diffuse Reflectance Infrared Spectroscopy (DRIFT) and Far Infrared Spectroscopy (FIR) in transmission mode. The DRIFT is a powerful infrared technique that is not widely used in the analyses of artworks in spite of being especially adequate for powdered samples. In this mode, sample pretreatment is not required and the obtained spectra are easier to solve than those obtained in transmittance mode. Those pigments which are not active in the mid-infrared region may be determined easily by FIR. In the last decade, in the field of painted materials very few studies performed by far infrared spectroscopy and mid infrared spectroscopy in diffuse reflectance mode can be found. In most of them the researchers have used one of these techniques, but in no case the combination of both. As we demonstrate in this work, combining these two techniques a complete characterization of the wallpaper can be carried out. Small samples were collected from the wallpaper for the analysis of the rose, brown, yellow and blue colours. In this way, minium (Pb3O4), calcite (CaCO3), barium sulphate (BaSO4), prussian blue (Fe7C18N18), iron oxide yellow (α-FeOOH), vermillion (HgS) and carbon black pigment from organic origen were detected. Finally, the validation was carried out by XRF and Raman spectroscopy getting the same results as with the combination of diffuse reflectance infrared spectroscopy and far infrared spectroscopy. Copyright © 2014 Elsevier B.V. All rights reserved.

  15. [Bare Soil Moisture Inversion Model Based on Visible-Shortwave Infrared Reflectance].

    Science.gov (United States)

    Zheng, Xiao-po; Sun, Yue-jun; Qin, Qi-ming; Ren, Hua-zhong; Gao, Zhong-ling; Wu, Ling; Meng, Qing-ye; Wang, Jin-liang; Wang, Jian-hua

    2015-08-01

    Soil is the loose solum of land surface that can support plants. It consists of minerals, organics, atmosphere, moisture, microbes, et al. Among its complex compositions, soil moisture varies greatly. Therefore, the fast and accurate inversion of soil moisture by using remote sensing is very crucial. In order to reduce the influence of soil type on the retrieval of soil moisture, this paper proposed a normalized spectral slope and absorption index named NSSAI to estimate soil moisture. The modeling of the new index contains several key steps: Firstly, soil samples with different moisture level were artificially prepared, and soil reflectance spectra was consequently measured using spectroradiometer produced by ASD Company. Secondly, the moisture absorption spectral feature located at shortwave wavelengths and the spectral slope of visible wavelengths were calculated after analyzing the regular spectral feature change patterns of different soil at different moisture conditions. Then advantages of the two features at reducing soil types' effects was synthesized to build the NSSAI. Thirdly, a linear relationship between NSSAI and soil moisture was established. The result showed that NSSAI worked better (correlation coefficient is 0.93) than most of other traditional methods in soil moisture extraction. It can weaken the influences caused by soil types at different moisture levels and improve the bare soil moisture inversion accuracy.

  16. Mapping of egg yolk and animal skin glue paint binders in Early Renaissance paintings using near infrared reflectance imaging spectroscopy.

    Science.gov (United States)

    Dooley, Kathryn A; Lomax, Suzanne; Zeibel, Jason G; Miliani, Costanza; Ricciardi, Paola; Hoenigswald, Ann; Loew, Murray; Delaney, John K

    2013-09-07

    In situ chemical imaging techniques are being developed to provide information on the spatial distribution of artists' pigments used in polychrome works of art such as paintings. The new methods include reflectance imaging spectroscopy and X-ray fluorescence mapping. Results from these new methods have extended the knowledge obtained from site-specific chemical analyses widely in use. While these mapping methods have aided in determining the distribution of pigments, there is a growing interest to develop methods capable of identifying and mapping organic paint binders as well. Near infrared (NIR) reflectance spectroscopy has been extensively used in the remote sensing field as well as in the chemical industry to detect organic compounds. NIR spectroscopy provides a rapid method to assay organics by utilizing vibrational overtones and combination bands of fundamental absorptions that occur in the mid-IR. Here we explore the utility of NIR reflectance imaging spectroscopy to map organic binders in situ by examining a series of panel paintings known to have been painted using distemper (animal skin glue) and tempera (egg yolk) binders as determined by amino acid analysis of samples taken from multiple sites on the panels. In this report we demonstrate the success in identifying and mapping these binders by NIR reflectance imaging spectroscopy in situ. Three of the four panel paintings from Cosimo Tura's The Annunciation with Saint Francis and Saint Louis of Toulouse (ca. 1475) are imaged using a highly sensitive, line-scanning hyperspectral imaging camera. The results show an animal skin glue binder was used for the blue skies and blue robe of the Virgin Mary, and egg yolk tempera was used for the red robes and brown landscape. The mapping results show evidence for the use of both egg yolk and animal skin glue in the faces of the figures. The strongest absorption associated with lipidic egg yolk features visually correlates with areas that appear to have white

  17. Electron dynamics in films made of transition metal nanograins embedded in SiO[sub 2]: Infrared reflectivity and nanoplasma infrared resonance

    KAUST Repository

    Massa, Néstor E.

    2009-06-04

    We report on near normal infrared reflectivityspectra of ∼550 nm thick films made of cosputtered transition metal nanograins and SiO2 in a wide range of metal fractions. Co0.85(SiO2)0.15,with conductivity well above the percolation threshold has a frequency and temperature behavior according to what it is find in conductingmetal oxides. The electron scattering rate displays a unique relaxation time characteristic of single type of carriers experiencing strong electron-phonon interactions. Using small polaron fits we identify those phonons as glass vibrational modes. Ni0.61(SiO2)0.39, with a metal fraction closer to the percolation threshold, undergoes a metal-nonmetal transition at ∼77 K. Here, as it is suggested by the scattering rate nearly quadratic dependence, we broadly identify two relaxation times (two carrier contributions) associated to a Drude mode and a midinfrared overdamped band, respectively. Disorder induced, the midinfrared contribution drives the phase transition by thermal electron localization. Co0.51(SiO2)0.49 has the reflectivity of an insulator with a distinctive band at ∼1450 cm−1 originating in electron promotion, localization, and defect induced polaron formation. Angle dependent oblique reflectivity of globally insulating Co0.38(SiO2)0.62, Fe0.34(SiO2)0.66, and Ni0.28(SiO2)0.72, reveals a remarkable resonance at that band threshold. We understand this as due to the excitation by normal to the film electric fields of defect localized electrons in the metallic nanoparticles. At higher oblique angles, this localized nanoplasma couples to SiO2 longitudinal optical Berreman phonons resulting in band peak softening reminiscent to the phonon behavior undergoing strong electron-phonon interactions. Singular to a globally insulating phase, we believe that this resonance might be a useful tool for tracking metal-insulator phase transitions in inhomogeneous materials.

  18. Investigation of applicability of a mid-infrared spectroscopic method using an attenuated total reflection accessory and a new near-infrared transmission method for determination of faecal fat

    NARCIS (Netherlands)

    Volmer, M; Kingma, AW; Borsboom, PCF; Wolthers, BG; Kema, IP

    In many laboratories, the titrimetric method of Van de Kamer is used for the analysis of faecal fat content of patients suspected of steatorrhoea. We investigated the applicability of a mid-infrared (MIR) spectroscopic method, using an attenuated total reflection (ATR) accessory, and a new

  19. Bare and thin-film-coated substrates with null reflection for p- and s-polarized light at the same angle of incidence: reflectance and ellipsometric parameters as functions of substrate refractive index and film thickness.

    Science.gov (United States)

    Azzam, R M A

    2016-10-20

    Intensity reflectances and ellipsometric parameters of a partially clad transparent substrate that suppresses the reflection of incident p- and s-polarized light at the same angle of incidence from uncoated and single-layer-coated areas are determined as functions of normalized film thickness ς and substrate refractive index n2. The common polarizing angle is the Brewster angle of the ambient-substrate interface, and the light beam incident from the ambient (air or vacuum) is refracted in the film at a 45° angle from the normal to the parallel-plane film boundaries. For n2≤2, the differential reflection phase shift Δ=δp-δs≈±90° for all values of ς so that the Brewster angle is also approximately the principal angle of the film-substrate system independent of film thickness. Accurate techniques for monitoring the deposition of such films are also proposed.

  20. LO-TO splittings, effective charges and interactions in electro-optic meta-nitroaniline crystal as studied by polarized IR reflection and transmission spectra

    Science.gov (United States)

    Szostak, M. M.; Le Calvé, N.; Romain, F.; Pasquier, B.

    1994-10-01

    The polarized IR reflection spectra of the meta-nitroaniline ( m-NA) single crystal along the a, b and c crystallographic axes as well as the b and c polarized transmission spectra have been measured in the 100-400 cm -1 region. The LO-TO splitting values have been calculated from the reflection spectra by fitting them with the four parameter dielectric function. The dipole moment derivatives, relevant to dynamic effective charges, of the vibrations have also been calculated and used to check the applicability of the oriented gas model (OGM) to reflection spectra. The discrepancies from the OGM have been discussed in terms of vibronic couplings, weak hydrogen bondings (HB) and intramolecular charge transfer.

  1. Diffuse Reflectance Infrared Fourier Transform Study of NOx Adsorption on CGO10 Impregnated with K2O or BaO

    DEFF Research Database (Denmark)

    Traulsen, Marie Lund; Härelind Ingelsten, H.; Kammer Hansen, Kent

    2012-01-01

    In the present work Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy is applied to study the adsorption of NOx at 300-500 °C in different atmospheres on gadolinium doped ceria (CGO), an important material in electrodes investigated for electrochemical NOx removal. Furthermore...

  2. Retrieval of tropospheric aerosol properties over land from visible and near-infrared spectral reflectance: Application over Maryland

    Science.gov (United States)

    Levy, Robert Carroll

    Aerosols are major components of the Earth's global climate system, affecting the radiation budget and cloud processes of the atmosphere. When located near the surface, high concentrations lead to lowered visibility, increased health problems and generally reduced quality of life for the human population. Over the United States mid-Atlantic region, aerosol pollution is a problem mainly during the summer. Satellites, such as the MODerate Imaging Spectrometer (MODIS), from their vantage point above the atmosphere, provide unprecedented coverage of global and regional aerosols over land. During MODIS' eight-year operation, exhaustive data validation and analyses have shown how the algorithm should be improved. This dissertation describes the development of the 'second-generation' operational algorithm for retrieval of global tropospheric aerosol properties over dark land surfaces, from MODIS-observed spectral reflectance. New understanding about global aerosol properties, land surface reflectance characteristics, and radiative transfer properties were learned in the process. This new operational algorithm performs a simultaneous inversion of reflectance in two visible channels (0.47 and 0.66 mum) and one shortwave infrared channel (2.12 mum), thereby having increased sensitivity to coarse aerosol. Inversion of the three channels retrieves the aerosol optical depth (tau) at 0.55 mum, the percentage of non-dust (fine model) aerosol (eta) and the surface reflectance. This algorithm is applied globally, and retrieves tau that is highly correlated (y = 0.02 + 1.0x, R=0.9) with ground-based sunphotometer measurements. The new algorithm estimates the global, over-land, long-term averaged tau ˜ 0.21, a 25% reduction from previous MODIS estimates. This leads to reducing estimates of global, non-desert, over-land aerosol direct radiative effect (all aerosols) by 1.7 W·m-2 (0.5 W·m-2 over the entire globe), which significantly impacts assessment of aerosol direct radiative

  3. Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends.

    Science.gov (United States)

    Nagata, Yuuya; Uno, Makoto; Suginome, Michinori

    2016-06-13

    Two poly(quinoxaline-2,3-diyl) copolymers bearing miscibility-enhancing 8-chlorooctyloxy and (S)-2-methylbutoxy or n-butoxy side chains were synthesized. After annealing in CHCl3 vapor, a polymer-blend film of these copolymers exhibited selective reflection of right-handed circularly polarized light (CPL) in the visible region. The handedness of the CPL reflected was completely inverted upon annealing of the film in THF vapor. Annealing in n-hexane vapor resulted in the phase separation of the polymer blend, which turned the selective reflection off. This three-way-switchable reflection, that is, reflection of right-handed or left-handed CPL, together with an OFF state, could be observed visually through right- and left-handed CPL filters. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Modeling Microalgal Biosediment Formation Based on Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Monitoring.

    Science.gov (United States)

    Ogburn, Zachary L; Vogt, Frank

    2018-03-01

    With increasing amounts of anthropogenic pollutants being released into ecosystems, it becomes ever more important to understand their fate and interactions with living organisms. Microalgae play an important ecological role as they are ubiquitous in marine environments and sequester inorganic pollutants which they transform into organic biomass. Of particular interest in this study is their role as a sink for atmospheric CO 2 , a greenhouse gas, and nitrate, one cause of harmful algal blooms. Novel chemometric hard-modeling methodologies have been developed for interpreting phytoplankton's chemical and physiological adaptations to changes in their growing environment. These methodologies will facilitate investigations of environmental impacts of anthropogenic pollutants on chemical and physiological properties of marine microalgae (here: Nannochloropsis oculata). It has been demonstrated that attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy can gain insights into both and this study only focuses on the latter. From time-series of spectra, the rate of microalgal biomass settling on top of a horizontal ATR element is derived which reflects several of phytoplankton's physiological parameters such as growth rate, cell concentrations, cell size, and buoyancy. In order to assess environmental impacts on such parameters, microalgae cultures were grown under 25 different chemical scenarios covering 200-600 ppm atmospheric CO 2 and 0.35-0.75 mM dissolved NO 3 - . After recording time-series of ATR FT-IR spectra, a multivariate curve resolution-alternating least squares (MCR-ALS) algorithm extracted spectroscopic and time profiles from each data set. From the time profiles, it was found that in the considered concentration ranges only NO 3 - has an impact on the cells' physiological properties. In particular, the cultures' growth rate has been influenced by the ambient chemical conditions. Thus, the presented spectroscopic

  5. Effect of in-material losses on terahertz absorption, transmission, and reflection in photonic crystals made of polar dielectrics

    Energy Technology Data Exchange (ETDEWEB)

    Serebryannikov, Andriy E., E-mail: andser@amu.edu.pl [Faculty of Physics, Adam Mickiewicz University, 61-614 Poznań (Poland); Nanotechnology Research Center—NANOTAM, Bilkent University, 06800 Ankara (Turkey); Nojima, S. [Yokohama City University, Department of Nanosystem Science, Graduate School of Nanobioscience, Kanazawa Ku, 22-2 Seto, Yokohama, Kanagawa 2360027 (Japan); Alici, K. B. [TUBITAK Marmara Research Center, Materials Institute, 41470 Gebze, Kocaeli (Turkey); Ozbay, Ekmel [Nanotechnology Research Center—NANOTAM, Bilkent University, 06800 Ankara (Turkey)

    2015-10-07

    The effect of the material absorption factor on terahertz absorption (A), transmittance (T), and reflectance (R) for slabs of PhC that comprise rods made of GaAs, a polar dielectric, is studied. The main goal was to illustrate how critical a choice of the absorption factor for simulations is and to indicate the importance of the possible modification of the absorption ability by using either active or lossy impurities. The spectra of A, T, and R are strongly sensitive to the location of the polaritonic gap with respect to the photonic pass and stop bands connected with periodicity that enables the efficient combination of the effects of material and structural parameters. It will be shown that the spectra can strongly depend on the utilized value of the material absorption factor. In particular, both narrow and wide absorption bands may appear owing to a variation of the material parameters with a frequency in the vicinity of the polaritonic gap. The latter are often achieved at wideband suppression of transmission, so that an ultra-wide stop band can appear as a result of adjustment of the stop bands having different origin. The results obtained at simultaneous variation of the absorption factor and frequency, and angle of incidence and frequency, indicate the possibility of the existence of wide ranges of tolerance, in which the basic features do remain. This allows for mitigating the accuracy requirements for the absorption factor in simulations and promises the efficient absorption of nonmonochromatic waves and beams with a wide angular spectrum. Suppression of narrowband effects in transmission is demonstrated at rather large values of the absorption factor, when they appear due to either the defect modes related to structural defects or dispersion inspired variations of the material parameters in the vicinity of the polaritonic gap. Comparison with auxiliary structures helps one to detect the common features and differences of homogeneous slabs and slabs of a

  6. Comparison of Portable and Bench-Top Spectrometers for Mid-Infrared Diffuse Reflectance Measurements of Soils

    Directory of Open Access Journals (Sweden)

    Christopher Hutengs

    2018-03-01

    Full Text Available Mid-infrared (MIR spectroscopy has received widespread interest as a method to complement traditional soil analysis. Recently available portable MIR spectrometers additionally offer potential for on-site applications, given sufficient spectral data quality. We therefore tested the performance of the Agilent 4300 Handheld FTIR (DRIFT spectra in comparison to a Bruker Tensor 27 bench-top instrument in terms of (i spectral quality and measurement noise quantified by wavelet analysis; (ii accuracy of partial least squares (PLS calibrations for soil organic carbon (SOC, total nitrogen (N, pH, clay and sand content with a repeated cross-validation analysis; and (iii key spectral regions for these soil properties identified with a Monte Carlo spectral variable selection approach. Measurements and multivariate calibrations with the handheld device were as good as or slightly better than Bruker equipped with a DRIFT accessory, but not as accurate as with directional hemispherical reflectance (DHR data collected with an integrating sphere. Variations in noise did not markedly affect the accuracy of multivariate PLS calibrations. Identified key spectral regions for PLS calibrations provided a good match between Agilent and Bruker DHR data, especially for SOC and N. Our findings suggest that portable FTIR instruments are a viable alternative for MIR measurements in the laboratory and offer great potential for on-site applications.

  7. Effects of mercury on visible/near-infrared reflectance spectra of mustard spinach plants (Brassica rapa P.)

    Energy Technology Data Exchange (ETDEWEB)

    Dunagan, Sarah C. [Department of Earth and Environmental Sciences, Wesleyan University, 265 Church Street, Middletown, CT 06459 (United States)]. E-mail: sdunagan@wesleyan.edu; Gilmore, Martha S. [Department of Earth and Environmental Sciences, Wesleyan University, 265 Church Street, Middletown, CT 06459 (United States)]. E-mail: mgilmore@wesleyan.edu; Varekamp, Johan C. [Department of Earth and Environmental Sciences, Wesleyan University, 265 Church Street, Middletown, CT 06459 (United States)]. E-mail: jvarekamp@wesleyan.edu

    2007-07-15

    Mustard spinach plants were grown in mercury-spiked and contaminated soils collected in the field under controlled laboratory conditions over a full growth cycle to test if vegetation grown in these soils has discernible characteristics in visible/near-infrared (VNIR) spectra. Foliar Hg concentrations (0.174-3.993 ppm) of the Mustard spinach plants were positively correlated with Hg concentration of soils and varied throughout the growing season. Equations relating foliar Hg concentration to spectral reflectance, its first derivative, and selected vegetation indices were generated using stepwise multiple linear regression. Significant correlations are found for limited wavelengths for specific treatments and dates. Ratio Vegetation Index (RVI) and Red Edge Position (REP) values of plants in Hg-spiked and field-contaminated soils are significantly lower relative to control plants during the early and middle portions of the growth cycle which may be related to lower chlorophyll abundance or functioning in Hg-contaminated plants. - Some spectral characteristics of leaves of Brassica rapa P. may be associated with foliar mercury content.

  8. The application of Near-Infrared Reflectance Spectroscopy (NIRS) to detect melamine adulteration of soya bean meal.

    Science.gov (United States)

    Haughey, Simon A; Graham, Stewart F; Cancouët, Emmanuelle; Elliott, Christopher T

    2013-02-15

    Soya bean products are used widely in the animal feed industry as a protein based feed ingredient and have been found to be adulterated with melamine. This was highlighted in the Chinese scandal of 2008. Dehulled soya (GM and non-GM), soya hulls and toasted soya were contaminated with melamine and spectra were generated using Near Infrared Reflectance Spectroscopy (NIRS). By applying chemometrics to the spectral data, excellent calibration models and prediction statistics were obtained. The coefficients of determination (R(2)) were found to be 0.89-0.99 depending on the mathematical algorithm used, the data pre-processing applied and the sample type used. The corresponding values for the root mean square error of calibration and prediction were found to be 0.081-0.276% and 0.134-0.368%, respectively, again depending on the chemometric treatment applied to the data and sample type. In addition, adopting a qualitative approach with the spectral data and applying PCA, it was possible to discriminate between the four samples types and also, by generation of Cooman's plots, possible to distinguish between adulterated and non-adulterated samples. Copyright © 2012 Elsevier Ltd. All rights reserved.

  9. The application of Near Infrared Reflectance Spectroscopy (NIRS for the quantitative analysis of hydrocortisone in primary materials

    Directory of Open Access Journals (Sweden)

    A. PITTAS

    2001-03-01

    Full Text Available Near Infrared Reflectance Spectroscopy (NIRS, coupled with fiber optic probes, has been shown to be a quick and reliable analytical tool for quality assurance and quality control in the pharmaceutical industry, both for verifications of raw materials and quantification of the active ingredients in final products. In this paper, a typical pharmaceutical product, hydrocortisone sodium succinate, is used as an example for the application of NIR spectroscopy for quality control. In order to develop an NIRS method with higher precision and accuracy than the official UV/VIS spectroscopic method (BP '99, 19 samples, taken from one year’s production and several prepared in the laboratory, having a hydrocortisone sodium succinate concentration in the range from 89.05%to 95.83 %, were analysed by NIR and UV/VIS spectroscopy. Three frequency ranges: 5939.73–5627.32 cm-1; 4863.64 – 4574.36 cm-1; 4308.23–4200.24 cm-1, with the best positive correlation between the changes in the spectral and concentration data, were chosen. The validity of the developed NIRS chemometric method for the determination of the hydrocortisone sodium succinate concentration, constructed by the partial least squares (PLS regression technique, is discussed. A correlation coefficient of 0.9758 and a standard error of cross validation (RMSECVof 1.06%were found between the UV/VI Sand òhe NIR spectroscopic results of the hydrocortisone sodium succinate concentration in the samples.

  10. Non-invasive characterization of colorants by portable diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy and chemometrics

    Science.gov (United States)

    Manfredi, Marcello; Barberis, Elettra; Aceto, Maurizio; Marengo, Emilio

    2017-06-01

    During the last years the need for non-invasive and non-destructive analytical methods brought to the development and application of new instrumentation and analytical methods for the in-situ analysis of cultural heritage objects. In this work we present the application of a portable diffuse reflectance infrared Fourier transform (DRIFT) method for the non-invasive characterization of colorants prepared according to ancient recipes and using egg white and Gum Arabic as binders. Approximately 50 colorants were analyzed with the DRIFT spectroscopy: we were able to identify and discriminate the most used yellow (i.e. yellow ochres, Lead-tin Yellow, Orpiment, etc.), red (i.e. red ochres, Hematite) and blue (i.e. Lapis Lazuli, Azurite, indigo) colorants, creating a complete DRIFT spectral library. The Principal Component Analysis-Discriminant Analysis (PCA-DA) was then employed for the colorants classification according to the chemical/mineralogical composition. The DRIFT analysis was also performed on a gouache painting of the artist Sutherland; and the colorants used by the painter were identified directly in-situ and in a non-invasive manner.

  11. Quantitative evaluation of multiple adulterants in roasted coffee by Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) and chemometrics.

    Science.gov (United States)

    Reis, Nádia; Franca, Adriana S; Oliveira, Leandro S

    2013-10-15

    The current study presents an application of Diffuse Reflectance Infrared Fourier Transform Spectroscopy for detection and quantification of fraudulent addition of commonly employed adulterants (spent coffee grounds, coffee husks, roasted corn and roasted barley) to roasted and ground coffee. Roasted coffee samples were intentionally blended with the adulterants (pure and mixed), with total adulteration levels ranging from 1% to 66% w/w. Partial Least Squares Regression (PLS) was used to relate the processed spectra to the mass fraction of adulterants and the model obtained provided reliable predictions of adulterations at levels as low as 1% w/w. A robust methodology was implemented that included the detection of outliers. High correlation coefficients (0.99 for calibration; 0.98 for validation) coupled with low degrees of error (1.23% for calibration; 2.67% for validation) confirmed that DRIFTS can be a valuable analytical tool for detection and quantification of adulteration in ground, roasted coffee. Copyright © 2013 Elsevier B.V. All rights reserved.

  12. Quartz crystal microbalance and infrared reflection absorption spectroscopy characterization of bisphenol A absorption in the poly(acrylate) thin films.

    Science.gov (United States)

    Li, Guifeng; Morita, Shigeaki; Ye, Shen; Tanaka, Masaru; Osawa, Masatoshi

    2004-02-01

    The absorption process of bisphenol A (BPA) in a number of poly(acrylate) thin films, such as poly(2-methoxyethyl acrylate) (PMEA), poly(ethyl acrylate) (PEA), poly(n-butyl methacrylate) (PBMA), and poly(methyl methacrylate) (PMMA), has been investigated by quartz crystal microbalance (QCM) and infrared reflection absorption spectroscopy (IRRAS) measurements. Both QCM and IRRAS measurements show that the BPA molecules absorb in PMEA, PEA, and PBMA thin films but not in PMMA thin film. The differences in the BPA absorption behavior are mainly attributed to the difference in the glass transition temperature (T(g)) between these polymers. This absorption behavior also depends on the BPA concentration and polymer film thickness. Furthermore, IRRAS characterization demonstrates that the hydrogen bonding is formed between the hydroxyl group in BPA and the carbonyl group in the poly(acrylate) thin films. BPA molecule absorbed in these polymer thin films can be removed by ethanol rinse treatment. By optimizing experimental conditions for the QCM electrode modified by PMEA thin film, detection limitation of approximately 1 ppb for BPA can be realized by the in situ QCM measurement. This method is expected to be a sensitive in situ detection way for trace BPA in the environmental study.

  13. Enhanced Single Seed Trait Predictions in Soybean (Glycine max) and Robust Calibration Model Transfer with Near-Infrared Reflectance Spectroscopy.

    Science.gov (United States)

    Hacisalihoglu, Gokhan; Gustin, Jeffery L; Louisma, Jean; Armstrong, Paul; Peter, Gary F; Walker, Alejandro R; Settles, A Mark

    2016-02-10

    Single seed near-infrared reflectance (NIR) spectroscopy predicts soybean (Glycine max) seed quality traits of moisture, oil, and protein. We tested the accuracy of transferring calibrations between different single seed NIR analyzers of the same design by collecting NIR spectra and analytical trait data for globally diverse soybean germplasm. X-ray microcomputed tomography (μCT) was used to collect seed density and shape traits to enhance the number of soybean traits that can be predicted from single seed NIR. Partial least-squares (PLS) regression gave accurate predictive models for oil, weight, volume, protein, and maximal cross-sectional area of the seed. PLS models for width, length, and density were not predictive. Although principal component analysis (PCA) of the NIR spectra showed that black seed coat color had significant signal, excluding black seeds from the calibrations did not impact model accuracies. Calibrations for oil and protein developed in this study as well as earlier calibrations for a separate NIR analyzer of the same design were used to test the ability to transfer PLS regressions between platforms. PLS models built from data collected on one NIR analyzer had minimal differences in accuracy when applied to spectra collected from a sister device. Model transfer was more robust when spectra were trimmed from 910 to 1679 nm to 955-1635 nm due to divergence of edge wavelengths between the two devices. The ability to transfer calibrations between similar single seed NIR spectrometers facilitates broader adoption of this high-throughput, nondestructive, seed phenotyping technology.

