WorldWideScience

Sample records for plasma spectroscopy time

  1. THz time-domain spectroscopy for tokamak plasma diagnostics

    Energy Technology Data Exchange (ETDEWEB)

    Causa, F.; Zerbini, M.; Buratti, P.; Gabellieri, L.; Pacella, D.; Romano, A.; Tuccillo, A. A.; Tudisco, O. [ASSOCIAZIONE EURATOM ENEA sulla Fusione, C. R. Frascati, via E. Fermi 45, 00044 Frascati (Roma) (Italy); Johnston, M. [Clarendon Laboratory, Department of Physics, University of Oxford, Parks Road, Oxford OX1 3PU (United Kingdom); Doria, A.; Gallerano, G. P.; Giovenale, E. [ENEA C.R. Frascati UTAPRAD, via E. Fermi 45, 00044 Frascati (Roma) (Italy)

    2014-08-21

    The technology is now becoming mature for diagnostics using large portions of the electromagnetic spectrum simultaneously, in the form of THz pulses. THz radiation-based techniques have become feasible for a variety of applications, e.g., spectroscopy, imaging for security, medicine and pharmaceutical industry. In particular, time-domain spectroscopy (TDS) is now being used also for plasma diagnostics in various fields of application. This technique is promising also for plasmas for fusion applications, where plasma characteristics are non-uniform and/or evolve during the discharge This is because THz pulses produced with femtosecond mode-locked lasers conveniently span the spectrum above and below the plasma frequency and, thus, can be used as very sensitive and versatile probes of widely varying plasma parameters. The short pulse duration permits time resolving plasma characteristics while the large frequency span permits a large dynamic range. The focus of this work is to present preliminary experimental and simulation results demonstrating that THz TDS can be realistically adapted as a versatile tokamak plasma diagnostic technique.

  2. Boosting persistence time of laser-induced plasma by electric arc discharge for optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Eschlböck-Fuchs, S., E-mail: simon.eschlboeck-fuchs@jku.at [Christian Doppler Laboratory for Laser-Assisted Diagnostics, Institute of Applied Physics, Johannes Kepler University Linz, A-4040 Linz (Austria); Kolmhofer, P.J.; Bodea, M.A.; Hechenberger, J.G.; Huber, N. [Christian Doppler Laboratory for Laser-Assisted Diagnostics, Institute of Applied Physics, Johannes Kepler University Linz, A-4040 Linz (Austria); Rössler, R. [voestalpine Stahl GmbH, A-4031 Linz (Austria); Pedarnig, J.D., E-mail: johannes.pedarnig@jku.at [Christian Doppler Laboratory for Laser-Assisted Diagnostics, Institute of Applied Physics, Johannes Kepler University Linz, A-4040 Linz (Austria)

    2015-07-01

    Plasma induced by nanosecond laser ablation is re-excited by a pulsed electric discharge and the parameters and optical emission of the plasma are measured. The discharge is a low-voltage and high-current electric arc that is triggered by the laser-induced plasma and slowly decaying with time. The optical emission of such combined plasma lasts up to several milliseconds which is much longer than without re-excitation (μs range). The emission spectra of re-excited plasma measured on different sample materials show higher line intensities than spectra measured by conventional laser-induced breakdown spectroscopy (LIBS). Moreover, emission lines of fluorine (spectral range 683–691 nm) and sulfur (range 520–550 nm) not detected by conventional LIBS become easily detectable with the combined plasma. The concentration of major components in metallurgical slags, as determined by calibration-free LIBS, agrees very well to the reference data evaluating the spectra taken from re-excited plasma. - Highlights: • Persistence time of laser-induced plasma in air is increased from ~ 10 μs to ~ 1 ms. • Laser-induced plasma triggers an electric arc discharge that boosts the plasma. • The combined laser-arc plasma is in LTE state over very long time (ms range). • CF-LIBS method delivers accurate results evaluating spectra of combined plasma. • Emission from S and F, not detected by LIBS, is detected with combined plasma.

  3. Plasma polarization spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, Takashi; Iwamae, Atsushi (eds.) [Kyoto Univ. (Japan). Dept. of Mechanical Engineering and Science

    2008-07-01

    Plasma Polarization Spectroscopy (PPS) is now becoming a standard diagnostic technique for working with laboratory plasmas. This new area needs a comprehensive framework, both experimental and theoretical. This book reviews the historical development of PPS, develops a general theoretical formulation to deal with this phenomenon, along with an overview of relevant cross sections, and reports on laboratory experiments so far performed. It also includes various facets that are interesting from this standpoint, e.g. X-ray lasers and effects of microwave irradiation. It also offers a timely discussion of instrumentation that is quite important in a practical PPS experiment. (orig.)

  4. Real-time imaging, spectroscopy, and structural investigation of cathodic plasma electrolytic oxidation of molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Stojadinović, Stevan, E-mail: sstevan@ff.bg.ac.rs; Tadić, Nenad; Šišović, Nikola M.; Vasilić, Rastko [Faculty of Physics, University of Belgrade, Studentski trg 12-16, 11000 Belgrade (Serbia)

    2015-06-21

    In this paper, the results of the investigation of cathodic plasma electrolytic oxidation (CPEO) of molybdenum at 160 V in a mixed solution of borax, water, and ethylene glycol are presented. Real-time imaging and optical emission spectroscopy were used for the characterization of the CPEO. During the process, vapor envelope is formed around the cathode and strong electric field within the envelope caused the generation of plasma discharges. The spectral line shape analysis of hydrogen Balmer line H{sub β} (486.13 nm) shows that plasma discharges are characterized by the electron number density of about 1.4 × 10{sup 21 }m{sup −3}. The electron temperature of 15 000 K was estimated by measuring molybdenum atomic lines intensity. Surface morphology, chemical, and phase composition of coatings formed by CPEO were characterized by scanning electron microscopy with energy dispersive x-ray spectroscopy and x-ray diffraction. The elemental components of CPEO coatings are Mo and O and the predominant crystalline form is MoO{sub 3}.

  5. Time-resolved tunable diode laser absorption spectroscopy of pulsed plasma.

    Science.gov (United States)

    Adámek, P; Olejníček, J; Čada, M; Kment, Š; Hubička, Z

    2013-07-15

    A method for time-resolved tunable diode laser absorption spectroscopy (LAS) has been developed. In this Letter, we describe in detail a developed electronic module that controls the time resolution of the LAS system. The transistor-transistor logic signal triggering the plasma pulse is used for generation of two signals: the first one triggers fine tuning of the laser wavelength and the second one controls time-defined signal sampling from the absorption detector. The described method and electronic system enable investigation of the temporal evolution of the density and temperature of selected particles in technological plasma systems. The high-power impulse magnetron sputtering system with a period of 10 ms and a duty cycle of 1% has been used to verify this method. The temporal evolution of argon metastable density was measured in the active part of the pulse and in the afterglow. The resulting density of Ar* displays a double-peak structure with a first peak in the plasma "ON" phase and a second peak in the afterglow approximately 1 ms after the end of the pulse.

  6. Laser plasma x-ray source for ultrafast time-resolved x-ray absorption spectroscopy.

    Science.gov (United States)

    Miaja-Avila, L; O'Neil, G C; Uhlig, J; Cromer, C L; Dowell, M L; Jimenez, R; Hoover, A S; Silverman, K L; Ullom, J N

    2015-03-01

    We describe a laser-driven x-ray plasma source designed for ultrafast x-ray absorption spectroscopy. The source is comprised of a 1 kHz, 20 W, femtosecond pulsed infrared laser and a water target. We present the x-ray spectra as a function of laser energy and pulse duration. Additionally, we investigate the plasma temperature and photon flux as we vary the laser energy. We obtain a 75 μm FWHM x-ray spot size, containing ∼10(6) photons/s, by focusing the produced x-rays with a polycapillary optic. Since the acquisition of x-ray absorption spectra requires the averaging of measurements from >10(7) laser pulses, we also present data on the source stability, including single pulse measurements of the x-ray yield and the x-ray spectral shape. In single pulse measurements, the x-ray flux has a measured standard deviation of 8%, where the laser pointing is the main cause of variability. Further, we show that the variability in x-ray spectral shape from single pulses is low, thus justifying the combining of x-rays obtained from different laser pulses into a single spectrum. Finally, we show a static x-ray absorption spectrum of a ferrioxalate solution as detected by a microcalorimeter array. Altogether, our results demonstrate that this water-jet based plasma source is a suitable candidate for laboratory-based time-resolved x-ray absorption spectroscopy experiments.

  7. Laser plasma x-ray source for ultrafast time-resolved x-ray absorption spectroscopy

    Directory of Open Access Journals (Sweden)

    L. Miaja-Avila

    2015-03-01

    Full Text Available We describe a laser-driven x-ray plasma source designed for ultrafast x-ray absorption spectroscopy. The source is comprised of a 1 kHz, 20 W, femtosecond pulsed infrared laser and a water target. We present the x-ray spectra as a function of laser energy and pulse duration. Additionally, we investigate the plasma temperature and photon flux as we vary the laser energy. We obtain a 75 μm FWHM x-ray spot size, containing ∼106 photons/s, by focusing the produced x-rays with a polycapillary optic. Since the acquisition of x-ray absorption spectra requires the averaging of measurements from >107 laser pulses, we also present data on the source stability, including single pulse measurements of the x-ray yield and the x-ray spectral shape. In single pulse measurements, the x-ray flux has a measured standard deviation of 8%, where the laser pointing is the main cause of variability. Further, we show that the variability in x-ray spectral shape from single pulses is low, thus justifying the combining of x-rays obtained from different laser pulses into a single spectrum. Finally, we show a static x-ray absorption spectrum of a ferrioxalate solution as detected by a microcalorimeter array. Altogether, our results demonstrate that this water-jet based plasma source is a suitable candidate for laboratory-based time-resolved x-ray absorption spectroscopy experiments.

  8. Fast, deep record length, time-resolved visible spectroscopy of plasmas using fiber grids

    Science.gov (United States)

    Brockington, Samuel; Case, Andrew; Cruz, Edward; Witherspoon, F. Douglas; Horton, Robert; Klauser, Ruth; Hwang, D. Q.

    2016-10-01

    HyperV Technologies is developing a fiber-coupled, deep-record-length, low-light camera head for performing high time resolution spectroscopy on visible emission from plasma events. New solid-state Silicon Photo-Multiplier (SiPM) chips are capable of single photon event detection and high speed data acquisition. By coupling the output of a spectrometer to an imaging fiber bundle connected to a bank of amplified SiPMs, time-resolved spectroscopic imagers of 100 to 1,000 pixels can be constructed. Target pixel performance is 10 Megaframes/sec with record lengths of up to 256,000 frames yielding 25.6 milliseconds of record at10 Megasamples/sec resolution. Pixel resolutions of 8 to 12 bits are pos- sible. Pixel pitch can be refined by using grids of 100 μm to 1000 μm diameter fibers. A prototype 32-pixel spectroscopic imager employing this technique was constructed and successfully tested at the University of California at Davis Compact Toroid Injection Experiment (CTIX) as a full demonstration of the concept. Experimental results will be dis-cussed, along with future plans for the Phase 2 project, and potential applications to plasma experiments . Work supported by USDOE SBIR Grant DE-SC0013801.

  9. Measurements of plasma temperature and electron density in laser-induced copper plasma by time-resolved spectroscopy of neutral atom and ion emissions

    Indian Academy of Sciences (India)

    V K Unnikrishnan; Kamlesh Alti; V B Kartha; C Santhosh; G P Gupta; B M Suri

    2010-06-01

    Plasma produced by a 355 nm pulsed Nd:YAG laser with a pulse duration of 6 ns focussed onto a copper solid sample in air at atmospheric pressure is studied spectroscopically. The temperature and electron density characterizing the plasma are measured by time-resolved spectroscopy of neutral atom and ion line emissions in the time window of 300–2000 ns. An echelle spectrograph coupled with a gated intensified charge coupled detector is used to record the plasma emissions. The temperature is obtained using the Boltzmann plot method and the electron density is determined using the Saha– Boltzmann equation method. Both parameters are studied as a function of delay time with respect to the onset of the laser pulse. The results are discussed. The time window where the plasma is optically thin and is also in local thermodynamic equilibrium (LTE), necessary for the laser-induced breakdown spectroscopy (LIBS) analysis of samples, is deduced from the temporal evolution of the intensity ratio of two Cu I lines. It is found to be 700–1000 ns.

  10. Evaluation of Penicillium digitatum sterilization using non-equilibrium atmospheric pressure plasma by terahertz time-domain spectroscopy

    Science.gov (United States)

    Hiraoka, Takehiro; Ebizuka, Noboru; Takeda, Keigo; Ohta, Takayuki; Kondo, Hiroki; Ishikawa, Kenji; Kawase, Kodo; Ito, Masafumi; Sekine, Makoto; Hori, Masaru

    2011-10-01

    Recently, the plasma sterilization has attracted much attention as a new sterilization technique that takes the place of spraying agricultural chemicals. The conventional methods for sterilization evaluation, was demanded to culture the samples for several days after plasma treatment. Then, we focused on Terahertz time-domain spectroscopy (THz-TDS). At the THz region, vibrational modes of biological molecules and fingerprint spectra of biologically-relevant molecules were also observed. In this study, our purpose was measurement of the fingerprint spectrum of the Penicillium digitatum (PD) spore and establishment of sterilization method by THz-TDS. The sample was 40mg/ml PD spore suspensions which dropped on cover glass. The atmospheric pressure plasma generated under the conditions which Ar gas flow was 3slm, and alternating voltage of 6kV was applied. The samples were exposed the plasma from 10mm distance for 10 minutes. We could obtain the fingerprint spectrum of the PD spore from 0.5 to 0.9THz. This result indicated the possibility of in-situ evaluation for PD sterilization using THz-TDS.

  11. Spectroscopy of Low Temperature Plasma

    CERN Document Server

    Ochkin, Vladimir N

    2009-01-01

    Providing an up-to-date overview on spectroscopical diagnostics of low temperature plasma Spectroscopy of Low Temperature Plasma covers the latest developments and techniques. Written by a distinguished scientist and experienced book author this text is applicable to many fields in materials and surface science as well as nanotechnology and contains numerous appendices with indispensable reference data.

  12. Plasma polarization spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, Takashi [Department of Engineering Physics and Mechanics, Graduate School of Engineering, Kyoto University, Kyoto (Japan)

    2000-03-01

    Polarization of radiation emitted from a plasma reflects the anisotropic properties of the plasma, especially the angular anisotropic distribution of electron velocities. Polarization has been observed on impurity ion lines from the WT-3 tokamak and the GAMMA-10 tandem mirror machines. The soft x-ray laser line from the neonlike germanium was also found polarized. (author)

  13. Plasma polarization spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Iwamae, Atsushi; Inoue, Takeru; Tanaka, Akihiro; Kawakami, Kazuki; Fujimoto, Takashi [Kyoto Univ., Dept. of Engineering Physics, Kyoto (Japan)

    2000-03-01

    Polarization of radiation emitted from plasma reflects the anisotropic properties of the plasma, especially the angular isotropic distribution of electron velocities. Polarization has been observed on impurity ion lines from the WT-3 tokamak and GAMMA 10 tandem mirror device. (author)

  14. Introduction to Plasma Spectroscopy

    CERN Document Server

    Kunze, H-J

    2009-01-01

    Based on lectures given at the Ruhr-University of Bochum for graduate students and postgraduates starting in plasma physics as well as from low- to high-density hot plasmas, this book introduces basic ideas and fundamental concepts and typical instrumentation from the X-ray to the infrared spectral regions

  15. Time-Resolved Optical Emission Spectroscopy Diagnosis of CO2 Laser-Produced SnO2 Plasma

    Science.gov (United States)

    Lan, Hui; Wang, Xinbing; Zuo, Duluo

    2016-09-01

    The spectral emission and plasma parameters of SnO2 plasmas have been investigated. A planar ceramic SnO2 target was irradiated by a CO2 laser with a full width at half maximum of 80 ns. The temporal behavior of the specific emission lines from the SnO2 plasma was characterized. The intensities of Sn I and Sn II lines first increased, and then decreased with the delay time. The results also showed a faster decay of Sn I atoms than that of Sn II ionic species. The temporal evolutions of the SnO2 plasma parameters (electron temperature and density) were deduced. The measured temperature and density of SnO2 plasma are 4.38 eV to 0.5 eV and 11.38×1017 cm-3 to 1.1×1017 cm-3, for delay times between 0.1 μs and 2.2 μs. We also investigated the effect of the laser pulse energy on SnO2 plasma. supported by National Natural Science Foundation of China (No. 11304235) and the Director Fund of WNLO

  16. Characterization of the ionization degree evolution of the PF-400J plasma sheath by means of time resolved optical spectroscopy

    Science.gov (United States)

    Avaria, G.; Cuadrado, O.; Moreno, J.; Pavez, C.; Soto, L.

    2016-05-01

    Spectral measurements in the visible range of the plasma sheath ionization degree evolution on the plasma focus device PF-400J are presented. The measurements were done with temporal and spatial resolution in a plasma focus device of low stored energy: PF-400J (176-539 J, 880 nF, 20-35 kV, quarter period ∼ 300ns) [1]. An ICCD was attached to a 0.5 m focal length visible spectrometer, which enabled the acquisition of time resolved spectrum with 20 ns integration time throughout the whole current pulse evolution. The spatial resolution was attained using a set of lenses which allowed the focusing of a small volume of the plasma sheath in different positions of the inter-electrode space. Discharges were carried out in mixtures of Hydrogen with gases in different proportions: 5% Neon, 5% Krypton and 2% Nitrogen. Discharges using Neon as an impurity showed no ionization of the gas, just a very low intensity emission of Ne I at times much larger than the maximum current. Nitrogen, on the other hand, showed a high ionization reaching N V (N 4+) at the end of the axial phase, with a distinctive evolution of the ionization degree as the plasma sheath moved towards the end of the electrodes. A mixed result was found when using Krypton, since the ionization degree only reached levels around Kr II/III, even though it has an ionization potential lower than Neon.

  17. BOOK REVIEW: Principles of Plasma Spectroscopy

    Science.gov (United States)

    Osterheld, A. L.

    1998-08-01

    This book gives a comprehensive treatment of plasma spectroscopy, the quantitative study of line and continuous radiation from high temperature plasmas. This highly interdisciplinary field combines elements of atomic, plasma and statistical physics, and has wide application to simulations and diagnostics of laboratory and astrophysical plasmas. Plasma spectroscopy is naturally intertwined with magnetic and inertial fusion energy science. Radiative processes in plasmas are important in the design of fusion facilities, and can be used to diagnose and control conditions in fusion plasmas. In turn, fusion scientists and facilities have played a central role in developing plasma spectroscopy theory and applications. The book covers radiation from plasmas, spectral line broadening, atomic processes in plasmas and level kinetic models, radiative transfer and applications to spectroscopic plasma diagnostics. It is successful both as an introductory text and as a source book of theoretical and experimental research. The book presents a broad development of the theoretical foundations of these topics, and discusses the seminal papers and critical experiments. There is a strong emphasis on applications of plasma spectroscopy, primarily to plasma diagnostics and calculations of radiative cooling rates. Extensive references (current through the end of 1995) point readers to original material and detailed discussions of advanced topics. Of course, a single text cannot treat all aspects of plasma spectroscopy in depth. The strongest and most detailed section of the book is a long chapter on spectral line broadening. For me, the most significant omission is lack of a discussion of laser assisted transitions which can occur in plasmas produced by high intensity lasers. The book was intentionally written to be accessible to young researchers and graduate students. The level is roughly that of a graduate text. It assumes some familiarity with quantum mechanics and statistical

  18. Kinetics and spectroscopy of low temperature plasmas

    CERN Document Server

    Loureiro, Jorge

    2016-01-01

    This is a comprehensive textbook designed for graduate and advanced undergraduate students. Both authors rely on more than 20 years of teaching experience in renowned Physics Engineering courses to write this book addressing the students’ needs. Kinetics and Spectroscopy of Low Temperature Plasmas derives in a full self-consistent way the electron kinetic theory used to describe low temperature plasmas created in the laboratory with an electrical discharge, and presents the main optical spectroscopic diagnostics used to characterize such plasmas. The chapters with the theoretical contents make use of a deductive approach in which the electron kinetic theory applied to plasmas with basis on the electron Boltzmann equation is derived from the basic concepts of Statistical and Plasma Physics. On the other hand, the main optical spectroscopy diagnostics used to characterize experimentally such plasmas are presented and justified from the point of view of the Atomic and Molecular Physics. Low temperature plasmas...

  19. Zeeman Spectroscopy of Tokamak Edge Plasmas

    Science.gov (United States)

    Hey, J. D.; Chu, C. C.; Mertens, Ph.

    2002-12-01

    Zeeman spectroscopy is a valuable tool both for diagnostic purposes, and for more fundamental studies of atomic and molecular processes in the boundary region of magnetically confined fusion plasmas (B ≃ 1 to 10 T). The method works well when the Zeeman (Paschen-Back) effect plays an important, or dominant, rôle in relation to other broadening mechanisms (Doppler, Stark, resonant excitation transfer) in determining the spectral line shape. For impurity species identification and temperature determination, Zeeman spectroscopy has advantages over charge-exchange recombination spectroscopy from highly excited radiator states, since spectral features practically unique to the species under investigation are analysed. It also provides useful information on probable mechanisms of line production (e.g. sputtering mechanisms, electron impact-induced dissociative excitation from molecules in the edge plasma), and on the temperature evolution of lower charge states in the process of convection inwards or diffusion outwards from the hotter plasma interior. Where different physical processes are responsible for different sections of the line profile — especially in the case of hydrogen isotopes — Zeeman spectroscopy can provide a set of characteristic temperatures for each section. The method is introduced in both passive and active spectroscopy, and general principles of the Zeeman effect are discussed with special reference to régimes of interest for the tokamak. Relevant physical processes (sputtering mechanisms, electron impact-induced dissociative excitation from molecules in the edge plasma, and ion-atom collisional heating mechanisms) are illustrated by sample spectra.

  20. Plasma Polarization Spectroscopy and collision cross sections

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, Takashi; Nakai, Manabu [Dept. of Engineering Physics and Mechanics, Graduate School of Engineering, Kyoto Univ. (Japan)

    2000-01-01

    In Plasma Polarization Spectroscopy (PPS), we observe the polarized spectral lines emitted from a plasma. For berylliumlike oxygen lines from a tokamak plasma the polarization feature is interpreted as due to the anisotropic velocity distribution of electrons which excite the ions. In this interpretation in terms of the population-alignment collisional-radiative (PACR) model various collision processes are involved concerning the population and the alignment, e.g., transfer of the alignment, and the coherence by collisional excitation and production of an alignment from a population by elastic collisions. These latter processes are little known so far. (author)

  1. Mid infrared emission spectroscopy of carbon plasma

    Science.gov (United States)

    Nemes, Laszlo; Brown, Ei Ei; Yang, Clayton S.-C.; Hommerich, Uwe

    2017-01-01

    Mid infrared time-resolved emission spectra were recorded from laser-induced carbon plasma. These spectra constitute the first study of carbon materials LIB spectroscopy in the mid infrared range. The carbon plasma was induced using a Q-switched Nd: YAG laser. The laser beam was focused to high purity graphite pellets mounted on a translation stage. Mid infrared emission from the plasma in an atmospheric pressure background gas was detected by a cooled HgCdTe detector in the range 4.4-11.6 μm, using long-pass filters. LIB spectra were taken in argon, helium and also in air. Despite a gate delay of 10 μs was used there were strong backgrounds in the spectra. Superimposed on this background broad and noisy emission bands were observed, the form and position of which depended somewhat on the ambient gas. The spectra were digitally smoothed and background corrected. In argon, for instance, strong bands were observed around 4.8, 6.0 and 7.5 μm. Using atomic spectral data by NIST it could be concluded that carbon, argon, helium and nitrogen lines from neutral and ionized atoms are very weak in this spectral region. The width of the infrared bands supports molecular origin. The infrared emission bands were thus compared to vibrational features of carbon molecules (excluding C2) of various sizes on the basis of previous carbon cluster infrared absorption and emission spectroscopic analyses in the literature and quantum chemical calculations. Some general considerations are given about the present results.

  2. Mid infrared emission spectroscopy of carbon plasma.

    Science.gov (United States)

    Nemes, Laszlo; Brown, Ei Ei; S-C Yang, Clayton; Hommerich, Uwe

    2017-01-05

    Mid infrared time-resolved emission spectra were recorded from laser-induced carbon plasma. These spectra constitute the first study of carbon materials LIB spectroscopy in the mid infrared range. The carbon plasma was induced using a Q-switched Nd: YAG laser. The laser beam was focused to high purity graphite pellets mounted on a translation stage. Mid infrared emission from the plasma in an atmospheric pressure background gas was detected by a cooled HgCdTe detector in the range 4.4-11.6μm, using long-pass filters. LIB spectra were taken in argon, helium and also in air. Despite a gate delay of 10μs was used there were strong backgrounds in the spectra. Superimposed on this background broad and noisy emission bands were observed, the form and position of which depended somewhat on the ambient gas. The spectra were digitally smoothed and background corrected. In argon, for instance, strong bands were observed around 4.8, 6.0 and 7.5μm. Using atomic spectral data by NIST it could be concluded that carbon, argon, helium and nitrogen lines from neutral and ionized atoms are very weak in this spectral region. The width of the infrared bands supports molecular origin. The infrared emission bands were thus compared to vibrational features of carbon molecules (excluding C2) of various sizes on the basis of previous carbon cluster infrared absorption and emission spectroscopic analyses in the literature and quantum chemical calculations. Some general considerations are given about the present results.

  3. Time-resolved vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Tokmakoff, Andrei [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Champion, Paul [Northeastern Univ., Boston, MA (United States); Heilweil, Edwin J. [National Inst. of Standards and Technology (NIST), Boulder, CO (United States); Nelson, Keith A. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Ziegler, Larry [Boston Univ., MA (United States)

    2009-05-14

    This document contains the Proceedings from the 14th International Conference on Time-Resolved Vibrational Spectroscopy, which was held in Meredith, NH from May 9-14, 2009. The study of molecular dynamics in chemical reaction and biological processes using time-resolved spectroscopy plays an important role in our understanding of energy conversion, storage, and utilization problems. Fundamental studies of chemical reactivity, molecular rearrangements, and charge transport are broadly supported by the DOE's Office of Science because of their role in the development of alternative energy sources, the understanding of biological energy conversion processes, the efficient utilization of existing energy resources, and the mitigation of reactive intermediates in radiation chemistry. In addition, time-resolved spectroscopy is central to all fiveof DOE's grand challenges for fundamental energy science. The Time-Resolved Vibrational Spectroscopy conference is organized biennially to bring the leaders in this field from around the globe together with young scientists to discuss the most recent scientific and technological advances. The latest technology in ultrafast infrared, Raman, and terahertz spectroscopy and the scientific advances that these methods enable were covered. Particular emphasis was placed on new experimental methods used to probe molecular dynamics in liquids, solids, interfaces, nanostructured materials, and biomolecules.

  4. TIME-RESOLVED VIBRATIONAL SPECTROSCOPY

    Energy Technology Data Exchange (ETDEWEB)

    Andrei Tokmakoff, MIT (Conference Chair); Paul Champion, Northeastern University; Edwin J. Heilweil, NIST; Keith A. Nelson, MIT; Larry Ziegler, Boston University

    2009-05-14

    This document contains the Proceedings from the 14th International Conference on Time-Resolved Vibrational Spectroscopy, which was held in Meredith, NH from May 9-14, 2009. The study of molecular dynamics in chemical reaction and biological processes using time-resolved spectroscopy plays an important role in our understanding of energy conversion, storage, and utilization problems. Fundamental studies of chemical reactivity, molecular rearrangements, and charge transport are broadly supported by the DOE’s Office of Science because of their role in the development of alternative energy sources, the understanding of biological energy conversion processes, the efficient utilization of existing energy resources, and the mitigation of reactive intermediates in radiation chemistry. In addition, time-resolved spectroscopy is central to all five of DOE’s grand challenges for fundamental energy science. The Time-Resolved Vibrational Spectroscopy conference is organized biennially to bring the leaders in this field from around the globe together with young scientists to discuss the most recent scientific and technological advances. The latest technology in ultrafast infrared, Raman, and terahertz spectroscopy and the scientific advances that these methods enable were covered. Particular emphasis was placed on new experimental methods used to probe molecular dynamics in liquids, solids, interfaces, nanostructured materials, and biomolecules.

  5. Analysis and differentiation of seminal plasma via polarized SERS spectroscopy

    Directory of Open Access Journals (Sweden)

    Chen X

    2012-12-01

    Full Text Available Xiwen Chen,1,* Zufang Huang,1,* Shangyuan Feng,1 Jinhua Chen,2 Lan Wang,1 Peng Lu,1 Haishan Zeng,3 Rong Chen1 1Key Laboratory of Opto-Electronic Science and Technology for Medicine of Ministry of Education, Fujian Provincial Key Laboratory for Photonics Technology, Fujian Normal University, Fuzhou, China; 2Fujian Provincial Hospital, Fuzhou, China; 3Imaging Unit – Integrative Oncology Department, British Columbia Cancer Agency Research Centre, Vancouver, BC, Canada*These authors contributed equally to this workAbstract: Polarized surface-enhanced Raman scattering (SERS spectroscopy was applied for obtaining biochemical information about the seminal plasma. The effect of different laser polarizations (nonpolarized, linear-polarized, right-handed circularly polarized, and left-handed circularly polarized on seminal plasma SERS spectroscopy was explored for the first time. The diagnostic performance in differentiating abnormal seminal plasma (n = 37 from normal seminal plasma (n = 24 was evaluated. A combination of principal component analysis (PCA and linear discriminant analysis (LDA was employed to develop diagnostic algorithms. Classification results of different laser polarizations demonstrated different diagnostic sensitivities and specificities, among which, left-handed circularly polarized laser excitation showed the best diagnostic result (95.8% sensitivity and 64.9% specificity. Our exploratory study demonstrated that SERS spectroscopy with left-handed circularly polarized laser excitation has the potential for becoming a new diagnostic method in semen-quality assessment.Keywords: SERS, seminal plasma, PCA-LDA, polarized laser excitation, silver nanoparticles, biomolecule chirality

  6. Plasma spectroscopy using optical vortex laser

    Science.gov (United States)

    Yoshimura, Shinji; Aramaki, Mitsutoshi; Terasaka, Kenichiro; Toda, Yasunori; Czarnetzki, Uwe; Shikano, Yutaka

    2014-10-01

    Laser spectroscopy is a useful tool for nonintrusive plasma diagnostics; it can provide many important quantities in a plasma such as temperature, density, and flow velocity of ions and neutrals from the spectrum obtained by scanning the frequency of narrow bandwidth laser. Obtainable information is, however, limited in principle to the direction parallel to the laser path. The aim of this study is to introduce a Laguerre-Gaussian beam, which is called as optical vortex, in place of a widely used Hermite-Gaussian beam. One of the remarkable properties of the Laguerre-Gaussian beam is that it carries an angular momentum in contrast to the Hermite-Gaussian beam. It follows that particles in the laser beam feel the Doppler effect even in the transverse direction of the laser path. Therefore it is expected that the limitation imposed by the laser path can be overcome by using an optical vortex laser. The concept of optical vortex spectroscopy, the development of the laser system, and some preliminary results of a proof-of-principle experiment will be presented. This work is performed with the support and under the auspices of NINS young scientists collaboration program for cross-disciplinary study, NIFS collaboration research program (NIFS13KOAP026), and JSPS KAKENHI Grant Number 25287152.

  7. Active plasma resonance spectroscopy: A functional analytic description

    OpenAIRE

    Lapke, Martin; Oberrath, Jens; Mussenbrock, Thomas; Brinkmann, Ralf Peter

    2012-01-01

    The term "Active Plasma Resonance Spectroscopy" refers to a class of diagnostic methods which employ the ability of plasmas to resonate on or near the plasma frequency. The basic idea dates back to the early days of discharge physics: An signal in the GHz range is coupled to the plasma via an electrical probe; the spectral response is recorded, and then evaluated with a mathematical model to obtain information on the electron density and other plasma parameters. In recent years, the concept h...

  8. Ultrabroadband THz time-domain spectroscopy of biomolecular crystals

    DEFF Research Database (Denmark)

    Kaltenecker, Korbinian J.; Engelbrecht, Sebastian; Iwaszczuk, Krzysztof

    2016-01-01

    Ultrabroadband THz time-domain spectroscopy based on two-color plasma generation and air biased coherent detection is used for the investigation of molecular dynamics of crystalline materials in the frequency range from 0.3 THz to 20 THz. We show that the spectral features in this extended...

  9. Cavity Ring-Down Spectroscopy of Etching Plasmas

    Science.gov (United States)

    Booth, Jean-Paul; Cunge, Gilles; Biennier, Ludovic; Romanini, Daniele; Katachanov, Alexander

    1999-10-01

    Many of the reactive species of interest in etching plasmas absorb light in the UV spectral region (200 ~ 300 nm). Measurement of these weak absorbances (10-2 ~ 10-4 for a single pass) allows their absolute concentration to be determined. Previously, low-resolution spectra have been obtained using broad-band absorption spectroscopy, using a Xe arc lamp as the light source and a small monochromator equipped with a CCD Camera. Here we report high-resolution measurements using the recently developed Cavity Ring-Down Spectroscopy (CRDS) technique. The pulsed tunable output of an excimer pumped doubled dye laser was injected into a high-Q optical cavity in which the plasma is included. The absorbance as a function of wavelength is then deduced from the lifetime of the light pulse in the cavity. This technique offers the possibility of real-time (1 second) absolute concentration measurements. Results have been obtained for the detection of CF, CF_2, AlF and SiF2 radicals in capacitively-coupled radio-frequency plasmas in fluorocarbon gases. However, the deduction of absolute concentrations from CRDS spectra is complicated by the phenomenon of non-single exponential decays when the line-width of the laser is greater then that of the transition observed.

  10. Two-dimensional fluorescence spectroscopy of laser-produced plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Harilal, Sivanandan S.; LaHaye, Nicole L.; Phillips, Mark C.

    2016-08-01

    We use a two-dimensional laser-induced fluorescence spectroscopy technique to measure the coupled absorption and emission properties of atomic species in plasmas produced via laser ablation of solid aluminum targets at atmospheric pressure. Emission spectra from the Al I 394.4 nm and Al I 396.15 nm transitions are measured while a frequency-doubled, continuous-wave, Ti:Sapphire laser is tuned across the Al I 396.15 nm transition. The resulting two-dimensional spectra show the energy coupling between the two transitions via increased emission intensity for both transitions during resonant absorption of the continuous-wave laser at one transition. Time-delayed and gated detection of the emission spectrum is used to isolate the resonantly-excited fluorescence emission from the thermally-excited emission from the plasma. In addition, the tunable continuous-wave laser measures the absorption spectrum of the Al transition with ultra-high resolution after the plasma has cooled, resulting in narrower spectral linewidths than observed in emission spectra. Our results highlight that fluorescence spectroscopy employing continuous-wave laser re-excitation after pulsed laser ablation combines benefits of both traditional emission and absorption spectroscopic methods.

  11. Applying Quantum Cascade Laser Spectroscopy in Plasma Diagnostics

    Directory of Open Access Journals (Sweden)

    Jürgen Röpcke

    2016-07-01

    Full Text Available The considerably higher power and wider frequency coverage available from quantum cascade lasers (QCLs in comparison to lead salt diode lasers has led to substantial advances when QCLs are used in pure and applied infrared spectroscopy. Furthermore, they can be used in both pulsed and continuous wave (cw operation, opening up new possibilities in quantitative time resolved applications in plasmas both in the laboratory and in industry as shown in this article. However, in order to determine absolute concentrations accurately using pulsed QCLs, careful attention has to be paid to features like power saturation phenomena. Hence, we begin with a discussion of the non-linear effects which must be considered when using short or long pulse mode operation. More recently, cw QCLs have been introduced which have the advantage of higher power, better spectral resolution and lower fluctuations in light intensity compared to pulsed devices. They have proved particularly useful in sensing applications in plasmas when very low concentrations have to be monitored. Finally, the use of cw external cavity QCLs (EC-QCLs for multi species detection is described, using a diagnostics study of a methane/nitrogen plasma as an example. The wide frequency coverage of this type of QCL laser, which is significantly broader than from a distributed feedback QCL (DFB-QCL, is a substantial advantage for multi species detection. Therefore, cw EC-QCLs are state of the art devices and have enormous potential for future plasma diagnostic studies.

  12. C-axis Josephson plasma resonance observed in Tl(2)Ba(2)CaCu(2)O(8) superconducting thin films by use of terahertz time-domain spectroscopy.

    Science.gov (United States)

    Thorsmølle, V K; Averitt, R D; Maley, M P; Bulaevskii, L N; Helm, C; Taylor, A J

    2001-08-15

    We have unambiguously observed the c -axis Josephson plasma resonance (JPR) in high-critical-temperature (T(c)) cuprate (Tl(2)Ba(2)CaCu(2)O(8)) superconducting thin films, employing terahertz time-domain spectroscopy in transmission as a function of temperature in zero magnetic field. These are believed to be the first measurements of the JPR temperature dependence of a high-T(c) material in transmission. With increasing temperature, the JPR shifts from 705 GHz at 10 K to ~170 GHz at 98 K, corresponding to an increase in c-axis penetration depth from 22.4+/-0.6mum to 94+/-9mum . The linewidth of the JPR peak increases with temperature, which indicates an increase in the quasi-particle scattering rate. We have probed the onset of the c -axis phase coherence to ~0.95T(c) . The JPR vanishes above T(c) as expected.

  13. Proceedings of the Japan-US workshop on plasma polarization spectroscopy and the international seminar on plasma polarization spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, Takashi; Beiersdorfer, Peter [eds.

    1998-06-01

    The international meeting on Plasma Polarization Spectroscopy (PPS) was held in Kyoto during January 26-28, 1998. This Proceedings book includes the papers of the talks given at the meeting. These include: overviews of PPS from the aspects of atomic physics, and of plasma physics; several PPS and MSE (motional Stark effect) experiments on magnetically confined plasmas and a laser-produced plasma; polarized laser-induced fluorescence spectroscopy, several experiments on EBITs (electron beam ion trap) and their theoretical interpretations; polarized profiles of spectral lines, basic formulation of PPS; inelastic and elastic electron collisions leading to polarized atomic states; polarization in recombining plasma; relationship between the collisional polarization relaxation and the line broadening; and characteristics of the plasma produced by very short pulse and high power laser irradiation. The 19 of the presented papers are indexed individually. (J.P.N.)

  14. Near-infrared spectroscopy for burning plasma diagnostic applications.

    Science.gov (United States)

    Soukhanovskii, V A

    2008-10-01

    Ultraviolet and visible (UV-VIS, 200-750 nm) atomic spectroscopy of neutral and ionized fuel species (H, D, T, and Li) and impurities (e.g., He, Be, C, and W) is a key element of plasma control and diagnosis on International Thermonuclear Experimental Reactor and future magnetically confined burning plasma experiments (BPXs). Spectroscopic diagnostic implementation and performance issues that arise in the BPX harsh nuclear environment in the UV-VIS range, e.g., degradation of first mirror reflectivity under charge-exchange atom bombardment (erosion) and impurity deposition, permanent and dynamic loss of window, and optical fiber transmission under intense neutron and gamma-ray fluxes, are either absent or not as severe in the near-infrared (NIR, 750-2000 nm) range. An initial survey of NIR diagnostic applications has been undertaken on the National Spherical Torus Experiment. It is demonstrated that NIR spectroscopy can be used for machine protection and plasma control applications, as well as contribute to plasma performance evaluation and physics studies. Emission intensity estimates demonstrate that NIR measurements are possible in the BPX plasma operating parameter range. Complications in the NIR range due to the parasitic background emissions are expected to occur at very high plasma densities, low impurity densities, and at high plasma-facing component temperatures.

  15. Spectroscopy of laser-produced plasmas: Setting up of high-performance laser-induced breakdown spectroscopy system

    Indian Academy of Sciences (India)

    V K Unnikrishnan; Kamlesh Alti; Rajesh Nayak; Rodney Bernard; V B Kartha; C Santhosh; G P Gupta; B M Suri

    2010-12-01

    It is a well-known fact that laser-induced breakdown spectroscopy (LIBS) has emerged as one of the best analytical techniques for multi-elemental compositional analysis of samples. We report assembling and optimization of LIBS set up using high resolution and broad-range echelle spectrograph coupled to an intensified charge coupled device (ICCD) to detect and quantify trace elements in environmental and clinical samples. Effects of variations of experimental parameters on spectroscopy signals of copper and brass are reported. Preliminary results of some plasma diagnostic calculations using recorded time-resolved optical emission signals are also reported for brass samples.

  16. Elemental analysis of coal by tandem laser induced breakdown spectroscopy and laser ablation inductively coupled plasma time of flight mass spectrometry

    Science.gov (United States)

    Dong, Meirong; Oropeza, Dayana; Chirinos, José; González, Jhanis J.; Lu, Jidong; Mao, Xianglei; Russo, Richard E.

    2015-07-01

    The capabilities and analytical benefits of combined LIBS and LA-ICP-MS were evaluated for the analysis of coal samples. The ablation system consisted of a Nd:YAG laser operated 213 nm. A Czerny-turner spectrograph with ICCD detector and time-of-flight based mass spectrometer were utilized for LIBS and ICP-MS detection, respectively. This tandem approach allows simultaneous determination of major and minor elements (C, Si, Ca, Al, Mg), and trace elements (V, Ba, Pb, U, etc.) in the coal samples. The research focused on calibration strategies, specifically the use of univariate and multivariate data analysis on analytical performance. Partial least square regression (PLSR) was shown to minimize and compensate for matrix effects in the emission and mass spectra improving quantitative analysis by LIBS and LA-ICP-MS, respectively. The correlation between measurements from these two techniques demonstrated that mass spectral data combined with LIBS emission measurements by PLSR improved the accuracy and precision for quantitative analysis of trace elements in coal.

  17. Elemental analysis of coal by tandem laser induced breakdown spectroscopy and laser ablation inductively coupled plasma time of flight mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Meirong [School of Electric Power, South China University of Technology, Guangzhou, Guangdong 510640 (China); Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 (United States); Oropeza, Dayana [Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 (United States); Chirinos, José [Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 (United States); Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Caracas 1041a (Venezuela, Bolivarian Republic of); González, Jhanis J. [Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 (United States); Lu, Jidong [School of Electric Power, South China University of Technology, Guangzhou, Guangdong 510640 (China); Mao, Xianglei [Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 (United States); Russo, Richard E., E-mail: RERusso@lbl.gov [Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 (United States)

    2015-07-01

    The capabilities and analytical benefits of combined LIBS and LA-ICP-MS were evaluated for the analysis of coal samples. The ablation system consisted of a Nd:YAG laser operated 213 nm. A Czerny-turner spectrograph with ICCD detector and time-of-flight based mass spectrometer were utilized for LIBS and ICP-MS detection, respectively. This tandem approach allows simultaneous determination of major and minor elements (C, Si, Ca, Al, Mg), and trace elements (V, Ba, Pb, U, etc.) in the coal samples. The research focused on calibration strategies, specifically the use of univariate and multivariate data analysis on analytical performance. Partial least square regression (PLSR) was shown to minimize and compensate for matrix effects in the emission and mass spectra improving quantitative analysis by LIBS and LA-ICP-MS, respectively. The correlation between measurements from these two techniques demonstrated that mass spectral data combined with LIBS emission measurements by PLSR improved the accuracy and precision for quantitative analysis of trace elements in coal. - Highlights: • Tandem LIBS LA-ICP-MS • Simultaneous determination of major and minor elements and trace elements in the coal samples. • Extended Dynamic Range • Correlation between LIBS with LA-ICP-MS demonstrated improved the accuracy and precision for quantitative analysis of coal.

  18. Optical Emission Spectroscopy of an Atmospheric Pressure Plasma Jet During Tooth Bleaching Gel Treatment.

    Science.gov (United States)

    Šantak, Vedran; Zaplotnik, Rok; Tarle, Zrinka; Milošević, Slobodan

    2015-11-01

    Optical emission spectroscopy was performed during atmospheric pressure plasma needle helium jet treatment of various tooth-bleaching gels. When the gel sample was inserted under the plasma plume, the intensity of all the spectral features increased approximately two times near the plasma needle tip and up to two orders of magnitude near the sample surface. The color change of the hydroxylapatite pastille treated with bleaching gels in conjunction with the atmospheric pressure plasma jet was found to be in correlation with the intensity of OH emission band (309 nm). Using argon as an additive to helium flow (2 L/min), a linear increase (up to four times) of OH intensity and, consequently, whitening (up to 10%) of the pastilles was achieved. An atmospheric pressure plasma jet activates bleaching gel, accelerates OH production, and accelerates tooth bleaching (up to six times faster).

  19. Evaluation of two-beam spectroscopy as a plasma diagnostic

    Energy Technology Data Exchange (ETDEWEB)

    Billard, B.D.

    1980-04-01

    A two-beam spectroscopy (TBS) system is evaluated theoretically and experimentally. This new spectroscopic technique uses correlations between components of emitted light separated by a small difference in angle of propagation. It is thus a non-perturbing plasma diagnostic which is shown to provide local (as opposed to line-of-sight averaged) information about fluctuations in the density of light sources within a plasma - information not obtainable by the usual spectroscopic methods. The present design is an improvement on earlier systems proposed in a thesis by Rostler.

  20. Plasma temperature clamping in filamentation laser induced breakdown spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Harilal, Sivanandan S.; Yeak, J.; Phillips, Mark C.

    2015-10-19

    Ultrafast laser filament induced breakdown spectroscopy is a very promising method for remote material detection. We present characteristics of plasmas generated in a metal target by laser filaments in air. Our measurements show that the temperature of the ablation plasma is clamped along the filamentation channel due to intensity clamping in a filament. Nevertheless, significant changes in radiation intensity are noticeable, and this is essentially due to variation in the number density of emitting atoms. The present results also partly explains the reason for the occurrence of atomic plume during fs LIBS in air compared to long-pulse ns LIBS.

  1. Active plasma resonance spectroscopy: A functional analytic description

    CERN Document Server

    Lapke, Martin; Mussenbrock, Thomas; Brinkmann, Ralf Peter

    2012-01-01

    The term "Active Plasma Resonance Spectroscopy" refers to a class of diagnostic methods which employ the ability of plasmas to resonate on or near the plasma frequency. The basic idea dates back to the early days of discharge physics: An signal in the GHz range is coupled to the plasma via an electrical probe; the spectral response is recorded, and then evaluated with a mathematical model to obtain information on the electron density and other plasma parameters. In recent years, the concept has found renewed interest as a basis of industry compatible plasma diagnostics. This paper analyzes the diagnostics technique in terms of a general description based on functional analytic (or Hilbert Space) methods which hold for arbitrary probe geometries. It is shown that the response function of the plasma-probe system can be expressed as a matrix element of the resolvent of an appropriately defined dynamical operator. A specialization of the formalism for a symmetric probe desing is given, as well as an interpreation...

  2. Visible-light spectroscopy of pulsed-power plasmas (invited)

    Science.gov (United States)

    Arad, R.; Clark, R. E. H.; Dadusc, G.; Davara, G.; Duvall, R. E.; Fisher, A.; Fisher, V.; Foord, M. E.; Fruchtman, A.; Gregorian, L.; Krasik, Ya.; Litwin, C.; Maron, Y.; Perelmutter, L.; Sarfaty, M.; Sarid, E.; Shkolnikova, S.; Shpitalnik, R.; Troyansky, L.; Weingarten, A.

    1992-10-01

    We describe the investigations of the plasma behavior in three pulsed-power systems: a magnetically insulated ion diode, and plasma opening switch, and a gas-puffed Z pinch. Recently developed spectroscopic diagnostic techniques allow for measurements with relatively high spectral, temporal, and spatial resolutions. The particle velocity and density distributions within a few tens of microns from the dielectric-anode surface are observed using laser spectroscopy. Fluctuating electric fields in the plasma are inferred from anisotropic Stark broadening. For the plasma opening switch experiment, a novel gaseous plasma source was developed which is mounted inside the high-voltage inner conductor. The properties of this source, together with spectroscopic observations of the electron density and particle velocities of the injected plasma, are described. Emission line intensities during the switch operation are discussed. In the Z-pinch experiment, spectral emission-line profiles of various charge-state ions are studied during the implosion phase. Radial velocity distributions are observed from the line Doppler shifts and widths.

  3. Space and time resolved spectroscopy of laser-produced plasmas: A study of density-sensitive x-ray transitions in helium-like and neon-like ions

    Energy Technology Data Exchange (ETDEWEB)

    Young, Bruce Kai Fong

    1988-09-01

    The determination of level populations and detailed population mechanisms in dense plasmas has become an increasingly important problem in atomic physics. In this work, the density variation of line intensities and level populations in aluminum K-shell and molybdenum and silver L-shell emission spectra have been measured from high-powered, laser-produced plasmas. For each case, the density dependence of the observed line emission is due to the effect of high frequency electron-ion collisions on metastable levels. The density dependent line intensities vary greatly in laser-produced plasmas and can be used to extract detailed information concerning the population kinetics and level populations of the ions. The laser-plasmas had to be fully characterized in order to clearly compare the observed density dependence with atomic theory predictions. This has been achieved through the combined use of new diagnostic instruments and microdot targets which provided simultaneously space, time, and spectrally resolved data. The plasma temperatures were determined from the slope of the hydrogen-like recombination continuum. The time resolved electron density profiles were measured using multiple frame holographic interferometry. Thus, the density dependence of K-shell spectral lines could be clearly examined, independent of assumptions concerning the dynamics of the plasma. In aluminum, the electron density dependence of various helium-like line intensity ratios were measured. Standard collisional radiative equilibrium models fail to account for the observed density dependence measured for the ''He/sub ..cap alpha..//IC'' ratio. Instead, a quasi-steady state atomic model based on a purely recombining plasma is shown to accurately predict the measured density dependence. This same recombining plasma calculation successfully models the density dependence of the high-n ''He/sub ..gamma..//He/sub ..beta../'' and ''He/sub delta

  4. E × B ion mass spectroscopy in magnetised plasmas

    Science.gov (United States)

    Hellblom, K. G.; Armstrong, R. J.

    1995-02-01

    A spectrometer based on the E × B drift during the transit time of the ion through a cross field region has been tested in a hydrogen plasma in the Blaamann toroidal plasma device [T. Brundtland, Vacuum 43 (1992) 185]. The magnetic field B, is the field of the device. The electric field E, which is imposed and oriented perpendicular to the magnetic field, is swept with a time long compared to the ion transit time. The ions are accelerated along the magnetic field as they enters the cross field region giving them a velocity and a transit time proportional to the charge over the mass.

  5. Time of relaxation in dusty plasma model

    Science.gov (United States)

    Timofeev, A. V.

    2015-11-01

    Dust particles in plasma may have different values of average kinetic energy for vertical and horizontal motion. The partial equilibrium of the subsystems and the relaxation processes leading to this asymmetry are under consideration. A method for the relaxation time estimation in nonideal dusty plasma is suggested. The characteristic relaxation times of vertical and horizontal motion of dust particles in gas discharge are estimated by analytical approach and by analysis of simulation results. These relaxation times for vertical and horizontal subsystems appear to be different. A single hierarchy of relaxation times is proposed.

  6. A Review on Inductively Coupled Plasma Mass Spectroscopy

    Directory of Open Access Journals (Sweden)

    Ramyalakshmi G

    2012-12-01

    Full Text Available Inductively coupled plasma mass spectroscopy is routinely used in many diverse research fields such as earth, environmental, life and forensic sciences and in food, material, chemical, semiconductor and nuclear industries. The high ion density and the high temperature in a plasma provide an ideal atomizer and element ionizer for all types of samples and materials introduced by a specialised devices .outstanding properties such as high sensitivity, relative salt tolerance, compound-independent element response and highest quantitation accuracy lead to the unchallenged performance of ICPMS in efficiently detecting, identifying and reliably quantifying trace element. The increasing availability of relevant reference compounds and high separation selectively extend the molecular identification capability of ICPMS hyphenated to species – specific separation techniques

  7. Combined laser induced ignition and plasma spectroscopy: Fundamentals and application to a hydrogen-air combustor

    Energy Technology Data Exchange (ETDEWEB)

    Zimmer, L. [Aeroengine Technology Center, Japan Aerospace Exploration Agency, 7-44-1 Jindaiji-Higashi Chofu, 182-8522 Tokyo (Japan)], E-mail: laurent.zimmer@em2c.ecp.fr; Okai, K. [Aeroengine Technology Center, Japan Aerospace Exploration Agency, 7-44-1 Jindaiji-Higashi Chofu, 182-8522 Tokyo (Japan)], E-mail: okai@chofu.jaxa.jp; Kurosawa, Y. [Clean engine team, Japan Aerospace Exploration Agency, 7-44-1 Jindaiji-Higashi Chofu, 182-8522 Tokyo (Japan)], E-mail: kuro@chofu.jaxa.jp

    2007-12-15

    Combined Laser Induced Ignition and Plasma Spectroscopy (LI2PS) has the potential to give the exact local composition of a mixture at the ignition point and at the ignition time. However, as different laser energies are required to ignite a particular mixture as function of space, the typical approach using two power meters to calibrate the plasma spectroscopy measurement is not well suited. Furthermore, LI2PS requires single shot measurements and therefore high accuracy. In this paper, a novel calibration scheme is presented for application of Laser Induced Plasma Spectroscopy (LIPS) to gaseous analyses. Numerical simulations of air spectra are used to show that species emission can be used directly from the broadband spectra to determine the plasma conditions. The ratio of nitrogen emission around 744 nm and around 870 nm is found to be a sensitive indication of temperature in the emission ranging from 700 to 890 nm. Comparisons with experimental spectra show identical tendencies and validate the findings of the simulations. This approach is used in a partially-premixed hydrogen-air burner. First, helium is used instead of hydrogen. After an explanation of timing issue related to LIPS, it is shown that the calibration required depends only on nitrogen excitation and nitrogen-hydrogen ratio, without the need to know the deposited power. Measurements of the fuel distribution as function of injection momentum and spatial localization are reported. To illustrate the use of such a single shot approach, combined laser ignition and plasma spectroscopy is proposed. In this case, the calibration is based on hydrogen excitation and hydrogen-oxygen and hydrogen-nitrogen ratio. Results obtained with LI2PS show that ignition is successful only for high power and relatively high hydrogen concentration compared to the local mean. It is expected that LI2PS will become an important tool when dealing with partially-premixed or diffusion flame ignition.

  8. Individual variation in macronutrient regulation measured by proton magnetic resonance spectroscopy of human plasma.

    Science.gov (United States)

    Park, Youngja; Kim, Seoung Bum; Wang, Bing; Blanco, Roberto A; Le, Ngoc-Anh; Wu, Shaoxiong; Accardi, Carolyn J; Alexander, R Wayne; Ziegler, Thomas R; Jones, Dean P

    2009-07-01

    Proton nuclear magnetic resonance ((1)H-NMR) spectroscopy of plasma provides a global metabolic profiling method that shows promise for clinical diagnostics. However, cross-sectional studies are complicated by a lack of understanding of intraindividual variation, and this limits experimental design and interpretation of data. The present study determined the diurnal variation detected by (1)H NMR spectroscopy of human plasma. Data reduction methods revealed three time-of-day metabolic patterns, which were associated with morning, afternoon, and night. Major discriminatory regions for these time-of-day patterns included the various kinds of lipid signals (-CH(2)- and -CH(2)OCOR), and the region between 3 and 4 ppm heavily overlapped with amino acids that had alpha-CH and alpha-CH(2). The phasing and duration of time-of-day patterns were variable among individuals, apparently because of individual difference in food processing/digestion and absorption and clearance of macronutrient energy sources (fat, protein, carbohydrate). The times of day that were most consistent among individuals, and therefore most useful for cross-sectional studies, were fasting morning (0830-0930), postprandial afternoon (1430-1630), and nighttime samples (0430-0530). Importantly, the integrated picture of metabolism provided by (1)H-NMR spectroscopy of plasma suggests that this approach is suitable to study complex regulatory processes, including eating patterns/eating disorders, upper gastrointestinal functions (gastric emptying, pancreatic, biliary functions), and absorption/clearance of macronutrients. Hence, (1)H-NMR spectroscopy of plasma could provide a global metabolic tolerance test to assess complex processes involved in disease, including eating disorders and the range of physiological processes causing dysregulation of energy homeostasis.

  9. Continuous, real time microwave plasma element sensor

    Science.gov (United States)

    Woskov, Paul P.; Smatlak, Donna L.; Cohn, Daniel R.; Wittle, J. Kenneth; Titus, Charles H.; Surma, Jeffrey E.

    1995-01-01

    Microwave-induced plasma for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury.

  10. Real-Time Fault Classification for Plasma Processes

    Directory of Open Access Journals (Sweden)

    Ryan Yang

    2011-07-01

    Full Text Available Plasma process tools, which usually cost several millions of US dollars, are often used in the semiconductor fabrication etching process. If the plasma process is halted due to some process fault, the productivity will be reduced and the cost will increase. In order to maximize the product/wafer yield and tool productivity, a timely and effective fault process detection is required in a plasma reactor. The classification of fault events can help the users to quickly identify fault processes, and thus can save downtime of the plasma tool. In this work, optical emission spectroscopy (OES is employed as the metrology sensor for in-situ process monitoring. Splitting into twelve different match rates by spectrum bands, the matching rate indicator in our previous work (Yang, R.; Chen, R.S. Sensors 2010, 10, 5703-5723 is used to detect the fault process. Based on the match data, a real-time classification of plasma faults is achieved by a novel method, developed in this study. Experiments were conducted to validate the novel fault classification. From the experimental results, we may conclude that the proposed method is feasible inasmuch that the overall accuracy rate of the classification for fault event shifts is 27 out of 28 or about 96.4% in success.

  11. Real-time fault classification for plasma processes.

    Science.gov (United States)

    Yang, Ryan; Chen, Rongshun

    2011-01-01

    Plasma process tools, which usually cost several millions of US dollars, are often used in the semiconductor fabrication etching process. If the plasma process is halted due to some process fault, the productivity will be reduced and the cost will increase. In order to maximize the product/wafer yield and tool productivity, a timely and effective fault process detection is required in a plasma reactor. The classification of fault events can help the users to quickly identify fault processes, and thus can save downtime of the plasma tool. In this work, optical emission spectroscopy (OES) is employed as the metrology sensor for in-situ process monitoring. Splitting into twelve different match rates by spectrum bands, the matching rate indicator in our previous work (Yang, R.; Chen, R.S. Sensors 2010, 10, 5703-5723) is used to detect the fault process. Based on the match data, a real-time classification of plasma faults is achieved by a novel method, developed in this study. Experiments were conducted to validate the novel fault classification. From the experimental results, we may conclude that the proposed method is feasible inasmuch that the overall accuracy rate of the classification for fault event shifts is 27 out of 28 or about 96.4% in success.

  12. Ion rotational velocity of a field-reversed configuration plasma measured by neutral beam probe spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ito, Y.; Tanjyo, M.; Ohi, S.; Goto, S.; Ishimura, T.

    1987-01-01

    The ion rotational angular velocity ..cap omega.. and the ion temperature T/sub i/ of a translated field-reversed configuration (FRC) plasma are measured using neutral beam probe spectroscopy. The value of ..cap omega.. is --(1.0--1.2) x ..cap omega..* at the onset time of the n = 2 rotational instability, where ..cap omega..* is the ion diamagnetic frequency for a rigid-rotor equilibrium. The ion rotational direction is the same as the ion diamagnetic direction. The value of ..cap omega.. is smaller than the angular frequency ..omega../sub re/ of the n = 2 instability, which can yield experimental evidence of the ion kinetic effects on the n = 2 instability in the FRC plasma. When the octupole field is applied to the plasma in order to suppress the n = 2 deformation, ..cap omega.. is slightly reduced. The ion temperature T/sub i/ is --70 eV at the onset time of the n = 2 instability.

  13. Laser-induced breakdown spectroscopy of tantalum plasma

    Energy Technology Data Exchange (ETDEWEB)

    Khan, Sidra; Bashir, Shazia; Hayat, Asma; Khaleeq-ur-Rahman, M.; Faizan–ul-Haq [Centre for Advanced Studies in Physics, GC University, Lahore (Pakistan)

    2013-07-15

    Laser Induced Breakdown spectroscopy (LIBS) of Tantalum (Ta) plasma has been investigated. For this purpose Q-switched Nd: YAG laser pulses (λ∼ 1064 nm, τ∼ 10 ns) of maximum pulse energy of 100 mJ have been employed as an ablation source. Ta targets were exposed under the ambient environment of various gases of Ar, mixture (CO{sub 2}: N{sub 2}: He), O{sub 2}, N{sub 2}, and He under various filling pressure. The emission spectrum of Ta is observed by using LIBS spectrometer. The emission intensity, excitation temperature, and electron number density of Ta plasma have been evaluated as a function of pressure for various gases. Our experimental results reveal that the optical emission intensity, the electron temperature and density are strongly dependent upon the nature and pressure of ambient environment. The SEM analysis of the ablated Ta target has also been carried out to explore the effect of ambient environment on the laser induced grown structures. The growth of grain like structures in case of molecular gases and cone-formation in case of inert gases is observed. The evaluated plasma parameters by LIBS analysis such as electron temperature and the electron density are well correlated with the surface modification of laser irradiated Ta revealed by SEM analysis.

  14. Optical emission spectroscopy of argon and hydrogen-containing plasmas

    Science.gov (United States)

    Siepa, Sarah; Danko, Stephan; Tsankov, Tsanko V.; Mussenbrock, Thomas; Czarnetzki, Uwe

    2015-09-01

    Optical emission spectroscopy (OES) on neutral argon is applied to investigate argon, hydrogen and hydrogen-silane plasmas. The spectra are analyzed using an extensive collisional-radiative model (CRM), from which the electron density and the electron temperature (or mean energy) can be calculated. The CRM also yields insight into the importance of different excited species and kinetic processes. The OES measurements are performed on pure argon plasmas at intermediate pressure. Besides, hydrogen and hydrogen-silane plasmas are investigated using argon as a trace gas. Especially for the gas mixture discharges, CRMs for low and high pressure differ substantially. The commonly used line-ratio technique is found to lose its sensitivity for gas mixture discharges at higher pressure. A solution using absolutely calibrated line intensities is proposed. The effect of radiation trapping and the shape of the electron energy distribution function on the results are discussed in detail, as they have been found to significantly influence the results. This work was supported by the Ruhr University Research School PLUS, funded by Germany's Excellence Initiative [DFG GSC 98/3].

  15. Analysis of structural transformation in wool fiber resulting from oxygen plasma treatment using vibrational spectroscopy

    Science.gov (United States)

    Barani, Hossein; Haji, Aminoddin

    2015-01-01

    The aim of this study was to investigate the influence of oxygen plasma procedure at different time treatments on wool fiber using the micro-Raman spectroscopy as a non-destructive vibrational spectroscopic technique and Fourier transform infrared spectroscopy. The amide I and III regions, Csbnd C skeletal vibration region, and Ssbnd S and Csbnd S bonds vibration regions were analyzed with the Raman microscope. The Fourier transform infrared spectroscope analysis was employed to find out the effect of oxygen plasma treatment on the cysteic acid residues content of the wool fiber sample. The results indicated that the α-helix structure was the highest component content of wool fiber. Moreover, the protein secondary structure of wool fibers was transformed from α-helical arrangement to the β-pleated sheet configuration during the oxygen plasma treatment. Also, the disulphide bonds content in the treated wool fiber reduced because they were fractured and oxidized during oxygen plasma treatment. The oxygen plasma treated samples presented higher cysteic acid compared to the untreated wool samples due to produce more cleavage of disulfide linkages.

  16. Nonselective and polarization effects in time-resolved optogalvanic spectroscopy

    Science.gov (United States)

    Zhechev, D.; Steflekova, V.

    2016-02-01

    Three interfering effects in optogalvanic (OG) spectroscopy are identified in a hollow cathode discharge (HCD) - OG detector. The laser beam is found to generate two nonselective processes, namely photoelectron emission (PE) from the cathode surface with a sub-breakdown bias applied, and nonresonant space ionization. The convolution of these galvanic contributions was determined experimentally as an instrumental function and a deconvolution procedure to determine the actual OG signal was developed. Specific plasma conductance is detected dependent on the polarization of the laser beam irradiating. Linearly/circularly polarized light beam is found to induce OG signals differ in amplitude (and their shape parameters in the time-resolved OG signals (TROGS)). The phenomena coherence and specific conductance are found to be in causal relationship. The additional conductance due to coherent states of atoms manifests itself as an intrinsic instrumental property of OG detector.

  17. Time-resolved terahertz spectroscopy of charge carrier dynamics in the chalcogenide glass As30Se30Te40 [Invited

    DEFF Research Database (Denmark)

    Wang, Tianwu; Romanova, Elena A.; Abdel-Moneim, Nabil

    2016-01-01

    Broadband (1.6-18 THz) terahertz time-domain spectroscopy (THz-TDS) and time-resolved terahertz spectroscopy (TRTS) were performed on a 54 mu m thick chalcogenide glass (As30Se30Te40) sample with a two-color laser-induced air plasma THz system in transmission and reflection modes, respectively. T...

  18. Plasma diagnostics from self-absorbed doublet lines in laser-induced breakdown spectroscopy

    Science.gov (United States)

    D'Angelo, C. A.; Garcimuño, M.; Díaz Pace, D. M.; Bertuccelli, G.

    2015-10-01

    In this paper, a generalized approach is developed and applied for plasma characterization and quantitative purposes in laser-induced breakdown spectroscopy (LIBS) experiences by employing a selected pair of spectral lines belonging to the same multiplet. It is based on the comparison between experimental ratios of line parameters and the theoretical calculus obtained under the framework of a homogeneous plasma in local thermodynamic equilibrium. The applicability of the method was illustrated by using the atomic resonance transitions 279.55-280.27 nm of Mg II, which are usually detected in laser-induced plasma (LIP) during laser ablation of many kinds of targets. The laser induced plasmas were produced using a Nd:YAG laser from a pressed pellet of powdered calcium hydroxide with a concentration of 300 ppm of Mg. The experimental ratios for peak intensities, total intensities and Stark widths were obtained for different time windows and matched to the theoretical calculus. The temperature and the electron density of the plasma, as well as the Mg columnar density (the atom/ion concentration times the length of the plasma along the line-of-sight), were determined. The results were interpreted under the employed approach.

  19. Time-resolved spectroscopy and imaging

    Science.gov (United States)

    Chance, Britton

    1995-05-01

    In response to the conference organizer's request, I am presenting a summary of the current status of medical optical imaging and spectroscopy. This is a topic which is advancing rapidly and on which there have been a number of conferences recently, and yet there has not been presented an overview of the field and some idea of what the advantages and disadvantages of the photon diffusion technology may be. Thus, this paper emphasizes diffusion waves for spectroscopy and imaging deep within the tissue and, at the same time, for providing specificity information of both absorption and scattering. In achieving this goal, I will not be able to cite all of the advantages of technologies that view the superficial layers of skin, retina, etc., on the one hand, nor those that measure the photons that have been scattered minimally on the transit between input and output. One of the main reasons for this is that specificity of the optical methods requires all of the information available: absorption and scattering of intrinsic signals naturally in the tissue, and of extrinsic signal due to contrast agents that have been artificially lodged in strategic tissue volumes. Since this paper is essentially the transcript of a lecture, it is not proposed as a topic review and does not contain full-scale bibliographic references, some of which may be found in a recent review elsewhere. This paper highlights what we all might accomplish in order to bring to bear with maximal effectiveness the optical method for altering the outcome of medical problems. I have not emphasized the mathematics of photon diffusion so well represented by the papers of this symposium volume. The achievable goals of the optical methods are to speed detection, improve diagnosis, guide therapy, and what appears in the minds of most, contribute to the improvement of medical economics. In order to fulfill these objectives, we will in the end have to demonstrate by lengthy and expensive clinical studies that the

  20. Optical emission spectroscopy of deuterium and helium plasma jets emitted from plasma focus discharges at the PF-1000U facility

    Science.gov (United States)

    Skladnik-Sadowska, E.; Dan'ko, S. A.; Kwiatkowski, R.; Sadowski, M. J.; Zaloga, D. R.; Paduch, M.; Zielinska, E.; Kharrasov, A. M.; Krauz, V. I.

    2016-12-01

    Optical emission spectroscopy techniques were used to investigate the spectra of dense deuterium-plasma jets generated by high-current pulse discharges within the large PF-1000U facility and to estimate parameters of plasma inside the jets and their surroundings. Time-resolved optical spectra were recorded by means of a Mechelle®900 spectrometer. From an analysis of the deuterium line broadening, it was estimated that the electron concentration at a distance 57 cm from the electrode outlets amounted to (0.4-3.7) × 1017 cm-3 depending on the initial gas distribution and the time interval of the spectrum registration after the instant of the plasma jet generation. From the re-absorption dip in the Dβ profile, it was assessed that the electron concentration in the surrounding gas was equal to about 1.5 × 1015 cm-3. On the basis of the measured ratio of He II 468.6 nm and He I 587.6 nm line intensities, it was estimated that the electron temperature amounted to about 5.3 eV. Also estimated were some dimensionless parameters of the investigated plasma jets.

  1. Nondestructive Evaluation of Aircraft Composites Using Terahertz Time Domain Spectroscopy

    Science.gov (United States)

    2008-12-10

    Taday, P. F., Pepper , M. (2008). Elimination of scattering effects in spectral measurement of granulated materials using terahertz time domain...W., Ferguson , B., Rainsford, T., Mickan, S. P., & Abbott, D. (2005). Material parameter extraction for terahertz time-domain spectroscopy using... Ferguson , B., Rainsford, T., Mickan, S. P., & Abbott, D. (2005). Simple material parameter estimation via terahertz time-domain spectroscopy

  2. Two-Dimensional Terahertz Time-Domain Spectroscopy and Its Applications

    Institute of Scientific and Technical Information of China (English)

    Jia-Yu Zhao; Wei-Wei Liu

    2015-01-01

    Abstract¾In this work, we review the developing progress of two-dimensional terahertz time-domain spectroscopy (THz-TDS) and its diverse applications, including analyzing the polarization of THz radiation from a laser-induced plasma source and studying the corresponding physical mechanism, and characterizing the optical properties of crystals, etc.

