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Sample records for polarization charging mechanism

  1. Preparation of electrospun polyacrylonitrile fibers containing only the polarization charges

    Science.gov (United States)

    Zhong, Qin; Yao, Yongyi; Guo, Xiaoming; Zhou, Tao; Xiang, Ruili

    2017-03-01

    In this paper, we report a simple method to separate immobile charges into polarization charges and trapped charges and successfully prepare electrospun polyacrylonitrile fibers only containing polarization charge. The amount of surface polarization charges and trapped charges were +5.34 nC/g and -2.98 nC/g, respectively. We also tried to explain the mechanism of formation and location of immobile charges by using a model of a parallel plate capacitor, and to track the route and location of charges. Additionally, we investigated the influence of residual solvent, a water bath and the temperature of the water bath on the immobile charges.

  2. Charge transport in non-polar and semi-polar III-V nitride heterostructures

    International Nuclear Information System (INIS)

    Konar, Aniruddha; Verma, Amit; Fang, Tian; Zhao, Pei; Jana, Raj; Jena, Debdeep

    2012-01-01

    Compared to the intense research focus on the optical properties, the transport properties in non-polar and semi-polar III-nitride semiconductors remain relatively unexplored to date. The purpose of this paper is to discuss charge-transport properties in non-polar and semi-polar orientations of GaN in a comparative fashion to what is known for transport in polar orientations. A comprehensive approach is adopted, starting from an investigation of the differences in the electronic bandstructure along different polar orientations of GaN. The polarization fields along various orientations are then discussed, followed by the low-field electron and hole mobilities. A number of scattering mechanisms that are specific to non-polar and semi-polar GaN heterostructures are identified, and their effects are evaluated. Many of these scattering mechanisms originate due to the coupling of polarization with disorder and defects in various incarnations depending on the crystal orientation. The effect of polarization orientation on carrier injection into quantum-well light-emitting diodes is discussed. This paper ends with a discussion of orientation-dependent high-field charge-transport properties including velocity saturation, instabilities and tunneling transport. Possible open problems and opportunities are also discussed. (paper)

  3. Polarization Charge Density in Strained Graphene

    Science.gov (United States)

    Wilson, Noah

    Graphene, the world's first truly two-dimensional material, is unique for having an electronic structure described by an effective Lorentz invariant theory. One important consequence is that the ratio or Coulomb energy to kinetic energy is a constant, depending only on conditions within the lattice rather than on the average charge density as in a typical Galilean invariant material. Given this unusual property, a natural question would be how do phenomena, such as screening of a Coulomb impurity, happen in graphene? Moreover, how does the addition of uniaxial strain enhance or diminish this behavior? Here I discuss our work to calculate the charge density distribution in a lattice of strained graphene under the effect of an external Coulomb impurity. Graphene can have its band structure significantly altered by the application of uniaxial strain. Two cases are here explored: relatively weak strain at some finite chemical potential, and extreme strain with zero chemical potential. In the first system, the strain induces elliptic Dirac cones, engendering some inherent directionality to graphene's electronic properties that did not exist before. This anisotropy manifests itself in the polarization function, and so too in the screening charge density. A finite chemical potential in this case is necessary for any screening to take place in graphene since, without it, there are no electron states near the Fermi level to polarize. Both in the strained and unstrained case, decaying oscillations known as Friedel oscillations are observed. The result of strain is a multifaceted anisotropy of the charge distribution: the amplitude, frequency, and the position of the first peak in the oscillations are each varied depending on the direction one observes. In the second system, extreme strain in graphene leads to a merging of Dirac cones, yielding a transition to a new energy spectrum. This band structure is unusual in that it becomes quadratic along the direction of strain

  4. Mechanical writing of ferroelectric polarization.

    Science.gov (United States)

    Lu, H; Bark, C-W; Esque de los Ojos, D; Alcala, J; Eom, C B; Catalan, G; Gruverman, A

    2012-04-06

    Ferroelectric materials are characterized by a permanent electric dipole that can be reversed through the application of an external voltage, but a strong intrinsic coupling between polarization and deformation also causes all ferroelectrics to be piezoelectric, leading to applications in sensors and high-displacement actuators. A less explored property is flexoelectricity, the coupling between polarization and a strain gradient. We demonstrate that the stress gradient generated by the tip of an atomic force microscope can mechanically switch the polarization in the nanoscale volume of a ferroelectric film. Pure mechanical force can therefore be used as a dynamic tool for polarization control and may enable applications in which memory bits are written mechanically and read electrically.

  5. Mechanical Writing of Ferroelectric Polarization

    Science.gov (United States)

    Lu, H.; Bark, C.-W.; Esque de los Ojos, D.; Alcala, J.; Eom, C. B.; Catalan, G.; Gruverman, A.

    2012-04-01

    Ferroelectric materials are characterized by a permanent electric dipole that can be reversed through the application of an external voltage, but a strong intrinsic coupling between polarization and deformation also causes all ferroelectrics to be piezoelectric, leading to applications in sensors and high-displacement actuators. A less explored property is flexoelectricity, the coupling between polarization and a strain gradient. We demonstrate that the stress gradient generated by the tip of an atomic force microscope can mechanically switch the polarization in the nanoscale volume of a ferroelectric film. Pure mechanical force can therefore be used as a dynamic tool for polarization control and may enable applications in which memory bits are written mechanically and read electrically.

  6. Direct Probing of Polarization Charge at Nanoscale Level

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Owoong [Sungkyunkwan Univ., Suwon (Republic of Korea). School of Advanced Materials and Engineering; Seol, Daehee [Sungkyunkwan Univ., Suwon (Republic of Korea). School of Advanced Materials and Engineering; Lee, Dongkyu [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Han, Hee [Korea Research Inst. of Standards and Science (KRISS), Daejeon (South Korea); Lindfors-Vrejoiu, Ionela [Univ. of Cologne (Germany). Physics Inst.; Lee, Woo [Korea Research Inst. of Standards and Science (KRISS), Daejeon (South Korea); Jesse, Stephen [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences; Lee, Ho Nyung [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Kalinin, Sergei V. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences; Alexe, Marin [Univ. of Warwick, Coventry (United Kingdom). Dept. of Physics; Kim, Yunseok [Sungkyunkwan Univ., Suwon (Republic of Korea). School of Advanced Materials and Engineering

    2017-11-14

    Ferroelectric materials possess spontaneous polarization that can be used for multiple applications. Owing to a long-term development of reducing the sizes of devices, the preparation of ferroelectric materials and devices is entering the nanometer-scale regime. In order to evaluate the ferroelectricity, there is a need to investigate the polarization charge at the nanoscale. Nonetheless, it is generally accepted that the detection of polarization charges using a conventional conductive atomic force microscopy (CAFM) without a top electrode is not feasible because the nanometer-scale radius of an atomic force microscopy (AFM) tip yields a very low signal-to-noise ratio. But, the detection is unrelated to the radius of an AFM tip and, in fact, a matter of the switched area. In this work, the direct probing of the polarization charge at the nanoscale is demonstrated using the positive-up-negative-down method based on the conventional CAFM approach without additional corrections or circuits to reduce the parasitic capacitance. The polarization charge densities of 73.7 and 119.0 µC cm-2 are successfully probed in ferroelectric nanocapacitors and thin films, respectively. The results we obtained show the feasibility of the evaluation of polarization charge at the nanoscale and provide a new guideline for evaluating the ferroelectricity at the nanoscale.

  7. Effective Topological Charge Cancelation Mechanism.

    Science.gov (United States)

    Mesarec, Luka; Góźdź, Wojciech; Iglič, Aleš; Kralj, Samo

    2016-06-01

    Topological defects (TDs) appear almost unavoidably in continuous symmetry breaking phase transitions. The topological origin makes their key features independent of systems' microscopic details; therefore TDs display many universalities. Because of their strong impact on numerous material properties and their significant role in several technological applications it is of strong interest to find simple and robust mechanisms controlling the positioning and local number of TDs. We present a numerical study of TDs within effectively two dimensional closed soft films exhibiting in-plane orientational ordering. Popular examples of such class of systems are liquid crystalline shells and various biological membranes. We introduce the Effective Topological Charge Cancellation mechanism controlling localised positional assembling tendency of TDs and the formation of pairs {defect, antidefect} on curved surfaces and/or presence of relevant "impurities" (e.g. nanoparticles). For this purpose, we define an effective topological charge Δmeff consisting of real, virtual and smeared curvature topological charges within a surface patch Δς identified by the typical spatially averaged local Gaussian curvature K. We demonstrate a strong tendency enforcing Δmeff → 0 on surfaces composed of Δς exhibiting significantly different values of spatially averaged K. For Δmeff ≠ 0 we estimate a critical depinning threshold to form pairs {defect, antidefect} using the electrostatic analogy.

  8. Magnetic Field Generation through Angular Momentum Exchange between Circularly Polarized Radiation and Charged Particles

    CERN Document Server

    Shvets, G

    2002-01-01

    The interaction between circularly polarized (CP) radiation and charged particles can lead to generation of magnetic field through an inverse Faraday effect. The spin of the circularly polarized electromagnetic wave can be converted into the angular momentum of the charged particles so long as there is dissipation. We demonstrate this by considering two mechanisms of angular momentum absorption relevant for laser-plasma interactions: electron-ion collisions and ionization. The precise dissipative mechanism, however, plays a role in determining the efficiency of the magnetic field generation.

  9. Magnetic Field Generation through Angular Momentum Exchange between Circularly Polarized Radiation and Charged Particles

    International Nuclear Information System (INIS)

    G. Shvets; N.J. Fisch; J.-M. Rax

    2002-01-01

    The interaction between circularly polarized (CP) radiation and charged particles can lead to generation of magnetic field through an inverse Faraday effect. The spin of the circularly polarized electromagnetic wave can be converted into the angular momentum of the charged particles so long as there is dissipation. We demonstrate this by considering two mechanisms of angular momentum absorption relevant for laser-plasma interactions: electron-ion collisions and ionization. The precise dissipative mechanism, however, plays a role in determining the efficiency of the magnetic field generation

  10. Polarization and charge-transfer effects in aqueous solution via ab initio QM/MM simulations.

    Science.gov (United States)

    Mo, Yirong; Gao, Jiali

    2006-02-23

    Combined ab initio quantum mechanical and molecular mechanical (QM/MM) simulations coupled with the block-localized wave function energy decomposition (BLW-ED) method have been conducted to study the solvation of two prototypical ionic systems, acetate and methylammonium ions in aqueous solution. Calculations reveal that the electronic polarization between the targeted solutes and water is the primary many-body effect, whereas the charge-transfer term only makes a small fraction of the total solute-solvent interaction energy. In particular, the polarization effect is dominated by the solvent (water) polarization.

  11. Numerical modelling of electrochemical polarization around charged metallic particles

    Science.gov (United States)

    Bücker, Matthias; Undorf, Sabine; Flores Orozco, Adrián; Kemna, Andreas

    2017-04-01

    We extend an existing analytical model and carry out numerical simulations to study the polarization process around charged metallic particles immersed in an electrolyte solution. Electro-migration and diffusion processes in the electrolyte are described by the Poisson-Nernst-Planck system of partial differential equations. To model the surface charge density, we consider a time- and frequency-invariant electric potential at the particle surface, which leads to the build-up of a static electrical double layer (EDL). Upon excitation by an external electric field at low frequencies, we observe the superposition of two polarization processes. On the one hand, the induced dipole moment on the metallic particle leads to the accumulation of opposite charges in the electrolyte. This charge polarization corresponds to the long-known response of uncharged metallic particles. On the other hand, the unequal cation and anion concentrations in the EDL give rise to a salinity gradient between the two opposite sides of the metallic particle. The resulting concentration polarization enhances the magnitude of the overall polarization response. Furthermore, we use our numerical model to study the effect of relevant model parameters such as surface charge density and ionic strength of the electrolyte on the resulting spectra of the effective conductivity of the composite model system. Our results do not only give interesting new insight into the time-harmonic variation of electric potential and ion concentrations around charged metallic particle. They are also able to reduce incongruities between earlier model predictions and geophysical field and laboratory measurements. Our model thereby improves the general understanding of IP signatures of metallic particles and represents the next step towards a quantitative interpretation of IP imaging results. Part of this research is funded by the Austrian Federal Ministry of Science, Research and Economy under the Raw Materials Initiative.

  12. Understanding the effects of electronic polarization and delocalization on charge-transport levels in oligoacene systems

    KAUST Repository

    Sutton, Christopher

    2017-06-13

    Electronic polarization and charge delocalization are important aspects that affect the charge-transport levels in organic materials. Here, using a quantum mechanical/ embedded-charge (QM/EC) approach based on a combination of the long-range corrected omega B97X-D exchange-correlation functional (QM) and charge model 5 (CM5) point-charge model (EC), we evaluate the vertical detachment energies and polarization energies of various sizes of crystalline and amorphous anionic oligoacene clusters. Our results indicate that QM/EC calculations yield vertical detachment energies and polarization energies that compare well with the experimental values obtained from ultraviolet photoemission spectroscopy measurements. In order to understand the effect of charge delocalization on the transport levels, we considered crystalline naphthalene systems with QM regions including one or five-molecules. The results for these systems show that the delocalization and polarization effects are additive; therefore, allowing for electron delocalization by increasing the size of the QM region leads to the additional stabilization of the transport levels. Published by AIP Publishing.

  13. Charged questions concerning noctilucent clouds and polar mesospheric summer echoes

    Science.gov (United States)

    Gumbel, J.

    2012-12-01

    Noctilucent clouds (NLC) and polar mesosphere summer echoes (PMSE) are prominent phenomena related to ice layers in the Earth's atmosphere at 80-90 km. These phenomena have been recognized as important tracers for interactions and variability in this part of the atmosphere. In order to draw proper conclusions from global observations, a better understanding of the microphysics of mesospheric ice grains is needed. This presentation provides an overview of current research topics concerning NLC and PMSE, with an emphasis is on charging pocesses. NLC and PMSE coincide with the ionospheric D-region, thus constituting a weakly ionized dusty plasma. Prominent open questions concern the efficiency of charge capture and photoionization, the role of charges in ice nucleation, charge diffusion, and interactions between ice and meteoric material.

  14. Switching of charged inverse micelles in non-polar liquids.

    Science.gov (United States)

    Prasad, Manoj; Beunis, Filip; Neyts, Kristiaan; Strubbe, Filip

    2015-11-15

    The electrodynamics of micellar ions in nonpolar liquids are well understood for the case that a voltage is applied or switched off. In this work, the electrodynamics of charged inverse micelles (CIMs) are studied when the applied voltage is switched to the opposite polarity, which is relevant for applications such as electrophoretic displays and liquid toner printing. Transient current measurements are used to characterize the switching of CIMs formed in a solution of surfactant polyisobutylene succinimide in n-dodecane. For reverse voltages with amplitude below 10V the measurements are in good agreement with a drift and diffusion model, confirming the established understanding of CIMs in nonpolar liquids. When the charge content is high, the reversal current shows a characteristic peak which is explained on the basis of dynamic space-charge effects. However, for reverse voltages larger than 10V, the transient currents are influenced by electrohydrodynamic flow in the liquid causing the CIMs to switch faster than predicted by the model. The occurrence of electrohydrodynamic flow is verified by optical tracking of tracer particles. Also, when the polarizing voltage is applied for longer times, an additional current peak emerges which is due to the accumulation of newly generated charges at the electrodes. Copyright © 2015 Elsevier Inc. All rights reserved.

  15. Metallicity at interphase boundaries due to polar catastrophe induced by charge density discontinuity

    KAUST Repository

    Albar, Arwa

    2018-02-09

    The electronic properties of interphase boundaries are of basic importance for most materials, particularly when those properties deviate strongly from the bulk behavior. We introduce a mechanism that can result in metallicity at stoichiometric interphase boundaries between semiconductors based on the idea of polar catastrophe, which is usually considered only in the context of heterostructures. To this end, we perform ab initio calculations within density functional theory to investigate the electronic states at stoichiometric SnO/SnO2 (110) interphase boundaries. In this system, one would not expect polar catastrophe to have a role according to state-of-the-art theory because the interface lacks formal charge discontinuity. However, we observe the formation of a hole gas between the semiconductors SnO and SnO2. To explain these findings, we provide a generalized theory based on the idea that the charge density discontinuity between SnO and SnO2, a consequence of lattice mismatch, drives a polar catastrophe scenario. As a result, SnO/SnO2 (110) interphase boundaries can develop metallicity depending on the grain size. The concept of metallicity due to polar catastrophe induced by charge density discontinuity is of general validity and applies to many interphase boundaries with lattice mismatch.

  16. Quantum mechanics of charged particle beam optics

    CERN Document Server

    Khan, Sameen Ahmed

    2018-01-01

    Theory of charged particle beam optics is basic to the design and working of charged particle beam devices from electron microscopes to accelerator machines. Traditionally, the optical elements of the devices are designed and operated based on classical mechanics and classical electromagnetism, and only certain specific quantum mechanical aspects are dealt with separately using quantum theory. This book provides a systematic approach to quantum theory of charged particle beam optics, particularly in the high energy cases such as accelerators or high energy electron microscopy.

  17. Mechanism of stimulated radiation by charged particles

    International Nuclear Information System (INIS)

    Zachary, W.W.

    1979-01-01

    We have studied the mechanism for radiation by charged particles called stimulated electromagnetic shock radiation (SESR) by Schneider and Spitzer caused by the interaction between a relativistic charged particle and an externally applied electromagnetic plane wave in a dielectric. The present theory predicts that the SESR effect is large when the frequency of the plane wave lies in the microwave region but is small at higher frequencies for plane-wave field strengths smaller than the breakdown field of the dielectric

  18. Concentration polarization and desalination in nanochannels: Effect of surface charge dynamics

    Science.gov (United States)

    Andersen, Mathias B.; Bruus, Henrik; Mani, Ali; Bazant, Martin Z.

    2011-11-01

    Mani, Zangle, and Santiago (Langmuir, 25, 3898-3916) have shown that at microchannel-nanochannel junctions the coupled effect of concentration polarization and surface conduction can lead to long range propagation of bulk ion-depletion shocks. Essential for this phenomena is the surface charge which for many materials depends on both the concentration and the pH of the local bulk electrolyte. Standard models predict that the surface charge decreases with decreasing concentration leading to the contradictory expectation that there is little or no surface charge in the depleted region and hence no mechanism to sustain long range propagation of desalination shocks. We show that this simple prediction fails to take into account axial transport terms. As such, we couple a surface charge model with the Poisson-Nernst-Planck equations for electric potential and ionic species combined with the Navier-Stokes and continuity equations for fluid velocity. Motivated by experimental work we consider steady-state solutions at the dead end of a nanochannel against a membrane, a scenario where especially space charge and electroosmotic flow are important. Our results suggest that the surface charge density remains finite and does not vanish, and even grows, as the depletion front propagates through the channel.

  19. Polarization mechanism and ferroelectric instability in KH2PO4

    International Nuclear Information System (INIS)

    Koval, S.; Migoni, R.L.; Kohanoff, J.; Bussmann-Holder, A.

    2000-11-01

    The polarization mechanism and the origin of ferroelectricity in KH 2 PO 4 (KDP) are studied by first-principles electronic structure calculations. In the low-temperature phase, the collective off-center ordering of the protons is accompanied by an electronic charge delocalization from the near and localization at the far oxygen within the O-H...0 bonds. Electrostatic forces, then, push the K + ions towards off-center positions, and induce a macroscopic polarization. The analysis of the correlation between different geometrical and electronic quantities, in connection with experimental data, supports the idea that the role of tunnelling in isotopic effects is irrelevant. Instead, geometrical quantum effects appear to play a central role. (author)

  20. Production of Polarized Ions with Nearly Resonant Charge-Exchange Collisions in Plasma

    Science.gov (United States)

    Belov, A. S.

    2008-02-01

    Review of results of development of polarized ion sources with nearly resonant charge-exchange plasma ionizer is presented. Pulsed beams of polarized protons with peak intensity up to 11 mA and polarization of 80% and polarized negative hydrogen ions with peak current of 4 mA and polarization of 91% have been obtained. Polarized deuterons, negative deuterium ions and 3He++ ions can be produced by this method as well. A study of a pulsed polarized atomic hydrogen beam has been performed. It was found that intensity of the pulsed atomic hydrogen beam is limited by a beam-skimmer interference and by noncomplete cooling of hydrogen atoms.

  1. Production of Polarized Ions with Nearly Resonant Charge-Exchange Collisions in Plasma

    International Nuclear Information System (INIS)

    Belov, A. S.

    2008-01-01

    Review of results of development of polarized ion sources with nearly resonant charge-exchange plasma ionizer is presented. Pulsed beams of polarized protons with peak intensity up to 11 mA and polarization of 80% and polarized negative hydrogen ions with peak current of 4 mA and polarization of 91% have been obtained. Polarized deuterons, negative deuterium ions and 3 He ++ ions can be produced by this method as well. A study of a pulsed polarized atomic hydrogen beam has been performed. It was found that intensity of the pulsed atomic hydrogen beam is limited by a beam-skimmer interference and by noncomplete cooling of hydrogen atoms

  2. Polarization and charge transfer in the hydration of chloride ions

    International Nuclear Information System (INIS)

    Zhao Zhen; Rogers, David M.; Beck, Thomas L.

    2010-01-01

    A theoretical study of the structural and electronic properties of the chloride ion and water molecules in the first hydration shell is presented. The calculations are performed on an ensemble of configurations obtained from molecular dynamics simulations of a single chloride ion in bulk water. The simulations utilize the polarizable AMOEBA force field for trajectory generation and MP2-level calculations are performed to examine the electronic structure properties of the ions and surrounding waters in the external field of more distant waters. The ChelpG method is employed to explore the effective charges and dipoles on the chloride ions and first-shell waters. The quantum theory of atoms in molecules (QTAIM) is further utilized to examine charge transfer from the anion to surrounding water molecules. The clusters extracted from the AMOEBA simulations exhibit high probabilities of anisotropic solvation for chloride ions in bulk water. From the QTAIM analysis, 0.2 elementary charges are transferred from the ion to the first-shell water molecules. The default AMOEBA model overestimates the average dipole moment magnitude of the ion compared to the quantum mechanical value. The average magnitude of the dipole moment of the water molecules in the first shell treated at the MP2-level, with the more distant waters handled with an AMOEBA effective charge model, is 2.67 D. This value is close to the AMOEBA result for first-shell waters (2.72 D) and is slightly reduced from the bulk AMOEBA value (2.78 D). The magnitude of the dipole moment of the water molecules in the first solvation shell is most strongly affected by the local water-water interactions and hydrogen bonds with the second solvation shell, rather than by interactions with the ion.

  3. Quantum mechanical force field for water with explicit electronic polarization.

    Science.gov (United States)

    Han, Jaebeom; Mazack, Michael J M; Zhang, Peng; Truhlar, Donald G; Gao, Jiali

    2013-08-07

    A quantum mechanical force field (QMFF) for water is described. Unlike traditional approaches that use quantum mechanical results and experimental data to parameterize empirical potential energy functions, the present QMFF uses a quantum mechanical framework to represent intramolecular and intermolecular interactions in an entire condensed-phase system. In particular, the internal energy terms used in molecular mechanics are replaced by a quantum mechanical formalism that naturally includes electronic polarization due to intermolecular interactions and its effects on the force constants of the intramolecular force field. As a quantum mechanical force field, both intermolecular interactions and the Hamiltonian describing the individual molecular fragments can be parameterized to strive for accuracy and computational efficiency. In this work, we introduce a polarizable molecular orbital model Hamiltonian for water and for oxygen- and hydrogen-containing compounds, whereas the electrostatic potential responsible for intermolecular interactions in the liquid and in solution is modeled by a three-point charge representation that realistically reproduces the total molecular dipole moment and the local hybridization contributions. The present QMFF for water, which is called the XP3P (explicit polarization with three-point-charge potential) model, is suitable for modeling both gas-phase clusters and liquid water. The paper demonstrates the performance of the XP3P model for water and proton clusters and the properties of the pure liquid from about 900 × 10(6) self-consistent-field calculations on a periodic system consisting of 267 water molecules. The unusual dipole derivative behavior of water, which is incorrectly modeled in molecular mechanics, is naturally reproduced as a result of an electronic structural treatment of chemical bonding by XP3P. We anticipate that the XP3P model will be useful for studying proton transport in solution and solid phases as well as across

  4. Carrier polarity engineering in carbon nanotube field-effect transistors by induced charges in polymer insulator

    Science.gov (United States)

    Aikawa, Shinya; Kim, Sungjin; Thurakitseree, Theerapol; Einarsson, Erik; Inoue, Taiki; Chiashi, Shohei; Tsukagoshi, Kazuhito; Maruyama, Shigeo

    2018-01-01

    We present that the electrical conduction type in carbon nanotube field-effect transistors (CNT-FETs) can be converted by induced charges in a polyvinyl alcohol (PVA) insulator. When the CNT channels are covered with pure PVA, the FET characteristics clearly change from unipolar p-type to ambipolar. The addition of ammonium ions (NH4+) in the PVA leads to further conversion to unipolar n-type conduction. The capacitance - voltage characteristics indicate that a high density of positive charges is induced at the PVA/SiO2 interface and within the bulk PVA. Electrons are electrostatically accumulated in the CNT channels due to the presence of the positive charges, and thus, stable n-type conduction of PVA-coated CNT-FETs is observed, even under ambient conditions. The mechanism for conversion of the conduction type is considered to be electrostatic doping due to the large amount of positive charges in the PVA. A blue-shift of the Raman G-band peak was observed for CNTs coated with NH4+-doped PVA, which corresponds to unipolar n-type CNT-FET behavior. These results confirm that carrier polarity engineering in CNT-FETs can be achieved with a charged PVA passivation layer.

  5. Modeling charge polarization voltage for large lithium-ion batteries in electric vehicles

    Directory of Open Access Journals (Sweden)

    Yan Jiang

    2013-06-01

    Full Text Available Purpose: Polarization voltage of the lithium-ion battery is an important parameter that has direct influence on battery performance. The paper aims to analyze the impedance characteristics of the lithium-ion battery based on EIS data. Design/methodology/approach: The effects of currents, initial SOC of the battery on charge polarization voltage are investigated, which is approximately linear function of charge current. The change of charge polarization voltage is also analyzed with the gradient analytical method in the SOC domain. The charge polarization model with two RC networks is presented, and parts of model parameters like Ohmic resistance and charge transfer impedance are estimated by both EIS method and battery constant current testing method. Findings: This paper reveals that the Ohmic resistance accounts for much contribution to battery total polarization compared to charge transfer impedance. Practical implications: Experimental results demonstrate the efficacy of the model with the proposed identification method, which provides the foundation for battery charging optimization. Originality/value: The paper analyzed the impedance characteristics of the lithium-ion battery based on EIS data, presented a charge polarization model with two RC networks, and estimated parameters like Ohmic resistance and charge transfer impedance.

  6. Polarized parton distributions from charged-current deep-inelastic scattering and future neutrino factories

    CERN Document Server

    Forte, Stefano; Ridolfi, G; Forte, Stefano; Mangano, Michelangelo L.; Ridolfi, Giovanni

    2001-01-01

    We discuss the determination of polarized parton distributions from charged-current deep-inelastic scattering experiments. We summarize the next-to-leading order treatment of charged-current polarized structure functions, their relation to polarized parton distributions and scale dependence, and discuss their description by means of a next-to-leading order evolution code. We discuss current theoretical expectations and positivity constraints on the unmeasured C-odd combinations Delta q-Delta qbar of polarized quark distributions, and their determination in charged-current deep-inelastic scattering experiments. We give estimates of the expected errors on charged-current structure functions at a future neutrino factory, and perform a study of the accuracy in the determination of polarized parton distributions that would be possible at such a facility. We show that these measurements have the potential to distinguish between different theoretical scenarios for the proton spin structure.

  7. Polarized parton distributions from charged-current deep-inelastic scattering and future neutrino factories

    International Nuclear Information System (INIS)

    Forte, Stefano; Mangano, Michelangelo L.; Ridolfi, Giovanni

    2001-01-01

    We discuss the determination of polarized parton distributions from charged-current deep-inelastic scattering experiments. We summarize the next-to-leading-order treatment of charged-current polarized structure functions, their relation to polarized parton distributions and scale dependence, and discuss their description by means of a next-to-leading-order evolution code. We discuss current theoretical expectations and positivity constraints on the unmeasured C-odd combinations Δq-Δq-bar of polarized quark distributions, and their determination in charged-current deep-inelastic scattering experiments. We give estimates of the expected errors on charged-current structure functions at a future neutrino factory, and perform a study of the accuracy in the determination of polarized parton distributions that would be possible at such a facility. We show that these measurements have the potential to distinguish between different theoretical scenarios for the proton spin structure

  8. Solvation thermodynamics and heat capacity of polar and charged solutes in water

    Science.gov (United States)

    Sedlmeier, Felix; Netz, Roland R.

    2013-03-01

    The solvation thermodynamics and in particular the solvation heat capacity of polar and charged solutes in water is studied using atomistic molecular dynamics simulations. As ionic solutes we consider a F- and a Na+ ion, as an example for a polar molecule with vanishing net charge we take a SPC/E water molecule. The partial charges of all three solutes are varied in a wide range by a scaling factor. Using a recently introduced method for the accurate determination of the solvation free energy of polar solutes, we determine the free energy, entropy, enthalpy, and heat capacity of the three different solutes as a function of temperature and partial solute charge. We find that the sum of the solvation heat capacities of the Na+ and F- ions is negative, in agreement with experimental observations, but our results uncover a pronounced difference in the heat capacity between positively and negatively charged groups. While the solvation heat capacity ΔCp stays positive and even increases slightly upon charging the Na+ ion, it decreases upon charging the F- ion and becomes negative beyond an ion charge of q = -0.3e. On the other hand, the heat capacity of the overall charge-neutral polar solute derived from a SPC/E water molecule is positive for all charge scaling factors considered by us. This means that the heat capacity of a wide class of polar solutes with vanishing net charge is positive. The common ascription of negative heat capacities to polar chemical groups might arise from the neglect of non-additive interaction effects between polar and apolar groups. The reason behind this non-additivity is suggested to be related to the second solvation shell that significantly affects the solvation thermodynamics and due to its large spatial extent induces quite long-ranged interactions between solvated molecular parts and groups.

  9. Morphology-dependent space charge polarization and dielectric relaxation of CdO nanomorphotypes

    Directory of Open Access Journals (Sweden)

    Paulose Thomas

    2016-12-01

    Full Text Available A versatile approach signifying the morphology-dependent dielectric polarization and relaxation mechanisms of cadmium oxide (CdO nanosphere, nanoflakes and nanoparallelepiped morphotypes as a function of frequency and temperature is presented. Variation of dielectric property is observed due to the changes of space charge/interfacial polarization resulting from the variations of surface to volume ratio of nanomorphology. Accordingly, colossal dielectric constant value has been observed in CdO nanosphere having larger surface to volume ratio. The order of dielectric constant (dc values observed for the present nanomorphologies is: dc of sphere > dc of flakes > dc of parallelepiped resembles the order of surface to volume ratios of the present morphologies respectively. The experimental data of complex impedance values are numerically fitted using theoretical models which provide the information of role of grain resistance on dielectric polarization and Cole–Cole type mechanism of dielectric relaxation process. The activation energies for electron transport are found to be 0.087eV for spheres, 0.074eV for flakes and 0.067 for parallelepiped nanomorphotypes of CdO. The dielectric and impedance spectroscopic analysis of the present material opens up wide scope for morphology-dependent tuning of nanomaterials for electrical applications.

  10. Polarization of X rays of multiply charged ions in dense high-temperature plasma

    NARCIS (Netherlands)

    Baronova, EO; Dolgov, AN; Yakubovskii, LK

    2004-01-01

    The development of a method for studying the features of X-ray emission by multiply charged ions in a dense hot plasma is considered. These features are determined by the radiation polarization phenomenon.

  11. Extreme Spacecraft Charging in Polar Low Earth Orbit

    Science.gov (United States)

    Colson, Andrew D.; Minow, Joseph I.; Parker, L. Neergaard

    2012-01-01

    Spacecraft in low altitude, high inclination (including sun -synchronous) orbits are widely used for remote sensing of the Earth fs land surface and oceans, monitoring weather and climate, communications, scientific studies of the upper atmosphere and ionosphere, and a variety of other scientific, commercial, and military applications. These systems episodically charge to frame potentials in the kilovolt range when exposed to space weather environments characterized by a high flux of energetic (approx.10 fs kilovolt) electrons in regions of low background plasma density. Auroral charging conditions are similar in some ways to the space weather conditions in geostationary orbit responsible for spacecraft charging to kilovolt levels. We first review the physics of space environment interactions with spacecraft materials that control auroral charging rates and the anticipated maximum potentials that should be observed on spacecraft surfaces during disturbed space weather conditions. We then describe how the theoretical values compare to the observational history of extreme charging in auroral environments. Finally, a set of extreme DMSP charging events are described varying in maximum negative frame potential from approx.0.6 kV to approx.2 kV, focusing on the characteristics of the charging events that are of importance both to the space system designer and to spacecraft operators. The goal of the presentation is to bridge the gap between scientific studies of auroral charging and the need for engineering teams to understand how space weather impacts both spacecraft design and operations for vehicles on orbital trajectories that traverse auroral charging environments.

  12. Charge transport by inverse micelles in non-polar media

    Science.gov (United States)

    Strubbe, Filip; Neyts, Kristiaan

    2017-11-01

    Charged inverse micelles play an important role in the electrical charging and the electrodynamics of nonpolar colloidal dispersions relevant for applications such as electronic ink displays and liquid toner printing. This review examines the properties and the behavior of charged inverse micelles in microscale devices in the absence of colloidal particles. It is discussed how charge in nonpolar liquids is stabilized in inverse micelles and how conductivity depends on the inverse micelle size, water content and ionic impurities. Frequently used nonpolar surfactant systems are investigated with emphasis on aerosol-OT (AOT) and poly-isobutylene succinimide (PIBS) in dodecane. Charge generation in the bulk by disproportionation is studied from measurements of conductivity as a function of surfactant concentration and from generation currents in quasi steady-state. When a potential difference is applied, the steady-state situation can show electric field screening or complete charge separation. Different regimes of charge transport are identified when a voltage step is applied. It is shown how the transient and steady-state currents depend on the rate of bulk generation, on insulating layers and on the sticking or non-sticking behavior of charged inverse micelles at interfaces. For the cases of AOT and PIBS in dodecane, the magnitude of the generation rate and the type of interaction at the interface are very different.

  13. Asymmetry in ternary fission induced by polarized neutrons and fission mechanism

    International Nuclear Information System (INIS)

    Bunakov, V.E.; Gennenvajn, F.; Dzhessinger, P.; Mutterer, M.; Petrov, G.A.

    2003-01-01

    The results of measuring the P-odd, P-even (right-left) and T-odd asymmetries of the charged particles emission in the double and ternary fission, induced by the polarized neutrons, are considered. It is shown, what kind of information on the mechanism of the ternary nuclear fission may be obtained from the theoretical analysis of these data [ru

  14. π--induced single charge exchange on polarized 3He

    International Nuclear Information System (INIS)

    Zhao, Q.; Burleson, S.; Blanchard, T.

    1995-01-01

    Asymmetries, A y , for the (π - ,π 0 ) reaction on polarized 3 He were measured using the pion beam of the P3W channel at LAMPF. The π 0 were detected with the new Neutral Meson Spectrometer (NMS) in coincidence with recoiling tritons. The recoil detector consisted of scintillation-counter telescopes and a wire chamber that provided energy-loss and direction information, respectively. The polarized gaseous 3 He target developed at TRIUMF was modified and run with the use of two diode lasers. Polarizations were typically 50%. The A y taken at T π = 200 MeV between 60 and 105 degrees were found to be strongly angle-dependent. The results will be compared with the theoretical predictions

  15. Symmetry breaking signaling mechanisms during cell polarization

    NARCIS (Netherlands)

    Bruurs, LJM

    2017-01-01

    Breaking of cellular symmetry in order to establish an apico-basal polarity axis initiates de novo formation of cell polarity. However, symmetry breaking provides a formidable challenge from a signaling perspective, because by definition no spatial cues are present to instruct axis establishment.

  16. Exploring Electric Polarization Mechanisms in Multiferroic Oxides

    Energy Technology Data Exchange (ETDEWEB)

    Tyson, Trevor A. [New Jersey Institute of Technology (NJIT), Newark, NJ (United States)

    2017-01-24

    Multiferroic oxides are a class of systems which exhibit coupling between the electrical polarization and the magnetization. These materials show promise to lead to devices in which ferromagnetic memory can be written with magnetic fields or magnetic bits can be written by an electric field. The work conducted in our research focuses on single phase materials. We studied the detailed coupling of the spin and lattice correlations in these systems. In the first phase of the proposal, we explored the complex spin spiral systems and low temperature behavior of hexagonal layered REMnO3 (RE= rare earth, Y and Sc) system following the detailed structural changes which occurred on crossing into the magnetic states. The techniques were applied to other layered materials such as superconductors and thermoelectric where the same layered motif exists. The second phase of the proposal focused on understanding the mechanisms involved in the onset high temperature ferroelectricity ion hexagonal REMnO3 and at low temperature in E-Type magnetic ordered perovskite REMnO3. We wsynthesized preovskite small A site multiferroics by high pressure and high temperature methods. Detailed measurement of the structural properties and dynamics were conducted over a range of length scales from atomic to mesoscopic scale using, x-ray absorption spectroscopy, x-ray diffuse scattering, x-ray and neutron pair distribution analysis and high resolution x-ray diffraction. Changes in vibration modes which occur with the onset of polarization were probed with temperature and pressure dependent infrared absorption spectroscopy. In addition the orthorhombic system (small radius RE ions) which is believed to exhibit electronically driven ferroelectricity and is also not understood was examined. The multiple length scale synchrotron based measurements may assist in developing more detailed models of these materials and possibly lead to device applications. The experimental

  17. Study of proton polarization in charge exchange process on optically oriented sodium atoms

    International Nuclear Information System (INIS)

    Zelenskij, A.N.; Kokhanovskij, S.A.

    1984-01-01

    Using high-power adjustable dye lasers for electron spin orientation in a charge-exchange target enables to significantly increase the proton polarization efficiency. A device is described that permits to avoid growth of the polarized proton beam emittance in a charge-exchange process in a strong magnetic field. The devise main feature is the use of an intensive source of neutral hydrogen atoms and the presence of a helium additional charge-exchange target which actualy is a proton ''source''. The helium charge-exchange cell is placed in the same magnetic field of a solenoid where a cell with oriented sodium is placed, a polarized electron being captured by a proton in the latter cell. In this case the beam at the solenoid inlet and outlet is in a neutral state; emittance growth related to the effect of end magnetic fields is not observed. The device after all prouduces polarized protons, their polarization degree is measured and the effect of various factors on polarization degree is studied. The description of the laser source and laser system is given. Measurement results have shown the beam intensity of neutral 7 keV atoms which passed through a polarizer to be 2 mA. The proton current doesn't depend. On the beeld fin the region of chrge exchange for the 8 kGs magnetic field. The degree of sodium polarization was 80% and polarized proton current approximately 70 μA at a temperature of the polarized sodium cell corresponding to the density of sodium vapar approximately 3x10 13 at/cm 2

  18. Direct visualization of polarization reversal of organic ferroelectric memory transistor by using charge modulated reflectance imaging

    Science.gov (United States)

    Otsuka, Takako; Taguchi, Dai; Manaka, Takaaki; Iwamoto, Mitsumasa

    2017-11-01

    By using the charge modulated reflectance (CMR) imaging technique, charge distribution in the pentacene organic field-effect transistor (OFET) with a ferroelectric gate insulator [P(VDF-TrFE)] was investigated in terms of polarization reversal of the P(VDF-TrFE) layer. We studied the polarization reversal process and the carrier spreading process in the OFET channel. The I-V measurement showed a hysteresis behavior caused by the spontaneous polarization of P(VDF-TrFE), but the hysteresis I-V curve changes depending on the applied drain bias, possibly due to the gradual shift of the polarization reversal position in the OFET channel. CMR imaging visualized the gradual shift of the polarization reversal position and showed that the electrostatic field formed by the polarization of P(VDF-TrFE) contributes to hole and electron injection into the pentacene layer and the carrier distribution is significantly dependent on the direction of the polarization. The polarization reversal position in the channel region is governed by the electrostatic potential, and it happens where the potential reaches the coercive voltage of P(VDF-TrFE). The transmission line model developed on the basis of the Maxwell-Wagner effect element analysis well accounts for this polarization reversal process in the OFET channel.

  19. Multiply charged negative ions of hydrogen in linearly polarized laser fields

    International Nuclear Information System (INIS)

    van Duijn, E.; Muller, H.G.

    1997-01-01

    Motivated by the prediction of the appearance of atomic multiply charged negative ions (AMCNI) of hydrogen, induced by a linearly polarized laser field, we present an analytical quantum mechanical treatment of the appearance and structure of AMCNI in a linearly polarized field, based on high-frequency Floquet theory (HFFT). For the simplest AMCNI of hydrogen, H 2- and H 3- , the values of α 0 at which the first bound state appears are α 0 =1.62x10 2 and α 0 =1.02x10 4 , where α 0 =I 1/2 /ω 2 is the amplitude of the oscillation of a free electron in the field with frequency ω and intensity I (unless stated otherwise, we use atomic units throughout this paper). Whereas in vacuum at least one of the electrons of an AMCNI autodetaches, an intense high-frequency field can change the character of the ion dramatically, such that bound states of AMCNI can appear. Due to the interaction with the field, the electrons of the AMCNI oscillate in phase along the polarization axis. This open-quotes quiverclose quotes motion enables the electrons to be spatially separated over distances of order α 0 , reducing the repulsive e-e interaction as α 0 increases. In other words, for α 0 large enough, the field enables a configuration in which the electrons, while widely separated, are bound to one proton. For the prediction of bound states of H N- with N>3, however, a relativistic description or low-frequency theory is required. copyright 1997 The American Physical Society

  20. Luminescent systems based on the isolation of conjugated PI systems and edge charge compensation with polar molecules on a charged nanostructured surface

    Science.gov (United States)

    Ivanov, Ilia N.; Puretzky, Alexander A.; Zhao, Bin; Geohegan, David B.; Styers-Barnett, David J.; Hu, Hui

    2014-07-15

    A photoluminescent or electroluminescent system and method of making a non-luminescent nanostructured material into such a luminescent system is presented. The method of preparing the luminescent system, generally, comprises the steps of modifying the surface of a nanostructured material to create isolated regions to act as luminescent centers and to create a charge imbalance on the surface; applying more than one polar molecule to the charged surface of the nanostructured material; and orienting the polar molecules to compensate for the charge imbalance on the surface of the nanostructured material. The compensation of the surface charge imbalance by the polar molecules allows the isolated regions to exhibit luminescence.

  1. Polar transport in plants mediated by membrane transporters: focus on mechanisms of polar auxin transport.

    Science.gov (United States)

    Naramoto, Satoshi

    2017-12-01

    Directional cell-to-cell transport of functional molecules, called polar transport, enables plants to sense and respond to developmental and environmental signals. Transporters that localize to plasma membranes (PMs) in a polar manner are key components of these systems. PIN-FORMED (PIN) auxin efflux carriers, which are the most studied polar-localized PM proteins, are implicated in the polar transport of auxin that in turn regulates plant development and tropic growth. In this review, the regulatory mechanisms underlying polar localization of PINs, control of auxin efflux activity, and PIN abundance at PMs are considered. Up to date information on polar-localized nutrient transporters that regulate directional nutrient movement from soil into the root vasculature is also discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Polarized parton distributions from charged-current deep-inelastic scattering

    International Nuclear Information System (INIS)

    Ridolfi, G

    2003-01-01

    We investigate the capabilities of a neutrino factory in the determination of polarized parton distributions from charged-current deep-inelastic scattering experiments, with special attention to the accuracy of this kind of measurements. We show that a neutrino factory would allow to distinguish between different theoretical scenarios for the proton spin structure

  3. Coupled spin and charge collective excitations in a spin polarized electron gas

    International Nuclear Information System (INIS)

    Marinescu, D.C.; Quinn, J.J.; Yi, K.S.

    1997-01-01

    The charge and longitudinal spin responses induced in a spin polarized quantum well by a weak electromagnetic field are investigated within the framework of the linear response theory. The authors evaluate the excitation frequencies for the intra- and inter-subband transitions of the collective charge and longitudinal spin density oscillations including many-body corrections beyond the random phase approximation through the spin dependent local field factors, G σ ± (q,ω). An equation-of-motion method was used to obtain these corrections in the limit of long wavelengths, and the results are given in terms of the equilibrium pair correlation function. The finite degree of spin polarization is shown to introduce coupling between the charge and spin density modes, in contrast with the result for an unpolarized system

  4. Computer simulations analysis for determining the polarity of charge generated by high energy electron irradiation of a thin film

    DEFF Research Database (Denmark)

    Malac, Marek; Hettler, Simon; Hayashida, Misa

    2017-01-01

    Detailed simulations are necessary to correctly interpret the charge polarity of electron beam irradiated thin film patch. Relying on systematic simulations we provide guidelines and movies to interpret experimentally the polarity of the charged area, to be understood as the sign of the electrost...

  5. Resonance charge exchange mechanism at high and moderate energies

    International Nuclear Information System (INIS)

    Bogdanov, A.V.; Gevorkyan, A.S.

    1984-01-01

    Charge exchange mechanisms at high and medium energies are investigated, ta king the resonance charge exchange of a proton by an hydrogen atom as an example . It is established that there are two classical charge exchange mechanisms rel ated to direct proton knockout from the bound state and one quantum-mechanical mechanism corresponding to the electron tunnelling from one bound state to anoth er. The classical cross-section diverges for two of these mechanisms, and the quasiclassical scattering amplitude must be calculated on the base of a complex classical trajectory. Physical grounds for the choice of such trajectories are discussed and calculations of the Van Vleck determinant for these mechanisms a re presented. Contributions from different mechanisms to the total charge excha nge cross-section are analyzed. A comparison with experimental data and results of other authors is made

  6. Effects of D-600 on intramembrane charge movement of polarized and depolarized frog muscle fibers.

    Science.gov (United States)

    Caputo, C; Bolaños, P

    1989-07-01

    Intramembrane charge movement has been measured in frog cut skeletal muscle fibers using the triple vaseline gap voltage-clamp technique. Ionic currents were reduced using an external solution prepared with tetraethylammonium to block potassium currents, and O sodium + tetrodotoxin to abolish sodium currents. The internal solution contained 10 mM EGTA to prevent contractions. Both the internal and external solutions were prepared with impermeant anions. Linear capacitive currents were subtracted using the P-P/4 procedure, with the control pulses being subtracted either at very negative potentials, for the case of polarized fibers, or at positive potentials, for the case of depolarized fibers. In 63 polarized fibers dissected from Rana pipiens or Leptodactylus insularis frogs the following values were obtained for charge movement parameters: Qmax = 39 nC/microF, V = 36 mV, k = 18.5 mV. After depolarization we found that the total amount of movable charge was not appreciably reduced, while the voltage sensitivity was much changed. For 10 fibers, in which charge movement was measured at -100 and at 0 mV, Qmax changed from 46 to 41 nC/microF, while V changed from -41 to -103 mV and k changed from 20.5 to 30 mV. Thus membrane depolarization to 0 mV produces a shift of greater than 50 mV in the Q-V relationship and a decrease of the slope. Membrane depolarization to -20 and -30 mV, caused a smaller shift of the Q-V relationship. In normally polarized fibers addition of D-600 at concentrations of 50-100 microM, does not cause important changes in charge movement parameters. However, the drug appears to have a use-dependent effect after depolarization. Thus in depolarized fibers, total charge is reduced by approximately 20%. D-600 causes no further changes in the voltage sensitivity of charge movement in fibers depolarized to 0 mV, while in fibers depolarized to -20 and -30 mV it causes the same effects as that obtained with depolarization to 0 mV. These results are

  7. Variational calculation of quantum mechanical/molecular mechanical free energy with electronic polarization of solvent

    Science.gov (United States)

    Nakano, Hiroshi; Yamamoto, Takeshi

    2012-04-01

    Quantum mechanical/molecular mechanical (QM/MM) free energy calculation presents a significant challenge due to an excessive number of QM calculations. A useful approach for reducing the computational cost is that based on the mean field approximation to the QM subsystem. Here, we describe such a mean-field QM/MM theory for electronically polarizable systems by starting from the Hartree product ansatz for the total system and invoking a variational principle of free energy. The MM part is then recast to a classical polarizable model by introducing the charge response kernel. Numerical test shows that the potential of mean force (PMF) thus obtained agrees quantitatively with that obtained from a direct QM/MM calculation, indicating the utility of self-consistent mean-field approximation. Next, we apply the obtained method to prototypical reactions in several qualitatively different solvents and make a systematic comparison of polarization effects. The results show that in aqueous solution the PMF does not depend very much on the water models employed, while in nonaqueous solutions the PMF is significantly affected by explicit polarization. For example, the free energy barrier for a phosphoryl dissociation reaction in acetone and cyclohexane is found to increase by more than 10 kcal/mol when switching the solvent model from an empirical to explicitly polarizable one. The reason for this is discussed based on the parametrization of empirical nonpolarizable models.

  8. Charge-Dipole Acceleration of Polar Gas Molecules towards Charged Nanoparticles: Involvement in Powerful Charge-Induced Catalysis of Heterophase Chemical Reactions and Ball Lightning Phenomenon

    Directory of Open Access Journals (Sweden)

    Oleg Meshcheryakov

    2010-01-01

    Full Text Available In humid air, the substantial charge-dipole attraction and electrostatic acceleration of surrounding water vapour molecules towards charged combustible nanoparticles cause intense electrostatic hydration and preferential oxidation of these nanoparticles by electrostatically accelerated polar water vapour molecules rather than nonaccelerated nonpolar oxygen gas molecules. Intense electrostatic hydration of charged combustible nanoparticles converts the nanoparticle's oxide-based shells into the hydroxide-based electrolyte shells, transforming these nanoparticles into reductant/air core-shell nanobatteries, periodically short-circuited by intraparticle field and thermionic emission. Partially synchronized electron emission breakdowns within trillions of nanoparticles-nanobatteries turn a cloud of charged nanoparticles-nanobatteries into a powerful radiofrequency aerosol generator. Electrostatic oxidative hydration and charge-catalyzed oxidation of charged combustible nanoparticles also contribute to a self-oscillating thermocycling process of evolution and periodic autoignition of inflammable gases near to the nanoparticle's surface. The described effects might be of interest for the improvement of certain nanotechnological heterophase processes and to better understand ball lightning phenomenon.

  9. A numerical study on charging mechanism in leaky dielectric liquids inside the electrostatic atomizers

    Science.gov (United States)

    Kashir, Babak; Perri, Anthony; Yarin, Alexander L.; Mashayek, Farzad

    2017-11-01

    The charging of leaky dielectric liquids inside an electrostatic atomizer is studied numerically by developed codes based on OpenFOAM platform. Faradaic reactions are taken into account as the electrification mechanism. The impact of ionic finite size (steric terms) in high voltages is also investigated. The fundamental electrohydrodynamic understanding of the charging mechanism is aimed in the present work where the creation of polarized near-electrode layer and the movement of charges due to hydrodynamic flow are studied in conjunction with the solution of the Navier-Stokes equations. The case of a micro channel electrohydrodynamic flow subjected to two electrodes of the opposite polarity is considered as an example, with the goal to predict the resulting net charge at the exit. Even though the electrodes constitute a small portion of the channel wall, otherwise insulated, it is indicated that the channel length plays a dominant role in the discharging net charge. The ionic fluxes at the electrode surfaces are accounted through the Frumkin-Butler-Volmer relation found from the concurrent in-house experimental investigations. This projects was supported by National science Foundation (NSF) GOALI Grant CBET-1505276.

  10. Charge transfer state induced from locally excited state by polar solvent

    Science.gov (United States)

    Sun, Mengtao

    2005-06-01

    The photophysical properties of the novel perylene imide (Pi) and oligo-pentaphenyl bisfluorene (pPh) containing molecule have been investigated by quantum chemical methods. It is concluded that the first excited singlet state in the gas is the locally excited state; while the lowest excited state in polar solvents is the intramolecular charge transfer (ICT) state, which corresponds to the ICT from pPh to Pi. This excited state in the polar solvent adopts a planar geometry, in marked contrast to the twisted geometry in the gas phase. The planar geometry in the polar solvent significantly delocalized densities of HOMOs, compared to those in the gas phase, but the influence of the planar geometry to densities of LUMO is very small. Overall, the computed results remain in good agreement with the relevant experimental data.

  11. Mechanism of anterior-posterior polarity control in planarians

    Energy Technology Data Exchange (ETDEWEB)

    Lange, C.S.; Steele, V.E.

    1978-01-01

    The substance which inhibits brain formation in the regenerating planarian Dugesia etrusca was found to be a large molecule, at least in part protein, which electrophoreses as an electronegative moiety in pH 6.8 buffer. A model is presented, based on this finding and previous studies, which proposes an electrochemical mechanism for the control of polarity and possibly for the maintenance of tissue organization in planarians. It is proposed that a bioelectric field exists and moves the electronegative brain-inhibiting substance in a posterior direction, establishing polarity. This model explains the polarity reversal experiments using external fields and many of the previously unexplained classical planarian experiments. Data are presented demonstrating the existence, magnitude, and polarity of this bioelectric field, which is not greatly altered upon decapitation, all in accord with predictions of the model.

  12. Charge dividing mechanism in position-sensitive detectors

    International Nuclear Information System (INIS)

    Radeka, V.; Rehak, P.

    1978-01-01

    A complete charge-division mechanism, including both the diffusion and the electromagnetic wave propagation on resistive electrodes, is presented. The charge injected into such a transmission line divides between the two ends according to the ratio of resistances and independently of the value of the line resistance, of the propagation mechanism and of the distribution of inductance and capacitance along the line. The shortest charge division time is achieved for Rl = 2π (L/C)/sup 1/2), where R, L, C are resistance, inductance and capacitance per unit length and l is the length of the line

  13. Charge-Transfer States in Organic Solar Cells: Understanding the Impact of Polarization, Delocalization, and Disorder

    KAUST Repository

    Zheng, Zilong

    2017-05-08

    We investigate the impact of electronic polarization, charge delocalization, and energetic disorder on the charge-transfer (CT) states formed at a planar C60/pentacene interface. The ability to examine large complexes containing up to seven pentacene molecules and three C60 molecules allows us to take explicitly into account the electronic polarization effects. These complexes are extracted from a bilayer architecture modeled by molecular dynamics simulations and evaluated by means of electronic-structure calculations based on long-range-separated functionals (ωB97XD and BNL) with optimized range-separation parameters. The energies of the lowest charge-transfer states derived for the large complexes are in very good agreement with the experimentally reported values. The average singlet-triplet energy splittings of the lowest CT states are calculated not to exceed 10 meV. The rates of geminate recombination as well as of dissociation of the triplet excitons are also evaluated. In line with experiment, our results indicate that the pentacene triplet excitons generated through singlet fission can dissociate into separated charges on a picosecond time scale, despite the fact that their energy in C60/pentacene heterojunctions is slightly lower than the energies of the lowest CT triplet states.

  14. Polarization of electron-beam irradiated LDPE films: contribution to charge generation and transport

    Science.gov (United States)

    Banda, M. E.; Griseri, V.; Teyssèdre, G.; Le Roy, S.

    2018-04-01

    Electron-beam irradiation is an alternative way to generate charges in insulating materials, at controlled position and quantity, in order to monitor their behaviour in regard to transport phenomena under the space charge induced electric field or external field applied. In this study, low density polyethylene (LDPE) films were irradiated by a 80 keV electron-beam with a flux of 1 nA cm‑2 during 10 min in an irradiation chamber under vacuum conditions, and were then characterized outside the chamber using three experimental methods. The electrical behaviour of the irradiated material was assessed by space charge measurements using the pulsed electro-acoustic (PEA) method under dc stress. The influence of the applied electric field polarity and amplitude has been tested in order to better understand the charge behaviour after electron-beam irradiation. Fourier transform infra-red spectroscopy (FTIR) and photoluminescence (PL) measurements were performed to evaluate the impact of the electron beam irradiation, i.e. deposited charges and energy, on the chemical structure of the irradiated samples. The present results show that the electrical behaviour in LDPE after irradiation is mostly driven by charges, i.e. by physical process functions of the electric field, and that changes in the chemical structure seems to be mild.

  15. A polarity-induced defect mechanism for conductivity and magnetism at polar-nonpolar oxide interfaces.

    Science.gov (United States)

    Yu, Liping; Zunger, Alex

    2014-10-13

    The discovery of conductivity and magnetism at the polar-nonpolar interfaces of insulating nonmagnetic oxides such as LaAlO3 and SrTiO3 has raised prospects for attaining interfacial functionalities absent in the component materials. Yet, the microscopic origin of such emergent phenomena remains unclear, posing obstacles to design of improved functionalities. Here we present first principles calculations of electronic and defect properties of LaAlO3/SrTiO3 interfaces and reveal a unifying mechanism for the origins of both conductivity and magnetism. We demonstrate that the polar discontinuity across the interface triggers thermodynamically the spontaneous formation of certain defects that in turn cancel the polar field induced by the polar discontinuity. The ionization of the spontaneously formed surface oxygen vacancy defects leads to interface conductivity, whereas the unionized Ti-on-Al antisite defects lead to interface magnetism. The proposed mechanism suggests practical design principles for inducing and controlling both conductivity and magnetism at general polar-nonpolar interfaces.

  16. Nanoscale mechanical switching of ferroelectric polarization via flexoelectricity

    Energy Technology Data Exchange (ETDEWEB)

    Gu, Yijia; Hong, Zijian; Britson, Jason; Chen, Long-Qing [Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States)

    2015-01-12

    Flexoelectric coefficient is a fourth-rank tensor arising from the coupling between strain gradient and electric polarization and thus exists in all crystals. It is generally ignored for macroscopic crystals due to its small magnitude. However, at the nanoscale, flexoelectric contributions may become significant and can potentially be utilized for device applications. Using the phase-field method, we study the mechanical switching of electric polarization in ferroelectric thin films by a strain gradient created via an atomic force microscope tip. Our simulation results show good agreement with existing experimental observations. We examine the competition between the piezoelectric and flexoelectric effects and provide an understanding of the role of flexoelectricity in the polarization switching. Also, by changing the pressure and film thickness, we reveal that the flexoelectric field at the film bottom can be used as a criterion to determine whether domain switching may happen under a mechanical force.

  17. Nanoscale mechanical switching of ferroelectric polarization via flexoelectricity

    International Nuclear Information System (INIS)

    Gu, Yijia; Hong, Zijian; Britson, Jason; Chen, Long-Qing

    2015-01-01

    Flexoelectric coefficient is a fourth-rank tensor arising from the coupling between strain gradient and electric polarization and thus exists in all crystals. It is generally ignored for macroscopic crystals due to its small magnitude. However, at the nanoscale, flexoelectric contributions may become significant and can potentially be utilized for device applications. Using the phase-field method, we study the mechanical switching of electric polarization in ferroelectric thin films by a strain gradient created via an atomic force microscope tip. Our simulation results show good agreement with existing experimental observations. We examine the competition between the piezoelectric and flexoelectric effects and provide an understanding of the role of flexoelectricity in the polarization switching. Also, by changing the pressure and film thickness, we reveal that the flexoelectric field at the film bottom can be used as a criterion to determine whether domain switching may happen under a mechanical force

  18. Nanoscale mechanical switching of ferroelectric polarization via flexoelectricity

    Science.gov (United States)

    Gu, Yijia; Hong, Zijian; Britson, Jason; Chen, Long-Qing

    2015-01-01

    Flexoelectric coefficient is a fourth-rank tensor arising from the coupling between strain gradient and electric polarization and thus exists in all crystals. It is generally ignored for macroscopic crystals due to its small magnitude. However, at the nanoscale, flexoelectric contributions may become significant and can potentially be utilized for device applications. Using the phase-field method, we study the mechanical switching of electric polarization in ferroelectric thin films by a strain gradient created via an atomic force microscope tip. Our simulation results show good agreement with existing experimental observations. We examine the competition between the piezoelectric and flexoelectric effects and provide an understanding of the role of flexoelectricity in the polarization switching. Also, by changing the pressure and film thickness, we reveal that the flexoelectric field at the film bottom can be used as a criterion to determine whether domain switching may happen under a mechanical force.

  19. The use of charge extraction by linearly increasing voltage in polar organic light-emitting diodes

    Science.gov (United States)

    Züfle, Simon; Altazin, Stéphane; Hofmann, Alexander; Jäger, Lars; Neukom, Martin T.; Schmidt, Tobias D.; Brütting, Wolfgang; Ruhstaller, Beat

    2017-05-01

    We demonstrate the application of the CELIV (charge carrier extraction by linearly increasing voltage) technique to bilayer organic light-emitting devices (OLEDs) in order to selectively determine the hole mobility in N,N0-bis(1-naphthyl)-N,N0-diphenyl-1,10-biphenyl-4,40-diamine (α-NPD). In the CELIV technique, mobile charges in the active layer are extracted by applying a negative voltage ramp, leading to a peak superimposed to the measured displacement current whose temporal position is related to the charge carrier mobility. In fully operating devices, however, bipolar carrier transport and recombination complicate the analysis of CELIV transients as well as the assignment of the extracted mobility value to one charge carrier species. This has motivated a new approach of fabricating dedicated metal-insulator-semiconductor (MIS) devices, where the extraction current contains signatures of only one charge carrier type. In this work, we show that the MIS-CELIV concept can be employed in bilayer polar OLEDs as well, which are easy to fabricate using most common electron transport layers (ETLs), like Tris-(8-hydroxyquinoline)aluminum (Alq3). Due to the macroscopic polarization of the ETL, holes are already injected into the hole transport layer below the built-in voltage and accumulate at the internal interface with the ETL. This way, by a standard CELIV experiment only holes will be extracted, allowing us to determine their mobility. The approach can be established as a powerful way of selectively measuring charge mobilities in new materials in a standard device configuration.

  20. Mechanism of Cyclically Polarity Reversing Solar Magnetic Cycle as ...

    Indian Academy of Sciences (India)

    2016-01-27

    Jan 27, 2016 ... We briefly describe historical development of the concept of solar dynamo mechanism that generates electric current and magnetic field by plasma ... The dynamo is the driver of the cyclically polarity reversing solar magnetic cycle. ... Department of Astronomy, University of Tokyo, Tokyo, Japan 113-0033.

  1. Charge movement and mechanical repriming in skeletal muscle.

    Science.gov (United States)

    Adrian, R H; Chandler, W K; Rakowski, R F

    1976-01-01

    1. Muscles were placed in a solution which depolarized the membrane to -30 to -20 mV so that mechanical activation was made refractory. Mechanical repriming and the recovery of voltage dependent charge movement were studied using a voltage clamp technique. 2. Mechanical repriming was investigated by determining the duration of a hyperpolarizing pulse required to elicit a just-visible contraction for various post-pulse potentials. As the post-pulse potential was made more positive shorter repriming times were required to produce a threshold contraction. The relationship approached a minimum repriming time for very positive post-pulse potentials. 3. These results suggest that hyperpolarization gradually removes some component of the activation mechanism from a refractory state and that the effectiveness of the amount which has recovered depends on the post-pulse potential. A quantitative explanation is given using a simple model in which the essential component is assumed to be the charge movement process. 4. The rate of repriming contraction is voltage dependent; at -160 mV the rate is about twice that at -120 mV. Between 4 and 10 degrees C the rate has a Q10 of about 9. 5. Recovery of charge movement was studied using a repriming duration less than that required to produce a threshold contraction. The observed charge movement increased linearly with repriming time, consistent with the approximately linear initial segment of a slow exponential recovery process. Extrapolation of the recovery curve indicated that 2-5 n/CmuF of charge is reprimed in the time necessary to reprime a threshold contraction. 6. The charge which recovers during a subthreshold repriming pulse is distributed according to membrane potential in the same way as a fully reprimed charge. 7. These results are consistent with the hypothesis that voltage dependent charge movement is an intermediate step in excitation-contraction coupling. 8. The characteristics of a second type of charge movement are

  2. An EV Charging Scheduling Mechanism Based on Price Negotiation

    Directory of Open Access Journals (Sweden)

    Baocheng Wang

    2018-05-01

    Full Text Available Scheduling EV user’s charging behavior based on charging price and applying renewable energy resources are the effective methods to release the load pressure of power grids brought about by the large-scale popularity of electric vehicles (EVs. This paper presents a novel approach for EV charging scheduling based on price negotiation. Firstly, the EV charging system framework based on price negotiation and renewable energy resources is discussed. Secondly, the price negotiation model is presented, including the initial price models and the conditions of transactions. Finally, an EV charging scheduling mechanism based on price negotiation (CSM-PN, including the price adjustment strategies of both the operator and EV users is proposed to seek a final transaction during multi-round price negotiation. Simulation results show that this novel approach can effectively improve the charging station operator’s income, reduce the EV users’ costs, and balance the load of the power grid while improving the efficiency of the EV charging system.

  3. Determination of charged particles and their polarity in XLPE by temperature gradient thermally stimulated surface potential measurement

    International Nuclear Information System (INIS)

    Iwamoto, Mitsumasa; Kato, Keizo; Kook, Sang-Hoon; Hino, Taro

    1985-01-01

    By the thermally stimulated surface potential measurement with a temperature gradient in the insulator specimen, various information not possible by the uniform heating is obtained. Determination of polarity of the carriers is capable of providing a knowledge on space charge in power cables, for example. For the cross-linked polyethylene (XLPE) film as cable insulation, polarity of the carriers trapped in it was determined, thereby demonstrating effectiveness of the method. The determination of polarity of mobile ions forming polarization of the ion space charge was also studied. In the ion C-peak appearing in the thermally stimulated current are involved straight-polarity mobile ions, and in the trap D-peak, hole carriers. (Mori, K.)

  4. Long-Term Charge/Discharge Cycling Stability of MnO2 Aqueous Supercapacitor under Positive Polarization

    KAUST Repository

    Ataherian, Fatemeh

    2011-01-01

    The long-term charge/discharge cycling stability of MnO 2 electrode under positive polarization in aqueous KCl electrolyte has been studied over different potential windows spanning from the open circuit potential to varied higher-end potential limited by O 2 evolution. Cycling up to 1.2 V (vs Ag/AgCl (aq)) causes partial (35) capacitance fading to a plateau value within the initial cycles, accompanied by morphological reconstruction, reduction of surface Mn ions and oxygen evolution. The surface Mn-ion reduction has been attributed to a two-step oxidation-reduction mechanism involving OH oxidation in electrolyte, based on electrochemical analysis. When cycling potential extends to 1.4 V, extensive oxygen evolution takes place. The combination of surface passivation of current collector and extensive gas bubbling, which deteriorates electrical contact among the constituent particles within the electrode, results in further monotonic capacitance reduction. © 2011 The Electrochemical Society.

  5. Nonlinear waves in viscoelastic magnetized complex astroplasmas with polarized dust-charge variations

    Directory of Open Access Journals (Sweden)

    Papari Das

    2018-01-01

    Full Text Available A nonextensive nonthermal magnetized viscoelastic astrofluid, compositionally containing nonthermal electrons and ions together with massive polarized dust micro-spherical grains of variable electric charge, is allowed to endure weakly nonlinear perturbation around its equilibrium. The nonextensivity originating from the large-scale non-local effects is included via the Tsallis thermo-statistical distribution laws describing the lighter species. Assuming the equilibrium as a homogeneous hydrostatic one, the dust polarization effects are incorporated via the conventional homogeneous polarization force law. The perturbed fluid model evolves as a unique conjugate pair of coupled extended Korteweg-de Vries (e-KdV equations. A constructed numerical tapestry shows the collective excitations of a new pair of distinct classes of nonlinear mode structures in new parametric space. The first family indicates periodic electrostatic compressive eigenmodes in the form of soliton-chains. Likewise, the second one reveals gravitational rarefactive solitary patterns. Their microphysical multi-parametric dependencies of the eigen-patterns are illustratively analyzed and bolstered. The paper ends up with some promising implications and applications in the astro-cosmo-plasmic context of wave-induced accretive triggering processes responsible for gravitationally bounded (gravito-condensed astro-structure formation, such as stellesimals, planetsimals, etc.

  6. Nonlinear waves in viscoelastic magnetized complex astroplasmas with polarized dust-charge variations

    Science.gov (United States)

    Das, Papari; Karmakar, Pralay Kumar

    2018-01-01

    A nonextensive nonthermal magnetized viscoelastic astrofluid, compositionally containing nonthermal electrons and ions together with massive polarized dust micro-spherical grains of variable electric charge, is allowed to endure weakly nonlinear perturbation around its equilibrium. The nonextensivity originating from the large-scale non-local effects is included via the Tsallis thermo-statistical distribution laws describing the lighter species. Assuming the equilibrium as a homogeneous hydrostatic one, the dust polarization effects are incorporated via the conventional homogeneous polarization force law. The perturbed fluid model evolves as a unique conjugate pair of coupled extended Korteweg-de Vries (e-KdV) equations. A constructed numerical tapestry shows the collective excitations of a new pair of distinct classes of nonlinear mode structures in new parametric space. The first family indicates periodic electrostatic compressive eigenmodes in the form of soliton-chains. Likewise, the second one reveals gravitational rarefactive solitary patterns. Their microphysical multi-parametric dependencies of the eigen-patterns are illustratively analyzed and bolstered. The paper ends up with some promising implications and applications in the astro-cosmo-plasmic context of wave-induced accretive triggering processes responsible for gravitationally bounded (gravito-condensed) astro-structure formation, such as stellesimals, planetsimals, etc.