  14. An examination of the sequence of intersecting lines using attenuated total reflectance-Fourier transform infrared spectral imaging.

    Science.gov (United States)

    Bojko, Katherine; Roux, Claude; Reedy, Brian J

    2008-11-01

    In this study, the potential of attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectral imaging as a technique to determine the sequence of line crossings was examined. The technique was successful in determining the sequence of heterogeneous line intersections produced using ballpoint pens and laser printers. By imaging at characteristic frequencies, it was possible to form spectral images showing the spatial distribution of the materials. By examining the spectral images from the inks, it was possible to determine whether the ink was above or below the toner. In blind testing, ATR-FTIR spectral imaging results were directly compared to those obtained by eight experienced forensic document examiners using methods regularly employed in casework. ATR-FTIR spectral imaging was shown to achieve a 100% success rate in the blind tests, whereas some incorrect sequence determinations were made by the forensic document examiners when using traditional techniques. The technique was unable to image ink-jet printing, gel pens, roller ball pens, and felt-tip pens, and was also unable to determine the sequence of intersecting ballpoint pen lines.

  15. Determination of quality parameters of beers by the use of attenuated total reflectance-Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Llario, Rafael; Iñón, Fernando A; Garrigues, Salvador; de la Guardia, Miguel

    2006-04-15

    The estimation of important quality parameters of beers, such as original and real extracts and alcohol content, has been evaluated by attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) using a partial least square (PLS) calibration approach. Two sample populations, one consisting of 24 samples and other of 21 samples, obtained from the Spanish market and covering different types of beer were used. The first set was used for building and validating the model, whereas the second, measured 6 months after, was used for evaluating its robustness. The spectral range and the size of the calibration set and its suitability for building the PLS model have been evaluated. Considering a calibration set comprised of 12 samples, selected via hierarchical cluster analysis, and a validation data set of 11 samples, the absolute mean difference (d(x-y)) and standard deviation of mean differences (s(x-y)) of the real extract, original extract and alcohol content were 0.009 and 0.069% (w/w), -0.021 and 0.20% (w/w) and -0.003 and 0.130% (v/v), respectively. The maximum error for the prediction of any of these three parameters for a new sample did not exceed 2.5%. These values were practically invariant for both tested data sets. The developed methodology favourably compares with the automatic reference methodology in terms of speed and reagent consumption and waste generation.

  16. Left Prefrontal Activity Reflects the Ability of Vicarious Fear Learning: A Functional Near-Infrared Spectroscopy Study

    Directory of Open Access Journals (Sweden)

    Qingguo Ma

    2013-01-01

    Full Text Available Fear could be acquired indirectly via social observation. However, it remains unclear which cortical substrate activities are involved in vicarious fear transmission. The present study was to examine empathy-related processes during fear learning by-proxy and to examine the activation of prefrontal cortex by using functional near-infrared spectroscopy. We simultaneously measured participants’ hemodynamic responses and skin conductance responses when they were exposed to a movie. In this movie, a demonstrator (i.e., another human being was receiving a classical fear conditioning. A neutral colored square paired with shocks (CSshock and another colored square paired with no shocks (CSno-shock were randomly presented in front of the demonstrator. Results showed that increased concentration of oxygenated hemoglobin in left prefrontal cortex was observed when participants watched a demonstrator seeing CSshock compared with that exposed to CSno-shock. In addition, enhanced skin conductance responses showing a demonstrator's aversive experience during learning object-fear association were observed. The present study suggests that left prefrontal cortex, which may reflect speculation of others’ mental state, is associated with social fear transmission.

  17. Left prefrontal activity reflects the ability of vicarious fear learning: a functional near-infrared spectroscopy study.

    Science.gov (United States)

    Ma, Qingguo; Huang, Yujing; Wang, Lei

    2013-01-01

    Fear could be acquired indirectly via social observation. However, it remains unclear which cortical substrate activities are involved in vicarious fear transmission. The present study was to examine empathy-related processes during fear learning by-proxy and to examine the activation of prefrontal cortex by using functional near-infrared spectroscopy. We simultaneously measured participants' hemodynamic responses and skin conductance responses when they were exposed to a movie. In this movie, a demonstrator (i.e., another human being) was receiving a classical fear conditioning. A neutral colored square paired with shocks (CS(shock)) and another colored square paired with no shocks (CS(no-shock)) were randomly presented in front of the demonstrator. Results showed that increased concentration of oxygenated hemoglobin in left prefrontal cortex was observed when participants watched a demonstrator seeing CS(shock) compared with that exposed to CS(no-shock). In addition, enhanced skin conductance responses showing a demonstrator's aversive experience during learning object-fear association were observed. The present study suggests that left prefrontal cortex, which may reflect speculation of others' mental state, is associated with social fear transmission.

  18. Detection of aflatoxin and surface mould contaminated figs by using Fourier transform near-infrared reflectance spectroscopy.

    Science.gov (United States)

    Durmuş, Efkan; Güneş, Ali; Kalkan, Habil

    2017-01-01

    Aflatoxins are toxic metabolites that are mainly produced by members of the Aspergillus section Flavi on many agricultural products. Certain agricultural products such as figs are known to be high risk products for aflatoxin contamination. Aflatoxin contaminated figs may show a bright greenish yellow fluorescence (BGYF) under ultraviolet (UV) light at a wavelength of 365 nm. Traditionally, BGYF positive figs are manually selected by workers. However, manual selection depends on the expertise level of the workers and it may cause them skin-related health problems due to UV radiation. In this study, we propose a non-invasive approach to detect aflatoxin and surface mould contaminated figs by using Fourier transform near-infrared (FT-NIR) reflectance spectroscopy. A classification accuracy of 100% is achieved for classifying the figs into aflatoxin contaminated/uncontaminated and surface mould contaminated/uncontaminated categories. In addition, a strong correlation has been found between aflatoxin and surface mould. Combined with pattern classification methods, the NIR spectroscopy can be used to detect aflatoxin contaminated figs non-invasively. Furthermore, a positive correlation between surface mould and aflatoxin contamination leads to a promising alternative indicator for the detection of aflatoxin-contaminated figs. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  19. Rapid Analysis of the Quality of Amoxicillin and Clavulanate Potassium Tablets Using Diffuse Reflectance Near-Infrared Spectroscopy.

    Science.gov (United States)

    Chong, Xiao-Meng; Zou, Wen-Bo; Yao, Shang-Chen; Hu, Chang-Qin

    2017-05-01

    The cycle-closed dimer of amoxicillin influences its critical quality and is an important impurity in amoxicillin and clavulanate potassium tablets. The quality of the tablets could be rapidly evaluated using the impurity as an indicator. Here, we report a quantitative model to determine the cycle-closed dimer in samples from different manufacturers using diffuse reflectance near-infrared (NIR) spectroscopy by partial least squares regression for one y variable (PLS1) and hierarchical cluster analysis. Because the contents of the (active pharmaceutical ingredients) APIs (amoxicillin and clavulanate potassium) and water are also the important indexes of the tablet quality, three other quantitative models were used to confirm the API data and water content. All of the four models facilitate rapid and complete control of the tablet quality. In addition, quantitative models were validated in terms of specificity, linearity, accuracy, repeatability, and intermediate precision according to the International Conference on Harmonisation guidelines by evaluating the characteristics of the NIR spectra. These results confirmed that the models were satisfactory.

  20. Recognition of Banknote Fitness Based on a Fuzzy System Using Visible Light Reflection and Near-infrared Light Transmission Images.

    Science.gov (United States)

    Kwon, Seung Yong; Pham, Tuyen Danh; Park, Kang Ryoung; Jeong, Dae Sik; Yoon, Sungsoo

    2016-06-11

    Fitness classification is a technique to assess the quality of banknotes in order to determine whether they are usable. Banknote classification techniques are useful in preventing problems that arise from the circulation of substandard banknotes (such as recognition failures, or bill jams in automated teller machines (ATMs) or bank counting machines). By and large, fitness classification continues to be carried out by humans, and this can cause the problem of varying fitness classifications for the same bill by different evaluators, and requires a lot of time. To address these problems, this study proposes a fuzzy system-based method that can reduce the processing time needed for fitness classification, and can determine the fitness of banknotes through an objective, systematic method rather than subjective judgment. Our algorithm was an implementation to actual banknote counting machine. Based on the results of tests on 3856 banknotes in United States currency (USD), 3956 in Korean currency (KRW), and 2300 banknotes in Indian currency (INR) using visible light reflection (VR) and near-infrared light transmission (NIRT) imaging, the proposed method was found to yield higher accuracy than prevalent banknote fitness classification methods. Moreover, it was confirmed that the proposed algorithm can operate in real time, not only in a normal PC environment, but also in an embedded system environment of a banknote counting machine.

  1. Recognition of Banknote Fitness Based on a Fuzzy System Using Visible Light Reflection and Near-infrared Light Transmission Images

    Directory of Open Access Journals (Sweden)

    Seung Yong Kwon

    2016-06-01

    Full Text Available Fitness classification is a technique to assess the quality of banknotes in order to determine whether they are usable. Banknote classification techniques are useful in preventing problems that arise from the circulation of substandard banknotes (such as recognition failures, or bill jams in automated teller machines (ATMs or bank counting machines. By and large, fitness classification continues to be carried out by humans, and this can cause the problem of varying fitness classifications for the same bill by different evaluators, and requires a lot of time. To address these problems, this study proposes a fuzzy system-based method that can reduce the processing time needed for fitness classification, and can determine the fitness of banknotes through an objective, systematic method rather than subjective judgment. Our algorithm was an implementation to actual banknote counting machine. Based on the results of tests on 3856 banknotes in United States currency (USD, 3956 in Korean currency (KRW, and 2300 banknotes in Indian currency (INR using visible light reflection (VR and near-infrared light transmission (NIRT imaging, the proposed method was found to yield higher accuracy than prevalent banknote fitness classification methods. Moreover, it was confirmed that the proposed algorithm can operate in real time, not only in a normal PC environment, but also in an embedded system environment of a banknote counting machine.

  2. Feasibility of diffuse reflectance infrared Fourier spectroscopy (DRIFTS) to quantify iron-cyanide (Fe-CN) complexes in soil

    Science.gov (United States)

    Sut-Lohmann, Magdalena; Raab, Thomas

    2017-04-01

    Contaminated sites create a significant risk to human health, by poisoning drinking water, soil, air and as a consequence food. Continuous release of persistent iron-cyanide (Fe-CN) complexes from various industrial sources poses a high hazard to the environment and indicates the necessity to analyze considerable amount of samples. At the present time quantitative determination of Fe-CN concentration in soil usually requires a time consuming two step process: digestion of the sample (e.g., micro distillation system) and its analytical detection performed, e.g., by automated spectrophotometrical flow injection analysis (FIA). In order to determine the feasibility of diffuse reflectance infrared Fourier spectroscopy (DRIFTS) to quantify the Fe-CN complexes in soil matrix, 42 soil samples were collected (8 to 12.520 mg kg-1CN) indicating single symmetrical CN band in the range 2092 - 2084 cm-1. Partial least squares (PLS) calibration-validation model revealed IR response to CNtot exceeding 1268 mg kg-1 (limit of detection, LOD). Subsequently, leave-one-out cross-validation (LOO-CV) was performed on soil samples containing low CNtot (900 mg kg-1 resulted in LOD equal to 3494 mg kg-1. Our results indicate that spectroscopic data in combination with PLS statistics can efficiently be used to predict Fe-CN concentrations in soil. We conclude that the protocol applied in this study can strongly reduce the time and costs essential for the spatial and vertical screening of the site affected by complexed Fe-CN.

  3. Monitoring closed head injury induced changes in brain physiology with orthogonal diffuse near-infrared reflectance spectroscopy

    Science.gov (United States)

    Abookasis, David; Shochat, Ariel; Mathews, Marlon S.

    2014-03-01

    We applied an orthogonal diffuse reflectance spectroscopy (o-DRS) to assess brain physiology following closed head injury (CHI). CHI was induced in anesthetized male mice by weight-drop device using ~50gram cylindrical metal falling from a height of 90 cm onto the intact scalp. A total of twenty-six mice were used in the experiments divided randomly into three groups as follows: Group 1 (n=11) consisted of injured mice monitored for 1 hour every 10 minutes. Group 2 (n=10) were the control mice not experience CHI. Group 3 (n=5) consisted of injured mice monitored every minute up to 20 minutes. Measurement of optical quantities of brain tissue (absorption and reduced scattering coefficients) in the near-infrared window from 650 to 1000 nm were carried out by employing different source-detector distances and locations to provide depth sensitivity. With respect to baseline, we found difference in brain hemodynamic properties following injury. In addition, o-DRS successfully evaluate the structural variations likely from evolving cerebral edema throughout exploring the scattering spectral shape.

  4. A mid-infrared carbon monoxide sensor system using wideband absorption spectroscopy and a single-reflection spherical optical chamber

    Science.gov (United States)

    Dong, Ming; Zheng, Chuantao; Miao, Shuzhuo; Song, Fang; Wang, Yiding

    2017-09-01

    A mid-infrared carbon monoxide (CO) sensor system based on a dual-channel differential detection method was developed using a broadband light source in the 4.60 μm wavelength region and a single-reflection spherical optical chamber with ∼0.373 m absorption path length. CO detection was realized by targeting the wideband strong absorption lines within 4.55-4.65 μm. A dual-channel pyroelectric detector as well as a self-developed digital signal processor (DSP) based orthogonal lock-in amplifier was employed to process CO sensing signal. A minimum detection limit of ∼0.5 ppm in volume (ppmv) was achieved with a measurement time of 6 s, based on an Allan deviation analysis of the sensor system. The response time (1000 → 0 ppmv) was determined to be ∼7 s for the CO sensor operation. Due to the characteristics of low detection limit, fast response time and high cost performance, the proposed sensor has relatively good prospect in coal-mining operation.

  5. Rapid intra-operative diagnosis of kidney cancer by attenuated total reflection infrared spectroscopy of tissue smears.

    Science.gov (United States)

    Pucetaite, Milda; Velicka, Martynas; Urboniene, Vidita; Ceponkus, Justinas; Bandzeviciute, Rimante; Jankevicius, Feliksas; Zelvys, Arunas; Sablinskas, Valdas; Steiner, Gerald

    2018-01-09

    Herein, a technique to analyze air-dried kidney tissue impression smears by means of attenuated total reflection infrared (ATR-IR) spectroscopy is presented. Spectral tumor markers-absorption bands of glycogen-are identified in the ATR-IR spectra of the kidney tissue smear samples. Thin kidney tissue cryo-sections currently used for IR spectroscopic analysis lack such spectral markers as the sample preparation causes irreversible molecular changes in the tissue. In particular, freeze-thaw cycle results in degradation of the glycogen and reduction or complete dissolution of its content. Supervised spectral classification was applied to the recorded spectra of the smears and the test spectra were classified with a high accuracy of 92% for normal tissue and 94% for tumor tissue, respectively. For further development, we propose that combination of the method with optical fiber ATR probes could potentially be used for rapid real-time intra-operative tissue analysis without interfering with either the established protocols of pathological examination or the ordinary workflow of operating surgeon. Such approach could ensure easier transition of the method to clinical applications where it may complement the results of gold standard histopathology examination and aid in more precise resection of kidney tumors. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Far infrared near normal specular reflectivity of Nix(SiO2)1-x (x = 1.0, 0.84, 0.75, 0.61, 0.54, 0.28) granular films

    KAUST Repository

    Massa, Néstor E.

    2010-04-01

    One of the current issues at the basis of the understanding of novel materials is the degree of the role played by spatial inhomogeneities due to subtle phase separations. To clarify this picture here we compare the plain glass network response of transition metal granular films with different metal fractions against what is known for conducting oxides. Films for Nix(SiO2)1-x (x = 1.0, 0.84, 0.75, 0.61, 0.54, 0.28) were studied by temperature dependent far infrared measurements. While for pure Ni the spectrum shows a flat high reflectivity, those for x ∼ 0.84 and ∼0.75 have a Drude component, vibrational modes mostly carrier screened, and a long tail that extents toward near infrared. This is associated with hopping electron conductivity and strong electron-phonon interactions. The relative reduction of the number of carriers in Ni0.75(SiO2)0.25 allows less screened phonon bands on the top of a continuum and a wide and overdamped oscillator at mid-infrared frequencies. Ni0.54(SiO2)0.46 and Ni0.28(SiO2)0.72 have well defined vibrational bands and a sharp threshold at ∼1450 cm-1. It is most remarkable that a distinctive resonant peak at ∼1250 cm-1 found for p-polarized angle dependent specular reflectivity. It originates in an electron cloud traced to electrons that are not able to overcome the metal-dielectric interface that, beating against the positive background, generates the electric dipole. Overall, we conclude that the spectra are analogous to those regularly found in conducting oxides where with a suitable percolating network polarons are formed. © 2009 Elsevier B.V. All rights reserved.

  7. Direct observation of hopping induced spin polarization current in oxygen deficient Co-doped ZnO by Andreev reflection technique

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Kung-Shang; Huang, Tzu-Yu; Dwivedi, G.D. [Department of Physics, National Sun Yat-sen University, Kaohsiung, Taiwan (China); Lin, Lu-Kuei; Lee, Shang-Fan [Taiwan Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Sun, Shih-Jye [Department of Applied Physics, National Kaohsiung University, Kaohsiung, Taiwan (China); Chou, Hsiung, E-mail: hchou@mail.nsysu.edu.tw [Department of Physics, National Sun Yat-sen University, Kaohsiung, Taiwan (China)

    2017-07-01

    Highlights: • Co-doped ZnO thin-films were grown with varying V{sub O} concentartion. • PCAR measurements were done to study the SPC. • High spin polarization was observed above a certain V{sub O} concentartion. • High V{sub O} samples provide a high density of completed percolation path. • This complete percolation path gives rise to high SPC. - Abstract: Oxygen vacancy induced ferromagnetic coupling in diluted magnetic oxide (DMO) semiconductors have been reported in several studies, but technologically more crucial spin-polarized current (SPC) is still under-developed in DMOs. Few studies have claimed that VRH mechanism can originate the SPC, but, how VRH mechanism associated with percolation path, is not clearly understood. We used Point-contact Andreev reflection (PCAR) technique to probe the SPC in Co-doped ZnO (CZO) films. Since the high resistance samples cause broadening in conductance(G)-voltage(V) curves, which may result in an unreliable evaluation of spin polarization, we include two extra parameters, (i) effective temperature and (ii) spreading resistance, for the simulation to avoid the uncertainty in extracting spin polarization. The effective G-V curves and higher spin polarization can be obtained above a certain oxygen vacancy concentration. The number of completed and fragmentary percolation paths is proportional to the concentration of oxygen vacancies. For low oxygen vacancy samples, the Pb-tip has a higher probability of covering fragmentary percolation paths than the complete ones, due to its small contact size. The completed paths may remain independent of one another and get polarized in different directions, resulting in lower spin-polarization value. High oxygen vacancy samples provide a high density of completed path, most of them link to one another by crossing over, and gives rise to high spin-polarization value.

  8. A fast radiative transfer model for visible through shortwave infrared spectral reflectances in clear and cloudy atmospheres

    International Nuclear Information System (INIS)

    Wang, Chenxi; Yang, Ping; Nasiri, Shaima L.; Platnick, Steven; Baum, Bryan A.; Heidinger, Andrew K.; Liu, Xu

    2013-01-01

    A computationally efficient radiative transfer model (RTM) for calculating visible (VIS) through shortwave infrared (SWIR) reflectances is developed for use in satellite and airborne cloud property retrievals. The full radiative transfer equation (RTE) for combinations of cloud, aerosol, and molecular layers is solved approximately by using six independent RTEs that assume the plane-parallel approximation along with a single-scattering approximation for Rayleigh scattering. Each of the six RTEs can be solved analytically if the bidirectional reflectance/transmittance distribution functions (BRDF/BTDF) of the cloud/aerosol layers are known. The adding/doubling (AD) algorithm is employed to account for overlapped cloud/aerosol layers and non-Lambertian surfaces. Two approaches are used to mitigate the significant computational burden of the AD algorithm. First, the BRDF and BTDF of single cloud/aerosol layers are pre-computed using the discrete ordinates radiative transfer program (DISORT) implemented with 128 streams, and second, the required integral in the AD algorithm is numerically implemented on a twisted icosahedral mesh. A concise surface BRDF simulator associated with the MODIS land surface product (MCD43) is merged into a fast RTM to accurately account for non-isotropic surface reflectance. The resulting fast RTM is evaluated with respect to its computational accuracy and efficiency. The simulation bias between DISORT and the fast RTM is large (e.g., relative error >5%) only when both the solar zenith angle (SZA) and the viewing zenith angle (VZA) are large (i.e., SZA>45° and VZA>70°). For general situations, i.e., cloud/aerosol layers above a non-Lambertian surface, the fast RTM calculation rate is faster than that of the 128-stream DISORT by approximately two orders of magnitude. -- Highlights: ► An efficient radiative transfer model is developed for cloud remote sensing. ► Multi-layered clouds and a non-Lambertian surface can be fully considered.

  9. Temperature dependence of the phonon structure in the high-temperature superconductor Bi2Sr2CaCu2O8 studied by infrared reflectance spectroscopy

    International Nuclear Information System (INIS)

    Kamaras, K.; Herr, S.L.; Porter, C.D.; Tanner, D.B.; Etemad, S.; Tarascon, J.

    1991-01-01

    We have investigated a ceramic sample of the high-temperature superconductor Bi 2 Sr 2 CaCu 2 O 8 (T c =85 K) by infrared and visible reflectance spectroscopy at several temperatures both below and above the superconducting transition. We find that the temperature variation in the vibrational region is associated with minima or antiresonance features of the optical conductivity, instead of maxima, indicating strong Fano-type electron-phonon interaction and implying that the phonon structure in the infrared is strongly affected by the ab-plane response

  10. Characterization of silver halide fiber optics and hollow silica waveguides for use in the construction of a mid-infrared attenuated total reflection fourier transform infrared (ATR FT-IR) spectroscopy probe.

    Science.gov (United States)

    Damin, Craig A; Sommer, André J

    2013-11-01

    Advances in fiber optic materials have allowed for the construction of fibers and waveguides capable of transmitting infrared radiation. An investigation of the transmission characteristics associated with two commonly used types of infrared-transmitting fibers/waveguides for prospective use in a fiber/waveguide-coupled attenuated total internal reflection (ATR) probe was performed. Characterization of silver halide polycrystalline fiber optics and hollow silica waveguides was done on the basis of the transmission of infrared light using a conventional fiber optic coupling accessory and an infrared microscope. Using the fiber optic coupling accessory, the average percent transmission for three silver halide fibers was 18.1 ± 6.1% relative to a benchtop reflection accessory. The average transmission for two hollow waveguides (HWGs) using the coupling accessory was 8.0 ± 0.3%. (Uncertainties in the relative percent transmission represent the standard deviations.) Reduced transmission observed for the HWGs was attributed to the high numerical aperture of the coupling accessory. Characterization of the fibers/waveguides using a zinc selenide lens objective on an infrared microscope indicated 24.1 ± 7.2% of the initial light input into the silver halide fibers was transmitted. Percent transmission obtained for the HWGs was 98.7 ± 0.1%. Increased transmission using the HWGs resulted from the absence or minimization of insertion and scattering losses due to the hollow air core and a better-matched numerical aperture. The effect of bending on the transmission characteristics of the fibers/waveguides was also investigated. Significant deviations in the transmission of infrared light by the solid-core silver halide fibers were observed for various bending angles. Percent transmission greater than 98% was consistently observed for the HWGs at the bending angles. The combined benefits of high percent transmission, reproducible instrument responses, and increased bending

  11. Evaluation of Diffuse Reflection Infrared Spectrometry for End-of-Shift Measurement of α-quartz in Coal Dust Samples.

    Science.gov (United States)

    Miller, Arthur L; Murphy, Nathaniel C; Bayman, Sean J; Briggs, Zachary P; Kilpatrick, Andrew D; Quinn, Courtney A; Wadas, Mackenzie R; Cauda, Emanuele G; Griffiths, Peter R

    2015-01-01

    The inhalation of toxic substances is a major threat to the health of miners, and dust containing respirable crystalline silica (α-quartz) is of particular concern, due to the recent rise in cases of coal workers' pneumoconiosis and silicosis in some U.S. mining regions. Currently, there is no field-portable instrument that can measure airborne α-quartz and give miners timely feedback on their exposure. The U.S. National Institute for Occupational Safety and Health (NIOSH) is therefore conducting studies to investigate technologies capable of end-of-shift or real-time measurement of airborne quartz. The present study focuses on the potential application of Fourier transform infrared (FT-IR) spectrometry conducted in the diffuse reflection (DR) mode as a technique for measuring α-quartz in respirable mine dust. A DR accessory was used to analyze lab-generated respirable samples of Min-U-Sil 5 (which contains more than 90% α-quartz) and coal dust, at mass loadings in the ranges of 100-600 μg and 600-5300 μg, respectively. The dust samples were deposited onto three different types of filters, borosilicate fiberglass, nylon, and polyvinyl chloride (PVC). The reflectance, R, was calculated by the ratio of a blank filter and a filter with deposited mine dust. Results suggest that for coal and pure quartz dusts deposited on 37 mm PVC filters, measurements of -log R correlate linearly with known amounts of quartz on filters, with R(2) values of approximately 0.99 and 0.94, respectively, for samples loaded up to ∼4000 μg. Additional tests were conducted to measure quartz in coal dusts deposited onto the borosilicate fiberglass and nylon filter media used in the NIOSH-developed Personal Dust Monitor (PDM). The nylon filter was shown to be amenable to DR analysis, but quantification of quartz is more accurate when the filter is "free," as opposed to being mounted in the PDM filter holder. The borosilicate fiberglass filters were shown to produce excessive

  12. Application of partial least-squares regression to near-infrared reflectance spectroscopic determination of shive content in flax.