  3. Near-infrared spectroscopy and plasma homovanillic acid levels in bipolar disorder: a case report

    Directory of Open Access Journals (Sweden)

    Miura I

    2014-03-01

    Full Text Available Itaru Miura,1,2 Soichi Kono,1 Sachie Oshima,1 Keiko Kanno-Nozaki,1 Hirobumi Mashiko,1 Shin-Ichi Niwa,1 Hirooki Yabe11Department of Neuropsychiatry, School of Medicine, Fukushima Medical University, Fukushima, Japan; 2Division of Psychiatry Research, The Zucker Hillside Hospital, Glen Oaks, NY, USAAbstract: Misdiagnosis of bipolar disorder is a serious, but not unusual problem for patients. Nevertheless, there are few biomarkers for distinguishing unipolar and bipolar disorder. Near-infrared spectroscopy (NIRS is a noninvasive and useful method for the measurement of hemoglobin concentration changes in the cortical surface area, which enables the assessment of brain function. We measured NIRS and plasma monoamine metabolite levels in a patient with bipolar disorder. A 22-year-old man was admitted due to major depression. At admission, NIRS findings showed oxygenated hemoglobin reincrease in the posttask period, which is characteristic of schizophrenia. After treatment with paroxetine, he became manic with psychotic symptoms. His plasma level of homovanillic acid just before the manic switch was ten times higher than that just after paroxetine initiation. Treatment with lithium and antipsychotics was successful, and plasma homovanillic acid decreased after treatment. In this case, the NIRS findings may predict a possible risk of a manic switch, which is likely induced by paroxetine. NIRS may be able to help distinguish unipolar and bipolar disorder in clinical settings.Keywords: near-infrared spectroscopy, bipolar disorder, homovanillic acid, diagnosis, biomarker

  4. Fast differentiation of SIRS and sepsis from blood plasma of ICU patients using Raman spectroscopy.

    Science.gov (United States)

    Neugebauer, Ute; Trenkmann, Sabine; Bocklitz, Thomas; Schmerler, Diana; Kiehntopf, Michael; Popp, Jürgen

    2014-04-01

    Currently, there is no biomarker that can reliable distinguish between infectious and non-infectious systemic inflammatory response syndrome (SIRS). However, such a biomarker would be of utmost importance for early identification and stratification of patients at risk to initiate timely and appropriate antibiotic treatment. Within this proof of principle study, the high potential of Raman spectroscopy for the fast differentiation of non-infectious SIRS and sepsis is demonstrated. Blood plasma collected from 70 patients from the intensive care unit (31 patients with sepsis and 39 patients classified with SIRS without infection) was analyzed by means of Raman spectroscopy. A PCA-LDA based classification model was trained with Raman spectra from test samples and yielded for sepsis a sensitivity of 1.0 and specificity of 0.82. These results have been confirmed with an independent dataset (prediction accuracy 80%). Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Linearity of Air-Biased Coherent Detection for Terahertz Time-Domain Spectroscopy

    Science.gov (United States)

    Wang, Tianwu; Iwaszczuk, Krzysztof; Wrisberg, Emil Astrup; Denning, Emil Vosmar; Jepsen, Peter Uhd

    2016-06-01

    The performance of air-biased coherent detection (ABCD) in a broadband two-color laser-induced air plasma system for terahertz time-domain spectroscopy (THz-TDS) has been investigated. Fundamental parameters of the ABCD detection, including signal-to-noise ratio (SNR), dynamic range (DR), and linearity of detection have been characterized. Moreover, the performance of a photomultiplier tube (PMT) and an avalanche photodiode (APD) as photodetector in the ABCD have been compared. We have observed nonlinear behavior of PMT detector, which leads to artificial gain factor in TDS spectroscopy. The APD turns out to have superior linearity and three times higher dynamic compared to the PMT.

  6. Coherent spectroscopies on ultrashort time and length scales

    Directory of Open Access Journals (Sweden)

    Schneider C.

    2013-03-01

    Full Text Available Three spectroscopic techniques are presented that provide simultaneous spatial and temporal resolution: modified confocal microscopy with heterodyne detection, space-time-resolved spectroscopy using coherent control concepts, and coherent two-dimensional nano-spectroscopy. Latest experimental results are discussed.

  7. Dynamics of double-pulse laser produced titanium plasma inferred from thin film morphology and optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Krstulović, N., E-mail: niksak@ifs.hr [Institute of Physics, Bijenička 46, HR-10000 Zagreb (Croatia); Salamon, K., E-mail: ksalamon@ifs.hr [Institute of Physics, Bijenička 46, HR-10000 Zagreb (Croatia); Modic, M., E-mail: martina.modic@ijs.si [Jožef Stefan Institute, Jamova 39, 1001 Ljubljana (Slovenia); Bišćan, M., E-mail: mbiscan@ifs.hr [Institute of Physics, Bijenička 46, HR-10000 Zagreb (Croatia); Milat, O., E-mail: milat@ifs.hr [Institute of Physics, Bijenička 46, HR-10000 Zagreb (Croatia); Milošević, S., E-mail: slobodan@ifs.hr [Institute of Physics, Bijenička 46, HR-10000 Zagreb (Croatia)

    2015-05-01

    In this paper, dynamics of double-pulse laser produced titanium plasma was studied both directly using optical emission spectroscopy (OES) and indirectly from morphological properties of deposited thin films. Both approaches yield consistent results. Ablated material was deposited in a form of thin film on the Si substrate. During deposition, plasma dynamics was monitored using optical emission spectroscopy with spatial and temporal resolutions. The influence of ablation mode (single and double) and delay time τ (delay between first and second pulses in double-pulse mode) on plasma dynamics and consequently on morphology of deposited Ti-films was studied using X-ray reflectivity and atomic force microscopy. Delay time τ was varied from 170 ns to 4 μs. The results show strong dependence of both emission signal and Ti-film properties, such as thickness, density and roughness, on τ. In addition, correlation of average density and thickness of film is observed. These results are discussed in terms of dependency of angular distribution and kinetic energy of plasma plume particles on τ. Advantages of using double-pulse laser deposition for possible application in thin film production are shown. - Highlights: • Ti-thin films produced by single and double pulse laser ablation mode. • Ablation mode and delay time influenced plasma plume and film characteristics. • Films are most compact for optimized delay time (thinnest, smoothest and most dense). • Plasma dynamics can be inferred from film characteristics.

  8. [Determination of minor elements in stainless steel by laser-induced plasma spectroscopy (LIPS)].

    Science.gov (United States)

    Li, Jing; Zhai, Chao; Zhang, Shi-Ding; Zhang, Jian-Qiu; Meng, Xiang-Ru

    2008-04-01

    Laser-induced plasma spectroscopy (LIPS) is characterized by its non-contact and real-time analysis. Its application to the determination of steel composition can meet the need of high-speed, continuous and automatic production in large steel companies. In the present article the minor elements concentrations of aluminum, manganese, cobalt, molybdenum, and titanium in a series of stainless steel 1Cr18Ni9Ti samples were determinate by laser-induced plasma spectroscopy, based on a Nd : YAG Q-switched solid laser with wavelength 1 064 nm as an exciting source and ICCD as detector. In the experiment the working delay time and gate time of ICCD were set suitably to get high signal-to-noise ratio emission spectral lines, and the internal standardization method related to matrix effect was used to deal with spectral data. Experiment results show that the concentration ratios of all the measured elements versus the reference element ferrum have a good linear relationship with the intensity ratios of them, the detection limits of the five tested elements are within 150 microg x g(-1).

  9. Spectroscopy of the tungsten plasma produced by pulsed plasma-ion streams or laser beams

    Science.gov (United States)

    Skladnik-Sadowska, E.; Malinowski, K.; Sadowski, M. J.; Wolowski, J.; Gasior, P.; Kubkowska, M.; Rosinski, M.; Marchenko, A. K.; Sartowska, B.

    2009-06-01

    The paper reports on experiments, which concerned studies of plasma produced from a tungsten (W) target bombarded by powerful (ca. 5 μs, 1-5 MW/cm 2) plasma-ion streams in RPI-IBIS plasma accelerator, and a similar target irradiated with intense Nd:YAG laser pulses (0.5 J, 3 ns, ca. 5.3 × 10 9 W/cm 2) in another vacuum chamber. In both experiments optical measurements were performed with a Mechelle ®900 spectrometer, which enabled the spectrum from 300 nm to 1100 nm to be recorded, and different WI- and WII-lines to be identified. From space- and time-resolved measurements of those lines, basic W-plasma parameters were estimated. During W-plasma expansion the electron temperature was found to be 0.8-1 eV and electron concentration (2-8) × 10 16 cm -3. The emission of higher-ionized W-ions (up to W +6) was confirmed by measurements with an ion-energy analyzer. Structural changes in the irradiated targets were investigated with an optical microscope and SEM.

  10. Spectroscopy of the tungsten plasma produced by pulsed plasma-ion streams or laser beams

    Energy Technology Data Exchange (ETDEWEB)

    Skladnik-Sadowska, E.; Malinowski, K. [Andrzej Soltan Institute for Nuclear Studies (IPJ), 05-400 Otwock-Swierk (Poland); Sadowski, M.J., E-mail: msadowski@ipj.gov.p [Andrzej Soltan Institute for Nuclear Studies (IPJ), 05-400 Otwock-Swierk (Poland); Institute of Plasma Physics and Laser Microfusion (IPPLM), 01-497 Warsaw (Poland); Wolowski, J.; Gasior, P.; Kubkowska, M.; Rosinski, M. [Institute of Plasma Physics and Laser Microfusion (IPPLM), 01-497 Warsaw (Poland); Marchenko, A.K. [Institute of Plasma Physics, NSC KIPT, 61-108 Kharkov (Ukraine); Sartowska, B. [Institute of Nuclear Chemistry and Technology, 03-195 Warsaw (Poland)

    2009-06-15

    The paper reports on experiments, which concerned studies of plasma produced from a tungsten (W) target bombarded by powerful (ca. 5 mus, 1-5 MW/cm{sup 2}) plasma-ion streams in RPI-IBIS plasma accelerator, and a similar target irradiated with intense Nd:YAG laser pulses (0.5 J, 3 ns, ca. 5.3 x 10{sup 9} W/cm{sup 2}) in another vacuum chamber. In both experiments optical measurements were performed with a Mechelle 900 spectrometer, which enabled the spectrum from 300 nm to 1100 nm to be recorded, and different WI- and WII-lines to be identified. From space- and time-resolved measurements of those lines, basic W-plasma parameters were estimated. During W-plasma expansion the electron temperature was found to be 0.8-1 eV and electron concentration (2-8) x 10{sup 16} cm{sup -3}. The emission of higher-ionized W-ions (up to W{sup +6}) was confirmed by measurements with an ion-energy analyzer. Structural changes in the irradiated targets were investigated with an optical microscope and SEM.

  11. Real-Time Smart Tools for Processing Spectroscopy Data Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose novel and real-time smart software tools to process spectroscopy data. Material abundance or compositional maps will be generated for rover guidance,...

  12. Steady state and time resolved spectroscopy of photoswitchable systems

    NARCIS (Netherlands)

    Hou, Lili

    2013-01-01

    Steady state en time resolved spectroscopie zijn twee fundamentele methodes voor het bestuderen van fotochemische processen. In dit proefschrift zijn drie zelf-opgezette spectroscopische systemen beschreven, waarmee samen met andere spectroscopische methoden verscheidende met licht schakelbare syste

  13. An optimal real-time controller for vertical plasma stabilization

    CERN Document Server

    Cruz, N; Coda, S; Duval, B P; Le, H B; Rodrigues, A P; Varandas, C A F; Correia, C M B A; Goncalves, B S

    2014-01-01

    Modern Tokamaks have evolved from the initial axisymmetric circular plasma shape to an elongated axisymmetric plasma shape that improves the energy confinement time and the triple product, which is a generally used figure of merit for the conditions needed for fusion reactor performance. However, the elongated plasma cross section introduces a vertical instability that demands a real-time feedback control loop to stabilize the plasma vertical position and velocity. At the Tokamak \\`a Configuration Variable (TCV) in-vessel poloidal field coils driven by fast switching power supplies are used to stabilize highly elongated plasmas. TCV plasma experiments have used a PID algorithm based controller to correct the plasma vertical position. In late 2013 experiments a new optimal real-time controller was tested improving the stability of the plasma. This contribution describes the new optimal real-time controller developed. The choice of the model that describes the plasma response to the actuators is discussed. The ...

  14. Time-resolved spectroscopy with entangled photons

    CERN Document Server

    Kalashnikov, Dmitry A; Kalachev, Alexey A; Yu, Ye Feng; Kuznetsov, Arseniy I; Krivitsky, Leonid A

    2016-01-01

    Interaction of light with media often occurs with a femtosecond response time. Its measurement by conventional techniques requires the use of femtosecond lasers and sophisticated time-gated optical detection1-3. Here we demonstrate that by exploiting quantum interference of entangled photons it is possible to measure the phase relaxation time of a media on the femtosecond time scale (down to 100 fs) using accessible continuous wave laser and single-photon counting. We insert the sample in the Hong-Ou-Mandel interferometer4 and infer the phase relaxation time from the modification of the two-photon interference pattern. In addition to its simplicity and ease of use, the technique does not require compensation of group velocity dispersion5-8 and does not induce photo-damage of the samples. This technique will be useful for characterization of ultrafast phase relaxation processes in material science, chemistry, and biology.

  15. Stark spectroscopy of atomic hydrogen balmer-alpha line for electric field measurement in plasmas by saturation spectroscopy

    Science.gov (United States)

    Nishiyama, S.; Katayama, K.; Nakano, H.; Goto, M.; Sasaki, K.

    2016-09-01

    Detailed structures of electric fields in sheath and pre-sheath regions of various plasmas are interested from the viewpoint of basic plasma physics. Several researchers observed Stark spectra of Doppler-broadened Rydberg states to evaluate electric fields in plasmas; however, these measurements needed high-power, expensive tunable lasers. In this study, we carried out another Stark spectroscopy with a low-cost diode laser system. We applied saturation spectroscopy, which achieves a Doppler-free wavelength resolution, to observe the Stark spectrum of the Balmer-alpha line of atomic hydrogen in the sheath region of a low-pressure hydrogen plasma. The hydrogen plasma was generated in an ICP source which was driven by on-off modulated rf power at 20 kHz. A planar electrode was inserted into the plasma. Weak probe and intense pump laser beams were injected into the plasma from the counter directions in parallel to the electrode surface. The laser beams crossed with a small angle above the electrode. The observed fine-structure spectra showed shifts, deformations, and/or splits when varying the distance between the observation position and the electrode surface. The detection limit for the electric field was estimated to be several tens of V/cm.

  16. Spectroscopy

    CERN Document Server

    Walker, S

    1976-01-01

    The three volumes of Spectroscopy constitute the one comprehensive text available on the principles, practice and applications of spectroscopy. By giving full accounts of those spectroscopic techniques only recently introduced into student courses - such as Mössbauer spectroscopy and photoelectron spectroscopy - in addition to those techniques long recognised as being essential in chemistry teaching - sucha as e.s.r. and infrared spectroscopy - the book caters for the complete requirements of undergraduate students and at the same time provides a sound introduction to special topics for graduate students.

  17. Submillimeter Absorption Spectroscopy in Semiconductor Manufacturing Plasmas and Comparison to Theoretical Models

    Science.gov (United States)

    Helal, Yaser H.; Neese, Christopher F.; De Lucia, Frank C.; Ewing, Paul R.; Agarwal, Ankur; Craver, Barry; Stout, Phillip J.; Armacost, Michael D.

    2015-06-01

    Plasmas used in the semiconductor manufacturing industry are of a similar nature to the environments often created for submillimeter spectroscopic study of astrophysical species. At the low operating pressures of these plasmas, submillimeter absorption spectroscopy is a method capable of measuring the abundances and temperatures of molecules, radicals, and ions without disturbing any of the properties of the plasma. These measurements provide details and insight into the interactions and reactions occurring within the plasma and their implications for semiconductor manufacturing processes. A continuous wave, 500 to 750 GHz, absorption spectrometer was designed and used to make measurements of species in semiconductor processing plasmas. Comparisons with expectations from theoretical plasma models provide a basis for validating and improving these models, which is a complex and difficult science itself. Furthermore, these comparisons are an evaluation for the use of submillimeter spectroscopy as a diagnostic tool in manufacturing processes.

  18. Waiting Time Dynamics in Two-Dimensional Infrared Spectroscopy

    NARCIS (Netherlands)

    Jansen, Thomas L. C.; Knoester, Jasper

    We review recent work on the waiting time dynamics of coherent two-dimensional infrared (2DIR) spectroscopy. This dynamics can reveal chemical and physical processes that take place on the femto- and picosecond time scale, which is faster than the time scale that may be probed by, for example,

  19. Towards reconstruction of overlapping fingerprints using plasma spectroscopy

    Science.gov (United States)

    Yang, Jun-Ho; Choi, Soo-Jin; Yoh, Jack J.

    2017-08-01

    Chemical analysis is commonly used in the field of forensic science where the precise discrimination of primary evidence is of significant importance. Laser-Induced Breakdown Spectroscopy (LIBS) exceeds other spectroscopic methods in terms of the time required for pre- and post-sample preparation, the insensitivity to sample phase state be it solid, liquid, or gas, and the detection of two-dimensional spectral mapping from real time point measurements. In this research, fingerprint samples on various surface materials are considered in the chemical detection and reconstruction of fingerprints using the two-dimensional LIBS technique. Strong and distinct intensities of specific wavelengths represent visible ink, natural secretion of sweat, and contaminants from the environment, all of which can be present in latent fingerprints. The particular aim of the work presented here is to enhance the precision of the two-dimensional recreation of the fingerprints present on metal, plastic, and artificially prepared soil surface using LIBS with principal component analysis. By applying a distinct wavelength discrimination for two overlapping fingerprint samples, separation into two non-identical chemical fingerprints was successfully performed.

  20. Fast-timing spectroscopy at ISOLDE

    Science.gov (United States)

    Fraile, L. M.

    2017-09-01

    The advanced time-delayed β γ γ (t) method has been used at ISOLDE since the relocation of the facility from the synchrocyclotron to the CERN proton synchrotron booster, a quarter of a century ago. The method was designed for precision measurements with low-intensity beams, achieving good efficiency and excellent time resolution with a compact setup. Over this time the technique has evolved to cope with the challenge of measuring lifetimes of complex level schemes of increasingly exotic nuclei populated in β decay. The ISOLDE facility provides unsurpassed opportunities to study many regions of the nuclide chart. The physics case encompasses topics of interest across the nuclide chart, including the evolution of shell structure around neutron shell and subshell closures such as N = 20, N = 40 and N = 50, shape coexistence, and octupole correlations in heavy nuclei. The recently commissioned ISOLDE decay station provides enhanced capabilities that will be fully exploited with the increased beam intensities available at the upcoming HIE-ISOLDE facility.

  1. Proceedings of the 3rd US-Japan Workshop on Plasma Polarization Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Beiersdorfer, P; Flyimoto, T

    2002-01-02

    The third US-Japan Workshop on Plasma Polarization Spectroscopy was held at the Lawrence Livermore National Laboratory in Livermore, California, on June 18-21, 2001. The talks presented at this workshop are summarized in these proceedings. The papers cover both experimental investigation and applications of plasma polarization spectroscopy as well as the theoretical foundation and formalisms to understand and describe the polarization phenomena. The papers give an overview of the history of plasma polarization spectroscopy, derive the formal aspects of polarization spectroscopy, including the effects of electric and magnetic fields, discuss spectra perturbed by intense microwave fields, charge exchange, and dielectronic recombination, and present calculations of various collisional excitation and ionization cross sections and the modeling of plasma polarization spectroscopy phenomena. Experimental results are given from the WT-3 tokamak, the MST reverse field pinch, the Large Helical Device, the GAMMA 10 mirror machine, the Nevada Terrawatt Facility, the Livermore EBIT-II electron beam ion trap, and beam-foil spectroscopy. In addition, results were presented from studies of several laser-produced plasma experiments and new instrumental techniques were demonstrated.

  2. Ultrafast time resolved vibrational spectroscopy in liquid systems

    Energy Technology Data Exchange (ETDEWEB)

    Seifert, G.; Hofmann, M.; Weidlich, K.; Graener, H. [Physics Institute, University of Bayreuth, D-95440 Bayreuth (Germany)

    1996-04-01

    The ultrafast dynamics of small molecules in the liquid phase can successfully be studied tracing the relaxation pathways of vibrational excess energy. Two complementing experimental techniques, picosecond IR double resonance spectroscopy and time resolved incoherent Anti-Stokes Raman spectroscopy, are very powerful tools for such studies. The capabilities of investigations combining these methods are discussed on the example of new experimental data on liquid dichloromethane (CH{sub 2}Cl{sub 2}). {copyright} {ital 1996 American Institute of Physics.}

  3. Time-resolved spectroscopy using synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Poliakoff, E.D.

    1979-08-01

    Work performed at the Stanford Synchrotron Radiation Laboratory (SSRL) is reported. The timing characteristics of the SPEAR beam (pulse width less than or equal to 0.4 nsec, pulse repetition period = 780 nsec) were exploited to determine dynamic behavior of atomic, molecular, excimeric, and photodissociative gas-phase species excited by vacuum-ultraviolet (VUV) radiation. Fast fluorescence timing measurements were done to determine excited-state lifetimes of Kr and Xe. Pressure-dependent timing studies on Xe gas at higher concentrations demonstrated some of the problems associated with previous kinetic modeling of the Xe/sub 2/ system. It was found that even qualitative agreement of observed Xe/sub 2/ lifetimes as a function of pressure required the assumption that the radiative lifetime was a strong function of internuclear separation. The radiative decays of chemically unstable fragments, CN* (B/sup 2/..sigma../sup +/) and XeF* (B/sup 2/..sigma../sup +/ and C/sup 2/ Pi/sub 3/2//), were studied by pulsed photodissociation of stable parent compounds, ICN and XeF/sub 2/. When the polarization of the CN* (B/sup 2/..sigma../sup +/) fragment fluorescence was measured, it was found to be non-zero and strongly dependent on excitation wavelength. This polarization is related to the symmetry of the photodissociative surface via a classical model, and the variations in the polarization with wavelength is attributed to symmetry and lifetime effects of a predissociating parent molecule. Despite the drawbacks of limited availability and low radiation flux, synchrotron radiation is definitely a useful spectroscopic tool for VUV studies of gas-phase systems.

  4. Time-resolved terahertz spectroscopy of black silicon

    DEFF Research Database (Denmark)

    Porte, Henrik; Turchinovich, Dmitry; Jepsen, Peter Uhd;

    2010-01-01

    The ultrafast photoconductivity dynamics of black silicon is measured by time-resolved terahertz spectroscopy. Black silicon is produced by laser annealing of an a-Si:H film. We show that the decay time of the photoconductivity depends on the annealing method and fluence used in the production...

  5. Plasma-cavity ringdown spectroscopy for analytical measurement: Progress and prospectives

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Sida; Liu, Wei [Research Center of Analytical Instrumentation, Analytical and Testing Center, College of Chemistry, Sichuan University, Chengdu (China); Zhang, Xiaohe [College of Water Resources and Hydropower, Sichuan University, Chengdu (China); Duan, Yixiang, E-mail: yduan@scu.edu.cn [Research Center of Analytical Instrumentation, Analytical and Testing Center, College of Chemistry, Sichuan University, Chengdu (China)

    2013-07-01

    Plasma-cavity ringdown spectroscopy is a powerful absorption technique for analytical measurement. It combines the inherent advantages of high sensitivity, absolute measurement, and relative insensitivity to light source intensity fluctuations of the cavity ringdown technique with use of plasma as an atomization/ionization source. In this review, we briefly describe the background and principles of plasma-cavity ringdown spectroscopy(CRDS) technology, the instrumental components, and various applications. The significant developments of the plasma sources, lasers, and cavity optics are illustrated. Analytical applications of plasma-CRDS for elemental detection and isotopic measurement in atomic spectrometry are outlined in this review. Plasma-CRDS is shown to have a promising future for various analytical applications, while some further efforts are still needed in fields such as cavity design, plasma source design, instrumental improvement and integration, as well as potential applications in radical and molecular measurements. - Highlights: • Plasma-based cavity ringdown spectroscopy • High sensitivity and high resolution • Elemental and isotopic measurements.

  6. Active plasma resonance spectroscopy: a functional analytic description

    Science.gov (United States)

    Lapke, M.; Oberrath, J.; Mussenbrock, T.; Brinkmann, R. P.

    2013-04-01

    The term ‘active plasma resonance spectroscopy’ denotes a class of diagnostic methods which employ the ability of plasmas to resonate on or near the plasma frequency. The basic idea dates back to the early days of discharge physics: a signal in the GHz range is coupled to the plasma via an electrical probe; the spectral response is recorded, and then evaluated with a mathematical model to obtain information on the electron density and other plasma parameters. In recent years, the concept has found renewed interest as a basis of industry compatible plasma diagnostics. This paper analyzes the diagnostic technique in terms of a general description based on functional analytic (or Hilbert Space) methods which hold for arbitrary probe geometries. It is shown that the response function of the plasma-probe system can be expressed as a matrix element of the resolvent of an appropriately defined dynamical operator. A specialization of the formalism to a symmetric probe design is given, as well as an interpretation in terms of a lumped circuit model consisting of series resonance circuits. We present ideas for an optimized probe design based on geometric and electrical symmetry.

  7. In Situ Nanocalorimetric Investigations of Plasma Assisted Deposited Poly(ethylene oxide)-like Films by Specific Heat Spectroscopy.

    Science.gov (United States)

    Madkou, Sherif; Melnichu, Iurii; Choukourov, Andrei; Krakovsky, Ivan; Biederman, Hynek; Schönhals, Andreas

    2016-04-28

    In recent years, highly cross-linked plasma polymers have started to unveil their potential in numerous biomedical applications in thin-film form. However, conventional diagnostic methods often fail due to their diverse molecular dynamics conformations. Here, glassy dynamics and the melting transition of thin PEO-like plasma assisted deposited (ppPEO) films (thickness 100 nm) were in situ studied by a combination of specific heat spectroscopy, utilizing a pJ/K sensitive ac-calorimeter chip, and composition analytical techniques. Different cross-linking densities were obtained by different plasma powers during the deposition of the films. Glassy dynamics were observed for all values of the plasma power. It was found that the glassy dynamics slows down with increasing the plasma power. Moreover, the underlying relaxation time spectra broaden indicating that the molecular motions become more heterogeneous with increasing plasma power. In a second set of the experiment, the melting behavior of the ppPEO films was studied. The melting temperature of ppPEO was found to decrease with increasing plasma power. This was explained by a decrease of the order in the crystals due to formation of chemical defects during the plasma process.

  8. Time-Resolved Spectroscopy in Complex Liquids An Experimental Perspective

    CERN Document Server

    Torre, Renato

    2007-01-01

    Time-Resolved Spectroscopy in Complex Liquids introduces current state-of-the-art techniques in the study of complex dynamical problems in liquid phases. With a unique focus on the experimental aspects applied to complex liquids, this volume provides an excellent overview into the quickly emerging field of soft-matter science. Researchers and engineers will find a comprehensive review of current non-linear spectroscopic and optical Kerr effect techniques, in addition to an in-depth look into relaxation dynamics in complex liquids. This volume offers current experimental findings in transient grating spectroscopy and their application to viscoelastic phenomena in glass-formers, dynamics of confined liquid-crystals, and a time-resolved analysis of the host-quest interactions of dye molecules in liquid-crystal matter. Time-Resolved Spectroscopy in Complex Liquids provides a cohesive introduction suitable for individuals involved in this emerging field, complete with the latest experimental procedures of complex ...

  9. Asphaltene Erosion Process in Air Plasma: Emission Spectroscopy and Surface Analysis for Air-Plasma Reactions

    Institute of Scientific and Technical Information of China (English)

    H. MARTINEZ; O. FLORES; J. C. POVEDA; B. CAMPILLO

    2012-01-01

    Optical emission spectroscopy (OES) was applied for plasma characterization during the erosion of asphaltene substrates. An amount of 100 mg of asphaltene was carefully applied to an electrode and exposed to air-plasma glow discharge at a pressure of 1.0 Torr. The plasma was generated in a stainless steel discharge chamber by an ac generator at a frequency of 60 Hz, output power of 50 W and a gas flow rate of 1.8 L/min. The electron temperature and ion density were estimated to be 2.15±0.11 eV and (1.24±0.05)× 10^16 m^-3, respectively, using a double Langmuir probe. OES was employed to observe the emission from the asphaltene exposed to air plasma. Both molecular band emission from N2, N2+, OH, CH, NH, O2 as well as CN, and atomic light emission from V and Hγ were observed and used to monitor the evolution of asphaltene erosion. The asphaltene erosion was analyzed with the aid of a scanning electron microscope (SEM) equipped with an energy dispersive X-ray (EDX) detector. The EDX analysis showed that the time evolution of elements C, O, S and V were similar and the chemical composition of the exposed asphaltenes remained constant. Particle size evolution was measured, showing a maximum size of 2307 μm after 60 min. This behavior is most likely related to particle agglomeration as a function of time.

  10. Plasma diagnostics in gas metal arc welding by optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Valensi, F; Pellerin, S; Zielinska, S [GREMI, Universite d' Orleans (Site de Bourges)/CNRS, BP 4043, 18028 Bourges cedex (France); Boutaghane, A [Universite des Sciences et de la Technologie Houari Boumediene, Alger (Algeria); Dzierzega, K [Marian Smoluchowski Institute of Physics, Jagellonian University, Krakow (Poland); Pellerin, N [CNRS, UPR3079 CEMHTI, 1D av. de la Recherche Scientifique, 45071 Orleans cedex 2 (France); Briand, F, E-mail: flavien.valensi@laplace.univ-tsle.f, E-mail: stephane.pellerin@univ-orleans.f, E-mail: aboutaghane@yahoo.f, E-mail: krzycho@netmail.if.uj.edu.p, E-mail: sylwia.zielinska@airliquide.co, E-mail: nadia.pellerin@univ-orleans.f, E-mail: francis.briand@airliquide.co [CTAS-Air Liquide Welding, Saint Ouen l' Aumone, 95315 Cergy-Pontoise cedex (France)

    2010-11-03

    The plasma column in a metal inert gas welding process is investigated by optical emission spectroscopy and high-speed imaging. The concentration and repartition of iron vapours are measured and correlated with the plasma and electrode geometric configuration. Plasma temperatures and electron densities are also measured for each studied position in the plasma. The temperatures are calculated using two different methods, allowing validation of the local thermodynamic equilibrium state of the plasma. The results show a maximum temperature of 12 500 K in the upper part of the arc, away from the arc axis. The iron concentration reaches a maximum of 0.3% close to the anode and strongly decreases along both the vertical and radial directions. The plasma thermophysical properties, calculated from this plasma composition, are then discussed regarding the metal transfer mode.

  11. Recent advances in spectroscopy of strongly correlated plasmas

    Science.gov (United States)

    Leboucher-Dalimier, E.; Sauvan, P.; Gauthier, P.; Angelo, P.; Derfoul, H.; Alexiou, S.; Poquerusse, A.; Ceccotti, T.; Calisti, A.

    1998-09-01

    The Quasimolecular Model using a Two Centre basis to describe the electronic emitting structure gives an alternative treatment of line broadening in dense and hot plasmas. Two codes are developed: IDEFIX for the radiative properties, QMSPECTRA (postprocessed to the first one) for the spectral line shapes. The observability of dense plasma effects (PPS, asymmetries and satellite features) in spectroscopic measurements is analysed within the proposed model and taking care of the eventual integrations over density gradients.

  12. Characterisation of a micro-plasma device sensor using electrical measurements and emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Mariotti, D

    2002-04-01

    This thesis reports on research undertaken on the characterisation of a micro-plasma device to be used for gas analysis by mean of plasma emission spectroscopy. The work covers aspects related to the micro-plasma electrical and optical emission parameters, and their importance for the utilisation of the micro-plasma device in gas analysis. Experimental results have been used to analyse the fundamental micro-plasma processes and to develop a model, which could provide additional information. This dissertation contains a general literature review of topics related to plasma physics, plasma emission spectroscopy, gas analysis (chemical analysis and artificial olfaction) and other micro-plasma applications. Experimental work focuses on two main areas: electrical measurements and emission measurements. Firstly, electrical measurements are taken and interpretations are given. Where necessary, new theoretical treatments are suggested in order to describe better the physical phenomena. Plasma emission has been considered under different working conditions. This allowed the characterisation of the micro-plasma emission and also a better understanding of the micro-plasma processes. On the basis of the experimental data obtained and other assumptions a model has been developed. A computer simulation based on this model provided additional useful information on the micro- plasma behaviour. The first fundamental implication of this new research is the peculiar behaviour of the micro-plasma. This micro-plasma exhibited deviations from Paschen law and strong dependency on cathode material, which contributed to the formation of a low current stable regime. These results have been followed by physical interpretations and theoretical descriptions. The second implication is the establishment of the boundaries and of the influencing parameters for plasma emission spectroscopy as an analytical tool in this particular micro-plasma. From the applied perspective this study has shown that

  13. Investigation of Normalization Methods using Plasma Parameters for Laser Induced Breakdown Spectroscopy (LIBS) under simulated Martian Conditions

    OpenAIRE

    Vogt, David; Schröder, Susanne; Hübers, H.-W.

    2017-01-01

    Laser Induced Breakdown Spectroscopy data need to be normalized, especially in the field of planetary exploration We investigated plasma parameters as temperature and electron density for this purpose.

  14. Time-resolved THz spectroscopy in a parallel plate waveguide

    DEFF Research Database (Denmark)

    Cooke, David; Jepsen, Peter Uhd

    2009-01-01

    We demonstrate time-resolved terahertz spectroscopy inside a novel parallel plate waveguide where one of the metallic plates is replaced by a transparent conducting oxide. Considerable improvements to the waveguide loss coefficient are shown, with a power absorption coefficient of 4cm-1 at 0.5 THz....... The time resolution of the technique is shown to be limited by the spatial excitation profile, which for sharply focused beams can approach ~1 ps time scales....

  15. Determining Concentrations and Temperatures in Semiconductor Manufacturing Plasmas via Submillimeter Absorption Spectroscopy

    Science.gov (United States)

    Helal, Yaser H.; Neese, Christopher F.; De Lucia, Frank C.; Ewing, Paul R.; Agarwal, Ankur; Craver, Barry; Stout, Phillip J.; Armacost, Michael D.

    2016-06-01

    Plasmas used in the manufacturing processes of semiconductors are similar in pressure and temperature to plasmas used in studying the spectroscopy of astrophysical species. Likewise, the developed technology in submillimeter absorption spectroscopy can be used for the study of industrial plasmas and for monitoring manufacturing processes. An advantage of submillimeter absorption spectroscopy is that it can be used to determine absolute concentrations and temperatures of plasma species without the need for intrusive probes. A continuous wave, 500 - 750 GHz absorption spectrometer was developed for the purpose of being used as a remote sensor of gas and plasma species. An important part of this work was the optical design to match the geometry of existing plasma reactors in the manufacturing industry. A software fitting routine was developed to simultaneously fit for the background and absorption signal, solving for concentration, rotational temperature, and translational temperature. Examples of measurements made on inductively coupled plasmas will be demonstrated. We would like to thank the Texas Analog Center of Excellence/Semiconductor Research Corporation (TxACE/SRC) and Applied Materials for their support of this work.

  16. Curve of growth methodology applied to laser-induced plasma emission spectroscopy

    Science.gov (United States)

    Gornushkin, I. B.; Anzano, J. M.; King, L. A.; Smith, B. W.; Omenetto, N.; Winefordner, J. D.

    1999-04-01

    The curve-of-growth (COG) method was applied to a laser-induced plasma. The plasma was produced by a Nd:YAG laser on the surface of steel samples containing 0.007-1.3% of Cr. The emission was collected from the top of the plasma by means of a 45° pierced mirror and aligned onto an intensified charge-coupled device (ICCD) with a gate width of 1 μs and a variable delay time. The resonance 425.4 nm Cr line was used for construction of the COG. The temperature of the plasma (˜8000 K at 5-μs delay) was determined from a Boltzmann plot. The damping constant a, proportional to the ratio of the Lorentzian to the Doppler line widths, was found from the best fit of a series of calculated COG to the experimental data points and was 0.20±0.05. The number density of neutral Cr atoms which corresponded to the transition between low and high optical densities, was ≈6.5·10 12 cm -3. The cross-section for broadening collisions of Cr atoms with atmospheric species (presumably N 2) was calculated to be (66±16) Å. The shape of the 425.4-nm Cr line was additionally checked by scanning an ultra-narrow cw Ti:Sapphire laser across the atomic transition and found to be in agreement with preliminary estimates. The potential of the COG method for laser breakdown spectroscopy is discussed.

  17. Introduction to Plasma Spectroscopy 2.What do spectra tell us ?

    Science.gov (United States)

    Goto, Motoshi; Murakami, Izumi; Fujimoto, Takashi

    The collisional-radiative(CR) model is introduced as an improvement to the corona model. Its formulation indicates that the population of every excited level is divided into two independent components, i.e., the ionizing and recombining plasma components. For the pulsed discharge with helium gas in a Pyrex tube which exhibits intense line radiations twice, the first and second peaks are found to correspond to the ionizing and recombining plasmas, respectively, from the different population distributions over the n3D levels. The spectrum taken in the stationary phase of the main discharge in the Large Helical Device (LHD) with helium gas suggests an ionizing plasma, and for the other two spectra taken in the plasma terminating phase, the first and the second spectra indicate the recombining plasmas of ionized and neutral helium, respectively. In all these analyses, the electron temperature and density are the variable parameters and are determined as a result of fitting of calculation to the experimental data. The spectrum observed in the helium glow discharge cannot be reproduced by CR model calculations even if the quasi-steady-state approximation for meta stable states of neutral helium is removed. The opacity effect may be the origin of this difficulty.

  18. Investigations of GMAW plasma by optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Zielinska, S [Instytut Fizyki im. Mariana Smoluchowskiego, Uniwersytet Jagiellonski, ulica Reymonta 4, 30-059 Krakow (Poland); Musiol, K [Instytut Fizyki im. Mariana Smoluchowskiego, Uniwersytet Jagiellonski, ulica Reymonta 4, 30-059 Krakow (Poland); Dzierzega, K [Instytut Fizyki im. Mariana Smoluchowskiego, Uniwersytet Jagiellonski, ulica Reymonta 4, 30-059 Krakow (Poland); Pellerin, S [LASEP, Faculte des Sciences-Bourges, Universite d' Orleans, BP 4043, 18028 Bourges Cedex (France); Valensi, F [LASEP, Faculte des Sciences-Bourges, Universite d' Orleans, BP 4043, 18028 Bourges Cedex (France); Izarra, Ch de [LASEP, Faculte des Sciences-Bourges, Universite d' Orleans, BP 4043, 18028 Bourges Cedex (France); Briand, F [CTAS - Air Liquide Welding, Rue des Epluches, Saint Ouen l' Aumone (France)

    2007-11-15

    We report on investigations of gas metal arc welding plasma operated in pure argon and in a mixture of argon and CO{sub 2} at a dc current of 326 A. The spatially resolved electron densities and temperatures were directly obtained by measuring the Stark widths of the Ar I 695.5 nm and Fe I 538.3 nm spectral lines. Our experimental results show a reduction of the plasma conductivity and transfer from spray arc to globular arc operation with increasing CO{sub 2} concentration. Although the electron density n{sub e} increases while approaching the core of the plasma in the spray-arc mode, a drop in the electron temperature T{sub e} is observed. Moreover, the maximum T{sub e} that we measure is about 13 000 K. Our experimental results differ from the Haidar model where T{sub e} is always maximum on the arc axis and its values exceed 20 000 K. These discrepancies can be explained as a result of underestimation of the amount of metal vapours in the plasma core and of the assumption of local thermal equilibrium plasma in the model.

  19. Study of deuterium retention on lithiated tungsten exposed to high-flux deuterium plasma using laser-induced breakdown spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Li, Cong; Wu, Xingwei; Zhang, Chenfei [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Chinese Ministry of Education, School of Physics and Optical Electronic Technology, Dalian University of Technology, Dalian 116024 (China); Ding, Hongbin, E-mail: hding@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Chinese Ministry of Education, School of Physics and Optical Electronic Technology, Dalian University of Technology, Dalian 116024 (China); De Temmerman, G., E-mail: G.C.DeTemmerman@differ.nl [FOM Institute DIFFER, Dutch Institute for Fundamental Energy Research, Association EURATOM-FOM, Trilateral Euregio Cluster, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Meiden, H.J. van der [FOM Institute DIFFER, Dutch Institute for Fundamental Energy Research, Association EURATOM-FOM, Trilateral Euregio Cluster, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands)

    2014-10-15

    Highlights: • Deuterium retention effects on both pure tungsten and lithiated tungsten have been investigated in the linear plasma simulator Magnum-PSI by an in-situ laser-induced breakdown spectroscopy. • The lithiation can inhibit the blistering on tungsten surface. • The re-deposition of lithium results in the formation of chemical state of Li{sub 2}CO{sub 3} and tungsten oxides on a fresh surface of tungsten. - Abstract: Tungsten is under consideration for use as a plasma-facing material in the divertor region of ITER. Lithiation can significantly improve plasma performance in long-pulse tokamaks like EAST. The investigation of lithiated tungsten is important for understanding the lithium conditioning effects for EAST, where tungsten will be used as a plasma-facing material. In this paper, a few important issues of lithiated tungsten interacting with high-flux deuterium plasma have been studied, such as the effect of lithiation on deuterium retention, the profile of elemental distribution, and the chemical state of lithiated tungsten. Deuterium retention inside both pure and lithiated tungsten has been investigated for the first time in the linear plasma simulator Magnum-PSI by in-situ laser induced breakdown spectroscopy (LIBS). The results indicate that, after deuterium plasma exposure, deuterium retention could be saturated in the lithiation layer, and the lithium in the lithiated layer is chemically bound with deuterium. Moreover, the lithiation can inhibit the blistering on the tungsten surface. These results can be valuable for the application of LIBS as a diagnostic technique for plasma-facing components of tokamaks.

  20. Time-resolved vibrational spectroscopy of a molecular shuttle

    NARCIS (Netherlands)

    Panman, M.R.; Bodis, P.; Shaw, D.J.; Bakker, B.H.; Newton, A.C.; Kay, E.R.; Leigh, D.A.; Buma, W.J.; Brouwer, A.M.; Woutersen, S.

    2012-01-01

    Time-resolved vibrational spectroscopy is used to investigate the inter-component motion of an ultraviolet-triggered two-station molecular shuttle. The operation cycle of this molecular shuttle involves several intermediate species, which are observable in the amide I and amide II regions of the mid

  1. Magnetic excitations studied with time-of-flight spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Rainford, B. [Southampton Univ. (United Kingdom). Dept. of Physics

    1996-11-01

    An introduction to time-of-flight neutron spectroscopy is presented in the context of the study of magnetic materials. Examples are taken from the class of rare earth and actinide magnetic materials known as `strongly correlated electron` systems. (author) 11 figs., 24 refs.

  2. Terahertz Time Domain Spectroscopy for Structure-II Gas Hydrates

    DEFF Research Database (Denmark)

    Takeya, Kei; Zhang, Caihong; Kawayama, Iwao

    2009-01-01

    For the nondestructive inspection of gas hydrates, terahertz (THz) time-domain spectroscopy (TDS) was applied to tetrahydrofuran (THF) hydrate and propane hydrate. The absorption of propane hydrate monotonically increases with frequency, similar to the case of ice, while THF hydrate has a charact...

  3. Terahertz time-domain spectroscopy and imaging of artificial RNA

    DEFF Research Database (Denmark)

    Fischer, Bernd M.; Hoffmann, Matthias; Helm, Hanspeter

    2005-01-01

    We use terahertz time-domain spectroscopy (THz-TDS) to measure the far-infrared dielectric function of two artificial RNA single strands, composed of polyadenylic acid (poly-A) and polycytidylic acid (poly-C). We find a significant difference in the absorption between the two types of RNA strands...... in the absorption spectra....

  4. Terahertz time-domain spectroscopy and imaging of artificial RNA

    DEFF Research Database (Denmark)

    Fischer, Bernd M.; Hoffmann, Matthias; Helm, Hanspeter

    2005-01-01

    We use terahertz time-domain spectroscopy (THz-TDS) to measure the far-infrared dielectric function of two artificial RNA single strands, composed of polyadenylic acid (poly-A) and polycytidylic acid (poly-C). We find a significant difference in the absorption between the two types of RNA strands...

  5. Time- and space-resolved X-ray absorption spectroscopy of aluminum irradiated by a subpicosecond high-power laser

    Science.gov (United States)

    Tzortzakis, S.; Audebert, P.; Renaudin, P.; Bastiani-Ceccotti, S.; Geindre, J. P.; Chenais-Popovics, C.; Nagels, V.; Gary, S.; Shepherd, R.; Girard, F.; Matsushima, I.; Peyrusse, O.; Gauthier, J.-C.

    2006-05-01

    The ionization and recombination dynamics of transient aluminum plasmas was measured using point projection K-shell absorption spectroscopy. An aluminum plasma was produced with a subpicosecond beam of the 100-TW laser at the LULI facility and probed at different times with a picosecond X-ray backlighter created with a synchronized subpicosecond laser beam. Fourier-Domain-Interferometry (FDI) was used to measure the electron temperature at the peak of the heating laser pulse. Absorption X-ray spectra at early times are characteristic of a dense and rather homogeneous plasma, with limited longitudinal gradients as shown by hydrodynamic simulations. The shift of the Al K-edge was measured in the cold dense plasma located at the edge of the heated plasma. From the 1s 2p absorption spectra, the average ionization was measured as a function of time and was also modeled with a collisional-radiative atomic physics code coupled with hydrodynamic simulations.

  6. Drop coating deposition Raman spectroscopy of blood plasma for the detection of colorectal cancer

    Science.gov (United States)

    Li, Pengpeng; Chen, Changshui; Deng, Xiaoyuan; Mao, Hua; Jin, Shaoqin

    2015-03-01

    We have recently applied the technique of drop coating deposition Raman (DCDR) spectroscopy for colorectal cancer (CRC) detection using blood plasma. The aim of this study was to develop a more convenient and stable method based on blood plasma for noninvasive CRC detection. Significant differences are observed in DCDR spectra between healthy (n=105) and cancer (n=75) plasma from 15 CRC patients and 21 volunteers, particularly in the spectra that are related to proteins, nucleic acids, and β-carotene. The multivariate analysis principal components analysis and the linear discriminate analysis, together with leave-one-out, cross validation were used on DCDR spectra and yielded a sensitivity of 100% (75/75) and specificity of 98.1% (103/105) for detection of CRC. This study demonstrates that DCDR spectroscopy of blood plasma associated with multivariate statistical algorithms has the potential for the noninvasive detection of CRC.

  7. Time-dependent Integrated Predictive Modeling of ITER Plasmas

    Institute of Scientific and Technical Information of China (English)

    R.V. Budny

    2007-01-01

    @@ Introduction Modeling burning plasmas is important for speeding progress toward practical Tokamak energy production. Examples of issues that can be elucidated by modelinginclude requirements for heating, fueling, torque, and current drive systems, design of diagnostics, and estimates of the plasma performance (e.g., fusion power production) in various plasma scenarios. The modeling should be time-dependent to demonstrate that burning plasmas can be created, maintained (controlled), and terminated successfully. The modeling also should be integrated to treat self-consistently the nonlinearities and strong coupling between the plasma, heating, current drive, confinement, and control systems.

  8. Collisional-radiative model: a plasma spectroscopy theory for experimentalists

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, Takashi [Kyoto Univ. (Japan); Sawada, Keiji

    1997-01-01

    The rate equation describing the population n(p) of an excited (and the ground state) level p of ions immersed in plasma is shown. In 1962, the method of quasi-steady state solution (collisional-radiative model) was proposed. Its idea is explained. The coupled differential equations reduce to a set of coupled linear equations for excited levels. The solution of these coupled equations is presented. The equations giving the ionization and recombination of this system of ions under consideration are described in terms of the effective rate coefficients. The collisional-radiative ionization and recombination rate coefficients are expressed in terms of the population coefficients for p > 1. As for ionizing plasma, the excited level populations, the populations, the population distribution among the excited levels, two regimes of the excited levels, the dominant flows of electrons among the levels and so on are shown. As for recombining plasma, the excited level populations, the population distribution among the excited levels, the dominant flows of electrons and so on are shown. Ionization balance plasma may be considered. (K.I.)

  9. Simulations for plasma spectroscopy based on UTA theory

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    The unresolved transition array(UTA) simulation with configurationaverage approximation is used to calculate the spectral properties ofplasmas involving complex ions. This method is used to simulate thetransmission of X-rays through aluminum plasma and niobium plasmarespectively. The results are compared with experiments and other results ofadvanced models and good agreements are obtained.

  10. Adaptive real-time dual-comb spectroscopy

    CERN Document Server

    Ideguchi, Takuro; Guelachvili, Guy; Picqué, Nathalie; Hänsch, Theodor W

    2012-01-01

    With the advent of laser frequency combs, coherent light sources that offer equally-spaced sharp lines over a broad spectral bandwidth have become available. One decade after revolutionizing optical frequency metrology, frequency combs hold much promise for significant advances in a growing number of applications including molecular spectroscopy. Despite its intriguing potential for the measurement of molecular spectra spanning tens of nanometers within tens of microseconds at Doppler-limited resolution, the development of dual-comb spectroscopy is hindered by the extremely demanding high-bandwidth servo-control conditions of the laser combs. Here we overcome this difficulty. We experimentally demonstrate a straightforward concept of real-time dual-comb spectroscopy, which only uses free-running mode-locked lasers without any phase-lock electronics, a posteriori data-processing, or the need for expertise in frequency metrology. The resulting simplicity and versatility of our new technique of adaptive dual-com...

  11. Spatially resolved spectroscopy of an atmospheric pressure microwave plasma jet used for surface treatment

    OpenAIRE

    Potočňáková Lucia; Hnilica Jaroslav; Kudrle Vít

    2014-01-01

    In this study, the variations of properties of a microwave plasma jet (surfatron) along the discharge axis have been investigated using optical emission spectroscopy. As the argon jet is not enclosed, the spatial distribution of individual species in effluent plasma is the result of rather complicated interplay between energy loss and gradual mixing with the air. Spatial 2D relative intensity profiles of atomic lines and molecular bands at 310 nm, 336 nm, 391 nm and 656 nm are presented in th...

  12. Development of a gated optical multichannel analyser for laser-plasma spectroscopy

    OpenAIRE

    Corcoran, Richard

    1990-01-01

    An Optical Multichannel Analyser (OMA) has been developed for the detection of radiation from laser-produced plasmas (LPPs). The system is based on a gated image - intensified photodiode array (PDA) Software for the control of, and data acquisition from, the OMA system has been developed. A high resolution (10ns) delay generator was also designed and constructed to permit timeresolved. optical spectroscopy. The system has been tested and operated with a laser plasma source m...

  13. Seventh international conference on time-resolved vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dyer, R.B.; Martinez, M.A.D.; Shreve, A.; Woodruff, W.H. [comps.

    1997-04-01

    The International Conference on Time-Resolved Vibrational Spectroscopy (TRVS) is widely recognized as the major international forum for the discussion of advances in this rapidly growing field. The 1995 conference was the seventh in a series that began at Lake Placid, New York, 1982. Santa Fe, New Mexico, was the site of the Seventh International Conference on Time-Resolved Vibrational Spectroscopy, held from June 11 to 16, 1995. TRVS-7 was attended by 157 participants from 16 countries and 85 institutions, and research ranging across the full breadth of the field of time-resolved vibrational spectroscopy was presented. Advances in both experimental capabilities for time-resolved vibrational measurements and in theoretical descriptions of time-resolved vibrational methods continue to occur, and several sessions of the conference were devoted to discussion of these advances and the associated new directions in TRVS. Continuing the interdisciplinary tradition of the TRVS meetings, applications of time-resolved vibrational methods to problems in physics, biology, materials science, and chemistry comprised a large portion of the papers presented at the conference.

  14. Single and double core-hole ion emission spectroscopy of transient neon plasmas produced by ultraintense x-ray laser pulses

    Science.gov (United States)

    Gao, Cheng; Zeng, Jiaolong; Yuan, Jianmin

    2016-05-01

    Single core-hole (SCH) and double core-hole (DCH) spectroscopy is investigated systematically for neon gas in the interaction with ultraintense x-ray pulses with photon energy from 937 eV to 2000 eV. A time-dependent rate equation, implemented in the detailed level accounting approximation, is utilized to study the dynamical evolution of the level population and emission properties of the laser-produced highly transient plasmas. The plasma density effects on level populations are demonstrated with an x-ray photon energy of 2000 eV. For laser photon energy in the range of 937 - 1360 eV, resonant absorptions (RA) of 1s-np (n> = 2) transitions play important roles in time evolution of the population and DCH emission spectroscopy. For x-ray photon energy larger than 1360 eV, no RA exist and transient plasmas show different features in the DCH spectroscopy.

  15. The Time-Frequency Characteristics of Pulse Propagation Through Plasma

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In this paper, propagated δ pulses through different distance of Plasma are calculated, and their time-frequency characteristics are studied using CWD (Choi-William distrilution). It is found that several horizontal spectra appear at early arrival time like discrete spectruml at last time a hyperbolic curve lies in the time-frequency spectrum which corresponds to the frequency-group delay curve of plasma. To understand the time-frequency, the property of a signal is helpful for obtaining the plasma parameters.

  16. The use of laser-induced plasma spectroscopy technique for the characterization of boiler tubes

    Energy Technology Data Exchange (ETDEWEB)

    Nicolas, G. [Universidad de A Coruna, Departamento de Ingenieria Industrial II, E-15403 Ferrol (A Coruna) (Spain)], E-mail: gines@cdf.udc.es; Mateo, M.P.; Yanez, A. [Universidad de A Coruna, Departamento de Ingenieria Industrial II, E-15403 Ferrol (A Coruna) (Spain)

    2007-12-15

    The present work focuses on the characterization of boiler tube walls using laser-induced plasma spectroscopy technique with visual inspection by optical and scanning electron microscopy of the cross-sections of these tubes. In a watertube boiler, water runs through tubes that are surrounded by a heating source. As a result, the water is heated to very high temperatures, causing accumulation of deposits on the inside surfaces of the tubes. These deposits play an important role in the efficiency of the boiler tube because they produce a reduction of the boiler heat rate and an increase in the number of tube failures. The objectives are to determine the thickness and arrangement of deposits located on the highest heat area of the boiler and compare them with tube parts where the heat flux is lower. The major deposits found were copper and magnetite. These deposits come mainly from the boiler feedwater and from the reaction between iron and water, and they do not form on the tube walls at a uniform rate over time. Their amount depends on the areas where they are collected. A Nd:YAG laser operating at 355 nm has been used to perform laser-induced plasma spectra and depth profiles of the deposits.

  17. Spectroscopy Measurements on Ablation Testing in High Enthalpy Plasma Flows

    Science.gov (United States)

    2010-11-01

    stagnation point, are located on the ablative material sample. 3.5 InfraRed THERMOGRAPHY Surface temperature measurement is a topic of great concern...high temperature material at two different narrow wavelengths. The temperature is calculated by building the ratio of the radiation intensities. The...this work is to develop the capability of testing and characterization of ablative materials exposed to high enthalpy plasma flows including both

  18. Time resolved laser-induced breakdown spectroscopy for calcium concentration detection in water

    Institute of Scientific and Technical Information of China (English)

    WU Jiang-lai; LU Yuan; Li Ying; CHENG Kai; GUO Jin-jia; ZHENG Rong-er

    2011-01-01

    @@ The laser induced breakdown spectroscopy (LIBS) is an element analysis technique with the advantages of real time detection, simultaneous multi-element identification, and in-situ and stand-off capacities.To evaluate its potential of ocean applications, in this paper, the time resolved laser-induced breakdown spectroscopy for calcium concentration detection in water is investigated.With the optimum experimental parameters, the plasma emission lifetime is determined to be about 500 ns with 532 nm laser excitation, and 1000 ns with 1064 nm laser excitation.The lowest detection concentration of 50ppm is achieved for calcium detection in CaC12 water solution using the 532 nm LIBS.Even better detection sensitivity is achieved using the 1064 nm LIBS, and the resulted lowest detection concentration of calcium is 25 ppm.The results suggest that it is feasible to develop LIBS as an on-line sensor for metal element monitoring in the sea.

  19. Synthesis of low carbon boron carbide powder using a minimal time processing route: Thermal plasma

    Directory of Open Access Journals (Sweden)

    Avinna Mishra

    2015-12-01

    Full Text Available Boron carbide powder was synthesized by thermal plasma reduction of boric acid in presence of graphite with a very minimal processing time. Subsequently, the as-synthesized products were leached to minimize the impurities content. Based on the results of X-ray diffraction and Raman spectroscopy, the effect of leaching on phase purity and crystallinity was studied. X-ray photoelectron spectroscopy was performed to identify the chemical composition which highlighted the absence of the BO bonding in the deconvoluted B 1s core-level spectrum. Finally, the temperature dependent thermal conductivity behavior of the leached materials was analyzed and presented.

  20. Real-Time Fault Classification for Plasma Processes

    OpenAIRE

    Yang, Ryan; Chen, Rongshun

    2011-01-01

    Plasma process tools, which usually cost several millions of US dollars, are often used in the semiconductor fabrication etching process. If the plasma process is halted due to some process fault, the productivity will be reduced and the cost will increase. In order to maximize the product/wafer yield and tool productivity, a timely and effective fault process detection is required in a plasma reactor. The classification of fault events can help the users to quickly identify fault processes, ...

  1. Ultrafast Time-Resolved Hard X-Ray Emission Spectroscopy on a Tabletop

    Science.gov (United States)

    Miaja-Avila, Luis; O'Neil, Galen C.; Joe, Young I.; Alpert, Bradley K.; Damrauer, Niels H.; Doriese, William B.; Fatur, Steven M.; Fowler, Joseph W.; Hilton, Gene C.; Jimenez, Ralph; Reintsema, Carl D.; Schmidt, Daniel R.; Silverman, Kevin L.; Swetz, Daniel S.; Tatsuno, Hideyuki; Ullom, Joel N.

    2016-07-01

    Experimental tools capable of monitoring both atomic and electronic structure on ultrafast (femtosecond to picosecond) time scales are needed for investigating photophysical processes fundamental to light harvesting, photocatalysis, energy and data storage, and optical display technologies. Time-resolved hard x-ray (>3 keV ) spectroscopies have proven valuable for these measurements due to their elemental specificity and sensitivity to geometric and electronic structures. Here, we present the first tabletop apparatus capable of performing time-resolved x-ray emission spectroscopy. The time resolution of the apparatus is better than 6 ps. By combining a compact laser-driven plasma source with a highly efficient array of microcalorimeter x-ray detectors, we are able to observe photoinduced spin changes in an archetypal polypyridyl iron complex [Fe (2 ,2'-bipyridine)3]2 + and accurately measure the lifetime of the quintet spin state. Our results demonstrate that ultrafast hard x-ray emission spectroscopy is no longer confined to large facilities and now can be performed in conventional laboratories with 10 times better time resolution than at synchrotrons. Our results are enabled, in part, by a 100- to 1000-fold increase in x-ray collection efficiency compared to current techniques.

  2. Real-time optical plasma boundary reconstruction for plasma position control at the TCV Tokamak

    NARCIS (Netherlands)

    Hommen, G.; Baar, M. de; Duval, B.P.; Andrebe, Y.; Le, H.B.; Klop, M.A.; Doelman, N.J.; Witvoet, G.; Steinbuch, M.

    2014-01-01

    A dual, high speed, real-time visible light camera setup was installed on the TCV tokamak to reconstruct optically and in real-time the plasma boundary shape. Localized light emission from the plasma boundary in tangential view, broadband visible images results in clearly resolved boundary edge-feat

  3. Emission spectroscopy of laser-ablated Si plasma related to nanoparticle formation

    Science.gov (United States)

    Narayanan, V.; Thareja, R. K.

    2004-01-01

    We report on the laser ablation of Si in vacuum, and in the presence of helium ambient at 1 and 10 Torr, respectively. The silicon nanoparticles were deposited on silicon substrate at room temperature by ablating silicon wafer in ambient atmosphere of helium at 1 Torr. The mean cluster size ranging from 1.8 to 4.4 nm is observed depending on the laser intensity. Optical emission spectroscopy and images of the plume are used to study the spatial and temporal variation of the silicon plasma. The electron density, measured by the Stark-broadening of Si I transition 3 p2 1S-4 s 1P0 at 390.55 nm and temperature, assuming thermal equilibrium, were found to be 1.2×10 18 cm -3 and 2 eV, respectively. The temporal variation of Si I transition 3 p2 1S-4 s 1P0 at 390.55 nm showed a shift in peak position attributed to collisions at an early stage of plasma formation. The relative concentration of Si II/Si I estimated by using the Saha-Boltzmann relation showed abundance of Si I. Time resolved images of the plume were used to investigate the dynamics of the expanding plasma plume, estimating the vapor pressure, vapor temperature, velocity, and stopping distance of the plume. The photoluminescent spectra of the Si thin films showed three distinct emission bands at 2.7, 2.2 and 1.69 eV, the origin of these bands is attributed to defects and quantum confinement.

  4. Optical spectroscopy of free-propagating plasma and its interaction with tungsten targets in PF-1000 facility

    Energy Technology Data Exchange (ETDEWEB)

    Skladnik-Sadowska, E.; Malinowski, K. [The Andrzej Soltan Institute for Nuclear Studies, IPJ, 05-400 Otwock-Swierk (Poland); Sadowski, M.J. [The Andrzej Soltan Institute for Nuclear Studies, IPJ, 05-400 Otwock-Swierk (Poland)] [Institute of Plasma Physics and Laser Microfusion, IPPLM, 01-497 Warsaw (Poland); Kubkowska, M.; Jakubowska, K.; Paduch, M.; Scholz, M. [Institute of Plasma Physics and Laser Microfusion, IPPLM, 01-497 Warsaw (Poland); Garkusha, I.E.; Ladygina, M.; Tereshin, V.I. [Institute of Plasma Physics, NSC KIPT, 61-108 Kharkov (Ukraine)

    2011-07-01

    The paper reports on optical spectroscopy of pulsed plasma streams during their free propagation within a vacuum chamber and their interaction with tungsten targets. Experiments were performed with the PF-1000 facility and particular attention was paid to improvements in spectroscopic diagnostics techniques. In contrary to preliminary studies, the recent spectroscopic measurements of the free plasma streams were carried out perpendicular to the z-axis and at a larger distance from the electrode outlet. The center of the observation quartz-window was located at z = 30 cm in order to observe first a pure deuterium-plasma stream, and later on some heavy impurities which might reach that distance with a delay induced by differences in their production and time-of-flight. The recorded spectral lines were identified by means of a Kurucz database. It was confirmed that at the pure D{sub 2}-filling the PF-1000 facility emits first the deuterium-plasma stream and one can observe intense deuterium Balmer lines, but at a distance z = 30 cm, after about 2 microseconds there appear many impurity lines originating mainly from the Cu-electrodes, i.e. Cu-lines. The second part of the experiment concerned the spectroscopic measurements of metal plasma 'pillow' produced by the plasma stream impinging upon a solid target made of pure tungsten. The described measurements enabled the most intense spectral lines to be identified. This document is composed of an abstract followed by the slides of the presentation

  5. Time-related surface modification of denture base acrylic resin treated by atmospheric pressure cold plasma.

    Science.gov (United States)

    Qian, Kun; Pan, Hong; Li, Yinglong; Wang, Guomin; Zhang, Jue; Pan, Jie

    2016-01-01

    The changes of denture base acrylic resin surface properties under cold plasma and the relationships with time were investigated. Cold plasma treated the specimens for 30 s, 60 s, 90 s, and 120 s, respectively. Water contact angles were measured immediately after the treatment, 48 h, 15 days and 30 days later. Surface roughness was measured with 3-D laser scanning microscope. Candida albicans adherence was evaluated by CFU counting. Chemical composition was monitored by X-ray photoelectron spectroscopy analysis. Water contact angle reduced after treated for 30 s. No changes were observed with time prolonged, except the durability. There were no differences in roughness among all groups. However, treatment groups showed significantly lower C. albicans adherence. XPS demonstrated a decrease in C/O, and this reduction was affected by treatment time. Cold plasma was an effective means of increasing hydrophilicity of acrylic resin and reducing C. albicans adherence without affecting physical properties.

  6. [A method for time-resolved laser-induced breakdown spectroscopy measurement].

    Science.gov (United States)

    Pan, Cong-Yuan; Han, Zhen-Yu; Li, Chao-Yang; Yu, Yun-Si; Wang, Sheng-Bo; Wang, Qiu-Ping

    2014-04-01

    Laser-Induced Breakdown Spectroscopy (LIBS) is strongly time related. Time-resolved LIBS measurement is an important technique for the research on laser induced plasma evolution and self-absorption of the emission lines. Concerning the temporal characteristics of LIBS spectrum, a method is proposed in the present paper which can achieve micros-scale time-resolved LIBS measurement by using general ms-scale detector. By setting different integration delay time of the ms-scale spectrum detector, a series of spectrum are recorded. And the integration delay time interval should be longer than the worst temporal precision. After baseline correction and spectrum fitting, the intensity of the character line was obtained. Calculating this intensity with differential method at a certain time interval and then the difference value is the time-resolved line intensity. Setting the plasma duration time as X-axis and the time-resolved line intensity as Y-axis, the evolution curve of the character line intensity can be plotted. Character line with overlap-free and smooth background should be a priority to be chosen for analysis. Using spectrometer with ms-scale integration time and a control system with temporal accuracy is 0.021 micros, experiments carried out. The results validate that this method can be used to characterize the evolution of LIBS characteristic lines and can reduce the cost of the time-resolved LIBS measurement system. This method makes high time-resolved LIBS spectrum measurement possible with cheaper system.

  7. Real-time in vivo cancer diagnosis using Raman spectroscopy.

    Science.gov (United States)

    Wang, Wenbo; Zhao, Jianhua; Short, Michael; Zeng, Haishan

    2015-07-01

    Raman spectroscopy has becoming a practical tool for rapid in vivo tissue diagnosis. This paper provides an overview on the latest development of real-time in vivo Raman systems for cancer detection. Instrumentation, data handling, as well as oncology applications of Raman techniques were covered. Optic fiber probes designs for Raman spectroscopy were discussed. Spectral data pre-processing, feature extraction, and classification between normal/benign and malignant tissues were surveyed. Applications of Raman techniques for clinical diagnosis for different types of cancers, including skin cancer, lung cancer, stomach cancer, oesophageal cancer, colorectal cancer, cervical cancer, and breast cancer, were summarized. Schematic of a real-time Raman spectrometer for skin cancer detection. Without correction, the image captured on CCD camera for a straight entrance slit has a curvature. By arranging the optic fiber array in reverse orientation, the curvature could be effectively corrected. © 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Examining Electron-Boson Coupling Using Time-Resolved Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Sentef, Michael; Kemper, Alexander F.; Moritz, Brian; Freericks, James K.; Shen, Zhi-Xun; Devereaux, Thomas P.

    2013-12-26

    Nonequilibrium pump-probe time-domain spectroscopies can become an important tool to disentangle degrees of freedom whose coupling leads to broad structures in the frequency domain. Here, using the time-resolved solution of a model photoexcited electron-phonon system, we show that the relaxational dynamics are directly governed by the equilibrium self-energy so that the phonon frequency sets a window for “slow” versus “fast” recovery. The overall temporal structure of this relaxation spectroscopy allows for a reliable and quantitative extraction of the electron-phonon coupling strength without requiring an effective temperature model or making strong assumptions about the underlying bare electronic band dispersion.

  9. Time resolved spectroscopy of GRB 030501 using INTEGRAL

    DEFF Research Database (Denmark)

    Beckmann, V.; Borkowski, J.; Courvoisier, T.J.L.;

    2003-01-01

    The gamma-ray instruments on-board INTEGRAL offer an unique opportunity to perform time resolved analysis on GRBs. The imager IBIS allows accurate positioning of GRBs and broad band spectral analysis, while SPI provides high resolution spectroscopy. GRB 030501 was discovered by the INTEGRAL Burst...... Alert System in the ISGRI field of view. Although the burst was fairly weak (fluence F20-200 keV similar or equal to 3.5x10(-6) erg cm(-2)) it was possible to perform time resolved spectroscopy with a resolution of a few seconds. The GRB shows a spectrum in the 20-400 keV range which is consistent...

  10. Metal-wire terahertz time-domain spectroscopy

    Science.gov (United States)

    Walther, Markus; Freeman, Mark R.; Hegmann, Frank A.

    2005-12-01

    Terahertz (THz) pulses propagating on a metal-wire waveguide are used to perform terahertz time-domain spectroscopy of lactose powder dispersed on top of the wire. The THz pulses are generated by a photoconductive switch at one end of the metal wire and are detected at the other end by electro-optic sampling in a ZnTe crystal that can be moved parallel to the axis of the metal wire. A large enhancement in the peak amplitude of the THz signal is observed by contacting the metal wire to one of the electrodes of the photoconductive switch. The propagation characteristics of the THz pulse along the metal wire and near its end are studied. Potential applications of metal-wire terahertz time-domain spectroscopy are discussed.

  11. Physical design of positronium time of flight spectroscopy apparatus

    Institute of Scientific and Technical Information of China (English)

    JIANG Xiao-Pan; ZHANG Zi-Liang; QIN Xiu-Bo; YU Run-Sheng; WANG Bao-Yi

    2010-01-01

    Positronium time of flight spectroscopy(Ps-TOF)is an effective technique for porous material research.It has advantages over other techniques for analyzing the porosity and pore tortuosity of materials.This paper describes a design for Ps-TOF apparatus based on the Beijing intense slow positron beam,supplying a new material characterization technique.In order to improve the time resolution and increase the count rate of the apparatus,the detector system is optimized.For 3 eV o-Ps,the time broadening is 7.66 ns and the count rate is 3 cps after correction.

  12. Development of ultrafast time-resolved dual-comb spectroscopy

    Directory of Open Access Journals (Sweden)

    Akifumi Asahara

    2017-04-01

    Full Text Available Ultrafast time-resolved dual-comb spectroscopy (TR-DCS has been demonstrated, which enables direct observations of transient responses of complex optical spectra by combining dual-comb spectroscopy with the pump–probe method. TR-DCS achieves two-dimensional spectroscopy with a wide dynamic range for both the temporal and frequency axes. As a demonstration, we investigated the femtosecond relaxation dynamics of a photo-excited InGaAs saturable absorber in the near-infrared frequency region. The transient response of the interferogram was successfully obtained, and both the amplitude and phase spectra of the dynamic complex transmittance were independently deduced without using the Kramers-Kronig relations. A high phase resolution in the order of milliradian was achieved by suppressing the effect from the slow phase drift caused in the experimental system. Our proof-of-principle experiment promotes a pathway to coherent, highly accurate, and multi-dimensional pump–probe spectroscopy using the optical frequency comb technology.