  7. EGCG in Green Tea Induces Aggregation of HMGB1 Protein through Large Conformational Changes with Polarized Charge Redistribution

    Science.gov (United States)

    Meng, Xuan-Yu; Li, Baoyu; Liu, Shengtang; Kang, Hongsuk; Zhao, Lin; Zhou, Ruhong

    2016-02-01

    As a major effective component in green tea, (-)-epigallocatechin-3-gallate (EGCG)’s potential benefits to human health have been widely investigated. Recent experimental evidences indicate that EGCG can induce the aggregation of HMGB1 protein, a late mediator of inflammation, which subsequently stimulates the autophagic degradation and thus provides protection from lethal endotoxemia and sepsis. In this study, we use molecular dynamics (MD) simulations to explore the underlying molecular mechanism of this aggregation of HMGB1 facilitated by EGCG. Our simulation results reveal that EGCG firmly binds to HMGB1 near Cys106, which supports previous preliminary experimental evidence. A large HMGB1 conformational change is observed, where Box A and Box B, two homogenous domains of HMGB1, are repositioned and packed together by EGCG. This new HMGB1 conformation has large molecular polarity and distinctive electrostatic potential surface. We suggest that the highly polarized charge distribution leads to the aggregation of HMGB1, which differs from the previous hypothesis that two HMGB1 monomers are linked by the dimer of EGCG. Possible aggregating modes have also been investigated with potential of mean force (PMF) calculations. Finally, we conclude that the conformation induced by EGCG is more aggregation-prone with higher binding free energies as compared to those without EGCG.

  8. A next-to-leading determination of the singlet axial charge and the polarized gluon content of the nucleon

    CERN Document Server

    Ball, R D; Ridolfi, G

    1996-01-01

    We perform a full next-to-leading analysis of the the available experimental data on the polarized structure function g_1 of the nucleon, and give a precise determination of its singlet axial charge together with a thorough assessment of the theoretical uncertainties. We find that the data are now sufficient to separately determine first moments of the polarized quark and gluon distributions and show in particular that the gluon contribution is large and positive.

  9. General method for calculating polarization electric fields produced by auroral Cowling mechanism and application examples

    Science.gov (United States)

    Vanhamäki, Heikki; Amm, Olaf; Fujii, Ryo; Yoshikawa, Aki; Ieda, Aki

    2013-04-01

    The Cowling mechanism is characterized by the generation of polarization space charges in the ionosphere in consequence of a partial or total blockage of FAC flowing between the ionosphere and the magnetosphere. Thus a secondary polarization electric field builds up in the ionosphere, which guarantees that the whole (primary + secondary) ionospheric current system is again in balance with the FAC. In the Earth's ionosphere the Cowling mechanism is long known to operate in the equatorial electrojet, and several studies indicate that it is important also in auroral current systems. We present a general method for calculate the secondary polarization electric field, when the ionospheric conductances, the primary (modeled) or the total (measured) electric field, and the Cowling efficiency are given. Here the Cowling efficiency is defined as the fraction of the divergent Hall current canceled by secondary Pedersen current. In contrast to previous studies, our approach is a general solution which is not limited to specific geometrical setups (like an auroral arc), and all parameters may have any kind of spatial dependence. The solution technique is based on spherical elementary current (vector) systems (SECS). This way, we avoid the need to specify explicit boundary conditions for the searched polarization electric field or its potential, which would be required if the problem was solved in a differential equation approach. Instead, we solve an algebraic matrix equation, for which the implicit boundary condition that the divergence of the polarization electric field vanishes outside our analysis area is sufficient. In order to illustrate the effect of Cowling mechanism on ionospheric current systems, we apply our method to two simple models of auroral electrodynamic situations: 1) a mesoscale strong conductance enhancement in the early morning sector within a relatively weak southward primary electric field, 2) a morning sector auroral arc with only a weak conductance

  10. First time measurements of polarization observables for the charged cascade hyperon in photoproduction

    Energy Technology Data Exchange (ETDEWEB)

    Bono, Jason [Florida Intl Univ., Miami, FL (United States)

    2014-08-31

    The parity violating weak decay of hyperons offers a valuable means of measuring their polarization, providing insight into the production of strange quarks and the matter they compose. Jefferson Lab's CLAS collaboration has utilized this property of hyperons, publishing the most precise polarization measurements for the Lambda and Sigma in both photoproduction and electroproduction to date. In contrast, cascades, which contain two strange quarks, can only be produced through indirect processes and as a result, exhibit low cross sections thus remaining experimentally elusive. At present, there are two aspects in cascade physics where progress has been minimal: characterizing their production mechanism, which lacks theoretical and experimental developments, and observation of the numerous excited cascade resonances that are required to exist by fl avor SU(3)F symmetry. However, CLAS data were collected in 2008 with a luminosity of 68 pb^-1 using a circularly polarized photon beam with energies up to 5.45 GeV, incident on a liquid hydrogen target. This dataset is, at present, the world's largest for meson photoproduction in its energy range and provides a unique opportunity to study cascade physics with polarization measurements. The current analysis explores hyperon production through the yp -> K^+ K^+ Xi^- reaction by providing the first ever determination of spin observables P, Cx and Cz for the cascade. Three of our primary goals are to test the only cascade photoproduction model in existence, examine the underlying processes that give rise to hyperon polarization, and to stimulate future theoretical developments while providing constraints for their parameters. Our research is part of a broader program to understand the production of strange quarks and hadrons with strangeness. The remainder of this document discusses the motivation behind such research, the method of data collection, details of their analysis, and the significance of our results.

  11. Charge-Shift Corrected Electronegativities and the Effect of Bond Polarity and Substituents on Covalent-Ionic Resonance Energy.

    Science.gov (United States)

    James, Andrew M; Laconsay, Croix J; Galbraith, John Morrison

    2017-07-13

    Bond dissociation energies and resonance energies for H n A-BH m molecules (A, B = H, C, N, O, F, Cl, Li, and Na) have been determined in order to re-evaluate the concept of electronegativity in the context of modern valence bond theory. Following Pauling's original scheme and using the rigorous definition of the covalent-ionic resonance energy provided by the breathing orbital valence bond method, we have derived a charge-shift corrected electronegativity scale for H, C, N, O, F, Cl, Li, and Na. Atomic charge shift character is defined using a similar approach resulting in values of 0.42, 1.06, 1.43, 1.62, 1.64, 1.44, 0.46, and 0.34 for H, C, N, O, F, Cl, Li, and Na, respectively. The charge-shift corrected electronegativity values presented herein follow the same general trends as Pauling's original values with the exception of Li having a smaller value than Na (1.57 and 1.91 for Li and Na respectively). The resonance energy is then broken down into components derived from the atomic charge shift character and polarization effects. It is then shown that most of the resonance energy in the charge-shift bonds H-F, H 3 C-F, and Li-CH 3 and borderline charge-shift H-OH is associated with polarity rather than the intrinsic atomic charge-shift character of the bonding species. This suggests a rebranding of these bonds as "polar charge-shift" rather than simply "charge-shift". Lastly, using a similar breakdown method, it is shown that the small effect the substituents -CH 3 , -NH 2 , -OH, and -F have on the resonance energy (<10%) is mostly due to changes in the charge-shift character of the bonding atom.

  12. Electronic device for measuring the polarization parameter in the π-p → π0n charge exchange reaction on a polarized proton target

    International Nuclear Information System (INIS)

    Brehin, S.

    1967-12-01

    An electronic apparatus has been constructed to measure the polarization parameter P 0 (t) in π - p → π 0 n charge exchange scattering at 5.9 GeV/c and 11,2 GeV/c on polarized proton target. This device insures triggering of a heavy plate spark chamber, allowing visualisation of γ rays from the π 0 decays when the associated neutron offers suitable characteristics in direction and energy. The neutron is detected by an array of 32 counters and his energy is measured by a time of flight method. Electronic circuits of this apparatus are described as test and calibration methods used. (author) [fr

  13. Charge carrier transport mechanisms in nanocrystalline indium oxide

    International Nuclear Information System (INIS)

    Forsh, E.A.; Marikutsa, A.V.; Martyshov, M.N.; Forsh, P.A.; Rumyantseva, M.N.; Gaskov, A.M.; Kashkarov, P.K.

    2014-01-01

    The charge transport properties of nanocrystalline indium oxide (In 2 O 3 ) are studied. A number of nanostructured In 2 O 3 samples with various nanocrystal sizes are prepared by sol–gel method and characterized using various techniques. The mean nanocrystals size varies from 7–8 nm to 18–20 nm depending on the conditions of their preparation. Structural characterizations of the In 2 O 3 samples are performed by means of transmission electron microscopy and X-ray diffraction. The analysis of dc and ac conductivity in a wide temperature range (T = 50–300 K) shows that at high temperatures charge carrier transport takes place over conduction band and at low temperatures a variable range hopping transport mechanism can be observed. We find out that the temperature of transition from one mechanism to another depends on nanocrystal size: the transition temperature rises when nanocrystals are bigger in size. The average hopping distance between two sites and the activation energy are calculated basing on the analysis of dc conductivity at low temperature. Using random barrier model we show a uniform hopping mechanism taking place in our samples and conclude that nanocrystalline In 2 O 3 can be regarded as a disordered system. - Highlights: • In 2 O 3 samples with various nanocrystal sizes are prepared by sol–gel method. • The mean nanocrystal size varies from 7–8 nm to 18–20 nm. • At high temperatures charge carrier transport takes place over conduction band. • At low temperatures a variable range hopping transport mechanism can be observed. • We show a uniform hopping mechanism taking place in our samples

  14. Explicit polarization: a quantum mechanical framework for developing next generation force fields.

    Science.gov (United States)

    Gao, Jiali; Truhlar, Donald G; Wang, Yingjie; Mazack, Michael J M; Löffler, Patrick; Provorse, Makenzie R; Rehak, Pavel

    2014-09-16

    Conspectus Molecular mechanical force fields have been successfully used to model condensed-phase and biological systems for a half century. By means of careful parametrization, such classical force fields can be used to provide useful interpretations of experimental findings and predictions of certain properties. Yet, there is a need to further improve computational accuracy for the quantitative prediction of biomolecular interactions and to model properties that depend on the wave functions and not just the energy terms. A new strategy called explicit polarization (X-Pol) has been developed to construct the potential energy surface and wave functions for macromolecular and liquid-phase simulations on the basis of quantum mechanics rather than only using quantum mechanical results to fit analytic force fields. In this spirit, this approach is called a quantum mechanical force field (QMFF). X-Pol is a general fragment method for electronic structure calculations based on the partition of a condensed-phase or macromolecular system into subsystems ("fragments") to achieve computational efficiency. Here, intrafragment energy and the mutual electronic polarization of interfragment interactions are treated explicitly using quantum mechanics. X-Pol can be used as a general, multilevel electronic structure model for macromolecular systems, and it can also serve as a new-generation force field. As a quantum chemical model, a variational many-body (VMB) expansion approach is used to systematically improve interfragment interactions, including exchange repulsion, charge delocalization, dispersion, and other correlation energies. As a quantum mechanical force field, these energy terms are approximated by empirical functions in the spirit of conventional molecular mechanics. This Account first reviews the formulation of X-Pol, in the full variationally correct version, in the faster embedded version, and with systematic many-body improvements. We discuss illustrative examples

  15. Geomagnetic polarity reversals as a mechanism for the punctuated equilibrium model of biological evolution

    International Nuclear Information System (INIS)

    Welsh, J.S.; Welsh, A.L.; Welsh, W.F.

    2003-01-01

    In contrast to what is predicted by classical Darwinian theory (phyletic gradualism), the fossil record typically displays a pattern of relatively sudden, dramatic changes as detailed by Eldregde and Gould's model of punctuated equilibrium. Evolutionary biologists have been at a loss to explain the ultimate source of the new mutations that drive evolution. One hypothesis holds that the abrupt speciation seen in the punctuated equilibrium model is secondary to an increased mutation rate resulting from periodically increased levels of ionizing radiation on the Earth's surface. Sporadic geomagnetic pole reversals, occurring every few million years on the average, are accompanied by alterations in the strength of the Earth's magnetic field and magnetosphere. This diminution may allow charged cosmic radiation to bombard Earth with less attenuation, thereby resulting in increased mutation rates. This episodic fluctuation in the magnetosphere is an attractive mechanism for the observed fossil record. Selected periods and epochs of geologic history for which data was available were reviewed for both geomagnetic pole reversal history and fossil record. Anomalies in either were scrutinized in greater depth and correlations were made. A 35 million year span (118-83 Ma) was identified during the Early/Middle Cretaceous period that was devoid of geomagnetic polarity reversals(the Cretaceous normal superchron). Examination of the fossil record (including several invertebrate and vertebrate taxons) during the Cretaceous normal superchron does not reveal any significant gap or slowing of speciation. Although increased terrestrial radiation exposure due to a diminution of the Earth's magnetosphere caused by a reversal of geomagnetic polarity is an attractive explanation for the mechanism of punctuated equilibrium, our investigation suggests that such polarity reversals cannot fully provide the driving force behind biological evolution. Further research is required to determine if

  16. Simple Physics-Based Analytical Formulas for the Potentials of Mean Force of the Interaction of Amino Acid Side Chains in Water. VII. Charged-Hydrophobic/Polar and Polar-Hydrophobic/Polar Side Chains.

    Science.gov (United States)

    Makowski, Mariusz; Liwo, Adam; Scheraga, Harold A

    2017-01-19

    The physics-based potentials of side-chain-side-chain interactions corresponding to pairs composed of charged and polar, polar and polar, charged and hydrophobic, and hydrophobic and hydrophobic side chains have been determined. A total of 144 four-dimensional potentials of mean force (PMFs) of all possible pairs of molecules modeling these pairs were determined by umbrella-sampling molecular dynamics simulations in explicit water as functions of distance and orientation, and the analytical expressions were then fitted to the PMFs. Depending on the type of interacting sites, the analytical approximation to the PMF is a sum of terms corresponding to van der Waals interactions and cavity-creation involving the nonpolar sections of the side chains and van der Waals, cavity-creation, and electrostatic (charge-dipole or dipole-dipole) interaction energies and polarization energies involving the charged or polar sections of the side chains. The model used in this work reproduces all features of the interacting pairs. The UNited RESidue force field with the new side-chain-side-chain interaction potentials was preliminarily tested with the N-terminal part of the B-domain of staphylococcal protein A (PDBL 1BDD ; a three-α-helix bundle) and UPF0291 protein YnzC from Bacillus subtilis (PDB: 2HEP ; an α-helical hairpin).

  17. Influence of solvent polarization and non-uniform ion size on electrostatic properties between charged surfaces in an electrolyte solution

    Science.gov (United States)

    Sin, Jun-Sik

    2017-12-01

    In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using the mean-field approach accounting for solvent polarization and non-uniform size effects. Applying a free energy formalism accounting for unequal ion sizes and orientational ordering of water dipoles, we derive coupled and self-consistent equations to calculate electrostatic properties between charged surfaces. Electrostatic properties for similarly charged surfaces depend on the counterion size but not on the coion size. Moreover, electrostatic potential and osmotic pressure between similarly charged surfaces are found to be increased with increasing counterion size. On the other hand, the corresponding ones between oppositely charged surfaces are related to both sizes of positive and negative ions. For oppositely charged surfaces, the electrostatic potential, number density of solvent molecules, and relative permittivity of an electrolyte having unequal ion sizes are not symmetric about the centerline between the charged surfaces. For either case, the consideration of solvent polarization results in a decrease in the electrostatic potential and the osmotic pressure compared to the case without the effect.

  18. Residual-Charge Induced Memory Effect of Electric Polarization in Multiferroic CuFe1-xGaxO2 as Seen via Polarized Neutron Diffraction

    Science.gov (United States)

    Nakajima, Taro; Mitsuda, Setsuo; Yamazaki, Hiroe; Matsuura, Masato

    2013-02-01

    We have investigated ferroelectric polarization memory effect in a magneto-electric (ME) multiferroic CuFe1-x GaxO2 (CFGO) with x=0.035, which exhibits a spin-driven ferroelectric phase below TC˜ 7 K in zero magnetic field. In a previous study on CFGO(x=0.035), we have reported that the ferroelectric polarization induced by an applied electric field is retrieved after heating the sample to a non-ferroelectric high-temperature phase and then cooling down to the ferroelectric phase without electric field. [Mitsuda et al. Physica B 404 (2009) 2532] By measuring thermally stimulated electric current in detail, the previous study has elucidated that residual charges trapped in the sample are relevant to the memory effect. In the present study, we have performed polarized neutron diffraction measurements on CFGO(x=0.035) with applied electric fields, in order to investigate the multiferroic domain structure, which can reflect spatial distribution of internal electric fields due to the trapped charges. The present results have shown that the effect of the internal electric fields is significantly different from that of the ``uniform'' electric field applied on the first cooling. To explain the present results, we suggest a model that the residual charges are trapped on boundaries between the three types of magnetic domains originating from the trigonal symmetry of the crystal, implying that the presence of the bound charges of the ferroelectric polarization on the domain boundaries is a key to the memory effect in this system.

  19. Investigation on the Charge Loss Mechanisms of Nanoscale Charge Trap Non-Volatile Memory by Using Stretched Exponential Function.

    Science.gov (United States)

    Lee, Meng Chuan; Wong, Hin Yong

    2016-01-01

    Charge loss mechanisms of nanoscale charge trap non-volatile memory devices are carefully examined and studied. Fowler-Nordheim tunnelling mechanism is used to perform rapid program/erase cycling. Based on the good fit of post cycled and baked threshold voltage data to Stretched Exponential function, the lowest point and the peak of Vt distribution were found to evolve in a similar manner that resulted to similar derived Ea. The saturation behaviour of the threshold voltage decay can be predicted and validated through cells' threshold voltage measurements that fit well to Stretched Exponential function. The power law relationship of program/erase cycle count and the saturation behaviour was found to be similar on the device under study and NROM devices that utilizes significant different charge injection mechanisms for program/erase operation. The experimental results also demonstrated that charge injection mechanism is one of the dominant factors in determining the underlying charge loss mechanism. Moreover, the determination of charge loss mechanism depends on the total charges injected through the tunnel oxide layer of ONO stack in NB-CTNVM cell. Physical interpretation of the experimental findings of the dominant charge loss mechanism is deliberated in detail.

  20. The polar 2e/12c bond in phenalenyl-azaphenalenyl hetero-dimers: Stronger stacking interaction and fascinating interlayer charge transfer

    Science.gov (United States)

    Zhong, Rong-Lin; Xu, Hong-Liang; Li, Zhi-Ru

    2016-08-01

    An increasing number of chemists have focused on the two-electron/multicenter bond (2e/mc) that was first introduced to interpret the bonding mechanism of radical dimers. Herein, we report the polar two-electron/twelve center (2e/12c) bonding character in a series of phenalenyl-azaphenalenyl radical hetero-dimers. Interestingly, the bonding energy of weaker polar hetero-dimer (P-TAP) is dominated by the overlap of the two different singly occupied molecular orbital of radicals, while that of stronger polar hetero-dimer (P-HAP) is dominated by the electrostatic attraction. Results show that the difference between the electronegativity of the monomers plays a prominent role in the essential attribution of the polar 2e/12c bond. Correspondingly, a stronger stacking interaction in the hetero-dimer could be effectively achieved by increasing the difference of nitrogen atoms number between the monomers. It is worthy of note that an interesting interlayer charge transfer character is induced in the polar hetero-dimers, which is dependent on the difference between the electronegativity of the monomers. It is our expectation that the new knowledge about the bonding nature of radical hetero-dimers might provide important information for designing radical based functional materials with various applications.

  1. Non-coherent continuum scattering as a line polarization mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Del Pino Alemán, T.; Manso Sainz, R.; Trujillo Bueno, J., E-mail: tanausu@iac.es, E-mail: rsainz@iac.es, E-mail: jtb@iac.es [Instituto de Astrofísica de Canarias, E-38205 La Laguna, Tenerife (Spain)

    2014-03-20

    Line scattering polarization can be strongly affected by Rayleigh scattering at neutral hydrogen and Thomson scattering at free electrons. Often a depolarization of the continuum results, but the Doppler redistribution produced by the continuum scatterers, which are light (hence, fast), induces more complex interactions between the polarization in spectral lines and in the continuum. Here we formulate and solve the radiative transfer problem of scattering line polarization with non-coherent continuum scattering consistently. The problem is formulated within the spherical tensor representation of atomic and light polarization. The numerical method of solution is a generalization of the Accelerated Lambda Iteration that is applied to both the atomic system and the radiation field. We show that the redistribution of the spectral line radiation due to the non-coherence of the continuum scattering may modify the shape of the emergent fractional linear polarization patterns significantly, even yielding polarization signals above the continuum level in intrinsically unpolarizable lines.

  2. First principles molecular dynamics of molten NaI: Structure, self-diffusion, polarization effects, and charge transfer

    Science.gov (United States)

    Galamba, N.; Costa Cabral, B. J.

    2007-09-01

    The structure and self-diffusion of NaI and NaCl at temperatures close to their melting points are studied by first principles Hellmann-Feynman molecular dynamics (HFMD). The results are compared with classical MD using rigid-ion (RI) and shell-model (ShM) interionic potentials. HFMD for NaCl was reported before at a higher temperature [N. Galamba and B. J. Costa Cabral, J. Chem. Phys. 126, 124502 (2007)]. The main differences between the structures predicted by HFMD and RI MD for NaI concern the cation-cation and the anion-cation pair correlation functions. A ShM which allows only for the polarization of I- reproduces the main features of the HFMD structure of NaI. The inclusion of polarization effects for both ionic species leads to a more structured ionic liquid, although a good agreement with HFMD is also observed. HFMD Green-Kubo self-diffusion coefficients are larger than those obtained from RI and ShM simulations. A qualitative study of charge transfer in molten NaI and NaCl was also carried out with the Hirshfeld charge partitioning method. Charge transfer in molten NaI is comparable to that in NaCl, and results for NaCl at two temperatures support the view that the magnitude of charge transfer is weakly state dependent for ionic systems. Finally, Hirshfeld charge distributions indicate that differences between RI and HFMD results are mainly related to polarization effects, while the influence of charge transfer fluctuations is minimal for these systems.

  3. Development of polarized negative hydrogen ion source with resonant charge-exchange plasma ionizer

    Science.gov (United States)

    Belov, A. S.; Esin, S. K.; Netchaeva, L. P.; Turbabin, A. V.; Vasil'Ev, G. A.

    2001-06-01

    Polarized negative hydrogen ion beam with peak current of 2.5 mA has been obtained from an atomic beam-type polarized ion source of Institute for Nuclear Research, Moscow. The intensity improvement has been achieved due to increase of efficiency of conversion of polarized hydrogen atoms into polarized negative ions. New converter for production of deuterium plasma with high density of unpolarized negative ions is described. Limitations of the method and possible improvements are discussed. .

  4. Spin polarization driven by a charge-density wave in monolayer 1T−TaS2

    KAUST Repository

    Zhang, Qingyun

    2014-08-06

    Using first-principles calculations, we investigate the electronic and vibrational properties of monolayer T-phase TaS2. We demonstrate that a charge-density wave is energetically favorable at low temperature, similar to bulk 1T-TaS2. Electron-phonon coupling is found to be essential for the lattice reconstruction. The charge-density wave results in a strong localization of the electronic states near the Fermi level and consequently in spin polarization, transforming the material into a magnetic semiconductor with enhanced electronic correlations. The combination of inherent spin polarization with a semiconducting nature distinguishes the monolayer fundamentally from the bulk compound as well as from other two-dimensional transition metal dichalcogenides. Monolayer T-phase TaS2 therefore has the potential to enable two-dimensional spintronics. © 2014 American Physical Society.

  5. Polarization transfer in x-ray transitions due to photoionization in highly charged copper-like ions

    Science.gov (United States)

    Ma, Kun; Chen, Zhan-Bin; Xie, Lu-You; Dong, Chen-Zhong

    2018-02-01

    Using the density matrix theory and the multi-configuration Dirac-Fock method, the 3{d}3/2 subshell photoionization of highly charged ions is studied, together with their subsequent radiative decay. The effects of polarization transfer on the linear polarization and angular distribution of the 3{d}94{s}2{}2{D}3/2\\to 3{d}104p{}2{P}1/2 characteristic line photoemission for selected Cu-like Zn+, Ba27+, {{{W}}}45+, and {{{U}}}63+ ions are investigated. Our results show that the polarization transfer, arising from the originally polarized incident light, may lead to a considerable change in the alignment parameters and the polarization properties of the radiation, the character of which is highly sensitive to the initial photon polarization, yet virtually independent of the photon energy. These characteristics are very similar to those of the electron bremsstrahlung process reported by Märtin et al (2012 Phys. Rev. Lett. 108 264801). The present results are compared with available experimental results and show a good quantitative agreement.

  6. Magnetically coupled resonance wireless charging technology principles and transfer mechanisms

    Science.gov (United States)

    Zhou, Jiehua; Wan, Jian; Ma, Yinping

    2017-05-01

    With the tenure of Electric-Vehicle rising around the world, the charging methods have been paid more and more attention, the current charging mode mainly has the charging posts and battery swapping station. The construction of the charging pile or battery swapping station not only require lots of manpower, material costs but the bare conductor is also easy to generate electric spark hidden safety problems, still occupies large space. Compared with the wired charging, wireless charging mode is flexible, unlimited space and location factors and charging for vehicle safety and quickly. It complements the traditional charging methods in adaptability and the independent charge deficiencies. So the researching the wireless charging system have an important practical significance and application value. In this paper, wireless charging system designed is divided into three parts: the primary side, secondary side and resonant coupling. The main function of the primary side is to generate high-frequency alternating current, so selecting CLASS-E amplifier inverter structure through the research on full bridge, half-bridge and power amplification circuit. Addition, the wireless charging system is susceptible to outside interference, frequency drift phenomenon. Combined with the wireless energy transmission characteristics, resonant parts adopt resonant coupling energy transmission scheme and the Series-Series coupling compensation structure. For the electric vehicle charging power and voltage requirements, the main circuit is a full bridge inverter and Boost circuit used as the secondary side.

  7. A simple method of extracting the polarization charge density in the AlGaN/GaN heterostructure from current-voltage and capacitance-voltage characteristics

    International Nuclear Information System (INIS)

    Lü Yuan-Jie; Lin Zhao-Jun; Yu Ying-Xia; Meng Ling-Guo; Cao Zhi-Fang; Luan Chong-Biao; Wang Zhan-Guo

    2012-01-01

    An Ni Schottky contact on the AlGaN/GaN heterostructure is fabricated. The flat-band voltage for the Schottky contact on the AlGaN/GaN heterostructure is obtained from the forward current—voltage characteristics. With the measured capacitance—voltage curve and the flat-band voltage, the polarization charge density in the AlGaN/GaN heterostructure is investigated, and a simple formula for calculating the polarization charge density is obtained and analyzed. With the approach described in this paper, the obtained polarization charge density agrees well with the one calculated by self-consistently solving Schrodinger's and Poisson's equations

  8. Retinal processing and opponent mechanisms mediating ultraviolet polarization sensitivity in rainbow trout (Oncorhynchus mykiss)

    NARCIS (Netherlands)

    Ramsden, Samuel D.; Anderson, Leslie; Mussi, Martina; Kamermans, Maarten; Hawryshyn, Craig W.

    2008-01-01

    A number of teleost fishes have photoreceptor mechanisms to detect linearly polarized light. We studied the neuronal mechanism underlying this ability. It was found that a polarized signal could be detected in rainbow trout (Oncorhynchus mykiss) both in the electroretinogram (ERG) and in the

  9. Mechanism(s) for the suppression of the switchable polarization in PZT and BaTiO3

    Science.gov (United States)

    Warren, William L.; Dimos, Duane; Tuttle, Bruce A.; Pike, Gordon E.; Raymond, Mark V.; Nasby, Robert D.; Ramesh, R.; Evans, Joseph T., Jr.

    Switchable polarization can be significantly suppressed in ferroelectric (FE) materials by optical, thermal, and electrical processes. The thermal process can occur by either annealing the FE in a reducing environment or by heating it in air to 100 C while impressing a bias near the switching threshold. The optical process occurs while biasing the FE near the switching threshold and illuminating with bandgap light. And the electrical suppression effect occurs by subjecting the FE to repeated polarization reversals. Using electron paramagnetic resonance, polarization-voltage measurements, and charge injection scenarios, the authors have been able to elucidate both electronic and ionic trapping effects that lead to a suppression in the amount of switchable polarization in FE materials. The relative roles of electronic and ionic effects in the same material can depend on the stress condition. For instance, in oxidized BaTiO3 crystals, optical and thermal suppressions occur by electronic domain pinning; electrical fatigue in the BaTiO3 crystals also appears to involve electronic charge trapping, however, it is suggested that these electronic traps are further stabilized by nearby ionic defects. In sol-gel PZT thin films with either Pt, RuO2, or La-Sr-Co-O electrodes it appears that the polarization suppression induced by electrical fatigue, a temperature/bias combination, or a light/bias combination are all primarily due to the trapping of electronic charge carriers to first order.

  10. Scattering Mechanism Extraction by a Modified Cloude-Pottier Decomposition for Dual Polarization SAR

    Directory of Open Access Journals (Sweden)

    Kefeng Ji

    2015-06-01

    Full Text Available Dual polarization is a typical operational mode of polarimetric synthetic aperture radar (SAR. However, few studies have considered the scattering mechanism extraction of dual-polarization SARs. A modified Cloude-Pottier decomposition is proposed to investigate the performance of the scattering mechanism extraction of dual-polarization SARs. It is theoretically demonstrated that only HH-VV SAR can discriminate the three canonical scattering mechanisms from an isotropic surface, horizontal dipole, and isotropic dihedral. Various experiments are conducted using 21 scenes from real datasets acquired by AIRSAR, Convair-580 SAR, EMISAR, E-SAR, Pi-SAR, and RADARSAT-2. Division of the dual-polarization H-α plane is experimentally obtained. The lack of cross-polarization induces the diffusion of scattering mechanisms and their overlap in the HH-VV H-α plane. However, the performance of HH-VV SAR for extracting scattering mechanisms is acceptable. Thus, HH-VV SAR is a suitable alternative to full-polarization SAR in certain cases. Meanwhile, the extraction performance of the other two dual-polarization SARs is badly degraded due to the lack of co-polarization. Therefore, HH-HV and HV-VV SARs cannot effectively extract the scattering mechanisms in the H-α plane.

  11. Small scale density variations of electrons and charged particles in the vicinity of polar mesosphere summer echoes

    Directory of Open Access Journals (Sweden)

    M. Rapp

    2003-01-01

    Full Text Available We present small scale variations of electron number densities and particle charge number densities measured in situ in the presence of polar mesosphere summer echoes. It turns out that the small scale fluctuations of electrons and negatively charged particles show a strong anticorrelation down to the smallest scales observed. Comparing these small scale structures with the simultaneously measured radar signal to noise profile, we find that the radar profile is well described by the power spectral density of both electrons and charged particles at the radar half wavelength (=the Bragg scale. Finally, we consider the shape of the power spectra of the observed plasma fluctuations and find that both charged particles and electrons show spectra that can be explained in terms of either neutral air turbulence acting on the distribution of a low diffusivity tracer or the fossil remnants of a formerly active turbulent region. All these results are consistent with the theoretical ideas by Rapp and Lübken (2003 suggesting that PMSE can be explained by a combination of active and fossil neutral air turbulence acting on the large and heavy charged aerosol particles which are subsequently mirrored in the electron number density distribution that becomes visible to a VHF radar when small scale fluctuations are present.

  12. Measurement of the polarized forward-backward asymmetry of B quarks using momentum-weighted track charge at SLD

    International Nuclear Information System (INIS)

    Junk, T.R.

    1995-11-01

    This thesis presents a direct measurement of the parity-violating parameter A b by analyzing the polarized forward-backward asymmetry of b quarks in e + e - → Z 0 → b bar b. Data were taken at the Stanford Linear Accelerator Center (SLAC), with the Stanford Large Detector (SLD), which records the products of e + e - interactions at a center of mass energy √s = 91.2 GeV/c 2 at the SLAC Linear Collider (SLC). The SLC/SLD experimental apparatus provides a unique and ideal environment for measuring electroweak asymmetries. Heavy flavor decays of the Z 0 were identified inclusively by taking advantage of the long lifetime of B hadrons, the small, stable SLC beam spot, and SLD's precise tracking detectors. Two analysis techniques for measuring A b are presented: a binned fit to the left-right forward-backwards asymmetry of tagged events signed with momentum-weighted track charge, and a self-calibrating maximum-likelihood technique using momentum-weighted charge from the two hemispheres in each tagged event. From our 1994-1995 sample of 3.6 pb -1 , having a luminosity-weighted average e - polarization of 77.3%, and our 1993 sample of 1.8 pb -1 , having a luminosity-weighted polarization of 63.1%, we obtain A b = 0.848 ± 0.046(stat.) ± 0.050(syst.)

  13. Nuclear polarization study: new frontiers for tests of QED in heavy highly charged ions.

    Science.gov (United States)

    Volotka, Andrey V; Plunien, Günter

    2014-07-11

    A systematic investigation of the nuclear polarization effects in one- and few-electron heavy ions is presented. The nuclear polarization corrections in the zeroth and first orders in 1/Z are evaluated to the binding energies, the hyperfine splitting, and the bound-electron g factor. It is shown that the nuclear polarization contributions can be substantially canceled simultaneously with the rigid nuclear corrections. This allows for new prospects for probing the QED effects in a strong electromagnetic field and the determination of fundamental constants.

  14. PHYSIOLOGICAL MECHANISMS OF POLARIZED LIGHT INFLUENCE ON PAIN

    Directory of Open Access Journals (Sweden)

    S. О. Gulyar

    2016-06-01

    Full Text Available There are presented experimental evidences of BIOPTRON device polarized light influence on the acupuncture points and pain locus. It is proved that PILER-light can induce analgesia which depends on the choice of the application zone, exposure and nature of pain (tonic, acute or visceral. Analgesic response has systemic character and is accompanied by participation of opioidergic nociceptive system

  15. PHYSIOLOGICAL MECHANISMS OF POLARIZED LIGHT INFLUENCE ON PAIN

    OpenAIRE

    S. О. Gulyar; Z. А. Tamarova

    2016-01-01

    There are presented experimental evidences of BIOPTRON device polarized light influence on the acupuncture points and pain locus. It is proved that PILER-light can induce analgesia which depends on the choice of the application zone, exposure and nature of pain (tonic, acute or visceral). Analgesic response has systemic character and is accompanied by participation of opioidergic nociceptive system

  16. Hierarchy of mechanisms involved in generating Na/K-ATPase polarity in MDCK epithelial cells

    NARCIS (Netherlands)

    Mays, R.W.; Siemers, K.A.; Fritz, B.A.; Lowe, A.W.; van Meer, G.; Nelson, W.J.

    1995-01-01

    We have studied mechanisms involved in generating a polarized distribution of Na/K-ATPase in the basal-lateral membrane of two clones of MDCK II cells. Both clones exhibit polarized distributions of marker proteins of the apical and basal-lateral membranes, including Na/K-ATPase, at steady state.

  17. Effect of structural changes in sesquifulvalene on the intramolecular charge transfer and nonlinear polarizations a theoretical study

    Science.gov (United States)

    Nandi, P. K.; Mandal, K.; Kar, T.

    2003-11-01

    Ab initio HF calculations of the ground state structural parameters, and the time dependent HF (TDHF) calculations of static nonlinear polarizabilities have been performed for a number of sesquifulvalene derivatives. The calculated NLO parameters show a good correlation with the hardness parameters. The nature of hetero-atoms and their positions can strongly influence the intramolecular charge transfer (ICT) interactions and the nonlinear polarizations of sesquifulvalene. Nonlinear polarizabilities in the twisted structures have been found to depend both on the energy barrier to twist and the transition energy corresponding to the twisted ICT (TICT) state characterized by the HOMO → LUMO transition.

  18. Charged-Higgs on R{sub D}{sup {sub (}{sub *}{sub )}}, τ polarization, and FBA

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Chuan-Hung [National Cheng-Kung University, Department of Physics, Tainan (China); Nomura, Takaaki [KIAS, School of Physics, Seoul (Korea, Republic of)

    2017-09-15

    We study the influence of a charged-Higgs on the excess of branching fraction ratio, R{sub M} = BR(anti B → Mτ anti ν{sub τ})/BR(anti B → Ml anti ν{sub l}) (M = D, D*), in a generic two-Higgs-doublet model. In order to investigate the lepton polarization, the detailed decay amplitudes with lepton helicity are given. When the charged-Higgs is used to resolve excesses, it is found that two independent Yukawa couplings are needed to explain the R{sub D} and R{sub D*} anomalies. We show that when the upper limit of BR(B{sub c} → τ anti ν{sub τ}) < 30% is included, R{sub D} can be significantly enhanced while R{sub D*} < 0.27. With the BR(B{sub c} → τ anti ν{sub τ}) constraint, we find that the τ-lepton polarizations can be still affected by the charged-Higgs effects, where the standard model (SM) predictions are obtained: P{sup τ}{sub D} ∼ 0.324 and P{sup τ}{sub D*} ∼ -0.500, and they can be enhanced to be P{sup τ}{sub D} ∼ 0.5 and P{sup τ}{sub D*} ∼ -0.41 by the charged-Higgs. The integrated lepton forward-backward asymmetry (FBA) is also studied, where the SM result is anti A{sup D{sup ({sup *{sup ),τ}{sub FB}}}} ∼ -0.359(0.064), and they can be enhanced (decreased) to be anti A{sup D{sup ({sup *{sup ),τ}{sub FB}}}} ∼ -0.33(0.02). (orig.)

  19. Polarization Energies at Organic–Organic Interfaces: Impact on the Charge Separation Barrier at Donor–Acceptor Interfaces in Organic Solar Cells

    KAUST Repository

    Ryno, Sean

    2016-05-31

    We probe the energetic landscape at a model pentacene/fullerene-C60 interface to investigate the interactions between positive and negative charges, which are critical to the processes of charge separation and recombination in organic solar cells. Using a polarizable force field, we find that polarization energy, i.e. the stabilization a charge feels due to its environment, is larger at the interface than in the bulk for both a positive and a negative charge. The combination of the charge being more stabilized at the interface and the Coulomb attraction between the charges, results in a barrier to charge separation at the pentacene-C60 interface that can be in excess of 0.7 eV for static configurations of the donor and acceptor locations. However, the impact of molecular motions, i.e., the dynamics, at the interface at room temperature results in a distribution of polarization energies and in charge separation barriers that can be significantly reduced. The dynamic nature of the interface is thus critical, with the polarization energy distributions indicating that sites along the interface shift in time between favorable and unfavorable configurations for charge separation.

  20. Transient charging and discharging of spin-polarized electrons in a quantum dot

    DEFF Research Database (Denmark)

    De Souza, Fabricio; Leao, S.A.; Gester, R. M.

    2007-01-01

    We study spin-polarized transient transport in a quantum dot coupled to two ferromagnetic leads subjected to a rectangular bias voltage pulse. Time-dependent spin-resolved currents, occupations, spin accumulation, and tunneling magnetoresistance TMR are calculated using both nonequilibrium Green...

  1. Origin of traps and charge transport mechanism in hafnia

    Energy Technology Data Exchange (ETDEWEB)

    Islamov, D. R., E-mail: damir@isp.nsc.ru; Gritsenko, V. A., E-mail: grits@isp.nsc.ru [Rzhanov Institute of Semiconductor Physics, Siberian Branch of Russian Academy of Sciences, Novosibirsk 630090 (Russian Federation); Novosibirsk State University, Novosibirsk 630090 (Russian Federation); Cheng, C. H. [Department of Mechatronic Technology, National Taiwan Normal University, Taipei 106, Taiwan (China); Chin, A., E-mail: albert-achin@hotmail.com [National Chiao Tung University, Hsinchu 300, Taiwan (China)

    2014-12-01

    In this study, we demonstrated experimentally and theoretically that oxygen vacancies are responsible for the charge transport in HfO{sub 2}. Basing on the model of phonon-assisted tunneling between traps, and assuming that the electron traps are oxygen vacancies, good quantitative agreement between the experimental and theoretical data of current-voltage characteristics was achieved. The thermal trap energy of 1.25 eV in HfO{sub 2} was determined based on the charge transport experiments.

  2. Experimental characterization of the dominant multiple nodes charge collection mechanism in metal oxide-semiconductor transistors

    Science.gov (United States)

    Song, Ruiqiang; Chen, Shuming; Chi, Yaqing; Wu, Zhenyu; Liang, Bin; Chen, Jianjun; Xu, Jingyan; Hao, Peipei; Yu, Junting

    2017-06-01

    We propose an experimental method to investigate the dominant multiple node charge collection mechanism. A transistor array-based test structure is used to distinguish charge collection owing to the drift-diffusion and parasitic bipolar amplification effect. Heavy ion experimental results confirm that drift-diffusion dominates multiple node charge collection at low linear energy transfer (LET). However, the parasitic bipolar amplification effect dominates it at high LET. We also propose simple equations to determine the critical LET which may change the dominant multiple node charge collection mechanism. The calculated LET value is consistent with the heavy ion experimental results.

  3. Lithium-ion battery aging mechanisms and life model under different charging stresses

    Science.gov (United States)

    Gao, Yang; Jiang, Jiuchun; Zhang, Caiping; Zhang, Weige; Ma, Zeyu; Jiang, Yan

    2017-07-01

    The charging time-consuming and lifespan of lithium-ion batteries have always been the bottleneck for the tremendous application of electric vehicles. In this paper, cycle life tests are conducted to reveal the influence of different charging current rates and cut-off voltages on the aging mechanism of batteries. The long-term effects of charging current rates and cut-off voltages on capacity degradation and resistance increase are compared. The results show that there exists a critical charging current and a critical charging cut-off voltage. When the charging stress exceeds the critical value, battery degradation speed will be greatly accelerated. Furthermore, battery aging mechanisms at various charging currents and cut-off voltages are investigated using incremental capacity analysis. It is indicated that charging current and cut-off voltage should be reduced to retard battery degradation when the battery degrades to a certain extent. The time when the loss of electrode material accelerates is taken as the crisis to reduce charging current and the time when the loss of lithium inventory accelerates is taken as the crisis to reduce charging cut-off voltage. Moreover, an experiential model quantitatively describing the relationship between capacity degradation rate and charging stresses at different aging states is established.

  4. Atomic charge transfer-counter polarization effects determine infrared CH intensities of hydrocarbons: a quantum theory of atoms in molecules model.

    Science.gov (United States)

    Silva, Arnaldo F; Richter, Wagner E; Meneses, Helen G C; Bruns, Roy E

    2014-11-14

    Atomic charge transfer-counter polarization effects determine most of the infrared fundamental CH intensities of simple hydrocarbons, methane, ethylene, ethane, propyne, cyclopropane and allene. The quantum theory of atoms in molecules/charge-charge flux-dipole flux model predicted the values of 30 CH intensities ranging from 0 to 123 km mol(-1) with a root mean square (rms) error of only 4.2 km mol(-1) without including a specific equilibrium atomic charge term. Sums of the contributions from terms involving charge flux and/or dipole flux averaged 20.3 km mol(-1), about ten times larger than the average charge contribution of 2.0 km mol(-1). The only notable exceptions are the CH stretching and bending intensities of acetylene and two of the propyne vibrations for hydrogens bound to sp hybridized carbon atoms. Calculations were carried out at four quantum levels, MP2/6-311++G(3d,3p), MP2/cc-pVTZ, QCISD/6-311++G(3d,3p) and QCISD/cc-pVTZ. The results calculated at the QCISD level are the most accurate among the four with root mean square errors of 4.7 and 5.0 km mol(-1) for the 6-311++G(3d,3p) and cc-pVTZ basis sets. These values are close to the estimated aggregate experimental error of the hydrocarbon intensities, 4.0 km mol(-1). The atomic charge transfer-counter polarization effect is much larger than the charge effect for the results of all four quantum levels. Charge transfer-counter polarization effects are expected to also be important in vibrations of more polar molecules for which equilibrium charge contributions can be large.

  5. A salt water battery with high stability and charging rates made from solution processed conjugated polymers with polar side chains

    KAUST Repository

    Moia, Davide

    2017-11-28

    We report a neutral salt water based battery which uses p-type and n-type solution processed polymer films as the cathode and the anode of the cell. The specific capacity of the electrodes (approximately 30 mAh cm-3) is achieved via formation of bipolarons in both the p-type and n-type polymers. By engineering ethylene glycol and zwitterion based side chains attached to the polymer backbone we facilitate rapid ion transport through the non-porous polymer films. This, combined with efficient transport of electronic charge via the conjugated polymer backbones, allowed the films to maintain constant capacity at high charge and discharge rates (>1000 C-rate). The electrodes also show good stability during electrochemical cycling (less than 30% decrease in capacity over >1000 cycles) and an output voltage up to 1.4 V. The performance of these semiconducting polymers with polar side-chains demonstrates the potential of this material class for fast-charging, water based electrochemical energy storage devices.

  6. Pion-nucleon charge-exchange polarization by Gribov Reggeon calculus and the derivative rule

    International Nuclear Information System (INIS)

    Ardill, R.W.B.; Koehler, P.; Moriarty, K.J.M.

    1977-01-01

    The phenomenological consequences of the Gribov Reggeon calculus for the reaction πsup(-)+p→πdeg+n at 6 GeV/c are investigated and the polarization is obtained. The derivative rules is used to calculate the helicity flip amplitude. The results are very encouraging and would seem to indicate that the Gribov Reggeon calculus can be considered a more satisfactory approach to two-body phenomenology than the absorption model

  7. Statistical mechanics of the distribution of charge on particles in complex plasmas

    International Nuclear Information System (INIS)

    Sodha, M S; Mishra, S K; Misra, Shikha

    2011-01-01

    This paper presents an analytical study of the distribution of charge on the particles in a complex plasma; the study is based on statistical mechanics and ensures that the charge on the particles is an integral multiple of the electronic charge. The formulation incorporates both the number and energy balance of electrons/ions. Three specific cases of charging of particles have been considered, namely (i) in a plasma in the absence of electron emission from the particles, (ii) in a complex plasma in thermal equilibrium and (iii) in a complex plasma irradiated by monochromatic radiation, causing photoelectric emission of electrons from the particles. The effect of various parameters on the charge distribution has also been investigated. This paper is in reasonably good agreement with the fluctuation theory for large values of Z (Ze is the charge on a particle). It is seen that under certain conditions, a significant number of oppositely charged particles occur in the complex plasma.

  8. Effect of solvent on the charging mechanisms of poly(ethylene glycol) in droplets

    Science.gov (United States)

    Soltani, Sepideh; Oh, Myong In; Consta, Styliani

    2015-03-01

    We examine the effect of solvent on the charging mechanisms of a macromolecule in a droplet by using molecular dynamics simulations. The droplet contains excess charge that is carried by sodium ions. To investigate the principles of the charging mechanisms of a macromolecule in a droplet, we simulate aqueous and methanol droplets that contain a poly(ethylene glycol) (PEG) molecule. We find that the solvent plays a critical role in the charging mechanism and in the manner that the sodiated PEG emerges from a droplet. In the aqueous droplets, the sodiated PEG is released from the droplet while it is being charged at a droplet charge state below the Rayleigh limit. The charging of PEG occurs on the surface of the droplet. In contrast to the aqueous droplets, in the methanol droplet, the sodiated PEG resides in the interior of the droplet and it may become charged at any location in the droplet, interior or surface. The sodiated PEG emerges from the droplet by drying-out of the solvent. Even though these two mechanisms appear to be phenomenologically similar to the widely accepted ion-evaporation and charge-residue mechanisms, they have fundamental differences from those. An integral part of the mechanism that the macromolecular ions emerge from droplets is the droplet morphology. Droplet morphologies give rise to different solvation interactions between the solvent and the macromolecule. In the water-sodiated PEG system, we find the extrusion of the PEG morphology, while in methanol-sodiated droplet, we find the "pearl-on-the-necklace" morphology and the extrusion of the sodiated PEG in the last stage of the desolvation process. These findings provide insight into the mechanisms that macromolecules acquire their charge in droplets produced in electrospray ionization experiments.

  9. Stopping power and polarization induced in a plasma by a fast charged particle in circular motion

    Energy Technology Data Exchange (ETDEWEB)

    Villo-Perez, Isidro [Departamento de Electronica, Tecnologia de las Computadoras y Proyectos, Universidad Politecnica de Cartagena, Cartagena (Spain); Arista, Nestor R. [Division Colisiones Atomicas, Centro Atomico Bariloche and Instituto Balseiro, Comision Nacional de Energia Atomica, Bariloche (Argentina); Garcia-Molina, Rafael [Departamento de Fisica, Universidad de Murcia, Murcia (Spain)

    2002-03-28

    We describe the perturbation induced in a plasma by a charged particle in circular motion, analysing in detail the evolution of the induced charge, the electrostatic potential and the energy loss of the particle. We describe the initial transitory behaviour and the different ways in which convergence to final stationary solutions may be obtained depending on the basic parameters of the problem. The results for the stopping power show a resonant behaviour which may give place to large stopping enhancement values as compared with the case of particles in straight-line motion with the same linear velocity. The results also explain a resonant effect recently obtained for particles in circular motion in magnetized plasmas. (author)

  10. Effects of D-600 on intramembrane charge movement of polarized and depolarized frog muscle fibers

    OpenAIRE

    1989-01-01

    Intramembrane charge movement has been measured in frog cut skeletal muscle fibers using the triple vaseline gap voltage-clamp technique. Ionic currents were reduced using an external solution prepared with tetraethylammonium to block potassium currents, and O sodium + tetrodotoxin to abolish sodium currents. The internal solution contained 10 mM EGTA to prevent contractions. Both the internal and external solutions were prepared with impermeant anions. Linear capacitive currents were subtrac...

  11. Mechanism of the cooperative adsorption of oppositely charged nanoparticles.

    Science.gov (United States)

    Tretiakov, Konstantin V; Bishop, Kyle J M; Kowalczyk, Bartlomiej; Jaiswal, Archana; Poggi, Mark A; Grzybowski, Bartosz A

    2009-04-23

    Quartz crystal microbalance experiments were performed to study the kinetics of surface adsorption from solutions containing oppositely charged nanoparticles. A theoretical model was developed according to which formation of dense nanoparticle (NP) monolayers is driven by a cooperative process, in which the already-adsorbed NPs facilitate adsorption of NPs from solution. The kinetic rate constants change with the NP solution concentration and can be used to backtrack adsorption free energies. These energies agree with the predictions of a simple DLVO model.

  12. Mechanisms of Cell Polarity-Controlled Epithelial Homeostasis and Immunity in the Intestine.

    Science.gov (United States)

    Klunder, Leon J; Faber, Klaas Nico; Dijkstra, Gerard; van IJzendoorn, Sven C D

    2017-07-05

    Intestinal epithelial cell polarity is instrumental to maintain epithelial homeostasis and balance communications between the gut lumen and bodily tissue, thereby controlling the defense against gastrointestinal pathogens and maintenance of immune tolerance to commensal bacteria. In this review, we highlight recent advances with regard to the molecular mechanisms of cell polarity-controlled epithelial homeostasis and immunity in the human intestine. Copyright © 2017 Cold Spring Harbor Laboratory Press; all rights reserved.

  13. Study of mechanical compression of spin-polarized 3He gas

    International Nuclear Information System (INIS)

    Becker, J.; Heil, W.; Krug, B.; Leduc, M.; Meyerhoff, M.; Nacher, P.J.; Otten, E.W.; Prokscha, T.; Schearer, L.D.; Surkau, R.

    1994-01-01

    We have piloted mechanical compression of spinpolarized 3He by a titanium piston compressor. Questions of materials and design are discussed, followed by a thorough investigation of relaxation sources in the course of compression. The latter are traced mainly to regions with large surface to volume ratio, through which fast passage is demanded, therefore. We conclude from this feasibility study that polarized 3He may be compressed this way up to many bars without serious polarization losses. ((orig.))

  14. Cross-field injection of a charged, polarized, ion-electron beam

    International Nuclear Information System (INIS)

    Hamilton, G.W.

    1976-01-01

    An early idea for fueling a controlled fusion device had been the injection of a polarized mixture of ions and electrons across a magnetic field and into the device. Now, the beam intensity (several kA/cm 2 ) required for this technique is available from pulsed ion diodes. Remaining feasibility questions involve beam optics and trapping. The most obvious advantage over neutral-beam injection is avoidance of the need to produce high-energy atoms. Therefore, the technique will compete best at ion energies above 100 keV. The method appears feasible for pulsed startup of mirror machines, but not for steady-state injection into a plasma

  15. Classification of the ejection mechanisms of charged macromolecules from liquid droplets.

    Science.gov (United States)

    Consta, Styliani; Malevanets, Anatoly

    2013-01-28

    The relation between the charge state of a macromolecule and its ejection mechanism from droplets is one of the important questions in electrospray ionization methods. In this article, effects of solvent-solute interaction on the manifestation of the charge induced instability in a droplet are examined. We studied the instabilities in a prototype system of a droplet comprised of charged poly(ethylene glycol) and methanol, acetonitrile, and water solvents. We observed instances of three, previously only conjectured, [S. Consta, J. Phys. Chem. B 114, 5263 (2010)] mechanisms of macroion ejection. The mechanism of ejection of charged macroion in methanol is reminiscent of "pearl" model in polymer physics. In acetonitrile droplets, the instability manifests through formation of solvent spines around the solvated macroion. In water, we find that the macroion is ejected from the droplet through contiguous extrusion of a part of the chain. The difference in the morphology of the instabilities is attributed to the interplay between forces arising from the macroion solvation energy and the surface energy of the droplet interface. For the contiguous extrusion of a charged macromolecule from a droplet, we demonstrate that the proposed mechanism leads to ejection of the macromolecule from droplets with sizes well below the Rayleigh limit. The ejected macromolecule may hold charge significantly higher than that suggested by prevailing theories. The simulations reveal new mechanisms of macroion evaporation that differ from conventional charge residue model and ion evaporation mechanisms.

  16. Impacts of the application of the reverse charge mechanism of the value added tax

    Directory of Open Access Journals (Sweden)

    Miloš Grásgruber

    2013-01-01

    Full Text Available Reverse charge mechanism is considered to be a specific mechanism when applying the value added tax. The liability to declare and pay the output tax is transferred to the recipient of the fulfillment within the reverse charge mechanism. Since Apri1 1, 2011 there has been extended the application of the reverse charge mechanism to the domestic (home fulfillments and since this date the mechanism has been applied to the delivery of slag, waste and metal scrap, defined in the Annex 5 and to the trading with the greenhouse gas emissions allowances. Since January 1, 2012 the reverse charge mechanism has been applied also for construction and assembly works which leads to a significant extension of VAT payers which this provision may affect. The paper will evaluate the impacts of the application of the reverse charge mechanism to the provider and the recipient of the taxable fulfillments, mainly for the construction works. There will be evaluated also the impacts of the administrative burden related to the evidence of the reverse charge mechanism for the tax entity and also for the tax administrator.

  17. Pore Polarity and Charge Determine Differential Block of Kir1.1 and Kir7.1 Potassium Channels by Small-Molecule Inhibitor VU590.

    Science.gov (United States)

    Kharade, Sujay V; Sheehan, Jonathan H; Figueroa, Eric E; Meiler, Jens; Denton, Jerod S

    2017-09-01

    VU590 was the first publicly disclosed, submicromolar-affinity (IC 50 = 0.2 μ M), small-molecule inhibitor of the inward rectifier potassium (Kir) channel and diuretic target, Kir1.1. VU590 also inhibits Kir7.1 (IC 50 ∼ 8 μ M), and has been used to reveal new roles for Kir7.1 in regulation of myometrial contractility and melanocortin signaling. Here, we employed molecular modeling, mutagenesis, and patch clamp electrophysiology to elucidate the molecular mechanisms underlying VU590 inhibition of Kir1.1 and Kir7.1. Block of both channels is voltage- and K + -dependent, suggesting the VU590 binding site is located within the pore. Mutagenesis analysis in Kir1.1 revealed that asparagine 171 (N171) is the only pore-lining residue required for high-affinity block, and that substituting negatively charged residues (N171D, N171E) at this position dramatically weakens block. In contrast, substituting a negatively charged residue at the equivalent position in Kir7.1 enhances block by VU590, suggesting the VU590 binding mode is different. Interestingly, mutations of threonine 153 (T153) in Kir7.1 that reduce constrained polarity at this site (T153C, T153V, T153S) make wild-type and binding-site mutants (E149Q, A150S) more sensitive to block by VU590. The Kir7.1-T153C mutation enhances block by the structurally unrelated inhibitor VU714 but not by a higher-affinity analog ML418, suggesting that the polar side chain of T153 creates a barrier to low-affinity ligands that interact with E149 and A150. Reverse mutations in Kir1.1 suggest that this mechanism is conserved in other Kir channels. This study reveals a previously unappreciated role of membrane pore polarity in determination of Kir channel inhibitor pharmacology. Copyright © 2017 by The American Society for Pharmacology and Experimental Therapeutics.

  18. Engine Tune-up Service. Unit 2: Charging System. Student Guide. Automotive Mechanics Curriculum.

    Science.gov (United States)

    Richardson, Roger L.; Bacon, E. Miles

    This student guide is for Unit 2, Charging System, in the Engine Tune-Up Service portion of the Automotive Mechanics Curriculum. It deals with how to test the charging system. A companion review exercise book and posttests are available separately as CE 031 209-210. An introduction tells how this unit fits into the total tune-up service, defines…

  19. Spin-polarized charge transport in HgTe/CdTe quantum well topological insulator under a ferromagnetic metal strip

    Science.gov (United States)

    Wu, Zhenhua; Luo, Kun; Yu, Jiahan; Wu, Xiaobo; Lin, Liangzhong

    2018-02-01

    Electron tunneling through a single magnetic barrier in a HgTe topological insulator has been theoretically investigated. We find that the perpendicular magnetic field would not lead to spin-flip of the edge states due to the conservation of the angular moment. By tuning the magnetic field and the Fermi energy, the edge channels can be transited from switch-on states to switch-off states and the current from unpolarized states can be filtered to fully spin polarized states. These features offer us an efficient way to control charge/spin transport in a HgTe/CdTe quantum well, and pave a way to construct the nanoelectronic devices utilizing the topological edge states.

  20. New Phase Transition in the $Pr_{1-x}Ca_{x}MnO_{3}$ System Evidence for Electrical Polarization in Charge Ordered Manganites

    CERN Document Server

    Lopes, A M; Amaral, V S; Correia, G; Tomioka, Y; Tokura, Y

    2008-01-01

    In this Letter a detailed study of the electric field gradient (EFG) across the Pr1-xCaxMnO3 phase diagram and its temperature dependence is given. Clearly, distinct EFG behavior for samples outside or inside the charge order (CO) region are observed. The EFG temperature dependence evidences a new phase transition occurring over the broad CO region of the phase diagram. This transition is discontinuous and occurs at temperatures between the charge ordering and the Néel temperatures. The prominent features observed in the EFG are associated with polar atomic vibrations which eventually lead to a spontaneous local electric polarization below CO transition.

  1. Mechanism of Cyclically Polarity Reversing Solar Magnetic Cycle as ...

    Indian Academy of Sciences (India)

    tribpo

    solar dynamo mechanism that generates electric current and magnetic field by plasma flows inside the .... on the flow which makes the flow pattern twist and propagate to drive the dynamo must be strong enough to .... drive electric current in cosmos, Elsassar, a friend of Einstein, proposed that non- axisymmetric flows could ...

  2. Influence of polar medium on the reorganization energy of charge transfer between dyes in a dye sensitized film.

    Science.gov (United States)

    Vaissier, Valérie; Barnes, Piers; Kirkpatrick, James; Nelson, Jenny

    2013-04-07

    We study the kinetics of the lateral hole transfer occurring between dye molecules anchored at the surface of the metal oxide in Dye Sensitized Solar Cells (DSSC). We use Marcus' charge transfer rate equation for which we need the electronic coupling between two molecules (J) and the reorganization energy (λtot). In DSSC the medium surrounding the dyes is highly polar. This means that the contribution of the solvent to the reorganization energy cannot be neglected. Here we elaborate a method to calculate, from first principles, the total (i.e., inner- and outer-sphere) reorganization energy of hole exchange between ruthenium dyes. The influence of the solvent and of the ions in the solvent is incorporated. The inner-sphere reorganization energy depends on the nature of the dye, 0.1 eV for ruthenium dyes with CN ligands, 0.2 eV for ruthenium dyes with NCS ligands. In acetonitrile, the solvent reorganization energy contributes for at least 80% of the total giving a total reorganization energy of around 0.86 eV for ruthenium dyes with CN ligands and 0.95 eV for ruthenium dyes with NCS ligands. We use these results to estimate the rate of hole transfer within Marcus theory. We suggest that low diffusion coefficients observed experimentally may arise from the high polarity of the medium rather than by the chemical structure of the dye.

  3. Stability analysis of non-thermal complex astrofluids in the presence of polarized dust-charge fluctuations

    Science.gov (United States)

    Dutta, P.; Das, P.; Karmakar, P. K.

    2016-10-01

    The panoptic influence of plasma q-nonextensivity and dust-charge fluctuations on the gravito-electro-magnetic stability behaviour of a realistic non-thermal complex astroplasma model configuration with infinite geometrical extension is reconnoitered. It includes active viscoelasticity and dust polarization force-field effects in quasi-neutral hydrostatic equilibrium on the astrophysical fluid scales of space and time. The nontrivial linear model is simplified with the Jeans homogenization assumption (Jeans swindle, no zeroth-order force-field). It analytically and logically enables us to relax from the inclusion of large-scale inhomogeneities and of associated intrinsic complications. The role of boundary effects on the dynamical stability is assumed to be insignificant. We apply a standard technique of the Fourier formulaic plane-wave analysis over the basic cloud-structuring equations in a closed integrated form. It reduces the model Fourier algebraic equations decoupling into a unique form of cubic dispersion relation having mixed variable coefficients, which, indeed, explicitly, evolve on the diverse model plasma parameters. It is interestingly seen that the polarization and nonextensive effects directly play destabilizing roles. In contrast, the viscoelasticity and magnetic field create stabilizing effects on the instability. The pragmatic significance and applicability in the context of astro-cosmo-galactic environments are briefly indicated aboard analytic facts and introspective faults.

  4. Intermediate energy charge-exchange reactions induced by polarized 3He

    International Nuclear Information System (INIS)

    Kim, B.T.

    1998-01-01

    Spin polarization transfer is proven to be very useful in obtaining detailed information of the continuum nuclear responses. The data, taken for the (vector p,vector n) reactions, have enabled us to separate the response into the spin longitudinal and transverse components. These partial nuclear responses have been successfully used to make critical tests of nuclear structure models. In the present paper, we first summarize the results of the data and the theoretical analyses made so far. We then discuss information obtainable from the ( 3 vector He,vector t) reaction, emphasizing on the differences and similarities in comparison with the (vector p,vector n) reaction. The results of numerical calculations made for ( 3 vector He,vector t) reactions based on the microscopic distorted wave impulse approximation will also be reported. (orig.)

  5. Nonperturbative vacuum polarization effects in two-dimensional supercritical Dirac-Coulomb system I. Vacuum charge density

    Science.gov (United States)

    Davydov, A.; Sveshnikov, K.; Voronina, Yu.

    2018-01-01

    Based on the original combination of analytical methods, computer algebra tools and numerical calculations, proposed recently in Refs. 1-3, the nonperturbative vacuum polarization effects in the 2+1D supercritical Dirac-Coulomb system with Z > Zcr,1 are explored. Both the vacuum charge density ρV P(r→) and vacuum energy ℰV P are considered. The main result of the work is that in the overcritical region ℰV P turns out to be a rapidly decreasing function ˜-ηeffZ3/R with ηeff > 0 and R being the size of the external Coulomb source. Due to a lot of details of calculation the whole work is divided into two parts I and II. In the present part I, we consider the evaluation and behavior of the vacuum density ρV P, which further is used in part II for evaluation of the vacuum energy, with emphasis on the renormalization, convergence of the partial expansion for ρV P and behavior of the integral induced charge QV P in the overcritical region.

  6. Charge collection mechanisms in MOS/SOI transistors irradiated by energetic heavy ions

    International Nuclear Information System (INIS)

    Musseau, O.; Leray, J.L.; Ferlet, V.; Umbert, A.; Coic, Y.M.; Hesto, P.

    1991-01-01

    We have investigated with both experimental and numerical methods (Monte Carlo and drift-diffusion models) various charge collection mechanisms in NMOS/SOI transistors irradiated by single energetic heavy ions. Our physical interpretations of data emphasize the influence of various parasitic structures of the device. Two charge collection mechanisms are detailed: substrate funneling in buried MOS capacitor and latching of the parasitic bipolar transistor. Based on carrier transport and charge collection, the sensitivity of future scaled down CMOS/SOI technologies is finally discussed

  7. Charge dividing mechanism on resistive electrode in position-sensitive detectors

    International Nuclear Information System (INIS)

    Radeka, V.; Rehak, P.

    1978-10-01

    A complete charge-division mechanism, including both the diffusion and the electromagnetic wave propagation on resistive electrodes, is presented. The charge injected into such a transmission line divides between the two ends according to the ratio of resistancies and independently of the value of the line resistance, of the propagation mechanism and of the distribution of inductance and capacitance along the line. The shortest charge division time is achieved for Rl = 2π (L/C) 1 / 2 , where R, L, C are resistance, inductance and capacitance per unit length and l is the length of the line

  8. Polarization in K+n charge exchange scattering between 0.851 GeV/c and 1.351 GeV/c

    International Nuclear Information System (INIS)

    Watts, S.J.; Bugg, D.V.; Carter, A.A.; Coupland, M.; Eisenhandler, E.; Gibson, W.R.; Kalmus, P.I.P.; Sandhu, H.; Astbury, A.; Grayer, G.H.

    1980-01-01

    The polarization parameter for K + n charge exchange scattering has been measured at five momenta between 0.851 GeV/c and 1.351 GeV/c for centre of mass angles -0.8 < cos theta* < 0.8. Results from a phase shift analysis incorporating these results are presented. No Z* resonances are onserved. (orig.)

  9. Spectra and Charge Transport of Polar Molecular Photoactive Layers Used for Solar Cells

    Directory of Open Access Journals (Sweden)

    Yuanzuo Li

    2015-01-01

    Full Text Available The ground state structures, HOMO and LUMO energy levels, band gaps ΔH-L, ionization potentials (IP, and electron affinities (EA of three types of copolymer P1 and its derivatives P2, P3, and PBDT-BTA were investigated by using density functional theory (DFT with B3LYP and 6-31G (d basis set. On the base of optimized structures of ground states, their absorption spectra were obtained by using TD-DFT//Cam-B3LYP/6-31 G (d. Research shows that with the increasing conjugated units, HOMO energy levels increased, LUMO energy levels decreased, and band gaps decreased gradually. Moreover, their ionization potentials decreased and electron affinities increased along with the increase of conjugated chains, and absorption spectra red-shifted. In addition, the side chain has a significant effect on the properties of ground and excited states. In order to investigate the influence of conjugated units and side chain on the charge transport, their hole and electron reorganization energies were calculated, and the results indicated that Pb have a good hole transport capability. Considering the practical application, the HOMO and LUMO energy levels, band gaps, and absorption spectra under external electric field were studied, and the results proved that the external electric field has an effect on the optical and electronic properties.

  10. Modeling charged defects, dopant diffusion and activation mechanisms for TCAD simulations using kinetic Monte Carlo

    Energy Technology Data Exchange (ETDEWEB)

    Martin-Bragado, Ignacio [Synopsys Inc, 700 East Middlefield Road, Mountain View, 94043 CA (United States)]. E-mail: Ignacio.martin-bragado@synopsys.com; Tian, S. [Synopsys Inc, 700 East Middlefield Road, Mountain View, 94043 CA (United States); Johnson, M. [Synopsys Inc, 700 East Middlefield Road, Mountain View, 94043 CA (United States); Castrillo, P. [Department of Electronics, University of Valladolid Campus Miguel Delibes, Camino del Cementerio S/N, 47011 Valladolid (Spain); Pinacho, R. [Department of Electronics, University of Valladolid Campus Miguel Delibes, Camino del Cementerio S/N, 47011 Valladolid (Spain); Rubio, J. [Department of Electronics, University of Valladolid Campus Miguel Delibes, Camino del Cementerio S/N, 47011 Valladolid (Spain); Jaraiz, M. [Department of Electronics, University of Valladolid Campus Miguel Delibes, Camino del Cementerio S/N, 47011 Valladolid (Spain)

    2006-12-15

    This work will show how the kinetic Monte Carlo (KMC) technique is able to successfully model the defects and diffusion of dopants in Si-based materials for advanced microelectronic devices, especially for non-equilibrium conditions. Charge states of point defects and paired dopants are also simulated, including the dependency of the diffusivities on the Fermi level and charged particle drift coming from the electric field. The KMC method is used to simulate the diffusion of the point defects, and formation and dissolution of extended defects, whereas a quasi-atomistic approach is used to take into account the carrier densities. The simulated mechanisms include the kick-out diffusion mechanism, extended defect formation and the activation/deactivation of dopants through the formation of impurity clusters. Damage accumulation and amorphization are also taken into account. Solid phase epitaxy regrowth is included, and also the dopants redistribution during recrystallization of the amorphized regions. Regarding the charged defects, the model considers the dependencies of charge reactions, electric bias, pairing and break-up reactions according to the local Fermi level. Some aspects of the basic physical mechanisms have also been taken into consideration: how to smooth out the atomistic dopant point charge distribution, avoiding very abrupt and unphysical charge profiles and how to implement the drift of charged particles into the existing electric field. The work will also discuss the efficiency, accuracy and relevance of the method, together with its implementation in a technology computer aided design process simulator.

  11. Exploring the entrance of proton pathways in cytochrome c oxidase from Paracoccus denitrificans: surface charge, buffer capacity and redox-dependent polarity changes at the internal surface.