    Science.gov (United States)

    Sohn, Miryeong; Barton, Franklin E; Morrison, Wiley H; Archibald, Douglas D

    2003-05-01

    Shive, the nonfiberous core portion of the stem, in flax fiber after retting is related to fiber quality. The objective of this study is to develop a standard calibration model for determining shive content in retted flax by using near-infrared reflectance spectroscopy. Calibration samples were prepared by manually mixing pure, ground shive and pure, ground fiber from flax retted by three different methods (water, dew, and enzyme retting) to provide a wide range of shive content from 0 to 100%. Partial least-squares (PLS) regression was used to generate a calibration model, and spectral data were processed using various pretreatments such as a multiplicative scatter correction (MSC), normalization, derivatives, and Martens' Uncertainty option to improve the calibration model. The calibration model developed with a single sample set resulted in a standard error of 1.8% with one factor. The best algorithm was produced from first-derivative processing of the spectral data. MSC was not effective processing for this model. However, a big bias was observed when independent sample sets were applied to this calibration model to predict shive content in flax fiber. The calibration model developed using a combination sample set showed a slightly higher standard error and number of factors compared to the model for a single sample set, but this model was sufficiently accurate to apply to each sample set. The best algorithm for the combination sample set was generated from second derivatives followed by MSC processing of spectral data and from Martens' Uncertainty option; it resulted in a standard error of 2.3% with 2 factors. The value of the digital second derivative centered at 1674 nm for these spectral data was highly correlated to shive content of flax and could form the basis for a simple, low-cost sensor for the shive or fiber content in retted flax.

  13. Visible/near infrared reflectance (VNIR) spectroscopy for detecting twospotted spider mite (Acari: Tetranychidae) damage in strawberries.

    Science.gov (United States)

    Fraulo, Aimee B; Cohen, Matthew; Liburd, Oscar E

    2009-02-01

    The twospotted spider mite, Tetranychus urticae Koch, is among the most economically important pests in strawberries (Fragaria spp.). As T. urticae feeds, it ingests mesophyll cells that contain pigments essential for physiologic function and alters radiant energy use of the leaf tissue, severely compromising plant health and productivity. In our study, diffuse reflectance spectroscopy in the visible and near infrared (VNIR) portions of the spectrum was used to identify specific spectral regions altered by T. urticae feeding and to quantitatively assess T. urticae density. During the 2006-2007 growing season, 80 strawberry leaflets with varying levels of T. urticae infestation were collected. Spectral classification of both mite density (continuous) and mite density class (categorical) were developed. Spider mite density classes were low infestation (0-20 mites/leaflet), moderate infestation (20-50 mites/leaflet), and high infestation (> or = 50 mites/leaflet). Continuous spectral prediction for leaf infestation was developed using partial least squares (PLS) regression. Classification trees were used to train spectra to categorical levels of infestation. Both models were calibrated with 67% of the samples, and accuracy was evaluated using the remaining 33%. Categorical validation accuracy was 81%, with odds ratios for correctly predicting extreme categories (low and high) of 33 and 47.7, respectively. Continuous validation efficiency was also high, with an r2 between predicted and observed of 0.85 and a root-mean-squared error (RMSE) of 12.2 mites per leaf. Developing a spectral pest monitoring system would provide a diagnostic tool allowing early and effective intervention for precision management of T. urticae in strawberry.

  14. OSIRIS (Observing System Including PolaRisation in the Solar Infrared Spectrum) instrument: a multi-directional, polarized radiometer in the visible and shortwave infrared, airborne prototype of 3MI / EPS-SG Eumetsat - ESA mission

    Science.gov (United States)

    Matar, C.; Auriol, F.; Nicolas, J. M.; Parol, F.; Riedi, J.; Djellali, M. S.; Cornet, C.; Waquet, F.; Catalfamo, M.; Delegove, C.; Loisil, R.

    2017-12-01

    OSIRIS instrument largely inherits from the POLDER concept developed and operated between 1991 (first airborne prototype) and 2013 (end of the POLDER-3/PARASOL space-borne mission). It consists in two optical systems, one covering the visible to near infrared range (440, 490, 670, 763, 765, 870, 910 and 940 nm) and a second one for the shortwave infrared (940, 1020, 1240, 1360, 1620 and 2200 nm). Each optical system is composed of a wide field-of-view optics (114° and 105° respectively) associated to two rotating wheels with interferential filters (spectral) and analyzers filters (polarization) respectively, and a 2D array of detectors. For each channel, radiance is measured once without analyzer, followed by sequential measurements with the three analyzers shifted by an angle of 60° to reconstruct the total and polarized radiances. The complete acquisition sequence for all spectral channels last a couple of seconds according to the chosen measurement protocol. Thanks to the large field of view of the optics, any target is seen under several viewing angles during the aircraft motion. In a first step we will present the new ground characterization of the instrument based on laboratory measurements (linearity, flat-field, absolute calibration, induced polarization, polarizers efficiency and position), the radiometric model and the Radiometric Inverted Model (RIM) used to develop the Level 1 processing chain that is used to produce level 1 products (normalized radiances, polarized or not, with viewing geometries) from the instrument generated level 0 files (Digital Counts) and attitude information from inertial system. The stray light issues will be specifically discussed. In a second step we will present in-flight radiometric and geometric methods applied to OSIRIS data in order to control and validate ground-based calibrated products: molecular scattering method and sun-glint cross-band method for radiometric calibration, glories, rainbows and sun-glint targets

  15. Infrared imaging of cotton fiber bundles using a focal plane array detector and a single reflectance accessory

    Science.gov (United States)

    Infrared imaging is gaining attention as a technique used in the examination of cotton fibers. This type of imaging combines spectral analysis with spatial resolution to create visual images that examine sample composition and distribution. Herein, we report the use of an infrared instrument equippe...

  16. The O{sub 2} A-Band in the Fluxes and Polarization of Starlight Reflected by Earth-Like Exoplanets

    Energy Technology Data Exchange (ETDEWEB)

    Fauchez, Thomas [Laboratoire d’Optique Atmosphèrique (LOA), UMR 8518, Université Lille 1, Villeneuve d’Ascq (France); Rossi, Loic; Stam, Daphne M. [Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS Delft (Netherlands)

    2017-06-10

    Earth-like, potentially habitable exoplanets are prime targets in the search for extraterrestrial life. Information about their atmospheres and surfaces can be derived by analyzing the light of the parent star reflected by the planet. We investigate the influence of the surface albedo A {sub s}, the optical thickness b {sub cloud}, the altitude of water clouds, and the mixing ratio of biosignature O{sub 2} on the strength of the O{sub 2} A-band (around 760 nm) in the flux and polarization spectra of starlight reflected by Earth-like exoplanets. Our computations for horizontally homogeneous planets show that small mixing ratios ( η < 0.4) will yield moderately deep bands in flux and moderate-to-small band strengths in polarization, and that clouds will usually decrease the band depth in flux and the band strength in polarization. However, cloud influence will be strongly dependent on properties such as optical thickness, top altitude, particle phase, coverage fraction, and horizontal distribution. Depending on the surface albedo and cloud properties, different O{sub 2} mixing ratios η can give similar absorption-band depths in flux and band strengths in polarization, especially if the clouds have moderate-to-high optical thicknesses. Measuring both the flux and the polarization is essential to reduce the degeneracies, although it will not solve them, especially not for horizontally inhomogeneous planets. Observations at a wide range of phase angles and with a high temporal resolution could help to derive cloud properties and, once those are known, the mixing ratio of O{sub 2} or any other absorbing gas.

  17. Infrared reflectivity of the solid solutions LaNi1-xFexO3 (0.00<=x<=1.00)

    Science.gov (United States)

    Massa, Néstor E.; Falcón, Horacio; Salva, Horacio; Carbonio, Raúl E.

    1997-10-01

    We report temperature-dependent far- and midinfrared reflectivity spectra of LaNi(1-x)FexO3 (0.00Reik and Heese [H. G. Reik and D. Heese, J. Phys. Chem. Solids 28, 581 (1967)]. We find our spectral analysis relevant toward understanding the infrared reflectivity of conducting oxides in general. Since LaNiO3 is a three-dimensional compound we avoid the argument of misinterpreting spectral features as due to band leakages of unscreened phonons active in insulating crystal directions.

  18. Atomic charge transfer-counter polarization effects determine infrared CH intensities of hydrocarbons: a quantum theory of atoms in molecules model.

    Science.gov (United States)

    Silva, Arnaldo F; Richter, Wagner E; Meneses, Helen G C; Bruns, Roy E

    2014-11-14

    Atomic charge transfer-counter polarization effects determine most of the infrared fundamental CH intensities of simple hydrocarbons, methane, ethylene, ethane, propyne, cyclopropane and allene. The quantum theory of atoms in molecules/charge-charge flux-dipole flux model predicted the values of 30 CH intensities ranging from 0 to 123 km mol(-1) with a root mean square (rms) error of only 4.2 km mol(-1) without including a specific equilibrium atomic charge term. Sums of the contributions from terms involving charge flux and/or dipole flux averaged 20.3 km mol(-1), about ten times larger than the average charge contribution of 2.0 km mol(-1). The only notable exceptions are the CH stretching and bending intensities of acetylene and two of the propyne vibrations for hydrogens bound to sp hybridized carbon atoms. Calculations were carried out at four quantum levels, MP2/6-311++G(3d,3p), MP2/cc-pVTZ, QCISD/6-311++G(3d,3p) and QCISD/cc-pVTZ. The results calculated at the QCISD level are the most accurate among the four with root mean square errors of 4.7 and 5.0 km mol(-1) for the 6-311++G(3d,3p) and cc-pVTZ basis sets. These values are close to the estimated aggregate experimental error of the hydrocarbon intensities, 4.0 km mol(-1). The atomic charge transfer-counter polarization effect is much larger than the charge effect for the results of all four quantum levels. Charge transfer-counter polarization effects are expected to also be important in vibrations of more polar molecules for which equilibrium charge contributions can be large.

  19. Ultra-wideband, Wide Angle and Polarization-insensitive Specular Reflection Reduction by Metasurface based on Parameter-adjustable Meta-Atoms

    Science.gov (United States)

    Su, Jianxun; Lu, Yao; Zhang, Hui; Li, Zengrui; (Lamar) Yang, Yaoqing; Che, Yongxing; Qi, Kainan

    2017-02-01

    In this paper, an ultra-wideband, wide angle and polarization-insensitive metasurface is designed, fabricated, and characterized for suppressing the specular electromagnetic wave reflection or backward radar cross section (RCS). Square ring structure is chosen as the basic meta-atoms. A new physical mechanism based on size adjustment of the basic meta-atoms is proposed for ultra-wideband manipulation of electromagnetic (EM) waves. Based on hybrid array pattern synthesis (APS) and particle swarm optimization (PSO) algorithm, the selection and distribution of the basic meta-atoms are optimized simultaneously to obtain the ultra-wideband diffusion scattering patterns. The metasurface can achieve an excellent RCS reduction in an ultra-wide frequency range under x- and y-polarized normal incidences. The new proposed mechanism greatly extends the bandwidth of RCS reduction. The simulation and experiment results show the metasurface can achieve ultra-wideband and polarization-insensitive specular reflection reduction for both normal and wide-angle incidences. The proposed methodology opens up a new route for realizing ultra-wideband diffusion scattering of EM wave, which is important for stealth and other microwave applications in the future.

  20. Direct measurement of the static and transient magneto-optical permittivity of cobalt across the entire M -edge in reflection geometry by use of polarization scanning

    Science.gov (United States)

    Zusin, Dmitriy; Tengdin, Phoebe M.; Gopalakrishnan, Maithreyi; Gentry, Christian; Blonsky, Adam; Gerrity, Michael; Legut, Dominik; Shaw, Justin M.; Nembach, Hans T.; Silva, T. J.; Oppeneer, Peter M.; Kapteyn, Henry C.; Murnane, Margaret M.

    2018-01-01

    The microscopic state of a magnetic material is characterized by its resonant magneto-optical response through the off-diagonal dielectric tensor component ɛx y. However, the measurement of the full complex ɛx y in the extreme ultraviolet spectral region covering the M absorption edges of 3 d ferromagnets is challenging due to the need for either a careful polarization analysis, which is complicated by a lack of efficient polarization analyzers, or scanning the angle of incidence in fine steps. Here, we propose and demonstrate a technique to extract the complex resonant permittivity ɛx y simply by scanning the polarization angle of linearly polarized high harmonics to measure the magneto-optical asymmetry in reflection geometry. Because this technique is more practical and faster to experimentally implement than previous approaches, we can directly measure the full time evolution of ɛx y(t ) during laser-induced demagnetization across the entire M2 ,3 absorption edge of cobalt with femtosecond time resolution. We find that for polycrystalline Co films on an insulating substrate, the changes in ɛx y are uniform throughout the spectrum, to within our experimental precision. This result suggests that, in the regime of strong demagnetization, the ultrafast demagnetization response is primarily dominated by magnon generation. We estimate the contribution of exchange-splitting reduction to the ultrafast demagnetization process to be no more than 25%.

  1. Application of laboratory and portable attenuated total reflectance infrared spectroscopic approaches for rapid quantification of alpaca serum immunoglobulin G.

    Directory of Open Access Journals (Sweden)

    Ibrahim Elsohaby

    Full Text Available The objective of this study was to develop and compare the performance of laboratory grade and portable attenuated total reflectance infrared (ATR-IR spectroscopic approaches in combination with partial least squares regression (PLSR for the rapid quantification of alpaca serum IgG concentration, and the identification of low IgG (<1000 mg/dL, which is consistent with the diagnosis of failure of transfer of passive immunity (FTPI in neonates. Serum samples (n = 175 collected from privately owned, healthy alpacas were tested by the reference method of radial immunodiffusion (RID assay, and laboratory grade and portable ATR-IR spectrometers. Various pre-processing strategies were applied to the ATR-IR spectra that were linked to corresponding RID-IgG concentrations, and then randomly split into two sets: calibration (training and test sets. PLSR was applied to the calibration set and calibration models were developed, and the test set was used to assess the accuracy of the analytical method. For the test set, the Pearson correlation coefficients between the IgG measured by RID and predicted by both laboratory grade and portable ATR-IR spectrometers was 0.91. The average differences between reference serum IgG concentrations and the two IR-based methods were 120.5 mg/dL and 71 mg/dL for the laboratory and portable ATR-IR-based assays, respectively. Adopting an IgG concentration <1000 mg/dL as the cut-point for FTPI cases, the sensitivity, specificity, and accuracy for identifying serum samples below this cut point by laboratory ATR-IR assay were 86, 100 and 98%, respectively (within the entire data set. Corresponding values for the portable ATR-IR assay were 95, 99 and 99%, respectively. These results suggest that the two different ATR-IR assays performed similarly for rapid qualitative evaluation of alpaca serum IgG and for diagnosis of IgG <1000 mg/dL, the portable ATR-IR spectrometer performed slightly better, and provides more flexibility for

  2. Detection and identification of multiple adulterants in plant food supplements using attenuated total reflectance-Infrared spectroscopy.

    Science.gov (United States)

    Deconinck, E; Aouadi, C; Bothy, J L; Courselle, P

    2018-04-15

    Due to the rising popularity of dietary supplements, especially plant food supplements, and alternative herbal medicines, a whole market developed and these products became freely available through internet. Though several searches revealed that at least a part of these products, especially the ones obtained from websites disclosing their physical identity, are aldulterated with pharmaceutical compounds. This causes a threat for public health, since these compounds are not declared and therefore adverse effects will not immediately be related to the product. The more the adulterants can interfere with other medicinal treatments. Since the present active pharmaceutical ingredients are not declared on the package and the products are sold as 100% natural or herbal in nature, it is very difficult for custom personnel to discriminate between products to be confiscated or not. Therefore easy to apply analytical approaches to discriminate between adulterated and non-adulterated products are necessary. This paper presents an approach based on infrared spectroscopy combined with attenuated total reflectance (ATR) and partial least squares- discriminant analysis (PLS-DA) to easily differentiate between adulterated and non- adulterated plant food supplements and to get a first idea of the nature of the adulterant present. The performance of PLS-DA models based on Mid-IR and NIR data were compared as well as models based on the combined data. Further three preprocessing strategies were compared. The best performance was obtained for a PLS-DA model using Mid-IR data with the second derivative as preprocessing method. This model showed a correct classification rate of 98.3% for an external test set. Also eight real samples were screened using the model and for seven of these samples a correct classification was obtained. Generally it could be concluded that the obtained model and the presented approach could be used at customs to discriminate between adulterated and non

  3. Measurement of the infrared optical constants for spectral modeling: n and k values for (NH4)2SO4 via single-angle reflectance and ellipsometric methods

    Energy Technology Data Exchange (ETDEWEB)

    Blake, Thomas A.; Brauer, Carolyn S.; Kelly-Gorham, Molly Rose K.; Burton, Sarah D.; Bliss, Mary; Myers, Tanya L.; Johnson, Timothy J.; Tiwald, Thomas E.

    2017-05-05

    The optical constants n and k can be used to model infrared spectra, including refraction, absorption, reflectance, and emissivity, but obtaining reliable values for solid materials (pure or otherwise) presents a challenge: In the past, the best results for n and k have been obtained from bulk, homogeneous materials, free of defects. That is, materials where the Fresnel equations are operant since there is no light scattering. Since it is often not possible to obtain a pure macroscopic (crystalline) material, it may be possible to press the material into a (uniform, void-free) disk. We have recently been able to do this with ammonium sulfate powder and then measured the n & k values via two independent methods: 1) Ellipsometry - which measures the changes in amplitude and phase of light reflected from the material of interest as a function of wavelength and angle of incidence, and 2) Single angle specular reflectance with an FT spectrometer using a specular reflectance device within an FT instrument which measures the change in amplitude of light reflected from the material of interest as a function of wavelength and angle of incidence over a wide wavelength range. The quality of the derived n & k values was tested by generating the reflectance spectra of the pellet and comparing to the calculated to measured reflectance spectra of the pure material which has been previously published. The comparison to literature values showed good accuracy and good agreement, indicating promise to measure other materials by such methods.

  4. Investigating Langmuir films at the air-water interface using a planar array infrared reflection-absorption spectrograph

    Science.gov (United States)

    Kim, Young Shin

    In this work, a new planar array infrared reflection-absorption spectrograph (PA-IRRAS) was developed to investigate a broad range of Langmuir films at the air-water interface. This instrument is capable of recording sample and reference spectra simultaneously with an optical setup that is the same as that of a single-beam instrument but splits the incident infrared beam into two sections on a plane mirror (H) or a water trough. With this design, the instrument could accommodate large infrared accessories, such as a water trough. In addition, water bands were subtracted to obtain a high quality spectrum for a poly(lactic acid) (PLA) Langmuir film on the water subphase with a resolution of about 8 cm-1 in 10.8 sec. With this instrument, two types of monolayer systems were studied; polymeric and lipid Langmuir films at the air-water interface. For the polymeric monolayer system, PA-IRRAS was used as a probe to follow the real-time conformational changes associated with intermolecular interactions of the polymer chains during the compression of the monolayers. It was found that the mixture of poly(D-lactic acid) (PDLA) and poly(L-lactic acid) (PLLA) (D/L) formed a stereocomplex when the mixed solution developed the two-dimensional monolayer at the air-water interface. The stereocomplexation occurred before film compression, indicating that there is no direct correlation between film compression and stereocomplexation. For the lipid monolayer system, PA-IRRAS was also used as a probe to investigate the origin of the disruption of a lipid monolayer upon protein adsorption at the air-water interface. Analysis of the time-resolved PA-IRRAS spectra revealed that Cu(II) ion-chelated DSIDA lipid monolayer (Cu 2+-DSIDA) was readily disrupted by myoglobin adsorption as demonstrated by a blue shift of 1.7 cm-1 and a lower intensity in the vas(CH2) stretch mode of the lipid monolayer over a period of five hours. To find the origin of the disruption of the lipid monolayer, a

  5. Photoionization of water molecules by a train of attosecond pulses assisted by a near-infrared laser: delay and polarization control

    Science.gov (United States)

    Martini, Lara; Boll, Diego I. R.; Fojón, Omar A.

    2017-08-01

    Basic reactions involving water molecules are essential to understand the interaction between radiation and the biological tissue because living cells are composed mostly by water. Therefore, the knowledge of ionization of the latter is crucial in many domains of Biology and Physics. So, we study theoretically the photoionization of water molecules by extreme ultraviolet attopulse trains assisted by lasers in the near-infrared range. We use a separable Coulomb-Volkov model in which the temporal evolution of the system can be divided into three stages allowing spatial and temporal separation for the Coulomb and Volkov final state wavefunctions. First, we analyze photoelectron angular distributions for different delays between the attopulse train and the assistant laser field. We compare our results for water and Ne atoms as they belong to the same isoelectronic series. Moreover, we contrast our calculations with previous theoretical and experimental work for Ar atoms due to the similarities of the orbitals involved in the reaction. Second, we study the effect of varying the relative orientations of the attopulse and laser field polarizations and we compare our predictions with other theories and experiments. We expect these studies contribute to the improvement of polarization experiments and the development of the attopulse trains and assistant laser fields technologies. Finally, we hope our work promote progress on the control of the chemical reactivity of water molecules since this could be useful in different fields such as radiobiology and medical physics.

  6. Sensing cocaine in saliva with attenuated total reflection infrared (ATR-IR) spectroscopy combined with a one-step extraction method

    Science.gov (United States)

    Hans, Kerstin M.-C.; Gianella, Michele; Sigrist, Markus W.

    2012-03-01

    On-site drug tests have gained importance, e.g., for protecting the society from impaired drivers. Since today's drug tests are majorly only positive/negative, there is a great need for a reliable, portable and preferentially quantitative drug test. In the project IrSens we aim to bridge this gap with the development of an optical sensor platform based on infrared spectroscopy and focus on cocaine detection in saliva. We combine a one-step extraction method, a sample drying technique and infrared attenuated total reflection (ATR) spectroscopy. As a first step we have developed an extraction technique that allows us to extract cocaine from saliva to an almost infrared-transparent solvent and to record ATR spectra with a commercially available Fourier Transform-infrared spectrometer. To the best of our knowledge this is the first time that such a simple and easy-to-use one-step extraction method is used to transfer cocaine from saliva into an organic solvent and detect it quantitatively. With this new method we are able to reach a current limit of detection around 10 μg/ml. This new extraction method could also be applied to waste water monitoring and controlling caffeine content in beverages.

  7. Comprehensive analysis of polar and apolar constituents of butter and margarine by nuclear magnetic resonance, reflecting quality and production processes.

    Science.gov (United States)

    Schripsema, Jan

    2008-04-23

    The separation of butter or margarine into polar (soluble in water) and apolar fractions (soluble in chloroform) and subsequent analysis of these fractions by (1)H NMR permits a comprehensive analysis of its constituents. In the polar fraction the preservatives benzoic and sorbic acid, the organic acids citric, lactic, butyric, acetic, and formic acid, and, furthermore, the carbohydrate lactose were quantified. In the apolar fraction the conjugated linoleic acid (CLA) rumenic acid, diglycerides, and linoleic acid were quantified. Rumenic acid is a characteristic component of ruminant fats and was found in all butter samples. The levels varied between 0.50 and 1.08%. Ten brands of Brazilian butter were investigated as was one brand from Norway. Also, two brands of margarine were investigated for comparison. A large variation in especially polar constituents was found between the butter samples, revealing the presence of preservatives in five brands of butter from Brazil, remarkable because these additives are legally not allowed. Furthermore, the levels of organic acids and lactose permitted conclusions about the production process and quality; for example, the presence of higher levels of free butyric acid indicate lipolysis, leading to a lower quality, and low levels of lactose indicate that after churning the residual milk fluids have been removed by an additional washing step in the production process.

  8. Fourier transform infrared-attenuated total reflectance (FTIR-ATR spectroscopy and chemometric techniques for the determination of adulteration in petrodiesel/biodiesel blends

    Directory of Open Access Journals (Sweden)

    Armando Guerrero Peña

    2014-06-01

    Full Text Available We propose an analytical method based on fourier transform infrared-attenuated total reflectance (FTIR-ATR spectroscopy to detect the adulteration of petrodiesel and petrodiesel/palm biodiesel blends with African crude palm oil. The infrared spectral fingerprints from the sample analysis were used to perform principal components analysis (PCA and to construct a prediction model using partial least squares (PLS regression. The PCA results separated the samples into three groups, allowing identification of those subjected to adulteration with palm oil. The obtained model shows a good predictive capacity for determining the concentration of palm oil in petrodiesel/biodiesel blends. Advantages of the proposed method include cost-effectiveness and speed; it is also environmentally friendly.

  9. Comparability of red/near-infrared reflectance and NDVI based on the spectral response function between MODIS and 30 other satellite sensors using rice canopy spectra.

    Science.gov (United States)

    Huang, Weijiao; Huang, Jingfeng; Wang, Xiuzhen; Wang, Fumin; Shi, Jingjing

    2013-11-26

    Long-term monitoring of regional and global environment changes often depends on the combined use of multi-source sensor data. The most widely used vegetation index is the normalized difference vegetation index (NDVI), which is a function of the red and near-infrared (NIR) spectral bands. The reflectance and NDVI data sets derived from different satellite sensor systems will not be directly comparable due to different spectral response functions (SRF), which has been recognized as one of the most important sources of uncertainty in the multi-sensor data analysis. This study quantified the influence of SRFs on the red and NIR reflectances and NDVI derived from 31 Earth observation satellite sensors. For this purpose, spectroradiometric measurements were performed for paddy rice grown under varied nitrogen levels and at different growth stages. The rice canopy reflectances were convoluted with the spectral response functions of various satellite instruments to simulate sensor-specific reflectances in the red and NIR channels. NDVI values were then calculated using the simulated red and NIR reflectances. The results showed that as compared to the Terra MODIS, the mean relative percentage difference (RPD) ranged from -12.67% to 36.30% for the red reflectance, -8.52% to -0.23% for the NIR reflectance, and -9.32% to 3.10% for the NDVI. The mean absolute percentage difference (APD) compared to the Terra MODIS ranged from 1.28% to 36.30% for the red reflectance, 0.84% to 8.71% for the NIR reflectance, and 0.59% to 9.32% for the NDVI. The lowest APD between MODIS and the other 30 satellite sensors was observed for Landsat5 TM for the red reflectance, CBERS02B CCD for the NIR reflectance and Landsat4 TM for the NDVI. In addition, the largest APD between MODIS and the other 30 satellite sensors was observed for IKONOS for the red reflectance, AVHRR1 onboard NOAA8 for the NIR reflectance and IKONOS for the NDVI. The results also indicated that AVHRRs onboard NOAA7-17 showed

  10. Evidence of a circularly polarized light mode along the optic axis in c-cut NH4H2PO4, induced by circular differential reflection and anomalous birefringence

    International Nuclear Information System (INIS)

    Kaminsky, Werner; Steininger, Steven; Herreros-Cedres, Javier; Glazer, Anthony Michael

    2010-01-01

    The anomalous birefringence and circular differential reflection of NH 4 H 2 PO 4 (4-bar2m), cut on the optic axis, have been found to cause an additional signal in measurements of the optical rotation employing polarized light technology, with the sample between crossed and slightly modulated linear polarizers (tilting high accuracy universal polarimetry). The azimuthal rotation of the linearly polarized light, up to 100 times larger than expected, is described in terms of a circularly polarized light mode along the optic axis of varying amplitude. Experimental evidence leading to our conclusion is given and a qualitative model for the effect is presented.