  13. Adaptive real-time dual-comb spectroscopy

    Science.gov (United States)

    Ideguchi, Takuro; Poisson, Antonin; Guelachvili, Guy; Picqué, Nathalie; Hänsch, Theodor W.

    2014-01-01

    The spectrum of a laser frequency comb consists of several hundred thousand equally spaced lines over a broad spectral bandwidth. Such frequency combs have revolutionized optical frequency metrology and they now hold much promise for significant advances in a growing number of applications including molecular spectroscopy. Despite an intriguing potential for the measurement of molecular spectra spanning tens of nanometres within tens of microseconds at Doppler-limited resolution, the development of dual-comb spectroscopy is hindered by the demanding stability requirements of the laser combs. Here we overcome this difficulty and experimentally demonstrate a concept of real-time dual-comb spectroscopy, which compensates for laser instabilities by electronic signal processing. It only uses free-running mode-locked lasers without any phase-lock electronics. We record spectra spanning the full bandwidth of near-infrared fibre lasers with Doppler-limited line profiles highly suitable for measurements of concentrations or line intensities. Our new technique of adaptive dual-comb spectroscopy offers a powerful transdisciplinary instrument for analytical sciences. PMID:24572636

  14. Adaptive real-time dual-comb spectroscopy

    Science.gov (United States)

    Ideguchi, Takuro; Poisson, Antonin; Guelachvili, Guy; Picqué, Nathalie; Hänsch, Theodor W.

    2014-02-01

    The spectrum of a laser frequency comb consists of several hundred thousand equally spaced lines over a broad spectral bandwidth. Such frequency combs have revolutionized optical frequency metrology and they now hold much promise for significant advances in a growing number of applications including molecular spectroscopy. Despite an intriguing potential for the measurement of molecular spectra spanning tens of nanometres within tens of microseconds at Doppler-limited resolution, the development of dual-comb spectroscopy is hindered by the demanding stability requirements of the laser combs. Here we overcome this difficulty and experimentally demonstrate a concept of real-time dual-comb spectroscopy, which compensates for laser instabilities by electronic signal processing. It only uses free-running mode-locked lasers without any phase-lock electronics. We record spectra spanning the full bandwidth of near-infrared fibre lasers with Doppler-limited line profiles highly suitable for measurements of concentrations or line intensities. Our new technique of adaptive dual-comb spectroscopy offers a powerful transdisciplinary instrument for analytical sciences.

  15. Time-resolved laser-induced breakdown spectroscopy of aluminum

    Institute of Scientific and Technical Information of China (English)

    LIU Xian-yun; ZHANG Wei-jun; WANG Zhen-ya; HAO Li-qing; HUANG Ming-qiang; ZHAO Wen-wu; LONG Bo; Zhao Wei

    2008-01-01

    We develop a system to measure the elemental composition of unprepared samples using laser-induced breakdown spectroscopy (LIBS) in our laboratory, which can be used for the determination of elements in solids, liquids and aerosols. A description of the instrumentation, including laser, sample chamber and detection, is followed by a brief discussion. The time-resolved LIBS of aluminum at atmospheric pressure is presented. At the end, the possibilities and later uses of this technique are briefly discussed.

  16. Ultrafast chiroptical spectroscopy: Monitoring optical activity in quick time

    Directory of Open Access Journals (Sweden)

    Hanju Rhee

    2011-12-01

    Full Text Available Optical activity spectroscopy provides rich structural information of biologically important molecules in condensed phases. However, a few intrinsic problems of conventional method based on electric field intensity measurement scheme prohibited its extension to time domain technique. We have recently developed new types of optical activity spectroscopic methods capable of measuring chiroptical signals with femtosecond pulses. It is believed that these novel approaches will be applied to a variety of ultrafast chiroptical studies.

  17. Terahertz Time-Domain Spectroscopy of Glucose and Uric Acid

    OpenAIRE

    Upadhya, P.C.; Shen, Y.C.; Davies, A. G.; Linfield, E. H.

    2003-01-01

    We report the use ofterahertz time-domain spectroscopy for thestudy of two therapeutic bio-molecules:glucose and uric acid. Terahertztransmission spectra of crystalline samplesof both molecules were measured between 0.1–3.0 THz using an evacuated spectroscopysystem. We propose that the stereo-isomersof glucose show spectral featuresoriginating from intermolecular vibrationalmodes, as do uric acid and its derivativemolecule, allantoin. In addition, wepresent a full temperature dependence ofthe...

  18. Advances in experimental spectroscopy of Z-pinch plasmas and applications

    Science.gov (United States)

    Kantsyrev, V. L.; Safronova, A. S.; Safronova, U. I.; Shrestha, I.; Weller, M. E.; Osborne, G. C.; Shlyaptseva, V. V.; Wilcox, P. G.; Stafford, A.

    2012-06-01

    Recent advances in experimental work on plasma spectroscopy of Z-pinches are presented. The results of experiments on the 1.7 MA Z-pinch Zebra generator at UNR with wire arrays of various configurations and X-pinches are overviewed. A full x-ray and EUV diagnostic set for detailed spatial and temporal monitoring of such plasmas together with theoretical support from relativistic atomic structure and non-LTE kinetic codes used in the analysis are discussed. The use of a variety of wire materials in a broad range from Al to W provided an excellent opportunity to observe and study specific atomic and plasma spectroscopy features. In addition, the applications of such features to fusion and astrophysics will be considered.

  19. Time-resolved characterization of a filamentary argon discharge at atmospheric pressure in a capillary using emission and absorption spectroscopy

    Science.gov (United States)

    Schröter, Sandra; Pothiraja, Ramasamy; Awakowicz, Peter; Bibinov, Nikita; Böke, Marc; Niermann, Benedikt; Winter, Jörg

    2013-11-01

    An argon/nitrogen (0.999/0.001) filamentary pulsed discharge operated at atmospheric pressure in a quartz tube is characterized using voltage-current measurements, microphotography, optical emission spectroscopy (OES) and absorption spectroscopy. Nitrogen is applied as a sensor gas for the purpose of OES diagnostic. The density of argon metastable atoms Ar(3P2) is determined using tunable diode laser absorption spectroscopy (TDLAS). Using a plasma chemical model the measured OES data are applied for the characterization of the plasma conditions. Between intense positive pulses the discharge current oscillates with a damped amplitude. It is established that an electric current flows in this discharge not only through a thin plasma filament that is observed in the discharge image but also through the whole cross section of the quartz tube. A diffuse plasma fills the quartz tube during a time between intense current pulses. Ionization waves are propagating in this plasma between the spike and the grounded area of the tube producing thin plasma channels. The diameter of these channels increases during the pause between the propagation of ionization waves probably because of thermal expansion and diffusion. Inside the channels electron densities of ˜2 × 1013 cm-3, argon metastable densities ˜1014 cm-3 and a reduced electric field about 10 Td are determined.

  20. Time Evolution of Artificial Plasma Cloud in Atmospheric Environment

    Institute of Scientific and Technical Information of China (English)

    陆启明; 杨维纮; 刘万东

    2004-01-01

    By analyzing the time evolution of artificial plasma cloud in the high altitude of atmospheric environment, we found that there are two zones, an exponential attenuation zone and a linearly attenuating zone, existing in the spatial distribution of electron density of the artificial plasma clouds. The plasma generator's particle flux density only contributes to the exponential attenuation zone, and has no effect on the linear attenuation zone. The average electron density in the linear attenuation zone is about 10-5 of neutral particle density, and can diffuse over a wider area. The conclusion will supply some valuable references to the research of electromagnetic wave and artificial plasma interaction, the plasma invisibleness research of missile and special aerocraft,and the design of artificial plasma source.

  1. Label-Free Optical Detection of Acute Myocardial Infarction Based on Blood Plasma Surface-Enhanced Raman Spectroscopy

    Science.gov (United States)

    Chen, Y. X.; Chen, M. W.; Lin, J. Y.; Lai, W. Q.; Huang, W.; Chen, H. Y.; Weng, G. X.

    2016-11-01

    This study is intended to explore the potential of silver (Ag) nanoparticle-based plasma surface-enhanced Raman spectroscopy (SERS) for providing a rapid and simple "Yes/No" assessment to detect acute myocardial infarction (AMI). A simple, rapid, and accurate method of diagnosing AMI is critical to reduce mortality and improve prognosis. Techniques such as electrocardiography examination and use of cardiac troponins have not yet met the current clinical need. Therefore, alternative approaches need to be developed. Plasma samples from 32 patients with AMI and 32 healthy control (Clt) subjects were assessed. Multivariate statistical techniques, including principal component (PC) analysis and linear discriminant analysis (PCA-LDA), were employed to develop a diagnostic algorithm for differentiating between patients with AMI and Clt subjects. Furthermore, the receiver operating characteristic was tested to evaluate the performance of the PCA-LDA algorithm for AMI detection. Each plasma sample was mixed with an equal volume of Ag colloidal solution, and the SERS measurement of each plasma sample was performed. The plasma SERS spectrum showed much stronger and sharper peaks compared with the normal Raman spectrum. Tentative assignments of Raman spectroscopy bands showed specific biomolecular (e.g., proteins, adenosine, adenine, and uric acid) changes. PC analysis and LDA were employed to discriminate patients with AMI from Clt subjects, yielding a sensitivity of 87.5% and a specificity of 93.8%. The findings of this study suggest that plasma SERS has a great potential for improving AMI in the future, and this will certainly reduce the difficulty, time to draw blood, and patients' pain to a great extent.

  2. Limit of Spectral Resolution in Terahertz Time-Domain Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    Jingzhou Xu; Tao Yuan; Samuel Mickan; X.-C.Zhang

    2003-01-01

    The pulsed nature of terahertz time-domain spectroscopy (THz-TDS) sets a fundamental limit on its spectral resolution. The spectral resolution of THz-TDS can be improved by increasing the duration of the temporal measurement, but is limited by the dynamic range of the system in the time domain. This paper presents calculations and experimental results relating the temporal dynamic range of a THz-TDS system to its spectral resolution. We discuss three typical terahertz sources in terms of their dynamic range and hence achievable spectral resolution.

  3. Time-resolved photoluminescence spectroscopy of organic-plasmonic hybrids

    DEFF Research Database (Denmark)

    Leißner, Till; Brewer, Jonathan R.; Fiutowski, Jacek

    We study the optical properties of organic thin films and crystalline organic nanofibers as well as their interaction with plasmonic materials by means of laser-scanning fluorescence lifetime imaging microscopy (FLIM) and time-resolved photoluminescence spectroscopy (TR-PLS). The aim of our......-carrier dynamics in such systems. In this contribution we will show how the interaction of organic nanofibers placed on top of regular arrays of nanostructures leads to a significantly enhanced second-harmonic response and, at the same time, an increased decay rate of the photoluminescence lifetime....

  4. Multidimensional Time-Resolved Spectroscopy of Vibrational Coherence in Biopolyenes

    Science.gov (United States)

    Buckup, Tiago; Motzkus, Marcus

    2014-04-01

    Multidimensional femtosecond time-resolved vibrational coherence spectroscopy allows one to investigate the evolution of vibrational coherence in electronic excited states. Methods such as pump-degenerate four-wave mixing and pump-impulsive vibrational spectroscopy combine an initial ultrashort laser pulse with a nonlinear probing sequence to reinduce vibrational coherence exclusively in the excited states. By carefully exploiting specific electronic resonances, one can detect vibrational coherence from 0 cm-1 to over 2,000 cm-1 and map its evolution. This review focuses on the observation and mapping of high-frequency vibrational coherence for all-trans biological polyenes such as β-carotene, lycopene, retinal, and retinal Schiff base. We discuss the role of molecular symmetry in vibrational coherence activity in the S1 electronic state and the interplay of coupling between electronic states and vibrational coherence.

  5. Multidimensional time-resolved spectroscopy of vibrational coherence in biopolyenes.

    Science.gov (United States)

    Buckup, Tiago; Motzkus, Marcus

    2014-01-01

    Multidimensional femtosecond time-resolved vibrational coherence spectroscopy allows one to investigate the evolution of vibrational coherence in electronic excited states. Methods such as pump-degenerate four-wave mixing and pump-impulsive vibrational spectroscopy combine an initial ultrashort laser pulse with a nonlinear probing sequence to reinduce vibrational coherence exclusively in the excited states. By carefully exploiting specific electronic resonances, one can detect vibrational coherence from 0 cm(-1) to over 2,000 cm(-1) and map its evolution. This review focuses on the observation and mapping of high-frequency vibrational coherence for all-trans biological polyenes such as β-carotene, lycopene, retinal, and retinal Schiff base. We discuss the role of molecular symmetry in vibrational coherence activity in the S1 electronic state and the interplay of coupling between electronic states and vibrational coherence.

  6. Temperature and Electron Density Determination on Laser-Induced Breakdown Spectroscopy (LIBS) Plasmas: A Physical Chemistry Experiment

    Science.gov (United States)

    Najarian, Maya L.; Chinni, Rosemarie C.

    2013-01-01

    This laboratory is designed for physical chemistry students to gain experience using laser-induced breakdown spectroscopy (LIBS) in understanding plasma diagnostics. LIBS uses a high-powered laser that is focused on the sample causing a plasma to form. The emission of this plasma is then spectrally resolved and detected. Temperature and electron…

  7. Temperature and Electron Density Determination on Laser-Induced Breakdown Spectroscopy (LIBS) Plasmas: A Physical Chemistry Experiment

    Science.gov (United States)

    Najarian, Maya L.; Chinni, Rosemarie C.

    2013-01-01

    This laboratory is designed for physical chemistry students to gain experience using laser-induced breakdown spectroscopy (LIBS) in understanding plasma diagnostics. LIBS uses a high-powered laser that is focused on the sample causing a plasma to form. The emission of this plasma is then spectrally resolved and detected. Temperature and electron…

  8. System for time-resolved laser absorption spectroscopy and its application to high-power impulse magnetron sputtering

    Science.gov (United States)

    Adámek, P.; Olejníček, J.; Hubička, Z.; Čada, M.; Kment, Š.; Kohout, M.; Do, H. T.

    2017-02-01

    This paper deals with the development and construction of an apparatus for time-resolved tunable diode laser absorption spectroscopy (LAS) for the diagnostics of pulsed plasma. A detailed description of the extension of a progressive method of laser absorption spectroscopy in continuous regime to a direct triggering method of the time-resolved laser absorption spectroscopy (TR-LAS) is presented. The main advantage of the developed method is its capability to measure the time evolution of the whole absorption profile with a preset time resolution, which can be less than 1 μs. Therefore, the presented method of repetitive sampling applied on LAS in plasma processes is capable of simultaneous measurement of the density and kinetic temperature of selected particles. Its appropriate applications are to periodical processes in technological plasma, namely pulsed plasma discharges. The developed method of TR-LAS was applied to measurements of the temporal evolution of density and kinetic temperature of argon metastable species during high-power impulse magnetron sputtering of titanium and titanium dioxide thin films.

  9. Plasma-water systems studied with optical diagnostics including sum-frequency generation spectroscopy

    Science.gov (United States)

    Ito, Tsuyohito

    2016-09-01

    Recently, various applications of plasma-water systems have been reported, such as materials synthesis, agricultural applications, and medical treatments. As one of basic studies of such systems, we are investigating water surface structure influenced by a plasma via vibrational sum-frequency generation spectroscopy. Vibrational sum-frequency generation spectroscopy is known to be an interfacially active diagnostic technique, as such process occurs in noncentrosymmetric medium. Visible and wavenumber-tunable infrared beams are simultaneously irradiated to the interface. The interfacial water has ice-like ( 3200 cm-1), liquid-like ( 3400 cm-1), and free OH (3700 cm-1) structures (assignment of the ice-like structure still remains contentious), and the intensity of the signal becomes stronger when the tunable infrared beam resonates with a vibration of the structures. The results indicate that with generating air dielectric barrier discharges for supplying reactive species to the water surface, all investigated signals originating from the above-mentioned three structures decrease. Furthermore, the signal strengths are recovered after terminating the plasma generation. We currently believe that the surface density of the reactive species should be high when they are found at the water surface. Details on the experimental results of the sum-frequency generation spectroscopy, as well as other spectroscopic results of plasma-water systems, will be presented at the conference.

  10. Characterizing Hohlraum Plasma Conditions at the National Ignition Facility (NIF) Using X-ray Spectroscopy

    Science.gov (United States)

    Barrios, Maria Alejandra

    2015-11-01

    Improved hohlraums will have a significant impact on increasing the likelihood of indirect drive ignition at the NIF. In indirect-drive Inertial Confinement Fusion (ICF), a high-Z hohlraum converts laser power into a tailored x-ray flux that drives the implosion of a spherical capsule filled with D-T fuel. The x-radiation drive to capsule coupling sets the velocity, adiabat, and symmetry of the implosion. Previous experiments in gas-filled hohlraums determined that the laser-hohlraum energy coupling is 20-25% less than modeled, therefore identifying energy loss mechanisms that reduce the efficacy of the hohlraum drive is central to improving implosion performance. Characterizing the plasma conditions, particularly the plasma electron temperature (Te) , is critical to understanding mechanism that affect the energy coupling such as the laser plasma interactions (LPI), hohlraum x-ray conversion efficiency, and dynamic drive symmetry. The first Te measurements inside a NIF hohlraum, presented here, were achieved using K-shell X-ray spectroscopy of an Mn-Co tracer dot. The dot is deposited on a thin-walled CH capsule, centered on the hohlraum symmetry axis below the laser entrance hole (LEH) of a bottom-truncated hohlraum. The hohlraum x-ray drive ablates the dot and causes it to flow upward, towards the LEH, entering the hot laser deposition region. An absolutely calibrated streaked spectrometer with a line of sight into the LEH records the temporal history of the Mn and Co X-ray emission. The measured (interstage) Lyα/ Heα line ratios for Co and Mn and the Mn-Heα/Co-Heα isoelectronic line ratio are used to infer the local plasma Te from the atomic physics code SCRAM. Time resovled x-ray images perpendicular to the hohlraum axis record the dot expansion and trajectory into the LEH region. The temporal evolution of the measured Te and dot trajectory are compared with simulations from radiation-hydrodynamic codes. This work was performed under the auspices of the U

  11. Comparison endpoint study of process plasma and secondary electron beam exciter optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Stephan Thamban, P. L.; Yun, Stuart; Padron-Wells, Gabriel; Hosch, Jimmy W.; Goeckner, Matthew J. [Department of Mechanical Engineering, University of Texas at Dallas, 800W Campbell Road, Richardson, Texas 75080 (United States); Department of Electrical Engineering, University of Texas at Dallas, 800W Campbell Road, Richardson, Texas 75080 (United States); Verity Instruments, Inc., 2901 Eisenhower Street, Carrollton, Texas 75007 (United States); Department of Mathematical Sciences, University of Texas at Dallas, 800 W Campbell Road, Richardson, Texas 75080 (United States)

    2012-11-15

    Traditionally process plasmas are often studied and monitored by optical emission spectroscopy. Here, the authors compare experimental measurements from a secondary electron beam excitation and direct process plasma excitation to discuss and illustrate its distinctiveness in the study of process plasmas. They present results that show excitations of etch process effluents in a SF{sub 6} discharge and endpoint detection capabilities in dark plasma process conditions. In SF{sub 6} discharges, a band around 300 nm, not visible in process emission, is observed and it can serve as a good indicator of etch product emission during polysilicon etches. Based on prior work reported in literature the authors believe this band is due to SiF{sub 4} gas phase species.

  12. Mass spectroscopy of the ion flux produced during inductively coupled plasma nitriding process

    Science.gov (United States)

    Kolodko, D. V.; Kaziev, A. V.; Ageychenkov, D. G.; Meshcheryakova, E. A.; Pisarev, A. A.; Tumarkin, A. V.

    2017-05-01

    Ion fluxes on the surface of sample embedded in inductively coupled plasma have been studied in conditions typical for titanium alloy nitriding: total pressure 0.44 Pa, Ar/N2 = 70%/30%, and RF power 1500 W. The gas composition was independently monitored by the quadrupole analyser. The ion fluxes were sampled using a specially designed electrostatic extractor and then analysed with a magnetic sector mass-separator. The extractor design allowed us to apply a bias voltage to the plasma facing electrode thus imitating interaction of ions with the surface during the plasma processing. The ion fluxes of Ar+, {{{N}}}2{}+, and N+ on the surface were measured. The mass spectroscopy diagnostics unit is suitable for extensive ion content studies in the plasma technology facilities.

  13. Time resolved measurements of the CF{sub 2} rotational temperature in pulsed fluorocarbon rf plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Gabriel, O; Stepanov, S; Pfafferott, M; Meichsner, J [Institute of Physics, University of Greifswald, Domstrasse 10a, D-17498, Greifswald (Germany)

    2006-11-01

    Knowledge of the absolute densities of small radicals like CF, CF{sub 2} and CF{sub 3} in fluorocarbon plasmas is essential for a fundamental understanding of plasma chemical processes and plasma surface interaction. Infrared absorption spectroscopy by means of tunable diode lasers (IR-TDLAS) was established and widely used for density measurements in the last decade. The often unknown parameter in the calculation of absolute radical densities from a measured absorption of a single line is the rotational temperature. In particular, a strong dependence of the line strength on rotational temperature has a significant influence on density calculation. In this paper we report on measurements of the CF{sub 2} rotational temperature in capacitively coupled CF{sub 4}/H{sub 2} plasmas (CCP) with rf (13.56 MHz) powers up to 200 W. Rotational temperatures in continuous and pulsed modes of the discharge were found to be between 300 and 450 K. Furthermore, first measurements of the time dependence of the rotational temperature in pulsed rf plasma are presented. The rotational temperature rises in the plasma phase within 0.1 s and goes down again to the temperature of the background gas in the plasma pause within 0.5 s. It is also shown that accurate density measurements of the radicals by means of single line absorption need correct information about the rotational temperature and careful selection of a suitable absorption line.

  14. Vacuum ultraviolet spectroscopy in detached plasmas with impurity gas seeding in LHD

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, C., E-mail: csuzuki@nifs.ac.jp; Murakami, I.; Akiyama, T.; Masuzaki, S.; Funaba, H.; Yoshinuma, M.

    2015-08-15

    We have carried out vacuum ultraviolet (VUV) spectroscopy of impurity ions in detached plasmas with impurity gas seeding in the Large Helical Device (LHD). In neon (Ne) gas seeding experiments, temporal evolutions of VUV spectral lines from Ne IV–VIII were recorded by a grazing incidence spectrometer. In addition, spatial profiles of fully ionized Ne density were measured by charge exchange spectroscopy. An electron temperature range where each ion emits is inferred based on the comparisons of the measured line intensity ratios with the calculations using collisional-radiative models.

  15. Holographic Brownian motion and time scales in strongly coupled plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Atmaja, Ardian Nata [Research Center for Physics, Indonesian Institute of Sciences (LIPI), Kompleks PUSPITEK Serpong, Tangerang 15310 (Indonesia); Indonesia Center for Theoretical and Mathematical Physics (ICTMP), Bandung 40132 (Indonesia); Boer, Jan de [Institute for Theoretical Physics, University of Amsterdam, Valckenierstraat 65, 1018 XE Amsterdam (Netherlands); Shigemori, Masaki [Yukawa Institute for Theoretical Physics (YITP), Kyoto University, Kitashirakawa Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Hakubi Center, Kyoto University, Yoshida-Ushinomiyacho, Sakyo-ku, Kyoto 606-8501 (Japan)

    2014-03-15

    We study Brownian motion of a heavy quark in field theory plasma in the AdS/CFT setup and discuss the time scales characterizing the interaction between the Brownian particle and plasma constituents. Based on a simple kinetic theory, we first argue that the mean-free-path time is related to the connected 4-point function of the random force felt by the Brownian particle. Then, by holographically computing the 4-point function and regularizing the IR divergence appearing in the computation, we write down a general formula for the mean-free-path time, and apply it to the STU black hole which corresponds to plasma charged under three U(1)R-charges. The result indicates that the Brownian particle collides with many plasma constituents simultaneously.

  16. Time-resolved characterization of laser-induced plasma from fresh potatoes

    Science.gov (United States)

    Lei, Wenqi; Motto-Ros, Vincent; Boueri, Myriam; Ma, Qianli; Zhang, Dacheng; Zheng, Lijuan; Zeng, Heping; Yu, Jin

    2009-09-01

    Optical emission of laser-induced plasma on the surface of fresh vegetables provides sensitive analysis of trace elements for in situ or online detection of these materials. This emergent technique promises applications with expected outcomes in food security or nutrition quality, as well as environment pollution detection. Characterization of the plasma induced on such soft and humid materials represents the first step towards quantitative measurement using this technique. In this paper, we present the experimental setup and protocol that optimize the plasma generation on fresh vegetables, potatoes for instance. The temporal evolution of the plasma properties are investigated using time-resolved laser-induced breakdown spectroscopy (LIBS). In particular, the electron density and the temperatures of the plasma are reported as functions of its decay time. The temperatures are evaluated from the well known Boltzmann and Saha-Boltzmann plot methods. These temperatures are further compared to that of the typical molecular species, CN, for laser-induced plasma from plant materials. This comparison validates the local thermodynamic equilibrium (LTE) in the specific case of fresh vegetables ablated in the typical LIBS conditions. A study of the temporal evolution of the signal to noise ratio also provides practical indications for an optimized detection of trace elements. We demonstrate finally that, under certain conditions, the calibration-free LIBS procedure can be applied to determine the concentrations of trace elements in fresh vegetables.

  17. Time Resolved Phonon Spectroscopy, Version 1.0

    Energy Technology Data Exchange (ETDEWEB)

    2016-12-22

    TRPS code was developed for the project "Time Resolved Phonon Spectroscopy". Routines contained in this piece of software were specially created to model phonon generation and tracking within materials that interact with ionizing radiation, particularly applicable to the modeling of cryogenic radiation detectors for dark matter and neutrino research. These routines were created to link seamlessly with the open source Geant4 framework for the modeling of radiation transport in matter, with the explicit intent of open sourcing them for eventual integration into that code base.

  18. Time-resolved vibrational spectroscopy of a molecular shuttle.

    Science.gov (United States)

    Panman, Matthijs R; Bodis, Pavol; Shaw, Danny J; Bakker, Bert H; Newton, Arthur C; Kay, Euan R; Leigh, David A; Buma, Wybren Jan; Brouwer, Albert M; Woutersen, Sander

    2012-02-14

    Time-resolved vibrational spectroscopy is used to investigate the inter-component motion of an ultraviolet-triggered two-station molecular shuttle. The operation cycle of this molecular shuttle involves several intermediate species, which are observable in the amide I and amide II regions of the mid-IR spectrum. Using ab initio calculations on specific parts of the rotaxane, and by comparing the transient spectra of the normal rotaxane with that of the N-deuterated version, we can assign the observed vibrational modes of each species occurring during the shuttling cycle in an unambiguous way. The complete time- and frequency-dependent data set is analyzed using singular value decomposition (SVD). Using a kinetic model to describe the time-dependent concentrations of the transient species, we derive the absorption spectra associated with each stage in the operation cycle of the molecular shuttle, including the recombination of the charged species.

  19. Probing Local Environments by Time-Resolved Stimulated Emission Spectroscopy

    Directory of Open Access Journals (Sweden)

    Ana Rei

    2012-01-01

    Full Text Available Time-resolved stimulated emission spectroscopy was employed to probe the local environment of DASPMI (4-(4-(dimethylaminostyryl-N-methyl-pyridinium iodide in binary solvents of different viscosity and in a sol-gel matrix. DASPMI is one of the molecules of choice to probe local environments, and the dependence of its fluorescence emission decay on viscosity has been previously used for this purpose in biological samples, solid matrices as well as in solution. The results presented in this paper show that time-resolved stimulated emission of DASPMI is a suitable means to probe the viscosity of local environments. Having the advantage of a higher time resolution, stimulated emission can provide information that is complementary to that obtained from fluorescence decay measurements, making it feasible to probe systems with lower viscosity.

  20. Delay time for the onset of beam plasma discharge

    Science.gov (United States)

    Parish, J. L.; Denig, W. F.; Raitt, W. J.

    1987-01-01

    The interaction of a nonrelativistic electron beam with a neutral gas in a large chamber is considered, and the time interval before ignition of beam plasma discharge (BPD) is studied. A new theoretical expression for the time delay before BPD ignition is found as a function of the critical current necessary for BPD to be established. There are two parameters in the theoretical expression, and both are derived from two different experiments. These parameters are used to write the time evolution equation for plasma density as a function of time.

  1. Quantitative determination of citric acid in seminal plasma by using Raman spectroscopy.

    Science.gov (United States)

    Huang, Zufang; Chen, Xiwen; Li, Yongzeng; Chen, Jinhua; Lin, Juqiang; Wang, Jing; Lei, Jinping; Chen, Rong

    2013-07-01

    In this study, Raman spectroscopy was first used to study the linear relationship between Raman spectral intensities and citric acid concentrations in aqueous solution. By using the specific Raman band of 942 cm(-1), concentrations of citric acid ranging from 2 to 20 mg/mL were observed linearly (R(2) = 0.993), and the limit of detection was 1.0 mg/mL. Then, citric acid detection in clinical seminal plasma ultrafiltrate samples was performed, and the intensity of the Raman-specific peak demonstrates a good linear correlation (R(2) = 0.946) with citric acid concentrations determined by the enzymatic method. Our results showed that Raman spectroscopy has the potential of being applied to detect concentrations of citric acid in seminal plasma in clinic.

  2. Time-dependent Cooling in Photoionized Plasma

    Science.gov (United States)

    Gnat, Orly

    2017-02-01

    I explore the thermal evolution and ionization states in gas cooling from an initially hot state in the presence of external photoionizing radiation. I compute the equilibrium and nonequilibrium cooling efficiencies, heating rates, and ion fractions for low-density gas cooling while exposed to the ionizing metagalactic background radiation at various redshifts (z = 0 ‑ 3), for a range of temperatures (108–104 K), densities (10‑7–103 cm‑3), and metallicities (10‑3–2 times solar). The results indicate the existence of a threshold ionization parameter, above which the cooling efficiencies are very close to those in photoionization equilibrium (so that departures from equilibrium may be neglected), and below which the cooling efficiencies resemble those in collisional time-dependent gas cooling with no external radiation (and are thus independent of density).

  3. Self-absorption influence on the optical spectroscopy of zinc oxide laser produced plasma

    Energy Technology Data Exchange (ETDEWEB)

    De Posada, E; Arronte, M A; Ponce, L; Rodriguez, E; Flores, T [Centro de Investigacion en Ciencia Aplicada y TecnologIa Avanzada-Unidad Altamira, Tamaulipas (Mexico); Lunney, J G, E-mail: edeposada@ipn.mx [School of Physics, Trinity College Dublin (Ireland)

    2011-01-01

    Optical spectroscopy is used to study the laser ablation process of ZnO targets. It is demonstrated that even if Partial Local Thermal Equilibrium is present, self absorption process leads to a decrease of recorded lines emission intensities and have to be taken into account to obtain correct values of such parameters. It is presented a method that combines results of both Langmuir probe technique and Anisimov model to obtain correct values of plasma parameters.

  4. Time resolved spectroscopy of GRB030501 using INTEGRAL

    CERN Document Server

    Beckmann, V; Courvoisier, Thierry J L; Goetz, D; Hudec, R; Hroch, F; Lund, N; Mereghetti, S; Shaw, S E; Wigger, C

    2003-01-01

    The Gamma-ray instruments on-board INTEGRAL offer an unique opportunity to perform time resolved analysis on GRBs. The imager IBIS allows accurate positiioning of GRBs and broad band spectral analysis, while SPI provides high resolution spectroscopy. GRB 030501 was discovered by the INTEGRAL Burst Alert System in the ISGRI field of view. Although the burst was fairly weak (fluence F = 3.5 * 10^-6 erg cm^-2 in the 20-200 keV energy band) it was possible to perform time resolved spectroscopy with a resolution of a few seconds. The GRB shows a spectrum in the 20 - 400 keV range which is consistent with a spectral photon index of -1.7. No emission line or spectral break was detectable in the spectrum. Although the flux seems to be correlated with the hardness of the GRB spectrum, there is no clear soft to hard evolution seen over the duration of the burst. The INTEGRAL data have been compared with results from the Ulysses and RHESSI experiments.

  5. Fourier transform infrared absorption spectroscopy characterization of gaseous atmospheric pressure plasmas with 2 mm spatial resolution.

    Science.gov (United States)

    Laroche, G; Vallade, J; Bazinette, R; van Nijnatten, P; Hernandez, E; Hernandez, G; Massines, F

    2012-10-01

    This paper describes an optical setup built to record Fourier transform infrared (FTIR) absorption spectra in an atmospheric pressure plasma with a spatial resolution of 2 mm. The overall system consisted of three basic parts: (1) optical components located within the FTIR sample compartment, making it possible to define the size of the infrared beam (2 mm × 2 mm over a path length of 50 mm) imaged at the site of the plasma by (2) an optical interface positioned between the spectrometer and the plasma reactor. Once through the plasma region, (3) a retro-reflector module, located behind the plasma reactor, redirected the infrared beam coincident to the incident path up to a 45° beamsplitter to reflect the beam toward a narrow-band mercury-cadmium-telluride detector. The antireflective plasma-coating experiments performed with ammonia and silane demonstrated that it was possible to quantify 42 and 2 ppm of these species in argon, respectively. In the case of ammonia, this was approximately three times less than this gas concentration typically used in plasma coating experiments while the silane limit of quantification was 35 times lower. Moreover, 70% of the incoming infrared radiation was focused within a 2 mm width at the site of the plasma, in reasonable agreement with the expected spatial resolution. The possibility of reaching this spatial resolution thus enabled us to measure the gaseous precursor consumption as a function of their residence time in the plasma.

  6. Fourier transform infrared absorption spectroscopy characterization of gaseous atmospheric pressure plasmas with 2 mm spatial resolution

    Energy Technology Data Exchange (ETDEWEB)

    Laroche, G. [Laboratoire d' Ingenierie de Surface, Centre de Recherche sur les Materiaux Avances, Departement de genie des mines, de la metallurgie et des materiaux, Universite Laval, 1065, avenue de la Medecine, Quebec G1V 0A6 (Canada); Centre de recherche du CHUQ, Hopital St Francois d' Assise, 10, rue de l' Espinay, local E0-165, Quebec G1L 3L5 (Canada); Vallade, J. [Laboratoire Procedes, Materiaux et Energie Solaire, PROMES, CNRS, Technosud, Rambla de la Thermodynamique, F-66100 Perpignan (France); Agence de l' environnement et de la Ma Latin-Small-Letter-Dotless-I -carettrise de l' Energie, 20, avenue du Gresille, BP 90406, F-49004 Angers Cedex 01 (France); Bazinette, R.; Hernandez, E.; Hernandez, G.; Massines, F. [Laboratoire Procedes, Materiaux et Energie Solaire, PROMES, CNRS, Technosud, Rambla de la Thermodynamique, F-66100 Perpignan (France); Nijnatten, P. van [OMT Solutions bv, High Tech Campus 9, 5656AE Eindhoven (Netherlands)

    2012-10-15

    This paper describes an optical setup built to record Fourier transform infrared (FTIR) absorption spectra in an atmospheric pressure plasma with a spatial resolution of 2 mm. The overall system consisted of three basic parts: (1) optical components located within the FTIR sample compartment, making it possible to define the size of the infrared beam (2 mm Multiplication-Sign 2 mm over a path length of 50 mm) imaged at the site of the plasma by (2) an optical interface positioned between the spectrometer and the plasma reactor. Once through the plasma region, (3) a retro-reflector module, located behind the plasma reactor, redirected the infrared beam coincident to the incident path up to a 45 Degree-Sign beamsplitter to reflect the beam toward a narrow-band mercury-cadmium-telluride detector. The antireflective plasma-coating experiments performed with ammonia and silane demonstrated that it was possible to quantify 42 and 2 ppm of these species in argon, respectively. In the case of ammonia, this was approximately three times less than this gas concentration typically used in plasma coating experiments while the silane limit of quantification was 35 times lower. Moreover, 70% of the incoming infrared radiation was focused within a 2 mm width at the site of the plasma, in reasonable agreement with the expected spatial resolution. The possibility of reaching this spatial resolution thus enabled us to measure the gaseous precursor consumption as a function of their residence time in the plasma.

  7. Comparative measurements of mineral elements in milk powders with laser-induced breakdown spectroscopy and inductively coupled plasma atomic emission spectroscopy.

    Science.gov (United States)

    Lei, W Q; El Haddad, J; Motto-Ros, V; Gilon-Delepine, N; Stankova, A; Ma, Q L; Bai, X S; Zheng, L J; Zeng, H P; Yu, J

    2011-07-01

    Mineral elements contained in commercially available milk powders, including seven infant formulae and one adult milk, were analyzed with inductively coupled plasma atomic emission spectrometry (ICP-AES) and laser-induced breakdown spectroscopy (LIBS). The purpose of this work was, through a direct comparison of the analytical results, to provide an assessment of the performance of LIBS, and especially of the procedure of calibration-free LIBS (CF-LIBS), to deal with organic compounds such as milk powders. In our experiments, the matrix effect was clearly observed affecting the analytical results each time laser ablation was employed for sampling. Such effect was in addition directly observed by determining the physical parameters of the plasmas induced on the different samples. The CF-LIBS procedure was implemented to deduce the concentrations of Mg and K with Ca as the internal reference element. Quantitative analytical results with CF-LIBS were validated with ICP-AES measurements and nominal concentrations specified for commercial milks. The obtained good results with the CF-LIBS procedure demonstrate its capacity to take into account the difference in physical parameters of the plasma in the calculation of the concentrations of mineral elements, which allows a significant reduction of the matrix effect related to laser ablation. We finally discuss the way to optimize the implementation of the CF-LIBS procedure for the analysis of mineral elements in organic materials.

  8. Terahertz Time Domain Gas-phase Spectroscopy of Carbon Monoxide

    Science.gov (United States)

    Kilcullen, Patrick; Hartley, I. D.; Jensen, E. T.; Reid, M.

    2015-04-01

    Free induction decay signals emitted from Carbon Monoxide (CO) excited by sub-picosecond pulses of Terahertz (THz) radiation are directly measured in the time domain and compared to model calculations using a linear dispersion model to good agreement. Best fitting techniques of the data using the model allow the self-pressure broadening of CO to be measured across a range of absolute pressures, and the rotational constant to be determined. We find B V = 5.770 ± 0.003 × 1010 Hz in agreement with previous measurements. A partial pressure limit of detection for CO of 7900 ppm is estimated at atmosphere through extrapolating the calculated commensurate echo peaks down to low pressures with respect to the RMS noise floor of our THz time domain spectroscopy (THz-TDS) apparatus, which implies a limit of detection in the range of 40 ppm for commercial THz-TDS systems.

  9. Time-resolved terahertz spectroscopy of semiconductor nanostructures

    DEFF Research Database (Denmark)

    Porte, Henrik

    of the photoconductivity is observed, due the release of carriers from the quantum dots into the conducting barrier states. Secondly, the carrier dynamics in InGaN/GaN quantum wells subject to a built-in piezoelectric eld is described. An initial fast decay of the photoconductivity as the piezoelectric eld is screened......This thesis describes time-resolved terahertz spectroscopy measurements on various semiconductor nanostructures. The aim is to study the carrier dynamics in these nanostructures on a picosecond timescale. In a typical experiment carriers are excited with a visible or near-infrared pulse...... and by measuring the transmission of a terahertz probe pulse, the photoconductivity of the excited sample can be obtained. By changing the relative arrival time at the sample between the pump and the probe pulse, the photoconductivity dynamics can be studied on a picosecond timescale. The rst studied semiconductor...

  10. Resonant and Time-Resolved Spin Noise Spectroscopy

    Science.gov (United States)

    Song, Xinlin; Pursley, Brennan; Sih, Vanessa

    Spin noise spectroscopy is a technique which can probe the system while it remains in equilibrium. It was first demonstrated in atomic gases and then in solid state systems. Most existing spin noise measurement setups digitize the spin fluctuation signal and then analyze the power spectrum. Recently, pulsed lasers have been used to expand the bandwidth of accessible dynamics and allow direct time-domain correlation measurements. Here we develop and test a model for ultrafast pulsed laser spin noise measurements as well as a scheme to measure spin lifetimes longer than the laser repetition period. For the resonant spin noise technique, analog electronics are used to capture correlations from the extended pulse train, and the signal at a fixed time delay is measured as a function of applied magnetic field.

  11. Timing and Spectroscopy Requirements for a Plastic Scintillating Fiber Bundle Time-of-Flight Neutron Spectrometer

    Science.gov (United States)

    2013-12-01

    flexibility, efficiency, timing, and position resolution in developing novel Compton camera detectors capable of detecting special nuclear material. 1.3...oscilloscope needs to be fast enough to resolve coincident pulse events on the picoseconds to nanosecond time scale. The final objective is to experimentally...Mirsaleh-Kohan, W. D. Nasrin, and R. N. Compton , “Electron ionization time-of-flight mass spectroscopy: Historical review and current applications

  12. X-ray and EUV spectroscopy of various astrophysical and laboratory plasmas -- Collisional, photoionization and charge-exchange plasmas

    CERN Document Server

    Liang, G Y; Wang, F L; Wu, Y; Zhong, J Y; Zhao, G

    2014-01-01

    Several laboratory facilities were used to benchmark theoretical spectral models those extensively used by astronomical communities. However there are still many differences between astrophysical environments and laboratory miniatures that can be archived. Here we setup a spectral analysis system for astrophysical and laboratory (SASAL) plasmas to make a bridge between them, and investigate the effects from non-thermal electrons, contribution from metastable level-population on level populations and charge stage distribution for coronal-like, photoionized, and geocoronal plasmas. Test applications to laboratory measurement (i.e. EBIT plasma) and astrophysical observation (i.e. Comet, Cygnus X-3) are presented. Time evolution of charge stage and level population are also explored for collisional and photoionized plasmas.

  13. A project based on multi-configuration Dirac-Fock calculations for plasma spectroscopy

    Science.gov (United States)

    Comet, M.; Pain, J.-C.; Gilleron, F.; Piron, R.

    2017-09-01

    We present a project dedicated to hot plasma spectroscopy based on a Multi-Configuration Dirac-Fock (MCDF) code, initially developed by J. Bruneau. The code is briefly described and the use of the transition state method for plasma spectroscopy is detailed. Then an opacity code for local-thermodynamic-equilibrium plasmas using MCDF data, named OPAMCDF, is presented. Transition arrays for which the number of lines is too large to be handled in a Detailed Line Accounting (DLA) calculation can be modeled within the Partially Resolved Transition Array method or using the Unresolved Transition Arrays formalism in jj-coupling. An improvement of the original Partially Resolved Transition Array method is presented which gives a better agreement with DLA computations. Comparisons with some absorption and emission experimental spectra are shown. Finally, the capability of the MCDF code to compute atomic data required for collisional-radiative modeling of plasma at non local thermodynamic equilibrium is illustrated. In addition to photoexcitation, this code can be used to calculate photoionization, electron impact excitation and ionization cross-sections as well as autoionization rates in the Distorted-Wave or Close Coupling approximations. Comparisons with cross-sections and rates available in the literature are discussed.

  14. Time-resolved single-shot terahertz time-domain spectroscopy for ultrafast irreversible processes

    Science.gov (United States)

    Zhai, Zhao-Hui; Zhong, Sen-Cheng; Li, Jun; Zhu, Li-Guo; Meng, Kun; Li, Jiang; Liu, Qiao; Peng, Qi-Xian; Li, Ze-Ren; Zhao, Jian-Heng

    2016-09-01

    Pulsed terahertz spectroscopy is suitable for spectroscopic diagnostics of ultrafast events. However, the study of irreversible or single shot ultrafast events requires ability to record transient properties at multiple time delays, i.e., time resolved at single shot level, which is not available currently. Here by angular multiplexing use of femtosecond laser pulses, we developed and demonstrated a time resolved, transient terahertz time domain spectroscopy technique, where burst mode THz pulses were generated and then detected in a single shot measurement manner. The burst mode THz pulses contain 2 sub-THz pulses, and the time gap between them is adjustable up to 1 ns with picosecond accuracy, thus it can be used to probe the single shot event at two different time delays. The system can detect the sub-THz pulses at 0.1 THz-2.5 THz range with signal to noise ratio (SNR) of ˜400 and spectrum resolution of 0.05 THz. System design was described here, and optimizations of single shot measurement of THz pulses were discussed in detail. Methods to improve SNR were also discussed in detail. A system application was demonstrated where pulsed THz signals at different time delays of the ultrafast process were successfully acquired within single shot measurement. This time resolved transient terahertz time domain spectroscopy technique provides a new diagnostic tool for irreversible or single shot ultrafast events where dynamic information can be extracted at terahertz range within one-shot experiment.

  15. Charge-exchange recombination spectroscopy of the plasma ion temperature at the T-10 tokamak

    Science.gov (United States)

    Krupin, V. A.; Tugarinov, S. N.; Barsukov, A. G.; Dnestrovskij, A. Yu.; Klyuchnikov, L. A.; Korobov, K. V.; Krasnyanskii, S. A.; Naumenko, N. N.; Nemets, A. R.; Sushkov, A. V.; Tilinin, G. N.

    2013-08-01

    Charge-exchange recombination spectroscopy (CXRS) based on a diagnostic neutral beam has been developed at the T-10 tokamak. The diagnostics allows one to measure the ion temperature profile in the cross section of the plasma column. In T-10 experiments, the measurement technique was adjusted and the elements of the CXRS diagnostics for ITER were tested. The used spectroscopic equipment makes it possible to reliably determine the ion temperature from the Doppler broadening of impurity lines (helium, carbon), as well as of the spectral lines of the working gas. The profiles of the plasma ion temperature in deuterium and helium discharges were measured at different plasma currents and densities, including with the use of active Doppler measurements of lines of different elements. The validity and reliability of ion temperature measurements performed by means of the developed CXRS diagnostics are analyzed.

  16. Bremsstrahlung and Line Spectroscopy of Warm Dense Aluminum Plasma Generated by EUV Free Electron Laser

    Energy Technology Data Exchange (ETDEWEB)

    Zastrau, U; Fortmann, C; Faustlin, R; Bornath, T; Cao, L F; Doppner, T; Dusterer, S; Forster, E; Glenzer, S H; Gregori, G; Holl, A; Laarmann, T; Lee, H; Meiwes-Broer, K; Przystawik, A; Radcliffe, P; Redmer, R; Reinholz, H; Ropke, G; Tiggesbaumker, J; Thiele, R; Truong, N X; Uschmann, I; Toleikis, S; Tschentscher, T; Wierling, A

    2008-03-07

    We report on the novel creation of a solid density aluminum plasma using free electron laser radiation at 13.5 nm wavelength. Ultrashort pulses of 30 fs duration and 47 {micro}J pulse energy were focused on a spot of 25 {micro}m diameter, yielding an intensity of 3 x 10{sup 14} W/cm{sup 2} on the bulk Al-target. The radiation emitted from the plasma was measured using a high resolution, high throughput EUV spectrometer. The analysis of both bremsstrahlung and line spectra results in an estimated electron temperature of (30 {+-} 10) eV, which is in very good agreement with radiation hydrodynamics simulations of the laser-target-interaction. This demonstrates the feasibility of exciting plasmas at warm dense matter conditions using EUV free electron lasers and their accurate characterization by EUV spectroscopy.

  17. Spectroscopy and atomic physics of highly ionized Cr, Fe, and Ni for tokamak plasmas

    Science.gov (United States)

    Feldman, U.; Doschek, G. A.; Cheng, C.-C.; Bhatia, A. K.

    1980-01-01

    The paper considers the spectroscopy and atomic physics for some highly ionized Cr, Fe, and Ni ions produced in tokamak plasmas. Forbidden and intersystem wavelengths for Cr and Ni ions are extrapolated and interpolated using the known wavelengths for Fe lines identified in solar-flare plasmas. Tables of transition probabilities for the B I, C I, N I, O I, and F I isoelectronic sequences are presented, and collision strengths and transition probabilities for Cr, Fe, and Ni ions of the Be I sequence are given. Similarities of tokamak and solar spectra are discussed, and it is shown how the atomic data presented may be used to determine ion abundances and electron densities in low-density plasmas.

  18. Diode-Laser Induced Fluorescence Spectroscopy of an Optically Thick Plasma in Combination with Laser Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    S. Nomura

    2013-01-01

    Full Text Available Distortion of laser-induced fluorescence profiles attributable to optical absorption and saturation broadening was corrected in combination with laser absorption spectroscopy in argon plasma flow. At high probe-laser intensity, saturated absorption profiles were measured to correct probe-laser absorption. At low laser intensity, nonsaturated absorption profiles were measured to correct fluorescence reabsorption. Saturation broadening at the measurement point was corrected using a ratio of saturated to non-saturated broadening. Observed LIF broadening and corresponding translational temperature without correction were, respectively, 2.20±0.05 GHz and 2510±100 K and corrected broadening and temperature were, respectively, 1.96±0.07 GHz and 1990±150 K. Although this correction is applicable only at the center of symmetry, the deduced temperature agreed well with that obtained by LAS with Abel inversion.

  19. Real-Time Plasma Process Condition Sensing and Abnormal Process Detection

    Directory of Open Access Journals (Sweden)

    Ryan Yang

    2010-06-01

    Full Text Available The plasma process is often used in the fabrication of semiconductor wafers. However, due to the lack of real-time etching control, this may result in some unacceptable process performances and thus leads to significant waste and lower wafer yield. In order to maximize the product wafer yield, a timely and accurately process fault or abnormal detection in a plasma reactor is needed. Optical emission spectroscopy (OES is one of the most frequently used metrologies in in-situ process monitoring. Even though OES has the advantage of non-invasiveness, it is required to provide a huge amount of information. As a result, the data analysis of OES becomes a big challenge. To accomplish real-time detection, this work employed the sigma matching method technique, which is the time series of OES full spectrum intensity. First, the response model of a healthy plasma spectrum was developed. Then, we defined a matching rate as an indictor for comparing the difference between the tested wafers response and the health sigma model. The experimental results showed that this proposal method can detect process faults in real-time, even in plasma etching tools.

  20. Optical and structural properties of plasma-treated Cordyceps bassiana spores as studied by circular dichroism, absorption, and fluorescence spectroscopy

    Science.gov (United States)

    Lee, Geon Joon; Sim, Geon Bo; Choi, Eun Ha; Kwon, Young-Wan; Kim, Jun Young; Jang, Siun; Kim, Seong Hwan

    2015-01-01

    To understand the killing mechanism of fungal spores by plasma treatment, the optical, structural, and biological properties of the insect pathogenic fungus Cordyceps bassiana spores were studied. A nonthermal atmospheric-pressure plasma jet (APPJ) was used to treat the spores in aqueous solution. Optical emission spectra of the APPJ acquired in air indicated emission peaks corresponding to hydroxyl radicals and atomic oxygen. When the APPJ entered the aqueous solution, additional reactive species were derived from the interaction of plasma radicals with the aqueous solution. Fluorescence and absorption spectroscopy confirmed the generation of hydroxyl radicals and hydrogen peroxide in the plasma-activated water (PAW). Spore counting showed that plasma treatment significantly reduced spore viability. Absorption spectroscopy, circular dichroism (CD) spectroscopy, and agarose gel electrophoresis of the DNA extracted from plasma-treated spores showed a reduction in spore DNA content. The magnitude of the dip in the CD spectrum was lower in the plasma-treated spores than in the control, indicating that plasma treatment causes structural modifications and/or damage to cellular components. Tryptophan fluorescence intensity was lower in the plasma-treated spores than in the control, suggesting that plasma treatment modified cell wall proteins. Changes in spore viability and DNA content were attributed to structural modification of the cell wall by reactive species coming from the APPJ and the PAW. Our results provided evidence that the plasma radicals and the derived reactive species play critical roles in fungal spore inactivation.

  1. Optical and structural properties of plasma-treated Cordyceps bassiana spores as studied by circular dichroism, absorption, and fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Geon Joon, E-mail: gjlee@kw.ac.kr; Sim, Geon Bo; Choi, Eun Ha [Plasma Bioscience Research Center/Department of Electrical and Biological Physics, Kwangwoon University, Seoul 139-701 (Korea, Republic of); Kwon, Young-Wan [KU-KIST Graduate School of Converging Science and Technology, Korea University, Seoul 136-701 (Korea, Republic of); Kim, Jun Young; Jang, Siun; Kim, Seong Hwan, E-mail: piceae@naver.com [Department of Microbiology and Institute of Basic Sciences, Dankook University, Cheonan 330-714 (Korea, Republic of)

    2015-01-14

    To understand the killing mechanism of fungal spores by plasma treatment, the optical, structural, and biological properties of the insect pathogenic fungus Cordyceps bassiana spores were studied. A nonthermal atmospheric-pressure plasma jet (APPJ) was used to treat the spores in aqueous solution. Optical emission spectra of the APPJ acquired in air indicated emission peaks corresponding to hydroxyl radicals and atomic oxygen. When the APPJ entered the aqueous solution, additional reactive species were derived from the interaction of plasma radicals with the aqueous solution. Fluorescence and absorption spectroscopy confirmed the generation of hydroxyl radicals and hydrogen peroxide in the plasma-activated water (PAW). Spore counting showed that plasma treatment significantly reduced spore viability. Absorption spectroscopy, circular dichroism (CD) spectroscopy, and agarose gel electrophoresis of the DNA extracted from plasma-treated spores showed a reduction in spore DNA content. The magnitude of the dip in the CD spectrum was lower in the plasma-treated spores than in the control, indicating that plasma treatment causes structural modifications and/or damage to cellular components. Tryptophan fluorescence intensity was lower in the plasma-treated spores than in the control, suggesting that plasma treatment modified cell wall proteins. Changes in spore viability and DNA content were attributed to structural modification of the cell wall by reactive species coming from the APPJ and the PAW. Our results provided evidence that the plasma radicals and the derived reactive species play critical roles in fungal spore inactivation.

  2. Compact, accurate description of diagnostic neutral beam propagation and attenuation in a high temperature plasma for charge exchange recombination spectroscopy analysis.

    Science.gov (United States)

    Bespamyatnov, Igor O; Rowan, William L; Granetz, Robert S

    2008-10-01

    Charge exchange recombination spectroscopy on Alcator C-Mod relies on the use of the diagnostic neutral beam injector as a source of neutral particles which penetrate deep into the plasma. It employs the emission resulting from the interaction of the beam atoms with fully ionized impurity ions. To interpret the emission from a given point in the plasma as the density of emitting impurity ions, the density of beam atoms must be known. Here, an analysis of beam propagation is described which yields the beam density profile throughout the beam trajectory from the neutral beam injector to the core of the plasma. The analysis includes the effects of beam formation, attenuation in the neutral gas surrounding the plasma, and attenuation in the plasma. In the course of this work, a numerical simulation and an analytical approximation for beam divergence are developed. The description is made sufficiently compact to yield accurate results in a time consistent with between-shot analysis.

  3. Shock Formation in Electron-Ion Plasmas: Mechanism and Timing

    Science.gov (United States)

    Bret, Antoine; Stockem Novo, Anne; Ricardo, Fonseca; Luis, Silva

    2016-10-01

    We analyze the formation of a collisionless shock in electron-ion plasmas in theory and simulations. In initially un-magnetized relativistic plasmas, such shocks are triggered by the Weibel instability. While in pair plasmas the shock starts forming right after the instability saturates, it is not so in electron-ion plasmas because the Weibel filaments at saturation are too small. An additional merging phase is therefore necessary for them to efficiently stop the flow. We derive a theoretical model for the shock formation time, taking into account filament merging in the nonlinear phase of the Weibel instability. This process is much slower than in electron-positron pair shocks, and so the shock formation is longer by a factor proportional to √{mi /me } ln(mi /me).

  4. [Discussion on diagenesis of Xilingang pluton-constrained by X-ray Fluorescence spectroscopy, plasma mass spectrometry and Raman spectroscopy].

    Science.gov (United States)

    Tang, Yu-Kun; Chen, Guo-Neng; Zhang, Ke; Huang, Hai-Hua

    2013-05-01

    The results on Xilingang pluton, mainly consisting of red beds, granites containing numerous debris of red beds and granites, obtained by X-ray fluorescence spectroscopy, plasma mass spectrometry and Raman spectroscopy show: (1) Xilingang pluton from red beds, granites containing numerous debris of red beds to granites has obvious characteristics of decreasing silicon and alkali content, and rising ignition loss, dark mineral content and oxidation index; (2) Chondrite-normalized REE distribution curves and primitive mantle-normalized spider diagram for trace elements of redbed, granites containing numerous debris of red beds and granites have a good consistency, the distribution characteristics of elements are similar to Nanling transformation-type granite; (3) The value of Raman spectrogram characteristic peak of quartz crystal in Xilingang granite decreased from the center of quartz crystal, and FWHM is steady. According to the above, the authors believe that Xilingang granite formed was related to in-situ melting of red beds and underlying strata and magma consolidation. Volatile components were discharged continuously, and oxidation index decreased gradually in the melting process. In the process of diagenesis, the top of pluton tend to be an ongoing silicon and alkali increase, while TFeO and MgO continue to migrate to bottom, and crystallization environment is a relatively closed and steady system.

  5. V.U.V. plasma spectroscopy diagnostic of electron cyclotron resonance multicharged ion sources; Diagnostic de plasmas crees dans des sources d'ions multicharges a resonance cyclotronique electronique par spectroscopie V.U.V

    Energy Technology Data Exchange (ETDEWEB)

    Berreby, R

    1997-12-15

    To characterize the multicharged ions within the plasma of an E.C.R. ion source, the V.U.V. spectroscopy is used as a non invasive diagnostic of excited matter. In E.C.R.I. S. (electron cyclotron resonance ion source) electrons are heated and magnetically confined within the mirror machine to overcome the successive ionization potentials of the desired elements. As the electrons bounce inside the magnetic configuration in their gyration movement, they interact with the microwaves injected into the source at the resonance frequency. To enhance the performances in high charge states and extracted currents delivered by E.C.R.I.S., the fundamental parameters of the plasma created in these machines must be known. The goal of spectroscopic diagnostics in the V.U.V. range installed on the sources is to determine electron density and temperature on one hand, and the ionic densities and confinement time on the other hand. We used microchannel plates as detector on a 3 meter grazing incidence spectrometer equipped with a 600 lines/mm holographic grating. The calibration of the whole grating with detector was performed by two different methods. These are the branching ratio and charge exchange methods. Identification of lines emitted by a plasma, which gather the whole charge states of ions is necessary to make an exhaustive study of the plasma state. And finally, the determination of plasma parameters like electron density and temperature and ion densities and confinement times that uses theoretical models were the aim of this work. (author)

  6. Level crossings, excess times and transient plasma-wall interactions in fusion plasmas

    CERN Document Server

    Theodorsen, Audun

    2016-01-01

    Based on a stochastic model for intermittent fluctuations in the boundary region of magnetically confined plasmas, an expression for the level crossing rate is derived from the joint distribution of the process and its derivative. From this the average time spent by the process above a certain threshold level is obtained. This provides novel predictions of plasma-wall interactions due to transient transport events associated with radial motion of blob-like structures in the scrape-off layer.

  7. Tin re-deposition and erosion measured by cavity-ring-down-spectroscopy under a high flux plasma beam

    Science.gov (United States)

    Kvon, V.; Al, R.; Bystrov, K.; Peeters, F. J. J.; van de Sanden, M. C. M.; Morgan, T. W.

    2017-08-01

    Cavity-ring-down spectroscopy (CRDS) was implemented to measure the re-deposition of liquid tin under a high flux plasma beam in the linear plasma device Pilot-PSI. A capillary porous system (CPS) consisting of a molybdenum cup and tungsten meshes (pores diameters of 0.2 mm and 0.44 mm) was filled with tin and exposed to argon plasma. The absorption of a UV laser-beam at 286.331 nm was used to determine a number of sputtered neutral tin atoms. The incoming flux of argon ions of ~50 eV was 1.6-2.7  ×  1023 m-2 s-1, and the sample temperature measured by pyrometry varied from 850 °C to 1200 °C during exposures. The use of CRDS for measuring absolute number of particles under such plasma exposure was demonstrated for the first time. The number of sputtered tin particles in the cavity region assuming no losses would be expected to be 5.5  ×  1011-1.2  ×  1012 while CRDS measurements showed only 5.7-9.9  ×  108. About 98-99.8% of sputtered particles were therefore found to not reach the CRDS observation volume. Spectroscopic ratios of Sn I to Sn II ions, as well as equilibrium considerations, indicate that fast ionization as well as plasma entrainment of neutrals is responsible for the discrepancy. This would lead to high re-deposition rates, implying a lowered contamination rate of core plasma and lower required replenishment rates at high-flux conditions than would otherwise be expected.

  8. Finite-difference time-domain analysis of time-resolved terahertz spectroscopy experiments

    DEFF Research Database (Denmark)

    Larsen, Casper; Cooke, David G.; Jepsen, Peter Uhd

    2011-01-01

    In this paper we report on the numerical analysis of a time-resolved terahertz (THz) spectroscopy experiment using a modified finite-difference time-domain method. Using this method, we show that ultrafast carrier dynamics can be extracted with a time resolution smaller than the duration of the THz...... probe pulse and can be determined solely by the pump pulse duration. Our method is found to reproduce complicated two-dimensional transient conductivity maps exceedingly well, demonstrating the power of the time-domain numerical method for extracting ultrafast and dynamic transport parameters from time...

  9. Terahertz Time-Domain Spectroscopy and Its Applications

    Institute of Scientific and Technical Information of China (English)

    Guo-Zhong Zhao

    2014-01-01

    Theterahertz time-domain spectroscopy (THz-TDS) system and the related technology and the applications in Capital Normal University are presented. The most often used THz-TDS system as a spectroscopic measurement setup in our lab is introduced in detail, including the THz radiation source, the THz detection method and its measurement, and the control system. THz spectra of various materials is summarized and discussed. These materials include but not limited to two kinds of typical matter-the illegal drugs and explosives. The biological macro-molecules, cosmetics and fine chemical materials, edible pigments and food additives, homocysteic acid and related compounds, heavy ions in soil, Chinese medicines, tobacco and crops, oil and chemical products, carbon nanotubes, superconductors, and various semiconductors and their heterojunctions, are presented. THz emissions from the InAs and InN semiconductors surface are compared. THz spectral investigation of metallic mesh structures is summarized. Finally, an outlook of THz spectroscopic applications is given.

  10. Uncertainty in Terahertz Time-Domain Spectroscopy Measurement of Liquids

    Science.gov (United States)

    Yang, Fei; Liu, Liping; Song, Maojiang; Han, Feng; Shen, Li; Hu, Pengfei; Zhang, Fang

    2017-02-01

    Terahertz time-domain spectroscopy (THz-TDS) is a significant technique for characterizing materials as it allows fast and broadband measurement of optical constants in the THz regime. The measurement precision of the constants is highly influenced by the complicated measurement procedure and data processing. Taking THz transmission measurement of liquids into account, the sources of error existing in THz-TDS process are identified. The contributions of each source to the uncertainty of optical constants in THz-TDS process are formulated, with particular emphasis on the effect of multilayer reflections and plane wave assumption. As a consequence, an analytical model is proposed for uncertainty evaluation in a THz-TDS measurement of liquids. An actual experiment with a Di 2-Ethyl Hexyl Phthalate (DEHP) sample is carried out to show that the proposed model could be a basis to evaluate the measurement precision of optical constants of liquids.

  11. Terahertz time-domain spectroscopy of edible oils

    Science.gov (United States)

    Dinovitser, Alex; Valchev, Dimitar G.; Abbott, Derek

    2017-06-01

    Chemical degradation of edible oils has been studied using conventional spectroscopic methods spanning the spectrum from ultraviolet to mid-IR. However, the possibility of morphological changes of oil molecules that can be detected at terahertz frequencies is beginning to receive some attention. Furthermore, the rapidly decreasing cost of this technology and its capability for convenient, in situ measurement of material properties, raises the possibility of monitoring oil during cooking and processing at production facilities, and more generally within the food industry. In this paper, we test the hypothesis that oil undergoes chemical and physical changes when heated above the smoke point, which can be detected in the 0.05-2 THz spectral range, measured using the conventional terahertz time-domain spectroscopy technique. The measurements demonstrate a null result in that there is no significant change in the spectra of terahertz optical parameters after heating above the smoke point for 5 min.

  12. THz time-domain spectroscopy of amino acids

    Institute of Scientific and Technical Information of China (English)

    WANG Weining; YUE Weiwei; YAN Haitao; ZHANG Cunlin; ZHAO Guozhong

    2005-01-01

    The optical characteristics of four kinds of amino acids (tyrosine, arginine, histidine and glutamine) filled with nitrogen at room temperature were studied by THz time-domain spectroscopy (THz-TDS). Well-resolved absorption and refractive spectrums between 0.1 and 2.8 THz were obtained based on the physical model for extracting the optical parameters of materials in THz range. The results not only fill up the spectra gap of amino acids in far-infrared range, supply data for amino acid molecular identification and conformation analysis, but also demonstrate significantly potential to promote the research and application of biological materials in bio-chemical and medical fields by THz-TDS.

  13. Quantitative measurement of mixtures by terahertz time-domain spectroscopy

    Indian Academy of Sciences (India)

    Guifeng Liu; Zengyan Zhang; Shihua Ma; Hongwei Zhao; Xiaojing Ma; Wenfeng Wang

    2009-07-01

    Terahertz time-domain spectroscopy (THz-TDS) was applied for quantitatively analysing a series of binary mixtures and a ternary mixture. Binary mixtures having different weight ratios of two components, -aminophenol and m-nitroaniline, were investigated by THz-TDS in the range of 0.3 to 1.5 THz, and it was found that the absorption coefficients of the components in each mixture were linearly proportional to their concentrations in the mixture. The results from analysis were in agreement with actual values with a relative error of less than 7%. The quantitative method will help in the detection of illegal drugs, poisons and dangerous materials that are wrapped or mixed with other materials.

  14. Waiting time dynamics in two-dimensional infrared spectroscopy.

    Science.gov (United States)

    Jansen, Thomas L C; Knoester, Jasper

    2009-09-15

    We review recent work on the waiting time dynamics of coherent two-dimensional infrared (2DIR) spectroscopy. This dynamics can reveal chemical and physical processes that take place on the femto- and picosecond time scale, which is faster than the time scale that may be probed by, for example, nuclear magnetic resonance spectroscopy. A large number of chemically relevant processes take place on this time scale. Such processes range from forming and breaking hydrogen bonds and proton transfer to solvent exchange and vibrational population transfer. In typical 2DIR spectra, multiple processes contribute to the waiting time dynamics and the spectra are often congested. This makes the spectra challenging to interpret, and the aid of theoretical models and simulations is often needed. To be useful, such models need to account for all dynamical processes in the sample simultaneously. The numerical integration of the Schrodinger equation (NISE) method has proven to allow for a very general treatment of the dynamical processes. It accounts for both the motional narrowing resulting from solvent-induced frequency fluctuations and population transfer between coupled vibrations. At the same time, frequency shifts arising from chemical-exchange reactions and changes of the transition dipoles because of either non-Condon effects or molecular reorientation are included in the treatment. This method therefore allows for the disentanglement of all of these processes. The NISE method has thus far been successfully applied to study chemical-exchange processes. It was demonstrated that 2DIR is not only sensitive to reaction kinetics but also to the more detailed reaction dynamics. NISE has also been applied to the study of population transfer within the amide I band (CO stretch) and between the amide I and amide II bands (CN stretch and NH bend) in polypeptides. From the amide I studies, it was found that the population transfer can be used to enhance cross-peaks that act as

  15. Study on Performance Parameters of the Plasma Source for a Short-Conduction-Time Plasma Opening Switch

    Institute of Scientific and Technical Information of China (English)

    LUO Weixi; ZENG Zhengzhong; WANG Liangping; LEI Tianshi; HU Yixiang; HUANG Tao; SUN Tieping

    2012-01-01

    Plasma source performance parameters, including plasma ejection density and velocity, greatly affect the operation of a short-conduction-time plasma opening switch (POS). In this paper, the plasma source used in the POS of Qiangguang I generator is chosen as the study object. At first the POS working process is analyzed. The result shows that the opening performance of the POS can be improved by increasing the plasma ejection velocity and decreasing the plasma density. The influence of the cable plasma gun structure and number on the plasma ejection parameters is experimentally investigated with two charge collectors. Finally a semi-empirical model is proposed to describe the experimental phenomenon.

  16. [Classification of results of studying blood plasma with laser correlation spectroscopy based on semiotics of preclinical and clinical states].

    Science.gov (United States)

    Ternovoĭ, K S; Kryzhanovskiĭ, G N; Musiĭchuk, Iu I; Noskin, L A; Klopov, N V; Noskin, V A; Starodub, N F

    1998-01-01

    The usage of laser correlation spectroscopy for verification of preclinical and clinical states is substantiated. Developed "semiotic" classifier for solving the problems of preclinical and clinical states is presented. The substantiation of biological algorithms as well as the mathematical support and software for the proposed classifier for the data of laser correlation spectroscopy of blood plasma are presented.

  17. Plasma Wind Tunnel Investigation of European Ablators in Nitrogen/Methane Using Emission Spectroscopy

    Directory of Open Access Journals (Sweden)

    Ricarda Wernitz

    2013-01-01

    Full Text Available For atmospheric reentries at high enthalpies ablative heat shield materials are used, such as those for probes entering the atmosphere of Saturn’s moon Titan, such as Cassini-Huygens in December, 2004. The characterization of such materials in a nitrogen/methane atmosphere is of interest. A European ablative material, AQ60, has been investigated in plasma wind tunnel tests at the IRS plasma wind tunnel PWK1 using the magnetoplasma dynamic generator RD5 as plasma source in a nitrogen/methane atmosphere. The dimensions of the samples are 45 mm in length with a diameter of 39 mm. The actual ablator has a thickness of 40 mm. The ablator is mounted on an aluminium substructure. The experiments were conducted at two different heat flux regimes, 1.4 MW/m2 and 0.3 MW/m2. In this paper, results of emission spectroscopy at these plasma conditions in terms of plasma species’ temperatures will be presented, including the investigation of the free-stream species, N2 and N2+, and the major erosion product C2, at a wavelength range around 500 nm–600 nm.