    Science.gov (United States)

    Kirchberg, Kristina; Michel, Hartmut; Alexiev, Ulrike

    2013-03-01

    Cytochrome c oxidase (CcO), the terminal oxidase of cellular respiration, reduces molecular oxygen to water. The mechanism of proton pumping as well as the coupling of proton and electron transfer is still not understood in this redox-linked proton pump. Eleven residues at the aqueous-exposed surfaces of CcO from Paracoccus denitrificans have been exchanged to cysteines in a two-subunit base variant to yield single reactive cysteine variants. These variants are designed to provide unique labeling sites for probes to be used in spectroscopic experiments investigating the mechanism of proton pumping in CcO. To this end we have shown that all cysteine variants are enzymatically active. Cysteine positions at the negative (N-) side of the membrane are located close to the entrance of the D- and K-proton transfer pathways that connect the N-side with the catalytic oxygen reduction site. Labeling of the pH-indicator dye fluorescein to these sites allowed us to determine the surface potential at the cytoplasmic CcO surface, which corresponds to a surface charge density of -0.5 elementary charge/1000Å(2). In addition, acid-base titrations revealed values of CcO buffer capacity. Polarity measurements of the label environment at the N-side provided (i) site-specific values indicative of a hydrophilic and a more hydrophobic environment dependent on the label position, and (ii) information on a global change to a more apolar environment upon reduction of the enzyme. Thus, the redox state of the copper and heme centers inside the hydrophobic interior of CcO affect the properties at the cytoplasmic surface. Copyright © 2012 Elsevier B.V. All rights reserved.

  12. Charge and Polarity Preferences for N-Glycosylation: A Genome-Wide In Silico Study and Its Implications Regarding Constitutive Proliferation and Adhesion of Carcinoma Cells.

    Science.gov (United States)

    Manwar Hussain, Muhammad Ramzan; Iqbal, Zeeshan; Qazi, Wajahat M; Hoessli, Daniel C

    2018-01-01

    The structural and functional diversity of the human proteome is mediated by N - and O- linked glycosylations that define the individual properties of extracellular and membrane-associated proteins. In this study, we utilized different computational tools to perform in silico based genome-wide mapping of 1,117 human proteins and unravel the contribution of both penultimate and vicinal amino acids for the asparagine-based, site-specific N -glycosylation. Our results correlate the non-canonical involvement of charge and polarity environment of classified amino acids (designated as L, O, A, P, and N groups) in the N -glycosylation process, as validated by NetNGlyc predictions, and 130 literature-reported human proteins. From our results, particular charge and polarity combinations of non-polar aliphatic, acidic, basic, and aromatic polar side chain environment of both penultimate and vicinal amino acids were found to promote the N -glycosylation process. However, the alteration in side-chain charge and polarity environment of genetic variants, particularly in the vicinity of Asn-containing epitope, may induce constitutive glycosylation (e.g., aberrant glycosylation at preferred and non-preferred sites) of membrane proteins causing constitutive proliferation and triggering epithelial-to-mesenchymal transition. The current genome-wide mapping of 1,117 proteins (2,909 asparagine residues) was used to explore charge- and polarity-based mechanistic constraints in N -glycosylation, and discuss alterations of the neoplastic phenotype that can be ascribed to N -glycosylation at preferred and non-preferred sites.

  13. Charge and Polarity Preferences for N-Glycosylation: A Genome-Wide In Silico Study and Its Implications Regarding Constitutive Proliferation and Adhesion of Carcinoma Cells

    Directory of Open Access Journals (Sweden)

    Muhammad Ramzan Manwar Hussain

    2018-02-01

    Full Text Available The structural and functional diversity of the human proteome is mediated by N- and O-linked glycosylations that define the individual properties of extracellular and membrane-associated proteins. In this study, we utilized different computational tools to perform in silico based genome-wide mapping of 1,117 human proteins and unravel the contribution of both penultimate and vicinal amino acids for the asparagine-based, site-specific N-glycosylation. Our results correlate the non-canonical involvement of charge and polarity environment of classified amino acids (designated as L, O, A, P, and N groups in the N-glycosylation process, as validated by NetNGlyc predictions, and 130 literature-reported human proteins. From our results, particular charge and polarity combinations of non-polar aliphatic, acidic, basic, and aromatic polar side chain environment of both penultimate and vicinal amino acids were found to promote the N-glycosylation process. However, the alteration in side-chain charge and polarity environment of genetic variants, particularly in the vicinity of Asn-containing epitope, may induce constitutive glycosylation (e.g., aberrant glycosylation at preferred and non-preferred sites of membrane proteins causing constitutive proliferation and triggering epithelial-to-mesenchymal transition. The current genome-wide mapping of 1,117 proteins (2,909 asparagine residues was used to explore charge- and polarity-based mechanistic constraints in N-glycosylation, and discuss alterations of the neoplastic phenotype that can be ascribed to N-glycosylation at preferred and non-preferred sites.

  14. Charge carrier transport mechanisms in perovskite CdTiO3 fibers

    Directory of Open Access Journals (Sweden)

    Z. Imran

    2014-06-01

    Full Text Available Electrical transport properties of electrospun cadmium titanate (CdTiO3 fibers have been investigated using ac and dc measurements. Air annealing of as spun fibers at 1000 °C yielded the single phase perovskite fibers having diameter ∼600 nm - 800 nm. Both the ac and dc electrical measurements were carried out at temperatures from 200 K – 420 K. The complex impedance plane plots revealed a single semicircular arc which indicates the interfacial effect due to grain boundaries of fibers. The dielectric properties obey the Maxwell-Wagner theory of interfacial polarization. In dc transport study at low voltages, data show Ohmic like behavior followed by space charge limited current (SCLC with traps at higher voltages at all temperatures (200 K – 420 K. Trap density in our fibers system is Nt = 6.27 × 1017 /cm3. Conduction mechanism in the sample is governed by 3-D variable range hopping (VRH from 200 K – 300 K. The localized density of states were found to be N(EF = 5.51 × 1021 eV−1 cm−3 at 2 V. Other VRH parameters such as hopping distance (Rhop and hopping energy (Whop were also calculated. In the high temperature range of 320 K – 420 K, conductivity follows the Arrhenius law. The activation energy found at 2 V is 0.10 eV. Temperature dependent and higher values of dielectric constant make the perovskite CdTiO3 fibers efficient material for capacitive energy storage devices.

  15. Massless charged particles: Cosmic censorship, and the third law of black hole mechanics

    Science.gov (United States)

    Fairoos, C.; Ghosh, Avirup; Sarkar, Sudipta

    2017-10-01

    The formulation of the laws of Black hole mechanics assumes the stability of black holes under perturbations in accordance with the "cosmic censorship hypothesis" (CCH). CCH prohibits the formation of a naked singularity by a physical process from a regular black hole solution with an event horizon. Earlier studies show that naked singularities can indeed be formed leading to the violation of CCH if a near-extremal black hole is injected with massive charged particles and the backreaction effects are neglected. We investigate the validity of CCH by considering the infall of charged massless particles as well as a charged null shell. We also discuss the issue of the third law of Black hole mechanics in the presence of null charged particles by considering various possibilities.

  16. One-bit photon polarization in two-photon experiments. An information mechanics perspective

    International Nuclear Information System (INIS)

    Kantor, F.W.

    1991-01-01

    In this paper is presented a detailed treatment of amount and representation of photon polarization information in the two-photon experiments of Aspect, Grangier, and Roger, seeking to test Einstein, Podolsky, and Rosen's thought experiment. Newton's mechanics, Einstein's relativistic mechanics, and quantum mechanics do not treat as fundamental the amount and representation of information in physical systems. The line of reasoning presented here was reached via Kantor's information mechanics. The information bookkeeping presented here appears to offer a simple, physical insight into what the apparatus and the photons are doing together

  17. Charge storage mechanism of nanostructured anhydrous and hydrous ruthenium-based oxides

    International Nuclear Information System (INIS)

    Sugimoto, Wataru; Yokoshima, Katsunori; Murakami, Yasushi; Takasu, Yoshio

    2006-01-01

    The charge storage mechanism of nanostructured anhydrous and hydrous ruthenium-based oxides was evaluated by various electrochemical techniques (cyclic voltammety, hydrodynamic voltammetry, chronoamperometry, and electrochemical impedance spectroscopy). The effects of various factors, such as particle size, hydrous state, and structure, on the pseudocapacitive property were characterized. The electric double layer capacitance (C dl ), adsorption related charge (C ad ), and the irreversible redox related charge (C irr ) per unit mass and surface area of electrode material has been estimated and the role of structural water within the material either in micropores or interlayer are discussed

  18. Surface-screening mechanisms in ferroelectric thin films and their effect on polarization dynamics and domain structures

    Science.gov (United States)

    Kalinin, Sergei V.; Kim, Yunseok; Fong, Dillon D.; Morozovska, Anna N.

    2018-03-01

    For over 70 years, ferroelectric materials have been one of the central research topics for condensed matter physics and material science, an interest driven both by fundamental science and applications. However, ferroelectric surfaces, the key component of ferroelectric films and nanostructures, still present a significant theoretical and even conceptual challenge. Indeed, stability of ferroelectric phase per se necessitates screening of polarization charge. At surfaces, this can lead to coupling between ferroelectric and semiconducting properties of material, or with surface (electro) chemistry, going well beyond classical models applicable for ferroelectric interfaces. In this review, we summarize recent studies of surface-screening phenomena in ferroelectrics. We provide a brief overview of the historical understanding of the physics of ferroelectric surfaces, and existing theoretical models that both introduce screening mechanisms and explore the relationship between screening and relevant aspects of ferroelectric functionalities starting from phase stability itself. Given that the majority of ferroelectrics exist in multiple-domain states, we focus on local studies of screening phenomena using scanning probe microscopy techniques. We discuss recent studies of static and dynamic phenomena on ferroelectric surfaces, as well as phenomena observed under lateral transport, light, chemical, and pressure stimuli. We also note that the need for ionic screening renders polarization switching a coupled physical–electrochemical process and discuss the non-trivial phenomena such as chaotic behavior during domain switching that stem from this. ).

  19. Surface-screening mechanisms in ferroelectric thin films and their effect on polarization dynamics and domain structures

    Energy Technology Data Exchange (ETDEWEB)

    Kalinin, Sergei V.; Kim, Yunseok; Fong, Dillon D.; Morozovska, Anna N.

    2018-01-25

    For over 70 years, ferroelectric materials have been one of the central research topics for condensed matter physics and material science, an interest driven both by fundamental science and applications. However, ferroelectric surfaces, the key component of ferroelectric films and nanostructures, still present a significant theoretical and even conceptual challenge. Indeed, stability of ferroelectric phase per se necessitates screening of polarization charge. At surfaces, this can lead to coupling between ferroelectric and semiconducting properties of material, or with surface (electro) chemistry, going well beyond classical models applicable for ferroelectric interfaces. In this review, we summarize recent studies of surface-screening phenomena in ferroelectrics. We provide a brief overview of the historical understanding of the physics of ferroelectric surfaces, and existing theoretical models that both introduce screening mechanisms and explore the relationship between screening and relevant aspects of ferroelectric functionalities starting from phase stability itself. Given that the majority of ferroelectrics exist in multiple-domain states, we focus on local studies of screening phenomena using scanning probe microscopy techniques. We discuss recent studies of static and dynamic phenomena on ferroelectric surfaces, as well as phenomena observed under lateral transport, light, chemical, and pressure stimuli. We also note that the need for ionic screening renders polarization switching a coupled physical-electrochemical process and discuss the non-trivial phenomena such as chaotic behavior during domain switching that stem from this.

  20. Dissociation mechanisms and dynamics of doubly charged CD3CN observed by PEPIPICO spectroscopy

    International Nuclear Information System (INIS)

    Harada, C.; Tada, S.; Yamamoto, K.; Senba, Y.; Yoshida, H.; Hiraya, A.; Wada, S.; Tanaka, K.; Tabayashi, K.

    2006-01-01

    Dissociation of free acetonitrile-d 3 molecule, CD 3 CN induced by core level excitation was studied near the nitrogen K-edge by time-of-flight fragment mass spectroscopy. A variety of atomic and molecular fragment cations such as D + , CD n + , C 2 D n + , and CD n CN + were detected using the effusive CD 3 CN beam. Photoelectron-photoion-photoion coincidence technique was applied to analyse the dissociation mechanisms and dynamics of doubly charged CD 3 CN 2+ following the N(1s-π * ) excitation. The charge separation mechanisms of core-excited CD 3 CN were discussed in connection with Auger final state distributions

  1. Mechanisms of impact of greenhouse gases on the Earth's ozone layer in the Polar Regions

    Science.gov (United States)

    Zadorozhny, Alexander; Dyominov, Igor

    A numerical 2-D zonally averaged interactive dynamical radiative-photochemical model of the atmosphere including aerosol physics is used to examine the impact of the greenhouse gases CO2, CH4, and N2O on the future long-term changes of the Earth's ozone layer, in particular on its expected recovery after reduction of anthropogenic discharges of chlorine and bromine compounds into the atmosphere. The model allows calculating self-consistently diabatic circu-lation, temperature, gaseous composition of the troposphere and stratosphere at latitudes from the North to South Poles, as well as distribution of sulphate aerosol particles and polar strato-spheric clouds (PSCs) of types I and II. The scenarios of expected changes of the anthropogenic pollutants for the period from 1980 through 2050 are taken from Climate Change 2001. The processes, which determine the influence of anthropogenic growth of atmospheric abun-dance of the greenhouse gases on the long-term changes of the Earth's ozone layer in the Polar Regions, have been studied in details. Expected cooling of the stratosphere caused by increases of greenhouse gases, most importantly CO2, essentially influences the ozone layer by two ways: through temperature dependencies of the gas phase reaction rates and through enhancement of polar ozone depletion via increased PSC formation. The model calculations show that a weak-ness in efficiencies of all gas phase catalytic cycles of the ozone destruction due to cooling of the stratosphere is a dominant mechanism of the impact of the greenhouse gases on the ozone layer in Antarctic as well as at the lower latitudes. This mechanism leads to a significant acceleration of the ozone layer recovery here because of the greenhouse gases growth. On the contrary, the mechanism of the impact of the greenhouse gases on the ozone through PSC modification be-gins to be more effective in Arctic in comparison with the gas phase mechanism in springs after about 2020, which leads to retard

  2. Effect of counterions on the charging mechanisms of a macromolecule in aqueous nanodrops

    Science.gov (United States)

    Sharawy, Mahmoud; Consta, Styliani

    2014-09-01

    We report the first molecular dynamics study of the effect of counterions on the charging mechanisms of a macromolecule found in an aqueous droplet that contains excess charge. To investigate the principles of the charging mechanisms of a macromolecule in a droplet, we simulate aqueous droplets that contain a poly(ethylene glycol) (PEG) molecule, sodium, and chloride ions. We study the effect of counterions by varying the concentration of the chloride ions and the temperature of the droplets. We find that the size of the droplet from which the macromolecule is released is determined by the competition between the counterions and the macromolecule for capturing the sodium ions. In droplets with radii in the range of 4 nm and smaller, [Na_2Cl]^+ ion complexes and sodium chloride aggregates are formed. The smaller the droplet the more pronounced is the formation of the NaCl aggregates. At very high temperature, in the larger droplets the Na^+ ions are distributed throughout the entire droplet. Therefore, the sodiated PEG is released with a higher average charge than from droplets with no counterions because it has access to a higher concentration of Na^+ ions. At moderately high temperature, the NaCl aggregates do not affect the final charge state of the macromolecule relative to the no-counterion droplets. We also report that regardless of the concentration of the counterions, the temperature plays a critical role in determining the nature of the droplet shape fluctuations that are responsible for the charging of a macromolecule and its extrusion from a droplet. At high temperature the macromolecule is released by the formation of a Taylor cone that transports ions onto the macromolecule. Differently, at lower temperature the Taylor cones are absent or have subsided. These findings provide insight into the mechanisms that macromolecules acquire their charge in droplets produced in electrospray ionization experiments.

  3. LO-TO splittings, effective charges and interactions in electro-optic meta-nitroaniline crystal as studied by polarized IR reflection and transmission spectra

    Science.gov (United States)

    Szostak, M. M.; Le Calvé, N.; Romain, F.; Pasquier, B.

    1994-10-01

    The polarized IR reflection spectra of the meta-nitroaniline ( m-NA) single crystal along the a, b and c crystallographic axes as well as the b and c polarized transmission spectra have been measured in the 100-400 cm -1 region. The LO-TO splitting values have been calculated from the reflection spectra by fitting them with the four parameter dielectric function. The dipole moment derivatives, relevant to dynamic effective charges, of the vibrations have also been calculated and used to check the applicability of the oriented gas model (OGM) to reflection spectra. The discrepancies from the OGM have been discussed in terms of vibronic couplings, weak hydrogen bondings (HB) and intramolecular charge transfer.

  4. Mechanism and Dynamics of Charge Transfer in Donor-Bridge-Acceptor Systems

    NARCIS (Netherlands)

    Gorczak-Vos, N.

    2016-01-01

    Photoinduced charge transfer in organic materials is a fundamental process in various biological and technological areas. Donor-bridge-acceptor (DBA) molecules are used as model systems in numerous theoretical and experimental work to systematically study and unravel the underlying mechanisms of

  5. Coupling Mechanical Deformations and Planar Cell Polarity to Create Regular Patterns in the Zebrafish Retina

    Science.gov (United States)

    Salbreux, Guillaume; Barthel, Linda K.; Raymond, Pamela A.; Lubensky, David K.

    2012-01-01

    The orderly packing and precise arrangement of epithelial cells is essential to the functioning of many tissues, and refinement of this packing during development is a central theme in animal morphogenesis. The mechanisms that determine epithelial cell shape and position, however, remain incompletely understood. Here, we investigate these mechanisms in a striking example of planar order in a vertebrate epithelium: The periodic, almost crystalline distribution of cone photoreceptors in the adult teleost fish retina. Based on observations of the emergence of photoreceptor packing near the retinal margin, we propose a mathematical model in which ordered columns of cells form as a result of coupling between planar cell polarity (PCP) and anisotropic tissue-scale mechanical stresses. This model recapitulates many observed features of cone photoreceptor organization during retinal growth and regeneration. Consistent with the model's predictions, we report a planar-polarized distribution of Crumbs2a protein in cone photoreceptors in both unperturbed and regenerated tissue. We further show that the pattern perturbations predicted by the model to occur if the imposed stresses become isotropic closely resemble defects in the cone pattern in zebrafish lrp2 mutants, in which intraocular pressure is increased, resulting in altered mechanical stress and ocular enlargement. Evidence of interactions linking PCP, cell shape, and mechanical stresses has recently emerged in a number of systems, several of which show signs of columnar cell packing akin to that described here. Our results may hence have broader relevance for the organization of cells in epithelia. Whereas earlier models have allowed only for unidirectional influences between PCP and cell mechanics, the simple, phenomenological framework that we introduce here can encompass a broad range of bidirectional feedback interactions among planar polarity, shape, and stresses; our model thus represents a conceptual framework

  6. Robust automated classification of first-motion polarities for focal mechanism determination with machine learning

    Science.gov (United States)

    Ross, Z. E.; Meier, M. A.; Hauksson, E.

    2017-12-01

    Accurate first-motion polarities are essential for determining earthquake focal mechanisms, but are difficult to measure automatically because of picking errors and signal to noise issues. Here we develop an algorithm for reliable automated classification of first-motion polarities using machine learning algorithms. A classifier is designed to identify whether the first-motion polarity is up, down, or undefined by examining the waveform data directly. We first improve the accuracy of automatic P-wave onset picks by maximizing a weighted signal/noise ratio for a suite of candidate picks around the automatic pick. We then use the waveform amplitudes before and after the optimized pick as features for the classification. We demonstrate the method's potential by training and testing the classifier on tens of thousands of hand-made first-motion picks by the Southern California Seismic Network. The classifier assigned the same polarity as chosen by an analyst in more than 94% of the records. We show that the method is generalizable to a variety of learning algorithms, including neural networks and random forest classifiers. The method is suitable for automated processing of large seismic waveform datasets, and can potentially be used in real-time applications, e.g. for improving the source characterizations of earthquake early warning algorithms.

  7. Fouling control mechanisms of demineralized water backwash: Reduction of charge screening and calcium bridging effects

    KAUST Repository

    Li, Sheng

    2011-12-01

    This paper investigates the impact of the ionic environment on the charge of colloidal natural organic matter (NOM) and ultrafiltration (UF) membranes (charge screening effect) and the calcium adsorption/bridging on new and fouled membranes (calcium bridging effect) by measuring the zeta potentials of membranes and colloidal NOM. Fouling experiments were conducted with natural water to determine whether the reduction of the charge screening effect and/or calcium bridging effect by backwashing with demineralized water can explain the observed reduction in fouling. Results show that the charge of both membranes and NOM, as measured by the zeta potential, became more negative at a lower pH and a lower concentration of electrolytes, in particular, divalent electrolytes. In addition, calcium also adsorbed onto the membranes, and consequently bridged colloidal NOM and membranes via binding with functional groups. The charge screening effect could be eliminated by flushing NOM and membranes with demineralized water, since a cation-free environment was established. However, only a limited amount of the calcium bridging connection was removed with demineralized water backwashes, so the calcium bridging effect mostly could not be eliminated. As demineralized water backwash was found to be effective in fouling control, it can be concluded that the reduction of the charge screening is the dominant mechanism for this. © 2011 Elsevier Ltd.

  8. Charge trapping and carrier transport mechanism in silicon-rich silicon oxynitride

    Energy Technology Data Exchange (ETDEWEB)

    Yu Zhenrui [Department of Electronics, INAOE, Apdo. 51, Puebla, Pue. 72000 (Mexico)]. E-mail: yinaoep@yahoo.mx; Aceves, Mariano [Department of Electronics, INAOE, Apdo. 51, Puebla, Pue. 72000 (Mexico); Carrillo, Jesus [CIDS, BUAP, Puebla, Pue. (Mexico); Lopez-Estopier, Rosa [Department of Electronics, INAOE, Apdo. 51, Puebla, Pue. 72000 (Mexico)

    2006-12-05

    The charge-trapping and carrier transport properties of silicon-rich silicon oxynitride (SRO:N) were studied. The SRO:N films were deposited by low pressure chemical vapor deposition. Infrared (IR) and transmission electron microscopic (TEM) measurements were performed to characterize their structural properties. Capacitance versus voltage and current versus voltage measurements (I-V) were used to study the charge-trapping and carrier transport mechanism. IR and TEM measurements revealed the existence of Si nanodots in SRO:N films. I-V measurements revealed that there are two conduction regimes divided by a threshold voltage V {sub T}. When the applied voltage is smaller than V {sub T}, the current is dominated by the charge transfer between the SRO:N and substrate; and in this regime only dynamic charging/discharging of the SRO:N layer is observed. When the voltage is larger than V {sub T}, the current increases rapidly and is dominated by the Poole-Frenkel mechanism; and in this regime, large permanent trapped charge density is obtained. Nitrogen incorporation significantly reduced the silicon nanodots or defects near the SRO:N/Si interface. However, a significant increase of the density of silicon nanodot in the bulk of the SRO:N layer is obtained.

  9. Charge trapping and carrier transport mechanism in silicon-rich silicon oxynitride

    International Nuclear Information System (INIS)

    Yu Zhenrui; Aceves, Mariano; Carrillo, Jesus; Lopez-Estopier, Rosa

    2006-01-01

    The charge-trapping and carrier transport properties of silicon-rich silicon oxynitride (SRO:N) were studied. The SRO:N films were deposited by low pressure chemical vapor deposition. Infrared (IR) and transmission electron microscopic (TEM) measurements were performed to characterize their structural properties. Capacitance versus voltage and current versus voltage measurements (I-V) were used to study the charge-trapping and carrier transport mechanism. IR and TEM measurements revealed the existence of Si nanodots in SRO:N films. I-V measurements revealed that there are two conduction regimes divided by a threshold voltage V T . When the applied voltage is smaller than V T , the current is dominated by the charge transfer between the SRO:N and substrate; and in this regime only dynamic charging/discharging of the SRO:N layer is observed. When the voltage is larger than V T , the current increases rapidly and is dominated by the Poole-Frenkel mechanism; and in this regime, large permanent trapped charge density is obtained. Nitrogen incorporation significantly reduced the silicon nanodots or defects near the SRO:N/Si interface. However, a significant increase of the density of silicon nanodot in the bulk of the SRO:N layer is obtained

  10. Kif3a regulates planar polarization of auditory hair cells through both ciliary and non-ciliary mechanisms

    Science.gov (United States)

    Sipe, Conor W.; Lu, Xiaowei

    2011-01-01

    Auditory hair cells represent one of the most prominent examples of epithelial planar polarity. In the auditory sensory epithelium, planar polarity of individual hair cells is defined by their V-shaped hair bundle, the mechanotransduction organelle located on the apical surface. At the tissue level, all hair cells display uniform planar polarity across the epithelium. Although it is known that tissue planar polarity is controlled by non-canonical Wnt/planar cell polarity (PCP) signaling, the hair cell-intrinsic polarity machinery that establishes the V-shape of the hair bundle is poorly understood. Here, we show that the microtubule motor subunit Kif3a regulates hair cell polarization through both ciliary and non-ciliary mechanisms. Disruption of Kif3a in the inner ear led to absence of the kinocilium, a shortened cochlear duct and flattened hair bundle morphology. Moreover, basal bodies are mispositioned along both the apicobasal and planar polarity axes of mutant hair cells, and hair bundle orientation was uncoupled from the basal body position. We show that a non-ciliary function of Kif3a regulates localized cortical activity of p21-activated kinases (PAK), which in turn controls basal body positioning in hair cells. Our results demonstrate that Kif3a-PAK signaling coordinates planar polarization of the hair bundle and the basal body in hair cells, and establish Kif3a as a key component of the hair cell-intrinsic polarity machinery, which acts in concert with the tissue polarity pathway. PMID:21752934

  11. Effect of hydrogen charging on the mechanical properties of medium strength aluminium alloys 2091 and 2014

    DEFF Research Database (Denmark)

    Bandopadhyay, A.; Ambat, Rajan; Dwarakadasa, E.S.

    1992-01-01

    Cathodic hydrogen charging in 3.5% NaCl solution altered the mechanical properties of 2091-T351 (Al-Cu-Li-Mg-Zr) determined by a slow (10(-3)/s) strain rate tensile testing technique. UTS and YS decreased in the caw of 2091-T351 and 2014-T6(Al-Cu-Mn-Si-Mg) with increase in charging current density...... surface (brittle) to the core (ductile) was observed. The presence of hydrogen increased the hardness, mostly indicative of solution strengthening and it decreased with depth confirming the existence of hydrogen concentration gradient. The effects were similar in 2014-T6, but to a slightly smaller extent....

  12. Effect of a radial space-charge field on the movement of particles in a magneto-static field and under the influence of a circularly polarized wave

    International Nuclear Information System (INIS)

    Buffa, A.

    1967-06-01

    The effect of a circularly polarized wave on a cylindrical plasma in a axial magnetostatic field and a radial space-charge field proportional to r is studied. Single particle motion is considered. The electrostatic field produces a shift in the cyclotron resonance frequency and,in case of high charge density, a radial movement of the off-resonance particles. In these conditions a radio-frequency-particle resonance is also possible called 'drift-resonance'. The drift resonance can be produced, with whistler mode, and may be employed in ion acceleration. Afterwards parametrical resonances produced by space-charge field oscillations and collisional limits of theory are studied. Cases in which ion acceleration is possible are considered on the basis of a quantitative analysis of results. (author) [fr

  13. Non-woven carbon paper as current collector for Li-ion/Li2S system: Understanding of the first charge mechanism

    International Nuclear Information System (INIS)

    Waluś, S.; Barchasz, C.; Bouchet, R.; Martin, J.-F.; Leprêtre, J.-C.; Alloin, F.

    2015-01-01

    The use of porous 3D current collectors, especially carbon-based ones, has already been demonstrated as a concept of choice as alternative to standard 2D aluminium foil in sulfur positive electrodes. In this study, we investigated non-woven carbon (NwC) as a 3D current collector for Li 2 S positive electrodes. Improved charge and discharge capacities, and capacity retention were obtained, as compared with electrodes containing Al-foil current collector. However, irrespective of the current collector used, the initial charge presents a particular and weakly reproducible voltage shape. By applying GITT and XRD measurements an electrochemical mechanism was proposed to explain the initial charge profile, in terms of equilibrium potential and polarization phenomenon. During the 1st charge, competitive oxidation reactions can be evoked involving both Li 2 S and long polysulfide intermediates (Li 2 S n ), in the main part of the charge process. While the oxidation of Li 2 S is thermodynamically favorable over the oxidation of Li 2 S n , the kinetics of the latter is much more rapid.

  14. Towards 100% spin-polarized charge-injection : The half-metallic NiMnSb/CdS interface

    NARCIS (Netherlands)

    de Wijs, G.A.; de Groot, R A

    2001-01-01

    Spin-electronics requires an electron source with a spin-polarization as high as possible. For this, half-metallic materials seem ideally suited as they exhibit 100% spin polarization. Because of its high Curie temperature and compatibility with existing semiconductor technology, NiMnSb is a most

  15. Numerical simulation study of polar low in Kara sea: developing mechanisms evaluation

    Science.gov (United States)

    Verezemskaya, Polina; Stepanenko, Victor

    2016-04-01

    The study focuses on investigating the mechanisms of interaction between potential vorticity's anomalies and latent heat release as polar low development factors. The polar low observed in Kara sea 29th -30th September 2008 is analyzed using numerical modeling (WRF ARW model) and observational data (IR cloudiness and microwave water vapor and surface wind speeds from MODIS (Aqua)). Two numerical experiments with 5 km spatial resolution were conducted with microphisical scheme turned on and off to assess the role of latent heat on vortex intensification. The quality of modelling was estimated by comparing WRF output and the satellite data. Based on reference experiment (with microphysical parameterization turned on) and observational data PL developed in vertically stable, non-baroclinic atmosphere and characterized by very low surface heat fluxes. «Dry» experiment results suggests that without latent heat source in the middle troposphere polar low intensifies slower, than in reality. In order to divide low- and upper-level forcing within PL dynamics we used attribution concept based on the quasi-geostrophic omega-equation. To ensure that QG theory is applicable for this PL case, we estimate correlation between the modeled and QG vertical speed field obtained from omega-equation using finite-differences method.

  16. Charge transport mechanisms of graphene/semiconductor Schottky barriers: A theoretical and experimental study

    International Nuclear Information System (INIS)

    Zhong, Haijian; Liu, Zhenghui; Xu, Gengzhao; Shi, Lin; Fan, Yingmin; Yang, Hui; Xu, Ke; Wang, Jianfeng; Ren, Guoqiang

    2014-01-01

    Graphene has been proposed as a material for semiconductor electronic and optoelectronic devices. Understanding the charge transport mechanisms of graphene/semiconductor Schottky barriers will be crucial for future applications. Here, we report a theoretical model to describe the transport mechanisms at the interface of graphene and semiconductors based on conventional semiconductor Schottky theory and a floating Fermi level of graphene. The contact barrier heights can be estimated through this model and be close to the values obtained from the experiments, which are lower than those of the metal/semiconductor contacts. A detailed analysis reveals that the barrier heights are as the function of the interface separations and dielectric constants, and are influenced by the interfacial states of semiconductors. Our calculations show how this behavior of lowering barrier heights arises from the Fermi level shift of graphene induced by the charge transfer owing to the unique linear electronic structure

  17. Charge transport mechanisms of graphene/semiconductor Schottky barriers: A theoretical and experimental study

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, Haijian; Liu, Zhenghui; Xu, Gengzhao; Shi, Lin; Fan, Yingmin; Yang, Hui [Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, Suzhou 215123 (China); Xu, Ke, E-mail: kxu2006@sinano.ac.cn; Wang, Jianfeng; Ren, Guoqiang [Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, Suzhou 215123 (China); Suzhou Nanowin Science and Technology Co., Ltd., Suzhou 215123 (China)

    2014-01-07

    Graphene has been proposed as a material for semiconductor electronic and optoelectronic devices. Understanding the charge transport mechanisms of graphene/semiconductor Schottky barriers will be crucial for future applications. Here, we report a theoretical model to describe the transport mechanisms at the interface of graphene and semiconductors based on conventional semiconductor Schottky theory and a floating Fermi level of graphene. The contact barrier heights can be estimated through this model and be close to the values obtained from the experiments, which are lower than those of the metal/semiconductor contacts. A detailed analysis reveals that the barrier heights are as the function of the interface separations and dielectric constants, and are influenced by the interfacial states of semiconductors. Our calculations show how this behavior of lowering barrier heights arises from the Fermi level shift of graphene induced by the charge transfer owing to the unique linear electronic structure.

  18. Quantum mechanical investigations on the role of neutral and negatively charged enamine intermediates in organocatalyzed reactions

    Energy Technology Data Exchange (ETDEWEB)

    Hubin, Pierre O., E-mail: pierre.hubin@unamur.be [Laboratoire de Physico-Chimie Informatique (PCI), Unité de Chimie Physique Théorique et Structurale, University of Namur, 61 rue de Bruxelles, 5000 Namur (Belgium); Jacquemin, Denis [Laboratoire CEISAM – UMR CNRS 6230, Université de Nantes, 2 rue de la Houssinière, BP92208, 44322 Nantes Cedex 3 (France); Institut Universitaire de France 103, Boulevard St Michel, 75005 Paris Cedex 5 (France); Leherte, Laurence; Vercauteren, Daniel P. [Laboratoire de Physico-Chimie Informatique (PCI), Unité de Chimie Physique Théorique et Structurale, University of Namur, 61 rue de Bruxelles, 5000 Namur (Belgium)

    2014-04-15

    Highlights: • M06-2X functional is suitable to model key steps of proline-catalyzed reactions. • Investigation of the proline-catalyzed aldol reaction mechanism. • Influence of water molecules on the C–C bond formation step. • Mechanism for the reaction of proline-derived enamines with benzhydrylium cations. - Abstract: The proline-catalyzed aldol reaction is the seminal example of asymmetric organocatalysis. Previous theoretical and experimental studies aimed at identifying its mechanism in order to rationalize the outcome of this reaction. Here, we focus on key steps with modern first principle methods, i.e. the M06-2X hybrid exchange–correlation functional combined to the solvation density model to account for environmental effects. In particular, different pathways leading to the formation of neutral and negatively charged enamine intermediates are investigated, and their reactivity towards two electrophiles, i.e. an aldehyde and a benzhydrylium cation, are compared. Regarding the self-aldol reaction, our calculations confirm that the neutral enamine intermediate is more reactive than the negatively charged one. For the reaction with benzhydrylium cations however, the negatively charged enamine intermediate is more reactive.

  19. Understanding the molecular mechanism of pulse current charging for stable lithium-metal batteries.

    Science.gov (United States)

    Li, Qi; Tan, Shen; Li, Linlin; Lu, Yingying; He, Yi

    2017-07-01

    High energy and safe electrochemical storage are critical components in multiple emerging fields of technologies. Rechargeable lithium-metal batteries are considered to be promising alternatives for current lithium-ion batteries, leading to as much as a 10-fold improvement in anode storage capacity (from 372 to 3860 mAh g -1 ). One of the major challenges for commercializing lithium-metal batteries is the reliability and safety issue, which is often associated with uneven lithium electrodeposition (lithium dendrites) during the charging stage of the battery cycling process. We report that stable lithium-metal batteries can be achieved by simply charging cells with square-wave pulse current. We investigated the effects of charging period and frequency as well as the mechanisms that govern this process at the molecular level. Molecular simulations were performed to study the diffusion and the solvation structure of lithium cations (Li + ) in bulk electrolyte. The model predicts that loose association between cations and anions can enhance the transport of Li + and eventually stabilize the lithium electrodeposition. We also performed galvanostatic measurements to evaluate the cycling behavior and cell lifetime under pulsed electric field and found that the cell lifetime can be more than doubled using certain pulse current waveforms. Both experimental and simulation results demonstrate that the effectiveness of pulse current charging on dendrite suppression can be optimized by choosing proper time- and frequency-dependent pulses. This work provides a molecular basis for understanding the mechanisms of pulse current charging to mitigating lithium dendrites and designing pulse current waveforms for stable lithium-metal batteries.

  20. Anisotropy and polarization in charge changing collisions of C4+ with Na(3s) and laser aligned Na(3p)

    NARCIS (Netherlands)

    Hoekstra, R; Morgenstern, R; Olson, RE

    1996-01-01

    Absolute cross sections for C3+(6-->5) emission at 465.7 nm after collisions of C4+ ions with ground state Na(3s) and laser excited aligned Na(Sp) atoms are measured over the collision energy range of 3-7 keV amu(-1). For Na(3s) polarizations are observed by measuring the linear polarization of the

  1. Effect of trap states and microstructure on charge carrier conduction mechanism through semicrystalline poly(vinyl alcohol) granular film

    Science.gov (United States)

    Das, A. K.; Bhowmik, R. N.; Meikap, A. K.

    2018-05-01

    We report a comprehensive study on hysteresis behaviour of current-voltage characteristic and impedance spectroscopy of granular semicrystalline poly(vinyl alcohol) (PVA) film. The charge carrier conduction mechanism and charge traps of granular PVA film by measuring and analyzing the temperature dependent current-voltage characteristic indicate a bi-stable electronic state in the film. A sharp transformation of charge carrier conduction mechanism from Poole-Frenkel emission to space charge limited current mechanism has been observed. An anomalous oscillatory behaviour of current has been observed due to electric pulse effect on the molecular chain of the polymer. Effect of microstructure on charge transport mechanism has been investigated from impedance spectroscopy analysis. An equivalent circuit model has been proposed to explain the result.

  2. Probabilistic joint inversion of waveforms and polarity data for double-couple focal mechanisms of local earthquakes

    Science.gov (United States)

    Wéber, Zoltán

    2018-03-01

    Estimating the mechanisms of small (M earthquakes is quite challenging. A common scenario is that neither the available polarity data alone, nor the well predictable near-station seismograms alone are sufficient to obtain reliable focal mechanism solutions for weak events. To handle this situation we introduce here a new method that jointly inverts waveforms and polarity data following a probabilistic approach. The procedure called JOWAPO (joint waveform and polarity) inversion maps the posterior probability density of the model parameters and estimates the maximum likelihood double-couple mechanism, the optimal source depth and the scalar seismic moment of the investigated event. The uncertainties of the solution are described by confidence regions. We have validated the method on two earthquakes, for which well-determined focal mechanisms are available. The validation tests show that including waveforms in the inversion considerably reduces the uncertainties of the usually poorly constrained polarity solutions. The JOWAPO method performs best when it applies waveforms from at least two seismic stations. If the number of the polarity data is large enough, even single-station JOWAPO inversion can produce usable solutions. When only a few polarities are available, however, single-station inversion may result in biased mechanisms. In this case some caution must be taken when interpreting the results. We have successfully applied the JOWAPO method to an earthquake in North Hungary, whose mechanism could not be estimated by long-period waveform inversion. Using 17 P-wave polarities and waveforms at two nearby stations, the JOWAPO method produced a well-constrained focal mechanism. The solution is very similar to those obtained previously for four other events that occurred in the same earthquake sequence. The analysed event has a strike-slip mechanism with a P axis oriented approximately along a NE-SW direction.

  3. Na-Ion Intercalation and Charge Storage Mechanism in 2D Vanadium Carbide

    Energy Technology Data Exchange (ETDEWEB)

    Bak, Seong-Min [Chemistry Division, Brookhaven National Laboratory, Upton NY 11973 USA; Qiao, Ruimin [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley CA 94720 USA; Yang, Wanli [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley CA 94720 USA; Lee, Sungsik [X-Ray Science Division, Argonne National Laboratory, Argonne IL 60439 USA; Yu, Xiqian [Institute of Physics, Chinese Academy of Science, Beijing 100190 China; Anasori, Babak [Department of Material Science and Engineering, A.J. Drexel Nanomaterials Institute, Drexel University, Philadelphia PA 19104 USA; Lee, Hungsui [Chemistry Division, Brookhaven National Laboratory, Upton NY 11973 USA; Gogotsi, Yury [Department of Material Science and Engineering, A.J. Drexel Nanomaterials Institute, Drexel University, Philadelphia PA 19104 USA; Yang, Xiao-Qing [Chemistry Division, Brookhaven National Laboratory, Upton NY 11973 USA

    2017-07-14

    Two-dimensional vanadium carbide MXene containing surface functional groups (denoted as V2CTx, where Tx are surface functional groups) was synthesized and studied as anode material for Na-ion batteries. V2CTx anode exhibits reversible charge storage with good cycling stability and high rate capability through electrochemical test. The charge storage mechanism of V2CTx material during Na+ intercalation/deintercalation and the redox reaction of vanadium were studied using a combination of synchrotron based X-ray diffraction (XRD), hard X-ray absorption near edge spectroscopy (XANES) and soft X-ray absorption spectroscopy (sXAS). Experimental evidence of a major contribution of redox reaction of vanadium to the charge storage and the reversible capacity of V2CTx during sodiation/desodiation process have been provided through V K-edge XANES and V L2,3-edge sXAS results. A correlation between the CO32- content and Na+ intercalation/deintercalation states in the V2CTx electrode observed from C and O K-edge in sXAS results imply that some additional charge storage reactions may take place between the Na+-intercalated V2CTx and the carbonate based non-aqueous electrolyte. The results of this study will provide valuable information for the further studies on V2CTx as anode material for Na-ion batteries and capacitors.

  4. Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics

    Directory of Open Access Journals (Sweden)

    Shutthanandan V

    2008-06-01

    Full Text Available Abstract Molybdenum disulfide (MoS2, a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS2 is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia. The present work was performed to understand thermal oxidation and metal-insertion processes of molybdenite surfaces. The analysis was performed using atomic force microscopy (AFM, scanning electron microscopy (SEM, transmission electron microscopy (TEM, Rutherford backscattering spectrometry (RBS, and nuclear reaction analysis (NRA. Structural studies using SEM and TEM indicate the local-disordering of the structure as a result of charge-transfer process between the inserted lithium and the molybdenite layer. Selected area electron diffraction measurements indicate the large variations in the diffusivity of lithium confirming that the charge-transfer is different along and perpendicular to the layers in molybdenite. Thermal heating of molybenite surface in air at 400°C induces surface oxidation, which is slow during the first hour of heating and then increases significantly. The SEM results indicate that the crystals formed on the molybdenite surface as a result of thermal oxidation exhibit regular thin-elongated shape. The average size and density of the crystals on the surface is dependent on the time of annealing; smaller size and high density during the first one-hour and

  5. Transport of Heat and Charge in Electromagnetic Metrology Based on Nonequilibrium Statistical Mechanics

    Directory of Open Access Journals (Sweden)

    James Baker-Jarvis

    2009-11-01

    Full Text Available Current research is probing transport on ever smaller scales. Modeling of the electromagnetic interaction with nanoparticles or small collections of dipoles and its associated energy transport and nonequilibrium characteristics requires a detailed understanding of transport properties. The goal of this paper is to use a nonequilibrium statistical-mechanical method to obtain exact time-correlation functions, fluctuation-dissipation theorems (FD, heat and charge transport, and associated transport expressions under electromagnetic driving. We extend the time-symmetric Robertson statistical-mechanical theory to study the exact time evolution of relevant variables and entropy rate in the electromagnetic interaction with materials. In this exact statistical-mechanical theory, a generalized canonical density is used to define an entropy in terms of a set of relevant variables and associated Lagrange multipliers. Then the entropy production rate are defined through the relevant variables. The influence of the nonrelevant variables enter the equations through the projection-like operator and thereby influences the entropy. We present applications to the response functions for the electrical and thermal conductivity, specific heat, generalized temperature, Boltzmann’s constant, and noise. The analysis can be performed either classically or quantum-mechanically, and there are only a few modifications in transferring between the approaches. As an application we study the energy, generalized temperature, and charge transport equations that are valid in nonequilibrium and relate it to heat flow and temperature relations in equilibrium states.

  6. Charge exchange as a recombination mechanism in high-temperature plasmas

    International Nuclear Information System (INIS)

    Hulse, R.A.; Post, D.E.; Mikkelsen, D.R.

    1980-03-01

    Charge exchange with neutral hydrogen is examined as a recombination mechanism for multi-charged impurity ions present in high-temperature fusion plasmas. At sufficiently low electron densities, fluxes of atomic hydrogen produced by either the injection of neutral heating beams or the background of thermal neutrals can yield an important or even dominant recombination process for such ions. Equilibrium results are given for selected impurity elements showing the altered ionization balance and radiative cooling rate produced by the presence of various neutral populations. A notable result is that the stripping of impurities to relatively non-radiative ionization states with increasing electron temperature can be postponed or entirely prevented by the application of intense neutral beam heating power. A time dependent calculation modelling the behavior of iron in recent PLT tokamak high power neutral beam heating experiments is also presented

  7. Charge transport mechanism in p-type copper ion containing triazine thiolate metallopolymer thin film devices

    Science.gov (United States)

    K, Deepak; Roy, Amit; Anjaneyulu, P.; Kandaiah, Sakthivel; Pinjare, Sampatrao L.

    2017-10-01

    The charge transport mechanism in copper ions containing 1,3,5-Triazine-2,4,6-trithiolate (CuTCA) based polymer device in sandwich (Ag/CuTCA/Cu) geometry is studied. The current-voltage (I-V) characteristics of the metallopolymer CuTCA device have shown a transition in the charge transport mechanism from Ohmic to Space-charge limited conduction when temperature and voltage are varied. The carriers in CuTCA devices exhibit hopping transport, in which carriers hop from one site to the other. The hole mobility in this polymer device is found to be dependent on electric field E ( μpα√{E } ) and temperature, which suggests that the polymer has inherent disorder. The electric-field coefficient γ and zero-field mobility μ0 are temperature dependent. The values of mobility and activation energies are estimated from temperature (90-140 K) dependent charge transport studies and found to be in the range of 1 × 10-11-8 × 10-12 m2/(V s) and 16.5 meV, respectively. Temperature dependent electric-field coefficient γ is in the order of 17.8 × 10-4 (m/V)1/2, and the value of zero-field mobility μ0 is in the order of 1.2 × 10-11 m2/(V s) at 140 K. A constant phase element (Q) is used to model the device parameters, which are extracted using the Impedance spectroscopy technique. The bandgap of the polymer is estimated to be 2.6 eV from UV-Vis reflectance spectra.

  8. Quantum mechanical systems interacting with different polarizations of gravitational waves in noncommutative phase space

    Science.gov (United States)

    Saha, Anirban; Gangopadhyay, Sunandan; Saha, Swarup

    2018-02-01

    Owing to the extreme smallness of any noncommutative scale that may exist in nature, both in the spatial and momentum sector of the quantum phase space, a credible possibility of their detection lies in the gravitational wave (GW) detection scenario, where one effectively probes the relative length-scale variations ˜O [10-20-10-23] . With this motivation, we have theoretically constructed how a free particle and a harmonic oscillator will respond to linearly and circularly polarized gravitational waves if their quantum mechanical phase space has a noncommutative structure. We critically analyze the formal solutions which show resonance behavior in the responses of both free particle and HO systems to GW with both kind of polarizations. We discuss the possible implications of these solutions in detecting noncommutativity in a GW detection experiment. We use the currently available upper-bound estimates on various noncommutative parameters to anticipate the relative importance of various terms in the solutions. We also argue how the quantum harmonic oscillator system we considered here can be very relevant in the context of the resonant bar detectors of GW which are already operational.

  9. State of Charge Dependent Mechanical Integrity Behavior of 18650 Lithium-ion Batteries

    Science.gov (United States)

    Xu, Jun; Liu, Binghe; Hu, Dayong

    2016-01-01

    Understanding the mechanism of mechanical deformation/stress-induced electrical failure of lithium–ion batteries (LIBs) is important in crash-safety design of power LIBs. The state of charge (SOC) of LIBs is a critical factor in their electrochemical performance; however, the influence of SOC with mechanical integrity of LIBs remains unclear. This study investigates the electrochemical failure behaviors of LIBs with various SOCs under both compression and bending loadings, underpinned by the short circuit phenomenon. Mechanical behaviors of the whole LIB body, which is regarded as an intact structure, were analyzed in terms of structure stiffness. Results showed that the mechanical behaviors of LIBs depend highly on SOC. Experimental verification on the cathode and anode sheet compression tests show that higher SOC with more lithium inserted in the anode leads to higher structure stiffness. In the bending tests, failure strain upon occurrence of short circuit has an inverse linear relationship with the SOC value. These results may shed light on the fundamental physical mechanism of mechanical integrity LIBs in relation to inherent electrochemical status. PMID:26911922

  10. Indirect mechanisms in electron-impact ionization of multiply charged ions

    International Nuclear Information System (INIS)

    Phaneuf, R.A.; Gregory, D.C.

    1986-09-01

    The important role of indirect-ionization mechanisms in electron-impact ionization of multiply charged ions has been emphasized by some recent experiments conducted with the ORNL-ECR multicharged ion source. Illustrative examples of investigations of the Mg-isoelectronic and Fe-isonuclear sequences are presented and compared with the results of detailed theoretical calculations. New experimental data is also presented concerning the role of resonance effects in the ionization of Li-like O 5+ and Na-like Fe 15+ ions

  11. Temperature-dependent charge transport mechanisms in carbon sphere/polyaniline composite

    Science.gov (United States)

    Nieves, Cesar A.; Martinez, Luis M.; Meléndez, Anamaris; Ortiz, Margarita; Ramos, Idalia; Pinto, Nicholas J.; Zimbovskaya, Natalya

    2017-12-01

    Charge transport in the temperature range 80 K polyaniline (PANi). PANi was synthesized via the oxidative polymerization of aniline with ammonium peroxydisulfate (APS) in acidic media. The CS/PANi composite was prepared by coating the spheres with a thin polyaniline (PANi) film doped with hydrochloric acid (HCl) in situ during the polymerization process. Temperature dependent conductivity measurements show that three dimensional variable range hopping of electrons between polymeric chains in PANi-filled gaps between CS is the predominant transport mechanism through CS/PANi composites. The high conductivity of the CS/PANi composite makes the material attractive for the fabrication of devices and sensors.

  12. Effect of CdS nanocrystals on charge transport mechanism in poly(3-hexylthiophene)

    Science.gov (United States)

    Khan, Mohd Taukeer; Almohammedi, Abdullah

    2017-08-01

    The present manuscript demonstrates the optical and electrical characteristics of poly(3-hexylthiophene) (P3HT) and cadmium sulphide (CdS) hybrid nanocomposites. Optical results suggest that there is a formation of charge transfer complex (CTC) between host P3HT and guest CdS nanocrystals (NCs). Electrical properties of P3HT and P3HT-CdS thin films have been studied in hole only device configurations at different temperatures (290 K-150 K), and results were analysed by the space charge limited conduction mechanism. Density of traps and characteristic trap energy increase on incorporation of inorganic NCs in the polymer matrix, which might be due to the additional favourable energy states created by CdS NCs in the band gap of P3HT. These additional trap states assist charge carriers to move quicker which results in enhancement of hole mobility from 7 × 10-6 to 5.5 × 10-5 cm2/V s in nanocomposites. These results suggest that the P3HT-CdS hybrid system has desirable optical and electrical properties for its applications to photovoltaics devices.

  13. Preliminary results on the mechanism of charge equilibration in light ion collisions

    International Nuclear Information System (INIS)

    Pop, A.; Berceanu, I.; Duma, M.; Moisa, D.; Petrovici, M.; Simion, V.; Del Zoppo, A.; Coniglione, R.; Piatelli, P.; Sapienza, P.

    1998-01-01

    The charge equilibration process has been investigated in the collisions of 19 F(136.9 MeV) with 12 C, 27 Al and 27 Al(140.14 MeV) with 12 C, 27 Al. The measurements have been carried out with the experimental setup DRACULA using the two twin position sensitive ionization chambers for atomic number identification. The mass of the main reaction products has been determined by TOF measurements with two start and stop parallel plate avalanche detectors (PPAD). The data have been corrected for particle evaporation.The average mass and the average charge evaporated by different isotopes with A ≤40 are evaluated on the basis of statistical model calculations with the code PACE2, as a function of the excitation energy. This dependence has been used in an iterative procedure in order to obtain primary distributions. The conditional variances of the secondary and primary experimental charge distributions, compared with the quantum mechanical (QM) and statistical (S) limits, which have been the two challenging theoretical approaches used to describe this process, are presented. In spite of the rough assumptions used in the calculations (especially in the case of light systems) the experimental data lie systematically closer to the QM limit. (authors)

  14. Mechanical behavior of NiTi arc wires under pseudoelastic cycling and cathodically hydrogen charging

    Science.gov (United States)

    Sarraj, R.; Hassine, T.; Gamaoun, F.

    2018-01-01

    NiTi wires are mainly used to design orthodontic devices. However, they may be susceptible to a delayed fracture while they are submitted to cyclic loading with the presence of hydrogen in the oral cavity. Hydrogen may cause the embrittlement of the structure, leading to lower ductility and to a change in transformation behavior. The aim of the present study is to predict the NiTi behavior under cyclic loading with hydrogen charging. One the one hand, samples are submitted to superelastic cyclic loading, which results in investigating their performance degradations. On the other hand, after hydrogen charging, cyclic tensile aging tests are carried out on NiTi orthodontic wires at room temperature in the air. During cyclic loading, we notice that the critical stress for the martensite transformation evolves, the residual strain is accumulated in the structure and the hysteresis loop changes. Thus, via this work, we can assume that the embrittlement is due to the diffusion of hydrogen and the generation of dislocations after aging. The evolution of mechanical properties of specimens becomes more significant with hydrogen charging rather than without it.

  15. Mechanisms of charge-state determination in hydrogen-based impurity complexes in crystalline germanium

    International Nuclear Information System (INIS)

    Oliva, J.

    1984-01-01

    Recent experiments suggest that hydrogen may become bound to, and then tunnel around, substitutional carbon, silicon, or oxygen impurities in crystalline germanium. All these complexes are electrically active; [H,C] and [H,Si] are shallow acceptors, while [H,O] is a shallow donor. This paper attempts to elucidate the basic physical mechanisms controlling the charge state of such complexes as a function of the choice of the substitutional atom. A minimal-basis Bethe-cluster approach is used with the cluster comprising the ten-atom tetrahedral cage (including the substitutional atom) and enclosed H site, the latter coupled to all ten atoms of the cage. The important local correlation effect which tends to favor single occupation of the H site is modeled with a Hubbard-type term at that site. The charge state of the [H,C], [H,Si], and [H,O] complexes is associated with double occupation of the H site. Four aspects of the model are involved in favoring double occupation: (1) a low value of the H-site energy, (2) a reduced local correlation effect at the H site, (3) small hybridization between the H site and cage, and (4) a low value of the substitutional-site energy relative to that of the host. Results for the charge state for H at the cage center and for H near the substitutional atom are discussed in detail. Several useful formal results for local self-energies and local Green's functions are presented

  16. Charging effect in Au nanoparticle memory device with biomolecule binding mechanism.

    Science.gov (United States)

    Jung, Sung Mok; Kim, Hyung-Jun; Kim, Bong-Jin; Yoon, Tae-Sik; Kim, Yong-Sang; Lee, Hyun Ho

    2011-07-01

    Organic memory device having gold nanoparticle (Au NPs) has been introduced in the structure of metal-pentacene-insulator-silicon (MPIS) capacitor device, where the Au NPs layer was formed by a new bonding method. Biomolecule binding mechanism between streptavidin and biotin was used as a strong binding method for the formation of monolayered Au NPs on polymeric dielectric of poly vinyl alcohol (PVA). The self-assembled Au NPs was functioned to show storages of charge in the MPIS device. The binding by streptavidin and biotin was confirmed by AFM and UV-VIS. The UV-VIS absorption of the Au NPs was varied at 515 nm and 525 nm depending on the coating of streptavidin. The AFM image showed no formation of multi-stacked layers of the streptavidin-capped Au NPs on biotin-NHS layer. Capacitance-voltage (C-V) performance of the memory device was measured to investigate the charging effect from Au NPs. In addition, charge retention by the Au NPs storage was tested to show 10,000 s in the C-V curve.

  17. Measurement of the polarized forward-backward asymmetry of Z{sup 0} {yields} b{bar b} using a lifetime tag and momentum-weighted track charge

    Energy Technology Data Exchange (ETDEWEB)

    The SLD Collaboration

    1995-08-01

    We present a direct measurement of the parity-violating parameter A{sub b} by analyzing the left-right forward-backward asymmetry of b quarks in e{sup +}e{sup {minus}} {yields} Z{sup o} {yields} b{bar b}. The SLD experiment observes hadronic decays of Z{sup o} bosons produced at resonance in collisions of longitudinally polarized electrons and unpolarized positrons at the SLC. Heavy flavor decays of the Z{sup o} are identified by taking advantage of the long lifetime of B hadrons, the small, stable SLC beam spot, and precise tracking from SLD. The asymmetry A{sub b} is measured with a self-calibrating technique employing momentum-weighted track charge from both hemispheres in the tagged events. From our 1994--1995 sample of 3.6 pb{sup {minus}1} of e{sup +}e{sup {minus}} annihilation data with a luminosity-weighted average e{sup {minus}} polarization of 77.3%, and our 1993 sample of 1.8 pb{sup {minus}1} with a luminosity-weighted polarization of 63.1%, we obtain A{sub b}(preliminary) = 0.843 {plus_minus} 0.046(stat.) {plus_minus} 0.051(syst.).

  18. Electrokinetic effect combined with surface-charge assumption: a possible generation mechanism of coseismic EM signals

    Science.gov (United States)

    Ren, Hengxin; Wen, Jian; Huang, Qinghua; Chen, Xiaofei

    2015-02-01

    According to field observations, electromagnetic (EM) signals accompanying seismic waves can be recorded. The orders of magnitude of observed coseismic electric and magnetic signals associated with earthquakes are usually around 1 to 101 mV km-1 and 10-2 to 1 nT, respectively. In this paper, we carry out numerical simulation of coseismic EM signals associated with seismic waves due to electrokinetic effect and compare with field observations. The seismic source is represented by a finite fault measuring 15 × 9 km2 with a max slip displacement 1.5 m, corresponding to a Mw 5.9 earthquake. While using the EM surface boundary condition of continuous horizontal EM components, the magnetic signals only accompany the late-arriving S waves at receiver near the ground surface. This is obviously different from field observations. Thus, we adopt another EM surface boundary condition which assumes the ground surface carries surface charge. For the used half-space model, a surface-charge density magnitude |Qsc| in excess of 10-4 C m-2 is sufficient to make horizontal magnetic components clearly show up at the whole time duration of seismic waves. When |Qsc| increases, the contribution of surface-charge density to coseismic EM signals becomes more and more dominant comparing with that of the seismically induced streaming-current. We estimate the Qsc expected at the Earth's surface might be a value between -5 × 10-4 and -0.1 C m-2 by the comparison between numerical results and field observations. The vertical magnetic signals only accompany the late-arriving seismic waves, because they are theoretically only induced by SH wave. The field observation results of vertical magnetic signals may be resulted from the scattering effect or the seismic dynamo effect. We conclude that electrokinetic effect combined with surface-charge assumption is one possible generation mechanism of the observed coseismic EM signals.

  19. Nonlinear effects at volume charge polarization and calculation of the structure radiation changes in the crystals with hydrogen bonds

    International Nuclear Information System (INIS)

    Tonkonogov, M.P.; Medvedev, V.Ya.

    2003-01-01

    The formulas for volume charge distribution, complex permittivity, static dielectric constant for the crystals with hydrogen bonds are proposed. With help of the formulas the structure defect concentration, relaxation energy of relaxators were calculated for important electronic and optoelectronic materials as mica, KDP and DKDP crystals, gypsum, talk

  20. Injection-modulated polarity conversion by charge carrier density control via a self-assembled monolayer for all-solution-processed organic field-effect transistors

    Science.gov (United States)

    Roh, Jeongkyun; Lee, Taesoo; Kang, Chan-Mo; Kwak, Jeonghun; Lang, Philippe; Horowitz, Gilles; Kim, Hyeok; Lee, Changhee

    2017-04-01

    We demonstrated modulation of charge carrier densities in all-solution-processed organic field-effect transistors (OFETs) by modifying the injection properties with self-assembled monolayers (SAMs). The all-solution-processed OFETs based on an n-type polymer with inkjet-printed Ag electrodes were fabricated as a test platform, and the injection properties were modified by the SAMs. Two types of SAMs with different dipole direction, thiophenol (TP) and pentafluorobenzene thiol (PFBT) were employed, modifying the work function of the inkjet-printed Ag (4.9 eV) to 4.66 eV and 5.24 eV with TP and PFBT treatments, respectively. The charge carrier densities were controlled by the SAM treatment in both dominant and non-dominant carrier-channel regimes. This work demonstrates that control of the charge carrier densities can be efficiently achieved by modifying the injection property with SAM treatment; thus, this approach can achieve polarity conversion of the OFETs.

  1. Charged Higgs production from polarized top-quark decay in the 2HDM considering the general-mass variable-flavor-number scheme

    Science.gov (United States)

    Abbaspour, S.; Mohammad Moosavi Nejad, S.

    2018-05-01

    Charged Higgs bosons are predicted by some non-minimal Higgs scenarios, such as models containing Higgs triplets and two-Higgs-doublet models, so that the experimental observation of these bosons would indicate physics beyond the Standard Model. In the present work, we introduce a channel to indirect search for the charged Higgses through the hadronic decay of polarized top quarks where a top quark decays into a charged Higgs H+ and a bottom-flavored meson B via the hadronization process of the produced bottom quark, t (↑) →H+ + b (→ B + jet). To obtain the energy spectrum of produced B-mesons we present, for the first time, an analytical expression for the O (αs) corrections to the differential decay width of the process t →H+ b in presence of a massive b-quark in the General-Mass Variable-Flavor-Number (GM-VFN) scheme. We find that the most reliable predictions for the B-hadron energy spectrum are made in the GM-VFN scheme, specifically, when the Type-II 2HDM scenario is concerned.

  2. Account of magnetic field effects of polarized proton target on charged particle trajectories in experiments with magnetic spectrometers

    International Nuclear Information System (INIS)

    Telegin, Yu.N.; Ranyuk, Yu.N.; Karnaukhov, I.M.; Lukhanin, A.A.; Sporov, E.A.

    1980-01-01

    Some effects of the influence of magnetic field of a polarized proton target (PPT) on trajectories of secondary particles in experiments using magnetic spectrometers are considered. It is shown that these effects can be eliminated by the target shift relatively to the spectrometer rotation axis and variation of the spectrometer installation angle. Numerical calculations of the correction values were performed for emitted particle momenta of 100-800 MeB/s and working intensity of the H 0 magnetic field H 0 =27 kG. The influence of the PPT magnetic field on the functions of angular and energy resolution in the γp→π + n experiment is investigated. The results obtained can be used in experiments with a polarized proton target

  3. Spin observables in charged pion photo-production from polarized neutrons in solid HD at Jefferson Lab

    Energy Technology Data Exchange (ETDEWEB)

    Kageya, Tsuneo [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Ho, Dao [Carnegie Mellon Univ., Pittsburgh, PA (United States); Peng, Peng [Univ. of Virginia, Charlottesville, VA (United States); Klein, Franz [George Washington Univ., Washington, DC (United States); Sandorfi, Andrew M. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Schumacher, Reinhard A. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2018-04-01

    E asymmetries have been extracted from double-polarizationexperiments in Hall-B of the Thomas Jefferson National Accelerator Facility (JLab). Results have been obtained from the E06-101 (g14) experiment, using circularly polarized photon beams, longitudinally polarized Deuterons in solid HD targets, and the CEBAF Large Acceptance Spectrometer (CLAS). The results cover a range inW from 1.48 to 2.32 GeV. Three independent analyses, using distinctly different methods, have been combined to obtain the final values, which have been published recently. Partial wave analyses (PWA), which have had to rely on a sparse neutron data base, havebeen significantly changed with the inclusion of these g14 asymmetries.

  4. Charge Transfer Mechanism in Titanium-Doped Microporous Silica for Photocatalytic Water-Splitting Applications

    Directory of Open Access Journals (Sweden)

    Wendi Sapp

    2016-02-01

    Full Text Available Solar energy conversion into chemical form is possible using artificial means. One example of a highly-efficient fuel is solar energy used to split water into oxygen and hydrogen. Efficient photocatalytic water-splitting remains an open challenge for researchers across the globe. Despite significant progress, several aspects of the reaction, including the charge transfer mechanism, are not fully clear. Density functional theory combined with density matrix equations of motion were used to identify and characterize the charge transfer mechanism involved in the dissociation of water. A simulated porous silica substrate, using periodic boundary conditions, with Ti4+ ions embedded on the inner pore wall was found to contain electron and hole trap states that could facilitate a chemical reaction. A trap state was located within the silica substrate that lengthened relaxation time, which may favor a chemical reaction. A chemical reaction would have to occur within the window of photoexcitation; therefore, the existence of a trapping state may encourage a chemical reaction. This provides evidence that the silica substrate plays an integral part in the electron/hole dynamics of the system, leading to the conclusion that both components (photoactive materials and support of heterogeneous catalytic systems are important in optimization of catalytic efficiency.

  5. The spin-charge-family-theory unifies spin and charges and offers the mechanism for generating families and scalar fields

    International Nuclear Information System (INIS)

    Mankoc-Borstnik, N.S.

    2011-01-01

    The theory unifying the spin, charges and families predicts the number of families and their properties, explains the origin of the scalar and vector gauge fields and their properties, manifesting at low energies effectively the Higgs, Yukawa coupling and known gauge fields, respectively. The theory predicts that the fourth family could possibly be observed at the LHC, while the stable fifth family baryons might constitute the dark matter. It also predicts that searching for scalar fields will show up the differences between the Higgs and the scalar fields

  6. Visible-light photocatalysis in Cu2Se nanowires with exposed {111} facets and charge separation between (111) and (1[combining macron]1[combining macron]1[combining macron]) polar surfaces.

    Science.gov (United States)

    Liu, Bin; Ning, Lichao; Zhao, Hua; Zhang, Congjie; Yang, Heqing; Liu, Shengzhong Frank

    2015-05-28

    The search for active narrow band gap semiconductor photocatalysts that directly split water or degrade organic pollutants under solar irradiation remains an open issue. We synthesized Cu2Se nanowires with exposed {111} facets using ethanol and glycerol as morphology controlling agents. The {111} facets were found to be the active facets for decomposing organic contaminants in the entire solar spectrum. Based on the polar structure of the Cu2Se {111} facets, a charge separation model between polar (111) and (1[combining macron]1[combining macron]1[combining macron]) surfaces is proposed. The internal electric field between polar (111) and (1[combining macron]1[combining macron]1[combining macron]) surfaces created by spontaneous polarization drives charge separation. The reduction and oxidation reactions occur on the positive (111) and negative (1[combining macron]1[combining macron]1[combining macron]) polar surfaces, respectively. This suggests the surface-engineering of narrow band gap semiconductors as a strategy to fabricate photocatalysts with high reactivity in the entire solar spectrum. The charge separation model can deepen the understanding of charge transfer in other semiconductor nanocrystals with high photocatalytic activities and offer guidance to design more effective photocatalysts as well as new types of solar cells, photoelectrodes and photoelectric devices.

  7. Possible Mechanism for the Generation of a Fundamental Unit of Charge (long version)

    Energy Technology Data Exchange (ETDEWEB)

    Lestone, John Paul [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-06-16

    Various methods for calculating particle-emission rates from hot systems are reviewed. Semi-classically derived photon-emission rates often contain the term exp(-ε/T) which needs to be replaced with the corresponding Planckian factor of [exp(-ε/T)-1]-1 to obtain the correct rate. This replacement is associated with the existence of stimulated emission. Simple arguments are used to demonstrate that black holes can also undergo stimulated emission, as previously determined by others. We extend these concepts to fundamental particles, and assume they can be stimulated to emit virtual photons with a cross section of πλ2, in the case of an isolated particle when the incident virtual-photon energy is < 2πmc2. Stimulated-virtual photons can be exchanged with other particles generating a force. With the inclusion of near-field effects, the model choices presented give a calculated fundamental unit of charge of 1.6022x10-19 C. If these choices are corroborated by detailed calculations then an understanding of the numerical value of the fine structure constant may emerge. The present study suggests charge might be an emergent property generated by a simple interaction mechanism between point-like particles and the electromagnetic vacuum, similar to the process that generates the Lamb shift.

  8. Polar Bear Optimization Algorithm: Meta-Heuristic with Fast Population Movement and Dynamic Birth and Death Mechanism

    Directory of Open Access Journals (Sweden)

    Dawid Połap

    2017-09-01

    Full Text Available In the proposed article, we present a nature-inspired optimization algorithm, which we called Polar Bear Optimization Algorithm (PBO. The inspiration to develop the algorithm comes from the way polar bears hunt to survive in harsh arctic conditions. These carnivorous mammals are active all year round. Frosty climate, unfavorable to other animals, has made polar bears adapt to the specific mode of exploration and hunting in large areas, not only over ice but also water. The proposed novel mathematical model of the way polar bears move in the search for food and hunt can be a valuable method of optimization for various theoretical and practical problems. Optimization is very similar to nature, similarly to search for optimal solutions for mathematical models animals search for optimal conditions to develop in their natural environments. In this method. we have used a model of polar bear behaviors as a search engine for optimal solutions. Proposed simulated adaptation to harsh winter conditions is an advantage for local and global search, while birth and death mechanism controls the population. Proposed PBO was evaluated and compared to other meta-heuristic algorithms using sample test functions and some classical engineering problems. Experimental research results were compared to other algorithms and analyzed using various parameters. The analysis allowed us to identify the leading advantages which are rapid recognition of the area by the relevant population and efficient birth and death mechanism to improve global and local search within the solution space.

  9. A simple distributed mechanism for accounting system self-configuration in next-generation charging and billing

    NARCIS (Netherlands)

    Kühne, R.; Huitema, G.B.; Carle, G.

    2011-01-01

    Modern communication systems are becoming increasingly dynamic and complex. In this article a novel mechanism for next generation charging and billing is presented that enables self-configurability for accounting systems consisting of heterogeneous components. The mechanism is required to be simple,

  10. Polarization and charge-transfer effect on the transport properties in two-dimensional electron gases/LaNiO3 heterostructure

    Science.gov (United States)

    Chen, M. J.; Ning, X. K.; Wang, Z. J.; Liu, P.; Wang, S. F.; Wang, J. L.; Fu, G. S.; Ma, S.; Liu, W.; Zhang, Z. D.