  11. Fourier transform infrared spectral detection of life in polar subsurface environments and its application to Mars exploration.

    Science.gov (United States)

    Preston, Louisa J; Johnson, Diane; Cockell, Charles S; Grady, Monica M

    2015-09-01

    Cryptoendolithic lichen communities of the Dry Valleys, Antarctica, survive in an extremely inhospitable environment, finding refuge in microscopic niches where conditions suitable for life exist. Such "within-rock" communities may have evolved on Mars when conditions for life on the surface deteriorated to such an extent that they could no longer survive. Fourier transform infrared spectroscopy of unprepared whole-rock Antarctic Beacon sandstones was used to vertically profile molecular vibrations of fatty acids, proteins, and carboxylic acids created by endolithic communities. Spectral biosignatures were found localized to lichen-rich areas and were absent in crustal regions and the bulk rock substrate. These cryptoendolithic profiles will aid similar spectroscopic investigations of organic biosignatures during future Martian subsurface studies and will help in the identification of similar communities in other localities across the Earth.

  12. Complex reflection coefficients of p- and s-polarized light at the pseudo-Brewster angle of a dielectric-conductor interface.

    Science.gov (United States)

    Azzam, R M A

    2013-10-01

    The complex Fresnel reflection coefficients r(p) and r(s) of p- and s-polarized light and their ratio ρ=r(p)/r(s) at the pseudo-Brewster angle (PBA) φ(pB) of a dielectric-conductor interface are evaluated for all possible values of the complex relative dielectric function ε=|ε|exp(-jθ)=ε(r)-jε(i), ε(i)>0 that share the same φ(pB). Complex-plane trajectories of r(p), r(s), and ρ at the PBA are presented at discrete values of φ(pB) from 5° to 85° in equal steps of 5° as θ is increased from 0° to 180°. It is shown that for φ(pB)>70° (high-reflectance metals in the IR) r(p) at the PBA is essentially pure negative imaginary and the reflection phase shift δ(p)=arg(r(p))≈-90°. In the domain of fractional optical constants (vacuum UV or light incidence from a high-refractive-index immersion medium) 0reflection phase shifts δ(p), δ(s), Δ=δ(p)-δ(s)=arg(ρ) are also determined as functions of φ(pB).

  13. Rapid determination of carbohydrates, ash, and extractives contents of straw using attenuated total reflectance fourier transform mid-infrared spectroscopy.

    Science.gov (United States)

    Tamaki, Yukihiro; Mazza, Giuseppe

    2011-06-22

    Analysis of the chemical components of lignocellulosic biomass is essential to understanding its potential for utilization. Mid-infrared spectroscopy and partial least-squares regression were used for rapid measurement of the carbohydrate (total glycans; glucan; xylan; galactan; arabinan; mannan), ash, and extractives content of triticale and wheat straws. Calibration models for total glycans, glucan, and extractives showed good and excellent predictive performance on the basis of slope, r², RPD, and R/SEP criteria. The xylan model showed good and acceptable predictive performance. However, the ash model was evaluated as providing only approximate quantification and screening. The models for galactan, arabinan, and mannan indicated poor and insufficient prediction for application. Most models could predict both triticale and wheat straw samples with the same degree of accuracy. Mid-infrared spectroscopic techniques coupled with partial least-squares regression can be used for rapid prediction of total glycans, glucan, xylan, and extractives in triticale and wheat straw samples.

  14. Multiple-algorithm parallel fusion of infrared polarization and intensity images based on algorithmic complementarity and synergy

    Science.gov (United States)

    Zhang, Lei; Yang, Fengbao; Ji, Linna; Lv, Sheng

    2018-01-01

    Diverse image fusion methods perform differently. Each method has advantages and disadvantages compared with others. One notion is that the advantages of different image methods can be effectively combined. A multiple-algorithm parallel fusion method based on algorithmic complementarity and synergy is proposed. First, in view of the characteristics of the different algorithms and difference-features among images, an index vector-based feature-similarity is proposed to define the degree of complementarity and synergy. This proposed index vector is a reliable evidence indicator for algorithm selection. Second, the algorithms with a high degree of complementarity and synergy are selected. Then, the different degrees of various features and infrared intensity images are used as the initial weights for the nonnegative matrix factorization (NMF). This avoids randomness of the NMF initialization parameter. Finally, the fused images of different algorithms are integrated using the NMF because of its excellent data fusing performance on independent features. Experimental results demonstrate that the visual effect and objective evaluation index of the fused images obtained using the proposed method are better than those obtained using traditional methods. The proposed method retains all the advantages that individual fusion algorithms have.

  15. Changes in hemp secondary fiber production related to technical fiber variability revealed by light microscopy and attenuated total reflectance Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Fernandez-Tendero, Eva; Day, Arnaud; Legros, Sandrine; Habrant, Anouck; Hawkins, Simon; Chabbert, Brigitte

    2017-01-01

    Interest in hemp (Cannabis sativa L.) is increasing due to the development of a new range of industrial applications based on bast fibers. However the variability of bast fiber yield and quality represents an important barrier to further exploitation. Primary and secondary fiber content was examined in two commercial hemp varieties (Fedora 17, Santhica 27) grown under contrasted sowing density and irrigation conditions. Both growing conditions and hemp varieties impact stem tissue architecture with a large effect on the proportion of secondary fibers but not primary fibers. Attenuated total reflectance infrared spectroscopy allowed the discrimination of manually-isolated native primary fibers and secondary fibers but did not reveal any clustering according to growing conditions and variety. Infrared data were confirmed by wet chemistry analyses that revealed slight but significant differences between primary and secondary fiber cell wall composition. Infrared spectroscopy of technical fibers obtained after mechanical defibering revealed differences with native primary, but not secondary fibers and also discriminated samples obtained from plants grown under different conditions. Altogether the results suggested that the observed variability of hemp technical fibers could be partially explained by i) differences in secondary fiber production and ii) differential behavior during mechanical defibering resulting in unequal separation of primary and secondary fibers.

  16. The polarization of light in coastal and open oceans: Reflection and transmission by the air-sea interface and application for the retrieval of water optical properties

    Science.gov (United States)

    Foster, Robert

    For decades, traditional remote sensing retrieval methods that rely solely on the spectral intensity of the water-leaving light have provided indicators of aquatic ecosystem health. With the increasing demand for new water quality indicators and improved accuracy of existing ones, the limits of traditional remote sensing approaches are becoming apparent. Use of the additional information intrinsic to the polarization state of light is therefore receiving more attention. One of the major challenges inherent in any above-surface determination of the water-leaving radiance, scalar or vector, is the removal of extraneous light which has not interacted with the water body and is therefore not useful for remote sensing of the water itself. Due in-part to the lack of a proven alternative, existing polarimeter installations have thus far assumed that such light was reflected by a flat sea surface, which can lead to large inaccuracies in the water-leaving polarization signal. This dissertation rigorously determines the full Mueller matrices for both surface-reflected skylight and upwardly transmitted light by a wind-driven ocean surface. A Monte Carlo code models the surface in 3D and performs polarized ray-tracing, while a vector radiative transfer (VRT) simulation generates polarized light distributions from which the initial Stokes vector for each ray is inferred. Matrices are computed for the observable range of surface wind speeds, viewing and solar geometries, and atmospheric aerosol loads. Radiometer field-of-view effects are also assessed. Validation of the results is achieved using comprehensive VRT simulations of the atmosphere-ocean system based on several oceanographic research cruises and specially designed polarimeters developed by the City College of New York: one submerged beneath the surface and one mounted on a research vessel. When available, additional comparisons are made at 9 km altitude with the NASA Research Scanning Polarimeter (RSP). Excellent

  17. Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR FT-IR) Applied to Study the Distribution of Ink Components in Printed Newspapers.

    Science.gov (United States)

    Gómez, Nuria; Molleda, Cristina; Quintana, Ester; Carbajo, José M; Rodríguez, Alejandro; Villar, Juan C

    2016-09-01

    A new method was developed to study how the oil and cyan pigments of cold-set ink are distributed in newspaper thickness. The methodology involved laboratory printing followed by delamination of the printed paper. The unprinted side, printed side, and resulting layers were analyzed using attenuated total reflection Fourier transform infrared spectroscopy (ATR FT-IR). Three commercial newspapers and black and cyan cold-set inks were chosen for the study. Attenuated total reflection Fourier transform infrared spectroscopy enabled the proportion of oil and cyan pigment on the printed surface and throughout the sheet thickness to be measured. Oil percentage was evaluated as the area increment of the region from 2800 cm(-1) to 3000 cm(-1) The relative amount of cyan pigment was determined as the area of the absorption band at 730 cm(-1) The ink oil was found mainly below half the paper thickness, whereas the pigment was detected at the layers closer to the printed surface, at a depth penetration of less than 15 µm (20% of thickness). Distribution of these two components in paper thickness depended on the type of cold-set ink, the amount of ink transferred, and the newspaper properties. © The Author(s) 2016.

  18. Polarized Light Corridor Demonstrations.

    Science.gov (United States)

    Davies, G. R.

    1990-01-01

    Eleven demonstrations of light polarization are presented. Each includes a brief description of the apparatus and the effect demonstrated. Illustrated are strain patterns, reflection, scattering, the Faraday Effect, interference, double refraction, the polarizing microscope, and optical activity. (CW)

  19. An efficient zero-order description of the fine structure in the infrared reflection band of cubic ionic crystals and the phonon-polariton dispersion using Lorentz gauge

    Science.gov (United States)

    Meskers, Stefan C. J.

    2018-03-01

    The reflection of infrared light by ionic crystals with cubic symmetry such as lithium fluoride, LiF, is analyzed in terms of phonon-polaritons. In contrast to the conventional view on phonon-polaritons that uses the Coulomb gauge and assumes a purely local dielectric response of the material, we here develop an alternative description making use of the Lorentz gauge. This involves retarded interactions between charges, implying a non-local response of the material to electromagnetic radiation. The resulting new phonon-polariton dispersion relation features polaritons with negative group velocity in the frequency range in between the transverse (ωT) and longitudinal frequency (ωL). By contrast, the conventional description predicts, in zero order, the absence of any propagating polaritons in the frequency interval between ωT and ωL. The new dispersion relation provides an efficient, zero-order description of the fine structure within the reststrahlen band of LiF. The local minimum near the middle of the reflectance band is due to excitation of a phonon-polariton whose energy and momentum matches that of the incoming photon. The Lorentz gauge description can also describe off-normal reflection and accounts for the experimentally observed widening of the reflection band with increasing angle of incidence.

  20. Diffuse reflectance infrared fourier transform spectroscopic (DRIFTS) investigation of E.coli, Staphylococcus aureus and Candida albicans

    Digital Repository Service at National Institute of Oceanography (India)

    DeSouza, L; PrabhaDevi; Kamat, T.; Naik, C

    INDIAN J. MAR. SCI., VOL. 38, NO. 1, MARCH 2009 48 Fig. 3—Representative original mid-infrared absorption spectra (I), Kubelka Munk (II) and second derivative (III) for A) Candida albicans B) E. coli and C) Staphylococcus aureus D'SOUZA et... hand in the case of the strain Candida albicans, absorption bands were evident at 2931 cm-1 and 2894 cm-1 which is due to C-H asymmetric stretching of CH2 methylene and due to C-H stretching of C-H methine respectively. The region between 1800...

  1. Accurate Molecular Orientation Analysis Using Infrared p-Polarized Multiple-Angle Incidence Resolution Spectrometry (pMAIRS) Considering the Refractive Index of the Thin Film Sample.

    Science.gov (United States)

    Shioya, Nobutaka; Shimoaka, Takafumi; Murdey, Richard; Hasegawa, Takeshi

    2017-06-01

    Infrared (IR) p-polarized multiple-angle incidence resolution spectrometry (pMAIRS) is a powerful tool for analyzing the molecular orientation in an organic thin film. In particular, pMAIRS works powerfully for a thin film with a highly rough surface irrespective of degree of the crystallinity. Recently, the optimal experimental condition has comprehensively been revealed, with which the accuracy of the analytical results has largely been improved. Regardless, some unresolved matters still remain. A structurally isotropic sample, for example, yields different peak intensities in the in-plane and out-of-plane spectra. In the present study, this effect is shown to be due to the refractive index of the sample film and a correction factor has been developed using rigorous theoretical methods. As a result, with the use of the correction factor, organic materials having atypical refractive indices such as perfluoroalkyl compounds ( n = 1.35) and fullerene ( n = 1.83) can be analyzed with high accuracy comparable to a compound having a normal refractive index of approximately 1.55. With this improved technique, we are also ready for discriminating an isotropic structure from an oriented sample having the magic angle of 54.7°.

  2. Effects of high-intensity pulse irradiation with linear polarized near-infrared rays and stretching on muscle tone in patients with cerebrovascular disease: a randomized controlled trial.

    Science.gov (United States)

    Takeuchi, Nobuyuki; Takezako, Nobuhiro; Shimonishi, Yuko; Usuda, Shigeru

    2017-08-01

    [Purpose] The purpose of this study was to clarify the influence of high-intensity pulse irradiation with linear polarized near-infrared rays (HI-LPNR) and stretching on hypertonia in cerebrovascular disease patients. [Subjects and Methods] The subjects were 40 cerebrovascular disease patients with hypertonia of the ankle joint plantar flexor muscle. The subjects were randomly allocated to groups undergoing treatment with HI-LPNR irradiation (HI-LPNR group), stretching (stretching group), HI-LPNR irradiation followed by stretching (combination group), and control group (10 subjects each). In all groups, the passive range of motion of ankle dorsiflexion and passive resistive joint torque of ankle dorsiflexion were measured before and after the specified intervention. [Results] The changes in passive range of motion, significant increase in the stretching and combination groups compared with that in the control group. The changes in passive resistive joint torque, significant decrease in HI-LPNR, stretching, and combination groups compared with that in the control group. [Conclusion] HI-LPNR irradiation and stretching has effect of decrease muscle tone. However, combination of HI-LPNR irradiation and stretching has no multiplier effect.

  3. Portable ultrahigh-vacuum sample storage system for polarization-dependent total-reflection fluorescence x-ray absorption fine structure spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Yoshihide, E-mail: e0827@mosk.tytlabs.co.jp; Nishimura, Yusaku F.; Suzuki, Ryo; Beniya, Atsushi; Isomura, Noritake [Toyota Central R& D Labs., Inc., Yokomichi 41-1, Nagakute, Aichi 480-1192 (Japan); Uehara, Hiromitsu; Asakura, Kiyotaka; Takakusagi, Satoru [Catalysis Research Center, Hokkaido University, Kita 21-10, Sapporo, Hokkaido 001-0021 (Japan); Nimura, Tomoyuki [AVC Co., Ltd., Inada 1450-6, Hitachinaka, Ibaraki 312-0061 (Japan)

    2016-03-15

    A portable ultrahigh-vacuum sample storage system was designed and built to investigate the detailed geometric structures of mass-selected metal clusters on oxide substrates by polarization-dependent total-reflection fluorescence x-ray absorption fine structure spectroscopy (PTRF-XAFS). This ultrahigh-vacuum (UHV) sample storage system provides the handover of samples between two different sample manipulating systems. The sample storage system is adaptable for public transportation, facilitating experiments using air-sensitive samples in synchrotron radiation or other quantum beam facilities. The samples were transferred by the developed portable UHV transfer system via a public transportation at a distance over 400 km. The performance of the transfer system was demonstrated by a successful PTRF-XAFS study of Pt{sub 4} clusters deposited on a TiO{sub 2}(110) surface.

  4. Measurement of the infrared optical constants for spectral modeling: n and k values for (NH4)2SO4 via single-angle reflectance and ellipsometric methods

    Science.gov (United States)

    Blake, Thomas A.; Brauer, Carolyn S.; Kelly-Gorham, Molly Rose; Burton, Sarah D.; Bliss, Mary; Myers, Tanya L.; Johnson, Timothy J.; Tiwald, Thomas E.

    2017-05-01

    The complex index of refraction, ñ = n + ik, has two components, n(ν) and k(ν), both a function of frequency, ν. The constant n is the real component, and k is the complex component, proportional to the absorption. In combination with other parameters, n and k can be used to model infrared spectra. However, obtaining reliable n/k values for solid materials is often difficult. In the past, the best results for n and k have been obtained from bulk, polished homogeneous materials free of defects; i.e. materials where the Fresnel equations are valid and there is no appreciable light scattering. Since it is often not possible to obtain such pure macroscopic samples, the alternative is to press the powder form of the material into a uniform disk. Recently, we have pressed such pellets from ammonium sulfate powder, and have measured the pellets' n and k values via two independent methods: 1) ellipsometry, which measures the changes in amplitude and phase of light reflected from the material of interest as a function of wavelength and angle of incidence, and 2) single-angle reflectance using a specular reflectance device within a Fourier transform infrared spectrometer. This technique measures the change in amplitude of light reflected from the material of interest as a function of wavelength over a wide spectral domain. The optical constants are determined from the single-angle measurements using the Kramers-Kronig relationship, whereas an oscillator model is used to analyze the ellipsometric measurements. The n(ν) and k(ν) values determined by the two methods were compared to previous values determined from single crystal samples from which transmittance and reflectance measurements were made and converted to n(ν) and k(ν) using a simple dispersion model. [Toon et al., Journal of Geophysical Research, 81, 5733-5748, (1976)]. Comparison with the literature values shows good agreement, indicating that these are promising techniques to measure the optical constants

  5. Postlaunch assessment of the response versus scan angle for the thermal emissive bands of visible infrared imaging radiometer suite on-board the Suomi national polar-orbiting partnership satellite

    Science.gov (United States)

    Wu, Aisheng; Xiong, Xiaoxiong; Chiang, Kwofu

    2017-10-01

    The visible infrared imaging radiometer suite (VIIRS) is a key sensor carried on the Suomi national polar-orbiting partnership (S-NPP) satellite, which was launched in October 2011. It has several on-board calibration components, including a solar diffuser and a solar diffuser stability monitor for the reflective solar bands, a V-groove blackbody for the thermal emissive bands (TEB), and a space view port for background subtraction. These on-board calibrators are located at fixed scan angles. The VIIRS response versus scan angle (RVS) was characterized prelaunch in lab ambient conditions and is currently used to characterize the on-orbit response for all scan angles relative to the calibrator scan angle. Since the RVS is vitally important to the quality of calibrated radiance products, several independent studies were performed to analyze the prelaunch RVS measurement data. A spacecraft level pitch maneuver was scheduled during the first 3 months of intensive Cal/Val. The S-NPP pitch maneuver provided a rare opportunity for VIIRS to make observations of deep space over the entire range of Earth view scan angles, which can be used to characterize the TEB RVS. This study provides our analysis of the pitch maneuver data and assessment of the derived TEB RVS by comparison with prelaunch results. In addition, the stability of the RVS after the first 5 years of operation is examined using observed brightness temperatures (BT) over a clear ocean at various angles of incidence (AOI). To reduce the impact of variations in the BT measurements, the daily overpasses collected over the ocean are screened for cloud contamination, normalized to the results obtained at the blackbody AOI, and averaged each year.

  6. New modeling of reflection interference contrast microscopy including polarization and numerical aperture effects: application to nanometric distance measurements and object profile reconstruction.

    Science.gov (United States)

    Theodoly, O; Huang, Z-H; Valignat, M-P

    2010-02-02

    We have developed a new and improved optical model of reflection interference contrast microscopy (RICM) to determine with a precision of a few nanometers the absolute thickness h of thin films on a flat surface in immersed conditions. The model takes into account multiple reflections between a planar surface and a multistratified object, finite aperture illumination (INA), and, for the first time, the polarization of light. RICM intensity I is typically oscillating with h. We introduce a new normalization procedure that uses the intensity extrema of the same oscillation order for both experimental and theoretical intensity values and permits us to avoid significant error in the absolute height determination, especially at high INA. We also show how the problem of solution degeneracy can be solved by taking pictures at two different INA values. The model is applied to filled polystyrene beads and giant unilamellar vesicles of radius 10-40 microm sitting on a glass substrate. The RICM profiles I(h) can be fitted for up to two to three oscillation orders, and extrema positions are correct for up to five to seven oscillation orders. The precision of the absolute distance and of the shape of objects near a substrate is about 5 nm in a range from 0 to 500 nm, even under large numerical aperture conditions. The method is especially valuable for dynamic RICM experiments and with living cells where large illumination apertures are required.

  7. Concomitant Use of Fourier Transform Infrared Attenuated Total Reflectance Spectroscopy and Chemometrics for Quantification of Multiple Adulterants in Roasted and Ground Coffee

    Directory of Open Access Journals (Sweden)

    Nádia Reis

    2016-01-01

    Full Text Available This paper proposed the joint use of Fourier Transform Infrared Attenuated Total Reflectance Spectroscopy (FTIR-ATR and Partial Least Square (PLS regression for the simultaneous quantification of four adulterants (coffee husks, spent coffee grounds, barley, and corn in roasted and ground coffee. Roasted coffee samples were intentionally blended with the adulterants, at adulteration levels ranging from 0.5 to 66% w/w. A robust methodology was implemented in which the identification of outliers was carried out. High correlation coefficients (0.99 for both calibration and validation coupled with low degrees of error (0.69% for calibration; 2.00% for validation confirmed that FTIR-ATR can be a valuable analytical tool for quantification of adulteration in roasted and ground coffee. This method is simple, fast, and reliable for the proposed purpose.

  8. CO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy

    KAUST Repository

    Park, Youngjune

    2012-01-12

    Novel nanoparticle organic hybrid materials (NOHMs), which are comprised of organic oligomers or polymers tethered to an inorganic nanosized cores of various sizes, have been synthesized, and their solvating property for CO 2 was investigated using attenuated total reflectance (ATR) Fourier transform infrared (FT-IR) spectroscopy. Simultaneous measurements of CO 2 capture capacity and swelling behaviors of polyetheramine (Jeffamine M-2070) and its corresponding NOHMs (NOHM-I-PE2070) were reported at temperatures of (298, 308, 323 and 353) K and CO 2 pressure conditions ranging from (0 to 5.5) MPa. The polymeric canopy, or polymer bound to the nanoparticle surface, showed significantly less swelling behavior with enhanced or comparable CO 2 capture capacity compared to pure unbound polyetheramine. © 2011 American Chemical Society.

  9. Classification of pumpkin seed oils according to their species and genetic variety by attenuated total reflection Fourier-transform infrared spectroscopy.

    Science.gov (United States)

    Saucedo-Hernández, Yanelis; Lerma-García, María Jesús; Herrero-Martínez, José Manuel; Ramis-Ramos, Guillermo; Jorge-Rodríguez, Elisa; Simí-Alfonso, Ernesto F

    2011-04-27

    Attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR), followed by multivariate treatment of the spectral data, was used to classify seed oils of the genus Cucurbita (pumpkins) according to their species as C. maxima, C. pepo, and C. moschata. Also, C. moschata seed oils were classified according to their genetic variety as RG, Inivit C-88, and Inivit C-2000. Up to 23 wavelength regions were selected on the spectra, each region corresponding to a peak or shoulder. The normalized absorbance peak areas within these regions were used as predictors. Using linear discriminant analysis (LDA), an excellent resolution among all categories concerning both Cucurbita species and C. moschata varieties was achieved. The proposed method was straightforward and quick and can be easily implemented. Quality control of pumpkin seed oils is important because Cucurbita species and genetic variety are both related to the pharmaceutical properties of the oils.

  10. Complex refractive index measurements for BaF 2 and CaF 2 via single-angle infrared reflectance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Kelly-Gorham, Molly Rose K.; DeVetter, Brent M.; Brauer, Carolyn S.; Cannon, Bret D.; Burton, Sarah D.; Bliss, Mary; Johnson, Timothy J.; Myers, Tanya L.

    2017-10-01

    We have re-investigated the optical constants n and k for the homologous series of inorganic salts barium fluoride (BaF2) and calcium fluoride (CaF2) using a single-angle near-normal incidence reflectance device in combination with a calibrated Fourier transform infrared (FTIR) spectrometer. Our results are in good qualitative agreement with most previous works. However, certain features of the previously published data near the reststrahlen band exhibit distinct differences in spectral characteristics. Notably, our measurements of BaF2 do not include a spectral feature in the ~250 cm-1 reststrahlen band that was previously published. Additionally, CaF2 exhibits a distinct wavelength shift relative to the model derived from previously published data. We confirmed our results with recently published works that use significantly more modern instrumentation and data reduction techniques

  11. Reformulation of Traditional Chamomile Oil: Quality Controls and Fingerprint Presentation Based on Cluster Analysis of Attenuated Total Reflectance-Infrared Spectral Data.

    Science.gov (United States)

    Zargaran, Arman; Sakhteman, Amirhossein; Faridi, Pouya; Daneshamouz, Saeid; Akbarizadeh, Amin Reza; Borhani-Haghighi, Afshin; Mohagheghzadeh, Abdolali

    2017-10-01

    Herbal oils have been widely used in Iran as medicinal compounds dating back to thousands of years in Iran. Chamomile oil is widely used as an example of traditional oil. We remade chamomile oils and tried to modify it with current knowledge and facilities. Six types of oil (traditional and modified) were prepared. Microbial limit tests and physicochemical tests were performed on them. Also, principal component analysis, hierarchical cluster analysis, and partial least squares discriminant analysis were done on the spectral data of attenuated total reflectance-infrared in order to obtain insight based on classification pattern of the samples. The results show that we can use modified versions of the chamomile oils (modified Clevenger-type apparatus method and microwave method) with the same content of traditional ones and with less microbial contaminations and better physicochemical properties.

  12. Gas sensing properties and in situ diffuse reflectance infrared Fourier transform spectroscopy study of trichloroethylene adsorption and reactions on SnO2 films

    Science.gov (United States)

    Zhang, Zhenxin; Huang, Kaijin; Yuan, Fangli; Xie, Changsheng

    2014-05-01

    The detection of trichloroethylene has attracted much attention because it has an important effect on human health. The sensitivity of the SnO2 flat-type coplanar gas sensor arrays to 100 ppm trichloroethylene in air was investigated. The adsorption and surface reactions of trichloroethylene were investigated at 100-200 °C by in-situ diffuse reflection Fourier transform infrared spectroscopy (DIRFTS) on SnO2 films. Molecularly adsorbed trichloroethylene, dichloroacetyl chloride (DCAC), phosgene, HCl, CO, H2O, CHCl3, Cl2 and CO2 surface species are formed during trichloroethylene adsorption at 100-200 °C. A possible mechanism of the reaction process is discussed.