  18. Easy measurement of diffusion coefficients of EGFP-tagged plasma membrane proteins using k-space Image Correlation Spectroscopy

    DEFF Research Database (Denmark)

    Christensen, Eva Arnspang; Koffman, Jennifer Skaarup; Marlar, Saw

    2014-01-01

    Lateral diffusion and compartmentalization of plasma membrane proteins are tightly regulated in cells and thus, studying these processes will reveal new insights to plasma membrane protein function and regulation. Recently, k-Space Image Correlation Spectroscopy (kICS)1 was developed to enable ro...

  19. Application of mid-infrared tuneable diode laser absorption spectroscopy to plasma diagnostics: a review

    Energy Technology Data Exchange (ETDEWEB)

    Roepcke, J [INP-Greifswald, 17489 Greifswald, Friedrich-Ludwig-Jahn-Str. 19 (Germany); Lombardi, G [CNRS LIMHP, Universite Paris XIII, 99, av. J.B. Clement, 93430 Villetaneuse (France); Rousseau, A [Laboratoire de Physique et Technologie des Plasmas, Ecole Polytechnique, CNRS, 91128 Palaiseau (France); Davies, P B [Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (United Kingdom)

    2006-11-01

    Within the last decade mid-infrared absorption spectroscopy over a region from 3 to 17{mu}m and based on tuneable lead salt diode lasers, often called tuneable diode laser absorption spectroscopy or TDLAS, has progressed considerably as a powerful diagnostic technique for in situ studies of the fundamental physics and chemistry in molecular plasmas. The increasing interest in processing plasmas containing hydrocarbons, fluorocarbons, organo-silicon and boron compounds has led to further applications of TDLAS because most of these compounds and their decomposition products are infrared active. TDLAS provides a means of determining the absolute concentrations of the ground states of stable and transient molecular species, which is of particular importance for the investigation of reaction kinetic phenomena. Information about gas temperature and population densities can also be derived from TDLAS measurements. A variety of free radicals and molecular ions have been detected by TDLAS. Since plasmas with molecular feed gases are used in many applications such as thin film deposition, semiconductor processing, surface activation and cleaning, and materials and waste treatment, this has stimulated the adaptation of infrared spectroscopic techniques to industrial requirements. The recent development of quantum cascade lasers (QCLs) offers an attractive new option for the monitoring and control of industrial plasma processes. The aim of the present paper is threefold: (i) to review recent achievements in our understanding of molecular phenomena in plasmas (ii) to report on selected studies of the spectroscopic properties and kinetic behaviour of radicals and (iii) to describe the current status of advanced instrumentation for TDLAS in the mid-infrared.

  20. A Clinical Tissue Oximeter Using NIR Time-Resolved Spectroscopy.

    Science.gov (United States)

    Fujisaka, Shin-ichi; Ozaki, Takeo; Suzuki, Tsuyoshi; Kamada, Tsuyoshi; Kitazawa, Ken; Nishizawa, Mitsunori; Takahashi, Akira; Suzuki, Susumu

    2016-01-01

    The tNIRS-1, a new clinical tissue oximeter using NIR time-resolved spectroscopy (TRS), has been developed. The tNIRS-1 measures oxygenated, deoxygenated and total hemoglobin and oxygen saturation in living tissues. Two-channel TRS measurements are obtained using pulsed laser diodes (LD) at three wavelengths, multi-pixel photon counters (MPPC) for light detection, and time-to-digital converters (TDC) for time-of-flight photon measurements. Incorporating advanced semiconductor devices helped to make the design of this small-size, low-cost and low-power TRS instrument possible. In order to evaluate the correctness and reproducibility of measurement data obtained with the tNIRS-1, a study using blood phantoms and healthy volunteers was conducted to compare data obtained from a conventional SRS device and data from an earlier TRS system designed for research purposes. The results of the study confirmed the correctness and reproducibility of measurement data obtained with the tNIRS-1. Clinical evaluations conducted in several hospitals demonstrated a high level of usability in clinical situations and confirmed the efficacy of measurement data obtained with the tNIRS-1.

  1. Novel focal point multipass cell for absorption spectroscopy on small sized atmospheric pressure plasmas

    Science.gov (United States)

    Winter, Jörn; Hänel, Mattis; Reuter, Stephan

    2016-04-01

    A novel focal point multipass cell (FPMPC) was developed, in which all laser beams propagate through a common focal point. It is exclusively constructed from standard optical elements. Main functional elements are two 90∘ off-axis parabolic mirrors and two retroreflectors. Up to 17 laser passes are demonstrated with a near-infrared laser beam. The number of laser passes is precisely adjustable by changing the retroreflector distance. At the focal point beams are constricted to fit through an aperture of 0.8 mm. This is shown for 11 beam passes. Moreover, the fast temporal response of the cell permits investigation of transient processes with frequencies up to 10 MHz. In order to demonstrate the applicability of the FPMPC for atmospheric pressure plasma jets, laser absorption spectroscopy on the lowest excited argon state (1s5) was performed on a 1 MHz argon atmospheric pressure plasma jet. From the obtained optical depth profiles, the signal-to-noise ratio was deduced. It is shown that an elevation of the laser pass number results in an proportional increase of the signal-to-noise ratio making the FPMPC an appropriate tool for absorption spectroscopy on plasmas of small dimensions.

  2. Novel focal point multipass cell for absorption spectroscopy on small sized atmospheric pressure plasmas.

    Science.gov (United States)

    Winter, Jörn; Hänel, Mattis; Reuter, Stephan

    2016-04-01

    A novel focal point multipass cell (FPMPC) was developed, in which all laser beams propagate through a common focal point. It is exclusively constructed from standard optical elements. Main functional elements are two 90(∘) off-axis parabolic mirrors and two retroreflectors. Up to 17 laser passes are demonstrated with a near-infrared laser beam. The number of laser passes is precisely adjustable by changing the retroreflector distance. At the focal point beams are constricted to fit through an aperture of 0.8 mm. This is shown for 11 beam passes. Moreover, the fast temporal response of the cell permits investigation of transient processes with frequencies up to 10 MHz. In order to demonstrate the applicability of the FPMPC for atmospheric pressure plasma jets, laser absorption spectroscopy on the lowest excited argon state (1s5) was performed on a 1 MHz argon atmospheric pressure plasma jet. From the obtained optical depth profiles, the signal-to-noise ratio was deduced. It is shown that an elevation of the laser pass number results in an proportional increase of the signal-to-noise ratio making the FPMPC an appropriate tool for absorption spectroscopy on plasmas of small dimensions.

  3. Novel focal point multipass cell for absorption spectroscopy on small sized atmospheric pressure plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Winter, Jörn, E-mail: winter@inp-greifswald.de; Hänel, Mattis; Reuter, Stephan [Leibniz Institute for Plasma Science and Technology e.V., Felix-Hausdorff-St. 2, 17489 Greifswald (Germany)

    2016-04-15

    A novel focal point multipass cell (FPMPC) was developed, in which all laser beams propagate through a common focal point. It is exclusively constructed from standard optical elements. Main functional elements are two 90{sup ∘} off-axis parabolic mirrors and two retroreflectors. Up to 17 laser passes are demonstrated with a near-infrared laser beam. The number of laser passes is precisely adjustable by changing the retroreflector distance. At the focal point beams are constricted to fit through an aperture of 0.8 mm. This is shown for 11 beam passes. Moreover, the fast temporal response of the cell permits investigation of transient processes with frequencies up to 10 MHz. In order to demonstrate the applicability of the FPMPC for atmospheric pressure plasma jets, laser absorption spectroscopy on the lowest excited argon state (1s{sub 5}) was performed on a 1 MHz argon atmospheric pressure plasma jet. From the obtained optical depth profiles, the signal-to-noise ratio was deduced. It is shown that an elevation of the laser pass number results in an proportional increase of the signal-to-noise ratio making the FPMPC an appropriate tool for absorption spectroscopy on plasmas of small dimensions.

  4. Copper Determination in Gunshot Residue by Cyclic Voltammetric and Inductive Coupled Plasma-Optical Emission Spectroscopy

    Directory of Open Access Journals (Sweden)

    Mohd Hashim Nurul’Afiqah Hashimah

    2016-01-01

    Full Text Available Analysis of gunshot residue (GSR is a crucial evidences for a forensic analyst in the fastest way. GSR analysis insists a suitable method provides a relatively simple, rapid and precise information on the spot at the crime scene. Therefore, the analysis of Cu(II in GSR using cyclic voltammetry (CV on screen printed carbon electrode (SPCE is a better choice compared to previous alternative methods such as Inductive Coupled Plasma-Optical Emission Spectroscopy (ICP-OES those required a long time for analysis. SPCE is specially designed to handle with microvolumes of sample such as GSR sample. It gives advantages for identification of copper in GSR on-site preliminary test to prevent the sample loss on the process to be analyzed in the laboratory. SPCE was swabbed directly on the shooter’s arm immediately after firing and acetate buffer was dropped on SPCE before CV analysis. For ICP-OES analysis, cotton that had been soaked in 0.5 M nitric acid was swabbed on the shooter’s arm immediately after firing and kept in a tightly closed sampling tube. Gold coated SPCE that had been through nanoparticles modification exhibits excellent performance on voltammograms. The calibration was linear from 1 to 50 ppm of copper, the limit of detection for copper was 0.3 ppm and a relative standard deviation was 6.1 %. The method was successfully applied to the determination of copper in GSR. The Cu determination on SPCE was compared and validated by ICP-OES method with 94 % accuracy.

  5. Determination of total tin in canned food using inductively coupled plasma atomic emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Perring, Loic; Basic-Dvorzak, Marija [Department of Quality and Safety Assurance, Nestle Research Centre, P.O. Box 44, Vers chez-les-Blanc, 1000, Lausanne (Switzerland)

    2002-09-01

    Tin is considered to be a priority contaminant by the Codex Alimentarius Commission. Tin can enter foods either from natural sources, environmental pollution, packaging material or pesticides. Higher concentrations are found in processed food and canned foods. Dissolution of the tinplate depends on the of food matrix, acidity, presence of oxidising reagents (anthocyanin, nitrate, iron and copper) presence of air (oxygen) in the headspace, time and storage temperature. To reduce corrosion and dissolution of tin, nowadays cans are usually lacquered, which gives a marked reduction of tin migration into the food product. Due to the lack of modern validated published methods for food products, an ICP-AES (Inductively coupled plasma-atomic emission spectroscopy) method has been developed and evaluated. This technique is available in many laboratories in the food industry and is more sensitive than atomic absorption. Conditions of sample preparation and spectroscopic parameters for tin measurement by axial ICP-AES were investigated for their ruggedness. Two methods of preparation involving high-pressure ashing or microwave digestion in volumetric flasks were evaluated. They gave complete recovery of tin with similar accuracy and precision. Recoveries of tin from spiked products with two levels of tin were in the range 99{+-}5%. Robust relative repeatabilities and intermediate reproducibilities were <5% for different food matrices containing >30 mg/kg of tin. Internal standard correction (indium or strontium) did not improve the method performance. Three emission lines for tin were tested (189.927, 283.998 and 235.485 nm) but only 189.927 nm was found to be robust enough with respect to interferences, especially at low tin concentrations. The LOQ (limit of quantification) was around 0.8 mg/kg at 189.927 nm. A survey of tin content in a range of canned foods is given. (orig.)

  6. Real-time control of microreactors by Raman spectroscopy

    Science.gov (United States)

    Shende, Chetan; Maksymiuk, Paul; Inscore, Frank; Farquharson, Stuart

    2006-10-01

    In recent years a paradigm in chemical manufacturing has emerged, numbering-up production instead of the traditional scaling-up. This new approach employs nanoliter to milliliter reactors that increase control of reaction pathways, product choice and yield. These small-scale reactors virtually eliminate mixing and heat transfer problems associated with large-scale reactors that often limit yield. The value of small-scale reactors is being recognized by the pharmaceutical industry where only small-scale synthesis is required until clinical trials are complete, at which time fullscale production needs to be accomplished in the shortest possible time. One of the most often used reaction steps during the synthesis of pharmaceuticals is protecting carboxylic acid groups by esterification. We have been developing Raman spectroscopy as a process analytical tool to monitor and control chemistry in such small-scale reactors. Here we present Raman spectra of the esterification of benzoic acid performed in a 5-mL batch reactor.

  7. Quantitative analysis of surface amine groups on plasma-polymerized ethylenediamine films using UV-visible spectroscopy compared to chemical derivatization with FT-IR spectroscopy, XPS and TOF-SIMS

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jinmo [Department of Physics, Brain Korea 21 Physics Research Division and Institute of Basic Science, Sungkyunkwan University (SKKU), Suwon 440-746 (Korea, Republic of); Division of Advanced Technology, Korea Research Institute of Standards and Science (KRISS), Daejeon 305-600 (Korea, Republic of); Jung, Donggeun [Department of Physics, Brain Korea 21 Physics Research Division and Institute of Basic Science, Sungkyunkwan University (SKKU), Suwon 440-746 (Korea, Republic of); Park, Yongsup [Division of Advanced Technology, Korea Research Institute of Standards and Science (KRISS), Daejeon 305-600 (Korea, Republic of); Kim, Yongki [Department of Physics, Brain Korea 21 Physics Research Division and Institute of Basic Science, Sungkyunkwan University (SKKU), Suwon 440-746 (Korea, Republic of); Division of Advanced Technology, Korea Research Institute of Standards and Science (KRISS), Daejeon 305-600 (Korea, Republic of); Moon, Dae Won [Division of Advanced Technology, Korea Research Institute of Standards and Science (KRISS), Daejeon 305-600 (Korea, Republic of); Lee, Tae Geol [Division of Advanced Technology, Korea Research Institute of Standards and Science (KRISS), Daejeon 305-600 (Korea, Republic of)]. E-mail: tglee@kriss.re.kr

    2007-02-28

    A quantitative analysis of the surface density of amine groups on a plasma-polymerized ethylenediamine thin film deposited on a platinum surface using inductively coupled plasma chemical vapor deposition method is described. UV-visible spectroscopy together with a chemical derivatization technique using Fourier transform infrared (FT-IR) spectroscopy was used to obtain the quantitative information. Chemical tags of pentafluorobenzaldehyde were hybridized with the surface amine groups and were easily detected due to the characteristic absorption bands of C-F stretching, aromatic ring and C=N stretching vibrations in the reflection-absorption FT-IR spectra. The surface amine density was reproducibly controlled as a function of deposition plasma power and quantified using UV-visible spectroscopy. A good linear correlation was observed between the FT-IR intensities of the characteristic absorption bands and the surface amine densities, suggesting the possibility of using this chemical derivatization technique to quantify the surface densities of specific functional groups on an organic surface. Chemical derivatization was also used with X-ray photoelectron spectroscopy on the same samples, and the results were compared with those obtained from FT-IR and time-of-flight secondary ion mass spectrometry. Although each analysis technique has different probing depths from the surface, the three different data sets obtained from the chemical tags correlated well with each other since each analysis technique measured the chemical tags on the sample surface.

  8. Electron-transfer acceleration investigated by time resolved infrared spectroscopy.

    Science.gov (United States)

    Vlček, Antonín; Kvapilová, Hana; Towrie, Michael; Záliš, Stanislav

    2015-03-17

    Ultrafast electron transfer (ET) processes are important primary steps in natural and artificial photosynthesis, as well as in molecular electronic/photonic devices. In biological systems, ET often occurs surprisingly fast over long distances of several tens of angströms. Laser-pulse irradiation is conveniently used to generate strongly oxidizing (or reducing) excited states whose reactions are then studied by time-resolved spectroscopic techniques. While photoluminescence decay and UV-vis absorption supply precise kinetics data, time-resolved infrared absorption (TRIR) and Raman-based spectroscopies have the advantage of providing additional structural information and monitoring vibrational energy flows and dissipation, as well as medium relaxation, that accompany ultrafast ET. We will discuss three cases of photoinduced ET involving the Re(I)(CO)3(N,N) moiety (N,N = polypyridine) that occur much faster than would be expected from ET theories. [Re(4-N-methylpyridinium-pyridine)(CO)3(N,N)](2+) represents a case of excited-state picosecond ET between two different ligands that remains ultrafast even in slow-relaxing solvents, beating the adiabatic limit. This is caused by vibrational/solvational excitation of the precursor state and participation of high-frequency quantum modes in barrier crossing. The case of Re-tryptophan assemblies demonstrates that excited-state Trp → *Re(II) ET is accelerated from nanoseconds to picoseconds when the Re(I)(CO)3(N,N) chromophore is appended to a protein, close to a tryptophan residue. TRIR in combination with DFT calculations and structural studies reveals an interaction between the N,N ligand and the tryptophan indole. It results in partial electronic delocalization in the precursor excited state and likely contributes to the ultrafast ET rate. Long-lived vibrational/solvational excitation of the protein Re(I)(CO)3(N,N)···Trp moiety, documented by dynamic IR band shifts, could be another accelerating factor. The last

  9. Real-time analysis for MBE by time-resolved core-level photoelectron spectroscopy.

    Science.gov (United States)

    Maeda, F; Watanabe, Y; Oshima, M; Taguchi, M; Oiwa, R

    1998-05-01

    A system has been developed for the real-time analysis of surface reactions during molecular beam epitaxial growth which uses photoelectron spectroscopy with VUV light taken from synchrotron radiation. This system consists of a synchrotron radiation beamline and growth/analysis apparatus in which photoelectron spectroscopy is performed with sub-second time resolution. In this system, photoelectron spectra are measured in sequence by a 'non-scanning' measurement method that enables the acquisition of snapshot photoelectron spectra using a multi-channel detector. This non-scanning measurement method was enabled by equipping an electric field correction grid. This system was used to monitor the photoelectron spectra of a GaSb(001) surface.

  10. Inverse time-of-flight spectrometer for beam plasma research

    Energy Technology Data Exchange (ETDEWEB)

    Yushkov, Yu. G., E-mail: yuyushkov@gmail.com; Zolotukhin, D. B.; Tyunkov, A. V. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Oks, E. M. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation); Savkin, K. P. [Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation)

    2014-08-15

    The paper describes the design and principle of operation of an inverse time-of-flight spectrometer for research in the plasma produced by an electron beam in the forevacuum pressure range (5–20 Pa). In the spectrometer, the deflecting plates as well as the drift tube and the primary ion beam measuring system are at high potential with respect to ground. This provides the possibility to measure the mass-charge constitution of the plasma created by a continuous electron beam with a current of up to 300 mA and electron energy of up to 20 keV at forevacuum pressures in the chamber placed at ground potential. Research results on the mass-charge state of the beam plasma are presented and analyzed.

  11. Optical Emission Spectroscopy Investigation of a Surface Dielectric Barrier Discharge Plasma Aerodynamic Actuator

    Institute of Scientific and Technical Information of China (English)

    LI Ying-Hong; WU Yun; JIA Min; ZHOU Zhang-Wen; GUO Zhi-Gang; PU Yi-Kang

    2008-01-01

    The optical emission spectroscopy of a surface dielectric barrier discharge plasma aerodynamic actuator is investigated with different electrode configurations, applied voltages and driving frequencies. The rotational temperature of N2 (C3IIu) molecule is calculated according to its rotational emission band near 380.5 nm. The average electron energy of the discharge is evaluated by emission intensity ratio of first negative system to second positive system of N2. The rotational temperature is sensitive to the inner space of an electrode pair. The average electron energy shows insensitivity to the applied voltage, the driving frequency and the electrode configuration.

  12. A laser-generated plasma as a source of VUV continuum radiation for photoelectronic spectroscopy

    OpenAIRE

    Heckenkamp, Ch.; Heinzmann, Ulrich; Schönhense, G.; BURGESS.D.D; Thorne, A. P.; Wheaton, J. E. G.

    1981-01-01

    The feasibility of using laser-generated plasmas as VUV continuum sources for photoelectron spectroscopy has been demonstrated by measuring the spectral intensity distribution of the VUV continuum in the wavelength region from 79 to 43 nm by energy analysis of the photoelectrons ejected from argon atoms. The maximum photon flux obtained after reflection at a gold-coated spherical mirror was of the order of 10(11) photons nm(-1) per pulse at 50 nm for a laser energy of 830 mJ. The results show...

  13. Optical emission spectroscopy study of the expansion dynamics of a laser generated plasma during the deposition of thin films by laser ablation

    Directory of Open Access Journals (Sweden)

    Fazio, Enza

    2007-09-01

    Full Text Available The dynamics of the expanding plasma produced by excimer laser ablation of different materials such as silicon, silicon carbide, graphite and tin powder were studied by means of time integrated, spatially resolved emission spectroscopy and fast photography imaging of the expanding plasma. Experiments were performed both in vacuum and in different pure background atmosphere (i.e. oxygen or nitrogen and, finally, in gaseous mixtures (i.e. in O2/Ar and N2/Ar mixtures. These investigations were performed to gather information on the nature of the chemical species present in the plasma and on the occurrence of chemical reactions during the interaction between the plasma and the background gas. Then, we tried to correlate the plasma expansion dynamics to the structural and physical properties of the deposited materials. Experimental results clearly indicate that there is a strong correlation between the plasma expansion dynamics and the structural properties of the deposited thin films. In this respect, the investigations performed by means of fast photography and of optical emission spectroscopy revealed themselves as powerful tools for an efficient control of the deposition process itself.

  14. Real-time monitoring of reactive species in downstream etch reactor by VUV broad-band absorption spectroscopy

    Science.gov (United States)

    Soriano, R.; Vallier, L.; Cunge, G.; Sadeghi, N.

    2016-09-01

    Plasma etching of nanometric size, high aspect-ratio structures is more challenging at each new technological node. Remote plasmas are beginning to find use when damages on nanostructures by ion bombardment become critical or when etching with high selectivity on different materials present on the wafer is necessary (i . e . tungsten oxide etching with fluorine and hydrogen containing plasmas in remote reactor from AMAT). Furthermore, it is expected that downstream plasma will replace many wet chemical etching processes to alleviate the issue of pattern collapses caused by capillary forces when nanometer size high aspect ratio structures are immersed in liquids. In these downstream plasmas, radicals are the main active species and a control of their density is of prime importance. Most of gases used and radicals produced in etching plasmas (HBr, BrCl, Br2, NF3, CH2F2,...) have strong absorption bands in the vacuum UV spectral region and we have shown that very low concentration of these species can be detected by VUV absorption. We have recently improved the technique by using a VUV CCD camera, instead of the PMT, which render possible the Broad-Band absorption spectroscopy in the 120-200 nm range, with a deuterium lamp, or a laser produced xenon arc lamp as light source. The multi-spectral detection ability of the CCD reduces the acquisition time to less than 1 second and can permit the real time control of the process control.

  15. High sensitivity ultra-broad-band absorption spectroscopy of inductively coupled chlorine plasma

    Science.gov (United States)

    Marinov, Daniil; Foucher, Mickaël; Campbell, Ewen; Brouard, Mark; Chabert, Pascal; Booth, Jean-Paul

    2016-06-01

    We propose a method to measure the densities of vibrationally excited Cl2(v) molecules in levels up to v  =  3 in pure chlorine inductively coupled plasmas (ICPs). The absorption continuum of Cl2 in the 250-450 nm spectral range is deconvoluted into the individual components originating from the different vibrational levels of the ground state, using a set of ab initio absorption cross sections. It is shown that gas heating at constant pressure is the major depletion mechanism of the Cl2 feedstock in the plasma. In these line-integrated absorption measurements, the absorption by the hot (and therefore rarefied) Cl2 gas in the reactor centre is masked by the cooler (and therefore denser) Cl2 near the walls. These radial gradients in temperature and density make it difficult to assess the degree of vibrational excitation in the centre of the reactor. The observed line-averaged vibrational distributions, when analyzed taking into account the radial temperature gradient, suggest that vibrational and translational degrees of freedom in the plasma are close to local equilibrium. This can be explained by efficient vibrational-translational (VT) relaxation between Cl2 and Cl atoms. Besides the Cl2(v) absorption band, a weak continuum absorption is observed at shorter wavelengths, and is attributed to photodetachment of Cl- negative ions. Thus, line-integrated densities of negative ions in chlorine plasmas can be directly measured using broad-band absorption spectroscopy.

  16. Use of time-resolved fluorescence spectroscopy to evaluate diagnostic value of collagen degradation products.

    Science.gov (United States)

    Sikora, Joanna; Cyrankiewicz, Michał; Wybranowski, Tomasz; Ziomkowska, Blanka; Ośmiałowski, Borys; Obońska, Ewa; Augustyńska, Beata; Kruszewski, Stefan; Kubica, Jacek

    2015-05-01

    The concentration of collagen degradation products (CDPs) may reflect the process of left ventricular remodeling (LVR). The aim of this study was to evaluate the potential diagnostic usefulness of time-resolved fluorescence spectroscopy (TRFS) in assessment of CDPs. The preliminary experiment was designed to establish if CDPs’ characteristics might be visible by mean fluorescence lifetime (FLT) in determined conditions. The in vitro model of CDPs was prepared by conducting the hydrolysis of type III collagen. The FLT of samples was measured by the time-resolved spectrometer Life Spec II with the subnanosecond pulsed 360-nm EPLED diode. The FLTs were obtained by deconvolution analysis of the data using a multiexponential model of fluorescence decay. In order to determine the limit of traceability of CDPs, a comparison of different collagen/plasma ratio in samples was performed. The results of our study showed that the increase of added plasma to hydrolyzed collagen extended the mean FLT. Thus, the diagnosis of LVR based on measurements using TRFS is possible. However, it is important to point out the experiment was preliminary and further investigation in this field of research is crucial.

  17. Determination of structure tilting in magnetized plasmas - Time delay estimation in two dimensions

    CERN Document Server

    Guszejnov, Dávid; Zoletnik, Sándor; Andreas-Krämer-Flecken,

    2013-01-01

    Time delay estimation (TDE) is a well-known technique to investigate poloidal flows in fusion plasmas. The present work is an extension of the earlier works of A. Bencze and S. Zoletnik 2005 and B. T\\'al et al. 2011. From the prospective of the comparison of theory and experiment it seem to be important to estimate the statistical properties of the TDE based on solid mathematical groundings. This paper provides analytic derivation of the variance of the TDE using a two-dimensional model for coherent turbulent structures in the plasma edge and also gives an explicit method for determination of the tilt angle of structures. As a demonstration this method is then applied to the results of a quasi-2D Beam Emission Spectroscopy (BES) measurement performed at the TEXTOR tokamak.

  18. IAU Colloquium on UV and X-ray Spectroscopy of Astrophysical and Laboratory Plasmas, 102nd, Beaulieu-sur-Mer, France, Sept. 9-11, 1987, Proceedings

    Science.gov (United States)

    Bely-Dubau, F.; Faucher, P.

    1988-03-01

    The present conference discusses the solar physics results of Spacelab 2, spectroscopic methods for electron density determination, microcalorimeters for X-ray spectroscopy, spectral observations of the XUV astronomical background radiation, XUV lasers, spectroscopic diagnoses of tokamaks, nonthermal X-ray spectra from a tokamak, and space- and time-resolved plasma diagnostics in laser-produced plasmas. Also discussed are the application in atomic physics of coupled differential equations, the interpretation of unresolved hyperfine and/or Zeeman structures in stellar spectra, atomic physics for hot plasmas, IUE satellite-based UV astronomy contributions, plasma shifts of ion lines, and the use of Ti, Si, C, Be, and LiF in soft X-ray optics.

  19. Nitrocellulose membrane sample holder using for terahertz time domain spectroscopy

    Science.gov (United States)

    Zhao, Xiaojing; Liu, Shangjian; Wang, Cuicui; Zuo, Jian; Zhang, Cunlin

    2016-11-01

    Terahertz (THz) technology has promising applications for the detection and identification of materials because it has a great advantage in measuring material fingerprint spectrum. Terahertz time-domain spectroscopy (THz-TDS) is a key technique that is applied to spectroscopic measurement of materials. However, it is difficult to press a pellet with small mass of sample and a bulking medium such as polyethylene (PE) powder usually need to be added. Characteristic absorption peaks of the solution in liquid cell is hard to be observed due to the interaction between materials and water molecules. Therefore, one method using the hydrophilic nitrocellulose (NC) membrane as a sample holder was applied to detect samples in an aqueous medium by THz-TDS. In this study, the α-lactose samples were mixed with 20 μl of deionized water and then applied directly onto the double-layered NC membrane sample holder. This mixture is located on the gap of two piece of NC membranes. Firstly the NC membranes with different pore sizes were tested in the experiment. And then the α-lactose solutions with different concentrations were measured on the NC with different pore sizes. Consequently, the small mass of samples can be detected and the characteristic absorption peaks become stronger with the increase of NC pore size. Moreover, compared to the traditional pellet-making and liquid cell detection, this membrane method is more convenient and easy to operate.

  20. Determining Phthalic Acid Esters Using Terahertz Time Domain Spectroscopy

    Science.gov (United States)

    Liu, L.; Shen, L.; Yang, F.; Han, F.; Hu, P.; Song, M.

    2016-09-01

    In this report terahertz time domain spectroscopy (THz-TDS) is applied for determining phthalic acid esters (PAEs) in standard materials. We reported the THz transmission spectrum in the frequency range of 0.2 to 2.0 THz for three PAEs: di-n-butyl phthalate (DBP), di-isononyl phthalate (DINP), and di-2-ethylhexyl phthalate ester (DEHP). The study provided the refractive indices and absorption features of these materials. The absorption spectra of three PAEs were simulated by using Gaussian software with Density Functional Theory (DFT) methods. For pure standard PAEs, the values of the refractive indices changed between 1.50 and 1.60. At 1.0 THz, the refractive indices were 1.524, 1.535, and 1.563 for DINP, DEHP, and DBP, respectively. In this experiment different concentrations of DBP were investigated using THz-TDS. Changes were measured in the low THz frequency range for refractive indices and characteristic absorption. The results indicated that THz-TDS is promising as a new method in determining PAEs in many materials. The results of this study could be used to support the practical application of THz-TDS in quality detection and food monitoring. In particular, this new technique could be used in detecting hazardous materials and other substances present in wine or foods.

  1. Reconstruction of relaxation time distribution from linear electrochemical impedance spectroscopy

    Science.gov (United States)

    Zhang, Yanxiang; Chen, Yu; Yan, Mufu; Chen, Fanglin

    2015-06-01

    Linear electrochemical impedance spectroscopy (EIS), and in particular its representation of distribution of relaxation time (DRT), enables the identification of the number of processes and their nature involved in electrochemical cells. With the advantage of high frequency resolution, DRT has recently drawn increasing attention for applications in solid oxide fuel cells (SOFCs). However, the method of DRT reconstruction is not yet presented clearly in terms of what mathematical treatments and theoretical assumptions have been made. Here we present unambiguously a method to reconstruct DRT function of impedance based on Tikhonov regularization. By using the synthetic impedances and analytic DRT functions of RQ element, generalized finite length Warburg element, and Gerischer element with physical quantities representative to those of SOFC processes, we show that the quality of DRT reconstruction is sensitive to the sampling points per decade (ppd) of frequency from the impedance measurement. The robustness of the DRT reconstruction to resist noise imbedded in impedance data and numerical calculations can be accomplished by optimizing the weighting factor λ according to well defined criterion.

  2. Characterization of a microsecond-conduction-time plasma opening switch

    Science.gov (United States)

    Commisso, R. J.; Goodrich, P. J.; Grossmann, J. M.; Hinshelwood, D. D.; Ottinger, P. F.; Weber, B. V.

    1992-07-01

    This paper presents data and analyses from which emerges a physical picture of microsecond-conduction-time plasma opening switch operation. During conduction, a broad current channel penetrates axially through the plasma, moving it toward the load. Opening occurs when the current channel reaches the load end of the plasma, far from the load. During conduction, the axial line density in the interelectrode region is reduced from its value with no current conduction as a result of radial hydrodynamic forces associated with the current channel. A factor of 20 reduction is observed at opening in a small, localized region between the electrodes. When open, the switch plasma behaves like a section of magnetically insulated transmission line with an effective gap of 2 to 3 mm. Increasing the magnetic field in this gap by 50% results in an improvement of 50% in the peak load voltage and load current rise time, to 1.2 MV and 20 nsec, respectively. An erosion opening mechanism explains the inferred gap growth rate using the reduced line density at opening. Improved switch performance results when the maximum gap size is increased by using a rising load impedance.

  3. Double core-hole spectroscopy of transient plasmas produced in the interaction of ultraintense x-ray pulses with neon

    CERN Document Server

    Gao, Cheng; Yuan, Jianmin

    2015-01-01

    Double core-hole (DCH) spectroscopy is investigated systematically for neon atomic system in the interaction with ultraintense x-ray pulses with photon energy from 937 eV to 2000 eV. A time-dependent rate equation, implemented in the detailed level accounting approximation, is utilized to study the dynamical evolution of the level population and emission properties of the highly transient plasmas. For x-ray pulses with photon energy in the range of 937-1030 eV, where $1s\\rightarrow 2p$ resonance absorption from single core-hole (SCH) states of neon charge states exist, inner-shell resonant absorption (IRA) effects play important roles in the time evolution of population and DCH spectroscopy. Such IRA physical effects are illustrated in detail by investigating the interaction of x-ray pulses at a photon energy of 944 eV, which corresponds to the $1s\\rightarrow 2p$ resonant absorption from the SCH states ($1s2s^22p^4$, $1s2s2p^5$ and $1s2p^6$) of Ne$^{3+}$. After averaging over the space and time distribution o...

  4. Time-resolved optical spectroscopy measurements of shocked liquid deuterium

    Science.gov (United States)

    Bailey, J. E.; Knudson, M. D.; Carlson, A. L.; Dunham, G. S.; Desjarlais, M. P.; Hanson, D. L.; Asay, J. R.

    2008-10-01

    Time-resolved optical spectroscopy has been used to measure the shock pressure steadiness, emissivity, and temperature of liquid deuterium shocked to 22-90 GPa. The shock was produced using magnetically accelerated flyer plate impact, and spectra were acquired with a suite of four fiber-optic-coupled spectrometers with streak camera detectors. The shock pressure changes by an average of -1.2% over the 10-30 ns cell transit time, determined from the relative changes in the shock front self-emission with time. The shock front reflectivity was measured from 5140Å and 5320Å laser light reflected from the D2 shock. The emissivity inferred from the reflectivity measurements was in reasonably good agreement with quantum molecular dynamics simulation predictions. The spectral radiance wavelength dependence was found to agree well (average normalized χ2=1.6 ) with a Planckian multiplied by the emissivity. The shock front temperature was determined from the emissivity and the wavelength-dependent shock self-emission. Thirty-seven temperature measurements spanning the 22-90 GPa range were accumulated. The large number of temperature measurements enables a comparison of the scatter in the data with expectations for a Gaussian distribution. This facilitates determination of uncertainties that incorporate both apparatus contributions and otherwise unquantified systematic effects that cause self-emission variations from one experiment to another. Agreement between temperatures determined from the absolute spectral radiance and from the relative shape of the spectrum further substantiates the absence of systematic biases. The weighted mean temperature uncertainties were as low as ±3-4% , enabling the discrimination between competing models for the D2 equation of state (EOS). The temperature results agree well with models that predict a maximum compression of ˜4.4 . Softer models that predict approximately sixfold compression are inconsistent with the data to a very high

  5. Real-time specific surface area measurements via laser-induced breakdown spectroscopy

    Science.gov (United States)

    Washburn, Kathryn E.; Birdwell, Justin E.; Howard, James E.

    2017-01-01

    From healthcare to cosmetics to environmental science, the specific surface area (SSA) of micro- and mesoporous materials or products can greatly affect their chemical and physical properties. SSA results are also widely used to examine source rocks in conventional and unconventional petroleum resource plays. Despite its importance, current methods to measure SSA are often cumbersome, time-consuming, or require cryogenic consumables (e.g., liquid nitrogen). These methods are not amenable to high-throughput environments, have stringent sample preparation requirements, and are not practical for use in the field. We present a new application of laser-induced breakdown spectroscopy for rapid measurement of SSA. This study evaluates geological samples, specifically organic-rich oil shales, but the approach is expected to be applicable to many other types of materials. The method uses optical emission spectroscopy to examine laser-generated plasma and quantify the amount of argon adsorbed to a sample during an inert gas purge. The technique can accommodate a wide range of sample sizes and geometries and has the potential for field use. These advantages for SSA measurement combined with the simultaneous acquisition of composition information make this a promising new approach for characterizing geologic samples and other materials.

  6. Influence of gas and treatment time on the surface modification of EPDM rubber treated at afterglow microwave plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Maia, J.V. da, E-mail: jaisondamaia@hotmail.com [Plasmas and Processes Laboratory, Department of Physics, Technological Institute of Aeronautics, 12228-900 S. J. dos Campos, SP (Brazil); Department of Physics, Federal Institute of Santa Catarina, 89251-000 Jaraguá do Sul, SC (Brazil); Pereira, F.P. [Plasmas and Processes Laboratory, Department of Physics, Technological Institute of Aeronautics, 12228-900 S. J. dos Campos, SP (Brazil); Dutra, J.C.N.; Mello, S.A.C. [EBO, Chemistry Division, IAE, CTA, 12228-900 S. J. dos Campos, SP (Brazil); Becerra, E.A.O. [Department of Physics, Pontifical Catholic University of Rio de Janeiro, Rio de Janeiro, RJ (Brazil); Massi, M.; Sobrinho, A.S. da Silva [Plasmas and Processes Laboratory, Department of Physics, Technological Institute of Aeronautics, 12228-900 S. J. dos Campos, SP (Brazil)

    2013-11-15

    The ethylene propylene diene monomer (EPDM) rubber possesses excellent physical/chemical bulk properties, is cost-effective, and has been used in the mechanical and aerospace industry. However, it has an inert surface and needs a surface treatment in order to improve its adhesion properties. Plasma modification is the most accepted technique for surface modification of polymers without affecting the properties of the bulk. In this study, an afterglow microwave plasma reactor was used to generate the plasma species responsible for the EPDM surface modification. The plasma modified surfaces were analyzed by means of contact angle measurement, adhesion tests, attenuated total reflection-infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscopy. Two experimental variables were analyzed: type of the plasma gases and exposure time were considered. The predominant failure mode was adhesive, for long treatment times a mixture of adhesive and cohesive failure can be observed and the best conditions tested there was an increase of the rupture strength of about 27%, that can be associated mainly with the creation of oxygen containing functional groups on the rubber surface (C-O, C-O-C and C=O) identified by spectroscopic methods. The predominant failure mode was adhesive, for long treatment times a mixture of adhesive and cohesive failure can be observed. In various conditions tested the contact angles easily decreased more than 500%. What can be concluded that high wettability is a necessary condition to obtain good adhesion, but this is not a sufficient condition.

  7. Investigation of neutral and ion dynamics in a HiPIMS plasma by tunable laser diode absorption spectroscopy (TDLAS)

    Science.gov (United States)

    Preissing, Patrick; Hecimovic, Ante; von Keudell, Achim

    2016-09-01

    High power impulse magnetron sputtering (HiPIMS) discharges are known for complex plasma interactions, and complex temporal and spatial dynamics. Spatial and temporal dynamic of argon metastable (Arm), Ti atom (Ti0) and Ti ion (Ti+) density and temperature is studied by an extended tunable diode laser absorption spectroscopy setup (TDLAS) during a HiPIMS pulse. The TDLAS setup used a beam expander in combination with a 6 photo diode array to simultaneously measure spatial (resolution 5 mm) and time resolved absorption profiles of an Arm, Ti0 and Ti+ transition. This in combination with moving the magnetron in axial direction gives a complete 2D map of the density evolution. Temporal resolution of 400 ns was achieved by recording the photo diode signal on the National Instruments card. Final results allowed to investigate temporal evolution of the observed species in the volume between the target and the substrate.

  8. Fast analysis of complex metallic alloys by double-pulse time-integrated Laser-Induced Breakdown Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Sorrentino, F., E-mail: marwan@df.unipi.i [Marwan Technology s.r.l., Spin-off University of Pisa Largo Pontecorvo 3, 56127 Pisa (Italy); Carelli, G.; Francesconi, F.; Francesconi, M.; Marsili, P. [Marwan Technology s.r.l., Spin-off University of Pisa Largo Pontecorvo 3, 56127 Pisa (Italy); Cristoforetti, G.; Legnaioli, S.; Palleschi, V.; Tognoni, E. [Applied Laser Spectroscopy Laboratory, IPCF/CNR - Via G.Moruzzi 1, 56124 Pisa (Italy)

    2009-10-15

    Results are reported on the application of double-pulse Laser-Induced Breakdown Spectroscopy (LIBS) for fast analysis of complex metallic alloys. The approach followed for the determination of the composition of the alloys is based on the time-integrated acquisition of LIBS spectra emitted by plasmas induced by collinear double-pulse laser excitation. The spectra are analysed using the Partial Least Squares method, which allows the determination of sample composition even in the presence of strong spectral interferences. The results shown indicate the possibility of measuring the composition of complex metallic alloys in very short times and using relatively cheap LIBS instrumentation.

  9. Advancements in time-resolved x-ray laser induced time-of-flight photoelectron spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, A J; Dunn, J; Widmann, K; Ao, T; Ping, Y; Hunter, J; Ng, A

    2005-07-28

    Time-resolved soft x-ray photoelectron spectroscopy is used to probe the non-steady-state evolution of the valence band electronic structure of laser heated ultra-thin (50 nm) metal foils and bulk semiconductors. Single-shot soft x-ray laser induced time-of-flight photoelectron spectroscopy with picosecond time resolution was used in combination with optical measurements of the disassembly dynamics that have shown the existence of a metastable liquid phase in fs-laser heated metal foils persisting 4-5 ps. This metastable phase is studied using a 527 nm wavelength 400 fs laser pulse containing 0.3-2.5 mJ laser energy focused in a large 500 x 700 {micro}m{sup 2} spot to create heated conditions of 0.2-1.8 x 10{sup 12} W cm{sup -2} intensity. The unique LLNL COMET compact tabletop soft x-ray laser source provided the necessary high photon flux, highly monoenergetic, picosecond pulse duration, and coherence for observing the evolution of changes in the valence band electronic structure of laser heated metals and semiconductors with picosecond time resolution. This work demonstrates the continuing development of a powerful new technique for probing reaction dynamics and changes of local order on surfaces on their fundamental timescales including phenomena such as non-thermal melting, chemical bond formation, intermediate reaction steps, and the existence of transient reaction products.

  10. Gamma-ray spectroscopy at MHz counting rates with a compact LaBr{sub 3} detector and silicon photomultipliers for fusion plasma applications

    Energy Technology Data Exchange (ETDEWEB)

    Nocente, M., E-mail: massimo.nocente@mib.infn.it [EUROfusion Consortium, JET, Culham Science Centre, Abingdon (United Kingdom); Dipartimento di Fisica, Università di Milano-Bicocca, Milano (Italy); Istituto di Fisica del Plasma “Piero Caldirola,” Milano (Italy); Rigamonti, D.; Croci, G.; Gorini, G. [Dipartimento di Fisica, Università di Milano-Bicocca, Milano (Italy); Istituto di Fisica del Plasma “Piero Caldirola,” Milano (Italy); Perseo, V. [Dipartimento di Fisica, Università di Milano-Bicocca, Milano (Italy); Tardocchi, M.; Cremona, A.; Muraro, A. [Istituto di Fisica del Plasma “Piero Caldirola,” Milano (Italy); Boltruczyk, G.; Broslawski, A.; Gosk, M.; Korolczuk, S.; Zychor, I. [Narodowe Centrum Badan Jadrowych (NCBJ), Otwock-Swierk (Poland); Kiptily, V. [Culham Centre for Fusion Energy, Culham (United Kingdom); Mazzocco, M.; Strano, E. [Dipartimento di Fisica, Istituto Nazionale di Fisica Nucleare, Padova (Italy); Collaboration: EUROfusion Consortium, JET, Culham Science Centre, Abingdon (United Kingdom)

    2016-11-15

    Gamma-ray spectroscopy measurements at MHz counting rates have been carried out, for the first time, with a compact spectrometer based on a LaBr{sub 3} scintillator and silicon photomultipliers. The instrument, which is also insensitive to magnetic fields, has been developed in view of the upgrade of the gamma-ray camera diagnostic for α particle measurements in deuterium-tritium plasmas of the Joint European Torus. Spectra were measured up to 2.9 MHz with a projected energy resolution of 3%-4% in the 3-5 MeV range, of interest for fast ion physics studies in fusion plasmas. The results reported here pave the way to first time measurements of the confined α particle profile in high power plasmas of the next deuterium-tritium campaign at the Joint European Torus.

  11. Gamma-ray spectroscopy at MHz counting rates with a compact LaBr3 detector and silicon photomultipliers for fusion plasma applications.

    Science.gov (United States)

    Nocente, M; Rigamonti, D; Perseo, V; Tardocchi, M; Boltruczyk, G; Broslawski, A; Cremona, A; Croci, G; Gosk, M; Kiptily, V; Korolczuk, S; Mazzocco, M; Muraro, A; Strano, E; Zychor, I; Gorini, G

    2016-11-01

    Gamma-ray spectroscopy measurements at MHz counting rates have been carried out, for the first time, with a compact spectrometer based on a LaBr3 scintillator and silicon photomultipliers. The instrument, which is also insensitive to magnetic fields, has been developed in view of the upgrade of the gamma-ray camera diagnostic for α particle measurements in deuterium-tritium plasmas of the Joint European Torus. Spectra were measured up to 2.9 MHz with a projected energy resolution of 3%-4% in the 3-5 MeV range, of interest for fast ion physics studies in fusion plasmas. The results reported here pave the way to first time measurements of the confined α particle profile in high power plasmas of the next deuterium-tritium campaign at the Joint European Torus.

  12. Gamma-ray spectroscopy at MHz counting rates with a compact LaBr3 detector and silicon photomultipliers for fusion plasma applications

    Science.gov (United States)

    Nocente, M.; Rigamonti, D.; Perseo, V.; Tardocchi, M.; Boltruczyk, G.; Broslawski, A.; Cremona, A.; Croci, G.; Gosk, M.; Kiptily, V.; Korolczuk, S.; Mazzocco, M.; Muraro, A.; Strano, E.; Zychor, I.; Gorini, G.

    2016-11-01

    Gamma-ray spectroscopy measurements at MHz counting rates have been carried out, for the first time, with a compact spectrometer based on a LaBr3 scintillator and silicon photomultipliers. The instrument, which is also insensitive to magnetic fields, has been developed in view of the upgrade of the gamma-ray camera diagnostic for α particle measurements in deuterium-tritium plasmas of the Joint European Torus. Spectra were measured up to 2.9 MHz with a projected energy resolution of 3%-4% in the 3-5 MeV range, of interest for fast ion physics studies in fusion plasmas. The results reported here pave the way to first time measurements of the confined α particle profile in high power plasmas of the next deuterium-tritium campaign at the Joint European Torus.

  13. Quantitation of a novel metalloporphyrin drug in plasma by atomic absorption spectroscopy.

    Science.gov (United States)

    Hoffman, K L; Feng, M R; Rossi, D T

    1999-03-01

    A bioanalytical method to quantify cobalt mesoporphyrin (CoMP), a novel therapeutic agent, in plasma has been developed and validated. The approach involves atomic absorption spectroscopy to determine total cobalt in a sample and a back-calculation of the amount of compound present. Endogenous plasma cobalt concentrations were small ( <0.2 ng/ml(-1) Co in rat plasma) in comparison to the quantitation limit (4.5 ng/ml(-1) Co). The inter-day imprecision of the method was 10.0% relative standard deviation (RSD) and the inter-day bias was +/- 8.0% relative error (RE) over a standard curve range of 4.5- 45.0 ng/ml(-1) Co. Because it quantifies total cobalt, the method cannot differentiate between parent drug and metabolites, but negligible metabolism allows reliable estimates of the actual parent drug concentration. A correlation study between the atomic absorption method and 14C-radiometry demonstrated excellent agreement (r = 0.9868, slope = 1.041 +/- 0.028, intercept = 223.7 +/- 190.0) and further substantiated the accuracy of the methods. Methodology was successfully applied to a pharmacokinetic study of CoMP in rat, with pharmacokinetic parameter estimation. The elimination half-lives, after intra-muscular and subcutaneous administration, were 7.7 and 8.8 days, respectively.

  14. Optical emission spectroscopy of the Linac4 and superconducting proton Linac plasma generators

    Energy Technology Data Exchange (ETDEWEB)

    Lettry, J.; Kronberger, M.; Mahner, E.; Schmitzer, C.; Sanchez, J.; Scrivens, R.; Midttun, O.; O' Neil, M.; Pereira, H.; Paoluzzi, M. [European Organization for Nuclear Research, CERN, 1211 Geneva 23 (Switzerland); Fantz, U.; Wuenderlich, D. [Max-Planck-Institut fuer Plasmaphysik, IPP, 85748 Garching (Germany); Kalvas, T.; Koivisto, H.; Komppula, J.; Myllyperkioe, P.; Tarvainen, O. [Department of Physics, University of Jyvaeskylae, 40500 Jyvaeskylae (Finland)

    2012-02-15

    CERN's superconducting proton Linac (SPL) study investigates a 50 Hz high-energy, high-power Linac for H{sup -} ions. The SPL plasma generator is an evolution of the DESY ion source plasma generator currently operated at CERN's Linac4 test stand. The plasma generator is a step towards a particle source for the SPL, it is designed to handle 100 kW peak RF-power at a 6% duty factor. While the acquisition of an integrated hydrogen plasma optical spectrum is straightforward, the measurement of a time-resolved spectrum requires dedicated amplification schemes. The experimental setup for visible light based on photomultipliers and narrow bandwidth filters and the UV spectrometer setup are described. The H{sub {alpha}}, H{sub {beta}}, and H{sub {gamma}} Balmer line intensities, the Lyman band and alpha transition were measured. A parametric study of the optical emission from the Linac4 ion source and the SPL plasma generator as a function of RF-power and gas pressure is presented. The potential of optical emission spectrometry coupled to RF-power coupling measurements for on-line monitoring of short RF heated hydrogen plasma pulses is discussed.

  15. X-ray imaging and imaging spectroscopy of fusion plasmas and light-source experiments with spherical optics and pixel array detectors

    Science.gov (United States)

    Hill, K. W.; Bitter, M.; Delgado-Aparicio, L.; Pablant, N. A.; Beiersdorfer, P.; Sanchez del Rio, M.; Zhang, L.

    2012-10-01

    High resolution (λ/Δλ ~10,000) 1D imaging x-ray spectroscopy using a spherically bent crystal and a 2D hybrid pixelarray detector (PAD) is used world wide for Doppler measurements of ion-temperature (Ti) and plasma flow-velocityprofiles in magnetic confinement fusion (MCF) plasmas. Meter sized plasmas are diagnosed with cm spatial resolution and 10 ms time resolution. This concept can also be used as a diagnostic of small sources, such as inertial confinement fusion (ICF) plasmas and targets on x-ray light source beam lines, with spatial resolution of microns. A new concept of using matched pairs of spherically bent crystals for monochromatic stigmatic 2D x-ray imaging of mm sized sources offers the possibility of spatial resolution of microns and large solid angle, relative to that achieved with pinhole imaging. Other potential applications of the 2D imaging schemes include x-ray lithography and x-ray microscopy for biological and materials science research. Measurements from MFE plasmas, as well as laboratory experiments and ray tracing computations validating the 1D imaging spectroscopy and 2D x-ray imaging techniques will be presented.

  16. Time-Resolved Spectroscopy of Active Binary Stars

    Science.gov (United States)

    Brown, Alexander

    2000-01-01

    This NASA grant covered EUVE observing and data analysis programs during EUVE Cycle 5 GO observing. The research involved a single Guest Observer project 97-EUVE-061 "Time-Resolved Spectroscopy of Active Binary Stars". The grant provided funding that covered 1.25 months of the PI's salary. The activities undertaken included observation planning and data analysis (both temporal and spectral). This project was awarded 910 ksec of observing time to study seven active binary stars, all but one of which were actually observed. Lambda-And was observed on 1997 Jul 30 - Aug 3 and Aug 7-14 for a total of 297 ksec; these observations showed two large complex flares that were analyzed by Osten & Brown (1999). AR Psc, observed for 350 ksec on 1997 Aug 27 - Sep 13, showed only relatively small flares that were also discussed by Osten & Brown (1999). EUVE observations of El Eri were obtained on 1994 August 24-28, simultaneous with ASCA X-ray spectra. Four flares were detected by EUVE with one of these also observed simultaneously, by ASCA. The other three EUVE observations were of the stars BY Dra (1997 Sep 22-28), V478 Lyr (1998 May 18-27), and sigma Gem (1998 Dec 10-22). The first two stars showed a few small flares. The sigma Gem data shows a beautiful complete flare with a factor of ten peak brightness compared to quiescence. The flare rise and almost all the decay phase are observed. Unfortunately no observations in other spectral regions were obtained for these stars. Analysis of the lambda-And and AR Psc observations is complete and the results were published in Osten & Brown (1999). Analysis of the BY Dra, V478 Lyr and sigma Gem EUVE data is complete and will be published in Osten (2000, in prep.). The El Eri EUV analysis is also completed and the simultaneous EUV/X-ray study will be published in Osten et al. (2000, in prep.). Both these latter papers will be submitted in summer 2000. All these results will form part of Rachel Osten's PhD thesis.

  17. Time- and space-resolved spectroscopic characterization of laser-induced swine muscle tissue plasma

    Energy Technology Data Exchange (ETDEWEB)

    Camacho, J.J. [Departamento de Química-Física Aplicada, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Diaz, L., E-mail: luis.diaz@csic.es [Instituto de Estructura de la Materia, CFMAC, CSIC, Serrano 121, 28006 Madrid (Spain); Martinez-Ramirez, S. [Instituto de Estructura de la Materia, CFMAC, CSIC, Serrano 121, 28006 Madrid (Spain); Caceres, J.O. [Departamento de Química Analítica, Facultad de Ciencias Químicas, Universidad Complutense, Cuidad Universitaria, 28040 Madrid (Spain)

    2015-09-01

    The spatial-temporal evolution of muscle tissue sample plasma induced by a high-power transversely excited atmospheric (TEA) CO{sub 2} pulsed laser at vacuum conditions (0.1–0.01 Pa) has been investigated using high-resolution optical emission spectroscopy (OES) and imaging methods. The induced plasma shows mainly electronically excited neutral Na, K, C, Mg, H, Ca, N and O atoms, ionized C{sup +}, C{sup 2+}, C{sup 3+}, Mg{sup +}, Mg{sup 2+}, N{sup +}, N{sup 2+}, Ca{sup +}, O{sup +} and O{sup 2+} species and molecular band systems of CN(B{sup 2}Σ{sup +}–X{sup 2}Σ{sup +}), C{sub 2}(d{sup 3}Π{sub g}–a{sup 3}Π{sub u}), CH(B{sup 2}Σ{sup −}–X{sup 2}Π; A{sup 2}Δ–X{sup 2}Π), NH(A{sup 3}Π–X{sup 3}Σ{sup −}), OH(A{sup 2}Σ{sup +}–X{sup 2} Σ{sup +}), and CaOH(B{sup 2}Σ{sup +}–X{sup 2}Σ{sup +}; A{sup 2}Π–X{sup 2}Σ{sup +}). Time-resolved two-dimensional emission spectroscopy is used to study the expanded distribution of different species ejected during ablation. Spatial and temporal variations of different atoms and ionic excited species are reported. Plasma parameters such as electron density and temperature were measured from the spatio-temporal analysis of different species. Average velocities of some plasma species were estimated. - Highlights: • LIBS of swine muscle tissue sample generated by CO{sub 2} laser pulses has been done for the first time. • Average velocities of some plasma species have been calculated from spatial and temporally resolved 2D OES images. • Electron density (~ 9 × 10{sup 17} cm{sup -3}) has been studied with spatial and temporal resolution. • Temporal evolution of the plasma temperature has been calculated by means of Boltzmann plots.

  18. Laser Optogalvanic Spectroscopy pf Neon and Argon in a Discharge Plasma and its Significance for Microgravity Combustion

    Science.gov (United States)

    Misra, Prabhakar; Haridass, C.; Major, H.

    1999-01-01

    A detailed study of combustion mechanisms in flames, employing laser-based diagnostics, has provided good knowledge and understanding of the physical phenomena, and led to better characterization of the dynamical and chemical combustion processes, both under low-gravity (in space) and normal gravity (in ground based facilities, e.g. drop towers). Laser induced fluorescence (LIF), laser-induced incandescence (LII) and LIF thermometry have been widely used to perform nonintrusive measurements and to better understand combustion phenomena. Laser optogalvanic (LOG) spectroscopy has well-established applications in ion mobility measurements, atomic and molecular spectroscopy, ionization rates, recombination rates, velocity measurements and as a combustion probe for trace element detection. Absorption spectra of atomic and molecular species in flames can be obtained via LOG spectroscopy by measuring the voltage and current changes induced by laser irradiation. There are different kinds of processes that contribute to a discharge current, namely: (1) electron impact ionization, (2) collisions among the excited atoms of the discharge species and (3) Penning ionization. In general, at higher discharge currents, the mechanism of electron impact ionization dominates over Penning ionization, whereby the latter is hardly noticeable. In a plasma, whenever the wavelength of a laser coincides with the absorption of an atomic or molecular species, the rate of ionization of the species momentarily increases or decreases due to laser-assisted acceleration of collisional ionization. Such a rate of change in the ionization is monitored as a variation in the transient current by inserting a high voltage electrode into the plasma. Optogalvanic spectroscopy in discharges has been useful for characterizing laser line-widths and for providing convenient calibration lines for tunable dye lasers in the ultraviolet, visible and infrared wavelength regions. Different kinds of quantitative

  19. Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hellman, Hal

    1968-01-01

    This booklet discusses spectroscopy, the study of absorption of radiation by matter, including X-ray, gamma-ray, microwave, mass spectroscopy, as well as others. Spectroscopy has produced more fundamental information to the study of the detailed structure of matter than any other tools.

  20. Investigations of the cathode region of an argon arc plasma by degenerate four-wave mixing laser spectroscopy and optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dzierzega, K [Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059 Cracow (Poland); Pokrzywka, B [Mt. Suhora Observatory, Cracow Pedagogical University, ul. Podchorazych 2, 30-083 Cracow (Poland); Pellerin, S [LASEP, Universite d' Orleans-Centre Universitaire de Bourges, Rue Gaston Berger BP 4043, 18028 Bourges (France)

    2004-07-07

    Degenerate four-wave mixing (DFWM) laser spectroscopy was used in local studies of atmospheric pressure argon plasma generated in a free-burning arc. The results of plasma diagnostics using the DFWM method were compared to the results obtained with optical emission measurements. In the cathode region of the arc the maxima of both the DFWM signal and the emission coefficient for the 696.5 nm Ar I line depend on the distance from the cathode tip. This effect proves the departure of the plasma state from local thermal equilibrium (LTE) as it has been reported by many authors. On the other hand the Stark shifts of the 696.5 nm Ar I line determined by the DFWM method in relation to plasma diagnostic results show no deviations from LTE on the arc axis down to 1.0 mm from the cathode tip.

  1. Quantitative plasma spectroscopy in a resistive shell reversed-field pinch

    Energy Technology Data Exchange (ETDEWEB)

    Hedqvist, Anders

    1999-10-01

    The subject addressed in this thesis is quantitative plasma spectroscopy. Measurements of electron temperature and impurity ion density, performed at EXTRAP-T2, are aimed to investigate the effects of operating a reversed- field pinch with a resistive shell and a graphite wall. The spectroscopic measurements are analyzed with a collisional-radiative model and a consistency check is performed for the measurements and the model itself. The resistive shell results in wall-locked modes, enhanced plasma-wall interaction and degraded confinement. Measurements of vacuum ultraviolet resonant transitions of carbon and oxygen show that the local heating of the wall, at the position of the locking, leads to influxes of hydrogen and impurities, resulting in a cold and resistive plasma. Effects on the local scale are also observed. Spatially-resolved measurements of line emission originating from charge exchange collisions are used to investigate the change in neutral hydrogen profile. Temporal correlations between soft x-ray emission and poloidal loop voltage at the position of the wall-locked modes are observed and in connection, a decrease in central electron temperature, indicating there is a direct energy loss channel between the center and the edge. The hydrogen recycling properties of the graphite wall are investigated in an isotope exchange experiment. The density of the hydrogen isotopes are measured from spectral line emission and compared with recycling models. In charge exchange collisions between fully stripped chlorine and thermal deuterium, observed in JET plasmas, only a single n-level is populated. This is different from most ions and may be used to test models for calculating charge exchange collision cross-sections.

  2. Characterization of Modified Tapioca Starch in Atmospheric Argon Plasma under Diverse Humidity by FTIR Spectroscopy

    Science.gov (United States)

    Deeyai, P.; Suphantharika, M.; Wongsagonsup, R.; Dangtip, S.

    2013-01-01

    Tapioca is economical crop grown in Thailand and continues to be one of the major sources of starch. Nowadays, tapioca starch has been widely used in industrial applications, however the native form of starch has limited the applications. Thus scientists try to modify the properties of starch for increasing the stability of the granules, pastes to low pH, heat, and shear during the food process. We modify the tapioca starch by plasma treatment under an argon atmosphere. The degree of modification is determined by following water content in the starch granules. The tablet samples of native starch are also prepared and compared with the plasma treated starch. Before plasma treatment, the starch tablets are stored under three different relative humilities (RH) including 11%, 68%, and 78%RH, respectively. The samples are characterized using FTIR spectroscopy associated with the degree of cross-linking. The results show that the water molecules are engulfed into the starch structure in two ways, a tight bond and a weak absorption of water molecules which is represented at two wave number of 1630 cm-1 and 3272 cm-1, respectively. The degree of cross-linking can be identified from the relative intensity of these two peaks with the C—O—H peak at 993 cm-1. The results show that the degree of cross-linking increase in the plasma treated starch. The degree of cross-linking of the treated starch with high relative humidity is less than that of the treated starch with low relative humidity.

  3. Time domain PD-detection vs. dielectric spectroscopy

    DEFF Research Database (Denmark)

    Holbøll, Joachim T.; Edin, Hans; Gäfvert, Uno

    1997-01-01

    A theoretically developed relationship between partial discharges and the response from a system for dielectric spectroscopy was experimentally confirmed. The losses caused by the discharges were highest at test voltages with low frequencies. At 0.1 Hz, tanδ tip-up at discharge inception was very...

  4. Monitoring Temperature in High Enthalpy Arc-heated Plasma Flows using Tunable Diode Laser Absorption Spectroscopy

    Science.gov (United States)

    Martin, Marcel Nations; Chang, Leyen S.; Jeffries, Jay B.; Hanson, Ronald K.; Nawaz, Anuscheh; Taunk, Jaswinder S.; Driver, David M.; Raiche, George

    2013-01-01

    A tunable diode laser sensor was designed for in situ monitoring of temperature in the arc heater of the NASA Ames IHF arcjet facility (60 MW). An external cavity diode laser was used to generate light at 777.2 nm and laser absorption used to monitor the population of electronically excited oxygen atoms in an air plasma flow. Under the assumption of thermochemical equilibrium, time-resolved temperature measurements were obtained on four lines-of-sight, which enabled evaluation of the temperature uniformity in the plasma column for different arcjet operating conditions.

  5. Detection of rhodopsin dimerization in situ by PIE-FCCS, a time-resolved fluorescence spectroscopy.

    Science.gov (United States)

    Smith, Adam W

    2015-01-01

    Rhodopsin self-associates in the plasma membrane. At low concentrations, the interactions are consistent with a monomer-dimer equilibrium (Comar et al., J Am Chem Soc 136(23):8342-8349, 2014). At high concentrations in native tissue, higher-order clusters have been observed (Fotiadis et al., Nature 421:127-128, 2003). The physiological role of rhodopsin dimerization is still being investigated, but it is clear that a quantitative assessment is essential to determining the function of rhodopsin clusters in vision. To quantify rhodopsin interactions, I will outline the theory and methodology of a specialized time-resolved fluorescence spectroscopy for measuring membrane protein-protein interactions called pulsed-interleaved excitation fluorescence cross-correlation spectroscopy (PIE-FCCS). The strength of this technique is its ability to quantify rhodopsin interactions in situ (i.e., a live cell plasma membrane). There are two reasons for restricting the scope to live cell membranes. First, the compositional heterogeneity of the plasma membrane creates a complex milieu with thousands of lipid, protein, and carbohydrate species. This makes it difficult to infer quaternary interactions from detergent solubilized samples or construct a model phospholipid bilayer that recapitulates all of the interactions present in native membranes. Second, organizational structure and dynamics is a key feature of the plasma membrane, and fixation techniques like formaldehyde cross-linking and vitrification will modulate the interactions. PIE-FCCS is based on two-color fluorescence imaging with time-correlated single-photon counting (TCSPC) (Becker et al., Rev Sci Instrum 70:1835-1841, 1999). By time-tagging every detected photon, the data can be analyzed as a fluorescence intensity distribution, fluorescence lifetime histogram, or fluorescence (cross-)correlation spectra (FCS/FCCS) (Becker, Advanced time-correlated single-photon counting techniques, Springer, Berlin, 2005). These

  6. Inductively coupled plasma optical emission spectroscopy determination of trace element composition of argan oil.

    Science.gov (United States)

    Gonzálvez, A; Ghanjaoui, M E; El Rhazi, M; de la Guardia, M

    2010-02-01

    A methodology based on inductively coupled plasma optical emission spectroscopy (ICP-OES) after microwave assisted acid digestion has been developed to determine the trace element content of Moroccan argan oil. Limit of detection values equal or lower than few mg/kg were obtained for all elements under study. To assure the accuracy of the whole procedure, recovery studies were carried out on argan oil samples spiked at different concentration levels from 10 to 200 µg/L. Quantitative average recovery values were obtained for all elements evaluated, demonstrating the suitability of this methodology for the determination of trace elements in argan oil samples. Aluminum, calcium, chromium, iron, potassium, lithium, magnesium, sodium, vanadium and zinc were quantitatively determined in Moroccan argan oils being found that their concentration is different of that found in other edible oils thus offering a way for authentication and for the evaluation of possible adulterations.

  7. Spatially resolved optical-emission spectroscopy of a radio-frequency driven iodine plasma source

    Science.gov (United States)

    Dedrick, James; Doyle, Scott; Grondein, Pascaline; Aanesland, Ane

    2016-09-01

    Iodine is of interest for potential use as a propellant for spacecraft propulsion, and has become attractive as a replacement to xenon due to its similar mass and ionisation potential. Optical emission spectroscopy has been undertaken to characterise the emission from a low-pressure, radio-frequency driven inductively coupled plasma source operating in iodine with respect to axial distance across its transverse magnetic filter. The results are compared with axial profiles of the electron temperature and density for identical source conditions, and the spatial distribution of the emission intensity is observed to be closely correlated with the electron temperature. This work has been done within the LABEX Plas@Par project, and received financial state aid managed by the ``Agence Nationale de la Recherche'', as part of the ``Programme d'Investissements d'Avenir'' under the reference ANR-11-IDEX-0004-02.

  8. A Movable Mass Spectroscopy Sampling Apparatus for Measuring Spatial Distribution of Neutral Radicals in Silane Plasma

    Institute of Scientific and Technical Information of China (English)

    WANG Zhao-Kui; LIN Kui-Xun; LIN Xuan-Ying; QIU Gui-Ming; ZHU Zu-Song

    2005-01-01

    @@ A movable mass spectroscopy gas sampling apparatus has been established and a straight-line fit ofsilane depletion fraction f is proposed.The spatial density distributions of SiHn (n = 0-3) radicals in silane radio frequency glow discharge have been measured by a mass spectrometer.The experimental results demonstrate that the densities of the neutral radicals have the peak value near the middle position of electrodes, and the densities of SiH2 and SiHs are higher than those of Si and SiH in silane plasma.This reveals that SiH2 and SiH3 may be the primary precursors in forming the a-Si:H film.

  9. Characterisation of laser-produced tungsten plasma using optical spectroscopy method

    Science.gov (United States)

    Kubkowska, M.; Gasior, P.; Rosinski, M.; Wolowski, J.; Sadowski, M. J.; Malinowski, K.; Skladnik-Sadowska, E.

    2009-08-01

    This paper describes results of spectroscopic investigation of laser-produced tungsten plasma. The laser intensity on the target surface reached up to 30 GW/cm2 depending on the focusing conditions. Optical spectra emitted from plasma plumes which were formed under vacuum conditions in front of the tungsten target due to the interaction of Nd-YAG laser pulses (1.06 μm, 0.5 J), were characterised by means of an optical spectrometer (λ/Δλ= 900) in the wavelength range from 300 to 1100 nm. The spectra were recorded automatically with the use of a CCD detector with exposition time varied from 100 ns to 50 ms. On the basis of WI and WII lines it was possible to estimate electron temperature and electron density which corresponded to the expansion phase of the plasma. Te and Ne were measured as 1.1 eV and 8×1016 cm-3, respectively. The spectra collected by the ion energy analyser showed that the plasma included tungsten ions up to 6+ ion charge. Signals from the ion collector allowed to estimate the average value of ion energy of tungsten as 4.6 keV. Basing on this value the electron temperature corresponding to the initial stage of the plasma formation was estimated to be about 320 eV. Optical microscope investigation showed that laser irradiation caused structural changes on the surface of the target.

  10. Stark Broadening Analysis Using Optical Spectroscopy of the Dense Plasma Focus

    Science.gov (United States)

    Ross, Patrick; Bennett, Nikki; Dutra, Eric; Hagen, E. Chris; Hsu, Scott; Hunt, Gene; Koch, Jeff; Waltman, Tom; NSTec DPF Team

    2015-11-01

    To aid in validating numerical modeling of MA-class dense plasma focus (DPF) devices, spectroscopic measurements of the Gemini Dense Plasma Focus (DPF) were performed using deuterium and deuterium/dopant (argon/krypton) gas. The spectroscopic measurements were made using a fiber-coupled spectrometer and streak camera. Stark line-broadening analysis was applied to the deuterium beta emission (486 nm) in the region near the breakdown of the plasma and during the run-down and run-in phases of the plasma evolution. Densities in the range of 1e17 to low 1e18 cm-3 were obtained. These values are in agreement with models of the DPF performed using the LSP code. The spectra also show a rise and fall with time, indicative of the plasma sheath passing by the view port. Impurity features were also identified in the spectra which grew in intensity as the gas inside the DPF was discharged repeatedly without cycling. Implications of this impurity increase for D-T discharges (without fresh gas fills between every discharge) will be discussed. This work was done by National Security Technologies, LLC, under Contract No. DE-AC52-06NA25946, and by Los Alamos National Laboratory, under Contract no. DE-AC52-06NA25396 with the U.S. Department of Energy. DOE/NV/25946-2515.