    2018-01-01

    The film thickness dependent transport properties of the LaNiO3 (LNO) layer epitaxially grown on LaAlO3/SrTiO3 (LAO) 2-dimensional electronic gas (2DEG) have been investigated. The ultrathin LNO films grown on the 2DEG have a sheet resistance below the values of h/e2 in all temperature ranges. The electron density is enhanced by more than one order of magnitude by capping LNO films. X-ray photoelectron spectroscopy shows that the interface undergoes unambiguous charge transfer and electronic reconstruction, leading to modulation doping of such atomically engineered complex oxide heterointerfaces. The polar-catastrophe of the 2DEG is directly linked to the electronic structure and transport properties of the LNO. The transport properties can be well modulated by the thickness of the LAO in the 2DEG, and the data can be well fitted with the polar-catastrophe scenario. These results suggest a general approach to tunable functional films in oxide heterostructures with the 2DEG.

  11. Electron transfer mechanism and photochemistry of ferrioxalate induced by excitation in the charge transfer band.

    Science.gov (United States)

    Chen, Jie; Zhang, Hua; Tomov, Ivan V; Rentzepis, Peter M

    2008-03-17

    The photoredox reaction of ferrioxalate after 266/267 nm excitation in the charge transfer band has been studied by means of ultrafast extended X-ray absorption fine structure (EXAFS) analysis, optical transient spectroscopy, and quantum chemistry calculations. The Fe-O bond length changes combined with the transient spectra and kinetics have been measured and in combination with ultrahigh frequency density functional theory (UHF/DFT) calculations are used to determine the photochemical mechanism for the Fe(III) to Fe(II) redox reaction. The present data and the results obtained with 266/267 nm excitations strongly suggest that the primary reaction is the dissociation of the Fe-O bond before intramolecular electron transfer occurs. Low quantum yield electron photodetachment from ferrioxalate has also been observed.

  12. Noether charges and black hole mechanics in Einstein-aether theory

    International Nuclear Information System (INIS)

    Foster, Brendan Z.

    2006-01-01

    The Noether charge method for defining the Hamiltonian of a diffeomorphism-invariant field theory is applied to 'Einstein-aether' theory, in which gravity couples to a dynamical, timelike, unit-norm vector field. Using the method, expressions are obtained for the total energy, momentum, and angular momentum of an Einstein-aether space-time. The method is also used to discuss the mechanics of Einstein-aether black holes. The derivation of Wald, and Iyer and Wald, of the first law of black hole thermodynamics fails for this theory because the unit-vector is necessarily singular at the bifurcation surface of the Killing horizon. A general identity relating variations of energy and angular momentum to a surface integral at the horizon is obtained, but a thermodynamic interpretation, including a definitive expression for the black hole entropy, is not found

  13. DC Model Cable under Polarity Inversion and Thermal Gradient: Build-Up of Design-Related Space Charge

    Directory of Open Access Journals (Sweden)

    Nugroho Adi

    2017-07-01

    Full Text Available In the field of energy transport, High-Voltage DC (HVDC technologies are booming at present due to the more flexible power converter solutions along with needs to bring electrical energy from distributed production areas to consumption sites and to strengthen large-scale energy networks. These developments go with challenges in qualifying insulating materials embedded in those systems and in the design of insulations relying on stress distribution. Our purpose in this communication is to illustrate how far the field distribution in DC insulation systems can be anticipated based on conductivity data gathered as a function of temperature and electric field. Transient currents and conductivity estimates as a function of temperature and field were recorded on miniaturized HVDC power cables with construction of 1.5 mm thick crosslinked polyethylene (XLPE insulation. Outputs of the conductivity model are compared to measured field distributions using space charge measurements techniques. It is shown that some features of the field distribution on model cables put under thermal gradient can be anticipated based on conductivity data. However, space charge build-up can induce substantial electric field strengthening when materials are not well controlled.

  14. Universal crossover of the charge carrier fluctuation mechanism in different polymer/carbon nanotubes composites

    Science.gov (United States)

    Barone, C.; Landi, G.; Mauro, C.; Neitzert, H. C.; Pagano, S.

    2015-10-01

    Carbon nanotubes added to polymer and epoxy matrices are compounds of interest for applications in electronics and aerospace. The realization of high-performance devices based on these materials can profit from the investigation of their electric noise properties, as this gives a more detailed insight of the basic charge carriers transport mechanisms at work. The dc and electrical noise characteristics of different polymer/carbon nanotubes composites have been analyzed from 10 to 300 K. The results suggest that all these systems can be regarded as random resistive networks of tunnel junctions formed by adjacent carbon nanotubes. However, in the high-temperature regime, contributions deriving from other possible mechanisms cannot be separated using dc information alone. A transition from a fluctuation-induced tunneling process to a thermally activated regime is instead revealed by electric noise spectroscopy. In particular, a crossover is found from a two-level tunneling mechanism, operating at low temperatures, to resistance fluctuations of a percolative network, in the high-temperature region. The observed behavior of 1/f noise seems to be a general feature for highly conductive samples, independent on the type of polymer matrix and on the nanotube density.

  15. Th1/Th2 paradigm extended: Macrophage polarization as an unappreciated pathogen-driven escape mechanism?

    Directory of Open Access Journals (Sweden)

    Eric eMuraille

    2014-11-01

    Full Text Available The classical view of the Th1/Th2 paradigm posits that the pathogen nature, infectious cycle and persistence represent key parameters controlling the choice of effector mechanisms operating during an immune response. Thus, efficient Th1 responses are triggered by replicating intracellular pathogens, while Th2 responses would control helminth infection and promote tissue repair during the resolution phase of an infectious event. However, this vision does not account for a growing body of data describing how pathogens exploit the polarization of the host immune response to their own benefit. Recently, the study of macrophages has illustrated a novel aspect of this arm race between pathogens and the immune system, and the central role of macrophages in homeostasis, repair and defense of all tissues is now fully appreciated. Like T lymphocytes, macrophages differentiate into distinct effectors including classically (M1 and alternatively (M2 activated macrophages. Interestingly in addition to represent immune effectors, M1/M2 cells have been shown to represent potential reservoir cells to a wide range of intracellular pathogens. Subversion of macrophage cell metabolism by microbes appears as a recently uncovered immune escape strategy. Upon infection, several microbial agents have been shown to activate host metabolic pathways leading to the production of nutrients necessary to their long term persistence in host. The purpose of this review is to summarize and discuss the strategies employed by pathogens to manipulate macrophage differentiation, and in particular their basic cell metabolism, to favor their own growth while avoiding immune control.

  16. Enhancing charge mobilities in organic semiconductors by selective fluorination: a design approach based on a quantum mechanical perspective.

    Science.gov (United States)

    Maiti, Buddhadev; Schubert, Alexander; Sarkar, Sunandan; Bhandari, Srijana; Wang, Kunlun; Li, Zhe; Geva, Eitan; Twieg, Robert J; Dunietz, Barry D

    2017-10-01

    Selective fluorination of organic semiconducting molecules is proposed as a means to achieving enhanced hole mobility. Naphthalene is examined here as a root molecular system with fluorination performed at various sites. Our quantum chemical calculations show that selective fluorination can enhance attractive intermolecular interactions while reducing charge trapping. Those observations suggest a design principle whereby fluorination is utilized for achieving high charge mobilities in the crystalline form. The utility of this design principle is demonstrated through an application to perylene, which is an important building block of organic semiconducting materials. We also show that a quantum mechanical perspective of nuclear degrees of freedom is crucial for a reliable description of charge transport.

  17. Measuring the effect of ion-induced drift-gas polarization on the electrical mobilities of multiply-charged ionic liquid nanodrops in air.

    Science.gov (United States)

    Fernández-García, Juan; Fernández de la Mora, Juan

    2013-12-01

    The electrical mobilities of multiply-charged nanodrops of the ionic liquid 1-ethyl, 3-methylimidazolium dicyanamide (EMI-N[CN]2) were accurately measured in air at 20 °C for mass-selected clusters of composition [EMI-N[CN]2] n [EMI(+)] z , with 2 ≤ n ≤ 369 and 1 ≤ z ≤ 10. We confirm prior reports that the mobility Z of a globular ion of mass m is given approximately by the modified Stokes-Millikan law for spheres, Z  =  Z SM,mod (d m   +  d g , z, m), where d m   =  (6m/πρ)(1/3) is the nanodrop mass-diameter based on the density ρ of the liquid (corrected for the capillary compression and electrostatic deformation of the nanodrop), and d g is an effective air molecule diameter. There is however a measurable (up to 7%) and systematic z-dependent departure of Z from Z SM,mod . As theoretically expected at small ε (*) , this effect is accurately described by a simple correction factor of the form Z/Z SM,mod   =  δ(1  -  βε (*)), where kTε (*) is the potential energy due to the ion-induced dipole (polarization) attraction between a perfectly-conducting charged nanodrop and a polarized neutral gas-molecule at a distance (d m   +  d g )/2 from its center. An excellent fit of this model to hundreds of data points is found for d g ≈ 0.26 nm, β ≈ 0.36, and δ ≈ 0.954. Accounting for the effect of polarization decreases d g considerably with respect to values inferred from earlier nanodrop measurements that ignored this effect. In addition, and in spite of ambiguities in the mobility calibration scale, the measured constant δ smaller than unity increases Millikan's drag enhancement factor from the accepted value ξ m ≈ 1.36 to the new value ξ ≈ ξ m /δ ≈ 1.42  ± 0.03.

  18. Measuring the Effect of Ion-Induced Drift-Gas Polarization on the Electrical Mobilities of Multiply-Charged Ionic Liquid Nanodrops in Air

    Science.gov (United States)

    Fernández-García, Juan; Fernández de la Mora, Juan

    2013-12-01

    The electrical mobilities of multiply-charged nanodrops of the ionic liquid 1-ethyl, 3-methylimidazolium dicyanamide (EMI-N[CN]2) were accurately measured in air at 20 °C for mass-selected clusters of composition [EMI-N[CN]2] n [EMI+] z , with 2 ≤ n ≤ 369 and 1 ≤ z ≤ 10. We confirm prior reports that the mobility Z of a globular ion of mass m is given approximately by the modified Stokes-Millikan law for spheres, Z = Z SM, mod ( d m + d g , z, m), where d m = (6 m/ πρ)1/3 is the nanodrop mass-diameter based on the density ρ of the liquid (corrected for the capillary compression and electrostatic deformation of the nanodrop), and d g is an effective air molecule diameter. There is however a measurable (up to 7 %) and systematic z-dependent departure of Z from Z SM,mod . As theoretically expected at small ɛ * , this effect is accurately described by a simple correction factor of the form Z/ Z SM, mod = δ(1 - βɛ *), where kTɛ * is the potential energy due to the ion-induced dipole ( polarization) attraction between a perfectly-conducting charged nanodrop and a polarized neutral gas-molecule at a distance ( d m + d g )/2 from its center. An excellent fit of this model to hundreds of data points is found for d g ≈ 0.26 nm, β ≈ 0.36, and δ ≈ 0.954. Accounting for the effect of polarization decreases d g considerably with respect to values inferred from earlier nanodrop measurements that ignored this effect. In addition, and in spite of ambiguities in the mobility calibration scale, the measured constant δ smaller than unity increases Millikan's drag enhancement factor from the accepted value ξ m ≈ 1.36 to the new value ξ ≈ ξ m / δ ≈ 1.42 ± 0.03.

  19. A service component-based accounting and charging architecture to support interim mechanisms across multiple domains

    NARCIS (Netherlands)

    Le, M. van; Beijnum, B.J.F. van; Huitema, G.B.

    2004-01-01

    Today, telematics services are often compositions of different chargeable service components offered by different service providers. To enhance component-based accounting and charging, the service composition information is used to match with the corresponding charging structure of a service

  20. A charged particle interacting with a stationary magnetic monopole: quantum mechanics based on the kinetic momentum operators

    International Nuclear Information System (INIS)

    Raković, Milun J

    2011-01-01

    The standard quantum mechanical description of the motion of a charged particle in the field of a stationary magnetic monopole is notorious for the presence of unnatural singularities in the Hamiltonian operator originating in the vector potential A(r) used to describe the magnetic field of the monopole. In this paper, an elementary quantum mechanical formulation of the problem which involves only the physically observable field B(r) is presented. This is achieved by treating as a fundamental observable of the charged particle its kinetic momentum instead of the linear momentum p. An irreducible representation of the fundamental commutation relations involving the operators r-hat. It is shown that the existence of an irreducible representation requires that Dirac’s charge quantization condition is satisfied. Also, it is demonstrated that, from the quantum mechanical perspective, the singularities (appearing when the vector potential is introduced) are in fact properties of coordinate representations of the fundamental commutation relations. (paper)

  1. Derivation of Maxwell's Equations Based on a Continuum Mechanical Model of Vacuum and a Singularity Model of Electric Charges

    Directory of Open Access Journals (Sweden)

    Wang X.-S.

    2008-04-01

    Full Text Available The main purpose of this paper is to seek a mechanical interpretation of electromagnetic phenomena. We suppose that vacuum is filled with a kind of continuously distributed material which may be called Omega(1 substratum. Further, we speculate that the Omega(1 substratum might behave like a fluid with respect to translational motion of large bod- ies through it, but would still posses elasticity to produce small transverse vibrations. Thus, we propose a visco-elastic constitutive relation of the Omega(1 substratum. Further- more, we speculate that electric charges are emitting or absorbing the Omega(1 substratum continuously and establish a fluidic source and sink model of electric charges. Thus, Maxwell’s equations in vacuum are derived by methods of continuum mechanics based on this mechanical model of vacuum and the singularity model of electric charges.

  2. Derivation of Maxwell's Equations Based on a Continuum Mechanical Model of Vacuum and a Singularity Model of Electric Charges

    Directory of Open Access Journals (Sweden)

    Xiao-Song Wang

    2008-04-01

    Full Text Available The main purpose of this paper is to seek a mechanical interpretation of electromagnetic phenomena. We suppose that vacuumis filled with a kind of continuously distributed material which may be called $Omega (1$ substratum. Further, we speculate that the $Omega (1$ substratum might behave like a fluid with respect to translational motion of large bodies through it, but would still posses elasticity to produce small transverse vibrations. Thus, we propose a visco-elastic constitutive relation of the $Omega (1$ substratum. Furthermore, we speculate that electric charges are emitting or absorbing the $Omega (1$ substratum continuously and establish a fluidic source and sink model of electric charges. Thus,Maxwell's equations in vacuum are derived by methods of continuum mechanics based on this mechanical model of vacuum and the singularity model of electric charges.

  3. Dynamics of ligand exchange mechanism at Cu(II) in water: An ab initio quantum mechanical charge field molecular dynamics study with extended quantum mechanical region

    International Nuclear Information System (INIS)

    Moin, Syed Tarique; Hofer, Thomas S.; Weiss, Alexander K. H.; Rode, Bernd M.

    2013-01-01

    Ab initio quantum mechanical charge field molecular dynamics (QMCF-MD) were successfully applied to Cu(II) embedded in water to elucidate structure and to understand dynamics of ligand exchange mechanism. From the simulation studies, it was found that using an extended large quantum mechanical region including two shells of hydration is required for a better description of the dynamics of exchanging water molecules. The structural features characterized by radial distribution function, angular distribution function and other analytical parameters were consistent with experimental data. The major outcome of this study was the dynamics of exchange mechanism and reactions in the first hydration shell that could not be studied so far. The dynamical data such as mean residence time of the first shell water molecules and other relevant data from the simulations are close to the results determined experimentally. Another major characteristic of hydrated Cu(II) is the Jahn-Teller distortion which was also successfully reproduced, leading to the final conclusion that the dominating aqua complex is a 6-coordinated species. The ab initio QMCF-MD formalism proved again its capabilities of unraveling even ambiguous properties of hydrated species that are far difficult to explore by any conventional quantum mechanics/molecular mechanics (QM/MM) approach or experiment

  4. A Kinematic, Flexure-based Mechanism for Precise, Parallel Motion for the Hertz Variable-delay Polarization Modulator (VPM)

    Science.gov (United States)

    Voellmer, G. M.; Chuss, D. T.; Jackson, M.; Krejny, M.; Moseley, S. H.; Novak, G.; Wollack, E. J.

    2008-01-01

    We describe the design of the linear motion stage for a Variable-delay Polarization Modulator (VPM) and of a grid flattener that has been built and integrated into the Hertz ground-based, submillimeter polarimeter. VPMs allow the modulation of a polarized source by controlling the phase difference between two linear, orthogonal polarizations. The size of the gap between a mirror and a very flat polarizing grid determines the amount of the phase difference. This gap must be parallel to better than 1% of the wavelength. A novel, kinematic, flexure-based mechanism is described that passively maintains the parallelism of the mirror and the grid to 1.5 pm over a 150 mm diameter, with a 400 pm throw. A single piezoceramic actuator is used to modulate the gap, and a capacitive sensor provides position feedback for closed-loop control. A simple device that ensures the planarity of the polarizing grid is also described. Engineering results from the deployment of this device in the Hertz instrument April 2006 at the Submillimeter Telescope Observatory (SMTO) in Arizona are presented.

  5. Nonvolatile data storage using mechanical force-induced polarization switching in ferroelectric polymer

    International Nuclear Information System (INIS)

    Chen, Xin; Tang, Xin; Chen, Xiang-Zhong; Chen, Yu-Lei; Shen, Qun-Dong; Guo, Xu; Ge, Hai-Xiong

    2015-01-01

    Ferroelectric polymers offer the promise of low-cost and flexible electronic products. They are attractive for information storage due to their spontaneous polarization which is usually switched by electric field. Here, we demonstrate that electrical signals can be readily written on ultra-thin ferroelectric polymer films by strain gradient-induced polarization switching (flexoelectric effect). A force with magnitude as small as 64nN is enough to induce highly localized (40 nm feature size) change in the polarization states. The methodology is capable of realizing nonvolatile memory devices with miniaturized cell size and storage density of tens to hundreds Gbit per square inch

  6. Numerical investigation of influence of ionic space charge and flexoelectric polarization on measurements of elastic constants in nematic liquid crystals

    Science.gov (United States)

    Buczkowska, M.; Derfel, G.; Konowalski, M.

    2009-06-01

    Deformations of nematic layers caused by magnetic field allow determination of the elastic constants of liquid crystal. In this paper, we simulated numerically the deformations of planar and homeotropic nematic layers. The flexoelectric properties of the nematic and presence of ions were taken into account. Our aim was to show the influence of flexoelectricity on the results of the real measurement of the elastic constants k33 and k11. In these simulations, we calculated the optical phase difference ΔΦ between the ordinary and extraordinary rays of light passing through the layer placed between crossed polarizers as a function of the magnetic field induction B. One of the elastic constants can be calculated from the magnetic field threshold for deformation. The ratio k33/k11 can be found by means of fitting theoretical ΔΦ(B) dependence to the experimental results. The calculations reveal that the flexoelectric properties influence the deformations induced by the external magnetic field. In the case of highly pure samples, this may lead to false results of measurement of the elastic constants ratio k33/k11. This influence can be reduced if the nematic material contains ions of sufficiently high concentration. These results show that the flexoelectric properties may play an important role, especially in well purified samples.

  7. Kinetics of aggregation in charged nanoparticle solutions driven by different mechanisms

    Science.gov (United States)

    Abbas, S.; Yadav, I.; Kumar, Sugam; Aswal, V. K.; Kohlbrecher, J.

    2017-05-01

    The structure and kinetics during aggregation of anionic silica nanoparticles as induced through different mechanisms have been studied by dynamic light scattering (DLS) and small-angle neutron scattering (SANS). Three different additives, namely an electrolyte (NaCl), cationic protein (lysozyme) and non-ionic surfactant (C12E10) were used to initiate nanoparticle aggregation. Electrolyte induced aggregation can be explained by DLVO interaction, whereas depletion interaction (non-DLVO interaction) is found responsible for nanoparticle aggregation in case of non-ionic surfactant. Unlike these two cases, strong electrostatic attraction between nanoparticle and oppositely charged protein results into protein-mediated nanoparticle aggregation. The electrolyte induced aggregation show quite slow aggregation rate whereas protein mediated as well as surfactant induced aggregation takes place almost instantaneously. The significant differences observed in the kinetics are explained based on range of interactions responsible for the aggregation. In spite of differences in mechanism and kinetics, the nanoparticle clusters are found to have similar fractal morphology (fractal dimension ˜ 2.5) in all the three cases.

  8. Physical mechanisms leading to high currents of highly charged ions in laser-driven ion sources

    Energy Technology Data Exchange (ETDEWEB)

    Haseroth, Helmut [European Organization for Nuclear Research, Geneva (Switzerland); Hora, Heinrich [New South Wales Univ., Kensington, NSW (Australia)]|[Regensburg Inst. of Tech. (Germany). Anwenderzentrum

    1996-12-31

    Heavy ion sources for the big accelerators, for example, the LHC, require considerably more ions per pulse during a short time than the best developed classical ion source, the electron cyclotron resonance (ECR) provides; thus an alternative ion source is needed. This can be expected from laser-produced plasmas, where dramatically new types of ion generation have been observed. Experiments with rather modest lasers have confirmed operation with one million pulses of 1 Hz, and 10{sup 11} C{sup 4+} ions per pulse reached 2 GeV/u in the Dubna synchrotron. We review here the complexities of laser-plasma interactions to underline the unique and extraordinary possibilities that the laser ion source offers. The complexities are elaborated with respect to keV and MeV ion generation, nonlinear (ponderomotive) forces, self-focusing, resonances and ``hot`` electrons, parametric instabilities, double-layer effects, and the few ps stochastic pulsation (stuttering). Recent experiments with the laser ion source have been analyzed to distinguish between the ps and ns interaction, and it was discovered that one mechanism of highly charged ion generation is the electron impact ionization (EII) mechanism, similar to the ECR, but with so much higher plasma densities that the required very large number of ions per pulse are produced. (author).

  9. Charge transport mechanism and low temperature phase transitions in KIO3

    Science.gov (United States)

    Abdel Kader, M. M.; El-Kabbany, F.; Naguib, H. M.; Gamal, W. M.

    2013-04-01

    Our report deals with the measurement of some electrical properties, namely the ac conductivity σ(ω,T) and the complex dielectric permittivity epsilon*(ω, T) in the temperature interval 95K < T < 280K and at some selected frequencies (0.7kHz - 20kHz) for polycrystalline samples of potassium iodate KIO3 using a computerized RLC meter. The improper character of the ferroelectricity over the mentioned temperature range has been achieved by recording the ferroelectric hysteresis loops. The temperature dependence of each electrical parameter reveals that the compound undergoes two phase transitions at T ≈ 258K and at T ≈ 110K. The frequency dependent conductivity seems to be in accordance with the power law σ(ω,T)αωs(T) and the trend of temperature dependence of the frequency exponent s (0 < s < 1) suggests that the quantum mechanical tunneling (QMT) model is the main mechanism of the charge transport. Comparison with the behavior of the NH4IO3 in the same temperature range was outlined.

  10. Physical mechanisms leading to high currents of highly charged ions in laser-driven ion sources

    International Nuclear Information System (INIS)

    Haseroth, Helmut; Hora, Heinrich; Regensburg Inst. of Tech.

    1996-01-01

    Heavy ion sources for the big accelerators, for example, the LHC, require considerably more ions per pulse during a short time than the best developed classical ion source, the electron cyclotron resonance (ECR) provides; thus an alternative ion source is needed. This can be expected from laser-produced plasmas, where dramatically new types of ion generation have been observed. Experiments with rather modest lasers have confirmed operation with one million pulses of 1 Hz, and 10 11 C 4+ ions per pulse reached 2 GeV/u in the Dubna synchrotron. We review here the complexities of laser-plasma interactions to underline the unique and extraordinary possibilities that the laser ion source offers. The complexities are elaborated with respect to keV and MeV ion generation, nonlinear (ponderomotive) forces, self-focusing, resonances and ''hot'' electrons, parametric instabilities, double-layer effects, and the few ps stochastic pulsation (stuttering). Recent experiments with the laser ion source have been analyzed to distinguish between the ps and ns interaction, and it was discovered that one mechanism of highly charged ion generation is the electron impact ionization (EII) mechanism, similar to the ECR, but with so much higher plasma densities that the required very large number of ions per pulse are produced. (author)

  11. Mechanisms of Cell Polarity-Controlled Epithelial Homeostasis and Immunity in the Intestine

    NARCIS (Netherlands)

    Klunder, Leon J.; Faber, Klaas Nico; Dijkstra, Gerard; van IJzendoorn, Sven C. D.

    Intestinal epithelial cell polarity is instrumental to maintain epithelial homeostasis and balance communications between the gut lumen and bodily tissue, thereby controlling the defense against gastrointestinal pathogens and maintenance of immune tolerance to commensal bacteria. In this review, we

  12. Polar filament discharge of Myxobolus cerebralis actinospores is triggered by combined non-specific mechanical and chemical cues.

    Science.gov (United States)

    Kallert, D M; El-Matbouli, M; Haas, W

    2005-11-01

    This study presents initial evidence for the requirement of both chemical and mechanical stimuli to discharge polar capsules of Myxobolus cerebralis actinospores, the causative agent of salmonid whirling disease. The obligate need for combined discharge triggers was concluded from data obtained in a before/after experimental set-up carried out with individual locally immobilized actinospores. Homogenized rainbow trout mucus as chemostimulus and tangency of the apical region of the spores to achieve mechanical stimulation were applied subsequently. The actinospores showed discharged polar filaments exclusively when mucus substrate application was followed by touching the polar capsule-bearing region, but not when either stimulus was offered solely to the same individuals. We measured filament discharge rates to mucus preparations in a microscopic assay using supplementary vibration stimuli to ensure mechanical excitation. The actinospores responded similarly to different frequencies, which suggested a touch-sensitive recognition mechanism. Discharge specificity for salmonid mucus could not be confirmed, as mucus of common carp and bream could trigger similar filament expulsion rates. To a lesser extent homogenized frog epidermis and bovine submaxillary mucin could also stimulate the attachment reaction. In contrast, mucus of a pulmonate freshwater snail elicited no response.

  13. Charge erasure analysis on the nanoscale using Kelvin probe force microscopy

    Science.gov (United States)

    Lin, Shi-quan; Shao, Tian-min

    2017-07-01

    The charge pattern produced by atomic force microscopy on an insulating surface can be detected on the nanoscale using Kelvin probe force microscopy. Recent applications of charge patterns include data storage, nano-xerography, and charge writing. At present, ongoing development of this technology is being restricted by a poor understanding of the charge modification and erasure mechanisms. In this study, modification and erasure of charge patterns are achieved by applying oppositely polarized pulses to an insulating surface. The effects of the oppositely polarized pulse height and width on the charge erasure behavior are examined, and the charge injection and erasure processes are compared. Hence, it is demonstrated that the charges on the patterned surface can be neutralized by adjusting the height and width of the oppositely polarized pulse appropriately. In addition, charge injection and erasure mechanisms are proposed. It is suggested that application of an oppositely polarized pulse to the insulating surface causes injection of opposite charges into the surface and removal of the initial charges, both of which occur simultaneously. The findings of this work provide a means of achieving data re-storage or data modification, for which charge spot erasure is essential. In addition, the findings may have general implications for the development of nano-xerography, charge writing, nano-lithography, etc.

  14. Compromising polarity and waveform constraints in focal-mechanism solutions; the Mara Rosa 2010 Mw 4 central Brazil earthquake revisited

    Czech Academy of Sciences Publication Activity Database

    Zahradník, J.; Fojtíková, Lucia; Carvalho, J.; Barros, L.V.; Sokos, E.; Janský, J.

    2015-01-01

    Roč. 63, NOV (2015), s. 323-333 ISSN 0895-9811 R&D Projects: GA ČR GAP210/12/2336 Institutional support: RVO:67985891 Keywords : weak events * focal mechanism * waveforms * polarities * uncertainties * Brazil * Mara Rosa Subject RIV: DC - Siesmology, Volcanology, Earth Structure Impact factor: 1.737, year: 2015 http://www. science direct.com/ science /article/pii/S0895981115300481

  15. Mechanical Properties of Surface-Charged Poly(Methyl Methacrylate as Denture Resins

    Directory of Open Access Journals (Sweden)

    Sang E. Park

    2009-01-01

    Full Text Available The aim of this study was to examine the mechanical properties of a new surface-modified denture resin for its suitability as denture base material. This experimental resin is made by copolymerization of methacrylic acid (MA to poly(methyl methacrylate (PMMA to produce a negative charge. Four experimental groups consisted of Orthodontic Dental Resin (DENTSPLY Caulk as a control and three groups of modified PMMA (mPMMA produced at differing ratios of methacrylic acid (5 : 95, 10 : 90, and 20 : 80 MA : MMA. A 3-point flexural test using the Instron Universal Testing Machine (Instron Corp. measured force-deflection curves and a complete stress versus strain history to calculate the transverse strength, transverse deflection, flexural strength, and modulus of elasticity. Analysis of Variance and Scheffe Post-test were performed on the data. Resins with increased methacrylic acid content exhibited lower strength values for the measured physical properties. The most significant decrease occurred as the methacrylic acid content was increased to 20% mPMMA. No significant differences at P<.05 were found in all parameters tested between the Control and 5% mPMMA.

  16. Polarity compensation mechanisms on the perovskite surface KTaO3(001)

    Science.gov (United States)

    Setvin, Martin; Reticcioli, Michele; Poelzleitner, Flora; Hulva, Jan; Schmid, Michael; Boatner, Lynn A.; Franchini, Cesare; Diebold, Ulrike

    2018-02-01

    An ionic crystal surface can be electrostatically unstable, and the surface must reconstruct in some way to avoid this “polar catastrophe.” Setvin et al. used scanning probe microscopies and density functional theory to study the changes in the polar surface of the perovskite KTaO3. They observed several structural reconstructions as the surface cleaved in vacuum was heated to higher temperatures. These ranged from surface distortions to the formation of oxygen vacancies to the development of KO and TaO2 stripes. Hydroxylation after exposure to water vapor also stabilized the surface.

  17. Engine Tune-up Service. Unit 2: Charging System. Posttests. Automotive Mechanics Curriculum.

    Science.gov (United States)

    Richardson, Roger L.; Bacon, E. Miles

    This book of posttests is designed to accompany the Engine Tune-Up Service Student Guide for Unit 2, Charging System, available separately as CE 031 208. Focus of the posttest is on the testing of the charging system. One multiple choice posttest is provided, that covers the three performance objectives contained in the unit. (No answer key is…

  18. Engine Tune-up Service. Unit 2: Charging System. Review Exercise Book. Automotive Mechanics Curriculum.

    Science.gov (United States)

    Richardson, Roger L.; Bacon, E. Miles

    This book of pretests and review exercises is designed to accompany the Engine Tune-Up Service Student Guide for Unit 2, Charging System, available separately as CE 031 208. Focus of the exercises and pretests is testing the charging system. Pretests and performance checklists are provided for each of the three performance objectives contained in…

  19. Single molecule charge transport : From a quantum mechanical to a classical description

    NARCIS (Netherlands)

    Kocherzhenko, A.A.; Grozema, F.C.; Siebbeles, L.D.A.

    2010-01-01

    This paper explores charge transport at the single molecule level. The conductive properties of both small organic molecules and conjugated polymers (molecular wires) are considered. In particular, the reasons for the transition from fully coherent to incoherent charge transport and the approaches

  20. A Service Component-based Accounting and Charging Architecture to Support Interim Mechanisms across Multiple Domains

    NARCIS (Netherlands)

    Le, V.M.; van Beijnum, Bernhard J.F.; Huitema, G.B.

    Today, telematics services are o Aen compositions of different chargeable service components offered by different service providers. To enhance component-based accounting and charging, the service composition information is used to match with the corresponding charging structure of a service

  1. Angular Distribution and Linear Polarization of X-ray Radiation Resulting from Electron Impact Excitation of Highly Charged Ions in Debye Plasmas

    Science.gov (United States)

    Chen, Zhanbin

    2018-05-01

    Plasma-screening effects on the 1s _{1/2} → 2l (l = s , p ) and 1s _{1/2} → 3d _{3/2} electron-impact excitation of highly charged ions are investigated, together with their subsequent radiative decay. The analysis is performed based on the multi-configuration Dirac-Fock method and the fully relativistic distorted-wave method incorporating the Debye-Hückel potential. To explore the nature of the effects, calculations are carried out based on detailed analyses of the integrated total and magnetic sublevel cross sections, the alignment parameters, the linear polarizations, and the angular distribution of the X-ray photoemission, as well as on corresponding data calculated in various Debye lengths/environments, taking the 2p _{3/2}→ 1s _{1/2} and 3d _{3/2}→ 1s _{1/2} characteristic lines of H-like Fe^{25+} ion as an example. The present results are compared with experimental data and other theoretical predictions where available.

  2. Molecular mechanisms that regulate the macrophage M1/M2 polarization balance

    Directory of Open Access Journals (Sweden)

    Nan eWang

    2014-11-01

    Full Text Available As an essential component of innate immunity, macrophages have multiple functions in both inhibiting or promoting cell proliferation and tissue repair. Diversity and plasticity are hallmarks of macrophages. Classical M1 and alternative M2 activation of macrophages, mirroring the Th1–Th2 polarization of T cells, represent two extremes of a dynamic changing state of macrophage activation. M1-type macrophages release cytokines that inhibit the proliferation of surrounding cells and damage contiguous tissue, and M2-type macrophages release cytokines that promote the proliferation of contiguous cells and tissue repair. M1-M2 polarization of macrophage is a tightly controlled process entailing a set of signaling pathways, transcriptional and posttranscriptional regulatory networks. An imbalance of macrophage M1-M2 polarization is often associated with various diseases or inflammatory conditions. Therefore identification of the molecules associated with the dynamic changes of macrophage polarization and understanding their interactions is crucial for elucidating the molecular basis of disease progression and designing novel macrophage-mediated therapeutic strategies.

  3. Stabilization mechanism for the polar ZnO(0001̅)-O surface

    DEFF Research Database (Denmark)

    Wahl, Roman; Lauritsen, Jeppe Vang; Besenbacher, Flemming

    2013-01-01

    When wurtzite ZnO is sliced perpendicular to the (0001) axis, two different polar surfaces, the (0001)-Zn and (0001̅ )-O terminated surfaces, are formed. In a simple ionic picture, both surfaces are electrostatically unstable due to a diverging electrostatic energy. Although the ionic picture...

  4. THE CONTROLLED DRIFT DETECTOR : CHARACTERISATION OF THE READOUT MECHANISM AND OF THE CHARGE HANDLING CAPABILITY.

    Energy Technology Data Exchange (ETDEWEB)

    CASTOLDI,A.; GATTI,E.; GUAZZONI,C.; LONGONI,A.; REHAK,P.; STRUDER,L.

    1998-11-08

    A new position-sensing X-ray detector operated in integrate-readout mode has been recently designed and characterized. Due to the peculiar working principle of the new detector, the charge handling capability, that is the maximum charge that can be stored in a pixel, is related to the operating conditions of the device. In particular the amplitude of the barriers that confine the signal electrons during the integration phase depends on the applied drift field and on the field perturbation superposed to it. A detailed experimental characterization of the charge handling capability as a function of these parameters has been carried out.

  5. Polar metals by geometric design

    Science.gov (United States)

    Kim, T. H.; Puggioni, D.; Yuan, Y.; Xie, L.; Zhou, H.; Campbell, N.; Ryan, P. J.; Choi, Y.; Kim, J.-W.; Patzner, J. R.; Ryu, S.; Podkaminer, J. P.; Irwin, J.; Ma, Y.; Fennie, C. J.; Rzchowski, M. S.; Pan, X. Q.; Gopalan, V.; Rondinelli, J. M.; Eom, C. B.

    2016-05-01

    Gauss’s law dictates that the net electric field inside a conductor in electrostatic equilibrium is zero by effective charge screening; free carriers within a metal eliminate internal dipoles that may arise owing to asymmetric charge distributions. Quantum physics supports this view, demonstrating that delocalized electrons make a static macroscopic polarization, an ill-defined quantity in metals—it is exceedingly unusual to find a polar metal that exhibits long-range ordered dipoles owing to cooperative atomic displacements aligned from dipolar interactions as in insulating phases. Here we describe the quantum mechanical design and experimental realization of room-temperature polar metals in thin-film ANiO3 perovskite nickelates using a strategy based on atomic-scale control of inversion-preserving (centric) displacements. We predict with ab initio calculations that cooperative polar A cation displacements are geometrically stabilized with a non-equilibrium amplitude and tilt pattern of the corner-connected NiO6 octahedra—the structural signatures of perovskites—owing to geometric constraints imposed by the underlying substrate. Heteroepitaxial thin-films grown on LaAlO3 (111) substrates fulfil the design principles. We achieve both a conducting polar monoclinic oxide that is inaccessible in compositionally identical films grown on (001) substrates, and observe a hidden, previously unreported, non-equilibrium structure in thin-film geometries. We expect that the geometric stabilization approach will provide novel avenues for realizing new multifunctional materials with unusual coexisting properties.

  6. Seeing is believing: Direct imaging of charge flow along pili proteins reveals new mechanism for bacterial electron transfer

    Science.gov (United States)

    Malvankar, Nikhil; Yalcin, Sibel Ebru; Adhikari, Ramesh; Tuominen, Mark; Lovley, Derek

    2015-03-01

    Visualization of charge flow on the nanoscale in proteins is crucial for a fundamental understanding of several life processes. Here, we report direct visualization of charge propagation along native pili of Geobacter sulfurreducens at nanometer resolution using electrostatic force microscopy. Surprisingly, charges injected at a single point into individual, untreated pili, still attached to cells, propagate over the entire filament. The charges propagate despite a lack of cytochromes on the pili, in contrast to the dominant biochemical model that proteins are electronically insulating and must incorporate redox-active cofactors in order to achieve electron transport functionality. The mobile charge density in pili is comparable to synthetic organic conductors, increasing with proton doping, and with temperature-dependence consistent with previously discovered metallic-like transport mechanism. Conductive pili enable syntrophic bacteria to share energy by directly exchanging electrons among each other. Measurements along individual pilus using nanoelectrodes showed ohmic behavior strongly dependent on the amino acid composition of pili. Electron transfer rate measurement revealed that the pili conductivity is the decisive factor in controlling the bacterial respiration rate. Funded by Office of Naval Research, DOE Genomic Sciences, NSF-NSEC CHM (CMMI-1025020) and Burroughs Wellcome Fund.

  7. Hybridizing energy conversion and storage in a mechanical-to-electrochemical process for self-charging power cell.

    Science.gov (United States)

    Xue, Xinyu; Wang, Sihong; Guo, Wenxi; Zhang, Yan; Wang, Zhong Lin

    2012-09-12

    Energy generation and energy storage are two distinct processes that are usually accomplished using two separated units designed on the basis of different physical principles, such as piezoelectric nanogenerator and Li-ion battery; the former converts mechanical energy into electricity, and the latter stores electric energy as chemical energy. Here, we introduce a fundamental mechanism that directly hybridizes the two processes into one, in which the mechanical energy is directly converted and simultaneously stored as chemical energy without going through the intermediate step of first converting into electricity. By replacing the polyethylene (PE) separator as for conventional Li battery with a piezoelectric poly(vinylidene fluoride) (PVDF) film, the piezoelectric potential from the PVDF film as created by mechanical straining acts as a charge pump to drive Li ions to migrate from the cathode to the anode accompanying charging reactions at electrodes. This new approach can be applied to fabricating a self-charging power cell (SCPC) for sustainable driving micro/nanosystems and personal electronics.

  8. Photochemistry and electron-transfer mechanism of transition metal oxalato complexes excited in the charge transfer band.

    Science.gov (United States)

    Chen, Jie; Zhang, Hua; Tomov, Ivan V; Ding, Xunliang; Rentzepis, Peter M

    2008-10-07

    The photoredox reaction of trisoxalato cobaltate (III) has been studied by means of ultrafast extended x-ray absorption fine structure and optical transient spectroscopy after excitation in the charge-transfer band with 267-nm femtosecond pulses. The Co-O transient bond length changes and the optical spectra and kinetics have been measured and compared with those of ferrioxalate. Data presented here strongly suggest that both of these metal oxalato complexes operate under similar photoredox reaction mechanisms where the primary reaction involves the dissociation of a metal-oxygen bond. These results also indicate that excitation in the charge-transfer band is not a sufficient condition for the intramolecular electron transfer to be the dominant photochemistry reaction mechanism.

  9. The control mechanism of surface traps on surface charge behavior in alumina-filled epoxy composites

    International Nuclear Information System (INIS)

    Li, Chuanyang; Hu, Jun; Lin, Chuanjie; He, Jinliang

    2016-01-01

    To investigate the role surface traps play in the charge injection and transfer behavior of alumina-filled epoxy composites, surface traps with different trap levels are introduced by different surface modification methods which include dielectric barrier discharges plasma, direct fluorination, and Cr 2 O 3 coating. The resulting surface physicochemical characteristics of experimental samples were observed using atomic force microscopy, scanning electron microscopy and fourier transform infrared spectroscopy. The surface potential under dc voltage was detected and the trap level distribution was measured. The results suggest that the surface morphology of the experimental samples differs dramatically after treatment with different surface modification methods. Different surface trap distributions directly determine the charge injection and transfer property along the surface. Shallow traps with trap level of 1.03–1.11 eV and 1.06–1.13 eV introduced by plasma and fluorination modifications are conducive for charge transport along the insulating surface, and the surface potential can be modified, producing a smoother potential curve. The Cr 2 O 3 coating can introduce a large number of deep traps with energy levels ranging from 1.09 to 1.15 eV. These can prevent charge injection through the reversed electric field formed by intensive trapped charges in the Cr 2 O 3 coatings. (paper)

  10. Scattering of inhomogeneous circularly polarized optical field and mechanical manifestation of the internal energy flows

    DEFF Research Database (Denmark)

    Bekshaev, A. Ya; Angelsky, O. V.; Hanson, Steen Grüner

    2012-01-01

    Based on the Mie theory and on the incident beam model via superposition of two plane waves, we analyze numerically the momentum flux of the field scattered by a spherical, nonmagnetic microparticle placed within the spatially inhomogeneous circularly polarized paraxial light beam. The asymmetry...... between the forward- and backward-scattered momentum fluxes in the Rayleigh scattering regime appears due to the spin part of the internal energy flow in the incident beam. The transverse ponderomotive forces exerted on dielectric and conducting particles of different sizes are calculated and special...

  11. Mechanisms controlling retention during ultrafiltration of charged saccharides: Molecular conformation and electrostatic forces

    DEFF Research Database (Denmark)

    Pinelo, Manuel; Møller, Victor; Prado-Rubio, Oscar A.

    2013-01-01

    and between solute molecules and membrane material are amongst the key factors determining the separation efficiency during ultrafiltration of charged saccharides. Our hypothesis is that the manipulation of pH in addition to the classic pressure control should enhance the ultrafiltration performance......Separation of different biomass components in solution, including charged saccharides, is one of the key challenges in biorefining of plant biomass. Ultrafiltration is one of the potential processes that could cope with such separation. Electrostatic interactions between solute molecules...... into account when it comes to optimizing ultrafiltration of such species....

  12. Electrochemical regulation of budding yeast polarity.

    Directory of Open Access Journals (Sweden)

    Armin Haupt

    2014-12-01

    Full Text Available Cells are naturally surrounded by organized electrical signals in the form of local ion fluxes, membrane potential, and electric fields (EFs at their surface. Although the contribution of electrochemical elements to cell polarity and migration is beginning to be appreciated, underlying mechanisms are not known. Here we show that an exogenous EF can orient cell polarization in budding yeast (Saccharomyces cerevisiae cells, directing the growth of mating projections towards sites of hyperpolarized membrane potential, while directing bud emergence in the opposite direction, towards sites of depolarized potential. Using an optogenetic approach, we demonstrate that a local change in membrane potential triggered by light is sufficient to direct cell polarization. Screens for mutants with altered EF responses identify genes involved in transducing electrochemical signals to the polarity machinery. Membrane potential, which is regulated by the potassium transporter Trk1p, is required for polarity orientation during mating and EF response. Membrane potential may regulate membrane charges through negatively charged phosphatidylserines (PSs, which act to position the Cdc42p-based polarity machinery. These studies thus define an electrochemical pathway that directs the orientation of cell polarization.

  13. The charge percolation mechanism and simulation of Ziegler–Natta polymerizations. Part VI. Mechanism of ethylene polymerization by supported chromium oxide

    Directory of Open Access Journals (Sweden)

    DRAGOSLAV STOILJKOVIC

    2007-11-01

    Full Text Available Despite intensive research over the last 50 years, many questions concerning ethylene polymerization by supported chromium oxide are still unanswered. Hence, the very fundamental issues of this polymerization are discussed in this paper. It is shown that a charge percolation mechanism (CPM of olefin polymerization by Ziegler–Natta transition metal complexes, recently proposed by us, can give the answers in this case, too.

  14. Techniques and mechanisms applied in electron cyclotron resonance sources for highly charged ions

    NARCIS (Netherlands)

    Drentje, AG

    Electron cyclotron resonance ion sources are delivering beams of highly charged ions for a wide range of applications in many laboratories. For more than two decades, the development of these ion sources has been to a large extent an intuitive and experimental enterprise. Much effort has been spent

  15. The electro-mechanical effect from charge dynamics on polymeric insulation lifetime

    Science.gov (United States)

    Alghamdi, H.; Chen, G.; Vaughan, A. S.

    2015-12-01

    For polymeric material used as electrical insulation, the presence of space charges could be the consequence of material degradations that are thermally activated but increased by the application of an electric field. The dynamics of space charge, therefore, can be potentially used to characterize the material. In this direction, a new aging model in which parameters have clear physical meanings has been developed and applied to the material to extrapolate the lifetime. The kinetic equation has been established based on charge trapping and detrapping of the injected charge from the electrodes. The local electromechanical energy stored in the region surrounding the trap is able to reduce the trap-depth with a value related to the electric field. At a level where the internal electric field exceeds the detrapping field in the material, an electron can be efficiently detrapped and the released energy from detrapping process can cause a weak bond or chain scission i.e. material degradation. The model has been applied to the electro-thermally aged low density polyethylene film samples, showing well fitted result, as well as interesting relationships between parameter estimates and insulation morphology.

  16. Air Conditioner Charging. Automotive Mechanics. Air Conditioning. Instructor's Guide [and] Student Guide.

    Science.gov (United States)

    Spignesi, B.

    This instructional package, one in a series of individualized instructional units on automobile air conditioning, consists of a student guide and an instructor guide dealing with air conditioning charging. Covered in the module are checking the air conditioning system for leaks, checking and adding refrigerant oil as needed, evacuating the system,…

  17. Mechanism of the Primary Charge Transfer Reaction in the Cytochrome bc1 Complex

    DEFF Research Database (Denmark)

    Barragan, Angela M; Schulten, Klaus; Solov'yov, Ilia A

    2016-01-01

    , the quinol-protein interaction, which initiates the Q-cycle, has not yet been completely described. Furthermore, the initial charge transfer reactions of the Q-cycle lack a physical description. The present investigation utilizes classical molecular dynamics simulations in tandem with quantum density...

  18. Signatures of the electron saddle swaps mechanism in the photon spectra following charge-exchange collisions

    Science.gov (United States)

    Otranto, Sebastian

    2014-10-01

    During the last few years, several experimental and theoretical studies have focused on state selective charge exchange processes between charged ions and alkali metals. These data are of particular importance for the tokamak nuclear fusion reactor program, since diagnostics on the plasma usually rely on charge-exchange spectroscopy. In this sense, alkali metals, have been proposed as potential alternatives to excited hydrogen/deuterium for which laboratory experiments are not feasible at present. In this talk, we present our recent work involving ion collisions with alkali metals. Oscillatory structures in the angular differential charge-exchange cross sections obtained using the MOTRIMS technique are correctly described by classical trajectory Monte Carlo simulations. These oscillations are found to originate from the number of swaps the electron undergoes around the projectile-target potential saddle before capture takes place and are very prominent at impact energies below 10 keV/amu. Moreover, cross sections of higher order of differentiability also indicate that the swaps leave distinctive signatures in the (n,l)-state selective cross sections and in the photon line emission cross sections. Oscillatory structures for the x-ray hardness ratio parameter are also predicted. In collaboration with Ronnie Hoekstra, Zernike Institute for Advanced Materials, University of Groningen and Ronald Olson, Department of Physics, Missouri University of Science and Technology.

  19. Charge transport through DNA/DNA duplexes and DNA/RNA hybrids: complex mechanism study

    Czech Academy of Sciences Publication Activity Database

    Kratochvílová, Irena; Vala, M.; Weiter, M.; Špérová, M.; Schneider, Bohdan; Páv, Ondřej; Šebera, Jakub; Rosenberg, Ivan; Sychrovský, Vladimír

    2013-01-01

    Roč. 20, č. 1 (2013), s. 9-9 ISSN 1211-5894. [Discussions in Structural Molecular Biology. Annual Meeting of the Czech Society for Structural Biology /11./. 14.03.2013-16.03.2013, Nové Hrady] Institutional support: RVO:61388963 ; RVO:68378271 ; RVO:86652036 Keywords : charge transport * fluorescence spectroscopy * DFT Subject RIV: CF - Physical ; Theoretical Chemistry

  20. Polarization-dependent NEXAFS study of adsorption of long-chain surfactants on mechanically milled iron powder

    Energy Technology Data Exchange (ETDEWEB)

    Syugaev, A.V., E-mail: syual@mail.ru; Maratkanova, A.N.

    2014-08-15

    Highlights: • Plate-like particles modified with surfactant molecules were obtained under high-energy ball milling. • Adsorption layers were studied with polarization-dependent NEXAFS spectroscopy. • For the first time, arrangement of surfactants molecules on the powdered metal surface has been determined. • Tails of surfactant molecules (C-F/C-H) are shown to be oriented perpendicular to the particle surface. • Arrangement of carboxylate groups on the particle surfaces is discussed. - Abstract: In this work we have demonstrated the possibility of using the polarization-dependent NEXAFS spectra to study the structure of organic layers at the surface of powdered materials with plate-like shaped particles. The polarization dependence of the NEXAFS spectra may be easily obtained by just changing the angle between the X-ray beam direction and the substrate onto which the powder particles are set. For the first time, we have carried out a detailed study of the surfactant layers (n-perfluorononanoic and stearic acid), which are formed at the surface of iron plate-like particles under mechanical milling of iron powder with an addition of corresponding surfactants. The surfactant molecules are predominantly oriented perpendicular to the surface of the mechanically milled particles. Such orientation is similar to the arrangement of the molecules in the layers formed under equilibrium conditions, e.g. deposition from solutions. The changes in the chemical environment occurring in the molecule tails (defluorination or dehydrogenation) under mechanochemical treatment, do not result in a significant change in the molecular orientation and disordering of the adsorbed layer.

  1. An insight into the mechanism of charge-transfer of hybrid polymer:ternary/quaternary chalcopyrite colloidal nanocrystals

    Directory of Open Access Journals (Sweden)

    Parul Chawla

    2014-08-01

    Full Text Available In this work, we have demonstrated the structural and optoelectronic properties of the surface of ternary/quaternary (CISe/CIGSe/CZTSe chalcopyrite nanocrystallites passivated by tri-n-octylphosphine-oxide (TOPO and tri-n-octylphosphine (TOP and compared their charge transfer characteristics in the respective polymer: chalcopyrite nanocomposites by dispersing them in poly(3-hexylthiophene polymer. It has been found that CZTSe nanocrystallites due to their high crystallinity and well-ordered 3-dimensional network in its pristine form exhibit a higher steric- and photo-stability, resistance against coagulation and homogeneity compared to the CISe and CIGSe counterparts. Moreover, CZTSe nanocrystallites display efficient photoluminescence quenching as evident from the high value of the Stern–Volmer quenching constant (KSV and eventually higher charge transfer efficiency in their respective polymer P3HT:CZTSe composites. We modelled the dependency of the charge transfer from the donor and the charge separation mechanism across the donor–acceptor interface from the extent of crystallinity of the chalcopyrite semiconductors (CISe/CIGSe/CZTSe. Quaternary CZTSe chalcopyrites with their high crystallinity and controlled morphology in conjunction with regioregular P3HT polymer is an attractive candidate for hybrid solar cells applications.

  2. Breaking the hydrophobicity of the MscL pore: insights into a charge-induced gating mechanism.

    Directory of Open Access Journals (Sweden)

    Balasubramanian Chandramouli

    Full Text Available The mechanosensitive channel of large conductance (MscL is a protein that responds to membrane tension by opening a transient pore during osmotic downshock. Due to its large pore size and functional reconstitution into lipid membranes, MscL has been proposed as a promising artificial nanovalve suitable for biotechnological applications. For example, site-specific mutations and tailored chemical modifications have shown how MscL channel gating can be triggered in the absence of tension by introducing charged residues at the hydrophobic pore level. Recently, engineered MscL proteins responsive to stimuli like pH or light have been reported. Inspired by experiments, we present a thorough computational study aiming at describing, with atomistic detail, the artificial gating mechanism and the molecular transport properties of a light-actuated bacterial MscL channel, in which a charge-induced gating mechanism has been enabled through the selective cleavage of photo-sensitive alkylating agents. Properties such as structural transitions, pore dimension, ion flux and selectivity have been carefully analyzed. Besides, the effects of charge on alternative sites of the channel with respect to those already reported have been addressed. Overall, our results provide useful molecular insights into the structural events accompanying the engineered MscL channel gating and the interplay of electrostatic effects, channel opening and permeation properties. In addition, we describe how the experimentally observed ionic current in a single-subunit charged MscL mutant is obtained through a hydrophobicity breaking mechanism involving an asymmetric inter-subunit motion.

  3. Vertebrate kidney tubules elongate using a planar cell polarity-dependent, rosette-based mechanism of convergent extension.

    Science.gov (United States)

    Lienkamp, Soeren S; Liu, Kun; Karner, Courtney M; Carroll, Thomas J; Ronneberger, Olaf; Wallingford, John B; Walz, Gerd

    2012-12-01

    Cystic kidney diseases are a global public health burden, affecting over 12 million people. Although much is known about the genetics of kidney development and disease, the cellular mechanisms driving normal kidney tubule elongation remain unclear. Here, we used in vivo imaging to show for the first time that mediolaterally oriented cell intercalation is fundamental to vertebrate kidney morphogenesis. Unexpectedly, we found that kidney tubule elongation is driven in large part by a myosin-dependent, multicellular rosette-based mechanism, previously only described in Drosophila melanogaster. In contrast to findings in Drosophila, however, non-canonical Wnt and planar cell polarity (PCP) signaling is required to control rosette topology and orientation during vertebrate kidney tubule elongation. These data resolve long-standing questions concerning the role of PCP signaling in the developing kidney and, moreover, establish rosette-based intercalation as a deeply conserved cellular engine for epithelial morphogenesis.

  4. Mechanically Reconfigurable Single-Arm Spiral Antenna Array for Generation of Broadband Circularly Polarized Orbital Angular Momentum Vortex Waves.

    Science.gov (United States)

    Li, Long; Zhou, Xiaoxiao

    2018-03-23

    In this paper, a mechanically reconfigurable circular array with single-arm spiral antennas (SASAs) is designed, fabricated, and experimentally demonstrated to generate broadband circularly polarized orbital angular momentum (OAM) vortex waves in radio frequency domain. With the symmetrical and broadband properties of single-arm spiral antennas, the vortex waves with different OAM modes can be mechanically reconfigurable generated in a wide band from 3.4 GHz to 4.7 GHz. The prototype of the circular array is proposed, conducted, and fabricated to validate the theoretical analysis. The simulated and experimental results verify that different OAM modes can be effectively generated by rotating the spiral arms of single-arm spiral antennas with corresponding degrees, which greatly simplify the feeding network. The proposed method paves a reconfigurable way to generate multiple OAM vortex waves with spin angular momentum (SAM) in radio and microwave satellite communication applications.

  5. Interplay of Classical and Quantum Mechanics in the Theory of Charged-Particle Stopping

    Science.gov (United States)

    Sigmund, Peter

    A quarter of a century ago the author stepped into Jens Oddershede's office and asked for support on a problem involving computation with atomic wave functions in connection with a new theoretical scheme to treat stopping of charged particles at intermediate speed. This visit resulted in two related publications, two joint papers and a number of follow-up studies by Jens and several others. In 1989 a Sanibel Symposium was devoted to aspects of the penetration of charged particles through matter, and since then, quite a few quantum chemists have joined the community of theoreticians dealing with particle penetration. Niels Bohr, a pioneer in both disciplines, emphasized the significance of classical vs. quantal arguments in particle penetration. Not the least in view of the complexity of ab initio computations in this area, such considerations keep being relevant. This note adds new points to an old discussion based on recent developments.

  6. Mechanism of Crystallization and Implications for Charge Transport in Poly(3-ethylhexylthiophene) Thin Films

    KAUST Repository

    Duong, Duc T.

    2014-04-09

    In this work, crystallization kinetics and aggregate growth of poly(3-ethylhexylthiophene) (P3EHT) thin films are studied as a function of film thickness. X-ray diffraction and optical absorption show that individual aggregates and crystallites grow anisotropically and mostly along only two packing directions: the alkyl stacking and the polymer chain backbone direction. Further, it is also determined that crystallization kinetics is limited by the reorganization of polymer chains and depends strongly on the film thickness and average molecular weight. Time-dependent, field-effect hole mobilities in thin films reveal a percolation threshold for both low and high molecular weight P3EHT. Structural analysis reveals that charge percolation requires bridged aggregates separated by a distance of ≈2-3 nm, which is on the order of the polymer persistence length. These results thus highlight the importance of tie molecules and inter-aggregate distance in supporting charge percolation in semiconducting polymer thin films. The study as a whole also demonstrates that P3EHT is an ideal model system for polythiophenes and should prove to be useful for future investigations into crystallization kinetics. Recrystallization kinetics and its relationship to charge transport in poly(3-ethylhexylthiophene) (P3EHT) thin films are investigated using a combination of grazing incidence X-ray diffraction, optical absorption, and field-effect transistor measurements. These results show that thin film crystallization kinetics is limited by polymer chain reorganization and that charge percolation depends strongly on the edge-to-edge distance between aggregates. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Electrical bistability and charge-transport mechanisms in cuprous sulfide nanosphere-poly(N-vinylcarbazole) composite films

    International Nuclear Information System (INIS)

    Tang Aiwei; Teng Feng; Liu Jie; Wang Yichao; Peng Hongshang; Hou Yanbing; Wang Yongsheng

    2011-01-01

    In this study, electrically bistable devices were fabricated by incorporating cuprous sulfide (Cu 2 S) nanospheres with mean size less than 10 nm into a poly(N-vinylcarbazole) (PVK) matrix. A remarkable electrical bistability was clearly observed in the current–voltage curves of the devices due to an electric-field-induced charge transfer between the dodecanethiol-capped Cu 2 S nanospheres and PVK. The maximum ON/OFF current ratio reached up to value as large as 10 4 , which was dependent on the mass ratios of Cu 2 S nanospheres to PVK, the amplitude of the scanning voltages, and the film thickness. The charge-transport mechanisms of the electrically bistable devices were described on the basis of the experimental results using different theoretical models of organic electronics.

  8. Reaction mechanism and nuclear correlations study by low energy pion double charge exchange

    International Nuclear Information System (INIS)

    Weinfeld, Z.

    1993-06-01

    In pion double-charge-exchange (DCX) reactions, a positive (negative) pion is incident on a nucleus and a negative (positive) pion emerges. These reactions are of fundamental interest since the process must involve at least two nucleons in order to conserve charge. Although two nucleon processes are present in many reactions they are usually masked by the dominant single nucleon processes. DCX is unique in that respect since it is a two nucleon process in lowest order and thus may be sensitive to two-nucleon correlations. Measurements of low energy pion double-charge-exchange reactions to the double-isobaric-analog-state (DIAS) and ground-state (GS) of the residual nucleus provide new means for studying nucleon-nucleon correlations in nuclei. At low energies (T π 7/2 shell at energies ranging from 25 to 65 MeV. Cross sections were measured on 42,44,48 Ca, 46,50 Ti and 54 Fe. The calcium isotopes make a good set of nuclei on which to study the effects of correlations in DCX reactions

  9. The ion dependent change in the mechanism of charge storage of chemically preintercalated bilayered vanadium oxide electrodes

    Science.gov (United States)

    Clites, Mallory; Pomerantseva, Ekaterina

    2017-08-01

    Chemical pre-intercalation is a soft chemistry synthesis approach that allows for the insertion of inorganic ions into the interlayer space of layered battery electrode materials prior to electrochemical cycling. Previously, we have demonstrated that chemical pre-intercalation of Na+ ions into the structure of bilayered vanadium oxide (δ-V2O5) results in record high initial capacities above 350 mAh g-1 in Na-ion cells. This performance is attributed to the expanded interlayer spacing and predefined diffusion pathways achieved by the insertion of charge-carrying ions. However, the effect of chemical pre-intercalation of δ-V2O5 has not been studied for other ion-based systems beyond sodium. In this work, we report the effect of the chemically preintercalated alkali ion size on the mechanism of charge storage of δ- MxV2O5 (M = Li, Na, K) in Li-ion, Na-ion, and K-ion batteries, respectively. The interlayer spacing of the δ-MxV2O5 varied depending on inserted ion, with 11.1 Å achieved for Li-preintercalated δ-V2O5, 11.4 Å for Na-preintercalated δ- V2O5, and 9.6 Å for K-preintercalated δ-V2O5. Electrochemical performance of each material has been studied in its respective ion-based system (δ-LixV2O5 in Li-ion cells, δ-NaxV2O5 in Na-ion cells, and δ-KxV2O5 in K-ion cells). All materials demonstrated high initial capacities above 200 mAh g-1. However, the mechanism of charge storage differed depending on the charge-carrying ion, with Li-ion cells demonstrating predominantly pseudocapacitive behavior and Naion and K-ion cells demonstrating a significant portion of capacity from diffusion-limited intercalation processes. In this study, the combination of increased ionic radii of the charge-carrying ions and decreased synthesized interlayer spacing of the bilayered vanadium oxide phase correlates to an increase in the portion of capacity attributed diffusion-limited charge-storage processes.

  10. All in one - integrating cell polarity, meiosis, mitosis and mechanical forces in early oocyte differentiation in vertebrates.

    Science.gov (United States)

    Elkouby, Yaniv M

    2017-01-01

    While the differentiation of oocytes is key for embryonic development, and its investigation is crucial for advancing our understanding of human reproduction and fertility, many fundamental questions in oogenesis have been long standing. However, recent technical advances have led to several breakthroughs mainly in mice and zebrafish. Here I review these recent findings, including regulation and organization of the germline cyst, the mechanistics of chromosomal pairing, establishment of cell polarity, and formation of a universal mRNA-protein (mRNP) granule called the Balbiani body. I discuss common themes in oogenesis from frogs, fish and mouse and compare them to findings from C. elegans and Drosophila. The zebrafish juvenile ovary is an attractive model where these individual processes can be investigated, but also revealing how they are inter-coordinated in oocyte differentiation. A conserved cellular organizer was discovered in the zebrafish oocyte that seems to function at a nexus of oocyte differentiation. This organizer, termed the Meiotic Vegetal Center (MVC), is composed of the oocyte centrosome, and couples meiotic chromosomal pairing with oocyte polarization and Balbiani body formation. The MVC breaks the oocyte symmetry, is regulated by upstream mitotic division in the cyst and nucleates Balbiani body mRNPs prion-like aggregation downstream. These processes can shed new light on broad questions in biology, such as how mitosis contributes to cell polarity, and how prion aggregation which lead to neurodegenerative disease when awry, is regulated in a physiological context. Furthermore, novel cytoskeletal structures can unravel cytoplasmic mechanical functions in chromosomal pairing. Finally, together with recently developed tools, genome editing technology now enables a robust genetic analysis of these fundamental processes in the zebrafish, paving the way for a comprehensive cell and developmental view of vertebrate oogenesis.

  11. Field theory of polar continua

    International Nuclear Information System (INIS)

    Heinz, C.

    1988-01-01

    A Lagrangian density in the polar space X 1+3+3 depending of the potentials and their derivativs and of the fluxes is introduced. The potentials are then the mechanical and electromagnetic potentials, the potentials of gravity and in the polar space X 1+3+3 the components of affine connection. The fluxes are essentially the tangential motors of the mechanical and electromagnetic world-lines multiplied with the density of mass and electric charge. The Hamilton principle gives, with the in variational calculus usual integrations by part, here done via the theorem of Gauss, the equations of motion and the field equations. The conditions of integrability for these equations are discussed. (author)

  12. Point charge embedding for ONIOM excited states calculations

    Science.gov (United States)

    Biancardi, Alessandro; Barnes, Jeremy; Caricato, Marco

    2016-12-01

    Hybrid quantum mechanical methods can assist in the interpretation and prediction of the electronic spectra of large molecular structures. In this work, we study the performance of the ONIOM (Our own N-layered Integrated molecular Orbital molecular Mechanics) hybrid method for the calculation of transition energies and oscillator strengths by embedding the core region in a field of fixed point charges. These charges introduce polarization effects from the substituent groups to the core region. We test various charge definitions, with particular attention to the issue of overpolarization near the boundary between layers. To minimize this issue, we fit the charges on the electrostatic potential of the entire structure in the presence of the link atoms used to cap dangling bonds. We propose two constrained fitting strategies: one that produces an average set of charges common to both model system calculations, EE(L1), and one that produces two separate sets of embedding charges, EE(L2). The results from our tests show that indeed electronic embedding with constrained-fitted charges tends to improve the performance of ONIOM compared to non-embedded calculations. However, the EE(L2) charges work best for transition energies, and the EE(L1) charges work best for oscillator strengths. This may be an indication that fixed point charges do not have enough flexibility to adapt to each system, and other effects (e.g., polarization of the embedding field) may be necessary.

  13. Model of polar auxin transport coupled to mechanical forces retrieves robust morphogenesis along the Arabidopsis root

    Science.gov (United States)

    Romero-Arias, J. Roberto; Hernández-Hernández, Valeria; Benítez, Mariana; Alvarez-Buylla, Elena R.; Barrio, Rafael A.

    2017-03-01

    Stem cells are identical in many scales, they share the same molecular composition, DNA, genes, and genetic networks, yet they should acquire different properties to form a functional tissue. Therefore, they must interact and get some external information from their environment, either spatial (dynamical fields) or temporal (lineage). In this paper we test to what extent coupled chemical and physical fields can underlie the cell's positional information during development. We choose the root apical meristem of Arabidopsis thaliana to model the emergence of cellular patterns. We built a model to study the dynamics and interactions between the cell divisions, the local auxin concentration, and physical elastic fields. Our model recovers important aspects of the self-organized and resilient behavior of the observed cellular patterns in the Arabidopsis root, in particular, the reverse fountain pattern observed in the auxin transport, the PIN-FORMED (protein family of auxin transporters) polarization pattern and the accumulation of auxin near the region of maximum curvature in a bent root. Our model may be extended to predict altered cellular patterns that are expected under various applied auxin treatments or modified physical growth conditions.

  14. A review of polarized ion sources

    International Nuclear Information System (INIS)

    Schmor, P.W.

    1995-06-01

    The two main types of polarized ion sources in use on accelerators today are the Atomic Beam Polarized Ion Source (ABIS) source and the Optically Pumped Polarized Ion Source (OPPIS). Both types can provide beams of nuclearly polarized light ions which are either positively or negatively charged. Heavy ion polarized ion sources for accelerators are being developed. (author). 35 refs., 1 tab

  15. Ion desorption induced by charged particle beams: mechanisms and mass spectroscopy

    International Nuclear Information System (INIS)

    Silveira, E.F. da; Schweikert, E.A.

    1988-01-01

    Surface analysis, through desorption, induced by fast particles, is presented and discussed. The stopping of projectils is essentially made by collisions with the target electrons. The desorbed particles are generally emmited with kinetic energy from 0.1 to 20 eV. Mass, charge, velocity and emission angle give information about the surface components, its structure as well as beam-solid interaction processes. Time-of-flight mass spectroscopy of desorbed ions, determine the mass of organic macromolecules and biomolecules. (A.C.A.S.) [pt

  16. Charge-dependent non-bonded interaction methods for use in quantum mechanical modeling of condensed phase reactions

    Science.gov (United States)

    Kuechler, Erich R.