  13. Low Group Delay Dispersion Optical Coating for Broad Bandwidth High Reflection at 45° Incidence, P Polarization of Femtosecond Pulses with 900 nm Center Wavelength

    Directory of Open Access Journals (Sweden)

    John C. Bellum

    2016-03-01

    Full Text Available We describe an optical coating design suitable for broad bandwidth high reflection (BBHR at 45° angle of incidence (AOI, P polarization (Ppol of femtosecond (fs laser pulses whose wavelengths range from 800 to 1000 nm. Our design process is guided by quarter-wave HR coating properties. The design must afford low group delay dispersion (GDD for reflected light over the broad, 200 nm bandwidth in order to minimize temporal broadening of the fs pulses due to dispersive alteration of relative phases between their frequency components. The design should also be favorable to high laser-induced damage threshold (LIDT. We base the coating on TiO2/SiO2 layer pairs produced by means of e-beam evaporation with ion-assisted deposition, and use OptiLayer Thin Film Software to explore designs starting with TiO2/SiO2 layers having thicknesses in a reverse chirped arrangement. This approach led to a design with R > 99% from 800 to 1000 nm and GDD < 20 fs2 from 843 to 949 nm (45° AOI, Ppol. The design’s GDD behaves in a smooth way, suitable for GDD compensation techniques, and its electric field intensities show promise for high LIDTs. Reflectivity and GDD measurements for the initial test coating indicate good performance of the BBHR design. Subsequent coating runs with improved process calibration produced two coatings whose HR bands satisfactorily meet the design goals. For the sake of completeness, we summarize our previously reported transmission spectra and LIDT test results with 800 ps, 8 ps and 675 fs pulses for these two coatings, and present a table of the LIDT results we have for all of our TiO2/SiO2 BBHR coatings, showing the trends with test laser pulse duration from the ns to sub-ps regimes.

  14. Infrared reflectivity investigation of the phase transition sequence in Pr{sub 0.5}Ca{sub 0.5}MnO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, J.L., E-mail: jlr@fisica.uminho.pt [Centro and Departamento de Física da Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Vieira, L.G. [Centro and Departamento de Física da Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Gomes, I.T. [Centro and Departamento de Física da Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); IFIMUP and IN - Institute of Nanoscience and Nanotechnology, Departamento de Física e Astronomia da Faculdade de Ciências da Universidade do Porto, R. do Campo Alegre, 687, 4769-007 Porto (Portugal); Araújo, J.P. [IFIMUP and IN - Institute of Nanoscience and Nanotechnology, Departamento de Física e Astronomia da Faculdade de Ciências da Universidade do Porto, R. do Campo Alegre, 687, 4769-007 Porto (Portugal); Tavares, P. [Centro de Química – Vila Real, Universidade de Trás-os-Montes e Alto Douro, 5001-801 Vila Real (Portugal); Almeida, B.G. [Centro and Departamento de Física da Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

    2016-06-15

    This work reports an infrared reflectivity study of the phase transition sequence observed in Pr{sub 0.5}Ca{sub 0.5}MnO{sub 3.} The need to measure over an extended spectral range in order to properly take into account the effects of the high frequency polaronic absorption is circumvented by adopting a simple approximate method, based on the asymmetry present in the Kramers Kronig inversion of the phonon spectrum. The temperature dependence of the phonon optical conductivity is then investigated by monitoring the behavior of three relevant spectral moments of the optical conductivity. This combined methodology allows us to disclose subtle effects of the orbital, charge and magnetic orders on the lattice dynamics of the compound. The characteristic transition temperatures inferred from the spectroscopic measurements are compared and correlated with those obtained from the temperature dependence of the induced magnetization and electrical resistivity. - Highlights: • Study of the effects of orbital, charge and spin orders on the lattice dynamics. • Phonon optical conductivity spectral moments are used to monitor phase transitions. • Precursor effects of the AFM order are detected by infrared spectroscopy.

  15. Comparison between red-green-blue imaging and visible-near infrared reflectance as potential process analytical tools for monitoring syneresis.

    Science.gov (United States)

    Mateo, M J; O'Callaghan, D J; O'Donnell, C P

    2010-05-01

    The current work focuses on the comparison of 2 on-line optical sensing systems; namely red-green-blue imaging and visible-near infrared reflectance, for monitoring syneresis during cheese manufacture. The experimental design consisted of 3 temperature treatments carried out in an 11-L cheese vat in triplicate. Both systems were shown to predict syneresis without significant differences in prediction accuracy. However, a single-wavelength near infrared model was the most parsimonious (standard error of prediction=4.35g/100g) for predicting syneresis. This technique was also the simplest in terms of parameters in the model (standard error of prediction=4.15g/100g with 2 parameters), when time after gel cutting and process parameters (temperature and cutting time) were included in the models. The study showed that either system could be employed to control syneresis in cheese manufacture and improve the control of moisture content in cheese. Copyright 2010 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

  16. Direct and simultaneous quantification of tannin mean degree of polymerization and percentage of galloylation in grape seeds using diffuse reflectance fourier transform-infrared spectroscopy.

    Science.gov (United States)

    Pappas, Christos; Kyraleou, Maria; Voskidi, Eleni; Kotseridis, Yorgos; Taranilis, Petros A; Kallithraka, Stamatina

    2015-02-01

    The direct and simultaneous quantitative determination of the mean degree of polymerization (mDP) and the degree of galloylation (%G) in grape seeds were quantified using diffuse reflectance infrared Fourier transform spectroscopy and partial least squares (PLS). The results were compared with those obtained using the conventional analysis employing phloroglucinolysis as pretreatment followed by high performance liquid chromatography-UV and mass spectrometry detection. Infrared spectra were recorded in solid state samples after freeze drying. The 2nd derivative of the 1832 to 1416 and 918 to 739 cm(-1) spectral regions for the quantification of mDP, the 2nd derivative of the 1813 to 607 cm(-1) spectral region for the degree of %G determination and PLS regression were used. The determination coefficients (R(2) ) of mDP and %G were 0.99 and 0.98, respectively. The corresponding values of the root-mean-square error of calibration were found 0.506 and 0.692, the root-mean-square error of cross validation 0.811 and 0.921, and the root-mean-square error of prediction 0.612 and 0.801. The proposed method in comparison with the conventional method is simpler, less time consuming, more economical, and requires reduced quantities of chemical reagents and fewer sample pretreatment steps. It could be a starting point for the design of more specific models according to the requirements of the wineries. © 2015 Institute of Food Technologists®

  17. Rapid, nondestructive estimation of surface polymer layer thickness using attenuated total reflection fourier transform infrared (ATR FT-IR) spectroscopy and synthetic spectra derived from optical principles.

    Science.gov (United States)

    Weinstock, B André; Guiney, Linda M; Loose, Christopher

    2012-11-01

    We have developed a rapid, nondestructive analytical method that estimates the thickness of a surface polymer layer with high precision but unknown accuracy using a single attenuated total reflection Fourier transform infrared (ATR FT-IR) measurement. Because the method is rapid, nondestructive, and requires no sample preparation, it is ideal as a process analytical technique. Prior to implementation, the ATR FT-IR spectrum of the substrate layer pure component and the ATR FT-IR and real refractive index spectra of the surface layer pure component must be known. From these three input spectra a synthetic mid-infrared spectral matrix of surface layers 0 nm to 10,000 nm thick on substrate is created de novo. A minimum statistical distance match between a process sample's ATR FT-IR spectrum and the synthetic spectral matrix provides the thickness of that sample. We show that this method can be used to successfully estimate the thickness of polysulfobetaine surface modification, a hydrated polymeric surface layer covalently bonded onto a polyetherurethane substrate. A database of 1850 sample spectra was examined. Spectrochemical matrix-effect unknowns, such as the nonuniform and molecularly novel polysulfobetaine-polyetherurethane interface, were found to be minimal. A partial least squares regression analysis of the database spectra versus their thicknesses as calculated by the method described yielded an estimate of precision of ±52 nm.

  18. Determination of some quality characteristics of peanut (Arachis hypogaea L. using Near-Infrared Reflectance Spectroscopy (NIRS

    Directory of Open Access Journals (Sweden)

    Murat Reis AKKAYA

    2017-06-01

    Full Text Available The aim of this study was to determine protein, oil and moisture contents of peanut using Near Infrared Spectroscopy (NIRS. Foss NIRSystem XDS rapid content analyzer was used to determine XDS spectra of the samples which were taken from breeding lines and commercial cultivars. Reference values used to obtain calibration equations in NIRS were obtained by analyzing protein, oil and moisture contents of the samples. Protein, oil and moisture contents of the samples were analyzed by kjeldahl, soxhlet extraction and oven methods, respectively. Protein contents of peanuts were found to range between 19.90 and 30.1% whereas oil contents were found as 44.03-53.70%. Moisture contents of peanuts varied between 5.03 and 6.16%. Coefficient of determination (RSQ=R2 values between the results of classical analytical methods and NIRS were 0.925, 0.857 and 0.821 for protein, oil and moisture contents, respectively. The results of this study showed that NIRS can be used quick and accurate method to determine important quality characteristics of peanut.

  19. Detection and quantification of anionic detergent (lissapol) in milk using attenuated total reflectance-Fourier Transform Infrared spectroscopy.

    Science.gov (United States)

    Jaiswal, Pranita; Jha, Shyam Narayan; Kaur, Jaspreet; Borah, Anjan

    2017-04-15

    Adulteration of milk to gain economic benefit is rampant. Addition of detergent in milk can cause food poisoning and other complications. Fourier Transform Infrared spectroscopy was evaluated as rapid method for detection and quantification of anionic detergent (lissapol) in milk. Spectra of pure and artificially adulterated milk (0.2-2.0% detergent) samples revealed clear differences in wavenumber range of 4000-500cm -1 . The apparent variations observed in region of 1600-995 and 3040-2851cm -1 corresponds to absorption frequencies of common constituents of detergent (linear alkyl benzene sulphonate). Principal component analysis showed discrete clustering of samples based on level of detergent (p⩽0.05) in milk. The classification efficiency for test samples were recorded to be >93% using Soft Independent Modelling of Class Analogy approach. Maximum coefficient of determination for prediction of detergent was 0.94 for calibration and 0.93 for validation, using partial least square regression in wavenumber combination of 1086-1056, 1343-1333, 1507-1456, 3040-2851cm -1 . Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR) in the discrimination of normal and oral cancer blood plasma

    Science.gov (United States)

    Pachaiappan, Rekha; Prakasarao, Aruna; Singaravelu, Ganesan

    2017-02-01

    Oral cancer is the most frequent type of cancer that occurs with 75000 to 80000 new cases reported every year in India. The carcinogens from tobacco and related products are the main cause for the oral cancer. ATR-FTIR method is label free, fast and cost-effective diagnostic method would allow for rapid diagnostic results in earlier stages by the minimal chemical changes occur in the biological metabolites available in the blood plasma. The present study reports the use of ATR-FTIR data with advanced statistical model (LDA-ANN) in the diagnosis of oral cancer from normal with better accuracy. The infrared spectra were acquired on ATR-FTIR Jasco spectrophotometer at 4 cm-1 resolution, 30 scans, in the 1800-900 cm-1 spectral range. Each sample had 5 spectra recorded from each blood plasma sample. The spectral data were routed through the multilayer perception of artificial neural network to evaluate for the statistical efficacy. Among the spectral data it was found that amide II (1486 cm-1) and lipid (1526 cm-1) affords about 90 % in the discrimination between groups using LDA. These preliminary results indicate that ATR-FTIR is useful to differentiate normal subject from oral cancer patients using blood plasma.

  1. Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy: An analytical technique to understand therapeutic responses at the molecular level.

    Science.gov (United States)

    Kalmodia, Sushma; Parameswaran, Sowmya; Yang, Wenrong; Barrow, Colin J; Krishnakumar, Subramanian

    2015-11-16

    Rapid monitoring of the response to treatment in cancer patients is essential to predict the outcome of the therapeutic regimen early in the course of the treatment. The conventional methods are laborious, time-consuming, subjective and lack the ability to study different biomolecules and their interactions, simultaneously. Since; mechanisms of cancer and its response to therapy is dependent on molecular interactions and not on single biomolecules, an assay capable of studying molecular interactions as a whole, is preferred. Fourier Transform Infrared (FTIR) spectroscopy has become a popular technique in the field of cancer therapy with an ability to elucidate molecular interactions. The aim of this study, was to explore the utility of the FTIR technique along with multivariate analysis to understand whether the method has the resolution to identify the differences in the mechanism of therapeutic response. Towards achieving the aim, we utilized the mouse xenograft model of retinoblastoma and nanoparticle mediated targeted therapy. The results indicate that the mechanism underlying the response differed between the treated and untreated group which can be elucidated by unique spectral signatures generated by each group. The study establishes the efficiency of non-invasive, label-free and rapid FTIR method in assessing the interactions of nanoparticles with cellular macromolecules towards monitoring the response to cancer therapeutics.

  2. Optical polarization: background and camouflage

    Science.gov (United States)

    Škerlind, Christina; Hallberg, Tomas; Eriksson, Johan; Kariis, Hans; Bergström, David

    2017-10-01

    Polarimetric imaging sensors in the electro-optical region, already military and commercially available in both the visual and infrared, show enhanced capabilities for advanced target detection and recognition. The capabilities arise due to the ability to discriminate between man-made and natural background surfaces using the polarization information of light. In the development of materials for signature management in the visible and infrared wavelength regions, different criteria need to be met to fulfil the requirements for a good camouflage against modern sensors. In conventional camouflage design, the aimed design of the surface properties of an object is to spectrally match or adapt it to a background and thereby minimizing the contrast given by a specific threat sensor. Examples will be shown from measurements of some relevant materials and how they in different ways affect the polarimetric signature. Dimensioning properties relevant in an optical camouflage from a polarimetric perspective, such as degree of polarization, the viewing or incident angle, and amount of diffuse reflection, mainly in the infrared region, will be discussed.

  3. Early On-Orbit Performance of the Visible Infrared Imaging Radiometer Suite Onboard the Suomi National Polar-Orbiting Partnership (S-NPP) Satellite

    Science.gov (United States)

    Cao, Changyong; DeLuccia, Frank J.; Xiong, Xiaoxiong; Wolfe, Robert; Weng, Fuzhong

    2014-01-01

    The Visible Infrared Imaging Radiometer Suite (VIIRS) is one of the key environmental remote-sensing instruments onboard the Suomi National Polar-Orbiting Partnership spacecraft, which was successfully launched on October 28, 2011 from the Vandenberg Air Force Base, California. Following a series of spacecraft and sensor activation operations, the VIIRS nadir door was opened on November 21, 2011. The first VIIRS image acquired signifies a new generation of operational moderate resolution-imaging capabilities following the legacy of the advanced very high-resolution radiometer series on NOAA satellites and Terra and Aqua Moderate-Resolution Imaging Spectroradiometer for NASA's Earth Observing system. VIIRS provides significant enhancements to the operational environmental monitoring and numerical weather forecasting, with 22 imaging and radiometric bands covering wavelengths from 0.41 to 12.5 microns, providing the sensor data records for 23 environmental data records including aerosol, cloud properties, fire, albedo, snow and ice, vegetation, sea surface temperature, ocean color, and nigh-time visible-light-related applications. Preliminary results from the on-orbit verification in the postlaunch check-out and intensive calibration and validation have shown that VIIRS is performing well and producing high-quality images. This paper provides an overview of the onorbit performance of VIIRS, the calibration/validation (cal/val) activities and methodologies used. It presents an assessment of the sensor initial on-orbit calibration and performance based on the efforts from the VIIRS-SDR team. Known anomalies, issues, and future calibration efforts, including the long-term monitoring, and intercalibration are also discussed.

  4. Use of total internal reflection Raman (TIR) and attenuated total reflection infrared (ATR-IR) spectroscopy to analyze component separation in thin offset ink films after setting on coated paper surfaces.

    Science.gov (United States)

    Kivioja, Antti; Hartus, Timo; Vuorinen, Tapani; Gane, Patrick; Jääskeläinen, Anna-Stiina

    2013-06-01

    The interactive behavior of ink constituents with porous substrates during and after the offset print process has an important effect on the quality of printed products. To help elucidate the distribution of ink components between the retained ink layer and the substrate, a variety of spectroscopic and microscopic analysis techniques have been developed. This paper describes for the first time the use of total internal reflection (TIR) Raman spectroscopy to analyze the penetration behavior of separated offset ink components (linseed oil, solid color pigment) in coated papers providing chemically intrinsic information rapidly, nondestructively, and with minimal sample preparation. In addition, the already widely applied technique of attenuated total reflection infrared spectroscopy (ATR-IR) was evaluated in parallel and compared. The results of the ATR-IR Raman clearly revealed an improvement in uppermost depth resolution compared with values previously published from other nondestructive techniques, and the method is shown to be capable of providing new knowledge of the setting of thin (0.25-2 μm) offset ink films, allowing the spreading and the penetration behavior on physically different paper coating surfaces to be studied.

  5. Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) for Rapid Determination of Microbial Cell Lipid Content: Correlation with Gas Chromatography-Mass Spectrometry (GC-MS).

    Science.gov (United States)

    Millan-Oropeza, Aaron; Rebois, Rolando; David, Michelle; Moussa, Fathi; Dazzi, Alexandre; Bleton, Jean; Virolle, Marie-Joelle; Deniset-Besseau, Ariane

    2017-10-01

    There is a growing interest worldwide for the production of renewable oil without mobilizing agriculture lands; fast and reliable methods are needed to identify highly oleaginous microorganisms of potential industrial interest. The aim of this study was to demonstrate the relevance of attenuated total reflection (ATR) spectroscopy to achieve this goal. To do so, the total lipid content of lyophilized samples of five Streptomyces strains with varying lipid content was assessed with two classical quantitative but time-consuming methods, gas chromatography-mass spectrometry (GC-MS) and ATR Fourier transform infrared (ATR FT-IR) spectroscopy in transmission mode with KBr pellets and the fast ATR method, often questioned for its lack of reliability. A linear correlation between these three methods was demonstrated allowing the establishment of equations to convert ATR values expressed as CO/amide I ratio, into micrograms of lipid per milligram of biomass. The ATR method proved to be as reliable and quantitative as the classical GC-MS and FT-IR in transmission mode methods but faster and more reproducible than the latter since it involves far less manipulation for sample preparation than the two others. Attenuated total reflection could be regarded as an efficient fast screening method to identify natural or genetically modified oleaginous microorganisms by the scientific community working in the field of bio-lipids.

  6. Polarimetric infrared imaging simulation of a synthetic sea surface with Mie scattering.

    Science.gov (United States)

    He, Si; Wang, Xia; Xia, Runqiu; Jin, Weiqi; Liang, Jian'an

    2018-03-01

    A novel method to simulate the polarimetric infrared imaging of a synthetic sea surface with atmospheric Mie scattering effects is presented. The infrared emission, multiple reflections, and infrared polarization of the sea surface and the Mie scattering of aerosols are all included for the first time. At first, a new approach to retrieving the radiative characteristics of a wind-roughened sea surface is introduced. A two-scale method of sea surface realization and the inverse ray tracing of light transfer calculation are combined and executed simultaneously, decreasing the consumption of time and memory dramatically. Then the scattering process that the infrared light emits from the sea surface and propagates in the aerosol particles is simulated with a polarized light Monte Carlo model. Transformations of the polarization state of the light are calculated with the Mie theory. Finally, the polarimetric infrared images of the sea surface of different environmental conditions and detection parameters are generated based on the scattered light detected by the infrared imaging polarimeter. The results of simulation examples show that our polarimetric infrared imaging simulation can be applied to predict the infrared polarization characteristics of the sea surface, model the oceanic scene, and guide the detection in the oceanic environment.

  7. Single-particle characterization of summertime Antarctic aerosols collected at King George Island using quantitative energy-dispersive electron probe X-ray microanalysis and attenuated total reflection Fourier transform-infrared imaging techniques.

    Science.gov (United States)

    Maskey, Shila; Geng, Hong; Song, Young-Chul; Hwang, Heejin; Yoon, Young-Jun; Ahn, Kang-Ho; Ro, Chul-Un

    2011-08-01

    Single-particle characterization of Antarctic aerosols was performed to investigate the impact of marine biogenic sulfur species on the chemical compositions of sea-salt aerosols in the polar atmosphere. Quantitative energy-dispersive electron probe X-ray microanalysis was used to characterize 2900 individual particles in 10 sets of aerosol samples collected between March 12 and 16, 2009 at King Sejong Station, a Korean scientific research station located at King George Island in the Antarctic. Two size modes of particles, i.e., PM(2.5-10) and PM(1.0-2.5), were analyzed, and four types of particles were identified, with sulfur-containing sea-salt particles being the most abundant, followed by genuine sea-salt particles without sulfur species, iron-containing particles, and other species including CaCO(3)/CaMg(CO(3))(2), organic carbon, and aluminosilicates. When a sulfur-containing sea-salt particle showed an atomic concentration ratio of sulfur to sodium of >0.083 (seawater ratio), it is regarded as containing nonsea-salt sulfate (nss-SO(4)(2-)) and/or methanesulfonate (CH(3)SO(3)(-)), which was supported by attenuated total reflection Fourier transform-infrared imaging measurements. These internal mixture particles of sea-salt/CH(3)SO(3)(-)/SO(4)(2-) were very frequently encountered. As nitrate-containing particles were not encountered, and the air-masses for all of the samples originated from the Pacific Ocean (based on 5-day backward trajectories), the oxidation of dimethylsulfide (DMS) emitted from phytoplanktons in the ocean is most likely to be responsible for the formation of the mixed sea-salt/CH(3)SO(3)(-)/SO(4)(2-) particles.

  8. Analysis of ewe’s milk by FT Near Infrared spectroscopy: measurement of samples on Petri dishes in reflectance mode

    Directory of Open Access Journals (Sweden)

    Květoslava Šustová

    2006-01-01

    Full Text Available Our work deals with a possibility of determination of basic composition (dry matter, fat, protein, casein, lactose and urea nitrogen of ewe’s milk and colostrum by FT NIR spectroscopy. Samples of milk were warmed to 40 °C, agitated, cooled to 20 °C, transferred into Petri dishes and analysed by reference methods and by FT NIR in reflectance mode. The measured area was spaced by a metallic mirror. Statistically significant differences between the reference values and the calculated values of NIR were not found (p=0.05. Results of calibration for ewe’s milk determined the highest correlation coefficients: dry matter 0.983, fat 0.989, true protein 0.997, casein 0.977, lactose 0.980 and urea nitrogen 0.973. The study showed that NIRS method, when samples of milk are measured on Petri dishes, is a useful technique for the prediction of dry matter, fat, protein and casein in ewe’s milk.

  9. Spectral dependence of backscattering coefficient of mixed phase clouds over West Africa measured with two-wavelength Raman polarization lidar: Features attributed to ice-crystals corner reflection

    Science.gov (United States)

    Veselovskii, I.; Goloub, P.; Podvin, T.; Tanre, D.; Ansmann, A.; Korenskiy, M.; Borovoi, A.; Hu, Q.; Whiteman, D. N.

    2017-11-01

    The existing models predict that corner reflection (CR) of laser radiation by simple ice crystals of perfect shape, such as hexagonal columns or plates, can provide a significant contribution to the ice cloud backscattering. However in real clouds the CR effect may be suppressed due to crystal deformation and surface roughness. In contrast to the extinction coefficient, which is spectrally independent, consideration of diffraction associated with CR results in a spectral dependence of the backscattering coefficient. Thus measuring the spectral dependence of the cloud backscattering coefficient, the contribution of CR can be identified. The paper presents the results of profiling of backscattering coefficient (β) and particle depolarization ratio (δ) of ice and mixed-phase clouds over West Africa by means of a two-wavelength polarization Mie-Raman lidar operated at 355 nm and 532 nm during the SHADOW field campaign. The lidar observations were performed at a slant angle of 43 degree off zenith, thus CR from both randomly oriented crystals and oriented plates could be analyzed. For the most of the observations the cloud backscatter color ratio β355/β532 was close to 1.0, and no spectral features that might indicate the presence of CR of randomly oriented crystals were revealed. Still, in two measurement sessions we observed an increase of backscatter color ratio to a value of nearly 1.3 simultaneously with a decrease of the spectral depolarization ratio δ355/δ532 ratio from 1.0 to 0.8 inside the layers containing precipitating ice crystals. We attribute these changes in optical properties to corner reflections by horizontally oriented ice plates.

  10. Assay of effervescent tablets by near-infrared spectroscopy in transmittance and reflectance mode: acetylsalicylic acid in mono and combination formulations.

    Science.gov (United States)

    Merckle, P; Kovar, K A

    1998-07-01

    Near-infrared spectroscopy (NIRS) was used to determine acetylsalicylic acid (ASA) in three different effervescent tablet formulations. The nominal ASA concentrations were 14.9% in the single substance formulation (ASA Mono), 17.4% in the combination with ascorbic acid (ASA + C) and 8.7% in the combination with paracetamol and ascorbic acid (ASA Combi). In each case the tablet matrix was composed of seven excipients typical of effervescent tablets. All three formulations were measured as intact tablets in diffuse transmittance and reflectance and as powdered tablets in diffuse reflectance. Calibration was carried out by partial least square (PLS) regression of second derivative spectra. High-performance liquid chromatography (HPLC) was used as the reference method. The relative standard errors of calibration (RSEC) achieved for the three NIR methods were between 1.20 and 2.01% for ASA Mono, between 1.91 and 2.21% for ASA + C and between 2.41 and 4.50% for ASA Combi. The results obtained in transmittance mode were comparable with those obtained in reflectance mode, which is normally used in NIRS. In the test sets of ASA Mono and ASA + C relative root mean square (RRMS) values between 2.21 and 3.13% were obtained. The three NIR methods applied are thus suitable for the quantitative determination of ASA in effervescent tablets and have the advantage over HPLC of being rapid and simply carried out with little sample preparation; they are nondestructive and do not require any environmentally harmful reagents.

  11. Influence of composition and roughness on the pigment mapping of paintings using mid-infrared fiberoptics reflectance spectroscopy (mid-IR FORS) and multivariate calibration.