  11. Analysis of Al and Fe transport coefficients in LHD core plasmas based on space-resolved EUV spectroscopy

    Science.gov (United States)

    Huang, Xianli; Morita, Shigeru; Oishi, Tetsutarou; Murakami, Izumi; Goto, Motoshi; Zhang, Hongming; Liu, Yang

    2016-10-01

    With impurity pellet injection and a one-dimensional transport code, the transport of Al and Fe ions has been analyzed in the Large Helical Device (LHD) based on extreme ultraviolet (EUV) space-resolved spectroscopy. The total density of Fe ions in the plasma core has been analyzed from the radial profiles of the Fe n =3-2 Lα emissions. When the ne profile is peaked or hollow, the Fe density also exhibits a peaked or hollow profile, respectively. Fe transport analysis shows that the convective velocity (V) is outward in the plasma core and inward near the edge when the ne profile is hollow. On the other hand, the V takes negative value over the whole radial range in the peaked ne profile. Therefore, the different Fe density profiles between peaked and hollow ne profiles can be explained by the significant difference in the V profile. Comparison of the transport coefficients between Al and Fe shows the magnitude of V for Al ions seems to be smaller than that for Fe ions while the difference in the diffusion coefficient profile is not significant. The difference in the decay time of line emissions between the two speices is attributed to the weaker convection for the Al.

  12. X-ray spectroscopic characterization of laser produced hot dense plasmas; Caracterisation par spectroscopie X de plasmas chauds et denses crees par lasers de puissance

    Energy Technology Data Exchange (ETDEWEB)

    Kontogiannopoulos, N

    2007-12-15

    In this work we performed experiments of emission and absorption spectroscopy of laser produced plasmas, to provide well characterized spectral data which permit to benchmark atomic physics codes. More precisely, we produced xenon and krypton plasmas in NLTE (non local thermodynamic equilibrium) conditions and studied their emission spectra. In a second experiment, we characterized the absorption spectra of zinc sulfide and aluminium plasmas in LTE (local thermodynamic equilibrium) conditions.The first two chapters give an outline of the theory involved in the study of the emission and absorption plasma spectroscopy. Chapter 1 describes the different atomic processes occurring in a plasma. The LTE and the NLTE statistics ruling the equilibrium of the atomic processes are presented. Then, we give a brief description of the different codes of plasma atomic physics used in the analysis of our experimental data, namely HULLAC, SCO and TRANSPEC/AVERROES. In Chapter 2 the macroscopic theory of the radiation transport through a plasma is given. We describe also the self-similar model of Basko and the view factor approach, which permits us to calculate the heating conditions of the absorption foils achieved in the interior of the spherical gold cavity. Chapter 3 gives a description of the instruments used for realizing the two experiments, as well as the technical characteristics of the LULI2000 laser facility used to perform the experiments. Chapter 4 presents the experiment realized to characterize the emission spectra of the xenon and krypton plasmas in NLTE, as well the analysis of the experimental data with TRANSPEC/AVERROES. Finally, the experiment for measuring the absorption spectrum of the ZnS plasma mixture and the analysis of the experimental data with the code SCO are given in Chapter 5.

  13. Real time optical Biopsy: Time-resolved Fluorescence Spectroscopy instrumentation and validation

    Science.gov (United States)

    Kittle, David S.; Vasefi, Fartash; Patil, Chirag G.; Mamelak, Adam; Black, Keith L.; Butte, Pramod V.

    2016-12-01

    The Time-resolved fluorescence spectroscopy (TR-FS) has the potential to differentiate tumor and normal tissue in real time during surgical excision. In this manuscript, we describe the design of a novel TR-FS device, along with preliminary data on detection accuracy for fluorophores in a mixture. The instrument is capable of near real-time fluorescence lifetime acquisition in multiple spectral bands and analysis. It is also able to recover fluorescence lifetime with sub-20ps accuracy as validated with individual organic fluorescence dyes and dye mixtures yielding lifetime values for standard fluorescence dyes that closely match with published data. We also show that TR-FS is able to quantify the relative concentration of fluorescence dyes in a mixture by the unmixing of lifetime decays. We show that the TR-FS prototype is able to identify in near-real time the concentrations of dyes in a complex mixture based on previously trained data. As a result, we demonstrate that in complex mixtures of fluorophores, the relative concentration information is encoded in the fluorescence lifetime across multiple spectral bands. We show for the first time the temporal and spectral measurements of a mixture of fluorochromes and the ability to differentiate relative concentrations of each fluorochrome mixture in real time.

  14. Fuji apple storage time rapid determination method using Vis/NIR spectroscopy.

    Science.gov (United States)

    Liu, Fuqi; Tang, Xuxiang

    2015-01-01

    Fuji apple storage time rapid determination method using visible/near-infrared (Vis/NIR) spectroscopy was studied in this paper. Vis/NIR diffuse reflection spectroscopy responses to samples were measured for 6 days. Spectroscopy data were processed by stochastic resonance (SR). Principal component analysis (PCA) was utilized to analyze original spectroscopy data and SNR eigen value. Results demonstrated that PCA could not totally discriminate Fuji apples using original spectroscopy data. Signal-to-noise ratio (SNR) spectrum clearly classified all apple samples. PCA using SNR spectrum successfully discriminated apple samples. Therefore, Vis/NIR spectroscopy was effective for Fuji apple storage time rapid discrimination. The proposed method is also promising in condition safety control and management for food and environmental laboratories.

  15. Fuji apple storage time rapid determination method using Vis/NIR spectroscopy

    Science.gov (United States)

    Liu, Fuqi; Tang, Xuxiang

    2015-01-01

    Fuji apple storage time rapid determination method using visible/near-infrared (Vis/NIR) spectroscopy was studied in this paper. Vis/NIR diffuse reflection spectroscopy responses to samples were measured for 6 days. Spectroscopy data were processed by stochastic resonance (SR). Principal component analysis (PCA) was utilized to analyze original spectroscopy data and SNR eigen value. Results demonstrated that PCA could not totally discriminate Fuji apples using original spectroscopy data. Signal-to-noise ratio (SNR) spectrum clearly classified all apple samples. PCA using SNR spectrum successfully discriminated apple samples. Therefore, Vis/NIR spectroscopy was effective for Fuji apple storage time rapid discrimination. The proposed method is also promising in condition safety control and management for food and environmental laboratories. PMID:25874818

  16. Calculation of the spatial resolution in two-photon absorption spectroscopy applied to plasma diagnosis

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Lechuga, M. [Departamento de Física Teórica, Atómica y Óptica, Universidad de Valladolid, 47011-Valladolid (Spain); Laser Processing Group, Instituto de Óptica “Daza de Valdés,” CSIC, 28006-Madrid (Spain); Fuentes, L. M. [Departamento de Física Aplicada, Universidad de Valladolid, 47011-Valladolid (Spain); Grützmacher, K.; Pérez, C., E-mail: concha@opt.uva.es; Rosa, M. I. de la [Departamento de Física Teórica, Atómica y Óptica, Universidad de Valladolid, 47011-Valladolid (Spain)

    2014-10-07

    We report a detailed characterization of the spatial resolution provided by two-photon absorption spectroscopy suited for plasma diagnosis via the 1S-2S transition of atomic hydrogen for optogalvanic detection and laser induced fluorescence (LIF). A precise knowledge of the spatial resolution is crucial for a correct interpretation of measurements, if the plasma parameters to be analysed undergo strong spatial variations. The present study is based on a novel approach which provides a reliable and realistic determination of the spatial resolution. Measured irradiance distribution of laser beam waists in the overlap volume, provided by a high resolution UV camera, are employed to resolve coupled rate equations accounting for two-photon excitation, fluorescence decay and ionization. The resulting three-dimensional yield distributions reveal in detail the spatial resolution for optogalvanic and LIF detection and related saturation due to depletion. Two-photon absorption profiles broader than the Fourier transform-limited laser bandwidth are also incorporated in the calculations. The approach allows an accurate analysis of the spatial resolution present in recent and future measurements.

  17. K-shell spectroscopy in hot plasmas: Stark effect, Breit interaction and QED corrections

    CERN Document Server

    Pain, Jean-Christophe; Comet, Maxime; Gilles, Dominique

    2016-01-01

    The broadening of lines by Stark effect is widely used for inferring electron density and temperature in plasmas. Stark-effect calculations often rely on atomic data (transition rates, energy levels,...) not always exhaustive and/or valid only for isolated atoms. In this work, we first present a recent development in the detailed opacity code SCO-RCG for K-shell spectroscopy. The approach is adapted from the work of Gilles and Peyrusse. Neglecting non-diagonal terms in dipolar and collision operators, the line profile is expressed as a sum of Voigt functions associated to the Stark components. The formalism relies on the use of parabolic coordinates and the relativistic fine-structure of Lyman lines is included by diagonalizing the hamiltonian matrix associated to quantum states having the same principal quantum number n. The SCO-RCG code enables one to investigate plasma environment effects, the impact of the microfield distribution, the decoupling between electron and ion temperatures and the role of satell...

  18. Real-Time Probing of Electron Dynamics Using Attosecond Time-Resolved Spectroscopy

    Science.gov (United States)

    Ramasesha, Krupa; Leone, Stephen R.; Neumark, Daniel M.

    2016-05-01

    Attosecond science has paved the way for direct probing of electron dynamics in gases and solids. This review provides an overview of recent attosecond measurements, focusing on the wealth of knowledge obtained by the application of isolated attosecond pulses in studying dynamics in gases and solid-state systems. Attosecond photoelectron and photoion measurements in atoms reveal strong-field tunneling ionization and a delay in the photoemission from different electronic states. These measurements applied to molecules have shed light on ultrafast intramolecular charge migration. Similar approaches are used to understand photoemission processes from core and delocalized electronic states in metal surfaces. Attosecond transient absorption spectroscopy is used to follow the real-time motion of valence electrons and to measure the lifetimes of autoionizing channels in atoms. In solids, it provides the first measurements of bulk electron dynamics, revealing important phenomena such as the timescales governing the switching from an insulator to a metallic state and carrier-carrier interactions.

  19. Determining the Concentrations and Temperatures of Products in a CF_4/CHF_3/N_2 Plasma via Submillimeter Absorption Spectroscopy

    Science.gov (United States)

    Helal, Yaser H.; Neese, Christopher F.; De Lucia, Frank C.; Ewing, Paul R.; Agarwal, Ankur; Craver, Barry; Stout, Phillip J.; Armacost, Michael D.

    2017-06-01

    Plasmas used for the manufacturing of semiconductor devices are similar in pressure and temperature to those used in the laboratory for the study of astrophysical species in the submillimeter (SMM) spectral region. The methods and technology developed in the SMM for these laboratory studies are directly applicable for diagnostic measurements in the semiconductor manufacturing industry. Many of the molecular neutrals, radicals, and ions present in processing plasmas have been studied and their spectra have been cataloged or are in the literature. In this work, a continuous wave, intensity calibrated SMM absorption spectrometer was developed as a remote sensor of gas and plasma species. A major advantage of intensity calibrated rotational absorption spectroscopy is its ability to determine absolute concentrations and temperatures of plasma species from first principles without altering the plasma environment. An important part of this work was the design of the optical components which couple 500-750 GHz radiation through a commercial inductively coupled plasma chamber. The measurement of transmission spectra was simultaneously fit for background and absorption signal. The measured absorption was used to calculate absolute densities and temperatures of polar species. Measurements for CHF_3, CF_2, FCN, HCN, and CN made in a CF_4/CHF_3/N_2 plasma will be presented. Temperature equilibrium among species will be shown and the common temperature is leveraged to obtain accurate density measurements for simultaneously observed species. The densities and temperatures of plasma species are studied as a function of plasma parameters, including flow rate, pressure, and discharge power.

  20. Preliminary design of laser-induced breakdown spectroscopy for proto-Material Plasma Exposure eXperiment.

    Science.gov (United States)

    Shaw, G; Martin, M Z; Martin, R; Biewer, T M

    2014-11-01

    Laser-induced breakdown spectroscopy (LIBS) is a technique for measuring surface matter composition. LIBS is performed by focusing laser radiation onto a target surface, ablating the surface, forming a plasma, and analyzing the light produced. LIBS surface analysis is a possible diagnostic for characterizing plasma-facing materials in ITER. Oak Ridge National Laboratory has enabled the initial installation of a laser-induced breakdown spectroscopy diagnostic on the prototype Material-Plasma Exposure eXperiment (Proto-MPEX), which strives to mimic the conditions found at the surface of the ITER divertor. This paper will discuss the LIBS implementation on Proto-MPEX, preliminary design of the fiber optic LIBS collection probe, and the expected results.

  1. Standoff Time-Resolved Laser-Based Spectroscopy Tools for Sample Characterization and Biosignature Detection

    Science.gov (United States)

    Gasda, P. J.; Acosta-Maeda, T.; Lucey, P. G.; Misra, A. K.; Sharma, S. K.; Taylor, J.

    2014-12-01

    The NASA Mars2020 rover will be searching for signs of past habitability and past life on Mars. Additionally, the rover mission will prepare a cache of highly significant samples for a future sample return mission. NASA requires these samples to be well characterized; the instruments on the rover must be capable of fine-scale in situ mineralogical or elemental analysis with emphasis on biosignature detection or characterization. We have been developing multiple standoff laser-based instruments at the University of Hawaii, Manoa that are capable of fine-scale in situ chemical analysis and biosignatures detection. By employing a time-resolved spectroscopy, we can perform elemental analysis with Laser-Induced Breakdown Spectroscopy (LIBS), mineral and organic analysis with Raman spectroscopy, and biosignature detection with Laser-Induced Fluorescence (LIF). Each of these techniques share the same optics and detection equipment, allowing us to integrate them into a single, compact instrument. High time-resolution (~100 ns/pulse) is the key to this instrument; with it, the detector only records data when the signal is the brightest. Spectra can be taken during the day, LIBS can be measured without a plasma light background, and the Raman signal can be separated from the mineral fluorescence signal. Since bio-organics have very short fluorescence lifetimes, the new instrument can be used to unambiguously detect bio-organics. The prototype uses a low power (0.5 mJ/pulse) 532 nm laser with a detection limit of laser spot and a camera to produce LIF images of wide area (25 cm area from 2 m distance with 2 mm/pixel resolution). The Biofinder can quickly assess the area around the rover (at 10 frames/s) by imaging sample cores, drill holes, or outcrops, and then allow the slower but more precise instruments on the rover to characterize the regions of interest. Either of these prototypes would be ideally suited for future NASA missions, including human exploration missions

  2. TIME-RESOLVED INFRARED SPECTROSCOPY IN THE U121R BEAMLINE AT THE NSLS

    Energy Technology Data Exchange (ETDEWEB)

    CARR,G.L.; LAVEIGNE,J.D.; LOBO,R.P.S.M.; REITZE,D.H.; TANNER,D.B.

    1999-07-19

    A facility for performing time-resolved infrared spectroscopy has been developed at the NSLS, primarily at beamline U12IR. The pulsed IR light from the synchrotron is used to perform pump-probe spectroscopy. The authors present here a description of the facility and results for the relaxation of photoexcitations in both a semiconductor and superconductor.

  3. Quantitative terahertz time-domain spectroscopy and analysis in chemistry and biology

    DEFF Research Database (Denmark)

    Jepsen, Peter Uhd

    2005-01-01

    I will describe how Terahertz Time-Domain Spectroscopy (THz-TDS) can be used for quantitative, broadband spectroscopy in the far-infrared spectral region. Thz-TDS is sensitive to long-range, non-covalent interactions in the condensed phase, for instance intermolecular hydrogen bonding in molecular...

  4. Applications of time-resolved terahertz spectroscopy in ultrafast carrier dynamics

    Institute of Scientific and Technical Information of China (English)

    Qingli Zhou; Xicheng Zhang

    2011-01-01

    1.Introduction Terahertz time-domain spectroscopy (THz-TDS)[1-3]is a powerful and coherent free-space technique in which nearly single-cycle electromagnetic pulse is generated and detected using femtosecond optical pulses.THz-TDS has been utilized as one of the important methods for material characterization in the past two decades.Because transmission or reflection of THz waves is sensitive to carrier density and mobility,an ultrafast THz-TDS system is required to provide time-resolved capability of material characterization in the THz region[4-6].In the past decade,one of the widely used time-resolved THz spectroscopy methods is optical-pump/THz probe (O/T)spectroscopy[3].%Three time-resolved terahertz (THz) spectroscopy methods (optical-pump/THz-probe spectroscopy, THz-pump/THz-probe spectroscopy, and THz-pump/optical-probe spectroscopy) are reviewed. These are used to characterize ultrafast dynamics in photo- or THz-excited semiconductors, superconductors, nanomateri-als, and other materials. In particular, the optical-pump/THz-probe spectroscopy is utilized to investigate carrier dynamics and the related intervalley scattering phenomena in semiconductors. The recent development of intense pulsed THz sources is expected to affect the research in nonlinear THz responses of various materials.

  5. Time-Resolved Spectroscopy Diagnostic of Laser-Induced Optical Breakdown

    OpenAIRE

    Parigger, Christian G.; Hornkohl, James O.; László Nemes

    2010-01-01

    Transient laser plasma is generated in laser-induced optical breakdown (LIOB). Here we report experiments conducted with 10.6-micron CO2 laser radiation, and with 1.064-micron fundamental, 0.532-micron frequency-doubled, 0.355-micron frequency-tripled Nd:YAG laser radiation. Characterization of laser induced plasma utilizes laser-induced breakdown spectroscopy (LIBS) techniques. Atomic hydrogen Balmer series emissions show electron number density of 1017 cm−3 measured approximately 10 μs and ...

  6. Time-resolved Spectroscopy of Active Binary Stars

    Science.gov (United States)

    Brown, Alexander

    EUVE has provided the first stellar coronal spectra showing individual emission lines, thereby allowing coronal modelling at a level of sophistication previously unattainable. Long EUVE observations have shown the prevalence of large-scale flaring in the coronae of active binary stars. We propose to obtain EUVE DSS spectra and photometry for 8 active binaries, four of which have never been observed by EUVE (EI Eri, AR Psc, V478 Lyr, BY Dra) and four EUV-bright systems that merit reobservation (Sigma CrB, Sigma Gem, Xi UMa, Lambda And). We shall use these observations to derive high quality quiescent coronal spectra for modelling, and to obtain new flare data. We shall try to coordinate these observations with ground-based radio observations and other spacecraft, if the scheduling allows. The proposed observations will significantly increase the available EUVE spectroscopy of active binaries.

  7. A cavity ring-down spectroscopy sensor for real-time Hall thruster erosion measurements

    Energy Technology Data Exchange (ETDEWEB)

    Lee, B. C. [Physics Department, Colorado State University, Fort Collins, Colorado 80521 (United States); Huang, W. [NASA Glenn Research Center, 2100 Brookpark Rd., Cleveland, Ohio 44135 (United States); Tao, L.; Yamamoto, N.; Yalin, A. P., E-mail: ayalin@engr.colostate.edu [Mechanical Engineering Department, Colorado State University, Fort Collins, Colorado 80521 (United States); Gallimore, A. D. [Aerospace Engineering Department, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2014-05-15

    A continuous-wave cavity ring-down spectroscopy sensor for real-time measurements of sputtered boron from Hall thrusters has been developed. The sensor uses a continuous-wave frequency-quadrupled diode laser at 250 nm to probe ground state atomic boron sputtered from the boron nitride insulating channel. Validation results from a controlled setup using an ion beam and target showed good agreement with a simple finite-element model. Application of the sensor for measurements of two Hall thrusters, the H6 and SPT-70, is described. The H6 was tested at power levels ranging from 1.5 to 10 kW. Peak boron densities of 10 ± 2 × 10{sup 14} m{sup −3} were measured in the thruster plume, and the estimated eroded channel volume agreed within a factor of 2 of profilometry. The SPT-70 was tested at 600 and 660 W, yielding peak boron densities of 7.2 ± 1.1 × 10{sup 14} m{sup −3}, and the estimated erosion rate agreed within ∼20% of profilometry. Technical challenges associated with operating a high-finesse cavity in the presence of energetic plasma are also discussed.

  8. Time-domain Bayesian detection and estimation of noisy damped sinusoidal signals applied to NMR spectroscopy.

    Science.gov (United States)

    Rubtsov, Denis V; Griffin, Julian L

    2007-10-01

    The problem of model detection and parameter estimation for noisy signals arises in different areas of science and engineering including audio processing, seismology, electrical engineering, and NMR spectroscopy. We have adopted the Bayesian modeling framework to jointly detect and estimate signal resonances. This considers a model of the time-domain complex free induction decay (FID) signal as a sum of exponentially damped sinusoidal components. The number of model components and component parameters are considered unknown random variables to be estimated. A Reversible Jump Markov Chain Monte Carlo technique is used to draw samples from the joint posterior distribution on the subspaces of different dimensions. The proposed algorithm has been tested on synthetic data, the (1)H NMR FID of a standard of L-glutamic acid and a blood plasma sample. The detection and estimation performance is compared with Akaike information criterion (AIC), minimum description length (MDL) and the matrix pencil method. The results show the Bayesian algorithm superior in performance especially in difficult cases of detecting low-amplitude and strongly overlapping resonances in noisy signals.

  9. On the determination of plasma electron number density from Stark broadened hydrogen Balmer series lines in Laser-Induced Breakdown Spectroscopy experiments

    Energy Technology Data Exchange (ETDEWEB)

    Pardini, L., E-mail: loren.pard@gmail.com [Istituto di Chimica dei Composti Organometallici del CNR, Area della Ricerca del CNR di Pisa, Via G. Moruzzi 1, 56124 Pisa (Italy); Legnaioli, S.; Lorenzetti, G.; Palleschi, V. [Istituto di Chimica dei Composti Organometallici del CNR, Area della Ricerca del CNR di Pisa, Via G. Moruzzi 1, 56124 Pisa (Italy); Gaudiuso, R.; De Giacomo, A. [Dipartimento di Chimica, Università di Bari, Via Orabona 4, 70126 Bari (Italy); Diaz Pace, D.M. [Instituto de Física ‘Arroyo Seco’, Facultad de Ciencias Exactas, Paraje Arroyo Seco, B7000GHG Tandil (Argentina); Anabitarte Garcia, F. [Photonic Engineering Group, Universidad de Cantabria, Edificio I+D+iTelecomunicación, Dpto. TEISA, 39005 Santander (Spain); Holanda Cavalcanti, G. de [Institute of Physics, Universidade Federal Fluminense, UFF, Campus da Praia Vermelha, Av. Gal Milton Tavares de Souza, Gragoatá, 24310 240 Niterói, RJ (Brazil); Parigger, C. [University of Tennessee Space Institute, 411 B. H. Goethert Parkway, Tullahoma, TN 37388-9700 (United States)

    2013-10-01

    In this work, different theories for the determination of the electron density in Laser-Induced Breakdown Spectroscopy (LIBS) utilizing the emission lines belonging to the hydrogen Balmer series have been investigated. The plasmas were generated by a Nd:Yag laser (1064 nm) pulsed irradiation of pure hydrogen gas at a pressure of 2 · 10{sup 4} Pa. H{sub α}, Η{sub β}, Η{sub γ}, Η{sub δ}, and H{sub ε} Balmer lines were recorded at different delay times after the laser pulse. The plasma electron density was evaluated through the measurement of the Stark broadenings and the experimental results were compared with the predictions of three theories (the Standard Theory as developed by Kepple and Griem, the Advanced Generalized Theory by Oks et al., and the method discussed by Gigosos et al.) that are commonly employed for plasma diagnostics and that describe LIBS plasmas at different levels of approximations. A simple formula for pure hydrogen plasma in thermal equilibrium was also proposed to infer plasma electron density using the H{sub α} line. The results obtained showed that at high hydrogen concentration, the H{sub α} line is affected by considerable self-absorption. In this case, it is preferable to use the H{sub β} line for a reliable calculation of the electron density. - Highlights: • We evaluated the electron density in LIPs utilizing the hydrogen Balmer series. • Plasmas were generated by a Nd:Yag laser (1064 nm) on pure hydrogen gas. • We show that at high hydrogen concentration, H{sub b}eta line is preferable than H{sub a}lpha. • We propose a formula to derive the plasma electron density using the H{sub a}lpha line.

  10. Spectroscopy

    DEFF Research Database (Denmark)

    Berg, Rolf W.

    This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules.......This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules....

  11. Easy measurement of diffusion coefficients of EGFP-tagged plasma membrane proteins using k-space Image Correlation Spectroscopy

    DEFF Research Database (Denmark)

    Christensen, Eva Arnspang; Koffman, Jennifer Skaarup; Marlar, Saw

    2014-01-01

    Lateral diffusion and compartmentalization of plasma membrane proteins are tightly regulated in cells and thus, studying these processes will reveal new insights to plasma membrane protein function and regulation. Recently, k-Space Image Correlation Spectroscopy (kICS)1 was developed to enable...... to the correlation function yields the diffusion coefficient. This paper provides a step-by-step guide to the image analysis and measurement of diffusion coefficients via kICS. First, a high frame rate image sequence of a fluorescently labeled plasma membrane protein is acquired using a fluorescence microscope Then...... routine measurements of diffusion coefficients directly from images of fluorescently tagged plasma membrane proteins, that avoided systematic biases introduced by probe photophysics. Although the theoretical basis for the analysis is complex, the method can be implemented by nonexperts using a freely...

  12. Detection of HO2 in an atmospheric pressure plasma jet using optical feedback cavity-enhanced absorption spectroscopy

    Science.gov (United States)

    Gianella, Michele; Reuter, Stephan; Lawry Aguila, Ana; Ritchie, Grant A. D.; van Helden, Jean-Pierre H.

    2016-11-01

    Cold non-equilibrium atmospheric pressure plasma jets are increasingly applied in material processing and plasma medicine. However, their small dimensions make diagnosing the fluxes of generated species a challenge. Here we report on the detection of the hydroperoxyl radical, HO2, in the effluent of a plasma jet by the use of optical feedback cavity-enhanced absorption spectroscopy. The spectrometer has a minimum detectable absorption coefficient {α }\\min of 2.25× {10}-10 cm-1 with a 100 second acquisition, equivalent to 5.5× {10}12 {{cm}}-3 of HO2 (under ideal conditions). Concentrations in the range of (3.1-7.8) × 1013 cm-3 were inferred in the 4 mm wide effluent of the plasma jet.

  13. Time-resolved photoelectron spectroscopy and ab initio multiple spawning studies of hexamethylcyclopentadiene

    DEFF Research Database (Denmark)

    Wolf, T. J. A.; Kuhlman, Thomas Scheby; Schalk, O.

    2014-01-01

    Time-resolved photoelectron spectroscopy and ab initio multiple spawning were applied to the ultrafast non-adiabatic dynamics of hexamethylcyclopentadiene. The high level of agreement between experiment and theory associates wavepacket motion with a distinct degree of freedom....

  14. Time-resolved spectroscopy of the fluorescence quenching of a donor — acceptor pair by halothane

    Science.gov (United States)

    Sharma, A.; Draxler, S.; Lippitsch, M. E.

    1992-04-01

    Donor (anthracene) sensitized acceptor (perylene) fluorescence is quenched more efficiently by halothane than is intrinsic perylene fluorescence. The underlying process of dynamic fluorescence quenching is investigated by time-resolved fluorescence spectroscopy.

  15. Time-resolved photoelectron spectroscopy of non-adiabatic dynamics in polyatomic molecules

    CERN Document Server

    Stolow, Albert

    2015-01-01

    This review article discusses advances in the use of time-resolved photoelectron spectroscopy for the study of non-adiabatic processes in molecules. A theoretical treatment of the experiments is presented together with a number of experimental examples.

  16. A multimodal spectroscopy system for real-time disease diagnosis

    Science.gov (United States)

    Šćepanović, Obrad R.; Volynskaya, Zoya; Kong, Chae-Ryon; Galindo, Luis H.; Dasari, Ramachandra R.; Feld, Michael S.

    2009-04-01

    The combination of reflectance, fluorescence, and Raman spectroscopy—termed multimodal spectroscopy (MMS)—provides complementary and depth-sensitive information about tissue composition. As such, MMS is a promising tool for disease diagnosis, particularly in atherosclerosis and breast cancer. We have developed an integrated MMS instrument and optical fiber spectral probe for simultaneous collection of all three modalities in a clinical setting. The MMS instrument multiplexes three excitation sources, a xenon flash lamp (370-740 nm), a nitrogen laser (337 nm), and a diode laser (830 nm), through the MMS probe to excite tissue and collect the spectra. The spectra are recorded on two spectrograph/charge-coupled device modules, one optimized for visible wavelengths (reflectance and fluorescence) and the other for the near-infrared (Raman), and processed to provide diagnostic parameters. We also describe the design and calibration of a unitary MMS optical fiber probe 2 mm in outer diameter, containing a single appropriately filtered excitation fiber and a ring of 15 collection fibers, with separate groups of appropriately filtered fibers for efficiently collecting reflectance, fluorescence, and Raman spectra from the same tissue location. A probe with this excitation/collection geometry has not been used previously to collect reflectance and fluorescence spectra, and thus physical tissue models ("phantoms") are used to characterize the probe's spectroscopic response. This calibration provides probe-specific modeling parameters that enable accurate extraction of spectral parameters. This clinical MMS system has been used recently to analyze artery and breast tissue in vivo and ex vivo.

  17. Terahertz time-domain spectroscopy of high-pressure flames

    Institute of Scientific and Technical Information of China (English)

    Jason BASSI; Mark STRINGER; Bob MILES; Yang ZHANG

    2009-01-01

    Laser spectroscopy in the visible and near infrared is widely used as a diagnostic tool for combustion devices, but this approach is difficult at high pressures within a sooty flame itself. High soot concentrations render flames opaque to visible light, but they remain transparent to far-infrared or terahertz (THz) radiation. The first far-infrared absorption spectra, to the best of our knowledge, of sooty, non-premixed, ethylene high-pressure flames covering the region of 0.2-2.5 THz is presented. A specially designed high-pressure burner which is optically accessible to THz radiation has been built allowing flame transmission measurements up to pressures of 1.6 MPa. Calculations of the theoretical combustion species absorption spectra in the 0.2-3 THz range have shown that almost all the observable features arise from H2O. A few OH (1.84 and 2.51 THz), CH (2.58 THz), and NH3 (1.77 and 2.95 THz) absorption lines are also observable in principle. A large number of H2O absorption lines are observed in the ground vibrational in a laminar non-premixed, sooty flame (ethylene) at pressures up to 1.6 MPa.

  18. Direct observation of low frequency confined acoustic phonons in silver nanoparticles: Terahertz time domain spectroscopy.

    Science.gov (United States)

    Kumar, Sunil; Kamaraju, N; Karthikeyan, B; Tondusson, M; Freysz, E; Sood, A K

    2010-07-01

    Terahertz time domain spectroscopy has been used to study low frequency confined acoustic phonons of silver nanoparticles embedded in poly(vinyl alcohol) matrix in the spectral range of 0.1-2.5 THz. The real and imaginary parts of the dielectric function show two bands at 0.60 and 2.12 THz attributed to the spheroidal and toroidal modes of silver nanoparticles, thus demonstrating the usefulness of terahertz time domain spectroscopy as a complementary technique to Raman spectroscopy in characterizing the nanoparticles.

  19. Magnetic Rotational Spectroscopy with Nanorods to Probe Time-Dependent Rheology of Microdroplets (Postprint)

    Science.gov (United States)

    2012-05-10

    Rheology of polymer solutions/ gels (e.g., hazardous fluids containing thickeners) and biofluids depends on the concen- tration, level of cross-linking...AFRL-RX-TY-TP-2012-0041 MAGNETIC ROTATIONAL SPECTROSCOPY WITH NANORODS TO PROBE TIME-DEPENDENT RHEOLOGY OF MICRODROPLETS (POSTPRINT...Rotational Spectroscopy with Nanorods to Probe Time- Dependent Rheology of Microdroplets (POSTPRINT) FA8650-09-D-5900-0002 QL102011 *Tokarev

  20. Spectroscopic Investigations of Highly Charged Tungsten Ions - Atomic Spectroscopy and Fusion Plasma Diagnostics

    Energy Technology Data Exchange (ETDEWEB)

    Clementson, Joel [Lund Univ. (Sweden)

    2010-05-01

    The spectra of highly charged tungsten ions have been investigated using x-ray and extreme ultraviolet spectroscopy. These heavy ions are of interest in relativistic atomic structure theory, where high-precision wavelength measurements benchmark theoretical approaches, and in magnetic fusion research, where the ions may serve to diagnose high-temperature plasmas. The work details spectroscopic investigations of highly charged tungsten ions measured at the Livermore electron beam ion trap (EBIT) facility. Here, the EBIT-I and SuperEBIT electron beam ion traps have been employed to create, trap, and excite tungsten ions of M- and L-shell charge states. The emitted spectra have been studied in high resolution using crystal, grating, and x-ray calorimeter spectrometers. In particular, wavelengths of n = 0 M-shell transitions in K-like W55+ through Ne-like W64+, and intershell transitions in Zn-like W44+ through Co-like W47+ have been measured. Special attention is given to the Ni-like W46+ ion, which has two strong electric-dipole forbidden transitions that are of interest for plasma diagnostics. The EBIT measurements are complemented by spectral modeling using the Flexible Atomic Code (FAC), and predictions for tokamak spectra are presented. The L-shell tungsten ions have been studied at electron-beam energies of up to 122 keV and transition energies measured in Ne-like W64+ through Li-like W71+. These spectra constitute the physics basis in the design of the ion-temperature crystal spectrometer for the ITER tokamak. Tungsten particles have furthermore been introduced into the Sustained Spheromak Physics Experiment (SSPX) spheromak in Livermore in order to investigate diagnostic possibilities of extreme ultraviolet tungsten spectra for the ITER divertor. The spheromak measurement and spectral modeling using FAC suggest that tungsten ions in charge states around Er-like W6+ could be useful for

  1. Experimental station for laser-based picosecond time-resolved x-ray absorption near-edge spectroscopy

    Science.gov (United States)

    Dorchies, F.; Fedorov, N.; Lecherbourg, L.

    2015-07-01

    We present an experimental station designed for time-resolved X-ray Absorption Near-Edge Spectroscopy (XANES). It is based on ultrashort laser-plasma x-ray pulses generated from a table-top 100 mJ-class laser at 10 Hz repetition rate. A high transmission (10%-20%) x-ray beam line transport using polycapillary optics allows us to set the sample in an independent vacuum chamber, providing high flexibility over a wide spectral range from 0.5 up to 4 keV. Some XANES spectra are presented, demonstrating 1% noise level in only ˜1 mn and ˜100 cumulated laser shots. Time-resolved measurements are reported, indicating that the time resolution of the entire experimental station is 3.3 ± 0.6 ps rms.

  2. Experimental station for laser-based picosecond time-resolved x-ray absorption near-edge spectroscopy.

    Science.gov (United States)

    Dorchies, F; Fedorov, N; Lecherbourg, L

    2015-07-01

    We present an experimental station designed for time-resolved X-ray Absorption Near-Edge Spectroscopy (XANES). It is based on ultrashort laser-plasma x-ray pulses generated from a table-top 100 mJ-class laser at 10 Hz repetition rate. A high transmission (10%-20%) x-ray beam line transport using polycapillary optics allows us to set the sample in an independent vacuum chamber, providing high flexibility over a wide spectral range from 0.5 up to 4 keV. Some XANES spectra are presented, demonstrating 1% noise level in only ∼1 mn and ∼100 cumulated laser shots. Time-resolved measurements are reported, indicating that the time resolution of the entire experimental station is 3.3 ± 0.6 ps rms.

  3. Experimental station for laser-based picosecond time-resolved x-ray absorption near-edge spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dorchies, F., E-mail: dorchies@celia.u-bordeaux1.fr; Fedorov, N.; Lecherbourg, L. [Université Bordeaux, CNRS, CEA, CELIA (Centre Lasers Intenses et Applications), UMR 5107, Talence F-33405 (France)

    2015-07-15

    We present an experimental station designed for time-resolved X-ray Absorption Near-Edge Spectroscopy (XANES). It is based on ultrashort laser-plasma x-ray pulses generated from a table-top 100 mJ-class laser at 10 Hz repetition rate. A high transmission (10%–20%) x-ray beam line transport using polycapillary optics allows us to set the sample in an independent vacuum chamber, providing high flexibility over a wide spectral range from 0.5 up to 4 keV. Some XANES spectra are presented, demonstrating 1% noise level in only ∼1 mn and ∼100 cumulated laser shots. Time-resolved measurements are reported, indicating that the time resolution of the entire experimental station is 3.3 ± 0.6 ps rms.

  4. LASER ABLATION-INDUCTIVELY COUPLED PLASMA-ATOMIC EMISSION SPECTROSCOPY STUDY AT THE 222-S LABORATORY USING HOT-CELL GLOVE BOX PROTOTYPE SYSTEM

    Energy Technology Data Exchange (ETDEWEB)

    SEIDEL CM; JAIN J; OWENS JW

    2009-02-23

    This report describes the installation, testing, and acceptance of the Waste Treatment and Immobilization Plant (WTP) procured laser ablation-inductively coupled plasma-atomic emission spectroscopy (LA-ICP-AES) system for remotely analyzing high-level waste (HLW) samples in a hot cell environment. The work was completed by the Analytical Process Development (APD) group in accordance with Task Order 2005-003; ATS MP 1027, Management Plan for Waste Treatment Plant Project Work Performed by Analytical Technical Services. The APD group at the 222-S Laboratory demonstrated acceptable turnaround time (TAT) and provide sufficient data to assess sensitivity, accuracy, and precision of the LA-ICP-AES method.

  5. Atomic oxygen in a cold argon plasma jet: TALIF spectroscopy in ambient air with modelling and measurements of ambient species diffusion

    Science.gov (United States)

    Reuter, S.; Winter, J.; Schmidt-Bleker, A.; Schroeder, D.; Lange, H.; Knake, N.; Schulz-von der Gathen, V.; Weltmann, K.-D.

    2012-04-01

    By investigating the atomic oxygen density in its effluent, two-photon absorption laser-induced fluorescence (TALIF) spectroscopy measurements are for the first time performed in a cold argon/oxygen atmospheric pressure plasma jet. The measurements are carried out in ambient air and quenching by inflowing air species is considered. We propose a novel absorption technique in the VUV spectral range, where emission originating from within the discharge is used as light source to determine the inflow of atmospheric oxygen into the effluent. Furthermore, we propose a modelling solution for the on-axis density of inflowing ambient air based on the stationary convection-diffusion equation.

  6. Determination of Dynamics of Plant Plasma Membrane Proteins with Fluorescence Recovery and Raster Image Correlation Spectroscopy.

    Science.gov (United States)

    Laňková, Martina; Humpolíčková, Jana; Vosolsobě, Stanislav; Cit, Zdeněk; Lacek, Jozef; Čovan, Martin; Čovanová, Milada; Hof, Martin; Petrášek, Jan

    2016-04-01

    A number of fluorescence microscopy techniques are described to study dynamics of fluorescently labeled proteins, lipids, nucleic acids, and whole organelles. However, for studies of plant plasma membrane (PM) proteins, the number of these techniques is still limited because of the high complexity of processes that determine the dynamics of PM proteins and the existence of cell wall. Here, we report on the usage of raster image correlation spectroscopy (RICS) for studies of integral PM proteins in suspension-cultured tobacco cells and show its potential in comparison with the more widely used fluorescence recovery after photobleaching method. For RICS, a set of microscopy images is obtained by single-photon confocal laser scanning microscopy (CLSM). Fluorescence fluctuations are subsequently correlated between individual pixels and the information on protein mobility are extracted using a model that considers processes generating the fluctuations such as diffusion and chemical binding reactions. As we show here using an example of two integral PM transporters of the plant hormone auxin, RICS uncovered their distinct short-distance lateral mobility within the PM that is dependent on cytoskeleton and sterol composition of the PM. RICS, which is routinely accessible on modern CLSM instruments, thus represents a valuable approach for studies of dynamics of PM proteins in plants.

  7. Optical emission spectroscopy characterizations of micro-air plasma used for simulation of cell membrane poration

    Science.gov (United States)

    Zerrouki, A.; Motomura, H.; Ikeda, Y.; Jinno, M.; Yousfi, M.

    2016-07-01

    A micro-air corona discharge, which is one of the plasmas successfully used for gene transfection in terms of high transfection and cell viability rates, is characterized by optical emission spectroscopy. This non-equilibrium low temperature plasma is generated from the tip of a pulsed high voltage micro-tube (0.2 mm inner diameter and 0.7 mm for outer diameter) placed 2 mm in front of a petri dish containing deionized water and set on a grounded copper plate. The electron temperature, equal to about 6.75 eV near the electrode tip and decreased down to 3.4 eV near the plate, has been estimated, with an error bar of about 30%, from an interesting approach based on the experimental ratio of the closest nitrogen emission spectra of \\text{N}2+ (FNS) at 391.4 nm and N2(SPS) at 394.3 nm. This is based on one hand on a balance equation between creations and losses of the excited upper levels of these two UV spectra and on the other hand on the electron impact rates of the creation of these upper levels calculated from solution of the multi-term Boltzmann equation. Then using the measured Hα spectrum, electron density n e has been estimated from Stark broadening versus the inter-electrode position with an average error bar of about 50%. n e  ≈  1  ×  1015 cm-3 is near the tip coherent with the usual magnitude of electron density in the streamer head developed near the tip of the corona discharges. Rotational temperatures, estimated from comparison of synthetic and experimental spectra of OH(A  -  X), \\text{N}2+ (FNS) at 391.4 nm, and N2(SPS) at 337 nm are respectively equal to 2350 K, 2000 K and 700 K in the gap space. This clearly underlines a thermal non-equilibrium of the corresponding excited species generated inside the thin streamer filaments. But, due to the high dilution of these species in the background gas, these high rotational temperatures do not affect the mean gas temperature that remains close to 300

  8. Reactive species output of a plasma jet with a shielding gas device—combination of FTIR absorption spectroscopy and gas phase modelling

    Science.gov (United States)

    Schmidt-Bleker, A.; Winter, J.; Iseni, S.; Dünnbier, M.; Weltmann, K.-D.; Reuter, S.

    2014-04-01

    In this work, a simple modelling approach combined with absorption spectroscopy of long living species generated by a cold atmospheric plasma jet yields insight into relevant gas phase chemistry. The reactive species output of the plasma jet is controlled using a shielding gas device. The shielding gas is varied using mixtures of oxygen and nitrogen at various humidity levels. Through the combination of Fourier transform infrared (FTIR) spectroscopy, computational fluid dynamics (CFD) simulations and zero dimensional kinetic modelling of the gas phase chemistry, insight into the underlying reaction mechanisms is gained. While the FTIR measurements yield absolute densities of ozone and nitrogen dioxide in the far field of the jet, the kinetic simulations give additional information on reaction pathways. The simulation is fitted to the experimentally obtained data, using the CFD simulations of the experimental setup to estimate the correct evaluation time for the kinetic simulation. It is shown that the ozone production of the plasma jet continuously rises with the oxygen content in the shielding gas, while it significantly drops as humidity is increased. The production of nitrogen dioxide reaches its maximum at about 30% oxygen content in the shielding gas. The underlying mechanisms are discussed based on the simulation results.

  9. Optical emission spectroscopy of OH lines in N2 and Ar plasma during the treatments of cotton fabric

    Science.gov (United States)

    Skoro, Nikola; Puac, Nevena; Spasic, Kosta; Malovic, Gordana; Gorjanc, Marija; Petrovic, Zoran Lj

    2016-09-01

    Low pressure non-equilibrium plasmas are proven to be irreplaceable tool in material processing. Among other fields their applications in treatments of textiles are still diversifying, but the main role of plasma is activation of the surface of treated sample. After, or during, the treatments these surfaces can be covered with different materials or species (such as microcapsules) that enhance properties of the fabric. In order to investigate mechanisms how active species from plasma interact with the cotton surface, we studied both plasma and surface properties. Bleached cotton samples were treated in low-pressure nitrogen and argon plasma in a chamber with parallel-plate electrodes. The effect of the plasma treatment on the cotton samples was investigated with the colorimetric measurements on dyes absorption by a spectrophotometer. Optical emission spectroscopy was performed by using spectrometer with a sensitive CCD camera. We have recorded the evolution of the maximum of the intensity of OH and N2 second positive band lines. Measurement were done with and without samples in the chamber and comparison between the lines intensity was made. The parameters for optimal plasma treatment conditions were determined. Research supported by the MESTD, projects III41011 and ON171037.

  10. Measurement of Refractive Index for High Reflectance Materials with Terahertz Time Domain Reflection Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    SUN Wen-Feng; WANG Xin-Ke; ZHANG Yan

    2009-01-01

    A method to measure the refractive index for high reflectance materials in the terahertz range with terahertz time domain reflection spectroscopy is proposed. In this method, the THz waveforms reflected by a silicon wafer and high reflectance sample are measured respectively. The refractive index of the silicon wafer, measured with the THz time domain transmission spectroscopy, is used as a reference in the THz time domain reflective spectroscopy. Therefore, the complex refractive index of the sample can be obtained by resorting to the known reflective index of the silicon and the Fresnel law. To improve the accuracy of the phase shift, the Kramers-Kronig transform is adopted. This method is also verified by the index of the silicon in THz reflection spectroscopy. The bulk metal plates have been taken as the sample, and the experimentally obtained metallic refractive indexes are compared with the simple Drude model.

  11. Late-time spectroscopy of Type Iax Supernovae

    Science.gov (United States)

    Foley, Ryan J.; Jha, Saurabh W.; Pan, Yen-Chen; Zheng, Wei Kang; Bildsten, Lars; Filippenko, Alexei V.; Kasen, Daniel

    2016-09-01

    We examine the late-time (t ≳ 200 d after peak brightness) spectra of Type Iax supernovae (SNe Iax), a low-luminosity, low-energy class of thermonuclear stellar explosions observationally similar to, but distinct from, Type Ia supernovae. We present new spectra of SN 2014dt, resulting in the most complete late-time spectral sequence of an SN Iax. At late times, SNe Iax have generally similar spectra, all with a similar continuum shape and strong forbidden-line emission. However, there is also significant diversity where some SN Iax spectra display narrow P-Cygni features from permitted lines and a continuum indicative of a photosphere at late times in addition to strong narrow (FWHM 6000 km s-1) forbidden lines, and weak narrow forbidden lines, and some SNe Iax have spectra intermediate to these two varieties. We find that SNe Iax with strong broad forbidden lines are more luminous and have higher velocity ejecta at peak brightness. We estimate blackbody and kinematic radii of the late-time photosphere, finding the latter significantly larger than the former. We propose a two-component model that solves this discrepancy and explains the diversity of the late-time spectra of SNe Iax. In this model, the broad forbidden lines originate from the SN ejecta, while the photosphere, P-Cygni lines, and narrow forbidden lines originate from a wind launched from the remnant of the progenitor white dwarf and is driven by the radioactive decay of newly synthesized material left in the remnant. The relative strength of the two components accounts for the diversity of late-time SN Iax spectra. This model also solves the puzzle of a long-lived photosphere and the slow late-time decline of SNe Iax.

  12. Experimental Investigation on the Ignition Delay Time of Plasma-Assisted Ignition

    Science.gov (United States)

    Xiao, Yang; Yu, Jin-Lu; He, Li-Ming; Jiang, Yong-Jian; Wu, Yong

    2016-09-01

    This paper investigates the ignition performances of plasma-assisted ignition in propane/air mixture. The results show that a shorter ignition delay time is obtained for the plasma ignition than the spark ignition and the average ignition delay time of plasma-assisted ignition can be reduced at least by 50%. The influence of air flow rate of combustor, the arc current and argon flow rate of plasma igniter on ignition delay time are also investigated. The ignition delay time of plasma-assisted ignition increases with increasing air flow rate in the combustor. By increasing the arc current, the plasma ignition will gain more ignition energy to ignite the mixture more easily. The influence of plasma ignition argon flow rates on the ignition delay time is quite minor.

  13. Theory of mirrored time domain sampling for NMR spectroscopy.

    Science.gov (United States)

    Ghosh, Arindam; Wu, Yibing; He, Yunfen; Szyperski, Thomas

    2011-12-01

    A generalized theory is presented for novel mirrored hypercomplex time domain sampling (MHS) of NMR spectra. It is the salient new feature of MHS that two interferograms are acquired with different directionality of time evolution, that is, one is sampled forward from time t=0 to the maximal evolution time tmax, while the second is sampled backward from t=0 to -tmax. The sampling can be accomplished in a (semi) constant time or non constant-time manner. Subsequently, the two interferograms are linearly combined to yield a complex time domain signal. The manifold of MHS schemes considered here is defined by arbitrary settings of sampling phases ('primary phase shifts') and amplitudes of the two interferograms. It is shown that, for any two given primary phase shifts, the addition theorems of trigonometric functions yield the unique linear combination required to form the complex signal. In the framework of clean absorption mode (CAM) acquisition of NMR spectra being devoid of residual dispersive signal components, 'secondary phase shifts' represent time domain phase errors which are to be eliminated. In contrast, such secondary phase shifts may be introduced by experimental design in order to encode additional NMR parameters, a new class of NMR experiments proposed here. For generalization, it is further considered that secondary phase shifts may depend on primary phase shifts and/or sampling directionality. In order to compare with MHS theory, a correspondingly generalized theory is derived for widely used hypercomplex ('States') sampling (HS). With generalized theory it is shown, first, that previously introduced 'canonical' schemes, characterized by primary phases being multiples of π/4, afford maximal intensity of the desired absorptive signals in the absence of secondary phase shifts, and second, how primary phases can be adjusted to maximize the signal intensity provided that the secondary phase shifts are known. Third, it is demonstrated that theory enables

  14. Absolute number densities of helium metastable atoms determined by atomic absorption spectroscopy in helium plasma-based discharges used as ambient desorption/ionization sources for mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Reininger, Charlotte; Woodfield, Kellie [Brigham Young University, Department of Chemistry and Biochemistry, Provo, UT 84602 (United States); Keelor, Joel D.; Kaylor, Adam; Fernández, Facundo M. [Georgia Institute of Technology, School of Chemistry and Biochemistry, Atlanta, GA 30332 (United States); Farnsworth, Paul B., E-mail: paul_farnsworth@byu.edu [Brigham Young University, Department of Chemistry and Biochemistry, Provo, UT 84602 (United States)

    2014-10-01

    The absolute number densities of helium atoms in the 2s {sup 3}S{sub 1} metastable state were determined in four plasma-based ambient desorption/ionization sources by atomic absorption spectroscopy. The plasmas included a high-frequency dielectric barrier discharge (HF-DBD), a low temperature plasma (LTP), and two atmospheric-pressure glow discharges, one with AC excitation and the other with DC excitation. Peak densities in the luminous plumes downstream from the discharge capillaries of the HF-DBD and the LTP were 1.39 × 10{sup 12} cm{sup −3} and 0.011 × 10{sup 12} cm{sup −3}, respectively. Neither glow discharge produced a visible afterglow, and no metastable atoms were detected downstream from the capillary exits. However, densities of 0.58 × 10{sup 12} cm{sup −3} and 0.97 × 10{sup 12} cm{sup −3} were measured in the interelectrode regions of the AC and DC glow discharges, respectively. Time-resolved measurements of metastable atom densities revealed significant random variations in the timing of pulsed absorption signals with respect to the voltage waveforms applied to the discharges. - Highlights: • We determine He metastable number densities for four plasma types • The highest number densities were observed in a dielectric barrier discharge • No helium metastable atoms were observed downstream from the exits of glow discharges.

  15. Absolute atomic oxygen density measurements for nanosecond-pulsed atmospheric-pressure plasma jets using two-photon absorption laser-induced fluorescence spectroscopy

    Science.gov (United States)

    Jiang, C.; Carter, C.

    2014-12-01

    Nanosecond-pulsed plasma jets that are generated under ambient air conditions and free from confinement of electrodes have become of great interest in recent years due to their promising applications in medicine and dentistry. Reactive oxygen species that are generated by nanosecond-pulsed, room-temperature non-equilibrium He-O2 plasma jets among others are believed to play an important role during the bactericidal or sterilization processes. We report here absolute measurements of atomic oxygen density in a 1 mm-diameter He/(1%)O2 plasma jet at atmospheric pressure using two-photon absorption laser-induced fluorescence spectroscopy. Oxygen number density on the order of 1013 cm-3 was obtained in a 150 ns, 6 kV single-pulsed plasma jet for an axial distance up to 5 mm above the device nozzle. Temporally resolved O density measurements showed that there are two maxima, separated in time by 60-70 µs, and a total pulse duration of 260-300 µs. Electrostatic modeling indicated that there are high-electric-field regions near the nozzle exit that may be responsible for the observed temporal behavior of the O production. Both the field-distribution-based estimation of the time interval for the O number density profile and a pulse-energy-dependence study confirmed that electric-field-dependent, direct and indirect electron-induced processes play important roles for O production.

  16. In-situ optical emission spectroscopy diagnostic of plasma ignition impact on crystalline silicon passivation by a-Si:H films

    Science.gov (United States)

    Meddeb, Hosny; Bearda, Twan; Abdulraheem, Yaser; Dimassi, Wissem; Ezzaouia, Hatem; Gordon, Ivan; Szlufcik, Jozef; Poortmans, Jef

    2016-08-01

    The influence of the plasma ignition condition during PECVD deposition from a silane/hydrogen mixture on the amorphous silicon passivation of crystalline silicon surface is investigated. The changes in this process step mainly consist in varying the power density for very brief durations in between 1 s and 3 s. We find that the ignition phase contributes significantly in the film growth, especially in the a-Si:H/c-Si interface formation. In particular, the deposition rate increases with ignition power density. TEM cross-section inspection presents a rougher a-Si:H/c-Si interface with higher plasma power and thus, a tendency for nano-clusters formation caused by the crystalline nature of the substrate. In-situ plasma diagnostics reveal the gradual raise up of IHa*/ISiH* with the power density leading to worse SiH* abstraction to the surface. Whereas, time-resolved optical emission spectroscopy explains the possible recombination mechanism in the plasma due to higher-silane related reactive species (HSRS) formation via polymerization reactions. Our results point out that the ignition conditions with a rather low power for longer time give the best passivation, resulting an effective lifetime up to 9 ms.

  17. Emission Characteristics of Laser-Induced Plasma Using Collinear Long and Short Dual-Pulse Laser-Induced Breakdown Spectroscopy (LIBS).

    Science.gov (United States)

    Wang, Zhenzhen; Deguchi, Yoshihiro; Liu, Renwei; Ikutomo, Akihiro; Zhang, Zhenzhen; Chong, Daotong; Yan, Junjie; Liu, Jiping; Shiou, Fang-Jung

    2017-09-01

    Collinear long and short dual-pulse laser-induced breakdown spectroscopy (DP-LIBS) was employed to clarify the emission characteristics from laser-induced plasma. The plasma was sustained and became stable by the long pulse-width laser with the pulse width of 60 μs under free running (FR) conditions as an external energy source. Comparing the measurement results of stainless steel in air using single-pulse LIBS (SP-LIBS) and DP-LIBS, the emission intensity was markedly enhanced using DP-LIBS. The temperature of plasma induced by DP-LIBS was maintained at a higher temperature under different gate delay time and short pulse-width laser power conditions compared with those measured using short SP-LIBS. Moreover, the variation rates of plasma temperatures measured using DP-LIBS were also lower. The superior detection ability was verified by the measurement of aluminum sample in water. The spectra were clearly detected using DP-LIBS, whereas it cannot be identified using SP-LIBS of short and long pulse widths. The effects of gate delay time and short pulse-width laser power were also discussed. These results demonstrate the feasibility and enhanced detection ability of the proposed collinear long and short DP-LIBS method.

  18. Plasma confinement time in trimix-M galatea multipole magnetic trap

    Science.gov (United States)

    Bishaev, A. M.; Bugrova, A. I.; Kozintseva, M. V.; Lipatov, A. S.; Sigov, A. S.; Kharchevnikov, V. K.

    2010-05-01

    The confinement time of hydrogen plasma trapped in a Trimix-M magnetic multipole galatea was studied in a range of plasma densities (1 × 1016 - 6 × 1018 m-3) and ion energies (˜100-300 eV). It is established that (i) the confinement time increases with decreasing plasma density in the trap and (ii) as the barrier magnetic field is increased, the plasma confinement time grows faster than according to a linear law. The obtained results are indicative of a collisional character of plasma diffusion through the barrier field in the trap.

  19. Investigation of the atomic emission spectroscopy of F atoms and CF2 molecules in CF4 plasma processing

    Science.gov (United States)

    Jin, Huiliang; Li, Jie; Tang, Caixue; Deng, Wenhui; Chen, Xianhua

    2016-10-01

    The surface chemistry reaction involved in the processing of Atmospheric Pressure Plasma Jet (APPJ) produced from CF4 precursor has been explored. The atomic emission spectroscopy of F atoms and CF2 molecules was investigated as they contribute to substrate etching and FC film formation during APPJ processing. Optical emission spectroscopy (OES) spectra were acquired for CF4 plasma, relative concentrations of excited state species of F atoms and CF2 molecules were also dependent upon plasma parameters. The densities of F atoms increased dramatically with increasing applied RF power, whereas CF2 molecules decreased monotonically over the same power range, the subsequent electron impacted decomposition of plasma species after CF4 precursor fragmentation. The spectrum of the F atoms and CF2 molecules fallowed the same tendency with the increasing concentration of gas CF4, reaching the maximum at the 20sccm and 15sccm respectively, and then the emission intensity of reactive atoms decreased with more CF4 molecules participating. Addition certain amount O2 into CF4 plasma resulted in promoting CF4 dissociation, O2 can easily react with the dissociation product of CF2 molecules, which inhibit the compound of the F atoms, so with the increasing concentration of O2, the concentration of the CF2 molecules decreased and the emission intensities of F atoms showed the maximum at the O2/CF4 ratio of 20%. These results have led to the development of a scheme that illustrates the mechanisms of surface chemistry reaction and the affection of plasma parameters in CF4 plasma systems with respect to F and CF2 gas-phase species.

  20. Valence band gaps and plasma energies for galena, sphalerite, and chalcopyrite natural minerals using differential optical reflectance spectroscopy

    Science.gov (United States)

    Todoran, R.; Todoran, D.; Szakacs, Zs.

    2015-12-01

    The paper presents the determinations of the valence band gaps and plasma energies of the galena, sphalerite and chalcopyrite natural minerals. The work was carried out using differential optical reflectance spectroscopy of the clean mineral surfaces. The determination of the optical properties such as refractive index, real part of the complex dielectric constant and the location of certain van Hove singularities, was carried out using the Kramers-Kronig formalism.

  1. Time-resolved spectroscopy in the Rijnhuizen Tokamak Project tokamak

    NARCIS (Netherlands)

    Box, F. M. A.; Howard, J.; VandeKolk, E.; Meijer, F. G.

    1997-01-01

    At the Rijnhuizen Tokamak Project tokamak spectrometers are used to diagnose the velocity distribution and abundances of impurity ions. Quantities can be measured as a function of time, and the temporal resolution depends on the line emissivity and can be as good as 0.2 ms for the strongest lines.

  2. Late-time Spectroscopy of Type Iax Supernovae

    CERN Document Server

    Foley, Ryan J; Pan, Yen-Chen; Zheng, WeiKang; Bildsten, Lars; Filippenko, Alexei V; Kasen, Daniel

    2016-01-01

    We examine the late-time (t > 200 days after peak brightness) spectra of Type Iax supernovae (SNe Iax), a low-luminosity, low-energy class of thermonuclear stellar explosions observationally similar to, but distinct from, Type Ia supernovae. We present new spectra of SN 2014dt, resulting in the most complete published late-time spectral sequence of a SN Iax. At late times, SNe Iax have generally similar spectra, all with a similar continuum shape and strong forbidden-line emission. However, there is also significant diversity where some late-time SN Iax spectra display narrow P-Cygni features and a continuum indicative of a photosphere in addition to strong narrow forbidden lines, while others have no obvious P-Cygni features, strong broad forbidden lines, and weak narrow forbidden lines. Finally, some SNe Iax have spectra intermediate to these two varieties with weak P-Cygni features and broad/narrow forbidden lines of similar strength. We find that SNe Iax with strong broad forbidden lines also tend to be m...

  3. Time-resolved spectroscopy in the Rijnhuizen Tokamak Project tokamak

    NARCIS (Netherlands)

    Box, F. M. A.; Howard, J.; VandeKolk, E.; Meijer, F. G.

    1997-01-01

    At the Rijnhuizen Tokamak Project tokamak spectrometers are used to diagnose the velocity distribution and abundances of impurity ions. Quantities can be measured as a function of time, and the temporal resolution depends on the line emissivity and can be as good as 0.2 ms for the strongest lines. S

  4. A streaked X-ray spectroscopy platform for rapidly heated, near-solid density plasmas

    Science.gov (United States)

    Stillman, C. R.; Nilson, P. M.; Ivancic, S. T.; Mileham, C.; Begishev, I. A.; Junquist, R. K.; Nelson, D. J.; Froula, D. H.

    2016-11-01

    A picosecond, time-resolved, x-ray spectroscopy platform was developed to study the thermal line emission from rapidly heated solid targets containing buried aluminum or iron layers. The targets were driven by high-contrast 1ω or 2ω laser pulses at focused intensities up to 1 × 1019 W/cm2. The experimental platform combines time-integrating and time-resolved x-ray spectrometers. Picosecond time resolution was achieved with a pair of ultrafast x-ray streak cameras coupled to high-throughput Hall spectrometers. Time-integrated spectra were collected on each shot to correct the streaked data for variations in x-ray photocathode spectral sensitivity. The time-integrated spectrometer uses three elliptical crystals to disperse x rays with energies between 800 and 2100 eV with moderate (E/ΔE ˜ 450) resolving power. The streaked spectrometers accept four interchangeable conical crystals with higher resolving power (E/ΔE ˜ 650) to measure the brightest thermal lines in the 1300 to 1700 eV spectral range.

  5. Mobile charge generation dynamics in P3HT: PCBM observed by time-resolved terahertz spectroscopy

    DEFF Research Database (Denmark)

    Cooke, D. G.; Krebs, Frederik C; Jepsen, Peter Uhd

    2012-01-01

    Ultra-broadband time-resolved terahertz spectroscopy is used to examine the sub-ps conductivity dynamics of a conjugated polymer bulk heterojunction film P3HT:PCBM. We directly observe mobile charge generation dynamics on a sub-100 fs time scale.......Ultra-broadband time-resolved terahertz spectroscopy is used to examine the sub-ps conductivity dynamics of a conjugated polymer bulk heterojunction film P3HT:PCBM. We directly observe mobile charge generation dynamics on a sub-100 fs time scale....

  6. Picosecond Streaked K-Shell Spectroscopy of Near Solid-Density Aluminum Plasmas

    Science.gov (United States)

    Stillman, C. R.; Nilson, P. M.; Ivancic, S. T.; Mileham, C.; Froula, D. H.; Golovkin, I. E.

    2016-10-01

    The thermal x-ray emission from rapidly heated solid targets containing a buried-aluminum layer was measured. The targets were driven by high-contrast 1 ω or 2 ω laser pulses at focused intensities up to 1 ×1019W/Wcm2 cm2 . A streaked x-ray spectrometer recorded the Al Heα and lithium-like satellite lines with 2-ps temporal resolution and moderate resolving power (E/E ΔE 700). Time-integrated measurements over the same spectral range were used to correct the streaked data for variations in photocathode sensitivity. Line widths and intensity ratios from the streaked data were interpreted using a collisional radiative atomic model to provide the average plasma conditions in the buried layer as a function of time. It was observed that the resonance line tends toward lower photon energies at high electron densities. The measured shifts will be compared to predicted shifts from Stark-operator calculations at the inferred plasma conditions. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944, the office of Fusion Energy Sciences Award Number DE-SC0012317, and the Stewardship Science Graduate Fellowship Grant Number DE-NA0002135.

  7. Experimental investigation of silicon photomultipliers as compact light readout systems for gamma-ray spectroscopy applications in fusion plasmas.

    Science.gov (United States)

    Nocente, M; Fazzi, A; Tardocchi, M; Cazzaniga, C; Lorenzoli, M; Pirovano, C; Rebai, M; Uboldi, C; Varoli, V; Gorini, G

    2014-11-01

    A matrix of Silicon Photo Multipliers has been developed for light readout from a large area 1 in. × 1 in. LaBr3 crystal. The system has been characterized in the laboratory and its performance compared to that of a conventional photo multiplier tube. A pulse duration of 100 ns was achieved, which opens up to spectroscopy applications at high counting rates. The energy resolution measured using radioactive sources extrapolates to 3%-4% in the energy range Eγ = 3-5 MeV, enabling gamma-ray spectroscopy measurements at good energy resolution. The results reported here are of relevance in view of the development of compact gamma-ray detectors with spectroscopy capabilities, such as an enhanced gamma-ray camera for high power fusion plasmas, where the use of photomultiplier is impeded by space limitation and sensitivity to magnetic fields.

  8. Experimental investigation of silicon photomultipliers as compact light readout systems for gamma-ray spectroscopy applications in fusion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Nocente, M., E-mail: massimo.nocente@mib.infn.it; Gorini, G. [Dipartimento di Fisica “G. Occhialini,” Università degli Studi di Milano-Bicocca, Milano (Italy); Istituto di Fisica del Plasma “P. Caldirola,” EURATOM-ENEA-CNR Association, Milano (Italy); Fazzi, A.; Lorenzoli, M.; Pirovano, C. [Dipartimento di Energia, CeSNEF, Politecnico di Milano, Milano (Italy); Istituto Nazionale di Fisica Nucleare, Sezione di Milano, Milano (Italy); Tardocchi, M. [Istituto di Fisica del Plasma “P. Caldirola,” EURATOM-ENEA-CNR Association, Milano (Italy); Cazzaniga, C.; Rebai, M. [Dipartimento di Fisica “G. Occhialini,” Università degli Studi di Milano-Bicocca, Milano (Italy); Uboldi, C.; Varoli, V. [Dipartimento di Energia, CeSNEF, Politecnico di Milano, Milano (Italy)

    2014-11-15

    A matrix of Silicon Photo Multipliers has been developed for light readout from a large area 1 in. × 1 in. LaBr{sub 3} crystal. The system has been characterized in the laboratory and its performance compared to that of a conventional photo multiplier tube. A pulse duration of 100 ns was achieved, which opens up to spectroscopy applications at high counting rates. The energy resolution measured using radioactive sources extrapolates to 3%–4% in the energy range E{sub γ} = 3–5 MeV, enabling gamma-ray spectroscopy measurements at good energy resolution. The results reported here are of relevance in view of the development of compact gamma-ray detectors with spectroscopy capabilities, such as an enhanced gamma-ray camera for high power fusion plasmas, where the use of photomultiplier is impeded by space limitation and sensitivity to magnetic fields.

  9. Metastable argon atom density in complex argon/acetylene plasmas determined by means of optical absorption and emission spectroscopy

    Science.gov (United States)

    Sushkov, Vladimir; Herrendorf, Ann-Pierra; Hippler, Rainer

    2016-10-01

    Optical emission and absorption spectroscopy has been utilized to investigate the instability of acetylene-containing dusty plasmas induced by growing nano-particles. The density of Ar(1s5) metastable atoms was derived by two methods: tunable diode laser absorption spectroscopy and with the help of the branching ratio method of emitted spectral lines. Results of the two techniques agree well with each other. The density of Ar(1s3) metastable atoms was also measured by means of optical emission spectroscopy. The observed growth instability leads to pronounced temporal variations of the metastable and other excited state densities. An analysis of optical line ratios provides evidence for a depletion of free electrons during the growth cycle but no indication for electron temperature variations.

  10. Time-resolved fluorescence spectroscopy for chemical sensors

    Science.gov (United States)

    Draxler, Sonja; Lippitsch, Max E.

    1996-07-01

    A family of sensors is presented with fluorescence decay-time measurements used as the sensing technique. The concept is to take a single fluorophore with a suitably long fluorescence decay time as the basic building block for numerous different sensors. Analyte recognition can be performed by different functional groups that are necessary for selective interaction with the analyte. To achieve this, the principle of excited-state electron transfer is applied with pyrene as the fluorophore. Therefore the same instrumentation based on a small, ambient air-nitrogen laser and solid-state electronics can be used to measure different analytes, for example, oxygen, pH, carbon dioxide, potassium, ammonium, lead, cadmium, zinc, and phosphate.

  11. Estimation of liquid volume fraction using ultrasound transit time spectroscopy

    Science.gov (United States)

    Al-Qahtani, Saeed M.; Langton, Christian M.

    2016-12-01

    It has recently been proposed that the propagation of an ultrasound wave through complex structures, consisting of two-materials of differing ultrasound velocity, may be considered as an array of parallel ‘sonic rays’, the transit time of each determined by their relative proportion; being a minimum (t min) in entire higher velocity material, and a maximum (t max) in entire lower velocity material. An ultrasound transit time spectrum (UTTS) describes the proportion of sonic rays at an individual transit time. It has previously been demonstrated that the solid volume fraction of a solid:liquid composite, specifically acrylic step-wedges immersed in water, may be reliably estimated from the UTTS. The aim of this research was to investigate the hypothesis that the volume fraction of a two-component liquid mixture, of unequal ultrasound velocity, may also be estimated by UTTS. A through-transmission technique incorporating two 1 MHz ultrasound transducers within a horizontally-aligned cylindrical tube-housing was utilised, the proportion of silicone oil to water being varied from 0% to 100%. The liquid volume fraction was estimated from the UTTS at each composition, the coefficient of determination (R 2%) being 98.9  ±  0.7%. The analysis incorporated a novel signal amplitude normalisation technique to compensate for absorption within the silicone oil. It is therefore envisaged that the parallel sonic ray concept and the derived UTTS may be further applied to the quantification of liquid mixture composition assessment.

  12. Time domain terahertz electro- and magneto-optic spectroscopy

    CERN Document Server

    Moore, G P

    2001-01-01

    sub i sub c sub u sub l sub a sub r = 0 centre dot 19m sub e and m sub p sub a sub r sub a sub l sub l sub e sub l = 0 centre dot 90m sub e. The temperature dependence of the cyclotron resonance was measured over the range 5K to 80 K, and a peak is found at approx 30 K which can be explained in terms of ionised and neutral impurity scattering at temperatures below 30 K and by phonon scattering above 30 K. The measurement of small amplitude ferromagnetic resonance oscillations in the time domain in thin films of permalloy (78), iron and cobalt has been achieved by using the time resolved magneto-optic Kerr effect. A stripline device was fabricated to provide an out of plane broadband magnetic pulse with a peak strength of approx 5 Oe. The observed frequencies are shown to agree well with the established theory. A time domain terahertz spectrometer and a bolometer have been used to study the coherent THz radiation emitted from n- and p-type InAs surfaces illuminated by femtosecond near infrared pulses. The magn...