    Molecular modeling and computer simulation techniques can provide detailed insight into biochemical phenomena. This dissertation describes the development, implementation and parameterization of two methods for the accurate modeling of chemical reactions in aqueous environments, with a concerted scientific effort towards the inclusion of charge-dependent non-bonded non-electrostatic interactions into currently used computational frameworks. The first of these models, QXD, modifies interactions in a hybrid quantum mechanical/molecular (QM/MM) mechanical framework to overcome the current limitations of 'atom typing' QM atoms; an inaccurate and non-intuitive practice for chemically active species as these static atom types are dictated by the local bonding and electrostatic environment of the atoms they represent, which will change over the course of the simulation. The efficacy QXD model is demonstrated using a specific reaction parameterization (SRP) of the Austin Model 1 (AM1) Hamiltonian by simultaneously capturing the reaction barrier for chloride ion attack on methylchloride in solution and the solvation free energies of a series of compounds including the reagents of the reaction. The second, VRSCOSMO, is an implicit solvation model for use with the DFTB3/3OB Hamiltonian for biochemical reactions; allowing for accurate modeling of ionic compound solvation properties while overcoming the discontinuous nature of conventional PCM models when chemical reaction coordinates. The VRSCOSMO model is shown to accurately model the solvation properties of over 200 chemical compounds while also providing smooth, continuous reaction surfaces for a series of biologically motivated phosphoryl transesterification reactions. Both of these methods incorporate charge-dependent behavior into the non-bonded interactions variationally, allowing the 'size' of atoms to change in meaningful ways with respect to changes in local charge state, as to provide an accurate, predictive and

  17. Azimuthal transverse single-spin asymmetries of inclusive jets and charged pions within jets from polarized-proton collisions at √{s }=500 GeV

    Science.gov (United States)

    Adamczyk, L.; Adams, J. R.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Ajitanand, N. N.; Alekseev, I.; Anderson, D. M.; Aoyama, R.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Ashraf, M. U.; Attri, A.; Averichev, G. S.; Bai, X.; Bairathi, V.; Barish, K.; Behera, A.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Bouchet, J.; Brandenburg, J. D.; Brandin, A. V.; Brown, D.; Bryslawskyj, J.; Bunzarov, I.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Campbell, J. M.; Cebra, D.; Chakaberia, I.; Chaloupka, P.; Chang, Z.; Chankova-Bunzarova, N.; Chatterjee, A.; Chattopadhyay, S.; Chen, X.; Chen, X.; Chen, J. H.; Cheng, J.; Cherney, M.; Christie, W.; Contin, G.; Crawford, H. J.; Das, S.; Dedovich, T. G.; Deng, J.; Deppner, I. M.; Derevschikov, A. A.; Didenko, L.; Dilks, C.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Dunlop, J. C.; Efimov, L. G.; Elsey, N.; Engelage, J.; Eppley, G.; Esha, R.; Esumi, S.; Evdokimov, O.; Ewigleben, J.; Eyser, O.; Fatemi, R.; Fazio, S.; Federic, P.; Federicova, P.; Fedorisin, J.; Feng, Z.; Filip, P.; Finch, E.; Fisyak, Y.; Flores, C. E.; Fujita, J.; Fulek, L.; Gagliardi, C. A.; Geurts, F.; Gibson, A.; Girard, M.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, A.; Guryn, W.; Hamad, A. I.; Hamed, A.; Harlenderova, A.; Harris, J. W.; He, L.; Heppelmann, S.; Heppelmann, S.; Herrmann, N.; Hirsch, A.; Horvat, S.; Huang, B.; Huang, T.; Huang, X.; Huang, H. Z.; Humanic, T. J.; Huo, P.; Igo, G.; Jacobs, W. W.; Jentsch, A.; Jia, J.; Jiang, K.; Jowzaee, S.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kapukchyan, D.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Khan, Z.; Kikoła, D. P.; Kim, C.; Kisel, I.; Kisiel, A.; Kochenda, L.; Kocmanek, M.; Kollegger, T.; Kosarzewski, L. K.; Kraishan, A. F.; Krauth, L.; Kravtsov, P.; Krueger, K.; Kulathunga, N.; Kumar, L.; Kvapil, J.; Kwasizur, J. H.; Lacey, R.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Li, X.; Li, W.; Li, Y.; Li, C.; Lidrych, J.; Lin, T.; Lisa, M. A.; Liu, F.; Liu, P.; Liu, Y.; Liu, H.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, X.; Luo, S.; Ma, G. L.; Ma, L.; Ma, R.; Ma, Y. G.; Magdy, N.; Majka, R.; Mallick, D.; Margetis, S.; Markert, C.; Matis, H. S.; Mayes, D.; Meehan, K.; Mei, J. C.; Miller, Z. W.; Minaev, N. G.; Mioduszewski, S.; Mishra, D.; Mizuno, S.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nasim, Md.; Nayak, T. K.; Nelson, J. M.; Nemes, D. B.; Nie, M.; Nigmatkulov, G.; Niida, T.; Nogach, L. V.; Nonaka, T.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Okorokov, V. A.; Olvitt, D.; Page, B. S.; Pak, R.; Pandit, Y.; Panebratsev, Y.; Pawlik, B.; Pei, H.; Perkins, C.; Pluta, J.; Poniatowska, K.; Porter, J.; Posik, M.; Pruthi, N. K.; Przybycien, M.; Putschke, J.; Quintero, A.; Ramachandran, S.; Ray, R. L.; Reed, R.; Rehbein, M. J.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Roth, J. D.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Salur, S.; Sandweiss, J.; Saur, M.; Schambach, J.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Schweid, B. R.; Seger, J.; Sergeeva, M.; Seto, R.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Shen, W. Q.; Shi, S. S.; Shi, Z.; Shou, Q. Y.; Sichtermann, E. P.; Sikora, R.; Simko, M.; Singha, S.; Skoby, M. J.; Smirnov, N.; Smirnov, D.; Solyst, W.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stewart, D. J.; Strikhanov, M.; Stringfellow, B.; Suaide, A. A. P.; Sugiura, T.; Sumbera, M.; Summa, B.; Sun, Y.; Sun, X.; Sun, X. M.; Surrow, B.; Svirida, D. N.; Tang, A. H.; Tang, Z.; Taranenko, A.; Tarnowsky, T.; Tawfik, A.; Thäder, J.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Todoroki, T.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Tripathy, S. K.; Trzeciak, B. A.; Tsai, O. D.; Ullrich, T.; Underwood, D. G.; Upsal, I.; Van Buren, G.; van Nieuwenhuizen, G.; Vasiliev, A. N.; Videbæk, F.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wang, G.; Wang, Y.; Wang, F.; Wang, Y.; Webb, G.; Webb, J. C.; Wen, L.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y.; Xiao, Z. G.; Xie, G.; Xie, W.; Xu, Y. F.; Xu, J.; Xu, Q. H.; Xu, N.; Xu, Z.; Yang, S.; Yang, Y.; Yang, C.; Yang, Q.; Ye, Z.; Ye, Z.; Yi, L.; Yip, K.; Yoo, I.-K.; Yu, N.; Zbroszczyk, H.; Zha, W.; Zhang, Z.; Zhang, J.; Zhang, S.; Zhang, S.; Zhang, J.; Zhang, Y.; Zhang, X. P.; Zhang, J. B.; Zhao, J.; Zhong, C.; Zhou, L.; Zhou, C.; Zhu, X.; Zhu, Z.; Zyzak, M.; STAR Collaboration

    2018-02-01

    We report the first measurements of transverse single-spin asymmetries for inclusive jet and jet+π± production at midrapidity from transversely polarized proton-proton collisions at √{s }=500 GeV . The data were collected in 2011 with the STAR detector sampled from 23 pb-1 integrated luminosity with an average beam polarization of 53%. Asymmetries are reported for jets with transverse momenta 6 polarized Collins fragmentation function; and the first measurement of the "Collins-like" asymmetry, sensitive to linearly polarized gluons. Within the present statistical precision, inclusive-jet and Collins-like asymmetries are small, with the latter allowing the first experimental constraints on gluon linear polarization in a polarized proton. At higher values of jet transverse momenta, we observe the first nonzero Collins asymmetries in polarized-proton collisions, with a statistical significance of greater than 5 σ . The results span a range of x similar to results from semi-inclusive deep-inelastic scattering but at much higher Q2. The Collins results enable tests of universality and factorization breaking in the transverse momentum-dependent formulation of perturbative quantum chromodynamics.

  18. Estimating and modeling charge transfer from the SAPT induction energy.

    Science.gov (United States)

    Deng, Shi; Wang, Qiantao; Ren, Pengyu

    2017-10-05

    Recent studies using quantum mechanics energy decomposition methods, for example, SAPT and ALMO, have revealed that the charge transfer energy may play an important role in short ranged inter-molecular interactions, and have a different distance dependence comparing with the polarization energy. However, the charge transfer energy component has been ignored in most current polarizable or non-polarizable force fields. In this work, first, we proposed an empirical decomposition of SAPT induction energy into charge transfer and polarization energy that mimics the regularized SAPT method (ED-SAPT). This empirical decomposition is free of the divergence issue, hence providing a good reference for force field development. Then, we further extended this concept in the context of AMOEBA polarizable force field, proposed a consistent approach to treat the charge transfer phenomenon. Current results show a promising application of this charge transfer model in future force field development. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  19. Discrete allowed and forbidden states in the classical mechanical domain in the charged particle motion in a magnetic field

    International Nuclear Information System (INIS)

    Varma, R.K.; Punithavelu, A.M.; Banerjee, S.B.

    1994-01-01

    The properties of the motion of charged particles injected almost parallel to the magnetic field are studied by measuring the electron current as a function of the cathode voltage (electron energy), as electrons from the gun traverse a distance L to the detector. The plate current is found to exhibit oscillatory behaviour in contradistinction with the behaviour expected according to the standard classical mechanical paradigm, with the peaks fitting a relation obtained from a quantum like theory predicting such a behaviour. (author). 4 refs, 1 fig, 1 tab

  20. Effective polarization interaction potentials of the partially ionized dense plasma

    Energy Technology Data Exchange (ETDEWEB)

    Ramazanov, T S [IETP, Al Farabi Kazakh National University, Tole Bi 96a, 050012 Almaty (Kazakhstan); Dzhumagulova, K N [IETP, Al Farabi Kazakh National University, Tole Bi 96a, 050012 Almaty (Kazakhstan); Omarbakiyeva, Yu A [IETP, Al Farabi Kazakh National University, Tole Bi 96a, 050012 Almaty (Kazakhstan); Roepke, G [Institute of Physics, University of Rostock, D-18051 Rostock (Germany)

    2006-04-28

    The effective polarization interaction potential between charged and neutral particles is considered for a partially ionized plasma. This pseudopotential is deduced taking into account quantum-mechanical effects at short distances as well as screening effects at large distances. Furthermore, a cutoff radius is obtained using a modified effective-range theory. Explicit results for parameters describing the interaction of the atom with charged particles are given.

  1. Measurement of the polarization parameter for antiproton-proton annihilation into charged pion and kaon pairs between 1.0 and 2.2 GeV/c

    International Nuclear Information System (INIS)

    Carter, A.A.; Coupland, M.; Eisenhandler, E.; Franklyn, C.; Gibson, W.R.; Hojvat, C.; Jeremiah, D.R.; Kalmus, P.I.P.; Pritchard, T.W.; Atkinson, M.; Duke, P.J.; Williams, D.T.; Woulds, J.N.; Arnison, G.T.J.; Astbury, A.; Hill, D.; Jones, D.P.

    1977-01-01

    The polarization parameter P for the reactions anti pp→π - π + and anti pp→K - K + has been measured over essentially the full angular range at 11 laboratory momenta between 1.0 and 2.2 GeV/c, using a proton target polarized perpendicular to the scattering plane. The angles and momenta of both final state particles were determined from wire spark chambers, using the deflection caused by the polarized target magnet. Between 1000 and 5300 p - π + events, and 140 and 1300 K - K + events, were measured at each momentum. Differential cross sections for anti pp→π - π + were obtained. These are in excellent agreement with previous results. The polarization parameter for both channels is very close to +1 over much of the angular range. Legendre polynomial fits to the data are presented. (Auth.)

  2. Spin-polarization dependent carrier recombination dynamics and spin relaxation mechanism in asymmetrically doped (110) n-GaAs quantum wells

    Science.gov (United States)

    Teng, Lihua; Jiang, Tianran; Wang, Xia; Lai, Tianshu

    2018-05-01

    Carrier recombination and electron spin relaxation dynamics in asymmetric n-doped (110) GaAs/AlGaAs quantum wells are investigated with time-resolved pump-probe spectroscopy. The experiment results reveal that the measured carrier recombination time depends strongly on the polarization of pump pulse. With the same pump photon flux densities, the recombination time of spin-polarized carriers is always longer than that of the spin-balanced carriers except at low pump photon flux densities, this anomaly originates from the polarization-sensitive nonlinear absorption effect. Differing from the traditional views, in the low carrier density regime, the D'yakonov-Perel' (DP) mechanism can be more important than the Bir-Aronov-Pikus (BAP) mechanism, since the DP mechanism takes effect, the spin relaxation time in (110) GaAs QWs is shortened obviously via asymmetric doping.

  3. Modeling the Electric Potential and Surface Charge Density Near Charged Thunderclouds

    Science.gov (United States)

    Neel, Matthew Stephen

    2018-03-01

    Thundercloud charge separation, or the process by which the bottom portion of a cloud gathers charge and the top portion of the cloud gathers the opposite charge, is still not thoroughly understood. Whatever the mechanism, though, a charge separation definitely exists and can lead to electrostatic discharge via cloud-to-cloud lightning and cloud-to-ground lightning. We wish to examine the latter form, in which upward leaders from Earth connect with downward leaders from the cloud to form a plasma channel and produce lightning. Much of the literature indicates that the lower part of a thundercloud becomes negatively charged while the upper part becomes positively charged via convective charging, although the opposite polarity can certainly exist along with various, complex intra-cloud currents. It is estimated that >90% of cloud-to-ground lightning is "negative lightning," or the flow of charges from the bottom of the cloud, while the remaining the flow of charges from the top of the cloud. We wish to understand the electric potential surrounding charged thunderclouds as well as the resulting charge density on the surface of Earth below them. In this paper we construct a simple and adaptable model that captures the very basic features of the cloud/ground system and that exhibits conditions favorable for both forms of lightning. In this way, we provide a practical application of electrostatic dipole physics as well as the method of images that can serve as a starting point for further modeling and analysis by students.

  4. Charge storage and tunneling mechanism of Ni nanocrystals embedded HfOx film

    International Nuclear Information System (INIS)

    Zhu, H. X.; Zhang, T.; Wang, R. X.; Zhang, Y. Y.; Li, L. T.; Qiu, X. Y.

    2016-01-01

    A nano-floating gate memory structure based on Ni nanocrystals (NCs) embedded HfO x film is deposited by means of radio-frequency magnetron sputtering. Microstructure investigations reveal that self-organized Ni-NCs with diameters of 4-8 nm are well dispersed in amorphous HfO x matrix. Pt/Ni-NCs embedded HfO x /Si/Ag capacitor structures exhibit voltage-dependent capacitance-voltage hysteresis, and a maximum flat-band voltage shift of 1.5 V, corresponding to a charge storage density of 6.0 × 10 12 electrons/cm 2 , is achieved. These capacitor memory cells exhibit good endurance characteristic up to 4 × 10 4 cycles and excellent retention performance of 10 5 s, fulfilling the requirements of next generation non-volatile memory devices. Schottky tunneling is proven to be responsible for electrons tunneling in these capacitors.

  5. Neutrino mass matrix suppression by Abelian charges with see-saw mechanism

    CERN Document Server

    Nielsen, Holger Bech

    2000-01-01

    We have investigated a neutrino mass matrix model without supersymmetry including three see-saw right-handed neutrinos around order $10^{12}$ GeV masses, aiming at a picture with all small numbers explained as being due to approximately conserved gauge charges. The prediction of the solar neutrino mixing angle is given by $\\sin^22\\theta_{\\odot}= 3 {+3\\atop -2}\\times10^{-2}$; in fact, the solar mixing angle is, apart from detailed order unity corrections, equal to the Cabibbo angle. Furthermore the ratio of the solar neutrino mass square difference to that for the atmospheric neutrino oscillation is predicted to $6 {+11\\atop -4}\\times10^{-4}$ and is given by the same Cabibbo angle related parameter $\\xi$ as $6 \\xi^4$.

  6. Mechanisms for charge-transfer processes at electrode/solid-electrolyte interfaces.

    Energy Technology Data Exchange (ETDEWEB)

    Chueh, William; El Gabaly Marquez, Farid; Whaley, Josh A.; McCarty, Kevin F.; McDaniel, Anthony H.; Farrow, Roger L.

    2011-11-01

    This report summarizes the accomplishments of a Laboratory-Directed Research and Development (LDRD) project focused on developing and applying new x-ray spectroscopies to understand and improve electric charge transfer in electrochemical devices. Our approach studies the device materials as they function at elevated temperature and in the presence of sufficient gas to generate meaningful currents through the device. We developed hardware and methods to allow x-ray photoelectron spectroscopy to be applied under these conditions. We then showed that the approach can measure the local electric potentials of the materials, identify the chemical nature of the electrochemical intermediate reaction species and determine the chemical state of the active materials. When performed simultaneous to traditional impedance-based analysis, the approach provides an unprecedented characterization of an operating electrochemical system.

  7. ZnO nanowires: Synthesis and charge transfer mechanism in the detection of ammonia vapour

    Science.gov (United States)

    Nancy Anna Anasthasiya, A.; Ramya, S.; Rai, P. K.; Jeyaprakash, B. G.

    2018-01-01

    ZnO nanowires with hexagonal wurtzite structure were grown on the glass substrate using Successive Ionic Layer Adsorption and Reaction (SILAR) method. Both experimental and theoretical studies demonstrated that NH3 chemisorbed and transferred the charge to the surface of the nanowire via its nitrogen site to the zinc site of ZnO nanowires, leading to the detection of NH3 vapour. The adsorbed ammonia dissociated into NH2 and H due to steric repulsion, and then into N2 and H2 gas. The formation of the N2 gas during the desorption process confirmed by observing peak at 14 and 28 m/z in the GC-MS spectrum.

  8. Charge storage and tunneling mechanism of Ni nanocrystals embedded HfO{sub x} film

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, H. X.; Zhang, T.; Wang, R. X.; Zhang, Y. Y.; Li, L. T.; Qiu, X. Y., E-mail: qxy2001@swu.edu.cn [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China)

    2016-05-15

    A nano-floating gate memory structure based on Ni nanocrystals (NCs) embedded HfO{sub x} film is deposited by means of radio-frequency magnetron sputtering. Microstructure investigations reveal that self-organized Ni-NCs with diameters of 4-8 nm are well dispersed in amorphous HfO{sub x} matrix. Pt/Ni-NCs embedded HfO{sub x}/Si/Ag capacitor structures exhibit voltage-dependent capacitance-voltage hysteresis, and a maximum flat-band voltage shift of 1.5 V, corresponding to a charge storage density of 6.0 × 10{sup 12} electrons/cm{sup 2}, is achieved. These capacitor memory cells exhibit good endurance characteristic up to 4 × 10{sup 4} cycles and excellent retention performance of 10{sup 5} s, fulfilling the requirements of next generation non-volatile memory devices. Schottky tunneling is proven to be responsible for electrons tunneling in these capacitors.

  9. The Physics of Polarization

    Science.gov (United States)

    Landi Degl'Innocenti, Egidio

    2015-10-01

    The introductory lecture that has been delivered at this Symposium is a condensed version of an extended course held by the author at the XII Canary Island Winter School from November 13 to November 21, 2000. The full series of lectures can be found in Landi Degl'Innocenti (2002). The original reference is organized in 20 Sections that are here itemized: 1. Introduction, 2. Description of polarized radiation, 3. Polarization and optical devices: Jones calculus and Muller matrices, 4. The Fresnel equations, 5. Dichroism and anomalous dispersion, 6. Polarization in everyday life, 7. Polarization due to radiating charges, 8. The linear antenna, 9. Thomson scattering, 10. Rayleigh scattering, 11. A digression on Mie scattering, 12. Bremsstrahlung radiation, 13. Cyclotron radiation, 14. Synchrotron radiation, 15. Polarization in spectral lines, 16. Density matrix and atomic polarization, 17. Radiative transfer and statistical equilibrium equations, 18. The amplification condition in polarized radiative transfer, and 19. Coupling radiative transfer and statistical equilibrium equations.

  10. Nanoscale insight into the exfoliation mechanism of graphene with organic dyes: effect of charge, dipole and molecular structure.

    Science.gov (United States)

    Schlierf, Andrea; Yang, Huafeng; Gebremedhn, Elias; Treossi, Emanuele; Ortolani, Luca; Chen, Liping; Minoia, Andrea; Morandi, Vittorio; Samorì, Paolo; Casiraghi, Cinzia; Beljonne, David; Palermo, Vincenzo

    2013-05-21

    We study the mechanism of surface adsorption of organic dyes on graphene, and successive exfoliation in water of these dye-functionalized graphene sheets. A systematic, comparative study is performed on pyrenes functionalized with an increasing number of sulfonic groups. By combining experimental and modeling investigations, we find an unambiguous correlation between the graphene-dye interaction energy, the molecular structure and the amount of graphene flakes solubilized. The results obtained indicate that the molecular dipole is not important per se, but because it facilitates adsorption on graphene by a "sliding" mechanism of the molecule into the solvent layer, facilitating the lateral displacement of the water molecules collocated between the aromatic cores of the dye and graphene. While a large dipole and molecular asymmetry promote the adsorption of the molecule on graphene, the stability and pH response of the suspensions obtained depend on colloidal stabilization, with no significant influence of molecular charging and dipole.

  11. Capacitive MEMS-based sensors : thermo-mechanical stability and charge trapping

    NARCIS (Netherlands)

    van Essen, M.C.

    2009-01-01

    Micro-Electro Mechanical Systems (MEMS) are generally characterized as miniaturized systems with electrostatically driven moving parts. In many cases, the electrodes are capacitively coupled. This basic scheme allows for a plethora of specifications and functionality. This technology has presently

  12. Stable charged antiparallel domain walls in hyperferroelectrics

    Science.gov (United States)

    Liu, S.; Cohen, R. E.

    2017-06-01

    Charge-neutral 180° domain walls that separate domains of antiparallel polarization directions are common structural topological defects in ferroelectrics. In normal ferroelectrics, charged 180° domain walls running perpendicular to the polarization directions are highly energetically unfavorable because of the depolarization field and are difficult to stabilize. We explore both neutral and charged 180° domain walls in hyperferroelectrics, a class of proper ferroelectrics with persistent polarization in the presence of a depolarization field, using density functional theory. We obtain zero temperature equilibrium structures of head-to-head and tail-to-tail walls in recently discovered ABC-type hexagonal hyperferroelectrics. Charged domain walls can also be stabilized in canonical ferroelectrics represented by LiNbO3 without any dopants, defects or mechanical clamping. First-principles electronic structure calculations show that charged domain walls can reduce and even close the band gap of host materials and support quasi-two-dimensional electron(hole) gas with enhanced electrical conductivity.

  13. On the theory of pyro- and ferroelectrics: Dipole moment density and polarization

    Science.gov (United States)

    Belyavskii, V. I.; Gorbatsevich, A. A.

    2017-04-01

    The physical origin of the ambiguity related to the dependence of the polarization on the choice of the unit cell in a crystal is established in the framework of classical electrodynamics. It is shown that the electric polarization of a crystal is determined not only by the charge distribution in the unit cell (dipole moment density) but also by the microscopic mechanism of symmetry breaking in the polar phase. An approach to the calculation of the polarization invariant with respect to the choice of the unit cell is suggested. It is demonstrated that the dependence of the polarization on the mechanism of formation of the polar phase exists in the "modern topological theory" of polarization too.

  14. Molecular-level mechanisms of vibrational frequency shifts in a polar liquid.

    Science.gov (United States)

    Morales, Christine M; Thompson, Ward H

    2011-06-16

    A molecular-level analysis of the origins of the vibrational frequency shifts of the CN stretching mode in neat liquid acetonitrile is presented. The frequency shifts and infrared spectrum are calculated using a perturbation theory approach within a molecular dynamics simulation and are in good agreement with measured values reported in the literature. The resulting instantaneous frequency of each nitrile group is decomposed into the contributions from each molecule in the liquid and by interaction type. This provides a detailed picture of the mechanisms of frequency shifts, including the number of surrounding molecules that contribute to the shift, the relationship between their position and relative contribution, and the roles of electrostatic and van der Waals interactions. These results provide insight into what information is contained in infrared (IR) and Raman spectra about the environment of the probed vibrational mode. © 2011 American Chemical Society

  15. Increasing nuclear safety and operational reliability by upgrading the charging pump mechanical sealing system

    International Nuclear Information System (INIS)

    Loenhout, Gerard van; Nilsson, Peter; Jehander, Magnus

    2016-01-01

    For the Ringhals-2 nuclear power plant, three installed centrifugal pumps were designated to have a combined High Head Safety Injection function, as well as a Chemical Volume Control System function. The pumps were originally installed with rubber bellow type mechanical seals, which over time had demonstrated an unreliable sealing performance by displaying high leakages. In 2002, the Ringhals Maintenance engineers initiated to identify a more reliable and robust shaft sealing solution. In 2007, the project was launched and the installation of the first, new mechanical sealing solution took place in the autumn of 2011. In October 2014, these mechanical seals were dismantled and inspected. The inspection confirmed the expected reliability of the new solution.

  16. Chain propagation and termination mechanisms for polymerization of conjugated polar alkenes by [Al]-based frustrated Lewis pairs

    KAUST Repository

    He, Jianghua

    2014-11-25

    A combined experimental and theoretical study on mechanistic aspects of polymerization of conjugated polar alkenes by frustrated Lewis pairs (FLPs) based on N-heterocyclic carbene (NHC) and Al(C6F5)3 pairs is reported. This study consists of three key parts: structural characterization of active propagating intermediates, propagation kinetics, and chain-termination pathways. Zwitterionic intermediates that simulate the active propagating species in such polymerization have been generated or isolated from the FLP activation of monomers such as 2-vinylpyridine and 2-isopropenyl-2-oxazoline-one of which, IMes+-CH2C(Me)=(C3H2NO)Al(C6F5)3 - (2), has been structurally characterized. Kinetics performed on the polymerization of 2-vinylpyridine by ItBu/Al(C6F5)3 revealed that the polymerization follows a zero-order dependence on monomer concentration and a first-order dependence on initiator (ItBu) and activator [Al(C6F5)3] concentrations, indicating a bimolecular, activated monomer propagation mechanism. The Lewis pair polymerization of conjugate polar alkenes such as methacrylates is accompanied by competing chain-termination side reactions; between the two possible chain-termination pathways, the one that proceeds via intramolecular backbiting cyclization involving nucleophilic attack of the activated ester group of the growing polymer chain by the O-ester enolate active chain end to generate a six-membered lactone (δ-valerolactone)-terminated polymer chain is kinetically favored, but thermodynamically disfavored, over the pathway leading to the -ketoester-terminated chain, as revealed by computational studies.

  17. Angular distribution of electrons ejected by charged particles. IV. Combined classical and quantum-mechanical treatment

    NARCIS (Netherlands)

    Boesten, L.G.J.; Bonsen, T.F.M.

    1975-01-01

    Angular distributions of electrons ejected from helium by 100 and 300 keV protons have been calculated by a method which is a comination of the classical three-body collision theory and the quantum-mechanical Born approximation. The results of this theory have been compared with the corresponding

  18. Organic Chemistry Students' Ideas about Nucleophiles and Electrophiles: The Role of Charges and Mechanisms

    Science.gov (United States)

    Anzovino, Mary E.; Bretz, Stacey Lowery

    2015-01-01

    Organic chemistry students struggle with reaction mechanisms and the electron-pushing formalism (EPF) used by practicing organic chemists. Faculty have identified an understanding of nucleophiles and electrophiles as one conceptual prerequisite to mastery of the EPF, but little is known about organic chemistry students' knowledge of nucleophiles…

  19. Selection of tRNA charging quality control mechanisms that increase mistranslation of the genetic code

    DEFF Research Database (Denmark)

    Yadavalli, Srujana S; Ibba, Michael

    2013-01-01

    Mistranslation can follow two events during protein synthesis: production of non-cognate amino acid:transfer RNA (tRNA) pairs by aminoacyl-tRNA synthetases (aaRSs) and inaccurate selection of aminoacyl-tRNAs by the ribosome. Many aaRSs actively edit non-cognate amino acids, but editing mechanisms...

  20. Negative Ion MALDI Mass Spectrometry of Polyoxometalates (POMs): Mechanism of Singly Charged Anion Formation and Chemical Properties Evaluation

    Science.gov (United States)

    Boulicault, Jean E.; Alves, Sandra; Cole, Richard B.

    2016-08-01

    MALDI-MS has been developed for the negative ion mode analysis of polyoxometalates (POMs). Matrix optimization was performed using a variety of matrix compounds. A first group of matrixes offers MALDI mass spectra containing abundant intact singly charged anionic adduct ions, as well as abundant in-source fragmentations at elevated laser powers. A relative ranking of the ability to induce POM fragmentation is found to be: DAN > CHCA > CNA > DIT> HABA > DCTB > IAA. Matrixes of a second group provide poorer quality MALDI mass spectra without observable fragments. Sample preparation, including the testing of salt additives, was performed to optimize signals for a model POM, POMc12, the core structure of which bears four negative charges. The matrix 9-cyanoanthracene (CNA) provided the best signals corresponding to singly charged intact POMc12 anions. Decompositions of these intact anionic species were examined in detail, and it was concluded that hydrogen radical-induced mechanisms were not prevalent, but rather that the observed prompt fragments originate from transferred energy derived from initial electronic excitation of the CNA matrix. Moreover, in obtained MALDI mass spectra, clear evidence of electron transfer to analyte POM species was found: a manifestation of the POMs ability to readily capture electrons. The affinity of polyanionic POMc12 toward a variety of cations was evaluated and the following affinity ranking was established: Fe3+ > Al3+ > Li+ > Ga3+ > Co2+ > Cr3+ > Cu2+ > [Mn2+, Mg2+] > [Na+, K+]. Thus, from the available cationic species, specific adducts are preferentially formed, and evidence is given that these higher affinity POM complexes are formed in the gas phase during the early stages of plume expansion.

  1. Dynamical chaos and stochastic mechanism of high-energy negatively charged particle deflection by bent crystals

    International Nuclear Information System (INIS)

    Shul'ga, N.F.; Kirillin, I.V.; Truten', V.I.

    2011-01-01

    Deflection of high-energy negatively charged particles in straight and bent crystals through multiple scattering by crystal atomic strings was considered for the case in which the initial angle between the particle momentum and one of the main crystallographic axes was approximately four critical angles of axial channeling. It was shown that in a bent crystal with a small crystal thickness, when the crystal bend was less than the beam incidence angle, the beam deflected in the direction opposite to the direction of the crystal bend. At larger crystal thicknesses, the large part of the beam starts to deflect in the direction of the crystal bend. In addition, there is a group of particles that follow the crystal axis bend in the angular region of approximately the critical angle of axial channeling with respect to the current direction of the crystal axis. It was shown that in all of these deflection processes, the periodicity of the location of atomic strings in the crystal does not influence the angular distributions of scattered particles. This fact is connected with the effect of dynamical chaos in particle motion in the periodical field of bent crystal atomic strings. It was also shown that observed in a recent CERN experiment effect of beam deflection, when the angle between the initial particle momentum and the crystal axis was approximately four critical angles of axial channeling, is due to peculiarities of the stochastic multiple scattering of particles by bent crystal atomic strings. These peculiarities are connected with the effect of dynamical chaos in particle motion in crystals.

  2. Persistent polar depletion of stratospheric ozone and emergent mechanisms of ultraviolet radiation-mediated health dysregulation.

    Science.gov (United States)

    Dugo, Mark A; Han, Fengxiang; Tchounwou, Paul B

    2012-01-01

    Year 2011 noted the first definable ozone "hole" in the Arctic region, serving as an indicator to the continued threat of dangerous ultraviolet radiation (UVR) exposure caused by the deterioration of stratospheric ozone in the northern hemisphere. Despite mandates of the Montreal Protocol to phase out the production of ozone-depleting chemicals (ODCs), the relative stability of ODCs validates popular notions of persistent stratospheric ozone for several decades. Moreover, increased UVR exposure through stratospheric ozone depletion is occurring within a larger context of physiologic stress and climate change across the biosphere. In this review, we provide commentaries on stratospheric ozone depletion with relative comparisons between the well-known Antarctic ozone hole and the newly defined ozone hole in the Arctic. Compared with the Antarctic region, the increased UVR exposure in the Northern Hemisphere poses a threat to denser human populations across North America, Europe, and Asia. In this context, we discuss emerging targets of UVR exposure that can potentially offset normal biologic rhythms in terms of taxonomically conserved photoperiod-dependent seasonal signaling and entrainment of circadian clocks. Consequences of seasonal shifts during critical life history stages can alter fitness and condition, whereas circadian disruption is increasingly becoming associated as a causal link to increased carcinogenesis. We further review the significance of genomic alterations via UVR-induced modulations of phase I and II transcription factors located in skin cells, the aryl hydrocarbon receptor (AhR), and the nuclear factor (erythroid-derived 2)-related factor 2 (Nrf2), with emphasis on mechanism that can lead to metabolic shifts and cancer. Although concern for adverse health consequences due to increased UVR exposure are longstanding, recent advances in biochemical research suggest that AhR and Nrf2 transcriptional regulators are likely targets for UVR

  3. A KEY PHYSICAL MECHANISM FOR UNDERSTANDING THE ENIGMATIC LINEAR POLARIZATION OF THE SOLAR Ba II AND Na I D{sub 1} LINES

    Energy Technology Data Exchange (ETDEWEB)

    Belluzzi, Luca; Trujillo Bueno, Javier [Instituto de Astrofisica de Canarias, E-38205 La Laguna, Tenerife (Spain)

    2013-09-10

    The linearly polarized spectrum of the solar limb radiation produced by scattering processes is of great diagnostic potential for exploring the magnetism of the solar atmosphere. This spectrum shows an impressive richness of spectral details and enigmatic Q/I signals, whose physical origin must be clearly understood before they can be exploited for diagnostic purposes. The most enduring enigma is represented by the polarization signals observed in the D{sub 1} resonance lines of Na I (5896 A) and Ba II (4934 A), which were expected to be intrinsically unpolarizable. The totality of sodium and 18% of barium have hyperfine structure (HFS), and it has been argued that the only way to produce a scattering polarization signal in such lines is through the presence of a substantial amount of atomic polarization in their lower HFS levels. The strong sensitivity of these long-lived levels to depolarizing mechanisms led to the paradoxical conclusion that the observed D{sub 1}-line polarization is incompatible with the presence in the lower solar chromosphere of inclined magnetic fields sensibly stronger than 0.01 G. Here we show that by properly taking into account the fact that the solar D{sub 1}-line radiation has a non-negligible spectral structure over the short frequency interval spanned by the HFS transitions, it is possible to produce scattering polarization signals in the D{sub 1} lines of Na I and Ba II without the need of ground-level polarization. The resulting linear polarization is not so easily destroyed by elastic collisions and/or magnetic fields.

  4. Measurement of the polarization for antiproton--proton annihilation into charged π and K pairs between 1.0 and 2.2 GeV/c

    International Nuclear Information System (INIS)

    Carter, A.A.; Coupland, M.; Eisenhandler, E.

    1976-01-01

    The polarization parameter for the interactions anti pp → π - π + and anti pp → K - K + was measured over essentially the full angular range at 11 momenta between 1.0 and 2.2 GeV/c. A proton target polarized perpendicular to the scattering plane was used. The experiment measured the angles and momenta of both outgoing particles using wire spark chambers and the field of the polarized target magnet. Between 1000 and 5300 π - π + events, and 140 and 1300 K - K + events, were measured at each momentum. As a check, one obtained differential cross sections for anti pp → π - π + which are in excellent agreement with previous results. The polarizations for both channels are very large and positive over much of the angular range. Preliminary results of a fit to the cross sections and asymmetries for anti pp → π - π + show strong evidence for three new resonances at 2.14, 2.36, and 2.40 GeV/c 2

  5. Combustion Characteristics of C5 Alcohols and a Skeletal Mechanism for Homogeneous Charge Compression Ignition Combustion Simulation

    KAUST Repository

    Park, Sungwoo

    2015-10-27

    C5 alcohols are considered alternative fuels because they emit less greenhouse gases and fewer harmful pollutants. In this study, the combustion characteristics of 2-methylbutanol (2-methyl-1-butanol) and isopentanol (3-methyl-1-butanol) and their mixtures with primary reference fuels (PRFs) were studied using a detailed chemical kinetic model obtained from merging previously published mechanisms. Ignition delay times of the C5 alcohol/air mixtures were compared to PRFs at 20 and 40 atm. Reaction path analyses were conducted at intermediate and high temperatures to identify the most influential reactions controlling ignition of C5 alcohols. The direct relation graph with expert knowledge methodology was used to eliminate unimportant species and reactions in the detailed mechanism, and the resulting skeletal mechanism was tested at various homogeneous charge compression ignition (HCCI) engine combustion conditions. These simulations were used to investigate the heat release characteristics of the methyl-substituted C5 alcohols, and the results show relatively strong reactions at intermediate temperatures prior to hot ignition. C5 alcohol blending in PRF75 in HCCI combustion leads to a significant decrease of low-temperature heat release (LTHR) and a delay of the main combustion. The heat release features demonstrated by C5 alcohols can be used to improve the design and operation of advanced engine technologies.

  6. YAP and TAZ in epithelial stem cells: A sensor for cell polarity, mechanical forces and tissue damage.

    Science.gov (United States)

    Elbediwy, Ahmed; Vincent-Mistiaen, Zoé I; Thompson, Barry J

    2016-07-01

    The YAP/TAZ family of transcriptional co-activators drives cell proliferation in epithelial tissues and cancers. Yet, how YAP and TAZ are physiologically regulated remains unclear. Here we review recent reports that YAP and TAZ act primarily as sensors of epithelial cell polarity, being inhibited when cells differentiate an apical membrane domain, and being activated when cells contact the extracellular matrix via their basal membrane domain. Apical signalling occurs via the canonical Crumbs/CRB-Hippo/MST-Warts/LATS kinase cascade to phosphorylate and inhibit YAP/TAZ. Basal signalling occurs via Integrins and Src family kinases to phosphorylate and activate YAP/TAZ. Thus, YAP/TAZ is localised to the nucleus in basal stem/progenitor cells and cytoplasm in differentiated squamous cells or columnar cells. In addition, other signals such as mechanical forces, tissue damage and possibly receptor tyrosine kinases (RTKs) can influence MST-LATS or Src family kinase activity to modulate YAP/TAZ activity. © 2016 The Authors BioEssays Published by WILEY Periodicals, Inc.

  7. Polarization Optics

    OpenAIRE

    Fressengeas, Nicolas

    2010-01-01

    The physics of polarization optics *Polarized light propagation *Partially polarized light; DEA; After a brief introduction to polarization optics, this lecture reviews the basic formalisms for dealing with it: Jones Calculus for totally polarized light and Stokes parameters associated to Mueller Calculus for partially polarized light.

  8. Spin polarized electron tunneling and magnetoresistance in molecular junctions.

    Science.gov (United States)

    Szulczewski, Greg

    2012-01-01

    This chapter reviews tunneling of spin-polarized electrons through molecules positioned between ferromagnetic electrodes, which gives rise to tunneling magnetoresistance. Such measurements yield important insight into the factors governing spin-polarized electron injection into organic semiconductors, thereby offering the possibility to manipulate the quantum-mechanical spin degrees of freedom for charge carriers in optical/electrical devices. In the first section of the chapter a brief description of the Jullière model of spin-dependent electron tunneling is reviewed. Next, a brief description of device fabrication and characterization is presented. The bulk of the review highlights experimental studies on spin-polarized electron tunneling and magnetoresistance in molecular junctions. In addition, some experiments describing spin-polarized scanning tunneling microscopy/spectroscopy on single molecules are mentioned. Finally, some general conclusions and prospectus on the impact of spin-polarized tunneling in molecular junctions are offered.

  9. Flaw preparations for HSST program vessel fracture mechanics testing: mechanical-cyclic pumping and electron-beam weld-hydrogen-charge cracking schemes

    International Nuclear Information System (INIS)

    Holz, P.P.

    1980-06-01

    The purpose of the document is to present schemes for flaw preparations in heavy section steel. The ability of investigators to grow representative sharp cracks of known size, location, and orientation is basic to representative field testing to determine data for potential flaw propagation, fracture behavior, and margin against fracture for high-pressure-, high-temperature-service steel vessels subjected to increasing pressurization and/or thermal shock. Gaging for analytical stress and strain procedures and ultrasonic and acoustic emission instrumentation can then be applied to monitor the vessel during testing and to study crack growth. This report presents flaw preparations for HSST fracture mechanics testing. Cracks were grown by two techniques: (1) a mechanical method wherein a premachined notch was sharpened by pressurization and (2) a method combining electron-beam welds and hydrogen charging to crack the chill zone of a rapidly placed autogenous weld. The mechanical method produces a naturally occurring growth shape controlled primarily by the shape of the machined notch; the welding-electrochemical method produces flaws of uniform depth from the surface of a wall or machined notch. Theories, details, discussions, and procedures are covered for both of the flaw-growing schemes

  10. Precision measurement of the cross section of charged-current and neutral current processes at large Q{sup 2} at HERA with the polarized-electron beam; Mesures de precision de la section efficace des processus courant charge et courant neutre a grand Q{sup 2} a HERA avec le faisceau d'electrons polarises

    Energy Technology Data Exchange (ETDEWEB)

    Tran, Trong Hieu

    2011-04-15

    The inclusive cross sections for both charged and neutral current processes have been measured in interactions of longitudinally polarized electrons (positrons) with unpolarized protons using the full data samples collected by H1 at HERA-II. The data taken at a center-of-mass energy of 319 GeV correspond to an integrated luminosity of 149.1 pb{sup -1} and 180.0 pb{sup -1} for e{sup -}p and e{sup +}p collisions, representing an increase in statistics of a factor of 10 and 2, respectively, over the data from HERA-I. The measured double differential cross sections d{sup 2}{sigma}/dxdQ{sup 2} cover more than two orders of magnitude in both Q{sup 2}, the negative four-momentum transfer squared, up to 30000 GeV{sup 2}, and Bjorken x, down to 0.003. The cross section data are compared to predictions of the Standard Model which is able to provide a good description of the data. The polarization asymmetry as a function of Q{sup 2} is measured with improved precision, confirming the previous observation of P violation effect in neutral current ep scattering at distances down to 10{sup -18} m. The total cross sections of the charged current process, for Q{sup 2} > 400 GeV{sup 2} and inelasticity y < 0.9 are measured for 4 independent data samples with e{sup {+-}} beams and different polarization values. Together with the corresponding cross section obtained from the previously published unpolarized data, the polarization dependence of the charged current cross section is measured and found to be in agreement with the Standard Model prediction with the absence of right-handed charged current. The cross sections are combined with previously published data from H1 to obtain the most precise unpolarized measurements. These are used to extract the structure function xF{sub 3}{sup {gamma}}{sup Z} which is sensitive to the valence quark distributions down to low x values. The new cross sections have also been used in a combined electroweak and QCD fit to significantly improve the

  11. Mechanism of ({sup 14}N, {sup 12}B) reactions at intermediate energy leading to large spin-polarization of {sup 12}B

    Energy Technology Data Exchange (ETDEWEB)

    Mitsuoka, Shin-ichi [Osaka Univ., Ibaraki (Japan). Research Center for Nuclear Physics; Shimoda, Tadashi; Miyatake, Hiroari [and others

    1996-05-01

    To study mechanisms of the ({sup 14}N, {sup 12}B) reactions at intermediate energies, double differential cross section and nuclear spin-polarization of the {sup 12}B projectile-like fragments have been measured as a function of longitudinal momentum in the angular range of 0deg - 9deg. Large spin-polarization of the reaction products {sup 12}B has been observed in the {sup 9}Be({sup 14}N, {sup 12}B) reaction at 39.3 MeV/u. The momentum distributions at forward angles exhibit characteristic features which can not be understood by the current projectile fragmentation picture. It is shown that by assuming the existence of direct two-proton transfer process in addition to the fragmentation process, both the cross section and polarization of {sup 12}B fragments are successfully explained. The target and incident energy dependence of the momentum distribution are also explained reasonably. (author)

  12. Isotope effects on product polarization and reaction mechanism in the Li + HF(v = 0, j = 0) → LiF + H reaction

    Science.gov (United States)

    Yue, Xian-Fang; Wang, Mei-Shan

    2012-09-01

    Isotope effects on product polarization and reaction mechanism in the title reaction and its isotopic variants are investigated by employing the quasiclassical trajectory method. At a collision energy of 363 meV, the calculated differential cross sections display a strongly forward scattering in the Li + HF(v = 0, j = 0) → LiF + H reaction, but both the forward and sideways scatterings in the Li + DF(v = 0, j = 0) → LiF + D and Li + TF(v = 0, j = 0) → LiF + T reactions. Analysis of trajectories propagation along the time reveals that the Li + HF and Li + DF reactions proceed predominantly by the direct reaction mechanism. This is consistent with the experimental results of Becker et al. however, the Li + TF reaction undergoes both the direct and indirect reaction mechanisms. The product polarization shows a monotonically decreasing behavior with increasing the mass of the hydrogen isotopes.

  13. Simulation studies of nucleation of ferroelectric polarization reversal.

    Energy Technology Data Exchange (ETDEWEB)

    Brennecka, Geoffrey L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Winchester, Benjamin Michael [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-08-01

    Electric field-induced reversal of spontaneous polarization is the defining characteristic of a ferroelectric material, but the process(es) and mechanism(s) associated with the initial nucleation of reverse-polarity domains are poorly understood. This report describes studies carried out using phase field modeling of LiTaO3, a relatively simple prototype ferroelectric material, in order to explore the effects of either mechanical deformation or optically-induced free charges on nucleation and resulting domain configuration during field-induced polarization reversal. Conditions were selected to approximate as closely as feasible those of accompanying experimental work in order to provide not only support for the experimental work but also ensure that additional experimental validation of the simulations could be carried out in the future. Phase field simulations strongly support surface mechanical damage/deformation as effective for dramatically reducing the overall coercive field (Ec) via local field enhancements. Further, optically-nucleated polarization reversal appears to occur via stabilization of latent nuclei via the charge screening effects of free charges.

  14. H- ion current from a polarized vapor target

    International Nuclear Information System (INIS)

    Cornelius, W.D.

    1984-01-01

    A method of determining the polarization transferred to hydrogen atoms in charge-exchange reactions is outlined. The method also provides a means of determining target polarizations once the polarization transfer function is known

  15. The effects of localized tail states on charge transport mechanisms in amorphous zinc tin oxide Schottky diodes

    Science.gov (United States)

    Son, Youngbae; Peterson, Rebecca L.

    2017-12-01

    Temperature-dependent current–voltage measurements were performed on vertical Schottky diodes made with solution-processed amorphous zinc tin oxide (a-ZTO) semiconductor and palladium rectifying contacts. Above 260 K, forward bias electron transport occurs via thermionic emission over an inhomogeneous, voltage-dependent Schottky barrier with {\\bar{φ }}b0 = 0.72 eV, σ 0 = 0.12 eV, and A* = 44 A cm‑2 K‑2, where {\\bar{φ }}b0 and {σ }0 are the mean potential barrier and its standard deviation at zero bias, respectively, and A* is Richardson’s constant. For large currents, the series ohmic resistance of the bulk semiconductor dominates. At temperatures below 260 K, less carriers are excited from localized states below the conduction band edge, and space-charge-limited current (SCLC) dominates. The exponential tail density of states parameters extracted for a-ZTO are g tc = 1.34 × 1019 cm‑3 eV‑1 and kT t = 26 meV. The intermediate tail state density in a-ZTO, less than that of amorphous silicon and greater than that of amorphous indium gallium zinc oxide, allows for experimental observation of a temperature-dependent transition of bulk charge transport mechanisms in strong forward bias from semiconductor-like ohmic conduction near room temperature to insulator-like SCLC at lower temperatures. In reverse bias, the same tail states lead to modified Poole–Frenkel emission, reducing the leakage current. The frequency response of a half-wave rectifier and diode impedance spectroscopy confirm that the Schottky diode cut-off frequency is above 1 MHz.

  16. Noble gases solubility models of hydrocarbon charge mechanism in the Sleipner Vest gas field

    Science.gov (United States)

    Barry, P. H.; Lawson, M.; Meurer, W. P.; Warr, O.; Mabry, J. C.; Byrne, D. J.; Ballentine, C. J.

    2016-12-01

    Noble gases are chemically inert and variably soluble in crustal fluids. They are primarily introduced into hydrocarbon reservoirs through exchange with formation waters, and can be used to assess migration pathways and mechanisms, as well as reservoir storage conditions. Of particular interest is the role groundwater plays in hydrocarbon transport, which is reflected in hydrocarbon-water volume ratios. Here, we present compositional, stable isotope and noble gas isotope and abundance data from the Sleipner Vest field, in the Norwegian North Sea. Sleipner Vest gases are generated from primary cracking of kerogen and the thermal cracking of oil. Gas was emplaced into the Sleipner Vest from the south and subsequently migrated to the east, filling and spilling into the Sleipner Ost fields. Gases principally consist of hydrocarbons (83-93%), CO2 (5.4-15.3%) and N2 (0.6-0.9%), as well as trace concentrations of noble gases. Helium isotopes (3He/4He) are predominantly radiogenic and range from 0.065 to 0.116 RA; reported relative to air (RA = 1.4 × 10-6; Clarke et al., 1976; Sano et al., 1988), showing predominantly (>98%) crustal contributions, consistent with Ne (20Ne/22Ne from 9.70 to 9.91; 21Ne/22Ne from 0.0290 to 0.0344) and Ar isotopes (40Ar/36Ar from 315 to 489). Air-derived noble gas isotopes (20Ne, 36Ar, 84Kr, 132Xe) are introduced into the hydrocarbon system by direct exchange with air-saturated water (ASW). The distribution of air-derived noble gas species are controlled by phase partitioning processes; in that they preferentially partition into the gas (i.e., methane) phase, due to their low solubilities in fluids. Therefore, the extent of exchange between hydrocarbon phases and formation waters - that have previously equilibrated with the atmosphere - can be determined by investigating air-derived noble gas species. We utilize both elemental ratios to address process (i.e., open vs. closed system) and concentrations to quantify the extent of hydrocarbon

  17. Comparison of rheological, mechanical, electrical properties of HDPE filled with BaTiO{sub 3} with different polar surface tension

    Energy Technology Data Exchange (ETDEWEB)

    Su, Jun [Department of Polymer Science and Engineering, College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China); College of Mechanics Engineering, Nanjing Institute of Industry Technology, Nanjing, 210023 (China); Zhang, Jun, E-mail: zhangjun@njtech.edu.cn [Department of Polymer Science and Engineering, College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China)

    2016-12-01

    Graphical abstract: - Highlights: • The non-polar and short vinyl groups can greatly reduce G′ of HDPE composites. • Long chains on BaTiO{sub 3} surface enhance the interaction of BaTiO{sub 3} with HDPE. • Polar amino groups on BaTiO{sub 3} surface raise the interaction of BaTiO{sub 3} with HDPE. • Polar amino groups can boost the dielectric constant of HDPE composites. • The potential use in electronic equipment of the KH550 composites is obtained. - Abstract: In this work, three types of coupling agents: isopropyl trioleic titanate (NDZ105), vinyltriethoxysilane (SG-Si151), 3-aminopropyltriethoxysilane (KH550) were applied to modify the surface tension of Barium titanate (BaTiO{sub 3}) particles. The Fourier transform infrared (FT-IR) spectra confirm the chemical adherence of coupling agents to the particle surface. The long hydrocarbon chains in NDZ105 can cover the particle surface and reduce the polar surface tension of BaTiO{sub 3} from 37.53 mJ/m{sup 2} to 7.51 mJ/m{sup 2}, turning it from hydrophilic to oleophilic properties. The short and non-polar vinyl groups in SG-Si151 does not influence the surface tension of BaTiO{sub 3}, but make BaTiO{sub 3} have both hydrophilic and oleophilic properties. The polar amino in KH550 can keep BaTiO{sub 3} still with hydrophilic properties. It is found that SG-Si151 modified BaTiO{sub 3} has the lowest interaction with HDPE matrix, lowering the storage modulus of HDPE composites to the greatest extent. As for mechanical properties, the polar amino groups in KH550 on BaTiO{sub 3} surface can improve the adhesion of BaTiO{sub 3} with HDPE matrix, which increases the elongation at break of HDPE composites to the greatest extent. In terms of electrical properties, the polar amino groups on surface of BaTiO{sub 3} can boost the dielectric properties of HDPE/BaTiO{sub 3} composites and decrease the volume resistivity of HDPE/BaTiO{sub 3} composites. The aim of this study is to investigate how functional groups

  18. A new strategy for earthquake focal mechanisms using waveform-correlation-derived relative polarities and cluster analysis: Application to the 2014 Long Valley Caldera earthquake swarm

    Science.gov (United States)

    Shelly, David R.; Hardebeck, Jeanne L.; Ellsworth, William L.; Hill, David P.

    2016-01-01

    In microseismicity analyses, reliable focal mechanisms can typically be obtained for only a small subset of located events. We address this limitation here, presenting a framework for determining robust focal mechanisms for entire populations of very small events. To achieve this, we resolve relative P and S wave polarities between pairs of waveforms by using their signed correlation coefficients—a by-product of previously performed precise earthquake relocation. We then use cluster analysis to group events with similar patterns of polarities across the network. Finally, we apply a standard mechanism inversion to the grouped data, using either catalog or correlation-derived P wave polarity data sets. This approach has great potential for enhancing analyses of spatially concentrated microseismicity such as earthquake swarms, mainshock-aftershock sequences, and industrial reservoir stimulation or injection-induced seismic sequences. To demonstrate its utility, we apply this technique to the 2014 Long Valley Caldera earthquake swarm. In our analysis, 85% of the events (7212 out of 8494 located by Shelly et al. [2016]) fall within five well-constrained mechanism clusters, more than 12 times the number with network-determined mechanisms. Of the earthquakes we characterize, 3023 (42%) have magnitudes smaller than 0.0. We find that mechanism variations are strongly associated with corresponding hypocentral structure, yet mechanism heterogeneity also occurs where it cannot be resolved by hypocentral patterns, often confined to small-magnitude events. Small (5–20°) rotations between mechanism orientations and earthquake location trends persist when we apply 3-D velocity models and might reflect a geometry of en echelon, interlinked shear, and dilational faulting.

  19. No evidence for orbital loop currents in charge-ordered YBa2Cu3O6 +x from polarized neutron diffraction

    Science.gov (United States)

    Croft, T. P.; Blackburn, E.; Kulda, J.; Liang, Ruixing; Bonn, D. A.; Hardy, W. N.; Hayden, S. M.

    2017-12-01

    It has been proposed that the pseudogap state of underdoped cuprate superconductors may be due to a transition to a phase which has circulating currents within each unit cell. Here, we use polarized neutron diffraction to search for the corresponding orbital moments in two samples of underdoped YBa2Cu3O6 +x with doping levels p =0.104 and 0.123. In contrast to some other reports using polarized neutrons, but in agreement with nuclear magnetic resonance and muon spin rotation measurements, we find no evidence for the appearance of magnetic order below 300 K. Thus, our experiment suggests that such order is not an intrinsic property of high-quality cuprate superconductor single crystals. Our results provide an upper bound for a possible orbital loop moment which depends on the pattern of currents within the unit cell. For example, for the CC-θI I pattern proposed by Varma, we find that the ordered moment per current loop is less than 0.013 μB for p =0.104 .

  20. Motion model for a charged particle in a plasma during the interaction of an electromagnetic pulse elliptically polarized propagating in the direction of a static and homogeneous magnetic field

    International Nuclear Information System (INIS)

    Gomez R, F.; Ondarza R, R.

    2004-01-01

    An analytic model is presented for the description of the motion of a charged particle in the interaction of an elliptically electromagnetic pulse polarized propagating along a static and homogeneous external magnetic field in a plasma starting from the force equation. The method allows to express the solution in terms of the invariant phase, obtaining differential equations for the trajectory of the accelerated particle by means of an electromagnetic pulse of arbitrary and modulated width by an encircling Gaussian. The numerical solutions reported in this work can find varied applications, for example in the physics of the interaction laser-plasma, in the acceleration of particles, in hot plasma and in radioactive effects. (Author)

  1. Model of the motion of a charged particle into a plasma during the interaction of an electromagnetic pulse elliptically polarized propagating in the direction of a static and homogeneous magnetic field

    International Nuclear Information System (INIS)

    Gomez R, F.; Ondarza R, R.

    2004-01-01

    An analytical model for the description of the movement of a charged particle in the interaction of an electromagnetic pulse elliptically polarized propagating along of a static and homogeneous external magnetic field in a plasma starting from the force equation is presented. The method allows to express the solution in terms of the invariant phase, obtaining differential equations for the trajectory of the accelerated particle by means of an electromagnetic pulse of arbitrary amplitude and modulated by an encircling Gaussian. The numerical solutions reported in this work can find varied applications, for example in the physics of the interaction laser-plasma, in the acceleration of particles, in hot plasma and in radiative effects. (Author)

  2. Charge separation of dense two-dimensional electron-hole gases: mechanism for exciton ring pattern formation.

    Science.gov (United States)

    Rapaport, R; Chen, Gang; Snoke, D; Simon, Steven H; Pfeiffer, Loren; West, Ken; Liu, Y; Denev, S

    2004-03-19

    We report on new experiments and theory that unambiguously resolve the recent puzzling observation of large diameter exciton emission halos around a laser excitation spot in two dimensional systems. We find a novel separation of plasmas of opposite charge with emission from the sharp circular boundary between these two regions. This charge separation allows for cooling of initially hot optically generated carriers as they dwell in the charge reservoirs for very long times.

  3. Binding mechanisms of DNA/RNA nucleobases adsorbed on graphene under charging: first-principles van der Waals study

    Science.gov (United States)

    Gürel, Hikmet Hakan; Salmankurt, Bahadır

    2017-06-01

    Graphene is a 2D material that has attracted much attention due to its outstanding properties. Because of its high surface area and unique chemical and physical properties, graphene is a good candidate for biological applications. For this reason, a deep understanding of the mechanism of interaction of graphene with biomolecules is required. In this study, theoretical investigation of van der Waals effects has been conducted using density functional theory. Here we show that the order of the binding energies of five nucleobases with graphene is G  >  A  >  T  >  C  >   U. This trend is in good agreement with most of the theoretical and experimental data. Also, the effects of charging on the electronic and structural properties of the graphene-nucleubase systems are studied for the first time. We show that the binding energy can be changed by adding or removing an electron from the system. The results presented in this work provide fundamental insights into the quantum interactions of DNA with carbon-based nanostructures and will be useful for developments in biotechnology and nanotechnology.

  4. The effect of fixed charge density and cartilage swelling on mechanics of knee joint cartilage during simulated gait.

    Science.gov (United States)

    Räsänen, Lasse P; Tanska, Petri; Zbýň, Štefan; van Donkelaar, Corrinus C; Trattnig, Siegfried; Nieminen, Miika T; Korhonen, Rami K

    2017-08-16

    The effect of swelling of articular cartilage, caused by the fixed charge density (FCD) of proteoglycans, has not been demonstrated on knee joint mechanics during simulated walking before. In this study, the influence of the depth-wise variation of FCD was investigated on the internal collagen fibril strains and the mechanical response of the knee joint cartilage during gait using finite element (FE) analysis. The FCD distribution of tibial cartilage was implemented from sodium ( 23 Na) MRI into a 3-D FE-model of the knee joint ("Healthy model"). For comparison, models with decreased FCD values were created according to the decrease in FCD associated with the progression of osteoarthritis (OA) ("Early OA" and "Advanced OA" models). In addition, a model without FCD was created ("No FCD" model). The effect of FCD was studied with five different collagen fibril network moduli of cartilage. Using the reference fibril network moduli, the decrease in FCD from "Healthy model" to "Early OA" and "Advanced OA" models resulted in increased axial strains (by +2 and +6%) and decreased fibril strains (by -3 and -13%) throughout the stance, respectively, calculated as mean values through cartilage depth in the tibiofemoral contact regions. Correspondingly, compared to the "Healthy model", the removal of the FCD altogether in "NoFCD model" resulted in increased mean axial strains by +16% and decreased mean fibril strains by -24%. This effect was amplified as the fibril network moduli were decreased by 80% from the reference. Then mean axial strains increased by +6, +19 and +49% and mean fibril strains decreased by -9, -20 and -32%, respectively. Our results suggest that the FCD in articular cartilage has influence on cartilage responses in the knee during walking. Furthermore, the FCD is suggested to have larger impact on cartilage function as the collagen network degenerates e.g. in OA. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Mechanisms of charge transport and resistive switching in composite films of semiconducting polymers with nanoparticles of graphene and graphene oxide

    Science.gov (United States)

    Berestennikov, A. S.; Aleshin, A. N.

    2017-11-01

    We have investigated the effect of the resistive switching in the composite films based on polyfunctional polymers - PVK, PFD and PVC mixed with particles of Gr and GO with the concentration of ˜ 1 - 3 wt.%. We have developed the solution processed hybrid memory structures based on PVK and GO particles composite films. The effect of the resistive switching in Al/PVK(PFD; PVC):Gr(GO)/ITO/PET structures manifests itself as a sharp change of the electrical resistance from a low-conducting state to a relatively high-conducting state when applying a bias to Al-ITO electrodes of ˜ 0.2-0.4 V. It has been established that a sharp conductivity jump characterized by S-shaped current-voltage curves and the presence of their hysteresis occurs upon applying a voltage pulse to the Au/PVK(PFD; PVC):Gr(GO)/ITO/PET structures, with the switching time in the range from 1 to 30 μs. The mechanism of resistive switching associated with the processes of capture and accumulation of charge carriers by Gr(GO) particles introduced into the matrixes of the PVK polymer due to the reduction/oxidation processes. The possible mechanisms of energy transfer between organic and inorganic components in PVK(PFD; PVC):GO(Gr) films causes increase mobility are discussed. Incorporating of Gr (GO) particles into the polymer matrix is a promising route to enhance the performance of hybrid memory structures, as well as it is an effective medium for memory cells.

  6. Continuum treatment of electronic polarization effect.

    Science.gov (United States)

    Tan, Yu-Hong; Luo, Ray

    2007-03-07

    A continuum treatment of electronic polarization has been explored for in molecular mechanics simulations in implicit solvents. The dielectric constant for molecule interior is the only parameter in the continuum polarizable model. A value of 4 is found to yield optimal agreement with high-level ab initio quantum mechanical calculations for the tested molecular systems. Interestingly, its performance is not sensitive to the definition of molecular volume, in which the continuum electronic polarization is defined. In this model, quantum mechanical electrostatic field in different dielectric environments from vacuum, low-dielectric organic solvent, and water can be used simultaneously in atomic charge fitting to achieve consistent treatment of electrostatic interactions. The tests show that a single set of atomic charges can be used consistently in different dielectric environments and different molecular conformations, and the atomic charges transfer well from training monomers to tested dimers. The preliminary study gives us the hope of developing a continuum polarizable force field for more consistent simulations of proteins and nucleic acids in implicit solvents.

  7. Continuum treatment of electronic polarization effect

    Science.gov (United States)

    Tan, Yu-Hong; Luo, Ray

    2007-03-01

    A continuum treatment of electronic polarization has been explored for in molecular mechanics simulations in implicit solvents. The dielectric constant for molecule interior is the only parameter in the continuum polarizable model. A value of 4 is found to yield optimal agreement with high-level ab initio quantum mechanical calculations for the tested molecular systems. Interestingly, its performance is not sensitive to the definition of molecular volume, in which the continuum electronic polarization is defined. In this model, quantum mechanical electrostatic field in different dielectric environments from vacuum, low-dielectric organic solvent, and water can be used simultaneously in atomic charge fitting to achieve consistent treatment of electrostatic interactions. The tests show that a single set of atomic charges can be used consistently in different dielectric environments and different molecular conformations, and the atomic charges transfer well from training monomers to tested dimers. The preliminary study gives us the hope of developing a continuum polarizable force field for more consistent simulations of proteins and nucleic acids in implicit solvents.

  8. Charge-transfer complexes of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone with amino molecules in polar solvents.

    Science.gov (United States)

    Berto, Silvia; Chiavazza, Enrico; Ribotta, Valentina; Daniele, Pier Giuseppe; Barolo, Claudia; Giacomino, Agnese; Vione, Davide; Malandrino, Mery

    2015-01-01

    The charge-transfer complexes have scientific relevance because this type of molecular interaction is at the basis of the activity of pharmacological compounds and because the absorption bands of the complexes can be used for the quantification of electron donor molecules. This work aims to assess the stability of the charge-transfer complexes between the electron acceptor 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and two drugs, procaine and atenolol, in acetonitrile and ethanol. The stability of DDQ in solution and the time required to obtain the maximum complex formation were evaluated. The stoichiometry and the stability of the complexes were determined, respectively, by Job's plot method and by the elaboration of UV-vis titrations data. The latter task was carried out by using the non-linear global analysis approach to determine the equilibrium constants. This approach to data elaboration allowed us to overcome the disadvantages of the classical linear-regression method, to obtain reliable values of the association constants and to calculate the entire spectra of the complexes. NMR spectra were recorded to identify the portion of the donor molecule that was involved in the interaction. The data support the participation of the aliphatic amino groups in complex formation and exclude the involvement of the aromatic amine present in the procaine molecule. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Polarized electron beams elastically scattered by atoms as a tool for testing fundamental predictions of quantum mechanics.

    Science.gov (United States)

    Dapor, Maurizio

    2018-03-29

    Quantum information theory deals with quantum noise in order to protect physical quantum bits (qubits) from its effects. A single electron is an emblematic example of a qubit, and today it is possible to experimentally produce polarized ensembles of electrons. In this paper, the theory of the polarization of electron beams elastically scattered by atoms is briefly summarized. Then the POLARe program suite, a set of computer programs aimed at the calculation of the spin-polarization parameters of electron beams elastically interacting with atomic targets, is described. Selected results of the program concerning Ar, Kr, and Xe atoms are presented together with the comparison with experimental data about the Sherman function for low kinetic energy of the incident electrons (1.5eV-350eV). It is demonstrated that the quantum-relativistic theory of the polarization of electron beams elastically scattered by atoms is in good agreement with experimental data down to energies smaller than a few eV.

  10. Charge Storage, Conductivity and Charge Profiles of Insulators As Related to Spacecraft Charging

    OpenAIRE

    Dennison, JR; Frederickson, A. R.; Swaminathan, Prasanna

    2003-01-01

    Dissipation of charges built up near the surface of insulators due to space environment interaction is central to understanding spacecraft charging. Conductivity of insulating materials is key to determine how accumulated charge will distribute across the spacecraft and how rapidly charge imbalance will dissipate. To understand these processes requires knowledge of how charge is deposited within the insulator, the mechanisms for charge trapping and charge transport within the insulator, and h...

  11. Modulation of UK lightning by heliospheric magnetic field polarity

    Science.gov (United States)

    Owens, M. J.; Scott, C. J.; Lockwood, M.; Barnard, L.; Harrison, R. G.; Nicoll, K.; Watt, C.; Bennett, A. J.

    2014-11-01

    Observational studies have reported solar magnetic modulation of terrestrial lightning on a range of time scales, from days to decades. The proposed mechanism is two-step: lightning rates vary with galactic cosmic ray (GCR) flux incident on Earth, either via changes in atmospheric conductivity and/or direct triggering of lightning. GCR flux is, in turn, primarily controlled by the heliospheric magnetic field (HMF) intensity. Consequently, global changes in lightning rates are expected. This study instead considers HMF polarity, which doesn't greatly affect total GCR flux. Opposing HMF polarities are, however, associated with a 40-60% difference in observed UK lightning and thunder rates. As HMF polarity skews the terrestrial magnetosphere from its nominal position, this perturbs local ionospheric potential at high latitudes and local exposure to energetic charged particles from the magnetosphere. We speculate as to the mechanism(s) by which this may, in turn, redistribute the global location and/or intensity of thunderstorm activity.

  12. Polarization of a stored electron beam

    Energy Technology Data Exchange (ETDEWEB)

    Chao, A.W.

    1981-07-01

    Synchrotron radiation by a point charge is a familiar subject in classical electrodynamics. Perhaps less familiar are some quantum mechanical corrections to the classical results. Some of those quantum aspects of synchrotron radiation are described. One of the quantum effects leads to the expectation that electrons in a storage ring will polarize themselves to 92% - a surprisingly high value. A semi-classical derivation of the quantum effects is given. An effort has been made to minimize the need of using quantum mechanics. Results are put together to derive a final expression of beam polarization. Conditions under which the expected 92% polarization is destroyed are found and attributed to depolarization resonances. The various depolarization mechanisms are first illustrated by an idealized example and then systematically treated by a matrix formalism. It is shown that the strength of depolarization is specified by a key quantity called the spin chromaticity. Finally as an application of the obtained results, an estimate of the achievable level of beam polarization for two existing electron storage rings, SPEAR and PEP, is given.

  13. On the molecular mechanism of surface charge amplification and related phenomena at aqueous polyelectrolyte-graphene interfaces

    Directory of Open Access Journals (Sweden)

    J.M. Simonson

    2011-09-01

    Full Text Available In this communication we illustrate the occurrence of a recently reported new phenomenon of surface-charge amplification, SCA, (originally dubbed overcharging, OC, [Jimenez-Angeles F. and Lozada-Cassou M., J. Phys. Chem. B, 2004, 108, 7286] by means of molecular dynamics simulation of aqueous electrolytes solutions involving multivalent cations in contact with charged graphene walls and the presence of short-chain lithium polystyrene sulfonates where the solvent water is described explicitly with a realistic molecular model. We show that the occurrence of SCA in these systems, in contrast to that observed in primitive models, involves neither contact co-adsorption of the negatively charged macroions nor divalent cations with a large size and charge asymmetry as required in the case of implicit solvents. In fact the SCA phenomenon hinges around the preferential adsorption of water (over the hydrated ions with an average dipolar orientation such that the charges of the water's hydrogen and oxygen sites induce magnification rather than screening of the positive-charged graphene surface, within a limited range of surface-charge density.

  14. Nonlinear screening of charge impurities in graphene

    OpenAIRE

    Katsnelson, M. I.

    2006-01-01

    It is shown that a ``vacuum polarization'' induced by Coulomb potential in graphene leads to a strong suppression of electric charges even for undoped case (no charge carriers). A standard linear response theory is therefore not applicable to describe the screening of charge impurities in graphene. In particular, it overestimates essentially the contributions of charge impurities into the resistivity of graphene.