    Science.gov (United States)

    Sessa, Clarimma; Bagán, Héctor; García, Jose Francisco

    2014-10-01

    Mid-infrared fiberoptics reflectance spectroscopy (mid-IR FORS) is a very interesting technique for artwork characterization purposes. However, the fact that the spectra obtained are a mixture of surface (specular) and volume (diffuse) reflection is a significant drawback. The physical and chemical features of the artwork surface may produce distortions in the spectra that hinder comparison with reference databases acquired in transmission mode. Several studies attempted to understand the influence of the different variables and propose procedures to improve the interpretation of the spectra. This article is focused on the application of mid-IR FORS and multivariate calibration to the analysis of easel paintings. The objectives are the evaluation of the influence of the surface roughness on the spectra, the influence of the matrix composition for the classification of unknown spectra, and the capability of obtaining pigment composition mappings. A first evaluation of a fast procedure for spectra management and pigment discrimination is discussed. The results demonstrate the capability of multivariate methods, principal component analysis (PCA), and partial least squares discrimination analysis (PLS-DA), to model the distortions of the reflectance spectra and to delimitate and discriminate areas of uniform composition. The roughness of the painting surface is found to be an important factor affecting the shape and relative intensity of the spectra. A mapping of the major pigments of a painting is possible using mid-IR FORS and PLS-DA when the calibration set is a palette that includes the potential pigments present in the artwork mixed with the appropriate binder and that shows the different paint textures.

  12. Qualitative and simultaneous quantitative analysis of cimetidine polymorphs by ultraviolet-visible and shortwave near-infrared diffuse reflectance spectroscopy and multivariate calibration models.

    Science.gov (United States)

    Feng, Yuyan; Li, Xiangling; Xu, Kailin; Zou, Huayu; Li, Hui; Liang, Bing

    2015-02-01

    The object of the present study was to investigate the feasibility of applying ultraviolet-visible and shortwave near-infrared diffuse reflectance spectroscopy (UV-vis-SWNIR DRS) coupled with chemometrics in qualitative and simultaneous quantitative analysis of drug polymorphs, using cimetidine as a model drug. Three polymorphic forms (A, B and D) and a mixed crystal (M1) of cimetidine, obtained by preparation under different crystallization conditions, were characterized by microscopy, X-ray powder diffraction (XRPD) and infrared spectroscopy (IR). The discriminant models of four forms (A, B, D and M1) were established by discriminant partial least squares (PLS-DA) using different pretreated spectra. The R and RMSEP of samples in the prediction set by discriminant model with original spectra were 0.9959 and 0.1004. Among the quantitative models of binary mixtures (A and D) established by partial least squares (PLS) and least squares-support vector machine (LS-SVM) with different pretreated spectra, the LS-SVM models based on original and MSC spectra had better prediction effect with a R of 1.0000 and a RMSEP of 0.0134 for form A, and a R of 1.0000 and a RMSEP of 0.0024 for form D. For ternary mixtures, the established PLS quantitative models based on normalized spectra had relatively better prediction effect for forms A, B and D with R of 0.9901, 0.9820 and 0.9794 and RMSEP of 0.0471, 0.0529 and 0.0594, respectively. This research indicated that UV-vis-SWNIR DRS can be used as a simple, rapid, nondestructive qualitative and quantitative method for the analysis of drug polymorphs. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Assessing saffron (Crocus sativus L.) adulteration with plant-derived adulterants by diffuse reflectance infrared Fourier transform spectroscopy coupled with chemometrics.

    Science.gov (United States)

    Petrakis, Eleftherios A; Polissiou, Moschos G

    2017-01-01

    Saffron, the dried red stigmas of the plant Crocus sativus L., is well-known as one of the most important and expensive spices worldwide. It is thus highly susceptible to fraudulent practices that employ, among others, plant-derived adulterants. This study presents an application of diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and chemometric techniques for evaluating adulteration of saffron with six characteristic adulterants of plant origin, i.e. C. sativus stamens, calendula, safflower, turmeric, buddleja, and gardenia. The proposed method involved a three-step process for the detection of adulteration as well as for the identification and quantification of adulterants. Partial least squares discriminant analysis (PLS-DA) was applied to perform authentication of saffron based on mid-infrared fingerprints (4000-600cm -1 ), resulting in 99% correct classification of pure saffron and saffron adulterated at 5-20% (w/w) levels. Adulterant identification in positive samples was performed with high sensitivity and specificity by a six-class PLS-DA model, with spectroscopic data from the region 2000-600cm -1 . Subsequently, partial least squares (PLS) regression models were built for the quantification of each adulterant. By using synergy interval PLS (siPLS) for variable selection, models with improved performance were developed, with detection limits ranging from 1.0% to 3.1% (w/w). The results obtained illustrate that this strategy based on DRIFTS has the potential to complement existing methodologies for the rapid and cost-effective assessment of typical saffron frauds. Copyright © 2016 Elsevier B.V. All rights reserved.

  14. Comparison of Fiber Optic and Conduit Attenuated Total Reflection (ATR) Fourier Transform Infrared (FT-IR) Setup for In-Line Fermentation Monitoring.

    Science.gov (United States)

    Koch, Cosima; Posch, Andreas E; Herwig, Christoph; Lendl, Bernhard

    2016-12-01

    The performance of a fiber optic and an optical conduit in-line attenuated total reflection mid-infrared (IR) probe during in situ monitoring of Penicillium chrysogenum fermentation were compared. The fiber optic probe was connected to a sealed, portable, Fourier transform infrared (FT-IR) process spectrometer via a plug-and-play interface. The optical conduit, on the other hand, was connected to a FT-IR process spectrometer via a knuckled probe with mirrors that had to be adjusted prior to each fermentation, which were purged with dry air. Penicillin V (PenV) and its precursor phenoxyacetic acid (POX) concentrations were determined by online high-performance liquid chromatography and the obtained concentrations were used as reference to build partial least squares regression models. Cross-validated root-mean-square errors of prediction were found to be 0.2 g L -1 (POX) and 0.19 g L -1 (PenV) for the fiber optic setup and 0.17 g L -1 (both POX and PenV) for the conduit setup. Higher noise-levels and spectrum-to-spectrum variations of the fiber optic setup lead to higher noise of estimated (i.e., unknown) POX and PenV concentrations than was found for the conduit setup. It seems that trade-off has to be made between ease of handling (fiber optic setup) and measurement accuracy (optical conduit setup) when choosing one of these systems for bioprocess monitoring. © The Author(s) 2016.

  15. Continuous wave terahertz reflection imaging of human colorectal tissue

    Science.gov (United States)

    Doradla, Pallavi; Alavi, Karim; Joseph, Cecil S.; Giles, Robert H.

    2013-03-01

    Continuous wave terahertz (THz) imaging has the potential to offer a safe, non-ionizing, and nondestructive medical imaging modality for delineating colorectal cancer. Fresh excisions of normal colon tissue were obtained from surgeries performed at the University of Massachusetts Medical School, Worcester. Reflection measurements of thick sections of colorectal tissues, mounted in an aluminum sample holder, were obtained for both fresh and formalin fixed tissues. The two-dimensional reflection images were acquired by using an optically pumped far-infrared molecular gas laser operating at 584 GHz with liquid Helium cooled silicon bolometer detector. Using polarizers in the experiment both co-polarized and cross-polarized remittance form the samples was collected. Analysis of the images showed the importance of understanding the effects of formalin fixation while determining reflectance level of tissue response. The resulting co- and cross-polarized images of both normal and formalin fixed tissues showed uniform terahertz response over the entire sample area. Initial measurements indicated a co-polarized reflectance of 16%, and a cross-polarized reflectance of 0.55% from fresh excisions of normal colonic tissues.

  16. Infrared spectroscopy for studying structure and aging effects in rhamnolipid biosurfactants

    OpenAIRE

    Kiefer, Johannes; Radzuan, Mohd Nazren; Winterburn, James

    2017-01-01

    Biosurfactants are produced by microorganisms and represent amphiphilic compounds with polar and non-polar moieties; hence they can be used to stabilize emulsions, e.g. in the cosmetic and food sectors. Their structure and its changes when exposed to light and elevated temperature are yet to be fully understood. In this study, we demonstrate that attenuated total reflection infrared (ATR-IR) spectroscopy is a useful tool for the analysis of biosurfactants, using rhamnolipids produced by ferme...

  17. Relative performance evaluation of a custom-made near infrared reflectance instrument and two commercial instruments (Foss and ASD) in the nondestructive moisture content measurement of in-shell peanuts

    Science.gov (United States)

    A custom made Near Infrared Reflectance (NIR) spectroscope was used to determine the moisture content of in-shell peanuts of Virginia type peanuts. Peanuts were conditioned to different moisture levels between 6 and 26 % (wet basis) and samples from different moisture levels were separated into two...

  18. Discrimination of various paper types using diffuse reflectance ultraviolet-visible near-infrared (UV-Vis-NIR) spectroscopy: forensic application to questioned documents.

    Science.gov (United States)

    Kumar, Raj; Kumar, Vinay; Sharma, Vishal

    2015-06-01

    Diffuse reflectance ultraviolet-visible-near-infrared (UV-Vis-NIR) spectroscopy is applied as a means of differentiating various types of writing, office, and photocopy papers (collected from stationery shops in India) on the basis of reflectance and absorbance spectra that otherwise seem to be almost alike in different illumination conditions. In order to minimize bias, spectra from both sides of paper were obtained. In addition, three spectra from three different locations (from one side) were recorded covering the upper, middle, and bottom portions of the paper sample, and the mean average reflectivity of both the sides was calculated. A significant difference was observed in mean average reflectivity of Side A and Side B of the paper using Student's pair >t-test. Three different approaches were used for discrimination: (1) qualitative features of the whole set of samples, (2) principal component analysis, and (3) a combination of both approaches. On the basis of the first approach, i.e., qualitative features, 96.49% discriminating power (DP) was observed, which shows highly significant results with the UV-Vis-NIR technique. In the second approach the discriminating power is further enhanced by incorporating the principal component analysis (PCA) statistical method, where this method describes each UV-Vis spectrum in a group through numerical loading values connected to the first few principal components. All components described 100% variance of the samples, but only the first three PCs are good enough to explain the variance (PC1 = 51.64%, PC2 = 47.52%, and PC3 = 0.54%) of the samples; i.e., the first three PCs described 99.70% of the data, whereas in the third approach, the four samples, C, G, K, and N, out of a total 19 samples, which were not differentiated using qualitative features (approach no. 1), were therefore subjected to PCA. The first two PCs described 99.37% of the spectral features. The discrimination was achieved by using a loading plot between

  19. Long-wave infrared radiation reflected by compression stockings in the treatment of cellulite: a clinical double-blind, randomized and controlled study.

    Science.gov (United States)

    Bagatin, E; Miot, H A; Soares, J L M; Sanudo, A; Afonso, J P J M; de Barros Junior, N; Talarico, S

    2013-10-01

    Cellulite refers to changes in skin relief on the thighs and buttocks of women, with a prevalence of 80-90%, causing dissatisfaction and search for treatment. Etiopathogenesis is multifactorial, as follows: herniation of the hypodermis towards the dermis, facilitated by perpendicular fibrous septa, changes in the dermal extracellular matrix, decreased adiponectin, genetic polymorphism, microcirculation alterations and inflammatory process. There are numerous therapeutic approaches, with little evidence of effectiveness. The long-wave infrared (LWIR) radiation interacts with water, improves microcirculation and stimulates metabolic processes. To date, the use of tissues with potential reflection of LWIR radiation has not been systematically investigated as adjuvant treatment for cellulite. To investigate the efficacy and safety of the treatment of cellulite through the use of compression stockings made with thread reflecting LWIR radiation. Clinical study of therapeutic intervention, controlled and double-blind, including 30 women, aging from 25 to 40 years, with cellulite of grades II and III on the thighs and buttocks who used compression stockings, "pantyhose" model, made with reflector thread of LWIR radiation, on only one randomized side. Women under other treatments for cellulite and with venous and/or blood insufficiencies were excluded. Evaluation of efficacy by clinical parameters, photographs, Dermatology Life Quality Index (DLQI), cutometry and high frequency ultrasonography and security by observation of adverse events and venous EcoDoppler recordings. DLQI scores showed significant reduction; the two-dimensional high-frequency ultrasonography showed an insignificant increase in dermal echogenicity as well as other efficacy parameters demonstrated no or slight improvement, with no differences between the sides exposed or not to LWIR; and there were no severe adverse events. Compression stockings, with or without thread reflector of LWIR, showed slight

  20. Extended X-ray absorption fine structure of copper(II) complexes at the air-water interface by a polarized total-reflection X-ray absorption technique.

    Science.gov (United States)

    Nagatani, Hirohisa; Tanida, Hajime; Watanabe, Iwao; Sagara, Takamasa

    2009-04-01

    Copper(II) complexes spread on an aqueous solution surface were studied by a polarized total-reflection X-ray absorption fine structure (TR-XAFS) technique. The polarized TR-XAFS spectra at the Cu-K edge for copper(II) porphyrins and copper(II) chlorophyllin in a monolayer were measured in situ at the air-water interface. The polarization dependences of X-ray absorption near-edge structure (XANES) involving a 1s-->4p(z) transition allowed us to estimate the molecular orientation and the local coordination structure around the copper(II) atom in the polarization plane selectively. The extended X-ray absorption fine structure (EXAFS) region of the polarized TR-XAFS spectra for the metal complexes present at the air-water interface was successfully analyzed for the first time. The relative coordination number for the copper center evaluated from the EXAFS analysis indicated larger values in the vertical polarization than in the horizontal one, in agreement with the standing-up molecular orientation at the air-water interface estimated from the XANES region.

  1. Optimizing the models for rapid determination of chlorogenic acid, scopoletin and rutin in plant samples by near-infrared diffuse reflectance spectroscopy

    Science.gov (United States)

    Mao, Zhiyi; Shan, Ruifeng; Wang, Jiajun; Cai, Wensheng; Shao, Xueguang

    2014-07-01

    Polyphenols in plant samples have been extensively studied because phenolic compounds are ubiquitous in plants and can be used as antioxidants in promoting human health. A method for rapid determination of three phenolic compounds (chlorogenic acid, scopoletin and rutin) in plant samples using near-infrared diffuse reflectance spectroscopy (NIRDRS) is studied in this work. Partial least squares (PLS) regression was used for building the calibration models, and the effects of spectral preprocessing and variable selection on the models are investigated for optimization of the models. The results show that individual spectral preprocessing and variable selection has no or slight influence on the models, but the combination of the techniques can significantly improve the models. The combination of continuous wavelet transform (CWT) for removing the variant background, multiplicative scatter correction (MSC) for correcting the scattering effect and randomization test (RT) for selecting the informative variables was found to be the best way for building the optimal models. For validation of the models, the polyphenol contents in an independent sample set were predicted. The correlation coefficients between the predicted values and the contents determined by high performance liquid chromatography (HPLC) analysis are as high as 0.964, 0.948 and 0.934 for chlorogenic acid, scopoletin and rutin, respectively.

  2. Application of micro-attenuated total reflectance Fourier transform infrared spectroscopy to ink examination in signatures written with ballpoint pen on questioned documents.

    Science.gov (United States)

    Nam, Yun Sik; Park, Jin Sook; Lee, Yeonhee; Lee, Kang-Bong

    2014-05-01

    Questioned documents examined in a forensic laboratory sometimes contain signatures written with ballpoint pen inks; these signatures were examined to assess the feasibility of micro-attenuated total reflectance (ATR) Fourier transform infrared (FTIR) spectroscopy as a forensic tool. Micro-ATR FTIR spectra for signatures written with 63 ballpoint pens available commercially in Korea were obtained and used to construct an FTIR spectral database. A library-searching program was utilized to identify the manufacturer, blend, and model of each black ballpoint pen ink based upon their FTIR peak intensities, positions, and patterns in the spectral database. This FTIR technique was also successfully used in determining the sequence of homogeneous line intersections from the crossing lines of two ballpoint pen signatures. We have demonstrated with a set of sample documents that micro-ATR FTIR is a viable nondestructive analytical method that can be used to identify the origin of the ballpoint pen ink used to mark signatures. © 2014 American Academy of Forensic Sciences.

  3. Application of the Polynomial-Based Least Squares and Total Least Squares Models for the Attenuated Total Reflection Fourier Transform Infrared Spectra of Binary Mixtures of Hydroxyl Compounds.

    Science.gov (United States)

    Shan, Peng; Peng, Silong; Zhao, Yuhui; Tang, Liang

    2016-03-01

    An analysis of binary mixtures of hydroxyl compound by Attenuated Total Reflection Fourier transform infrared spectroscopy (ATR FT-IR) and classical least squares (CLS) yield large model error due to the presence of unmodeled components such as H-bonded components. To accommodate these spectral variations, polynomial-based least squares (LSP) and polynomial-based total least squares (TLSP) are proposed to capture the nonlinear absorbance-concentration relationship. LSP is based on assuming that only absorbance noise exists; while TLSP takes both absorbance noise and concentration noise into consideration. In addition, based on different solving strategy, two optimization algorithms (limited-memory Broyden-Fletcher-Goldfarb-Shanno (LBFGS) algorithm and Levenberg-Marquardt (LM) algorithm) are combined with TLSP and then two different TLSP versions (termed as TLSP-LBFGS and TLSP-LM) are formed. The optimum order of each nonlinear model is determined by cross-validation. Comparison and analyses of the four models are made from two aspects: absorbance prediction and concentration prediction. The results for water-ethanol solution and ethanol-ethyl lactate solution show that LSP, TLSP-LBFGS, and TLSP-LM can, for both absorbance prediction and concentration prediction, obtain smaller root mean square error of prediction than CLS. Additionally, they can also greatly enhance the accuracy of estimated pure component spectra. However, from the view of concentration prediction, the Wilcoxon signed rank test shows that there is no statistically significant difference between each nonlinear model and CLS. © The Author(s) 2016.

  4. A Catalytic Path for Electrolyte Reduction in Lithium-Ion Cells Revealed by in Situ Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy

    KAUST Repository

    Shi, Feifei

    2015-03-11

    © 2015 American Chemical Society. Although controlling the interfacial chemistry of electrodes in Li-ion batteries (LIBs) is crucial for maintaining the reversibility, electrolyte decomposition has not been fully understood. In this study, electrolyte decomposition on model electrode surfaces (Au and Sn) was investigated by in situ attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy. Simultaneously obtained ATR-FTIR spectra and cyclic voltammetry measurements show that lithium ethylene dicarbonate and lithium propionate form on the Au electrode at 0.6 V, whereas diethyl 2,5-dioxahexane dicarboxylate and lithium propionate form on the Sn electrode surface at 1.25 V. A noncatalytic reduction path on the Au surface and a catalytic reduction path on the Sn surface are introduced to explain the surface dependence of the overpotential and product selectivity. This represents a new concept for explaining electrolyte reactions on the anode of LIBs. The present investigation shows that catalysis plays a dominant role in the electrolyte decomposition process and has important implications in electrode surface modification and electrolyte recipe selection, which are critical factors for enhancing the efficiency, durability, and reliability of LIBs.

  5. Development and validation of an environmentally friendly attenuated total reflectance in the mid-infrared region method for the determination of ethanol content in used engine lubrication oil.

    Science.gov (United States)

    Hatanaka, Rafael Rodrigues; Sequinel, Rodrigo; Gualtieri, Carlos Eduardo; Tercini, Antônio Carlos Bergamaschi; Flumignan, Danilo Luiz; de Oliveira, José Eduardo

    2013-05-15

    Lubricating oils are crucial in the operation of automotive engines because they both reduce friction between moving parts and protect against corrosion. However, the performance of lubricant oil may be affected by contaminants, such as gasoline, diesel, ethanol, water and ethylene glycol. Although there are many standard methods and studies related to the quantification of contaminants in lubricant oil, such as gasoline and diesel oil, to the best of our knowledge, no methods have been reported for the quantification of ethanol in used Otto cycle engine lubrication oils. Therefore, this work aimed at the development and validation of a routine method based on partial least-squares multivariate analysis combined with attenuated total reflectance in the mid-infrared region to quantify ethanol content in used lubrication oil. The method was validated based on its figures of merit (using the net analyte signal) as follows: limit of detection (0.049%), limit of quantification (0.16%), accuracy (root mean square error of prediction=0.089% w/w), repeatability (0.05% w/w), fit (R(2)=0.9997), mean selectivity (0.047), sensitivity (0.011), inverse analytical sensitivity (0.016% w/w(-1)) and signal-to-noise ratio (max: 812.4 and min: 200.9). The results show that the proposed method can be routinely implemented for the quality control of lubricant oils. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Remote sensing of potential and actual daily transpiration of plant canopies based on spectral reflectance and infrared thermal measurements: Concept with preliminary test

    International Nuclear Information System (INIS)

    Inoue, Y.; Moran, M.S.; Pinter, P.J.Jr.

    1994-01-01

    A new concept for estimating potential and actual values of daily transpiration rate of vegetation canopies is presented along with results of an initial test. The method is based on a physical foundation of spectral radiation balance for a vegetation canopy, the key inputs to the model being the remotely sensed spectral reflectance and the surface temperature of the plant canopy. The radiation interception or absorptance is estimated more directly from remotely sensed spectral data than it is from the leaf area index. The potential daily transpiration is defined as a linear function of the absorbed solar radiation, which can be estimated using a linear relationship between the fraction absorptance of solar radiation and the remotely sensed Soil Adjusted Vegetation Index for the canopy. The actual daily transpiration rate is estimated by combining this concept with the Jackson-Idso Crop Water Stress Index, which also can be calculated from remotely sensed plant leaf temperatures measured by infrared thermometry. An initial demonstration with data sets from an alfalfa crop and a rangeland suggests that the method may give reasonable estimates of potential and actual values of daily transpiration rate over diverse vegetation area based on simple remote sensing measurements and basic meteorological parameters

  7. [Simultaneous determination of instant coffee, plant fat and sugar content in liquid coffee beverage by diffuse reflectance near-infrared spectroscopy].

    Science.gov (United States)

    Wang, Dong; Min, Shun-geng; Duan, Jia; Xiong, Yan-mei; Li, Qian-qian

    2012-04-01

    The diffuse reflectance near-infrared spectra of 20 liquid coffee beverage samples were collected by FT-NIR spectrometer combined with integral sphere in this thesis. The quantitative calibration models of instant coffee, plant fat and sugar were developed respectively. The result indicated that for the calibration models of instant coffee, plant fat and sugar, the dimensions of the calibration models are 4, 5 and 4 respectively; the determination coefficients (R2) are 98.97%, 99.94% and 99.18% respectively; the root mean square errors of calibration (RMSEC) are 1.62, 0.42 and 1.58 respectively; the root mean square errors of cross validation (RMSECV) are 2.12, 0.72 and 2.01 respectively. The result of F-test showed that a very remarkable correlation exists between the estimated and specified values for each calibration model. This research indicated that NIR spectroscopy can be applied in the rapid, accurate and simultaneous determination of the three main ingredients in liquid coffee beverage. This research can provide some references for the quality control of liquid coffee beverage and the determination of the substance with chemical-fixation composition in liquid formula food.

  8. Capabilities and limitations of handheld Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) for the analysis of colourants and binders in 20th-century reverse paintings on glass

    Science.gov (United States)

    Steger, Simon; Stege, Heike; Bretz, Simone; Hahn, Oliver

    2018-04-01

    A non-invasive method has been carried out to show the capabilities and limitations of Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) for identifying of colourants and binders in modern reverse glass paintings. For this purpose, the reverse glass paintings "Zwei Frauen am Tisch" (1920-22), "Bäume" (1946) (both by Heinrich Campendonk), "Lofoten" (1933) (Edith Campendonk-van Leckwyck) and "Ohne Titel" (1954) (Marianne Uhlenhuth), were measured. In contrast to other techniques (e.g. panel and mural painting), the paint layers are applied in reverse succession. In multi-layered paint systems, the front paint layer may no longer be accessible. The work points out the different spectral appearance of a given substance (gypsum, basic lead white) in reverse glass paintings. However, inverted bands, band overlapping and derivative-shaped spectral features can be interpreted by comparing the spectra from the paintings with spectra from pure powders and pigment/linseed oil mock-ups. Moreover, the work focuses on this method's capabilities in identifying synthetic organic pigments (SOP). Reference spectra of three common SOP (PG7, PY1, PR83) were obtained from powders and historical colour charts. We identified PR83 and PY1 in two reverse glass paintings, using the measured reference spectra. The recorded DRIFTS spectra of pure linseed oil, gum Arabic, mastic, polyvinyl acetate resin and bees wax can be used to classify the binding media of the measured paintings.

  9. Determination of thermally induced trans-fatty acids in soybean oil by attenuated total reflectance fourier transform infrared spectroscopy and gas chromatography analysis.

    Science.gov (United States)

    Li, An; Ha, Yiming; Wang, Feng; Li, Weiming; Li, Qingpeng

    2012-10-24

    The intake of edible oil containing trans-fatty acids has deleterious effects mainly on the cardiovascular system. Thermal processes such as refining and frying cause the formation of trans-fatty acids in edible oil. This study was conducted to investigate the possible formation of trans-fatty acids because of the heat treatment of soybean oil. The types of trans-fatty acids in heated soybean oil are determined by attenuated total reflectance Fourier transform infrared spectroscopy and gas chromatography-mass spectrometry methods. The effects of the heating temperature on the trans-fatty acids in soybean oil were evaluated using gas chromatography flame ionization detection analysis. Results show that heat treatment at 240 °C causes the formation of trans-fatty acids in soybean oil and the amount of trans-fatty acids increases with heating time. The only peak observed at 966 cm(-1) of the samples indicates the formation of nonconjugated trans isomers in the heated soybean oil. The major types of trans-fatty acids formed were trans-polyunsaturated fatty acids. Significant increases (P oil heated to temperatures exceeding 200 °C were compared with those of the control sample. The heating temperature and duration should be considered to reduce the formation of trans-fatty acids during thermal treatment.

  10. Detection Limits for Blood on Fabrics Using Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy and Derivative Processing.

    Science.gov (United States)

    Lu, Zhenyu; DeJong, Stephanie A; Cassidy, Brianna M; Belliveau, Raymond G; Myrick, Michael L; Morgan, Stephen L

    2017-05-01

    Attenuated total reflection Fourier transform infrared spectroscopy (ATR FT-IR) was used to detect blood stains based on signature protein absorption in the mid-IR region, where intensity changes in the spectrum can be related to blood concentration. Partial least squares regression (PLSR) was applied for multivariate calibrations of IR spectra of blood dilutions on four types of fabric (acrylic, nylon, polyester, and cotton). Gap derivatives (GDs) were applied as a preprocessing technique to optimize the performance of calibration models. We report a much improved IR detection limit (DL) for blood on cotton (2700× in dilution factor units) and the first IR DL reported for blood on nylon (250×). Due to sample heterogeneity caused by fabric hydrophobicity, acrylic fabric produced variable ATR FT-IR spectra that caused poor DLs in concentration units compared to previous work. Polyester showed a similar problem at low blood concentrations that lead to a relatively poor DL as well. However, the increased surface sensitivity and decreased penetration depth of ATR FT-IR make it an excellent choice for detection of small quantities of blood on the front surface of all fabrics tested (0.0010 µg for cotton, 0.0077 µg for nylon, 0.011 µg for acrylic, and 0.0066 µg for polyester).