  13. Radiative lifetime measurements of some Tm I and Tm II levels by time-resolved laser spectroscopy

    Science.gov (United States)

    Tian, Yanshan; Wang, Xinghao; Yu, Qi; Li, Yongfan; Gao, Yang; Dai, Zhenwen

    2016-04-01

    Radiative lifetimes of 88 levels of Tm I in the energy range 22 791.176-48 547.98 cm-1 and 29 levels of Tm II in the range 27 294.79-65 612.85 cm-1 were measured by time-resolved laser-induced fluorescence spectroscopy in laser-ablation plasma. The lifetime values obtained are in the range from 15.4 to 7900 ns for Tm I and from 36.5 to 1000 ns for Tm II. To the best of our knowledge, 77 lifetimes of Tm I and 22 lifetimes of Tm II are reported for the first time. Good agreements between the present results and the previous experimental values were achieved for both Tm I and Tm II.

  14. Time-resolved photoluminescence spectroscopy of semiconductors for optical applications beyond the visible spectral range

    Energy Technology Data Exchange (ETDEWEB)

    Chernikov, Alexey A.

    2011-07-01

    The work discussed in this thesis is focused on the experimental studies regarding these three steps: (1) investigation of the fundamental effects, (2) characterization of new material systems, and (3) optimization of the semiconductor devices. In all three cases, the experimental technique of choice is photoluminescence (PL) spectroscopy. The thesis is organized as follows. Chapter 2 gives a summary of the PL properties of semiconductors relevant for this work. The first section deals with the intrinsic processes in an ideal direct band gap material, starting with a brief summary of the theoretical background followed by the overview of a typical PL scenario. In the second part of the chapter, the role of the lattice-vibrations, the internal electric fields as well as the influence of the band-structure and the dielectric environment are discussed. Finally, extrinsic PL properties are presented in the third section, focusing on defects and disorder in real materials. In chapter 3, the experimental realization of the spectroscopic studies is discussed. The time-resolved photoluminescence (TRPL) setup is presented, focusing on the applied excitation source, non-linear frequency mixing, and the operation of the streak camera used for the detection. In addition, linear spectroscopy setup for continous-wave (CW) PL and absorption measurements is illustrated. Chapter 4 aims at the study of the interactions between electrons and lattice-vibrations in semiconductor crystals relevant for the proper description of carrier dynamics as well as the heat-transfer processes. The presented discussion covers the experimental studies of many-body effects in phonon-assisted emission of semiconductors due to the carriercarrier Coulomb-interaction. The corresponding theoretical background is discussed in detail in chapter 2. The investigations are focused on the two main questions regarding electron-hole plasma contributions to the phonon-assisted light-matter interaction as well as

  15. Rapid, Time-Division Multiplexed, Direct Absorption- and Wavelength Modulation-Spectroscopy

    OpenAIRE

    Alexander Klein; Oliver Witzel; Volker Ebert

    2014-01-01

    We present a tunable diode laser spectrometer with a novel, rapid time multiplexed direct absorption- and wavelength modulation-spectroscopy operation mode. The new technique allows enhancing the precision and dynamic range of a tunable diode laser absorption spectrometer without sacrificing accuracy. The spectroscopic technique combines the benefits of absolute concentration measurements using calibration-free direct tunable diode laser absorption spectroscopy (dTDLAS) with the enhanced nois...

  16. Electron cyclotron resonance ion source plasma characterization by X-ray spectroscopy and X-ray imaging

    Energy Technology Data Exchange (ETDEWEB)

    Mascali, David, E-mail: davidmascali@lns.infn.it; Castro, Giuseppe; Celona, Luigi; Neri, Lorenzo; Gammino, Santo [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Biri, Sándor; Rácz, Richárd; Pálinkás, József [Institute for Nuclear Research (Atomki), Hungarian Academy of Sciences, Bem tér 18/c, H-4026 Debrecen (Hungary); Caliri, Claudia [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Università degli Studi di Catania, Dip.to di Fisica e Astronomia, via Santa Sofia 64, 95123 Catania (Italy); Romano, Francesco Paolo [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); CNR, Istituto per i Beni Archeologici e Monumentali, Via Biblioteca 4, 95124 Catania (Italy); Torrisi, Giuseppe [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Università Mediterranea di Reggio Calabria, DIIES, Via Graziella, I-89100 Reggio Calabria (Italy)

    2016-02-15

    An experimental campaign aiming to investigate electron cyclotron resonance (ECR) plasma X-ray emission has been recently carried out at the ECRISs—Electron Cyclotron Resonance Ion Sources laboratory of Atomki based on a collaboration between the Debrecen and Catania ECR teams. In a first series, the X-ray spectroscopy was performed through silicon drift detectors and high purity germanium detectors, characterizing the volumetric plasma emission. The on-purpose developed collimation system was suitable for direct plasma density evaluation, performed “on-line” during beam extraction and charge state distribution characterization. A campaign for correlating the plasma density and temperature with the output charge states and the beam intensity for different pumping wave frequencies, different magnetic field profiles, and single-gas/gas-mixing configurations was carried out. The results reveal a surprisingly very good agreement between warm-electron density fluctuations, output beam currents, and the calculated electromagnetic modal density of the plasma chamber. A charge-coupled device camera coupled to a small pin-hole allowing X-ray imaging was installed and numerous X-ray photos were taken in order to study the peculiarities of the ECRIS plasma structure.

  17. Time-domain spectroscopy in the mid-infrared

    Science.gov (United States)

    Lanin, A. A.; Voronin, A. A.; Fedotov, A. B.; Zheltikov, A. M.

    2014-10-01

    When coupled to characteristic, fingerprint vibrational and rotational motions of molecules, an electromagnetic field with an appropriate frequency and waveform offers a highly sensitive, highly informative probe, enabling chemically specific studies on a broad class of systems in physics, chemistry, biology, geosciences, and medicine. The frequencies of these signature molecular modes, however, lie in a region where accurate spectroscopic measurements are extremely difficult because of the lack of efficient detectors and spectrometers. Here, we show that, with a combination of advanced ultrafast technologies and nonlinear-optical waveform characterization, time-domain techniques can be advantageously extended to the metrology of fundamental molecular motions in the mid-infrared. In our scheme, the spectral modulation of ultrashort mid-infrared pulses, induced by rovibrational motions of molecules, gives rise to interfering coherent dark waveforms in the time domain. These high-visibility interference patterns can be read out by cross-correlation frequency-resolved gating of the field in the visible generated through ultrabroadband four-wave mixing in a gas phase.

  18. The distribution of radio plasma in time and space.

    Science.gov (United States)

    Blundell, Katherine M

    2005-03-15

    The influence of jet-ejected plasma has been an important theme of this meeting; I draw attention to the prevalence of jet-ejected plasma, in particular that which has not been properly accounted for in the past. There are three strands to this paper: important emission which is prominent only at the lowest radio frequencies; relic radio plasma which must exist if even the most basic aspects of radio source evolutionary models are correct; and evidence that some 'radio-quiet' quasars could be FR-I radio sources.

  19. Time dependent atomic processes in discharge produced low Z plasma

    Science.gov (United States)

    Yuyama, M.; Sasaki, T.; Horioka, K.; Kawamura, T.

    2008-05-01

    The z-pinch simulation have been performed with magneto-hydro dynamics and atomic population kinetics codes. A factor associated with transient atomic processes was proposed. The atomic transient degrees of dopant lithium in hydrogen plasma were calculated with initial plasma densities of 1.0 × 1016 ~ 5.0 × 1017cm-3. The higher initial plasma density is, the lower is the transient degree generally. It is also found that the transient properties of the atomic processes are sensitive to ionization energy and electron temperature.

  20. Elemental detection of arabica and robusta green bean coffee using laser-induced plasma spectroscopy

    Science.gov (United States)

    Abdulmadjid, Syahrun Nur; Meilina, Hesti; Hedwig, Rinda; Kurniawan, Koo Hendrik

    2017-01-01

    The elemental detection of green bean of arabica and robusta coffee from Gayo Highland, Aceh-Indonesia, has been identified by using fundamental Nd-YAG Laser at 10 Torr of surrounding air gas pressure for distinguishing the characteristics of both coffees. As the preliminary study, we have detected the elements of K 766.49 nm, Na 588.9 nm, Ca 393.3 nm, CN band at 388.3 nm, N 337.13 nm and C 247.8 nm of both coffees. It is noticed that the order of elements concentration from highest to lowest are Ca>K>CN> Na>N> C for arabica and K>Ca>CN >Na>C>N for robusta. The emission intensity of K 766.49 nm is almost same for both of coffee. However, the emission intensity of Na 588.9 nm is lower in Arabica coffee. To distinguish the Arabica coffee and Robusta Coffee, we take the ratio intensity of K/C, Na/C, CN/C, and Ca/C. It is found that the ratio intensities of CN/C and Ca/C in arabica bean are significantly different with robusta bean. That ratio intensities can be used as a marker to discriminate kind of coffee. We also noted that the arabica green bean is 1.3 harder than robusta green bean. These findings prove that the technique of laser-induced plasma spectroscopy can be used to make rapid identification of elements in coffee and can potentially be applied to measure the concentration of blended coffee for the purpose of authentication.

  1. X-ray High-resolution Spectroscopy for Laser-produced Plasma

    Science.gov (United States)

    Barbato, F.; Scarpellini, D.; Malizia, A.; Gaudio, P.; Richetta, M.; Antonelli, L.

    The study of the emission spectrum gives information about the material generating the spectrum itself and the condition in which this is generated. The wavelength spectra lines are linked to the specific element and plasma conditions (electron temperature, density), while their shape is influenced by several physical effects like Stark and Doppler ones. In this work we study the X-ray emission spectra of a copper laser-produced plasma by using a spherical bent crystal spectrometer to measure the electron temperature. The facility used is the laser TVLPS, at the Tor Vergata University in Rome. It consists of a Nd:Glass source (in first harmonic - 1064 nm) whose pulse parameters are: 8 J in energy, time duration of 15 ns and a focal spot diameter of 200 μm. The adopted spectrometer is based on a spherical bent crystal of muscovite. The device combines the focusing property of a spherical mirror with the Bragg's law. This allows to obtain a great power resolution but a limited range of analysis. In our case the resolution is on average 80 eV. As it is well-known, the position of the detector on the Rowland's circle is linked to the specific spectral range which has been studied. To select the area to be investigated, we acquired spectra by means of a flat spectrometer. The selected area is centered on 8.88 Å. To calibrate the spectrum we wrote a ray-tracing MATLAB code, which calculates the detector alignment parameters and calibration curve. We used the method of line ratio to measure the electron temperature. This is possible because we assumed the plasma to be in LTE condition. The temperature value was obtained comparing the experimental one, given by the line ratio, with the theoretical one, preceded by FLYCHK simulations.

  2. Time-resolved spectroscopy of low-dimensional semiconductor structures

    Science.gov (United States)

    Murphy, Joseph R.

    This dissertation is a survey of ultrafast time-resolved optical measurements conducted on a variety of low-dimensional semiconductor systems to further the understanding of the dynamic behavior in the following systems: ZnMnTe/ZnSe quantum dots, ZnTe/ZnMnSe quantum dots, InGaAs quantum wells, CdMnSe colloidal quantum dots, multi-shell CdSe/CdMnS/CdS colloidal nanoplatelets, and graphene and graphene-related solutions and films. Using time-resolved photoluminescence to study epitaxially-grown ZnTe and ZnMnTe quantum dots in corresponding ZnMnSe and ZnSe matrices, the location dependence of manganese ions in respect to magnetic polaron formation is shown. The structure with manganese ions located in the matrix exhibited magnetic polaron behavior consistent with previous literature, whereas the structure with the magnetic ions located within the quantum dots exhibited unconventional magnetic polaron properties. These properties, including temperature and magnetic field insensitivity, were explained through the use of a model that predicted an increased internal magnetic field due to a decreased effective volume of the magnetic polaron and a higher effective temperature due to laser heating. Magneto-time-resolved photoluminescence measurements on a system of colloidal CdMnSe quantum dots show that the magnetic polaron properties differ significantly from the epitaxially grown quantum dots. First the timescales at which the magnetic polaron forms and the polarization saturates are different by more than an order of magnitude, and second, the magnetic polaron energy exhibited step-like behavior as the strength of the externally applied magnetic field is increased. The field dependent MP formation energy that is observed experimentally is explained as due to the breaking of the antiferromagnetic coupling of Mn dimers within the QDs. This model is further verified by the observation of quantized behavior in the Zeeman energy splitting. Through the use of magneto

  3. Asphericity in supernova explosions from late-time spectroscopy.

    Science.gov (United States)

    Maeda, Keiichi; Kawabata, Koji; Mazzali, Paolo A; Tanaka, Masaomi; Valenti, Stefano; Nomoto, Ken'ichi; Hattori, Takashi; Deng, Jinsong; Pian, Elena; Taubenberger, Stefan; Iye, Masanori; Matheson, Thomas; Filippenko, Alexei V; Aoki, Kentaro; Kosugi, George; Ohyama, Youichi; Sasaki, Toshiyuki; Takata, Tadafumi

    2008-02-29

    Core-collapse supernovae (CC-SNe) are the explosions that announce the death of massive stars. Some CC-SNe are linked to long-duration gamma-ray bursts (GRBs) and are highly aspherical. One important question is to what extent asphericity is common to all CC-SNe. Here we present late-time spectra for a number of CC-SNe from stripped-envelope stars and use them to explore any asphericity generated in the inner part of the exploding star, near the site of collapse. A range of oxygen emission-line profiles is observed, including a high incidence of double-peaked profiles, a distinct signature of an aspherical explosion. Our results suggest that all CC-SNe from stripped-envelope stars are aspherical explosions and that SNe accompanied by GRBs exhibit the highest degree of asphericity.

  4. Time resolved spectroscopy of KPD1930+2752

    CERN Document Server

    Geier, S; Przybilla, N; Kudritzki, R P

    2005-01-01

    We present the analysis of 200 high-resolution and 150 low-resolution spectra of the pulsating subdwarf close binary KPD 1930+2752 obtained with the Keck and the Calar Alto 2.2 m telescopes. Using metal-rich, line blanketed LTE model atmospheres the atmospheric parameters T_{eff} = 35500 +/- 500 K, log g = 5.56 +/- 0.05 and log n(He)/n(H) = -1.48 +/- 0.02 were derived. The radial velocity curve was measured and combined with all available published and unpublished radial velocity data in order to get results of high accuracy (K = 341 +/- 1 km/s, P = 0.0950933 +/- 0.0000015 d). For the first time we measured the projected rotational velocity. The preliminary result is v_{rot}sin{i} = 97 +/- 9 km/s. Since the rotation of the sdB star is very likely tidally locked to the orbit, we can constrain the inclination of the system. Assuming the companion to be a white dwarf, the mass of the sdB is limited from 0.44M_{sun} to 0.63M_{sun} and the total mass range of the system is 1.3 M_{sun} to 2.0 M_{sun}. It is very li...

  5. Electric and Magnetic Field Measurements in High Energy Electron Beam Diode Plasmas using Optical Spectroscopy

    Science.gov (United States)

    Johnston, Mark; Patel, Sonal; Kiefer, Mark; Biswas, S.; Doron, R.; Stambulchik, E.; Bernshtam, V.; Maron, Yitzhak

    2016-10-01

    The RITS accelerator (5-11MV, 100-200kA) at Sandia National Laboratories is being used to evaluate the Self-Magnetic Pinch (SMP) diode as a potential flash x-ray radiography source. This diode consists of a small, hollowed metal cathode and a planar, high atomic mass anode, with a small vacuum gap of approximately one centimeter. The electron beam is focused, due to its self-field, to a few millimeters at the target, generating bremsstrahlung x-rays. During this process, plasmas form on the electrode surfaces and propagate into the vacuum gap, with a velocity of a 1-10 cm's/microseconds. These plasmas are measured spectroscopically using a Czerny-Turner spectrometer with a gated, ICCD detector, and input optical fiber array. Local magnetic and electric fields of several Tesla and several MV/cm were measured through Zeeman splitting and Stark shifting of spectral lines. Specific transitions susceptible to quantum magnetic and electric field effects were utilized through the application of dopants. Data was analyzed using detailed, time-dependent, collisional-radiative (CR) and radiation transport modeling. Recent results will be presented. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  6. Characterizing a multi-MeV e-beam induced plasma through visible spectroscopy and imaging

    Science.gov (United States)

    D'Almeida, Thierry; Ribiere, Maxime; Maisonny, Rémi; Ritter, Sandra; Plouhinec, Damien; Auriel, Gérard

    2016-10-01

    High energy electrons interaction and propagation mechanisms in solid targets have a broad range of applications in high energy density physics. The latter include fast ignition for inertial fusion research, production of ultra-high mechanical stress levels, plasma interactions with e-beam particles in electron diodes, radiative hydrodynamic models...This paper presents the results from recent experiments conducted on the multi-MeV generator ASTERIX operated at CEA-Gramat. This high flux density electron beam was launched from an aluminum cathode onto an aluminum-tantalum target for voltage and current of 2.4 MeV and 55 kA, respectively. A set of optical diagnostics were fielded in all of the experiments, including a UV-visible spectrometers and a fast imaging. The imaging data obtained during the experiment allowed for the ablated species velocity to be determined. based on spectroscopic analysis, the light emission was attributed to aluminum and tantalum excited atoms and ions. The analysis of this time-integrated spectrum based on radiative transfer model clearly unveiled two distinct regions of the plasma over its expansion: a hot core surrounded by a cold vapor. A quantitative analysis of these results is presented.

  7. Time-resolved diffusing wave spectroscopy applied to dynamic heterogeneity imaging

    CERN Document Server

    Cheikh, M; Ettori, D; Tinet, E; Avrillier, S; Tualle, J M; Cheikh, Monia; Nghiem, Ha Lien; Ettori, Dominique; Tinet, Eric; Avrillier, Sigrid; Tualle, Jean-Michel

    2006-01-01

    We report in this paper what is to our knowledge the first observation of a time-resolved diffusing wave spectroscopy signal recorded by transillumination through a thick turbid medium: the DWS signal is measured for a fixed photon transit time, which opens the possibility of improving the spatial resolution. This technique could find biomedical applications, especially in mammography.

  8. Time-resolved VUV spectroscopy in the EXTRAP-T2 reversed field pinch

    Science.gov (United States)

    Hedqvist, Anders; Rachlew-Källne, Elisabeth

    1998-09-01

    Time-resolved VUV spectroscopy has been used to investigate the effects of impurities in a reversed field pinch operating with a resistive shell. Results of electron temperature, impurity ion densities, particle confinement time and 0741-3335/40/9/004/img1 together with a description of the interpretation and the equipment are presented.

  9. New Approach for Near-Real-Time Measurement of Elemental Composition of Aerosol Using Laser-Induced Breakdown Spectroscopy

    Science.gov (United States)

    Diwakar, Prasoon; Kulkarni, Pramod; Birch, M. Eileen

    2015-01-01

    A new approach has been developed for making near-real-time measurement of elemental composition of aerosols using plasma spectroscopy. The method allows preconcentration of miniscule particle mass (pg to ng) directly from the sampled aerosol stream through electrostatic deposition of charged particles (30–900 nm) onto a flat-tip microneedle electrode. The collected material is subsequently ablated from the electrode and monitored by laser-induced breakdown spectroscopy. Atomic emission spectra were collected using a broadband spectrometer with a wavelength range of 200–980 nm. A single-sensor delay time of 1.3 μs was used in the spectrometer for all elements to allow simultaneous measurement of multiple elements. The system was calibrated for various elements including Cd, Cr, Cu, Mn, Na, and Ti. The absolute mass detection limits for these elements were experimentally determined and found to be in the range of 0.018–5 ng. The electrostatic collection technique has many advantages over other substrate-based methods involving aerosol collection on a filter or its focused deposition using an aerodynamic lens. Because the particle mass is collected over a very small area that is smaller than the spatial extent of the laser-induced plasma, the entire mass is available for analysis. This considerably improves reliability of the calibration and enhances measurement accuracy and precision. Further, the aerosol collection technique involves very low pressure drop, thereby allowing higher sample flow rates with much smaller pumps—a desirable feature for portable instrumentation. Higher flow rates also make it feasible to measure trace element concentrations at part per trillion levels. Detection limits in the range of 18–670 ng m−3 can be achieved for most of the elements studied at a flow rate of 1.5 L min−1 with sampling times of 5 min. PMID:26692632

  10. New Approach for Near-Real-Time Measurement of Elemental Composition of Aerosol Using Laser-Induced Breakdown Spectroscopy.

    Science.gov (United States)

    Diwakar, Prasoon; Kulkarni, Pramod; Birch, M Eileen

    A new approach has been developed for making near-real-time measurement of elemental composition of aerosols using plasma spectroscopy. The method allows preconcentration of miniscule particle mass (pg to ng) directly from the sampled aerosol stream through electrostatic deposition of charged particles (30-900 nm) onto a flat-tip microneedle electrode. The collected material is subsequently ablated from the electrode and monitored by laser-induced breakdown spectroscopy. Atomic emission spectra were collected using a broadband spectrometer with a wavelength range of 200-980 nm. A single-sensor delay time of 1.3 μs was used in the spectrometer for all elements to allow simultaneous measurement of multiple elements. The system was calibrated for various elements including Cd, Cr, Cu, Mn, Na, and Ti. The absolute mass detection limits for these elements were experimentally determined and found to be in the range of 0.018-5 ng. The electrostatic collection technique has many advantages over other substrate-based methods involving aerosol collection on a filter or its focused deposition using an aerodynamic lens. Because the particle mass is collected over a very small area that is smaller than the spatial extent of the laser-induced plasma, the entire mass is available for analysis. This considerably improves reliability of the calibration and enhances measurement accuracy and precision. Further, the aerosol collection technique involves very low pressure drop, thereby allowing higher sample flow rates with much smaller pumps-a desirable feature for portable instrumentation. Higher flow rates also make it feasible to measure trace element concentrations at part per trillion levels. Detection limits in the range of 18-670 ng m(-3) can be achieved for most of the elements studied at a flow rate of 1.5 L min(-1) with sampling times of 5 min.

  11. Transition probabilities for lines of Cr II, Na II and Sb I by laser produced plasma atomic emission spectroscopy; Probabilidades de transicion de algunos niveles de Cr II, Na II y Sb I medediante espectroscopia de plasma producidos por laser

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, A. M.; Ortiz, M.; Campos, J.

    1995-07-01

    Absolute transition probabilities for lines of CR II, Na II and Sb I were determined by emission spectroscopy of laser induced plasmas. the plasma was produced focusing the emission of a pulsed Nd-Yag laser on solid samples containing the atom in study. the light arising from the plasma region was collected by and spectrometer. the detector used was a time-resolved optical multichannel analyzer (OMA III EG and G). The wavelengths of the measured transitions range from 2000 sto 4100 A. The spectral resolution of the system was 0. 2 A. The method can be used in insulators materials as Cl Na crystals and in metallic samples as Al-Cr and Sn-Sn alloys. to avoid self-absorption effects the alloys were made with low Sb or Cr content. Relative transition probabilities have been determined from measurements of emission-line intensities and were placed on an absolute scale by using, where possible, accurate experimental lifetime values form the literature or theoretical data. From these measurements, values for plasma temperature (8000-24000 K), electron densities ({approx}{approx} 10''16 cm ''-3) and self-absorption coefficients have been obtained. (Author) 56 refs.

  12. Full-Field Spectroscopy at Megahertz-frame-rates: Application of Coherent Time-Stretch Transform

    Science.gov (United States)

    DeVore, Peter Thomas Setsuda

    Outliers or rogue events are found extensively in our world and have incredible effects. Also called rare events, they arise in the distribution of wealth (e.g., Pareto index), finance, network traffic, ocean waves, and e-commerce (selling less of more). Interest in rare optical events exploded after the sighting of optical rogue waves in laboratory experiments at UCLA. Detecting such tail events in fast streams of information necessitates real-time measurements. The Coherent Time-Stretch Transform chirps a pulsed source of radiation so that its temporal envelope matches its spectral profile (analogous to the far field regime of spatial diffraction), and the mapped spectral electric field is slow enough to be captured by a real-time digitizer. Combining this technique with spectral encoding, the time stretch technique has enabled a new class of ultra-high performance spectrometers and cameras (30+ MHz), and analog-to-digital converters that have led to the discovery of optical rogue waves and detection of cancer cells in blood with one in a million sensitivity. Conventionally, the Coherent Time-Stretch Transform maps the spectrum into the temporal electric field, but the time-dilation process along with inherent fiber losses results in reduction of peak power and loss of sensitivity, a problem exacerbated by extremely narrow molecular linewidths. The loss issue notwithstanding, in many cases the requisite dispersive optical device is not available. By extending the Coherent Time-Stretch Transform to the temporal near field, I have demonstrated, for the first time, phase-sensitive absorption spectroscopy of a gaseous sample at millions of frames per second. As the Coherent Time-Stretch Transform may capture both near and far field optical waves, it is a complete spectro-temporal optical characterization tool. This is manifested as an amplitude-dependent chirp, which implies the ability to measure the complex refractive index dispersion at megahertz frame rates. This

  13. Laser-induced breakdown spectroscopy for real time and online elemental analysis

    CERN Document Server

    Rai, V N; Yueh, Fang-Yu; Singh, J P

    2014-01-01

    Laser-induced breakdown spectroscopy (LIBS) is a laser based diagnostics used to study atomic emission from the expanding plasma plume formed during the laser-matter interaction. It provides valuable information about the composition of the target material. LIBS has proved its potential application in the analysis of impurities, pollutants and toxic elements in various types of matrices of different samples (solid, liquid and gases), even those present under difficult and harsh environmental conditions. This article reviews some recent developments in the field, and its wide application in various fields of research and analysis.

  14. Proceedings of the eighth international colloquium on ultraviolet and x-ray spectroscopy of astrophysical and laboratory plasmas (IAU colloquium 86)

    Energy Technology Data Exchange (ETDEWEB)

    1984-01-01

    This volume represents the Proceedings of the Eighth International Colloquium on Ultraviolet and X-Ray Spectroscopy of Astrophysical and Laboratory Plasmas. The aim of this series of colloquia has been to bring together workers in the fields of astrophysical spectroscopy, laboratory spectroscopy and atomic physics in order to exchange ideas and results on problems which are common to these different disciplines. In addition to the presented papers there was a poster paper session. (WRF)

  15. Determination of plasma trace elements in tumor-bearing animals by proton-induced X-ray emission spectroscopy.

    Science.gov (United States)

    Fogle, M; Daly, B; Evans, M; Justiniano, E L; Kovacs, C J; Shinpaugh, J L; Toburen, L H

    2001-11-01

    Although altered levels of circulating essential trace elements are known to accompany malignant disease, the lack of sensitivity of conventional detection methods has generally limited their study to clinical conditions involving extensive disease (i.e., significant tumor burden). As such, the application of altered trace element levels as potential prognostic guides or as response indicators subsequent to treatment has been of limited use. During this study, proton-induced X-ray emission spectroscopy was evaluated as a tool to determine trace element imbalances in a murine tumor model. Using plasma from C57B1/6 mice bearing the syngeneic Lewis lung carcinoma (LLCa), levels of Fe, Cu, and Zn, as well as changes in the Cu /Zn ratio, were measured in animals carrying an increasing primary tumor burden. The plasma levels of Fe, Cu, and Zn were found to decrease significantly 7 d following implants of LLCa cells with no significant change observed in the Cu/Zn ratio. By d 21, however, an increase in the Cu/Zn ratio was found to accompany increased growth of the LLCa tumor; the plasma levels of Cu had returned to normal levels, whereas both the Fe and Zn plasma levels remained lowered. Collectively, the results suggest that although a net change in individual plasma trace element concentrations might not be accurately associated with tumor growth, a clear relationship was established between the Cu/Zn ratio and tumor size.

  16. Modeling of plasma distortions by laser-induced ablation spectroscopy (LIAS) and implications for the interpretation of LIAS measurements

    Science.gov (United States)

    Tokar, M. Z.; Gierse, N.; Philipps, V.; Samm, U.

    2015-09-01

    For the interpretation of the line radiation observed from laser induced ablation spectroscopy (LIAS) such parameters as the density and temperature of electrons within very compact clouds of atoms and singly charged ions of ablated material have to be known. Compared to the local plasma conditions prior to the laser pulse, these can be strongly changed during LIAS since new electrons are generated by the ionisation of particles ejected from the irradiated target. Because of their transience and spatial inhomogeneity it is technically difficult to measure disturbances induced in the plasma by LIAS. To overcome this uncertainty a numerical model has been elaborated, providing a self-consistent description for the spreading of ablated particles and accompanying modifications in the plasma. The results of calculations for LIAS performed on carbon-containing targets in Ohmic and additionally heated discharges in the tokamak TEXTOR are presented. Due to the increase in the electron density the ‘ionisation per photon’ ratio, S/XB factor, is significantly enhanced compared to unperturbed plasma conditions. The impact of the amount of material ablated and of the plasma conditions before LIAS on the level of the S/XB-enhancement is investigated.

  17. Comparison of Nitric Oxide Concentrations in μs- and ns-Atmospheric Pressure Plasmas by UV Absorption Spectroscopy

    Science.gov (United States)

    Peters, F.; Hirschberg, J.; Mertens, N.; Wieneke, S.; Viöl, W.

    2016-04-01

    In this paper, an absorption spectroscopy measurement method was applied on two atmospheric pressure plasma sources to determine their production of nitric oxide. The concentrations are essential for evaluating the plasma sources based on the principle of the Dielectric Barrier Discharge (DBD) for applications in plasma medicine. The described method is based on a setup with an electrodeless discharge lamp filled with a mixture of oxygen and nitrogen. One of the emitted wavelengths is an important resonance wavelength of nitric oxide (λ = 226.2 nm). By comparing the absorption behaviour at the minimum and maximum of the spectral absorption cross section of nitric oxide around that wavelength, and measuring the change in intensity by the absorbing plasma, the concentration of nitric oxide inside the plasma can be calculated. The produced nitric oxide concentrations depend on the pulse duration and are in the range of 180 ppm to 1400 ppm, so that a distance of about 10cm to the respiratory tract is enough to conform to the VDI Guideline 2310.

  18. Investigation of aqueous alcohol and sugar solutions with reflection terahertz time-domain spectroscopy

    DEFF Research Database (Denmark)

    Jepsen, Peter Uhd; Møller, Uffe; Merbold, Hannes

    2007-01-01

    of the dielectric properties of especially liquids in environments where transmission measurements are difficult. We investigate the dielectric properties in the 0.1-1.0 THz frequency range of liquids using reflection terahertz time-domain spectroscopy. We apply the technique for the determination of alcohol......We give a detailed analysis of a general realization of reflection terahertz time-domain spectroscopy. The method is self-referenced and applicable at all incidence angles and for all polarizations of the incident terahertz radiation. Hence it is a general method for the determination...

  19. Contactless graphene conductance measurements: the effect of device fabrication on terahertz time-domain spectroscopy

    DEFF Research Database (Denmark)

    Mackenzie, David; Buron, Jonas Christian Due; Bøggild, Peter

    2016-01-01

    We perform contactless full-wafer maps of the electrical conductance of a 4-inch wafer of single-layer CVD graphene using terahertz time-domain spectroscopy both before and after deposition of metal contacts and fabrication of devices via laser ablation. We find that there is no significant change...... in the measured conductance of graphene before and after device fabrication. We also show that precise terahertz time-domain spectroscopy can be performed when the beam spot is at sufficient distance (>1.2 mm) from metal contacts....

  20. Absolute number densities of helium metastable atoms determined by atomic absorption spectroscopy in helium plasma-based discharges used as ambient desorption/ionization sources for mass spectrometry

    Science.gov (United States)

    Reininger, Charlotte; Woodfield, Kellie; Keelor, Joel D.; Kaylor, Adam; Fernández, Facundo M.; Farnsworth, Paul B.

    2014-10-01

    The absolute number densities of helium atoms in the 2s 3S1 metastable state were determined in four plasma-based ambient desorption/ionization sources by atomic absorption spectroscopy. The plasmas included a high-frequency dielectric barrier discharge (HF-DBD), a low temperature plasma (LTP), and two atmospheric-pressure glow discharges, one with AC excitation and the other with DC excitation. Peak densities in the luminous plumes downstream from the discharge capillaries of the HF-DBD and the LTP were 1.39 × 1012 cm- 3 and 0.011 × 1012 cm- 3, respectively. Neither glow discharge produced a visible afterglow, and no metastable atoms were detected downstream from the capillary exits. However, densities of 0.58 × 1012 cm- 3 and 0.97 × 1012 cm- 3 were measured in the interelectrode regions of the AC and DC glow discharges, respectively. Time-resolved measurements of metastable atom densities revealed significant random variations in the timing of pulsed absorption signals with respect to the voltage waveforms applied to the discharges.

  1. Atomic layer sensitive in-situ plasma etch depth control with reflectance anisotropy spectroscopy (RAS)

    Science.gov (United States)

    Doering, Christoph; Kleinschmidt, Ann-Kathrin; Barzen, Lars; Strassner, Johannes; Fouckhardt, Henning

    2017-06-01

    Reflectance anisotropy spectroscopy (RAS) allows for in-situ monitoring of reactive ion etching (RIE) of monocrystalline III-V semiconductor surfaces. Upon use of RAS the sample to be etched is illuminated with broad-band linearly polarized light under nearly normal incidence. Commonly the spectral range is between 1.5 and 5.5 eV. Typically the spectrally resolved difference in reflectivity for light of two orthogonal linear polarizations of light is measured with respect to time - for example for cubic lattices (like the zinc blende structures of most III-V semiconductors) polarizations along the [110] and the [-110] direction. Local anisotropies on the etch front cause elliptical polarization of the reflected light resulting in the RAS signal. The time and photon energy resolved spectra of RAS include reflectometric as well as interferometric information. Light with wavelengths well above 100 nm (even inside the material) can be successfully used to monitor surface abrasion with a resolution of some tens of nanometers. The layers being thinned out act as optical interferometers resulting in Fabry-Perot oscillations of the RAS-signal. Here we report on RAS measurements assessing the surface deconstruction during dry etching. For low etch rates our experimental data show even better resolution than that of the (slow) Fabry-Perot oscillations. For certain photon energies we detect monolayer-etch-related oscillations in the mean reflectivity, which give the best possible resolution in etch depth monitoring and control, i.e. the atomic scale.

  2. Quantifying the cerebral metabolic rate of oxygen by combining diffuse correlation spectroscopy and time-resolved near-infrared spectroscopy.

    Science.gov (United States)

    Verdecchia, Kyle; Diop, Mamadou; Lee, Ting-Yim; St Lawrence, Keith

    2013-02-01

    Preterm infants are highly susceptible to ischemic brain injury; consequently, continuous bedside monitoring to detect ischemia before irreversible damage occurs would improve patient outcome. In addition to monitoring cerebral blood flow (CBF), assessing the cerebral metabolic rate of oxygen (CMRO2) would be beneficial considering that metabolic thresholds can be used to evaluate tissue viability. The purpose of this study was to demonstrate that changes in absolute CMRO2 could be measured by combining diffuse correlation spectroscopy (DCS) with time-resolved near-infrared spectroscopy (TR-NIRS). Absolute CBF was determined using bolus-tracking TR-NIRS to calibrate the DCS measurements. Cerebral venous blood oxygenation (SvO2) was determined by multiwavelength TR-NIRS measurements, the accuracy of which was assessed by directly measuring the oxygenation of sagittal sinus blood. In eight newborn piglets, CMRO2 was manipulated by varying the anesthetics and by injecting sodium cyanide. No significant differences were found between the two sets of SvO2 measurements obtained by TR-NIRS or sagittal sinus blood samples and the corresponding CMRO2 measurements. Bland-Altman analysis showed a mean CMRO2 difference of 0.0268 ± 0.8340 mLO2/100 g/min between the two techniques over a range from 0.3 to 4 mL O2/100 g/min.

  3. Plasma density evolution in plasma opening switch obtained by a time-resolved sensitive He-Ne interferometer

    Science.gov (United States)

    Chen, Lin; Ren, Jing; Guo, Fan; Zhou, LiangJi; Li, Ye; He, An; Jiang, Wei

    2014-03-01

    To understand the formation process of vacuum gap in coaxial microsecond conduction time plasma opening switch (POS), we have made measurements of the line-integrated plasma density during switch operation using a time-resolved sensitive He-Ne interferometer. The conduction current and conduction time in experiments are about 120 kA and 1 μs, respectively. As a result, more than 85% of conduction current has been transferred to an inductive load with rise time of 130 ns. The radial dependence of the density is measured by changing the radial location of the line-of-sight for shots with the same nominal POS parameters. During the conduction phase, the line-integrated plasma density in POS increases at all radial locations over the gun-only case by further ionization of material injected from the guns. The current conduction is observed to cause a radial redistribution of the switch plasma. A vacuum gap forms rapidly in the plasma at 5.5 mm from the center conductor, which is consistent with the location where magnetic pressure is the largest, allowing current to be transferred from the POS to the load.

  4. Determination of the electron energy distribution function of a low temperature plasma from optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dodt, Dirk Hilar

    2009-01-05

    The experimental determination of the electron energy distribution of a low pressure glow discharge in neon from emission spectroscopic data has been demonstrated. The spectral data were obtained with a simple overview spectrometer and analyzed using a strict probabilistic, Bayesian data analysis. It is this Integrated Data Analysis (IDA) approach, which allows the significant extraction of non-thermal properties of the electron energy distribution function (EEDF). The results bear potential as a non-invasive alternative to probe measurements. This allows the investigation of spatially inhomogeneous plasmas (gradient length smaller than typical probe sheath dimensions) and plasmas with reactive constituents. The diagnostic of reactive plasmas is an important practical application, needed e.g. for the monitoring and control of process plasmas. Moreover, the experimental validation of probe theories for magnetized plasmas as a long-standing topic in plasma diagnostics could be addressed by the spectroscopic method. (orig.)

  5. Capturing molecular structural dynamics by 100 ps time-resolved X-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Tokushi [Department of Materials Science, Tokyo Institute of Technology, 2-12-1-H61 Ohokayama, Meguro-ku, Tokyo 152-8551 (Japan); Non-Equilibrium Dynamics Project, ERATO, Japan Science and Technology Agency, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); Nozawa, Shunsuke; Ichiyanagi, Kohei [Non-Equilibrium Dynamics Project, ERATO, Japan Science and Technology Agency, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); Tomita, Ayana [Department of Materials Science, Tokyo Institute of Technology, 2-12-1-H61 Ohokayama, Meguro-ku, Tokyo 152-8551 (Japan); Non-Equilibrium Dynamics Project, ERATO, Japan Science and Technology Agency, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); Chollet, Matthieu [Department of Materials Science, Tokyo Institute of Technology, 2-12-1-H61 Ohokayama, Meguro-ku, Tokyo 152-8551 (Japan); Ichikawa, Hirohiko [Non-Equilibrium Dynamics Project, ERATO, Japan Science and Technology Agency, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); Fujii, Hiroshi [Institute for Molecular Science and Okazaki Institute for Integrative Bioscience, Myodaiji, Okazaki 444-8787 (Japan); Adachi, Shin-ichi [Non-Equilibrium Dynamics Project, ERATO, Japan Science and Technology Agency, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); High Energy Accelerator Research Organization, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); Koshihara, Shin-ya, E-mail: skoshi@cms.titech.ac.jp [Department of Materials Science, Tokyo Institute of Technology, 2-12-1-H61 Ohokayama, Meguro-ku, Tokyo 152-8551 (Japan); Non-Equilibrium Dynamics Project, ERATO, Japan Science and Technology Agency, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); High Energy Accelerator Research Organization, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); Frontier Research Center, Tokyo Institute of Technology, 2-12-1 Ohokayama, Meguro-ku, Tokyo 152-8551 (Japan)

    2009-01-01

    An experimental set-up for time-resolved X-ray absorption spectroscopy with 100 ps time resolution at beamline NW14A at the Photon Factory Advanced Ring is presented. An experimental set-up for time-resolved X-ray absorption spectroscopy with 100 ps time resolution at beamline NW14A at the Photon Factory Advanced Ring is presented. The X-ray positional active feedback to crystals in a monochromator combined with a figure-of-merit scan of the laser beam position has been utilized as an essential tool to stabilize the spatial overlap of the X-ray and laser beams at the sample position. As a typical example, a time-resolved XAFS measurement of a photo-induced spin crossover reaction of the tris(1,10-phenanthrorine)iron(II) complex in water is presented.

  6. Study of laser-induced removal of co-deposits from tokamak plasma-facing components using ion diagnostics and optical spectroscopy

    Science.gov (United States)

    Wolowski, J.; Gasior, P.; Hoffman, J.; Kubkowska, M.; Rosinski, M.; Szymanski, Z.

    2010-10-01

    The paper presents studies of the application of ion diagnostics and optical spectroscopy for on-line measurement of the amount and characteristics of co-deposits from the laser-ablated surface of the plasma-facing components (e.g. graphite tiles). For removal of the co-deposit layer a repetitive Nd:YAG laser was used. Determination of the characteristics of ions emitted from the laser-illuminated targets was performed using ion collectors (on the basis of a time-of-flight method) and an optical spectrometer. The main ion stream parameters and spectral lines of deuterium and carbon or tungsten ions were measured depending on laser pulse parameters. The research proved that optical spectroscopy could be a convenient method for on-line observation of the co-deposited layer removal by means of laser ablation. In combination with the investigation of collected co-deposit dust, the performed study made it possible to state that laser-induced breakdown spectroscopy can be useful as a diagnostic method for the ablative co-deposited layer removal and the wall conditioning. The properties of modified surfaces of samples and collected dust (evaporated co-deposit) were determined using different measuring methods.

  7. Time-resolved terahertz spectroscopy in a parallel-plate waveguide

    DEFF Research Database (Denmark)

    Cooke, David; Jepsen, Peter Uhd

    2009-01-01

    Time-resolved THz spectroscopy is a powerful tool to investigate photoconductivity dynamics in a wide variety of materials with sub-picosecond resolution, all without applying contacts to the material. This technique uses coherently detected and broadband pulses of far-infrared light, known as THz...

  8. A Method for Quantitative Analysis of Chemical Mixtures with THz Time Domain Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zeng-Yan; JI Te; YU Xiao-Han; XIAO Ti-Qiao; XU Hong-Jie

    2006-01-01

    @@ A method for analysing chemical mixtures quantitatively with terahertz time domain spectroscopy is proposed.The experimental results demonstrate the feasibility of this technique. Transmission coefficient of THz wave at the sample surface is taken into account to improve the analytic precision. Isomer mixtures are chosen as the experimental samples. Compared to similar techniques, the analytic precision could be improved evidently in this method.

  9. Pseudo-bimolecular [2+2] cycloaddition studied by time-resolved photoelectron spectroscopy

    DEFF Research Database (Denmark)

    Brogaard, Rasmus Y; Boguslavskiy, Andrey E; Schalk, Oliver

    2011-01-01

    The first study of pseudo-bimolecular cycloaddition reaction dynamics in the gas phase is presented. We used femtosecond time-resolved photoelectron spectroscopy (TRPES) to study the [2+2] photocycloaddition in the model system pseudo-gem-divinyl[2.2]paracyclophane. From X-ray crystal diffraction...

  10. Diffuse reflectance spectroscopy : toward real-time quantification of steatosis in liver

    NARCIS (Netherlands)

    Evers, Daniel J.; Westerkamp, Andrie C.; Spliethoff, Jarich W.; Pully, Vishnu V.; Hompes, Daphne; Hendriks, Benno H. W.; Prevoo, Warner; van Velthuysen, Marie-Louise F.; Porte, Robert J.; Ruers, Theo J. M.

    2015-01-01

    Assessment of fatty liver grafts during orthotopic liver transplantation is a challenge due to the lack of real-time analysis options during surgery. Diffuse reflectance spectroscopy (DRS) could be a new diagnostic tool to quickly assess steatosis. Eight hundred and seventy-eight optical measurement

  11. The Self-Injected Laser for Picosecond Time-Resolved Spectroscopy

    OpenAIRE

    Armani, F.; Martini, F; Mataloni, P.

    1983-01-01

    The principles of operation and the characteristics of the self-injected picosecond laser are presented. We show that in spite of its simple design our device is able to generate very high power pulses in the picosecond domain. This warrants the use of this laser for time resolved spectroscopy in the picosecond domain.

  12. [Real time diagnostics of instantaneous temperature of combustion and explosion process by modern spectroscopy].

    Science.gov (United States)

    Zhou, Xue-tie; Wang, Jun-de; Li, Yan; Liu, Da-bing

    2003-04-01

    The combustion temperature is one of the important parameters to express flame combustion and explosion characteristics. It will effectively guide the design and manufacture of new model explosives, industrial explosive materials, and weapons. The recent developments and applications of real time diagnostics of instantaneous temperature of combustion and explosion processes by modern spectroscopic methods, such as atomic absorption-emission method, atomic emission two-line spectroscopy, atomic emission multiline spectroscopy, molecular rotation-vibration spectroscopy, coherent anti-stokes Raman scattering (CARS) and plane laser-induced fluorescence (PLIF), were reviewed in this paper. The maximum time resolution of atomic absorption-emission method is 25 microseconds. The time resolution of atomic emission two-line spectroscopy can reach 0.1 microsecond. These two methods can completely suit the need of real time and instantaneous temperature diagnostics of violent explosion and flame combustion. Other methods will also provide new effective research methods for the processes and characteristics of combustion, flame and explosion.

  13. Ultrabroadband time-resolved THz spectroscopy of polymer-based solar cells

    DEFF Research Database (Denmark)

    Cooke, David G.; Krebs, Frederik C; Jepsen, Peter Uhd

    2011-01-01

    We have developed ultrabroadband THz spectroscopy in reflection mode for characterization of conductivity dynamics in conductive polymer samples used in organic solar cells. The spectrometer is designed to have a time resolution limited only by the duration of the optical pump pulse, thus enabling...

  14. Real—time Analysis of the Interaction between Calmodulin and Melittin by SPR Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    WeiGuoLI; XiaoQiangCUI; 等

    2002-01-01

    The dynamic interaction process of calmodulin with an immobilized peptide melittin was investigated in real time by surface plasmon resonance spectroscopy, and dissociation constant of the complex was calculated to be 3.37×10-6 mol/L.

  15. Monitoring the catalytic synthesis of glycerol carbonate by real-time attenuated total reflection FTIR spectroscopy

    NARCIS (Netherlands)

    Calvino-Casilda, V.; Mul, G.; Fernandez, J.F.; Rubio-Marcos, F.; Banares, M.A.

    2011-01-01

    In situ Attenuated Total Reflectance FTIR spectroscopy was used to study the carbonylation of glycerol with urea. Cobalt oxide nanoparticles, Co3O4, hierarchically dispersed on zinc oxide microparticles, ZnO, were used as catalysts. The present work demonstrates that in situ real-time attenuated tot

  16. Chilling injury in stored nectarines and its detection by time-resolved reflectance spectroscopy

    NARCIS (Netherlands)

    Lurie, S.; Vanoli, M.; Dagar, A.; Weksler, A.; Eccher Zerbini, P.C.; Spinelli, L.; Torricelli, A.; Lovati, F.; Feng, R.; Rizzolo, A.

    2011-01-01

    Nectarine fruit after cold storage soften normally, but become dry instead of juicy and can develop flesh browning, bleeding and a gel-like or glassy formation of the flesh near the pit. An experiment was conducted to see if time-resolved reflectance spectroscopy could distinguish these internal dis

  17. Double pulse laser induced breakdown spectroscopy of a solid in water: Effect of hydrostatic pressure on laser induced plasma, cavitation bubble and emission spectra

    Science.gov (United States)

    López-Claros, M.; Dell'Aglio, M.; Gaudiuso, R.; Santagata, A.; De Giacomo, A.; Fortes, F. J.; Laserna, J. J.

    2017-07-01

    There is a growing interest in the development of sensors use in exploration of the deep ocean. Techniques for the chemical analysis of submerged solids are of special interest, as they show promise for subsea mining applications where a rapid sorting of materials found in the sea bottom would improve efficiency. Laser-Induced Breakdown Spectroscopy (LIBS) has demonstrated potential for this application thanks to its unique capability of providing the atomic composition of submerged solids. Here we present a study on the parameters that affect the spectral response of metallic targets in an oceanic pressure environment. Following laser excitation of the solid, the plasma persistence and the cavitation bubble size are considerably reduced as the hydrostatic pressure increases. These effects are of particular concern in dual pulse excitation as reported here, where a careful choice of the interpulse timing is required. Shadowgraphic images of the plasma demonstrate that cavitation bubbles are formed early after the plasma onset and that the effect of hydrostatic pressure is negligible during the early stage of plasma expansion. Contrarily to what is observed at atmospheric pressure, emission spectra observed at high pressures are characterized by self-absorbed atomic lines on continuum radiation resulting from strong radiative recombination in the electron-rich confined environment. This effect is much less evident with ionic lines due to the much higher energy of the levels involved and ionization energy of ions, as well as to the lower extent of absorption effects occurring in the inner part of the plasma, where ionized species are more abundant. As a result of the smaller shorter-lived cavitation bubble, the LIBS intensity enhancement resulting from dual pulse excitation is reduced when the applied pressure increases.

  18. Study on the influence of laser pulse duration in the long nanosecond regime on the laser induced plasma spectroscopy

    Science.gov (United States)

    Elnasharty, I. Y.

    2016-10-01

    By using a high power pulsed fiber laser, this study reports the experimental investigation of the laser-induced plasma characteristics for the laser pulse duration range extended from 40 ns to 200 ns. The experiments were performed with keeping the laser fluence constant at 64 J/cm2. The measurements show that, for the early phase of plasma formation, the spectral line intensities and the continuum emissions as well as the plasma characteristics decay to a certain extent with the increase of the pulse duration. On the other hand, as the plasma evolves in post laser pulse regime, the electron density and the degree of ionization increase slightly for the longer pulses, while the plume temperature is more or less independent from the pulse duration. Furthermore, the ablation characteristics, such as the ablation rate, coincide with the results of plasma characteristics for the different pulse durations. Eventually, with keeping the laser fluence constant at 64 J/cm2, the analytical performance of Laser-Induced Plasma Spectroscopy (LIPS) for the corresponding pulse duration range is examined by using a temporal gating and non-gating analyses. The measurements show that, in the case of gating analysis, all pulse durations yield almost the same range of limits of detections LODs. On the other hand, for non-gating analysis, the longer pulse durations provide lower LODs (better) than the shorter ones by orders of magnitude. Moreover, the calculated absolute limit of detection (LODAbs) for the longest pulse duration (i.e. 200 ns) is lower by approximately factor 2 than that of the shortest one (i.e. 40 ns).

  19. Electron density in amplitude modulated microwave atmospheric plasma jet as determined from microwave interferometry and emission spectroscopy

    Science.gov (United States)

    Faltýnek, J.; Hnilica, J.; Kudrle, V.

    2017-01-01

    Time resolved electron density in an atmospheric pressure amplitude modulated microwave plasma jet is determined using the microwave interferometry method, refined by numerical modelling of the propagation of non-planar electromagnetic waves in the vicinity of a small diameter, dense collisional plasma filament. The results are compared to those from the Stark broadening of the {{\\text{H}}β} emission line. Both techniques show, both qualitatively and quantitatively, a similar temporal evolution of electron density during one modulation period.

  20. Characterization of low temperature graphene synthesis in inductively coupled plasma chemical vapor deposition process with optical emission spectroscopy.

    Science.gov (United States)

    Ma, Yifei; Kim, Daekyoung; Jang, Haegyu; Cho, Sung Min; Chae, Heeyeop

    2014-12-01

    Low-temperature graphene was synthesized at 400 degrees C with inductively coupled plasma chemical vapor deposition (PECVD) process. The effects of plasma power and flow rate of various carbon containing precursors and hydrogen on graphene properties were investigated with optical emission spectroscopy (OES). Various radicals monitored by OES were correlated with graphene film properties such as sheet resistance, I(D)/I(G) ratio of Raman spectra and transparency. C2H2 was used as a main precursor and the increase of plasma power enhanced intensity of carbon (C2) radical OES intensity in plasma, reduced sheet resistance and increased transparency of graphene films. The reduced flow rate of C2H2 decreased sheet resistance and increased transparency of graphene films in the range of this study. H2 addition was found to increase sheet resistance, transparency and attributed to reduction of graphene grain and etching graphene layers. OES analysis showed that C2 radicals contribute to graphite networking and sheet resistance reduction. TEM and AFM were applied to provide credible information that graphene had been successfully grown at low temperature.

  1. Quantitative terahertz time-domain spectroscopy and analysis in chemistry and biology

    DEFF Research Database (Denmark)

    Jepsen, Peter Uhd

    2005-01-01

    crystals and biological material. In order to obtain quantitative results great care in the analysis of the experimental data is required. I will discuss common pitfalls in the analysis of THz-TDS data as well as the influence of electronic and laser noise on the results of a THz-TDS experiment.......I will describe how Terahertz Time-Domain Spectroscopy (THz-TDS) can be used for quantitative, broadband spectroscopy in the far-infrared spectral region. Thz-TDS is sensitive to long-range, non-covalent interactions in the condensed phase, for instance intermolecular hydrogen bonding in molecular...

  2. Determination of Metals Present in Textile Dyes Using Laser-Induced Breakdown Spectroscopy and Cross-Validation Using Inductively Coupled Plasma/Atomic Emission Spectroscopy

    Directory of Open Access Journals (Sweden)

    K. Rehan

    2017-01-01

    Full Text Available Laser-induced breakdown spectroscopy (LIBS was used for the quantitative analysis of elements present in textile dyes at ambient pressure via the fundamental mode (1064 nm of a Nd:YAG pulsed laser. Three samples were collected for this purpose. Spectra of textile dyes were acquired using an HR spectrometer (LIBS2000+, Ocean Optics, Inc. having an optical resolution of 0.06 nm in the spectral range of 200 to 720 nm. Toxic metals like Cr, Cu, Fe, Ni, and Zn along with other elements like Al, Mg, Ca, and Na were revealed to exist in the samples. The %-age concentrations of the detected elements were measured by means of standard calibration curve method, intensities of every emission from every species, and calibration-free (CF LIBS approach. Only Sample 3 was found to contain heavy metals like Cr, Cu, and Ni above the prescribed limit. The results using LIBS were found to be in good agreement when compared to outcomes of inductively coupled plasma/atomic emission spectroscopy (ICP/AES.

  3. Real-time measurement of materials properties at high temperatures by laser produced plasmas

    Science.gov (United States)

    Kim, Yong W.

    1990-01-01

    Determination of elemental composition and thermophysical properties of materials at high temperatures, as visualized in the context of containerless materials processing in a microgravity environment, presents a variety of unusual requirements owing to the thermal hazards and interferences from electromagnetic control fields. In addition, such information is intended for process control applications and thus the measurements must be real time in nature. A new technique is described which was developed for real time, in-situ determination of the elemental composition of molten metallic alloys such as specialty steel. The technique is based on time-resolved spectroscopy of a laser produced plasma (LPP) plume resulting from the interaction of a giant laser pulse with a material target. The sensitivity and precision were demonstrated to be comparable to, or better than, the conventional methods of analysis which are applicable only to post-mortem specimens sampled from a molten metal pool. The LPP technique can be applied widely to other materials composition analysis applications. The LPP technique is extremely information rich and therefore provides opportunities for extracting other physical properties in addition to the materials composition. The case in point is that it is possible to determine thermophysical properties of the target materials at high temperatures by monitoring generation and transport of acoustic pulses as well as a number of other fluid-dynamic processes triggered by the LPP event. By manipulation of the scaling properties of the laser-matter interaction, many different kinds of flow events, ranging from shock waves to surface waves to flow induced instabilities, can be generated in a controllable manner. Time-resolved detection of these events can lead to such thermophysical quantities as volume and shear viscosities, thermal conductivity, specific heat, mass density, and others.

  4. Space-time evolution of ejected plasma for the triggering of gas switch

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Shanhong, E-mail: liushanhong108098@163.com; Liu, Xuandong; Shen, Xi; Feng, Lei; Zhang, Qiaogen [State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Institute of High Voltage Technology, Xi' an Jiaotong University, Xi' an 710049 (China); Tie, Weihao [Xi' an Electrical Engineering Research Institute, Xi' an 710049 (China)

    2016-06-15

    Ejected plasma has been widely applied to the discharge process of gas spark switches as a trigger technology, and the development process of ejected plasma has a direct and important effect on the discharge characteristics of gas switches. In this paper, both the injection characteristics and space-time evolution of ejected plasma for the triggering of gas spark switch with different stored energies, pulse polarities, and pressures are studied. The discharge characteristics and breakdown process of a gas switch ignited by ejected plasma under different working coefficients are also discussed briefly. The results show that stored energy has significant influence on the characteristics of ejected plasma. With the increase of stored energy, the propulsion mode of ejected plasma in the axial direction transforms from “plasmoid” to “plasma flow,” and the distribution of the ejected plasma goes through “cloud,” “core-cloud,” and “branch” in sequence. The velocity of ejected plasma under negative pulse polarity is obviously higher than that under positive pulse polarity, especially at the very beginning time. The radial dimensions of ejected plasma under two kinds of pulse polarities follow the similar varying pattern over time, which increase first and then decrease, assuming an inverted “U”-shaped curve. With the increase of pressure, the velocity of ejected plasma significantly decreases and the “branch” channels droop earlier. Applying the ejected plasma to the triggering of a gas switch, the switch can be triggered reliably in a much wide working coefficient range of 10%–90%. With the increase of working coefficient, the breakdown process of the switch translates from slow working mode to fast working mode, and the delay time reduces from tens of μs to hundreds of ns.

  5. Space-time evolution of ejected plasma for the triggering of gas switch

    Science.gov (United States)

    Liu, Shanhong; Liu, Xuandong; Shen, Xi; Feng, Lei; Tie, Weihao; Zhang, Qiaogen

    2016-06-01

    Ejected plasma has been widely applied to the discharge process of gas spark switches as a trigger technology, and the development process of ejected plasma has a direct and important effect on the discharge characteristics of gas switches. In this paper, both the injection characteristics and space-time evolution of ejected plasma for the triggering of gas spark switch with different stored energies, pulse polarities, and pressures are studied. The discharge characteristics and breakdown process of a gas switch ignited by ejected plasma under different working coefficients are also discussed briefly. The results show that stored energy has significant influence on the characteristics of ejected plasma. With the increase of stored energy, the propulsion mode of ejected plasma in the axial direction transforms from "plasmoid" to "plasma flow," and the distribution of the ejected plasma goes through "cloud," "core-cloud," and "branch" in sequence. The velocity of ejected plasma under negative pulse polarity is obviously higher than that under positive pulse polarity, especially at the very beginning time. The radial dimensions of ejected plasma under two kinds of pulse polarities follow the similar varying pattern over time, which increase first and then decrease, assuming an inverted "U"-shaped curve. With the increase of pressure, the velocity of ejected plasma significantly decreases and the "branch" channels droop earlier. Applying the ejected plasma to the triggering of a gas switch, the switch can be triggered reliably in a much wide working coefficient range of 10%-90%. With the increase of working coefficient, the breakdown process of the switch translates from slow working mode to fast working mode, and the delay time reduces from tens of μs to hundreds of ns.

  6. Research of biological liquid albumin based on terahertz time domain spectroscopy

    Science.gov (United States)

    Yang, Shuai; Liu, Shang-jian; Zuo, Jian; Zhang, Cun-lin

    2016-11-01

    There is no corresponding fingerprint characteristic spectrum detecting complex ensemble biological samples in liquid, in the paper, such urine of kidney disease patients as samples of the research, using terahertz time-domain spectroscopy emphatically explores response characteristics of the urine albumin in the terahertz spectrum characteristics, and combined with stoichiometric method, we find a certain kind of relationship between terahertz spectrum data and the content of urine albumin, which offsets the defects of other spectroscopy in measuring liquid protein, and in accordance with hospital clinical data. This study established a semi-qualitative method of using terahertz spectroscopy in detecting non-purification of biological liquid sample, which provides a simple, nondestructive, cheap and fast reference method in identifying the early nephropathy for medical test.

  7. Characteristics of THz carrier dynamics in GaN thin film and ZnO nanowires by temperature dependent terahertz time domain spectroscopy measurement

    Science.gov (United States)

    Balci, Soner; Baughman, William; Wilbert, David S.; Shen, Gang; Kung, Patrick; Kim, Seongsin Margaret

    2012-12-01

    We present a comprehensive study of the characteristics of carrier dynamics using temperature dependent terahertz time domain spectroscopy. By utilizing this technique in combination with numerical calculations, the complex refractive index, dielectric function, and conductivity of n-GaN, undoped ZnO NWs, and Al-doped ZnO NWs were obtained. The unique temperature dependent behaviors of major material parameters were studied at THz frequencies, including plasma frequency, relaxation time, carrier concentration and mobility. Frequency and temperature dependent carrier dynamics were subsequently analyzed in these materials through the use of the Drude and the Drude-Smith models.

  8. Windowing of THz time-domain spectroscopy signals: A study based on lactose

    Science.gov (United States)

    Vázquez-Cabo, José; Chamorro-Posada, Pedro; Fraile-Peláez, Francisco Javier; Rubiños-López, Óscar; López-Santos, José María; Martín-Ramos, Pablo

    2016-05-01

    Time-domain spectroscopy has established itself as a reference method for determining material parameters in the terahertz spectral range. This procedure requires the processing of the measured time-domain signals in order to estimate the spectral data. In this work, we present a thorough study of the properties of the signal windowing, a step previous to the parameter extraction algorithm, that permits to improve the accuracy of the results. Lactose has been used as sample material in the study.

  9. Time-resolved fluorescence spectroscopy of oil spill detected by ocean lidar

    Science.gov (United States)

    Li, Xiao-long; Chen, Yong-hua; Li, Jie; Jiang, Jingbo; Ni, Zuotao; Liu, Zhi-shen

    2016-10-01

    Based on time-resolved fluorescence of oils, an oceanographic fluorescence Lidar was designed to identify oil pollutions. A third harmonic (at 355nm) of Nd:YAG laser is used as the excitation source, and the fluorescence intensities and lifetimes of oil fluorescence at wavelength from 380 nm to 580 nm are measured by an intensified CCD (ICCD). In the experiments, time-resolved fluorescence spectra of 20 oil samples, including crude oils, fuel oils, lubricating oil, diesel oils and gasoline, are analyzed to discuss fluorescence spectral characteristics of samples for oil classification. The spectral characteristics of oil fluorescence obtained by ICCD with delay time of 2 ns, 4 ns, and 6 ns were studied by using the principal component analysis (PCA) method. Moreover, an efficient method is used to improve the recognition rate of the oil spill types, through enlarging spectral differences of oil fluorescence at different delay times. Experimental analysis shows that the optimization method can discriminate between crude oil and fuel oil, and a more accurate classification of oils is obtained by time-resolved fluorescence spectroscopy. As the result, comparing to traditional fluorescence spectroscopy, a higher recognition rate of oil spill types is achieved by time-resolved fluorescence spectroscopy which is also a feasibility technology for Ocean Lidar.

  10. Atomic hydrogen and diatomic titanium-monoxide molecular spectroscopy in laser-induced plasma

    Science.gov (United States)

    Parigger, Christian G.; Woods, Alexander C.

    2017-03-01

    This article gives a brief review of experimental studies of hydrogen Balmer series emission spectra. Ongoing research aims to evaluate early plasma evolution following optical breakdown in laboratory air. Of interest is as well laser ablation of metallic titanium and characterization of plasma evolution. Emission of titanium monoxide is discussed together with modeling of diatomic spectra to infer temperature. The behavior of titanium particles in plasma draws research interests ranging from the modeling of stellar atmospheres to the enhancement of thin film production via pulsed laser deposition.

  11. Optical time of flight studies of lithium plasma in double pulse laser ablation: Evidence of inverse Bremsstrahlung absorption

    Energy Technology Data Exchange (ETDEWEB)

    Sivakumaran, V.; Joshi, H. C.; Singh, R. K.; Kumar, Ajai, E-mail: ajai@ipr.res.in [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India)

    2014-06-15

    The early stage of formation of lithium plasma in a collinear—double pulse laser ablation mode has been studied using optical time of flight (OTOF) spectroscopy as a function of inter-pulse delay time, the distance from the target surface and the fluence of the ablation lasers. The experimental TOF measurements were carried out for lithium neutral (670.8 nm and 610.3 nm), and ionic (548.4 nm and 478.8 nm) lines. These experimental observations have been compared with that for single pulse laser ablation mode. It is found that depending on the fluence and laser pulse shape of the first pre-ablation laser and the second main ablation laser, the plasma plume formation and its characteristic features can be described in terms of plume-plume or laser-plume interaction processes. Moreover, the enhancement in the intensity of Li neutral and ionic lines is observed when the laser-plume interaction is the dominant process. Here, we see the evidence of the role of inverse Bremsstrahlung absorption process in the initial stage of formation of lithium plasma in this case.

  12. A Study of Electron and Phonon Dynamics by Broadband Two-Dimensional THz Time-Domain Spectroscopy

    Science.gov (United States)

    Fu, Zhengping

    Terahertz (THz) wave interacts with semiconductors in many ways, such as resonant excitation of lattice vibration, intraband transition and polaron formation. Different from the optical waves, THz wave has lower photon energy (1 THz = 4.14 meV) and is suitable for studying dynamics of low-energy excitations. Recently the studies of the interaction of THz wave and semiconductors have been extending from the linear regime to the nonlinear regime, owing to the advance of the high-intensity THz generation and detection methods. Two-dimensional (2D) spectroscopy, as a useful tool to unravel the nonlinearity of materials, has been well developed in nuclear magnetic resonance and infrared region. However, the counterpart in THz region has not been well developed and was only demonstrated at frequency around 20 THz due to the lack of intense broadband THz sources. Using laser-induced plasma as the THz source, we developed collinear broadband 2D THz time-domain spectroscopy covering from 0.5 THz to 20 THz. Broadband intense THz pulses emitted from laser-induced plasma provide access to a variety of nonlinear properties of materials. Ultrafast optical and THz pulses make it possible to resolve the transient change of the material properties with temporal resolution of tens of femtoseconds. This thesis focuses on the linear and nonlinear interaction of the THz wave with semiconductors. Since a great many physical processes, including vibrational motion of lattice and plasma oscillation, has resonant frequency in the THz range, rich physics can be studies in our experiment. The thesis starts from the linear interaction of the THz wave with semiconductors. In the narrow band gap semiconductor InSb, the plasma absorption edge, Restrahlen band and dispersion of polaritons are observed. The nonlinear response of InSb in high THz field is verified in the frequency-resolved THz Z-scan experiment. The third harmonic generations due to the anharmonicity of plasma oscillation and the

  13. Measurements of egg shell plasma parameters using laser-induced breakdown spectroscopy

    Indian Academy of Sciences (India)

    Wenfeng Luo; Xiaoxia Zhao; Shuyuan Lv; Haiyan Zhu

    2015-07-01

    Measurements of 1064 nm laser-induced egg shell plasma parameters are presented in this paper. Of special interests were its elemental identification and the determination of spectroscopic temperature and electron density. The electron temperature of 5956 K was inferred using an improved iterative Boltzmann plot method with six calcium atomic emission lines, and the electron number density of 6.1 × 1016 cm−3 was determined by measuring the width of Stark-broadened once-ionized calcium line at 393.37 nm. Based on the experimental results, the laser-induced egg shell plasma was verified to be optically thin and satisfy local thermodynamic equilibrium (LTE). Furthermore, experiments also demonstrated that the loss of energy due to the reflection of the laser beam from the plasma can be neglected and the inverse bremsstrahlung (IB) absorption was the dominant mechanism of plasma heating at the IR wavelength.

  14. Dose-time relation in BF3 plasma immersion ion implantation

    Science.gov (United States)

    Shao, Jiqun; Round, Mark; Qin, Shu; Chan, Chung

    1995-03-01

    Etching and deposition rates of silicon and SiO2 during BF3 plasma immersion ion implantation are measured. The relation between total dose and plasma immersion ion implantation processing time is developed through computer modeling. The results are in very good agreement with the experimental data. Comparison with a previously published model is also given.

  15. Investigation of hydrogen atom addition to vinyl monomers by time resolved ESR spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Beckert, D.; Mehler, K.

    1983-07-01

    By means of time resolved ESR spectroscopy in the microsecond time scale the H atom addition to different vinyl monomers was investigated. The H atoms produced by pulse radiolysis of aqueous solutions show a strong recombination CIDEP effect which also allows the recombination rate constant of H atoms to be determined. By analysis of ESR time profiles with the modified Bloch equations the relaxation times T/sub 1/, T/sub 2/, the polarization factors and the chemical rate constants with scavengers were obtained. Besides the H atom addition rate constants to different vinyl monomers the structure of the monomer radical was determined for acrylic acid.

  16. Time-resolved terahertz spectroscopy of conjugated polymer/CdSe nanorod composites

    DEFF Research Database (Denmark)

    Cooke, David; Lek, Jun Y.; Krebs, Frederik C

    2010-01-01

    report ultrafast carrier dynamics in hybrid CdSe nanorod / poly(3-hexythiophene) (P3HT) bulk heterojunction films measured by time-resolved terahertz spectroscopy, and compare to the well studied P3HT/phenyl-C61-butyric acid methyl ester (PCBM) blend. Both films show an improved peak photoconduct......report ultrafast carrier dynamics in hybrid CdSe nanorod / poly(3-hexythiophene) (P3HT) bulk heterojunction films measured by time-resolved terahertz spectroscopy, and compare to the well studied P3HT/phenyl-C61-butyric acid methyl ester (PCBM) blend. Both films show an improved peak...... photoconductivity compared to P3HT alone, consistent with efficient charge transfer. The photoconductivity dynamics show fast, picosecond trapping or recombination in the hybrid blend while the all-organic film shows no such loss of mobile charge over ns time scales. The ac conductivity for all samples is well...

  17. Following [FeFe] Hydrogenase Active Site Intermediates by Time-Resolved Mid-IR Spectroscopy.

    Science.gov (United States)

    Mirmohades, Mohammad; Adamska-Venkatesh, Agnieszka; Sommer, Constanze; Reijerse, Edward; Lomoth, Reiner; Lubitz, Wolfgang; Hammarström, Leif

    2016-08-18

    Time-resolved nanosecond mid-infrared spectroscopy is for the first time employed to study the [FeFe] hydrogenase from Chlamydomonas reinhardtii and to investigate relevant intermediates of the enzyme active site. An actinic 355 nm, 10 ns laser flash triggered photodissociation of a carbonyl group from the CO-inhibited state Hox-CO to form the state Hox, which is an intermediate of the catalytic proton reduction cycle. Time-resolved infrared spectroscopy allowed us to directly follow the subsequent rebinding of the carbonyl, re-forming Hox-CO, and determine the reaction half-life to be t1/2 ≈ 13 ± 5 ms at room temperature. This gives direct information on the dynamics of CO inhibition of the enzyme.