  15. On measurement of top polarization as a probe of $t \\bar t$ production mechanisms at the LHC

    CERN Document Server

    Godbole, Rohini M; Rindani, Saurabh D; Singh, Ritesh K

    2010-01-01

    In this note we demonstrate the use of top polarization in the study of $t \\bar t$ resonances at the LHC, in the possible case where the dynamics implies a non-zero top polarization. As a probe of top polarization we construct an asymmetry in the decay-lepton azimuthal angle distribution (corresponding to the sign of $\\cos\\phi_\\ell$) in the laboratory. The asymmetry is non-vanishing even for a symmetric collider like the LHC, where a positive $z$ axis is not uniquely defined. The angular distribution of the leptons has the advantage of being a faithful top-spin analyzer, unaffected by possible anomalous $tbW$ couplings, to linear order. We study, for purposes of demonstration, the case of a $Z'$ as might exist in the little Higgs models. We identify kinematic cuts which ensure that our asymmetry reflects the polarization in sign and magnitude. We investigate possibilities at the LHC with two energy options: $\\sqrt{s} = 14$ TeV and $\\sqrt{s} = 7$ TeV, as well as at the Tevatron. At the LHC the model predicts n...

  16. Formation of oxide-trapped charges in 6H-SiC MOS structures

    Energy Technology Data Exchange (ETDEWEB)

    Yoshikawa, Masahito; Ohshima, Takeshi; Itoh, Hisayoshi; Nashiyama, Isamu [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment; Okumura, Hajime; Yoshida, Sadafumi

    1997-03-01

    The silicon and the carbon faces of hexagonal silicon carbide (6H-SiC) substrates were oxidized pyrogenically at 1100degC, and the metal-oxide-semiconductor structures were formed on these faces. The MOS capacitors developed using the silicon and the carbon faces were irradiated with {sup 60}Co gamma-rays under argon atmosphere at room temperature. The bias voltages with the different polarity were applied to the gate electrode during irradiation to examine the formation mechanisms of the trapped charges in the oxides of these MOS capacitors. The amount of the trapped charges in the oxide were obtained from capacitance pulse voltage characteristics. The generation of the trapped charges are affects with not only the absorbed dose but also the bias polarity applied to the gate electrodes during irradiation. The formation mechanisms of the trapped charges in the oxides were estimated in conjunction with the surface orientation of 6H-SiC substrates. (author)

  17. Single-molecule tracking of small GTPase Rac1 uncovers spatial regulation of membrane translocation and mechanism for polarized signaling

    Science.gov (United States)

    Das, Sulagna; Yin, Taofei; Yang, Qingfen; Zhang, Jingqiao; Wu, Yi I.; Yu, Ji

    2015-01-01

    Polarized Rac1 signaling is a hallmark of many cellular functions, including cell adhesion, motility, and cell division. The two steps of Rac1 activation are its translocation to the plasma membrane and the exchange of nucleotide from GDP to GTP. It is, however, unclear whether these two processes are regulated independent of each other and what their respective roles are in polarization of Rac1 signaling. We designed a single-particle tracking (SPT) method to quantitatively analyze the kinetics of Rac1 membrane translocation in living cells. We found that the rate of Rac1 translocation was significantly elevated in protrusions during cell spreading on collagen. Furthermore, combining FRET sensor imaging with SPT measurements in the same cell, the recruitment of Rac1 was found to be polarized to an extent similar to that of the nucleotide exchange process. Statistical analysis of single-molecule trajectories and optogenetic manipulation of membrane lipids revealed that Rac1 membrane translocation precedes nucleotide exchange, and is governed primarily by interactions with phospholipids, particularly PI(3,4,5)P3, instead of protein factors. Overall, the study highlights the significance of membrane translocation in spatial Rac1 signaling, which is in addition to the traditional view focusing primarily on GEF distribution and exchange reaction. PMID:25561548

  18. Insight into electronic, mechanical and transport properties of quaternary CoVTiAl: Spin-polarized DFT + U approach

    Energy Technology Data Exchange (ETDEWEB)

    Yousuf, Saleem, E-mail: nengroosaleem17@gmail.com; Gupta, D.C., E-mail: sosfizix@gmail.com

    2017-07-15

    Highlights: • 100% spin-polarized material important for the application in spintronics. • It is ferromagnetic and ductile in nature. • Shows semiconducting behavior with a band gap of 1.06 eV. • Possibly efficient high temperature thermoelectric material. - Abstract: We present a preliminary investigation of band structure and thermoelectric properties of new quaternary CoVTiAl Heusler alloy. Structural, magnetic property and 100% spin polarization of equiatomic CoVTiAl predicts ferromagnetic stable ground state. Band profile outlines the indirect semiconducting behavior in spin down channel with band gap of 1.06 eV, and the magnetic moment of 3 µ{sub B} in accordance with Slater-Pauling rule. To evaluate the accuracy of different approximations in predicting thermoelectric properties, the comparison with available experimental data is made which shows fair agreement for the transport coefficients. The high temperature (800 K) positive Seebeck coefficient of 73.71 µV/K describes the p-type character of the material with high efficiency due to highly influential semiconducting behavior around the Fermi level. Considering the combination of 100% spin-polarization, high Seebeck coefficient and large figure of merit, ferromagnetic semiconducting CoVTiAl may prove as a potential candidate for high temperature thermoelectrics and an ideal spin source material for spintronic applications.

  19. Dynamical mechanism of charge separation by photoexcited generation of proton–electron pairs in organic molecular systems. A nonadiabatic electron wavepacket dynamics study

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, Kentaro, E-mail: kyamamoto@fukui.kyoto-u.ac.jp; Takatsuka, Kazuo, E-mail: kaztak@fukui.kyoto-u.ac.jp

    2016-08-22

    Graphical abstract: Asymptotic biradical state produced by the excited-state coupled proton–electron transfer (CPET), resulting in charge separation (proton–electron pair creation) on a proton–electron acceptor A, in a series of photochemical systems generally denoted as X–Mn–OH{sub 2}⋯A, where X = (OH, Ca(OH){sub 3}) and A = (N-methylformamidine, guanidine, imidazole, or ammonia clusters). - Abstract: In this perspective article, we review, along with presenting new results, a series of our theoretical analyses on the excited-state mechanism of charge separation (proton–electron pair creation) relevant to the photoinduced water-splitting reaction (2H{sub 2}O → 4H{sup +} + 4e{sup −} + O{sub 2}) in organic and biological systems, which quite often includes Mn clusters in various molecular configurations. The present mechanism is conceived to be universal in the triggering process of the photoexcited water splitting dynamics. In other words, any Mn-based catalytic charge separation is quite likely to be initiated according to this mechanism. As computationally tractable yet realistic models, we examine a series of systems generally expressed as X–Mn–OH{sub 2}⋯A, where X = (OH, Ca(OH){sub 3}) and A = (N-methylformamidine, guanidine, imidazole or ammonia cluster) in terms of the theory of nonadiabatic electron wavepacket dynamics. We first find both an electron and a proton are simultaneously transferred to the acceptors through conical intersections upon photoexcitation. In this mechanism, the electron takes different pathways from that of the proton and reaches the densely lying Rydberg-like states of the acceptors in the end, thereby inducing charge separation. Therefore the presence of the Rydberg-like diffused unoccupied states as an electron acceptor is critical for this reaction to proceed. We also have found another crucial nonadiabatic process that deteriorates the efficiency of charge separation by rendering the created pair of proton

  20. Charge mechanism analysis of lithium ion secondary battery. X-ray absorption spectroscopy and first-principles calculations

    International Nuclear Information System (INIS)

    Kubobuchi, Kei; Imai, Hideto

    2015-01-01

    Redox reaction behaviors of a lithium ion secondary battery were investigated by K-edge in-situ XANES and L-edge XANES measurements combined with ab initio XANES simulation. During the charge process, the shape of K-edge XANES spectra was found to change, suggesting contribution of Mn 3d electron to charge and discharge. The detailed analysis based on first-principles electronic structure calculation and ab initio XANES simulation, however, indicated that valence change of Mn is little and rather O largely contribute to the reaction. (author)

  1. Imaging with Polarized Neutrons

    Directory of Open Access Journals (Sweden)

    Nikolay Kardjilov

    2018-01-01

    Full Text Available Owing to their zero charge, neutrons are able to pass through thick layers of matter (typically several centimeters while being sensitive to magnetic fields due to their intrinsic magnetic moment. Therefore, in addition to the conventional attenuation contrast image, the magnetic field inside and around a sample can be visualized by detecting changes of polarization in a transmitted beam. The method is based on the spatially resolved measurement of the cumulative precession angles of a collimated, polarized, monochromatic neutron beam that traverses a magnetic field or sample.

  2. A one dimensional model study of the mechanism of halogen liberation and vertical transport in the polar troposphere

    Directory of Open Access Journals (Sweden)

    E. Lehrer

    2004-01-01

    Full Text Available Sudden depletions of tropospheric ozone during spring were reported from the Arctic and also from Antarctic coastal sites. Field studies showed that those depletion events are caused by reactive halogen species, especially bromine compounds. However the source and seasonal variation of reactive halogen species is still not completely understood. There are several indications that the halogen mobilisation from the sea ice surface of the polar oceans may be the most important source for the necessary halogens. Here we present a one dimensional model study aimed at determining the primary source of reactive halogens. The model includes gas phase and heterogeneous bromine and chlorine chemistry as well as vertical transport between the surface and the top of the boundary layer. The autocatalytic Br release by photochemical processes (bromine explosion and subsequent rapid bromine catalysed ozone depletion is well reproduced in the model and the major source of reactive bromine appears to be the sea ice surface. The sea salt aerosol alone is not sufficient to yield the high levels of reactive bromine in the gas phase necessary for fast ozone depletion. However, the aerosol efficiently 'recycles' less reactive bromine species (e.g. HBr and feeds them back into the ozone destruction cycle. Isolation of the boundary layer air from the free troposphere by a strong temperature inversion was found to be critical for boundary layer ozone depletion to happen. The combination of strong surface inversions and presence of sunlight occurs only during polar spring.

  3. Flexoelectric charge separation and size dependent piezoelectricity in dielectric solids

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Wenhui [Department of Physics, Shantou University, Shantou, Guangdong 515063 (China)

    2010-01-15

    Flexoelectric charge separation and the associated size dependent piezoelectricity are investigated in centrosymmetric dielectric solids. Direct piezoelectricity can exist as external mechanical stress is applied to non-piezoelectric dielectrics with shapes such as truncated pyramids, due to elastic strain gradient induced flexoelectric polarization. Effective piezoelectric coefficient is analyzed in truncated pyramids, which is strongly enhanced by size reduction and depends on flexoelectricity, elastic compliance, and aspect ratio of the non-piezoelectric dielectric solids. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  4. NEW HYPOTHESIS AND ELECTROPHYSICS NATURE OF ADDITIONAL MECHANISMS OF ORIGIN, ACCUMULATION AND DIVISION OF ELECTRIC CHARGES IN THE ATMOSPHERIC CLOUDS OF EARTH

    Directory of Open Access Journals (Sweden)

    M. I. Baranov

    2018-02-01

    Full Text Available Purpose. Development of new hypothesis about the possible additional mechanisms of origin, accumulation and division of electric charges in atmospheric clouds, containing shallow dispersible drops of water, shallow particulate dielectric matters and crystals of ice. Methodology. Electrophysics bases of technique of high voltage, theoretical bases of the electrical engineering, theoretical electrophysics, theory of the electromagnetic field, technique of the high electric and magnetic fields. Results. Pulled out and grounded new scientific supposition, related to possible existence in earthly troposphere of additional mechanisms of origin, accumulation and division of electric charges in the atmospheric clouds of Earth, being based on electrization in the warm ascending currents of air of shallow round particulate dielectric matters, getting in an air atmosphere from a terrene and from the smoke extras of industrial enterprises. By a calculation a way it is shown that the offered additional electrophysics mechanisms are able to provide achievement in the atmospheric clouds of such values of volume closeness of charges, total electric charge and tension of the electrostatic field stocked in them inwardly and on the external border of storm clouds which correspond modern experimental information from an area atmospheric electricity. The calculation estimations of levels of electric potential and stocked electric energy executed on the basis of the offered hypothesis in storm clouds specify on possibility of receipt in them of ever higher electric potentials and large supplies of electric energy. The obtained results are supplemented by the known approaches of forming and development in earthly troposphere of the electric charged atmospheric clouds, being based on electrization in the warm ascending streams of air the masses of shallow round aquatic drops. Originality. First on the basis of the well-known theses of technique and electrophysics of

  5. Charge orders in organic charge-transfer salts

    Science.gov (United States)

    Kaneko, Ryui; Tocchio, Luca F.; Valentí, Roser; Becca, Federico

    2017-10-01

    Motivated by recent experimental suggestions of charge-order-driven ferroelectricity in organic charge-transfer salts, such as κ-(BEDT-TTF)2Cu[N(CN)2]Cl, we investigate magnetic and charge-ordered phases that emerge in an extended two-orbital Hubbard model on the anisotropic triangular lattice at 3/4 filling. This model takes into account the presence of two organic BEDT-TTF molecules, which form a dimer on each site of the lattice, and includes short-range intramolecular and intermolecular interactions and hoppings. By using variational wave functions and quantum Monte Carlo techniques, we find two polar states with charge disproportionation inside the dimer, hinting to ferroelectricity. These charge-ordered insulating phases are stabilized in the strongly correlated limit and their actual charge pattern is determined by the relative strength of intradimer to interdimer couplings. Our results suggest that ferroelectricity is not driven by magnetism, since these polar phases can be stabilized also without antiferromagnetic order and provide a possible microscopic explanation of the experimental observations. In addition, a conventional dimer-Mott state (with uniform density and antiferromagnetic order) and a nonpolar charge-ordered state (with charge-rich and charge-poor dimers forming a checkerboard pattern) can be stabilized in the strong-coupling regime. Finally, when electron–electron interactions are weak, metallic states appear, with either uniform charge distribution or a peculiar 12-site periodicity that generates honeycomb-like charge order.

  6. A chemo-mechanical free-energy-based approach to model durotaxis and extracellular stiffness-dependent contraction and polarization of cells.

    Science.gov (United States)

    Shenoy, Vivek B; Wang, Hailong; Wang, Xiao

    2016-02-06

    We propose a chemo-mechanical model based on stress-dependent recruitment of myosin motors to describe how the contractility, polarization and strain in cells vary with the stiffness of their surroundings and their shape. A contractility tensor, which depends on the distribution of myosin motors, is introduced to describe the chemical free energy of the cell due to myosin recruitment. We explicitly include the contributions to the free energy that arise from mechanosensitive signalling pathways (such as the SFX, Rho-Rock and MLCK pathways) through chemo-mechanical coupling parameters. Taking the variations of the total free energy, which consists of the chemical and mechanical components, in accordance with the second law of thermodynamics provides equations for the temporal evolution of the active stress and the contractility tensor. Following this approach, we are able to recover the well-known Hill relation for active stresses, based on the fundamental principles of irreversible thermodynamics rather than phenomenology. We have numerically implemented our free energy-based approach to model spatial distribution of strain and contractility in (i) cells supported by flexible microposts, (ii) cells on two-dimensional substrates, and (iii) cells in three-dimensional matrices. We demonstrate how the polarization of the cells and the orientation of stress fibres can be deduced from the eigenvalues and eigenvectors of the contractility tensor. Our calculations suggest that the chemical free energy of the cell decreases with the stiffness of the extracellular environment as the cytoskeleton polarizes in response to stress-dependent recruitment of molecular motors. The mechanical energy, which includes the strain energy and motor potential energy, however, increases with stiffness, but the overall energy is lower for cells in stiffer environments. This provides a thermodynamic basis for durotaxis, whereby cells preferentially migrate towards stiffer regions of the

  7. Ionization and excitation of lithium atoms by fast charged particle impact: identification of mechanisms for double K-shell vacancy production as a function of the projectile charge and velocity

    International Nuclear Information System (INIS)

    Rangama, J.

    2002-11-01

    Ionization and excitation of lithium atoms by fast charged particle impact: identification of mechanisms for double K-shell vacancy production as a function of projectile charge and velocity. Auger electron spectroscopy is used for an experimental investigation of ionization and excitation of lithium atoms by ions (Kr34 + and Ar18 + ) and electrons at high impact velocities (from 6 to 60 a.u.). In particular, relative contributions of the mechanisms responsible for lithium K-shell ionization-excitation are determined for various projectile charges Zp and velocities vp. A large range of perturbation parameters |Zp|/vp is explored (|Zp|/vp = 0,05 - 0,7 a.u.). From single K-shell excitation results, it appears that the projectile-electron interaction gives mainly rise to a dipole-like transition 1s -> np Concerning K-shell ionization-excitation, the separation of the TS2 (two independent projectile-electron interactions) and TS1 (one projectile-electron interaction) mechanisms responsible for the formation of the 2snp 1,3P and 2sns 1,3S lithium states is performed. In TS1 process, the projectile-electron interaction can be followed by an electron-electron interaction (dielectronic process) or by an internal rearrangement of the residual target after a sudden potential change (shake process). From Born theory, ab initio calculations are performed. The good agreement between theoretical and experimental results confirms the mechanism identification. For the production of P states, TS1 is found to be strongly dominant for small |Zp|/vp values and TS2 is found to be most important for large |Zp|/vp values. Since P states cannot be formed significantly via a shake process, the TS1 and TS2 separation provides a direct signature of the dielectronic process. On the other hand, the TS1 process is shown to be the unique process for producing the S states. At the moment, only the shake aspect of the TS1 process can explain the fact that the 2s3s configuration is preferentially

  8. Numerical analysis of the chemical kinetic mechanisms of ozone depletion and halogen release in the polar troposphere

    Science.gov (United States)

    Cao, L.; Sihler, H.; Platt, U.; Gutheil, E.

    2014-04-01

    The role of halogen species (e.g., Br, Cl) in the troposphere of polar regions has been investigated since the discovery of their importance for boundary layer ozone destruction in the polar spring about 25 years ago. Halogen species take part in an auto-catalytic chemical reaction cycle, which releases Br2 and BrCl from the sea salt aerosols, fresh sea ice or snowpack, leading to ozone depletion. In this study, three different chemical reaction schemes are investigated: a bromine-only reaction scheme, which then is subsequently extended to include nitrogen-containing compounds and chlorine species and corresponding chemical reactions. The importance of specific reactions and their rate constants is identified by a sensitivity analysis. The heterogeneous reaction rates are parameterized by considering the aerodynamic resistance, a reactive surface ratio, β, i.e., the ratio of reactive surface area to total ground surface area, and the boundary layer height, Lmix. It is found that for β = 1, a substantial ozone decrease occurs after five days and ozone depletion lasts for 40 h for Lmix = 200 m. For about β ≥ 20, the time required for major ozone depletion ([O3] layer, and for β = 100 it approaches two days, 28 h of which are attributable to the induction and 20 h to the depletion time. In polar regions, a small amount of NOx may exist, which stems from nitrate contained in the snow, and may have a strong impact on the ozone depletion. Therefore, the role of nitrogen-containing species on the ozone depletion rate is studied. The results show that the NOx concentrations are influenced by different chemical reactions over different time periods. During ozone depletion, the reaction cycle involving the BrONO2 hydrolysis is dominant. A critical value of 0.0004 of the uptake coefficient of the BrONO2 hydrolysis reaction at the aerosol and saline surfaces is identified, beyond which the existence of NOx species accelerates the ozone depletion event, whereas for lower

  9. Some developments in polarized ion sources

    International Nuclear Information System (INIS)

    Witteveen, G.J.

    1979-01-01

    Investigations concerning an atomic beam source are presented and a new polarized ion source of a more universal type is introduced. Polarized and unpolarized beams of positively or negatively charged ions can be produced with this new version and the theoretical limits are a polarized negative hydrogen ion beam with an intensity of about 1 mH and a polarized proton beam with an intensity of 10 mH. (C.F.)

  10. In-plane charge fluctuations in bismuth-sulfide superconductors

    Science.gov (United States)

    Athauda, Anushika; Yang, Junjie; Lee, Seunghun; Mizuguchi, Yoshikazu; Deguchi, Keita; Takano, Yoshihiko; Miura, Osuke; Louca, Despina

    2015-04-01

    The local atomic structure of the new nonmagnetic superconducting system LaO1-xFxBiS2 is investigated using neutron diffraction and the pair density function analysis. Evidence for local charge fluctuations linked to a charge disproportionation of the Bi ions in the distorted lattice of superconducting LaO1-xFxBiS2 is presented. In-plane short-range distortions of sulfur atoms up to 0.3 Å in magnitude break site symmetry and create two distinct environments around Bi. Out-of-plane motion of apical sulfur brings it closer to the La-O/F doping layer with increasing x that may lead to a charge transfer conduit between the doping layers and the superconducting BiS2 planes. The mechanism for superconductivity may arise from the interplay between charge density fluctuations and an enhanced spin-orbit coupling suggested theoretically that induces spin polarization.

  11. Dynamical mechanism of charge separation by photoexcited generation of proton-electron pairs in organic molecular systems. A nonadiabatic electron wavepacket dynamics study

    Science.gov (United States)

    Yamamoto, Kentaro; Takatsuka, Kazuo

    2016-08-01

    In this perspective article, we review, along with presenting new results, a series of our theoretical analyses on the excited-state mechanism of charge separation (proton-electron pair creation) relevant to the photoinduced water-splitting reaction (2H2O → 4H+ + 4e- + O2) in organic and biological systems, which quite often includes Mn clusters in various molecular configurations. The present mechanism is conceived to be universal in the triggering process of the photoexcited water splitting dynamics. In other words, any Mn-based catalytic charge separation is quite likely to be initiated according to this mechanism. As computationally tractable yet realistic models, we examine a series of systems generally expressed as X-Mn-OH2⋯A, where X = (OH, Ca(OH)3) and A = (N-methylformamidine, guanidine, imidazole or ammonia cluster) in terms of the theory of nonadiabatic electron wavepacket dynamics. We first find both an electron and a proton are simultaneously transferred to the acceptors through conical intersections upon photoexcitation. In this mechanism, the electron takes different pathways from that of the proton and reaches the densely lying Rydberg-like states of the acceptors in the end, thereby inducing charge separation. Therefore the presence of the Rydberg-like diffused unoccupied states as an electron acceptor is critical for this reaction to proceed. We also have found another crucial nonadiabatic process that deteriorates the efficiency of charge separation by rendering the created pair of proton and electron back to the originally donor site through the states of d-d band originated from Mn atom. Repetition of this process gradually annihilates the created pair of proton and electron in a way different from the usual charge recombination process. We address this dynamics by means of our proposed path-branching representation. The dynamical roles of a doped Ca atom are also uncovered, which are relevant to controlling the pathways of electron

  12. Polarized Neutron Reflectometry of Nickel Corrosion Inhibitors.

    Science.gov (United States)

    Wood, Mary H; Welbourn, Rebecca J L; Zarbakhsh, Ali; Gutfreund, Philipp; Clarke, Stuart M

    2015-06-30

    Polarized neutron reflectometry has been used to investigate the detailed adsorption behavior and corrosion inhibition mechanism of two surfactants on a nickel surface under acidic conditions. Both the corrosion of the nickel surface and the structure of the adsorbed surfactant layer could be monitored in situ by the use of different solvent contrasts. Layer thicknesses and roughnesses were evaluated over a range of pH values, showing distinctly the superior corrosion inhibition of one negatively charged surfactant (sodium dodecyl sulfate) compared to a positively charged example (dodecyl trimethylammonium bromide) due to its stronger binding interaction with the surface. It was found that adequate corrosion inhibition occurs at significantly less than full surface coverage.

  13. Degradation Mechanisms in Blue Phosphorescent Organic Light-Emitting Devices by Exciton-Polaron Interactions: Loss in Quantum Yield versus Loss in Charge Balance.

    Science.gov (United States)

    Zhang, Yingjie; Aziz, Hany

    2017-01-11

    We study the relative importance of deterioration of material quantum yield and charge balance to the electroluminescence stability of PHOLEDs, with a special emphasis on blue devices. Investigations show that the quantum yields of both host and emitter in the emission layer degrade due to exciton-polaron interactions and that the deterioration in material quantum yield plays the primary role in device degradation under operation. On the other hand, the results show that the charge balance factor is also affected by exciton-polaron interactions but only plays a secondary role in determining device stability. Finally, we show that the degradation mechanisms in blue PHOLEDs are fundamentally the same as those in green PHOLEDs. The limited stability of the blue devices is a result of faster deterioration in the quantum yield of the emitter.

  14. Polarization Bremsstrahlung

    CERN Document Server

    Korol, Andrey V

    2014-01-01

    This book introduces and reviews both theory and applications of polarizational bremsstrahlung, i.e. the electromagnetic radiation emitted during collisions of charged particles with structured, thus polarizable targets, such as atoms, molecules and clusters.   The subject, following the first experimental evidence a few decades ago, has gained importance through a number of modern applications.  Thus, the study of several radiative mechanisms is expected to lead to the design of novel light sources, operating in various parts of the electromagnetic spectrum. Conversely, the analysis of the spectral and angular distribution of the photon emission constitutes a new tool for extracting information on the interaction of the colliding particles, and on their internal structure and dynamical properties.   Last but not least, accurate quantitative descriptions of the photon emission processes determine the radiative energy losses of particles in various media, thereby providing essential  information required f...

  15. Polarization extension mechanism revealed through dynamic ferroelectric hysteresis and electric field driven structural distortions in lead free Na0.5Bi0.5TiO3 ceramic

    Science.gov (United States)

    Karthik, T.; Asthana, Saket

    2017-09-01

    The electric field amplitude (E o) dependent dynamic ferroelectric hysteresis and polarization current density curves measured at room temperature for Na0.5Bi0.5TiO3 (NBT), showed three different stages of polarization reversal mechanism. The scaling relationship confirmed the dominance of domain wall motion at Stage I (i.e. upto E o  <  35 kV cm-1), followed by domain switching at Stage II (35 kV cm-1  <  E o  <  60 kV cm-1). Interestingly, a unique behaviour with two sub stages was observed in Stage III (60 kV cm-1  <  E o  <  90 kV cm-1), with two distinct switching mechanisms viz., polarization rotation at Stage III-A and polarization extension at Stage III-B. X-ray diffraction analysis based on the Rietveld refined atomic positional co-ordinates, in electrically poled system strongly favors the polarization extension mechanism proposed at Stage III-B. The measured E o-dependent longitudinal piezoelectric response (d 33 and g33) values match closely with our proposed polarization reversal mechanism.

  16. Charge storage mechanisms of manganese oxide nanosheets and N-doped reduced graphene oxide aerogel for high-performance asymmetric supercapacitors

    Science.gov (United States)

    Iamprasertkun, Pawin; Krittayavathananon, Atiweena; Seubsai, Anusorn; Chanlek, Narong; Kidkhunthod, Pinit; Sangthong, Winyoo; Maensiri, Santi; Yimnirun, Rattikorn; Nilmoung, Sukanya; Pannopard, Panvika; Ittisanronnachai, Somlak; Kongpatpanich, Kanokwan; Limtrakul, Jumras; Sawangphruk, Montree

    2016-11-01

    Although manganese oxide- and graphene-based supercapacitors have been widely studied, their charge storage mechanisms are not yet fully investigated. In this work, we have studied the charge storage mechanisms of K-birnassite MnO2 nanosheets and N-doped reduced graphene oxide aerogel (N-rGOae) using an in situ X-ray absorption spectroscopy (XAS) and an electrochemical quart crystal microbalance (EQCM). The oxidation number of Mn at the MnO2 electrode is +3.01 at 0 V vs. SCE for the charging process and gets oxidized to +3.12 at +0.8 V vs. SCE and then reduced back to +3.01 at 0 V vs. SCE for the discharging process. The mass change of solvated ions, inserted to the layers of MnO2 during the charging process is 7.4 μg cm-2. Whilst, the mass change of the solvated ions at the N-rGOae electrode is 8.4 μg cm-2. An asymmetric supercapacitor of MnO2//N-rGOae (CR2016) provides a maximum specific capacitance of ca. 467 F g-1 at 1 A g-1, a maximum specific power of 39 kW kg-1 and a specific energy of 40 Wh kg-1 with a wide working potential of 1.6 V and 93.2% capacity retention after 7,500 cycles. The MnO2//N-rGOae supercapacitor may be practically used in high power and energy applications.

  17. Near-threshold photoionization of aromatic solutes in polar solvents

    Science.gov (United States)

    Kohler, Bern

    2000-03-01

    In recent years, pump-probe experiments with femtosecond laser pulses have provided exciting new insight into the dynamics of excess electrons in polar liquids. Some of these findings are resulting in revisions to long-held notions in radiation chemistry. In particular, there is now increasing evidence that photoionization close to threshold proceeds by a mechanism radically different than that of charge ejection from an isolated molecule. Photoionization in this near-threshold regime does not require the promotion of an electron to the conduction band of the solvent, but can instead proceed by a mechanism that more closely resembles photoinduced electron transfer to localized electronic states. The density of these localized trapping states is substantial in water and extends as much as several eV below the conduction band edge. Charge ejection experiments in polar solvents can thus provide new information about the energy landscapes of molecular liquids. Because it is inconvenient to access the ionization threshold energy of neat liquids, our work has focused on charge ejection from aromatic compounds "doped" into the band gap of various polar solvents. This allows easier access to the energies necessary for near-threshold photoionization and allows specific solute-solvent interactions to be explored by chemical substitution. Results from femtosecond transient absorption experiments will be presented on the photoionization dynamics of indole, benzimidazole, and some nucleic acid bases. In addition, some results will be presented from photodetachment experiments on solvated radical ions.

  18. Difference in surface reactions between titanium and zirconium in Hanks' solution to elucidate mechanism of calcium phosphate formation on titanium using XPS and cathodic polarization

    International Nuclear Information System (INIS)

    Tsutsumi, Y.; Nishimura, D.; Doi, H.; Nomura, N.; Hanawa, T.

    2009-01-01

    Titanium and zirconium were immersed in Hanks' solution with and without calcium and phosphate ions, and the surfaces were characterized with X-ray photoelectron spectroscopy (XPS) to determine the mechanism of calcium phosphate formation on titanium in simulated body fluids and in a living body. In addition, they were cathodically polarized in the above solutions. XPS characterization and cathodic polarization revealed differences in the surface properties in the ability of calcium phosphate formation between titanium and zirconium. The surface oxide film on titanium is not completely oxidized and is relatively reactive; that on zirconium is more passive and protective than that on titanium. Neither calcium nor phosphate stably exists alone on titanium, and calcium phosphate is naturally formed on it; calcium phosphate formed on titanium is stable and protective. On the other hand, calcium is never incorporated on zirconium, while zirconium phosphate, which is easily formed on zirconium, is highly stable and protective. Our study presents new information regarding the surface property of titanium and demonstrates that the characteristics of titanium and zirconium may be applied to various medical devices and new surface modification techniques.

  19. Space-charge-mediated anomalous ferroelectric switching in P(VDF-TrEE) polymer films

    KAUST Repository

    Hu, Weijin

    2014-11-12

    We report on the switching dynamics of P(VDF-TrEE) copolymer devices and the realization of additional substable ferroelectric states via modulation of the coupling between polarizations and space charges. The space-charge-limited current is revealed to be the dominant leakage mechanism in such organic ferroelectric devices, and electrostatic interactions due to space charges lead to the emergence of anomalous ferroelectric loops. The reliable control of ferroelectric switching in P(VDF-TrEE) copolymers opens doors toward engineering advanced organic memories with tailored switching characteristics.

  20. Polarization developments

    International Nuclear Information System (INIS)

    Prescott, C.Y.

    1993-07-01

    Recent developments in laser-driven photoemission sources of polarized electrons have made prospects for highly polarized electron beams in a future linear collider very promising. This talk discusses the experiences with the SLC polarized electron source, the recent progress with research into gallium arsenide and strained gallium arsenide as a photocathode material, and the suitability of these cathode materials for a future linear collider based on the parameters of the several linear collider designs that exist

  1. Mechanism of electron multiplication due to charging for a SiO2sample with a buried microstructure in SEM: A simulation analysis.

    Science.gov (United States)

    Wang, Fang; Feng, Guobao; Zhang, Xiusheng; Cao, Meng

    2016-11-01

    This study investigates the mechanism of electron redistribution and multiplication for a SiO 2 sample with a buried structure in scanning electron microscopy by numerical simulation. The simulation involved electron scattering and internal charge transport in the sample, the tracking of emitted secondary electrons (SEs), and the generation of tertiary electrons (TEs) produced by returned SEs due to charging of the sample. The results show that a buried grounded structure causes a non-uniform distribution of surface potential, and an electric field above the surface. As a result, although the number of escaped SEs above the margin of the buried structure decreases, the number of generated TEs increases more, leading to a final current of electrons that include escaped SEs and increased TEs. This multiplication of SEs might make a crucial contribution to the abnormal negative-charging contrast in SEM. During the electron beam irradiation, the variation in the number of total escaped electrons presents an obvious increase after an initial slight decrease, which corresponded to the transient characteristics of gray levels in SEM images from dark to abnormally bright. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Sources for charged particles

    International Nuclear Information System (INIS)

    Arianer, J.

    1997-01-01

    This document is a basic course on charged particle sources for post-graduate students and thematic schools on large facilities and accelerator physics. A simple but precise description of the creation and the emission of charged particles is presented. This course relies on every year upgraded reference documents. Following relevant topics are considered: electronic emission processes, technological and practical considerations on electron guns, positron sources, production of neutral atoms, ionization, plasma and discharge, different types of positive and negative ion sources, polarized particle sources, materials for the construction of ion sources, low energy beam production and transport. (N.T.)

  3. Mechanism of Lipid Binding of Human Apolipoprotein E3 by Hydrogen/Deuterium Exchange/Mass Spectrometry and Fluorescence Polarization.

    Science.gov (United States)

    Fabilane, Charina S; Nguyen, Patricia N; Hernandez, Roy V; Nirudodhi, Sasidhar; Duong, Mai; Maier, Claudia S; Narayanaswami, Vasanthy

    2016-01-01

    Human apolipoprotein E3 (apoE3) is an exchangeable apolipoprotein that plays a critical role in maintaining plasma cholesterol/triglyceride homeostasis. The C-terminal (CT) domain of apoE3 (residues 201-299) is composed of amphipathic α-helices C1: W210-S223, C2: V236-E266, and C3: D271-W276, which play a dominant role in mediating high-affinity lipid binding. The objective is to understand the accessibility of the CT domain at the sub-domain level and the mechanistic details regarding lipid-binding interaction. Hydrogen-deuterium exchange coupled to mass spectrometry (HDX/MS) of recombinant wild type (WT) apoE(201-299), chemical-induced unfolding monitored as changes in fluorescence polarization (FP) of labeled apoE(201-299) bearing a probe at specified sites, and lipid binding studies were carried out. HDX/MS revealed that residues towards the C-terminal end of the domain display significantly lower %D uptake compared to those towards the center, suggesting extensive protein-protein interaction in this segment. Functional assays showed that locking apoE(201-299) in an inter-molecular disulfide-bonded state at position 209, 223, 255, or 277 significantly decreases its ability to interact with lipids, especially when tethered towards the ends; this could be restored by reduction. Unfolding studies indicate that the C-terminal end offers less resistance to unfolding compared to the central portion of the domain. Taken together, our data suggest that two dimers of CT domain are juxtaposed around helix C3 leading to apoE3 tetramerization, and that dissociation to monomeric units is a required step in lipid binding, with helix C3 likely seeking stability via lipid interaction prior to helices C1 or C2.

  4. MECHANISMS OF PRIMARY RECEPTION OF ELECTROMAGNETIC WAVES OF OPTICAL RANGE AS A BIOPHYSICAL BASIS OF POLARIZED LIGHT THERAPY

    Directory of Open Access Journals (Sweden)

    S. O. Hulyar

    2015-09-01

    Full Text Available An existence of separate functional system of electromagnetic balance regulation has been substantiated and a working conception of light puncture has been formulated. As a basis, there is a possibility to use the acupuncture points for input of biologically necessary electromagnetic waves into the system of their conductors in a body that might be considered as a transport facility for energy ofthe polarized electromagnetic waves. Zones-recipients are organs having an electromagnetic disbalance due to excess of biologically inadequate radiation and being the targets for peroxide oxidation, foremost, a body has the neurohormonal and immune regulatory systems. Electromagnetic stimulation or modification of functions of the zones-recipients determines achievement of therapeutic and useful effects, and their combination with local reparative processes allows attaining a clinical goal. We represent own and literary experimental data about development of physiological responses (analgesia, bronchospasm control, immune stimulation and inhibition of peroxide oxidation of lipids to BIOPTRON-light exposure on the acupuncture points or biologically active zones. We show the experimental facts in support of a hypothesis that a living organism can perceive an action of the electromagnetic waves of optical range not only via the visual system, but also through the off-nerve receptors (specific energy-sensitive proteins detecting critical changes of energy in cells and functioning as the "sensory" cell systems, as well as via the acupuncture points. This confirms an important role of the electromagnetic waves of optical range in providing normal vital functions of living organisms. A current approach to BIOPTRON light therapy consists in combined (local and system exposure of the electromagnetic waves within the biologically necessary range.

  5. Polarization tunable photogenerated carrier transfer of CH3NH3PbI3/polyvinylidene fluoride heterostructure

    Science.gov (United States)

    Yang, Kang; Deng, Zun-Yi; Feng, Hong-Jian

    2017-10-01

    The integration of ferroelectrics and organic-inorganic halide perovskites could be a promising way to facilitate the separation of electron-hole pairs and charge extraction for the application of solar cells. To explore the effect of the external ferroelectric layer on the CH3NH3PbI3 (MAPbI3) side, we perform first-principles calculations to study the charge transfer properties of the MAPbI3/polyvinylidene fluoride (PVDF) heterostructure. Our calculations demonstrate that the ferroelectric polarization pointing to the PVDF side can clearly facilitate the separation of photo-induced carriers and enhance charge extraction from MAPbI3, while opposite polarization direction hinders the charge extraction and collection. Notably, the carrier behavior at the interface is strongly tuned by the electric field associated with the ferroelectric polarization. In addition, excited state simulation confirms the tunable charge transfer of the MAPbI3/PVDF heterojunction. Therefore, the polarization-driven charge transfer mechanism provides a route for fabricating the ferroelectrics-based high-efficiency photovoltaics and switchable diode devices.

  6. Strong electron-lattice coupling as the mechanism behind charge density wave transformations in transition-metal dichalcogenides

    Science.gov (United States)

    Gor'kov, Lev P.

    2012-04-01

    We consider a single band of conduction electrons interacting with displacements of the transitional ions. In the classical regime strong enough coupling transforms the harmonic elastic energy for an ion to the one of the well with two deep minima, so that the system is described in terms of Ising spins. Intersite interactions order spins at lower temperatures. Extension to the quantum regime is discussed. Below the charge density wave (CDW) transition the energy spectrum of electrons remains metallic because the structural vector Q and the Fermi surface sizes are not related. Large values of the CDW gap seen in the tunneling experiments correspond to the energy of the minima in the electron-ion two-well complex. The gap is defined through the density of states inside the electronic bands below the CDW transition. We focus mainly on electronic properties of transition-metal dichalcogenides.

  7. Polarization, political

    NARCIS (Netherlands)

    Wojcieszak, M.; Mazzoleni, G.; Barnhurst, K.G.; Ikeda, K.; Maia, R.C.M.; Wessler, H.

    2015-01-01

    Polarization has been studied in three different forms: on a social, group, and individual level. This entry first focuses on the undisputed phenomenon of elite polarization (i.e., increasing adherence of policy positions among the elites) and also outlines different approaches to assessing mass

  8. Investigation of surfactant mediated acid-base charging of mineral oxide particles dispersed in apolar systems.

    Science.gov (United States)

    Gacek, Matthew M; Berg, John C

    2012-12-21

    The current work examines the role of acid-base properties on particle charging in apolar media. Manipulating the polarity and magnitude of charge in such systems is of growing interest to a number of applications. A major hurdle to the implementation of this technology is that the mechanism(s) of particle charging remain a subject of debate. The authors previously conducted a study of the charging of a series of mineral oxide particles dispersed in apolar systems that contained the surfactant AOT. It was observed that there was a correlation between the particle electrophoretic mobility and the acid-base nature of the particle, as characterized by aqueous point of zero charge (PZC) or the isoelectric point (IEP). The current study investigates whether or not a similar correlation is observed with other surfactants, namely, the acidic Span 80 and the basic OLOA 11000. This is accomplished by measuring the electrophoretic mobility of a series of mineral oxides that are dispersed in Isopar-L containing various concentrations of either Span 80 or OLOA 11000. The mineral oxides used have PZC values that cover a wide range of pH, providing a systematic study of how particle and surfactant acid-base properties impact particle charge. It was found that the magnitude and polarity of particle surface charge varied linearly with the particle PZC for both surfactants used. In addition, the point at which the polarity of charge reversed for the basic surfactant OLOA 11000 was shifted to a pH of approximately 8.5, compared to the previous result of about 5 for AOT. This proves that both surfactant and particle acid-base properties are important, and provides support for the theory of acid-base charging in apolar media.

  9. Temperature dependent polarization reversal mechanism in 0.94(Bi1/2Na1/2)TiO3-0.06Ba(Zr0.02Ti0.98)O3 relaxor ceramics

    Science.gov (United States)

    Glaum, Julia; Simons, Hugh; Hudspeth, Jessica; Acosta, Matias; Daniels, John E.

    2015-12-01

    The temperature at which the electric field induced long-range ordered ferroelectric state undergoes transition into the short-range ordered relaxor state, TF-R, is commonly defined by the onset of strong dispersion of the dielectric permittivity. However, this combined macroscopic property and structural investigation of the polarization reversal process in the prototypical lead-free relaxor 0.94(Bi1/2Na1/2)TiO3-0.06Ba(Zr0.02Ti0.98)O3 reveals that an applied electric field can trigger depolarization and onset of relaxor-like behavior well below TF-R. The polarization reversal process can as such be described as a combination of (1) ferroelectric domain switching and (2) a reversible phase transition between two polar ferroelectric states mediated by a non-polar relaxor state. Furthermore, the threshold fields of the second, mediated polarization reversal mechanism depend strongly on temperature. These results are concomitant with a continuous ferroelectric to relaxor transition occurring over a broad temperature range, during which mixed behavior is observed. The nature of polarization reversal can be illustrated in electric-field-temperature (E-T) diagrams showing the electric field amplitudes associated with different polarization reversal processes. Such diagrams are useful tools for identifying the best operational temperature regimes for a given composition in actuator applications.

  10. Polarization holography

    DEFF Research Database (Denmark)

    Nikolova, L.; Ramanujam, P.S.

    Current research into holography is concerned with applications in optically storing, retrieving, and processing information. Polarization holography has many unique properties compared to conventional holography. It gives results in high efficiency, achromaticity, and special polarization...... properties. This books reviews the research carried out in this field over the last 15 years. The authors provide basic concepts in polarization and the propagation of light through anisotropic materials, before presenting a sound theoretical basis for polarization holography. The fabrication...... and characterization of azobenzene based materials, which remain the most efficient for the purpose, is described in detail. This is followed by a description of other materials that are used in polarization holography. An in-depth description of various applications, including display holography and optical storage...

  11. Dynamic nuclear spin polarization

    Energy Technology Data Exchange (ETDEWEB)

    Stuhrmann, H.B. [GKSS-Forschungszentrum Geesthacht GmbH (Germany)

    1996-11-01

    Polarized neutron scattering from dynamic polarized targets has been applied to various hydrogenous materials at different laboratories. In situ structures of macromolecular components have been determined by nuclear spin contrast variation with an unprecedented precision. The experiments of selective nuclear spin depolarisation not only opened a new dimension to structural studies but also revealed phenomena related to propagation of nuclear spin polarization and the interplay of nuclear polarisation with the electronic spin system. The observation of electron spin label dependent nuclear spin polarisation domains by NMR and polarized neutron scattering opens a way to generalize the method of nuclear spin contrast variation and most importantly it avoids precontrasting by specific deuteration. It also likely might tell us more about the mechanism of dynamic nuclear spin polarisation. (author) 4 figs., refs.

  12. Polar Bears

    Science.gov (United States)

    Amstrup, Steven C.; Douglas, David C.; Reynolds, Patricia E.; Rhode, E.B.

    2002-01-01

    Polar bears (Ursus maritimus) are hunted throughout most of their range. In addition to hunting polar bears of the Beaufort Sea region are exposed to mineral and petroleum extraction and related human activities such as shipping road-building, and seismic testing (Stirling 1990).Little was known at the start of this project about how polar bears move about in their environment, and although it was understood that many bears travel across political borders, the boundaries of populations had not been delineated (Amstrup 1986, Amstrup et al. 1986, Amstrup and DeMaster 1988, Garner et al. 1994, Amstrup 1995, Amstrup et al. 1995, Amstrup 2000).As human populations increase and demands for polar bears and other arctic resources escalate, managers must know the sizes and distributions of the polar bear populations. Resource managers also need reliable estimates of breeding rates, reproductive intervals, litter sizes, and survival of young and adults.Our objectives for this research were 1) to determine the seasonal and annual movements of polar bears in the Beaufort Sea, 2) to define the boundaries of the population(s) using this region, 3) to determine the size and status of the Beaufort Sea polar bear population, and 4) to establish reproduction and survival rates (Amstrup 2000).

  13. Optically pumped polarized H- ion source

    International Nuclear Information System (INIS)

    Anderson, L.W.

    1986-01-01

    The current status and future prospects for the optically pumped polarized H - ion source are discussed. At the present time H - ion currents of 60 μA and with a polarization of 65% have been produced. The ion current and polarization can be increased significantly if the optically pumped Na charge exchange target density and polarization can be increased. Studies of wall surfaces that permit many bounces before depolarizing the Na electron spin and studies of radiation trapping in optically pumped Na indicate that the Na target density and polarization can be increased substantially. 27 refs., 6 figs., 2 tabs

  14. Effect of annealing treatments on photoluminescence and charge storage mechanism in silicon-rich SiNx:H films

    Directory of Open Access Journals (Sweden)

    Sahu Bhabani

    2011-01-01

    Full Text Available Abstract In this study, a wide range of a-SiNx:H films with an excess of silicon (20 to 50% were prepared with an electron-cyclotron resonance plasma-enhanced chemical vapor deposition system under the flows of NH3 and SiH4. The silicon-rich a-SiNx:H films (SRSN were sandwiched between a bottom thermal SiO2 and a top Si3N4 layer, and subsequently annealed within the temperature range of 500-1100°C in N2 to study the effect of annealing temperature on light-emitting and charge storage properties. A strong visible photoluminescence (PL at room temperature has been observed for the as-deposited SRSN films as well as for films annealed up to 1100°C. The possible origins of the PL are briefly discussed. The authors have succeeded in the formation of amorphous Si quantum dots with an average size of about 3 to 3.6 nm by varying excess amount of Si and annealing temperature. Electrical properties have been investigated on Al/Si3N4/SRSN/SiO2/Si structures by capacitance-voltage and conductance-voltage analysis techniques. A significant memory window of 4.45 V was obtained at a low operating voltage of ± 8 V for the sample containing 25% excess silicon and annealed at 1000°C, indicating its utility in low-power memory devices.

  15. Polarization versus Temperature in Pyridinium Ionic Liquids

    DEFF Research Database (Denmark)

    Chaban, V. V.; Prezhdo, O. V.

    2014-01-01

    Electronic polarization and charge transfer effects play a crucial role in thermodynamic, structural, and transport properties of room-temperature ionic liquids (RTILs). These nonadditive interactions constitute a useful tool for tuning physical chemical behavior of RTILs. Polarization and charge...... electronic density description for a cationanion pair. Atom-centered density matrix propagation molecular dynamics, supplemented by a weak coupling to an external bath, is used to simulate the temperature impact on system properties. We show that, quite surprisingly, nonadditivity in the cationanion...

  16. From light polarization to the basic ideas of Quantum Mechanics. Experience carried out in a Technical Institute in Scampia (Naples)

    International Nuclear Information System (INIS)

    Moretti, M.

    2014-01-01

    The article focuses on teaching/learning Quantum Mechanics (QM) in secondary schools and involves two fundamental aspects: teacher training and experimentation in the classroom, carefully reflecting on the content and highlighting innovation in the teaching methodology. The experience of training took place within a second level post-graduate Master course for Physics teachers (The II level post-graduate Master course in Didactic Innovation in Physics and Guidance (Innovazione Didattica in Fisica e Orientamento IDIFO) http://www.fisica.uniud.it/ URDF/laurea/index.htm) is directed by M. Michelini. The University of Udine organizes the course with the collaboration of the Physiscs Education Research Groups of eighteen Italian Universities, and is a part of a training project addressed to physics teachers focused on modern physics. IDIFO is part of a national plan of the Ministry of Education, Research and University for the Scientific Degrees project (Piano Lauree Scientifiche)), based on a module dedicated to teaching/learning QM according to the fundamental concepts of Dirac theory. The teacher achieved formation attending three e-learning courses about teaching/learning quantum mechanics in secondary schools, researching and discussing research materials of physics education, planning an intervention module and experimenting in a real classroom the planned innovative path for a situated formation. The experimentation, carried out in a fifth class of a Technical Institute at Scampia (Naples), made the conclusive phase and gave data concerning the thinking ways of the students about some basic concepts of QM collected and evaluated. In particular, average students focused more the functional/applicative aspects of formal and conceptual constructs rather than on their physical meanings.

  17. Gate-bias controlled charge trapping as a mechanism for NO2 detection with field-effect transistors

    NARCIS (Netherlands)

    Andringa, A.-M.; Meijboom, J.R.; Smits, E.C.P.; Mathijssen, S.G.J.; Blom, P.W.M.; Leeuw, D.M. de

    2011-01-01

    Detection of nitrogen dioxide, NO2, is required to monitor the air-quality for human health and safety. Commercial sensors are typically chemiresistors, however field-effect transistors are being investigated. Although numerous investigations have been reported, the NO2 sensing mechanism is not

  18. Gate-Bias Controlled Charge Trapping as a Mechanism for NO2 Detection with Field-Effect Transistors

    NARCIS (Netherlands)

    Andringa, Anne-Marije; Meijboom, Juliaan R.; Smits, Edsger C. P.; Mathijssen, Simon G. J.; Blom, Paul W. M.; de Leeuw, Dago M.

    2011-01-01

    Detection of nitrogen dioxide, NO2, is required to monitor the air-quality for human health and safety. Commercial sensors are typically chemiresistors, however field-effect transistors are being investigated. Although numerous investigations have been reported, the NO2 sensing mechanism is not

  19. Study of elementary transfer mechanisms during a collision between a swift multi-charged heavy ion and a neutral atom

    International Nuclear Information System (INIS)

    Jardin, P.

    1995-01-01

    This work is dedicated to the study of the energy transfer mechanisms which occur during a collision between a swift multicharged heavy ion and a neutral atom. The elementary energy energy transfer mechanisms (scattering, excitation, ionization, capture) and their consequences on the target velocity after the collision (recoil velocity) are recalled in the first chapter. In the case of small projectile diffusion angles, we show that the recoil velocity component, transverse to the incident projectile direction, results principally from the diffusion mechanism, while the longitudinal component is due essentially to the mass transfer and the inelastic energy transfer mechanisms. Since the target recoil velocities are very small, we have built an experimental set-up which reduces the impreciseness on their measurement due to the target thermal spread using, as targets, cooled atoms of a supersonic jet (temperature 44+ (6.7 MeV/A) + Ar => Xe 44 + Ar q+ +qe - (q ranging from 1 to 7); Xe 44+ (6.7 MeV/A) + He => Xe 44+ He 1+,2+ +1e - ,2e - . We show that it is possible to interpret the recoil velocity in terms of kinetic energy transferred to the target and to the electrons ejected from the target. (author)

  20. An insight into the mechanism of charge transfer properties of hybrid organic (MEH-PPV): Inorganic (TiO2) nanocomposites

    International Nuclear Information System (INIS)

    Mittal, Tanu; Tiwari, Sangeeta; Mehta, Aarti; Sharma, Shailesh N.

    2016-01-01

    Now a days, inorganic nanoparticles are gaining importance and are potential candidate in different organic electronic device application like (LEDs, PVs) due to their novel properties and confinement in Nano-dimensions. [1, 2] In the present work, we have compared the properties of titanium di oxide (TiO 2 ) nanoparticles (NPs) synthesized by using two different chemical routes aqueous and ethanol respectively. These synthesized TiO 2 nanoparticles have been characterized by X-ray diffraction spectroscopy (XRD) for phase confirmation. It was observed that synthesized nanoparticles are in anatase phase for both preparation routes. Morphological information was collected by scanning electron microscopy (SEM) which confirms that particles are almost spherical in shape and distributed uniformly which is further ensured by transmission electron microscopy (TEM). Dynamic light scattering (DLS) technique was also used for further confirmation of size distribution of as-synthesized nanoparticles. Optical properties were also investigated by photoluminescence and UV-Vis spectroscopy and calculated bandgap was found to be in the range of 3.3-3.5eV for TiO 2 (aq/eth) nanoparticles. The increase in bandgap values with respect to bulk (3.2 eV) confirms that as- synthesized nanoparticles are confined in nanodimensions. As synthesized nanoparticles were interacted with MEHPPV polymer (donor) matrix to make their respective MEHPPV: TiO 2 nanocomposites and to confirm the charge transfer mechanism from polymer to nanoparticles. It can be observed from photoluminescence (PL) quenching experiments that continuous quenching obtained for respective nanocomposites confirms better charge transfer from polymer to inorganic TiO 2 nanoparticles respectively. Because of, better quenching and simultaneously enhanced charge transfer of respective nanocomposites, ensures that these nanocomposites are greatly applicable for photovoltaics (PVs) especially in Hybrid Solar cells (HSCs).

  1. the effect of surface polarity

    Indian Academy of Sciences (India)

    Abstract. An implant material when comes in contact with blood fluids (e.g., blood and lymph), adsorb proteins spontaneously on its surface. Notably, blood coagulation is influenced by many factors, including mainly chemical structure and polarity (charge) of the material. The present study describes the methodology to ...

  2. Detection of charged particles with a methylammonium lead tribromide perovskite single crystal

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Qiang [Nuclear Engineering Program, Department of Mechanical and Aerospace Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Wei, Haotong; Wei, Wei [Department of Mechanical and Materials Engineering, University of Nebraska-Lincoln, Lincoln, Nebraska 68588 (United States); Chuirazzi, William; DeSantis, Dylan [Nuclear Engineering Program, Department of Mechanical and Aerospace Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Huang, Jinsong, E-mail: jhuang2@unl.edu [Department of Mechanical and Materials Engineering, University of Nebraska-Lincoln, Lincoln, Nebraska 68588 (United States); Cao, Lei, E-mail: cao.152@osu.edu [Nuclear Engineering Program, Department of Mechanical and Aerospace Engineering, The Ohio State University, Columbus, Ohio 43210 (United States)

    2017-03-11

    Methylammonium lead tribromide (MAPbBr{sub 3}) perovskite crystals have attracted significant attention due to their attractive performance in various optoelectronic applications such as solar cells, light-emitting devices, photodetectors, and recently in X-ray detectors. In this study, we demonstrate a possible use of perovskite-based devices for detection of charged particles (which can be applied in basic scientific research, health physics, and environmental analysis) and investigate the mechanism of fundamental charge transport inside perovskite crystals. It was found that inexpensive MAPbBr{sub 3} single crystals could be used for measuring the energy spectrum of charged particles through direct collection of the produced charge. After fitting the plot of the centroid peak position versus voltage with the Hecht equation for single-polarity charge transport, the obtained hole mobility-lifetime product was in the range of (0.4–1.6)×10{sup −3} cm{sup 2}/V.

  3. Fractional charges

    International Nuclear Information System (INIS)

    Saminadayar, L.

    2001-01-01

    20 years ago fractional charges were imagined to explain values of conductivity in some materials. Recent experiments have proved the existence of charges whose value is the third of the electron charge. This article presents the experimental facts that have led theorists to predict the existence of fractional charges from the motion of quasi-particles in a linear chain of poly-acetylene to the quantum Hall effect. According to the latest theories, fractional charges are neither bosons nor fermions but anyons, they are submitted to an exclusive principle that is less stringent than that for fermions. (A.C.)

  4. Modulation of UK lightning and the atmospheric electric circuit by heliospheric magnetic field polarity

    Science.gov (United States)

    Owens, Mathew; Scott, Chris; Lockwood, Mike; Barnard, Luke; Harrison, Giles; Nicoll, Keri; Watt, Clare; Bennett, Alec

    2015-04-01

    Observational studies have reported solar magnetic modulation of terrestrial lightning on a range of time scales, from days to decades. The proposed mechanism is two-step: lightning rates vary with galactic cosmic ray (GCR) flux incident on Earth, either via changes in atmospheric conductivity and/or direct triggering of lightning. GCR flux is, in turn, primarily controlled by the heliospheric magnetic field (HMF) intensity. Consequently, global changes in lightning rates are expected. This study instead considers HMF polarity, which doesn't greatly affect total GCR flux. Opposing HMF polarities are, however, associated with a 40 to 60% difference in observed UK lightning and thunder rates. As HMF polarity skews the terrestrial magnetosphere from its nominal position, this perturbs local ionospheric potential at high latitudes and local exposure to energetic charged particles from the magnetosphere. We speculate as to the mechanism(s) by which this may, in turn, redistribute the global location and/or intensity of thunderstorm activity.

  5. Short-distance breakdown of the Higgs mechanism and the robustness of the BCS theory for charged superconductors

    Science.gov (United States)

    Fischer, Sonja; Hecker, Matthias; Hoyer, Mareike; Schmalian, Jörg

    2018-02-01

    Through the Higgs mechanism, the long-range Coulomb interaction eliminates the low-energy Goldstone phase mode in superconductors and transfers spectral weight all the way up to the plasma frequency. Here, we show that the Higgs mechanism breaks down for length scales shorter than the superconducting coherence length while it stays intact, even at high energies, in the long-wavelength limit. This effect is a consequence of the composite nature of the Higgs field of superconductivity and the broken Lorentz invariance in a solid. Most importantly, the breakdown of the Higgs mechanism inside the superconducting coherence volume is crucial to ensure the stability of the BCS mean-field theory in the weak-coupling limit. We also show that changes in the gap equation due to plasmon-induced fluctuations can lead to significant corrections to the mean-field theory and reveal that changes in the density-fluctuation spectrum of a superconductor are not limited to the vicinity of the gap.

  6. Passive electromagnetic NDE for mechanical damage inspection by detecting leakage magnetic flux. (I. Reconstruction of magnetic charges from detected field signals)

    International Nuclear Information System (INIS)

    Chen, Zhenmao; Aoto, Kazumi; Kato, Syoichi

    1999-07-01

    In this report, reconstruction of magnetic charges induced by mechanical damages in a test piece of SUS304 stainless steel is performed as a part of efforts to establish a passive nondestructive testing method on the basis of the inspection of leakage magnetic field. The approach for solving this typical ill-posed inverse problem is selected as a way in the least square method category. Concerning the ill-poseness of the system of equations, an iteration algorithm is adopted to its solving in which the designations of initial profile, the weight coefficients and the total number of iterations are taken as means of regularization. From examples using simulated input data, it is verified that the approach gives good reconstruction results in case of signals with a relative high S/N ratio. For improving the robustness of the proposed method, a Galerkin procedure with base functions chosen as the Daubechies' wavelet is also introduced for discretizing the governing equation. By comparing the reconstruction results of the least square method and those using wavelet discretization, it is found that the wavelet used approach is more feasible in the inversion of noise polluted signals. Reconstruction of 1-D and 2-D magnetic charges with the least square strategy and reconstruction of an 1-D problem with the wavelet used method are carried out from both simulated and measured magnetic field signals which are used as the validation of the proposed inversion strategy. (author)

  7. Passive electromagnetic NDE for mechanical damage inspection by detecting leakage magnetic flux. (I. Reconstruction of magnetic charges from detected field signals)

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Zhenmao; Aoto, Kazumi; Kato, Syoichi [Structure Safety Engineering Group, Oarai Engineering Center, Japan Nuclear Cycle Development Inst., Oarai, Ibaraki (Japan)

    1999-07-01

    In this report, reconstruction of magnetic charges induced by mechanical damages in a test piece of SUS304 stainless steel is performed as a part of efforts to establish a passive nondestructive testing method on the basis of the inspection of leakage magnetic field. The approach for solving this typical ill-posed inverse problem is selected as a way in the least square method category. Concerning the ill-poseness of the system of equations, an iteration algorithm is adopted to its solving in which the designations of initial profile, the weight coefficients and the total number of iterations are taken as means of regularization. From examples using simulated input data, it is verified that the approach gives good reconstruction results in case of signals with a relative high S/N ratio. For improving the robustness of the proposed method, a Galerkin procedure with base functions chosen as the Daubechies' wavelet is also introduced for discretizing the governing equation. By comparing the reconstruction results of the least square method and those using wavelet discretization, it is found that the wavelet used approach is more feasible in the inversion of noise polluted signals. Reconstruction of 1-D and 2-D magnetic charges with the least square strategy and reconstruction of an 1-D problem with the wavelet used method are carried out from both simulated and measured magnetic field signals which are used as the validation of the proposed inversion strategy. (author)

  8. Charge deformation and orbital hybridization: intrinsic mechanisms on tunable chromaticity of Y3Al5O12:Ce3+ luminescence by doping Gd3+ for warm white LEDs

    Science.gov (United States)

    Chen, Lei; Chen, Xiuling; Liu, Fayong; Chen, Haohong; Wang, Hui; Zhao, Erlong; Jiang, Yang; Chan, Ting-Shan; Wang, Chia-Hsin; Zhang, Wenhua; Wang, Yu; Chen, Shifu

    2015-01-01

    The deficiency of Y3Al5O12:Ce (YAG:Ce) luminescence in red component can be compensated by doping Gd3+, thus lead to it being widely used for packaging warm white light-emitting diode devices. This article presents a systematic study on the photoluminescence properties, crystal structures and electronic band structures of (Y1−xGdx)3Al5O12: Ce3+ using powerful experimental techniques of thermally stimulated luminescence, X-ray diffraction, X-ray absorption near edge structure (XANES), extended X-ray absorption fine structure (EXAFS) and ultraviolet photoelectron spectra (UPS) of the valence band, assisted with theoretical calculations on the band structure, density of states (DOS), and charge deformation density (CDD). A new interpretation from the viewpoint of compression deformation of electron cloud in a rigid structure by combining orbital hybridization with solid-state energy band theory together is put forward to illustrate the intrinsic mechanisms that cause the emission spectral shift, thermal quenching, and luminescence intensity decrease of YAG: Ce upon substitution of Y3+ by Gd3+, which are out of the explanation of the classic configuration coordinate model. The results indicate that in a rigid structure, the charge deformation provides an efficient way to tune chromaticity, but the band gaps and crystal defects must be controlled by comprehensively accounting for luminescence thermal stability and efficiency. PMID:26175141

  9. Electrochemical transformation of trichloroethylene in aqueous solution by electrode polarity reversal.

    Science.gov (United States)

    Rajic, Ljiljana; Fallahpour, Noushin; Yuan, Songhu; Alshawabkeh, Akram N

    2014-12-15

    Electrode polarity reversal is evaluated for electrochemical transformation of trichloroethylene (TCE) in aqueous solution using flow-through reactors with mixed metal oxide electrodes and Pd catalyst. The study tests the hypothesis that optimizing electrode polarity reversal will generate H2O2 in Pd presence in the system. The effect of polarity reversal frequency, duration of the polarity reversal intervals, current intensity and TCE concentration on TCE removal rate and removal mechanism were evaluated. TCE removal efficiencies under 6 cycles h(-1) were similar in the presence of Pd catalyst (50.3%) and without Pd catalyst (49.8%), indicating that Pd has limited impact on TCE degradation under these conditions. The overall removal efficacies after 60 min treatment under polarity reversal frequencies of 6, 10, 15, 30 and 90 cycles h(-1) were 50.3%, 56.3%, 69.3%, 34.7% and 23.4%, respectively. Increasing the frequency of polarity reversal increases TCE removal as long as sufficient charge is produced during each cycle for the reaction at the electrode. Electrode polarity reversal shifts oxidation/reduction and reduction/oxidation sequences in the system. The optimized polarity reversal frequency (15 cycles h(-1) at 60 mA) enables two reaction zones formation where reduction/oxidation occurs at each electrode surface. Published by Elsevier Ltd.

  10. The net charge at interfaces between insulators

    International Nuclear Information System (INIS)

    Bristowe, N C; Littlewood, P B; Artacho, Emilio

    2011-01-01

    The issue of the net charge at insulating oxide interfaces is briefly reviewed with the ambition of dispelling myths of such charges being affected by covalency and related charge density effects. For electrostatic analysis purposes, the net charge at such interfaces is defined by the counting of discrete electrons and core ion charges, and by the definition of the reference polarization of the separate, unperturbed bulk materials. The arguments are illustrated for the case of a thin film of LaAlO 3 over SrTiO 3 in the absence of free carriers, for which the net charge is exactly 0.5e per interface formula unit, if the polarization response in both materials is referred to zero bulk values. Further consequences of the argument are extracted for structural and chemical alterations of such interfaces, in which internal rearrangements are distinguished from extrinsic alterations (changes of stoichiometry, redox processes), only the latter affecting the interfacial net charge. The arguments are reviewed alongside the proposal of Stengel and Vanderbilt (2009 Phys. Rev. B 80 241103) of using formal polarization values instead of net interfacial charges, based on the interface theorem of Vanderbilt and King-Smith (1993 Phys. Rev. B 48 4442-55). Implications for non-centrosymmetric materials are discussed, as well as for interfaces for which the charge mismatch is an integer number of polarization quanta. (viewpoint)

  11. The net charge at interfaces between insulators

    Energy Technology Data Exchange (ETDEWEB)

    Bristowe, N C; Littlewood, P B [Theory of Condensed Matter Group, Cavendish Laboratory, University of Cambridge, J J Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Artacho, Emilio, E-mail: ncb30@cam.ac.uk [Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ (United Kingdom)

    2011-03-02

    The issue of the net charge at insulating oxide interfaces is briefly reviewed with the ambition of dispelling myths of such charges being affected by covalency and related charge density effects. For electrostatic analysis purposes, the net charge at such interfaces is defined by the counting of discrete electrons and core ion charges, and by the definition of the reference polarization of the separate, unperturbed bulk materials. The arguments are illustrated for the case of a thin film of LaAlO{sub 3} over SrTiO{sub 3} in the absence of free carriers, for which the net charge is exactly 0.5e per interface formula unit, if the polarization response in both materials is referred to zero bulk values. Further consequences of the argument are extracted for structural and chemical alterations of such interfaces, in which internal rearrangements are distinguished from extrinsic alterations (changes of stoichiometry, redox processes), only the latter affecting the interfacial net charge. The arguments are reviewed alongside the proposal of Stengel and Vanderbilt (2009 Phys. Rev. B 80 241103) of using formal polarization values instead of net interfacial charges, based on the interface theorem of Vanderbilt and King-Smith (1993 Phys. Rev. B 48 4442-55). Implications for non-centrosymmetric materials are discussed, as well as for interfaces for which the charge mismatch is an integer number of polarization quanta. (viewpoint)

  12. Squeezing out hydrated protons: low-frictional-energy triboelectric insulator charging on a microscopic scale

    Directory of Open Access Journals (Sweden)

    Nikolaus Knorr

    2011-06-01

    Full Text Available Though triboelectric charging of insulators is common, neither its mechanism nor the nature of the charge is well known. Most research has focused on the integral amount of charge transferred between two materials upon contact, establishing, e.g., a triboelectric series. Here, the charge distribution of tracks on insulating polymer films rubbed by polymer-covered pointed swabs is investigated in high resolution by Kelvin probe force microscopy. Pronounced bipolar charging was observed for all nine rubbing combinations of three different polymers, with absolute surface potentials of up to several volts distributed in streaks along the rubbing direction and varying in polarity on μm-length scales perpendicular to the rubbing direction. Charge densities increased considerably for rubbing in higher relative humidity, for higher rubbing loads, and for more hydrophilic polymers. The ends of rubbed tracks had positively charged rims. Surface potential decay with time was strongly accelerated in increased humidity, particularly for polymers with high water permeability. Based on these observations, a mechanism is proposed of triboelectrification by extrusions of prevalently hydrated protons, stemming from adsorbed and dissociated water, along pressure gradients on the surface by the mechanical action of the swab. The validity of this mechanism is supported by explanations given recently in the literature for positive streaming currents of water at polymer surfaces and by reports of negative charging of insulators tapped by accelerated water droplets and of potential built up between the front and the back of a rubbing piece, observations already made in the 19th century. For more brittle polymers, strongly negatively charged microscopic abrasive particles were frequently observed on the rubbed tracks. The negative charge of those particles is presumably due in part to triboemission of electrons by polymer chain scission, forming radicals and negatively

  13. Modeling of stored charge in metallized biaxially oriented polypropylene film capacitors based on charging current measurement.

    Science.gov (United States)

    Li, Hua; Wang, Bowen; Li, Zhiwei; Liu, De; Lin, Fuchang; Dai, Ling; Zhang, Qin; Chen, Yaohong

    2013-10-01

    Metallized biaxially oriented polypropylene film (BOPP) capacitors are widely used in pulsed power systems. When the capacitor is used as the energy storage equipment under high electric field, more charges should be provided to maintain the voltage of the capacitor. This should be ascribed to the completion of the slow polarization which may take several hours or even longer. This paper focuses on the stored charge in metallized BOPP film capacitors. The modeling of the stored charge by the equivalent conversion of circuits is conducted to analyse the slow polarization in the BOPP film. The 3-RC network is proposed to represent the time-dependent charge stored in the capacitor. A charging current measurement system is established to investigate the charge storage property of the capacitor. The measurement system can measure the long time charging current with a sampling rate of 300 Hz. The total charge calculated by the charging current indicates that the stored charge in the capacitor under the electric field of 400 V/μm is 13.5% larger than the product of the voltage and the capacitance measured by the AC bridge. The nonlinear effect of the electric field on the slow polarization charge is also demonstrated. And the simulation of charge storage based on the 3-RC network can match well with the trend of the stored charge increasing with the time.

  14. Charge Screening in a Charged Condensate

    International Nuclear Information System (INIS)

    Gabadadze, Gregory; Rosen, Rachel A.

    2009-01-01

    We consider a highly dense system of helium-4 nuclei and electrons in which the helium-4 nuclei have condensed. We present the condensation mechanism in the framework of low energy effective field theory and discuss the screening of electric charge in the condensate.