  11. Using visible and near-infrared diffuse reflectance spectroscopy for predicting soil properties based on regression with peaks parameters as derived from continuum-removed spectra

    Science.gov (United States)

    Vasat, Radim; Klement, Ales; Jaksik, Ondrej; Kodesova, Radka; Drabek, Ondrej; Boruvka, Lubos

    2014-05-01

    Visible and near-infrared diffuse reflectance spectroscopy (VNIR-DRS) provides a rapid and inexpensive tool for simultaneous prediction of a variety of soil properties. Usually, some sophisticated multivariate mathematical or statistical methods are employed in order to extract the required information from the raw spectra measurement. For this purpose especially the Partial least squares regression (PLSR) and Support vector machines (SVM) are the most frequently used. These methods generally benefit from the complexity with which the soil spectra are treated. But it is interesting that also techniques that focus only on a single spectral feature, such as a simple linear regression with selected continuum-removed spectra (CRS) characteristic (e.g. peak depth), can often provide competitive results. Therefore, we decided to enhance the potential of CRS taking into account all possible CRS peak parameters (area, width and depth) and develop a comprehensive methodology based on multiple linear regression approach. The eight considered soil properties were oxidizable carbon content (Cox), exchangeable (pHex) and active soil pH (pHa), particle and bulk density, CaCO3 content, crystalline and amorphous (Fed) and amorphous Fe (Feox) forms. In four cases (pHa, bulk density, Fed and Feox), of which two (Fed and Feox) were predicted reliably accurately (0.50 0.80). Acknowledgment: Authors acknowledge the financial support of the Ministry of Agriculture of the Czech Republic (grant No. QJ1230319).

  12. Study of the aerosol fragrances of eugenol derivatives in Cananga odorata using diffuse reflectance infrared Fourier transform spectroscopy and gas chromatography.

    Science.gov (United States)

    Kuo, Su-Ching; Chuang, Shien-Kai; Lin, Ho-Yang; Wang, Lai-Hao

    2009-10-19

    The purpose of this study was to develop and test a diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) method, a fast and non-destructive method without extraction, and compare it with the standard gas chromatography (GC) method currently used. A micro-orifice uniform deposit impactor (MOUDI) was used to sample all the size distributions of the aerosol particles of essential oils to investigate the relation between size distributions and the indoor concentration distributions of ylang essential oils. Correlation coefficients for DRIFTS and GC were 0.9904, 0.9910, 0.9913, and 0.9983 for eugenol, isoeugenol, methyl ether, and eugenyl acetate, respectively. The results showed that the concentrations of the four eugenol derivatives of smoke were approximately three times higher than those of mist. Additionally, the major size distributions of aerosol were 0.19 microm and 1.8 microm for the smoke and mist methods, respectively. Because these two methods produce similar results, DRIFTS is a practical method for assessing these fragrances in aerosols.

  13. Evaluation of low trans fat edible oils by attenuated total reflection-Fourier transform infrared spectroscopy and gas chromatography: a comparison of analytical approaches.

    Science.gov (United States)

    Tyburczy, Cynthia; Mossoba, Magdi M; Fardin-Kia, Ali Reza; Rader, Jeanne I

    2012-08-01

    Current interest by the food industry in exploring reformulation options that lower the content of trans fat in edible fats and oils requires methods to accurately measure low levels of trans fat. In the present study, the quantitation of trans fat in 25 edible fat and oil samples was evaluated using two current analytical approaches, attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), and gas chromatography with flame ionization detection (GC-FID) according to Official Methods of the American Oil Chemists' Society. Significant differences between the ATR-FTIR and reference GC-FID quantitations were found for samples with a trans fat content absorbance bands at or near 966 cm(-1) in the ATR-FTIR spectra, a region that was previously identified as being characteristic of isolated trans double bonds. Results demonstrate that the natural content of such oil constituents could result in significant overestimations of trans fat when ATR-FTIR is used to analyze edible fats and oils with a trans fat content <2% of total fat.

  14. A simple, sensitive and non-destructive technique for characterizing bovine dental enamel erosion: attenuated total reflection Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Kim, In-Hye; Son, Jun Sik; Min, Bong Ki; Kim, Young Kyoung; Kim, Kyo-Han; Kwon, Tae-Yub

    2016-03-30

    Although many techniques are available to assess enamel erosion in vitro, a simple, non-destructive method with sufficient sensitivity for quantifying dental erosion is required. This study characterized the bovine dental enamel erosion induced by various acidic beverages in vitro using attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. Deionized water (control) and 10 acidic beverages were selected to study erosion, and the pH and neutralizable acidity were measured. Bovine anterior teeth (110) were polished with up to 1 200-grit silicon carbide paper to produce flat enamel surfaces, which were then immersed in 20 mL of the beverages for 30 min at 37 °C. The degree of erosion was evaluated using ATR-FTIR spectroscopy and Vickers' microhardness measurements. The spectra obtained were interpreted in two ways that focused on the ν1, ν3 phosphate contour: the ratio of the height amplitude of ν3 PO4 to that of ν1 PO4 (Method 1) and the shift of the ν3 PO4 peak to a higher wavenumber (Method 2). The percentage changes in microhardness after the erosion treatments were primarily affected by the pH of the immersion media. Regression analyses revealed highly significant correlations between the surface hardness change and the degree of erosion, as detected by ATR-FTIR spectroscopy (Ptechnique for the quantification of enamel erosion.

  15. Capabilities and limitations of handheld Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) for the analysis of colourants and binders in 20th-century reverse paintings on glass.

    Science.gov (United States)

    Steger, Simon; Stege, Heike; Bretz, Simone; Hahn, Oliver

    2018-04-15

    A non-invasive method has been carried out to show the capabilities and limitations of Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) for identifying of colourants and binders in modern reverse glass paintings. For this purpose, the reverse glass paintings "Zwei Frauen am Tisch" (1920-22), "Bäume" (1946) (both by Heinrich Campendonk), "Lofoten" (1933) (Edith Campendonk-van Leckwyck) and "Ohne Titel" (1954) (Marianne Uhlenhuth), were measured. In contrast to other techniques (e.g. panel and mural painting), the paint layers are applied in reverse succession. In multi-layered paint systems, the front paint layer may no longer be accessible. The work points out the different spectral appearance of a given substance (gypsum, basic lead white) in reverse glass paintings. However, inverted bands, band overlapping and derivative-shaped spectral features can be interpreted by comparing the spectra from the paintings with spectra from pure powders and pigment/linseed oil mock-ups. Moreover, the work focuses on this method's capabilities in identifying synthetic organic pigments (SOP). Reference spectra of three common SOP (PG7, PY1, PR83) were obtained from powders and historical colour charts. We identified PR83 and PY1 in two reverse glass paintings, using the measured reference spectra. The recorded DRIFTS spectra of pure linseed oil, gum Arabic, mastic, polyvinyl acetate resin and bees wax can be used to classify the binding media of the measured paintings. Copyright © 2018 Elsevier B.V. All rights reserved.

  16. Cloud point extraction and diffuse reflectance-Fourier transform infrared spectroscopic determination of chromium(VI): A probe to adulteration in food stuffs.

    Science.gov (United States)

    Tiwari, Swapnil; Deb, Manas Kanti; Sen, Bhupendra K

    2017-04-15

    A new cloud point extraction (CPE) method for the determination of hexavalent chromium i.e. Cr(VI) in food samples is established with subsequent diffuse reflectance-Fourier transform infrared (DRS-FTIR) analysis. The method demonstrates enrichment of Cr(VI) after its complexation with 1,5-diphenylcarbazide. The reddish-violet complex formed showed λ max at 540nm. Micellar phase separation at cloud point temperature of non-ionic surfactant, Triton X-100 occurred and complex was entrapped in surfactant and analyzed using DRS-FTIR. Under optimized conditions, the limit of detection (LOD) and quantification (LOQ) were 1.22 and 4.02μgmL -1 , respectively. Excellent linearity with correlation coefficient value of 0.94 was found for the concentration range of 1-100μgmL -1 . At 10μgmL -1 the standard deviation for 7 replicate measurements was found to be 0.11μgmL -1 . The method was successfully applied to commercially marketed food stuffs, and good recoveries (81-112%) were obtained by spiking the real samples. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy on Intact Dried Leaves of Sage (Salvia officinalis L.): Accelerated Chemotaxonomic Discrimination and Analysis of Essential Oil Composition.

    Science.gov (United States)

    Gudi, Gennadi; Krähmer, Andrea; Krüger, Hans; Schulz, Hartwig

    2015-10-07

    Sage (Salvia officinalis L.) is cultivated worldwide for its aromatic leaves, which are used as herbal spice, and for phytopharmaceutical applications. Fast analytical strategies for essential oil analysis, performed directly on plant material, would reduce the delay between sampling and analytical results. This would enhance product quality by improving technical control of cultivation. The attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) method described here provides a reliable calibration model for quantification of essential oil components [EOCs; R(2) = 0.96; root-mean-square error of cross-validation (RMSECV) = 0.249 mL 100 g(-1) of dry matter (DM); and range = 1.115-5.280 mL 100 g(-1) of DM] and main constituents [e.g., α-thujone/β-thujone; R(2) = 0.97/0.86; RMSECV = 0.0581/0.0856 mL 100 g(-1) of DM; and range = 0.010-1.252/0.005-0.893 mL 100 g(-1) of DM] directly on dried intact leaves of sage. Except for drying, no further sample preparation is required for ATR-FTIR, and the measurement time of less than 5 min per sample contrasts with the most common alternative of hydrodistillation followed by gas chromatography analysis, which can take several hours per sample.

  18. Near-infrared imaging of demineralization under sealants

    Science.gov (United States)

    Tom, Henry; Simon, Jacob C.; Chan, Kenneth H.; Darling, Cynthia L.; Fried, Daniel

    2014-07-01

    Previous studies have shown that near-infrared (NIR) reflectance and transillumination imaging can be used to acquire high contrast images of early caries lesions and composite restorative materials. The aim of the study was to determine the optimum NIR wavelengths for imaging demineralized areas under dental sealants. Fifteen natural human premolars and molars with occlusal lesions were used in this in vitro study. Images before and after application of sealants were acquired using NIR reflectance and NIR transillumination at wavelengths of 1300, 1460, and 1500 to 1700 nm. Images were also acquired using polarization sensitive optical coherence tomography (OCT) for comparison. The highest contrast for NIR reflectance was at 1460 nm and 1500 to 1700 nm. These NIR wavelengths are coincident with higher water absorption. The clear Delton sealant investigated was not visible in either copolarization or cross-polarization OCT images. The wavelength region between 1500 and 1700 nm yielded the highest contrast of lesions under sealants for NIR reflectance measurements.

  19. Metasurfaces for Terahertz Waves Polarization Control

    DEFF Research Database (Denmark)

    Lavrinenko, Andrei; Malureanu, Radu; Zalkovskij, Maksim

    in the visible, near infrared or microwave regimes these issues in principle have strong alternatives via a conventional optics or electromagnetic approaches, at terahertz (THz) frequencies metamaterials are often considered as being the unique solution for the encountered problems. Several approaches involving...... that the maximal conversion efficiency with a single metamaterial surface is 50 % in transmission and up to 90% in reflection. However, a double layer transmission converter and a single layer with a metallic mirror can have 100% polarization conversion efficiency. We tested our conclusions numerically reaching...

  20. Electrochemical, atomic force microscopy and infrared reflection absorption spectroscopy studies of pre-formed mussel adhesive protein films on carbon steel for corrosion protection

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fan, E-mail: fanzhang@kth.se [KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Chemistry, Div. of Surface and Corrosion Science, Drottning Kristinas vaeg.51, SE-100 44 Stockholm (Sweden); Pan, Jinshan [KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Chemistry, Div. of Surface and Corrosion Science, Drottning Kristinas vaeg.51, SE-100 44 Stockholm (Sweden); Claesson, Per Martin [KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Chemistry, Div. of Surface and Corrosion Science, Drottning Kristinas vaeg.51, SE-100 44 Stockholm (Sweden); Institute for Surface Chemistry, P.O. Box 5607, SE-114 86 Stockholm (Sweden); Brinck, Tore [KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Physical Chemistry, Division of Physical Chemistry, Teknikringen 36, SE-10044 Stockholm (Sweden)

    2012-10-01

    Electrochemical measurements, in situ and ex situ atomic force microscopy (AFM) experiments and infrared reflection absorption spectroscopy (IRAS) analysis were performed to investigate the formation and stability as well as corrosion protection properties of mussel adhesive protein (Mefp-1) films on carbon steel, and the influence of cross-linking by NaIO{sub 4} oxidation. The in situ AFM measurements show flake-like adsorbed protein aggregates in the film formed at pH 9. The ex situ AFM images indicate multilayer-like films and that the film becomes more compact and stable in NaCl solution after the cross-linking. The IRAS results reveal the absorption bands of Mefp-1 on carbon steel before and after NaIO{sub 4} induced oxidation of the pre-adsorbed protein. Within a short exposure time, a certain corrosion protection effect was noted for the pre-formed Mefp-1 film in 0.1 M NaCl solution. Cross-linking the pre-adsorbed film by NaIO{sub 4} oxidation significantly enhanced the protection efficiency by up to 80%. - Highlights: Black-Right-Pointing-Pointer Mussel protein was tested as 'green' corrosion protection strategy for steel. Black-Right-Pointing-Pointer At pH 9, the protein adsorbs on carbon steel and forms a multilayer-like film. Black-Right-Pointing-Pointer NaIO{sub 4} leads to structural changes and cross-linking of the protein film. Black-Right-Pointing-Pointer Cross-linking results in a dense and compact film with increased stability. Black-Right-Pointing-Pointer Cross-linking of preformed film significantly enhances the corrosion protection.

  1. Attenuated Total Reflectance Fourier transform infrared spectroscopy for determination of Long Chain Free Fatty Acid concentration in oily wastewater using the double wavenumber extrapolation technique.

    Science.gov (United States)

    Hao, Zisu; Malyala, Divya; Dean, Lisa; Ducoste, Joel

    2017-04-01

    Long Chain Free Fatty Acids (LCFFAs) from the hydrolysis of fat, oil and grease (FOG) are major components in the formation of insoluble saponified solids known as FOG deposits that accumulate in sewer pipes and lead to sanitary sewer overflows (SSOs). A Double Wavenumber Extrapolative Technique (DWET) was developed to simultaneously measure LCFFAs and FOG concentrations in oily wastewater suspensions. This method is based on the analysis of the Attenuated Total Reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) spectrum, in which the absorbance of carboxyl bond (1710cm -1 ) and triglyceride bond (1745cm -1 ) were selected as the characteristic wavenumbers for total LCFFAs and FOG, respectively. A series of experiments using pure organic samples (Oleic acid/Palmitic acid in Canola oil) were performed that showed a linear relationship between the absorption at these two wavenumbers and the total LCFFA. In addition, the DWET method was validated using GC analyses, which displayed a high degree of agreement between the two methods for simulated oily wastewater suspensions (1-35% Oleic acid in Canola oil/Peanut oil). The average determination error of the DWET approach was ~5% when the LCFFA fraction was above 10wt%, indicating that the DWET could be applied as an experimental method for the determination of both LCFFAs and FOG concentrations in oily wastewater suspensions. Potential applications of this DWET approach includes: (1) monitoring the LCFFAs and FOG concentrations in grease interceptor (GI) effluents for regulatory compliance; (2) evaluating alternative LCFFAs/FOG removal technologies; and (3) quantifying potential FOG deposit high accumulation zones in the sewer collection system. Published by Elsevier B.V.

  2. Monitoring hemodynamic and morphologic responses to closed head injury in a mouse model using orthogonal diffuse near-infrared light reflectance spectroscopy

    Science.gov (United States)

    Abookasis, David; Shochat, Ariel; Mathews, Marlon S.

    2013-04-01

    The authors' aim is to assess and quantitatively measure brain hemodynamic and morphological variations during closed-head injury (CHI) in mice using orthogonal diffuse near-infrared reflectance spectroscopy (o-DRS). CHI is a type of injury to the head that does not penetrate the skull. Usually, it is caused by mechanical blows to the head and frequently occurs in traffic accidents, falls, and assaults. Measurements of brain optical properties, namely absorption and reduced scattering coefficients in the wavelength range from 650 to 1000 nm were carried out by employing different source-detector distance and locations to provide depth sensitivity on an intact scalp over the duration of the whole experiment. Furthermore, alteration in both cortical hemodynamics and morphologic markers, i.e., scattering power and amplitude properties were derived. CHI was induced in anesthetized male mice by a weight-drop model using ˜50 g cylindrical metal falling from a height of 90 cm onto the intact scalp producing an impact of 4500 g cm. With respect to baseline, difference in brain physiological properties was observed following injury up to 1 h post-trauma. Additionally, the reduced scattering spectral shapes followed Mie scattering theory was quantified and clearly shows changes in both scattering amplitude and power from baseline indicating structural variations likely from evolving cerebral edema during CHI. We further demonstrate high correlation between scattering amplitude and scattering power, with more than 20% difference in slope in comparison to preinjury. This result indicates the possibility of using the slope also as a marker for detection of structural changes. Finally, experiments investigating brain function during the first 20 min postinjury were conducted and changes in chromophore concentrations and scattering were observed. Overall, our experiments demonstrate the potential of using the proposed technique as a valuable quantitative noninvasive tool for

  3. On the reflectance of dust in comets

    Science.gov (United States)

    Zubko, Evgenij; Videen, Gorden; Shkuratov, Yuriy; Hines, Dean C.

    2017-11-01

    Reflectance of cometary dust is a key parameter used in the characterization of comets. In the literature, the reflectance of single-scattering cometary dust particles is widely assumed to be the same as that of the cometary nucleus. We discuss this assumption and demonstrate its inconsistency with photometric observations of comets, laboratory optical measurements, and numerical simulation of light scattering from single-scattering dust particles and particulate surfaces composed of the same particles. We estimate the reflectance of cometary dust particles using a comprehensive physical model of polarization measured in comets over wide range of phase angle and at different wavelengths in the visible. The model predicts that the reflectance of dust in comets inversely correlates with their maximum of positive polarization Pmax. We find that even the darkest dust particles appearing in comets with the highest Pmax, reflect considerably more incident solar-radiation energy, up to 200%, compared to what is thought for cometary nuclei. We also find that the reflectance retrieved from polarimetry in the visible appears in good quantitative accordance with previous estimations from infrared observations of comets. Our findings suggest that the dust production of comets is currently overestimated and may require revision.

  4. Reflective optics

    CERN Document Server

    Korsch, Dietrich

    1991-01-01

    This is the first book dedicated exclusively to all-reflective imaging systems. It is a teaching tool as well as a practical design tool for anyone who specializes in optics, particularly for those interested in telescopes, infrared, and grazing-incidence systems. The first part of the book describes a unified geometric optical theory of all-reflective imaging systems (from near-normal to grazing incidence) developed from basic principles. The second part discusses correction methods and a multitude of closed-form solutions of well-corrected systems, supplemented with many conventional and unc

  5. Polarization Optics

    OpenAIRE

    Fressengeas, Nicolas

    2010-01-01

    The physics of polarization optics *Polarized light propagation *Partially polarized light; DEA; After a brief introduction to polarization optics, this lecture reviews the basic formalisms for dealing with it: Jones Calculus for totally polarized light and Stokes parameters associated to Mueller Calculus for partially polarized light.

  6. Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: extending the predictions to different years and different sites

    Science.gov (United States)

    Reggente, Matteo; Dillner, Ann M.; Takahama, Satoshi

    2016-02-01

    Organic carbon (OC) and elemental carbon (EC) are major components of atmospheric particulate matter (PM), which has been associated with increased morbidity and mortality, climate change, and reduced visibility. Typically OC and EC concentrations are measured using thermal-optical methods such as thermal-optical reflectance (TOR) from samples collected on quartz filters. In this work, we estimate TOR OC and EC using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE Teflon) filters using partial least square regression (PLSR) calibrated to TOR OC and EC measurements for a wide range of samples. The proposed method can be integrated with analysis of routinely collected PTFE filter samples that, in addition to OC and EC concentrations, can concurrently provide information regarding the functional group composition of the organic aerosol. We have used the FT-IR absorbance spectra and TOR OC and EC concentrations collected in the Interagency Monitoring of PROtected Visual Environments (IMPROVE) network (USA). We used 526 samples collected in 2011 at seven sites to calibrate the models, and more than 2000 samples collected in 2013 at 17 sites to test the models. Samples from six sites are present both in the calibration and test sets. The calibrations produce accurate predictions both for samples collected at the same six sites present in the calibration set (R2 = 0.97 and R2 = 0.95 for OC and EC respectively), and for samples from 9 of the 11 sites not included in the calibration set (R2 = 0.96 and R2 = 0.91 for OC and EC respectively). Samples collected at the other two sites require a different calibration model to achieve accurate predictions. We also propose a method to anticipate the prediction error; we calculate the squared Mahalanobis distance in the feature space (scores determined by PLSR) between new spectra and spectra in the calibration set. The squared Mahalanobis distance provides a crude method for assessing the

  7. Soy Protein Isolate and Glycerol Hydrogen Bonding Using Two-Dimensional Correlation (2D-COS) Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy.

    Science.gov (United States)

    Yan, Zhiwei; Li, Qian; Zhang, Pudun

    2017-11-01

    It is a trend to substitute bioplastics for petroleum-based plastics in food packaging. Glycerol-plasticized soy protein isolate (SPI) is promising as a replacement for traditional petroleum-based plastics. Hydrogen bonding (H-bonding) plays a key role in plasticization of SPI film. However, few publications are concerned with the interactions of SPI and glycerol at the molecular level. In this paper, attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy was applied to investigate the effect of H-bonding on the secondary structures of glycerol-plasticized SPI films and thus on the plasticization. An "S" profile of the H-bonding between SPI and glycerol with an abrupt jump in the glycerol range of 10-30% was achieved. For more in-depth investigation of the H-bonding, two-dimensional correlation spectroscopy (2D-COS) and perturbation-correlation moving-window two-dimensional (PCMW2D) analyses were applied to the amide I and II bands of SPI films spectra series. The conformation change sequences under the effect of H-bonding were revealed. When glycerol was involved, it entered into the β-sheet and the H-bonds of the SPI peptide backbone (C = O···H-N-) were replaced by the new H-bonds between SPI and glycerol (C = O···H-O-). The transformations of parallel β-sheet to β-turn in the range of 0-20% and anti-parallel β-sheet to β-turn in the range of 20-35% were obtained. In the 35-60% concentration range, the β-sheet was first changed to a transition state conformation, then together with the β-turn, to the random coil. The 2D-COS results clearly suggest that the conformations of SPI gradually change from the ordered to the less ordered and disordered, which significantly improve the plasticity of SPI film.

  8. Quantitative determination of polyphosphate in sediments using Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy and partial least squares regression.

    Science.gov (United States)

    Khoshmanesh, Aazam; Cook, Perran L M; Wood, Bayden R

    2012-08-21

    Phosphorus (P) is a major cause of eutrophication and subsequent loss of water quality in freshwater ecosystems. A major part of the flux of P to eutrophic lake sediments is organically bound or of biogenic origin. Despite the broad relevance of polyphosphate (Poly-P) in bioremediation and P release processes in the environment, its quantification is not yet well developed for sediment samples. Current methods possess significant disadvantages because of the difficulties associated with using a single extractant to extract a specific P compound without altering others. A fast and reliable method to estimate the quantitative contribution of microorganisms to sediment P release processes is needed, especially when an excessive P accumulation in the form of polyphosphate (Poly-P) occurs. Development of novel approaches for application of emerging spectroscopic techniques to complex environmental matrices such as sediments significantly contributes to the speciation models of P mobilization, biogeochemical nutrient cycling and development of nutrient models. In this study, for the first time Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy in combination with partial least squares (PLS) was used to quantify Poly-P in sediments. To reduce the high absorption matrix components in sediments such as silica, a physical extraction method was developed to separate sediment biological materials from abiotic particles. The aim was to achieve optimal separation of the biological materials from sediment abiotic particles with minimum chemical change in the sample matrix prior to ATR-FTIR analysis. Using a calibration set of 60 samples for the PLS prediction models in the Poly-P concentration range of 0-1 mg g(-1) d.w. (dry weight of sediment) (R(2) = 0.984 and root mean square error of prediction RMSEP = 0.041 at Factor-1) Poly-P could be detected at less than 50 μg g(-l) d.w. Using this technique, there is no solvent extraction or chemical

  9. Radio properties of the highly polarized, quiescent quasar OI 287

    Science.gov (United States)

    Ulvestad, James S.; Antonucci, Robert R. J.

    1988-01-01

    The highly polarized, quiescent quasar OI 287 has been observed with high resolution at 2 cm and 6 cm in an effort to determine the origin of some of the object's peculiar properties. The results seem to rule out the classification of OI 287 as a blazar. Extrapolation of the radio core spectrum to midinfrared wavelengths fails to predict the infrared flux by at least an order of magnitude. This supports the conclusion that the infrared emission and the radio emission do not originate in the same synchrotron-emitting component. The high optical polarization could be related to possible broad absorption lines in the unobserved UV regime, or it could be caused by reflection into the line of sight by scattering agents distributed in a thin disk.

  10. Infrared retina

    Science.gov (United States)

    Krishna, Sanjay [Albuquerque, NM; Hayat, Majeed M [Albuquerque, NM; Tyo, J Scott [Tucson, AZ; Jang, Woo-Yong [Albuquerque, NM

    2011-12-06

    Exemplary embodiments provide an infrared (IR) retinal system and method for making and using the IR retinal system. The IR retinal system can include adaptive sensor elements, whose properties including, e.g., spectral response, signal-to-noise ratio, polarization, or amplitude can be tailored at pixel level by changing the applied bias voltage across the detector. "Color" imagery can be obtained from the IR retinal system by using a single focal plane array. The IR sensor elements can be spectrally, spatially and temporally adaptive using quantum-confined transitions in nanoscale quantum dots. The IR sensor elements can be used as building blocks of an infrared retina, similar to cones of human retina, and can be designed to work in the long-wave infrared portion of the electromagnetic spectrum ranging from about 8 .mu.m to about 12 .mu.m as well as the mid-wave portion ranging from about 3 .mu.m to about 5 .mu.m.

  11. Infrared dispersion analysis and Raman scattering spectra of taurine single crystals

    Science.gov (United States)

    Moreira, Roberto L.; Lobo, Ricardo P. S. M.; Dias, Anderson

    2018-01-01

    A comprehensive set of optical vibrational modes of monoclinic taurine crystals was determined by Raman scattering, and infrared reflectivity and transmission spectroscopies. By using appropriate scattering/reflection geometries, the vibrational modes were resolved by polarization and the most relevant modes of the crystal could be assigned. In particular, we were able to review the symmetry of the gerade modes and to resolve ambiguities in the literature. Owing to the non-orthogonal character of Bu modes in monoclinic crystals (lying on the optic axial plane), we carried out a generalized Lorentz dispersion analysis consisting of simultaneous adjust of infrared-reflectivity spectra at various light polarization angles. The Au modes (parallel to the C2-axis) were treated within the classical Lorentz model. The behavior of off-diagonal and diagonal terms of the complex dielectric tensors and the presence of anomalous dispersion were discussed as consequences of the low symmetry of the crystal.