  18. Simultaneous reference and differential waveform acquisition in time-resolved terahertz spectroscopy

    DEFF Research Database (Denmark)

    Iwaszczuk, Krzysztof; Cooke, David; Fujiwara, Masazumi;

    2009-01-01

    We present a new method for data acquisition in time-resolved terahertz spectroscopy experiments. Our approach is based on simultaneous collection of reference and differential THz scans. Both the optical THz generation beam and the pump beam are modulated at two different frequencies...... that are not harmonic with respect to each other. Our method allows not only twice as fast data acquisition but also minimization of noise connected to slowly varying laser power fluctuations and timing instabilities. Our use of the nonlinear crystal N-benzyl-2-methyl-4-nitroaniline (BNA) enables time-resolved THz...... spectroscopy to beyond 5 THz, thereby highlighting that the presented method is especially valuable at higher frequencies where phase errors in the data acquisition become increasingly important....

  19. CH spectroscopy for carbon chemical erosion analysis in high density low temperature hydrogen plasma

    NARCIS (Netherlands)

    Westerhout, J.; Cardozo, N. J. L.; Rapp, J.; van Rooij, G. J.

    2009-01-01

    The CH A-X molecular band is measured upon seeding the hydrogen plasma in the linear plasma generator Pilot-PSI [electron temperature T-e=0.1-2.5 eV and electron density n(e)=(0.5-5) X 10(20) m(-3)] with methane. Calculated inverse photon efficiencies for these conditions range from 3 up to >10(6

  20. Rapid, Time-Division Multiplexed, Direct Absorption- and Wavelength Modulation-Spectroscopy

    Directory of Open Access Journals (Sweden)

    Alexander Klein

    2014-11-01

    Full Text Available We present a tunable diode laser spectrometer with a novel, rapid time multiplexed direct absorption- and wavelength modulation-spectroscopy operation mode. The new technique allows enhancing the precision and dynamic range of a tunable diode laser absorption spectrometer without sacrificing accuracy. The spectroscopic technique combines the benefits of absolute concentration measurements using calibration-free direct tunable diode laser absorption spectroscopy (dTDLAS with the enhanced noise rejection of wavelength modulation spectroscopy (WMS. In this work we demonstrate for the first time a 125 Hz time division multiplexed (TDM-dTDLAS-WMS spectroscopic scheme by alternating the modulation of a DFB-laser between a triangle-ramp (dTDLAS and an additional 20 kHz sinusoidal modulation (WMS. The absolute concentration measurement via the dTDLAS-technique allows one to simultaneously calibrate the normalized 2f/1f-signal of the WMS-technique. A dTDLAS/WMS-spectrometer at 1.37 µm for H2O detection was built for experimental validation of the multiplexing scheme over a concentration range from 50 to 3000 ppmV (0.1 MPa, 293 K. A precision of 190 ppbV was achieved with an absorption length of 12.7 cm and an averaging time of two seconds. Our results show a five-fold improvement in precision over the entire concentration range and a significantly decreased averaging time of the spectrometer.

  1. Rapid, time-division multiplexed, direct absorption- and wavelength modulation-spectroscopy.

    Science.gov (United States)

    Klein, Alexander; Witzel, Oliver; Ebert, Volker

    2014-11-14

    We present a tunable diode laser spectrometer with a novel, rapid time multiplexed direct absorption- and wavelength modulation-spectroscopy operation mode. The new technique allows enhancing the precision and dynamic range of a tunable diode laser absorption spectrometer without sacrificing accuracy. The spectroscopic technique combines the benefits of absolute concentration measurements using calibration-free direct tunable diode laser absorption spectroscopy (dTDLAS) with the enhanced noise rejection of wavelength modulation spectroscopy (WMS). In this work we demonstrate for the first time a 125 Hz time division multiplexed (TDM-dTDLAS-WMS) spectroscopic scheme by alternating the modulation of a DFB-laser between a triangle-ramp (dTDLAS) and an additional 20 kHz sinusoidal modulation (WMS). The absolute concentration measurement via the dTDLAS-technique allows one to simultaneously calibrate the normalized 2f/1f-signal of the WMS-technique. A dTDLAS/WMS-spectrometer at 1.37 µm for H2O detection was built for experimental validation of the multiplexing scheme over a concentration range from 50 to 3000 ppmV (0.1 MPa, 293 K). A precision of 190 ppbV was achieved with an absorption length of 12.7 cm and an averaging time of two seconds. Our results show a five-fold improvement in precision over the entire concentration range and a significantly decreased averaging time of the spectrometer.

  2. Excitation emission and time-resolved fluorescence spectroscopy of selected varnishes used in historical musical instruments.

    Science.gov (United States)

    Nevin, Austin; Echard, Jean-Philippe; Thoury, Mathieu; Comelli, Daniela; Valentini, Gianluca; Cubeddu, Rinaldo

    2009-11-15

    The analysis of various varnishes from different origins, which are commonly found on historical musical instruments was carried out for the first time with both fluorescence excitation emission spectroscopy and laser-induced time-resolved fluorescence spectroscopy. Samples studied include varnishes prepared using shellac, and selected diterpenoid and triterpenoid resins from plants, and mixtures of these materials. Fluorescence excitation emission spectra have been collected from films of naturally aged varnishes. In parallel, time-resolved fluorescence spectroscopy of varnishes provides means for discriminating between short- (less than 2.0 ns) and long-lived (greater than 7.5 ns) fluorescence emissions in each of these complex materials. Results suggest that complementary use of the two non destructive techniques allows a better understanding of the main fluorophores responsible for the emission in shellac, and further provides means for distinguishing the main classes of other varnishes based on differences in fluorescence lifetime behaviour. Spectrofluorimetric data and time resolved spectra presented here may form the basis for the interpretation of results from future in situ fluorescence examination and time resolved fluorescence imaging of varnished musical instruments.

  3. Rapid, Time-Division Multiplexed, Direct Absorption- and Wavelength Modulation-Spectroscopy

    Science.gov (United States)

    Klein, Alexander; Witzel, Oliver; Ebert, Volker

    2014-01-01

    We present a tunable diode laser spectrometer with a novel, rapid time multiplexed direct absorption- and wavelength modulation-spectroscopy operation mode. The new technique allows enhancing the precision and dynamic range of a tunable diode laser absorption spectrometer without sacrificing accuracy. The spectroscopic technique combines the benefits of absolute concentration measurements using calibration-free direct tunable diode laser absorption spectroscopy (dTDLAS) with the enhanced noise rejection of wavelength modulation spectroscopy (WMS). In this work we demonstrate for the first time a 125 Hz time division multiplexed (TDM-dTDLAS-WMS) spectroscopic scheme by alternating the modulation of a DFB-laser between a triangle-ramp (dTDLAS) and an additional 20 kHz sinusoidal modulation (WMS). The absolute concentration measurement via the dTDLAS-technique allows one to simultaneously calibrate the normalized 2f/1f-signal of the WMS-technique. A dTDLAS/WMS-spectrometer at 1.37 μm for H2O detection was built for experimental validation of the multiplexing scheme over a concentration range from 50 to 3000 ppmV (0.1 MPa, 293 K). A precision of 190 ppbV was achieved with an absorption length of 12.7 cm and an averaging time of two seconds. Our results show a five-fold improvement in precision over the entire concentration range and a significantly decreased averaging time of the spectrometer. PMID:25405508

  4. Shock formation in magnetised electron-positron plasmas: mechanism and timing

    Science.gov (United States)

    Stockem Novo, A.; Bret, A.; Sinha, U.

    2016-10-01

    The shock formation process in electron-positron pair plasmas is investigated in the presence of an ambient perpendicular magnetic field. In initially unmagnetised plasmas, which are dominated by the Weibel or filamentation instability, the shock formation time is a multiple of the saturation time of the linear instability. While in weakly magnetised plasmas the mechanism is still the same, higher magnetisations induce synchrotron maser modes such that the shock formation is dominated by magnetic reflection. As a consequence the formation times are reduced. The focus is on the detailed picture of the particle kinetics, in which the transition between Weibel and magneto-hydrodynamic shocks can be clearly identified.

  5. Analysis of experimental tendinitis in rats treated with laser and platelet-rich plasma therapies by Raman spectroscopy and histometry.

    Science.gov (United States)

    de Carvalho, Paula Kariluce; Silveira, Landulfo; Barbosa, Danillo; Munin, Egberto; Salgado, Miguel Angel Castillo; Villaverde, Antonio Balbin

    2016-01-01

    The objective of this controlled experimental study was to analyze the changes in the Achilles tendons of rats with experimentally induced tendinitis after treatment with platelet-rich plasma (PRP) and/or laser therapies by histometry to quantify fibroblasts and by Raman spectroscopy to determine the biochemical concentration of collagen types I and III. Fifty-four male Wistar rats were divided into six treatment groups: control (G1); PRP only (G2); irradiation with 660 nm laser (G3); irradiation with 830 nm laser (G4); PRP plus 660 nm laser irradiation (G5); and PRP plus 830 nm laser irradiation (G6). Injuries (partial tenotomy) were inflicted in the middle third of the Achilles tendon, with PRP added prior to suture in the appropriate experimental groups. A diode laser (model Laser Flash® III, DMC Equipamentos Ltda, São Carlos, SP, Brazil) that can be operated in two wavelengths 660 and 830 nm was used for irradiation treatments. The irradiation protocol was energy density of 70 J/cm², 20 s irradiation time, and 0.028 cm² spot area, per point in three points in the injured. The histometry was made in micrographical images of the H&E stained sections and evaluated by ImageJ (version 1.46r)®. Raman spectra were collected using a dispersive spectrometer at 830 nm excitation, 200 mW power, and 10 s integration time (P-1 Raman system, Lambda Solutions, Inc. MA, USA). The relative amount of type I collagen was significantly greater in the PRP plus 830 nm laser irradiation group (468 ± 188) than in the control (147 ± 137), 630 nm laser only (191 ± 117), and 830 nm laser only (196 ± 106) groups (p < 0.01), while the quantity of type III collagen was significantly greater in the PRP-only group compared to both irradiated groups without PRP (p < 0.05). Treatment with PRP combined with irradiation at 830 nm resulted in a larger number of fibroblasts and increased concentration of type I collagen, thus accelerating the healing of the injured

  6. Delay time embedding of mass loss avalanches in a fusion plasma-oriented sandpile model

    Science.gov (United States)

    Bowie, C. A.; Dendy, R. O.; Hole, M. J.

    2016-10-01

    The sandpile paradigm is widely used to model aspects of the phenomenology of magnetically confined fusion (MCF) plasmas, including enhanced confinement, edge pedestals and, potentially, the impulsive energy and particle release process known as ELMing. Here we identify new points of contact between ELMing and the systemwide avalanches in a sandpile. We compare the quantified response [Calderon et al., Phys. Plasmas 20, 042306 (2014)] to increased fuelling of the time sequence of edge localised mode events in a series of similar Joint European Torus plasmas with the response to increased fuelling of the time sequence of systemwide avalanches in a sandpile model [Chapman et al., Phys. Rev. Lett. 86, 2814 (2001)] that has well established links to MCF plasma phenomenology. Both the probability density functions of inter-event time intervals, and delay time embeddings of event time sequences, at different fuelling rates, show common features and point to shared underlying physics.

  7. Spectroscopy of a plasma formed in the vicinity of implosion of the shock wave generated by underwater electrical explosion of spherical wire array

    Energy Technology Data Exchange (ETDEWEB)

    Antonov, O.; Efimov, S.; Gurovich, V. Tz.; Krasik, Ya. E. [Physics Department, Technion, Haifa 32000 (Israel); Bernshtam, V. [Weizmann Institute of Science, Rehovot 76100 (Israel)

    2015-05-15

    The results of visible spectroscopy of the plasma formed inside a copper capillary placed at the equatorial plane of an underwater electrically exploded spherical wire array (30 mm in diameter; 40 wires, each of 100 μm in diameter) are reported. In the experiments, a pulsed power generator with current amplitude of ∼300 kA and rise time of ∼1.1 μs was used to produce wire array explosion accompanied by the formation of a converging strong shock wave. The data obtained support the assumption of uniformity of the shock wave along the main path of its convergence. The spectroscopic measurements show that this rather simple method of formation of a converging strong shock wave can be used successfully for studying the shock wave's interaction with matter and the evaporation processes of atoms from a target.

  8. Influence of Dupree diffusivity on the occurrence scattering time advance in turbulent plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Myoung-Jae [Department of Physics and Research Institute for Natural Sciences, Hanyang University, Seoul 04763 (Korea, Republic of); Jung, Young-Dae, E-mail: ydjung@hanyang.ac.kr [Department of Applied Physics and Department of Bionanotechnology, Hanyang University, Ansan, Kyunggi-Do 15588, South Korea and Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, 110 8th Street, Troy, New York 12180-3590 (United States)

    2015-12-15

    The influence of Dupree diffusivity on the occurrence scattering time advance for the electron-ion collision is investigated in turbulent plasmas. The second-order eikonal method and the effective Dupree potential term associated with the plasma turbulence are employed to obtain the occurrence scattering time as a function of the diffusion coefficient, impact parameter, collision energy, thermal energy, and Debye length. The result shows that the occurrence scattering time advance decreases with an increase of the Dupree diffusivity. Hence, we have found that the influence of plasma turbulence diminishes the occurrence time advance in forward electron-ion collisions in thermal turbulent plasmas. The occurrence time advance shows that the propensity of the occurrence time advance increases with increasing scattering angle. It is also found that the effect of turbulence due to the Dupree diffusivity on the occurrence scattering time advance decreases with an increase of the thermal energy. In addition, the variation of the plasma turbulence on the occurrence scattering time advance due to the plasma parameters is also discussed.

  9. The use of laser-induced shock wave plasma spectroscopy (LISPS) for examining physical characteristics of pharmaceutical products

    Energy Technology Data Exchange (ETDEWEB)

    Abdulmadjid, Syahrun Nur, E-mail: syahrun-madjid@yahoo.com; Lahna, Kurnia, E-mail: kurnialahna@gmail.com [Department of Physics, Faculty of Mathematics and Natural Sciences, Syiah Kuala University, Darussalam, Banda Aceh 23111, Aceh (Indonesia); Desiyana, Lydia Septa, E-mail: lydia-septa@yahoo.com [Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Syiah Kuala University, Darussalam, Banda Aceh 23111, Aceh (Indonesia)

    2016-03-11

    An experimental study has been performed to examine the physical characteristics of pharmaceutical products, such as tablet, by employing an emission plasma induced by Nd-YAG laser at a low pressure of Helium gas. The hardness of tablet is one of the parameters that examined during the production process for standard quality of pharmaceutical products. In the Laser-Induced Shock Wave Plasma Spectroscopy (LISPS), the shock wave has a significant role in inducing atomic excitation. It was known that, the speed of the shock wavefront depends on the hardness of the sample, and it correlates with the ionization rate of the ablated atoms. The hardness of the tablet is examined using the intensity ratio between the ion of Mg (II) 275.2 nm and the neutral of Mg (I) 285.2 nm emission lines detected from the laser-induced plasma. It was observed that the ratio changes with respect to the change in the tablet hardness, namely the ratio is higher for the hard tablet. Besides the ratio measurements, we also measured the depth profile of a tablet by focusing 60 shots of irradiation of laser light at a fixed position on the surface of the tablet. It was found that the depth profile varies differently with the hardness of the tablet. These experiment results show that the technique of LISPS can be applied to examine the quality of pharmaceutical products.

  10. Fabry-Perot spectroscopy for kinetic temperature and velocity measurements of a high enthalpy air plasma flow

    Science.gov (United States)

    Zander, Fabian; Löhle, Stefan; Hermann, Tobias; Fulge, Hannes

    2017-08-01

    The atomic translational temperatures and velocities of a low pressure, high enthalpy air plasma are measured using Fabry-Perot spectroscopy. The measurements presented here are the first measurements using this system at this enthalpy level. The sub-picometre resolution of the unique system has allowed accurate translational temperature and velocity measurements of the atomic species in the plasma. The detection system allows the Doppler broadening of multiple atomic nitrogen and oxygen lines to be measured simultaneously. Additionally, having two optical paths, one perpendicular to the flow and one at 45 deg. allows the Doppler shift to be measured. Measurements were taken during three different plasma wind tunnel tests. Mean atomic nitrogen temperatures of 1.08+/- 0.11 × 104 K and atomic oxygen translational temperatures of 1.23+/- 0.12 ×104 K were measured. The thermal non-equilibrium determined verified earlier measurements of the same phenomena, however, the mechanism behind this has not yet been determined. The mean measured flow velocity was 3350+/- 840~m~s-1 and was consistent between the atomic species. The translational temperature and velocity contribute approximately 35% of the local enthalpy of the flow. The direct measurement of these parameters, removing previously required assumptions, increases the fidelity of the flow characterisation significantly. This allows high quality testing to be conducted in this flow field.

  11. Diagnosis of Methane Plasma Generated in an Atmospheric Pressure DBD Micro-Jet by Optical Emission Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jun-Feng; BIAN Xin-Chao; CHEN Qiang; LIU Fu-Ping; LIU Zhong-Wei

    2009-01-01

    Diagnosis of methane plasma,generated in an atmospheric pressure dielectric barrier discharge (DBD) microplasma jet with a quartz tube as dielectric material by a 25 kHz sinusoidal ac power source,is conducted by optical emission spectroscopy (OES).The reactive radicals in methane plasma such as CH,C2,and Ha are detected insitu by OES.The possible dissociation mechanism of methane in diluted Ar plasma is deduced from spectra.In addition,the density of CH radical,which is considered as one of the precursors in diamond-like (DLC) film formation,affected by the parameters of input voltage and the feed gas flow rate,is emphasized. With the Boltzmann plots,four Ar atomic spectral lines (located at 675.28nm,687.13nm,738.40nm and 794.82nm,respectively) are chosen to calculate the electron temperature,and the dependence of electron temperature on discharge parameters is also investigated.

  12. Qualitative and quantitative spectro-chemical analysis of dates using UV-pulsed laser induced breakdown spectroscopy and inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Mehder, A O; Habibullah, Y B; Gondal, M A; Baig, Umair

    2016-08-01

    Laser Induced Breakdown Spectroscopy (LIBS) is demonstrated for the spectral analysis of nutritional and toxic elements present in several varieties of date fruit samples available in the Saudi Arabia market. The method analyzes the optical emission of a test sample when subjected to pulsed laser ablation. In this demonstration, our primary focus is on calcium (Ca) and magnesium (Mg), as nutritional elements, and on chromium (Cr), as a toxic element. The local thermodynamic equilibrium (LTE) condition was confirmed prior to the elemental characterization of date samples to ensure accuracy of the LIBS analysis. This was achieved by measuring parameters associated with the plasma, such as the electron temperature and the electron number density. These plasma parameters aid interpretation of processes such as ionization, dissociation, and excitation occurring in the plasma plume formed by ablating the date palm sample. The minimum detection limit was established from calibration curves that involved plotting the LIBS signal intensity as a function of standard date samples with known concentrations. The concentration of Ca and Mg detected in different varieties of date samples was between 187 and 515 and 35-196mgL(-1) respectively, while Cr concentration measured between 1.72 and 7.76mgL(-1). In order to optimize our LIBS system, we have studied how the LIBS signal intensity depends on the incident laser energy and the delay time. In order to validate our LIBS analysis results, standard techniques such as inductively coupled plasma mass spectrometry (ICP-MS) were also applied on an identical (duplicate) date samples as those used for the LIBS analysis. The LIBS results exhibit remarkable agreement with those obtained from the ICP-MS analysis. In addition, the finger print wavelengths of other elements present in date samples were also identified and are reported here, which has not been previously reported, to the best of our knowledge. Copyright © 2016 Elsevier B

  13. Emission spectroscopy of an atmospheric pressure plasma jet operated with air at low frequency

    Science.gov (United States)

    Giuliani, L.; Gallego, J. L.; Minotti, F.; Kelly, H.; Grondona, D.

    2015-03-01

    Low-temperature, high-pressure plasma jets have an extensive use in plasma biology and plasma medicine, such as pathogen deactivation, wound disinfection, stopping of bleeding without damage of healthy tissue, acceleration of wound healing, control of bio-film proliferation, etc. In this work, a spectroscopic characterization of a typical plasma jet, operated in air at atmospheric pressure, is reported. Within the spectrum of wavelengths from 200 to 450 nm all remarkable emissions of N2 were monitored. Spectra of the N2 2nd positive system (C3Πu-B3Πg) emitted in air are the most convenient for plasma diagnostics, since they enable to determine electronic Te, rotational Tr and vibrational Tv temperatures by fitting the experimental spectra with the simulated ones. We used SPECAIR software for spectral simulation and obtained the best fit with all these temperatures about 3500K. The conclusion that all temperatures are equal, and its relatively high value, is consistent with the results of a previous work, where it was found that the experimentally determined electrical characteristic was consistent with the model of a thermal arc discharge, together with a highly collisional cathode sheet.

  14. Plasma-mirror frequency-resolved optical gating for simultaneous retrieval of a chirped vacuum-ultraviolet waveform and time-dependent reflectivity

    Institute of Scientific and Technical Information of China (English)

    Ryuji Itakura; Takayuki Kumada; Motoyoshi Nakano; Hiroshi Akagi

    2016-01-01

    We demonstrate that the methodology of frequency-resolved optical gating(FROG) is applicable to time-resolved reflection spectroscopy of a plasma mirror in the vacuum-ultraviolet(VUV) region. Our recent study [R. Itakura et al. Opt. Express 23, 10914(2015)] has shown that a VUV waveform can be retrieved from a VUV reflection spectrogram of a plasma mirror formed on a fused silica(FS) surface by irradiation with an intense femtosecond laser pulse. Simultaneously, the increase in the reflectivity with respect to the Fresnel reflection of the unexcited FS surface can be obtained as a time-dependent reflectivity of the plasma mirror. In this study, we update the FROG analysis procedure using the least-square generalized projections algorithm. This procedure can reach convergence much faster than the previous one and has no aliasing problem. It is demonstrated that a significantly chirped VUV pulse as long as 1 ps can be precisely characterized.

  15. [Possibilities in the differential diagnosis of brain neoplasms using the long and short time sequences of proton magnetic resonance spectroscopy

    NARCIS (Netherlands)

    Gajewicz, W.; Goraj, B.M.

    2004-01-01

    Currently to perform proton magnetic resonance spectroscopy (1H MRS) with single voxel spectroscopy (SVS) technique long and/or short echo time sequences are used in order to provide complementary information. PURPOSE: The aim of the study was to compare the usefulness of STEAM (time echo, TE, 20 ms

  16. Real-time reflectance-difference spectroscopy of GaAs molecular beam epitaxy homoepitaxial growth

    Directory of Open Access Journals (Sweden)

    A. Lastras-Martínez

    2014-03-01

    Full Text Available We report on real time-resolved Reflectance-difference (RD spectroscopy of GaAs(001 grown by molecular beam epitaxy, with a time-resolution of 500 ms per spectrum within the 2.3–4.0 eV photon energy range. Through the analysis of transient RD spectra we demonstrated that RD line shapes are comprised of two components with different physical origins and determined their evolution during growth. Such components were ascribed to the subsurface strain induced by surface reconstruction and to surface stoichiometry. Results reported in this paper render RD spectroscopy as a powerful tool for the study of fundamental processes during the epitaxial growth of zincblende semiconductors.

  17. Low-power Terahertz Time-Domain Spectroscopy with optimized electro-optical detection

    DEFF Research Database (Denmark)

    Gorenflo, Stefan; Hinkov, Iliyana; Lambrecht, Armin

    2005-01-01

    A Terahertz Time-Domain Spectroscopy (THz-TDS) system with electro-optical detector based on a ZnTe crystal is presented. The pump laser is a Ti:Sa laser with pulse duration of approx. 10 fs at a central wavelength of 800 nm. Using an optimized detection configuration, a signal-to-noise ratio bet...... better than 103 is achieved, applying an optical laser power of only 25mW. Several substances can be clearly distinguished on the basis of their specific THz absorption spectra.......A Terahertz Time-Domain Spectroscopy (THz-TDS) system with electro-optical detector based on a ZnTe crystal is presented. The pump laser is a Ti:Sa laser with pulse duration of approx. 10 fs at a central wavelength of 800 nm. Using an optimized detection configuration, a signal-to-noise ratio...

  18. Crystallization of amorphous lactose at high humidity studied by terahertz time domain spectroscopy

    Science.gov (United States)

    McIntosh, Alexander I.; Yang, Bin; Goldup, Stephen M.; Watkinson, Michael; Donnan, Robert S.

    2013-02-01

    We report the first use of terahertz time-domain spectroscopy (THz-TDS) to study the hydration and crystallization of an amorphous molecular solid at high humidity. Lactose in its amorphous and monohydrate forms exhibits different terahertz spectra due to the lack of long range order in the amorphous material. This difference allowed the transformation of amorphous lactose to its monohydrate form at high humidity to be studied in real time. Spectral fitting of frequency-domain data allowed kinetic data to be obtained and the crystallization was found to obey Avrami kinetics. Bulk changes during the crystallization could also be observed in the time-domain.

  19. Low-Cost Real-Time Gas Monitoring Using a Laser Plasma Induced by a Third Harmonic Q-Switched Nd-YAG Laser

    Directory of Open Access Journals (Sweden)

    Syahrun Nur Abdulmadjid

    2005-11-01

    Full Text Available A gas plasma induced by a third harmonic Nd-YAG laser with relatively low pulsed energy (about 10 mJ has favorable characteristics for gas analysis due to its low background characteristics, nevertheless a high power fundamental Nd-YAG laser (100-200 mJ is widely used for laser gas breakdown spectroscopy. The air plasma can be used as a low-cost real-time gas monitoring system such that it can be used to detect the local absolute humidity, while a helium plasma can be used for gas analysis with a high level of sensitivity. A new technique using a helium plasma to improve laser ablation emission spectroscopy is proposed. Namely, the third harmonic Nd-YAG laser is focused at a point located some distance from the target in the 1-atm helium surrounding gas. By using this method, the ablated vapor from the target is excited through helium atoms in a metastable state in the helium plasma.

  20. Real-time tissue differentiation based on optical emission spectroscopy for guided electrosurgical tumor resection

    OpenAIRE

    Spether, Dominik; Scharpf, Marcus; Hennenlotter, Jörg; Schwentner, Christian; Neugebauer, Alexander; Nüßle, Daniela; Fischer, Klaus; Zappe, Hans; Stenzl, Arnulf; Fend, Falko; Seifert, Andreas; Enderle, Markus

    2015-01-01

    Complete surgical removal of cancer tissue with effective preservation of healthy tissue is one of the most important challenges in modern oncology. We present a method for real-time, in situ differentiation of tissue based on optical emission spectroscopy (OES) performed during electrosurgery not requiring any biomarkers, additional light sources or other excitation processes. The analysis of the optical emission spectra, enables the differentiation of healthy and tumorous tissue. By using m...

  1. Detection of pesticides residues in rapeseed oil by terahertz time domain spectroscopy

    Science.gov (United States)

    Xiao-li, Zhao; Jiu-sheng, Li

    2011-02-01

    The absorption spectra of panax notoginseng and glycyrrhiza in the frequency range of 0.2~1.6THz has been measured with terahertz time-domin spectroscopy at room temperature. Simultaneously, the corresponding theoretical spectra were given by using density functional theory methods. It was found that the absorption peaks of the two molecules obtained by theoretical were in good agreement with the experimental results.

  2. Real-time assessment of Krebs cycle metabolism using hyperpolarized 13C magnetic resonance spectroscopy

    OpenAIRE

    Schroeder, Marie A.; Atherton, Helen J; Ball, Daniel R.; Cole, Mark A.; Heather, Lisa C.; Griffin, Julian L; Clarke, Kieran; Radda, George K.; Tyler, Damian J

    2009-01-01

    The Krebs cycle plays a fundamental role in cardiac energy production and is often implicated in the energetic imbalance characteristic of heart disease. In this study, we measured Krebs cycle flux in real time in perfused rat hearts using hyperpolarized magnetic resonance spectroscopy (MRS). [2-13C]Pyruvate was hyperpolarized and infused into isolated perfused hearts in both healthy and postischemic metabolic states. We followed the enzymatic conversion of pyruvate to lactate, acetylcarnitin...

  3. Real-time assessment of Krebs cycle metabolism using hyperpolarized 13C magnetic resonance spectroscopy

    OpenAIRE

    Schroeder, Marie A; Atherton, Helen J.; Ball, Daniel R.; Cole, Mark A; Heather, Lisa C.; Griffin, Julian L.; Clarke, Kieran; Radda, George K; Tyler, Damian J.

    2009-01-01

    The Krebs cycle plays a fundamental role in cardiac energy production and is often implicated in the energetic imbalance characteristic of heart disease. In this study, we measured Krebs cycle flux in real time in perfused rat hearts using hyperpolarized magnetic resonance spectroscopy (MRS). [2-13C]Pyruvate was hyperpolarized and infused into isolated perfused hearts in both healthy and postischemic metabolic states. We followed the enzymatic conversion of pyruvate to lactate, acetylcarnitin...

  4. EBIT spectroscopy of highly charged heavy ions relevant to hot plasmas

    Science.gov (United States)

    Nakamura, Nobuyuki

    2013-05-01

    An electron beam ion trap (EBIT) is a versatile device for studying highly charged ions. We have been using two types of EBITs for the spectroscopic studies of highly charged ions. One is a high-energy device called the Tokyo-EBIT, and another is a compact low-energy device called CoBIT. Complementary use of them enables us to obtain spectroscopic data for ions over a wide charge-state range interacting with electrons over a wide energy range. In this talk, we present EBIT spectra of highly charged ions for tungsten, iron, bismuth, etc., which are relevant to hot plasmas. Tungsten is considered to be the main impurity in the ITER (the next generation nuclear fusion reactor) plasma, and thus its emission lines are important for diagnosing and controlling the ITER plasma. We have observed many previously unreported lines to supply the lack of spectroscopic data of tungsten ions. Iron is one of the main components of the solar corona, and its spectra are used to diagnose temperature, density, etc. The diagnostics is usually done by comparing observed spectra with model calculations. An EBIT can provide spectra under a well-defined condition; they are thus useful to test the model calculations. Laser-produced bismuth plasma is one of the candidates for a soft x-ray source in the water window region. An EBIT has a narrow charge state distribution; it is thus useful to disentangle the spectra of laser-produced plasma containing ions with a wide charge-state range. Performed with the support and under the auspices of the NIFS Collaboration Research program (NIFS09KOAJ003) and JSPS KAKENHI Number 23246165, and partly supported by the JSPS-NRF-NSFC A3 Foresight Program in the field of Plasma Physics.

  5. Time-Resolved Spectroscopy Diagnostic of Laser-Induced Optical Breakdown

    Directory of Open Access Journals (Sweden)

    Christian G. Parigger

    2010-01-01

    Full Text Available Transient laser plasma is generated in laser-induced optical breakdown (LIOB. Here we report experiments conducted with 10.6-micron CO2 laser radiation, and with 1.064-micron fundamental, 0.532-micron frequency-doubled, 0.355-micron frequency-tripled Nd:YAG laser radiation. Characterization of laser induced plasma utilizes laser-induced breakdown spectroscopy (LIBS techniques. Atomic hydrogen Balmer series emissions show electron number density of 1017 cm−3 measured approximately 10 μs and 1 μs after optical breakdown for CO2 and Nd:YAG laser radiation, respectively. Recorded molecular recombination emission spectra of CN and C2 Swan bands indicate an equilibrium temperature in excess of 7000 Kelvin, inferred for these diatomic molecules. Reported are also graphite ablation experiments where we use unfocused laser radiation that is favorable for observation of neutral C3 emission due to reduced C3 cation formation. Our analysis is based on computation of diatomic molecular spectra that includes accurate determination of rotational line strengths, or Hönl-London factors.

  6. Time resolved ESR spectroscopy. ESR pulse radiolysis equipment with microsecond time resolution

    Energy Technology Data Exchange (ETDEWEB)

    Beckert, D.; Mehler, K. (Akademie der Wissenschaften der DDR, Leipzig. Zentralinstitut fuer Isotopen- und Strahlenforschung)

    1983-01-01

    Time resolved ESR experiments allow the study of the chemical kinetics as well as spin dynamics of free radicals in the liquid phase. Starting from the physical and chemical requirements the experimental parameters of a universal time resolved ESR spectrometer are derived. The main components of the ESR pulse radiolysis equipment are described and their technical parameters are discussed. By two experimental examples it is shown that at a time resolution of 0.3 ..mu..s a sensitivity of c/sub min/ = 10/sup -6/ mol dm/sup -3/ for simple radical spectra can be achieved.

  7. Time-resolved rotational spectroscopy of para-difluorobenzene·Ar

    Science.gov (United States)

    Weichert, A.; Riehn, C.; Matylitsky, V. V.; Jarzeba, W.; Brutschy, B.

    2002-07-01

    We report on time-resolved rotational spectroscopy experiments of the cluster para-difluorobenzene·Ar ( pDFB·Ar) by picosecond laser pulses in a supersonic expansion. Rotational coherences of pDFB·Ar are generated by resonant electronic excitation and probed by time-resolved fluorescence depletion spectroscopy and time-resolved photoionization ((1+1') PPI) spectroscopy. The former allows the determination of both ground and excited state rotational constants, whereas the latter technique enables the separate study of the excited state with the benefit of mass-selective detection. Since pDFB·Ar represents a near symmetric oblate rotor, persistent J-type transients with tJ≈ n/2( A+ B) could be measured. From their analysis, (A″+B″)=2234.9±2 MHz and (A'+B')=2237.9±2 MHz were obtained. A structural investigation, based on data of the pDFB monomer, is presented resulting in a pDFB·Ar center-of-mass distance of both moieties of R z=3.543±0.017 Å with a change of ΔR z=-0.057±0.009 Å upon electronic excitation. These results are compared to data of former frequency-resolved experiments and ab initio computations.

  8. In vitro monitoring of time and dose dependent cytotoxicity of aminated nanoparticles using Raman spectroscopy.

    Science.gov (United States)

    Efeoglu, Esen; Casey, Alan; Byrne, Hugh J

    2016-09-21

    Investigation of possible adverse health effects of nanomaterials, in a rapid multi-parametric fashion, has become increasingly important, due to their increased production and potential uses in a wide range of application areas, from cosmetics to pharmaceutics. Although conventional in vitro cytotoxicological techniques provide valuable information about the particle toxicity, the importance of gaining high content information in a single assay with the analysis of multiple parameters in a non-invasive and label-free way is still one of the biggest challenges in nanotoxicology. As a vibrational spectroscopic technique, the power of Raman spectroscopy for the analysis of cells, tissues and also nanoparticle localization within cells has been shown previously. In this study, the ability of Raman spectroscopy to fingerprint the dose and time dependent cellular responses and effect of cytotoxic events on biochemical constituents of the cells is monitored. A549 human lung carcinoma cells and aminated polystyrene nanoparticles (PS-NH2) are used as a model cell line and nanoparticle, respectively. Following the determination of cellular responses in the presence of toxic PS-NH2 by using conventional cellular assays, Alamar Blue (AB) and 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazoliumbromid (MTT), and calculation of EC50 values for both assays, Raman spectroscopy was employed at response related doses and time points. Multiple point spectra from the cytoplasm, nucleus and nucleolus of 20 cells were acquired using Raman spectroscopy for each exposure dose and timepoint. Unsupervised principle components analysis (PCA) was applied to the Raman data sets for the comparison of exposed and unexposed cells as well as different exposure doses and times. The study shows the ability of Raman spectroscopy to provide information about cellular responses at different particle concentrations and exposure times with the aid of multivariate analysis. In the chosen range of

  9. Electron plasmas as a diagnostic tool for hyperfine spectroscopy of antihydrogen

    Science.gov (United States)

    Friesen, T.; Amole, C.; Ashkezari, M. D.; Baquero-Ruiz, M.; Bertsche, W.; Bowe, P. D.; Butler, E.; Capra, A.; Cesar, C. L.; Charlton, M.; Deller, A.; Evetts, N.; Eriksson, S.; Fajans, J.; Fujiwara, M. C.; Gill, D. R.; Gutierrez, A.; Hangst, J. S.; Hardy, W. N.; Hayden, M. E.; Isaac, C. A.; Jonsell, S.; Kurchaninov, L.; Little, A.; Madsen, N.; McKenna, J. T. K.; Menary, S.; Napoli, S. C.; Olchanski, K.; Olin, A.; Pusa, P.; Rasmussen, C. Ø.; Robicheaux, F.; Sarid, E.; Silveira, D. M.; So, C.; Stracka, S.; Thompson, R. I.; van der Werf, D. P.; Wurtele, J. S.

    2013-03-01

    Long term magnetic confinement of antihydrogen atoms has recently been demonstrated by the ALPHA collaboration at CERN, opening the door to a range of experimental possibilities. Of particular interest is a measurement of the antihydrogen spectrum. A precise comparison of the spectrum of antihydrogen with that of hydrogen would be an excellent test of CPT symmetry. One prime candidate for precision CPT tests is the ground-state hyperfine transition; measured in hydrogen to a precision of nearly one part in 1012. Effective execution of such an experiment with trapped antihydrogen requires precise knowledge of the magnetic environment. Here we present a solution that uses an electron plasma confined in the antihydrogen trapping region. The cyclotron resonance of the electron plasma is probed with microwaves at the cyclotron frequency and the subsequent heating of the electron plasma is measured through the plasma quadrupole mode frequency. Using this method, the minimum magnetic field of the neutral trap can be determined to within 4 parts in 104. This technique was used extensively in the recent demonstration of resonant interaction with the hyperfine levels of trapped antihydrogen atoms.

  10. THz spectroscopy of whole blood, plasma and cells in mice of SHR line with various pathology

    Science.gov (United States)

    Panchenko, A.; Tyndyk, M.; Smolyanskaya, O.; Sulatskiy, M.; Kravtsenyuk, O.; Balbekin, N.; Khodzitsky, M.

    2016-08-01

    This paper is devoted to studying of optical properties of whole blood and blood plasma in SHR mice grafted Ehrlich's carcinoma and mice with chronic inflammation at the terahertz frequency range. Additionally physiological saline solution suspension of ascites Ehrlich's carcinoma cells was explored.

  11. Electron plasmas as a diagnostic tool for hyperfine spectroscopy of antihydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Friesen, T.; Thompson, R. I. [Department of Physics and Astronomy, University of Calgary, Calgary AB, T2N 1N4 (Canada); Amole, C.; Capra, A.; Menary, S. [Department of Physics and Astronomy, York University, Toronto ON, M3J 1P3 (Canada); Ashkezari, M. D.; Hayden, M. E. [Department of Physics, Simon Fraser University, Burnaby BC, V5A 1S6 (Canada); Baquero-Ruiz, M.; Fajans, J.; Little, A.; So, C.; Wurtele, J. S. [Department of Physics, University of California, Berkeley, CA 94720-7300 (United States); Bertsche, W. [School of Physics and Astronomy, University of Manchester, M13 9PL Manchester, UK and The Cockcroft Institute, WA4 4AD Warrington (United Kingdom); Bowe, P. D.; Hangst, J. S.; Rasmussen, C. O. [Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark); Butler, E. [Physics Department, CERN, CH-1211 Geneva 23 (Switzerland); Cesar, C. L.; Silveira, D. M. [Instituto de Fisica, Universidade Federal do Rio de Janeiro, Rio de Janeiro 21941-972 (Brazil); Charlton, M. [Department of Physics, College of Science, Swansea University, Swansea SA2 8PP (United Kingdom); and others

    2013-03-19

    Long term magnetic confinement of antihydrogen atoms has recently been demonstrated by the ALPHA collaboration at CERN, opening the door to a range of experimental possibilities. Of particular interest is a measurement of the antihydrogen spectrum. A precise comparison of the spectrum of antihydrogen with that of hydrogen would be an excellent test of CPT symmetry. One prime candidate for precision CPT tests is the ground-state hyperfine transition; measured in hydrogen to a precision of nearly one part in 10{sup 12}. Effective execution of such an experiment with trapped antihydrogen requires precise knowledge of the magnetic environment. Here we present a solution that uses an electron plasma confined in the antihydrogen trapping region. The cyclotron resonance of the electron plasma is probed with microwaves at the cyclotron frequency and the subsequent heating of the electron plasma is measured through the plasma quadrupole mode frequency. Using this method, the minimum magnetic field of the neutral trap can be determined to within 4 parts in 10{sup 4}. This technique was used extensively in the recent demonstration of resonant interaction with the hyperfine levels of trapped antihydrogen atoms.

  12. The role of plasma shielding in collinear double-pulse femtosecond laser-induced breakdown spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Penczak, John [Department of Chemistry (m/c 111), University of Illinois at Chicago, Chicago, IL 60680-7061 (United States); Kupfer, Rotem; Bar, Ilana [Department of Physics, Ben-Gurion University of the Negev, Beer-Sheva 84105 (Israel); Gordon, Robert J. [Department of Chemistry (m/c 111), University of Illinois at Chicago, Chicago, IL 60680-7061 (United States)

    2014-07-01

    We report an experimental and theoretical study of the mechanism for the enhancement of the laser-induced breakdown signal produced by two collinear femtosecond pulses separated by a suitable delay. A bilayer sample consisting of a 500 nm thick film of Ag deposited on Al was used in the experiments, and a particle-in-cell (PIC) simulation was implemented in the theoretical part of the study. Experiments on the effect of laser polarization, performed at a 30° angle of incidence over a wide range of fluences, together with the PIC results, showed that the plasma produced by the first pulse was further excited by the second pulse. Experiments at normal incidence and a fluence of 200 J/cm{sup 2} showed that the second pulse did not penetrate the Ag layer. In addition, measurements of the effect of pulse delay on the signal supported the conclusion that double pulse enhancement is produced by plasma heating rather than by increased surface ablation. - Highlights: • We study the mechanism for collinear double-pulse enhancement of LIBS produced by a fs laser. • We use a bilayer of Ag on Al to determine which region is reached by the 2nd pulse. • Signal enhancement is produced by plasma heating rather than by increased surface ablation. • Particle-in-cell calculations show that plasma shielding plays a key role.

  13. Solid-State 13C NMR Spectroscopy Applied to the Study of Carbon Blacks and Carbon Deposits Obtained by Plasma Pyrolysis of Natural Gas

    Directory of Open Access Journals (Sweden)

    Jair C. C. Freitas

    2016-01-01

    Full Text Available Solid-state 13C nuclear magnetic resonance (NMR spectroscopy was used in this work to analyze the physical and chemical properties of plasma blacks and carbon deposits produced by thermal cracking of natural gas using different types of plasma reactors. In a typical configuration with a double-chamber reactor, N2 or Ar was injected as plasma working gas in the first chamber and natural gas was injected in the second chamber, inside the arc column. The solid residue was collected at different points throughout the plasma apparatus and analyzed by 13C solid-state NMR spectroscopy, using either cross polarization (CP or direct polarization (DP, combined with magic angle spinning (MAS. The 13C CP/MAS NMR spectra of a number of plasma blacks produced in the N2 plasma reactor showed two resonance bands, broadly identified as associated with aromatic and aliphatic groups, with indication of the presence of oxygen- and nitrogen-containing groups in the aliphatic region of the spectrum. In contrast to DP experiments, only a small fraction of 13C nuclei in the plasma blacks are effectively cross-polarized from nearby 1H nuclei and are thus observed in spectra recorded with CP. 13C NMR spectra are thus useful to distinguish between different types of carbon species in plasma blacks and allow a selective study of groups spatially close to hydrogen in the material.

  14. Enhancement of laser-induced breakdown spectroscopy (LIBS) Detection limit using a low-pressure and short-pulse laser-induced plasma process.

    Science.gov (United States)

    Wang, Zhen Zhen; Deguchi, Yoshihiro; Kuwahara, Masakazu; Yan, Jun Jie; Liu, Ji Ping

    2013-11-01

    Laser-induced breakdown spectroscopy (LIBS) technology is an appealing technique compared with many other types of elemental analysis because of the fast response, high sensitivity, real-time, and noncontact features. One of the challenging targets of LIBS is the enhancement of the detection limit. In this study, the detection limit of gas-phase LIBS analysis has been improved by controlling the pressure and laser pulse width. In order to verify this method, low-pressure gas plasma was induced using nanosecond and picosecond lasers. The method was applied to the detection of Hg. The emission intensity ratio of the Hg atom to NO (IHg/INO) was analyzed to evaluate the LIBS detection limit because the NO emission (interference signal) was formed during the plasma generation and cooling process of N2 and O2 in the air. It was demonstrated that the enhancement of IHg/INO arose by decreasing the pressure to a few kilopascals, and the IHg/INO of the picosecond breakdown was always much higher than that of the nanosecond breakdown at low buffer gas pressure. Enhancement of IHg/INO increased more than 10 times at 700 Pa using picosecond laser with 35 ps pulse width. The detection limit was enhanced to 0.03 ppm (parts per million). We also saw that the spectra from the center and edge parts of plasma showed different features. Comparing the central spectra with the edge spectra, IHg/INO of the edge spectra was higher than that of the central spectra using the picosecond laser breakdown process.

  15. Pulse Phase-coherent Timing and Spectroscopy of CXOU J164710.2-45521 Outbursts

    CERN Document Server

    Castillo, Guillermo A Rodríguez; Esposito, Paolo; Pons, José A; Rea, Nanda; Turolla, Roberto; Viganò, Daniele; Zane, Silvia

    2014-01-01

    We present a long-term phase-coherent timing analysis and pulse-phase resolved spectroscopy for the two outbursts observed from the transient anomalous X-ray pulsar CXOU J164710.2-45521. For the first outburst we used 11 Chandra and XMM-Newton observations between September 2006 to August 2009, the longest baseline yet for this source. We obtain a coherent timing solution with $P=10.61065583(4)$ s, $\\dot{P} = 9.72(1) \\times 10^{-13}\\;$s s$^{-1}$ and $\\ddot{P} = -1.05(5)\\times10^{-20}\\; $s s$^{-2}$. Under the standard assumptions this implies a surface dipolar magnetic field of $\\sim 10^{14}$ G, confirming this source as a standard-$B$ magnetar. We also study the evolution of the pulse profile (shape, intensity and pulsed fraction) as a function of time and energy. Using the phase-coherent timing solution we perform a phase-resolved spectroscopy analysis, following the spectral evolution of pulse-phase features, which hints at the physical processes taking place on the star. The results are discussed from the ...

  16. TIME DOMAIN ANALYSIS OF TRANSIENT PROPAGATION IN INHOMOGENEOUS MAGNETIZED PLASMA USING Z-TRANSFORMS

    Institute of Scientific and Technical Information of China (English)

    Huang Shoujiang; Li Fang

    2006-01-01

    The electromagnetic propagation through an inhomogeneous magnetized plasma slab is studied using the Z-transform formulation of the Finite-Difference Time-Domain(FDTD) method. The direction of electromagnetic propagation is parallel to the biasing magnetic filed. To validate the Z-transform algorithm, the reflection and transmission coefficients for the right-hand circularly polarized wave of the homogeneous magnetized plasma slab are computed by means of discrete Fourier transform. The comparison between the reflection and transmission coefficients of the homogeneous plasma slab and analytical values indicates that Z-transform algorithm is very accurate. When the plasma frequency varies according to the square root and parabolic relations, the reflection and transmission coefficients of the inhomogeneous magnetized plasma slab are computed.

  17. Vibrationally resolved UV/Vis spectroscopy with time-dependent density functional based tight binding

    CERN Document Server

    Rüger, Robert; van Lenthe, Erik; Heine, Thomas; Visscher, Lucas

    2016-01-01

    We report a time-dependent density functional based tight-binding (TD-DFTB) scheme for the calculation of UV/Vis spectra, explicitly taking into account the excitation of nuclear vibrations via the harmonic approximation. The theory of vibrationally resolved UV/Vis spectroscopy is first summarized from the viewpoint of TD-DFTB. The method is benchmarked against time-dependent density functional theory (TD-DFT) calculations for strongly dipole allowed excitations in various aromatic and polar molecules. Using the recent 3ob:freq parameter set of Elstner's group, excellent agreement with TD-DFT calculations using local functionals was achieved.

  18. Computationally effective solution of the inverse problem in time-of-flight spectroscopy

    DEFF Research Database (Denmark)

    Kamran, Faisal; Abildgaard, Otto Højager Attermann; Subash, Arman Ahamed

    2015-01-01

    Photon time-of-flight (PTOF) spectroscopy enables the estimation of absorption and reduced scattering coefficients of turbid media by measuring the propagation time of short light pulses through turbid medium. The present investigation provides a comparison of the assessed absorption and reduced...... scattering coefficients from PTOF measurements of intralipid 20% and India ink-based optical phantoms covering a wide range of optical properties relevant for biological tissues and dairy products. Three different models are used to obtain the optical properties by fitting to measured temporal profiles...

  19. Computationally effective solution of the inverse problem in time-of-flight spectroscopy

    DEFF Research Database (Denmark)

    Kamran, Faisal; Abildgaard, Otto Højager Attermann; Subash, Arman Ahamed;

    2015-01-01

    Photon time-of-flight (PTOF) spectroscopy enables the estimation of absorption and reduced scattering coefficients of turbid media by measuring the propagation time of short light pulses through turbid medium. The present investigation provides a comparison of the assessed absorption and reduced...... scattering coefficients from PTOF measurements of intralipid 20% and India ink-based optical phantoms covering a wide range of optical properties relevant for biological tissues and dairy products. Three different models are used to obtain the optical properties by fitting to measured temporal profiles...

  20. Time-resolved terahertz spectroscopy of conjugated polymer/CdSe nanorod composites

    DEFF Research Database (Denmark)

    Cooke, David; Lek, Jun Y.; Krebs, Frederik C

    2010-01-01

    photoconductivity compared to P3HT alone, consistent with efficient charge transfer. The photoconductivity dynamics show fast, picosecond trapping or recombination in the hybrid blend while the all-organic film shows no such loss of mobile charge over ns time scales. The ac conductivity for all samples is well......report ultrafast carrier dynamics in hybrid CdSe nanorod / poly(3-hexythiophene) (P3HT) bulk heterojunction films measured by time-resolved terahertz spectroscopy, and compare to the well studied P3HT/phenyl-C61-butyric acid methyl ester (PCBM) blend. Both films show an improved peak...

  1. Vibrationally resolved UV/Vis spectroscopy with time-dependent density functional based tight binding

    OpenAIRE

    Rüger, Robert; Niehaus, Thomas; van Lenthe, Erik; Heine, Thomas; Visscher, Lucas

    2016-01-01

    We report a time-dependent density functional based tight-binding (TD-DFTB) scheme for the calculation of UV/Vis spectra, explicitly taking into account the excitation of nuclear vibrations via the adiabatic Hessian Franck-Condon (AH|FC) method with a harmonic approximation for the nuclear wavefunction. The theory of vibrationally resolved UV/Vis spectroscopy is first summarized from the viewpoint of TD-DFTB. The method is benchmarked against time-dependent density functional theory (TD-DFT) ...

  2. Hexamethylcyclopentadiene: time-resolved photoelectron spectroscopy and ab initio multiple spawning simulations

    DEFF Research Database (Denmark)

    Wolf, T. J. A.; Kuhlman, Thomas Scheby; Schalk, O.

    2014-01-01

    comparing time-resolved photoelectron spectroscopy (TRPES) with ab initio multiple spawning (AIMS) simulations on the MS-MR-CASPT2 level of theory. We disentangle the relationship between two phenomena that dominate the immediate molecular response upon light absorption: a spectrally dependent delay...... replaced by ‘‘hydrogen atoms’’ having mass 15 and TRPES spectra were calculated. These showed an induction time of (108 10) fs which could directly be assigned to progress along a torsional mode leading to the intersection seam with the molecular ground state. In a stepladder-type approach, the close...

  3. Broadband THz waveguiding and high-precision broadband time-resolved spectroscopy

    DEFF Research Database (Denmark)

    Cooke, David; Iwaszczuk, Krzysztof; Nielsen, Kristian;

    2009-01-01

    , particularly in spectroscopic applications where tight confinement of the THz field is required. We further demonstrate a new spectroscopic technique for ultrafast time-resolved THz time-domain spectroscopy which simultaneously acquires both reference and sample data. By using this scheme we show...... that the influence of fluctuations on the laser parameters during data acquisition can be minimized, and highly reproducible quantitative data can be recorded and extracted in a very efficient manner. This technique may become especially important in the high THz range, where phase noise becomes critical...

  4. Nuclear dynamical correlation effects in X-ray spectroscopy from a time-domain perspective

    CERN Document Server

    Karsten, Sven; Aziz, Saadullah G; Bokarev, Sergey I; Kühn, Oliver

    2016-01-01

    To date X-ray spectroscopy has become a routine tool that can reveal highly local and element-specific information on the electronic structure of atoms in complex environments. Here, we focus on nuclear dynamical effects in X-ray spectra and develop a rigorous time-correlation method employing ground state molecular dynamics simulations. The importance of nuclear correlation phenomena is demonstrated by comparison against the results from the conventional sampling approach for gas phase water. In contrast to the first-order absorption, second-order resonant inelastic scattering spectra exhibit pronounced fingerprints of nuclear motions. The developed methodology does not depend on the accompanying electronic structure method in principle as well as on the spectral range and, thus, can be applied to, e.g., UV and X-ray photo-electron and Auger spectroscopies.

  5. THz Time-Domain Spectroscopy of Mixed CO2-CH3OH Interstellar Ice Analogs

    CERN Document Server

    McGuire, Brett A; Allodi, Marco A; Blake, Geoffrey A

    2016-01-01

    The icy mantles of interstellar dust grains are the birthplaces of the primordial prebiotic molecular inventory that may eventually seed nascent solar systems and the planets and planetesimals that form therein. Here, we present a study of two of the most abundant species in these ices after water: carbon dioxide (CO2) and methanol (CH3OH) using TeraHertz (THz) time-domain spectroscopy and mid-infrared spectroscopy. We study pure and mixed-ices of these species, and demonstrate the power of the THz region of the spectrum to elucidate the long-range structure (i.e. crystalline versus amorphous) of the ice, the degree of segregation of these species within the ice, and the thermal history of the species within the ice. Finally, we comment on the utility of the THz transitions arising from these ices for use in astronomical observations of interstellar ices.

  6. Determination of Silicon in Gasoline by Directly Measuring under Organic Phase Using Inductively Coupled Plasma Optical Emission Spectroscopy.

    Science.gov (United States)

    Zhang, Wen-mei; Wen, Huan; Lü, Huan-ming; Liu, Hui-qin; Lin, Zhi-sheng; Wang, Rong-hua

    2015-03-01

    A simple and accurate method was developed for determining silicon in gasoline using inductively coupled plasma optical emission spectroscopy (ICP-OES). For sample inroduction a Burgener nubulizer and a Cyclonic spray chamber were used. A gasoline sample was diluted with isooctane and then introduced into the cooled spray chamber of the ICP-OES. Good linearity was achieved in the silicon concentration range 0.1 - 10.0 mg x kg(-1), and the correlation coefficient was 0.999 96. The detection limit for silicon was 0.012 mg x kg(-1) and the silicon recoveries from gasoline samples were 95.8% - 98.4%, with relative standard deviations of less than 3.0% The method was proved to be simple, reliable and highly sensitive, and suitable for determining silicon in samples of motor gasoline, ethanol-gasoline and methanol-gasoline fuel mixtures those containing not more than 15% (V/V) oxygenates.

  7. Multiple myeloma detection based on blood plasma surface-enhanced Raman spectroscopy using a portable Raman spectrometer

    Science.gov (United States)

    Chen, Jie; Huang, Meizhen; Zou, Ye; Song, Biao; Wang, Yang; Wang, Kehui; Li, Xia; Liu, Xi; Chen, Xiaofan; Li, Feng; Zhan, Yanxia

    2016-10-01

    The feasibility of surface enhanced Raman spectroscopy (SERS) for multiple myeloma (MM) detection is investigated in this work. SERS measurements of silver nanoparticle mixed blood plasma samples are performed using a low-cost and portable Raman spectrometer. The tentative assignment of Raman peaks indicates an increase in amino acids, nucleic acid base content and a decrease in cholesterol ester in the MM group. Combined with the multivariate analysis method of principle component analysis (PCA) and linear discriminate analysis (LDA), a diagnosis result for 32 samples with a sensitivity of 93.75% and specificity of 87.5% is achieved. The performance of the corresponding receiver operating characteristic (ROC) curve is 0.957. It is a potential rapid and non-invasive method for preliminary MM screening.

  8. Interaction of plasma-generated water cluster ions with chemically-modified Si surfaces investigated by infrared absorption spectroscopy

    Directory of Open Access Journals (Sweden)

    Ayumi Hirano-Iwata

    2016-03-01

    Full Text Available We have investigated the interaction of water cluster ions generated by discharge plasma, with chemically modified Si surfaces using infrared absorption spectroscopy in the multiple internal reflection geometry. We observe that water cluster ions readily adsorb on SiO2-covered Si surfaces to form water droplets. We demonstrate that positively- and negatively-charged cluster ions adsorb on the SiO2-covered Si surface in different manners, indicating ionic interaction of the water droplets with the negatively-charged SiO2 surface. Water droplets formed on the protein-coated surface rupture the amide bond of the proteins, suggesting the function of protein decomposition of water cluster ions.

  9. Interaction of plasma-generated water cluster ions with chemically-modified Si surfaces investigated by infrared absorption spectroscopy

    Science.gov (United States)

    Hirano-Iwata, Ayumi; Matsumura, Ryosuke; Ma, Teng; Kimura, Yasuo; Niwano, Michio; Nishikawa, Kazuo

    2016-03-01

    We have investigated the interaction of water cluster ions generated by discharge plasma, with chemically modified Si surfaces using infrared absorption spectroscopy in the multiple internal reflection geometry. We observe that water cluster ions readily adsorb on SiO2-covered Si surfaces to form water droplets. We demonstrate that positively- and negatively-charged cluster ions adsorb on the SiO2-covered Si surface in different manners, indicating ionic interaction of the water droplets with the negatively-charged SiO2 surface. Water droplets formed on the protein-coated surface rupture the amide bond of the proteins, suggesting the function of protein decomposition of water cluster ions.

  10. Zinc, lead and copper in human teeth measured by induced coupled argon plasma atomic emission spectroscopy (ICP-AES)

    Energy Technology Data Exchange (ETDEWEB)

    Chew, L.T.; Bradley, D.A. E-mail: D.A.Bradley@exeter.ac.uk; Mohd, Y.; Jamil, M

    2000-11-15

    Inductively Coupled Argon Plasma Atomic Emission Spectroscopy (ICP-AES) has been used to determine Pb, Zn and Cu levels in 47 exfoliated human teeth (all of which required extraction for orthodontic reasons). Lead concentrations for the group were 1.7 {mu}g (g tooth mass){sup -1} to 40.5 {mu}g (g tooth mass){sup -1}, with a median of 9.8 {mu}g (g tooth mass){sup -1}. A median lead level in excess of the group value was found for the teeth of six lorry drivers who were included in the study. A more significant enhancement was found for the seven subjects whose age was in excess of 60 years. The median values for Zn and Cu were 123.0 and 0.6 {mu}g (g tooth mass){sup -1} respectively. Present values for tooth-Zn are lower than published data for other ethnic groups.

  11. Photoluminescence, time-resolved emission and photoresponse of plasma-modified porous silicon thin films

    Energy Technology Data Exchange (ETDEWEB)

    Benyahia, Be., E-mail: benyahiabedra@hotmail.com [Unité de Développement de la Technologie du Silicium, 2 Boulevard Frantz Fanon, B.P. 140, Alger-7 Merveilles, Algiers 16200 (Algeria); Guerbous, L. [Centre de Recherche Nucléaire d' Alger, 2 Boulevard Frantz Fanon, B.P. 399, Alger-Gare, Algiers 16000 (Algeria); Gabouze, N.; Mahmoudi, Br. [Unité de Développement de la Technologie du Silicium, 2 Boulevard Frantz Fanon, B.P. 140, Alger-7 Merveilles, Algiers 16200 (Algeria)

    2013-07-01

    Photoluminescence and photoelectrical study on plasma-modified porous silicon (PS) thin films is presented. Porous silicon passivated by hydrocarbon groups (CH{sub x}) shows an intense broad and stable photoluminescence (PL) band centered at 623 nm whereas the maximum of the photosensitivity spectrum is placed around 400 nm. Along with its potential utilization for silicon-based light emitters' fabrication, it could also represent an appealing option for the improvement of energy conversion efficiency in silicon-based solar cells whether by using its luminescence properties (photon down-conversion) or the excess photocurrent produced by an improved high-energy photon's absorption. Excitation spectra (PLE) under steady-state conditions are reported. PLE shows that visible PL is excited by light from UV region. The time-resolved photoluminescence of CH{sub x}/PS in the range of some tenth of μs are investigated at room temperature. The PL decay line shape, in CH{sub x}/PS is well described by stretched exponential. The photosensitivity spectroscopy shows a significant increase of absorption at high photon energy excitation. - Highlights: • Coating porous silicon (PS) by hydrocarbon (CH{sub x}) reduces nonradiative transition. • Drop of the photoluminescence (PL) intensity. • The PL of CH{sub x}/PS is due to radiative transitions at 1.8 and 1.87 eV. • Photosensitivity revealed an excess spectral response (SR) at high-energy excitation. • For photovoltaic PL and SR could be used for the evolution of the silicon solar cells.

  12. Dynamics of lipoprotein level in blood plasma of pregnant women as a function of gestational age according to FTIR spectroscopy

    Science.gov (United States)

    Korolik, E. V.; Korolenko, E. A.; Tretinnikov, O. N.; Kozlyakova, O. V.; Korolik, A. K.; Kirkovskiy, V. V.

    2013-01-01

    Results of an IR spectroscopic investigation of films of blood plasma taken from women of reproductive age, pregnant women with positive and negative Rh factors, and Rh-immunized women were presented as a function of gestational age. It was found that the lipoprotein content in blood plasma of all groups of pregnant women increased during the early stages of pregnancy (17-23 weeks) irrespective of the Rh factor and attained its peak value by weeks 30-35. It was shown that the lipoprotein level in blood plasma as a function of gestational age was quantitatively the same for pregnant women with positive and negative Rh factors. It was established for the first time that this dependence for Rh-immunized women featured a considerable increase of lipoprotein content at gestational age 30-32 weeks and declined acutely by week 36.

  13. Laser-induced Fluorescence and Optical Emission Spectroscopy for the Determination of Reactive Species in the Effluent of Atmospheric Pressure Low Temperature Plasma Jets

    Science.gov (United States)

    Pei, Xuekai; Razavi, Hamid; Lu, Xinpei; Laroussi, Mounir

    2014-10-01

    OH radicals and O atoms are important active species in various applications of room temperature atmospheric pressure plasma jet (RT-APPJ). So the determination of absolute density of OH radicals and O atoms in RT-APPJs is necessary. In this work, the time and spatially resolved OH radicals density of a RT-APPJ are measured using the laser-induced fluorescence (LIF) technology. In addition, the spatial distribution of the emitting species along the axial direction of the jet is of interest and is measured using optical emission spectroscopy. The absolute OH density of the RT-APPJ is about 2.0 × 1013 cm-3 at 5 mm away from the plasma jet nozzle and 1 μs after the discharge. The OH density reaches a maximum when H2O concentration in helium gas flow is about 130ppm. In order to control the OH density, the effect of voltage polarity, applied voltage magnitude, pulse frequency, pulse width on the OH density are also investigated and discussed. O atoms are investigated by TA-LIF. It is demonstrated that the O atoms density reaches a maximum when O2 percent is about 0.3% in pure He and the lifetime of O atoms in RT-APPJ is much longer (up to dozens of ms) than OH radicals.

  14. Laser-induced breakdown spectroscopy and inductively coupled plasma-mass spectrometry for determination of Cr in soils from Brits District, South Africa

    Directory of Open Access Journals (Sweden)

    A. A. Ambushe

    2015-10-01

    Full Text Available Laser-induced breakdown spectroscopy (LIBS is an emerging analytical technique, which can be used to perform elemental analysis of any material, irrespective of its physical state. In this study, the LIBS technique has been applied for quantification of total Cr in soil samples collected from polluted areas of Brits, North West Province, South Africa. A Q-switched neodymium-yttrium aluminium garnet (Nd-YAG laser (10 Hz, λ = 1064 nm was employed for generation of a laser-induced plasma on the surface of the soil sample. The atomic emission lines were recorded using an Andor Shamrock SR-303i spectrometer, fitted with an intensified charge-coupled device (ICCD camera. Detailed investigation of experimental parameters such as gate delay time, gate width and laser pulse energy was conducted. Soil samples were dried, finely ground, sieved and thereafter pelletized before LIBS analysis. Calibration curve for the quantification of Cr was constructed using certified reference materials of soils and sediments. The concentrations of Cr in soil samples varied from 111 to 3180 mg/kg. In order to test the validity of the LIBS results, inductively coupled plasma-mass spectrometry (ICP-MS was also employed for determination of Cr. The results obtained using LIBS were found to be in good agreement with those of ICP-MS.DOI: http://dx.doi.org/10.4314/bcse.v29i3.3

  15. Indirect determination of the electric field in plasma discharges using laser-induced fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Vaudolon, J., E-mail: julien.vaudolon@cnrs-orleans.fr; Mazouffre, S., E-mail: stephane.mazouffre@cnrs-orleans.fr [CNRS - ICARE (Institut de Combustion Aérothermique Réactivité et Environnement), 1 C Av. de la Recherche Scientifique, 45071 Orléans Cedex 2 (France)

    2014-09-15

    The evaluation of electric fields is of prime interest for the description of plasma characteristics. In this work, different methods for determining the electric field profile in low-pressure discharges using one- and two-dimensional Laser-Induced Fluorescence (LIF) measurements are presented and discussed. The energy conservation, fluid, and kinetic approaches appear to be well-suited for the electric field evaluation in this region of the plasma flow. However, the numerical complexity of a two-dimensional kinetic model is penalizing due to the limited signal-to-noise ratio that can be achieved, making the computation of the electric field subject to large error bars. The ionization contribution which appears in the fluid model makes it unattractive on an experimental viewpoint. The energy conservation and 1D1V kinetic approaches should therefore be preferred for the determination of the electric field when LIF data are used.

  16. The Role of Plasma Shielding in Double-Pulse Femtosecond Laser-Induced Breakdown Spectroscopy

    CERN Document Server

    Penczak, John S; Bar, Ilana; Gordon, Robert J

    2013-01-01

    It is well known that optical emission produced by femtosecond laser-induced breakdown on a surface may be enhanced by using a pair of laser pulses separated by a suitable delay. Here we elucidate the mechanism for this effect both experimentally and theoretically. Using a bilayer sample consisting of a thin film of Ag deposited on an Al substrate as the ablation target and measuring the breakdown spectrum as a function of fluence and pulse delay, it is shown experimentally that the enhanced signal is not caused by additional ablation initiated by the second pulse. Rather, particle-in-cell calculations show that the plasma produced by the first pulse shields the surface from the second pulse for delays up to 100 ps. These results indicate that the enhancement is the result of excitement of particles entrained in the plasma produced by the first pulse.

  17. Oxygen ion impurity in the TEXTOR tokamak boundary plasma observed and analysed by Zeeman spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hey, J.D.; Chu, C.C. [Plasma Physics Research Institute, University of Natal, Durban (South Africa)]. E-mails: hey@nu.ac.za; chu@nu.ac.za; Brezinsek, S.; Unterberg, B.; Mertens, Ph. [Institut fuer Plasmaphysik, Forschungszentrum Juelich, Juelich (Germany)]. E-mail: ph.mertens@fz-juelich.de

    2002-03-28

    Oxygen ion impurity radiation is a potential source of inaccuracy in ion temperature determination with the aid of the commonly used C VI transition n=8{yields}n'=7, produced by charge-exchange recombination (CXR) of C{sup 6+} ions, since the corresponding transition in O VI cannot be resolved under typical plasma conditions in the tokamak. In order to demonstrate the possible importance of oxygen ion impurity radiation, we have selected a convenient spectroscopic 'window' (about 8 A wide) containing the major Zeeman components of two prominent lines in the visible (multiplet 1), one emitted by C{sup 2+} and one by O{sup +}. Observations have been performed in this wavelength range, both tangentially and perpendicularly to the magnetic flux surfaces, in the second case with the aid of a special graphite test limiter. Measurements include the case of special plasma discharges in which oxygen gas was introduced from the test limiter. The temperatures of both species are evaluated from the Doppler broadening of the respective Zeeman components, and compared with the results from a model for collisional heating by impact with hot protons (deuterons) in the plasma edge. The spectra and derived results show that impurity identification in tokamak edge plasmas should not be carried out with the aid of spectral lines from highly excited levels populated by CXR, but using lines corresponding to much more species-specific transitions from lower ionization stages. The identification and quantitative analysis should be performed with the aid of carefully measured and calculated Zeeman-(Paschen-Back-) broadened line profiles, since these have features practically unique to the species under investigation. Some allowance may, however, be required for deviation, from a statistical distribution, of population among fine-structure sublevels. (author)

  18. Schlieren, Phase-Contrast, and Spectroscopy Diagnostics for the LBNL HIF Plasma Channel Experiment

    Science.gov (United States)

    Ponce, D. M.; Niemann, C.; Fessenden, T. J.; Leemans, W.; Vandersloot, K.; Dahlbacka, G.; Yu, S. S.; Sharp, W. M.; Tauschwitz, A.

    1999-11-01

    The LBNL Plasma Channel experiment has demonstrated stable 42-cm Z-pinch discharge plasma channels with peak currents in excess of 50 kA for a 7 torr nitrogen, 30 kV discharge. These channels offer the possibility of transporting heavy-ion beams for inertial fusion. We postulate that the stability of these channels resides in the existance of a neutral-gas density depresion created by a pre-pulse discharge before the main capacitor bank discharge is created. Here, we present the results and experimental diagnostics setup used for the study of the pre-pulse and main bank channels. Observation of both the plasma and neutral gas dynamics is achieved. Schlieren, Zernike's phase-contrast, and spectroscopic techniques are used. Preliminary Schlieren results show a gas shockwave moving radially at a rate of ≈ 10^6 mm/sec as a result of the fast and localized deposited energy during the evolution of the pre-pulse channel. This data will be used to validate simulation codes (BUCKY and CYCLOPS).