  15. Charge transport and bipolar switching mechanism in a Cu/HfO2/Pt resistive switching cell

    International Nuclear Information System (INIS)

    Tan Tingting; Guo Tingting; Wu Zhihui; Liu Zhengtang

    2016-01-01

    Bipolar resistance switching characteristics are investigated in Cu/sputtered-HfO 2 /Pt structure in the application of resistive random access memory (RRAM). The conduction mechanism of the structure is characterized to be SCLC conduction. The dependence of resistances in both high resistance state (HRS) and low resistance state (LRS) on the temperature and device area are studied. Then, the composition and chemical bonding state of Cu and Hf at Cu/HfO 2 interface region are analyzed by x-ray photoelectron spectroscopy (XPS). Combining the electrical characteristics and the chemical structure at the interface, a model for the resistive switching effect in Cu/HfO 2 /Pt stack is proposed. According to this model, the generation and recovery of oxygen vacancies in the HfO 2 film are responsible for the resistance change. (paper)

  16. Generalized form of boundary value problems method for material modeled as micro-polar media subjecting to the thermo-mechanical interaction

    Science.gov (United States)

    Zhang, Xiaomin; Zhang, Long; Chu, Zhongxiang; Peng, Song

    2016-09-01

    In this paper, the periodic structure material is modeled as the continuum homogeneous micro-polar media subjecting to thermo-mechanical interaction. Meanwhile, a series of equivalent quantities such as the equivalent stress, couple stress, displacement gradient and torsion tensor were defined by the integral forms of the boundary values of the external surface force, moment, displacement and the angular displacement, and were proved to satisfy the equivalence conditions of virtual work. Based on above works, the displacement boundary value problem was established to deduce the equivalent constitutive equation. Assume the representative volume element is composed of the spatial cross-framework, and applying the boundary value problem of displacement on frame structures, the equivalent elastic coefficients, temperature coefficients of equivalent stress and the temperature gradient coefficients of equivalent couple stress are deduced. In addition, themethod can also be extended to the stress boundary value problem to deduce the equivalent constitutive equation. The calculations indicate that the equivalent result can be obtained from the two kinds of boundary value problems.

  17. Charging transient in polyvinyl formal

    Indian Academy of Sciences (India)

    Unknown

    tally influences all the transport phenomena and their effects at the electrodes. The different facts, including the weak polar structure of polymer, the power-law dependence of current on field, the observed value of 'n' and the thermal activation of current over a certain temperature range indicate that a space charge due to ...

  18. Disruption of the Cdc42/Par6/aPKC or Dlg/Scrib/Lgl Polarity Complex Promotes Epithelial Proliferation via Overlapping Mechanisms.

    Science.gov (United States)

    Schimizzi, Gregory V; Maher, Meghan T; Loza, Andrew J; Longmore, Gregory D

    2016-01-01

    The establishment and maintenance of apical-basal polarity is a defining characteristic and essential feature of functioning epithelia. Apical-basal polarity (ABP) proteins are also tumor suppressors that are targeted for disruption by oncogenic viruses and are commonly mutated in human carcinomas. Disruption of these ABP proteins is an early event in cancer development that results in increased proliferation and epithelial disorganization through means not fully characterized. Using the proliferating Drosophila melanogaster wing disc epithelium, we demonstrate that disruption of the junctional vs. basal polarity complexes results in increased epithelial proliferation via distinct downstream signaling pathways. Disruption of the basal polarity complex results in JNK-dependent proliferation, while disruption of the junctional complex primarily results in p38-dependent proliferation. Surprisingly, the Rho-Rok-Myosin contractility apparatus appears to play opposite roles in the regulation of the proliferative phenotype based on which polarity complex is disrupted. In contrast, non-autonomous Tumor Necrosis Factor (TNF) signaling appears to suppress the proliferation that results from apical-basal polarity disruption, regardless of which complex is disrupted. Finally we demonstrate that disruption of the junctional polarity complex activates JNK via the Rho-Rok-Myosin contractility apparatus independent of the cortical actin regulator, Moesin.

  19. Charge preamplifier

    International Nuclear Information System (INIS)

    Chaminade, R.; Passerieux, J.P.

    1961-01-01

    We describe a charge preamplifier having the following properties: - large open loop gain giving both stable gain and large input charge transfer; - stable input grid current with aging and without any adjustment; - fairly fast rise; - nearly optimum noise performance; - industrial material. (authors)

  20. Political polarization

    OpenAIRE

    Dixit, Avinash K.; Weibull, Jörgen W.

    2007-01-01

    Failures of government policies often provoke opposite reactions from citizens; some call for a reversal of the policy, whereas others favor its continuation in stronger form. We offer an explanation of such polarization, based on a natural bimodality of preferences in political and economic contexts and consistent with Bayesian rationality.

  1. Political polarization.

    Science.gov (United States)

    Dixit, Avinash K; Weibull, Jörgen W

    2007-05-01

    Failures of government policies often provoke opposite reactions from citizens; some call for a reversal of the policy, whereas others favor its continuation in stronger form. We offer an explanation of such polarization, based on a natural bimodality of preferences in political and economic contexts and consistent with Bayesian rationality.

  2. Charging machine

    International Nuclear Information System (INIS)

    Medlin, J.B.

    1976-01-01

    A charging machine for loading fuel slugs into the process tubes of a nuclear reactor includes a tubular housing connected to the process tube, a charging trough connected to the other end of the tubular housing, a device for loading the charging trough with a group of fuel slugs, means for equalizing the coolant pressure in the charging trough with the pressure in the process tubes, means for pushing the group of fuel slugs into the process tube and a latch and a seal engaging the last object in the group of fuel slugs to prevent the fuel slugs from being ejected from the process tube when the pusher is removed and to prevent pressure liquid from entering the charging machine. 3 claims, 11 drawing figures

  3. Performance of the SLC polarized electron source with high polarization

    International Nuclear Information System (INIS)

    Clendenin, J.E.; Alley, R.K.; Aoyagi, H.

    1993-04-01

    For the 1992 operating cycle of the SLAC Linear Collider (SLC), the polarized electron source (PES) during its maiden run successfully met the pulse intensity and overall efficiency requirements of the SLC. However, the polarization of the bulk GaAs cathode was low (∼27%) and the pulse-to-pulse stability was marginal. We have shown that adequate charge for the SLC can be extracted from a strained layer cathode having P e ∼80% even though the quantum efficiency (QE) is - beam stability. The performance of the PES during the 1993 SLC operating cycle with these and other improvements is discussed

  4. Charge Transport in Electrostatic Radiography.

    Science.gov (United States)

    Fallone, B. Gino

    A new analytical hyperbolic expression is presented to describe the full saturation curve of parallel-plate ionization chambers filled with air or with high atomic number gases at elevated pressures. It is shown that all parameters of the saturation curve expression can be calculated from one single measurement of ionization current at a given electric field and air gap thickness. Isothermal charge deposition on polymers to form stable foil electrets by using an apparatus resembling parallel-plate ionization chambers is reported. Charge carriers produced by irradiation of the sensitive air volume drift in the externally applied electric field and get trapped on the polymer surface to form electrets. The time dependence of the polarization and depolarization current densities, the effective electric field in the electret chamber, and the electret surface charge densities are presented for the radiation-induced foil electret and an excellent agreement is obtained with the measured electret data. The theory of linear systems is used to derive the electric field and potential in distance space in the electret chamber. The charging characteristics of ionographi latent images are discussed in terms of saturation characteristics of ionographic chambers. The minimum applied electric field needed for an optimized charge collection in the ionographic chamber is presented in terms of both the electret characteristic polarization time and the electret relaxation time. The feasibility of radiographic image subtraction based on electrostatic imaging techniques is demonstrated. Latent image charging at one polarity corresponding to the production of the primary image, and latent image discharging with the opposite chamber polarity, are used to create the final image representing the region of interest.

  5. The physics of polarization

    Science.gov (United States)

    Landi Degl'Innocenti, Egidio

    This course is intended to give a description of the basic physical concepts which underlie the study and the interpretation of polarization phenomena. Apart from a brief historical introduction (Sect. 1), the course is organized in three parts. A first part (Sects. 2 - 6) covers the most relevant facts about the polarization phenomena that are typically encountered in laboratory applications and in everyday life. In Sect. 2, the modern description of polarization in terms of the Stokes parameters is recalled, whereas Sect. 3 is devoted to introduce the basic tools of laboratory polarimetry, such as the Jones calculus and the Mueller matrices. The polarization phenomena which are met in the reflection and refraction of a beam of radiation at the separation surface between two dielectrics, or between a dielectric and a metal, are recalled in Sect. 4. Finally, Sect. 5 gives an introduction to the phenomena of dichroism and of anomalous dispersion and Sect. 6 summarizes the polarization phenomena that are commonly encountered in everyday life. The second part of this course (Sects. 7-14) deals with the description, within the formalism of classical physics, of the spectro-polarimetric properties of the radiation emitted by accelerated charges. Such properties are derived by taking as starting point the Liénard and Wiechert equations that are recalled and discussed in Sect. 7 both in the general case and in the non-relativistic approximation. The results are developed to find the percentage polarization, the radiation diagram, the cross-section and the spectral characteristics of the radiation emitted in different phenomena particularly relevant from the astrophysical point of view. The emission of a linear antenna is derived in Sect. 8. The other Sections are devoted to Thomson scattering (Sect. 9), Rayleigh scattering (Sect. 10), Mie scattering (Sect. 11), bremsstrahlung radiation (Sect. 12), cyclotron radiation (Sect. 13), and synchrotron radiation (Sect. 14

  6. A study of relaxation mechanisms in the A{sup 2}{Sigma}{sup +} state of nitric oxide by time resolved double resonant polarization spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Stampanoni-Panariello, A.; Bombach, R.; Hemmerling, B.; Hubschmid, W. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Double resonant polarization labeling spectroscopy is applied to detect nitric oxide in flames and to characterize rotational energy transfer and orientation changing collisions in its first excited electronic state. (author) 4 figs., 3 refs.

  7. Experimental and Theoretical Investigations of Glass Surface Charging Phenomena

    Science.gov (United States)

    Agnello, Gabriel

    Charging behavior of multi-component display-type (i.e. low alkali) glass surfaces has been studied using a combination of experimental and theoretical methods. Data obtained by way of a Rolling Sphere Test (RST), streaming/zeta potential and surface energy measurements from commercially available display glass surfaces (Corning EAGLE XGRTM and Lotus(TM) XT) suggest that charge accumulation is highly dependent on surface treatment (chemical and/or physical modification) and measurement environment, presumably through reactionary mechanisms at the surface with atmospheric moisture. It has been hypothesized that water dissociation, along with the corresponding hydroxylation of the glass surface, are important processes related to charging in glass-metal contact systems. Classical Molecular Dynamics (MD) simulations, in conjunction with various laboratory based measurements (RST, a newly developed ElectroStatic Gauge (ESG) and Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS)) on simpler Calcium AluminoSilicate (CAS) glass surfaces were used to further explore these phenomena. Analysis of simulated high-silica content (≥50%) (CAS) glass structures suggest that controlled variation of bulk chemistry can directly affect surface defect concentrations, such as non-bridging oxygen (NBO), which can be suitable high-energy sites for hydrolysis-type reactions to occur. Calculated NBO surface concentrations correlate well with charge based measurements on laboratory fabricated CAS surfaces. The data suggest that a directional/polar shift in contact-charge transfer occurs at low silica content (≤50%) where the highest concentrations of NBOs are observed. Surface charging sensitivity with respect to NBO concentration decreases as the relative humidity of the measurement environment increases; which should be expected as the highly reactive sites are progressively covered by liquid water layers. DRIFTS analysis of CAS powders expand on this analysis showing

  8. CHARGE syndrome

    Directory of Open Access Journals (Sweden)

    Prasad Chitra

    2006-09-01

    Full Text Available Abstract CHARGE syndrome was initially defined as a non-random association of anomalies (Coloboma, Heart defect, Atresia choanae, Retarded growth and development, Genital hypoplasia, Ear anomalies/deafness. In 1998, an expert group defined the major (the classical 4C's: Choanal atresia, Coloboma, Characteristic ears and Cranial nerve anomalies and minor criteria of CHARGE syndrome. Individuals with all four major characteristics or three major and three minor characteristics are highly likely to have CHARGE syndrome. However, there have been individuals genetically identified with CHARGE syndrome without the classical choanal atresia and coloboma. The reported incidence of CHARGE syndrome ranges from 0.1–1.2/10,000 and depends on professional recognition. Coloboma mainly affects the retina. Major and minor congenital heart defects (the commonest cyanotic heart defect is tetralogy of Fallot occur in 75–80% of patients. Choanal atresia may be membranous or bony; bilateral or unilateral. Mental retardation is variable with intelligence quotients (IQ ranging from normal to profound retardation. Under-development of the external genitalia is a common finding in males but it is less apparent in females. Ear abnormalities include a classical finding of unusually shaped ears and hearing loss (conductive and/or nerve deafness that ranges from mild to severe deafness. Multiple cranial nerve dysfunctions are common. A behavioral phenotype for CHARGE syndrome is emerging. Mutations in the CHD7 gene (member of the chromodomain helicase DNA protein family are detected in over 75% of patients with CHARGE syndrome. Children with CHARGE syndrome require intensive medical management as well as numerous surgical interventions. They also need multidisciplinary follow up. Some of the hidden issues of CHARGE syndrome are often forgotten, one being the feeding adaptation of these children, which needs an early aggressive approach from a feeding team. As the child

  9. Modeling of charge switching in ferroelectric capacitors.

    Science.gov (United States)

    Sun, Shunming; Kalkur, Thottam S

    2004-07-01

    To simulate charge switching in ferroelectric capacitors, a pair of exponential growth and decay currents is mapped to the process of polarization reversal. This is based on the fact that these exponential currents [i.e., i = I(m) e(t/tau) (t or = 0)], are completely specified by two constants I(m) and tau and each accommodates an integral charge Q = I(m) x tau. Equating this charge to the remanent spontaneous polarization allows for the modeling of switching current. For practical circuit simulations for charge switching, this modeling of switching current is simplified to an exponential decay current whose integral charge is set equal to the total reversed spontaneous polarization. This is because an exponential decay current can be conveniently implemented by charging a series resistor and capacitor (RC) circuit with a pulse-voltage source. The voltage transitions of the pulse source are associated with the polarization reversal and can be controlled with a noninverting Schmitt trigger that toggles at the positive and negative coercive voltages of a ferroelectric capacitor. The final circuit model incorporates such electrical and geometrical parameters as capacitance, remanent spontaneous polarization, coercive field, electrode area, and film thickness of a ferroelectric, thin-film capacitor.

  10. Electro-elastic fields due to a point charge in a flexoelectric medium

    Science.gov (United States)

    Sharma, Rajdeep

    2015-10-01

    Flexoelectricity provides a two-way connection between strain gradients and polarization that is pronounced at the nanoscale for isotropic materials which cannot link electromechanically via piezoelectricity. In this paper, the general equations for an isotropic, flexoelectric material were formulated, with contributions from strain gradients included. The electromechanical fields associated with a point charge in an infinite medium were derived, and results for GaAs were obtained. Our formulation yields two electromechanical length-scales, instead of one obtained from previous theories, and enables us to capture local fields accurately. Results from this paper provide insight into the electro-mechanical behavior of materials with charged defects.

  11. Electro-elastic fields due to a point charge in a flexoelectric medium

    International Nuclear Information System (INIS)

    Sharma, Rajdeep

    2015-01-01

    Flexoelectricity provides a two-way connection between strain gradients and polarization that is pronounced at the nanoscale for isotropic materials which cannot link electromechanically via piezoelectricity. In this paper, the general equations for an isotropic, flexoelectric material were formulated, with contributions from strain gradients included. The electromechanical fields associated with a point charge in an infinite medium were derived, and results for GaAs were obtained. Our formulation yields two electromechanical length-scales, instead of one obtained from previous theories, and enables us to capture local fields accurately. Results from this paper provide insight into the electro-mechanical behavior of materials with charged defects

  12. Measurement of the polarization for antiproton--proton annihilation into charged. pi. and K pairs between 1. 0 and 2. 2 GeV/c. [Differential cross sections, asymmetries

    Energy Technology Data Exchange (ETDEWEB)

    Carter, A.A.; Coupland, M.; Eisenhandler, E.

    1976-01-01

    The polarization parameter for the interactions anti pp ..-->.. ..pi../sup -/..pi../sup +/ and anti pp ..-->.. K/sup -/K/sup +/ was measured over essentially the full angular range at 11 momenta between 1.0 and 2.2 GeV/c. A proton target polarized perpendicular to the scattering plane was used. The experiment measured the angles and momenta of both outgoing particles using wire spark chambers and the field of the polarized target magnet. Between 1000 and 5300 ..pi../sup -/..pi../sup +/ events, and 140 and 1300 K/sup -/K/sup +/ events, were measured at each momentum. As a check, one obtained differential cross sections for anti pp ..-->.. ..pi../sup -/..pi../sup +/ which are in excellent agreement with previous results. The polarizations for both channels are very large and positive over much of the angular range. Preliminary results of a fit to the cross sections and asymmetries for anti pp ..-->.. ..pi../sup -/..pi../sup +/ show strong evidence for three new resonances at 2.14, 2.36, and 2.40 GeV/c/sup 2/.

  13. Photoemission mechanism of water-soluble silver nanoclusters: ligand-to-metal-metal charge transfer vs strong coupling between surface plasmon and emitters.

    Science.gov (United States)

    Chen, Yuting; Yang, Taiqun; Pan, Haifeng; Yuan, Yufeng; Chen, Li; Liu, Mengwei; Zhang, Kun; Zhang, Sanjun; Wu, Peng; Xu, Jianhua

    2014-02-05

    Using carboxylate-protected silver nanoclusters (Ag-carboxylate NCs) as a model, we separately investigated the contribution of the ligand shell and the metal core to understand the nature of photoluminescence of Ag NCs. A new Ag(0)NCs@Ag(I)-carboxylate complex core-shell structural model has been proposed. The emission from the Ag-carboxylate NCs could be attributed to ligand-to-metal-metal charge transfer from Ag(I)-carboxylate complexes (the oxygen atom in the carboxylate ligands to the Ag(I) ions) to the Ag atoms and subsequent radiative relaxation. Additionally, we found that the emission wavelength of the Ag NCs depends on the excitation wavelength implying a strong coupling between surface plasmon and emitter in Ag NCs. The strong coupling between the surface plasmon and the emitter determines the quantum yield and lifetime. The emission mechanism of Ag NCs and its relation to the organic templates and metal cores were clearly clarified. The results should stimulate additional experimental and theoretical research on the molecular-level design of luminescent metal probes for optoelectronics and other applications.

  14. Sources of polarized negative ions: progress and prospects

    International Nuclear Information System (INIS)

    Haeberli, W.

    1980-01-01

    A summary of recent progress in the art of producing beams of polarized ions is given. In all sources of polarized ions, one first produces (or selects) neutral atoms which are polarized in electron spin. Those types of sources which use a beam of thermal polarized hydrogen atoms are discussed. Progress made in the preparation of the atomic beam and the methods used to convert the neutral atoms to polarized ions is summarized. The second type of source discussed is based on fast (keV) polarized hydrogen atoms. Conversion to negative ions is very simple because one only needs to pass the fast atoms through a suitable charge exchange medium (gas or vapor). However, the production of the polarized atoms is more difficult in this case. The proposal to employ polarized alkali vapor to form a beam of polarized fast H atoms, where the polarized alkali atoms are produced either by an atomic beam apparatus or by optical pumping is discussed

  15. T cells' immunological synapses induce polarization of brain astrocytes in vivo and in vitro: a novel astrocyte response mechanism to cellular injury.

    Science.gov (United States)

    Barcia, Carlos; Sanderson, Nicholas S R; Barrett, Robert J; Wawrowsky, Kolja; Kroeger, Kurt M; Puntel, Mariana; Liu, Chunyan; Castro, Maria G; Lowenstein, Pedro R

    2008-08-20

    Astrocytes usually respond to trauma, stroke, or neurodegeneration by undergoing cellular hypertrophy, yet, their response to a specific immune attack by T cells is poorly understood. Effector T cells establish specific contacts with target cells, known as immunological synapses, during clearance of virally infected cells from the brain. Immunological synapses mediate intercellular communication between T cells and target cells, both in vitro and in vivo. How target virally infected astrocytes respond to the formation of immunological synapses established by effector T cells is unknown. Herein we demonstrate that, as a consequence of T cell attack, infected astrocytes undergo dramatic morphological changes. From normally multipolar cells, they become unipolar, extending a major protrusion towards the immunological synapse formed by the effector T cells, and withdrawing most of their finer processes. Thus, target astrocytes become polarized towards the contacting T cells. The MTOC, the organizer of cell polarity, is localized to the base of the protrusion, and Golgi stacks are distributed throughout the protrusion, reaching distally towards the immunological synapse. Thus, rather than causing astrocyte hypertrophy, antiviral T cells cause a major structural reorganization of target virally infected astrocytes. Astrocyte polarization, as opposed to hypertrophy, in response to T cell attack may be due to T cells providing a very focused attack, and thus, astrocytes responding in a polarized manner. A similar polarization of Golgi stacks towards contacting T cells was also detected using an in vitro allogeneic model. Thus, different T cells are able to induce polarization of target astrocytes. Polarization of target astrocytes in response to immunological synapses may play an important role in regulating the outcome of the response of astrocytes to attacking effector T cells, whether during antiviral (e.g. infected during HIV, HTLV-1, HSV-1 or LCMV infection), anti

  16. T cells' immunological synapses induce polarization of brain astrocytes in vivo and in vitro: a novel astrocyte response mechanism to cellular injury.

    Directory of Open Access Journals (Sweden)

    Carlos Barcia

    2008-08-01

    Full Text Available Astrocytes usually respond to trauma, stroke, or neurodegeneration by undergoing cellular hypertrophy, yet, their response to a specific immune attack by T cells is poorly understood. Effector T cells establish specific contacts with target cells, known as immunological synapses, during clearance of virally infected cells from the brain. Immunological synapses mediate intercellular communication between T cells and target cells, both in vitro and in vivo. How target virally infected astrocytes respond to the formation of immunological synapses established by effector T cells is unknown.Herein we demonstrate that, as a consequence of T cell attack, infected astrocytes undergo dramatic morphological changes. From normally multipolar cells, they become unipolar, extending a major protrusion towards the immunological synapse formed by the effector T cells, and withdrawing most of their finer processes. Thus, target astrocytes become polarized towards the contacting T cells. The MTOC, the organizer of cell polarity, is localized to the base of the protrusion, and Golgi stacks are distributed throughout the protrusion, reaching distally towards the immunological synapse. Thus, rather than causing astrocyte hypertrophy, antiviral T cells cause a major structural reorganization of target virally infected astrocytes.Astrocyte polarization, as opposed to hypertrophy, in response to T cell attack may be due to T cells providing a very focused attack, and thus, astrocytes responding in a polarized manner. A similar polarization of Golgi stacks towards contacting T cells was also detected using an in vitro allogeneic model. Thus, different T cells are able to induce polarization of target astrocytes. Polarization of target astrocytes in response to immunological synapses may play an important role in regulating the outcome of the response of astrocytes to attacking effector T cells, whether during antiviral (e.g. infected during HIV, HTLV-1, HSV-1 or LCMV

  17. Development of a high average current polarized electron source with long cathode operational lifetime

    Energy Technology Data Exchange (ETDEWEB)

    C. K. Sinclair; P. A. Adderley; B. M. Dunham; J. C. Hansknecht; P. Hartmann; M. Poelker; J. S. Price; P. M. Rutt; W. J. Schneider; M. Steigerwald

    2007-02-01

    Substantially more than half of the electromagnetic nuclear physics experiments conducted at the Continuous Electron Beam Accelerator Facility of the Thomas Jefferson National Accelerator Facility (Jefferson Laboratory) require highly polarized electron beams, often at high average current. Spin-polarized electrons are produced by photoemission from various GaAs-based semiconductor photocathodes, using circularly polarized laser light with photon energy slightly larger than the semiconductor band gap. The photocathodes are prepared by activation of the clean semiconductor surface to negative electron affinity using cesium and oxidation. Historically, in many laboratories worldwide, these photocathodes have had short operational lifetimes at high average current, and have often deteriorated fairly quickly in ultrahigh vacuum even without electron beam delivery. At Jefferson Lab, we have developed a polarized electron source in which the photocathodes degrade exceptionally slowly without electron emission, and in which ion back bombardment is the predominant mechanism limiting the operational lifetime of the cathodes during electron emission. We have reproducibly obtained cathode 1/e dark lifetimes over two years, and 1/e charge density and charge lifetimes during electron beam delivery of over 2?105???C/cm2 and 200 C, respectively. This source is able to support uninterrupted high average current polarized beam delivery to three experimental halls simultaneously for many months at a time. Many of the techniques we report here are directly applicable to the development of GaAs photoemission electron guns to deliver high average current, high brightness unpolarized beams.

  18. Inclusive quasielastic scattering of polarized electrons from polarized nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Amaro, J.E. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Center for Theoretical Physics]|[Universidad de Granada (Spain). Dept. de Fisica Moderna]|[Massachusetts Inst. of Tech., Cambridge, MA (United States). Lab. for Nuclear Science]|[Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Physics; Caballero, J.A. [Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Inst. de Estructura de la Materia]|[Sevilla Univ. (Spain). Dept. de Fisica Atomica, Molecular y Nuclear; Donnelly, T.W. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Center for Theoretical Physics]|[Massachusetts Inst. of Tech., Cambridge, MA (United States). Lab. for Nuclear Science]|[Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Physics; Moya de Guerra, E. [Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Inst. de Estructura de la Materia

    1996-12-23

    The inclusive quasielastic response functions that appear in the scattering of polarized electrons from polarized nuclei are computed and analyzed for several closed-shell-minus-one nuclei with special attention paid to {sup 39}K. Results are presented using two models for the ejected nucleon - when described by a distorted wave in the continuum shell model or by a plane wave in PWIA with on- and off-shell nucleons. Relativistic effects in kinematics and in the electromagnetic current have been incorporated throughout. Specifically, the recently obtained expansion of the electromagnetic current in powers only of the struck nucleon`s momentum is employed for the on-shell current and the effects of the first-order terms (spin-orbit and convection) are compared with the zeroth-order (charge and magnetization) contributions. The use of polarized inclusive quasielastic electron scattering as a tool for determining near-valence nucleon momentum distributions is discussed. (orig.).

  19. On polarization in biomembranes

    DEFF Research Database (Denmark)

    Zecchi, Karis Amata

    close to physiological conditions, making these effects biologically relevant. In this work, we consider the case of asymmetric membranes which can display spontaneous polarization in the absence of a field. Close to the phase transition, we find that the membrane displays piezoelectric, flexoelectric...... on different geometries point in the direction of a flexoelectric mechanism behind current rectification in lipid bilayers. Finally, we suggest that our updated equivalent circuit should be included in the interpretation of elctrophysiological data....

  20. An optically pumped polarized lithium ion source

    International Nuclear Information System (INIS)

    Myers, E.G.; Mendez, A.J.; Schmidt, B.G.; Kemper, K.W.

    1991-01-01

    A laser-optically-pumped polarized lithium ion source is being developed to provide beams of nuclear polarized 6,7 Li - for injection into the FSU tandem Van de Graaff-linac. Electro-optically modulated, circularly polarized light optically pumps a lithium atomic beam into a single magnetic substate, M 1 =1, M J =1/2. No inhomogeneous magnetic field (sextupole or quadrupole) is needed. Adiabatic rf transitions enable the polarization to be changed by transferring the population into different magnetic substates. Using a second electro-optic to modulate a second beam from the same laser, and Zeeman tuning, the polarization of the atomic beam is obtained by laser induced fluorescence. The polarized atomic beam is ionized to Li + and then charge exchanged to Li - . (orig.)

  1. Selective Complexation of Cyanide and Fluoride Ions with Ammonium Boranes: A Theoretical Study on Sensing Mechanism Involving Intramolecular Charge Transfer and Configurational Changes.

    Science.gov (United States)

    Bhat, Haamid R; Jha, Prakash C

    2017-05-18

    The anion binding selectivity and the recognition mechanism of two isomeric boranes, namely, 4-[bis(2,4,6-trimethylphenyl)boranyl]-N,N,N-trimethylaniline ([p-(Mes 2 B)C 6 H 4 (NMe 3 )] + , 1, where "Mes" represents mesitylene and "Me" represents methyl) and 2-[bis(2,4,6-trimethylphenyl)boranyl]-N,N,N-trimethylaniline ([o-(Mes 2 B)C 6 H 4 (NMe 3 )] + , 2) has been investigated using density functional theory (DFT) and time dependent-density functional theory (TD-DFT) methods. Natural population analysis indicates that the central boron atoms in 1 and 2 are the most active centers for nucleophilic addition of anions. The negative magnitude of free energy changes (ΔG) reveals that out of CN - , F - , Cl - , Br - , NO 3 - , and HSO 4 - only the binding of CN - and F - with 1 and 2 is thermodynamically feasible and spontaneous. In addition, the calculated binding energies reveal that the CN - is showing lesser binding affinity than F - both with 1 and 2, while other ions, viz. NO 3 - , HSO 4 - , Br - , and Cl - , either do not bind at all or show very insignificant binding energy. The first excited states (S 1 ) of 1 and 2 are shown to be the local excited states with π → σ* transition by frontier molecular orbital analysis, whereas fourth excited states (S 4 ) of 4-[bis(2,4,6-trimethylphenyl)boranyl]-N,N,N-trimethylaniline cyanide ([p-(Mes 2 B)C 6 H 4 (NMe 3 )] CN, 1CN, the cyano form of 1) and 4-[bis(2,4,6-trimethylphenyl)boranyl]-N,N,N-trimethylaniline fluoride ([p-(Mes 2 B)C 6 H 4 (NMe 3 )] F, 1F, the fluoro form of 1) and fifth excited state (S 5 ) of 2-[bis(2,4,6-trimethylphenyl)boranyl]-N,N,N-trimethylaniline fluoride ([o-(Mes 2 B)C 6 H 4 (NMe 3 )] F, 2F, the fluoro form of 2) are charge separation states that are found to be responsible for the intramolecular charge transfer (ICT) process. The synergistic effect of ICT and partial configuration changes induce fluorescence quenching in 1CN, 1F, and 2F after a significant internal conversion (IC) from S 4 and

  2. General load function in geo-mechanics: application to underground works; Fonction de charge generale en geomecanique: application aux travaux souterrains

    Energy Technology Data Exchange (ETDEWEB)

    Maiolino, S

    2006-04-15

    This work deals both with the behavioral and numerical aspects of the mechanical response of a rock massif to the digging out of a tunnel. The comparison between existing criteria has permitted to stress on some key points, like the dependence of the criterion to the average stress and the extension ratio. A load function, easily identifiable with tests, with regular and convex properties, has been proposed which allows to take into account the shape of the Mohr envelope of the criterion and the extension ratio. Regularized forms of Mohr-Coulomb and Hoek-Brown criteria can thus be achieved. The development of this new criterion has been completed by the proposal of a numerical charts method which greatly speeds up the resolution. For the proposed criterion, the physical problem is equivalent to a purely geometrical problem in polar coordinates in the plan. Numerical charts can thus be built which allow to find immediately the value of plastic deformations and to greatly reduce the processing time. Tunnel calculation methods have been the object of a bibliographic synthesis, specifying the domains and limitations of use of tunnel dimensioning methods used by engineers. The modeling of tunnels excavation has been performed with the stationary algorithm designed for the calculation of systems submitted to mobile loads. This algorithm has been adapted to integrate the new criterion and the numerical charts system. These tools have been validated using a real case study and data supplied by the French national agency of radioactive waste management (ANDRA) in the framework of the MODEX-REP European project (5. Euratom plan). The study of these data has permitted to define a rock wear variable, easily identifiable and allowing to parameterize the damaged rock criterion. (J.S.)

  3. Polarization transfer in weak pion production off the nucleon

    Science.gov (United States)

    Graczyk, Krzysztof M.; Kowal, Beata E.

    2018-01-01

    Polarization transfer (PT) observables in the single pion production induced by the charged current interaction of the neutrino with the nucleon are examined. The polarization components of the final nucleon and the charged lepton are calculated within two models for the pion production. The predictions are made for neutrino energy of the order of 1 GeV as well as for the T2K energy distribution. It is demonstrated that the PT observables, the degree of polarization and the polarization components of outgoing fermions, are sensitive to assumptions about the nonresonant background model. In particular it is shown that the normal components of the polarization of the outgoing nucleon and the lepton are determined by the interference between the resonant (RES) and nonresonant (NB) amplitudes. Moreover, the sign of the normal component of the polarization of the charged lepton is fixed by the relative sign between the RES and the NB amplitudes.

  4. Imaging ferroelectric domains via charge gradient microscopy enhanced by principal component analysis

    Directory of Open Access Journals (Sweden)

    Ehsan Nasr Esfahani

    2017-12-01

    Full Text Available Local domain structures of ferroelectrics have been studied extensively using various modes of scanning probes at the nanoscale, including piezoresponse force microscopy (PFM and Kelvin probe force microscopy (KPFM, though none of these techniques measure the polarization directly, and the fast formation kinetics of domains and screening charges cannot be captured by these quasi-static measurements. In this study, we used charge gradient microscopy (CGM to image ferroelectric domains of lithium niobate based on current measured during fast scanning, and applied principal component analysis (PCA to enhance the signal-to-noise ratio of noisy raw data. We found that the CGM signal increases linearly with the scan speed while decreases with the temperature under power-law, consistent with proposed imaging mechanisms of scraping and refilling of surface charges within domains, and polarization change across domain wall. We then, based on CGM mappings, estimated the spontaneous polarization and the density of surface charges with order of magnitude agreement with literature data. The study demonstrates that PCA is a powerful method in imaging analysis of scanning probe microscopy (SPM, with which quantitative analysis of noisy raw data becomes possible.

  5. Salmonella Taking Charge

    OpenAIRE

    Weigele, Bethany A.; Alto, Neal M.

    2010-01-01

    Pathogens develop creative ways to undermine host defenses. In this issue of Cell Host & Microbe, Bakowski et al. (2010) have unveiled a mechanism by which Salmonella evades lysosomal fusion by using a bacterial protein, SopB, that depletes the phagosomal membrane of negative charge.

  6. Hexagonal SiC with spatially separated active sites on polar and nonpolar facets achieving enhanced hydrogen production from photocatalytic water reduction.

    Science.gov (United States)

    Wang, Da; Liu, Ning; Guo, Zhongnan; Wang, Wenjun; Guo, Liwei; Yuan, Wenxia; Chen, Xiaolong

    2018-02-14

    Sufficient spatial separation of photo-generated electrons and holes plays a significant role in affecting the efficiency for solar energy conversion. Non-equivalent facets of a catalyst are known to possess different charge distribution properties. Here, we report that hexagonal 6H-SiC, a metal-free, environmentally friendly, polar semiconductor, exhibits different charge distribution and photocatalytic properties on naturally occurring Si-{0001} and {10-10} facets. Very strong selectivity of metals in situ photodeposition occurs in these two facets, demonstrating that the photo-excited electrons are assembled only on polar Si-{0001} facets while the holes are assembled on non-polar {10-10} facets. Consequently, reduction reactions occur only on the Si-{0001} facets with noble metals, and meantime oxidation occurs only in {10-10} with metal oxide. We show that the activity of photocatalytic water splitting is significantly enhanced by this kind of selective depositions resulting from the charge spatial separation. The underlying mechanism is investigated in terms of experimental evidence and first principles calculations. Our results demonstrate that the utilization of facets with opposite catalytic characteristics could be a feasible means to enhance the photocatalytic performance in diverse semiconducting materials. This is, in particular, of interest for polar semiconductors, as their particles always naturally occur in both polar facets and non-polar ones without needing facet engineering.

  7. Carbon nanotube fiber terahertz polarizer

    Energy Technology Data Exchange (ETDEWEB)

    Zubair, Ahmed [Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States); Tsentalovich, Dmitri E.; Young, Colin C. [Department of Chemical and Biomolecular Engineering, Rice University, Houston, Texas 77005 (United States); Heimbeck, Martin S. [Charles M. Bowden Laboratory, Aviation & Missile Research, Development, and Engineering Center (AMRDEC), Redstone Arsenal, Alabama 35898 (United States); Everitt, Henry O. [Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States); Charles M. Bowden Laboratory, Aviation & Missile Research, Development, and Engineering Center (AMRDEC), Redstone Arsenal, Alabama 35898 (United States); Pasquali, Matteo [Department of Chemical and Biomolecular Engineering, Rice University, Houston, Texas 77005 (United States); Department of Chemistry, Rice University, Houston, Texas 77005 (United States); Department of Materials Science and NanoEngineering, Rice University, Houston, Texas 77005 (United States); Kono, Junichiro, E-mail: kono@rice.edu [Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States); Department of Materials Science and NanoEngineering, Rice University, Houston, Texas 77005 (United States); Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States)

    2016-04-04

    Conventional, commercially available terahertz (THz) polarizers are made of uniformly and precisely spaced metallic wires. They are fragile and expensive, with performance characteristics highly reliant on wire diameters and spacings. Here, we report a simple and highly error-tolerant method for fabricating a freestanding THz polarizer with nearly ideal performance, reliant on the intrinsically one-dimensional character of conduction electrons in well-aligned carbon nanotubes (CNTs). The polarizer was constructed on a mechanical frame over which we manually wound acid-doped CNT fibers with ultrahigh electrical conductivity. We demonstrated that the polarizer has an extinction ratio of ∼−30 dB with a low insertion loss (<0.5 dB) throughout a frequency range of 0.2–1.1 THz. In addition, we used a THz ellipsometer to measure the Müller matrix of the CNT-fiber polarizer and found comparable attenuation to a commercial metallic wire-grid polarizer. Furthermore, based on the classical theory of light transmission through an array of metallic wires, we demonstrated the most striking difference between the CNT-fiber and metallic wire-grid polarizers: the latter fails to work in the zero-spacing limit, where it acts as a simple mirror, while the former continues to work as an excellent polarizer even in that limit due to the one-dimensional conductivity of individual CNTs.

  8. Using matrix effects as a probe for the study of the charge-transfer mechanism in inductively coupled plasma-atomic emission spectrometry

    International Nuclear Information System (INIS)

    Chan, George C.-Y.; Hieftje, Gary M.

    2004-01-01

    A novel method is presented for using matrix effects as a probe for the charge-transfer reaction between analyte atoms and argon ions in inductively coupled plasma-atomic emission spectrometry (ICP-AES). The method is based on the fact that the matrix effect caused by Ca or Ba depends on whether the studied analyte spectral line is from an ion or a neutral atom. Because the charge transfer reaction directly links atomic and high-energy ionic levels of the analyte, ionic spectral lines excited by charge transfer behave more like neutral-atom emission. As a result, quasi-resonant ionic emission lines exhibit a unique matrix effect character and can be easily identified. A commercial simultaneous full UV-Vis wavelength-coverage ICP spectrometer was used to study the responses of a large pool of spectral lines from a total of 22 elements in the presence of Na, Ca and Ba matrices. Candidate elements with charge-transfer character were thereby identified. The results match closely with those reported in the literature. The technique was further used to study charge-transfer reactions exhibited by the fourth-row metals from Sr to Sb. With the exception of Cd, Sr and Mo, all the other studied fourth-row metals showed positive evidence of excitation and ionization by charge-transfer from argon ion. While Sr showed negative results, the charge transfer-character of Cd and Mo could not be confirmed. It was also found that charge transfer can originate from other low-lying atomic analyte levels, in addition to the atomic ground state, and that charge-transfer reactions can occur at an appreciable rate even with a negative energy defect (i.e. negative ΔE) up to -1.6 eV

  9. Strategic Polarization.

    Science.gov (United States)

    Kalai, Adam; Kalai, Ehud

    2001-08-01

    In joint decision making, similarly minded people may take opposite positions. Consider the example of a marriage in which one spouse gives generously to charity while the other donates nothing. Such "polarization" may misrepresent what is, in actuality, a small discrepancy in preferences. It may be that the donating spouse would like to see 10% of their combined income go to charity each year, while the apparently frugal spouse would like to see 8% donated. A simple game-theoretic analysis suggests that the spouses will end up donating 10% and 0%, respectively. By generalizing this argument to a larger class of games, we provide strategic justification for polarization in many situations such as debates, shared living accommodations, and disciplining children. In some of these examples, an arbitrarily small disagreement in preferences leads to an arbitrarily large loss in utility for all participants. Such small disagreements may also destabilize what, from game-theoretic point of view, is a very stable equilibrium. Copyright 2001 Academic Press.

  10. PH-DEPENDENT PROTON PERMEABILITY OF THE PLASMA-MEMBRANE IN A REGULATING MECHANISM OF POLAR TRANSPORT THROUGH THE SUBMERGED LEAVES OF POTAMOGETON-LUCENS

    NARCIS (Netherlands)

    MIEDEMA, H; PRINS, HBA

    Recently it has been hypothesized that light-induced polarity in leaves of the submerged angiosperms Potamogeton and Elodea results in part from a pH-dependent change in the permeability of the plasma membrane for protons. It is assumed that the proton permeability increases at high pH. In this

  11. Polarization bremsstrahlung in α decay

    International Nuclear Information System (INIS)

    Amusia, M. Ya.; Zon, B. A.; Kretinin, I. Yu.

    2007-01-01

    A mechanism of formation of electromagnetic radiation that accompanies α decay and is associated with the emission of photons by electrons of atomic shells due to the scattering of α particles by these atoms (polarization bremsstrahlung) is proposed. It is shown that, when the photon energy is no higher than the energy of K electrons of an atom, polarization bremsstrahlung makes a significant contribution to the bremsstrahlung in α decay

  12. EDITORIAL: Non-polar and semipolar nitride semiconductors Non-polar and semipolar nitride semiconductors

    Science.gov (United States)

    Han, Jung; Kneissl, Michael

    2012-02-01

    topics including growth and heteroepitaxy, bulk GaN substrates, theory and modelling, optical properties, laser diodes and LEDs as well as transport properties and electronics. Farrell et al review materials and growth issues for high-performance non- and semipolar light-emitting devices, and Scholz provides an overview of heteroepitaxial growth of semipolar GaN. Okada et al review growth mechanisms of non- and semipolar GaN layers on patterned sapphire substrates, and Vennéguès discusses defect reduction methods for heteroepitaxially grown non- and semipolar III-nitride films. Leung et al explain how kinetic Wulff plots can be used to design and control non-polar and semipolar GaN heteroepitaxy, and a contribution by Sawaki et al explores the impurity incorporation in (1-101) GaN grown on Si substrates. In the area of bulk crystal growth Kucharski et al review non- and semipolar GaN substrates by ammonothermal growth, and Chichibu et al discuss the challenges for epitaxial growth of InGaN on free-standing m-plane GaN substrates. Calculation of semipolar orientations for wurtzitic semiconductor heterostructures and their application to nitrides and oxides are reviewed by Bigenwald et al, and Ito et al present an ab initio approach to reconstruction, adsorption, and incorporation on GaN surfaces. Finally, the theoretical description of non-polar and semipolar nitride semiconductor quantum-well structures is presented by Ahn et al. In a discussion of the optical properties, Kisin et al discuss the effect of the quantum well population on the optical characteristics of polar, semipolar and non-polar III-nitride light emitters, and Jönen et al investigate the indium incorporation and optical properties of non- and semipolar GaInN QW structures. Wernicke et al explore the emission wavelength of polar, non-polar, and semipolar InGaN quantum wells and the incorporation of indium. In a contribution by Melo et al, the gain in polar and non-polar/semipolar gallium

  13. Crack growth and fracture toughness of amorphous Li-Si anodes: Mechanisms and role of charging/discharging studied by atomistic simulations

    Science.gov (United States)

    Khosrownejad, S. M.; Curtin, W. A.

    2017-10-01

    Fracture is the main cause of degradation and capacity fading in lithiated silicon during cycling. Experiments on the fracture of lithiated silicon show conflicting results, and so mechanistic models can help interpret experiments and guide component design. Here, large-scale K-controlled atomistic simulations of crack propagation (R-curve KI vs. Δa) are performed at LixSi compositions x = 0.5 , 1.0 , 1.5 for as-quenched/relaxed samples and at x = 0.5 , 1.0 for samples created by discharging from higher Li compositions. In all cases, the fracture mechanism is void nucleation, growth, and coalescence. In as-quenched materials, with increasing Li content the plastic flow stress and elastic moduli decrease but void nucleation and growth happen at smaller stress, so that the initial fracture toughness KIc ≈ 1.0 MPa√{ m} decreases slightly but the initial fracture energy JIc ≈ 10.5J/m2 is similar. After 10 nm of crack growth, the fracture toughnesses increase and become similar at KIc ≈ 1.9 MPa√{ m} across all compositions. Plane-strain equi-biaxial expansion simulations of uncracked samples provide complementary information on void nucleation and growth. The simulations are interpreted within the framework of Gurson model for ductile fracture, which predicts JIc = ασy D where α ≃ 1 and D is the void spacing, and good agreement is found. In spite of flowing plastically, the fracture toughness of LixSi is low because voids nucleate within nano-sized distances ahead of the crack (D ≈ 1nm). Scaling simulation results to experimental conditions, reasonable agreement with experimentally-estimated fracture toughnesses is obtained. The discharging process facilitates void nucleation but decreases the flow stress (as shown previously), leading to enhanced fracture toughness at all levels of crack growth. Therefore, the fracture behavior of lithiated silicon at a given composition is not a material property but instead depends on the history of charging

  14. XPS study of Li/Nb ratio in LiNbO{sub 3} crystals. Effect of polarity and mechanical processing on LiNbO{sub 3} surface chemical composition

    Energy Technology Data Exchange (ETDEWEB)

    Skryleva, E.A., E-mail: easkryleva@gmail.com; Kubasov, I.V., E-mail: kubasov.ilya@gmail.com; Kiryukhantsev-Korneev, Ph.V., E-mail: kiruhancev-korneev@yandex.ru; Senatulin, B.R., E-mail: borisrs@yandex.ru; Zhukov, R.N., E-mail: rom_zhuk@mail.ru; Zakutailov, K.V., E-mail: zakkonst@gmail.com; Malinkovich, M.D., E-mail: malinkovich@yandex.ru; Parkhomenko, Yu.N., E-mail: parkh@rambler.ru

    2016-12-15

    Highlights: • XPS Li/Nb ratio measurement uncertainty in LNbO3 specimens was obtained. • The effect of polarization on surface chemistry was observed only on cleaves. • Li/Nb ratio on positive cleave surface is higher than on negative one. • The positive cleave surface adsorbs fluorine more efficiently than negative one. • Mechanical processing of crystals reduces surface Li/Nb. - Abstract: Different sections of congruent lithium niobate (CLN) crystals have been studied using X-ray photoelectron spectroscopy (XPS). We have developed a method for measuring the lithium-to-niobium atomic ratio Li/Nb from the ratio of the Li1s and Nb4s spectral integral intensities with an overall error of within 8 %. Polarity and mechanical processing affect the Li/Nb ratio on CLN crystal surfaces. The Li/Nb ratio is within the tolerance (0.946 ± 0.074) on the negative cleave surface Z, and there is excess lithium (Li/Nb = 1.25 ± 0.10) on the positive surface. The positive surfaces of the 128° Y cut plates after long exposure to air exhibit LiOH formation indications (obvious lithium excess, higher Li1s spectral binding energy and a wide additional peak in the O1s spectrum produced by nonstructural oxygen). XPS and glow discharge optical electron spectroscopy showed that mechanical processing of differently oriented crystals (X, Z and 128° Y) and different polarities dramatically reduces the Li/Nb ratio. In situ fluorine adsorption experiments revealed the following regularities: fluorine adsorption only occurred on crystal cleaves and was not observed for mechanically processed specimens. Positive cleave surfaces have substantially higher fluorine adsorption capacity compared to negative ones.

  15. Dynamics of a charged particle in a circularly polarized travelling electromagnetic wave. Self-consistent model for the wave-particle dynamical interaction; Dynamique d'une particule chargee dans un champ electromagnetique polarise circulairement. Traitement auto-consistant de l'interaction entre plusieurs particules et l'onde

    Energy Technology Data Exchange (ETDEWEB)

    Bourdier, A

    1999-07-01

    This work concerns mainly the dynamics of a charged particle in an electromagnetic wave. It is a first step in elaborating a more general model permitting to predict the wave-particle interaction. We show how deriving a first integral gives an idea on how to create an electron current in a cold electron plasma. We present results which can be used to test the 2D and 3D Vlasov-Maxwell codes being built up in CEA-DAM. These codes will allow the calcination of the magnetic field created by an electromagnetic wave like the one due to the inverse Faraday effect when a circularly polarized wave drives the electrons of a plasma into circular orbits. (author)

  16. Model of the motion of a charged particle into a plasma during the interaction of an electromagnetic pulse elliptically polarized propagating in the direction of a static and homogeneous magnetic field; Modelo del movimiento de una particula cargada en un plasma durante la interaccion de un pulso electromagnetico elipticamente polarizado propagandose en la direccion de un campo magnetico estatico y homogeneo

    Energy Technology Data Exchange (ETDEWEB)

    Gomez R, F. [UAEM, A.P. 2-139, 50000 Toluca, Estado de Mexico (Mexico); Ondarza R, R. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2004-07-01

    An analytical model for the description of the movement of a charged particle in the interaction of an electromagnetic pulse elliptically polarized propagating along of a static and homogeneous external magnetic field in a plasma starting from the force equation is presented. The method allows to express the solution in terms of the invariant phase, obtaining differential equations for the trajectory of the accelerated particle by means of an electromagnetic pulse of arbitrary amplitude and modulated by an encircling Gaussian. The numerical solutions reported in this work can find varied applications, for example in the physics of the interaction laser-plasma, in the acceleration of particles, in hot plasma and in radiative effects. (Author)

  17. Motion model for a charged particle in a plasma during the interaction of an electromagnetic pulse elliptically polarized propagating in the direction of a static and homogeneous magnetic field; Modelo del movimiento de una particula cargada en un plasma durante la interaccion de un pulso electromagnetico elipticamente polarizado propagandose en la direccion de un campo magnetico estatico y homogeneo

    Energy Technology Data Exchange (ETDEWEB)

    Gomez R, F. [UAEM, Facultad de Ciencias, 50000 Toluca, Estado de Mexico (Mexico); Ondarza R, R. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2004-07-01

    An analytic model is presented for the description of the motion of a charged particle in the interaction of an elliptically electromagnetic pulse polarized propagating along a static and homogeneous external magnetic field in a plasma starting from the force equation. The method allows to express the solution in terms of the invariant phase, obtaining differential equations for the trajectory of the accelerated particle by means of an electromagnetic pulse of arbitrary and modulated width by an encircling Gaussian. The numerical solutions reported in this work can find varied applications, for example in the physics of the interaction laser-plasma, in the acceleration of particles, in hot plasma and in radioactive effects. (Author)

  18. Brane polarization is no cure for tachyons

    OpenAIRE

    Bena, Iosif; Kuperstein, Stanislav

    2015-01-01

    Anti-M2 and anti-D3 branes placed in regions with charges dissolved in fluxes have a tachyon in their near-horizon region, which causes these branes to repel each other. If the branes are on the Coulomb branch this tachyon gives rise to a runaway behavior, but when the branes are polarized into five-branes this tachyon only appears to lower the energy of the polarized branes, without affecting its stability. We analyze brane polarization in the presence of a brane-brane-repelling tachyon and ...

  19. Precessing deuteron polarization

    International Nuclear Information System (INIS)

    Sitnik, I.M.; Volkov, V.I.; Kirillov, D.A.; Piskunov, N.M.; Plis, Yu.A.

    2002-01-01

    The feasibility of the acceleration in the Nuclotron of deuterons polarized in the horizontal plane is considered. This horizontal polarization is named precessing polarization. The effects of the main magnetic field and synchrotron oscillations are included. The precessing polarization is supposed to be used in studying the polarization parameters of the elastic dp back-scattering and other experiments

  20. Features of the ESI mechanism that affect the observation of multiply charged noncovalent protein complexes and the determination of the association constant by the titration method.

    Science.gov (United States)

    Peschke, Michael; Verkerk, Udo H; Kebarle, Paul

    2004-10-01

    Several factors, attributable to the ESIMS mechanism, that can affect the assumptions of the titration method are examined: (1) The assumption that the concentrations in solution of the protein P, the ligand L, and the complex PL are proportional to the respective ion intensities observed with ESIMS, is examined with experiments in which ion intensities of two non-interacting proteins are compared with the respective concentrations. The intensities are found to be approximately proportional to the concentrations. The proportionality factors are found to increase as the mass of the protein is decreased. Very small proteins have much higher intensities. The results suggest that it is preferable to use only the intensity ratio of PL and P, whose masses are very close to each other when L is small, to determine the association constant KA in solution. (2) From the charge residue model (CRM) one expects that the solution will experience a very large increase of concentration due to evaporation of the precursor droplets, before the proteins P and PL are produced in the gas phase. This can shift the equilibrium in the droplets: P + L = PL, towards PL. Analysis of the droplet evaporation history shows that such a shift is not likely, because the time of droplet evolution is very short, only several micros, and the equilibrium relaxation time is much longer. (3) The droplet history shows that unreacted P and L can be often present together in the same droplet. On complete evaporation of such droplets L will land on P leading to PL and this effect will lead to values of KA that are too high. However, it is argued that mostly accidental, weakly bonded, complexes will form and these will dissociate in the clean up stages (heated transfer capillary and CAD region). Thus only very small errors are expected due to this cause. (4) Some PL complexes may have bonding that is too weak in the gas phase even though they have KA values in solution that predict high solution PL yields

  1. Polarized Photocathode R&D for Future Linear Collliders

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, F; Brachmann, A.; Maruyama, T.; Sheppard, J.C.; /SLAC

    2009-01-23

    It is a challenge to generate full charge electrons from the electron sources without compromising polarization for the proposed ILC and CLIC. It is essential to advance polarized photocathodes to meet the requirements. SLAC has worldwide unique dedicated test facilities, Cathode Test System and dc-Gun Test Laboratory, to fully characterize polarized photocathodes. Recent systematic measurements on a strained-well InAlGaAs/AlGaAs cathode at the facilities show that 87% polarization and 0.3% QE are achieved. The QE can be increased to {approx}1.0% with atomic hydrogen cleaning. The surface charge limit at a very low current intensity and the clear dependence of the polarization on the surface charge limit are observed for the first time. On-going programs to develop photocathodes for the ILC and CLIC are briefly introduced.

  2. Anodic Concentration Polarization in SOFCs

    Energy Technology Data Exchange (ETDEWEB)

    Williford, Rick E.; Chick, Lawrence A.; Maupin, Gary D.; Simner, Steve P.; Stevenson, Jeffry W.; Khaleel, Mohammad A.; Wachsman, ED, et al

    2003-08-01

    Concentration polarization is important because it determines the maximum power output of a solid oxide fuel cell (SOFC) at high fuel utilization. Anodic concentration polarization occurs when the demand for reactants exceeds the capacity of the porous ceramic anode to supply them by gas diffusion mechanisms. High tortuosities (bulk diffusion resistances) are often assumed to explain this behavior. However, recent experiments show that anodic concentration polarization originates in the immediate vicinity of the reactive triple phase boundary (TPB) sites near the anode/electrolyte interface. A model is proposed to describe how concentration polarization is controlled by two localized phenomena: competitive adsorption of reactants in areas adjacent to the reactive TPB sites, followed by relatively slow surface diffusion to the reactive sites. Results suggest that future SOFC design improvements should focus on optimization of the reactive area, adsorption, and surface diffusion at the anode/electrolyte interface.

  3. Polare maskuliniteter

    Directory of Open Access Journals (Sweden)

    Marit Anne Hauan

    2012-05-01

    Full Text Available In this paper my aim is to read and understand the journal of Gerrit de Veer from the last journey of William Barents to the Arctic Regions in 1596 and the journal of captain Junge on his hunting trip from Tromsø to Svalbard in 1834.It is nearly 240 years between this to voyages. The first journal is known as the earliest report from the arctic era. Gerrit de Veer adds instructive copper engravings to his text and give us insight in the crews meeting with this new land. Captain Junges journal is found together with his dead crew in a house in a fjord nearby Ny-Ålesund and has no drawings, but word. Both of these journals may be read as sources of the knowledge and understanding of the polar region. They might also unveil the ideas of how to deal with and survive under the challenges that is given. In addition one can ask if the sources can tell us more about how men describe their challenges. Can the way they expressed themselves in the journals give us an understanding of masculinity? And not least help us to create good questions of the change in the ideas of masculinities which is said to follow the change in understanding of the wilderness.

  4. Charge Storage, Conductivity and Charge Profiles of Insulators as Related to Spacecraft Charging

    Science.gov (United States)

    Dennison, J. R.; Swaminathan, Prasanna; Frederickson, A. R.

    2004-01-01

    Dissipation of charges built up near the surface of insulators due to space environment interaction is central to understanding spacecraft charging. Conductivity of insulating materials is key to determine how accumulated charge will distribute across the spacecraft and how rapidly charge imbalance will dissipate. To understand these processes requires knowledge of how charge is deposited within the insulator, the mechanisms for charge trapping and charge transport within the insulator, and how the profile of trapped charge affects the transport and emission of charges from insulators. One must consider generation of mobile electrons and holes, their trapping, thermal de-trapping, mobility and recombination. Conductivity is more appropriately measured for spacecraft charging applications as the "decay" of charge deposited on the surface of an insulator, rather than by flow of current across two electrodes around the sample. We have found that conductivity determined from charge storage decay methods is 102 to 104 smaller than values obtained from classical ASTM and IEC methods for a variety of thin film insulating samples. For typical spacecraft charging conditions, classical conductivity predicts decay times on the order of minutes to hours (less than typical orbit periods); however, the higher charge storage conductivities predict decay times on the order of weeks to months leading to accumulation of charge with subsequent orbits. We found experimental evidence that penetration profiles of radiation and light are exceedingly important, and that internal electric fields due to charge profiles and high-field conduction by trapped electrons must be considered for space applications. We have also studied whether the decay constants depend on incident voltage and flux or on internal charge distributions and electric fields; light-activated discharge of surface charge to distinguish among differing charge trapping centers; and radiation-induced conductivity. Our

  5. Charge accumulation in lossy dielectrics: a review

    DEFF Research Database (Denmark)

    Rasmussen, Jørgen Knøster; McAllister, Iain Wilson; Crichton, George C

    1999-01-01

    At present, the phenomenon of charge accumulation in solid dielectrics is under intense experimental study. Using a field theoretical approach, we review the basis for charge accumulation in lossy dielectrics. Thereafter, this macroscopic approach is applied to planar geometries such that the mat......At present, the phenomenon of charge accumulation in solid dielectrics is under intense experimental study. Using a field theoretical approach, we review the basis for charge accumulation in lossy dielectrics. Thereafter, this macroscopic approach is applied to planar geometries...... such that the material parameters which influence charge accumulation are clearly identified; viz. the conductivity, permittivity and dimensions of the insulating media. The two former parameters, together with the applied voltage, govern both the magnitude and polarity of the accumulated charge....

  6. Oppositely charged colloids out of equilibrium

    Science.gov (United States)

    Vissers, T.

    2010-11-01

    Colloids are particles with a size in the range of a few nanometers up to several micrometers. Similar to atomic and molecular systems, they can form gases, liquids, solids, gels and glasses. Colloids can be used as model systems because, unlike molecules, they are sufficiently large to be studied directly with light microscopy and move sufficiently slow to study their dynamics. In this thesis, we study binary systems of polymethylmethacrylate (PMMA) colloidal particles suspended in low-polar solvent mixtures. Since the ions can still partially dissociate, a surface charge builds up which causes electrostatic interactions between the colloids. By carefully tuning the conditions inside the suspension, we make two kinds of particles oppositely charged. To study our samples, we use Confocal Laser Scanning Microscopy (CLSM). The positively and negatively charged particles can be distinguished by a different fluorescent dye. Colloids constantly experience a random motion resulting from random kicks of surrounding solvent molecules. When the attractions between the oppositely charged particles are weak, the particles can attach and detach many times and explore a lot of possible configurations and the system can reach thermodynamic equilibrium. For example, colloidal ‘ionic’ crystals consisting of thousands to millions of particles can form under the right conditions. When the attractions are strong, the system can become kinetically trapped inside a gel-like state. We observe that when the interactions change again, crystals can even emerge again from this gel-like phase. By using local order parameters, we quantitatively study the crystallization of colloidal particles and identify growth defects inside the crystals. We also study the effect of gravity on the growth of ionic crystals by using a rotating stage. We find that sedimentation can completely inhibit crystal growth and plays an important role in crystallization from the gel-like state. The surface

  7. Depth profiling of oxide-trapped charges in 6H-SiC MOS structures by slant etching method

    Energy Technology Data Exchange (ETDEWEB)

    Saitoh, Kazunari; Takahashi, Yoshihiro; Ohnishi, Kazunori [Nihon Univ., Tokyo (Japan). Coll. of Science and Technology; Yoshikawa, Masahito; Ohshima, Takeshi; Itoh, Hisayoshi; Nashiyama, Isamu

    1997-03-01

    In this paper, we propose a method to evaluate the depth profile of trapped charges in an oxide layer on SiC. Using this method, 6H-SiC MOS structures with different oxide thickness were fabricated on the same substrate under the same oxidation condition, and the depth profile of oxide-trapped charges before and after {sup 60}Co-gamma ray irradiation were obtained. It is found, from the depth profiling, that the trapping mechanism of electrons and holes in the oxide strongly depends on the bias polarity during irradiation, and these charges are trapped near 6H-SiC/SiO{sub 2} interface. We believe that this method is very useful for estimation of the oxide-trapped charges in 6H-SiC MOS structures. (author)

  8. Extending the strong-field approximation of high-order harmonic generation to polar molecules: gating mechanisms and extension of the harmonic cutoff

    DEFF Research Database (Denmark)

    Etches, Adam; Madsen, Lars Bojer

    2010-01-01

    Polar molecules such as CO are interesting target systems for high-order harmonic generation (HHG) as they can be oriented with current laser techniques, thus allowing the study of systems without inversion symmetry. However, the asymmetry of the molecule also means that the molecular orbitals...... (enhanced) every other half-cycle. We show that the Stark shift weakens the strength of system-induced gating and also determines the relative contribution from opposite orientations in field-induced gating. Finally, we propose a novel scheme for extending the high-order harmonic cutoff by letting the two...

  9. Unraveling the Charge Extraction Mechanism of Perovskite Solar Cells Fabricated with Two-Step Spin Coating: Interfacial Energetics between Methylammonium Lead Iodide and C60.

    Science.gov (United States)

    Shin, Dongguen; Kang, Donghee; Jeong, Junkyeong; Park, Soohyung; Kim, Minju; Lee, Hyunbok; Yi, Yeonjin

    2017-11-02

    In organolead halide perovskite solar cells (PSCs), interfacial properties between the perovskite and charge transport layers are the critical factors governing charge extraction efficiency. In this study, the effect of interfacial energetics between two-step spin-coated methylammonium lead iodide (MAPbI 3 ) with different methylammonium iodide (MAI) concentrations and C 60 on the charge extraction efficiency is investigated. The electronic structures of perovskite films are significantly varied by the MAI concentrations due to the changes in the residual precursor and MA + defect content. As compared to the optimum PSCs with 25 mg mL -1 MAI, PSCs with other MAI concentrations show significantly lower power conversion efficiencies and severe hysteresis. The energy level alignment at the C 60 /MAPbI 3 interface determined by ultraviolet and inverse photoelectron spectroscopy measurements reveals the origin of distinct differences in device performances. The conduction band offset at the C 60 /MAPbI 3 interface plays a crucial role in efficient charge extraction in PSCs.

  10. Construction of a unique metric in quasi-Hermitian quantum mechanics: Nonexistence of the charge operator in a 2 x 2 matrix model (vol 640, pg 52, 2006)

    Czech Academy of Sciences Publication Activity Database

    Znojil, Miloslav; Geyer, HB.

    2007-01-01

    Roč. 649, 5-6 (2007), s. 494-494 ISSN 0370-2693 R&D Projects: GA ČR GA202/07/1307 Institutional research plan: CEZ:AV0Z10480505 Keywords : metrics * quasi-Hermitian * charge Subject RIV: BE - Theoretical Physics Impact factor: 4.189, year: 2007

  11. Safeguarding Digital Library Contents: Charging for Online Content.

    Science.gov (United States)

    Herzberg, Amir

    1998-01-01

    Investigates the need for mechanisms for charging by digital libraries and other providers of online content, in particular for micropayments, i.e., charging for small amounts. The SSL (Secure Socket Layer) and SET (Secure Electronic Transactions) protocols for charge card payments and the MiniPay micropayment mechanism for charging small amounts…

  12. Dynamics of Current, Charge and Mass

    Directory of Open Access Journals (Sweden)

    Eisenberg Bob

    2017-10-01

    Full Text Available Electricity plays a special role in our lives and life. The dynamics of electrons allow light to flow through a vacuum. The equations of electron dynamics are nearly exact and apply from nuclear particles to stars. These Maxwell equations include a special term, the displacement current (of a vacuum. The displacement current allows electrical signals to propagate through space. Displacement current guarantees that current is exactly conserved from inside atoms to between stars, as long as current is defined as the entire source of the curl of the magnetic field, as Maxwell did.We show that the Bohm formulation of quantum mechanics allows the easy definition of the total current, and its conservation, without the dificulties implicit in the orthodox quantum theory. The orthodox theory neglects the reality of magnitudes, like the currents, during times that they are not being explicitly measured.We show how conservation of current can be derived without mention of the polarization or dielectric properties of matter. We point out that displacement current is handled correctly in electrical engineering by ‘stray capacitances’, although it is rarely discussed explicitly. Matter does not behave as physicists of the 1800’s thought it did. They could only measure on a time scale of seconds and tried to explain dielectric properties and polarization with a single dielectric constant, a real positive number independent of everything. Matter and thus charge moves in enormously complicated ways that cannot be described by a single dielectric constant,when studied on time scales important today for electronic technology and molecular biology. When classical theories could not explain complex charge movements, constants in equations were allowed to vary in solutions of those equations, in a way not justified by mathematics, with predictable consequences. Life occurs in ionic solutions where charge is moved by forces not mentioned or described in the

  13. Polarizing PVC--A Discrepant Event

    Science.gov (United States)

    Headly, David; Karabatek, Mohamed

    2016-01-01

    This article describes an experiment teaching polarization phenomena and the Triboelectric Series in a unit on electrostatics. Using rods (2-3 ft in length) made from wood, aluminum, PVC, and Plexiglas on an inverted watch glass, these items demonstrated to the class how a party balloon rubbed with fake rabbit fur (charging the balloon negative)…

  14. Charge transfer and momentum exchange in exospheric D-H(+) and H-D(+) collisions

    Science.gov (United States)

    Hodges, R. R., Jr.; Breig, E. L.

    1993-01-01

    Mechanisms that control the escape of deuterium from planetary exospheres include the acceleration of D(+) in the polar wind, and the production of suprathermal D atoms through nonthermal collisions. In this paper we examine the effects of neutral-ion interactions involving deuterium and hydrogen on the velocity distribution of neutral D. A two-center scattering approximation is used as the basis for calculations of the differential cross sections for charge transfer and elastic scatter in collision of H with D(+) and of D with H(+) for ionosphere-exosphere collision energies below 10 e V. These data are used to derive temperature dependent rate coefficients for the charge transfer branches of these interactions, and to determine the effects of ion-neutral temperature differences on the rate of generation of suprathermal D through charge transfer and elastic scatter.

  15. Novel electronic ferroelectricity in an organic charge-order insulator investigated with terahertz-pump optical-probe spectroscopy

    Science.gov (United States)

    Yamakawa, H.; Miyamoto, T.; Morimoto, T.; Yada, H.; Kinoshita, Y.; Sotome, M.; Kida, N.; Yamamoto, K.; Iwano, K.; Matsumoto, Y.; Watanabe, S.; Shimoi, Y.; Suda, M.; Yamamoto, H. M.; Mori, H.; Okamoto, H.

    2016-01-01

    In electronic-type ferroelectrics, where dipole moments produced by the variations of electron configurations are aligned, the polarization is expected to be rapidly controlled by electric fields. Such a feature can be used for high-speed electric-switching and memory devices. Electronic-type ferroelectrics include charge degrees of freedom, so that they are sometimes conductive, complicating dielectric measurements. This makes difficult the exploration of electronic-type ferroelectrics and the understanding of their ferroelectric nature. Here, we show unambiguous evidence for electronic ferroelectricity in the charge-order (CO) phase of a prototypical ET-based molecular compound, α-(ET)2I3 (ET:bis(ethylenedithio)tetrathiafulvalene), using a terahertz pulse as an external electric field. Terahertz-pump second-harmonic-generation(SHG)-probe and optical-reflectivity-probe spectroscopy reveal that the ferroelectric polarization originates from intermolecular charge transfers and is inclined 27° from the horizontal CO stripe. These features are qualitatively reproduced by the density-functional-theory calculation. After sub-picosecond polarization modulation by terahertz fields, prominent oscillations appear in the reflectivity but not in the SHG-probe results, suggesting that the CO is coupled with molecular displacements, while the ferroelectricity is electronic in nature. The results presented here demonstrate that terahertz-pump optical-probe spectroscopy is a powerful tool not only for rapidly controlling polarizations, but also for clarifying the mechanisms of ferroelectricity. PMID:26864779

  16. Tunable charge transfer properties in metal-phthalocyanine heterojunctions

    Science.gov (United States)

    Siles, P. F.; Hahn, T.; Salvan, G.; Knupfer, M.; Zhu, F.; Zahn, D. R. T.; Schmidt, O. G.