  12. Airborne Laser Polarization Sensor

    Science.gov (United States)

    Kalshoven, James, Jr.; Dabney, Philip

    1991-01-01

    Instrument measures polarization characteristics of Earth at three wavelengths. Airborne Laser Polarization Sensor (ALPS) measures optical polarization characteristics of land surface. Designed to be flown at altitudes of approximately 300 m to minimize any polarizing or depolarizing effects of intervening atmosphere and to look along nadir to minimize any effects depending on look angle. Data from measurements used in conjunction with data from ground surveys and aircraft-mounted video recorders to refine mathematical models used in interpretation of higher-altitude polarimetric measurements of reflected sunlight.

  13. UV Coatings, Polarization, and Coronagraphy

    Science.gov (United States)

    Bolcar, Matthew R.; Quijada, Manuel; West, Garrett; Balasubramanian, Bala; Krist, John; Martin, Stefan; Sabatke, Derek

    2016-01-01

    Presenation for the Large UltraViolet Optical Infrared (LUVOIR) and Habitable Exoplanet Imager (HabEx) Science and Technology Definition Teams (STDT) on technical considerations regarding ultraviolet coatings, polarization, and coronagraphy. The presentations review the state-of-the-art in ultraviolet coatings, how those coatings generate polarization aberrations, and recent study results from both the LUVOIR and HabEx teams.

  14. Reflection of circularly polarized light and the effect of particle distribution on circular dichroism in evaporation induced self-assembled cellulose nanocrystal thin films

    Science.gov (United States)

    Hewson, D.; Vukusic, P.; Eichhorn, S. J.

    2017-06-01

    Evaporation induced self-assembled (EISA) thin films of cellulose nanocrystals (CNCs) have shown great potential for displaying structural colour across the visible spectrum. They are believed primarily to reflect left handed circularly polarised (LCP) light due to their natural tendency to form structures comprising left handed chirality. Accordingly the fabrication of homogenously coloured CNC thin films is challenging. Deposition of solid material towards the edge of a dried droplet, via the coffee-stain effect, is one such difficulty in achieving homogenous colour across CNC films. These effects are most easily observed in films prepared from droplets where observable reflection of visible light is localised around the edge of the dry film. We report here, the observation of both left and right hand circularly polarised (LCP/RCP) light in reflection from distinct separate regions of CNC EISA thin films and we elucidate how these reflections are dependent on the distribution of CNC material within the EISA thin film. Optical models of reflection are presented which are based on structures revealed using high resolution transmission electron microscopy (TEM) images of film cross sections. We have also employed spectroscopic characterisation techniques to evaluate the distribution of solid CNC material within a selection of CNC EISA thin films and we have correlated this distribution with polarised light spectra collected from each film. We conclude that film regions from which RCP light was reflected were associated with lower CNC concentrations and thicker film regions.

  15. Reflection of circularly polarized light and the effect of particle distribution on circular dichroism in evaporation induced self-assembled cellulose nanocrystal thin films

    Directory of Open Access Journals (Sweden)

    D. Hewson

    2017-06-01

    Full Text Available Evaporation induced self-assembled (EISA thin films of cellulose nanocrystals (CNCs have shown great potential for displaying structural colour across the visible spectrum. They are believed primarily to reflect left handed circularly polarised (LCP light due to their natural tendency to form structures comprising left handed chirality. Accordingly the fabrication of homogenously coloured CNC thin films is challenging. Deposition of solid material towards the edge of a dried droplet, via the coffee-stain effect, is one such difficulty in achieving homogenous colour across CNC films. These effects are most easily observed in films prepared from droplets where observable reflection of visible light is localised around the edge of the dry film. We report here, the observation of both left and right hand circularly polarised (LCP/RCP light in reflection from distinct separate regions of CNC EISA thin films and we elucidate how these reflections are dependent on the distribution of CNC material within the EISA thin film. Optical models of reflection are presented which are based on structures revealed using high resolution transmission electron microscopy (TEM images of film cross sections. We have also employed spectroscopic characterisation techniques to evaluate the distribution of solid CNC material within a selection of CNC EISA thin films and we have correlated this distribution with polarised light spectra collected from each film. We conclude that film regions from which RCP light was reflected were associated with lower CNC concentrations and thicker film regions.

  16. Dynamically Switching the Polarization State of Light Based on the Phase Transition of Vanadium Dioxide

    Science.gov (United States)

    Jia, Zhi-Yong; Shu, Fang-Zhou; Gao, Ya-Jun; Cheng, Feng; Peng, Ru-Wen; Fan, Ren-Hao; Liu, Yongmin; Wang, Mu

    2018-03-01

    There have been great endeavors devoted to manipulating the polarization state of light by plasmonic nanostructures in recent decades. However, the topic of active polarizers has attracted much less attention. We present a composite plasmonic nanostructure consisting of vanadium dioxide that can dynamically modulate the polarization state of the reflected light through a thermally induced phase transition of vanadium dioxide. We design a system consisting of anisotropic plasmonic nanostructures with vanadium dioxide that exhibits distinct reflections subjected to different linearly polarized incidence at room temperature and in the heated state. Under a particular linearly polarized incidence, the polarization state of the reflected light changes at room temperature, and reverts to its original polarization state above the phase-transition temperature. The composite structure can also be used to realize a dynamically switchable infrared image, wherein a pattern can be visualized at room temperature while it disappears above the phase-transition temperature. The composite structure could be potentially used for versatile optical modulators, molecular detection, and polarimetric imaging.

  17. Step-type and step-density influences on CO adsorption probed by reflection absorption infrared spectroscopy using a curved Pt(1 1 1) surface

    NARCIS (Netherlands)

    Walsh, A. J.; van Lent, R.; Auras, S. V.; Gleeson, M. A.; Berg, O. T.; Juurlink, L. B. F.

    2017-01-01

    In comparison to flat single crystals, the continuous variation of structure provided by curved crystals offers many benefits for the study of physical and chemical processes at surfaces. However, the curvature of the surface also creates experimental challenges. For infrared spectroscopy, in

  18. Analysis of various quality attributes of sunflower and soybean plants by near infra-red reflectance spectroscopy: Development and validation calibration models

    Science.gov (United States)

    Sunflower and soybean are summer annuals that can be grown as an alternative to corn and may be particularly useful in organic production systems. Rapid and low cost methods of analyzing plant quality would be helpful for crop management. We developed and validated calibration models for Near-infrar...

  19. HAWC+/SOFIA Instrumental Polarization Calibration

    Science.gov (United States)

    Michail, Joseph M.; Chuss, David; Dowell, Charles D.; Santos, Fabio; Siah, Javad; Vaillancourt, John; HAWC+ Instrument Team

    2018-01-01

    HAWC+ is a new far-infrared polarimeter for the NASA/DLR SOFIA (Stratospheric Observatory for Infrared Astronomy) telescope. HAWC+ has the capability to measure the polarization of astronomical sources with unprecedented sensitivity and angular resolution in four bands from 50-250 microns. Using data obtained during commissioning flights, we implemented a calibration strategy that separates the astronomical polarization signal from the induced instrumental polarization. The result of this analysis is a map of the instrumental polarization as a function of position in the instrument's focal plane in each band. The results show consistency between bands, as well as with other methods used to determine preliminary instrumental polarization values.

  20. Kramers-Kronig relations for interstellar polarization

    International Nuclear Information System (INIS)

    Martin, P.G.

    1975-01-01

    The difficulties encountered in using the Kramers-Kronig relations to predict the behavior of interstellar polarization are pointed out, while at the same time their value in an interpretive role is acknowledged. Observations of interstellar circular polarization lead to restrictions on the interstellar grain composition, and additional constraints should be possible through measurement of linear polarization in the infrared and the ultraviolet

  1. Study of mixed phase clouds over west Africa: Ice-crystal corner reflection effects observed with a two-wavelength polarization lidar

    Directory of Open Access Journals (Sweden)

    Veselovskii Igor

    2018-01-01

    Full Text Available Lidar sounding is used for the analysis of possible contribution of the corner reflection (CR effect to the total backscattering in case of ice crystals. Our study is based on observations of mixed phase clouds performed during the SHADOW campaign in Senegal. Mie-Raman lidar allows measurements at 355 nm and 532 nm at 43 dg. off-zenith angle, so the extinction and backscattering Ångström exponents can be evaluated. In some measurements we observed the positive values of backscattering Ångström exponent, which can be attributed to the corner reflection by horizontally oriented ice plates.

  2. [The multi-angle polarization spectral character of water and its applications in water color remote sensing].

    Science.gov (United States)

    Wu, Tai-Xia; Yan, Lei; Xiang, Yun; Zhao, Yun-Sheng; Chen, Wei

    2010-02-01

    The reflectance of pure water is very low at visible and near infrared bands. Its spectral characteristics are not obvious. Water always shows dark hue in optical remote sensing images. This dark hue causes the difficulties in water remote sensing identification. There is an interesting phenomenon when the authors research the water polarization spectroscopy. The authors measured water's polarization spectra and reflectance spectra at different view zenith angles using the ASD spectrometer. When the view zenith angle was zero (measured vertically), as the spectrum people commonly measure, there was no polarization phenomenon at the water surface, and the reflectance was low at each band. Along with the increase in view zenith angle, the DOP spectra curves increased evidently, while the reflectance curves only changed a little. When the view zenith angle was over 30 degree, the values of DOP spectrum were much larger than the reflectance spectrum values at the entire visible and near infrared bands. At some bands, the DOP value was several dozen times than its reflectance value. This phenomenon shows that the water's brightness in DOP image is much higher than its brightness in intensity image under the same condition. This rule was verified by the PARASOL multiangle polarization satellite data. Comparing the average brightness of DOP images with the average brightness of intensity images at 490, 670 and 865 nm band, the former is higher than the latter apparently. The brighter DOP images are better for water remote sensing identification It is the first time that the authors found this special multiangle polarization spectral character of water. It revealed the advantage of water detection using the multiangle polarization remote sensing data. This method solved the low reflectivity problem of water color remote sensing. It will greatly improve the capability of water remote sensing identification and the retrieval accuracy of water quality parameters.

  3. Rapid integrated rheo-optical and polarized Fourier-transform infrared spectrometry measurement system for polymer films undergoing chemo-mechanical changes.

    Science.gov (United States)

    Unsal, E; Nugay, I I; Offenbach, I; Gross, M; Manning, C; Cakmak, M

    2013-07-01

    The design and performance of a multisensory instrument to track physical and chemical changes of thin polymer films (typically 5 μm stretching direction, received by detector unit. This design allows to analyze both polarizations simultaneously wavenumbers in the range of 500 cm(-1)-4000 cm(-1). Controlled processing parameters include air speed, air temperature, stretching rate, stretching ratio, stretch cycling, and holding times; while simultaneously measuring optical retardation, sample width, temperature, load cell, and both parallel and perpendicular IR spectra. Calibration and performance of this instrument is demonstrated with several film samples. These are: A polystyrene standard, an atactic polystyrene (homo-polymer), a polyurethane (consists of hard and soft segments) for physical changes during uniaxial deformation, and a polyamic acid during imidization reaction. This measurement system is particularly useful in unraveling molecular level details of complex physical and chemical events that take place during very fast deformation schemes (uniaxial stretching, retraction, relaxation, annealing, etc.) relevant to industrial processes. These include specific orientation behavior of each phase, block or filler, crystallization, relaxation and orientation state. It is also suited to track reaction rates and products in polymers undergoing thermal or photo curing.

  4. Parallel Polarization State Generation.

    Science.gov (United States)

    She, Alan; Capasso, Federico

    2016-05-17

    The control of polarization, an essential property of light, is of wide scientific and technological interest. The general problem of generating arbitrary time-varying states of polarization (SOP) has always been mathematically formulated by a series of linear transformations, i.e. a product of matrices, imposing a serial architecture. Here we show a parallel architecture described by a sum of matrices. The theory is experimentally demonstrated by modulating spatially-separated polarization components of a laser using a digital micromirror device that are subsequently beam combined. This method greatly expands the parameter space for engineering devices that control polarization. Consequently, performance characteristics, such as speed, stability, and spectral range, are entirely dictated by the technologies of optical intensity modulation, including absorption, reflection, emission, and scattering. This opens up important prospects for polarization state generation (PSG) with unique performance characteristics with applications in spectroscopic ellipsometry, spectropolarimetry, communications, imaging, and security.

  5. Application of reflectance micro-Fourier Transform infrared analysis to the study of coal macerals: An example from the Late Jurassic to Early Cretaceous coals of the Mist Mountain Formation, British Columbia, Canada

    Science.gov (United States)

    Mastalerz, Maria; Bustin, R.M.

    1996-01-01

    The applicability of the reflectance micro-Fourier Transform infra-red spectroscopy (FTIR) technique for analyzing the distribution of functional groups in coal macerals is discussed. High quality of spectra, comparable to those obtained using other FTIR techniques (KBr pellet and transmission micro-FTIR), indicate this technique can be applied to characterizing functional groups under most conditions. The ease of sample preparation, the potential to analyze large intact samples, and ability to characterize organic matter in areas as small as 20 ??m are the main advantages of reflectance micro-FTIR. The quantitative aspects of reflectance micro-FTIR require further study. The examples from the coal seams of the Mist Mountain Formation, British Columbia show that at high volatile bituminous rank, reflectance micro-FTIR provides valuable information on the character of aliphatic chains of vitrinite and liptinite macerals. Because the character of aliphatic chains influences bond disassociation energies, such information is useful from a hydrocarbon generation viewpoint. In medium volatile bituminous coal liptinite macerals are usually not detectable but this technique can be used to study the degree of oxidation and reactivity of vitrinite and semifusinite.

  6. Study of magnetic thin films by polarized neutron reflectivity. Off-specular diffusion on periodical structures; Etude de couches minces magnetiques par reflectivite de neutrons polarises. Diffusion non speculaire sur des structures periodiques

    Energy Technology Data Exchange (ETDEWEB)

    Ott, F

    1998-11-26

    Theoretical (Zeeman energy effects) and experimental (beam polarisation problems) progress have been made in the understanding of polarized neutron reflectivity with polarisation analysis. It has been shown that modelization and numerical simulations makes it possible to avoid to have to systematically measure a full set of reflectivity curves for each field and temperature condition. It has been possible to determine a magnetic profile as a function of the field in a magnetic bilayer system by using only a few points in the reciprocal space. This technique allows to considerable reduce the experiment time. In single nickel layer systems, we have shown that it is possible to induce magnetic rotation inhomogeneities when these systems are subjects to deformation strains. The effect are related to magneto-elastic constants gradients. In trilayer systems, with a ME constant modulation, we have been able to induce large magnetic rotation gradients. A new magneto-optic technique to measure the magnetization direction without rotating the magnetic field has been developed. The field of neutron reflectivity has been extended to off-specular studies. It has been possible to account quantitatively of the off-specular diffusion on 2-D model systems (prepared by optical lithography). This new technique should make it possible in the future to determine magnetic structures with a in-depth as well as lateral resolution. (author)

  7. Hubble Space Telescope NICMOS Polarization Measurements of OMC-1

    Science.gov (United States)

    Simpson, Janet P.; Colgan, Sean W. J.; Erickson, Edwin F.; Burton, Michael G.; Schultz, A. S. B.

    2006-01-01

    We present 2 micrometer polarization measurements of positions in the BN region of the Orion Molecular Cloud (OMC-1) made with NICMOS Camera 2 (0.2" resolution) on Hubble Space Telescope. Our goals are to seek the sources of heating for IRc2, 3, 4, and 7, identify possible young stellar objects (YSOs), and characterize the grain alignment in the dust clouds along the lines-of-sight to the stars. Our results are as follows: BN is approximately 29% polarized by dichroic absorption and appears to be the illuminating source for most of the nebulosity to its north and up to approximately 5" to its south. Although the stars are probably all polarized by dichroic absorption, there are a number of compact, but non-point-source, objects that could be polarized by a combination of both dichroic absorption and local scattering of star light. We identify several candidate YSOs, including an approximately edge-on bipolar YSO 8.7" east of BN, and a deeply-embedded IRc7, all of which are obviously self-luminous at mid-infrared wavelengths and may be YSOs. None of these is a reflection nebula illuminated by a star located near radio source I, as was previously suggested. Other IRc sources are clearly reflection nebulae: IRc3 appears to be illuminated by IRc2-B or a combination of the IRc2 sources, and IRc4 and IRc5 appear to be illuminated by an unseen star in the vicinity of radio source I, or by Star n or IRc2-A. Trends in the magnetic field direction are inferred from the polarization of the 26 stars that are bright enough to be seen as NICMOS point sources. Their polarization ranges from N less than or equal to 1% (all stars with this low polarization are optically visible) to greater than 40%. The most polarized star has a polarization position angle different from its neighbors by approximately 40 degrees, but in agreement with the grain alignment inferred from millimeter polarization measurements of the cold dust cloud in the southern part of OMC-1. The polarization

  8. NEAR-INFRARED CIRCULAR AND LINEAR POLARIMETRY OF MONOCEROS R2

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Jungmi; Tamura, Motohide [Department of Astronomy, Graduate School of Science, The University of Tokyo, 113-0033 (Japan); Hough, James H. [University of Hertfordshire, Hatfield, Herts AL10 9AB (United Kingdom); Nagata, Tetsuya [Kyoto University, Sakyo-ku, Kyoto 606-8502 (Japan); Kusakabe, Nobuhiko [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan)

    2016-09-01

    We have conducted simultaneous JHK{sub s}-band imaging circular and linear polarimetry of the Monoceros R2 (Mon R2) cluster. We present results from deep and wide near-infrared linear polarimetry of the Mon R2 region. Prominent and extended polarized nebulosities over the Mon R2 field are revisited, and an infrared reflection nebula associated with the Mon R2 cluster and two local reflection nebulae, vdB 67 and vdB 69, is detected. We also present results from deep imaging circular polarimetry in the same region. For the first time, the observations show relatively high degrees of circular polarization (CP) in Mon R2, with as much as approximately 10% in the K{sub s} band. The maximum CP extent of a ring-like nebula around the Mon R2 cluster is approximately 0.60 pc, while that of a western nebula, around vdB 67, is approximately 0.24 pc. The extended size of the CP is larger than those seen in the Orion region around IRc2, while the maximum degree of CP of ∼10% is smaller than those of ∼17% seen in the Orion region. Nonetheless, both the CP size and degree of this region are among the largest in our infrared CP survey of star-forming regions. We have also investigated the time variability of the degree of the polarization of several infrared sources and found possible variations in three sources.

  9. Hyper-Spectral Imager in visible and near-infrared band for lunar ...

    Indian Academy of Sciences (India)

    e-mail: kiran@sac.isro.gov.in. India's first lunar mission, ... SMART-1 Infra-red Imager (SIR-2) (Nathues et al. 2000) and Moon ... 2. Operating principle. The instrument will map the lunar surface in push broom-mode from a polar orbit of 100km alti- tude. HySI will collect the Sun's reflected light from the Moon's surface through ...

  10. Robust design of subwavelength grating mirror for mid-infrared VCSEL application

    OpenAIRE

    Chevallier, Christyves; Genty, Frédéric; Fressengeas, Nicolas; Jacquet, Joel

    2011-01-01

    Oral Presentation - The final publication is available at http://ieeexplore.ieee.org/xpl/freeabs_all.jsp?arnumber=6041173; International audience; We present the design of a Si/Si3N4 subwavelength grating mirror optimized for an integration in mid-infrared VCSEL. The definition of a quality factor adapted to VCSEL requirements and maximized by an optimization algorithm allowed us to obtain a polarization selective and high reflectivity structure. The robustness with respect to fabrication err...

  11. Systematic Assessment of Attenuated Total Reflectance-Fourier Transforms Infrared Spectroscopy Coupled with Multivariate Analysis for Forensic Analysis of Black Ball-point Pen Inks

    International Nuclear Information System (INIS)

    Lee, L.C.; Mohamed Rozali Othman; Pua, H.; Lee, L.C.

    2012-01-01

    This manuscript aims to provide a new and non-destructive method for systematic analysis of inks on a questioned document. Ink samples were analyzed in situ on the paper substrate by micro-ATR-FTIR spectroscopy and the data obtained was processed and evaluated by a series of multivariate chemometrics. Absorbance value from wavenumbers of 2000-675 cm -1 were first processed by cluster analysis (CA), followed by principal component analysis (PCA) to form a set of new variables. Subsequently, the variables set was used for classification, differentiation and identification of 155 sample pens that comprise nine different brands. Results show that nine black ball-point pen brands could be classified into three main groups via discriminant analysis (DA). Differentiation analyses of nine different pen brands performed using one-way ANOVA indicated only two pairs of brands cannot be differentiated at 95 % confidence interval. Finally an identification flow chart was proposed to determine the brand of unknown pen inks. As a conclusion, the proposed method for extracting and creating a new variable set from infrared spectrum was evaluated to be satisfactory for systematic analysis of inks based on their infrared spectrum. (author)

  12. First Near-infrared Imaging Polarimetry of Young Stellar Objects in the Circinus Molecular Cloud

    Science.gov (United States)

    Kwon, Jungmi; Nakagawa, Takao; Tamura, Motohide; Hough, James H.; Choi, Minho; Kandori, Ryo; Nagata, Tetsuya; Kang, Miju

    2018-02-01

    We present the results of near-infrared (NIR) linear imaging polarimetry in the J, H, and K s bands of the low-mass star cluster-forming region in the Circinus Molecular Cloud Complex. Using aperture polarimetry of point-like sources, positive detection of 314, 421, and 164 sources in the J, H, and K s bands, respectively, was determined from among 749 sources whose photometric magnitudes were measured. For the source classification of the 133 point-like sources whose polarization could be measured in all 3 bands, a color–color diagram was used. While most of the NIR polarizations of point-like sources are well-aligned and can be explained by dichroic polarization produced by aligned interstellar dust grains in the cloud, 123 highly polarized sources have also been identified with some criteria. The projected direction on the sky of the magnetic field in the Cir-MMS region is indicated by the mean polarization position angles (70°) of the point-like sources in the observed region, corresponding to approximately 1.6× 1.6 pc2. In addition, the magnetic field direction is compared with the outflow orientations associated with Infrared Astronomy Satellite sources, in which two sources were found to be aligned with each other and one source was not. We also show prominent polarization nebulosities over the Cir-MMS region for the first time. Our polarization data have revealed one clear infrared reflection nebula (IRN) and several candidate IRNe in the Cir-MMS field. In addition, the illuminating sources of the IRNe are identified with near- and mid-infrared sources.

  13. Fast, Low-Cost and Non-Destructive Physico-Chemical Analysis of Virgin Olive Oils Using Near-Infrared Reflectance Spectroscopy

    Science.gov (United States)

    Garrido-Varo, Ana; Sánchez, María-Teresa; De la Haba, María-José; Torres, Irina; Pérez-Marín, Dolores

    2017-01-01

    Near-Infrared (NIR) Spectroscopy was used for the non-destructive assessment of physico-chemical quality parameters in olive oil. At the same time, the influence of the sample presentation mode (spinning versus static cup) was evaluated using two spectrophotometers with similar optical characteristics. A total of 478 olive oil samples were used to develop calibration models, testing various spectral signal pre-treatments. The models obtained by applying MPLS regression to spectroscopic data yielded promising results for olive oil quality measurements, particularly for acidity, the peroxide index and alkyl and ethyl ester content. The results obtained indicate that this non-invasive technology can be used successfully by the olive oil sector to categorize olive oils, to detect potential fraud and to provide consumers with more reliable information. Although both sample presentation modes yielded comparable results, equations constructed with samples scanned using the spinning mode provided greater predictive capacity. PMID:29144417

  14. Real-time feedback control using online attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy for continuous flow optimization and process knowledge.

    Science.gov (United States)

    Skilton, Ryan A; Parrott, Andrew J; George, Michael W; Poliakoff, Martyn; Bourne, Richard A

    2013-10-01

    The use of automated continuous flow reactors is described, with real-time online Fourier transform infrared spectroscopy (FT-IR) analysis to enable rapid optimization of reaction yield using a self-optimizing feedback algorithm. This technique has been applied to the solvent-free methylation of 1-pentanol with dimethyl carbonate using a γ-alumina catalyst. Calibration of the FT-IR signal was performed using gas chromatography to enable quantification of yield over a wide variety of flow rates and temperatures. The use of FT-IR as a real-time analytical technique resulted in an order of magnitude reduction in the time and materials required compared to previous studies. This permitted a wide exploration of the parameter space to provide process understanding and validation of the optimization algorithms.

  15. A Decrease in Spatially Resolved Near-Infrared Spectroscopy-Determined Frontal Lobe Tissue Oxygenation by Phenylephrine Reflects Reduced Skin Blood Flow

    DEFF Research Database (Denmark)

    Ogoh, Shigehiko; Sato, Kohei; Okazaki, Kazunobu

    2014-01-01

    O2. METHODS: We measured ScO2 and internal and external carotid as well as vertebral artery blood flow in 7 volunteers (25 [SD 4] years) by duplex ultrasonography during IV infusion of phenylephrine, together with middle cerebral artery mean blood velocity, forehead skin blood flow, and mean arterial...... blood pressure. RESULTS: During phenylephrine infusion, mean arterial blood pressure increased, while ScO2 decreased by -19% ± 3% (mean ± SE; P = 0.0005). External carotid artery (-27.5% ± 3.0%) and skin blood flow (-25.4% ± 7.8%) decreased in response to phenylephrine administration......BACKGROUND: Spatially resolved near-infrared spectroscopy-determined frontal lobe tissue oxygenation (ScO2) is reduced with administration of phenylephrine, while cerebral blood flow may remain unaffected. We hypothesized that extracranial vasoconstriction explains the effect of phenylephrine on Sc...

  16. Design and fabrication of anti-reflection coating on Gallium Phosphide, Zinc Selenide and Zinc Sulfide substrates for visible and infrared application

    Directory of Open Access Journals (Sweden)

    Mokrý P.

    2013-05-01

    Full Text Available Results of design and fabrication of a dual-band anti-reflection coating on a gallium phosphide (GaP, zinc selenide (ZnSe and zinc sulfide (ZnS substrates are presented. A multilayer stack structure of antireflection coatings made of zinc sulfide and yttrium fluoride (YF3 was theoretically designed for optical bands between 0.8 and 0.9 μm and between 9.5 and 10.5 μm. This stack was designed as efficient for these materials (GaP, ZnS, ZnSe together. Multilayer stack structure was deposited using thermal evaporation method. Theoretically predicted trans