  19. The design of circuit for THz time domain spectroscopy system based on asynchronous optical sampling

    Science.gov (United States)

    Wang, Ruike; Zhang, Mile; Li, Yihan; He, Jingsuo; Zhang, Cunlin; Cui, Hailin

    2016-11-01

    Terahertz time domain spectroscopy system (THz-TDS) is the most commonly means of measuring terahertz time-domain spectroscopy. The time delay between the pump and probe laser is an important technology to realize THz time domain spectrum measurement. The translation platform with two mirrors and the mechanical structure is the popular means to adjust the optical path difference between the pump and probe laser to get the time delay of femtosecond pulse. Because of the limit of the mechanical structure and the phase-locked amplifier, this technique can't scan spectrum fast. In order to obtain high quality signal, a long time will be taken to scan spectrum. So a more rapid and convenient time delay technology is required to Instead of the machine translation platform and accomplish the Rapid spectral measurement. Asynchronous optical sampling technique is a way to get the time delay by producing a very small frequency difference between the repetition frequency of two femtosecond lasers. The scanner time will be reduced, because of there is no waste of time, due to mechanical inertia, not only by using the asynchronous optical sampling method to replace the mechanical structure without the influence of vibration. It will greatly increase the degree of integration by using the fiber femtosecond laser and highly integrated circuit to realize optical asynchronous sampling. To solve the problem above, a terahertz time-domain spectroscopy system based on asynchronous sampling is designed in this thesis. The system is based of two femtosecond laser whose repetition frequency is 100MHz.In order to realize asynchronous sampling, the control circuit of the two lasers is the most important. This thesis focuses on the researching, designing and experiment of this circuit. Firstly, the circuit is designed overall. Then the selection of the key device and the designing of the circuit principle is done by myself. Secondly, the test of the circuit to phase locked the master and

  20. Broadband ultraviolet-visible transient absorption spectroscopy in the nanosecond to microsecond time domain with sub-nanosecond time resolution.

    Science.gov (United States)

    Lang, Bernhard; Mosquera-Vázquez, Sandra; Lovy, Dominique; Sherin, Peter; Markovic, Vesna; Vauthey, Eric

    2013-07-01

    A combination of sub-nanosecond photoexcitation and femtosecond supercontinuum probing is used to extend femtosecond transient absorption spectroscopy into the nanosecond to microsecond time domain. Employing a passively Q-switched frequency tripled Nd:YAG laser and determining the jitter of the time delay between excitation and probe pulses with a high resolution time delay counter on a single-shot basis leads to a time resolution of 350 ps in picosecond excitation mode. The time overlap of almost an order of magnitude between fs and sub-ns excitation mode permits to extend ultrafast transient absorption (TA) experiments seamlessly into time ranges traditionally covered by laser flash photolysis. The broadband detection scheme eases the identification of intermediate reaction products which may remain undetected in single-wavelength detection flash photolysis arrangements. Single-shot referencing of the supercontinuum probe with two identical spectrometer/CCD arrangements yields an excellent signal-to-noise ratio for the so far investigated chromophores in short to moderate accumulation times.

  1. Characterization of RF He-N2/Ar mixture plasma via Langmuir probe and optical emission spectroscopy techniques

    Science.gov (United States)

    Younus, Maria; Rehman, N. U.; Shafiq, M.; Hussain, S. S.; Zakaullah, M.; Zaka-ul-Islam, M.

    2016-08-01

    A Magnetic Pole Enhanced inductively coupled RF H e - N 2 / A r plasma is characterized using a Langmuir probe and optical emission spectroscopy (OES) techniques. The effect of helium mixing on electron density ( n e ) and temperature ( T e ) , electron energy probability functions (EEPFs), [ N ] atomic density, and N 2 dissociation is investigated. A Langmuir probe and a zero slope method based on trace rare gas-optical emission spectroscopy (TRG-OES) are employed to measure the electron temperature. It is noted that the electron temperature shows an increasing trend for both methods. However, the temperature measured by a zero slope method T e ( Z . S ) approaches the temperature measured by a Langmuir probe; T e ( L . P ) at 56% and above helium concentration in the discharge. "Advance actinometry" is employed to monitor the variation in [ N ] atomic density with helium concentration and gas pressure. It is noted that [ N ] atomic density increases at 56% and above helium in the discharge, which is consistent with the trend of electron temperature and EEPFs. A drastic enhancement in N 2 dissociation fraction D 1 determined by "advance actinometry" is noted at 56% and above helium concentration in the mixture due to modifications in different population and depopulation mechanisms. However, it is also noted that the dissociation fraction D 2 determined by intensity ratio method increases linearly with helium addition.

  2. Real-time DSP-based shape determination and plasma position control in the ISTTOK tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, B. E-mail: bernardo@cfn.ist.utl.pt; Fernandes, H.; Silva, C.; Borba, D.; Varandas, C.A.F

    2004-06-01

    We have developed a digital signal processor-based system for real-time control of the ISTTOK plasma position based on a low-cost digital signal processor (DSP) board. A novel plasma shape reproduction method was developed using a Cauchy-condition expansion applied to the vacuum region around the plasma. This method showed to be best suited than classic methods such as Legendre-Fourier expansion (LFE) or current filaments (CF), particularly in small tokamaks with passive stabilizer conductors where the presence of strong eddy currents can cause significant errors in magnetic field sensors. We compare the results of the boundary reconstruction method with the measurements from a microwave interferometer diagnostic. We present an implementation in the DSP system that allows the real time control of the plasma position with a required 1 ms period.

  3. Capturing interfacial photoelectrochemical dynamics with picosecond time-resolved X-ray photoelectron spectroscopy.

    Science.gov (United States)

    Neppl, Stefan; Shavorskiy, Andrey; Zegkinoglou, Ioannis; Fraund, Matthew; Slaughter, Daniel S; Troy, Tyler; Ziemkiewicz, Michael P; Ahmed, Musahid; Gul, Sheraz; Rude, Bruce; Zhang, Jin Z; Tremsin, Anton S; Glans, Per-Anders; Liu, Yi-Sheng; Wu, Cheng Hao; Guo, Jinghua; Salmeron, Miquel; Bluhm, Hendrik; Gessner, Oliver

    2014-01-01

    Time-resolved core-level spectroscopy using laser pulses to initiate and short X-ray pulses to trace photoinduced processes has the unique potential to provide electronic state- and atomic site-specific insight into fundamental electron dynamics in complex systems. Time-domain studies using transient X-ray absorption and emission techniques have proven extremely valuable to investigate electronic and structural dynamics in isolated and solvated molecules. Here, we describe the implementation of a picosecond time-resolved X-ray photoelectron spectroscopy (TRXPS) technique at the Advanced Light Source (ALS) and its application to monitor photoinduced electron dynamics at the technologically pertinent interface formed by N3 dye molecules anchored to nanoporous ZnO. Indications for a dynamical chemical shift of the Ru3d photoemission line originating from the N3 metal centre are observed ∼30 ps after resonant HOMO-LUMO excitation with a visible laser pump pulse. The transient changes in the TRXPS spectra are accompanied by a characteristic surface photovoltage (SPV) response of the ZnO substrate on a pico- to nanosecond time scale. The interplay between the two phenomena is discussed in the context of possible electronic relaxation and recombination pathways that lead to the neutralisation of the transiently oxidised dye after ultrafast electron injection. A detailed account of the experimental technique is given including an analysis of the chemical modification of the nano-structured ZnO substrate during extended periods of solution-based dye sensitisation and its relevance for studies using surface-sensitive spectroscopy techniques.

  4. Evaluation of the ID220 single photon avalanche diode for extended spectral range of photon time-of-flight spectroscopy

    DEFF Research Database (Denmark)

    Nielsen, Otto Højager Attermann; Dahl, Anders Bjorholm; Anderson-Engels, Stefan

    This paper describe the performance of the ID220 single photon avalanche diode for single photon counting, and investigates its performance for photon time-of-flight (PToF) spectroscopy. At first this report will serve as a summary to the group for PToF spectroscopy at the Department of Physics...

  5. Space-Time Localization of Plasma Turbulence Using Multiple Spacecraft Radio Links

    Science.gov (United States)

    Armstrong, John W.; Estabrook, Frank B.

    2011-01-01

    Space weather is described as the variability of solar wind plasma that can disturb satellites and systems and affect human space exploration. Accurate prediction requires information of the heliosphere inside the orbit of the Earth. However, for predictions using remote sensing, one needs not only plane-of-sky position but also range information the third spatial dimension to show the distance to the plasma disturbances and thus when they might propagate or co-rotate to create disturbances at the orbit of the Earth. Appropriately processed radio signals from spacecraft having communications lines-of-sight passing through the inner heliosphere can be used for this spacetime localization of plasma disturbances. The solar plasma has an electron density- and radio-wavelength-dependent index of refraction. An approximately monochromatic wave propagating through a thin layer of plasma turbulence causes a geometrical-optics phase shift proportional to the electron density at the point of passage, the radio wavelength, and the thickness of the layer. This phase shift is the same for a wave propagating either up or down through the layer at the point of passage. This attribute can be used for space-time localization of plasma irregularities. The transfer function of plasma irregularities to the observed time series depends on the Doppler tracking mode. When spacecraft observations are in the two-way mode (downlink radio signal phase-locked to an uplink radio transmission), plasma fluctuations have a two-pulse response in the Doppler. In the two-way mode, the Doppler time series y2(t) is the difference between the frequency of the downlink signal received and the frequency of a ground reference oscillator. A plasma blob localized at a distance x along the line of sight perturbs the phase on both the up and down link, giving rise to two events in the two-way tracking time series separated by a time lag depending the blob s distance from the Earth: T2-2x/c, where T2 is the

  6. Analyzing the adsorption of blood plasma components by means of fullerene-containing silica gels and NMR spectroscopy in solids

    Science.gov (United States)

    Melenevskaya, E. Yu.; Mokeev, M. V.; Nasonova, K. V.; Podosenova, N. G.; Sharonova, L. V.; Gribanov, A. V.

    2012-10-01

    The results from studying the adsorption of blood plasma components (e.g., protein, triglycerides, cholesterol, and lipoproteins of low and high density) using silica gels modified with fullerene molecules (in the form of C60 or the hydroxylated form of C60(OH) x ) and subjected to hydration (or, alternatively, dehydration) are presented. The conditions for preparing adsorbents that allow us to control the adsorption capacity of silica gel and the selectivity of adsorption toward the components of blood plasma, are revealed. The nature and strength of the interactions of the introduced components (fullerene molecules and water) with functional groups on the silica surface are studied by means of solid state NMR spectroscopy (NMR-SS). Conclusions regarding the nature of the centers that control adsorption are drawn on the basis of NMR-SS spectra in combination with direct measurements of adsorption. The interaction of the oxygen of the hydroxyl group of silica gel with fullerene, leading to the formation of electron-donor complexes of C60-H, C60-OH, or C60-OSi type, is demonstrated by the observed changes in the NMR-SS spectra of silica gels in the presence of fullerene.

  7. Biochemical characterization of blood plasma of coronary artery disease patients by in vitro high-resolution proton NMR spectroscopy

    Indian Academy of Sciences (India)

    Anu Malik; Uma Sharma; R Lakshmy; Rajiv Narang; Naranamanglam R Jagannathan

    2015-03-01

    This study aimed to investigate the biochemical profile of blood plasma of patients with coronary artery disease (CAD) and angiographically normal subjects (controls) to determine biomarkers for their differentiation. In this double blind study, 5 mL venous blood was drawn before angiography from CAD patients (n=60) and controls (n=13) comprising angiography normal individuals. In vitro high-resolution NMR spectroscopy of these blood plasma samples was carried out at 400 MHz, and intensity data were analysed with partial least square discriminant analysis. Categorization of subjects as controls or CAD patients and the patients further as single vessel disease (SVD), double vessel disease (DVD) and triple vessel disease (TVD) was done at the end of the study based on their angiography reports. Raised levels of lipids, alanine (Ala) and isoleucine/leucine/valine (Ile/Leu/Val) were observed in CAD patients compared with controls. Partial least square discriminant analysis showed separation between controls vs CAD patients. TVD patients showed increased levels of Ile/Leu/Val and Ala compared with controls and SVD. Alanine, Ile/Leu/Val, and LDL/VLDL appear as possible biomarkers for distinguishing between controls and patients with SVD and TVD. A metabolic adaptation of myocardium may play a role in raising the Ala level.

  8. Digital Holography for in Situ Real-Time Measurement of Plasma-Facing-Component Erosion

    Energy Technology Data Exchange (ETDEWEB)

    ThomasJr., C. E. [Third Dimension Technologies, LLC, Knoxville, TN; Granstedt, E. M. [Tri-Alpha Energy; Biewer, Theodore M [ORNL; Baylor, Larry R [ORNL; Combs, Stephen Kirk [ORNL; Meitner, Steven J [ORNL; Hillis, Donald Lee [ORNL; Majeski, R. [Princeton Plasma Physics Laboratory (PPPL); Kaita, R. [Princeton Plasma Physics Laboratory (PPPL)

    2014-01-01

    In situ, real time measurement of net plasma-facing-component (PFC) erosion/deposition in a real plasma device is challenging due to the need for good spatial and temporal resolution, sufficient sensitivity, and immunity to fringe-jump errors. Design of a high-sensitivity, potentially high-speed, dual-wavelength CO2 laser digital holography system (nominally immune to fringe jumps) for PFC erosion measurement is discussed.

  9. Spectral characterisation of dairy products using photon time-of-flight spectroscopy

    DEFF Research Database (Denmark)

    Nielsen, Otto Højager Attermann; Subash, Arman Ahamed; Nielsen, Frederik Donbæk

    2013-01-01

    In this paper, we present, for the first time, the absorption and reduced scattering spectra of commercially available milk and yoghurt products, obtained using photon-time-of-flight spectroscopy. The ability of this technique to separate the contributions from absorption and scattering in the sa......In this paper, we present, for the first time, the absorption and reduced scattering spectra of commercially available milk and yoghurt products, obtained using photon-time-of-flight spectroscopy. The ability of this technique to separate the contributions from absorption and scattering......) for milk with 0.1% fat in the near infrared range, to 60 cm(-1) for yoghurt with 3.0% fat in the green wavelength regime. The absorption is within the range of 0.05-0.5cm(-1), with only small variation in the absolute value between products. Our results show that the reduced scattering clearly...... distinguishes milk and yoghurt with the same fat content and can offer a reliable way of monitoring structural formation during milk fermentation....

  10. Applying of the optical time-of-flight spectroscopy for the paper and pulp characterization

    Science.gov (United States)

    Pluciński, Jerzy

    2006-02-01

    The paper presents benefits of optical time-of-flight spectroscopy for the pulp and paper characterization. A semiconductor pulse laser and a streak camera as the photodetector were utilized in experimental part of research described in this paper. Distribution of the time of flight of photons through various kinds of wood pulp (e.g. pulp after mechanical treatment coming both fi-om tree species giving hard and soft wood and pulp after thermo-mechanical treatment) was measured. The pulp samples used in the measurements had consistency ranging from 0 to 5% of dry mass in the suspension. The influence of additives (kaolin, talc and calcium carbonate) present in the suspension on the time of flight distribution of photons was studied as well. Finally, dependence of the time of flight of photons through various kinds of the paper (i.e. newspaper, copy paper, and tissue) on the thickness of the sample was investigated.

  11. Disentangling Multichannel Photodissociation Dynamics in Acetone by Time-Resolved Photoelectron-Photoion Coincidence Spectroscopy.

    Science.gov (United States)

    Maierhofer, Paul; Bainschab, Markus; Thaler, Bernhard; Heim, Pascal; Ernst, Wolfgang E; Koch, Markus

    2016-08-18

    For the investigation of photoinduced dynamics in molecules with time-resolved pump-probe photoionization spectroscopy, it is essential to obtain unequivocal information about the fragmentation behavior induced by the laser pulses. We present time-resolved photoelectron-photoion coincidence (PEPICO) experiments to investigate the excited-state dynamics of isolated acetone molecules triggered by two-photon (269 nm) excitation. In the complex situation of different relaxation pathways, we unambiguously identify three distinct pump-probe ionization channels. The high selectivity of PEPICO detection allows us to observe the fragmentation behavior and to follow the time evolution of each channel separately. For channels leading to fragment ions, we quantitatively obtain the fragment-to-parent branching ratio and are able to determine experimentally whether dissociation occurs in the neutral molecule or in the parent ion. These results highlight the importance of coincidence detection for the interpretation of time-resolved photochemical relaxation and dissociation studies if multiple pathways are present.

  12. X-Ray Photoelectron Spectroscopy Study of the Effect of Hydrocarbon Contamination on Poly(Tetrafluoroethylene) Exposed to a Nitrogen Plasma

    Science.gov (United States)

    Golub, Morton A.; Lopata, Eugene S.; Finney, Lorie S.

    1993-01-01

    It has been shown that unless the surface of poly(tetrafluoroethylene)(PTFE) is free of hydrocarbon contamination, anomalous changes in the oxygen and fluorine contents, as measured by X-ray photoelectron spectroscopy (XPS), and hence also the surface properties, may be improperly ascribed to a PTFE film exposed to a oxygen plasma.

  13. Ultra-Sensitive Elemental and Isotope Measurements with Compact Plasma Source Cavity Ring-Down Spectroscopy (CPS-CRDS)

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Yixiang; Wang, Chuji; Winstead, Christopher B.

    2005-06-01

    The proposed research is to develop a new class of instruments for actinide isotopes and hazardous element analysis through coupling highly sensitive cavity ring-down spectroscopy to a compact microwave plasma source. The research work will combine advantages of CRDS measurement with a low power, low flow rate, tubing-type microwave plasma source to reach breakthrough sensitivity for elemental analysis and unique capability of isotope measurement. The project has several primary goals: (1) Explore the feasibility of marrying CRDS with a new microwave plasma source; (2) Provide quantitative evaluation of CMP-CRDS for ultratrace elemental and actinide isotope analysis; (3) Approach a breakthrough detection limit of ca. 10{sup -13} g/ml or so, which are orders of magnitude better than currently available best values; (4) Demonstrate the capability of CMP-CRDS technology for isobaric measurements, such as {sup 238}U and {sup 238}Pu isotopes. (5) Design and assemble the first compact, field portable CMP-CRDS instrument with a high-resolution diode laser for DOE/EM on-site demonstration. With all these unique capabilities and sensitivities, we expect CMP-CRDS will bring a revolutionary change in instrument design and development, and will have great impact and play critical roles in supporting DOE's missions in environmental remediation, environmental emission control, waste management and characterization, and decontamination and decommissioning. The ultimate goals of the proposed project are to contribute to environmental management activities that would decrease risk for the public and workers, increase worker productivity with on-site analysis, and tremendously reduce DOE/EM operating costs.

  14. K-shell X-ray spectroscopy of laser produced aluminum plasma

    Science.gov (United States)

    Kaur, Channprit; Chaurasia, S.; Poswal, A. K.; Munda, D. S.; Rossall, A. K.; Deo, M. N.; Sharma, Surinder M.

    2017-01-01

    Optimization of a laser produced plasma (LPP) X-ray source has been performed by analyzing K-shell emission spectra of Al plasma at a laser intensity of 1013-1014 W/cm2. The effect of varying the laser intensity on the emissivity of the K-shell resonance lines is studied and found to follow a power law, Ix =(IL) α with α=2.2, 2.3, 2.4 for Heβ, Heγ, Heδ respectively. The emission of these resonance lines has been found to be heavily anisotropic. A Python language based code has been developed to generate an intensity profile of K-shell spectral lines from the raw data. In theoretical calculations, the temperature is estimated by taking the ratio of the Li-like satellite (1s22p-1s2p3p) and the Heβ (1s2-1s3p) resonance line and the ratio of the He-like satellite (1s2p-2p2) and the Lyα (1s-2p) resonance line. To determine the plasma density, stark broadening of the Lyβ spectral line is used. Simulation was carried out using the FLYCHK code to generate a synthetic emission spectrum. The results obtained by FLYCHK are Te=160 eV, Th=1 keV, f=0.008, ne=5×1020 cm-3 and the analytical model resulted Te=260-419 eV and ne=3x1020 cm-3.

  15. Determination of ammonium and organic bound nitrogen by inductively coupled plasma emission spectroscopy.

    Science.gov (United States)

    Jaber, A M Y; Mehanna, N A; Sultan, S M

    2009-06-15

    The continuous flow sample introduction technique with a hydride generator system in conjunction with an inductively coupled plasma emission spectrometer (ICP-AES-HG), is used in this study for quantitative determination of ammonium and organic bound nitrogen in aqueous and solid samples. Ammonia vapor released from ammonium salt after treatment with concentrated NaOH is transferred by argon to plasma for detection at 174.273 nm using axial argon plasma mode. The calibration curves were linear within a range of 25-1000 mg L(-1)N as ammonium molybdate with correlation coefficients of better than 0.99 and limits of detection of about 10-25mg L(-1)N. The percent recovery of N (25-500 mg L(-1)N) in soft (distilled) water and high salt content (1.7 mol L(-1) NaCl) matrices was found to be in the range of about 97-102% with %RSD in the range of 4.6-0.62. The sensitivity, limit of detection, and blank contribution from the atmospheric nitrogen, were tremendously improved in this method compared with the available ICP-AES spray chamber counterpart. Furthermore, the ICP-AES-HG method gave results for real samples (soil, fertilizer, waste water) containing about 50-1800 mg L(-1)N in good agreement with those obtained by the standard Kjeldahl method. No statistical differences at the 95% confidence level on applying the t-test were observed between the values obtained by the two methods. Thus, the ICP-AES-HG method is reliable and faster than the conventional tedious Kjeldahl method, superior to the ICP-AES spray chamber method, and almost free from matrix interference which is usually a critical factor in atomic emission spectroscopic techniques.

  16. Solution of time-dependent Boltzmann equation for electrons in non-thermal plasma

    Energy Technology Data Exchange (ETDEWEB)

    Trunec, D; Bonaventura, Z; Necas, D [Department of Physical Electronics, Faculty of Science, Masaryk University, Kotlarska 2, 611 37 Brno (Czech Republic)

    2006-06-21

    The time development of the electron distribution function and electron macroscopic parameters was studied by solving the time-dependent Boltzmann equation for low temperature plasma. A new technique for solving the time-dependent Boltzmann equation was developed. This technique is based on a multi-term approximation of the electron distribution function expansion in Legendre polynomials. The results for electron relaxation in Reid's ramp model and argon plasma are presented. The effect of negative mobility was studied and is discussed for argon plasma. Finally, the time-dependent Boltzmann equation was solved for pulsed microwave discharge in nitrogen. The accuracy of all results was confirmed by the Monte Carlo simulation.

  17. Inductively Coupled Plasma Optical-Emission Spectroscopy Determination of Major and Minor Elements in Vinegar

    Directory of Open Access Journals (Sweden)

    Arzu AKPINAR-BAYIZIT

    2010-12-01

    Full Text Available This study characterizes the mineral content of vinegar samples. The concentrations of Na, K, Ca, Mg and P (major elements as well as Fe, Mn, Sn, Cu, Ni, Zn, Pb and Cd (minor elements were determined in 35 commercial vinegar samples using inductively coupled plasma optical-emission spectrometry (ICP-OES. The elements with the highest concentrations were K, Na, Ca, Mg and P. The concentrations of heavy metals in the vinegar samples, including Cd, Ni, Sn and Pb, were not considered a health risk.

  18. Neutron emission spectroscopy of DT plasmas at enhanced energy resolution with diamond detectors

    Science.gov (United States)

    Giacomelli, L.; Nocente, M.; Rebai, M.; Rigamonti, D.; Milocco, A.; Tardocchi, M.; Chen, Z. J.; Du, T. F.; Fan, T. S.; Hu, Z. M.; Peng, X. Y.; Hjalmarsson, A.; Gorini, G.

    2016-11-01

    This work presents measurements done at the Peking University Van de Graaff neutron source of the response of single crystal synthetic diamond (SD) detectors to quasi-monoenergetic neutrons of 14-20 MeV. The results show an energy resolution of 1% for incoming 20 MeV neutrons, which, together with 1% detection efficiency, opens up to new prospects for fast ion physics studies in high performance nuclear fusion devices such as SD neutron spectrometry of deuterium-tritium plasmas heated by neutral beam injection.

  19. Transformation optics: a time- and frequency-domain analysis of electron-energy loss spectroscopy

    CERN Document Server

    Kraft, Matthias; Pendry, J B

    2016-01-01

    Electron energy loss spectroscopy (EELS) and Cathodoluminescence (CL) play a pivotal role in many of the cutting edge experiments in plasmonics. EELS and CL experiments are usually supported by numerical simulations, which, whilst accurate, may not provide as much physical insight as analytical calculations do. Fully analytical solutions to EELS and CL systems in plasmonics are rare and difficult to obtain. This paper aims to narrow this gap by introducing a new method based on Transformation optics that allows to calculate the quasi-static frequency and time-domain response of plasmonic particles under electron beam excitation.

  20. Probing negative refractive index of metamaterials by terahertz time-domain spectroscopy.

    Science.gov (United States)

    Han, Jiaguang

    2008-01-21

    Terahertz time-domain spectroscopy (THz-TDS) offers a new perspective for extraction of negative refractive index of low-loss metamaterials directly. We present the detailed extraction procedure how to obtain the negative refractive index of metamaterials through THz-TDS measurement. The basic equations are deduced to obtain the negative index through comparison of THz data measured for the sample and reference, respectively. Further simulation examples matching the practical experimental cases are given, which verifies that the extraction procedure is reliable. This approach demonstrates the potential use of THz-TDS in study of metamaterials and is helpful for design of metamaterial devices.

  1. Hole emission from Ge/Si quantum dots studied by time-resolved capacitance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Kapteyn, C.M.A.; Lion, M.; Heitz, R.; Bimberg, D. [Technische Univ. Berlin (Germany). Inst. fuer Festkoerperphysik; Miesner, C.; Asperger, T.; Brunner, K.; Abstreiter, G. [Technische Univ. Muenchen, Garching (Germany). Walter-Schottky-Inst. fuer Physikalische Grundlagen der Halbleiterelektronik

    2001-03-01

    Emission of holes from self-organized Ge quantum dots (QDs) embedded in Si Schottky diodes is studied by time-resolved capacitance spectroscopy (DLTS). The DLTS signal is rather broad and depends strongly on the filling and detection bias conditions. The observed dependence is interpreted in terms of carrier emission from many-hole states of the QDs. The activation energies obtained from the DLTS measurements are a function of the amount of stored charge and the position of the Fermi level in the QDs. (orig.)

  2. Characterization of powellite-based solid solutions by site-selective time resolved laser fluorescence spectroscopy

    OpenAIRE

    Schmidt, Moritz; Heck, Stephanie; Bosbach, Dirk; Ganschow, Steffen; Walther, Clemens; Stumpf, Thorsten

    2013-01-01

    We present a comprehensive study of the solid solution system Ca-2(MoO4)(2)-NaGd(MoO4)(2) on the molecular scale, by means of site-selective time resolved laser fluorescence spectroscopy (TRLFS). Eu3+ is used as a trace fluorescent probe, homogeneously substituting for Gd3+ in the solid solution crystal structure. Site-selective TRLFS of a series of polycrystalline samples covering the whole composition range of the solid solution series from 10% substitution of Ca2+ to the NaGd end-member re...

  3. Terahertz time domain attenuated total reflection spectroscopy with an integrated prism system.

    Science.gov (United States)

    Nakanishi, Atsushi; Kawada, Yoichi; Yasuda, Takashi; Akiyama, Koichiro; Takahashi, Hironori

    2012-03-01

    We demonstrated attenuated total reflection (ATR) spectroscopy with an integrated prism system that included a terahertz emitter, a terahertz receiver, and an ATR prism. The ATR prism had two internal off-axis parabolic mirrors for, respectively, collimating and focusing the terahertz waves. The Fresnel loss at each interface was reduced, and the total propagation efficiency was 3.36 times larger than when using a non-integrated prism system. The refractive index of water samples calculated from the experimental data showed good agreement with values reported in the literature.

  4. Real time assessment of RF cardiac tissue ablation with optical spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Demos, S G; Sharareh, S

    2008-03-20

    An optical spectroscopy approach is demonstrated allowing for critical parameters during RF ablation of cardiac tissue to be evaluated in real time. The method is based on incorporating in a typical ablation catheter transmitting and receiving fibers that terminate at the tip of the catheter. By analyzing the spectral characteristics of the NIR diffusely reflected light, information is obtained on such parameters as, catheter-tissue proximity, lesion formation, depth of penetration of the lesion, formation of char during the ablation, formation of coagulum around the ablation site, differentiation of ablated from healthy tissue, and recognition of micro-bubble formation in the tissue.

  5. Ordering of PCDTBT revealed by time-resolved electron paramagnetic resonance spectroscopy of its triplet excitons.

    Science.gov (United States)

    Biskup, Till; Sommer, Michael; Rein, Stephan; Meyer, Deborah L; Kohlstädt, Markus; Würfel, Uli; Weber, Stefan

    2015-06-22

    Time-resolved electron paramagnetic resonance (TREPR) spectroscopy is shown to be a powerful tool to characterize triplet excitons of conjugated polymers. The resulting spectra are highly sensitive to the orientation of the molecule. In thin films cast on PET film, the molecules' orientation with respect to the surface plane can be determined, providing access to sample morphology on a microscopic scale. Surprisingly, the conjugated polymer investigated here, a promising material for organic photovoltaics, exhibits ordering even in bulk samples. Orientation effects may significantly influence the efficiency of solar cells, thus rendering proper control of sample morphology highly important.

  6. Plasmonic enhanced terahertz time-domain spectroscopy system for identification of common explosives

    Science.gov (United States)

    Demiraǧ, Yiǧit; Bütün, Bayram; Özbay, Ekmel

    2017-05-01

    In this study, we present a classification algorithm for terahertz time-domain spectroscopy systems (THz-TDS) that can be trained to identify most commonly used explosives (C4, HMX, RDX, PETN, TNT, composition-B and blackpowder) and some non-explosive samples (lactose, sucrose, PABA). Our procedure can be used in any THz-TDS system that detects either transmission or reflection spectra at room conditions. After preprocessing the signal in low THz regime (0.1 - 3 THz), our algorithm takes advantages of a latent space transformation based on principle component analysis in order to classify explosives with low false alarm rate.

  7. Comparison of organic phantom recipes and characterization by time-resolved diffuse optical spectroscopy

    Science.gov (United States)

    Quarto, G.; Pifferi, A.; Bargigia, I.; Farina, A.; Cubeddu, R.; Taroni, P.

    2013-06-01

    Three recipes for tissue constituent-equivalent phantoms of water and lipids are presented. Nature phantoms are made using no emulsifying agent, but just a professional disperser, instead Agar and Triton phantoms are made using agar or Triton X-100, respectively, as agents to emulsify water and lipids. Different water-to-lipid ratios ranging from 30 to 70 percent by mass are proposed and tested. Optical characterization by time-resolved spectroscopy was performed in terms of optical properties, homogeneity, reproducibility and composition retrieval.

  8. Analysis of drugs-of-abuse and explosives using terahertz time-domain and Raman spectroscopy

    Science.gov (United States)

    Burnett, Andrew; Fan, Wenhui; Upadhya, Prashanth; Cunningham, John; Linfield, Edmund; Davies, Giles; Edwards, Howell; Munshi, Tasnim; O'Neil, Andrew

    2006-02-01

    We demonstrate that, through coherent measurement of the transmitted terahertz electric fields, broadband (0.3-8THz) time-domain spectroscopy can be used to measure far-infrared vibrational modes of a range of illegal drugs and high explosives that are of interest to the forensic and security services. Our results show that these absorption features are highly sensitive to the structural and spatial arrangement of the molecules. Terahertz frequency spectra are also compared with high-resolution low-frequency Raman spectra to assist in understanding the low frequency inter- and intra-molecular vibrational modes of the molecules.

  9. Time-resolved pump-probe spectroscopy of intraband absorption by a semiconductor nanorod

    Science.gov (United States)

    Leonov, Mikhail Y.; Rukhlenko, Ivan D.; Baranov, Alexander V.; Fedorov, Anatoly V.

    2013-09-01

    We develop a theory of time-resolved pump-probe optical spectroscopy of intraband absorption of a probe pulse inside an anisotropic semiconductor nanorod. The absorption is preceded by the absorption of the pump pulse resonant to an interband transition. It is assumed that the resonantly exited states of the nanorod are interrelated via the relaxation induced by their interaction with a bath. We reveal the conditions for which the absorption of the probe's pulse is governed by a simple formula regardless of the pulse's shape. This formula is useful for the analysis of the experimental data containing information on the relaxation parameters of the nanorod's electronic subsystem.

  10. Time-resolved energy transfer spectroscopy for measuring mitochondrial metabolism in living cells

    Science.gov (United States)

    Schneckenburger, Herbert; Gschwend, Michael H.; Strauss, Wolfgang S. L.; Sailer, Reinhard; Bauer, Manfred; Steiner, Rudolf W.

    1997-12-01

    Energy transfer from NADH to the mitochondrial marker rhodamine 123 (R123) was used to probe mitochondrial malfunction of cultivated endothelial cells incubated with various inhibitors of specific enzyme complexes of the respiratory chain. Pronounced differences of 'energy transfer efficacy' of incubated cells as compared to controls were deduced from the ratio of fluorescence intensity and intracellular amount of the acceptor. A combination of cw and time-gated (nanosecond) fluorescence spectroscopy appeared to be an appropriate tool for probing mitochondrial malfunction in various kinds of diseases.

  11. Characterization of crystal transformation in the solid-state by terahertz time-domain spectroscopy

    Science.gov (United States)

    Ge, Min; Wang, Wenfeng; Zhao, Hongwei; Zhang, Zengyan; Yu, Xiaohan; Li, Wenxin

    2007-08-01

    Terahertz time-domain spectroscopy (THz-TDS) was utilized to investigate crystal transformation between p-benzoquinone and p-dihydroxybenzene in the solid-state. This process can be clearly visualized by THz spectral patterns of the pure starting compounds and the products at different conditions. The observed results were further confirmed by characteristic X-ray powder diffraction and mid-infrared spectra. The extent of crystal-to-crystal transformation was quantified by the absorption intensity ratio according to the Beer-Lambert law. THz-TDS was demonstrated to be a promising and complementary method in analyzing solid-state reactions.

  12. A beamline for time-resolved extreme ultraviolet and soft x-ray spectroscopy

    CERN Document Server

    Grilj, Jakob; Koch, Markus; Gühr, Markus

    2013-01-01

    High harmonic generation is a convenient way to obtain extreme ultraviolet light from table-top laser systems and the experimental tools to exploit this simple and powerful light source for time-resolved spectroscopy are being developed by several groups. For these applications, brightness and stability of the high harmonic generation is a key feature. This article focuses on practical aspects in the generation of extreme ultraviolet pulses with ultrafast commercial lasers, namely generation parameters and online monitoring as well as analysis of generation yield and stability.

  13. New ultrarapid-scanning interferometer for FT-IR spectroscopy with microsecond time-resolution

    Science.gov (United States)

    Süss, B.; Ringleb, F.; Heberle, J.

    2016-06-01

    A novel Fourier-transform infrared (FT-IR) rapid-scan spectrometer has been developed (patent pending EP14194520.4) which yields 1000 times higher time resolution as compared to conventional rapid-scanning spectrometers. The central element to achieve faster scanning rates is based on a sonotrode whose front face represents the movable mirror of the interferometer. A prototype spectrometer with a time resolution of 13 μs was realized, capable of fully automated long-term measurements with a flow cell for liquid samples, here a photosynthetic membrane protein in solution. The performance of this novel spectrometer is demonstrated by recording the photoreaction of bacteriorhodopsin initiated by a short laser pulse that is synchronized to the data recording. The resulting data are critically compared to those obtained by step-scan spectroscopy and demonstrate the relevance of performing experiments on proteins in solution. The spectrometer allows for future investigations of fast, non-repetitive processes, whose investigation is challenging to step-scan FT-IR spectroscopy.

  14. Cyclohexene Photo-oxidation over Vanadia Catalyst Analyzed by Time Resolved ATR-FT-IR Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Frei, Heinz; Mul, Guido; Wasylenko, Walter; Hamdy, M. Sameh; Frei, Heinz

    2008-06-04

    Vanadia was incorporated in the 3-dimensional mesoporous material TUD-1 with a loading of 2percent w/w vanadia. The performance in the selective photo-oxidation of liquid cyclohexene was investigated using ATR-FT-IR spectroscopy. Under continuous illumination at 458 nm a significant amount of product, i.e. cyclohexenone, was identified. This demonstrates for the first time that hydroxylated vanadia centers in mesoporous materials can be activated by visible light to induce oxidation reactions. Using the rapid scan method, a strong perturbation of the vanadyl environment could be observed in the selective oxidation process induced by a 458 nm laser pulse of 480 ms duration. This is proposed to be caused by interaction of the catalytic centre with a cyclohexenyl hydroperoxide intermediate. The restoration of the vanadyl environment could be kinetically correlated to the rate of formation of cyclohexenone, and is explained by molecular rearrangement and dissociation of the peroxide to ketone and water. The ketone diffuses away from the active center and ATR infrared probing zone, resulting in a decreasing ketone signal on the tens of seconds time scale after initiation of the photoreaction. This study demonstrates the high potential of time resolved ATR FT-IR spectroscopy for mechanistic studies of liquid phase reactions by monitoring not only intermediates and products, but by correlating the temporal behavior of these species to molecular changes of the vanadyl catalytic site.

  15. Terahertz time domain spectroscopy of epoxy resin composite with various carbon inclusions

    Energy Technology Data Exchange (ETDEWEB)

    Macutkevic, J., E-mail: jan@pfi.lt [Center for Physical Sciences and Technology, A. Gostauto 11, Vilnius LT-01108 (Lithuania); Seliuta, D.; Valusis, G.; Adomavicius, R. [Center for Physical Sciences and Technology, A. Gostauto 11, Vilnius LT-01108 (Lithuania); Kuzhir, P.; Paddubskaya, A.; Shuba, M.; Maksimenko, S. [Institute for Nuclear Problem, Belarus State University, 11 Bobruiskaya St., 220030 Minsk (Belarus); Coderoni, L.; Micciulla, F.; Sacco, I.; Bellucci, S. [Frascati National Laboratory, National Institute of Nuclear Physics, via E. Fermi 40, I-00044 Frascati (Roma) (Italy)

    2012-08-24

    Highlights: Black-Right-Pointing-Pointer Epoxy resin with carbon inclusions is studied by terahertz time domain spectroscopy. Black-Right-Pointing-Pointer The resonance dielectric dispersion is observed for all investigated samples. Black-Right-Pointing-Pointer Dielectric properties are modeled by Maxwell-Garnett and nanoelectromagnetic formalism. -- Abstract: The propagation properties of terahertz waves through epoxy resin filled with small amounts (0.25-1.5 wt.%) of commercially available carbon black (CB) and CVD made single-walled and multi-walled carbon nanotubes (CNT) have been investigated by terahertz time domain spectroscopy. High electromagnetic attenuation specified substantially with absorption of THz radiation and strongly decreasing with the decrease of frequency from 0.2 to 1.5 THz has been found for both types of CNT fillers starting from 1 wt.% of nanocarbon concentration. At the same time CB in the same concentration does not make any impact to THz transmission spectrum. The resonance dielectric dispersion has been observed for all investigated samples, which can be attributed to phonon resonance in epoxy resin matrix. The availability of Maxwell-Garnett model for epoxy resin filled with 0.25-1.5 wt.% of CNT was also addressed in the paper.

  16. Time-resolved spatially offset Raman spectroscopy for depth analysis of diffusely scattering layers.

    Science.gov (United States)

    Iping Petterson, Ingeborg E; Dvořák, Patrick; Buijs, Joost B; Gooijer, Cees; Ariese, Freek

    2010-12-01

    The objective of this study is to use time-resolved (TR) Raman spectroscopy, spatially offset Raman spectroscopy (SORS), and a combination of these approaches to obtain high quality Raman spectra from materials hidden underneath an opaque layer. Both TR Raman and SORS are advanced techniques that allow for an increased relative selectivity of photons from deeper layers within a sample. Time-resolved detection reduces fluorescence background, and the selectivity for the second layer is improved. By combining this with spatially offset excitation we additionally increased selectivity for deeper layers. Test samples were opaque white polymer blocks of several mm thicknesses. Excitation was carried out with a frequency-doubled Ti:sapphire laser at 460 nm, 3 ps pulse width and 76 MHz repetition rate. Detection was either with a continuous-wave CCD camera or in time-resolved mode using an intensified CCD camera with a 250 ps gate width. The Raman photons were collected in backscatter mode, with or without lateral offset. By measuring the delay of the Raman signal from the second layer (polyethylene terephthalate/PET/Arnite), the net photon migration speeds through Teflon, polythene, Delrin and Nylon were determined. Raman spectra could be obtained from a second layer of PET through Teflon layers up to 7 mm of thickness. The ability to obtain chemical information through layers of diffusely scattering materials has powerful potential for biomedical applications.

  17. Laser-induced breakdown spectroscopy: a tool for real-time, in vitro and in vivo identification of carious teeth.

    Science.gov (United States)

    Samek, Ota; Telle, Helmut H; Beddows, David CS

    2001-01-01

    BACKGROUND: Laser Induced Breakdown Spectroscopy (LIBS) can be used to measure trace element concentrations in solids, liquids and gases, with spatial resolution and absolute quantifaction being feasible, down to parts-per-million concentration levels. Some applications of LIBS do not necessarily require exact, quantitative measurements. These include applications in dentistry, which are of a more "identify-and-sort" nature - e.g. identification of teeth affected by caries. METHODS: A one-fibre light delivery / collection assembly for LIBS analysis was used, which in principle lends itself for routine in vitro / in vivo applications in a dental practice. A number of evaluation algorithms for LIBS data can be used to assess the similarity of a spectrum, measured at specific sample locations, with a training set of reference spectra. Here, the description has been restricted to one pattern recognition algorithm, namely the so-called Mahalanobis Distance method. RESULTS: The plasma created when the laser pulse ablates the sample (in vitro / in vivo), was spectrally analysed. We demonstrated that, using the Mahalanobis Distance pattern recognition algorithm, we could unambiguously determine the identity of an "unknown" tooth sample in real time. Based on single spectra obtained from the sample, the transition from caries-affected to healthy tooth material could be distinguished, with high spatial resolution. CONCLUSIONS: The combination of LIBS and pattern recognition algorithms provides a potentially useful tool for dentists for fast material identification problems, such as for example the precise control of the laser drilling / cleaning process.

  18. Laser-induced breakdown spectroscopy: a tool for real-time, in vitro and in vivo identification of carious teeth

    Directory of Open Access Journals (Sweden)

    Beddows David CS

    2001-12-01

    Full Text Available Abstract Background Laser Induced Breakdown Spectroscopy (LIBS can be used to measure trace element concentrations in solids, liquids and gases, with spatial resolution and absolute quantifaction being feasible, down to parts-per-million concentration levels. Some applications of LIBS do not necessarily require exact, quantitative measurements. These include applications in dentistry, which are of a more "identify-and-sort" nature – e.g. identification of teeth affected by caries. Methods A one-fibre light delivery / collection assembly for LIBS analysis was used, which in principle lends itself for routine in vitro / in vivo applications in a dental practice. A number of evaluation algorithms for LIBS data can be used to assess the similarity of a spectrum, measured at specific sample locations, with a training set of reference spectra. Here, the description has been restricted to one pattern recognition algorithm, namely the so-called Mahalanobis Distance method. Results The plasma created when the laser pulse ablates the sample (in vitro / in vivo, was spectrally analysed. We demonstrated that, using the Mahalanobis Distance pattern recognition algorithm, we could unambiguously determine the identity of an "unknown" tooth sample in real time. Based on single spectra obtained from the sample, the transition from caries-affected to healthy tooth material could be distinguished, with high spatial resolution. Conclusions The combination of LIBS and pattern recognition algorithms provides a potentially useful tool for dentists for fast material identification problems, such as for example the precise control of the laser drilling / cleaning process.

  19. Imaging electron dynamics with time- and angle-resolved photoelectron spectroscopy

    CERN Document Server

    Popova-Gorelova, Daria; Santra, Robin

    2016-01-01

    We theoretically study how time- and angle-resolved photoemission spectroscopy can be applied for imaging coherent electron dynamics in molecules. We consider a process in which a pump pulse triggers coherent electronic dynamics in a molecule by creating a valence electron hole. An ultrashort extreme ultraviolet (XUV) probe pulse creates a second electron hole in the molecule. Information about the electron dynamics is accessed by analyzing angular distributions of photoemission probabilities at a fixed photoelectron energy. We demonstrate that a rigorous theoretical analysis, which takes into account the indistinguishability of transitions induced by the ultrashort, broadband probe pulse and electron hole correlation effects, is necessary for the interpretation of time- and angle-resolved photoelectron spectra. We show how a Fourier analysis of time- and angle-resolved photoelectron spectra from a molecule can be applied to follow its electron dynamics by considering photoelectron distributions from an indol...

  20. Label-Free Toxin Detection by Means of Time-Resolved Electrochemical Impedance Spectroscopy

    Directory of Open Access Journals (Sweden)

    Paul Takhistov

    2010-01-01

    Full Text Available The real-time detection of trace concentrations of biological toxins requires significant improvement of the detection methods from those reported in the literature. To develop a highly sensitive and selective detection device it is necessary to determine the optimal measuring conditions for the electrochemical sensor in three domains: time, frequency and polarization potential. In this work we utilized a time-resolved electrochemical impedance spectroscopy for the detection of trace concentrations of Staphylococcus enterotoxin B (SEB. An anti-SEB antibody has been attached to the nano-porous aluminum surface using 3-aminopropyltriethoxysilane/glutaraldehyde coupling system. This immobilization method allows fabrication of a highly reproducible and stable sensing device. Using developed immobilization procedure and optimized detection regime, it is possible to determine the presence of SEB at the levels as low as 10 pg/mL in 15 minutes.

  1. Ultra-broadband THz time-domain spectroscopy of common polymers using THz air photonics

    DEFF Research Database (Denmark)

    D’Angelo, Francesco; Mics, Zoltán; Bonn, Mischa

    2014-01-01

    Terahertz-range dielectric properties of the common polymers low-density polyethylene (LDPE), cyclic olefin/ethylene copolymer (TOPAS®), polyamide-6 (PA6), and polytetrafluoroethylene (PTFE or Teflon®) are characterized in the ultra-broadband frequency window 2-15 THz, using a THz time-domain spe......Terahertz-range dielectric properties of the common polymers low-density polyethylene (LDPE), cyclic olefin/ethylene copolymer (TOPAS®), polyamide-6 (PA6), and polytetrafluoroethylene (PTFE or Teflon®) are characterized in the ultra-broadband frequency window 2-15 THz, using a THz time...... and PTFE, and their dielectric functions in the complete frequency window 2-15 THz are theoretically reproduced. Our results demonstrate the potential of ultrabroadband air-photonics-based THz time domain spectroscopy as a valuable analytic tool for materials science....

  2. Complete momentum and energy resolved TOF electron spectrometerfor time-resolved photoemission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hussain, Zahid; Lebedev, G.; Tremsin, A.; Siegmund, O.; Chen, Y.; Shen, Z.X.; Hussain, Z.

    2007-08-12

    Over the last decade, high-resolution Angle-Resolved Photoemission Spectroscopy (ARPES) has emerged as a tool of choice for studying the electronic structure of solids, in particular, strongly correlated complex materials such as cuprate superconductors. In this paper we present the design of a novel time-of-flight based electron analyzer with capability of 2D in momentum space (kx and ky) and all energies (calculated from time of flight) in the third dimension. This analyzer will utilize an improved version of a 2D delay linedetector capable of imaging with<35 mm (700x700 pixels) spatial resolution and better than 120 ps FWHM timing resolution. Electron optics concepts and optimization procedure are considered for achieving an energy resolution less than 1 meV and an angular resolution better than 0.11.

  3. Time-and-frequency-gated photon coincidence counting; a novel multidimensional spectroscopy tool

    Science.gov (United States)

    Dorfman, Konstantin E.; Mukamel, Shaul

    2016-08-01

    Coherent multidimensional optical spectroscopy is broadly applied across the electromagnetic spectrum ranging from NMR to UV. These techniques reveal the properties of matter through the correlation plots of signal fields generated in response to sequences of short pulses with variable delays. Here we discuss a new class of multidimensional techniques obtained by the time-and-frequency-resolved photon coincidence counting measurements of N photons, which constitute a 2N dimensional spectrum. A compact description of these signals is developed based on time-ordered superoperators rather than the normally ordered ordinary operators used in Glauber's photon counting formalism. The independent control of the time and frequency gate parameters reveals fine details of matter dynamics not available otherwise. These signal are illustrated for application to an anharmonic oscillator model with fluctuating energy and anharmonicity.

  4. Time-and-frequency gated photon coincidence counting; a novel multidimensional spectroscopy tool

    CERN Document Server

    Dorfman, Konstantin E

    2016-01-01

    Coherent multidimensional optical spectroscopy techniques are broadly applied across the electromagnetic spectrum ranging from NMR to the UV. These reveal properties of matter through correlation plots of signal fields generated in response to sequences of short pulses with variable delays. Here we discuss a new class of multidimensional techniques obtained by time-and-frequency resolved photon coincidence counting measurements of N photons which constitutes a 2N dimensional spectrum. A compact description of these signals is developed based on time ordered superoperators rather than the normally ordered ordinary operators used in Glauber's photon counting formalism. The independent control of the time and frequency gate parameters reveals details of matter dynamics not available otherwise. Application to an anharmonic oscillator model with fluctuating energy and anharmonicity demonstrates the power of these signals.

  5. Label-Free Toxin Detection by Means of Time-Resolved Electrochemical Impedance Spectroscopy

    Science.gov (United States)

    Chai, Changhoon; Takhistov, Paul

    2010-01-01

    The real-time detection of trace concentrations of biological toxins requires significant improvement of the detection methods from those reported in the literature. To develop a highly sensitive and selective detection device it is necessary to determine the optimal measuring conditions for the electrochemical sensor in three domains: time, frequency and polarization potential. In this work we utilized a time-resolved electrochemical impedance spectroscopy for the detection of trace concentrations of Staphylococcus enterotoxin B (SEB). An anti-SEB antibody has been attached to the nano-porous aluminum surface using 3-aminopropyltriethoxysilane/glutaraldehyde coupling system. This immobilization method allows fabrication of a highly reproducible and stable sensing device. Using developed immobilization procedure and optimized detection regime, it is possible to determine the presence of SEB at the levels as low as 10 pg/mL in 15 minutes. PMID:22315560

  6. Investigations on the time evolution of the plasma density in argon electron-beam plasma at intermediate pressure

    Science.gov (United States)

    Xiaoyan, BAI; Chen, CHEN; Hong, LI; Wandong, LIU

    2017-03-01

    The time evolution of the argon electron-beam plasma at intermediate pressure and low electron beam intensity was presented. By applying the amplitude modulation with the frequency of 20 Hz on the stable beam current, the plasma evolution was studied. A Faraday cup was used for the measurement of the electron beam current and a single electrostatic probe was used for the measurement of the ion current. Experimental results indicated that the ion current was in phase with the electron beam current in the pressure range from 200 Pa to 3000 Pa and in the beam current range lower than 20 mA, the residual density increased approximately linearly with the maximum density in the log-log plot and the fitting coefficient was irrelative to the pressure. And then three kinds of kinetic models were developed and the simulated results given by the kinetic model, without the consideration of the excited atoms, mostly approached to the experimental results. This indicated that the effect of the excited atoms on the plasma density can be ignored at intermediate pressure and low electron beam current intensity, which can greatly simplify the kinetic model. In the end, the decrease of the plasma density when the beam current was suddenly off was studied based on the simplified model and it was found that the decease characteristic at intermediate pressure was approximate to the one at high pressure at low electron beam intensity, which was in good accordance with the experimental results. Supported by National Natural Science Foundations of China (No. 11375187) and the Foundation of State key Laboratory of China (No. SKLIPR1510).

  7. Combination of the ionic-to-atomic line intensity ratios from two test elements for the diagnostic of plasma temperature and electron number density in Inductively Coupled Plasma Atomic Emission Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Tognoni, E. [Istituto per i Processi Chimico-Fisici, Area della Ricerca del Consiglio Nazionale delle Ricerche Via Moruzzi 1, 56124 Pisa (Italy)], E-mail: tognoni@ipcf.cnr.it; Hidalgo, M.; Canals, A. [Departamento de Quimica Analitica, Nutricion y Bromatologia. Universidad de Alicante. Apdo. 99, 03080, Alicante (Spain); Cristoforetti, G.; Legnaioli, S.; Salvetti, A.; Palleschi, V. [Istituto per i Processi Chimico-Fisici, Area della Ricerca del Consiglio Nazionale delle Ricerche Via Moruzzi 1, 56124 Pisa (Italy)

    2007-05-15

    In Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) spectrochemical analysis, the MgII(280.270 nm)/MgI(285.213 nm) ionic to atomic line intensity ratio is commonly used as a monitor of the robustness of operating conditions. This approach is based on the univocal relationship existing between intensity ratio and plasma temperature, for a pure argon atmospheric ICP in thermodynamic equilibrium. In a multi-elemental plasma in the lower temperature range, the measurement of the intensity ratio may not be sufficient to characterize temperature and electron density. In such a range, the correct relationship between intensity ratio and plasma temperature can be calculated only when the complete plasma composition is known. We propose the combination of the line intensity ratios of two test elements (double ratio) as an effective diagnostic tool for a multi-elemental low temperature LTE plasma of unknown composition. In particular, the variation of the double ratio allows us discriminating changes in the plasma temperature from changes in the electron density. Thus, the effects on plasma excitation and ionization possibly caused by introduction of different samples and matrices in non-robust conditions can be more accurately interpreted. The method is illustrated by the measurement of plasma temperature and electron density in a specific analytic case.

  8. HARDENING OF CRANE RAILS BY PLASMA DISCRETE-TIME SURFACE TREATMENT

    Directory of Open Access Journals (Sweden)

    S. S. Samotugin

    2017-01-01

    Full Text Available Crane wheels and rails are subjected to intensive wear in the process of operation. Therefore, improvement of these components’ performance can be considered a task of high importance. A promising direction in this regard is surface treatment by highly concentrated energy flows such as laser beams or plasma jets. This thesis suggests that the use of gradient plasma surface treatment can improve the performance of crane rails. A research was conducted, according to which hardened zones were deposited on crane rails under different treatment modes. Microhardness was measured both at the surface and in depth using custom-made microsections. The article includes the results of study of plasma surface hardening effects on wear resistance of crane rails. Change of plasma surface treatment parameters (current, plasma torch movement speed, argon gas flow rate allows for desired steel hardness and structure, while the choice of optimal location for hardened zones makes it possible to significantly improve wear resistance and crack resistance. As a result of plasma surface hardening, the fine-grained martensite structure is obtained with mainly lamellar morphology and higher hardness rate compared toinduction hardening or overlaying. Wear test of carbon steels revealed that plasma surfacing reduces abrasive wear rate compared to the irinitial state by 2 to 3 times. Enough sharp boundary between hardened and non-hardened portions has a positive effect on the performance of parts under dynamic loads, contributing to the inhibition of cracks during the transition from solid to a soft metal. For carbon and low alloy rail steels, the properties achieved by plasma surface hardening can effectively replace induction hardening or overlaying.The mode range for plasma surface treatment that allow sobtaining a surface layer with certain operating properties has been determined.

  9. Sedimentation in Particulate Aqueous Suspensions as studied by means of Dielectric Time Domain Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Pettersen, Bjoernar Hauknes

    1997-12-31

    Many problems in offshore oil production and multiphase transport are related to surface and colloid chemistry. This thesis applies dielectric spectroscopy as an experimental technique to study the behaviour of particle suspensions in polar media. The thesis opens with an introduction to suspensions and time domain dielectric spectroscopy. It then investigates the dielectric properties of silica and alumina dispersed in polar solvents. It is found that theoretical models can be used to calculate the volume fraction disperse phase in the suspension and that the particle sedimentation depends on the wetting of the particles, charge on the particle surface and viscosity of the solvent, and that this dependency can be measured by time domain dielectric spectroscopy. When the surface properties of silica and alumina particles were modified by coating them with a non-ionic polymer and a non-ionic surfactant, then different degrees of packing in the sedimented phase at the bottom of the sedimentation vessel occurred. Chemometrical methods on the synthesis of monodisperse silica particles were used to investigate what factors influence the particle size. It turned out that it is insufficient to consider only main variables when discussing the results of the synthesis. By introducing interaction terms, the author could explain the variation in the size of particles synthesized. The difference in the sedimentation rate of monodisperse silica particles upon variation of volume fraction particles, pH, salinity, amount of silanol groups at the particle surface and temperature was studied. The cross interactions play an important role and a model explaining the variation in sedimentation is introduced. Finally, magnetic particles dispersed in water and in an external magnetic field were used to study the impact on the sedimentation due to the induced flocculation. 209 refs., 90 figs., 9 tabs.

  10. Toward a real-time measurement of atmospheric mercury concentrations using cavity ring-down spectroscopy

    Directory of Open Access Journals (Sweden)

    X. Faïn

    2009-10-01

    Full Text Available A new sensor based on cavity ring-down spectroscopy (CRDS has been developed for the measurement of gaseous elemental mercury (Hg0 mass concentration with sub-ng m−3 detection limit and high temporal resolution. Cavity ring-down spectroscopy is a direct absorption technique that utilizes path lengths of up to multiple kilometers in a compact absorption cell and has a significantly higher sensitivity than conventional absorption spectroscopy. Our prototype uses a frequency-doubled, tuneable dye laser emitting pulses at ~253.65 nm with a pulse repetition frequency of 50 Hz. The dye laser incorporates a unique piezo element attached to its tuning grating allowing it to tune the laser on and off the Hg0 absorption line on a pulse to pulse basis to facilitate differential absorption measurements. Hg0 absorption measurements with this CRDS laboratory prototype are highly linearly related to Hg0 concentrations determined by a Tekran 2537B analyzer over a Hg0 concentration range of four orders of magnitude, from 0.2 ng m−3 to 573 ng m−3 implying excellent linearity of both instruments. The current CRDS instrument has a~sensitivity of 0.10 ng m−3 at 10 s time resolution. This tool opens new prospects for the study of Hg0 because of its high temporal resolution and reduced limited sample volume requirements (<0.5 l of sample air. Future applications may include ambient Hg0 flux measurements with eddy covariance techniques, which require measurements of Hg0 concentrations with sub-ng m−3 sensitivity and sub-second time resolution.

  11. Real time and in situ determination of ammonia concentration in the atmosphere by intermodulated Stark resonant CO2 laser spectroscopy.

    NARCIS (Netherlands)

    Sauren, H.; Gerkema, E.; Bicanic, D.; Jalink, H.

    1993-01-01

    A concept of Intermodulated Photoacoustic Stark Spectroscopy (IMPASS) was used in an attempt to perform the interference-free field measurement of trace ammonia (3-40 ppbv) concentration levels in the air with a time resolution of 40 s.

  12. CHF3 Dual-Frequency Capacitively Coupled Plasma by Optical Emission Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    XU Yi-Jun; YE Chao; HUANG Xiao-Jiang; YUAN Jing; XING Zhen-Yu; NING Zhao-Yuan

    2008-01-01

    @@ We investigate the intermediate gas phase in the CHF3 13.56 MHz//2 MHz dual-frequency capacitively couple plasma (CCP) for the SiCOH low dielectric constant (low-k) film etching, and the effect of 2MHz power on radicals concentration. The major dissociation reactions of CHF3 in 13.56 MHz CCP are the low dissociation bond energy reactions, which lead to the low F and high CF2 concentrations. The addition of 2MHz power can raise the probability of high dissociation bond energy reactions and lead to the increase of F concentration while keeping the CF2 concentration almost a constant, which is of advantage to the SiCOH low-k films etching. The radical spatial uniformity is dependent on the power coupling of two sources. The increase of 2 MHz power leads to a poor uniformity, however, the uniformity can be improved by increasing 13.56 MHz power.

  13. Detection of copper in water using on-line plasma-excited atomic absorption spectroscopy (AAS).

    Science.gov (United States)

    Porento, Mika; Sutinen, Veijo; Julku, Timo; Oikari, Risto

    2011-06-01

    A measurement method and apparatus was developed to measure continuously toxic metal compounds in industrial water samples. The method was demonstrated by using copper as a sample metal. Water was injected into the sample line and subsequently into a nitrogen plasma jet, in which the samples comprising the metal compound dissolved in water were decomposed. The transmitted monochromatic light was detected and the absorbance caused by copper atoms was measured. The absorbance and metal concentration were used to calculate sensitivity and detection limits for the studied metal. The sensitivity, limit of detection, and quantification for copper were 0.45 ± 0.02, 0.25 ± 0.01, and 0.85 ± 0.04 ppm, respectively.

  14. Time-dependent effects of ultraviolet and nonthermal atmospheric pressure plasma on the biological activity of titanium

    Science.gov (United States)

    Choi, Sung-Hwan; Jeong, Won-Seok; Cha, Jung-Yul; Lee, Jae-Hoon; Yu, Hyung-Seog; Choi, Eun-Ha; Kim, Kwang-Mahn; Hwang, Chung-Ju

    2016-09-01

    Here, we evaluated time-dependent changes in the effects of ultraviolet (UV) and nonthermal atmospheric pressure plasma (NTAPPJ) on the biological activity of titanium compared with that of untreated titanium. Grade IV machined surface titanium discs (12-mm diameter) were used immediately and stored up to 28 days after 15-min UV or 10-min NTAPPJ treatment. Changes of surface characteristics over time were evaluated using scanning electron microscopy, surface profiling, contact angle analysis, X-ray photoelectron spectroscopy, and surface zeta-potential. Changes in biological activity over time were as determined by analysing bovine serum albumin adsorption, MC3T3-E1 early adhesion and morphometry, and alkaline phosphatase (ALP) activity between groups. We found no differences in the effects of treatment on titanium between UV or NTAPPJ over time; both treatments resulted in changes from negatively charged hydrophobic (bioinert) to positively charged hydrophilic (bioactive) surfaces, allowing enhancement of albumin adsorption, osteoblastic cell attachment, and cytoskeleton development. Although this effect may not be prolonged for promotion of cell adhesion until 4 weeks, the effects were sufficient to maintain ALP activity after 7 days of incubation. This positive effect of UV and NTAPPJ treatment can enhance the biological activity of titanium over time.

  15. Time-Resolved Broadband Cavity-Enhanced Absorption Spectroscopy behind Shock Waves.

    Science.gov (United States)

    Matsugi, Akira; Shiina, Hiroumi; Oguchi, Tatsuo; Takahashi, Kazuo

    2016-04-07

    A fast and sensitive broadband absorption technique for measurements of high-temperature chemical kinetics and spectroscopy has been developed by applying broadband cavity-enhanced absorption spectroscopy (BBCEAS) in a shock tube. The developed method has effective absorption path lengths of 60-200 cm, or cavity enhancement factors of 12-40, over a wavelength range of 280-420 nm, and is capable of simultaneously recording absorption time profiles over an ∼32 nm spectral bandpass in a single experiment with temporal and spectral resolutions of 5 μs and 2 nm, respectively. The accuracy of the kinetic and spectroscopic measurements was examined by investigating high-temperature reactions and absorption spectra of formaldehyde behind reflected shock waves using 1,3,5-trioxane as a precursor. The rate constants obtained for the thermal decomposition reactions of 1,3,5-trioxane (to three formaldehyde molecules) and formaldehyde (to HCO + H) agreed well with the literature data. High-temperature absorption cross sections of formaldehyde between 280 and 410 nm have been determined at the post-reflected-shock temperatures of 955, 1265, and 1708 K. The results demonstrate the applicability of the BBCEAS technique to time- and wavelength-resolved sensitive absorption measurements at high temperatures.

  16. Study of broadband THz time-domain spectroscopy at different relative humidity levels

    Institute of Scientific and Technical Information of China (English)

    Chiajen Lin; Ichen Ho; X. C. Zhang

    2012-01-01

    Two detection techniques of broadband terahertz (THz) time-domain spectroscopy-THz air-biased coherent detection (THz-ABCD; from 0.3 to 14 THz) and electro-optical (EO) detection (from 0.3 to 7 THz) - are both performed at several different relative humidity levels.The THz power exponentially decays with the increase in relative humidity.The dynamic range of the main pulse in the time domain linearly decreases as the relative humidity increases from 0% to 40%,and linear fittings show that the slopes are -0.017 and -0.019 for THz-ABCD and EO detection,respectively.Because of the multiple reflections caused by the crystal in the common EO detection,THz-ABCD has better spectral resolution (17 GHz) than that of EO detection (170 GHz).The spectrum of water vapor absorption measured by THz-ABCD is also compared with that measured by the Fourier transform infrared spectroscopy (FTIR).

  17. Fluorescence imaging and time-resolved spectroscopy of steroid using confocal synchrotron radiation microscopy

    Science.gov (United States)

    Gerritsen, Hans C.; van der Oord, C. J. R.; Levine, Yehudi K.; Munro, Ian H.; Jones, Gareth R.; Shaw, D. A.; Rommerts, Fokko F.

    1994-08-01

    The Confocal Synchrotron Radiation Microscope at Daresbury was used in a study of the transport and distribution of the steroid Coumestrol in single Leydig cells. The broad spectrum of synchrotron radiation in combination with UV compatible microscope optics affords the extension of confocal microscopy from the visible to the UV region down to about 200 nm. Consequently fluorescent molecules with absorption bands in the UV can be imaged. In addition the pulsed nature of the light source allows us to perform time-resolved fluorescence spectroscopy experiments on microscopic volumes. Coumestrol is a naturally fluorescing plant steroid exhibiting estrogenic activity. In physiological environments it has an absorption peak in the UV at 340 nm and it emits around 440 nm. First results indicate that the Coumestrol transport through the cell membrane is diffusion limited. The weak fluorescence observed in the nuclei of the Leydig cells may be due to fluorescence quenching arising from the interaction of the Coumesterol with nuclear components. However, micro-volume time-resolved fluorescence spectroscopy experiments on cell nuclei have revealed the same decay behavior for Coumesterol in both the cytoplasm and nucleus of the cells.

  18. Estimation of optical parameters of highly scattering materials by time-of-flight spectroscopy

    Science.gov (United States)

    Plucinski, Jerzy

    2004-07-01

    Optical measurement methods are indispensable tool in biomedical research, providing invaluable information on optical properties of biological tissues. However, the application of these techniques is a big challenge, as most tissues are highly scattering materials whose optical properties cannot be measured in a straightforward way, due to multiple scattering of photons. Therefore, new optical measurement techniques and methods for highly scattering media are being developed to address this problem. One of the very promising techniques is time-of-flight spectroscopy. The paper presents problems encountered in reconstruction of basic optical parameters of tissues or other highly scattering materials from optical time-of-flight spectroscopy measurement data. To estimate the reconstruction accuracy of optical parameters (i.e. absorption coefficient, scattering coefficient, anisotropy factor and refractive index) the test data were generated by a computer program simulating light propagation in highly scattering material by Monte Carlo method. Following, a set of computer programs based on diffusion equation and optimization algorithms such as simplex method and genetic method were used to reconstruct optical parameters from the test data. Finally, by comparing reconstructed optical parameters with those used for generation of the test data, the accuracy of reconstructing algorithms it was estimated.

  19. Design and evaluation of a device for fast multispectral time-resolved fluorescence spectroscopy and imaging.

    Science.gov (United States)

    Yankelevich, Diego R; Ma, Dinglong; Liu, Jing; Sun, Yang; Sun, Yinghua; Bec, Julien; Elson, Daniel S; Marcu, Laura

    2014-03-01

    The application of time-resolved fluorescence spectroscopy (TRFS) to in vivo tissue diagnosis requires a method for fast acquisition of fluorescence decay profiles in multiple spectral bands. This study focusses on development of a clinically compatible fiber-optic based multispectral TRFS (ms-TRFS) system together with validation of its accuracy and precision for fluorescence lifetime measurements. It also presents the expansion of this technique into an imaging spectroscopy method. A tandem array of dichroic beamsplitters and filters was used to record TRFS decay profiles at four distinct spectral bands where biological tissue typically presents fluorescence emission maxima, namely, 390, 452, 542, and 629 nm. Each emission channel was temporally separated by using transmission delays through 200 μm diameter multimode optical fibers of 1, 10, 19, and 28 m lengths. A Laguerre-expansion deconvolution algorithm was used to compensate for modal dispersion inherent to large diameter optical fibers and the finite bandwidth of detectors and digitizers. The system was found to be highly efficient and fast requiring a few nano-Joule of laser pulse energy and time-resolved fluorescence lifetime measurements of low quantum efficiency sub-nanosecond fluorophores.

  20. Detection of renal cell carcinoma using neutron time of flight spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Viana, Rodrigo S.; Yoriyaz, Helio, E-mail: rodrigossviana@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Lakshmanan, Manu N.; Agasthya, Greeshma A.; Kapadia, Anuj J. [Duke University Medical Center, Durham, NC, (United States). Ravin Advanced Imaging Labs, Radiology

    2013-07-01

    The diagnosis of renal cell carcinoma (RCC) is challenging because the symptoms accompanying it are not unique to the disease, and can therefore be misdiagnosed as other diseases. Due to this characteristic, detection of renal cancer is incidental most of time, occurring via abdominal radiographic examinations unrelated to the disease. Presently, biopsy, which is invasive and an unpleasant procedure for the patient, is the most commonly used technique to diagnose RCC. In this study, we demonstrate the application of a novel noninvasive technique for detecting and imaging RCC in vivo. The elemental composition of biological tissues including kidneys has been investigated using a new technique called Neutron Stimulated Emission Computed Tomography (NSECT). This technique is based on detecting the energy signature emitted by the stable isotopes of elements in the body, which are stimulated to emit gamma radiation via inelastic neutron scattering. Methods for improving detection sensitivity and reducing dose, such as time-of-flight neutron spectroscopy have been explored. MCNP5 simulations were used to model the NSECT scanning of the human kidney where the energy and time of arrival of gamma photons were recorded in an ideal detector placed around the human torso. A 5 MeV collimated neutron beam was used to irradiate the kidney containing an RCC lesion. The resulting spectra were resolved in 100 picosecond and 1 keV time and energy bins, respectively. The preliminary results demonstrate the ability to localize the lesion through neutron time of flight spectroscopy and generate a tomographic image at a low dose to the patient. (author)