    2016-04-01

    Organic materials such as phthalocyanine-based systems present a great potential for organic device applications due to the possibility of integrating films of different organic materials to create organic heterostructures which combine the electrical capabilities of each material. This opens the possibility to precisely engineer and tune new electrical properties. In particular, similar transition metal phthalocyanines demonstrate hybridization and charge transfer properties which could lead to interesting physical phenomena. Although, when considering device dimensions, a better understanding and control of the tuning of the transport properties still remain in the focus of research. Here, by employing conductive atomic force microscopy techniques, we provide an insight about the nanoscale electrical properties and transport mechanisms of MnPc and fluorinated phthalocyanines such as F16CuPc and F16CoPc. We report a transition from typical diode-like transport mechanisms for pure MnPc thin films to space-charge-limited current transport regime (SCLC) for Pc-based heterostructures. The controlled addition of fluorinated phthalocyanine also provides highly uniform and symmetric-polarized transport characteristics with conductance enhancements up to two orders of magnitude depending on the polarization. We present a method to spatially map the mobility of the MnPc/F16CuPc structures with a nanoscale resolution and provide theoretical calculations to support our experimental findings. This well-controlled nanoscale tuning of the electrical properties for metal transition phthalocyanine junctions stands as key step for future phthalocyanine-based electronic devices, where the low dimension charge transfer, mediated by transition metal atoms could be intrinsically linked to a transfer of magnetic moment or spin.Organic materials such as phthalocyanine-based systems present a great potential for organic device applications due to the possibility of integrating films of

  17. PolarHub: A Global Hub for Polar Data Discovery

    Science.gov (United States)

    Li, W.

    2014-12-01

    This paper reports the outcome of a NSF project in developing a large-scale web crawler PolarHub to discover automatically the distributed polar dataset in the format of OGC web services (OWS) in the cyberspace. PolarHub is a machine robot; its goal is to visit as many webpages as possible to find those containing information about polar OWS, extract this information and store it into the backend data repository. This is a very challenging task given huge data volume of webpages on the Web. Three unique features was introduced in PolarHub to make it distinctive from earlier crawler solutions: (1) a multi-task, multi-user, multi-thread support to the crawling tasks; (2) an extensive use of thread pool and Data Access Object (DAO) design patterns to separate persistent data storage and business logic to achieve high extendibility of the crawler tool; (3) a pattern-matching based customizable crawling algorithm to support discovery of multi-type geospatial web services; and (4) a universal and portable client-server communication mechanism combining a server-push and client pull strategies for enhanced asynchronous processing. A series of experiments were conducted to identify the impact of crawling parameters to the overall system performance. The geographical distribution pattern of all PolarHub identified services is also demonstrated. We expect this work to make a major contribution to the field of geospatial information retrieval and geospatial interoperability, to bridge the gap between data provider and data consumer, and to accelerate polar science by enhancing the accessibility and reusability of adequate polar data.

  18. The ILC polarized electron source

    CERN Document Server

    Brachmann, Axel; Garwin, Edward; Kirby, Robert; Luh Dah An; Maruyama, Takashi; Prepost, Richard; Schultz, David; Sheppard, John

    2005-01-01

    The SLC polarized electron source (PES) can meet the expected requirements of the International Linear Collider (ILC) for polarization, charge and lifetime. However, experience with newer and successful PES designs at JLAB, Mainz and elsewhere can be incorporated into a first-generation ILC source that will emphasize reliability and stability without compromising the photocathode performance. The long pulse train for the ILC may introduce new challenges for the PES, and in addition more reliable and stable operation of the PES may be achievable if appropriate R&D is carried out for higher voltage operation and for a simpler load-lock system. The outline of the R&D program currently taking shape at SLAC and elsewhere is discussed. The principal components of the proposed ILC PES, including the laser system necessary for operational tests, are described.

  19. The role of charged ice hydrometeors in lightning initiation

    DEFF Research Database (Denmark)

    Babich, L. P.; Bochkov, E. I.; Neubert, Torsten

    2017-01-01

    In connection with the lightning initiation problem, we consider positive streamer formation around charged, needle-shaped ice hydrometeors in an external electric field. We present results of numerical simulations of the streamer discharges that include the ice dielectric polarization and conduc......In connection with the lightning initiation problem, we consider positive streamer formation around charged, needle-shaped ice hydrometeors in an external electric field. We present results of numerical simulations of the streamer discharges that include the ice dielectric polarization...

  20. Kinetic isoforms of intramembrane charge in intact amphibian striated muscle.

    Science.gov (United States)

    Huang, C L

    1996-04-01

    The effects of the ryanodine receptor (RyR) antagonists ryanodine and daunorubicin on the kinetic and steady-state properties of intramembrane charge were investigated in intact voltage-clamped frog skeletal muscle fibers under conditions that minimized time-dependent ionic currents. A hypothesis that RyR gating is allosterically coupled to configurational changes in dihydropyridine receptors (DHPRs) would predict that such interactions are reciprocal and that RyR modification should influence intramembrane charge. Both agents indeed modified the time course of charging transients at 100-200-microM concentrations. They independently abolished the delayed charging phases shown by q gamma currents, even in fibers held at fully polarized, -90-mV holding potentials; such waveforms are especially prominent in extracellular solutions containing gluconate. Charge movements consistently became exponential decays to stable baselines in the absence of intervening inward or other time-dependent currents. The steady-state charge transfers nevertheless remained equal through the ON and the OFF parts of test voltage steps. The charge-voltage function, Q(VT), shifted by approximately +10 mV, particularly through those test potentials at which delayed q gamma currents normally took place but retained steepness factors (k approximately 8.0 to 10.6 mV) that indicated persistent, steeply voltage-dependent q gamma contributions. Furthermore, both RyR antagonists preserved the total charge, and its variation with holding potential, Qmax (VH), which also retained similarly high voltage sensitivities (k approximately 7.0 to 9.0 mV). RyR antagonists also preserved the separate identities of q gamma and q beta species, whether defined by their steady-state voltage dependence or inactivation or pharmacological properties. Thus, tetracaine (2 mM) reduced the available steady-state charge movement and gave shallow Q(VT) (k approximately 14 to 16 mV) and Qmax (VH) (k approximately 14 to 17 m

  1. Mechanism

    Directory of Open Access Journals (Sweden)

    Yao Yu

    2010-01-01

    Full Text Available The kinematics analysis method of a novel 3-DOF wind tunnel mechanism based on cable-driven parallel mechanism is provided. Rodrigues' parameters are applied to express the transformation matrix of the wire-driven mechanism in the paper. The analytical forward kinematics model is described as three quadratic equations using three Rodridgues' parameters based on the fundamental theory of parallel mechanism. Elimination method is used to remove two of the variables, so that an eighth-order polynomial with one variable is derived. From the equation, the eight sets of Rodridgues' parameters and corresponding Euler angles for the forward kinematical problem can be obtained. In the end, numerical example of both forward and inverse kinematics is included to demonstrate the presented forward-kinematics solution method. The numerical results show that the method for the position analysis of this mechanism is effective.

  2. The impacts of surface polarity on the solubility of nanoparticle

    International Nuclear Information System (INIS)

    Zhu, Jianzhuo; Su, Jiguo; Ou, Xinwen; Li, Jingyuan

    2016-01-01

    In order to study the dependence of water solubility and hydration behavior of nanoparticles on their surface polarity, we designed polar nanoparticles with varying surface polarity by assigning atomic partial charge to the surface of C60. The water solubility of the nanoparticle is enhanced by several orders of magnitude after the introduction of surface polarity. Nevertheless, when the atomic partial charge grows beyond a certain value (q M ), the solubility continuously decreases to the level of nonpolar nanoparticle. It should be noted that such q M is comparable with atomic partial charge of a variety of functional groups. The hydration behaviors of nanoparticles were then studied to investigate the non-monotonic dependence of solubility on the surface polarity. The interaction between the polar nanoparticle and the hydration water is stronger than the nonpolar counterpart, which should facilitate the dissolution of the nanoparticles. On the other hand, the surface polarity also reduces the interaction of hydration water with the other water molecules and enhances the interaction between the nanoparticles which may hinder their dispersion. Besides, the introduction of surface polarity disturbs and even rearranges the hydration structure of nonpolar nanoparticle. Interestingly, the polar nanoparticle with less ordered hydration structure tends to have higher water solubility.

  3. Charge transfer mechanism for the formation of metallic states at the KTaO3/SrTiO3 interface

    KAUST Repository

    Nazir, Safdar

    2011-03-29

    The electronic and optical properties of the KTaO3/SrTiO3 heterointerface are analyzed by the full-potential linearized augmented plane-wave approach of density functional theory. Optimization of the atomic positions points at subordinate changes in the crystal structure and chemical bonding near the interface, which is due to a minimal lattice mismatch. The creation of metallic interface states thus is not affected by structural relaxation but can be explained by charge transfer between transition metal and oxygen atoms. It is to be expected that a charge transfer is likewise important for related interfaces such as LaAlO3/SrTiO3. The KTaO3/SrTiO3 system is ideal for disentangling the complex behavior of metallic interface states, since almost no structural relaxation takes place.

  4. Polarized particle levitation in hexapole field

    International Nuclear Information System (INIS)

    Jones, T.B.; Kallio, G.A.; Robinson, K.S.

    1976-06-01

    Proposed here is a novel electrostatic levitation scheme which uses the force exerted by a non-uniform electric field on a polarized particle. The scheme differs from conventional quadrupole levitation devices principally in that the levitated particle is uncharged. In order to provide the proper force required to achieve dynamic stabilization, a very intense non-uniform time-varying electric field produced by a three-dimensional hexapole electrode structure is utilized. The primary advantage of this levitation scheme might accrue in target fabrication operations where particle charge is undesirable or where reproducible charging of the particles themselves is difficult, due to high resistivity. The disadvantages of this scheme, as compared to charged particle levitation, are (i) a more complex electrode structure and (ii) significantly higher voltages. The scheme has possible application to molecular mass spectrometry, in situations where un-ionized but strongly polar or polarizable molecules are to be trapped or confined for analysis

  5. Static Gas-Charging Plug

    Science.gov (United States)

    Indoe, William

    2012-01-01

    A gas-charging plug can be easily analyzed for random vibration. The design features two steeped O-rings in a radial configuration at two different diameters, with a 0.050-in. (.1.3-mm) diameter through-hole between the two O-rings. In the charging state, the top O-ring is engaged and sealing. The bottom O-ring outer diameter is not squeezed, and allows air to flow by it into the tank. The inner diameter is stretched to plug the gland diameter, and is restrained by the O-ring groove. The charging port bushing provides mechanical stop to restrain the plug during gas charge removal. It also prevents the plug from becoming a projectile when removing gas charge from the accumulator. The plug can easily be verified after installation to ensure leakage requirements are met.

  6. Apico-basal polarity complex and cancer

    Indian Academy of Sciences (India)

    Loss of cell polarity is a hallmark for carcinoma, and its underlying molecular mechanism is beginning to emerge from studies on model organisms and cancer cell lines. Moreover, deregulated expression of apico-basal polarity complex components has been reported in human tumours. In this review, we provide an ...

  7. Coronavirus infection of polarized epithelial cells

    NARCIS (Netherlands)

    Rossen, J W; Horzinek, M C; Rottier, P J

    1995-01-01

    Epithelial cells are the first host cells to be infected by incoming c oronaviruses. Recent observations in vitro show that coronaviruses are released from a specific side of these polarized cells, and this polarized release might be important for the spread of the infection in vivo. Mechanisms for

  8. Polarized electron sources

    Energy Technology Data Exchange (ETDEWEB)

    Prepost, R. [Univ. of Wisconsin, Madison, WI (United States)

    1994-12-01

    The fundamentals of polarized electron sources are described with particular application to the Stanford Linear Accelerator Center. The SLAC polarized electron source is based on the principle of polarized photoemission from Gallium Arsenide. Recent developments using epitaxially grown, strained Gallium Arsenide cathodes have made it possible to obtain electron polarization significantly in excess of the conventional 50% polarization limit. The basic principles for Gallium and Arsenide polarized photoemitters are reviewed, and the extension of the basic technique to strained cathode structures is described. Results from laboratory measurements of strained photocathodes as well as operational results from the SLAC polarized source are presented.

  9. Links between the charge model and bonded parameter force constants in biomolecular force fields

    Science.gov (United States)

    Cerutti, David S.; Debiec, Karl T.; Case, David A.; Chong, Lillian T.

    2017-10-01

    The ff15ipq protein force field is a fixed charge model built by automated tools based on the two charge sets of the implicitly polarized charge method: one set (appropriate for vacuum) for deriving bonded parameters and the other (appropriate for aqueous solution) for running simulations. The duality is intended to treat water-induced electronic polarization with an understanding that fitting data for bonded parameters will come from quantum mechanical calculations in the gas phase. In this study, we compare ff15ipq to two alternatives produced with the same fitting software and a further expanded data set but following more conventional methods for tailoring bonded parameters (harmonic angle terms and torsion potentials) to the charge model. First, ff15ipq-Qsolv derives bonded parameters in the context of the ff15ipq solution phase charge set. Second, ff15ipq-Vac takes ff15ipq's bonded parameters and runs simulations with the vacuum phase charge set used to derive those parameters. The IPolQ charge model and associated protocol for deriving bonded parameters are shown to be an incremental improvement over protocols that do not account for the material phases of each source of their fitting data. Both force fields incorporating the polarized charge set depict stable globular proteins and have varying degrees of success modeling the metastability of short (5-19 residues) peptides. In this particular case, ff15ipq-Qsolv increases stability in a number of α -helices, correctly obtaining 70% helical character in the K19 system at 275 K and showing appropriately diminishing content up to 325 K, but overestimating the helical fraction of AAQAA3 by 50% or more, forming long-lived α -helices in simulations of a β -hairpin, and increasing the likelihood that the disordered p53 N-terminal peptide will also form a helix. This may indicate a systematic bias imparted by the ff15ipq-Qsolv parameter development strategy, which has the hallmarks of strategies used to develop

  10. Charge solitons in one-dimensional arrays of serially coupled Josephson junctions

    International Nuclear Information System (INIS)

    Hermon, Z.; Ben-Jacob, E.; Schoen, G.

    1996-01-01

    We study a 1D array of Josephson coupled superconducting grains with kinetic inductance which dominates over the Josephson inductance. In this limit the dynamics of excess Cooper pairs in the array is described in terms of charge solitons, created by polarization of the grains. We analyze the dynamics of these topological excitations, which are dual to the fluxons in a long Josephson junction, using the continuum sine-Gordon model. We find that their classical relativistic motion leads to saturation branches in the I-V characteristic of a ring-shaped array. We then discuss the semiclassical quantization of the charge soliton, and show that it is consistent with the large kinetic inductance of the array. We study the dynamics of a quantum charge soliton in a ring-shaped array biased by an external flux through its center. If the dephasing length of the quantum charge soliton is larger than the circumference of the array, quantum phenomena like persistent current and coherent current oscillations are expected. As the characteristic width of the charge soliton is of the order of 100μm, it is a macroscopic quantum object. We discuss the dephasing mechanisms which can suppress the quantum behavior of the charge soliton. copyright 1996 The American Physical Society

  11. Charged particle acceleration with plasmas

    International Nuclear Information System (INIS)

    Bravo O, A.

    1989-01-01

    Under certain conditions it is possible to create spatial charge waves (OCE) in a plasma (ionized gas) through some disturbance mechanism, the phenomenon produces electric fields of high intensity that are propagated at velocities near to a c. When charged particles are connected to such OCE they may be accelerated to very high energies in short distances. At present electric fields of approximately 10 7 V/cm have been observed. (Author). 4 refs

  12. Polarized H- source development at BNL

    International Nuclear Information System (INIS)

    Alessi, J.G.; Hershcovitch, A.; Kponou, A.; Niinikoski, T.; Sluyters, T.

    1986-01-01

    The AGS polarized H - source (PONI-1) now produces currents of 25-40 μA, and has operated reliably during polarized physics runs. A new polarized source, having as its goal mA's of H-vector, is now under development. An atomic hydrogen beam has been cooled to about 20 K with a forward flux of approx.10 19 atoms/s/sr. A superconducting solenoid having a calculated acceptance angle of 0.1 sr for the cold H 0 beam, is now being built. An ionizer for the resulting polarized H 0 beam based on resonant charge exchange of H 0 with D - , is being tested. 500 μA of H - have been produced by ionizing an unpolarized H 0 beam using this ionizer

  13. The influence of preferred orientation and poling temperature on the polarization switching current in PZT thin films

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, Mi; Zhang, Weikang; Zhang, Zebin; Zhang, Ping [Tianjin University, School of Electrical and Information Engineering, Tianjin (China); Lan, Kuibo [Tianjin University, School of Microelectronics, Tianjin (China)

    2017-07-15

    In this paper, Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} (PZT) thin films with different preferred orientation were prepared on platinized silicon substrates by a modified sol-gel method. Our results indicate that the polarization switching current in PZT thin films is dependent on preferred orientation and poling temperature. In our measurements, (111)-oriented PZT has a larger polarization switching current than randomly oriented PZT, and with the increase of the degree of (111) preferred orientation and the poling temperature, the polarization switching current gradually increase. Considering the contact of PZT thin film with electrodes, the space-charged limited conduction (SCLC) combined with domain switching mechanism may be responsible for such phenomena. By analyzing the conduction data, we found the interface-limited Schottky emission (ES) and bulk-limited Poole-Frenkel hopping (PF) are not suitable for our samples. (orig.)

  14. Nanoparticle charge control in nonpolar liquids: insights from small-angle neutron scattering and microelectrophoresis.

    Science.gov (United States)

    Kemp, Roger; Sanchez, Rodrigo; Mutch, Kevin J; Bartlett, Paul

    2010-05-18

    Electrostatic forces are typically produced in low polarity solvents by the addition of surfactants or charge-control additives. Although widely used, there is no consensus on the mechanism by which surfactants control the level of particle charge. We report an investigation using highly sensitive, single particle optical microelectrophoresis measurements combined with a small-angle neutron scattering study to establish the mechanism of charging by the surfactant AOT in the nonpolar solvent n-dodecane. We show that polymer-grafted particles with no chemically bound surface charges only charge above the critical micellar concentration of the surfactant. The surface potential increases gradually with increasing surfactant concentration c, before finally saturating at high c. The increase in the surface potential is correlated to the amount of surfactant adsorbed onto the surface of the particle. Using deuterated AOT and contrast variation techniques, we demonstrate that the surfactant is adsorbed within the polymer layer surrounding the particle core, probably as individual molecules rather than surfactant aggregates. A simple thermodynamic model accounts for the concentration dependence of the observed surface potential.

  15. Intramolecular charge transfer effects on 3-aminobenzoic acid

    Energy Technology Data Exchange (ETDEWEB)

    Stalin, T. [Department of Chemistry, Annamalai University, Annamalainagar, Chidambaram 608 002, Tamil Nadu (India); Rajendiran, N. [Department of Chemistry, Annamalai University, Annamalainagar, Chidambaram 608 002, Tamil Nadu (India)], E-mail: drrajendiran@rediffmail.com

    2006-03-20

    Effect of solvents, buffer solutions of different pH and {beta}-cyclodextrin on the absorption and fluorescence spectra of 3-aminobenzoic acid (3ABA) have been investigated. The solid inclusion complex of 3ABA with {beta}-CD is discussed by UV-Vis, fluorimetry, semiempirical quantum calculations (AM1), FT-IR, {sup 1}H NMR and Scanning Electron Microscope (SEM). The thermodynamic parameters ({delta}H, {delta}G and {delta}S) of the inclusion process are also determined. The experimental results indicated that the inclusion processes is an exothermic and spontaneous. The large Stokes shift emission in solvents with 3ABA are correlated with different solvent polarity scales suggest that, 3ABA molecule is more polar in the S{sub 1} state. Solvent, {beta}-CD studies and excited state dipole moment values confirms that the presence of intramolecular charge transfer (ICT) in 3ABA. Acidity constants for different prototropic equilibria of 3ABA in the S{sub 0} and S{sub 1} states are calculated. {beta}-Cyclodextrin studies shows that 3ABA forms a 1:1 inclusion complex with {beta}-CD. {beta}-CD studies suggest COOH group present in non-polar part and amino group present in hydrophilic part of the {beta}-CD cavity. A mechanism is proposed to explain the inclusion process.

  16. Charging for the use of plant varieties

    OpenAIRE

    Kingwell, Ross S.

    2001-01-01

    Private and many publicly funded plant breeding organisations charge farmers for use of varieties they develop. This article compares four alternative charging mechanisms and outlines responses to these alternatives by farmers and plant breeders. Risk‐averse farmers and breeders are shown to have opposite preferences for charging mechanisms. Results suggest profit‐based or royalties are preferred by farmers whereas breeders prefer area or tonnage‐based royalties. Risk‐sharing arrangements bet...

  17. CHARGE Association

    Directory of Open Access Journals (Sweden)

    Semanti Chakraborty

    2012-01-01

    Full Text Available We present here a case of 17-year-old boy from Kolkata presenting with obesity, bilateral gynecomastia, mental retardation, and hypogonadotrophic hypogonadism. The patient weighed 70 kg and was of 153 cm height. Facial asymmetry (unilateral facial palsy, gynecomastia, decreased pubic and axillary hair, small penis, decreased right testicular volume, non-palpable left testis, and right-sided congenital inguinal hernia was present. The patient also had disc coloboma, convergent squint, microcornea, microphthalmia, pseudohypertelorism, low set ears, short neck, and choanalatresia. He had h/o VSD repaired with patch. Laboratory examination revealed haemoglobin 9.9 mg/dl, urea 24 mg/dl, creatinine 0.68 mg/dl. IGF1 77.80 ng/ml (decreased for age, GH <0.05 ng/ml, testosterone 0.25 ng/ml, FSH-0.95 ΅IU/ml, LH 0.60 ΅IU/ml. ACTH, 8:00 A.M cortisol, FT3, FT4, TSH, estradiol, DHEA-S, lipid profile, and LFT was within normal limits. Prolactin was elevated at 38.50 ng/ml. The patient′s karyotype was 46XY. Echocardiography revealed ventricularseptal defect closed with patch, grade 1 aortic regurgitation, and ejection fraction 67%. Ultrasound testis showed small right testis within scrotal sac and undescended left testis within left inguinal canal. CT scan paranasal sinuses revealed choanalatresia and deviation of nasal septum to the right. Sonomammography revealed bilateral proliferation of fibroglandular elements predominantly in subareoalar region of breasts. MRI of brain and pituitary region revealed markedly atrophic pituitary gland parenchyma with preserved infundibulum and hypothalamus and widened suprasellar cistern. The CHARGE association is an increasingly recognized non-random pattern of congenital anomalies comprising of coloboma, heart defect, choanal atresia, retarded growth and development, genital hypoplasia, ear abnormalities, and/or deafness. [1] These anomalies have a higher probability of occurring together. In this report, we have

  18. Proximity charge sensing for semiconductor detectors

    Science.gov (United States)

    Luke, Paul N; Tindall, Craig S; Amman, Mark

    2013-10-08

    A non-contact charge sensor includes a semiconductor detector having a first surface and an opposing second surface. The detector includes a high resistivity electrode layer on the first surface and a low resistivity electrode on the high resistivity electrode layer. A portion of the low resistivity first surface electrode is deleted to expose the high resistivity electrode layer in a portion of the area. A low resistivity electrode layer is disposed on the second surface of the semiconductor detector. A voltage applied between the first surface low resistivity electrode and the second surface low resistivity electrode causes a free charge to drift toward the first or second surface according to a polarity of the free charge and the voltage. A charge sensitive preamplifier coupled to a non-contact electrode disposed at a distance from the exposed high resistivity electrode layer outputs a signal in response to movement of free charge within the detector.

  19. Tungsten-based nanomaterials (WO{sub 3} & Bi{sub 2}WO{sub 6}): Modifications related to charge carrier transfer mechanisms and photocatalytic applications

    Energy Technology Data Exchange (ETDEWEB)

    Girish Kumar, S., E-mail: girichem@yahoo.co.in; Koteswara Rao, K.S.R., E-mail: raoksrk@gmail.com

    2015-11-15

    Graphical abstract: - Highlights: • Photocatalytic applications of WO{sub 3} and Bi{sub 2}WO{sub 6} based nanomaterial are reviewed. • Modifications to improve their performance are highlighted. • Charge carrier generation–separation–recombination is discussed. • Challenges and future prospects in this area are addressed. - Abstract: Heterogeneous photocatalysis is an ideal green energy technology for the purification of wastewater. Although titania dominates as the reference photocatalyst, its wide band gap is a bottleneck for extended utility. Thus, search for non-TiO{sub 2} based nanomaterials has become an active area of research in recent years. In this regard, visible light absorbing polycrystalline WO{sub 3} (2.4–2.8 eV) and Bi{sub 2}WO{sub 6} (2.8 eV) with versatile structure-electronic properties has gained considerable interest to promote the photocatalytic reactions. These materials are also explored in selective functional group transformation in organic reactions, because of low reduction and oxidation potential of WO{sub 3} CB and Bi{sub 2}WO{sub 6} VB, respectively. In this focused review, various strategies such as foreign ion doping, noble metal deposition and heterostructuring with other semiconductors designed for efficient photocatalysis is discussed. These modifications not only extend the optical response to longer wavelengths, but also prolong the life-time of the charge carriers and strengthen the photocatalyst stability. The changes in the surface-bulk properties and the charge carrier transfer dynamics associated with each modification correlating to the high activity are emphasized. The presence of oxidizing agents, surface modification with Cu{sup 2+} ions and synthesis of exposed facets to promote the degradation rate is highlighted. In depth study on these nanomaterials is likely to sustain interest in wastewater remediation and envisaged to signify in various green energy applications.

  20. Computational investigation and hydrogen/deuterium exchange of the fixed charge derivative tris(2,4,6-trimethoxyphenyl) phosphonium: implications for the aspartic acid cleavage mechanism.

    Science.gov (United States)

    Herrmann, Kristin A; Wysocki, Vicki H; Vorpagel, Erich R

    2005-07-01

    Aspartic acid (Asp)-containing peptides with the fixed charge derivative tris(2,4,6trimethoxyphenyl) phosphonium (tTMP-P+) were explored computationally and experimentally by hydrogen/deuterium (H/D) exchange and by fragmentation studies to probe the phenomenon of selective cleavage C-terminal to Asp in the absence of a "mobile" proton. Ab initio modeling of the tTMP-P+ electrostatic potential shows that the positive charge is distributed on the phosphonium group and therefore is not initiating or directing fragmentation as would a "mobile" proton. Geometry optimizations and vibrational analyses of different Asp conformations show that the Asp structure with a hydrogen bond between the side-chain hydroxy and backbone carbonyl lies 2.8 kcal/mol above the lowest energy conformer. In reactions with D2O, the phosphonium-derived doubly charged peptide (H+)P+LDIFSDF rapidly exchanges all 12 of its exchangeable hydrogens for deuterium and also displays a nonexchanging population. With no added proton, P+LDIFSDF exchanges a maximum of 4 of 11 exchangeable hydrogens for deuterium. No exchange is observed when all acidic groups are converted to the corresponding methyl esters. Together, these H/D exchange results indicate that the acidic hydrogens are "mobile locally" because they are able to participate in exchange even in the absence of an added proton. Fragmentation of two distinct (H+)P+LDIFSDF ion populations shows that the nonexchanging population displays selective cleavage, whereas the exchanging population fragments more evenly across the peptide backbone. This result indicates that H/D exchange can sometimes distinguish between and provide a means of separation of different protonation motifs and that these protonation motifs can have an effect on the fragmentation.

  1. Charging machine for a fast production reactor

    International Nuclear Information System (INIS)

    Artem'ev, L.N.; Kurilkin, V.V.

    1971-01-01

    Charging machine for a fast production reactor is described. The machine contains charging mechanism, mechanism for positioning fresh fuel and spent fuel assemtlies, storage drums with sockets for control rod assemtlies and collet tongs for control rods. Recharging is conducted by means of ramp channel

  2. Profiling of Polar Lipids in Marine Oleaginous Diatom Fistulifera solaris JPCC DA0580: Prediction of the Potential Mechanism for Eicosapentaenoic Acid-Incorporation into Triacylglycerol

    Directory of Open Access Journals (Sweden)

    Yue Liang

    2014-05-01

    Full Text Available The marine oleaginous diatom Fistulifera solaris JPCC DA0580 is a candidate for biodiesel production because of its high lipid productivity. However, the substantial eicosapentaenoic acid (EPA content in this strain would affect the biodiesel quality. On the other hand, EPA is also known as the essential health supplement for humans. EPAs are mainly incorporated into glycerolipids in the microalgal cell instead of the presence as free fatty acids. Therefore, the understanding of the EPA biosynthesis including the incorporation of the EPA into glycerolipids especially triacylglycerol (TAG is fundamental for regulating EPA content for different purposes. In this study, in order to identify the biosynthesis pathway for the EPA-containing TAG species, a lipidomic characterization of the EPA-enriched polar lipids was performed by using direct infusion electrospray ionization (ESI-Q-TRAP-MS and MS/MS analyses. The determination of the fatty acid positional distribution showed that the sn-2 position of all the chloroplast lipids and part of phosphatidylcholine (PC species was occupied by C16 fatty acids. This result suggested the critical role of the chloroplast on the lipid synthesis in F. solaris. Furthermore, the exclusive presence of C18 fatty acids in PC highly indicated the biosynthesis of EPA on PC. Finally, the PC-based acyl-editing and head group exchange processes were proposed to be essential for the incorporation of EPA into TAG and chloroplast lipids.

  3. Rapid integrated rheo-optical and polarized Fourier-transform infrared spectrometry measurement system for polymer films undergoing chemo-mechanical changes.

    Science.gov (United States)

    Unsal, E; Nugay, I I; Offenbach, I; Gross, M; Manning, C; Cakmak, M

    2013-07-01

    The design and performance of a multisensory instrument to track physical and chemical changes of thin polymer films (typically 5 μm stretching direction, received by detector unit. This design allows to analyze both polarizations simultaneously wavenumbers in the range of 500 cm(-1)-4000 cm(-1). Controlled processing parameters include air speed, air temperature, stretching rate, stretching ratio, stretch cycling, and holding times; while simultaneously measuring optical retardation, sample width, temperature, load cell, and both parallel and perpendicular IR spectra. Calibration and performance of this instrument is demonstrated with several film samples. These are: A polystyrene standard, an atactic polystyrene (homo-polymer), a polyurethane (consists of hard and soft segments) for physical changes during uniaxial deformation, and a polyamic acid during imidization reaction. This measurement system is particularly useful in unraveling molecular level details of complex physical and chemical events that take place during very fast deformation schemes (uniaxial stretching, retraction, relaxation, annealing, etc.) relevant to industrial processes. These include specific orientation behavior of each phase, block or filler, crystallization, relaxation and orientation state. It is also suited to track reaction rates and products in polymers undergoing thermal or photo curing.

  4. Spin-polarized light-emitting diodes based on organic bipolar spin valves

    Energy Technology Data Exchange (ETDEWEB)

    Vardeny, Zeev Valentine; Nguyen, Tho Duc; Ehrenfreund, Eitan Avraham

    2017-10-25

    Spin-polarized organic light-emitting diodes are provided. Such spin-polarized organic light-emitting diodes incorporate ferromagnetic electrodes and show considerable spin-valve magneto-electroluminescence and magneto-conductivity responses, with voltage and temperature dependencies that originate from the bipolar spin-polarized space charge limited current.

  5. Mechanics

    CERN Document Server

    Hartog, J P Den

    1961-01-01

    First published over 40 years ago, this work has achieved the status of a classic among introductory texts on mechanics. Den Hartog is known for his lively, discursive and often witty presentations of all the fundamental material of both statics and dynamics (and considerable more advanced material) in new, original ways that provide students with insights into mechanical relationships that other books do not always succeed in conveying. On the other hand, the work is so replete with engineering applications and actual design problems that it is as valuable as a reference to the practicing e

  6. Frequency dependent polarization in blazars

    International Nuclear Information System (INIS)

    Bjoernsson, C.I.

    1984-10-01

    It is argued that the intrinsic frequency dependent polarization in blazars finds its most straightforward explanations in terms of a single rather than a multicomponent sourcemodel. In order to reproduce the observations, under the assumption that the emission mechanism is optically thin synchrotron radiation, both a well ordered magnetic field and an electron distribution with a sharp break or cuttoff are necessary. Non-uniform pitch angle distribution and/or environments where synchrotron losses are important are both conducive to producing strong frequency dependent polarization. Reasons are put forth as to why such conditions ar expected to occur in blazars. Two specific models are discussed in detail and it is shown that they are both able to produce strong frequency dependent polarization, even when the spectral index changes by a small amount only. (orig.)

  7. Charge ordering in low dimensional organic conductors: Structural aspects

    Energy Technology Data Exchange (ETDEWEB)

    Pouget, Jean-Paul; Foury-Leylekian, Pascale [Laboratoire de Physique des Solides, Universite Paris-sud, CNRS UMR 8502, Batiment 510, 91405 Orsay Cedex (France); Alemany, Pere [Departament de Quimica Fisica and Institut de Quimica Teorica i Computacional (IQTCUB), Universitat de Barcelona, Diagonal 627, 08028 Barcelona (Spain); Canadell, Enric [Institut de Ciencia de Materials de Barcelona, CSIC, Campus UAB, 08193 Bellaterra (Spain)

    2012-05-15

    The paper points out the importance of the coupling between anions and donors in order to achieve the 4k{sub F} charge localization observed in (TMTTF){sub 2}PF{sub 6}, {delta}-(EDT-TTF-CONMe{sub 2}){sub 2}Br and (o-DMTTF){sub 2}Cl/Br salts, the 2k{sub F} charge density wave (CDW) ground state of {alpha}-(BEDT-TTF){sub 2}KHg(SCN){sub 4} and the metal to insulator transition of {alpha}-(BEDT-TTF){sub 2}I{sub 3}. This coupling leads to a cooperative displacement wave of the anions accompanied by a modulation of the density of {pi} holes on the donors. We distinguish two principal anion-donor coupling mechanisms: a direct mechanism via the Hartree anion potential on donor sites and an indirect mechanism via the polarization of {sigma} bonds activated by the modification of the H bonds network. Both kinds of interaction are tuned by the relative displacement of the anions with respect to the donors. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Polarizing PVC — A Discrepant Event

    Science.gov (United States)

    Headly, David; Karabatek, Mohamed

    2016-01-01

    Each year when teaching polarization phenomena and the Triboelectric Series in a unit on electrostatics, I would balance some rods (2-3 ft in length) made from wood, aluminum, PVC, and Plexiglas on an inverted watch glass and demonstrate to the class how a party balloon rubbed with fake rabbit fur (charging the balloon negative) would always attract the uncharged rods, causing them to rotate towards the balloon (see Fig. 1). The fact that a charged object always attracts a neutral object due to the induced dipole in the latter is a great way to test if something is in fact charged. Surprisingly, the PVC pipe would usually, but not always, repel the charged balloon and rotate away! Repulsion means that neither of the objects are electrically neutral. In a separate test, after rubbing together a Plexiglas rod with a polyethylene grocery bag (making the rod positively charged and the bag negatively charged), the PVC usually attracts the rod. With the help of a student as part of his senior project, I finally decided to investigate further the source of the negative charge that exists on PVC. Specifically, is it nothing more than static charge that builds up on the pipe from unavoidable contact with its surroundings, or is it somehow intrinsic to the manufacturing process?

  9. Geographical Income Polarization

    DEFF Research Database (Denmark)

    Azhar, Hussain; Jonassen, Anders Bruun

    inter municipal income inequality. Counter factual simulations show that rising property prices to a large part explain the rise in polarization. One side-effect of polarization is tendencies towards a parallel polarization of residence location patterns, where low skilled individuals tend to live......In this paper we estimate the degree, composition and development of geographical income polarization based on data at the individual and municipal level in Denmark from 1984 to 2002. Rising income polarization is reconfirmed when applying new polarization measures, the driving force being greater...

  10. Insights into an intriguing gas sorption mechanism in a polar metal–organic framework with open-metal sites and narrow channels

    KAUST Repository

    Forrest, Katherine A.

    2014-01-01

    Simulations of H2 and CO2 sorption were performed in the metal-organic framework (MOF), [Cu(Me-4py-trz-ia)]. This MOF was recently shown experimentally to exhibit high uptake for H2 and CO2 sorption and this was reproduced and elucidated through the simulations performed herein. Consistent with experiment, the theoretical isosteric heat of adsorption, Qst, values were nearly constant across all loadings for both sorbates. The simulations revealed that sorption directly onto the open-metal sites was not observed in this MOF, ostensibly a consequence of the low partial positive charges of the Cu2+ ions as determined through electronic structure calculations. Sorption was primarily observed between adjacent carboxylate oxygen atoms (site 1) and between nearby methyl groups (site 2) of the organic linkers. In addition, saturation of the most energetically favorable sites (site 1) is possible only after filling a nearby site (site 2) first due to the MOF topology. This suggests that the lack of dependence on loading for the Qst is due to the concurrent filling of sites 1 and 2, leading to an observed average Qst value. © 2014 the Partner Organisations.

  11. The BNL polarized H- ion source development program

    International Nuclear Information System (INIS)

    Kponou, A.; Alessi, J.; Hershcovitch, A.; DeVito, B.

    1992-01-01

    Polarized protons have been available for acceleration in the AGS for the high energy physics program since 1984. The polarized H - source, PONI-1, has routinely supplied a 0.4 Hz, 400 μsec pulse having a nominal intensity of 40 μA. Polarization is ∼80% out of the ion source. After PONI- 1 became operational, a program was initiated to develop a more intense source based on a cold ground state atomic beam source, followed by ionization of the polarized H degrees beam by D - charge exchange. Various phases of this work have been fully reported elsewhere, and only a summary is given here

  12. Ionization and excitation of lithium atoms by fast charged particle impact: identification of mechanisms for double K-shell vacancy production as a function of the projectile charge and velocity; Ionisation et excitation de l'atome de lithium par impact de particules chargees rapides: Identification des mecanismes de creation de deux lacunes en couche K du lithium en fonction de la charge et de la vitesse du projectile

    Energy Technology Data Exchange (ETDEWEB)

    Rangama, J

    2002-11-01

    Ionization and excitation of lithium atoms by fast charged particle impact: identification of mechanisms for double K-shell vacancy production as a function of projectile charge and velocity. Auger electron spectroscopy is used for an experimental investigation of ionization and excitation of lithium atoms by ions (Kr34{sup +} and Ar18{sup +}) and electrons at high impact velocities (from 6 to 60 a.u.). In particular, relative contributions of the mechanisms responsible for lithium K-shell ionization-excitation are determined for various projectile charges Zp and velocities vp. A large range of perturbation parameters |Zp|/vp is explored (|Zp|/vp = 0,05 - 0,7 a.u.). From single K-shell excitation results, it appears that the projectile-electron interaction gives mainly rise to a dipole-like transition 1s -> np Concerning K-shell ionization-excitation, the separation of the TS2 (two independent projectile-electron interactions) and TS1 (one projectile-electron interaction) mechanisms responsible for the formation of the 2snp 1,3P and 2sns 1,3S lithium states is performed. In TS1 process, the projectile-electron interaction can be followed by an electron-electron interaction (dielectronic process) or by an internal rearrangement of the residual target after a sudden potential change (shake process). From Born theory, ab initio calculations are performed. The good agreement between theoretical and experimental results confirms the mechanism identification. For the production of P states, TS1 is found to be strongly dominant for small |Zp|/vp values and TS2 is found to be most important for large |Zp|/vp values. Since P states cannot be formed significantly via a shake process, the TS1 and TS2 separation provides a direct signature of the dielectronic process. On the other hand, the TS1 process is shown to be the unique process for producing the S states. At the moment, only the shake aspect of the TS1 process can explain the fact that the 2s3s configuration is

  13. Investigation of electronic band structure and charge transfer mechanism of oxidized three-dimensional graphene as metal-free anodes material for dye sensitized solar cell application

    Science.gov (United States)

    Loeblein, Manuela; Bruno, Annalisa; Loh, G. C.; Bolker, Asaf; Saguy, Cecile; Antila, Liisa; Tsang, Siu Hon; Teo, Edwin Hang Tong

    2017-10-01

    Dye-sensitized solar cells (DSSCs) offer an optimal trade-off between conversion-efficiency and low-cost fabrication. However, since all its electrodes need to fulfill stringent work-function requirements, its materials have remained unchanged since DSSC's first report early-90s. Here we describe a new material, oxidized-three-dimensional-graphene (o-3D-C), with a band gap of 0.2 eV and suitable electronic band-structure as alternative metal-free material for DSSCs-anodes. o-3D-C/dye-complex has a strong chemical bonding via carboxylic-group chemisorption with full saturation after 12 sec at capacity of ∼450 mg/g (600x faster and 7x higher than optimized metal surfaces). Furthermore, fluorescence quenching of life-time by 28-35% was measured demonstrating charge-transfer from dye to o-3D-C.

  14. Mn L2,3-edge X-ray absorption spectroscopic studies on charge-discharge mechanism of Li2MnO3

    International Nuclear Information System (INIS)

    Kubobuchi, Kei; Mogi, Masato; Imai, Hideto; Ikeno, Hidekazu; Tanaka, Isao; Mizoguchi, Teruyasu

    2014-01-01

    The redox reaction of Mn in Li 2 MnO 3 was studied by X-ray absorption spectroscopy and ab initio multiplet calculation. Associated with the de-intercalation of Li-ion, small but clear spectral changes were observed in Mn-L 2,3 X-ray absorption near edge structure (XANES). The systematic ab initio multiplet calculations of Mn-L 2,3 XANES revealed that the spectral changes in the experiment could not simply be ascribed to the change of the valency from Mn 4+ to Mn 5+ but can be explained well by the changes of local atomic structures around Mn 4+ due to the Li de-intercalation. Our results suggest that the electronic state of oxygen should change during charging in Li 2 MnO 3

  15. Charge-discharge mechanisms of Li3V2(PO4)3 cathode materials in Li-batteries - studied by operando PXD

    DEFF Research Database (Denmark)

    Sørensen, Daniel Risskov; Mathiesen, Jette Katja; Henriksen, Christian

    potential and high theoretical capacity (197 mAh g-1) . The material exhibits distinct potential plateaus during Li-extraction for the crystallographic distinct lithium ions, which is typically a sign of a multiphase system where each phase determines the potential2. In this work, we wished to explore...... of their safety, cost, energy density and rate performance. Herein lie the demand for new electrode materials that can provide the required battery properties. Monoclinic Li3V2(PO4)3 (LVP) is a well-known candidate as a cathode material in rechargeable Li-batteries, showing good cyclic stability, high operating...... the following: •Is it possible to correlate the features seen in the charge/discharge curves with changes in the crystal structure of LVP? Is operando synchrotron PXD a suitable tool in this investigation? •Changes in the used potential window are known to significantly influence the performance of the battery...

  16. Development of a high average current polarized electron source with long cathode operational lifetime

    Directory of Open Access Journals (Sweden)

    C. K. Sinclair

    2007-02-01

    Full Text Available Substantially more than half of the electromagnetic nuclear physics experiments conducted at the Continuous Electron Beam Accelerator Facility of the Thomas Jefferson National Accelerator Facility (Jefferson Laboratory require highly polarized electron beams, often at high average current. Spin-polarized electrons are produced by photoemission from various GaAs-based semiconductor photocathodes, using circularly polarized laser light with photon energy slightly larger than the semiconductor band gap. The photocathodes are prepared by activation of the clean semiconductor surface to negative electron affinity using cesium and oxidation. Historically, in many laboratories worldwide, these photocathodes have had short operational lifetimes at high average current, and have often deteriorated fairly quickly in ultrahigh vacuum even without electron beam delivery. At Jefferson Lab, we have developed a polarized electron source in which the photocathodes degrade exceptionally slowly without electron emission, and in which ion back bombardment is the predominant mechanism limiting the operational lifetime of the cathodes during electron emission. We have reproducibly obtained cathode 1/e dark lifetimes over two years, and 1/e charge density and charge lifetimes during electron beam delivery of over 2×10^{5}   C/cm^{2} and 200 C, respectively. This source is able to support uninterrupted high average current polarized beam delivery to three experimental halls simultaneously for many months at a time. Many of the techniques we report here are directly applicable to the development of GaAs photoemission electron guns to deliver high average current, high brightness unpolarized beams.

  17. Polarized electron sources for linear colliders

    International Nuclear Information System (INIS)

    Clendenin, J.E.; Ecklund, S.D.; Miller, R.H.; Schultz, D.C.; Sheppard, J.C.

    1992-07-01

    Linear colliders require high peak current beams with low duty factors. Several methods to produce polarized e - beams for accelerators have been developed. The SLC, the first linear collider, utilizes a photocathode gun with a GaAs cathode. Although photocathode sources are probably the only practical alternative for the next generation of linear colliders, several problems remain to be solved, including high voltage breakdown which poisons the cathode, charge limitations that are associated with the condition of the semiconductor cathode, and a relatively low polarization of ≤5O%. Methods to solve or at least greatly reduce the impact of each of these problems are at hand

  18. Workplace Charging. Charging Up University Campuses

    Energy Technology Data Exchange (ETDEWEB)

    Giles, Carrie [ICF International, Fairfax, VA (United States); Ryder, Carrie [ICF International, Fairfax, VA (United States); Lommele, Stephen [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-03-01

    This case study features the experiences of university partners in the U.S. Department of Energy's (DOE) Workplace Charging Challenge with the installation and management of plug-in electric vehicle (PEV) charging stations.

  19. Polarized Light Corridor Demonstrations.

    Science.gov (United States)

    Davies, G. R.

    1990-01-01

    Eleven demonstrations of light polarization are presented. Each includes a brief description of the apparatus and the effect demonstrated. Illustrated are strain patterns, reflection, scattering, the Faraday Effect, interference, double refraction, the polarizing microscope, and optical activity. (CW)

  20. Big break for charge symmetry

    CERN Document Server

    Miller, G A

    2003-01-01

    Two new experiments have detected charge-symmetry breaking, the mechanism responsible for protons and neutrons having different masses. Symmetry is a crucial concept in the theories that describe the subatomic world because it has an intimate connection with the laws of conservation. The theory of the strong interaction between quarks - quantum chromodynamics - is approximately invariant under what is called charge symmetry. In other words, if we swap an up quark for a down quark, then the strong interaction will look almost the same. This symmetry is related to the concept of sup i sospin sup , and is not the same as charge conjugation (in which a particle is replaced by its antiparticle). Charge symmetry is broken by the competition between two different effects. The first is the small difference in mass between up and down quarks, which is about 200 times less than the mass of the proton. The second is their different electric charges. The up quark has a charge of +2/3 in units of the proton charge, while ...

  1. Influence of absorption in linear polarization imaging of melanoma tissues

    Directory of Open Access Journals (Sweden)

    Dongzhi Li

    2014-05-01

    Full Text Available The contrast mechanism of different polarization imaging techniques for melanoma in mouse skin is studied using both experiments and Monte Carlo simulations. Total intensity, linear polarization difference imaging (DPI, degree of polarization imaging (DOPI and rotating linear polarization imaging (RLPI are applied and the relative contrasts of these polarization imaging methods between the normal and cancerous tissues are compared. A two-layer absorption-scattering model is proposed to explain the contrast mechanism of the polarization imaging for melanoma. By taking into account of both scattering of symmetrical and asymmetrical scatterers and absorption of inter-scatterer medium, the two-layer model reproduces the relative contrasts for polarization images observed in experiments. The simulation results also show that, the parameters of polarization imaging change more dramatically with the variation of absorption in the bottom layer than the top layer.

  2. Electrically tunable dynamic nuclear spin polarization in GaAs quantum dots at zero magnetic field

    Science.gov (United States)

    Manca, M.; Wang, G.; Kuroda, T.; Shree, S.; Balocchi, A.; Renucci, P.; Marie, X.; Durnev, M. V.; Glazov, M. M.; Sakoda, K.; Mano, T.; Amand, T.; Urbaszek, B.

    2018-04-01

    In III-V semiconductor nano-structures, the electron and nuclear spin dynamics are strongly coupled. Both spin systems can be controlled optically. The nuclear spin dynamics are widely studied, but little is known about the initialization mechanisms. Here, we investigate optical pumping of carrier and nuclear spins in charge tunable GaAs dots grown on 111A substrates. We demonstrate dynamic nuclear polarization (DNP) at zero magnetic field in a single quantum dot for the positively charged exciton X+ state transition. We tune the DNP in both amplitude and sign by variation of an applied bias voltage Vg. Variation of ΔVg on the order of 100 mV changes the Overhauser splitting (nuclear spin polarization) from -30 μeV (-22%) to +10 μeV (+7%) although the X+ photoluminescence polarization does not change sign over this voltage range. This indicates that absorption in the structure and energy relaxation towards the X+ ground state might provide favourable scenarios for efficient electron-nuclear spin flip-flops, generating DNP during the first tens of ps of the X+ lifetime which is on the order of hundreds of ps. Voltage control of DNP is further confirmed in Hanle experiments.

  3. Polarized Moessbauer transitions

    International Nuclear Information System (INIS)

    Barb, D.

    1975-01-01

    Theoretical aspects of the emission, absorption and scattering of polarized gamma rays are reviewed for a general case of combined magnetic and electric hyperfine interactions; various possibilities of obtaining polarized gamma sources are described and examples are given of the applications of Moessbauer spectroscopy with polarized gamma rays in solving problems of solid state physics. (A.K.)

  4. Charge exchange and energy loss of slowed down heavy ions channeled in silicon crystals; Echanges de charge et perte d'energie d'ions lourds ralentis, canalises dans des cristaux de silicium

    Energy Technology Data Exchange (ETDEWEB)

    Testa, E

    2005-10-15

    This work is devoted to the study of charge exchange processes and of the energy loss of highly charged heavy ions channeled in thin silicon crystals. The two first chapters present the techniques of heavy ion channeling in a crystal, the ion-electron processes and the principle of our simulations (charge exchange and trajectory of channeled ions). The next chapters describe the two experiments performed at the GSI facility in Darmstadt, the main results of which follow: the probability per target atom of the mechanical capture (MEC) of 20 MeV/u U{sup 91+} ions as a function of the impact parameter (with the help of our simulations), the observation of the strong polarization of the target electron gas by the study of the radiative capture and the slowing down of Pb{sup 81+} ions from 13 to 8,5 MeV/u in channeling conditions for which electron capture is strongly reduced. (author)

  5. Renormalized vacuum polarization for finite range potentials

    International Nuclear Information System (INIS)

    Lewin, J.D.

    1975-10-01

    This report presents computed vacuum polarization effects for leptons in a spherical potential well of radius large compared with the lepton Compton wavelength. These results, together with those previously obtained for small radius wells, show that the total charge generated is independent of well radius and lepton mass; thus the quadratic divergence obtained for the total unrenormalized charge can be removed by the subtraction of the contribution computed for a lepton of mass M(→ infinity) as in the case of the Coulomb potential. Various other problems arising from the earlier study are clarified by the present results. (author)

  6. Polarizable charge equilibration model for predicting accurate electrostatic interactions in molecules and solids

    Science.gov (United States)

    Naserifar, Saber; Brooks, Daniel J.; Goddard, William A.; Cvicek, Vaclav

    2017-03-01

    Electrostatic interactions play a critical role in determining the properties, structures, and dynamics of chemical, biochemical, and material systems. These interactions are described well at the level of quantum mechanics (QM) but not so well for the various models used in force field simulations of these systems. We propose and validate a new general methodology, denoted PQEq, to predict rapidly and dynamically the atomic charges and polarization underlying the electrostatic interactions. Here the polarization is described using an atomic sized Gaussian shaped electron density that can polarize away from the core in response to internal and external electric fields, while at the same time adjusting the charge on each core (described as a Gaussian function) so as to achieve a constant chemical potential across all atoms of the system. The parameters for PQEq are derived from experimental atomic properties of all elements up to Nobelium (atomic no. = 102). We validate PQEq by comparing to QM interaction energy as probe dipoles are brought along various directions up to 30 molecules containing H, C, N, O, F, Si, P, S, and Cl atoms. We find that PQEq predicts interaction energies in excellent agreement with QM, much better than other common charge models such as obtained from QM using Mulliken or ESP charges and those from standard force fields (OPLS and AMBER). Since PQEq increases the accuracy of electrostatic interactions and the response to external electric fields, we expect that PQEq will be useful for a large range of applications including ligand docking to proteins, catalytic reactions, electrocatalysis, ferroelectrics, and growth of ceramics and films, where it could be incorporated into standard force fields as OPLS, AMBER, CHARMM, Dreiding, ReaxFF, and UFF.

  7. Study of charge transfer reactions in a microbial fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Martin, E.; Savadogo, O. [Ecole Polytechnique, Montreal, PQ (Canada). Dept. de Genie Chimique; National Research Council of Canada, Montreal, PQ (Canada). Biotechnology Research Inst.; Tartakovsky, B. [National Research Council of Canada, Montreal, PQ (Canada). Biotechnology Research Inst.

    2008-07-01

    Electron transfer reactions in a microbial fuel cell (MFC) were evaluated. The MFC was inoculated with anaerobic mesophilic sludge and operated with carbon felt, carbon cloth, and platinum (Pt) coated carbon cloth. The MFC was then fed with either acetate or glucose as a source of fuel and operated at a temperature of 25 degrees C and a pH of 7. Scanning electron microscopy (SEM) micrographs demonstrated that the micro-organisms colonized the anodes. Cyclic voltammetry and polarization tests were conducted using different fractions of the anodophilic biofilm in order to determine charge transfer routes. The study characterized the electron transfer mechanisms used by the exoelectrogenic micro-organisms to produce electricity. It was concluded that further research is needed to characterize reaction transfer routes. 2 refs., 1 fig.

  8. The mechanism of contribution to the taxes of the electricity public service; Le mecanisme de contribution aux Charges de Service Public d'Electricite

    Energy Technology Data Exchange (ETDEWEB)

    Blonde, G.; Poizat, F.; Triboulet, A. [IED, Louvain-la-Neuve (Belgium)

    2008-02-15

    This report presents the results of an expertise realized by the Institute of the Energy and development for the CCE of EDF. The CSPE is a mechanism of mutualization of taxes of the electricity public service. These taxes concern the impact of the tariffs adjustment, the assistance to systems of energy conservation, the solidarity to poor households. the document presents the historical aspects and the bases of the mechanism, the cost of the global compensation, the foundations of this mutualization system, the forecasts and some recommendations. (A.L.B.)

  9. Electrochemistry of end-capped oligothienyls. New insights into the polymerization mechanism and the charge storage, conduction and capacitive properties of polythiophene

    Energy Technology Data Exchange (ETDEWEB)

    Zotti, G. (Ist. di Polarografia ed Elettrochimica Preparativa, Consiglio Nazionale delle Ricerche, Padua (Italy)); Schiavon, G. (Ist. di Polarografia ed Elettrochimica Preparativa, Consiglio Nazionale delle Ricerche, Padua (Italy)); Berlin, A. (Dipt. di Chimica Organica e Industriale dell' Univ. e Centro CNR, Speciali Sistemi Organici, Milan (Italy)); Pagani, G. (Dipt. di Chimica Organica e Industriale dell' Univ. e Centro CNR, Speciali Sistemi Organici, Milan (Italy))

    1993-11-23

    The kinetics of anodic coupling to dimers of thiophene oligomers (n=3-5), methyl protected at one [alpha]-terminal position, is second order in oligomer concentration and evidences high activation enthalpies and negative activation entropies. Activation free energies are linearly related to the inverse of the oligomer length n (the dimerization rate decreases as n is increased). Thin films of methyl end-capped thiophene oligomers (n=4, 6, 8 and 10) display reversible oxidations from a single one-electron step (tetramer) to a single two-electron step (octamer and decamer) through two separate one-electron steps (hexamer). ESR indicates strong magnetic dimerization for the one-electron-oxidized hexamer. The close resemblance of the electrochemical and ESR behaviour of the hexamer with that of polythiophene suggests that oxidation of the latter occurs via hexameric spin-dimerized polarons. The conductive and capacitive properties of the end-capped oligomers (n=6, 8 and 10) were investigated by in situ conductivity and chronopotentiometry. While conductivity of octamer and decamer is displayed at the two-electron (bipolaron) state, the hexamer, insulating at this state, is conducting at the mixed-valence polaron-bipolaron state; capacitive responses are evidenced at the bipolaron state for the octamer and decamer only. The difference of conductive and capacitive behaviour between the hexamer and the higher oligomers is explained by charge localization in hexameric segments. (orig.)

  10. Disinfection of Escherichia coli Gram negative bacteria using surface modified TiO2: optimization of Ag metallization and depiction of charge transfer mechanism.

    Science.gov (United States)

    Gomathi Devi, LakshmipathiNaik; Nagaraj, Basavalingaiah

    2014-01-01

    The antibacterial activity of silver deposited TiO2 (Ag-TiO2 ) against Gram negative Escherichia coli bacteria was investigated by varying the Ag metal content from 0.10 to 0.50% on the surface of TiO2 . Ag depositions by the photoreduction method were found to be stable. Surface silver metallization was confirmed by EDAX and XPS studies. Photoluminescence studies show that the charge carrier recombination is less for 0.1% Ag-TiO2 and this catalyst shows superior bactericidal activity under solar light irradiation compared to Sol gel TiO2 (SG-TiO2 ) due to the surface plasmon effect. The energy levels of deposited Ag are dependent on the Ag content and it varies from -4.64 eV to -1.30 eV with respect to the vacuum energy level based on atomic silver to bulk silver deposits. The ability of electron transfer from Ag deposit to O2 depends on the position of the energy levels. The 0.25% and 0.50% Ag depositions showed detrimental effect on bactericidal activity due to the mismatch of energy levels. The effect of the EROS (External generation of the Reactive Oxygen Species by 0.1% Ag-TiO2 ) and IROS (Interior generation of Reactive Oxygen Species within the bacteria) on the bactericidal inactivation is discussed in detail. © 2014 The American Society of Photobiology.

  11. Point charges optimally placed to represent the multipole expansion of charge distributions.

    Directory of Open Access Journals (Sweden)

    Ramu Anandakrishnan

    Full Text Available We propose an approach for approximating electrostatic charge distributions with a small number of point charges to optimally represent the original charge distribution. By construction, the proposed optimal point charge approximation (OPCA retains many of the useful properties of point multipole expansion, including the same far-field asymptotic behavior of the approximate potential. A general framework for numerically computing OPCA, for any given number of approximating charges, is described. We then derive a 2-charge practical point charge approximation, PPCA, which approximates the 2-charge OPCA via closed form analytical expressions, and test the PPCA on a set of charge distributions relevant to biomolecular modeling. We measure the accuracy of the new approximations as the RMS error in the electrostatic potential relative to that produced by the original charge distribution, at a distance 2x the extent of the charge distribution--the mid-field. The error for the 2-charge PPCA is found to be on average 23% smaller than that of optimally placed point dipole approximation, and comparable to that of the point quadrupole approximation. The standard deviation in RMS error for the 2-charge PPCA is 53% lower than that of the optimal point dipole approximation, and comparable to that of the point quadrupole approximation. We also calculate the 3-charge OPCA for representing the gas phase quantum mechanical charge distribution of a water molecule. The electrostatic potential calculated by the 3-charge OPCA for water, in the mid-field (2.8 Å from the oxygen atom, is on average 33.3% more accurate than the potential due to the point multipole expansion up to the octupole order. Compared to a 3 point charge approximation in which the charges are placed on the atom centers, the 3-charge OPCA is seven times more accurate, by RMS error. The maximum error at the oxygen-Na distance (2.23 Å is half that of the point multipole expansion up to the octupole

  12. Investigation of the effect of mechanical pressure on the performance of negative lead accumulator electrodes during partial state of charge operation

    Czech Academy of Sciences Publication Activity Database

    Bača, P.; Micka, Karel; Křivík, P.; Tonar, K.; Tošer, P.

    2012-01-01

    Roč. 207, JUN 1 2012 (2012), s. 37-44 ISSN 0378-7753 Institutional research plan: CEZ:AV0Z40400503 Keywords : Lead battery electrodes * Doping with carbon or titanium dioxide * Effect of mechanical pressure Subject RIV: CG - Electrochemistry Impact factor: 4.675, year: 2012

  13. Scattering Polarization in Solar Flares

    Czech Academy of Sciences Publication Activity Database

    Štěpán, Jiří; Heinzel, Petr

    2013-01-01

    Roč. 778, č. 1 (2013), L6/1-L6/6 ISSN 2041-8205 R&D Projects: GA ČR GAP209/12/1652; GA ČR GPP209/12/P741 Institutional support: RVO:67985815 Keywords : line formation * polarization * radiative transfer Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 5.602, year: 2013

  14. Bipolar resistive switching and charge transport in silicon oxide memristor

    Energy Technology Data Exchange (ETDEWEB)

    Mikhaylov, Alexey N., E-mail: mian@nifti.unn.ru [Lobachevsky State University of Nizhni Novgorod, 23/3 Gagarin Prospect, Nizhni Novgorod 603950 (Russian Federation); Belov, Alexey I.; Guseinov, Davud V.; Korolev, Dmitry S.; Antonov, Ivan N.; Efimovykh, Denis V.; Tikhov, Stanislav V.; Kasatkin, Alexander P.; Gorshkov, Oleg N.; Tetelbaum, David I.; Bobrov, Alexander I.; Malekhonova, Natalia V.; Pavlov, Dmitry A. [Lobachevsky State University of Nizhni Novgorod, 23/3 Gagarin Prospect, Nizhni Novgorod 603950 (Russian Federation); Gryaznov, Evgeny G. [Lobachevsky State University of Nizhni Novgorod, 23/3 Gagarin Prospect, Nizhni Novgorod 603950 (Russian Federation); Sedakov Scientific-Research Institute, GSP-486, Nizhny Novgorod 603950 (Russian Federation); Yatmanov, Alexander P. [Sedakov Scientific-Research Institute, GSP-486, Nizhny Novgorod 603950 (Russian Federation)

    2015-04-15

    Graphical abstract: - Highlights: • Si-based thin-film memristor structure was fabricated by magnetron sputtering. • We study bipolar resistive switching and charge transport mechanisms. • Resistive switching parameters are determined by a balance between redox reactions. - Abstract: Reproducible bipolar resistive switching has been studied in SiO{sub x}-based thin-film memristor structures deposited by magnetron sputtering technique on the TiN/Ti metalized SiO{sub 2}/Si substrates. It is established that, after electroforming, the structure can be switched between the quasi-ohmic low-resistance state related to silicon chains (conducting filaments) and the high-resistance state with semiconductor-like hopping mechanism of charge transport through the defects in silicon oxide. The switching parameters are determined by a balance between the reduction and oxidation processes that, in turn, are driven by the value and polarity of voltage bias, current, temperature and device environment. The results can be used for the development of silicon-based nonvolatile memory and memristive systems as a key component of future electronics.

  15. Mechanics

    CERN Document Server

    Chester, W

    1979-01-01

    When I began to write this book, I originally had in mind the needs of university students in their first year. May aim was to keep the mathematics simple. No advanced techniques are used and there are no complicated applications. The emphasis is on an understanding of the basic ideas and problems which require expertise but do not contribute to this understanding are not discussed. How­ ever, the presentation is more sophisticated than might be considered appropri­ ate for someone with no previous knowledge of the subject so that, although it is developed from the beginning, some previous acquaintance with the elements of the subject would be an advantage. In addition, some familiarity with element­ ary calculus is assumed but not with the elementary theory of differential equations, although knowledge of the latter would again be an advantage. It is my opinion that mechanics is best introduced through the motion of a particle, with rigid body problems left until the subject is more fully developed. Howev...

  16. POLARIZED LIGHT IN PHYSIOTHERAPY

    Directory of Open Access Journals (Sweden)

    L. D. Tondiy

    2015-12-01

    Full Text Available The data on polarized light (PS - a new promising treatment, rehabilitation and prevention, which took its deserved place among the known therapeutic physical factors and may even compete with laser radiation of low and LED therapy. It is reflected the significant contribution of domestic scientists in the study of aircraft action on the body, its introduction in the treatment, rehabilitation and prevention of grippe, ARI. These action's mechanisms of the aircraft on the electro-physiological processes in the body that have the leading role in the regulation of its life. The new moment in the study of aircraft on the body is the evidence of its positive impact on the mechanisms of self body - its different units: the disease's banning - a revitalization of the stress-protective, stress-limiting system antioxidial, detoxification and other protection systems, the formation by the body antiviral and antimicrobial specific substances (interferon and lysozyme, activation of the immune system, phagocytosis, protective functions of skin. The protective and mobilizing role of the second link is studied: which is triggered in case of occurrence of disease or preexisting diseases: PL mobilized processes of restitution, reparations, compensation, immunity and microcirculation. The authors studied the possibility of aircraft's using to enhance performance, reduce side effects of physical factors, which are often used in the treatment (electric methods, treatment by sound, fresh and mineral water, etc..

  17. Modeling alignment enhancement for solid polarized targets

    Energy Technology Data Exchange (ETDEWEB)

    Keller, D. [University of Virginia, Charlottesville, VA (United States)

    2017-07-15

    A model of dynamic orientation using optimized radiofrequency (RF) irradiation produced perpendicular to the holding field is developed for the spin-1 system required for tensor-polarized fixed-target experiments. The derivation applies to RF produced close to the Larmor frequency of the nucleus and requires the electron spin-resonance linewidth to be much smaller than the nuclear magnetic resonance frequency. The rate equations are solved numerically to study a semi-saturated steady-state resulting from the two sources of irradiation: microwave from the DNP process and the additional RF used to manipulate the tensor polarization. The steady-state condition and continuous-wave NMR lineshape are found that optimize the spin-1 alignment in the polycrystalline materials used as solid polarized targets in charged-beam nuclear and particle physics experiments. (orig.)

  18. Polarization measurement of laser-accelerated protons

    Energy Technology Data Exchange (ETDEWEB)

    Raab, Natascha; Engels, Ralf; Engin, Ilhan; Greven, Patrick; Holler, Astrid; Lehrach, Andreas; Maier, Rudolf [Institut für Kernphysik and Jülich Center for Hadron Physics, Forschungszentrum Jülich, 52425 Jülich (Germany); Büscher, Markus, E-mail: m.buescher@fz-juelich.de [Institut für Kernphysik and Jülich Center for Hadron Physics, Forschungszentrum Jülich, 52425 Jülich (Germany); Peter Grünberg Institut (PGI-6), Forschungszentrum Jülich, 52425 Jülich (Germany); Institute for Laser- and Plasma Physics, Heinrich-Heine Universität Düsseldorf, Universitätsstr. 1, 40225 Düsseldorf (Germany); Cerchez, Mirela; Swantusch, Marco; Toncian, Monika; Toncian, Toma; Willi, Oswald [Institute for Laser- and Plasma Physics, Heinrich-Heine Universität Düsseldorf, Universitätsstr. 1, 40225 Düsseldorf (Germany); Gibbon, Paul; Karmakar, Anupam [Institute for Advanced Simulation, Jülich Supercomputing Centre, Forschungszentrum Jülich, 52425 Jülich (Germany)

    2014-02-15

    We report on the successful use of a laser-driven few-MeV proton source to measure the differential cross section of a hadronic scattering reaction as well as on the measurement and simulation study of polarization observables of the laser-accelerated charged particle beams. These investigations were carried out with thin foil targets, illuminated by 100 TW laser pulses at the Arcturus laser facility; the polarization measurement is based on the spin dependence of hadronic proton scattering off nuclei in a Silicon target. We find proton beam polarizations consistent with zero magnitude which indicates that for these particular laser-target parameters the particle spins are not aligned by the strong magnetic fields inside the laser-generated plasmas.

  19. Femtosecond Polarization Phase Selective (PPS) High Magnetic Field Studies of Electron-Spin-Hole (ESH) Dynamics: New Tools for Ultrafast Imaging Fe-centered ESH Transfer Mechanisms Steps

    Science.gov (United States)

    Rupnik, Kresimir; Cooper, Benjamin; Dunne, Taylor; Gerosa, Katherine; Mercer, Kaitlyn; McGill, Stephen

    In previous work, new Nanoparticle-enzyme Based Hybrids (NEBH) synthesis methods were investigated for nanoparticles of different shapes and electron energies. These hybrids can provide electromagnetic-field-driven ESH separations and transfers to desired molecular locations. Of paramount biomedical interest are the activity centers (including Fe-clusters) in proteins that perform their intended function and help synthesize other molecules. In this work we discuss results of our recent in situ ESH dynamics measurements: we use PPS broad band pulses and ultrahigh, 25T, magnetic fields from Split-helix magnet at NHMFL. Work included multi-spectral domain PPS harmonic generations and PPS sum frequency generations. Model compounds, including cytochromes, were used for testing and calibrations and previously studied Fe-S enzymes were prepared for measurements. While PPS opto-magnetic methods are known for their insight into electronic structure, our femtosecond measurements can provide ultrafast dynamic imaging of ESH mechanisms decision making steps. UF-PPS Project, performed in part at NHMFL, supported by NSF CA No. DMR-1157490, and 0654118 and U.S. DOE.

  20. Modeling, hybridization, and optimal charging of electrical energy storage systems

    Science.gov (United States)

    Parvini, Yasha

    analytically. Efficiency analysis for constant power (CP) and optimal charging strategies under different charging times (slow and fast) was performed. In case of the lithium ion battery, the model included the electronic as well as polarization resistance. Furthermore, in order to investigate the influence of temperature on the internal resistance of the lithium ion battery, the optimal charging problem for a three state electro-thermal model was solved using dynamic programming (DP). The ability to charge electric vehicles is a pace equivalent to fueling a gasoline car will be a game changer in the widespread acceptability and feasibility of the electric vehicles. Motivated by the knowledge gained from the optimal charging study, the challenges facing the fast charging of lithium ion batteries are investigated. In this context, the suitable models for the study of fast charging, high rate anode materials, and different charging strategies are studied. The side effects of fast charging such as lithium plating and mechanical failure are also discussed. This dissertation has targeted some of the most challenging questions in the field of electrical energy storage systems and the reported results are applicable to a wide range of applications such as in electronic gadgets, medical devices, electricity grid, and electric vehicles.